WorldWideScience

Sample records for taiyo denchi ni

  1. Fluid power education in Taiyo Ltd; Taiyo Tekko (kabu) ni okeru yukuatsu kyoiku

    Energy Technology Data Exchange (ETDEWEB)

    Muraok, Y. [Taiyo Ltd., Tokyo (Japan)

    2000-03-15

    Taiyo Ltd. is a corporation mainly in business of production and sales of industrial machines and facilities, centered by hydraulic/pneumatic devices and assembling machines. The company's products cover individual devices and assemblies, such as pneumatic devices, hydraulic elevator devices, automatic assembling machines for power trains of vehicle engines, and semiconducting wafer transfer machines, centered by industrial standard hydraulic cylinders, special cylinders, and pneumatic cylinders. Education of technical employees is based on OJT at each section. We are worried for the future that essentially no lectures are given to students for hydraulics and pneumatics at colleges and special schools. It seems that students learn basic and professional subjects from the beginning without grasping how they are useful until they start experiments for graduation theses, merely attending lectures for obtaining units for graduation. However, there are still many colleges carrying out concrete researches which surprise students (or make them wonder). It will be an effective way to provide students with concrete themes as soon as they enter colleges, and make them attend basic and professional lectures to pursue these themes. (NEDO)

  2. Estimation of the charge quantity from solar cell to battery; Taiyo denchi ni yoru chikudenchi eno juden yosoku

    Energy Technology Data Exchange (ETDEWEB)

    Tsutsumi, K.; Nishitani, M. [Daiichi University, College of Technology, Kagoshima (Japan)

    1996-10-27

    In performing an experiment of running a small electric vehicle by installing solar cells in it and by charging the storage battery at a specific voltage, an estimation was made on the charge quantity to the battery for each solar altitude and inclination of a module at different hours. The solar altitude was determined at Daiichi University, College of Technology, according to the month and the time of day from a formula using day-declination and time equation of a chronological table of science. The quantity of global solar radiation was determined by resolving the solar radiation into its direct and diffuse components on the basis of the extra-terrestrial solar radiation quantity with the change in radius vector taken into consideration; and then, the global solar radiation on the inclined face was obtained from the angle of inclination and incidence. On the roof of a Daiichi University building, solar cell modules were installed facing north and south at 0{degree}, 30{degree}, 45{degree}, 60{degree} and 90{degree} each, so that a short-circuit current was measured for each differently inclined angle. As a result of the experiment, shown in an regression formula is a relation between the temperature conversion value of the maximum output of the solar cell at the standard temperature of 25{degree}C and the quantity of solar radiation on the inclined surface. Consequently, it enabled the prediction of a charging quantity, in the case of running a small vehicle with solar cells installed, from the quantity of solar radiation on the inclined surface in the clear weather. 2 refs., 4 figs., 2 tabs.

  3. On practicality of a hybrid car with solar cells; Taiyo denchi wo tosaishita hybrid car no jitsuyosei ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Sasaki, K.; Nagayoshi, H.; Kamisako, K. [Tokyo University of Agriculture and Technology, Tokyo (Japan)

    1997-11-25

    The paper stated a development of a hybrid car which is a parallel type with gasoline engine and electric motor as driving source (connecting each according to the situation) and is also equipped with solar cells. Specifications are gasoline engine of 1200cc, induction motor of 5.5kW, lead battery of 288V and 7.2kWh, monocrystal silicon solar cells of 180W maximum output, and body weight of 1100kg. The rear wheel is driven by electric motor, and the front wheel by gasoline engine. The car is loaded with battery charge use solar cells on hood and roof. To enhance cleaning degree, 1.6kW solar cells are installed as an installed power system and used for battery charge. Even by an electric motor with output less than that of the usual electric car, harmful exhaust gas emitted in start-up can be controlled. This is because the electric motor can be used in accelerating. It was confirmed that the power required for it could be supplied by solar cells installed on the car. The hybrid car is practically useful for prevention of local air pollution. 5 refs., 4 figs., 2 tabs.

  4. Research on fabrication technology for thin film solar cells for practical use. Research on low-cost fabrication technology for large-area modules (production technology for amorphous silicon solar cell modules); Usumaku taiyo denchi seizo gijutsu no jitsuyoka kenkyu. Daimenseki module no tei cost seizo gijutsu (amorphous taiyo denchi module seizo no gijutsu kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    Tatsuta, M. [New Energy and Industrial Technology Development Organization, Tokyo (Japan)

    1994-12-01

    This paper reports the study results on the fabrication technology of amorphous Si solar cell modules in fiscal 1994. (1) On process technology for prototype film substrate solar cells, an advanced preprocessing equipment for film substrates, stepping roll type film forming technology, and prototype submodules were studied. A conversion efficiency of 7.2% was achieved by use of the submodule formed in an effective region of 40 {times} 40cm{sup 2}. (2) On efficiency improvement technology for film substrate solar cells, p/i and n/i interfaces, forming condition for Ag film electrodes, film thickness of transparent electrode ITO, and optimum transmissivity were studied. (3) On technology for advanced solar cells, high-quality a-SiGe: H film, ion control in plasma CVD, and a-Si film formation by plasma CVD using SiH2Cl2 were studied as production technology of narrow gap materials. (4) On advanced two-layer tandem solar cells, the defect density in optical degradation of a-Si cells by reverse bias dark current was evaluated, and outdoor exposure data were analyzed. 4 figs., 1 tab.

  5. Study of installation of PV systems at campus; Campus ni okeru taiyoko hatsuden donyu ni kansuru kenkyu (taiyo denchi nomi wo secchishita baai no yobi kento)

    Energy Technology Data Exchange (ETDEWEB)

    Tsuboi, N.; Tanaka, H.; Okumiya, M. [Nagoya University, Nagoya (Japan)

    1997-11-25

    In terms of energy consumption, environmentality and economical efficiency in the case of installing the photovoltaic power system on the rooftop of the university campus, a comparative study was conducted with other power generation systems. As objects to be comparatively studied, selected were the all-electric type centralized space heating/cooling system, cogeneration system, nighttime heat storage system and centralized system with solar cells installed. The panel area of the PV system is 10,000m{sup 2} on the rooftop and 7,000{sup 2} on the outer wall. About data on solar radiation, average values obtained in Nagoya were used. Assessment was made in terms of energy consumption amount at the time of operation, system COP, emission amounts of CO2, NOx and SOx at the time of manufacturing and operation, initial cost, running cost, etc. As a result of the study, an effect of reducing global warming gas was admitted in the PV system. However, the initial cost of the solar cell panel was high, and the life cycle cost of the PV system was lower than other systems. 1 ref., 7 figs., 3 tabs.

  6. Effect of PV module output power on module temperature; Taiyo denchi no shutsuryoku henka ga module hyomen ondo ni oyobosu eikyo

    Energy Technology Data Exchange (ETDEWEB)

    Hongo, T.; Kitamura, A. [Kansai Electric Power Co. Inc., Osaka (Japan); Igaki, K.; Mizumoto, T. [Kanden Kako Co. Inc., Osaka (Japan)

    1996-10-27

    Effect of the photovoltaic (PV) module output power variation on the module surface temperature has been investigated by field measurements. PV modules with capacity of 54 W were used for the temperature measurements. Three 2 kW-class PV systems were operated. T-type thermocouples were used for measuring temperatures. Measurement time intervals were 15 minutes, 30 minutes, 60 minutes, and 24 hours. Measurement period was between May 25, 1995 and June 25, 1996. The surface temperature increased during non-loaded PV output, and decreased during load-carrying PV output. Difference of the surface temperature between non-loaded PV output and load-carrying PV output was 3.5{degree}C at maximum through a year. The surface temperature was saturated within 30 minutes. When PV output was changed in 30 or 60 minutes interval, the variation of surface temperature was distinctly observed. When PV output was changed in 15 minutes interval, it was not observed distinctly. There was no difference of the surface temperatures during the time zones with less solar radiation, such as in the morning and evening, and at night. Except these time zones, difference of the surface temperatures was 3.5{degree}C at maximum. 4 figs.

  7. Technological development for super-high efficiency solar cells. Survey on the commercialization on analysis; Chokokoritsu taiyo denchi no gijutsu kaihatsu. Jitsuyoka kaiseki ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Tatsuta, M. [New Energy and Industrial Technology Development Organization, Tokyo (Japan)

    1994-12-01

    This paper reports the survey results on analysis of super-high efficiency solar cells for practical use in fiscal 1994. (1) On the survey on crystalline compound solar cells, it was pointed out that the present study target is III-V compound semiconductor solar cell, and efficiencies of 36-39% are theoretically expected by use of two-junction cells. (2) On structure of super-high efficiency solar cells of 40%, selection of upper and lower cell materials for multi-junction cells, high-efficiency tandem Si solar cells, and the merit and possibility of light collection operation were surveyed, and their issues were discussed. (3) On physical properties of mixed crystalline semiconductors and characteristic evaluation of solar cells, impurities, trap center, minority carrier life, and applicability of supper lattice structure to high-efficiency solar cells were surveyed. (4) On fabrication technology of compound semiconductor solar cells, various problems of and approaches to electrode formation and antireflection film technologies, the meaning and issues of thin film substrate technology and continuous process, trial calculation of costs, safety, and resource problem were surveyed.

  8. Method for estimation of the spectral distribution that influence electric power of PV module; Taiyo denchi shutsuryoku ni eikyo wo ataeru bunko nissha bunpu no suiteiho

    Energy Technology Data Exchange (ETDEWEB)

    Yamagami, Y.; Tani, T. [Science University of Tokyo, Tokyo (Japan)

    1997-11-25

    A method was proposed for estimating the spectral distribution using air mass, precipitable water, and clear indexes which are generally obtainable, and a comparative study was made between the spectral distribution obtained by this method and the measured data using output power of PV modules, etc. as indexes. When solar light comes into the atmosphere, it dissipates receiving scattering/absorption by various gases and aerosols. Direct light component and scattered light component which arrive at the earth surface become functions of air mass and precipitable water. The wavelength distribution of scattered light in cloudy sky is not dependent upon air mass, but affected strongly by absorption band by steam of clouds. By relational equations considered of these, output power and short-circuit current of PV modules are obtained to make a comparison with the measured data. As a result, it was found that this method estimated the spectral distribution with accuracy. Further, seasonal changes in the spectral distribution were well reproduced. The simulation of the module output in Sapporo and Okinawa brought a result that the output in Okinawa is 1.93% larger than in Okinawa. 5 refs., 5 figs., 6 tabs.

  9. Analysis of output characteristics of PV modules under natural sunlight; Shizen taiyokoka ni okeru taiyo denchi module shutsuryoku tokusei no kaiseki

    Energy Technology Data Exchange (ETDEWEB)

    Murai, Y.; Igari, S. [Japan Quality Assurance of Organization, Tokyo (Japan)

    1997-11-25

    The paper measured current/voltage characteristics of various PV modules under natural light and analyzed various characteristics such as generated output and module power generation efficiency. In the experiment, installing various PV modules at the solar techno center located at north latitude 34.7deg and east longitude 137.6deg, measurement was made by I-V curve tracer, pyranometer, and thermocouple buried on the module back. As a result, the following were confirmed: As to the monthly mean power generation efficiency, the crystalline system is lowest in summer and highest in winter, and the amorphous system highest in summer and lowest in winter. Concerning the power generation efficiency and illuminance, the gap of power generation efficiency between at high illuminance and at low illuminance is large in the crystalline system and small in amorphous system. Relating to the azimuth angle of module installation and the generated output, the installation inclined 15deg angle west in summer and 15deg angle east in fall/winter generates more power in the crystalline system. On the contrary, the installation on the south face generates more power in the amorphous system. 4 refs., 8 figs., 3 tabs.

  10. Study on the best utilization of solar energy. Experimental study of hydrogen generation by water electrolysis using solar battery; Taiyo energy no yuko riyo ni kansuru kenkyu. Taiyo denchi riyosui denki bunkai suiso hassei field test

    Energy Technology Data Exchange (ETDEWEB)

    Kawashima, Y.; Murai, K.; Nakai, T. [Himeji Institute of Technology, Hyogo (Japan)

    1997-11-25

    Shortcomings of solar energy are that it is subject to weather and is not available in the nighttime. The weak points may be effectively made up for when solar energy collected on a fine day is stored in the form of hydrogen energy for recovery as required. In this report, power generated by solar cells is used for the electrolysis of water for the generation of hydrogen. The amounts of the thus-generated hydrogen and hydrogen energy are determined and, on the basis of the measured amount of insolation, the solar energy availability rate (hydrogen conversion performance) is calculated. The amount of hydrogen generated in fiscal 1996 is also calculated for every month. The hydrogen generation level is quite low in the TiO2 wet type solar cell, approximately 0.2% at most. The current efficiency is fairly high in hydrogen generation using electrolysis, which is approximately 96-97%. The efficiency is higher when several units of electrolyte are connected in series until the solar cell optimum voltage is attained. A linear relationship is found between the daily summation of insolation and the amount of hydrogen generated. 1 ref., 7 figs., 2 tabs.

  11. System approach on solar hydrogen generation and the gas utilization; Taiyo energy ni yoru suiso no seisei oyobi sono riyo system ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Fujii, I.; Hirooka, N.; Deguchi, Y.; Narita, D. [Meiji University, Tokyo (Japan)

    1997-11-25

    An apparatus is developed to establish a system which allows utilization of hydrogen safely and easily, and its applicability to a hydrogen system for domestic purposes is tested. The system converts solar energy by the photovoltaic cell unit into power, which is used to generate hydrogen by electrolysis of water at the hydrogen generator, stores hydrogen in a metal hydride , and sends stored hydrogen to the burner and fuel cell units. It is found that a hydrogen occluding alloy of LaNi4.8Al0.2 stores hydrogen to approximately 80% when cooled to 20 to 25degC, and releases it to 10% when heated to 40degC. The fuel cell uses a solid polymer as the electrolyte. The hydrogen gas burner is a catalytic combustion burner with a Pt catalyst carried by expanded Ni-Al alloy. The optimum distance between the burner and object to be heated is 22mm. High safety and fabrication simplicity are confirmed for use for domestic purposes. The system characteristics will be further investigated. 4 refs., 8 figs.

  12. Valuation of the quantity of electric output from photovoltaic generation system in case of PV module applied to installing to vertical direction; Taiyo denchi wo suichoku ni haichishita baai no hatsudenryo hyoka

    Energy Technology Data Exchange (ETDEWEB)

    Miyajima, K. [Kansai Electric Power Co. Inc., Osaka (Japan)

    1996-10-27

    In general, it is most efficient and economical to install photovoltaic (PV) modules with proper slope. There are room spaces on the wall except ground or roof. The PV modules were installed on the vertical wall, to consider the compensative method for this weak point. When modules were installed vertically, there is an advantage that reflecting solar light as well as incident solar light can be utilized compared with the installation with slope. The PV modules were installed on the roof of building with inclination of 90{degree} facing to south using the roof material as a reflecting material (S90), and with inclination of 15{degree} facing to south (S15), to compare their output. The output ratio, S90/S15 was 0.42. When it was very fine, this value increased to 0.60. When using plated steel plate as the reflecting material, this value increased to 0.74, which provided 10 to 30% larger output than the roof material. From these results, about 50% of module output of S15 can be expected for S90. If receiving larger reflection, there would only a slight difference in the module output between S15 and S90. 3 figs., 1 tab.

  13. Changes of the temperature coefficients of the characteristics which accompany degradation and recovery of a-Si solar cells; A-Si taiyo denchi no hikari (denryu) rekka oyobi kaifuku ni tomonau tokusei ondo keisu no henka

    Energy Technology Data Exchange (ETDEWEB)

    Yanagisawa, T.; Koyanagi, T.; Nakamura, K.; Takahisa, K.; Kojima, T. [electrotechnical Laboratory, Tsukuba (Japan)

    1996-10-27

    Pursuant to the measuring of temperature dependency of the characteristics such as conversion efficiency, during the process of degradation in a-Si solar cells due to light and electric current and the process of recovery by annealing, this paper describes changes in temperature coefficients, correlation between the characteristic parameters and the degradation, and the results of the examination of their characteristics. The conversion efficiency {mu} degraded approximately by 45% of the initial value each by the irradiation under a light intensity with 3 SUN accelerated and by the infusion of current at 20mA/cm{sup 2}; and then, the efficiency recovered to 70-75% of the degradation by subsequent annealing. In addition, in the temperature dependency at 80{degree}C against at 20{degree}C, Isc slightly increased while Vcc greatly decreased. This slight increase in Isc was mainly due to the decrease in the width of the forbidden band, while the decrease in Vcc was due to the increase in the reverse saturation current. The temperature dependency of {mu}N was negative, becoming small in accordance with the degradation. The temperature dependency of FF/FFO was negative initially both in light and current, but it decreased with the degradation and turned to positive. The temperature coefficients of I-V parameters reversibly changed corresponding to the degradation and recovery of these parameters and stayed in a good correlation. 7 refs., 8 figs., 1 tab.

  14. Simulation of power generating characteristics of a large PV array consisting of plural sub-arrays with different inclination and orientation; Taiyo denchi wo fukusuu no houikaku, oyobi keishakaku ni secchi shita taiyoko hatsuden arei no shumireshon

    Energy Technology Data Exchange (ETDEWEB)

    Matsukawa, H.; Kurokawa, K. [Tokyo University of Agriculture and Technology, Tokyo (Japan); Nakamura, H.; Sugiura, T. [Japan Quality Assurance Organization, Tokyo (Japan); Ishikawa, N. [Daido Hoxan Inc., Osaka (Japan)

    1998-12-05

    The electrical outputs from plural sub arrays with different inclination and orientation differs each other. In such cases, total array characteristics may give a large amount of mismatch losses. For estimating these losses, a basic method of calculation has been proposed by synthesizing some I-V curves. The curves are specified by such parameters as radiation, ambient temperature, wind direction, wind speed, position of the system and so on. A total plan of this work is also suggested in this paper. (author)

  15. Research on fabrication technology for thin film solar cells for practical use. Survey on the commercialization analysis; Usumaku taiyo denchi seizo gijutsu no jitsuyoka kenkyu. Jitsuyoka kaiseki ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Tatsuta, M. [New Energy and Industrial Technology Development Organization, Tokyo (Japan)

    1994-12-01

    This paper reports the survey results on the technological trend, safety and latest technologies of thin film solar cells in fiscal 1994. As the fabrication technology for amorphous film solar cells, three-electrode plasma CVD was surveyed as fabrication method for high-mobility materials, and hydrogen radical CVD as fabrication method for high-photostable films. Current foreign and domestic reliability tests were surveyed for reliability evaluation of solar cells. In order to ascertain the performance, efficiency, physical properties and optimum structure of polycrystalline Si thin film solar cells, previously reported test results on physical properties such as carrier concentration, carrier lifetime and mobility of films were surveyed together with device simulation results. In addition, technologies for high-efficiency CuInSe2 system and CdTe system solar cells, technologies for cost reduction and mass production, and environmental influence were surveyed. Estimation of production costs for cell modules, and safety of thin film solar cells were also surveyed.

  16. Development of technology for thin substrate polycrystalline solar cells for practical use. Survey on analysis for practical use; Usugata takessho taiyo denchi seizo gijutsu no jitsuyoka kenkyu. Jitsuyoka kaiseki ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Tatsuta, M. [New Energy and Industrial Technology Development Organization, Tokyo (Japan)

    1994-12-01

    This paper reports the survey results on the manufacturing technology trend of thin substrate solar cells for practical use in fiscal 1994. In production of Si raw material, as electron beam melting and ingot production are combined, C, P, Ca and Al are removed by evaporation, while Fe and Ti by solidifying segregation. As the basic technology of continuous casting for substrate production, a drop coagulation method for Si melt is under investigation which is more advantageous in unidirectional solidification and cell conversion efficiency than conventional methods. The cost and future of single crystal Si and polycrystal Si were compared on the basis of document survey. Every institute commonly uses FZ substrates to produce single crystal Si cells, and SiO2 for surface passivation. New cell structure, hetero-structure, thin cell, crystalline defect and lifetime are under investigation for ultrahigh-efficiency solar cells. The technology trend was also surveyed through academic societies and conferences. 5 tabs.

  17. Change of the equivalent circuit constants accompanied by the degradation and recovery of efficiency on a-Si solar cells; A-Si taiyo denchi no koritsu no rekka to kaifuku ni tomonau toka kairo teisu no henka

    Energy Technology Data Exchange (ETDEWEB)

    Takahisa, K.; Kojima, T.; Nakamura, K.; Koyanagi, T.; Yanagisawa, T. [Electrotechnical Laboratory, Tsukuba (Japan)

    1997-11-25

    Investigations were given on how the equivalent circuit constants change when efficiency of amorphous silicon solar cells changes with time in light degradation and temperature recovery. In the experiment, light irradiation tests under a constant temperature and light intensity condition, followed by recovery tests under a constant temperature and constant weak light intensity or constant temperature condition were repeated continuously. According to the result of an experiment on single layer type cells, the change in each equivalent circuit constant in association with degradation in efficiency and file factor and variation in recovery is reversible mostly. However, a slightly irreversible component was recognized only in the initial degradation process in series resistance and diode factor values. With regard to stacked cells, it was suggested that the main players to determine cell characteristics during the processes of deterioration and recovery take turns among the three layers as follows: the shape of the time-based change in the efficiency comes different and is not saturating; as the efficiency decreases, the extent of the change increases in the diode factor and series resistance; and the path the deterioration takes differs from that the recovery takes. 2 refs., 12 figs.

  18. Fiscal 1999 research and development of technologies for practical application of photovoltaic power generation systems. Development of ultrahigh-efficiency crystalline compound solar cell manufacturing technology (Survey of peripheral element technologies - Survey of environmental adaptation of next-generation solar cell development); 1999 nendo taiyoko hatsuden system jitsuyoka gijutsu kaihatsu seika hokokusho. Chokokoritsu kessho kagobutsu taiyo denchi no seizo gijutsu kaihatsu (shuhen yoso gijutsu ni kansuru chosa kenkyu - jisedai taiyo denchi kaihatsu kankyo tekioka chosa)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    Surveys are conducted of photovoltaic power system development projects and their utilization in Japan and overseas, and a discussion is made on the progress, technical challenges, effects, and implementation systems relating to the solar cell application technology development project under the New Sunshine Program. Compiled in the report are the results of surveys of the research and development of photovoltaic power systems and their diffusion in the U.S. and European nations, and the research and development strategies for and the trends of the development of various types of solar cells in these countries. The trends of research and development of non-conventional type solar cells are also collected, which include 3 cases of TPV (thermophotovoltaic) devices, 5 cases of new inorganic materials, 1 case of new organic materials, and 4 cases of dye-sensitized solar cells. In relation to the status of resources of crystalline compound-based solar cell materials, raw materials for solar cells other than silicon are taken up, and their reserves, manufacturing methods, quantities yielded and consumed, costs, etc., are surveyed. These are all taken into consideration in discussing the basic approach to the study of future research and development as it ought to be. (NEDO)

  19. Production method of thin film solar cell; Hakumaku taiyo denchi no seizo hoho

    Energy Technology Data Exchange (ETDEWEB)

    Oki, K.; Watanabe, T.; Matsui, M.

    1996-01-23

    This invention relates to the film formation of chalcopyrite type compound semiconductor used for thin film solar cell. In the case of CuInS2 thin film, heteromorphic phases such as CuIn5S8, Cu2S, and In2S3 are formed on the top surface together with the CuInS2 phase, resulting in the decrease in junction property when n-type semiconductor layer such as CdS layer is formed on it. According to the invention, p-type semiconductor layer made of chalcopyrite type compound semiconductor is dipped into an ammonia water before being laminated with n-type semiconductor layer. Although higher concentration and higher temperature of the ammonia water accelerates the heteromorphic phase film removal velocity, it also gives rise to higher evaporation rate of ammonia. The preferable concentration and temperature are, therefore, 0.01 - 50% and 5 - 80{degree}C, respectively. In this way, the chalcopyrite type compound semiconductor thin film free from heteromorphic phases on its surface can be produced. The thin film solar cell produced by using such thin film has a high conversion efficiency because of a good junction property with n-type semiconductor. 1 fig.

  20. Thin film solar cell and its production method; Hakumaku taiyo denchi oyobi sono seiho

    Energy Technology Data Exchange (ETDEWEB)

    Yokoyama, H.; Yamamoto, K.; Mishima, T.; Matsuda, T. [Daido Hokusan Co. Ltd., Osaka (Japan). Sakai Lab.

    1997-01-17

    An attempt has been made to replace the single crystal silicon substrate for other inexpensive substrate coated with Si thin film for cost saving in the silicon solar cell production. It was found, however, a big difference in thermal expansion coefficient between the substrate and Si brought about a big warp of the substrate when the Si film was made thick enough for solar cell use. This invention solves the problem. The Si thin film is grown through a mask having many holes with constant interval instead of being grown as a continuous layer. The Si film is, therefore, formed in island structure which rises from many holes. The island structure crystals exist, being separated from each other. They consist of discontinuous points. So that they can expand thermally in accordance with the thermal expansion of the substrate. Even if there is a difference in thermal expansion between the inexpensive substrate and Si crystal film, little warp takes place in the laminate. 8 figs.

  1. Evaluation of PV modules integrated with roofing materials; Kenzai ittaigata taiyo denchi module no hyoka

    Energy Technology Data Exchange (ETDEWEB)

    Morizane, M.; Yagiura, T.; Nakashima, S.; Yagi, H.; Murata, K.; Uchihashi, K.; Tsuda, S.; Nakano, S. [Sanyo Electric Co. Ltd., Osaka (Japan); Ito, M.; Kurimoto, T.; Yamakawa, H.; Fujiwara, T. [Kubota Corp., Osaka (Japan)

    1997-11-25

    PV modules unified with building materials which are low in cost, easy to install and excellent in designing were developed and were evaluated in various tests. As to the basic structure of this module, seamless and unified construction with the back metal plate was adopted considering improvement in fire prevention and cost reduction. About the installation, module is easy to install by just fit connection with the frame, and easy to remove with no use of special tools. Concerning intensity and durability requested for this module, tests on reliability such as torsion strength and wind pressure resistance were conducted according to JIS standards, and it was confirmed that there were no problems. Also on the long-term durability, tests on long-term reliability were carried out by doubling test terms of the temperature/humidity cycle test, salt water resistance test, etc., and the reliability the same as that of the existing type was confirmed. In the verification test using a model house, no changes were seen in electrical characteristics and appearance, and waterproof was also favorable one and a half year after the installation. 4 refs., 7 figs., 5 tabs.

  2. Change of environmental factors in different site which effect the conversion efficiency of photovoltaic module. Comparison of the environmental factors in Shinjuku Tokyo with the one in Chino Nagano; Kotonaru chiten ni okeru taiyo denchi no henkan koritsu ni eikyo wo ataeru kankyo inshi no henka. Tokyoto Shinjukuku to Naganoken Chinoshi no kankyo inshi no hikaku

    Energy Technology Data Exchange (ETDEWEB)

    Higuchi, T.; Tani, T.; Hirata, Y.; Inasaka, T. [Science University of Tokyo, Tokyo (Japan)

    1997-11-25

    Environmental factors affecting conversion efficiency of solar cells were measured in Tokyo and Nagano to comparatively study the difference. In the study, measurement was made of intensity of global solar radiation on an inclined surface (insolation intensity), ambient air temperature, and distribution of spectral solar radiation at the two points. Also measured were output characteristics of polycrystal silicon solar cell modules and amorphous silicon solar cell modules. The result of the comparative analysis was as follows: The annual inclined global solar radiation amount integrated in 1996 is 27% more in Nagano than in Tokyo. The weighted average insolation intensity in Nagano is 0.09 kW/m{sup 2} higher in Tokyo. The weighted average cell temperature in Nagano is 4degC lower than in Tokyo. The effective spectral ratio in Nagano is 1-2% lower both in polycrystal Si and amorphous Si than in Tokyo. Thus, it was inferred from that environmental factors are different that conversion efficiencies of photovoltaic modules were different. 6 refs., 5 figs., 5 tabs.

  3. Forced-circulation solar water heater using a solar battery; Taiyo denchi wo mochiita kyosei junkanshiki taiyonetsu onsuiki

    Energy Technology Data Exchange (ETDEWEB)

    Asai, S.; Mizuno, T. [Yazaki Resources Co. Ltd., Shizuoka (Japan)

    1996-10-27

    For the purpose of satisfying demands for qualitative improvement on tapwater temperature and pressure, an indirect-type solar water heater using solar cells, in which a closed type hot water storage tank connected directly to the water supply is integrated with a solar collector, was examined for its characteristics and performance. The heat collecting medium is a water solution of polypropylene glycol, which circulates through the solar collector pump, cistern, solar collector, and heat exchanger (hot water storage tank). The results of the test are summarized below. When comparison is made between the two solar collector pump control methods, the solar cells direct connection method and the differential thermo method utilizing temperature difference between the solar collector and the hot water storage tank, they are alike in collecting heat on clear days, but on cloudy days the latter collects 5% more than the former. In winter, when the heat exchanger heat transfer area is 0.4m{sup 2} large, a further increase in the area improves but a little the heat collecting efficiency. An increase in the medium flow rate and temperature, or in the Reynolds number, enhances the heat collecting efficiency. 13 figs., 6 tabs.

  4. Resin composite for sealing and its use in a solar cell. Fushiyo jushi soseibutsu oyobi sore wo mochiita taiyo denchi

    Energy Technology Data Exchange (ETDEWEB)

    Toma, H.; Mimura, T.; Takehara, N.

    1994-01-28

    This invention presents resin composites for sealing of a solar cell composed of a hardening resin and a thermoplastic resin which has a number average molecular weight larger than that of the hardening resin and is soluble in the hardening resin, and the invention affords a solar cell to endure a long-term stable operation and to give a good performance. The hardening resin includes unsaturated polyester resin, phenolic resin, alkyd resin, unsaturated acrylic resin, epoxy resin, polyurethane resin, melamine resin, diallyl phthalate resin, their oligomers and their modifications. The thermoplastic resin includes saturated polyester resin, phenolic resin, acrylic resin, styrene resin, epoxy resin, polyurethane resin, polyvinyl acetate resin, polyvinyl chloride resin, polyvinyl alcohol resin, polyacetal resin, their modifications and their copolymer resin. 2 figs., 3 tabs.

  5. Roof-mounted solar cell and method of mounting. Yane secchi gata taiyo denchi oyobi sono secchi hoho

    Energy Technology Data Exchange (ETDEWEB)

    Iwamoto, M.; Minami, K.; Yamaki, T. (Sanyo Electric Co. Ltd., Osaka (Japan))

    1991-09-02

    This invention provides a roof-mounted solar cell which can be readily installed on the existing roofs without impairing the roofs and excels in durability. In this invention, a solar cell panal is made by placing at least one solar cell module into a frame and this panel is mounted on a roof via a spacer in a freely movable arrangement. The frame and the material under the eaves are fixed by means of a wire. In addition, a roughly L-shaped clamp made of a shape memory alloy is fixed to the material under the eaves. This clamp and the frame of the solar cell panel can be fixed by means of a wire. At installation, a frame to assemble the solar cell module is mounted by means of a spacer in freely movable arrangement. After this frame is ficed to the part under the eave, the solar cell module is fixed into the frame body. Durability is improved because the vibration (e.g., of earthquakes) is mutually released through the frame, wires and the roofs, thus enhancing its durability. 12 figs., 1 tab.

  6. Influence of spectral solar radiation to the generating power of photovoltaic module; Taiyo denchi shutsuryoku eno taiyoko supekutoru eno eikyo

    Energy Technology Data Exchange (ETDEWEB)

    Minaki, S.; Ishihara, Y.; Todaka, T.; Harada, K. [Doshisha University, Kyoto (Japan); Oshiro, T.; Nakamura, H. [Japan quality Assurance Organization, Tokyo (Japan)

    1997-11-25

    As to the influence of spectral solar radiation to generating power of solar cells, a study was conducted from the aspects of season, time zone, intensity of solar radiation, etc. In the study, spectral responsive variation correction coefficients were introduced as evaluation values expressing the influence of spectral solar radiation. For the spectral distribution, an all sky spectral pyranometer by wavelength was used, and data were used which were obtained in the measurement in experimental facilities of the solar techno center. Concerning solar cell relative spectral sensitivity values, used were relative spectral sensitivity values of monocrystal and amorphous standard solar cells to the short-circuit current. Spectral response variation correction coefficients are coefficients correcting variations in conversion efficiency of solar cells due to changes in the spectral distribution. The changes of spectral responsive variation correction coefficients were studied using data obtained during April 1994 and March 1996. As a result, it was found that the coefficients showed large changes in summer and small ones in winter and that amorphous solar cells indicate this trend conspicuously. 3 refs., 6 figs., 3 tabs.

  7. Stabilized efficiency of stacked a-Si solar cell; Sekisogata a-Si taiyo denchi no anteika koritsu

    Energy Technology Data Exchange (ETDEWEB)

    Takahisa, K.; Kojima, T.; Nakamura, K.; Koyanagi, T.; Yanagisawa, T. [Electrotechnical Laboratory, Tsukuba (Japan)

    1997-11-25

    Different types of tests combining light and temperature were carried out in a laboratory on predicting long-term performance of stacked amorphous silicon solar cells. Cell terminals were left open, xenon was used as an irradiation light source, and cell temperature was controlled within {+-} 2 degC of the setting. The result of the experiment may be summarized as follows: with regard to the deterioration characteristics, the speed in which the efficiency changes reached a maximum within 10 hours, and thereafter the change has slowed down gradually in the case of temperature at 50 degC; in the case of 25 degC, the maximization is reached between 500 and 1000 hours; the stabilization efficiency turns out to be a pessimistic value according to the saturated value derived from an experimental expression, hence the value would have to be expressed by specifying cell temperatures, light intensities and elapsed time; the minimum value of seasonal variation may be estimated at about 85% as a pessimistic value; for recovery characteristics, the saturated value for the recovery tends to become lower as the lower the value immediately before the recovery; and if the light intensity is varied, the deterioration characteristic shifts to that at an individual light intensity. 4 refs., 11 figs., 2 tabs.

  8. Forced-circulation solar water heater using a solar battery; Taiyo denchi wo mochiita kyosei junkahshiki taiyonetsu onsuiki

    Energy Technology Data Exchange (ETDEWEB)

    Asai, S.; Mizuno, T. [Yazaki Corp., Tokyo (Japan)

    1997-11-25

    Optimal operation control was discussed on a forced-circulation solar water heater using solar cells not only as the power supply of a heat collecting pump, but also for controlling operation of the heat collecting pump. With this system, when the amount of power generated by solar cells reaches a sufficient level for operating the heat collecting pump, the heat collecting pump starts operation, wherein the heat collecting medium circulates in the system. The discussion was given by using simulation based on experimental expressions such as the relation expression between insolation and heat collecting medium flow rate as derived from the result of the system`s heat collecting performance test. As a result, the following conclusions were obtained: optimal insolation for activating the discussed system is from 50 to 100 W/m {sup 2}, and the heat collected within this range is within -1.5% of the collected heat amount at an optimum value; optimal activating insolation for the case of 1000 to 2000 W/m {sup 2} with low daily cumulative insolation is from 0 to 50 W/m {sup 2}, whereas the optimal activating insolation amount increases as the daily cumulative insolation amount increases; and the optimal activating insolation amount increases as water to be supplied requires higher temperature. 1 ref., 17 figs., 2 tabs.

  9. Influence of angle of inclination on power of solar module; Taiyo denchi module no keisha kakudo to shutsuryoku tokusei

    Energy Technology Data Exchange (ETDEWEB)

    Tsutsumi, K.; Nishitani, M. [Dai Ichi University, College of Technology, Kagoshima (Japan)

    1997-11-25

    Experiment/study were conducted on the influence of angle of inclination on output of solar modules. In the experiment, changing the angle of inclination of the photovoltaic module installed on the top of school building to 0, 30, 60 and 90 degC, the global radiation on an inclined surface was measured by pyranometer equipped with the module, and at the same time output characteristics were measured by I-V curve tracer. In the I-V curve tracer, voltage, current, and output capability diagram are illustrated automatically changing bias voltage to get the maximum output. The global radiation on an inclined surface and the maximum output indicated an almost proportional relation and were expressed in a recursion method. Moreover, measurement of the global radiation is usually conducted using the amount of global radiation on a horizontal surface, and the global radiation on an inclined surface is calculated as a sum of the direct solar radiation amount and the sky solar radiation amount after determining a penetration rate by the relational equation. By calculating the global radiation on an inclined surface, it becomes possible to calculate the maximum output of photovoltaic modules by this recursion method. 1 ref., 6 figs., 1 tab.

  10. Method for estimation of the output electric power of PV module with considering environmental factors. Method for estimation of output using I-V curves; Kankyo inshi wo koryoshita taiyo denchi module no shutsuryoku keisanho. I-V tokusei curve ni yoru keisan

    Energy Technology Data Exchange (ETDEWEB)

    Yamagami, Y.; Tani, T. [Science University of Tokyo, Tokyo (Japan)

    1996-10-27

    Based on the basic quality equation of photovoltaic (PV) cell, a quality equation of PV module has been constructed by considering the spectral distribution of solar radiation and its intensity. A calculation method has been also proposed for determining the output from current-voltage (I-V) curves. Effectiveness of this method was examined by comparing calculated results and observed results. Amorphous Si (a-Si) and polycrystal Si PV modules were examined. By considering the environmental factors, differences of the annual output between the calculated and observed values were reduced from 2.50% to 0.95% for the a-Si PV module, and from 2.52% to 1.24% for the polycrystal Si PV module, which resulted in the reduction more than 50%. For the a-Si PV module, the environmental factor most greatly affecting the annual output was the spectral distribution of solar radiation, which was 3.86 times as large as the cell temperature, and 1.04 times as large as the intensity of solar radiation. For the polycrystal PV module, the environmental factor most greatly affecting the annual output was the cell temperature, which was 7.05 times as large as the spectral distribution of solar radiation, and 1.74 times as large as the intensity of solar radiation. 6 refs., 4 figs., 1 tab.

  11. Improvement of the efficiency characteristics on the photovoltaic generation system based on a generation control circuit. Part 3. Research on architectural systematization of energy conversion devices; Dosaten seigyo kairo wo mochiita taiyo denchi hatsuden koritsu no kaizen. 3. Energy henkan no kenchiku system ka ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Shimizu, T.; Ito, N.; Kimura, G.; Fukao, S.; Sunaga, N.; Tsunoda, M.; Muro, K. [Tokyo Metropolitan University, Tokyo (Japan)

    1996-10-27

    In introducing a photovoltaic power generation system to urban homes, the general practice is to install a large number of solar cell panels on the roof. However, as is often the case, a part of the solar cell panels is in the shadows (partial shadows) of neighboring homes, electric poles, cables and trees. Under the circumstances, studies were made on the numerous changes in the lowered generating capacity of individual solar cells by the partial shadows. Developed by the authors were the generation point control principle, in which the generation point was individually controlled on serially connected plural solar cell modules, and a practical circuit system based on that principle with the effects verified in a field test. In the test, the generated power of the system was 476W without partial shadows, and was 323W with partial shadows and without the operation of the generation point control circuit, increasing to 406W with partial shadows and with the operation of the circuit. As a result, compared with the case where no generation point control circuit was employed, the effectiveness of the proposed circuit was evident. 3 refs., 10 figs., 1 tab.

  12. Achievement report for fiscal 1997 on developing a silicon manufacturing process with reduced energy consumption. Investigation and research on analyzing practical application of a technology to manufacture solar cell silicon raw materials; 1997 nendo energy shiyo gorika silicon seizo process kaihatsu. Taiyo denchi silicon genryo seizo gijutsu no jitsuyoka kaiseki ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    This paper describes the achievement in fiscal 1997 of analyzing practical application of a technology to manufacture solar cell silicon raw materials. Silicon consumption for solar cells in fiscal 1997 has increased to 2000-ton level, and the supply has been very tight. For drastic improvement in the demand and supply situation, development of SOG-Si manufacturing technology and its early practical application are desired. The development of the NEDO mass-production technology using melting and refining has completed constructing the process facilities in fiscal 1998, and will enter the stage of operational research. However, insufficiency in the basic data about behavior of impurities is inhibiting the development. In the substrate manufacturing technology, discussions have shown progress on use of diversifying silicons outside the standard by using the electromagnetic casting process. For slicing and processing the substrates, development of a high-performance slicing equipment and automatic rough rinsing machine is under way. Properties required on silicon raw materials vary considerably widely because of difference in cell making systems and conditions, which is attributable to unknown impurity behavior. When 1GW production is assumed, the cell module manufacturing cost is calculated as 137 yen/W, for which low-cost mass production for its realization, slicing productivity enhancement, and cost reduction are required. The paper also describes site surveys in overseas countries. (NEDO)

  13. Development of technology for thin substrate polycrystalline solar cells for practical use. Development of manufacturing technologies for low-cost substrates (low-cost Si sheets by continuous casting method); Usugata takessho taiyo denchi seizo gijutsu no jitsuyoka kenkyu. Tei cost kiban seizo gijutsu kaihatsu (renzoku cast ho ni yoru tei cost Si kiban seizo gijutsu kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    Tatsuta, M. [New Energy and Industrial Technology Development Organization, Tokyo (Japan)

    1994-12-01

    This paper reports the study results on manufacturing of low-cost Si substrates by continuous casting method in fiscal 1994. (1) On manufacturing of ingots of 16 piece size, the ingot of nearly 170kg was manufactured by batch process using the Si melt injection unit prepared in last year. (2) On oxygen and carbon contents in wafers, the contents were measured by FT-IR after slicing of the ingot. As a result, the oxygen and carbon contents could be successfully reduced to the targets of 10ppma and 5ppma or less, respectively. (3) The resistivity distribution of the ingot ranged over the target of 1-2ohm-cm. (4) Cells of 100 {times} 100mm{sup 2} wide and 350{mu}m thick were verified by in-house evaluation process. Although lower cell conversion efficiency was found at the center top of the ingot, a vertical efficiency stability was nearly sufficient as a whole. (5) On the crystal growth unit prepared in fiscal 1994, any problems were not found on automatic driving and vibration during moving. 8 figs.

  14. Research and development of system to utilize photovoltaic energy. Survey on the high-durability and low-cost materials for constructing the solar-cell module and its structure; Taiyoko hatsuden riyo system no kenkyu. Taiyo denchi module yo kotaikyusei tei cost zairyo, kozo ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    Tatsuta, M. [New Energy and Industrial Technology Development Organization, Tokyo (Japan)

    1994-12-01

    This paper reports the results obtained during fiscal 1994 on a survey on the high-durability and low-cost materials for constructing the solar-cell module and on its structure. With respect to forms and materials used in the present solar-cell modules, identification was made on the current status of products commercially available and developed inside and outside Japan. Main types of solar cells used for electric power are of crystal-based silicon. Amorphous silicon and CdS-CdTe are used for consumer applications of indoor and outdoor use. As regards transparent resin materials, fluorine resin, PET, acryl, and polyimide are used as surface materials, and EVA, silicon and PVB are often used as fillers. Developments inside and outside Japan are limited to systems of polycarbonate, methacryl, fluorine, polyurethane, acryl and polyester. Butyl rubber and polyurethane are used as sealing materials. Developments are being performed on silicon rubber, polychloroprene rubber and EPT rubber for shaped materials, and silicon systems, urethane systems and polysulfide systems for non-shaped materials. 3 figs., 8 tabs.

  15. Change of photovoltaic module conversion efficiency with the environmental factors in different site. Comparison of the conversion efficiency in Tokyo with the one in Nagano; Kotonaru chiten ni okeru taiyo denchi module no shutsuryoku tokusei no henka. Tokyoto Shinjukuku to Naganoken Chinoshi tono hikaku

    Energy Technology Data Exchange (ETDEWEB)

    Higuchi, T.; Tani, T.; Hirata, Y.; Inasaka, T. [Science University of Tokyo, Tokyo (Japan)

    1997-11-25

    Assuming that photovoltaic power systems were installed at two points, Shinjuku Tokyo and Chino Nagano, a study was conducted of difference in generated output of the systems caused by the difference in environmental factors. In the study, it was assumed that two of the photovoltaic power system with rated capacity of 3kW were installed at the two points, and the annual generated output was calculated and compared by the conventional method considering only cell temperature and the output estimation method considering intensity of solar radiation, cell temperature, and spectral distribution of solar radiation. The result of the study was as follows: the difference in output ratio at the two points was 1.7% or lower under the influence of intensity of solar radiation and cell temperature. On the other hand, under the influence of the distribution of spectral solar radiation, the difference is larger than under other environmental factors, 2.4% in polycrystalline Si and 5.5% in amorphous Si. The generated output estimated by the conventional method and the spectral method produced a difference between 81 kWh in Tokyo and 258 kWh in Nagano in amorphous Si. This is because environmental factors such as intensity of solar radiation and distribution of spectral solar radiation are different between the two points. 1 ref., 2 figs., 3 tabs.

  16. Technological development for super-high efficiency solar cells. Technological development for crystalline compound solar cells (high-efficiency III-V tandem solar cells); Chokokoritsu taiyo denchi no gijutsu kaihatsu. Kessho kagobutsu taiyo denchi no gijutsu kaihatsu (III-V zoku kagobutsu handotai taiyo denchi no gijutsu kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    Tatsuta, M. [New Energy and Industrial Technology Development Organization, Tokyo (Japan)

    1994-12-01

    This paper reports the study results on technological development of III-V compound semiconductor solar cells in fiscal 1994. (1) On development of epitaxial growth technology of lattice mismatching systems, the optimum structure of InGaAs strain intermediate layers was studied for reducing a dislocation density by lattice mismatching of GaAs layer grown on Si substrate and difference in thermal expansion coefficient. The effect of strain layer on dislocation reduction was found only at 250dyne/cm in strain energy. Growth of GaAs layers on the Si substrate treated by hydrofluoric acid at low temperature was attempted by MBE method. As a dislocation distribution was controlled by laying different atoms at hetero-interface, the dislocation density of growing layer surfaces decreased by concentration of dislocation at hetero-interface. (2) On development of high-efficiency tandem cell structure, tunnel junction characteristics, cell formation process and optimum design method of lattice matching tandem cells were studied, while thin film cell formation was basically studied for lattice mismatching tandem cells. 45 figs., 8 tabs.

  17. Technological development for super-high efficiency solar cells. Technological development for super-high efficiency singlecrystalline silicon solar cells (super-high efficiency singlecrystalline Si solar cells); Chokokoritsu taiyo denchi no gijutsu kaihatsu. Chokokoritsu tankessho silicon taiyo denchi no gijutsu kaihatsu (chokokoritsu tankessho silicon taiyo denchi cell no gijutsu kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    Tatsuta, M. [New Energy and Industrial Technology Development Organization, Tokyo (Japan)

    1994-12-01

    This paper reports the study results on technological development of super-high efficiency singlecrystalline silicon solar cells in fiscal 1994. (1) On development of high-performance light receiving layer, the fine electrode for receiving surfaces was designed to reduce serial resistance, and the high-quality oxide passivation film was studied to reduce surface recombination velocity. (2) On development of forming technology of back heterojunction, the high-quality cell with B-doped fine crystalline Si film on its back was studied by heat treatment of the fine crystalline Si film, and the cell structure with high back reflectance of light was also studied. (3) On analysis for high-efficiency cells, the relation between the back recombination velocity at the interface between p-type substrate and back passivation film, and the internal collection efficiency as probe light was injected from the back, was calculated by numerical simulation. As a result, the cell back recombination velocity could be evaluated by measuring the spectral internal collection efficiency to back injection. 15 figs., 6 tabs.

  18. Technological development for super-high efficiency solar cells. Technological development for crystalline compound solar cells (research and development of composite materials on solar cells under microgravity environment); Chokokoritsu taiyo denchi no gijutsu kaihatsu. Kessho kagobutsu taiyo denchi no gijutsu kaihatsu (bisho juryoku kankyo wo riyoshita taiyo denchiyo zairyo kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    Tatsuta, M. [New Energy and Industrial Technology Development Organization, Tokyo (Japan)

    1994-12-01

    This paper reports the study results on development of composite materials for solar cells under microgravity environment in fiscal 1994. (1) On a thin film capillary method, 26 experiments of GaSb thin film crystal growth were conducted using the especially prepared high-accuracy electric furnace under microgravity. The wettability of thin film crystals was improved by refining equipment. Rhombus crystal planes and large crystal grains were observed in GaSb thin film crystals prepared under microgravity. (2) On a liquid phase method, the effect of the gravity on crystal structure and grain morphology was studied for synthesis of CdS fine grains. (3) On technological development of composite materials, the solidification experiment of Cu-In-Se melt was conducted under short time microgravity of 10{sup -4}g for 10 sec. As a result, more uniform texture and more high crystallinity were obtained under microgravity, and In in melt was concentrated by surface tension effect. It was suggested that high-quality CIS thin films will be obtained by Se doping into Cu-In composite films under microgravity environment.

  19. New Sunshine Program for fiscal 2000. Development of photovoltaic power system commercialization technology (Development of ultrahigh-efficiency crystalline compound solar cell manufacturing technology - Surveys and studies of peripheral key technologies/Surveys of environmentally-friendliness enhancement for next-generation solar cell development); 2000 nendo New sunshine keikaku seika hokokusho. Taiyoko hatsuden system jitsuyoka gijutsu kaihatsu - Chokokoritsu kessho kagobutsu taiyo denchi no seizo gijutsu kaihatsu (Shuhen yoso gijutsu ni kansuru kenkyu chosa, Jisedai taiyodenchi kaihatsu kankyo tekioka chosa)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    Though the trends of solar cell development are becoming increasingly diverse across the world, yet none has emerged to promise a stable solar cell supply in the future. Under the circumstances, studies were conducted to clarify strategies for solar cell technology development which would be well adapted to Japan's social environments, with the trends of development in the United States and European countries taken into consideration. The surveys covered the research and development and diffusion of photovoltaic power generation in the United States and European countries, and their solar cell research and development strategies and trends of development were put together. Surveys were also conducted into the research and development of unconventional types of solar cells, such as the dye-sensitized solar cell, organic solar cell, conjugate polymer solar cell, and the polymer/C{sub 60} based solar cell, and into the status of resources of materials for solar cells such as gallium, arsenic, cadmium, tellurium, indium, selenium, and germanium. Regarding the future of photovoltaic power generation research and development, it was concluded that commercialization technology development and basic research and development should continue. Also pointed out was the importance of the enlargement of the market for photovoltaic power generation systems. (NEDO)

  20. Analysis and evaluation for practical application of photovoltaic power generation system. Analysis and evaluation for thin substrate polycrystalline solar cells (alloy-base amorphous materials, PIN layers, strains in the interface, and effects of impurities); Taiyoko hatsuden system jitsuyoka no tame no kaiseki hyoka. Usumaku taiyo denchi jitsuyoka no tame no kaiseki hyoka (gokinkei amorphous zairyo pin kakuso kaimen ni okeru yugami fujunbutsu nado no eikyo)

    Energy Technology Data Exchange (ETDEWEB)

    Matsuda, A.; Oeda, H.; Yamasaki, S.; Hata, N.; Kondo, M.; Toshima, Y.; Sakata, I.; Ganguly, G.; Suzuki, A.; Kamei, T.; Okushi, H.; Nonaka, H.; Oda, N.; Katagiri, H.; Ichimura, N.; Kokubu, K.; Nakamura, K.; Sekikawa, T.; Yamanaka, M. [Electrotechnical Laboratory, Tsukuba (Japan)

    1994-12-01

    Described herein are the results of the FY1994 research program for analysis and evaluation for thin film solar cells. The study on quantitative analysis of hydrogen atoms in a plasma determines quantity of hydrogen atoms in the plasma of monosilane diluted with hydrogen. It is found, contrary to expectation, that quantity of hydrogen atoms in the plasma decreases as it is more diluted with hydrogen. The study on light-induced degradation of the thin chlorine-base amorphous silicon films confirms that the plasma CVD method with 20% of dichlorosilane gas added to monosilane gas produces the thin amorphous silicon film 3 times faster than the conventional method. The thin film has essentially the same defect density as the one prepared by the conventional method, showing good photoelectric characteristics. The thin film of chlorinated amorphous silicon has a 1 digit lower defect density than the conventional one of amorphous silicon, as revealed by the accelerated degradation test with irradiated laser light and the constant current method to determine saturated defect density. 3 figs.

  1. 29th Solar Energy Promotion Committee Meeting - 4th Solar Cell Liaison Meeting. (Report for fiscal 1991); Dai 29 kai taiyo energy suisuin iinkai dai 4 kai taiyo denchi renrakukai. 1991 nendo hokoku

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1992-04-21

    The above-named events took place in Tokyo in the period of April 21-24, 1992, and a total of 55 essays were presented. Presented in the session of the thin-film/a-Si systems were 27 essays, which were 'Light-induced degradation and its mechanism in a-Si:H and its multilayers,' 'Light-induced ESR (electron spin resonance) in a-Si{sub 1-x}N{sub x}:H,' 'Distribution of hydrogen surrounding light-induced defects,' 'Equilibration temperature and hydrogen diffusion in a-Si:H,' etc. Presented in the session of the thin-film compound systems were 6 essays, which were 'Local structure studies of CuInSe{sub 2} thin films,' 'Characterization of CuInSe{sub 2} bilayer films fabricated by ICB (ionized cluster beam) techniques,' etc. Presented in the session of the crystal compound systems were 7 essays, which were 'heteroepitaxy of In{sub x}Ga{sub 1-x}As/GaAs,' 'cell efficiency calculation for optimization of cell structure,' etc. Presented in the session of the crystal/Si systems were 15 essays which were 'Preparation of textured AR film,' 'Development of amorphous/thin film polycrystalline silicon tandem cell,' 'Development of high efficiency polycrystalline silicon thin-film solar cells,' 'Production of SOG (spin on glass)-Si from metallic grade silicon,' etc. (NEDO)

  2. 32nd Solar Energy Promotion Committee Meeting - 7th Solar Cell Liaison Meeting. Report for fiscal 1994; Dai 32 kai taiyo energy suishin iinkai dai 7 kai taiyo denchi renrakukai (1994 nendo hokoku)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-04-24

    The above-named events were convened in the period of April 24-27, 1995, when a total of 77 presentations were given on research achievements. In the session on thin type Si polycrystalline systems, 12 essays were presented concerning the thermodynamics of phosphorus and titanium in silicon, etc. In addition, a discussion was held on the 'Technological tasks remaining to be discharged toward industrialization.' In the session on thin film polycrystalline silicon systems, 5 essays were presented and 'Technological tasks related to thin film polycrystalline silicon solar cell' was discussed. In the session on ultrahigh efficiency Si systems, 5 essays were presented and 'Tasks related to the development of ultrahigh frequency single crystal Si solar cell' was discussed. At the symposium, 'Adoption of new energy to be accelerated following the formulation of the New Energy Introduction Guidelines' and 'Outlook for thin film solar cell practical application' were taken up. Various essays were presented and a discussion was held in each of the other sessions on ultrahigh efficiency III-V group systems, thin film chalcopyrite/II-VI group systems, international collaboration, matters related to systems, and thin film a-Si systems. (NEDO)

  3. 31st Solar Energy Promotion Committee Meeting - 6th Solar Cell Liaison Meeting. Report for fiscal 1993; Dai 31 kai taiyo energy suishin iinkai dai 6 kai taiyo denchi renrakukai (1993 nendo hokoku)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-04-25

    The above-named events were convened in the period of April 25-28, 1994, when a total of 71 presentations were given on research achievements. Presented in the session on thin film systems were 21 essays concerning the low cost manufacturing technology of low-area modules, development of film substrate a-Si solar cells, etc. Discussed at the symposium were the 'Autonomous development of photovoltaic power generation' and 'Practical application and research and development.' Presented in the session on crystalline Si systems were 17 essays concerning real-time observation of epitaxial growth using STM (scanning tunneling microscope), research on single crystal silicon manufacturing technology, etc. Discussed in the session on international cooperation was 'How international joint research should be.' Presented in the session on systems were 11 essays including the research and development of photovoltaic modules integrated with construction materials. Presented in the session on III-V group systems were 7 essays including the development of crystallized compound solar cell technology. Presented in the session on chalcopyrite II-VI group systems were 9 essays including the development of large area CdS/CdTe solar cell. (NEDO)

  4. Development of measurement device for evaluation of solar cell module output. 2; Taiyo denchi module shutsuryoku hyokayo sokuteiki no kaihatsu. 2

    Energy Technology Data Exchange (ETDEWEB)

    Minoda, M.; Itsumi, J. [Kumamoto Institute of Technology, Kumamoto (Japan)

    1996-10-27

    Enhancement in design efficiency may be attained as well as utilization in maintenance if on-the-spot data is made available, for the purpose of flexibly dealing with changes in design or matching with a house structure, in calculating the power generation output of a solar cell (PV) module. Under the circumstances, a small-sized compound measuring device was produced as a prototype which, using an I-V curve tracer, measured output and condition of a roof at the time of installation, compared with the optimum operation and predicted the power generation. The device was structured with the main body consisting of a computing part, measurement controller and power supply and with various sensor modules. The electron load control method was employed in order to measure I-V characteristics of the PV module, since it was desirable to use a variable load and to cover the range from the release voltage of a solar cell to the short-circuit state through the maximum output point. The reference module method was used for the system evaluation. The device was presumably applicable to a PV system design by incorporating a sensor module for measuring design environment data, which was essential at the time of a system design, in addition to those for measuring output. 9 refs., 4 figs., 3 tabs.

  5. Indirect solar-pumped laser diode using a solar cell; Taiyo denchi wo mochiita taiyoko kansetsu reikigata handotai laser no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Kanamori, Y.; Yugami, H.; Naito, H.; Arashi, H. [Tohoku University, Sendai (Japan). Faculty of Engineering

    1996-10-27

    This paper describes the operating characteristics of a stabilizing circuit using commercial electricity, those of a stabilizing circuit using solar cells, relation between the quantity of solar radiation and the maximum output of a semiconductor laser diode (LD), and simulation results of annual LD output in Sendai City. The stabilizing circuit for the solar-cell driven LD was structured such that the output of the solar cell panels was guided to a DC/DC converter, that the voltage was set at a prescribed value and that the current was stabilized with the use of power MOSFET. The solar cells used in the experiment were monocrystal silicone solar cells with the maximum output of 53W each. In the experiment, the LD was protected by stabilizing the current at a set value when an excess current was supplied to the stabilizing circuit. As a result of the simulation of the annual LD output from the meteorological data of Sendai City, it was predicted that a solar cell of approximately 1kW was able to provide an annual output of 102MJ and that the efficiency was highest with four sheets of the solar cell. Consequently, consistency proved to be essential between the LD and the solar cell output. 3 refs., 7 figs.

  6. Control method for light deterioration of amorphous solar cell. Temperature effect method; Amorphous taiyo denchi no hikari rekka yokuseiho. Ondo kokaho

    Energy Technology Data Exchange (ETDEWEB)

    Fujimoto, H.; Yokoyama, S.; Itsumi, J. [Kumamoto Institute of Technology, Kumamoto (Japan)

    1996-10-27

    This paper describes a proposed method for suppressing light deterioration (temperature effect method), in which an annealing effect was always expected by laminating an NEM element and a heat insulation material on the back side of a-Si solar cell module and thereby raising the temperature in the back side of the module, and also describes an outdoor exposure test device completed for the method. The NEM element consisted of conductive potassium titanate and high molecular polymer and was a self temperature-controlling organic exothermic body that required no outside temperature control device. It was provided with a heat generating temperature of 45-75{degree}C as the exothermic property of the element and capable of generating heating temperature arbitrarily according to the purpose. The NEM element varied a resistance value against the ambient temperature and kept the element temperature constant. Measurement was commenced starting April 19, 1996, using the completed outdoor exposure test device and a measuring circuit. The deterioration phenomenon was and from then on continuously examined under the following conditions: (1) measurements were those of clear days only, and (2) measurements to be used were those between 10:00 and 14:00 with the quantity of solar radiation on a constant level. 4 refs., 4 figs., 1 tab.

  7. Control method for light deterioration of amorphous solar cell. 2. Temperature effect method; Amorphous taiyo denchi no hikari rekka yokuseiho. 2. Ondo kokaho

    Energy Technology Data Exchange (ETDEWEB)

    Fujimoto, H.; Itsumi, J.; Sano, N. [Kumamoto Institute of Technology, Kumamoto (Japan)

    1997-11-25

    Experimental studies have been carried out on suppressing early deterioration in amorphous silicon solar cells. The amorphous silicon solar cell is characterized by deterioration due to light irradiation and restoration due to temperature rise. An exposure experiment was performed under three conditions: installation in natural environment, installation with rear side of the solar cells covered with an insulating material, and installation with rear side of the solar cells covered with warming elements and an insulating material. Tests were made on suppressing progress of the early deterioration caused by temperature conditions. As a result, the efficiency in the natural condition was found to decrease as largely as 32% in an open circuit condition and 58% in a short circuit condition. The efficiency reduction rate was smaller in the open circuit condition when the insulation material was installed, but in the short circuit condition, resistance characteristics caused by rain water and electrolytic corrosion were exhibited. For the case with warming elements installed, the reduction in the efficiency was more remarkable, contrary to the expectation. The cause was determined that water existing between the rear side and the warming elements was warmed up, accelerating the electrolytic action, and resulting in deterioration advanced over a wide area in the rear side. 6 refs., 6 figs., 3 tabs.

  8. Temperature dependence of the early degradation in a-Si solar cells; Amorphous Si taiyo denchi no shoki rekka no ondo izonsei

    Energy Technology Data Exchange (ETDEWEB)

    Takahisa, K.; Kojima, T.; Nakamura, K.; Koyanagi, T.; Yanagisawa, T. [Electrotechnical Laboratory, Tsukuba (Japan)

    1997-11-25

    Discussions were given on early degradation in up to about ten minutes in amorphous silicon solar cells. The experiment has used a model cell of single junction layer for power use with a Glass/ITO/P-i-n:a-Si/Al structure. Test samples were annealed at 130 degC for 30 minutes to eliminate hysteresis of degradation during storage. Xenon was used as an irradiation light source, and the temperatures were varied from 0 to 100 degC and the measurement time was set to 0.1 to 500 minutes. The result of the experiment may be summarized as follows: with regard to time-based degradation pattern for conversion efficiency, the tilt of a pattern to express degradation rate varies with temperature conditions, and changes in 10 to 20 minutes of light irradiation as a boundary; in long-term degradation after 20 minutes, the higher the environmental temperature, the lower the degradation is suppressed, but the rate of initial degradation up to about 10 minutes is higher as the higher the temperature; and the degradation rate increases as the higher the temperature in the initial degradation of about 10 minutes, whereas, corresponding to this fact, it is estimated that a phenomenon is involved, in which carrier recombination defect may increase. 4 refs., 7 figs., 1 tab.

  9. Shunt and series resistance of photovoltaic module evaluated from the I-V curve; I-V tokusei kara hyokashita taiyo denchi no shunt teiko to chokuretsu teiko

    Energy Technology Data Exchange (ETDEWEB)

    Asano, K.; Kawamura, H.; Yamanaka, S.; Kawamura, H.; Ono, H. [Meijo University, Nagoya (Japan)

    1997-11-25

    With an objective of discussing I-V characteristics when a shadow has appeared on part of a photovoltaic module, evaluations were given as a first stage of the study on saturation current, shunt resistance and series resistance for the solar cell module. As a result of measuring change in amount of power generated in a sunny day with a shadow appearing over the solar cell module, reduction in power generation capability of about 23% was verified. In other words, the I-V characteristics of the solar cell module change largely because of existence of the shadow caused on the module. The I-V characteristics curve may be expressed and calculated as a function of the shunt resistance and series resistance. By curve-fitting measurement data for a case of changing insolation without existence of partial shadow, values of the shunt resistance and series resistance were derived. As a result, it was found that the calculations agree well with measurements. It was made also clear that each parameter shows temperature dependence. 6 refs., 10 figs., 1 tab.

  10. Concentration characteristics and cell arrangement in luminescent concentrator PV modules; Keiko shukogata taiyo denchi module no cell haichi to shuko tokusei

    Energy Technology Data Exchange (ETDEWEB)

    Inamura, A. [Science University of Tokyo, Tokyo (Japan); Sakuta, K. [Electrotechnical Laboratory, Tsukuba (Japan)

    1997-11-25

    A luminescent concentrator PV module requires no tracking equipment and can use scattered light. A mini PV module was prepared from a luminescent plate of 100times100times3mm, and a single-crystalline PV cell of 100times20mm. Characteristics of various prototype modules with different PV cell areas and cell arrangements were also measured. Four kinds of edge reflecting materials with different reflectances by various white coating were applied to Al sashes for module frames, and each sash was fixed on one edge of the luminescent plate. In experiment, 3 other edges were covered with black tapes to reduce each reflectance to 0%. Although PV module output was affected by reflectance of edges, the output was satisfactory at 90% or more in reflectance showing no difference in output. A concentrating efficiency decreased with an increase in luminescent plate (concentrator) area, while it was improved by cell arrangement with short optical pass length, and cell arrangement hardly affected by edge reflection. 4 refs., 7 figs.

  11. The significant contribution of FADs to Solomon Taiyo Limited's fishing operations

    OpenAIRE

    Sibisopere, M

    2000-01-01

    From 1972, when Solomon Taiyo Limited (stl) started a pole-and-line fishing operation, to 1980, stl vessels had been catching tuna almost exclusively from surface free-swimming schools. In 1981, a fad programme group purse-seining fishing operation, using the Filipino "payao" model, was put in place. Results were excellent and STL vessels quickly adapted their fishing methods to make the best use of fads. STL slightly modified the original payao design to better suit its own needs and nowaday...

  12. Technological development for super-high efficiency solar cells. Technological development of solar-high efficiency singlecrystalline silicon solar cells (high quality singlecrystalline silicon substrates); Chokokoritsu taiyo denchi no gijutsu kaihatsu. Chokokoritsu tankessho silicon taiyo denchi no gijutsu kaihatsu (kohinshitsu tankessho silicon kiban no gijutsu kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    Tatsuta, M. [New Energy and Industrial Technology Development Organization, Tokyo (Japan)

    1994-12-01

    This paper reports the study results on technological development for high quality efficiency singlecrystalline silicon substrates in fiscal 1994. (1) On electromagnetic casting/once FZ bath method, a Si single crystal of 600mm long was successfully obtained by improvement of power source frequency and furnace parts. High carbon content resulted in no single crystal including solids. In undoped electromagnetic casting ingots, resistivities over 1500ohm-cm were obtained because of effective preventive measures from contaminants. (2) On electromagnetic melting CZ method, since vibration and temperature control of melt surface by magnetic shield was insufficient for stable pulling of single crystals, its practical use was hopeless. (3) On electron beam melting CZ method, a Si single crystal of 25mm in diameter was obtained by preventive measures from evaporation of Si and influence of deposits, and improved uniform deposition distribution in a furnace. The oscillation circuit constant of power source, and water-cooling copper crucible structure were also analyzed for the optimum design of electromagnetic melting furnaces. 3 figs., 1 tab.

  13. Analysis and evaluation for practical application of photovoltaic power generation system. Analysis and evaluation for development of extra-high efficiency solar cells (fundamental research on extra-high efficiency Si solar cells); Taiyoko hatsuden system jitsuyoka no tame no kaiseki hyoka. Chokokoritsu taiyo denchi no gijutsu kaihatsu no tame no kaiseki hyoka (chokokoritsu silicon taiyo denchi gijutsu kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    Sekikawa, T.; Suzuki, E.; Ishikawa, K.; Takato, H.; Yui, N.; Shimokawa, R. [Electrotechnical Laboratory, Tsukuba (Japan)

    1994-12-01

    Described herein are the results of the FY1994 research program for analysis and evaluation for development of extra-high efficiency silicon solar cells. It is necessary for development of extra-high efficiency Si solar cells to extend as far as possible service life of minority carriers and to develop the evaluation techniques. Noting photoluminescence (PL) observable even with Si, the method of evaluating characteristics of minority carriers, which are not limited in samples, is developed to experimentally determine their service life from transitional response of the PL characteristics. Si has an extremely low quantum effect, because it is an indirect transitional semiconductor, and needs measurement of very high sensitivity. A rapid heat annealing apparatus and others to generate carriers in the infrared and ultraviolet regions are provided in consideration that these are possible means to increase efficiency. These possibilities will be pursued by developing the annealing techniques. 1 fig.

  14. Research on fabrication technology for thin film solar cells for practical use. Research on low-cost fabrication technology for large-area modules (CdS/CdTe solar cell modules); Usumaku taiyo denchi seizo gijutsu no jitsuyoka kenkyu. Daimenseki module no tei cost seizo gijutsu (CdTe taiyo denchi module seizo no gijutsu kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    Tatsuta, M. [New Energy and Industrial Technology Development Organization, Tokyo (Japan)

    1994-12-01

    This paper reports the study results on the fabrication technology of CdS/CdTe solar cell modules in fiscal 1994. (1) On the fabrication technology for high-efficiency large-area solar cells, high-quality CdTe active layer was studied. S content taken in the active layer at sintering of CdTe decreased with an increase in formed CdTe, resulting in improvement of Voc of cells. (2) On the window layer with wide band gap, the solar cell superior in collection efficiency and photoelectric characteristics could be obtained using the newly developed mixed crystal film of Cd(1-x)Zn(x)S. (3) On the forming technology of large-area coating/sintering films, improvement of CdS film quality was studied by pressurized processing of printed CdS films. As a result, improvement of film density and light transmissivity was confirmed. (4) On the leveling process technology of CdTe films, smooth surface films were obtained by experiment using an equipment simultaneously exciting samples in all directions as one of uniform coating methods of films. 7 figs.

  15. Research on fabrication technology for thin film solar cells for practical use. Technological development for qualitative improvement (CuInSe2 based PV cell); Usumaku taiyo denchi seizo gijutsu no jitsuyoka kenkyu. Kohinshitsuka gijutsu (CuInSe2 taiyo denchi seizo no gijutsu kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    Tatsuta, M. [New Energy and Industrial Technology Development Organization, Tokyo (Japan)

    1994-12-01

    This paper reports the study results on the fabrication technology of CuInSe2 based PV cell in fiscal 1994. (1) On formation of high-quality CIGS thin films by bilayer method, Mo film was deposited on a glass substrate by sputtering, and CIGS film with different Ga/In ratios was next formed on the substrate by quaternary simultaneous deposition at different In and Ga deposition speeds. In addition, CdS film was deposited on the CIGS film, and ZnO and ITO films were finally deposited on it by sputtering to complete solar cell. This solar cell offered the maximum conversion efficiency among cells using CIGS film. (2) On formation of high-quality CIGS thin films by three-stage method, a certain correlation was found between substrate temperature and CIGS film composition by monitoring substrate temperature in film forming process. This phenomenon allowed rigorous control of CIS film compositions important for CIS thin film solar cells. (3) On low-cost process technology for thin film formation, Cu(In,Ga)S2 solid solution film was fabricated by expanded selenic process. 3 figs.

  16. Research on fabrication technology for thin film solar cells for practical use. Technological development for qualitative improvement (development of fabrication technology of thin film polycrystalline Si solar cell); Usumaku taiyo denchi seizo gijutsu no jitsuyoka kenkyu. Kohinshitsuka gijutsu (usumaku takessho silicon kei taiyo denchi seizo no gijutsu kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    Tatsuta, M. [New Energy and Industrial Technology Development Organization, Tokyo (Japan)

    1994-12-01

    This paper reports the study results on the fabrication technology of thin film polycrystalline Si solar cells in fiscal 1994. (1) On the fabrication technology of high-quality Si thin films, the new equipment was studied which allows uniform stable melting recrystallization over a large area. The new equipment adopted a heating method based on RTP system, and is now under adjustment. (2) On the fabrication technology of light/carrier confinement structure, degradation of hydrogen-treated thin film Si solar cells by light irradiation was examined. As a result, since any characteristic degradation was not found even by long time light irradiation, the high quality of the cells was confirmed regardless of hydrogen-treatment. Fabrication of stable reproducible fine texture structure became possible by using fabrication technology of light confinement structure by texture treatment of cell surfaces. (3) On low-cost process technology, design by VEST process, estimation of cell characteristics by simulation, and characteristics of prototype cells were reported. 33 figs., 1 tab.

