Semi-detailed uranium geochemical survey in Northwestern Samar (27 March 1979 - 4 July 1979)

International Nuclear Information System (INIS)

Santos, G. Jr.; Ogena, M.; Tauli, G.

1980-04-01

A uranium geochemical survey was conducted to delineate in detail the uranium prospective area(s) in northwestern Samar. A total of 805 stream sediments and 1.115 water samples were obtained from the target areas from uranium analysis. Geochemical anomalies were indicated in San Isidro and Mauo. Geochemical correlations between uranium and trace elements (Pb, Ag, Ni, Cu, Co, Zn and Mn) were generally poor. (ELC)

Geochemical exploration for uranium

International Nuclear Information System (INIS)

Rose, A.W.

1977-01-01

The processes and types of dispersion that produce anomalies in stream water, stream sediment, and ground water, and the factors that must be considered in planning and interpreting geochemical surveys are reviewed. Examples of surveys near known deposits show the types of results to be expected. Background values depend mainly on the content of U in rocks of the drainage area. In igneous rocks, U tends to increase with potassium from ultramafic rocks (0.01 ppM) to granitic rocks (1 to 5 ppM). Some alkalic rocks have unusually high contents of U (15 to 100 ppM). Uranium-rich provinces marked by igneous rocks unusually rich in U are recognized in several areas and appear to have a deep crustal or mantle origin. In western U.S., many tertiary tuffaceous rocks have a high U content. Sandstones, limestones, and many shales approximate the crustal abundance at 0.5 to 4 ppM, but black shales, phosphates, and some organic materials are notably enriched in U. Uranium is very soluble in most oxidizing waters at the earth's surface, but is precipitated by reducing agents (organic matter, H 2 S) and adsorbed by organic material and some Fe oxides. In most surface and ground waters, U correlates approximately with the total dissolved solids, conductivity, and bicarbonate concentration of the water, and with the U content of rocks it comes into contact with. Most surveys of stream water near known districts show distinct anomalies extending a few km to tens of km downstream. A complication with water is the large variability with time, up to x 50, as a result of changes in the ratio of ground water to direct runoff, and changes in rate of oxidation and leaching. Collection and analysis of water samples also pose some difficulties

Geochemical drainage surveys for uranium: sampling and analytical methods based on trial surveys in Pennsylvania

International Nuclear Information System (INIS)

Rose, A.W.; Keith, M.L.; Suhr, N.H.

1976-01-01

Geochemical surveys near sandstone-type uranium prospects in northeastern and north-central Pennsylvania show that the deposits can be detected by carefully planned stream sediment surveys, but not by stream water surveys. Stream waters at single sites changed in U content by x10 to 50 during the 18 months of our studies, and even near known prospects, contain less than 0.2 ppB U most of the time. Uranium extractable from stream sediment by acetic acid--H 2 O 2 provides useful contrast between mineralized and nonmineralized drainages of a square mile or less; total U in sediment does not. High organic material results in increased U content of sediments and must be corrected. Changes in U content of sediment with time reach a maximum of x3 and appear to be of short duration. A sediment of about 200 mi 2 near Jim Thorpe detects anomalies extending over several square miles near known occurrences and a second anomaly about two miles northeast of Penn Haven Jct. A similar survey in Lycoming-Sullivan Counties shows anomalous zones near known prospects of the Beaver Lake area and northwest of Muncy Creek. As, Mn, Pb, and V are enriched in the mineralized zones, and perhaps in surrounding halo zones, but do not appear to be pathfinder elements useful for reconnaissance exploration

The geochemical atlas of Alaska, 2016

Science.gov (United States)

Lee, Gregory K.; Yager, Douglas B.; Mauk, Jeffrey L.; Granitto, Matthew; Denning, Paul; Wang, Bronwen; Werdon, Melanie B.

2016-06-21

A rich legacy of geochemical data produced since the early 1960s covers the great expanse of Alaska; careful treatment of such data may provide significant and revealing geochemical maps that may be used for landscape geochemistry, mineral resource exploration, and geoenvironmental investigations over large areas. To maximize the spatial density and extent of data coverage for statewide mapping of element distributions, we compiled and integrated analyses of more than 175,000 sediment and soil samples from three major, separate sources: the U.S. Geological Survey, the National Uranium Resource Evaluation program, and the Alaska Division of Geological & Geophysical Surveys geochemical databases. Various types of heterogeneity and deficiencies in these data presented major challenges to our development of coherently integrated datasets for modeling and mapping of element distributions. Researchers from many different organizations and disparate scientific studies collected samples that were analyzed using highly variable methods throughout a time period of more than 50 years, during which many changes in analytical techniques were developed and applied. Despite these challenges, the U.S. Geological Survey has produced a new systematically integrated compilation of sediment and soil geochemical data with an average sample site density of approximately 1 locality per 10 square kilometers (km2) for the entire State of Alaska, although density varies considerably among different areas. From that compilation, we have modeled and mapped the distributions of 68 elements, thus creating an updated geochemical atlas for the State.

Geochemical analysis of brine samples for exploration of Borate deposits in the South of Sabzevar

Directory of Open Access Journals (Sweden)

Mahdi Bemani

2016-07-01

suggested for detailed exploration (Bemani et al., 2014. Generally speaking, for considering the spatial distribution of data the fractal method could better identify the anomalies. Also, EDA is a quick and easy method to detect anomalies. Acknowledgment The authors are grateful to the Kaniran Mining Company and the south Khorasan branch of the Iranian Mining Engineering Organization for their financial support of this study. References Bemani, M., 2012. Prospecting and Exploring of Borax in the south of Sabzevar, combination of remote sensing, field surveying and geochemical studying. M.Sc. Thesis, University of Yazd, Yazd, Iran, 137 pp (in Persian with English abstract. Bemani, M., Mojtahedzadeh, S.H. and Kohsari, A.H., 2014. Investigation of geology, mineralogy and genesis of Mohammadabad-Oryan index boron (south of Sabzevar. Iranian Journal of Crystallography and Mineralogy 22(1: 173- 186 (in Persian with English abstract. Carranza, E.J.M., 2009. Geochemical Anomaly and Mineral Prospectivity Mapping in GIS. In: M. Hale (Editor, Handbook of exploration and environmental geochemistry. Elsevier, Amsterdam, pp. 51-115. Filliben, J.J. and Heckert, A., 2005. Exploratory data analysis. Engineering Statistics Handbook, Internet, National Institute of Standards and Technology, http://www.itl.nist.gov/div898/handbook/eda/section3/eda356.htm. Hasanipak, A.A. and Sharafaddin, M., 2005. Exploratory Data Analysis.Tehran University press, Tehran 996 pp (in Persian.

Application of integrated Landsat, geochemical and geophysical data in mineral exploration

International Nuclear Information System (INIS)

Conradsen, K.; Nilsson, G.; Thyrsted, T.; Gronlands Geologiske Undersogelse, Copenhagen, Denmark)

1985-01-01

In South Greenland (20000 sq. km) a remote sensing investigation is executed in connection with uranium exploration. The investigation includes analysis of Landsat data, conversion of geological, geochemical and geophysical data to image format compatible with Landsat images, and analysis of the total set of integrated data. The available geochemical data consisted of samples from 2000 sites, analyzed for U, K, Rb, Sr, Nb, Ga, Y, and Fe. The geophysical data comprised airborne gamma-spectrometric measurements and aeromagnetic data. The interpolation routines consisted of a kriging procedure for the geochemical data and a minimum curvature routine for the geophysical data. The analysis of the integrated data set is at a preliminary stage. As example a composite image showing Landsat channel 7, magnetic values, and Fe values as respectively intensity, hue and saturation is analyzed. It reveals alkaline intrusions and basaltic layers as anomalies while other anomalies cannot be accounted for on the basis of the present geological knowledge. 12 references

Stream-sediment geochemical exploration for uranium in Narigan area Central Iran

International Nuclear Information System (INIS)

Yazdi, M.; Khoshnoodi, K.; Kavand, M.; Ashteyani, A. R.

2009-01-01

Uranium deposits of Iran occur mainly in the Central Iran zone. Several uranium deposits have been discovered in this zone. The Narigan area is one of the most important uranium mineralized area in this zone. The uranium bearing sequences in this area are contained in the plutonic to volcanic rocks of Narigan which intruded to the Pre-Cambrian pyroclastics rocks. Plutonic and volcanic rocks are granite, rhyolite and volcanoclastic. Diabasic dykes have been intruded to these igneous rocks. The plutonic and volcanic rocks have been covered by Cretaceous limestones which seem to be youngest the rocks in this area. The aim of our project is to develop a regional exploration strategy for uranium in these igneous rocks. A grid-based sampling was planned following the results of the previous geochemical mapping at a scale of 1:100,000, integrated with geophysical data and alteration zones and outcrop of intrusive rocks. The following results are based on geological, and stream geochemical explorations in 1:20000 scale of this area. During this study 121 samples were collected from the stream sediments of <80 mesh for final sampling. Ten percent of the samples were used for checking laboratories errors. The samples were collected according to conventional methods from 30-40 cm depth of stream sediments. Finally, geochemical and radiometric data were combined and the results introduced 3 anomalies in the Narigan area

An integrated geophysical and geochemical exploration of critical zone weathering on opposing montane hillslope

Science.gov (United States)

Singha, K.; Navarre-Sitchler, A.; Bandler, A.; Pommer, R. E.; Novitsky, C. G.; Holbrook, S.; Moore, J.

2017-12-01

Quantifying coupled geochemical and hydrological properties and processes that operate in the critical zone is key to predicting rock weathering and subsequent transmission and storage of water in the shallow subsurface. Geophysical data have the potential to elucidate geochemical and hydrologic processes across landscapes over large spatial scales that are difficult to achieve with point measurements alone. Here, we explore the connections between weathering and fracturing, as measured from integrated geochemical and geophysical borehole data and seismic velocities on north- and south-facing aspects within one watershed in the Boulder Creek Critical Zone Observatory. We drilled eight boreholes up to 13 m deep on north- and south-facing aspects within Upper Gordon Gulch, and surface seismic refraction data were collected near these wells to explore depths of regolith and bedrock, as well as anisotropic characteristics of the subsurface material due to fracturing. Optical televiewer data were collected in these wells to infer the dominant direction of fracturing and fracture density in the near surface to corroborate with the seismic data. Geochemical samples were collected from four of these wells and a series of shallow soil pits for bulk chemistry, clay fraction, and exchangeable cation concentrations to identify depths of chemically altered saprolite. Seismic data show that depth to unweathered bedrock, as defined by p-wave seismic velocity, is slightly thicker on the north-facing slopes. Geochemical data suggest that the depth to the base of saprolite ranges from 3-5 m, consistent with a p-wave velocity value of 1200 m/s. Based on magnitude and anisotropy of p-wave velocities together with optical televiewer data, regolith on north-facing slopes is thought to be more fractured than south-facing slopes, while geochemical data indicate that position on the landscape is another important characteristic in determining depths of weathering. We explore the importance

Recent developments and evaluation of selected geochemical techniques applied to uranium exploration

International Nuclear Information System (INIS)

Wenrich-Verbeek, K.J.; Cadigan, R.A.; Felmlee, J.K.; Reimer, G.M.; Spirakis, C.S.

1976-01-01

Various geochemical techniques for uranium exploration are currently under study by the geochemical techniques team of the Branch of Uranium and Thorium Resources, US Geological Survey. Radium-226 and its parent uranium-238 occur in mineral spring water largely independently of the geochemistry of the solutions and thus are potential indicators of uranium in source rocks. Many radioactive springs, hot or cold, are believed to be related to hydrothermal systems which contain uranium at depth. Radium, when present in the water, is co-precipitated in iron and/or manganese oxides and hydroxides or in barium sulphate associated with calcium carbonate spring deposits. Studies of surface water samples have resulted in improved standardized sample treatment and collection procedures. Stream discharge has been shown to have a significant effect on uranium concentration, while conductivity shows promise as a ''pathfinder'' for uranium. Turbid samples behave differently and consequently must be treated with more caution than samples from clear streams. Both water and stream sediments should be sampled concurrently, as anomalous uranium concentrations may occur in only one of these media and would be overlooked if only one, the wrong one, were analysed. The fission-track technique has been applied to uranium determinations in the above water studies. The advantages of the designed sample collecting system are that only a small quantity, typically one drop, of water is required and sample manipulation is minimized, thereby reducing contamination risks. The fission-track analytical technique is effective at the uranium concentration levels commonly found in natural waters (5.0-0.01 μg/litre). Landsat data were used to detect alteration associated with uranium deposits. Altered areas were detected but were not uniquely defined. Nevertheless, computer processing of Landsat data did suggest a smaller size target for further evaluation and thus is useful as an exploration tool

Characterization of primary geochemical haloes for gold exploration at the Huanxiangwa gold deposit, China

NARCIS (Netherlands)

Wang, Changming; Carranza, E.J.M; Zhang, Shouting; Zhang, Jing; Liu, Xiaoji Liu; Zhang, Da; Sun, Xiang; Duan, Cunji

2013-01-01

Recognition of primary geochemical haloes is one of the most important tools for exploring undiscovered mineral resources. This tool is being routinely applied in exploration programs at the Huanxiangwa gold deposit, Xiong'er Mountains, China. Sampling of unweathered rock for multi-element analysis

Geochemical prospecting for uranium and thorium deposits

International Nuclear Information System (INIS)

Boyle, R.W.

1980-01-01

A brief review of analytical geochemical prospecting methods for uranium and thorium is given excluding radiometric techniques, except those utilized in the determination of radon. The indicator (pathfinder) elements useful in geochemical surveys are listed for each of the types of known uranium and thorium deposits; this is followed by sections on analytical geochemical surveys based on rocks (lithochemical surveys), unconsolidated materials (pedochemical surveys), natural waters and sediments (hydrochemical surveys), biological materials (biogeochemical surveys) and gases (atmochemical surveys). All of the analytical geochemical methods are applicable in prospecting for thorium and uranium, particularly where radiometric methods fail due to attenuation by overburden, water, deep leaching and so on. Efficiency in the discovery of uranium and/or thorium orebodies is promoted by an integrated methods approach employing geological pattern recognition in the localization of deposits, analytical geochemical surveys, and radiometric surveys. (author)

Uranium exploration techniques

International Nuclear Information System (INIS)

Nichols, C.E.

1984-01-01

The subject is discussed under the headings: introduction (genetic description of some uranium deposits; typical concentrations of uranium in the natural environment); sedimentary host rocks (sandstones; tabular deposits; roll-front deposits; black shales); metamorphic host rocks (exploration techniques); geologic techniques (alteration features in sandstones; favourable features in metamorphic rocks); geophysical techniques (radiometric surveys; surface vehicle methods; airborne methods; input surveys); geochemical techniques (hydrogeochemistry; petrogeochemistry; stream sediment geochemistry; pedogeochemistry; emanometry; biogeochemistry); geochemical model for roll-front deposits; geologic model for vein-like deposits. (U.K.)

DNA-based methods of geochemical prospecting

Energy Technology Data Exchange (ETDEWEB)

Ashby, Matthew [Mill Valley, CA

2011-12-06

The present invention relates to methods for performing surveys of the genetic diversity of a population. The invention also relates to methods for performing genetic analyses of a population. The invention further relates to methods for the creation of databases comprising the survey information and the databases created by these methods. The invention also relates to methods for analyzing the information to correlate the presence of nucleic acid markers with desired parameters in a sample. These methods have application in the fields of geochemical exploration, agriculture, bioremediation, environmental analysis, clinical microbiology, forensic science and medicine.

Interpretation of aerial gamma-ray surveys - adding the geochemical factors

International Nuclear Information System (INIS)

Dickson, B.L.; Scott, K.M.

1997-01-01

Aerial gamma-ray surveying reflects the geochemical variations of potassium, uranium and thorium in the upper 30 cm of the Earth's surface. This thin layer is subject to the effects of weathering, which leads to loss of K in all rock types and, for felsic rocks, loss of U and Th as well. The extent of the loss depends on many factors, but is typically 20-30 per cent for all three radioelements. Intermediate and basic rocks show little change in radioelement concentrations during initial weathering, but pedogenesis can result in soils with 2-3 times the U and Th content of the parent rock. However, wide ranges in radioelement compositions occur for a given rock type and its weathered products. Mineralizing processes can also affect radioelement contents. For example, K is increased in altered rocks at the Copper Hill and Goonumbla porphyry Cu deposits in central NSW. Thorium concentration shows both depletion and enrichment during hydrothermal alteration, as illustrated by the Au prospects at Bimurra, in northeast Queensland. Uranium is even more erratically affected by alteration and is generally not a useful indicator of alteration. Regolith processes can affect these alteration signatures. Highly weathered deposits may lose their K, particularly if hosted by K-feldspar, as at Goonumbla. Transported soils may disguise or change rock signatures often in unexpected ways. The Mt Leyshon gold deposit, in north Queensland, is seen in the aerial survey as a K-rich area because its signature is not contaminated by material weathered from late-Silurian dolerites. Detailed interpretation of aerial gamma-ray surveys for exploration purposes requires the delineation of the major geological units of the survey area, then examination of the subtle variations within the most prospective units, aided by other data sets and field checking of the anomalous areas identified. 42 refs.,2 tabs., 13 figs

Geochemical reanalysis of historical U.S. Geological Survey sediment samples from the Tonsina area, Valdez Quadrangle, Alaska

Science.gov (United States)

Werdon, Melanie B.; Granitto, Matthew; Azain, Jaime S.

2015-01-01

The State of Alaska’s Strategic and Critical Minerals (SCM) Assessment project, a State-funded Capital Improvement Project (CIP), is designed to evaluate Alaska’s statewide potential for SCM resources. The SCM Assessment is being implemented by the Alaska Division of Geological & Geophysical Surveys (DGGS), and involves obtaining new airborne-geophysical, geological, and geochemical data. As part of the SCM Assessment, thousands of historical geochemical samples from DGGS, U.S. Geological Survey (USGS), and U.S. Bureau of Mines archives are being reanalyzed by DGGS using modern, quantitative, geochemical-analytical methods. The objective is to update the statewide geochemical database to more clearly identify areas in Alaska with SCM potential. The USGS is also undertaking SCM-related geologic studies in Alaska through the federally funded Alaska Critical Minerals cooperative project. DGGS and USGS share the goal of evaluating Alaska’s strategic and critical minerals potential and together created a Letter of Agreement (signed December 2012) and a supplementary Technical Assistance Agreement (#14CMTAA143458) to facilitate the two agencies’ cooperative work. Under these agreements, DGGS contracted the USGS in Denver to reanalyze historical USGS sediment samples from Alaska. For this report, DGGS funded reanalysis of 128 historical USGS sediment samples from the statewide Alaska Geochemical Database Version 2.0 (AGDB2; Granitto and others, 2013). Samples were chosen from the Tonsina area in the Chugach Mountains, Valdez quadrangle, Alaska (fig. 1). The USGS was responsible for sample retrieval from the National Geochemical Sample Archive (NGSA) in Denver, Colorado through the final quality assurance/quality control (QA/QC) of the geochemical analyses obtained through the USGS contract lab. The new geochemical data are published in this report as a coauthored DGGS report, and will be incorporated into the statewide geochemical databases of both agencies

Geochemical surveys in the United States in relation to health

Energy Technology Data Exchange (ETDEWEB)

Tourtelot, H A

1979-12-11

Geochemical surveys in relation to health may be classified as having one, two or three dimensions. One-dimensional surveys examine relations between concentrations of elements such as Pb in soils and other media and burdens of the same elements in humans, at a given time. The spatial distributions of element concentrations are not investigated. The primary objective of two-dimensional surveys is to map the distributions of element concentrations, commonly according to stratified random sampling designs based on either conceptual landscape units or artificial sampling strata, but systematic sampling intervals have also been used. Political units have defined sample areas that coincide with the units used to accumulate epidemiological data. Element concentrations affected by point sources have also been mapped. Background values, location of natural or technological anomalies and the geographic scale of variation for several elements often are determined. Three-dimensional surveys result when two-dimensional surveys are repeated to detect environmental changes.

The 'glass earth' - geochemical frontiers in exploration through cover

International Nuclear Information System (INIS)

Carr, G.; Denton, G.; Giblin, A.; Korsch, M.; Andrew, A.; Whitford, D.

1999-01-01

'Glass Earth' represents a number of current and planned projects within CSIRO aimed at making 'transparent' the top 1000 m of the Earth's crust It builds upon current technologies developed within a number of CSIRO divisions as well as the Australian Mineral Exploration Technologies CRC (AMET CRC), the Australian Geodynamics CRC (AG CRC) and the CRC for Landscape Evolution and Mineral Exploration (CRC LEME). New geophysical and geochemical technologies will be developed to complement these, together with new capabilities in modelling, data integration and visualisation, including hydrogeochemistry, hydrogeology, surface geochemistry and isotope geochemistry, modelling of chemical, fluid and heat flows in rock and regolith, advanced visualisation and data fusion. This paper describes some recent work in the field of isotope geochemistry, with the principal aim of 'seeing through' cover to understand basement geology and detect hidden ore systems

Development of data processing system for regional geophysical and geochemical exploration of sandstone-hosted uranium deposits based on ArcGIS Engine

International Nuclear Information System (INIS)

Han Shaoyang; Ke Dan; Hou Huiqun; Hu Shuiqing

2010-01-01

According to the data processing need of geophysical and geochemical exploration of sandstone-hosted uranium deposits, the function design of the regional geophysical and geochemical data processing system is completed in the paper. The geophysical and geochemical data processing software with powerful functions is also developed based on ArcGIS Engine which remedies the shortage of GIS software for performing the geophysical and geochemical data processing. The development technique route of system software and key techniques are introduced, and the development processes of system software are showed through some development examples. Application practices indicate that the interface of developed system software with friendly interface and utility functions, may quickly perform the data processing of regional geophysical and geochemical exploration and provide the helpful deep information for predicting metallogenic prospective areas of sandstone-hosted uranium deposits. The system software is of a great application foreground. (authors)

Sulfide geochemical survey in Dawahan, Larap, Camarines Norte (Southern Luzon), Philippines

International Nuclear Information System (INIS)

Santos, G. Jr.

1979-07-01

Sulfide geochemical activation analysis survey was conducted in Southern Luzon, Philippines. Trace elements in the rocks of Dawahan, Larap, Camarines Norte, particularly in the sulfide fraction of the rocks were determined and correlated in the search for mineral deposits in the project area. The study has shown that the Cu, V, Co, Pb, Mn, Zn, Ni, Au, Ag and As distributions in Dawahan are log normal with Cu, As and V having an excess of low values. There is a direct relationship between the mineralizations of Ag and Pb with Cu mineralization. Fair geochemical correlations were observed between Cu-Zn, Cu-As and Cu-Co. Low negative or inverse correlation exists between Cu-Mn, Cu-V and Cu-Au. Silver is a good pathfinder for copper deposits in Dawahan and adjacent areas and most probably including the Paracale mining district

Detailed geochemical survey for east-central Minnesota, geology and geochemistry of selected uranium targets

International Nuclear Information System (INIS)

Morey, G.B.; Lively, R.S.

1980-01-01

Results of a detailed geochemical survey of approximately 6820 km 2 in parts of Aitkin, Carlton, Kanabec, and Pine Counties, east-central Minnesota are reported. Geochemical data are presented for 883 groundwater samples and 200 bedrock samples. Although all of the groundwaters in the study area have similar major-element concentrations and therefore presumably a common ancestry, small differences in the minor-element concentrations serve to characterize various aquifers, both in the Quaternary deposits and in the bedrock. All of the aquifers locally yield waters having statistically anomalous concentrations of uranium or radon, but these anomalies are spatially coincident only in a few places and particularly in three geologic environments considered favorable for uranium mineralization. These include the following: (1) Thomson Formation near the unconformably overlying Fond du Lac Formation, (2) Hinckley Sandstone near a major fault system, and (3) Denham Formation near the unconformity with the McGrath Gneiss, particularly where these rocks are faulted and overlain by the Fond du Lac Formation. One additional uranium environment characterized by thin laminae of uraniferous apatite was located in the Thomson Formation during outcrop reconnaissance and sampling. The coincidence of this and other anomalously high uranium values in the bedrock with specific uranium and radon anomalies in the groundwater confirms the usefulness of the hydrogeochemical data to uranium exploration in this glaciated terrane

Neutron activation analysis in reconnaissance geochemical survey of Northwestern Mindoro

International Nuclear Information System (INIS)

Santos, G. Jr.; Fernandez, L.G.

1987-01-01

Instrumental neutron activation analysis (NAA) technique was used to analyze stream sediments collected in Northwestern Mindoro. The concentration levels of 18 elements were determined. It was noted that NAA is suitable for the determination of rare earth, gold, arsenic and cobalt among others because of favorable high neutron cross sections. Samples collected in regional reconnaissance geochemical surveys could be analyzed usng NAA technique to complement other non-nuclear techniques, such as atomic absorption and X-ray fluorescence analysis. (Author). 11 figs.; 2 tabs.; 12 refs

Novel Geochemical Techniques Integrated In Exploration for Uranium Deposits at Depth

International Nuclear Information System (INIS)

Kyser, Kurt

2014-01-01

Recent results in the use of geochemistry in detecting deep uranium deposits: (1) Map element distributions in and around deposits to assess the total chemical environment associated with the deposit, (2) Use element tracing with isotopic compositions in surface media to detect specific components from uranium deposits at depth, (3) Capitalize on element mobility across the geosphere-biosphere interface to enhance exploration using select media, (4) Geochemical data from drill core or surface media can enhance target identification when integrated with geophysical data.

Fluid-rock geochemical interaction for modelling calibration in geothermal exploration in Indonesia

Science.gov (United States)

Deon, Fiorenza; Barnhoorn, Auke; Lievens, Caroline; Ryannugroho, Riskiray; Imaro, Tulus; Bruhn, David; van der Meer, Freek; Hutami, Rizki; Sibarani, Besteba; Sule, Rachmat; Saptadij, Nenny; Hecker, Christoph; Appelt, Oona; Wilke, Franziska

2017-04-01

Indonesia with its large, but partially unexplored geothermal potential is one of the most interesting and suitable places in the world to conduct geothermal exploration research. This study focuses on geothermal exploration based on fluid-rock geochemistry/geomechanics and aims to compile an overview on geochemical data-rock properties from important geothermal fields in Indonesia. The research carried out in the field and in the laboratory is performed in the framework of the GEOCAP cooperation (Geothermal Capacity Building program Indonesia- the Netherlands). The application of petrology and geochemistry accounts to a better understanding of areas where operating power plants exist but also helps in the initial exploration stage of green areas. Because of their relevance and geological setting geothermal fields in Java, Sulawesi and the sedimentary basin of central Sumatra have been chosen as focus areas of this study. Operators, universities and governmental agencies will benefit from this approach as it will be applied also to new green-field terrains. By comparing the characteristic of the fluids, the alteration petrology and the rock geochemistry we also aim to contribute to compile an overview of the geochemistry of the important geothermal fields in Indonesia. At the same time the rock petrology and fluid geochemistry will be used as input data to model the reservoir fluid composition along with T-P parameters with the geochemical workbench PHREEQC. The field and laboratory data are mandatory for both the implementation and validation of the model results.

Geochemical reanalysis of historical U.S. Geological Survey sediment samples from the Zane Hills, Hughes and Shungnak quadrangles, Alaska

Science.gov (United States)

Werdon, Melanie B.; Granitto, Matthew; Azain, Jaime S.

2015-01-01

The State of Alaska’s Strategic and Critical Minerals (SCM) Assessment project, a State-funded Capital Improvement Project (CIP), is designed to evaluate Alaska’s statewide potential for SCM resources. The SCM Assessment is being implemented by the Alaska Division of Geological & Geophysical Surveys (DGGS), and involves obtaining new airborne-geophysical, geological, and geochemical data. As part of the SCM Assessment, thousands of historical geochemical samples from DGGS, U.S. Geological Survey (USGS), and U.S. Bureau of Mines archives are being reanalyzed by DGGS using modern, quantitative, geochemical-analytical methods. The objective is to update the statewide geochemical database to more clearly identify areas in Alaska with SCM potential.The USGS is also undertaking SCM-related geologic studies in Alaska through the federally funded Alaska Critical Minerals cooperative project. DGGS and USGS share the goal of evaluating Alaska’s strategic and critical minerals potential and together created a Letter of Agreement (signed December 2012) and a supplementary Technical Assistance Agreement (#14CMTAA143458) to facilitate the two agencies’ cooperative work. Under these agreements, DGGS contracted the USGS in Denver to reanalyze historical USGS sediment samples from Alaska.For this report, DGGS funded reanalysis of 105 historical USGS sediment samples from the statewide Alaska Geochemical Database Version 2.0 (AGDB2; Granitto and others, 2013). Samples were chosen from the Zane Hills area in the Hughes and Shungnak quadrangles, Alaska (fig. 1). The USGS was responsible for sample retrieval from the National Geochemical Sample Archive (NGSA) in Denver, Colorado through the final quality assurance/quality control (QA/QC) of the geochemical analyses obtained through the USGS contract lab. The new geochemical data are published in this report as a coauthored DGGS report, and will be incorporated into the statewide geochemical databases of both agencies.

Geochemical approach values to the base line (Cu, Cr, Pb, Zn and P) for environmental studies in Montevideo coastal zone

International Nuclear Information System (INIS)

Brugnoli, E.; Burone, L.; Hutton, M.; Tuduri, A.; Bueno, C.; Muniz, P.; Venturini, N.; Garcia-Rodriguez, F.

2012-01-01

The geochemical base line values (background) represent the natural chemical concentrations (heavy metals) in sediments and soils. These are used in archaeological surveys to identify anomalies, and environmental studies of contaminated areas. In Montevideo coastal zone are explored the base line values for geochemical application and enrichment index

Stream sediment detailed geochemical survey for Marysvale, Utah

International Nuclear Information System (INIS)

Butz, T.R.; Vreeland, J.L.; Bard, C.S.; Helgerson, R.N.; Grimes, J.G.; Pritz, P.M.

1980-01-01

Results of the Marysvale detailed geochemical survey are reported. Field and laboratory data are presented for 397 stream sediment samples and 160 radiometric readings. Statistical and areal distributions of uranium and possible uranium-related variables are displayed. A generalized geologic map of the area is provided, and pertinent geologic factors which may be of significance in evaluating the potential for uranium mineralization are briefly discussed. Stream sediments containing significant amounts of soluble uranium (greater than or equal to 16.93 ppM) occur in numerous areas, the most prevalent being in the western portion of the survey area, within and surrounding the Mount Belknap Caldera. Thorium, beryllium, cerium, manganese, molybdenum, niobium, potassium, yttrium, zinc, and zirconium occur in concentrations greater than or equal to 84th percentile in many sediment samples taken from within and surrounding the Mount Belknap Caldera. The uranium and related variables are associated with highly silicic intrusions and extrusions of the Mount Belknap Volcanics, as well as hydrothermal activity which has occurred in the Marysvale volcanic field

Applications of inductively coupled plasma spectroscopy to geochemical reconnaissance for uranium exploration

International Nuclear Information System (INIS)

Cagle, G.W.; Butz, T.R.

1980-01-01

The analysis of large numbers of natural groundwater and stream sediment samples by Inductively Coupled Plasma (ICP) Spectroscopy has been applied to a geochemical reconnaissance program as part of the National Uranium Resource Evaluation Program. Approximately 25 elements have been determined in over 60,000 samples by ICP analysis. These data are combined with additional measurements obtained by atomic absorption, colorimetry, neutron activation, and fluorescence spectroscopy. Results are presented and interpreted in terms of the uranium favorability of areas in Texas where this survey has been completed

Geological, geochemical, and geophysical survey of the geothermal resources at Hot Springs Bay Valley, Akutan Island, Alaska

Energy Technology Data Exchange (ETDEWEB)

Motyka, R.J.; Wescott, E.M.; Turner, D.L.; Swanson, S.E.; Romick, J.D.; Moorman, M.A.; Poreda, R.J.; Witte, W.; Petzinger, B.; Allely, R.D.

1985-01-01

An extensive survey was conducted of the geothermal resource potential of Hot Springs Bay Valley on Akutan Island. A topographic base map was constructed, geologic mapping, geophysical and geochemical surveys were conducted, and the thermal waters and fumarolic gases were analyzed for major and minor element species and stable isotope composition. (ACR)

Geochemical prospecting for thorium and uranium deposits

International Nuclear Information System (INIS)

Boyle, R.W.

1982-01-01

The basic purpose of this book is to present an analysis of the various geochemical methods applicable in the search for all types of thorium and uranium deposits. The general chemistry and geochemistry of thorium and uranium are briefly described in the opening chapter, and this is followed by a chapter on the deposits of the two elements with emphasis on their indicator (pathfinder) elements and on the primary and secondary dispersion characteristics of thorium and uranium in the vicinity of their deposits. The next seven chapters form the main part of the book and describe geochemical prospecting for thorium and uranium, stressing selection of areas in which to prospect, radiometric surveys, analytical geochemical surveys based on rocks (lithochemical surveys), unconsolidated materials (pedochemical surveys), natural waters and sediments (hydrochemical surveys), biological materials (biogeochemical surveys), gases (atmochemical surveys), and miscellaneous methods. A final brief chapter reviews radiometric and analytical methods for the detection and estimation of thorium and uranium. (Auth.)

A national-scale geochemical and mineralogical survey of soils of the conterminous United States

International Nuclear Information System (INIS)

Smith, David B.; Cannon, William F.; Woodruff, Laurel G.

2011-01-01

Highlights: → Sampling for national-scale soil geochemical and mineralogical survey completed for conterminous USA. → Natural variation for most elements is approximately three orders of magnitude. → Composition of soil parent material is the major controlling factor. → Climate (average annual precipitation) is also an important controlling factor for some elements. → Sample archive (4800 sites) available for future investigations. - Abstract: In 2007, the US Geological Survey initiated a low-density (1 site per 1600 km 2 , c. 4800 sites) geochemical and mineralogical survey of soils of the conterminous USA. The ideal sampling protocol at each site includes a sample from 0-5 cm depth, a composite of the soil A horizon, and a sample from the soil C horizon. The 3 , HClO 4 and HF. Separate methods are used for As, Hg, Se and total C on this same size fraction. The major mineralogical components are determined by a quantitative X-ray diffraction method. Sampling was completed in 2010 with chemical and mineralogical analysis currently underway. Preliminary results for a swath from the central USA to Florida clearly show the effects of soil parent material and climate on the chemical and mineralogical composition of soils. A sample archive will be established and made available for future investigations.

Geochemical reanalysis of historical U.S. Geological Survey sediment samples from the Kougarok area, Bendeleben and Teller quadrangles, Seward Peninsula, Alaska

Science.gov (United States)

Werdon, Melanie B.; Granitto, Matthew; Azain, Jaime S.

2015-01-01

The State of Alaska’s Strategic and Critical Minerals (SCM) Assessment project, a State-funded Capital Improvement Project (CIP), is designed to evaluate Alaska’s statewide potential for SCM resources. The SCM Assessment is being implemented by the Alaska Division of Geological & Geophysical Surveys (DGGS), and involves obtaining new airborne-geophysical, geological, and geochemical data. As part of the SCM Assessment, thousands of historical geochemical samples from DGGS, U.S. Geological Survey (USGS), and U.S. Bureau of Mines archives are being reanalyzed by DGGS using modern, quantitative, geochemical-analytical methods. The objective is to update the statewide geochemical database to more clearly identify areas in Alaska with SCM potential. The USGS is also undertaking SCM-related geologic studies in Alaska through the federally funded Alaska Critical Minerals cooperative project. DGGS and USGS share the goal of evaluating Alaska’s strategic and critical minerals potential and together created a Letter of Agreement (signed December 2012) and a supplementary Technical Assistance Agreement (#14CMTAA143458) to facilitate the two agencies’ cooperative work. Under these agreements, DGGS contracted the USGS in Denver to reanalyze historical USGS sediment samples from Alaska. For this report, DGGS funded reanalysis of 302 historical USGS sediment samples from the statewide Alaska Geochemical Database Version 2.0 (AGDB2; Granitto and others, 2013). Samples were chosen from the Kougarok River drainage as well as smaller adjacent drainages in the Bendeleben and Teller quadrangles, Seward Peninsula, Alaska (fig. 1). The USGS was responsible for sample retrieval from the National Geochemical Sample Archive (NGSA) in Denver, Colorado through the final quality assurance/quality control (QA/QC) of the geochemical analyses obtained through the USGS contract lab. The new geochemical data are published in this report as a coauthored DGGS report, and will be incorporated

The outlier sample effects on multivariate statistical data processing geochemical stream sediment survey (Moghangegh region, North West of Iran)

International Nuclear Information System (INIS)

Ghanbari, Y.; Habibnia, A.; Memar, A.

2009-01-01

In geochemical stream sediment surveys in Moghangegh Region in north west of Iran, sheet 1:50,000, 152 samples were collected and after the analyze and processing of data, it revealed that Yb, Sc, Ni, Li, Eu, Cd, Co, as contents in one sample is far higher than other samples. After detecting this sample as an outlier sample, the effect of this sample on multivariate statistical data processing for destructive effects of outlier sample in geochemical exploration was investigated. Pearson and Spear man correlation coefficient methods and cluster analysis were used for multivariate studies and the scatter plot of some elements together the regression profiles are given in case of 152 and 151 samples and the results are compared. After investigation of multivariate statistical data processing results, it was realized that results of existence of outlier samples may appear as the following relations between elements: - true relation between two elements, which have no outlier frequency in the outlier sample. - false relation between two elements which one of them has outlier frequency in the outlier sample. - complete false relation between two elements which both have outlier frequency in the outlier sample

Geochemical reanalysis of historical U.S. Geological Survey sediment samples from the Haines area, Juneau and Skagway quadrangles, southeast Alaska

Science.gov (United States)

Werdon, Melanie B.; Granitto, Matthew; Azain, Jaime S.

2015-01-01

The State of Alaska’s Strategic and Critical Minerals (SCM) Assessment project, a State-funded Capital Improvement Project (CIP), is designed to evaluate Alaska’s statewide potential for SCM resources. The SCM Assessment is being implemented by the Alaska Division of Geological & Geophysical Surveys (DGGS), and involves obtaining new airborne-geophysical, geological, and geochemical data. As part of the SCM Assessment, thousands of historical geochemical samples from DGGS, U.S. Geological Survey (USGS), and U.S. Bureau of Mines archives are being reanalyzed by DGGS using modern, quantitative, geochemical-analytical methods. The objective is to update the statewide geochemical database to more clearly identify areas in Alaska with SCM potential. The USGS is also undertaking SCM-related geologic studies in Alaska through the federally funded Alaska Critical Minerals cooperative project. DGGS and USGS share the goal of evaluating Alaska’s strategic and critical minerals potential and together created a Letter of Agreement (signed December 2012) and a supplementary Technical Assistance Agreement (#14CMTAA143458) to facilitate the two agencies’ cooperative work. Under these agreements, DGGS contracted the USGS in Denver to reanalyze historical USGS sediment samples from Alaska. For this report, DGGS funded reanalysis of 212 historical USGS sediment samples from the statewide Alaska Geochemical Database Version 2.0 (AGDB2; Granitto and others, 2013). Samples were chosen from the Chilkat, Klehini, Tsirku, and Takhin river drainages, as well as smaller drainages flowing into Chilkat and Chilkoot Inlets near Haines, Skagway Quadrangle, Southeast Alaska. Additionally some samples were also chosen from the Juneau gold belt, Juneau Quadrangle, Southeast Alaska (fig. 1). The USGS was responsible for sample retrieval from the National Geochemical Sample Archive (NGSA) in Denver, Colorado through the final quality assurance/quality control (QA/QC) of the geochemical

Hydrogeochemical and stream sediment detailed geochemical survey for Trans-Pecos, Texas. Solitario survey area

International Nuclear Information System (INIS)

Butz, T.R.; Payne, A.G.; Grimes, J.G.; Helgerson, R.N.; Bard, C.S.

1979-01-01

Results of the Solitario survey area portion of the detailed geochemical survey for Trans-Pecos, Texas are reported. Field and laboratory data are presented for 119 groundwater and 520 stream sediment samples. Statistical and areal distributions of uranium and possible uranium-related variables are given. A generalized geologic map of the survey area is provided, and pertinent geologic factors which may be of significance in evaluating the potential for uranium mineralization are breifly discussed. Groundwaters having concentrations of uranium greater than or equal to 11.5 ppB are observed in the western half of the survey area. These wells generally produce from the Chisos Formation and Buck Hill Volcanic Series or alluvium derived from these units. Lithium, sodium, boron, uranium/specific conductance, uranium/boron, and uranium/sulfate are noted to be most highly associated within the area of anomalously high uranium. The highest potential for uranium mineralization, in view of these groundwater data, lies in the LaVuida and Bandera Mesa areas. Stream sediments containing greater than or equal to 2.57 ppM soluble uranium occur in numerous areas within the survey area. The highest concentrations of uranium occur in sediments derived from the Buck Hill Volcanic Series and Cretaceous limestones. Above background concentrations of arsenic, selenium, molybdenum, nickel, calcium, and strontium were noted to be associated with areas of anomalously high uranium. These elements are most prominently associated with uranium anomalies occurring in Cretaceous limestone

Comparison of U-spatial statistics and C-A fractal models for delineating anomaly patterns of porphyry-type Cu geochemical signatures in the Varzaghan district, NW Iran

Science.gov (United States)

Ghezelbash, Reza; Maghsoudi, Abbas

2018-05-01

The delineation of populations of stream sediment geochemical data is a crucial task in regional exploration surveys. In this contribution, uni-element stream sediment geochemical data of Cu, Au, Mo, and Bi have been subjected to two reliable anomaly-background separation methods, namely, the concentration-area (C-A) fractal and the U-spatial statistics methods to separate geochemical anomalies related to porphyry-type Cu mineralization in northwest Iran. The quantitative comparison of the delineated geochemical populations using the modified success-rate curves revealed the superiority of the U-spatial statistics method over the fractal model. Moreover, geochemical maps of investigated elements revealed strongly positive correlations between strong anomalies and Oligocene-Miocene intrusions in the study area. Therefore, follow-up exploration programs should focus on these areas.

Geochemical soil sampling for deeply-buried mineralized breccia pipes, northwestern Arizona

Science.gov (United States)

Wenrich, K.J.; Aumente-Modreski, R. M.

1994-01-01

degree of anomalousness, named the "correlation value", was used to rank collapse features by their potential to overlie a deeply-buried mineralized breccia pipe. Soil geochemical results from the three mineralized breccia pipes (the only three of the 50 that had previously been drilled) show that: (1) Soils above the SBF pipe contain significant enrichment of Ag, Al, As, Ba, Ga, K, La, Mo, Nd, Ni, Pb, Sc, Th, U and Zn, and depletion in Ca, Mg and Sr, in contrast to soils outside the topographic and structural rim; (2) Soils over the inner treeless zone of the Canyon pipe show Mo and Pb enrichment anf As and Ga depletion, in contrast to soils from the surrounding forest; and (3) The soil survey of the Mohawk Canyon pipe was a failure because of the rocky terrane and lack of a B soil horizon, or because the pipe plunges. At least 11 of the 47 other collapse structures studied contain anomalous soil enrichments similar to the SBF uranium ore-bearing pipe, and thus have good potential as exploration targets for uranium. One of these 11, #1102, does contain surface mineralized rock. These surveys suggest that soil geochemical sampling is a useful tool for the recognition of many collapse structures with underlying ore-bearing breccia pipes. ?? 1994.

Geochemical and geophysical investigations, and fluid inclusion studies in the exploration area of Zafarghand (Northeast Isfahan, Iran

Directory of Open Access Journals (Sweden)

Zahra Alaminia

2017-11-01

Full Text Available Introduction Urumieh-Dokhtar Magmatic Arc (UDMA is a good prospective area for Cu, Cu-Mo and Cu-Au deposits (Fig. 1A and B. The Zafarghand district is located in the central part of the UDMA and the northeastern Isfahan. The present study concerns geological observations, alteration investigations, geochemical data and fluid inclusion studies. The purpose of the research is to identify geochemical anomalies and source of metals in this area. Geochemical anomalies for mineralizing elements and element associations were identified by using statistical analysis methods. Additionally, these results together suggest a site for exploration drilling in this study area. Materials and methods We collected 186 samples (rock along multi-cross sections oriented perpendicular to the strike of the South -Ardestan fault (Fig. 2.Trace element concentrations were determined by the ICP-MS technique in Amdel laboratory (Australia. Thin sections and doubly polished sections (100–200 µm thick from quartz veins were prepared from samples collected from the Zafarghand district in the University of Isfahan. Heating and freezing experiments on fluid inclusions were performed as defined (by Goldstein and Reynolds (1994 on a Linkam THM600 stage. Results Igneous rocks in the Zafarghand area are dominated by the Eocene and post Eocene acidic-intermediate rocks that include dacite, rhyodacite and andesite associated with diorite, quartz diorite and microdiorite intrusions. The present investigations indicate that all rocks of the Zafarghand district exhibit a variety of alterations. Hydrothermal alterations include phyllic, potassic, silicification, and argillic with widespread propylitic. The mineralization consists of malachite, azurite, hematite, and goethite, rare amounts of magnetite, pyrite, and chalcopyrite. Numerical traditional statistical analysis techniques have been applied to interpret the geochemical data of the study area. These methods are aimed at

Hydrogeochemical and stream sediment detailed geochemical survey for Trans-Pecos, Texas. Tascotal survey area

International Nuclear Information System (INIS)

Butz, T.R.; Payne, A.G.; Grimes, J.G.; Helgerson, R.N.; Bard, C.S.

1979-01-01

Results of the Tascotal survey area portion of the detailed geochemical survey for Trans-Pecos, Texas are reported. Field and laboratory data are presented for 337 groundwater and 611 stream sediment samples. Statistical and areal distributions of uranium and possible uranium-related variables are given. A generalized geologic map of the survey area is provided, and pertinent geologic factors which may be of significance in evaluating the potential for uranium mineralization are briefly discussed. Groundwaters containing greater than or equal to 80.0 ppB uranium were detected in three areas largely producing from acidic volcanoclastics in the south central portion of the survey area. High specific conductance and an association of lithium, selenium, and sodium were observed in these areas of anomalously high uranium. High uranium/specific conductance, uranium/boron, and uranium/sulfate ratios are also associated with areas of the highest uranium concentrations. Alkalinities in these areas were noted to be highly variable over short distances within the same hydrologic unit. Stream sediments containing greater than or equal to 2.57 ppM soluble uranium are located in the southwestern and the north and south central portions of the survey area. High U-FL/U-NT and low thorium/U-NT values are observed with sediments derived from acidic volcanics in the southern portions of the survey area. In areas of anomalously high uranium, an association of above background concentrations of thorium, lithium, potassium, beryllium, and zirconium were noted. In view of these data, areas containing the Buck Hill Volcanic Series, the Mitchell Mesa, and Tascotal Formations provide the best possibilities of an economical uranium deposit

A stream sediment geochemical survey of the Ganga River headwaters in the Garhwal Himalaya

Science.gov (United States)

Mukherjee, P.K.; Purohit, K.K.; Saini, N.K.; Khanna, P.P.; Rathi, M.S.; Grosz, A.E.

2007-01-01

This study models geochemical and adjunct geologic data to define provinces that are favorable for radioactive-mineral exploration. A multi-element bed-sediment geochemical survey of streams was carried out in the headwaters region of the Ganga River in northern India. Overall median values for uranium and thorium (3.6 and 13.8 ppm; maxima of 4.8 and 19.0 ppm and minima of 3.1 and 12.3 ppm respectively) exceed average upper crustal abundances (2.8 and 10.7 ppm) for these radioactive elements. Anomalously high values reach up to 8.3 and 30.1 ppm in thrust zone rocks, and 11.4 and 22.5 ppm in porphyroids. At their maxima, these abundances are nearly four- and three-fold (respectively) enriched in comparison to average crustal abundances for these rock types. Deformed, metamorphosed and sheared rocks are characteristic of the main central thrust zone (MCTZ). These intensively mylonitized rocks override and juxtapose porphyritic (PH) and proterozoic metasedimentary rock sequences (PMS) to the south. Granitoid rocks, the major protoliths for mylonites, as well as metamorphosed rocks in the MCT zone are naturally enriched in radioelements; high values associated with sheared and mylonitized zones are coincident with reports of radioelement mineralization and with anomalous radon concentrations in soils. The radioelement abundance as well as REE abundance shows a northward enrichment trend consistent with increasing grade of metamorphism indicating deformation-induced remobilization of these elements. U and Th illustrate good correlation with REEs but not with Zr. This implies that zircon is not a principal carrier of U and Th within the granitoid-dominant thrust zone and that other radioelement-rich secondary minerals are present in considerable amounts. Thus, the relatively flat, less fractionated, HREE trend is also not entirely controlled by zircon. The spatial correlation of geologic boundary zones (faults, sheared zones) with geochemical and with geophysical (Rn

Comprehensive geophysical and geochemical method and prognosis criteria for the exploration of unconformity type uranium deposit in Russia

International Nuclear Information System (INIS)

Li Mao; Chen Zuyi

2007-01-01

According to the transcripts of the lectures by Russian experts during the investigation and training in Russia, the comprehensive geophysical and geochemical method and the prognosis criteria of Russia's unconformity type uranium deposit exploration are introduced in the paper. (authors)

Geochemical reanalysis of historical U.S. Geological Survey sediment samples from the northeastern Alaska Range, Healy, Mount Hayes, Nabesna, and Tanacross quadrangles, Alaska

Science.gov (United States)

Werdon, Melanie B.; Granitto, Matthew; Azain, Jaime S.

2015-01-01

The State of Alaska’s Strategic and Critical Minerals (SCM) Assessment project, a State-funded Capital Improvement Project (CIP), is designed to evaluate Alaska’s statewide potential for SCM resources. The SCM Assessment is being implemented by the Alaska Division of Geological & Geophysical Surveys (DGGS), and involves obtaining new airborne-geophysical, geological, and geochemical data. As part of the SCM Assessment, thousands of historical geochemical samples from DGGS, U.S. Geological Survey (USGS), and U.S. Bureau of Mines archives are being reanalyzed by DGGS using modern, quantitative, geochemical-analytical methods. The objective is to update the statewide geochemical database to more clearly identify areas in Alaska with SCM potential. The USGS is also undertaking SCM-related geologic studies in Alaska through the federally funded Alaska Critical Minerals cooperative project. DGGS and USGS share the goal of evaluating Alaska’s strategic and critical minerals potential and together created a Letter of Agreement (signed December 2012) and a supplementary Technical Assistance Agreement (#14CMTAA143458) to facilitate the two agencies’ cooperative work. Under these agreements, DGGS contracted the USGS in Denver to reanalyze historical USGS sediment samples from Alaska. For this report, DGGS funded reanalysis of 670 historical USGS sediment samples from the statewide Alaska Geochemical Database Version 2.0 (AGDB2; Granitto and others, 2013). Samples were chosen from the northeastern Alaska Range, in the Healy, Mount Hayes, Nabesna, and Tanacross quadrangles, Alaska (fig. 1). The USGS was responsible for sample retrieval from the National Geochemical Sample Archive (NGSA) in Denver, Colorado through the final quality assurance/quality control (QA/QC) of the geochemical analyses obtained through the USGS contract lab. The new geochemical data are published in this report as a coauthored DGGS report, and will be incorporated into the statewide geochemical

Methods for geochemical analysis

Science.gov (United States)

Baedecker, Philip A.

1987-01-01

The laboratories for analytical chemistry within the Geologic Division of the U.S. Geological Survey are administered by the Office of Mineral Resources. The laboratory analysts provide analytical support to those programs of the Geologic Division that require chemical information and conduct basic research in analytical and geochemical areas vital to the furtherance of Division program goals. Laboratories for research and geochemical analysis are maintained at the three major centers in Reston, Virginia, Denver, Colorado, and Menlo Park, California. The Division has an expertise in a broad spectrum of analytical techniques, and the analytical research is designed to advance the state of the art of existing techniques and to develop new methods of analysis in response to special problems in geochemical analysis. The geochemical research and analytical results are applied to the solution of fundamental geochemical problems relating to the origin of mineral deposits and fossil fuels, as well as to studies relating to the distribution of elements in varied geologic systems, the mechanisms by which they are transported, and their impact on the environment.

