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Sample records for surveys geochemical exploration

  1. Merging high resolution geophysical and geochemical surveys to reduce exploration risk at glass buttes, Oregon

    Energy Technology Data Exchange (ETDEWEB)

    Walsh, Patrick [Ormat Nevada, Inc., Reno, NV (United States); Fercho, Steven [Ormat Nevada, Inc., Reno, NV (United States); Perkin, Doug [Ormat Nevada, Inc., Reno, NV (United States); Martini, Brigette [Corescan Inc., Ascot (Australia); Boshmann, Darrick [Oregon State Univ., Corvallis, OR (United States)

    2015-06-01

    The engineering and studies phase of the Glass Buttes project was aimed at reducing risk during the early stages of geothermal project development. The project’s inclusion of high resolution geophysical and geochemical surveys allowed Ormat to evaluate the value of these surveys both independently and in combination to quantify the most valuable course of action for exploration in an area where structure, permeability, and temperature are the most pressing questions. The sizes of the thermal anomalies at Glass Buttes are unusually large. Over the course of Phase I Ormat acquired high resolution LIDAR data to accurately map fault manifestations at the surface and collected detailed gravity and aeromagnetic surveys to map subsurface structural features. In addition, Ormat collected airborne hyperspectral data to assist with mapping the rock petrology and mineral alteration assemblages along Glass Buttes faults and magnetotelluric (MT) survey to try to better constrain the structures at depth. Direct and indirect identification of alteration assemblages reveal not only the geochemical character and temperature of the causative hydrothermal fluids but can also constrain areas of upflow along specific fault segments. All five datasets were merged along with subsurface lithologies and temperatures to predict the most likely locations for high permeability and hot fluids. The Glass Buttes temperature anomalies include 2 areas, totaling 60 km2 (23 mi2) of measured temperature gradients over 165° C/km (10° F/100ft). The Midnight Point temperature anomaly includes the Strat-1 well with 90°C (194 °F) at 603 m (1981 ft) with a 164 °C/km (10°F/100ft) temperature gradient at bottom hole and the GB-18 well with 71°C (160 °F) at 396 m (1300 ft) with a 182°C/km (11°F/100ft) gradient. The primary area of alteration and elevated temperature occurs near major fault intersections associated with Brothers Fault Zone and Basin and Range systems. Evidence for faulting is

  2. Surface geochemical survey for geothermal exploration in the south-east zone of Tenerife Island, Canary Islands

    Science.gov (United States)

    Diaz Requejo, M.; Marrero, R.; Padron, E.; Melian, G.; Guerrero, V.; Hernandez Perez, P. A.; Perez, N.; Hidalgo, R.

    2009-12-01

    Water and gas sampling of natural discharges are the most common type of geochemical surveys for geothermal exploration. However, these natural discharges are generally scarces at geothermal exploration areas where the extent of the field is not known. Therefore, soil-volatile (Hg, As, Sb, NH3 and B) and soil-gas surveys (222Rn, CO2, He, H2, CH4, O2, Ar) are becoming a useful geochemical tool to identify permeable areas and potential upflow or boiling zones. These surveys can also help to delineate the margins of a geothermal system, and therefore often complement geophysical surveys particularly where the interpretation of geophysical data shows some difficulties. During July and August, 2008, a surface geochemical survey was undertaken in a ~120 km2 area at the south-east slope of Tenerife Island, Spain. In order to obtain a representative distribution of the whole study area, during the field work a total of 577 sampling points were performed. In-situ measurement of radon (222Rn) and thoron (220Rn) activities together with Hg0 and H2S gas concentration and CO2 and H2S soil effluxes were performed at each sampling point. At the same time, gas samples were taken from the soil atmosphere at 40 cm depth for subsequent chemical analysis by means of micro-gas chromatography and quadrupole mass spectrometry (He, H2, Ne, N2, CO2, CH4, Ar and CO2). At least two geochemical anomalous zones have been identified in the present work: (A) one close to Siete Fuentes-Fasnia historical vents (1704-1705 AD) and (B) located on the southwestern limit of the study area. Relatively high concentrations of H2 and ΔHe as well as high H2/Ar and He/CO2 ratios were observed at both zones, indicating a clear evidence of the existence of an upflow zone with an important contribution of endogenous gases. The existence of a volcanic-hydrothermal system coupled with a vertical permeability structures in both zones could explain these geochemical anomalies observed in the surface environment

  3. The National Geochemical Survey - database and documentation

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The USGS, in collaboration with other federal and state government agencies, industry, and academia, is conducting the National Geochemical Survey (NGS) to produce a...

  4. Geochemical exploration in the Montseny Mountains (NE Spain)

    OpenAIRE

    Font Cisteró, Xavier; Viladevall Solé, Manuel; Casas i Ponsatí, Albert; Vaquer Navarro, Ramon

    1984-01-01

    A five year program of systematic multi-element geochemical exploration of the Catalonian Coastal Ranges has been initiated by the Geological Survey of Autonomic Government of Catalonia (Generalitat de Catalunya) and the Department of Geological and Geophysical Exploration (University of Barcelona). This paper reports the first stage results of this regional survey, covering an area of 530 km2 in the Montseny Mountains, NE of Barcelona (Spain). Stream sediments for metals and stream waters fo...

  5. Blind Geothermal System Exploration in Active Volcanic Environments; Multi-phase Geophysical and Geochemical Surveys in Overt and Subtle Volcanic Systems, Hawai’i and Maui

    Energy Technology Data Exchange (ETDEWEB)

    Fercho, Steven [Ormat Nevada, Inc., Reno, NV (United States); Owens, Lara [Ormat Nevada, Inc., Reno, NV (United States); Walsh, Patrick [Ormat Nevada, Inc., Reno, NV (United States); Drakos, Peter [Ormat Nevada, Inc., Reno, NV (United States); Martini, Brigette [Corescan Inc., Ascot (Australia); Lewicki, Jennifer L. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Kennedy, Burton M. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

    2015-08-01

    Suites of new geophysical and geochemical exploration surveys were conducted to provide evidence for geothermal resource at the Haleakala Southwest Rift Zone (HSWRZ) on Maui Island, Hawai’i. Ground-based gravity (~400 stations) coupled with heli-bourne magnetics (~1500 line kilometers) define both deep and shallow fractures/faults, while also delineating potentially widespread subsurface hydrothermal alteration on the lower flanks (below approximately 1800 feet a.s.l.). Multi-level, upward continuation calculations and 2-D gravity and magnetic modeling provide information on source depths, but lack of lithologic information leaves ambiguity in the estimates. Additionally, several well-defined gravity lows (possibly vent zones) lie coincident with magnetic highs suggesting the presence of dike intrusions at depth which may represent a potentially young source of heat. Soil CO2 fluxes were measured along transects across geophysically-defined faults and fractures as well as young cinder cones along the HSWRZ. This survey generally did not detect CO2 levels above background, with the exception of a weak anomalous flux signal over one young cinder cone. The general lack of observed CO2 flux signals on the HSWRZ is likely due to a combination of lower magmatic CO2 fluxes and relatively high biogenic surface CO2 fluxes which mix with the magmatic signal. Similar surveys at the Puna geothermal field on the Kilauea Lower East Rift Zone (KLERZ) also showed a lack of surface CO2 flux signals, however aqueous geochemistry indicated contribution of magmatic CO2 and He to shallow groundwater here. As magma has been intercepted in geothermal drilling at the Puna field, the lack of measured surface CO2 flux indicative of upflow of magmatic fluids here is likely due to effective “scrubbing” by high groundwater and a mature hydrothermal system. Dissolved inorganic carbon (DIC) concentrations, δ13C compositions and 3He/4He values were sampled at Maui from several shallow

  6. Alaska Geochemical Database - Mineral Exploration Tool for the 21st Century - PDF of presentation

    Science.gov (United States)

    Granitto, Matthew; Schmidt, Jeanine M.; Labay, Keith A.; Shew, Nora B.; Gamble, Bruce M.

    2012-01-01

    The U.S. Geological Survey has created a geochemical database of geologic material samples collected in Alaska. This database is readily accessible to anyone with access to the Internet. Designed as a tool for mineral or environmental assessment, land management, or mineral exploration, the initial version of the Alaska Geochemical Database - U.S. Geological Survey Data Series 637 - contains geochemical, geologic, and geospatial data for 264,158 samples collected from 1962-2009: 108,909 rock samples; 92,701 sediment samples; 48,209 heavy-mineral-concentrate samples; 6,869 soil samples; and 7,470 mineral samples. In addition, the Alaska Geochemical Database contains mineralogic data for 18,138 nonmagnetic-fraction heavy mineral concentrates, making it the first U.S. Geological Survey database of this scope that contains both geochemical and mineralogic data. Examples from the Alaska Range will illustrate potential uses of the Alaska Geochemical Database in mineral exploration. Data from the Alaska Geochemical Database have been extensively checked for accuracy of sample media description, sample site location, and analytical method using U.S. Geological Survey sample-submittal archives and U.S. Geological Survey publications (plus field notebooks and sample site compilation base maps from the Alaska Technical Data Unit in Anchorage, Alaska). The database is also the repository for nearly all previously released U.S. Geological Survey Alaska geochemical datasets. Although the Alaska Geochemical Database is a fully relational database in Microsoft® Access 2003 and 2010 formats, these same data are also provided as a series of spreadsheet files in Microsoft® Excel 2003 and 2010 formats, and as ASCII text files. A DVD version of the Alaska Geochemical Database was released in October 2011, as U.S. Geological Survey Data Series 637, and data downloads are available at http://pubs.usgs.gov/ds/637/. Also, all Alaska Geochemical Database data have been incorporated into

  7. National Geochemical Survey Locations and Results for Iowa

    Data.gov (United States)

    Iowa State University GIS Support and Research Facility — The United States Geological Survey (USGS), in collaboration with other state and federal agencies, industry, and academia, is conducting a National Geochemical...

  8. Use of thermal springs for geochemical exploration in Ethiopia ...

    African Journals Online (AJOL)

    Hence, hot spring water anomalous in Au, Mn, Zn, Pb, Cu, Co and Ag could be a proxy for precious metal searching in epithermal systems associated with thermal springs. Keywords: Epithermal system, Ethiopian Rift Valley, geochemical exploration, thermal springs. Ethiopian Journal of Environmental Studies and ...

  9. The role of atomic absorption spectrometry in geochemical exploration

    Science.gov (United States)

    Viets, J.G.; O'Leary, R. M.

    1992-01-01

    In this paper we briefly describe the principles of atomic absorption spectrometry (AAS) and the basic hardware components necessary to make measurements of analyte concentrations. Then we discuss a variety of methods that have been developed for the introduction of analyte atoms into the light path of the spectrophotometer. This section deals with sample digestion, elimination of interferences, and optimum production of ground-state atoms, all critical considerations when choosing an AAS method. Other critical considerations are cost, speed, simplicity, precision, and applicability of the method to the wide range of materials sampled in geochemical exploration. We cannot attempt to review all of the AAS methods developed for geological materials but instead will restrict our discussion to some of those appropriate for geochemical exploration. Our background and familiarity are reflected in the methods we discuss, and we have no doubt overlooked many good methods. Our discussion should therefore be considered a starting point in finding the right method for the problem, rather than the end of the search. Finally, we discuss the future of AAS relative to other instrumental techniques and the promising new directions for AAS in geochemical exploration. ?? 1992.

  10. Geochemical orientation for mineral exploration in the Hashemite Kingdom of Jordan

    Science.gov (United States)

    Overstreet, W.C.; Grimes, D.J.; Seitz, J.F.

    1982-01-01

    This report is a supplement to previous accounts of geochemical exploration conducted in the Hashemite Kingdom of Jordan by the Natural Resources Authority of the Royal Government of Jordan and the U.S. Geological Survey. The field work on which this report is based was sponsored by the U.S. Agency for International Development, U.S. Department of State. Procedures used in collecting various kinds of rocks, ores, slags, eluvial and alluvial sediments, heavy-mineral concentrates, and organic materials for use as geochemical sample media are summarized, as are the laboratory procedures followed for the analysis of these sample materials by semiquantitative spectrographic, atomic absorption, fluorometric, and X-ray diffraction methods. Geochemical evaluations of the possibilities for economic mineral deposits in certain areas are presented. The results of these preliminary investigations open concepts for further use in geochemical exploration in the search for metallic mineral deposits in Jordan. Perhaps the most desirable new activity would be hydrogeochemical exploration for uranium and base metals, accompanied by interpretation of such remote-sensing data as results of airborne radiometric surveys and computer-enhanced LANDSAT imagery. For more conventional approaches to geochemical exploration, however, several fundamental problems regarding proper choice of geochemical sample media for different geologic and geographic parts of the Country must be solved before effective surveys can be made. The present results also show that such common geochemical exploration techniques as the determination of the trace-element contents of soils, plant ash, and slags have direct application also toward the resolution of several archaeological problems in Jordan. These include the relation of trace-elements chemistry of local soils to the composition of botanic remains, the trace-elements composition of slags to the technological development of the extractive metallurgy of

  11. Using multifractal modeling as a standard tool in geochemical exploration for predicting mineralized areas

    Science.gov (United States)

    Gonçalves, Mario A.

    2015-04-01

    It has been 20 years since the pioneering work of Cheng et al (1994) first proposed a quantitative relationship for the areas enclosing concentration values of an element above given thresholds and their distribution in the field, known as concentration-area (CA) method, which is based in multifractal theory. The method allows the definition of geochemical anomalies in wide set of geological backgrounds but it took nearly 15 years before it became a widely used methodology for mineral exploration. The method was also extended to 1D and 3D data sets. It is worth noting the variety of methods that spanned from the theory of fractals. Building on previous models, including multiplicative cascades and size-grade relationships, increasing evidence points to the powerful tools of fractal theory to describe and model ore deposit distribution and formation. However, while much of these approaches become complex and not easy to use, the CA method is remarkable for its utter simplicity and disarming results obtained when confronted with the geological reality in the field. This is most valued by companies and professionals undertaking geochemical exploration surveys for the characterization or refining of potential ore targets or known mineralized areas. Several approaches have combined the CA method with geostatistic modeling and simulation and other established statistical techniques in order to enhance anomalous threshold identification. Examples are not restricted to geochemical exploration alone, other applications being studies on environmental change. Some of these examples will be addressed as they have been applied to different regions in the world, but particular emphasis will be put on geochemical exploration surveys in different geotectonic units of the Variscan basement in the Iberian Peninsula. These include quartz-vein gold mineralization in Northern Portugal and several surveys for base metals over two wide areas, which served to re-evaluate much of the

  12. Stream sediment detailed geochemical survey for Date Creek Basin, Arizona

    Energy Technology Data Exchange (ETDEWEB)

    Butz, T.R.; Tieman, D.J.; Grimes, J.G.; Bard, C.S.; Helgerson, R.N.; Pritz, P.M.

    1980-06-30

    Results of the Date Creek Basin detailed geochemical survey are reported. Field and laboratory data are reported for 239 stream sediment samples. Statistical and areal distributions of uranium and possible uranium-related variables are displayed. A generalized geologic map of the area is provided, and pertinent geologic factors which may be of significance in evaluating the potential for uranium mineralization are briefly discussed. Based on stream sediment geochemical data, significant concentrations of uranium are restricted to the Anderson Mine area. The 84th percentile concentrations of U-FL, U-NT, and U-FL/U-NT combined with low thorium/U-NT values reflect increased mobility and enrichment of uranium in the carbonate host rocks of that area. Elements characteristically associated with the uranium mineralization include lithium and arsenic. No well defined diffusion halos suggesting outliers of similar uranium mineralization were observed from the stream sediment data in other areas of the Date Creek Basin. Significant concentrations of U-FL or U-NT found outside the mine area are generally coincident with low U-FL/U-NT values and high concentrations of zirconium, titanium, and phosphorus. This suggests that the uranium is related to a resistate mineral assemblage derived from surrounding crystalline igneous and metamorphic rocks.

  13. Geochemical exploration for copper-nickel deposits in the cool-humid climate of northeastern Minnesota

    Science.gov (United States)

    Miller, W.R.; Ficklin, W.H.; McHugh, J.B.

    1992-01-01

    Water was used as a medium for geochemical exploration to detect copper-nickel mineralization along the basal zone of the Duluth Complex. Ni2+ is the most important pathfinder for the detection of the mineralized rocks, followed by Cu2+ and SO42- and to a lesser extent Mg2+ and SiO2. A normalized sum plot using these species defines the mineralization more consistently than a single-element plot, mainly because the absence of one variable does not significantly influence the normalized sum value. A hydrogeochemical survey was conducted in an area of known copper-nickel mineralization in the cool-humid climate of northeastern Minnesota. The area is covered with glacial drift, and wetlands are abundant. Modeling of the chemistry of waters indicates that the waters are oxidizing and have a pH of 7 or less. The most important pathfinder species in the waters, Cu2+, Ni2+, and SO42-, are derived from the simple weathering of sulfide minerals and are mobile in the waters in this environment. Plots of Cu and Ni concentrations in soils show that Cu followed by Ni are the most useful indicator elements for delineating copper-nickel mineralization. The ability of soils and water to delineate the mineralization supports the use of both media for geochemical exploration in this cool-humid environment. In the wetlands, abundant water is available and soils are scarce or absent; where soils are abundant, waters are generally scarce or absent. The use of both media is recommended for geochemical exploration in this environment. ?? 1992.

  14. Geochemical analysis of brine samples for exploration of Borate deposits in the South of Sabzevar

    Directory of Open Access Journals (Sweden)

    Mahdi Bemani

    2016-07-01

    suggested for detailed exploration (Bemani et al., 2014. Generally speaking, for considering the spatial distribution of data the fractal method could better identify the anomalies. Also, EDA is a quick and easy method to detect anomalies. Acknowledgment The authors are grateful to the Kaniran Mining Company and the south Khorasan branch of the Iranian Mining Engineering Organization for their financial support of this study. References Bemani, M., 2012. Prospecting and Exploring of Borax in the south of Sabzevar, combination of remote sensing, field surveying and geochemical studying. M.Sc. Thesis, University of Yazd, Yazd, Iran, 137 pp (in Persian with English abstract. Bemani, M., Mojtahedzadeh, S.H. and Kohsari, A.H., 2014. Investigation of geology, mineralogy and genesis of Mohammadabad-Oryan index boron (south of Sabzevar. Iranian Journal of Crystallography and Mineralogy 22(1: 173- 186 (in Persian with English abstract. Carranza, E.J.M., 2009. Geochemical Anomaly and Mineral Prospectivity Mapping in GIS. In: M. Hale (Editor, Handbook of exploration and environmental geochemistry. Elsevier, Amsterdam, pp. 51-115. Filliben, J.J. and Heckert, A., 2005. Exploratory data analysis. Engineering Statistics Handbook, Internet, National Institute of Standards and Technology, http://www.itl.nist.gov/div898/handbook/eda/section3/eda356.htm. Hasanipak, A.A. and Sharafaddin, M., 2005. Exploratory Data Analysis.Tehran University press, Tehran 996 pp (in Persian.

  15. Debba China presentation on optimal field sampling for exploration targets and geochemicals

    CSIR Research Space (South Africa)

    Debba, Pravesh

    2008-10-01

    Full Text Available A presentation was done at the Chinese Academy of Geological Science in October 2008 on optimal field sampling for both exploration targets and sampling for geochemicals in mine tailing areas...

  16. The New Frontiers Venus In Situ Atmospheric and Geochemical Explorer (VISAGE) Mission Proposal

    Science.gov (United States)

    Esposito, L. W.; Atkinson, D. H.; Baines, K. H.

    2017-09-01

    The New Frontiers Venus In Situ Atmospheric and Geochemical Explorer (VISAGE) Mission Proposal submitted to 2017 New Frontiers 4 program by University of Colorado, managed by Caltech/Jet Propulsion Laboratory.

  17. Geophysical and geochemical techniques for exploration of hydrocarbons and minerals. [389 US patents

    Energy Technology Data Exchange (ETDEWEB)

    Sittig, M. (ed.)

    1980-01-01

    The detailed descriptive information in this book is based on 389 US patents that deal with geophysical and geochemical techniques useful for the exploration of hydrocarbons and minerals. Where it was necessary to round out the complete technological picture, a few paragraphs from cited government reports have been included. These techniques are used in prospecting for oil, coal, oil shale, tar sand and minerals. The patents are grouped under the following chapters: geochemical prospecting; geobiological prospecting; geophysical exploration; magnetic geophysical prospecting; gravitational geophysical prospecting; electrical geophysical prospecting; nuclear geophysical prospecting; seismic geophysical prospecting; and exploratory well drilling. This book serves a double purpose in that it supplies detailed technical information and can be used as a guide to the US patent literature in this field. By indicating all the information that is significant, and eliminating legal jargon and juristic phraseology, this book presents an advanced, industrially oriented review of modern methods of geophysical and geochemical exploration techniques. (ATT)

  18. A stream sediment geochemical survey of the Ganga River headwaters in the Garhwal Himalaya

    Science.gov (United States)

    Mukherjee, P.K.; Purohit, K.K.; Saini, N.K.; Khanna, P.P.; Rathi, M.S.; Grosz, A.E.

    2007-01-01

    This study models geochemical and adjunct geologic data to define provinces that are favorable for radioactive-mineral exploration. A multi-element bed-sediment geochemical survey of streams was carried out in the headwaters region of the Ganga River in northern India. Overall median values for uranium and thorium (3.6 and 13.8 ppm; maxima of 4.8 and 19.0 ppm and minima of 3.1 and 12.3 ppm respectively) exceed average upper crustal abundances (2.8 and 10.7 ppm) for these radioactive elements. Anomalously high values reach up to 8.3 and 30.1 ppm in thrust zone rocks, and 11.4 and 22.5 ppm in porphyroids. At their maxima, these abundances are nearly four- and three-fold (respectively) enriched in comparison to average crustal abundances for these rock types. Deformed, metamorphosed and sheared rocks are characteristic of the main central thrust zone (MCTZ). These intensively mylonitized rocks override and juxtapose porphyritic (PH) and proterozoic metasedimentary rock sequences (PMS) to the south. Granitoid rocks, the major protoliths for mylonites, as well as metamorphosed rocks in the MCT zone are naturally enriched in radioelements; high values associated with sheared and mylonitized zones are coincident with reports of radioelement mineralization and with anomalous radon concentrations in soils. The radioelement abundance as well as REE abundance shows a northward enrichment trend consistent with increasing grade of metamorphism indicating deformation-induced remobilization of these elements. U and Th illustrate good correlation with REEs but not with Zr. This implies that zircon is not a principal carrier of U and Th within the granitoid-dominant thrust zone and that other radioelement-rich secondary minerals are present in considerable amounts. Thus, the relatively flat, less fractionated, HREE trend is also not entirely controlled by zircon. The spatial correlation of geologic boundary zones (faults, sheared zones) with geochemical and with geophysical (Rn

  19. Stream sediment geochemical survey of an area around Dass, N.E. ...

    African Journals Online (AJOL)

    Stream sediment geochemical survey was carried out in Dass area to determine possible dispersion train for Pb, Cu, Co, Ni and Zn. A total of 114 active stream sediment samples were collected over an area of 60km2. The samples were treated with hot HNO3 and analysed for Pb, Cu, Co, Ni, Zn, Mn, Mg, Ca, and Fe.

  20. Multielement geochemical exploration data for the Cove Fort-Sulphurdale Known Geothermal Resource Area, Beaver and Millard counties, Utah

    Energy Technology Data Exchange (ETDEWEB)

    Bamford, R.W.; Christensen, O.D.

    1979-09-01

    Multielement geochemical exploration data have been acquired for the Cove Fort-Sulphurdale Known Geothermal Resource Area (KGRA). This was accomplished by analysis of both whole rock and +3.3 specific gravity concentrate samples from cuttings composites collected from shallow rotary drill holes. Areal distributions are reported for arsenic, mercury, lead and zinc. These are elements indicated by previous studies to be broadly zoned around thermal centers in geothermal systems and thus to be useful for selecting and prioritizing drilling targets. Results from this work suggest that reservoir temperature and/or reservoir to surface permeability, and thus possibly overall potential for a geothermal resource, increase northward beneath the approximately 18 square mile area containing shallow drill holes, possibly to beyond the northern limits of the area. The data provide a basis for development of three principal target models for the geothermal system but do not permit prioritization of these models. It is recommended that geochemical, geological, and temperature gradient surveys be expanded northward from the present survey area to more fully define the area which appears to have the best resource potential and to aid prioritization of the target models.

  1. Exploration geochemical technique for the determination of preconcentrated organometallic halides by ICP-AES

    Science.gov (United States)

    Motooka, J.M.

    1988-01-01

    An atomic absorption extraction technique which is widely used in geochemical exploration for the determination of Ag, As, Au, Bi, Cd, Cu, Mo, Pb, Sb, and Zn has been modified and adapted to a simultaneous inductively coupled plasma-atomic emission instrument. the experimental and operating parameters are described for the preconcentration of the metals into their organometallic halides and for the determination of the metals. Lower limits of determination are equal to or improved over those for flame atomic absorption (except Au) and ICP results are very similar to the accepted AA values, with precision for the ICP data in excess of that necessary for exploration purposes.

  2. Application of regional geochemical surveys to environmental studies; a case study from the Namaqualand copper district

    Science.gov (United States)

    Wulfse, A. D.; Holdsworth, R.

    1994-04-01

    Data from the Geological Survey of South Africa's regional geochemical programme is discussed with particular reference to environmental and agricultural aspects. Stream sediments from the Okiep copper district, Namaqualand in South Africa show highly elevated copper values as the result of a history of mining activity in the area. The potential for contamination of forage and drinking water was investigated and no obvious clinical evidence of copper excesses was observed in the ecosystem.

  3. Multifractal interpolation and spectrum-area fractal modeling of stream sediment geochemical data: Implications for mapping exploration targets

    Science.gov (United States)

    Parsa, Mohammad; Maghsoudi, Abbas; Yousefi, Mahyar; Carranza, Emmanuel John M.

    2017-04-01

    The spectrum-area (S-A) fractal model is a powerful tool for decomposition of complex anomaly patterns of gridded geochemical data. Ordinary moving average interpolation techniques are commonly being used for gridding geochemical data; however, these methods suffer from two major drawbacks of (1) ignoring the locally high values and (2) smoothing the interpolated surface. Multifractal moving average interpolation methods have been developed to overcome the shortcomings of ordinary moving average methods. This study seeks to compare two sets of multifractal and ordinary gridded geochemical data using success rate curves and applies the S-A fractal model to decompose anomalous geochemical patterns. A set of stream sediment geochemical data in Ahar area, NW Iran, was used as a case study. Then, a mineralization-related multi-element geochemical signature was gridded by ordinary and multifractal approaches and considered for further analyses. The S-A fractal method was applied to decompose anomaly and background components of the resultant multi-element geochemical signature. Exploration targets were delimited and further evaluated using two bivariate statistical procedures of Student's t-value and normalized density index. The results revealed that (a) application of multifractal gridded data enhances the predicting ability of geochemical signatures, (b) application of S-A fractal model on multifractal gridded data allows for superior discrimination of geochemical anomalies, and (c) the multi-element geochemical anomalies in the Ahar area related to porphyry-Cu deposits were properly delineated through sequence application of multifractal interpolation and S-A fractal model.

  4. National Uranium Resource Evaluation program. Uranium geochemical survey in the Crystal City and Beeville Quadrangles, Texas

    Energy Technology Data Exchange (ETDEWEB)

    Nichols, C.E.; Butz, T.R.; Cagle, G.W.; Kane, V.E.

    1977-02-11

    A uranium geochemical survey was conducted in the Crystal City and western half of the Beeville Quadrangles, Texas, an area of approximately 34,000 km/sup 2/. Using the Texas Gulf Coast Uranium Province as a study area, this survey demonstrates the applicability of a 2 phase hierarchical sampling program with multielement analysis of the samples for regional geochemical reconnaissance for uranium. Phase I samples of stream sediment, stream water, and well water were collected from drainage basins with a target drainage of 250 km/sup 2/ to identify uranium province lines which define the area in which closer spaced Phase II sampling should be conducted. Phase II samples of stream sediment, stream water, well water, and tree branches were collected from drainage basins with a target drainage of 25 km/sup 2/ in order to identify uranium district lines. Stream sediment, stream water, well water, and ash of tree branches were analyzed for approximately 25 parameters. The most useful sample type for identifying potential uranium mineralization in the Texas Gulf Coast is well water. Wells were found to accurately distinguish both province lines at Phase I sample spacing and district lines at Phase II sample spacing by several methods of evaluation. Results of the survey indicate that the concept of 2 phase sampling with multielement analyses of samples, developed by the ORGDP Project, may yield good results for the remainder of the area to be surveyed by ORGDP with modifications for different geologic regions.

  5. A geochemical drainage survey of the Preseli Hills, south-west Dyfed, Wales

    OpenAIRE

    Cameron, D. G.; Cooper, D C; Allen, P.M.; Haslam, H.W.

    1984-01-01

    A geochemical drainage survey at a density of 1 sample per km2 was carried out across the Preseli Hills, southwest Dyfed. Stream sediment, water and panned concentrate samples were collected from each of 358 sites, and Cu, Pb, Zn, Ba, Fe, Mn, Co, Ni, V, Cr, B, Zr, As, MO and Sn were determined in sediment, Cu, Pb, Zn, Ba, Fe, Mn, Ti, Ni, Sn, As, Ca, Ce, Sr, Sb, Zr, U and MO in panned concentrate and Cu and Zn in water. From a study of regional variation patterns and ...

  6. A reconnaissance geochemical drainage survey of the Harlech Dome, north Wales

    OpenAIRE

    Cooper, D C; Bide, P.J.; Cameron, D. G.; Bell, N.; Allen, P M

    1985-01-01

    A geochemical drainage survey was carried out across 1 050 km’ of the Harlech Dome and adjacent areas at a mean density of 0.85 sample/km2. Fine (-100 mesh) stream sediment, panned concentrate and water samples were collected at every site. Cu, Pb, Zn, MO, As, Ba, Fe, Mn, Co, Ni, Cr, V and Zr were determined in stream sediment samples; Cu, Pb, Zn, Ba, Fe, Mn, Ti, Nl, Ce and Sn in panned concentrates, and Cu, Pb and Zn in water. Gold was determined in panned concentrate...

  7. Geochemical reanalysis of historical U.S. Geological Survey sediment samples from the Zane Hills, Hughes and Shungnak quadrangles, Alaska

    Science.gov (United States)

    Werdon, Melanie B.; Granitto, Matthew; Azain, Jaime S.

    2015-01-01

    The State of Alaska’s Strategic and Critical Minerals (SCM) Assessment project, a State-funded Capital Improvement Project (CIP), is designed to evaluate Alaska’s statewide potential for SCM resources. The SCM Assessment is being implemented by the Alaska Division of Geological & Geophysical Surveys (DGGS), and involves obtaining new airborne-geophysical, geological, and geochemical data. As part of the SCM Assessment, thousands of historical geochemical samples from DGGS, U.S. Geological Survey (USGS), and U.S. Bureau of Mines archives are being reanalyzed by DGGS using modern, quantitative, geochemical-analytical methods. The objective is to update the statewide geochemical database to more clearly identify areas in Alaska with SCM potential.The USGS is also undertaking SCM-related geologic studies in Alaska through the federally funded Alaska Critical Minerals cooperative project. DGGS and USGS share the goal of evaluating Alaska’s strategic and critical minerals potential and together created a Letter of Agreement (signed December 2012) and a supplementary Technical Assistance Agreement (#14CMTAA143458) to facilitate the two agencies’ cooperative work. Under these agreements, DGGS contracted the USGS in Denver to reanalyze historical USGS sediment samples from Alaska.For this report, DGGS funded reanalysis of 105 historical USGS sediment samples from the statewide Alaska Geochemical Database Version 2.0 (AGDB2; Granitto and others, 2013). Samples were chosen from the Zane Hills area in the Hughes and Shungnak quadrangles, Alaska (fig. 1). The USGS was responsible for sample retrieval from the National Geochemical Sample Archive (NGSA) in Denver, Colorado through the final quality assurance/quality control (QA/QC) of the geochemical analyses obtained through the USGS contract lab. The new geochemical data are published in this report as a coauthored DGGS report, and will be incorporated into the statewide geochemical databases of both agencies.

  8. Geochemical reanalysis of historical U.S. Geological Survey sediment samples from the Tonsina area, Valdez Quadrangle, Alaska

    Science.gov (United States)

    Werdon, Melanie B.; Granitto, Matthew; Azain, Jaime S.

    2015-01-01

    The State of Alaska’s Strategic and Critical Minerals (SCM) Assessment project, a State-funded Capital Improvement Project (CIP), is designed to evaluate Alaska’s statewide potential for SCM resources. The SCM Assessment is being implemented by the Alaska Division of Geological & Geophysical Surveys (DGGS), and involves obtaining new airborne-geophysical, geological, and geochemical data. As part of the SCM Assessment, thousands of historical geochemical samples from DGGS, U.S. Geological Survey (USGS), and U.S. Bureau of Mines archives are being reanalyzed by DGGS using modern, quantitative, geochemical-analytical methods. The objective is to update the statewide geochemical database to more clearly identify areas in Alaska with SCM potential. The USGS is also undertaking SCM-related geologic studies in Alaska through the federally funded Alaska Critical Minerals cooperative project. DGGS and USGS share the goal of evaluating Alaska’s strategic and critical minerals potential and together created a Letter of Agreement (signed December 2012) and a supplementary Technical Assistance Agreement (#14CMTAA143458) to facilitate the two agencies’ cooperative work. Under these agreements, DGGS contracted the USGS in Denver to reanalyze historical USGS sediment samples from Alaska. For this report, DGGS funded reanalysis of 128 historical USGS sediment samples from the statewide Alaska Geochemical Database Version 2.0 (AGDB2; Granitto and others, 2013). Samples were chosen from the Tonsina area in the Chugach Mountains, Valdez quadrangle, Alaska (fig. 1). The USGS was responsible for sample retrieval from the National Geochemical Sample Archive (NGSA) in Denver, Colorado through the final quality assurance/quality control (QA/QC) of the geochemical analyses obtained through the USGS contract lab. The new geochemical data are published in this report as a coauthored DGGS report, and will be incorporated into the statewide geochemical databases of both agencies

  9. Geological, geochemical, and geophysical survey of the geothermal resources at Hot Springs Bay Valley, Akutan Island, Alaska

    Energy Technology Data Exchange (ETDEWEB)

    Motyka, R.J.; Wescott, E.M.; Turner, D.L.; Swanson, S.E.; Romick, J.D.; Moorman, M.A.; Poreda, R.J.; Witte, W.; Petzinger, B.; Allely, R.D.

    1985-01-01

    An extensive survey was conducted of the geothermal resource potential of Hot Springs Bay Valley on Akutan Island. A topographic base map was constructed, geologic mapping, geophysical and geochemical surveys were conducted, and the thermal waters and fumarolic gases were analyzed for major and minor element species and stable isotope composition. (ACR)

  10. Analyzing legacy U.S. Geological Survey geochemical databases using GIS: applications for a national mineral resource assessment

    Science.gov (United States)

    Yager, Douglas B.; Hofstra, Albert H.; Granitto, Matthew

    2012-01-01

    This report emphasizes geographic information system analysis and the display of data stored in the legacy U.S. Geological Survey National Geochemical Database for use in mineral resource investigations. Geochemical analyses of soils, stream sediments, and rocks that are archived in the National Geochemical Database provide an extensive data source for investigating geochemical anomalies. A study area in the Egan Range of east-central Nevada was used to develop a geographic information system analysis methodology for two different geochemical datasets involving detailed (Bureau of Land Management Wilderness) and reconnaissance-scale (National Uranium Resource Evaluation) investigations. ArcGIS was used to analyze and thematically map geochemical information at point locations. Watershed-boundary datasets served as a geographic reference to relate potentially anomalous sample sites with hydrologic unit codes at varying scales. The National Hydrography Dataset was analyzed with Hydrography Event Management and ArcGIS Utility Network Analyst tools to delineate potential sediment-sample provenance along a stream network. These tools can be used to track potential upstream-sediment-contributing areas to a sample site. This methodology identifies geochemically anomalous sample sites, watersheds, and streams that could help focus mineral resource investigations in the field.

  11. National Geochemical Database: Soil

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — Geochemical analysis of soil samples from the National Geochemical Database. Primarily inorganic elemental concentrations, most samples are from the continental US...

  12. National Geochemical Database: Sediment

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — Geochemical analysis of sediment samples from the National Geochemical Database. Primarily inorganic elemental concentrations, most samples are of stream sediment in...

  13. Chemical elements in the environment: multi-element geochemical datasets from continental to national scale surveys on four continents

    Science.gov (United States)

    Caritat, Patrice de; Reimann, Clemens; Smith, David; Wang, Xueqiu

    2017-01-01

    During the last 10-20 years, Geological Surveys around the world have undertaken a major effort towards delivering fully harmonized and tightly quality-controlled low-density multi-element soil geochemical maps and datasets of vast regions including up to whole continents. Concentrations of between 45 and 60 elements commonly have been determined in a variety of different regolith types (e.g., sediment, soil). The multi-element datasets are published as complete geochemical atlases and made available to the general public. Several other geochemical datasets covering smaller areas but generally at a higher spatial density are also available. These datasets may, however, not be found by superficial internet-based searches because the elements are not mentioned individually either in the title or in the keyword lists of the original references. This publication attempts to increase the visibility and discoverability of these fundamental background datasets covering large areas up to whole continents.

  14. Geochemical and geophysical investigations, and fluid inclusion studies in the exploration area of Zafarghand (Northeast Isfahan, Iran

    Directory of Open Access Journals (Sweden)

    Zahra Alaminia

    2017-11-01

    Full Text Available Introduction Urumieh-Dokhtar Magmatic Arc (UDMA is a good prospective area for Cu, Cu-Mo and Cu-Au deposits (Fig. 1A and B. The Zafarghand district is located in the central part of the UDMA and the northeastern Isfahan. The present study concerns geological observations, alteration investigations, geochemical data and fluid inclusion studies. The purpose of the research is to identify geochemical anomalies and source of metals in this area. Geochemical anomalies for mineralizing elements and element associations were identified by using statistical analysis methods. Additionally, these results together suggest a site for exploration drilling in this study area. Materials and methods We collected 186 samples (rock along multi-cross sections oriented perpendicular to the strike of the South -Ardestan fault (Fig. 2.Trace element concentrations were determined by the ICP-MS technique in Amdel laboratory (Australia. Thin sections and doubly polished sections (100–200 µm thick from quartz veins were prepared from samples collected from the Zafarghand district in the University of Isfahan. Heating and freezing experiments on fluid inclusions were performed as defined (by Goldstein and Reynolds (1994 on a Linkam THM600 stage. Results Igneous rocks in the Zafarghand area are dominated by the Eocene and post Eocene acidic-intermediate rocks that include dacite, rhyodacite and andesite associated with diorite, quartz diorite and microdiorite intrusions. The present investigations indicate that all rocks of the Zafarghand district exhibit a variety of alterations. Hydrothermal alterations include phyllic, potassic, silicification, and argillic with widespread propylitic. The mineralization consists of malachite, azurite, hematite, and goethite, rare amounts of magnetite, pyrite, and chalcopyrite. Numerical traditional statistical analysis techniques have been applied to interpret the geochemical data of the study area. These methods are aimed at

  15. Geochemical investigations by the U.S. Geological Survey on uranium mining, milling, and environmental restoration

    Science.gov (United States)

    Landa, Edward R.; Cravotta, Charles A.; Naftz, David L.; Verplanck, Philip L.; Nordstrom, D. Kirk; Zielinski, Robert A.

    2000-01-01

    Recent research by the U.S. Geological Survey has characterized contaminant sources and identified important geochemical processes that influence transport of radionuclides from uranium mining and milling wastes. 1) Selective extraction studies indicated that alkaline earth sulfates and hydrous ferric oxides are important hosts of 226Ra in uranium mill tailings. The action of sulfate-reducing and ironreducing bacteria on these phases was shown to enhance release of radium, and this adverse result may temper decisions to dispose of uranium mill tailings in anaerobic environments. 2) Field studies have shown that although surface-applied sewage sludge/wood chip amendments aid in revegetating pyritic spoil, the nitrogen in sludge leachate can enhance pyrite oxidation, acidification of groundwater, and the consequent mobilization of metals and radionuclides. 3) In a U.S. Environmental Protection Agencyfunded study, three permeable reactive barriers consisting of phosphate-rich material, zero-valent iron, or amorphous ferric oxyhydroxide have been installed at an abandoned uranium upgrader facility near Fry Canyon, UT. Preliminary results indicate that each of the permeable reactive barriers is removing the majority of the uranium from the groundwater. 4) Studies on the geochemistry of rare earth elements as analogues for actinides such as uranium and thorium in acid mine drainage environments indicate high mobility under acid-weathering conditions but measurable attenuation associated with iron and aluminum colloid formation. Mass balances from field and laboratory studies are being used to quantify the amount of attenuation. 5) A field study in Colorado demonstrated the use of 234U/238U isotopic ratio measurements to evaluate contamination of shallow groundwater with uranium mill effluent.

  16. Geochemical exploration of a promissory Enhanced Geothermal System (EGS): the Acoculco caldera, Mexico.

    Science.gov (United States)

    Peiffer, Loic; Romero, Ruben Bernard; Pérez-Zarate, Daniel; Guevara, Mirna; Santoyo Gutiérrez, Edgar

    2014-05-01

    The Acoculco caldera (Puebla, Mexico) has been identified by the Mexican Federal Electricity Company (in Spanish 'Comisión Federal de Electricidad', CFE) as a potential Enhanced Geothermal System (EGS) candidate. Two exploration wells were drilled and promising temperatures of ~300° C have been measured at a depth of 2000 m with a geothermal gradient of 11oC/100m, which is three times higher than the baseline gradient measured within the Trans-Mexican Volcanic Belt. As usually observed in Hot Dry Rock systems, thermal manifestations in surface are scarce and consist in low-temperature bubbling springs and soil degassing. The goals of this study were to identify the origin of these fluids, to estimate the soil degassing rate and to explore new areas for a future detailed exploration and drilling activities. Water and gas samples were collected for chemical and isotopic analysis (δ18O, δD, 3He/4He, 13C, 15N) and a multi-gas (CO2, CH4, H2S) soil survey was carried out using the accumulation chamber method. Springs' compositions indicate a meteoric origin and the dissolution of CO2 and H2S-rich gases, while gas compositions reveal a MORB-type origin mixed with some arc-type contribution. Gas geothermometry results are similar to temperatures measured during well drilling (260° C-300° C). Amongst all measured CO2 fluxes, only 5% (mean: 5543 g m-2 day-1) show typical geothermal values, while the remaining fluxes are low and correspond to biogenic degassing (mean: 18 g m-2 day-1). The low degassing rate of the geothermal system is a consequence of the intense hydrothermal alteration observed in the upper 800 m of the system which acts as an impermeable caprock. Highest measured CO2 fluxes (above > 600 g m-2 day-1) have corresponding CH4/CO2 flux ratios similar to mass ratios of sampled gases, which suggest an advective fluid transport. To represent field conditions, a numerical model was also applied to simulate the migration of CO2 towards the surface through a

  17. Exploring Geochemical Markers of the Anthropocene in River Sediments: Southern New England

    Science.gov (United States)

    Tran, J.

    2015-12-01

    The sedimentary record of New England is complex. From glacial till to colonial land use to the industrial revolution, any sediment preserved is intertwined and muddled by humans. Recent studies support the idea that any anthropogenic markers in the sediment record are site specific. Southern New England is marked by a myriad of practices including farming, charcoal kilns, hatting, mill dams, and iron furnaces. While specific markers of the anthropocene have been identified, little work has been done to correlate and quantify these noted markers across multiple basins. Specifically, a combination of x-ray fluorescence (XRF), x-ray diffraction (XRD), and grain size analysis were done on sediment cores taken within Southern New England across various watersheds. We present a combination of geochemical analysis and detrital zircon geochronology in order identify and account for basin differences. This in turn results in a more comprehensive trans-basin understanding of the anthropocene in this region. We observe strong evidence that supports the idea of geochemical markers anthropocene which include an increase in Mercury and Lead content in the sediments. Additionally, in basins where mill dams are present we observe sediment records consistent with flood events and dam degradation. While still fairly novel and understudied, our results provide insight to the much often question topic of the anthropocene in relation to this particular region and the potential pitfalls of doing large scale anthropogenic dating.

  18. The U.S. geological survey rass-statpac system for management and statistical reduction of geochemical data

    Science.gov (United States)

    VanTrump, G.; Miesch, A.T.

    1977-01-01

    RASS is an acronym for Rock Analysis Storage System and STATPAC, for Statistical Package. The RASS and STATPAC computer programs are integrated into the RASS-STATPAC system for the management and statistical reduction of geochemical data. The system, in its present form, has been in use for more than 9 yr by scores of U.S. Geological Survey geologists, geochemists, and other scientists engaged in a broad range of geologic and geochemical investigations. The principal advantage of the system is the flexibility afforded the user both in data searches and retrievals and in the manner of statistical treatment of data. The statistical programs provide for most types of statistical reduction normally used in geochemistry and petrology, but also contain bridges to other program systems for statistical processing and automatic plotting. ?? 1977.

  19. Soil geochemical survey of abandoned mining sites in the Eastern-Central Peloritani Mountains, Sicily, Italy

    Science.gov (United States)

    Consenza, A.; Lima, A.; Ayuso, Robert A.; Foley, Nora K.; Albanese, S.; Messina, A.; De Vivo, B.

    2015-01-01

    This investigation focused on topsoils (n = 122) and vertical profiles (n = 6) distributed over an area of 250 km2 in the eastern-central Peloritani Mountains, northeastern Sicily. Georeferenced concentration of 53 elements (including potentially harmful ones), determined by ICP-MS after an aqua regia leach, were used to produce geochemical maps by means of a GIS-aided spatial interpolation process. Results show that there are two distinct areas: the larger, located between the Fiumendinisi, Budali and Ali villages, and the other between C. Postlioni and Femmina Morta, which contain anomalous As (up to 727 mg/kg), Sb (up to 60 mg/kg), Ag (up to 1 mg/kg) and Au (up to 0.1 mg/kg) concentrations. Most of the investigated areas have high contamination levels for As, Zn, Sb, and Pb that exceed the threshold values (As = 20 mg/kg, Zn = 150 mg/kg, Sb = 10 mg/kg and Pb = 100 mg/kg) established for soils by the Italian Environmental Law (Decreto Legislativo 2006, number 152).The isotopic ratios of 206Pb/207Pb and 208Pb/207Pb have been measured in selected soils on both leaches [using 1M HNO3–1.75M HCl (50:50)] and residues thereof. Soil leach reflects possible anthropogenic contamination, whereas soil residues indicate geogenic contributions. Results suggest that most of contamination in the soils is related to the presence of sulphide and sulphosalt rock-forming minerals in the surveyed area. The soil fraction contains a Pb value >1600 mg/kg and has ratios of 1.1695 for 206Pb/207Pb and 2.4606 for 208Pb/207Pb. Only one soil leach isotopic composition could reflect possible anthropogenic contamination. The correlation among As, Zn, Pb contents v. Pb isotopic signatures of 206Pb/207Pb indicates that surface and deep soils collected from profiles are dominated by geogenic compositions.

  20. The Source, Spatial Distribution and Risk Assessment of Heavy Metals in Soil from the Pearl River Delta Based on the National Multi-Purpose Regional Geochemical Survey.

    Science.gov (United States)

    Zhang, Lingyan; Guo, Shuhai; Wu, Bo

    2015-01-01

    The data on the heavy metal content at different soil depths derived from a multi-purpose regional geochemical survey in the Pearl River Delta (PRD) were analyzed using ArcGIS 10.0. By comparing their spatial distributions and areas, the sources of heavy metals (Cd, Hg, As and Pb) were quantitatively identified and explored. Netted measuring points at 25 ×25 km were set over the entire PRD according to the geochemical maps. Based on the calculation data obtained from different soil depths, the concentrations of As and Cd in a large area of the PRD exceeded the National Second-class Standard. The spatial disparity of the geometric centers in the surface soil and deep soil showed that As in the surface soil mainly came from parent materials, while Cd had high consistency in different soil profiles because of deposition in the soil forming process. The migration of Cd also resulted in a considerable ecological risk to the Beijiang and Xijiang River watershed. The potential ecological risk index followed the order Cd ≥ Hg > Pb > As. According to the sources, the distribution trends and the characteristics of heavy metals in the soil from the perspective of the whole area, the Cd pollution should be repaired, especially in the upper reaches of the Xijiang and Beijiang watershed to prevent risk explosion while the pollution of Hg and Pb should be controlled in areas with intense human activity, and supervision during production should be strengthened to maintain the ecological balance of As.

  1. Short-range variability of soil pH in a regional geochemical survey, communicating uncertainty to the data user

    Science.gov (United States)

    Ander, Louise; Knights, Kate; Lark, Murray

    2015-04-01

    The north of Ireland is well-furnished with geochemical data after completion of the Tellus survey of Northern Ireland and the Tellus Border survey of six northern counties of the Republic of Ireland. These data are of considerable interest to the agricultural sector, in particular the data on soil pH. However, a geochemical survey at regional scale cannot resolve significant variation of soil pH, in particular effects of soil management and fine-scale variation of superficial material. This leads to uncertainties in the mapped soil pH which must be accounted for when making decisions about management interventions, including more detailed local sampling. In this poster we show how uncertainty of predicted soil pH, relative to established threshold values, can be quantified by disjunctive kriging. The uncertainty is expressed in terms of probabilities. We show how this can be communicated to the data user by means of the calibrated phrases of the IPCC, using results from recent research on its efficacy to modify its presentation.

  2. Geochemical reanalysis of historical U.S. Geological Survey sediment samples from the northeastern Alaska Range, Healy, Mount Hayes, Nabesna, and Tanacross quadrangles, Alaska

    Science.gov (United States)

    Werdon, Melanie B.; Granitto, Matthew; Azain, Jaime S.

    2015-01-01

    The State of Alaska’s Strategic and Critical Minerals (SCM) Assessment project, a State-funded Capital Improvement Project (CIP), is designed to evaluate Alaska’s statewide potential for SCM resources. The SCM Assessment is being implemented by the Alaska Division of Geological & Geophysical Surveys (DGGS), and involves obtaining new airborne-geophysical, geological, and geochemical data. As part of the SCM Assessment, thousands of historical geochemical samples from DGGS, U.S. Geological Survey (USGS), and U.S. Bureau of Mines archives are being reanalyzed by DGGS using modern, quantitative, geochemical-analytical methods. The objective is to update the statewide geochemical database to more clearly identify areas in Alaska with SCM potential. The USGS is also undertaking SCM-related geologic studies in Alaska through the federally funded Alaska Critical Minerals cooperative project. DGGS and USGS share the goal of evaluating Alaska’s strategic and critical minerals potential and together created a Letter of Agreement (signed December 2012) and a supplementary Technical Assistance Agreement (#14CMTAA143458) to facilitate the two agencies’ cooperative work. Under these agreements, DGGS contracted the USGS in Denver to reanalyze historical USGS sediment samples from Alaska. For this report, DGGS funded reanalysis of 670 historical USGS sediment samples from the statewide Alaska Geochemical Database Version 2.0 (AGDB2; Granitto and others, 2013). Samples were chosen from the northeastern Alaska Range, in the Healy, Mount Hayes, Nabesna, and Tanacross quadrangles, Alaska (fig. 1). The USGS was responsible for sample retrieval from the National Geochemical Sample Archive (NGSA) in Denver, Colorado through the final quality assurance/quality control (QA/QC) of the geochemical analyses obtained through the USGS contract lab. The new geochemical data are published in this report as a coauthored DGGS report, and will be incorporated into the statewide geochemical

  3. Geochemical reanalysis of historical U.S. Geological Survey sediment samples from the Kougarok area, Bendeleben and Teller quadrangles, Seward Peninsula, Alaska

    Science.gov (United States)

    Werdon, Melanie B.; Granitto, Matthew; Azain, Jaime S.

    2015-01-01

    The State of Alaska’s Strategic and Critical Minerals (SCM) Assessment project, a State-funded Capital Improvement Project (CIP), is designed to evaluate Alaska’s statewide potential for SCM resources. The SCM Assessment is being implemented by the Alaska Division of Geological & Geophysical Surveys (DGGS), and involves obtaining new airborne-geophysical, geological, and geochemical data. As part of the SCM Assessment, thousands of historical geochemical samples from DGGS, U.S. Geological Survey (USGS), and U.S. Bureau of Mines archives are being reanalyzed by DGGS using modern, quantitative, geochemical-analytical methods. The objective is to update the statewide geochemical database to more clearly identify areas in Alaska with SCM potential. The USGS is also undertaking SCM-related geologic studies in Alaska through the federally funded Alaska Critical Minerals cooperative project. DGGS and USGS share the goal of evaluating Alaska’s strategic and critical minerals potential and together created a Letter of Agreement (signed December 2012) and a supplementary Technical Assistance Agreement (#14CMTAA143458) to facilitate the two agencies’ cooperative work. Under these agreements, DGGS contracted the USGS in Denver to reanalyze historical USGS sediment samples from Alaska. For this report, DGGS funded reanalysis of 302 historical USGS sediment samples from the statewide Alaska Geochemical Database Version 2.0 (AGDB2; Granitto and others, 2013). Samples were chosen from the Kougarok River drainage as well as smaller adjacent drainages in the Bendeleben and Teller quadrangles, Seward Peninsula, Alaska (fig. 1). The USGS was responsible for sample retrieval from the National Geochemical Sample Archive (NGSA) in Denver, Colorado through the final quality assurance/quality control (QA/QC) of the geochemical analyses obtained through the USGS contract lab. The new geochemical data are published in this report as a coauthored DGGS report, and will be incorporated

  4. Distinguishing between natural and anthropogenic sources for elements in the environment: regional geochemical surveys versus enrichment factors.

    Science.gov (United States)

    Reimann, Clemens; de Caritat, Patrice

    2005-01-20

    High element enrichment factors (EFs) are commonly used in the literature to support the hypothesis that a particular suite of elements is of anthropogenic origin. Real-world examples of regional geochemical surveys demonstrate that EFs can be high or low due to a multitude of reasons, of which contamination is but one. This applies to EFs calculated relative to either the crust or some local background (e.g., a deeper soil layer). Results from local studies near industrial centres showing high (and pollution-related) EFs cannot be generalised over large areas or for sample sites far removed (i.e., more than some tens of kilometers) from a likely pollution source. Regional-scale geochemical mapping, on the other hand, facilitates the reliable estimation of the influence of contamination on the measured element concentrations. EFs are strongly influenced by, among other factors, biogeochemical processes that redistribute chemical elements between environmental compartments at the Earth's surface. Using EFs to detect or 'prove' human influence on element cycles in remote areas should be avoided because, in most cases, high EFs cannot conclusively demonstrate, nor even suggest, such influence.

  5. National Geochemical Database: Concentrate

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — Geochemistry of concentrates from the National Geochemical Database. Primarily inorganic elemental concentrations, most samples are from the continental US and...

  6. Trace elements in tourmalines from massive sulfide deposits and tourmalinites: Geochemical controls and exploration applications

    Science.gov (United States)

    Griffin, W.L.; Slack, J.F.; Ramsden, A.R.; Win, T.T.; Ryan, C.G.

    1996-01-01

    hydrothermal formation, in spite of variable metamorphic recrystallization. Such trace element patterns in massive sulfide tourmalines may be useful in mineral exploration, specifically for the evaluation of tourmaline concentrations in rocks, soils, and stream sediments.

  7. Microbiological and Geochemical Survey of CO2-Dominated Mofette and Mineral Waters of the Cheb Basin, Czech Republic

    Directory of Open Access Journals (Sweden)

    Patryk Krauze

    2017-12-01

    Full Text Available The Cheb Basin (NW Bohemia, Czech Republic is a shallow, neogene intracontinental basin. It is a non-volcanic region which features frequent earthquake swarms and large-scale diffuse degassing of mantle-derived CO2 at the surface that occurs in the form of CO2-rich mineral springs and wet and dry mofettes. So far, the influence of CO2 degassing onto the microbial communities has been studied for soil environments, but not for aquatic systems. We hypothesized, that deep-trenching CO2 conduits interconnect the subsurface with the surface. This admixture of deep thermal fluids should be reflected in geochemical parameters and in the microbial community compositions. In the present study four mineral water springs and two wet mofettes were investigated through an interdisciplinary survey. The waters were acidic and differed in terms of organic carbon and anion/cation concentrations. Element geochemical and isotope analyses of fluid components were used to verify the origin of the fluids. Prokaryotic communities were characterized through quantitative PCR and Illumina 16S rRNA gene sequencing. Putative chemolithotrophic, anaerobic and microaerophilic organisms connected to sulfur (e.g., Sulfuricurvum, Sulfurimonas and iron (e.g., Gallionella, Sideroxydans cycling shaped the core community. Additionally, CO2-influenced waters form an ecosystem containing many taxa that are usually found in marine or terrestrial subsurface ecosystems. Multivariate statistics highlighted the influence of environmental parameters such as pH, Fe2+ concentration and conductivity on species distribution. The hydrochemical and microbiological survey introduces a new perspective on mofettes. Our results support that mofettes are either analogs or rather windows into the deep biosphere and furthermore enable access to deeply buried paleo-sediments.

  8. The Source, Spatial Distribution and Risk Assessment of Heavy Metals in Soil from the Pearl River Delta Based on the National Multi-Purpose Regional Geochemical Survey.

    Directory of Open Access Journals (Sweden)

    Lingyan Zhang

    Full Text Available The data on the heavy metal content at different soil depths derived from a multi-purpose regional geochemical survey in the Pearl River Delta (PRD were analyzed using ArcGIS 10.0. By comparing their spatial distributions and areas, the sources of heavy metals (Cd, Hg, As and Pb were quantitatively identified and explored. Netted measuring points at 25 ×25 km were set over the entire PRD according to the geochemical maps. Based on the calculation data obtained from different soil depths, the concentrations of As and Cd in a large area of the PRD exceeded the National Second-class Standard. The spatial disparity of the geometric centers in the surface soil and deep soil showed that As in the surface soil mainly came from parent materials, while Cd had high consistency in different soil profiles because of deposition in the soil forming process. The migration of Cd also resulted in a considerable ecological risk to the Beijiang and Xijiang River watershed. The potential ecological risk index followed the order Cd ≥ Hg > Pb > As. According to the sources, the distribution trends and the characteristics of heavy metals in the soil from the perspective of the whole area, the Cd pollution should be repaired, especially in the upper reaches of the Xijiang and Beijiang watershed to prevent risk explosion while the pollution of Hg and Pb should be controlled in areas with intense human activity, and supervision during production should be strengthened to maintain the ecological balance of As.

  9. Geochemical soil survey of the Netherlands. Atlas of major and trace elements in topsoil and parent material; assessment of natural and anthropegenic enrichment factors

    NARCIS (Netherlands)

    Veer, G. van der

    2006-01-01

    Geochemical surveying is a generic tool to provide high quality, multi-element databases of the Earth’s surface compartments such as soil, sediment, and stream water. Such databases are not only an essential component of environmental knowledge, but also of relevance to other fields such as spatial

  10. The geochemical atlas of Alaska, 2016

    Science.gov (United States)

    Lee, Gregory K.; Yager, Douglas B.; Mauk, Jeffrey L.; Granitto, Matthew; Denning, Paul D.; Wang, Bronwen; Werdon, Melanie B.

    2016-06-21

    A rich legacy of geochemical data produced since the early 1960s covers the great expanse of Alaska; careful treatment of such data may provide significant and revealing geochemical maps that may be used for landscape geochemistry, mineral resource exploration, and geoenvironmental investigations over large areas. To maximize the spatial density and extent of data coverage for statewide mapping of element distributions, we compiled and integrated analyses of more than 175,000 sediment and soil samples from three major, separate sources: the U.S. Geological Survey, the National Uranium Resource Evaluation program, and the Alaska Division of Geological & Geophysical Surveys geochemical databases. Various types of heterogeneity and deficiencies in these data presented major challenges to our development of coherently integrated datasets for modeling and mapping of element distributions. Researchers from many different organizations and disparate scientific studies collected samples that were analyzed using highly variable methods throughout a time period of more than 50 years, during which many changes in analytical techniques were developed and applied. Despite these challenges, the U.S. Geological Survey has produced a new systematically integrated compilation of sediment and soil geochemical data with an average sample site density of approximately 1 locality per 10 square kilometers (km2) for the entire State of Alaska, although density varies considerably among different areas. From that compilation, we have modeled and mapped the distributions of 68 elements, thus creating an updated geochemical atlas for the State.

  11. Self-organizing maps in geothermal exploration-A new approach for understanding geochemical processes and fluid evolution

    Science.gov (United States)

    Brehme, Maren; Bauer, Klaus; Nukman, Mochamad; Regenspurg, Simona

    2017-04-01

    Understanding geochemical processes is an important part of geothermal exploration to get information about the source and evolution of geothermal fluids. However, in most cases knowledge of fluid properties is based on few parameters determined in samples from the shallow subsurface. This study presents a new approach that allows to conclude from the combination of a variety of these data on processes occurring at depth in a geothermal reservoir. The neural network clustering technique called ;self-organizing maps; (SOMs) successfully distinguished two different geothermal settings based on a hydrochemical database and disclosed the source, evolution and flow pathways of geothermal fluids. Scatter plots, as shown in this study, are appropriate presentations of element concentrations and the chemical interaction of water and rock at depth. One geological setting presented here is marked by fault dominated fluid pathways and minor influence of volcanic affected fluids with high concentrations of HCO3, Ca and Sr. The second is a magmatically dominated setting showing strong alteration features in volcanic rocks and accommodates acidic fluids with high SO4 and Si concentrations. Former studies, i.e., Giggenbach (1988), suggested Cl, HCO3 and SO4 to be generally the most important elements for understanding hydrochemical processes in geothermal reservoirs. Their relation has been widely used to classify different water types in geothermal fields. However, this study showed that non-standard elements are at least of same importance to reveal different fluid types in geothermal systems. Therefore, this study is an extended water classification approach using SOM for element correlations. SOM have been proven to be a successful method for analyzing even relatively small hydrochemical datasets in geothermal applications.

  12. Magnetic mineral exploration using ground magnetic survey data of ...

    African Journals Online (AJOL)

    Ground magnetic survey is an essential geophysical method employed in locating subsurface magnetic materials for possible exploration. In geophysics, the anomalous magnetization might be associated with local mineralization that is potentially of commercial interest. Hence a ground magnetic survey was carried out at a ...

  13. Geochemical reanalysis of historical U.S. Geological Survey sediment samples from the Haines area, Juneau and Skagway quadrangles, southeast Alaska

    Science.gov (United States)

    Werdon, Melanie B.; Granitto, Matthew; Azain, Jaime S.

    2015-01-01

    The State of Alaska’s Strategic and Critical Minerals (SCM) Assessment project, a State-funded Capital Improvement Project (CIP), is designed to evaluate Alaska’s statewide potential for SCM resources. The SCM Assessment is being implemented by the Alaska Division of Geological & Geophysical Surveys (DGGS), and involves obtaining new airborne-geophysical, geological, and geochemical data. As part of the SCM Assessment, thousands of historical geochemical samples from DGGS, U.S. Geological Survey (USGS), and U.S. Bureau of Mines archives are being reanalyzed by DGGS using modern, quantitative, geochemical-analytical methods. The objective is to update the statewide geochemical database to more clearly identify areas in Alaska with SCM potential. The USGS is also undertaking SCM-related geologic studies in Alaska through the federally funded Alaska Critical Minerals cooperative project. DGGS and USGS share the goal of evaluating Alaska’s strategic and critical minerals potential and together created a Letter of Agreement (signed December 2012) and a supplementary Technical Assistance Agreement (#14CMTAA143458) to facilitate the two agencies’ cooperative work. Under these agreements, DGGS contracted the USGS in Denver to reanalyze historical USGS sediment samples from Alaska. For this report, DGGS funded reanalysis of 212 historical USGS sediment samples from the statewide Alaska Geochemical Database Version 2.0 (AGDB2; Granitto and others, 2013). Samples were chosen from the Chilkat, Klehini, Tsirku, and Takhin river drainages, as well as smaller drainages flowing into Chilkat and Chilkoot Inlets near Haines, Skagway Quadrangle, Southeast Alaska. Additionally some samples were also chosen from the Juneau gold belt, Juneau Quadrangle, Southeast Alaska (fig. 1). The USGS was responsible for sample retrieval from the National Geochemical Sample Archive (NGSA) in Denver, Colorado through the final quality assurance/quality control (QA/QC) of the geochemical

  14. Reconnaissance geochemical study of a part of Igarra Schist Belt ...

    African Journals Online (AJOL)

    Geochemical exploration of Orle district within the Igarra schist belt in southwestern Nigeria was carried out using reconnaissance stream-sediment survey. A total of 56 samples were collected and chemically analysed for 22 trace elements including Au, Ag, As, Pb, Zn, Cu, Co, Mo, Hg, Sb, Tl, Sc, Cr, Ni, La, W, V, U, Th, ...

  15. Geological, geochemical, and geophysical studies by the U.S. Geological Survey in Big Bend National Park, Texas

    Science.gov (United States)

    Page, W.R.; Turner, K.J.; Bohannon, R.G.; Berry, M.E.; Williams, V.S.; Miggins, D.P.; Ren, M.; Anthony, E.Y.; Morgan, L.A.; Shanks, P.W.C.; Gray, J. E.; Theodorakos, P.M.; Krabbenhoft, D. P.; Manning, A.H.; Gemery-Hill, P. A.; Hellgren, E.C.; Stricker, C.A.; Onorato, D.P.; Finn, C.A.; Anderson, E.; Gray, J. E.; Page, W.R.

    2008-01-01

    Big Bend National Park (BBNP), Tex., covers 801,163 acres (3,242 km2) and was established in 1944 through a transfer of land from the State of Texas to the United States. The park is located along a 118-mile (190-km) stretch of the Rio Grande at the United States-Mexico border. The park is in the Chihuahuan Desert, an ecosystem with high mountain ranges and basin environments containing a wide variety of native plants and animals, including more than 1,200 species of plants, more than 450 species of birds, 56 species of reptiles, and 75 species of mammals. In addition, the geology of BBNP, which varies widely from high mountains to broad open lowland basins, also enhances the beauty of the park. For example, the park contains the Chisos Mountains, which are dominantly composed of thick outcrops of Tertiary extrusive and intrusive igneous rocks that reach an altitude of 7,832 ft (2,387 m) and are considered the southernmost mountain range in the United States. Geologic features in BBNP provide opportunities to study the formation of mineral deposits and their environmental effects; the origin and formation of sedimentary and igneous rocks; Paleozoic, Mesozoic, and Cenozoic fossils; and surface and ground water resources. Mineral deposits in and around BBNP contain commodities such as mercury (Hg), uranium (U), and fluorine (F), but of these, the only significant mining has been for Hg. Because of the biological and geological diversity of BBNP, more than 350,000 tourists visit the park each year. The U.S. Geological Survey (USGS) has been investigating a number of broad and diverse geologic, geochemical, and geophysical topics in BBNP to provide fundamental information needed by the National Park Service (NPS) to address resource management goals in this park. Scientists from the USGS Mineral Resources and National Cooperative Geologic Mapping Programs have been working cooperatively with the NPS and several universities on several research studies within BBNP

  16. Alaska Geochemical Database (AGDB) - Geochemical Data for Rock, Sediment, Soil, Mineral, and Concentrate Sample Media

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The Alaska Geochemical Database (AGDB) was created and designed to compile and integrate geochemical data from Alaska in order to facilitate geologic mapping,...

  17. DNA-based methods of geochemical prospecting

    Science.gov (United States)

    Ashby, Matthew [Mill Valley, CA

    2011-12-06

    The present invention relates to methods for performing surveys of the genetic diversity of a population. The invention also relates to methods for performing genetic analyses of a population. The invention further relates to methods for the creation of databases comprising the survey information and the databases created by these methods. The invention also relates to methods for analyzing the information to correlate the presence of nucleic acid markers with desired parameters in a sample. These methods have application in the fields of geochemical exploration, agriculture, bioremediation, environmental analysis, clinical microbiology, forensic science and medicine.

  18. Gas geochemical survey of long dormant Ciomadul volcano (South Harghita Mts., Romania): constraints on the flux and origin of fluids

    Science.gov (United States)

    Kis, Boglárka-Mercedesz; Ionescu, Artur; Harangi, Szabolcs; Palcsu, László; Etiope, Giuseppe; Baciu, Cǎlin

    2016-04-01

    The Ciomadul, located in the South Harghita Mountains (Eastern Carpathians, Romania) is the youngest volcano built by the Neogene volcanism in the Carpathian-Pannonian Region. The volcanic activity was characterized by an initial extrusive lava dome building period from about 200 ka to 100 ka followed by a more explosive eruption stage from 57 to 32 ka. Although the volcano seems to be inactive, several features (e.g. geophysical anomalies in the crust; fast remobilization of near solidus long lasting crystal mush prior to the past eruptions) suggest that melt-bearing magmatic body could still exist beneath the Ciomadul. This is supported by the abundance of dry gas emanations (CO2, CH4, H2S), CO2 rich mineral water springs and bubbling pools. The long-term observation of seemingly inactive, dormant volcanoes has become important in the past years (Ontake volcano-Japan, Colli Albani volcano-Italy). Gas-geochemical survey and monitoring (noble gases, isotopic composition of carbon species, flux measurements) of such volcanoes is an adequate tool in detecting changes in their volcanic plumbing system. Starting from 2015 we commenced a gas-monitoring study to constrain the origin of fluids at Ciomadul by measuring the flux of two gas-species and collecting the gas-phase from several mofettes and mineral water springs. A total of 46 sites have been surveyed, including 29 gas emanations (mofettes and bubbling pools), 3 drilled wells, 11 springs and 3 surface water sites. We provide the first complex CO2 and CH4 flux measurements in the area considering mofettes and bubbling pools. The CO2 flux values range between 10 and 264 kg/day while the CH4 flux has a range between 125 and 4723 g/day. Estimates of total CO2 and CH4 output into the atmosphere are ~229 and ~1.3 t/year, respectively. These values are consistent with other geothermal systems in Europe. The chemical composition of samples indicate CO2 content of up to 96.77%, CH4 content up to 1.42% and He content up to

  19. Exploring CRRT practices in ICU: a survey of Canadian hospitals.

    Science.gov (United States)

    Langford, Stephanie; Slivar, Sharon; Tucker, Sue Malone; Bourbonnais, Frances Fothergill

    2008-01-01

    Continuous renal replacement therapy (CRRT) is a highly specialized therapy not only for patients with acute renal failure, but also for patients with other critical conditions. The nursing work involved in CRRT is complex and the learning requirements are challenging to sustain ongoing competence. There are also adverse events associated with CRRT, such as those resulting from the anticoagulation therapy. Limited nursing literature is available regarding the use of CRRT by nurses in Canadian intensive care units. In 2005, the authors conducted a national survey of CRRT nursing practices with nurse educators in intensive care units. The survey had fixed choice, as well as open-ended questions exploring various aspects of CRRT implementation, including education provided and adverse events experienced by patients. Of the 53 teaching and non-teaching hospitals that were sent the survey, 50 replied (94% response rate). Thirty-four of the sites used CRRT. The results reported here represent the findings from the survey questions pertaining to education and adverse events only. The results indicate that education, continuing competence, and prevention and management of adverse events, such as bleeding and filter clotting, are the major issues related to CRRT nursing practice across Canada.

  20. Reanalysis of historical U.S. Geological Survey sediment samples for geochemical data from the western part of the Wrangellia terrane, Anchorage, Gulkana, Healy, Mt. Hayes, Nabesna, and Talkeetna Mountains quadrangles, Alaska

    Science.gov (United States)

    Werdon, Melanie B.; Azain, Jaime S.; Granitto, Matthew

    2014-01-01

    The State of Alaska’s Strategic and Critical Minerals (SCM) Assessment project, a State-funded Capital Improvement Project (CIP), is designed to evaluate Alaska’s statewide potential for SCM resources. The SCM Assessment is being implemented by the Alaska Division of Geological & Geophysical Surveys (DGGS), and involves obtaining new airborne-geophysical, geological, and geochemical data. For the geochemical part of the SCM Assessment, thousands of historical geochemical samples from DGGS, U.S. Geological Survey (USGS), and U.S. Bureau of Mines archives are being reanalyzed by DGGS using modern, quantitative, geochemical-analytical methods. The objective is to update the statewide geochemical database to more clearly identify areas in Alaska with SCM potential. The USGS is also undertaking SCM-related geologic studies in Alaska through the federally funded Alaska Critical Minerals cooperative project. DGGS and USGS share the goal of evaluating Alaska’s strategic and critical minerals potential and together created a Letter of Agreement (signed December 2012) and a supplementary Technical Assistance Agreement (#14CMTAA143458) to facilitate the two agencies’ cooperative work. Under these agreements, DGGS contracted the USGS in Denver to reanalyze historical USGS sediment samples from Alaska. For this report, DGGS funded reanalysis of 1,682 historical USGS sediment samples from the statewide Alaska Geochemical Database Version 2.0 (AGDB2; Granitto and others, 2013). Samples were chosen from an area covering the western half of the Wrangellia Terrane in the Anchorage, Gulkana, Healy, Mt. Hayes, Nabesna, and Talkeetna Mountains quadrangles of south-central Alaska (fig. 1). USGS was responsible for sample retrieval from the Denver warehouse through the final quality assurance/quality control (QA/QC) of the geochemical analyses obtained through the USGS contract lab. The new geochemical data are published in this report as a coauthored DGGS report, and will be

  1. Geochemical reanalysis of historical U.S. Geological Survey sediment samples from the Inmachuk, Kugruk, Kiwalik, and Koyuk River drainages, Granite Mountain, and the northern Darby Mountains, Bendeleben, Candle, Kotzebue, and Solomon quadrangles, Alaska

    Science.gov (United States)

    Werdon, Melanie B.; Granitto, Matthew; Azain, Jaime S.

    2015-01-01

    The State of Alaska’s Strategic and Critical Minerals (SCM) Assessment project, a State-funded Capital Improvement Project (CIP), is designed to evaluate Alaska’s statewide potential for SCM resources. The SCM Assessment is being implemented by the Alaska Division of Geological & Geophysical Surveys (DGGS), and involves obtaining new airborne-geophysical, geological, and geochemical data. As part of the SCM Assessment, thousands of historical geochemical samples from DGGS, U.S. Geological Survey (USGS), and U.S. Bureau of Mines archives are being reanalyzed by DGGS using modern, quantitative, geochemical-analytical methods. The objective is to update the statewide geochemical database to more clearly identify areas in Alaska with SCM potential. The USGS is also undertaking SCM-related geologic studies in Alaska through the federally funded Alaska Critical Minerals cooperative project. DGGS and USGS share the goal of evaluating Alaska’s strategic and critical minerals potential and together created a Letter of Agreement (signed December 2012) and a supplementary Technical Assistance Agreement (#14CMTAA143458) to facilitate the two agencies’ cooperative work. Under these agreements, DGGS contracted the USGS in Denver to reanalyze historical USGS sediment samples from Alaska. For this report, DGGS funded reanalysis of 653 historical USGS sediment samples from the statewide Alaska Geochemical Database Version 2.0 (AGDB2; Granitto and others, 2013). Samples were chosen from an area covering portions of the Inmachuk, Kugruk, Kiwalik, and Koyuk river drainages, Granite Mountain, and the northern Darby Mountains, located in the Bendeleben, Candle, Kotzebue, and Solomon quadrangles of eastern Seward Peninsula, Alaska (fig. 1). The USGS was responsible for sample retrieval from the National Geochemical Sample Archive (NGSA) in Denver, Colorado through the final quality assurance/quality control (QA/QC) of the geochemical analyses obtained through the USGS contract

  2. Predicted risk of cobalt deficiency in grazing sheep from a geochemical survey; communicating uncertainty with the IPCC verbal scale.