  17. Analysis and evaluation for practical application of photovoltaic power generation system. Analysis and evaluation for thin substrate polycrystalline solar cells (compound semiconductors and their fabrication technologies); Taiyoko hatsuden system jitsuyoka no tame no kaiseki hyoka. Usumaku taiyo denchi jitsuyoka no tame no kaiseki hyoka (kagobutsu taiyo denchi zairyo oyobi seisaku gijutsu no kaiseki hyoka)

    Energy Technology Data Exchange (ETDEWEB)

    Oyagi, H.; Okada, Y.; Yamaguchi, H.; Shiota, T.; Kuroda, S.; Igarashi, O.; Tanino, H.; Makita, Y.; Yamada, A.; Kimura, S.; Ohara, A.; Niki, S.; Shibata, H.; Fons, P. [Electrotechnical Laboratory, Tsukuba (Japan)

    1994-12-01

    Described herein are the results of the FY1994 research program for analysis and evaluation for thin-film compound semiconductor solar cells. The study on epitaxial growth and optical properties of the thin films of CuInSe2 and CuGaSe2 evaluates the thin epitaxial films grown under various conditions, showing morphology of the defects at the interface of heteroepitaxial growth. These results are used to set the growth conditions under which a thin film of high luminescence by exciter recombination is produced. The study also gives information of luminescence transition in the vicinity of the band ends and of energy level between the bands. The study on structural analysis of the epitaxially grown thin films of CuInSe2 investigates dependence of lattice constants of the MBE-grown CIS layer on film thickness by the X-ray diffractometry based on the bond method. The study on epitaxial growth by the Se(CH3)2-halogen transfer method tests epitaxial growth of the single-crystalline Mo on a substrate of single-crystalline sapphire. 5 figs.

  18. Research on fabrication technology for thin film solar cells for practical use. Technological development for qualitative improvement (improvement of conversion efficiency of amorphous silicon solar cells after degradation); Usumaku taiyo denchi seizo gijutsu no jitsuyoka kenkyu. Kohinshitsuka gijutsu (amorphous taiyo denchi no shoki rekkago koritsu kojo no gijutsu kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    Tatsuta, M. [New Energy and Industrial Technology Development Organization, Tokyo (Japan)

    1994-12-01

    This paper reports the study results on technological development for qualitative improvement of a-Si solar cells after initial degradation in fiscal 1994. On the fabrication technology of light-stable a-Si films, the film formation method possible to control combined hydrogen by repetitive formation/treatment was developed. The obtained high-quality light-stable a-Si film was featured by low defect density in a wide optical band gap range, and defect density of nearly 3 {times} 10{sup 16}/cm{sup -3} after light irradiation. The light degradation rate of the cell where the a-Si film was applied to i layer was relatively stable by 10% or less. The a-Si/a-Si double-layer tandem cell fabricated by this technology produced a high conversion efficiency of 10.5%. By applying {mu}c-Si material to photoactive layer as narrow band gap material, the cell with optical sensitivity even in long wavelength ranges more than 1000nm was obtained. The a-Si/{mu}c-Si double-layer tandem cell produced an initial efficiency of 8.0% and an efficiency after degradation of 7.5%. 12 figs., 3 tabs.

  19. Achievement report for fiscal 1997. Technological development for practical application of a solar energy power generation system/development of technology to manufacture thin film solar cells/development of technology to manufacture low-cost large-area modules/development of technology to manufacture next generation thin film solar cells (development of technology to manufacture applied type thin film solar cells with new construction); 1997 nendo tiayoko hatsuden system jitsuyoka gijutsu kaihatsu. Usumaku taiyo denchi no seizo gijutsu kaihatsu, tei cost daimenseki module esizo gijutsu kaihatsu (jisedai usumaku taiyo denchi no seizo gijutsu kaihatsu, oyogata shinkozo usumaku taiyo denchi no seizo gijutsu kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    A thin film single crystal silicon solar cell module is developed, in which a porous silicon layer is formed on the surface of a long-sized single crystal silicon substrate, a single crystal silicon film is integrated on the layer by epitaxially growing the film thereon to form a solar cell, and the solar cell is peeled off from the silicon substrate and transferred to a plastic film substrate. The achievements during this fiscal year may be summarized as follows: simultaneous formation of a porous silicon layer on a silicon substrate, reduction of anode formation current density from 200 mA/cm{sup 2} to 10 mA/cm{sup 2}, development of a silicon epitaxial device using a carbon heater, and attainment of aperture conversion efficiency of 11.8% in a thin film single crystal silicon solar cell. Three kinds of methods were developed to peel off the solar cell. A method was developed to grind silicon substrate surface from which the solar cell has been peeled off. A technology was developed to obtain a long-sized silicon substrate of about 30 cm times 10 cm times 0.1 cm from a 4-inch silicon ingot by using a wire saw. (NEDO)

  20. Development of practical application technology for photovoltaic power generation systems in fiscal 1997. Development of technologies to manufacture thin film solar cells, development of technologies to manufacture low-cost large-area modules, development of technologies to manufacture next-generation thin film solar cells (development of technologies to manufacture CIS solar cell modules); 1997 nendo taiyoko hatsuden system jitsuyoka gijutsu kaihatsu. Usumaku taiyo denchi no seizo gijutsu kaihatsu, tei cost daimenseki module seizo gijutsu kaihatsu, jisedai usumaku taiyo denchi no seizo gijutsu kaihatsu (CIS taiyo denchi module no seizo gijutsu kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    Research and development was made with an objective to achieve conversion efficiency of 13% in a 30 cm times 30 cm size submodule of a CIS-based thin film solar cell, and to develop a manufacturing technology that can achieve 140 yen/Wp. This paper describes the achievements attained during fiscal 1997. In fiscal 1997, based on the achievements reached during the previous year, a submodule with a size of 10 cm times 30 cm was fabricated for an attempt of improving the open voltage and short circuit current density. Simultaneously, the applicability thereof to a module with an area as large as 30 cm times 30 cm was evaluated. As a result of experimental discussions, enhancement in the open voltage was verified by increasing amount of Ga or sulfur, but it was not possible to achieve 600 mV or higher. In the research of component technologies to establish a mass production process, research and development was made on a high-resistance buffer layer film forming technology, a high-quality window layer film forming technology, a high-quality metallic rear electrode film forming technology, and patterning technologies. The outdoor exposure test was continued on laminated mini-modules with a size of 10 cm times 10 cm. (NEDO)

  1. Achievement report for fiscal 1997 on development of technologies for practical photovoltaic system under New Sunshine Program. Manufacture of thin-film solar cell / low-cost and large-area module / next-generation thin-film solar cell (Manufacture of thin-film polycrystalline solar module); 1997 nendo taiyoko hatsuden system jitsuyoka gijutsu kaihatsu seika hokokusho. Usumaku taiyo denchi no seizo gijutsu kaihatsu, tei cost daimenseki module seizo gijutsu kaihatsu, jisedai usumaku taiyo denchi no seizo gijutsu kaihatsu (usumaku takessho taiyo denchi module no seizo gijutsu kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    Fiscal 1997 is the first year of another 4-year-long research and development phase. In addition to researches for improving on thin-film polycrystalline Si cell efficiency that have been under way, new efforts are started, which include the development of practicality-conscious thin film producing technologies aiming at higher throughput and yield and the development of modularization process technologies which are necessary for putting thin-film cells to practical use. Concerning the formation of a power generation layer on a polycrystalline Si thin film formed by the ZMR (zone-melting recrystallization) process, studies are conducted for improvement on its throughput and yield using a new CVD (chemical vapor deposition) unit. A method of modularization is evaluated, which involves a laminate of a thin-film cell attached to a resin-coated, reinforced glass substrate and an EVA (ethylene vinyl acetate) back film. A remarkable achievement is earned toward the practicalization of technologies of thin film formation enhanced in quality and throughput and technologies of thin film modularization. (NEDO)

  2. Achievement report for fiscal 1997. Technological development for practical application of a solar energy power generation system/development of technology to manufacture thin film solar cells (development of technology to manufacture applied type thin film solar cells with new construction) (development of technology to manufacture micro light collection type solar cells); 1997 nendo taiyoko hatsuden system jitsuyoka gijutsu kaihatsu seika hokokusho. Usumaku taiyo denchi no seizo gijutsu kaihatsu, oyogata shinkozo usumaku taiyo denchi no seizo gijutsu kaihatsu (micro shukogata taiyo denchi no seizo gijutsu kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    These technological developments are intended to demonstrate module efficiency of a micro light collection type solar cell of 15% by fiscal 2000, and obtain prospect on the module manufacturing cost of 140 yen per watt. Discussions given during fiscal 1997 are as follows: development has been performed on a design method to decide construction of a non-tracking micro light collection type module; in the state of cells being integrated on the module, the cells are arranged minutely and discretely, whereas, with discussions on a method to form them and assessment of the optical system as the main objective, single crystal silicon solar cells with a size smaller than 5 mm were fabricated on a trial basis; problems of forming micro cells by using the wafer cutting process were clarified; micro cells operating on light collection were fabricated trially to extract technological problems in light collecting operation and discuss technical problems in mass production; and development was performed on an evaluation method to analyze the cells' light collecting operation, and discussions were given on a method to estimate power generation amount from the light collection type modules. (NEDO)

  3. Studies of flat-plate solar air collectors with absorber plates made of amorphous silicon photovoltaic modules; Amorphous taiyo denchi module wo shunetsuban to shita heibangata kukishiki shunetsuki no kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Sato, K.; Ito, S.; Miura, N. [Kanagawa Institute of Technology, Kanagawa (Japan)

    1996-10-27

    A light/heat hybrid air type heat collector has been developed in which heat is collected by solar cell panels. In Type 1 heat collector provided with a glass cover, two modules are connected in series and placed under a glass cover to serve as a heat collecting plate, each module built of a steel plate and two thin-film amorphous solar cells bonded to the steel plate. Air runs under the heat collecting plate. Type 2 heat collector is a Type 1 heat collector minus the glass cover. Air is taken in by a fan, runs in a vinyl chloride tube, and then through the heat collector where it is heated by the sun, and goes out at the exit. Heat collecting performance was subjected to theoretical analysis. This heat collector approximated in point of heat collection a model using a board painted black, which means that the new type functions effectively as an air-type heat collector. Operating as a photovoltaic power generator, the covered type generated approximately 20% less than the uncovered type under 800W/m{sup 2} insolation conditions. Type 1 has been in service for five months, and Type 2 for 2 months. At present, both are free of troubles such as deformation and the amorphous solar cell modules have deteriorated but a little. 4 refs., 9 figs.

  4. Research and development of evaluation system for photovoltaic power generation system. Survey on research and development of solar cell evaluation system; Taiyoko hatsuden system hyoka gijutsu no kenkyu kaihatsu. Taiyo denchi hyoka system no kenkyu kaihatsu chosa

    Energy Technology Data Exchange (ETDEWEB)

    Tatsuta, M. [New Energy and Industrial Technology Development Organization, Tokyo (Japan)

    1994-12-01

    This paper reports the survey results on R and D of solar cell evaluation systems in fiscal 1994. The performance/reliability evaluation subcommittee continuously analyzed technical issues and discussed solution measures from the last fiscal year. On development of performance evaluation methods, improvement of measurement accuracy for laminated solar cells is the study issue to be solved. Although laminated solar cells are measured by multiple light source solar simulator, difficult spectrum compensation causes measurement errors. Collection and analysis of data for determining atmospheric conditions, and outdoor measurement experiment under the atmospheric conditions for reference solar light were carried out. The study on incident angle characteristics of laminated solar cells clarified that the deviation from COS characteristics is 1.0% or less at an incident angle of 30{degree}. The study on generated energy in solar cell module level in field clarified that generated energy and generation efficiency are proportional to intensity of solar radiation. 1 tab.

  5. Research and development of evaluation system for photovoltaic power generation system. Research and development of evaluation systems for photovoltaic cells and modules; Taiyoko hatsuden system hyoka gijutsu no kenkyu kaihatsu. Taiyo denchi hyoka system no kenkyu kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Tatsuta, M. [New Energy and Industrial Technology Development Organization, Tokyo (Japan)

    1994-12-01

    This paper reports the study results on R and D of the evaluation system for solar cells in fiscal 1994. (1) On development of the performance evaluation method for solar cells, data collection, analysis and measurement of atmospheric conditions necessary for outdoor measurement were carried out to improve the measurement accuracy of laminated solar cells. The validity of measurement methods was verified by comparing experimental results with outdoor measurement ones to improve the indoor measurement accuracy by multiple light source solar simulator. Generated energy in solar cell module level was also studied in field. (2) On development of the reliability evaluation method for solar cells, deterioration data were collected and analyzed by long-term exposure test. As a result, it was clarified that Pmax values are directly affected by seasonal change in air mass, and deterioration of solar cells is hardly found after exposure test for one year, showing a stable state. The characteristic recovery experiment of amorphous solar cell modules was carried out, and the accelerated deterioration test method of thin film cell modules was also studied. 2 figs.

  6. Design and construction of radiant panel for cooling and heating with photovoltaic and thermoelectric element modules; Taiyo denchi to netsuden soshi module wo mochiita fukusha reidanbo panel no sekkei oyobi shisaku

    Energy Technology Data Exchange (ETDEWEB)

    Sato, M.; Tani, T. [Science University of Tokyo, Tokyo (Japan); Kadotani, K.; Imaizumi, H. [Komatsu Ltd., Tokyo (Japan)

    1997-11-25

    Utilizing cooling properties and current voltage characteristics of a small cooling panel using thermoelectric elements which had been fabricated previously on a trial basis, design and prototype production were executed on a large radiant cooling and heating panel driven by photovoltaic cell modules. The panel design set the cooling area to about 0.5 m {sup 2} and the number of elements to 70 pieces, and optimum number of elements in series and parallel connection was derived. As a result of the analysis, it was made clear that the optimum number of thermoelectric module arrays in series and parallel connection varies depending on insolation intensity. It was found preferable that the number of parallel connection array be set to one to two in a region or time period in which low insolation intensity is distributed in greater amount. In the case where high insolation intensity is distributed in a greater amount, setting it to two to three is preferable. By using the structured design method and the HASP Tokyo data, thermoelectric element modules were interconnected with 35 modules in series and two in parallel on a cooling panel installed on the roof of the Science University of Tokyo. A simulation result revealed that the average temperature difference on the cooled surface in summer is 4.37 degC, and the solar cell utilization rate is 0.67. It is necessary in the future to improve heat dissipation efficiency and area ratio. 1 ref., 12 figs., 5 tabs.

  7. Output characteristic of photovoltaic module on different installing conditions. Comparison with calculated value and measured value; Secchi joken no kotonaru taiyo denchi module no shutsuryoku tokusei. Suchi kaiseki to jissokuchi tono hikaku

    Energy Technology Data Exchange (ETDEWEB)

    Sasaki, T.; Morita, Y.; Iwawaki, H.; Fujisawa, T.; Tani, T. [Science University of Tokyo, Tokyo (Japan)

    1997-11-25

    The paper studied output characteristics of photovoltaic modules different in installation conditions on the basis of the energy balance state. In the study, an energy balance equation was constructed for insolation intensity, heat losses from PV surface/back, and output, in order to calculate cell temperatures in each installation condition. A comparative study was made between calculated results and measured data obtained on the top of the school building. The results indicated the following: The thickness of thermal boundary layer became approximately 27mm at insolation intensity of 800 W/m{sup 2}, ambient air temperature of 25degC, and wind velocity of 0.5m/s. When widening air gap from 20mm to 40mm, the cell temperature decreased 4degC, and the output increased 1.6%. In the case of installing photovoltaic modules on the roof considering the relation between the air gap in the heat balance state and the thickness of thermal boundary layer, heat from PV back was released outside the air gap if widening the air gap to more than 30-40mm. The type with a heat insulating material on the panel back decreased in output from other types. 5 refs., 7 figs., 4 tabs.

  8. Dependence of open-circuit voltage of SnO2-nSi solar cells; SnO2-nSi taiyo denchi no sanka ondo menhoi izonsei

    Energy Technology Data Exchange (ETDEWEB)

    Shinoda, S.; Shimizu, A.; Yano, K.; Kasuga, M. [Yamanashi University, Yamanashi (Japan). Faculty of Engineering

    1997-11-25

    Although metal(or semiconductor)-semiconductor solar cells, SnO2-nSi solar cell for example, are superior in cost and efficiency, its barrier height and open-circuit voltage V(oc) are lower than those of p-n junctions. To improve these defects, study was made on the dependence of V(oc) on oxidation temperature and surface orientation using various solar cells prepared from (100)Si and (111)Si under various oxidation conditions. As a result, the density of surface states increases with a decrease in oxidation temperature of Si substrates, resulting in an increase in diode factor and V(oc). In this case, since oxide films are extremely thin and contribution of non-terminated bonds is large in the initial oxidation stage, the quantity of dangling bonds is larger in (100) plane than (111) plane, resulting in an increase in diode factor and V(oc). Since the surface energy level (the degree of electrons dominated by acceptor-like surface state from this level to the top of a valence band) of (100) Si is lower than that of (111) Si, the effective barrier height and V(oc) increase. 28 refs., 6 figs., 2 tabs.

  9. FY 1999 research and development of technologies for commercialization of photovoltaic power generation systems. Development of technologies for production of thin-film solar cells and low-cost, large-area modules (Development of technologies for high-reliability CdTe solar cell modules); 1999 nendo taiyoko hatsuden system jitsuyoka gijutsu kaihatsu seika hokokusho. Usumaku taiyo denchi no seizo gijutsu kaihatsu / tei cost daimenseki module seizo gijutsu kaihatsu (koshinraisei CdTe taiyo denchi module no seizo gijutsu kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    The research and development project is implemented for production of low-cost, large-area modules of CdTe solar cells by the high-quality film-making process and high-function patterning, and the FY 1999 results are reported. The research program for the large-area TCO film-making technologies involves investigations on improvement of SnO{sub 2} film quality by the mist method and continuous film-making, which lead to continuous, stable production of 34 substrates of low resistance of 9.7{omega} on the average. The program for production of the large-area, thin-film CdS/CdTe solar cells involves production of TCO and CdS by the mist method, and patterning of the laminated TCO/CdS film by laser scribing. The CdTe film is formed by the atmospheric pressure CSS method, and treated with CdCl{sub 2} to improve its crystallinity. The CdTe film is patterned by sand blasting, and provided with the carbon and silver electrodes by screen printing, to complete the cell. The process is totally effected at the atmospheric pressure, needing no vacuum device. The CdTe solar cell assembly (130 cells connected in series, opening area: 5,413cm{sup 2}), fabricated on a trial basis, achieves a conversion efficiency of 10%. (NEDO)

  10. Development of practical application technology for photovoltaic power generation systems in fiscal 1997. Development of technologies to manufacture next-generation thin film solar cells, development of technologies to manufacture CIS solar cell modules, development of technologies to increase high-quality film area; 1997 nendo taiyoko hatsuden system jitsuyoka gijutsu kaihatsu. Jisedai usumaku taiyo denchi module no seizo gijutsu kaihatsu, CIS taiyo denchi module no seizo gijutsu kaihatsu, kohinshitsumaku no daimensekika gijutsu kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    With an objective to improve efficiency and reduce cost of CIS-based thin film solar cells, research and development has been made on technologies to increase high-quality CIS film area and technologies to increase speed in the manufacturing process. This paper describes the achievements attained during fiscal 1997. The research covered development of technologies to form high-grade Cu (In, Ga) Se{sub 2} (CIGS) film by using the multi-dimensional deposition process, component technologies for forming a rear electrode, a buffer layer and a transparent electrode, and patterning technologies. As a result of the research, thickness of the CIGS film was reduced to half as much as that of the conventional films, having achieved conversion efficiency of 13.1%, which corresponds to about 90% of the conventional CIGS solar cells. In addition, elucidation was made on the effect of an MoSe{sub 2} layer existing on interface with CIGS/Mo in a CIGS solar cell imposed on solar cell characteristics. In developing an Mo film laser scribing technology, intensity dependence of laser energy was made clear, the energy being required for scribing according to surface condition of the Mo film. (NEDO)

  11. Achievement report for fiscal 1997 on developing practical application technology for photovoltaic power generation systems under the New Sunshine Project. Development of technologies to manufacture thin film solar cells, development of technologies to manufacture low-cost large-area modules, and development of technologies to manufacture new type amorphous solar cells; 1997 nendo taiyoko hatsuden system jitsuyoka gijutsu kaihatsu. Usumaku taiyo denchi no seizo gijutsu kaihatsu, tei cost daimenseki module seizo gijutsu kaihatsu, shingata amorphous taiyo denchi no seizo gijutsu kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    Development will be made on high-performance a-solar cells as part of developing practical application technology for a-solar cells for electric power use. Development will be also made on a low-cost process technology. This paper describes the achievements attained during fiscal 1997. Quality improvement has been realized by using a high RF power hydrogen dilution process on a-Si films for front cells of lamination type cells. Four times faster film forming speed was obtained even by using the VHF plasma CVD process, with film quality equivalent to those made by using the conventional RF process maintained. By optimizing the light enclosing construction, the short circuit current was enhanced by over 20%. Discussions were given on forming homogenous a-Si films by optimizing the conditions for forming films on large-area substrates, which resulted in forming film of 30 cm times 40 cm size with good homogeneity at a film forming speed three times faster than the conventional speed. A surface electrode was formed successfully with good uniformity on a substrate with a size of 60 cm times 90 cm. Productivity greater by over three times the conventional productivity was achieved in patterning of transparent electrodes by using high-output laser. Simultaneous and collective patterning and very small and long size collective patterning were realized in a-Si film selection patterning by using the plasma CVD process. (NEDO)

  12. Achievement report for fiscal 1997 on development of technologies for practical photovoltaic system under New Sunshine Program. Manufacture of thin-film solar cell and of low-cost/large-area module (Manufacture of high-reliability CdTe solar module); 1997 nendo taiyoko hatsuden system jitsuyoka gijutsu kaihatsu seika hokokusho. Usumaku taiyo denchi no seizo gijutsu kaihatsu, tei cost daimenseki module seizo gijutsu kaihatsu (koshinraisei CdTe taiyo denchi module no seizo gijutsu kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    The target is a low-cost CdS/CdTe solar cell of a large area (60cm times 90cm), the establishment of mass-production technologies for the cell, and the enhancement of production efficiency. A thin film formation technology of subjecting CdS film organic metal to pyrolysis is established, which reduces photoabsorption loss in the shortwave domain of wavelength of not longer than 500nm, reduces reflection loss in the film, and improves on short-circuit current density. Improvement is also achieved on CdTe film quality and junction quality by use of a proximity sublimation method in a vacuum, when a conversion rate of 16.0% (1cm{sup 2}) is attained which is the highest in the world. Based on the results of the above-said efforts, a 3.3mm-thick glass substrate is employed for CdTe film to develop into a 30cm times 60cm-large size, with the film thereon uniformly thick over a large area thanks to a normal pressure proximity sublimation method. Studies are made toward a process nearer to the ultimate product and, using the patterning technique, a 30cm times 60cm-large CdTe solar cell is tentatively built realizing a conversion rate of 9.8%. (NEDO)

  13. Development of technology for thin substrate polycrystalline solar cells for practical use. Development of manufacturing technologies for low-cost substrates (technical development for production of high purity silicon); Usugata takessho taiyo denchi seizo gijutsu no jitsuyoka kenkyu. Tei cost kiban seizo gijutsu kaihatsu (taiyo denchiyo silicon seizo gijutsu kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    Tatsuta, M. [New Energy and Industrial Technology Development Organization, Tokyo (Japan)

    1994-12-01

    This paper reports the study results on development of manufacturing technologies of Si for solar cells in fiscal 1994. (1) P in Si could be successfully reduced to 0.1ppmw by EB melting method. The condition possible to reduce P in Si while continuously supplying metal Si was found. The 20kg class EB melting equipment was also designed and manufactured which can be connected with solidifying rough refining process. (2) Use of a water-cooling copper mold was studied using a small melting equipment for cost reduction in solidifying rough refining process. As a result, the prospect of crucible-free technology for removal of P and solidifying rough refining was obtained. (3) B in Si could be successfully reduced to the target of 0.1ppmw by vapor addition method using a plasma melting equipment. (4) The prototype SOG-Si achieved a conversion efficiency of 14.1% as solar cell. In addition, the advanced solar cell prepared by efficiency enhancement process achieved a conversion efficiency of 15.9%. 3 figs.

  14. Polymer electric battery to challenge light weight of portable machines; Keitai kiki no keiryoka ni idomu porima denchi

    Energy Technology Data Exchange (ETDEWEB)

    Suzuki, Masayuki.

    1999-06-01

    Polymer electric battery is one of lithium secondary battery, roughly divided into two types. One type is to use the Li ion active polymer as electrode active matter and polyaniline was used as a positive electrode in a part of the coin type secondary battery. Recently, organic sulfur polymer has been paid attention as the positive electrode materials with high energy density, an example of a larger capacity by compounding sulfur was reported and its further development was expected. Another type of polymer electric battery is to use solid polyelectrolyte (SPE) into separators and binders of batteries. Polymer electric battery had a character to be packaged by the soft aluminum minute film since the shape solidified from polymer at the interior was independent on a case. (NEDO)

  15. Confinement of solar thermal energy by Nesa film; Nesa maku ni yoru taiyo netsu energy no fujikome

    Energy Technology Data Exchange (ETDEWEB)

    Shimizu, A.; Yano, K.; Kasuga, M.; Daigo, Y. [Yamanashi University, Yamanashi (Japan). Faculty of Engineering

    1997-11-25

    This paper reports a Nesa (SnO2) film as selective transmissive film for effective confinement of solar thermal energy. Solar light spectrum ranges from 0.3 to 2.0{mu}m, while thermal radiation from bodies at 100-200degC is infrared ray more than 2{mu}m. Consequently, a solar water heater using the film which can pass rays below 2.0{mu}m while reflect rays over 2.0{mu}m for windows is very efficient. The Nesa film reflects rays with wavelengths more than plasma wavelengths (controllable from 1 to several {mu}m) by plasma action of free electrons. The Nesa films with different carrier densities were fabricated by spraying deposition method at dopant rates (Sb/Sn) from 0 to 2mol%. The solar water heaters were prepared using normal glass and specific glass coated with the Nesa film as selective transmissive film. The heater using the glass coated with the Nesa film of 2{mu}m plasma wavelength for windows could efficiently confine solar heat. The Nesa film of 700nm plasma wavelength which can pass visible light while reflect infrared ray was effective to reduce cooling/heating losses. 3 refs., 6 figs.

  16. Electrolyte for phosphoric acid fuel cell. Rinsangata nenryo denchi no denkaieki

    Energy Technology Data Exchange (ETDEWEB)

    Suzuki, Y.; Uede, M.; Yamaken, H. (Yamaha Motor Co. Ltd., Shizuoka (Japan))

    1991-02-14

    When the phosphoric fuel cell is used in cold districts, the electrolyte used in the cell solidifies and freezes because its freezing point is high, and the cell can not be used any more. The object of this invention is to provide a fuel cell which does not freeze even the cell is shutdown in low temperature environment by adding non-conjugating inorganic salt to strong phosphoric acid to lower the freezing point. The phosphoric acid used in accordance with this invention is desirable generally to be of 80 to 105% if calculated in terms of orthophosphoric acid to maintain the cell performance. As the negative ions constituting the non-conjugating inorganic salt, sulphate ion, carbonate ion, silicate ion, and boric acid ion are desirable. In concrete, ZnSO{sub 4}, NiSO{sub 4}, Na{sub 2}SO{sub 4}, BeSO{sub 4}, CdSO{sub 4}, CoSO{sub 4}, FeSO{sub 4}, K{sub 2}CO{sub 3}, Na{sub 2}CO{sub 3}, CaCO{sub 3}, MgCO{sub 3}, K{sub 2}SiO{sub 3}, Na{sub 2}B{sub 4}O{sub 7}, etc. can be quoted. Excessive addition of inorganic salt results rather in the precipitation of the added inorganic salt to cause freezing, and addition of 20wt% or less is desirable. 1 fig.

  17. Achievement report for fiscal 1997. Technological development for practical application of a solar energy power generation system /development of technology to manufacture solar cells/development of technology to manufacture thin film solar cells (development of technology to manufacture materials and substrates (development of technology to manufacture silicon crystal based high-quality materials and substrates)); 1997 nendo taiyoko hatsuden system jitsuyoka gijutsu kaihatsu seika hokokusho. Taiyo denchi seizo gijutsu kaihatsu, usumaku taiyo denchi seizo gijutsu kaihatsu, zairyo kiban seizo gijutsu kaihatsu (silicon kesshokei kohinshitsu zairyo kiban no seizo gujutsu kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    It is intended to develop thin film solar cells capable of mass production with high photo-stability and at low cost. Thus, the objective of the present research is to analyze the growth process of micro crystal silicon based thin films, the crystal being a high quality silicon crystal based material, and develop technology to manufacture high-quality micro crystal silicon thin films based on the findings therefrom. It was found that, when silicon source is available in cathode, pure hydrogen plasma forms micro crystal silicon films by using the plasma as a result of the chemical transportation effect from the silicon source. It was revealed that the crystal formation due to hydrogen plasma exposure is performed substantially by the crystals forming the films due to the chemical transportation effect, rather than crystallization in the vicinity of the surface. The crystal formation under this experiment was concluded that the formation takes place during film growth accompanied by diffusion of film forming precursors on the surface on which the film grows. According to the result obtained so far, the most important issue in the future is particularly the control of crystal growing azimuth by reducing the initially formed amorphous layer by controlling the stress in the initial phase for film formation, and by controlling the film forming precursors. (NEDO)

  18. Sony Co., Ltd.: An outlook is made for merchandising of the manganese acid lithium ion battery; Mangansan richiumuion denchi no shohinka ni medo

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-12-31

    Sony Co., Ltd. sells the manganese acid lithium ion battery that a battery is 1 by 2 as to the next generation lithium ion during 99 years. It is characteristics that a price is restrained because manganese is used for the proper pole material instead of cobalt of the rare metal. It becomes mass production by Koriyama factory where a lithium ion battery is being manufactured improving an existent production line. It is seen when some percents of manufacture cost goes down more than cobalt acid battery of news file before. A manganese acid lithium ion battery uses manganese acid lithium for the proper pole of the battery. The efficiency of the charge of the usual lithium ion battery is good, and composition is easy, and uses cobalt acid lithium, which is easy to produce. One side where a material fee is cheap, the stability at the high temperature of manganese acid is low, and composition is difficult. Only NEC Moli Energy corporation who is the subsidiary company of NEC succeeds in the mass production. NEC Moli Energy corporation is extending market share by the price competition power. It seems to have the possibility that manganese acid becomes the main force with a battery by two by new entering of Sony Co., Ltd. of the lithium ion battery extreme big enterprises. (translated by NEDO)

  19. Study on property-gradient polymer electrolyte for rechargeable lithium batteries; Lithium niji denchi no tame no keisha tokusei kobunshi denkaishitsu no sosei ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Kokumi, Z.; Kanemura, S.; Inaba, M.; Takehara, Z.; Yao, K.; Uchimoto, Y. [Kyoto University, Kyoto (Japan)

    1997-02-01

    This paper describes the fundamental experiments for creating property-gradient polymer electrolyte for rechargeable lithium batteries. The rechargeable lithium battery is composed of an anodic composite agent section with high ion conductivity, a separator equivalent section with high mechanical strength (high bridging degree), and a section surpressing the precipitation of metal lithium by contacting with it. The continuous property-gradient polymer electrolyte was tried to be synthesized by means of the plasma polymerization method. As a result, plasma polymerization electrolyte with high ion conductivity could be prepared from the liquid phase by using a monomer with low vapor pressure. Porous material simulating the anodic composite agent was impregnated by the monomer, which was plasma-polymerized. As a result, it was found that the bridging degree decreased from the surface towards the inside of the plasma-polymerized porous material. In addition, polymer was prepared using fluorine-base monomer. Thus, LiF thin film could be prepared through the reaction between the polymer and metal lithium. 3 figs.

  20. Hear recovery properties from fuel cell system for telecommunications use; Tsushin`yo nenryo denchi system no fuirudotesuto ni okeru hainetsu kaishu tokusei

    Energy Technology Data Exchange (ETDEWEB)

    Ishizawa, M.; Iida, S.; Abe, I.; Amanuma, H. [NTT Integrated Information and Energy Systems Laboratories Tokyo (Japan); Uekusa, T.; Waragai, S. [NTT Power and Building Eacilities Inc., Tokyo (Japan)

    1997-12-20

    NTT is developing a phosphoric acid fuel cell energy system for telecommunication co-generation systems to reduce energy costs and help preserve the environment. Fuel cells are used to provide electrical power to telecommunication equipment and the heat energy that is generated is used by the absorption refrigerator to cool the telecommunication rooms throughout the year. We fieldtested this fuel cell energy system in a telephone office for three years. Heat recovered water from fuel cell stack coolant was supplied to the absorption refrigerator and further extra-heat was recovered by a heat exchanger. The toral heat recovery amount was about 86000 kca/h (the heat recovery efficiency was 20%) under 200kW operation. The absorption refrigerator was supplied about 49000kcal/h of heat and operated with 0.7 of coefficient of performance throughtout the year. The electrical efficiency was maintained more than 38% after 13000h operation. 12 refs., 10 figs., 3 tabs.

  1. Heat recovery properties from fuel cell system for telecommunications use; Tsushin`yo nenryo denchi system ni okeru hainetsu kaishu tokusei

    Energy Technology Data Exchange (ETDEWEB)

    Ishizawa, M.; Iida, S.; Abe, I.; Yamamoto, M. [NTT Integrated Information and Energy Systems Laboratories, Tokyo (Japan)

    1997-08-20

    NTT is developing a phosphoric-acid fuel-cell energy system for telecommunication co-generation systems to reduce energy costs and help preserve the environment. Fuel cells are used to provide electrical power to telecommunication equipment and the heat energy that is generated is used by the absorption refrigerators to cool the telecommunication rooms throughout the year. We field-tested this fuel-cell energy system in a telephone office. Two heat recovery methods were applied in the test: one uses direct steam heat recovery from fuel-cell stack coolant to keep the heat recovery temperature high and to avoid requiring a heat exchanger for the recovery; the other uses heat recovery from the reformer exhaust gas that is directly in contact with the heat recovery water to recover heat more economically. Our field tests confirmed that the average efficiency of heat recovery from fuel-cell stack coolant is 16%, and from the reformer exhaust gas is 9% under 80-kW continuous operation. Maximum total efficiency including electrical power efficiency was confirmed to be about 73% under the condition of 100-kW and an S/C ratio of 2.5 in the winter period: heat recovery from the fuel-cell stack coolant was 23%, from the reformer exhaust gas was 10%, and from electrical conversion was about 40%. 9 refs., 12 figs., 1 tab.

  2. Development of practical application technology for photovoltaic power generation systems in fiscal 1997. Development of technologies to manufacture ultra high efficiency crystal compound solar cells; 1997 nendo taiyoko hatsuden system jitsuyoka gijutsu kaihatsu. Chokokoritsu kessho kagobutsu taiyo denchi no seizo gijutsu kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    Research and development was made for the purpose of achieving by the end of fiscal 2000 conversion efficiency of 30% or higher in a 5-cm square tandem solar cell using hypercomplex compound semiconductors, and establishing a new low-cost cell structure. In developing a large area cell manufacturing technology, a totally organic MOCVD process was used for epitaxial growth for forming the cell structure in manufacturing a 2.5-cm square GaInP single junction cell. Conversion efficiency of 13.1% was attained, but this is still insufficient as the conversion efficiency for a top cell. In the epitaxial growth in the GaAs cell structure, conversion efficiency as good as 22.1% was obtained. Also for a GaInAs cell being a bottom cell, a 2.5-cm square cell was fabricated on a trial basis. When a GaAs/GaAs laminated cell is formed by using the mechanical stacking method, the conversion efficiency has risen to 27.5% in total, thus having nearly achieved the goal for fiscal 1997. Fundamental discussion has begun on epitaxial growth of GaInNAs and nitride mixed crystal, which has a possibility as a new bottom cell material. (NEDO)

  3. Development of technology for thin substrate polycrystalline solar cells for practical use. Development of elementary technologies for low-cost polycrystalline cell modules; Usugata takessho taiyo denchi seizo gijutsu no jitsuyoka kenkyu. Takessho cell module tei cost ka yoso gijutsu kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Tatsuta, M. [New Energy and Industrial Technology Development Organization, Tokyo (Japan)

    1994-12-01

    This paper reports the study results on development of elementary technologies for low-cost polycrystalline cell modules in fiscal 1994. (1) On development of elementary technologies for mass production, fast surface machining, fast electrode forming and fast forming of junctions and antireflection films were studied. Surface machining by rotating grindstone was studied as fast cutting of fine grooves on Si substrates, resulting in possible fast machining superior in shape accuracy. Electrode properties equivalent or superior to previous ones were obtained by fast electrode forming using a fast printing/sintering equipment even at transfer speed 7.5 times as high as that of conventional methods. Simultaneous fast forming of junctions and antireflection films were achieved by heat treatment after deposition on Si substrate surfaces while heat-decomposing Ti and P compound gas. (2) On development of module structure, an optimum cell group angle, low reflection rate at glass surface, and fast wiring were studied. 5 figs., 2 tabs.

  4. Research on fabrication technology for thin film solar cells for practical use. Research on low-cost fabrication technology for large-area modules (Over-layered TCO on tempered glass for solar cell); Usumaku taiyo denchi seizo gijutsu no jitsuyoka kenkyu. Daimenseki module no tei cost seizo gijutsu (kyoka class fukugo tomei doden kiban seizo no gijutsu kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    Tatsuta, M. [New Energy and Industrial Technology Development Organization, Tokyo (Japan)

    1994-12-01

    This paper reports the study results on the fabrication technology of over-layered TCO on tempered glass in fiscal 1994. (1) On the fabrication technology of heat-resistant over-layered TCO, thermal deformation of TCO substrates was studied by both experiment and numerical computation. The thermal deformation increased with carrier concentration. As the observation result on change in lattice strain of heated TCO films by high-temperature X-ray diffraction, lattice strain was largely affected by thermal expansion. (2) On development of the low-temperature heat treatment method of TCO films, a technological prospect was obtained for fabrication of low-resistance TCO films by heat treatment without strength deterioration of tempered TCO substrates. (3) On development of cost reduction technology, the large-area CVD equipment was devised on the basis of the inline tempering method which tempers substrate glass by air cooling after formation of SnO2 film as fabrication method of tempered TCO. The TCO substrate tempered by air cooling could endure the drop test of 227g and 1.5m. 5 figs., 1 tab.

  5. Analysis and evaluation for practical application of photovoltaic power generation system. Research and development of elemental technologies for thin-type solar cells; Taiyoko hatsuden system jitsuyoka no tame no kaiseki hyoka. Usugata takessho taiyo denchi jitsuyoka no tame no kaiseki hyoka

    Energy Technology Data Exchange (ETDEWEB)

    Sekikawa, T.; Shimokawa, R.; Yui, N.; Takato, H.; Takahashi, T.; Ishii, K.; Suzuki, E.; Nagai, K.; Kawanami, H.; Tanimoto, J.; Sakuta, H.; Iwata, Y.; Saito, N.; Koyama, K.; Sawada, S. [Electrotechnical Laboratory, Tsukuba (Japan)

    1994-12-01

    Described herein are the results of the FY1994 research program for analysis and evaluation for thin substrate polycrystalline solar cells. In order to analyze the structures of the grain boundaries in and interfaces with the cell substrate, and their effects on electrical activity, the photoluminescence (PL) measurement which enables spectroscopic analysis is applied to electromagnetically cast Si crystals. There are good correlations among PL luminous intensity, MBIC output and dislocation density for the grain boundary which contains many strains and serves as the dislocation source, because carriers in such a grain boundary easily disappear to reduce its luminous intensity at the band ends. Concrete scenarios for realizing thin-film silicon solar cells of high efficiency are presented, based on the analysis of the light-contained thin-film silicon solar cells of high output current, made in the previous year on a trial basis. An alumina substrate of high reflectivity is produced by the experiments of combining various devices. It is expected to realize high output current for the thin-film solar cells. 3 figs.

  6. Development of technology for thin substrate polycrystalline solar cells for practical use. Development of manufacturing technologies for low-cost substrates (low-cost Si substrates); Usugata takessho taiyo denchi seizo gijutsu no jitsuyoka kenkyu. Tei cost kiban seizo gijutsu kaihatsu (usugata takessho kigan seizo gijutsu kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    Tatsuta, M. [New Energy and Industrial Technology Development Organization, Tokyo (Japan)

    1994-12-01

    This paper reports the study results on manufacturing technologies for low-cost high-quality Si substrates in fiscal 1994. (1) On the 220mm square type electromagnetic casting technology, development of fast stable casting technology was studied using the previously installed 220mm square type electromagnetic casting furnace. As a result, continuous stable casting was achieved at high casting speed up to 3.0mm/min. Any degradation of crystalline quality due to high speed casting was not found. (2) On the 350mm square type electromagnetic casting furnace, oscillation circuit constants were analyzed for design of the power source for No.4 electromagnetic casting furnace. In graphite heating experiment using the 350mm square type water-cooling copper crucible heated by 1000kW high-frequency power source, sufficient heat quantity was obtained for initial melting of Si. Any problems in Si melting were not found through Al block melting test. 6 figs.

  7. Leveling of battery load and extension of battery life by serial connection of electric double layer capacitors with batteries for electric vehicles. Experimental results on the small model; Denki jidoshayo denchi to denki nijuso capacitor no chokuretsu setsuzoku ni yoru denchi futan no heijunka oyobi denchijumyo no enshinka. (kogata model ni yoru jikken seika). Kogata model ni yoru jikken seika

    Energy Technology Data Exchange (ETDEWEB)

    Takehara, J.; Okubo, N.; Miyaoka, K. [Chugoku Electric Power Co. Inc., Hiroshima (Japan)

    1996-10-25

    The load leveling method of batteries for electric vehicles was studied for extension of a battery life and mileage every charging. Under large load fluctuation conditions such as deceleration and acceleration, use of electric power sources other than battery for peek load at acceleration can improve a battery life, output power capacity and mileage every charging. Combination of effective recovery of regenerative power at deceleration with its discharge at acceleration is one of the effective methods. The electric double layer capacitors are serially connected with the batteries, regenerative power is charged only into the capacitors, and both voltages of the battery and capacitor are applied to a power circuit. Battery load is reduced by load on the capacitor. Until the capacitor is re-charged by regenerative power after full discharge, power is supplied only by battery through a diode. Capacitor power is used as effectively as possible until approaching considerably low voltage. As peak load of the battery is reduced by 30%, the mileage increases by 5.7%, and the battery cycle life becomes 1.5 times longer. 7 refs., 5 figs., 3 tabs.

  8. Report on the participation in the international convention of the International Solar Enertgy Society held in Zimbabwe; Jinbabue deno Kokusai Taiyo Energy Gakkai sekai taikai ni sankashite

    Energy Technology Data Exchange (ETDEWEB)

    Katsube, K.

    1996-03-29

    The international convention of ISES (International Solar Energy Society) was held at Harare, the metropolis of Zimbabwe, South Africa, from September 11 to 15, 1995. 550 delegates from 55 countries attended the convention out of which 40 members were from Japan. The convention is to be held every two years. Zimbabwe has been promoting realistic policy called Zimbabwe socialism, and is called an A student. The ISES meeting was held for 5 days, and many programs such as general meeting, presentation by subcommittees, and conducted tours were proceeded everyday. The address of the President, the main event, took place for one hour in the evening of the second day. A proposal was made to the effect that it was necessary to strengthen ISES and to hold a solar energy summit meeting. Approximately 50 companies displayed products in the exhibition, but it was regrettable that Canon was the only company from Japan to display the products. Next convention is scheduled to be held in Taejon, Korea in August, 1997. 14 figs.

  9. Improved design of three-dimensional lens for low concentrator PV modules; Teishukogata taiyo denchiyo sanjigen lens no koseinoka ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Goma, S.; Yoshioka, K.; Saito, T. [Tokyo Univ. of Agriculture and Technology, Tokyo (Japan)

    1997-11-25

    Attention is paid to reduction in area required for solar cells by solar concentration as a means of solving cost limits of solar cells and unstable supply of Si materials. Low concentration solar cells are effective from the aspects of utilization of scattered light and unnecessary ray tracing. The optical concentration ratio was calculated of three-dimensional lens having design values of various north/south and east/west direction allowable incidence half angles. The three-dimensional lens are designed by cutting a rectangular parallelepiped by the two-dimensional composite elliptical plane designed by various allowable incidence half angles from two directions of north/south and east/west. Using Perez`s sky solar radiation models and meteorological data HASP, calculated were the annual accumulated global radiation ratio on an inclined surface and the optical efficiency. Calculated were the solar cell area ratio and solar concentration area ratio of the concentration type to obtain solar radiation the same as that of the planar type. From the optimization calculation, it was found that lens are optimal which have design values of north/south and east/west direction allowable incidence half angles of 30-70deg. The solar cell area ratio is 57% and the solar concentration area ratio is 1.2 times. It was found that by making the module area 1.2 times, more than 40% of the solar cells used can be saved. 5 refs., 8 figs.

  10. Study on the optimal control of the ground thermal storage system in the greenhouse. Part 4; Onshitsu ni okeru taiyo energy dochu chikunetsu system ni okeru saiteki seigyo ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Zheng, M. [Sanko Air Conditioning Co. Ltd., Osaka (Japan); Nakahara, N. [Kanagawa University, Yokohama (Japan)

    1996-10-27

    Three types of weight in both energy saving and optimum room temperature environment were changed to obtain the optimal control solution of the ground thermal storage system in a greenhouse. The relation diagram between the optimal solution of a performance function, and the state constraints and control function constraints was created in consideration of the energy term in a control function value area and the room temperature environment. As a result, the whole image of the performance function could be grasped in consideration of the energy term with inequality constraints and the room temperature environmental term in this study. The rate of a weighting factor in the performance function significantly influences the optimal solution. The influence on the optimal solution also changes when the optimal room temperature schedule differs. The influence that three types of rising algorithm exert on the convergence and converging speed was investigated. Superiority or inferiority occurs according to the space properties of a performance function. A zigzag method is most disadvantageous. The constraints can be converged to the optimal solution using an SUMT outer point method irrespective of the initial value. 6 refs., 6 figs., 4 tabs.

  11. Annual cycle solar energy utilization with seasonal storage. Part 8. Study on periodic steady state of the annual cycle energy system at a practical operation; Kisetsukan chikunetsu ni yoru nenkan cycle taiyo energy riyo system ni kansuru kenkyu. 8

    Energy Technology Data Exchange (ETDEWEB)

    Tanaka, H.; Okumiya, M. [Nagoya University, Nagoya (Japan)

    1997-11-25

    A study was made of the periodic steady state of the annual cycle solar energy system with seasonal heat storage at a practical operation. Cold heat in winter and warm heat in summer are stored in the seasonal storage tank, and these are each used in shift until when demand for cold/warm heat appears. Moreover, gap in quantity of cold/warm heat going in/out of the heat storage tank during a year is filled by natural energy such as solar energy, so that the system can be operated in annual cycles. Studies were conducted of the periodic unsteady term and the problem on lowering of performance during the term such as the periodic unsteady term of water temperature inside the seasonal heat storage tank and temperature of the soil around the storage tank, and the level of lowering of performance during the term, necessity of additional operation/control at the start of operation and aged deterioration of the system. Within the assumption, even if starting operation in any time of the year, the system could show the performance almost expected from the first operation year with no additional system operation and control required only at the start of operation. It is thought that the heat source selection control of heat pump largely contributes to this. 4 refs., 5 figs., 3 tabs.

  12. Achievement report for fiscal 1997 on development of technologies for practical photovoltaic system under New Sunshine Program. Manufacture of thin-film solar cell and of low-cost/large-area module (Formation of low-temperature film); 1997 nendo taiyoko hatsuden system jitsuyoka gijutsu kaihatsu seika hokokusho. Usukau taiyo denchi no seizo gijutsu kaihatsu, tei cost daimenseki module seizo gijutsu kaihatsu (teion maku keisei gijutsu kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    A polycrystalline Si thin film formation technology is developed, which uses the flux process in which a reaction occurs between the target crystal and a flux component which is eutectic. Using this process, a crystal grain relatively large in diameter is obtained at a relatively low temperature. This method is now attracting attention as one of the technologies for producing crystalline Si film for use in thin-film polycrystalline Si solar cells. Especially when Al is used for flux, since Al is automatically doped into the target crystalline Si film, it is expected that the resulting film will serve as the ground for a photoactive layer provided with the BSF (back surface field) function which is important for the improvement of solar cell efficiency. A polycrystalline Si thin film is formed on a 2cm times 2cm-large glass substrate at a temperature not higher than 600 degrees C. It is recognized that films selectively oriented towards the (111) or (100) plane are acquired when other processes are employed. It is expected that the said Al-doped film provides a ground on which a BSF function-provided photoactive layer will be formed. (NEDO)

  13. Simulation of PV/FC power hybrid system. Change of system capacity with load form factor; Taiyoko hatsuden nenryo denchi hybrid system no simulation. Fuka keijoritsu ni yoru system yoryo no henka

    Energy Technology Data Exchange (ETDEWEB)

    Sekiguchi, N.; Tani, T. [Science University of Tokyo, Tokyo (Japan)

    1997-11-25

    Study is conducted of a photovoltaic/fuel-cell hybrid system whose power storage is a hydrogen storage that uses a hydrogen absorbing alloy. In a simulation in this research, the solar cell conversion efficiency is changed from 15.0% to 21.0% and the fuel cell power conversion efficiency from 40.0% to 50.0%, and the resultant changes in the capacity and operation rate are investigated for each of the devices in the system. The findings follow. A 1.0% change in the solar cell conversion efficiency results in a 4.8kW change in the solar cell capacity and a 1.6-ton change in the hydrogen storage capacity. With a 1.0% change in the fuel cell power conversion efficiency, there is a 14.7kW change in the solar cell capacity and a 5.3-ton change in the hydrogen storage capacity. The fuel cell capacity is not dependent on the solar cell conversion efficiency or fuel cell power conversion efficiency but on the maximum load in each of the load form factors. The rate of occurrence of an operation rate of less than 30% is 54.7% both in DC/DC converter and hydrogen generator, 24.6% in fuel cells, and 16.7% in the DC/DC inverter. 7 refs., 7 figs., 1 tab.

  14. Solid electrolyte membranes and the system to produce hydrogen from thermally decomposed water by solar energy; Taiyo energy riyo ni yoru mizu no chokusetsu netsubunkai kara no suiso seizoyo

    Energy Technology Data Exchange (ETDEWEB)

    Nigara, K.; Watanabe, K.; Kawamura, K.; Kawada, T.; Mizusaki, J.; Ishigame, M. [Tohoku University, Sendai (Japan). Research Institute for Scientific Measurements

    1996-10-27

    For conversion of solar heat to transportable energy, hydrogen production by direct thermal decomposition of water using concentrated high-temperature solar heat was studied. Water vapor is injected into the tubular target with high melting point and high oxygen permeability at high temperature while heating the target by concentrated solar heat over 2000K. Oxygen in decomposed gas is discharged through an oxygen permeable membrane to extract hydrogen. Solid electrolyte is used as one of the target materials. Oxygen gas in the high-oxygen partial pressure site changes into oxygen ion by accepting two electrons at the target surface, and returns to neutral oxygen gas in the low-oxygen partial pressure site by discharging two electrons at the surface after permeation through oxygen vacancy. In the case of n-type solid electrolyte, to obtain constant permeation of a large amount of oxygen, flow of a large amount of electrons is indispensable in the opposite direction to oxygen ion. Among [(ZrO2)(1-x)(CeO2)x](0.9)(CaO)(0.1), materials of 0.4-0.5 in x seems to be useful as the target material. 7 refs., 7 figs.

  15. Hybrid utilization of solar energy. Part 2. Performance analyses of heating system with air hybrid collector; Taiyo energy no hybrid riyo ni kansuru kenkyu. 2. Kuki shunetsu hybrid collector wo mochiita danbo system no seino hyoka

    Energy Technology Data Exchange (ETDEWEB)

    Yoshinaga, M.; Okumiya, M. [Nagoya University, Nagoya (Japan)

    1996-10-27

    For the effective utilization of solar energy at houses, a heating system using an air hybrid collector (capable of simultaneously performing heat collection and photovoltaic power generation). As the specimen house, a wooden house of a total floor area of 120m{sup 2} was simulated. Collected air is fanned into a crushed stone heat accumulator (capable of storing one day`s collection) or into a living room. The output of solar cell arrays is put into a heat pump (capable of handling a maximum hourly load of 36,327kJ/h) via an inverter so as to drive the fan (corresponding to average insolation on the heat collecting plate of 10.7MJ/hm{sup 2} and heat collecting efficiency of 40%), and shortage in power if any is supplied from the system interconnection. A hybrid collector, as compared with the conventional air collector, is lower in thermal efficiency but the merit that it exhibits with respect to power generation is far greater than what is needed to counterbalance the demerit. When the hybrid system is in heating operation, there is an ideal heat cycle of collection, accumulation, and radiation when the load is light, but the balance between accumulation and radiation is disturbed when the load is heavy. 4 refs., 8 figs., 3 tabs.

  16. Effects on annual cost of solar/air-heat utilization system of carbon tax and interest rate for a residential house; Jutakuyo taiyo/taikinetsu riyo system no nenkan keihi ni oyobosu tansozei kinri no eikyo

    Energy Technology Data Exchange (ETDEWEB)

    Shen, Q.; Kenmoku, Y.; Sakakibara, T. [Toyohashi University of Technology, Aichi (Japan); Nakagawa, S. [Maizuru National College of Technology, Kyoto (Japan); Kawamoto, T. [Shizuoka University, Shizuoka (Japan). Faculty of Engineering

    1996-10-27

    In recent years, a system has been proposed that utilizes river heat, air-heat, exhaust heat from a cooler, etc., in addition to natural energy for the heat pump. With the introduction of such system, the amount of energy used and that of CO2 exhaust will be greatly reduced, but annual expenses will be increased as it stands. In order to improve the cost efficiency of the system, a proposal has been made for the introduction of an economic policy such as the carbon tax and a low interest financing system. With these matters in the background, the subject study predicts the production of solar cells in the future and, on the basis of this production, determines the price, conversion efficiency and equipment energy of solar cells in the future. Using these values and taking into consideration the introduction of the carbon tax and the low interest financing system, the optimum area was determined for solar cells and heat concentrators in a future residential solar/air-heat energy system. The carbon tax, being imposed on all CO2 discharges, had a large effect. Moreover, as the tax increased, annual expenses decreased for the solar/air-heat system. 3 refs., 6 figs.

  17. Simulation study on reduction of peak power demand and energy consumption in residential houses with solar thermal and PV systems; Taiyo energy riyo jutaku no fuka heijunka oyobi energy sakugen koka no simulation ni yoru kento

    Energy Technology Data Exchange (ETDEWEB)

    Endo, T. [Yokohama City Office, Yokohama (Japan); Udagawa, M. [Kogakuin Univ., Tokyo (Japan). Faculty of Engineering

    1995-11-20

    In this study, taking the all factors involved in the energy consumption in residential houses as subjects, the effectiveness of the solar PV system and solar thermal utilizing system in residential houses has been studied by simulating a model residential house considering the improvement of the residual environment in the future. Therefore, a model residual house is assumed, 18 kinds of combinations of construction style, cooling and heating type and solar energy utilizing form are assumed and year round simulation is carried out. The conclusions obtained by the simulation are as follows. The energy consumption in residential houses may decrease greatly by using a solar hot water supplying system. If combined with a solar PV system, the energy consumption in one year is about 8.7 to 9.7 MWh. The combined use of a solar thermal utilizing system and a PV system is more effective to reduce the second-time energy in comparison with the PV system only. 36% of the space heating energy consumption may be decreased by using the solar space heating system, but the decrease effect of the energy consumption of the solar space heating system is smaller than the solar hot water supplying system. 12 refs., 26 figs., 3 tabs.

  18. Solar energy and ecosystem. ; Japanized biosphere simulator (restructing of artificial ecosystem originating in the biosphere). Taiyo energy to ecosystem. ; Nipponban biosphere simulator (biosphere ni manabu jinkoteki ecosystem no kochiku)

    Energy Technology Data Exchange (ETDEWEB)

    Azuma, K. (Hazama Gumi, Ltd., Tokyo (Japan))

    1992-11-30

    The present report introduces Japanized biosphere (BS) simulator which was structured in order for the BS research committee composed of people of experience or academic standing and related industrials to elucidate the CO2 circulation behavior in the biological sphere of temperate zone. Its principal structural factors were ocean, grassland and broad-leaved tree forest, while river and lake were assumed to be those for the water circulation. Animals and plants which were necessary for the ecological system were taken as biological elements, while the installed system technology facilities covered the air, water, lighting, monitoring and energy. Those facilities are 40000m[sup 2], 60m and 2400000m[sup 3] in total area, height and volume, respectively on the site expanding to a scale of 20ha. Apart, land and ocean were arranged on the ground expanding to 2000000m[sup 2]. The quantification of different circulating substances is being studied, while the material balance is controlled so as to totally result in zero. Nobody can enter the facilities because of simplification in experimental model. The meteorological condition is monitored. The structuring was done by taking the biological sphere of BS-II Project, USA as an object. As the basic survey has been generally completed, an investigation team is on the point of being organized. 2 figs., 1 tab.

  19. and ni(ii)

    African Journals Online (AJOL)

    userpc

    NI(II) COMPLEXES WITH SCHIFF BASE DERIVED FROM SULPHANILAMINE AND. SALICYLALDEHYDE. ⃰Siraj, I. T. and ... with nickel(II) and cobalt(II) chloride in 2:1 mole ratio yielded Ni(II) and Co(II) complexes respectively. The synthesized .... coordinated ligand (coordination number) was determined using the relation ...

  20. Decay of 57Ni

    International Nuclear Information System (INIS)

    Santos Scardino, A.M. dos.

    1987-01-01

    The decay of 57 Ni to 57 Co was studied by gamma ray spectroscopy using both singles and coincidence spectra. The sources were obtained with the 58 Ni (Y,n) 57 Ni reaction. Natural metallic nickel was irradiated in the bremsstrahluhng beam of the linear accelerator of the Instituto de Fisica da Universidade de Sao Paulo with 30 MeV electrons. The singles espectra were taken with 104 cc HPGe detector and the coincidences espectra with 27 and 53cc Ge(Li) and 104 cc. HPGe detectors. The energies of transitions that follow the 57 Ni decay were measured using 56 Co as standard (which was obtained by (Y,np) reaction in 58 Ni) and taking into account the cascade cross-over relations. (author) [pt

  1. Submicron particles of Co, Ni and Co–Ni alloys

    Indian Academy of Sciences (India)

    Unknown

    meter (VSM). It may be noted that Co and Ni form a solid solution in the bulk, CoxNi1–x. For x 0⋅7, the alloy has a fcc structure, with a mixed regime in the intermediate compositions. The atomic moments in Co–Ni alloys increase linearly with Ni content (Tebble and Craik.

  2. Bridging exchange bias effect in NiO and Ni(core)@NiO(shell) nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Rinaldi-Montes, Natalia, E-mail: nataliarin@gmail.com [Departamento de Física, Universidad de Oviedo, E-33007 Oviedo (Spain); Gorria, Pedro [Departamento de Física & IUTA, EPI, Universidad de Oviedo, E-33203 Gijón (Spain); Martínez-Blanco, David [Servicios Científico-Técnicos, Universidad de Oviedo, E-33006 Oviedo (Spain); Fuertes, Antonio B. [Instituto Nacional del Carbón, CSIC, E-33080 Oviedo (Spain); Fernández Barquín, Luis [CITIMAC, Facultad de Ciencias, Universidad de Cantabria, E-39005 Santander (Spain); Puente-Orench, Inés [Instituto de Ciencia de Materiales de Aragón, CSIC-Universidad de Zaragoza and Institut Laue-Langevin, BP 156, F-38042 Grenoble Cedex 9 (France); Blanco, Jesús A. [Departamento de Física, Universidad de Oviedo, E-33007 Oviedo (Spain)

    2016-02-15

    Among all bi-magnetic core(transition metal)@shell(transition metal oxide) nanoparticles (NPs), Ni@NiO ones show an onset temperature for the exchange bias (EB) effect far below the Néel temperature of bulk antiferromagnetic NiO. In this framework, the role played by the magnetism of NiO at the nanoscale is investigated by comparing the microstructure and magnetic properties of NiO and Ni@NiO NPs. With the aim of bridging the two systems, the diameter of the NiO NPs (~4 nm) is chosen to be comparable to the shell thickness of Ni@NiO ones (~2 nm). The EB effect in Ni@NiO NPs is attributed to the exchange coupling between the core and the shell, with an interfacial exchange energy of ΔE~0.06 erg cm{sup −2}, thus comparable to previous reports on Ni/NiO interfaces both in thin film and NP morphologies. In contrast, the EB detected in NiO NPs is explained in a picture where uncompensated spins located on a magnetically disordered surface shell are exchange coupled to the antiferromagnetic core. In all the studied NPs, the variation of the EB field as a function of temperature is described according to a negative exponential law with a similar decay constant, yielding a vanishing EB effect around T~40–50 K. In addition, the onset temperature for the EB effect in both NiO and Ni@NiO NPs seems to follow a universal dependence with the NiO crystallite size. - Highlights: • Comparison of the exchange bias effect in NiO and Ni(core)@NiO(shell) nanoparticles. • Universal temperature dependence of the exchange bias effect. • Suggested similar physical origin of the effect in both systems. • Size and crystallinity of the NiO shell hold the key for exchange bias properties.

  3. OpenNI cookbook

    CERN Document Server

    Falahati, Soroush

    2013-01-01

    This is a Cookbook with plenty of practical recipes enriched with explained code and relevant screenshots to ease your learning curve. If you are a beginner or a professional in NIUI and want to write serious applications or games, then this book is for you. Even OpenNI 1 and OpenNI 1.x programmers who want to move to new versions of OpenNI can use this book as a starting point. This book uses C++ as the primary language but there are some examples in C# and Java too, so you need to have about a basic working knowledge of C or C++ for most cases.

  4. Achievement report for fiscal 1997 on research and development of solid electrolyte fuel cells; Kotai denkaishitsugata nenryo denchi no kenkyu kaihatsu 1997 nendo seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-07-01

    This paper describes the achievements in fiscal 1997 on research and development of solid electrolyte fuel cells. Fuji Electric has demonstrated possibilities of film type cells of predominantly metallic flat plate supporting type of a large-area cell lamination system, and seal-less stack structure. Sanyo Electric has discussed making thinner the composite cell lamination type anode, optimization in sintering temperature, and sealing materials. The Fine Ceramic Center has performed a 1,000-hour test on an La(Sr) MnO{sub 3}-YSZ electrode, in which A-site defect amount was decreased to 0.1-0.02 to stabilize micro-structure air electrodes for an extended period of time. Fujikura has discussed functional materials for high dispersion and slanting in a fuel electrode Ni/YSZ. Mitsubishi Heavy Industries has fabricated MgO-based fuel electrodes on a trial basis, and performed internal reformation and power generation tests by using full-size stacks. Murata Manufacturing Company has verified long-term power generation properties and stability of a three-layered co-sintered film of flat plate type. Mitsui Shipbuilding has reached a near final conclusion on the basic structure of gas separator cells. The Central Electric Power Research Institute has completed a conceptual design on a 300-MW class composite power generation system in which SOFC and gas turbines are combined. The Electric Power Development Company has discussed problems in SOFC composite power generation development using coal gasified fuel. (NEDO)

  5. FY 1999 Report on the technical results. Part 2-1. Development of fuel cell power generation technologies (Research and development of molten carbonate fuel cell power generation system); 1999 nendo nenryo denchi hatsuden gijutsu kaihatsu seika hokokusho. 2-1. Yoyu tansan'engata nenryo denchi (hatsuden system no kenkyu kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-05-01

    This research and development project is aimed at modification and improvement of the stacking technologies, to improve service life and performance of the molten carbonate fuel cell power generation system and reduce its cost. For the cross-flow type stack, optimization of the anode firing conditions leads to controlled reduction of the fine pores, and incorporation of the cathode with MgO successfully leads to controlled elution of NiO and Ni short-cut. For the separator, the service life is extended by treatment of the material with Al and controlling its rigidity. The cell life prediction method is improved to enhance its accuracy. The cell life of -4.3mV/1,000h is achieved by these technologies. For the parallel-flow type stack, the electrodes are improved to achieve the cell life of -1.4mV/1,000h, the technologies for producing the separator for a 1m{sup 2} class unit are developed, and the basic structures of a large-capacity stack are designed. For the internal reforming type, a 200kW class reforming stack is constructed, and operated for 5,259 hours. The causes for electrolyte loss are analyzed by developing the relationships between operating temperature and electrolyte loss, electrolyte mass and sustainability of the cell characteristics, and steam partial pressure over the cathode and electrolyte loss, and also by testing the Ni short-cut. (NEDO)

  6. Reduction mechanism of Ni2+ into Ni nanoparticles prepared from ...

    Indian Academy of Sciences (India)

    journal of. March 2009 physics pp. 577–586. Reduction mechanism of Ni2+ into Ni nanoparticles prepared from different precursors: Magnetic studies ... 2Department of Chemistry, Indian Institute of Technology, Kanpur 208 016, India ..... this work and Avanti, Analytical Chemistry Division, BARC for her help in cyclic.

  7. Reactive Ni/Ti nanolaminates

    International Nuclear Information System (INIS)

    Adams, D. P.; Bai, M. M.; Rodriguez, M. A.; McDonald, J. P.; Jones, E. Jr.; Brewer, L.; Moore, J. J.

    2009-01-01

    Nickel/titanium nanolaminates fabricated by sputter deposition exhibited rapid, high-temperature synthesis. When heated locally, self-sustained reactions were produced in freestanding Ni/Ti multilayer foils characterized by average propagation speeds between ∼0.1 and 1.4 m/s. The speed of a propagating reaction front was affected by total foil thickness and bilayer thickness (layer periodicity). In contrast to previous work with compacted Ni-Ti powders, no preheating of Ni/Ti foils was required to maintain self-propagating reactions. High-temperature synthesis was also stimulated by rapid global heating demonstrating low ignition temperatures (T ig )∼300-400 deg. C for nanolaminates. Ignition temperature was influenced by bilayer thickness with more coarse laminate designs exhibiting increased T ig . Foils reacted in a vacuum apparatus developed either as single-phase B2 cubic NiTi (austenite) or as a mixed-phase structure that was composed of monoclinic B19 ' NiTi (martensite), hexagonal NiTi 2 , and B2 NiTi. Single-phase, cubic B2 NiTi generally formed when the initial bilayer thickness was made small.

  8. Research and development of peripheral technology for photovoltaic power systems. Study of nickel-hydride storage battery for photovoltaic generation systems; Shuhen gijutsu no kenkyu kaihatsu. Taiyoko hatsuden`yo suiso denchi no kenkyu kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Tatsuta, M. [New Energy and Industrial Technology Development Organization, Tokyo (Japan)

    1994-12-01

    This paper reports the study results on R and D of nickel-hydride storage battery for photovoltaic generation systems in fiscal 1994. (1) On the study on low-cost electrode materials, the physical properties and electrode characteristics were studied of the prototype hydrogen absorbing alloys prepared by substituting Cu or Ni for Co in Mm(Ni-Co-Mn-Al)5 (Mm: mixture of rare earth elements). The result clarified that it is difficult to reduce Co content in the alloy to 0.4 atom or less. Simple heat treatment and milling processes in production of hydrogen absorbing alloy electrodes were achieved by adopting an improved metal mold and gas atomization method. Characteristics and cycle life of the Ni positive electrode prepared by applying active paste material of Ni(OH)2 were studied, however, the result showed only lives of nearly 300 cycles. (2) On the study on electrode structure for high-performance (long-life) battery, the 3-D porous metal electrode support was evaluated, and various battery configurations were studied. 11 figs., 1 tab.

  9. Annual cycle solar energy utilization with seasonal storage. Part 7. Examination on design and control of the system partially recovering exhaust heat of heat pump; Kisetsukan chikunetsu ni yoru nenkan cycle taiyo energy riyo system ni kansuru kenkyu. 7. Bubuntekina hainetsu kaishu wo koryoshita baai no sekkei seigyoho no kento

    Energy Technology Data Exchange (ETDEWEB)

    Tanaka, H.; Okumiya, M. [Nagoya University, Nagoya (Japan)

    1996-10-27

    The capacity and performance of the existing system that recovers the overall heating and cooling exhaust heat completely into a seasonal storage tank and the system that discharges the exhaust heat slightly to the outside and recovers it partially were compared and investigated. The system uses a central single-duct discharge system as an air-conditioning system. A heat pump and a flat-plate solar collector installed on the roof of a building are used as the heat source. The seasonal storage tank in the ground just under the building is a cylindrical water tank of 5 m deep with the concrete used as body. The upper surface of a storage tank is heat-insulated by a stylo-platform of 200 mm, and the lower side surface by a stylo-platform of 100 mm. Calculation when the difference in temperature used in a seasonal storage tank is set to 35{degree}C and 25{degree}C was performed for the system that has two control methods. The overall exhaust heat recovery system is almost the same in energy performance as the partial exhaust heat recovery system. The partial exhaust heat recovery system is more advantageous on the economic side. 4 refs., 6 figs., 3 tabs.

  10. Excitations of the unstable nuclei 48Ni and 49Ni

    International Nuclear Information System (INIS)

    Kamerdzhiev, S.P.; Tselyaev, V.I.

    2002-01-01

    The isoscalar E1 and E2 resonances in the proton-rich nuclei 48,49 Ni and the {f 7/2 x3 - } multiplet in 49 Ni have been calculated taking into account the single-particle continuum exactly. The analogous calculations for the mirror nuclei 48 Ca and 49 Sc are presented. The models used are the continuum random-phase approximation (RPA) for 48 Ni, 48 Ca and the odd RPA for 49 Ni, 49 Sc, where the latter has been developed recently and describes both single particle and collective excitations of an odd nucleus on a common basis. In all four nuclei, we obtained a distinct splitting of the isoscalar E1 resonance into 1(ℎ/2π)ω and 3(ℎ/2π)ω peaks at about 11 MeV and 30 MeV, respectively. The main part of the isoscalar E1 energy-weighted sum rule (EWSR) is exhausted by the 3(ℎ/2π)ω resonances. The 1(ℎ/2π)ω resonances exhaust about 35% of this EWSR in 48,49 Ni and about 22% in 48 Ca and 49 Sc. All seven {f 7/2 x3 - } multiplet members in 49 Ni are calculated to be in the 6-8 MeV energy region and have noticeable escape widths

  11. Nitriding behavior of Ni and Ni-based binary alloys

    Energy Technology Data Exchange (ETDEWEB)

    Fonovic, Matej

    2015-01-15

    Gaseous nitriding is a prominent thermochemical surface treatment process which can improve various properties of metallic materials such as mechanical, tribological and/or corrosion properties. This process is predominantly performed by applying NH{sub 3}+H{sub 2} containing gas atmospheres serving as the nitrogen donating medium at temperatures between 673 K and 873 K (400 C and 600 C). NH{sub 3} decomposes at the surface of the metallic specimen and nitrogen diffuses into the surface adjacent region of the specimen whereas hydrogen remains in the gas atmosphere. One of the most important parameters characterizing a gaseous nitriding process is the so-called nitriding potential (r{sub N}) which determines the chemical potential of nitrogen provided by the gas phase. The nitriding potential is defined as r{sub N} = p{sub NH{sub 3}}/p{sub H{sub 2}{sup 3/2}} where p{sub NH{sub 3}} and p{sub H{sub 2}} are the partial pressures of the NH{sub 3} and H{sub 2} in the nitriding atmosphere. In contrast with nitriding of α-Fe where the nitriding potential is usually in the range between 0.01 and 1 atm{sup -1/2}, nitriding of Ni and Ni-based alloys requires employing nitriding potentials higher than 100 atm{sup -1/2} and even up to ∞ (nitriding in pure NH{sub 3} atmosphere). This behavior is compatible with decreased thermodynamic stability of the 3d-metal nitrides with increasing atomic number. Depending on the nitriding conditions (temperature, nitriding potential and treatment time), different phases are formed at the surface of the Ni-based alloys. By applying very high nitriding potential, formation of hexagonal Ni{sub 3}N at the surface of the specimen (known as external nitriding) leads to the development of a compound layer, which may improve tribological properties. Underneath the Ni{sub 3}N compound layer, two possibilities exist: (i) alloying element precipitation within the nitrided zone (known as internal nitriding) and/or (ii) development of metastable and

  12. Electronic structure of Ni/sub 3/Al and Ni/sub 3/Ga alloys

    CERN Document Server

    Pong, W F; Chang, Y K; Tsai, M H; Hsieh, H H; Pieh, J Y; Tseng, P K; Lee, J F; Hsu, L S

    1999-01-01

    This work investigates the charge transfer and Al(Ga) p-Ni d hybridization effects in the intermetallic Ni/sub 3/Al(Ni/sub 3/Ga) alloy using the NiL/sub 3.2/- and K-edge and Al(Ga)K X-ray absorption near edge structure (XANES) measurements. We find that the intensity of white-line features at the NiL/sub 3.2/-edge in the Ni/sub 3/Al(Ni /sub 3/Ga) alloy decreased in comparison with that of pure Ni, which can be attributed to the enhancement of Ni3d states filling and the depletion of the density of Ni 3d unoccupied states in the Ni/sub 3 /Al(Ni/sub 3/Ga) alloy. Two clear features are also observed in the Ni/sub 3/Al(Ni/sub 3/Ga) XANES spectrum at the Al(Ga) K-edge, which can be assigned to the Al(Ga) unoccupied 3p (4p) states and their hybridized states with the Ni 3d/4sp states above the Fermi level in Ni/sub 3/Al(Ni/sub 3/Ga). The threshold at Al K-edge XANES for Ni/sub 3/Al clearly shifts towards higher photon energies relative to that of pure Al, indicating that Al loses charges upon forming Ni/sub 3 /Al. ...