Blind Geothermal System Exploration in Active Volcanic Environments; Multi-phase Geophysical and Geochemical Surveys in Overt and Subtle Volcanic Systems, Hawai’i and Maui

Energy Technology Data Exchange (ETDEWEB)

Fercho, Steven [Ormat Nevada, Inc., Reno, NV (United States); Owens, Lara [Ormat Nevada, Inc., Reno, NV (United States); Walsh, Patrick [Ormat Nevada, Inc., Reno, NV (United States); Drakos, Peter [Ormat Nevada, Inc., Reno, NV (United States); Martini, Brigette [Corescan Inc., Ascot (Australia); Lewicki, Jennifer L. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Kennedy, Burton M. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

2015-08-01

Suites of new geophysical and geochemical exploration surveys were conducted to provide evidence for geothermal resource at the Haleakala Southwest Rift Zone (HSWRZ) on Maui Island, Hawai’i. Ground-based gravity (~400 stations) coupled with heli-bourne magnetics (~1500 line kilometers) define both deep and shallow fractures/faults, while also delineating potentially widespread subsurface hydrothermal alteration on the lower flanks (below approximately 1800 feet a.s.l.). Multi-level, upward continuation calculations and 2-D gravity and magnetic modeling provide information on source depths, but lack of lithologic information leaves ambiguity in the estimates. Additionally, several well-defined gravity lows (possibly vent zones) lie coincident with magnetic highs suggesting the presence of dike intrusions at depth which may represent a potentially young source of heat. Soil CO2 fluxes were measured along transects across geophysically-defined faults and fractures as well as young cinder cones along the HSWRZ. This survey generally did not detect CO2 levels above background, with the exception of a weak anomalous flux signal over one young cinder cone. The general lack of observed CO2 flux signals on the HSWRZ is likely due to a combination of lower magmatic CO2 fluxes and relatively high biogenic surface CO2 fluxes which mix with the magmatic signal. Similar surveys at the Puna geothermal field on the Kilauea Lower East Rift Zone (KLERZ) also showed a lack of surface CO2 flux signals, however aqueous geochemistry indicated contribution of magmatic CO2 and He to shallow groundwater here. As magma has been intercepted in geothermal drilling at the Puna field, the lack of measured surface CO2 flux indicative of upflow of magmatic fluids here is likely due to effective “scrubbing” by high groundwater and a mature hydrothermal system. Dissolved inorganic carbon (DIC) concentrations, δ13C compositions and 3He/4He values were sampled at Maui from several shallow

Chemical elements in the environment: multi-element geochemical datasets from continental to national scale surveys on four continents

Science.gov (United States)

Caritat, Patrice de; Reimann, Clemens; Smith, David; Wang, Xueqiu

2017-01-01

During the last 10-20 years, Geological Surveys around the world have undertaken a major effort towards delivering fully harmonized and tightly quality-controlled low-density multi-element soil geochemical maps and datasets of vast regions including up to whole continents. Concentrations of between 45 and 60 elements commonly have been determined in a variety of different regolith types (e.g., sediment, soil). The multi-element datasets are published as complete geochemical atlases and made available to the general public. Several other geochemical datasets covering smaller areas but generally at a higher spatial density are also available. These datasets may, however, not be found by superficial internet-based searches because the elements are not mentioned individually either in the title or in the keyword lists of the original references. This publication attempts to increase the visibility and discoverability of these fundamental background datasets covering large areas up to whole continents.

Review of the use of magnetic concentrates in geochemical exploration

Science.gov (United States)

Overstreet, W.C.; Day, G.W.

1985-01-01

Magnetic concentrates recovered readily by hand magnet from alluvial sediments or panned concentrates have been used successfully in exploration as a geochemical sample medium for Cu, Zn, Co, Cr, Mo, Ni, V, Sn, and Be, particularly in arid environments where alluvial sediments may be contaminated by aeolian debris. Opportunity for this use arose recently as chemical and spectrographic techniques were developed to determine the abundances of a variety of trace elements in Fe-rich media. The use of analytical data from magnetic concentrates was introduced as one of several anomaly-enhancement techniques based on heavy minerals and intended to identify blind ore deposits. An extensive literature, reviewed here, on the relation of the chemical composition of the mineral magnetite, a main component of magnetic concentrates, to geologic conditions of origin, facilitates the interpretation of trace-element data in the context of association with ore deposits.

Geochemical Survey of Pernambuco

International Nuclear Information System (INIS)

Horowitz, A.; Duarte, P.J.; Almeida, M.G. de; Medeiros, M.O.

1988-01-01

The area studied i this work is located in a triangle formed by the Sibiro and Boca da Mata Sugar-Mills and Serinhaem country. In the Cabo Formation the search determinated conglomerates, arcos and clays. Although the highest geochemical activity have been done in the decomposed crystalin, and the values from Cabo Formation don't be encourager, this formation has lithology compatible with uranium mineralization. The Cabo Formation's sediments presents lithologic variations very expressives, with conglomerates, arcoses and clay silts, which determinate the choise of the area. This area presented favorable to uranium prospecting and to others elements interesting to ragional geochemistry. The atomic absorption analysis, fluorimetry and spectrometry were done for the following elements: Zn, V, Ti, Ni, Pb, Mn, Ga, Cu, Co, Bi, Ag, B, Mo, and U. (C.D.G.) [pt

Research on the exploration and use of geothermal energy in Austria

Energy Technology Data Exchange (ETDEWEB)

1976-01-01

The current status of geothermal exploration and utilization in Austria is reviewed. Geological characteristics of geothermal fields are discussed in general, as are exploration techniques including geological surveys, geophysical surveys, remote sensing, geochemical surveys, and test drilling. The geology of Austria is described in detail, and the economic and legal problems peculiar to Austria are discussed. Certain regions may be suitable for geothermal exploitation including the Vienna basin. Research and economic recommendations are made. Three figures one table, and thirty references are provided.

Hydrogeochemical and stream sediment detailed geochemical survey for Trans-Peco, Texas. Sierra Vieja survey area

International Nuclear Information System (INIS)

Butz, T.R.; Payne, A.G.; Grimes, J.G.; Helgerson, R.N.; Bard, C.S.

1979-01-01

Results of the Sierra Vieja survey area of the detailed geochemical survey for Trans-Pecos, Texas are reported. Field and laboratory data are presented for 29 groundwater and 240 stream sediment samples. Statistical and areal distributions of uranium and possible uranium-related variables are given. A generalized geologic map of the survey area is provided, and pertinent geologic factors which may be of significance in evaluating the potential for uranium mineralization are briefly discussed. Highest concentrations of uranium in groundwater predominantly occur in areas marginal to the Rio Grande. These wells and spring produce from Quaternary alluvium or the Vieja Group. High specific conductance is also associated with most of the wells located marginal to the Rio Grande. The specific conductance of wells in other areas with greater than or equal to 11.5 ppB uranium are notably lower. Higher than background concentrations of molybdenum, arsenic, and vanadium are observed with wells containing greater than or equal to 11.5 ppB uranium. Total alkalinity and pH display a variable distribution throughout the survey area. Stream sediment from several areas contain greater than or equal to 2.57 soluble uranium. In areas where these concentrations account for greater than or equal to 83% of the uranium present in the sediment, above background concentrations of sodium, aluminum, barium, potassium, zirconium, cerium, and strontium are detected. The degree to which these elements are associated with favorably high uranium concentrations is related to the relative amounts of volcaniclastic and calcareous sedimentary material incorporated in the sample

Role of geochemical background at evaluation of investment attractiveness of recreational territories

Directory of Open Access Journals (Sweden)

Vdovina Ol'ga Konstantinovna

2014-09-01

Full Text Available The article shows the role of natural geochemical background when estimating investment attractiveness of recreational areas. It is noted, that geochemical background influence on people's sickness rate isn't considered now. Though it's understood, that even insignificant increase of geochemical background in relation to percentage abundance of Earth crest may lead to endemic diseases of people, animals and plants. An indicator of geochemical endemicity areas was proposed for assessing the impact of storage elements and of a lack of geological environment on human health. Thanks to this measure, and taking into account landscape features of the area, the authors allocated lands, dangerous and potentially dangerous in terms of endemicity. The importance of ratings was achieved by the use of those factors that could have a great influence on the cost of land development. This includes, first of all, the factors that affect population health, and economic and geographic factors that minimize the cost of the territory development and the factors that give rise to financial risks and risks of human losses. The main risk factors include: potential ecological and geochemical risk; high absolute heights, development and activity of dangerous geological processes and phenomena. Systemacity of researches was reached by using factors, that characterize the object from different aspects; readiness of area infrastructure to its exploration and possible risks. Objectivity was achieved by the use of figures obtained from the results of geochemical and engineering surveys with their metrological support.

Geochemical surface exploration between Bueckeberge Hills and Rehburg Anticline (Lower Saxony Basin, Germany)

Energy Technology Data Exchange (ETDEWEB)

Berner, U. [Bundesanstalt fuer Geowissenschaften und Rohstoffe, Hannover (Germany); Marquardt, D. [Rijksuniversiteit Utrecht (Netherlands)

2013-01-15

The Lower Saxony Basin (LSB) of northwestern Germany is since long a target in hydrocarbon-related research in which the organic-rich Wealden sediments, known to contain good to excellent source rocks, play an important role. We demonstrate that cost effective surface exploration and geochemical research provide significant insight into the petroleum geology of an area of interest. Our research concentrates on a sub-basin in the eastern part of the LSB and aims at assessing the petroleum geology, hydrocarbon potential, depositional environment and tectonics of the Stadthagen syncline using surface samples of Wealden outcrops and evaluating these subsequently with geochemical methods (XRF, total sulfur, total organic carbon, Rock-Eval pyrolysis) and physical property data. The depositional environment in the research area varied significantly throughout the Lower Cretaceous (oxic to anoxic) due to paleoclimate changes and tectonically induced marine ingressions. Microbial sulfate reduction related to the marine ingressions reduced organic matter quality in the basin significantly, supporting the strong vertical variability in hydrocarbon potential of the sediments. Thermal maturity data suggests a complex tectonic history for the Stadthagen syncline. Thermal maturities (oil to wet gas window) combined with a multi-heat flow scenario result in estimated burial and subsequent uplift in the region of more than 2500 m. (orig.)

Hydrogeochemical and stream sediment detailed geochemical survey for Edgemont, South Dakota; Wyoming

Energy Technology Data Exchange (ETDEWEB)

Butz, T.R.; Dean, N.E.; Bard, C.S.; Helgerson, R.N.; Grimes, J.G.; Pritz, P.M.

1980-05-31

Results of the Edgemont detailed geochemical survey are reported. Field and laboratory data are presented for 109 groundwater and 419 stream sediment samples. Statistical and areal distributions of uranium and possible uranium-related variables are given. A generalized geologic map of the survey area is provided, and pertinent geologic factors which may be of significance in evaluating the potential for uranium mineralization are briefly discussed. Groundwaters containing greater than or equal to 7.35 ppB uranium are present in scattered clusters throughout the area sampled. Most of these groundwaters are from wells drilled where the Inyan Kara Group is exposed at the surface. The exceptions are a group of samples in the northwestern part of the area sampled and south of the Dewey Terrace. These groundwaters are also produced from the Inyan Kara Group where it is overlain by the Graneros Group and alluvium. The high uranium groundwaters along and to the south of the terrace are characterized by high molybdenum, uranium/specific conductance, and uranium/sulfate values. Many of the groundwaters sampled along the outcrop of the Inyan Kara Group are near uranium mines. Groundwaters have high amounts of uranium and molybdenum. Samples taken downdip are sulfide waters with low values of uranium and high values of arsenic, molybdenum, selenium, and vanadium. Stream sediments containing greater than or equal to 5.50 ppM soluble uranium are concentrated in basins draining the Graneros and Inyan Kara Groups. These values are associated with high values for arsenic, selenium, and vanadium in samples from both groups. Anomalous values for these elements in the Graneros Group may be caused by bentonite beds contained in the rock units. As shown on the geochemical distribution plot, high uranium values that are located in the Inyan Kara Group are almost exclusively draining open-pit uranium mines.

Hydrogeochemical and stream sediment detailed geochemical survey for Edgemont, South Dakota; Wyoming

International Nuclear Information System (INIS)

Butz, T.R.; Dean, N.E.; Bard, C.S.; Helgerson, R.N.; Grimes, J.G.; Pritz, P.M.

1980-01-01

Results of the Edgemont detailed geochemical survey are reported. Field and laboratory data are presented for 109 groundwater and 419 stream sediment samples. Statistical and areal distributions of uranium and possible uranium-related variables are given. A generalized geologic map of the survey area is provided, and pertinent geologic factors which may be of significance in evaluating the potential for uranium mineralization are briefly discussed. Groundwaters containing greater than or equal to 7.35 ppB uranium are present in scattered clusters throughout the area sampled. Most of these groundwaters are from wells drilled where the Inyan Kara Group is exposed at the surface. The exceptions are a group of samples in the northwestern part of the area sampled and south of the Dewey Terrace. These groundwaters are also produced from the Inyan Kara Group where it is overlain by the Graneros Group and alluvium. The high uranium groundwaters along and to the south of the terrace are characterized by high molybdenum, uranium/specific conductance, and uranium/sulfate values. Many of the groundwaters sampled along the outcrop of the Inyan Kara Group are near uranium mines. Groundwaters have high amounts of uranium and molybdenum. Samples taken downdip are sulfide waters with low values of uranium and high values of arsenic, molybdenum, selenium, and vanadium. Stream sediments containing greater than or equal to 5.50 ppM soluble uranium are concentrated in basins draining the Graneros and Inyan Kara Groups. These values are associated with high values for arsenic, selenium, and vanadium in samples from both groups. Anomalous values for these elements in the Graneros Group may be caused by bentonite beds contained in the rock units. As shown on the geochemical distribution plot, high uranium values that are located in the Inyan Kara Group are almost exclusively draining open-pit uranium mines

Geochemical surveys in the Lusi mud eruption

Science.gov (United States)

Sciarra, Alessandra; Mazzini, Adriano; Etiope, Giuseppe; Inguaggiato, Salvatore; Hussein, Alwi; Hadi J., Soffian

2016-04-01

The Lusi mud eruption started in May 2006 following to a 6.3 M earthquake striking the Java Island. In the framework of the Lusi Lab project (ERC grant n° 308126) we carried out geochemical surveys in the Sidoarjo district (Eastern Java Island, Indonesia) to investigate the gas bearing properties of the Watukosek fault system that crosses the Lusi mud eruption area. Soil gas (222Rn, CO2, CH4) concentration and flux measurements were performed 1) along two detailed profiles (~ 1km long), trending almost W-E direction, and 2) inside the Lusi embankment (about 7 km2) built to contain the erupted mud. Higher gas concentrations and fluxes were detected at the intersection with the Watukosek fault and the antithetic fault system. These zones characterized by the association of higher soil gas values constitute preferential migration pathways for fluids towards surface. The fractures release mainly CO2 (with peaks up to 400 g/m2day) and display higher temperatures (up to 41°C). The main shear zones are populated by numerous seeps that expel mostly CH4. Flux measurements in the seeping pools reveal that φCO2 is an order of magnitude higher than that measured in the fractures, and two orders of magnitude higher for φCH4. An additional geochemical profile was completed perpendicularly to the Watukosek fault escarpement (W-E direction) at the foots of the Penanngungang volcano. Results reveal CO2 and CH4 flux values significantly lower than those measured in the embankment, however an increase of radon and flux measurements is observed approaching the foots of the escarpment. These measurements are complemented with a database of ~350 CH4 and CO2 flux measurements and some soil gas concentrations (He, H2, CO2, CH4 and C2H6) and their isotopic analyses (δ13C-CH4, δD-CH4 and δ13C-CO2). Results show that the whole area is characterized by diffused gas release through seeps, fractures, microfractures and soil degassing. The collected results shed light on the origin of the

Scientific fundamentals of the exploration and calculability of a waste repository. Project part III, sub-project 2: Validity and applicability of geochemical models

International Nuclear Information System (INIS)

Baumann, J.

1991-04-01

The thermodynamic computer models WATEQF, PHREEQE, EQ3NR/EQ6, and SOLMINEQ 88 have been verified for their applicability to describe geochemical processes in the system salt stock/cap rock/ground water, i.e. processes such as dissolution, sedimentation, exchange and redox reactions. To begin with, the hydrochemical data obtained by the hydrogeological survey at the Gorleben site have been evaluated to thus form a reference data base. Then, these data have been used to derive the essential conditions and benchmark data to establish a geochemical model. (HP) [de

GEOCHEMICAL EXPLORATION

Institute of Scientific and Technical Information of China (English)

2011-01-01

<正>20111936 Gao Yuyan(School of Earth Sciences and Resourses,China University of Geosciences,Beijing 100083,China);Wang Mingqi Study on the Geogas Composition of the Concealed Metal Deposit and Its Background Area:Taking Zhangquanzhuang Gold Deposit as an Example(Geological Survey and Research,ISSN1672-4135,CN12-1353/P,33(3),2010,p.198-206,4 illus.,6 tables,10 refs.)Key words:metal ores,geogas methods,Hebei ProvinceStudy on the ore-forming elements,trace elements,REE and their spatial distribution of the geogas in the Zhangquanzhuang gold deposit shows the anomaly compositions o

Predictive geochemical mapping using environmental correlation

International Nuclear Information System (INIS)

Wilford, John; Caritat, Patrice de; Bui, Elisabeth

2016-01-01

The distribution of chemical elements at and near the Earth's surface, the so-called critical zone, is complex and reflects the geochemistry and mineralogy of the original substrate modified by environmental factors that include physical, chemical and biological processes over time. Geochemical data typically is illustrated in the form of plan view maps or vertical cross-sections, where the composition of regolith, soil, bedrock or any other material is represented. These are primarily point observations that frequently are interpolated to produce rasters of element distributions. Here we propose the application of environmental or covariate regression modelling to predict and better understand the controls on major and trace element geochemistry within the regolith. Available environmental covariate datasets (raster or vector) representing factors influencing regolith or soil composition are intersected with the geochemical point data in a spatial statistical correlation model to develop a system of multiple linear correlations. The spatial resolution of the environmental covariates, which typically is much finer (e.g. ∼90 m pixel) than that of geochemical surveys (e.g. 1 sample per 10-10,000 km 2 ), carries over to the predictions. Therefore the derived predictive models of element concentrations take the form of continuous geochemical landscape representations that are potentially much more informative than geostatistical interpolations. Environmental correlation is applied to the Sir Samuel 1:250,000 scale map sheet in Western Australia to produce distribution models of individual elements describing the geochemical composition of the regolith and exposed bedrock. As an example we model the distribution of two elements – chromium and sodium. We show that the environmental correlation approach generates high resolution predictive maps that are statistically more accurate and effective than ordinary kriging and inverse distance weighting interpolation

Gamma-ray surveys in uranium exploration

International Nuclear Information System (INIS)

1979-01-01

This report is intended to provide newcomers to uranium exploration with an up-to-date statement of the principal factors to be considered in planning and using gamma-ray surveys. Since the report incorporates the results of recent research, and since its preparation was influenced by the cumulative experience of its contributors, it should also be useful to those who already have some knowledge of radioactivity surveys and methods. The intention is that the information and explanations given in the report will make it possible for gamma-ray surveys to be used in the most efficient way for a given exploration task

Report on the survey of geothermal development at Okushiri Island, Hokkaido. Geochemical survey (Finger print method); Hokkaido Okushiritou chinetsu kaihatsu chosa chikagaku chosa (Finga print ho) hokokusho

Energy Technology Data Exchange (ETDEWEB)

NONE

1989-07-01

The geochemical survey by the finger print method was carried out in the Okushiri Island area, Hokkaido, and places of fracture existence were extracted and districts of possible geothermal existence were estimated. The finger print method is a geochemical survey method of soil gas, and the soil gas was collected along the main roads and mountain streams at measuring intervals of 100-300m. The gas collector was buried 30cm deep from the ground surface for 17 days, and the soil gas that rose from deep underground was adsorbed/accumulated into activated carbon. The gas analysis was made by the high sensitivity Curie point pyrolysis/quadrupole mass spectrometer. As a result of the survey analysis, the existence of fracture zone was presumed in the district along the Shiromizusawa that is a branch of the Horonai River, district along the road of the Okushiri Island line and district 1.5km WSW from the 5.8K Pass. Further, out of all 12 specimens, 6 specimens of Type X were distributed in a group in the district 1km square in north, south, east and west with the top of Mt. Shokan almost as the center. The possible existence of geothermal reservoirs was presumed. (NEDO)

Adjustment of geochemical background by robust multivariate statistics

Science.gov (United States)

Zhou, D.

1985-01-01

Conventional analyses of exploration geochemical data assume that the background is a constant or slowly changing value, equivalent to a plane or a smoothly curved surface. However, it is better to regard the geochemical background as a rugged surface, varying with changes in geology and environment. This rugged surface can be estimated from observed geological, geochemical and environmental properties by using multivariate statistics. A method of background adjustment was developed and applied to groundwater and stream sediment reconnaissance data collected from the Hot Springs Quadrangle, South Dakota, as part of the National Uranium Resource Evaluation (NURE) program. Source-rock lithology appears to be a dominant factor controlling the chemical composition of groundwater or stream sediments. The most efficacious adjustment procedure is to regress uranium concentration on selected geochemical and environmental variables for each lithologic unit, and then to delineate anomalies by a common threshold set as a multiple of the standard deviation of the combined residuals. Robust versions of regression and RQ-mode principal components analysis techniques were used rather than ordinary techniques to guard against distortion caused by outliers Anomalies delineated by this background adjustment procedure correspond with uranium prospects much better than do anomalies delineated by conventional procedures. The procedure should be applicable to geochemical exploration at different scales for other metals. ?? 1985.

Alaska Geochemical Database (AGDB)-Geochemical data for rock, sediment, soil, mineral, and concentrate sample media

Science.gov (United States)

Granitto, Matthew; Bailey, Elizabeth A.; Schmidt, Jeanine M.; Shew, Nora B.; Gamble, Bruce M.; Labay, Keith A.

2011-01-01

The Alaska Geochemical Database (AGDB) was created and designed to compile and integrate geochemical data from Alaska in order to facilitate geologic mapping, petrologic studies, mineral resource assessments, definition of geochemical baseline values and statistics, environmental impact assessments, and studies in medical geology. This Microsoft Access database serves as a data archive in support of present and future Alaskan geologic and geochemical projects, and contains data tables describing historical and new quantitative and qualitative geochemical analyses. The analytical results were determined by 85 laboratory and field analytical methods on 264,095 rock, sediment, soil, mineral and heavy-mineral concentrate samples. Most samples were collected by U.S. Geological Survey (USGS) personnel and analyzed in USGS laboratories or, under contracts, in commercial analytical laboratories. These data represent analyses of samples collected as part of various USGS programs and projects from 1962 to 2009. In addition, mineralogical data from 18,138 nonmagnetic heavy mineral concentrate samples are included in this database. The AGDB includes historical geochemical data originally archived in the USGS Rock Analysis Storage System (RASS) database, used from the mid-1960s through the late 1980s and the USGS PLUTO database used from the mid-1970s through the mid-1990s. All of these data are currently maintained in the Oracle-based National Geochemical Database (NGDB). Retrievals from the NGDB were used to generate most of the AGDB data set. These data were checked for accuracy regarding sample location, sample media type, and analytical methods used. This arduous process of reviewing, verifying and, where necessary, editing all USGS geochemical data resulted in a significantly improved Alaska geochemical dataset. USGS data that were not previously in the NGDB because the data predate the earliest USGS geochemical databases, or were once excluded for programmatic reasons

Cerro Prieto geothermal field: exploration during exploitation

Energy Technology Data Exchange (ETDEWEB)

1982-07-01

Geological investigations at Momotombo included photogeology, field mapping, binocular microscope examination of cuttings, and drillhole correlations. Among the geophysical techniques used to investigate the field sub-structure were: Schlumberger and electromagnetic soundings, dipole mapping and audio-magnetotelluric surveys, gravity and magnetic measurements, frequency domain soundings, self-potential surveys, and subsurface temperature determinations. The geochemical program analyzed the thermal fluids of the surface and in the wells. The description and results of exploration methods used during the investigative stages of the Momotombo Geothermal Field are presented. A conceptual model of the geothermal field was drawn from the information available at each exploration phase. The exploration methods have been evaluated with respect to their contributions to the understanding of the field and their utilization in planning further development.

Use of termite mounds in geochemical exploration in North Ethiopia [rapid communication

Science.gov (United States)

Kebede, Fassil

2004-09-01

The geochemistry of the termite mounds was studied in lower Giba River basin, Kolla Tambien district, northern Ethiopia to show that they are useful in searching for metals. Specimens from the termite mounds and parent materials were collected to quantify gold, silver, copper, zinc, cobalt, manganese, iron and nickel. The results of the geochemical analysis of the samples indicated that these metals exist both in the termite mound and the parent material in the surrounding area. Correlation analysis shows that termite mounds and the parent materials are positively correlated for gold ( r = 0.75∗), copper ( r = 0.77∗), silver ( r = 0.56∗) and manganese ( r = 0.72). This positive correlation leads to the conclusion that there is a direct relation between the concentration of metals in termite mound and the parent rocks. Termite mounds can therefore be used as tools in exploring for these metals.

Putting it to the test : alternative exploration techniques seek recognition

Energy Technology Data Exchange (ETDEWEB)

Cope, G.

2005-06-01

In the past, remote sensing techniques such as magnetic surveying, geochemical sampling and radiometric surveys, were efficient in hard rock mining exploration but were limited in hydrocarbon detection due to problems such as diurnal and weather variations. This article discussed some of the recent advances in technology that have been developed to overcome many of the drawbacks of older systems. Two Calgary-based companies are currently offering innovative and viable exploration alternatives. The Gore-Sorber module is the most accurate and comprehensive surface geochemical sampling technology currently available to the oil and gas industry. The testing module consists of 2 portions of expanded polytetrafluoroethylene polymer material sealed into a GORE-TEX sheath to prevent water and particle contamination. The module is then inserted into a shallow hole to a depth of 50 centimetres and left there for up to 2 weeks. The sample position is marked and surveyed. Over the course of the 2 weeks, volatile and semi-volatile soil gases in the C2-C15 range are absorbed into the material. The modules are analysed in mass spectrometers and gas chromatographs to determine zone and phase information. Advantages of the system include a reduction in soil contamination; the elimination of day-to-day fluctuations; and the fact that lab analysis allows for higher sensitivity. Costs are approximately $60,000 to $70,000 for an area of 16 square kilometres. Disadvantages include the inability to define the amount of hydrocarbons in place or their depth and the fact that proper field operation and collection of data by trained personnel is critical to the analysis process. The technique has been gaining in popularity in Canada as more exploration is directed towards environmentally sensitive frontier areas. Radiometric surveys record the gamma ray emissions of potassium, uranium and thorium as they decay radioactively. As hydrocarbons leak to the surface, they cause geochemical changes

Reconnaissance geochemical exploration of plutons of syenite and shonkinite, southern Asir, Kingdom of Saudi Arabia

Science.gov (United States)

Overstreet, W.C.; Assegaff, A.B.; Hussain, M.A.; Naqvi, M.I.; Selner, G.I.; Matzko, J.J.

1985-01-01

Reconnaissance geochemical exploration for rare metals in plutons of syenite and shonkinite disclosed generally less than 20 ppm Nb in rocks, wadi sediments, and concentrates. The sparsity of Nb is accompanied by low values for La, Sn, W, Y, and Zr and relatively high but insignificant values for Be and Mo. Base and precious metals are either below their respective limits of determination in the various sample media or are present at background levels commensurate with average crustal abundances in felsic rocks. Pegmatite dikes associated with the syenite plutons are rare and lack vermiculite. The present investigation disclosed no possible ore deposits in the plutons covered by the field work.

Application of cluster analysis to geochemical compositional data for identifying ore-related geochemical anomalies

Science.gov (United States)

Zhou, Shuguang; Zhou, Kefa; Wang, Jinlin; Yang, Genfang; Wang, Shanshan

2017-12-01

Cluster analysis is a well-known technique that is used to analyze various types of data. In this study, cluster analysis is applied to geochemical data that describe 1444 stream sediment samples collected in northwestern Xinjiang with a sample spacing of approximately 2 km. Three algorithms (the hierarchical, k-means, and fuzzy c-means algorithms) and six data transformation methods (the z-score standardization, ZST; the logarithmic transformation, LT; the additive log-ratio transformation, ALT; the centered log-ratio transformation, CLT; the isometric log-ratio transformation, ILT; and no transformation, NT) are compared in terms of their effects on the cluster analysis of the geochemical compositional data. The study shows that, on the one hand, the ZST does not affect the results of column- or variable-based (R-type) cluster analysis, whereas the other methods, including the LT, the ALT, and the CLT, have substantial effects on the results. On the other hand, the results of the row- or observation-based (Q-type) cluster analysis obtained from the geochemical data after applying NT and the ZST are relatively poor. However, we derive some improved results from the geochemical data after applying the CLT, the ILT, the LT, and the ALT. Moreover, the k-means and fuzzy c-means clustering algorithms are more reliable than the hierarchical algorithm when they are used to cluster the geochemical data. We apply cluster analysis to the geochemical data to explore for Au deposits within the study area, and we obtain a good correlation between the results retrieved by combining the CLT or the ILT with the k-means or fuzzy c-means algorithms and the potential zones of Au mineralization. Therefore, we suggest that the combination of the CLT or the ILT with the k-means or fuzzy c-means algorithms is an effective tool to identify potential zones of mineralization from geochemical data.

Proceedings of 2. Brazilian Geochemical Congress

International Nuclear Information System (INIS)

1989-01-01

Some works about geochemistry are presented, including themes about geochemical exploration, lithogeochemistry and isotope geochemistry, environmental geochemistry, analytical geochemistry, geochemistry of carbonatites and rare earth elements and organic geochemistry. (C.G.C.) [pt

An exploration systems approach to the Copper Mountain uranium deposits, Wyoming, USA

International Nuclear Information System (INIS)

Babcock, L.L.; Sayala, D.

1982-01-01

This study of Copper Mountain uranium deposits entailed the examination, interpretation, and synthesis of geological, geochemical, geophysical, and emanometric results. Regional, structural, and metallogenic syntheses yielded criteria concerning the occurrence of anomalously radioactive granites and associated uranium deposits. Geochemical surveys indicated various pathfinder elements for uranium deposits and defined the extent of the anomalous granites. Subsurface spectral radiometrics outlined high K-Th zones which contain secondary uranium deposits. Aerial spectral radiometric and magnetic surveys delineated the Copper Mountain uranium district. Ground water helium and U-234/U-238 activity ratios are the most effective emanometric and isotopic techniques. Based on the systems approach employed and logistical considerations, a five-phase exploration strategy is suggested for Copper Mountain-type deposits

Geochemical modelling baseline compositions of groundwater

DEFF Research Database (Denmark)

Postma, Diederik Jan; Kjøller, Claus; Andersen, Martin Søgaard

2008-01-01

and variations in water chemistry that are caused by large scale geochemical processes taking place at the timescale of thousands of years. The most important geochemical processes are ion exchange (Valreas and Aveiro) where freshwater solutes are displacing marine ions from the sediment surface, and carbonate......Reactive transport models, were developed to explore the evolution in groundwater chemistry along the flow path in three aquifers; the Triassic East Midland aquifer (UK), the Miocene aquifer at Valreas (F) and the Cretaceous aquifer near Aveiro (P). All three aquifers contain very old groundwaters...... dissolution (East Midlands, Valreas and Aveiro). Reactive transport models, employing the code PHREEQC, which included these geochemical processes and one-dimensional solute transport were able to duplicate the observed patterns in water quality. These models may provide a quantitative understanding...

A geochemical atlas of North Carolina, USA

Science.gov (United States)

Reid, J.C.

1993-01-01

A geochemical atlas of North Carolina, U.S.A., was prepared using National Uranium Resource Evaluation (NURE) stream-sediment data. Before termination of the NURE program, sampling of nearly the entire state (48,666 square miles of land area) was completed and geochemical analyses were obtained. The NURE data are applicable to mineral exploration, agriculture, waste disposal siting issues, health, and environmental studies. Applications in state government include resource surveys to assist mineral exploration by identifying geochemical anomalies and areas of mineralization. Agriculture seeks to identify areas with favorable (or unfavorable) conditions for plant growth, disease, and crop productivity. Trace elements such as cobalt, copper, chromium, iron, manganese, zinc, and molybdenum must be present within narrow ranges in soils for optimum growth and productivity. Trace elements as a contributing factor to disease are of concern to health professionals. Industry can use pH and conductivity data for water samples to site facilities which require specific water quality. The North Carolina NURE database consists of stream-sediment samples, groundwater samples, and stream-water analyses. The statewide database consists of 6,744 stream-sediment sites, 5,778 groundwater sample sites, and 295 stream-water sites. Neutron activation analyses were provided for U, Br, Cl, F, Mn, Na, Al, V, Dy in groundwater and stream water, and for U, Th, Hf, Ce, Fe, Mn, Na, Sc, Ti, V, Al, Dy, Eu, La, Sm, Yb, and Lu in stream sediments. Supplemental analyses by other techniques were reported on U (extractable), Ag, As, Ba, Be, Ca, Co, Cr, Cu, K, Li, Mg, Mo, Nb, Ni, P, Pb, Se, Sn, Sr, W, Y, and Zn for 4,619 stream-sediment samples. A small subset of 334 stream samples was analyzed for gold. The goal of the atlas was to make available the statewide NURE data with minimal interpretation to enable prospective users to modify and manipulate the data for their end use. The atlas provides only

Geochemical Constraints for Mercury's PCA-Derived Geochemical Terranes

Science.gov (United States)

Stockstill-Cahill, K. R.; Peplowski, P. N.

2018-05-01

PCA-derived geochemical terranes provide a robust, analytical means of defining these terranes using strictly geochemical inputs. Using the end members derived in this way, we are able to assess the geochemical implications for Mercury.

User's Manual Frac-Explore 2.0

Energy Technology Data Exchange (ETDEWEB)

George, S.A.; Guo, Genliang

1999-03-09

FRAC-EXPLORE 2.0, a new computer software package for oil and gas exploration using surface lineament and fracture analysis. FRAC-EXPLORE 2.0 provides a suite of tools for analyzing the characteristics and patterns of surface lineaments and fractures, as well as other surface geological features. These tools help identify priority areas of potential subsurface oil and gas traps. The package can be used in a frontier basin to initially screen the priority locations for further seismic and/or geochemical surveys. It can also be used in a mature basin to help delineate additional oil and gas reservoirs.

Oak Ridge Geochemical Reconnaissance Program

International Nuclear Information System (INIS)

Arendt, J.W.

1977-03-01

The Oak Ridge reconnaissance program is responsible for the geochemical survey in a 12-state area covering Texas, Oklahoma, Kansas, Nebraska, South Dakota, North Dakota, Minnesota, Wisconsin, Michigan, Iowa, Indiana, and Illinois as part of the National Uranium Resource Evaluation Program. The program concept is outlined and the planning and organization of the program is discussed

Metallogenetic characterization of granitoid rocks through geochemical prospection: the Lagoa Real example related to uranium mineralization in Bahia state, Brazil; Caracterizacao metalogenetica de corpos gratinoides atraves de prospeccao geoquimica: o exemplo da suite intrusiva Lagoa Real relacionada a mineralizacoes de uranio no Estado da Bahia

Energy Technology Data Exchange (ETDEWEB)

Oliveira, J.E., E-mail: cprmsa@bahianet.com.br [Servico Geologico do Brasil (GEREMI/SUREG/SA/CPRM), Salvador, BA (Brazil)

2011-07-01

Within a broad metallogenetic evaluation program carried out by CPRM - Geological Survey of Brazil in covenant with the CBPM - Companhia Baiana de Pesquisa Mineral in the central part of the Sao Francisco Craton, the Lagoa Real granitoid rocks was one of the selected targets. The work included geochemical exploration supplemented by follow-in survey and integrated 1:200.000 scale geochemical cartography. The Lagoa Real granitoid was recognized with composition ranging from monzogranitic to alcaligranitic type. The geochemical surveying led to the definition of the metallogenetic specialization of the granitoid rock, with characteristic geochemical and mineralogic associations. These associations are related to uranium mineralization. The genetic model using stream sediment and pan concentrate data, show similarity with the metallogenetic model of zonal partitioning proposed by Routhier (1963), for plutonogenic lode deposits with potential for Sn, W, Nb, Be, REE, Au, and U. In this work emphasis is given to the importance of the integrated use of different prospective methods toward the evaluation of granitoid systems, particularly the combination of geochemical surveying methods with results for a better understanding of the geologic and metallogenetic settings. (author)

International training course on uranium exploration

International Nuclear Information System (INIS)

Barretto, P.M.C.

1978-01-01

Full text: As part of its Technical Assistance Programme for developing countries, the IAEA has conducted a series of training courses in prospecting for nuclear raw materials for example, in 1974 a regional course on uranium and thorium prospecting was held in India, and an interregional training course on uranium geochemical prospecting methods was held in Austria in 1975. In September 1977, another interregional training course on uranium geochemical prospecting methods was held at Skofja Loka, Slovenia, Yugoslavia. Twenty-four delegates from Afghanistan, Algeria, Argentina, Bolivia, Chile, Colombia, Czechoslovakia, India, Indonesia, Malaysia, Philippines, Portugal, Sri Lanka, Turkey, Venezuela and Yugoslavia participated in the four-week training course. The Federal Republic of Yugoslavia acted as host for the course. The Skofja Loka area was selected because it contains sedimentary rocks with known uranium mineralization, and presented ideal conditions (soil, drainage and topography) for Uranium geochemical surveys. In addition, the participants could benefit from a technical visit to a very interesting type of uranium mineralization near the town of Gorenje Vaz. Several well-known geologists, such as Dr. A. Grimbert (France) and Prof. Ian Nichol (Canada) were present as guest lecturers. In the first week the lectures dealt with the basic concepts of geochemical exploration for uranium, as well as preparing the participants for the field work. In addition to specific topics on geochemistry and uranium behaviour in the natural environment, the lectures also covered other topics of interest, such as world uranium resources and demand, types of uranium deposits and technical advances in exploration equipment. A visit to the Zirovski Vrh uranium mine was made, where the participants saw different techniques for mining ore bodies with complex structure and rapid change in grade concentration. At the end of the mine tour, there was a lengthy discussion of

Well sediments: a medium for geochemical prospecting, an example from the Nisa region, Portugal

NARCIS (Netherlands)

Vriend, S.P.; Dekkers, M.J.; Janssen, M.A.; Commandeur, J.

1991-01-01

Vriend, S.P., Dekkers, M.J.. Janssen, M.A. and Commandeur, J., 1991. Well sediments: a medium for geochemical prospecting, an example from the Nisa region. Portugal. In: A.W. Rose and P.M. Taufen I Editors). Geochemical Exploration ! 989. J. Geochem. Expior., 4 ! : ! 5 I- 167. Tile potential of

Geochemical mapping using stream sediments in west-central Nigeria: Implications for environmental studies and mineral exploration in West Africa

International Nuclear Information System (INIS)

Lapworth, Dan J.; Knights, Katherine V.; Key, Roger M.; Johnson, Christopher C.; Ayoade, Emmanuel; Adekanmi, Michael A.; Arisekola, Tunde M.; Okunlola, Olugbenga A.; Backman, Birgitta; Eklund, Mikael; Everett, Paul A.; Lister, Robert T.; Ridgway, John; Watts, Michael J.; Kemp, Simon J.; Pitfield, Peter E.J.

2012-01-01

This paper provides an overview of regional geochemical mapping using stream sediments from central and south-western Nigeria. A total of 1569 stream sediment samples were collected and 54 major and trace elements determined by ICP-MS and Au, Pd and Pt by fire assay. Multivariate statistical techniques (e.g., correlation analysis and principal factor analysis) were used to explore the data, following appropriate data transformation, to understand the data structure, investigate underlying processes controlling spatial geochemical variability and identify element associations. Major geochemical variations are controlled by source geology and provenance, as well as chemical weathering and winnowing processes, more subtle variations are a result of land use and contamination from anthropogenic activity. This work has identified placer deposits of potential economic importance for Au, REE, Ta, Nb, U and Pt, as well as other primary metal deposits. Areas of higher As and Cr (>2 mg/kg and >70 mg/kg respectively) are associated with Mesozoic and younger coastal sediments in SW Nigeria. High stream sediment Zr concentrations (mean >0.2%), from proximal zircons derived from weathering of basement rocks, have important implications for sample preparation and subsequent analysis due to interferences. Associated heavy minerals enriched in high field strength elements, and notably rare earths, may also have important implications for understanding magmatic processes within the basement terrain of West Africa. This study provides important new background/baseline geochemical values for common geological domains in Nigeria (which extend across other parts of West Africa) for assessment of contamination from urban/industrial land use changes and mining activities. Regional stream sediment mapping is also able to provide important new information with applications across a number of sectors including agriculture, health, land use and planning.

Geochemical signature of columbite-tantalite and radiometric survey of radioactive pegmatites in the region of Parelhas, Rio Grande do Norte, Brazil

International Nuclear Information System (INIS)

Moura, Jorge Costa de

2013-01-01

This thesis is the result of geochemical, structural and radiometric investigations on radioactive pegmatites of the Borborema Pegmatitic Province in Northeast Brazil. The studied area, located in the surroundings of the city of Parelhas in the region of the Serra da Borborema, is well known for its thousands of pegmatitic bodies exploited in primitive mines called 'garimpos'. The main goal was to find an efficient, cheap and routine inspection procedure to identify the origin of commercialized radioactive columbite-tantalite (coltan) ore. The Brazilian Nuclear Energy Agency (CNEN) controls uranium commerce and nuclear activity in Brazil. Without an effective method to characterize coltan ores from different localities it is impossible to control the trade. The here presented new method was developed by correlating structural features of these pegmatites with the geochemical behavior of their coltan samples. It was found that the variation of the ratio U/Th versus Nb 2 O 5 /Ta 2 O 5 provides geochemical signatures (analytical fingerprints) for the source location of such ore. A test of the new method with coltan samples of commercial batches from the Brazilian states Amapa and Rondonia also generated distinct geochemical signatures. A radiometric survey (CPS) was carried out in several mines and pegmatites to study the environmental impact of gamma radiation. It included in situ measurements of pegmatite walls, host rocks, soil, and accumulated water and revealed that gamma emitters are hardly solubilized and environmental gamma radiation therefore generally is not enhanced to a dangerous level. (author)

Evaluation of uranium geochemical anomalies in the Charlotte 10 x 20 NTMS quadrangle

International Nuclear Information System (INIS)

Carpenter, R.H.

1981-11-01

This report contains a synthesis of published geological, geophysical, and geochemical information for portions of Cabarrus and Rowan Counties, NC, where uranium geochemical anomalies have been described by Heffner and Ferguson (1978). The results of a ground radiation survey in selected areas are also described. Based on an evaluation of published information and the data obtained in the field study, conclusions are made regarding the possible occurrence of uranium concentration. Recommendations for detailed surveys in certain areas are also presented

Uruguay mining Inventory: Geochemical prospecting results of Valentines mapping

International Nuclear Information System (INIS)

Spangenberg, J.; Filippini, J.

1985-01-01

This work is about geochemical prospecting carried out into the Uruguay mining inventory framework. In this case the survey was in Valentines mapping. Florida, Durazno and Treinta y Tres provinces of Uruguay .

Discovery of Wolitu Pb-Zn deposit through geochemical prospecting under loess cover in Inner Mongolia, China

Directory of Open Access Journals (Sweden)

Fan Yang

2017-09-01

Full Text Available We report the finding of the Wolitu Pb-Zn deposit in Inner Mongolia, China, through a series of geochemical surveys. The Wolitu area, located in the loess-cover area in the Hure Banner, Tongliao City, Inner Mongolia, and neighboring the Horqin Sandy Land to the north, had no previous history of Pb-Zn mining or record of Pb-Zn mineralization. Our study identified a large Pb-Zn anomaly with potential zones of mineralization by stream sediment survey. Random rock sampling reveals limonitization at sporadic outcrops in the gullies. The high concentrations of Pb in the residual debris provided guidelines to fix the position for exploratory trench. Oxidized concealed orebodies were identified by trenching. Blind orebodies in veins hosted within the structural zone between slates and marbles of the upper Carboniferous Shizuizi Formation and the Permian granite were discovered by drilling. It is computed that the ore reserve may reach up to 540,000 tones with Pb grade of 1.27% and Zn of 1.9%. This case study is an excellent example for identifying potential polymetallic deposits in loess covered terrains using geochemical exploration.

Heliborne time-domain electromagnetic (TEM) surveys for uranium exploration

International Nuclear Information System (INIS)

Chaturvedi, A.K.

2015-01-01

Airborne geophysical surveys have been used extensively in petroleum, mineral exploration, and environmental mapping. Of all the geophysical methods, Electromagnetic (EM) methods, both ground and airborne are used to map the conductive ore bodies buried in the resistive bed rock. Mapping resistivity variations can help unravel complex geological problems and identify areas of hidden potential. Besides the traditional applications to ground water investigations and other natural resource exploration and geological mapping, a number of new applications have been reported. These include hazardous-waste characterization studies, precision agriculture applications, archaeological surveys etc. Airborne Electromagnetic (AEM) methods have undergone rapid improvements over the past few decades. Several new airborne Time Do-main EM (TDEM) systems appeared; existing systems were updated and/or enhanced. The use of natural field (passive) EM surveys continued to increase, with new or improved systems becoming available for both airborne and ground surveys. The number of large airborne survey systems with combined EM, magnetic, gravimetric and gamma-ray spectrometric capabilities also increased. Exploration of a mineral deposit is a multi-stage and multi-disciplinary approach that commences from regional investigations and concludes with establishing of a deposit. As economics play a major role in exploration, a proper integrated study is always beneficial in narrowing down the potential mineral target zones. Heliborne geophysical surveys are being conducted world-wide for exploration of base metals, gold, phosphorite, oil, uranium etc. that are very effective tool in identifying zones of interest accurately, economically and with less span of time. These surveys give a very good insight of surface and sub-surface geophysical signatures that can be attributed to geology with proper modeling. Heliborne Time - domain Electromagnetic (TEM) methods are well known for search of

Report on the geothermal development promotion survey. No.36. Mt. Amemasudake area; Chinetsu kaihatsu sokushin chosa hokokusho. No. 36 Amemasudake chiiki

Energy Technology Data Exchange (ETDEWEB)

NONE

1995-03-01

The paper summed up the results of the geothermal development promotion survey 'Mt. Amemasudake area' which was carried out at Akaigawa village, Yoichi county, Hokkaido, from FY 1991 to FY 1994. In the survey, the following were conducted for the comprehensive analysis: surface survey such as geology/alteration zone survey, geochemical survey, gravity exploration, electromagnetic exploration and electric exploration, core test by drilling 5 boreholes, test to induce jetting of geothermal fluids, measurement of in-borehole temperature/pressure, survey of geochemical properties of geothermal water. As to the fracture system in this area, the Amemasudake fault and the Amemasuzawa fault are especially important, and it was assumed that these faults had relation to the present geothermal distribution. It is thought that structural conditions of geothermal reservoirs are fractures in basement rocks. As a result of the borehole survey, it was indicated that the center of the high-temperature part with a temperature of 250 degrees C or more was in the boundary zone southeast of this area at a level of 500m below sea level. The scale, which reached about 3km both in east/west and north/south, is almost the same scale as that of the neighboring Toyoha area where great potentiality of the geothermal development is expected. (NEDO)

Report on the geothermal development promotion survey. No.36. Mt. Amemasudake area; Chinetsu kaihatsu sokushin chosa hokokusho. No. 36 Amemasudake chiiki

Energy Technology Data Exchange (ETDEWEB)

NONE

1995-03-01

The paper summed up the results of the geothermal development promotion survey 'Mt. Amemasudake area' which was carried out at Akaigawa village, Yoichi county, Hokkaido, from FY 1991 to FY 1994. In the survey, the following were conducted for the comprehensive analysis: surface survey such as geology/alteration zone survey, geochemical survey, gravity exploration, electromagnetic exploration and electric exploration, core test by drilling 5 boreholes, test to induce jetting of geothermal fluids, measurement of in-borehole temperature/pressure, survey of geochemical properties of geothermal water. As to the fracture system in this area, the Amemasudake fault and the Amemasuzawa fault are especially important, and it was assumed that these faults had relation to the present geothermal distribution. It is thought that structural conditions of geothermal reservoirs are fractures in basement rocks. As a result of the borehole survey, it was indicated that the center of the high-temperature part with a temperature of 250 degrees C or more was in the boundary zone southeast of this area at a level of 500m below sea level. The scale, which reached about 3km both in east/west and north/south, is almost the same scale as that of the neighboring Toyoha area where great potentiality of the geothermal development is expected. (NEDO)

Top Soils Geochemical and Radioactivity Survey of Naples (Italy) Metropolitan.

Science.gov (United States)

Somma, R.; De Vivo, B.; Cicchella, D.

2001-05-01

The metropolitan area of Naples due to intense human activities is an emblematic area affected by various environmental pollution of soils and waters in addition to hydrogeological volcanic, seismic and bradyseismic hazards. The geology of the area is prevailing represented by volcanics erupted, from the Upper Pleistocene to Recent by Mt. Somma-Vesuvius on the east and the Campi Flegrei fields on the west. The morphology of the metropolitan area of Naples city can be subdivided in flat areas, constituted by reworked pyroclastic terrains, and by hills originated by the overlapping of different welded pyroclastic flows (i.e.: Campanian Ignimbrite and Neapoletan Yellow Tuff) intercalated with pyroclastic deposits of different origins (i.e.: Campi Flegrei, Mt. Somma-Vesuvius, Ischia) and ages. In order to compile a multi-element baseline geochemical and radioactivity mapping of the metropolitan area of the Napoli we have sampled for this study, in situ top soil and imported filling material (mainly soil, volcanic ash, pumice and scoriae). The sampling and radioactivity survey has been carried out on about 200 sampling sites covering an area of about 150 Km2, with a grid of 0.5 x 0.5 km in the urbanised downtown and 1 km x 1 km in the sub urban areas. In each site has been determined a radioactivity by a Scintrex GRS-500 at different emission spectra as total radioactivity (> 0.08 MeV and > 0.40 MeV), 238U (at 1.76 MeV mostly from 214Bi), 232Th (at 2.6 MeV mostly from 208Tl) and 40K (at 1.46 MeV mostly for 40K). The range of values of in situ soils are as follow for the in situ soils (Total radioactivity: 1327- 360 and 114- 47; 238U: 2.6- 1.3; 40K: 8.1- 3.1; 232U: 0.5- 0.1). Analyses of major, metallic elements and pH of each soil sample are in progress, while Pb isotopes compositions, for a selected number of samples, will be determined to discriminate the natural (geogenic) from the anthropogenic components in the soils by versus the anthropogenetic origin. The data

FY 2000 report on the geothermal development promotion survey - No.C-4 Shiro-mizukoshi area. Resource survey (Primary); 2000 nendo chinetsu kaihatsu sokushin chosa. No. C-4 Shiromizukoshi chiiki shigen chosa hokokusho (Dai 1 ji)

Energy Technology Data Exchange (ETDEWEB)

NONE

2002-01-01

As a part of the FY 2000 geothermal development promotion survey, survey was conducted in the Shiro-mizukoshi area (about 10km{sup 2}), Kagoshima prefecture, the gradually-inclined area located at the southwest foot of Volcano Kirishima, and the results were summed up. In the survey, the following were carried out: surface survey such as geology/alteration zone/fracture system, high-density gravity exploration, electromagnetic exploration, geochemical fluid survey, core test by drilling three exploration boreholes, temperature log, temperature recovery test, water injection test, short-term jetting test, etc. N12-SZ-1 came across the reservoir associated with the ENE-WSW system fault at a depth of 1,085m. The result of the temperature log and the geochemical temperature indicated that the temperature of the reservoir was between 230 and 240 degrees C. However, the reservoir was regarded as the vapor heating reservoir heated by the high-temperature vapor which is thought to be the shallow ground water separated from the deep reservoir. N12-SZ-2 was a large lost circulation zone at a depth between 1,325 and 1,486m, which indicated that N12-SZ-2 came across the ENE-WSW system Shiro-mizukoshi fault. N12-SZ-3 seems to be the area into which ground water flows. (NEDO)

Geochemical reanalysis of historical U.S. Geological Survey sediment samples from the Inmachuk, Kugruk, Kiwalik, and Koyuk River drainages, Granite Mountain, and the northern Darby Mountains, Bendeleben, Candle, Kotzebue, and Solomon quadrangles, Alaska

Science.gov (United States)

Werdon, Melanie B.; Granitto, Matthew; Azain, Jaime S.

2015-01-01

The State of Alaska’s Strategic and Critical Minerals (SCM) Assessment project, a State-funded Capital Improvement Project (CIP), is designed to evaluate Alaska’s statewide potential for SCM resources. The SCM Assessment is being implemented by the Alaska Division of Geological & Geophysical Surveys (DGGS), and involves obtaining new airborne-geophysical, geological, and geochemical data. As part of the SCM Assessment, thousands of historical geochemical samples from DGGS, U.S. Geological Survey (USGS), and U.S. Bureau of Mines archives are being reanalyzed by DGGS using modern, quantitative, geochemical-analytical methods. The objective is to update the statewide geochemical database to more clearly identify areas in Alaska with SCM potential. The USGS is also undertaking SCM-related geologic studies in Alaska through the federally funded Alaska Critical Minerals cooperative project. DGGS and USGS share the goal of evaluating Alaska’s strategic and critical minerals potential and together created a Letter of Agreement (signed December 2012) and a supplementary Technical Assistance Agreement (#14CMTAA143458) to facilitate the two agencies’ cooperative work. Under these agreements, DGGS contracted the USGS in Denver to reanalyze historical USGS sediment samples from Alaska. For this report, DGGS funded reanalysis of 653 historical USGS sediment samples from the statewide Alaska Geochemical Database Version 2.0 (AGDB2; Granitto and others, 2013). Samples were chosen from an area covering portions of the Inmachuk, Kugruk, Kiwalik, and Koyuk river drainages, Granite Mountain, and the northern Darby Mountains, located in the Bendeleben, Candle, Kotzebue, and Solomon quadrangles of eastern Seward Peninsula, Alaska (fig. 1). The USGS was responsible for sample retrieval from the National Geochemical Sample Archive (NGSA) in Denver, Colorado through the final quality assurance/quality control (QA/QC) of the geochemical analyses obtained through the USGS contract

A survey on exploring key performance indicators

Directory of Open Access Journals (Sweden)

Mohammed Badawy

2016-12-01

Full Text Available Key Performance Indicators (KPIs allows gathering knowledge and exploring the best way to achieve organization goals. Many researchers have provided different ideas for determining KPI's either manually, and semi-automatic, or automatic which is applied in different fields. This work concentrates on providing a survey of different approaches for exploring and predicting key performance indicators (KPIs.