    Science.gov (United States)

    Lark, R. M.; Ander, E. L.; Cave, M. R.; Knights, K. V.; Glennon, M. M.; Scanlon, R. P.

    2014-05-01

    Deficiency or excess of certain trace elements in the soil causes problems for agriculture, including disorders of grazing ruminants. Farmers and their advisors in Ireland use index values for the concentration of total soil cobalt and manganese to identify where grazing sheep are at risk of cobalt deficiency. We used cokriging with topsoil data from a regional geochemical survey across six counties of Ireland to form local cokriging predictions of cobalt and manganese concentrations with an attendant distribution which reflects the joint uncertainty of these predictions. From this distribution we then computed conditional probabilities for different combinations of cobalt and manganese index values, and so for the corresponding inferred risk to sheep of cobalt deficiency and the appropriateness of different management interventions. The challenge is to communicate these results effectively to an audience comprising, inter alia, farmers, agronomists and veterinarians. Numerical probabilities are not generally well-understood by non-specialists. For this reason we presented our results as maps using a verbal scale to communicate the probability that a deficiency is indicated by local soil conditions, or that a particular intervention is indicated. In the light of recent research on the effectiveness of the verbal scale used by the Intergovernmental Panel on Climate Change to communicate probabilistic information we reported the geostatistical predictions as follows. First, we use the basic IPCC scale with intensifiers, but we also indicate the corresponding probabilities (as percentages) as recommended by Budescu et al. (2009). Second, we make it clear that the source of uncertainty in these predictions is the spatial variability of soil Co and Mn. The outcome under consideration is therefore that a particular soil management scenario would be indicated if the soil properties were known without error, possible uncertainty about the implications of particular soil

  3. Use of a time-domain electromagnetic method with geochemical tracers to explore the salinity anomalies in a small coastal aquifer in north-eastern Tunisia

    Science.gov (United States)

    Chekirbane, Anis; Tsujimura, Maki; Kawachi, Atsushi; Lachaal, Fethi; Isoda, Hiroko; Tarhouni, Jamila

    2014-12-01

    The study area is a small coastal plain in north-eastern Tunisia. It is drained by an ephemeral stream network and is subject to several pollutant discharges such as oilfield brine coming from a neighboring oil company and wastewater from Somâa city, located in the upstream of the plain. Furthermore, a hydraulic head near the coastal part of the aquifer is below sea level, suggesting that seawater intrusion may occur. A time-domain electromagnetic (TDEM) survey, based on 28 soundings, was conducted in Wadi Al Ayn and Daroufa plains to delineate the saline groundwater. Based on longitudinal and transversal resistivity two-dimensional pseudosections calibrated with boring data, the extent of saline water was identified. Geochemical tracers were combined with the resistivity dataset to differentiate the origin of groundwater salinization. In the upstream part of the plain, the infiltration of oilfield brine through the sandy bed of Wadi Al Ayn seems to have a considerable effect on groundwater salinization. However, in the coastal part of the aquifer, groundwater salinization is due to seawater intrusion and the saltwater is reaching an inland extent around 1.3 km from the shoreline. The contribution ratios of saline water bodies derived from the inverted chloride data vary for the oilfield brine from 1 to 13 % and for the seawater from 2 to 21 %.

  4. Selections from 2017: Hubble Survey Explores Distant Galaxies

    Science.gov (United States)

    Kohler, Susanna

    2017-12-01

    Editors note:In these last two weeks of 2017, well be looking at a few selections that we havent yet discussed on AAS Nova from among the most-downloaded paperspublished in AAS journals this year. The usual posting schedule will resume in January.CANDELS Multi-Wavelength Catalogs: Source Identification and Photometry in the CANDELS COSMOSSurvey FieldPublished January2017Main takeaway:A publication led byHooshang Nayyeri(UC Irvine and UC Riverside) early this year details acatalog of sources built using the Cosmic Assembly Near-infrared Deep Extragalactic Legacy Survey(CANDELS), a survey carried out by cameras on board the Hubble Space Telescope. The catalogliststhe properties of 38,000 distant galaxies visiblewithin the COSMOS field, a two-square-degree equatorial field explored in depthto answer cosmological questions.Why its interesting:Illustration showing the three-dimensional map of the dark matter distribution in theCOSMOS field. [Adapted from NASA/ESA/R. Massey(California Institute of Technology)]The depth and resolution of the CANDELS observations areuseful for addressingseveral major science goals, including the following:Studying the most distant objects in the universe at the epoch of reionization in the cosmic dawn.Understanding galaxy formation and evolution during the peak epoch of star formation in the cosmic high noon.Studying star formation from deep ultravioletobservations and studying cosmology from supernova observations.Why CANDELS is a major endeavor:CANDELS isthe largest multi-cycle treasury program ever approved on the Hubble Space Telescope using over 900 orbits between 2010 and 2013 withtwo cameras on board the spacecraftto study galaxy formation and evolution throughout cosmic time. The CANDELS images are all publicly available, and the new catalogrepresents an enormous source of information about distant objectsin our universe.CitationH. Nayyeri et al 2017 ApJS 228 7. doi:10.3847/1538-4365/228/1/7

  5. Geochemical characteristics of oil seepages from Dam Thi Nai, central Vietnam: implications for hydrocarbon exploration in the offshore Phu Khanh Basin

    Energy Technology Data Exchange (ETDEWEB)

    Bojesen Koefoed, J.A.; Nielsen, L.H.; Nytoft, H.P.; Petersen, H.I. [Geological Survey of Denmark and Greenland, Copenhagen (Denmark); Dau, N.T.; Van Hien, L.; Duc, N.A.; Quy, N.H. [Vietnam Petroluem Inst., Hanoi (Vietnam)

    2005-01-01

    Dam Thi Nai is a semi-enclosed embayment on the coast of central Vietnam, adjacent to the northern part of the offshore and largely unexplored Phu Khanh Basin. Seepages of oil have been known in Dam Thi Nai since the early part of the twentieth century. This paper presents organic geochemical data on a number of samples of seepage oil collected from Dam Thi Nai and discusses their implications for the prospectivity of the Phu Khanh Basin. The results indicate that the petroleum was generated from a Tertiary marine marl source rock. Seepage oils are found in varying degrees of biodegradation and modes of occurrence at different locations in the embayment. Thus, oil was observed to fill fractures in freshly quarried outcrops of Cretaceous granite, and also occurs in shallow pits dug in the beach sand and in shallow basins used for shrimp farming. The oils indicate active seepage from kitchen areas or leaking accumulations in the Phu Khanh Basin. Seismic data suggest the existence of both source rocks and kitchens, and indicate a possible migration route from the deep basin to the surface at the bay. A few samples show anomalous compositions, indicating the presence of two other oil types which have different sources. These occurrences cannot at present be explained. However, the results obtained are encouraging for future exploration in the Phu Khanh Basin. (Author)

  6. A GUPIX-based approach to interpreting the PIXE-plus-XRF spectra from the Mars Exploration rovers: II geochemical reference materials

    Energy Technology Data Exchange (ETDEWEB)

    Campbell, J.L., E-mail: icampbel@uoguelph.c [Guelph-Waterloo Physics Institute, University of Guelph, Guelph, Ontario, N1G 2W1 (Canada); McDonald, A.M. [Department of Earth Sciences, Laurentian University, Sudbury, Ontario, P3E 2E6 (Canada); Perrett, G.M. [Guelph-Waterloo Physics Institute, University of Guelph, Guelph, Ontario, N1G 2W1 (Canada); Taylor, S.M. [Department of Atmospheric and Oceanic Sciences, McGill University, Montreal, Quebec, H3A 2T5 (Canada)

    2011-01-01

    A detailed examination of the original calibration data for the laboratory version of the Mars Exploration Rover alpha particle X-ray spectrometer is undertaken to ascertain if the results from a suite of certified geochemical reference materials (GRMs) agree with the APXS calibration based upon homogeneous standards which was established in the previous paper. Various discrepancies, some of them large, are observed for specific elements in specific rock types, and it is argued on the basis of X-ray diffraction analyses of the GRMS that these are caused by the mineral phase structure of the rocks. Elements present in accessory mineral phases can be subject to very large errors, necessitating caution in interpretation of trace element results from the APXS. Some of the discrepancies can be dealt with by developing sub-calibrations, each of which is 'tuned' to a specific rock type. This approach has the potential to provide more accurate APXS analysis of unknown rocks than a calibration scheme based upon a simple averaging over many rock types within a GRM suite, or over a mix of rock and homogeneous standards. It also has the potential to measure the content of mineralogically bound water provided that a means of determining the distance from sample to detector is available.

  7. 50 CFR 37.45 - Exploration by the U.S. Geological Survey.

    Science.gov (United States)

    2010-10-01

    ... 50 Wildlife and Fisheries 6 2010-10-01 2010-10-01 false Exploration by the U.S. Geological Survey... INTERIOR (CONTINUED) THE NATIONAL WILDLIFE REFUGE SYSTEM GEOLOGICAL AND GEOPHYSICAL EXPLORATION OF THE....S. Geological Survey. Notwithstanding the requirement found in § 37.21(b) on when exploration plans...

  8. Geochemical Potamology

    Science.gov (United States)

    Gaillardet, J.

    2007-12-01

    The surface of our planet has been reworked by erosion and weathering processes throughout its geological history. Erosion processes are so fast that only 10's of millions years are necessary to remove major reliefs formed by plate tectonics. The material of the surface of the Earth has been recycled many times and the only visible remains of the ancient continental crust are in the sediments, in the atmosphere, or dissolved in the ocean. The chemical action of water on rocks and the associated physical gravity-driven processes are the key features of the « weathering engine ». Rivers are messengers from the surface of the Earth and integrate weathering processes at various scales of time and space. They provide a unique opportunity to have average information about the chemical interactions between surface waters and rocks, about their kinetics and about the major geochemical fractionations created by this major geological process. The study of rivers has been focused on small- and large-scale approaches, both giving different information. Although the sampling of small river basin allows us to simplify nature and separate the potential controlling parameters by fixing them (climate, vegetation, type of rock, slopes), the study of large rivers give global information about the composition of sediments, oceanic budgets, the significance of isotopic proxies. A geochemical potamology has developed over the last decades and we now more fully understand the critical questions that have to be solved. Numerous isotopic and elemental proxies have been developed to shed light on weathering processes, deciphering their control and calculate rates and timescales of erosion based on river products. A coupling between physical and chemical processes of erosion is now clear at different scales but probably the most important factor in controlling weathering style and rates are the protons. Low pH solutions are much more aggressive than neutral waters, as confirmed by

  9. The potential of mid- and near-infrared diffuse reflectance spectroscopy for determining major- and trace-element concentrations in soils from a geochemical survey of North America

    Science.gov (United States)

    Reeves, J. B.; Smith, D.B.

    2009-01-01

    In 2004, soils were collected at 220 sites along two transects across the USA and Canada as a pilot study for a planned soil geochemical survey of North America (North American Soil Geochemical Landscapes Project). The objective of the current study was to examine the potential of diffuse reflectance (DR) Fourier Transform (FT) mid-infrared (mid-IR) and near-infrared (NIRS) spectroscopy to reduce the need for conventional analysis for the determination of major and trace elements in such continental-scale surveys. Soil samples (n = 720) were collected from two transects (east-west across the USA, and north-south from Manitoba, Canada to El Paso, Texas (USA), n = 453 and 267, respectively). The samples came from 19 USA states and the province of Manitoba in Canada. They represented 31 types of land use (e.g., national forest, rangeland, etc.), and 123 different land covers (e.g., soybeans, oak forest, etc.). The samples represented a combination of depth-based sampling (0-5 cm) and horizon-based sampling (O, A and C horizons) with 123 different depths identified. The set was very diverse with few samples similar in land use, land cover, etc. All samples were analyzed by conventional means for the near-total concentration of 49 analytes (Ctotal, Ccarbonate and Corganic, and 46 major and trace elements). Spectra were obtained using dried, ground samples using a Digilab FTS-7000 FT spectrometer in the mid- (4000-400 cm-1) and near-infrared (10,000-4000 cm-1) at 4 cm-1 resolution (64 co-added scans per spectrum) using a Pike AutoDIFF DR autosampler. Partial least squares calibrations were develop using: (1) all samples as a calibration set; (2) samples evenly divided into calibration and validation sets based on spectral diversity; and (3) samples divided to have matching analyte concentrations in calibration and validation sets. In general, results supported the conclusion that neither mid-IR nor NIRS would be particularly useful in reducing the need for conventional

  10. The Survey of hydro-geochemical and health related of water quality in Ramian city, Golestan province

    Directory of Open Access Journals (Sweden)

    fahimeh Khanduzi

    2015-12-01

    Full Text Available Background and Purpose: Investigation of water quality is an important step for the suitable use of water resources in order to drinking and irrigation. Water quality affects agriculture programming.  Hence the need of the study of water quality is strongly considered in the water resources management. Material and Methods: In this study Hydro-geochemical quality of ground water resources in the Ramian city -Golestan province has been studied for drinking and agriculture purpose. For this purpose, 15 qualitative characteristics of the 13 wells of Golestan province in two dry and wet seasons in 2011-2012 were analyzed by Aua Chem and Aq-qa. Results: The results showed that the ground water in the study area is classified in hard and very hard water. The original cations and anions in water are Ca2+> Mg2+> Na+ and HCO3-> Cl-> SO42-. Based on hydro-chemical diagram the dominant of water type is classified as Ca-HCO3. Salinity index of water indicated that more samples in two seasons are in the middle class. According to Schuler and Wilcox groundwater quality index, they are moderate suitable for agricultural and drinking consumption and in for agricultural purpose and 77% cases are in C3-S1 category. Conclusion: The results show that too much salt is one of the most important problems of water supply in the Ramian city for irrigation. This reduced plant growth or even stops the growth of some plant. If water resources in this area do not manage, after shortly time the soil will be suffered and polluted.

  11. Exploring Ancient Skies An Encyclopedic Survey of Archaeoastronomy

    CERN Document Server

    Kelley, David H

    2005-01-01

    Exploring Ancient Skies brings together the methods of archaeology and the insights of modern astronomy to explore the science of astronomy as it was practiced in various cultures prior to the invention of the telescope. The book reviews an enormous and growing body of literature on the cultures of the ancient Mediterranean, the Far East, and the New World (particularly Mesoamerica), putting the ancient astronomical materials into their archaeological and cultural contexts. The authors begin with an overview of the field and proceed to essential aspects of naked-eye astronomy, followed by an examination of specific cultures. The book concludes by taking into account the purposes of ancient astronomy: astrology, navigation, calendar regulation, and (not least) the understanding of our place and role in the universe. Skies are recreated to display critical events as they would have appeared to ancient observers - events such as the supernova of 1054, the 'lion horoscope' or the 'Star of Bethlehem.' Exploring An...

  12. Southern Philippines Public Perception Survey Exploration and Analysis

    Science.gov (United States)

    2013-07-31

    Philippines as part of a widespread Islamic state which would span Indonesia, Malaysia , southern Thailand, Singapore, Brunei, and the southern Philippines...interview exactly half male and half female respondents. A total of 3000 respondents were interviewed during each wave of the survey with an equal number...females were listed on the probability selection tables for even-numbered interviews. In cases where no qualified respondent of the correct gender

  13. Exploring Milkyway Halo Substructures with Large-Area Sky Surveys

    Energy Technology Data Exchange (ETDEWEB)

    Li, Ting [Texas A & M Univ., College Station, TX (United States)

    2016-01-01

    Over the last two decades, our understanding of the Milky Way has been improved thanks to large data sets arising from large-area digital sky surveys. The stellar halo is now known to be inhabited by a variety of spatial and kinematic stellar substructures, including stellar streams and stellar clouds, all of which are predicted by hierarchical Lambda Cold Dark Matter models of galaxy formation. In this dissertation, we first present the analysis of spectroscopic observations of individual stars from the two candidate structures discovered using an M-giant catalog from the Two Micron All-Sky Survey. The follow-up observations show that one of the candidates is a genuine structure which might be associated with the Galactic Anticenter Stellar Structure, while the other one is a false detection due to the systematic photometric errors in the survey or dust extinction in low Galactic latitudes. We then presented the discovery of an excess of main sequence turn-off stars in the direction of the constellations of Eridanus and Phoenix from the first-year data of the Dark Energy Survey (DES) – a five-year, 5,000 deg2 optical imaging survey in the Southern Hemisphere. The Eridanus-Phoenix (EriPhe) overdensity is centered around l ~ 285° and b ~ -60° and the Poisson significance of the detection is at least 9σ. The EriPhe overdensity has a cloud-like morphology and the extent is at least ~ 4 kpc by ~ 3 kpc in projection, with a heliocentric distance of about d ~ 16 kpc. The EriPhe overdensity is morphologically similar to the previously-discovered Virgo overdensity and Hercules-Aquila cloud. These three overdensities lie along a polar plane separated by ~ 120° and may share a common origin. In addition to the scientific discoveries, we also present the work to improve the photometric calibration in DES using auxiliary calibration systems, since the photometric errors can cause false detection in first the halo substructure. We present a detailed description of the two

  14. Field Survey - A Journey of Exploration and Discovery

    Science.gov (United States)

    Jadhav, Kiran

    2017-04-01

    You can teach a student a lesson a day but if you teach him to learn by creating curiosity ,he will continue the learning process for life.This abstract is a manifestation of my innate desire as an educator to build students cognitive level of thinking and refine their processes to gain knowledge from the environment ,process it and put it to optimum use. This field survey has been planned and conducted for students of 12th grade (+16yrs). At this level students are introduced to various aspects of Human geography and how human intervention has harnessed environmental resources for its growth and development. They are also encouraged to observe how humans have adapted to the environment and in this process also modified it to satisfy their needs and demands. Students are also sensitized to the understand how geography has evolved as a scientific subject of enquiry. Hence it calls for a deeper understanding and analysis of issues from the local to the global level. Through the pedagogical approach of field survey, they have been oriented to the process of conducting Research -as a well-defined procedure. It involves three phases 1. Planning and preliminary preparation before the survey, 2. During the field survey 3. After the survey compilation, computation and presentation. This activity has been planned over a period of 3 months and as of now the topic and area of case study have been selected. The general concern was studying low rainfall and agriculturally less productive regions hence a case study of a drought prone village- Hiware Bazaar in Ahmednagar district of Maharashtra was undertaken. The site Hiware Bazar has been selected as it is based on the principles of sustainable development and water shed development programme to combat severe drought. The statement of the problem has been defined along with the outlined objectives ,scope of study and the time frame needed to gather the information. The field visit spanned over 5 days for data collection has

  15. Exploring Ancient Skies A Survey of Ancient and Cultural Astronomy

    CERN Document Server

    Kelley, David H

    2011-01-01

    Exploring Ancient Skies brings together the methods of archaeology and the insights of modern astronomy to explore the science of astronomy as it was practiced in various cultures prior to the invention of the telescope. The book reviews an enormous and growing body of literature on the cultures of the ancient Mediterranean, the Far East, and the New World (particularly Mesoamerica), putting the ancient astronomical materials into their archaeological and cultural contexts. The authors begin with an overview of the field and proceed to essential aspects of naked-eye astronomy, followed by an examination of specific cultures. The book concludes by taking into account the purposes of ancient astronomy: astrology, navigation, calendar regulation, and (not least) the understanding of our place and role in the universe. Skies are recreated to display critical events as they would have appeared to ancient observers—events such as the supernova of 1054 A.D., the "lion horoscope," and the Star of Bethlehem. Explori...

  16. Samples and data accessibility in research biobanks: an explorative survey

    Directory of Open Access Journals (Sweden)

    Marco Capocasa

    2016-02-01

    Full Text Available Biobanks, which contain human biological samples and/or data, provide a crucial contribution to the progress of biomedical research. However, the effective and efficient use of biobank resources depends on their accessibility. In fact, making bio-resources promptly accessible to everybody may increase the benefits for society. Furthermore, optimizing their use and ensuring their quality will promote scientific creativity and, in general, contribute to the progress of bio-medical research. Although this has become a rather common belief, several laboratories are still secretive and continue to withhold samples and data. In this study, we conducted a questionnaire-based survey in order to investigate sample and data accessibility in research biobanks operating all over the world. The survey involved a total of 46 biobanks. Most of them gave permission to access their samples (95.7% and data (85.4%, but free and unconditioned accessibility seemed not to be common practice. The analysis of the guidelines regarding the accessibility to resources of the biobanks that responded to the survey highlights three issues: (i the request for applicants to explain what they would like to do with the resources requested; (ii the role of funding, public or private, in the establishment of fruitful collaborations between biobanks and research labs; (iii the request of co-authorship in order to give access to their data. These results suggest that economic and academic aspects are involved in determining the extent of sample and data sharing stored in biobanks. As a second step of this study, we investigated the reasons behind the high diversity of requirements to access biobank resources. The analysis of informative answers suggested that the different modalities of resource accessibility seem to be largely influenced by both social context and legislation of the countries where the biobanks operate.

  17. Pilot fatigue survey: exploring fatigue factors in air medical operations.

    Science.gov (United States)

    Gregory, Kevin B; Winn, William; Johnson, Kent; Rosekind, Mark R

    2010-01-01

    Humans confront significant physiological challenges with sleep and alertness when working in 24/7 operations. A web-based national survey of air medical pilots examined issues relevant to fatigue and sleep management. Six hundred ninety-seven responses were received, with a majority of rotor wing pilots working 3/3/7 and 7/7 duty schedules. Over 84% of the pilots reported that fatigue had affected their flight performance; less than 28% reported "nodding off" during flight. More than 90% reported a separate work site "rest" room with a bed available. Over 90% reported no company policies restricting on-duty sleep. Approximately half of the pilots reported getting 4 hours or more sleep during a typical night shift. Approximately half reported that sleep inertia had never compromised flight safety. Over 90% reported that it was better to sleep during the night and overcome sleep inertia if necessary. Survey results reflected practices that can mitigate the degrading effects of fatigue, including the availability of designated work-site sleep rooms. As demands continue to evolve, the need remains for sustained efforts to address fatigue-related risks in the air medical transport industry. This includes further study of sleep inertia issues and the need for alertness management programs. Copyright © 2010 Air Medical Journal Associates. Published by Elsevier Inc. All rights reserved.

  18. Exploring with PAM: Prospecting ANTS Missions for Solar System Surveys

    Science.gov (United States)

    Clark, P. E.; Rilee, M. L.; Curtis, S. A.

    2003-01-01

    ANTS (Autonomous Nano-Technology Swarm), a large (1000 member) swarm of nano to picoclass (10 to 1 kg) totally autonomous spacecraft, are being developed as a NASA advanced mission concept. ANTS, based on a hierarchical insect social order, use an evolvable, self-similar, hierarchical neural system in which individual spacecraft represent the highest level nodes. ANTS uses swarm intelligence attained through collective, cooperative interactions of the nodes at all levels of the system. At the highest levels this can take the form of cooperative, collective behavior among the individual spacecraft in a very large constellation. The ANTS neural architecture is designed for totally autonomous operation of complex systems including spacecraft constellations. The ANTS (Autonomous Nano Technology Swarm) concept has a number of possible applications. A version of ANTS designed for surveying and determining the resource potential of the asteroid belt, called PAM (Prospecting ANTS Mission), is examined here.

  19. Geochemical orientation survey of stream sediment, stream water, and ground water near uranium prospects, Monticello area, New York. National Uranium Resource Evaluation Program

    Energy Technology Data Exchange (ETDEWEB)

    Rose, A. W.; Smith, A. T.; Wesolowski, D.

    1982-08-01

    A detailed geochemical test survey has been conducted in a 570 sq km area around six small copper-uranium prospects in sandstones of the Devonian Catskill Formation near Monticello in southern New York state. This report summarizes and interprets the data for about 500 stream sediment samples, 500 stream water samples, and 500 ground water samples, each analyzed for 40 to 50 elements. The groundwater samples furnish distinctive anomalies for uranium, helium, radon, and copper near the mineralized localities, but the samples must be segregated into aquifers in order to obtain continuous well-defined anomalies. Two zones of uranium-rich water (1 to 16 parts per billion) can be recognized on cross sections; the upper zone extends through the known occurrences. The anomalies in uranium and helium are strongest in the deeper parts of the aquifers and are diluted in samples from shallow wells. In stream water, copper and uranium are slightly anomalous, as in an ore factor derived from factor analysis. Ratios of copper, uranium, and zinc to conductivity improve the resolution of anomalies. In stream sediment, extractable uranium, copper, niobium, vanadium, and an ore factor furnish weak anomalies, and ratios of uranium and copper to zinc improve the definition of anomalies. The uranium/thorium ratio is not helpful. Published analyses of rock samples from the nearby stratigraphic section show distinct anomalies in the zone containing the copper-uranium occurrences. This report is being issued without the normal detailed technical and copy editing, to make the data available to the public before the end of the National Uranium Reconnaissance Evaluation program.

  20. 3D Spectroscopic Surveys: Exploring Galaxy Evolution Mechanisms

    Science.gov (United States)

    Epinat, Benoît

    2011-12-01

    I review the major surveys of high redshift galaxies observed using integral field spectroscopy techniques in the visible and in the infrared. The comparison of various samples has to be done with care since they have different properties linked to their parent samples, their selection criteria and the methods used to study them. I present the various kinematic types of galaxies that are identified within these samples (rotators, mergers, etc.) and summarize the discussions on the mass assembly processes at various redshifts deduced from these classifications: at intermediate redshift (z ~ 0.6) merger may be the main mass assembly process whereas the role of cold gas accretion along cosmic web filaments may increase with redshift. The baryonic Tully-Fisher relation is also discussed. This relation seems to be already in place 3 Gyr after the Big-Bang and is then evolving until the present day. This evolution is interpreted as an increase of the stellar mass content of dark matter haloes of a given mass. The discovery of positive abundance gradients in MASSIV and LSD/AMAZE samples is highlighted. At z ~ 3 this discovery might be linked to cold gas accretion along cosmic filaments toward the centre whereas at lower redshift (z ~ 1.3), this may be mainly due to accretion of gas from outer reservoirs toward the centre via tidal tails due to interactions.

  1. What is a microbiologist? A survey exploring the microbiology workforce.

    Science.gov (United States)

    Redfern, James; Verran, Joanna

    2015-12-01

    Microbiology has a long tradition of making inspirational, world-changing discovery. Microbiology now plays essential roles in many disciplines, leading to some microbiologists raising concern over the apparent loss of identity. An electronic survey was undertaken to capture the scientific identity (based on scientific discipline) of people for whom microbiology forms a part of their profession, in addition to information regarding their first degree (title, country and year in which the degree was completed) and the sector in which they currently work. A total of 447 responses were collected, representing 52 countries from which they gained their first degree. Biology was the most common first degree title (of 32 titles provided), while microbiologist was the most common scientific identity (of 26 identities provided). The data collected in this study gives a snapshot of the multidisciplinarity, specialism and evolving nature of the microbiology academic workforce. While the most common scientific identity chosen in this study was that of a microbiologist, it appears that the microbiological workforce is contributed to by a range of different disciplines, highlighting the cross-cutting, multidisciplined and essential role microbiology has within scientific endeavour. Perhaps, we should be less concerned with labels, and celebrate the success with which our discipline has delivered. © FEMS 2015. All rights reserved. For permissions, please e-mail: journals.permissions@oup.com.

  2. 75 FR 16830 - Geological and Geophysical Exploration (G&G) on the Mid- and South Atlantic Outer Continental...

    Science.gov (United States)

    2010-04-02

    ... Minerals Management Service Geological and Geophysical Exploration (G&G) on the Mid- and South Atlantic... surveys, sidescan-sonar surveys, electromagnetic surveys, geological and geochemical sampling, and remote...-LeasingDocument.pdf ) and MMS's Geological and Geophysical Exploration for Mineral Resources on the Gulf...

  3. Role of geochemical background at evaluation of investment attractiveness of recreational territories

    Directory of Open Access Journals (Sweden)

    Vdovina Ol'ga Konstantinovna

    2014-09-01

    Full Text Available The article shows the role of natural geochemical background when estimating investment attractiveness of recreational areas. It is noted, that geochemical background influence on people's sickness rate isn't considered now. Though it's understood, that even insignificant increase of geochemical background in relation to percentage abundance of Earth crest may lead to endemic diseases of people, animals and plants. An indicator of geochemical endemicity areas was proposed for assessing the impact of storage elements and of a lack of geological environment on human health. Thanks to this measure, and taking into account landscape features of the area, the authors allocated lands, dangerous and potentially dangerous in terms of endemicity. The importance of ratings was achieved by the use of those factors that could have a great influence on the cost of land development. This includes, first of all, the factors that affect population health, and economic and geographic factors that minimize the cost of the territory development and the factors that give rise to financial risks and risks of human losses. The main risk factors include: potential ecological and geochemical risk; high absolute heights, development and activity of dangerous geological processes and phenomena. Systemacity of researches was reached by using factors, that characterize the object from different aspects; readiness of area infrastructure to its exploration and possible risks. Objectivity was achieved by the use of figures obtained from the results of geochemical and engineering surveys with their metrological support.

  4. Exploring the Variable Sky with the Sloan Digital Sky Survey

    Energy Technology Data Exchange (ETDEWEB)

    Sesar, Branimir; Ivezic, Zeljko; Lupton, Robert; Juric, Mario; Gunn, James; Knapp, Gillian; De Lee, Nathan; Smith, J. Allyn; Miknaitis,Gajus; Lin, Huan; Tucker, Douglas; Doi, Mamoru; Tanaka, Masayuki; Fukugita, Masataka; Holtzman, Jon; Kent, Steve; Yanny, Brian; Schlegel,David; Finkbeiner, Douglas; Padmanabhan, Nikhil; Rockosi, Constance; Bond, Nicholas; Lee, Brian; Stoughton, Chris; Jester, Sebastian; Harris,Hugh; Harding, Paul; Brinkmann, Jon; Schneider, Donald; York, Donald; Richmond, Michael; Vanden Berk, Daniel

    2007-04-01

    We quantify the variability of faint unresolved optical sources using a catalog based on multiple SDSS imaging observations. The catalog covers SDSS Stripe 82, which lies along the celestial equator in the Southern Galactic Hemisphere (22h 24m < {alpha}{sub J2000} < 04h 08m, -1.27{sup o} < {delta}{sub J2000} < +1.27{sup o}, {approx} 290 deg{sup 2}), and contains 58 million photometric observations in the SDSS ugriz system for 1.4 million unresolved sources that were observed at least 4 times in each of the gri bands (with a median of 10 observations obtained over {approx}5 years). In each photometric bandpass we compute various low-order lightcurve statistics such as root-mean-square scatter (rms), {chi}{sup 2} per degree of freedom, skewness, minimum and maximum magnitude, and use them to select and study variable sources. We find that 2% of unresolved optical sources brighter than g = 20.5 appear variable at the 0.05 mag level (rms) simultaneously in the g and r bands. The majority (2/3) of these variable sources are low-redshift (< 2) quasars, although they represent only 2% of all sources in the adopted flux-limited sample. We find that at least 90% of quasars are variable at the 0.03 mag level (rms) and confirm that variability is as good a method for finding low-redshift quasars as is the UV excess color selection (at high Galactic latitudes). We analyze the distribution of lightcurve skewness for quasars and find that is centered on zero. We find that about 1/4 of the variable stars are RR Lyrae stars, and that only 0.5% of stars from the main stellar locus are variable at the 0.05 mag level. The distribution of lightcurve skewness in the g-r vs. u-g color-color diagram on the main stellar locus is found to be bimodal (with one mode consistent with Algol-like behavior). Using over six hundred RR Lyrae stars, we demonstrate rich halo substructure out to distances of 100 kpc. We extrapolate these results to expected performance by the Large Synoptic Survey

  5. Exploring the Variable Sky with the Sloan Digital Sky Survey

    Energy Technology Data Exchange (ETDEWEB)

    Sesar, Branimir; Ivezic, Zeljko; Lupton, Robert H.; Juric, Mario; Gunn, James E.; Knapp, Gillian R.; Lee, Nathan De; Smith, J.Allyn; Miknaitis, Gajus; Lin, Huan; Tucker,

    2007-04-01

    We quantify the variability of faint unresolved optical sources using a catalog based on multiple SDSS imaging observations. The catalog covers SDSS Stripe 82, which lies along the celestial equator in the Southern Galactic Hemisphere (22h 24m < {alpha}{sub J2000} < 04h 08m, -1.27 < {delta}{sub J2000} < +1.27, {approx}290 deg{sup 2} ), and contains 58 million photometric observations in the SDSS ugriz system for 1.4 million unresolved sources that were observed at least 4 times in each of the gri bands (with a median of 10 observations obtained over {approx}5 years). In each photometric bandpass we compute various low-order lightcurve statistics such as root-mean-square scatter (rms), {chi}{sup 2} 2 per degree of freedom, skewness, minimum and maximum magnitude, and use them to select and study variable sources. We find that 2% of unresolved optical sources brighter than g = 20.5 appear variable at the 0.05 mag level (rms) simultaneously in the g and r bands. The majority (2/3) of these variable sources are low-redshift (< 2) quasars, although they represent only 2% of all sources in the adopted ux-limited sample. We find that at least 90% of quasars are variable at the 0.03 mag level (rms) and confirm that variability is as good a method for finding low-redshift quasars as is the UV excess color selection (at high Galactic latitudes). We analyze the distribution of lightcurve skewness for quasars and find that is centered on zero. We find that about 1/4 of the variable stars are RR Lyrae stars, and that only 0.5% of stars from the main stellar locus are variable at the 0.05 mag level. The distribution of lightcurve skewness in the g-r vs. u-g color-color diagram on the main stellar locus is found to be bimodal (with one mode consistent with Algol-like behavior). Using over six hundred RR Lyrae stars, we demonstrate rich halo substructure out to distances of 100 kpc. We extrapolate these results to expected performance by the Large Synoptic Survey Telescope and

  6. Alaska Geochemical Database Version 2.0 (AGDB2) - Including "Best Value" Data Compilations for Geochemical Data for Rock, Sediment, Soil, Mineral, and Concentrate Sample Media

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The Alaska Geochemical Database Version 2.0 (AGDB2) contains new geochemical data compilations in which each geologic material sample has one "best value"...

  7. Geochemical monitoring of the Tenerife North-East Rift Zone (NERZ) volcano (Canary Islands) by means of diffuse CO_{2} degassing surveys

    Science.gov (United States)

    Barrancos, José; O'Neill, Ryan; Gould, Catherine E.; Padilla, Germán; Rodríguez, Fátima; Amonte, Cecilia; Padrón, Eleazar; Pérez, Nemesio M.

    2017-04-01

    Tenerife is the largest of the Canary Islands (2100 km2) and the North East Rift (NERZ) volcano is one of the three active volcanic rift-zones of the island (210 km2). The last eruptive activity at NERZ volcano occurred in 1704 and 1705, with three volcanic eruptions: Siete Fuentes, Fasnia and Arafo. In order to provide a multidisciplinary approach to monitor potential volcanic activity changes at the NERZ volcano, diffuse CO2 emission surveys have been undertaken in a yearly basis since 2001. This study shows the results of the last soil CO2 efflux survey undertaken in summer 2016, with 600 soil gas sampling sites homogenously distributed. Soil CO2 efflux measurements were performed at the surface environment by means of a portable non-dispersive infrared spectrophotometer (NDIR) LICOR Li800 following the accumulation chamber method. Soil CO2 efflux values ranged from non-detectable (˜0.5 g m-2 d-1) up to 70 g m-2 d-1, with an average value of 8.8 g m-2 d-1. In order to distinguish the existence of different geochemical populations on the soil CO2 efflux data, a Sinclair graphical analysis was done. The average value of background population was 2.9 g m-2 d-1 and that of peak population was 67.8 g m-2 d-1, value that has been increasing since the year 2014. To quantify the total CO2 emission rate from the NERZ volcano a sequential Gaussian simulation (sGs) was used as interpolation method to construct soil CO2 emission contour maps. The diffuse CO2 emission rate for the studied area was estimated in 1,675 ± 47 t d-1. If we compare the 2016 results with those ones obtained in previous surveys since 2001, two main pulses on diffuse CO2 emission are identified, the first one in 2007 and the second one between during 2014 and 2016. This long-term variation on the diffuse CO2 emission doesn't seem to be masked by the external-meteorological variations. However, the first peak precedes the anomalous seismicity recorded in and around Tenerife Island between 2009 and

  8. Geochemical signature of columbite-tantalite and radiometric survey of radioactive pegmatites in the region of Parelhas, Rio Grande do Norte, Brazil; Assinatura geoquimica de columbita-tantalita e levantamento radiometrico de pegmatitos radioativos da regiao de Parelhas, RN, Brasil

    Energy Technology Data Exchange (ETDEWEB)

    Moura, Jorge Costa de

    2013-07-01

    This thesis is the result of geochemical, structural and radiometric investigations on radioactive pegmatites of the Borborema Pegmatitic Province in Northeast Brazil. The studied area, located in the surroundings of the city of Parelhas in the region of the Serra da Borborema, is well known for its thousands of pegmatitic bodies exploited in primitive mines called 'garimpos'. The main goal was to find an efficient, cheap and routine inspection procedure to identify the origin of commercialized radioactive columbite-tantalite (coltan) ore. The Brazilian Nuclear Energy Agency (CNEN) controls uranium commerce and nuclear activity in Brazil. Without an effective method to characterize coltan ores from different localities it is impossible to control the trade. The here presented new method was developed by correlating structural features of these pegmatites with the geochemical behavior of their coltan samples. It was found that the variation of the ratio U/Th versus Nb{sub 2}O{sub 5}/Ta{sub 2}O{sub 5} provides geochemical signatures (analytical fingerprints) for the source location of such ore. A test of the new method with coltan samples of commercial batches from the Brazilian states Amapa and Rondonia also generated distinct geochemical signatures. A radiometric survey (CPS) was carried out in several mines and pegmatites to study the environmental impact of gamma radiation. It included in situ measurements of pegmatite walls, host rocks, soil, and accumulated water and revealed that gamma emitters are hardly solubilized and environmental gamma radiation therefore generally is not enhanced to a dangerous level. (author)

  9. Geochemistry of rock samples from the National Geochemical Database

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set contains geochemical data for rock samples collected by U.S. Geological Survey (USGS) personnel and analyzed either in the analytical laboratories of...

  10. SYNERGY: an Explorer mission concept for a next-generation ultraviolet survey

    Science.gov (United States)

    MacKenty, John W.; Tumlinson, Jason; Arenberg, Jonathan W.; Elder, Craig; Gunderson, Adam; Warwick, Steven; O'Connell, Terri; Wong, Carlton

    2017-09-01

    Synergy is an Explorer class mission concept to obtain a large-area, multi-tier near-ultraviolet sky survey with lowresolution, spatially resolved slitless spectroscopy (R = 200-600) and simultaneous arc-second imaging between 210-320 nm. It's Wide and Deep surveys will examine the co-evolution of more than 200 million galaxies, 500,000 AGN, and 30,000 gas halos between 0.8 z z = 2 require ultraviolet observations.

  11. Reconnaissance Geochemical Study

    African Journals Online (AJOL)

    as means, standard deviation, etc. that allow the calculation of thresholds for individual elements. Geochemical distribution and anomalous-concentration maps were plotted for the elements, so as to have an insight into their distribution patterns. The geochemical distribution maps of the elements reveal that Cu, Pb, Zn, Co, ...

  12. Constraints on interpretation of geochemical data for gold exploration in multiply deformed and metamorphosed areas: an example from Legadembi gold deposit, southern Ethiopia

    Science.gov (United States)

    Tolessa, Dandena; Pohl, Walter

    1999-08-01

    The Legadembi Au deposit, situated in southern Ethiopia, is hosted in sheared metamorphic rocks of Pan-African age. The ore minerals and country rocks were subjected to multiple phases of deformation, metamorphism and mineralisation. Correlation studies and factor analysis are applied to test whether geostatistical studies can identify factors responsible for element relationships and pathfinder elements for Au. The results are compared with mineral paragenetic studies to decipher the temporal relationships between minerals and to further constrain possible pathfinder elements for Au. Spearman correlation coefficients identify NiCuPbAu, AgAuPb, BaZnTiPb and CdZnYbTiVSrScNiCuCrY correlations at 95 and 99% confidence levels. A four-factor model explains 99% of the data variability. Factor 1 (BaCdScSrTiVYr) is a lithological factor. Factor 2 (AuCuZnPbCdNiCo) is an overlap of mineralisation factor. Factor 3 (CrNiPbAgSrV) and Factor 4 (CdCrCuVYb) are due to the overlap of lithological and mineralisation factors. Even though the data are not normally distributed, geostatistical data processing using factor analysis gives geologically meaningful results. Mineral paragenetic studies show two main phases of mineralisation. The early phase is represented by chalcopyrite, pyrite, pyrrhotite and sphalerite. The later phase includes Au, galena and electrum. Based on geochemical factors and mineral paragenetic studies, Ag and Pb are potential pathfinder elements for Au for Legadembi-type Au deposits. The correlation of other elements with Au is due to the spatial overlap of mineralisation events with different metal associations.

  13. A geochemical atlas of North Carolina, USA

    Science.gov (United States)

    Reid, J.C.

    1993-01-01

    A geochemical atlas of North Carolina, U.S.A., was prepared using National Uranium Resource Evaluation (NURE) stream-sediment data. Before termination of the NURE program, sampling of nearly the entire state (48,666 square miles of land area) was completed and geochemical analyses were obtained. The NURE data are applicable to mineral exploration, agriculture, waste disposal siting issues, health, and environmental studies. Applications in state government include resource surveys to assist mineral exploration by identifying geochemical anomalies and areas of mineralization. Agriculture seeks to identify areas with favorable (or unfavorable) conditions for plant growth, disease, and crop productivity. Trace elements such as cobalt, copper, chromium, iron, manganese, zinc, and molybdenum must be present within narrow ranges in soils for optimum growth and productivity. Trace elements as a contributing factor to disease are of concern to health professionals. Industry can use pH and conductivity data for water samples to site facilities which require specific water quality. The North Carolina NURE database consists of stream-sediment samples, groundwater samples, and stream-water analyses. The statewide database consists of 6,744 stream-sediment sites, 5,778 groundwater sample sites, and 295 stream-water sites. Neutron activation analyses were provided for U, Br, Cl, F, Mn, Na, Al, V, Dy in groundwater and stream water, and for U, Th, Hf, Ce, Fe, Mn, Na, Sc, Ti, V, Al, Dy, Eu, La, Sm, Yb, and Lu in stream sediments. Supplemental analyses by other techniques were reported on U (extractable), Ag, As, Ba, Be, Ca, Co, Cr, Cu, K, Li, Mg, Mo, Nb, Ni, P, Pb, Se, Sn, Sr, W, Y, and Zn for 4,619 stream-sediment samples. A small subset of 334 stream samples was analyzed for gold. The goal of the atlas was to make available the statewide NURE data with minimal interpretation to enable prospective users to modify and manipulate the data for their end use. The atlas provides only

  14. Microbial iron cycling in acidic geothermal springs of yellowstone national park: integrating molecular surveys, geochemical processes, and isolation of novel fe-active microorganisms.

    Science.gov (United States)

    Kozubal, Mark A; Macur, Richard E; Jay, Zackary J; Beam, Jacob P; Malfatti, Stephanie A; Tringe, Susannah G; Kocar, Benjamin D; Borch, Thomas; Inskeep, William P

    2012-01-01

    Geochemical, molecular, and physiological analyses of microbial isolates were combined to study the geomicrobiology of acidic iron oxide mats in Yellowstone National Park. Nineteen sampling locations from 11 geothermal springs were studied ranging in temperature from 53 to 88°C and pH 2.4 to 3.6. All iron oxide mats exhibited high diversity of crenarchaeal sequences from the Sulfolobales, Thermoproteales, and Desulfurococcales. The predominant Sulfolobales sequences were highly similar to Metallosphaera yellowstonensis str. MK1, previously isolated from one of these sites. Other groups of archaea were consistently associated with different types of iron oxide mats, including undescribed members of the phyla Thaumarchaeota and Euryarchaeota. Bacterial sequences were dominated by relatives of Hydrogenobaculum spp. above 65-70°C, but increased in diversity below 60°C. Cultivation of relevant iron-oxidizing and iron-reducing microbial isolates included Sulfolobus str. MK3, Sulfobacillus str. MK2, Acidicaldus str. MK6, and a new candidate genus in the Sulfolobales referred to as Sulfolobales str. MK5. Strains MK3 and MK5 are capable of oxidizing ferrous iron autotrophically, while strain MK2 oxidizes iron mixotrophically. Similar rates of iron oxidation were measured for M. yellowstonensis str. MK1 and Sulfolobales str. MK5. Biomineralized phases of ferric iron varied among cultures and field sites, and included ferric oxyhydroxides, K-jarosite, goethite, hematite, and scorodite depending on geochemical conditions. Strains MK5 and MK6 are capable of reducing ferric iron under anaerobic conditions with complex carbon sources. The combination of geochemical and molecular data as well as physiological observations of isolates suggests that the community structure of acidic Fe mats is linked with Fe cycling across temperatures ranging from 53 to 88°C.

  15. Microbial iron cycling in acidic geothermal springs of Yellowstone National Park: Integrating molecular surveys, geochemical processes and isolation of novel Fe-active microorganisms

    Directory of Open Access Journals (Sweden)

    Mark A Kozubal

    2012-03-01

    Full Text Available Geochemical, molecular, and physiological analyses of microbial isolates were combined to study the geomicrobiology of acidic iron oxide mats in Yellowstone National Park (YNP. Nineteen sampling locations from 11 geothermal springs were studied ranging in temperature from 53 to 84 °C and pH 2.4 to 3.6. All iron-oxide mats exhibited high diversity of crenarchaeal sequences from the Sulfolobales, Thermoproteales, and Desulfurococcales. The predominant Sulfolobales sequences were highly similar to Metallosphaera yellowstonensis str. MK1, previously isolated from one of these sites. Other groups of archaea were consistently associated with different types of iron oxide mats, including undescribed members of the phyla Thaumarchaeota and Euryarchaeota. Bacterial sequences were dominated by relatives of Hydrogenobaculum spp. above 65-70 °C, but increased in diversity below 60 °C. Cultivation of relevant iron-oxidizing and iron-reducing microbial isolates included Sulfolobus str. MK3, Sulfobacillus str. MK2, Acidicaldus str. MK6, and a new candidate genus in the Sulfolobales referred to as Sulfolobales str. MK5. Strains MK3 and MK5 are capable of oxidizing ferrous iron autotrophically, while strain MK2 oxidizes iron mixotrophically. Similar rates of iron oxidation were observed for M. yellowstonensis str. MK1 and Sulfolobales str. MK5 cultures, and these rates are close to those measured in situ. Biomineralized phases of ferric iron varied among cultures and field sites, and included ferric oxyhydroxides, K-jarosite, goethite, hematite, and scorodite depending on geochemical conditions. Strains MK5 and MK6 are capable of reducing ferric iron under anaerobic conditions with complex carbon sources. The combination of geochemical and molecular data as well as physiological observations of isolates suggests that the community structure of acidic Fe mats is linked with Fe cycling across temperatures ranging from 53 to 88 oC.

  16. Microbial Iron Cycling in Acidic Geothermal Springs of Yellowstone National Park: Integrating Molecular Surveys, Geochemical Processes, and Isolation of Novel Fe-Active Microorganisms

    Science.gov (United States)

    Kozubal, Mark A.; Macur, Richard E.; Jay, Zackary J.; Beam, Jacob P.; Malfatti, Stephanie A.; Tringe, Susannah G.; Kocar, Benjamin D.; Borch, Thomas; Inskeep, William P.

    2012-01-01

    Geochemical, molecular, and physiological analyses of microbial isolates were combined to study the geomicrobiology of acidic iron oxide mats in Yellowstone National Park. Nineteen sampling locations from 11 geothermal springs were studied ranging in temperature from 53 to 88°C and pH 2.4 to 3.6. All iron oxide mats exhibited high diversity of crenarchaeal sequences from the Sulfolobales, Thermoproteales, and Desulfurococcales. The predominant Sulfolobales sequences were highly similar to Metallosphaera yellowstonensis str. MK1, previously isolated from one of these sites. Other groups of archaea were consistently associated with different types of iron oxide mats, including undescribed members of the phyla Thaumarchaeota and Euryarchaeota. Bacterial sequences were dominated by relatives of Hydrogenobaculum spp. above 65–70°C, but increased in diversity below 60°C. Cultivation of relevant iron-oxidizing and iron-reducing microbial isolates included Sulfolobus str. MK3, Sulfobacillus str. MK2, Acidicaldus str. MK6, and a new candidate genus in the Sulfolobales referred to as Sulfolobales str. MK5. Strains MK3 and MK5 are capable of oxidizing ferrous iron autotrophically, while strain MK2 oxidizes iron mixotrophically. Similar rates of iron oxidation were measured for M. yellowstonensis str. MK1 and Sulfolobales str. MK5. Biomineralized phases of ferric iron varied among cultures and field sites, and included ferric oxyhydroxides, K-jarosite, goethite, hematite, and scorodite depending on geochemical conditions. Strains MK5 and MK6 are capable of reducing ferric iron under anaerobic conditions with complex carbon sources. The combination of geochemical and molecular data as well as physiological observations of isolates suggests that the community structure of acidic Fe mats is linked with Fe cycling across temperatures ranging from 53 to 88°C. PMID:22470372

  17. Autonomous Marine Seismic Survey Systems for Seafloor Massive Sulfide (SMS) Exploration

    Science.gov (United States)

    Asakawa, E.; Murakami, F.; Tsukahara, H.; Lee, S.; Saito, S.; Tara, K.; Sumi, T.; Kadoshima, K.; Kose, M.

    2016-12-01

    The Cabinet Office, Government Japan started the Cross-ministerial Strategic Innovation Promotion Program (SIP) in 2014. "Next-generation Ocean Resource Exploration Techniques" is scheduled under SIP from 2014 to 2018. J-MARES participates this program and aims "Multi-stage and integrated approach for Seafloor Massive Sulfide(SMS) exploration" through the development of highly efficient and cost-effective geophysical exploration methods mainly on seismic and EM methods. J-MARES proposed Vertical Cable Seismic (VCS) technique as seismic survey. It is one of reflection seismic methods that uses hydrophone arrays vertically moored from the seafloor. It is useful to delineate detailed structures in a spatially-limited area efficiently. JGI, a member of J-MARES, has developed autonomous VCS systems and carried out several VCS surveys in hydrothermal fields and the detailed subsurface structure is revealed up to 100m. VCS surveys have provides high resolution results but it covers a small survey area with a limited number of vertical cables. To expand the survey area, we operate ROV for re-deployments of the VCS. Another approach is to develop a deep-towed seismic system based on the VCS technology. We re-deployed the vertical cables using ROV. The ROV moved to the location of vertical cable using SSBL navigation and the video information. After arriving the location of vertical cable, the ROV grabbed the anchor and moved it to next target point. We carried out 3 time re-deployment VCS survey with four vertical cables in Iheya North Knoll, Okinawa Trough. The combined seismic sections of the 3 patches are consistent without any gap of each section. Following this, we modified the VCS system to use as a more efficient deep-tow seismic survey system. Although there are other deep-tow seismic systems, signal cables present challenges in deep waters. We use VCS technology in order to avoid these problems. The basic idea is autonomous recording system and we call it ACS

  18. Radon, helium and uranium survey in some thermal springs located in NW Himalayas, India: mobilization by tectonic features or by geochemical barriers?

    Science.gov (United States)

    Walia, V; Quattrocchi, F; Virk, H S; Yang, T F; Pizzino, L; Bajwa, B S

    2005-09-01

    Radon, helium and uranium measurements have been carried out in hot water springs in the Parbati and Beas valleys of Himachal Himalaya. Most of these hot springs are known as famous pilgrimage centers. The activity of dissolved radon in the liquid phase is found to vary widely, by an order of magnitude, between 10 and 750 Bq L(-1), whereas, the dissolved helium content in these thermal springs varies between 10 and 100 ppm. The uranium contents are low and vary from geochemical barriers cause the mobilization of uranile ions in solution (UO2+); the most plausible hypothesis is when the conditions are oxidising, confirming the importance of physico-chemical conditions up to the supergenic environment, to control the fluid geochemistry of the U-He-222Rn system. Some evidence is available from both geothermometric considerations and geochemical data which will be reported elsewhere, whereas the present study is focused on U decay series-noble gas geochemistry. The first analysis of collected 3He/4He data is consistent with a crustal signature at the studied thermal springs.

  19. Application effectiveness of the microtremor survey method in the exploration of geothermal resources

    Science.gov (United States)

    Tian, Baoqing; Xu, Peifen; Ling, Suqun; Du, Jianguo; Xu, Xueqiu; Pang, Zhonghe

    2017-10-01

    Geophysical techniques are critical tools of geothermal resource surveys. In recent years, the microtremor survey method, which has two branch techniques (the microtremor sounding technique and the two-dimensional (2D) microtremor profiling technique), has become a common method for geothermal resource exploration. The results of microtremor surveys provide important deep information for probing structures of geothermal storing basins and researching the heat-controlling structures, as well as providing the basis for drilling positions of geothermal wells. In this paper, the southern Jiangsu geothermal resources area is taken as a study example. By comparing the results of microtremor surveys and drilling conclusions, and analyzing microtremor survey effectiveness, and geological and technical factors such as observation radius and sampling frequency, we study the applicability of the microtremor survey method and the optimal way of working with this method to achieve better detection results. A comparative study of survey results and geothermal drilling results shows that the microtremor sounding technique effectively distinguishes sub-layers and determines the depth of geothermal reservoirs in the area with excellent layer conditions. The error of depth is generally no more than 8% compared with the results of drilling. It detects deeper by adjusting the size of the probing radius. The 2D microtremor profiling technique probes exactly the buried structures which display as low velocity anomalies in the apparent velocity profile of the S-wave. The anomaly is the critical symbol of the 2D microtremor profiling technique to distinguish and explain the buried geothermal structures. 2D microtremor profiling results provide an important basis for locating exactly the geothermal well and reducing the risk of drilling dry wells.

  20. 77 FR 19321 - Geological and Geophysical Exploration on the Atlantic Outer Continental Shelf (OCS)

    Science.gov (United States)

    2012-03-30

    ... Bureau of Ocean Energy Management Geological and Geophysical Exploration on the Atlantic Outer... environmental effects of multiple Geological and Geophysical (G&G) activities in the Mid- and South Atlantic...-sonar surveys, electromagnetic surveys, geological and geochemical sampling, and remote sensing. The...

  1. Exploration

    Science.gov (United States)

    Wilburn, D.R.

    2001-01-01

    Part of an annual review of mines and mineral resources in the U.S. An overview of nonfuel-mineral exploration in 2000 is presented. Principal exploration target was gold exploration in Latin America, Australia, and the U.S. There was a decrease of 18 percent in the exploration budget for gold as compared with the budget for 1999. Statistical information on nonfuel-mineral exploration worldwide is presented, analyzed, and interpreted.

  2. The ESO Diffuse Interstellar Bands Large Exploration Survey: EDIBLES I. Project description, survey sample and quality assessment.

    Science.gov (United States)

    Cox, Nick L J; Cami, Jan; Farhang, Amin; Smoker, Jonathan; Monreal-Ibero, Ana; Lallement, Rosine; Sarre, Peter J; Marshall, Charlotte C M; Smith, Keith T; Evans, Christopher J; Royer, Pierre; Linnartz, Harold; Cordiner, Martin A; Joblin, Christine; van Loon, Jacco Th; Foing, Bernard H; Bhatt, Neil H; Bron, Emeric; Elyajouri, Meriem; de Koter, Alex; Ehrenfreund, Pascale; Javadi, Atefeh; Kaper, Lex; Khosroshadi, Habib G; Laverick, Mike; Le Petit, Franck; Mulas, Giacomo; Roueff, Evelyne; Salama, Farid; Spaans, Marco

    2017-10-01

    The carriers of the diffuse interstellar bands (DIBs) are largely unidentified molecules ubiquitously present in the interstellar medium (ISM). After decades of study, two strong and possibly three weak near-infrared DIBs have recently been attributed to the [Formula: see text] fullerene based on observational and laboratory measurements. There is great promise for the identification of the over 400 other known DIBs, as this result could provide chemical hints towards other possible carriers. In an effort to systematically study the properties of the DIB carriers, we have initiated a new large-scale observational survey: the ESO Diffuse Interstellar Bands Large Exploration Survey (EDIBLES). The main objective is to build on and extend existing DIB surveys to make a major step forward in characterising the physical and chemical conditions for a statistically significant sample of interstellar lines-of-sight, with the goal to reverse-engineer key molecular properties of the DIB carriers. EDIBLES is a filler Large Programme using the Ultraviolet and Visual Echelle Spectrograph at the Very Large Telescope at Paranal, Chile. It is designed to provide an observationally unbiased view of the presence and behaviour of the DIBs towards early-spectral type stars whose lines-of-sight probe the diffuse-to-translucent ISM. Such a complete dataset will provide a deep census of the atomic and molecular content, physical conditions, chemical abundances and elemental depletion levels for each sightline. Achieving these goals requires a homogeneous set of high-quality data in terms of resolution (R ~ 70 000 - 100 000), sensitivity (S/N up to 1000 per resolution element), and spectral coverage (305-1042 nm), as well as a large sample size (100+ sightlines). In this first paper the goals, objectives and methodology of the EDIBLES programme are described and an initial assessment of the data is provided.

  3. The ESO Diffuse Interstellar Bands Large Exploration Survey (EDIBLES) . I. Project description, survey sample, and quality assessment

    Science.gov (United States)

    Cox, Nick L. J.; Cami, Jan; Farhang, Amin; Smoker, Jonathan; Monreal-Ibero, Ana; Lallement, Rosine; Sarre, Peter J.; Marshall, Charlotte C. M.; Smith, Keith T.; Evans, Christopher J.; Royer, Pierre; Linnartz, Harold; Cordiner, Martin A.; Joblin, Christine; van Loon, Jacco Th.; Foing, Bernard H.; Bhatt, Neil H.; Bron, Emeric; Elyajouri, Meriem; de Koter, Alex; Ehrenfreund, Pascale; Javadi, Atefeh; Kaper, Lex; Khosroshadi, Habib G.; Laverick, Mike; Le Petit, Franck; Mulas, Giacomo; Roueff, Evelyne; Salama, Farid; Spaans, Marco

    2017-10-01

    The carriers of the diffuse interstellar bands (DIBs) are largely unidentified molecules ubiquitously present in the interstellar medium (ISM). After decades of study, two strong and possibly three weak near-infrared DIBs have recently been attributed to the C60^+ fullerene based on observational and laboratory measurements. There is great promise for the identification of the over 400 other known DIBs, as this result could provide chemical hints towards other possible carriers. In an effort tosystematically study the properties of the DIB carriers, we have initiated a new large-scale observational survey: the ESO Diffuse Interstellar Bands Large Exploration Survey (EDIBLES). The main objective is to build on and extend existing DIB surveys to make a major step forward in characterising the physical and chemical conditions for a statistically significant sample of interstellar lines-of-sight, with the goal to reverse-engineer key molecular properties of the DIB carriers. EDIBLES is a filler Large Programme using the Ultraviolet and Visual Echelle Spectrograph at the Very Large Telescope at Paranal, Chile. It is designed to provide an observationally unbiased view of the presence and behaviour of the DIBs towards early-spectral-type stars whose lines-of-sight probe the diffuse-to-translucent ISM. Such a complete dataset will provide a deep census of the atomic and molecular content, physical conditions, chemical abundances and elemental depletion levels for each sightline. Achieving these goals requires a homogeneous set of high-quality data in terms of resolution (R 70 000-100 000), sensitivity (S/N up to 1000 per resolution element), and spectral coverage (305-1042 nm), as well as a large sample size (100+ sightlines). In this first paper the goals, objectives and methodology of the EDIBLES programme are described and an initial assessment of the data is provided.

  4. Establishing geochemical background variation and threshold values for 59 elements in Australian surface soil.

    Science.gov (United States)

    Reimann, Clemens; de Caritat, Patrice

    2017-02-01

    During the National Geochemical Survey of Australia over 1300 top (0-10cm depth) and bottom (~60-80cm depth) sediment samples (including ~10% field duplicates) were collected from the outlet of 1186 catchments covering 81% of the continent at an average sample density of 1 site/5200km 2 . The PTEs), in Australian surface soil. Different methods of obtaining geochemical threshold values, which differentiate between background and those samples with unusually high element concentrations and requiring attention, are presented and compared to Western Australia's 'ecological investigation levels' (EILs) established for 14 PTEs. For Mn and V these EILs are so low that an unrealistically large proportion (~24%) of the sampled sites would need investigation in Australia. For the 12 remaining elements (As, Ba, Cd, Co, Cr, Cu, Hg, Mo, Ni, Pb, Sn and Zn) few sample sites require investigation and as most of these are located far from human activity centres, they potentially suggest either minor local contamination or mineral exploration potential rather than pollution. No major diffuse source of contamination by PTEs affects Australian soil at the continental scale. Of the statistical methods used to establish geochemical threshold values, the most pertinent results come from identifying breaks in cumulative probability distributions, the Tukey inner fence and the 98th percentile. Geochemical threshold values for 59 elements, including emerging 'high-tech' critical elements such as lanthanides, Be, Ga or Ge, for which no EILs currently exist, are presented. Crown Copyright © 2016. Published by Elsevier B.V. All rights reserved.

  5. Alaska Geochemical Database (AGDB)-Geochemical data for rock, sediment, soil, mineral, and concentrate sample media

    Science.gov (United States)

    Granitto, Matthew; Bailey, Elizabeth A.; Schmidt, Jeanine M.; Shew, Nora B.; Gamble, Bruce M.; Labay, Keith A.

    2011-01-01

    The Alaska Geochemical Database (AGDB) was created and designed to compile and integrate geochemical data from Alaska in order to facilitate geologic mapping, petrologic studies, mineral resource assessments, definition of geochemical baseline values and statistics, environmental impact assessments, and studies in medical geology. This Microsoft Access database serves as a data archive in support of present and future Alaskan geologic and geochemical projects, and contains data tables describing historical and new quantitative and qualitative geochemical analyses. The analytical results were determined by 85 laboratory and field analytical methods on 264,095 rock, sediment, soil, mineral and heavy-mineral concentrate samples. Most samples were collected by U.S. Geological Survey (USGS) personnel and analyzed in USGS laboratories or, under contracts, in commercial analytical laboratories. These data represent analyses of samples collected as part of various USGS programs and projects from 1962 to 2009. In addition, mineralogical data from 18,138 nonmagnetic heavy mineral concentrate samples are included in this database. The AGDB includes historical geochemical data originally archived in the USGS Rock Analysis Storage System (RASS) database, used from the mid-1960s through the late 1980s and the USGS PLUTO database used from the mid-1970s through the mid-1990s. All of these data are currently maintained in the Oracle-based National Geochemical Database (NGDB). Retrievals from the NGDB were used to generate most of the AGDB data set. These data were checked for accuracy regarding sample location, sample media type, and analytical methods used. This arduous process of reviewing, verifying and, where necessary, editing all USGS geochemical data resulted in a significantly improved Alaska geochemical dataset. USGS data that were not previously in the NGDB because the data predate the earliest USGS geochemical databases, or were once excluded for programmatic reasons

  6. Towards a 3d Based Platform for Cultural Heritage Site Survey and Virtual Exploration

    Science.gov (United States)

    Seinturier, J.; Riedinger, C.; Mahiddine, A.; Peloso, D.; Boï, J.-M.; Merad, D.; Drap, P.

    2013-07-01

    This paper present a 3D platform that enables to make both cultural heritage site survey and its virtual exploration. It provides a single and easy way to use framework for merging multi scaled 3D measurements based on photogrammetry, documentation produced by experts and the knowledge of involved domains leaving the experts able to extract and choose the relevant information to produce the final survey. Taking into account the interpretation of the real world during the process of archaeological surveys is in fact the main goal of a survey. New advances in photogrammetry and the capability to produce dense 3D point clouds do not solve the problem of surveys. New opportunities for 3D representation are now available and we must to use them and find new ways to link geometry and knowledge. The new platform is able to efficiently manage and process large 3D data (points set, meshes) thanks to the implementation of space partition methods coming from the state of the art such as octrees and kd-trees and thus can interact with dense point clouds (thousands to millions of points) in real time. The semantisation of raw 3D data relies on geometric algorithms such as geodetic path computation, surface extraction from dense points cloud and geometrical primitive optimization. The platform provide an interface that enables expert to describe geometric representations of interesting objects like ashlar blocs, stratigraphic units or generic items (contour, lines, … ) directly onto the 3D representation of the site and without explicit links to underlying algorithms. The platform provide two ways for describing geometric representation. If oriented photographs are available, the expert can draw geometry on a photograph and the system computes its 3D representation by projection on the underlying mesh or the points cloud. If photographs are not available or if the expert wants to only use the 3D representation then he can simply draw objects shape on it. When 3D

  7. WIDE-FIELD INFRARED SURVEY EXPLORER OBSERVATIONS OF THE EVOLUTION OF MASSIVE STAR-FORMING REGIONS

    Energy Technology Data Exchange (ETDEWEB)

    Koenig, X. P.; Leisawitz, D. T.; Benford, D. J.; Padgett, D. L. [NASA Goddard Space Flight Center, Greenbelt, MD 20771 (United States); Rebull, L. M. [Spitzer Science Center (SSC), California Institute of Technology, M/S 220-6, 1200 East California Boulevard, Pasadena, CA 91125 (United States); Assef, R. J. [Jet Propulsion Laboratory, MS 169-530, 4800 Oak Grove Drive, Pasadena, CA 91109 (United States)

    2012-01-10

    We present the results of a mid-infrared survey of 11 outer Galaxy massive star-forming regions and 3 open clusters with data from the Wide-field Infrared Survey Explorer (WISE). Using a newly developed photometric scheme to identify young stellar objects and exclude extragalactic contamination, we have studied the distribution of young stars within each region. These data tend to support the hypothesis that latter generations may be triggered by the interaction of winds and radiation from the first burst of massive star formation with the molecular cloud material leftover from that earlier generation of stars. We dub this process the 'fireworks hypothesis' since star formation by this mechanism would proceed rapidly and resemble a burst of fireworks. We have also analyzed small cutout WISE images of the structures around the edges of these massive star-forming regions. We observe large (1-3 pc size) pillar and trunk-like structures of diffuse emission nebulosity tracing excited polycyclic aromatic hydrocarbon molecules and small dust grains at the perimeter of the massive star-forming regions. These structures contain small clusters of emerging Class I and Class II sources, but some are forming only a single to a few new stars.

  8. Ethics Considerations in Global Mobile Phone-Based Surveys of Noncommunicable Diseases: A Conceptual Exploration.

    Science.gov (United States)

    Ali, Joseph; Labrique, Alain B; Gionfriddo, Kara; Pariyo, George; Gibson, Dustin G; Pratt, Bridget; Deutsch-Feldman, Molly; Hyder, Adnan A

    2017-05-05

    Mobile phone coverage has grown, particularly within low- and middle-income countries (LMICs), presenting an opportunity to augment routine health surveillance programs. Several LMICs and global health partners are seeking opportunities to launch basic mobile phone-based surveys of noncommunicable diseases (NCDs). The increasing use of such technology in LMICs brings forth a cluster of ethical challenges; however, much of the existing literature regarding the ethics of mobile or digital health focuses on the use of technologies in high-income countries and does not consider directly the specific ethical issues associated with the conduct of mobile phone surveys (MPS) for NCD risk factor surveillance in LMICs. In this paper, we explore conceptually several of the central ethics issues in this domain, which mainly track the three phases of the MPS process: predata collection, during data collection, and postdata collection. These include identifying the nature of the activity; stakeholder engagement; appropriate design; anticipating and managing potential harms and benefits; consent; reaching intended respondents; data ownership, access and use; and ensuring LMIC sustainability. We call for future work to develop an ethics framework and guidance for the use of mobile phones for disease surveillance globally. ©Joseph Ali, Alain B Labrique, Kara Gionfriddo, George Pariyo, Dustin G Gibson, Bridget Pratt, Molly Deutsch-Feldman, Adnan A Hyder. Originally published in the Journal of Medical Internet Research (http://www.jmir.org), 05.05.2017.

  9. Wide-Field Infrared Survey Explorer Observations of the Evolution of Massive Star-Forming Regions

    Science.gov (United States)

    Koenig, X. P.; Leisawitz, D. T.; Benford, D. J.; Rebull, L. M.; Padgett, D. L.; Asslef, R. J.

    2012-01-01

    We present the results of a mid-infrared survey of II outer Galaxy massive star-forming regions and 3 open clusters with data from the Wide-field Infrared Survey Explorer (WISE). Using a newly developed photometric scheme to identify young stellar objects and exclude extragalactic contamination, we have studied the distribution of young stars within each region. These data tend to support the hypothesis that latter generations may be triggered by the interaction of winds and radiation from the first burst of massive star formation with the molecular cloud material leftover from that earlier generation of stars. We dub this process the "fireworks hypothesis" since star formation by this mechanism would proceed rapidly and resemble a burst of fireworks. We have also analyzed small cutout WISE images of the structures around the edges of these massive star-forming regions. We observe large (1-3 pc size) pillar and trunk-like structures of diffuse emission nebulosity tracing excited polycyclic aromatic hydrocarbon molecules and small dust grains at the perimeter of the massive star-forming regions. These structures contain small clusters of emerging Class I and Class II sources, but some are forming only a single to a few new stars.

  10. Exploration of Global Trend on Biomedical Application of Polyhydroxyalkanoate (PHA): A Patent Survey.

    Science.gov (United States)

    Ponnaiah, Paulraj; Vnoothenei, Nagiah; Chandramohan, Muruganandham; Thevarkattil, Mohamed Javad Pazhayakath

    2018-01-30

    Polyhydroxyalkanoates are bio-based, biodegradable naturally occurring polymers produced by a wide range of organisms, from bacteria to higher mammals. The properties and biocompatibility of PHA make it possible for a wide spectrum of applications. In this context, we analyze the potential applications of PHA in biomedical science by exploring the global trend through the patent survey. The survey suggests that PHA is an attractive candidate in such a way that their applications are widely distributed in the medical industry, drug delivery system, dental material, tissue engineering, packaging material as well as other useful products. In our present study, we explored patents associated with various biomedical applications of polyhydroxyalkanoates. Patent databases of European Patent Office, United States Patent and Trademark Office and World Intellectual Property Organization were mined. We developed an intensive exploration approach to eliminate overlapping patents and sort out significant patents. We demarcated the keywords and search criterions and established search patterns for the database request. We retrieved documents within the recent 6 years, 2010 to 2016 and sort out the collected data stepwise to gather the most appropriate documents in patent families for further scrutiny. By this approach, we retrieved 23,368 patent documents from all the three databases and the patent titles were further analyzed for the relevance of polyhydroxyalkanoates in biomedical applications. This ensued in the documentation of approximately 226 significant patents associated with biomedical applications of polyhydroxyalkanoates and the information was classified into six major groups. Polyhydroxyalkanoates has been patented in such a way that their applications are widely distributed in the medical industry, drug delivery system, dental material, tissue engineering, packaging material as well as other useful products. There are many avenues through which PHA & PHB could be

  11. Geochemical modeling: a review

    Energy Technology Data Exchange (ETDEWEB)

    Jenne, E.A.

    1981-06-01

    Two general families of geochemical models presently exist. The ion speciation-solubility group of geochemical models contain submodels to first calculate a distribution of aqueous species and to secondly test the hypothesis that the water is near equilibrium with particular solid phases. These models may or may not calculate the adsorption of dissolved constituents and simulate the dissolution and precipitation (mass transfer) of solid phases. Another family of geochemical models, the reaction path models, simulates the stepwise precipitation of solid phases as a result of reacting specified amounts of water and rock. Reaction path models first perform an aqueous speciation of the dissolved constituents of the water, test solubility hypotheses, then perform the reaction path modeling. Certain improvements in the present versions of these models would enhance their value and usefulness to applications in nuclear-waste isolation, etc. Mass-transfer calculations of limited extent are certainly within the capabilities of state-of-the-art models. However, the reaction path models require an expansion of their thermodynamic data bases and systematic validation before they are generally accepted.

  12. Geochemical baseline studies of soil in Finland

    Science.gov (United States)

    Pihlaja, Jouni

    2017-04-01

    The soil element concentrations regionally vary a lot in Finland. Mostly this is caused by the different bedrock types, which are reflected in the soil qualities. Geological Survey of Finland (GTK) is carrying out geochemical baseline studies in Finland. In the previous phase, the research is focusing on urban areas and mine environments. The information can, for example, be used to determine the need for soil remediation, to assess environmental impacts or to measure the natural state of soil in industrial areas or mine districts. The field work is done by taking soil samples, typically at depth between 0-10 cm. Sampling sites are chosen to represent the most vulnerable areas when thinking of human impacts by possible toxic soil element contents: playgrounds, day-care centers, schools, parks and residential areas. In the mine districts the samples are taken from the areas locating outside the airborne dust effected areas. Element contents of the soil samples are then analyzed with ICP-AES and ICP-MS, Hg with CV-AAS. The results of the geochemical baseline studies are published in the Finnish national geochemical baseline database (TAPIR). The geochemical baseline map service is free for all users via internet browser. Through this map service it is possible to calculate regional soil baseline values using geochemical data stored in the map service database. Baseline data for 17 elements in total is provided in the map service and it can be viewed on the GTK's web pages (http://gtkdata.gtk.fi/Tapir/indexEN.html).

  13. Development of a Survey to Explore Factors Influencing the Adoption of Best Practices for Diabetic Foot Ulcer Offloading.

    Science.gov (United States)

    Bleau Lavigne, Maude; Reeves, Isabelle; Sasseville, Marie-Josée; Loignon, Christine

    The primary purpose of this study was to develop 2 survey tools to explore factors influencing adoption of best practices for diabetic foot ulcer offloading treatment in primary health care settings. One survey was intended for the patients receiving care for a diabetic foot ulcer in primary health care settings and the other was intended for the health professionals providing treatment. The second purpose of this study was to evaluate the psychometric properties of the 2 surveys. Development and validation of survey instruments. Two surveys were developed using a published guide. Following review of pertinent literature and identification of variables to be measured, a bank of items was developed and pretested to determine clarity of the item and responses. Psychometric testing comprised measurement of content validity index (CVI) and intraclass correlation coefficient (ICC). Only items obtaining satisfactory CVI and ICC scores were included in the final version of the surveys. The final version of the patient survey contained 41 items and the final version of the survey for health care professionals contained 21 items. The patient-intended survey's items demonstrate high content validity scores and satisfactory test-retest reliability scores. The overall CVI score was 0.98. Forty of the 49 items eligible for testing obtain satisfactory ICC scores. One item's test-retest reliability could not be tested but it was retained based on its high CVI. The health professional-intended survey, an overall CVI score of 0.91 but items had lower ICC scores (63%, 31 of the 49 items), did not achieve a satisfactory ICC score for inclusion in the final instrument. This project led to development of 2 instruments designed to identify and explore factors influencing adoption of best practices for diabetic foot ulcer offloading treatment in the primary health care setting. Future research and testing is required to translate these French surveys into English and additional languages

  14. Exploring the Therapeutic Affordances of Self-Harm Online Support Communities: An Online Survey of Members.

    Science.gov (United States)

    Coulson, Neil S; Bullock, Emma; Rodham, Karen

    2017-10-13

    A growing number of online communities have been established to support those who self-harm. However, little is known about the therapeutic affordances arising from engagement with these communities and resulting outcomes. The aim of this study was to explore the presence of therapeutic affordances as reported by members of self-harm online support communities. In total, 94 respondents (aged 13-63 years, mean=23.5 years; 94% female) completed an online survey exploring their experiences of engaging with a self-harm online support community. Respondents varied in terms of how long they had been accessing an online community, with 22% (21/94) accessing less than 1 year, 39% (37/94) 1 to 2 years, 14% (13/94) 2 to 3 years, and 24.5% (23/94) more than 3 years. Responses were analyzed using deductive thematic analysis. The results of our analysis describe each of the five therapeutic affordances that were present in the data, namely (1) connection, the ability to make contact with others who self-harm for the purposes of mutual support and in so doing reduce feelings of loneliness and isolation; (2) adaptation, that is, how use of online support varies in relation to the personal circumstances of the individual user; (3) exploration, that is, the ability to learn about self-harm and learn about strategies to reduce or stop self-harming behavior; (4) narration, that is, the ability to share experiences, as well as read about the experiences of others; and (5) self-presentation, that is, how and what users present about themselves to others in the online community. Our findings suggest that engagement with self-harm online support communities may confer a range of therapeutic benefits for some users, which may serve to minimize the psychosocial burden of self-harm and promote positive coping strategies. In addition, the online nature of the support available may be helpful to those who are unable to access face-to-face support.