  13. 111Cd PAC Study of Gd-Ni Intermetallic Compounds

    International Nuclear Information System (INIS)

    Presa, P. de la; Forker, M.

    2004-01-01

    This paper presents a perturbed angular correlation study of the magnetic and electric hyperfine interactions of 111 Cd on Gd sites of the Gd-Ni intermetallic compounds GdNi, GdNi 2 , GdNi 3 , Gd 2 Ni 7 , GdNi 5 and Gd 2 Ni 17 .

  14. Measurement of 59Ni and 63Ni by accelerator mass spectrometry at CIAE

    Science.gov (United States)

    Wang, Xiaoming; He, Ming; Ruan, Xiangdong; Xu, Yongning; Shen, Hongtao; Du, Liang; Xiao, Caijin; Dong, Kejun; Jiang, Shan; Yang, Xuran; Lan, Xiaoxi; Wu, Shaoyong; Zhao, Qingzhang; Cai, Li; Pang, Fangfang

    2015-10-01

    The long lived isotopes 59Ni and 63Ni can be used in many areas such as radioactive waste management, neutron dosimetry, cosmic radiation study, and so on. Based on the large accelerator and a big Q3D magnetic spectrometer, the measurement method for 59Ni and 63Ni is under development at the AMS facility at China Institute of Atomic Energy (CIAE). By using the ΔE-Q3D technique with the Q3D magnetic spectrometer, the isobaric interferences were greatly reduced in the measurements of 59Ni and 63Ni. A four anode gas ionization chamber was then used to further identify isobars. With these techniques, the abundance sensitivities of 59Ni and 63Ni measurements are determined as 59Ni/Ni = 1 × 10-13 and 63Ni/Ni = 2 × 10-12, respectively.

  15. Measurement of {sup 59}Ni and {sup 63}Ni by accelerator mass spectrometry at CIAE

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Xiaoming [China Institute of Atomic Energy, P.O. Box 275(50), Beijing 102413 (China); He, Ming, E-mail: minghe@ciae.ac.cn [China Institute of Atomic Energy, P.O. Box 275(50), Beijing 102413 (China); Ruan, Xiangdong [College of Physics and Technology, Guangxi University, Nanning 530004 (China); Xu, Yongning [China Institute of Atomic Energy, P.O. Box 275(50), Beijing 102413 (China); Shen, Hongtao [College of Physics and Technology, Guangxi Normal University, Guilin 541004 (China); Du, Liang; Xiao, Caijin; Dong, Kejun; Jiang, Shan; Yang, Xuran [China Institute of Atomic Energy, P.O. Box 275(50), Beijing 102413 (China); Lan, Xiaoxi [College of Physics and Technology, Guangxi University, Nanning 530004 (China); Wu, Shaoyong; Zhao, Qingzhang [China Institute of Atomic Energy, P.O. Box 275(50), Beijing 102413 (China); Cai, Li [College of Physics and Technology, Guangxi University, Nanning 530004 (China); Pang, Fangfang [College of Physics and Technology, Guangxi Normal University, Guilin 541004 (China)

    2015-10-15

    The long lived isotopes {sup 59}Ni and {sup 63}Ni can be used in many areas such as radioactive waste management, neutron dosimetry, cosmic radiation study, and so on. Based on the large accelerator and a big Q3D magnetic spectrometer, the measurement method for {sup 59}Ni and {sup 63}Ni is under development at the AMS facility at China Institute of Atomic Energy (CIAE). By using the ΔE-Q3D technique with the Q3D magnetic spectrometer, the isobaric interferences were greatly reduced in the measurements of {sup 59}Ni and {sup 63}Ni. A four anode gas ionization chamber was then used to further identify isobars. With these techniques, the abundance sensitivities of {sup 59}Ni and {sup 63}Ni measurements are determined as {sup 59}Ni/Ni = 1 × 10{sup −13} and {sup 63}Ni/Ni = 2 × 10{sup −12}, respectively.

  16. Ni4Ti3 precipitate structures in Ni-rich NiTi shape memory alloys

    Czech Academy of Sciences Publication Activity Database

    Holec, David; Bojda, Ondřej; Dlouhý, Antonín

    2008-01-01

    Roč. 481, Sp. Iss. (2008), s. 462-465 ISSN 0921-5093. [ESOMAT 2006. Bochum, 10.09.2006-15.09.2006] R&D Projects: GA ČR(CZ) GA106/05/0918 Institutional research plan: CEZ:AV0Z20410507 Keywords : NiTi shape memory alloys * Ni4Ti3 precipitates * Multi-step martensitic transformations Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 1.806, year: 2008

  17. Relation between shape of Ni-particles and Ni migration in Ni-YSZ electrodes – a hypothesis

    DEFF Research Database (Denmark)

    Mogensen, Mogens Bjerg; Hauch, Anne; Sun, Xiufu

    2016-01-01

    pressure (pH2O) gradient as previously observed [1], but in the present cases Ni seems to migrate up the pH2O gradient. However, it is also observed that there is a preceding phase in this Ni-YSZ electrode degradation, namely that the Ni-particles closest to the YSZ electrolyte loose contact to each other......This is an attempt to explain a phenomenon of total depletion of Ni next to the electrolyte in Ni-YSZ cermet electrodes in solid oxide electrolysis cells during electrolysis at high current density/overpotential. Intuitively, we would think that Ni would always migrate down the steam partial...

  18. Hexanuclear [Ni6L12] metallacrown framework consisting of NiS4 square-planar and NiS5 square-pyramidal building blocks

    NARCIS (Netherlands)

    Angamuthu, R.; Kooijman, H.; Lutz, M.; Spek, A.L.; Bouwman, E.

    2007-01-01

    The hexanuclear [Ni6L12] (2) wheel-type cluster adopts an unusual structural motif whereby four NiS4 square-planar and two NiS5 square-pyramidal units are conjoined by edge sharing; the NiS5 units resemble the Ni centre of the inactive state in the [NiFe] hydrogenase.

  19. Superstructure of NiAs

    International Nuclear Information System (INIS)

    Nozue, Tatsuhiro; Kobayashi, Hisao; Kamimura, Takashi; Yamaguchi, Yasuo

    2001-01-01

    The structural transition in NiAs was studied by neutron diffraction on the single crystalline sample. The crystal structure of NiAs has been reported to be bottom-centered orthorhombic with Cmc2 1 symmetry (niccolite-type). The measurement of temperature dependence of the powder X-ray diffraction revealed that NiAs undergoes a structural transition to the NiAs-type at T t =335 K. In present neutron diffraction experiment at room temperature, we observed the reflections indexed on the basis of the orthorhombic unit cell. The intensities of these reflections are qualitatively explained in terms of the niccolite-type structure with taking account of three domain structures, except for the weak reflections indexed as (001), (003) and (012). Then, the intensities of (001), (002) and (004) reflections were measured in temperature range of 20 to 420 K. The temperature dependences of (002) and (004) reflections qualitatively agree with those of the calculated intensities using the atomic positions of niccolite-type structure. However, the temperature dependence of (001) reflection shows the anomaly around T t , which suggests the symmetry of crystal structure of NiAs is not the Cmc2 1 symmetry. (author)

  20. Giant magnetoimpedance effect in sputtered single layered NiFe film and meander NiFe/Cu/NiFe film

    International Nuclear Information System (INIS)

    Chen, L.; Zhou, Y.; Lei, C.; Zhou, Z.M.; Ding, W.

    2010-01-01

    Giant magnetoimpedance (GMI) effect on NiFe thin film is very promising due to its application in developing the magnetic field sensors with highly sensitivity and low cost. In this paper, the single layered NiFe thin film and NiFe/Cu/NiFe thin film with a meander structure are prepared by the MEMS technology. The influences of sputtering parameters, film structure and conductor layer width on GMI effect in NiFe single layer and meander NiFe/Cu/NiFe film are investigated. Maximum of the GMI ratio in single layer and sandwich film is 5% and 64%, respectively. The results obtained are useful for developing the high-performance magnetic sensors based on NiFe thin film.

  1. The Ni-YSZ interface

    DEFF Research Database (Denmark)

    Jensen, Karin Vels

    content (99.8% Ni and 99.995% Ni) were used to examine the impact of impurities on the polarisation resistance and contact area morphology. The electropolished nickel wires were pressed against a polished 8 mol% YSZ surface. Extensive structural changes from a flat interface to a hill and valley structure...... between polarised and non-polarised samples. With pure nickel wires, however, the microstructures depended on the polarisation/non-polarisation conditions. At non-polarised conditions a hill and valley type structure was found. Anodic polarisation produced an up to 1 μm thick interface layer consisting...... of nano-sized YSZ particles with some Ni present. At cathodic polarisation both a granulated structure and a hill and valley structure resembling the structure of non-polarised samples were found. Small impurity ridges were surrounding the contact areas on non-polarised and cathodically polarised samples...

  2. Umreti ni mogla stara Sibila

    Directory of Open Access Journals (Sweden)

    Matej Hriberšek

    2001-07-01

    Full Text Available Izid omenjene knjige prof. Jožeta Kastelica predstavlja še enega od dogodkov v sklopu proslave 200-letnice Prešernovega rojstva. Delo je nastalo na osnovi njegove (kot sam pravi »Že davno napisane in neobjavljene« doktorske disertacije, ki jo je za izdajo v knjižni obliki dopolnil in obogatil ne le vsebinsko, ampak tudi oblikovno. Naslov sam skriva v sebi globoko simboliko; na eni strani kaže na simbolično povezavo med Sibilo, ki ni mogla umreti prej, dokler se ni dotaknila prsti iz svoje domovine (zgodba je povzeta po Serviju in Prešernom kot prvim imenom slovenskega parnasa ter aludira na njuno nesmrtnost, po drugi pa že sam po sebi kaže na Prešernovo izjemno poznavanje antike.

  3. ni potni list

    Directory of Open Access Journals (Sweden)

    Ana Krajnc

    1996-12-01

    Full Text Available Decembra 1994 je bila v Rimu velika mednarodna konferenca o permanentnem ali vse življenje trajajočem izobraževanju. Široki strokovni javnosti sta bila takrat prvič predstavljena tudi dva nova pojma: osebni učni načrt in učni potni list. Pri priči sta se prijela v teoriji in praksi - očitno sta bila oba predloga odsev potreb.

  4. Submicron particles of Co, Ni and Co–Ni alloys

    Indian Academy of Sciences (India)

    Home; Journals; Bulletin of Materials Science; Volume 24; Issue 5. Submicron particles of Co, Ni and ... bulk values. The alloy particles follow a trend similar to the bulk alloys. ... G U Kulkarni1. Chemistry and Physics of Materials Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Bangalore 560 064, India ...

  5. Revisiting El Niño Modokis

    Science.gov (United States)

    Marathe, Shamal; Ashok, Karumuri; Swapna, P.; Sabin, T. P.

    2015-12-01

    The suggestion that there exist two types of El Niño in the tropical Pacific has generated a debate in the community. Applying various linear and non-linear approaches and composite analysis technique on observed and reanalyzed climate datasets primarily for the 1950-2010 period, we revisit the variability of the tropical Pacific in the light of this debate. Our objective is to examine whether the proposed El Niño Modokis need a classification distinct from canonical El Niños. Even if the distinction is subject to short data records, we demonstrate that the El Niño Modoki events indeed display a seasonal evolution and teleconnections different from the canonical El Niños, and that the distinction is not subject to inclusion of the two extreme El Niños 1982 and 1997 as canonical El Niños. We show that the El Niño Modoki events are not an artifact associated with the orthogonality constraint associated with the EOF technique. Our cluster analysis shows that evolutions of the canonical El Niño and El Niño Modokis through various seasons differ from one another. Importantly, the dynamic and thermodynamic air-sea coupling strength is distinctly different between the El Niño Modoki and the canonical El Niño events. We find that, dynamic feedback intensity is stronger for El Niño Modoki (canonical El Niño) during boreal summer (winter); though the air-sea coupling strength, a major contributor to Bjerknes feedback, is maximum for Modokis during the developing stages, it decreases thereafter. In case of thermodynamic feedback intensity, SST-wind-evaporation feedback is dominant for El Niños while SST-SHF feedback is important during El Niño Modokis. However, we find that the thermodynamic feedback values significantly differ across the flux datasets.

  6. Laser alloyed Al-Ni-Fe coatings

    CSIR Research Space (South Africa)

    Pityana, SL

    2008-10-01

    Full Text Available The aim of this work was to produce crack-free thin surface layers consisting of binary (Al-Ni, Al-Fe) and ternary (Al-Ni-Fe) intermetallic phases by means of a high power laser beam. The laser surface alloying was carried out by melting Fe and Ni...

  7. Nanostructure analysis of friction welded Pd-Ni-P/Pd-Cu-Ni-P metallic glass interface

    International Nuclear Information System (INIS)

    Ohkubo, T.; Shoji, S.; Kawamura, Y.; Hono, K.

    2005-01-01

    Friction welded Pd 40 Ni 40 P 20 /Pd 40 Cu 30 Ni 10 P 20 metallic glass interface has been characterized by energy filtering transmission electron microscopy. The interface is fully amorphous with a gradual compositional change of Cu and Ni in the range of 30 nm. By annealing above T g , the interdiffusion of Cu and Ni progressed in the supercooled liquid region, and the crystallization occurred from the Pd 40 Ni 40 P 20 glass

  8. Niños investigadores

    OpenAIRE

    Manfred Liebel

    2007-01-01

    EN LA SOCIOLOGÍA INFANTIL, EL PRINCIPIO DE HACER PARTICIPAR A NIÑAS Y NIÑOS en los procesos de investigación está ampliamente reconocido. Tomando como punto de partida ese principio de participación, el presente aporte analiza la pregunta de en qué medida y de qué manera los niños mismos pueden actuar como investigadores. A fin de apreciar en lo justo la perspectiva de los niños, el presente trabajo aboga por que –con el debido acompañamiento de personas adultas– la investigación esté en mano...

  9. Flowsheet for 63Ni production

    International Nuclear Information System (INIS)

    Williams, D.F.; Knauer, J.B.; O'Kelley, G.D.; Wiggins, J.T.; Porter, C.E.

    1992-01-01

    The production of large quantities of high specific activity 63 Ni (>10Ci/g) requires both a highly enriched 62 Ni target and a long irradiation period at high neutron flux. Trace impurities in the nickel and associated target materials are also activated and account for a significant fraction of the discharged activity and essentially all of the gamma activity. While most of these undesirable activation products (mainly transition metals) can be easily removed as chloride complexes during anion exchange, chromium, present as 51 Cr, and manganese, present as 54 Mn, are exceptions and require solvent extraction of the in-cell product to achieve the desired purity. In addition to summarizing the current development and production experience, optimized flowsheets are discussed

  10. niños preescolares

    Directory of Open Access Journals (Sweden)

    Claudia Rosario Portilla Ramírez

    2007-01-01

    Full Text Available Este estudio explora la relación entre la escritura y la comprensión de la referencia a través de una tarea de sinonimia en niños entre 5 y 6 años de edad, de origen latinoamericano, escolarizados en Barcelona (España. Las variables relacionadas con la tarea de sinonimia fueron (a la comprensión de la entidad lingüística nombre y (b el nivel de conceptualización de la escritura de los niños y la presencia de etiquetas escritas durante la tarea. Para la tarea de sinonimia se utilizaron pares de sinónimos dialectales del español (de Latinoamérica y de la Península Ibérica. Los resultados mostraron una diferenciación en el razonamiento de los niños, la cual dependía de la comparación entre lenguaje oral y lenguaje escrito en el desarrollo de la tarea, evidenciando una mayor aceptación de la sinonimia en la modalidad de lenguaje oral que en la modalidad de lenguaje escrito.

  11. Exclusive study of Ni+Ni and Ni+Au central collisions: phase coexistence and spinodal decomposition; Etude exclusive des collisions centrales Ni+Ni et Ni+Au: coexistence de phase et decomposition spinodale

    Energy Technology Data Exchange (ETDEWEB)

    Guiot, B

    2002-12-01

    The INDRA multidetector allowed us to study the Ni+Ni collisions at 32A MeV and the Ni+Au collisions at 52,4 MeV. Central collisions leading to 'quasi-fused' systems were isolated using multidimensional analysis techniques: the Discriminant Analysis and the Principal Component Analysis. Comparison with a statistical model shows that the selected events are compatible with thermodynamical equilibrium. The average thermal excitation energy is 5A MeV for both systems. Calculations of heat capacities show that the deexcitation of the hot sources are akin to a liquid-gas phase transition of nuclear matter. Indeed heat capacities exhibit a negative branch as expected for a phase transition of a finite system. The dynamics of this phase transition has been investigated by applying the charge correlation method. An enhanced production of events with equal-sized fragments has been evidenced for Ni+Au at 52A MeV. No signal was found for Ni+Ni at 32A MeV. Finally this method was improved by taking into account the total charge conservation. The signal is seen more clearly for Ni+Au at 52A MeV, but is ambiguous for Ni+Ni at 32A MeV. The path followed in the state diagram, or the involved time scales, seem to be different for these systems. (authors)

  12. Processing and Mechanical Properties of Directionally Solidified NiAl/NiAlTa Alloys

    Science.gov (United States)

    Johnson, D. R.; Oliver, B. F.; Noebe, R. D.; Whittenberger, J. D.

    1994-01-01

    Promising creep strengths were found for a directionally solidified NiAl-NiAlTa alloy when compared to other NiAl based intermetallics. The directionally solidified alloy had an off-eutectic composition that resulted in microstructures consisting of NiAl dendrites surrounded by aligned eutectic regions. The room temperature toughness of the two phase alloy was similar to that of polycrystalline NiAl even with the presence of the brittle Laves phase NiAlTa. Alloying additions that may improve the room temperature toughness by producing multiphase alloys are discussed.

  13. Transparent nanostructured electrodes: Electrospun NiO nanofibers/NiO films

    Energy Technology Data Exchange (ETDEWEB)

    Lamastra, F.R. [Italian Interuniversity Consortium on Materials Science and Technology (INSTM), Research Unit Roma Tor Vergata, Via del Politecnico 1, 00133 Rome (Italy); Nanni, F. [Italian Interuniversity Consortium on Materials Science and Technology (INSTM), Research Unit Roma Tor Vergata, Via del Politecnico 1, 00133 Rome (Italy); Department of Enterprise Engineering, University of Rome Tor Vergata, Via del Politecnico 1, 00133 Rome (Italy); Menchini, F. [ENEA, CR Casaccia, Via Anguillarese 301, 00123 Rome (Italy); Nunziante, P. [Italian Interuniversity Consortium on Materials Science and Technology (INSTM), Research Unit Roma Tor Vergata, Via del Politecnico 1, 00133 Rome (Italy); Department of Chemical Sciences and Technologies, University of Rome Tor Vergata, Via della Ricerca Scientifica 1, 00133 Rome (Italy); Grilli, M.L., E-mail: marialuisa.grilli@enea.it [ENEA, CR Casaccia, Via Anguillarese 301, 00123 Rome (Italy)

    2016-02-29

    Polyvinylpyrrolidone (PVP)/nickel(II) acetate precursor fibers were deposited by electrospinning directly on radio frequency sputtered thin Ni and NiO films grown on quartz substrate, starting from Ni(II) acetate and PVP solution in ethanol. The samples were calcined in air in the temperature range 400–500 °C to obtain transparent and conductive p-type NiO nanofibers on NiO films. A higher density of nanofibers was obtained on Ni/quartz substrates, as compared to NiO/quartz ones, demonstrating the feasibility of fiber adhesion directly to an insulating substrate previously coated by a thin Ni layer. Samples were characterized by field emission-scanning electron microscopy, X-ray diffraction, spectrophotometric and resistance measurements. - Highlights: • Nanostructured electrodes: electrospun NiO nanofibers/NiO films were fabricated. • NiO fibers were directly grown on insulating substrate coated by thin Ni or NiO films. • Good quality crystalline fibers were obtained at low calcination temperatures. • Transparent and conductive p-type electrodes were fabricated.

  14. Atomistic calculations of hydrogen interactions with Ni3Al grain boundaries and Ni/Ni3Al interfaces

    International Nuclear Information System (INIS)

    Baskes, M.I.; Angelo, J.E.; Moody, N.R.

    1995-01-01

    Embedded Atom Method (EAM) potentials have been developed for the Ni/Al/H system. The potentials have been fit to numerous properties of this system. For example, these potentials represent the structural and elastic properties of bulk Ni, Al, Ni 3 Al, and NiAl quite well. In addition the potentials describe the solution and migration behavior of hydrogen in both nickel and aluminum. A number of calculations using these potentials have been performed. It is found that hydrogen strongly prefers sites in Ni 3 Al that are surrounded by 6 Ni atoms. Calculations of the trapping of hydrogen to a number of grain boundaries in Ni 3 Al have been performed as a function of hydrogen chemical potential at room temperature. The failure of these bicrystals under tensile stress has been examined and will be compared to the failure of pure Ni 3 Al boundaries. Boundaries containing a preponderance of nickel are severely weakened by hydrogen. In order to investigate the potential embrittlement of γ/γ' alloys, trapping of hydrogen to a spherical Ni 3 Al precipate in nickel as a function of chemical potential at room temperature has been calculated. It appears that the boundary is not a strong trap for hydrogen, hence embrittlement in these alloys is not primarily due to interactions of hydrogen with the γ/γ interface

  15. Exclusive study of Ni+Ni and Ni+Au central collisions: phase coexistence and spinodal decomposition

    International Nuclear Information System (INIS)

    Guiot, B.

    2002-12-01

    The INDRA multidetector allowed us to study the Ni+Ni collisions at 32A MeV and the Ni+Au collisions at 52,4 MeV. Central collisions leading to 'quasi-fused' systems were isolated using multidimensional analysis techniques: the Discriminant Analysis and the Principal Component Analysis. Comparison with a statistical model shows that the selected events are compatible with thermodynamical equilibrium. The average thermal excitation energy is 5A MeV for both systems. Calculations of heat capacities show that the deexcitation of the hot sources are akin to a liquid-gas phase transition of nuclear matter. Indeed heat capacities exhibit a negative branch as expected for a phase transition of a finite system. The dynamics of this phase transition has been investigated by applying the charge correlation method. An enhanced production of events with equal-sized fragments has been evidenced for Ni+Au at 52A MeV. No signal was found for Ni+Ni at 32A MeV. Finally this method was improved by taking into account the total charge conservation. The signal is seen more clearly for Ni+Au at 52A MeV, but is ambiguous for Ni+Ni at 32A MeV. The path followed in the state diagram, or the involved time scales, seem to be different for these systems. (authors)

  16. Microstructural investigations of Ni and Ni2Al3 coatings exposed in biomass power plants

    DEFF Research Database (Denmark)

    Wu, D. L.; Dahl, K. V.; Christiansen, T. L.

    2018-01-01

    temperature pack cementation. After exposure, microstructural investigations were performed by light optical and electron microscopy (SEM-EDS). Electroplated Ni coatings were not protective in straw firing power plants and exhibited similar corrosion morphology as uncoated tubes. For Ni2Al3 coatings......The present work investigates the corrosion resistance of Ni and Ni2Al3 coated austenitic stainless steel (TP347H) tubes, which were exposed in a biomass-fired boiler with an outlet steam temperature of 540 °C for 6757 h. The Ni2Al3 coating was produced by electroplating Ni followed by low......, the nickel aluminide layer was no longer adherent to the tube and was only found within the deposit. However, Ni2Al3 coatings had provided some protection compared to uncoated and Ni coated tubes. The formation of nickel chloride binds aggressive chlorine and slows down the active oxidation mechanism...

  17. Analisis Interferensi dalam Kelas Kata Keishiki Meishi Khususnya Penggunaan Tame Ni dan You Ni

    Directory of Open Access Journals (Sweden)

    Nalti Novianti

    2008-05-01

    Full Text Available Article aimed to find out the amount of interference in the translation using tame ni and you ni. The research used analysis description. Data were taken by giving a test to 20 student from the Japanese Department, Bina Nusantara University. The result showed that there is some interference in the exercises in the test given to the respondents. It is concluded that the interference occurs because many students do not understand the differences in using tame ni anda you ni.

  18. Formation enthalpy of NiBe and Ni5Be21

    International Nuclear Information System (INIS)

    Ivanov, M.I.; Karpova, T.F.; Dalago, N.Yu.

    1981-01-01

    The method of dissolution calorimetry is used to determine standard enthalpies of NiBe and Ni 5 Be 21 formation, which are 84.8+-2.2 and (-669+-37)kJ/mol. The enthalpy values of NiBe and Ni 5 Be 21 at 331 K are shown to coincide (within the limits of errors of these values) with the values at the standard temperature of 298.15 K [ru

  19. Composite Ni/NiO-Cr2O3Catalyst for Alkaline Hydrogen Evolution Reaction.

    Science.gov (United States)

    Bates, Michael K; Jia, Qingying; Ramaswamy, Nagappan; Allen, Robert J; Mukerjee, Sanjeev

    2015-03-12

    We report a Ni-Cr/C electrocatalyst with unprecedented mass-activity for the hydrogen evolution reaction (HER) in alkaline electrolyte. The HER kinetics of numerous binary and ternary Ni-alloys and composite Ni/metal-oxide/C samples were evaluated in aqueous 0.1 M KOH electrolyte. The highest HER mass-activity was observed for Ni-Cr materials which exhibit metallic Ni as well as NiO x and Cr 2 O 3 phases as determined by X-ray diffraction (XRD) and X-ray absorption spectroscopy (XAS) analysis. The onset of the HER is significantly improved compared to numerous binary and ternary Ni-alloys, including Ni-Mo materials. It is likely that at adjacent Ni/NiO x sites, the oxide acts as a sink for OH ads , while the metallic Ni acts as a sink for the H ads intermediate of the HER, thus minimizing the high activation energy of hydrogen evolution via water reduction. This is confirmed by in situ XAS studies that show that the synergistic HER enhancement is due to NiO x content and that the Cr 2 O 3 appears to stabilize the composite NiO x component under HER conditions (where NiO x would typically be reduced to metallic Ni 0 ). Furthermore, in contrast to Pt, the Ni(O x )/Cr 2 O 3 catalyst appears resistant to poisoning by the anion exchange ionomer (AEI), a serious consideration when applied to an anionic polymer electrolyte interface. Furthermore, we report a detailed model of the double layer interface which helps explain the observed ensemble effect in the presence of AEI.

  20. Composite Ni/NiO-Cr2O3 Catalyst for Alkaline Hydrogen Evolution Reaction

    Energy Technology Data Exchange (ETDEWEB)

    Bates, MK; Jia, QY; Ramaswamy, N; Allen, RJ; Mukerjee, S

    2015-03-12

    We report a Ni-Cr/C electrocatalyst with unpreeedented massactivity for the hydrogen evolution reaction (HER). in alkaline electrolyte. The HER Oietics of numerous binary and ternary Ni-alloys and composite Ni/metal-euride/C samples were evaluated in aquebus 0.1 M KOH electrolyte. The highest HER mass-activity was observed for Ni-Cr materials which exhibit metallic Ni as well as NiOx and Cr2O3 phases as determined by X-ray diffraction (XRD) and X-ray absorption spectroscopy (XAS) analysis. The onset of the HER is significantly improved compared to munerous binary dor ternary Ni-alloys, inCluding Ni Mg materials. It is likely that at adjacent Ni/NiOx sites, the oxide acts as a sink for OHads, while the metallic Ni acts as a, sink for the H-ads, intermediate of the HER, thus minimizing the high activation energy of hydrogen evolution via water reduction. This is confirmed by in situ XAS studies that show that the synergistic HER enhancement is due to NiO content and that the Cr2O3 appears to stabilize the composite NiO component-under HER conditions (where NiOx would typically be reduced to metallic Ni-0). Furthermore, in contrast to Pt, the Ni(O-x)/Cr2O3 catalyst appears resistant to poisoning by the anion.exchange ionomer (AEI), a serloua consideration when applied to an anionic polymer electrolyte interface. Furthermore, we report a: detailed model of the double layer interface which helps explain the observed ensemble effect in the presence of AEI.

  1. The Ni-Al-Hf Multiphase Diffusion

    Directory of Open Access Journals (Sweden)

    Romanowska J.

    2016-06-01

    Full Text Available The generalized Darken method was applied to simulate the diffusion between γ-Ni| γ’-Ni3Al and γ’-Ni3Al|β-NiAl interfaces. The results of calculations were compared with the experimental concentration’s profiles of nickel, aluminum and hafnium in aluminide and hafnium doped aluminide coatings deposited by the CVD and PVD methods on pure nickel. The method deals with the Wagner’s integral diffusion coefficients and thermodynamic data - activities of components. The experimental results agree with the simulated ones.

  2. Effects of Ni vacancy, Ni antisite, Cr and Pt on the third-order elastic constants and mechanical properties of NiAl

    KAUST Repository

    Wu, Shaohua

    2014-12-01

    Effects of Ni vacancy, Ni antisite in Al sublattice, Cr in Al sublattice, Pt in Ni sublattice on the second-order elastic constants (SOECs) and third-order elastic constants (TOECs) of the B2 NiAl have been investigated using the first-principles methods. Lattice constant and the SOECs of NiAl are in good agreement with the previous results. The brittle/ductile transition map based on Pugh ratio G/B and Cauchy pressure Pc shows that Ni antisite, Cr, Pt and pressure can improve the ductility of NiAl, respectively. Ni vacancy and lower pressure can enhance the Vickers hardness Hv of NiAl. The density of states (DOS) and the charge density difference are also used to analysis the effects of vacancy, Ni antisite, Cr and Pt on the mechanical properties of NiAl, and the results are in consistent with the transition map. © 2014 Elsevier Ltd. All rights reserved.

  3. Achievement report (edition B) for fiscal 1999 on development of technology to manufacture coal gas for fuel cells. Studies by using pilot test facilities (Volumes for equipment fabrication and constructions, and trial run design); 1999 nendo seika hokokusho (B ban). Nenryo denchi you sekitan gas seizo gijutsu kaihatsu - Pilot setsubi ni yoru kenkyu (kisokoji kiki seisaku hen shiunten sekkei hen)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    With an objective to develop a coal gas manufacturing system for fuel cells, research and development has been performed on a oxygen-blown coal gasifier and researches on a technology to purify gases for fuel cells. This paper summarizes the achievements in fiscal 1999. The current fiscal year has performed, among other the pilot plant construction works, execution of the above-the-ground constructions for the operation center and compressor room building, construction of the cooling water tanks, and partial improvement of roads in the plant site. In the gasifier facilities, items of equipment were fabricated, some of the outsourced articles were procured, and the installations thereof were carried out. For the gas purifying equipment, installation of the gas analyzer room was executed. In the trial run design, discussions were given on the systematic improvements in the test items, the gas sampling procedures, the unit protecting interlock, and the facility protecting logic. For the trial run design, establishment has been implemented on the efficient and functional test plans by establishing priority on the tests to be executed, so that the development items demanded in the pilot test and research can be achieved within the limited test processes. (NEDO)

  4. Fiscal 1997 report on the results of the international standardization R and D. R and D of the standardization of a method to test acceleration life of phosphorous acid fuel cells; 1997 nendo seika hokokusho kokusai hyojun soseigata kenkyu kaihatsu. Rinsangata nenryo denchi no kasoku jumyo shiken hoho no hyojunka ni kansuru kenkyu kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    As for fuel cells, which are expected as a new clean energy, the R and D are being proceeded with in various fields of the world, but the standardization has not been made both in Japan and abroad. In Japan, the situation is that the information on technical terms, indication method, performance test method, and environment/safety test methods of the phosphorous acid fuel cell power generation is publicly spread. In relation to the international promotion of fuel cells to be predicted, it is necessary to internationally standardize cells themselves which are a key component of fuel cell power generation facilities. Phosphorous acid fuel cells are expected of the earliest commercialization of all, but the common test method to evaluate life characteristics of the cell stack has not been established yet. In the R and D, for the purpose of internationally standardizing test methods to evaluate life characteristics of the cell stack, a study on the acceleration life test method of phosphoric acid fuel cells was conducted in terms of the technical trend, data, standard, etc. A plan was prepared on general rules of the method to test acceleration life at the cell reaction part of the small cell, and activities also were started for setting up a technical committee for the fuel cell power system in President`s Advisory Committee on Future Technology. 29 figs., 20 tabs.

  5. Contexto Familiar: Diferencias Conductuales entre Niños y Niñas

    Directory of Open Access Journals (Sweden)

    María Aurelia Ramírez Castillo

    2005-01-01

    Full Text Available En este trabajo se investigan las diferencias por género en problemas de conducta. En una muestra de 200 sujetos (niños y niñas en tre 5 y 18 años de Granada (España, los resultados concluyen que los niños tienen más problemas de conducta delictiva que las niñas. Cuando existen conflictos matrimoniales y prácticas de crianza negativas, de nuevo los niños tienen más problemas externos que las niñas. En este trabajo se investigan las diferencias por género en problemas de conducta. En una muestra de 200 sujetos (niños y niñas en tre 5 y 18 años de Granada (España, los resultados concluyen que los niños tienen más problemas de conducta delictiva que las niñas. Cuando existen conflictos matrimoniales y prácticas de crianza negativas, de nuevo los niños tienen más problemas externos que las niñas.

  6. Porous NiTi shape memory alloys produced by SHS: microstructure and biocompatibility in comparison with Ti2Ni and TiNi3.

    Science.gov (United States)

    Bassani, Paola; Panseri, Silvia; Ruffini, Andrea; Montesi, Monica; Ghetti, Martina; Zanotti, Claudio; Tampieri, Anna; Tuissi, Ausonio

    2014-10-01

    Shape memory alloys based on NiTi have found their main applications in manufacturing of new biomedical devices mainly in surgery tools, stents and orthopedics. Porous NiTi can exhibit an engineering elastic modulus comparable to that of cortical bone (12-17 GPa). This condition, combined with proper pore size, allows good osteointegration. Open cells porous NiTi was produced by self propagating high temperature synthesis (SHS), starting from Ni and Ti mixed powders. The main NiTi phase is formed during SHS together with other Ni-Ti compounds. The biocompatibility of such material was investigated by single culture experiment and ionic release on small specimen. In particular, NiTi and porous NiTi were evaluated together with elemental Ti and Ni reference metals and the two intermetallic TiNi3, Ti2Ni phases. This approach permitted to clearly identify the influence of secondary phases in porous NiTi materials and relation with Ni-ion release. The results indicated, apart the well-known high toxicity of Ni, also toxicity of TiNi3, whilst phases with higher Ti content showed high biocompatibility. A slightly reduced biocompatibility of porous NiTi was ascribed to combined effect of TiNi3 presence and topography that requires higher effort for the cells to adapt to the surface.

  7. Dynamic recovery in nanocrystalline Ni

    International Nuclear Information System (INIS)

    Sun, Z.; Van Petegem, S.; Cervellino, A.; Durst, K.; Blum, W.; Van Swygenhoven, H.

    2015-01-01

    The constant flow stress reached during uniaxial deformation of electrodeposited nanocrystalline Ni reflects a quasi-stationary balance between dislocation slip and grain boundary (GB) accommodation mechanisms. Stress reduction tests allow to suppress dislocation slip and bring recovery mechanisms into the foreground. When combined with in situ X-ray diffraction it can be shown that grain boundary recovery mechanisms play an important role in producing plastic strain while hardening the microstructure. This result has a significant consequence for the parameters of thermally activated glide of dislocations, such as athermal stress and activation volume, which are traditionally derived from stress/strain rate change tests

  8. Morphological control of Ni/NiO core/shell nanoparticles and production of hollow NiO nanostructures

    International Nuclear Information System (INIS)

    Chopra, Nitin; Claypoole, Leslie; Bachas, Leonidas G.

    2010-01-01

    Chemical synthesis coupled with a microwave irradiation process allowed for the control of size (6-40 nm), shape, and shell thickness of Ni/NiO core/shell nanoparticles. In this unique synthetic route, the size of Ni nanoparticles (NiNPs) was strongly influenced by the nickel salt-to-stabilizer ratio and the amount of the stabilizer. Interestingly, it was observed that the shape of the nanoparticles was altered by varying the reaction time, where longer reaction times resulted in annealing effects and rupture of the stabilizer micelle leading to distinct shapes of Ni/NiO core/shell nanostructures. Product cooling rate was another important parameter identified in this study that not only affected the shape, but also the crystal structure of the core/shell nanoparticles. In addition, a simple and cost-effective method of microwave irradiation of NiNPs led to the formation of distinctly shaped hollow NiO nanoparticles. These high surface area core/shell nanoparticles with well-controlled morphologies are important and can lead to significant advancement in the design of improved fuel cells, electrochromic display devices, and catalysis systems.

  9. .';.:NI~

    African Journals Online (AJOL)

    He mentions, inter alia, the share he had in the passing of Defence Act no 44 of 1957 and expresses his gratitude to God for saving his life and allowing him to ...... gevolg dat vier van ons seniors, brigadiers rang behou het. Een offisier, wat betreklik junior was voor die oorlog, is ook brigadiersrang toegeken, sodat hy in een ...

  10. Development in fiscal 1999 of technologies to put photovoltaic power generation systems into practical use. International cooperation projects (Collection of information on IEA photovoltaic air conditioning and hot water supply program); 1999 nendo taiyoko hatsuden system jitsuyoka gijutsu kaihatsu seika hokokusho. Kokusai kyoryoku jigyo (IEA taiyo reidanbo kyuto program ni kansuru joho shushu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    This paper reports activities of collecting items of information by dispatching experts mainly composed of members of the IEA photovoltaic air conditioning, and solar heating and cooling program (SHCP) committee to the SHCP Executive Committee and the Task expert conferences. This treaty is intended to assist creating the environmentally sustainable future by utilizing solar designs and technologies. It also aims at developing solar technologies including cost reduction as a result of the joint researches with business entities, structuring international markets, providing items of information, quantifying the effectiveness to the environment, performing the international standardization, and promoting utilization of solar technologies in developing countries. The tasks now in action include architectural lighting, methods for analyzing solar architectural energies, optimization of solar energy utilization in large buildings, procurement of active solar systems, air conditioning systems in buildings using the solar energy, solar heat composite systems, expansion of exterior component materials for solar buildings, sustainable buildings, agricultural solar drying, solar cities, a hybrid heat/PV solar system. (NEDO)

  11. FY 2000 report on the results of the development of commercialization technology of the photovoltaic power system. International cooperation project (Collection of the information on the IEA Solar Heating and Cooling Program); 2000 nendo seika hokokusho. Taiyoko hatsuden system jitsuyoka gijutsu kaihatsu kokusai jigyo kyoryoku (IEA taiyo reidanbo kyuto program ni kansuru joho shushu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    By sending specialists including mostly members of the IEA (International Energy Agency)/SHCP (Solar Heating and Cooling Program) to the Executive Committee Meeting of SHCP and the Task Specialist Meeting, information was collected, and the FY 2000 results were summarized. The mission of this implementing agreement by 2004 was to positively support the creation of the future environmentally sustainable by using solar design/technology to a high degree. For it, the following were to be carried out: development of solar technology including the cost reduction through the joint research with enterprises, construction of the international market, supply of the required information, quantification of the effectiveness of solar technology for the environment, tackling with the international standardization for expansion of the use in the building sector, promotion of solar technology utilization in developing countries, etc. In this fiscal year, finished were Task 19: Solar air/heat collecting system and Task 21: Natural lighting in buildings. Activities of Tasks 22-26, which started in the previous fiscal year, were continued. Activities of Tasks 27, 28 and 29 were newly started in this fiscal year. (NEDO)

  12. Research on PV system application on residences. Part 1. Report on the systems and PV measurement results of an experimental passive solar house; Taiyoko hatsuden system no jutaku eno oyo ni kansuru kenkyu. 1. Taisho tatemono taiyo to taiyoko hatsuden system keisoku kekka

    Energy Technology Data Exchange (ETDEWEB)

    Ishihara, O.; Sakai, K.; Hirakawa, M. [Kumamoto University, Kumamoto (Japan). Faculty of Engineering

    1997-11-25

    System of the house is outlined, and warming performance and photovoltaic power generation system energy performance are taken up. It is a one-storied meeting hall situated in an apartment area, whose heat loss factor is 2.59kcal/m2hdegC. Ninety hybrid solar cells provided with circulating air heat collectors are installed on the east-side of the roof, interconnected to the commercial power system. In the daytime in summer, the house is fully insulated from solar radiation, with the room temperature kept a little lower than the open air temperature. The range of daily change in the room temperature is narrow, providing a comfortable residential space. When the windows are opened in the evening, cool air comes into the room to replace the warm air inside, reducing the difference in temperature between the inside and outside of the room. In winter, insolation time is short on the east side of the roof which finds itself out of the sun. Under the circumstances, the system outputs but a little and the quantity sold is quite small in winter. But, in summer, sale of power can be practicable, thanks to exposure to sufficient sunshine. The inverter rated at 3.5kW attains a 90% or higher operating rate in the presence of an input of power of 0.5kW or more. 4 refs., 10 figs.

  13. Estilos de vida saludables de niños, niñas y adolescentes

    OpenAIRE

    Lilia Campo-Ternera; Yaneth Herazo-Beltrán; Floralinda García-Puello; Mariela Suarez-Villa; Orlando Méndez; Francisco Vásquez-De la Hoz

    2017-01-01

    Objetivo: Describir los estilos de vida saludables de niños, niñas y adolescentes de Barranquilla. Materiales y métodos: Estudio descriptivo de corte transversal en 991 niños, niñas y ado - lescentes. Se evaluó la actividad física mediante los cuestionarios de Actividad Física para Adolescentes y para niños escolares; se aplicó una encuesta que midió los conocimientos y prácticas de los escolares sobre salud bucal, lavado de manos, consumo de frutas y verduras y ...

  14. Creatividad en niños superdotados

    OpenAIRE

    González Román, María del Pilar

    1992-01-01

    Se ha realizado un estudio sobre la creatividad en los niños superdotados. Analizándose los diferentes modelos de creatividad y superdotacion avalados por un estudio empírico, en el cual se han valorado las diferencial que existen entre los niños superdotados y contraste a nivel verbal y grafico-espacial.

  15. Who is El Niño?

    Science.gov (United States)

    Philander, S. George

    It is a curious story, about a phenomenon we first welcomed as a blessing but now view with dismay, if not horror [Philander, 1998]. We named it El Niño for the child Jesus, provided it with relatives—La Niña and ENSO—and are devoting innumerable studies to the description and idealization of this family. These scriptures provide such a broad spectrum of historical, cultural, and scientific perspectives that there is now confusion about the identity of El Niño. Trenberth [1997] summarizes the situation as follows.The atmospheric component tied to El Niño is termed the “Southern Oscillation.” Scientists often call the phenomenon where the atmosphere and ocean collaborate ENSO, short for El Niño-Southern Oscillation. El Niño then corresponds to the warm phase of ENSO. The opposite “La Niña” (“the girl” in Spanish) phase consists of a basinwide cooling of the tropical Pacific and thus the cold phase of ENSO. However, for the public, the term for the whole phenomenon is “El Niño.”

  16. Preparation of one-step NiO/Ni-CGO composites using factorial design

    International Nuclear Information System (INIS)

    Araujo, A.J.M. de; Sousa, A R.O. de; Camposa, L.F.A.; Macedo, D.A.; Loureiro, F. J.A.; Fagg, D.P.

    2016-01-01

    This work deals with the synthesis, processing and characterization of NiO/Ni- CGO composite materials as potential solid oxide fuel cell (SOFC) anodes. The particulate materials were obtained by a one-step synthesis method and characterized by thermal analysis (prior to calcination) and X-ray diffraction (calcined powder). The ceramic processing of samples containing from 30 to 70 wt.% NiO was carried out by factorial design. Besides the NiO content controlled during the chemical synthesis, the impacts of the pore-former content (citric acid, used in proportions of 0, 7.5 and 15 wt.%) and the sintering temperature (1300, 1350 and 1400 °C) were also investigated. The open porosity of NiO-CGO composites and reduced Ni-CGO cermets was modeled as a function of factors (NiO content, citric acid content and sintering temperature) and interaction of factors. (author)

  17. Torsional superelasticity of NiTi archwires.

    Science.gov (United States)

    Bolender, Yves; Vernière, Anne; Rapin, Christophe; Filleul, Marie-Pierryle

    2010-11-01

    To reproduce and compare the intraoral torsional behavior of 10 commonly used preformed upper NiTi 0.017 x 0.025 archwires in 0.018-slot brackets at 20 degrees C, 35 degrees C, and 55 degrees C. Ten upper preformed NiTi archwires were compared to a multibraided stainless steel wire. An original testing bench was used to reproduce palatal root torque applied onto an upper central incisor with a maximum value of 1540 g x mm. Ten samples of each wire type were tested at 20 degrees C, 35 degrees C, and 55 degrees C each. Loading and unloading at 20 degrees C revealed three categories of wires: a group of four NiTi wires of relative stiffness bereft of any superelasticity, a group of six NiTi wires displaying some horizontal plateau, and finally the stainless steel wire of lesser stiffness. Testing at the average oral temperature of 35 degrees C produced the same three categories of wires, with only 2 of 10 NiTi wires displaying a superelastic effect (Copper NiTi 35 degrees C and 40 degrees C). None of the NiTi wires was superelastic at 55 degrees C. Moments increased with temperature as the martensite was replaced by the more rigid austenite. This study showed that most NiTi wires did not exhibit in torsion the superelastic effect traditionally described in bending. The combination of straight-wire prescriptions and rectangular superelastic NiTi archwires did not provide optimal constant moments necessary to gain third-order control of tooth movement early in treatment. A braided stainless steel rectangular archwire displayed better torsional behavior at 35 degrees C than most NiTi archwires of the same dimensions.

  18. Influence of annealing temperature on the microstructure and magnetic properties of Ni/NiO core-shell nanowires

    Science.gov (United States)

    Xiang, Wenfeng; Liu, Yuan; Yao, Jiangfeng; Sun, Rui

    2018-03-01

    Ni/NiO core-shell nanowires (NWs) were synthesized by thermal annealing of Ni NWs and variations in the microstructure, surface morphology, and magnetic properties of the NWs as a function of annealing temperature were investigated. The results showed that the grain size and crystal quality of NiO increased with an increasing annealing temperature. Specially, the effect of annealing temperature was much greater than annealing time for the formation of Ni/NiO NWs during the oxidization process. The total weight gain of the Ni/NiO NWs continuously increased when the annealing temperature was lower than 400 °C and the annealing time was more than 2 h; however, the weight gain of the Ni/NiO NWs was almost constant after annealing for 40 min when the annealing temperature was higher than 500 °C. The thorns on the surface of the Ni/NiO NWs gradually passivated and magnetic properties declined when the annealing temperature was increased from 300 °C to 400 °C. Smooth Ni/NiO NWs with no magnetic properties were prepared when the annealing temperature was over 500 °C. The detail study regarding the formation and evolution of Ni/NiO NWs is of considerable value and may provide useful information regarding the choice of post-treatment parameters for different applications of Ni/NiO NWs.

  19. Niño maltratado

    Directory of Open Access Journals (Sweden)

    Ana Ivis Crespo Barrios

    1996-12-01

    Full Text Available Se presentan 200 niños maltratados que acuden al Hospital Pediátrico Docente "Juan Manuel Márquez" en el período comprendido de diciembre de 1990 a enero de 1992; éstos fueron seleccionados teniendo en cuenta los criterios de maltrato, y era el objetivo fundamental del estudio conocer cómo se comporta en nuestro medio. En los resultados se muestra que la forma más frecuente fue el tipo no intencional; la ingestión de tóxicos fue la forma de negligencia física más frecuente dentro del maltrato no intencional, ésta es más usual en los niños menores de 5 años; los trastornos psiquiátricos y el alcoholismo son favorecedores del maltrato intencional, la madre es la que más maltrata; la mortalidad por esta causa no fue elevada (5 fallecidos y los criterios de riesgo de maltrato tienen utilidad para su identificación.200 mistreated children who were seen at the "Juan Manual Márquez" Pediatric Teaching Hospital from December, 1990 to January, 1992, are presented. These patients were selected taking into consideration the abuse criteria. The main objective of this paper was to know how these criteria behave in our enviroment. According to the results, the most common form was the non-intentional type. The ingestion of toxic agents was the most frequent form of physical neglect within the non-intentional mistreatment, and it is the most usual among children under 5. Psychiatric disorders and alcoholism favor the intentional mistreatment, and the mother mistreats the most. Mortality due to this cause was not high (5 deaths, and the abuse risk criteria are useful for its identification.

  20. Nonenzymatic Glucose Sensor Based on In Situ Reduction of Ni/NiO-Graphene Nanocomposite

    Directory of Open Access Journals (Sweden)

    Xiaohui Zhang

    2016-10-01

    Full Text Available Ni/NiO nanoflower modified reduced graphene oxide (rGO nanocomposite (Ni/NiO-rGO was introduced to screen printed electrode (SPE for the construction of a nonenzymatic electrochemical glucose biosensor. The Ni/NiO-rGO nanocomposite was synthesized by an in situ reduction process. Graphene oxide (GO hybrid Nafion sheets first chemical adsorbed Ni ions and assembled on the SPE. Subsequently, GO and Ni ions were reduced by hydrazine hydrate. The electrochemical properties of such a Ni/NiO-rGO modified SPE were carefully investigated. It showed a high activity for electrocatalytic oxidation of glucose in alkaline medium. The proposed nonenzymatic sensor can be utilized for quantification of glucose with a wide linear range from 29.9 μM to 6.44 mM (R = 0.9937 with a low detection limit of 1.8 μM (S/N = 3 and a high sensitivity of 1997 μA/mM∙cm−2. It also exhibited good reproducibility as well as high selectivity.

  1. Asymmetry of inter-El Niño and -La Niña diversity

    Science.gov (United States)

    Kim, S.; Kug, J. S.

    2016-12-01

    Over the North Pacific, there is a distinctive asymmetry of inter-El Niño and -La Niña diversity in atmospheric teleconnection patterns, indicating a strong diversity during La Niña events. Recent studies suggested that the typical patterns of the extratopical teleconnections associated with El Niño-Southern Oscillation (ENSO) are predominantly explained by the relative roles of the equatorial central Pacific (CP) and western North Pacific (WNP) precipitation anomalies. We find that the diversity of WNP precipitation anomalies is greater during La Niña events than during El Niño events. It also implies that the diversity of WNP precipitation anomalies during La Niña events is responsible for the diversity in the extratropical teleconnection. Since the relationship of anomalous sea surface temperature (SST) to precipitation is quite sensitive for SST in the range of 27-28°C, the WNP precipitation differences located over the warm pool among La Niña events lead to considerable teleconnection changes. In addition, we find here that the CMIP5 models well simulate the overall diversity in the tropical precipitation and extratropical teleconnection patterns during La Niña events, but it fails to reproduce a detailed pattern difference of atmospheric teleconnection in inter-La Niña events.

  2. Enthalpy of mixing of liquid Ni-Zr and Cu-Ni-Zr alloys

    International Nuclear Information System (INIS)

    Witusiewicz, V.T.; Sommer, F.

    2000-01-01

    Since the Al-Cu-Ni-Zr system is a basis for the production of bulk amorphous materials by rapid solidification techniques from the liquid state, it is of great scientific interest to determine the partial and the integral thermodynamic functions of liquid and undercooled liquid alloys. Such data, as was pointed out previously, are important in order to understand their extremely good glass-forming ability in multicomponent metallic systems as well as for processing improvements. In order to measure the thermodynamic properties of the Al-Cu-Ni-Zr quaternary, it is necessary to have reliable thermochemical data for its constituent canaries and ternaries first. In a series of articles, the authors have reported in detail the thermodynamic properties of liquid Al-Cu, Al-Ni, Cu-Ni, Cu-Zr, Al-Zr, Al-Cu-Ni, and Al-Cu-Zr alloys. This article deals with the direct calorimetric measurements of the partial and the integral enthalpies of mixing of liquid Ni-Zr and Cu-Ni-Zr alloys and the heat capacity of liquid Ni 26 Zr 74 . In a subsequent article, the authors will present similar data for the liquid ternary Al-Ni-Zr and for the liquid quaternary Al-Cu-Ni-Zr alloys

  3. Composite Ni/NiO-Cr2O3 Catalyst for Alkaline Hydrogen Evolution Reaction

    Science.gov (United States)

    Bates, Michael K.; Jia, Qingying; Ramaswamy, Nagappan; Allen, Robert J.; Mukerjee, Sanjeev

    2015-01-01

    We report a Ni–Cr/C electrocatalyst with unprecedented mass-activity for the hydrogen evolution reaction (HER) in alkaline electrolyte. The HER kinetics of numerous binary and ternary Ni-alloys and composite Ni/metal-oxide/C samples were evaluated in aqueous 0.1 M KOH electrolyte. The highest HER mass-activity was observed for Ni–Cr materials which exhibit metallic Ni as well as NiOx and Cr2O3 phases as determined by X-ray diffraction (XRD) and X-ray absorption spectroscopy (XAS) analysis. The onset of the HER is significantly improved compared to numerous binary and ternary Ni-alloys, including Ni–Mo materials. It is likely that at adjacent Ni/NiOx sites, the oxide acts as a sink for OHads, while the metallic Ni acts as a sink for the Hads intermediate of the HER, thus minimizing the high activation energy of hydrogen evolution via water reduction. This is confirmed by in situ XAS studies that show that the synergistic HER enhancement is due to NiOx content and that the Cr2O3 appears to stabilize the composite NiOx component under HER conditions (where NiOx would typically be reduced to metallic Ni0). Furthermore, in contrast to Pt, the Ni(Ox)/Cr2O3 catalyst appears resistant to poisoning by the anion exchange ionomer (AEI), a serious consideration when applied to an anionic polymer electrolyte interface. Furthermore, we report a detailed model of the double layer interface which helps explain the observed ensemble effect in the presence of AEI. PMID:26191118

  4. Study of the central collisions in the reactions Ni + Al and Ni + Ni at 28 A.MeV; Etude des collisions centrales dans les reactions Ni + Al et Ni + Ni a 28 A.MeV

    Energy Technology Data Exchange (ETDEWEB)

    Lebreton, L.

    1995-12-01

    The work is in characterisation of mechanisms in the energy range of onset of multifragmentation (excitation energy of composed nucleus around 4 - 5 AMeV). This work focused on an experiment performed at the SARA facility, in Grenoble, using the AMPHORA multi detection array. I have been particularly interested in central collisions in the Ni + Al and Ni + Ni systems. The possibility to detect complete events for Ni + Al, and quasi-complete events for the Ni + Ni case, is the reason of this choice. Furthermore Ni + Ni presents the interest of a symmetrical system, for which the excitation energy per nucleon is maximum. The study of these reactions has been focused on the quasi-complete events (events for which at least 80 % of the total charge has been detected). Heavy ions produced in peripheral collisions are very likely emitted along the beam line or stopped in the plastic detectors, energy thresholds are too high for the quasi-target products detection, consequently by requiring complete or quasi-complete measurement of the total charge, we are able to detect mostly central events. The knowledge of informations like charge, energy or detection angles allows to isolate the source(s) and to reconstruct the size and the excitation energy of the source(s). Comparisons with simulations like sequential emission (GEMINI code), very deep inelastic collision or instantaneous emission (Berliner code) allows to characterise the first stage of the collision (binary collisions or central collisions) and the type of deexcitation of the source(s). Some calculations was also performed with the statistical model code MODGAN. Indeed azimuthal correlations seem to be a good tool in getting more information about involved reaction mechanisms. Comparisons with MODGAN provide information about angular momentum of the source and time delay between emissions of the two particles (separation between sequential or instantaneous process). (author). 69 refs.

  5. niños pre-escolares

    Directory of Open Access Journals (Sweden)

    Sandra León Muñoz

    2006-01-01

    Full Text Available Este estudio tuvo como objetivo caracterizar las producciones narrativas orales de niños de pre-escolar y relacionar estos desempeños con la lectura de imágenes. Se conformó una muestra de 9 niños entre 4 y 6 años que pertenecían a instituciones de educación formal. Se realizó un análisis de tarea de la historieta presentada y la aplicación de ésta fue de manera individual en el contexto familiar del niño. Los resultados mostraron que los niños identificaban la situación inicial de la narración, en la cual relacionaban personajes principales, actividades propias de ellos y del espacio donde sucedían sin embargo, a medida que se avanzaban en el procedimiento, se observó cómo se dificultaba para los niños la elaboración de las otras categorías que estructuran la narración como la complicación, la reacción, la resolución y la situación final. En relación con las estrategias cognitivas se observó que cuatro niños se encuentra en un nivel cognitivo bajo, cuatro se encuentra en un nivel cognitivo medio y un niño, en un nivel cognitivo alto. En cuanto a los procesos de lectura de imágenes se encontró que sólo dos niños utilizaron la referencia y dos niños usaron conectores temporales

  6. Electrochemical preparation and characteristics of Ni-Co-LaNi5 composite coatings as electrode materials for hydrogen evolution

    International Nuclear Information System (INIS)

    Wu Gang; Li Ning; Dai Changsong; Zhou Derui

    2004-01-01

    Electrocatalytic activity for the hydrogen evolution reaction on Ni-Co-LaNi 5 composite electrodes prepared by electrochemical codeposition technique was evaluated. The relationship between the current density for hydrogen evolution reaction and the amount of LaNi 5 particles in Ni-Co baths is like the well-known 'volcano plot'. The Surface morphology and microstructure of Ni-Co-LaNi 5 coatings were determined by means of scanning electron microscopy (SEM) and X-ray diffraction (XRD). The kinetic parameters were determined from electrochemical steady-state Tafel polarization and electrochemical impedance spectroscopy technology in 1 M NaOH solution. The values obtained for the apparent energies of activation are 32.48, 46.29 and 57.03 kJ mol -1 for the Ni-Co-LaNi 5 , Ni-Co and Ni electrodes, respectively. The hydrogen evolution reaction on Ni-Co-LaNi 5 proceeds via Volmer-Tafel reaction route with the mixed rate determining characteristics. The composite coating Ni-Co-LaNi 5 is catalytically more active than Ni and Ni-Co electrodes due to the increase in its real surface areas and the decrease in the apparent free energy of activation caused by the electrocatalytic synergistic effect of the Ni-Co alloys and the hydrogen storage intermetallic particles on the electrode surface

  7. De niños e infancias

    OpenAIRE

    Camenen, Gersende; Liendo, Victoria

    2014-01-01

    A Sarmiento, el niño sabio, lo llevan de casa en casa como al prodigio del pueblo para oírlo leer en voz alta. Norah Lange, la niña excéntrica, grita desaforada en distintos idiomas y finge carcajadas enloquecidas desde el techo de su casa hasta gastar la voz. Reinaldo Arenas, el niño salvaje, escribe, como Celestino, poemas con un cuchillo en el tronco los árboles para que no amanezca. Borges, el traductor precoz, lee a los seis años el Quijote en inglés sin tener la menor sospecha de que el...

  8. New developments in Ni/Ti multilayers

    Energy Technology Data Exchange (ETDEWEB)

    Anderson, I.; Hoghoj, P. [Institut Max von Laue - Paul Langevin (ILL), 38 - Grenoble (France)

    1997-04-01

    It is now 20 years since super-mirrors were first used as a neutron optical element. Since then the field of multilayer neutron-optics has matured with multilayers finding their way to application in many neutron scattering instruments. However, there is still room for progress in terms of multilayer quality, performance and application. Along with work on multilayers for neutron polarisation Ni/Ti super-mirrors have been optimised. The state-of-the-art Ni/Ti super-mirror performance and the results obtained in two neutron-optics applications of Ni/Ti multilayers are presented. (author).

  9. Nickel Release, ROS Generation and Toxicity of Ni and NiO Micro- and Nanoparticles.

    Science.gov (United States)

    Latvala, Siiri; Hedberg, Jonas; Di Bucchianico, Sebastiano; Möller, Lennart; Odnevall Wallinder, Inger; Elihn, Karine; Karlsson, Hanna L

    2016-01-01

    Occupational exposure to airborne nickel is associated with an elevated risk for respiratory tract diseases including lung cancer. Therefore, the increased production of Ni-containing nanoparticles necessitates a thorough assessment of their physical, chemical, as well as toxicological properties. The aim of this study was to investigate and compare the characteristics of nickel metal (Ni) and nickel oxide (NiO) particles with a focus on Ni release, reactive oxygen species (ROS) generation, cellular uptake, cytotoxicity and genotoxicity. Four Ni-containing particles of both nano-size (Ni-n and NiO-n) and micron-size (Ni-m1 and Ni-m2) were tested. The released amount of Ni in solution was notably higher in artificial lysosomal fluid (e.g. 80-100 wt% for metallic Ni) than in cell medium after 24h (ca. 1-3 wt% for all particles). Each of the particles was taken up by the cells within 4 h and they remained in the cells to a high extent after 24 h post-incubation. Thus, the high dissolution in ALF appeared not to reflect the particle dissolution in the cells. Ni-m1 showed the most pronounced effect on cell viability after 48 h (alamar blue assay) whereas all particles showed increased cytotoxicity in the highest doses (20-40 μg cm2) when assessed by colony forming efficiency (CFE). Interestingly an increased CFE, suggesting higher proliferation, was observed for all particles in low doses (0.1 or 1 μg cm-2). Ni-m1 and NiO-n were the most potent in causing acellular ROS and DNA damage. However, no intracellular ROS was detected for any of the particles. Taken together, micron-sized Ni (Ni-m1) was more reactive and toxic compared to the nano-sized Ni. Furthermore, this study underlines that the low dose effect in terms of increased proliferation observed for all particles should be further investigated in future studies.

  10. Exchange bias variations of the seed and top NiFe layers in NiFe/FeMn/NiFe trilayer as a function of seed layer thickness

    International Nuclear Information System (INIS)

    Sankaranarayanan, V.K.; Yoon, S.M.; Kim, C.G.; Kim, C.O.

    2005-01-01

    Development of exchange bias at the seed and top NiFe layers in the NiFe (t nm)/FeMn(10 nm)/NiFe(5 nm) trilayer structure is investigated as a function of seed layer thickness, in the range of 2-20 nm. The seed NiFe layer shows maximum exchange bias at 4 nm seed layer thickness. The bias shows inverse thickness dependence with increasing thickness. The top NiFe layer on the other hand shows only half the bias of the seed layer which is retained even after the sharp fall in seed layer bias. The much smaller bias for the top NiFe layer is related to the difference in crystalline texture and spin orientations at the top FeMn/NiFe interface, in comparison to the bottom NiFe/FeMn interface which grows on a saturated NiFe layer with (1 1 1) orientation

  11. Synthesis of Supported NiPt Bimetallic Nanoparticles, Methods for Controlling the Surface Coverage of Ni Nanoparticles With Pt, Methods Of Making NiPt Multilayer Core-Shell Structures and Application of the Supported Catalysts for CO2 Reforming

    KAUST Repository

    Li, Lidong

    2015-06-25

    Embodiments of the present disclosure provide for supported Ni/Pt bimetallic nanoparticles, compositions including supported NiPt nanoparticles, methods of making supported NiPt nanoparticles, methods of using supported NiPt nanoparticles, and the like.

  12. Free-energies of the Ti-Ni, Fe-Ni and Mo-Ni alloys in relation to their behaviour under particle irradiation

    International Nuclear Information System (INIS)

    De Tendler, R.H.; Rodriguez, C.; Gallego, L.J.; Alonso, J.A.

    1996-01-01

    The metastable free-energy diagrams of the Ti-Ni, Fe-Ni and Mo-Ni systems were calculated at room temperature using a semiempirical theory based on thermodynamic considerations. Ti-Ni and Mo-Ni form equilibrium-ordered compounds that are destabilized by particle irradiation. Effectively, Ti 2 Ni, TiNi, MoNi and MoNi 3 amorphize after irradiation. In the present work, this experimental behaviour is understood by considering the modification of the free-energy diagrams after particle irradiation. Conversely, in the Fe-Ni system, a metastable f c c solid solution evolves under irradiation towards ordered FeNi. In this system, according to our calculation, the free-energy of the amorphous phase is much higher than the free-energy of any other competing phase, so the amorphous phase cannot be produced. Each selected alloy has an intermetallic compound (TiNi 3 , FeNi 3 and MoNi 4 ) which does not amorphize by particle irradiation and whose composition is close to the nickel-rich end of the phase diagram. According to the calculated free-energy diagrams, the reason for this impossibility of amorphization would be the competition of the terminal solid solution with the amorphous phase. (Author)

  13. Precipitation of Ni4Ti3-variants in a polycrystalline Ni-rich NiTi shape memory alloy

    Czech Academy of Sciences Publication Activity Database

    Bojda, Ondřej; Eggeler, G.; Dlouhý, Antonín

    2005-01-01

    Roč. 53, č. 1 (2005), s. 99-104 ISSN 1359-6462 R&D Projects: GA ČR(CZ) GA106/05/0918 Institutional research plan: CEZ:AV0Z20410507 Keywords : NiTi shape memory alloys * Ni4Ti3 precipitation * Transmission electron microscopy Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 2.228, year: 2005

  14. Influence of Ni Solute segregation on the intrinsic growth stresses in Cu(Ni) thin films

    International Nuclear Information System (INIS)

    Kaub, T.M.; Felfer, P.; Cairney, J.M.; Thompson, G.B.

    2016-01-01

    Using intrinsic solute segregation in alloys, the compressive stress in a series of Cu(Ni) thin films has been studied. The highest compressive stress was noted in the 5 at.% Ni alloy, with increasing Ni concentration resulting in a subsequent reduction of stress. Atom probe tomography quantified Ni's Gibbsian interfacial excess in the grain boundaries and confirmed that once grain boundary saturation is achieved, the compressive stress was reduced. This letter provides experimental support in elucidating how interfacial segregation of excess adatoms contributes to the post-coalescence compressive stress generation mechanism in thin films. - Graphical abstract: Cu(Ni) film stress relationship with Ni additions. Atom probe characterization confirms solute enrichment in the boundaries, which was linked to stress response.

  15. Continuum mechanics simulations of NiO/Ni-YSZ composites during reduction and re-oxidation

    DEFF Research Database (Denmark)

    Pihlatie, Mikko; Frandsen, Henrik Lund; Kaiser, Andreas

    2010-01-01

    Repeated reduction–oxidation (redox) cycles on Ni-based solid oxide fuel cells (SOFC) have been experimentally well investigated and are known to be detrimental to the thermomechanical stability of the composites, especially on anode supported structures. In the present work the mechanistic...... for the dimensional change arises from the volumetric change related to the phase change NiO ↔ Ni. The measurable change in bulk length is given by the ceramic YSZ backbone as a response to the stress created by the chemical strain. The different subprocesses described in the model for YSZ were elastic and anelastic...... expansion, diffusional creep, grain boundary sliding (GBS) and microcracking due to excessive stress. In the Ni/NiO phase, nonelastic strains in terms of diffusional and power law creep were implemented, and additionally for NiO deformation due to microcracking and/or pseudoplasticity. Semi...

  16. Site occupancy of Fe in ternary Ni 75-x

    Indian Academy of Sciences (India)

    The results of a detailed structural and magnetic study clearly indicate that regardless of the thermal history of the samples, Fe has a strong preference for the Ni sites in Ni-poor (non-stoichiometric) Ni75Al25 alloys. Fe substitution has a profound effect on the nature of magnetism in Ni75Al25.

  17. Reduction of a Ni/Spinel Catalyst for Methane Reforming

    DEFF Research Database (Denmark)

    Kehres, Jan; Andreasen, Jens Wenzel; Fløystad, Jostein Bø

    2015-01-01

    microscopy (HRTEM) was performed on the fresh catalyst sample. The Ni particles in the fresh catalyst sample were observed to exhibit a Ni/NiO core/shell structure. A decrease of the Ni lattice parameter is observed during the reduction in a temperature interval from 413 – 453 K, which can be related...

  18. Electronic structure of graphene on Ni surfaces with different orientation

    International Nuclear Information System (INIS)

    Pudikov, D.A.; Zhizhin, E.V.; Rybkin, A.G.; Rybkina, A.A.; Zhukov, Y.M.; Vilkov, O. Yu.; Shikin, A.M.

    2016-01-01

    An experimental study of the graphene, synthesized by propylene cracking on Ni surfaces with different orientation: (100) and (111), using angle-resolved photoemission, has been performed. It has been shown that graphene on Ni(111) had a perfect lateral structure due to consistency of their lattices, whereas graphene/Ni(100) consisted of a lot of domains. For both systems electronic structure was quite similar and demonstrated a strong bonding of graphene to the underlying Ni surface. After Au intercalation the electronic structure of graphene in both systems was shifted to the Fermi level and became linear in the vicinity of the K point of the Brillouin zone. - Highlights: • Graphene on Ni(111) is well-ordered, whereas on Ni(100) – multi-domain. • Graphene on Ni(111) and Ni(100) is strongly bonded with substrate. • Intercalation of Au atoms restores the linearity in dispersion and makes graphene quasi-free on both Ni(100) and Ni(111).

  19. Modeling and simulation of NiO dissolution and Ni deposition in molten carbonate fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Nam, Suk Woo; Choi, Hyung-Joon; Lim, Tae Hoon [Korea Institute of Science & Technology, Seoul (Korea, Republic of)] [and others

    1996-12-31

    Dissolution of NiO cathode into the electrolyte matrix is an important phenomena limiting the lifetime of molten carbonate fuel cell (MCFC). The dissolved nickel diffuses into the matrix and is reduced by dissolved hydrogen leading to the formation of metallic nickel films in the pores of the matrix. The growth of Ni films in the electrolyte matrix during the continuous cell operation results eventually in shorting between cathode and anode. Various mathematical and empirical models have been developed to describe the NiO dissolution and Ni deposition processes, and these models have some success in estimating the lifetime of MCFC by correlating the amount of Ni deposited in the matrix with shorting time. Since the exact mechanism of Ni deposition was not well understood, deposition reaction was assumed to be very fast in most of the models and the Ni deposition region was limited around a point in the matrix. In fact, formation of Ni films takes place in a rather broad region in the matrix, the location and thickness of the film depending on operating conditions as well as matrix properties. In this study, we assumed simple reaction kinetics for Ni deposition and developed a mathematical model to get the distribution of nickel in the matrix.

  20. Directional Solidification and Mechanical Properties of NiAl-NiAlTa Alloys

    Science.gov (United States)

    Johnson, D. R.; Chen, X. F.; Oliver, B. F.; Noebe, R. D.; Whittenberger, J. D.

    1995-01-01

    Directional solidification of eutectic alloys is a promising technique for producing in-situ composite materials exhibiting a balance of properties. Consequently, the microstructure, creep strength and fracture toughness of directionally solidified NiAl-NiAlTa alloys were investigated. Directional solidification was performed by containerless processing techniques to minimize alloy contamination. The eutectic composition was found to be NiAl-15.5 at% Ta and well-aligned microstructures were produced at this composition. A near-eutectic alloy of NiAl-14.5Ta was also investigated. Directional solidification of the near-eutectic composition resulted in microstructures consisting of NiAl dendrites surrounded by aligned eutectic regions. The off-eutectic alloy exhibited promising compressive creep strengths compared to other NiAl-based intermetallics, while preliminary testing indicated that the eutectic alloy was competitive with Ni-base single crystal superalloys. The room temperature toughness of these two-phase alloys was similar to that of polycrystalline NiAl even with the presence of the brittle Laves phase NiAlTa.