Geochemical mapping study of Panjang island

International Nuclear Information System (INIS)

Sutisna; Sumardjo

2010-01-01

Impact of industrial and regional development are not only related to an improvement of socio-economic, but also to an environmental conservation and sustainable. This impact could be observed on a change of geochemical mapping before and after an operational of the industry. In the relation with a regional development and resources utilization, the geochemical mapping have been done in the aim to know a resources and an elemental distribution at Panjang island. In this research, ko-Instrumental Neutron Activation Analysis (k_0-INAA) have been applied in an elemental quantification on the geochemical mapping. Pencuplikan of geochemical sample have been carried out by using a grid systematic method with a sample density of about 10 sample per square kilometre involved 85 pencuplikan point. The geochemical sample of sediment and soil have been provided as a dry weight of 100 mesh. Internal quality control have done by using a number of Standard Reference Materials obtained from US. Geological Survey. Fifteen elements of Sc, Co, In, Rb, Mo, Ba, Ce, Nd, Eu, La, Yb, Th, U, lr and Hf contained in standard materials have been evaluated. The analysis result show that a relative standard deviation less than 11 %, except for Mo (13 %) and lr (26 %). Fourteen elements of Al, Br, Ca, Co, Eu, Fe, La, U, Na, Ce, Mn, As, Sc and Th have been mapped and presented in this paper. The major elements of Ca, Al and Fe, and minor elements of Mn, U and Sc are distributed at all region. The lanthanide elements of La, Ce and Eu have vary concentration and could be found at the middle to the north of the island. (author)

Computer analysis to the geochemical interpretation of soil and stream sediment data in an area of Southern Uruguay

International Nuclear Information System (INIS)

Spangenberg, J.

2010-01-01

In southern Uruguay there are several known occurrences of base metal sulphide mineralization within an area of Precambrian volcanic sedimentary rocks. Regional geochemical stream sediment reconnaissance surveys revealed new polymetallic anomalies in the same stratigraphic zone. Geochemical interpretation of multi-element data from a soil and stream sediment survey carried out in one of these anomalous areas is presented.

50 CFR 37.45 - Exploration by the U.S. Geological Survey.

Science.gov (United States)

2010-10-01

... 50 Wildlife and Fisheries 6 2010-10-01 2010-10-01 false Exploration by the U.S. Geological Survey... INTERIOR (CONTINUED) THE NATIONAL WILDLIFE REFUGE SYSTEM GEOLOGICAL AND GEOPHYSICAL EXPLORATION OF THE....S. Geological Survey. Notwithstanding the requirement found in § 37.21(b) on when exploration plans...

The Momotombo Geothermal Field, Nicaragua: Exploration and development case history study

Energy Technology Data Exchange (ETDEWEB)

None

1982-07-01

This case history discusses the exploration methods used at the Momotombo Geothermal Field in western Nicaragua, and evaluates their contributions to the development of the geothermal field models. Subsequent reservoir engineering has not been synthesized or evaluated. A geothermal exploration program was started in Nicaragua in 1966 to discover and delineate potential geothermal reservoirs in western Nicaragua. Exploration began at the Momotombo field in 1970 using geological, geochemical, and geophysical methods. A regional study of thermal manifestations was undertaken and the area on the southern flank of Volcan Momotombo was chosen for more detailed investigation. Subsequent exploration by various consultants produced a number of geotechnical reports on the geology, geophysics, and geochemistry of the field as well as describing production well drilling. Geological investigations at Momotombo included photogeology, field mapping, binocular microscope examination of cuttings, and drillhole correlations. Among the geophysical techniques used to investigate the field sub-structure were: Schlumberger and electromagnetic soundings, dipole mapping and audio-magnetotelluric surveys, gravity and magnetic measurements, frequency domain soundings, self-potential surveys, and subsurface temperature determinations. The geochemical program analyzed the thermal fluids of the surface and in the wells. This report presents the description and results of exploration methods used during the investigative stages of the Momotombo Geothermal Field. A conceptual model of the geothermal field was drawn from the information available at each exploration phase. The exploration methods have been evaluated with respect to their contributions to the understanding of the field and their utilization in planning further development. Our principal finding is that data developed at each stage were not sufficiently integrated to guide further work at the field, causing inefficient use of

A Spatially Constrained Multi-autoencoder Approach for Multivariate Geochemical Anomaly Recognition

Science.gov (United States)

Lirong, C.; Qingfeng, G.; Renguang, Z.; Yihui, X.

2017-12-01

Separating and recognizing geochemical anomalies from the geochemical background is one of the key tasks in geochemical exploration. Many methods have been developed, such as calculating the mean ±2 standard deviation, and fractal/multifractal models. In recent years, deep autoencoder, a deep learning approach, have been used for multivariate geochemical anomaly recognition. While being able to deal with the non-normal distributions of geochemical concentrations and the non-linear relationships among them, this self-supervised learning method does not take into account the spatial heterogeneity of geochemical background and the uncertainty induced by the randomly initialized weights of neurons, leading to ineffective recognition of weak anomalies. In this paper, we introduce a spatially constrained multi-autoencoder (SCMA) approach for multivariate geochemical anomaly recognition, which includes two steps: spatial partitioning and anomaly score computation. The first step divides the study area into multiple sub-regions to segregate the geochemical background, by grouping the geochemical samples through K-means clustering, spatial filtering, and spatial constraining rules. In the second step, for each sub-region, a group of autoencoder neural networks are constructed with an identical structure but different initial weights on neurons. Each autoencoder is trained using the geochemical samples within the corresponding sub-region to learn the sub-regional geochemical background. The best autoencoder of a group is chosen as the final model for the corresponding sub-region. The anomaly score at each location can then be calculated as the euclidean distance between the observed concentrations and reconstructed concentrations of geochemical elements.The experiments using the geochemical data and Fe deposits in the southwestern Fujian province of China showed that our SCMA approach greatly improved the recognition of weak anomalies, achieving the AUC of 0.89, compared

Geochemical baseline studies of soil in Finland

Science.gov (United States)

Pihlaja, Jouni

2017-04-01

The soil element concentrations regionally vary a lot in Finland. Mostly this is caused by the different bedrock types, which are reflected in the soil qualities. Geological Survey of Finland (GTK) is carrying out geochemical baseline studies in Finland. In the previous phase, the research is focusing on urban areas and mine environments. The information can, for example, be used to determine the need for soil remediation, to assess environmental impacts or to measure the natural state of soil in industrial areas or mine districts. The field work is done by taking soil samples, typically at depth between 0-10 cm. Sampling sites are chosen to represent the most vulnerable areas when thinking of human impacts by possible toxic soil element contents: playgrounds, day-care centers, schools, parks and residential areas. In the mine districts the samples are taken from the areas locating outside the airborne dust effected areas. Element contents of the soil samples are then analyzed with ICP-AES and ICP-MS, Hg with CV-AAS. The results of the geochemical baseline studies are published in the Finnish national geochemical baseline database (TAPIR). The geochemical baseline map service is free for all users via internet browser. Through this map service it is possible to calculate regional soil baseline values using geochemical data stored in the map service database. Baseline data for 17 elements in total is provided in the map service and it can be viewed on the GTK's web pages (http://gtkdata.gtk.fi/Tapir/indexEN.html).

Targeting of Gold Deposits in Amazonian Exploration Frontiers using Knowledge- and Data-Driven Spatial Modeling of Geophysical, Geochemical, and Geological Data

Science.gov (United States)

Magalhães, Lucíola Alves; Souza Filho, Carlos Roberto

2012-03-01

This paper reports the application of weights-of-evidence, artificial neural networks, and fuzzy logic spatial modeling techniques to generate prospectivity maps for gold mineralization in the neighborhood of the Amapari Au mine, Brazil. The study area comprises one of the last Brazilian mineral exploration frontiers. The Amapari mine is located in the Maroni-Itaicaiúnas Province, which regionally hosts important gold, iron, manganese, chromite, diamond, bauxite, kaolinite, and cassiterite deposits. The Amapari Au mine is characterized as of the orogenic gold deposit type. The highest gold grades are associated with highly deformed rocks and are concentrated in sulfide-rich veins mainly composed of pyrrhotite. The data used for the generation of gold prospectivity models include aerogeophysical and geological maps as well as the gold content of stream sediment samples. The prospectivity maps provided by these three methods showed that the Amapari mine stands out as an area of high potential for gold mineralization. The prospectivity maps also highlight new targets for gold exploration. These new targets were validated by means of detailed maps of gold geochemical anomalies in soil and by fieldwork. The identified target areas exhibit good spatial coincidence with the main soil geochemical anomalies and prospects, thus demonstrating that the delineation of exploration targets by analysis and integration of indirect datasets in a geographic information system (GIS) is consistent with direct prospecting. Considering that work of this nature has never been developed in the Amazonian region, this is an important example of the applicability and functionality of geophysical data and prospectivity analysis in regions where geologic and metallogenetic information is scarce.

Microbiological and Geochemical Survey of CO2-Dominated Mofette and Mineral Waters of the Cheb Basin, Czech Republic

Directory of Open Access Journals (Sweden)

Patryk Krauze

2017-12-01

Full Text Available The Cheb Basin (NW Bohemia, Czech Republic is a shallow, neogene intracontinental basin. It is a non-volcanic region which features frequent earthquake swarms and large-scale diffuse degassing of mantle-derived CO2 at the surface that occurs in the form of CO2-rich mineral springs and wet and dry mofettes. So far, the influence of CO2 degassing onto the microbial communities has been studied for soil environments, but not for aquatic systems. We hypothesized, that deep-trenching CO2 conduits interconnect the subsurface with the surface. This admixture of deep thermal fluids should be reflected in geochemical parameters and in the microbial community compositions. In the present study four mineral water springs and two wet mofettes were investigated through an interdisciplinary survey. The waters were acidic and differed in terms of organic carbon and anion/cation concentrations. Element geochemical and isotope analyses of fluid components were used to verify the origin of the fluids. Prokaryotic communities were characterized through quantitative PCR and Illumina 16S rRNA gene sequencing. Putative chemolithotrophic, anaerobic and microaerophilic organisms connected to sulfur (e.g., Sulfuricurvum, Sulfurimonas and iron (e.g., Gallionella, Sideroxydans cycling shaped the core community. Additionally, CO2-influenced waters form an ecosystem containing many taxa that are usually found in marine or terrestrial subsurface ecosystems. Multivariate statistics highlighted the influence of environmental parameters such as pH, Fe2+ concentration and conductivity on species distribution. The hydrochemical and microbiological survey introduces a new perspective on mofettes. Our results support that mofettes are either analogs or rather windows into the deep biosphere and furthermore enable access to deeply buried paleo-sediments.

Technique of uranium exploration in tropical rain forests as applied in Sumatra and other tropical areas

International Nuclear Information System (INIS)

Hahn, L.

1983-01-01

The technique of uranium prospecting in areas covered by tropical rain forest is discussed using a uranium exploration campaign conducted from 1976 to 1978 in Western Sumatra as an example. A regional reconnaissance survey using stream sediment samples combined with radiometric field measurements proved ideal for covering very large areas. A mobile field laboratory was used for the geochemical survey. Helicopter support in diffult terrain was found to be very efficient and economical. A field procedure for detecting low uranium concentrations in stream water samples is described. This method has been successfully applied in Sarawak. To distinguish meaningful uranium anomalies in water from those with no meaning for prospecting, the correlations between U content and conductivity of the water and between U content and Ca and HCO 3 content must be considered. This method has been used successfully in a geochemical survey in Thailand. (author)

The Use of Univariate and Multivariate Analyses in the Geochemical Exploration, Ravanj Lead Mine, Delijan, Iran

Directory of Open Access Journals (Sweden)

Mostafa Nejadhadad

2017-11-01

Full Text Available A geochemical exploration program was applied to recognize the anomalous geochemical haloes at the Ravanj lead mine, Delijan, Iran. Sampling of unweathered rocks were undertaken across rock exposures on a 10 × 10 meter grid (n = 302 as well as the accessible parts of underground mine A (n = 42. First, the threshold values of all elements were determined using the cut-off values used in the exploratory data analysis (EDA method. Then, for further studies, elements with lognormal distributions (Pb, Zn, Ag, As, Cd, Co, Cu, Sb, S, Sr, Th, Ba, Bi, Fe, Ni and Mn were selected. Robustness against outliers is achieved by application of central log ratio transformation to address the closure problems with compositional data prior to principle components analysis (PCA. Results of these analyses show that, in the Ravanj deposit, Pb mineralization is characterized by a Pb-Ba-Ag-Sb ± Zn ± Cd association. The supra-mineralization haloes are characterized by barite and tetrahedrite in a Ba- Th- Ag- Cu- Sb- As- Sr association and sub-mineralization haloes are comprised of pyrite and tetrahedrite, probably reflecting a Fe-Cu-As-Bi-Ni-Co-Mo-Mn association. Using univariate and multivariate geostatistical analyses (e.g., EDA and robust PCA, four anomalies were detected and mapped in Block A of the Ravanj deposit. Anomalies 1 and 2 are around the ancient orebodies. Anomaly 3 is located in a thin bedded limestone-shale intercalation unit that does not show significant mineralization. Drilling of the fourth anomaly suggested a low grade, non-economic Pb mineralization.

Geochemical assessment of light gaseous hydrocarbons in near ...

Indian Academy of Sciences (India)

Light hydrocarbons in soil have been used as direct indicators in geochemical hydrocarbon exploration, which remains an unconventional path in the petroleum industry. The occurrence of adsorbed soil ... Kalpana1 D J Patil1 A M Dayal1. National Geophysical Research Institute, Uppal Road, Hyderabad 500606, India.

Cost-effective geophysical survey systems for uranium exploration

International Nuclear Information System (INIS)

Hasbrouck, J.C.

1981-01-01

When planning a uranium exploration survey the question always arises as to how to take advantage of the different exploration methods and equipment for maximum probability of success. Discussed here are the choice of radiometric geophysical equipment, its effectiveness in identifying targets, its limitations, and the criteria for selection. Particular attention is given to systems that are suitable for the exploration programmes of small size and on a small budget, that are common in Latin America. (author)

The Source, Spatial Distribution and Risk Assessment of Heavy Metals in Soil from the Pearl River Delta Based on the National Multi-Purpose Regional Geochemical Survey.

Science.gov (United States)

Zhang, Lingyan; Guo, Shuhai; Wu, Bo

2015-01-01

The data on the heavy metal content at different soil depths derived from a multi-purpose regional geochemical survey in the Pearl River Delta (PRD) were analyzed using ArcGIS 10.0. By comparing their spatial distributions and areas, the sources of heavy metals (Cd, Hg, As and Pb) were quantitatively identified and explored. Netted measuring points at 25 ×25 km were set over the entire PRD according to the geochemical maps. Based on the calculation data obtained from different soil depths, the concentrations of As and Cd in a large area of the PRD exceeded the National Second-class Standard. The spatial disparity of the geometric centers in the surface soil and deep soil showed that As in the surface soil mainly came from parent materials, while Cd had high consistency in different soil profiles because of deposition in the soil forming process. The migration of Cd also resulted in a considerable ecological risk to the Beijiang and Xijiang River watershed. The potential ecological risk index followed the order Cd ≥ Hg > Pb > As. According to the sources, the distribution trends and the characteristics of heavy metals in the soil from the perspective of the whole area, the Cd pollution should be repaired, especially in the upper reaches of the Xijiang and Beijiang watershed to prevent risk explosion while the pollution of Hg and Pb should be controlled in areas with intense human activity, and supervision during production should be strengthened to maintain the ecological balance of As.

Petroleum exploration in Africa from space

Science.gov (United States)

Gianinetto, Marco; Frassy, Federico; Aiello, Martina; Rota Nodari, Francesco

2017-10-01

Hydrocarbons are nonrenewable resources but today they are the cheaper and easier energy we have access and will remain the main source of energy for this century. Nevertheless, their exploration is extremely high-risk, very expensive and time consuming. In this context, satellite technologies for Earth observation can play a fundamental role by making hydrocarbon exploration more efficient, economical and much more eco-friendly. Complementary to traditional geophysical methods such as gravity and magnetic (gravmag) surveys, satellite remote sensing can be used to detect onshore long-term biochemical and geochemical alterations on the environment produced by invisible small fluxes of light hydrocarbons migrating from the underground deposits to the surface, known as microseepage effect. This paper describes two case studies: one in South Sudan and another in Mozambique. Results show how remote sensing is a powerful technology for detecting active petroleum systems, thus supporting hydrocarbon exploration in remote or hardly accessible areas and without the need of any exploration license.

Geochemical landscapes of the conterminous United States; new map presentations for 22 elements

Science.gov (United States)

Gustavsson, N.; Bolviken, B.; Smith, D.B.; Severson, R.C.

2001-01-01

Geochemical maps of the conterminous United States have been prepared for seven major elements (Al, Ca, Fe, K, Mg, Na, and Ti) and 15 trace elements (As, Ba, Cr, Cu, Hg, Li, Mn, Ni, Pb, Se, Sr, V, Y, Zn, and Zr). The maps are based on an ultra low-density geochemical survey consisting of 1,323 samples of soils and other surficial materials collected from approximately 1960-1975. The data were published by Boerngen and Shacklette (1981) and black-and-white point-symbol geochemical maps were published by Shacklette and Boerngen (1984). The data have been reprocessed using weighted-median and Bootstrap procedures for interpolation and smoothing.

Uruguay mining Inventory: geochemical prospecting results of Cerro de las Cuentas mapping

International Nuclear Information System (INIS)

Spangenberg, J.; Filippini, J.

1986-01-01

This work is about the geochemical prospecting carried out into the Uruguay mining inventory framework. In this case the survey was in Cerro de las Cuentas mapping. Cerro Largo department. Scale 1 / 50000.

Geothermal investigations with isotope and geochemical techniques in Latin America

International Nuclear Information System (INIS)

1992-03-01

The IAEA Co-ordinated Research Programme (CRP) for Latin America on the Use of Isotope and Geochemical Techniques in Geothermal Exploration started in 1984. The first activity carried out was a Seminar on isotope and geochemical techniques in geothermal exploration, which took place in June 1984 in Morelia, Mexico. During the seminar, which was attended by representatives of the institutions which later took part in the programme, the objectives, main research lines, and geothermal fields to be studied during the CRP were discussed. The first research contracts were awarded towards the end of 1984. The field work started in 1985 and continued through 1990. During the implementation of the CRP a considerable number of geothermal fields were studied in the nine participating countries. The investigations carried out were geochemically quite comprehensive in most cases, but in some others they were still in a reconnaissance stage when the CRP ended: the latter studies are not reported in these proceedings, but the data obtained are in principle available from the relevant national institutions. While investigations with conventional geochemical techniques had already started in several fields before 1985, isotope methods were applied for the first time in all cases during this CRP. Due to the remoteness and high elevation of many of the fields studied and the adverse meteorological conditions during long periods of the year, the investigations could not proceed rapidly: this is the main reason for the unusually long duration of the CRP, which could be concluded only after more than five years after its inception

Geochemical exploration for phosphate in the State of Acre

International Nuclear Information System (INIS)

Costa, M.L. da; Melo Costa, W.A. de; Santos, A.J.M. dos

1989-01-01

The geochemical prospecting conducted for phosphates in Acre which could explain the good fertility of the region was charged to discover this material. The phosphates are strictly built of all the bone structures and coprolites of the several fragments of vertebrate fossils, which are widespread in the region. The phosphatic fossils are bedded in the Solimoes Formation, especially its basal to intermediary conglomeratic bed. The fossils are constituted of low crystallinity apatite, and their matrix sediments include quartz, feldspars, smectite, halloysite and calcite. The P 2 O 5 content reaches up to 5% in the sediments and up to 32% in the fragments. The fossils are enriched in U 3 O 8 and rare earth elements. There is no perspect of classic or mineral deposits but the geological knowlwdge will permit the improvement of the use of the soils in Acre. (author) [pt

Introductory study of super survey (next generation underground exploration technology); Super survey (jisedai chika tansa gijutsu) no sendo kenkyu

Energy Technology Data Exchange (ETDEWEB)

NONE

1998-03-01

An investigational study was conducted on the R and D trend of innovative technology aiming at high-accuracy/high-efficiency next generation underground exploration technology (super survey technology). Paying attention to the seismic survey and electromagnetic survey, the study was made on technical characteristics, the utilization status and the needs at sites, the R and D trend, etc. As to the present R and D, the development is proceeded with of the time domain method in the electromagnetic survey, the effective quantity data processing/analysis method and the indication method using the reflection method in the elastic survey. As new technology to be noticed, the following are cited: SQUID magnetometer, underground analysis using magnetic deviation data, electromagnetic migration, ACROSS, rotating seismometer, laser Doppler vibrator, etc. Concerning the course of the next generation underground survey technology, a system of the integrated underground exploration theory is considered which is based on a combination of the electromagnetic survey and seismic exploration. In the study, a plan is worked out for research/development of a technology of analyzing the different data obtained. 49 figs., 13 tabs.

Geochemical sensitivity analysis: Identification of important geochemical parameters for performance assessment studies

International Nuclear Information System (INIS)

Siegel, M.; Guzowski, R.; Rechard, R.; Erickson, K.

1986-01-01

The EPA Standard for geologic disposal of high level waste requires demonstration that the cumulative discharge of individual radioisotopes over a 10,000 year period at points 5 kilometers from the engineered barrier system will not exceed the limits prescribed in 40 CFR Part 191. The roles of the waste package, engineered facility, hydrogeology and geochemical processes in limiting radionuclide releases all must be considered in calculations designed to assess compliance of candidate repositories with the EPA Standard. In this talk, they will discuss the geochemical requirements of calculations used in these compliance assessments. In addition, they will describe the complementary roles of (1) simple models designed to bound the radionuclide discharge over the widest reasonable range of geochemical conditions and scenarios and (2) detailed geochemical models which can provide insights into the actual behavior of the radionuclides in the ground water. Finally, they will discuss development of sensitivity/uncertainty techniques designed to identify important site-specific geochemical parameters and processes using data from a basalt formation

Recent exploration progresses on sandstone-hosted uranium deposits in north-western China

International Nuclear Information System (INIS)

Li, Z.

2014-01-01

The metallogenic target selection using multiple exploration techniques and drilling program for sandstone-hosted uranium deposits have been intensively carried out for recent years, and big progresses on new discoveries of uranium reserve/resource have been made in the Mesozoic sedimentary basins such as in Yili, Ordos etc. in North-western China The Yili basin is a depression one within the Tianshan Mountain belt in the western part of China. Its basement is composed of Proterozoic-Paleozoic metamorphic and sedimentary rocks, and covers of Mesozoic sediments. The early-middle Jurassic Shuixigou Group is major uranium-productive beds which are composed of three Formations such as Badaowan, Sangonghe, Xisanyao and eight sedimentary cycles. Uranium deposits are found in the south margin of the Basin and controlled by the redox zone. The combined exploration techniques of detailed sedimentary facies study, Rn-survey, high-precision magnetic and soil geochemical and seismic surveys have been successfully used to have locate the potential targets and mineralization zones. The enlargement of uranium reserve/resources in the known deposits and new resources in the selected new targets and cycles have been achieved through further drilling programs. The Ordos basin is a large Meso-Cenozoic basin developed in North China Platform, with its size of approximately 250,000 km"2 and is well known as an important “energy resources basin” because of abundance of coal, oil and gas deposits. The Dongsheng sandstone type uranium deposit is a large one discovered in recent years in northeastern Ordos basin. It is a special kind of sandstone type uranium deposit, different from other ordinary sandstone type deposits because of its unique signatures. It is generally controlled by a transitional zone between greenish and grayish sandstones, both of those two kinds of sandstones now indicate reduced geochemical environments. The greenish color of the paleooxidized sandstones mainly

The effect of scale on the interpretation of geochemical anomalies

Science.gov (United States)

Theobald, P.K.; Eppinger, R.G.; Turner, R.L.; Shiquan, S.

1991-01-01

The purpose of geochemical surveys changes with scale. Regional surveys identify areas where mineral deposits are most likely to occur, whereas intermediate surveys identify and prioritize specific targets. At detailed scales specific deposit models may be applied and deposits delineated. The interpretation of regional geochemical surveys must take into account scale-dependent difference in the nature and objectives of this type of survey. Overinterpretation of regional data should be resisted, as should recommendations to restrict intermediate or detailed follow-up surveys to the search for specific deposit types or to a too limited suite of elements. Regional surveys identify metallogenic provinces within which a variety of deposit types and metals are most likely to be found. At intermediate scale, these regional provinces often dissipate into discrete clusters of anomalous areas. At detailed scale, individual anomalous areas reflect local conditions of mineralization and may seem unrelated to each other. Four examples from arid environments illustrate the dramatic change in patterns of anomalies between regional and more detailed surveys. On the Arabian Shield, a broad regional anomaly reflects the distribution of highly differentiated anorogenic granites. A particularly prominent part of the regional anomaly includes, in addition to the usual elements related to the granites, the assemblage of Mo, W and Sn. Initial interpretation suggested potential for granite-related, stockwork Mo deposits. Detailed work identified three separate sources for the anomaly: a metal-rich granite, a silicified and stockwork-veined area with scheelite and molybdenite, and scheelite/powellite concentrations in skarn deposits adjacent to a ring-dike complex. Regional geochemical, geophysical and remote-sensing data in the Sonoran Desert, Mexico, define a series of linear features interpreted to reflect fundamental, northeast-trending fractures in the crust that served as the prime

Isotope and geochemical techniques applied to geothermal investigations. Proceedings of the final research co-ordination meeting held in Dumaguete City, Philippines, 12-15 October 1993

Energy Technology Data Exchange (ETDEWEB)

NONE

1995-02-01

In the last ten years, geothermal energy has emerged as an alternative source of energy for electrical and non-electrical uses. In some of these countries geothermal energy contributed up to 40% of the national power requirement. In others, it is being widely used in agriculture, aquaculture, air conditioning, kiln and fruit drying, pulp and paper industry, greenhouses and food processing. The Co-ordinated Research Programme (CRP) on the Application of Isotope and Geochemical Techniques to Geothermal Exploration in the Middle East, Asia, the Pacific and Africa aimed at integrating isotope techniques with traditional geochemical and hydrological methods in understanding the characteristics of geothermal systems. It involved isotopic and chemical surveys of hot to cold springs, wells and rivers in exploration areas as well as in exploited reservoirs where problems such as return of injected wastewaters are experienced. This publication is a compilation of the scientific papers presented at the final Research Co-ordination Meeting, held in Dumaguete City, Philippines, from 12 to 15 October 1993. Refs, figs and tabs.

Geochemistry and analysis of uranium - an overview; with special reference to geochemical exploration in Malaysia

Energy Technology Data Exchange (ETDEWEB)

Choong, W Y; Seevaratnam, S

1981-01-01

The paper presents discussions of the general chemistry of uranium, its abundance and occurrence, and the geochemistry applications to exploration of uranium in Malaysia in silts vs. water. Methods of analysis at the Geological Survey of Malaysia are fluorimetry for uranium analysis of ores and minerals.

Geochemical correlations between uranium and other components in U-bearing formations of Ogcheon belt

International Nuclear Information System (INIS)

Lee, M.S.; Chon, H.T.

1980-01-01

Some components in uranium-bearing formations which consist mainly of black shale, slate and low grade coal-bearing formation of Ogcheon Belt were processed statistically in order to find out the geochemical correlations with uranium. Geochemical enrichment of uranium, vanadium and molybdenum in low grade coal-bearing formations and surrounding rocks is remarkable in the studied area. Geochemical correlation coefficient of uranium and molybdenum in the rocks displays about 0.6 and that of uranium and fixed carbon about 0.4. Uranium and vanadium in uranium-bearing low grade coals denote very high correlation with fixed carbon, which is considered to be responsible for enrichment of metallic elements, especially molybdenum. Close geochemical correlation of uranium-molybdenum couple in the rocks can be applied as a competent exploration guide to low grade uranium deposits of this area. (author)

Geophysical and geochemical regional evaluation and geophysical model for uranium exploration in the western part of Yanliao region

International Nuclear Information System (INIS)

Liu Tengyao; Cui Huanmin; Chen Guoliang; Zhai Yugui

1992-01-01

The western part of Yanliao region is an important uranium metallogenic region. This paper summarizes the regional geophysical model for uranium exploration composed of prediction model for favourable area of mineralization and evaluation model for anomalies on the basis of aeromagnetic and aeroradiometric data interpretation and analysis of the data from carborane and ground gamma spectrometric survey, high accurate magnetic survey, VLF survey and α-collected film survey in mult-displiary research work. The prospective prediction for uranium metallogenesis in this region was also conducted

A new approach for geochemical surveys of large areas for uranium resource potential

International Nuclear Information System (INIS)

Arendt, J.W.; Butz, T.R.; Cagle, G.W.; Kane, V.E.; Nichols, C.E.

1977-01-01

The Grand Junction, Colorado office of the United States Energy Research and Development Administration (ERDA) is conducting the National Uranium Resource Evaluation Program to evaluate the uranium resources in the United States and Alaska. The program is designed to identify favorable areas for uranium exploration, to assess the supply of domestic resources, and to improve exploration technology. The Nuclear Division of the Union Carbide Corporation has been assigned the responsibility of conducting a hydrogeochemical and stream sediment survey of the mid-continental states in the United States. This survey covers approximately 2,500,000 km 2 (1,000,000 mi 2 ) and includes the states of Texas, Oklahoma, Kansas, Nebraska, South Dakota, North Dakota, Minnesota, Wisconsin, Michigan, Indiana, Illinois, and Iowa. The uranium potential of sandstones, Precambrian conglomerates, veins, granites, and phosphorites is being assessed utliizing a three-part program consisting of pilot surveys in each geological province and two phases of reconnaissance sampling of drainage basins. Samples of stream sediment, stream water, groundwater, algae, and vegetation are analyzed for uranium and some 20 additional elements. Data resulting from this program is released to private industry by ERDA as it becomes available. Analysis of results from a typical three-part survey are given. For distinctive geological regions, the pilot survey will: (1) define characteristic concentration background levels of the elements of interest, (2) identify potential uranium pathfinder elements, (3) determine relationship between stream, stream sediment and botanical samples, (4) identify any necessary modification to field sampling techniques, and (5) determine necessary sensitivities required for chemical analysis. The first reconnaissance phase average sample spacing of one station per 250 km 2 (100 mi 2 ) drainage basin is shown to delineate general boundaries of uranium provinces, and the second

Delineation of geochemical anomalies based on stream sediment data utilizing fractal modeling and staged factor analysis

Science.gov (United States)

Afzal, Peyman; Mirzaei, Misagh; Yousefi, Mahyar; Adib, Ahmad; Khalajmasoumi, Masoumeh; Zarifi, Afshar Zia; Foster, Patrick; Yasrebi, Amir Bijan

2016-07-01

Recognition of significant geochemical signatures and separation of geochemical anomalies from background are critical issues in interpretation of stream sediment data to define exploration targets. In this paper, we used staged factor analysis in conjunction with the concentration-number (C-N) fractal model to generate exploration targets for prospecting Cr and Fe mineralization in Balvard area, SE Iran. The results show coexistence of derived multi-element geochemical signatures of the deposit-type sought and ultramafic-mafic rocks in the NE and northern parts of the study area indicating significant chromite and iron ore prospects. In this regard, application of staged factor analysis and fractal modeling resulted in recognition of significant multi-element signatures that have a high spatial association with host lithological units of the deposit-type sought, and therefore, the generated targets are reliable for further prospecting of the deposit in the study area.

A preliminary report of geochemical investigations in the Blackbird District

Science.gov (United States)

Canney, F.C.; Hawkes, H.E.; Richmond, G.M.; Vhay, J. S.

1953-01-01

This paper reviews an experimental geochemical prospecting survey in the Blackbird cobalt-copper mining district. The district is in east-central Idaho, about 20 miles west-southwest of Salmon. The area is one of deeply weathered nearly flat-topped upland surfaces cut by steep-walled valleys which are tributary to the canyon of Panther Creek. Most of the area has a relatively heavy vegetative cover, and outcrops are scarce except on the sides of the steeper valleys* Because of the importance of the surficial deposits and soils and the physiographic history of the region on the interpretation of the geochemical data, a separate chapter on this subject by Gerald H. Richmond follows the following brief description of the geology of the district.

Regional geochemical prospecting of uranium in the Amazon region

International Nuclear Information System (INIS)

Zenker, A.O.; Hohn, H.

1982-01-01

A regional geochemical prospecting program for uranium in the Serra dos Carajas area, south of Para, was performed by NUCLEBRAS using stream sediment samples obtained from other companies acting in this area. The results of the survey are presented compared to regional geology and an aerial total count map. The different data showed a good correlation, particularly in areas mapped regionally as granitic rocks. (Author) [pt

A comparative study of stream water and stream sediment as geochemical exploration media in the Rio Tanama porphyry copper district, Puerto Rico

Science.gov (United States)

Learned, R.E.; Chao, T.T.; Sanzolone, R.F.

1985-01-01

To test the relative effectiveness of stream water and sediment as geochemical exploration media in the Rio Tanama porphyry copper district of Puerto Rico, we collected and subsequently analyzed samples of water and sediment from 29 sites in the rivers and tributaries of the district. Copper, Mo, Pb, Zn, SO42-, and pH were determined in the waters; Cu, Mo, Pb, and Zn were determined in the sediments. In addition, copper in five partial extractions from the sediments was determined. Geochemical contrast (anomaly-to-background quotient) was the principal criterion by which the effectiveness of the two media and the five extractions were judged. Among the distribution patterns of metals in stream water, that of copper most clearly delineates the known porphyry copper deposits and yields the longest discernable dispersion train. The distribution patterns of Mo, Pb, and Zn in water show little relationship to the known mineralization. The distribution of SO42- in water delineates the copper deposits and also the more extensive pyrite alteration in the district; its recognizable downstream dispersion train is substantially longer than those of the metals, either in water or sediment. Low pH values in small tributaries delineate areas of known sulfide mineralization. The distribution patterns of copper in sediments clearly delineate the known deposits, and the dispersion trains are longer than those of copper in water. The partial determinations of copper related to secondary iron and manganese oxides yield the strongest geochemical contrasts and longest recognizable dispersion trains. Significantly high concentrations of molybdenum in sediments were found at only three sites, all within one-half km downstream of the known copper deposits. The distribution patterns of lead and zinc in sediments are clearly related to the known primary lead-zinc haloes around the copper deposits. The recognizable downstream dispersion trains of lead and zinc are shorter than those of

Exploring Ohio's Private Education Sector. School Survey Series

Science.gov (United States)

Catt, Andrew D.

2014-01-01

Exploring Ohio's Private Education Sector is the second entry in the Friedman Foundation for Educational Choice's "School Survey Series." This report synthesizes information on Ohio's private schools collected by the U.S. Department of Education and the Ohio Department of Education (ODE). Two appendices provide supplementary tables and…

Exploration of the Key Lake uranium deposits, Saskatchewan, Canada

International Nuclear Information System (INIS)

Gatzweiler, R.; Schmeling, B.; Tan, B.

1981-01-01

In 1969, one year after the discovery of the Rabbit Lake uranium deposit, exploration started in the Key Lake area as part of a major uranium rush into Northern Saskatchewan, and within the frame of a joint venture. The area was not chosen on the basis of a particular metallogenetic concept. The lack of exploratory success in 1969 and 1970, together with the introduction in March 1970 of foreign ownership restrictions for uranium mining in Canada, discouraged six of the nine companies forming the original joint venture. In 1971 the three remaining companies decided to continue under a redefined concept, based on the knowledge obtained from the Rabbit Lake deposit (Uranerz had acquired a 49% share in 1970) and from the newly discovered uranium deposits in the Pine Creek Geosyncline, Australia. In the same year, exploration work resulted in the discovery of two high-grade mineralized boulders and significant radioactive and geochemical anomalies 5 km SW of Key Lake deposits. Subsequent exploration, aimed at finding the source of the mineralized boulders, comprised geological, glacial geological and ground radiometric surveys, boulder tracing, air-photo interpretation, lake sediment and muskeg sampling surveys, radon surveys, ground magnetic, gravity, electromagnetic and IP surveys, and drilling. The systematic exploration efforts resulted in the discovery of the Gaertner ore body in July 1975 and the Deilmann ore body in June 1976, where glacial geology, lake sediment sampling, magnetic and electromagnetic surveys were the key methods in defining the drilling targets. Three further years and a total of about 2400 drillholes were needed to fully delineate the two ore bodies. (author)

Reconnaisance geochemical survey of heavy minerals in Northern Luzon, Philippines

International Nuclear Information System (INIS)

Santos, G. Jr.; Seguis, J.E.; Fernandez, L.G.

1983-07-01

A reconnaissance sampling was undertaken in northern Luzon to study the distribution of uranium as well as copper, lead, zinc, manganese, silver, cobalt and nickel in heavy minerals. The average background and threshold values of the elements were determined. Uranium content in the heavy mineral was low, in the order of 0.5-0.6 ppm U. Three uranium anomaly zones were delineated in Malanas Rever-Licuan area, Abra, Itogon, Benguet and Bambang, Nueva Viscaya, all within the Central Cordillera. The anomalous zones appeared to be related to copper-gold mineral areas. Geochemical correlations between uranium and the other elements were generally poor. (author)

Geochemical maps of stream sediments in central Colorado, from New Mexico to Wyoming

Science.gov (United States)

Eppinger, Robert G.; Giles, Stuart A.; Klein, Terry L.

2015-01-01

The U.S. Geological Survey has completed a series of geologic, mineral resource, and environmental assessment studies in the Rocky Mountains of central Colorado, from Leadville eastward to the range front and from New Mexico to the Wyoming border. Regional stream-sediment geochemical maps, useful for assessing mineral resources and environmental effects of historical mining activities, were produced as part of the study. The data portrayed in this 56-parameter portfolio of landscape geochemical maps serve as a geochemical baseline for the region, indicate element abundances characteristic of various lithologic terranes, and identify gross anthropogenic effects of historical mining. However, although reanalyzed in this study by modern, sensitive methods, the majority of the stream-sediment samples were collected in the 1970s. Thus, metal concentrations portrayed in these maps represent stream-sediment geochemistry at the time of collection.

TAPIR--Finnish national geochemical baseline database.

Science.gov (United States)

Jarva, Jaana; Tarvainen, Timo; Reinikainen, Jussi; Eklund, Mikael

2010-09-15

In Finland, a Government Decree on the Assessment of Soil Contamination and Remediation Needs has generated a need for reliable and readily accessible data on geochemical baseline concentrations in Finnish soils. According to the Decree, baseline concentrations, referring both to the natural geological background concentrations and the diffuse anthropogenic input of substances, shall be taken into account in the soil contamination assessment process. This baseline information is provided in a national geochemical baseline database, TAPIR, that is publicly available via the Internet. Geochemical provinces with elevated baseline concentrations were delineated to provide regional geochemical baseline values. The nationwide geochemical datasets were used to divide Finland into geochemical provinces. Several metals (Co, Cr, Cu, Ni, V, and Zn) showed anomalous concentrations in seven regions that were defined as metal provinces. Arsenic did not follow a similar distribution to any other elements, and four arsenic provinces were separately determined. Nationwide geochemical datasets were not available for some other important elements such as Cd and Pb. Although these elements are included in the TAPIR system, their distribution does not necessarily follow the ones pre-defined for metal and arsenic provinces. Regional geochemical baseline values, presented as upper limit of geochemical variation within the region, can be used as trigger values to assess potential soil contamination. Baseline values have also been used to determine upper and lower guideline values that must be taken into account as a tool in basic risk assessment. If regional geochemical baseline values are available, the national guideline values prescribed in the Decree based on ecological risks can be modified accordingly. The national geochemical baseline database provides scientifically sound, easily accessible and generally accepted information on the baseline values, and it can be used in various

Marine Mineral Exploration

DEFF Research Database (Denmark)

in EEZ areas are fairly unknown; many areas need detailed mapping and mineral exploration, and the majority of coastal or island states with large EEZ areas have little experience in exploration for marine hard minerals. This book describes the systematic steps in marine mineral exploration....... Such exploration requires knowledge of mineral deposits and models of their formation, of geophysical and geochemical exploration methods, and of data evaluation and interpretation methods. These topics are described in detail by an international group of authors. A short description is also given of marine...

Uranium exploration methods used by NUCLEBRAS

International Nuclear Information System (INIS)

Santos, L.C.S. dos.

1985-01-01

The main methods used by geologists of NUCLEBRAS in uranium prospecting are presented and described. Severals geologic areas were evaluated based on geologic environments and short local surveys. The efficiency of methods were proved by the results. The steps for uranium prospecting carried out are: geological reconnaissances, aereal surveys, photogeological mappings, geochemical surveys, geological profiles, radiometric surveys, geological mappings, drillings and chemical analysis. (M.C.K.) [pt

Radio spectrometric survey of un-surveyed areas in Syria

International Nuclear Information System (INIS)

Aissa, M.; Al-Hent, R; Jubeli, Y.

2002-11-01

The values and distribution of the radioelements e U, e Th, % K and Ur units in the surface geological formations of the west and south sectors of Syrian region, were estimated using carbone gamma ray spectrometric survey. The radiometric maps were prepared, as well as, many geological profiles, cross sections studied in different locations and geochemical samples were analyzed by laboratory gamma ray spectrometry and by x-ray diffractometry, the results of the all sets were compared. In general, the survey shows, low radioelement concentrations in the area, especially on basic rocks (Jabal Al-arab, Hawran) south Syria, and on ultra basic rocks (ophiolitic complex) north-west Syria, but there are some separate anomalous spots were connected with phosphate rocks, detected on cretaceous and Palaeogene age. Some times we noticed high radioelement concentrations haloes associated with fractured zones were already arise from secondary uranium mineralization, as a result of solutions movement through fissures in carbonatic and/or chalk like limestone rocks. finally, the obtained concentrations, represent a background values which has no significant importance for uranium exploration point of view. (author)

Geochemical survey of an illegal waste disposal site under a waste emergency scenario (Northwest Naples, Italy).

Science.gov (United States)

Ferrara, L; Iannace, M; Patelli, A M; Arienzo, M

2013-03-01

Since the mid 1980s, Naples and the Campania region have suffered from the dumping of wastes into overfilled landfills. The aim was to characterise a former cave located in Roccarainola (Naples, Italy) for its eventual destination to a controlled landfill site. A detailed hydro-geochemical survey of the area was carried out through drilling of 14 boreholes and four monitoring wells. Samples of water, sediment and soil were analysed for heavy metals and organic contaminants from a dew pond placed in the middle of the cave. The underneath aquifer was also surveyed. The nature of gases emitted from the site was investigated. Results of the geognostic survey revealed the presence of huge volumes of composite wastes, approximately half a million of cubic metre, which accumulated up to a thickness of 25.6 m. In some points, wastes lie below the free surface level of the aquifer. The sampled material from the boreholes revealed levels of As, Cd, Cr, Cu, Hg, Pb, Sn, Tl and Zn exceeding the intervention legal limits. Outstanding loads of Cd, Pb and Zn were found, with levels exceeding of about 50, 100 and 1,870 times the limit. In several points, polycyclic aromatic hydrocarbon load was extremely high, 35 vs 1 mg kg(-1) of the threshold. The aquifer was also very heavily polluted by Cd, Cr-tot, Cu, Fe, Mn, Ni, Pb and Zn, with impressive high load of Cr and Mn, up to 250-370 times the limits. Hot gases up to 62 °C with presence of xylene and ethylbenzene were found. Results indicated that the site needs an urgent intervention of recovery to avoid compromising the surrounding areas and aquifers of the Campania plain.

Exploring community pharmacists' experiences of surveying patients for drug utilization research purposes

DEFF Research Database (Denmark)

Frisk, Pia; Bergman, Ulrika; Kälvemark Sporrong, Sofia

2015-01-01

pharmacists. This study is part of a validation of that data acquisition method. Objectives (1) To explore the experiences of the pharmacists involved, (2) to explore a random or systematic exclusion of eligible patients by the pharmacists, and (3) to find areas of improvement to the applied method...... of surveying. Setting 72 Swedish community pharmacies, distributed all over the country. Method (a) A questionnaire was distributed to approximately 400 dispensing pharmacists at the pharmacies conducting the patient surveys; (b) semi-structured telephone interviews conducted with 19 pharmacists at 12...... of the pharmacies. Main outcome measure Proportions of pharmacists reporting positive and negative experiences of structured survey interviews, the nature of their experiences, proportion of pharmacists reporting to avoid survey interviews and reasons for doing so, and suggested areas of improvement. Results...

Heavy mineral survey for rare earths in the Northern part of Palawan

International Nuclear Information System (INIS)

Reyes, R.Y.; Santos, G.P.; Magsambol, W.N.; Ramos, A.F.; Petrache, C.A.; Tabora, E.U.

1992-01-01

A reconnaissance geochemical survey for rare earths was carried out over the northern half of Palawan with considerable success. The survey represents the first systematic geochemical exploration effort to look for indigenous rare earth resources in the Philippines. Total area covered was about 5,000 sq km. The survey entailed the systematic collection of 740 heavy mineral panned concentrate and stream sediment samples along streams and rivers. The average sampling density was about one set of sample per 2-15 sq km. A total of 218 heavy mineral samples were analyzed for lathanum, cerium, praseodymium, neodymium and yttrium. Analysis of stream sediments for rare earths was discontinued due to the high detection limit of the X-ray fluorescence spectrometer. Results of the survey clearly indicated the effectiveness of heavy mineral sampling for rare earths at the reconnaissance level of exploration. Six anomalous and well-defined areas of interest were delineated for possible rare earth mineralization. Three priority zones were further outlined from the six prospective areas for possible follow-up surveys. Mineralogical examination of heavy minerals revealed the presence of major allanite and minor monazite as the potential hosts of rare earths in the priority zone number one. Gray monazite was identified in the priority zone number two as the rare earth mineral. Minute specks and grains of gold were visibly present in some of the heavy mineral samples taken in this area. A combined mineralization of rare earths and gold in this area is a possibility. The discovery of the first gray nodular monazite in Palawan may extend the age of the oldest rocks in the Philippines to Lower Paleozoic. A separate study to establish the age of the oldest rocks in the country is likewise necessary. (auth.). 27 refs.; 6 figs.; 8 tabs

Geochemical Characterization of the Upper and Middle Floridan Aquifer System, South Florida

Science.gov (United States)

Mirecki, J.; Richardson, E.; Bennett, M.; Hendel, J.

2008-05-01

Our study focus is to characterize the water quality and geochemical environment of the Floridan Aquifer System (FAS) throughout the regional flowpath. A synoptic survey of 21 wells (n=15, upper FAS; n=6 middle FAS) was supplemented by additional samples (n=11) obtained during exploratory well development at 4 aquifer storage recovery (ASR) pilot sites. Synoptic survey samples were analyzed intensively, yielding a dataset that consists of major and trace dissolved constituents (including metals), stable isotopes (δ18O, δ13C, δD, δ34S in sulfate and sulfide), carbon species (carbonate alkalinity and organic carbon), uranium-series radionuclides, nutrients, and selected microbes and pathogens. The objectives of this study are three-fold: 1) to provide baseline water-quality and geochemical information prior to initiation of ASR activities that are part of the Comprehensive Everglades Restoration Plan; 2) to quantify the major controls on geochemical evolution along upper and middle FAS flowpaths using geochemical modeling methods; and 3) to identify areas where water- quality may limit the feasibility of ASR methods in the FAS. Preliminary interpretations water quality changes along the regional FAS flowpath can be summarized as follows. Concentrations of dissolved constituents increase from north to south along the flow path; generally, the upper FAS has lower total dissolved solids than the middle FAS at locations where well pairs were analyzed. The redox environment changes from oxic to strongly anoxic, very close to the recharge area. Redox measurements, dissolved iron, sulfide, and sulfur isotope data are consistent with sulfate-reducing conditions. Uranium-series isotope concentrations and activities generally are below regulatory criteria, with few exceptions in both the upper and middle FAS. Areas with greater radionuclide activity occur primarily at distal flowpath locations or at the coast.

Geologic and geochemical studies of the New Albany Shale Group (Devonian-Mississippian) in Illinois. Final report

Energy Technology Data Exchange (ETDEWEB)

Bergstrom, R.E.; Shimp, N.F.

1980-06-30

The Illinois State Geological Survey is conducting geological and geochemical investigations to evaluate the potential of New Albany Group shales as a source of hydrocarbons, particularly natural gas. Geological studies include stratigraphy and structure, mineralogic and petrographic characterization; analyses of physical properties; and development of a computer-based resources evaluation system. Geochemical studies include organic carbon content and trace elements; hydrocarbon content and composition; and adsorption/desorption studies of gas through shales. Separate abstracts have been prepared for each task reported.

Uranium exploration in Central and Eastern Macedonia and Thrace (Greece)

International Nuclear Information System (INIS)

Kampanellos, John; Persianis, Demetrios.

1985-01-01

In accordance with the Greek AEC Project for Uranium Exploration in Central and Eastern Macedonia and Thrace (Greece) car-borne scintillometer, ground scintillometer and geochemical stream sediment surveys along with reconnaissance geological mapping have been carried out within the area of map sheets 2623(II,III)-2622 (Feres-Lefkimmi, Evros Dept., Thrace). The results of these surveys, presented in a series of 15 maps, indicate that three areas totalling 380 km 2 require further detailed examination in order to test their potential of economic uranium deposits. Of these areas Kotronia and Dadia-Nipsa-Loutros covering 325 km 2 should be given first priority and be further investigated by detailed stream sediment and bank soil sampling, detailed ground scintillometer measurements, grid soil and radon soil gas samplings, as well as by detailed geological mapping. (author)

Coupled geochemical and solute transport code development

International Nuclear Information System (INIS)

Morrey, J.R.; Hostetler, C.J.

1985-01-01

A number of coupled geochemical hydrologic codes have been reported in the literature. Some of these codes have directly coupled the source-sink term to the solute transport equation. The current consensus seems to be that directly coupling hydrologic transport and chemical models through a series of interdependent differential equations is not feasible for multicomponent problems with complex geochemical processes (e.g., precipitation/dissolution reactions). A two-step process appears to be the required method of coupling codes for problems where a large suite of chemical reactions must be monitored. Two-step structure requires that the source-sink term in the transport equation is supplied by a geochemical code rather than by an analytical expression. We have developed a one-dimensional two-step coupled model designed to calculate relatively complex geochemical equilibria (CTM1D). Our geochemical module implements a Newton-Raphson algorithm to solve heterogeneous geochemical equilibria, involving up to 40 chemical components and 400 aqueous species. The geochemical module was designed to be efficient and compact. A revised version of the MINTEQ Code is used as a parent geochemical code

The Validity of a German Version of the Career Exploration Survey

Science.gov (United States)

Rowold, Jens; Staufenbiel, Kathrin

2010-01-01

This paper reports psychometric properties of a German version of the Career Exploration Survey (CES-G). The instrument's 16 scales allow for a detailed description of career exploration. Based on data from two studies (N[subscript 1] = 1023; N[subscript 2] = 816), confirmatory factor analyses supported the 16-factor model. With regard to…

The role of GIS in spatial modeling of multi-disciplinary geoscientific data for uranium exploration over the Kunjar-Darjing basin, Odisha

International Nuclear Information System (INIS)

Chaturvedi, Anand Kumar; Veldi, Ramesh Babu; Amulotu, Markandeyulu; Chaki, Anjan; Pavanaguru, R.

2015-01-01

Application of Geographical Information System (GIS) for identifying the spatial locations of uranium exploration target areas using multi-disciplinary geoscientific data is presented in this paper. The data sets used in this study are Airborne Gamma Ray Spectrometric (AGRS), Aeromagnetic (AM), Satellite images, regional ground gravity and geochemical surveys over one of the promising mobile Proterozoic Kunjar-Darjing Basins to the west of Singhbum Uranium Province (SUP), Odisha, India. Analysis of the geochemical data indicated unconformity related uranium mineralization along the unconformity between Kunjar-Darjing sediments and the S-type per-aluminous Tamparkola granite with labile uranium. All the data sets are processed and interpreted independently in terms of geology based on characteristics such as intensity, frequency and texture of the images generated. Various ratio maps generated from AGRS data were used as training points for spatial modeling by building relationships (topology) with the structures and geology interpreted from the magnetic and gravity datasets. Index overlay method is adapted in spatial modeling. The study shows that integrating the geological, geophysical, geochemical and other geodata in a GIS environment provides valuable guidelines for geological mapping as well as identifying target areas for uranium exploration. The GIS study facilitated in identifying potential target areas for uranium exploration along the regional faults D1 and D2 around the villages Kelo, Tarnra, northeast of Kunjar, Nuarali and Betajharan. (author)

Modeling background radiation using geochemical data: A case study in and around Cameron, Arizona.

Science.gov (United States)

Marsac, Kara E; Burnley, Pamela C; Adcock, Christopher T; Haber, Daniel A; Malchow, Russell L; Hausrath, Elisabeth M

2016-12-01

This study compares high resolution forward models of natural gamma-ray background with that measured by high resolution aerial gamma-ray surveys. The ability to predict variations in natural background radiation levels should prove useful for those engaged in measuring anthropogenic contributions to background radiation for the purpose of emergency response and homeland security operations. The forward models are based on geologic maps and remote sensing multi-spectral imagery combined with two different sources of data: 1) bedrock geochemical data (uranium, potassium and thorium concentrations) collected from national databases, the scientific literature and private companies, and 2) the low spatial resolution NURE (National Uranium Resource Evaluation) aerial gamma-ray survey. The study area near Cameron, Arizona, is located in an arid region with minimal vegetation and, due to the presence of abandoned uranium mines, was the subject of a previous high resolution gamma-ray survey. We found that, in general, geologic map units form a good basis for predicting the geographic distribution of the gamma-ray background. Predictions of background gamma-radiation levels based on bedrock geochemical analyses were not as successful as those based on the NURE aerial survey data sorted by geologic unit. The less successful result of the bedrock geochemical model is most likely due to a number of factors including the need to take into account the evolution of soil geochemistry during chemical weathering and the influence of aeolian addition. Refinements to the forward models were made using ASTER visualizations to create subunits of similar exposure rate within the Chinle Formation, which contains multiple lithologies and by grouping alluvial units by drainage basin rather than age. Copyright © 2016 The Authors. Published by Elsevier Ltd.. All rights reserved.

Neutron activation analysis of geochemical samples

International Nuclear Information System (INIS)

Rosenberg, R.; Zilliacus, R.; Kaistila, M.