  15. Genetic counseling: a survey to explore knowledge and attitudes of Italian nurses and midwives.

    Science.gov (United States)

    Godino, Lea; Turchetti, Daniela; Skirton, Heather

    2013-03-01

    In the past, genetic services were delivered to a limited number of families with rare conditions. However, genomics is now being applied to both inherited and common diseases in a range of healthcare settings, and there is a greater need for nurses to understand the basic concepts of genetic health care. The aim of this cross-sectional survey was to explore the understanding and attitudes of Italian nurses toward genetic health care. A questionnaire was completed by 102 nurses and midwives (85% response rate). Of these, 61% believed that genetic counseling was only an informative and advisory process, and 53.9% could not specify to whom the counseling was aimed. When asked to identify nurses' role in genetic health care, 62% of the respondents believed they had no role, although 28% believed that nurses could provide information, support, and counseling. These findings indicate that nurses have only partial knowledge of the issues surrounding genetic health care. To prepare nurses for the post-genomic era, improved genetic education at the undergraduate and postgraduate levels is required. © 2012 Wiley Publishing Asia Pty Ltd.

  16. HUBBLE SPACE TELESCOPE SPECTROSCOPY OF BROWN DWARFS DISCOVERED WITH THE WIDE-FIELD INFRARED SURVEY EXPLORER

    Energy Technology Data Exchange (ETDEWEB)

    Schneider, Adam C.; Cushing, Michael C. [Department of Physics and Astronomy, University of Toledo, 2801 W. Bancroft St., Toledo, OH 43606 (United States); Kirkpatrick, J. Davy; Gelino, Christopher R. [Infrared Processing and Analysis Center, MS 100-22, California Institute of Technology, Pasadena, CA 91125 (United States); Mace, Gregory N.; Wright, Edward L. [Department of Physics and Astronomy, UCLA, 430 Portola Plaza, Box 951547, Los Angeles, CA 90095-1547 (United States); Eisenhardt, Peter R. [Jet Propulsion Laboratory, California Institute of Technology, 4800 Oak Grove Dr., Pasadena, CA 91109 (United States); Skrutskie, M. F. [Department of Astronomy, University of Virginia, 530 McCormick Road, Charlottesville, VA 22904 (United States); Griffith, Roger L. [Department of Astronomy and Astrophysics, 525 Davey Lab, The Pennsylvania State University, University Park, PA 16802 (United States); Marsh, Kenneth A., E-mail: Adam.Schneider@Utoledo.edu [School of Physics and Astronomy, Cardiff University, Cardiff CF24 3AA (United Kingdom)

    2015-05-10

    We present a sample of brown dwarfs identified with the Wide-field Infrared Survey Explorer (WISE) for which we have obtained Hubble Space Telescope (HST) Wide Field Camera 3 (WFC3) near-infrared grism spectroscopy. The sample (22 in total) was observed with the G141 grism covering 1.10–1.70 μm, while 15 were also observed with the G102 grism, which covers 0.90–1.10 μm. The additional wavelength coverage provided by the G102 grism allows us to (1) search for spectroscopic features predicted to emerge at low effective temperatures (e.g.,ammonia bands) and (2) construct a smooth spectral sequence across the T/Y boundary. We find no evidence of absorption due to ammonia in the G102 spectra. Six of these brown dwarfs are new discoveries, three of which are found to have spectral types of T8 or T9. The remaining three, WISE J082507.35+280548.5 (Y0.5), WISE J120604.38+840110.6 (Y0), and WISE J235402.77+024015.0 (Y1), are the 19th, 20th, and 21st spectroscopically confirmed Y dwarfs to date. We also present HST grism spectroscopy and reevaluate the spectral types of five brown dwarfs for which spectral types have been determined previously using other instruments.

  17. Exploring the expansion dynamics of the universe from galaxy cluster surveys

    Science.gov (United States)

    Wang, Deng; Meng, Xin-He

    2017-12-01

    To understand the expansion dynamics of the universe from galaxy cluster scales, using the angular diameter distance (ADD) data from two different galaxy cluster surveys, we constrain four cosmological models to explore the underlying value of H0 and employ the model-independent Gaussian Processes to investigate the evolution of the equation of state of dark energy. The ADD data in the X-ray bands consists of two samples covering the redshift ranges [0.023, 0.784] and [0.14, 0.89], respectively. We find that: (i) For these two samples, the obtained values of H0 are more consistent with the recent local observation by Riess et al. than the global measurement by the Planck Collaboration, and the ΛCDM model is still preferred utilizing the information criterions; (ii) For the first sample, there is no evidence of dynamical dark energy (DDE) at the 2 σ confidence level (CL); (iii) For the second one, the reconstructed equation of state of dark energy exhibits a phantom-crossing behavior in the relatively low redshift range over the 2 σ CL, which gives a hint that the late-time universe may be actually dominated by the DDE from galaxy cluster scales; (iv) By adding a combination of Type Ia Supernovae, cosmic chronometers and Planck-2015 shift parameter and HII galaxy measurements into both ADD samples, the DDE exists evidently over the 2 σ CL.

  18. Applications of microcomputing devices to a field exploration environment: advantages and pitfalls

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, I.M.; Parker, W.

    1982-04-01

    Modern digital computers are able to store, manipulate, process and plot large volumes of data quickly. Most ground geological, geophysical and geochemical survey data, however, are still treated largely with paper and pencil from in-field data gathered to final plotting. The authors review the introduction of advanced micro-processor electronics into the field exploration environment.

  19. Exploring the gap between the practical and theoretical world of ERP implementations: results of a global survey.

    NARCIS (Netherlands)

    Catersels, R.; Helms, R.W.; Batenburg, R.

    2010-01-01

    This paper describes the differences between the theoretical world of ERP researchers and the practical world of ERP consultants. A survey was held among 129 ERP consultants to explore their opinion and experience with regard to a number of subjects that have been researched in many papers, such as

  20. Results from a Pilot REU Program: Exploring the Cosmos Using Sloan Digital Sky Survey Data

    Science.gov (United States)

    Chanover, Nancy J.; Holley-Bockelmann, Kelly; Holtzman, Jon A.

    2017-01-01

    In the Summer of 2016 we conducted a 10-week pilot Research Experience for Undergraduates (REU) program aimed at increasing the participation of underrepresented minority undergraduate students in research using data from the Sloan Digital Sky Survey (SDSS). This program utilized a distributed REU model, whereby students worked with SDSS scientists on exciting research projects while serving as members of a geographically distributed research community. The format of this REU is similar to that of the SDSS collaboration itself, and since this collaboration structure has become a model for the next generation of large scale astronomical surveys, the students participating in the SDSS REU received early exposure and familiarity with this approach to collaborative scientific research. The SDSS REU also provided the participants with a low-risk opportunity to audition for graduate schools and to explore opportunities afforded by a career as a research scientist. The six student participants were placed at SDSS REU host sites at the Center for Astrophysics at Harvard University, University of Wisconsin-Madison, Vanderbilt University, and the University of Portsmouth. Their research projects covered a broad range of topics related to stars, galaxies, and quasars, all making use of SDSS data. At the start of the summer the REU students participated in a week-long Boot Camp at NMSU, which served as a program orientation, an introduction to skills relevant to their research projects, and an opportunity for team-building and cohort-forming. To foster a sense of community among our distributed students throughout the summer, we conducted a weekly online meeting for all students in the program via virtual meeting tools. These virtual group meetings served two purposes: as a weekly check-in to find out how their projects were progressing, and to conduct professional development seminars on topics of interest and relevance to the REU participants. We discuss the outcomes of this

  1. Validation of a motivation survey tool for pharmacy students: Exploring a link to professional identity development.

    Science.gov (United States)

    Mylrea, Martina F; Sen Gupta, Tarun; Glass, Beverley D

    2017-09-01

    Self-determination theory (SDT), which describes a continuum of motivation regulators, is proposed as an appropriate framework to study pharmacy student motivation. The aim was to develop a Pharmacy Motivation Scale (Pharm-S) to determine motivation regulators in undergraduate students and explore a possible link to professional identity development. The Pharm-S was adapted from the SDT-based, Sports Motivation Scale (SMS-II), and administered to undergraduate students in an Australian pharmacy course. Convergent validity was assessed by conducting a correlation analysis between the Pharm-S and MacLeod Clark Professional Identity Scale (MCPIS-9). Face, content and construct validity were established for the Pharm-S through the analysis of 327 survey responses. Factor analysis extracted four of the six theoretical subscales as proposed by SDT (variance explained: 65.7%). Support for the SDT structure was confirmed by high factor loadings in each of the subscales and acceptable reliability coefficients. Subscale correlations revealed a simplex pattern, supporting the presence of a motivation continuum, as described by SDT. A moderate positive correlation (0.64) between Pharm-S responses and the validated professional identity instrument, MCPIS-9, indicated a possible link between levels of motivation and professional identity. and conclusions: Content and structural validity and internal consistency of the Pharm-S confirmed the reliability of the Pharm-S as a valid tool to assess motivational regulators. Pharm-S and the MCPIS-9 were positively correlated, lending support to a link between motivation and professional identity. This suggests a potential role for the Pharm-S as a valid tool to measure pharmacy student professional identity development. Crown Copyright © 2017. Published by Elsevier Inc. All rights reserved.

  2. The Advancement of Geothermal Energy Production through Improved Exploration Methods

    Science.gov (United States)

    Thorsteinsson, H.; Klein, K.

    2010-12-01

    Through the American Recovery and Reinvestment Act of 2009, the U.S. Department of Energy’s Geothermal Technologies Program invested $98 million in the geothermal exploration industry, and continues to encourage further research, development and demonstration in this field. The continued development of innovative exploration technologies is essential for wide adoption of geothermal resources. In 2008, the United States Geological Survey estimated that there are approximately 30,000 MW of undiscovered hydrothermal resources in the western United States alone. Improvements in exploration technologies are necessary to discover and define these hidden resources and to reduce up-front risk and cost through more accurate and efficient exploration. Currently, the surface and subsurface are characterized through combinations of ground-based and airborne geophysical surveys, geochemical surveys, satellite imaging and drilling. However, to increase geothermal exploration well success rates, development of improved and new exploration techniques is required.

  3. [Microbial geochemical calcium cycle].

    Science.gov (United States)

    Zavarzin, G A

    2002-01-01

    The participation of microorganisms in the geochemical calcium cycle is the most important factor maintaining neutral conditions on the Earth. This cycle has profound influence on the fate of inorganic carbon, and, thereby, on the removal of CO2 from the atmosphere. The major part of calcium deposits was formed in the Precambrian, when prokaryotic biosphere predominated. After that, calcium recycling based on biogenic deposition by skeletal organisms became the main process. Among prokaryotes, only a few representatives, e.g., cyanobacteria, exhibit a special calcium function. The geochemical calcium cycle is made possible by the universal features of bacteria involved in biologically mediated reactions and is determined by the activities of microbial communities. In the prokaryotic system, the calcium cycle begins with the leaching of igneous rock predominantly through the action of the community of organotrophic organisms. The release of carbon dioxide to the soil air by organotrophic aerobes leads to leaching with carbonic acid and soda salinization. Under anoxic conditions, of major importance is the organic acid production by primary anaerobes (fermentative microorganisms). Calcium carbonate is precipitated by secondary anaerobes (sulfate reducers) and to a smaller degree by methanogens. The role of the cyanobacterial community in carbonate deposition is exposed by stromatolites, which are the most common organo-sedimentary Precambrian structures. Deposition of carbonates in cyanobacterial mats as a consequence of photoassimilation of CO2 does not appear to be a significant process. It is argued that carbonates were deposited at the boundary between the "soda continent", which emerged as a result of subaerial leaching with carbonic acid, and the ocean containing Ca2+. Such ecotones provided favorable conditions for the development of the benthic cyanobacterial community, which was a precursor of stromatolites.

  4. Leveling data in geochemical mapping: scope of application, pros and cons of existing methods

    Science.gov (United States)

    Pereira, Benoît; Vandeuren, Aubry; Sonnet, Philippe

    2017-04-01

    Geochemical mapping successfully met a range of needs from mineral exploration to environmental management. In Europe and around the world numerous geochemical datasets already exist. These datasets may originate from geochemical mapping projects or from the collection of sample analyses requested by environmental protection regulatory bodies. Combining datasets can be highly beneficial for establishing geochemical maps with increased resolution and/or coverage area. However this practice requires assessing the equivalence between datasets and, if needed, applying data leveling to remove possible biases between datasets. In the literature, several procedures for assessing dataset equivalence and leveling data are proposed. Daneshfar & Cameron (1998) proposed a method for the leveling of two adjacent datasets while Pereira et al. (2016) proposed two methods for the leveling of datasets that contain records located within the same geographical area. Each discussed method requires its own set of assumptions (underlying populations of data, spatial distribution of data, etc.). Here we propose to discuss the scope of application, pros, cons and practical recommendations for each method. This work is illustrated with several case studies in Wallonia (Southern Belgium) and in Europe involving trace element geochemical datasets. References: Daneshfar, B. & Cameron, E. (1998), Leveling geochemical data between map sheets, Journal of Geochemical Exploration 63(3), 189-201. Pereira, B.; Vandeuren, A.; Govaerts, B. B. & Sonnet, P. (2016), Assessing dataset equivalence and leveling data in geochemical mapping, Journal of Geochemical Exploration 168, 36-48.

  5. Exploring Ethical Issues Associated with Using Online Surveys in Educational Research

    Science.gov (United States)

    Roberts, Lynne D.; Allen, Peter J.

    2015-01-01

    Online surveys are increasingly used in educational research, yet little attention has focused on ethical issues associated with their use in educational settings. Here, we draw on the broader literature to discuss 5 key ethical issues in the context of educational survey research: dual teacher/researcher roles; informed consent; use of…

  6. The geochemical Phenomenon-Local geochemical fields in a glacier (scientific note)

    OpenAIRE

    V. N., Makarov

    2001-01-01

    Geochemical fields in alpine cold and warm glaciers were studied. Local geochemical fields of typomorphic elements were found to form in the ice and on the surface of glaciers overlying ore bodies and endogenic geochemical haloes. The formation of local cryogenic geochemical fields in the glaciers results from sharp geochemical heterogeneity and geochemical processes in underlying rocks which cause cryogenic migration of chemical elements and compounds in the glacier. The thickness of geochem...

  7. Complexing-precipitating geochemical barriers

    Science.gov (United States)

    Savenko, A. V.

    2017-02-01

    New types of geochemical barriers on which chemical elements are immobilized as a result of combined complex formation and precipitation of barely soluble mineral phases are examined. A significant concentration of major components (Fe, Al) forming more stable complexes than an immobilized component X in the material is a necessary condition for this type of geochemical barriers. Filtration of the solution through a geochemical barrier is accompanied by substitution of X in the complex with a major component. As a result, the activity of X in the free state increases, and one barely soluble mineral phase or another of the component X precipitates when the state of saturation is achieved.

  8. EX1305: Summer Ecosystem Monitoring Survey on NOAA Ship Okeanos Explorer between 20130821 and 20130901

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The survey consists of 120 random stratified stations in the Middle Atlantic Bight, Southern New England, Georges Bank and the Gulf of Maine. Depending on the...

  9. Exploring Student-to-Workforce Transitions with the National Geoscience Exit Survey

    Science.gov (United States)

    Gonzales, L. M.; Keane, C. M.; Houlton, H. R.

    2011-12-01

    In 2011, the American Geological Institute (AGI) launched the first pilot of a National Geoscience Exit Survey in collaboration with 32 geoscience university departments. The survey collects data about demographics, high school and community college coursework, university degrees, financial aid, field and research experiences, internships, and when and why the student chose to pursue a geosciences degree. Additionally, the survey collects information about students' future academic and career plans, and gives participants the option to take part in a longitudinal survey to track long-term career trajectories of geosciences graduates. The survey also provides geoscience departments with the ability to add customized questions to collect data about important departmental-level topics. The National Geoscience Exit Survey will be available to all U.S. geoscience programs at two- and four-year colleges and universities by the end of the 2011-2012 academic year. We use the results of the National Geoscience Exit Survey to examine student preparation and transition into geosciences and non-geoscience careers. Preliminary results from the pilot survey indicated future academic and career trajectories for geoscience Bachelor's degree recipients included graduate school (53%) and pursuit of a geoscience career (45%), with some undergraduates keeping their options open for either trajectory. Twelve percent of Bachelor's degree recipients already accepted job offers with geoscience employers. For geoscience Master's degree recipients, 17% planned to continue in graduate school, 35% were seeking a geoscience job, and 42% had already accepted job offers with geoscience employers. Furthermore, the majority of those geoscience graduates who already accepted geoscience job offers had also interned previously with the employer.

  10. Spiral Survey Expedition: A proposal to organize for the Survey, exploration and eventual colonization of the Milky Way Galaxy

    Science.gov (United States)

    Galloway, Scott

    1993-12-01

    This paper details a plan to explore the galaxy. Areas of interest to an era of cyberspace include the Tech-Index information system for the expedition and the role cyberspace has in increasing expedition productivity and increasing the capabilities of cyberspace by expanding the goals and data set. The paper offers lists of projects for the cybermarket pool. The expedition is described also as a developers tool for cyberspace to acknowledge the scope of the human mind far surpasses present engineering yet guides our direction of energies and materials. Maintaining the biological capability to reproduce the Terran biosphere via Evolution park conservation areas is discussed. The ecological repair of Spaceship Earth and the build up of an interstellar industrial base from simple recyling and educational programs is meshed with a proposed 'reverse engineering cyberspace' plan. A set of constructive contests are proposed with 3 new currencies offered as prizes. The Planet, The Solar System, The Galaxy are 3 areas of focus. Each of these areas are considered in a cyberspectrum of (1) Sentience; (2) Biological diversity; and (3) Energy/Matter resources.

  11. Metallogenetic characterization of granitoid rocks through geochemical prospection: the Lagoa Real example related to uranium mineralization in Bahia state, Brazil; Caracterizacao metalogenetica de corpos gratinoides atraves de prospeccao geoquimica: o exemplo da suite intrusiva Lagoa Real relacionada a mineralizacoes de uranio no Estado da Bahia

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, J.E., E-mail: cprmsa@bahianet.com.br [Servico Geologico do Brasil (GEREMI/SUREG/SA/CPRM), Salvador, BA (Brazil)

    2011-07-01

    Within a broad metallogenetic evaluation program carried out by CPRM - Geological Survey of Brazil in covenant with the CBPM - Companhia Baiana de Pesquisa Mineral in the central part of the Sao Francisco Craton, the Lagoa Real granitoid rocks was one of the selected targets. The work included geochemical exploration supplemented by follow-in survey and integrated 1:200.000 scale geochemical cartography. The Lagoa Real granitoid was recognized with composition ranging from monzogranitic to alcaligranitic type. The geochemical surveying led to the definition of the metallogenetic specialization of the granitoid rock, with characteristic geochemical and mineralogic associations. These associations are related to uranium mineralization. The genetic model using stream sediment and pan concentrate data, show similarity with the metallogenetic model of zonal partitioning proposed by Routhier (1963), for plutonogenic lode deposits with potential for Sn, W, Nb, Be, REE, Au, and U. In this work emphasis is given to the importance of the integrated use of different prospective methods toward the evaluation of granitoid systems, particularly the combination of geochemical surveying methods with results for a better understanding of the geologic and metallogenetic settings. (author)

  12. Exploring community pharmacists' experiences of surveying patients for drug utilization research purposes

    DEFF Research Database (Denmark)

    Frisk, Pia; Bergman, Ulrika; Kälvemark Sporrong, Sofia

    2015-01-01

    , and dispensing pharmacists suitable for conducting them. When regular dispensing staff perform the survey interviews as a part of the drug dispensing process, additional resources to manage the immediate increase in work load have to be considered. Otherwise, data quality may be compromised.......Background Patient self-reported data are important in drug utilization research, but often logistically difficult to collect. During 2006–2012, 72 Swedish community pharmacies regularly collected such data through structured survey interviews at the pharmacy counter, performed by the dispensing...

  13. The geological effect of direct exploring the hydrocarbon reservoir in Chaidamu basin using airborne magnetic survey

    Energy Technology Data Exchange (ETDEWEB)

    Luling, L.; Yongxia, Z.; Fuhong, Z.

    1987-04-01

    There are good geological and geophysical conditions for airborne magnetic survey in Chaidamu basin because there is no igneous rock in sedimentary formation, and a little civilization interference in the basin. The upmigrated hydrocarbon from reservoir caused chemical reaction in overburden to form magnetite, which results in magnetic anomaly. The minimum altitude airborne magnetic survey (with large scale and high accuracy) mapped weak magnetic anomaly which covers a large area. It has been proved that the weak magnetic anomaly is related to hydrocarbon accumulation. This experience can also be used in other sedimentary basins in Northwest China which have analogous geological and geophysical conditions.

  14. Exploring how to increase response rates to surveys of older people.

    Science.gov (United States)

    Palonen, Mira; Kaunonen, Marja; Åstedt-Kurki, Päivi

    2016-05-01

    To address the special considerations that need to be taken into account when collecting data from older people in healthcare research. An objective of all research studies is to ensure there is an adequate sample size. The final sample size will be influenced by methods of recruitment and data collection, among other factors. There are some special considerations that need to be addressed when collecting data among older people. Quantitative surveys of people aged 60 or over in 2009-2014 were analysed using statistical methods. A quantitative study of patients aged 75 or over in an emergency department was used as an example. A methodological approach to analysing quantitative studies concerned with older people. The best way to ensure high response rates in surveys involving people aged 60 or over is to collect data in the presence of the researcher; response rates are lowest in posted surveys and settings where the researcher is not present when data are collected. Response rates do not seem to vary according to the database from which information about the study participants is obtained or according to who is responsible for recruitment to the survey. Implications for research/practice To conduct coherent studies with older people, the data collection process should be carefully considered.

  15. Use of shallow seismic surveys in the exploration of nearshore placers off Maharashtra coast, India

    Digital Repository Service at National Institute of Oceanography (India)

    Rajamanickam, G.V.; Ramana, M.V.; Gujar, A.R.

    depth. These surveys water used for the first time in this country by the authors to determine (1) the lateral continuity of the placers below the clay, (2) the vertical thickness of placer sand and to use the same for the calculation of the inferred...

  16. Using Survey Data to Explore Preschool Children's Ethnic Awareness and Attitudes

    Science.gov (United States)

    Connolly, Paul

    2011-01-01

    This article presents the findings of a large-scale survey (n = 1049) of ethnic awareness and attitudes among three to four-year-old children in Northern Ireland. In drawing upon and applying Bourdieu's notion of habitus, the article demonstrates how, even at this age, the children are already beginning to embody and internalize the cultural…

  17. Exploring Dispositions toward Online Reading: Analyzing the Survey of Online Reading Attitudes and Behaviors

    Science.gov (United States)

    Putman, S. Michael

    2014-01-01

    The Internet is having a profound impact on the literacy practices of today's students. Acknowledging the complex processes associated with reading online, the Survey of Online Reading Attitudes and Behaviors (SORAB) was created to further our understandings in this area. A factor analysis revealed the instrument included five factors that…

  18. Exploring E-Learning Acceptance among University Students in Thailand: A National Survey

    Science.gov (United States)

    Teo, Timothy; Ruangrit, Nammon; Khlaisang, Jintavee; Thammetar, Thapanee; Sunphakitjumnong, Kobkul

    2014-01-01

    This study surveys the e-learning acceptance of university students in Thailand. One thousand nine hundred and eighty-one (1,981) participants completed the E-Learning Acceptance Measure (Teo, 2010) which measures three constructs that predict e-learning acceptance (tutor quality, perceived usefulness, and facilitating conditions). Data analysis…

  19. Using Meta-Regression to Explore Moderating Effects in Surveys of International Achievement

    Science.gov (United States)

    Benton, Tom

    2014-01-01

    This article demonstrates how meta-analytic techniques, that have typically been used to synthesize findings across numerous studies, can also be applied to examine the reasons why relationships between background characteristics and outcomes may vary across different locations in a single multi-site survey. This application is particularly…

  20. Oil samples and geochemical analyses of Afghanistan and adjacent areas (oilafg.shp)

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This shapefile contains points that describe the location of oil samples collected in Afghanistan and adjacent areas, and the results of organic geochemical analysis.

  1. Geochemical and mineralogical maps for soils of the conterminous United States

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — Geochemical and mineralogical maps along with a histogram, boxplot, and empirical cumulative distribution function plot for each element or mineral whose data are...

  2. Using laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) to explore geochemical taphonomy of vertebrate fossils in the upper cretaceous two medicine and Judith River formations of Montana

    Science.gov (United States)

    Rogers, R.R.; Fricke, H.C.; Addona, V.; Canavan, R.R.; Dwyer, C.N.; Harwood, C.L.; Koenig, A.E.; Murray, R.; Thole, J.T.; Williams, J.

    2010-01-01

    Laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) was used to determine rare earth element (REE) content of 76 fossil bones collected from the Upper Cretaceous (Campanian) Two Medicine (TMF) and Judith River (JRF) Formations of Montana. REE content is distinctive at the formation scale, with TMF samples exhibiting generally higher overall REE content and greater variability in REE enrichment than JRF samples. Moreover, JRF bones exhibit relative enrichment in heavy REE, whereas TMF bones span heavy and light enrichment fields in roughly equal proportions. TMF bones are also characterized by more negative Ce anomalies and greater U enrichment than JRF bones, which is consistent with more oxidizing diagenetic conditions in the TMF. Bonebeds in both formations show general consistency in REE content, with no indication of spatial or temporal mixing within sites. Previous studies, however, suggest that the bonebeds in question are attritional assemblages that accumulated over considerable time spans. The absence of geochemical evidence for mixing is consistent with diagenesis transpiring in settings that remained chemically and hydrologically stable during recrystallization. Lithology-related patterns in REE content were also compared, and TMF bones recovered from fluvial sandstones show relative enrichment in heavy REE when compared with bones recovered from fine-grained floodplain deposits. In contrast, JRF bones, regardless of lithologic context (sandstone versus mudstone), exhibit similar patterns of REE uptake. This result is consistent with previous reconstructions that suggest that channel-hosted microfossil bonebeds of the JRF developed via the reworking of preexisting concentrations embedded in the interfluve. Geochemical data further indicate that reworked elements were potentially delivered to channels in a recrystallized condition, which is consistent with rapid adsorption of REE postmortem. Copyright ?? 2010, SEPM (Society for

  3. Marine survey techniques: A pre-requisite in marine archaeological exploration

    Digital Repository Service at National Institute of Oceanography (India)

    Pathak, M.C.

    The topography of the sea floor is an essential tool for almost every exploration or exploitation program. Bathymetric charts are used for the measurement of topographic variation of the sea bed. The calibration by the echosounder by means of a bar...

  4. Fiscal 1995 verification survey of geothermal exploration technology. Report on a deep geothermal resource survey; 1995 nendo chinetsu tansa gijutsu nado kensho chosa. Shinbu chinetsu shigen hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-06-01

    For the purpose of reducing the risk of deep geothermal resource development, the paper investigated three factors for the formation of geothermal resource in the deep underground, that is, heat supply from heat source, supply of geothermal fluids, and the developmental status of fracture systems forming reservoir structures. The survey further clarified the status of existence of deep geothermal resource and the whole image of the geothermal system including shallow geothermal energy in order to research/study usability of deep geothermal resource. In the deep geothermal resource survey, drilling/examination were made of a deep geothermal exploration well (`WD-1,` target depth: approximately 3,000-4,000m) in the already developed area, with the aim of making rationalized promotion of the geothermal development. And the status of existence of deep geothermal resource and the whole image of the geothermal system were clarified to investigate/study usability of the geothermal system. In fiscal 1995, `WD-1` in the Kakkonda area reached a depth of 3,729m. By this, surveys were made to grasp the whole image of the shallow-deep geothermal system and to obtain basic data for researching usability of deep geothermal resource. 22 refs., 531 figs., 136 tabs.

  5. Exploring the uses of ICT in education: A national survey study

    OpenAIRE

    Reuter, Bob; Busana, Gilbert; Linckels, Serge

    2016-01-01

    This study aims at documenting current educational technology practices in Luxembourgish public schools and to better understand them in terms of various internal/proximal and external/distal enabling factors and barriers. It is supposed to serve as a guide for current digital education policies, strategies and actions and to assess their effects in the near and mid-term future. Therefore, an online survey was designed and deployed to all primary and secondary school teachers asking (mostly m...

  6. Cerro Prieto geothermal field: exploration during exploitation

    Energy Technology Data Exchange (ETDEWEB)

    1982-07-01

    Geological investigations at Momotombo included photogeology, field mapping, binocular microscope examination of cuttings, and drillhole correlations. Among the geophysical techniques used to investigate the field sub-structure were: Schlumberger and electromagnetic soundings, dipole mapping and audio-magnetotelluric surveys, gravity and magnetic measurements, frequency domain soundings, self-potential surveys, and subsurface temperature determinations. The geochemical program analyzed the thermal fluids of the surface and in the wells. The description and results of exploration methods used during the investigative stages of the Momotombo Geothermal Field are presented. A conceptual model of the geothermal field was drawn from the information available at each exploration phase. The exploration methods have been evaluated with respect to their contributions to the understanding of the field and their utilization in planning further development.

  7. 3D modelling of an aero-gravity and -magnetic survey as an first exploration step in a frontier basin

    Science.gov (United States)

    Köther, Nils; Eckard, Marcel; Götze, Hans-Jürgen

    2010-05-01

    The West African Taoudeni basin covers a desert area of about 1.8 million km² and is one of the last frontier basins worldwide. Here Wintershall Holding AG holds acreage of about 68000 km². During 2005-2007 geological surveys and an aero-gravity and -magnetic survey were conducted in this area. The potential field modelling should contribute first insight about the subsurface to plan an economic seismic survey. 2D models lead to poor results. 2008 the results of an internship (NK) were 3D subsurface models, which were enhanced during the following diploma thesis (Köther, 2009). Complex igneous rocks and sparsely distributed constraints lead to an ambiguous interpretation. Therefore, several simple 3D models were compiled with the in-house software IGMAS+, which base on geological ideas of the underground and fit well the measured data. These basic models allow a geophysical evaluation of different geological theories about the subsurface. Also, for a thorough interpretation field transformations (Euler, Curvature, and Derivatives) were calculated. These results led to new constraints for further interpretation of the basin structures and therefore they are important contributions for future exploration e.g. the planning of seismic surveys.

  8. An Exploration of Canadian Physiotherapists' Decisions about Whether to Supervise Physiotherapy Students: Results from a National Survey.

    Science.gov (United States)

    Hall, Mark; Poth, Cheryl; Manns, Patricia; Beaupre, Lauren

    2016-01-01

    Purpose: To explore Canadian physiotherapists' perceptions of the factors that influence their decisions whether to supervise students in clinical placements. Methods: Using accepted survey development methodology, a survey was developed and administered to 18,110 physiotherapists to identify which factors contribute to the decision to supervise students. The survey also gave respondents opportunities to provide comments; these were analyzed via directed content analysis, using the factors identified in an exploratory factor analysis as an organizing structure. Results: A representative sample of 3,148 physiotherapists responded to the survey. Qualitative analysis of respondent comments provided a rich understanding of the factors contributing to the decision on whether to supervise students, which centred on themes related to stress, workplace productivity, the evaluation instrument, student preparation, and physiotherapists' professional roles and responsibilities. Challenges specific to loss of income and the ethics of charging for student services in private practice were also identified. Conclusions: Supervising students can be stressful, and stress is perceived by respondents to be most influential in deciding whether to supervise students. Effective supervisor training may mitigate some of the stresses related to supervising students. A collaborative approach involving all stakeholders is needed to resolve the issues of student placement capacity.

  9. Exploring the brown dwarf desert: new substellar companions from the SDSS-III MARVELS survey

    Science.gov (United States)

    Grieves, Nolan; Ge, Jian; Thomas, Neil; Ma, Bo; Sithajan, Sirinrat; Ghezzi, Luan; Kimock, Ben; Willis, Kevin; De Lee, Nathan; Lee, Brian; Fleming, Scott W.; Agol, Eric; Troup, Nicholas; Paegert, Martin; Schneider, Donald P.; Stassun, Keivan; Varosi, Frank; Zhao, Bo; Jian, Liu; Li, Rui; Porto de Mello, Gustavo F.; Bizyaev, Dmitry; Pan, Kaike; Dutra-Ferreira, Letícia; Lorenzo-Oliveira, Diego; Santiago, Basílio X.; da Costa, Luiz N.; Maia, Marcio A. G.; Ogando, Ricardo L. C.; del Peloso, E. F.

    2017-06-01

    Planet searches using the radial velocity technique show a paucity of companions to solar-type stars within ˜5 au in the mass range of ˜10-80 MJup. This deficit, known as the brown dwarf desert, currently has no conclusive explanation. New substellar companions in this region help assess the reality of the desert and provide insight to the formation and evolution of these objects. Here, we present 10 new brown dwarf and 2 low-mass stellar companion candidates around solar-type stars from the Multi-object APO Radial Velocity Exoplanet Large-Area Survey (MARVELS) of the Sloan Digital Sky Survey III. These companions were selected from processed MARVELS data using the latest University of Florida Two Dimensional pipeline, which shows significant improvement and reduction of systematic errors over previous pipelines. The 10 brown dwarf companions range in mass from ˜13 to 76 MJup and have orbital radii of less than 1 au. The two stellar companions have minimum masses of ˜98 and 100 MJup. The host stars of the MARVELS brown dwarf sample have a mean metallicity of [Fe/H] = 0.03 ± 0.08 dex. Given our stellar sample we estimate the brown dwarf occurrence rate around solar-type stars with periods less than ˜300 d to be ˜0.56 per cent.

  10. Petrologic-geodynamic models of the geochemical evolution of the segmented Siqueiros transform fault (Invited)

    Science.gov (United States)

    Gregg, P. M.; Perfit, M. R.; Fornari, D. J.

    2013-12-01

    Recent investigations of the dynamics of fast-slipping oceanic transform faults have illustrated the highly transient nature of these systems. Rather than focusing deformation along single long-lived fault strands, many fast-slipping transform fault systems exhibit complex plate boundaries and tectonic histories. Along the fast-spreading East Pacific Rise (EPR) plate motion reorganizations have resulted in the segmentation of 8 of the 9 major transform fault systems. We focus our investigation on the Siqueiros transform fault, which has been the site of detailed surveying and sampling along its four intra-transform spreading centers (ITSCs) and connecting fault strands. The structural history of the Siqueiros transform fault is complex with several counterclockwise changes in spreading direction of the EPR causing transtension within the fault domain, resulting in the formation of four ITSCs at discrete time intervals. Geochemical analyses of lavas from the western portion of Siqueiros generally fit into a similar compositional space as the northern EPR ridge axis lavas, while lavas collected from the eastern Siqueiros appear more closely linked in composition to rocks from the adjacent EPR south of the transform. However, no systematic along-transform chemical gradient is observed and a few lavas collected along the eastern Siqueiros are more similar in composition to the northern EPR ridge segment. Furthermore, the only E-MORB from the transform domain were recovered from the western ridge-transform intersection. In contrast, some of the most incompatible depleted and primitive basalts erupted along one of the western fault strands. These geochemical observations suggest that the Siqueiros transform preserves small-scale mantle heterogeneities beneath the transform domain. We utilize time-dependent, three-dimensional petrologic-geodynamic models to investigate the chemical evolution of the mantle beneath the Siqueiros transform fault in response to changes in

  11. Survey of Potential Geothermal Exploration Sites at Newberry Volcano Deschutes County, Oregon.

    Energy Technology Data Exchange (ETDEWEB)

    Priest, George R.; Vogt, Beverly F.; Black, Gerald L.

    1983-01-01

    The study summarizes the current data, generates some new data, and recommends further steps which should be taken to investigate the electrical power production potential of Newberry volcano. The objective was to concentrate on data from the developable flanks of the volcano. All previous data on the geology, hydrology, and geophysics were summarized. A soil-mercury survey focused on the flanks of the volcano was conducted. Samples from 1000 km/sup 2/ of the volcano were analyzed for mercury content. All this information was utilized to evaluate (1) the likelihood of future discovery of electrical-quality geothermal fluids on the flanks, and (2) the most cost-effective means of improving the quality of available power generation estimates for the volcano. 37 figures.

  12. Extent, Awareness and Perception of Dissemination Bias in Qualitative Research: An Explorative Survey.

    Science.gov (United States)

    Toews, Ingrid; Glenton, Claire; Lewin, Simon; Berg, Rigmor C; Noyes, Jane; Booth, Andrew; Marusic, Ana; Malicki, Mario; Munthe-Kaas, Heather M; Meerpohl, Joerg J

    2016-01-01

    Qualitative research findings are increasingly used to inform decision-making. Research has indicated that not all quantitative research on the effects of interventions is disseminated or published. The extent to which qualitative researchers also systematically underreport or fail to publish certain types of research findings, and the impact this may have, has received little attention. A survey was delivered online to gather data regarding non-dissemination and dissemination bias in qualitative research. We invited relevant stakeholders through our professional networks, authors of qualitative research identified through a systematic literature search, and further via snowball sampling. 1032 people took part in the survey of whom 859 participants identified as researchers, 133 as editors and 682 as peer reviewers. 68.1% of the researchers said that they had conducted at least one qualitative study that they had not published in a peer-reviewed journal. The main reasons for non-dissemination were that a publication was still intended (35.7%), resource constraints (35.4%), and that the authors gave up after the paper was rejected by one or more journals (32.5%). A majority of the editors and peer reviewers "(strongly) agreed" that the main reasons for rejecting a manuscript of a qualitative study were inadequate study quality (59.5%; 68.5%) and inadequate reporting quality (59.1%; 57.5%). Of 800 respondents, 83.1% "(strongly) agreed" that non-dissemination and possible resulting dissemination bias might undermine the willingness of funders to support qualitative research. 72.6% and 71.2%, respectively, "(strongly) agreed" that non-dissemination might lead to inappropriate health policy and health care. The proportion of non-dissemination in qualitative research is substantial. Researchers, editors and peer reviewers play an important role in this. Non-dissemination and resulting dissemination bias may impact on health care research, practice and policy. More

  13. NOAA and MMS Marine Minerals Geochemical Database

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The Marine Minerals Geochemical Database was created by NGDC as a part of a project to construct a comprehensive computerized bibliography and geochemical database...

  14. Geochemical and mineralogical data for soils of the conterminous United States

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — In 2007, the U.S. Geological Survey began a low-density (1 site per 1,600 sq. km., 4857 sites) geochemical and mineralogical survey of soils of the conterminous...

  15. The Photogrammetric Survey Methodologies Applied to Low Cost 3d Virtual Exploration in Multidisciplinary Field

    Science.gov (United States)

    Palestini, C.; Basso, A.

    2017-11-01

    In recent years, an increase in international investment in hardware and software technology to support programs that adopt algorithms for photomodeling or data management from laser scanners significantly reduced the costs of operations in support of Augmented Reality and Virtual Reality, designed to generate real-time explorable digital environments integrated to virtual stereoscopic headset. The research analyzes transversal methodologies related to the acquisition of these technologies in order to intervene directly on the phenomenon of acquiring the current VR tools within a specific workflow, in light of any issues related to the intensive use of such devices , outlining a quick overview of the possible "virtual migration" phenomenon, assuming a possible integration with the new internet hyper-speed systems, capable of triggering a massive cyberspace colonization process that paradoxically would also affect the everyday life and more in general, on human space perception. The contribution aims at analyzing the application systems used for low cost 3d photogrammetry by means of a precise pipeline, clarifying how a 3d model is generated, automatically retopologized, textured by color painting or photo-cloning techniques, and optimized for parametric insertion on virtual exploration platforms. Workflow analysis will follow some case studies related to photomodeling, digital retopology and "virtual 3d transfer" of some small archaeological artifacts and an architectural compartment corresponding to the pronaus of Aurum, a building designed in the 1940s by Michelucci. All operations will be conducted on cheap or free licensed software that today offer almost the same performance as their paid counterparts, progressively improving in the data processing speed and management.

  16. THE PHOTOGRAMMETRIC SURVEY METHODOLOGIES APPLIED TO LOW COST 3D VIRTUAL EXPLORATION IN MULTIDISCIPLINARY FIELD

    Directory of Open Access Journals (Sweden)

    C. Palestini

    2017-11-01

    Full Text Available In recent years, an increase in international investment in hardware and software technology to support programs that adopt algorithms for photomodeling or data management from laser scanners significantly reduced the costs of operations in support of Augmented Reality and Virtual Reality, designed to generate real-time explorable digital environments integrated to virtual stereoscopic headset. The research analyzes transversal methodologies related to the acquisition of these technologies in order to intervene directly on the phenomenon of acquiring the current VR tools within a specific workflow, in light of any issues related to the intensive use of such devices , outlining a quick overview of the possible "virtual migration" phenomenon, assuming a possible integration with the new internet hyper-speed systems, capable of triggering a massive cyberspace colonization process that paradoxically would also affect the everyday life and more in general, on human space perception. The contribution aims at analyzing the application systems used for low cost 3d photogrammetry by means of a precise pipeline, clarifying how a 3d model is generated, automatically retopologized, textured by color painting or photo-cloning techniques, and optimized for parametric insertion on virtual exploration platforms. Workflow analysis will follow some case studies related to photomodeling, digital retopology and "virtual 3d transfer" of some small archaeological artifacts and an architectural compartment corresponding to the pronaus of Aurum, a building designed in the 1940s by Michelucci. All operations will be conducted on cheap or free licensed software that today offer almost the same performance as their paid counterparts, progressively improving in the data processing speed and management.

  17. The Gaia-ESO Survey: Exploring the complex nature and origins of the Galactic bulge populations

    Science.gov (United States)

    Rojas-Arriagada, A.; Recio-Blanco, A.; de Laverny, P.; Mikolaitis, Š.; Matteucci, F.; Spitoni, E.; Schultheis, M.; Hayden, M.; Hill, V.; Zoccali, M.; Minniti, D.; Gonzalez, O. A.; Gilmore, G.; Randich, S.; Feltzing, S.; Alfaro, E. J.; Babusiaux, C.; Bensby, T.; Bragaglia, A.; Flaccomio, E.; Koposov, S. E.; Pancino, E.; Bayo, A.; Carraro, G.; Casey, A. R.; Costado, M. T.; Damiani, F.; Donati, P.; Franciosini, E.; Hourihane, A.; Jofré, P.; Lardo, C.; Lewis, J.; Lind, K.; Magrini, L.; Morbidelli, L.; Sacco, G. G.; Worley, C. C.; Zaggia, S.

    2017-05-01

    Context. As observational evidence steadily accumulates, the nature of the Galactic bulge has proven to be rather complex: the structural, kinematic, and chemical analyses often lead to contradictory conclusions. The nature of the metal-rich bulge - and especially of the metal-poor bulge - and their relation with other Galactic components, still need to be firmly defined on the basis of statistically significant high-quality data samples. Aims: We used the fourth internal data release of the Gaia-ESO survey to characterize the bulge metallicity distribution function (MDF), magnesium abundance, spatial distribution, and correlation of these properties with kinematics. Moreover, the homogeneous sampling of the different Galactic populations provided by the Gaia-ESO survey allowed us to perform a comparison between the bulge, thin disk, and thick disk sequences in the [Mg/Fe] vs. [Fe/H] plane in order to constrain the extent of their eventual chemical similarities. Methods: We obtained spectroscopic data for 2500 red clump stars in 11 bulge fields, sampling the area -10° ≤ l ≤ + 8° and -10° ≤ b ≤ -4° from the fourth internal data release of the Gaia-ESO survey. A sample of 6300 disk stars was also selected for comparison. Spectrophotometric distances computed via isochrone fitting allowed us to define a sample of stars likely located in the bulge region. Results: From a Gaussian mixture models (GMM) analysis, the bulge MDF is confirmed to be bimodal across the whole sampled area. The relative ratio between the two modes of the MDF changes as a function of b, with metal-poor stars dominating at high latitudes. The metal-rich stars exhibit bar-like kinematics and display a bimodality in their magnitude distribution, a feature which is tightly associated with the X-shape bulge. They overlap with the metal-rich end of the thin disk sequence in the [Mg/Fe] vs. [Fe/H] plane. On the other hand, metal-poor bulge stars have a more isotropic hot kinematics and do

  18. ESO Diffuse Interstellar Bands Large Exploration Survey (EDIBLES) - Merging Observations and Laboratory Data

    Science.gov (United States)

    Salama, Farid

    2016-01-01

    laboratory facilities, MIS and COSmIC, that have been developed for this study and discuss the findings resulting from the comparison of the laboratory data with high resolution, high S/N ratio astronomical observations. MIS stands for Matrix Isolation Spectroscopy, a well-proven technique for isolating cold molecular species in inert solid environments. COSmIC stands for Cosmic Simulation Chamber. It combines a supersonic free jet expansion with discharge plasma and high-sensitivity cavity ringdown spectroscopy and time-of-flight mass spectrometry detection tools for the generation and the detection of cold, isolated gas-phase molecules and ions under experimental conditions that closely mimic interstellar conditions. The column densities of the individual neutral PAH molecules and ions probed in these surveys are derived from the comparison of these unique laboratory data with high resolution, high S/N ratio astronomical observations. The comparisons of astronomical and laboratory data lead to clear and unambiguous conclusions regarding the expected abundances for PAHs of various sizes and charge states in the interstellar environments probed in the surveys. Band profile comparisons between laboratory and astronomical spectra lead to information regarding the molecular structures and characteristics associated with the DIB carriers in the corresponding lines-of-sight. These quantitative surveys of neutral and ionized PAHs in the optical range open the way for unambiguous quantitative searches of PAHs and complex organics in a variety of interstellar and circumstellar environments.

  19. Geochemical signature of radioactive waste: oil NORM

    Energy Technology Data Exchange (ETDEWEB)

    Costa, Gilberto T. de Paula; Costa-de-Moura, Jorge; Gomes, Carlos de Almeida; Sampaio, Emidio A. Lopes, E-mail: gilberto.costa@cnen.gov.br, E-mail: jcmoura@cnen.gov.br, E-mail: cgomes@cnen.gov.br [Comissao Nacional de Energia Nuclear (CNEN), Rio de Janeiro, RJ (Brazil). Div. de Controle de Rejeitos e Transporte de Materiais Radioativos

    2017-07-01

    The Brazilian Nuclear Agency (CNEN) rules all nuclear activity in Brazil as demanded by the Federal Constitution, articles 21, XXIII, and 177, V, and by the Federal Acts 4.118/62 and 10.308/2001. Therefore, the CNEN is responsible for any radioactive waste disposal in the country. Oil Naturally Occurring Radioactive Materials (Oil NORM) in this paper refers to waste coming from oil exploration. Oil NORM has called much attention during the last decades, mostly because it is not possible to determine its primary source due to the actual absence of regulatory control mechanism. There is no efficient regulatory tool which allows determining the origin of such NORM wastes even among those facilities under regulatory control. This fact may encourage non-authorized radioactive material transportation, smuggling and terrorism. The aim of this project is to provide a geochemical signature for each oil NORM waste using its naturally occurring isotopic composition to identify its origin. The here proposed method is a specific geochemical modeling of oil sludge NORM samples which are analyzed for radioisotopes normally present in oil pipes, such as {sup 228}Ac, {sup 214}Bi and {sup 214}Pb. The activity ratios are plotted in scatter diagrams. This method was successfully tested with data of different sources obtained from analysis reports from the Campos Basin/Brazil and from literature. (author)

  20. Sustainable employability for older workers: an explorative survey of belgian companies.

    Science.gov (United States)

    Verbrugghe, Mathieu; Kuipers, Yoline; Vriesacker, Bart; Peeters, Ilse; Mortelmans, Katrien

    2016-01-01

    The European Agency for Safety and Health at Work (EU-OSHA) is developing an online e-guide, which will provide tips and practical information for each EU country (in their national language(s)) on ageing and occupational health and safety. The e-guide will be launched in 2016 as part of the EU-OSHA campaign on Healthy Workplaces for all ages. The e-guide will present evidence, tools and practical examples of how companies can take action and effectively promote sustainable employability. As part of the development of the e-guide, a cross-sectional study was conducted to survey Belgian employers in April 2015 to determine their specific needs concerning older workers' occupational health and safety issues. Researchers from Milieu Ltd. (Brussels, Belgium), the consultancy company coordinating the e-guide project, and Mensura Occupational Health Services (Brussels, Belgium) developed a 13-item questionnaire. The survey addressed the needs and importance given to sustainable employability of older workers in Belgian companies and evaluated corporate knowledge regarding relevant national policies. The questionnaire was distributed electronically to the management of 22,084 private-sector companies affiliated with Mensura. Ten percent (n = 2133) of recipients opened the e-mail, and 37 % (n = 790) of these completed the questionnaire. In 89 % of the responding companies, sustainable employability of workers aged ≥55 years plays an important role; 70 % have no active sustainable employability policy/initiative; 18 % experience difficulties promoting sustainable employability; and 86 % indicate no need for support to promote sustainable employability. Respondents noted the following health complaints among workers aged ≥55 years: work-related health problems (31 %), stress (26 %), work agreements/type of work (17 %), work/life balance (15 %), and career development and/or training (9 %). Topics concerning health and well-being of workers aged ≥55

  1. Exploring improvements in patient logistics in Dutch hospitals with a survey

    Directory of Open Access Journals (Sweden)

    van Lent Wineke AM

    2012-08-01

    Full Text Available Abstract Background Research showed that promising approaches such as benchmarking, operations research, lean management and six sigma, could be adopted to improve patient logistics in healthcare. To our knowledge, little research has been conducted to obtain an overview on the use, combination and effects of approaches to improve patient logistics in hospitals. We therefore examined the approaches and tools used to improve patient logistics in Dutch hospitals, the reported effects of these approaches on performance, the applied support structure and the methods used to evaluate the effects. Methods A survey among experts on patient logistics in 94 Dutch hospitals. The survey data were analysed using cross tables. Results Forty-eight percent of all hospitals participated. Ninety-eight percent reported to have used multiple approaches, 39% of them used five or more approaches. Care pathways were the preferred approach by 43% of the hospitals, followed by business process re-engineering and lean six sigma (both 13%. Flowcharts were the most commonly used tool, they were used on a regular basis by 94% of the hospitals. Less than 10% of the hospitals used data envelopment analysis and critical path analysis on a regular basis. Most hospitals (68% relied on external support for process analyses and education on patient logistics, only 24% had permanent internal training programs on patient logistics. Approximately 50% of the hospitals that evaluated the effects of approaches on efficiency, throughput times and financial results, reported that they had accomplished their goals. Goal accomplishment in general hospitals ranged from 63% to 67%, in academic teaching hospitals from 0% to 50%, and in teaching hospitals from 25% to 44%. More than 86% performed an evaluation, 53% performed a post-intervention measurement. Conclusions Patient logistics appeared to be a rather new subject as most hospitals had not selected a single approach, they relied on

  2. Extent, Awareness and Perception of Dissemination Bias in Qualitative Research: An Explorative Survey.

    Directory of Open Access Journals (Sweden)

    Ingrid Toews

    Full Text Available Qualitative research findings are increasingly used to inform decision-making. Research has indicated that not all quantitative research on the effects of interventions is disseminated or published. The extent to which qualitative researchers also systematically underreport or fail to publish certain types of research findings, and the impact this may have, has received little attention.A survey was delivered online to gather data regarding non-dissemination and dissemination bias in qualitative research. We invited relevant stakeholders through our professional networks, authors of qualitative research identified through a systematic literature search, and further via snowball sampling.1032 people took part in the survey of whom 859 participants identified as researchers, 133 as editors and 682 as peer reviewers. 68.1% of the researchers said that they had conducted at least one qualitative study that they had not published in a peer-reviewed journal. The main reasons for non-dissemination were that a publication was still intended (35.7%, resource constraints (35.4%, and that the authors gave up after the paper was rejected by one or more journals (32.5%. A majority of the editors and peer reviewers "(strongly agreed" that the main reasons for rejecting a manuscript of a qualitative study were inadequate study quality (59.5%; 68.5% and inadequate reporting quality (59.1%; 57.5%. Of 800 respondents, 83.1% "(strongly agreed" that non-dissemination and possible resulting dissemination bias might undermine the willingness of funders to support qualitative research. 72.6% and 71.2%, respectively, "(strongly agreed" that non-dissemination might lead to inappropriate health policy and health care.The proportion of non-dissemination in qualitative research is substantial. Researchers, editors and peer reviewers play an important role in this. Non-dissemination and resulting dissemination bias may impact on health care research, practice and policy

  3. Exploring improvements in patient logistics in Dutch hospitals with a survey

    Science.gov (United States)

    2012-01-01

    Background Research showed that promising approaches such as benchmarking, operations research, lean management and six sigma, could be adopted to improve patient logistics in healthcare. To our knowledge, little research has been conducted to obtain an overview on the use, combination and effects of approaches to improve patient logistics in hospitals. We therefore examined the approaches and tools used to improve patient logistics in Dutch hospitals, the reported effects of these approaches on performance, the applied support structure and the methods used to evaluate the effects. Methods A survey among experts on patient logistics in 94 Dutch hospitals. The survey data were analysed using cross tables. Results Forty-eight percent of all hospitals participated. Ninety-eight percent reported to have used multiple approaches, 39% of them used five or more approaches. Care pathways were the preferred approach by 43% of the hospitals, followed by business process re-engineering and lean six sigma (both 13%). Flowcharts were the most commonly used tool, they were used on a regular basis by 94% of the hospitals. Less than 10% of the hospitals used data envelopment analysis and critical path analysis on a regular basis. Most hospitals (68%) relied on external support for process analyses and education on patient logistics, only 24% had permanent internal training programs on patient logistics. Approximately 50% of the hospitals that evaluated the effects of approaches on efficiency, throughput times and financial results, reported that they had accomplished their goals. Goal accomplishment in general hospitals ranged from 63% to 67%, in academic teaching hospitals from 0% to 50%, and in teaching hospitals from 25% to 44%. More than 86% performed an evaluation, 53% performed a post-intervention measurement. Conclusions Patient logistics appeared to be a rather new subject as most hospitals had not selected a single approach, they relied on external support and they did

  4. Geomagnetic Survey to Explore High-Temperature Geothermal System in Blawan-Ijen, East Java, Indonesia

    Directory of Open Access Journals (Sweden)

    Daud Yunus

    2018-01-01

    Full Text Available Ijen geothermal area is high-temperature geothermal system located in Bondowoso regency, East Java. It is categorized as caldera-hosted geothermal system which is covered by quaternary andesitic volcanic rocks with steep topography at the surrounding. Several surface thermal manifestations are found, such as altered rocks near Mt. Kukusan and a group of Blawan hotsprings in the northern part of the caldera. Geomagnetic survey was conducted at 72 stations which is distributed inside the caldera to delineate the existence of hydrothermal activity. Magnetic anomaly was obtained by reducing total magnetic measured on the field by IGRF and diurnal variation. Reduction to pole (RTP method was applied with geomagnetic inclination of about -32°. In general, the result shows that high magnetic anomaly is distributed at the boundary of study area, while low magnetic anomaly is observed in the centre. The low anomaly indicates demagnetized rock that probably caused by hydrothermal activity. It has a good correlation with surface alteration observed close to Mt. Kukusan as well as high temperature reservoir drilled in the centre of caldera. Accordingly, the low magnetic anomaly also presents the possibility of geothermal reservoir in Ijen geothermal area.

  5. What teachers think about inclusion. Data from a large-scale explorative survey

    Directory of Open Access Journals (Sweden)

    Nicoletta Di Blas

    2014-06-01

    Full Text Available Inclusion is high on the agenda of school systems around the world. But what does “inclusion” mean? Do teachers really know what it is? Do they know what strategies to use in order to achieve it? This paper investigates some of the “myths” about this issue, highlighting that teachers are often in contradictory in what they state and what they actually do. Group-work is a typical inclusive strategy, yet often times disguises the weaker contributions of lower performing students while giving the impression that “everyone is taking part.” Peer-to-peer learning may be useful for the lower performing students but may also not add much to the best ones. Using the results from a survey of 258 respondents, including all teachers on the job, from all school grades, this paper provides useful findings in this regard. Additional considerations come from the authors’ experience with a three-year long national project about educational experiences and inclusion, called Learning4All - www.learningforall.it. This involved more than 250 teachers being interviewed in detail. The paper presents what teachers think and say about inclusion, what they do in the class and what they get, in terms of benefits, from the students.

  6. Geomagnetic Survey to Explore High-Temperature Geothermal System in Blawan-Ijen, East Java, Indonesia

    Science.gov (United States)

    Daud, Yunus; Rosid, Syamsu; Fahmi, Fikri; Yunus, Faris Maulana; Muflihendri, Reza

    2018-02-01

    Ijen geothermal area is high-temperature geothermal system located in Bondowoso regency, East Java. It is categorized as caldera-hosted geothermal system which is covered by quaternary andesitic volcanic rocks with steep topography at the surrounding. Several surface thermal manifestations are found, such as altered rocks near Mt. Kukusan and a group of Blawan hotsprings in the northern part of the caldera. Geomagnetic survey was conducted at 72 stations which is distributed inside the caldera to delineate the existence of hydrothermal activity. Magnetic anomaly was obtained by reducing total magnetic measured on the field by IGRF and diurnal variation. Reduction to pole (RTP) method was applied with geomagnetic inclination of about -32°. In general, the result shows that high magnetic anomaly is distributed at the boundary of study area, while low magnetic anomaly is observed in the centre. The low anomaly indicates demagnetized rock that probably caused by hydrothermal activity. It has a good correlation with surface alteration observed close to Mt. Kukusan as well as high temperature reservoir drilled in the centre of caldera. Accordingly, the low magnetic anomaly also presents the possibility of geothermal reservoir in Ijen geothermal area.

  7. Subaru High-z Exploration of Low-Luminosity Quasars (SHELLQs): New z > 6 Quasar Survey with Subaru/HSC

    Science.gov (United States)

    Matsuoka, Yoshiki; SHELLQs Collaboration

    2017-01-01

    Quasars at high redshift are an important and unique probe of the distant Universe, for understanding the origin and progress of cosmic reionization, the early growth of supermassive black holes, and the evolution of quasar host galaxies and their dark matter halos, among other topics. We are currently carrying out a new spectroscopic survey, called SHELLQs (Subaru High-z Exploration of Low-Luminosity Quasars), to search for low-luminosity quasars at z > 6. By exploiting the exquisite imaging data produced by the Subaru Hyper Suprime-Cam (HSC) survey, we aim to probe quasar luminosities down to M1450 ~ -22 mag, i.e., below the classical threshold between quasars and Seyfert galaxies. Candidate selection is performed by combining several photometric approaches including a Bayesian probabilistic algorithm. A large spectroscopic observing program is underway, using Subaru/FOCAS, GTC/OSIRIS, and Gemini/GMOS; in particular, SHELLQs has been approved as a Subaru intensive program to use 20 nights in the coming four semesters. As of August 2016, we have discovered ~40 quasars and bright galaxies at z ~ 6 and beyond, from the first 100 deg2 of the HSC survey (Matsuoka et al. 2016, ApJ, 828, 26). Surprisingly, we are starting to see the steep rise of the luminosity function of high-z galaxies, compared with that of quasars, at magnitudes fainter than M1450 ~ -22 mag or zAB ~ 24 mag. Multi-wavelength follow-up studies of the discovered objects as well as further survey observations are ongoing.

  8. Exploring the Evolution of Star Formation and Dwarf Galaxy Properties with JWST /MIRI Serendipitous Spectroscopic Surveys

    Energy Technology Data Exchange (ETDEWEB)

    Bonato, Matteo; Sajina, Anna; McKinney, Jed; Marchesini, Danilo; Roebuck, Eric; Shipley, Heath [Department of Physics and Astronomy, Tufts University, 574 Boston Avenue, Medford, MA (United States); Zotti, Gianfranco De [INAF, Osservatorio Astronomico di Padova, Vicolo Osservatorio 5, I-35122 Padova (Italy); Baronchelli, Ivano; Yan, Lin [California Institute of Technology, Pasadena, CA (United States); Negrello, Mattia [School of Physics and Astronomy, Cardiff University, Queens Buildings, The Parade, Cardiff CF24 3AA (United Kingdom); Kurinsky, Noah [Department of Physics, Stanford University, Stanford, CA (United States); Pope, Alexandra [Department of Astronomy, University of Massachusetts Amherst, Amherst, MA (United States); Noriega-Crespo, Alberto [Space Telescope Science Institute, 3700 San Martin Drive, Baltimore, MD (United States); Kirkpatrick, Allison [Department of Astronomy, Yale University, New Haven, CT (United States)

    2017-02-20

    The James Webb Space Telescope ’s Medium Resolution Spectrometer (MRS), will offer nearly two orders of magnitude improvement in sensitivity and >3× improvement in spectral resolution over our previous space-based mid-IR spectrometer, the Spitzer IRS. In this paper, we make predictions for spectroscopic pointed observations and serendipitous detections with the MRS. Specifically, pointed observations of Herschel sources require only a few minutes on source integration for detections of several star-forming and active galactic nucleus lines, out to z = 3 and beyond. But the same data will also include tens of serendipitous 0 ≲ z ≲ 4 galaxies per field with infrared luminosities ranging ∼10{sup 6}–10{sup 13} L {sub ☉}. In particular, for the first time and for free we will be able to explore the L {sub IR} < 10{sup 9} L {sub ☉} regime out to z ∼ 3. We estimate that with ∼ 100 such fields, statistics of these detections will be sufficient to constrain the evolution of the low- L end of the infrared luminosity function, and hence the star formation rate function. The above conclusions hold for a wide range in the potential low- L end of the IR luminosity function, and account for the PAH deficit in low- L , low-metallicity galaxies.

  9. When doctors marry doctors: a survey exploring the professional and family lives of young physicians.

    Science.gov (United States)

    Sobecks, N W; Justice, A C; Hinze, S; Chirayath, H T; Lasek, R J; Chren, M M; Aucott, J; Juknialis, B; Fortinsky, R; Youngner, S; Landefeld, C S

    1999-02-16

    Soon, half of all physicians may be married to other physicians (that is, in dual-doctor families). Little is known about how marriage to another physician affects physicians themselves. To learn how physicians in dual-doctor families differ from other physicians in their professional and family lives and in their perceptions of career and family. Cross-sectional survey. Two medical schools in Ohio. A random sample of physicians from the classes of 1980 to 1990. Responses to a questionnaire on hours worked, income, number of children, child-rearing arrangements, and perceptions about work and family. Of 2000 eligible physicians, 1208 responded (752 men and 456 women). Twenty-two percent of male physicians and 44% of female physicians were married to physicians (P families differed (P family lives: They earned less money, less often felt that their career took precedence over their spouse's career, and more often played a major role in child-rearing. These differences were greater for female physicians than for male physicians. Men and women in dual-doctor families were similar to other physicians in the frequency with which they achieved career goals and goals for their children and with which they felt conflict between professional and family roles. Marriage to another physician had distinct benefits (P family incomes. Men and women in dual-doctor families differed from other physicians in many aspects of their professional and family lives, but they achieved their career and family goals as frequently. These differences reflect personal choices that will increasingly affect the profession as more physicians marry physicians.

  10. FY 1998 report on the basic survey for coal resource development (Summary). New exploration technology survey and development (land area shallow seam exploration); 1998 nendo sekitan shigen kaihatsu kiso chosa hokokusho. Shintansa gijutsu chosa kaihatsu (rikuiki senso tansa)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    The paper described the FY 1998 results of the development of new exploration technology of coal resource. The detailed design was made based on the conceptual design of a high accuracy 3D geological modeling system in the FY 1997 equipment development. The expression of the reverse fault, excess folding, etc., which has been difficult, became possible, and high-level visualization of the geological model made became possible. The prototype model in Caroona district as survey field is easy of expression of fault, folding, etc. By the increase of data on test boring, made clear were geological characteristics of this area, especially the complicated geological state of Black Jack Formation groups of the coal-bearing formation. In explaining the reflection section, after roughly identifying 5 horizons from features of the total reflection patterns, reflection waves were explained from specified reflected waves, that is, the base of the Quaternary, the top of the Doona coal seam group, the base of the Clift coal seam group, and the top of the Hoskissons coal seam. By adopting the S-wave reflection method which is effective in converting in-situ numerical values such as the rock-mass related elastic modulus, compressive strength and rigidity ratio, an outlook for getting data of good quality was obtained in VSP survey. (NEDO)

  11. Physicians' characteristics associated with exploring suicide risk among patients with depression: a French panel survey of general practitioners.

    Directory of Open Access Journals (Sweden)

    Aurélie Bocquier

    Full Text Available BACKGROUND: General practitioners (GPs have a key role to play in suicide prevention, but the rates at which they question patients with depression about suicidal thoughts and plans are rather low. Little is known about GPs' characteristics associated with such inquiries. Our objectives were to describe GPs' attitudes, perceived barriers, and self-reported practices in this questioning of these patients and to analyze factors associated with these practices. METHODOLOGY: This cross-sectional survey was conducted among participants in a panel of randomly selected French GPs (1249/1431 participated: 87.3%. GPs were interviewed with a standardized questionnaire covering their professional and personal characteristics, attitudes, and practices in exploring the suicide risk of their patients with depression. We built a suicide inquiry score by summing the responses to 5 items and used a multiple linear regression analysis to explore the characteristics associated with this score. PRINCIPAL FINDINGS: Most GPs reported inquiring about the presence of suicidal ideation often or very often; less than 30% reported that they frequently explored signs of a specific suicide plan. The mean suicide inquiry score was 12.4 (SD, 2.9; range, 5-20. False ideas, such as thinking that patients who report suicidal ideas do not often commit suicide, were frequent (42.3%. Previous continuing medical education on suicide, participation in a formal mental health network, and patients who committed suicide in the past 5 years were associated with a higher score. Reluctance to question patients about suicide and perception of insufficient skill were associated with a lower score. CONCLUSIONS/SIGNIFICANCE: This study showed great variability in French GPs' practices in exploring suicide risk in patients with depression. Interventions aiming at improving GPs' initial training and continuing medical education in suicide and/or depression, and their collaboration with mental

  12. Physicians' characteristics associated with exploring suicide risk among patients with depression: a French panel survey of general practitioners.

    Science.gov (United States)

    Bocquier, Aurélie; Pambrun, Elodie; Dumesnil, Hélène; Villani, Patrick; Verdoux, Hélène; Verger, Pierre

    2013-01-01

    General practitioners (GPs) have a key role to play in suicide prevention, but the rates at which they question patients with depression about suicidal thoughts and plans are rather low. Little is known about GPs' characteristics associated with such inquiries. Our objectives were to describe GPs' attitudes, perceived barriers, and self-reported practices in this questioning of these patients and to analyze factors associated with these practices. This cross-sectional survey was conducted among participants in a panel of randomly selected French GPs (1249/1431 participated: 87.3%). GPs were interviewed with a standardized questionnaire covering their professional and personal characteristics, attitudes, and practices in exploring the suicide risk of their patients with depression. We built a suicide inquiry score by summing the responses to 5 items and used a multiple linear regression analysis to explore the characteristics associated with this score. Most GPs reported inquiring about the presence of suicidal ideation often or very often; less than 30% reported that they frequently explored signs of a specific suicide plan. The mean suicide inquiry score was 12.4 (SD, 2.9; range, 5-20). False ideas, such as thinking that patients who report suicidal ideas do not often commit suicide, were frequent (42.3%). Previous continuing medical education on suicide, participation in a formal mental health network, and patients who committed suicide in the past 5 years were associated with a higher score. Reluctance to question patients about suicide and perception of insufficient skill were associated with a lower score. This study showed great variability in French GPs' practices in exploring suicide risk in patients with depression. Interventions aiming at improving GPs' initial training and continuing medical education in suicide and/or depression, and their collaboration with mental health specialists should be developed, and their impacts assessed.

  13. A survey exploring the knowledge and perceptions of senior medical students in Nepal toward generic medicines

    Directory of Open Access Journals (Sweden)

    Sudesh Gyawali

    2016-08-01

    Full Text Available Background: The accurate knowledge of generic medicine issues among future prescribers will enhance the prescribing of cost-effective medicines. This study aimed to explore the knowledge and perception of senior medical students about the generic medicines. Methodology: A cross-sectional study was conducted among 237 senior medical students (final year students and interns using a validated self-administered questionnaire. The collected data were analyzed using Statistical Package for the Social Sciences version 20 for windows and comparison of difference was done using linear by linear association. A p value of less than 0.05 was taken as statistically significant. Results: The average age (standard deviation of the respondents was 23.54 (1.39 years. Almost 5% of respondents correctly answered the question regarding the regulatory limits for bioequivalence. Almost two-thirds of respondents correctly agreed that generic medicine is bioequivalent to a brand-name medicine, and 79.3% and 72.5% of respondents correctly agreed that the medicine should be present in the same dosage form and same dose, respectively, as the brand-name medicines. However, almost half of the respondents had impression that brand-name medicines are required to meet higher safety standard than generic medicines. Almost 90% of respondents felt that advertisement by the drug companies would influence the use of brand-name medicine and they need more information about generic medicine. Conclusion: This study highlights the negative perception and knowledge deficit among the respondents. The students’ responses to almost all the statements were almost similar to the respondents’ academic year (final year students and interns, gender and nationality.

  14. A survey exploring the knowledge and perceptions of senior medical students in Nepal toward generic medicines.

    Science.gov (United States)

    Gyawali, Sudesh; Hassali, Mohamed Azmi; Saha, Archana

    2016-01-01

    The accurate knowledge of generic medicine issues among future prescribers will enhance the prescribing of cost-effective medicines. This study aimed to explore the knowledge and perception of senior medical students about the generic medicines. A cross-sectional study was conducted among 237 senior medical students (final year students and interns) using a validated self-administered questionnaire. The collected data were analyzed using Statistical Package for the Social Sciences version 20 for windows and comparison of difference was done using linear by linear association. A p value of less than 0.05 was taken as statistically significant. The average age (standard deviation) of the respondents was 23.54 (1.39) years. Almost 5% of respondents correctly answered the question regarding the regulatory limits for bioequivalence. Almost two-thirds of respondents correctly agreed that generic medicine is bioequivalent to a brand-name medicine, and 79.3% and 72.5% of respondents correctly agreed that the medicine should be present in the same dosage form and same dose, respectively, as the brand-name medicines. However, almost half of the respondents had impression that brand-name medicines are required to meet higher safety standard than generic medicines. Almost 90% of respondents felt that advertisement by the drug companies would influence the use of brand-name medicine and they need more information about generic medicine. This study highlights the negative perception and knowledge deficit among the respondents. The students' responses to almost all the statements were almost similar to the respondents' academic year (final year students and interns), gender and nationality.

  15. Exploring the gender gap in the conceptual survey of electricity and magnetism

    Science.gov (United States)

    Henderson, Rachel; Stewart, Gay; Stewart, John; Michaluk, Lynnette; Traxler, Adrienne

    2017-12-01

    The "gender gap" on various physics conceptual evaluations has been extensively studied. Men's average pretest scores on the Force Concept Inventory and Force and Motion Conceptual Evaluation are 13% higher than women's, and post-test scores are on average 12% higher than women's. This study analyzed the gender differences within the Conceptual Survey of Electricity and Magnetism (CSEM) in which the gender gap has been less well studied and is less consistent. In the current study, data collected from 1407 students (77% men, 23% women) in a calculus-based physics course over ten semesters showed that male students outperformed female students on the CSEM pretest (5%) and post-test (6%). Separate analyses were conducted for qualitative and quantitative problems on lab quizzes and course exams and showed that male students outperformed female students by 3% on qualitative quiz and exam problems. Male and female students performed equally on the quantitative course exam problems. The gender gaps within CSEM post-test scores, qualitative lab quiz scores, and qualitative exam scores were insignificant for students with a CSEM pretest score of 25% or less but grew as pretest scores increased. Structural equation modeling demonstrated that a latent variable, called Conceptual Physics Performance/Non-Quantitative (CPP/NonQnt), orthogonal to quantitative test performance was useful in explaining the differences observed in qualitative performance; this variable was most strongly related to CSEM post-test scores. The CPP/NonQnt of male students was 0.44 standard deviations higher than female students. The CSEM pretest measured CPP/NonQnt much less accurately for women (R2=4 % ) than for men (R2=17 % ). The failure to detect a gender gap for students scoring 25% or less on the pretest suggests that the CSEM instrument itself is not gender biased. The failure to find a performance difference in quantitative test performance while detecting a gap in qualitative performance

  16. The CALIFA Survey: Exploring the Oxygen Abundance in the Local Universe

    Directory of Open Access Journals (Sweden)

    Sebastian F. Sánchez

    2015-11-01

    Full Text Available We present here a review of the latest results on the spatially-resolved analysis of the stellar populations and ionized gas of disk-dominated galaxies based on Calar Alto Legacy Integral Field Area (CALIFA data. CALIFA is an ongoing integral field spectroscopy (IFS survey of galaxies in the Local Universe (0.005 < z < 0.03 that has already obtained spectroscopic information up to \\(\\sim\\2.5 \\(r_e\\ with a spatial resolution better than \\(\\sim\\1 kpc for a total number of more than 600 galaxies of different morphological types, covering the color-magnitude diagram up to M\\(_{\\rm R}<-\\18 mag. With nearly 2000 spectra obtained for each galaxy, CALIFA offers one of the best IFU datasets to study the star formation histories and chemical enrichment of galaxies. In this article, we focus on the main results from the analysis of the oxygen abundances based on the study of ionized gas in H II regions and individual spaxels and their relation to the global properties of galaxies, using an updated/revised dataset with more galaxies and ionized regions. In summary, we have confirmed previous published results indicating that: (1 the M-Z relation does not present a secondary relation to the star formation rate, when the abundance is measured at the effective radius; (2 the oxygen abundance presents a strong correlation with the stellar surface density (∑-Z relation; (3 the oxygen abundance profiles present three well-defined regimes: (i an overall negative radial gradient between 0.5 and 2 \\(r_e\\, with a characteristic slope of \\(\\alpha_{O/H}\\ \\(\\sim\\\\(-\\0.1 dex/\\(r_e\\; (ii a universal flattening beyond \\(>\\2 \\(r_e\\; and (iii an inner drop at \\(<\\0.5 \\(r_e\\ that depends on mass; (4 the presence of bending in the surface brightness profile of disk galaxies is not clearly related to either the change in the shape of the oxygen abundance profile or the properties of the underlying stellar population. All of these results

  17. Exploring the gender gap in the conceptual survey of electricity and magnetism

    Directory of Open Access Journals (Sweden)

    Rachel Henderson

    2017-09-01

    Full Text Available The “gender gap” on various physics conceptual evaluations has been extensively studied. Men’s average pretest scores on the Force Concept Inventory and Force and Motion Conceptual Evaluation are 13% higher than women’s, and post-test scores are on average 12% higher than women’s. This study analyzed the gender differences within the Conceptual Survey of Electricity and Magnetism (CSEM in which the gender gap has been less well studied and is less consistent. In the current study, data collected from 1407 students (77% men, 23% women in a calculus-based physics course over ten semesters showed that male students outperformed female students on the CSEM pretest (5% and post-test (6%. Separate analyses were conducted for qualitative and quantitative problems on lab quizzes and course exams and showed that male students outperformed female students by 3% on qualitative quiz and exam problems. Male and female students performed equally on the quantitative course exam problems. The gender gaps within CSEM post-test scores, qualitative lab quiz scores, and qualitative exam scores were insignificant for students with a CSEM pretest score of 25% or less but grew as pretest scores increased. Structural equation modeling demonstrated that a latent variable, called Conceptual Physics Performance/Non-Quantitative (CPP/NonQnt, orthogonal to quantitative test performance was useful in explaining the differences observed in qualitative performance; this variable was most strongly related to CSEM post-test scores. The CPP/NonQnt of male students was 0.44 standard deviations higher than female students. The CSEM pretest measured CPP/NonQnt much less accurately for women (R^{2}=4% than for men (R^{2}=17%. The failure to detect a gender gap for students scoring 25% or less on the pretest suggests that the CSEM instrument itself is not gender biased. The failure to find a performance difference in quantitative test performance while detecting a gap in

  18. Exploring Perceived Discrimination Among LGBT Individuals in Turkey in Education, Employment, and Health Care: Results of an Online Survey.