  1. The magnetic moment of Ni in the Laves phase compound GdNi2

    International Nuclear Information System (INIS)

    Yano, Kazuo; Umehara, Izuru; Miyazawa, Tomoaki; Adachi, Yoshiya; Sato, Kiyoo

    2005-01-01

    Magnetization and inverse susceptibility of the Laves phase compound GdNi 2 were investigated and analyzed in detail by employing molecular-field analysis. Both the temperature dependence of the magnetization and the Curie-Weiss (C-W) law-like linear relationship of inverse susceptibility are reproduced in terms of a two-sublattice model and it is seen that the magnetic structure of GdNi 2 is ferrimagnetic and Ni in GdNi 2 retains a magnetic moment of about 0.24μ B

  2. Polymer stabilized Ni-Ag and Ni-Fe alloy nanoclusters: Structural and magnetic properties

    Energy Technology Data Exchange (ETDEWEB)

    Kabir, L.; Mandal, A.R. [Department of Physics, Visva-Bharati, Santiniketan-731 235 (India); Mandal, S.K., E-mail: sk_mandal@hotmail.co [Department of Physics, Visva-Bharati, Santiniketan-731 235 (India)

    2010-04-15

    We report here the structural and magnetic behaviors of nickel-silver (Ni-Ag) and nickel-iron (Ni-Fe) nanoclusters stabilized with polymer (polypyrrole). High resolution transmission electron microscopy (HRTEM) indicates Ni-Ag nanoclusters to stabilize in core-shell configuration while that of Ni-Fe nanoclusters in a mixed type of geometry. Structural characterizations by X-ray diffraction (XRD) reveal the possibility of alloying in such bimetallic nanoclusters to some extent even at temperatures much lower than that of bulk alloying. Electron paramagnetic resonance (EPR) spectra clearly reveal two different absorption behaviors: one is ascribed to non-isolated Ni{sup 2+} clusters surrounded by either silver or iron giving rise to a broad signal, other (very narrow signal) being due to the isolated superparamagnetic Ni{sup 2+} clusters or bimetallic alloy nanoclusters. Results obtained for Ni-Ag and Ni-Fe nanoclusters have been further compared with the behavior exhibited by pure Ni nanoclusters in polypyrrole host. Temperature dependent studies (at 300 and 77 K) of EPR parameters, e.g. linewidth, g-value, line shape and signal intensity indicating the significant influence of surrounding paramagnetic silver or ferromagnetic iron within polymer host on the EPR spectra have been presented.

  3. Polymer stabilized Ni-Ag and Ni-Fe alloy nanoclusters: Structural and magnetic properties

    Science.gov (United States)

    Kabir, L.; Mandal, A. R.; Mandal, S. K.

    2010-04-01

    We report here the structural and magnetic behaviors of nickel-silver (Ni-Ag) and nickel-iron (Ni-Fe) nanoclusters stabilized with polymer (polypyrrole). High resolution transmission electron microscopy (HRTEM) indicates Ni-Ag nanoclusters to stabilize in core-shell configuration while that of Ni-Fe nanoclusters in a mixed type of geometry. Structural characterizations by X-ray diffraction (XRD) reveal the possibility of alloying in such bimetallic nanoclusters to some extent even at temperatures much lower than that of bulk alloying. Electron paramagnetic resonance (EPR) spectra clearly reveal two different absorption behaviors: one is ascribed to non-isolated Ni 2+ clusters surrounded by either silver or iron giving rise to a broad signal, other (very narrow signal) being due to the isolated superparamagnetic Ni 2+ clusters or bimetallic alloy nanoclusters. Results obtained for Ni-Ag and Ni-Fe nanoclusters have been further compared with the behavior exhibited by pure Ni nanoclusters in polypyrrole host. Temperature dependent studies (at 300 and 77 K) of EPR parameters, e.g. linewidth, g-value, line shape and signal intensity indicating the significant influence of surrounding paramagnetic silver or ferromagnetic iron within polymer host on the EPR spectra have been presented.

  4. Polymer stabilized Ni-Ag and Ni-Fe alloy nanoclusters: Structural and magnetic properties

    International Nuclear Information System (INIS)

    Kabir, L.; Mandal, A.R.; Mandal, S.K.

    2010-01-01

    We report here the structural and magnetic behaviors of nickel-silver (Ni-Ag) and nickel-iron (Ni-Fe) nanoclusters stabilized with polymer (polypyrrole). High resolution transmission electron microscopy (HRTEM) indicates Ni-Ag nanoclusters to stabilize in core-shell configuration while that of Ni-Fe nanoclusters in a mixed type of geometry. Structural characterizations by X-ray diffraction (XRD) reveal the possibility of alloying in such bimetallic nanoclusters to some extent even at temperatures much lower than that of bulk alloying. Electron paramagnetic resonance (EPR) spectra clearly reveal two different absorption behaviors: one is ascribed to non-isolated Ni 2+ clusters surrounded by either silver or iron giving rise to a broad signal, other (very narrow signal) being due to the isolated superparamagnetic Ni 2+ clusters or bimetallic alloy nanoclusters. Results obtained for Ni-Ag and Ni-Fe nanoclusters have been further compared with the behavior exhibited by pure Ni nanoclusters in polypyrrole host. Temperature dependent studies (at 300 and 77 K) of EPR parameters, e.g. linewidth, g-value, line shape and signal intensity indicating the significant influence of surrounding paramagnetic silver or ferromagnetic iron within polymer host on the EPR spectra have been presented.

  5. Composite Ni/NiO-Cr2O3 Catalyst for Alkaline Hydrogen Evolution Reaction

    OpenAIRE

    Bates, Michael K.; Jia, Qingying; Ramaswamy, Nagappan; Allen, Robert J.; Mukerjee, Sanjeev

    2015-01-01

    We report a Ni–Cr/C electrocatalyst with unprecedented mass-activity for the hydrogen evolution reaction (HER) in alkaline electrolyte. The HER kinetics of numerous binary and ternary Ni-alloys and composite Ni/metal-oxide/C samples were evaluated in aqueous 0.1 M KOH electrolyte. The highest HER mass-activity was observed for Ni–Cr materials which exhibit metallic Ni as well as NiOx and Cr2O3 phases as determined by X-ray diffraction (XRD) and X-ray absorption spectroscopy (XAS) analysis. Th...

  6. Pressure dependence on the remanent magnetization of Fe-Ni alloys and Ni metal

    Science.gov (United States)

    Wei, Qingguo; Gilder, Stuart Alan; Maier, Bernd

    2014-10-01

    We measured the acquisition of magnetic remanence of iron-nickel alloys (Fe64Ni36, Fe58Ni42, and Fe50Ni50) and pure Ni under pressures up to 23 GPa at room temperature. Magnetization decreases markedly for Fe64Ni36 between 5 and 7 GPa yet remains ferromagnetic until at least 16 GPa. Magnetization rises by a factor of 2-3 for the other compositions during compression to the highest applied pressures. Immediately upon decompression, magnetic remanence increases for all Fe-Ni alloys while magnetic coercivity remains fairly constant at relatively low values (5-20 mT). The amount of magnetization gained upon complete decompression correlates with the maximum pressure experienced by the sample. Martensitic effects best explain the increase in remanence rather than grain-size reduction, as the creation of single domain sized grains would raise the coercivity. The magnetic remanence of low Ni Invar alloys increases faster with pressure than for other body-centered-cubic compositions due to the higher magnetostriction of the low Ni Invar metals. Thermal demagnetization spectra of Fe64Ni36 measured after pressure release broaden as a function of peak pressure, with a systematic decrease in Curie temperature. Irreversible strain accumulation from the martensitic transition likely explains the broadening of the Curie temperature spectra, consistent with our x-ray diffraction analyses.

  7. Grain boundaries in Ni3Al. 2

    International Nuclear Information System (INIS)

    Kung, H.; Sass, S.L.

    1992-01-01

    This paper discusses the dislocation structure of small angle tilt and twist boundaries in ordered Ni 3 Al, with and without boron, investigated using transmission electron microscopy. Dislocation with Burgers vectors that correspond to anti-phase boundary (APB)-coupled superpartials were found in small angle twist boundaries in both boron-free and boron-doped Ni 3 Al, and a small angle tilt boundary in boron-doped Ni 3 Al. The boundary structures are in agreement with theoretical models proposed by Marcinkowski and co-workers. The APB energy determined from the dissociation of the grain boundary dislocations was lower than values reported for isolated APBs in Ni 3 Al. For small angle twist boundaries the presence of boron reduced the APB energy at the interface until it approached zero. This is consistent with the structure of these boundaries containing small regions of increased compositional disorder in the first atomic plane next to the interface

  8. Niños y Violencia

    OpenAIRE

    International Child Development Centre

    1997-01-01

    Este Innocenti Digest explora la violencia de los niños y hacia los niños, usando el marco de la Convención de los Derechos del Niño de las Naciones Unidas. Se centra en la violencia interpersonal, tanto intrafamiliar como extrafamiliar. Se incluye el abuso sexual y la explotación ya que a pesar de no implicar obligatoriamente violencia o coerción, la mayor parte de la evidencia demuestra su efectos dañinos tanto físicos como psicológicos. También se discute la implicación de los niños en los...

  9. Root morphology of Ni-treated plants

    International Nuclear Information System (INIS)

    Leskova, A.; Fargasova, A.; Giehl, R. F. H.; Wiren, N. von

    2015-01-01

    Plant roots are very important organs in terms of nutrient and water acquisition but they also serve as anchorages for the aboveground parts of the plants. The roots display extraordinary plasticity towards stress conditions as a result of integration of environmental cues into the developmental processes of the roots. Our aim was to investigate the root morphology of Arabidopsis thaliana plants exposed to a particular stress condition, excess Ni supply. We aimed to find out which cellular processes - cell division, elongation and differentiation are affected by Ni, thereby explaining the seen root phenotype. Our results reveal that a distinct sensitivity exists between roots of different order and interference with various cellular processes is responsible for the effects of Ni on roots. We also show that Ni-treated roots have several auxin-related phenotypes. (authors)

  10. Ni adsorption and Ni-Al LDH precipitation in a sandy aquifer: An experimental and mechanistic modeling study

    NARCIS (Netherlands)

    Regelink, I.C.; Temminghoff, E.J.M.

    2011-01-01

    Mining activities and industries have created nickel (Ni) contaminations in many parts of the world. The objective of this study is to increase our understanding of Ni adsorption and Nickel-Aluminium Layered Double Hydroxide (Ni-Al LDH) precipitation to reduce Ni mobility in a sandy soil aquifer. At

  11. Fe-Cr-Ni system alloys

    International Nuclear Information System (INIS)

    Levin, F.L.

    1986-01-01

    Phase diagram of Fe-Cr-Ni system, which is the basic one for production of corrosion resistant alloys, is considered. Data on corrosion resistance of such alloys are correlated depending on a number of factors: quality and composition of modifying elements, corrosion medium, temperature, alloy structure, mechanical and thermal treatment. Grades of Fe-Ni-Cr alloys are presented, and fields of their application are pointed out

  12. Heteromorphic NiCo2S4/Ni3S2/Ni Foam as a Self-Standing Electrode for Hydrogen Evolution Reaction in Alkaline Solution.

    Science.gov (United States)

    Liu, Hui; Ma, Xiao; Rao, Yuan; Liu, Yang; Liu, Jialiang; Wang, Luyang; Wu, Mingbo

    2018-04-04

    Considerable works have been devoted on developing high-efficiency nonplatinum electrocatalysts for hydrogen evolution reaction (HER). Herein, 3D heteromorphic NiCo 2 S 4 /Ni 3 S 2 nanosheets network has been constructed on Ni foam (denoted as NiCo 2 S 4 /Ni 3 S 2 /NF) serving as a self-standing electrocatalyst through directly thermal sulfurization of a single-source NiCo-layered double hydroxide precursor. The resultant NiCo 2 S 4 /Ni 3 S 2 /NF electrode exhibits outstanding electrocatalytic HER performance with an extremely low onset overpotential of 15 mV and long-term durability in alkaline solution. Such enhanced HER performance can be credited to (1) the massive exposed active sites provided by mixed transition metal chalcogenides (NiCo 2 S 4 and Ni 3 S 2 ), (2) the strong interfacial interaction at NiCo 2 S 4 /Ni 3 S 2 heterojunction interfaces with the strengthened H binding, and (3) the porous highly conductive Ni foam substrate with accelerated electron transfer. This work opens up a new direction to fabricate effective and non-noble-metal electrodes for water splitting and hydrogen generation.

  13. Heavy metal environmental impact. Nickel (Ni); Impatto ambientale da metalli pesanti. Il Nichel (Ni)

    Energy Technology Data Exchange (ETDEWEB)

    Bressa, G. [Padua Univ. Padua (Italy). Dipt. di Farmacologia, Lab. di Tossicologia

    2001-02-01

    Nickel (Ni) is a heavy metal in over 3.000 different alloys used to produce kitchen utensils, batteries, coins, etc.. Human extractive and industrial activities are therefore a cause for environmental dispersion of this metal into the biosphere. This shows how in urban areas car traffic and house-heating are the main sources of nickel pollution. Nickel is relatively non-toxic, such as iron, cobalt, copper and zinc; nevertheless prolonged inhalation of dust containing such compounds as Ni O or NiCl{sub 2} concurs in the outbreak of respiratory pathologies. The carcinogenic effect of such compounds as Ni S, Ni O and Ni(CO){sub 4} has been confirmed by experiments on laboratory animals. Ni potentially toxic concentrations, and as a consequence of potential environmental impact, are to be mainly found in populated areas where the main sources are represented by industries and landfills. [Italian] Il nichel (Ni) e' un metallo presente in oltre 3.000 differenti leghe che vengono utilizzate per la produzione di utensili da cucina, batterie, monete, ecc.. Le attivita' estrattive ed industriali dell'uomo sono quindi causa di una dispersione del metallo nella biosfera. Sono stati riscontrati elevati tassi di Ni nell'atmosfera di aree urbane. Cio' sta a dimostrare che nelle aree urbane il traffico automobilistico e il riscaldamento domestico sono le fonti principali di inquinamento da tale metallo. Il nichel e' relativamente atossico, analogamente a ferro, cobalto, rame e zinco, tuttavia l'inalazione protratta di polveri contenenti composti come il NiO o il NiCl{sub 2} contribuisce al manifestarsi di patologie dell'apparato respiratorio. E' stato confermato sperimentalmente su animali da laboratorio l'effetto cancerogeno di alcuni composti quali NiS, NiO e Ni(CO){sub 4}. Concentrazioni potenzialmente tossiche di Ni, e quindi di probabile impatto ambientale, sono maggiormente da ricercare nelle zone antropizzate dove le fonti

  14. Moessbauer analysis and magnetic properties of Invar Fe-Ni-C and Fe-Ni-Mn-C alloys

    International Nuclear Information System (INIS)

    Nadutov, V. M.; Svystunov, Ye. O.; Kosintsev, S. G.; Tatarenko, V. A.

    2006-01-01

    The saturation magnetization and the hyperfine magnetic field of different f.c.c. Fe-Ni based alloys containing nearby 29 at .% Ni were studied as a function of temperature and for different Carbon and Manganese contents. We have observed abnormal behaviors that are explained in terms of mixed exchange interactions between atomic spins: J NiNi (r i ) FeFe (r i ) > 0, J NiFe (r i ) < 0.

  15. Single-crystalline Ni2Ge/Ge/Ni2Ge nanowire heterostructure transistors.

    Science.gov (United States)

    Tang, Jianshi; Wang, Chiu-Yen; Xiu, Faxian; Hong, Augustin J; Chen, Shengyu; Wang, Minsheng; Zeng, Caifu; Yang, Hong-Jie; Tuan, Hsing-Yu; Tsai, Cho-Jen; Chen, Lih Juann; Wang, Kang L

    2010-12-17

    In this study, we report on the formation of a single-crystalline Ni(2)Ge/Ge/Ni(2)Ge nanowire heterostructure and its field effect characteristics by controlled reaction between a supercritical fluid-liquid-solid (SFLS) synthesized Ge nanowire and Ni metal contacts. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) studies reveal a wide temperature range to convert the Ge nanowire to single-crystalline Ni(2)Ge by a thermal diffusion process. The maximum current density of the fully germanide Ni(2)Ge nanowires exceeds 3.5 × 10(7) A cm(-2), and the resistivity is about 88 μΩ cm. The in situ reaction examined by TEM shows atomically sharp interfaces for the Ni(2)Ge/Ge/Ni(2)Ge heterostructure. The interface epitaxial relationships are determined to be [Formula: see text] and [Formula: see text]. Back-gate field effect transistors (FETs) were also fabricated using this low resistivity Ni(2)Ge as source/drain contacts. Electrical measurements show a good p-type FET behavior with an on/off ratio over 10(3) and a one order of magnitude improvement in hole mobility from that of SFLS-synthesized Ge nanowire.

  16. Synthesis and magnetic properties of multilayer Ni/Cu and NiFe/Cu ...

    Indian Academy of Sciences (India)

    (EV5 VSM, ADE Technologies) and MFM (D3100, Digital Instrument) were used to characterize the magnetic properties of these nanowires. 3. Discussion. The bamboo-like structure of Ni/Cu nanowires is shown in figure 1. From the. TEM micrograph the thickness of Ni layer and Cu layer are 400 nm and 50 nm, respectively.

  17. Eutectic superalloys strengthened by delta Ni3Cb lamellae, and gamma prime, Ni3Al precipitates.

    Science.gov (United States)

    Lemkey, F. D.; Thompson, E. R.

    1972-01-01

    Bivariant eutectic alloys, located on a liquidus surface within the Ni-Cb-Cr-Al quaternary, were identified which permitted the production of aligned delta Ni3Cb lamellae within a nichrome matrix containing the fcc precipitate gamma prime Ni3Al. The volume fraction of delta and gamma prime could be varied significantly by compositional changes. After directional solidification certain alloys possessed improved ductility and corrosion resistance with respect to the Ni3Al-Ni3Cb eutectic, while their values of tensile and creep strength approached or exceeded those for the Ni3Al-Ni3Cb pseudobinary system. The mechanical properties of the directionally solidified alloy, Ni-19.7 wt % Cb-6.0 wt % Cr-2.5 wt % Al, were evaluated. Its longitudinal strength in tension and creep was found to be superior to all advanced nickel base superalloys. It is thus demonstrated that useful properties for gas turbine airfoil applications can be achieved by reinforcing a strong and tough gamma nichrome matrix containing precipitated gamma prime by a strong lamellar intermetallic compound having greater strength at elevated temperature.

  18. Enhanced Electrocatalytic Activity for Water Splitting on NiO/Ni/Carbon Fiber Paper

    Directory of Open Access Journals (Sweden)

    Ruoyu Zhang

    2016-12-01

    Full Text Available Large-scale growth of low-cost, efficient, and durable non-noble metal-based electrocatalysts for water splitting is crucial for future renewable energy systems. Atomic layer deposition (ALD provides a promising route for depositing uniform thin coatings of electrocatalysts, which are useful in many technologies, including the splitting of water. In this communication, we report the growth of a NiO/Ni catalyst directly on carbon fiber paper by atomic layer deposition and report subsequent reduction and oxidation annealing treatments. The 10–20 nm NiO/Ni nanoparticle catalysts can reach a current density of 10 mA·cm−2 at an overpotential of 189 mV for hydrogen evolution reactions and 257 mV for oxygen evolution reactions with high stability. We further successfully achieved a water splitting current density of 10 mA·cm−2 at 1.78 V using a typical NiO/Ni coated carbon fiber paper two-electrode setup. The results suggest that nanoparticulate NiO/Ni is an active, stable, and noble-metal-free electrocatalyst, which facilitates a method for future water splitting applications.

  19. Adherencia al tratamiento en niñas y niños con VIH

    Directory of Open Access Journals (Sweden)

    Ana María Ruiz Navia

    2009-01-01

    Full Text Available Este artículo describe y determina el grado de adherencia al tratamiento en niños y niñas con VIH/ SIDA teniendo en cuenta los comportamientos y las variables asociadas a ésta. La muestra estuvo conformada por 1 niño y 5 niñas, diagnosticados con VIH, y su respectivo cuidador primario, quienes respondieron a la entrevista semiestructurada de evaluación de adherencia para niños y niñas con VIH/ SIDA ad hoc y a la entrevista semiestructurada de evaluación de adherencia para niños y niñas con VIH/SIDA versión cuidador primario ad hoc, respectivamente. Los resultados muestran la presencia de conductas de adherencia en los participantes del estudio, evidenciando la influencia de una serie de variables determinantes para este comportamiento. Cinco de los participantes cumplieron más del 95% de adherencia, mientras que uno se ubicó por debajo de este porcentaje. Como aspectos centrales se destacan la influencia de los estados emocionales en la toma del medicamento y la importancia del rol del cuidador primario en la adherencia.

  20. Probing the semi-magicity of $^{68}$Ni via the $^{3}$H($^{66}$Ni,$^{68}$Ni)p two-neutron transfer reaction in inverse kinematics

    CERN Multimedia

    Reiter, P; Blazhev, A A; Kruecken, R; Franchoo, S; Mertzimekis, T; Darby, I G; Van de walle, J; Raabe, R; Elseviers, J; Gernhaeuser, R A; Sorlin, O H; Georgiev, G P; Bree, N C F; Habs, D; Chapman, R; Gaudefroy, L; Diriken, J V J; Jenkins, D G; Kroell, T; Axiotis, M; Huyse, M L; Patronis, N

    We propose to perform the two-neutron transfer reaction $^{3}$H($^{66}$Ni, $^{68}$Ni)$p$ using the ISOLDE radioactive ion beam at 2.7 $A$ MeV and the MINIBALL + T-REX setup to characterize the 0$^{+}$ and 2$^{+}$ states in $^{68}$Ni.

  1. First-Principles Study of Substitution of Au for Ni in Ni3Sn4

    Science.gov (United States)

    Tian, Yali; Wu, Ping

    2018-02-01

    First-principles calculations were performed to investigate the effects of substitution of Au for Ni on the structural, elastic, thermodynamic and electronic properties of Ni3Sn4. The calculated lattice constants for the pure phase are consistent with the reported values. Substitution of Au for Ni results in a stable thermodynamic structure. The bulk modulus, shear modulus, Young's modulus, hardness and thermal conductivity are decreased and the relative brittleness is improved after substitution. A three-dimensional graphic representation of the anisotropy of Young's modulus indicates that substitution of Au for Ni increases the anisotropy. All of the compound compositions examined are metallic and nonmagnetic. The electronic density of states manifests a conjoined peak between - 6 eV and - 4 eV hybridized by Au-d electrons and Sn-p electrons when the fraction of Au atom is above 14.29 at.% in Ni3Sn4.

  2. Ni(OH){sub 2} and NiO nano structures: Synthesis, characterization and electrochemical performance

    Energy Technology Data Exchange (ETDEWEB)

    Saghatforoush, Lotf Ali; Sanati, Soheila; Mehdizadeh, Robabeh [Payam Noor Univ., Tehran (Iran, Islamic Republic of); Hasanzadeh, Mohammad [Tabriz Univ. of Medical Sciences, Tabriz (Iran, Islamic Republic of)

    2012-04-15

    Hydrothermal route have been used in different conditions for preparation of Ni(OH){sub 2} nano structures. The NiO nanoparticles were obtained by calcining the Ni(OH){sub 2} precursor at 450 .deg. C for 2 h. The effect of sodium dodecyl sulfonate (SDS) as surfactant on the morphology and size of Ni(OH){sub 2} nanoparticles were discussed in detail. X-ray diffraction (XRD), Scanning electron microscopy (SEM), Transmission electron microscopy (TEM) and Fourier transform infrared (FT-IR) spectroscopy were used to characterize the products. The growth mechanism of the as-synthesized nano structures was also discussed in detail based on the experimental results. Coming up, the NiO nanoparticle modified carbon paste electrode was applied to the determination of captopril in aqueous solution.

  3. Effect of amount of glycine as fuel in obtaining nanocomposite Ni/NiO

    International Nuclear Information System (INIS)

    Simoes, A.N.; Simoes, V.N.; Neiva, L.S.; Quirino, M.R.; Vieira, D.A.; Gama, L.

    2010-01-01

    This paper proposes to investigate the effect of the amount of glycine in obtaining nanocomposite Ni/NiO synthesized by combustion reaction technique. The amount of glycine used was calculated on the stoichiometric composition of 50% and 100%. Characterizations by X-ray diffraction (XRD), N2 adsorption by the BET method and scanning electron microscopy (SEM) were performed with powder of Ni/NiO result. The analysis of X-ray diffraction showed the presence of crystalline NiO phase in the presence of nickel as a secondary phase, whose amount increased with the amount of glycine. Increasing the concentration of glycine also caused an increase in surface area, which ranged from 1.1 to 1.4 m 2 /g. The micrographs revealed the formation of soft agglomerates with porous appearance and easy dispersions. It can be concluded that the synthesis is effective to obtain nanosized powders. (author)

  4. Mechanical alloying of the FeNi-Ag system

    International Nuclear Information System (INIS)

    Gonzalez, G.; Ibarra, D.; Ochoa, J.; Villalba, R.; Sagarzazu, A.

    2007-01-01

    The Fe-Ni-Ag system is of particular interest for its potential applications as soft magnetic granular material with small magnetic grains embedded in a non-magnetic metal matrix. Under equilibrium conditions: Fe-Ag and Ni-Ag are immiscible and Fe-Ni shows complete solubility. These materials are particularly important for magnetoresistivity properties. The properties of these alloys are closely related to their microstructure; therefore, a detailed study of the transformations occurring during milling was undertaken using pre-alloyed Fe x Ni 100-x (x = 30, 50 and 70) further milled with different Ag content to give the following alloys compositions (Fe x -Ni 100-x ) 100-y Ag y (y = 5, 20, 60). Consolidation of the mechanically alloyed powders by sintering at 950 o C was performed. Morphological and structural characterization of the sintered powders was carried out by scanning and transmission electron microscopy and X-ray diffraction. Fe 30 Ni 70 and Fe 50 Ni 50 formed ordered FeNi 3 compound. Fe 70 Ni 30 showed the formation of a mixture of γ-(Fe,Ni) and α-Fe(Ni) solid solutions. The mixture of these systems with Ag showed the metal solid solutions surrounded by Ag islands of Fe x Ni y -Ag, There was also evidence of Ag diffusing into the γ-(Fe,Ni). High Ag content (60%) shows formation of islands of FeNi surrounded by Ag. Sintering is always improved with the Ag content

  5. Magnetoresistance of nanogranular Ni/NiO controlled by exchange anisotropy

    International Nuclear Information System (INIS)

    Del Bianco, L.; Spizzo, F.; Tamisari, M.; Allia, P.

    2013-01-01

    A link between exchange anisotropy and magnetoresistance has been found to occur in a Ni/NiO sample consisting of Ni nanocrystallites (mean size ∼13 nm, Ni content ∼33 vol%) dispersed in a NiO matrix. This material shows metallic-type electric conduction and isotropic spin-dependent magnetoresistance as well as exchange bias effect. The latter is the outcome of an exchange anisotropy arising from the contact interaction between the Ni phase and the NiO matrix. Combined analysis of magnetization M(H) and magnetoresistance MR(H) loops measured in the 5–250 K temperature range after zero-field-cooling (ZFC) and after field-cooling (FC) from 300 K reveals that the magnetoresistance is influenced by exchange anisotropy, which is triggered by the FC process and can be modified in strength by varying the temperature. Compared to the ZFC case, the exchange anisotropy produces a horizontal shift of the FC MR(H) loop along with a reduction of the MR response associated to the reorientation of the Ni moments. A strict connection between magnetoresistance and remanent magnetization of FC loops on one side and the exchange field on the other, ruled by exchange anisotropy, is indicated. - Highlights: • Nanogranular Ni/NiO with giant magnetoresistance (MR) and exchange bias effect. • Exchange anisotropy produces a shift of the field-cooled MR(H) loop and reduces MR. • MR, remanence of field-cooled loops and exchange field are three correlated quantities. • It is possible to control MR of nanogranular systems through the exchange anisotropy

  6. Oxide Scales Formed on NiTi and NiPtTi Shape Memory Alloys

    Science.gov (United States)

    Smialek, James L.; Garg, Anita; Rogers, Richard B.; Noebe, Ronald D.

    2011-01-01

    Ni-49Ti and Ni-30Pt-50Ti (at.%) shape memory alloys were oxidized isothermally in air over the temperature range of 500 to 900 C. The microstructure, composition, and phase content of the scales were studied by SEM, EDS, XRD, and metallography. Extensive plan view SEM/EDS identified various features of intact or spalled scale surfaces. The outer surface of the scale was a relatively pure TiO2 rutile structure, typified by a distinct highly striated and faceted crystal morphology. Crystal size increased significantly with temperature. Spalled regions exhibited some porosity and less distinct features. More detailed information was obtained by correlation of SEM/EDS studies of 700 C/100 hr cross-sections with XRD analyses of serial or taper-polishing of plan surfaces. Overall, multiple layers exhibited graded mixtures of NiO, TiO2, NiTiO3, Ni(Ti) or Pt(Ni,Ti) metal dispersoids, Ni3Ti or Pt3Ti depletion zones, and substrate, in that order. The NiTi alloy contained a 3 at.% Fe impurity that appeared in embedded localized Fe-Ti-rich oxides, while the NiPtTi alloy contained a 2 v/o dispersion of TiC that appeared in lower layers. The oxidation kinetics of both alloys (in a previous report) indicated parabolic growth and an activation energy (250 kJ/mole) near those reported in other Ti and NiTi studies. This is generally consistent with TiO2 existing as the primary scale constituent, as described here.

  7. Fuel cell power generation facility; Nenryo denchi hatsuden sochi

    Energy Technology Data Exchange (ETDEWEB)

    Hara, T.; Kato, K. [Aishin AW Co. Ltd., Aichi (Japan); Tanizaki, K.; Ishiko, C. [Equos Research Co. Ltd., Tokyo (Japan)

    1996-07-12

    In a fuel cell power generation facility with a carbon monoxide removal equipment to remove carbon monoxide in a reformed gas by oxidation, a reversed flow of the residual reformed gas in the reformed gas feeding line to the fuel reforming equipment cannot be prevented by a previous suspension technique. This invention aims to present a method to prevent a reversed flow of the residual reformed gas and to protect effectively the fuel cell power generation facility against the danger of catching fire or explosion. This invention relates to a fuel cell power generation facility installed with a fuel reforming equipment and a carbon monoxide removal equipment to remove carbon monoxide in the reformed gas by oxidation, which is equipped with reversed flow prevention devices on the oxidizer gas feeding duct to the carbon monoxide removal equipment, on the reformed gas feeding duct from the fuel reforming equipment to the carbon monoxide removal equipment and on the source fuel feeding duct to the fuel reforming equipment. The reversed flow prevention devices are made of direction control valves or pressure control valves. 2 figs.

  8. Cell with scrolled electrodes. Uzumaki jo denkyokutai wo sonaeta denchi

    Energy Technology Data Exchange (ETDEWEB)

    Kamibayashi, M.; Morioka, Y. (Sanyo Electric Co. Ltd., Osaka (Japan))

    1990-10-03

    Non-sintered electrode plates produced by direct filling of paste state active materials in metal fiber felt type porous body are proposed recently for use as electrode plates for alkali cells and the like. Although this type of electrode plates can be produced with a simple facility because sintering process is not required, it has a shorcoming of internal short circuiting because metal fibers pass through the separator due to fuzzing of metal fiber. According to this invention, a sheet comprising metallic fibers oriented at right angles against the scrolled direction of the electrode plate is stacked on the surface of the metal fiber felt type porous body sheet when it is scrolled with the interposed separator. As the result, fibers are not bent and does not protrude from the surface of sheet to pass through the separator because each metallic fiber comprising the metallic sheet on the surface are arranged at a right angle against the direction of scrolling of the porous sheet. 2 figs., 1 tab.

  9. Hydrothermal synthesis of α-Ni(OH){sub 2} and its conversion to NiO with electrochemical properties

    Energy Technology Data Exchange (ETDEWEB)

    Cai, Yong; Ma, Jianmin, E-mail: nanoelechem@hnu.edu.cn; Wang, Taihong, E-mail: thwang@hnu.edu.cn

    2014-01-05

    Highlights: • α-Ni(OH){sub 2} microspheres have been synthesized with triethanolamine. • The formation mechanism of α-Ni(OH){sub 2} microspheres is suggested. • NiO deriving from α-Ni(OH){sub 2} microspheres exhibits better electrochemical performances. -- Abstract: The paper reports the fabrication of microscale NiO matrixes with enhanced electrochemical properties through annealing the corresponding chrysanthemum-like α-Ni(OH){sub 2} microspheres. The precursor α-Ni(OH){sub 2} can be synthesized by a hydrothermal method using triethanolamine as the alkaline source. The formation mechanism of chrysanthemum-like α-Ni(OH){sub 2} microspheres is properly discussed. Furthermore, the electrochemical experiments demonstrate that the microscale NiO matrixes show superior electrochemical behavior in lithium-ion batteries due to their unique structures.

  10. Hydrogen absorption kinetics and structural properties of Mg85Ni10Ca5 and Mg90Ni10

    International Nuclear Information System (INIS)

    Aoki, Masakazu; Saito, Katsushi; Towata, Shin-ichi

    2005-01-01

    Mg 85 Ni 10 Ca 5 and Mg 90 Ni 10 were prepared by melting mixtures of the elements in mild steel crucibles and pouring them into copper molds. Hydrogen absorption kinetics and structural properties of the alloys were characterized by the volumetric method using a Sievert's apparatus, X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The crystallite size of Mg in Mg 85 Ni 10 Ca 5 , which is evaluated by XRD peak broadening, is about 50% smaller than that in Mg 90 Ni 10 . In addition, the nanometer-scale structure composed of Mg, Mg 2 Ni, Mg 2 Ca was observed in Mg 85 Ni 10 Ca 5 . Mg 85 Ni 10 Ca 5 shows better hydrogen absorption kinetics than Mg 90 Ni 10 in the temperature range of room temperature to 573 K. The better absorption kinetics of Mg 85 Ni 10 Ca 5 is mainly attributed to the nanometer-scale structure

  11. Evolution of Ni nanofilaments and electromagnetic coupling in the resistive switching of NiO

    Science.gov (United States)

    Luo, Yuxiang; Zhao, Diyang; Zhao, Yonggang; Chiang, Fu-Kuo; Chen, Pengcheng; Guo, Minghua; Luo, Nannan; Jiang, Xingli; Miao, Peixian; Sun, Ying; Chen, Aitian; Lin, Zhu; Li, Jianqi; Duan, Wenhui; Cai, Jianwang; Wang, Yayu

    2014-12-01

    Resistive switching effect in conductor/insulator/conductor thin-film stacks is promising for resistance random access memory with high-density, fast speed, low power dissipation and high endurance, as well as novel computer logic architectures. NiO is a model system for the resistive switching effect and the formation/rupture of Ni nanofilaments is considered to be essential. However, it is not clear how the nanofilaments evolve in the switching process. Moreover, since Ni nanofilaments should be ferromagnetic, it provides an opportunity to explore the electromagnetic coupling in this system. Here, we report a direct observation of Ni nanofilaments and their specific evolution process for the first time by a combination of various measurements and theoretical calculations. We found that multi-nanofilaments are involved in the low resistance state and the nanofilaments become thin and rupture separately in the RESET process with subsequent increase of the rupture gaps. Theoretical calculations reveal the role of oxygen vacancy amount in the evolution of Ni nanofilaments. We also demonstrate electromagnetic coupling in this system, which opens a new avenue for multifunctional devices.Resistive switching effect in conductor/insulator/conductor thin-film stacks is promising for resistance random access memory with high-density, fast speed, low power dissipation and high endurance, as well as novel computer logic architectures. NiO is a model system for the resistive switching effect and the formation/rupture of Ni nanofilaments is considered to be essential. However, it is not clear how the nanofilaments evolve in the switching process. Moreover, since Ni nanofilaments should be ferromagnetic, it provides an opportunity to explore the electromagnetic coupling in this system. Here, we report a direct observation of Ni nanofilaments and their specific evolution process for the first time by a combination of various measurements and theoretical calculations. We found

  12. Exchange bias beyond the superparamagnetic blocking temperature of the antiferromagnet in a Ni-NiO nanoparticulate system

    Science.gov (United States)

    Roy, Aparna; De Toro, J. A.; Amaral, V. S.; Muniz, P.; Riveiro, J. M.; Ferreira, J. M. F.

    2014-02-01

    We report magnetic and exchange bias studies on Ni-NiO nanoparticulate systems synthesized by a two-step process, namely, chemical reduction of a Ni salt followed by air annealing of the dried precipitate in the temperature range 400-550 °C. Size of Ni and NiO crystallites as estimated from X-ray diffraction line broadening ranges between 10.5-13.5 nm and 2.3-4 nm, respectively. The magneto-thermal plots (M-T) of these bi-magnetic samples show a well developed peak in the vicinity of 130 K. This has been identified as the superparamagnetic blocking temperature "TB" of NiO. Interestingly, all samples exhibit exchange bias even above their respective NiO blocking temperatures, right up to 300 K, the maximum temperature of measurement. This is in contrast to previous reports since exchange bias requires the antiferromagnetic NiO to have a stable direction of its moment in order to pin the ferromagnet (Ni) magnetization, whereas such stability is unlikely above TB since the NiO is superparamagnetic, its moment flipping under thermal activation. Our observation is elucidated by taking into account the core-shell morphology of the Ni-NiO nanoparticles whereby clustering of some of these nanoparticles connects their NiO shells to form extended continuous regions of NiO, which because of their large size remain blocked at T > TB, with thermally stable spins capable of pinning the Ni cores and giving rise to exchange bias. The investigated samples may thus be envisaged as being constituted of both isolated core-shell Ni-NiO nanoparticles as well as clustered ones, with TB denoting the blocking temperature of the NiO shell of the isolated particles.

  13. La niña proletaria

    Directory of Open Access Journals (Sweden)

    Cartabia, Sabrina A.

    2011-12-01

    Full Text Available El presente trabajo se propone trazar un paralelo entre el cuento de Osvaldo Lamborghini “El niño proletario”, el cual, según la autora del ensayo, introduce al lector en la lucha de clases y el sometimiento de los/as proletarios/as, que sufren las mujeres, en particular a través de la violencia sexual. De esa forma la autora se pregunta si el poder que ciertas clases detentan sobre otras no influye también sobre el sometimiento de la mujer. El ensayo analiza además cómo la violencia sexual es una herramienta que constituye la base de la desigualdad, el sometimiento y la degradación de la mujer, al igual que constituye una herramienta de opresión de otros grupos vulnerables como los niños y niñas.

  14. Analisis Kesalahan Penggunaan Partikel Ni dan De

    Directory of Open Access Journals (Sweden)

    Elisa Carolina Marion

    2008-05-01

    Full Text Available Articel clasified the type and cause of mistake done by Bina Nusantara Japanese student of six and eight semesters on the use of ni (に and de (で particles indicating place in the exam. Data were collected from library research and distributed questionnaires to 79 student of the 6th and 8th semester, Japanese departement. The result showed that the student of Japanese language did not make the same mistake in using the ni (に and de (で particles having the some function in indicating place. It is concluded that the respondents are able to use the ni (に and de (で particles.       

  15. Advances in developing TiNi nanoparticles

    International Nuclear Information System (INIS)

    Castro, A. Torres; Cuellar, E. Lopez; Mendez, U. Ortiz; Yacaman, M. Jose

    2006-01-01

    The elaboration of nanoparticles has become a field of great interest for many scientists. Nanoparticles possess different properties than those ones shown in bulk materials. Shape memory alloys have the exceptional ability to recuperate its original shape by simple heating after being 'plastically' deformed. When this process is originated, important changes in properties, as mechanical and electrical, are developed in bulk material. If there is possible to obtain nanoparticles with shape memory effects, these nanoparticles could be used in the elaboration of nanofluids with the ability to change their electrical and thermal conductivity with temperature changes, i.e., smart nanofluids. In this work, some recent results and discussion of TiNi nanoparticles obtained by ion beam milling directly from a TiNi wire with shape memory are presented. The nanoparticles obtained by this process are about 2 nm of diameter with a composition of Ti-41.0 at.% Ni. Synthesized nanoparticles elaborated by this method have an ordered structure

  16. Effects of phase transformation and interdiffusion on the exchange bias of NiFe/NiMn

    International Nuclear Information System (INIS)

    Lai, Chih-Huang; Lien, W. C.; Chen, F. R.; Kai, J. J.; Mao, S.

    2001-01-01

    The correlation between the exchange field of NiFe/NiMn and the phase transformation of NiMn was investigated. Transmission electron microscopy (TEM) dark-field images, contributed by the order phase of NiMn, were used to identify the location and volume fraction of the order phase. TEM selected area diffraction patterns showed the (110) superlattice diffraction rings of NiMn, verifying the existence of the order phase in the annealed samples. The order volume fraction can be calculated by the dark field image contributed by the (110) diffraction. The exchange field increased almost linearly with increasing order volume fraction. Energy dispersive x-ray spectroscopy attached to TEM indicated that Mn diffused into NiFe for annealing at 280 degreeC, leading to a larger coercivity and small coercivity squareness. Part of the NiMn still maintains the paramagnetic phase even after annealing at 280 degreeC. [copyright] 2001 American Institute of Physics

  17. Corrosion and wear resistance study of Ni-P and Ni-P-PTFE nanocomposite coatings

    Science.gov (United States)

    Ankita, Sharma; Singh, Ajay

    2011-09-01

    This article reports on the corrosion and wear resistance of Ni-P and Ni-P-PTFE nanocomposite coatings deposited on mild steel substrates using the electroless plating technique. The coatings were characterized by scanning electron microscopy (SEM), energy dispersive analysis of X-Ray (EDAX), and X-ray diffractometry (XRD). The coatings were smooth and had thicknesses between 7 and 23 µm. They contained Ni, P, and additionally, F, in the case of the Ni-P-PTFE films. A broadening of the Ni peak in XRD was attributed to the amorphous nature and/or fine grain size of the films. Corrosion resistance was measured using immersion and electrochemical polarization tests in 3.5% NaCl solution whereas wear resistance was determined by the pin-on-disc method. Both Ni-P and Ni-P-PTFE coatings exhibited significant improvement in corrosion (in salty media) and wear behavior. Furthermore, the addition of PTFE in the coatings showed improvement in their corrosion resistance as well as a reduction in friction coefficient. Our testing revealed that the coatings' wore out following the "adhesive type" mechanism.

  18. Exchange bias in finite sized NiO nanoparticles with Ni clusters

    Energy Technology Data Exchange (ETDEWEB)

    Gandhi, Ashish Chhaganlal; Lin, Jauyn Grace, E-mail: jglin@ntu.edu.tw

    2017-02-15

    Structural and magnetic properties of finite sized NiO nanoparticles are investigated with synchrotron X-ray diffraction (XRD), transmission electron microscopy, magnetometer and ferromagnetic resonance (FMR) spectroscopy. A minor Ni phase is detected with synchrotron XRD, attributed to the oxygen defects in the NiO core. A considerable exchange bias of ~100 Oe is observed at 50 K and it drops abruptly and vanishes above 150 K, in association with the reduction of frozen spins. FMR data indicate a strong interaction between ferromagnetic (FM) and antiferromagnetic (AFM) phases below 150 K, consistent with the picture of isolated FM clusters in AFM matrix. - Highlights: • Structural and magnetic properties of finite sized NiO nanoparticles are systematically investigated with several advanced techniques. • A strong interaction between ferromagnetic and antiferromagnetic phases is found below 150 K. • Exchange bias field in finite sized NiO nanoparticles is due to anisotropy energy of Ni clusters over riding the domain wall energy of NiO.

  19. Exchange bias in finite sized NiO nanoparticles with Ni clusters

    International Nuclear Information System (INIS)

    Gandhi, Ashish Chhaganlal; Lin, Jauyn Grace

    2017-01-01

    Structural and magnetic properties of finite sized NiO nanoparticles are investigated with synchrotron X-ray diffraction (XRD), transmission electron microscopy, magnetometer and ferromagnetic resonance (FMR) spectroscopy. A minor Ni phase is detected with synchrotron XRD, attributed to the oxygen defects in the NiO core. A considerable exchange bias of ~100 Oe is observed at 50 K and it drops abruptly and vanishes above 150 K, in association with the reduction of frozen spins. FMR data indicate a strong interaction between ferromagnetic (FM) and antiferromagnetic (AFM) phases below 150 K, consistent with the picture of isolated FM clusters in AFM matrix. - Highlights: • Structural and magnetic properties of finite sized NiO nanoparticles are systematically investigated with several advanced techniques. • A strong interaction between ferromagnetic and antiferromagnetic phases is found below 150 K. • Exchange bias field in finite sized NiO nanoparticles is due to anisotropy energy of Ni clusters over riding the domain wall energy of NiO.

  20. Bone Cell–materials Interactions and Ni Ion Release of Anodized Equiatomic NiTi Alloy

    Science.gov (United States)

    Bernard, Sheldon A.; Balla, Vamsi Krishna; Davies, Neal M.; Bose, Susmita; Bandyopadhyay, Amit

    2011-01-01

    Laser processed NiTi alloy was anodized for different durations in H2SO4 electrolyte with varying pH to create biocompatible surfaces with low Ni ion release as well as bioactive surfaces to enhance biocompatibility and bone cell-materials interactions. The anodized surfaces were assessed for their in vitro cell-materials interactions using human fetal osteoblast (hFOB) cells for 3, 7 and 11 days, and Ni ion release up to 8 weeks in simulated body fluids. The results were correlated with surface morphologies of anodized surfaces characterized using field-emission scanning electron microscopy (FESEM). The results show that the anodization creates a surface with nano/micro roughness depending on anodization conditions. The hydrophilicity of NiTi surface was found to improve after anodization due to lower contact angles in cell media, which dropped from 32° to NiTi surfaces after anodization. This work indicates that anodization of NiTi alloy has a positive influence on the surface energy and surface morphology, which in turn improve bone cell-materials interactions and reduce Ni ion release in vitro. PMID:21232641

  1. Tipos especiales de niños

    Directory of Open Access Journals (Sweden)

    Mercedes Rodrigo Bellido

    1946-09-01

    Full Text Available En las tres últimas lecciones han sido expuestas algunas consideraciones referentes a niños y adolescentes desde el nacimiento hasta el dintel de la juventud. En todas ellas hemos procurado poner de relieve la necesidad de individualizar el conocimiento de cada niño para obtener mejores resultados en su adaptación a su futura vida de adultos, En todas ellas  nos hemos referido al llamado niño normal. Nos corresponde en la lección de hoy ocuparnos can la superficialidad característica de estas charlas tipo-muestrario, de otras categorías de niños muy dignos de interés.. quienes unas por exceso, otros por defecto, otros por dificultades de adaptación por diferentes causas, se desvían de la línea media de la normalidad. Consideramos que no está fuera del lugar, aquí, el tema de los niños excepcionales y por el contrario que es necesario intensificar el estudio de los trastornos de la vida mental y emocional de los niños en la preparación de los estudiantes de Medicina. Y no es nuestra solo esta opinión; no hace mucho tiempo en la Medical School de Ia Universidad de Minnessota hemos sabido que se ha hecho un intento de considerar y evaluar factores emocionales ambientales sobre las mismas bases que los descubrimientos fisiológicos.

  2. Protective material for solar cell; Taiyo denchiyo hyomen hogozai

    Energy Technology Data Exchange (ETDEWEB)

    Iimura, M.; Domoto, T. [Nitto Denko Corp., Osaka (Japan)

    1998-02-03

    The protective material for the solar cell of this invention consists of fluororesin containing from 1 to 20wt% titanium oxide particles with the particle size range from 1 to 1,000nm. Surface contamination of the protective material for the solar cell and deterioration of the adhesive are prevented when titanium oxide with particular particle size is contained in the fluororesin in a particular range as mentioned above. Titanium oxide has photocatalytic performance to decompose organic substances, and the surface protective material for the solar cell containing titanium oxide can decompose and remove dirt such as dust adhering the surface for preventing surface contamination. In addition, total light permeability can be maintained at high rate and the permeability of less than 350nm ultraviolet rays causing deterioration of the adhesive can be decreased if the particle size and content of titanium oxide are specified. Titanium dioxide of anatase type crystal structure is ideal as the titanium oxide. 1 tab.

  3. Generation and Decay Mechanisms of Ningaloo Niño/Niña

    Science.gov (United States)

    Kataoka, Takahito; Tozuka, Tomoki; Yamagata, Toshio

    2017-11-01

    Using an ocean model, generation and decay mechanisms of warm/cool sea surface temperature anomalies (SSTAs) off Western Australia, or Ningaloo Niño/Niña, are investigated through the calculation of a mixed-layer temperature (MLT) balance taking the mixed-layer depth (MLD) variation into account. Since Ningaloo Niño/Niña develops owing to local air-sea interaction and/or remote forcing, events are classified into two cases based on alongshore wind anomalies and analyzed separately. It is revealed that the anomalous meridional advection associated with the stronger Leeuwin Current and the enhanced warming by the climatological shortwave radiation because of the shallower MLD generate warm SSTAs in the coastal region for both cases of Ningaloo Niño. On the other hand, the latent heat flux damps SSTAs only in a case without northerly alongshore wind anomalies. In the decay, larger sensible heat loss is important. Because of the reduced meridional temperature gradient, the meridional advection eventually damps SSTAs. The sensitivity change to the climatological shortwave radiation owing to MLD anomalies explains offshore MLT tendency anomalies for both cases throughout the events. The mechanisms for Ningaloo Niña are close to a mirror image of Ningaloo Niño but differ in that the latent heat flux damps offshore SSTAs. The seasonal phase-locking nature of Ningaloo Niño/Niña is related to the seasonal variations of MLD and surface heat fluxes, which regulate the amplitude and sign of the sensitivity change to surface heat fluxes. It is also related to the seasonal variations of the Leeuwin Current and meridional temperature gradient through advection anomalies.

  4. Ionizing Radiation Effects in Ni Nanotubes

    Science.gov (United States)

    Shlimas, D.; Kozlovsky, A.; Shumskaya, A.; Kaniukov, E.; Ibragimova, M.; Zdorovets, M.; Kadyrzhanov, K.

    2017-01-01

    Polycrystalline nickel nanotubes with diameter of 380 nm and wall thickness 95 nm were synthesized by electrochemical method using PET track-etched membranes with thickness of 12 μm. A comprehensive study of the structural, morphological and electrical characteristics of Ni nanotubes irradiated with C+13 ions with energy 1.75 MeV/nucleon and fluence ranging from 109 to 5 × 1011 cm-2 was carried out. The ability of modification of structural parameters such as lattice parameter and the average size of crystallites and conductivity of Ni nanotubes by irradiation was shown.

  5. Salud mental del niño

    OpenAIRE

    Ospina de González, Bernarda

    1987-01-01

    Es ya reconocida por todos las importancia de los primeros años de vida en la estructutración de la personalidad y, por consiguiente, en la salud mental del niño. En este artículo se hace una síntesis de los diferentes aspectos del desarrollo de la personalidad infanltil que seben ser conocidos por el personal de salud para estar en condiciones de brindar una atención integral a la madre y al niño. Con igual propósito se señalan algunos patrones de tipo psicosocial que influyen en la estabili...

  6. Magnetic anisotropy of Ni/Cr multilayers

    International Nuclear Information System (INIS)

    Kang, S.; Xia, H.

    1997-01-01

    The magnetic anisotropy of Ni/Cr multilayers has been investigated by using vibrating sample magnetometer (VSM) and ferromagnetic resonance techniques (FMR). The FMR spectra are obtained as a function of the orientation of the applied magnetic field from in-plane to out-of-plane. The results are fitted theoretically to determine the magnetic anisotropy. From VSM and FMR, a positive value for Ni/Cr interface anisotropy is obtained, which favours a perpendicular easy axis. The possible mechanism for the perpendicular anisotropy has been discussed and it may be attributed to the magnetostriction, caused by intrinsic stress due to lattice mismatch. (orig.). With 005 figs., 001 tabs

  7. The structure of extruded NiAl

    Science.gov (United States)

    Baker, I.; Schulson, E. M.

    1984-01-01

    The deformation structure of Ni-rich NiAl extruded at 550 C has been characterized by transmission electron microscopy and by optical microscopy. Dislocations having a(100) Burgers vectors were found as complex networks, tangles, and prismatic loops. a(110) dislocations, which were rare, were concluded to arise from reactions of a(100) dislocations. Evidence of recovery and recrystallization was obtained. Extrusion was deemed to have been possible by the operation of (hko)(001) slip systems (often in plane strain flow) plus diffusion-assisted processes.

  8. Comparative effectiveness of NiCl2, Ni- and NiO-NPs in controlling oral bacterial growth and biofilm formation on oral surfaces.

    Science.gov (United States)

    Khan, Shams Tabrez; Ahamed, Maqusood; Alhadlaq, Hisham A; Musarrat, Javed; Al-Khedhairy, Abdulaziz

    2013-12-01

    Oral ailments are often treated with antibiotics, which are rendered ineffective as bacteria continue to develop resistance against them. It has been suggested that the nanoparticles (NPs) approach may provide a safer and viable alternative to traditional antibacterial agents. Therefore, nickel (Ni)- and nickel oxide (NiO)-NPs were synthesized, characterized and assessed for their efficacy in reducing oral bacterial load in vitro. Also, the effects of bulk compound NiCl2 (Ni ions), along with the Ni- and NiO-NPs on bacterial exopolysaccharide (EPS) production and biofilm formation on the surface of artificial teeth, and acrylic dentures, were investigated. Total bacteria from a healthy male were collected and adjusted to 4×109cells/ml for all the tests. Effect of the NPs on growth, biofilm formation, EPS production and acid production from glucose was tested using standard protocols. Data revealed that the Ni-NPs (average size 41.23nm) exhibited an IC50 value of 73.37μg/ml against total oral bacteria. While, NiO-NPs (average size 35.67nm) were found less effective with much higher IC50 value of 197.18μg/ml. Indeed, the Ni ions exhibited greater biocidal activity with an IC50 value of 70μg/ml. Similar results were obtained with biofilm inhibition on the surfaces of dental prostheses. The results explicitly suggested the effectiveness of tested Ni compounds on the growth of oral bacteria and biofilm formation in the order as NiCl2>Ni-NPs>NiO-NPs. The results elucidated that Ni-NPs could serve as effective nanoantibiotics against oral bacteria. Copyright © 2013 Elsevier Ltd. All rights reserved.

  9. Thermodynamics of disaggregated polymer composites based on nanosized powders of Ni and NiO

    Directory of Open Access Journals (Sweden)

    N. S. Volodina

    2015-03-01

    Full Text Available Technique to obtain disaggregated composites with uniform distribution of the Ni nanoparticles in a polymer matrix was developed on the example of epoxy resin. Disaggregated and aggregated composites based on butyl methacrylate copolymer with 5 wt% methacrylic acid and Ni and NiO nanoparticles were obtained. Enthalpies of mixing the components compositions in a wide range of compositions were defined using isothermal calorimetry. Parameters adhesive interaction at the interface and glassy polymer structure changes were calculated. The influence of the chemical nature of nanosized filler on interfacial energy was found.

  10. IMPURITY CENTRES.Ni+ and Ni3+ centers in X-irradiated CaF2

    OpenAIRE

    Casas, J.; Den Hartog, H.; Alcalá, R.

    1980-01-01

    Optical and EPR measurements of CaF2 : Ni before and after X-irradiation are reported. An absorption band at 255 nm grows during X-irradiation. The thermal evolution of this band and some bleaching experiments in 15 K X-irradiated samples containing Vk centers indicate that the 255 nm band is due to Ni+ centers. Some EPR signals associated with the Ni+ centers are also observed. Low temperature measurements show that there are two slightly different kinds of centers one of them having tetrago...

  11. Structure characterization of Ni/NiO and Ti/TiO2 interfaces

    International Nuclear Information System (INIS)

    Lamine, Brahim

    1983-01-01

    This research thesis reports the structure characterization of Ni-NiO and Ti-TiO 2 interfaces through an in-situ investigation of thin blade oxidation, of oxide germination and growth, and through a determination of mutual metal/oxide orientation relationships. Thin films of TiO 2 have also been characterized and the study of the influence of vacuum annealing on TiO 2 layer structure and morphology has been attempted. The examination of metal-oxide interface reveals a duplex structure of NiO and TiO 2 layers, and a preferential grain boundary oxidation of the underlying metal [fr

  12. X-ray fluorescence analysis of Fe - Ni - Mo systems

    International Nuclear Information System (INIS)

    Belyaev, E.E.; Ershov, A.V.; Mashin, A.I.; Mashin, N.I.; Rudnevskij, N.K.

    1998-01-01

    Procedures for the X-ray fluorescence determination of the composition and thickness of Fe - Ni - Mo thin films and the concentration of elements in thick films of the Fe - Ni - Mo alloy are developed [ru

  13. Enhancement of porous silicon photoluminescence using (Ni) treatment

    Science.gov (United States)

    Nabil, M.; Elnouby, M.; Gayeh, N.; Sakr, A. H.; Motaweh, H. A.

    2017-10-01

    A new method has been developed to improve the photoluminescence intensity of porous silicon (PS). Self-organized (PS) can be used in various fields. The deposition of metal nanoparticles (Ni) allows utilizing the obtained nano-composite for numerous applications such as sensor technology, biomedicine, and many more. (Ni/PS) nano-composite powders are prepared using Ni deposition on the PS powder surface. The (Ni/PS) powders became hydrophilic by the deposited Ni nanoparticles. At the different percentages of (Ni: PS), at a higher percentage than (3:1) the values of the crystallite size of Ni and PS are nearly equivalent which suggests the saturation case of PS surface by Ni particles. It also depends on the deposition time value. In this study, that is the commercialization of nanostructured materials, it is important that the manufacturing costs are appropriate and inexpensive for large scale production, in addition, the enhancement of the photoluminescence intensity of (PS).

  14. Effect of thermomechanical pre-treatment on short- and long-term Ni release from biomedical NiTi.

    Science.gov (United States)

    Freiberg, Katharina E; Bremer-Streck, Sibylle; Kiehntopf, Michael; Rettenmayr, Markus; Undisz, Andreas

    2014-05-01

    The effect of annealing and deformation on short-term (21days) and long-term (8months) Ni release from biomedical NiTi wires is studied. The deformation of annealed NiTi wires causes cracking and flaking of the surface oxide layer. Flaking of oxide particles does not uncover the Ni-rich layer underneath the surface oxide layer, since at sites where flaking occurs, a thin (∼25nm) layer of oxide remains on top of this Ni-rich layer. The number of cracks in the oxide and Ni-rich layer, respectively, increases with deformation, and intercrystalline crack propagation into the Ni-rich layer and the NiTi bulk is observed. In plastically deformed wires, the cracks may remain opened, providing access of immersion liquid to these zones. Characteristics and quantity of short-term Ni release are significantly affected by the pre-deformation, resulting in an up to 2 times higher total Ni release within the first 21days of deformed compared to annealed wires. Pre-deformation does not significantly influence long-term Ni release; all annealed and deformed samples exhibit similar long-term Ni release rates. The source of Ni during short-term release is the Ni contained in the surface zone of the oxide layer. For high pre-deformation, the Ni-rich layer is a second source for Ni. This second source is also the cause for Ni release in long-term immersion experiments. Copyright © 2014 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

  15. Simple solution-combustion synthesis of Ni-NiO@C nanocomposites with highly electrocatalytic activity for methanol oxidation

    Science.gov (United States)

    Yu, Jie; Ni, Yonghong; Zhai, Muheng

    2018-01-01

    Transition metal and its oxide composite nanomaterials are attracting increasing research interest due to their superior properties and extensive applications in many fields. In this paper, Ni-NiO@C nanocomposites were successfully synthesized in one step via a simple solution-combustion route, employing NiCl2 as the Ni source, oxygen in the atmosphere as the oxygen source, and ethanol as the solvent. The final product was characterized by powder X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), energy dispersive X-ray spectrometry (EDS), (high resolution) transmission electron microscopy (TEM/HRTEM), and Raman spectra. N2 gas sorption-desorption experiments uncovered that the BET surface area of Ni-NiO@C nanocomposites reached 161.9 m2 g-1, far higher than 34.2 m2 g-1 of Ni-NiO. The electrochemical measurement showed that the as-produced Ni-NiO@C nanocomposites presented better catalytic activity for the electro-oxidation of methanol than Ni-NiO and NiO, which provides a new catalyst selection for the electro-oxidation of methanol.

  16. Fabrication of CdTe/NiTe films on Ni foils by radio-frequency magnetron sputtering method

    International Nuclear Information System (INIS)

    Mu, Yannan; Zhou, Xiaoming; Yao, Huizhen; Su, Shi; Lv, Pin; Chen, Yanli; Wang, Jun; Fu, Wuyou; Song, Wenxu; Yang, Haibin

    2015-01-01

    Highlights: • The effects of T s on CdTe deposited on Ni by magnetron sputtering is investigated. • An effective method is studied of making CdTe/NiTe without post-treatment. • As-prepared CdTe/NiTe raised optical absorption and PEC properties. • Pre-deposited Te can react with Ni to generate NiTe at T s = 350 °C. - Abstract: Cadmium Telluride (CdTe) semiconductor thin films are fabricated on flexible Ni foil substrates using radio-frequency (RF) magnetron sputtering under different substrate temperatures. The crystal structure and properties of the prepared functional thin films were characterized with series analysis technologies. The characterization results revealed that Nickel Telluride (NiTe) phase formatted at the interface of CdTe and Ni substrate when substrate temperature (T s ) is 450 °C. Specially, XRD results demonstrated that CdTe/NiTe films could also be obtained by pre-depositing Te film on Ni and reducing T s to 350 °C. The investigation on optical and photoelectrochemical (PEC) properties of the products illustrated that compact CdTe/NiTe films had improved the absorption in the visible region. Furthermore, PEC measurements indicated that CdTe/NiTe/Ni photoelectrode can have a promising application in photovoltaic devices

  17. Effect of Synthetic Levers on Nickel Phosphide Nanoparticle Formation: Ni5P4 and NiP2.

    Science.gov (United States)

    Li, Da; Senevirathne, Keerthi; Aquilina, Lance; Brock, Stephanie L

    2015-08-17

    Due to their unique catalytic, electronic, and redox processes, Ni5P4 and NiP2 nanoparticles are of interest for a wide-range of applications from the hydrogen evolution reaction to energy storage (batteries); yet synthetic approaches to these materials are limited. In the present work, a phase-control strategy enabling the arrested-precipitation synthesis of nanoparticles of Ni5P4 and NiP2 as phase-pure samples using different Ni organometallic precursors and trioctylphosphine (TOP) is described. The composition and purity of the product can be tuned by changing key synthetic levers, including the Ni precursor, the oleylamine (OAm) coordinating solvent and TOP concentrations, temperature, time, and the presence or absence of a moderate temperature soak step to facilitate formation of Ni and/or Ni-P amorphous nanoparticle intermediates. Notably, the 230 °C intermediate step favors the ultimate formation of Ni2P and hinders further phosphidation to form Ni5P4 or NiP2 as phase-pure products. In the absence of this step, increasing the P/Ni ratio (13-20), reaction temperature (350-385 °C), and time (10-48 h) favors more P-rich phases, and these parameters can be adjusted to generate either Ni5P4 or NiP2. The phase of the obtained particles can also be tuned between pure Ni2P to Ni5P4 and NiP2 by simply decreasing the OAm/TOP ratio and/or changing the nickel precursor (nickel(II)acetylacetonate, nickel(II)acetate tetrahydrate, or bis(cyclooctadiene)nickel(0)). However, at high concentrations of OAm, the product formed is the same regardless of Ni precursor, suggesting the formation of a uniform Ni intermediate (an Ni-oleylamine complex) under these conditions that is responsible for product distribution. Intriguingly, under the extreme phosphidation conditions required to favor Ni5P4 and NiP2 over Ni2P (large excess of TOP), the 20-30 nm crystallites assemble into supraparticles with diameters of 100-500 nm. These factors are discussed in light of a comprehensive

  18. Oxidation of hydrogen peroxide by [Ni (cyclam)] in aqueous acidic ...

    Indian Academy of Sciences (India)

    e-mail: smradha73@gmail.com; viju47@yahoo.co.in. MS received 29 August 2012; revised 9 February 2013; accepted 8 March 2013. Abstract. The kinetics of oxidation of H2O2 by [NiIII(cyclam)]3+, [NiIIIL1], was studied in aqueous acidic media at 25. ◦. C and I = 0.5 M (NaClO4). The [NiIIIL1] to [NiIIL1] reduction was found ...

  19. New route for synthesis of electrocatalytic Ni (OH) 2 modified ...

    Indian Academy of Sciences (India)

    Immobilization of redox species like Ni(OH)2 onto the electrode surface is important in the application areas such as super capacitor, electrochromic displays and electrocatalysis. Nickel hexacyanoferrate (NiHCF) modified glassy carbon could be further derivatized with Ni(OH)2 by electrochemical cycling in alkali.

  20. Phytoremediation technologies for Ni ++ by water hyacinth | Hussain ...

    African Journals Online (AJOL)

    In the second experiment, Ni++ contaminated Hoagland's solution was used for the hydroponic growth of water hyacinth. The result of hydroponic experiment showed the phytoremoval of Ni++ from Ni++ contaminated wastewater; maximum removal was 1.954 μg/g of dry weight. In third experiment, ash of water hyacinth ...

  1. Large scale synthesis and characterization of Ni nanoparticles by ...

    Indian Academy of Sciences (India)

    WINTEC

    energy absorption, fuel cell electrodes, catalysts etc. So the synthesis of Ni nanoparticles has attracted considerable attention. Although many methods are used to prepare Ni particles (Pfeil and Leonard 1987; Degen and Matek. 1999; Zheng et al 2001; Ni et al 2003; Syukri et al 2003;. Hou and Gao 2004; Kumar et al 2004; ...

  2. Fabrication of micro-Ni arrays by electroless and electrochemical ...

    Indian Academy of Sciences (India)

    Administrator

    Abstract. Nickel micro-arrays were fabricated by electroless and electrochemical deposition in an etched porous aluminum membrane. The aluminum membrane with metal characteristic could be fabricated from high-purity aluminium by electrochemical method. The aluminum reduced Ni. 2+ into Ni and the formed Ni.

  3. Morphological and compositional engineering of Ni/carbon ...

    Indian Academy of Sciences (India)

    Ni/multi-walled carbon nanotubes (MWCNTs) composite films were deposited on the glassy carbon electrode (GCE) by a Ni plating bath containing homogeneously dispersed MWCNTs using polyvinylpyrrolidone (PVP) as dispersion additive. Incorporation of MWCNTs into Ni matrix was greatly enhanced by the application ...

  4. Optimization of process parameters for synthesis of silica–Ni ...

    Indian Academy of Sciences (India)

    The optimumcombination of experimental variable, temperature, time of heat treatment under nitrogen atmosphere and amount of Ni-salt was delineated to find out the maximum yield of nanophase Ni in the silica gel matrix. The size of Ni in the silica gel was found to be 34 and 45 nm for the two chosen compositions, ...

  5. Optimization of process parameters for synthesis of silica–Ni ...

    Indian Academy of Sciences (India)

    Abstract. The optimum combination of experimental variable, temperature, time of heat treatment under nitrogen atmosphere and amount of Ni-salt was delineated to find out the maximum yield of nanophase Ni in the silica gel matrix. The size of Ni in the silica gel was found to be 34 and 45 nm for the two chosen ...

  6. Irradiation induced defects in deformed $Ni_{3}Ge$ and $Ni_{3}Al$ single crystals

    CERN Document Server

    Murakumo, T; Miyahara, A; Hannuki, T; Sato, A

    2000-01-01

    The effect of plastic deformation on the formation of point defects and defect clusters by electron irradiation has been studied in Ll /sub 2/ ordered Ni/sub 3/Ge and Ni/sub 3/Al by high voltage electron microscopy. It is found that defects are formed preferentially along the Burgers vector directions as linear lines and grow into linear chains of clusters by electron irradiation. This phenomenon is explained by preferential generation of the defects along the antiphase boundary (APE) tubes, in specimens deformed both below and above the peak temperature T/sub p/. Based on three-dimensional analyses of the defect distribution, the formation mechanism of the APE tubes is discussed with particular reference to superdislocation motion and the strengthening of the Ll/sub 2/ ordered compounds of Ni /sub 3/Ge and Ni/sub 3/Al. (44 refs).

  7. Evolution of collectivity in the 78Ni region: Coulomb excitation of 74Ni at intermediate energies.

    Directory of Open Access Journals (Sweden)

    Marchi T.

    2014-03-01

    Full Text Available The study of the collective properties of nuclear excitations far from stability provides information about the shell structure at extreme conditions. Spectroscopic observables such as the energy or the transition probabilities of the lowest states, in nuclei with large neutron excess, allow to probe the density and isospin dependence of the effective interaction. Indeed, it was recently shown that tensor and three-body forces play an important role in breaking and creating magic numbers. Emblematic is the case of the evolution of the Ni isotopic chain where several features showed up moving from the most neutron rich stable isotope (64Ni towards the 78Ni nucleus where the large neutron excess coincides with a double shell closure. In this framework, we have recently performed an experiment with the goal to extract the B(E2; 0+ → 2+ value for the 74Ni nucleus in an intermediate-energy Coulomb excitation experiment: preliminary results are discussed.

  8. Mechanical properties of NiO/Ni-YSZ composites depending on temperature, porosity and redox cycling

    DEFF Research Database (Denmark)

    Pihlatie, Mikko; Kaiser, Andreas; Mogensen, Mogens Bjerg

    2009-01-01

    %. For all samples a linear relation between Young's modulus and porosity was found. The temperature dependency of the mechanical properties of both as-sintered and reduced composites was investigated by IET up to 1200 degrees C. In the as-sintered state, first an increase and peak of stiffness coinciding......The Impulse Excitation Technique (IET) was used to determine the elastic modulus and specific damping of different Ni/NiO-YSZ composites suitable for use in solid oxide fuel cells (SOFC). The porosity of the as-sintered samples varied from 9 to 38% and that of the reduced ones from 31 to 52...... with the Neel temperature, 250 degrees C, of NiO was observed. Above this temperature, a linear decrease occurred. Specific damping showed a peak at 170-180 degrees C and increased above ca. 1000 degrees C in NiO-YSZ. In the reduced state the elastic modulus decreased linearly with temperature; specific damping...

  9. Synthesis and Magnetic Properties of Ni and Carbon Coated Ni by Levitational Gas Condensation (LGC

    Directory of Open Access Journals (Sweden)

    Young Rang Uhm

    2013-01-01

    Full Text Available The nickel (Ni, and carbon coated nickel (Ni@C nanoparticles were synthesized by levitaional gas condensation (LGC methods using a micron powder feeding (MPF system. Both metal and carbon coated metal nano powders include a magnetic ordered phase. The synthesis by LGC yields spherical particles with a large coercivity. The abnormal initial magnetization curve for Ni indicates a non-collinear magnetic structure between the core and surface layer of the particles. The carbon coated particles had a core structure diameter at and below 10 nm and were covered by 2-3 nm thin carbon layers. The hysteresis loop of the as-prepared Ni@Cs materials with unsaturated magnetization shows a superparamagnetic state at room temperature.

  10. Thermal stability of electrodeposited Ni and Ni-Co layers; an EBSD-study

    DEFF Research Database (Denmark)

    Rasmussen, Anette Alsted; Gholinia, A.; Trimby, P.W.

    2004-01-01

    The influence of heat treatment on the microstructure and the microtexture of electrodeposited Ni and Ni-Co layers was investigated with Electron Backscatter Diffraction (EBSD) with high resolution. Samples were annealed for 1 hour at 523 K and 673 K, the temperature region wherein recrystallisat......The influence of heat treatment on the microstructure and the microtexture of electrodeposited Ni and Ni-Co layers was investigated with Electron Backscatter Diffraction (EBSD) with high resolution. Samples were annealed for 1 hour at 523 K and 673 K, the temperature region wherein...... recrystallisation occurs. The results are discussed in relation to the resolution of EBSD for the very fine grained electrodeposits and previous X-ray diffracton investigations....