1983-06-01

The present paper will describe the work done at the Technical Research Centre of Finland in developing methods for the large-scale activation analysis of samples for the geochemical prospecting of metals. The geochemical prospecting for uranium started in Finland in 1974 and consequently a manually operated device for the delayed neutron activation analysis of uranium was taken into use. During 1974 9000 samples were analyzed. The small capacity of the analyzer made it necessary to develop a completely automated analyzer which was taken into use in August 1975. Since then 20000-30000 samples have been analyzed annually the annual capacity being about 60000 samples when running seven hours per day. Multielemental instrumental neutron activation analysis is used for the analysis of more than 40 elements. Using instrumental epithermal neutron activation analysis 25-27 elements can be analyzed using one irradiation and 20 min measurement. During 1982 12000 samples were analyzed for mining companies and Geological Survey of Finland. The capacity is 600 samples per week. Besides these two analytical methods the analysis of lanthanoids is an important part of the work. 11 lanthanoids have been analyzed using instrumental neutron activation analysis. Radiochemical separation methods have been developed for several elements to improve the sensitivity of the analysis

Some results of NURE uranium geochemical studies

International Nuclear Information System (INIS)

Price, V. Jr.

1979-01-01

Some technical developments of the National Uranium Resource Evaluation Program which are of general application in geochemical exploration are being studied. Results of stream water and suspended and bottom sediment analyses are compared for an area near Williamsport, Pennsylvania. Variations of uranium content of water samples with time in the North Carolina Piedmont are seen to correlate with rainfall. Ground water samples from coastal and piedmont areas were analyzed for helium. All media sampled provide useful information when properly analyzed and interpreted as part of a total geological analysis of an area

Stand-off laser-induced breakdown spectroscopy of aluminum and geochemical reference materials at pressure below 1 torr

Energy Technology Data Exchange (ETDEWEB)

Lee, Kang-Jae; Choi, Soo-Jin; Yoh, Jack J., E-mail: jjyoh@snu.ac.kr

2014-11-01

Laser-induced breakdown spectroscopy (LIBS) is an atomic emission spectroscopy that utilizes a highly irradiated pulse laser focused on the target surface to produce plasma. We obtain spectroscopic information from the microplasma and determine the chemical composition of the sample based on its elemental and molecular emission peaks. We develop a stand-off LIBS system to analyze the effect of the remote sensing of aluminum and various geochemical reference materials at pressures below 1 torr. Using a commercial 4 inch refracting telescope, our stand-off LIBS system is configured at a distance of 7.2 m from the four United States Geological Survey (USGS) geochemical samples that include granodiorite, quartz latite, shale-cody, and diabase, which are selected for planetary exploration. Prepared samples were mixed with a paraffin binder containing only hydrogen and carbon, and were pelletized for experimental convenience. The aluminum plate sample is considered as a reference prior to using the geochemical samples in order to understand the influence of a low pressure condition on the resulting LIBS signal. A Q-switched Nd:YAG laser operating at 1064 nm and pulsed at 10 Hz with 21.7 to 48.5 mJ/pulse was used to obtain signals, which showed that the geochemical samples were successfully detected by the present stand-off detection scheme. A low pressure condition generally results in a decrease of the signal intensity, while the signal to noise ratio can vary according to the samples and elements of various types. We successfully identified the signals at below 1 torr with stand-off detection by a tightly focused light detection and by using a relatively larger aperture telescope. The stand-off LIBS detection at low pressure is promising for potential detection of the minor elements at pressures below 1 torr. - Highlights: • Stand-off LIBS signals at below 1 torr are compared to those of in-situ conditions. • Vacuum condition provides easier detection of the

Manual hierarchical clustering of regional geochemical data using a Bayesian finite mixture model

International Nuclear Information System (INIS)

Ellefsen, Karl J.; Smith, David B.

2016-01-01

Interpretation of regional scale, multivariate geochemical data is aided by a statistical technique called “clustering.” We investigate a particular clustering procedure by applying it to geochemical data collected in the State of Colorado, United States of America. The clustering procedure partitions the field samples for the entire survey area into two clusters. The field samples in each cluster are partitioned again to create two subclusters, and so on. This manual procedure generates a hierarchy of clusters, and the different levels of the hierarchy show geochemical and geological processes occurring at different spatial scales. Although there are many different clustering methods, we use Bayesian finite mixture modeling with two probability distributions, which yields two clusters. The model parameters are estimated with Hamiltonian Monte Carlo sampling of the posterior probability density function, which usually has multiple modes. Each mode has its own set of model parameters; each set is checked to ensure that it is consistent both with the data and with independent geologic knowledge. The set of model parameters that is most consistent with the independent geologic knowledge is selected for detailed interpretation and partitioning of the field samples. - Highlights: • We evaluate a clustering procedure by applying it to geochemical data. • The procedure generates a hierarchy of clusters. • Different levels of the hierarchy show geochemical processes at different spatial scales. • The clustering method is Bayesian finite mixture modeling. • Model parameters are estimated with Hamiltonian Monte Carlo sampling.

Computer analysis to the geochemical of soil and stream sediments data in an area of Southern Uruguay

International Nuclear Information System (INIS)

Spangenberg, J.

2012-01-01

This work is about geochemical interpretation of multi-element data from a soil and stream sediment survey carried out in Southern of Uruguay .This zone has several occurrences of metal sulphide mineralization

Uranium exploration in Central and Eastern Macedonia and Thrace (Greece)

International Nuclear Information System (INIS)

Kampanellos, John; Persianis, Demetrios.

1986-02-01

In accordance with the Greek AEC Project for Uranium Exploration in Central and Eastern Macedonia and Thrace (Greece) car-borne scintillometer, ground scintillometer and geochemical stream sediment surveys along with reconnaissance geological mapping have been carried out within the area of map sheets 2523-2522 (Alexandroupolis-Aesymi, Evros Dept., Thrace). The results of these surveys, presented in a series of 15 maps, indicate that five areas totalling 632 km 2 require further detailed examination in order to test their potential of economic uranium deposits. Of these areas Nea Santa-Kechros-Chloi-Goniko-Kallithea-Leptokarya, Kirki-Kizari-Aesymi and Drosia-Fillyra-Darmeni should be given first priority and be further investigated by detailed stream sediment and bank soil sampling, detailed ground scintillometer measurements, grid soil and radon soil gas samplings, as well as by detailed geological mapping. (author)

Geochemical survey maps of the wildernesses and roadless areas in the White Mountains National Forest, Coos, Grafton, and Carroll counties, New Hampshire

Science.gov (United States)

Canney, F.C.; Howd, F.H.; Domenico, J.A.; Nakagawa, H.M.

1987-01-01

The Wilderness Act (Public Law 88-577, September 3, 1964) and related acts require the U.S. Geological Survey and the U.S. Bureau of Mines to survey certain areas on Federal lands to determine what mineral values, if any, may be present. Results must be made available to the public and be submitted to the President and the Congress. This report presents the results a geochemical survey of the Great Gulf and Presidential Range-Dry River Wilderness Areas; the Dartmouth Range, Wild River, Pemigewasset, Kinsman Mountain, Mount Wolf-Gordon Pond, Jobildunk, Carr Mountain, Sandwich Range, and the Dry River Extention (2 parcels) Roadless Areas; and the intervening and immediately surrounding areas in the White Mountain National Forest, Coos, Grafton, and Carroll Counties, New Hampshire. The Great Gulf Wilderness was established when the Wilderness Act was passed in 1964, and the Presidential Range-Dray Wiver Wilderness was established by Public Law 93-622, January 3, 1975. The Dartmouth Range, Wild River, Pemigewasset, Kinsman Mountain, Mount Wolf-Gordon Pond, Carr Mountain, and Jobildunk areas were classified as a further planning area during the Second Roadless Area Review and Evaluation (RARE II) by the U.S. Forest Service, January 1979.

Proceedings of the workshop on geochemical modeling

International Nuclear Information System (INIS)

1986-01-01

The following collection of papers was presented at a workshop on geochemical modeling that was sponsored by the Office of Civilian Radioactive Waste Management Program at the Lawrence Livermore National Laboratory (LLNL). The LLNL Waste Management Program sponsored this conference based on their belief that geochemical modeling is particularly important to the radioactive waste disposal project because of the need to predict the consequences of long-term water-rock interactions at the proposed repository site. The papers included in this volume represent a subset of the papers presented at the Fallen Leaf Lake Conference and cover a broad spectrum of detail and breadth in a subject that reflects the diverse research interests of the conference participants. These papers provide an insightful look into the current status of geochemical modeling and illustrate how various geochemical modeling codes have been applied to problems of geochemical interest. The emphasis of these papers includes traditional geochemical modeling studies of individual geochemical systems, the mathematical and theoretical development and refinement of new modeling capabilities, and enhancements of data bases on which the computations are based. The papers in this proceedings volume have been organized into the following four areas: Geochemical Model Development, Hydrothermal and Geothermal Systems, Sedimentary and Low Temperature Environments, and Data Base Development. The participants of this symposium and a complete list of the talks presented are listed in the appendices

Proceedings of the workshop on geochemical modeling

Energy Technology Data Exchange (ETDEWEB)

1986-01-01

The following collection of papers was presented at a workshop on geochemical modeling that was sponsored by the Office of Civilian Radioactive Waste Management Program at the Lawrence Livermore National Laboratory (LLNL). The LLNL Waste Management Program sponsored this conference based on their belief that geochemical modeling is particularly important to the radioactive waste disposal project because of the need to predict the consequences of long-term water-rock interactions at the proposed repository site. The papers included in this volume represent a subset of the papers presented at the Fallen Leaf Lake Conference and cover a broad spectrum of detail and breadth in a subject that reflects the diverse research interests of the conference participants. These papers provide an insightful look into the current status of geochemical modeling and illustrate how various geochemical modeling codes have been applied to problems of geochemical interest. The emphasis of these papers includes traditional geochemical modeling studies of individual geochemical systems, the mathematical and theoretical development and refinement of new modeling capabilities, and enhancements of data bases on which the computations are based. The papers in this proceedings volume have been organized into the following four areas: Geochemical Model Development, Hydrothermal and Geothermal Systems, Sedimentary and Low Temperature Environments, and Data Base Development. The participants of this symposium and a complete list of the talks presented are listed in the appendices.

Central Colorado Assessment Project (CCAP)-Geochemical data for rock, sediment, soil, and concentrate sample media

Science.gov (United States)

Granitto, Matthew; DeWitt, Ed H.; Klein, Terry L.

2010-01-01

This database was initiated, designed, and populated to collect and integrate geochemical data from central Colorado in order to facilitate geologic mapping, petrologic studies, mineral resource assessment, definition of geochemical baseline values and statistics, environmental impact assessment, and medical geology. The Microsoft Access database serves as a geochemical data warehouse in support of the Central Colorado Assessment Project (CCAP) and contains data tables describing historical and new quantitative and qualitative geochemical analyses determined by 70 analytical laboratory and field methods for 47,478 rock, sediment, soil, and heavy-mineral concentrate samples. Most samples were collected by U.S. Geological Survey (USGS) personnel and analyzed either in the analytical laboratories of the USGS or by contract with commercial analytical laboratories. These data represent analyses of samples collected as part of various USGS programs and projects. In addition, geochemical data from 7,470 sediment and soil samples collected and analyzed under the Atomic Energy Commission National Uranium Resource Evaluation (NURE) Hydrogeochemical and Stream Sediment Reconnaissance (HSSR) program (henceforth called NURE) have been included in this database. In addition to data from 2,377 samples collected and analyzed under CCAP, this dataset includes archived geochemical data originally entered into the in-house Rock Analysis Storage System (RASS) database (used by the USGS from the mid-1960s through the late 1980s) and the in-house PLUTO database (used by the USGS from the mid-1970s through the mid-1990s). All of these data are maintained in the Oracle-based National Geochemical Database (NGDB). Retrievals from the NGDB and from the NURE database were used to generate most of this dataset. In addition, USGS data that have been excluded previously from the NGDB because the data predate earliest USGS geochemical databases, or were once excluded for programmatic reasons

Vertical Cable Seismic Survey for SMS exploration

Science.gov (United States)

Asakawa, Eiichi; Murakami, Fumitoshi; Tsukahara, Hotoshi; Mizohata, Shigeharu

2014-05-01

hundred meters. Our VCS system has been demonstrated as a promising survey tool for the SMS exploration.

Historical reconstruction of oil and gas spills during moderate and strong earthquakes and related geochemical surveys in Southern Apennines

Science.gov (United States)

Sciarra, Alessandra; Cantucci, Barbara; Ferrari, Graziano; Pizzino, Luca; Quattrocchi, Fedora

2016-04-01

The aim of this study is to contribute to the assessment of natural hazards in a seismically active area of southern Italy through the joint analysis of historical sources and fluid geochemistry. In particular, our studies have been focalized in the Val d'Agri basin, in the Apennines extensional belt, since it hosts the largest oilfield in onshore Europe and normal-fault systems with high seismogenic potential (up to M7). The work was organized into three main themes: 1) literature search aimed at identifying fluid emissions during previous moderate-strong earthquakes; 2) consultation of local and national archives to identify historic local place names correlated to natural fluids emissions; 3) geochemical sampling of groundwater and gas issuing at surface, identified on the basis of the bibliographic sources. A reasoned reading of written documents and available historical data was performed. Moreover, we reworked information reported in historical catalogues, referred to liquid and gas hydrocarbon leakages occurred during seismic events of the past (in a range of magnitude from 5 to 7) in the Southern Apennines (with a particular focus on the Val d'Agri). Special attention was given to the phenomena of geochemical emissions related to major historical earthquakes that took place in the area, most notably that of 16 December 1857 (M = 7). A careful analysis of the Robert Mallet's report, a complete work aimed at describing the social impact and the effects on the environment produced by this earthquake through illustrated maps and diagrams, included several hundred monoscopic and stereoscopic photographs, was done. From archival sources (at national and/or local administrations), "sensitive" sites to the onset of leakage of liquid and gaseous hydrocarbons in the past were identified. A soil-gas survey (22 gas concentrations and flux measurements) and 35 groundwater samplings were carried out in specific sites recognized through the above studies. From a

Uranium exploration in Bangladesh

International Nuclear Information System (INIS)

Faruquee, A.R.

1988-01-01

The sedimentary succession of Bangladesh has continental sandstones with lignite and organic matter which are favourable host rocks for sedimentary uranium. The shield areas around Bangladesh are considered good source areas for uranium. Encouraged by this idea, the Bangladesh Atomic Energy Commission (BAEC) started an exploration programme in 1976 with the assistance of the IAEA and the United Nations Development Programme. Preliminary reconnaissance radiometric surveys carried out in 1976-1977 in the Chittagong, Chittagong hill tract and Sylhet districts identified some anomalies with 3 to 5 times the background (XBG). This was followed by regional reconnaissance radiometric surveys which were carried out between 1977 and 1985 in some of the anticlines of the Chittagong and Sylhet districts, including an airborne (helicopter) survey over the Jaldi area. These surveys resulted in the discovery of more than 300 radiometric anomalies of 3 to 60 XBG. They occur in the medium to fine grained ferruginous sandstones of the Dupitila and Tipam Formations of Mio-Pliocene age. These anomalous beds show variation in slime and heavy mineral contents. Some samples collected from the anomalous beds contain uranium and thorium ranging from 20 to 100 ppm and 100 to 1000 ppm, respectively. Exploratory drilling to a depth of about 400 ft was carried out on a very limited scale in the northeastern part of the Sylhet district. Gamma logging of these holes indicated many subsurface anomalies (3 to 21 XBG) in the Dupitila Formation. These anomalies are linked to thin layers with restricted lateral extensions. Geochemical orientation studies and radon surveys were done in some selected areas of Sylhet to test their suitability for further surveys. 9 refs, 13 figs, 4 tabs

Hydrogeochemical and stream sediment detailed geochemical survey for Thomas Range-Wasatch, Utah. Farmington Project area

International Nuclear Information System (INIS)

Butz, T.R.; Bard, C.S.; Witt, D.A.; Helgerson, R.N.; Grimes, J.G.; Pritz, P.M.

1980-01-01

Results of the Farmington project area of the Thomas Range-Wasatch detailed geochemical survey are reported. Field and laboratory data are presented for 71 groundwater samples, 345 stream sediment samples, and 178 radiometric readings. Statistical and areal distributions of uranium and possible uranium-related variables are given. A generalized geologic map of the project area is provided, and pertinent geologic factors which may be of significance in evaluating the potential for uranium mineralization are briefly discussed. Uranium concentrations in groundwater range from <0.20 to 21.77 ppB. The highest values are from groundwaters producing from areas in or near the Norwood Tuff and Wasatch, Evanston, and/or Echo Canyon Formations, and the Farmington Canyon Complex. The uranium:boron ratio delineates an anomalous trend associated with the Farmington Canyon Complex. Variables associated with uranium in groundwaters producing from the Norwood Tuff and Wasatch, Evanston, and/or Echo Canyon Formations include the uranium:sulfate ratio, boron, barium, potassium, lithium, silicon, chloride, selenium, and vanadium. Soluble uranium concentrations (U-FL) in stream sediments range from 0.99 to 86.41 ppM. Total uranium concentrations (U-NT) range from 1.60 to 92.40 ppM. Thorium concentrations range from <2 to 47 ppM. Anomalous concentrations of these variables are associated with the Farmington Canyon Complex. Variables which are associated with uranium include cerium, sodium, niobium, phosphorus, titanium, and yttrium

History and progress of the North American Soil Geochemical Landscapes Project, 2001-2010

Science.gov (United States)

Smith, David B.; Cannon, William F.; Woodruff, Laurel G.; Rivera, Francisco Moreira; Rencz, Andrew N.; Garrett, Robert G.

2012-01-01

In 2007, the U.S. Geological Survey, the Geological Survey of Canada, and the Mexican Geological Survey initiated a low-density (1 site per 1600 km2, 13323 sites) geochemical and mineralogical survey of North American soils (North American Soil Geochemical Landscapes Project). Sampling and analytical protocols were developed at a series of workshops in 20032004 and pilot studies were conducted from 20042007. The ideal sampling protocol at each site includes a sample from 05 cm depth, a composite of the soil A horizon, and a sample from the soil C horizon. The 3, HClO4, and HF. Separate methods are used for As, Hg, Se, and total C on this same size fraction. The major mineralogical components are determined by a quantitative X-ray diffraction method. Sampling in the conterminous U.S. was completed in 2010 (c. 4800 sites) with chemical and mineralogical analysis currently underway. In Mexico, approximately 66% of the sampling (871 sites) had been done by the end of 2010 with completion expected in 2012. After completing sampling in the Maritime provinces and portions of other provinces (472 sites, 7.6% of the total), Canada withdrew from the project in 2010. Preliminary results for a swath from the central U.S. to Florida clearly show the effects of soil parent material and climate on the chemical and mineralogical composition of soils. A sample archive will be established and made available for future investigations.

Possible uses of geochemical and isotopical investigations of ground waters in oil and gas prospecting

International Nuclear Information System (INIS)

Mercado, A.; Kahanovitz, Y.

1978-07-01

This work describes the use of geochemical investigation of ground waters for finding deep organic accumulations. It is based on the identification of abnormal values of chemical and isotopical parameters: bicarbonates, CO 2 , sulfates, carbon 13 and carbon 14. Further improvements will make this method a useful tool in oil and gas prospecting and detection as well as in the detection of geochemical anomalies. The advantages of the method are its low cost and relative rapidity; the disadvantage is that it can be carried out only when water sources are present in the exploration field. (B.G.)

Geochemical computer codes. A review

International Nuclear Information System (INIS)

Andersson, K.

1987-01-01

In this report a review of available codes is performed and some code intercomparisons are also discussed. The number of codes treating natural waters (groundwater, lake water, sea water) is large. Most geochemical computer codes treat equilibrium conditions, although some codes with kinetic capability are available. A geochemical equilibrium model consists of a computer code, solving a set of equations by some numerical method and a data base, consisting of thermodynamic data required for the calculations. There are some codes which treat coupled geochemical and transport modeling. Some of these codes solve the equilibrium and transport equations simultaneously while other solve the equations separately from each other. The coupled codes require a large computer capacity and have thus as yet limited use. Three code intercomparisons have been found in literature. It may be concluded that there are many codes available for geochemical calculations but most of them require a user that us quite familiar with the code. The user also has to know the geochemical system in order to judge the reliability of the results. A high quality data base is necessary to obtain a reliable result. The best results may be expected for the major species of natural waters. For more complicated problems, including trace elements, precipitation/dissolution, adsorption, etc., the results seem to be less reliable. (With 44 refs.) (author)

Bacterial communities associated with subsurface geochemical processes in continental serpentinite springs.

Science.gov (United States)

Brazelton, William J; Morrill, Penny L; Szponar, Natalie; Schrenk, Matthew O

2013-07-01

Reactions associated with the geochemical process of serpentinization can generate copious quantities of hydrogen and low-molecular-weight organic carbon compounds, which may provide energy and nutrients to sustain subsurface microbial communities independently of the photosynthetically supported surface biosphere. Previous microbial ecology studies have tested this hypothesis in deep sea hydrothermal vents, such as the Lost City hydrothermal field. This study applied similar methods, including molecular fingerprinting and tag sequencing of the 16S rRNA gene, to ultrabasic continental springs emanating from serpentinizing ultramafic rocks. These molecular surveys were linked with geochemical measurements of the fluids in an interdisciplinary approach designed to distinguish potential subsurface organisms from those derived from surface habitats. The betaproteobacterial genus Hydrogenophaga was identified as a likely inhabitant of transition zones where hydrogen-enriched subsurface fluids mix with oxygenated surface water. The Firmicutes genus Erysipelothrix was most strongly correlated with geochemical factors indicative of subsurface fluids and was identified as the most likely inhabitant of a serpentinization-powered subsurface biosphere. Both of these taxa have been identified in multiple hydrogen-enriched subsurface habitats worldwide, and the results of this study contribute to an emerging biogeographic pattern in which Betaproteobacteria occur in near-surface mixing zones and Firmicutes are present in deeper, anoxic subsurface habitats.

Pipe Explorer surveying system. Innovative technology summary report

International Nuclear Information System (INIS)

1999-06-01

The US Department of Energy's (DOE) Chicago Operations Office and the DOE's Federal Energy Technology Center (FETC) developed a Large Scale Demonstration Project (LSDP) at the Chicago Pile-5 Research Reactor (CP-5) at Argonne National Laboratory-East (ANL). The objective of the LSDP is to demonstrate potentially beneficial decontamination and decommissioning (D and D) technologies in comparison with current baseline technologies. The Pipe Explorer trademark system was developed by Science and Engineering Associates, Inc. (SEA), Albuquerque, NM as a deployment method for transporting a variety of survey tools into pipes and ducts. Tools available for use with the system include alpha, beta and gamma radiation detectors; video cameras; and pipe locator beacons. Different versions of this technology have been demonstrated at three other sites; results of these demonstrations are provided in an earlier Innovative Technology Summary Report. As part of a D and D project, characterization radiological contamination inside piping systems is necessary before pipes can be recycled, remediated or disposed. This is usually done manually by surveying over the outside of the piping only, with limited effectiveness and risk of worker exposure. The pipe must be accessible to workers, and embedded pipes in concrete or in the ground would have to be excavated at high cost and risk of exposure to workers. The advantage of the Pipe Explorer is its ability to perform in-situ characterization of pipe internals

Marine gamma spectrometric survey

International Nuclear Information System (INIS)

Kostoglodov, V.V.

1979-01-01

Presented are theoretical problems physical and geochemical prerequisites and possibilities of practical application of the method of continuous submarine gamma-spectrometric survey and radiometric survey destined for rapid study of the surface layer of marine sediments. Shown is high efficiency and advantages of this method in comparison with traditional and widely spread in marine geology methods of bottom sediments investigation

The potential of mid- and near-infrared diffuse reflectance spectroscopy for determining major- and trace-element concentrations in soils from a geochemical survey of North America

Science.gov (United States)

Reeves, J. B.; Smith, D.B.

2009-01-01

In 2004, soils were collected at 220 sites along two transects across the USA and Canada as a pilot study for a planned soil geochemical survey of North America (North American Soil Geochemical Landscapes Project). The objective of the current study was to examine the potential of diffuse reflectance (DR) Fourier Transform (FT) mid-infrared (mid-IR) and near-infrared (NIRS) spectroscopy to reduce the need for conventional analysis for the determination of major and trace elements in such continental-scale surveys. Soil samples (n = 720) were collected from two transects (east-west across the USA, and north-south from Manitoba, Canada to El Paso, Texas (USA), n = 453 and 267, respectively). The samples came from 19 USA states and the province of Manitoba in Canada. They represented 31 types of land use (e.g., national forest, rangeland, etc.), and 123 different land covers (e.g., soybeans, oak forest, etc.). The samples represented a combination of depth-based sampling (0-5 cm) and horizon-based sampling (O, A and C horizons) with 123 different depths identified. The set was very diverse with few samples similar in land use, land cover, etc. All samples were analyzed by conventional means for the near-total concentration of 49 analytes (Ctotal, Ccarbonate and Corganic, and 46 major and trace elements). Spectra were obtained using dried, ground samples using a Digilab FTS-7000 FT spectrometer in the mid- (4000-400 cm-1) and near-infrared (10,000-4000 cm-1) at 4 cm-1 resolution (64 co-added scans per spectrum) using a Pike AutoDIFF DR autosampler. Partial least squares calibrations were develop using: (1) all samples as a calibration set; (2) samples evenly divided into calibration and validation sets based on spectral diversity; and (3) samples divided to have matching analyte concentrations in calibration and validation sets. In general, results supported the conclusion that neither mid-IR nor NIRS would be particularly useful in reducing the need for conventional

Geochemical prospecting for rare earth elements using termite mound materials

Science.gov (United States)

Horiuchi, Yu; Ohno, Tetsuji; Hoshino, Mihoko; Shin, Ki-Cheol; Murakami, Hiroyasu; Tsunematsu, Maiko; Watanabe, Yasushi

2014-12-01

The Blockspruit fluorite prospect, located in North West State of the Republic of South Africa, occurs within an actinolite rock zone that was emplaced into the Kenkelbos-type granite of Proterozoic age. There are a large number of termite mounds in the prospect. For geochemical prospecting for rare earth elements (REEs), in total, 200 samples of termite mound material were collected from actinolite rock and granite zones in the prospect. Geochemical analyses of these termite mound materials were conducted by two methods: portable X-ray fluorescence (XRF) spectrometry and inductively coupled plasma-mass spectrometry (ICP-MS). Comparison of the two methods broadly indicates positive correlations of REEs (La, Ce, Pr, Nd, and Y), in particular Y and La having a strong correlation. As the result of modal abundance analyses, the actinolite rock at surface mainly consists of ferro-actinolite (89.89 wt%) and includes xenotime (0.26 wt%) and monazite (0.21 wt%) grains as REE minerals. Termite mound materials from actinolite rock also contain xenotime (0.27 wt%) and monazite (0.41 wt%) grains. In addition, termite mound materials from the actinolite rock zone have high hematite and Fe silicate contents compared to those from granite zone. These relationships suggest that REE minerals in termite mound materials originate form actinolite rock. Geochemical anomaly maps of Y, La, and Fe concentrations drawn based on the result of the portable XRF analyses show that high concentrations of these elements trend from SW to NE which broadly correspond to occurrences of actinolite body. These results indicate that termite mounds are an effective tool for REE geochemical prospection in the study area for both light REEs and Y, but a more detailed survey is required to establish the distribution of the actinolite rock body.

Appliance of geochemical engineering in radioactive waste disposal

International Nuclear Information System (INIS)

Li Shuang; Zhang Chengjiang; Ni Shijun; Li Kuanliang

2008-01-01

The basic foundation of applying geochemical engineering to control environment, common engineering models of disposal radioactive waste and the functions of the engineering barriers are introduced in this paper. The authors take the geochemical engineering barrier materiel research of a radioactive waste repository as an example to explain the appliance of geochemical engineering in the disposal of radioactive waste. And the results show that it can enhance the security of the nuclear waste repository if we use geochemical engineering barrier. (authors)

Geochemical characteristics of the Permian sedimentary rocks from Qiangtang Basin: Constraints for paleoenvironment and paleoclimate

Directory of Open Access Journals (Sweden)

Junjie Hu

2017-01-01

Full Text Available Qiangtang Basin is expected to become important strategic petroleum exploitation area in China. However, little research has been done on the Permian strata in this area. This paper presents Lower Permian Zhanjin Formation geochemical data from the Jiaomuri area, reconstructing the paleo-depositional environment and providing information for further petroleum exploration. The geochemical characteristics of 19 samples were investigated. These geochemical samples show a developed mud flat characteristic with light rich clay content. The geological data were used to constrain the paleoredox environment, which proved that these sediments were deposited mainly beneath a slightly oxic water column with relatively low paleoproductivity as evidenced by the P/Ti (mean of 0.07 and Ba/Al (mean of 20.5. Palaeoclimate indexes such as the C-value (0.24-1.75 and Sr/Cu (1.28-11.58 reveal a humid climatic condition during Zhanjin Formation sediment deposition. The ω(LaN/ω(YbN ratio values indicate a fast sedimentary rate during the deposition period.

Soil Iodine Determination in Deccan Syneclise, India: Implications for Near Surface Geochemical Hydrocarbon Prospecting

International Nuclear Information System (INIS)

Mani, Devleena; Kumar, T. Satish; Rasheed, M. A.; Patil, D. J.; Dayal, A. M.; Rao, T. Gnaneshwar; Balaram, V.

2011-01-01

The association of iodine with organic matter in sedimentary basins is well documented. High iodine concentration in soils overlying oil and gas fields and areas with hydrocarbon microseepage has been observed and used as a geochemical exploratory tool for hydrocarbons in a few studies. In this study, we measure iodine concentration in soil samples collected from parts of Deccan Syneclise in the west central India to investigate its potential application as a geochemical indicator for hydrocarbons. The Deccan Syneclise consists of rifted depositional sites with Gondwana–Mesozoic sediments up to 3.5 km concealed under the Deccan Traps and is considered prospective for hydrocarbons. The concentration of iodine in soil samples is determined using ICP-MS and the values range between 1.1 and 19.3 ppm. High iodine values are characteristic of the northern part of the sampled region. The total organic carbon (TOC) content of the soil samples range between 0.1 and 1.3%. The TOC correlates poorly with the soil iodine (r 2 < 1), indicating a lack of association of iodine with the surficial organic matter and the possibility of interaction between the seeping hydrocarbons and soil iodine. Further, the distribution pattern of iodine compares well with two surface geochemical indicators: the adsorbed light gaseous hydrocarbons (methane through butane) and the propane-oxidizing bacterial populations in the soil. The integration of geochemical observations show the occurrence of elevated values in the northern part of the study area, which is also coincident with the presence of exposed dyke swarms that probably serve as conduits for hydrocarbon microseepage. The corroboration of iodine with existing geological, geophysical, and geochemical data suggests its efficacy as one of the potential tool in surface geochemical exploration of hydrocarbons. Our study supports Deccan Syneclise to be promising in terms of its hydrocarbon prospects.

77 FR 19321 - Geological and Geophysical Exploration on the Atlantic Outer Continental Shelf (OCS)

Science.gov (United States)

2012-03-30

... DEPARTMENT OF THE INTERIOR Bureau of Ocean Energy Management Geological and Geophysical... Statement (PEIS) to evaluate potential environmental effects of multiple Geological and Geophysical (G&G... limited to, seismic surveys, sidescan-sonar surveys, electromagnetic surveys, geological and geochemical...

Methodological approaches in estimating anomalous geochemical field structure

International Nuclear Information System (INIS)

Gavrilov, R; Rudmin, M

2015-01-01

Mathematical statistic methods were applied to analyze the core samples from vertical expendable wells in Chertovo Koryto gold ore field. The following methods were used to analyse gold in samples: assay tests and atomic absorption method (AAS), while emission spectrum semiquantative method was applied to identify traces. The analysis of geochemical association distribution in one central profile demonstrated that bulk metasomatic aureoles are characteristic of concentric zonal structure. The distribution of geochemical associations is correlated to the hydrothermal stages of mineral formation identified in this deposit. It was proved that the processed geochemical data by factor and cluster analyses provided additional information on the anomalous geochemical field structure in gold- bearing black-shale strata. Such methods are effective tools in interpretating specific features of geochemical field structures in analogous potential ore-bearing areas

Baseline Geochemical Data for Medical Researchers in Kentucky

Science.gov (United States)

Anderson, W.

2017-12-01

According to the Centers for Disease Control, Kentucky has the highest cancer incidence and death rates in the country. New efforts by geochemists and medical researchers are examining ways to diagnose the origin and sources of carcinogenesis. In an effort to determine if naturally occurring geochemical or mineral elements contributes to the cancer causation, the Kentucky Geological Survey has established a Minerals and Geochemical Database that is available to medical researchers for examination of baseline geochemistry and determine if naturally occurring mineral or chemical elements contribute to the high rate of cancers in the state. Cancer causation is complex, so if natural sources can be accounted for, then researchers can focus on the true causation. Naturally occurring minerals, metals and elements occur in many parts of the state, and their presence is valuable for evaluating causation. For example, some data in the database contain maps showing (a) statewide elemental geochemistry, (b) areas of black shale oxidation occurrence, which releases metals in soil and surface waters, (c) some clay deposits in the state that can contain high content of rare earth elements, and (d) site-specific uranium occurrences. Knowing the locations of major ore deposits in the state can also provide information related to mineral and chemical anomalies, such as for base metals and mercury. Radionuclide data in soil and water analyses are limited, so future research may involve obtaining more analyses to determine radon potential. This database also contains information on faulting and geology in the state. Although the metals content of trees may not seem relevant, the ash and humus content of degraded trees affects soil, stream sediment and water geochemistry. Many rural homes heat with wood, releasing metals into the surrounding biosphere. Stressed vegetation techniques can be used to explore for ore deposits and look for high metal contents in soils and rocks. These

Application of exploration geochemistry techniques in agriculture

International Nuclear Information System (INIS)

Santos, G.P. Jr.; Fernandez, L.G.; Petrache, C.A.; Almoneda, R.V.; Rosales, C.M.

1989-01-01

Soil samples collected from Tarlac, Nueva Ecija, Pampanga, Bulacan, Laguna and Quezon provinces were analyzed for Zn, Mn, Cu, Fe, Co, Pb, and Ni using two analytical methods - Smith and Lynch (S and L) element extraction technique used in exploration geochemical survey and the International Rice Research Institute (IRRI) technique for determining zinc availability in soil. The analytical results were treated statistically using the method of Lepeltier to obtain the background values. The background, or average concentrations of the elements obtained by the S and L method were an order-higher than those computed for the IRRI method. The different metal value contour maps of northwestern Luzon were multiplied by its corresponding metal ratio, IRRI/S and L to produce the agri-geochemical maps or agri-maps that show approximate trace element levels available to the plant. The agri-maps of northwestern Luzon show a region wide deficiency in Cu, Zn, Mn, Pb, Co, and Ni, with the exception of Baguio Area. It has been recognized that excess deficiency in certain minor or trace elements in, particularly the essential micronutrient elements, is one of the important factors in agricultural productivity. It is therefore, recommended that in order to assure the necessary level of trace elements in northwestern Luzon, additions of at least copper, zinc and manganese be provided together with the needed fertilizer. (Author). 14 figs.; 14 refs.; 4 tabs

Geochemical modeling: a review

International Nuclear Information System (INIS)

Jenne, E.A.

1981-06-01

Two general families of geochemical models presently exist. The ion speciation-solubility group of geochemical models contain submodels to first calculate a distribution of aqueous species and to secondly test the hypothesis that the water is near equilibrium with particular solid phases. These models may or may not calculate the adsorption of dissolved constituents and simulate the dissolution and precipitation (mass transfer) of solid phases. Another family of geochemical models, the reaction path models, simulates the stepwise precipitation of solid phases as a result of reacting specified amounts of water and rock. Reaction path models first perform an aqueous speciation of the dissolved constituents of the water, test solubility hypotheses, then perform the reaction path modeling. Certain improvements in the present versions of these models would enhance their value and usefulness to applications in nuclear-waste isolation, etc. Mass-transfer calculations of limited extent are certainly within the capabilities of state-of-the-art models. However, the reaction path models require an expansion of their thermodynamic data bases and systematic validation before they are generally accepted

Geochemical modeling: a review

Energy Technology Data Exchange (ETDEWEB)

Jenne, E.A.

1981-06-01

Two general families of geochemical models presently exist. The ion speciation-solubility group of geochemical models contain submodels to first calculate a distribution of aqueous species and to secondly test the hypothesis that the water is near equilibrium with particular solid phases. These models may or may not calculate the adsorption of dissolved constituents and simulate the dissolution and precipitation (mass transfer) of solid phases. Another family of geochemical models, the reaction path models, simulates the stepwise precipitation of solid phases as a result of reacting specified amounts of water and rock. Reaction path models first perform an aqueous speciation of the dissolved constituents of the water, test solubility hypotheses, then perform the reaction path modeling. Certain improvements in the present versions of these models would enhance their value and usefulness to applications in nuclear-waste isolation, etc. Mass-transfer calculations of limited extent are certainly within the capabilities of state-of-the-art models. However, the reaction path models require an expansion of their thermodynamic data bases and systematic validation before they are generally accepted.

NOAA and MMS Marine Minerals Geochemical Database

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — The Marine Minerals Geochemical Database was created by NGDC as a part of a project to construct a comprehensive computerized bibliography and geochemical database...

Notes on the geochemical survey for uranium in Mindoro Island, Philippines

International Nuclear Information System (INIS)

Santos, G. Jr.; Fernandez, L.G.; Villamater, D.T.; Seguis, J.E.; Ibe, M.G.

1981-03-01

Geochemical reconnaisance using stream sediment and heavy-mineral concentrates panned from coarse alluvium has been carried out in Mindoro Island, one of the oldest and diverse geologic terrains in the Philippines. A total of 135 selected sampling points situated near accessible areas along the periphery of the island were sampled. The samples were collected at a density of one sample per 53 sq. km. A set minus 80 mesh stream sediment fraction and heavy-mineral concentrates was obtained from each sampling point. Mobile or extractable and total uranium were determined. A large uranium anomaly was delineated over the Carboniferous Mindoro Metamorphics as well as in areas underlain by Early Tertiary sedimentary formations. Another group of anomalies were outlined in the southern part of the island underlain by Jurassic Mansalay Formation and Early to Middle Tertiary sedimentary rocks with associated limestone and coal measures. (author)

Uruguay mining Inventory: Geochemical prospecting results of Valentines mapping; Inventario minero del Uruguay : Resultados de la prospeccion geoquimica del fotoplano Valentines

Energy Technology Data Exchange (ETDEWEB)

Spangenberg, J; Filippini, J

1985-07-01

This work is about geochemical prospecting carried out into the Uruguay mining inventory framework. In this case the survey was in Valentines mapping. Florida, Durazno and Treinta y Tres provinces of Uruguay .

32 CFR 552.35 - Rights-of-entry for survey and exploration.

Science.gov (United States)

2010-07-01

... RESERVATIONS AND NATIONAL CEMETERIES REGULATIONS AFFECTING MILITARY RESERVATIONS Acquisition of Real Estate and... to enter upon non-Government-owned real estate during site selection, particularly for the purpose of... 32 National Defense 3 2010-07-01 2010-07-01 true Rights-of-entry for survey and exploration. 552...

Geochemical and mineralogical characteristics of Lithomargic clay

African Journals Online (AJOL)

Administrator

Geochemical and mineralogical characteristics of Lithomargic clay. GEOCHEMICAL AND .... tries, as filling material in the pulp and paper, toothpaste and paint industries as well ..... tions very vital to human health and other ac- tivities of man.

Uranium exploration of Samar Island

International Nuclear Information System (INIS)

Santos, G. Jr.

1979-02-01

Uranium exploration is being undertaken to meet the requirements of the Philippine Nuclear Power Plant-1 (PNPP-1) programmed to operate in 1982, for about 140 metric tons annually or 2664 MT of U 3 O 8 up to the year 2000. Samar was chosen as the survey pilot project and the method used was a geochemical reconnaissance or low density observation survey to delineate broad areas where follow-up uranium surveys may be undertaken. Stream sediments or surface waters were collected at each sampling point at a density of one sample per 20-25 sq. km. The conductance and pH of the water were measured with a conductivity meter and pH respectively. Radioactivity was determined using a portable scintillometer. The stream sediment and heavy mineral samples were analyzed for uranium (U), copper (CCu), lead (Pb), zinc (Zn), manganese (Mn), silver (Ag), cobalt (Co), nickel (Ni). Water samples were analyzed for uranium only. The solid samples were digested in an acid mixture of 85% concentrated nitric acid and 15% concentrated hydrochloric acid, and the leachable uranium was determined using a fluorimeter. The detection limits for uranium were 0.3 ppb and 0.3 ppm for water and solid samples, respectively. Analysis for Cu, Pb, Zn, Mn, Ag, Co, and Ni were done by Atomic Absorption Spectrophotometry using the same leaching solution prepared for uranium analysis. Over 9000 determinations were done on nearly 1600 samples. The survey delineated at least two areas where follow-up surveys for uranium are warranted. These areas are the San Isidro - Catarman in Northwestern Samar, and the vicinity of Bagacay mines in Central Samar

FY 1992 report on the survey of geothermal development promotion. Geochemical survey (No. A-1 - Haneyama area); 1992 nendo chinetsu kaihatsu sokushin chosa chijo chosa hokokusho futai shiryo. Chikagaku chosa hokokusho (No. A-1 Haneyama chiiki)

Energy Technology Data Exchange (ETDEWEB)

NONE

1993-05-01

For the purpose of studying an expanse and characteristics of the geothermal system and a possibility of geothermal development in the Haneyama area, Oita Prefecture, geochemical survey was conducted. In the survey, various kinds of analyses were made for 13 specimens of hot spring water and 5 specimens of surface water in the area of about 280km{sup 2} at 402 measuring points of the concentration of Hg in soil gas. The results of the survey were as follows: In this survey area, it was thought that the HCO{sub 3} type geothermal water of a comparatively low temperature which was heated by the wide-spread conduction heat from the depths was widely distributed deeper than the depth of 500-700m, and it was presumed that a possibility was low of existence of a high geothermal potential which can be used for the geothermal power generation in the part deeper than the drilling depth of 700m. In the Noya area in the southwest part of the survey area, the high temperature deep geothermal reservoir was confirmed. In this area, the high temperature neutral-alkalescent Cl-SO{sub 4} type geothermal water was distributed in the depth of several 100 meters or deeper. The geothermal water seemed to flow from NE to SW along the structure in the NE-SW direction, and it was concluded that the area was the most promising one. (NEDO)

Survey Exploring Views of Scientists on Current Trends in Chemistry Education

Science.gov (United States)

Vamvakeros, Xenofon; Pavlatou, Evangelia A.; Spyrellis, Nicolas

2010-01-01

A survey exploring the views of scientists, chemists and chemical engineers, on current trends in Chemistry Education was conducted in Greece. Their opinions were investigated using a questionnaire focusing on curricula (the content and process of chemistry teaching and learning), as well as on the respondents' general educational beliefs and…

Uranium exploration in Ecuador

International Nuclear Information System (INIS)

Severne, B.; Penaherrera, P.F.; Fiallos, V.S.

1981-01-01

The 600-km segment of the Andean Cordillera in Ecuador includes zones that can be correlated, geologically, with uranium districts elsewhere in the Andes. It is believed that these essentially unexplored zones have the potential for economic uranium mineralization. Exploration activity to date has been limited, although it has involved both geochemical and radiometric techniques to evaluate geological concepts. Minor uranium occurrences (with chemical analyses up to 100 ppm) have been encountered, which provide further incentive to commence large-scale systematic exploration. It is recognized that a very large exploration budget and considerable technical expertise will be required to ensure exploration success. Consequently, participation by groups of proven capability from other countries will be sought for Ecuador's national exploration programme. (author)

Geothermal development promotion survey. No. B-3 Kumaishi area; Chinethu kaihatsu sokushin chosa seika hokokusho. No. B-3. Kumaishi chiiki

Energy Technology Data Exchange (ETDEWEB)

NONE

1999-03-01

This paper summarizes the result of a geothermal resource survey carried out from fiscal 1995 through fiscal 1997 in the Kumaishi Area located in the western center of Oshima Peninsula in the south western part of Hokkaido. The survey for this area was performed with an objective to search the spread of high temperature area continuing from the adjoining Yakumo area where the highest temperature of 233 degrees C has been confirmed in a structural test well (N63-YK-6), to identify high water permeating areas in great depth points underground, and to find possibility of existence of geothermal resources. The survey included geological and alteration zone survey, geochemical survey, gravitation exploration, electromagnetic exploration, drilling and temperature logging of five structural test wells, water injection test, temperature restoration test, core survey and hot water survey. Also performed were environmental effect survey, rock age measurement, alteration age measurement, and fluid inclusion test. As a result of the survey, it was identified that the verified geothermal hot water has been stored in granites with poor water permeability, whose low temperature has not formed convection systems spreading in wide areas despite having been heated, making each system exist in small scale independently. It was estimated that the possibility is low to expect geothermal power generation. (NEDO)

Geochemical signature of radioactive waste: oil NORM

International Nuclear Information System (INIS)

Costa, Gilberto T. de Paula; Costa-de-Moura, Jorge; Gomes, Carlos de Almeida; Sampaio, Emidio A. Lopes

2017-01-01

The Brazilian Nuclear Agency (CNEN) rules all nuclear activity in Brazil as demanded by the Federal Constitution, articles 21, XXIII, and 177, V, and by the Federal Acts 4.118/62 and 10.308/2001. Therefore, the CNEN is responsible for any radioactive waste disposal in the country. Oil Naturally Occurring Radioactive Materials (Oil NORM) in this paper refers to waste coming from oil exploration. Oil NORM has called much attention during the last decades, mostly because it is not possible to determine its primary source due to the actual absence of regulatory control mechanism. There is no efficient regulatory tool which allows determining the origin of such NORM wastes even among those facilities under regulatory control. This fact may encourage non-authorized radioactive material transportation, smuggling and terrorism. The aim of this project is to provide a geochemical signature for each oil NORM waste using its naturally occurring isotopic composition to identify its origin. The here proposed method is a specific geochemical modeling of oil sludge NORM samples which are analyzed for radioisotopes normally present in oil pipes, such as 228 Ac, 214 Bi and 214 Pb. The activity ratios are plotted in scatter diagrams. This method was successfully tested with data of different sources obtained from analysis reports from the Campos Basin/Brazil and from literature. (author)

Geochemical signature of radioactive waste: oil NORM

Energy Technology Data Exchange (ETDEWEB)

Costa, Gilberto T. de Paula; Costa-de-Moura, Jorge; Gomes, Carlos de Almeida; Sampaio, Emidio A. Lopes, E-mail: gilberto.costa@cnen.gov.br, E-mail: jcmoura@cnen.gov.br, E-mail: cgomes@cnen.gov.br [Comissao Nacional de Energia Nuclear (CNEN), Rio de Janeiro, RJ (Brazil). Div. de Controle de Rejeitos e Transporte de Materiais Radioativos

2017-07-01

The Brazilian Nuclear Agency (CNEN) rules all nuclear activity in Brazil as demanded by the Federal Constitution, articles 21, XXIII, and 177, V, and by the Federal Acts 4.118/62 and 10.308/2001. Therefore, the CNEN is responsible for any radioactive waste disposal in the country. Oil Naturally Occurring Radioactive Materials (Oil NORM) in this paper refers to waste coming from oil exploration. Oil NORM has called much attention during the last decades, mostly because it is not possible to determine its primary source due to the actual absence of regulatory control mechanism. There is no efficient regulatory tool which allows determining the origin of such NORM wastes even among those facilities under regulatory control. This fact may encourage non-authorized radioactive material transportation, smuggling and terrorism. The aim of this project is to provide a geochemical signature for each oil NORM waste using its naturally occurring isotopic composition to identify its origin. The here proposed method is a specific geochemical modeling of oil sludge NORM samples which are analyzed for radioisotopes normally present in oil pipes, such as {sup 228}Ac, {sup 214}Bi and {sup 214}Pb. The activity ratios are plotted in scatter diagrams. This method was successfully tested with data of different sources obtained from analysis reports from the Campos Basin/Brazil and from literature. (author)

Predictive geophysics: geochemical simulations to geophysical targets

Science.gov (United States)

Chopping, R. G.; Cleverley, J.

2017-12-01

With an increasing focus on deep exploration for covered targets, new methods are required to target mineral systems under cover. Geophysical responses are driven by physical property contrasts; for example, density contrasts provide a gravity signal, acoustic impedance contrasts provide a seismic reflection signal. In turn, the physical properties for basement, crystalline rocks which host the vast majority of mineral systems are determined almost wholly by the mineralogy of the rocks in question. Mineral systems, through the transport of heat and reactive fluids, will serve to modify the physical properties of country rock as they chemically alter the hosting strata. To understand these changes, we have performed 2D reactive transport modelling that simulates the formation of Archean gold deposits of the Yilgarn Craton, Western Australia. From this, we derive a model of mineralogy that we can use to predict the density, magnetic susceptibility and seismic reflection changes associated with ore formation. It is then possible to predict the gravity, magnetic and seismic reflection responses associated with these deposits. Scenario mapping, such as testing the ability to resolve buried ore bodies or the geophysical survey spacing required to resolve the mineral system, can be performed to produce geophysical targets from these geochemical simulations. We find that there is a gravity response of around 9% of the unaltered response for deposits even buried by 1km of cover, and there is a magnetic spike associated with proximal alteration of the ore system. Finally, seismic reflection response is mostly characterised by additional reflections along faults that plumb the alteration system.

Probabilistic, sediment-geochemical parameterisation of the groundwater compartment of the Netherlands for spatially distributed, reactive transport modelling

Science.gov (United States)

Janssen, Gijs; Gunnink, Jan; van Vliet, Marielle; Goldberg, Tanya; Griffioen, Jasper

2017-04-01

Pollution of groundwater aquifers with contaminants as nitrate is a common problem. Reactive transport models are useful to predict the fate of such contaminants and to characterise the efficiency of mitigating or preventive measures. Parameterisation of a groundwater transport model on reaction capacity is a necessary step during building the model. Two Dutch, national programs are combined to establish a methodology for building a probabilistic model on reaction capacity of the groundwater compartment at the national scale: the Geological Survey program and the NHI Netherlands Hydrological Instrument program. Reaction capacity is considered as a series of geochemical characteristics that control acid/base condition, redox condition and sorption capacity. Five primary reaction capacity variables are characterised: 1. pyrite, 2. non-pyrite, reactive iron (oxides, siderite and glauconite), 3. clay fraction, 4. organic matter and 5. Ca-carbonate. Important reaction capacity variables that are determined by more than one solid compound are also deduced: 1. potential reduction capacity (PRC) by pyrite and organic matter, 2. cation-exchange capacity (CEC) by organic matter and clay content, 3. carbonate buffering upon pyrite oxidation (CPBO) by carbonate and pyrite. Statistical properties of these variables are established based on c. 16,000 sediment geochemical analyses. The first tens of meters are characterised based on 25 regions using combinations of lithological class and geological formation as strata. Because of both less data and more geochemical uniformity, the deeper subsurface is characterised in a similar way based on 3 regions. The statistical data is used as input in an algoritm that probabilistically calculates the reaction capacity per grid cell. First, the cumulative frequency distribution (cfd) functions are calculated from the statistical data for the geochemical strata. Second, all voxel cells are classified into the geochemical strata. Third, the

Hydrogeochemical and stream sediment detailed geochemical survey for Thomas Range-Wasatch, Utah. Cottonwood project area

International Nuclear Information System (INIS)

Butz, T.R.; Bard, C.S.; Witt, D.A.; Helgerson, R.N.; Grimes, J.G.; Pritz, P.M.

1980-01-01

Results of Cottonwood project area of the Thomas Range-Wasatch detailed geochemical survey are reported. Field and laboratory data are presented for 15 groundwater samples, 79 stream sediment samples, and 85 radiometric readings. Statistical and areal distributions of uranium and possible uranium-related variables are given. A generalized geologic map of the project area is provided, and pertinent geologic factors which may be of significance in evaluating the potential for uranium mineralization are briefly discussed. Uranium concentrations in groundwater range from 0.25 to 3.89 ppB. The highest concentrations are from groundwaters from the Little Cottonwood and Ferguson Stocks. Variables that appear to be associated with uranium in groundwater include cobalt, iron, potassium, manganese, nickel, sulfate, and to a lesser extent, molybdenum and strontium. This association is attributed to the Monzonitic Little Cottonwood Stock, granodioritic to granitic and lamprophyric dikes, and known sulfide deposits. Soluble uranium concentrations (U-FL) in stream sediments range from 0.31 to 72.64 ppM. Total uranium concentrations (U-NT) range from 1.80 to 75.20 ppM. Thorium concentrations range from <2 to 48 ppM. Anomalous values for uranium and thorium are concentrated within the area of outcrop of the Little Cottonwood and Ferguson Stocks. Variables which are areally associated with high values of uranium, thorium, and the U-FL:U-NT ratio within the Little Cottonwood Stock are barium, copper, molybdenum, and zinc. High concentrations of these variables are located near sulfide deposits within the Little Cottonwood Stock

Geologic field notes and geochemical analyses of outcrop and drill core from Mesoproterozoic rocks and iron-oxide deposits and prospects of southeast Missouri

Science.gov (United States)

Day, Warren C.; Granitto, Matthew

2014-01-01

The U.S. Geological Survey, in cooperation with the Missouri Department of Natural Resources/Missouri Geological Survey, undertook a study from 1988 to 1994 on the iron-oxide deposits and their host Mesoproterozoic igneous rocks in southeastern Missouri. The project resulted in an improvement of our understanding of the geologic setting, mode of formation, and the composition of many of the known deposits and prospects and the associated rocks of the St. Francois terrane in Missouri. The goal for this earlier work was to allow the comparison of Missouri iron-oxide deposits in context with other iron oxide-copper ± uranium (IOCG) types of mineral deposits observed globally. The raw geochemical analyses were released originally through the USGS National Geochemical Database (NGDB, http://mrdata.usgs.gov). The data presented herein offers all of the field notes, locations, rock descriptions, and geochemical analyses in a coherent package to facilitate new research efforts in IOCG deposit types. The data are provided in both Microsoft Excel (Version Office 2010) spreadsheet format (*.xlsx) and MS-DOS text formats (*.txt) for ease of use by numerous computer programs.