    Science.gov (United States)

    Göçmen, İpek; Yılmaz, Volkan

    2017-01-01

    This article explores the discrimination practices encountered by lesbian, gay, bisexual, and transgender (LGBT) individuals in education, income, employment, and health care in Turkey. Limited quantitative data on LGBT individuals are available in Turkey. This study collected data from 2,875 LGBT individuals through a Web-based survey. The findings suggest that LGBT individuals report perceived direct and indirect discrimination in accessing education, employment, and health care. In a country where LGBT rights are not yet recognized and antidiscrimination legislation covering sexual orientation and gender identity is still nonexistent, findings demonstrate perceived discrimination of LGBTs rarely turns into a legal complaint. Even when they do, most LGBTs in our sample report that they did not feel that the justice system addressed their grievances.

  19. A search for a distant companion to the sun with the wide-field infrared survey explorer

    Energy Technology Data Exchange (ETDEWEB)

    Luhman, K. L., E-mail: kluhman@astro.psu.edu [Department of Astronomy and Astrophysics, The Pennsylvania State University, University Park, PA 16802 (United States); Center for Exoplanets and Habitable Worlds, The Pennsylvania State University, University Park, PA 16802 (United States)

    2014-01-20

    I have used multi-epoch astrometry from the Wide-field Infrared Survey Explorer to perform a search for a distant companion to the Sun via its parallactic motion. I have not found an object of this kind down to W2 = 14.5. This limit corresponds to analogs of Saturn and Jupiter at 28,000 and 82,000 AU, respectively, according to models of the Jovian planets by Fortney and coworkers. Models of brown dwarfs by Burrows and coworkers predict fainter fluxes at a given mass for the age of the solar system, producing a closer distance limit of 26,000 AU for a Jupiter-mass brown dwarf. These constraints exclude most combinations of mass and separation at which a solar companion has been suggested to exist by various studies over the years.

  20. Wide-field infrared survey explorer observations of young stellar objects in the Lynds 1509 dark cloud in Auriga

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Wilson M.; McCollum, Bruce; Fajardo-Acosta, Sergio [Infrared Processing and Analysis Center, California Institute of Technology, MC 100-22, Pasadena, CA 91125 (United States); Padgett, Deborah L. [National Aeronautics and Space Administration, Goddard Space Flight Center, Code 665, Greenbelt, MD 20771 (United States); Terebey, Susan; Angione, John [Department of Physics and Astronomy, California State University, Los Angeles, CA 90032 (United States); Rebull, Luisa M. [Spitzer Science Center, California Institute of Technology, MC 314-6, Pasadena, CA 91125 (United States); Leisawitz, David, E-mail: wliu@ipac.caltech.edu [National Aeronautics and Space Administration, Goddard Space Flight Center, Code 605, Greenbelt, MD 20771 (United States)

    2014-06-01

    The Wide-Field Infrared Survey Explorer (WISE) has uncovered a striking cluster of young stellar object (YSO) candidates associated with the L1509 dark cloud in Auriga. The WISE observations, at 3.4 μm, 4.6 μm, 12 μm, and 22 μm, show a number of objects with colors consistent with YSOs, and their spectral energy distributions suggest the presence of circumstellar dust emission, including numerous Class I, flat spectrum, and Class II objects. In general, the YSOs in L1509 are much more tightly clustered than YSOs in other dark clouds in the Taurus-Auriga star forming region, with Class I and flat spectrum objects confined to the densest aggregates, and Class II objects more sparsely distributed. We estimate a most probable distance of 485-700 pc, and possibly as far as the previously estimated distance of 2 kpc.

  1. Exploring the Clinical Practice of Speech and Language Therapists with Adults with Dementia: A Cross-Sectional Survey in Portugal.

    Science.gov (United States)

    Nóbrega, Jossie; Lousada, Marisa; Figueiredo, Daniela

    2016-01-01

    Adults with acquired communication and swallowing disorders secondary to dementia can benefit from speech and language therapy services. However, there is limited information on the role of speech and language therapists (SLTs) in the treatment of individuals with dementia. The aim of this study was to explore the clinical practice of SLTs with adults with dementia. A cross-sectional survey of SLTs was conducted in Portugal using a web-based questionnaire designed specifically for the purpose of this study. A total of 230 SLTs responded to the survey. Among the respondents, 52.2% had limited clinical practice with individuals with dementia, with only 14.3% having worked with more than 10 cases. In Portugal, the clinical practice of SLTs in dementia is limited and mostly centred on the assessment of language, communication, and swallowing. The current findings highlight the need to address training in dementia within graduate and post-graduate programmes for SLTs. © 2017 S. Karger AG, Basel.

  2. Female genital cosmetic surgery: a cross-sectional survey exploring knowledge, attitude and practice of general practitioners.

    Science.gov (United States)

    Simonis, M; Manocha, R; Ong, J J

    2016-09-26

    To explore general practitioner's (GP) knowledge, attitudes and practice regarding female genital cosmetic surgery (FGCS) in Australia. Cross-sectional survey. Australia. GPs who attended a women's health seminar and GPs who subscribed to a non-governmental, national health professional organisation database that provides education to primary care professionals. A national online survey of GPs was conducted for the 10-week period, starting 1 week prior and 2 months after a Women's Health seminar was held in Perth on 8 August 2015. 31 questions prompted GPs' knowledge, attitudes and practice in managing patients asking about FGCS. The survey was fully completed by 443 GPs; 54% had seen patients requesting FGCS. Overall, 75% (95% CI 71% to 79%) of GPs rated their knowledge of FGCS as inadequate and 97% (95% CI 94% to 99%) had been asked by women of all ages about genital normality. Of those who had seen patients requesting FGCS, nearly half (44%, 95% CI 38% to 51%) reported they had insufficient knowledge of risks of FGCS procedures and 35% (95% CI 29% to 41%) reported seeing females younger than 18 years of age requesting FGCS. Just over half (56%, 95% CI 51% to 60%) of the GPs felt that women should be counselled before making a referral for FGCS. More than half the GPs suspected psychological disturbances in their patients requesting FGCS such as depression, anxiety, relationship difficulties and body dysmorphic disorder. GPs see women of all ages presenting with genital anatomy concerns and in those who request FGCS, GPs often suspected a range of mental health difficulties. GPs require greater education to support their patients who request FGCS. Published by the BMJ Publishing Group Limited. For permission to use (where not already granted under a licence) please go to http://www.bmj.com/company/products-services/rights-and-licensing/

  3. FY 1998 report on the verification survey of geothermal exploration technology, etc. 1/2. Survey of deep geothermal resource; 1998 nendo chinetsu tansa gijutsu nado kensho chosa hokokusho. 1/2. Shinbu chinetsu shigen chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-12-01

    For the purpose of commercializing deep geothermal resource, a deep exploration well of 4000m class was drilled in the existing geothermal development area to survey the situation of deep geothermal resource existence and the availability. Concretely, the deep geothermal exploration well was drilled for study in the Kakkonda area, Shizukuishi town, Iwate prefecture, to clarify the situation of deep geothermal resource existence and the whole image of geothermal system. Consideration was made of the deep geothermal exploration method, systematization of deep high temperature drilling technology, and availability of deep geothermal resource. The results of the survey were summed up as follows: 1) general remarks; 2) deep exploration well drilling work; 3) details of the study. 1) and 2) were included in this report, and 3) in the next report. In 1), the items were as follows: the study plan/gist of study execution, the details and results of the deep geothermal resource survey, the outline of the deep exploration well drilling work, and the outline of the results of the FY 1998 study. In 2), the drilling work plan/the actual results of the drilling work were summed up. As to the results of the study, summarized were the acquisition of survey data on deep exploration well, heightening of accuracy of the deep geothermal resource exploration method, etc. (NEDO)

  4. Chang'E-3 Science Exploration Progress

    Science.gov (United States)

    Zou, Yongliao; Ouyang, Ziyuan

    Chang’e-3 mission is the second phase of China Lunar Exploration Program which its main science objectives is to map the landing site and the rover path, determine its surface chemical composition and study the regional geological and geochemical characteristics, map the earth’s plasmasphere and study Earth’s plasmasphere responses to solar activity and plasma behaviors in the magnetosphere, monitor the variable stars, bright active galactic nuclei ( AGN ) and survey the sky. Eight scientific payloads onboard the CE-3 probe has obtained lots of data, and this paper will introduce their exploration progresses and some new scientific results. Key words: Chang’e-3 Mission, Science Exploration Progress, Scientific Payloads

  5. Geochemical Investigations of Groundwater Stability

    Energy Technology Data Exchange (ETDEWEB)

    Bath, Adrian [Intellisci Ltd., Loughborough (United Kingdom)

    2006-05-15

    The report describes geochemical parameters and methods that provide information about the hydrodynamic stability of groundwaters in low permeability fractured rocks that are potential hosts for radioactive waste repositories. Hydrodynamic stability describes the propensity for changes in groundwater flows over long timescales, in terms of flow rates and flow directions. Hydrodynamic changes may also cause changes in water compositions, but the related issue of geochemical stability of a potential repository host rock system is outside the scope of this report. The main approaches to assessing groundwater stability are numerical modelling, measurement and interpretation of geochemical indicators in groundwater compositions, and analyses and interpretations of secondary minerals and fluid inclusions in these minerals. This report covers the latter two topics, with emphasis on geochemical indicators. The extent to which palaeohydrogeology and geochemical stability indicators have been used in past safety cases is reviewed. It has been very variable, both in terms of the scenarios considered, the stability indicators considered and the extent to which the information was explicitly or implicitly used in assessing FEPs and scenarios in the safety cases. Geochemical indicators of hydrodynamic stability provide various categories of information that are of hydrogeological relevance. Information about groundwater mixing, flows and water sources is potentially provided by the total salinity of groundwaters, their contents of specific non-reactive solutes (principally chloride) and possibly of other solutes, the stable isotopic ratio of water, and certain characteristics of secondary minerals and fluid inclusions. Information pertaining directly to groundwater ages and the timing of water and solute movements is provided by isotopic systems including tritium, carbon-14, chlorine-36, stable oxygen and hydrogen isotopes, uranium isotopes and dissolved mobile gases in

  6. Contributions to a shallow aquifer study by reprocessed seismic sections from petroleum exploration surveys, eastern Abu Dhabi, United Arab Emirates

    Science.gov (United States)

    Woodward, D.

    1994-01-01

    The US Geological Survey, in cooperation with the National Drilling Company of Abu Dhabi, is conducting a 4-year study of the fresh and slightly saline groundwater resources of the eastern Abu Dhabi Emirate. Most of this water occurs in a shallow aquifer, generally less than 150 m deep, in the Al Ain area. A critical part of the Al Ain area coincides with a former petroleum concession area where about 2780 km of vibroseis data were collected along 94 seismic lines during 1981-1983. Field methods, acquistion parameters, and section processing were originally designed to enhance reflections expected at depths ranging from 5000 to 6000 m, and subsurface features directly associated with the shallow aquifer system were deleted from the original seismic sections. The original field tapes from the vibroseis survey were reprocessed in an attempt to extract shallow subsurface information (depths less than 550 m) for investigating the shallow aquifer. A unique sequence of reproccessing parameters was established after reviewing the results from many experimental tests. Many enhancements to the resolution of shallow seismic reflections resulted from: (1) application of a 20-Hz, low-cut filter; (2) recomputation of static corrections to a datum nearer the land surface; (3) intensive velocity analyses; and (4) near-trace muting analyses. The number, resolution, and lateral continuity of shallow reflections were greatly enhanced on the reprocessed sections, as was the delineation of shallow, major faults. Reflections on a synthetic seismogram, created from a borehole drilled to a depth of 786 m on seismic line IQS-11, matcheddprecisely with shallow reflections on the reprocessed section. The 33 reprocessed sections were instrumental in preparing a map showing the major structural features that affect the shallow aquifer system. Analysis of the map provides a better understanding of the effect of these shallow features on the regional occurrence, movement, and quality of

  7. Exploring midwifery students' views and experiences of caseload midwifery: A cross-sectional survey conducted in Victoria, Australia.

    Science.gov (United States)

    Dawson, Kate; Newton, Michelle; Forster, Della; McLachlan, Helen

    2015-02-01

    in Australia, models of maternity care that offer women continuity of care with a known midwife have been promoted. Little is known about the intentions of the future midwifery workforce to work in such models. This study aimed to explore midwifery students' views and experiences of caseload midwifery and their work intentions in relation to the caseload model following graduation. cross-sectional survey. Victoria, Australia. 129 midwifery students representing all midwifery course pathways (Post Graduate Diploma, Bachelor of Midwifery, Bachelor of Nursing/Bachelor of Midwifery) in Victoria. midwifery students from all course pathways considered that continuity of care is important to women and indicated that exposure to continuity models during their course was very positive. Two-thirds of the students (67%) considered that the continuity experiences made them want to work in a caseload model; only 5% reported that their experiences had discouraged them from continuity of care work in the future. Most wanted a period of consolidation to gain experience as a midwife prior to commencing in the caseload model. Perceived barriers to caseload work were being on-call, and challenges in regard to work/life balance and family commitments. midwifery students in this study were very positive about caseload midwifery and most would consider working in caseload after a period of consolidation. Continuity of care experiences during students' midwifery education programmes appeared to provide students with insight and understanding of continuity of care for both women and midwives. Further research should explore what factors influence students' future midwifery work, whether or not their plans are fulfilled, and whether or not the caseload midwifery workforce can be sustained. Copyright © 2014 Elsevier Ltd. All rights reserved.

  8. Market applications of Resistivity, Induced Polarisation, Magnetic Resonance and Electromagnetic methods for Groundwater Investigations, Mining Exploration, Environmental and Engineering Surveys

    Science.gov (United States)

    Bernard, J.

    2012-12-01

    The Manufacturers of geophysical instruments have been facing these past decades the fast evolution of the electronics and of the computer sciences. More automatisms have been introduced into the equipment and into the processing and interpretation software which may let believe that conducting geophysical surveys requires less understanding of the method and less experience than in the past. Hence some misunderstandings in the skills that are needed to make the geophysical results well integrated among the global information which the applied geologist needs to acquire to be successful in his applications. Globally, the demand in geophysical investigation goes towards more penetration depth, requiring more powerful transmitters, and towards a better resolution, requiring more data such as in 3D analysis. Budgets aspects strongly suggest a high efficiency in the field associated to high speed data processing. The innovation is required in all aspects of geophysics to fit with the market needs, including new technological (instruments, software) and methodological (methods, procedures, arrays) developments. The structures in charge of the geophysical work can be public organisations (institutes, ministries, geological surveys,…) or can come from the private sector (large companies, sub-contractors, consultants, …), each one of them getting their own constraints in the field work and in the processing and interpretation phases. In the applications concerning Groundwater investigations, Mining Exploration, Environmental and Engineering surveys, examples of data and their interpretation presently carried out all around the world will be presented for DC Resistivity (Vertical Electrical Sounding, 2D, 3D Resistivity Imaging, Resistivity Monitoring), Induced Polarisation (Time Domain 2D, 3D arrays for mining and environmental), Magnetic Resonance Sounding (direct detection and characterisation of groundwater) and Electromagnetic (multi-component and multi

  9. Discovery of Wolitu Pb-Zn deposit through geochemical prospecting under loess cover in Inner Mongolia, China

    Directory of Open Access Journals (Sweden)

    Fan Yang

    2017-09-01

    Full Text Available We report the finding of the Wolitu Pb-Zn deposit in Inner Mongolia, China, through a series of geochemical surveys. The Wolitu area, located in the loess-cover area in the Hure Banner, Tongliao City, Inner Mongolia, and neighboring the Horqin Sandy Land to the north, had no previous history of Pb-Zn mining or record of Pb-Zn mineralization. Our study identified a large Pb-Zn anomaly with potential zones of mineralization by stream sediment survey. Random rock sampling reveals limonitization at sporadic outcrops in the gullies. The high concentrations of Pb in the residual debris provided guidelines to fix the position for exploratory trench. Oxidized concealed orebodies were identified by trenching. Blind orebodies in veins hosted within the structural zone between slates and marbles of the upper Carboniferous Shizuizi Formation and the Permian granite were discovered by drilling. It is computed that the ore reserve may reach up to 540,000 tones with Pb grade of 1.27% and Zn of 1.9%. This case study is an excellent example for identifying potential polymetallic deposits in loess covered terrains using geochemical exploration.

  10. An integrated geophysical survey of Kilbourne Hole, southern New Mexico: Implications for near surface exploration of Mars and the Moon

    Science.gov (United States)

    Maksim, Nisa

    Features such as the Home Plate plateau on Mars, a suspected remnant of an ancient phreatomagmatic eruption, can reveal important information about paleohydrologic conditions. The eruption intensity of a phreatomagmatic volcano is controlled mainly by the quantity of water and magma, the internal geometry of the volcano, and the depth of the interaction zone between magma and water. In order to understand the paleohydrologic conditions at the time of eruption, we must understand all the factors that influenced the phreatomagmatic event. I conducted an integrated geophysical survey, which are magnetic and gravity surveys, and a ground-penetrating radar (GPR) surveys at Kilbourne Hole, a phreatomagmatic crater in southern New Mexico. These investigations serve an analog paleo-hydrogeological study that could be conducted on Mars and the Moon with an implication for planetary exploration. These geophysical surveys are designed to delineate the internal structure of a phreatomagmatic volcano and to define the volumes and masses of volcanic dikes and excavation unit, the depth of feeder dikes, and impacted velocity of the volcanic blocks. For the gravity and magnetic surveys at Kilbourne Hole, I collected data at a total of 171 gravity survey stations and 166 magnetics survey stations. A 2D gravity and magnetic inverse model was developed jointly to map the body of the magma intrusions and the internal structure of Kilbourne Hole. A total of 6 GPR surveys lines were also completed at Kilbourne Hole to image and to define locations of pyroclastic deposits, volcanic sags and blocks, the sizes distribution of volcanic blocks, and the impact velocity of the volcanic blocks. Using the size distribution and impact velocity of volcanic blocks from our GPR data, I derived the initial gas expansion velocity and the time duration of the gas expansion phase of the Kilbourne Hole eruption. These obtained parameters (volumes, masses, and depths of the feeder dikes and the excavation

  11. NEOSURVEY 1: INITIAL RESULTS FROM THE WARM SPITZER EXPLORATION SCIENCE SURVEY OF NEAR-EARTH OBJECT PROPERTIES

    Energy Technology Data Exchange (ETDEWEB)

    Trilling, David E.; Mommert, Michael [Department of Physics and Astronomy, PO Box 6010, Northern Arizona University, Flagstaff, AZ 86011 (United States); Hora, Joseph; Fazio, Giovanni; Smith, Howard [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, MS-65, Cambridge, MA 02138-1516 (United States); Chesley, Steve [Jet Propulsion Laboratory, California Institute of Technology, California Institute of Technology, 4800 Oak Grove Drive, Pasadena, CA 91109 (United States); Emery, Joshua [Department of Earth and Planetary Science, University of Tennessee, 306 EPS Building, 1412 Circle Drive, Knoxville, TN 37996 (United States); Harris, Alan [German Aerospace Center (DLR), Institute of Planetary Research, Rutherfordstrasse 2, 12489, Berlin (Germany); Mueller, Michael [SRON, Netherlands Institute for Space Research, PO Box 800, 9700AV Groningen (Netherlands)

    2016-12-01

    Near-Earth objects (NEOs) are small solar system bodies whose orbits bring them close to the Earth’s orbit. We are carrying out a Warm Spitzer Cycle 11 Exploration Science program entitled NEOSurvey—a fast and efficient flux-limited survey of 597 known NEOs in which we derive a diameter and albedo for each target. The vast majority of our targets are too faint to be observed by NEOWISE, though a small sample has been or will be observed by both observatories, which allows for a cross-check of our mutual results. Our primary goal is to create a large and uniform catalog of NEO properties. We present here the first results from this new program: fluxes and derived diameters and albedos for 80 NEOs, together with a description of the overall program and approach, including several updates to our thermal model. The largest source of error in our diameter and albedo solutions, which derive from our single-band thermal emission measurements, is uncertainty in η , the beaming parameter used in our thermal modeling; for albedos, improvements in solar system absolute magnitudes would also help significantly. All data and derived diameters and albedos from this entire program are being posted on a publicly accessible Web page at nearearthobjects.nau.edu.

  12. Exploring Graduate Students’ Attitudes towards Team Research and Their Scholarly Productivity: A Survey Guided by the Theory of Planned Behavior

    Directory of Open Access Journals (Sweden)

    Tianlan Wei

    2015-01-01

    Full Text Available This study explores the attitudinal and motivational factors underlying graduate students’ attitudes towards team research. Guided by the Theory of Planned Behavior, we hypothesize that attitude, subjective norm, and perceived behavioral control are three major determinants of graduate students’ intentions to conduct team research. An instrument was developed to measure the influences of these factors on students’ intentions and relevant scholarly productivity. A total of 281 graduate students from a large, comprehensive university in the southwest United States participated in the survey. Descriptive statistics reveal that around two-thirds of graduate students have no co-authored manuscripts submitted for publication since they started graduate school. Factor analyses validated the factor structure of the instrument, and the results of Structural Equation Modeling show that (a graduate students’ attitudes towards team research have a positive correlation with their attitudes towards individual research; (b attitude towards team research, subjective norm, and perceived behavioral control, along with students’ discipline/major areas and classification, account for 58% of the variance in the intention to conduct team research; and (c subjective norm appears to be the most influential factor in the model, followed by attitude; while perceived behavioral control is not of much importance. These findings provide implications for academic departments and programs to promote graduate students’ team research. Specifically, creating a climate for collaborative research in academic programs/disciplines/universities may work jointly with enhancing students’ appraisals of such collaborations.

  13. Along-Strike Geochemical Variations in the Late Triassic Nikolai Magmatic System, Wrangellia, Central Alaska

    Science.gov (United States)

    Wypych, A.; Twelker, E.; Lande, L. L.; Newberry, R.

    2015-12-01

    The Nikolai Basalt and related mafic to ultramafic intrusions are one of the world's most complete and best exposed sections of a large igneous province (Amphitheater Mountains, Alaska), and have been explored for magmatic Ni-Cu-Co-PGE mineralization (Wellgreen deposit in the Kluane Ranges, Yukon Territory, and Eureka zone in the Eastern Alaska Range). The full extent of the basalts and the intrusions, as well as along-strike variations in the geochemical and petrological composition and the causes for those variations has yet to be fully established. To better understand the extent and magmatic architecture of this system, the Alaska Division of Geological & Geophysical Surveys conducted mapping and geochemical investigations of the province from 2013 through 2015 field seasons. We present major and trace element data from whole rock, olivine, and chromite from samples of Triassic basalts and intrusives collected over a 250 km along-strike transect. This data is used to answer questions about variations in magma generation, temperature of crystallization, and degree of fractional crystallization required to produce the Nikolai Basalts. Using chalcophile elements, we examine the history of sulfide solubility, further adding to our understanding of the processes of magma evolution and its influence on the formation of economic mineral deposits. Our initial findings corroborate the presence of two phases of magma generation and eruption, as well as along-strike variation in composition of these phases. We propose that the major along-strike variations are due to differences in amount of cumulate olivine and other late-stage processes. This magmatic architecture has important implications for exploration for magmatic sulfide deposits of nickel-copper and strategic and critical platinum group elements (PGEs) as it can help to better understand the occurrences and point to future possible deposits within the system.

  14. SURVEY

    DEFF Research Database (Denmark)

    SURVEY er en udbredt metode og benyttes inden for bl.a. samfundsvidenskab, humaniora, psykologi og sundhedsforskning. Også uden for forskningsverdenen er der mange organisationer som f.eks. konsulentfirmaer og offentlige institutioner samt marketingsafdelinger i private virksomheder, der arbejder...

  15. Central Colorado Assessment Project (CCAP)-Geochemical data for rock, sediment, soil, and concentrate sample media

    Science.gov (United States)

    Granitto, Matthew; DeWitt, Ed H.; Klein, Terry L.

    2010-01-01

    This database was initiated, designed, and populated to collect and integrate geochemical data from central Colorado in order to facilitate geologic mapping, petrologic studies, mineral resource assessment, definition of geochemical baseline values and statistics, environmental impact assessment, and medical geology. The Microsoft Access database serves as a geochemical data warehouse in support of the Central Colorado Assessment Project (CCAP) and contains data tables describing historical and new quantitative and qualitative geochemical analyses determined by 70 analytical laboratory and field methods for 47,478 rock, sediment, soil, and heavy-mineral concentrate samples. Most samples were collected by U.S. Geological Survey (USGS) personnel and analyzed either in the analytical laboratories of the USGS or by contract with commercial analytical laboratories. These data represent analyses of samples collected as part of various USGS programs and projects. In addition, geochemical data from 7,470 sediment and soil samples collected and analyzed under the Atomic Energy Commission National Uranium Resource Evaluation (NURE) Hydrogeochemical and Stream Sediment Reconnaissance (HSSR) program (henceforth called NURE) have been included in this database. In addition to data from 2,377 samples collected and analyzed under CCAP, this dataset includes archived geochemical data originally entered into the in-house Rock Analysis Storage System (RASS) database (used by the USGS from the mid-1960s through the late 1980s) and the in-house PLUTO database (used by the USGS from the mid-1970s through the mid-1990s). All of these data are maintained in the Oracle-based National Geochemical Database (NGDB). Retrievals from the NGDB and from the NURE database were used to generate most of this dataset. In addition, USGS data that have been excluded previously from the NGDB because the data predate earliest USGS geochemical databases, or were once excluded for programmatic reasons

  16. Proceedings of the workshop on geochemical modeling

    Energy Technology Data Exchange (ETDEWEB)

    1986-01-01

    The following collection of papers was presented at a workshop on geochemical modeling that was sponsored by the Office of Civilian Radioactive Waste Management Program at the Lawrence Livermore National Laboratory (LLNL). The LLNL Waste Management Program sponsored this conference based on their belief that geochemical modeling is particularly important to the radioactive waste disposal project because of the need to predict the consequences of long-term water-rock interactions at the proposed repository site. The papers included in this volume represent a subset of the papers presented at the Fallen Leaf Lake Conference and cover a broad spectrum of detail and breadth in a subject that reflects the diverse research interests of the conference participants. These papers provide an insightful look into the current status of geochemical modeling and illustrate how various geochemical modeling codes have been applied to problems of geochemical interest. The emphasis of these papers includes traditional geochemical modeling studies of individual geochemical systems, the mathematical and theoretical development and refinement of new modeling capabilities, and enhancements of data bases on which the computations are based. The papers in this proceedings volume have been organized into the following four areas: Geochemical Model Development, Hydrothermal and Geothermal Systems, Sedimentary and Low Temperature Environments, and Data Base Development. The participants of this symposium and a complete list of the talks presented are listed in the appendices.

  17. Exploration of contextual factors in a successful quality improvement collaborative in English ambulance services: cross-sectional survey.

    Science.gov (United States)

    Phung, Viet-Hai; Essam, Nadya; Asghar, Zahid; Spaight, Anne; Siriwardena, Aloysius N

    2016-02-01

    Clinical leadership and organizational culture are important contextual factors for quality improvement (QI) but the relationship between these and with organizational change is complex and poorly understood. We aimed to explore the relationship between clinical leadership, culture of innovation and clinical engagement in QI within a national ambulance QI Collaborative (QIC). We used a self-administered online questionnaire survey sent to front-line clinicians in all 12 English ambulance services. We conducted a cross-sectional analysis of quantitative data and qualitative analysis of free-text responses. There were 2743 (12% of 22 117) responses from 11 of the 12 participating ambulance services. In the 3% of responders that were directly involved with the QIC, leadership behaviour was significantly higher than for those not directly involved. QIC involvement made no significant difference to responders' perceptions of the culture of innovation in their organization, which was generally considered poor. Although uptake of QI methods was low overall, QIC members were significantly more likely to use QI methods, which were also significantly associated with leadership behaviour. Despite a limited organizational culture of innovation, clinical leadership and use of QI methods in ambulance services generally, the QIC achieved its aims to significantly improve pre-hospital care for acute myocardial infarction and stroke. We postulate that this was mediated through an improvement subculture, linked to the QIC, which facilitated large-scale improvement by stimulating leadership and QI methods. Further research is needed to understand success factors for QI in complex health care environments. © 2016 The Authors. Journal of Evaluation in Clinical Practice published by John Wiley & Sons, Ltd.

  18. Exploring the attitudes of medical faculty members and students in Pakistan towards plagiarism: a cross sectional survey.

    Science.gov (United States)

    Rathore, Farooq Azam; Waqas, Ahmed; Zia, Ahmad Marjan; Mavrinac, Martina; Farooq, Fareeha

    2015-01-01

    Objective. The objective of this survey was to explore the attitudes towards plagiarism of faculty members and medical students in Pakistan. Methods. The Attitudes Toward Plagiarism questionnaire (ATP) was modified and distributed among 550 medical students and 130 faculty members in 7 medical colleges of Lahore and Rawalpindi. Data was entered in the SPSS v.20 and descriptive statistics were analyzed. The questionnaire was validated by principal axis factoring analysis. Results. Response rate was 93% and 73%, respectively. Principal axis factoring analysis confirmed one factor structure of ATP in the present sample. It had an acceptable Cronbach's alpha value of 0.73. There were 421 medical students (218 (52%) female, 46% 3rd year MBBS students, mean age of 20.93 ± 1.4 years) and 95 faculty members (54.7% female, mean age 34.5 ± 8.9 years). One fifth of the students (19.7%) trained in medical writing (19.7%), research ethics (25.2%) or were currently involved in medical writing (17.6%). Most of the faculty members were demonstrators (66) or assistant professors (20) with work experience between 1 and 10 years. Most of them had trained in medical writing (68), research ethics (64) and were currently involved in medical writing (64). Medical students and faculty members had a mean score of 43.21 (7.1) and 48.4 (5.9) respectively on ATP. Most of the respondents did not consider that they worked in a plagiarism free environment and reported that self-plagiarism should not be punishable in the same way as plagiarism. Opinion regarding leniency in punishment of younger researchers who were just learning medical writing was divided. Conclusions. The general attitudes of Pakistani medical faculty members and medical students as assessed by ATP were positive. We propose training in medical writing and research ethics as part of the under and post graduate medical curriculum.

  19. Exploring the attitudes of medical faculty members and students in Pakistan towards plagiarism: a cross sectional survey

    Directory of Open Access Journals (Sweden)

    Farooq Azam Rathore

    2015-06-01

    Full Text Available Objective. The objective of this survey was to explore the attitudes towards plagiarism of faculty members and medical students in Pakistan.Methods. The Attitudes Toward Plagiarism questionnaire (ATP was modified and distributed among 550 medical students and 130 faculty members in 7 medical colleges of Lahore and Rawalpindi. Data was entered in the SPSS v.20 and descriptive statistics were analyzed. The questionnaire was validated by principal axis factoring analysis.Results. Response rate was 93% and 73%, respectively. Principal axis factoring analysis confirmed one factor structure of ATP in the present sample. It had an acceptable Cronbach’s alpha value of 0.73. There were 421 medical students (218 (52% female, 46% 3rd year MBBS students, mean age of 20.93 ± 1.4 years and 95 faculty members (54.7% female, mean age 34.5 ± 8.9 years. One fifth of the students (19.7% trained in medical writing (19.7%, research ethics (25.2% or were currently involved in medical writing (17.6%. Most of the faculty members were demonstrators (66 or assistant professors (20 with work experience between 1 and 10 years. Most of them had trained in medical writing (68, research ethics (64 and were currently involved in medical writing (64. Medical students and faculty members had a mean score of 43.21 (7.1 and 48.4 (5.9 respectively on ATP. Most of the respondents did not consider that they worked in a plagiarism free environment and reported that self-plagiarism should not be punishable in the same way as plagiarism. Opinion regarding leniency in punishment of younger researchers who were just learning medical writing was divided.Conclusions. The general attitudes of Pakistani medical faculty members and medical students as assessed by ATP were positive. We propose training in medical writing and research ethics as part of the under and post graduate medical curriculum.

  20. Exploring the attitudes of medical faculty members and students in Pakistan towards plagiarism: a cross sectional survey

    Science.gov (United States)

    Rathore, Farooq Azam; Zia, Ahmad Marjan; Mavrinac, Martina; Farooq, Fareeha

    2015-01-01

    Objective. The objective of this survey was to explore the attitudes towards plagiarism of faculty members and medical students in Pakistan. Methods. The Attitudes Toward Plagiarism questionnaire (ATP) was modified and distributed among 550 medical students and 130 faculty members in 7 medical colleges of Lahore and Rawalpindi. Data was entered in the SPSS v.20 and descriptive statistics were analyzed. The questionnaire was validated by principal axis factoring analysis. Results. Response rate was 93% and 73%, respectively. Principal axis factoring analysis confirmed one factor structure of ATP in the present sample. It had an acceptable Cronbach’s alpha value of 0.73. There were 421 medical students (218 (52%) female, 46% 3rd year MBBS students, mean age of 20.93 ± 1.4 years) and 95 faculty members (54.7% female, mean age 34.5 ± 8.9 years). One fifth of the students (19.7%) trained in medical writing (19.7%), research ethics (25.2%) or were currently involved in medical writing (17.6%). Most of the faculty members were demonstrators (66) or assistant professors (20) with work experience between 1 and 10 years. Most of them had trained in medical writing (68), research ethics (64) and were currently involved in medical writing (64). Medical students and faculty members had a mean score of 43.21 (7.1) and 48.4 (5.9) respectively on ATP. Most of the respondents did not consider that they worked in a plagiarism free environment and reported that self-plagiarism should not be punishable in the same way as plagiarism. Opinion regarding leniency in punishment of younger researchers who were just learning medical writing was divided. Conclusions. The general attitudes of Pakistani medical faculty members and medical students as assessed by ATP were positive. We propose training in medical writing and research ethics as part of the under and post graduate medical curriculum. PMID:26157615

  1. Exploration of contextual factors in a successful quality improvement collaborative in English ambulance services: cross‐sectional survey

    Science.gov (United States)

    Phung, Viet‐Hai; Essam, Nadya; Asghar, Zahid; Spaight, Anne

    2015-01-01

    Abstract Rationale, aims and objectives Clinical leadership and organizational culture are important contextual factors for quality improvement (QI) but the relationship between these and with organizational change is complex and poorly understood. We aimed to explore the relationship between clinical leadership, culture of innovation and clinical engagement in QI within a national ambulance QI Collaborative (QIC). Methods We used a self‐administered online questionnaire survey sent to front‐line clinicians in all 12 English ambulance services. We conducted a cross‐sectional analysis of quantitative data and qualitative analysis of free‐text responses. Results There were 2743 (12% of 22 117) responses from 11 of the 12 participating ambulance services. In the 3% of responders that were directly involved with the QIC, leadership behaviour was significantly higher than for those not directly involved. QIC involvement made no significant difference to responders' perceptions of the culture of innovation in their organization, which was generally considered poor. Although uptake of QI methods was low overall, QIC members were significantly more likely to use QI methods, which were also significantly associated with leadership behaviour. Conclusions Despite a limited organizational culture of innovation, clinical leadership and use of QI methods in ambulance services generally, the QIC achieved its aims to significantly improve pre‐hospital care for acute myocardial infarction and stroke. We postulate that this was mediated through an improvement subculture, linked to the QIC, which facilitated large‐scale improvement by stimulating leadership and QI methods. Further research is needed to understand success factors for QI in complex health care environments. PMID:26303398

  2. Mobile phone and young people. A survey pilot study to explore the controversial aspects of a new social phenomenon.

    Science.gov (United States)

    Dimonte, M; Ricchiuto, G

    2006-08-01

    Aim of this paper is to report the results of a pilot study as a part of a program addressed to health promotion and to improve the culture of sustainability in the school. A 15-items structured questionnaire was administered to 1 011 students (aged 9-18 years) in order to explore the entity of the phenomenon of mobile telephony among the young and qualitatively esteem the level of exposure to the potential adverse health and social effects of such dominant form of electronically mediate communication. This preliminary information was then deepened by in-group interviews focused to clarify the cultural basis of the phenomenon. The survey-study confirmed that the penetration of mobile telephony among the young matches with the national trend: 96% of 14-18-teens own at least one mobile phone; 22% of them own multiple mobile phones. In addition, most of them use mobile phone all the day; a third makes calls over 6 minutes long; half is poorly informed about the potential health risks related to ''electromagnetic pollution''. Despite the most perceive mobile phone like something noxious, only 23% holds it far from body; a very small percentage uses a hands-free kit. Most declared to suffer from a sort of addiction towards mobile phone. In the light of a growing literature and of a supposed more vulnerability of children and adolescents towards toxicants than adults, we believe that health and school operators should inform parents and the young about the possible risks linked to the abuse of technology and promote a more critic and responsible approach to mobile phone.

  3. Engaging scientists: An online survey exploring the experience of innovative biotechnological approaches to controlling vector-borne diseases.

    Science.gov (United States)

    Boëte, Christophe; Beisel, Uli; Reis Castro, Luísa; Césard, Nicolas; Reeves, R Guy

    2015-08-10

    Pioneering technologies (e.g., nanotechnology, synthetic biology or climate engineering) are often associated with potential new risks and uncertainties that can become sources of controversy. The communication of information during their development and open exchanges between stakeholders is generally considered a key issue in their acceptance. While the attitudes of the public to novel technologies have been widely considered there has been relatively little investigation of the perceptions and awareness of scientists working on human or animal diseases transmitted by arthropods. Consequently, we conducted a global survey on 1889 scientists working on aspects of vector-borne diseases, exploring, under the light of a variety of demographic and professional factors, their knowledge and awareness of an emerging biotechnology that has the potential to revolutionize the control of pest insect populations. Despite extensive media coverage of key developments (including releases of manipulated mosquitoes into human communities) this has in only one instance resulted in scientist awareness exceeding 50% on a national or regional scale. We document that awareness of pioneering releases significantly relied on private communication sources that were not equally accessible to scientists from countries with endemic vector-borne diseases (dengue and malaria). In addition, we provide quantitative analysis of the perceptions and knowledge of specific biotechnological approaches to controlling vector-borne disease, which are likely to impact the way in which scientists around the world engage in the debate about their value. Our results indicate that there is scope to strengthen already effective methods of communication, in addition to a strong demand by scientists (expressed by 79.9% of respondents) to develop new, creative modes of public engagement.

  4. Use of Geochemical Indices in Environmental Assessment of Soil; the Predictable and the Predictably Unpredictable

    Science.gov (United States)

    Mikkonen, Hannah; Clarke, Bradley; van de Graaff, Robert; Reichman, Suzie

    2016-04-01

    Geochemical correlations between common contaminants (Pb, Ni, As, Cr, Co and Zn) and earth metals, Fe and Mn, have been recommended as empirical tools to estimate "background" concentrations of metals in soil. A limited number of studies indicate that geochemical ratios between Pb, Ni, As, Cr, Co, V and Zn with scavenger metals Fe or Mn, are consistent between soils collected from different regions (Hamon et al. 2004, Myers and Thorbjornsen 2004). These studies have resulted in the incorporation of geochemical indices into Australian guidance, for derivation of ecological investigation levels for Ni, Cr, Cu and Zn. However, little research has been undertaken to assess the variation of geochemical patterns between soils derived from different parent materials or different weathering environments. A survey of background soils derived from four different parent materials, across Victoria, Australia, was undertaken, comprising collection of samples (n=640) from the surface (0 to 0.1 m) and sub-surface (0.3 to 0.6 m). Soil samples were collected from urban and rural areas of low disturbance, away from point sources of contamination. Samples were analysed for metals/metalloids and soil physical and chemical properties. Statistical review of results included regression and multivariate analysis. The results of the soil survey were compared against geochemical relationships reported within Australia and internationally. Compilation of results from this study and international data sets, indicates that geochemical relationships for metals Cr and V (in the format of log[Cr] = alog[Fe] +c) are predictable, not only between soils derived from different parent materials, but also between soils of different continents. Conversely, relationships between Zn and Fe, Pb and Fe, Cu and Fe, Co and Mn are variable, particularly within soils derived from alluvial sediments, which may have undergone periods of reducing conditions, resulting in dissociation from metal oxides. Broad

  5. FREZCHEM: An Aqueous Geochemical Model for Mars

    Science.gov (United States)

    Marion, G. M.; Mironenko, M. V.; Roberts, M. W.

    2006-12-01

    For the past eight years, the NASA PG&G and MFR programs have funded the development of the FREZCHEM model. FREZCHEM is an equilibrium chemical thermodynamic model parameterized for concentrated electrolyte solutions (with 81 solid phases) using the Pitzer equations for the temperature range from 200 to 298 K and the total pressure range from 1 to 1000 bars. This model has been extensively used to explore cold geochemical processes and the limits for life in the Arctic, Antarctica, Europa, and Mars. The FORTRAN code has been made freely available to interested scientists. Despite these wide-spread applications, the continual updating, dissemination, and archiving of the model is problematic. The objectives of this project were to (1) develop a user-friendly FORTRAN code, (2) implement an Internet-accessible working model, and (3) develop an archive for various model versions. In this presentation, we will outline the new computer algorithm that uses the Gibbs energy minimization approach, describe the Internet-accessible working model, and illustrate model applications to Martian geochemistry. This project will make this unique research tool readily and easily available, even to occasional users, now and in the future. Today, such a user-friendly model would be especially helpful in interpreting the exciting data from the new Mars missions.

  6. Exploring differences in Canadian adult men and women with diabetes management: results from the Canadian Community Health Survey.

    Science.gov (United States)

    De Melo, Margaret; de Sa, Eric; Gucciardi, Enza

    2013-11-22

    Over 2 million Canadians are known to have diabetes. In addition to the economic burden placed on the healthcare system, the human cost associated with diabetes poses a heavy burden on those living with diabetes. The literature shows that apparent differences exist in diabetes complications and diabetes management between men and women. How self-care management and utilization of health services differ by sex is not clearly understood.The purpose of this study was to explore sex differences in diabetes self-care and medical management in the Canadian population, using a nationally representative sample. Data collected from the cross-sectional, population-based Canadian Community Health Survey (2007-2008) were used in these analyses. A bootstrap variance estimation method and bootstrap weights provided by Statistics Canada were used to calculate 95% confidence intervals. Bivariate analyses identified variables of interest between females and males that were used in subsequent multivariate analyses. A total of 131,959 respondents were surveyed for the years of 2007 and 2008, inclusive. Fully adjusted multinomial and logistic regression analyses revealed sex differences for those living with diabetes. Compared to men with diabetes, women were more likely to be in the lowest income quintiles than the highest (OR: 1.8, 95% CI: 1.3-2.6) and were more likely not to have a job in the previous week (OR: 1.8, 95% CI: 1.4-2.4). Women were also more likely to avoid foods with fats or high calories (OR: 2.1, 95% CI: 1.4-3.0 and OR: 2.2, 95% CI: 1.6-3.0, respectively), to be concerned about heart disease (OR: 1.6, 95% CI: 1.1-2.2), and to be non-smokers (OR: 2.2, 95% CI: 1.6-3.0). However, despite their increased concern, women checked their blood-glucose less frequently on a daily basis than men (μwomen = 1.7, 95% CI: 1.7-1.8; μmen = 3.1, 95% CI: 2.9-3.2). Women were more likely to have an anxiety disorder (OR: 2.3, 95% CI: 1.7-3.2) and a mood disorder (OR: 2.4, 95% CI: 1

  7. Exploring the 'follow-through experience': a statewide survey of midwifery students and academics conducted in Victoria, Australia.

    Science.gov (United States)

    McLachlan, Helen L; Newton, Michelle; Nightingale, Helen; Morrow, Jane; Kruger, Gina

    2013-09-01

    Follow-through experiences (which enable midwifery students to experience continuity of care with individual women through pregnancy, labour and birth and the postnatal period) are a component of midwifery education programmes in Australia and the United Kingdom. Current accreditation standards in Australia require midwifery students to have a total of 20 continuity of care experiences with an average of 20 hours per woman over the duration of their course. There has been limited research regarding students' and academics' experiences of follow-through experiences; and there has been debate regarding the appropriate number of follow-through experiences in midwifery curricula. This study aimed to explore the follow-through experience from the perspective of midwifery students and academics in Victoria, Australia. cross-sectional design using a web-based survey. Victoria, Australia. Students (n=401) and academics (n=35) from all seven universities in Victoria that offer accredited midwifery programmes including the Bachelor of Midwifery, Bachelor of Nursing/Bachelor of Midwifery double degree, Postgraduate Diploma of Midwifery and Masters of Midwifery (entry to practice). Students and academics were in agreement that continuity of care is important to women. They considered the follow-through experience to be a unique and valuable learning opportunity and agreed that follow-through experiences should be included in midwifery education programmes. However, students and academics raised major concerns about the impact of follow-through experiences on students' capacity to meet university course requirements (such as missing lectures/tutorials and clinical placements), and spending extensive periods of time on-call both within and outside the university semester. Students and academics also reported concerns about the impact of follow-through experiences on students' personal lives, including paid employment and family responsibilities (such as childcare or caring for

  8. The Dublin SURGE Project: geochemical baseline for heavy metals in topsoils and spatial correlation with historical industry in Dublin, Ireland.

    Science.gov (United States)

    Glennon, M M; Harris, P; Ottesen, R T; Scanlon, R P; O'Connor, P J

    2014-04-01

    The Dublin SURGE (Soil Urban Geochemistry) Project is Dublin's first baseline survey of heavy metals and persistent organic pollutants in topsoils and is part of a Europe-wide initiative to map urban geochemical baselines in ten cities. 1,058 samples were collected as part of a stratified random sampling programme in the greater Dublin area to give an overview of baseline conditions in the city. Samples were analysed for 31 inorganic elements including heavy metals. Analysis of results indicates that the concentrations of lead, copper, zinc and mercury are strongly influenced by human activities, with elevated concentrations in the city docklands, inner city and heavy industry areas. Sources of heavy metals in these areas may include historical industry, coal burning, re-use of contaminated soil, modern traffic and leaded paint and petrol. Concentrations of other inorganic elements in topsoil show patterns which are strongly related to regional bedrock parent material. The spatial distributions of heavy metals, in particular Pb and As, are explored in detail with respect to regional geology and the influence of historical industry on soil quality. Exploratory data, geostatistical and correlation analyses suggest that the concentrations of heavy metals tend to increase as the intensity of historical industrial activity increases. In particular, drinks production, power generation, oil/gas/coal, metals and textile historical industries appear to be the contamination source for several heavy metals. The data provide a geochemical baseline relevant to the protection of human health, compliance with environmental legislation, land use planning and urban regeneration.

  9. Alaska Geochemical Database, Version 2.0 (AGDB2)--including “best value” data compilations for rock, sediment, soil, mineral, and concentrate sample media

    Science.gov (United States)

    Granitto, Matthew; Schmidt, Jeanine M.; Shew, Nora B.; Gamble, Bruce M.; Labay, Keith A.

    2013-01-01

    The Alaska Geochemical Database Version 2.0 (AGDB2) contains new geochemical data compilations in which each geologic material sample has one “best value” determination for each analyzed species, greatly improving speed and efficiency of use. Like the Alaska Geochemical Database (AGDB, http://pubs.usgs.gov/ds/637/) before it, the AGDB2 was created and designed to compile and integrate geochemical data from Alaska in order to facilitate geologic mapping, petrologic studies, mineral resource assessments, definition of geochemical baseline values and statistics, environmental impact assessments, and studies in medical geology. This relational database, created from the Alaska Geochemical Database (AGDB) that was released in 2011, serves as a data archive in support of present and future Alaskan geologic and geochemical projects, and contains data tables in several different formats describing historical and new quantitative and qualitative geochemical analyses. The analytical results were determined by 85 laboratory and field analytical methods on 264,095 rock, sediment, soil, mineral and heavy-mineral concentrate samples. Most samples were collected by U.S. Geological Survey personnel and analyzed in U.S. Geological Survey laboratories or, under contracts, in commercial analytical laboratories. These data represent analyses of samples collected as part of various U.S. Geological Survey programs and projects from 1962 through 2009. In addition, mineralogical data from 18,138 nonmagnetic heavy-mineral concentrate samples are included in this database. The AGDB2 includes historical geochemical data originally archived in the U.S. Geological Survey Rock Analysis Storage System (RASS) database, used from the mid-1960s through the late 1980s and the U.S. Geological Survey PLUTO database used from the mid-1970s through the mid-1990s. All of these data are currently maintained in the National Geochemical Database (NGDB). Retrievals from the NGDB were used to generate

  10. Map showing geochemical data for panned stream sediments from the Bread Loaf Further Planning Area, Addison and Washington counties, Vermont

    Science.gov (United States)

    Grosz, A.E.; Schruben, P.G.; Atelsek, P.J.

    1987-01-01

    A geochemical survey of bedrock samples in the Bread Loaf Roadless Area (index map; fig. 1) was conducted by the U.S. Geological Survey (USGS) during October, 1981 in order to outline areas that may contain undiscovered mineral deposits. This report describes the results of a geochemical analysis of panned concentrates collected from stream sediments, and complements other geologic and geochemical investigations of the area (Slack and Bitar, 1983). The present study has offered us a chance to identify sampling media and a technique most appropriate for the enhancement of certain metallic elements in samples of panned concentrate. This study is important to the resource evaluation of the Bread Loaf Roadless Area because it reveals that geochemical anomalies produced by this technique are not evident in the standard magnetic and nonmagnetic fractions of panned concentrates.

  11. Collected radiochemical and geochemical procedures

    Energy Technology Data Exchange (ETDEWEB)

    Kleinberg, J [comp.

    1990-05-01

    This revision of LA-1721, 4th Ed., Collected Radiochemical Procedures, reflects the activities of two groups in the Isotope and Nuclear Chemistry Division of the Los Alamos National Laboratory: INC-11, Nuclear and radiochemistry; and INC-7, Isotope Geochemistry. The procedures fall into five categories: I. Separation of Radionuclides from Uranium, Fission-Product Solutions, and Nuclear Debris; II. Separation of Products from Irradiated Targets; III. Preparation of Samples for Mass Spectrometric Analysis; IV. Dissolution Procedures; and V. Geochemical Procedures. With one exception, the first category of procedures is ordered by the positions of the elements in the Periodic Table, with separate parts on the Representative Elements (the A groups); the d-Transition Elements (the B groups and the Transition Triads); and the Lanthanides (Rare Earths) and Actinides (the 4f- and 5f-Transition Elements). The members of Group IIIB-- scandium, yttrium, and lanthanum--are included with the lanthanides, elements they resemble closely in chemistry and with which they occur in nature. The procedures dealing with the isolation of products from irradiated targets are arranged by target element.

  12. Petrographic features, geochemical trends and mass balance ...

    African Journals Online (AJOL)

    Petrographic features, geochemical trends and mass balance computation, in relation to the evolution of anatectic migmatites in the granulite facies terrain of the Manalur area, Tamil Nadu, south India.

  13. Geologic and geochemical studies of the New Albany Shale Group (Devonian-Mississippian) in Illinois. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Bergstrom, R.E.; Shimp, N.F.

    1980-06-30

    The Illinois State Geological Survey is conducting geological and geochemical investigations to evaluate the potential of New Albany Group shales as a source of hydrocarbons, particularly natural gas. Geological studies include stratigraphy and structure, mineralogic and petrographic characterization; analyses of physical properties; and development of a computer-based resources evaluation system. Geochemical studies include organic carbon content and trace elements; hydrocarbon content and composition; and adsorption/desorption studies of gas through shales. Separate abstracts have been prepared for each task reported.

  14. Gemas: Geochemical mapping of the agricultural and grasing land soils of Europe

    Science.gov (United States)

    Reimann, Clemens; Fabian, Karl; Birke, Manfred; Demetriades, Alecos; Matschullat, Jörg; Gemas Project Team

    2017-04-01

    Geochemical Mapping of Agricultural and grazing land Soil (GEMAS) is a cooperative project between the Geochemistry Expert Group of EuroGeoSurveys and Eurometaux. During 2008 and until early 2009, a total of 2108 samples of agricultural (ploughed land, 0-20 cm, Ap-samples) and 2023 samples of grazing land (0-10 cm, Gr samples)) soil were collected at a density of 1 site/2500 km2 each from 33 European countries, covering an area of 5,600,000 km2. All samples were analysed for 52 chemical elements following an aqua regia extraction, 42 elements by XRF (total), and soil properties, like CEC, TOC, pH (CaCl2), following tight external quality control procedures. In addition, the Ap soil samples were analysed for 57 elements in a mobile metal ion (MMI®) extraction, Pb isotopes, magnetic susceptibility and total C, N and S. The results demonstrate that robust geochemical maps of Europe can be constructed based on low density sampling, the two independent sample materials, Ap and Gr, show very comparable distribution patterns across Europe. At the European scale, element distribution patterns are governed by natural processes, most often a combination of geology and climate. The geochemical maps reflect most of the known metal mining districts in Europe. In addition, a number of new anomalies emerge that may indicate mineral potential. The size of some anomalies is such that they can only be detected when mapping at the continental scale. For some elements completely new geological settings are detected. An anthropogenic impact at a much more local scale is discernible in the immediate vicinity of some major European cities (e.g., London, Paris) and some metal smelters. The impact of agriculture is visible for Cu (vineyard soils) and for some further elements only in the mobile metal ion (MMI) extraction. For several trace elements deficiency issues are a larger threat to plant, animal and finally human health at the European scale than toxicity. Taking the famous step

  15. Geochemical studies of backfill aggregates, lake sediment cores and the Hueco Bolson Aquifer

    Science.gov (United States)

    Thapalia, Anita

    Aquifer that an important sources of water in the El Paso/Cd. Juraez metroplex. To delineate the boundary between fresh and brackish water from the northern Hueco Bolson Aquifer, we utilize an integrative geochemical, geophysical, and sedimentological approach. The goal of this study is to use geophysical well-log analysis and the water chemical analysis for identifying the changes in the quality of the groundwater. A detailed microgravity survey is utilized to explore the subsurface geological structures that control the conduits and/or barriers of groundwater flow. A detailed geochemical analysis of aquifer samples provide salinity of groundwater that will complement to the subsurface structures obtained from the geophysical study. This fundamental research in developing methods from an integrated approach to estimate aquifer quality can be used as an analog for similar studies in other arid regions.

  16. Heavy metals in European soils: A geostatistical analysis of the FOREGS geochemical database

    NARCIS (Netherlands)

    Rodríguez Lado, L.; Hengl, T.; Reuter, H.I.

    2008-01-01

    This paper presents the results of modeling the distribution of eight critical heavy metals (arsenic, cadmium, chromium, copper, mercury, nickel, lead and zinc) in topsoils using 1588 georeferenced samples from the Forum of European Geological Surveys Geochemical database (26 European countries).

  17. Exploration Review

    Science.gov (United States)

    Wilburn, D.R.; Stanley, K.A.

    2013-01-01

    This summary of international mineral exploration activities for 2012 draws upon information from industry sources, published literature and U.S. Geological Survey (USGS) specialists. The summary provides data on exploration budgets by region and mineral commodity, identifies significant mineral discoveries and areas of mineral exploration, discusses government programs affecting the mineral exploration industry and presents analyses of exploration activities performed by the mineral industry. Three sources of information are reported and analyzed in this annual review of international exploration for 2012: 1) budgetary statistics expressed in U.S. nominal dollars provided by SNL Metals Economics Group (MEG) of Halifax, Nova Scotia; 2) regional and site-specific exploration activities that took place in 2012 as compiled by the USGS and 3) regional events including economic, social and political conditions that affected exploration activities, which were derived from published sources and unpublished discussions with USGS and industry specialists.

  18. Exploring ethical considerations for the use of biological and physiological markers in population-based surveys in less developed countries

    Directory of Open Access Journals (Sweden)

    Hyder Adnan A

    2005-11-01

    Full Text Available Abstract Background The health information needs of developing countries increasingly include population-based estimates determined by biological and physiological measures. Collection of data on these biomarkers requires careful reassessment of ethical standards and procedures related to issues of safety, informed consent, reporting, and referral policies. This paper reviews the survey practices of health examination surveys that have been conducted in developed nations and discusses their application to similar types of surveys proposed for developing countries. Discussion The paper contends that a unitary set of ethical principles should be followed for surveys around the world that precludes the danger of creating double standards (and implicitly lowers standards for work done in developing countries. Global ethical standards must, however, be interpreted in the context of the unique historical and cultural context of the country in which the work is being done. Factors that influence ethical considerations, such as the relationship between investigators in developed and developing countries are also discussed. Summary The paper provides a set of conclusions reached through this discussion and recommendations for the ethical use of biomarkers in populations-based surveys in developing countries.

  19. On the need and use of models to explore the role of economic confidence:a survey.

    Energy Technology Data Exchange (ETDEWEB)

    Sprigg, James A.; Paez, Paul J. (University of New Mexico, Albuquerque, NM); Hand, Michael S. (University of New Mexico, Albuquerque, NM)

    2005-04-01

    Empirical studies suggest that consumption is more sensitive to current income than suggested under the permanent income hypothesis, which raises questions regarding expectations for future income, risk aversion, and the role of economic confidence measures. This report surveys a body of fundamental economic literature as well as burgeoning computational modeling methods to support efforts to better anticipate cascading economic responses to terrorist threats and attacks. This is a three part survey to support the incorporation of models of economic confidence into agent-based microeconomic simulations. We first review broad underlying economic principles related to this topic. We then review the economic principle of confidence and related empirical studies. Finally, we provide a brief survey of efforts and publications related to agent-based economic simulation.

  20. Organic geochemical constraints on paleoelevation

    Science.gov (United States)

    Polissar, P. J.; Rowley, D. B.; Currie, B. S.; Freeman, K. H.

    2012-12-01

    The elevation history of the land surface is an important factor in the interpretation of past tectonic, climate and ecological processes. However, quantitative estimates of paleoelevation are difficult to produce and new techniques are needed. Organic geochemical approaches to quantifying paleoelevations provide a new perspective on this difficult task. The hydrogen isotopic composition of organic biomarker molecules synthesized by plants and algae is systematically related to the water used for growth. Organic molecules in ancient sediments can provide values for the isotopic composition of this water and thus elevation, provided the relationship between elevation and isotopic values is known. Molecular hydrogen isotope ratios from Cenozoic lake sediments on the Tibetan Plateau demonstrate the utility of a biomarker approach. Terrestrial plant-wax D/H values on Neogene sediments from the Namling-Oiyug Basin provide new paleoelevation estimates that compare well with previous studies. Plant wax D/H ratios paired with lacustrine carbonate oxygen isotope values from the Lunpola and Hoh-Xil basins illustrate how paired isotope systems can unravel the isotopic composition of precipitation from evaporative enrichment of lake waters. A potentially fruitful avenue for future research is illustrated by D/H analyses on older sediments from the Namling-Oiyug Basin. These sediments—like many that could be useful for paleoaltimetry—have experienced significant burial and heating. As temperatures approach the oil window it becomes possible to exchange hydrogen in both the extractable organic molecules (bitumen) and the insoluble organic residue (kerogen). The extent to which this exchange alters the original isotopic composition will determine the usefulness of D/H analyses on thermally mature organic matter. The potential payoff and pitfalls of D/H analyses on heated sediments is illustrated with thermally immature and mature samples from the Namling-Oiyug Basin.

  1. The effect of scale on the interpretation of geochemical anomalies

    Science.gov (United States)

    Theobald, P.K.; Eppinger, R.G.; Turner, R.L.; Shiquan, S.

    1991-01-01

    The purpose of geochemical surveys changes with scale. Regional surveys identify areas where mineral deposits are most likely to occur, whereas intermediate surveys identify and prioritize specific targets. At detailed scales specific deposit models may be applied and deposits delineated. The interpretation of regional geochemical surveys must take into account scale-dependent difference in the nature and objectives of this type of survey. Overinterpretation of regional data should be resisted, as should recommendations to restrict intermediate or detailed follow-up surveys to the search for specific deposit types or to a too limited suite of elements. Regional surveys identify metallogenic provinces within which a variety of deposit types and metals are most likely to be found. At intermediate scale, these regional provinces often dissipate into discrete clusters of anomalous areas. At detailed scale, individual anomalous areas reflect local conditions of mineralization and may seem unrelated to each other. Four examples from arid environments illustrate the dramatic change in patterns of anomalies between regional and more detailed surveys. On the Arabian Shield, a broad regional anomaly reflects the distribution of highly differentiated anorogenic granites. A particularly prominent part of the regional anomaly includes, in addition to the usual elements related to the granites, the assemblage of Mo, W and Sn. Initial interpretation suggested potential for granite-related, stockwork Mo deposits. Detailed work identified three separate sources for the anomaly: a metal-rich granite, a silicified and stockwork-veined area with scheelite and molybdenite, and scheelite/powellite concentrations in skarn deposits adjacent to a ring-dike complex. Regional geochemical, geophysical and remote-sensing data in the Sonoran Desert, Mexico, define a series of linear features interpreted to reflect fundamental, northeast-trending fractures in the crust that served as the prime

  2. Major- and Trace-Element Concentrations in Soils from Northern California: Results from the Geochemical Landscapes Project Pilot Study

    Science.gov (United States)

    Morrison, Jean M.; Goldhaber, Martin B.; Holloway, JoAnn M.; Smith, David B.

    2008-01-01

    In 2004, the U.S. Geological Survey (USGS), the Geological Survey of Canada (GSC), and the Mexican Geological Survey (Servicio Geologico Mexicano, or SGM) initiated pilot studies in preparation for a soil geochemical survey of North America called the Geochemical Landscapes Project. The purpose of this project is to provide a better understanding of the variability in chemical composition of soils in North America. The data produced by this survey will be used to construct baseline geochemical maps for regions within the continent. Two initial pilot studies were conducted: (1) a continental-scale study involving a north-south and east-west transect across North America and (2) a regional-scale study. The pilot studies were intended to test and refine sample design, sampling protocols, and field logistics for the full continental soils geochemical survey. Smith and others (2005) reported the results from the continental-scale pilot study. The regional-scale California study was designed to represent more detailed, higher resolution geochemical investigations in a region of particular interest that was identified from the low-sample-density continental-scale survey. A 20,000-km2 area of northern California (fig. 1), representing a wide variety of topography, climate, and ecoregions, was chosen for the regional-scale pilot study. This study area also contains diverse geology and soil types and supports a wide range of land uses including agriculture in the Sacramento Valley, forested areas in portions of the Sierra Nevada, and urban/suburban centers such as Sacramento, Davis, and Stockton. Also of interest are potential effects on soil geochemistry from historical hard rock and placer gold mining in the foothills of the Sierra Nevada, historical mercury mining in the Coast Range, and mining of base-metal sulfide deposits in the Klamath Mountains to the north. This report presents the major- and trace-element concentrations from the regional-scale soil geochemical

  3. A National Survey Exploring School Nurses Knowledge and Experience When Working with Children with Autism Spectrum Disorders

    Science.gov (United States)

    McIntosh, Constance E.

    2013-01-01

    This study explored school nurses knowledge of the diagnostic criteria and secondary conditions related to Autism Spectrum Disorders (ASD), their involvement in the identification and treatment of ASD, their knowledge of medication used to treat ASD, and their overall medication management of children with ASD. Participants included 100 school…

  4. The effects of physical and geochemical heterogeneities on hydro-geochemical transport and effective reaction rates

    Science.gov (United States)

    Atchley, Adam L.; Navarre-Sitchler, Alexis K.; Maxwell, Reed M.

    2014-09-01

    The role of coupled physical and geochemical heterogeneities in hydro-geochemical transport is investigated by simulating three-dimensional transport in a heterogeneous system with kinetic mineral reactions. Ensembles of 100 physically heterogeneous realizations were simulated for three geochemical conditions: 1) spatially homogeneous reactive mineral surface area, 2) reactive surface area positively correlated to hydraulic heterogeneity, and 3) reactive surface area negatively correlated to hydraulic heterogeneity. Groundwater chemistry and the corresponding effective reaction rates were calculated at three transverse planes to quantify differences in plume evolution due to heterogeneity in mineral reaction rates and solute residence time (τ). The model is based on a hypothetical CO2 intrusion into groundwater from a carbon capture utilization and storage (CCUS) operation where CO2 dissolution and formation of carbonic acid created geochemical dis-equilibrium between fluids and the mineral galena that resulted in increased aqueous lead (Pb2 +) concentrations. Calcite dissolution buffered the pH change and created conditions of galena oversaturation, which then reduced lead concentrations along the flow path. Near the leak kinetic geochemical reactions control the release of solutes into the fluid, but further along the flow path mineral solubility controls solute concentrations. Simulation results demonstrate the impact of heterogeneous distribution of geochemical reactive surface area in coordination with physical heterogeneity on the effective reaction rate (Krxn,eff) and Pb2 + concentrations within the plume. Dissimilarities between ensemble Pb2 + concentration and Krxn,eff are attributed to how geochemical heterogeneity affects the time (τeq) and therefore advection distance (Leq) required for the system to re-establish geochemical equilibrium. Only after geochemical equilibrium is re-established, Krxn,eff and Pb2 + concentrations are the same for all three

  5. The effects of physical and geochemical heterogeneities on hydro-geochemical transport and effective reaction rates.

    Science.gov (United States)

    Atchley, Adam L; Navarre-Sitchler, Alexis K; Maxwell, Reed M

    2014-09-01

    The role of coupled physical and geochemical heterogeneities in hydro-geochemical transport is investigated by simulating three-dimensional transport in a heterogeneous system with kinetic mineral reactions. Ensembles of 100 physically heterogeneous realizations were simulated for three geochemical conditions: 1) spatially homogeneous reactive mineral surface area, 2) reactive surface area positively correlated to hydraulic heterogeneity, and 3) reactive surface area negatively correlated to hydraulic heterogeneity. Groundwater chemistry and the corresponding effective reaction rates were calculated at three transverse planes to quantify differences in plume evolution due to heterogeneity in mineral reaction rates and solute residence time (τ). The model is based on a hypothetical CO2 intrusion into groundwater from a carbon capture utilization and storage (CCUS) operation where CO2 dissolution and formation of carbonic acid created geochemical dis-equilibrium between fluids and the mineral galena that resulted in increased aqueous lead (Pb(2+)) concentrations. Calcite dissolution buffered the pH change and created conditions of galena oversaturation, which then reduced lead concentrations along the flow path. Near the leak kinetic geochemical reactions control the release of solutes into the fluid, but further along the flow path mineral solubility controls solute concentrations. Simulation results demonstrate the impact of heterogeneous distribution of geochemical reactive surface area in coordination with physical heterogeneity on the effective reaction rate (Krxn,eff) and Pb(2+) concentrations within the plume. Dissimilarities between ensemble Pb(2+) concentration and Krxn,eff are attributed to how geochemical heterogeneity affects the time (τeq) and therefore advection distance (Leq) required for the system to re-establish geochemical equilibrium. Only after geochemical equilibrium is re-established, Krxn,eff and Pb(2+) concentrations are the same for all

  6. Geochemical research of soil and attic dust in Litija area, Slovenia

    Directory of Open Access Journals (Sweden)

    Mateja Jemec

    2007-12-01

    Full Text Available Geochemical research was carried as part of the environmental research project at the Geological Survey of Slovenia. The aim of the project was to determine the impact on the environment caused by heavy metals released in the environment during mining and smeltingactivity in the area of Litija. The samples of attic dust and soil (0–5 cm were examined with the view to separate the natural distribution of chemical elements in the environment from the one caused by past mining and smelting activities. Based on chemically analyses we determine two main geochemical associations and their spatial distribution. First geochemical association (Al, Co, Ce, K, La, Li, Nb, Rb, Sc, Ta, Th in Ti is influencedmainlybynatural source, the second man-made association (As, Cd, Hg, Pb, Sb, Sn in Zn is caused mainly because of mining and lead smelting.

  7. Exploring opportunities to support mental health care using social media: A survey of social media users with mental illness.

    Science.gov (United States)

    Naslund, John A; Aschbrenner, Kelly A; McHugo, Gregory J; Unützer, Jürgen; Marsch, Lisa A; Bartels, Stephen J

    2017-10-20

    Social media holds promise for expanding the reach of mental health services, especially for young people who frequently use these popular platforms. We surveyed social media users who self-identified as having a mental illness to learn about their use of social media for mental health and to identify opportunities to augment existing mental health services. We asked 240 Twitter users who self-identified in their profile as having a mental illness to participate in an online survey. The survey was in English and inquired about participants' mental health condition, use of social media for mental health and interest in accessing mental health programs delivered through social media. Respondents from 10 countries completed 135 surveys. Most respondents were from the United States (54%), Canada (22%) and the United Kingdom (17%) and reported a psychiatric diagnosis of either schizophrenia spectrum disorder (27%), bipolar disorder (25%), major depressive disorder (16%) or depression (20%). Young adults age ≤35 (46%) were more likely to use Instagram (P = .002), Snapchat (P < .001) and their mobile phone for accessing social media (P < .001) compared to adults age 36 and older (53%). Most participants (85%) expressed interest in mental health programs delivered through social media, especially to promote overall health and wellbeing (72%) and for coping with mental health symptoms (90%). This exploratory study demonstrates the feasibility of reaching social media users with mental illness and can inform efforts to leverage social media to make evidence-based mental health services more widely available to those in need. © 2017 John Wiley & Sons Australia, Ltd.

  8. pplication of Fractal Technique for Analysis of Geophysical - Geochemical Databases in Tekieh Pb-Zn Ore Deposit (SE of Arak

    Directory of Open Access Journals (Sweden)

    Seyed Reza Mehrnia

    2017-02-01

    should emphasize on self-organized distribution of Pb-Zn anomalies to introduce a new set of nonlinear distributions in order to find the confidence regression coefficients between the variables. As the final results, fractal analysis of available databases represented new target areas with better mineralization aggregations than linear analysis of the anomalous regions according to micrographs. It means that surficial mineralization processes could be extended in depth and enriched next to altered host units because of a nonlinear but self-organized distribution of geochemical- geophysical anomalies in Tekieh ore deposit region. References Annells, R.N., Arthurton, R.S., Bazley, R.A.B., Davies, R.G., Hamedi, M.A.R. and Rahimzadeh, F.R., 1985. Geological Map of Shazand- Khomein. Scale: 1:100000, Cartographic Department of Geological Survey of Iran. Calagari, A.A., 2010. Principles of geophysical explorations. University of Tabriz, Tabriz, 485 pp. Jafari, H., 2007. Using geoelectrical techniques for Zn-Pb explorations in Haft-Emarat district, Tekieh region (South East of Arak. Kimya Kavan Tosee Novin Company, Tehran, 206 pp. Mandelbrot, B., 2005. Fractal Geometry of Nature. W.H Freeman & Company, New York, 468 pp. Mehrnia, S.R.,2013. Application of fractal geometry for recognizing the pattern of textural zoning in epithermal deposits: (case study: Shikhdarabad Au-Cu indices East- Azerbaijan province. Journal of Economic Geology, 5(1: 23-36. (in Persian Momenzadeh, M. and Ziseman, H., 1981. Lead – Zinc re mineralization potentials in Malayer – Esfahan district. Journal of Ore Deposit, 3(1: 88-101. Salehi, L., 2004. Geochemistry of REE content in Tekieh Pb-Zn ore deposit. M.Sc. Thesis, Shahid Beheshti University, Tehran, Iran, 181 pp. Torkashvand, S., Mehrnia, S.R. and Moghaddasi, S.J., 2009. Co-Processing of the geophysical parameters for Tekieh Zn-Pb ore deposits (south east of Arak. 4th PNU Geological National Conference, Payam Noor University of Mashhad, Mashhad

  9. Results from a national survey of health communication master's degree recipients: an exploration of training, placement, satisfaction, and success.

    Science.gov (United States)

    Edgar, Timothy; Gallagher, Susan Scavo; Silk, Kami J; Cruz, Tess Boley; Abroms, Lorien C; Evans, W Douglas; Finley, Anna Marie; Miller, Gregory A

    2015-01-01

    The field of health communication has seen substantial growth in recent years, but existing health communication research literature contains little information on individuals who practice health communication in applied settings. This study reports the results of a national survey that targeted the alumni of 5 institutions that offer a master's degree in health communication. Of the 522 total graduates to whom the survey was sent, 398 responded. Survey results provided information in a number of areas including undergraduate education background; criteria used to determine what type of master's degree in health communication to pursue; strategies used to gain employment; employment sector of first job after graduation; salaries received after completion of a master's degree in health communication; satisfaction with career choice after completion of master's degree; satisfaction with type of master's degree in health communication received; satisfaction with career choice after completion of master's degree; and the degree to which respondents felt their master's program in health communication prepared them to meet core competencies in the field. These findings have significant implications for the health communication field and the programs that prepare individuals for a career as a health communication practitioner.

  10. Geochemical evaluation of Niger Delta sedimentary organic rocks: a new insight

    Science.gov (United States)

    Akinlua, Akinsehinwa; Torto, Nelson

    2010-05-01

    A geochemical evaluation of Niger Delta organic matter was carried out using supercritical fluid extraction (SFE) sample preparation procedure. Comparison of geochemical significance of gas chromatographic data of rock extracts of SFE with those of Soxhlet extraction method from previous studies was made in order to establish the usefulness of SFE in geochemical exploration. The assessment of geochemical character of the rock samples from the comparison and interpretation of other geochemical parameters were used to give more insights into understanding the source rocks characteristics of onshore and shelf portions of the Niger Delta Basin. The results of the gas chromatographic (GC) analysis of the rock extracts across the lithostratigraphic units show that Pr/Ph, Pr/nC17, Pr/nC18, CPI and odd/even preference ranged from 0.07 to 12.39, 0.04 to 6.66, 0.05 to 13.80, 0.12 to 8.4 and 0.06 to 8.12, respectively. The Rock-Eval pyrolysis data and geochemical ratios and parameters calculated from the GC data showed that most of the samples are mature and have strong terrestrial provenance while a few samples have strong marine provenance. The few marine source rocks are located in the deeper depth horizon. Pr/Ph and standard geochemical plots indicate that most of samples were derived from organic matter deposited in less reducing conditions, i.e. more of oxidizing conditions while a few samples have predominantly influence of reducing conditions. The results of trace metal analysis of older samples from Agbada Formation also indicate marine and mixed organic matter input deposited in less reducing conditions. The results obtained in this study are comparable with those obtained from previous studies when Soxhlet extraction method was used and also indicated the presence of more than one petroleum systems in the Niger Delta.