  11. Bottom and top AF/FM interfaces of NiFe/FeMn/NiFe trilayers

    Energy Technology Data Exchange (ETDEWEB)

    Nascimento, V.P. [Universidade Federal Rural do Rio de Janeiro, Instituto Multidisciplinar, Rua Professor Paris, s/n Centro, 26221-150 Nova Iguacu, RJ (Brazil)], E-mail: valberto@cbpf.br; Passamani, E.C. [Universidade Federal do Espirito Santo, Depto. Fisica, Avenida Fernando Ferrari, 514 Goiabeiras, 29075-910 Vitoria, ES (Brazil); Alvarenga, A.D. [Instituto Nacional de Metrologia, Normalizacao e Qualidade Industrial, Avenida Nossa Senhora das Gracas, 50 Duque de Caxias, 25250-020 Rio de Janeiro, RJ (Brazil); Biondo, A. [Universidade Federal do Espirito Santo, Depto. Fisica, Avenida Fernando Ferrari, 514 Goiabeiras, 29075-910 Vitoria, ES (Brazil); Pelegrini, F. [Universidade Federal de Goias, Instituto de Fisica, Campus Samambaia, 74001-970 Goiania, GO (Brazil); Saitovitch, E. Baggio [Centro Brasileiro de Pesquisas Fisicas, Rua Dr. Xavier Sigaud, 150 Urca, 22290-180 Rio de Janeiro, RJ (Brazil)

    2008-01-30

    X-ray reflectivity analyses were performed in the Si/WTi (7 nm)/NiFe (30 nm)/FeMn (13 nm)/NiFe (10 nm)/WTi (7 nm) exchange-biased system prepared by magnetron sputtering under three different argon working pressures. Layer-by-layer analyses were realized in order to obtain the interfacial roughness parameters quantitatively. For a fixed argon pressure, the root-mean-square roughness (including the atomic grading) of the upper (FeMn/NiFe) interface are greater than that for the lower one in all studied samples. Argon working pressure also has severe influence over the NiFe/FeMn interfaces, being more pronounced at the upper interfaces.

  12. Ni MINERALIZATION AND PGE CHARACTERIZATION IN THE ...

    African Journals Online (AJOL)

    Mgina

    fractionation, (2) the IPGEs are often associated with chromites as alloys or sulfides in dunites whilst the PPGEs are often ... al. 2001, Maier et al. 2001). Several factors affect the Ni, Cu and PGE grades of the sulfides of the magmatic sulfide deposits, the most important of which include: concentration of these elements in the.

  13. Collision strengths for transitions in Ni XIX

    Indian Academy of Sciences (India)

    atomic data (namely energy levels, radiative rates, collision strengths, excitation rates, etc.) are required in order to estimate the power loss from the walls of the reactors. Furthermore, Ni XIX, a neon-like ion, is also very useful in lasing plas- mas. Similarly many transitions, particularly within the n = 3 configurations, have.

  14. Ni (II) complexes of dithiophosphonic acids

    Indian Academy of Sciences (India)

    Home; Journals; Journal of Chemical Sciences; Volume 126; Issue 4. Ni(II) complexes of dithiophosphonic acids ... Gholivand Ali Asghar Ebrahimi Valmoozi. Volume 126 Issue 4 July 2014 pp 1125-1133 ... The new compounds were additionally tested in view of their anti-bacterial properties. The ligands containing amine ...

  15. CLASSICAL AREAS OF PHENOMENOLOGY: First-principles calculations for the elastic properties of Ni-base model superalloys: Ni/Ni3Al multilayers

    Science.gov (United States)

    Wang, Yun-Jiang; Wang, Chong-Yu

    2009-10-01

    A model system consisting of Ni[001](100)/Ni3Al[001](100) multi-layers are studied using the density functional theory in order to explore the elastic properties of single crystal Ni-based superalloys. Simulation results are consistent with the experimental observation that rafted Ni-base superalloys virtually possess a cubic symmetry. The convergence of the elastic properties with respect to the thickness of the multilayers are tested by a series of multilayers from 2γ'+2γ to 10γ'+10γ atomic layers. The elastic properties are found to vary little with the increase of the multilayer's thickness. A Ni/Ni3Al multilayer with 10γ'+10γ atomic layers (3.54 nm) can be used to simulate the mechanical properties of Ni-base model superalloys. Our calculated elastic constants, bulk modulus, orientation-dependent shear modulus and Young's modulus, as well as the Zener anisotropy factor are all compatible with the measured results of Ni-base model superalloys R1 and the advanced commercial superalloys TMS-26, CMSX-4 at a low temperature. The mechanical properties as a function of the γ' phase volume fraction are calculated by varying the proportion of the γ and γ' phase in the multilayers. Besides, the mechanical properties of two-phase Ni/Ni3Al multilayer can be well predicted by the Voigt-Reuss-Hill rule of mixtures.

  16. Microporous Ni@NiO nanoparticles prepared by chemically dealloying Al{sub 3}Ni{sub 2}@Al nanoparticles as a high microwave absorption material

    Energy Technology Data Exchange (ETDEWEB)

    Pang, Yu; Xie, Xiubo; Li, Da [Key Laboratory of Aerospace Materials and Performance (Ministry of Education), School of Materials Science and Engineering, Beihang University, No.37 Xueyuan Road, Beijing 100191 (China); Chou, Wusheng [School of Mechanical Engineering and Automation, Beihang University, Beijing 100191 (China); Liu, Tong, E-mail: tongliu@buaa.edu.cn [Key Laboratory of Aerospace Materials and Performance (Ministry of Education), School of Materials Science and Engineering, Beihang University, No.37 Xueyuan Road, Beijing 100191 (China)

    2017-03-15

    The Al{sub 3}Ni{sub 2}@Al nanoparticles (NPs) were prepared from Ni{sub 45}Al{sub 55} master alloy by hydrogen plasma-metal reaction method, and were subsequently dealloyed to produce porous Ni@NiO NPs of 36 nm. The pore size ranges from 0.7 to 1.6 nm, leading to large specific surface area of 69.5 m{sup 2}/g and big pore volume of 0.507 cc/g. The saturation magnetization (M{sub S}) and coercivity (H{sub C}) of the microporous Ni@NiO NPs are 11.5 emu/g and 5.2 Oe. They exhibit high microwave absorption performance with a minimum reflection coefficient (RC) of −86.9 dB and an absorption bandwidth of 2.6 GHz (RC≤−10 dB) at thickness of 4.5 mm. The enhanced microwave absorption properties are attributed to the synergistic effect of the magnetic Ni core and dielectric NiO shell, and the micropore architecture. The NPs with micropore morphology and core/shell structure open a new way to modify the microwave absorption performance. - Graphical abstract: The microporous Ni/NiO nanoparticles prepared by chemically dealloying Al{sub 3}Ni{sub 2}@Al NPs exhibit high microwave absorption intensity (−86.9 dB) and wide absorption bandwidth (2.6 GHz for RC≤−10 dB). - Highlights: • Microporous Ni/NiO nanoparticals were prepared by chemically dealloying method. • They possessed micropores of 0.7–1.6 nm with a surface area of 69.5 m{sup 2}/g. • They showed high microwave absorption intensity and wide absorption bandwidth. • Microwave absorption mechanism was explained by micropore and core/shell structures.

  17. Electroplating condition for Ni nanocrystalline on metal (Ni and Cu) plates

    Energy Technology Data Exchange (ETDEWEB)

    Park, Keun Yung; Uhm, Young Rang; Son, Kwang Jae; Shim, Young Ho; Choi, Sun Ju [KAERI, Daejeon (Korea, Republic of)

    2012-10-15

    Ni 63, a beta radiation source, is prepared by the electrical deposition of radioactive Ni 63 ions on a thin non radioactive nickel foil or Cu plate. Given a half life of 100 years, a nuclear battery will still produce half of its initial starting power after 100 years. A speck of a radioisotope like nickel 63, for example, contains enough energy to power a nano nuclear battery for decades, and to do so safely. Ni 63 plating is similar to other electroplating processes that employ soluble metal anodes. It requires the passage of a direct current between two electrodes that are immersed in a conductive, aqueous solution of nickel salts. The charged Ni ions are formed by sulfate, sulfamate, chloride, and a Watts bath. However, the charged Ni 63 ions are formed by dissolving metal Ni 63. To established the coating condition of Ni 63, non radioactive metal Ni particles are dissolved an acid solution and electroplated on a Ni sheet. The nickel plating process is used extensively for decorative, engineering and electro forming purposes because the appearance and other properties of electrodeposited nickel can be varied over a wide range by controlling the composition and operating parameters of the plating solution. A continuous increase in the grain size versus current density has also been recognized in the direct current electrodeposition of nickel coating. On the other hand, A runa et al. reported that the current density has no significant effect on the grain size of nickel electro deposits. A review of the literature shows that saccharin has often been added to a nickel plating bath since the 1980s to improve the ductility and brightness, and in later periods as a grain refiner agent. In the present paper, not only the preparation of a Ni plating solution prepared by dissolving metal particles, but also an optimization of the deposition conditions, such as the current density, saccharin concentration in the bath, and different metal substrates were investigated

  18. Electroplating condition for Ni nanocrystalline on metal (Ni and Cu) plates

    International Nuclear Information System (INIS)

    Park, Keun Yung; Uhm, Young Rang; Son, Kwang Jae; Shim, Young Ho; Choi, Sun Ju

    2012-01-01

    Ni 63, a beta radiation source, is prepared by the electrical deposition of radioactive Ni 63 ions on a thin non radioactive nickel foil or Cu plate. Given a half life of 100 years, a nuclear battery will still produce half of its initial starting power after 100 years. A speck of a radioisotope like nickel 63, for example, contains enough energy to power a nano nuclear battery for decades, and to do so safely. Ni 63 plating is similar to other electroplating processes that employ soluble metal anodes. It requires the passage of a direct current between two electrodes that are immersed in a conductive, aqueous solution of nickel salts. The charged Ni ions are formed by sulfate, sulfamate, chloride, and a Watts bath. However, the charged Ni 63 ions are formed by dissolving metal Ni 63. To established the coating condition of Ni 63, non radioactive metal Ni particles are dissolved an acid solution and electroplated on a Ni sheet. The nickel plating process is used extensively for decorative, engineering and electro forming purposes because the appearance and other properties of electrodeposited nickel can be varied over a wide range by controlling the composition and operating parameters of the plating solution. A continuous increase in the grain size versus current density has also been recognized in the direct current electrodeposition of nickel coating. On the other hand, A runa et al. reported that the current density has no significant effect on the grain size of nickel electro deposits. A review of the literature shows that saccharin has often been added to a nickel plating bath since the 1980s to improve the ductility and brightness, and in later periods as a grain refiner agent. In the present paper, not only the preparation of a Ni plating solution prepared by dissolving metal particles, but also an optimization of the deposition conditions, such as the current density, saccharin concentration in the bath, and different metal substrates were investigated

  19. Effects of Ni concentration on structural, magnetic and optical properties of Ni-doped ZnO nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Yang [Institute of Condensed State Physics, Jilin Normal University, Siping 136000 (China); Institute of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013 (China); Department of Chemistry, Purdue University, West Lafayette 47907 (United States); Liu, Hongbo [Institute of Condensed State Physics, Jilin Normal University, Siping 136000 (China); Institute of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013 (China); Chen, Zhenguo; Kadasala, Naveen; Mao, Chenyi [Department of Chemistry, Purdue University, West Lafayette 47907 (United States); Wang, Yaxin; Zhang, Yongjun; Liu, Huilian; Liu, Yanqing [Institute of Condensed State Physics, Jilin Normal University, Siping 136000 (China); Yang, Jinghai, E-mail: jhyang1@jlnu.edu.cn [Institute of Condensed State Physics, Jilin Normal University, Siping 136000 (China); Yan, Yongsheng [Institute of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013 (China)

    2014-08-01

    Graphical abstract: With increase of Ni concentration, the saturated magnetization increases firstly and then decreases, which results from the competition between oxygen vacancies and antiferromagnetic coupling between Ni{sup 2+} in NiO. - Highlights: • Ni-doped zinc oxide nanoparticles (NPs) were synthesized by sol–gel method. • Ni ions are substitutionally incorporated into the crystal lattice of ZnO. • Saturated solubility of Ni in ZnO is 2%. • Oxygen vacancies are the origin of ferromagnetism in Ni-doped ZnO NPs. - Abstract: Ni-doped zinc oxide (Zn{sub 1−x}Ni{sub x}O, 0 ⩽ x ⩽ 0.08) diluted magnetic semiconductors have been synthesized by the using a sol–gel method. Structural, magnetic and optical properties of the samples have been studied. The results of X-ray diffraction (XRD), transmission electron microscope (TEM) and X-ray absorption fine structure (XAFS) indicated that Ni ions were substitutionally incorporated into the crystal lattice of ZnO. With Ni concentration increasing up to 2 at.%, all diffraction peaks corresponded to wurtzite structure of ZnO, but for Zn{sub 0.97}Ni{sub 0.03}O, secondary phase of NiO emerged. Based on the results of X-ray photoelectron spectroscopy (XPS), Ni incorporated into the ZnO lattice as Ni{sup 2+}. The produced samples showed good high-Tc (Curie temperature) ferromagnetism. The results of vibrating sample magnetometer (VSM) and photoluminescence (PL) showed that ferromagnetism (FM) of the Ni-doped ZnO nanoparticles originated from the presence of the O vacancy.

  20. Superconductivity in Bi/Ni bilayer system: Clear role of superconducting phases found at Bi/Ni interface

    Science.gov (United States)

    Liu, L. Y.; Xing, Y. T.; Merino, I. L. C.; Micklitz, H.; Franceschini, D. F.; Baggio-Saitovitch, E.; Bell, D. C.; Solórzano, I. G.

    2018-01-01

    Bi/Ni bilayers with varying Bi and Ni layer thicknesses have been prepared by (a) pulsed-laser deposition (PLD) at 300 K and (b) thermal evaporation at 4.2 K. A two-step superconducting transition appears on the electrical transport measurements in the samples prepared by PLD. High-resolution transmission and scanning transmission electron microscopy, supported by energy-dispersive x-ray spectroscopy (EDXS) analysis, reveal that two superconducting intermetallic alloys, namely NiBi and NiBi3, are formed by interdiffusion, if the bilayers are prepared at 300 K. The Tc of the two phases behaves very differently in an external magnetic field and the upper critical magnetic fields at zero temperature [Bc 2(0 ) ] were estimated as 1.1 and 7.4 T, respectively. The lower value corresponds to the Bc 2(0) of NiBi3 phase and the higher one is supposed to be of NiBi. These alloys are responsible for the superconductivity and the two-step transition appearing in the Bi/Ni bilayer system. Surprisingly, the Bi-rich phase (NiBi3) is formed near the Ni layer, while the Ni-rich phase (NiBi) is formed far from the Ni layer. The EDXS analysis at nanometer scale clearly shows an unusual increase of Ni concentration near the interface of Bi/substrate. The limited thickness of Bi layer in the interdiffusion process results in an unexpected distribution of Ni concentration. Samples prepared at 4.2 K after annealing at 300 K do not show any superconductivity, which indicates that a nonepitaxial Bi/Ni interface does not induce superconductivity in the case interdiffusion does not occur. These results offer a deeper understanding of the superconductivity in the Bi/Ni bilayer system.

  1. Geometric structures of thin film: Pt on Pd(110) and NiO on Ni(100)

    Energy Technology Data Exchange (ETDEWEB)

    Warren, Oden L. [Iowa State Univ., Ames, IA (United States)

    1993-07-01

    This thesis is divided into 3 papers: dynamical low-energy electron- diffraction investigation of lateral displacements in topmost layer of Pd(110); determination of (1x1) and (1x2) structures of Pt thin films on Pd(110) by dynamical low-energy electron-diffraction analysis; and structural determination of a NiO(111) film on Ni(100) by dynamical low-energy electron-diffraction analysis.

  2. Electrodeposited nanocrystalline Ni-Co and Co-Ni-P coatings for hard chromium replacement

    OpenAIRE

    Ma, Chao

    2013-01-01

    This thesis describes the preparation and characterisation of environmentally friendly and low-cost nanocrystalline Ni-Co coatings and Co-Ni-P coatings to replace hard chromium coatings for anti-wear and anti-corrosion applications. nanocrystalline Ni–Co coatings with different cobalt contents were electrodeposited.The investigation on the role of tribofilms and wear debris in the tribological behavior sliding against AISI-52100 stainless steel under unlubricated conditions shows that the tri...

  3. 3D Computer Models of T- x- y Diagrams, Forming the Fe-Ni-Co-FeS-NiS-CoS Subsystem

    Science.gov (United States)

    Lutsyk, V. I.; Vorob'eva, V. P.

    2017-12-01

    3D computer models of Fe-Ni-Co, Fe-Ni-FeS-NiS, Fe-Co-FeS-CoS, Ni-Co-NiS-CoS T- x- y diagrams have been designed. The geometric structure (35 surfaces, two-phase surface of the reaction type change, 17 phase regions) of the Fe-Ni-FeS-NiS T- x- y diagram is investigated in detail. The liquidus hypersurfaces prediction of the Fe-Ni-Co-FeS-NiS-CoS subsystem is represented.

  4. Weldability of spheroidal graphite ductile cast iron using Ni / Ni-Fe electrodes

    Directory of Open Access Journals (Sweden)

    Pascual, M.

    2009-10-01

    Full Text Available Weldability of spheroidal graphite ductile cast iron was established using a cheap Ni-Fe and a high purity Ni electrode. A preheating treatment at 350 °C and an annealing treatment at 850 °C were carried out to improve mechanical properties of welded pieces. The pure Ni electrode showed graphite diffusion in the bead with a uniform distribution of phases, improving weldability and decreasing fragility. Preheating and annealing treatments increased ductility and improved weldability.

    Se establece la soldabilidad de funciones dúctiles de grafito según las características mecánicas alcanzadas, utilizando un electrodo puro de Ni mientras se compara con uno más económico de Ni-Fe. Diferentes tratamientos t��rmicos son propuestos y analizados. El electrodo de Ni puro mostró difusión de grafito desde el material original al cordón de soldadura, dando como resultado una fase homogénea que mejoró la soldabilidad y redujo la fragilidad. Un pre tratamiento a 350 °C y un recocido a 850 °C incrementaron la ductilidad y mejoró la soldabilidad.

  5. Effect of Ni4Ti3 precipitation on martensitic transformation in Ti-Ni

    International Nuclear Information System (INIS)

    Zhou, N.; Shen, C.; Wagner, M.F.-X.; Eggeler, G.; Mills, M.J.; Wang, Y.

    2010-01-01

    Precipitation of Ni 4 Ti 3 plays a critical role in determining the martensitic transformation path and temperature in Ni-Ti shape memory alloys. In this study, the equilibrium shape of a coherent Ni 4 Ti 3 precipitate and the concentration and stress fields around it are determined quantitatively using the phase field method. Most recent experimental data on lattice parameters, elastic constants, precipitate-matrix orientation relationship and thermodynamic database are used as model inputs. The effects of the concentration and stress fields on subsequent martensitic transformations are analyzed through interaction energy between a nucleating martensitic particle and the existing microstructure. Results indicate that R-phase formation prior to B19' phase could be attributed to both direct elastic interaction and stress-induced spatial variation in concentration near Ni 4 Ti 3 precipitates. The preferred nucleation sites for the R-phase are close to the broad side of the lenticular-shaped Ni 4 Ti 3 precipitates, where tension normal to the habit plane is highest, and Ni concentration is lowest.

  6. Phase transformation and deformation behavior of NiTi-Nb eutectic joined NiTi wires.

    Science.gov (United States)

    Wang, Liqiang; Wang, Cong; Zhang, Lai-Chang; Chen, Liangyu; Lu, Weijie; Zhang, Di

    2016-04-06

    NiTi wires were brazed together via eutectic reaction between NiTi and Nb powder deposited at the wire contact region. Phase transformation and deformation behavior of the NiTi-Nb eutectic microstructure were investigated using transmission electron microscopy (TEM) and cyclic loading-unloading tests. Results show that R phase and B19' martensite transformation are induced by plastic deformation. R phase transformation, which significantly contributes to superelasticity, preferentially occurs at the interfaces between NiTi and eutectic region. Round-shaped Nb-rich phase with rod-like and lamellar-type eutectics are observed in eutectic regions. These phases appear to affect the deformation behavior of the brazed NiTi-Nb region via five distinct stages in stress-strain curves: (I) R phase reorientation, (II) R phase transformation from parent phase, (III) elastic deformation of reoriented martensite accompanied by the plastic deformation of Nb-rich phase and lamellar NiTi-Nb eutectic, (IV) B19' martensitic transformation, and (V) plastic deformation of the specimen.

  7. Fabrication of metallic alloy powder (Ni{sub 3}Fe) from Fe–77Ni scrap

    Energy Technology Data Exchange (ETDEWEB)

    Seo, Inseok [ES Materials Research Center, Research Institute of Industrial Science and Technology, Incheon 406-840 (Korea, Republic of); Shin, Shun-Myung [Extractive Metallurgy Department, Korea Institute of Geoscience and Mineral Resources, Deajeon 305-350 (Korea, Republic of); Ha, Sang-An [Department of Environmental Engineering, Silla University, Busan 46958 (Korea, Republic of); Wang, Jei-Pil, E-mail: jpwang@pknu.ac.kr [Department of Metallurgical Engineering, Pukyong National University, Busan 608-739 (Korea, Republic of)

    2016-06-15

    The oxidation behavior of Fe–77Ni alloy scrap was investigated at an oxygen partial pressure of 0.2 atm and temperatures ranging from 400 °C to 900 °C. The corresponding oxidation rate increased with increasing temperature and obeyed the parabolic rate law, as evidenced by its linear proportionality to the temperature. In addition, surface morphologies, cross-sectional views, compositions, structural properties were examined by scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and X-ray diffraction (XRD). Diffusion through either the spinel structure or the NiO layer, which were both present in the alloy during oxidation at elevated temperatures, was deemed the rate-limiting step of the reaction. The oxide powder less than 10 μm was obtained from Fe–77Ni alloy scrap was obtained using ball-milling and sieving processes. In fact, 15 h of milling yielded a recovery ratio of 97%. Using hydrogen gas, the oxide powder was successfully reduced to an alloy powder of Ni{sub 3}Fe and reduction rates of ∼97% were achieved after 3 h at 1000 °C. - Highlights: • The oxidation behavior of Fe–77Ni alloy scrap was investigated. • The oxide powder less than 10 μm was obtained from Fe–77Ni alloy scrap. • Using hydrogen gas, the oxide powder was successfully reclaimed. • Reduction rates of ∼97% were achieved after 3 h at 1000 °C.

  8. Epitaxial NiWO4 films on Ni(110): Experimental and theoretical study of surface stability

    Science.gov (United States)

    Doudin, N.; Pomp, S.; Blatnik, M.; Resel, R.; Vorokhta, M.; Goniakowski, J.; Noguera, C.; Netzer, F. P.; Surnev, S.

    2017-05-01

    Despite the application potential of nickel tungstate (NiWO4) in heterogeneous catalysis, humidity and gas sensing, etc, its surfaces have essentially remained unexplored. In this work, NiWO4 nanoparticles and films with the wolframite structure have been grown via a solid-state reaction of (WO3)3 clusters and a NiO(100) film on a Ni(110) crystal surface and characterized by a variety of experimental techniques, including x-ray photoelectron spectroscopy (XPS), scanning tunneling microscopy (STM) and x-ray diffraction (XRD), combined with ab-initio density functional theory (DFT) calculations. NiWO4 grows initially as three-dimensional (3D) crystalline nanoparticles displaying mainly two crystalline facets vicinal to the (100) surface, which merge with increasing the (WO3)3 coverage into a quasi-continuous epitaxial film. The DFT results provide an account of the energetics of NiWO4 low index surfaces and highlight the role of faceting in the stabilization of extended polar (100) terraces. These combined experimental and theoretical results show that interaction with a metal substrate and vertical confinement may stabilize oxide nano-objects with high energy facets, able to enhance their reactivity.

  9. Studies on the valence electronic structure of Fe and Ni in FexNi1−x ...

    Indian Academy of Sciences (India)

    sults of MCDF calculations performed for various valence electronic configurations [2] of. Fe and Ni. The 3d electron populations, thus obtained, for pure Fe and Ni metals (table 2) are found to be in close agreement with the results of band structure calculations of Papa- constantopoulos [9] (6.93 for Fe and 8.97 for Ni) and ...

  10. Synthesis and catalytic activity of electrospun NiO/NiCo2O4 nanotubes for CO and acetaldehyde oxidation

    Science.gov (United States)

    Kim, Il Hee; Lee, Hyerim; Yu, Areum; Jeong, Jae Hwan; Lee, Youngmi; Kim, Myung Hwa; Lee, Chongmok; Dok Kim, Young

    2018-04-01

    NiO/NiCo2O4 nanotubes with a diameter of approximately 100 nm are synthesized using Ni and Co precursors via electro-spinning and subsequent calcination processes. The tubular structure is confirmed via transmission electron microscopy imaging, whereas the structures and elemental compositions of the nanotubes are determined using x-ray diffraction, energy dispersive x-ray spectroscopy, and x-ray photoelectron spectroscopy. N2 adsorption isotherm data reveal that the surface of the nanotubes consists of micropores, thereby resulting in a significantly higher surface area (˜20 m2 g-1) than expected for a flat-surface structure (present a study of the catalytic activity of our novel NiO/NiCo2O4 nanotubes for CO and acetaldehyde oxidation. The catalytic activity of NiO/NiCo2O4 is superior to Pt below 100 °C for CO oxidation. For acetaldehyde oxidation, the total oxidation activity of NiO/NiCo2O4 for acetaldehyde is comparable with that of Pt. Coexistence of many under-coordinated Co and Ni active sites in our structure is suggested be related to the high catalytic activity. It is suggested that our novel NiO/NiCo2O4 tubular structures with surface microporosity can be of interest for a variety of applications, including the catalytic oxidation of harmful gases.

  11. Interfacial reaction of Ni{sub 3}Sn{sub 4} intermetallic compound in Ni/SnAg solder/Ni system under thermomigration

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Yi-Shan; Yang, Chia-Jung; Ouyang, Fan-Yi, E-mail: fyouyang@ess.nthu.edu.tw

    2016-07-25

    The growth of Ni{sub 3}Sn{sub 4} intermetallic compound (IMC) between liquid–solid interface in micro-scale Ni/SnAg/Ni system was investigated under a temperature gradient of 160 °C/cm at 260 °C on a hot plate. In contrast to a symmetrical growth of Ni{sub 3}Sn{sub 4} on both interfaces under isothermally annealed at 260 °C, the interfacial Ni{sub 3}Sn{sub 4} IMC exhibited asymmetric growth under a temperature gradient; the growth of Ni{sub 3}Sn{sub 4} at cold interface was faster than that at hot side because of temperature gradient induced mass migration of Ni atoms from the hot end toward the cold end. It was found that two-stage growth behavior of Ni{sub 3}Sn{sub 4} IMC under a temperature gradient. A growth model was established and growth kinetic analysis suggested that the chemical potential gradient controlled the growth of Ni{sub 3}Sn{sub 4} at stage I (0–120 min) whereas the dynamic equilibrium between chemical potential gradient and temperature gradient forces was attained at the hot end at stage II (120–210 min). When dynamic equilibrium was achieved at 260 °C, the critical length-temperature gradient product at the hot end was experimentally estimated to be 489.18 μm × °C/cm and the moving velocity of Ni{sub 3}Sn{sub 4} interface due to Ni consumption was calculated to be 0.134 μm/h. The molar heat of transport (Q*) of Ni atoms in molten SnAg solder was calculated to be +0.76 kJ/mol. - Highlights: • Interfacial reaction in Ni/SnAg solder/Ni system under thermal gradient. • Growth rate of Ni{sub 3}Sn{sub 4} at cold end is faster than that at hot end. • Critical length-temperature gradient product at hot end is 489.2 μm°C/cm at 260 °C. • Velocity of Ni{sub 3}Sn{sub 4} moving interface is 0.134 μm/h during dynamic equilibrium. • Molar heat of transport (Q*) of Ni in molten SnAg was +0.76 kJ/mol.

  12. Thin NiTi Films Deposited on Graphene Substrates

    Science.gov (United States)

    Hahn, S.; Schulze, A.; Böhme, M.; Hahn, T.; Wagner, M. F.-X.

    2017-03-01

    We present experimental results on the deposition of Nickel Titanium (NiTi) films on graphene substrates using a PVD magnetron sputter process. Characterization of the 2-4 micron thick NiTi films by electron microscopy, electron backscatter diffraction, and transmission electron microscopy shows that grain size and orientation of the thin NiTi films strongly depend on the type of combination of graphene and copper layers below. Our experimental findings are supported by density functional theory calculations: a theoretical estimation of the binding energies of different NiTi-graphene interfaces is in line with the experimentally determined microstructural features of the functional NiTi top layer.

  13. Evaluation of the Antitumor Activity by Ni Nanoparticles with Verbascoside

    Directory of Open Access Journals (Sweden)

    Mingyue Chen

    2013-01-01

    Full Text Available Verbascoside (VB has attracted a great deal of attention due to ITS pharmacological properties. In our study, we synthesized a multifunctional verbascoside coated Ni nanoparticles (VB-Ni. Transmission electron microscopy (TEM and high performance liquid chromatography (HPLC display the characteristics of VB-Ni nanoparticles. Compared with VB, VB-Ni has been proven to induce apoptosis and resist the growth of doxorubicin-resistant K562 cells in vitro and in vivo. Thus, VB-Ni nanoparticles can be thought of as an ideal mode of cancer treatment.

  14. Atomistic modeling of ternary additions to NiTi and quaternary additions to Ni-Ti-Pd, Ni-Ti-Pt and Ni-Ti-Hf shape memory alloys

    Energy Technology Data Exchange (ETDEWEB)

    Mosca, H.O., E-mail: hmosca@cnea.gov.ar [Gcia. Investigacion y Aplicaciones, CNEA, Av. Gral Paz 1499, B1650KNA San Martin (Argentina); GCMM, UTN, FRG Pacheco, Av. H. Yrigoyen 288, Gral. Pacheco (Argentina); Bozzolo, G. [Loyola University Maryland, 4501 N. Charles St., Baltimore, MD 21210 (United States); Grosso, M.F. del [Gcia. Investigacion y Aplicaciones, CNEA, Av. Gral Paz 1499, B1650KNA San Martin (Argentina); GCMM, UTN, FRG Pacheco, Av. H. Yrigoyen 288, Gral. Pacheco (Argentina); Consejo Nacional de Investigaciones Cientificas y Tecnicas, CONICET (Argentina)

    2012-08-15

    The behavior of ternary and quaternary additions to NiTi shape memory alloys is investigated using a quantum approximate method for the energetics. Ternary additions X to NiTi and quaternary additions to Ni-Ti-Pd, Ni-Ti-Pt, and Ni-Ti-Hf alloys, for X=Au, Pt, Ir, Os, Re, W, Ta,Ag, Pd, Rh, Ru, Tc, Mo, Nb, Zr, Zn, Cu, Co, Fe, Mn, V, Sc, Si, Al and Mg are considered. Bulk properties such as lattice parameter, energy of formation, and bulk modulus of the B2 alloys are studied for variations due to the presence of one or two simultaneous additives.

  15. Kinetic study of hydrogen evolution reaction on Ni30 Mo70, Co30Mo70, Co30Ni70 and Co10Ni20Mo70 alloy electrodes

    International Nuclear Information System (INIS)

    Dominguez-Crespo, M.A.; Plata-Torres, M.; Torres-Huerta, A.M.; Arce-Estrada, E.M.; Hallen-Lopez, J.M.

    2005-01-01

    The hydrogen evolution reaction on nanocrystalline Ni 30 Mo 70 , Co 30 Mo 70 , Co 30 Ni 70 , and Co 10 Ni 20 Mo 70 , metallic powders prepared by mechanical alloying was investigated with linear polarization and ac impedance methods, in 30 wt.% KOH aqueous solution at room temperature. The formation process and structural properties of these nanocrystalline materials were characterized by X-ray diffraction and transmission electron microscopy. Alloyed powders showed the presence of two phases: an fcc solid solution and intermetallic compounds of Ni, Co and Mo. Based on polarization and ac impedance measurements, an improved electrocatalytic activity for hydrogen evolution reaction was observed in mechanically alloyed Co 30 Ni 70 powders, which is slightly higher than milled metallic Ni powders

  16. Structural evaluation and nonlinear optical properties of Ni/NiO, Ni/NiCo{sub 2}O{sub 4} and Co/Co{sub 3}O{sub 4} nanocomposites

    Energy Technology Data Exchange (ETDEWEB)

    Rahulan, K. Mani, E-mail: krahul.au@gmail.com [Department of Chemistry, SRM Valliammai Engineering College, Chennai 603203 (India); Padmanathan, N. [Department of Physics, Anna University, Guindy, Chennai 600025 (India); Philip, Reji [Light and Matter Physics Group, Raman Research Institute, Bangalore 560080 (India); Balamurugan, S. [Liquid Crystal Research Laboratory, School of Chemical Sciences, Universiti Sains Malaysia, 11800 Minden, Penang (Malaysia); Kanakam, Charles C., E-mail: charlesckin@yahoo.com [Department of Chemistry, SRM Valliammai Engineering College, Chennai 603203 (India)

    2013-10-01

    Nanocomposites of Ni/NiO, Ni/NiCo{sub 2}O{sub 4} and Co/Co{sub 3}O{sub 4} have been synthesized by a chemical reduction technique. X-ray diffraction (XRD) and transmission electron microscopy (TEM) images confirm the mixed composite nature of the sample and uniform particle size of approximately 13 nm. Formation of Ni/NiCo{sub 3}O{sub 4} solid solution or NiCo{sub 2}O{sub 4} spinel phase in the mixed composite is confirmed by energy dispersive X-ray (EDX) spectrum. Magnetic hysteresis (M–H) curves of the nanocomposites show excellent ferromagnetic (FM) nature at room temperature. Nonlinear optical transmission of the nanocomposites is measured using the open aperture Z-scan technique employing 7 nanosecond laser pulses at 532 nm. Experimental results show that NiO/NiO–Co{sub 3}O{sub 4}/Co{sub 3}O{sub 4} nanocomposites exhibit good optical limiting performance. From the measurements and numerical fitting of the data to theory, it is found that nonlinear absorption has contributions from excited state absorption and two-photon absorption. Optical limiting is enhanced in Co{sub 3}O{sub 4} and Ni/NiCo{sub 2}O{sub 4} in which the Co{sub 3}O{sub 4} content has a larger volume ratio.

  17. CO2 activation on bimetallic CuNi nanoparticles

    Directory of Open Access Journals (Sweden)

    Natalie Austin

    2016-10-01

    Full Text Available Density functional theory calculations have been performed to investigate the structural, electronic, and CO2 adsorption properties of 55-atom bimetallic CuNi nanoparticles (NPs in core-shell and decorated architectures, as well as of their monometallic counterparts. Our results revealed that with respect to the monometallic Cu55 and Ni55 parents, the formation of decorated Cu12Ni43 and core-shell Cu42Ni13 are energetically favorable. We found that CO2 chemisorbs on monometallic Ni55, core-shell Cu13Ni42, and decorated Cu12Ni43 and Cu43Ni12, whereas, it physisorbs on monometallic Cu55 and core-shell Cu42Ni13. The presence of surface Ni on the NPs is key in strongly adsorbing and activating the CO2 molecule (linear to bent transition and elongation of C˭O bonds. This activation occurs through a charge transfer from the NPs to the CO2 molecule, where the local metal d-orbital density localization on surface Ni plays a pivotal role. This work identifies insightful structure-property relationships for CO2 activation and highlights the importance of keeping a balance between NP stability and CO2 adsorption behavior in designing catalytic bimetallic NPs that activate CO2.

  18. Changing effect of El Niño on Antarctic iceberg distribution: From canonical El Niño to El Niño Modoki

    Science.gov (United States)

    Romanov, Yury A.; Romanova, Nina A.; Romanov, Peter

    2014-01-01

    Earlier studies indicate that during El Niño events the iceberg concentration increases in the east of the Pacific sector and in the west of the Atlantic sector of Southern Ocean, but decreases in the center of the Pacific sector. During La Niña the pattern of the iceberg concentration anomalies in these regions reverses. This iceberg redistribution is explained by anomalous winds and currents around an extensive positive atmospheric pressure anomaly that typically develops in the South-East Pacific during the warm El Niño-Southern Oscillation (ENSO) phase. In this study, the results of iceberg observations during two cruises of the r/v "Akademik Fedorov" in Antarctica in January-February 2008 (La Niña) and 2010 (El Niño) have been used to examine the consistency of changes in the iceberg distribution in the Southern Ocean related to El Niño events. The analysis of these observations has shown that in the Pacific Sector of Antarctica changes in the iceberg distribution between 2008 and 2010 followed the scenario outlined above and thus could be associated with the ENSO phase change. Contrary to earlier observations, the iceberg concentration in the Atlantic sector of Antarctica did not increase during 2010 El Niño. The latter is explained by a noncanonical type of 2010 El Niño, El Niño Modoki, and associated atmospheric circulation pattern different from the canonical El Niño. Further analysis has shown that a more frequent occurrence of El Niño Modoki in recent years have resulted in weaker links between El Niño events and the Antarctic iceberg distribution.

  19. NiCo2S4nanosheet-decorated 3D, porous Ni film@Ni wire electrode materials for all solid-state asymmetric supercapacitor applications.

    Science.gov (United States)

    Saravanakumar, Balasubramaniam; Jayaseelan, Santhana Sivabalan; Seo, Min-Kang; Kim, Hak-Yong; Kim, Byoung-Suhk

    2017-12-07

    Wire type supercapacitors with high energy and power densities have generated considerable interest in wearable applications. Herein, we report a novel NiCo 2 S 4 -decorated 3D, porous Ni film@Ni wire electrode for high performance supercapacitor application. In this work, a facile method is introduced to fabricate a 3D, porous Ni film deposited on a Ni wire as a flexible electrode, followed by decoration with NiCo 2 S 4 as an electroactive material. The fabricated NiCo 2 S 4 -decorated 3D, porous Ni film@Ni wire electrode displays a superior performance with an areal and volumetric capacitance of 1.228 F cm -2 and 199.74 F cm -3 , respectively, at a current density of 0.2 mA cm -1 with a maximum volumetric energy and power density (E V : 6.935 mW h cm -3 ; P V : 1.019 W cm -3 ). Finally, the solid state asymmetric wire type supercapacitor is fabricated using the fabricated NiCo 2 S 4 -decorated 3D, porous Ni film@Ni wire as a positive electrode and N-doped reduced graphene oxide (N-rGO) as a negative electrode and this exhibits good areal and volumetric capacitances of C A : 0.12 F cm -2 and C V : 19.57 F cm -2 with a higher rate capability (92%). This asymmetric wire type supercapacitor demonstrates a low leakage current and self-discharge with a maximum volumetric energy (E V : 5.33 mW h cm -3 ) and power (P V : 855.69 mW cm -3 ) density.

  20. Structural and magnetic properties of Ni-Zn and Ni-Zn-Co ferrites

    Energy Technology Data Exchange (ETDEWEB)

    Knyazev, A.V., E-mail: knyazevav@gmail.com [N.I. Lobachevsky State University of Nizhni Novgorod, Gagarin Prospekt 23/2, 603950 Nizhni Novgorod (Russian Federation); Zakharchuk, I.; Lähderanta, E. [Lappeenranta University of Technology, P.O. Box 20, FI-53851 Lappeenranta (Finland); Baidakov, K.V.; Knyazeva, S.S. [N.I. Lobachevsky State University of Nizhni Novgorod, Gagarin Prospekt 23/2, 603950 Nizhni Novgorod (Russian Federation); Ladenkov, I.V. [Joint-stock Company “Research and Production Company “Salut”, Nizhni Novgorod (Russian Federation)

    2017-08-01

    Highlights: • Ni-Zn and Ni-Zn-Co ferrite powders were prepared by the solid-state reaction at 1073 K. • The room temperature saturation magnetizations are 59.7 emu/g for Ni{sub 0.5}Zn{sub 0.5}Fe{sub 2}O{sub 4} and 57.1 emu/g for Ni{sub 0.5}Zn{sub 0.3}Co{sub 0.2}Fe{sub 2}O{sub 4}. • The coercivity of the samples is found to be much larger than that of bulk ferrites and increases with Co introduction. • The temperature dependences of magnetization exhibit large spin frustration and spin-glass-like behavior. - Abstract: Ni-Zn and Ni-Zn-Co ferrite powders with nominal compositions Ni{sub 0.5}Zn{sub 0.5}Fe{sub 2}O{sub 4} and Ni{sub 0.5}Zn{sub 0.3}Co{sub 0.2}Fe{sub 2}O{sub 4} were prepared by the solid-state reaction synthesis with periodic regrinding during the calcination at 1073 K. The structure of Ni{sub 0.5}Zn{sub 0.5}Fe{sub 2}O{sub 4} and Ni{sub 0.5}Zn{sub 0.3}Co{sub 0.2}Fe{sub 2}O{sub 4} was refined assuming space group F d-3m. Scanning electron microscopy revealed the average sizes of the crystalline ferrite particles are 130–630 nm for Ni{sub 0.5}Zn{sub 0.5}Fe{sub 2}O{sub 4} and 140–350 nm for Ni{sub 0.5}Zn{sub 0.3}Co{sub 0.2}Fe{sub 2}O{sub 4}. The room temperature saturation magnetizations are 59.7 emu/g for Ni{sub 0.5}Zn{sub 0.5}Fe{sub 2}O{sub 4} and 57.1 emu/g for Ni{sub 0.5}Zn{sub 0.3}Co{sub 0.2}Fe{sub 2}O{sub 4}. The coercivity of the samples is found to be much larger than that of bulk ferrites and increases with Co introduction. The Curie temperature tends to increase upon Zn substitution by Co, as well. The temperature dependences of magnetization measured using zero-field cooled and field cooled protocols exhibit large spin frustration and spin-glass-like behavior.

  1. Effects of Bond Coating on NiCrBSi-Mo Composite Functional Coating Properties in Plasma Spraying NiCrBSi-Mo/Ni Coating

    OpenAIRE

    DU Ji-yu; LI Fang-yi; LU Hai-yang; SHANG Jian-tong; LI Zhen

    2017-01-01

    Nickel-based bond coating and composite functional coating were sprayed on leaf blade steel material FV520B successively by using air plasma spraying system. NiCrBSi-Mo powder deposition rate, coating porosity, bonding strength and surface hardness were tested. The results indicate that, for the NiCrBSi-Mo/Ni coating, bond coating with 180-220μm thickness can improve NiCrBSi-Mo powder deposition rate while the surface coating with lower porosity, higher bonding strength and high hardness is p...

  2. Thermodynamic characterization of Ni3TeO6, Ni2Te3O8 and NiTe2O5

    Science.gov (United States)

    Dawar, Rimpi; Babu, R.; Ananthasivan, K.; Anthonysamy, S.

    2017-09-01

    Measurement of vapour pressure of TeO2(g) over the biphasic mixture Ni3TeO6 (s) + NiO(s) in the temperature range 1143-1272 K was carried out using transpiration-thermogravimetric technique (TTG). Gibbs energy of formation of Ni3TeO6 was obtained from the temperature dependence of vapour pressure of TeO2 (g) generated by the incongruent vapourisation reaction, Ni3TeO6 (s) → NiO(s) + TeO2 (g) + 1/2 O2 in the temperature range 1143-1272 K. An isoperibol type drop calorimeter was used to measure the enthalpy increments of Ni3TeO6, Ni2Te3O8 and NiTe2O5. Thermodynamic functions viz., heat capacity, entropy and Gibbs energy functions of these compounds were derived from the experimentally measured enthalpy increment values. Third-law analysis was carried out to ascertain absence of temperature dependent systematic errors in the measurement of vapour pressure of TeO2 (g). A value of -1265.1 ± 1.5 kJ mol-1 was obtained for Δ Hf,298K o (Ni3TeO6) using third-law analysis.

  3. Estilos de vida saludables de niños, niñas y adolescentes

    Directory of Open Access Journals (Sweden)

    Lilia Campo-Ternera

    2017-01-01

    Full Text Available Objetivo: Describir los estilos de vida saludables de niños, niñas y adolescentes de Barranquilla. Materiales y métodos: Estudio descriptivo de corte transversal en 991 niños, niñas y ado - lescentes. Se evaluó la actividad física mediante los cuestionarios de Actividad Física para Adolescentes y para niños escolares; se aplicó una encuesta que midió los conocimientos y prácticas de los escolares sobre salud bucal, lavado de manos, consumo de frutas y verduras y cuidado postural; la Lista de Chequeo “Mi Vida en la Escuela”, la cual evalúa los índices de “bullying” y agresión; y la inteligencia emocional a través dela escala TMMS -24. Resultados: El 65,4 % se categoriza como inactivos físicamente. Solo el 14,7% de los estudiantes reconoce que el peso máximo del bolso es el 10 % de su peso corporal; el 34,1 % cambia el cepillo de dientes cada 3 meses, como lo recomiendan los expertos, y 48,4 % se cepilla los dientes entre 2 y 3 veces al día. El 16,6 % no se lava las manos antes y después de ir al baño y 9,4 % no lo hace antes y después de las comidas; el 17,5 % no tiene un buen consumo de verduras y frutas; y se encontró un Índice de “bullying” en el 55,6 % de los participantes. Conclusión: Los anteriores resultados obligan a plantear intervenciones que incrementen las prácticas saludables en niños, niñas y adolescentes.

  4. Evaluation of structure and mechanical properties of Ni-rich NiTi/Kapton composite film

    Energy Technology Data Exchange (ETDEWEB)

    Mohri, Maryam [Institute of Nanotechnology (INT), Karlsruhe Institute of Technology (KIT), Karlsruhe (Germany); School of Metallurgy and Materials Engineering, College of Engineering, University of Tehran, Tehran (Iran, Islamic Republic of); Nili-Ahmadabadi, Mahmoud [School of Metallurgy and Materials Engineering, College of Engineering, University of Tehran, Tehran (Iran, Islamic Republic of); PouryazdanPanah, Mohsen; Hahn, Horst [Institute of Nanotechnology (INT), Karlsruhe Institute of Technology (KIT), Karlsruhe (Germany); Joint Research Labaratory Nanomaterials, Technische Universität Darmstadt, Darmstadt (Germany)

    2016-06-21

    NiTi thin films are usually sputtered on silicon wafers by magnetron sputtering. But the systems composed of thin film on flexible polymeric substrate are used in many applications such as micro electro-mechanical systems (MEMS). Investigation on mechanical properties of thin films has attracted much attention due to their widespread applications. In this paper, the mechanical properties of 1 µm-thick crystallized Ni-49.2 at%Ti thin film alloy deposited by DC magnetron sputtering on Kapton substrate are investigated by using tensile test. The as-deposited thin films are in amorphous state, then for crystallization, the thin film was annealed at 450 °C for 30 min. Formation of the austenite phase after annealing was confirmed by X-ray diffractometry (XRD) and differential scanning calorimetry (DSC). The surface morphology of as deposited and crystallized thin films were examined by scanning electron microscopy (SEM). Stress-strain curves of the NiTi alloy thin film were obtained by subtracting of the stress-strain Kapton curves from the corresponding curves of the NiTi/Kapton composite. The XRD results revealed that the NiTi thin film deposited on the Kapton is austenitic and presents super-elastic effect at room temperature. This pseudo elastic effect leads to more recoverable strain in NiTi/Kapton composite film compared with Kapton foils on loading/unloading test. Furthermore, it was concluded that nanostructure of the NiTi thin film is responsible for remarkable improvement of ultimate tensile strength (1.4 GPa) at a strain of 30% compared with the bulk material.

  5. High Damping of Lightweight TiNi-Ti2Ni Shape Memory Composites for Wide Temperature Range Usage

    Science.gov (United States)

    Yang, Bing; Luo, Zheng; Yuan, Bin; Liu, Jiangwen; Gao, Yan

    2017-10-01

    A bimodal porous TiNi-Ti2Ni shape memory alloy composite (SMAC) with 59% porosity was fabricated by sintering Ti-46at.%Ni elemental powders with pore-forming agent. The porous TiNi-Ti2Ni SMAC contains two irregular pores of about 400 and 120 μm. We investigated the microstructure and pore morphology correlated with the mechanical properties and damping capacities of the SMAC. Ti2Ni intermetallic phases with size of 1-3 μm were homogeneously distributed in the TiNi matrix. The porous TiNi-Ti2Ni SMAC exhibits exceptionally high inverse mechanical quality factor ( Q -1) of 0.25 at SMAC at relatively low strain amplitude can exhibit considerable high Q -1 of 0.06 0.11 for a wide range of temperature between - 90 and 200 °C, which is attributed to the stress concentration distribution provided by the bimodal structure of pores and the massive interfaces between pore/matrix and TiNi/Ti2Ni. These porous SMACs can be an ideal candidate for using as a lightweight damping material in the energy-saving applications.

  6. Preparation of Ni-YSZ Cermet through Reduction of NiO-YSZ Ceramic for SOFC Anode

    Science.gov (United States)

    Baity, P. S. N.; Budiana, B.; Suasmoro, S.

    2017-07-01

    Research on the synthesis of Nickel-Yttria Stabilized Zirconia (Ni-YSZ) cermet for Solid Oxide Fuel Cell (SOFC) anode has been performed. The preparation was carried out through the reduction process of the Nickel Oxide-Yttria stabilized Zirconia (NiO-YSZ) ceramic. NiO and YSZ were prepared separately, the NiO powder was prepared by calcination of CH4Ni3O7.xH2O at 500°C for 3 hours, while YSZ powder was prepared by calcination of 7mol% Y2O3 and 93mol% ZrO2 mixture at 1350°C for an hour. The NiO-YSZ ceramic preparation was carried outby mixing of YSZ and NiO powder with natural white starch by weight ratio NiO: YSZ: natural white starch = 4:6:1 followed by sintering at 1200°C for 4 hours. The completion of reduction process of NiO-YSZ ceramic was performed at 1000°C in flowing Argon (Ar) containing 10% Hydrogen (H2) up to 4 hours. The characterisations include thermogravimetric analysis (TGA), XRD, SEM-EDX and Impedance Analyzer meter. The synthesised Ni-YSZ cermet at composition 33wt% Ni and 67wt% YSZ, shows relative density 70% and electrical conductivity 10-2 S/cm at 700°C, it qualifies as anode for SOFC.

  7. Role of Ni-tolerant Bacillus spp. and Althea rosea L. in the phytoremediation of Ni-contaminated soils.

    Science.gov (United States)

    Khan, Waheed Ullah; Yasin, Nasim Ahmad; Ahmad, Sajid Rashid; Ali, Aamir; Ahmed, Shakil; Ahmad, Aqeel

    2017-05-04

    In our current study, four nickel-tolerant (Ni-tolerant) bacterial species viz, Bacillus thuringiensis 002, Bacillus fortis 162, Bacillus subtilis 174, and Bacillus farraginis 354, were screened using Ni-contaminated media. The screened microbes exhibited positive results for synthesis of indole acetic acid (IAA), siderophore production, and phosphate solubilization. The effects of these screened microbes on Ni mobility in the soil, root elongation, plant biomass, and Ni uptake in Althea rosea plants grown in Ni-contaminated soil (200 mg Ni kg -1 ) were evaluated. Significantly higher value for water-extractable Ni (38 mg kg -1 ) was observed in case of Ni-amended soils inoculated with B. subtilis 174. Similarly, B. thuringiensis 002, B. fortis 162, and B. subtilis 174 significantly enhanced growth and Ni uptake in A. rosea. The Ni uptake in the shoots and roots of B. subtilis 174-inoculated plants enhanced up to 1.7 and 1.6-fold, respectively, as compared to that in the un-inoculated control. Bacterial inoculation also significantly improved the root and shoot biomass of treated plants. The current study presents a novel approach for bacteria-assisted phytoremediation of Ni-contaminated areas.

  8. Microwave assisted synthesis and characterization of Ni/NiO nanoparticles as electrocatalyst for methanol oxidation in alkaline solution

    Science.gov (United States)

    Arunachalam, Prabhakarn; Ghanem, Mohamed A.; Al-Mayouf, Abdullah M.; Al-shalwi, Matar; Hamed Abd-Elkader, Omar

    2017-02-01

    Nickel/Nickel oxide (Ni/NiO) nanoparticles catalyst is prepared by microwave-assisted liquid-phase deposition using ethylene glycol (EG) and water mixture under atmospheric conditions. The physicochemical characterizations of the catalyst carried out by surface area analyzer, x-ray diffraction (XRD), x-ray photoelectron spectroscopy (XPS), electron microscopes measurements suggest the formation of crystalline nanoparticles structure of NiO. The surface area of Ni/NiO prepared using EG/water mixture reaches 70 m2 g-1 which is 2-fold enhsancement in surface area in comparison with NiO prepared in pure EG and an order of magnitude higher than that of bulk nickel prepared in pure water. The methanol electro-oxidation activity of the Ni/NiO nanoparticles obtained in EG/water mixture displayed more than 4-fold increase in oxidation current at 1.7 V versus RHE in comparison with NiO nanoparticles obtained in EG and 20-fold increase compared to bulk nickel catalyst concord with the enhancement of electro-active surface area. The results show the Ni/NiO nanoparticles produced by microwave assisted synthesis has superior activity for methanol oxidation in alkaline solution over the other nickel based catalysts and has potential for mass production.

  9. Anti-corrosive and anti-microbial properties of nanocrystalline Ni-Ag coatings

    Energy Technology Data Exchange (ETDEWEB)

    Raghupathy, Y.; Natarajan, K.A.; Srivastava, Chandan, E-mail: csrivastava@materials.iisc.ernet.in

    2016-04-15

    Graphical abstract: - Highlights: • Electrodeposition yielded phase-segregated, nanocrystalline Ni-Ag coatings. • Ni-Ag alloys exhibited smaller Ni crystals compared to pure Ni. • Ultra fine Ni grains of size 12–14 nm favoured Ni-Ag solid solution. • Nanocrystalline Ag resisted bio-fouling by Sulphate Reducing bacteria. • Ni-Ag outperformed pure Ni in corrosion and bio-corrosion tests. - Abstract: Anti-corrosive and anti-bacterial properties of electrodeposited nanocrystalline Ni-Ag coatings are illustrated. Pure Ni, Ni-7 at.% Ag, & Ni-14 at.% Ag coatings were electrodeposited on Cu substrate. Coating consisted of Ni-rich and Ag-rich solid solution phases. With increase in the Ag content, the corrosion resistance of the Ni-Ag coating initially increased and then decreased. The initial increase was due to the Ni-Ag solid solution. The subsequent decrease was due to the increased galvanic coupling between the Ag-rich and Ni-rich phases. For all Ag contents, the corrosion resistance of the Ni-Ag coating was higher than the pure Ni coating. Exposure to Sulphate Reducing Bacteria (SRB) revealed that the extent of bio-fouling decreased with increase in the Ag content. After 2 month exposure to SRB, the Ni-Ag coatings demonstrated less loss in corrosion resistance (58% for Ni-7 at.% Ag and 20% for Ni-14 at.% Ag) when compared pure Ni coating (115%).

  10. Anti-corrosive and anti-microbial properties of nanocrystalline Ni-Ag coatings

    International Nuclear Information System (INIS)

    Raghupathy, Y.; Natarajan, K.A.; Srivastava, Chandan

    2016-01-01

    Graphical abstract: - Highlights: • Electrodeposition yielded phase-segregated, nanocrystalline Ni-Ag coatings. • Ni-Ag alloys exhibited smaller Ni crystals compared to pure Ni. • Ultra fine Ni grains of size 12–14 nm favoured Ni-Ag solid solution. • Nanocrystalline Ag resisted bio-fouling by Sulphate Reducing bacteria. • Ni-Ag outperformed pure Ni in corrosion and bio-corrosion tests. - Abstract: Anti-corrosive and anti-bacterial properties of electrodeposited nanocrystalline Ni-Ag coatings are illustrated. Pure Ni, Ni-7 at.% Ag, & Ni-14 at.% Ag coatings were electrodeposited on Cu substrate. Coating consisted of Ni-rich and Ag-rich solid solution phases. With increase in the Ag content, the corrosion resistance of the Ni-Ag coating initially increased and then decreased. The initial increase was due to the Ni-Ag solid solution. The subsequent decrease was due to the increased galvanic coupling between the Ag-rich and Ni-rich phases. For all Ag contents, the corrosion resistance of the Ni-Ag coating was higher than the pure Ni coating. Exposure to Sulphate Reducing Bacteria (SRB) revealed that the extent of bio-fouling decreased with increase in the Ag content. After 2 month exposure to SRB, the Ni-Ag coatings demonstrated less loss in corrosion resistance (58% for Ni-7 at.% Ag and 20% for Ni-14 at.% Ag) when compared pure Ni coating (115%).

  11. Effect of Ni Core Structure on the Electrocatalytic Activity of Pt-Ni/C in Methanol Oxidation

    Science.gov (United States)

    Kang, Jian; Wang, Rongfang; Wang, Hui; Liao, Shijun; Key, Julian; Linkov, Vladimir; Ji, Shan

    2013-01-01

    Methanol oxidation catalysts comprising an outer Pt-shell with an inner Ni-core supported on carbon, (Pt-Ni/C), were prepared with either crystalline or amorphous Ni core structures. Structural comparisons of the two forms of catalyst were made using transmission electron microscopy (TEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS), and methanol oxidation activity compared using CV and chronoamperometry (CA). While both the amorphous Ni core and crystalline Ni core structures were covered by similar Pt shell thickness and structure, the Pt-Ni(amorphous)/C catalyst had higher methanol oxidation activity. The amorphous Ni core thus offers improved Pt usage efficiency in direct methanol fuel cells. PMID:28811402

  12. Effect of Ni Core Structure on the Electrocatalytic Activity of Pt-Ni/C in Methanol Oxidation

    Directory of Open Access Journals (Sweden)

    Vladimir Linkov

    2013-07-01

    Full Text Available Methanol oxidation catalysts comprising an outer Pt-shell with an inner Ni-core supported on carbon, (Pt-Ni/C, were prepared with either crystalline or amorphous Ni core structures. Structural comparisons of the two forms of catalyst were made using transmission electron microscopy (TEM, X-ray diffraction (XRD and X-ray photoelectron spectroscopy (XPS, and methanol oxidation activity compared using CV and chronoamperometry (CA. While both the amorphous Ni core and crystalline Ni core structures were covered by similar Pt shell thickness and structure, the Pt-Ni(amorphous/C catalyst had higher methanol oxidation activity. The amorphous Ni core thus offers improved Pt usage efficiency in direct methanol fuel cells.

  13. Resiliencia en Niños

    OpenAIRE

    Norma Ivonne González Arratia Lopez Fuentes

    2007-01-01

    Con el objetivo de acercarse al constructo teórico de resiliencia, y desde la propuesta de Grotberg (1995a) y Melillo (2003), del modelo donde es posible caracterizar a un niño resiliente a través de la posesión de condiciones que en el lenguaje se expresan diciendo: "Yo tengo", "Yo soy", "Yo estoy", "Yo puedo", es que se procedió a hacer la aplicación de la técnica de Redes Semánticas Naturales a 400 niños de ambos sexos, de 6° año de primaria de escuelas públicas y privadas de la ciudad de ...

  14. Ni ion damage in Cu and Nb

    International Nuclear Information System (INIS)

    Roberto, J.B.; Narayan, J.

    1975-01-01

    Ni ion damage in Cu was studied using x-ray diffuse scattering and transmission electron microscopy, and in Nb using x-ray diffuse scattering. Single crystals of Cu and Nb were irradiated at room temperature to a fluence of 1.2 x 10 13 /cm 2 at 60 MeV, and Cu was also irradiated to 5 x 10 12 /cm 2 at 4 MeV. The x-ray diffuse scattering from loop-type defect clusters in the crystals was measured near several Bragg reflections in order to probe the depth distributions of the damage. In Cu, cluster size distributions derived from the x-ray measurements agreed well with TEM results. Comparison with fission reactor irradiations using the damage energy concept suggests similarities in retained damage between the neutron and Ni ion irradiations

  15. Internal chlorination of Ni-Cr alloys

    Energy Technology Data Exchange (ETDEWEB)

    Berztiss, D.; Hennesen, K.; Grabke, H.J. [Max-Planck-Institut fuer Eisenforschung GmbH, Duesseldorf (Germany)

    1998-12-31

    In contrast to internal oxidation, sulfidation and carburization, very little information is available regarding internal chlorination, especially diffusion of chlorine in metallic alloys. This paper describes results of experiments on Ni-Cr alloys (<10 wt% Cr) exposed in an atmosphere containing radioactive HCl. The diffusion of chlorine in the alloy can be determined by measurement of residual {beta}-activity from the sample surface. Successively thin layers (0.5-10 {mu}m) of the alloy were removed by lapping and the surface activity was measured to obtain a depth profile. Both single and polycrystalline materials were tested. Through this work it should be determined if there is in fact solubility and diffusion of chlorine in Ni-based alloys as some authors have proposed or if the ingress of chlorine is mainly a grain boundary phenomenon. (orig.)

  16. Fe-Ni-bearing serpentines from the saprolite horizon of Caribbean Ni-laterite deposits: new insights from thermodynamic calculations

    Science.gov (United States)

    Villanova-de-Benavent, Cristina; Domènech, Cristina; Tauler, Esperança; Galí, Salvador; Tassara, Santiago; Proenza, Joaquín A.

    2017-10-01

    Fe-Ni-bearing serpentine from the saprolite horizon is the main Ni ores in hydrous silicate-type Ni laterites and formed by chemical weathering of partially serpentinized ultramafic rocks under tropical conditions. During lateritization, Mg, Si, and Ni are leached from the surface and transported downwards. Fe2+ is oxidized to Fe3+ and fixed as insoluble Fe-oxyhydroxides (mostly goethite) that incorporate Ni. This Ni is later leached from goethite and incorporated in secondary serpentine and garnierite. As a result, a serpentine-dominated saprolite horizon forms over the ultramafic protolith, overlapped by a Fe-oxyhydroxide-dominated limonite horizon. The serpentine from the protolith (serpentine I) is of hydrothermal origin and yields similar Ni (0.10-0.62 wt.% NiO) and lower Fe (mostly 1.37-5.81 wt.% FeO) concentrations than the primary olivine. In contrast, Fe-Ni-bearing serpentine from the saprolite (serpentine II) shows significantly higher and variable Fe and Ni contents, typically ranging from 2.23 to 15.59 wt.% Fe2O3 and from 1.30 to 7.67 wt.% NiO, suggesting that serpentine get enriched in Fe and Ni under supergene conditions. This study presents detailed mineralogical, textural, and chemical data on this serpentine II, as well as new insights by thermodynamic calculations assuming ideal solution between Fe-, Ni- and Mg-pure serpentines. The aim is to assess if at atmospheric pressure and temperature Fe-Ni-bearing serpentine can be formed by precipitation. Results indicate that the formation of serpentine II under atmospheric pressure and temperature is thermodynamically supported, and pH, Eh, and the equilibrium constant of the reaction are the parameters that affect the results more significantly.

  17. Electrochemically induced transformation of NiS nanoparticles into Ni(OH)2 in KOH aqueous solution toward electrochemical capacitors

    International Nuclear Information System (INIS)

    Hou Linrui; Yuan Changzhou; Li Diankai; Yang Long; Shen Laifa; Zhang Fang; Zhang Xiaogang

    2011-01-01

    Highlights: → NiS is synthesized by means of the H 2 O/CS 2 interface under hydrothermal treatment. → NiS itself owns poor electrochemical capacitance in 2 M KOH solution. → NiS is electrochemically induced and transformed into electroactive Ni(OH) 2 . → Ni(OH) 2 is responsible for good energy storage of the NiS in the KOH solution. → The new formed Ni(OH) 2 delivers large energy density at high rates. - Abstract: Nickel sulfide nanoparticles (NPs) are first synthesized by virtue of a unique H 2 O/CS 2 interface under mild hydrothermal treatment. Electrochemical data reveals that the as-synthesized NiS NPs themselves own poor supercapacitive behavior at initial cyclic voltammetry (CV) cycles in 2 M KOH solution, while a specific capacitance of 893 F g -1 can be surprisingly obtained at a current density of 5 A g -1 just after continuous 320 CV cycles. X-ray diffraction and Fourier transform infrared techniques demonstrate that what is really responsible for the good electrochemical capacitance in the KOH aqueous solution is the new electrochemically formed Ni(OH) 2 phase, rather than NiS NPs themselves. The Ni(OH) 2 is slowly formed during the continuous CV cycling process, in which the electrochemically induced phase transformation from NiS to Ni(OH) 2 phase takes place. Furthermore, the new Ni(OH) 2 phase demonstrates the great ability of delivering large specific capacitance at high rates.

  18. Marca personal: Niña Pinturera

    OpenAIRE

    Cordero González, Bella

    2017-01-01

    En el siguiente trabajo fin de grado se expone el proceso del Personal Branding o creación de marca personal de “Niña Pinturera”. Se desarrolla desde los inicios de su historia, el diseño de la identidad corporativa hasta la estrategia a seguir y su plan de comunicación, enfocado al entorno digital y las redes sociales. Grado en Publicidad y Relaciones Públicas

  19. Imaging magnetic domains in Ni nanostructures

    International Nuclear Information System (INIS)

    Asenjo, A.; Jaafar, M.; Gonzalez, E.M.; Martin, J.I.; Vazquez, M.; Vicent, J.L.

    2007-01-01

    The study of nanomagnets is the subject of increasing scientific effort. The size, the thickness and the geometric shape of the elements determine the magnetic properties and then the domain configuration. In this work, we fabricated by electron-beam lithography the three different arrays of Ni nanostructures keeping the size, the thickness and also the distance constant between the elements but varying the geometry: square, triangular and circular. The domain structure of the nanomagnets is studied by magnetic force microscopy

  20. Breakdown of antiferromagnet order in polycrystalline NiFe/NiO bilayers probed with acoustic emission

    Science.gov (United States)

    Lebyodkin, M. A.; Lebedkina, T. A.; Shashkov, I. V.; Gornakov, V. S.

    2017-07-01

    Magnetization reversal of polycrystalline NiFe/NiO bilayers was investigated using magneto-optical indicator film imaging and acoustic emission techniques. Sporadic acoustic signals were detected in a constant magnetic field after the magnetization reversal. It is suggested that they are related to elastic waves excited by sharp shocks in the NiO layer with strong magnetostriction. Their probability depends on the history and number of repetitions of the field cycling, thus testifying the thermal-activation nature of the long-time relaxation of an antiferromagnetic order. These results provide evidence of spontaneous thermally activated switching of the antiferromagnetic order in NiO grains during magnetization reversal in ferromagnet/antiferromagnet (FM/AFM) heterostructures. The respective deformation modes are discussed in terms of the thermal fluctuation aftereffect in the Fulcomer and Charap model which predicts that irreversible breakdown of the original spin orientation can take place in some antiferromagnetic grains with disordered anisotropy axes during magnetization reversal of exchange-coupled FM/AFM structures. The spin reorientation in the saturated state may induce abrupt distortion of isolated metastable grains because of the NiO magnetostriction, leading to excitation of shock waves and formation of plate (or Lamb) waves.

  1. Structural, electrical and magnetic properties of evaporated Ni/Cu and Ni/glass thin films

    International Nuclear Information System (INIS)

    Nacereddine, C.; Layadi, A.; Guittoum, A.; Cherif, S.-M.; Chauveau, T.; Billet, D.; Youssef, J. Ben; Bourzami, A.; Bourahli, M.-H.

    2007-01-01

    The structural, electrical and magnetic properties of Ni thin films evaporated onto glass and polycrystalline Cu substrates have been investigated. The Ni thickness ranges from 31 to 165 nm. X-ray diffraction (XRD), scanning electron microscopy (SEM) and atomic force microscopy (AFM) have been used to study the structure and morphology of these systems. The Ni/Cu and Ni/glass thin films are found to be polycrystalline with a (1 1 1) texture. There is an overall increase of the grain size with increasing thickness. A negative strain was noted indicating that all the samples are under a compressive stress. Diffusion at the grain boundaries seems to be a major contribution to the electrical resistivity in this thickness range. Study of the hysteresis curves, obtained by vibrating sample magnetometer (VSM), indicates that all samples are characterized by an in-plane magnetization easy axis. Higher in-plane coercive fields seem to be associated with higher grain size, indicating that coercivity may be due to nucleation of reverse domains rather than pinning of domain walls. The saturation field and the squareness have been studied as a function of the Ni thickness

  2. Participar como niña o niño en el mundo social

    Directory of Open Access Journals (Sweden)

    Silvia Paulina Díaz

    2010-01-01

    Full Text Available En este artículo presento la participación como resultado de un trabajo investigativo realizado durante el año 2007, con niños y niñas escolarizados habitantes de la ciudad de Medellín, Colombia, cuyo objetivo fue analizar las representaciones sociales que ellos y ellas comparten sobre el ejercicio ciudadano. El análisis de la información tiene como ejes fundamentales, la salud colectiva, la sociología de la infancia y la participación en la niñez, en una aproximación que se realiza desde un enfoque cualitativo y etnográfico. En los hallazgos, sobresale cómo las niñas y niños se muestran preparados para ejercer su derecho a la participación como aspecto de sus vidas que se haría posible dentro del marco normativo existente, pero que aún no es asumido en prácticas sociales que los incluyan.

  3. High resolution TEM study of Ni4Ti3 precipitates in austenitic Ni51Ti49

    International Nuclear Information System (INIS)

    Tirry, Wim; Schryvers, Dominique

    2003-01-01

    Binary NiTi with a composition of 51 at.% Ni was heat treated to form lens-shaped Ni 4 Ti 3 precipitates that are coherent or semi-coherent with the B2 matrix. High resolution transmission electron microscopy (HRTEM) was used to study the internal structure of the precipitates, precipitate-precipitate and matrix-precipitate interfaces and the deformation of the B2 matrix near a precipitate. Observations were made in the B2 and B2 zones and compared with computer simulated high resolution images. The B2 observations made it possible to study the [0 0 1] H zone orientation of Ni 4 Ti 3 (direction defined according to the hexagonal unit cell of Ni 4 Ti 3 ) which corresponds to the normal of the central plane of the discs. In these images the superperiodicity of the 4:3 ordering is clearly visible confirming the known atomic structure. Close to the precipitate the B2 matrix is deformed, as determined by measuring the interplanar spacing from the HRTEM images. The observed deformations are compared with theoretical models for the stress field

  4. Coarsening kinetics of coherent precipitates in Ni-Al-Mo and Fe-Ni-Al alloys

    International Nuclear Information System (INIS)

    Calderon, H.A.; Dorantes, H.J.; Cruz, J.J.; Cabanas-Moreno, J.G.

    1997-01-01

    The late stage coarsening kinetics of coherent γ' and β' have been investigated in single crystalline specimens of Ni-14.5 at.% Al-5.9 at.% Mo and Fe-10 at.% Ni-15 at.% Al after aging at 1453 K for the Ni alloy and 1233 K for the Fe alloy. Scanning electron microscopy (SEM) shows that early in the coarsening regime there is particle splitting in the Ni-base alloy. Continued aging changes the spatial distribution of particles giving rise to the formation of groups of many particles. In the Fe-base alloy, formation of particle groups is seen earlier. Longer aging treatments produce large particles that split forming plate like precipitates. Particle migration is evident in both alloys. The coarsening kinetics of particles in the Ni-base alloy show deviations from the usual linear behavior between the cube of the average particle radius and the aging time. There is a reduction of the coarsening rate and in addition broader particle size distributions are obtained. In the Fe-base alloy, direct measurements of particle areas on SEM images show a linear dependence of the cube of the average particle radius with the aging time. However, after correcting for particle shape an increase of the coarsening rate is suggested. (orig.)

  5. Coarsening kinetics of coherent precipitates in Ni-Al-Mo and Fe-Ni-Al alloys

    Energy Technology Data Exchange (ETDEWEB)

    Calderon, H.A.; Dorantes, H.J.; Cruz, J.J.; Cabanas-Moreno, J.G. [ESIQIE-IPN, Mexico (Mexico). Dept. de Ingenieria Metalurgica; Kostorz, G.; Qu, Y.Y. [ETH Zuerich, Institut fuer Angewandte Physik, Zuerich CH-8093 (Switzerland)

    1997-10-30

    The late stage coarsening kinetics of coherent {gamma}` and {beta}` have been investigated in single crystalline specimens of Ni-14.5 at.% Al-5.9 at.% Mo and Fe-10 at.% Ni-15 at.% Al after aging at 1453 K for the Ni alloy and 1233 K for the Fe alloy. Scanning electron microscopy (SEM) shows that early in the coarsening regime there is particle splitting in the Ni-base alloy. Continued aging changes the spatial distribution of particles giving rise to the formation of groups of many particles. In the Fe-base alloy, formation of particle groups is seen earlier. Longer aging treatments produce large particles that split forming plate like precipitates. Particle migration is evident in both alloys. The coarsening kinetics of particles in the Ni-base alloy show deviations from the usual linear behavior between the cube of the average particle radius and the aging time. There is a reduction of the coarsening rate and in addition broader particle size distributions are obtained. In the Fe-base alloy, direct measurements of particle areas on SEM images show a linear dependence of the cube of the average particle radius with the aging time. However, after correcting for particle shape an increase of the coarsening rate is suggested. (orig.) 19 refs.