Groundwater discharge mapping at Altnabreac by thermal infrared linescan surveying

International Nuclear Information System (INIS)

Brereton, N.R.; Hall, D.H.

1983-07-01

A thermal infra-red linescan survey has been carried out of the area around Altnabreac, Caithness. The objectives of the survey were: to assess the applicability of the technique to the location of springs discharging from peat covered crystalline rocks; to provide the locations of springs for a subsequent geochemical sampling programme; and to gain clearer understanding of the ground water circulation patterns in the area. The number and distribution of springs located by the survey has proved to be far greater than had been previously anticipated and the capabilities of the technique have been clearly demonstrated. The results, together with other geochemical and hydrogeological data, indicate that the majority of the springs represent near surface recent groundwaters circulating within the moraine deposits and weathered granite. (author)

Geochemical controls on groundwater chemistry in shales

International Nuclear Information System (INIS)

Von Damm, K.L.

1989-01-01

The chemistry of groundwaters is one of the most important parameters in determining the mobility of species within a rock formation. A three pronged approach was used to determine the composition of, and geochemical controls, on groundwaters specifically within shale formations: (1) available data were collected from the literature, the US Geological Survey WATSTORE data base, and field sampling, (2) the geochemical modeling code EQ3/6 was used to simulate interaction of various shales and groundwaters, and (3) several types of shale were reacted with synthetic groundwaters in the laboratory. The comparison of model results to field and laboratory data provide a means of validating the models, as well as a means of deconvoluting complex field interactions. Results suggest that groundwaters in shales have a wide range in composition and are primarily of the Na-Cl-HCO 3 - type. The constancy of the Na:Cl (molar) ratio at 1:1 and the Ca:Mg ratio from 3:1 to 1:1 suggests the importance of halite and carbonates in controlling groundwater compositions. In agreement with the reaction path modeling, most of the groundwaters are neutral to slightly alkaline at low temperatures. Model and experimental results suggest that reaction (1) at elevated temperatures, or (2) in the presence of oxygen will lead to more acidic conditions. Some acetate was found to be produced in the experiments; depending on the constraints applied, large amounts of acetate were produced in the model results. 13 refs., 1 tab

The IUGS/IAGC Task Group on Global Geochemical Baselines

Science.gov (United States)

Smith, David B.; Wang, Xueqiu; Reeder, Shaun; Demetriades, Alecos

2012-01-01

The Task Group on Global Geochemical Baselines, operating under the auspices of both the International Union of Geological Sciences (IUGS) and the International Association of Geochemistry (IAGC), has the long-term goal of establishing a global geochemical database to document the concentration and distribution of chemical elements in the Earth’s surface or near-surface environment. The database and accompanying element distribution maps represent a geochemical baseline against which future human-induced or natural changes to the chemistry of the land surface may be recognized and quantified. In order to accomplish this long-term goal, the activities of the Task Group include: (1) developing partnerships with countries conducting broad-scale geochemical mapping studies; (2) providing consultation and training in the form of workshops and short courses; (3) organizing periodic international symposia to foster communication among the geochemical mapping community; (4) developing criteria for certifying those projects whose data are acceptable in a global geochemical database; (5) acting as a repository for data collected by those projects meeting the criteria for standardization; (6) preparing complete metadata for the certified projects; and (7) preparing, ultimately, a global geochemical database. This paper summarizes the history and accomplishments of the Task Group since its first predecessor project was established in 1988.

Reconnaissance Geochemical Study

African Journals Online (AJOL)

distribution patterns. The geochemical distribution maps of the elements reveal that Cu, Pb, Zn, Co, Sc, Ni, Cr, .... After filtration, the leached solutions were diluted with ultra ...... some other rare earth elements in the study area. The occurrence ...

Pipe Explorer{trademark} surveying system. Innovative technology summary report

Energy Technology Data Exchange (ETDEWEB)

1999-06-01

The US Department of Energy`s (DOE) Chicago Operations Office and the DOE`s Federal Energy Technology Center (FETC) developed a Large Scale Demonstration Project (LSDP) at the Chicago Pile-5 Research Reactor (CP-5) at Argonne National Laboratory-East (ANL). The objective of the LSDP is to demonstrate potentially beneficial decontamination and decommissioning (D and D) technologies in comparison with current baseline technologies. The Pipe Explorer{trademark} system was developed by Science and Engineering Associates, Inc. (SEA), Albuquerque, NM as a deployment method for transporting a variety of survey tools into pipes and ducts. Tools available for use with the system include alpha, beta and gamma radiation detectors; video cameras; and pipe locator beacons. Different versions of this technology have been demonstrated at three other sites; results of these demonstrations are provided in an earlier Innovative Technology Summary Report. As part of a D and D project, characterization radiological contamination inside piping systems is necessary before pipes can be recycled, remediated or disposed. This is usually done manually by surveying over the outside of the piping only, with limited effectiveness and risk of worker exposure. The pipe must be accessible to workers, and embedded pipes in concrete or in the ground would have to be excavated at high cost and risk of exposure to workers. The advantage of the Pipe Explorer is its ability to perform in-situ characterization of pipe internals.

Geochemical modelling: what phenomena are missing

International Nuclear Information System (INIS)

Jacquier, P.

1989-12-01

In the framework of safety assessment of radioactive waste disposal, retention phenomena are usually taken into account by the Kd concept. It is well recognized that this concept is not enough for safety assessment models, because of the several and strong assumptions which are involved in this kind of representation. One way to have a better representation of the retention phenomena, is to substitute for this Kd concept an explicit description of geochemical phenomena and then couple transport codes with geochemical codes in a fully or a two-step procedure. We use currently such codes, but the scope of this paper is to display the limits today of the geochemical modelling in connection with sites analysis for deep disposal. In this paper, we intend to give an overview of phenomena which are missing in the geochemical models, or which are not completely introduced in the models. We can distinguish, on one hand phenomena for which modelling concepts exist such as adsorption/desorption and, on the other hand, phenomena for which modelling concepts do not exist for the moment such as colloids, and complexation by polyelectrolyte solutions (organics). Moreover we have to take care of very low concentrations of radionuclides, which can be expected from the leaching processes in the repository. Under those conditions, some reactions may not occur. After a critical review of the involved phenomena, we intend to stress the main directions of the wishful evolution of the geochemical modelling. This evolution should improve substantially the quality of the above-mentioned site assessments

Coupling of transport and geochemical models

International Nuclear Information System (INIS)

Noy, D.J.

1986-01-01

This report considers mass transport in the far-field of a radioactive waste repository, and detailed geochemical modelling of the ground-water in the near-field. A parallel approach to this problem of coupling transport and geochemical codes is the subject of another CEC report (ref. EUR 10226). Both studies were carried out in the framework of the CEC project MIRAGE. (Migration of radionuclides in the geosphere)

Magnetic and geochemical characterization of Andosols developed on basalts in the Massif Central, France

Science.gov (United States)

Grison, Hana; Petrovsky, Eduard; Stejskalova, Sarka; Kapicka, Ales

2015-05-01

Identification of Andosols is primarily based upon the content of their colloidal constituents—clay and metal-humus complexes—and on the determining of andic properties. This needs time and cost-consuming geochemical analyses. Our primary aim of this study is to describe the magnetic and geochemical properties of soils rich in iron oxides derived from strongly magnetic volcanic basement (in this case Andosols). Secondary aim is to explore links between magnetic and chemical parameters of andic soils with respect to genesis factors: parent material age, precipitation, and thickness of the soil profile. Six pedons of andic properties, developed on basaltic lavas, were analyzed down to parent rock by a set of magnetic and geochemical methods. Magnetic data of soil and rock samples reflect the type, concentration, and particle-size distribution of ferrimagnetic minerals. Geochemical data include soil reaction (pH in H2O), cation exchange capacity, organic carbon, and different forms of extractable iron and aluminum content. Our results suggest the following: (1) magnetic measurements of low-field mass-specific magnetic susceptibility can be a reliable indicator for estimating andic properties, and in combination with thermomagnetic curves may be suitable for discriminating between alu-andic and sil-andic subtypes. (2) In the studied Andosols, strong relationships were found between (a) magnetic grain-size parameters, precipitation, and exchangeable bases; (b) concentration of ferrimagnetic particles and degree of crystallization of free iron; and (c) parameters reflecting changes in magneto-mineralogy and soil genesis (parent material age + soil depth).

Concerning evaluation of eco-geochemical background in remediation strategy

Science.gov (United States)

Korobova, Elena; Romanov, Sergey

2015-04-01

The geochemical concept of biosphere developed by V.I. Vernadsky states the geological role of the living organisms in the course of their active chemical interaction with the inert matter (Vernadsky, 1926, 1960). Basing on this theory it is reasonable to suggest that coevolution of living organisms and their environment led to development of the dynamically stable biogeocenoses precisely adequate to their geochemical environment. Soil cover was treated by V.I. Vernadsky as a balanced bio-inert matter resulting from this interaction. Appearance of human mind and then a civilization led to global expansion of human beings, first able to survive in unfavorable geochemical conditions and then starting chemical transformation of the environment to satisfy the growing demands of mankind in food and energy. The residence in unfavorable environment and local contamination was followed by appearance of endemic diseases of plants, animals and man. Therefore zonal, regional and local chemical composition of the soil cover formed in natural conditions may be used for estimation of the optimum geochemical background, most adequate for the corresponding zonal biogeocenoses and species. Moreover, the natural geochemical background and technogenic fields have unequal spatial structure and this facilitates their identification that may be relatively easy realized in remediation strategy. On the assumption of the foregoing, the adequate methodical approach to remediation of technogenically affected areas should account of the interaction of the existing natural and the newly formed technogenic geochemical fields and include the following steps: 1) the study and mapping of geochemical structure of the natural geochemical background basing on soil maps; 2) the study of contaminants and mapping spatial distribution of technogenic releases; 3) construction of risk maps for the target risk groups with due regard to natural ecological threshold concentration in context of risk degree for

Geochemical radioactive investigation of beach sands and stream sediments, using heavy minerals, trace elements and radon measurements, (Qerdaha sheet of the Syrian coast)

International Nuclear Information System (INIS)

Jubeli, Y.; Kattaa, B.; Al-Hilal, M.

2000-05-01

Reconnaissance geochemical radiometric survey of stream sediments resulting from the weathering of outcropped rocks in and around the study area was performed. This survey included heavy mineral sampling, trace and radioelements and radon measurements to evaluate the radioactivity of the source rocks and to understand the nature and distribution of the heavy minerals and trace elements in the study area. Several techniques were used to achieve these objectives. The results of heavy mineral geochemical survey show that the abundant minerals are iron oxides (magnetite, hematite, goehtite and limonite) pyroxene and olivine; less abundant minerals are apatite, ilmenite, garnet, barite, siderite and gloconite, while rare minerals are zircon and rutile. Amphibole is reported as an abundant mineral in sand dunes and is less abundant in samples located in the northern part of the study area. The amphibole seems to be derived from the ophiolitic complex north of the study area. Grain size analysis of heavy minerals revealed that the concentration of economic minerals such as zircon rutile and ilmenite increases with the decrease of the grain size. The microscopic study showed fragments and fossils of foraminifere mostly impregnated with heavy metals such as iron and manganese resulting from diagenetic metasomatism and replacement processes of. Fish teeth (< 2 mm) and oolite of iron were also noticed in most of the samples. The morphology of heavy mineral grains shows that most of the grains are angular to subangular suggesting that they were transported for short distance from their source rocks. Normally, phosphate pellets, gloconite and iron ooids are not considered since their original morphological features show clear roundness that attributed to their sedimentological origin, not to transportation factor. The source rock of most of the heavy mineral assemblage is the basalt. Apatite and gloconite are derived from the phosphorite and phosphatized limestone encountered

Geochemical investigations by the U.S. Geological Survey on uranium mining, milling, and environmental restoration

Science.gov (United States)

Landa, Edward R.; Cravotta, Charles A.; Naftz, David L.; Verplanck, Philip L.; Nordstrom, D. Kirk; Zielinski, Robert A.

2000-01-01

Recent research by the U.S. Geological Survey has characterized contaminant sources and identified important geochemical processes that influence transport of radionuclides from uranium mining and milling wastes. 1) Selective extraction studies indicated that alkaline earth sulfates and hydrous ferric oxides are important hosts of 226Ra in uranium mill tailings. The action of sulfate-reducing and ironreducing bacteria on these phases was shown to enhance release of radium, and this adverse result may temper decisions to dispose of uranium mill tailings in anaerobic environments. 2) Field studies have shown that although surface-applied sewage sludge/wood chip amendments aid in revegetating pyritic spoil, the nitrogen in sludge leachate can enhance pyrite oxidation, acidification of groundwater, and the consequent mobilization of metals and radionuclides. 3) In a U.S. Environmental Protection Agencyfunded study, three permeable reactive barriers consisting of phosphate-rich material, zero-valent iron, or amorphous ferric oxyhydroxide have been installed at an abandoned uranium upgrader facility near Fry Canyon, UT. Preliminary results indicate that each of the permeable reactive barriers is removing the majority of the uranium from the groundwater. 4) Studies on the geochemistry of rare earth elements as analogues for actinides such as uranium and thorium in acid mine drainage environments indicate high mobility under acid-weathering conditions but measurable attenuation associated with iron and aluminum colloid formation. Mass balances from field and laboratory studies are being used to quantify the amount of attenuation. 5) A field study in Colorado demonstrated the use of 234U/238U isotopic ratio measurements to evaluate contamination of shallow groundwater with uranium mill effluent.

Geochemical characteristics of Lower Jurassic source rocks in the Zhongkouzi Basin

Science.gov (United States)

Niu, Haiqing; Han, Xiaofeng; Wei, Jianshe; Zhang, Huiyuan; Wang, Baowen

2018-01-01

Zhongkouzi basin is formed in Mesozoic and Cenozoic and developed on the Hercynian folded belt, the degree of exploration for oil and gas is relatively low hitherto. In order to find out the geochemical characteristics of the source rocks and the potentials for hydrocarbon generation. The research result shows that by analysis the geochemical characteristics of outcrop samples and new core samples in Longfengshan Group, Longfengshan Group are most developed intervals of favorable source rocks. They are formed in depression period of the basin when the sedimentary environments is salt water lacustrine and the water is keeping stable; The organic matter abundance is middle-higher, the main kerogen type is II1-II2 and few samples act as III type, The organic matter maturity is low maturity to medium maturity. The organic matter maturity of the source rock from eastern part of the basin is higher than in the western region. The source rock of Longfengshan Group are in the hydrocarbon generation threshold. The great mass of source rocks are matured and in the peak stage of oil generation.

Geochemical dispersion of uranium near prospects in Pennsylvania

International Nuclear Information System (INIS)

Rose, A.W.; Schmiermund, R.L.; Mahar, D.L.

1977-06-01

The geochemical dispersion of U was investigated near sedimentary uranium prospects in eastern and north-central Pennsylvania. Near Jim Thorpe, known uranium occurrences in the Catskill Fm. are limited to the base of the Duncannon member. At Penn Haven Junction, roll-type U deposits with appreciable Pb and Se are localized adjacent to an oxidized tongue of channel-filling conglomeratic sandstone. The channel and encircling U occurrences furnish a large target for geochemical exploration. Selective extractions show that the organic, Fe-oxide, sand and silt fractions of stream sediments are the major hosts for U in stream sediments. Fe-oxides have a greater affinity for U than organic matter but are less abundant. The U content of organic matter is about 10 5 times the U content of stream water. Stream sediments furnish a representative sample of the average content of U, Zn, Cu, and major elements in soils of a drainage basin in north-central Pennsylvania, so a semiquantitative appraisal of weathering uranium occurrences can be made from stream sediments in climates and topography like Pennsylvania. The flux of uranium leaving the basin in solution is about equal to that leaving as sediment. Uranium is considerably less mobile than Ca and Na. A new method of extracting uranium from water samples, using a liquid ion exchanger (Amberlite LA-1), shows promise for simple field application

Geochemical mapping of Anheung, Wonju and Eomjeong sheets (1:50,000)

Energy Technology Data Exchange (ETDEWEB)

Lee, Jin Soo; Seo, Hyo Joon; Shin, Seong Cheon; Chi, Se Jung; Kim, Seong Jae [Korea Inst. of Geology Mining and Materials, Taejon (Korea, Republic of)

1995-12-01

A geochemical mapping was undertaken on the three quadrangles of the Anheung, Wonju and Eomjeong sheets (1:50,000, new edition) in the southwestern Taebaeg Mineralized Belt. The survey area, ca. 1,900 km{sup 2}, is covered mostly by Jurassic granites and Precambrian metamorphic rocks, and partly by Cambro-Ordovician limestones and the Cretaceous igneous and sedimentary rocks. Light mineral stream sediments and water samples, totally 751 for each media, were collected from active channels of primary or secondary order with a mean sampling density of 1/2.4 km{sup 2}. Geochemical maps were made on 17 elements (i.e., Ag, Al, As, Ba, Cd, Co, Cr, Cu, Fe, Mn, Mo, Ni, Pb, Sr, V, W, Zn) for stream sediments. Geochemical distribution maps for water samples were independently made on major and minor components (i.e., Na, K, Li, Si, Ca, Mg, Al, As, B, Ba, Cd, Co, Cr, Cu, Fe, Mn, Mo, Ni, Pb, Sr, V, Zn, F{sup -}, Cl{sup -}, NO{sub 3}{sup -}, NO{sub 2}{sup -}, PO{sub 4}{sup 3-}, SO{sub 4}{sup 2-}, HCO{sub 3}{sup -}) and other physico-chemical properties (i.e., Electric Conductivity, Total Dissolved Solids, pH, Dissolved Oxygen). Analysis was carried out by Ion Coupled Plasma Spectrometry and Ion Chromatography. Geochemical anomalies were evaluated based upon geological and other field information. The Ag-As, Cu-Pb-Zn and W-Mo anomalies of stream sediments in the northern Anheung and southern Eomjeong sheets indicate a contamination derived from mining districts. Pb-Zn anomalies from southeastern area in the Eomjeong sheet may suggest a potential of polymetallic deposits near Mesozoic granites intruding the Ogcheon strata. High concentrations of Ca, Na, K, Cl{sup -} and NO{sub 3}{sup -} in stream waters around Chungju and Wonju imply a strong pollution over urban districts and stock farms. (author). 57 refs., 70 figs.

Geochemical Constraints on Archaeal Diversity in the Vulcano Hydrothermal System

Science.gov (United States)

Rogers, K. L.; Amend, J. P.

2006-12-01

The shallow marine hydrothermal system of Vulcano, Italy hosts a wide diversity of cultured thermophilic Archaea, including Palaeococcus helgesonii, Archaeoglobus fulgidus, and Pyrococcus furiosus, to name a few. However, recent studies have revealed a plethora of uncultured archaeal lineages in the Vulcano system. For example, a 16S rRNA gene survey of an onshore geothermal well identified a diverse archaeal community including deeply-branching uncultured Crenarchaeota, Korarchaeota, and Euryarchaeota. Additionally, culture-independent hybridization techniques suggested that Archaea account for nearly half of the microbial community in the Vulcano system. Furthermore, geochemical characterization of fluids revealed numerous lithotrophic and heterotrophic exergonic reactions that could support as yet uncultured organisms. Archaeal diversity throughout the Vulcano hydrothermal system was investigated using 16S rRNA gene surveys at five submarine vents and an onshore sediment seep. Overall, archaeal diversity was higher (10 groups) at submarine vents with moderate temperatures (59°C) compared with higher temperature (94°C) vents (4 groups). Archaeal communities at the moderately thermal vents were dominated by Thermococcales and also contained Archaeoglobales, Thermoproteales, and uncultured archaea among the Korarchaeota, Marine Group I, and the Deep-sea Hydrothermal Vent Euryarchaeota (DHVE). Fluid composition also affects the microbial community structure. At two high-temperature sites variations in archaeal diversity can be attributed to differences in iron and hydrogen concentrations, and pH. Comparing sites with similar temperature and pH conditions suggests that the presence of Desulfurococcales is limited to sites at which metabolic energy yields exceed 10 kJ per mole of electrons transferred. The Vulcano hydrothermal system hosts diverse archaeal communities, containing both cultured and uncultured species, whose distribution appears to be constrained by

Geochemical Investigations of Groundwater Stability

International Nuclear Information System (INIS)

Bath, Adrian

2006-05-01

The report describes geochemical parameters and methods that provide information about the hydrodynamic stability of groundwaters in low permeability fractured rocks that are potential hosts for radioactive waste repositories. Hydrodynamic stability describes the propensity for changes in groundwater flows over long timescales, in terms of flow rates and flow directions. Hydrodynamic changes may also cause changes in water compositions, but the related issue of geochemical stability of a potential repository host rock system is outside the scope of this report. The main approaches to assessing groundwater stability are numerical modelling, measurement and interpretation of geochemical indicators in groundwater compositions, and analyses and interpretations of secondary minerals and fluid inclusions in these minerals. This report covers the latter two topics, with emphasis on geochemical indicators. The extent to which palaeohydrogeology and geochemical stability indicators have been used in past safety cases is reviewed. It has been very variable, both in terms of the scenarios considered, the stability indicators considered and the extent to which the information was explicitly or implicitly used in assessing FEPs and scenarios in the safety cases. Geochemical indicators of hydrodynamic stability provide various categories of information that are of hydrogeological relevance. Information about groundwater mixing, flows and water sources is potentially provided by the total salinity of groundwaters, their contents of specific non-reactive solutes (principally chloride) and possibly of other solutes, the stable isotopic ratio of water, and certain characteristics of secondary minerals and fluid inclusions. Information pertaining directly to groundwater ages and the timing of water and solute movements is provided by isotopic systems including tritium, carbon-14, chlorine-36, stable oxygen and hydrogen isotopes, uranium isotopes and dissolved mobile gases in

Geochemistry as a prospecting method for uranium in Nuclebras (Empresas Nucleares Brasileiras)

International Nuclear Information System (INIS)

Pereira, N.M.

1982-01-01

The geochemical services useful to the uranium prospecting, mainly those refering to the geochemical exploration, are discussed. The application to the geochemical services in the uranium research adopted by Nuclebras is basically oriented by the goals to be reached in each survey. Geochemistry has been more applied to: a) identification of ore-bodies and zones; b) delimitation of ore bodies and c) establishment of geochemical models. (E.G.) [pt

Report on the geothermal development promotion survey. No.C-2. Wasabizawa area; Chinetsu kaihatsu sokushin chosa hokokusho. No.C-2 Wasabizawa chiiki

Energy Technology Data Exchange (ETDEWEB)

NONE

1998-03-01

The paper summed up the results of the survey of the geothermal development promotion survey - Wasabizawa area which was carried out in Yuzawa City and Ogachi Town, Akita Prefecture, from FY 1993 to FY 1996. In the survey, the following were conducted: surface survey such as geological alteration zone survey, fluid geochemical survey, gravity survey and electromagnetic exploration, temperature log by drilling 9 exploration wells, short-term/long-term jetting test, etc. Further, using the data obtained from these, analysis was made of geology/reservoir structure, thermal structure, geothermal water/hydraulic structure, geothermal system models, etc. As a result, a high-temperature (about 300 degrees C) zone promising as the geothermal development area was picked out, and the existence was confirmed of a dominant geothermal reservoir around the fault. In the jetting test, a total steam amount of 111.6 t/h was confirmed, and from the reservoir simulation, the result was obtained that there was a high possibility of 30-year power generation of 30MW/y. As a result of studying 'a power generation system by small-scale unit serial development' considering regional characteristics in the Wasabizawa area, the power generation cost (sending end, 15-year average) was estimated at approximately 9-10 yen/kWh. (NEDO)

Report on the geothermal development promotion survey. No.C-2. Wasabizawa area; Chinetsu kaihatsu sokushin chosa hokokusho. No.C-2 Wasabizawa chiiki

Energy Technology Data Exchange (ETDEWEB)

NONE

1998-03-01

The paper summed up the results of the survey of the geothermal development promotion survey - Wasabizawa area which was carried out in Yuzawa City and Ogachi Town, Akita Prefecture, from FY 1993 to FY 1996. In the survey, the following were conducted: surface survey such as geological alteration zone survey, fluid geochemical survey, gravity survey and electromagnetic exploration, temperature log by drilling 9 exploration wells, short-term/long-term jetting test, etc. Further, using the data obtained from these, analysis was made of geology/reservoir structure, thermal structure, geothermal water/hydraulic structure, geothermal system models, etc. As a result, a high-temperature (about 300 degrees C) zone promising as the geothermal development area was picked out, and the existence was confirmed of a dominant geothermal reservoir around the fault. In the jetting test, a total steam amount of 111.6 t/h was confirmed, and from the reservoir simulation, the result was obtained that there was a high possibility of 30-year power generation of 30MW/y. As a result of studying 'a power generation system by small-scale unit serial development' considering regional characteristics in the Wasabizawa area, the power generation cost (sending end, 15-year average) was estimated at approximately 9-10 yen/kWh. (NEDO)

Geochemical signature of columbite-tantalite and radiometric survey of radioactive pegmatites in the region of Parelhas, Rio Grande do Norte, Brazil; Assinatura geoquimica de columbita-tantalita e levantamento radiometrico de pegmatitos radioativos da regiao de Parelhas, RN, Brasil

Energy Technology Data Exchange (ETDEWEB)

Moura, Jorge Costa de

2013-07-01

This thesis is the result of geochemical, structural and radiometric investigations on radioactive pegmatites of the Borborema Pegmatitic Province in Northeast Brazil. The studied area, located in the surroundings of the city of Parelhas in the region of the Serra da Borborema, is well known for its thousands of pegmatitic bodies exploited in primitive mines called 'garimpos'. The main goal was to find an efficient, cheap and routine inspection procedure to identify the origin of commercialized radioactive columbite-tantalite (coltan) ore. The Brazilian Nuclear Energy Agency (CNEN) controls uranium commerce and nuclear activity in Brazil. Without an effective method to characterize coltan ores from different localities it is impossible to control the trade. The here presented new method was developed by correlating structural features of these pegmatites with the geochemical behavior of their coltan samples. It was found that the variation of the ratio U/Th versus Nb{sub 2}O{sub 5}/Ta{sub 2}O{sub 5} provides geochemical signatures (analytical fingerprints) for the source location of such ore. A test of the new method with coltan samples of commercial batches from the Brazilian states Amapa and Rondonia also generated distinct geochemical signatures. A radiometric survey (CPS) was carried out in several mines and pegmatites to study the environmental impact of gamma radiation. It included in situ measurements of pegmatite walls, host rocks, soil, and accumulated water and revealed that gamma emitters are hardly solubilized and environmental gamma radiation therefore generally is not enhanced to a dangerous level. (author)

Geochemical signature of columbite-tantalite and radiometric survey of radioactive pegmatites in the region of Parelhas, Rio Grande do Norte, Brazil; Assinatura geoquimica de columbita-tantalita e levantamento radiometrico de pegmatitos radioativos da regiao de Parelhas, RN, Brasil

Energy Technology Data Exchange (ETDEWEB)

Moura, Jorge Costa de

2013-07-01

This thesis is the result of geochemical, structural and radiometric investigations on radioactive pegmatites of the Borborema Pegmatitic Province in Northeast Brazil. The studied area, located in the surroundings of the city of Parelhas in the region of the Serra da Borborema, is well known for its thousands of pegmatitic bodies exploited in primitive mines called 'garimpos'. The main goal was to find an efficient, cheap and routine inspection procedure to identify the origin of commercialized radioactive columbite-tantalite (coltan) ore. The Brazilian Nuclear Energy Agency (CNEN) controls uranium commerce and nuclear activity in Brazil. Without an effective method to characterize coltan ores from different localities it is impossible to control the trade. The here presented new method was developed by correlating structural features of these pegmatites with the geochemical behavior of their coltan samples. It was found that the variation of the ratio U/Th versus Nb{sub 2}O{sub 5}/Ta{sub 2}O{sub 5} provides geochemical signatures (analytical fingerprints) for the source location of such ore. A test of the new method with coltan samples of commercial batches from the Brazilian states Amapa and Rondonia also generated distinct geochemical signatures. A radiometric survey (CPS) was carried out in several mines and pegmatites to study the environmental impact of gamma radiation. It included in situ measurements of pegmatite walls, host rocks, soil, and accumulated water and revealed that gamma emitters are hardly solubilized and environmental gamma radiation therefore generally is not enhanced to a dangerous level. (author)

Evaluation of selected geochemical anomalies in Colorado and the Southeastern US. Final report

International Nuclear Information System (INIS)

Carpenter, R.H.

1980-08-01

This study demonstrates the utility of HSSR geochemical data from stream sediment in exploration for uranium. In the southeastern US, four uraniferous occurrences and associated radiometric anomalies were identified in areas where uranium mineralization has not been previously reported. At two localities, assays of about .01% have been obtained from saprolite. There is some evidence which suggests that uranium may have been leached at these localities and that higher grades of U are likely at depth

A comparison of iron oxide-rich joint coatings and rock chips as geochemical sampling media in exploration for disseminated gold deposits

Science.gov (United States)

Crone, W.; Larson, L.T.; Carpenter, R.H.; Chao, T.T.; Sanzolone, R.F.

1984-01-01

We evaluated the effectiveness of iron oxide-rich fracture coatings as a geochemical sampling medium for disseminated gold deposits, as compared with conventional lithogeochemical methods, for samples from the Pinson mine and Preble prospect in southeastern Humboldt County, Nevada. That disseminated gold mineralization is associated with Hg, As, and Sb is clearly demonstrated in these deposits for both fracture coatings and rock chip samples. However, the relationship is more pronounced for fracture coatings. Fracture coatings at Pinson contain an average of 3.61, 5.13, 14.37, and 3.42 times more Au, As, Sb and Hg, respectively, than adjacent rock samples. At Preble, fracture coatings contain 3.13, 9.72, 9.18, and 1.85 times more Au, As, Sb and Hg, respectively, than do adjacent rock samples. Geochemical anomalies determined from fracture coatings are thus typically more intense than those determined from rock samples for these elements. The sizes of anomalies indicated by fracture coatings are also somewhat larger, but this is less obvious. In both areas, Sb anomalies are more extensive in fracture coatings. At Preble, some Hg and Au anomalies are also more extensive in fracture coatings. In addition to halos formed by the Hg, As and Sb, high values for Au/Ag and Zn/(Fe + Mn) are closely associated with gold mineralization at the Pinson mine. The large enhancement in geochemical response afforded by fracture coatings indicates a definite potential in the search for buried disseminated gold deposits. ?? 1984.

Monitoring active volcanoes: The geochemical approach

Directory of Open Access Journals (Sweden)

Takeshi Ohba

2011-06-01

Full Text Available

The geochemical surveillance of an active volcano aims to recognize possible signals that are related to changes in volcanic activity. Indeed, as a consequence of the magma rising inside the volcanic "plumbing system" and/or the refilling with new batches of magma, the dissolved volatiles in the magma are progressively released as a function of their relative solubilities. When approaching the surface, these fluids that are discharged during magma degassing can interact with shallow aquifers and/or can be released along the main volcano-tectonic structures. Under these conditions, the following main degassing processes represent strategic sites to be monitored.

The main purpose of this special volume is to collect papers that cover a wide range of topics in volcanic fluid geochemistry, which include geochemical characterization and geochemical monitoring of active volcanoes using different techniques and at different sites. Moreover, part of this volume has been dedicated to the new geochemistry tools.

Geochemical Interactions and Viral-Prokaryote Relationships in Freshwater Environments

Science.gov (United States)

Kyle, J. E.; Ferris, G.

2009-05-01

Viral and prokaryotic abundances were surveyed throughout southern Ontario aquatic habitats to determine relationships with geochemical parameters in the natural environment. Surface water samples were collected from acid mine drainage in summer of 2007 and 2008 and from circum-neutral pH environments in October to November 2008. Site determination was based on collecting samples from various aquatic habitats (acid mine drainage, lakes, rivers, tributaries, wetlands) with differing bedrock geology (limestone and shale dominated vs granitic Canadian Shield) to obtain a range of geochemical conditions. At each site, measurements of temperature, pH, and Eh were conducted. Samples collected for microbial counts and electron imaging were preserved to a final concentration of 2.5 % (v/v) glutaraldehyde. Additional sample were filtered into 60 mL nalgene bottles and amber EPA certified 40 mL glass vials to determine chemical constituents and dissolved organic carbon (DOC), respectively. Water was also collected to determine additional physiochemical parameters (dissolved total iron, ferric iron, nitrate, sulfate, phosphate, alkalinity, and turbidity). All samples were stored at 4 °C until analysis. Viral and prokaryotic abundance was determined by staining samples with SYBR Green I and examining with a epifluorescence microscope under blue excitation. Multiple regression analysis using stepwise backwards regression and general linear models revealed that viral abundance was the most influential predictor of prokaryotic abundance. Additional predictors include pH, sulfate, phosphate, and magnesium. The strength of the model was very strong with 90 % of the variability explained (R2 = 0.90, p < 0.007). This is the first report, to our knowledge, of viruses exhibiting such strong controls over prokaryotic abundance in the natural environment. All relationships are positively correlated with the exception of Mg, which is negatively correlated. Iron was also noted as a

The isotope X-ray fluorescence analysis and its application in geochemical investigations in Greenland

International Nuclear Information System (INIS)

Kunzendorf, H.

1973-01-01

The applicability of the isotope X-ray fluorescence analysis (IRFA) in the geochemical exploration was investigated. Detection limits of about 0.1% for the elements Ti, Zr, Nb, Mo and La+Ce were achieved in terrain measurements. Detection limits of 0.05% were found in the analysis of Cr, Ni, Cu, Zn, Zr, Nb, Mo, La+Ce and Pb in finely grinded rock samples. Geochemical investigations were carried out in the Ilimaussag-Intrusion in south Greenland as well as on the Mo deposits Malmbjerg and the heavy mineral occurence 'kote 800' in East Greenland. The use of portable IRFA equipment proved to be particularly suitable in the analysis of bed rocks, loose rock samples such as moraine material, in the semi-quantitative analysis of heavy mineral concentrates, the analysis of bored cores during the boring programme, as well as the analysis of finely grinded rock samples. (ORU) [de

Alligator Rivers Analogue project. Geochemical Data Bases

International Nuclear Information System (INIS)

Bennett, D.G.; Read, D.

1992-01-01

The Koongarra uranium deposit in the Northern Territory of Australia is being studied to evaluate the processes involved in the geochemical alteration of the ore body and the formation of the uranium dispersion fan. A broad range of research is being undertaken into the geochemistry and hydrology of the site with the aim of understanding the transport of radionuclides through the system. During the project a range of geochemical and hydrogeochemical models have been developed to account for measured data from the site and with which to predict site evolution. The majority of these models are based on the premise of thermodynamic chemical equilibrium and employ fundamental thermodynamic data to characterise the chemistry of the system. From the differences which exist between the thermodynamic data bases (Appendices I and II) it is possible to gain a view of the level of uncertainty associated with thermodynamic data in each set of calculations. This report gives a brief introduction to the geochemical processes underlying the models, and details the equations used to quantify the more common of these processes (e.g. aqueous speciation and mineral solubility). A description is given of the computer codes (EQ3/6, PHREEQE, MINTEQ) most commonly used during the project for geochemical modelling. Their key features are highlighted and comparisons made. It is concluded that the degree of uncertainty in geochemical modelling studies arising as a result of using one code rather than another is relatively insignificant when compared to that related to differences in the underlying data bases. 73 refs., 3 figs

FY 1998 report on the data processing of the geothermal development promotion survey. Secondary. No.B-5 Mt. Musadake area; 1998 nendo chinetsu kaihatsu sokushin chosa data shori hokokusho. No. B-5 Musadake chiiki (Dai 2 ji)

Energy Technology Data Exchange (ETDEWEB)

NONE

2000-01-01

As part of the geothermal development promotion survey, the comprehensive analysis was made on the survey of the existence amount of geothermal resource in the Mt. Musadake area, Shibetsu county, Hokkaido, which was conducted in FY 1997 and FY 1998. In the surface survey, the following were carried out: survey of geology/alteration zone, geochemical survey, gravity exploration, wide-area gravity/magnetic structure analysis, seismic exploration, etc. In the well exploration, structural boreholes N10-MD-1 and N10-MD-2 were drilled, and the following were conducted: temperature logging/temperature recovery test, electric logging, water injection test and survey of core cuttings. For borehole N10-MD-2, the survey of geothermal water was made. In the survey of environmental effects, survey of flora/fauna and survey of hot spring variations were conducted. The results of the analysis were outlined as follows. At deep underground, the existence of the deep geothermal water forming geothermal reservoirs is presumed, and the deep geothermal water seems to be helped by the thermal conduction from the magma reservoir related to a series of volcanoes, centered on Mt. Musadake that is regarded as heat source. The geothermal water has a temperature of over 250 degrees C and a high Cl concentration. (NEDO)

Geochemical Investigations of Groundwater Stability

Energy Technology Data Exchange (ETDEWEB)

Bath, Adrian [Intellisci Ltd., Loughborough (United Kingdom)

2006-05-15

The report describes geochemical parameters and methods that provide information about the hydrodynamic stability of groundwaters in low permeability fractured rocks that are potential hosts for radioactive waste repositories. Hydrodynamic stability describes the propensity for changes in groundwater flows over long timescales, in terms of flow rates and flow directions. Hydrodynamic changes may also cause changes in water compositions, but the related issue of geochemical stability of a potential repository host rock system is outside the scope of this report. The main approaches to assessing groundwater stability are numerical modelling, measurement and interpretation of geochemical indicators in groundwater compositions, and analyses and interpretations of secondary minerals and fluid inclusions in these minerals. This report covers the latter two topics, with emphasis on geochemical indicators. The extent to which palaeohydrogeology and geochemical stability indicators have been used in past safety cases is reviewed. It has been very variable, both in terms of the scenarios considered, the stability indicators considered and the extent to which the information was explicitly or implicitly used in assessing FEPs and scenarios in the safety cases. Geochemical indicators of hydrodynamic stability provide various categories of information that are of hydrogeological relevance. Information about groundwater mixing, flows and water sources is potentially provided by the total salinity of groundwaters, their contents of specific non-reactive solutes (principally chloride) and possibly of other solutes, the stable isotopic ratio of water, and certain characteristics of secondary minerals and fluid inclusions. Information pertaining directly to groundwater ages and the timing of water and solute movements is provided by isotopic systems including tritium, carbon-14, chlorine-36, stable oxygen and hydrogen isotopes, uranium isotopes and dissolved mobile gases in

Wide-field Infrared Survey Explorer Observations of the Evolution of Massive Star-forming Regions

OpenAIRE

Koenig, X. P.; Leisawitz, D. T.; Benford, D. J.; Rebull, L. M.; Padgett, D. L.; Assef, R. J.

2012-01-01

We present the results of a mid-infrared survey of 11 outer Galaxy massive star-forming regions and 3 open clusters with data from the Wide-field Infrared Survey Explorer (WISE). Using a newly developed photometric scheme to identify young stellar objects and exclude extragalactic contamination, we have studied the distribution of young stars within each region. These data tend to support the hypothesis that latter generations may be triggered by the interaction of winds and radiation from th...

Reconnaissance geochemical exploration of the plutons of quartz monzonite and granite in the Jabal Lababa and Ar Rayth areas, southern Asir, Kingdom of Saudi Arabia

Science.gov (United States)

Overstreet, W.C.; Assegaff, A.B.; Jambi, Mohammed; Hussain, M.A.; Selner, G.I.; Matzko, J.J.

1985-01-01

Geochemical reconnaissance for rare metals in plutons of albite-muscovite granite and quartz monzonite in the vicinity of Jabal Lababa disclosed positive geochemical anomalies for beryllium, tantalum, thorium, lanthanum, niobium, tin, yttrium, and zirconium. The low anomalous values for the rare metals in rocks and the short mechanical dispersion trains, seldom exceeding 4 km in length, of rare-metal-bearing heavy minerals, are interpreted to indicate that primary deposits of these metals are lacking, and any placers would be small and low in tenor.

pplication of Fractal Technique for Analysis of Geophysical - Geochemical Databases in Tekieh Pb-Zn Ore Deposit (SE of Arak

Directory of Open Access Journals (Sweden)

Seyed Reza Mehrnia

2017-02-01

should emphasize on self-organized distribution of Pb-Zn anomalies to introduce a new set of nonlinear distributions in order to find the confidence regression coefficients between the variables. As the final results, fractal analysis of available databases represented new target areas with better mineralization aggregations than linear analysis of the anomalous regions according to micrographs. It means that surficial mineralization processes could be extended in depth and enriched next to altered host units because of a nonlinear but self-organized distribution of geochemical- geophysical anomalies in Tekieh ore deposit region. References Annells, R.N., Arthurton, R.S., Bazley, R.A.B., Davies, R.G., Hamedi, M.A.R. and Rahimzadeh, F.R., 1985. Geological Map of Shazand- Khomein. Scale: 1:100000, Cartographic Department of Geological Survey of Iran. Calagari, A.A., 2010. Principles of geophysical explorations. University of Tabriz, Tabriz, 485 pp. Jafari, H., 2007. Using geoelectrical techniques for Zn-Pb explorations in Haft-Emarat district, Tekieh region (South East of Arak. Kimya Kavan Tosee Novin Company, Tehran, 206 pp. Mandelbrot, B., 2005. Fractal Geometry of Nature. W.H Freeman & Company, New York, 468 pp. Mehrnia, S.R.,2013. Application of fractal geometry for recognizing the pattern of textural zoning in epithermal deposits: (case study: Shikhdarabad Au-Cu indices East- Azerbaijan province. Journal of Economic Geology, 5(1: 23-36. (in Persian Momenzadeh, M. and Ziseman, H., 1981. Lead – Zinc re mineralization potentials in Malayer – Esfahan district. Journal of Ore Deposit, 3(1: 88-101. Salehi, L., 2004. Geochemistry of REE content in Tekieh Pb-Zn ore deposit. M.Sc. Thesis, Shahid Beheshti University, Tehran, Iran, 181 pp. Torkashvand, S., Mehrnia, S.R. and Moghaddasi, S.J., 2009. Co-Processing of the geophysical parameters for Tekieh Zn-Pb ore deposits (south east of Arak. 4th PNU Geological National Conference, Payam Noor University of Mashhad, Mashhad

Geology, Geochemistry and Ground Magnetic Survey on Kalateh Naser Iron Ore Deposit, Khorasan Jonoubi Province

Directory of Open Access Journals (Sweden)

Saeed Saadat

2017-02-01

Full Text Available Introduction Ground magnetometer surveys is one of the oldest geophysical exploration methods used in identifying iron reserves. The correct interpretation of ground magnetic surveys, along with geological and geochemical data will not only reduce costs but also to indicate the location, depth and dimensions of the hidden reserves of iron (Robinson and Coruh, 2005; Calagari, 1992. Kalateh Naser prospecting area is located at 33° 19َ to 33° 19ََ 42" latitude and 60° 0' to 60° 9َ 35" longitude in the western side of the central Ahangaran mountain range, eastern Iran (Fig.1. Based on primary field evidences, limited outcrops of magnetite mineralization were observed and upon conducting ground magnetic survey, evidence for large Iron ore deposits were detected (Saadat, 2014. This paper presents the geological and geochemical studies and the results of magnetic measurements in the area of interest and its applicability in exploration of other potential Iron deposits in the neighboring areas. Materials and methods To better understand the geological units of the area, samples were taken and thin sections were studied. Geochemical studies were conducted through XRF and ICP-Ms and wet chemistry analysis. The ground magnetic survey was designed to take measurements from grids of 20 meter apart lines and 10 meter apart points along the north-south trend. 2000 points were measured during a 6-day field work by expert geophysicists. Records were made by Canadian manufactured product Magnetometer Proton GSM19T (Fig. 2. Properties of Proton Magnetometer using in magnetic survey in Kalateh Naser prospecting area is shown in Table 1. Total magnetic intensity map, reduced to pole magnetic map, analytic single map, first vertical derivative map and upward continuation map have been prepared for this area. Results The most significant rock units in the area are cretaceous carbonate rocks (Fig. 3. The unit turns to shale and thin bedded limestone in the

Distinguishing of uranium-bearing sandstone by the geochemical characteristics in northern Sichuan

International Nuclear Information System (INIS)

Wang Wangzhang; Zhang Zhufeng; Wang Yunliang; Sun Shuqin.

1994-01-01

Expounding geochemical characteristics of sandstone-type uranium deposits in northern Sichuan, the authors demonstrate the favourable and unfavourable conditions for enrichment of uranium on the basis of element abundances and ratios of U, Th and K measured by the gamma-ray spectroscopy surveying. The differences between uranium-bearing and non-uranium sandstones and between red sandstone (clay stone) and greenish sandstone can be determined by the gamma-ray spectroscopy (measuring U, Th and K) and XRF analysis (measuring As and Ba). Therefore, the prospecting of the sandstone-type uranium deposits in northern Sichuan can be concentrated in a certain range

Sharp fronts within geochemical transport problems

International Nuclear Information System (INIS)

Grindrod, P.

1995-01-01

The authors consider some reactive geochemical transport problems in groundwater systems. When incoming fluid is in disequilibrium with the mineralogy sharp transition fronts may develop. They show that this is a generic property for a class of systems where the timescales associated with reaction and diffusion phenomena are much shorter than those associated with advective transport. Such multiple timescale problems are relevant to a variety of processes in natural systems: mathematically methods of singular perturbation theory reduce the dimension of the problems to be solved locally. Furthermore, they consider how spatial heterogeneous mineralogy can impact upon the propagation of sharp geochemical fronts. The authors developed an asymptotic approach in which they solve equations for the evolving geometry of the front and indicate how the non-smooth perturbations due to natural heterogeneity of the mineralogy on underlying ground water flow field are balanced against the smoothing effect of diffusion/dispersive processes. Fronts are curvature damped, and the results here indicate the generic nature of separate front propagation within both model (idealized) and natural (heterogeneous) geochemical systems

Tracking riverborne sediment and contaminants in Commencement Bay, Washington, using geochemical signatures

Science.gov (United States)

Takesue, Renee K.; Conn, Kathleen E.; Dinicola, Richard S.

2017-09-29

Large rivers carry terrestrial sediment, contaminants, and other materials to the coastal zone where they can affect marine biogeochemical cycles and ecosystems. This U.S. Geological Survey study combined river and marine sediment geochemistry and organic contaminant analyses to identify riverborne sediment and associated contaminants at shoreline sites in Commencement Bay, Puget Sound, Washington, that could be used by adult forage fish and other marine organisms. Geochemical signatures distinguished the fine fraction (contaminants were measured in surface sediment did not have measurable 7Be activities in that layer, so their contaminant assemblages were attributed to sources from previous years. Concentrations of organic contaminants (the most common of which were polycyclic aromatic hydrocarbons, polychlorinated biphenyls, and fecal sterols) were higher in the contaminants in marine rather than river sediment, indicates that riverborne sediment-bound contaminants are retained in shallow marine habitats of Commencement Bay. The retention of earlier inputs complicates efforts to identify recent inputs and sources. Understanding modern sources and fates of riverborne sediment and contaminants and their potential ecological impacts will therefore require a suite of targeted geochemical studies in such marine depositional environments.

The geological, geochemical, topographical and hydrogeological characteristics of the Broubster natural analogue site, Caithness

International Nuclear Information System (INIS)

Ball, T.K.; Milodowski, A.E.

1991-01-01

One of the four analogue sites chosen for investigation by the British Geological Survey is the uranium mineralization at Broubster, Caithness, Scotland. Naturally occurring uranium has been leached from a thin mineralized limestone horizon and has been carried by groundwater flow into a peat bog about 100 m away. This process has probably been going on for at least 5 000 years. Standard surveying, hydrogeological and geochemical methods have been applied in the investigation and analysis of the area. Selected samples of the mineralization, peat soils and associated groundwaters have been examined in detail. This report summarizes the main findings accumulated since 1968 when the site was first discovered, and provides a useful information base for further modelling work. 27 refs.; 12 plates; 40 figs.; 17 tabs

The geological, geochemical, topographical and hydrogeological characteristics of the Broubster natural analogue site, Caithness

International Nuclear Information System (INIS)

Ball, T.K.; Milodowski, A.E.

1989-06-01

One of the four natural analogue sites chosen for investigation by the British Geological Survey is the uranium mineralisation at Broubster, Caithness, Scotland. Naturally occurring uranium has been leached from a thin mineralised limestone horizon and has been carried by groundwater flow into a peat bog about 100m away. This process has probably been going on for at least 5000 years. Standard surveying, hydrogeological and geochemical methods have been applied in the investigation and analysis of the area. Selected samples of the mineralisation, peat soils and associated groundwaters have been examined in detail. This report summarises the main findings accumulated since 1968 when the site was first discovered, and provides a useful information base for further modelling work. (author)

Significance of geochemical characterization to performance at Yucca Mountain, Nevada

International Nuclear Information System (INIS)

Simmons, A.M.

1993-01-01

The U.S. concept for permanent disposal of high-level radioactive waste resembles those of other countries in that it relies upon burial in a deep geologic medium. This concept relies upon multiple barriers to retard transport of radionuclides to the accessible environment; those barriers consist of the waste form, waste container, engineered barrier system (including possible backfill) and retardant properties of the host rock. Because mobilization of radionuclides is fundamentally a geochemical problem, an understanding of past, present, and future geochemical processes is a requisite part of site characterization studies conducted by the U.S. Department of Energy at Yucca Mountain, Nevada. Geochemical information is needed for evaluating three favorable conditions (the rates of geochemical processes, conditions that promote precipitation or sorption of radionuclides or prohibit formation of colloids, and stable mineral assemblages) and four potentially adverse conditions of the site (groundwater conditions that could increase the chemical reactivity of the engineered barried system or reduce sorption, potential for gaseous radionuclide movement, and oxidizing groundwaters) for key issues of radionuclide release, groundwater quality, and stability of the geochemical environment. Preliminary results of long-term heating experiments indicate that although zeolites can be modified by long-term, low temperature reactions, their beneficial sorptive properties will not be adversely affected. Mineral reactions will be controlled by the aqueous activity of silica in groundwater with which the minerals are in contact. Geochemical barriers alone may satisfy release requirements to the accessible environment for many radionuclides; however, additional site specific geochemical and mineralogical data are needed to test existing and future radionuclide transport models

Robust statistics and geochemical data analysis

International Nuclear Information System (INIS)

Di, Z.

1987-01-01

Advantages of robust procedures over ordinary least-squares procedures in geochemical data analysis is demonstrated using NURE data from the Hot Springs Quadrangle, South Dakota, USA. Robust principal components analysis with 5% multivariate trimming successfully guarded the analysis against perturbations by outliers and increased the number of interpretable factors. Regression with SINE estimates significantly increased the goodness-of-fit of the regression and improved the correspondence of delineated anomalies with known uranium prospects. Because of the ubiquitous existence of outliers in geochemical data, robust statistical procedures are suggested as routine procedures to replace ordinary least-squares procedures

Coupling of transport and geochemical models

International Nuclear Information System (INIS)

Noy, D.J.

1985-01-01

This contract stipulated separate pieces of work to consider mass transport in the far-field of a repository, and more detailed geochemical modelling of the groundwater in the near-field. It was envisaged that the far-field problem would be tackled by numerical solutions to the classical advection-diffusion equation obtained by the finite element method. For the near-field problem the feasibility of coupling existing geochemical equilibrium codes to the three dimensional groundwater flow codes was to be investigated. This report is divided into two sections with one part devoted to each aspect of this contract. (author)

Integrated geophysical-geochemical methods for archaeological prospecting

OpenAIRE

Persson, Kjell

2005-01-01

A great number of field measurements with different methods and instruments were conducted in attempts to develop a method for an optimal combination of various geochemical and geophysical methods in archaeological prospecting. The research presented in this thesis focuses on a study of how different anthropogenic changes in the ground can be detected by geochemical and geophysical mapping and how the results can be presented. A six-year pilot project, Svealand in Vendel and Viking periods (S...

Retention/sorption and geochemical modelling

Energy Technology Data Exchange (ETDEWEB)

Arcos, D.; Grandia, F.; Domenech, C. [Enviros Spain, S.L., Barcelona (Spain); SCK-CEN, Mol (Belgium); Sellin, P. [SKB - Swedish Nuclear Fuel and Waste Management, SE, Stockholm (Sweden); Hunter, F.M.I.; Bate, F.; Heath, T.G.; Hoch, A. [Serco Assurance, Oxfordshire (United Kingdom); Werme, L.O. [SKB - Svensk Karnbranslehantering AB, Stockholm (Sweden); Bruggeman, C.; Maes, I.A.; Breynaert, E.; Vancluysen, J. [Leuven Katholieke Univ., Lab. for Colloid Chemistry (Belgium); Montavon, G.; Guo, Z. [Ecole des Mines, 44 - Nantes (France); Riebe, B.; Bunnenberg, C.; Meleshyn, A. [Leibniz Univ. Hannover, Zentrum fur Strahlenschutz und Radiookologie, Hannover (Germany); Dultz, S. [Leibniz Univ. Hannover, Institut fur Bodenkunde, Hannover (Germany)

2007-07-01

This session gathers 4 articles dealing with: the long-term geochemical evolution of the near field of a KBS-3 HLNW repository: insights from reactive transport modelling (D. Arcos, F. Grandia, C. Domenech, P. Sellin); the investigation of iron transport into bentonite from anaerobically corroding steel: a geochemical modelling study (F.M.I. Hunter, F. Bate, T.G. Heath, A. Hoch, L.O. Werme); SeO{sub 3}{sup 2-} adsorption on conditioned Na-illite: XAS spectroscopy, kinetics, surface complexation model and influence of compaction (C. Bruggeman, A. Maes, G. Montavon, E. Breynaert, Z. Guo, J. Vancluysen); the influence of temperature and gamma-irradiation on the anion sorption capacity of modified bentonites (B. Riebe, C. Bunnenberg, A. Meleshyn, S. Dultz)

Geochemical prospect ion results of Treinta y Tres aerial photo

International Nuclear Information System (INIS)

Zeegers, H.; Bonnefoy, D.; Garau, M.; Spangenberg, J.