  11. Exploring Graduate Students’ Attitudes towards Team Research and Their Scholarly Productivity: A Survey Guided by the Theory of Planned Behavior

    OpenAIRE

    Tianlan Wei; Alime N Sadikova; Lucy Barnard-Brak; Eugene W. Wang; Dilshod Sodikov

    2015-01-01

    This study explores the attitudinal and motivational factors underlying graduate students’ attitudes towards team research. Guided by the Theory of Planned Behavior, we hypothesize that attitude, subjective norm, and perceived behavioral control are three major determinants of graduate students’ intentions to conduct team research. An instrument was developed to measure the influences of these factors on students’ intentions and relevant scholarly productivity. A total of 281 graduate stud...

  12. Impacts of Hydrologic and Geochemical Uncertainty on Predicting Uranium Migration at the Hanford 300 Area

    Science.gov (United States)

    Chen, X.; Hammond, G. E.; Lichtner, P. C.; Rockhold, M. L.

    2011-12-01

    In modeling the uranium migration within the Integrated Field Research Challenge (IFRC) site at the Hanford 300 Area, the model simulations are affected by both the hydrologic and geochemical uncertainties. This study investigates the propagation of both types of uncertainty in the simulation of a uranium desorption experiment using a Monte-Carlo framework. The hydrologic uncertainty arises from estimating the transient flow boundary conditions induced by the dynamics in the Columbia River and the underlying heterogeneous hydraulic conductivity field, while the geochemical uncertainty is a result of limited knowledge in the geochemical reaction processes that take place in field and heterogeneity in source terms and reaction coefficients. We also evaluated the effectiveness of various conditioning data in reducing the uncertainty in the simulated uranium plume. For example, identifying the optimal boundary condition and estimating the 3D hydraulic conductivity field through inversion of concurrent conservative tracer test, and exploring the possibility of including the geophysical and geochemical data available at the site to characterize hydrologic and geochemical heterogeneities. The multi-realization capability of the parallel simulator, PFLOTRAN, enables this computationally demanding task to be completed within a reasonable turn-around time.

  13. A national survey exploring UK trainees' perceptions, core training experience, and decisions to pursue advanced training in breast radiology.

    Science.gov (United States)

    Lowes, S; Bydder, M; Sinnatamby, R

    2017-11-01

    To investigate UK radiology trainees' perceptions of breast radiology and the factors that influenced their decision whether or not to choose breast radiology as an area of special interest. An online survey was compiled and distributed to all UK specialty trainees in clinical radiology via the Royal College of Radiologists Junior Radiologists' Forum (JRF) regional representatives. There were 275 respondents, representing 22% of all UK radiology trainees. Responses were received from all regions. A significant factor identified in influencing whether or not trainees decide to pursue advanced training in breast radiology is the timing and quality of their initial core training experience. Specific positive aspects of breast radiology that were repeatedly identified included the high level of patient contact and frequent use of interventional procedures. Recurring negative aspects of breast radiology included isolation from general radiology and finding the subject matter boring. Breast radiology faces a significant workforce shortfall that is predicted to worsen in the coming years. There has never been a greater need to recruit specialty trainees into this field, and action is urgently needed to help ensure the sustainability of breast services and drive further improvements to patient care. The findings from this survey should be regarded as a challenge to all breast radiologists to engage with trainees from an early stage in their training and to enthuse them with the many positive aspects of a career in breast radiology. Copyright © 2017 The Royal College of Radiologists. Published by Elsevier Ltd. All rights reserved.

  14. National survey of crystalline rocks and recommendations of regions to be explored for high-level radioactive waste repository sites

    Energy Technology Data Exchange (ETDEWEB)

    Smedes, H.W.

    1983-04-01

    A reconnaissance of the geological literature on large regions of exposed crystalline rocks in the United States provides the basis for evaluating if any of those regions warrant further exploration toward identifying potential sites for development of a high-level radioactive waste repository. The reconnaissance does not serve as a detailed evaluation of regions or of any smaller subunits within the regions. Site performance criteria were selected and applied insofar as a national data base exists, and guidelines were adopted that relate the data to those criteria. The criteria include consideration of size, vertical movements, faulting, earthquakes, seismically induced ground motion, Quaternary volcanic rocks, mineral deposits, high-temperature convective ground-water systems, hydraulic gradients, and erosion. Brief summaries of each major region of exposed crystalline rock, and national maps of relevant data provided the means for applying the guidelines and for recommending regions for further study. It is concluded that there is a reasonable likelihood that geologically suitable repository sites exist in each of the major regions of crystalline rocks. The recommendation is made that further studies first be conducted of the Lake Superior, Northern Appalachian and Adirondack, and the Southern Appalachian Regions. It is believed that those regions could be explored more effectively and suitable sites probably could be found, characterized, verified, and licensed more readily there than in the other regions.

  15. Implementation of a guideline for local health policy making by regional health services: exploring determinants of use by a web survey.

    Science.gov (United States)

    Kuunders, Theo J M; Jacobs, Monique A M; Goor, Ien A M van de; Bon-Martens, Marja J H van; Oers, Hans A M van; Paulussen, Theo G W M

    2017-08-15

    Previous evaluation showed insufficient use of a national guideline for integrated local health policy by Regional Health Services (RHS) in the Netherlands. The guideline focuses on five health topics and includes five checklists to support integrated municipal health policies. This study explores the determinants of guideline use by regional Dutch health professionals. A web survey was send to 304 RHS health professionals. The questionnaire was based on a theory- and research-based framework of determinants of public health innovations. Main outcomes were guideline use and completeness of use, defined as the number of health topics and checklists used. Associations between determinants and (completeness of) guideline use were explored by multivariate regression models. The survey was started by 120 professionals (39%). Finally, results from 73 respondents (24%) were eligible for analyses. All 28 Dutch RHS organizations were represented in the final dataset. About half of the respondents (48%) used the guideline. The average score for completeness of use (potential range 1-10) was 2.37 (sd = 1.78; range 1-7). Knowledge, perceived task responsibility and usability were significantly related to guideline use in univariate analyses. Only usability remained significant in the multivariate model on guideline use. Only self-efficacy accounted for significant proportions of variance in completeness of use. The results imply that strategies to improve guideline use by RHSs should primarily target perceived usability. Self-efficacy appeared the primary target for improving completeness of guideline use. Methods for targeting these determinants in RHSs are discussed.

  16. Exploring the association between social capital and depressive symptoms: results of a survey in German information and communication technology companies.

    Science.gov (United States)

    Jung, Julia; Ernstmann, Nicole; Nitzsche, Anika; Driller, Elke; Kowalski, Christoph; Lehner, Birgit; Stieler-Lorenz, Brigitte; Friepörtner, Katharina; Schmidt, Anna; Pfaff, Holger

    2012-01-01

    This study examines the association between social capital at work and depressive symptoms in employees. Data for this cross-sectional study were collected through an online survey with the full population of employees from six companies in the German information and communication technology sector (response rate: 58.4%). A multivariate logistic regression analysis was performed. Results of data from a total of 328 employees suggest that, after controlling for sociodemographic factors, health awareness, and job strain, lower levels of perceived social capital at work are associated with the experience of depressive symptoms (OR = 0.76; 95% CI: 0.64-0.90). Our findings suggest that characteristics of high social capital at work, such as an established environment of trust and a sense of common values and convictions, could be an essential resource for preventing depressive disorders.

  17. Exploring the Use of information and communication technologies and social networks among university nursing faculty staff. An opinion survey

    Directory of Open Access Journals (Sweden)

    José Luis Fernández-Alemán

    2014-12-01

    Full Text Available Objective. This work sought to analyze the use of Information and Communication Technologies (ICTs and social networks among the university nursing faculty staff in Spain. Methodology. This was a descriptive, cross-sectional study using a questionnaire on ICT skills designed to comply with the research objective, which was evaluated by experts and which was subjected to exploratory analysis of principal components; the reliability of this instrument measured with Cronbach's alpha was 0.85. The information technology tool used to publish the questionnaire on line was Limesurvey. The sample comprised 165 professors from 25 Nursing Faculties and Schools from universities in Spain. Results. Seventy one percent of the total surveyed used internet services to look for information, 63% used the internet as a means for formation and learning, and 72% used it as a communication platform (e-mail and virtual platforms like Sakai and Moodle. Although 51% of the teaching staff surveyed had more than 120 students registered in their courses, hypothesis testing revealed that the number of students in class is not a determining factor for the teaching staff to have greater interest to update its knowledge in ICTs. Younger professors use new technologies more profusely and the most-valued advantage of using ICTs was quick access to information. Professors perceive that after the Bologna Declaration, which requires modifying their teaching-learning processes through the new teaching methodologies, a drop has been produced in their performance and that of their peers in their area of knowledge. Conclusion. The nursing teaching staff is making strong efforts to confront the new challenges posed by ICTs to train the professionals of the 21st century. It is fundamental to pay special attention to improving the university teaching staff's skills in managing ICTs, promoting the implementation of the knowledge acquired.

  18. Exploring the Use of information and communication technologies and social networks among university nursing faculty staff. An opinion survey.

    Science.gov (United States)

    Fernández-Alemán, José Luis; Sánchez García, Ana Belén; López Montesinos, María José; Marqués-Sánchez, Pilar; Bayón Darkistade, Enrique; Pérez Rivera, Francisco Javier

    2014-01-01

    This work sought to analyze the use of Information and Communication Technologies (ICTs) and social networks among the university nursing faculty staff in Spain. This was a descriptive, cross-sectional study using a questionnaire on ICT skills designed to comply with the research objective, which was evaluated by experts and which was subjected to exploratory analysis of principal components; the reliability of this instrument measured with Cronbach's alpha was 0.85. The information technology tool used to publish the questionnaire on line was Limesurvey. The sample comprised 165 professors from 25 Nursing Faculties and Schools from universities in Spain. Seventy one percent of the total surveyed used internet services to look for information, 63% used the internet as a means for formation and learning, and 72% used it as a communication platform (e-mail and virtual platforms like Sakai and Moodle). Although 51% of the teaching staff surveyed had more than 120 students registered in their courses, hypothesis testing revealed that the number of students in class is not a determining factor for the teaching staff to have greater interest to update its knowledge in ICTs. Younger professors use new technologies more profusely and the most-valued advantage of using ICTs was quick access to information. Professors perceive that after the Bologna Declaration, which requires modifying their teaching-learning processes through the new teaching methodologies, a drop has been produced in their performance and that of their peers in their area of knowledge. The nursing teaching staff is making strong efforts to confront the new challenges posed by ICTs to train the professionals of the 21st century. It is fundamental to pay special attention to improving the university teaching staff's skills in managing ICTs, promoting the implementation of the knowledge acquired.

  19. Exploring the characteristics, global distribution and reasons for retraction of published articles involving human research participants: a literature survey.

    Science.gov (United States)

    Li, Guowei; Kamel, Mariam; Jin, Yanling; Xu, Michael Kuan; Mbuagbaw, Lawrence; Samaan, Zainab; Levine, Mitchell Ah; Thabane, Lehana

    2018-01-01

    Article retraction is a measure taken by journals or authors where there is evidence of research misconduct or error, redundancy, plagiarism or unethical research. Recently, the retraction of scientific publications has been on the rise. In this survey, we aimed to describe the characteristics and distribution of retracted articles and the reasons for retractions. We searched retracted articles on the PubMed database and Retraction Watch website from 1980 to February 2016. The primary outcomes were the characteristics and distribution of retracted articles and the reasons for retractions. The secondary outcomes included how article retractions were handled by journals and how to improve the journal practices toward article retractions. We included 1,339 retracted articles. Most retracted articles had six authors or fewer. Article retraction was most common in the USA (26%), Japan (11%) and Germany (10%). The main reasons for article retraction were misconduct (51%, n = 685) and error (14%, n = 193). There were 66% (n = 889) of retracted articles having male senior or corresponding authors. Of the articles retracted after August 2010, 63% (n = 567) retractions were reported on Retraction Watch. Large discrepancies were observed in the ways that different journals handled article retractions. For instance, articles were completely withdrawn from some journals, while in others, articles were still available with no indication of retraction. Likewise, some retraction notices included a detailed account of the events that led to article retraction, while others only consisted of a statement indicating the article retraction. The characteristics, geographic distribution and reasons for retraction of published articles involving human research participants were examined in this survey. More efforts are needed to improve the consistency and transparency of journal practices toward article retractions.

  20. Geochemical variability of copper and iron in Oman margin sediments

    Digital Repository Service at National Institute of Oceanography (India)

    Alagarsamy, R.

    An analysis of the geochemical distribution of selected trace metals among various geochemical phases of the sediments in the Oman Margin was carried out using a sequential extraction technique. The present study showed that most Cu in abyssal...

  1. Heavy Metal Pollution Assessment by Partial Geochemical ...

    African Journals Online (AJOL)

    Mn and Fe oxides are powerful absorbents of heavy metal cations in soils and stream sediments therefore considered in this environmental geochemical investigation. Steam sediment samples were collected from Au-Ag and Pb-Zn-Cu mineralized areas of the Rodalquilar old gold mine, located in the southeastern part of ...

  2. Heavy Metal Pollution Assessment by Partial Geochemical ...

    African Journals Online (AJOL)

    Bheema

    Ni, Mo and P (Thompson, 1983). Table 2. Geochemical analytical procedure for the three leachates. Water extraction (W). Partial extraction (HA). Total extraction (AR). 10 gm,. 1gm. 1gm. Adding 25ml demineralized water. 20 ml of 0.25M hydroxylamine and 0.1M HCl solution. 5ml agua regia and 5ml demineralized water.

  3. Geochemical Investigation of Vertical Migration of Petroleum ...

    African Journals Online (AJOL)

    The investigation comprised bulk geochemical analyses in order to estimate various leakage indicators (S1 & PI). High Extractable Organic Matter (EOM) values of up to 6 mg/g rock were obtained in most of the samples. The high S1 and PI values obtained from the samples suggest oil staining. Furthermore, Iatroscan SARA ...

  4. A Geochemical Survey of Groundwater in Khana and Gokana Local ...

    African Journals Online (AJOL)

    Chloride contents in the water show salt-water encroachment into the aquifers in both areas. However, when compared with the World Health Organisation (WHO) standards for drinking water, the results show that the water is suitable for drinking and other domestic purposes in view of the parameters determined. It is also ...

  5. Current and future perspectives on lumbar degenerative disc disease: a UK survey exploring specialist multidisciplinary clinical opinion.

    Science.gov (United States)

    Deane, Janet A; McGregor, Alison H

    2016-09-15

    Despite lumbar degenerative disc disease (LDDD) being significantly associated with non-specific low back pain and effective treatment remaining elusive, specialist multidisciplinary clinical stakeholder opinion remains unexplored. The present study examines the views of such experts. A reliable and valid electronic survey was designed to establish trends using theoretical constructs relating to current assessment and management practices. Clinicians from the Society of Back Pain Research (SBPR) UK were invited to take part. Quantitative data were collated and coded using Bristol Online Surveys (BOS) software, and content analysis was used to systematically code and categorise qualitative data. Specialist multidisciplinary spinal interest group in the UK. 38/141 clinically active, multidisciplinary SBPR members with specialist spinal interest participated. Among them, 84% had >9 years postgraduate clinical experience. None. Frequency distributions were used to establish general trends in quantitative data. Qualitative responses were coded and categorised in relation to each theme and percentage responses were calculated. LDDD symptom recurrence, in the absence of psychosocial influence, was associated with physical signs of joint stiffness (26%), weakness (17%) and joint hypermobility (6%), while physical factors (21%) and the ability to adapt (11%) were postulated as reasons why some experience pain and others do not. No one management strategy was supported exclusively or with consensus. Regarding effective modalities, there was no significant difference between allied health professional and medic responses (p=0.1-0.8). The future of LDDD care was expressed in terms of improvements in patient communication (35%), patient education (38%) and treatment stratification (24%). Results suggest that multidisciplinary expert spinal clinicians appear to follow UK-based assessment guidelines with regard to recurrent LDDD; there are, however, inconsistencies in the

  6. Geobiochemistry: Placing Biochemistry in Its Geochemical Context

    Science.gov (United States)

    Shock, E.; Boyer, G. M.; Canovas, P. A., III; Prasad, A.; Dick, J. M.

    2014-12-01

    Goals of geobiochemistry include simultaneously evaluating the relative stabilities of microbial cells and minerals, and predicting how the composition of biomolecules can change in response to the progress of geochemical reactions. Recent developments in theoretical geochemistry make it possible to predict standard thermodynamic properties of proteins, nucleotides, lipids, and many metabolites including the constituents of the citric acid cycle, at all temperatures and pressures where life is known to occur, and beyond. Combining these predictions with constraints from geochemical data makes it possible to assess the relative stabilities of biomolecules. Resulting independent predictions of the environmental occurrence of homologous proteins and lipid side-chains can be compared with observations from metagenomic and metalipidomic data to quantify geochemical driving forces that shape the composition of biomolecules. In addition, the energetic costs of generating biomolecules from within a diverse range of habitable environments can be evaluated in terms of prevailing geochemical variables. Comparisons of geochemical bioenergetic calculations across habitats leads to the generalization that the availability of H2 determines the cost of autotrophic biosynthesis relative to the aquatic environment external to microbial cells, and that pH, temperature, pressure, and availability of C, N, P, and S are typically secondary. Increasingly reduced conditions, which are determined by reactions of water with mineral surfaces and mineral assemblages, allow many biosynthetic reactions to shift from costing energy to releasing energy. Protein and lipid synthesis, as well as the reverse citric acid cycle, become energy-releasing processes under these conditions. The resulting energy balances that determine habitability contrast dramatically with assumptions derived from oxic surface conditions, such as those where human biochemistry operates.

  7. Exploring the Nature of Galaxies with Abundance Gradient Anomalies in the SDSS-IV/MaNGA Survey

    Science.gov (United States)

    Keith, Celeste; Tremonti, Christy; Pace, Zach; Schaefer, Adam

    2018-01-01

    Disk galaxies are known to have radial oxygen abundance gradients with their centers being more chemically enriched than their outskirts. The steepness of the abundance gradient has recently been shown to correlate with galaxy stellar mass, on average. However, individual galaxies sometimes show pronounced deviations from the expected trends, such as flatter or steeper slopes than expected for their mass, abrupt changes in slope, or azimuthal asymmetries. Here we report on a systematic search for galaxies with abundance gradient anomalies using 2-D spectroscopy from the Sloan Digital Sky Survey IV MaNGA. We construct nebular oxygen and nitrogen abundance maps for 300 moderately inclined non-interacting disk galaxies and use visual inspection to identify the most interesting cases. We use this training set to develop an automated pipeline to flag galaxies with abundance anomalies from the larger MaNGA dataset for visual inspection. We combine the metallicity maps with kinematic data and measurements of the galaxies' local environments to better understand the processes that shape the radial abundance gradients of disk galaxies.

  8. Exploring the relationship between social class, mental illness stigma and mental health literacy using British national survey data.

    Science.gov (United States)

    Holman, Daniel

    2015-07-01

    The relationship between social class and mental illness stigma has received little attention in recent years. At the same time, the concept of mental health literacy has become an increasingly popular way of framing knowledge and understanding of mental health issues. British Social Attitudes survey data present an opportunity to unpack the relationships between these concepts and social class, an important task given continuing mental health inequalities. Regression analyses were undertaken which centred on depression and schizophrenia vignettes, with an asthma vignette used for comparison. The National Statistics Socio-economic Classification, education and income were used as indicators of class. A number of interesting findings emerged. Overall, class variables showed a stronger relationship with mental health literacy than stigma. The relationship was gendered such that women with higher levels of education, especially those with a degree, had the lowest levels of stigma and highest levels of mental health literacy. Interestingly, class showed more of an association with stigma for the asthma vignette than it did for both the depression and schizophrenia vignettes, suggesting that mental illness stigma needs to be contextualised alongside physical illness stigma. Education emerged as the key indicator of class, followed by the National Statistics Socio-economic Classification, with income effects being marginal. These findings have implications for targeting health promotion campaigns and increasing service use in order to reduce mental health inequalities. © The Author(s) 2014.

  9. Food crop production, nutrient availability, and nutrient intakes in Bangladesh: exploring the agriculture-nutrition nexus with the 2010 Household Income and Expenditure Survey.

    Science.gov (United States)

    Fiedler, John L

    2014-12-01

    Systematic collection of national agricultural data has been neglected in many low- and middle-income countries for the past 20 years. Commonly conducted nationally representative household surveys collect substantial quantities of highly underutilized food crop production data. To demonstrate the potential usefulness of commonly available household survey databases for analyzing the agriculture-nutrition nexus. Using household data from the 2010 Bangladesh Household Income and Expenditure Survey, the role and significance of crop selection, area planted, yield, nutrient production, and the disposition of 34 food crops in affecting the adequacy of farming households' nutrient availability and nutrient intake status are explored. The adequacy of each farming household's available energy, vitamin A, calcium, iron, and zinc and households' apparent intakes and intake adequacies are estimated. Each household's total apparent nutrient intake adequacies are estimated, taking into account the amount of each crop that households consume from their own production, together with food purchased or obtained from other sources. Even though rice contains relatively small amounts of micronutrients, has relatively low nutrient density, and is a relatively poor source of nutrients compared with what other crops can produce on a given tract of land, because so much rice is produced in Bangladesh, it is the source of 90% of the total available energy, 85% of the zinc, 67% of the calcium, and 55% of the iron produced by the agricultural sector. The domination of agriculture and diet by rice is a major constraint to improving nutrition in Bangladesh. Simple examples of how minor changes in the five most common cropping patterns could improve farming households' nutritional status are provided. Household surveys' agricultural modules can provide a useful tool for better understanding national nutrient production realities and possibilities.

  10. Exploring risk factors associated with intimate partner violence in Vietnam: results from a cross-sectional national survey.

    Science.gov (United States)

    Jansen, Henrica A F M; Nguyen, Thi Viet Nga; Hoang, Tu Anh

    2016-11-01

    Empirical evidence documents that some risk factors for intimate partner violence (IPV) are similar across contexts, while others differ considerably. In Vietnam, there was a need to investigate risk factors for IPV to support evidence-based policy and programming. Using the dataset gathered in the 2010 National Study on Domestic Violence against Women, forty variables were explored in logistic regression analysis, including socio-demographic characteristics of women and their husbands, other experiences with violence, husband's behaviours, family support, and context-specific variables such as the sex of their children. Fifteen independent factors remained strongly associated with IPV. Significant risk was associated with husbands' behaviour that supports male power (extra-marital relationships; fighting with other men) and alcohol use. Violence experienced in childhood increased the likelihood of women experiencing and of men perpetrating IPV. Notable was further the association with women's higher financial contribution to the household and lack of association with not having sons. The findings support theories describing how underlying gender and power imbalance are fundamental causes of IPV and indicate the need for context-specific interventions.

  11. Exploring the choice to refuse or delay vaccines: a national survey of parents of 6- through 23-month-olds.

    Science.gov (United States)

    McCauley, Mary Mason; Kennedy, Allison; Basket, Michelle; Sheedy, Kristine

    2012-01-01

    The purpose of this study was to assess respondents' self-reported choices for vaccinating their young children; knowledge, attitudes, and beliefs (KABs) about vaccination; and communication with their child's vaccination provider. A national telephone survey of 1500 parents of children aged 6 to 23 months was conducted in 2010. We calculated proportions of parents who had chosen-or planned-to refuse or delay 1 or more recommended vaccines, and proportions for responses to KABs and communication questions, stratified by vaccination choice (ie, refuse or delay). The response rate was 46%. Among the 96.6% of respondents (95% confidence interval [CI], 95.5%-97.4%; weighted n = 1453) who had chosen for their child to receive at least 1 vaccine, 80.6% (95% CI, 78.8%-83.0%) reported that their child had received all vaccines when recommended and 86.5% (95% CI, 84.7%-88.2%) reported that their child would receive remaining vaccines when recommended. Respondents who considered not following recommendations, but ultimately did, cited the physician's recommendation as the reason for vaccinating. Most vaccinators who reported past or planned deviations from recommendations cited only 1 vaccine that they would refuse and/or delay; all vaccines were mentioned. These parents reported approaching vaccination with serious concerns, while believing other parents did not. All parents cited "vaccine side effects" as their top question or concern. Almost all parents talked to a doctor or nurse about vaccines and, overall, satisfaction with communication was high. Communication about vaccines is important to most parents, but may be challenging for providers, because parental choices vary; thus, efforts to improve and support vaccine communication by providers should continue. Published by Elsevier Inc.

  12. Exploring racial influences on flu vaccine attitudes and behavior: Results of a national survey of White and African American adults.

    Science.gov (United States)

    Quinn, Sandra Crouse; Jamison, Amelia; Freimuth, Vicki S; An, Ji; Hancock, Gregory R; Musa, Donald

    2017-02-22

    Racial disparities in adult flu vaccination rates persist with African Americans falling below Whites in vaccine acceptance. Although the literature has examined traditional variables including barriers, access, attitudes, among others, there has been virtually no examination of the extent to which racial factors including racial consciousness, fairness, and discrimination may affect vaccine attitudes and behaviors. We contracted with GfK to conduct an online, nationally representative survey with 819 African American and 838 White respondents. Measures included risk perception, trust, vaccine attitudes, hesitancy and confidence, novel measures on racial factors, and vaccine behavior. There were significant racial differences in vaccine attitudes, risk perception, trust, hesitancy and confidence. For both groups, racial fairness had stronger direct effects on the vaccine-related variables with more positive coefficients associated with more positive vaccine attitudes. Racial consciousness in a health care setting emerged as a more powerful influence on attitudes and beliefs, particularly for African Americans, with higher scores on racial consciousness associated with lower trust in the vaccine and the vaccine process, higher perceived vaccine risk, less knowledge of flu vaccine, greater vaccine hesitancy, and less confidence in the flu vaccine. The effect of racial fairness on vaccine behavior was mediated by trust in the flu vaccine for African Americans only (i.e., higher racial fairness increased trust in the vaccine process and thus the probability of getting a flu vaccine). The effect of racial consciousness and discrimination for African Americans on vaccine uptake was mediated by perceived vaccine risk and flu vaccine knowledge. Racial factors can be a useful new tool for understanding and addressing attitudes toward the flu vaccine and actual vaccine behavior. These new concepts can facilitate more effective tailored and targeted vaccine communications

  13. Adjustment to hand injury: Cross-sectional survey exploring adjustment in relation to illness perceptions and coping strategies.

    Science.gov (United States)

    Turkington, Catherine; Dempster, Martin; Maguire, Jennifer

    2017-07-03

    Cross-sectional descriptive. Hand injuries are highly prevalent, and the impact they have on physical, emotional, and functional adjustment is well recognized. Increasingly, adjustment to health conditions including hand injuries is being understood in terms of psychological variables. To examine the role of illness beliefs and coping strategies in adjustment to hand injury. Adjustment was considered from a complete perspective including quality of life (QOL) and functional ability as well as mood and trauma symptoms. Cross-sectional survey whereby consecutive patients (n = 65) attending the regional plastic surgery service with hand injuries were invited to complete a questionnaire assessing illness perceptions, coping strategies, QOL, hand functioning, depression, and trauma symptoms. Data were analyzed in SPSS (IBM Corporation, Armonk, NY) by correlation and then hierarchical regression analysis. Illness perceptions and coping strategies were significantly related to the adjustment outcomes (hand functioning, QOL, depression, and trauma symptoms). Specifically, poorer adjustment was associated with more negative illness beliefs (r = 0.31-0.47), greater use of denial (r = 0.24-0.53), and avoidance-based (r = 0.41-0.64) coping strategies. Illness beliefs and coping play an important role in adjustment after hand injury. Adjustment is multifaceted with a need to consider physical and emotional functioning. More optimistic beliefs and adaptive coping styles are associated with improved adjustment. The role of psychological variables in optimizing adjustment is an important consideration for the design of psychological interventions, but because this study was cross sectional and cannot assume directional effects, future longitudinal studies are needed. N/A. Copyright © 2017 Hanley & Belfus. Published by Elsevier Inc. All rights reserved.

  14. The Impact of Carsharing on Public Transit and Non-Motorized Travel: An Exploration of North American Carsharing Survey Data

    Directory of Open Access Journals (Sweden)

    Susan Shaheen

    2011-11-01

    Full Text Available By July 2011, North American carsharing had grown to an industry of nearly 640,000 members since its inception on the continent more than 15 years ago. Carsharing engenders changes in member travel patterns both towards and away from public transit and non-motorized modes. This study, which builds on the work of two previous studies, evaluates this shift in travel based on a 6281 respondent survey completed in late-2008 by members of major North American carsharing organizations. Across the entire sample, the results showed an overall decline in public transit use that was statistically significant, as 589 carsharing members reduced rail use and 828 reduced bus use, while 494 increased rail use and 732 increased bus use. Thus for every five members that use rail less, four members use rail more, and for every 10 members that ride a bus less, almost nine members ride the bus more. The people increasing and decreasing their transit use are fundamentally different in terms of how carsharing impacts their travel environment. This reduction, however, is also not uniform across all organizations; it is primarily driven by a minority (three of eleven of participating organizations. At the same time, members exhibited a statistically significant increase in travel by walking, bicycling, and carpooling. Across the sample, 756 members increased walking versus a 568 decrease, 628 increased bicycling versus a 235 decrease, and 289 increased carpooling versus a decrease of 99  study participants. The authors found that 970 members reduced their auto commuting to work, while 234 increased it. Interestingly, when these shifts are combined across modes, more people increased their overall public transit and non-motorized modal use after joining carsharing than decreased it. Data collected on the commute distance of respondents found that carsharing members tend to have shorter commutes than most people living in the same zip code. The analysis also evaluates

  15. Geochemical engineering problem identification and program description. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Crane, C.H.; Kenkeremath, D.C.

    1981-05-01

    The Geochemical Engineering Program has as its goal the improvement of geochemical fluid management techniques. This document presents the strategy and status of the Geochemical Engineering Program. The magnitude and scope of geochemical-related problems constraining geothermal industry productivity are described. The goals and objectives of the DGE Geochemical Engineering Program are defined. The rationale and strategy of the program are described. The structure, priorities, funding, and management of specific elements within the program are delineated, and the status of the overall program is presented.

  16. A geochemical examination of humidity cell tests

    Science.gov (United States)

    Maest, Ann; Nordstrom, D. Kirk

    2017-01-01

    Humidity cell tests (HCTs) are long-term (20 to >300 weeks) leach tests that are considered by some to be the among the most reliable geochemical characterization methods for estimating the leachate quality of mined materials. A number of modifications have been added to the original HCT method, but the interpretation of test results varies widely. We suggest that the HCTs represent an underutilized source of geochemical data, with a year-long test generating approximately 2500 individual chemical data points. The HCT concentration peaks and valleys can be thought of as a “chromatogram” of reactions that may occur in the field, whereby peaks in concentrations are associated with different geochemical processes, including sulfate salt dissolution, sulfide oxidation, and dissolution of rock-forming minerals, some of which can neutralize acid. Some of these reactions occur simultaneously, some do not, and geochemical modeling can be used to help distinguish the dominant processes. Our detailed examination, including speciation and inverse modeling, of HCTs from three projects with different geology and mineralization shows that rapid sulfide oxidation dominates over a limited period of time that starts between 40 and 200 weeks of testing. The applicability of laboratory tests results to predicting field leachate concentrations, loads, or rates of reaction has not been adequately demonstrated, although early flush releases and rapid sulfide oxidation rates in HCTs should have some relevance to field conditions. Knowledge of possible maximum solute concentrations is needed to design effective treatment and mitigation approaches. Early flush and maximum sulfide oxidation results from HCTs should be retained and used in environmental models. Factors that complicate the use of HCTs include: sample representation, time for microbial oxidizers to grow, sample storage before testing, geochemical reactions that add or remove constituents, and the HCT results chosen for use

  17. Soil gas geochemical behaviour across buried and exposed faults during the 24 august 2016 central Italy earthquake

    Directory of Open Access Journals (Sweden)

    Giancarlo Ciotoli

    2016-12-01

    Full Text Available Following the earthquake (ML=6.0 of 24 August 2016 that affected large part of the central Apennine between the municipalities of Norcia (PG and Amatrice (RI (central Italy, two soil gas profiles (i.e., 222Rn, 220Rn, CO2 and CO2 flux were carried out across buried and exposed coseismic fault rupture of the Mt. Vettore fault during the seismic sequence. The objective of the survey was to explore the mechanisms of migration and the spatial behaviour of different gas species near still-degassing active fault. Results provide higher gas and CO2 flux values (about twice for 222Rn and CO2 flux in correspondence of the buried sector of the fault than those measured across the exposed coseismic rupture. Anomalous peaks due to advective migration are clearly visible on both side of the buried fault (profile 1, whereas the lower soil gas concentrations measured across the exposed coseimic rupture (profile 2 are mainly caused by shallow and still acting diffusive degassing associated to faulting during the seismic sequence. These results confirm the usefulness of the soil gas survey to spatially recognise the shallow geometry of hidden faults, and to discriminate the geochemical migration mechanisms occurring at buried and exposed faults related to seismic activity.

  18. A survey exploring factors associated with 2890 companion-rabbit owners' knowledge of rabbit care and the neuter status of their companion rabbit.

    Science.gov (United States)

    Welch, Tasha; Coe, Jason B; Niel, Lee; McCobb, Emily

    2017-02-01

    Pet owners' knowledge of pet care has been shown to affect the human-animal relationship and the welfare of companion animals. With rabbits being the third most common companion animal in many regions, and evidence of owners' lack of awareness for the standards of care required to care for companion rabbits, it is important to understand the knowledge level of rabbit owners and determine how companion rabbits are being cared for. The purpose of this study was to survey rabbit owners in order to explore factors associated with their knowledge of rabbit care, and the neuter status of their companion rabbit. Current rabbit owners (n=2890) completed an online survey investigating acquisition of their companion rabbit, husbandry and care of their current rabbit, neuter status of their rabbit, owners' knowledge of rabbit care and owners' attachment to their current rabbit. An approximation of logistic regression modeling revealed increasing attachment (powners, the current study suggests acquisition sources, veterinarians, and companion-animal professionals can have an important role in the development of companion-rabbit owners' knowledge of rabbit care and in promoting the importance of neutering companion rabbits. Efforts to develop accessible resources to assist with educating companion-rabbit owners is important to ensuring successful rabbit-owner relationships. Copyright © 2016 Elsevier B.V. All rights reserved.

  19. Using Short Dietary Questions to Develop Indicators of Dietary Behaviour for Use in Surveys Exploring Attitudinal and/or Behavioural Aspects of Dietary Choices.

    Science.gov (United States)

    Daly, Alison; Pollard, Christina M; Kerr, Deborah A; Binns, Colin W; Phillips, Michael

    2015-08-04

    For countries where nutrition surveys are infrequent, there is a need to have some measure of healthful eating to plan and evaluate interventions. This study shows how it is possible to develop healthful eating indicators based on dietary guidelines from a cross sectional population survey. Adults 18 to 64 years answered questions about the type and amount of foods eaten the previous day, including fruit, vegetables, cereals, dairy, fish or meat and fluids. Scores were based on serves and types of food according to an established method. Factor analysis indicated two factors, confirmed by structural equation modeling: a recommended food healthful eating indicator (RF_HEI) and a discretionary food healthful eating indicator (DF_HEI). Both yield mean scores similar to an established dietary index validated against nutrient intake. Significant associations for the RF_HEI were education, income, ability to save, and attitude toward diet; and for the DF_HEI, gender, not living alone, living in a socially disadvantaged area, and attitude toward diet. The results confirm that short dietary questions can be used to develop healthful eating indicators against dietary recommendations. This will enable the exploration of dietary behaviours for "at risk" groups, such as those with excess weight, leading to more relevant interventions for populations.

  20. Using Short Dietary Questions to Develop Indicators of Dietary Behaviour for Use in Surveys Exploring Attitudinal and/or Behavioural Aspects of Dietary Choices

    Directory of Open Access Journals (Sweden)

    Alison Daly

    2015-08-01

    Full Text Available For countries where nutrition surveys are infrequent, there is a need to have some measure of healthful eating to plan and evaluate interventions. This study shows how it is possible to develop healthful eating indicators based on dietary guidelines from a cross sectional population survey. Adults 18 to 64 years answered questions about the type and amount of foods eaten the previous day, including fruit, vegetables, cereals, dairy, fish or meat and fluids. Scores were based on serves and types of food according to an established method. Factor analysis indicated two factors, confirmed by structural equation modeling: a recommended food healthful eating indicator (RF_HEI and a discretionary food healthful eating indicator (DF_HEI. Both yield mean scores similar to an established dietary index validated against nutrient intake. Significant associations for the RF_HEI were education, income, ability to save, and attitude toward diet; and for the DF_HEI, gender, not living alone, living in a socially disadvantaged area, and attitude toward diet. The results confirm that short dietary questions can be used to develop healthful eating indicators against dietary recommendations. This will enable the exploration of dietary behaviours for “at risk” groups, such as those with excess weight, leading to more relevant interventions for populations.

  1. Geochemical origins of sedimentary benzoporphyrins and tetrahydrobenzoporphyrins

    Energy Technology Data Exchange (ETDEWEB)

    Lash, T.D. (Illinois State University, Normal, IL (USA). Dept. of Chemistry)

    Complex mixtures of metalloporphyrins are associated with organic-rich sediments. Although some of these petroporphyrins have been correlated with known biological pigments, the origins of certain structures are obscure. Benzoporphyrins and tetrahydrobenzoporphyrins, two minor families of geological tetrapyrroles, have been isolated from numerous oil shales and petroleums but the origins of these molecular fossils are poorly understood. A number of possible pathways for the geochemical formation of benzo- and tetrahydrobenzoporphyrins are discussed. The data presently available favours a Diels-Alder cycloaddition mechanism between putative divinylchlorophyll and quinone precursors for the formation of these compounds. As an aid to these duties, total syntheses of benzo- and naphthoporphyrins have been carried out and the spectroscopic properties of these extended chromophores are discussed. Further studies are proposed to help distinguish between the various possible pathways for the geochemical genesis of tetrahydrobenzo- and benzoporphyrins. 62 refs., 2 figs.

  2. Exploring the views and experiences of callers to the PANDA Post and Antenatal Depression Association Australian National Perinatal Depression Helpline: a cross-sectional survey.

    Science.gov (United States)

    Biggs, Laura J; Shafiei, Touran; Forster, Della A; Small, Rhonda; McLachlan, Helen L

    2015-09-07

    Anxiety and depression are common in the perinatal period. Telephone interventions, including telephone peer support and counselling, have been developed to support those experiencing perinatal mental illness. PANDA Post and Antenatal Depression Association provides support to women and men experiencing perinatal mental illness via the Australian National Perinatal Depression Helpline, encompassing both volunteer peer support and professional counselling. This study aimed to explore the experiences of callers to the Helpline. A cross-sectional survey design was used. All new callers from 1(st) May to 30(th) September 2013 were invited to participate. The survey, adapted from a previous survey of PANDA callers, included 23 questions using Likert-type scales, demographic and open-ended questions. Thematic network analysis was undertaken for responses to open-ended questions. 124 responses were received (124/405; 30% response). The majority of callers had called the Helpline regarding themselves (90%), with over one third (33%) of all callers seeking crisis support and help. Ninety-nine per cent of respondents 'agreed' or 'strongly agreed' that staff and/or volunteers understood their concerns, and 97% 'agreed' or 'strongly agreed' that overall PANDA had helped them. Callers described the PANDA service as uniquely tailored to the perinatal period, providing accessible, non-judgemental understanding and support, with a global theme from open-ended comments describing PANDA as 'a safe space to be heard and receive support without judgement'. Recommendations for service changes included increased hours of availability. Callers reported positive experiences of accessing support from the PANDA National Perinatal Depression Helpline. The Helpline was described as an accessible and acceptable telephone support for individuals experiencing perinatal mental illness. Recommendations for changes to the service included an increase in hours of operation to enable greater

  3. USGS exploration geochemistry studies at the Pebble porphyry Cu-Au-Mo deposit, Alaska-pdf of presentation

    Science.gov (United States)

    Eppinger, Robert G.; Kelley, Karen D.; Fey, David L.; Giles, Stuart A.; Minsley, Burke J.; Smith, Steven M.

    2010-01-01

    From 2007 through 2010, scientists in the U.S. Geological Survey (USGS) have been conducting exploration-oriented geochemical and geophysical studies in the region surrounding the giant Pebble porphyry Cu-Au-Mo deposit in southwestern Alaska. The Cretaceous Pebble deposit is concealed under tundra, glacial till, and Tertiary cover rocks, and is undisturbed except for numerous exploration drill holes. These USGS studies are part of a nation-wide research project on evaluating and detecting concealed mineral resources. This report focuses on exploration geochemistry and comprises illustrations and associated notes that were presented as a case study in a workshop on this topic. The workshop, organized by L.G. Closs and R. Glanzman, is called 'Geochemistry in Mineral Exploration and Development,' presented by the Society of Economic Geologists at a technical conference entitled 'The Challenge of Finding New Mineral Resources: Global Metallogeny, Integrative Exploration and New Discoveries,' held at Keystone, Colorado, October 2-5, 2010.

  4. Geochemical patterns in the soils of Cyprus.

    Science.gov (United States)

    Cohen, David R; Rutherford, Neil F; Morisseau, Eleni; Zissimos, Andreas M

    2012-03-15

    The soil geochemical atlas of Cyprus is a recent addition to the series of national to continental-scale geochemical mapping programmes implemented over the last two decades for environmental and resource applications. The study has been conducted at the high sampling density of 1 site per 1km(2), with multi-element and multi-method analysis performed on samples of top soil (0-25cm) and sub soil (50-75cm) from a grid of over 5350 sites across a major portion of Cyprus. Major and most trace elements display sharp concentration changes across the main geological boundaries but a high degree of spatial continuity and consistency of values within those boundaries. Some elements display one to two orders of magnitude difference in median concentrations between the soils developed over ultramafic or mafic units and those developed over sedimentary rocks or alluvial units. The ratio of aqua regia-extractable to total metal contents provides an indication of the general mineralogical host for a number of trace elements. The majority of soils are near-neutral to alkaline with the small proportion of areas with soil pHmapping local to regional-scale features of the geochemical landscape. Copyright © 2012 Elsevier B.V. All rights reserved.

  5. Monitoring active volcanoes: The geochemical approach

    Directory of Open Access Journals (Sweden)

    Takeshi Ohba

    2011-06-01

    Full Text Available

    The geochemical surveillance of an active volcano aims to recognize possible signals that are related to changes in volcanic activity. Indeed, as a consequence of the magma rising inside the volcanic "plumbing system" and/or the refilling with new batches of magma, the dissolved volatiles in the magma are progressively released as a function of their relative solubilities. When approaching the surface, these fluids that are discharged during magma degassing can interact with shallow aquifers and/or can be released along the main volcano-tectonic structures. Under these conditions, the following main degassing processes represent strategic sites to be monitored.

    The main purpose of this special volume is to collect papers that cover a wide range of topics in volcanic fluid geochemistry, which include geochemical characterization and geochemical monitoring of active volcanoes using different techniques and at different sites. Moreover, part of this volume has been dedicated to the new geochemistry tools.

  6. Geochemical and mineralogical maps for soils of the conterminous United States

    Science.gov (United States)

    Smith, David B.; Cannon, William F.; Woodruff, Laurel G.; Solano, Federico; Ellefsen, Karl J.

    2014-01-01

    The U.S. Geological Survey began sampling in 2007 for a low-density (1 site per 1,600 square kilometers, 4,857 sites) geochemical and mineralogical survey of soils in the conterminous United States as part of the North American Soil Geochemical Landscapes Project. The sampling protocol for the national-scale survey included, at each site, a sample from a depth of 0 to 5 centimeters, a composite of the soil A horizon, and a deeper sample from the soil C horizon or, if the top of the C horizon was at a depth greater than 1 meter, a sample from a depth of approximately 80–100 centimeters. The mineralogical components in the samples from the soil A and C horizons were determined by a quantitative X-ray diffraction method using Rietveld refinement. Sampling in the conterminous United States was completed in 2010, with chemical and mineralogical analyses completed in May 2013. The resulting data set provides an estimate of the abundance and spatial distribution of chemical elements and minerals in soils of the conterminous United States and represents a baseline for soil geochemistry and mineralogy against which future changes may be recognized and quantified. This report releases geochemical and mineralogical maps along with a histogram, boxplot, and empirical cumulative distribution function plot for each element or mineral.

  7. Leachate Geochemical Results for Ash and Burned Soil Samples from the October 2007 Southern California Wildfires

    Science.gov (United States)

    Hageman, Philip L.; Plumlee, Geoffrey S.; Martin, Deborah A.; Hoefen, Todd M.; Meeker, Gregory P.; Adams, Monique; Lamothe, Paul J.; Anthony, Michael W.

    2008-01-01

    This report is the second release of leachate geochemical data included as part of a multidisciplinary study of ash and burned soil samples from the October 2007 wildfires in southern California. Geochemical data for the first set of samples were released in an Open-File Report (Plumlee and others, 2007). This study is a continuation of that work. The objectives of this leaching study are to aid in understanding the interactions of ash and burned soil with rainfall. For this study, 12 samples collected in early November 2007 were leached using the U.S. Geological Survey (USGS) Field Leach Test (FLT). Following leaching, sub-samples of the leachate were analyzed for pH and specific conductance. The leachate was then filtered, and aliquots were preserved for geochemical analysis. This report presents leachate geochemical data for pH, specific conductance, alkalinity, anions using ion chromatography (I.C.), cations using inductively coupled plasma?atomic mass spectrometry (ICP-MS), and mercury by continuous flow injection?cold vapor?atomic fluorescence (CVAFS).

  8. Qualitative Exploration of the Potential for Adverse Events When Using an Online Peer Support Network for Mental Health: Cross-Sectional Survey.

    Science.gov (United States)

    Easton, Katherine; Diggle, Jacob; Ruethi-Davis, Mabel; Holmes, Megan; Byron-Parker, Darian; Nuttall, Jessica; Blackmore, Chris

    2017-10-30

    Online peer support networks are a growing area of mental health support for offering social connection, identity, and support. However, it has been reported that not all individuals have a positive experience on such networks. The potential for adverse events within a moderated online peer support network is a new area of research exploration. The objective of the study was to determine if use of an online moderated peer networks leads to adverse events for users. Four biannual online surveys (October 2014 to March 2016) were conducted by a large national UK mental health charity, with users of their online peer support network exploring personal safety, moderation, experiences on the site, and how the site could be improved. Data were analyzed using thematic analysis by 2 independent researchers using a priori themes: negative experiences of moderation, social exclusion, contagion, negative interactions with other users, online relationships, co-rumination and collusion, and other. In total, 2353 survey responses were logged with 197 (8.37%) documenting an adverse event of negative experience. A dominant theme of negative experiences of moderation emerged (73/197, 37.1%) with evidence of social exclusion (50/197, 25.4%). Reading user posts was shown to be a cause of worry and distress for a few users, and analysis highlighted several instances of depressogenic and emotional contagion as well as some limited evidence of behavioral contagion (46/197, 23.4%). Very limited evidence of co-rumination (1/197, 0.5%) and no evidence of collusion were identified. Evidence of adverse events was identified at low levels in the sample of respondents, although we have no comparison data to indicate if levels are low compared with comparable platforms. Not all users of online peer support networks find them wholly beneficial. Research must explore what works for whom. The next stage of service development should consider which users may be likely to receive no benefit, or even

  9. Evaluation of selected geochemical anomalies in Colorado and the Southeastern US. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Carpenter, R H

    1980-08-01

    This study demonstrates the utility of HSSR geochemical data from stream sediment in exploration for uranium. In the southeastern US, four uraniferous occurrences and associated radiometric anomalies were identified in areas where uranium mineralization has not been previously reported. At two localities, assays of about .01% have been obtained from saprolite. There is some evidence which suggests that uranium may have been leached at these localities and that higher grades of U are likely at depth.

  10. Modeling Low-temperature Geochemical Processes

    Science.gov (United States)

    Nordstrom, D. K.

    2003-12-01

    Geochemical modeling has become a popular and useful tool for a wide number of applications from research on the fundamental processes of water-rock interactions to regulatory requirements and decisions regarding permits for industrial and hazardous wastes. In low-temperature environments, generally thought of as those in the temperature range of 0-100 °C and close to atmospheric pressure (1 atm=1.01325 bar=101,325 Pa), complex hydrobiogeochemical reactions participate in an array of interconnected processes that affect us, and that, in turn, we affect. Understanding these complex processes often requires tools that are sufficiently sophisticated to portray multicomponent, multiphase chemical reactions yet transparent enough to reveal the main driving forces. Geochemical models are such tools. The major processes that they are required to model include mineral dissolution and precipitation; aqueous inorganic speciation and complexation; solute adsorption and desorption; ion exchange; oxidation-reduction; or redox; transformations; gas uptake or production; organic matter speciation and complexation; evaporation; dilution; water mixing; reaction during fluid flow; reaction involving biotic interactions; and photoreaction. These processes occur in rain, snow, fog, dry atmosphere, soils, bedrock weathering, streams, rivers, lakes, groundwaters, estuaries, brines, and diagenetic environments. Geochemical modeling attempts to understand the redistribution of elements and compounds, through anthropogenic and natural means, for a large range of scale from nanometer to global. "Aqueous geochemistry" and "environmental geochemistry" are often used interchangeably with "low-temperature geochemistry" to emphasize hydrologic or environmental objectives.Recognition of the strategy or philosophy behind the use of geochemical modeling is not often discussed or explicitly described. Plummer (1984, 1992) and Parkhurst and Plummer (1993) compare and contrast two approaches for

  11. Calculation of individual isotope equilibrium constants for geochemical reactions

    Science.gov (United States)

    Thorstenson, D.C.; Parkhurst, D.L.

    2004-01-01

    Theory is derived from the work of Urey (Urey H. C. [1947] The thermodynamic properties of isotopic substances. J. Chem. Soc. 562-581) to calculate equilibrium constants commonly used in geochemical equilibrium and reaction-transport models for reactions of individual isotopic species. Urey showed that equilibrium constants of isotope exchange reactions for molecules that contain two or more atoms of the same element in equivalent positions are related to isotope fractionation factors by ?? = (Kex)1/n, where n is the number of atoms exchanged. This relation is extended to include species containing multiple isotopes, for example 13C16O18O and 1H2H18O. The equilibrium constants of the isotope exchange reactions can be expressed as ratios of individual isotope equilibrium constants for geochemical reactions. Knowledge of the equilibrium constant for the dominant isotopic species can then be used to calculate the individual isotope equilibrium constants. Individual isotope equilibrium constants are calculated for the reaction CO2g = CO2aq for all species that can be formed from 12C, 13C, 16O, and 18O; for the reaction between 12C18 O2aq and 1H218Ol; and among the various 1H, 2H, 16O, and 18O species of H2O. This is a subset of a larger number of equilibrium constants calculated elsewhere (Thorstenson D. C. and Parkhurst D. L. [2002] Calculation of individual isotope equilibrium constants for implementation in geochemical models. Water-Resources Investigation Report 02-4172. U.S. Geological Survey). Activity coefficients, activity-concentration conventions for the isotopic variants of H2O in the solvent 1H216Ol, and salt effects on isotope fractionation have been included in the derivations. The effects of nonideality are small because of the chemical similarity of different isotopic species of the same molecule or ion. The temperature dependence of the individual isotope equilibrium constants can be calculated from the temperature dependence of the fractionation

  12. The Momotombo Geothermal Field, Nicaragua: Exploration and development case history study

    Energy Technology Data Exchange (ETDEWEB)

    None

    1982-07-01

    This case history discusses the exploration methods used at the Momotombo Geothermal Field in western Nicaragua, and evaluates their contributions to the development of the geothermal field models. Subsequent reservoir engineering has not been synthesized or evaluated. A geothermal exploration program was started in Nicaragua in 1966 to discover and delineate potential geothermal reservoirs in western Nicaragua. Exploration began at the Momotombo field in 1970 using geological, geochemical, and geophysical methods. A regional study of thermal manifestations was undertaken and the area on the southern flank of Volcan Momotombo was chosen for more detailed investigation. Subsequent exploration by various consultants produced a number of geotechnical reports on the geology, geophysics, and geochemistry of the field as well as describing production well drilling. Geological investigations at Momotombo included photogeology, field mapping, binocular microscope examination of cuttings, and drillhole correlations. Among the geophysical techniques used to investigate the field sub-structure were: Schlumberger and electromagnetic soundings, dipole mapping and audio-magnetotelluric surveys, gravity and magnetic measurements, frequency domain soundings, self-potential surveys, and subsurface temperature determinations. The geochemical program analyzed the thermal fluids of the surface and in the wells. This report presents the description and results of exploration methods used during the investigative stages of the Momotombo Geothermal Field. A conceptual model of the geothermal field was drawn from the information available at each exploration phase. The exploration methods have been evaluated with respect to their contributions to the understanding of the field and their utilization in planning further development. Our principal finding is that data developed at each stage were not sufficiently integrated to guide further work at the field, causing inefficient use of

  13. Fiscal 1997 report on the survey of overseas geological structures, `the Tanjungenim Coal Exploration Project between Japan and Indonesia`; 1997 nendo kaigai chishitsu kozonado chosa `Nippon Indonesia sekitan kyodo tansa Tanjungenim project`

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    The basic survey for coal mine development was conducted in the Banjarsari area of Tanjungenim, Sumatra, Indonesia. In the survey, Japan deals with ground surface exploration, borehole physical survey, VSP survey and seismic survey, and Indonesia exploratory drilling, topographical mapping, measurement, hydrologic/hydraulic survey, access road formation, etc. The boreholes drilled are 35 in number and 4004m in total drilling length. The borehole physical survey was conducted in all 35 holes. The seismic survey was conducted on 5 traverse lines and in a total length of 10.19km, and the VSP survey in two boreholes. As a result of the survey, it was found out that there existed a large amount of coal reserve in a comparatively shallow area in the south-central part of the Banjarsari area. There exist faults, which has no great effects on the open pit mining. There is a high possibility of developing large-scale coal mines of open pit mining type with a comparatively low soil removing ratio. Concerning the coal quality, the heating value is comparatively low, the latter half of a 4000 kcal/kg level. It can be expected to realize a pit-mouth power plant which is low in coal carrying cost. 129 figs., 28 tabs.

  14. Exploring public sector physicians' resilience, reactions and coping strategies in times of economic crisis; findings from a survey in Portugal's capital city area.

    Science.gov (United States)

    Russo, Giuliano; Pires, Carlos André; Perelman, Julian; Gonçalves, Luzia; Barros, Pedro Pita

    2017-03-15

    Evidence is accumulating on the impact of the recent economic crisis on health and health systems across Europe. However, little is known about the effect this is having on physicians - a crucial resource for the delivery of healthcare services. This paper explores the adaptation to the crisis of public sector physicians and their ability to keep performing their functions, with the objective of gaining a better understanding of health workers' resilience under deteriorating conditions. We conducted a survey among 484 public primary care and hospital physicians in Portugal's capital city area and explored their perceptions of the crisis, adaptation and coping strategies. We used ordinal and logistic regression models to link changes in hours worked and intentions to migrate with physicians' characteristics and specific answers. We found little evidence of physicians changing their overall allocation of working time before and after the crisis, with their age, types of specialisation, valuation of job flexibility and independence significantly associated with changes in public sector hours between 2010 and 2015. Being divorced, not Portuguese, of younger age, and working a high number of hours per week, were found to increase the probability of physicians considering migration, the same as having a poor opinion of recent government health policies. On the other hand, enjoying their current working environment, not wanting to disrupt provision of service, and leisure time were found to protect against scaling down public sector hours or considering migration. Our work on Portuguese physicians contributes to the debate on health workers' resilience, showing the value of understanding the influence of personal characteristics and opinions on their adaptation to changing circumstances, before designing policies to improve their working conditions and retention.

  15. Mixing and speciation algorithms for geochemical and reactive transport problems

    OpenAIRE

    De Gaspari, Francesca

    2015-01-01

    Geochemical and reactive transport modelling are essential tools in hydrogeology. They help to identify and assess geochemical processes occurring in applications such as groundwater contamination, water-rock interactions and geologic carbon sequestration. In this thesis we present methods for mixing and speciation calculations to be used for both interpretation of hydrochemical data and numerical modelling. The first method presented allows solving geochemical speciation using redundant i...

  16. Kriging - a challenge in geochemical mapping

    Science.gov (United States)

    Stojdl, Jiri; Matys Grygar, Tomas; Elznicova, Jitka; Popelka, Jan; Vachova, Tatina; Hosek, Michal

    2017-04-01

    Geochemists can easily provide datasets for contamination mapping thanks to recent advances in geographical information systems (GIS) and portable chemical-analytical instrumentation. Kriging is commonly used to visualise the results of such mapping. It is understandable, as kriging is a well-established method of spatial interpolation. It was created in 1950's for geochemical data processing to estimate the most likely distribution of gold based on samples from a few boreholes. However, kriging is based on the assumption of continuous spatial distribution of numeric data that is not realistic in environmental geochemistry. The use of kriging is correct when the data density is sufficient with respect to heterogeneity of the spatial distribution of the geochemical parameters. However, if anomalous geochemical values are focused in hotspots of which boundaries are insufficiently densely sampled, kriging could provide misleading maps with the real contours of hotspots blurred by data smoothing and levelling out individual (isolated) but relevant anomalous values. The data smoothing can thus it results in underestimation of geochemical extremes, which may in fact be of the greatest importance in mapping projects. In our study we characterised hotspots of contamination by uranium and zinc in the floodplain of the Ploučnice River. The first objective of our study was to compare three methods of sampling: random (based on stochastic generation of sampling points), systematic (square grid) and judgemental sampling (based on judgement stemming from principles of fluvial deposition) as the basis for pollution maps. The first detected problem in production of the maps was the reduction of the smoothing effect of kriging using appropriate function of empirical semivariogram and setting the variation of at microscales smaller than the sampling distances to minimum (the "nugget" parameter of semivariogram). Exact interpolators such as Inverse Distance Weighting (IDW) or Radial

  17. Multidisciplinary exploration of the Tendaho Graben geothermal fields

    Science.gov (United States)

    Armadillo, Egidio; Rizzello, Daniele; Verdoya, Massimo; Pasqua, Claudio; Marini, Luigi; Meqbel, Naser; Stimac, Jim; Kebede, Solomon; Mengiste, Andarge; Hailegiorgis, Getenesch; Abera, Fitsum; Mengesha, Kebede

    2017-04-01

    The NW-SE trending Tendaho Graben is the major extensional feature of the Afar, Ethiopia. Rifting and volcanic activity within the graben occurred mostly between 1.8 and 0.6 Ma, but extended to at least 0.2 Ma. Very recent (0.22- 0.03 Ma) activity is focused along the southern part of the younger and active Manda Hararo Rift, which is included in the north-western part of the graben. Extension gave rise to about 1600 m of vertical displacement (verified by drilling) of the basaltic Afar Stratoid sequence, over a crust with a mean thickness of about 23 km. The infill of graben, overlying the Stratoids, consists of volcanic and sedimentary deposits that have been drilled by six exploratory wells. Within the graben, two main geothermal fields have been explored by intensive geological, geochemical and geophysical surveys over an area that approximately covers a square sector of 40x40 km. Both new and existing data sets have been integrated. The Dubti-Ayrobera system is located along the central axis of the graben. Available data, acquired in the last three decades, comprise more than two thousands gravity and magnetic stations, 229 magnetotelluric stations and structural-geological and geochemical observations. The Alalobeda system is located along the SW flank of the graben, at about 25 km from the Dubti-Ayrobera system and has been very recently studied by means of gravimetric (300 stations), magnetotelluric and TDEM (140 stations) geological and geochemical surveys. The new residual magnetic anomaly map has been used to map the younger normal polarity basalt distribution and infer the location of the unknown main rift axis. The bedrock surface resulting by the 3D inversion of the new residual Bouguer anomaly enlightens the main normal faults hindered by sediments and the secondary structures represented by horsts and grabens. The three-dimensional resistivity models allow mapping the sedimentary infill of the graben, fracture zones in the Afar Stradoids bedrock and

  18. History and evaluation of national-scale geochemical data sets for the United States

    Directory of Open Access Journals (Sweden)

    David B. Smith

    2013-03-01

    Full Text Available Six national-scale, or near national-scale, geochemical data sets for soils or stream sediments exist for the United States. The earliest of these, here termed the ‘Shacklette’ data set, was generated by a U.S. Geological Survey (USGS project conducted from 1961 to 1975. This project used soil collected from a depth of about 20 cm as the sampling medium at 1323 sites throughout the conterminous U.S. The National Uranium Resource Evaluation Hydrogeochemical and Stream Sediment Reconnaissance (NURE-HSSR Program of the U.S. Department of Energy was conducted from 1975 to 1984 and collected either stream sediments, lake sediments, or soils at more than 378,000 sites in both the conterminous U.S. and Alaska. The sampled area represented about 65% of the nation. The Natural Resources Conservation Service (NRCS, from 1978 to 1982, collected samples from multiple soil horizons at sites within the major crop-growing regions of the conterminous U.S. This data set contains analyses of more than 3000 samples. The National Geochemical Survey, a USGS project conducted from 1997 to 2009, used a subset of the NURE-HSSR archival samples as its starting point and then collected primarily stream sediments, with occasional soils, in the parts of the U.S. not covered by the NURE-HSSR Program. This data set contains chemical analyses for more than 70,000 samples. The USGS, in collaboration with the Mexican Geological Survey and the Geological Survey of Canada, initiated soil sampling for the North American Soil Geochemical Landscapes Project in 2007. Sampling of three horizons or depths at more than 4800 sites in the U.S. was completed in 2010, and chemical analyses are currently ongoing. The NRCS initiated a project in the 1990s to analyze the various soil horizons from selected pedons throughout the U.S. This data set currently contains data from more than 1400 sites. This paper (1 discusses each data set in terms of its purpose, sample collection protocols

  19. Forensic Analysis using Geological and Geochemical Techniques

    Science.gov (United States)

    Hoogewerff, J.

    2009-04-01

    Due to the globalisation of legal (and illegal) trade there is an increasing demand for techniques which can verify the geographical origin and transfer routes of many legal and illegal commodities and products. Although geological techniques have been used in forensic investigations since the emergence of forensics as a science in the late eighteen hundreds, the last decade has seen a marked increase in geo-scientists initiating concept studies using the latest analytical techniques, including studying natural abundance isotope variations, micro analysis with laser ablation ICPMS and geochemical mapping. Most of the concept studies have shown a good potential but uptake by the law enforcement and legal community has been limited due to concerns about the admissibility of the new methods. As an introduction to the UGU2009 session "Forensic Provenancing using Geological and Geochemical Techniques" I will give an overview of the state of the art of forensic geology and the issues that concern the admissibility of geological forensic evidence. I will use examples from the NITECRIME and FIRMS networks, the EU TRACE project and other projects and literature to illustrate the important issues at hand.

  20. Report on the results of the Sunshine Project - Verification survey for geothermal exploration technology, etc. Summary. Survey of deep geothermal resource; Chinetsu tansa gijutsu tou kensho chosa. Shinbu chinetsu shigen chosa sokatsu seika hokokusho (Yoyaku)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2002-03-01

    As to the development of deep geothermal resource which is expected to contribute to increasing the capacity of future power generation in Japan, investigational study was made from FY 1992 to FY 2000, and the results were summed up. The investigational study was conducted for the hydrothermal convection type deep geothermal resource with a thermal conducting heating mechanism, of which Kakkonda is typical, including the drilling of deep exploration well using the existing technology. As a result, new information/knowledge were acquired about the thermal structure, reservoir structure and hydrothermal supply structure of the depths, and a deep geothermal model was made. Based on the model, a detailed simulation was made possible, and a whole image of the hydrothermal convection type deep geothermal resource with the thermal conducting heating mechanism was made clear. In the surface survey, observation of microearthquakes, high-accuracy MT method, etc. were carried out, and a grasp of the shape of a new granite body from the surface was made possible. Concerning the drilling technology, the geologic stratum with a temperature over 500 degrees C was successfully drilled down to a depth of 3,729m by prolonging the life of bit at the time of drilling by introducing the top drive system, the closed mud cooling device, etc. (NEDO)

  1. Geochemical and isotopic characterization of groundwater origins in a Mediterranean karst system (southern France)

    Science.gov (United States)

    Seidel, J. L.; Ladouche, B.; Batiot-Guilhe, C.

    2013-12-01

    Geochemical and isotopic ratio (11B/10B and 87Sr/86Sr) results are reported for better determining the groundwater origins in the Lez Karst system (southern France). The Lez spring is the main perennial outlet of the system and supplies with drinking water the metropolitan area of Montpellier. According to the hydrodynamic conditions, five water-types discharge at the Lez spring with important mineralization fluctuations (Caetano Bicalho et al., 2012). This geochemical response suggests that hydrodynamics targets groundwater circulation, resulting from different water end-member solicitation and mixing. Previous studies using conventional natural tracers do not succeed to identify all the water compartments supporting the flow during the hydrologic cycle (Marjolet & Salado, 1977; Joseph et al., 1988) and to explain the mineralization variation of the Lez spring. The present study combines a basic geochemical survey data with boron and strontium isotope ratio data for a better characterization of the Lez spring geochemical functioning. Groundwater samples were collected at the Lez spring and surrounding springs and wells under different hydrologic conditions from 2009 to 2011. Major, trace and rare earth elements were determined at AETE analytical platform (OREME, Univ. Montpellier 2) by ionic chromatography and Q-ICP-MS respectively. d11B and 87Sr/86Sr were determined at BRGM/MMA Orleans by TIMS. The geochemical survey has been extended at a larger scale by sampling the main geochemical end- members already identified to replace the Lez spring waters in the regional geochemical context. From this geochemical study, valuable informations have been provided on the reservoir types and water origins flowing in high and low stage periods. For the highly mineralized waters occurring in the fall first rainy events or severe low stages, a deep contribution is highlighted but B and Sr isotopic data do not ascertain the two Triassic end-members (halite or gypsum) as possible

  2. Geochemical characteristics of oil from well Shacan 2 in the Tarim Basin

    Science.gov (United States)

    Bin, Yang

    A large amount of oil and gas was discovered from well Shacan 2 on 22 September, 1984. Since then, more oil discoveries have been made from exploration wells. Based on comprehensive studies of the geological and geochemical data, such as physical properties, biomarkers of saturated hydrocarbons and aromatic hydrocarbons, and isotopes of carbon, hydrogen and sulphur, it is found that the oil is characterized by marine algae and lower aquatic organisms. The oil is highly mature, biodegraded and has migrated far from the source. The isomerization of all the biomarkers in the oil is close to or equal to the thermal balance values. In addition, it has some characteristics of Lower Paleozoic oil in the aspects of n-alkane gas chromatography, monoaromatic steroid components and the composition of the isotopes of carbon and sulphur. From geochemical characteristics and an evaluation of the source rocks existing in the area, the oil is postulated to originate from marine Cambrian-Ordovician source rocks.

  3. Exploring the correlates of suicide attempts among individuals with major depressive disorder: findings from the national epidemiologic survey on alcohol and related conditions.

    Science.gov (United States)

    Bolton, James M; Belik, Shay-Lee; Enns, Murray W; Cox, Brian J; Sareen, Jitender

    2008-07-01

    There are no previous studies describing the correlates of suicide attempts in individuals with major depressive disorder in a nationally representative sample. This study explores the sociodemographic variables, mental disorders, and specific depressive symptoms associated with suicide attempts in depression. Data were drawn from Wave 1 of the National Epidemiologic Survey on Alcohol and Related Conditions (NESARC), a large (N = 43,093) nationally representative survey of mental illness in the United States conducted between 2001 and 2002. Persons with lifetime major depressive disorder (N = 5128; diagnosed according to DSM-IV) were categorized according to the presence (N = 865) or absence (N = 4263) of a lifetime history of suicide attempts. Multivariate logistic regression was used to compare the 2 groups across a broad range of socio-demographic and mental disorder correlates, as well as to compare specific depressive symptoms associated with a history of suicide attempts. Positive predictive values (PPVs) were calculated to evaluate the effectiveness of each correlate in predicting suicide attempts. Analyses were conducted separately for men and women. Sociodemographic factors significantly associated with a history of suicide attempts included Hispanic or Latino ethnicity (p suicide attempt was significantly associated with any anxiety, personality, or substance use disorder among both men and women (all p suicide attempt. In men, suicide attempts had a strong association with dependent personality disorder (adjusted odds ratio [AOR] = 3.81; 95% CI = 1.14 to 12.73), whereas in women, suicide attempts had a strong association with antisocial personality disorder (AOR = 2.71; 95% CI = 1.72 to 4.25). Dependent personality disorder predicted suicide attempt in almost three quarters of depressed men (PPV = 74.3%; 95% CI = 54.2 to 87.6). The depressive symptom most strongly associated with a history of suicide attempts in both men and women was feelings of

  4. Some geochemical considerations in the petrogenesis of Madagali ...

    African Journals Online (AJOL)

    Some geochemical considerations in the petrogenesis of Madagali granitoids, northeastern Nigeria. S Baba. Abstract. Major and trace element geochemical data on granitoids of Madagali area of northeastern Nigeria show a series that ranges from K-calc-alkaline, through granodiorite-monzogranite to granite. They are ...

  5. Geochemical study of volcanic and associated granitic rocks from ...

    Indian Academy of Sciences (India)

    Geochemical studies and modelling show that both volcanic and granitic magmas from the western part of the Johor National Park, Endau Rompin are different and probably have different sources. The geochemical plot suggests that both dacite/rhyolite and andesite probably have a common origin as in many of the ...

  6. Modeling background radiation using geochemical data: A case study in and around Cameron, Arizona.

    Science.gov (United States)

    Marsac, Kara E; Burnley, Pamela C; Adcock, Christopher T; Haber, Daniel A; Malchow, Russell L; Hausrath, Elisabeth M

    2016-12-01

    This study compares high resolution forward models of natural gamma-ray background with that measured by high resolution aerial gamma-ray surveys. The ability to predict variations in natural background radiation levels should prove useful for those engaged in measuring anthropogenic contributions to background radiation for the purpose of emergency response and homeland security operations. The forward models are based on geologic maps and remote sensing multi-spectral imagery combined with two different sources of data: 1) bedrock geochemical data (uranium, potassium and thorium concentrations) collected from national databases, the scientific literature and private companies, and 2) the low spatial resolution NURE (National Uranium Resource Evaluation) aerial gamma-ray survey. The study area near Cameron, Arizona, is located in an arid region with minimal vegetation and, due to the presence of abandoned uranium mines, was the subject of a previous high resolution gamma-ray survey. We found that, in general, geologic map units form a good basis for predicting the geographic distribution of the gamma-ray background. Predictions of background gamma-radiation levels based on bedrock geochemical analyses were not as successful as those based on the NURE aerial survey data sorted by geologic unit. The less successful result of the bedrock geochemical model is most likely due to a number of factors including the need to take into account the evolution of soil geochemistry during chemical weathering and the influence of aeolian addition. Refinements to the forward models were made using ASTER visualizations to create subunits of similar exposure rate within the Chinle Formation, which contains multiple lithologies and by grouping alluvial units by drainage basin rather than age. Copyright © 2016 The Authors. Published by Elsevier Ltd.. All rights reserved.

  7. Geochemical Evidence for a Terrestrial Magma Ocean

    Science.gov (United States)

    Agee, Carl B.

    1999-01-01

    The aftermath of phase separation and crystal-liquid fractionation in a magma ocean should leave a planet geochemically differentiated. Subsequent convective and other mixing processes may operate over time to obscure geochemical evidence of magma ocean differentiation. On the other hand, core formation is probably the most permanent, irreversible part of planetary differentiation. Hence the geochemical traces of core separation should be the most distinct remnants left behind in the mantle and crust, In the case of the Earth, core formation apparently coincided with a magma ocean that extended to a depth of approximately 1000 km. Evidence for this is found in high pressure element partitioning behavior of Ni and Co between liquid silicate and liquid iron alloy, and with the Ni-Co ratio and the abundance of Ni and Co in the Earth's upper mantle. A terrestrial magma ocean with a depth of 1000 km will solidify from the bottom up and first crystallize in the perovskite stability field. The largest effect of perovskite fractionation on major element distribution is to decrease the Si-Mg ratio in the silicate liquid and increase the Si-Mg ratio in the crystalline cumulate. Therefore, if a magma ocean with perovskite fractionation existed, then one could expect to observe an upper mantle with a lower than chondritic Si-Mg ratio. This is indeed observed in modern upper mantle peridotites. Although more experimental work is needed to fully understand the high-pressure behavior of trace element partitioning, it is likely that Hf is more compatible than Lu in perovskite-silicate liquid pairs. Thus, perovskite fractionation produces a molten mantle with a higher than chondritic Lu-Hf ratio. Arndt and Blichert-Toft measured Hf isotope compositions of Barberton komatiites that seem to require a source region with a long-lived, high Lu-Hf ratio. It is plausible that that these Barberton komatiites were generated within the majorite stability field by remelting a perovskite

  8. Speak-up culture in an intensive care unit in Hong Kong: a cross-sectional survey exploring the communication openness perceptions of Chinese doctors and nurses.

    Science.gov (United States)

    Ng, George Wing Yiu; Pun, Jack Kwok Hung; So, Eric Hang Kwong; Chiu, Wendy Wai Hang; Leung, Avis Siu Ha; Stone, Yuk Han; Lam, Chung Ling; Lai, Sarah Pui Wa; Leung, Rowlina Pui Wah; Luk, Hing Wah; Leung, Anne Kit Hung; Au Yeung, Kin Wah; Lai, Kang Yiu; Slade, Diana; Chan, Engle Angela

    2017-08-11

    Despite growing recognition of the importance of speaking up to protect patient safety in critical care, little research has been performed in this area in an intensive care unit (ICU) context. This study explored the communication openness perceptions of Chinese doctors and nurses and identified their perceptions of issues in ICU communication, their reasons for speaking up and the possible factors and strategies involved in promoting the practice of speaking up. A mixed-methods design with quantitative and sequential qualitative components was used. Eighty ICU staff members from a large public hospital in Hong Kong completed a questionnaire regarding their perceptions of communication openness. Ten clinicians whose survey responses indicated support for open communication were then interviewed about their speak-up practices. The participating ICU staff members had similar perceptions of their openness to communication. However, the doctors responded more positively than the nurses to many aspects of communication openness. The two groups also had different perceptions of speaking up. The interviewed ICU staff members who indicated a high level of communication openness reported that their primary reasons for speaking up were to seek and clarify information, which was achieved by asking questions. Other factors perceived to influence the motivation to speak up included seniority, relationships and familiarity with patient cases. Creating an atmosphere of safety and equality in which team members feel confident in expressing their personal views without fear of reprisal or embarrassment is necessary to encourage ICU staff members, regardless of their position, to speak up. Because harmony and saving face is valued in Chinese culture, training nurses and doctors to speak up by focusing on human factors and values rather than simply addressing conflict management is desirable in this context. © Article author(s) (or their employer(s) unless otherwise stated in the

  9. The geochemical record in rock glaciers

    Science.gov (United States)

    Steig, E.J.; Fitzpatrick, J.J.; Potter, N.; Clark, D.H.