  6. Participar como niña o niño en el mundo social

    Directory of Open Access Journals (Sweden)

    Silvia Paulina Díaz

    2010-10-01

    Full Text Available En este artículo presento la participación como resultado de un trabajo investigativo realizado durante el año 2007, con niños y niñas escolarizados habitantes de la ciudad de Medellín, Colombia, cuyo objetivo fue analizar las representaciones sociales que ellos y ellas comparten sobre el ejercicio ciudadano. El análisis de la información tiene como ejes fundamentales, la salud colectiva, la sociología de la infancia y la participación en la niñez, en una aproximación que se realiza desde un enfoque cualitativo y etnográfico. En los hallazgos, sobresale cómo las niñas y niños se muestran preparados para ejercer su derecho a la participación como aspecto de sus vidas que se haría posible dentro del marco normativo existente, pero que aún no es asumido en prácticas sociales que los incluyan.

  7. Carbon dioxide hydrogenation on Ni(110).

    Science.gov (United States)

    Vesselli, Erik; De Rogatis, Loredana; Ding, Xunlei; Baraldi, Alessandro; Savio, Letizia; Vattuone, Luca; Rocca, Mario; Fornasiero, Paolo; Peressi, Maria; Baldereschi, Alfonso; Rosei, Renzo; Comelli, Giovanni

    2008-08-27

    We demonstrate that the key step for the reaction of CO 2 with hydrogen on Ni(110) is a change of the activated molecule coordination to the metal surface. At 90 K, CO 2 is negatively charged and chemically bonded via the carbon atom. When the temperature is increased and H approaches, the H-CO 2 complex flips and binds to the surface through the two oxygen atoms, while H binds to the carbon atom, thus yielding formate. We provide the atomic-level description of this process by means of conventional ultrahigh vacuum surface science techniques combined with density functional theory calculations and corroborated by high pressure reactivity tests. Knowledge about the details of the mechanisms involved in this reaction can yield a deeper comprehension of heterogeneous catalytic organic synthesis processes involving carbon dioxide as a reactant. We show why on Ni the CO 2 hydrogenation barrier is remarkably smaller than that on the common Cu metal-based catalyst. Our results provide a possible interpretation of the observed high catalytic activity of NiCu alloys.

  8. Electric Monopole Transition Strengths in 62Ni

    Directory of Open Access Journals (Sweden)

    Evitts L. J.

    2016-01-01

    Full Text Available Excited states in 62Ni were populated with a (p, p’ reaction using the 14UD Pelletron accelerator at the Australian National University. Electric monopole transition strengths, ρ2(E0, were measured through simultaneous detection of the internal conversion electrons and γ rays emitted from the de-excitation of populated states, using the Super-e spectrometer coupled with a germanium detector. The strength of the 02+ to 01+ transition has been measured to be 77−34+23 × 10−3 and agrees with previously reported values. Upper limits have been placed on the 03+ to 01+ and 03+ to 02+ transitions. The measured ρ2(E0 value of the 22+ to 21+ transition in 62Ni has been measured for the first time and found to be one of the largest ρ2(E0 values measured to date in nuclei heavier than Ca. The low-lying states of 62Ni have previously been classified as one- and two-phonon vibrational states based on level energies. The measured electric quadrupole transition strengths are consistent with this interpretation. However as electric monopole transitions are forbidden between states which differ by one phonon number, the simple harmonic quadrupole vibrational picture is not suffcient to explain the large ρ2(E0 value for the 22+ to 21+ transition.

  9. Electric Monopole Transition Strengths in 62Ni

    Science.gov (United States)

    Evitts, L. J.; Garnsworthy, A. B.; Kibédi, T.; Moukaddam, M.; Alshahrani, B.; Eriksen, T. K.; Holt, J. D.; Hota, S. S.; Lane, G. J.; Lee, B. Q.; McCormick, B. P.; Palalani, N.; Reed, M. W.; Stroberg, S. R.; Stuchbery, A. E.

    2016-09-01

    Excited states in 62Ni were populated with a (p, p') reaction using the 14UD Pelletron accelerator at the Australian National University. Electric monopole transition strengths, ρ2(E0), were measured through simultaneous detection of the internal conversion electrons and γ rays emitted from the de-excitation of populated states, using the Super-e spectrometer coupled with a germanium detector. The strength of the 02+ to 01+ transition has been measured to be 77-34+23 × 10-3 and agrees with previously reported values. Upper limits have been placed on the 03+ to 01+ and 03+ to 02+ transitions. The measured ρ2(E0) value of the 22+ to 21+ transition in 62Ni has been measured for the first time and found to be one of the largest ρ2(E0) values measured to date in nuclei heavier than Ca. The low-lying states of 62Ni have previously been classified as one- and two-phonon vibrational states based on level energies. The measured electric quadrupole transition strengths are consistent with this interpretation. However as electric monopole transitions are forbidden between states which differ by one phonon number, the simple harmonic quadrupole vibrational picture is not suffcient to explain the large ρ2(E0) value for the 22+ to 21+ transition.

  10. Combining Ru, Ni and Ni(OH){sub 2} active sites for improving catalytic performance in benzene hydrogenation

    Energy Technology Data Exchange (ETDEWEB)

    Zhu, Lihua, E-mail: lihuazhu@stu.xmu.edu.cn [School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, Jiang Xi (China); Department of Chemical and Biochemical Engineering, National Engineering Laboratory for Green Productions of Alcohols-Ethers-Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China); Sun, Hanlei; Zheng, Jinbao [Department of Chemical and Biochemical Engineering, National Engineering Laboratory for Green Productions of Alcohols-Ethers-Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China); Yu, Changlin, E-mail: yuchanglinjx@163.com [School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, Jiang Xi (China); Zhang, Nuowei [Department of Chemical and Biochemical Engineering, National Engineering Laboratory for Green Productions of Alcohols-Ethers-Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China); Shu, Qing [School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, Jiang Xi (China); Chen, Bing H., E-mail: chenbh@xmu.edu.cn [Department of Chemical and Biochemical Engineering, National Engineering Laboratory for Green Productions of Alcohols-Ethers-Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China)

    2017-05-01

    In this study, the Ru{sub 0.04}Ni{sub 0.96}/C(T) catalysts were successfully prepared by the simple methods of hydrazine-reduction and galvanic replacement, where 0.04/0.96 and T represented the Ru/Ni atomic ratio and reducing temperature of the catalyst in N{sub 2}+10%H{sub 2}, respectively. The nanostructures of the Ru{sub 0.04}Ni{sub 0.96} nanoparticles in the Ru{sub 0.04}Ni{sub 0.96}/C(T) catalysts were controlled by modulating their annealing temperature in N{sub 2}+10%H{sub 2} and characterized by an array of techniques, including X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), high resolution transmission electron microscopy (HRTEM), scanning transmission electron microscopy energy dispersive X-ray spectroscopy (STEM-EDS) mapping and high-sensitivity low-energy ion scattering (HS-LEIS). The Ru{sub 0.04}Ni{sub 0.96}/C(30) catalyst, which was composed of Ru clusters or single atoms supported on Ni/Ni(OH){sub 2} nanoparticles, exhibited much better catalytic performance for benzene hydrogenation than the Ru{sub 0.04}Ni{sub 0.96}/C(T) catalysts reduced at above 30 °C, such as Ru{sub 0.04}Ni{sub 0.96}/C(160) with the nanostructure of partial Ru{sub 0.04}Ni{sub 0.9} alloy and Ru{sub 0.04}Ni{sub 0.96}/C(280) with the nanostructure of complete Ru{sub 0.04}Ni{sub 0.9} alloy. The reason was that the synergistic effect of multiple active sites – Ru, Ni and Ni(OH){sub 2} sites was present in the Ru{sub 0.04}Ni{sub 0.96}/C(30) catalyst, where hydrogen was preferentially activated at Ru sites, benzene was probably activated at Ni(OH){sub 2} surface and Ni acted as a “bridge” for transferring activated H{sup ∗} species to activated benzene by hydrogen spillover effect, hydrogenating and forming product – cyclohexane. This study also provided a typical example to illustrate that the synergy effect of multiple active sites can largely improve the catalytic hydrogenation performance. - Highlights: • The Ru

  11. Fabrications of High-Capacity Alpha-Ni(OH2

    Directory of Open Access Journals (Sweden)

    Kwo-Hsiung Young

    2017-03-01

    Full Text Available Three different methods were used to produce α-Ni(OH2 with higher discharge capacities than the conventional β-Ni(OH2, specifically a batch process of co-precipitation, a continuous process of co-precipitation with a phase transformation step (initial cycling, and an overcharge at low temperature. All three methods can produce α-Ni(OH2 or α/β mixed-Ni(OH2 with capacities higher than that of conventional β-Ni(OH2 and a stable cycle performance. The second method produces a special core–shell β-Ni(OH2/α-Ni(OH2 structure with an excellent cycle stability in the flooded half-cell configuration, is innovative and also already mass-production ready. The core–shell structure has been investigated by both scanning and transmission electron microscopies. The shell portion of the particle is composed of α-Ni(OH2 nano-crystals embedded in a β-Ni(OH2 matrix, which helps to reduce the stress originating from the lattice expansion in the β-α transformation. A review on the research regarding α-Ni(OH2 is also included in the paper.

  12. Phytoremediation of Ni-contaminated soil by Salicornia iranica.

    Science.gov (United States)

    Kaviani, Elina; Niazi, Ali; Moghadam, Ali; Taherishirazi, Mohsen; Heydarian, Zohreh

    2017-10-16

    Although nickel (Ni) is useful and is used in various industries, it is one of the most usual and important sources of heavy metals pollutants in the world. In this study, Salicornia iranica was used in order to phytoremediate Ni-contaminated soil. Possible mechanisms of plant tolerance to Ni pollution and its detoxification were studied through using expression analysis of glutathione-S-transferase (GST) and measurement of involved key physiological components. The concentration of the chlorophylls a, b, total chlorophyll, and carotenoids were significantly decreased in 500 mg/kg Ni at 3, 24, 48 h, and 90 days after the treatment. Free proline significantly increased in the tissues. The absorption and concentration of Ni increased in tissues, so that Ni concentration at 50, 250, and 500 mg Ni/kg soil significantly increased to 2.5, 3.5, and 4.5 fold compared with the lowest Ni level respectively. In addition, the GST expression was significantly increased both in the 50 and 500 mg/kg Ni treatment. The highest concentration of Ni affected plant growth parameters such as the root and shoot lengths. Therefore, S. iranica is able to accumulate Ni and it can be used as an environmental biotechnological study for phytoremediation of Ni-polluted soils. ABA: abscisic acid; ABRE: ABA-responsive element; As +3 : arsenic; Cd 2+ : cadmium; ef1: elongation factor; FW: fresh weight; GSH: glutathione; GST: glutathione-S-transferase; GSTU: tau class GST; Hcl: hydrochloric acid; Hg 2+ : mercury; HgCl 2 : mercury(II) chloride; MYB: myeloblastosis viral oncogene homolog; Ni +2 : nickel; Pb: lead; SiGSTU: Salicornia iranica GSTU; ZnSO 4 : zinc sulfate.

  13. Density function theoretical investigation on the Ni3PP structure and the hydrogen adsorption property of the Ni2P(0001) surface

    OpenAIRE

    Ariga, Hiroko; Kawashima, Mayumi; Takakusagi, Satoru; Asakura, Kiyotaka

    2013-01-01

    The electronic and structural properties of a phosphorus-terminated structure of Ni2P(0001) surface (Ni3PP) are investigated by density functional theory (DFT) calculations. Phosphorus adsorption largely stabilizes the Ni2P(0001) surface by creating Ni-P bonds on the Ni trimer. Atomic hydrogen can adsorb on the topmost P site although its adsorption energy is much lower than its adsorption energy on the Ni trimer site of the Ni3P2 surface. Our results suggest that the Ni trimer is the key fac...

  14. Morphological instability of lamellar structures in directionally solidified Ni-Ni3Si alloys

    Science.gov (United States)

    Wei, Lufeng; Zhao, Zhilong; Gao, Jianjun; Cui, Kai; Guo, Jingying; Chen, Sen; Liu, Lin

    2018-02-01

    The morphological instability of lamellar structures in Ni-Ni3Si eutectic and hypereutectic alloys directionally solidified at low growth rates was investigated. The first instability in large lamellar structures was zigzag instability, which formed curved lamellae. A zigzag pattern was first displayed in three dimensions. The diffusion-limited growth of the Ni3Si phase decreased phase width and spacing, consequently causing zigzag instability. The reduced spacing was observed at λ/λave = 0.9. After zigzag instability, the microstructure of the eutectic alloy turned into a labyrinth structure and lamellar fragmentation. However, in hypereutectic alloys, shape transition from lamellae to rods occurred, in turn, by the broken lamellae or elongated rods to dumbbell-shaped rods, peanut-shaped rods, and circular rods.

  15. Hydrothermal Ni Prospectivity Analysis of Tasmania, Australia

    Science.gov (United States)

    Gonzalez-Alvarez, I.; Porwal, A.; McCuaig, T. C.; Maier, W.

    2009-04-01

    Tasmania contains the largest hydrothermal Ni deposit in Australia: Avebury (118,000 Ni metal tonnes). This Devonian deposit was discovered in 1998 in the Dundas geological region, and consists of a system of hydrothermal Ni ore bodies. They are hosted by an intensely altered and serpentinized Cambrian ultramafic suite in close proximity to major structural features. The mineralization is considered to be the result of hydrothermal scavenging and remobilization of the original nickel content of mafic/ultramafic rocks in the area, and subsequent re-deposition in favourable structural traps. This is based on the low sulphur, low Cu and Platinum element content of the mineralization. The mineralization is spatially (at the edge) and temporally related to a large granitic intrusion, the Heemskirk Granite, which is considered to be the source of the hydrothermal fluids as well as the necessary thermal gradients for the circulation of the fluids. Tasmania is largely covered by the Jurassic Ferrar continental flood basalt province in the East and constrains a number of early Cambrian ultramafic-mafic complexes in the West. The Ferrar large igneous province (LIP) extends over to Antarctica and is temporally and genetically related to the Karoo igneous province in southern Africa that comprises tholeiitic lava flows, sills, and dyke swarms. The Ferrar and Karoo igneous provinces were associated with the same thermal anomaly that was responsible for the break up of eastern Gondwana at ca 180 Ma. Despite of timeframe differences between the Avebury Ni deposits and the Ferrar LIP emplacement, similar geological settings to the Avebury could be duplicated along the Ferrar LIP. The presence of mafic/ultramafic rocks in favourable lithological packages and/or structural traps along the margins of the province indicate that this LIP could represent a possible exploration target for Ni hydrothermal deposits. Based on this background, a prospectivity analysis for hydrothermal Ni

  16. Influence of Ni doping on PtNi nanoparticles: Synthesis, electronic/atomic structure and photocatalyst investigations

    Science.gov (United States)

    Varshney, Mayora; Sharma, Aditya; Shin, Hyun-Joon; Lee, Hyun Hwi; Jeon, Tae-Yeol; Lee, Byeong-Hyeon; Chae, Keun-Hwa; Won, Sung Ok

    2017-11-01

    Carbon-supported Pt and PtNi nanoparticles (NPs) were synthesized using a borohydride reduction method. Structural properties were studied by synchrotron X-ray diffraction (XRD) and the size/shape of the NPs was determined by transmission electron microscope (TEM). X-ray absorption spectroscopy with its two amendments; X-ray absorption near edge structure (XANES) and extended X-ray absorption fine structure (EXAFS), has been employed to investigate the local electronic/atomic structure surrounding the Pt and Ni atoms. XANES results, at Pt L3-edge and Ni K-edge, have shown fractional oxidation of Pt and Ni atoms. The Pt3Ni1NPs have exhibited a lower bond distance of Pt-Ni shell and higher coordination number of Pt-Ni shells, indicating the alloy formation between Pt and Ni. We further have demonstrated that the Pt and PtNi NPs can serve as effective photocatalysts towards the degradation of water pollutant dye (methyl orange (MO)). By considering the interband charge-transfer of Pt (5d →6sp), a tentative mechanism is proposed to understand the photocatalytic degradation of MO dye molecules by Pt/PtNi NPs under the light irradiation.

  17. Impact of Interstitial Ni on the Thermoelectric Properties of the Half-Heusler TiNiSn

    Directory of Open Access Journals (Sweden)

    Sonia A. Barczak

    2018-03-01

    Full Text Available TiNiSn is an intensively studied half-Heusler alloy that shows great potential for waste heat recovery. Here, we report on the structures and thermoelectric properties of a series of metal-rich TiNi1+ySn compositions prepared via solid-state reactions and hot pressing. A general relation between the amount of interstitial Ni and lattice parameter is determined from neutron powder diffraction. High-resolution synchrotron X-ray powder diffraction reveals the occurrence of strain broadening upon hot pressing, which is attributed to the metastable arrangement of interstitial Ni. Hall measurements confirm that interstitial Ni causes weak n-type doping and a reduction in carrier mobility, which limits the power factor to 2.5–3 mW m−1 K−2 for these samples. The thermal conductivity was modelled within the Callaway approximation and is quantitively linked to the amount of interstitial Ni, resulting in a predicted value of 12.7 W m−1 K−1 at 323 K for stoichiometric TiNiSn. Interstitial Ni leads to a reduction of the thermal band gap and moves the peak ZT = 0.4 to lower temperatures, thus offering the possibility to engineer a broad ZT plateau. This work adds further insight into the impact of small amounts of interstitial Ni on the thermal and electrical transport of TiNiSn.

  18. When NiO@Ni Meets WS2 Nanosheet Array: A Highly Efficient and Ultrastable Electrocatalyst for Overall Water Splitting

    Directory of Open Access Journals (Sweden)

    Dewen Wang

    2017-12-01

    Full Text Available The development of low-cost, high-efficiency, and stable bifunctional electrocatalysts toward the hydrogen evolution reaction (HER and oxygen evolution reaction (OER is of paramount importance for large-scale water splitting. Here, we develop a new strategy for the first design and synthesis of a NiO@Ni decorated WS2 nanosheet array on carbon cloth (NiO@Ni/WS2/CC composite. This composite serves as a unique three-dimensional (3D synergistic electrocatalyst that not only combines the intrinsic properties of individual NiO@Ni and WS2, but also exhibits significantly improved HER and OER activities when compared to that of pure NiO@Ni and WS2. This electrocatalyst possesses Pt-like activity for HER and exhibits better OER performance than that for commercial RuO2, as well as demonstrating superior long-term durability in alkaline media. Furthermore, it enables an alkaline electrolyzer with a current density of 10 mA cm–2 at a cell voltage as 1.42 V, which is the lowest one among all reported values to date. The excellent performance is mainly attributed to the unique 3D configuration and multicomponent synergies among NiO, Ni, and WS2. Our findings provide a new idea to design advanced bifunctional catalysts for water splitting.

  19. On the Ni-Ion release rate from surfaces of binary NiTi shape memory alloys

    Science.gov (United States)

    Ševčíková, Jana; Bártková, Denisa; Goldbergová, Monika; Kuběnová, Monika; Čermák, Jiří; Frenzel, Jan; Weiser, Adam; Dlouhý, Antonín

    2018-01-01

    The study is focused on Ni-ion release rates from NiTi surfaces exposed in the cell culture media and human vascular endothelial cell (HUVEC) culture environments. The NiTi surface layers situated in the depth of 70 μm below a NiTi oxide scale are affected by interactions between the NiTi alloys and the bio-environments. The finding was proved with use of inductively coupled plasma mass spectrometry and electron microscopy experiments. As the exclusive factor controlling the Ni-ion release rates was not only thicknesses of the oxide scale, but also the passivation depth, which was two-fold larger. Our experimental data strongly suggested that some other factors, in addition to the Ni concentration in the oxide scale, admittedly hydrogen soaking deep below the oxide scale, must be taken into account in order to rationalize the concentrations of Ni-ions released into the bio-environments. The suggested role of hydrogen as the surface passivation agent is also in line with the fact that the Ni-ion release rates considerably decrease in NiTi samples that were annealed in controlled hydrogen atmospheres prior to bio-environmental exposures.

  20. Controlled growth of Ni/NiO core–shell nanoparticles: Structure, morphology and tuning of magnetic properties

    Energy Technology Data Exchange (ETDEWEB)

    D’Addato, S., E-mail: sergio.daddato@unimore.it [CNR-NANO, S3, via G. Campi 213/a, Modena (Italy); Dipartimento FIM, Università di Modena e Reggio Emilia, via G. Campi 213/a, Modena (Italy); Spadaro, M.C. [CNR-NANO, S3, via G. Campi 213/a, Modena (Italy); Dipartimento FIM, Università di Modena e Reggio Emilia, via G. Campi 213/a, Modena (Italy); Luches, P. [CNR-NANO, S3, via G. Campi 213/a, Modena (Italy); Grillo, V. [CNR-NANO, S3, via G. Campi 213/a, Modena (Italy); CNR-IMEM, Parco Area delle Scienze 37/A, 43100 Parma (Italy); Frabboni, S.; Valeri, S. [CNR-NANO, S3, via G. Campi 213/a, Modena (Italy); Dipartimento FIM, Università di Modena e Reggio Emilia, via G. Campi 213/a, Modena (Italy); Ferretti, A.M.; Capetti, E.; Ponti, A. [CNR-ISTM, Laboratorio di Nanotecnologie, via G. Fantoli 16/15, 20138 Milano (Italy)

    2014-07-01

    We performed a detailed study of Ni/NiO core–shell nanoparticles (NP) obtained with a gas aggregation source. The NP oxide shells were produced by oxidizing the NP with different procedures: deposition in oxygen atmosphere, post-annealing in air, sequential deposition of (a) first NiO layer, (b) Ni NP and (c) third NiO Layer. X-ray photoelectron spectroscopy from Ni 2p core-level gave information about the chemical state of Ni in the core and in the oxide shell, while scanning electron microscopy was used for investigation of the NP morphology. High quality scanning transmission electron microscopy in high angle annular dark field mode data demonstrated core–shell structure also for NiO/Ni NP/NiO samples. Field-cooled/zero-field-cooled magnetization curves and field-cooled isothermal hysteresis cycles at T = 5 K were recorded by a SQUID magnetometer. In this way, the relation between magnetic properties and oxide shell structure was assessed, showing the role played by the control of the formation of oxide on the exchange bias and interparticle magnetic interaction.

  1. Effect of amorphous Mg50Ni50 on hydriding and dehydriding behavior of Mg2Ni alloy

    International Nuclear Information System (INIS)

    Guzman, D.; Ordonez, S.; Fernandez, J.F.; Sanchez, C.; Serafini, D.; Rojas, P.A.; Aguilar, C.; Tapia, P.

    2011-01-01

    Composite Mg 2 Ni (25 wt.%) amorphous Mg 50 Ni 50 was prepared by mechanical milling starting with nanocrystalline Mg 2 Ni and amorphous Mg 50 Ni 50 powders, by using a SPEX 8000 D mill. The morphological and microstructural characterization of the powders was performed via scanning electron microscopy and X-ray diffraction. The hydriding characterization of the composite was performed via a solid gas reaction method in a Sievert's-type apparatus at 363 K under an initial hydrogen pressure of 2 MPa. The dehydriding behavior was studied by differential thermogravimetry. On the basis of the results, it is possible to conclude that amorphous Mg 50 Ni 50 improved the hydriding and dehydriding kinetics of Mg 2 Ni alloy upon cycling. A tentative rationalization of experimental observations is proposed. - Research Highlights: → First study of the hydriding behavior of composite Mg 2 Ni (25 wt.%) amorphous Mg 50 Ni 50 . → Microstructural characterization of composite material using XRD and SEM was obtained. → An improved effect of Mg 50 Ni 50 on the Mg 2 Ni hydriding behavior was verified. → The apparent activation energy for the hydrogen desorption of composite was obtained.

  2. Controlled growth of Ni/NiO core–shell nanoparticles: Structure, morphology and tuning of magnetic properties

    International Nuclear Information System (INIS)

    D’Addato, S.; Spadaro, M.C.; Luches, P.; Grillo, V.; Frabboni, S.; Valeri, S.; Ferretti, A.M.; Capetti, E.; Ponti, A.

    2014-01-01

    We performed a detailed study of Ni/NiO core–shell nanoparticles (NP) obtained with a gas aggregation source. The NP oxide shells were produced by oxidizing the NP with different procedures: deposition in oxygen atmosphere, post-annealing in air, sequential deposition of (a) first NiO layer, (b) Ni NP and (c) third NiO Layer. X-ray photoelectron spectroscopy from Ni 2p core-level gave information about the chemical state of Ni in the core and in the oxide shell, while scanning electron microscopy was used for investigation of the NP morphology. High quality scanning transmission electron microscopy in high angle annular dark field mode data demonstrated core–shell structure also for NiO/Ni NP/NiO samples. Field-cooled/zero-field-cooled magnetization curves and field-cooled isothermal hysteresis cycles at T = 5 K were recorded by a SQUID magnetometer. In this way, the relation between magnetic properties and oxide shell structure was assessed, showing the role played by the control of the formation of oxide on the exchange bias and interparticle magnetic interaction.

  3. Three-dimensional electrode of Ni/Co layered double hydroxides@NiCo2S4@graphene@Ni foam for supercapacitors with outstanding electrochemical performance

    International Nuclear Information System (INIS)

    Tao, Yan; Ruiyi, Li; Lin, Zhou; Chenyang, Ma; Zaijun, Li

    2015-01-01

    We reported a new strategy for fabricating three-dimensiona electrode of Ni/Co layered double hydroxide@NiCo 2 S 4 @graphene@Ni foam for supercapacitors. The resulting 3D electrode offers a jungle-like architecture. The unique structure creates ultra fast electron transfer and electrolyte transport as well as the maximum utilization rate of the space and the surface. The electrode exhibits a prominent advantage of high specific capacitance, high-current capacitive behaviour and cycle stability. - Highlights: • The study developed a new strategy for fabricating 3D electrode of Ni/Co-LDH@NiCo 2 S 4 @G. • The as-prepared 3D electrode offers a jungle-like architecture. • The unique structure creates an efficient conduction network and high mass loading. • The electrode achieves significantly synergetic effect among different materials. • The electrode exhibits an excellent electrochemical performance for supercapacitors. - ABSTRACT: Great challenge for the fabrication of free-standing three-dimensional electrode still remains to simultaneously achieve high specific capacitance, rate performance and cycle stability. The paper reprted a new three-dimensional (3D) electrode of Ni/Co layered double hydroxide@NiCo 2 S 4 @graphene@Ni foam (Ni/Co-LDH@NiCo 2 S 4 @G) for supercapacitors. The as-prepared 3D electrode offers an unique architecture, which create an efficient conduction network and maximum utilization of space and interface. The graphene acts as well-knit and conductive skin coated on the skeleton of Ni foam for growing NiCo 2 S 4 . The conductive NiCo 2 S 4 array serves as bridge between Ni/Co-LDH and graphene, leading to ultrafast electron transfer and electrolyte transport. A slew of splits and holes existing in the NiCo 2 S 4 array play one role as the ion-reservoir to contain host of electrolyte ions. To evaluate the feasibility of 3D electrode’s application in supercapacitors, the electrochemical performance was investigated by using the three

  4. High yield of pentane production by aqueous-phase reforming of xylitol over Ni/HZSM-5 and Ni/MCM22 catalysts

    International Nuclear Information System (INIS)

    Jiang Ting; Zhang Qing; Wang Tiejun; Zhang Qi; Ma Longlong

    2012-01-01

    Graphical abstract: Ni/HZSM-5 and Ni/MCM22 catalysts were developed with remarkable pentane yield of 90–95% for aqueous-phase reforming of xylitol. Pentane can be selectively generated by adjusting the Ni loading and acid amount of the catalyst. The Ni/MCM22 catalyst exhibited excellent stability ever after five recycle runs, while the Ni/HZSM-5 catalyst deactivated significantly. Display Omitted Highlights: ► Development of Ni/HZSM-5 and Ni/MCM22 catalyst with remarkable catalytic activity. ► High pentane production by optimizing the Ni loading of the catalyst. ► Excellent stability of Ni/MCM22 catalyst under the hydrothermal condition. - Abstract: Ni/HZSM-5 and Ni/MCM22 catalysts with different Ni loadings were prepared by impregnation method and evaluated for aqueous-phase reforming (APR) reaction of xylitol at 240 °C and 4 MPa. Effects of Ni loadings on the xylitol conversion and pentane selectivity of the catalyst was investigated. The results showed that the catalytic activities of the two Ni/HZSM-5 and Ni/MCM22 catalysts both increased with increasing Ni loading in the range of 0–2%, and then decreased as Ni loading further increased to 4%. Maximum pentane yields of 91% and 95% could be obtained over 2%Ni/HZSM-5 and 2%Ni/MCM22, respectively. 2%Ni/HZSM-5 deactivated obviously after five recycle runs, while 2%Ni/MCM22 still kept excellent activity with the pentane yield of 90–95%. The catalysts with different Ni loading were characterized by BET, H 2 -TPR and NH 3 -TPD techniques and the used selected 2%Ni/MCM22 and 2%Ni/HZSM-5 catalyst were also characterized by XRD, FTIR and TG. The characterization results revealed that 2%Ni/MCM22 and 2%Ni/HZSM-5 have similar amounts of Ni active sites, while the 2%Ni/MCM22 has larger surface area, more mesopore and less strong acid sites than the 2%Ni/HZSM-5. Moreover, partial dealumination and coke formation of the used 2%Ni/HZSM-5 catalyst were found. All these factors resulted in the deactivation of 2%Ni

  5. Strengthening by ordered precipitates in a Ni--Ni4Mo system

    International Nuclear Information System (INIS)

    Goodrum, J.W.; LeFevre, B.G.

    1977-01-01

    The strength characteristics and microstructures of aged Ni-Mo alloys containing ordered (Ni 4 Mo) precipitates were studied as a function of aging time and temperature. It was found that 17 at. percent Mo alloy aged at 750 0 C produced a uniform dispersion of cuboidal β precipitates which coarsened with time producing a gradual increase in flow stress. The flow stress increment was found to vary in qualitative agreement with both order strengthening and coherency strain models. Both these models give over-estimates of the strengthening increment. A negative dependence of flow stress on temperature is attributed to coherency strain contributions

  6. Incumplimiento del deber alimentario hacia niños, niñas y adolescentes

    OpenAIRE

    Navarro Navarro, Ysabel Liz

    2015-01-01

    Se investigaron las causas del incumplimiento alimentario hacia niños, niñas y adolescentes por parte de sus progenitores, a través de entrevistas a deudores de alimentos en la Provincia Constitucional del Callao. Se identificaron las variables que han contribuido a la construcción de determinado estilo de paternidad, masculinidad y familia. Asimismo se analizó el efecto de la cultura patriarcal y el machismo como limitante en la participación paterna en las labores de cuidado y crianza con l...

  7. Thermal variation of magnetization in Ni/V multilayers

    International Nuclear Information System (INIS)

    Benkirane, K.; Elkabil, R.; Hamdoun, A.; Lassri, M.; Abid, M.; Lassri, H.; Krishnan, R.

    2004-01-01

    The magnetic properties of Ni/V multilayers, prepared by the RF sputtering method, have been systematically studied by magnetic measurements. The magnetization decreases with a decrease in Ni layer thickness tNi and the analysis of the results at 5K indicates the presence of a dead Ni layer about 12A thick. The effective anisotropy Keff of Ni/V multilayers is obtained using a torque magnetometer. The interface contribution to the magnetic anisotropy is practically negligible. A spin-wave theory has been used to explain the temperature dependence of the magnetization and the approximate values for the bulk exchange interaction Jb, surface exchange interaction JS, and the interlayer coupling strength JI for various Ni layer thicknesses have been obtained

  8. Electrochemical deposition and characterization of Ni-Mo alloy powders

    Directory of Open Access Journals (Sweden)

    M.G. Pavlović

    2007-12-01

    Full Text Available Electrodeposition of Ni-Mo alloy powders from ammonium sulfate and ammonium chloride containing electrolytes of different Ni/Mo ions concentration ratios was investigated by polarization measurements. The morphology, chemical composition and phase composition of electrodeposited Ni-Mo alloy powders were investigated using DSC, TGA, SEM, EDS and XRD analysis. EDS results showed that powder composition depends on Ni/Mo ions concentration ratio, as well as on the position where the EDS analysis was performed. As-deposited alloy powders were nanocrystalline showing no XRD peaks with undefined morphology (SEM. After recrystallization for 2 h in N2 atmosphere at 600°C the presence of NiMoO4 phase was identified in the powder electrodeposited from chloride electrolyte at the Ni/Mo ions concentration ratio 1/3, with well defined crystalline powder particles.

  9. Effect of Polyethylene Glycol on the NiO Photocathode

    Science.gov (United States)

    Li, Shengjun; Chen, Zeng; Kong, Wenping; Jia, Xiyang; Cai, Junhao; Dong, Shaokang

    2017-08-01

    In this study, a uniform nanoporous NiO film, with a thickness of up to 2.6 μm, was prepared using polyethylene glycol (PEG). The addition of PEG significantly decreased the cracks in the NiO film and prevented the peeling of the NiO film from a fluorine-doped tin oxide substrate. The NiO cathode was prepared using CdSeS quantum dots (QDs) as the sensitizer, with an optimized photoelectric conversion of 0.80%. The optimized QD-sensitized NiO films were first assembled with the TiO2 anode to prepared QD-sensitized p-n-type tandem solar cells. The open circuit voltage was greater than that obtained using the separated NiO cathode or TiO2 anode.

  10. Diffusion studies in amorphous NiZr alloys

    International Nuclear Information System (INIS)

    Hahn, H.; Averback, R.S.; Hoshino, K.; Rothman, S.J.

    1987-06-01

    Tracer impurity and self diffusion measurements have been made on amorphous (a-) NiZr alloys using radioactive tracer, Secondary Ion Mass Spectrometry and Rutherford backscattering techniques. The temperature dependence of diffusion in a-NiZr can be represented in the form D = D 0 exp(-Q/kT), with no structural relaxation effects being observed. The mobility of an atom in a-NiZr increased dramatically with decreasing atomic radius of the diffusing atom and also with decreasing Ni content for Ni concentrations below ≅40 at. %. These diffusion characteristics in a-NiZr are remarkably similar to those in α-Zr and α-Ti. These mechanisms assume that Zr and Ti provide a close packed structure, either crystalline or amorphous, through which small atoms diffuse by an interstitial mechanism and large atoms diffuse by a vacancy mechanism. 12 refs., 2 figs., 2 tabs

  11. Equilibrium relationships in the system Ni-U-O

    International Nuclear Information System (INIS)

    Mansour, N.A.L.

    1980-01-01

    Phase relationships were established in air and in oxygen. Mixtures of NiO and U 3 O 8 oxidize to NiUO 4 . The results of analysis of NiUO 4 were identical to those previously published for NiU 3 O 10 . The uranate dissociates to NiO and U 3 O 8 at a temperature higher than that of their oxidation back to the uranate on cooling because of the difficulty of oxygen diffusion and uranate nucleation. Accordingly, dissociation temperature was taken to represent equilibrium and was used to calculate roughly ΔH and ΔS for the reaction of dissociation. In presence of NiO, U 3 O 8 melts partially and does not dissociate to the lower oxide. (orig.) [de

  12. Microstructure and martensitic transformation of Ni-Ti-Pr alloys

    Energy Technology Data Exchange (ETDEWEB)

    Zhao, Chunwang [Inner Mongolia University of Technology, College of Science, Hohhot (China); Shanghai Maritime University, College of Arts and Sciences, Shanghai (China); Zhao, Shilei; Jin, Yongjun; Hou, Qingyu [Inner Mongolia University of Technology, College of Science, Hohhot (China); Guo, Shaoqiang [Beihang University, Key Laboratory of Micro-nano Measurement, Manipulation and Physics (Ministry of Education), Department of Physics, Beijing (China)

    2017-09-15

    The effect of Pr addition on the microstructure and martensitic transformation behavior of Ni{sub 50}Ti{sub 50-x}Pr{sub x} (x = 0, 0.1, 0.3, 0.5, 0.7, 0.9) alloys were investigated experimentally. Results show that the microstructures of Ni-Ti-Pr alloys consist of the NiTi matrix and the NiPr precipitate with the Ti solute. The martensitic transformation start temperature decreases gradually with the increase in Pr fraction. The stress around NiPr precipitates is responsible for the decrease in martensitic transformation temperature with the increase in Pr fraction in Ni-Ti-Pr alloys. (orig.)

  13. Los niños y los videojuegos

    OpenAIRE

    Orrego Gaviria, Jaime; Fundación Valle de Lili

    2007-01-01

    Los niños y los videojuegos / Efectos perjudiciales de la utilización de los videojuegos por los niños y adolescentes/ Efectos benéficos de la de la utilización de los videojuegos por los niños y adolescentes/ Recomendaciones para favorecer el uso adecuado/ Sistema de clasificación de los videojuegos

  14. Electrochemical Characterization of Ni/(Sc)YSZ Electrodes

    DEFF Research Database (Denmark)

    Ramos, Tania; Thydén, Karl Tor Sune; Mogensen, Mogens Bjerg

    2010-01-01

    Investigations of Ni/(Sc)YSZ cermets for solid oxide cells (SOCs) were performed by electrochemical impedance spectroscopy (EIS), under varying experimental conditions and upon redox cycling, using three different designs of symmetric cells. The deconvolution and fitting of the obtained impedance...... parameters. Initial degradation results for both Ni/ScYSZ and Ni/YSZ based anodes under very high steam content are also reported. ©2010 COPYRIGHT ECS - The Electrochemical Society...

  15. NiAl-based Polyphase in situ Composites in the NiAl-Ta-X (X = Cr, Mo, or V) Systems

    Science.gov (United States)

    Johnson, D. R.; Oliver, B. F.; Noebe, R. D.; Whittenberger, J. D.

    1995-01-01

    Polyphase in situ composites were generated by directional solidification of ternary eutectics. This work was performed to discover if a balance of properties could be produced by combining the NiAl-Laves phase and the NiAl-refractory metal phase eutectics. The systems investigated were the Ni-Al-Ta-X (X = Cr, Mo, or V) alloys. Ternary eutectics were found in each of these systems and the eutectic composition, temperature, and morphology were determined. The ternary eutectic systems examined were the NiAl-NiAlTa-(Mo, Ta), NiAl-(Cr, Al) NiTa-Cr, and the NiAl-NiAlTa-V systems. Each eutectic consists of NiAl, a C14 Laves phase, and a refractory metal phase. Directional solidification was performed by containerless processing techniques in a levitation zone refiner to minimize alloy contamination. Room temperature fracture toughness of these materials was determined by a four-point bend test. Preliminary creep behavior was determined by compression tests at elevated temperatures, 1100-l400 K. Of the ternary eutectics, the one in the NiAl-Ta-Cr system was found to be the most promising. The fracture toughness of the NiAl-(Cr, Al)NiTa-Cr eutectic was intermediate between the values of the NiAl-NiAlTa eutectic and the NiAl-Cr eutectic. The creep strength of this ternary eutectic was similar to or greater than that of the NiAl-Cr eutectic.

  16. Constitutional and thermal point defects in B2 NiAl

    DEFF Research Database (Denmark)

    Korzhavyi, P. A.; Ruban, Andrei; Lozovoi, A. Y.

    2000-01-01

    . The theory correctly reproduces the ground state for the off-stoichiometric NiAl alloys. The constitutional defects (antisite Ni atoms and Ni vacancies in Ni-rich and Al-rich NiAl, respectively) are shown to form ordered structures in the ground state, in which they tend to avoid each other at the shortest...

  17. Comparison of three Ni-Hard I alloys

    Energy Technology Data Exchange (ETDEWEB)

    Dogan, Omer N.; Hawk, Jeffrey A.; Rice, J. (Texaloy Foundry Co., Inc., Floresville, Texas)

    2004-09-01

    This report documents the results of an investigation which was undertaken to reveal the similarities and differences in the mechanical properties and microstructural characteristics of three Ni-Hard I alloys. One alloy (B1) is ASTM A532 class IA Ni-Hard containing 4.2 wt. pct. Ni. The second alloy (B2) is similar to B1 but higher in Cr, Si, and Mo. The third alloy (T1) also falls in the same ASTM specification, but it contains 3.3 wt. pct. Ni. The alloys were evaluated in both as-cast and stress-relieved conditions except for B2, which was evaluated in the stress-relieved condition only. While the matrix of the high Ni alloys is composed of austenite and martensite in both conditions, the matrix of the low Ni alloy consists of a considerable amount of bainite, in addition to the martensite and the retained austenite in as cast condition, and primarily bainite, with some retained austenite, in the stress relieved condition. It was found that the stress relieving treatment does not change the tensile strength of the high Ni alloy. Both the as cast and stress relieved high Ni alloys had a tensile strength of about 350 MPa. On the other hand, the tensile strength of the low Ni alloy increased from 340 MPa to 452 MPa with the stress relieving treatment. There was no significant difference in the wear resistance of these alloys in both as-cast and stressrelieved conditions.

  18. Positron annihilation in the aging alloy Ti49Ni51

    International Nuclear Information System (INIS)

    Baturin, A.A.; Grishkov, V.N.; Lotkov, A.I.

    2002-01-01

    The processes of low temperature aging in alloy Ti 49 Ni 51 at temperatures of 443 and 523 K are investigated using the method of angular correlation of annihilation irradiation. The distinction of positron behaviour in aging TiNi base alloys from that in aging solid solutions on the basis of unalloyed metals is the positron location in type (0001) plane of Ti 3 Ni 4 phase structure which consist practically of nickel atoms only. As this taken place, the parameters of angular correlation spectra are defined by chemical composition of these layers depending on Ti and Ni atoms redistribution between neighboring layers [ru

  19. Oxidation of hydrogen peroxide by [Ni III (cyclam)

    Indian Academy of Sciences (India)

    The kinetics of oxidation of H2O2 by [NiIII(cyclam)]3+, [NiIIIL1], was studied in aqueous acidic media at 25°C and I = 0.5M (NaClO4). The [NiIIIL1] to [NiIIL1] reduction was found to be fast in the presence of Cu(II) ion than the oxidation of the cyclam ligand by ·OH. The rate constant showed an inverse acid dependence on H+ ...

  20. CVD Graphene/Ni Interface Evolution in Sulfuric Electrolyte

    DEFF Research Database (Denmark)

    Yivlialin, Rossella; Bussetti, Gianlorenzo; Duò, Lamberto

    2018-01-01

    Systems comprising single and multilayer graphene deposited on metals and immersed in acid environments have been investigated, with the aim of elucidating the mechanisms involved, for instance, in hydrogen production or metal protection from corrosion. In this work, a relevant system, namely...... chemical vapor deposited (CVD) multilayer graphene/Ni (MLGr/Ni), is studied when immersed in a diluted sulfuric electrolyte. The MLGr/Ni electrochemical and morphological properties are studied in situ and interpreted in light of the highly oriented pyrolytic graphite (HOPG) electrode behavior, when...... immersed in the same electrolyte. Following this interpretative framework, the dominant role of the Ni substrate in hydrogen production is clarified....

  1. Ion Ni2+ di Dalam Air; Pembentukan Fungsi Potensial Intermolekul

    Directory of Open Access Journals (Sweden)

    Bambang Setiaji

    2010-06-01

    Full Text Available Pair potential function of Ni2+-H2O system has been constructed by ab initio method at UHF (Unrestricted Hartre-Fock level. The basis sets used for energy interaction calculation were LANL2 Double-z ECP of Hay and Wadt for Ni2+ and Double-z Polarization of Dunning for H2O. Construction of pair potential function was done by collecting more than 3000 energy points that represent all interactions of Ni2+ ion and water. The pair potential function of Ni2+-H2O resulted of fitting proses by standard deviation of 3,25 kcal/mol is where AiM, BiM, CiM  and DiM are fitting parameter of Ni2+-O or Ni2+-H, riM is distance of i atoms between H2O and Ni2+, q is charge of i atoms of H2O resulted by Mulliken population analysis, and qM is net charge of Ni2+ ion.   Keywords: Ni2+ ion in water, intermoleculer potential function.

  2. An investigation of the oxidized Ni/InAs interface

    Energy Technology Data Exchange (ETDEWEB)

    Venter, A., E-mail: andre.venter@nmmu.ac.z [Department of Physics, Nelson Mandela Metropolitan University, PO Box 77000, Port Elizabeth 6031 (South Africa); Botha, J.R. [Department of Physics, Nelson Mandela Metropolitan University, PO Box 77000, Port Elizabeth 6031 (South Africa); Swart, H.C. [Department of Physics, University of the Free State, PO Box 339, Bloemfontein 9300 (South Africa); Naidoo, S.; Olivier, E.J. [Department of Physics, Nelson Mandela Metropolitan University, PO Box 77000, Port Elizabeth 6031 (South Africa)

    2009-12-01

    Ni was resistively deposited onto bulk InAs and subsequently oxidized in an O{sub 2} atmosphere. The anneal temperature and time were 450 deg. C and 2.5 h, respectively. X-ray diffraction of the oxidized Ni/InAs sample revealed the formation of In{sub 3}Ni{sub 2} and In{sub 2}O{sub 3} on the front suggesting inter diffusion of In, Ni and O. NiO was not detected by X-ray diffraction. In a preliminary study, using glass as a substrate, NiO readily formed when using these oxidation parameters. Conductivity measurements of the oxidized Ni/InAs surface revealed a conducting front and insulating rear surface while TEM of the Ni/InAs interface revealed an intermediate amorphous diffusion zone between the 'oxidized' Ni layer and the bulk InAs. A closer investigation of the intermediate layer supports the X-ray diffraction results, suggesting compound formation due to diffusion of oxygen and nickel into the substrate, and out-diffusion of In and As from the bulk of the sample. AES was used to further elucidate these results.

  3. Stress corrosion cracking of NiTi in artificial saliva.

    Science.gov (United States)

    Wang, Jianqiu; Li, Nianxing; Rao, Guangbin; Han, En-Hou; Ke, Wei

    2007-02-01

    This paper aimed to study the mechanism of the cracking of orthodontic NiTi wire. Two orthodontic NiTi wires were subjected: (1) optical and scanning electron microscopy (SEM) to observe the fracture surface; (2) energy dispersive X-ray spectroscopy to determine the composition of the surface product; (3) anodic polarization to remove the surface product. Samples of NiTi alloy were subjected to the constant loading test to study the stress corrosion cracking (SCC) behavior of NiTi shape memory alloy in artificial saliva. The results showed that there were three typical areas at the fracture surface of NiTi orthodontic wire. Area '1' was a tool-made notch. Crack initiated from the root of this notch and propagated to form Area '2', which was perpendicular to the wire axis and covered by surface film. This film consisted of Na, K, Cl, P, S and O except Ni and Ti. The cracking process of NiTi alloy under the constant loading test depended on the pH of saliva and applied stress. The crack length was about 262microm, the longest at 300MPa and pH 3.0. A tool-made notch in orthodontic NiTi wires can cause SCC. At high stress and low pH, this NiTi alloy was most sensitive to cracking.

  4. Microstructural Investigations On Ni-Ta-Al Ternary Alloys

    International Nuclear Information System (INIS)

    Negache, M.; Taibi, K.; Lounis, Z.; Souami, N.

    2010-01-01

    The Ni-Al-Ta ternary alloys in the Ni-rich part present complex microstructures. They are composed of multiple phases that are formed according to the nominal composition of the alloy, primary Ni(γ), Ni 3 Al(γ'), Ni 6 AlTa(τ 3 ), Ni 3 Ta(δ) or in equilibrium: two solid phases (γ'-τ 3 ), (τ 3 -δ), (τ 3 -γ), (γ-δ) or three solid phases (γ'-τ 3 -δ). The nature and the volume fraction of these phases give these alloys very interesting properties at high temperature, and this makes them attractive for specific applications. We have developed a series of ternary alloys in electric arc furnace, determining their solidification sequences using Differential Thermal Analysis (DTA), characterized by SEM-EDS, X-ray diffraction and by a microhardness tests. The follow-up results made it possible to make a correlation between the nature of the formed phases and their solidifying way into the Ni 75 Al x Ta y (x+y = 25at.%) system, which are varied and complex. In addition to the solid solution Ni (γ), the formed intermetallics compounds (γ', τ 3 and δ) has been identified and correlated with a complex balance between phases.We noticed that the hardness increases with the tantalum which has a hardening effect and though the compound Ni 3 Ta(δ) is the hardest. The below results provide a better understanding of the complex microstructure of these alloys.

  5. Level density of radioactive doubly-magic nucleus 56Ni

    International Nuclear Information System (INIS)

    Santhosh Kumar, S.; Rengaiyan, R.; Victor Babu, A.; Preetha, P.

    2012-01-01

    In this work the single particle energies are obtained by diagonalising the Nilsson Hamiltonian in the cylindrical basis and are generated up to N =11 shells for the isotopes of Ni from A = 48-70, emphasizing the three magic nuclei viz, 48 Ni, 56 Ni and 68 Ni. The statistical quantities like excitation energy, level density parameter and nuclear level density which play the important roles in the nuclear structure and nuclear reactions can be calculated theoretically by means of the Statistical or Partition function method. Hence the statistical model approach is followed to probe the dynamical properties of the nucleus in the microscopic level

  6. Ni cycling in mangrove sediments from New Caledonia

    Science.gov (United States)

    Noël, Vincent; Morin, Guillaume; Juillot, Farid; Marchand, Cyril; Brest, Jessica; Bargar, John R.; Muñoz, Manuel; Marakovic, Grégory; Ardo, Sandy; Brown, Gordon E.

    2015-11-01

    Covering more than 70% of tropical and subtropical coastlines, mangrove intertidal forests are well known to accumulate potentially toxic trace metals in their sediments, and thus are generally considered to play a protective role in marine and lagoon ecosystems. However, the chemical forms of these trace metals in mangrove sediments are still not well known, even though their molecular-level speciation controls their long-term behavior. Here we report the vertical and lateral changes in the chemical forms of nickel, which accumulates massively in mangrove sediments downstream from lateritized ultramafic deposits from New Caledonia, where one of nature's largest accumulations of nickel occurs. To accomplish this we used Ni K-edge Extended X-ray Absorption Fine Structure (EXAFS) spectroscopy data in combination with microscale chemical analyses using Scanning Electron Microscopy coupled with Energy-Dispersive X-ray Spectroscopy (SEM-EDXS). After Principal Component and Target Transform analyses (PCA-TT), the EXAFS data of the mangrove sediments were reliably least-squares fitted by linear combination of 3-components chosen from a large model compound spectral database including synthetic and natural Ni-bearing sulfides, clay minerals, oxyhydroxides, and organic complexes. Our results show that in the inland salt flat Ni is hosted in minerals inherited from the eroded lateritic materials, i.e. Ni-poor serpentine (44-58%), Ni-rich talc (20-31%), and Ni-goethite (18-24%). In contrast, in the hydromorphic sediments beneath the vegetated Avicennia and Rhizophora stands, a large fraction of Ni is partly redistributed into a neoformed smectite pool (20-69% of Ni-montmorillonite), and Ni speciation significantly changes with depth in the sediment. Indeed, Ni-rich talc (25-56%) and Ni-goethite (15-23%) disappear below ∼15 cm depth in the sediment and are replaced by Ni-sorbed pyrite (23-52%) in redox-active intermediate depth layers and by pyrite (34-55%) in the deepest

  7. Interacción familiar y desarrollo emocional en niños y niñas

    OpenAIRE

    Gloria Cecilia Henao López; María Cristina García Vesga

    2009-01-01

    En la presente investigación se tuvo como objetivo principal abordar los estilos de interacción de padres y madres de niños y niñas preescolares y su relación con el desarrollo emocional de sus hijos e hijas (235 niños y 169 niñas) entre cinco y seis años de edad. Las dimensiones que se consideraron para evaluar el nivel emocional de los niños y niñas fueron: autorregulación, comprensión emocional, y empatía. Como primer aspecto describimos los tipos de interacción con sus hijos e hijas y el ...

  8. Comparative study of NiW, NiMo and MoW prepared by mechanical alloying

    International Nuclear Information System (INIS)

    Gonzalez, G.; Sagarzazu, A.; Villalba, R.; Ochoa, J.

    2007-01-01

    The present work concern the amorphisation process induced by mechanical alloying in the NiW, NiMo and MoW systems. The alloys chosen combine a group of transition elements varying from very similar atomic radius and electronic valences (MoW) to different ones (NiW and NiMo). The three systems achieved an amorphous state after 50 h of milling. The mechanism of amorphisation proposed for NiW and NiMo was the combined effect of an excess concentration of the solute atoms entering into the structure of one of the elements and a critical concentration of defects. Continuous formation of an amorphous phase at the interface of the crystalline phase was observed during the process. MoW seems to amorphize by continuous reduction of grain size down to a critical value where the amorphisation takes place

  9. The irradiation hardening of Ni-Mo-Cr and Ni-W-Cr alloy under Xe26+ ion irradiation

    Science.gov (United States)

    Chen, Huaican; Hai, Yang; Liu, Renduo; Jiang, Li; Ye, Xiang-xi; Li, Jianjian; Xue, Wandong; Wang, Wanxia; Tang, Ming; Yan, Long; Yin, Wen; Zhou, Xingtai

    2018-04-01

    The irradiation hardening of Ni-Mo-Cr and Ni-W-Cr alloy was investigated. 7 MeV Xe26+ ion irradiation was performed at room temperature and 650 °C with peak damage dose from 0.05 to 10 dpa. With the increase of damage dose, the hardness of Ni-Mo-Cr and Ni-W-Cr alloy increases, and reaches saturation at damage dose ≥1 dpa. Moreover, the damage dose dependence of hardness in both alloys can be described by the Makin and Minter's equation, where the effective critical volume of obstacles can be used to represent irradiation hardening resistance of the alloys. Our results also show that Ni-W-Cr alloy has better irradiation hardening resistance than Ni-Mo-Cr alloy. This is ascribed to the fact that the W, instead of Mo in the alloy, can suppress the formation of defects under ion irradiation.

  10. Fiscal 1993 international research cooperation project. Feasibility study of finding out the seeds of international joint research (technology for environmental preservation using biotechnology, technology for effective use unused hydrocarbon resource, technology of solid electrolyte fuel cells for high-efficient electric vehicles); 1993 nendo kokusai kenkyu kyoryoku jigyo. Kokusai kyodo kenkyu seeds hakkutsu no tame no FS chosa (biotechnology ni yoru kankyo taisaku gijutsu, miriyo tanka suiso shigen no yuko riyo gijutsu, kokoritsu denki jidosha no kotai denkaishitsu nenryo denchi gijutsu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-03-01

    This project is aimed at internationally cooperating in the R and D of industrial technology and improving industrial technology of Japan. For it, the following three technologies were investigated: 1) environmental preservation technology using biotechnology, 2) technology for effective use of unused hydrocarbon resource, 3) solid electrolyte fuel cell (SOFC) technology for high-efficient electric vehicles. In 1), bio-remediation is a choice as the result of trially using technologies for remediation of the environment polluted by pollutant, but it is not a technically completed one, but one which will be improved by trial and error. By the application of gene engineering, the use of gene recombination enables wide spread of decomposition genes. In 2), technical subjects were studied such as superheavy distillate, oil shale, coalhead methane and methane hydrate. In 3), designed were cylinder type and planar type SOFC of 850degC operation and 10kW output. Accumulation and weight of a total SOFC system are 81 liters and 100 kg in cylinder type and 136 liters and 200 kg in planar type. The vehicle can be equipped with the SOFC. 171 refs., 72 figs., 54 tabs.

  11. Hydride Reactivity of Ni-II-X-Ni-II Entities : Mixed-Valent Hydrido Complexes and Reversible Metal Reduction

    NARCIS (Netherlands)

    Gehring, Henrike; Metzinger, Ramona; Herwig, Christian; Intemann, Julia; Harder, Sjoerd; Limberg, Christian

    After the lithiation of PYR-H2 (PYR2-=[{NC(Me)C(H)C(Me)NC6H3(iPr)2}2(C5H3N)]2-), which is the precursor of an expanded beta-diketiminato ligand system with two binding pockets, its reaction with [NiBr2(dme)] led to a dinuclear nickel(II)bromide complex, [(PYR)Ni(mu-Br)NiBr] (1). The bridging bromide

  12. Viviendo con VIH/SIDA: Las voces ocultas de los niños y niñas afectados

    Directory of Open Access Journals (Sweden)

    Luz Adriana Aristizábal Becerra

    2012-01-01

    Full Text Available El VIH/SIDA no es solamente un problema de salud, sino también un problema social. Los primeros casos de VIH/SIDA en niños se describen en 1982 en Estados Unidos, y desde entonces el número de niños infectados y afectados continúa incrementándose, hasta convertirse en lo que en la actualidad se denota como una pandemia. Objetivo. Posibilitar un espacio para que los niños y niñas afectados por el VIH/SIDA, puedan expresar sus vivencias en torno al padecimiento propio y/o de sus padres. Metodología. Estudio de enfoque cualitativo con una orientación fenomenológica. Participaron 29 niños (68 % y 13 niñas (32 % de 4 a 17 años, quienes fueron visitados en sus entornos hogareños. Para evitar la revictimización se utilizaron estrategias lúdicas y juegos para conocer las voces ocultas de estos infantes. Resultados: los hallazgos se agruparon en tres categorías: 1. La orfandad, 2. Rechazo social, estigma y discriminación y 3. Servicios de Salud, donde en cada una se percibe la vivencia subjetiva de cada niño y niña entrevistado(a. Conclusiones: el estigma que ha revestido al VIH/SIDA dificulta considerablemente el desarrollo pleno de los niños y niñas, obstaculizando su libre expresión y crecimiento. Sus voces siguen estando ausentes en las políticas públicas, es por ello que este estudio resaltó las vivencias de los niños y niñas expresadas desde sus propias voces.

  13. Effects of Ni content on nanocrystalline Fe–Co–Ni ternary alloys synthesized by a chemical reduction method

    Energy Technology Data Exchange (ETDEWEB)

    Chokprasombat, Komkrich, E-mail: komkrich28@gmail.com [Department of Physics, Faculty of Science, Thaksin University, Phatthalung 93210 Thailand (Thailand); Pinitsoontorn, Supree [Integrated Nanotechnology Research Center, Department of Physics, Faculty of Science, Khon Kaen University, Khon Kaen 40002 Thailand (Thailand); Maensiri, Santi [School of Physics, Institute of Science, Suranaree University of Technology, Nakhon Ratchasima 30000 Thailand (Thailand)

    2016-05-01

    Magnetic properties of Fe–Co–Ni ternary alloys could be altered by changing of the particle size, elemental compositions, and crystalline structures. In this work, Fe{sub 50}Co{sub 50−x}Ni{sub x} nanoparticles (x=10, 20, 40, and 50) were prepared by the novel chemical reduction process. Hydrazine monohydrate was used as a reducing agent under the concentrated basic condition with the presence of poly(vinylpyrrolidone). We found that the nanoparticles were composed of Fe, Co and Ni with compositions according to the molar ratio of the metal sources. Interestingly, the particles were well-crystalline at the as-prepared state without post-annealing at high temperature. Increasing Ni content resulted in phase transformation from body centered cubic (bcc) to face centered cubic (fcc). For the fcc phase, the average particle size decreased when increased the Ni content; the Fe{sub 50}Ni{sub 50} nanoparticles had the smallest average size with the narrowest size distribution. In additions, the particles exhibited ferromagnetic properties at room temperature with the coercivities higher than 300 Oe, and the saturation magnetiation decreased with increasing Ni content. These results suggest that the structural and magnetic properties of Fe–Co–Ni alloys could be adjusted by varying the Ni content. - Highlights: • We prepared nanocrystalline Fe–Co–Ni alloys by a novel chemical reduction process. • Elemental compositions could be well controlled by the molar ratio of metal sources. • Particle size and magnetic properties clearly depended on the Ni contents. • Fe{sub 50}Co{sub 10}Ni{sub 40} exhibited high saturation magnetization of 126.3 emu/g.

  14. Experimental study of the $^{66}$Ni$(d,p)^{67}$Ni one-neutron transfer reaction

    CERN Document Server

    Diriken, J.; Andreyev, A.N.; Antalic, S.; Bildstein, V.; Blazhev, A.; Darby, I.G.; De Witte, H.; Eberth, J.; Elseviers, J.; Fedosseev, V.N.; Flavigny, F.; Fransen, Ch.; Georgiev, G.; Gernhauser, R.; Hess, H.; Huyse, M.; Jolie, J.; Kröll, Th.; Krücken, R.; Lutter, R.; Marsh, B.A.; Mertzimekis, T.; Muecher, D.; Orlandi, R.; Pakou, A.; Raabe, R.; Randisi, G.; Reiter, P.; Roger, T.; Seidlitz, M.; Seliverstov, M.; Sotty, C.; Tornqvist, H.; Van De Walle, J.; Van Duppen, P.; Voulot, D.; Warr, N.; Wenander, F.; Wimmer, K.

    2015-01-01

    The quasi-SU(3) sequence of the positive parity $νg_{9/2}, d_{5/2}, s_{1/2}$ orbitals above the N=40 shell gap are assumed to induce strong quadrupole collectivity in the neutron-rich Fe (Z=26) and Cr (Z=24) isotopes below the nickel region. In this paper the position and strength of these single-particle orbitals are characterized in the neighborhood of $^{68}$Ni (Z=28,N=40) through the $^{66}$Ni($d,p$)$^{67}$Ni one-neutron transfer reaction at 2.95 MeV/nucleon in inverse kinematics, performed at the REX-ISOLDE facility in CERN. A combination of the Miniball $\\gamma$-array and T-REX particle-detection setup was used and a delayed coincidence technique was employed to investigate the 13.3-$\\mu$s isomer at 1007 keV in $^{67}$Ni. Excited states up to an excitation energy of 5.8 MeV have been populated. Feeding of the $νg_{9/2}$ (1007 keV) and $νd_{5/2}$ (2207 keV and 3277 keV) positive-parity neutron states and negative parity ($νpf$) states have been observed at low excitation energy. The extracted relativ...

  15. Transformation dynamics of Ni clusters into NiO rings under electron beam irradiation

    Energy Technology Data Exchange (ETDEWEB)

    Knez, Daniel, E-mail: daniel.knez@felmi-zfe.at [Institute of Electron Microscopy and Nanoanalysis, Graz University of Technology, Steyrergasse 17, 8010 Graz (Austria); Graz Centre for Electron Microscopy, Steyrergasse 17, 8010 Graz (Austria); Thaler, Philipp; Volk, Alexander [Institute of Experimental Physics, Graz University of Technology, Petersgasse 16, 8010 Graz (Austria); Kothleitner, Gerald [Institute of Electron Microscopy and Nanoanalysis, Graz University of Technology, Steyrergasse 17, 8010 Graz (Austria); Graz Centre for Electron Microscopy, Steyrergasse 17, 8010 Graz (Austria); Ernst, Wolfgang E. [Institute of Experimental Physics, Graz University of Technology, Petersgasse 16, 8010 Graz (Austria); Hofer, Ferdinand [Institute of Electron Microscopy and Nanoanalysis, Graz University of Technology, Steyrergasse 17, 8010 Graz (Austria); Graz Centre for Electron Microscopy, Steyrergasse 17, 8010 Graz (Austria)

    2017-05-15

    We report the transformation of nickel clusters into NiO rings by an electron beam induced nanoscale Kirkendall effect. High-purity nickel clusters consisting of a few thousand atoms have been used as precursors and were synthesized with the superfluid helium droplet technique. Aberration-corrected, analytical scanning transmission electron microscopy was applied to oxidise and simultaneously analyse the nanostructures. The transient dynamics of the oxidation could be documented by time lapse series using high-angle annular dark-field imaging and electron energy-loss spectroscopy. A two-step Cabrera-Mott oxidation mechanism was identified. It was found that water adsorbed adjacent to the clusters acts as oxygen source for the electron beam induced oxidation. The size-dependent oxidation rate was estimated by quantitative EELS measurements combined with molecular dynamics simulations. Our findings could serve to better control sample changes during examination in an electron microscope, and might provide a methodology to generate other metal oxide nanostructures. - Highlights: • Beam induced conversion of Ni clusters into crystalline NiO rings has been observed. • Ni clusters were grown with the superfluid He-droplet technique. • oxidizeSTEM was utilized to investigate and simultaneously oxidize these clusters. • Oxidation dynamics was captured in real-time. • Cluster sizes and the oxidation rate were estimated via EELS and molecular dynamics.

  16. The Ni-rich Part of the Ni-P-Sn System: Isothermal Sections

    Czech Academy of Sciences Publication Activity Database

    Schmetterer, C.; Vízdal, J.; Kroupa, Aleš; Kodentsov, A.; Ipser, H.

    2009-01-01

    Roč. 38, č. 11 (2009), s. 2275-2300 ISSN 0361-5235 R&D Projects: GA MŠk(CZ) OC08053 Institutional research plan: CEZ:AV0Z20410507 Keywords : lead free solder * phase diagram * Ni-P-Sn Subject RIV: BJ - Thermodynamics Impact factor: 1.428, year: 2009

  17. Influence of Ni on martensitic phase transformations in NiTi

    Czech Academy of Sciences Publication Activity Database

    Frenzel, J.; George, E.P.; Dlouhý, Antonín; Somsen, Ch.; Wagner, M.F.-X.; Eggeler, G.

    2010-01-01

    Roč. 58, č. 9 (2010), s. 3444-3458 ISSN 1359-6454 R&D Projects: GA ČR GA106/09/1913 Institutional research plan: CEZ:AV0Z20410507 Keywords : NiTi shape memory alloys * Phase transformation temperatures * Thermodynamics * Vacuum arc melting Subject RIV: JJ - Other Materials Impact factor: 3.781, year: 2010

  18. Performance and Structure of LiNi Mn O Prepared from Various Ni ...

    African Journals Online (AJOL)

    NJD

    Various Ni Precursors for Lithium Ion Batteries. Zhaoyong Chena, Shan Jib*, Huali Zhua, Sivakumar .... Z. Chen, S. Ji, H. Zhu, S. Pasupathi, B. Bladergroen and V. Linkov,. 157. S. Afr. J. Chem., 2008, 61, 157–161, ... 1 mol L–1 LiPF6 solution in an ethylene carbonate (EC) and dimethyl carbonate (DMC) mixed solvent (1:1 ...

  19. Residual stress in Ni-W electrodeposits

    DEFF Research Database (Denmark)

    Mizushima, Io; Tang, Peter Torben; Hansen, Hans Nørgaard

    2006-01-01

    In the present work, the residual stress in Ni–W layers electrodeposited from electrolytes based on NiSO4 and Na2WO4, is investigated. Citrate, glycine and triethanolamine were used as complexing agents, enabling complex formation between the nickel ion and tungstate. The results show that the type...... of complexing agent and the current efficiency have an influence on the residual stress. In all cases, an increase in tensile stress in the deposit with time after deposition was observed. Pulse plating could improve the stress level for the electrolyte containing equal amounts of citrate...

  20. Anomalous Hall effect in polycrystalline Ni films

    KAUST Repository

    Guo, Zaibing

    2012-02-01

    We systematically studied the anomalous Hall effect in a series of polycrystalline Ni films with thickness ranging from 4 to 200 nm. It is found that both the longitudinal and anomalous Hall resistivity increased greatly as film thickness decreased. This enhancement should be related to the surface scattering. In the ultrathin films (46 nm thick), weak localization corrections to anomalous Hall conductivity were studied. The granular model, taking into account the dominated intergranular tunneling, has been employed to explain this phenomenon, which can explain the weak dependence of anomalous Hall resistivity on longitudinal resistivity as well. © 2011 Elsevier Ltd. All rights reserved.

  1. Photoelectrochemical Water Splitting Properties of Ti-Ni-Si-O Nanostructures on Ti-Ni-Si Alloy.

    Science.gov (United States)

    Li, Ting; Ding, Dongyan; Dong, Zhenbiao; Ning, Congqin

    2017-10-31

    Ti-Ni-Si-O nanostructures were successfully prepared on Ti-1Ni-5Si alloy foils via electrochemical anodization in ethylene glycol/glycerol solutions containing a small amount of water. The Ti-Ni-Si-O nanostructures were characterized by field-emission scanning electron microscopy (FE-SEM), energy dispersive spectroscopy (EDS), X-ray diffraction (XRD), and diffuse reflectance absorption spectra. Furthermore, the photoelectrochemical water splitting properties of the Ti-Ni-Si-O nanostructure films were investigated. It was found that, after anodization, three different kinds of Ti-Ni-Si-O nanostructures formed in the α-Ti phase region, Ti₂Ni phase region, and Ti₅Si₃ phase region of the alloy surface. Both the anatase and rutile phases of Ti-Ni-Si-O oxide appeared after annealing at 500 °C for 2 h. The photocurrent density obtained from the Ti-Ni-Si-O nanostructure photoanodes was 0.45 mA/cm² at 0 V (vs. Ag/AgCl) in 1 M KOH solution. The above findings make it feasible to further explore excellent photoelectrochemical properties of the nanostructure-modified surface of Ti-Ni-Si ternary alloys.

  2. Ni ion release, osteoblast-material interactions, and hemocompatibility of hafnium-implanted NiTi alloy.

    Science.gov (United States)

    Zhao, Tingting; Li, Yan; Zhao, Xinqing; Chen, Hong; Zhang, Tao

    2012-04-01

    Hafnium ion implantation was applied to NiTi alloy to suppress Ni ion release and enhance osteoblast-material interactions and hemocompatibility. The auger electron spectroscopy, x-ray photoelectron spectroscopy, and atomic force microscope results showed that a composite TiO(2)/HfO(2) nanofilm with increased surface roughness was formed on the surface of NiTi, and Ni concentration was reduced in the superficial surface layer. Potentiodynamic polarization tests displayed that 4 mA NiTi sample possessed the highest E(br) - E(corr), 470 mV higher than that of untreated NiTi, suggesting a significant improvement on pitting corrosion resistance. Inductively coupled plasma mass spectrometry tests during 60 days immersion demonstrated that Ni ion release rate was remarkably decreased, for example, a reduction of 67% in the first day. The water contact angle increased and surface energy decreased after Hf implantation. Cell culture and methyl-thiazol-tetrazolium indicated that Hf-implanted NiTi expressed enhanced osteoblasts adhesion and proliferation, especially after 7 days culture. Hf implantation decreased fibrinogen adsorption, but had almost no effect on albumin adsorption. Platelets adhesion and activation were suppressed significantly (97% for 4 mA NiTi) and hemolysis rate was decreased by at least 57% after Hf implantation. Modified surface composition and morphology and decreased surface energy should be responsible for the improvement of cytocompatibility and hemocompatibility. Copyright © 2011 Wiley Periodicals, Inc.

  3. Viviendo con VIH/SIDA: Las voces ocultas de los niños y niñas afectados

    OpenAIRE

    Luz Adriana Aristizábal Becerra

    2012-01-01

    El VIH/SIDA no es solamente un problema de salud, sino también un problema social. Los primeros casos de VIH/SIDA en niños se describen en 1982 en Estados Unidos, y desde entonces el número de niños infectados y afectados continúa incrementándose, hasta convertirse en lo que en la actualidad se denota como una pandemia. Objetivo. Posibilitar un espacio para que los niños y niñas afectados por el VIH/SIDA, puedan expresar sus vivencias en torno al padecimiento propio y/o de sus padres. Metodol...

  4. Amorphous NiFe-OH/NiFeP Electrocatalyst Fabricated at Low Temperature for Water Oxidation Applications

    KAUST Repository

    Liang, Hanfeng

    2017-04-11

    Water splitting driven by electricity or sunlight is one of the most promising ways to address the global terawatt energy needs of future societies; however, its large-scale application is limited by the sluggish kinetics of the oxygen evolution reaction (OER). NiFe-based compounds, mainly oxides and hydroxides, are well-known OER catalysts and have been intensively studied; however, the utilization of the synergistic effect between two different NiFe-based materials to further boost the OER performance has not been achieved to date. Here, we report the rapid conversion of NiFe double hydroxide into metallic NiFeP using PH3 plasma treatment and further construction of amorphous NiFe hydroxide/NiFeP/Ni foam as efficient and stable oxygen-evolving anodes. The strong electronic interactions between NiFe hydroxide and NiFeP significantly lower the adsorption energy of H2O on the hybrid and thus lead to enhanced OER performance. As a result, the hybrid catalyst can deliver a geometrical current density of 300 mA cm–2 at an extremely low overpotential (258 mV, after ohmic-drop correction), along with a small Tafel slope of 39 mV decade–1 and outstanding long-term durability in alkaline media.

  5. Streptococcus mutans adhesion on nickel titanium (NiTi) and copper-NiTi archwires: A comparative prospective clinical study.