1981-01-01

This report shows the geochemical prospect ion results carried out within the framework of the multielemental geochemical strategy. The samples were studied by e spectrometry in the laboratories of Orleans.

Western states uranium resource survey

International Nuclear Information System (INIS)

Tinney, J.F.

1977-01-01

ERDA's National Uranium Resource Evaluation (NURE) program was established to provide a comprehensive description of uranium resources in the United States. To carry out this task, ERDA has contracted with various facilities, including universities, private companies, and state agencies, to undertake projects such as airborne radiometric surveys, geological and geochemical studies, and the development of advanced geophysical technology. LLL is one of four ERDA laboratories systematically studying uranium distribution in surface water, groundwater, and lake and stream sediments. We are specifically responsible for surveying seven western states. This past year we have designed and installed facilities for delayed-neutron counting and neutron-activation analysis, completed seven orientation surveys, and analyzed several thousand field samples. Full-scale reconnaissance surveys began last fall

Geochemical and Geophysical Characteristics of the Balud Ophiolitic Complex (BOC, Masbate Island, Philippines: Implications for its Generation, Evolution and Emplacement

Directory of Open Access Journals (Sweden)

Pearlyn C. Manalo

2015-01-01

Full Text Available This paper presents the first field, geochemical and geophysical information on the recently recognized Early Cretaceous Balud Ophiolitic Complex (BOC in the island of Masbate in the Central Philippines. Mapping of the western limb of the island revealed that only the upper crustal section of the BOC is exposed in this area. Geochemically, the pillow basalts are characterized by transitional mid-oceanic ridge basalt-island arc tholeiitic compositions. Gravity surveys yielded low Bouguer anomaly values that are consistent with the highly dismembered nature of the BOC. Short wavelength, high amplitude magnetic anomalies registered across the study area are attributed to shallow magnetic sources. This is taken to support the model that the ophiolitic complex occurs as thin crustal slivers that are not deeply-rooted in the mantle. Comparing BOC with other ophiolites in the Central Philippines, such as those in the islands of Sibuyan, Leyte and Bohol, suggests the possibility of a common or contiguous source for similarly-aged and geochemically composed crust-mantle sequences in the region.

Geochemical studies of backfill aggregates, lake sediment cores and the Hueco Bolson Aquifer

Science.gov (United States)

Thapalia, Anita

Aquifer that an important sources of water in the El Paso/Cd. Juraez metroplex. To delineate the boundary between fresh and brackish water from the northern Hueco Bolson Aquifer, we utilize an integrative geochemical, geophysical, and sedimentological approach. The goal of this study is to use geophysical well-log analysis and the water chemical analysis for identifying the changes in the quality of the groundwater. A detailed microgravity survey is utilized to explore the subsurface geological structures that control the conduits and/or barriers of groundwater flow. A detailed geochemical analysis of aquifer samples provide salinity of groundwater that will complement to the subsurface structures obtained from the geophysical study. This fundamental research in developing methods from an integrated approach to estimate aquifer quality can be used as an analog for similar studies in other arid regions.

Geochemistry of soils along a transect from Central Mexico to the Pacific Coast: a pilot study for continental-scale geochemical mapping

Science.gov (United States)

Chiprés, J.A.; de la Calleja,; Tellez, J.I.; Jiménez, F.; Cruz, Carlos; Guerrero, E.G.; Castro, J.; Monroy, M.G.; Salinas, J.C.

2009-01-01

The Mexican Geological Survey (SGM), the National Institute of Statistics, Geography and Informatics (INEGI) and the Autonomous University of San Luis Potosi (UASLP) have established a multidisciplinary team with the objective of creating a national program of geochemical mapping of soils in Mexico. This is being done as part of the North American Soil Geochemical Landscapes Project in partnership with the US Geological Survey and the Geological Survey of Canada. As the first step, a pilot study was conducted over a transect that extends from the Mexico–US border near Ciudad Juarez in the north to the Pacific Ocean in the south. This pilot transect was conducted in two phases, and this paper presents results from the first phase, which sampled soils at about a 40-km spacing along a 730-km transect beginning in Central Mexico and ending at the Pacific Coast. Samples were collected from the A and C horizons at each site and 60 elements were analyzed. This pilot study demonstrates that geochemical mapping based on a 40-km spacing is adequate to identify broad-scale geochemical patterns. Geologic influence (i.e., soil parent material) was the most important factor influencing the distribution of elements along the transect, followed by the influence of regional mineralization. The study also showed that influence by human activities over the transect is minimal except possibly in large mining districts. A comparison of element abundance in the A horizon with the environmental soil guidelines in Mexico showed that the natural concentrations of the studied soils were lower than the established threshold for soil restoration with the exception of V and As. The former had a median value (75 mg/kg) approximately equal to the value established in Mexico for soil restoration in agricultural and residential lands (78 mg/kg), and the latter had three values higher than the 22 mg/kg threshold for soil restoration in agricultural and residential lands. These cases demonstrate

Geochemical behaviour of natural uranium-series nuclides in geological formation

International Nuclear Information System (INIS)

Yamakawa, Minoru

1991-01-01

Recent research and investigation show that the Tono uranium deposit and its natural uranium-series nuclides have been preserved, without any significant changes like re-migration or reconcentration, throughout geological events such as upheaval-submergence, marine transgression-regression, and faulting which can readily change geological, hydrogeological, and geochemical conditions. This situation might have come about as a result of being kept in a geometrical closure system, with reducing and milk alkalic geochemical conditions, from the hydrogeological and geochemical point of view. (author)

Geochemical exploration of a promissory Enhanced Geothermal System (EGS): the Acoculco caldera, Mexico.

Science.gov (United States)

Peiffer, Loic; Romero, Ruben Bernard; Pérez-Zarate, Daniel; Guevara, Mirna; Santoyo Gutiérrez, Edgar

2014-05-01

The Acoculco caldera (Puebla, Mexico) has been identified by the Mexican Federal Electricity Company (in Spanish 'Comisión Federal de Electricidad', CFE) as a potential Enhanced Geothermal System (EGS) candidate. Two exploration wells were drilled and promising temperatures of ~300° C have been measured at a depth of 2000 m with a geothermal gradient of 11oC/100m, which is three times higher than the baseline gradient measured within the Trans-Mexican Volcanic Belt. As usually observed in Hot Dry Rock systems, thermal manifestations in surface are scarce and consist in low-temperature bubbling springs and soil degassing. The goals of this study were to identify the origin of these fluids, to estimate the soil degassing rate and to explore new areas for a future detailed exploration and drilling activities. Water and gas samples were collected for chemical and isotopic analysis (δ18O, δD, 3He/4He, 13C, 15N) and a multi-gas (CO2, CH4, H2S) soil survey was carried out using the accumulation chamber method. Springs' compositions indicate a meteoric origin and the dissolution of CO2 and H2S-rich gases, while gas compositions reveal a MORB-type origin mixed with some arc-type contribution. Gas geothermometry results are similar to temperatures measured during well drilling (260° C-300° C). Amongst all measured CO2 fluxes, only 5% (mean: 5543 g m-2 day-1) show typical geothermal values, while the remaining fluxes are low and correspond to biogenic degassing (mean: 18 g m-2 day-1). The low degassing rate of the geothermal system is a consequence of the intense hydrothermal alteration observed in the upper 800 m of the system which acts as an impermeable caprock. Highest measured CO2 fluxes (above > 600 g m-2 day-1) have corresponding CH4/CO2 flux ratios similar to mass ratios of sampled gases, which suggest an advective fluid transport. To represent field conditions, a numerical model was also applied to simulate the migration of CO2 towards the surface through a

Geothermal development promotion survey report. No. 22. Noboribetsu region; 1987-1990 chinetsu kaihatsu sokushin chosa hokokusho. No. 22 Noboribetsu chiiki

Energy Technology Data Exchange (ETDEWEB)

NONE

1991-03-01

The results of surveys conducted in the Noboribetsu region, Hokkaido, in fiscal 1987-1989 are compiled in this report. Conducted in the surveys were a geological/alteration zone survey, geochemical survey, electromagnetic surveillance (simplified magnetotelluric method), electric prospecting (Schlumberger method), electric prospecting (mise-a-la-masse method), heat flow rate survey, structural boring, precision structural boring, environmental exploration well, geothermal water survey, environmental impact survey, and so forth. Conclusions reached on the basis of the survey results are described below. It is supposed that a horizon, positioned in the Osarugawa stratum in the Karls Noboribetsu zone or in a fissure system in the Omagarisawa stratum below the Osarugawa stratum, contains a geothermal reservoir. The hot water at the Noboribetsu hot spring originates in gas or geothermal water separated from the deep-seated geothermal water while that at the Karls hot spring or the like originates in meteoric water built up in higher places. Although an area abundant in geothermal fluids is supposed to exist in the Karls-Noboribetsu zone, yet a section located between the Karls-Noboribetsu zone and the Noboribetsu hot spring area also draws attention as a zone having a potential to store geothermal fluids. (NEDO)

Digitization of uranium deposit information in basin. A new strategy of ISL sandstone-type uranium deposits exploration

International Nuclear Information System (INIS)

Tan Chenglong

2006-01-01

The discovered ISL sandstone-type uranium deposits in the entire world are mostly blind deposits, many of them occur in bleak desert, gobi desert, and semi-hilly land area. Exploration methods for these deposits mainly depend on great and systematic drilling. There are many large-medium size Meso-Cenozoic sedimentary basins in northern China, and over twenty of them are thick overburden basins which are mostly the virgin land for ISL sandstone-type uranium deposit. Due to the comprehensive national power, geological background, uranium exploration ability, great and systematic drilling is not favorable for prospecting ISL sandstone-type uranium deposit in China. According to the exploration and prospecting experiences for mineral ore bodies at home and abroad, uranium information mapping based on geochemical survey of the basins is a new strategy for ISL sandstone-type uranium deposits. It is an economic, practical, fast and effective method, and has been manifested by the performing information digitization for oil and gas resources, gold mineral resources in China and the mapping of uranium information for whole Europe continent. (authors)

Gamma Spectrometric Determination of U, Th, K and Some Geochemical Applications

International Nuclear Information System (INIS)

Dodona, A.; Tashko, A.

2001-01-01

The application of 'in situ' gamma-spectrometric method (''infinite'' environment), made possible the simultanious determination of U, Th and K. 4 channel gamma-spectrometric analyser with NaI(TI) scintilation counter crystal detector (103 cm 3 φ=50x50mm) was used to determin U, Th(more than 1-2 ppm) and K (more than 1%) in laboratory conditions. The detector was inserted into a lead camera and calibrated for measurement geometry with vessel of ''Marineli'' type of a 17o cm 3 volume. The study of main factors, which influence in the gamma spectrometric measurements, (the technical, physical, geometrical and time parameters) has been carried out. International standards of U, Th, K and internal monitoring standard samples are used for the calibration. External analytical control has been realized by other radiometric and chemical methods. The detection limits ( 1 ppm Th, 2ppm U and 1% K) and the relative errors (17-20% for 1-10 ppm U, Th and 10-15% for more than 10 ppm U, Th and more than 1% K) guarantee a quantitative analysis that may be used successfully in the geochemical studies. Some geochemical applications, based on the content of Th, U and Th/U ratio in rocks samples that we have we have analyzed with this method, are shown in this paper. U, Th and their ratio are used as trace elements to indicate the differences between the acidic magmatic rocks of Albania (Th/U ratio=2-6 and>10). The bimodal character of Th/U scattering in ignimbrides and monzonites (Korabi zone) shows that in addition to the ''normal'' rocks, there are also some ones enriched with Th, So, the differential analysis of Th, U, and K may be used as geochemical exploration criteria for the radioactive and non-radioactive mineralization, such as REE (Rare Earth Elements), phospghorites, bauxites, placers etc. (authors)

Geothermal Exploration of Newberry Volcano, Oregon

Energy Technology Data Exchange (ETDEWEB)

Waibel, Albert F. [Columbia Geoscience, Pasco, WA (United States); Frone, Zachary S. [Southern Methodist Univ., Dallas, TX (United States); Blackwell, David D. [Southern Methodist Univ., Dallas, TX (United States)

2014-12-01

Davenport Newberry (Davenport) has completed 8 years of exploration for geothermal energy on Newberry Volcano in central Oregon. Two deep exploration test wells were drilled by Davenport on the west flank of the volcano, one intersected a hydrothermal system; the other intersected isolated fractures with no hydrothermal interconnection. Both holes have bottom-hole temperatures near or above 315°C (600°F). Subsequent to deep test drilling an expanded exploration and evaluation program was initiated. These efforts have included reprocessing existing data, executing multiple geological, geophysical, geochemical programs, deep exploration test well drilling and shallow well drilling. The efforts over the last three years have been made possible through a DOE Innovative Exploration Technology (IET) Grant 109, designed to facilitate innovative geothermal exploration techniques. The combined results of the last 8 years have led to a better understanding of the history and complexity of Newberry Volcano and improved the design and interpretation of geophysical exploration techniques with regard to blind geothermal resources in volcanic terrain.

Statistical interpretation of geochemical data

International Nuclear Information System (INIS)

Carambula, M.

1990-01-01

Statistical results have been obtained from a geochemical research from the following four aerial photographies Zapican, Carape, Las Canias, Alferez. They have been studied 3020 samples in total, to 22 chemical elements using plasma emission spectrometry methods.

Uranium geochemistry, mineralogy, geology, exploration and resources

International Nuclear Information System (INIS)

De Vivo, B.

1984-01-01

This book comprises papers on the following topics: history of radioactivity; uranium in mantle processes; transport and deposition of uranium in hydrothermal systems at temperatures up to 300 0 C: Geological implications; geochemical behaviour of uranium in the supergene environment; uranium exploration techniques; uranium mineralogy; time, crustal evolution and generation of uranium deposits; uranium exploration; geochemistry of uranium in the hydrographic network; uranium deposits of the world, excluding Europe; uranium deposits in Europe; uranium in the economics of energy; role of high heat production granites in uranium province formation; and uranium deposits

LAMOST Experiment for Galactic Understanding and Exploration (LEGUE) — The survey's science plan

International Nuclear Information System (INIS)

Deng Licai; Liu Chao; Chen Yuqin; Li Jing; Newberg Heidi Jo; Carlin, Jeffrey L.; Beers, Timothy C.; Chen Li; Hou Jinliang; Christlieb, Norbert; Grillmair, Carl J.; Guhathakurta, Puragra; Han Zhanwen; Wang Bo; Lee, Hsu-Tai; Lépine, Sébastien; Liu Xiaowei; Pan Kaike; Sellwood, J. A.; Wang Hongchi

2012-01-01

We describe the current plans for a spectroscopic survey of millions of stars in the Milky Way galaxy using the Guo Shou Jing Telescope (GSJT, formerly called the Large sky Area Multi-Object fiber Spectroscopic Telescope — LAMOST). The survey will obtain spectra for 2.5 million stars brighter than r < 19 during dark/grey time, and 5 million stars brighter than r < 17 or J < 16 on nights that are moonlit or have low transparency. The survey will begin in the fall of 2012, and will run for at least four years. The telescope's design constrains the optimal declination range for observations to 10° < δ < 50°, and site conditions lead to an emphasis on stars in the direction of the Galactic anticenter. The survey is divided into three parts with different target selection strategies: disk, anticenter, and spheroid. The resulting dataset will be used to study the merger history of the Milky Way, the substructure and evolution of the disks, the nature of the first generation of stars through identification of the lowest metallicity stars, and star formation through study of open clusters and OB associations. Detailed design of the LAMOST Experiment for Galactic Understanding and Exploration (LEGUE) survey will be completed in summer 2012, after a review of the results of the pilot survey.

Fiscal 1989 geothermal development promotion survey. Annex to on-the-ground survey report, geothermal development promotion survey (Geochemical survey report - No. 32: Hachijojima district); 1989 nendo chinetsu kaihatsu sokushin chosa chijo chosa hokokusho futai shiryo (Chikagaku chosa hokokusho - No.32 Hachijojima chiiki)

Energy Technology Data Exchange (ETDEWEB)

NONE

1989-11-01

A geochemical survey was conducted by examining soil gas and hot spa water temperature for contributing to the clarification of the subsurface geothermal structure in the Hachijojima district, Tokyo. Mercury concentration, carbon dioxide gas concentration, and 1 m-deep temperature were measured at 155 sites; and chemical and isotope analyses were conducted for 10 specimens of hot spa water and 6 specimens of surface water. After examination, 5 significant locations were isolated at the regions of Yaene-Ogago, Taredo, the northern foot of Mt. Nishi to Weather Station, the southern foot of Mt. Higashi, and the region to the south of Mt. Higashi with hot spa distributed therein. The significant locations are situated in the vicinity of a mar that produced deposit by magma-steam eruption, an alteration zone, and the parasitic volcano in Mt. Higashi, and in an area with hot spa distributed therein. It is therefore concluded that they are closely related with volcanic activities. It is inferred that geothermal signs in the Mt. Nishi area reflect a relatively deep-seated structure. As for the mercury and carbon dioxide gas concentration levels in the Mt. Higashi area, it is inferred that they again represent geothermal signs reflecting a relatively deep-seated structure. (NEDO)

Application of uranium exploration data and techniques in environmental studies. Proceedings of a technical committee meeting held in Vienna, 9-12 November 1993

Energy Technology Data Exchange (ETDEWEB)

NONE

1995-10-01

Exploration for mineral commodities, uranium included normally utilizes extensive, systematic geophysical and geochemical surveys covering very large areas, often entire countries. This information represents a great wealth of data that could be used to produce baseline information for environmental studies and monitoring. It is with this appreciation that IAEA convened a Technical Committee meeting with the purpose of bringing together experts in uranium exploration, geophysics and geochemistry to discuss and exchange information on the benefits of past exploration data and commonly applied techniques in environmental studies. The meeting on the Use of Uranium Exploration Data and Techniques in Environmental Studies was attended by 44 participants from 23 countries and one international organization. Thirty-two papers covering case histories on the use of old uranium exploration data to prepare exposure dose rate and radon potential maps, the use of airborne gamma ray spectrometric systems to monitor nuclear power plants and nuclear fuel cycle facilities, and the use of similar systems in response to emergency measures in the case of accidental releases were presented. Refs, figs and tabs.

Application of uranium exploration data and techniques in environmental studies. Proceedings of a technical committee meeting held in Vienna, 9-12 November 1993

International Nuclear Information System (INIS)

1995-10-01

Exploration for mineral commodities, uranium included normally utilizes extensive, systematic geophysical and geochemical surveys covering very large areas, often entire countries. This information represents a great wealth of data that could be used to produce baseline information for environmental studies and monitoring. It is with this appreciation that IAEA convened a Technical Committee meeting with the purpose of bringing together experts in uranium exploration, geophysics and geochemistry to discuss and exchange information on the benefits of past exploration data and commonly applied techniques in environmental studies. The meeting on the Use of Uranium Exploration Data and Techniques in Environmental Studies was attended by 44 participants from 23 countries and one international organization. Thirty-two papers covering case histories on the use of old uranium exploration data to prepare exposure dose rate and radon potential maps, the use of airborne gamma ray spectrometric systems to monitor nuclear power plants and nuclear fuel cycle facilities, and the use of similar systems in response to emergency measures in the case of accidental releases were presented. Refs, figs and tabs

Regional geochemical maps of uranium in Northern Scotland. Environmental and economic considerations

International Nuclear Information System (INIS)

Plant, J.

1978-01-01

The Institute of Geological Studies geochemical mapping programme is outlined. The natural levels of uranium in rocks, soils and waters are discussed. Some practical details of geochemical mapping are given. Applications of geochemical maps of uranium in Scotland are considered: economic applications and medical geography and agriculture. A list of 38 references is appended. (U.K.)

Radiochemical neutron activation analysis of gold in geochemical samples

International Nuclear Information System (INIS)

Zilliacus, R.

1983-01-01

A fast method for the radiochemical neutron activation analysis of gold in geochemical samples is described. The method is intended for samples having background concentrations of gold. The method is based on the dissolution of samples with hydrofluoric acid and aqua regia followed by the dissolution of the fluorides with boric acid and hydrochloric acid. Gold is then adsorbed on activated carbon by filtrating the solution through a thin carbon layer. The activity measurements are carried out using a Ge(Li)-detector and a multichannel analyzer. The chemical yields of the separation determined by reirradiation vary between 60 and 90%. The detection limit of the method is 0.2 ng/g gold in rock samples. USGS standard rocks and exploration reference materials are analyzed and the results are presented and compared with literature data. (author)

Report on the geothermal development promotion survey. No.B-6. Mt. Tsujinodake area; Chinetsu kaihatsu sokushin chosa hokokusho. No. B-6 Tsujinodake chiiki

Energy Technology Data Exchange (ETDEWEB)

NONE

2001-03-01

The paper summed up the results of the geothermal development promotion survey B 'Mt. Tsujinodake area' which was carried out at Yamagawa town, Ibusuki county, Kagoshima prefecture, from FY 1997 to FY 1999. In the survey, the following were conducted: surface survey such as geology/alteration zone survey, fluid geochemical survey, gravity exploration and electromagnetic exploration, and geothermal fluid survey by drilling 4 structural testing boreholes. In the Mt. Tsujinodake area, active fumarolic activities are still now continuing around the Unagi hot spring in the north, and the acidic alteration zone is distributed in the peripheral surface area. In Borehole N11-TD-2 in the north, it is assumed that there exists the hydrothermal bed of a temperature of approximately 230 degrees C in the depth of 400-800m, which is comparatively shallow, and that the stored geothermal water flows laterally. In the central area, a hydrothermal bed of a temperature of approximately 130 degrees C was confirmed in N11-TD-1, but it is judged that chances of the existence of high temperature hydrothermal bed are not very good. In N11-TD-3 in the south, the existence of promising heat sources is expected in the deeper part since the remarkable alteration was seen in the depth of 1,435m or deeper, and the sharp rise in temperature was recognized. (NEDO)

Surface geochemical data evaluation and integration with geophysical observations for hydrocarbon prospecting, Tapti graben, Deccan Syneclise, India

OpenAIRE

Satish Kumar, T.; Dayal, A.M.; Sudarshan, V.

2014-01-01

The Deccan Syneclise is considered to have significant hydrocarbon potential. However, significant hydrocarbon discoveries, particularly for Mesozoic sequences, have not been established through conventional exploration due to the thick basalt cover over Mesozoic sedimentary rocks. In this study, near-surface geochemical data are used to understand the petroleum system and also investigate type of source for hydrocarbons generation of the study area. Soil samples were collected from favorable...

Uranium exploration and evaluation techniques

International Nuclear Information System (INIS)

Bowie, S.H.U.

1977-01-01

Ground, carborne and airborne surveys for uranium commenced with GM-counters and developed to total-count scintillation counters which have subsequently been replaced to some extent by gamma spectrometers. Stabilisation of the last mentioned is important and has only been achieved recently. Hydrogeochemistry has been revitalised by the introduction of neutron activation analysis and has considerable promise of success in the discovery of surface and near-surface uranium deposits. Soil, stream sediment and lake sediment analyses also have potential particularly in follow-up surveys. One of the most encouraging methods of detecting relatively deeply buried uranium ore bodies is by measuring the radon content of air retained in soil or sub-soil; also that dissolved in stream or lake water. Helium, particularly 4 He, which is also a decay product of uranium but which has an infinite half-life could be measured along with radon. Theoretically this could not only give additional information on buried ore bodies, but on the depth of burial. Another possible technique for use in the detection of buried ore bodies is that of measuring the increased heat flow at surface which, in favourable circumstatnces, should be associated with significant uranium occurrences. Measurement of heat flow could either be by surface thermal sensors or by thermal infra-red scanning techniques from aircraft. For the purposes of preliminary surveys of large areas, airborne geochemical techniques offer considerable scope. Possibilities include the measurement of 222 Rn in the atmosphere. Alternatively, one or more of the decay products of radon could be measured. These are 210 Pb, 210 Bi and 210 Po. It is concluded that there is ample evidence to suggest that the more widespread application of known exploration methods, together with new techniques that can already be envisaged, will result in important new discoveries of uranium reserves

FY 1998 report on the verification survey of geothermal exploration technology, etc. 1/2. Survey of deep geothermal resource; 1998 nendo chinetsu tansa gijutsu nado kensho chosa hokokusho. 1/2. Shinbu chinetsu shigen chosa

Energy Technology Data Exchange (ETDEWEB)

NONE

1999-12-01

For the purpose of commercializing deep geothermal resource, a deep exploration well of 4000m class was drilled in the existing geothermal development area to survey the situation of deep geothermal resource existence and the availability. Concretely, the deep geothermal exploration well was drilled for study in the Kakkonda area, Shizukuishi town, Iwate prefecture, to clarify the situation of deep geothermal resource existence and the whole image of geothermal system. Consideration was made of the deep geothermal exploration method, systematization of deep high temperature drilling technology, and availability of deep geothermal resource. The results of the survey were summed up as follows: 1) general remarks; 2) deep exploration well drilling work; 3) details of the study. 1) and 2) were included in this report, and 3) in the next report. In 1), the items were as follows: the study plan/gist of study execution, the details and results of the deep geothermal resource survey, the outline of the deep exploration well drilling work, and the outline of the results of the FY 1998 study. In 2), the drilling work plan/the actual results of the drilling work were summed up. As to the results of the study, summarized were the acquisition of survey data on deep exploration well, heightening of accuracy of the deep geothermal resource exploration method, etc. (NEDO)

Some simple guides to finding useful information in exploration geochemical data

Science.gov (United States)

Singer, D.A.; Kouda, R.

2001-01-01

Most regional geochemistry data reflect processes that can produce superfluous bits of noise and, perhaps, information about the mineralization process of interest. There are two end-member approaches to finding patterns in geochemical data-unsupervised learning and supervised learning. In unsupervised learning, data are processed and the geochemist is given the task of interpreting and identifying possible sources of any patterns. In supervised learning, data from known subgroups such as rock type, mineralized and nonmineralized, and types of mineralization are used to train the system which then is given unknown samples to classify into these subgroups. To locate patterns of interest, it is helpful to transform the data and to remove unwanted masking patterns. With trace elements use of a logarithmic transformation is recommended. In many situations, missing censored data can be estimated using multiple regression of other uncensored variables on the variable with censored values. In unsupervised learning, transformed values can be standardized, or normalized, to a Z-score by subtracting the subset's mean and dividing by its standard deviation. Subsets include any source of differences that might be related to processes unrelated to the target sought such as different laboratories, regional alteration, analytical procedures, or rock types. Normalization removes effects of different means and measurement scales as well as facilitates comparison of spatial patterns of elements. These adjustments remove effects of different subgroups and hopefully leave on the map the simple and uncluttered pattern(s) related to the mineralization only. Supervised learning methods, such as discriminant analysis and neural networks, offer the promise of consistent and, in certain situations, unbiased estimates of where mineralization might exist. These methods critically rely on being trained with data that encompasses all populations fairly and that can possibly fall into only the

Geochemical site-selection criteria for HLW repositories in Europe and North America

International Nuclear Information System (INIS)

Savage, David; Arthur, Randolph C.; Sasamoto, Hiroshi; Shibata, Masahiro; Yui, Mikazu

2000-01-01

Geochemical as well as socio-economic issues associated with the selection of potential sites to host a high-level nuclear waste repository have received considerable attention in repository programs in Europe (Belgium, Finland, France, Germany, Spain, Sweden, Switzerland and the U.K.) and North America (Canada and the United States). The objective of the present study is to summarize this international experience with particular emphasis on geochemical properties that factor into the adopted site-selection strategies. Results indicate that the geochemical properties of a site play a subordinate role, at best, to other geotechnical properties in the international site-selection approaches. In countries where geochemical properties are acknowledged in the site-selection approach, requirements are stated qualitatively and tend to focus on associated impacts on the stability of the engineered barrier system and on radionuclide transport. Site geochemical properties that are likely to control the long-term stability of geochemical conditions and radionuclide migration behavior are unspecified, however. This non-prescriptive approach may be reasonable for purposes of screening among potential sites, but a better understanding of site properties that are most important in controlling the long-term geochemical evolution of the site over a range of possible scenarios would enable the potential sites to be ranked in terms of their suitability to host a repository. (author)

Granite-repository - geochemical environment

International Nuclear Information System (INIS)

1979-04-01

Some geochemical data of importance for a radioactive waste repository in hard rock are reviewed. The ground water composition at depth is assessed. The ground water chemistry in the vicinity of uranium ores is discussed. The redox system in Swedish bedrock is described. Influences of extreme climatic changes and of repository mining and construction are also evaluated

Geochemical modelling of bentonite porewater in high-level waste repositories

Science.gov (United States)

Wersin, Paul

2003-03-01

The description of the geochemical properties of the bentonite backfill that serves as engineered barrier for nuclear repositories is a central issue for perfomance assessment since these play a large role in determining the fate of contaminants released from the waste. In this study the porewater chemistry of bentonite was assessed with a thermodynamic modelling approach that includes ion exchange, surface complexation and mineral equilibrium reactions. The focus was to identify the geochemical reactions controlling the major ion chemistry and acid-base properties and to explore parameter uncertainties specifically at high compaction degrees. First, the adequacy of the approach was tested with two distinct surface complexation models by describing recent experimental data performed at highly varying solid/liquid ratios and ionic strengths. The results indicate adequate prediction of the entire experimental data set. Second, the modelling was extended to repository conditions, taking as an example the current Swiss concept for high-level waste where the compacted bentonite backfill is surrounded by argillaceous rock. The main reactions controlling major ion chemistry were found to be calcite equilibrium and concurrent Na-Ca exchange reactions and de-protonation of functional surface groups. Third, a sensitivity analysis of the main model parameters was performed. The results thereof indicate a remarkable robustness of the model with regard to parameter uncertainties. The bentonite system is characterised by a large acid-base buffering capacity which leads to stable pH-conditions. The uncertainty in pH was found to be mainly induced by the pCO 2 of the surrounding host rock. The results of a simple diffusion-reaction model indicate only minor changes of porewater composition with time, which is primarily due to the geochemical similarities of the bentonite and the argillaceous host rock. Overall, the results show the usefulness of simple thermodynamic models to

Fiscal 2000 basic survey for coal resource exploration. Survey for development of new exploration technology (Exploration of shallow layers on the land - Collection of data and materials); 2000 nendo sekitan shigen kaihatsu kiso chosa shiryoshu. Shintansa gijutsu chosa kaihatsu (rikuiki senso tansa)

Energy Technology Data Exchange (ETDEWEB)

NONE

2001-09-01

As agreed upon between NEDO (New Energy and Industrial Technology Development Organization), Japan, and Queensland, Australia, joint research was conducted on new technology for coal exploration within Queensland, and data collected during the research and related materials are compiled into this book. The book contains the Agreement for the Joint Research of New Technology in the Geophysical Exploration of Coal Resources (Japanese and English), GPS (global positioning system) survey results along 2-dimensional seismic reflection method traverse lines, GPS survey results along 3-dimensional seismic reflection method traverse lines, seismic generator vehicle inspection and repair report, geophysical logging observer's logs and test bore dip measurement data sheets, examples of outputted shot records (2-dimensional seismic reflection method), examples of outputted shot records (3-dimensional seismic reflection method), analysis and testing report on Girrah layer samples, reference literature on PRBS (pseudorandom binary sequence), collections of photographs of cores sampled by test boring (BG001, BG002, BG003, BG004), collections of other photographs, and so forth. (NEDO)

Stream sediment geochemical surveys for uranium

International Nuclear Information System (INIS)

Price, V.; Ferguson, R.B.

1979-01-01

Stream sediment is more universally available than ground and surface waters and comprises the bulk of NURE samples. Orientation studies conducted by the Savannah River Laboratory indicate that several mesh sizes can offer nearly equivalent information. Sediment is normally sieved in the field to pass a 420-micrometer screen (US Std. 40 mesh) and that portion of the dried sediment passing a 149-micrometer screen (US Std. 100 mesh) is recovered for analysis. Sampling densities usually vary with survey objectives and types of deposits anticipated. Principal geologic features that can be portrayed at a scale of 1:250,000, such as major tectonic units, plutons, and pegmatite districts, are readily defined using a sampling density of 1 site per 5 square miles (13 km 2 ). More detailed studies designed to define individual deposits require greater sampling density. Analyses for elements known to be associated with uranium in a particular mineral host may be used to estimate the relative proportion of uranium in several forms. For example, uranium may be associated with thorium and cerium in monazite, and with zirconium and hafnium in zircon. Readily leachable uranium may be adsorbed to trapped in oxide coatings on mineral particles. Soluble or mobile uranium may indicate an ore source, whereas uranium in monazite or zircon is not likely to be economically attractive. Various schemes may be used to estimate for form of uranium in a sample. Simple elemental ratios are a useful first approach. Multiple ratios and subtractive formulas empirically designed to account for the presence of particular minerals are more useful. Residuals calculated from computer-derived regression equations or factor scores appear to have the greatest potential for locating uranium anomalies

Geochemical Distribution of Lead and Chromium in River Getsi-Kano

African Journals Online (AJOL)

Geochemical forms of lead (Pb) and Chromium (Cr) from the sediment of River Getsi Kano-Nigeria were determined using Atomic Absorption spectrometer for eighteen months. Apart from determination of the metals in water, geochemical forms of the metals were also evaluated into five fractions. Exchangeable, bound to ...

Induced Polarization Surveying for Acid Rock Screening in Highway Design

Science.gov (United States)

Butler, K. E.; Al, T.; Bishop, T.

2004-05-01

Highway and pipeline construction agencies have become increasingly vigilant in their efforts to avoid cutting through sulphide-bearing bedrock that has potential to produce acid rock drainage. Blasting and fragmentation of such rock increases the surface area available for sulphide oxidation and hence increases the risk of acid rock drainage unless the rock contains enough natural buffering capacity to neutralize the pH. In December, 2001, the New Brunswick Department of Transportation (NBOT) sponsored a field trial of geophysical surveying in order to assess its suitability as a screening tool for locating near-surface sulphides along proposed highway alignments. The goal was to develop a protocol that would allow existing programs of drilling and geochemical testing to be targeted more effectively, and provide design engineers with the information needed to reduce rock cuts where necessary and dispose of blasted material in a responsible fashion. Induced polarization (IP) was chosen as the primary geophysical method given its ability to detect low-grade disseminated mineralization. The survey was conducted in dipole-dipole mode using an exploration-style time domain IP system, dipoles 8 to 25 m in length, and six potential dipoles for each current dipole location (i.e. n = 1 - 6). Supplementary information was provided by resistivity and VLF-EM surveys sensitive to lateral changes in electrical conductivity, and by magnetic field surveying chosen for its sensitivity to the magnetic susceptibility of pyrrhotite. Geological and geochemical analyses of samples taken from several IP anomalies located along 4.3 line-km of proposed highway confirmed the effectiveness of the screening technique. IP pseudosections from a region of metamorphosed shales and volcaniclastic rocks identified discrete, well-defined mineralized zones. Stronger, overlapping, and more laterally extensive IP anomalies were observed over a section of graphitic and sulphide-bearing metasedimentary

Heavy mineral survey for uranium in the Philippines

International Nuclear Information System (INIS)

Tauchid, M.; Santos, G. Jr.; Hernandez, E.; Bernido, C.

1983-01-01

A reconnaissance geochemical survey for uranium was carried out in the island of Samar in the Philippines covering an area of about 13,000 km 2 . The survey represents the first practical demonstration in the country of the use of geochemical techniques to outline large possibly interesting areas within a short period and with modest monetary expenditure. The survey entailed the systematic collection of 1530 heavy mineral concentrates, stream sediments and water samples, and the measurement of radioactivity at 510 stations along the major drainage system of Samar. The average sampling density was 1/20-25 km 2 . All solid samples were analysed for U, Cu, Pb, Zn, Mn, Ag, Co and Ni. Uranium, radon, conductivity and pH were measured in most of the water samples collected. More than 9000 chemical determinations were made. Results of the survey clearly point to the usefulness of heavy mineral sampling at the low density level of observation. The non-magnetic fraction of the heavy mineral concentrates outlined strong and well defined areas of interest for most of the elements analysed. Stream sediment sampling at this sampling density indicated weaker, less clearly defined anomalies. Uranium and radon analyses performed on stream water samples and ground scintillometer readings provided invaluable complementary information relevant to the evaluation of the island's uranium potential. (author)

Geochemical prospecting in Guiana

International Nuclear Information System (INIS)

Coulomb, R.

1957-01-01

During the last few years geochemical prospecting techniques have become common usage in the field of mineral deposit prospecting. The real scope of these methods lies in their use in the prospecting of large areas. The most promising use of the geochemistry and hydro-geochemistry of uranium is in heavily forested tropical territories, with few outcrops, where radiometry is strongly handicapped. (author) [fr

Baseline geochemical data for stream sediment and surface water samples from Panther Creek, the Middle Fork of the Salmon River, and the Main Salmon River from North Fork to Corn Creek, collected prior to the severe wildfires of 2000 in central Idaho

Science.gov (United States)

Eppinger, Robert G.; Briggs, Paul H.; Brown, Zoe Ann; Crock, James G.; Meier, Allen; Theodorakos, Peter M.; Wilson, Stephen A.

2001-01-01

In 1996, the U.S. Geological Survey conducted a reconnaissance baseline geochemical study in central Idaho. The purpose of the baseline study was to establish a 'geochemical snapshot' of the area, as a datum for monitoring future change in the geochemical landscape, whether natural or human-induced. This report presents the methology, analytical results, and sample descriptions for water, sediment, and heavy-mineral concentrate samples collected during this geochemical investigation. In the summer of 2000, the Clear Creek, Little Pistol, and Shellrock wildfires swept across much of the area that was sampled. Thus, these data represent a pre-fire baseline geochemical dataset. A 2001 post- fire study is planned and will involve re-sampling of the pre-fire baseline sites, to allow for pre- and post-fire comparison.

Geology of pre-Dakota uranium geochemical cell, sec. 13, T. 16 N., R. 17 W., Church Rock area, McKinley County

International Nuclear Information System (INIS)

Peterson, R.J.

1980-01-01

Exploration drilling on sec. 13, T. 16 N., R. 17 W., McKinley County, New Mexico, has defined uranium deposits within the Westwater Canyon Member of the Morrison Formation (Jurassic). Elongate, tabular, redistributed deposits were formed peripherally along the zones of highest transmissivity of the northeast-trending Westwater Canyon fluvial system by a Jurassic-Cretaceous geochemical cell. Strongly reducing conditions, which existed locally in the channel-margin areas owing to the presence of organic materials, were the primary ore control. Evidence that this major redistribution process took place in pre-Dakota time is the bleaching of the Westwater Canyon Sandstone by Dakota swamps is superimposed on older oxidation, and the primary mineralization above the Jurassic-Cretaceous water table was not affected by the geochemical-cell redistribution process

Summary report on geochemical barrier special study

International Nuclear Information System (INIS)

1988-12-01

Long-term management of uranium mill tailings must provide assurance that soluble contaminants will not migrate beyond the Point of Compliance. Conventional management alternatives provide containment through the use of physical barriers which are designed to prevent migration of water through the tailings pile. An alternative is to geochemically modify the tailings to immobilize the contaminants. This investigation examined three potential geochemical modifiers to determine their ability to immobilize inorganic groundwater contaminants found in uranium mill tailings. These modifiers were hydrated lime (Ca(OH) 2 ), limestone (CaCO 3 ), and a sphaegnum peat moss. This investigation focused on both the geochemical interactions between the tailings and the modifiers, and the effects the modifiers had on the physical strength of the tailings. The geochemical investigations began with characterization of the tailings by X-ray diffraction and scanning electron microscopy. This was followed by batch leaching experiments in which various concentrations of each modifier were added to tailings in shaker flasks and allowed to come to equilibrium. Finally, column experiments were conducted to simulate flow through a tailings pile. The results show that all of the modifiers were at least moderately effective at immobilizing most of the groundwater contaminants of concern at uranium mill tailings sites. Hydrated lime was able to achieve 90 percent concentration reduction of arsenic, cadmium, selenium, uranium, and sulfate when added at a two percent concentration. Limestone was somewhat less effective and peat removed greater than 90 percent of arsenic, lead, uranium, and sulfate at a one percent concentration. The column tests showed that kinetic and/or mass transfer limitations are important and that sufficient time must be allowed for the immobilization reactions to occur

Geochemical modelling. Pt.1, Pt.2

International Nuclear Information System (INIS)

Skytte Jensen, B.; Jensen, H.; Pearson, F.J.

1992-01-01

This work is carried out under cost-sharing contract with the European Atomic Energy Community in the framework of its fourth research programme on radioactive waste management and radioactive waste storage. This final report is subdivided into two parts. In the first part, JENSEN, a computer code for the computation of chemical equilibria in aqueous systems, describes the structure, function and use of a new geochemical computer program intended for PC's. The program, which is written in Turbo Pascal, version 4, is fundamentally similar to most other geochemical programs, but combines in one program several of the merits these programs have. The intention has been to make an advanced program, which also should be user friendly and fast, and to attain this several new algorithms have been developed and implemented. The program has a built-in database mainly based on the CHEMVAL compilation containing data for 395 soluble species and 149 minerals. The program can find equilibria in the presence of all or some of these soluble species, under conditions or fixed or floating pH and / or Redox potential. The program by itself eliminates a bad guess of a candidate for precipitation. In the present version, the program can identify which minerals and how much of them there will be formed when equilibrium is established. In the second part, LITTLE JOE, an expert system to support geochemical modelling, describes the construction of a minor expert system for use in the evaluation of analytical data for the composition of ground waters from limestone formation. Although the example given is rather limited in scope, the application of the expert system for the evaluation of the analytical data clearly demonstrates the mature expert knowledge imbedded in the system which is contrasted with the uncritical acceptance of analytical or theoretical data. With the overall neglect of ion-exchange and the formation of solid solutions in geochemical calculations, geochemistry is

Geochemical modelling of groundwater evolution using chemical equilibrium codes

International Nuclear Information System (INIS)

Pitkaenen, P.; Pirhonen, V.

1991-01-01

Geochemical equilibrium codes are a modern tool in studying interaction between groundwater and solid phases. The most common used programs and application subjects are shortly presented in this article. The main emphasis is laid on the approach method of using calculated results in evaluating groundwater evolution in hydrogeological system. At present in geochemical equilibrium modelling also kinetic as well as hydrologic constrains along a flow path are taken into consideration

Brazil Geologic Basic Survey Program - Barbacena - Sheet SF.23-X-C-III -Minas Gerais State

International Nuclear Information System (INIS)

Brandalise, L.A.

1991-01-01

The present report refers to the Barbacena sheet (SF.23-X-C-III) systematic geological mapping, on the 1:10,000 scale, related to the Levantamentos Geologicos Basicos do Brasil Program - PLGB, carried out by CPRM for the DNPM. Integrated to geochemical and geophysical surveys, the geological mapping not only yielded geophysical and geochemical maps but a consistent to the 1:100.000 scale Metallogenetic/Provisional one as well. The geological mapping carried out during the Project has really evidenced that samples of distinct stratigraphic units had been employed to define the one and only isochrone. However geochronologic Rb/Sr dating performed during the geological mapping phase evidenced Archean ages for rocks of the Sao Bento dos Torres Metamorphic Suite (2684 ± 110 m.y.) and ages of about 2000 m.y. for the Ressaquinha Complex rocks. An analysis of crustal evolution patterns based on geological mapping, gravimetric survey data, aeromagnetometry and available geochronologic data is given in the Chapter 6, Part II, in the test. Major element oxides, trace-elements and rare-earths elements were analysed to establish parameters for the rocks environment elucidation. Geochemical survey was carried out with base on pan concentrated and stream sediments distributed throughout the sheet. (author)

Review of geochemical measurement techniques for a nuclear waste repository in bedded salt

International Nuclear Information System (INIS)

Knauss, K.G.; Steinborn, T.L.

1980-01-01

A broad, general review is presented of geochemical measurement techniques that can provide data necessary for site selection and repository effectiveness assessment for a radioactive waste repository in bedded salt. The available measurement techniques are organized according to the parameter measured. The list of geochemical parameters include all those measurable geochemical properties of a sample whole values determine the geochemical characteristics or behavior of the system. For each technique, remarks are made pertaining to the operating principles of the measurement instrument and the purpose for which the technique is used. Attention is drawn to areas where further research and development are needed

Behaviour of nature and technogenic radioisotopes in buried geochemical barriers

International Nuclear Information System (INIS)

Kuznetsov, V.A.; Onoshko, M.P.; Generalova, V.A.

1998-01-01

Behaviour of potassium 40, radium 226, thorium 232, strontium 90 and cesium 137 on geochemical barriers connected with buried soils and cut-off meander sediments of the Holocene age of the Sozh river valley are examined. Some sides of the barrier geochemical structure caused by syngeneic and epigenetic processes have been taken into consideration

Management of Reclaimed Produced Water in the Rocky Mountain States Enhanced with the Expanded U.S. Geological Survey Produced Waters Geochemical Database

Science.gov (United States)

Gans, K. D.; Blondes, M. S.; Reidy, M. E.; Conaway, C. H.; Thordsen, J. J.; Rowan, E. L.; Kharaka, Y. K.; Engle, M.

2016-12-01

The Rocky Mountain states; Wyoming, Colorado, Montana, New Mexico and Utah produce annually approximately 470,000 acre-feet (3.66 billion barrels) of produced water - water that coexists with oil and gas and is brought to the surface with the pumping of oil and gas wells. Concerns about severe drought, groundwater depletion, and contamination have prompted petroleum operators and water districts to examine the recycling of produced water. Knowledge of the geochemistry of produced waters is valuable in determining the feasibility of produced water reuse. Water with low salinity can be reclaimed for use inside and outside of the petroleum industry. Since a great proportion of petroleum wells in the Rocky Mountain states, especially coal-bed methane wells, have produced water with relatively low salinity (generally oil recovery, and even for municipal uses, such as drinking water. The USGS Produced Waters Geochemical Database, available at http://eerscmap.usgs.gov/pwapp, has 60,000 data points in this region (this includes 35,000 new data points added to the 2002 database) and will facilitate studies on the management of produced water for reclamation in the Rocky Mountain region. Expanding on the USGS 2002 database, which contains geochemical analyses of major ions and total dissolved solids, the new data also include geochemical analyses of minor ions and stable isotopes. We have added an interactive web map application which allows the user to filter data on chosen fields (e.g. TDS data set can provide critical insight for better management of produced waters in water-constrained regions of the Rocky Mountains.

Constraints and prospects of uranium exploration in Himalaya

International Nuclear Information System (INIS)

Singh, Rajendra

1994-01-01

Exploration for uranium in the Himalaya over the last thirty years has brought to light five distinct types of mineralisation, namely, vein-type, hydrothermal shear controlled-type, disseminated-type, syngenetic-type, and sandstone-type. The first three are associated with lower to middle proterozoic metasedimentary rocks, metabasic rocks, and granitoids of the lesser Himalaya in close proximity to the main central thrust (MCT). The carbonaceous slates of Haimanta group (late proterozoic to eocambrian) and the Mussoorie phosphorites (eocambrian) represent the syngenetic types. The sandstone-type is associated with the late tertiary Siwaliks of the northwestern Himalaya. The constraints in geology and uranium exploration in the Himalaya have been briefly discussed and principal uranium occurrences in relation to their tectonic environment and genesis listed. The need for geochemical characterization of the Himalayan granitoids and the metabasics related to known uranium mineralisation and new areas have been suggested. Integrated application of radiometric, geochemical and geophysical methods of prospecting and remote sensing techniques in regional geological correlation, identification of subtle rock alterations associated with mineralized zones, geologic structures, and deep crustal lineaments have been advocated. A case for the exploration of the areas of lesser Himalaya outside the MCT has been made out so as to locate hitherto unknown types of uranium deposits including, strata bound, metamorphic, and intra granitic types, possibly with better depth persistence. (author). 57 refs., 1 fig., 2 tabs

An integrated geological, geochemical, and geophysical investigation of uranium metallogenesis in selected granitic plutons of the Miramichi Anticlinorium, New Brunswick

International Nuclear Information System (INIS)

Hassan, H.H.; McAllister, A.L.

1992-01-01

Integrated geological, geochemical, and geophysical data for the post-tectonic granitic rocks of the North Pole, Burnthill, Dungarvon, Trout Brook, and Rocky Brook plutons and surrounding areas were examined to assess their potential for uranium mineralization. Geological, geochemical, and geophysical criteria that are thought to be useful guides for uranium exploration were also established for the host granites. The granitic plutons were emplaced discordantly, late in the tectonomagmatic sequence and at shallow depths within the metasedimentary rocks of the Miramichi Anticlinorium. Geochemically, the host granites are highly evolved (Si0 2 > 75 wt. %), peraluminous and have strong similarities with ilmenite-series 'S-type' and 'A-type' granitoids. Uranium occurrences are spatially and perhaps temporally associated with late-phase differentiates of the plutons where elevated levels of other lithophile elements such as Sn, W, Mo, and F were also detected. Geophysically, the granitic plutons are associated with distinctively high aeroradiometric eU, eTh, and K anomalies that coincide with strong negative Bouguer anomalies and low magnetic values. Conceptual models involving magmatic and hydrothermal processes have been adopted to explain the concentration of uranium and associated metals in the granitic plutons

Airborne gamma ray spectrometer surveying

International Nuclear Information System (INIS)

1991-01-01

The International Atomic Energy Agency (IAEA) in its role as collector and disseminator of information on nuclear techniques has long had an interest in gamma ray spectrometer methods and has published a number of Technical Reports on various aspects of the subject. At an Advisory Group Meeting held in Vienna in November 1986 to review appropriate activities the IAEA could take following the Chernobyl accident, it was recommended that preparation begin on a new Technical Report on airborne gamma ray spectrometer surveying, taking into account the use of the technique for environmental monitoring as well as for nuclear emergency response requirements. Shortly thereafter the IAEA became the lead organization in the Radioelement Geochemical Mapping section of the International Geological Correlation Programme/United Nations Educational, Scientific and Cultural Organization (UNESCO) Project on International Geochemical Mapping. These two factors led to the preparation of the present Technical Report. 18 figs, 4 tabs

Geological, geochemical, and geophysical studies by the U.S. Geological Survey in Big Bend National Park, Texas

Science.gov (United States)

Page, W.R.; Turner, K.J.; Bohannon, R.G.; Berry, M.E.; Williams, V.S.; Miggins, D.P.; Ren, M.; Anthony, E.Y.; Morgan, L.A.; Shanks, P.W.C.; Gray, J. E.; Theodorakos, P.M.; Krabbenhoft, D. P.; Manning, A.H.; Gemery-Hill, P. A.; Hellgren, E.C.; Stricker, C.A.; Onorato, D.P.; Finn, C.A.; Anderson, E.; Gray, J. E.; Page, W.R.

2008-01-01

Big Bend National Park (BBNP), Tex., covers 801,163 acres (3,242 km2) and was established in 1944 through a transfer of land from the State of Texas to the United States. The park is located along a 118-mile (190-km) stretch of the Rio Grande at the United States-Mexico border. The park is in the Chihuahuan Desert, an ecosystem with high mountain ranges and basin environments containing a wide variety of native plants and animals, including more than 1,200 species of plants, more than 450 species of birds, 56 species of reptiles, and 75 species of mammals. In addition, the geology of BBNP, which varies widely from high mountains to broad open lowland basins, also enhances the beauty of the park. For example, the park contains the Chisos Mountains, which are dominantly composed of thick outcrops of Tertiary extrusive and intrusive igneous rocks that reach an altitude of 7,832 ft (2,387 m) and are considered the southernmost mountain range in the United States. Geologic features in BBNP provide opportunities to study the formation of mineral deposits and their environmental effects; the origin and formation of sedimentary and igneous rocks; Paleozoic, Mesozoic, and Cenozoic fossils; and surface and ground water resources. Mineral deposits in and around BBNP contain commodities such as mercury (Hg), uranium (U), and fluorine (F), but of these, the only significant mining has been for Hg. Because of the biological and geological diversity of BBNP, more than 350,000 tourists visit the park each year. The U.S. Geological Survey (USGS) has been investigating a number of broad and diverse geologic, geochemical, and geophysical topics in BBNP to provide fundamental information needed by the National Park Service (NPS) to address resource management goals in this park. Scientists from the USGS Mineral Resources and National Cooperative Geologic Mapping Programs have been working cooperatively with the NPS and several universities on several research studies within BBNP

GEOBASI: The geochemical Database of Tuscany Region (Italy

Directory of Open Access Journals (Sweden)

Brunella Raco

2015-03-01

Full Text Available In this study the new Regional Geochemical Database (RGDB, called GEOBASI, is presented and illustrated in the framework of a joint collaboration among the three Tuscan universities (Florence, Pisa and Siena, CNR-IGG (Institute of Geosciences and Earth Resources of Pisa, ARPAT (Regional Agency for the Environmental Protection, LAMMA (Environmental Modelling and Monitoring Laboratory for Sustainable Development Consortium and S.I.R.A. (Territorial and Environmental Informative System of Tuscany. The database has permitted the construction of a repository where the geochemical information (compositional and isotopic has been stored in a structured way so that it can be available for different groups of users (e.g. institutional, public and private companies. The information contained in the database can in fact be downloaded freely and queried to correlate geochemistry to other non compositional variables. The first phase of the project was aimed at promoting the use of the geochemical data already available from previous investigations through a powerful Web-GIS interface to implement the exploratory statistics graphical-numerical tools used to: 1 analyse the spatial variability of the investigated context, 2 highlight the geographic location of data pertaining to classes of values or single cases, 3 compare the results of different analytical methodologies applied to the determination of the same element and/or chemical species, 4 extract the geochemical data related to specific monitoring plans and/or geographical areas, and finally 5 recover information about data below the detection limit to understand their impact on the behaviour of the investigated variable. Developments of this project will be focused on the definition of rules and standardized methods in a way that external users could also interactively pursue the RGDB. Furthermore, a detailed investigation of the Scarlino-Follonica plain will permit the improvement and test of

Geochemical Anomalies in the Sediments of Lake Druksiai

International Nuclear Information System (INIS)

Kleinas, A.