    1998-01-01

    A 9.5 m ice core was extracted from beneath the surficial debris cover of a rock glacier at Galena Creek, northwestern Wyoming. The core contains clean, bubble-rich ice with silty debris layers spaced at roughly 20 cm intervals. The debris layers are similar in appearance to those in typical alpine glaciers, reflecting concentration of debris by melting at the surface during the summer ablation season. Profiles of stable isotope concentrations and electrical conductivity measurements provide independent evidence for melting in association with debris layers. These observations are consistent with a glacial origin for the ice, substantiating the glacigenic model for rock glacier formation. The deuterium excess profile in the ice indicates that the total depth of meltwater infiltration is less than the thickness of one annual layer, suggesting that isotope values and other geochemical signatures are preserved at annual resolution. This finding demonstrates the potential for obtaining useful paleoclimate information from rock glacier ice.

  10. Modeling Background Radiation in our Environment Using Geochemical Data

    Energy Technology Data Exchange (ETDEWEB)

    Malchow, Russell L.; Marsac, Kara [University of Nevada, Las Vegas; Burnley, Pamela [University of Nevada, Las Vegas; Hausrath, Elisabeth [Uniiversity of Nevada, Las Vegas; Haber, Daniel [University of Nevada, Las Vegas; Adcock, Christopher [University of Nevada, Las Vegas

    2015-02-01

    Radiation occurs naturally in bedrock and soil. Gamma rays are released from the decay of the radioactive isotopes K, U, and Th. Gamma rays observed at the surface come from the first 30 cm of rock and soil. The energy of gamma rays is specific to each isotope, allowing identification. For this research, data was collected from national databases, private companies, scientific literature, and field work. Data points were then evaluated for self-consistency. A model was created by converting concentrations of U, K, and Th for each rock and soil unit into a ground exposure rate using the following equation: D=1.32 K+ 0.548 U+ 0.272 Th. The first objective of this research was to compare the original Aerial Measurement System gamma ray survey to results produced by the model. The second objective was to improve the method and learn the constraints of the model. Future work will include sample data analysis from field work with a goal of improving the geochemical model.

  11. Geochemical and geophysical monitoring of thermal waters in Sloveniain relation to seismic activity

    Directory of Open Access Journals (Sweden)

    T. Dolenec

    2005-06-01

    Full Text Available Pre-seismic related strains in the Earth s crust are the main cause of the observed geophysical and geochemical anomalies in ground waters preceding an earthquake. Posoc?je Region, situated along the Soc?a River, is one of the most seismically active areas of Slovenia. Our measuring stations close to the Posoc?je Region were installed in the thermal springs at Bled in 1998 and at Zatolmin in 1999. Since the beginning of our survey, radon concentration, electrical conductivity and water temperature have been measured continuously once every hour. In May 2002, the number of geochemical parameters monitored was extended to ionic concentration, pH and Eh, which are analysed once a month. Before seeking a correlation between geochemical and geophysical anomalies with seismic events, the influence of meteorological (atmospheric precipitation, barometric pressure and hydrological (water table of the Tolminka River factors on observed anomalies were studied. Results at Zatolmin showed that some radon variation during the period from June to October 2002 may be related to seismic activity and not only to meteorological effects.

  12. Manual hierarchical clustering of regional geochemical data using a Bayesian finite mixture model

    Science.gov (United States)

    Ellefsen, Karl J.; Smith, David

    2016-01-01

    Interpretation of regional scale, multivariate geochemical data is aided by a statistical technique called “clustering.” We investigate a particular clustering procedure by applying it to geochemical data collected in the State of Colorado, United States of America. The clustering procedure partitions the field samples for the entire survey area into two clusters. The field samples in each cluster are partitioned again to create two subclusters, and so on. This manual procedure generates a hierarchy of clusters, and the different levels of the hierarchy show geochemical and geological processes occurring at different spatial scales. Although there are many different clustering methods, we use Bayesian finite mixture modeling with two probability distributions, which yields two clusters. The model parameters are estimated with Hamiltonian Monte Carlo sampling of the posterior probability density function, which usually has multiple modes. Each mode has its own set of model parameters; each set is checked to ensure that it is consistent both with the data and with independent geologic knowledge. The set of model parameters that is most consistent with the independent geologic knowledge is selected for detailed interpretation and partitioning of the field samples.

  13. Continental geodynamics and mineral exploration - the Western Australian perspective

    Science.gov (United States)

    Gessner, Klaus; Murdie, Ruth; Yuan, Huaiyu; Brisbout, Lucy; Sippl, Christian; Tyler, Ian; Kirkland, Chris; Wingate, Michael; Johnson, Simon; Spaggiari, Catherine; Smithies, Hugh; Lu, Yongjun; Gonzalez, Chris; Jessell, Mark; Holden, Eun-Jung; Gorczyk, Weronika; Occhipinti, Sandra

    2017-04-01

    The exploration for mineral resources and their extraction has been a fundamental human activity since the dawn of civilisation: Geology is everywhere - ore deposits are rare. Most deposits were found at or near Earth's surface, often by chance or serendipity. To meet the challenge of future demand, successful exploration requires the use of advanced technology and scientific methods to identify targets at depth. Whereas the use and development of high-tech exploration, extraction and processing methods is of great significance, understanding how, when and where dynamic Earth systems become ore-forming systems is a difficult scientific challenge. Ore deposits often form by a complex interplay of coupled physical processes with evolving geological structure. The mineral systems approach states that understanding the geodynamic and tectonic context of crustal scale hydrothermal fluid flow and magmatism can help constrain the spatial extent of heat and mass transport and therefore improve targeting success in mineral exploration. Tasked with promoting the geological assets of one of the World's largest and most resource-rich jurisdictions, the Geological Survey of Western Australia is breaking new ground by systematically collecting and integrating geophysical, geological and geochemical data with the objective to reveal critical ties between lithospheric evolution and mineral deposits. We present examples where this approach has led to fundamental reinterpretations of Archean and Proterozoic geodynamics and the nature of tectonic domains and their boundaries, including cases where geodynamic modelling has played an important role in testing hypotheses of crustal evolution.

  14. The IUGS/IAGC Task Group on Global Geochemical Baselines

    Science.gov (United States)

    Smith, David B.; Wang, Xueqiu; Reeder, Shaun; Demetriades, Alecos

    2012-01-01

    The Task Group on Global Geochemical Baselines, operating under the auspices of both the International Union of Geological Sciences (IUGS) and the International Association of Geochemistry (IAGC), has the long-term goal of establishing a global geochemical database to document the concentration and distribution of chemical elements in the Earth’s surface or near-surface environment. The database and accompanying element distribution maps represent a geochemical baseline against which future human-induced or natural changes to the chemistry of the land surface may be recognized and quantified. In order to accomplish this long-term goal, the activities of the Task Group include: (1) developing partnerships with countries conducting broad-scale geochemical mapping studies; (2) providing consultation and training in the form of workshops and short courses; (3) organizing periodic international symposia to foster communication among the geochemical mapping community; (4) developing criteria for certifying those projects whose data are acceptable in a global geochemical database; (5) acting as a repository for data collected by those projects meeting the criteria for standardization; (6) preparing complete metadata for the certified projects; and (7) preparing, ultimately, a global geochemical database. This paper summarizes the history and accomplishments of the Task Group since its first predecessor project was established in 1988.

  15. Geothermal development promotion survey. No. B-3 Kumaishi area; Chinethu kaihatsu sokushin chosa seika hokokusho. No. B-3. Kumaishi chiiki

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    This paper summarizes the result of a geothermal resource survey carried out from fiscal 1995 through fiscal 1997 in the Kumaishi Area located in the western center of Oshima Peninsula in the south western part of Hokkaido. The survey for this area was performed with an objective to search the spread of high temperature area continuing from the adjoining Yakumo area where the highest temperature of 233 degrees C has been confirmed in a structural test well (N63-YK-6), to identify high water permeating areas in great depth points underground, and to find possibility of existence of geothermal resources. The survey included geological and alteration zone survey, geochemical survey, gravitation exploration, electromagnetic exploration, drilling and temperature logging of five structural test wells, water injection test, temperature restoration test, core survey and hot water survey. Also performed were environmental effect survey, rock age measurement, alteration age measurement, and fluid inclusion test. As a result of the survey, it was identified that the verified geothermal hot water has been stored in granites with poor water permeability, whose low temperature has not formed convection systems spreading in wide areas despite having been heated, making each system exist in small scale independently. It was estimated that the possibility is low to expect geothermal power generation. (NEDO)

  16. Geochemical and mineralogical data for soils of the conterminous United States

    Science.gov (United States)

    Smith, David B.; Cannon, William F.; Woodruff, Laurel G.; Solano, Federico; Kilburn, James E.; Fey, David L.

    2013-01-01

    In 2007, the U.S. Geological Survey initiated a low-density (1 site per 1,600 square kilometers, 4,857 sites) geochemical and mineralogical survey of soils of the conterminous United States as part of the North American Soil Geochemical Landscapes Project. Sampling and analytical protocols were developed at a workshop in 2003, and pilot studies were conducted from 2004 to 2007 to test and refine these recommended protocols. The final sampling protocol for the national-scale survey included, at each site, a sample from a depth of 0 to 5 centimeters, a composite of the soil A horizon, and a deeper sample from the soil C horizon or, if the top of the C horizon was at a depth greater than 1 meter, from a depth of approximately 80–100 centimeters. The soil A and C horizons were determined by a quantitative X-ray diffraction method using Rietveld refinement. Sampling in the conterminous United States was completed in 2010, with chemical and mineralogical analyses completed in May 2013. The resulting dataset provides an estimate of the abundance and spatial distribution of chemical elements and minerals in soils of the conterminous United States and represents a baseline for soil geochemistry and mineralogy against which future changes may be recognized and quantified. This report (1) describes the sampling, sample preparation, and analytical methods used; (2) gives details of the quality control protocols used to monitor the quality of chemical and mineralogical analyses over approximately six years; and (3) makes available the soil geochemical and mineralogical data in downloadable tables.

  17. Geochemical characteristics of the Permian sedimentary rocks from Qiangtang Basin: Constraints for paleoenvironment and paleoclimate

    Directory of Open Access Journals (Sweden)

    Junjie Hu

    2017-01-01

    Full Text Available Qiangtang Basin is expected to become important strategic petroleum exploitation area in China. However, little research has been done on the Permian strata in this area. This paper presents Lower Permian Zhanjin Formation geochemical data from the Jiaomuri area, reconstructing the paleo-depositional environment and providing information for further petroleum exploration. The geochemical characteristics of 19 samples were investigated. These geochemical samples show a developed mud flat characteristic with light rich clay content. The geological data were used to constrain the paleoredox environment, which proved that these sediments were deposited mainly beneath a slightly oxic water column with relatively low paleoproductivity as evidenced by the P/Ti (mean of 0.07 and Ba/Al (mean of 20.5. Palaeoclimate indexes such as the C-value (0.24-1.75 and Sr/Cu (1.28-11.58 reveal a humid climatic condition during Zhanjin Formation sediment deposition. The ω(LaN/ω(YbN ratio values indicate a fast sedimentary rate during the deposition period.

  18. Study on mineralization at Jian copper deposit, Fars province, using petrographical and geochemical data

    Directory of Open Access Journals (Sweden)

    Mohamad Ali Rajabzade

    2013-04-01

    Full Text Available Jian Cu deposit is hosted by Surian volcano-sedimentary complex of Permo-Triassic age on the eastern edge of the Sanandaj-Sirjan metamorphic zone at a distance of 195 km from Shiraz, southwestern Iran. The complex consists mainly of metabasalt, chlorite-quartz schist, chlorite-muscovite schist, mica schist and graphite schist. Pyrite is the most important sulfide and chalcopyrite is the major Cu-bearing mineral occurring as disseminated grains and veinlets in host chlorite-quartz schist and chlorite-muscovite schist. Chondrite-normalized REE pattern of metabasalt with La/LuN=2/9 indicates mantle tholeiitic basalt as the source of metamorphosed igneous rocks. Geochemical data on the metabasalts, especially the content of immobile elements (e.g., Ti and High Field Strength Elements (HFSE (e.g., Zr، Nb and Y, show low degree of partial melting for parental magma with E-MORB affinity. Chloritic, silicification and minor sericitic assemblages are the main alteration types associated with the Jian Cu deposit. The Y/Ho ratio of Cu ores varies from 29.9 to 32.5, indicating the important role of sea water in the mineralizing system. Petrographical and geochemical data indicate that the Jian Cu deposit was formed as volcano-sedimentary hosted massive sulfide. The Ishikawa alteration index (AI in association with chlorite-carbonate-pyrite index (CCP is useful for the geochemical exploration of Cu deposits in the study area.

  19. Chain of custody; recommendations for acceptance and analysis of evidentiary geochemical samples

    Science.gov (United States)

    Murphy, Christine M.; Briggs, Paul H.; Adrian, Betty M.; Wilson, Steve A.; Hageman, Phil L.; Theodorakos, Pete M.

    1997-01-01

    Personnel from the Analytical Chemistry Services Group (ACSG), Mineral Resource Survey Program, formed a team to determine the policies for acceptance and analysis of geochemical samples. This team contacted law enforcement agencies that handle litigious samples, laboratories that work with samples of special nature, and the Solicitor General, Department of the Interior. Using the knowledge from these agencies as well as the expertise of ACSG personnel, sample control routine procedures, sample control evidentiary procedures, personnel policy governing chain-of-custody samples, and the general polices governing physical security of chain-of custody samples have been enacted.

  20. Geochemical constraints on the distribution of gas hydrates in the Gulf of Mexico

    Science.gov (United States)

    Paull, C. K.; Ussler, W.; Lorenson, T.; Winters, W.; Dougherty, J.

    2005-11-01

    Gas hydrates are common within near-seafloor sediments immediately surrounding fluid and gas venting sites on the continental slope of the northern Gulf of Mexico. However, the distribution of gas hydrates within sediments away from the vents is poorly documented, yet critical for gas hydrate assessments. Porewater chloride and sulfate concentrations, hydrocarbon gas compositions, and geothermal gradients obtained during a porewater geochemical survey of the northern Gulf of Mexico suggest that the lack of bottom simulating reflectors in gas-rich areas of the gulf may be the consequence of elevated porewater salinity, geothermal gradients, and microbial gas compositions in sediments away from fault conduits.

  1. Geochemical constraints on the distribution of gas hydrates in the Gulf of Mexico

    Science.gov (United States)

    Paull, C.K.; Ussler, W.; Lorenson, T.; Winters, W.; Dougherty, J.

    2005-01-01

    Gas hydrates are common within near-seafloor sediments immediately surrounding fluid and gas venting sites on the continental slope of the northern Gulf of Mexico. However, the distribution of gas hydrates within sediments away from the vents is poorly documented, yet critical for gas hydrate assessments. Porewater chloride and sulfate concentrations, hydrocarbon gas compositions, and geothermal gradients obtained during a porewater geochemical survey of the northern Gulf of Mexico suggest that the lack of bottom simulating reflectors in gas-rich areas of the gulf may be the consequence of elevated porewater salinity, geothermal gradients, and microbial gas compositions in sediments away from fault conduits. 

  2. History and evaluation of national-scale geochemical data sets for the United States

    OpenAIRE

    Smith, David B.; Smith, Steven M.; Horton, John D.

    2013-01-01

    Six national-scale, or near national-scale, geochemical data sets for soils or stream sediments exist for the United States. The earliest of these, here termed the ‘Shacklette’ data set, was generated by a U.S. Geological Survey (USGS) project conducted from 1961 to 1975. This project used soil collected from a depth of about 20 cm as the sampling medium at 1323 sites throughout the conterminous U.S. The National Uranium Resource Evaluation Hydrogeochemical and Stream Sediment Reconnaissance ...

  3. Geochemical map of the Arnold Mesa Roadless Area, Yavapai County, Arizona

    Science.gov (United States)

    Wolfe, Edward W.

    1983-01-01

    The Wilderness Act (Public Law 88-577, September 3, 1964) and related acts require the U.S. Geological Survey and the U.S. Bureau of Mines to survey certain areas on Federal lands to determine their mineral resource potential. Results must be made available to the public and be submitted to the President and the Congress. This report presents the results of a geochemical survey of the Arnold Mesa Roadless Area (U.S. Forest Service number 03092) in the Prescott and Tonto National Forests, Yavapai County, Arizona. The Arnold Mesa Roadless Area was classified as a further planning area during the Second Roadless Area Review and Evaluation (RARE II) by the U.S. Forest Service, January 1979.

  4. Geochemical evolution of groundwaterof the Iblean Foreland (Southeastern Sicily after the December 13, 1990 earthquake (M = 5.4

    Directory of Open Access Journals (Sweden)

    S. Tersigni

    1995-06-01

    Full Text Available Geochemical surveys were performed by the Istituto Nazionale di Geofisica (ING, between December 1990 and July 1991, in the framework of an interdisciplinary task study throughout the Siracusa epicentral area: these studies were aimed at col1ecting specific information on the geochemical patterns of fluids, in relation to the geodynamic and seismic evolution of the nol1hern Iblean Foreland area, stal1ing from the December, 13, 1990 Syracuse earthquake (M = 5,4. The results of the hydrogeochemical surveys, discussed in this paper, were in part unexpected. In particular, a steady decrease of the PCO2 va1ues, after the eal1hquake, in ground- waters of the epicentral area, along a NNW-SSE fault bordering the Augusta Graben (Brucoli Sulphureous Spring, was observed. This observation enabled us to reconstruct the geochemical processes triggered by the earthquake: a sudden and strong release of CO2 of deep origin, probably related to a pore pressure uprising and/or to a water/rock interaction changes in the vicinity of the seismogenic structure. The existence of deep- fluid uprising (CO2, 222Rn, NHj, H2S, as well as the variation in time of geochemica1 flows accompanying seismic activity along this NNW-SSE anomalous-sites 1ine, within the whole Iblean Foreland, witnes., the activity (as concern as fluidodynamic and geochemistry of the NNW-SSE striking Ibleo-Maltese Escarpment fault system. This fact can be taken into account in locating the seismogenic structure responsible for the 1990 earthquake, like a contribution of the geochemical methods applied to seismotectonics. During June 1992, a more complete ana1ysis of the Iblean Foreland groundwaters was performed, co1lecting data on the geochemi- ca1 feature, of the different aquifers in aseismic period. Mu1tivariable statistics, chemical equilibria studies and mapping with our geochemical data, were also performed.

  5. Database creation, data quality assessment, and geochemical maps (phase V, deliverable 59)—Final report on compilation and validation of geochemical data: Chapter D in Second projet de renforcement institutionnel du secteur minier de la République Islamique de Mauritanie (PRISM-II)

    Science.gov (United States)

    Eppinger, Robert G.; Giles, Stuart A.; Lee, Gregory K.; Smith, Steven M.

    2015-01-01

    Under the World Bank-funded Second Projet de Renforcement Institutionnel du Secteur Minier de la Republique Islamique de Mauritanie (PRISM-II), this Phase V geochemistry report follows earlier Phase I and Phase II summary reports on geochemical data (U.S. Geological Survey, 2007 and Eppinger, 2007; respectively). All the reports are based on evaluations of geochemical data collected in 1999-2004 under an earlier World Bank program (PRISM-I) by the British Geological Survey (BGS) and the Bureau de Recherches Géologiques et Minières (BRGM) for the Government of Mauritania. There are no associated Phase III or IV reports.

  6. The Dublin SURGE Project: geochemical baseline for heavy metals in topsoils and spatial correlation with historical industry in Dublin, Ireland

    OpenAIRE

    Glennon, M.M.; Harris, P.; Ottesen, R.T.; Scanlon, R.P.; O’Connor, P.J.

    2013-01-01

    The Dublin SURGE (Soil Urban Geochemistry) Project is Dublin’s first baseline survey of heavy metals and persistent organic pollutants in topsoils and is part of a Europe-wide initiative to map urban geochemical baselines in ten cities. 1,058 samples were collected as part of a stratified random sampling programme in the greater Dublin area to give an overview of baseline conditions in the city. Samples were analysed for 31 inorganic elements including heavy metals. Analysis of results indica...

  7. The Geochemical Earth Reference Model (GERM)

    Energy Technology Data Exchange (ETDEWEB)

    Staudigel, H. [Vrije Univ., Amsterdam (Netherlands); Albarede, F. [Ecole Normale Superieure, Lyon (France); Shaw, H. [Lawrence Livermore National Lab., CA (United States); McDonough, B. [Harvard Univ., Cambridge, MA (United States). Dept. of Earth and Planetary Sciences; White, W. [Cornell Univ., Ithaca, NY (United States). Dept. of Geology

    1996-12-01

    The Geochemical Earth Reference Model (GERM) initiative is a grass- roots effort with the goal of establishing a community consensus on a chemical characterization of the Earth, its major reservoirs, and the fluxes between them. Long term goal of GERM is a chemical reservoir characterization analogous to the geophysical effort of the Preliminary Reference Earth Model (PREM). Chemical fluxes between reservoirs are included into GERM to illuminate the long-term chemical evolution of the Earth and to characterize the Earth as a dynamic chemical system. In turn, these fluxes control geological processes and influence hydrosphere-atmosphere-climate dynamics. While these long-term goals are clearly the focus of GERM, the process of establishing GERM itself is just as important as its ultimate goal. The GERM initiative is developed in an open community discussion on the World Wide Web (GERM home page is at http://www-ep.es.llnl. gov/germ/germ-home.html) that is mediated by a series of editors with responsibilities for distinct reservoirs and fluxes. Beginning with the original workshop in Lyons (March 1996) GERM is continued to be developed on the Internet, punctuated by workshops and special sessions at professional meetings. It is planned to complete the first model by mid-1997, followed by a call for papers for a February 1998 GERM conference in La Jolla, California.

  8. Geochemical modeling of magmatic gas scrubbing

    Directory of Open Access Journals (Sweden)

    B. Gambardella

    2005-06-01

    Full Text Available The EQ3/6 software package, version 7.2 was successfully used to model scrubbing of magmatic gas by pure water at 0.1 MPa, in the liquid and liquid-plus-gas regions. Some post-calculations were necessary to account for gas separation effects. In these post-calculations, redox potential was considered to be fixed by precipitation of crystalline a-sulfur, a ubiquitous and precocious process. As geochemical modeling is constrained by conservation of enthalpy upon water-gas mixing, the enthalpies of the gas species of interest were reviewed, adopting as reference state the liquid phase at the triple point. Our results confirm that significant emissions of highly acidic gas species (SO2(g, HCl(g, and HF(g are prevented by scrubbing, until dry conditions are established, at least locally. Nevertheless important outgassing of HCl(g can take place from acid, HCl-rich brines. Moreover, these findings support the rule of thumb which is generally used to distinguish SO2-, HCl-, and HF-bearing magmatic gases from SO2-, HCl-, and HF-free hydrothermal gases.

  9. Geochemical barriers of manganese distribution in edaphotopes of Dnieper Prysamarye

    National Research Council Canada - National Science Library

    N. N. Tsvetkova; Y. O. Tagunova

    2015-01-01

    ...’ health and stability of the biosphere as a whole. Geochemical barriers are local zones where the conditions of elemental migration are significantly different, resulting in accumulation of some chemical elements...

  10. Chlorine isotopes potential as geo-chemical tracers

    Digital Repository Service at National Institute of Oceanography (India)

    Shirodkar, P.V.; Pradhan, U.K.; Banerjee, R.

    The potential of chlorine isotopes as tracers of geo-chemical processes of earth and the oceans is highlighted based on systematic studies carried out in understanding the chlorine isotope fractionation mechanism, its constancy in seawater and its...

  11. Geochemical characteristics of the Jos-Plateau Basalts, North ...

    African Journals Online (AJOL)

    phenocrysts of both olivine, plagioclase (bytwonite-labradorite) and rarely pyroxene (diopside-augite) set in a groundmass of labradorite laths, magnetite, ilmenite, biotite, minor k-feldpars, nepheline and volcanic glass. Geochemical data show ...

  12. Geochemical characterization of the siliciclastic rocks of Chitravati ...

    Indian Academy of Sciences (India)

    59

    feldspar. 15 and plagioclase), mica, rock fragments, heavy minerals, with minor proportion of the matrix. 16 and cement. Based on major element geochemical classification diagram, Pulivendla. 17. Quartzite is considered as quartz-arenite and ...

  13. The geochemical chararateristics of the marble deposits east of ...

    African Journals Online (AJOL)

    ), marbles were investigated with the view to establishing marble occurrences and their geochemical characteristics. Crystalline rocks of the Nigerian Basement Complex (migmatite – gneiss complex) underlie the area. Ten marble bodies were ...

  14. GEOCHEM-EZ: a chemical speciation program with greater power and flexibility

    Science.gov (United States)

    GEOCHEM –EZ is a multi-functional chemical speciation program, which was designed to replace the existing GEOCHEM-PC, a program that can only be used on DOS consoles. Chemical speciation programs, such as GEOCHEM (Sposito and Mattigod, 1980) and GEOCHEM-PC (Parker et al., 1995), have been excellent ...

  15. Probabilistic, sediment-geochemical parameterisation of the groundwater compartment of the Netherlands for spatially distributed, reactive transport modelling

    Science.gov (United States)

    Janssen, Gijs; Gunnink, Jan; van Vliet, Marielle; Goldberg, Tanya; Griffioen, Jasper

    2017-04-01

    Pollution of groundwater aquifers with contaminants as nitrate is a common problem. Reactive transport models are useful to predict the fate of such contaminants and to characterise the efficiency of mitigating or preventive measures. Parameterisation of a groundwater transport model on reaction capacity is a necessary step during building the model. Two Dutch, national programs are combined to establish a methodology for building a probabilistic model on reaction capacity of the groundwater compartment at the national scale: the Geological Survey program and the NHI Netherlands Hydrological Instrument program. Reaction capacity is considered as a series of geochemical characteristics that control acid/base condition, redox condition and sorption capacity. Five primary reaction capacity variables are characterised: 1. pyrite, 2. non-pyrite, reactive iron (oxides, siderite and glauconite), 3. clay fraction, 4. organic matter and 5. Ca-carbonate. Important reaction capacity variables that are determined by more than one solid compound are also deduced: 1. potential reduction capacity (PRC) by pyrite and organic matter, 2. cation-exchange capacity (CEC) by organic matter and clay content, 3. carbonate buffering upon pyrite oxidation (CPBO) by carbonate and pyrite. Statistical properties of these variables are established based on c. 16,000 sediment geochemical analyses. The first tens of meters are characterised based on 25 regions using combinations of lithological class and geological formation as strata. Because of both less data and more geochemical uniformity, the deeper subsurface is characterised in a similar way based on 3 regions. The statistical data is used as input in an algoritm that probabilistically calculates the reaction capacity per grid cell. First, the cumulative frequency distribution (cfd) functions are calculated from the statistical data for the geochemical strata. Second, all voxel cells are classified into the geochemical strata. Third, the

  16. Using Short Dietary Questions to Develop Indicators of Dietary Behaviour for Use in Surveys Exploring Attitudinal and/or Behavioural Aspects of Dietary Choices

    OpenAIRE

    Daly, Alison; Pollard, Christina M.; Kerr, Deborah A.; Binns, Colin W.; Phillips, Michael

    2015-01-01

    For countries where nutrition surveys are infrequent, there is a need to have some measure of healthful eating to plan and evaluate interventions. This study shows how it is possible to develop healthful eating indicators based on dietary guidelines from a cross sectional population survey. Adults 18 to 64 years answered questions about the type and amount of foods eaten the previous day, including fruit, vegetables, cereals, dairy, fish or meat and fluids. Scores were based on serves and typ...

  17. Identification of Sediment Sources to Calumet River through Geochemical Fingerprinting

    Science.gov (United States)

    2017-04-01

    historic geochemical fingerprint for sediments within this reach of the river. Geochemical measurements and advanced multivariate statistics were...depositional fluxes of stable Pb, 210Pb, and 7Be into Chesapeake Bay. Journal of Atmospheric Chemistry 36(1):65–79. Kirchner, G. 2011. 210Pb as a tool for...Jackson, M. Roy-Barman, S. Schmidt, and M. Elskens. 2006. 234Th sorption and export models in the water column: A review. Marine Chemistry 100(3– 4

  18. Organic shale analysis using geochemical data and seismic attributes: Case study of Talang Akar formation, South Sumatera Basin

    Science.gov (United States)

    Manaf, P. E.; Suparno, S.; Haris, A.; Usman, A.; Riyanto, A.

    2017-07-01

    Organic shale analysis of Talang Akar Formation, south Sumatera basin has been carried out using integrated seismic attributes, petrophysical and geochemical data. This shale layer has been deposited in sagging phase with low deposition energy at transgression period, which results in abundant shale deposit. The paper is aimed at characterizing the geochemical and petrophysical properties of shale rock formation and mapping their distribution using transformed seismic data into acoustic impedance and Total Organic Carbon (TOC). The assessment of this shale formation is carried out by first analyzing rock physics properties to identify the interest zone of a reservoir. The next step is performing geochemical analysis to quantify TOC and determine the maturity level of the shale formation. In order to map the shale formation distribution, we transform seismic data into acoustic impedance and further into organic-rich shale (TOC) distribution. Our analysis of petrophysical and geochemical properties shows that there are two interest zones, in the depth interval of 2030-2182 m (zone A) and 2204-2396 m (zone B). Both zones are predicted as shale layer that has very good organic richness criteria and fulfills sufficient maturity level. In addition, the shale layer distribution is represented by inverted acoustic impedance and TOC, where we found the consistent information related to identified interest zone A and B, which is indicated by relatively low impedance and relatively high TOC. Further, these two zones (zone A and B) are predicted as the potential sweet spot to be explored as unconventional hydrocarbon resource.

  19. Development of thermodynamic databases for geochemical calculations

    Energy Technology Data Exchange (ETDEWEB)

    Arthur, R.C. [Monitor Scientific, L.L.C., Denver, Colorado (United States); Sasamoto, Hiroshi; Shibata, Masahiro; Yui, Mikazu [Japan Nuclear Cycle Development Inst., Tokai, Ibaraki (Japan); Neyama, Atsushi [Computer Software Development Corp., Tokyo (Japan)

    1999-09-01

    Two thermodynamic databases for geochemical calculations supporting research and development on geological disposal concepts for high level radioactive waste are described in this report. One, SPRONS.JNC, is compatible with thermodynamic relations comprising the SUPCRT model and software, which permits calculation of the standard molal and partial molal thermodynamic properties of minerals, gases, aqueous species and reactions from 1 to 5000 bars and 0 to 1000degC. This database includes standard molal Gibbs free energies and enthalpies of formation, standard molal entropies and volumes, and Maier-Kelly heat capacity coefficients at the reference pressure (1 bar) and temperature (25degC) for 195 minerals and 16 gases. It also includes standard partial molal Gibbs free energies and enthalpies of formation, standard partial molal entropies, and Helgeson, Kirkham and Flowers (HKF) equation-of-state coefficients at the reference pressure and temperature for 1147 inorganic and organic aqueous ions and complexes. SPRONS.JNC extends similar databases described elsewhere by incorporating new and revised data published in the peer-reviewed literature since 1991. The other database, PHREEQE.JNC, is compatible with the PHREEQE series of geochemical modeling codes. It includes equilibrium constants at 25degC and l bar for mineral-dissolution, gas-solubility, aqueous-association and oxidation-reduction reactions. Reaction enthalpies, or coefficients in an empirical log K(T) function, are also included in this database, which permits calculation of equilibrium constants between 0 and 100degC at 1 bar. All equilibrium constants, reaction enthalpies, and log K(T) coefficients in PHREEQE.JNC are calculated using SUPCRT and SPRONS.JNC, which ensures that these two databases are mutually consistent. They are also internally consistent insofar as all the data are compatible with basic thermodynamic definitions and functional relations in the SUPCRT model, and because primary

  20. Compilation of kinetic data for geochemical calculations

    Energy Technology Data Exchange (ETDEWEB)

    Arthur, R.C. [Monitor Scientific, LLC., Denver, Colorado (United States); Savage, D. [Quintessa, Ltd., Nottingham (United Kingdom); Sasamoto, Hiroshi; Shibata, Masahiro; Yui, Mikazu [Japan Nuclear Cycle Development Inst., Tokai, Ibaraki (Japan). Tokai Works

    2000-01-01

    Kinetic data, including rate constants, reaction orders and activation energies, are compiled for 34 hydrolysis reactions involving feldspars, sheet silicates, zeolites, oxides, pyroxenes and amphiboles, and for similar reactions involving calcite and pyrite. The data are compatible with a rate law consistent with surface reaction control and transition-state theory, which is incorporated in the geochemical software package EQ3/6 and GWB. Kinetic data for the reactions noted above are strictly compatible with the transition-state rate law only under far-from-equilibrium conditions. It is possible that the data are conceptually consistent with this rate law under both far-from-equilibrium and near-to-equilibrium conditions, but this should be confirmed whenever possible through analysis of original experimental results. Due to limitations in the availability of kinetic data for mine-water reactions, and in order to simplify evaluations of geochemical models of groundwater evolution, it is convenient to assume local-equilibrium in such models whenever possible. To assess whether this assumption is reasonable, a modeling approach accounting for couple fluid flow and water-rock interaction is described that can be use to estimate spatial and temporal scale of local equilibrium. The approach is demonstrated for conditions involving groundwater flow in fractures at JNC's Kamaishi in-situ tests site, and is also used to estimate the travel time necessary for oxidizing surface waters to migrate to the level of a HLW repository in crystalline rock. The question of whether local equilibrium is a reasonable assumption must be addressed using an appropriate modeling approach. To be appropriate for conditions at the Kamaishi site using the modeling approach noted above, the fracture fill must closely approximate a porous mine, groundwater flow must be purely advective and diffusion of solutes across the fracture-host rock boundary must not occur. Moreover, the

  1. Geochemical Treasure Hunt for Primary School Children

    Science.gov (United States)

    Tesmer, Maja; Frick, Daniel; Gerrits, Ruben; des GFZ-GeoWunderWerkstatt, Schülerlabor

    2017-04-01

    How can you inspire school children for geochemistry, and scientific exploratory urge? The key is to raise their curiosity and make learning new things a hands-on experience. The Fellows of the European Marie Curie Initial Training Network IsoNose designed and established a "Geochemical Treasure Hunt" to excite children for scientific investigations. This workshop explains primary school children the research and scientific methods of isotopic geochemistry, and their use to understand processes on the Earth's surface. From obtaining 'samples', performing various experiments, the school children gather clues leading them to the hidden treasure on the Telegrafenberg (campus of the GFZ Potsdam). The course was designed for school children to learn hands-on the meaning of elements, atoms and isotopes. In small groups the children conduct experiments of simplified methods being indispensable to any isotope geochemist. However, prior to working in any laboratory environment, a security briefing is necessary. For the course, two stages were implemented; firstly the use of harmful substances and dangerous equipment was minimised, and secondly children were equipped with size-matched personal protective equipment (lab coats, gloves, and safety googles). The purification of elements prior to isotopic analysis was visualised using colour chromatography. However, instead of using delicate mass spectrometers for the isotope ratio measurements, the pupils applied flame spectroscopy to analyse their dissolved and purified mineral solutions. Depending on the specific element present, a different colour was observed in the flame. The children plotted their colours of the flame spectroscopy onto a map and by interpreting the emerging colour patterns they localized the treasure on the map. In small teams they swarmed out on the Telegrafenberg to recover the hidden treasure. The project leading to this outreach activity has received funding from the People Programme (Marie Curie

  2. Geochemical fate of arsenic in swine litter

    Science.gov (United States)

    Quazi, S.; Makris, K.; Sarkar, D.; Datta, R.; Punamiya, P.

    2007-12-01

    Swine diet is often supplemented by organoarsenicals, such as roxarsone to treat diseases and to promote growth. Recent data reported roxarsone degradation under anaerobic conditions in poultry litter, but no such data exist for swine wastes typically stored in unprotected lagoons in concentrated animal feeding operations (CAFOs). However, serious environmental health risk may arise upon significant arsenic (As) release into solution. The problem may be exacerbated under certain environmental conditions where organoarsenicals, such as roxarsone transform into the more toxic inorganic As, posing serious health risk to the surrounding ecosystem. The objective of this study were to analyze swine wastes collected from 19 randomly selected CAFOs in the USA for As concentrations, and to determine the geochemical fate of As in the swine waste suspensions. Swine wastes were analyzed for total-recoverable, total soluble, and water-extractable As, which were measured by ICP-MS. Speciation of As was performed following a well-established hyphenated technique using HPLC- ICPMS. Swine waste suspensions differed in solids contents; thus, the particulate matters with varying As concentrations were spiked with roxarsone and incubated under dark/light and aerobic/anaerobic conditions. Findings show the prevalence of inorganic As [As(V)] in swine waste suspension solutions. Roxarsone underwent degradation to both organoarsenicals, such as p-ASA, as well as inorganic arsenate and to a number of unidentified metabolites. Roxarsone degradation kinetics was influenced by the solids content and the air conditions (anaerobic/aerobic) of the swine waste suspensions. Maximum degradation rates were observed under anaerobic conditions, in suspensions which were low in solids content. Roxarsone degradation was primarily microbially-mediated, but in certain cases abiotic degradation was also observed, which were significantly slower.

  3. A geochemical model of the Platanares geothermal system, Honduras

    Science.gov (United States)

    Janik, C. J.; Truesdell, A. H.; Goff, F.; Shevenell, L.; Stallard, M. L.; Trujillo, P. E.; Counce, D.

    1991-03-01

    Results of exploration drilling combined with results of geologic, geophysical, and hydrogeochemical investigations have been used to construct a geochemical model of the Platanares geothermal system, Honduras. Three coreholes were drilled, two of which produced fluids from fractured Miocene andesite and altered Cretaceous to Eocene conglomerate at 450 to 680 m depth. Large volume artesian flows of 160-165°C, predominantly bicarbonate water are chemically similar to, but slightly less saline than widespread boiling hot-spring waters. The chemistry of the produced fluid is dominated by equilibrium reactions in sedimentary rocks at greater depths and higher temperatures than those measured in the wells. Chemical, isotope, and gas geothermometers indicate a deep fluid temperature of 200-245°C and reflect a relatively short residence time in the fractures feeding the wells. Chloride-enthalpy relations as well as isotopic and chemical compositions of well discharges, thermal springs, and local cold waters support a conceptual model of ascending high-temperature (minimum 225°C) parent fluid that has cooled conductively to form the 160-165°C shallow (to 680 m) fluid encountered by the wells. The hot-spring waters are formed by boiling and steam loss from more or less conductively cooled parent fluid. The more dilute boiling spring waters (Cl = ˜32 mg/kg) have cooled from > 225°C to about 160°C by conduction and from 160°C to 98°C by boiling. The most concentrated boiling spring waters (Cl = 37 mg/kg) have cooled from > 225°C to about 200°C by conduction and from 200°C to 98°C by boiling. Intermediate concentrations reflect mixed cooling paths.

  4. Application of fractal content-gradient method for delineating geochemical anomalies associated with copper occurrences in the Yangla ore field, China

    Directory of Open Access Journals (Sweden)

    Zhen Chen

    2017-01-01

    Full Text Available Fractal and multi-fractal content area method finds application in a wide variety of geological, geochemical and geophysical fields. In this study, the fractal content-gradient method was used on 1:10,000 scale to delineate geochemical anomalies associated with copper mineralization. Analysis of geochemical data from the Yangla super large Cu-Pb-Zn polymetallic ore district using the fractal content-gradient method, combined with other geological data from this area, indicates that ore-prospecting in the ore district should focus on Cu as the main metal and Pb-Zn and Au as the auxiliary metals. The types of deposits include (in chronological order re-formed sedimentary exhalative (SEDEX, skarns, porphyries, and hydrothermal vein-type deposits. Three ore-prospecting targets are divided on a S–N basis: (1 the Qulong exploration area, in which the targets are porphyry-type Cu deposits; (2 the Zongya exploration area, where the targets are porphyry-type Cu and hydrothermal vein-type Cu-Pb polymetallic deposits; and (3 the Zarelongma exploration area, characterized mainly skarn-type “Yangla-style” massive sulfide Cu-Pb deposits. Our study demonstrates that the fractal content-gradient method is convenient, simple, rapid, and direct for delineating geochemical anomalies and for outlining potential exploration targets.

  5. Exploring Online Students' Self-Regulated Learning with Self-Reported Surveys and Log Files: A Data Mining Approach

    Science.gov (United States)

    Cho, Moon-Heum; Yoo, Jin Soung

    2017-01-01

    Many researchers who are interested in studying students' online self-regulated learning (SRL) have heavily relied on self-reported surveys. Data mining is an alternative technique that can be used to discover students' SRL patterns from large data logs saved on a course management system. The purpose of this study was to identify students' online…

  6. Hydrologic Regulation of Global Geochemical Cycles

    Science.gov (United States)

    Maher, K.

    2015-12-01

    understand the processes controlling marine isotopic weathering processes, the need to integrate solute and solid transport into Earth system models, and the need to understand the role of extreme physical and temporal heterogeneities in moderating geochemical fluxes.

  7. Predicting species’ tolerance to salinity and alkalinity using distribution data and geochemical modelling: a case study using Australian grasses

    Science.gov (United States)

    Saslis-Lagoudakis, C. Haris; Hua, Xia; Bui, Elisabeth; Moray, Camile; Bromham, Lindell

    2015-01-01

    Background and Aims Salt tolerance has evolved many times independently in different plant groups. One possible explanation for this pattern is that it builds upon a general suite of stress-tolerance traits. If this is the case, then we might expect a correlation between salt tolerance and other tolerances to different environmental stresses. This association has been hypothesized for salt and alkalinity tolerance. However, a major limitation in investigating large-scale patterns of these tolerances is that lists of known tolerant species are incomplete. This study explores whether species’ salt and alkalinity tolerance can be predicted using geochemical modelling for Australian grasses. The correlation between taxa found in conditions of high predicted salinity and alkalinity is then assessed. Methods Extensive occurrence data for Australian grasses is used together with geochemical modelling to predict values of pH and electrical conductivity to which species are exposed in their natural distributions. Using parametric and phylogeny-corrected tests, the geochemical predictions are evaluated using a list of known halophytes as a control, and it is determined whether taxa that occur in conditions of high predicted salinity are also found in conditions of high predicted alkalinity. Key Results It is shown that genera containing known halophytes have higher predicted salinity conditions than those not containing known halophytes. Additionally, taxa occurring in high predicted salinity tend to also occur in high predicted alkalinity. Conclusions Geochemical modelling using species’ occurrence data is a potentially useful approach to predict species’ relative natural tolerance to challenging environmental conditions. The findings also demonstrate a correlation between salinity tolerance and alkalinity tolerance. Further investigations can consider the phylogenetic distribution of specific traits involved in these ecophysiological strategies, ideally by

  8. Geochemical water signature in the Bahariya Depression, Western Desert, Egypt

    Science.gov (United States)

    Sciarra, Alessandra; Mazzini, Adriano; Lupi, Matteo; Hammed, Mohammed S.

    2017-04-01

    The Bahariya Oasis is located about 200 km SW of Cairo in the central part of the Western Desert of Egypt. It occupies a sub-elliptic 40 km wide depression stretching NE-SW for approximately 90 km. The Bahariya Oasis has been targeted for numerous geological studies on structural geology, stratigraphy, and iron ore deposits. The oasis was characterized since the Roman times by the presence of natural hydrothermal springs venting water from the relatively shallow Nubia Sandstone formation. Inside the depression are visible numerous circular concentric features that morphologically resemble the hydrothermal vent complexes observed at igneous provinces in other localities of the planet. In order to investigate the origin and the mechanisms of formation of these features, we conducted a fieldwork survey as well as fluids sampling from the available well sites. The aim was to constrain the origin of the fluids that potentially triggered or facilitated the formation of the concentric structures observed on the field. This study presents the geochemical results of groundwaters and soil gas samples. Ten samples were collected from deep wells present in the area. In particular, 8 warm waters were collected by wells between 800 m and 1200 m deep. The measured temperatures at these sites range from 36.5 °C to 52.3°C, while the coldest wells have temperatures ranging from 27.9 °C to 36.5°C. For each sample collected from the wells we analyzed the major, minor and trace elements, dissolved gases (He, Ne, H2, O2, N2, CH4, CO2, Rn), and relative isotopic values. In the areas around the wells we measured CO2 and CH4 fluxes as well as radon activity. Overall, the water showed a high value of dissolved Rn, ranging from 9 to 43 Bq/l, and dissolved CO2 ranging from 5.9 to 17.4 cc/l. The waters show a radiogenic signature of isotopic helium, highlighting very prolonged interaction with local crust enriched in radiogenic elements. The isotopic values of δ18O and δD show a clear

  9. U.S. Geological Survey Scientific Activities in the Exploration of Antarctica: Introduction to Antarctica (Including USGS Field Personnel: 1946-59)

    Science.gov (United States)

    Tony K. Meunier Edited by Williams, Richard S.; Ferrigno, Jane G.

    2007-01-01

    INTRODUCTION Antarctica is the planet's fifth largest continent [13.2 million km2 (5.1 million mi2)]; it contains the Earth's largest (of two) remaining ice sheets; it is considered to be one of the most important scientific laboratories on Earth. This report is the introduction to a series that covers 60 years of U.S. Geological Survey (USGS) scientific activity in Antarctica. It will concentrate primarily on three major topics:

  10. GEOCHEMICAL MODELING OF F AREA SEEPAGE BASIN COMPOSITION AND VARIABILITY

    Energy Technology Data Exchange (ETDEWEB)

    Millings, M.; Denham, M.; Looney, B.

    2012-05-08

    From the 1950s through 1989, the F Area Seepage Basins at the Savannah River Site (SRS) received low level radioactive wastes resulting from processing nuclear materials. Discharges of process wastes to the F Area Seepage Basins followed by subsequent mixing processes within the basins and eventual infiltration into the subsurface resulted in contamination of the underlying vadose zone and downgradient groundwater. For simulating contaminant behavior and subsurface transport, a quantitative understanding of the interrelated discharge-mixing-infiltration system along with the resulting chemistry of fluids entering the subsurface is needed. An example of this need emerged as the F Area Seepage Basins was selected as a key case study demonstration site for the Advanced Simulation Capability for Environmental Management (ASCEM) Program. This modeling evaluation explored the importance of the wide variability in bulk wastewater chemistry as it propagated through the basins. The results are intended to generally improve and refine the conceptualization of infiltration of chemical wastes from seepage basins receiving variable waste streams and to specifically support the ASCEM case study model for the F Area Seepage Basins. Specific goals of this work included: (1) develop a technically-based 'charge-balanced' nominal source term chemistry for water infiltrating into the subsurface during basin operations, (2) estimate the nature of short term and long term variability in infiltrating water to support scenario development for uncertainty quantification (i.e., UQ analysis), (3) identify key geochemical factors that control overall basin water chemistry and the projected variability/stability, and (4) link wastewater chemistry to the subsurface based on monitoring well data. Results from this study provide data and understanding that can be used in further modeling efforts of the F Area groundwater plume. As identified in this study, key geochemical factors

  11. Geochemical modelling baseline compositions of groundwater

    DEFF Research Database (Denmark)

    Postma, Diederik Jan; Kjøller, Claus; Andersen, Martin Søgaard

    2008-01-01

    Reactive transport models, were developed to explore the evolution in groundwater chemistry along the flow path in three aquifers; the Triassic East Midland aquifer (UK), the Miocene aquifer at Valreas (F) and the Cretaceous aquifer near Aveiro (P). All three aquifers contain very old groundwaters...... of the evolution in natural baseline properties in groundwater....

  12. Multielement geochemical dataset of surficial materials for the northern Great Basin

    Science.gov (United States)

    Coombs, Mary Jane; Kotlyar, Boris B.; Ludington, Steve; Folger, Helen W.; Mossotti, Victor G.

    2002-01-01

    This report presents geochemical data generated during mineral and environmental assessments for the Bureau of Land Management in northern Nevada, northeastern California, southeastern Oregon, and southwestern Idaho, along with metadata and map representations of selected elements. The dataset presented here is a compilation of chemical analyses of over 10,200 stream-sediment and soil samples originally collected during the National Uranium Resource Evaluation's (NURE) Hydrogeochemical and Stream Sediment Reconnaissance (HSSR) program of the Department of Energy and its predecessors and reanalyzed to support a series of mineral-resource assessments by the U.S. Geological Survey (USGS). The dataset also includes the analyses of additional samples collected by the USGS in 1992. The sample sites are in southeastern Oregon, southwestern Idaho, northeastern California, and, primarily, in northern Nevada. These samples were collected from 1977 to 1983, before the development of most of the present-day large-scale mining infrastructure in northern Nevada. As such, these data may serve as an important baseline for current and future geoenvironmental studies. Largely because of the very diverse analytical methods used by the NURE HSSR program, the original NURE analyses in this area yielded little useful geochemical information. The Humboldt, Malheur-Jordan-Andrews, and Winnemucca-Surprise studies were designed to provide useful geochemical data via improved analytical methods (lower detection levels and higher precision) and, in the Malheur-Jordan-Andrews and Winnemucca Surprise areas, to collect additional stream-sediment samples to increase sampling coverage. The data are provided in *.xls (Microsoft Excel) and *.csv (comma-separated-value) format. We also present graphically 35 elements, interpolated ("gridded") in a geographic information system (GIS) and overlain by major geologic trends, so that users may view the variation in elemental concentrations over the

  13. Geochemical Data for Samples Collected in 2007 Near the Concealed Pebble Porphyry Cu-Au-Mo Deposit, Southwest Alaska

    Science.gov (United States)

    Fey, David L.; Granitto, Matthew; Giles, Stuart A.; Smith, Steven M.; Eppinger, Robert G.; Kelley, Karen D.

    2008-01-01

    In the summer of 2007, the U.S. Geological Survey (USGS) began an exploration geochemical research study over the Pebble porphyry copper-gold-molydenum (Cu-Au-Mo) deposit in southwest Alaska. The Pebble deposit is extremely large and is almost entirely concealed by tundra, glacial deposits, and post-Cretaceous volcanic and volcaniclastic rocks. The deposit is presently being explored by Northern Dynasty Minerals, Ltd., and Anglo-American LLC. The USGS undertakes unbiased, broad-scale mineral resource assessments of government lands to provide Congress and citizens with information on national mineral endowment. Research on known deposits is also done to refine and better constrain methods and deposit models for the mineral resource assessments. The Pebble deposit was chosen for this study because it is concealed by surficial cover rocks, it is relatively undisturbed (except for exploration company drill holes), it is a large mineral system, and it is fairly well constrained at depth by the drill hole geology and geochemistry. The goals of the USGS study are (1) to determine whether the concealed deposit can be detected with surface samples, (2) to better understand the processes of metal migration from the deposit to the surface, and (3) to test and develop methods for assessing mineral resources in similar concealed terrains. This report presents analytical results for geochemical samples collected in 2007 from the Pebble deposit and surrounding environs. The analytical data are presented digitally both as an integrated Microsoft 2003 Access? database and as Microsoft 2003 Excel? files. The Pebble deposit is located in southwestern Alaska on state lands about 30 km (18 mi) northwest of the village of Illiamna and 320 km (200 mi) southwest of Anchorage (fig. 1). Elevations in the Pebble area range from 287 m (940 ft) at Frying Pan Lake just south of the deposit to 1146 m (3760 ft) on Kaskanak Mountain about 5 km (5 mi) to the west. The deposit is in an area of

  14. Sky Surveys

    Science.gov (United States)

    Djorgovski, S. George; Mahabal, Ashish; Drake, Andrew; Graham, Matthew; Donalek, Ciro

    Sky surveys represent a fundamental data basis for astronomy. We usethem to map in a systematic way the universe and its constituents andto discover new types of objects or phenomena. We review the subject,with an emphasis on the wide-field, imaging surveys, placing them ina broader scientific and historical context. Surveys are now the largestdata generators in astronomy, propelled by the advances in informationand computation technology, and have transformed the ways in whichastronomy is done. This trend is bound to continue, especially with thenew generation of synoptic sky surveys that cover wide areas of the skyrepeatedly and open a new time domain of discovery. We describe thevariety and the general properties of surveys, illustrated by a number ofexamples, the ways in which they may be quantified and compared, andoffer some figures of merit that can be used to compare their scientificdiscovery potential. Surveys enable a very wide range of science, and that isperhaps their key unifying characteristic. As new domains of the observableparameter space open up thanks to the advances in technology, surveys areoften the initial step in their exploration. Some science can be done withthe survey data alone (or a combination of data from different surveys),and some require a targeted follow-up of potentially interesting sourcesselected from surveys. Surveys can be used to generate large, statisticalsamples of objects that can be studied as populations or as tracers of largerstructures to which they belong. They can be also used to discover orgenerate samples of rare or unusual objects and may lead to discoveriesof some previously unknown types. We discuss a general framework ofparameter spaces that can be used for an assessment and comparison ofdifferent surveys and the strategies for their scientific exploration. As we aremoving into the Petascale regime and beyond, an effective processing andscientific exploitation of such large data sets and data streams pose

  15. A survey to explore what information, advice and support community-dwelling people with stroke currently receive to manage instability and falls.

    Science.gov (United States)

    Shovlin, Eleanor; Kunkel, Dorit

    2017-09-13

    To describe and determine the benefits of the information and support services currently offered to people with stroke experiencing instability and falls. A cross-sectional survey study. Two hundred and fifty-six surveys were sent out to community stroke groups in Hampshire and the Isle of Wight, as well as to people with stroke on a patient register. One hundred and twenty-five surveys were returned. A total of 107 participants (86%) reported instability and 62 (50%) had experienced a fall in the preceding year; 29 (28%) had reportedly received information on falls prevention. Forty-four participants (43%) sought help from health professionals following instability and falls; just over half reported that the information they received was useful. One quarter (n = 11) of those seeking help were referred on to falls clinics; all attended and 86% felt attending had been beneficial. However, only one participant was followed up by these clinics. Findings suggest that the majority of people with stroke who have experienced instability and falls did not receive any information and support, with very few referred on to falls clinics. Health professionals play a key role in information provision and facilitating access to falls prevention programs. Further research is required to determine the most effective ways to implement current guidelines to manage instability and falls in this high-risk group. Implications for rehabilitation: Many community-dwelling people with stroke did not receive any information, help or support after experiencing instability and falls. Clinicians must stress that falls are a complication, not an expectation, post-stroke. Information on falls prevention and available support services should be offered to individuals prior to discharge from hospital, in GP practices and in rehabilitation settings. All individuals with stroke seeking health professional help following instability and falls should be referred on to falls clinics for

  16. Geochemical Modeling of ILAW Lysimeter Water Extracts

    Energy Technology Data Exchange (ETDEWEB)

    Cantrell, Kirk J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2014-12-22

    Geochemical modeling results of water extracts from simulated immobilized low-activity waste (ILAW) glasses, placed in lysimeters for eight years suggest that the secondary phase reaction network developed using product consistency test (PCT) results at 90°C may need to be modified for field conditions. For sediment samples that had been collected from near the glass samples, the impact of glass corrosion could be readily observed based upon the pH of their water extracts. For unimpacted sediments the pH ranged from 7.88 to 8.11 with an average of 8.04. Sediments that had observable impacts from glass corrosion exhibited elevated pH values (as high as 9.97). For lysimeter sediment samples that appear to have been impacted by glass corrosion to the greatest extent, saturation indices determined for analcime, calcite, and chalcedony in the 1:1 water extracts were near equilibrium and were consistent with the secondary phase reaction network developed using PCT results at 90°C. Fe(OH)3(s) also appears to be essentially at equilibrium in extracts impacted by glass corrosion, but with a solubility product (log Ksp) that is approximately 2.13 units lower than that used in the secondary phase reaction network developed using PCT results at 90°C. The solubilities of TiO2(am) and ZrO2(am) also appear to be much lower than that assumed in the secondary phase reaction network developed using PCT results at 90°C. The extent that the solubility of TiO2(am) and ZrO2(am) were reduced relative to that assumed in the secondary phase reaction network developed using PCT results at 90°C could not be quantified because the concentrations of Ti and Zr in the extracts were below the estimated quantification limit. Gibbsite was consistently highly oversaturated in the extract while dawsonite was at or near equilibrium. This suggests that dawsonite might be a more suitable phase for the secondary phase reaction network

  17. Levelling and merging of two discrete national-scale geochemical databases: A case study showing the surficial expression of metalliferous black shales

    Science.gov (United States)

    Smith, Steven M.; Neilson, Ryan T.; Giles, Stuart A.

    2015-01-01

    Government-sponsored, national-scale, soil and sediment geochemical databases are used to estimate regional and local background concentrations for environmental issues, identify possible anthropogenic contamination, estimate mineral endowment, explore for new mineral deposits, evaluate nutrient levels for agriculture, and establish concentration relationships with human or animal health. Because of these different uses, it is difficult for any single database to accommodate all the needs of each client. Smith et al. (2013, p. 168) reviewed six national-scale soil and sediment geochemical databases for the United States (U.S.) and, for each, evaluated “its appropriateness as a national-scale geochemical database and its usefulness for national-scale geochemical mapping.” Each of the evaluated databases has strengths and weaknesses that were listed in that review.Two of these U.S. national-scale geochemical databases are similar in their sample media and collection protocols but have different strengths—primarily sampling density and analytical consistency. This project was implemented to determine whether those databases could be merged to produce a combined dataset that could be used for mineral resource assessments. The utility of the merged database was tested to see whether mapped distributions could identify metalliferous black shales at a national scale.

  18. The provision of family-centred intensive care bereavement support in Australia and New Zealand: Results of a cross sectional explorative descriptive survey.

    Science.gov (United States)

    Mitchell, Marion; Coombs, Maureen; Wetzig, Krista

    2017-05-01

    Caring for the bereaved is an intrinsic part of intensive care practice with family bereavement support an important aspect of the nursing role at end of life. However, reporting on provision of intensive care family bereavement support at a national level has not been well reported since an Australian paper published ten years ago. The objective was to investigate provision of family bereavement support in intensive care units (ICU) across New Zealand (NZ) and Australia. A cross-sectional exploratory descriptive web-based survey was used. All ICUs [public/private, neonatal/pediatrics/adults] were included. The survey was distributed to one nursing leader from each identified ICU (n=229; 188 in Australia, 41 in NZ). Internal validity of the survey was established through piloting. Descriptive statistics were used to analyse the data. Ethical approval was received by the ethics committees of two universities. One-hundred and fifty-three (67%) responses were received from across New Zealand and Australia with 69.3% of respondents from the public sector. Whilst respondents reported common bereavement practices to include debriefing for staff after a traumatic death (87.9%), there was greater variation in sending a sympathy card to families (NZ 54.2%, Australia 20.8%). Fifty percent of responding New Zealand units had a bereavement follow-up service compared to 28.3% of Australian unit respondents. Of those with follow-up services, 92.3% of New Zealand units undertook follow-up calls to families compared to 76.5% of Australian units. Bereavement follow-up services were mainly managed by social workers in Australia and nursing staff in New Zealand. This is the first Australia and New Zealand-wide survey on ICU bereavement support services. Whilst key components of family bereavement support remain consistent over the past decade, there were fewer bereavement follow-up services in responding Australian ICUs in 2015. As a quality improvement initiative, support for this

  19. Forensic Assessment of Metal Contaminated Rivers in the 21st Century Using Geochemical and Isotopic Tracers

    Directory of Open Access Journals (Sweden)

    Jerry R. Miller

    2013-05-01

    Full Text Available Documentation of contaminant source and dispersal pathways in riverine environments is essential to mitigate the potentially harmful effects of contaminants on human and ecosystem health, and is required from a legal perspective (particularly where the polluter pays principle is in effect in assessing site liability. Where multiple natural and/or anthropogenic sources exist, identification of contaminant provenance has proven problematic, and estimated contributions from a specific source are often the subject of judicial debate. The past, current, and future use of geochemical and isotopic tracers in environmental forensic investigations of contaminant provenance, transport, and fate are analyzed herein for sediment-associated trace metals in riverine environments, particularly trace metals derived from mining and refining operations. The utilized methods have evolved significantly over the past four decades. Of primary significance has been the growing integration of geomorphic and stratigraphic techniques with the use of an increasing number of geochemical tracers including stable isotopes. The isotopes of Pb have been particularly well studied, and have been applied to a wide range of environmental media. Advances in analytical chemistry since the early 1990s have allowed for the precise characterization of other non-traditional stable isotopic systems within geological materials. The potential for using these non-traditional isotopes as tracers in river systems has yet to be adequately explored, but a number of these isotopes (e.g., Cd, Cu, Cr, Hg, Sb, and Zn show considerable promise. Moreover, some of these isotopes (e.g., those of Cu, Cr, and Hg may provide important insights into biogeochemical cycling processes within aquatic environments. This review suggests that future environmental forensic investigations will be characterized by an interdisciplinary approach that combines the use of multiple geochemical tracers with detailed

  20. Quality of doctoral nursing education in the United Kingdom: exploring the views of doctoral students and staff based on a cross-sectional questionnaire survey.

    Science.gov (United States)

    McKenna, Hugh; Keeney, Sinead; Kim, Mi Ja; Park, Chang Gi

    2014-07-01

    To evaluate the quality of doctoral education in nursing in the United Kingdom. In recent decades, doctoral education programmes in nursing are increasing worldwide. There are many reasons for this and concerns have been raised regarding the quality of provision in and across countries. To date, the quality of doctoral education on a global level has not been reported in the literature. This United Kingdom study is part of a seven country investigation into the quality of doctoral education in nursing (Australia, Japan, Korea, South Africa, Thailand, United Kingdom and United States of America). A quantitative study using a cross-sectional comparative survey design. An online survey was administered to collect the views of doctoral students and staff members on four domains: programme, faculty/staff, resource and evaluation. The study was carried out between 2010-2012. In most cases, staff perceived these more positively than students and the differences in perception were often statistically significant. Interestingly, many students rated the quality of supervision as excellent, whereas no staff member rated supervision this highly. The crucial importance of resources was confirmed in the path analysis of the four Quality of Doctoral Nursing Education domains. This demonstrates that investment in resources is much more cost-effective than investment in the other domains in relation to improving the overall quality of doctoral education in nursing. This study has wide-ranging implications for how the quality of doctoral education is monitored and enhanced. © 2013 John Wiley & Sons Ltd.

  1. Medical students as patients: implications of their dual role as explored in a vignette-based survey study of 1027 medical students at nine medical schools.

    Science.gov (United States)

    Roberts, Laura Weiss; Warner, Teddy D; Smithpeter, Megan; Rogers, Melinda; Horwitz, Russell

    2011-01-01

    Medical students experience a range of mental and physical illnesses during training and may encounter significant barriers in seeking health care. Little is known about the issues surrounding the dual role as both learner and patient when a medical student seeks care at his or her training institution. A confidential survey examining medical students' health care needs, practices, and concerns was administered at 9 US medical schools. One part of the survey focused on responses to 4 medical student-patient vignettes. The vignettes systematically varied preexisting student vs preexisting patient status before assuming a medical student-patient role, and the vignettes also varied illness situations that were more vs less stigmatizing. Responses were analyzed using χ(2) and multivariate analysis of variance tests. A total of 1027 students participated. We found that students were more likely to accept the dual role as medical student-patient in vignettes depicting a preexisting patient role than a preexisting student role. Students sought to avoid the dual role as student-patient in the context of stigmatizing health concerns. Women students were more likely than men to reject the dual role in all cases. Medical students appear to be sensitive to the conflicts that may be associated with the dual role as both medical student and patient when seeking care at their training institution. Our data suggest the importance of substantive efforts to promote the health, interests, and well-being of medical student-patients. Copyright © 2011 Elsevier Inc. All rights reserved.

  2. Social stratification, development and health in Pakistan: an empirical exploration of relationships in population-based national health examination survey data.

    Science.gov (United States)

    Hadden, Wilbur C; Pappas, Gregory; Khan, Abdul Qayyum

    2003-11-01

    There is a growing literature on an overall direct relationship between health and social position in developed countries. The relationship, however, is less well documented in developing countries where social hierarchies are changing more rapidly, demographic and health transitions are less advanced, and this topic has received less attention from researchers than in some developed countries. This paper presents an empirical investigation of the relationship between social stratification and social development and population health using data on over 6000 adults from the National Health Survey of Pakistan, a nationally representative health examination survey of people in that country. We analyze four indicators of poor nutrition in adults from this data set. The findings reveal complex relationships among social development, social stratification and the consequences for the health of the people of Pakistan. Underweight is related to economic status, anemia to education and social development, and both severe dental caries and a monotonous diet are related to both development and economic status which interact with each other. These results suggest that continued conceptual refinement and the development of standardized measures of stratification and development would contribute to building cross-nationally comparable data sets addressing issues of the relationship among health and economic development and health transitions.

  3. A survey for endodontists in today's economy: exploring the current state of endodontics as a profession and the relationship between endodontists and their referral base.

    Science.gov (United States)

    Lin, Stan; Sabbah, Wael; Sedgley, Christine M; Whitten, Brian

    2015-03-01

    The purpose of this study was to assess the perceptions, referral trends, and practice patterns of practicing endodontists in the United States and any effect the recent economy may have had on these. A 24-question survey was formulated and sent via www.surveymonkey.com to 3255 active members of the American Association of Endodontists. Overall, 875 participants completed the survey, a response rate of 26.9%. The average number of treatment cases per day was 5.7. Average work hours per week were 34.3 for men and 30.7 for women (P endodontic procedures, and 7.7% placed implants. Among endodontists who practice in urban areas, 69.7% believed there were too many endodontists, and 50% have delayed their retirement plans because of recent economic impact, compared with their suburban and rural counterparts at 66.1% and 38%, 25.9% and 33.1%, respectively (P endodontics as a specialty, but those who have practiced more than 20 years were more pessimistic than those with less experience (P 20 years), practice in urban settings, and practice in a solo environment are most significantly affected. Copyright © 2015 American Association of Endodontists. Published by Elsevier Inc. All rights reserved.

  4. A geochemical study of the Rio Pantanos area, Department of Antioquia, Colombia preliminary report

    Science.gov (United States)

    Alminas, Henry V.; Mosier, Elwin L.

    1972-01-01

    Geochemical sampling in the Western Cordillera has delineated an 18 km 2 area anomalous in copper, molybdenum, and silver. Highly anomalous metal contents are found in stream sediment, soil, and outcrop samples collected within this area. The area is underlain by intrusive granodiorite to quartz diorite that has porphyritic and granitoid phases. Most of the outcrop samples contain disseminated pyrite, chalcopyrite, and bornite. A geochemical reconnaissance sampling program in the Western Cordillera, formulated by Andros Jimeno V., Director, Instituto National de Investigaciones Geologico-Mineras (INGEOMINAS), and Earl M. Irving, U. S. Geological Survey (USGS) Chief of Party in Colombia, was carried out from 1969 to 1971 by geologists of the INGEOMINAS office in Medellin. This work was part of a cooperative program of INGEOMINAS and the USGS sponsored by the Government of Colombia and the Agency for International Development, U. S. Department of State. Seventeen generally east-trending traverses were completed across the Western Cordillera. These traverses, generally paralleling major drainages, cross the range at intervals of 10 to 30 km.

  5. Snowmelt induced hydrologic perturbations drive dynamic microbiological and geochemical behaviors across a shallow riparian aquifer

    Directory of Open Access Journals (Sweden)

    Robert eDanczak

    2016-05-01

    Full Text Available Shallow riparian aquifers represent hotspots of biogeochemical activity in the arid western US. While these environments provide extensive ecosystem services, little is known of how natural environmental perturbations influence subsurface microbial communities and associated biogeochemical processes. Over a six-month period we tracked the annual snowmelt-driven incursion of groundwater into the vadose zone of an aquifer adjacent to the Colorado River, leading to increased dissolved oxygen (DO concentrations in the normally suboxic saturated zone. Strong biogeochemical heterogeneity was measured across the site, with abiotic reactions between DO and sulfide minerals driving rapid DO consumption and mobilization of redox active species in reduced aquifer regions. Conversely, extensive DO increases were detected in less reduced sediments. 16S rRNA gene surveys tracked microbial community composition within the aquifer, revealing strong correlations between increases in putative oxygen-utilizing chemolithoautotrophs and heterotrophs and rising DO concentrations. The gradual return to suboxic aquifer conditions favored increasing abundances of 16S rRNA sequences matching members of the Microgenomates (OP11 and Parcubacteria (OD1 that have been strongly implicated in fermentative processes. Microbial community stability measurements indicated that deeper aquifer locations were relatively less affected by geochemical perturbations, while communities in shallower locations exhibited the greatest change. Reactive transport modeling of the geochemical and microbiological results supported field observations, suggesting that a predictive framework can be applied to develop a greater understanding of such environments.

  6. Tracking riverborne sediment and contaminants in Commencement Bay, Washington, using geochemical signatures

    Science.gov (United States)

    Takesue, Renee K.; Conn, Kathleen E.; Dinicola, Richard S.

    2017-09-29

    Large rivers carry terrestrial sediment, contaminants, and other materials to the coastal zone where they can affect marine biogeochemical cycles and ecosystems. This U.S. Geological Survey study combined river and marine sediment geochemistry and organic contaminant analyses to identify riverborne sediment and associated contaminants at shoreline sites in Commencement Bay, Puget Sound, Washington, that could be used by adult forage fish and other marine organisms. Geochemical signatures distinguished the fine fraction (<0.063 millimeter, mm) of Puyallup River sediment—which originates from Mount Rainier, a Cascade volcano—from glacial fine sediment in lowland bluffs that supply sediment to beaches. In combination with activities of beryllium-7 (7Be), a short-lived radionuclide, geochemical signatures showed that winter 2013–14 sediment runoff from the Puyallup River was transported to and deposited along the north shore of Commencement Bay, then mixed downward into the sediment column. The three Commencement Bay sites at which organic contaminants were measured in surface sediment did not have measurable 7Be activities in that layer, so their contaminant assemblages were attributed to sources from previous years. Concentrations of organic contaminants (the most common of which were polycyclic aromatic hydrocarbons, polychlorinated biphenyls, and fecal sterols) were higher in the <0.063-mm fraction compared to the <2-mm fraction, in winter compared to summer, in river suspended sediment compared to river bar and bank sediment, and in marine sediment compared to river sediment. The geochemical property barium/aluminum (Ba/Al) showed that the median percentage of Puyallup River derived fine surface sediment along the shoreline of Commencement Bay was 77 percent. This finding, in combination with higher concentrations of organic contaminants in marine rather than river sediment, indicates that riverborne sediment-bound contaminants are retained in shallow

  7. Fiscal 2000 survey report on overseas geological structure, etc. Project for exchanging experts - Exploration technology (Indonesia); 2000 nendo kaigai chishitsu kozo to chosa hokokusho. Gijutsusha koryu jigyo - Tansa gijutsu bunya (Indonesia)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    For the stabilization of coal supply/demand in the APEC (Asia-Pacific Economic Cooperation Conference) region and for the stable supply of coal to Japan, Japanese engineers and experts were dispatched to Indonesia, where coal production was remarkably increasing and efforts were being actively exerted to develop new coal mining fields, for training Indonesian specialists there, and Indonesian specialists were invited to Japan for training here. Japanese instructors on dispatch delivered lectures on coal geology, exploration, and exploitation at the human resource development center of Bandung City during the period July 20 through August 4, 2000, which was followed by a coal outcrop survey training session in the field. The trainees were from Kalimantan, Sumatra, Java, etc., and numbered 30. The trainees invited to Japan received lectures and training related to coal geology, exploration, and mining programs during the period October 19 through November 18, 2000, at the Geological Survey of Japan, Agency of Industrial Science and Technology, Ministry of International Trade and Industry; Matsushima Coal Mining Co., Ltd.; Enzan Plant, Tone Corporation; DIA Consultants Co., Ltd.; and Mitsubishi Materials Corporation. (NEDO)

  8. Multichannel seismic reflection surveys over the Antarctic continental margin relevant to petroleum resource studies: Chapter 5 in Antarctica as an exploration-hydrocarbon potential, geology, and hazards

    Science.gov (United States)

    Behrendt, John C.

    1990-01-01

    More than 100,000 km of marine multichannel seismic profiles have been acquired over the continental margin of Antarctica since 1976 by scientific research programs of Australia, Brazil, France, Italy, Japan, Norway, Poland, United Kingdom, United States, U.S.S.R. and West Germany. Although scientific results are reported for most of these data, they also are relevant to petroleum resource assessment. Because of the one or two orders of magnitude greater cost of standard land survey techniques in Antarctica compared with marine techniques in areas of open water, there will likely be no great amount of coverage on the interior of the Antarctic ice sheet. Despite this, several countries are experimenting in a research mode using land systems, and deep crustal reflection sur eys at carefully selected interior sites will probably be made soon.

  9. Frequency and circumstances of falls in people with inclusion body myositis: a questionnaire survey to explore falls management and physiotherapy provision.

    Science.gov (United States)

    Hiscock, A; Dewar, L; Parton, M; Machado, P; Hanna, M; Ramdharry, G

    2014-03-01

    To survey the incidence and circumstances of falls for people with inclusion body myositis (IBM) in the UK, and to investigate the provision of physiotherapy and falls management. Postal questionnaire survey. Participants completed questionnaires at home. Ninety-four people diagnosed with IBM were screened against the inclusion criteria. Seventy-two potential participants were sent a questionnaire, and 62 were completed and returned. Invited participants were sent an adapted Falls Event Questionnaire pertaining to falls, perceived causes of falls and the provision of physiotherapy. Questionnaires were returned anonymously. The proportions of respondents who reported a fall or a near fall, along with the frequencies of falls and near falls were calculated. Descriptive data of falls were collected pertaining to location and cause. Data analysis was performed to investigate provision of physiotherapy services. The response rate was 86% [62/72, mean (standard deviation) age 68 (8) years]. Falls were reported by 98% (61/62) of respondents, with 60% (37/62) falling frequently. In this study, age was not found to be an indicator of falls risk or frequency. Twenty-one percent (13/62) of respondents had not seen a physiotherapist in relation to their IBM symptoms, and of those that had, 31% (15/49) had not seen a physiotherapist until more than 12 months after IBM was diagnosed. Only 18% (11/61) of fallers reported that they had received falls management input. Falls are a common occurrence for people with IBM, independent of age and years since symptoms first presented, and are poorly addressed by appropriate physiotherapy management. National falls guidelines are not being followed, and referral rates to physiotherapy need to improve. Copyright © 2013 Chartered Society of Physiotherapy. Published by Elsevier Ltd. All rights reserved.

  10. Reject the ridiculous and explore the plausible: A Bayesian McMC approach to model assessment and uncertainty analysis for airborne electromagnetic surveys (Invited)

    Science.gov (United States)

    Minsley, B. J.; Brodie, R. C.; Bedrosian, P.; Esfahani, A.