    Science.gov (United States)

    Abraham, Kirubaharan S; Jagdish, Nithya; Kailasam, Vignesh; Padmanabhan, Sridevi

    2017-05-01

    To compare the adhesion of Streptococcus mutans to nickel titanium (NiTi) and copper-NiTi (Cu-NiTi) archwires and to correlate the adhesion to surface characteristics (surface free energy and surface roughness) of these wires. A total of 16 patients undergoing orthodontic treatment with preadjusted edgewise appliances were included in the study. 0.016" and 0.016" × 0.022" NiTi and Cu-NiTi archwires in as-received condition and after 4 weeks of intraoral use were studied for S mutans adhesion using real-time polymerase chain reaction. Surface roughness and surface free energy were studied by three-dimensional surface profilometry and dynamic contact angle analysis, respectively. S mutans adhesion was more in Cu-NiTi archwires. These wires exhibited rougher surface and higher surface free energy when compared to NiTi archwires. S mutans adhesion, surface roughness, and surface free energy were greater in Cu-NiTi than NiTi archwires. Surface roughness and surface free energy increased after 4 weeks of intraoral exposure for all of the archwires studied. A predominantly negative correlation was seen between the cycle threshold value of adherent bacteria and surface characteristics.

  6. Enhanced photocatalytic efficiency in zirconia buffered n-NiO/p-NiO single crystalline heterostructures by nanosecond laser treatment

    Energy Technology Data Exchange (ETDEWEB)

    Molaei, R.; Bayati, M. R.; Alipour, H. M.; Nori, S.; Narayan, J. [Department of Materials Science and Engineering, NC State University, EB-1, Raleigh, North Carolina 27695-7907 (United States)

    2013-06-21

    We report the formation of NiO based single crystalline p-n junctions with enhanced photocatalytic activity induced by pulsed laser irradiation. The NiO epilayers were grown on Si(001) substrates buffered with cubic yttria-stabilized zirconia (c-YSZ) by using pulsed laser deposition. The NiO/c-YSZ/Si heterostructures were subsequently laser treated by 5 pulses of KrF excimer laser (pulse duration = 25 Multiplication-Sign 10{sup -9} s) at lower energies. Microstructural studies, conducted by X-ray diffraction ({theta}-2{theta} and {phi} techniques) and high resolution transmission electron microscope, showed a cube-on-cube epitaxial relationship at the c-YSZ/Si interface; the epitaxial relationship across the NiO/c-YSZ interface was established as NiO<111 > Double-Vertical-Line Double-Vertical-Line c-YSZ<001> and in-plane NiO<110> Double-Vertical-Line Double-Vertical-Line c-YSZ<100>. Electron microscopy studies showed that the interface between the laser annealed and the pristine region as well as the NiO/c-YSZ interface was atomically sharp and crystallographically continuous. The formation of point defects, namely oxygen vacancies and NiO, due to the coupling of the laser photons with the NiO epilayers was confirmed by XPS. The p-type electrical characteristics of the pristine NiO epilayers turned to an n-type behavior and the electrical conductivity was increased by one order of magnitude after laser treatment. Photocatalytic activity of the pristine (p-NiO/c-YSZ/Si) and the laser-annealed (n-NiO/p-NiO/c-YSZ/Si) heterostructures were assessed by measuring the decomposition rate of 4-chlorophenol under UV light. The photocatalytic reaction rate constants were determined to be 0.0059 and 0.0092 min{sup -1} for the as-deposited and the laser-treated samples, respectively. The enhanced photocatalytic efficiency was attributed to the suppressed charge carrier recombination in the NiO based p-n junctions and higher electrical conductivity. Besides, the oxygen vacancies

  7. Interacción familiar y desarrollo emocional en niños y niñas

    Directory of Open Access Journals (Sweden)

    Gloria Cecilia Henao López

    2009-01-01

    Full Text Available En la presente investigación se tuvo como objetivo principal abordar los estilos de interacción de padres y madres de niños y niñas preescolares y su relación con el desarrollo emocional de sus hijos e hijas (235 niños y 169 niñas entre cinco y seis años de edad. Las dimensiones que se consideraron para evaluar el nivel emocional de los niños y niñas fueron: autorregulación, comprensión emocional, y empatía. Como primer aspecto describimos los tipos de interacción con sus hijos e hijas y el desarrollo emocional de los niños y niñas evaluados. Un segundo aspecto que se abordó, es el de explorar las asociaciones entre el estilo de interacción familiar y el desarrollo emocional infantil. El instrumento utilizado dirigido a los padres y madres fue la Escala de Identificación de Prácticas Educativas Familiares (PEF, versión española realizada por Alonso y Román; a los niños y niñas les aplicamos la evaluación del desempeño emocional (EDEI, que se construye como parte de esta investigación. Se trabajó con una muestra de 404 niños y niñas, y sus respectivos padres y madres. Los resultados obtenidos en esta investigación resaltan el estilo equilibrado como generador de conductas adecuadas y adaptativas en el niño o niña, al igual que rescata este estilo como el que más posibilita el nivel de comprensión emocional en los niños y niñas de nuestro estudio.

  8. Pautas para fomentar la autoestima en niños y niñas con discapacidad motora

    OpenAIRE

    Yagüe Lobo, Delia

    2014-01-01

    El informe aborda las pautas de actuación necesarias para trabajar la autoestima en niños y niñas con discapacidad motora y, por ello, se proponen pautas a desarrollar en distintos ámbitos, tanto en el aula como en el hogar. Se facilitan diferentes propuestas de actuación para la intervención individualiza-da en un aula ordinaria. Las pautas de actuación se han organizado a partir de los com-ponentes de la autoestima. Las mismas van dirigidas a cualquier niño o niña con disca-pacidad motor...

  9. Photoelectrochemical Water Splitting Properties of Ti-Ni-Si-O Nanostructures on Ti-Ni-Si Alloy

    Directory of Open Access Journals (Sweden)

    Ting Li

    2017-10-01

    Full Text Available Ti-Ni-Si-O nanostructures were successfully prepared on Ti-1Ni-5Si alloy foils via electrochemical anodization in ethylene glycol/glycerol solutions containing a small amount of water. The Ti-Ni-Si-O nanostructures were characterized by field-emission scanning electron microscopy (FE-SEM, energy dispersive spectroscopy (EDS, X-ray diffraction (XRD, and diffuse reflectance absorption spectra. Furthermore, the photoelectrochemical water splitting properties of the Ti-Ni-Si-O nanostructure films were investigated. It was found that, after anodization, three different kinds of Ti-Ni-Si-O nanostructures formed in the α-Ti phase region, Ti2Ni phase region, and Ti5Si3 phase region of the alloy surface. Both the anatase and rutile phases of Ti-Ni-Si-O oxide appeared after annealing at 500 °C for 2 h. The photocurrent density obtained from the Ti-Ni-Si-O nanostructure photoanodes was 0.45 mA/cm2 at 0 V (vs. Ag/AgCl in 1 M KOH solution. The above findings make it feasible to further explore excellent photoelectrochemical properties of the nanostructure-modified surface of Ti-Ni-Si ternary alloys.

  10. Formation of nickel germanides from Ni layers with thickness below 10 nm

    Energy Technology Data Exchange (ETDEWEB)

    Jablonka, Lukas; Kubart, Tomas; Primetzhofer, Daniel; Abedin, Ahmad; Hellström, Per-Erik; Östling, Mikael; Jordan-Sweet, Jean; Lavoie, Christian; Zhang, Shi-Li; Zhang, Zhen

    2017-03-01

    The authors have studied the reaction between a Ge (100) substrate and thin layers of Ni ranging from 2 to 10 nm in thickness. The formation of metal-rich Ni5Ge3Ni5Ge3 was found to precede that of the monogermanide NiGe by means of real-time in situ x-ray diffraction during ramp-annealing and ex situ x-ray pole figure analyses for phase identification. The observed sequential growth of Ni5Ge3Ni5Ge3 and NiGe with such thin Ni layers is different from the previously reported simultaneous growth with thicker Ni layers. The phase transformation from Ni5Ge3Ni5Ge3 to NiGe was found to be nucleation-controlled for Ni thicknesses <5 nm<5 nm, which is well supported by thermodynamic considerations. Specifically, the temperature for the NiGe formation increased with decreasing Ni (rather Ni5Ge3Ni5Ge3) thickness below 5 nm. In combination with sheet resistance measurement and microscopic surface inspection of samples annealed with a standard rapid thermal processing, the temperature range for achieving morphologically stable NiGe layers was identified for this standard annealing process. As expected, it was found to be strongly dependent on the initial Ni thickness

  11. Synergetic interface between NiO/Ni3S2 nanosheets and carbon nanofiber as binder-free anode for highly reversible lithium storage

    Science.gov (United States)

    Jiang, Jialin; Ma, Chao; Yang, Yinbo; Ding, Jingjing; Ji, Hongmei; Shi, Shaojun; Yang, Gang

    2018-05-01

    A novel heterostructure of NiO/Ni3S2 nanoflake is synthesized and composited with carbon nanofibers (CNF) membrane. NiO/Ni3S2 nanoflakes are homogeneously dispersed in CNF network, herein, NiO/Ni3S2 like leaf and CNF like branch. Carbon nanofibers network efficiently prevents the pulverization and buffers the volume changes of NiO/Ni3S2, meanwhile, NiO/Ni3S2 nanoflakes through the conductive channels of carbon nanofibers own improved Li+ diffusion ability and structural stability. The capacity of NiO/Ni3S2/CNF reaches to 519.2 mA g-1 after 200 cycles at the current density of 0.5 A g-1 while NiO/Ni3S2 fades to 71 mAh g-1 after 40 cycles. Owing to the synergetic structure, the resultant binder-free electrode NiO/Ni3S2/carbon nanofibers shows an excellent reversible lithium storage capability.

  12. In situ synchrotron X-ray diffraction study of deformation behavior and load transfer in a Ti2Ni-NiTi composite

    Science.gov (United States)

    Zhang, Junsong; Liu, Yinong; Ren, Yang; Huan, Yong; Hao, Shijie; Yu, Cun; Shao, Yang; Ru, Yadong; Jiang, Daqiang; Cui, Lishan

    2014-07-01

    The deformation behavior and load transfer of a dual-phase composite composed of martensite NiTi embedded in brittle Ti2Ni matrices were investigated by using in situ synchrotron x-ray diffraction during compression. The composite exhibits a stage-wise deformation feature and a double-yielding phenomenon, which were caused by the interaction between Ti2Ni and NiTi with alternative microscopic deformation mechanism. No load transfer occurs from the soft NiTi dendrites to the hard Ti2Ni matrices during the pseudoplastic deformation (detwinning) of NiTi, which is significantly different from that previously reported in bulk metallic glasses matrices composites.

  13. Fabrication and Gas-Sensing Properties of Ni-Silicide/Si Nanowires

    OpenAIRE

    Hsu, Hsun-Feng; Chen, Chun-An; Liu, Shang-Wu; Tang, Chun-Kai

    2017-01-01

    Ni-silicide/Si nanowires were fabricated by atomic force microscope nano-oxidation on silicon-on-insulator substrates, selective wet etching, and reactive deposition epitaxy. Ni-silicide nanocrystal-modified Si nanowire and Ni-silicide/Si heterostructure multi-stacked nanowire were formed by low- and high-coverage depositions of Ni, respectively. The Ni-silicide/Si Schottky junction and Ni-silicide region were attributed high- and low-resistance parts of nanowire, respectively, causing the re...

  14. Immunoproteomic identification and characterization of Ni2+-regulated proteins implicates Ni2+in the induction of monocyte cell death.

    Science.gov (United States)

    Jakob, Annika; Mussotter, Franz; Ohnesorge, Stefanie; Dietz, Lisa; Pardo, Julian; Haidl, Ian D; Thierse, Hermann-Josef

    2017-03-16

    Nickel allergy is the most common cause of allergic reactions worldwide, with cutaneous and systemic effects potentially affecting multiple organs. Monocytes are precursors of not only macrophages but also dendritic cells, the most potent activators of nickel hypersensitivity. Monocytes are themselves important antigen-presenting cells, capable of nickel-specific T-cell activation in vivo and in vitro, in addition to being important for immediate innate immune inflammation. To elucidate early Ni 2+ -dependent inflammatory molecular mechanisms in human monocytes, a Ni 2+ -specific proteomic approach was applied. Quantitative two-dimensional (2D) differential gel electrophoresis and Delta2D software analyses coupled with matrix-assisted laser desorption/ionization mass spectrometry (MALDI-MS) revealed that Ni 2+ significantly regulated 56 protein species, of which 36 were analyzed by MALDI-MS. Bioinformatics analyses of all identified proteins resulted in Ni 2+ -associated functional annotation clusters, such as cell death, metal ion binding, and cytoskeletal remodeling. The involvement of Ni 2+ in the induction of monocyte cell death, but not T-cell death, was observed at Ni 2+ concentrations at or above 250 μM. Examination of caspase activity during Ni 2+ -mediated cell death revealed monocytic cell death independent of caspase-3 and -7 activity. However, confocal microscopy analysis demonstrated Ni 2+ -triggered cytoskeletal remodeling and nuclear condensation, characteristic of cellular apoptosis. Thus, Ni 2+ -specific peripheral blood mononuclear cell stimulation suggests monocytic cell death at Ni 2+ concentrations at or above 250 μM, and monocytic effects on immune regulation at lower Ni 2+ concentrations.

  15. Electrolytic deposition and corrosion resistance of Zn–Ni coatings ...

    Indian Academy of Sciences (India)

    Zn–Ni coatings were deposited under galvanostatic conditions on steel substrate (OH18N9). The influence of current density of deposition on the surface morphology, chemical and phase composition was investigated. The corrosion resistance of Zn–Ni coatings obtained at current density 10–25 mA cm-2 are measured, ...

  16. Optimization of process parameters for synthesis of silica–Ni ...

    Indian Academy of Sciences (India)

    Optimization of process parameters for synthesis of silica–Ni nanocomposite by design of experiment ... Sol–gel; Ni; design of experiments; nanocomposites. ... Jadavpur University, Kolkata 700 032, India; School of Material Science and Nano-Technology, Jadavpur University, Kolkata 700 032, India; Rustech Products Pvt.

  17. Structural, morphological, optical and opto-thermal properties of Ni ...

    Indian Academy of Sciences (India)

    The effect of Ni concentration on the structural, morphological, optical and pho- ... catalytic [3], solar cells [4], gas sensors [5] and transparent ..... larger wavelength. This phenomenon indicates that the opti- cal energy gap decreases with doping concentration. It is well. Figure 4. Transmission spectra of sprayed ZnO : Ni thin ...

  18. Solubility of sulfur in Fe-Cr-Ni alloys

    International Nuclear Information System (INIS)

    Bogolyubskij, S.D.; Petrova, E.F.; Rogov, A.I.; Shvartsman, L.A.

    1979-01-01

    The solubility of 35 S was determined in Fe-Cr-Ni alloys in the range of temperatures between 910 and 1050 deg C by the method of radiometric analysis. It was found that the solubility of sulfur increases with the concentration of chromium in alloys with 20% Ni

  19. Facile synthesis of monodisperse thermally immiscible Ag–Ni alloy ...

    Indian Academy of Sciences (India)

    Microscopic and spectroscopic studies confirmed dependence of the alloy composition on size of nanoparticles. In the presence of different ligands such as sodium citrate, polyvinyl alcohol and potassium carbonate a mixture of silver oxide and Ag–Ni ANPs was achieved. Stoichiometry of the Ag–Ni ANPs was also found to ...

  20. Violencia sexual contra hombres y niños

    OpenAIRE

    Russell, Wynne

    2007-01-01

    Es bien sabido que los conflictos armados y la violencia sexual contra las mujeres y las niñas suelen ir de la mano. Lo que no se conoce tanto es que los conflictos armados y sus secuelas también suponen un peligro sexual para los hombres y los niños.

  1. Sodium-dodecyl-sulphate-assisted synthesis of Ni nanoparticles ...

    Indian Academy of Sciences (India)

    Stabilized nickel nanoparticles (SNNPs) were prepared using Ni(acac) 2 (acac = acetylacetonate) via a simplesolvothermal method. The synthesis of the nickel nanoparticles was performed in the presence of sodium dodecyl sulphate(SDS) of different concentrations (mole ratios of SDS:Ni(acac) 2 = 1:1, 2:1 and 4:1), as the ...

  2. Sodium-dodecyl-sulphate-assisted synthesis of Ni nanoparticles ...

    Indian Academy of Sciences (India)

    2017-11-20

    Nov 20, 2017 ... Abstract. Stabilized nickel nanoparticles (SNNPs) were prepared using Ni(acac)2 (acac = acetylacetonate) via a simple solvothermal method. The synthesis of the nickel nanoparticles was performed in the presence of sodium dodecyl sulphate. (SDS) of different concentrations (mole ratios of SDS:Ni(acac)2 ...

  3. Nanostructured CdO-NiO composite for multifunctional applications

    Science.gov (United States)

    Karthik, K.; Dhanuskodi, S.; Gobinath, C.; Prabukumar, S.; Sivaramakrishnan, S.

    2018-01-01

    In this study, CdO, NiO, and CdO-NiO nanocomposites (NCs) were synthesized and investigated by X-ray diffraction (XRD), scanning electron microscopy, and Fourier transform-infrared spectroscopy. XRD detected cubic structures with average crystallite sizes of 45 nm for CdO, 25 nm for NiO, and 30 nm for CdO-NiO. The band gap was estimated based on the ultraviolet-visible spectra. The near band edge emission was determined according to the luminescence spectrum. The antibacterial activities were tested against seven foodborne pathogens and the zones of inhibition with the Gram-negative bacterium Bacillus subtilis measured as 30 mm with CdO, 20 mm NiO, and 27 mm with CdO-NiO. The death of the bacterial cells was confirmed by confocal laser scanning microscope analysis. Cytotoxicity assays indicated the non-toxic effects of the NCs on normal healthy red blood cells. Furthermore, the in vitro cytotoxic effects of the CdO, NiO, and CdO-NiO NCs were examined using the human MCF-7 breast cancer cell line based on 3-[4,5-dimethylthiazol-2-yl]2,5-diphenyltetrazolium bromide assays with normal mouse embryonic fibroblasts (NH3T3) under identical conditions.

  4. High temperature coatings based on beta-NiAl

    Science.gov (United States)

    Severs, Kevin Richard

    Ni-based superalloys have been the workhorse materials in the high temperature alloy industry. Further increases in operating temperatures of these alloys have been limited due to low melting temperatures of constituent phases. A new alloy system has been proposed based on the Mo-Ni-Al system, which appears to be a promising alternative alloy. However, the intrinsic oxidation resistance of these alloys is relatively poor compared to current Ni-based superalloys. A two-step coating process based on electroplating and pack cementation was used to synthesize beta-NiAl coatings on top of the Mo-Ni-Al alloys. These coatings were seen to be stable when exposed to expected operating conditions, and substantially improved the oxidation resistance of the Mo-Ni-Al alloys. Grain size of beta-NiAl has been shown to be important during oxidation. Platinum group metals and Hf have been identified as effective alloying additions. However, less expensive additions need to be identified. Additions of 2 nd phase TiB2 particles were found to decrease the initial grain size of beta-NiAl, and limit grain growth after long term exposure at 1300°C.

  5. Structural study of Novel (superhard) material: NiO

    Indian Academy of Sciences (India)

    We have investigated the pressure-induced phase transition of NiO and other structural properties using three-body potential approach. NiO undergoes phase transition from B1 (rocksalt) to B2 (CsCl) structure associated with a sudden collapse in volume showing first-order phase transition. A theoretical study of high ...

  6. Electrolytic deposition and corrosion resistance of Zn–Ni coatings ...

    Indian Academy of Sciences (India)

    Administrator

    trochemical corrosion resistance were carried out in the 5% NaCl, using potentiodynamic and electrochemical impedance spectroscopy (EIS) methods. On the ground of these research, the possibility of deposition of Zn–. Ni coatings contained 24–26% at. Ni was exhibited. It was stated, that surface morphology, chemical ...

  7. REMOVAL OF Ni(II) FROM AQUEOUS SOLUTION USING LEAF ...

    African Journals Online (AJOL)

    Preferred Customer

    ABSTRACT. The present study investigates the possibility of using leaf, bark and seed of Moringa stenopetala as alternative adsorbents for removal of Ni(II) from aqueous solutions. The optimum adsorption conditions for removal of Ni(II) were found to be 30, 20 and 50 mg/L initial concentration, 1.5, 2 and 2.5 g adsorbent ...

  8. PtNi nanoparticles embedded in porous silica microspheres as ...

    Indian Academy of Sciences (India)

    SEM, EDS, TEM, FTIR, XRD, ICP-AES, XPS and nitrogen adsorption/desorption analysis were employed to systematically investigate the morphology and structure of the obtained SiO2 microspheres and SiO₂/PtNi nanocatalysts. Results show that uniform PtNi nanoparticles can be homogeneously and firmly embedded ...

  9. Phase transformation of NiTi alloys during vacuum sintering

    Science.gov (United States)

    Wang, Jun; Hu, Kuang

    2017-05-01

    The aim of this study is to ascertain the Phase transformation of NiTi alloys during vacuum sintering. NiTi shape memory alloys (SMA) of atomic ratio 1:1 were prepared through press forming and vacuum sintering with the mixture of Ni and Ti powders. Different samples were prepared by changing the sintering time and the sintering temperature. Phase and porosity of the samples were investigated by X-ray diffraction (XRD) and scanning electron microscope (SEM). The results show that in the process of sintering NiTi2 and Ni3Ti phases are formed firstly and then transform into NiTi phase. The quantity of NiTi2 and Ni3Ti phases gradually decreased but not eliminate completely with increase of sintering time. The porosity of specimen sintering at 900°C decreases slightly with increase of sintering time. With increase of sintering time the porosity of specimen sintering at 1050°C decreased firstly and then increased because of generation rich titanium liquid in the process of sintering.

  10. Microemulsion prepared Ni88Pt12 for methane cracking

    KAUST Repository

    Zhou, Lu

    2017-01-16

    Monodispersed NiPt nanoparticles of 10 nm were synthesized by water-in-oil microemulsion. The Ni-Pt alloy structure was stable during the thermal treatment between 330 and 1037 °C, whereas the relatively low temperature range of 600-700 °C was favorable for methane cracking to produce hydrogen and carbon nanotubes.

  11. Hydrocracking activity of NiMo-USY zeolite hydrotreating catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Egia, B.; Cambra, J.F.; Gueemez, B.; Arias, P.L. [Departamento de Ingeniera Quimica y del Medio Ambiente. Escuela de Ingenieros, Bilbao (Spain); Pawelec, B.; Fierro, J.L.G. [Instituto de Catalisis y Petroleoquimica, Madrid (Spain)

    1997-07-01

    In previous works the hydrodesulfurization and hydrodenitrogenation activities of Ni, Mo and MoNi zeolite supported catalysts were studied, and a remarkable initial deactivation by cocking was detected. In the present work the hydrocracking activity of these catalysts in the sulfided state has been studied. 21 refs.

  12. Energetic Mapping of Ni Catalysts by Detailed Kinetic Modeling

    DEFF Research Database (Denmark)

    Bjørgum, Erlend; Chen, De; Bakken, Mari G.

    2005-01-01

    precursor seems to result in more steplike sites, kinks, and defects for carbon monoxide dissociation. A detailed kinetic modeling of the TPO results based on elementary reaction steps has been conducted to give an energetic map of supported Ni catalysts. Experimental results from the ideal Ni surface fit...

  13. Electrolytic deposition and corrosion resistance of Zn–Ni coatings

    Indian Academy of Sciences (India)

    Zn–Ni coatings were deposited under galvanostatic conditions on steel substrate (OH18N9). The influence of current density of deposition on the surface morphology, chemical and phase composition was investigated. The corrosion resistance of Zn–Ni coatings obtained at current density 10–25 mA cm-2 are measured, ...

  14. Estudo da eletrocristalização de Ni e Ni-P sobre ultramicroeletrodo de platina Study of electrocrystallization of Ni and Ni-P on platinum ultramicroelectrode

    Directory of Open Access Journals (Sweden)

    Katlin Ivon Barrios Eguiluz

    2008-01-01

    Full Text Available This work describes a comparative study of the electrocrystallization of Ni and Ni-P on Pt ultramicroelectrodes using chronoamperometric measurements. It was possible to confirm that in all cases a progressive nucleation was the predominant mechanism. Moreover, the application of the Atomistic Theory to the experimental rate of nuclei formation showed that the number of atoms in the critical nucleus was zero, except for Ni-P on Pt at low overpotentials were a value of one was observed. Furthermore, the physical characterisation of the different deposits on Pt by atomic force microscopy allowed observing the coalescence of the hemispherical nuclei of Ni and Ni-P at t max thus confirming the results obtained from the current-time analysis.

  15. Pressure-induced Invar effect in Fe-Ni alloys.

    Science.gov (United States)

    Dubrovinsky, L; Dubrovinskaia, N; Abrikosov, I A; Vennström, M; Westman, F; Carlson, S; van Schilfgaarde, M; Johansson, B

    2001-05-21

    We have measured the pressure-volume (P-V) relations for cubic iron-nickel alloys for three different compositions: Fe 0.64Ni (0.36), Fe 0.55Ni (0.45), and Fe 0.20Ni (0.80). It is observed that for a certain pressure range the bulk modulus does not change or can even decrease to some minimum value, after which it begins to increase under still higher pressure. In our experiment, we observe for the first time a new effect, namely, that the Fe-Ni alloys with high Ni concentrations, which show positive thermal expansion at ambient pressure, become Invar system upon compression over a certain pressure range.

  16. Physical and mechanical metallurgy of NiAl

    Science.gov (United States)

    Noebe, Ronald D.; Bowman, Randy R.; Nathal, Michael V.

    1994-01-01

    Considerable research has been performed on NiAl over the last decade, with an exponential increase in effort occurring over the last few years. This is due to interest in this material for electronic, catalytic, coating and especially high-temperature structural applications. This report uses this wealth of new information to develop a complete description of the properties and processing of NiAl and NiAl-based materials. Emphasis is placed on the controlling fracture and deformation mechanisms of single and polycrystalline NiAl and its alloys over the entire range of temperatures for which data are available. Creep, fatigue, and environmental resistance of this material are discussed. In addition, issues surrounding alloy design, development of NiAl-based composites, and materials processing are addressed.

  17. Natural Ni speciation in the Callovo-Oxfordian clay rocks: implications for potential 63Ni isotopic exchange and retention mechanisms

    International Nuclear Information System (INIS)

    Grangeon, S.; Tournassat, C.; Schaefer, T.; Lerouge, C.; Wille, G.; Giffaut, E.

    2010-01-01

    Document available in extended abstract form only. In the perspective of deep underground long-term nuclear waste storage, 63 Ni is considered as a priority radio-element to be studied. 63 Ni behaviour prediction is made difficult mainly because its geochemical behaviour is still subject to debate. For instance, the solubility of Ni simple compounds at high pH is ill-defined, and the knowledge on solubility control phases is still pending. Clay rocks such as Callovo-Oxfordian (COx) contain non negligible amounts of natural and stable isotopes of Ni. As a consequence, a good understanding of the natural speciation of Ni in the formation could help to understand 63 Ni controls in this environment, including long term isotopic exchange with naturally present Ni. We focused our study on the COx formation, where the Bure (France) ANDRA underground research laboratory is located. Speciation of naturally occurring Ni was studied by combining chemical, microscopic and spectrometric methods. Chemical methods consisted of total rock analyses and sequential extractions on various COx samples representative of the variability of the formation (from carbonate rich samples to clay rich samples). This method enabled quantifying the main Ni reservoirs. Physical methods were used to get a closer look at the Ni-bearing phases. Optical and scanning electron microscopy techniques were used to identify and isolate minerals from thin rock sections, originating from different geological horizons. Chemical results indicate that the mean Ni concentration in the Callovo-Oxfordian clay rock is of ∼30 ppm (10 -6 g/g). Identified Ni-bearing minerals were mainly primary minerals (biotite, chlorite, muscovite), calcite and pyrite; organic matter being also observed. Electron microprobe and X-ray fluorescence analyses were performed in order to quantify the amounts and variability of Ni contents in these different Callovo-Oxfordian components. Ni is occasionally present in primary minerals with

  18. Facile and Scalable Synthesis of Robust Ni(OH)2Nanoplate Arrays on NiAl Foil as Hierarchical Active Scaffold for Highly Efficient Overall Water Splitting.

    Science.gov (United States)

    Niu, Shuai; Jiang, Wen-Jie; Tang, Tang; Zhang, Yun; Li, Ji-Hui; Hu, Jin-Song

    2017-08-01

    Developing highly efficient low-cost electrocatalysts for both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) in alkaline electrolyte is essential to advance water electrolysis technology. Herein, Ni(OH) 2 nanoplates aligned on NiAl foil (Ni(OH) 2 /NiAl) are developed by simply dealloying NiAl foil in KOH, which exhibits high electrocatalytic activity for OER with a small overpotential of 289 mV to achieve 10 mA cm -2 and outstanding durability with no detectable degradation during long-term operation. Furthermore, such Ni(OH) 2 /NiAl can effectively act as an active and robust hierarchical scaffold to simply electrodeposit other catalysts with intrinsically higher activity such as NiMo and NiFe nanoparticles for highly efficient HER and OER, respectively. The prepared NiFe/Ni(OH) 2 /NiAl displays superior OER catalytic activity with overpotentials of 246, 315, and 374 mV at 10, 100, and 500 mA cm -2 , respectively. While NiMo/Ni(OH) 2 /NiAl catalyst exhibits remarkable HER performance with a small overpotential of 78 mV to deliver 10 mA cm -2 . Consequently, the electrolysis device composed of the above two electrocatalysts demonstrates superb water splitting performance with a cell voltage of 1.59 V at 10 mA cm -2 . These results open up opportunities to explore and optimize low-cost advanced catalysts for energy applications.

  19. Evolution of Ni3X Precipitation Kinetics, Morphology and Spatial Correlations in Binary Ni-X Alloys Aged Under Externally Applied Stress

    Energy Technology Data Exchange (ETDEWEB)

    Ardell, Alan J

    2006-02-07

    Coarsening of Ni3Al, Ni3Ga, Ni3Ge and Ni3Si precipitates in aged binary single-crystal Ni-Al, Ni-Ga, Ni-Ge and Ni-Si alloys under applied compressive stress was measured experimentally over the temperature range 600 to 700 °C. Experiments were also performed on binary Ni-Al single crystals deformed in tension at 640°C. The orientation of the crystals was [100] in all the experiments. Compared to the kinetics of coarsening in unstressed alloys, coarsening was slightly slower in specimens aged under compression and slightly faster in specimens aged in tension. The effect of applied stress on morphology and spatial correlation was also measured and found to be small. Ni3Al precipitates of a given size generally tended to become more non-equiaxed and their interfaces more planar, with increasing compressive stress. Ni3Ge precipitates behaved differently, becoming more spherical in specimens aged under compression. The effect of applied stress on kinetics is attributed to the influence of elastic deformation on diffusion. A model was developed that predicts slightly slower diffusion under compression and slightly faster diffusion in tension. The elastic constants of single crystals of Ni-Al, Ni-Si, Ni-Ga and Ni-Ge solid solutions were measured from room temperature to about 1100 K using resonant ultrasound spectroscopy.

  20. Intrinsic ductility and environmental embrittlement of binary Ni3Al

    International Nuclear Information System (INIS)

    George, E.P.; Liu, C.T.; Pope, D.P.

    1993-01-01

    Polycrystalline, B-free Ni 3 Al (23.4 at.% Al), produced by cold working and recrystallizing a single crystal, exhibits room temperature tensile ductilities of 3-5% in air and 13-16% in oxygen. These ductilities are considerably higher than anything previously reported, and demonstrate that the 'intrinsic' ductility of Ni 3 Al is much higher than previously thought. They also show that the moisture present in ordinary ambient air can severely embrittle Ni 3 Al (ductility decreasing from a high of 16% in oxygen to a low of 3% in air). Fracture is predominantly intergranular in both air and oxygen. This indicates that, while moisture can further embrittle the GBs in Ni 3 Al, they persist as weak links even in the absence of environmental embrittlement. However, they are not 'intrinsically brittle' as once thought, since they can withstand relatively large plastic deformations prior to fracture. Because B essentially eliminates environmental embrittlement in Ni 3 Al - and environmental embrittlement is a major cause of poor ductility in B-free Ni 3 Al - it is concluded that a significant portion of the so-called B effect must be related to suppression of moisture-induced environmental embrittlement. However, since B-doped Ni 3 Al fractures transgranularly, whereas B-free Ni 3 Al fractures predominantly intergranularly, B must have the added effect that it strengthens the GBs. A comparison with the earlier work on Zr-doped Ni 3 Al shows that Zr improves the ductility of Ni 3 Al, both in air and (and even more dramatically) in oxygen. While the exact mechanism of this ductility improvement is not clear at present, Zr appears to have more of an effect on (enhancing) GB strength than on (suppressing) environmental embrittlement

  1. Carbon supported Pd-Ni and Pd-Ru-Ni nanocatalysts for the alkaline direct ethanol fuel cell (DEFC)

    CSIR Research Space (South Africa)

    Mathe, MK

    2011-08-01

    Full Text Available Carbon supported Pd-Ni and Pd-Ru-Ni nanocatalysts were prepared by the chemical reduction method, using sodium borohydride and ethylene glycol mixture as the reducing agent. The catalytic activity towards ethanol electro-oxidation in alkaline medium...

  2. First-principles investigations of Ni3Al(111) and NiAl(110) surfaces at metal dusting conditions

    DEFF Research Database (Denmark)

    Saadi, Souheil; Hinnemann, Berit; Appel, Charlotte C.

    2011-01-01

    We investigate the structure and surface composition of the γ′-Ni3Al(111) and β-NiAl(110) alloy surfaces at conditions relevant for metal dusting corrosion related to catalytic steam reforming of natural gas. In regular service as protective coatings, nickel–aluminum alloys are protected...

  3. Studies on the valence electronic structure of Fe and Ni in FexNi1−x ...

    Indian Academy of Sciences (India)

    Studies on the valence electronic structure of Fe and Ni in FexNi1−x alloys. D K BASA1,∗. , S RAJ2, H C PADHI2, M POLASIK3 and F PAWLOWSKI3. 1Department of Physics, Utkal University, Bhubaneswar 751 004, India. 2Institute of Physics, Bhubaneswar 751 005, India. 3Faculty of Chemistry, Nicholas Copernicus ...

  4. Exchange bias coupling in NiO/Ni bilayer tubular nanostructures synthetized by electrodeposition and thermal oxidation

    Energy Technology Data Exchange (ETDEWEB)

    Yu, T., E-mail: work_tian@scu.edu.cn [College of Physical Science and Technology, Sichuan University, Chengdu 610064 (China); Zhang, Z.W.; Xu, Y.H. [College of Physical Science and Technology, Sichuan University, Chengdu 610064 (China); Liu, Y. [Analytical & Testing Center, Sichuan University, Chengdu 610064 (China); Li, W.J. [Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, University of Chinese Academy of Sciences, Chinese Academy of Sciences, Beijing 100190 (China); Nie, Y.; Zhang, X. [College of Physical Science and Technology, Sichuan University, Chengdu 610064 (China); Xiang, G., E-mail: gxiang@scu.edu.cn [College of Physical Science and Technology, Sichuan University, Chengdu 610064 (China)

    2017-05-01

    In this paper, we reported the synthesis of NiO/Ni bilayer nanotubes by electrodeposition and thermal oxidation using anodic aluminum oxide templates. The morphology, structure, chemical composition and magnetic properties, especially magnetic exchange bias induced by subsequent magnetic field cooling, in this one-dimensional antiferromagnetic/ferromagnetic hybrid system were investigated. It was found that the effect of the annealing temperature, which mainly dominated the thickness of the NiO layer, and the annealing time, which mainly dominated the grain size of the NiO, on the exchange bias field showed competitive relationship. The optimized exchange bias field was achieved by the combination of the shorter annealing time and higher annealing temperature. - Highlights: • NiO-Ni bilayer tubular nanotubes were fabricated by electrodeposition and thermal oxidation. • The exchange bias effect in NiO-Ni nanotubes was induced by magnetic field cooling. • The competitive effect of annealing temperature and annealing time on the exchange bias coupling was analyzed.

  5. Controlled synthesis of mesoporous β-Ni(OH)2 and NiO nanospheres with enhanced electrochemical performance

    International Nuclear Information System (INIS)

    Xing, Shengtao; Wang, Qian; Ma, Zichuan; Wu, Yinsu; Gao, Yuanzhe

    2012-01-01

    Highlights: ► Uniform mesoporous β-Ni(OH) 2 and NiO nanospheres with hierarchical structures were synthesized by a simple complexation–precipitation method. ► Both ammonia and citrate played an important role for the formation of mesoporous nanospheres. ► β-Ni(OH) 2 and NiO nanospheres showed excellent capacitive properties due to their mesoporous structures and larger surface areas. -- Abstract: Uniform mesoporous β-Ni(OH) 2 and NiO nanospheres with hierarchical structures were synthesized by a facile complexation–precipitation method. The effects of ammonia and citrate on the structure and morphology of the products were thoroughly investigated by X-ray powder diffraction, scanning electron microscopy, transmission electron microscopy and nitrogen adsorption–desorption measurements. The results indicated that ammonia played an important role for the formation of flowerlike spheres assembled from nanosheets. The addition of citrate could remarkably reduce the particle sizes and increase the specific surface areas of flowerlike spheres. A possible formation mechanism based on the experimental results was proposed to understand their growing procedures. β-Ni(OH) 2 and NiO nanospheres prepared with the addition of citrate showed excellent capacitive properties due to their mesoporous structures and large surface areas, suggesting the importance of controlled synthesis of hierarchical nanostructures for their applications.

  6. Absence of Ni on the outer surface of Sr doped La 2 NiO 4 single crystals

    KAUST Repository

    Burriel, Mónica

    2014-01-01

    A combination of surface sensitive techniques was used to determine the surface structure and chemistry of La2-xSrxNiO 4+δ. These measurements unequivocally showed that Ni is not present in the outermost atomic layer, suggesting that the accepted model with the B-site cations exposed to the environment is incorrect. © 2014 The Royal Society of Chemistry.

  7. Site determination of Ni atoms in Cu-Al-Ni shape memory alloys by electron channelling enhanced microanalysis

    International Nuclear Information System (INIS)

    Nakata, Yoshiyuki; Tadaki, Tsugio; Shimizu, Ken-ichi

    1990-01-01

    The crystallographic site of Ni atoms in the parent phase of differently heat-treated Cu-28.6Al-3.7Ni (at.%) shape memory alloys has been examined by electron channelling enhanced microanalysis (ALCHEMI) in order to clarify effects of heat-treatments on the Ni atom site and M s temperature. The heat-treatments were as follows: (a) Quenching into a 10% NaOH solution at 263 K, (b) Quenching into hot water at 363 K and (c) Aging at 523 K for 3.6 ks after treatment (b). The M s temperatures of specimens (a), (b) and (c) were 158, 185 and 259 K, respectively, increasing with lowering quenching rate or aging. ALCHEMI revealed that Ni atoms occupied an identical site in all the three kinds of specimens: The Ni atoms were located at the nearest neighbor sites around Al atoms. This preferential occupation of Ni atoms was attributed to the strong binding force between Ni and Al atoms. Thus, the change in M s temperature due to different heat-treatments was not directly related to the crystallographic site of Ni atoms, but might be caused by the ordering between the next nearest neighbor Cu and Al atoms. (author)

  8. Atomic scale modelling of nanosize Ni sub 3 Al cluster beam deposition on Al, Ni and Ni sub 3 Al (1 1 1) surfaces

    CERN Document Server

    Kharlamov, V S; Hou, M

    2002-01-01

    The slowing down of Ni sub 3 Al clusters on a Al, Ni and Ni sub 3 Al (1 1 1) surfaces is studied by atomic scale modelling. The semi-grand canonical metropolis Monte Carlo is used for the preparation of isolated clusters at thermodynamic equilibrium. The cluster deposition on the surface is studied in detail by classical Molecular Dynamics simulations that include a model to account for electron-phonon coupling. Long- and short-range orders in the cluster are evaluated as functions of temperature in an impact energy range between 0 and 1.5 eV/atom. The interaction between the Ni sub 3 Al cluster and an Al surface is characterised low short range (chemical) disorder. No sizeable epitaxy is found, subsequent to the impact. In contrast, in the case of Ni and Ni sub 3 Al substrates, which are harder materials than aluminium, the chemical disorder is higher and epitaxial accommodation is possible. With these substrates, chemical disorder in the cluster is an increasing function of the impact energy, as well as of ...

  9. Martensitic transformation and magnetic properties of manganese-rich Ni-Mn-In and Ni-Mn-Sn Heusler alloys

    International Nuclear Information System (INIS)

    Krenke, T.

    2007-01-01

    In the present work, the martensitic transition and the magnetic properties of Manganese rich Ni 50 Mn 50-x Sn x and Ni 50 Mn 50-y In y alloys with 5 at%≤x(y)≤25 at% were investigated. Calorimetry, X-ray and neutron diffraction, magnetization, and strain measurements were performed on polycrystalline samples. It was shown that alloys close to the stoichiometric composition Ni 50 Mn 25 Sn 25 and Ni 50 Mn 25 Sn 25 do not exhibit a structural transition on lowering of the temperature, whereas alloys with x≤15 at% Tin and y≤16 at% Indium transform martensitically. The structural transition temperatures increase linearly with decreasing Tin or Indium content. The crystal structures of the low temperature martensite are modulated as well as unmodulated. Alloys with compositions close to stoichiometry are dominated by ferromagnetic interactions, whereas those close to the binary composition Ni 50 Mn 50 order antiferromagnetically. Ferromagnetic order and structural instability coexist in a narrow composition range between 13 at%≤x≤15 at% and 15 at%≤x≤16 at% for Ni 50 Mn 50-x Sn x and Ni 50 Mn 50-y In y respectively. As a consequence, interesting magnetoelastic effects are observed. The Ni 50 Mn 34 In 16 alloy shows a magnetic field-induced structural transition, whereby application of an external magnetic field in the martensitic state stabilizes the high temperature L2 1 structure. Evidence for this was given by neutron diffraction experiments in external magnetic fields. Moreover, the structural transition temperatures of this alloy show large magnetic field dependencies. By use of calorimetry, M(T), and strain measurements, changes in M s up to -11 K/Tesla are observed. Such large values have, until now, not been observed in Heusler alloys. Since during transformation the volume changes reversibly, magnetic field-induced strains of about 0.12 % appear. Additionally, the alloys Ni 50 Mn 35 Sn 15 , Ni 50 Mn 37 Sn 13 , Ni 50 Mn 34 In 16 , Ni 51.5 Mn 33 In

  10. Fabrication and characterization of single segment CoNiP and multisegment CoNiP/Au nanowires

    International Nuclear Information System (INIS)

    Luu Van Thiem; Le Tuan Tu

    2014-01-01

    This paper presents the fabrication of CoNiP single segment and CoNiP/Au multisegment nanowires. We have fabricated these nanowires by electrodeposition method into polycarbonate templates with a nominal pore diameter about 100 nm. The hysteresis loops were measured with the applied magnetic field parallel and perpendicular to the wire axis using a vibrating sample magnetometer (VSM). The structure morphology was observed by Scanning Electron Microscopy (SEM) and the element composition of CoNiP/Au multisegment nanowires were analyzed by EDS. The results show that nanowires are very uniform with the diameter of 100 nm. The observed coercivity (H C ) and squareness (Mr/Ms) of CoNiP single segment nanowires are larger than the CoNiP/Au multisegment nanowires. (author)

  11. Photochemical deposition of NiCoO {sub x} thin films from Ni/Co heteronuclear triketonate complexes

    Energy Technology Data Exchange (ETDEWEB)

    Buono-Core, G.E. [Instituto de Quimica, Pontificia Universidad Catolica de Valparaiso, Avda. Brasil 2950, Valparaiso (Chile)]. E-mail: gbuonoco@ucv.cl; Tejos, M. [Facultad de Ciencias, Universidad de Valparaiso, Valparaiso (Chile); Cabello, G. [Instituto de Quimica, Pontificia Universidad Catolica de Valparaiso, Avda. Brasil 2950, Valparaiso (Chile); Guzman, N. [Instituto de Quimica, Pontificia Universidad Catolica de Valparaiso, Avda. Brasil 2950, Valparaiso (Chile); Hill, R.H. [Department of Chemistry, Simon Fraser University, Burnaby B.C. V5A 1S6 (Canada)

    2006-03-10

    UV light irradiation of thin films of a polyketonate Ni/Co heteronuclear complex, NiCo(DBA){sub 2} [DBA, dibenzoylacetone)], spin coated on Si(1 0 0) substrates produced NiCoO {sub x} mixed oxides as amorphous films. On annealing at 600 deg. C under air, the mixed oxide film decomposed to NiO and CoO as indicated by XRD measurements. The morphology of the as-deposited films was examined by AFM analysis showing a smooth surface with low rms roughness values. The ratio of Ni/Co (1.08) present in the film reflects the stoichiometry in the starting compound within the experimental error, as shown by XPS analysis. The large amount of carbon (20.8%) detected on the surface of the film may be due to the presence of phenyl rings in the precursor complex.

  12. Enhanced Dry Reforming of Methane on Ni and Ni-Pt Catalysts Synthesized by Atomic Layer Deposition

    Energy Technology Data Exchange (ETDEWEB)

    Gould, Troy D.; Montemore, Matthew M.; Lubers, Alia M.; Ellis, Lucas D.; Weimer, Alan; Falconer, John L.; Medlin, James W.

    2015-02-25

    Atomic layer deposition (ALD) was used to deposit Ni and Pt on alumina supports to form monometallic and bimetallic catalysts with initial particle sizes of 1–2.4 nm. The ALD catalysts were more active (per mass of metal) than catalysts prepared by incipient wetness (IW) for dry reforming of methane (DRM), and they did not form carbon whiskers during reaction due to their sufficiently small size. Catalysts modified by Pt ALD had higher rates of reaction per mass of metal and inhibited coking, whereas NiPt catalysts synthesized by IW still formed carbon whiskers. Temperature-programmed reduction of Ni catalysts modified by Pt ALD indicated the presence of bimetallic interaction. Density functional theory calculations suggested that under reaction conditions, the NiPt surfaces form Ni-terminated surfaces that are associated with higher DRM rates (due to their C and O adsorption energies, as well as the CO formation and CH4 dissociation energies).

  13. Magnetoresistance Effect in NiFe/BP/NiFe Vertical Spin Valve Devices

    Directory of Open Access Journals (Sweden)

    Leilei Xu

    2017-01-01

    Full Text Available Two-dimensional (2D layered materials such as graphene and transition metal dichalcogenides are emerging candidates for spintronic applications. Here, we report magnetoresistance (MR properties of a black phosphorus (BP spin valve devices consisting of thin BP flakes contacted by NiFe ferromagnetic (FM electrodes. The spin valve effect has been observed from room temperature to 4 K, with MR magnitudes of 0.57% at 4 K and 0.23% at 300 K. In addition, the spin valve resistance is found to decrease monotonically as temperature is decreased, indicating that the BP thin film works as a conductive interlayer between the NiFe electrodes.

  14. Edge geometry effects on resonance response of electroplated cylindrical Ni/PZT/Ni magnetoelectric composites

    Directory of Open Access Journals (Sweden)

    Vladislav Yakubov

    2017-08-01

    Full Text Available Trilayer Ni/PZT/Ni cylindrical magnetoelectric (ME composites were prepared by electrodeposition, a process, which creates sub-millimeter raised edges due to current concentration near sharp points. The ME response in both axial and vertical modes was measured with the edges, with only outer edges removed, and with both outer and inner edges removed. The ME voltage coefficient improved at resonance by 40% and 147% without the edges in the vertical and axial modes, respectively. The observed improvements in three different samples were only present at the ME resonance and no changes were detected outside of the ME resonance. Mechanical quality factor at resonance also improved with no effect on the resonant frequency. Experimentally demonstrated minor geometry changes resulted in substantial ME improvement at resonant frequency. This study demonstrates device performance optimization. The observed effects have been attributed to improved vibrations in terms of decreased damping coefficient and enhanced vibration amplitude at resonance.

  15. Probing core polarization around 78Ni: intermediate energy Coulomb excitation of 74Ni

    Directory of Open Access Journals (Sweden)

    Marchi T.

    2013-12-01

    We have recently measured the B(E2; 0+ → 2+ of the 74Ni nucleus in an intermediate-energy Coulomb excitation experiment performed at the National Superconducting Cyclotron Laboratory of the Michigan State University. The 74Ni secondary beam has been produced by fragmentation of 86Kr at 140 AMeV on a thick Be target. Selected radioactive fragments impinged on a secondary 197Au target where the measurement of the emitted γ-rays allows to extract the Coulomb excitation cross section and related structure information. Preliminary B(E2 values do not point towards an enhancement of the transition matrix element and the comparison to what was already measured by Aoi and co-workers in [1] opens new scenarios in the interpretation of the shell evolution of the Z=28 isotopes.

  16. Static magnetic susceptibility of radiopaque NiTiPt and NiTiEr

    Science.gov (United States)

    Chovan, Drahomír; Gandhi, Abbasi; Butler, James; Tofail, Syed A. M.

    2018-04-01

    Magnetic properties of metallic alloys used in biomedical industry are important for the magnetic resonance imaging (MRI). If the alloys were to be used for long term implants or as guiding devices, safety of the patient as well as the medical staff has to be ensured. Strong response to the external magnetic field can cause mechanical damage to the patients body. In this paper we present magnetic susceptibility of nickel rich, ternary NiTiPt and NiTiEr to static magnetic field. We show that the magnetic susceptibility of these radiopaque alloys has values in low paramagnetic region comparable to the binary nickel-titanium. Furthermore, we studied the effect of the thermal and mechanical treatments on magnetic properties. Despite deviation from linear M (H) treated samples spanning small region around H = 0 , the linearity of the M (H) and χ =d M /d H values suggest that these ternary alloys are safe to use under MRI conditions.

  17. Active Pt3Ni (111) Surface of Pt3Ni Icosahedron for Oxygen Reduction.

    Science.gov (United States)

    Zhu, Jianbing; Xiao, Meiling; Li, Kui; Liu, Changpeng; Zhao, Xiao; Xing, Wei

    2016-11-09

    Highly active, durable oxygen reduction reaction (ORR) electrocatalysts are extremely important for fuel cell applications. Herein, we provide an efficient way to synthesis of activity Pt 3 M icosahedra by the one-pot hydrothermal method in the presence of glucosamine which can well adjust the reduction rate of Pt 4+ and efficiently control the morphology of final catalysts. Compared to Pt/C, the Pt 3 Ni icosahedra show 32-fold and 12-fold enhancement in specific and mass activity, respectively. Furthermore, robust durability was also observed in the accelerated durability test. Thus, this Pt 3 Ni icosahedron is found among the best Pt-based ORR catalysts, moreover, the findings also demonstrate how to mimic active extended surfaces in nanoscale.

  18. Characteristics of electrodeposition of Ni and Ni-P alloys from methanesulfonate electrolytes

    Science.gov (United States)

    Sknar, Yu. E.; Savchuk, O. O.; Sknar, I. V.

    2017-11-01

    The characteristics of electrodeposition of Ni-P alloys from a methanesulfonate electrolyte have been investigated. Ni-P alloys electrodeposited from an electrolyte containing 0.03-0.12 mol dm-3 of sodium hypophosphite, produce uniform, smooth, and well adherent to the substrate deposits. Phosphorus content of the alloy increases with an increase in the sodium hypophosphite concentration in the electrolyte and a decrease in the electrodeposition current density. Nickel-phosphorus alloys have a refined surface structure with small grains closely adjacent to each other. Ni-P alloys obtained from the methanesulfonate electrolyte at pH 3, have gloss levels of up to 20%. The coatings exhibit higher internal stresses and hardness, which increase with an increased concentration of sodium hypophosphite in the electrolyte. A decrease in the electrolyte pH increases the phosphorus content of the deposits and enhances the properties studied. The phosphorus content of the coatings obtained from a methanesulfonate electrolyte is lower than in the coatings deposited from a sulfate electrolyte under the same conditions. However, the deposits produced from the methanesulfonate electrolyte are characterized by higher values of gloss, hardness and internal stresses. This is due to the fact that along with phosphorus incorporated into the coating, the deposit structure is distorted by nickel hydroxide incorporated to the deposit during the electrolysis. The methanesulfonate electrolyte has lower buffering properties and, correspondingly, a higher amount of nickel hydroxide dispersion is formed in the near-electrode layer. The experimental data indicate that, in spite of lower phosphorus content, Ni-P alloys deposited from a methanesulfonate electrolyte have better physical-mechanical properties than those deposited from a sulfate electrolyte.

  19. Equidad entre niñas y niños: situaciones didácticas

    Directory of Open Access Journals (Sweden)

    Antonio Paoli

    2010-01-01

    Full Text Available Este artículo presenta cuatro situaciones didácticas para la educación primaria, de cuarto y quinto grado en especial, y un conjunto de principios educativos; su finalidad es esclarecer y ejemplificar claves del programa educativo Jugar y vivir los valores (jvlv, orientadas a propiciar la equidad y la armonía entre los géneros. En este trabajo se muestran actividades prácticas que buscan explícitamente favorecer en las aulas la equidad de género: cuentos, canciones, preguntas a los niños para propiciar diálogos y conceptualizaciones surgidas de ellos, tareas familiares y reflexiones sobre la didáctica aplicada en la comunidad educativa, comunidad que incluye a maestros, padres de familia, niños y a todo el personal de la escuela. El Programa jvlv se creó en el Departamento de Educación y Comunicación de la uam-x, y hoy se aplica en más de 1000 primarias oficiales del estado de Chiapas. El programa se experimentó como programa piloto primero en diez jardines de niñas y niños en el año escolar 2001-2002, posteriormente en seis primarias oficiales en 2003-2004 y hoy se desarrolla un nuevo programa piloto en 52 primarias en los municipios de Tuxtla Gutiérrez y Suchiapa. La concepción de equidad se tiende a identificar con la de justicia, entendida como dar beneficio a los demás, al medio ambiente y a uno mismo. La equidad de género supone centrar la atención en hacer bien tanto a hombres como a mujeres, sistemáticamente.

  20. Ni-Based Solid Oxide Cell Electrodes

    DEFF Research Database (Denmark)

    Mogensen, Mogens Bjerg; Holtappels, Peter

    2013-01-01

    This paper is a critical review of the literature on nickel-based electrodes for application in solid oxide cells at temperature from 500 to 1000 _C. The applications may be fuel cells or electrolyser cells. The reviewed literature is that of experimental results on both model electrodes...... and practical composite cermet electrodes. A substantially longer three-phase boundary (TPB) can be obtained per unit area of cell in such a composite of nickel and electrolyte material, provided that two interwoven solid networks of the two solid and one gaseous phases are obtained to provide a three...... such as milling and sintering. The various electrode properties are deeply related to these parameters, but also much related to the atomic scale structure of the Ni-electrolyte interface, which in turn is affected by segregation of electrolyte components and impurities as well as poisons in the gas phase...

  1. Structure analysis of NiAl martensite

    Energy Technology Data Exchange (ETDEWEB)

    Noda, Y.; Shapiro, S.M.; Shirane, G.; Yamada, Y.; Fuchizaki, K.; Tanner, L.E.

    1989-01-01

    Neutron elastic scattering experiments were performed in order to investigate the structure of the low temperature martensitic phase of Ni/sub 62.5/Al/sub 37.5/ alloy. The average structure analyzed from the integrated intensity was approximately described by the (5,/minus/2) structure proposed by Martynov et al. Small deviation from the exact (5,/minus/2) model in the positional parameters and the anomalously large Debye-Waller factor were obtained. The observed satellite profiles show asymmetrical broadening, and the peak positions shift from the regular reciprocal lattice points. These anomalous features of scattering profiles were tentatively interpreted by introducing spatial modulation of the strain and order parameters. 12 refs., 2 figs., 1 tab.

  2. Structure analysis of NiAl martensite

    International Nuclear Information System (INIS)

    Noda, Y.; Shapiro, S.M.; Shirane, G.; Yamada, Y.; Fuchizaki, K.; Tanner, L.E.

    1989-01-01

    Neutron elastic scattering experiments were performed in order to investigate the structure of the low temperature martensitic phase of Ni 62.5 Al 37.5 alloy. The average structure analyzed from the integrated intensity was approximately described by the (5,-2) structure proposed by Martynov et al. Small deviation from the exact (5,-2) model in the positional parameters and the anomalously large Debye-Waller factor were obtained. The observed satellite profiles show asymmetrical broadening, and the peak positions shift from the regular reciprocal lattice points. These anomalous features of scattering profiles were tentatively interpreted by introducing spatial modulation of the strain and order parameters. 12 refs., 2 figs., 1 tab

  3. The Influence of Cr on the Solidification Behavior of Polycrystalline γ(Ni)/ γ'(Ni3Al)- δ(Ni3Nb) Eutectic Ni-Base Superalloys

    Science.gov (United States)

    Xie, Mengtao; Helmink, Randolph; Tin, Sammy

    2012-04-01

    In the current investigation, the effect of Cr on the solidification characteristics and as-cast microstructure of pseudobinary γ- δ eutectic alloys based on a near-eutectic composition (Ni-5.5Al-13.5Nb at. pct) was investigated. It was found that Cr additions promote the formation of a higher volume fraction of γ- δ eutectic microstructure in the interdendritic region. Increasing levels of Cr also triggered morphological changes in the γ- δ eutectic and the formation of γ- γ'- δ ternary eutectic during the last stage of solidification. A detailed characterization of the as-cast alloys also revealed that Cr additions suppressed the liquidus, solidus, and γ' precipitation temperature of these γ/ γ'- δ eutectic alloys. A comparison of the experimental results with thermodynamic calculations using the CompuTherm Pandat database (CompuTherm LLC, Madison, WI) showed qualitative agreement.

  4. Interface stress in Au/Ni multilayers

    DEFF Research Database (Denmark)

    Schweitz, K.O.; Böttiger, J.; Chevallier, J.

    2000-01-01

    The effect of intermixing on the apparent interface stress is studied in -textured dc-magnetron sputtered Au/Ni multilayers by use of two methods commonly used for determining interface stress. The method using profilometry and in-plane x-ray diffraction does not take intermixing...... into account and yields an apparent interface stress of -8.46 +/- 0.99 J m(-2). However, observed discrepancies between model calculations and measured high-angle x-ray diffractograms indicate intermixing, and by use of the profilometry and sin(2) psi method the real interface stress value of -2.69 +/- 0.43 J...... m(-2) is found. This method also reveals a significant and systematic change of the stress-free lattice parameter of both constituents as a function of modulation period which is shown to account for the difference between the two findings. The method using in-plane diffraction is thus shown...

  5. Microstructure and property of directionally solidified Ni-Si hypereutectic alloy

    Science.gov (United States)

    Cui, Chunjuan; Tian, Lulu; Zhang, Jun; Yu, Shengnan; Liu, Lin; Fu, Hengzhi

    2016-03-01

    This paper investigates the influence of the solidification rate on the microstructure, solid/liquid interface, and micro-hardness of the directionally solidified Ni-Si hypereutectic alloy. Microstructure of the Ni-Si hypereutectic alloy is refined with the increase of the solidification rate. The Ni-Si hypereutectic composite is mainly composed of α-Ni matrix, Ni-Ni3Si eutectic phase, and metastable Ni31Si12 phase. The solid/liquid interface always keeps planar interface no matter how high the solidification rate is increased. This is proved by the calculation in terms of M-S interface stability criterion. Moreover, the Ni-Si hypereutectic composites present higher micro-hardness as compared with that of the pure Ni3Si compound. This is caused by the formation of the metastable Ni31Si12 phase and NiSi phase during the directional solidification process.

  6. Ferromagnetic resonance in bulk nanocrystalline Ni

    Science.gov (United States)

    Prakash Madduri, P. V.; Mathew, S. P.; Kaul, S. N.

    2018-03-01

    A detailed lineshape analysis of the ferromagnetic resonance (FMR) spectra taken on pulse electrodeposited nanocrystalline (nc-) Ni sheets (with the average crystallite size, d, varying from 10 nm to 40 nm) at temperatures ranging from 113 K to 325 K yield accurate values for saturation magnetization, Ms (T), Landé splitting factor, g, anisotropy field, Hk (T) , resonance field, Hres , and FMR linewidth, ΔHpp (T) . Thermally-excited spin-wave (SW) excitations completely account for Ms (T) and the SW description of Ms (T) gives the values for the saturation magnetization and spin-wave stiffness at absolute zero of temperature, i.e., Ms (0) and D0 , for nc-Ni samples of different d that are in excellent agreement with the corresponding values deduced previously from an elaborate SW analysis of the bulk magnetization data. While Ms (0) varies with d as Ms (0) d - 3 / 2,D0 follows the power law D0 ∼d 4 / 3 . The angular variations of Hres in the 'in-plane' as well as 'out-of-plane' sample configurations, demonstrate that the main contribution to Hk (T) comes from the cubic magnetocrystalline anisotropy. The exchange-conductivity mechanism describes the observed thermal decline of ΔHpp reasonably well but fails to explain the very large magnitude of ΔHpp at any given temperature. By comparison, the Landau-Lifshitz-Gilbert (LLG) damping gives a much greater contribution to ΔHpp but the LLG contribution is relatively insensitive to temperature.

  7. Study of the 66Ni(t,d)67Ni Transfer Reaction in Inverse Kinematics

    CERN Document Server

    Callens, Maarten

    The nickel isotopes with 28 protons are an interesting series in the study of nuclear structure. In the framework of the shell model nickel has a closed proton shell and the number of neutrons ranges from the magic numbers 20 to 50. The neutron-rich isotope $^{78}$Ni, is a waiting point in the nucleosynthesis r-process. In this process an intense neutron flux such as in supernovae results in the rapid capture of neutrons. The reaction sequence halts at $^{78}$Ni and waits for this nucleus to decay [Hea05]. For several decades the nickel isotopes have been studied extensively, particularly how the nuclear structure evolves when moving to the exotic boundaries of the nuclear chart. A remarkable feature was observed in $^{68}$Ni. This nucleus with 40 neutrons exhibits properties that are characteristic for doubly magic nuclei. Such as the energy of the first 2$^+$ state lies significantly higher than in neighbouring even-A isotopes, and is also higher than the energy of the second 0$^+$ state. Moreover also the ...

  8. Combinatorial search for hydrogen storage alloys: Mg-Ni and Mg-Ni-Ti

    Energy Technology Data Exchange (ETDEWEB)

    Oelmez, Rabia; Cakmak, Guelhan; Oeztuerk, Tayfur [Dept. of Metallurgical and Materials Engineering, Middle East Technical University, 06531 Ankara (Turkey)

    2010-11-15

    A combinatorial study was carried out for hydrogen storage alloys involving processes similar to those normally used in their fabrication. The study utilized a single sample of combined elemental (or compound) powders which were milled and consolidated into a bulk form and subsequently deformed to heavy strains. The mixture was then subjected to a post annealing treatment, which brings about solid state reactions between the powders, yielding equilibrium phases in the respective alloy system. A sample, comprising the equilibrium phases, was then pulverized and screened for hydrogen storage compositions. X-ray diffraction was used as a screening tool, the sample having been examined both in the as processed and the hydrogenated state. The method was successfully applied to Mg-Ni and Mg-Ni-Ti yielding the well known Mg{sub 2}Ni as the storage composition. It is concluded that a partitioning of the alloy system into regions of similar solidus temperature would be required to encompass the full spectrum of equilibrium phases. (author)

  9. Alloy composition dependence of formation of porous Ni prepared by rapid solidification and chemical dealloying

    Energy Technology Data Exchange (ETDEWEB)

    Qi Zhen [Key Laboratory of Liquid Structure and Heredity of Materials, Shandong University, Jingshi Road 73, Jinan 250061 (China); Zhang Zhonghua [Key Laboratory of Liquid Structure and Heredity of Materials, Shandong University, Jingshi Road 73, Jinan 250061 (China)], E-mail: zh_zhang@sdu.edu.cn; Jia Haoling [Key Laboratory of Liquid Structure and Heredity of Materials, Shandong University, Jingshi Road 73, Jinan 250061 (China); Qu Yingjie [Shandong Labor Occupational Technology College, Jingshi Road 388, Jinan 250022 (China); Liu Guodong; Bian Xiufang [Key Laboratory of Liquid Structure and Heredity of Materials, Shandong University, Jingshi Road 73, Jinan 250061 (China)

    2009-03-20

    In this paper, the effect of alloy composition on the formation of porous Ni catalysts prepared by chemical dealloying of rapidly solidified Al-Ni alloys has been investigated using X-ray diffraction (XRD), scanning electron microscopy (SEM) with energy dispersive X-ray (EDX) analysis and N{sub 2} adsorption experiments. The experimental results show that rapid solidification and alloy composition have a significant effect on the phase constituent and microstructure of Al-Ni alloys. The melt spun Al-20 at.% Ni alloy consists of {alpha}-Al, NiAl{sub 3} and Ni{sub 2}Al{sub 3}, while the melt spun Al-25 and 31.5 at.% Ni alloys comprise NiAl{sub 3} and Ni{sub 2}Al{sub 3}. Moreover, the formation and microstructure of the porous Ni catalysts are dependent upon the composition of the melt spun Al-Ni alloys. The morphology and size of Ni particles in the Ni catalysts inherit from those of grains in the melt spun Al-Ni alloys. Rapid solidification can extend the alloy composition of Al-Ni alloys suitable for preparation of the Ni catalysts, and obviously accelerate the dealloying process of the Al-Ni alloys.

  10. Cavitation resistance of surface composition "Steel-Ni-TiNi-TiNiZr-cBNCo", formed by High-Velocity Oxygen-Fuel spraying

    Science.gov (United States)

    Blednova, Zh. M.; Dmitrenko, D. V.; Balaev, E. U. O.

    2018-01-01

    The object of the study is a multilayered surface composition "Steel - a Multicomponent material with Shape Memory Effect - a wear-resistant layer" under conditions of cavitation effects in sea water. Multicomponent TiNi-based coatings with addition of alloying elements such as Zr in an amount up to 10% mass, allow to create a composite material with a gradient of properties at the interface of layers, which gives new properties to coatings and improves their performance significantly. The use of materials with shape memory effect (SME) as surface layers or in the composition of surface layered compositions allows to provide an effective reaction of materials to the influence of external factors and adaptation to external influences. The surface composite layer cBN-10%Co has high hardness and strength, which ensures its resistance to shock cyclic influences of collapsing caverns. The increased roughness of the surface of a solid surface composite in the form of strong columnar structures ensures the crushing of vacuum voids, redistributing their effect on the entire surface, and not concentrating them in certain zones. In addition, the gradient structure of the multilayer composite coating TiNi-Ti33Ni49Zr18-cBN-10%Co Co makes it possible to create conditions for the relaxation of stresses created by the variable impact load of cavitation caverns and the manifestation of compensating internal forces due to thermo-elastic martensitic transformations of SME materials. The cavitation resistance of the coating TiNi-Ti33Ni49Zr18-cBN-10%Co according to the criterion of mass wear is 15-20 times higher than that of the base material without coating and 10-12 times higher than that of the TiNi-TiNiZr coating. The proposed architecture of the multifunctional gradient composition, "steel-Ni-TiNi- Ti33Ni49Zr18-cBN-10%Co", each layer of which has its functional purpose, allows to increase the service life of parts operating under conditions of cavitation-fatigue loading in

  11. Preparation of fine Ni powders from nickel hydrazine complex

    International Nuclear Information System (INIS)

    Park, Jung Woo; Chae, Eun H.; Kim, Sang H.; Lee, Jong Ho; Kim, Jeong Wook; Yoon, Seon Mi; Choi, Jae-Young

    2006-01-01

    Fine nickel powders with narrow size distribution have been prepared from the reduction of nickel hydrazine complexes in aqueous solution. The pure nickel hydrazine complexes, [Ni(N 2 H 4 ) 3 ]Cl 2 were prepared with the molar ratio of N 2 H 4 /Ni 2+ = 4.5, while a mixture of complexes, such as Ni(N 2 H 4 ) 2 Cl 2 , [Ni(N 2 H 4 ) 3 ]Cl 2 , and [Ni(NH 3 ) 6 ]Cl 2 were formed with N 2 H 4 /Ni 2+ 2+ to metallic Ni powder proceeded via the formation of nickel hydroxide which was reduced by hydrazine liberated from the ligand exchange reaction between the nickel hydrazine complex and NaOH. The standard deviation of the particle size decreased with the decreasing molar concentration of nickel hydrazine complex while the mean particle size increased. As the amount of hydrazine increased, the surface roughness of the particles was improved significantly due to the catalytic decomposition of the excess hydrazine at the surface of the nickel particle. It was found that average particle size could be controlled from 150 to 380 nm by adjusting the reaction molar ratio and temperature

  12. Diffusion couple studies of the Ni-Bi-Sn system

    Directory of Open Access Journals (Sweden)

    Vassilev G.

    2012-01-01

    Full Text Available Investigations of Ni-Bi-Sn system were performed in order to inquire the phase diagram and to assess some diffusion kinetic parameters. For this purpose diffusion couples consisting of solid nickel (preliminary electroplated with tin and liquid Bi-Sn phase were annealed at 370 °C. Three compositions (0.8, 0.6 and 0.4 mole fractions Sn of the Bi-Sn melts were chosen. Annealing times from 24 to 216 h were applied. The phase and chemical compositions of the contact zone were determined by means of electron scanning microscope. It was confirmed that the diffusion layers consist mainly of Ni3Sn4 but other intermetallic phases grow as well. For the first time metastable Ni-Sn phases as NiSn and NiSn8 (NiSn9 were observed in metallurgical alloys (i.e. not in electroplated samples. The existence of a ternary compound previously reported in the literature was confirmed. More than one ternary Ni-Bi-Sn compounds might possibly be admitted. A growth coefficient of (2.29 ± 0.02 x 10-15 m2 s-1 was obtained. It was found that the apparent activation energy for diffusion layers growth (18 ± 8 kJ mol-1 is inferior to that one assessed at growth from solid state Bi-Sn mixtures (88 ± 12 kJ mol-1.

  13. Porous NiTi for bone implants: A review

    Science.gov (United States)

    Bansiddhi, A.; Sargeant, T.D.; Stupp, S.I.; Dunand, D.C.

    2011-01-01

    NiTi foams are unique among biocompatible porous metals because of their high recovery strain (due to the shape-memory or superelastic effects) and their low stiffness facilitating integration with bone structures. To optimize NiTi foams for bone implant applications, two key areas are under active study: synthesis of foams with optimal architectures, microstructure and mechanical properties; and tailoring of biological interactions through modifications of pore surfaces. This article reviews recent research on NiTi foams for bone replacement, focusing on three specific topics: (i) surface modifications designed to create bio-inert porous NiTi surfaces with low Ni release and corrosion, as well as bioactive surfaces to enhance and accelerate biological activity; (ii) In vitro and in vivo biocompatibility studies to confirm the long-term safety of porous NiTi implants; and (iii) biological evaluations for specific applications, such as in intervertebral fusion devices and bone tissue scaffolds. Possible future directions for bio-performance and processing studies are discussed that could lead to optimized porous NiTi implants. PMID:18348912

  14. Electrochromic performances of nonstoichiometric NiO thin films

    International Nuclear Information System (INIS)

    Moulki, H.; Faure, C.; Mihelčič, M.; Vuk, A. Šurca; Švegl, F.; Orel, B.; Campet, G.; Alfredsson, M.; Chadwick, A.V.; Gianolio, D.; Rougier, A.

    2014-01-01

    Electrochromic (EC) performances of Ni 3+ containing NiO thin films, called modified NiO thin films, prepared either by pulsed laser deposition or by chemical route are reported. When cycled in lithium based electrolyte, the comparison of the EC behavior of nonstoichiometric NiO thin films points out a larger optical contrast for the films synthesized by chemical route with the absence of an activation period on early electrochemical cycling due in particular to a larger porosity. Herein we demonstrate faster kinetics for modified NiO thin films cycled in lithium ion free electrolyte. Finally, X-ray absorption spectroscopy is used for a preliminary understanding of the mechanism involved in this original EC behavior linked to the film characteristics including their disorder character, the presence of Ni 3+ and their porous morphology. - Highlights: • Nonstoichiometric NiO thin films • Electrochromic performances in lithium free electrolyte • X-ray absorption spectroscopy investigation of as-deposited films and upon cycling

  15. Synthesis of FeCoNi nanoparticles by galvanostatic technique

    International Nuclear Information System (INIS)

    Budi, Setia; Hafizah, Masayu Elita; Manaf, Azwar

    2016-01-01

    Soft magnetic nanoparticles of FeCoNi have been becoming interesting objects for many researchers due to its potential application in electronic devices. One of the most promising methods for material preparation is the electrodeposition which capable of growing nanoparticles alloy directly onto the substrate. In this paper, we report our electrodeposition studies on nanoparticles synthesis using galvanostatic electrodeposition technique. Chemical composition of the synthesized FeCoNi was successfully controlled through the adjustment of the applied currents. It is revealed that the content of each element, obtained from quantitative analysis using atomic absorption spectrometer (AAS), could be modified by the adjustment of current in which Fe and Co content decreased at larger applied currents, while Ni content increased. The nanoparticles of Co-rich FeCoNi and Ni-rich FeCoNi were obtained from sulphate electrolyte at the range of applied current investigated in this work. Broad diffracted peaks in the X-ray diffractograms indicated typical nanostructures of the solid solution of FeCoNi.