1999-01-01

In order to evaluate the impact of Ignalina Nuclear Power Plant (NPP) on natural processes in Lake Druksiai and accumulation of pollutants, in 19931997, carrying on the state scientific program, the Marine Geochemistry Division of the Institute of Geography performed lithological geochemical mapping of lake bottom sediments on a scale of 1 .50 000. The results obtained enabled to distinguish zones of higher anthropogenous geochemical load, where geochemical anomalies of pollutants, including oil hydrocarbons and heavy metals, had been taken into account. Applying concentration coefficients for oil hydrocarbons and heavy metals (Cr, Cu, Ni, Pb, and Zn) and their natural background, the attempt was made to differentiate natural and technogenous components in the geochemical anomalies As expected, the finer sediments -aleurite-pelite mud - showed amounts of oil hydrocarbons and heavy metals being 12.1 times higher than in fine sand - the most coarse of the sediments studied Sediments with organic mater exceeding 20% contained 11.7 times more pollutants than those with organic matter below 1 .5%. Calculations of concentration coefficients (CC) showed no elements in no stations exceeded 10 - the sediments did not reach the category of high pollution However, in many sites, the coefficients exceeded values of 1-2, thus, showing sediments attributable to the categories of weakly polluted or just polluted. Mapping model done by GIS methods (by superimposing schemes of pollutant CCs distribution in the lake and summing them) for geochemical anomalies two derivative map-schemes were obtained for oil hydrocarbons and heavy metals. They showed that clean sediments cover just 24.75% (according to the pollutant background for soil types) and 12.35% (according to the organic matter background for its amount intervals) lake bottom area. Zones slightly polluted by an element at least cover 69.7 and 80.29% of lake area, correspondingly; whereas zones slightly polluted by all

FY 1997 report on the data processing of the geothermal development promotion survey. Primary. No.B-5 Mt. Musadake area; 1997 nendo chinetsu kaihatsu sokushin chosa data shori hokokusho. No. B-5 Musadake chiiki (Dai 1 ji)

Energy Technology Data Exchange (ETDEWEB)

NONE

1998-06-01

As part of the geothermal development promotion survey, the comprehensive analysis was made on the survey of the existence amount of geothermal resource in the Mt. Musadake area, Shibetsu county, Hokkaido, which was conducted in FY 1997. In the surface survey, the following were carried out: survey of geology/alteration zone, age determination of rocks, alteration age determination by thermoluminescence method, geochemical survey (hot spring gas, hot spring water), gravity exploration and electromagnetic exploration. In the survey of environmental effects, survey of flora/fauna and survey of hot spring variations were made. The results of the analysis were outlined as follows. The geothermal system in this area seems to be controlled by the Mt. Musadake - Mt. Shitabanupuri fault, folding zone along the fault and Graben-state structure extending southeast of the zone. At deep underground, the existence of the deep geothermal water forming geothermal reservoirs is presumed, and the deep geothermal water seems to be helped by the thermal conduction and volcanic effluences from the magma reservoir related to a series of volcanoes, centered on Mt. Musadake that is regarded as heat source. The geothermal water has a temperature of over 250 degrees C and a high Cl concentration. (NEDO)

Advances in the exploration model for Athabasca unconformity uranium deposits

International Nuclear Information System (INIS)

Wheatley, K.; Murphy, J.; Leppin, M.; Cutts, C.; Climie, J.A.

1997-01-01

This paper covers the genetic model of ore formation and exploration techniques Uranerz Exploration and Mining is presently using to explore for unconformity uranium deposits in the deeper parts of the Athabasca Basin. The main objectives of this paper are: 1) to present a genetic model for unconformity uranium deposits which is being used in our current exploration strategy, and 2) to present the sequence of exploration techniques used by Uranerz to explore for uranium in areas of the Athabasca Basin with up to 1000 m of sandstone cover. The Athabasca unconformity deposits are located in northern Saskatchewan, Canada. Within the Precambrian Athabasca Basin, exploration companies have discovered 18 uranium deposits. These contain more than 500 million kilograms of uranium, with average grades ranging from 0.3 to 12%. Uranerz discovered the Key Lake deposits in 1975, currently the largest and richest open pit uranium mine in the world. Uranerz also holds interests in the Rabbit Lake, Midwest Lake and McArthur River deposits, all in Saskatchewan, and is also actively exploring for uranium worldwide. The first discovery in the eastern Athabasca Basin was in 1968 at Rabbit Lake, followed by Key Lake in 1975. Both deposits had surficial indicators, such as radioactive boulders, strong geochemical anomalies in the surrounding lakes and swamps, and well-defined geophysical signatures. After the Key Lake discovery, an exploration model was devised which incorporated the underlying graphitic horizon and its strong electro-magnetic signature. Since then, there have been numerous new discoveries made by systematically drilling along these electro-magnetic conductors. The advancements in geophysical and geochemical techniques have led to discoveries at increasing depths. In 1988, the McArthur River deposit was discovered at a depth of 500 m. (author). 6 refs

Effect of source integration on the geochemical fluxes from springs

International Nuclear Information System (INIS)

Frisbee, Marty D.; Phillips, Fred M.; White, Art F.; Campbell, Andrew R.; Liu, Fengjing

2013-01-01

Geochemical fluxes from watersheds are typically defined using mass-balance methods that essentially lump all weathering processes operative in a watershed into a single flux of solute mass measured in streamflow at the watershed outlet. However, it is important that we understand how weathering processes in different hydrological zones of a watershed (i.e., surface, unsaturated, and saturated zones) contribute to the total geochemical flux from the watershed. This capability will improve understanding of how geochemical fluxes from these different zones may change in response to climate change. Here, the geochemical flux from weathering processes occurring solely in the saturated zone is investigated. This task, however, remains exceedingly difficult due to the sparsity of subsurface sampling points, especially in large, remote, and/or undeveloped watersheds. In such cases, springflow is often assumed to be a proxy for groundwater (defined as water residing in fully saturated geologic formations). However, springflow generation may integrate different sources of water including, but not limited to, groundwater. The authors’ hypothesis is that long-term estimates of geochemical fluxes from groundwater using springflow proxies will be too large due to the integrative nature of springflow generation. Two conceptual models of springflow generation are tested using endmember mixing analyses (EMMA) on observations of spring chemistries and stable isotopic compositions in a large alpine watershed in the San Juan Mountains of southwestern Colorado. In the “total springflow” conceptual model, springflow is assumed to be 100% groundwater. In the “fractional springflow” conceptual model, springflow is assumed to be an integration of different sources of water (e.g., groundwater, unsaturated flow, preferential flow in the soil, etc.) and groundwater is only a fractional component. The results indicate that groundwater contributions in springflow range from 2% to 100

Drowning in Geochemical Data: The Good, the bad, and the Ugly

Science.gov (United States)

Hofmann, A. W.; Goldstein, S. L.

2008-12-01

Geochemical databases are placing unprecedented amounts of geochemical data at the fingertips of professionals and students. How these data are being used is taking an increasingly important role in shaping our thinking about the Earth. Databases have helped to expose (and eventually kill?) some long- cherished myths, such as the idea of the well-homogenized upper-mantle reservoir, and and they have made geochemical data accessible to geophysicists and enabled them to look at geochemistry with fresh eyes, leading to genuinely new insights. Yet, their very accessibility also makes them "dangerous tools" in the hands of the inexperienced. Statistical treatment of masses of geochemical data without, or with excessive, filtering can yield all sorts of "answers" we would probably be better off without. Data that are severely flawed (due to alteration or poor analytical quality, errors in published data, or errors during data entry) might not be easily identified by, say, a geodynamicist. Other dangers stem from overrepresentation of over-sampled locations and the general, but faulty, assumption of random sampling of the Earth. We will show examples where raw downloads of data from databases without extensive screening can yield data collections where the garbage swamps the useful information. We will also show impressive but meaningless correlations, e.g. upper-mantle temperature versus atmospheric temperature. The lesson is that screening is necessary. On the other hand, sound database compilations now demonstrate that average incompatible-element concentrations in global MORB are two to five times higher than published estimates. This fundamentally changes 30-year-old geochemical mass balance estimates of the mantle. OIBs are fundamentally similar to MORBs but are isotopically shifted, on average, to more "enriched" values. Mantle geochemistry is now fully consistent with dynamic models of "whole-mantle" circulation, with the likely exception of a relatively small

Pulsed neutron generator system for astrobiological and geochemical exploration of planetary bodies

International Nuclear Information System (INIS)

Akkurt, Hatice; Groves, Joel L.; Trombka, Jacob; Starr, Richard; Evans, Larry; Floyd, Samuel; Hoover, Richard; Lim, Lucy; McClanahan, Timothy; James, Ralph; McCoy, Timothy; Schweitzer, Jeffrey

2005-01-01

A pulsed neutron/gamma-ray detection system for use on rovers to survey the elemental concentrations of Martian and Lunar surface and subsurface materials is evaluated. A robotic survey system combining a pulsed neutron generator (PNG) and detectors (gamma ray and neutron) can measure the major constituents to a depth of about 30 cm. Scanning mode measurements can give the major elemental concentrations while the rover is moving; analyzing mode measurements can give a detailed elemental analysis of the adjacent material when the rover is stationary. A detailed map of the subsurface elemental concentrations will provide invaluable information relevant to some of the most fundamental astrobiological questions including the presence of water, biogenic activity, life habitability and deposition processes

The geochemical environment of nuclear fuel waste disposal

International Nuclear Information System (INIS)

Gascoyne, M.

1995-01-01

The concept for disposal of Canada's nuclear fuel waste in a geologic environment on the Canadian Shield has recently been presented by Atomic Energy of Canada Limited (AECL) to governments, scientists, and the public, for review. An important part of this concept concerns the geochemical environment of a disposal vault and includes consideration of rock and groundwater compositions, geochemical interactions between rocks, groundwaters, and emplaced vault materials, and the influences and significance of anthropogenic and microbiological effects following closure of the vault. This paper summarizes the disposal concept and examines aspects of the geochemical environment. The presence of saline groundwaters and reducing conditions at proposed vault depths (500-1000 m) in the Canadian Shield has an important bearing on the stability of the used nuclear fuel, its container, and buffer and backfill materials. The potential for introduction of anthropogenic contaminants and microbes during site investigations and vault excavation, operation, and sealing is described with examples from AECL's research areas on the Shield and in their underground research laboratory in southeastern Manitoba. (author)

Selections from 2017: Hubble Survey Explores Distant Galaxies

Science.gov (United States)

Kohler, Susanna

2017-12-01

Editors note:In these last two weeks of 2017, well be looking at a few selections that we havent yet discussed on AAS Nova from among the most-downloaded paperspublished in AAS journals this year. The usual posting schedule will resume in January.CANDELS Multi-Wavelength Catalogs: Source Identification and Photometry in the CANDELS COSMOSSurvey FieldPublished January2017Main takeaway:A publication led byHooshang Nayyeri(UC Irvine and UC Riverside) early this year details acatalog of sources built using the Cosmic Assembly Near-infrared Deep Extragalactic Legacy Survey(CANDELS), a survey carried out by cameras on board the Hubble Space Telescope. The catalogliststhe properties of 38,000 distant galaxies visiblewithin the COSMOS field, a two-square-degree equatorial field explored in depthto answer cosmological questions.Why its interesting:Illustration showing the three-dimensional map of the dark matter distribution in theCOSMOS field. [Adapted from NASA/ESA/R. Massey(California Institute of Technology)]The depth and resolution of the CANDELS observations areuseful for addressingseveral major science goals, including the following:Studying the most distant objects in the universe at the epoch of reionization in the cosmic dawn.Understanding galaxy formation and evolution during the peak epoch of star formation in the cosmic high noon.Studying star formation from deep ultravioletobservations and studying cosmology from supernova observations.Why CANDELS is a major endeavor:CANDELS isthe largest multi-cycle treasury program ever approved on the Hubble Space Telescope using over 900 orbits between 2010 and 2013 withtwo cameras on board the spacecraftto study galaxy formation and evolution throughout cosmic time. The CANDELS images are all publicly available, and the new catalogrepresents an enormous source of information about distant objectsin our universe.CitationH. Nayyeri et al 2017 ApJS 228 7. doi:10.3847/1538-4365/228/1/7

Experiments on geochemical prospecting for uranium in arid country; Essais de prospection geochimique de l'uranium en pays aride

Energy Technology Data Exchange (ETDEWEB)

Grimbert, A; Obellianne, J M [Commissariat a l' Energie Atomique, Centre d' Etudes Nucleaires de Fontenay-aux-Roses, 92 (France)

1962-07-01

The necessity for preliminary inquiries before applying routine geochemical prospecting techniques to the exploration of a new region is shown. Under conditions presumed to be unfavorable for geochemical prospecting as found in Nigeria along the banks of the Air, a preliminary examination showed that sampling of the stabilized superficial deposits at a depth of 15 cm made it possible to detect the presence of U-containing mineralizations hidden under about 20 meters of sterile sandy deposits. To confirm this result, a boring located on a U-containing geochemical anomaly in a paleosol, encountered a mineralized formation at a depth of 28 meters. (authors) [French] Les auteurs montrent la necessite des enquetes preliminaires avant toute application en routine des techniques geochimiques de prospection, lorsque l'on aborde une region nouvelle. Dans les conditions, a priori defavorables pour la prospection geochimique, que l'on trouve au Niger, en bordure de l'Air, une enquete preliminaire a etabli que l'echantillonnage des depots superficiels stabilises, a 15 centimetres de profondeur, permettait de deceler la presence de mineralisations uraniferes cachees sous une vingtaine de metres de sediments greseux steriles. Pour verifier ce resultat, un sondage implante sur une anomalie geochimique uranifere au sein d'un paleosol, a rencontre une formation mineralisee a 28 metres de profondeur. (auteurs)

Validation of the WATEQ4 geochemical model for uranium

International Nuclear Information System (INIS)

Krupka, K.M.; Jenne, E.A.; Deutsch, W.J.

1983-09-01

As part of the Geochemical Modeling and Nuclide/Rock/Groundwater Interactions Studies Program, a study was conducted to partially validate the WATEQ4 aqueous speciation-solubility geochemical model for uranium. The solubility controls determined with the WATEQ4 geochemical model were in excellent agreement with those laboratory studies in which the solids schoepite [UO 2 (OH) 2 . H 2 O], UO 2 (OH) 2 , and rutherfordine ((UO 2 CO 3 ) were identified as actual solubility controls for uranium. The results of modeling solution analyses from laboratory studies of uranyl phosphate solids, however, identified possible errors in the characterization of solids in the original solubility experiments. As part of this study, significant deficiencies in the WATEQ4 thermodynamic data base for uranium solutes and solids were corrected. Revisions included recalculation of selected uranium reactions. Additionally, thermodynamic data for the hydroxyl complexes of U(VI), including anionic (VI) species, were evaluated (to the extent permitted by the available data). Vanadium reactions were also added to the thermodynamic data base because uranium-vanadium solids can exist in natural ground-water systems. This study is only a partial validation of the WATEQ4 geochemical model because the available laboratory solubility studies do not cover the range of solid phases, alkaline pH values, and concentrations of inorganic complexing ligands needed to evaluate the potential solubility of uranium in ground waters associated with various proposed nuclear waste repositories. Further validation of this or other geochemical models for uranium will require careful determinations of uraninite solubility over the pH range of 7 to 10 under highly reducing conditions and of uranyl hydroxide and phosphate solubilities over the pH range of 7 to 10 under oxygenated conditions

Lateritinga project: a geochemical orientation study for Amazon lateritic

International Nuclear Information System (INIS)

Costa, M.L. da

1990-01-01

The aim of this project is the development of systematic geochemical orientation survey in lateritic weathered terrain, like those form Amazon Region. The main selected targets (sheets) are: Turiacu, Cajuapara and Serra dos Carajas, with 690 samples collected (soils and lateritic rocks). For the Aurizona-Serra do Pirocaua target (Turiacu sheet), within the purpose of this work, 49 samples were collected in a 100x 200m regular grid. From all samples the fraction minor than 200 mesh was taken to analyses (by XRF, AA, OES, ICP and fire assay) for SiO sub(2), Fe sub(2) O sub(3), TiO sub(2), P sub(2) O sub(5), Sr, Ba, Y, Nb, Zr, Ga, Sc, Ni, Co, Cr, Cu, Mn, V, As, Bi, Pt, Pd, Th, Au and REE, as well for their mineralogy by XRD. The chemical results were submitted to statistical treatment with the Geoquant-software for IBM-compatible microcomputer. (author)

Modeling Background Radiation in our Environment Using Geochemical Data

Energy Technology Data Exchange (ETDEWEB)

Malchow, Russell L.; Marsac, Kara [University of Nevada, Las Vegas; Burnley, Pamela [University of Nevada, Las Vegas; Hausrath, Elisabeth [Uniiversity of Nevada, Las Vegas; Haber, Daniel [University of Nevada, Las Vegas; Adcock, Christopher [University of Nevada, Las Vegas

2015-02-01

Radiation occurs naturally in bedrock and soil. Gamma rays are released from the decay of the radioactive isotopes K, U, and Th. Gamma rays observed at the surface come from the first 30 cm of rock and soil. The energy of gamma rays is specific to each isotope, allowing identification. For this research, data was collected from national databases, private companies, scientific literature, and field work. Data points were then evaluated for self-consistency. A model was created by converting concentrations of U, K, and Th for each rock and soil unit into a ground exposure rate using the following equation: D=1.32 K+ 0.548 U+ 0.272 Th. The first objective of this research was to compare the original Aerial Measurement System gamma ray survey to results produced by the model. The second objective was to improve the method and learn the constraints of the model. Future work will include sample data analysis from field work with a goal of improving the geochemical model.

The ESO Diffuse Interstellar Band Large Exploration Survey (EDIBLES)

Science.gov (United States)

Cami, J.; Cox, N. L.; Farhang, A.; Smoker, J.; Elyajouri, M.; Lallement, R.; Bacalla, X.; Bhatt, N. H.; Bron, E.; Cordiner, M. A.; de Koter, A..; Ehrenfreund, P.; Evans, C.; Foing, B. H.; Javadi, A.; Joblin, C.; Kaper, L.; Khosroshahi, H. G.; Laverick, M.; Le Petit, F..; Linnartz, H.; Marshall, C. C.; Monreal-Ibero, A.; Mulas, G.; Roueff, E.; Royer, P.; Salama, F.; Sarre, P. J.; Smith, K. T.; Spaans, M.; van Loon, J. T..; Wade, G.

2018-03-01

The ESO Diffuse Interstellar Band Large Exploration Survey (EDIBLES) is a Large Programme that is collecting high-signal-to-noise (S/N) spectra with UVES of a large sample of O and B-type stars covering a large spectral range. The goal of the programme is to extract a unique sample of high-quality interstellar spectra from these data, representing different physical and chemical environments, and to characterise these environments in great detail. An important component of interstellar spectra is the diffuse interstellar bands (DIBs), a set of hundreds of unidentified interstellar absorption lines. With the detailed line-of-sight information and the high-quality spectra, EDIBLES will derive strong constraints on the potential DIB carrier molecules. EDIBLES will thus guide the laboratory experiments necessary to identify these interstellar “mystery molecules”, and turn DIBs into powerful diagnostics of their environments in our Milky Way Galaxy and beyond. We present some preliminary results showing the unique capabilities of the EDIBLES programme.

Kriging - a challenge in geochemical mapping

Czech Academy of Sciences Publication Activity Database

Štojdl, J.; Matys Grygar, Tomáš; Elznicová, J.; Popelka, J.; Váchová, T.; Hošek, Michal

2017-01-01

Roč. 19, APR (2017) ISSN 1607-7962. [EGU General Assembly 2017. 23.04.2017-28.04.2017, Vienna] Institutional support: RVO:61388980 Keywords : kriging * geochemical mapping Subject RIV: DD - Geochemistry http://meetingorganizer.copernicus.org/EGU2017/EGU2017-3615.pdf

Geochemical signature of columbite-tantalite and environmental impact of radioactive pegmatite mining in the Parelhas region, Rio Grande do Norte, Northeast Brazil

International Nuclear Information System (INIS)

Moura, Jorge Costa de; Cruz, Paulo R.; Pereira, Valmir; Ludka, Isabel P.; Mendes, Julio C.

2013-01-01

This article comprises geochemical, structural and radiometric investigations on radioactive pegmatites of the Borborema Pegmatitic Province in Northeast Brazil. The studied area is located in the surroundings of the city of Parelhas, in the geotectonic Province of Borborema. It is well known for its thousands of pegmatitic bodies exploited in primitive mines called garimpos. The main goal was to find an efficient, cheap and routine inspection procedure to identify the origin of commercialized radioactive columbite-tantalite (coltan) ore. The Brazilian Nuclear Energy Agency (CNEN) controls uranium commerce and nuclear activity in Brazil. Without an effective method to characterize coltan ores from different localities it is impossible to control the trade. The here presented new method was developed by correlating structural features of these pegmatites with the geochemical behavior of their coltan samples. It was found that the variation of U/Th vs. Nb 2 O 5 /Ta 2 O 5 provides geochemical signatures (analytical fingerprints) for the source location of such ore. The new method was tested with coltan samples of commercial batches from the Brazilian states of Amapa and Rondonia and also generated distinct geochemical signatures. A radiometric survey (CPS) to study the environmental impact of gamma radiation was also carried out in several mines and pegmatites. It included in situ measurements of pegmatite walls, enclosing rocks, soil, and accumulated water and revealed that gamma emitters are hardly solubilized and therefore environmental gamma radiation generally is not enhanced to a dangerous level. (author)

Geological, radiometrical, and geochemical studies of Banggai granites and Bobong formation to determine potential Uranium area in Taliabu Island, North Maluku

International Nuclear Information System (INIS)

Ngadenin

2016-01-01

Geological, radiometrical, and geochemical studies of Banggai granites and Bobong Formation have been conducted in order to obtain potential uranium area. Taliabu Island is selected for the study because Taliabu Island is a micro continent fraction of the Gondwana super continent that separated at the end of the Mesozoic to Paleogene period. Some types of uranium mineralization formed in the period of Gondwana include sandstone-type, lignite coal type, and vein-type. Taliabu Island is a small part from the Gondwana super continent so it is expected will be found uranium mineralization or at least indications of uranium mineralization occurrences. The aim of this study is to obtain uranium potential areas for the development of uranium exploration in the future. The methods used are reviewing geological, radiometric, and geochemical data from various sources. The results of review showed that geological setting, radiometric, and geochemical data gives positive indication to the formation of uranium mineralization for sandstone type. Banggai granite is a potential uranium source. Sandstone of Bobong Formation as a potential host rock. Coal and pyrite as a potential precipitant. Uranium potential area is located on Bobong Formation and its surrounding. (author)

GEOCHEMICAL CONTROLS ON NUCLEAR MAGNETIC RESONANCE MEASUREMENTS

International Nuclear Information System (INIS)

Knight, Rosemary

2008-01-01

Proton nuclear magnetic resonance (NMR) is used in the Earth Sciences as a means of obtaining information about the molecular-scale environment of fluids in porous geological materials. Laboratory experiments were conducted to advance our fundamental understanding of the link between the NMR response and the geochemical properties of geological materials. In the first part of this research project, we studied the impact of both the surface-area-to-volume ratio (S/V) of the pore space and the surface relaxivity on the NMR response of fluids in sand-clay mixtures. This study highlighted the way in which these two parameters control our ability to use NMR measurements to detect and quantify fluid saturation in multiphase saturated systems. The second part of the project was designed to explore the way in which the mineralogic form of iron, as opposed to simply the concentration of iron, affects the surface relaxation rate and, more generally, the NMR response of porous materials. We found that the magnitude of the surface relaxation rate was different for the various iron-oxide minerals because of changes in both the surface-area-to-volume ratio of the pore space, and the surface relaxivity. Of particular significance from this study was the finding of an anomalously large surface relaxivity of magnetite compared to that of the other iron minerals. Differences in the NMR response of iron minerals were seen in column experiments during the reaction of ferrihydrite-coated quartz sand with aqueous Fe(II) solutions to form goethite, lepidocrocite and magnetite; indicating the potential use of NMR as a means of monitoring geochemical reactions. The final part of the research project investigated the impact of heterogeneity, at the pore-scale, on the NMR response. This work highlighted the way in which the geochemistry, by controlling the surface relaxivity, has a significant impact on the link between NMR data and the microgeometry of the pore space.

Status report on geochemical modelling

International Nuclear Information System (INIS)

Read, D.

1991-12-01

This report describes the findings of a review undertaken on behalf of the project management group of the programme 'Endlagersicherheit in der Nachbetriebsphase' based at GSF-IfT (Forschungszentrum fuer Umwelt und Gesundheit - Institut fuer Tieflagerung) to establish the current status of research into the simulation of geochemical processes relevant to radiological assessment. The review is intended to contribute to Stage 1 of a strategy formulated to enhance the use of geochemical models in Germany. Emphasis has been placed on processes deemed to be of greatest relevance to performance assessment for a HLW-repository in a salt dome principally, speciation-solubility in high salinity solutions, complexation by natural organics and generation-transport of colloids. For each of these and other topics covered, a summary is given of fundamental concepts, theoretical representations and their limitations, highlighting, where appropriate, the advantages and disadvantages of alternative approaches. The availability of data to quantify any given representation is addressed, taking into account the need for information at elevated temperatures and pressures. Mass transfer is considered in terms of aqueous, particulate and gas-mediated transport, respectively. (orig.) [de

FY 1998 report on the verification survey of geothermal exploration technology, etc. 2/2. Survey of deep geothermal resource; 1998 nendo chinetsu tansa gijutsu nado kensho chosa hokokusho. 2/2. Shinbu chinetsu shigen chosa

Energy Technology Data Exchange (ETDEWEB)

NONE

1999-12-01

For the purpose of commercializing deep geothermal resource, a deep exploration well of 4000m class was drilled in the existing geothermal development area to survey the situation of deep geothermal resource existence and the availability. Concretely, the deep geothermal exploration well was drilled for study in the Kakkonda area, Shizukuishi town, Iwate prefecture, to clarify the situation of deep geothermal resource existence and the whole image of geothermal system. Consideration was made of the deep geothermal exploration method, systematization of deep high temperature drilling technology, and availability of deep geothermal resource. The results of the survey were summed up as follows: 1) general remarks; 2) deep exploration well drilling work; 3) details of the study. This report contained 3). In 3), the items were as follows: heightening of accuracy of the deep geothermal resource exploration method, making of a geothermal model in the Kakkonda area, study of deep drilling technology, study of deep fluid utilization technology, and making of a guide for deep geothermal resource exploration/development in the Kakkonda area. As to the technology of high temperature deep geothermal well drilling, studies were made of the borehole cooling method, mud water cooling method, survey of deterioration of casing with age, etc. (NEDO)

Geochemical evidence for waning magmatism and polycyclic volcanism at Crater Flat, Nevada

International Nuclear Information System (INIS)

Perry, F.V.; Crowe, B.M.

1992-01-01

This paper reports that petrologic and geochemical studies of basaltic rocks in the Yucca Mountain region are currently focused on understanding the evolution of volcanism in the Crater Flat volcanic field and the mechanisms of polycyclic volcanic field and the mechanisms of polycyclic volcanism at the Lathrop Wells volcanic center, the youngest center in the Crater Flat volcanic field. Geochemical and petrologic data indicate that the magma chambers which supplied the volcanic centers at Crater Flat became situated at greater crustal depths as the field evolved. Deep magma chambers may be related to a waning magma flux that was unable to sustain upper crustal magma conduits and chambers. Geochemical data from the Lathrop Wells volcanic center indicate that eruptive units identified from field and geomorphic relationships are geochemically distinct. The geochemical variations cannot be explained by fractional crystallization of a single magma batch, indicating that several magma batches were involved in the formation of the Lathrop Wells center. Considering the low magma flux in the Yucca Mountain region in the Quaternary, the probability of several magma batches erupting essentially simultaneously at Lathrop Wells is considered remote

Expression of Geochemical Controls on Water Quality in Loch Vale, Rocky Mountain National Park

Science.gov (United States)

Podzorski, H.; Navarre-Sitchler, A.; Stets, E.; Clow, D. W.

2017-12-01

Relationships between concentrations of rock weathering products and discharge provide insight into the interactions between climate and solute dynamics. This concentration-discharge (C-Q) relationship is especially interesting in high alpine regions, due to their susceptibility to changes in the timing and magnitude of snowmelt. Previous studies looking at C-Q relationships have concluded that concentrations of conservative solutes remain relatively constant as discharge varies; however, these results may be due to relatively small sample sizes, especially at higher discharge values. Using water chemistry data collected regularly by the U.S. Geological Survey from Loch Vale, a high-elevation catchment in Rocky Mountain National Park, C-Q relationships were examined to determine possible geochemical controls on stream solute concentrations. A record of over 20 years of C-Q data resulted in a pattern that shows little variation in conservative solute concentrations during base flow and larger variations in concentrations around peak discharge. This observed pattern is consistent with accumulation of solutes in pore water during base flow, which are then flushed out and diluted by snowmelt. Further evidence of this flushing out mechanism is found in patterns of hysteresis that are present in annual C-Q relationships. Before peak discharge, concentrations of weathering products are higher than after peak discharge at similar values of discharge. Based on these observations, we hypothesize that the geochemical processes controlling stream chemistry vary by season. During the winter, solute concentrations are transport-limited due to slow subsurface flushing resulting in concentrations that are effectively constant and close to equilibrium. During the spring and summer, concentrations drop sharply after peak discharge due to a combination of dilution and reaction-limited processes under conditions with faster subsurface flow and continued snowmelt. This study provides

Migrated hydrocarbons in outcrop samples: revised petroleum exploration directions in the Tarim Basin

Energy Technology Data Exchange (ETDEWEB)

Li, Maowen; Snowdon, Lloyd [Geological Survey of Canada, Calgary, AB (Canada); Xiao, Zhongyao [CNPC Tarim Petroleum Exploration Bureau, Kuerle, Xinjiang (China); Lin, Renzi [Petroleum Univ., Changping, Beijing (China); Wang, Peirong; Hou, Dujie [Jianghan Petroleum Univ., Hubei (China); Zhang, Linye [SINOPEC Shengli Petroleum Bureau, Dongying, Shandong (China); Zhang, Shuichang; Liang, Digang [Research Inst. of Petroleum Exploration and Development, Beijing (China)

2000-07-01

The application of age-specific biomarker distributions established from mature exploration areas of the Tarim Basin, northwestern China, indicates that most Carboniferous-Permian outcrop samples in the eastern segment of the Southwest Depression, previously believed to have significant petroleum source potential, in fact contain migrated hydrocarbons derived from Cambrian-Lower Ordovician strata. New geochemical results have led to a major revision of petroleum exploration directions in this area. (Author)

Literature survey of redox reactions in the near field

International Nuclear Information System (INIS)

Miki, Takahito; Chiba, Tamotsu; Inagaki, Manabu; Sasamoto, Hiroshi; Yui, Mikazu

2000-01-01

This report presents a summary of literature survey about geochemical reactions which are important to evaluate the redox conditions in the near field rock mass and buffer. The results of literature survey are summarized as follows; Minerals including ferrous iron and organic materials in the rock mass are important reductants. Initial stage after closure of repository, oxygen will be consumed by pyrite, because the reaction rate between pyrite and oxygen is relatively fast. It is possible to estimate the redox capacity for reductants by rock (mineral)-water interaction experiment in a laboratory. And it is expected that the ferrous iron-rich rock and higher porosity rock may have bigger redox capacity. It is impossible to estimate the oxygen consumption rate by reductants such as minerals including ferrous iron. The rate law and rate constant for the oxidation reaction of ferrous iron in the solution are also determined. As a conclusion, it seems that we can evaluate kinetically the evolution of geochemical conditions in the near field rock mass and buffer by excavation of drifts, based on data derived from these existing literatures. (author)

The application of radon survey by activated carbon in the exploration of sandstone-type uranium deposit in Teguidda, Niger

International Nuclear Information System (INIS)

Shen Zhengxin

2012-01-01

This paper described the application of the method of activated carbon survey in the exploration of sandstone-type uranium deposits in Niger. The survey principle and the measures to ensure the survey quality were also introduced. Through the tests at known deposits, this method shows good response to ground mineralization, deep uranium sources and fault information. Good result had been obtained in the study area which indicated that this method can be used as an important evidence to determine the target area for uranium mineralization. (author)

Integration of multi-source data in mineral exploration

DEFF Research Database (Denmark)

Conradsen, Knut; Ersbøll, Bjarne Kjær; Nielsen, Allan Aasbjerg

1991-01-01

This paper describes several multivariate statistical analysis applications of geochemical, geophysical, and spectral variables in mineral exploration. Mahalanobis' distance is described in some detail and based on four multisource variables this measure is applied to produce a map that gives an ...... of automatically generated linear features based on Landsat TM data. The results indicate among other things a not previously recognized subsurface continuation of an already mapped lineament....

Compilation of new and previously published geochemical and modal data for Mesoproterozoic igneous rocks of the St. Francois Mountains, southeast Missouri

Science.gov (United States)

du Bray, Edward A.; Day, Warren C.; Meighan, Corey J.

2018-04-16

The purpose of this report is to present recently acquired as well as previously published geochemical and modal petrographic data for igneous rocks in the St. Francois Mountains, southeast Missouri, as part of an ongoing effort to understand the regional geology and ore deposits of the Mesoproterozoic basement rocks of southeast Missouri, USA. The report includes geochemical data that is (1) newly acquired by the U.S. Geological Survey and (2) compiled from numerous sources published during the last fifty-five years. These data are required for ongoing petrogenetic investigations of these rocks. Voluminous Mesoproterozoic igneous rocks in the St. Francois Mountains of southeast Missouri constitute the basement buried beneath Paleozoic sedimentary rock that is over 600 meters thick in places. The Mesoproterozoic rocks of southeast Missouri represent a significant component of approximately 1.4 billion-year-old (Ga) igneous rocks that crop out extensively in North America along the southeast margin of Laurentia and subsequent researchers suggested that iron oxide-copper deposits in the St. Francois Mountains are genetically associated with ca. 1.4 Ga magmatism in this region. The geochemical and modal data sets described herein were compiled to support investigations concerning the tectonic setting and petrologic processes responsible for the associated magmatism.

Use of a time-domain electromagnetic method with geochemical tracers to explore the salinity anomalies in a small coastal aquifer in north-eastern Tunisia

Science.gov (United States)

Chekirbane, Anis; Tsujimura, Maki; Kawachi, Atsushi; Lachaal, Fethi; Isoda, Hiroko; Tarhouni, Jamila

2014-12-01

The study area is a small coastal plain in north-eastern Tunisia. It is drained by an ephemeral stream network and is subject to several pollutant discharges such as oilfield brine coming from a neighboring oil company and wastewater from Somâa city, located in the upstream of the plain. Furthermore, a hydraulic head near the coastal part of the aquifer is below sea level, suggesting that seawater intrusion may occur. A time-domain electromagnetic (TDEM) survey, based on 28 soundings, was conducted in Wadi Al Ayn and Daroufa plains to delineate the saline groundwater. Based on longitudinal and transversal resistivity two-dimensional pseudosections calibrated with boring data, the extent of saline water was identified. Geochemical tracers were combined with the resistivity dataset to differentiate the origin of groundwater salinization. In the upstream part of the plain, the infiltration of oilfield brine through the sandy bed of Wadi Al Ayn seems to have a considerable effect on groundwater salinization. However, in the coastal part of the aquifer, groundwater salinization is due to seawater intrusion and the saltwater is reaching an inland extent around 1.3 km from the shoreline. The contribution ratios of saline water bodies derived from the inverted chloride data vary for the oilfield brine from 1 to 13 % and for the seawater from 2 to 21 %.

Remote sensing applied in uranium exploration

International Nuclear Information System (INIS)

Conradsen, K.; Nilsson, G.; Thyrsted, T.

1985-01-01

A research project, aiming at investigation the use of remote sensing in uranium exploration, has been accomplished on data from South Greenland. During the project, analyses have been done on pure remote sensing data (Landsat MSS) and on integrated data of various types, including geochemical, aeromagnetic, radiometric and geological data in addition to the MSS data. Ratioing, factor analysis and discriminant analysis were used for enhancement of colour anomalies which correspond to oxidation zones. Some of the anomalies coincide with U and Nb mineralizations. Lineaments were mapped visually from photoprints, digitized and analysed statistically. A sinusoidal model could be applied to the general directional frequency distribution and was used to define ten classes of significant directions. Three of these directions were of major geological significance. Thus some of the major alkaline intrusions are situated at the intersections of some of the lineaments, a particular NE-SW trending lineament coincides with a geochemical boundary and pitchblende occurrences may be related to a WNW-ESE direction. The various types of data set were brought onto format of the Landsat images and collected in a data base. Representing three different types of data (Landsat MSS-band 7, aeromagnetic data and the geochemical Fe-content of stream sediments) on basis of intensity, hue and saturation revealed new features among which can be mentioned a possible indication of a subsurface continuation of one of the major alkaline intrusions. (author)

Geochemical methods for identification of formations being prospective for uranium

International Nuclear Information System (INIS)

Zhukova, A.M.; Komarova, N.I.; Spiridonov, A.A.; Shor, G.M.

1985-01-01

Geochemical methods of uranium content evaluation in metamorphic, ultrametamorphic and sedimentary formations are considered. At that, the following four factors are of the highest importance: 1) average uranium content-geochemical background; 2) character of uranium distribution; 3) forms of uranium presence; 4) the value of thorium-uranium ratio. A complex of radiogeochemical criteria, favourable for uranium presence is formulated: high average background content of total and '' mobile''uranium and high value of variation coefficient (80-100% and above); low (approximately one or lower) thorium-uranium ratio; sharp increase in uranium concentration in accessory minerals. Radiogeochemical peculiarities of metamorphic and ultrametamorphic formations prospective for uranium are enumerated. The peculiarities condition specificity of geochemical prospecting methods. Prospecting methods first of all must be directed at the evaluation of radioelement distribution parameters and specification of the forms of their presence

Geochemical Data Package for Performance Assessment Calculations Related to the Savannah River Site

Energy Technology Data Exchange (ETDEWEB)

Kaplan, Daniel I. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

2016-07-22

The Savannah River Site (SRS) disposes of low-level radioactive waste (LLW) and stabilizes high-level radioactive waste (HLW) tanks in the subsurface environment. Calculations used to establish the radiological limits of these facilities are referred to as Performance Assessments (PA), Special Analyses (SA), and Composite Analyses (CA). The objective of this document is to revise existing geochemical input values used for these calculations. This work builds on earlier compilations of geochemical data (2007, 2010), referred to a geochemical data packages. This work is being conducted as part of the on-going maintenance program of the SRS PA programs that periodically updates calculations and data packages when new information becomes available. Because application of values without full understanding of their original purpose may lead to misuse, this document also provides the geochemical conceptual model, the approach used for selecting the values, the justification for selecting data, and the assumptions made to assure that the conceptual and numerical geochemical models are reasonably conservative (i.e., bias the recommended input values to reflect conditions that will tend to predict the maximum risk to the hypothetical recipient). This document provides 1088 input parameters for geochemical parameters describing transport processes for 64 elements (>740 radioisotopes) potentially occurring within eight subsurface disposal or tank closure areas: Slit Trenches (ST), Engineered Trenches (ET), Low Activity Waste Vault (LAWV), Intermediate Level (ILV) Vaults, Naval Reactor Component Disposal Areas (NRCDA), Components-in-Grout (CIG) Trenches, Saltstone Facility, and Closed Liquid Waste Tanks. The geochemical parameters described here are the distribution coefficient, Kd value, apparent solubility concentration, k_s value, and the cementitious leachate impact factor.

Synthesizing Earth's geochemical data for hydrogeochemical analysis

Science.gov (United States)

Brantley, S. L.; Kubicki, J.; Miller, D.; Richter, D.; Giles, L.; Mitra, P.

2007-12-01

For over 200 years, geochemical, microbiological, and chemical data have been collected to describe the evolution of the surface earth. Many of these measurements are data showing variations in time or in space. To forward predict hydrologic response to changing tectonic, climatic, or anthropogenic forcings requires synthesis of these data and utilization in hydrogeochemical models. Increasingly, scientists are attempting to synthesize such data in order to make predictions for new regions or for future time periods. However, to make such complex geochemical data accessible requires development of sophisticated cyberinfrastructures that both invite uploading as well as usage of data. Two such cyberinfrastructure (CI) initiatives are currently developing, one to invite and promote the use of environmental kinetics data (laboratory time course data) through ChemxSeer, and the other to invite and promote the use of spatially indexed geochemical data for the Earth's Critical Zone through CZEN.org. The vision of these CI initiatives is to provide cyber-enhanced portals that encourage domain scientists to upload their data before publication (in private cyberspace), and to make these data eventually publicly accessible (after an embargo period). If the CI can be made to provide services to the domain specialist - e.g. to provide data analysis services or data comparison services - we envision that scientists will upload data. In addition, the CI can promote the use and comparison of datasets across disciplines. For example, the CI can facilitate the use of spatially indexed geochemical data by scientists more accustomed to dealing with time-course data for hydrologic flow, and can provide user-friendly interfaces with CI established to facilitate the use of hydrologic data. Examples of the usage of synthesized data to predict soil development over the last 13ky and its effects on active hydrological flow boundaries in surficial systems will be discussed for i) a N

Cross-correlation analysis of 2012-2014 seismic events in Central-Northern Italy: insights from the geochemical monitoring network of Tuscany

Science.gov (United States)

Pierotti, Lisa; Facca, Gianluca; Gherardi, Fabrizio

2015-04-01

Since late 2002, a geochemical monitoring network is operating in Tuscany, Central Italy, to collect data and possibly identify geochemical anomalies that characteristically occur before regionally significant (i.e. with magnitude > 3) seismic events. The network currently consists of 6 stations located in areas already investigated in detail for their geological setting, hydrogeological and geochemical background and boundary conditions. All these stations are equipped for remote, continuous monitoring of selected physicochemical parameters (temperature, pH, redox potential, electrical conductivity), and dissolved concentrations of CO2 and CH4. Additional information are obtained through in situ discrete monitoring. Field surveys are periodically performed to guarantee maintenance and performance control of the sensors of the automatic stations, and to collect water samples for the determination of the chemical and stable isotope composition of all the springs investigated for seismic precursors. Geochemical continuous signals are numerically processed to remove outliers, monitoring errors and aseismic effects from seasonal and climatic fluctuations. The elaboration of smoothed, long-term time series (more than 200000 data available today for each station) allows for a relatively accurate definition of geochemical background values. Geochemical values out of the two-sigma relative standard deviation domain are inspected as possible indicators of physicochemical changes related to regional seismic activity. Starting on November 2011, four stations of the Tuscany network located in two separate mountainous areas of Northern Apennines separating Tuscany from Emilia-Romagna region (Equi Terme and Gallicano), and Tuscany from Emilia-Romagna and Umbria regions (Vicchio and Caprese Michelangelo), started to register anomalous values in pH and CO2 partial pressure (PCO2). Cross-correlation analysis indicates an apparent relationship between the most important seismic

Geochemical fingerprints and pebbles zircon geochronology

Indian Academy of Sciences (India)

Home; Journals; Journal of Earth System Science; Volume 125; Issue 7. Geochemical fingerprints and pebbles zircon geochronology: Implications for the provenance and tectonic setting of Lower Cretaceous sediments in the Zhucheng Basin (Jiaodong peninsula, North China). Jin-Long Ni Jun-Lai Liu Xiao-Ling Tang ...

LASL approach to uranium geochemical reconnaissance

Energy Technology Data Exchange (ETDEWEB)

Sharp, R.R. Jr.

1977-01-01

The US ERDA, as part of the NURE program, has initiated a nationwide Hydrogeochemical and Stream Sediment Reconnaissance (HSSR). The aims of the NURE program are to provide data on which to base more accurate estimates of US uranium reserves for long-range planning and to aid in meeting the nation's projected uranium demands into the next century. The HSSR objective is to complete, by 1980, a reconnaissance of the nation's surface waters, ground waters, and stream and lake sediments, to aid in assessment of uranium reserves and identification of areas of interest for exploration. Patterned after extensive uranium reconnaissance done in many other countries, the LASL project is comprised of the following five components: (1) organization and planning, which includes management, design, and execution; (2) field sampling, which includes orientation studies, generation of specifications, and contracting and inspection of field work; (3) sample receiving and analysis, which includes development of methods and hardware, quality assurance, and archival storage; (4) data handling and presentation, including verification, storage, output, and plotting; and (5) data evaluation and publication, which incorporates geochemical, geological, statistical, and empirical evaluation and report writing. The LASL approach to each component and the current status in each state are described.

LASL approach to uranium geochemical reconnaissance

International Nuclear Information System (INIS)

Sharp, R.R. Jr.

1977-01-01

The US ERDA, as part of the NURE program, has initiated a nationwide Hydrogeochemical and Stream Sediment Reconnaissance (HSSR). The aims of the NURE program are to provide data on which to base more accurate estimates of US uranium reserves for long-range planning and to aid in meeting the nation's projected uranium demands into the next century. The HSSR objective is to complete, by 1980, a reconnaissance of the nation's surface waters, ground waters, and stream and lake sediments, to aid in assessment of uranium reserves and identification of areas of interest for exploration. Patterned after extensive uranium reconnaissance done in many other countries, the LASL project is comprised of the following five components: (1) organization and planning, which includes management, design, and execution; (2) field sampling, which includes orientation studies, generation of specifications, and contracting and inspection of field work; (3) sample receiving and analysis, which includes development of methods and hardware, quality assurance, and archival storage; (4) data handling and presentation, including verification, storage, output, and plotting; and (5) data evaluation and publication, which incorporates geochemical, geological, statistical, and empirical evaluation and report writing. The LASL approach to each component and the current status in each state are described

User’s guide for GcClust—An R package for clustering of regional geochemical data

Science.gov (United States)

Ellefsen, Karl J.; Smith, David B.

2016-04-08

GcClust is a software package developed by the U.S. Geological Survey for statistical clustering of regional geochemical data, and similar data such as regional mineralogical data. Functions within the software package are written in the R statistical programming language. These functions, their documentation, and a copy of the user’s guide are bundled together in R’s unit of sharable code, which is called a “package.” The user’s guide includes step-by-step instructions showing how the functions are used to cluster data and to evaluate the clustering results. These functions are demonstrated in this report using test data, which are included in the package.

Geochemical, hydrological, and biological cycling of energy residual. Research plan

International Nuclear Information System (INIS)

Wobber, F.J.

1983-03-01

Proposed research goals and specific research areas designed to provide a base of fundamental scientific information so that the geochemical, hydrological, and biophysical mechanisms that contribute to the transport and long term fate of energy residuals in natural systems can be understood are described. Energy development and production have resulted in a need for advanced scientific information on the geochemical transformations, transport rates, and potential for bioaccumulation of contaminants in subsurface environments

Adaptive Multiscale Modeling of Geochemical Impacts on Fracture Evolution

Science.gov (United States)

Molins, S.; Trebotich, D.; Steefel, C. I.; Deng, H.

2016-12-01

Understanding fracture evolution is essential for many subsurface energy applications, including subsurface storage, shale gas production, fracking, CO2 sequestration, and geothermal energy extraction. Geochemical processes in particular play a significant role in the evolution of fractures through dissolution-driven widening, fines migration, and/or fracture sealing due to precipitation. One obstacle to understanding and exploiting geochemical fracture evolution is that it is a multiscale process. However, current geochemical modeling of fractures cannot capture this multi-scale nature of geochemical and mechanical impacts on fracture evolution, and is limited to either a continuum or pore-scale representation. Conventional continuum-scale models treat fractures as preferential flow paths, with their permeability evolving as a function (often, a cubic law) of the fracture aperture. This approach has the limitation that it oversimplifies flow within the fracture in its omission of pore scale effects while also assuming well-mixed conditions. More recently, pore-scale models along with advanced characterization techniques have allowed for accurate simulations of flow and reactive transport within the pore space (Molins et al., 2014, 2015). However, these models, even with high performance computing, are currently limited in their ability to treat tractable domain sizes (Steefel et al., 2013). Thus, there is a critical need to develop an adaptive modeling capability that can account for separate properties and processes, emergent and otherwise, in the fracture and the rock matrix at different spatial scales. Here we present an adaptive modeling capability that treats geochemical impacts on fracture evolution within a single multiscale framework. Model development makes use of the high performance simulation capability, Chombo-Crunch, leveraged by high resolution characterization and experiments. The modeling framework is based on the adaptive capability in Chombo

A hydro-geochemical study of Nahr-Ibrahim catchment area: Fluvial metal transport

International Nuclear Information System (INIS)

Korfali, Samira

2004-01-01

peaks only to calcite, dolomite and quartz. No speciation of metals in flood plain soils was done, nor XRD. The flood plain contains mostly terra rossa soils high in oxides and it is expected that the Ferric soil phase would have a major role in metal retention. The objective of this study is a complete hydro-geochemical survey of Nahr-Ibrahim catchment area and this study would clarify fluvial metal transport within the catchment area. The outcome of this work might assess the factors that influence water quality. This is attained through an improved knowledge of river hydrology, texture of sediment and soil, minerals in soil and sediment and soil and sediment geochemistry

Archean crust-mantle geochemical differentiation

Science.gov (United States)

Tilton, G. R.

Isotope measurements on carbonatite complexes and komatiites can provide information on the geochemical character and geochemical evolution of the mantle, including the sub-continental mantle. Measurements on young samples establish the validity of the method. These are based on Sr, Nd and Pb data from the Tertiary-Mesozoic Gorgona komatiite and Sr and Pb data from the Cretaceous Oka carbonatite complex. In both cases the data describe a LIL element-depleted source similar to that observed presently in MORB. Carbonatite data have been used to study the mantle beneath the Superior Province of the Canadian Shield one billion years (1 AE) ago. The framework for this investigation was established by Bell et al., who showed that large areas of the province appear to be underlain by LIL element-depleted mantle (Sr-85/Sr-86=0.7028) at 1 AE ago. Additionally Bell et al. found four complexes to have higher initial Sr ratios (Sr-87/Sr-86=0.7038), which they correlated with less depleted (bulk earth?) mantle sources, or possibly crustal contamination. Pb isotope relationships in four of the complexes have been studied by Bell et al.

Archean crust-mantle geochemical differentiation

Science.gov (United States)

Tilton, G. R.

1983-01-01

Isotope measurements on carbonatite complexes and komatiites can provide information on the geochemical character and geochemical evolution of the mantle, including the sub-continental mantle. Measurements on young samples establish the validity of the method. These are based on Sr, Nd and Pb data from the Tertiary-Mesozoic Gorgona komatiite and Sr and Pb data from the Cretaceous Oka carbonatite complex. In both cases the data describe a LIL element-depleted source similar to that observed presently in MORB. Carbonatite data have been used to study the mantle beneath the Superior Province of the Canadian Shield one billion years (1 AE) ago. The framework for this investigation was established by Bell et al., who showed that large areas of the province appear to be underlain by LIL element-depleted mantle (Sr-85/Sr-86=0.7028) at 1 AE ago. Additionally Bell et al. found four complexes to have higher initial Sr ratios (Sr-87/Sr-86=0.7038), which they correlated with less depleted (bulk earth?) mantle sources, or possibly crustal contamination. Pb isotope relationships in four of the complexes have been studied by Bell et al.