    2013-12-01

    Geophysical data are typically used to infer a single ';best' model consistent with observations and prior information. However, because of non-uniqueness, limited resolution, and data errors, many models satisfy both the data and reasonable prior assumptions. Instead of seeking to describe the properties of any single model, we developed a trans-dimensional Bayesian Markov chain Monte Carlo (McMC) algorithm for the analysis of airborne electromagnetic (AEM) surveys that assesses the characteristics of models that are consistent with observations and prior assumptions. This is a powerful tool for model assessment and uncertainty analysis, and provides a wealth of information that can be used to make inferences about plausible subsurface properties. For example, we can estimate the likelihood of geological interfaces as a function of depth, quantify the probability that resistivity is above or below a certain threshold within a given depth range, assess model resolution and depth of investigation, or query subsets of models that are consistent with auxiliary datasets. Model assessment and uncertainty analysis is compounded by the large volume of data that are typically acquired for AEM surveys. Here, we discuss the mechanics of a McMC algorithm developed for the analysis of time- or frequency-domain airborne electromagnetic data, along with examples where this algorithm has been used to add new insight into model uncertainty and geological interpretations. Specific aspects of the algorithm that will be discussed include: the trans-dimensional nature of the program, which allows the number of layers to be a free parameter; the capability to assess random and/or systematic data errors as unknown parameters; the use of parallel computing tools to run multiple chains for a single dataset in order to assess convergence, and to analyze many datasets simultaneously; the use of stochastic Newton sampling to optimize sampling efficiency; and the ability to integrate multiple

  11. An integrated geochemical and geoelectrical Investigation of an ...

    African Journals Online (AJOL)

    Geochemical analysis of borehole soil samples for Total Petroleum Hydrocarbon (TPH), geoelectrical imaging and geotechnical sieve analysis were used to assess the intensity and extent of hydrocarbon contamination at an ancient oil spill site near Ejama-Ebubu community in Eleme, near Port Harcourt. The subsurface ...

  12. Geochemical and isotopic signatures for the identification of ...

    Indian Academy of Sciences (India)

    The objective of this study is to identify the extent of seawater intruded area by major geochemical and isotopic signatures. A total of 102 groundwater samples were collected and analysed for major and minor ions. Groundwater samples with electrical conductivity (EC) greater than 5000 S/cm and a river mouth sample ...

  13. phosphorus sorption in relation to soil grain size and geochemical ...

    African Journals Online (AJOL)

    Mgina

    Agriculture (Morogoro) for determination of. P sorption capacity, pH and soil grain size distribution. Sub-samples were also taken to. Southern and Eastern Africa Mineral Centre. - SEAMIC (Dar es Salaam) where soil geochemical compositions were determined. Particle size distribution was determined by the hydrometer ...

  14. Geochemical study of volcanic and associated granitic rocks from ...

    Indian Academy of Sciences (India)

    Geochemical studies and modelling show that both volcanic and granitic magmas from the western part of the Johor National Park, Endau Rompin are different and probably have different sources. The geo- chemical plot suggests that both dacite/rhyolite and andesite probably have a common origin as in many.

  15. Geochemical behaviour of vanadium in iron—titanium oxides

    NARCIS (Netherlands)

    Schuiling, R.D.; Feenstra, A.

    The following geochemical rules-of-thumb seem to hold for vanadium: 1. (1) Magnetites as a group have higher V contents than either hematites or ilmenites. 2. (2) In magnetite—hematite pairs, however, the hematite has the higher V content. 3. (3) In magnetite—ilmenite pairs, the magnetite

  16. mineralogical and geochemical trends in lateritic weathering profiles ...

    African Journals Online (AJOL)

    Three soil profiles on the basement rocks in Awa-Oru-Ijebu Igbo area of southwestern Nigeria were investigated for the formation secondary minerals and the comparison of the mineralogical and geochemical patterns in the weathering profiles overlying the rocks during the humid tropical weathering. X-ray data showed that ...

  17. Geochemical characteristics and organic carbon sources within the ...

    Indian Academy of Sciences (India)

    Carbon (POC, DOC) and carbon isotopes (δ13C) within two headwater tributaries to the Xi River Basin, southwest China were analyzed to document the geochemical characteristics and sources of organic carbon (C) within basins characterized by a monsoonal climate and karst landforms. δ¹³CPOC value and C/N ratio ...

  18. Adaptive processing of geochemical analysis by means of spline model

    Directory of Open Access Journals (Sweden)

    А. Я. Білецький

    2000-09-01

    Full Text Available Proposed is adaptive algorithm of geochemical analysis processing by means of spline model. Demonstrated is the possibility of splines to reveal heterogeneous fields in the composition of iron ore which, because of considerable dispersion of random component, is practically impossible to reveal

  19. Remote Raman - laser induced breakdown spectroscopy (LIBS) geochemical investigation under Venus atmospheric conditions

    Energy Technology Data Exchange (ETDEWEB)

    Clegg, Sanuel M [Los Alamos National Laboratory; Barefield, James E [Los Alamos National Laboratory; Humphries, Seth D [Los Alamos National Laboratory; Wiens, Roger C [Los Alamos National Laboratory; Vaniman, D. T. [Los Alamos National Laboratory; Sharma, S. K. [UNIV OF HAWAII; Misra, A. K. [UNIV OF HAWAII; Dyar, M. D. [MT. HOLYOKE COLLEGE; Smrekar, S. E. [JET PROPULSION LAB.

    2010-12-13

    The extreme Venus surface temperatures ({approx}740 K) and atmospheric pressures ({approx}93 atm) create a challenging environment for surface missions. Scientific investigations capable of Venus geochemical observations must be completed within hours of landing before the lander will be overcome by the harsh atmosphere. A combined remote Raman - LIBS (Laser Induced Breakdown Spectroscopy) instrument is capable of accomplishing the geochemical science goals without the risks associated with collecting samples and bringing them into the lander. Wiens et al. and Sharma et al. demonstrated that both analytical techniques can be integrated into a single instrument capable of planetary missions. The focus of this paper is to explore the capability to probe geologic samples with Raman - LIBS and demonstrate quantitative analysis under Venus surface conditions. Raman and LIBS are highly complementary analytical techniques capable of detecting both the mineralogical and geochemical composition of Venus surface materials. These techniques have the potential to profoundly increase our knowledge of the Venus surface composition, which is currently limited to geochemical data from Soviet Venera and VEGA landers that collectively suggest a surface composition that is primarily tholeiitic basaltic with some potentially more evolved compositions and, in some locations, K-rich trachyandesite. These landers were not equipped to probe the surface mineralogy as can be accomplished with Raman spectroscopy. Based on the observed compositional differences and recognizing the imprecise nature of the existing data, 15 samples were chosen to constitute a Venus-analog suite for this study, including five basalts, two each of andesites, dacites, and sulfates, and single samples of a foidite, trachyandesite, rhyolite, and basaltic trachyandesite under Venus conditions. LIBS data reduction involved generating a partial least squares (PLS) model with a subset of the rock powder standards to

  20. Geochemical characteristics of Lower Jurassic source rocks in the Zhongkouzi Basin

    Science.gov (United States)

    Niu, Haiqing; Han, Xiaofeng; Wei, Jianshe; Zhang, Huiyuan; Wang, Baowen

    2018-01-01

    Zhongkouzi basin is formed in Mesozoic and Cenozoic and developed on the Hercynian folded belt, the degree of exploration for oil and gas is relatively low hitherto. In order to find out the geochemical characteristics of the source rocks and the potentials for hydrocarbon generation. The research result shows that by analysis the geochemical characteristics of outcrop samples and new core samples in Longfengshan Group, Longfengshan Group are most developed intervals of favorable source rocks. They are formed in depression period of the basin when the sedimentary environments is salt water lacustrine and the water is keeping stable; The organic matter abundance is middle-higher, the main kerogen type is II1-II2 and few samples act as III type, The organic matter maturity is low maturity to medium maturity. The organic matter maturity of the source rock from eastern part of the basin is higher than in the western region. The source rock of Longfengshan Group are in the hydrocarbon generation threshold. The great mass of source rocks are matured and in the peak stage of oil generation.

  1. Geochemical characterization of PM10 emitted by glass factories in Murano, Venice (Italy).

    Science.gov (United States)

    Rampazzo, Giancarlo; Masiol, Mauro; Visin, Flavia; Rampado, Egisto; Pavoni, Bruno

    2008-05-01

    The atmosphere in Venice, like in other European cities, is influenced by complex PM(10) multi-emission sources with a net tendency to exceed the limits fixed by the directive 99/30/EC. This study investigated the composition of an ensemble of similar industrial sources, the Murano Glassmaking Factories (MGFs), and their influence on the Venice air quality, using a modelling approach, statistical analysis and geochemical considerations. Preliminary modelling simulations were conducted to select three sampling sites along the way of preferential transport of pollutants from source between February and April 2003. Subsequently, a sampling campaign was carried out in the same period of simulations. Concentrations of PM(10), eight major elements (Al, Ti, Ca, Mg, Na, K, Fe, Mn), 20 minor and trace elements (Li, V, Cr, Co, Ni, Cu, Zn, Ga, As, Se, Rb, Sr, Ru, Rh, Cd, Sb, Ba, Ce, Pt, Pb) and four PAHs (BaA, BbF, BkF, BaP) were quantified. The analytical results were statistically processed for exploring the relationships between inorganic elements and organic compounds, and results were interpreted using geochemical considerations. Results show a MGF component of PM(10) characterised by two different fingerprints: the first linked to glass raw material composition and the second mainly related to glass additives. Particularly, Cd, Se, As and Li preserve their ratios in all study area, and are interpreted as principal components of the MGF emissions. Other fingerprints can be traced to urban sources from the Venetian mainland.

  2. Validation of the WATEQ4 geochemical model for uranium

    Energy Technology Data Exchange (ETDEWEB)

    Krupka, K.M.; Jenne, E.A.; Deutsch, W.J.

    1983-09-01

    As part of the Geochemical Modeling and Nuclide/Rock/Groundwater Interactions Studies Program, a study was conducted to partially validate the WATEQ4 aqueous speciation-solubility geochemical model for uranium. The solubility controls determined with the WATEQ4 geochemical model were in excellent agreement with those laboratory studies in which the solids schoepite (UO/sub 2/(OH)/sub 2/ . H/sub 2/O), UO/sub 2/(OH)/sub 2/, and rutherfordine ((UO/sub 2/CO/sub 3/) were identified as actual solubility controls for uranium. The results of modeling solution analyses from laboratory studies of uranyl phosphate solids, however, identified possible errors in the characterization of solids in the original solubility experiments. As part of this study, significant deficiencies in the WATEQ4 thermodynamic data base for uranium solutes and solids were corrected. Revisions included recalculation of selected uranium reactions. Additionally, thermodynamic data for the hydroxyl complexes of U(VI), including anionic (VI) species, were evaluated (to the extent permitted by the available data). Vanadium reactions were also added to the thermodynamic data base because uranium-vanadium solids can exist in natural ground-water systems. This study is only a partial validation of the WATEQ4 geochemical model because the available laboratory solubility studies do not cover the range of solid phases, alkaline pH values, and concentrations of inorganic complexing ligands needed to evaluate the potential solubility of uranium in ground waters associated with various proposed nuclear waste repositories. Further validation of this or other geochemical models for uranium will require careful determinations of uraninite solubility over the pH range of 7 to 10 under highly reducing conditions and of uranyl hydroxide and phosphate solubilities over the pH range of 7 to 10 under oxygenated conditions.

  3. GEOBASI: The geochemical Database of Tuscany Region (Italy

    Directory of Open Access Journals (Sweden)

    Brunella Raco

    2015-03-01

    Full Text Available In this study the new Regional Geochemical Database (RGDB, called GEOBASI, is presented and illustrated in the framework of a joint collaboration among the three Tuscan universities (Florence, Pisa and Siena, CNR-IGG (Institute of Geosciences and Earth Resources of Pisa, ARPAT (Regional Agency for the Environmental Protection, LAMMA (Environmental Modelling and Monitoring Laboratory for Sustainable Development Consortium and S.I.R.A. (Territorial and Environmental Informative System of Tuscany. The database has permitted the construction of a repository where the geochemical information (compositional and isotopic has been stored in a structured way so that it can be available for different groups of users (e.g. institutional, public and private companies. The information contained in the database can in fact be downloaded freely and queried to correlate geochemistry to other non compositional variables. The first phase of the project was aimed at promoting the use of the geochemical data already available from previous investigations through a powerful Web-GIS interface to implement the exploratory statistics graphical-numerical tools used to: 1 analyse the spatial variability of the investigated context, 2 highlight the geographic location of data pertaining to classes of values or single cases, 3 compare the results of different analytical methodologies applied to the determination of the same element and/or chemical species, 4 extract the geochemical data related to specific monitoring plans and/or geographical areas, and finally 5 recover information about data below the detection limit to understand their impact on the behaviour of the investigated variable. Developments of this project will be focused on the definition of rules and standardized methods in a way that external users could also interactively pursue the RGDB. Furthermore, a detailed investigation of the Scarlino-Follonica plain will permit the improvement and test of

  4. Surveying the citizen science landscape: an exploration of the design, delivery and impact of citizen science through the lens of the Open Air Laboratories (OPAL) programme.

    Science.gov (United States)

    Davies, Linda; Fradera, Roger; Riesch, Hauke; Lakeman-Fraser, Poppy

    2016-07-22

    This paper provides a short introduction to the topic of citizen science (CS) identifying the shift from the knowledge deficit model to more inclusive, participatory science. It acknowledges the benefits of new technology and the opportunities it brings for mass participation and data manipulation. It focuses on the increase in interest in CS in recent years and draws on experience gained from the Open Air Laboratories (OPAL) programme launched in England in 2007. The drivers and objectives for OPAL are presented together with background information on the partnership, methods and scales. The approaches used by researchers ranged from direct public participation in mass data collection through field surveys to research with minimal public engagement. The supporting services focused on education, particularly to support participants new to science, a media strategy and data services. Examples from OPAL are used to illustrate the different approaches to the design and delivery of CS that have emerged over recent years and the breadth of opportunities for public participation the current landscape provides. Qualitative and quantitative data from OPAL are used as evidence of the impact of CS. While OPAL was conceived ahead of the more recent formalisation of approaches to the design, delivery and analysis of CS projects and their impact, it nevertheless provides a range of examples against which to assess the various benefits and challenges emerging in this fast developing field.

  5. Exploring the personal and professional impact of reflective practice groups: a survey of 18 cohorts from a UK clinical psychology training course.

    Science.gov (United States)

    Knight, Katherine; Sperlinger, David; Maltby, Michael

    2010-01-01

    Given the importance of reflective practice within clinical psychology and a lack of empirical research, this study aimed to investigate the personal and professional impact of reflective practice groups (RPGs) for former trainees. This study followed an analytic survey design utilizing a convenience sample of qualified clinical psychologists from a UK training programme. A RPG questionnaire (RPGQ) was developed for the purposes of the study. Following initial pilot work, 297 qualified psychologists were invited to complete the RPGQ. One hundred and twenty-four psychologists (42%) completed the RPGQ. Factor analysis yielded two underlying constructs labelled 'value' and 'distress'. The RPGQ demonstrated significant internal and test-retest reliability. The majority rated the RPGs as valuable for personal and professional development and learning about group processes. Just under half however reported distress as a result of the groups. Whilst some trainees, who reported distress, were able to view the challenges positively, one-sixth were not. Potency of facilitation and group size significantly predicted levels of perceived value and distress. In view of the ethical issues raised by compulsory RPGs, recommendations were made to keep group sizes within an average of 10-13, utilize facilitators with sufficient training in group processes and ensure additional methods of reflective practice development are available. Further suggestions and recommendations for future research in relation to coping and personal learning style were also made.  © 2009 John Wiley & Sons, Ltd.

  6. Geochemical and Geophysical Characteristics of the Balud Ophiolitic Complex (BOC, Masbate Island, Philippines: Implications for its Generation, Evolution and Emplacement

    Directory of Open Access Journals (Sweden)

    Pearlyn C. Manalo

    2015-01-01

    Full Text Available This paper presents the first field, geochemical and geophysical information on the recently recognized Early Cretaceous Balud Ophiolitic Complex (BOC in the island of Masbate in the Central Philippines. Mapping of the western limb of the island revealed that only the upper crustal section of the BOC is exposed in this area. Geochemically, the pillow basalts are characterized by transitional mid-oceanic ridge basalt-island arc tholeiitic compositions. Gravity surveys yielded low Bouguer anomaly values that are consistent with the highly dismembered nature of the BOC. Short wavelength, high amplitude magnetic anomalies registered across the study area are attributed to shallow magnetic sources. This is taken to support the model that the ophiolitic complex occurs as thin crustal slivers that are not deeply-rooted in the mantle. Comparing BOC with other ophiolites in the Central Philippines, such as those in the islands of Sibuyan, Leyte and Bohol, suggests the possibility of a common or contiguous source for similarly-aged and geochemically composed crust-mantle sequences in the region.

  7. Identification of source of a marine oil-spill using geochemical and chemometric techniques.

    Science.gov (United States)

    Lobão, Marcio M; Cardoso, Jari N; Mello, Marcio R; Brooks, Paul W; Lopes, Claudio C; Lopes, Rosangela S C

    2010-12-01

    The current work aimed to identify the source of an oil spill off the coast of Maranhão, Brazil, in September 2005 and effect a preliminary geochemical survey of this environment. A combination of bulk analytical parameters, such as carbon isotope (δ(13)C) and Ni/V ratios, and conventional fingerprinting methods (High Resolution Gas Chromatography and Mass Spectrometry) were used. The use of bulk methods greatly speeded source identification for this relatively unaltered spill: identification of the likely source was possible at this stage. Subsequent fingerprinting of biomarker distributions supported source assignment, pointing to a non-Brazilian oil. Steranes proved the most useful biomarkers for sample correlation in this work. Distribution patterns of environmentally more resilient compound types, such as certain aromatic structures, proved inconclusive for correlation, probably in view of their presence in the background. Copyright © 2010 Elsevier Ltd. All rights reserved.

  8. A geophysical, geochemical and remote sensing investigation of the water resources at the city of Chihuahua, Mexico

    Science.gov (United States)

    Rodriguez-Pineda, Jose Alfredo

    This doctoral dissertation is an investigation of the underground water resources of a typical urban center in and northern Mexico, the City of Chihuahua. In the first part of the investigation I analyzed by remote sensing the urban growth and the consequent water demand and supply of the city of Chihuahua over a period of 22 years (1975--1997). A linear and a regression model was successfully fit to the data and can be used to forecast future water needs based on urban growth. The second study was a gravity survey of about 200 stations and a reprocessing of about 800 earlier gravity readings in the City of Chihuahua area to define the local geologic structures. The findings were used as a first exploration step to assess groundwater resources in the area. Landsat TM imagery, 30-m resolution, was applied in conjunction with Bouguer gravity anomalies to understand and define the lateral extension of the Chihuahua, Tabalaopa Basins, and the western side of the Aldama Basin. Depth and strata thickness of these three alluvial basins were defined by gravity modeling and constrained by exploration oil well data and published stratigraphic columns. The gravity results showed that the western side of the Chihuahua Basin could be the site of potential aquifers. Also, the gravity results suggested an structural gap between the southern side of the Tabalaopa Basin and the Horcasitas Basin, likely a former course of the Chuviscar River. This gap exposes the Horcasitas Basin as another basin with promise as future groundwater source. The last part of this research focused on the groundwater pollution generated by the discharge of sewage into the Rio Chuviscar and Sacramento for decades by the City of Chihuahua. Based on a groundwater and during three consecutive years (from 1993 to 1995) the elements derived mainly from the urban sewage were identified in the Tabalaopa Aquifer. A multivariable statistical evaluation supported by a surface water sampling and analysis, and of a

  9. Geochemical barriers of manganese distribution in edaphotopes of Dnieper Prysamarye

    Directory of Open Access Journals (Sweden)

    N. N. Tsvetkova

    2015-01-01

    Full Text Available Microelement composition is an important condition of edaphotopes as the major, summarizing parts of any biogeocenosis. Microelements in ultra-microquantity are necessary for vital functions of all organisms, but their anthropogenic accumulation and transformation in soil environment represents a real threat for living organisms’ health and stability of the biosphere as a whole. Geochemical barriers are local zones where the conditions of elemental migration are significantly different, resulting in accumulation of some chemical elements. The relevance of geochemical barriers’ study consists in the prospective possibility of artificial limitation of the migration of polluting elements in the environment. The aim of this research is to determine the role of geochemical barriers in distribution and migration of manganese in edaphotopes of Dnieper Prysamarye. Content of manganese in soils, regularity of its distribution and relationship between a number of physical and chemical properties of soils were considered in the course of investigation. Besides, this paper summarizes the main features and regularities of the different geochemical barriers’ formation. Manganese content in soils was analyzed by atomic absorption spectrophotometry. The objects of the research are edaphotopes of the biogeocenoses of Dnieper Prisamarye situated in steppe zone of Ukraine, subzone of forb-fescue-stipa steppe. According to our data, the average concentrations of manganese in the horizons of 0–50 cm of ordinary chernozem, alkaline-saline meadow-forest soil, floodplain meadow-forest and sod upland soils are 495 ± 24, 610 ± 223, 810 ± 220, 51 ± 11 mg/kg of ovendry weight soil, respectively. Furthermore, the authors investigated the correlation between the content of manganese and absorption capacity, humus content, composition of exchange cations, pH and dry residue of soils under study. The results obtained demonstrate that specific soil horizons can be

  10. Geochemical Parameters Required from the SKB Site Characterisation Programme

    Energy Technology Data Exchange (ETDEWEB)

    Bath, Adrian [Intellisci Ltd., Loughborough (United Kingdom)

    2002-01-01

    SKB has described its approach to site characterisation in a number of Technical Reports. One of the scientific topics in which specific information requirements and priorities are set out is geochemistry. This report for SKI examines critically whether the geochemical parameters identified in the SKB programme documents will be adequate for safety and regulatory requirements. It also examines some of the details of parameter requirements and interpretation tools that will be necessary to convert site investigation data into knowledge about chemical conditions and groundwater movements. The SKB strategy for geochemical data focuses on a small number of 'suitability indicators', primarily dissolved oxygen, pH and salinity. Their parameter requirements aim to assess those primary characteristics, as well as to acquire a wider range of data that will support those assessments and provide a broader understanding of candidate areas. An initial observation in this review that, though it is a primary suitability indicator, dissolved oxygen apparently will not be measured and instead will be inferred from other redox indicators. This raises a number of issues about sampling and monitoring measures, analytical data reliability and sensitivity, and the degree of confidence in geochemical understanding. A geochemical programme involves reconnaissance by desk study and acquisition of new data at levels of details that are appropriate to the stage of site investigations. As early as possible, a conceptual model of a candidate area should help to define the objectives of geochemical measurements on both rock and groundwater samples. It is recommended that parameters requirements should be defined and considered not only in terms of isolated measurements but more in terms of addressing broader objectives that relate to safety and also to geoscientific understanding. The safety priorities remain (e.g. dissolved oxygen) but will then be supported by an understanding of

  11. Achievement report for fiscal 1997 on the research and development to lead to gas hydrate using technology. Research and development on exploration, research and development on drilling technologies, survey and research on a method to evaluate environmental impact, and survey and research on a utilization system; 1997 nendo gas haidoreto shigenka gijutsu sendo kenkyu kaihatsu seika hokokusho. Tansanado ni kansuru kenkyu kaihatsu, kussaku gijutsu ni kansuru kenkyu kaihatsu, kankyo eikyo hyokaho no chosa kenkyu, riyo system ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-09-01

    The present study is intended to analyze comprehensively geophysical, geological and geochemical data, and establish a technology to estimate distribution of gas hydrate (GH) in sea areas around Japan. It is also intended to develop a high-accuracy resource amount calculating method utilizing the result of excavation of GH planned in the future. In order to achieve these goals, the following activities are performed: (1) study on a method to estimate production environment of GH deposits, (2) development of a method to estimate GH stability areas by using the crust thermal flow measuring method, and (3) study on estimation of GH distribution and wide-area potential. For the study (1), an inorganic element analyzer was introduced, and calibration of devices was performed in fiscal 1997. A survey was carried out on literatures related to distribution of inorganic elements and process of GH deposit production. In the study (2), design and trial fabrication were executed on a high-accuracy crust thermal flow measuring device, capable of long-term continuous observation. In the study (3), re-processing focusing on BSR was implemented by using the latest computer and analysis software on the data in which BSR has been confirmed in the surveys done in the past on sea areas around Japan. (NEDO)

  12. Interface Induced Carbonate Mineralization: A Fundamental Geochemical Process Relevant to Carbon Sequestration

    Energy Technology Data Exchange (ETDEWEB)

    Teng, H. Henry [PI, The George Washington University; Xu, Huifang [Co-PI, University of Wisconsin-Madison

    2013-07-17

    We have approached the long-standing geochemical question why anhydrous high-Mg carbonate minerals (i.e., magnesite and dolomite) cannot be formed at ambient conditions from a new perspective by exploring the formation of MgCO{sub 3} and Mg{sub x}Ca{sub (1-x)}CO{sub 3} in non-aqueous solutions. Data collected from our experiments in this funding period suggest that a fundamental barrier, other than cation hydration, exists that prevents Mg{sup 2+} and CO{sub 3}{sup 2-} ions from forming long-range ordered structures. We propose that this barrier mainly stems from the lattice limitation on the spatial configuration of CO{sub 3} groups in magnesite crystals. On the other hand, the measured higher distribution coefficients of Mg between magnesian calcites formed in the absence and presence of water give us a first direct proof to support and quantify the cation hydration effect.

  13. Extensive geochemical studies in the geothermal field of Cerro Prieto, Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Manon, A.; Mazor, E.; Jimenez, M.; Sanchez, A.; Fausto, J.; Zenizo, C.

    1977-12-01

    Data collected during 12 years of operation of the chemical laboratory at Cerro Prieto are presented. These data include analyses of dissolved ions and gases in exploration and production wells and in thermal springs, as observed in repeatedly collected samples and measurements of wellhead and separator pressures, flow of steam and water and size of orifice, condition of well, etc., at the time of chemical sampling. The discussion in Part I is intended to illustrate graphically the geochemical pattern of the Cerro Prieto fluids, to search for ion correlations, and to provide a preliminary discussion of a small number of topics. The figures and tables in Part II provide the bulk of information in the report. (JGB)

  14. Exploration technology

    Energy Technology Data Exchange (ETDEWEB)

    Roennevik, H.C. [Saga Petroleum A/S, Forus (Norway)

    1996-12-31

    The paper evaluates exploration technology. Topics discussed are: Visions; the subsurface challenge; the creative tension; the exploration process; seismic; geology; organic geochemistry; seismic resolution; integration; drilling; value creation. 4 refs., 22 figs.

  15. Investigation on type and origin of iron mineralization at Mesgar occurrence, south of Zanjan, using petrological, mineralogical and geochemical data

    Directory of Open Access Journals (Sweden)

    Mohammad Ebrahimi

    2015-04-01

    Full Text Available Introduction Mesgar iron occurrence is located in northwestern part of the Central Iran, 115 km south of Zanjan. Although there is a sequence of volcanic-pyroclastic rocks accompanied by iron mineralization, no detailed works had been conducted in the area. The present paper provides an overview of the geological framework, the mineralization characteristics, and the results of geochemical study of the Mesgar iron occurrence with an application to the ore genesis. Identification of these characteristics can be used as a model for exploration of this type of iron mineralization in the Central Iran and elsewhere. Materials and methods Detailed field work has been carried out at different scales in the Mesgar area. About 16 polished thin and thin sections from host rocks and mineralized and altered zones were studied by conventional petrographic and mineralogic methods at the Department of Geology, University of Zanjan. In addition, a total of 3 samples from least-altered volcanic host rocks and 2 samples from ore zones from the Mesgar occurrence were analyzed by ICP-MS and ICP-OES for whole-rock major and trace elements and REE compositions at the Zarazma Laboratories, Tehran, Iran. Results and Discussion Based on field observation, rock units exposed in the Mesgar area consist of Miocene sedimentary rocks and volcanic-pyroclastic units (Rādfar et al., 2005. The pyroclastic units consist of volcanic breccia and agglomerate. They lie concordantly on the Miocene sedimentary units, and are in turn concordantly overlain by andesitic basalt lavas. The lavas show porphyritic texture consisting of plagioclase (up to 3 mm in size and pyroxene phenocrysts set in a fine-grained to glassy groundmass. Seriate, cumulophyric, glomeroporphyritic and trachytic textures are also observed. Iron mineralization occurs as vein and lens-shaped bodies within and along the contacts of pyroclastic (footwall and andesitic basalt lavas (hanging wall. The veins reach up to

  16. INEEL Subregional Conceptual Model Report Volume 2: Summary of Existing Knowledge of Geochemical Influences on the Fate and Transport of Contaminants in the Subsurface at the INEEL

    Energy Technology Data Exchange (ETDEWEB)

    Paul L. Wichlacz; Robert C. Starr; Brennon Orr

    2003-09-01

    This document summarizes previous descriptions of geochemical system conceptual models for the vadose zone and groundwater zone (aquifer) beneath the Idaho National Engineering and Environmental Laboratory (INEEL). The primary focus is on groundwater because contaminants derived from wastes disposed at INEEL are present in groundwater, groundwater provides a pathway for potential migration to receptors, and because geochemical characteristics in and processes in the aquifer can substantially affect the movement, attenuation, and toxicity of contaminants. The secondary emphasis is perched water bodies in the vadose zone. Perched water eventually reaches the regional groundwater system, and thus processes that affect contaminants in the perched water bodies are important relative to the migration of contaminants into groundwater. Similarly, processes that affect solutes during transport from nearsurface disposal facilities downward through the vadose zone to the aquifer are relevant. Sediments in the vadose zone can affect both water and solute transport by restricting the downward migration of water sufficiently that a perched water body forms, and by retarding solute migration via ion exchange. Geochemical conceptual models have been prepared by a variety of researchers for different purposes. They have been published in documents prepared by INEEL contractors, the United States Geological Survey (USGS), academic researchers, and others. The documents themselves are INEEL and USGS reports, and articles in technical journals. The documents reviewed were selected from citation lists generated by searching the INEEL Technical Library, the INEEL Environmental Restoration Optical Imaging System, and the ISI Web of Science databases. The citation lists were generated using the keywords ground water, groundwater, chemistry, geochemistry, contaminant, INEL, INEEL, and Idaho. In addition, a list of USGS documents that pertain to the INEEL was obtained and manually searched

  17. Water information bulletin No. 30: geothermal investigations in Idaho. Part 11. Geological, hydrological, geochemical and geophysical investigations of the Nampa-Caldwell and adjacent areas, southwestern Idaho

    Energy Technology Data Exchange (ETDEWEB)

    Mitchell, J.C. (ed.)

    1981-12-01

    The area under study included approximately 925 sq km (357 sq mi) of the Nampa-Caldwell portion of Canyon County, an area within the central portion of the western Snake River Plain immediately west of Boise, Idaho. Geologic mapping, hydrologic, geochemical, geophysical, including detailed gravity and aeromagnetic surveys, were run to acquire needed data. In addition, existing magnetotelluric and reflection seismic data were purchased and reinterpreted in light of newly acquired data.

  18. Modeling the geochemical distribution of rare earth elements (REEs using multivariate statistics in the eastern part of Marvast placer, the Yazd province

    Directory of Open Access Journals (Sweden)

    Amin Hossein Morshedy

    2017-07-01

    , H. and Milodowski, A.E., 2012. Occurrence and paragenesis of diagenetic monazite in the upper Triassic black shales of the Marvast region, South Yazd, Iran. Mineralogy and Petrology, 104(3-4: 197-210. Castor, S.B. and Hedrick, J.B., 2006. Rare earth elements. In: J.E. Kogel (Editors, Industrial minerals & rocks: commodities, markets, and uses. Society for mining, metallurgy, and exploration, Inc. (SME, Colorado, pp. 769-792. Everitt, B., Landau, S., Leese, M. and Stahl, D., 2011. Cluster Analysis. 5th ed., Wiley Publishing, Hoboken, Geological Survey of Iran (GSI, 2004. Exploration of rare earth element and monazite in the alluvium of the southern Marvast (eastern area. Tehran, 66 pp. (in Persian Ghorbani, M., 2013. The economic geology of Iran: mineral deposits and natural resources. Springer, London, 569 pp. Jain, A.K., Murty, M.N. and Flynn, P.J., 1999. Data clustering: a review. Association for Computing Machinery computing surveys, 31(3: 264-323. Jaireth, S., Hoatson D.M. and Miezitis Y., 2014. Geological setting and resources of the major rare-earth-element deposits in Australia. Ore Geology Reviews, 62: 72-128. Ji, H., Zeng, D., Shi, Y., Wu, Y. and Wu, X., 2007. Semi-hierarchical correspondence cluster analysis and regional geochemical pattern recognition. Journal of Geochemical Exploration, 93(2: 109-119.

  19. Multi-element geochemical mapping in Southern China.

    Science.gov (United States)

    Cheng, Zhizhong; Xie, Xuejing; Yao, Wensheng; Feng, Jizhou; Zhang, Qin; Fang, Jindong

    2014-04-01

    The 76-element Geochemical Mapping (76 GEM) Project was undertaken in southwestern China in 2000 and in southeastern China in 2008. In this project, 5244 composite samples of stream sediment at a density of one composite sample for each 1:50,000-scale map sheet were prepared from sample archives of the China Regional Geochemistry-National Reconnaissance (RGNR) Project, which have been available since 1978. The 76 elements were analyzed by using inductively coupled plasma mass spectrometry (ICP-MS), X-ray fluorescence (XRF), and inductively coupled plasma atomic emission spectroscopy (ICP-AES). In the present study, a new quality-control method known as the visualized standard map method was applied to the results of the 76 GEM project. Mean value and background value, which indicate the average concentration of the 76 elements in southern China, were derived from statistical data. Moreover, geochemical maps were compiled to demonstrate the distribution of the 76 elements in southern China.

  20. Geochemical barriers for environment protection and recovery of nonferrous metals.

    Science.gov (United States)

    Chanturiya, Valentine; Masloboev, Vladimir; Makarov, Dmitriy; Nesterov, Dmitriy; Bajurova, Julia; Svetlov, Anton; Men'shikov, Yuriy

    2014-01-01

    A study of natural minerals, ore tailings and their products as materials for artificial geochemical barriers is presented. In particular, it focuses on interaction between calcite and dolomite and sulfate solutions containing nickel, copper and iron under static conditions. Calcite of -0.1 mm fraction has been shown to perform well as a barrier when added to water phases of tailing dumps and natural reservoirs. Experiments under dynamic conditions have revealed a high potential of thermally activated copper-nickel tailings as barriers. After a 500-day precipitating period on a geochemical barrier, the contents of nickel and copper in ore dressing tailings were found to increase 12- and 28-fold, respectively. An effective sorbent of copper, iron and nickel ions is a brucite-based product of hydrochloric acid treatment of vermiculite ore tailings. Its sorption capacity can be essentially increased through thermal activation.

  1. Exploring the geochemical distribution of organic carbon in early land plants: a novel approach.

    Science.gov (United States)

    Abbott, Geoffrey D; Fletcher, Ian W; Tardio, Sabrina; Hack, Ethan

    2018-02-05

    Terrestrialization depended on the evolution of biosynthetic pathways for biopolymers including lignin, cutin and suberin, which were concentrated in specific tissues, layers or organs such as the xylem, cuticle and roots on the submillimetre scale. However, it is often difficult, or even impossible especially for individual cells, to resolve the biomolecular composition of the different components of fossil plants on such a scale using the well-established coupled techniques of gas chromatography/mass spectrometry and liquid chromatography/mass spectrometry. Here, we report the application of techniques for surface analysis to investigate the composition of Rhynia gwynne-vaughanii X-ray photoelectron spectroscopy of two different spots (both 300 µm × 600 µm) confirmed the presence of carbon. Time-of-flight secondary ion mass spectrometry (ToF-SIMS) revealed 'chemical maps' (imaging mode with 300 nm resolution) of aliphatic and aromatic carbon in the intact fossil that correlate with the vascular structures observed in high-resolution optical images. This study shows that imaging ToF-SIMS has value for determining the location of the molecular components of fossil embryophytes while retaining structural information that will help elucidate how terrestrialization shaped the early evolution of land plant cell wall biochemistry.This article is part of a discussion meeting issue 'The Rhynie cherts: our earliest terrestrial ecosystem revisited'. © 2017 The Author(s).

  2. Interpreting pan-concentrate analysis of stream sediments in geochemical exploration for gold

    Science.gov (United States)

    Fischer, Richard Philip; Fisher, Frederick S.

    1968-01-01

    A study of methods of collecting and processing samples to determine whether or not gold is present in areas of moderate size was undertaken in the northwestern part of the San Juan Mountains, Colo. As part of this study, 57 samples of pan concentrates were taken from streams draining three types of areas: (1)'barren' areas, where gold mineralization might be geologically possible but no deposits are known, (2) slightly mineralized areas that contain only a few known veins and prospects and small mines, and (3) well-mineralized areas that contain numerous veins and some very productive mines. The concentrate samples were analyzed by the fire-assay-atomic-absorption method. Replicate analyses of large samples gave results consistent enough to permit placing considerable confidence in the results obtained for smaller samples on which only one analysis was made. For general field practice, it is necessary to pan only enough sand and gravel to yield about 15 grams of concentrate. The analytical r6sults are also quantitatively compatible with known geologic relations and indicate that a few samples from a stream are adequate to distinguish between 'barren' and mineralized areas and to determine the relative amount of gold in mineralized areas. In other areas of similar gold deposits, data of this type should help decide whether more intensive search for gold deposits is justified.

  3. Methane Hydrate Exploration, Atwater Valley, Texas-Louisiana Shelf: Geophysical and Geochemical Profiles

    Science.gov (United States)

    2006-12-27

    with sediment to maximum capacity in order to leave a minimum volume of air . A clean dental dam was place on the air inflow side of the press body to...hydrates may have dissociated and diluted the pore water. Among the 15 cores we analyzed (Figure 12), pore water freshening was observed in one sample...high chloride concentrations were measured on mound F and may have masked the pore water freshening signal imparted during the dissociation of gas

  4. Reconnaissance exploration geochemistry in the central Brooks Range, northern Alaska: Implications for exploration of sediment-hosted zinc-lead-silver deposits

    Science.gov (United States)

    Kelley, K.D.; Kelley, D.L.

    1992-01-01

    A reconnaissance geochemical survey was conducted in the southern Killik River quadrangle, central Brooks Range, northern Alaska. The Brooks Range lies within the zone of continuous permafrost which may partially inhibit chemical weathering and oxidation. The minus 30-mesh and nonmagnetic heavy-mineral concentrate fractions of sediment samples were chosen as the sample media for the survey so that mechanical rather than chemical dispersion patterns would be enhanced. A total of 263 sites were sampled within the southern half of the Killik River quadrangle at an average sample density of approximately one sample per 12 km2. All samples were submitted for multi-element analyses. In the western and central Brooks Range, several known sediment-hosted Zn-Pb-Ag(-Ba) deposits occur within a belt of Paleozoic rocks of the Endicott Mountains allochthon. Exploration for this type of deposit in the Brook Range is difficult, due to the inherently high background values for Ba, Zn and Pb in shale and the common occurrence of metamorphic quartz-calcite veins, many of which contain traces of sulfide minerals. Stream sediments derived from these sources produce numerous geochemical anomalies which are not necessarily associated with significant mineralization. R-mode factor analysis provides a means of distinguishing between element associations related to lithology and those related to possible mineralization. Factor analysis applied to the multi-element data from the southern Killik River quadrangle resulted in the discovery of two additional Zn-Pb-Ag mineral occurrences of considerable areal extent which are 80-100 km east of any previously known deposit. These have been informally named the Kady and Vidlee. Several lithogeochemical element associations, or factors, and three factors which represent sulfide mineralization were identified: Ag-Pb-Zn (galena and sphalerite) and Fe-Ni-Co-Cu (pyrite ?? chalcopyrite) in the concentrate samples and Cd-Zn-Pb-As-Mn in the sediment

  5. Natural Bacterial Communities Serve as Quantitative Geochemical Biosensors

    OpenAIRE

    Smith, Mark B.; Rocha, Andrea M.; Smillie, Chris S.; Olesen, Scott W.; Paradis, Charles; Wu, Liyou; Campbell, James H; Julian L Fortney; Mehlhorn, Tonia L.; Lowe, Kenneth A.; Earles, Jennifer E.; Phillips, Jana; Techtmann, Stephen M.; Joyner, Dominique C.; Elias, Dwayne A.

    2015-01-01

    ABSTRACT Biological sensors can be engineered to measure a wide range of environmental conditions. Here we show that statistical analysis of DNA from natural microbial communities can be used to accurately identify environmental contaminants, including uranium and nitrate at a nuclear waste site. In addition to contamination, sequence data from the 16S rRNA gene alone can quantitatively predict a rich catalogue of 26 geochemical features collected from 93 wells with highly differing geochemis...

  6. POSSIBLE GEOCHEMICAL IDENTIFICATION OF THE MESOADRIATIC VORTEX

    Science.gov (United States)

    Marconi, D.; Calcara, M.

    2009-12-01

    the general MAD Vortex structure that is characterized by a strong concentration discontinuity on the transition from shallow to deep waters across the continental slope. Although, at this time, we cannot solve the finer vortex structures, our work shows the potential utility of trace-elements chemical surveys in studying the physics of marine currents and structures, and of ocean bio-chemical dynamics; processes that are commonly studied only by physical measurements. We achieved these results because in our case measured chemicals are unambiguously related to their respective continental sources, just like the tracers to the starting locations. In fact, we are also able to distinguish elements input even from aeolian and benthonic sources. The aeolian Saharan input has strong positive concentration anomalies of Fe and Al, that are limited to the surface samples of the water column. The benthonic input results in high concentrations of As and Se on the water column bottom, probably because As and Se are diagenetically released from tephra layers found close to sea bottom.

  7. Geochemical characterization of oceanic basalts using Artificial Neural Network.

    Science.gov (United States)

    Das, Pranab; Iyer, Sridhar D

    2009-12-23

    The geochemical discriminate diagrams help to distinguish the volcanics recovered from different tectonic settings but these diagrams tend to group the ocean floor basalts (OFB) under one class i.e., as mid-oceanic ridge basalts (MORB). Hence, a method is specifically needed to identify the OFB as normal (N-MORB), enriched (E-MORB) and ocean island basalts (OIB). We have applied Artificial Neural Network (ANN) technique as a supervised Learning Vector Quantisation (LVQ) to identify the inherent geochemical signatures present in the Central Indian Ocean Basin (CIOB) basalts. A range of N-MORB, E-MORB and OIB dataset was used for training and testing of the network. Although the identification of the characters as N-MORB, E-MORB and OIB is completely dependent upon the training data set for the LVQ, but to a significant extent this method is found to be successful in identifying the characters within the CIOB basalts. The study helped to geochemically delineate the CIOB basalts as N-MORB with perceptible imprints of E-MORB and OIB characteristics in the form of moderately enriched rare earth and incompatible elements. Apart from the fact that the magmatic processes are difficult to be deciphered, the architecture performs satisfactorily.

  8. Geochemical characterization of oceanic basalts using Artificial Neural Network

    Directory of Open Access Journals (Sweden)

    Iyer Sridhar D

    2009-12-01

    Full Text Available Abstract The geochemical discriminate diagrams help to distinguish the volcanics recovered from different tectonic settings but these diagrams tend to group the ocean floor basalts (OFB under one class i.e., as mid-oceanic ridge basalts (MORB. Hence, a method is specifically needed to identify the OFB as normal (N-MORB, enriched (E-MORB and ocean island basalts (OIB. We have applied Artificial Neural Network (ANN technique as a supervised Learning Vector Quantisation (LVQ to identify the inherent geochemical signatures present in the Central Indian Ocean Basin (CIOB basalts. A range of N-MORB, E-MORB and OIB dataset was used for training and testing of the network. Although the identification of the characters as N-MORB, E-MORB and OIB is completely dependent upon the training data set for the LVQ, but to a significant extent this method is found to be successful in identifying the characters within the CIOB basalts. The study helped to geochemically delineate the CIOB basalts as N-MORB with perceptible imprints of E-MORB and OIB characteristics in the form of moderately enriched rare earth and incompatible elements. Apart from the fact that the magmatic processes are difficult to be deciphered, the architecture performs satisfactorily.

  9. Geochemical signature of columbite-tantalite and environmental impact of radioactive pegmatite mining in the Parelhas region, Rio Grande do Norte, Northeast Brazil

    Energy Technology Data Exchange (ETDEWEB)

    Moura, Jorge Costa de; Cruz, Paulo R.; Pereira, Valmir, E-mail: jcmoura@cnen.gov.br, E-mail: pcruz@cnen.gov.br, E-mail: vpereira@cnen.gov.br [Comissao Nacional de Energia Nuclear (CNEN-RJ), Rio de Janeiro, RJ (Brazil); Ludka, Isabel P.; Mendes, Julio C., E-mail: ludka@geologia.ufrj.br, E-mail: julio@geologia.ufrj.br [Universidade Federal de Rio do Janeiro (CCMN/UFRJ), Rio de Janeiro, RJ (Brazil). Centro de Ciencias Matematicas e da Natureza. Dept. de Geologia

    2013-07-01

    This article comprises geochemical, structural and radiometric investigations on radioactive pegmatites of the Borborema Pegmatitic Province in Northeast Brazil. The studied area is located in the surroundings of the city of Parelhas, in the geotectonic Province of Borborema. It is well known for its thousands of pegmatitic bodies exploited in primitive mines called garimpos. The main goal was to find an efficient, cheap and routine inspection procedure to identify the origin of commercialized radioactive columbite-tantalite (coltan) ore. The Brazilian Nuclear Energy Agency (CNEN) controls uranium commerce and nuclear activity in Brazil. Without an effective method to characterize coltan ores from different localities it is impossible to control the trade. The here presented new method was developed by correlating structural features of these pegmatites with the geochemical behavior of their coltan samples. It was found that the variation of U/Th vs. Nb{sub 2}O{sub 5}/Ta{sub 2}O{sub 5} provides geochemical signatures (analytical fingerprints) for the source location of such ore. The new method was tested with coltan samples of commercial batches from the Brazilian states of Amapa and Rondonia and also generated distinct geochemical signatures. A radiometric survey (CPS) to study the environmental impact of gamma radiation was also carried out in several mines and pegmatites. It included in situ measurements of pegmatite walls, enclosing rocks, soil, and accumulated water and revealed that gamma emitters are hardly solubilized and therefore environmental gamma radiation generally is not enhanced to a dangerous level. (author)

  10. Geochemistry in the modern soil survey program.

    Science.gov (United States)

    Wilson, M A; Burt, R; Indorante, S J; Jenkins, A B; Chiaretti, J V; Ulmer, M G; Scheyer, J M

    2008-04-01

    Elemental analysis has played an important role in the characterization of soils since inception of the soil survey in the US. Recent efforts in analysis of trace and major elements (geochemistry) have provided necessary data to soil survey users in a variety of areas. The first part of this paper provides a brief overview of elemental sources, forms, mobility, and bioavailability; critical aspects important to users of soil survey geochemical data for appropriate use and interpretations. Examples are provided based on data gathered as part of the US soil survey program. The second part addresses the organization of sample collection in soil survey and how soil surveys are ideally suited as a sampling strategy for soil geochemical studies. Geochemistry is functional in characterization of soil types, determining soil processes, ecological evaluation, or issues related to soil quality and health, such as evaluating suitability of soils for urban or agricultural land use. Applications of geochemistry are on-going across the US and are documented herein. This analytical direction of soil survey complements historic efforts of the National Cooperative Soil Survey Program and addresses the increasing need of soil survey users for data that assists in understanding the influence of human activities on soil properties.

  11. Adaptive Multiscale Modeling of Geochemical Impacts on Fracture Evolution

    Science.gov (United States)

    Molins, S.; Trebotich, D.; Steefel, C. I.; Deng, H.

    2016-12-01

    Understanding fracture evolution is essential for many subsurface energy applications, including subsurface storage, shale gas production, fracking, CO2 sequestration, and geothermal energy extraction. Geochemical processes in particular play a significant role in the evolution of fractures through dissolution-driven widening, fines migration, and/or fracture sealing due to precipitation. One obstacle to understanding and exploiting geochemical fracture evolution is that it is a multiscale process. However, current geochemical modeling of fractures cannot capture this multi-scale nature of geochemical and mechanical impacts on fracture evolution, and is limited to either a continuum or pore-scale representation. Conventional continuum-scale models treat fractures as preferential flow paths, with their permeability evolving as a function (often, a cubic law) of the fracture aperture. This approach has the limitation that it oversimplifies flow within the fracture in its omission of pore scale effects while also assuming well-mixed conditions. More recently, pore-scale models along with advanced characterization techniques have allowed for accurate simulations of flow and reactive transport within the pore space (Molins et al., 2014, 2015). However, these models, even with high performance computing, are currently limited in their ability to treat tractable domain sizes (Steefel et al., 2013). Thus, there is a critical need to develop an adaptive modeling capability that can account for separate properties and processes, emergent and otherwise, in the fracture and the rock matrix at different spatial scales. Here we present an adaptive modeling capability that treats geochemical impacts on fracture evolution within a single multiscale framework. Model development makes use of the high performance simulation capability, Chombo-Crunch, leveraged by high resolution characterization and experiments. The modeling framework is based on the adaptive capability in Chombo

  12. The Conterminous United States Mineral Assessment Program; background information to accompany folio of geologic, geochemical, remote sensing, and mineral resources maps of the Butte 1 degree x 2 degrees Quadrangle, Montana

    Science.gov (United States)

    Elliott, James E.; Trautwein, C.M.; Wallace, C.A.; Lee, G.K.; Rowan, L.C.; Hanna, W.F.

    1993-01-01

    The Butte 1?x2 ? quadrangle in west-central Montana was investigated as part of the U.S. Geological Survey's Conterminous United States Mineral Assessment Program (CUSMAP). These investigations included geologic mapping, geochemical surveys, gravity and aeromagnetic surveys, examinations of mineral deposits, and specialized geochronologic and remote-sensing studies. The data collected during these studies were compiled, combined with available published and unpublished data, analyzed, and used in a mineral-resource assessment of the quadrangle. The results, including data, interpretations, and mineral-resource assessments for nine types of mineral deposits, are published separately as a folio of maps. These maps are accompanied by figures, tables, and explanatory text. This circular provides background information on the Butte quadrangle, summarizes the studies and published maps, and lists a selected bibliography of references pertinent to the geology, geochemistry, geophysics, and mineral resources of the quadrangle. The Butte quadrangle, which includes the world-famous Butte mining district, has a long history of mineral production. Many mining districts within the quadrangle have produced large quantities of many commodities; the most important in dollar value of production were copper, gold, silver, lead, zinc, manganese, molybdenum, and phosphate. At present, mines at several locations produce copper, molybdenum, gold, silver, lead, zinc, and phosphate. Exploration, mainly for gold, has indicated the presence of other mineral deposits that may be exploited in the future. The results of the investigations by the U.S. Geological Survey indicate that many areas of the quadrangle are highly favorable for the occurrence of additional undiscovered resources of gold, silver, copper, molybdenum, tungsten, and other metals in several deposit types.

  13. Quality assurance and quality control of geochemical data—A primer for the research scientist

    Science.gov (United States)

    Geboy, Nicholas J.; Engle, Mark A.

    2011-01-01

    Geochemistry is a constantly expanding science. More and more, scientists are employing geochemical tools to help answer questions about the Earth and earth system processes. Scientists may assume that the responsibility of examining and assessing the quality of the geochemical data they generate is not theirs but rather that of the analytical laboratories to which their samples have been submitted. This assumption may be partially based on knowledge about internal and external quality assurance and quality control (QA/QC) programs in which analytical laboratories typically participate. Or there may be a perceived lack of time or resources to adequately examine data quality. Regardless of the reason, the lack of QA/QC protocols can lead to the generation and publication of erroneous data. Because the interpretations drawn from the data are primary products to U.S. Geological Survey (USGS) stakeholders, the consequences of publishing erroneous results can be significant. The principal investigator of a scientific study ultimately is responsible for the quality and interpretation of the project's findings, and thus must also play a role in the understanding, implementation, and presentation of QA/QC information about the data. Although occasionally ignored, QA/QC protocols apply not only to procedures in the laboratory but also in the initial planning of a research study and throughout the life of the project. Many of the tenets of developing a sound QA/QC program or protocols also parallel the core concepts of developing a good study: What is the main objective of the study? Will the methods selected provide data of enough resolution to answer the hypothesis? How should samples be collected? Are there known or unknown artifacts or contamination sources in the sampling and analysis methods? Assessing data quality requires communication between the scientists responsible for designing the study and those collecting samples, analyzing samples, treating data, and

  14. The Geologic and Geochemical Setting of Lago Fagnano, Tierra del Fuego, Argentina

    Science.gov (United States)

    Tingle, D.; Odle, K.; Knettel, P.; Redding, S.; Perry, E.; Ellins, K.; Ormiston, C.; Dovzak, N.; Anderson, S.

    2005-12-01

    Lago Fagnano, Tierra del Fuego, Argentina is the largest and southernmost ice-free lake on Earth. The isolated lake is unique because the geographic and geologic context provides information relating to the westerly wind patterns, interaction of multiple water sources (hot springs, glacial meltwater, precipitation, groundwater), and tectonic dynamics along a major transform fault. In March, 2005, four students and three teachers from Boerne High School, south-central Texas joined scientists from the United States, Argentina and Switzerland engaged in a geophysical survey of this lake. Lago Fagnano potentially contains within its sediments an undisturbed record of the geotectonic and global climate variability of past 20,000 years. The science team imaged the lake floor with a boat specially equipped to collect both high resolution data (high frequency), imaging the upper 10-15 meters of the sediment, and long range data (low frequency), penetrating 100 or more meters into the sediment. The group conducted field research of existing tectonic features at the eastern end of Tierra del Fuego, an activity directly tied to the research objectives of the science team. They also collected water and soil samples to assess chemical and isotopic trends in the Lago Fagnano region. The research performed can help to characterize the modern geochemical setting of the lake. Analyses of dissolved oxygen, NH4+, PO42-, pH (water) and N, P, and pH (soils) demonstrate a link between low nutrient levels and low biodiversity (which was confirmed by observation) in Tierra del Fuego. Water and soil data are incorporated into a database to facilitate comparisons to North American samples collected and analyzed during the Boerne High School summer field courses. Twenty-three ^18O and ^D analyses yielded a south-north isotopic trend across the Lago Fagnano region. ^18O and ^D transition from -11.92 to -3.53% and -87.81 to -40.26%, respectively, moving south to the Beagle Channel. These

  15. Hydrogeologic and geochemical characteristics of the Ogallala and White River aquifers, Cheyenne, Wyoming

    Science.gov (United States)

    Ogle, K.M.; Hallberg, L.L.

    2000-01-01

    The Ogallala aquifer and the underlying White River aquifer are important ground-water resources of public and private drinking water in the Cheyenne, Wyoming area. In 1997, as part of a cooperative project between the Cheyenne Board of Public Utilities and the U.S. Geological Survey, a well was installed to develop information for those two aquifers. Information provided for the Ogallala aquifer included core descriptions, geophysical logs, water levels, aquifer transmissivity, water quality, isotopic analysis, and geochemical modeling. Information for the White River aquifer was limited to core descriptions and geophysical logs.Evaluation of the core obtained from the drill hole showed the sediments to be primarily sands, silts, and clays. The thickness of the Ogallala Formation at the well site was estimated to be 246 feet. Water levels and precipitation from October 1, 1998 to September 30, 1999 indicated that water levels responded to precipitation. During that time, water levels ranged from 6,002.41 feet to 6,004.27 feet above mean sea level. The transmissivity was estimated to be 1.1 feet squared/day. The temperature differences between the municipal water and the Ogallala aquifer water were examined in relation to selected hydraulic conductivities and it was found that the warmer municipal water would slightly increase the hydraulic conductivity if the water were injected into the Ogallala aquifer.The water quality of a sample from the Ogallala 1 well indicated the predominant major ions were calcium, magnesium, and bicarbonate. Isotopic analyses of hydrogen-2, tritium, chlorine-36, carbon-14, and carbon-13 indicated the water was a mixture of pre- and post-1953 recharge. A simple geochemical mixing model indicated there was the potential for dissolution of anhydrite, calcite, gypsum, and dolomite and precipitation of goethite, hematite, pyrolusite, and amorphous ferric hydroxide if municipal and Ogallala aquifer waters were mixed.

  16. Snowmelt Induced Hydrologic Perturbations Drive Dynamic Microbiological and Geochemical Behaviors across a Shallow Riparian Aquifer

    Energy Technology Data Exchange (ETDEWEB)

    Danczak, Robert E.; Yabusaki, Steven B.; Williams, Kenneth H.; Fang, Yilin; Hobson, Chad; Wilkins, Michael J.

    2016-05-11

    Shallow riparian aquifers represent hotspots of biogeochemical activity in the arid western US. While these environments provide extensive ecosystem services, little is known of how natural environmental perturbations influence subsurface microbial communities and associated biogeochemical processes. Over a six-month period we tracked the annual snowmelt-driven incursion of groundwater into the vadose zone of an aquifer adjacent to the Colorado River, leading to increased dissolved oxygen (DO) concentrations in the normally suboxic saturated zone. Strong biogeochemical heterogeneity was measured across the site, with abiotic reactions between DO and sulfide minerals driving rapid DO consumption and mobilization of redox active species in reduced aquifer regions. Conversely, extensive DO increases were detected in less reduced sediments. 16S rRNA gene surveys tracked microbial community composition within the aquifer, revealing strong correlations between increases in putative oxygen-utilizing chemolithoautotrophs and heterotrophs and rising DO concentrations. The gradual return to suboxic aquifer conditions favored increasing abundances of 16S rRNA sequences matching members of the Microgenomates (OP11) and Parcubacteria (OD1) that have been strongly implicated in fermentative processes. Microbial community stability measurements indicated that deeper aquifer locations were relatively less affected by geochemical perturbations, while communities in shallower locations exhibited the greatest change. Reactive transport modeling of the geochemical and microbiological results supported field observations, suggesting that a predictive framework can be applied to develop a greater understanding of such environments. Frontiers in Earth Science Journal Impact & Description - ResearchGate - Impact Rankings ( 2015 and 2016 ). Available from: https://www.researchgate.net/journal/2296-6463_Frontiers_in_Earth_Science [accessed Jul 25, 2016].

  17. Geochemical baseline for chemical elements in top- and subsoil of Idrija

    Directory of Open Access Journals (Sweden)

    Špela Bavec

    2017-12-01

    Full Text Available This study is a continuation of our previous study (Bavec et al., 2015, where the geochemical baseline levels of potentially harmful elements (As, Cd, Co, Cr, Cu, Hg, Mo, Ni, Pb and Zn in Idrija top- and subsoil (0-10 cm and 10-20 cm at 45 locations were reported. Here we summarise our previous work and present baseline levels of additional 33 elements (Ag, Al, Ba, Be, Bi, Ca, Ce, Cs, Fe, Ga, Hf, In, K, La, Li, Mg, Mn, Nb, P, Rb, S, Sb, Sc, Se, Sn, Sr, Th, Ti, Tl, U, V, Y and Zr in order to round off the fist systematic geochemical survey of soil in Idrija town and establish a data set of soil elements, which will serve as a baseline for monitoring future changes in the soil chemical composition of the studied area. The baseline levels were determined after aqua regia digestion, their statistical distribution was examined and the medians were compared to the recently established European grazing land and Maribor urban soil medians. To investigate relationships between elements, a correlation-matrix-based hierarchical clustering method was performed and the spatial distribution of their highest levels was examined. The results showed that in general, the median levels of elements in Idrija soil are mostly similar or slightly higher than in European and Maribor soil, with exception of Hg. Elements Al, Bi, Ca, Ce, Co, Cr, Cs, Fe, Ga, Hf, La, Li, Mg, Mn, Nb, Ni, Rb, S, Sc, Th, Ti, Tl, V, Y and Zr are enriched in the rural surroundings, while elements Ag, Ba, Cu, Hg, P, Pb, Se, Sb, Sn and Zn are enriched only partly in the rural surroundings, but mostly in the urban part of the study area. It is assumed that elements, which are enriched only in the rural surroundings, are of natural origin, while elements, which are enriched also in the urban area, are to a certain extent inflenced by anthropogenic activities.

  18. Geochemical modelling of bentonite porewater in high-level waste repositories

    Science.gov (United States)

    Wersin, Paul

    2003-03-01

    The description of the geochemical properties of the bentonite backfill that serves as engineered barrier for nuclear repositories is a central issue for perfomance assessment since these play a large role in determining the fate of contaminants released from the waste. In this study the porewater chemistry of bentonite was assessed with a thermodynamic modelling approach that includes ion exchange, surface complexation and mineral equilibrium reactions. The focus was to identify the geochemical reactions controlling the major ion chemistry and acid-base properties and to explore parameter uncertainties specifically at high compaction degrees. First, the adequacy of the approach was tested with two distinct surface complexation models by describing recent experimental data performed at highly varying solid/liquid ratios and ionic strengths. The results indicate adequate prediction of the entire experimental data set. Second, the modelling was extended to repository conditions, taking as an example the current Swiss concept for high-level waste where the compacted bentonite backfill is surrounded by argillaceous rock. The main reactions controlling major ion chemistry were found to be calcite equilibrium and concurrent Na-Ca exchange reactions and de-protonation of functional surface groups. Third, a sensitivity analysis of the main model parameters was performed. The results thereof indicate a remarkable robustness of the model with regard to parameter uncertainties. The bentonite system is characterised by a large acid-base buffering capacity which leads to stable pH-conditions. The uncertainty in pH was found to be mainly induced by the pCO 2 of the surrounding host rock. The results of a simple diffusion-reaction model indicate only minor changes of porewater composition with time, which is primarily due to the geochemical similarities of the bentonite and the argillaceous host rock. Overall, the results show the usefulness of simple thermodynamic models to

  19. The Origin Billions Star Survey: Galactic Explorer

    Science.gov (United States)

    2006-10-18

    using OBSS. 3.2. The Milky Way, Galactic Structure, Local Group, Local Supercluster, Dark Matter, and Cosmology 3.2.1. The Local Velocity Field of the... gravitationally bound clusters. OB associations contain the most massive stars in the local part of the Galaxy and are therefore of paramount importance for the...since most of the stars with life-bearing planets may have been formed in gravitationally unbound as- sociations. It is possible that massive star

  20. Deep Water Survey Data

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The deep water biodiversity surveys explore and describe the biodiversity of the bathy- and bentho-pelagic nekton using Midwater and bottom trawls centered in the...

  1. Characterization of geochemical alteration halo associated with gold mineralization at the Buzwagi mine, northern Tanzania

    Science.gov (United States)

    Manya, Shukrani

    2017-05-01

    Alteration halo geochemical study was carried out along one transect at the Buzwagi mine which is found in the Neoarchaean Nzega greenstone belt of northern Tanzania. The Buzwagi mine Au mineralization is hosted in quartz veins that are cross-cutting strongly sheared and hydrothermally altered K-granites. Mineralogical studies within the shear zone reveal that sericite, silica and sulphides are the most important hydrothermal mineral assemblages responsible for Au mineralization at the Buzwagi mine. The geochemical alteration halo is characterized by the addition of Au, Cu, Fe, K, Rb, Sn, W and U to wall rocks and simultaneous removal of Na, Sr, Ba, LREE and MREE from the host rocks. The concentrations of Cu (130-870 ppm) which show strong positive correlation with Au (R2 = 0.99) are so high in the alteration halo indicating that Cu is a strong Au pathfinder at the Buzwagi mine. Owing to their immobility during the post-emplacement processes, the HFSE (Zr, Hf, Th, Ta) remained unchanged during the hydrothermal alteration process. The addition of Fe and Cu is attributed to the presence of Fe- and Cu-sulphides (pyrite, chalcopyrite and chalcocite) whereas the addition of K, Rb, Sn, W and U is a function of both primary concentrations of these elements in the host rocks as well as the subsequent strong hydrothermal alteration evidenced by sericitization and silicification which involved the destruction of feldspars into sericites). The destruction of albite and its replacement by sericite accounts for the depletion of Na, Sr (and Ba). The Buzwagi mine Au mineralization mineral association do not include the more known pathfinders like Ag, As, Sb, Bi, Te and Tl and they seem not to have played a role in the mineralization process. These elements, therefore, should not be considered as pathfinders for Au exploration purposes at a Buzwagi-like deposit.

  2. Variable Quaternary chemical weathering fluxes and imbalances in marine geochemical budgets.

    Science.gov (United States)

    Vance, Derek; Teagle, Damon A H; Foster, Gavin L

    2009-03-26

    Rivers are the dominant source of many elements and isotopes to the ocean. But this input from the continents is not balanced by the loss of the elements and isotopes through hydrothermal and sedimentary exchange with the oceanic crust, or by temporal changes in the marine inventory for elements that are demonstrably not in steady state. To resolve the problem of the observed imbalance in marine geochemical budgets, attention has been focused on uncertainties in the hydrothermal and sedimentary fluxes. In recent Earth history, temporally dynamic chemical weathering fluxes from the continents are an inevitable consequence of periodic glaciations. Chemical weathering rates on modern Earth are likely to remain far from equilibrium owing to the physical production of finely ground material at glacial terminations that acts as a fertile substrate for chemical weathering. Here we explore the implications of temporal changes in the riverine chemical weathering flux for oceanic geochemical budgets. We contend that the riverine flux obtained from observations of modern rivers is broadly accurate, but not representative of timescales appropriate for elements with oceanic residence longer than Quaternary glacial-interglacial cycles. We suggest that the pulse of rapid chemical weathering initiated at the last deglaciation has not yet decayed away and that weathering rates remain about two to three times the average for an entire late Quaternary glacial cycle. Taking into account the effect of the suggested non-steady-state process on the silicate weathering flux helps to reconcile the modelled marine strontium isotope budget with available data. Overall, we conclude that consideration of the temporal variability in riverine fluxes largely ameliorates long-standing problems with chemical and isotopic mass balances in the ocean.

  3. Application of fractal-wavelet analysis for separation of geochemical anomalies

    Science.gov (United States)

    Afzal, Peyman; Ahmadi, Kamyar; Rahbar, Kambiz

    2017-04-01

    The purpose of this paper is separation and detection of different geochemical populations and anomalies from background utilizing fractal-wavelet analysis. Daubechies2 and Morlet wavelets were used for transformation of the Cu estimated data to spatial frequency based on lithogeochemical data in Bardaskan area (SE Iran) by a MATLAB code. Wavelet is a significant tool for transformation of exploratory data because the noise data are removed from results and also, accuracy for determination of thresholds can be higher than other conventional methods. The Cu threshold values for extremely, highly and moderately anomalies are 1.4%, 0.66% and 0.4%, respectively, according to the fractal-wavelet analysis based on the Daubichies2 transformation. Moreover, the fractal-wavelet analysis by the Morlet wavelet shows that the Cu threshold values are 2%, 0.75% and 0.46% for extremely, highly and moderately anomalies and populations, respectively. The results obtained by the both WT methods indicate that the main Cu enriched anomalies and populations were situated in the central parts of the Bardaskan district which are associated with surface mineralization and ancient mining digs. Furthermore, results derived via the Morlet WT is better than Daubichies2 WT according to the correlation with geological characteristics by logratio matrix. The results obtained by the fractal-wavelet method have a good correlation with geological particulars including alteration zones and surface Cu mineralization which reveals the proposed technique is an applicable approach for identification of various geochemical anomalies and zones from background. However, the main targets for detailed exploration is located in the central part of the studied area.

  4. Stream-sediment and panned-concentrate geochemical maps of the Buffalo Peaks Wilderness Study Area, Lake, Park, and Chaffee counties, Colorado

    Science.gov (United States)

    Nowlan, G.A.; Gerstel, W.J.

    1985-01-01

    Under provisions of the Wilderness Act (Public Law 88-577, September 3, 1964), the U.S. Geological Survey and the U.S. Bureau of Mines have been conducting mineral surveys of areas selected for possible inclusion in the National Wilderness Preservation System. This report presents results of geochemical studies carried out in June and July, 1982, as part of the investigation of the Buffalo Peaks Wilderness Study Area, Colo. Stream-sediment and panned-concentrate samples were collected from about 80 sites on streams draining the study area. Analytical results and a sample locality map were published by Domenico and others (1984).

  5. Hydrothermal system of the Papandayan Volcano from temperature, self-potential (SP) and geochemical measurements

    Science.gov (United States)

    Byrdina, Svetlana; Revil, André; Gunawan, Hendra; Saing, Ugan B.; Grandis, Hendra

    2017-07-01

    Papandayan volcano in West Java, Indonesia, is characterized by intense hydrothermal activities manifested by numerous fumaroles at three craters or kawah, i.e. Mas, Manuk and Baru. The latter was created after November 2002 phreatic eruption. Since 2011, numerous volcano-tectonic B events are encountered and the volcano was set on alert status on several occasions. The purpose of the present study is to delineate the structure of the summital hydrothermal system from Self-Potential (SP), soil temperature and gas concentrations in the soil (CO2, SO2 and H2S) data. This combination of geophysical and geochemical methods allows identification of the weak permeable zones serving as preferential pathways for hydrothermal circulation and potential candidates to future landslides or flank collapses. This study is an on-going collaborative research project and we plan to conduct electrical resistivity tomography (ERT) and also Induced-Polarization (IP) surveys. Additional data would allow the 3D imaging of the studied area. The IP parameters will be used to characterise and to quantify the degree of alteration of the volcanic rocks as has been shown very recently in the laboratory studies. There are also rocks and soil samples that will undergo laboratory analyses at ISTerre for IP and complex resistivity parameters at the sample scale that will help to interpret the survey results.

  6. Petrological and Geochemical Features of the Neogene Volcanites of the Osogovo Mountains, Eastern Macedonia

    OpenAIRE

    Serafimovski, Todor; Tasev, Goran; DOLENEC, TADEJ

    2006-01-01

    The subject of the presented study was the petrological and geochemical characterization of the Neogene volcanic rocks from the Osogovo Mountains. In this paper we present new results of petrological and geochemical analyses of igneous rocks, mostly from Sasa, Toranica and Ruen. The mineralogical and geochemical characteristics of the studied rocks confirmed the results of some previous investigations that indicated that the exposed lithologies are mostly dacites, quartzlatites, trachyandesit...

  7. A carbonate-silicate aqueous geochemical cycle model for Mars

    Science.gov (United States)

    Schaefer, M. W.; Leidecker, H.

    1992-01-01

    A model for the carbonate-silicate geochemical cycle of an early, wet Mars is under development. The results of this study will be used to constrain models of the geochemical history of Mars and the likely mineralogy of its present surface. Although Mars today is a cold, dry planet, it may once have been much warmer and wetter. Values of total outgassed CO2 from several to about 10 bars are consistent with present knowledge (Pollack et al. 1987), and this amount of CO2 implies an amount of water outgassed at least equal to an equivalent depth of 500-1000 meters (Carr 1986). Pollack et al. (1987), in addition, estimate that a thick CO2 atmosphere may have existed for an extended period of time, perhaps as long as a billion years. The greenhouse effect of such an atmosphere would permit the presence of liquid water on the surface, most likely in the form of a shallow sea in the lowest regions of the planet, such as the northern plains (Schaefer 1990). The treatment of geochemical cycles as complex kinetic chemical reactions has been undertaken for terrestrial systems in recent years with much success (Lasaga 1980, 1981; Berner et al. 1983; Lasaga et al. 1985). Although the Martian system is vastly less well understood, and hence less well-constrained, it is also a much simpler system, due to the lack of biogenic reactions that make the terrestrial system so complex. It should be possible, therefore, to use the same techniques to model the Martian system as have been used for terrestrial systems, and to produce useful results. A diagram of the carbonate-silicate cycle for Mars (simplified from the terrestrial system) is given.

  8. A Low-Li Geochemical Province in the NE Atlantic

    DEFF Research Database (Denmark)

    Bailey, J. C.; Gwozdz, R.

    1978-01-01

    Lithium was analysed in 392 basalts and related igneous rocks from the North Atlantic Tertiary-Recent province using activation analysis and Čerenkov counting. Monotonous Li values of 5.5±2 ppm in NE Atlantic basalts define a low-Li geochemical province which has persisted for 60 million years...... basalt series. No whole-rock coherence is observed between Li and Mg, K, Rb or Ca. Mantle phlogopite is considered to play an insignificant rôle in controlling the Li levels of NE Atlantic basalts....

  9. This year`s model: Geochemical modeling and groundwater quality

    Energy Technology Data Exchange (ETDEWEB)

    Tuchfeld, H.A.; Simmons, S.P.; Jesionek, K.S. [GeoSyntec Consultants, Walnut Creek, CA (United States)]|[GeoSyntec Consultants, Atlanta, GA (United States); Romito, A.A. [Browning-Ferris Industries, Inc., Houston, TX (United States)

    1998-07-01

    It has been determined that landfill gas migration is a source of volatile organic compounds (VOCs) in groundwater. This can occur through: direct partitioning of migrating gas constituents into the groundwater; alteration of the physiochemical properties of the groundwater; and by indirect means (such as migration of landfill gas condensate and vadose zone water contaminated by landfill gas). This article examines the use of geochemical modeling as a useful tool for differentiating the effects of municipal solid waste (MSW) landfill gas versus leachate on groundwater quality at MSW landfill sites.

  10. Review of geochemical measurement techniques for a nuclear waste repository in bedded salt

    Energy Technology Data Exchange (ETDEWEB)

    Knauss, K.G.; Steinborn, T.L.

    1980-05-22

    A broad, general review is presented of geochemical measurement techniques that can provide data necessary for site selection and repository effectiveness assessment for a radioactive waste repository in bedded salt. The available measurement techniques are organized according to the parameter measured. The list of geochemical parameters include all those measurable geochemical properties of a sample whole values determine the geochemical characteristics or behavior of the system. For each technique, remarks are made pertaining to the operating principles of the measurement instrument and the purpose for which the technique is used. Attention is drawn to areas where further research and development are needed.

  11. Spatial and Geochemical Spatial and Geochemical Heterogeneity Impacts on Iron Biomineralization and Uranium Sequestration

    Energy Technology Data Exchange (ETDEWEB)

    Scott Fendorf; Shawn Benner; Jim Neiss; Colleen Hansel; Peter Nico; Chris Francis; Phil Jardine

    2004-03-17

    Bioreductive transformations of iron (hydr)oxides are a critically important processes controlling the fate and transport of contaminants in soil and aquifer systems. Heterogeneity arising from both chemical and physical conditions will lead to various biomineralization products of iron oxides and will additionally alter reactions controlling the partitioning of hazardous elements such as uranium. We are presently exploring chemical and mineralogical transformations within physically complex material having a range of pore-size distribution and chemical environments. Here we discuss the impact of calcium on the reactive transport of uranium and the spatial heterogeneity in iron hydroxide mineralization and concomitant uranium reduction along a diffusive flow path.

  12. Geochemical Atlas of the San Jose and Golfito quadrangles, Costa Rica. Atlas Geoquimico de los cuadrangulos de San Jose y Golfito, Costa Rica

    Energy Technology Data Exchange (ETDEWEB)

    1987-07-01

    The Geochemical Atlas of the San Jose and Golfito 1:200,000-scale quadrangles, Costa Rica, was produced to help stimulate the growth of the Costa Rican mining industry and, thus, to benefit the economy of the country. As a result of the geochemical data presented in the Atlas, future exploration for metallic minerals in Costa Rica can be focused on specific areas that have the highest potential for mineralization. Stream-sediment samples were collected from drainage basins within the two quadrangles. These samples were analyzed for 50 elements and the results were displayed as computer-generated color maps. Each map shows the variation in abundance of a single element within the quadrangle. Basic statistics, geological and cultural data are included as insets in each map to assist in interpretation. In the Golfito quadrangle, the geochemical data do not clearly indicate undiscovered gold mineralization. The areas known to contain placer (alluvial) gold are heavily affected by mining activity. Statistical treatment of the geochemical data is necessary before it will be possible to determine the gold potential of this quadrangle. In San Jose quadrangle, gold and the pathfinder elements, arsenic and antimony, are indicators of the gold mineralization characteristic of the Costa Rican gold district located in the Tilaran-Montes del Aguacate Range. This work shows that high concentrations of these elements occur in samples collected downstream from active gold mines. More importantly, the high concentrations of gold, arsenic, and antimony in sediment samples from an area southeast of the known gold district suggest a previously unknown extension of the district. This postulated extension underlain by Tertiary volcanic rocks which host the gold deposits within the gold district. The geochemical data, displayed herein, also indicate that drainage basins north of Ciudad Quesada on the flanks of Volcan Platanar have high gold potential.