  16. Microstructural characterisation of Ni75Al25 and Ni31.5Al68.5 powder particles produced by gas atomisation

    International Nuclear Information System (INIS)

    García-Escorial, A.; Lieblich, M.

    2014-01-01

    Highlight: ► Successful production of gas atomised Ni75Al25 and Ni31.5Al68.5 powder particles. ► Characterization of the as-solidified microstructure of 75 Al 25 and Ni 31.5 Al 68.5 at.% powder particles below 100 μm in size have been studied. The gas atomised Ni 75 Al 25 powder particles are mainly spherical. The solidification of this alloy is very fast, and its microstructure consists of a dendrite and lamellar structure of partially ordered γ-(Ni), γ′-Ni 3 Al L1 2 phase, and β-NiAl phase. The order increases with the powder particle size. The gas atomised Ni 31.5 Al 68.5 powder particles are also spherical in shape. The microstructure consists of Ni 2 Al 3 dendrites with interdendritic peritectic NiAl 3 and eutectic NiAl 3 + α-Al. The amount of the Ni 2 Al 3 increases as the cooling rate increases. NiAl phase is absent in the gas atomised Ni 31.5 Al 68.5 powder

  17. Determination of 63Ni and 59Ni in spent ion-exchange resin and activated charcoal from the IEA-R1 nuclear research reactor

    International Nuclear Information System (INIS)

    Taddei, M.H.T.; Macacini, J.F.; Vicente, R.; Marumo, J.T.; Sakata, S.K.; Terremoto, L.A.A.

    2013-01-01

    A radiochemical method has been adapted to determine 59 Ni and 63 Ni in samples of radioactive wastes from the water cleanup system of the IEA-R1 nuclear research reactor. The process includes extraction chromatographic resin with dimethylglyoxime (DMG) as a functional group. Activity concentrations of 59 Ni and 63 Ni were measured, respectively, by X-ray spectrometry and liquid scintillation counting, whereas the chemical yield was determined by ICP-OES. The average ratio of measured activity concentrations of 63 Ni and 59 Ni agree well with theory. - Highlights: ► A radiochemical method was adapted for determination of 59 Ni and 63 Ni. ► 59 Ni and 63 Ni were determined in samples of radioactive wastes from research reactor. ► The activity concentration of 59 Ni was measured by X-ray spectrometry. ► The activity concentration of 63 Ni was measured by liquid scintillation counting. ► Average ratio of measured activity concentrations of 63 Ni and 59 Ni agrees with theory

  18. Synthesis of porous NiS thin films on Ni foam substrate via an electrodeposition route and its application in lithium-ion batteries

    International Nuclear Information System (INIS)

    Ruan, Hongcheng; Li, Yafeng; Qiu, Heyuan; Wei, Mingdeng

    2014-01-01

    Graphical abstract: The porous NiS thin films on Ni foam substrate were fabricated for the first time by an electrodeposition route and then used directly as an anode for lithium-ion batteries, which exhibited larger capacity and good cycle stability. -- Highlights: • The porous NiS on Ni foam substrate were fabricated by an electrodeposition route. • NiS/Ni thin films were used as the electrode material in lithium-ion batteries. • The cell fabricated by NiS/Ni exhibited larger capacity and good cycle stability. -- Abstract: Electrodeposition, a convenient approach, has been used for fabricating porous NiS thin films on Ni foam substrate. The obtained NiS/Ni thin films were characterized by scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy and energy dispersive spectrometry. Furthermore, the electrodeposited NiS/Ni thin films were first used as the anode for lithium-ion intercalation and exhibited large capacities and good cycling stability

  19. Study of hyperfine interactions in intermetallic compounds Gd(Ni,Pd,Cu)In, Tb(Ni,Pd)In, Dy(Ni,Pd)In and Ho(Ni,Pd)In; Estudo de interacoes hiperfinas em compostos intermetalicos Gd(Ni,Pd,Cu)In, Tb(Ni,Pd)In, Dy(Ni,Pd)In e Ho(Ni,Pd)In

    Energy Technology Data Exchange (ETDEWEB)

    Lapolli, Andre Luis

    2006-07-01

    Systematic behavior of magnetic hyperfine field (B{sub hf}) in the intermetallic compounds Gd(Ni,Pd,Cu)In Tb(Ni,Pd)In, Dy(Ni,Pd)In and Ho(Ni,Pd)In was studied by Perturbed Gamma-Gamma Angular Correlation spectroscopy. The measurements of B{sub hf} were carried out at the rare earth atom and in sites using the nuclear probes {sup 140}Ce and {sup 11}'1Cd respectively. The variation of hyperfine field with temperature, in most cases, follows the Brillouin function predicted from the molecular field theory. The hyperfine field values at rare earth atom sites obtained from {sup 140}Ce probe as well as at in sites obtained from {sup 111}Cd probe for each series of compounds were extrapolated to zero Kelvin B{sub hf}(T=0) from these curves. These values were compared with the values of the literature for other compounds containing the same rare earth element and all of them show a linear relationship with the ordering temperature. This indicates that the main contribution to B{sub hf} comes from the conduction electron polarization (CEP) through Fermi contact interaction and the principal mechanism of magnetic interaction in these compounds can be described by the RKKY type interaction. The values of B{sub hf}(T=0) for each family of intermetallic compounds RNiIn and RPdIn when plotted as a function of 4f spin projection of rare earth element also shows a linear relationship. Exceptions are the results for the compounds RNiIn obtained with {sup 111}Cd probe where a small deviation from linearity is observed. The results of the measurements carried out with the {sup 111}Cd probe were also analyzed to obtain the hyperfine parameters of the quadrupole interaction as a function of temperature for RPdln and GdNiIn compounds. The results show that for the compound GdPdIn there might be some Gd-In disorder at high temperature. (author)

  20. First observation of two-proton radioactivity in 48Ni

    Energy Technology Data Exchange (ETDEWEB)

    Pomorski, M. [University of Warsaw; Pfutzner, M. [University of Warsaw; Dominik, W. [University of Warsaw; Grzywacz, Robert Kazimierz [ORNL; Baumann, T. [Michigan State University, East Lansing; Berryman, J. S. [Michigan State University, East Lansing; Czyrkowski, H. [University of Warsaw; Dabrowski, Ryszard [Warsaw University; Ginter, T. N. [Michigan State University, East Lansing; Johnson, James W [ORNL; Kaminski, A. [PAN, Krakow, Poland; Kuzniak, A. [University of Tennessee, Knoxville (UTK); Larson, N. [Michigan State University, East Lansing; Liddick, S. N. [Michigan State University, East Lansing; Madurga, M [University of Tennessee, Knoxville (UTK); Mazzocchi, C. [University of Warsaw; Miernik, K. [Oak Ridge National Laboratory (ORNL); Miller, D [University of Tennessee, Knoxville (UTK); Paulauskas, S. [University of Tennessee, Knoxville (UTK); Pereira, J. [National Superconducting Cyclotron Laboratory (NSCL); Rykaczewski, Krzysztof Piotr [ORNL; Stolz, A. [Michigan State University, East Lansing; Suchyta, S. [Michigan State University, East Lansing

    2011-01-01

    The decay of the extremely neutron deficient 48Ni was studied by means of an imaging time projection chamber which allowed the recording of tracks of charged particles. Decays of 6 atoms were observed. Four of them clearly correspond to two-proton radioactivity providing the first direct evidence for this decay mode in 48Ni. Two decays represent -delayed proton emission. The half-life of 48Ni is determined to be T1=2 = 2:1+1:4 0:4 ms.

  1. Niños maltratados: Un problema que insiste.

    OpenAIRE

    EM Gagneten

    1992-01-01

    En este trabajo se analiza el maltrato a los niños a partir de la evaluación del vínculo entre padres e hijos, considerando en particular lo ocurrido en periodos de dictadura, aplicando una ética terapéutica orientada a posibilitar un mejor handicap en la vida de estos niños El trabajo se realizó en en el Hospital de Niños Zona Norte de la ciudad de Rosario (República Argentina) entre 1986 y 1989, aplicando un enfoque multidisciplinario.

  2. Abuso sexual en la niñez

    OpenAIRE

    Ricardo García-Jaime

    2013-01-01

    El abuso sexual en la niñez se presenta en dos grandes modalidades: el abuso sexual familiar (también conocido como incesto), y la explotación sexual comercial de niños/as y adolescentes (conocida como trata de personas con fines sexuales). Ambas modalidades afectan a millones de niños/as en todo el mundo. El objetivo de este artículo es ofrecer una panorámica en torno al abuso sexual que ocurre al interior de las fami-lias. Para ello se revisan algunos conceptos en torno al abuso, sus princi...

  3. Brasil: Favela, niños y video

    Directory of Open Access Journals (Sweden)

    Denise María Cogo

    2015-01-01

    Full Text Available La experiencia Video-Niños surgió en 1990 con un grupo de niños afro-brasileños de 8 a 14 años que mantienen vivos elementos de su cultura en la música y la religión. El trabajo abarcó la producción de una telenovela (Gente rica, un telediario (Niño-reportero y un show de variedades donde la creatividad y participación fueron evidentes.

  4. First principles calculations on Ni impurities in Cu clusters

    International Nuclear Information System (INIS)

    Ricardo-Chavez, J.L.; Pastor, G.M.

    2005-01-01

    Structural and magnetic properties of small NiCu N-1 clusters are determined in the framework of Kohn-Sham density-functional theory (DFT). Besides some changes in bond length, the calculated structures for N= N . For the optimal NiCu N-1 geometry the Ni ion occupies the most-coordinated atomic position and the ground-state corresponds to a minimum-spin configuration (S z =0 or 12). Interesting correlations between cluster structure and magnetism are revealed by varying the total spin. The possible consequences of electron correlations and finite-temperature effects are briefly discussed

  5. Hydride phase equilibria in V-Ti-Ni alloy membranes

    Energy Technology Data Exchange (ETDEWEB)

    Dolan, Michael D., E-mail: michael.dolan@csiro.au [CSIRO Energy, Pullenvale, Queensland (Australia); Kochanek, Mark A.; Munnings, Christopher N. [CSIRO Energy, Pullenvale, Queensland (Australia); McLennan, Keith G. [Queensland Micro- and Nanotechnology Centre, Griffith University, Nathan, Queensland (Australia); Viano, David M. [CSIRO Energy, Pullenvale, Queensland (Australia)

    2015-02-15

    Highlights: • V{sub 70}Ti{sub 15}Ni{sub 15} (at.%) comprises a vanadium solid solution plus NiTi and NiTi{sub 2}. • Dissolution of Ni and Ti into vanadium solid solution increase critical temperature for BCT β-hydride formation. • Three V{sub SS} hydride phase fields were observed: BCC, BCC + BCT, BCT + BCT. • NiTi and NiTi{sub 2} phases do not stabilise the alloy against brittle failure. - Abstract: Vanadium is highly permeable to hydrogen which makes it one of the leading alternatives to Pd alloys for hydrogen-selective alloy membrane applications, but it is prone to brittle failure through excessive hydrogen absorption and transitions between the BCC α and BCT β phases. V-Ti-Ni alloys are a prospective class of alloy for hydrogen-selective membrane applications, comprising a highly-permeable vanadium solid solution and several interdendritic Ni-Ti compounds. These Ni-Ti compounds are thought to stabilise the alloy against brittle failure. This hypothesis was investigated through a systematic study of V{sub 70}Ti{sub 15}Ni{sub 15} by hydrogen absorption and X-ray diffraction under conditions relevant to membrane operation. Dissolved hydrogen concentration in the bulk alloy and component phases, phase identification, thermal and hydrogen-induced expansion, phase quantification and hydride phase transitions under a range of pressures and temperatures have been determined. The vanadium phase passes through three different phase fields (BCC, BCC + BCT, BCT + BCT) during cooling under H{sub 2} from 400 to 30 °C. Dissolution of Ni and Ti into the vanadium phase increases the critical temperature for β-hydride formation from <200 to >400 °C. Furthermore, the Ni-Ti phases also exhibit several phase transitions meaning their ability to stabilise the alloy is questionable. We conclude that this alloy is significantly inferior to V with respect to its stability when used as a hydrogen-selective membrane, but the hydride phase transitions suggest potential

  6. Mechanical and structural properties of sputtered Ni/Ti multilayers

    Energy Technology Data Exchange (ETDEWEB)

    Senthil Kumar, M.; Boeni, P.; Tixier, S.; Clemens, D.; Horisberger, M. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1997-09-01

    Ni/Ti bilayers have been prepared by dc-magnetron sputtering in order to study their mechanical and structural properties. A remarkable reduction of stress is observed when the Ni layers are sputtered reactively in argon with a high partial pressure of air. The high angle x-ray diffraction studies show a tendency towards amorphisation of the Ni layers with increasing air flow. The low angle measurements indicate a substantial reduction of interdiffusion resulting in smoother interfaces with increasing air content. (author) 2 figs., 2 refs.

  7. Theory of Valence Transition in BiNiO$_3$

    OpenAIRE

    Naka, Makoto; Seo, Hitoshi; Motome, Yukitoshi

    2015-01-01

    Motivated by the colossal negative thermal expansion recently found in BiNiO$_3$, the valence transition accompanied by the charge transfer between the Bi and Ni sites is theoretically studied. We introduce an effective model for Bi-$6s$ and Ni-$3d$ orbitals with taking into account the valence skipping of Bi cations, and investigate the ground-state and finite-temperature phase diagrams within the mean-field approximation. We find that the valence transition is caused by commensurate locking...

  8. Determination of 63Ni and 59Ni in spent ion-exchange resin and activated charcoal from the IEA-R1 nuclear research reactor.

    Science.gov (United States)

    Taddei, M H T; Macacini, J F; Vicente, R; Marumo, J T; Sakata, S K; Terremoto, L A A

    2013-07-01

    A radiochemical method has been adapted to determine (59)Ni and (63)Ni in samples of radioactive wastes from the water cleanup system of the IEA-R1 nuclear research reactor. The process includes extraction chromatographic resin with dimethylglyoxime (DMG) as a functional group. Activity concentrations of (59)Ni and (63)Ni were measured, respectively, by X-ray spectrometry and liquid scintillation counting, whereas the chemical yield was determined by ICP-OES. The average ratio of measured activity concentrations of (63)Ni and (59)Ni agree well with theory. Copyright © 2013 Elsevier Ltd. All rights reserved.

  9. Template-Mediated Ni(II) Dispersion in Mesoporous SiO2for Preparation of Highly Dispersed Ni Catalysts: Influence of Template Type.

    Science.gov (United States)

    Ning, Xin; Lu, Yiyuan; Fu, Heyun; Wan, Haiqin; Xu, Zhaoyi; Zheng, Shourong

    2017-06-07

    Supported Ni catalysts on three mesoporous SiO 2 supports (i.e., SBA-15, MCM-41, and HMS) were prepared using a solid-state reaction between Ni(NO 3 ) 2 and organic template-occluded mesoporous SiO 2 . For comparison, supported Ni catalysts on mesoporous SiO 2 synthesized by the conventional impregnation method were also included. The catalysts were characterized by scanning electron microscopy, X-ray diffraction, UV-vis diffuse reflectance spectroscopy, N 2 adsorption, X-ray photoelectron spectroscopy, H 2 temperature-programmed reduction, transmission electron microscopy, and transmission electron microscopy-energy-dispersive X-ray. The catalytic properties of the catalysts were evaluated using gas-phase catalytic hydrodechlorination of 1,2-dichloroethane. The results showed that upon grinding Ni(NO 3 ) 2 with template-occluded mesoporous SiO 2 , strong coordination between Ni 2+ and dodecylamine was identified in the Ni(NO 3 ) 2 -HMS system. Additionally, the results of H 2 temperature-programmed reduction revealed that NiO in calcined NiO/HMS was reduced at higher temperature than those in calcined NiO/SBA-15 and NiO/MCM-41, reflecting the presence of a strong interaction between NiO and mesoporous SiO 2 in NiO/HMS. Consistently, the average particle sizes of metallic Ni were found to be 2.7, 3.4, and 9.6 nm in H 2 -reduced Ni/HMS, Ni/SBA-15, and Ni/MCM-41, respectively, indicative of a much higher Ni dispersion in Ni/HMS. For the catalytic hydrodechlorination of 1,2-dichloroethane, Ni/MCM-41 synthesized by the solid-state reaction method exhibited a catalytic activity similar to that prepared by the impregnation method, while higher catalytic activities were observed on Ni/HMS and Ni/SBA-15 than on their counterparts prepared by the impregnation method. Furthermore, a higher conversion was identified on Ni/HMS than on Ni/SBA-15 and Ni/MCM-41, highlighting the importance of template type for the preparation of highly dispersed metal catalysts on mesoporous Si

  10. Wetting - Dewetting Transitions of Au/Ni Bilayer Films

    Science.gov (United States)

    Cen, Xi

    Thin films deposited at low temperatures are often kinetically constrained and will dewet the underlying substrate when annealed. Solid state dewetting is driven by the minimization of the total free energy of thin film-substrate interface and free surface, and mostly occurs through surface diffusion. Dewetting is a serious concern in microelectronics reliability. However, it can also be utilized for the self-assembly of nanostructures with potentials in storage, catalysis, or transistors. Therefore, a fundamental understanding of the dewetting behavior of thin metal films is critical for improving the thermal stability of microelectronics and controlling the order of self-assembled nanostructures. Mechanisms for dewetting of single layer films have been studied extensively. However little work has been reported on multilayer or alloyed thin films. In the thesis, the solid state dewetting of Au/Ni bilayer films deposited on SiO2/Si substrates was investigated by scanning electron microscopy (SEM), transmission electron microscopy (TEM) and aberration corrected scanning TEM (STEM). Ex-situ SEM and TEM studies were performed with in-situ TEM heating characterization to identify the mechanisms during the dewetting process of Au/Ni bilayer films. The solid state dewetting of Au/Ni bilayer films from SiO2/Si substrates exhibits both homogeneous and localized dewetting of Ni and long-edge retraction for Au under isothermal annealing condition. The top Au layer retracts up to 1 mm from the edge of the substrate wafer to reduce the energetically unfavored Au/Ni interface. In contrast, Ni dewets and agglomerates locally due to its limited diffusivity compared to Au. Film morphology and local chemical composition varies significantly across hundreds of microns along the direction normal to the retracting edge. Besides long range edge receding, localized dewetting shows significant changes in film morphology and chemical distribution. Both Au and Ni shows texturing. Despite

  11. Effects of Ni-5%RExOy Composite Additives on Electrochemical Hydrogen Storage Performances of Mg2Ni

    Directory of Open Access Journals (Sweden)

    ZHANG Guo-fang

    2017-11-01

    Full Text Available The Ni-5%RExOy (CeO2, La2O3, Eu2O3 as composite additives, Mg2Ni-Ni-5%RExOy composites were prepared by the ball milling method. The effects of different additives on the structure, morphology, electrochemistry and kinetic properties of Mg2Ni alloy were studied systematically. The results show that composite additives can improve the proportion of amorphous and nanocrystalline structure of Mg2Ni alloy. The particle size is homogeneous but the agglomeration is observed in the sample with Ni-5%CeO2 additives. The composites with additives show higher maximum discharge capacity and better cycle stabilities. All of these three kinds of composite additives can improve the kinetic properties of the composites effectively, including optimizing the charge-transfer ability, the reversibility of the electrochemical reaction on the alloy surface, and enhancing the diffusion coefficients of H atoms in the bulk of alloy. Among these three kinds of additives, Ni-5%CeO2 additive shows the best catalysis effect on promoting the kinetic properties of the composites.

  12. Migración con rostro de niños, niñas y adolescentes

    Directory of Open Access Journals (Sweden)

    Álvaro Caballeros

    2011-12-01

    Full Text Available El artículo presenta un análisis descriptivo de los niños, niñas y adolescentes migrantes no acompañados que fueron deportados y atendidos por el Hogar Casa Nuestras Raíces de la Secretaría de Bienestar Social de la Secretaría de Bienestar Social de Guatemala. La información presentada se deriva de los registros del Centro, de entrevistas realizadas con los niños, niñas y adolescentes atendidos en el mismo, y en datos oficiales del Instituto Nacional de Migración de México. El artículo presenta un panorama de la experiencia de la niñez migrante, las circunstancias del viaje, elproceso de deportación y de reinserción en sus países de origen. El autor señala que la atención y protección que reciben los niños, niñas y adolescentes por parte de autoridades migratorias y sociales ha mejorado considerablemente, sin embargo, no se adecúa al enfoque de derechos humanos.

  13. Hydrogen sensing by sol–gel grown NiO and NiO:Li thin films

    Energy Technology Data Exchange (ETDEWEB)

    Sta, I., E-mail: imenstalpv@yahoo.fr [Photovoltaic Laboratory, Research and Technology Centre of Energy, Borj-Cedria Science and Technology Park, BP 95, 2050 Hammam-Lif (Tunisia); Jlassi, M. [Photovoltaic Laboratory, Research and Technology Centre of Energy, Borj-Cedria Science and Technology Park, BP 95, 2050 Hammam-Lif (Tunisia); Kandyla, M. [National Hellenic Research Foundation, Theoretical and Physical Chemistry Institute, 48 Vasileos Konstantinou Ave., 11635 Athens (Greece); Hajji, M. [Photovoltaic Laboratory, Research and Technology Centre of Energy, Borj-Cedria Science and Technology Park, BP 95, 2050 Hammam-Lif (Tunisia); National School of Electronics and Telecommunications of Sfax, Sfax Technopark, BP 1163, CP 3018 Sfax (Tunisia); Koralli, P. [National Hellenic Research Foundation, Theoretical and Physical Chemistry Institute, 48 Vasileos Konstantinou Ave., 11635 Athens (Greece); Allagui, R. [Photovoltaic Laboratory, Research and Technology Centre of Energy, Borj-Cedria Science and Technology Park, BP 95, 2050 Hammam-Lif (Tunisia); Kompitsas, M. [National Hellenic Research Foundation, Theoretical and Physical Chemistry Institute, 48 Vasileos Konstantinou Ave., 11635 Athens (Greece); Ezzaouia, H. [Photovoltaic Laboratory, Research and Technology Centre of Energy, Borj-Cedria Science and Technology Park, BP 95, 2050 Hammam-Lif (Tunisia)

    2015-03-25

    Highlights: • NiO:Li sensors were able to detect 1000 ppm hydrogen concentration in air. • The operation temperature was as low as 140 °C. • Performance of sensors was significantly improved by Li doping. - Abstract: Hydrogen sensors have been prepared using nickel oxide (NiO) and lithium-doped nickel oxide (NiO:Li) thin films, deposited on glass substrates by the sol–gel spin coating technique. The surface morphology, structure, optical and electrical properties of the obtained films were studied. Hydrogen sensing results are presented for three operating temperatures (140, 160, and 180 °C) and for hydrogen concentrations ranging from 1000 to 15,000 ppm in synthetic air. The NiO and NiO:Li (2% and 8% doping concentrations) sensors show maximum responses for the operating temperature of 180 °C. When tested at different hydrogen concentrations in air, the lithium-doped NiO sensors showed a higher response than the undoped NiO films.

  14. Hydrogen sensing by sol–gel grown NiO and NiO:Li thin films

    International Nuclear Information System (INIS)

    Sta, I.; Jlassi, M.; Kandyla, M.; Hajji, M.; Koralli, P.; Allagui, R.; Kompitsas, M.; Ezzaouia, H.

    2015-01-01

    Highlights: • NiO:Li sensors were able to detect 1000 ppm hydrogen concentration in air. • The operation temperature was as low as 140 °C. • Performance of sensors was significantly improved by Li doping. - Abstract: Hydrogen sensors have been prepared using nickel oxide (NiO) and lithium-doped nickel oxide (NiO:Li) thin films, deposited on glass substrates by the sol–gel spin coating technique. The surface morphology, structure, optical and electrical properties of the obtained films were studied. Hydrogen sensing results are presented for three operating temperatures (140, 160, and 180 °C) and for hydrogen concentrations ranging from 1000 to 15,000 ppm in synthetic air. The NiO and NiO:Li (2% and 8% doping concentrations) sensors show maximum responses for the operating temperature of 180 °C. When tested at different hydrogen concentrations in air, the lithium-doped NiO sensors showed a higher response than the undoped NiO films

  15. Pressure-induced development of bonding in NiAs type compounds and polymorphism of NiP

    Energy Technology Data Exchange (ETDEWEB)

    Dera, Przemyslaw; Lazarz, John D.; Lavina, Barbara (UC); (UNLV)

    2016-07-29

    A reversible, displacive, pressure-induced structural phase transition has been found to occur in nickel monophosphide NiP at approximately 3.5 GPa by means of in situ synchrotron single-crystal X-ray diffraction. The new phase, with Pearson symbol oC56, assumes an orthorhombic structure with Cmc2{sub 1} space group and unit cell parameters a=23.801(2) {angstrom}, b=5.9238(6) {angstrom}, and c=4.8479(4) {angstrom} at 5.79 GPa. The high-pressure phase is a superstructure of the ambient, oP16 phase with multiplicity of 3.5. The phosphorous sublattice gradually converts from the net of isolated P{sub 2} dimers found in the ambient NiP, towards zig-zag polymeric P{infinity} chains found in MnP-type structures. The transformation involves development of triatomic phosphorous clusters and interconnected Ni slabs with diamondoid topology. The high-pressure phase, which represents intermediate polymerization step, is a commensurately modulated superstructure of the NiAs aristotype. The phase transformation in NiP bears resemblance to the effect of successive substitution of Si or Ge in place of P found in the series of stoichiometric inhomogeneous linear structures in ternary NiP{sub 1-x}Si{sub x} and NiP{sub 1-x}Ge{sub x} systems.

  16. In Situ Synthesis and Electrophoretic Deposition of NiO/Ni Core-Shell Nanoparticles and Its Application as Pseudocapacitor

    Directory of Open Access Journals (Sweden)

    Joaquin Yus

    2017-11-01

    Full Text Available A simple, low cost and transferable colloidal processing method and the subsequent heat treatment has been optimized to prepare binder-free electrodes for their application in supercapacitors. NiO/Ni core–shell hybrid nanostructures have been synthetized by heterogeneous precipitation of metallic Ni nanospheres onto NiO nanoplatelets as seed surfaces. The electrophoretic deposition (EPD has been used to shape the electroactive material onto 3D substrates such as Ni foams. The method has allowed us to control the growth and the homogeneity of the NiO/Ni coatings. The presence of metallic Nickel in the microstructure and the optimization of the thermal treatment have brought several improvements in the electrochemical response due to the connectivity of the final microstructure. The highest specific capacitance value has been obtained using a thermal treatment of 325 °C during 1 h in Argon. At this temperature, necks formed among ceramic-metallic nanoparticles preserve the structural integrity of the microstructure avoiding the employment of binders to enhance their connectivity. Thus, a compromise between porosity and connectivity should be established to improve electrochemical performance.

  17. Effect of interface intermixing on giant magnetoresistance in NiFe/Cu and Co/NiFe/Co/Cu multilayers

    International Nuclear Information System (INIS)

    Nagamine, L.C.C.M.; Biondo, A.; Pereira, L.G.; Mello, A.; Schmidt, J.E.; Chimendes, T.W.; Cunha, J.B.M.; Saitovitch, E.B.

    2003-01-01

    This article reports on the important influence of the spontaneously built-in paramagnetic interfacial layers on the magnetic and magnetoresistive properties of NiFe/Cu and Co/NiFe/Co/Cu multilayers grown by magnetron sputtering. A computational simulation, based on a semiclassical model, has been used to reproduce the variations of the resistivity and of the magnetoresistance (MR) amplitude with the thickness of the NiFe, Cu, and Co layers. We showed that the compositionally intermixed layers at NiFe/Cu interfaces, which are paramagnetic, reduce the flow of polarized electrons and produce a masking on the estimated mean-free path of both types of electrons due to the reduction of their effective values, mainly for small NiFe thickness. Moreover, the transmission coefficients for the electrons decrease when Fe buffer layers are replaced by NiFe ones. This result is interpreted in terms of the variations of the interfacial intermixing and roughness at the interfaces, leading to an increase of the paramagnetic interfacial layer thickness. The effect provoked by Co deposition at the NiFe 16 A/Cu interfaces has also been investigated. The maximum of the MR amplitudes was found at 5 A of Co, resulting in the quadruplication of the MR amplitude. This result is partially attributed to the interfacial spin-dependent scattering due to the increase of the magnetic order at interfaces. Another effect observed here was the increase of the spin-dependent scattering events in the bulk NiFe due to a larger effective NiFe thickness, since the paramagnetic interfacial layer thickness is decreased

  18. Magnetoimpedance of thin film meander with composite coating layer containing Ni nanoparticles

    NARCIS (Netherlands)

    Lodewijk, K. J.; Fernandez, E.; Garcia-Arribas, A.; Kurlyandskaya, G. V.; Lepalovskij, V. N.; Safronov, A. P.; Kooi, B. J.

    2014-01-01

    Giant magnetoimpedance (GMI) [FeNi/Cu](4)/FeNi/Cu/[FeNi/Cu](4)/FeNi sensing meander elements were designed and tested aiming to develop a new instrumentation for characterization of polymer/magnetic nanoparticles composites. Acrylic copolymer of 95% of butyl methacrylate and 5% of methacrylic acid

  19. Optimal synthesis of a Ni(II)-dimethylglyoxime ion-imprinted polymer ...

    African Journals Online (AJOL)

    A Ni(II)-dimethylglyoxime ion-imprinted polymer {Ni(II)-DMG IIP} was optimised by the uniform design experimental method and used to adsorb Ni(II) ions from ... The optimal molar ratios of crosslinker to monomer, monomer to template and nickel(II) sulphate hexahydrate (NiSO4.6H2O) to 4-vinylpyridine to dimethylglyoxime ...

  20. Ni-toughened nc-TiN/a-SiNx nanocomposite thin films

    NARCIS (Netherlands)

    Zhang, Sam; Sun, Deen; Fu, Yongqing; Pei, Y.T.; Hosson, J.Th.M. De

    2005-01-01

    Nanocomposite nc-TiN/a-SiNx thin films containing Ni up to similar to 40 at.% were prepared by co-sputtering of Ti, TiNi and Si3N4 targets in ArN2 gas atmosphere. Adjusting TiNi/(Ti+TiNi) target power ratio altered chemical composition, microstructure and consequently mechanical properties. X-ray

  1. Improvement of the wear resistance of electroplated Au-Ni coatings by Zr ion bombardment of Ni-B sublayer

    International Nuclear Information System (INIS)

    Lyazgin, Alexander; Shugurov, Artur; Sergeev, Viktor; Neufeld, Vasily; Panin, Alexey; Shesterikov, Evgeny

    2015-01-01

    The effect of bombardment of the Ni-B sublayer by Zr ion beams on the surface morphology and tribomechanical properties of Au-Ni coatings was investigated. It was found that the treatment has no significant effect on the surface roughness and grain size of the Au-Ni coatings, while it provides essential reducing of their friction coefficient and improvement of wear resistance. It is shown that increased wear resistance of these coatings was caused by their strain hardening resulted from localization of plastic strain. The optimal Zr fluence were determined that provide the maximum reduction of linear wear of the coatings

  2. Hierarchically porous Ni monolith@branch-structured NiCo2O4 for high energy density supercapacitors

    Directory of Open Access Journals (Sweden)

    Mengjie Xu

    2016-06-01

    Full Text Available A variety of NiCo2O4 nanostrucutures ranging from nanowire to nanoplate and branched structures were successfully prepared via a simple hydrothermal process. The experimental results show that NiCo2O4 with branched structures possesses the best overall electrochemical performance. The improvement of energy density was explored in terms of hierarchically three-dimensional (3D metal substrates and a high specific area capacitance, and area energy density is obtained with hierarchically porous Ni monolith synthesized through a controlled combustion procedure.

  3. Linear thermal expansion coefficient of cast Fe-Ni invar and Fe-Ni-Co superinvar alloys

    International Nuclear Information System (INIS)

    Ogorodnikova, O.M.; Chermenskaya, E.V.; Rabinovich, S.V.; Grachev, S.V.

    1999-01-01

    Cast invar alloys Fe-Ni (28-35 wt. % Ni) are investigated using metallography, dilatometry and X-ray methods as soon as the crystallization is completed and again after low-temperature treatment resulting in martensitic transformation in low nickel alloys. Nickel distribution in a cast superinvar Fe-32% Ni-4% Co is studied by means of X-ray spectrum microanalysis. The results obtained permit the correction of model concepts about cast invars and the estimate of a coefficient of linear expansion depending on phase composition and nickel microsegregation [ru

  4. Production and identification of heavy Ni isotopes: Evidence for the doubly magic nucleus 7828Ni. Short note

    International Nuclear Information System (INIS)

    Engelmann, C.; Ameil, F.; Bernas, M.; Heinz, A.; Janas, Z.; Kozhuharov, C.; Miehe, C.; Pfuetzner, M.; Roehl, C.; Stephan, C.; Tassan-Got, L.; Voss, B.

    1995-07-01

    We report the first observation of the doubly magic nucleus 78 Ni 50 and the heavy isotopes 77 Ni, 73,74,75 Co, 80 Cu. The isotopes were produced by nuclear fission in collisions of 750 A.MeV projectiles of 238 U on Be target nuclei. The fully-stripped fission products were separated in-flight by the fragment separator FRS and identified event-by-event by measuring the magnetic rigidity, the trajectory, the energy deposit, and the time of flight. Production cross-sections and fission yields for the new Ni-isotopes are given. (orig.)

  5. Probing the semi-magicity of $^{68}$Ni via the $^{66}$Ni(t,p)$^{68}$Ni two-neutron transfer reaction in inverse kinematics

    CERN Document Server

    AUTHOR|(CDS)2079390; Van Duppen, Piet

    The region around the nucleus $^{68}$Ni, with a shell closure for its protons at Z=28 and a harmonic oscillator shell gap for its neutrons at N=40, has drawn considerable interest over the past decades. $^{68}$Ni has properties that are typical for a doubly-magic nucleus, such as a high excitation energy and low B($E2:2^{+} \\rightarrow 0^{+}$) transition probability for the first excited 2$^{+}$ level and a 0$^{+}$ level as the first excited state. However, it has been suggested that the magic properties of $^{68}$Ni arise due to the fact that the N=40 separates the negative parity $pf$-shell from the positive parity 1$g_{9/2}$ orbital, and indeed, recent mass measurements have not revealed a clear N = 40 energy gap. Despite all additional information that was acquired over the last decade the specific role of the N=40 is not yet understood and a new experimental approach to study $^{68}$Ni was proposed. Namely, a two-neutron transfer reaction on $^{66}$Ni to characterize and disentangle the structure of the ...

  6. Corrosion resistance of amorphous and crystalline Pd40Ni40P20 alloys in aqueous solutions

    DEFF Research Database (Denmark)

    Wu, Y.F.; Chiang, Wen-Chi; Chu, J.

    2006-01-01

    The corrosion behaviors of amorphous and crystalline Pd40Ni40P20 alloys in various aqueous solutions are reported in this paper. The corrosion resistance of crystalline (annealed) Pd40Ni40P20 is better than that of amorphous Pd40Ni40P20 in various corrosive solutions, due to crystalline Pd40Ni40P20...... and mainly consists of inert Pd5P2, NI3P, Ni2Pd2P and noble Pd phases. These inert and noble properties result in a higher corrosion resistance in crystalline Pd40Ni40P20....

  7. Electron energy-loss spectroscopy study of NiTi shape memory alloys

    International Nuclear Information System (INIS)

    Yang, Z.Q.; Schryvers, D.

    2008-01-01

    Electron energy loss spectroscopy (EELS) investigations were carried out on NiTi shape memory alloys. The composition of lens-shaped precipitates is determined to be Ni 4 Ti 3 by model-based EELS quantification, and the Ni-depleted zone in the B2 matrix surrounding the Ni 4 Ti 3 precipitates was quantified. The Young's modulus Y m of the B2 matrix with 51 at.% Ni and the Ni 4 Ti 3 precipitates was evaluated to be about 124 and 175 GPa, respectively. The intensity of the Ni L 3 edge for the precipitate is slightly higher than that for the B2 phase

  8. Effect of Ti seed and spacer layers on structure and magnetic properties of FeNi thin films and FeNi-based multilayers

    Energy Technology Data Exchange (ETDEWEB)

    Svalov, A.V., E-mail: andrey.svalov@ehu.es [Departamento de Electricidad y Electrónica, Universidad del País Vasco (UPV/EHU), 48080 Bilbao (Spain); Department of Magnetism and Magnetic Nanomaterials, Ural Federal University, 620002 Ekaterinburg (Russian Federation); Larrañaga, A. [SGIker, Servicios Generales de Investigación, Universidad del País Vasco (UPV/EHU), 48080 Bilbao (Spain); Kurlyandskaya, G.V. [Departamento de Electricidad y Electrónica, Universidad del País Vasco (UPV/EHU), 48080 Bilbao (Spain); Department of Magnetism and Magnetic Nanomaterials, Ural Federal University, 620002 Ekaterinburg (Russian Federation)

    2014-10-15

    Highlights: • Fe{sub 19}Ni{sub 81} films and FeNi-based multilayers were prepared by magnetron sputtering. • The samples were deposited onto glass substrates at room temperature. • Ti/FeNi films exhibit good (1 1 1) texture and crystallinity. • The thick Cu seed increases the coercive force of the magnetic layer. • The thin Ti spacer restores the magnetic softness of the Cu/Ti/FeNi multilayers. - Abstract: The microstructure and magnetic properties of sputtered permalloy films and FeNi-based multilayers prepared by magnetron sputtering have been studied. X-ray diffraction measurements indicate that Ti/FeNi films exhibit good (1 1 1) texture and crystallinity. Ti/FeNi bilayers with high crystallographic quality have relatively low resistivity. The Ti seed layer does not influence the magnetic properties of FeNi film in Ti/FeNi bilayers, but the thick Cu seed layer leads to an increase of the coercive force of the magnetic layer. For the FeNi films deposited on thick Cu seed layer, the (0 1 0) and (0 0 2) diffraction peaks of hcp nickel were clearly observed. The thin Ti spacer between Cu and FeNi layers prevents the formation of the nickel phase and restores the magnetic softness of the FeNi layer in the Cu/Ti/FeNi sample. Obtained results can be important for the development of multilayer sensitive elements for giant magnetoimpedance or magnetoresistance detectors.

  9. Magnetoimpedance of FeNi-based asymmetric sensitive elements

    Energy Technology Data Exchange (ETDEWEB)

    Chlenova, A.A., E-mail: chlenova.anna@gmail.com [Ural Federal University, Laboratory of Magnetic Sensorics, Lenin Ave. 51, 620083 Ekaterinburg, Russian Ferderation (Russian Federation); Immanuel Kant Baltic Federal University, Science and Technology Park “Fabrica”, Gaidara str. 6, Kaliningrad (Russian Federation); Svalov, A.V.; Kurlyandskaya, G.V. [Ural Federal University, Laboratory of Magnetic Sensorics, Lenin Ave. 51, 620083 Ekaterinburg, Russian Ferderation (Russian Federation); Universidad del País Vasco, UPV/EHU, Departamento de Electricidad y Electrónica, P.O. Box 644, Bilbao 48080 (Spain); Volchkov, S.O. [Ural Federal University, Laboratory of Magnetic Sensorics, Lenin Ave. 51, 620083 Ekaterinburg, Russian Ferderation (Russian Federation)

    2016-10-01

    [Ti/FeNi]{sub 5}/Ti/Cu/Ti/[FeNi/Ti]{sub x} (x=0–5) multilayers were prepared by sputtering. Their magnetic properties and magnetoimpedance were studied focusing on future technological applications. Both (ΔZ/Z){sub max} and (ΔR/R){sub max} values showed a tendency to decrease with a decrease of the number of magnetic layers of the top multilayer. Such a parameter as an even or odd number of layers is important for the MI value. In the field interval of technological interest all [Ti/FeNi]{sub 5}/Ti/Cu/Ti/[FeNi/Ti]{sub x} structures show similar sensitivities of about 70%/Oe for ΔR/R ratios but the lower the number of magnetic layers in the top multilayer, the higher the operating frequency. - Highlights: • Giant magnetoimpedance effect. • Non-symmetric multilayers sructure. • Biosensing.

  10. An investigation of fatigue in LIGA Ni MEMS thin films

    International Nuclear Information System (INIS)

    Allameh, S.M.; Lou, J.; Kavishe, F.; Buchheit, T.; Soboyejo, W.O.

    2004-01-01

    This paper presents results of an experimental study of fatigue in LIGA Ni micro-electro-mechanical systems (MEMS)/thin films produced by electroplating from a sulfamate bath at a current density of 50 mA/cm 2 . Following a brief description of microstructure and micro-tensile properties, the results of stress-life (S-N) experiments are presented for specimens with thicknesses of 70 and 270 μm. Specimens with the thicker cross-sections (270 μm thick) are shown to have comparable fatigue resistance to annealed bulk Ni in the as-plated condition. The thinner specimens (70 μm thick) have comparable fatigue resistance to hardened Ni, and better fatigue resistance than the thicker samples. The underlying fatigue fracture modes are elucidated via scanning electron microscopy. The implications of the results are then discussed for the failure analysis of LIGA Ni MEMS structures

  11. Mixed conductor anodes: Ni as electrocatalyst for hydrogen conversion

    DEFF Research Database (Denmark)

    Primdahl, S.; Mogensen, Mogens Bjerg

    2002-01-01

    Five types of anodes for solid oxide fuel cells (SOFC) are examined on an yttria-stabilised zirconia (YSZ) electrolyte by impedance spectroscopy at 850 degreesC in hydrogen. The examined porous anodes are a Ni/Zr(0.92)Y(0.16)O(2.08) (Ni/YSZ) cermet, a Ni/Ce(0.9)Gd(0.1)O(1.95) (Ni/CGI) cermet, a Ce...... conductors (MIEC's), distinctly in the low-frequency part of the impedance spectra. An effect of isotope exchange (H(2)/H(2)O to D(2)/D(2)O) is observed for all anodes. The low-frequency limitation is suggested to be hydrogen adsorption and/or dissociation on the surface of MIEC electrodes, (C) 2002 Elsevier...

  12. Magnetoimpedance of FeNi-based asymmetric sensitive elements

    International Nuclear Information System (INIS)

    Chlenova, A.A.; Svalov, A.V.; Kurlyandskaya, G.V.; Volchkov, S.O.

    2016-01-01

    [Ti/FeNi] 5 /Ti/Cu/Ti/[FeNi/Ti] x (x=0–5) multilayers were prepared by sputtering. Their magnetic properties and magnetoimpedance were studied focusing on future technological applications. Both (ΔZ/Z) max and (ΔR/R) max values showed a tendency to decrease with a decrease of the number of magnetic layers of the top multilayer. Such a parameter as an even or odd number of layers is important for the MI value. In the field interval of technological interest all [Ti/FeNi] 5 /Ti/Cu/Ti/[FeNi/Ti] x structures show similar sensitivities of about 70%/Oe for ΔR/R ratios but the lower the number of magnetic layers in the top multilayer, the higher the operating frequency. - Highlights: • Giant magnetoimpedance effect. • Non-symmetric multilayers sructure. • Biosensing.

  13. NiAl-based approach for rocket combustion chambers

    Science.gov (United States)

    Nathal, Michael V. (Inventor); Gayda, John (Inventor); Noebe, Ronald D. (Inventor)

    2005-01-01

    A multi-layered component, such as a rocket engine combustion chamber, includes NiAl or NiAl-based alloy as a structural layer on the hot side of the component. A second structural layer is formed of material selected from Ni-based superalloys, Co-based alloys, Fe-based alloys, Cu, and Cu-based alloys. The second material is more ductile than the NiAl and imparts increased toughness to the component. The second material is selected to enhance one or more predetermined physical properties of the component. Additional structural layers may be included with the additional material(s) being selected for their impact on physical properties of the component.

  14. Discovery of doubly-magic 48Ni at GANIL

    International Nuclear Information System (INIS)

    Chartier, M.; Blank, B.; Czajkowski, S.; Giovinazzo, J.; Pravikoff, M.S.; Thomas, J.-C.; France, G. de; Oliveira Santos, F. de; Lewitowicz, M.; Borcea, C.; Grzywacz, R.; Janas, Z.; Pfuetzner, M.

    2002-01-01

    An experiment was performed at GANIL using a high-intensity 58 Ni beam at 74.5 MeV/nucleon on a nickel target. The projectile fragments produced in the high-acceptance SISSI device were selected in the LISE3 spectrometer using the Wien filter. The detection setup performed an unambiguous identification of four 48 Ni implantation events. A lower limit of its half-life of the order of 0.5 μs and an estimate of the production cross section of about 0.05 pb were deduced. In addition, a few tens of 45 Fe and 49 Ni nuclei were implanted, which may give information on their decay modes. Besides, 48 Ni and 45 Fe are very good candidates for two-proton radioactivity, still to be observed

  15. Growth mechanism and magnon excitation in NiO nanowalls

    Directory of Open Access Journals (Sweden)

    Yang Chun

    2011-01-01

    Full Text Available Abstract The nanosized effects of short-range multimagnon excitation behavior and short-circuit diffusion in NiO nanowalls synthesized using the Ni grid thermal treatment method were observed. The energy dispersive spectroscopy mapping technique was used to characterize the growth mechanism, and confocal Raman scattering was used to probe the antiferromagnetic exchange energy J 2 between next-nearest-neighboring Ni ions in NiO nanowalls at various growth temperatures below the Neel temperature. This study shows that short spin correlation leads to an exponential dependence of the growth temperatures and the existence of nickel vacancies during the magnon excitation. Four-magnon configurations were determined from the scattering factor, revealing a lowest state and monotonic change with the growth temperature. PACS: 75.47.Lx; 61.82.Rx; 75.50.Tt; 74.25.nd; 72.10.Di

  16. Mechanical properties of highly textured Cu/Ni multilayers

    International Nuclear Information System (INIS)

    Liu, Y.; Bufford, D.; Wang, H.; Sun, C.; Zhang, X.

    2011-01-01

    We report on the synthesis of highly (1 1 1) and (1 0 0) textured Cu/Ni multilayers with individual layer thicknesses, h, varying from 1 to 200 nm. When, h, decreases to 5 nm or less, X-ray diffraction spectra show epitaxial growth of Cu/Ni multilayers. High resolution transmission electron microscopy studies show the coexistence of nanotwins and coherent layer interfaces in highly (1 1 1) textured Cu/Ni multilayers with smaller h. Hardnesses of multilayer films increase with decreasing h, approach a maximum at h of a few nanometers, and show softening thereafter at smaller h. The influence of layer interfaces as well as twin interfaces on strengthening mechanisms of multilayers and the formation of twins in Ni in multilayers are discussed.

  17. Microstructure evolution of heat treated NiTi alloys

    Science.gov (United States)

    Losertová, M.; Štencek, M.; Matýsek, D.; Štefek, O.; Drápala, J.

    2017-11-01

    Superelastic behavior of off-stoichiometric NiTi alloys is significantly affected by microstructure changes due to heat treatment. Applying appropriate thermal treatments important effects on microstructural changes, transformation temperatures and thermomechanical properties of final NiTi products can be achieved. The experimental samples of NiTi alloy with 55.8 wt.% Ni were submitted to heat treatment and the microstructures before and after the treatment were observed. The thermal regimes consisted of annealing treatment at 600 °C for 1 hour followed by water quenching and of ageing at eight different temperatures (250, 270, 290, 300, 350, 400, 450 and 500 °C) for 30 minutes. Microstructure features studied by means of optical and scanning electron microscopies, EDX microanalyses, X-ray diffraction analyses and microhardness measurement, have shown that higher ageing temperatures led to microstructure changes and corresponding increase in microhardness.

  18. Steam Reforming of CH4 Using Ni- Substituted Pyrochlore Catalysts

    Science.gov (United States)

    Haynes, Daniel J.

    The steam reforming of methane (SMR) continues to remain an important industrial reaction for large-scale production of H2 as well as synthesis gas mixtures which can be used for the production of useful chemicals (e.g. methanol). Although SMR is a rather mature technology, traditional nickel based catalysts used industrially are subjected to severe temperatures and reaction conditions, which lead to irreversible activity loss through sintering, support collapse, and carbon formation. Pyrochlore-based mixed oxide have been identified as refractory materials that can be modified through the substitution of catalytic metals and other promoting species into the structure to mitigate these issues causing deactivation. For this study, a lanthanum zirconate pyrochlore catalyst was substituted with Ni to determine whether the oxide structure could effectively stabilize the activity of the catalytic metal during the SMR. The effect of different variables including calcination temperature, a comparison of a substituted versus supported Ni pyrochlore catalyst, Ni weight loading, and Sr promotion have been evaluated to determine the location of the Ni in the structure, and their effect on catalytic behavior. It was revealed that the effect of calcination temperature on a 6wt% Ni substituted pyrochlore produced by the Pechini method demonstrated very little Ni was soluble in the pyrochlore lattice. It was further revealed that by XRD, TEM, and atom probe tomography that, despite the metal loading, Ni exsolves from the structure upon crystallization of the pyrochlore at 700°C, and forms NiO at the surface and grain boundaries. An additional separate La2ZrNiO6 perovskite phase also began to form at higher temperatures (>800°C). Increasing calcination temperature was found to lead to slight sintering of the NiO at the surface, which made the NiO more reducible. Meanwhile decreasing the Ni weight loading was found to produce a lower reduction temperature due to the presence of

  19. Magnetic exchange at realistic CoO/Ni interfaces

    KAUST Repository

    Grytsiuk, Sergii

    2012-07-30

    We study the CoO/Ni interface by first principles calculations. Because the lattice mismatch is large, a realistic description requires a huge supercell. We investigate two interface configurations: in interface 1 the coupling between the Ni and Co atoms is mediated by O, whereas in interface 2 the Ni and Co atoms are in direct contact. We find that the magnetization (including the orbital moment) in interface 1 has a similar value as in bulk Ni but opposite sign, while in interface 2 it grows by 164%. The obtained magnetic moments can be explained by the local atomic environments. In addition, we find effects of charge transfer between the interface atoms. The Co 3d local density of states of interface 2 exhibits surprisingly small deviations from the corresponding bulk result, although the first coordination sphere is no longer octahedral. © Springer-Verlag 2012.

  20. Can the Ni classification of vessels predict neoplasia?

    DEFF Research Database (Denmark)

    Mehlum, Camilla Slot; Rosenberg, Tine; Dyrvig, Anne-Kirstine

    2018-01-01

    of the Ni classification to predict laryngeal or hypopharyngeal neoplasia and to investigate if a changed cutoff value would support the recent European Laryngological Society (ELS) proposal of perpendicular vascular changes as indicative of neoplasia. DATA SOURCES: PubMed, Embase, Cochrane, and Scopus......OBJECTIVES: The Ni classification of vascular change from 2011 is well documented for evaluating pharyngeal and laryngeal lesions, primarily focusing on cancer. In the planning of surgery it may be more relevant to differentiate neoplasia from non-neoplasia. We aimed to evaluate the ability....... The pooled sensitivity and specificity of the Ni classification with two different cutoffs were calculated, and bubble and summary receiver operating characteristics plots were created. RESULTS: The combined sensitivity of five studies (n = 687) with Ni type IV-V defined as test-positive was 0.89 (95...

  1. Neutron matter densities in the even Ni isotopes

    International Nuclear Information System (INIS)

    Alkhazov, G.D.; Beurtey, R.; Boudard, A.; Bruge, G.; Catz, H.; Chaumeaux, A.; Couvert, P.; Escudie, J.L.; Fontaine, J.M.; Garcon, M.; Guyot, J.; Legrand, D.; Lugol, J.C.; Lombard, R.M.; Matoba, M.; Terrien, Y.

    1977-01-01

    Elastic scattering of 1.047 GeV protons is studied on the isotopically enriched 58 60 62 64 Ni isotopes. A spin independent Glauber theory analysis allowed the extraction of nuclear matter densities for these targets. (Auth.)

  2. NiCo2S4@NiMoO4 Core-Shell Heterostructure Nanotube Arrays Grown on Ni Foam as a Binder-Free Electrode Displayed High Electrochemical Performance with High Capacity

    Science.gov (United States)

    Zhang, Yan; Xu, Jie; Zheng, Yayun; Zhang, Yingjiu; Hu, Xing; Xu, Tingting

    2017-06-01

    Core-shell-structured system has been proved as one of the best architecture for clean energy products owing to its inherited superiorities from both the core and the shell part, which can provide better conductivity and high surface area. Herein, a hierarchical core-shell NiCo2S4@NiMoO4 heterostructure nanotube array on Ni foam (NF) (NiCo2S4@NiMoO4/NF) has been successfully fabricated. Because of its novel heterostructure, the capacitive performance has been enhanced. A specific capacitance up to 2006 F g-1 was obtained at a current density of 5 mA cm-2, which was far higher than that of pristine NiCo2S4 nanotube arrays (about 1264 F g-1). More importantly, NiCo2S4@NiMoO4/NF and active carbon (AC) were congregated as positive electrode and negative electrode in an asymmetric supercapacitor. As-fabricated NiCo2S4@NiMoO4/NF//AC device has a good cyclic behavior with 78% capacitance retention over 2000 cycles, and exhibits a high energy density of 21.4 Wh kg-1 and power density of 58 W kg-1 at 2 mA cm-2. As displayed, the NiCo2S4@NiMoO4/NF core-shell herterostructure holds great promise for supercapacitors in energy storage.

  3. Remedio para una niñez descarriada

    Directory of Open Access Journals (Sweden)

    Victoria D'hers

    2012-08-01

    Full Text Available ¿Cómo una manifestación conductual pasa a convertirse en una enfermedad? ¿Alguien (un niño está enfermo porque se mueve demasiado o habla mucho? Desde estas preguntas y su contextualización, MN Míguez nos interpela con datos que deberían alarmarnos: un 30% de los niños uruguayos son medicados a base de risperidona, metilfenidato, valproato, clonazepam y sertralina. ¿Está tan enferma la niñez uruguaya? Mejor observemos y analicemos las mediaciones del saber/poder en la distinción entre enfermedad y salud. Así, nos propone un camino que se articula rastreando este uso y abuso de psicofármacos en la niñez, a la vez que analiza el discurso de niños, padres, familias, referentes de la salud y la educación, quienes se ven involucrados en este presente de la niñez uruguaya patologizada. Pero no se trata de hablar en términos de “buenos” ni “malos”, dirá, sino de evidenciar un problema analizando la sociedad uruguaya como colectivo: “en ese 30% de la niñez uruguaya medicalizada lo que se cuestiona es la subjetividad inmanente en los diagnósticos que apelan extrema objetividad científica.” Consecuentemente, Míguez despliega su investigación desde una posición ética específica, rescatando la voz de los considerados “no calificados”, y asumiendo un proceso reflexivo respecto de su propia indagación/posición.

  4. Ordered arrays of Ni magnetic nanowires: Synthesis and investigation

    Science.gov (United States)

    Napolskii, K. S.; Eliseev, A. A.; Yesin, N. V.; Lukashin, A. V.; Tretyakov, Yu. D.; Grigorieva, N. A.; Grigoriev, S. V.; Eckerlebe, H.

    2007-03-01

    The present study is focused on the synthesis and investigation of anodic aluminum oxide (AAO) films and magnetic nanocomposites Ni/AAO obtained by Ni electrodeposition into porous matrix. AAO membranes and magnetic nanocomposites were investigated by HRSEM, EDX microanalysis, XRD, nitrogen capillary adsorption method, SQUID magnetometry, and polarized small-angle neutron scattering (SANS). The influence of synthesis conditions and form factor effect on the magnetic properties of nanowire arrays is reported.

  5. Hydrogen solubility in austenite of Fe-Ni-Cr alloys

    International Nuclear Information System (INIS)

    Zhirnova, V.V.; Mogutnov, B.M.; Tomilin, I.A.

    1981-01-01

    Hydrogen solubility in Fe-Ni-Cr alloys at 600-1000 deg C is determined. Hydrogen solubility in ternary alloys can not be predicted on the basis of the data on its solubility in binary Fe-Ni, Fe-Cr alloys. Chromium and nickel effect on hydrogen solubility in iron is insignificant in comparison with the effect of these elements on carbon or nitrogen solubility [ru

  6. Fracturas de cadera en niños

    OpenAIRE

    Alvaro A. Vanegas

    1990-01-01

    Se hizo una evaluación retrospectiva de los resultados finales obtenidos en 37 niñas y 34 niños, de 2 a 16 años, con fractura de cadera, tratados por el grupo de Ortopedia Infantil de la Facultad de Medicina de la Universidad de Antioquia y el Hospital Universitario San Vicente de
    Paúl, entre 1976 y 1986.

  7. Fracturas de cadera en niños

    Directory of Open Access Journals (Sweden)

    Alvaro A. Vanegas

    1990-03-01

    Full Text Available Se hizo una evaluación retrospectiva de los resultados finales obtenidos en 37 niñas y 34 niños, de 2 a 16 años, con fractura de cadera, tratados por el grupo de Ortopedia Infantil de la Facultad de Medicina de la Universidad de Antioquia y el Hospital Universitario San Vicente de
    Paúl, entre 1976 y 1986.

  8. Reactions at the Ni-ZrO2 interface

    International Nuclear Information System (INIS)

    Shinde, S.L.; Reimanis, I.E.; DeJonghe, L.C.

    1985-01-01

    The degradation of metal-ceramic interface at elevated temperatures in protective ceramic coatings limits their life-time. A model system of nickel particles dispersed in a zirconia matrix is used to resolve these changes. Oxidation at elevated temperatures (900 0 C) leads to NiO growth at the interface. The matrix is destabilized when the stabilizer is soluble in NiO, resulting in transformation to deleterious monoclinic phase which is found to be one important reason for interface degradation

  9. Structure of Ni60Nb40 metallic glass studied by combined X-ray and neutron diffraction

    International Nuclear Information System (INIS)

    Forgacs, F.; Svab, E.; Takacs, J.; Hajdu, F.

    1980-10-01

    The partial structure factors S(Q)sub(NiNi), S(Q)sub(NiNb) and S(Q)sub(NbNb) were determined for rapidly quenched Ni 60 Nb 40 metallic glass samples by combined X-ray and neutron diffraction experiments, the latter on isotope substituted samples. The partial distribution functions were calculated. Details are given on interatomic distances and coordination numbers for Ni-Ni, Ni-Nb and Nb-Nb pairs. (author)

  10. Strangeness production in Ni+Ni collisions at 1.93 AGeV

    International Nuclear Information System (INIS)

    Lopez, X.

    2004-12-01

    This work deals with the production of strange particles in Ni + Ni collisions at 1.93 A GeV detected with the Fopi (four pi) detector at the heavy ion synchrotron SIS (GSI - Germany). We have limited our investigation to the study of Λ and Ξ hyperons. The first chapter presents the models used to describe ultra-relativistic heavy ions collisions. In the second chapter we present the main experimental results concerning the production and transport of strange particles in an energy domain ranging from SIS to RHIC (relativistic heavy ion collider) energies. The third chapter is dedicated to the specificities of the Fopi detector. The fourth chapter deals with the production of Λ particles in Ni + Ni collisions. An analysis method based on neuron network has been used in parallel with a more classical method. The production rate and temperature of Λ have been deduced from both methods. The neuron network method gives a statistical gain and allows a better identification of particles with low transverse impulses. The fifth chapter is dedicated to the detection of the doubly strange Ξ - particle. A detailed study about the stability of the signal is presented. In the last chapter all our experimental results are confronted with theoretical predictions. The UrQMD model that uses a hard equation of state, can simulate satisfactorily the production rates of Λ and K + as well as their dependency on collision centrality despite the fact that this model does not use a potential linked to the medium density. The comparison between experimental results and predictions given by the IQMD model (that is based on a soft equation of state) is better when the version of the model that does not take into account the effects of the media is used. We see that the choices for the nuclear matter compressibility, for the particles involved in Kaon and Λ creation process, or for the interaction potential with dense medium, appear to be degrees of freedom that are difficult to adjust

  11. The characteristics of unidirectional solidified Ni-Al-Mo alloys

    Energy Technology Data Exchange (ETDEWEB)

    Ishak, M. [Department of Mechanical Engineering, University of Tokushima, Tokushima (Japan); Takagi, H. [Faculty of Mechanical Engineering, Universiti Malaysia Pahang, Pekan, Pahang (Malaysia)

    2012-05-15

    The material composite was fabricated by the unidirectional solidification method in the eutectic composition alloy. Performing unidirectional solidification of Ni-Al-Mo alloy in eutectic composition produces {gamma} phase -Ni and {gamma}' phase-Ni{sub 3}Al as a matrix, and the phase-Mo growth into fibrous and lamellar-like structure. The aim of this research was to study the characteristics of Ni-Al-Mo after various heat treatment conditions. The specimens were solution-treated at temperatures of 1180 C and 1280 C, followed by water quenching. In addition, aging treatments were carried out at various temperatures (from 700 C to 1000 C) and at different time durations. The microstructure, mechanical properties and characteristics of non-treated, solution-treated and aging specimens were investigated. It was found that the mechanical properties of unidirectional solidified Ni-Al-Mo can be improved by solution treatment whilst the strength through performing an aging treatment. The optimized conditions were at 1280 C and 4 hours for water quenching (solution treatment), followed by an aging process at 800 C and 4 hours. These treatments led to an increase of mechanical properties due to uniformly precipitations of finely dispersed {gamma}' phase-Ni{sub 3}Al throughout the specimens. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  12. A Simple theoretical model for 63Ni betavoltaic battery

    International Nuclear Information System (INIS)

    ZUO, Guoping; ZHOU, Jianliang; KE, Guotu

    2013-01-01

    A numerical simulation of the energy deposition distribution in semiconductors is performed for 63 Ni beta particles. Results show that the energy deposition distribution exhibits an approximate exponential decay law. A simple theoretical model is developed for 63 Ni betavoltaic battery based on the distribution characteristics. The correctness of the model is validated by two literature experiments. Results show that the theoretical short-circuit current agrees well with the experimental results, and the open-circuit voltage deviates from the experimental results in terms of the influence of the PN junction defects and the simplification of the source. The theoretical model can be applied to 63 Ni and 147 Pm betavoltaic batteries. - Highlights: • The energy deposition distribution is found following an approximate exponential decay law when beta particles emitted from 63 Ni pass through a semiconductor. • A simple theoretical model for 63 Ni betavoltaic battery is constructed based on the exponential decay law. • Theoretical model can be applied to the betavoltaic batteries which radioactive source has a similar energy spectrum with 63 Ni, such as 147 Pm

  13. Thermoelectric properties of electrodeposited CuNi alloys on Si

    Science.gov (United States)

    Delatorre, R. G.; Sartorelli, M. L.; Schervenski, A. Q.; Pasa, A. A.; Güths, S.

    2003-05-01

    Thin films with the composition of the constantan alloy (a solid solution with 35 to 50 wt. % of Ni in Cu) have a high-thermoelectric power, which allows the fabrication of very sensitive heat-flux sensors based on planar technology. In this article, the thermoelectric properties of CuxNi100-x thin films electrodeposited on silicon were studied as a function of the composition, temperature, and thickness. The electrodeposition of thin layers on silicon is an important step for the integration of thermal sensors with semiconductor technology. The CuxNi100-x alloys were electrodeposited potentiostatically at room temperature, from a citrate electrolyte containing both copper and nickel sulfates. The layer composition was controlled by the applied potential in the range from pure copper (at -0.4 V/SCE) up to a solid solution of about 25 wt. % Cu in Ni (at -1.2 V/SCE). Extremely high values of thermoelectric power were measured for very thin layers of Cu40Ni60 on Si, showing a strong influence of the substrate. By considering the system as a thermoelectric bilayer and extracting the contribution of the semiconductor, thermopower values for the Cu40Ni60 alloys comparable to the expected ones for constantan wires were obtained.

  14. Prediction of Indentation Behavior of Superelastic TiNi

    Science.gov (United States)

    Neupane, Rabin; Farhat, Zoheir

    2014-09-01

    Superelastic TiNi shape memory alloys have been extensively used in various applications. The great interest in TiNi alloys is due to its unique shape memory and superelastic effects, along with its superior wear and dent resistance. Assessment of mechanical properties and dent resistance of superelastic TiNi is commonly performed using indentation techniques. However, the coupling of deformation and reversible martensitic transformation of TiNi under indentation conditions makes the interpretation of results challenging. An attempt is made to enhance current interpretation of indentation data. A load-depth curve is predicted that takes into consideration the reversible martensitic transformation. The predicted curve is in good agreement with experimental results. It is found in this study that the elastic modulus is a function of indentation depth. At shallow depths, the elastic modulus is high due to austenite dominance, while at high depths, the elastic modulus drops as the depth increases due to austenite to martensite transition, i.e., martensite dominance. It is also found that TiNi exhibits superior dent resistance compared to AISI 304 steel. There is two orders of magnitude improvement in dent resistance of TiNi in comparison to AISI 304 steel.

  15. Synthesis, characterization and catalytic activity of nanosized Ni complexed aminoclay

    Science.gov (United States)

    Ranchani, A. Amala Jeya; Parthasarathy, V.; Devi, A. Anitha; Meenarathi, B.; Anbarasan, R.

    2017-11-01

    A novel Ni complexed aminoclay (AC) catalyst was prepared by complexation method followed by reduction reaction. Various analytical techniques such as FTIR spectroscopy, UV-visible spectroscopy, DSC, TGA, SEM, HRTEM, EDX, XPS and WCA measurement are used to characterize the synthesized material. The AC-Ni catalyst system exhibited improved thermal stability and fiber-like morphology. The XPS results declared the formation of Ni nanoparticles. Thus, synthesized catalyst was tested towards the Schiff base formation reaction between various bio-medical polymers and aniline under air atmosphere at 85 °C for 24 h. The catalytic activity of the catalyst was studied by varying the % weight loading of the AC-Ni system towards the Schiff base formation. The Schiff base formation was quantitatively calculated by the 1H-NMR spectroscopy. While increasing the % weight loading of the AC-Ni catalyst, the % yield of Schiff base was also increased. The k app and Ti values were determined for the reduction of indole and α-terpineol in the presence of AC-Ni catalyst system. The experimental results were compared with the literature report.

  16. Comparative study on microstructure and martensitic transformation of aged Ni-rich NiTi and NiTiCo shape memory alloys

    Science.gov (United States)

    El-Bagoury, Nader

    2016-05-01

    In this article the influence of aging heat treatment conditions of 250, 350, 450 and 550 °C for 3 h on the microstructure, martensitic transformation temperatures and mechanical properties of Ni51Ti49Co0 and Ni47 Ti49Co4 shape memory alloys was investigated. This comparative study was carried out using X-ray diffraction analysis, scanning electron microscope, energy dispersive spectrometer, differential scanning calorimeter and Vickers hardness tester. The results show that the microstructure of both aged alloys contains martensite phase and Ti2Ni in addition to some other precipitates. The martensitic transformation temperature was increased steadily by increasing the ageing temperature and lowering the value of valence electron number (ev/a) and concentration. Moreover, the hardness measurements were gradually increased at first by increasing the aging temperature from 250 to 350 °C. Further elevating in aging temperature to 450 and 550 °C decreases the hardness value.

  17. Spin correlations in Ni-Mn-Ga

    CERN Document Server

    Runov, V V; Runova, M K; Gavrilyuk, V; Glavatskaya, N I

    2001-01-01

    The results of measuring the neutrons low-angle scattering and depolarization in the Ni sub 4 sub 9 sub . sub 1 Mn sub 2 sub 9 sub . sub 4 Ga sub 2 sub 1 sub . sub 5 monocrystal within the range of the 15 < T < 400 K temperatures and 0 < H < 4.5 kE magnetic fields are presented. The characteristic temperatures of the alloy T sub c = 373.7 K and the martensite transition T sub m = 301-310 K are determined. The temperature dependences of the scattering parameters are obtained. The left-right asymmetry in scattering the neutrons, polarized according to and against the applied field at 150 < T < T sub m , conditioned by the neutrons inelastic magnetic interaction in the sample is identified. The problem on the alloy magnetization near T sub m , critical scattering at T approx = T sub c , scattering anomalies and magnetic excitations moderation at 150 < T < T sub m are discussed

  18. Dye-sensitized MIL-101 metal organic frameworks loaded with Ni/NiO{sub x} nanoparticles for efficient visible-light-driven hydrogen generation

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Xin-Ling; Wang, Rong; Yuan, Yu-Peng, E-mail: yupengyuan@ahu.edu.cn, E-mail: cxue@ntu.edu.sg [School of Chemistry and Chemical Engineering, and Innovation Lab for Clean Energy and Green Catalysis, Anhui University, Hefei 230036 (China); Zhang, Ming-Yi [Key Laboratory for Photonic and Electronic Bandgap Materials, Ministry of Education, School of Physics and Electronic Engineering, Harbin Normal University, Harbin 150025 (China); Xue, Can, E-mail: yupengyuan@ahu.edu.cn, E-mail: cxue@ntu.edu.sg [Solar Fuels Lab, School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798 (Singapore)

    2015-10-01

    The Ni/NiO{sub x} particles were in situ photodeposited on MIL-101 metal organic frameworks as catalysts for boosting H{sub 2} generation from Erythrosin B dye sensitization under visible-light irradiation. The highest H{sub 2} production rate of 125 μmol h{sup −1} was achieved from the system containing 5 wt. % Ni-loaded MIL-101 (20 mg) and 30 mg Erythrosin B dye. Moreover, the Ni/NiO{sub x} catalysts show excellent stability for long-term photocatalytic reaction. The enhancement on H{sub 2} generation is attributed to the efficient charge transfer from photoexcited dye to the Ni catalyst via MIL-101. Our results demonstrate that the economical Ni/NiO{sub x} particles are durable and active catalysts for photocatalytic H{sub 2} generation.

  19. Preliminary Microstructural and Microscratch Results of Ni-Cr-Fe and Cr3C2-NiCr Coatings on Magnesium Substrate

    Science.gov (United States)

    Istrate, B.; Munteanu, C.; Lupescu, S.; Benchea, M.; Vizureanu, P.

    2017-06-01

    Thermal coatings have a large scale application in aerospace and automotive field, as barriers improving wear mechanical characteristics and corrosion resistance. In present research, there have been used two types of coatings, Ni-Cr-Fe, respectively Cr3C2-NiCr which were deposited on magnesium based alloys (pure magnesium and Mg-30Y master alloy). There have been investigated the microstructural aspects through scanning electronic microscopy and XRD analysis and also a series of mechanical characteristics through microscratch and indentation determinations. The results revealed the formation of some adherent layers resistant to the penetration of the metallic indenter, the coatings did not suffer major damages. Microstructural analysis highlighted the formation of Cr3C2, Cr7C3, Cr3Ni2, Cr7Ni3, FeNi3, Cr-Ni phases. Also, the apparent coefficient of friction for Ni-Cr-Fe coatings presents superior values than Cr3C2-NiCr coatings.

  20. Tuning Surface Electronic Configuration of NiFe LDHs Nanosheets by Introducing Cation Vacancies (Fe or Ni) as Highly Efficient Electrocatalysts for Oxygen Evolution Reaction.

    Science.gov (United States)

    Wang, Yanyong; Qiao, Man; Li, Yafei; Wang, Shuangyin

    2018-04-03

    Intrinsically inferior electrocatalytic activity of NiFe layered double hydroxides (LDHs) nanosheets is considered as a limiting factor to inhibit the electrocatalytic properties for oxygen evolution reaction (OER). Proper defect engineering to tune the surface electronic configuration of electrocatalysts may significantly improve the intrinsic activity. In this work, the selective formation of cation vacancies in NiFe LDHs nanosheets is successfully realized. The as-synthesized NiFe LDHs-V Fe and NiFe LDHs-V Ni electrocatalysts show excellent activity for OER, mainly attributed to the introduction of rich iron or nickel vacancies in NiFe LDHs nanosheets, which efficiently tune the surface electronic structure increasing the adsorbing capacity of OER intermediates. Density functional theory (DFT) computational results also further indicate that the OER catalytic performance of NiFe LDHs can be pronouncedly improved by introducing Fe or Ni vacancies. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.