  13. Space exploration

    National Research Council Canada - National Science Library

    Chris Moore

    2012-01-01

      Here, Moore presents a year in review on space exploration programs. This 2012 NASA's strategy of stimulating the development of commercial capabilities to launch crew and cargo to the ISS began to pay off...

  14. Three New Cool Brown Dwarfs Discovered with the Wide-field Infrared Survey Explorer (WISE) and an Improved Spectrum of the Y0 Dwarf WISE J041022.71+150248.4

    Science.gov (United States)

    Cushing, Michael C.; Kirkpatrick, J. Davy; Gelino, Christopher R.; Mace, Gregory N.; Skrutskie, Michael F.; Gould, Andrew

    2014-05-01

    As part of a larger search of Wide-field Infrared Survey Explorer (WISE) data for cool brown dwarfs with effective temperatures less than 1000 K, we present the discovery of three new cool brown dwarfs with spectral types later than T7. Using low-resolution, near-infrared spectra obtained with the NASA Infrared Telescope Facility and the Hubble Space Telescope, we derive spectral types of T9.5 for WISE J094305.98+360723.5, T8 for WISE J200050.19+362950.1, and Y0: for WISE J220905.73+271143.9. The identification of WISE J220905.73+271143.9 as a Y dwarf brings the total number of spectroscopically confirmed Y dwarfs to 17. In addition, we present an improved spectrum (i.e., higher signal-to-noise ratio) of the Y0 dwarf WISE J041022.71+150248.4 that confirms the Cushing et al. classification of Y0. Spectrophotometric distance estimates place all three new brown dwarfs at distances less than 12 pc, with WISE J200050.19+362950.1 lying at a distance of only 3.9-8.0 pc. Finally, we note that brown dwarfs like WISE J200050.19+362950.1 that lie in or near the Galactic plane offer an exciting opportunity to directly measure the mass of a brown dwarf via astrometric microlensing.

  15. Three new cool brown dwarfs discovered with the wide-field infrared survey explorer (WISE) and an improved spectrum of the Y0 dwarf wise J041022.71+150248.4

    Energy Technology Data Exchange (ETDEWEB)

    Cushing, Michael C. [Department of Physics and Astronomy, The University of Toledo, 2801 West Bancroft Street, Toledo, OH 43606 (United States); Kirkpatrick, J. Davy; Gelino, Christopher R. [Infrared Processing and Analysis Center, California Institute of Technology, Pasadena, CA 91125 (United States); Mace, Gregory N. [Department of Physics and Astronomy, UCLA, Los Angeles, CA 90095 (United States); Skrutskie, Michael F. [Department of Astronomy, University of Virginia, Charlottesville, VA 22904 (United States); Gould, Andrew, E-mail: michael.cushing@utoledo.edu [Department of Astronomy, Ohio State University, 140 West 18th Avenue, Columbus, OH 43210 (United States)

    2014-05-01

    As part of a larger search of Wide-field Infrared Survey Explorer (WISE) data for cool brown dwarfs with effective temperatures less than 1000 K, we present the discovery of three new cool brown dwarfs with spectral types later than T7. Using low-resolution, near-infrared spectra obtained with the NASA Infrared Telescope Facility and the Hubble Space Telescope, we derive spectral types of T9.5 for WISE J094305.98+360723.5, T8 for WISE J200050.19+362950.1, and Y0: for WISE J220905.73+271143.9. The identification of WISE J220905.73+271143.9 as a Y dwarf brings the total number of spectroscopically confirmed Y dwarfs to 17. In addition, we present an improved spectrum (i.e., higher signal-to-noise ratio) of the Y0 dwarf WISE J041022.71+150248.4 that confirms the Cushing et al. classification of Y0. Spectrophotometric distance estimates place all three new brown dwarfs at distances less than 12 pc, with WISE J200050.19+362950.1 lying at a distance of only 3.9-8.0 pc. Finally, we note that brown dwarfs like WISE J200050.19+362950.1 that lie in or near the Galactic plane offer an exciting opportunity to directly measure the mass of a brown dwarf via astrometric microlensing.

  16. Impact of geochemical stressors on shallow groundwater quality

    Science.gov (United States)

    An, Y.-J.; Kampbell, D.H.; Jeong, S.-W.; Jewell, K.P.; Masoner, J.R.

    2005-01-01

    Groundwater monitoring wells (about 70 wells) were extensively installed in 28 sites surrounding Lake Texoma, located on the border of Oklahoma and Texas, to assess the impact of geochemical stressors to shallow groundwater quality. The monitoring wells were classified into three groups (residential area, agricultural area, and oil field area) depending on their land uses. During a 2-year period from 1999 to 2001 the monitoring wells were sampled every 3 months on a seasonal basis. Water quality assay consisted of 25 parameters including field parameters, nutrients, major ions, and trace elements. Occurrence and level of inorganics in groundwater samples were related to the land use and temporal change. Groundwater of the agricultural area showed lower levels of ferrous iron and nitrate than the residential area. The summer season data revealed more distinct differences in inorganic profiles of the two land use groundwater samples. There is a possible trend that nitrate concentrations in groundwater increased as the proportions of cultivated area increased. Water-soluble ferrous iron occurred primarily in water samples with a low dissolved oxygen concentration and/or a negative redox potential. The presence of brine waste in shallow groundwater was detected by chloride and conductivity in oil field area. Dissolved trace metals and volatile organic carbons were not in a form of concentration to be stressors. This study showed that the quality of shallow ground water could be related to regional geochemical stressors surrounding the lake. ?? 2005 Elsevier B.V. All rights reserved.

  17. Multivariate analysis relating oil shale geochemical properties to NMR relaxometry

    Science.gov (United States)

    Birdwell, Justin E.; Washburn, Kathryn E.

    2015-01-01

    Low-field nuclear magnetic resonance (NMR) relaxometry has been used to provide insight into shale composition by separating relaxation responses from the various hydrogen-bearing phases present in shales in a noninvasive way. Previous low-field NMR work using solid-echo methods provided qualitative information on organic constituents associated with raw and pyrolyzed oil shale samples, but uncertainty in the interpretation of longitudinal-transverse (T1–T2) relaxometry correlation results indicated further study was required. Qualitative confirmation of peaks attributed to kerogen in oil shale was achieved by comparing T1–T2 correlation measurements made on oil shale samples to measurements made on kerogen isolated from those shales. Quantitative relationships between T1–T2 correlation data and organic geochemical properties of raw and pyrolyzed oil shales were determined using partial least-squares regression (PLSR). Relaxometry results were also compared to infrared spectra, and the results not only provided further confidence in the organic matter peak interpretations but also confirmed attribution of T1–T2 peaks to clay hydroxyls. In addition, PLSR analysis was applied to correlate relaxometry data to trace element concentrations with good success. The results of this work show that NMR relaxometry measurements using the solid-echo approach produce T1–T2 peak distributions that correlate well with geochemical properties of raw and pyrolyzed oil shales.

  18. Geochemical response to hydrologic change along land-sea interfaces

    Science.gov (United States)

    Michael, H. A.; Yu, X.; LeMonte, J. J.; Sparks, D. L.; Kim, K. H.; Heiss, J.; Ullman, W. J.; Guimond, J. A.; Seyfferth, A.

    2016-12-01

    Coastal groundwater-surface water interfaces are hotspots of geochemical activity, where reactants contributed by different sources come in contact. Reactions that occur along these land-sea boundaries have important effects on fluxes and cycling of carbon, nutrients, and contaminants. Hydrologic perturbations can alter interactions by promoting mixing, changing redox state, and altering subsurface residence times during which reactions may occur. We present examples from field and modeling investigations along the Delaware coastline that illustrate the impacts of hydrologic fluctuations on geochemical conditions and fluxes in different coastal environments. Along the highly populated Wilmington coastline, soils are contaminated with heavy metals from legacy industrial practices. We show with continuous redox monitoring and sampling over tidal to seasonal timescales that arsenic is mobilized and immobilized in response to hydrologic change. Along a beach, modeling and long-term monitoring show the influence of tidal to seasonal changes in the mixing zone between discharging fresh groundwater and seawater in the intertidal beach aquifer and associated impacts on biogeochemical reactivity and denitrification. In a saltmarsh, hydrologic changes alter carbon dynamics, with implications for the discharge of dissolved organic carbon to the ocean and export of carbon dioxide and methane to the atmosphere. Understanding the impacts of hydrologic changes on both long and short timescales is essential for improving our ability to predict the global biogeochemical impacts of a changing climate.

  19. Soil Lysimeter Excavation for Coupled Hydrological, Geochemical, and Microbiological Investigations.

    Science.gov (United States)

    Sengupta, Aditi; Wang, Yadi; Meira Neto, Antonio A; Matos, Katarena A; Dontsova, Katerina; Root, Rob; Neilson, Julie W; Maier, Raina M; Chorover, Jon; Troch, Peter A

    2016-09-11

    Studying co-evolution of hydrological and biogeochemical processes in the subsurface of natural landscapes can enhance the understanding of coupled Earth-system processes. Such knowledge is imperative in improving predictions of hydro-biogeochemical cycles, especially under climate change scenarios. We present an experimental method, designed to capture sub-surface heterogeneity of an initially homogeneous soil system. This method is based on destructive sampling of a soil lysimeter designed to simulate a small-scale hillslope. A weighing lysimeter of one cubic meter capacity was divided into sections (voxels) and was excavated layer-by-layer, with sub samples being collected from each voxel. The excavation procedure was aimed at detecting the incipient heterogeneity of the system by focusing on the spatial assessment of hydrological, geochemical, and microbiological properties of the soil. Representative results of a few physicochemical variables tested show the development of heterogeneity. Additional work to test interactions between hydrological, geochemical, and microbiological signatures is planned to interpret the observed patterns. Our study also demonstrates the possibility of carrying out similar excavations in order to observe and quantify different aspects of soil-development under varying environmental conditions and scale.

  20. Evolution of geochemical conditions in SFL 3-5

    Energy Technology Data Exchange (ETDEWEB)

    Karlsson, Fred [Swedish Nuclear Fuel and Waste Management Co., Stockholm (Sweden); Lindgren, M.; Skagius, K.; Wiborgh, M. [Kemakta Konsult AB, Stockholm (Sweden); Engkvist, I. [Barsebaeck Kraft AB (Sweden)

    1999-12-01

    The evolution of geochemical conditions in the repository for long-lived low- and intermediate-level waste, SFL 3-5, and in the vicinity of the repository are important when predicting the retention of radionuclides and the long-term stability of engineered barriers. In this study the initial conditions at different repository sites at 300 - 400 m depth, the influence of repository construction and operation, the expected conditions after repository closure and saturation, and the evolution in a long-term perspective are discussed. Groundwaters that are found at these depths have near-neutral pH and are reducing in character, but the composition can vary from saline to non-saline water. The water chemistry in the near-field will mainly be influenced by the composition of the groundwater and by the large amounts of cementitious material that can be found in the repository. Disturbances caused during construction and operation are not expected to be permanent. Studies of old concrete indicate that leaching of concrete is a slow process. The geochemical conditions in the repository are therefore expected to be stable and prevail for hundreds of thousand years. However, the evolution of the surrounding environment may influence the conditions in long-term perspective.

  1. Fiscal 1997 report on the survey of verification of geothermal exploration technology, etc. 1. Development of the reservoir variation exploration method (development of the fracture hydraulic exploration method); 1997 nendo chinetsu tansa gijutsu nado kensho chosa. Choryuso hendo tansaho kaihatsu (danretsu suiri tansaho kaihatsu) hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    The paper described the fiscal 1997 result of the fracture hydraulic exploration method as the variation exploration method of geothermal reservoirs. By elucidating hydraulic characteristics of the fracture system forming reservoir, technologies are established which are effective for the reservoir evaluation in early stages of development, maintenance of stable power after operational start-up, and extraction of peripheral reservoirs. As for the pressure transient test method, a test supporting system was basically designed to obtain high accuracy hydraulic parameters. As to the tiltmeter fracture monitoring method, a simulation was made for distribution of active fractures and evaluation of hydraulic constants without drilling wells. In relation to the two-phase flow measuring method, for stable steam production, the use of the orifice plate, the existing flow measuring method, etc. was forecast as a simple measuring method of the two-phase state of reservoir. Concerning the hydrophone VSP method, a feasibility study was made of the practical VSP for high temperature which can analyze hydraulic characteristics and geological structures around the well at the same time which the existing methods were unable to grasp, and brought the results. Moreover, to make high accuracy reservoir modeling possible, Doppler borehole televiewer was made in each reservoir. 80 refs., 147 figs., 22 tabs.

  2. Recent developments in exploration. Pt. 1

    Energy Technology Data Exchange (ETDEWEB)

    Wellmer, F.W.

    1983-01-01

    The development over the years of the specific exploration costs necessary for an ore deposit discovery are examined. It is concluded that the development has been cyclic and it is not appropriate to compare minimum with maximum but only minima or maxima. Contrary to the frequent claim an increase till now of the specific exploration costs per discovery in constant money terms cannot be observed. It is postulated however that in future exploration costs will rise due to the declining resolution of exploration methods with greater depth of exploration and because the favorability does not increase proportionally with a higher depth penetration capability. A statistical model is developed showing that an increase of depth penetration from 100 to 200 m increases relative favorability for steeply dipping ore bodies only by 10 to 20%. Concerning better chances of detecting ore bodies in underdeveloped countries it is concluded that a positive influence on the development of specific exploration costs cannot be expected. In part II of the article it is shown that the reserve balances (reserves/consumption) have been in a dynamic balance till now. The influence of unconventional reserves on the reserve balance is considered. Developments in exploration technology are discussed like improved multielement geochemical and multichannel geophysical methods, evaluation of data of such methods with EDP and using EDP for an optimal exploration area selection. In the future it will be necessary to better define absolute and relative favorability of an exploration area.

  3. Farside explorer

    DEFF Research Database (Denmark)

    Mimoun, David; Wieczorek, Mark A.; Alkalai, Leon

    2012-01-01

    Farside Explorer is a proposed Cosmic Vision medium-size mission to the farside of the Moon consisting of two landers and an instrumented relay satellite. The farside of the Moon is a unique scientific platform in that it is shielded from terrestrial radio-frequency interference, it recorded...... the primary differentiation and evolution of the Moon, it can be continuously monitored from the Earth-Moon L2 Lagrange point, and there is a complete lack of reflected solar illumination from the Earth. Farside Explorer will exploit these properties and make the first radio-astronomy measurements from...... the most radio-quiet region of near-Earth space, determine the internal structure and thermal evolution of the Moon, from crust to core, and quantify impact hazards in near-Earth space by the measurement of flashes generated by impact events. The Farside Explorer flight system includes two identical solar...

  4. Geochemical Distribution of Lead and Chromium in River Getsi-Kano

    African Journals Online (AJOL)

    Geochemical forms of lead (Pb) and Chromium (Cr) from the sediment of River Getsi Kano-Nigeria were determined using Atomic Absorption spectrometer for eighteen months. Apart from determination of the metals in water, geochemical forms of the metals were also evaluated into five fractions. Exchangeable, bound to ...

  5. Geochemical and Isotopic Interpretations of Groundwater Flow in the Oasis Valley Flow System, Southern Nevada

    Energy Technology Data Exchange (ETDEWEB)

    J.M. Thomas; F.C. Benedict, Jr.; T.P. Rose; R.L. Hershey; J.B. Paces; Z.E. Peterman; I.M. Farnham; K.H. Johannesson; A.K. Singh; K.J. Stetzenbach; G.B. Hudson; J.M. Kenneally; G.F. Eaton; D.K. Smith

    2003-01-08

    This report summarizes the findings of a geochemical investigation of the Pahute Mesa-Oasis Valley groundwater flow system in southwestern Nevada. It is intended to provide geochemical data and interpretations in support of flow and contaminant transport modeling for the Western and Central Pahute Mesa Corrective Action Units.

  6. Pilot studies for the North American Soil Geochemical Landscapes Project - Site selection, sampling protocols, analytical methods, and quality control protocols

    Science.gov (United States)

    Smith, D.B.; Woodruff, L.G.; O'Leary, R. M.; Cannon, W.F.; Garrett, R.G.; Kilburn, J.E.; Goldhaber, M.B.

    2009-01-01

    In 2004, the US Geological Survey (USGS) and the Geological Survey of Canada sampled and chemically analyzed soils along two transects across Canada and the USA in preparation for a planned soil geochemical survey of North America. This effort was a pilot study to test and refine sampling protocols, analytical methods, quality control protocols, and field logistics for the continental survey. A total of 220 sample sites were selected at approximately 40-km intervals along the two transects. The ideal sampling protocol at each site called for a sample from a depth of 0-5 cm and a composite of each of the O, A, and C horizons. The analysis, the USGS QC officer, and the principal investigator for the study. This level of review resulted in an average of one QC sample for every 20 field samples, which proved to be minimally adequate for such a large-scale survey. Additional QC samples should be added to monitor within-batch quality to the extent that no more than 10 samples are analyzed between a QC sample. Only Cr (77%), Y (82%), and Sb (80%) fell outside the acceptable limits of accuracy (% recovery between 85 and 115%) because of likely residence in mineral phases resistant to the acid digestion. A separate sample of 0-5-cm material was collected at each site for determination of organic compounds. A subset of 73 of these samples was analyzed for a suite of 19 organochlorine pesticides by gas chromatography. Only three of these samples had detectable pesticide concentrations. A separate sample of A-horizon soil was collected for microbial characterization by phospholipid fatty acid analysis (PLFA), soil enzyme assays, and determination of selected human and agricultural pathogens. Collection, preservation and analysis of samples for both organic compounds and microbial characterization add a great degree of complication to the sampling and preservation protocols and a significant increase to the cost for a continental-scale survey. Both these issues must be

  7. Geochemical and isotopic characteristics of groundwater from Velenje Basin, Slovenia

    Science.gov (United States)

    Kanduč, Tjaša; Grassa, Fausto; Mori, Nataša; Verbovšek, Timotej

    2016-04-01

    The Velenje Basin in Slovenia is one of the largest actively mined coal basins in central Europe, producing around 4 million tons of lignite per year. Large amounts of groundwater are extracted from aquifers to facilitate underground mining of coal, and coal seam gas outbursts are a serious mine safety concern. This study analyses the geochemical and isotopic composition of groundwater to provide a general understanding of hydrogeological and geochemical processes in groundwater. Thirty-eight groundwater samples were taken from dewatering objects in the mine and at the surface in years 2014-2015. Groundwater in the Triassic aquifer is dominated by hydrogen carbonate, calcium, magnesium and isotopic composition of dissolved inorganic carbon in the range from -19.3 to -2.8‰ indicating degradation of soil organic matter and dissolution of carbonate minerals. In contrast, groundwater in the Pliocene aquifers is enriched in magnesium, sodium, calcium, potassium, and silicon, and has high alkalinity, with isotopic composition of dissolved inorganic carbon in the range of -14.4 to +4.6‰ . Based on isotopic composition of dissolved inorganic carbon values in all aquifers (Pliocene and Triassic), influencing processes are the dissolution of carbonate minerals and dissolution of organic matter, and additionally methanogenesis in the Pliocene aquifers. Based on the Principal Component Analysis (PCA) we can conclude that following different types of groundwater in Velenje Basin could be distinguished based on geochemical and isotopic data: Triassic aquifers with higher pH and lower conductivity and chloride, Pliocene, Pliocene 1 and Pliocene 2 aquifers with lower pH and higher conductivity and chloride contents, and Pliocene 3 and Pliocene 2, 3 aquifers with the highest pH and lowest conductivity and chloride contents. Major dissolved gas component in groundwater are carbon dioxide, nitrogen and methane. Concentrations of dissolved gases dewatering Triassic strata are low

  8. Geochemical survey of underground water pollution at Ditengteng northern cemetery within City of Tshwane municipality

    OpenAIRE

    2009-01-01

    M.Sc. In a country such as South Africa, there is a rich diversity of cultural, social, traditional and religious practices. The issue of death takes on a similar diversity, as such responding to death through a burial practice differs to varying degrees with regard to burial containment, burial material and burial procedure. The last few decades have seen an increasing recognition of the impact of human activity on the environment and the critical need to transform our approach on how we ...

  9. Genome data mining and soil survey for the novel group 5 [NiFe]-hydrogenase to explore the diversity and ecological importance of presumptive high-affinity H(2)-oxidizing bacteria.

    Science.gov (United States)

    Constant, Philippe; Chowdhury, Soumitra Paul; Hesse, Laura; Pratscher, Jennifer; Conrad, Ralf

    2011-09-01

    Streptomyces soil isolates exhibiting the unique ability to oxidize atmospheric H(2) possess genes specifying a putative high-affinity [NiFe]-hydrogenase. This study was undertaken to explore the taxonomic diversity and the ecological importance of this novel functional group. We propose to designate the genes encoding the small and large subunits of the putative high-affinity hydrogenase hhyS and hhyL, respectively. Genome data mining revealed that the hhyL gene is unevenly distributed in the phyla Actinobacteria, Proteobacteria, Chloroflexi, and Acidobacteria. The hhyL gene sequences comprised a phylogenetically distinct group, namely, the group 5 [NiFe]-hydrogenase genes. The presumptive high-affinity H(2)-oxidizing bacteria constituting group 5 were shown to possess a hydrogenase gene cluster, including the genes encoding auxiliary and structural components of the enzyme and four additional open reading frames (ORFs) of unknown function. A soil survey confirmed that both high-affinity H(2) oxidation activity and the hhyL gene are ubiquitous. A quantitative PCR assay revealed that soil contained 10(6) to 10(8) hhyL gene copies g (dry weight)(-1). Assuming one hhyL gene copy per genome, the abundance of presumptive high-affinity H(2)-oxidizing bacteria was higher than the maximal population size for which maintenance energy requirements would be fully supplied through the H(2) oxidation activity measured in soil. Our data indicate that the abundance of the hhyL gene should not be taken as a reliable proxy for the uptake of atmospheric H(2) by soil, because high-affinity H(2) oxidation is a facultatively mixotrophic metabolism, and microorganisms harboring a nonfunctional group 5 [NiFe]-hydrogenase may occur.

  10. Exploration of knowledge of, adherence to, attitude and barriers toward evidence-based guidelines (EBGs for prevention of ventilator-associated pneumonia (VAP in healthcare workers of pediatric cardiac intensive care units (PCICUs: A Quali-Quantitative survey

    Directory of Open Access Journals (Sweden)

    Leila Jahansefat

    2016-09-01

    Full Text Available Implementation of evidence-based guidelines (EBGs is an effective measure for prevention of ventilator-associated pneumonia (VAP. Appropriate knowledge, attitude and adherence of healthcare workers (HCWs to EBGs are necessary factors for implementation of EBGs. This study was conducted with objective of evaluation of knowledge, attitude, and adherence of HCWs to EBGs for prevention of VAP and exploration of the barriers of their implementation in clinical practice. Totally, a total number of 45 HCWs of two pediatric cardiac surgery ICU (PCICUs participated in this quali-quantitative survey. Knowledge, attitude and adherence of participants was evaluated by a validated multiple-choice questionnaire and barriers of implementation of EBGs was extracted from participants’ answer to an open-ended question of our self-made questionnaire. Knowledge of HCWs was poor and significantly different between nurse assistants (RAs, nurses (RNs, and physicians (MDs (respectively, 1.25±0.95, 4.53±1.73, and 5.54±2.01, P=0.001. Likewise, attit ude of HCWs is not positive and significantly different between NAs, RNs, and MDs (respectively, 32.96±2.42, 34.00±2.44, 36.81±4.35, P=0.003. The adherence of HCWs is not good and different between RAs, RNs, and MDs (respectively, 11.50±1.00, 13.13±1.83, and 17.18±6.06, P= 0.17. The Barriers of implementation of EBGs was categorized into four category of individual, organizational, social, and educational factors. Unsatisfying status of knowledge, attitude, and adherence of HCWs is a challenging concern of health-care system, especially in PICUs. In addition to these well-known factors, poor implementation of EBGs is related to many other barriers which should recognized and taken into consideration for designation of infection controlling programs.

  11. Examining Volcanic Terrains Using In Situ Geochemical Technologies; Implications for Planetary Field Geology

    Science.gov (United States)

    Young, K. E.; Bleacher, J. E.; Evans, C. A.; Rogers, A. D.; Ito, G.; Arzoumanian, Z.; Gendreau, K.

    2015-01-01

    Regardless of the target destination for the next manned planetary mission, the crew will require technology with which to select samples for return to Earth. The six Apollo lunar surface missions crews had only the tools to enable them to physically pick samples up off the surface or from a boulder and store those samples for return to the Lunar Module and eventually to Earth. Sample characterization was dependent upon visual inspection and relied upon their extensive geology training. In the four decades since Apollo however, great advances have been made in traditionally laboratory-based instrument technologies that enable miniaturization to a field-portable configuration. The implications of these advancements extend past traditional terrestrial field geology and into planetary surface exploration. With tools that will allow for real-time geochemical analysis, an astronaut can better develop a series of working hypotheses that are testable during surface science operations. One such technology is x-ray fluorescence (XRF). Traditionally used in a laboratory configuration, these instruments have now been developed and marketed commercially in a field-portable mode. We examine this technology in the context of geologic sample analysis and discuss current and future plans for instrument deployment. We also discuss the development of the Chromatic Mineral Identification and Surface Texture (CMIST) instrument at the NASA Goddard Space Flight Center (GSFC). Testing is taking place in conjunction with the RIS4E (Remote, In Situ, and Synchrotron Studies for Science and Exploration) SSERVI (Solar System Exploration and Research Virtual Institute) team activities, including field testing at Kilauea Volcano, HI..

  12. The Earth's heterogeneous mantle a geophysical, geodynamical, and geochemical perspective

    CERN Document Server

    Khan, Amir

    2015-01-01

    This book highlights and discusses recent developments that have contributed to an improved understanding of observed mantle heterogeneities and their relation to the thermo-chemical state of Earth's mantle, which ultimately holds the key to unlocking the secrets of the evolution of our planet. This series of topical reviews and original contributions address 4 themes. Theme 1 covers topics in geophysics, including global and regional seismic tomography, electrical conductivity and seismic imaging of mantle discontinuities and heterogeneities in the upper mantle, transition zone and lower mantle. Theme 2 addresses geochemical views of the mantle including lithospheric evolution from analysis of mantle xenoliths, composition of the deep Earth and the effect of water on subduction-zone processes. Theme 3 discusses geodynamical perspectives on the global thermo-chemical structure of the deep mantle. Theme 4 covers application of mineral physics data and phase equilibrium computations to infer the regional-scale ...

  13. Geochemical signatures in Late Triassic brachiopods from New Caledonia

    DEFF Research Database (Denmark)

    Ullmann, C. V.; Campbell, H. J.; Frei, R.

    2014-01-01

    .7065, and light δ13C values of c.-20‰, suggesting major contributions by oxidized organic matter. Diagenetic equilibrium was reached at δ18O values of c.-12‰, very low Sr/Ca ratios of ...Brachiopod fossils from the sedimentary sequences of the Téremba Terrane (New Caledonia) provide a unique opportunity to study the environmental parameters of the Late Triassic. 87Sr/86Sr ratios, δ13C and δ18O values, and Sr/Ca, Mg/Ca and Mn/Ca ratios were measured on brachiopods from Oretian...... to Otapirian (Norian to Rhaetian) fossil localities of the Baie de St.-Vincent area. Post-depositional impacts on the geochemical proxies were investigated by analysing calcite cements and partly recrystallized shell material. Diagenetic fluids carried strontium with a low 87Sr/86Sr ratio of c. 0...

  14. Geochemical characterisation of arsenic in uranium tailings pore fluids

    Energy Technology Data Exchange (ETDEWEB)

    Moldovan, B.; Hendry, M.J. [Univ. of Saskatchewan, Dept. of Geological Sciences, Saskatoon, Saskatchewan (Canada); Landine, P. [Cameco Corp., Saskatoon, Saskatchewan (Canada)

    2000-07-01

    Geochemical characterisation of uranium tailings porewater and solids is required to determine the long-term source contaminant potential of arsenic in the tailings. The Rabbit Lake In-pit Tailings Management Facility in Northern Saskatchewan was investigated with the objective of obtaining representative tailings porewater samples from a detailed depth profile. Methods of extracting porewater, including centrifugation and hydraulic squeezing were compared to drive-point piezometer data. Field measurements of Eh, pH and temperature were taken as the core samples were recovered. Pore fluid samples were analysed for arsenic speciation. Analytical results were compared to the previous sampling event in the same location. Tailings produced from several ore bodies were also compared in terms of pore fluid contaminant concentrations. (author)

  15. Geochemical Proxies for Enhanced Process Control of Underground Coal Gasification

    Science.gov (United States)

    Kronimus, A.; Koenen, M.; David, P.; Veld, H.; van Dijk, A.; van Bergen, F.

    2009-04-01

    Underground coal gasification (UCG) represents a strategy targeting at syngas production for fuel or power generation from in-situ coal seams. It is a promising technique for exploiting coal deposits as an energy source at locations not allowing conventional mining under economic conditions. Although the underlying concept has already been suggested in 1868 and has been later on implemented in a number of field trials and even at a commercial scale, UCG is still facing technological barriers, impeding its widespread application. Field UCG operations rely on injection wells enabling the ignition of the target seam and the supply with oxidants (air, O2) inducing combustion (oxidative conditions). The combustion process delivers the enthalpy required for endothermic hydrogen production under reduction prone conditions in some distance to the injection point. The produced hydrogen - usually accompanied by organic and inorganic carbon species, e.g. CH4, CO, and CO2 - can then be retrieved through a production well. In contrast to gasification of mined coal in furnaces, it is difficult to measure the combustion temperature directly during UCG operations. It is already known that geochemical parameters such as the relative production gas composition as well as its stable isotope signature are related to the combustion temperature and, consequently, can be used as temperature proxies. However, so far the general applicability of such relations has not been proven. In order to get corresponding insights with respect to coals of significantly different rank and origin, four powdered coal samples covering maturities ranging from Ro= 0.43% (lignite) to Ro= 3.39% (anthracite) have been gasified in laboratory experiments. The combustion temperature has been varied between 350 and 900 ˚ C, respectively. During gasification, the generated gas has been captured in a cryo-trap, dried and the carbon containing gas components have been catalytically oxidized to CO2. Thereafter, the

  16. Geochemical behavior of uranium mill tailings leachate in the subsurface

    Energy Technology Data Exchange (ETDEWEB)

    Brookins, D.G. (New Mexico Univ., Albuquerque, NM (United States). Dept. of Geology); Thomson, B.M. (New Mexico Univ., Albuquerque, NM (United States). Dept. of Civil Engineering); Longmire, P.; Eller, P.G. (Los Alamos National Lab., Isotope and Nuclear Chemistry Div., Los Alamos (United States))

    1993-01-01

    Leachate generated from surface disposal of acidic uranium mill tailings at Maybell, CO has impacted groundwater quality within the underlying mineralized Browns Park Formation. The extent of groundwater contamination, however, is located directly beneath the tailings impoundment. The milling process consisted of sulfuric acid extraction of uranium from the feed ore by a complex chemical leaching and precipitation process. Tailings leachate at the site contains elevated concentrations of Al, As, Cd, Mo, Ni, NO[sub 3], Se, U, and other solutes. From column leach tests, the concentrations of contaminants within tailings pore fluid are SO[sub 4]>NH[sub 4]>NO[sub 3]>U>Se>Ni>As>Cd at pH 4.0. The carbonate buffering capacity of the tailings subsoil has decreased because of calcite dissolution in the presence of acidic leachate. Groundwater quality data, mineralogical and microbiological studies, and geochemical modeling suggest that As, NO[sub 3], Se, U and other solutes are being removed from solution through precipitation, adsorption, and denitrification processes under reducing conditions. Presence of hydrogen sulfide, liquid and gaseous hydrocarbons, dissolved organic, and abundant pyrite within the Browns Park Formations have maintained reducing conditions subjacent to the tailings impoundment. Groundwater is in close equilibrium with coffinite and uraninite, the primary U(IV) minerals extracted from the Browns Parks Formation. Denitrifying bacteria identified in this study catalyze redox reactions involving NO[sub 3]. Subsequently, contaminant distributions of NO[sub 3] decrease 1000 times beneath the tailings impoundment. Applying geochemical and biochemical processes occurring at Maybell provides an excellent model for in situ aquifer restoration programs considered at other uranium tailings and heavy-metal-mixed waste contaminated sites. (author) 4 figs., 4 tabs., 27 refs.

  17. Experimental study on neptunium migration under in situ geochemical conditions

    Science.gov (United States)

    Kumata, M.; Vandergraaf, T. T.

    1998-12-01

    Results are reported for migration experiments performed with Np under in situ geochemical conditions over a range of groundwater flow rates in columns of crushed rock in a specially designed facility at the 240-level of the Underground Research Laboratory (URL) near Pinawa, Manitoba, Canada. This laboratory is situated in an intrusive granitic rock formation, the Lac du Bonnet batholith. Highly altered granitic rock and groundwater were obtained from a major subhorizontal fracture zone at a depth of 250 m in the URL. The granite was wet-crushed and wet-sieved with groundwater from this fracture zone. The 180-850-μm size fraction was selected and packed in 20-cm long, 2.54-cm in diameter Teflon™-lined stainless steel columns. Approximately 30-ml vols of groundwater containing 3HHO and 237Np were injected into the columns at flow rates of 0.3, 1, and 3 ml/h, followed by elution with groundwater, obtained from the subhorizontal fracture, at the same flow rates, for a period of 95 days. Elution profiles for 3HHO were obtained, but no 237Np was detected in the eluted groundwater. After terminating the migration experiments, the columns were frozen, the column material was removed and cut into twenty 1-cm thick sections and each section was analyzed by gamma spectrometry. Profiles of 237Np were obtained for the three columns. A one-dimensional transport model was fitted to the 3HHO breakthrough curves to obtain flow parameters for this experiment. These flow parameters were in turn applied to the 237Np concentration profiles in the columns to produce sorption and dispersion coefficients for Np. The results show a strong dependence of retardation factors ( Rf) on flow rate. The decrease in the retarded velocity of the neptunium ( Vn) varied over one order of magnitude under the geochemical conditions for these experiments.

  18. Geophysical and geochemical signatures of Gulf of Mexico seafloor brines

    Directory of Open Access Journals (Sweden)

    S. B. Joye

    2005-01-01

    Full Text Available Geophysical, temperature, and discrete depth-stratified geochemical data illustrate differences between an actively venting mud volcano and a relatively quiescent brine pool in the Gulf of Mexico along the continental slope. Geophysical data, including laser-line scan mosaics and sub-bottom profiles, document the dynamic nature of both environments. Temperature profiles, obtained by lowering a CTD into the brine fluid, show that the venting brine was at least 10°C warmer than the bottom water. At the brine pool, thermal stratification was observed and only small differences in stratification were documented between three sampling times (1991, 1997 and 1998. In contrast, at the mud volcano, substantial temperature variability was observed, with the core brine temperature being slightly higher than bottom water (by 2°C in 1997 but substantially higher than bottom water (by 19°C in 1998. Detailed geochemical samples were obtained in 2002 using a device called the 'brine trapper' and concentrations of dissolved gases, major ions and nutrients were determined. Both brines contained about four times as much salt as seawater and steep concentration gradients of dissolved ions and nutrients versus brine depth were apparent. Differences in the concentrations of calcium, magnesium and potassium between the two brine fluids suggest that the fluids are derived from different sources, have different dilution/mixing histories, or that brine-sediment reactions are more important at the mud volcano. Substantial concentrations of methane, ammonium, and silicate were observed in both brines, suggesting that fluids expelled from deep ocean brines are important sources of these constituents to the surrounding environment.

  19. Arsenic: geochemical distribution and health risk in Italy

    Science.gov (United States)

    Zuzolo, Daniela; Cicchella, Domenico; Albanese, Stefano; Catani, Vittorio; Dinelli, Enrico; Lima, Annamaria; Valera, Paolo; De Vivo, Benedetto

    2017-04-01

    Characterization of risks to human health is determinant for risk management and population surveillance. This study represent the first work at national scale for Italy about arsenic occurrence, distribution and health impact. We analyzed the As geochemical distribution in different environmental matrices on the whole Italian territory, and assessed both carcinogenic and non-carcinogenic risks for different exposure routes and age groups. The results demonstrate that, in Italy, arsenic is present in significant concentrations both in water (up to 27.2 µg/L) and soils (up to 70 mg/kg). Its presence is mainly controlled by geological processes and locally reflects the industrial history of the Country. The population of the Central Italy, where high content of arsenic in the analyzed samples is due to the presence of alkaline volcanics, are the most exposed to the health risk. Based on the results of our work, it is clear that the consumption of tap water for potable use is the most impactful route for As daily exposure and play an important role in governing potential cancer and non-cancer risks for the considered population. It is interesting to observe that the Incremental Life Cancer Risk through water ingestion show that almost 80% of data falls above the internationally accepted benchmark value of 1 x 10-5. Moreover it was demonstrated that childhood is the most susceptible age stage to As exposure. Geochemical mapping provided a useful tool to spatially analyze and represent data and to highlight the most critic areas and the most exposed population to arsenic at national scale. In conclusion, this study improve knowledge about As occurrence for an entire Country, recognizing an health emerging problem. It might be a good starting point to support the urgently needed policy actions, in order to prevent and reduce the health risk. Moreover, the performed method in this case study research is potentially generalizable and applicable in other countries.

  20. WATEQ3 geochemical model: thermodynamic data for several additional solids

    Energy Technology Data Exchange (ETDEWEB)

    Krupka, K.M.; Jenne, E.A.

    1982-09-01

    Geochemical models such as WATEQ3 can be used to model the concentrations of water-soluble pollutants that may result from the disposal of nuclear waste and retorted oil shale. However, for a model to competently deal with these water-soluble pollutants, an adequate thermodynamic data base must be provided that includes elements identified as important in modeling these pollutants. To this end, several minerals and related solid phases were identified that were absent from the thermodynamic data base of WATEQ3. In this study, the thermodynamic data for the identified solids were compiled and selected from several published tabulations of thermodynamic data. For these solids, an accepted Gibbs free energy of formation, ..delta..G/sup 0//sub f,298/, was selected for each solid phase based on the recentness of the tabulated data and on considerations of internal consistency with respect to both the published tabulations and the existing data in WATEQ3. For those solids not included in these published tabulations, Gibbs free energies of formation were calculated from published solubility data (e.g., lepidocrocite), or were estimated (e.g., nontronite) using a free-energy summation method described by Mattigod and Sposito (1978). The accepted or estimated free energies were then combined with internally consistent, ancillary thermodynamic data to calculate equilibrium constants for the hydrolysis reactions of these minerals and related solid phases. Including these values in the WATEQ3 data base increased the competency of this geochemical model in applications associated with the disposal of nuclear waste and retorted oil shale. Additional minerals and related solid phases that need to be added to the solubility submodel will be identified as modeling applications continue in these two programs.

  1. Exploring quadrangulations

    KAUST Repository

    Peng, Chihan

    2014-01-01

    Here we presented a framework to explore quad mesh topologies. The core of our work is a systematic enumeration algorithm that can generate all possible quadrangular meshes inside a defined boundary with an upper limit of v3-v5 pairs. The algorithm is orders of magnitude more efficient than previous work. The combination of topological enumeration and shape-space exploration demonstrates that mesh topology has a powerful influence on geometry. The Fig. 18. A gallery of different quadrilateral meshes for a Shuriken. The quadrilaterals of the model were colored in a postprocess. Topological variations have distinctive, interesting patterns of mesh lines. © 2014 ACM 0730-0301/2014/01-ART3 15.00.

  2. Radiogenic heat production of crustal rocks: An assessment based on geochemical data

    Science.gov (United States)

    Wollenberg, H. A.; Smith, A. R.

    A survey of the geochemical literature and unpublished data has resulted in the classification of U, Th, and K concentrations by rock type. Over 2500 data entries have been compiled, permitting calculation of their radiogenic heat production. In the igneous rocks mean heat production ranges from highs of 12-20 heat production units (HPU: µWm-3) in some peralkaline intrusives, through ˜ 4 HPU in acidic, ˜ 2 in intermediate, and ˜ 1 in basic rocks, to a low of 0.3 HPU in ultramafic rocks. Siliceous clastic rocks generally have greater heat production (2 to 4 HPU) than do chemical sedimentary rocks, including the carbonates (0.4 to 2 HPU). The heat production of metamorphic rocks generally depends on the radioelement contents of their igneous and sedimentary predecessors, modified by metamorphic processes. Based on estimates of the proportion of the continental crust that specific rock types occupy, the weighted mean radiogenic heat production of the upper continental crust estimated from this data base is ˜ 3 HPU.

  3. Investigation of Coastal Hydrogeology Utilizing Geophysical and Geochemical Tools along the Broward County Coast, Florida

    Science.gov (United States)

    Reich, Christopher D.; Swarzenski, Peter W.; Greenwood, W. Jason; Wiese, Dana S.

    2008-01-01

    Geophysical (CHIRP, boomer, and continuous direct-current resistivity) and geochemical tracer studies (continuous and time-series 222Radon) were conducted along the Broward County coast from Port Everglades to Hillsboro Inlet, Florida. Simultaneous seismic, direct-current resistivity, and radon surveys in the coastal waters provided information to characterize the geologic framework and identify potential groundwater-discharge sites. Time-series radon at the Nova Southeastern University National Coral Reef Institute (NSU/NCRI) seawall indicated a very strong tidally modulated discharge of ground water with 222Rn activities ranging from 4 to 10 disintegrations per minute per liter depending on tidal stage. CHIRP seismic data provided very detailed bottom profiles (i.e., bathymetry); however, acoustic penetration was poor and resulted in no observed subsurface geologic structure. Boomer data, on the other hand, showed features that are indicative of karst, antecedent topography (buried reefs), and sand-filled troughs. Continuous resistivity profiling (CRP) data showed slight variability in the subsurface along the coast. Subtle changes in subsurface resistivity between nearshore (higher values) and offshore (lower values) profiles may indicate either a freshening of subsurface water nearshore or a change in sediment porosity or lithology. Further lithologic and hydrologic controls from sediment or rock cores or well data are needed to constrain the variability in CRP data.

  4. Integration of multi-source data in mineral exploration

    DEFF Research Database (Denmark)

    Conradsen, Knut; Ersbøll, Bjarne Kjær; Nielsen, Allan Aasbjerg

    1991-01-01

    This paper describes several multivariate statistical analysis applications of geochemical, geophysical, and spectral variables in mineral exploration. Mahalanobis' distance is described in some detail and based on four multisource variables this measure is applied to produce a map that gives an ...... of automatically generated linear features based on Landsat TM data. The results indicate among other things a not previously recognized subsurface continuation of an already mapped lineament....

  5. Corporate Recruiters Survey: 2014 Survey Report

    Science.gov (United States)

    Estrada Worthington, Rebecca

    2014-01-01

    The 2014 Corporate Recruiters Survey Report examines the current hiring outlook for graduate business students and analyzes demand by industry and world region, salaries, job functions, and mobility in regional job placement. It also explores recruiter behavior, including recruitment practices and school and candidate selection criteria, and…

  6. Identification of hydrologic and geochemical pathways using high frequency sampling, REE aqueous sampling and soil characterization at Koiliaris Critical Zone Observatory, Crete

    Energy Technology Data Exchange (ETDEWEB)

    Moraetis, Daniel, E-mail: moraetis@mred.tuc.gr [Department of Environmental Engineering, Technical University of Crete, 73100 Chania (Greece); Stamati, Fotini; Kotronakis, Manolis; Fragia, Tasoula; Paranychnianakis, Nikolaos; Nikolaidis, Nikolaos P. [Department of Environmental Engineering, Technical University of Crete, 73100 Chania (Greece)

    2011-06-15

    Highlights: > Identification of hydrological and geochemical pathways within a complex watershed. > Water increased N-NO{sub 3} concentration and E.C. values during flash flood events. > Soil degradation and impact on water infiltration within the Koiliaris watershed. > Analysis of Rare Earth Elements in water bodies for identification of karstic water. - Abstract: Koiliaris River watershed is a Critical Zone Observatory that represents severely degraded soils due to intensive agricultural activities and biophysical factors. It has typical Mediterranean soils under the imminent threat of desertification which is expected to intensify due to projected climate change. High frequency hydro-chemical monitoring with targeted sampling for Rare Earth Elements (REE) analysis of different water bodies and geochemical characterization of soils were used for the identification of hydrologic and geochemical pathways. The high frequency monitoring of water chemical data highlighted the chemical alterations of water in Koiliaris River during flash flood events. Soil physical and chemical characterization surveys were used to identify erodibility patterns within the watershed and the influence of soils on surface and ground water chemistry. The methodology presented can be used to identify the impacts of degraded soils to surface and ground water quality as well as in the design of methods to minimize the impacts of land use practices.

  7. Geochemical data for environmental studies of mineral deposits at Nabesna, Kennecott, Orange Hill, Bond Creek, Bremner, and Gold Hill, Wrangell-St. Elias National Park and Preserve, Alaska

    Science.gov (United States)

    Eppinger, R.G.; Briggs, P.H.; Rosenkrans, D.S.; Ballestrazze, Vanessa; Aldir, Jose; Brown, Z.A.; Crock, J.G.; d'Angelo, W. M.; Doughten, M.W.; Fey, D.L.; Hageman, P.L.; Hopkins, R.T.; Knight, R.J.; Malcolm, M.J.; McHugh, J.B.; Meier, A.L.; Motooka, J.M.; O'Leary, R. M.; Roushey, B.H.; Sultley, S.J.; Theodorakos, P.M.; Wilson, S.A.

    1999-01-01

    Environmental geochemical investigations were carried out between 1994 and 1997 in Wrangell-St. Elias National Park and Preserve (WRST), Alaska. Mineralized areas studied include the historic Nabesna gold mine/mill and surrounding areas; the historic Kennecott copper mill area and nearby Bonanza, Erie, Glacier, and Jumbo mines; the historic mill and gold mines in the Bremner district; the active gold placer mines at Gold Hill; and the unmined copper-molybdenum deposits at Orange Hill and Bond Creek. The purpose of the study was to determine the extent of possible environmental hazards associated with these mineralized areas and to establish background and baseline levels for selected elements. Thus, concentrations of a large suite of trace elements were determined to assess metal loadings in the various sample media collected. This report presents the methodology, analytical results, and sample descriptions for water, leachate, sediment, heavy-mineral concentrate, rock, and vegetation (willow) samples collected during these geochemical investigations. An interpretive U.S. Geological Survey Professional Paper incorporating these geochemical data will follow.

  8. Geophysical and Geochemical Characterization of Subsurface Drip Irrigation Sites, Powder River Basin, Wyoming

    Science.gov (United States)

    Burton, B. L.; Bern, C. R.; Sams, J. I., III; Veloski, G.; Minsley, B. J.; Smith, B. D.

    2010-12-01

    Coalbed natural gas (CBNG) production in the Powder River Basin (PRB) in northeastern Wyoming has increased rapidly since 1997. CBNG production involves the extraction of large amounts of water containing >2000 mg/L total dissolved solids, dominantly sodium bicarbonate. Subsurface drip irrigation (SDI) is a beneficial disposal method of produced waters, provided that waters and associated salts are managed properly. We are studying how water and solute distributions change in soils with progressive irrigation at two PRB sites using a combination of geophysical, geochemical, and mineralogical analyses. Perennial crops are grown at both sites, drip tapes are located at 92 cm depth, and water is applied year-round. The first SDI site is located at the confluence of Crazy Woman Creek and the Powder River. Baseline ground-based and helicopter-borne frequency domain electromagnetic induction (EMI) surveys were completed in 2007 and 2008, respectively, prior to the installation of the SDI system. Since installation, additional ground-based EMI, resistivity, and downhole geophysical log surveys have been completed along with soil geochemical and mineralogical analyses. Determining baseline physical, chemical, and electrical soil characteristics at this study site is an important step in linking the EMI measurements to the soil characteristics they are intended to assess. EMI surveys indicate that soil conductivity has generally increased with irrigation, but lateral migration of water away from the irrigated blocks is minimal. Median downhole electrical conductivity was positively correlated with soil mass wetness but not correlated with soil mineralogy. Soil-water extract results indicate existing salts are chemically heterogeneous throughout the site and in depth. The observed EMI conductivity variations are therefore primarily attributed to water content changes and secondarily to soil texture. The second SDI site, located northeast of Sheridan, WY, has been operating

  9. Gamma radiometric survey of Jamaica

    Energy Technology Data Exchange (ETDEWEB)

    Lalor, G.C.; Robotham, H. (West Indies Univ., Mona (Jamaica)); Miller, J.M.; Simpson, P.R. (British Geological Survey, Keyworth (UK))

    The results of a total gamma radiometric survey of Jamaica, carried out with car-borne instrumentation, are presented and the data compared with the contents of potassium, thorium and uranium in rocks and in surface (soil, stream-sediment, pan concentrate and water) samples obtained at six sites selected to be representative of the principal rock types and surface environments of Jamaica. The work formed part of an orientation study for a regional geochemical survey of the CARICOM countries of the Caribbean. The initial results indicate that enhanced gamma activity is correlated with enrichment in uranium and thorium, but not potassium, in terra rossa soils and/or bauxite deposits in limestone. Elsewhere, gamma levels are increased on the Above Rocks Cretaceous basement Inlier, where they correlate generally with the presence of volcanogenic sediments and a granodiorite intrusion. The lowest radioactivity was recorded in the vicinity of ultrabasic rocks in the Blue Mountains Inlier. (author).

  10. A geochemical study of the River Lagan, Northern Ireland: Insights into the hydrochemical catchment response

    Science.gov (United States)

    Russell, Alexander; Hindshaw, Ruth

    2015-04-01

    The management of water resources is rapidly becoming one of the most important issues affecting many societies worldwide. The chemical components of a river are often not directly related to discharge, instead the water chemistry and transit time of a catchment are a function of several parameters including the flow pathways, water sources and the storage of water within a catchment. There is a need to constrain the parameters controlling hydrochemistry if water resources are to be managed efficiently and be protected from anthropogenic influences. This study will present experimental analysis of a small catchment, focusing on the relationship between discharge and hydrochemistry; tracing water sources through the investigation of the hydrochemistry, δ18O and 87Sr/86Sr composition of rain water, groundwater, and stream water. This study focuses on the River Lagan catchment in Northern Ireland. The lower catchment of the river surrounds the city of Belfast, where it drains into the sea. However, the upper catchment (84.6 km2) is noted to be a natural regime, unaffected by damming and, as such, should provide an ideal opportunity to gain insight into the natural hydrochemistry and hydrologic pathways of the catchment. The bedrock of the area is dominated by the Southern Uplands-Down-Longford Terrane, consisting of greywacke sandstone and mudstone successions. Geochemical data obtained from the Geological Survey of Northern Ireland (GSNI), focusing on stream sediment and soils, suggests there is minimal geochemical variation throughout the upper catchment. The response of the catchment to rainfall was investigated through a time series, recorded during July and August 2014. This time series included a more intensive hourly series, taken over a period of 24 hours, during a forecast rain event. Potential end-members were also sampled: shallow groundwater samples were taken from a well and regular rain samples were collected. Spatial variability within the catchment

  11. Geochemical analysis of leachates from cement/low-level radioactive waste/soil systems

    Energy Technology Data Exchange (ETDEWEB)

    Criscenti, L.J.; Serne, R.J.

    1988-09-01

    Laboratory experiments were conducted as part of the Special Waste Form Lysimeters/endash/Arid Program. These experiments were conducted to investigate the performance of solidified low-level nuclear waste in a typical arid, near-surface disposal site, and to evaluate the ability of laboratory tests to predict leaching in actual field conditions. Batch leaching, soil adsorption column, and soil/waste form column experiments were conducted using Portland III cement waste forms containing boiling-water reactor evaporator concentrate and ion-exchange resin waste. In order to understand the reaction chemistry of the cement waste form/soil/ground-water system, the compositions of the leachates from the laboratory experiments were studied with the aid of the MINTEQ ion speciation/solubility and mass transfer computer code. The purpose of this report is to describe the changes in leachate composition that occur during the course of the experiments, to discuss the geochemical modeling results, and to explore the factors controlling the major element chemistry of these leachates. 18 refs., 84 figs., 14 tabs.

  12. Geochemical characteristics of igneous rocks associated with epithermal mineral deposits—A review

    Science.gov (United States)

    du Bray, Edward A.

    2017-01-01

    Newly synthesized data indicate that the geochemistry of igneous rocks associated with epithermal mineral deposits varies extensively and continuously from subalkaline basaltic to rhyolitic compositions. Trace element and isotopic data for these rocks are consistent with subduction-related magmatism and suggest that the primary source magmas were generated by partial melting of the mantle-wedge above subducting oceanic slabs. Broad geochemical and petrographic diversity of individual igneous rock units associated with epithermal deposits indicate that the associated magmas evolved by open-system processes. Following migration to shallow crustal reservoirs, these magmas evolved by assimilation, recharge, and partial homogenization; these processes contribute to arc magmatism worldwide.Although epithermal deposits with the largest Au and Ag production are associated with felsic to intermediate composition igneous rocks, demonstrable relationships between magmas having any particular composition and epithermal deposit genesis are completely absent because the composition of igneous rock units associated with epithermal deposits ranges from basalt to rhyolite. Consequently, igneous rock compositions do not constitute effective exploration criteria with respect to identification of terranes prospective for epithermal deposit formation. However, the close spatial and temporal association of igneous rocks and epithermal deposits does suggest a mutual genetic relationship. Igneous systems likely contribute heat and some of the fluids and metals involved in epithermal deposit formation. Accordingly, deposit formation requires optimization of source metal contents, appropriate fluid compositions and characteristics, structural features conducive to hydrothermal fluid flow and confinement, and receptive host rocks, but not magmas with special compositional characteristics.

  13. Space exploration

    CERN Document Server

    2009-01-01

    Space Exploration, is one book in the Britannica Illustrated Science Library Series that is correlated to the science curriculum in grades 5-8. The Britannica Illustrated Science Library is a visually compelling set that covers earth science, life science, and physical science in 16 volumes.  Created for ages 10 and up, each volume provides an overview on a subject and thoroughly explains it through detailed and powerful graphics-more than 1,000 per volume-that turn complex subjects into information that students can grasp.  Each volume contains a glossary with full definitions for vocabulary help and an index.

  14. Geothermal Exploration of Newberry Volcano, Oregon

    Energy Technology Data Exchange (ETDEWEB)

    Waibel, Albert F. [Columbia Geoscience, Pasco, WA (United States); Frone, Zachary S. [Southern Methodist Univ., Dallas, TX (United States); Blackwell, David D. [Southern Methodist Univ., Dallas, TX (United States)

    2014-12-01

    Davenport Newberry (Davenport) has completed 8 years of exploration for geothermal energy on Newberry Volcano in central Oregon. Two deep exploration test wells were drilled by Davenport on the west flank of the volcano, one intersected a hydrothermal system; the other intersected isolated fractures with no hydrothermal interconnection. Both holes have bottom-hole temperatures near or above 315°C (600°F). Subsequent to deep test drilling an expanded exploration and evaluation program was initiated. These efforts have included reprocessing existing data, executing multiple geological, geophysical, geochemical programs, deep exploration test well drilling and shallow well drilling. The efforts over the last three years have been made possible through a DOE Innovative Exploration Technology (IET) Grant 109, designed to facilitate innovative geothermal exploration techniques. The combined results of the last 8 years have led to a better understanding of the history and complexity of Newberry Volcano and improved the design and interpretation of geophysical exploration techniques with regard to blind geothermal resources in volcanic terrain.

  15. Geochemical characteristics of West Molokai shield- and postshield-stage lavas: Constraints on Hawaiian plume models

    Science.gov (United States)

    Xu, Guangping; Frey, Frederick A.; Clague, David A.; Abouchami, Wafa; Blichert-Toft, Janne; Cousens, Brian; Weisler, Marshall

    2007-08-01

    There are systematic geochemical differences between the Hawaiian shields forming the subparallel spatial trends, known as Loa and Kea. These spatial and temporal geochemical changes provide insight into the spatial distribution of geochemical heterogeneities within the source of Hawaiian lavas, and the processes that create the Hawaiian plume. Lavas forming the ˜1.9 Ma West Molokai volcano are important for evaluating alternative models proposed for the spatial distribution of geochemical heterogeneities because (1) the geochemical distinction between Loa and Kea trends may end at the Molokai Fracture Zone and (2) West Molokai is a Loa-trend volcano that has exposures of shield and postshield lavas. This geochemical study (major and trace element abundances and isotopic ratios of Sr, Nd, Hf, and Pb) shows that the West Molokai shield includes lavas with Loa- and Kea-like geochemical characteristics; a mixed Loa-Kea source is required. In contrast, West Molokai postshield lavas are exclusively Kea-like. This change in source geochemistry can be explained by the observed change in strike of the Pacific plate near Molokai Island so that as West Molokai volcano moved away from a mixed Loa-Kea source it sampled only the Kea side of a bilaterally zoned plume.

  16. Landscape and bio- geochemical strategy for monitoring transformation and reclamation of the soil mining sites

    Science.gov (United States)

    Korobova, Elena

    2010-05-01

    Sites of active or abandoned mining represent areas of considerable technogenic impact and need scientifically ground organization of their monitoring and reclamation. The strategy of monitoring and reclamation depends on the scale and character of the physical, chemical and biological consequences of the disturbances. The geochemical studies for monitoring and rehabilitation of the career-dump complexes should methodically account of formation of the particular new landforms and the changes in circulation of the remobilized elements of the soil cover. However, the general strategy should account of both the initial and transformed landscape geochemical structure of the area with due regard to the natural and new content of chemical elements in the environmental components. For example the tailings and waste rocks present new geochemical fields with specifically different concentration of chemical elements that cause formation of new geochemical barriers and landscapes. The way of colonization of the newly formed landscapes depends upon the new geochemical features of the technogenic environment and the adaptive ability of local and intrusive flora. The newly formed biogeochemical anomalies need organization of permanent monitoring not only within the anomaly itself but also of its impact zones. Spatial landscape geochemical monitoring combined with bio-geochemical criteria of threshold concentrations seems to be a helpful tool for decision making on reclamation and operation of the soil mining sites to provide a long-term ecologically sustainable development of the impact zone as a whole.

  17. Experiments on geochemical prospecting for uranium in arid country; Essais de prospection geochimique de l'uranium en pays aride

    Energy Technology Data Exchange (ETDEWEB)

    Grimbert, A.; Obellianne, J.M. [Commissariat a l' Energie Atomique, Centre d' Etudes Nucleaires de Fontenay-aux-Roses, 92 (France)

    1962-07-01

    The necessity for preliminary inquiries before applying routine geochemical prospecting techniques to the exploration of a new region is shown. Under conditions presumed to be unfavorable for geochemical prospecting as found in Nigeria along the banks of the Air, a preliminary examination showed that sampling of the stabilized superficial deposits at a depth of 15 cm made it possible to detect the presence of U-containing mineralizations hidden under about 20 meters of sterile sandy deposits. To confirm this result, a boring located on a U-containing geochemical anomaly in a paleosol, encountered a mineralized formation at a depth of 28 meters. (authors) [French] Les auteurs montrent la necessite des enquetes preliminaires avant toute application en routine des techniques geochimiques de prospection, lorsque l'on aborde une region nouvelle. Dans les conditions, a priori defavorables pour la prospection geochimique, que l'on trouve au Niger, en bordure de l'Air, une enquete preliminaire a etabli que l'echantillonnage des depots superficiels stabilises, a 15 centimetres de profondeur, permettait de deceler la presence de mineralisations uraniferes cachees sous une vingtaine de metres de sediments greseux steriles. Pour verifier ce resultat, un sondage implante sur une anomalie geochimique uranifere au sein d'un paleosol, a rencontre une formation mineralisee a 28 metres de profondeur. (auteurs)

  18. Do weirs affect the physical and geochemical mobility of toxic metals in mining-impacted floodplain sediments?

    Science.gov (United States)

    Bulcock, Amelia; Coleman, Alexandra; Whitfield, Elizabeth; Andres Lopez-Tarazon, Jose; Byrne, Patrick; Whitfield, Greg

    2015-04-01

    aerial vehicle (UAV) photographic surveys, historical aerial photographs, ground-based topographic surveys, surface and subsurface particle size determination, bed stability and sediment entrainment assessment, together with discharge and sediment (both suspended and bedload) monitoring to establish the effect of the weir on patterns of sediment flux and the physical transport of metal contaminants. 2D and 1D models (IBER, HEC-RAS) of the weir-affected reach will investigate sediment and metal flux following weir removal. (2) The physicochemical speciation and geochemical stability of contaminated floodplain sediments will be characterised using bulk chemistry, mineralogical (XRD, SEM) and speciation methods (sequential extractions, electron microprobe analysis).

  19. Geothermal resources in Martinique (Lesser Antilles): new insight of geochemical isotopic tools

    Science.gov (United States)

    Gadalia, A.; Rad, S.; Braibant, G.; Brach, M.; Millot, R.; Traineau, H.

    2012-12-01

    exploration, especially in a context of difficult topography, seems to be a fast method and good indicator of hydrothermal manifestations at large scale before focusing on detail zones. References : Germa, A., Quidelleur, X., Labanieh, S., Chauvel, C., Lahitte, P., 2011. The volcanic evolution of Martinique Island: Insights from K-Ar dating into the Lesser Antilles arc migration since the Oligocene. Journal of Volcanology and Geothermal Research. 208, 122-135. Rad, S., Rivé, K., Allègre, C.J., 2011. Weathering regime associated with subsurface circulation on volcanic islands. Aquat. Geochem. 17, 3, 221-241.

  20. Exploring textual data

    CERN Document Server

    Lebart, Ludovic; Berry, Lisette

    1998-01-01

    Researchers in a number of disciplines deal with large text sets requiring both text management and text analysis. Faced with a large amount of textual data collected in marketing surveys, literary investigations, historical archives and documentary data bases, these researchers require assistance with organizing, describing and comparing texts. Exploring Textual Data demonstrates how exploratory multivariate statistical methods such as correspondence analysis and cluster analysis can be used to help investigate, assimilate and evaluate textual data. The main text does not contain any strictly mathematical demonstrations, making it accessible to a large audience. This book is very user-friendly with proofs abstracted in the appendices. Full definitions of concepts, implementations of procedures and rules for reading and interpreting results are fully explored. A succession of examples is intended to allow the reader to appreciate the variety of actual and potential applications and the complementary processin...

  1. Fiscal 1997 report on the verification survey of geothermal exploration technology. 2. Development of the reservoir variation survey method (development of the gravity survey method); 1997 nendo chinetsu tansa gijutsu nado kensho chosa. Choryuso hendo tansaho kaihatsu (juryoku tansaho kaihatsu) hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    Among technology developments such as the reservoir evaluation at initial developmental stage and stabilization/maintenance of power after the start of operation, the fiscal 1997 result was described of the development of the gravity survey method. The paper conducted the installation of gravity measuring points outside the existing monitoring range, introduction of CG-3M gravimeter/GPS measuring system, drilling of ground water level monitoring well, etc. for the setup of a system for new gravity monitoring. Moreover, regular measurement of gravity was made for the first fiscal year, and at the same time the continued observation of ground water level, precipitation, atmospheric pressure, and temperature was started. It is necessary to study the effects on gravity variation such as gravity gradient and tidal correction. Conducted were collection/arrangement of the existing data and database construction for history matching/variation prediction in the Yanaizu Nishiyama area. The paper made surveys of the trends/literature. In the future, needed are the computation using density models of geothermal reservoirs and test use of EDCON`s downhole gravimeter. 44 refs., 30 figs., 17 tabs.

  2. Geochemical data for stream-sediment, heavy-mineral-concentrate and rock samples collected from the Fortyseven Creek gold-arsenic-antimony-tungsten prospect, southwestern Alaska

    Science.gov (United States)

    Gray, John E.; Lee, G.K.; O'Leary, R. M.; Theodorakos, P.M.

    1999-01-01

    In the summer of 1991, we conducted a reconnaissance geochemical survey around the Fortyseven Creek Au-As-Sb-W prospect that is located in the southwestern part of the Sleetmute quadrangle. At that time, this project was a small part of a more comprehensive Alaska Mineral Resource Assessment Program (AMRAP) study of the Sleemute quadrangle. AMRAP studies were conducted by the U.S. Geological Survey (USGS) to fulfill requirements of the Alaska National Interests Lands Conservation Act (Public Law 96-487, 1980) to survey certain federal lands to determine their mineral potential. Although AMRAP is no longer in operation, this study represents a small topical study that was conducted during the Sleetmute quadrangle AMRAP study. The objective of the Fortyseven Creek work was to characterize the geochemistry of samples collected downstream from the Fortyseven Creek prospect, as well as mineralized and altered rock samples collected from the prospect. In this report, we describe the samples collected in 1991, the methods used for the analysis of the samples, and the geochemical data for these samples. The data in this report are also available in digital form on computer diskette in Gray and others (1999). An interpretation of these data appears in Gray and others (1998).

  3. New Results for the Multi-stage Geochemical Evolution of the Manihiki and Hikurangi Plateaus (Invited)

    Science.gov (United States)

    Hoernle, K.; Timm, C.; Hauff, S. F.; Rupke, L.; Werner, R.; van den Bogaard, P.; Michael, P. J.; Coffin, M.; Mortimer, N. N.; Davy, B. W.

    2009-12-01

    range from E-MORB (FOZO) - like to HIMU-type isotopic compositions (with 206Pb/204Pb approaching 21) and are similar in composition to rare 90 Ma old alkalic dikes on the OJP. The geochemical data support a common origin and geochemical evolution for the Manihiki, Hikurangi and OJ plateaus. Evidence for large degrees of melting of an enriched peridotitic source at elevated mantle potential temperature favors a plume-type model for the origin of these plateau fragments. The late alkalic stage of volcanism, however, is more difficult to explain, since the plateaus were located thousands of kilometers apart when this volcanism primarily occurred (c. 70-100 Ma ago). We are exploring detachment/delamination and pulsating super-plume models to explain the origin of the late-stage volcanism.

  4. Geoelectrical exploration

    Directory of Open Access Journals (Sweden)

    Mostafa Said Barseem

    2015-12-01

    Full Text Available Sinai development is a goal of successive governments in Egypt. The present study is a geoelectrical exploration to find appropriate solutions of the problems affecting the land of a Research Station in Southeast Al Qantara. This research station is one of the Desert Research Center stations to facilitate the development of desert land for agriculture by introducing applied research. It suffers from some problems which can be summarized in the shortage of irrigation water and water logging. The appropriate solutions of these problems have been delineated by the results of 1D and 2D geoelectrical measurements. Electrical resistivity (ER revealed the subsurface sedimentary sequences and extension of subsurface layers in the horizontal and vertical directions, especially, the water bearing layer. Additionally it helped to choose the most suitable places to drill productive wells with a good condition.

  5. Exploring ESASky

    Science.gov (United States)

    De Marchi, Guido; ESASky Team

    2017-06-01

    ESASky is a science-driven discovery portal for all ESA space astronomy missions. It also includes missions from international partners such as Suzaku and Chandra. The first public release of ESASky features interfaces for sky exploration and for single and multiple target searches. Using the application requires no prior-knowledge of any of the missions involved and gives users world-wide simplified access to high-level science-ready data products from space-based Astronomy missions, plus a number of ESA-produced source catalogues, including the Gaia Data Release 1 catalogue. We highlight here the latest features to be developed, including one that allows the user to project onto the sky the footprints of the JWST instruments, at any chosen position and orientation. This tool has been developed to aid JWST astronomers when they are defining observing proposals. We aim to include other missions and instruments in the near future.

  6. Intermittent Volcanism in the S Pacific: Tracking Persistent Geochemical Sources

    Science.gov (United States)

    Konter, J. G.; Koppers, A. A.; Staudigel, H.; Hanan, B. B.; Blichert-Toft, J.

    2004-12-01

    South Pacific ocean intraplate volcanoes (OIV's) have formed relatively short, discontinuous chains over the last 140 Ma, in contrast to classic continuous hot spot chains like Hawaii or Louisville. Moreover, its volcanism stands apart by very diverse and radiogenic mantle source regions, defining the South Pacific Isotopic and Thermal Anomaly (SOPITA). Discontinuous SOPITA OIV's form a complex array of crossing lineaments and isolated seamounts that can be back-tracked in time to the western Pacific. We studied the Hf and Pb isotopic composition of the prominent western Gilbert's and Tokelau chain that mostly correspond to the plate motion stage expressed by the Emperor Seamounts. The Gilbert's chain (to the West of Tokelau) has an age range of 74-65 Ma, and back-tracks to an OIV source origin near Rurutu. Notably, this chain shows an isotopic signature similar to the Rurutu chain, from Burtaritari (176Hf/177Hf: 0.282900, 206Pb/204Pb: 20.582) to Tuba (0.282938, 19.691). The parallel-running Tokelau chain ranges from 76-58 Ma, projecting current activity around Macdonald seamount. Its isotopic composition is also similar to Macdonald seamount, as shown by Howland (0.282951, 20.773) to Polo (0.283050, 19.390). However, both chains also contain seamounts with ages and isotopic signatures that are outliers, inconsistent with their general age range and isotopic trends (e.g. Ava; 0.282641, 17.729 and Sakau; 0.282880, 18.997). Our results show that the discontinuous magmatic provinces within SOPITA can be tracked back in time by geochronology and geochemical fingerprinting. This suggests that the SOPITA OIV's are fed by distinct, long-lived mantle source regions that may turn "on" or "off" for distinct periods during their life-times. This intermittent volcanism is inconsistent with the "standard" fixed hot spot model, since it does not produce continuous chains with linear age progressions. Furthermore, our results demonstrate the utility of geochemical fingerprinting

  7. Phosphorus geochemical cycling inferences from high frequency lake monitoring

    Science.gov (United States)

    Crockford, Lucy; Jordan, Philip; Taylor, David

    2013-04-01

    Freshwater bodies in Europe are required to return to good water quality status under the Water Framework Directive by 2015. A small inter-drumlin lake in the northeast of Ireland has been susceptible to eutrophic episodes and the presence of algal blooms during summer since annual monitoring began in 2002. While agricultural practice has been controlled by the implementation of the Nitrates Directive in 2006, the lake is failing to recover to good water quality status to meet with the Water Framework Directive objectives. Freshwaters in Ireland are regarded, in the main, as phosphorus (P) limited so identifying the sources of P possibly fuelling the algal blooms may provide an insight into how to improve water quality conditions. In a lake, these sources are divided between external catchment driven loads, as a result of farming and point sources, and P released from sediments made available to photic waters through internal lake mechanisms. High frequency sensors on data-sondes, installed on the lake in three locations, have provided chlorophyll a, redox potential, dissolved oxygen, temperature, pH, conductivity and turbidity data since March 2010. A data-sonde was installed in the hypolimnion to observe the change in lake conditions as P is released from lake sediments as a result of geochemical cycling with iron during anoxic periods. As compact high frequency sampling equipment for P analysis is still in its infancy for freshwaters, a proxy measurement of geochemical cycling in lakes would be useful to determine fully the extent of P contribution from sediments to the overall P load. Phosphorus was analysed once per month along with a number of other parameters and initial analysis of the high frequency data has shown changes in readings when known P release from lake sediments has occurred. Importantly, these data have shown when these P enriched hypolimnetic waters may be re-introduced to shallower waters in the photic zone, by changes in dissolved oxygen

  8. Geochemical databases: minding the pitfalls to avoid the pratfalls

    Science.gov (United States)

    Goldstein, S. L.; Hofmann, A. W.

    2011-12-01

    The field of geochemistry has been revolutionized in recent years by the advent of databases (PetDB, GEOROC, NAVDAT, etc). A decade ago, a geochemical synthesis required major time investments in order to compile relatively small amounts of fragmented data from large numbers of publications, Now virtually all of the published data on nearly any solid Earth topic can be downloaded to nearly any desktop computer with a few mouse clicks. Most solid Earth talks at international meetings show data compilations from these databases. Applications of the data are playing an increasingly important role in shaping our thinking about the Earth. They have changed some fundamental ideas about the compositional structure of the Earth (for example, showing that the Earth's "trace element depleted upper mantle" is not so depleted in trace elements). This abundance of riches also poses new risks. Until recently, important details associated with data publication (adequate metadata and quality control information) were given low priority, even in major journals. The online databases preserve whatever has been published, irrespective of quality. "Bad data" arises from many causes, here are a few. Some are associated with sample processing, including incomplete dissolution of refractory trace minerals, or inhomogeneous powders, or contamination of key elements during preparation (for example, this was a problem for lead when gasoline was leaded, and for niobium when tungsten-carbide mills were used to powder samples). Poor analytical quality is a continual problem (for example, when elemental abundances are at near background levels for an analytical method). Errors in published data tables (more common than you think) become bad data in the databases. The accepted values of interlaboratory standards change with time, while the published data based on old values stay the same. Thus the pitfalls associated with the new data accessibility are dangerous in the hands of the inexperienced

  9. Cool seafloor hydrothermal springs reveal global geochemical fluxes

    Science.gov (United States)

    Wheat, C. Geoffrey; Fisher, Andrew T.; McManus, James; Hulme, Samuel M.; Orcutt, Beth N.

    2017-10-01

    We present geochemical data from the first samples of spring fluids from Dorado Outcrop, a basaltic edifice on 23 M.y. old seafloor of the Cocos Plate, eastern Pacific Ocean. These samples were collected from the discharge of a cool hydrothermal system (CHS) on a ridge flank, where typical reaction temperatures in the volcanic crust are low (2-20 °C) and fluid residence times are short. Ridge-flank hydrothermal systems extract 25% of Earth's lithospheric heat, with a global discharge rate equivalent to that of Earth's river discharge to the ocean; CHSs comprise a significant fraction of this global flow. Upper crustal temperatures around Dorado Outcrop are ∼15 °C, the calculated residence time is concentrations in spring fluids are indistinguishable from those of bottom seawater; however, concentrations of Rb, Mo, V, U, Mg, phosphate, Si and Li are different. Applying these observed differences to calculated global CHS fluxes results in chemical fluxes for these ions that are ≥15% of riverine fluxes. Fluxes of K and B also may be significant, but better analytical resolution is required to confirm this result. Spring fluids also have ∼50% less dissolved oxygen (DO) than bottom seawater. Calculations of an analytical model suggest that the loss of DO occurs primarily (>80%) within the upper basaltic crust by biotic and/or abiotic consumption. This calculation demonstrates that permeable pathways within the upper crust can support oxic water-rock interactions for millions of years.

  10. Geochemical effects of electro-osmosis in clays

    KAUST Repository

    Loch, J. P. Gustav

    2010-02-13

    Geochemical effects of electro-osmosis in bentonite clay are studied in the laboratory, where a 6 mm thick bentonite layer is subjected to direct current. Acidification and alkalization near anode and cathode are expected, possibly causing mineral deterioration, ion mobilization and precipitation of new solids. Afterwards the clay is analysed by XRF and anolyte and catholyte are analysed by ICP-MS. In addition, as a preliminary experiment treated bentonite is analysed by high resolution μ-XRF. Electro-osmotic flow is observed. Due to its carbonate content the bentonite is pH-buffering. Alkalization in the catholyte is substantial. Ca, Na and Sr are significantly removed from the clay and accumulate in the catholyte. Recovery in the catholyte accounts for a small fraction of the element-loss from the clay. The rest will have precipitated in undetected solid phases. μ-XRF indicates the loss of Ca-content throughout the bentonite layer. © The Author(s) 2010.