Geochemical signature of columbite-tantalite and environmental impact of radioactive pegmatite mining in the Parelhas region, Rio Grande do Norte, Northeast Brazil

Energy Technology Data Exchange (ETDEWEB)

Moura, Jorge Costa de; Cruz, Paulo R.; Pereira, Valmir, E-mail: jcmoura@cnen.gov.br, E-mail: pcruz@cnen.gov.br, E-mail: vpereira@cnen.gov.br [Comissao Nacional de Energia Nuclear (CNEN-RJ), Rio de Janeiro, RJ (Brazil); Ludka, Isabel P.; Mendes, Julio C., E-mail: ludka@geologia.ufrj.br, E-mail: julio@geologia.ufrj.br [Universidade Federal de Rio do Janeiro (CCMN/UFRJ), Rio de Janeiro, RJ (Brazil). Centro de Ciencias Matematicas e da Natureza. Dept. de Geologia

2013-07-01

This article comprises geochemical, structural and radiometric investigations on radioactive pegmatites of the Borborema Pegmatitic Province in Northeast Brazil. The studied area is located in the surroundings of the city of Parelhas, in the geotectonic Province of Borborema. It is well known for its thousands of pegmatitic bodies exploited in primitive mines called garimpos. The main goal was to find an efficient, cheap and routine inspection procedure to identify the origin of commercialized radioactive columbite-tantalite (coltan) ore. The Brazilian Nuclear Energy Agency (CNEN) controls uranium commerce and nuclear activity in Brazil. Without an effective method to characterize coltan ores from different localities it is impossible to control the trade. The here presented new method was developed by correlating structural features of these pegmatites with the geochemical behavior of their coltan samples. It was found that the variation of U/Th vs. Nb{sub 2}O{sub 5}/Ta{sub 2}O{sub 5} provides geochemical signatures (analytical fingerprints) for the source location of such ore. The new method was tested with coltan samples of commercial batches from the Brazilian states of Amapa and Rondonia and also generated distinct geochemical signatures. A radiometric survey (CPS) to study the environmental impact of gamma radiation was also carried out in several mines and pegmatites. It included in situ measurements of pegmatite walls, enclosing rocks, soil, and accumulated water and revealed that gamma emitters are hardly solubilized and therefore environmental gamma radiation generally is not enhanced to a dangerous level. (author)

Acceptance of the 2014 Geochemical Society Distinguished Service Award by Carla Koretsky

Science.gov (United States)

Koretsky, Carla

2015-06-01

I am deeply touched to have received the Geochemical Society Distinguished Service Award. It was a great surprise when I received the notice that I had been chosen for the award. It has been a tremendous pleasure to work on behalf of student members of the Geochemical Society, Japanese Geochemical Society and the European Association of Geochemists to organize the student travel grants over the past few years. Certainly, this is not an effort that I undertook on my own. Many, many members of the GS, the JGS and the EAG generously donated their time and expertise to serve as reviewers for the many travel grant applicants we receive each year. Seth Davis, the GS Chief Operating Officer, spent countless hours helping to organize applications, the website, distribution of funds and many other aspects of the competition. Without Seth and the many expert reviewers, we could not run the travel grant program each year and provide this important financial support to allow more students to experience the Goldschmidt Conference. I also enjoyed my time as Geochemical News co-editor, and I should point out that GN during those years was ably co-edited by Johnson Haas. It has been a pleasure to see Elements take off, and GN evolve into a timely source of important announcements and information about cutting-edge science since I stepped down as co-editor. I feel very fortunate to work with so many outstanding colleagues in the global geochemical community, and I am a little embarrassed, and also very grateful, to have been selected for the Geochemical Society Distinguished Service Award. Thank you!

Geochemical disturbance of soil cover in the nonferrous mining centers of the Selenga River basin.

Science.gov (United States)

Timofeev, Ivan V; Kosheleva, Natalia E

2017-08-01

The anthropogenic geochemical transformation of soil cover in large nonferrous mining centers of the Selenga River basin was assessed. The results of the geochemical survey of 2010-2012 revealed the spatial distribution patterns and abundances of 18 hazardous heavy metals and metalloids in the soils of Erdenet (Mongolia) and Zakamensk (Buryat republic, Russian Federation). In both cities, mining activities disturbed soil cover which accumulates Mo, Cu, As, Sb, W in Erdenet and Bi, W, Cd, Be, Pb, Mo, Sb in Zakamensk. Maximum accumulation of elements in Erdenet is restricted to the industrial zone. In Zakamensk, it has spread on ½ of the territory with the degree of multielemental pollution exceeding the extremely dangerous level by 16 times. The effect of mining centers on the state of the river system is local and does not spread to the Selenga River. Downstream from Erdenet, an artificial pool intercepts heavy metal and metalloid flows of the Erdenetii-Gol River. By contrast, downstream from the tailing dumps of the Dzhida tungsten-molybdenum plant the concentrations of ore elements W and Mo and their accessories Bi and Cd in the Modonkul River exceed background values by 146, 20, 57, and 21 times, respectively, decreasing by an order of magnitude 30 km downstream.

Identification of hydrologic and geochemical pathways using high frequency sampling, REE aqueous sampling and soil characterization at Koiliaris Critical Zone Observatory, Crete

Energy Technology Data Exchange (ETDEWEB)

Moraetis, Daniel, E-mail: moraetis@mred.tuc.gr [Department of Environmental Engineering, Technical University of Crete, 73100 Chania (Greece); Stamati, Fotini; Kotronakis, Manolis; Fragia, Tasoula; Paranychnianakis, Nikolaos; Nikolaidis, Nikolaos P. [Department of Environmental Engineering, Technical University of Crete, 73100 Chania (Greece)

2011-06-15

Highlights: > Identification of hydrological and geochemical pathways within a complex watershed. > Water increased N-NO{sub 3} concentration and E.C. values during flash flood events. > Soil degradation and impact on water infiltration within the Koiliaris watershed. > Analysis of Rare Earth Elements in water bodies for identification of karstic water. - Abstract: Koiliaris River watershed is a Critical Zone Observatory that represents severely degraded soils due to intensive agricultural activities and biophysical factors. It has typical Mediterranean soils under the imminent threat of desertification which is expected to intensify due to projected climate change. High frequency hydro-chemical monitoring with targeted sampling for Rare Earth Elements (REE) analysis of different water bodies and geochemical characterization of soils were used for the identification of hydrologic and geochemical pathways. The high frequency monitoring of water chemical data highlighted the chemical alterations of water in Koiliaris River during flash flood events. Soil physical and chemical characterization surveys were used to identify erodibility patterns within the watershed and the influence of soils on surface and ground water chemistry. The methodology presented can be used to identify the impacts of degraded soils to surface and ground water quality as well as in the design of methods to minimize the impacts of land use practices.

Statistical treatment of geochemical data and its application in the geologic mapping and in the definition of the geochemical anomalies in the Alvo 2-Corpo 4 -Provincia Mineral de Carajas

International Nuclear Information System (INIS)

Moura, C.A.V.

1982-01-01

It was given a statistical treatment for the geochemical data about soil in the are named Alvo2 - Corpo4- in the Provincia Mineral de Carajas, Para, Brazil, for application of the geological mapping and definition of geochemical anomalies. (A.B.) [pt

Chlorine isotopes potential as geo-chemical tracers

Digital Repository Service at National Institute of Oceanography (India)

Shirodkar, P.V.; Pradhan, U.K.; Banerjee, R.

The potential of chlorine isotopes as tracers of geo-chemical processes of earth and the oceans is highlighted based on systematic studies carried out in understanding the chlorine isotope fractionation mechanism, its constancy in seawater and its...

Reconnaissance survey for lightweight and carbon tetrachloride extractable hydrocarbons in the central and eastern basins of Lake Erie: September 1978

Energy Technology Data Exchange (ETDEWEB)

Zapotosky, J.E.; White, W.S.

1980-10-01

A reconnaissance survey of the central and eastern basins of Lake Erie (22,240 km/sup 2/) was conducted from September 17 to 27, 1978. The survey provided baseline information on natural gas and oil losses from geologic formations, prior to any potential development of natural gas resources beneath the United States portion of the Lake. Lightweight hydrocarbons indicative of natural gas (methane, ethane, propane, isobutane, and n-butane) are introduced into the waters of Lake Erie by escape from geologic formations and by biological/photochemical processes. The geochemical exploration technique of hydrocarbon sniffing provided enough data to reveal significant distribution patterns, approximate concentrations, and potential sources. Twelve sites with elevated lightweight hydrocarbon concentrations had a composition similar to natural gas. In one area of natural gas input, data analysis suggested a potential negative effect of natural gas on phytoplanktonic metabolism (i.e., ethylene concentration). Samples taken for liquid hydrocarbon analysis (carbon tetrachloride extractable hydrocarbons) correlated best with biologically derived lightweight hydrocarbons.

Exploring the gap between the practical and theoretical world of ERP implementations: results of a global survey.

NARCIS (Netherlands)

Catersels, R.; Helms, R.W.; Batenburg, R.

2010-01-01

This paper describes the differences between the theoretical world of ERP researchers and the practical world of ERP consultants. A survey was held among 129 ERP consultants to explore their opinion and experience with regard to a number of subjects that have been researched in many papers, such as

Interim report on Tanjung Enim IV coal exploration project. South Arahan area (1998/1999)

Energy Technology Data Exchange (ETDEWEB)

NONE

1999-05-01

The exploration project in Indonesia covered geological mapping, drilling, geophysical logging, underground water pumping tests, vertical seismic profiling (VSP), and seismic reflection survey. Ten boreholes were drilled. Moreover, coal property analysis, geotechnical rock test, geochemical analysis, and the like were conducted by examining core specimens sampled from the boreholes. It was found that there are three main coal beds which continuously extend to the two ends of the synclinic structure. It was also found that there is a 6m-thick coal bed 200m further below the three main coal beds, and it is estimated to produce approximately 6,000kcal/kg. Coal from two of the three beds produces 5,000kcal/kg, containing but a little ash and sulfur. Coal from the third includes 1.17% of sulfur. Coal in all the beds is summed up, and then it is estimated that there is approximately 1,054-million tons of coal in reserve in the South Arahan area. (NEDO)

Stream Sediment Geochemical Survey of Selected Element In Catchment Area Of Saguling Lake

Directory of Open Access Journals (Sweden)

Wardhani Eka

2018-01-01

Full Text Available Saguling Lake is one of the largest lakes in West Java Province that accommodates domestic and non-domestic wastes via the Citarum River as its main water source. This study aims to determine the geochemical background concentration (Cbg in water catchment area of Saguling Lake. The knowledge of the Cbg of heavy metals is essential for defining pollution, identifying the source of contamination, and for establishing reliable environmental quality criteria for sediments. The value of Cbg will be used for assessment of the sediment quality in Saguling Lake. Assessment of sediment quality is very important to determine the actual condition of water in the lake and as the basis for management of waters environment in the future. The search was taken at 22 sampling points in the unpolluted water catchment area. Samples were collected and analyzed for Cd, Cr, Cu, and Pb. Each sample was digested in agua regia and analyzed by ICP-EOS. Results showed Cbg which are: Cd 0.34 ± 0.10 mg/kg, Cr 110.57 ± 28.61 mg/kg, Cu 49.93 ± 9.28 mg/kg, and Pb 18.62 ± 9.83 mg/kg. Based on the assessment result, it is concluded that the sediment quality in Saguling Lake is categorized as polluted by Cd, Cr, Cu, and Pb metals.

Geochemical typification of kimberlite and related rocks of the North Anabar region, Yakutia

Science.gov (United States)

Kargin, A. V.; Golubeva, Yu. Yu.

2017-11-01

The results of geochemical typification of kimberlites and related rocks (alneites and carbonatites) of the North Anabar region are presented with consideration of the geochemical specification of their source and estimation of their potential for diamonds. The content of representative trace elements indicates the predominant contribution of an asthenospheric component (kimberlites and carbonatites) in their source, with a subordinate contribution of vein metasomatic formations containing Cr-diopside and ilmenite. A significant contribution of water-bearing potassium metasomatic parageneses is not recognized. According to the complex of geochemical data, the studied rocks are not industrially diamondiferous.

NEW GEOCHEMICAL DATA OF BASALTS IN THE TSOROIDOG AREA, CENTRAL MONGOLIA

Directory of Open Access Journals (Sweden)

T. Oyunchimeg

2017-01-01

Full Text Available At present, geochemical data are widely used for reconstructing geodynamic settings, especially, volcanic rocks of mafic composition, i.e., basalts, because they are widespread in many orogenic belts and are indicative of different geodynamic environments. In general, we propose the reconstruction of the tectonic settings of basalts according to their relationships with associated ocean plate stratigraphy (OPS sediments, their petrogenesis and their geochemical features.

The application of isotopic dating methods for prospection and exploration of nuclear raw material

International Nuclear Information System (INIS)

Komlev, L.V.; Anderson, E.B.

1977-01-01

Among the geological and geochemical methods for prospecting and searching the nuclear raw material, the isotope-dating methods determine the most important search criterion - the time of the ore-forming. The elaboration and use of these methods in uranium-ore regions reveal a series of geochemical epochs of uranium and thorium accumulation connected naturally with the history of geological evolution of the earth crust. The isotope-dating methods enable with confidence to establish the stages of tectono-magmatic activity resulting in the redistribution and the local concentration of uranium. The wide use of isotopic methods is a necessary condition for reasonable trends of the modern geological exploration [ru

Geochemical Parameters Required from the SKB Site Characterisation Programme

International Nuclear Information System (INIS)

Bath, Adrian

2002-01-01

SKB has described its approach to site characterisation in a number of Technical Reports. One of the scientific topics in which specific information requirements and priorities are set out is geochemistry. This report for SKI examines critically whether the geochemical parameters identified in the SKB programme documents will be adequate for safety and regulatory requirements. It also examines some of the details of parameter requirements and interpretation tools that will be necessary to convert site investigation data into knowledge about chemical conditions and groundwater movements. The SKB strategy for geochemical data focuses on a small number of 'suitability indicators', primarily dissolved oxygen, pH and salinity. Their parameter requirements aim to assess those primary characteristics, as well as to acquire a wider range of data that will support those assessments and provide a broader understanding of candidate areas. An initial observation in this review that, though it is a primary suitability indicator, dissolved oxygen apparently will not be measured and instead will be inferred from other redox indicators. This raises a number of issues about sampling and monitoring measures, analytical data reliability and sensitivity, and the degree of confidence in geochemical understanding. A geochemical programme involves reconnaissance by desk study and acquisition of new data at levels of details that are appropriate to the stage of site investigations. As early as possible, a conceptual model of a candidate area should help to define the objectives of geochemical measurements on both rock and groundwater samples. It is recommended that parameters requirements should be defined and considered not only in terms of isolated measurements but more in terms of addressing broader objectives that relate to safety and also to geoscientific understanding. The safety priorities remain (e.g. dissolved oxygen) but will then be supported by an understanding of processes

Geochemical Parameters Required from the SKB Site Characterisation Programme

Energy Technology Data Exchange (ETDEWEB)

Bath, Adrian [Intellisci Ltd., Loughborough (United Kingdom)

2002-01-01

SKB has described its approach to site characterisation in a number of Technical Reports. One of the scientific topics in which specific information requirements and priorities are set out is geochemistry. This report for SKI examines critically whether the geochemical parameters identified in the SKB programme documents will be adequate for safety and regulatory requirements. It also examines some of the details of parameter requirements and interpretation tools that will be necessary to convert site investigation data into knowledge about chemical conditions and groundwater movements. The SKB strategy for geochemical data focuses on a small number of 'suitability indicators', primarily dissolved oxygen, pH and salinity. Their parameter requirements aim to assess those primary characteristics, as well as to acquire a wider range of data that will support those assessments and provide a broader understanding of candidate areas. An initial observation in this review that, though it is a primary suitability indicator, dissolved oxygen apparently will not be measured and instead will be inferred from other redox indicators. This raises a number of issues about sampling and monitoring measures, analytical data reliability and sensitivity, and the degree of confidence in geochemical understanding. A geochemical programme involves reconnaissance by desk study and acquisition of new data at levels of details that are appropriate to the stage of site investigations. As early as possible, a conceptual model of a candidate area should help to define the objectives of geochemical measurements on both rock and groundwater samples. It is recommended that parameters requirements should be defined and considered not only in terms of isolated measurements but more in terms of addressing broader objectives that relate to safety and also to geoscientific understanding. The safety priorities remain (e.g. dissolved oxygen) but will then be supported by an understanding of

Ionizing radiation and radionuclides in the environment: sources, origin, geochemical processes and health risks

International Nuclear Information System (INIS)

Dangic, A.

1995-01-01

Ionizing radiation related to the radioactivity and radionuclides appears to be ones of most dangerous environmental risks to the human health. The paper considers appearance and importance of radionuclides, both natural (cosmogenic and Earth's) and anthropogenic, mode of their entering into and movement through the environment. Most risk to the population are radionuclides related to the geological-geochemical systems - in Serbia, high concentrations of radionuclides related to these sources were indicated at a number of localities. Movement of radionuclides through the environment is regulated by the geochemical processes i.e. the geochemical cycles of the elements. For the discovering of radionuclides in the nature, the assessment of the health risks to the population and the related protection are necessary multilayer geochemical studies. (author)

The geochemical profile of Mn, Co, Cu and Fe in Kerteh Mangrove Forest, Terengganu

International Nuclear Information System (INIS)

Kamaruzzaman, B.Y.; Antotina, A.; Airiza, Z.; Syalindran, S.; Ong, M.C.

2007-01-01

The geochemical profile of Kerteh mangrove sediments was analyzed for the vertical and horizontal distribution. The 100 cm core sediment sample and 15 surface sediments samples were taken from the field. The geochemical elements of Mn, Co, Cu and Fe of the sediments were analyzed. Geochemical proxy of Mn, Co, Cu and Fe were analyzed by using Inductively Coupled Plasma-Mass Spectrometry (ICP-MS). The mean concentrations of Mn, Co, Cu and Fe for the vertical distribution were 210.18 μg/ g, 15.55 μg/ g, 43.65 μg/ g and 1.88 μg/ g respectively. on the other hand, the mean concentrations of the geochemical elements for horizontal distributions were 230.50 μg/ g for Mn, 17.57 μg/ g for Co, 43.381 μg/ g for Cu and 2.93 μg/ g for Fe. Enrichment factor and normalization was used to point out the level of pollution. The EF and the normalization indicated that all the geochemical elements were from the natural sources. (author)

Microbial iron cycling in acidic geothermal springs of Yellowstone National Park: Integrating molecular surveys, geochemical processes and isolation of novel Fe-active microorganisms

Directory of Open Access Journals (Sweden)

Mark A Kozubal

2012-03-01

Full Text Available Geochemical, molecular, and physiological analyses of microbial isolates were combined to study the geomicrobiology of acidic iron oxide mats in Yellowstone National Park (YNP. Nineteen sampling locations from 11 geothermal springs were studied ranging in temperature from 53 to 84 °C and pH 2.4 to 3.6. All iron-oxide mats exhibited high diversity of crenarchaeal sequences from the Sulfolobales, Thermoproteales, and Desulfurococcales. The predominant Sulfolobales sequences were highly similar to Metallosphaera yellowstonensis str. MK1, previously isolated from one of these sites. Other groups of archaea were consistently associated with different types of iron oxide mats, including undescribed members of the phyla Thaumarchaeota and Euryarchaeota. Bacterial sequences were dominated by relatives of Hydrogenobaculum spp. above 65-70 °C, but increased in diversity below 60 °C. Cultivation of relevant iron-oxidizing and iron-reducing microbial isolates included Sulfolobus str. MK3, Sulfobacillus str. MK2, Acidicaldus str. MK6, and a new candidate genus in the Sulfolobales referred to as Sulfolobales str. MK5. Strains MK3 and MK5 are capable of oxidizing ferrous iron autotrophically, while strain MK2 oxidizes iron mixotrophically. Similar rates of iron oxidation were observed for M. yellowstonensis str. MK1 and Sulfolobales str. MK5 cultures, and these rates are close to those measured in situ. Biomineralized phases of ferric iron varied among cultures and field sites, and included ferric oxyhydroxides, K-jarosite, goethite, hematite, and scorodite depending on geochemical conditions. Strains MK5 and MK6 are capable of reducing ferric iron under anaerobic conditions with complex carbon sources. The combination of geochemical and molecular data as well as physiological observations of isolates suggests that the community structure of acidic Fe mats is linked with Fe cycling across temperatures ranging from 53 to 88 oC.

Geochemical haloes as an indication of over oil and gas fields in the Arctic shelf

Science.gov (United States)

Kholmiansky, Mikhail; Anokhin, Vladimir

2013-04-01

Hydrocarbon deposits at the Arctic shelf of Russia are a source of jet dispersion of heavy metals that forms haloes in sediments and in the bottom layer of sea water. The intensity of the haloes and their spatial position are jointly determined by geological structure of their source and the environment, i.e., hydrocarbon deposits in host rocks, seafloor lithodynamics and oceanographic factors. Based on theoretical works of Kholmyansky and Putikov (2000; 2006; 2008), an application of electrochemical modification of electric prospecting for offshore hydrocarbon exploration and detailed survey of the morphology of deposits was developed. Specialized equipment was developed for studies of electrochemical features of bottom water layer. With this equipment one can detect ion anomalies in water and determine the type of deposit as gas, gas hydrate, gas condensate or oil. At operation, the unit with equipment is towed underwater off the stern of research vessel. Type and configuration of deposits are determined based on occurrence of trace heavy metals detected by ion-selective electrodes. The proposed method was applied to study a few hydrocarbon fields in Barents and Kara seas in 2001 -2012 including Shtokman, Medyn, Polyarnoe, Prirazlomnoye and others. The results allowed us to trace the margins of the deposits in more detail, and geochemical data, in addition, showed the type of deposits. In general, the method has proven efficient and applicable to a wide range of hydrocarbon deposits.

FY 1997 basic survey for coal resource development. Data collection of the joint research of new technology in the geophysical exploration of coal resources (water area medium depth seam survey); 1997 nendo sekitan shigen kaihatsu kiso chosa shiryoshu. Shintansa gijutsu chosa kaihatsu (suiiki chushindoso tansa)

Energy Technology Data Exchange (ETDEWEB)

NONE

1999-03-01

In 'the new exploration technology test on coal resource' (water area medium depth seam exploration) jointly conducted between Japan and China, tests have been carried out for 5 years on the BDR-5 test boring measurement monitoring system and the diamond bit which are items of the technology development of high resolution seismic survey system and high efficiency test boring system. As a result, the new technology test was successful, and technical economic effects were obtained. The situation of the test was summarized. The following data were compiled as shown in Data No.1-12. 1. The proceedings of the FY 1997 Japan-China steering committee (No.9). 2. Report on the survey of China verification field South Sihu water level situation. 3. The proceedings of the FY 1997 Japan-China steering committee (final). 4. Report on the FY 1997 reflection seismic exploration survey. 5. Report on the FY 1997 No.2 test boring survey. 6. Summarization of the test on 'the new exploration technology of coal source' conducted between Japan and China. 7. Report on the drilling data measurement. 8. Various sections of the reflection seismic survey data processing. 9. Traverse line chart. 10. T3 isochrone chart. 11. T3 depth structural chart. 12. Report on the new exploration technology survey development (water area medium depth seam exploration) geological model making. (NEDO)

Uranium exploration target selection for proterozoic iron oxide/breccia complex type deposits in India

International Nuclear Information System (INIS)

Dwivedy, K.K.; Sinha, K.K.

1997-01-01

Multimetal iron oxide/breccia complex (IOBC) type deposits exemplified by Olympic Dam in Australia, fall under low grade, large tonnage deposits. A multidisciplinary integrated exploration programme consisting of airborne surveys, ground geological surveys, geophysical and geochemical investigations and exploratory drilling, supported adequately by the state of the art analytical facilities, data processing using various software and digital image processing has shown moderate success in the identification of target areas for this type of deposits in the Proterozoic terrains of India. Intracratonic, anorogenic, continental rift to continental margin environment have been identified in a very wide spectrum of rock associations. The genesis and evolution of such associations during the Middle Proterozoic period have been reviewed and applied for target selection in the (i) Son-Narmada rift valley zone; (ii) areas covered by Dongargarh Supergroup of rocks in Madhya Pradesh; (iii) areas exposing ferruginous breccia in the western part of the Singhbhum Shear Zone (SSZ) around Lotapahar; (iv) Siang Group of rocks in Arunachal Pradesh; (v) Crystalline rocks of Garo Hills around Anek; and (vi) Chhotanagpur Gneissic complex in the Bahia-Ulatutoli tract of Ranchi Plateau. Of theses six areas, the Son-Narmada rift area appears to be the most promising area for IOBC type deposits. Considering occurrences of the uranium anomalies near Meraraich, Kundabhati, Naktu and Kudar and positive favourability criteria observed in a wide variety of rocks spatially related to the rifts and shears, certain sectors in Son-Narmada rift zone have been identified as promising for intense subsurface exploration. 20 refs, 4 figs, 1 tab

Landscape and bio- geochemical strategy for monitoring transformation and reclamation of the soil mining sites

Science.gov (United States)

Korobova, Elena

2010-05-01

Sites of active or abandoned mining represent areas of considerable technogenic impact and need scientifically ground organization of their monitoring and reclamation. The strategy of monitoring and reclamation depends on the scale and character of the physical, chemical and biological consequences of the disturbances. The geochemical studies for monitoring and rehabilitation of the career-dump complexes should methodically account of formation of the particular new landforms and the changes in circulation of the remobilized elements of the soil cover. However, the general strategy should account of both the initial and transformed landscape geochemical structure of the area with due regard to the natural and new content of chemical elements in the environmental components. For example the tailings and waste rocks present new geochemical fields with specifically different concentration of chemical elements that cause formation of new geochemical barriers and landscapes. The way of colonization of the newly formed landscapes depends upon the new geochemical features of the technogenic environment and the adaptive ability of local and intrusive flora. The newly formed biogeochemical anomalies need organization of permanent monitoring not only within the anomaly itself but also of its impact zones. Spatial landscape geochemical monitoring combined with bio-geochemical criteria of threshold concentrations seems to be a helpful tool for decision making on reclamation and operation of the soil mining sites to provide a long-term ecologically sustainable development of the impact zone as a whole.

Version 4. 00 of the MINTEQ geochemical code

Energy Technology Data Exchange (ETDEWEB)

Eary, L.E.; Jenne, E.A.

1992-09-01

The MINTEQ code is a thermodynamic model that can be used to calculate solution equilibria for geochemical applications. Included in the MINTEQ code are formulations for ionic speciation, ion exchange, adsorption, solubility, redox, gas-phase equilibria, and the dissolution of finite amounts of specified solids. Since the initial development of the MINTEQ geochemical code, a number of undocumented versions of the source code and data files have come into use at the Pacific Northwest Laboratory (PNL). This report documents these changes, describes source code modifications made for the Aquifer Thermal Energy Storage (ATES) program, and provides comprehensive listings of the data files. A version number of 4.00 has been assigned to the MINTEQ source code and the individual data files described in this report.

Version 4.00 of the MINTEQ geochemical code

Energy Technology Data Exchange (ETDEWEB)

Eary, L.E.; Jenne, E.A.

1992-09-01

The MINTEQ code is a thermodynamic model that can be used to calculate solution equilibria for geochemical applications. Included in the MINTEQ code are formulations for ionic speciation, ion exchange, adsorption, solubility, redox, gas-phase equilibria, and the dissolution of finite amounts of specified solids. Since the initial development of the MINTEQ geochemical code, a number of undocumented versions of the source code and data files have come into use at the Pacific Northwest Laboratory (PNL). This report documents these changes, describes source code modifications made for the Aquifer Thermal Energy Storage (ATES) program, and provides comprehensive listings of the data files. A version number of 4.00 has been assigned to the MINTEQ source code and the individual data files described in this report.

The ESO Diffuse Interstellar Bands Large Exploration Survey (EDIBLES) . I. Project description, survey sample, and quality assessment

Science.gov (United States)

Cox, Nick L. J.; Cami, Jan; Farhang, Amin; Smoker, Jonathan; Monreal-Ibero, Ana; Lallement, Rosine; Sarre, Peter J.; Marshall, Charlotte C. M.; Smith, Keith T.; Evans, Christopher J.; Royer, Pierre; Linnartz, Harold; Cordiner, Martin A.; Joblin, Christine; van Loon, Jacco Th.; Foing, Bernard H.; Bhatt, Neil H.; Bron, Emeric; Elyajouri, Meriem; de Koter, Alex; Ehrenfreund, Pascale; Javadi, Atefeh; Kaper, Lex; Khosroshadi, Habib G.; Laverick, Mike; Le Petit, Franck; Mulas, Giacomo; Roueff, Evelyne; Salama, Farid; Spaans, Marco

2017-10-01

The carriers of the diffuse interstellar bands (DIBs) are largely unidentified molecules ubiquitously present in the interstellar medium (ISM). After decades of study, two strong and possibly three weak near-infrared DIBs have recently been attributed to the C60^+ fullerene based on observational and laboratory measurements. There is great promise for the identification of the over 400 other known DIBs, as this result could provide chemical hints towards other possible carriers. In an effort tosystematically study the properties of the DIB carriers, we have initiated a new large-scale observational survey: the ESO Diffuse Interstellar Bands Large Exploration Survey (EDIBLES). The main objective is to build on and extend existing DIB surveys to make a major step forward in characterising the physical and chemical conditions for a statistically significant sample of interstellar lines-of-sight, with the goal to reverse-engineer key molecular properties of the DIB carriers. EDIBLES is a filler Large Programme using the Ultraviolet and Visual Echelle Spectrograph at the Very Large Telescope at Paranal, Chile. It is designed to provide an observationally unbiased view of the presence and behaviour of the DIBs towards early-spectral-type stars whose lines-of-sight probe the diffuse-to-translucent ISM. Such a complete dataset will provide a deep census of the atomic and molecular content, physical conditions, chemical abundances and elemental depletion levels for each sightline. Achieving these goals requires a homogeneous set of high-quality data in terms of resolution (R 70 000-100 000), sensitivity (S/N up to 1000 per resolution element), and spectral coverage (305-1042 nm), as well as a large sample size (100+ sightlines). In this first paper the goals, objectives and methodology of the EDIBLES programme are described and an initial assessment of the data is provided.

National Uranium Resource Evaluation Program. Hydrogeochemical and stream sediment pilot survey of Llano area, Texas

International Nuclear Information System (INIS)

Nichols, C.E.; Kane, V.E.; Minkin, S.C.; Cagle, G.W.

1976-01-01

A pilot geochemical survey of the Llano, Texas, area was conducted during February and March 1976. The purpose of this work was to prepare for a subsequent reconnaissance geochemical survey of uranium in Central Texas. Stream sediment, stream water, well water, and plant ash from five geologic areas were analyzed in the laboratory for approximately 25 parameters. Examples of anomalous values in stream sediment and stream water indicate the usefulness of both sample types in identifying anomalies at a regional reconnaissance-scale station spacing of approximately 5 km (3 mi). Groundwater samples, which generally best indicate the geochemistry of formations at depth in a survey of this type, represent another important tool in detecting uranium mineralization. Anomalies in San Saba County are associated with the Marble Falls-Smithwich Formations and the Strawn Series (Pennsylvanian), the Houy Formation (Devonian and lower Mississippian), and the Hickory Sandstone Member of the Riley Formation (Cambrian). In Burnet County anomalous values are due to the influence of the Valley Spring Formation (Precambrian); and in Blanco County anomalies are found associated with the Riley Formation

Determination of geochemical and natural radioactivity characteristics in Bilecik Marble, Turkey

Science.gov (United States)

Yerel Kandemir, Suheyla; Ozbay, Nurgul

2014-05-01

Natural stones are one of the oldest known building materials. There are more than 400 natural stone in Turkey. Recently, the demand for the natural stone types in markets has been increasing rapidly. For this reason, the geochemical and natural radioactivity characteristics of natural stone are very important. Bilecik province is located at the northwest part of Turkey and it is surrounded by Sakarya, Bursa, Eskisehir and Kutahya city. Bilecik is one of the important marble industry regions of Turkey. Thus, the geochemical and natural radioactivity characteristics of Bilecik marble are very important. In this study, Bilecik marble was collected to determine the geochemistry and natural radioactivity. Then, analyses of geochemical and natural radioactivity in the marble samples are interpreted. ACKNOWLEDGMENT This study is supported by Bilecik Seyh Edebali University scientific project (Project Number =2011-02-BIL.03-04).

Report on the geothermal development promotion survey. No.C-3. Akinomiya area; Chinetsu kaihatsu sokushin chosa hokokusho. No.C-3 Akinomiya chiiki

Energy Technology Data Exchange (ETDEWEB)

NONE

2001-03-01

The paper summed up the results of the survey of the geothermal development promotion survey - Akinomiya area which was carried out in Yuzawa City and Ogachi Town, Akita Prefecture, from FY 1996 to FY 1999. In the survey, the following were conducted: surface survey such as the geological alteration zone survey, fluid geochemical survey, gravity survey and electromagnetic exploration, logging by drilling 8 boreholes, jetting test, etc. Further, using the data obtained from these, analysis was made of geology/reservoir structure, thermal structure, hydraulic structure, etc. As a result, grasped were the distribution of the main underground fracture structure and the distribution of promising high-temperature zones. In the short-term/long-term jetting test, a total steam amount of 124 t/h was confirmed. Moreover, there was the pressure interference between the geothermal reservoir in the Akinomiya area and the geothermal reservoir in the Wasabizawa area, and it was confirmed that there was the hydraulic relation between those reservoirs. Further, it was assumed that there was not so much effect on hot spring reservoirs in the Akinomiya area. In the simulation of production prediction, the result was obtained that there was a possibility of power generation of 30MW only in the Akinomiya area and of 60MW both in the Akinomiya area and the Wasabizawa area. (NEDO)

Development of geophysical and geochemical data processing software based on component GIS

International Nuclear Information System (INIS)

Ke Dan; Yu Xiang; Wu Qubo; Han Shaoyang; Li Xi

2013-01-01

Based on component GIS and mixed programming techniques, a software which combines the basic GIS functions, conventional and unconventional data process methods for the regional geophysical and geochemical data together, is designed and developed. The software has many advantages, such as friendly interface, easy to use and utility functions and provides a useful platform for regional geophysical and geochemical data processing. (authors)

Disciplinary reinforcement of separation and immobilization of radionuclides. Survey of present and required knowledge

International Nuclear Information System (INIS)

Comans, R.N.J.; Prij, J.; Konings, R.J.M.; Woittiez, J.R.W.

1996-11-01

An overview of the knowledge and technical possibilities within the units Nuclear Energy, Radiation Technology, and Fossil Fuels of the Netherlands Energy Research Foundation (ECN) in the fields of separation and immobilization, including the geochemical behavior, of radionuclides, is given. The aim of the survey is to maintain the competence at ECN in this field, to better serve the present market in the future, and to explore potential, new markets, all by means of a disciplinary-oriented development. From the results of the survey it appears that the present knowledge and technical know-how at the three units is complementary and that there are good options to strengthen the position of ECN, in particular in the working areas back-end of the nuclear fuel cycle, and the post trajectory of the decontamination activities (actinide migration in the geosphere and the biosphere, assessment of the effectiveness of immobilization of fissionable materials with respect to recycling, leaching performance of waste containers and natural radioisotopes in solid waste, produced by the group Decontamination and Radioactive Waste Processing (DRA, abbreviated in Dutch) and a modelled description, health effects of radiation. Recommendations are given how the required knowledge reinforcement can be realized. 59 refs

Geochemical prospect ion results of Mariscala aerial photo

International Nuclear Information System (INIS)

Filippini, J.

1989-01-01

This report shows the geochemical prospect ion results carried out within the framework of the metalical mining prospect ion in Mariscala aerial photo. Lavalleja district belong to the Mining inventory programme of Uruguay.

Geochemical methodology for gold prospect ion in Uruguay

International Nuclear Information System (INIS)

Spangenber, J.

1987-01-01

This work is about the history of gold prospection in Uruguay. In this study there are considered the geochemical aspects, the gold performance, the applicability to mining prospection and the gold prospection aluvionar

Report on the geothermal development promotion survey. No.34. Kaminoyu/Santai area; Chinetsu kaihatsu sokushin chosa hokokusho. No. 34 Kaminoyu Santai chiiki

Energy Technology Data Exchange (ETDEWEB)

NONE

1994-03-01

The paper summed up the results of the geothermal development promotion survey 'Kaminoyu/Santai area' which was carried out at Yakumo town, Yamakoshi county, and Mori town, Kayabe county, Hokkaido, from FY 1990 to FY 1992. In the survey, the following were conducted for the comprehensive analysis: surface survey such as geology/alteration zone survey, geochemical survey and gravity exploration, test to induce jetting of geothermal fluids by drilling 7 boreholes, temperature/pressure log, etc. The geological structure of this area is featured by the uplift structure/caldera structure and the anticline structure. In the wide-area geothermal system, it is thought that the low-temperature seawater permeates underground by mixture with meteoric water, is heated, and forms the deep geothermal water. It is thought that the hot spring water in this area is stored in the hot spring reservoir by mixture with the surface water, and it is gushing. In the area, the region which is regarded as favorable as passage/storage place of geothermal fluid is a region of 1.5km width extending linearly in the E-W direction from the Nigorikawa basin to Kaminoyu. Further, it is thought that fractures were unfavorably developed in the Santai/Kaminoyu area. (NEDO)

Report on the geothermal development promotion survey. No.34. Kaminoyu/Santai area; Chinetsu kaihatsu sokushin chosa hokokusho. No. 34 Kaminoyu Santai chiiki

Energy Technology Data Exchange (ETDEWEB)

NONE

1994-03-01

The paper summed up the results of the geothermal development promotion survey 'Kaminoyu/Santai area' which was carried out at Yakumo town, Yamakoshi county, and Mori town, Kayabe county, Hokkaido, from FY 1990 to FY 1992. In the survey, the following were conducted for the comprehensive analysis: surface survey such as geology/alteration zone survey, geochemical survey and gravity exploration, test to induce jetting of geothermal fluids by drilling 7 boreholes, temperature/pressure log, etc. The geological structure of this area is featured by the uplift structure/caldera structure and the anticline structure. In the wide-area geothermal system, it is thought that the low-temperature seawater permeates underground by mixture with meteoric water, is heated, and forms the deep geothermal water. It is thought that the hot spring water in this area is stored in the hot spring reservoir by mixture with the surface water, and it is gushing. In the area, the region which is regarded as favorable as passage/storage place of geothermal fluid is a region of 1.5km width extending linearly in the E-W direction from the Nigorikawa basin to Kaminoyu. Further, it is thought that fractures were unfavorably developed in the Santai/Kaminoyu area. (NEDO)

Geochemical and biogeochemical investigations in national parks [Badania geochemiczne i biogeochemiczne w parkach narodowych

Science.gov (United States)

Migaszewski, Z.M.; Lamothe, P.J.; Crock, J.G.

1998-01-01

National parks hold a key position among nature protection areas including a diversity of resources - natural, cultural, recreational and scenic. These "inviolable sanctuaries" are simultaneosuly ecologic knots and pristine nature refuges due to the presence of a number of unique plant and animal species. These species make up a natural gene bank. Classically, the level of biologic degradation in national parks is determined on the basis of qualitative and quantitative studies of plant bioindicators. Their scope encompasses phytosociologic survey the purpose of which is to identify floral assemblages with a detailed list of species to record future changes in their number. The best biomonitors of air quality are epiphytic lichens, ground mosses and conifers. Geochemical and biogeochemical investigations are widely performed in the U.S.A. to evaluate the degree of pollution in the nature protection areas including national parks (Gough et al., 1988a, b; Crock et al., 1992a, 1993; Jackson et al., 1995). Variability of element concentrations in soils and plants is assessed by using unbalanced, nested analysis-of-variance (ANOVA). It enables obtaining important statistical information with a minimum number of samples. In some cases a combined grid and barbell sampling design is applied (Jackson et al., 1995). In specific mountainous parks a method of 2-3 transects parallel to the extent of range (crest) is recommended. To determine the impact of a single pollution source on a given park, traverse sampling beginning near the emitter is used (Crock et al., 1992, 1993). The obtained results are a "snapshot" of chemical composition of soils and plant bioindicators that can be a reference for any future changes in the concentration level of chemical elements and organics. In addition, baseline element and organics composition of the media mentioned above can be compared with that obtained for geochemical atlases of polluted urban and industrial areas. Geochemical and

Geochemical and isotopic evidences for a severe anthropogenic boron contamination: A case study from Castelluccio (Arezzo, central Italy)

International Nuclear Information System (INIS)

Venturi, Stefania; Vaselli, Orlando; Tassi, Franco; Nisi, Barbara; Pennisi, Maddalena; Cabassi, Jacopo; Bicocchi, Gabriele; Rossato, Luca

2015-01-01

In 2009 a deterioration of garden plants watered with domestic wells was related to high boron concentrations (up to 57 mg/L) measured in the shallow aquifer from the industrial area of Castelluccio (Tuscany, Italy), where several factories are or were using boron compounds for their industrial processes. Since 2012 a geochemical and isotopic survey of stream, ground and waste waters, and sediment samples was performed. In addition, monthly geochemical surveys were carried out from January to September 2013, during which concentrations of boron up to 139 mg/L were measured. The geochemical dataset also included raw (borax and sodium boron-hydride) and anthropogenic materials (B-rich slags and muds stored in one of the local factories), the latter being, to the best of our knowledge, analyzed for the first time in this work for bulk and leachate boron concentration and isotopic ratios. The results highlighted that the high concentrations of boron found in the local shallow aquifer had unequivocally an anthropogenic source. It was suggested that prolonged interaction between industrial (presently stored at ground level or buried) by-products and waste and meteoric waters was likely the main process responsible of the groundwater contamination as supported by the analysis of the major solutes. The dispersion of the contaminant could not clearly be observed downward the shallow hydrogeological circuit. Consequently, the presence of other sources of boron in the industrial area of Castelluccio cannot be excluded. This would also explain the reason why no univocal results were obtained by the "1"1B/"1"0B isotopic ratios measured in water, sediment and (bulk and leachate) anthropogenic samples. To minimize the boron contamination a hydraulic barrier should be constructed where the highest concentrations of boron were measured. - Highlights: • High boron concentrations were measured in a groundwater system near Arezzo (Italy). • Several factories in the local

Evaluation of disposal site geochemical performance using a containment factor

International Nuclear Information System (INIS)

Lerman, A.; Domenico, P.A.; Bartlett, J.W.

1988-01-01

The containment factor is a measure of retention by geologic setting of wastes released from a repository. The factor is alternatively defined either in terms of several measurable hydrological and geochemical parameters, or in terms of amounts of waste components that may be released to the geologic setting and, subsequently, to the environment. Containment factors for individual waste components in a given geologic setting are functions of groundwater to rock volume ratios, sorption or exchange characteristics of the rocks, and containment time to groundwater travel time ratios. For high-level radioactive wastes, containment factors based on the NRC and EPA limit values for cumulative releases from waste and to the environment provide a measure of the geochemical performance of the geologic setting in tuff, basalt, and salt. The containment factor values for individual nuclides from high-level wastes indicate that for some of the nuclides containment may be achieved by groundwater travel time along. For other nuclides, additional performance functions need to be allocated to geochemical retention by such processes as sorption, ion-exchange or precipitation

Geochemical prospecting for Cu mineralization in an arid terrain-central Iran

Science.gov (United States)

Mokhtari, Ahmad Reza; Roshani Rodsari, Parisa; Fatehi, Moslem; Shahrestani, Shahed; Pournik, Peyman

2014-12-01

Geochemical sampling and data processing were implemented for prospecting Cu mineralization through catchment basin approach in central Iran, Yazd province, over drainage systems in order to determine areas of interest for the detailed exploration program. The target zone, inside an area called Kalout-e-Ashrafa in Yazd province-Iran, was characterized by the collection of 107 stream sediment samples. Catchment basin modeling was conducted based on digital elevation model (DEM) and geological map of the study area. Samples were studied by univariate and multivariate statistical techniques of exploratory data analysis, classical statistical analysis and cluster analysis. The results showed that only Cu had anomalous behavior and it did not exhibit a considerable correlation with other elements. Geochemical maps were prepared for Cu and anomalous zones and separated for potential copper mineralization. It was concluded that due to especial geomorphological and geographical characteristics (smooth topography, negligible annual precipitation and insufficient thickness of silicified Cu-bearing outcrops of the area), low concentrations of Cu would be expected for the delineation of promising zones in similar trains. Using cluster analysis showed that there was a strong correlation between Ag, Sr and S. Calcium and Pb present moderate correlation with Cu. Additionally, there was a strong correlation between Zn and Li, thereby indicating a meaningful correlation with Fe, P, Ti and Mg. Aluminum, Sc and V had a correlation with Be and K. Applying threshold value according to MAD (median absolute deviation) helped us to distinguish anomalous catchments more properly. Finally, there was a significant kind of conformity among anomalous catchment basins and silicified veins and veinlets (as validating index) at the central part of the area.

Environmental and geochemical assessment of surface sediments on irshansk ilmenite deposit area

Directory of Open Access Journals (Sweden)

Наталия Олеговна Крюченко

2015-03-01

Full Text Available It is revealed the problem of pollution of surface sediments of Irshansk ilmenite deposit area of various chemical elements hazard class (Mn, V, Ba, Ni, Co, Cr, Mo, Cu, Pb, Zn. It is determined its average content in surface sediments of various functional areas (forest and agricultural land, flood deposits, reclaimed land, calculated geochemical criteria, so given ecological and geochemical assessment of area

Geochemical of clay formations : study of Spanish clay REFERENCE

International Nuclear Information System (INIS)

Turrero, M. J.; Pena, J.

2003-01-01

Clay rocks are investigated in different international research programs in order to assess its feasibility for the disposal of high level radioactive wastes. This is because different sepcific aspects: they have low hydraulic conductivity (10''-11-10''-15 m/s), a high sorption capacity, self-sealing capacity of facults and discontinuities and mechanical resistance. Several research programs on clay formations are aimed to study the chemistry of the groundwater and the water-rock reactions that control it: e. g. Boom Clay (Mol, Belgium), Oxford Clay /Harwell, United Kingdom), Toarcian Clay (Tournemire, France), Palfris formation (Wellenberg, Switzerland), Opalinus Clay (Bure, France). Based on these studies, considerable progress in the development of techniques for hydrologic, geochemical and hydrogeochemical characterization of mudstones has been accomplished (e. g. Beaufais et al. 1994, De Windt el al. 1998. Thury and Bossart 1999, Sacchi and Michelot 2000) with important advances in the knowledge of geochemical process in these materials (e. g. Reeder et al. 1993, Baeyens and Brandbury 1994, Beaucaire et al. 2000, Pearson et al., 2003).Furtermore, geochemical modeling is commonly used to simulate the evolution of water chemistry and to understand quantitatively the processes controlling the groundwater chemistry (e. g. Pearson et al. 1998, Tempel and Harrison 2000, Arcos et al., 2001). The work presented here is part of a research program funded by Enresa in the context of its R and D program. It is focused on the characterization of a clay formation (reference Argillaceous Formation, RAF) located within the Duero Basin (north-centralSpain). The characterisation of th ephysical properties,, fluid composition, mineralogy, water-rock reaction processes, geochemical modelling and sorption properties of the clays from the mentioned wells is the main purpose of this work. (Author)

Geochemical characterization of Parana Basin volcanic rocks: petrogenetic implications

International Nuclear Information System (INIS)

Marques, L.S.

1988-01-01

A detailed study of the geochemical characteristics of Parana Basin volcanic rocks is presented. The results are based on the analyses of major and trace elements of 158 samples. Ninety three of these volcanic samples belong to 8 flow sequences from Rio Grande do Sul and Santa Catarina States. The remaining sixty five samples are distributed over the entire basin. In order to study the influence of crustal contamination processes in changing chemical characteristics of the volcanic rocks, 47 samples representative of the crystalline basement of the southern and southeastern Parana Basin were also analysed. Several petrogenetic models were tested to explain the compocional variability of the volcanic rocks, in particular those of southern region. The results obtained sugest an assimilation-fractional crystallization process as viable to explain the differences of both the chemical characteristics and Sr isotope initial ratios observed in basic and intermediate rocks. A model involving melting processes of basic material, trapped at the base of the crust, with composition similar to low and high TiO 2 basalts appears to be a possibility to originate the Palmas and Chapeco acid melts, respectively. The study of ''uncontaminated'' or poorly contaminated low TiO 2 basic rocks from the southern, central and northern regions shows the existence of significant differences in the geochemical charactetistics according to their geographical occurrence. A similar geochemical diversity is also observed in high TiO 2 basalts and Chapeco volcanics. Differences in incompatible element ratios between low and high TiO 2 ''uncontaminated'' or poorly contaminated basalts suggest that they could have been produced by different degrees of melting in a garnet peridotite source. Geochemical and isotopic (Sr and Nd) data also support the view that basalts from northern and southern regions of Parana Basin originated from mantle source with different composition. (author) [pt

Remote Raman - laser induced breakdown spectroscopy (LIBS) geochemical investigation under Venus atmospheric conditions

Energy Technology Data Exchange (ETDEWEB)

Clegg, Sanuel M [Los Alamos National Laboratory; Barefield, James E [Los Alamos National Laboratory; Humphries, Seth D [Los Alamos National Laboratory; Wiens, Roger C [Los Alamos National Laboratory; Vaniman, D. T. [Los Alamos National Laboratory; Sharma, S. K. [UNIV OF HAWAII; Misra, A. K. [UNIV OF HAWAII; Dyar, M. D. [MT. HOLYOKE COLLEGE; Smrekar, S. E. [JET PROPULSION LAB.

2010-12-13

The extreme Venus surface temperatures ({approx}740 K) and atmospheric pressures ({approx}93 atm) create a challenging environment for surface missions. Scientific investigations capable of Venus geochemical observations must be completed within hours of landing before the lander will be overcome by the harsh atmosphere. A combined remote Raman - LIBS (Laser Induced Breakdown Spectroscopy) instrument is capable of accomplishing the geochemical science goals without the risks associated with collecting samples and bringing them into the lander. Wiens et al. and Sharma et al. demonstrated that both analytical techniques can be integrated into a single instrument capable of planetary missions. The focus of this paper is to explore the capability to probe geologic samples with Raman - LIBS and demonstrate quantitative analysis under Venus surface conditions. Raman and LIBS are highly complementary analytical techniques capable of detecting both the mineralogical and geochemical composition of Venus surface materials. These techniques have the potential to profoundly increase our knowledge of the Venus surface composition, which is currently limited to geochemical data from Soviet Venera and VEGA landers that collectively suggest a surface composition that is primarily tholeiitic basaltic with some potentially more evolved compositions and, in some locations, K-rich trachyandesite. These landers were not equipped to probe the surface mineralogy as can be accomplished with Raman spectroscopy. Based on the observed compositional differences and recognizing the imprecise nature of the existing data, 15 samples were chosen to constitute a Venus-analog suite for this study, including five basalts, two each of andesites, dacites, and sulfates, and single samples of a foidite, trachyandesite, rhyolite, and basaltic trachyandesite under Venus conditions. LIBS data reduction involved generating a partial least squares (PLS) model with a subset of the rock powder standards to

Geochemical modeling of the nuclear-waste repository system. A status report

International Nuclear Information System (INIS)

Deutsch, W.J.

1980-12-01

The primary objective of the geochemical modeling task is to develop an understanding of the waste-repository geochemical system and provide a valuable tool for estimating future states of that system. There currently exists a variety of computer codes which can be used in geochemical modeling studies. Some available codes contain the framework for simulating a natural chemical system and estimating, within limits, the response of that system to environmental changes. By data-base enhancement and code development, this modeling technique can be even more usefully applied to a nuclear-waste repository. In particular, thermodynamic data on elements not presently in the data base but identified as being of particular hazard in the waste-repository system, need to be incorporated into the code to estimate the near-field as well as the far-field reactions during a hypothetical breach. A reaction-path-simulation code, which estimates the products of specific rock/water reactions, has been tested using basalt and ground water. Results show that the mass-transfer capabilities of the code will be useful in chemical-evolution studies and scenario analyses. The purpose of this report is to explain the status of geochemical modeling as it currently applies to the chemical system of a hypothetical nuclear-waste repository in basalt and to present the plan proposed for further developmet and application

Use of natural geochemical tracers to improve reservoir simulation models

Energy Technology Data Exchange (ETDEWEB)

Huseby, O.; Chatzichristos, C.; Sagen, J.; Muller, J.; Kleven, R.; Bennett, B.; Larter, S.; Stubos, A.K.; Adler, P.M.

2005-01-01

This article introduces a methodology for integrating geochemical data in reservoir simulations to improve hydrocarbon reservoir models. The method exploits routine measurements of naturally existing inorganic ion concentration in hydrocarbon reservoir production wells, and uses the ions as non-partitioning water tracers. The methodology is demonstrated on a North Sea field case, using the field's reservoir model, together with geochemical information (SO{sub 4}{sup 2}, Mg{sup 2+} K{sup +}, Ba{sup 2+}, Sr{sup 2+}, Ca{sup 2+}, Cl{sup -} concentrations) from the field's producers. From the data-set we show that some of the ions behave almost as ideal sea-water tracers, i.e. without sorption to the matrix, ion-exchange with the matrix or scale-formation with other ions in the formation water. Moreover, the dataset shows that ion concentrations in pure formation-water vary according to formation. This information can be used to allocate produced water to specific water-producing zones in commingled production. Based on an evaluation of the applicability of the available data, one inorganic component, SO{sub 4}{sup 2}, is used as a natural seawater tracer. Introducing SO{sub 4}{sup 2} as a natural tracer in a tracer simulation has revealed a potential for improvements of the reservoir model. By tracking the injected seawater it was possible to identify underestimated fault lengths in the reservoir model. The demonstration confirms that geochemical data are valuable additional information for reservoir characterization, and shows that integration of geochemical data into reservoir simulation procedures can improve reservoir simulation models. (author)

Using geoelectrochemical technique to extract uranium and other metals

International Nuclear Information System (INIS)

Gao Yulong

1990-10-01

The geoelectrochemical extraction technique, which is a direct deep exploring method, is one of the geoelectrochemical exploring methods. It is developed recently to explore basic metals, precious metals, rare metals and some nonmetal mineral products. It is also a combination of electrical surveying and geochemical surveying. This method is more useful in the seeking of gold ore deposit. The principle and technique of this method and the results in seeking gold, uranium, lead, nickel and tin ore deposits are introduced. The equipment and instruments used in this method are also given

Geophysical Exploration. New site exploration method

Energy Technology Data Exchange (ETDEWEB)

Imai, Tsuneo; Otomo, Hideo; Sakayama, Toshihiko

1988-07-25

Geophysical exploration is used for geologic survey to serve purposes in civil engineering. New methods are being developed inside and outside Japan and are used to serve various purposes. This paper discusses recently developed techniques based on the measurement of seismic waves and electric potential. It also explains seismic tomography, radar tomography, and resistivity tomography which are included in the category of geotomography. At present, effort is being made to apply geophysical exploration technology to problems which were considered to be unsuitable for conventional exploration techniques. When such effort proceeds successfully, it is necessary to develop technology for presenting results quickly and exploration equipment which can work in various conditions. (10 figs, 15 refs)

Estimation of Supraglacial Dust and Debris Geochemical Composition via Satellite Reflectance and Emissivity

Science.gov (United States)

Casey, Kimberly Ann; Kaab, Andreas

2012-01-01

We demonstrate spectral estimation of supraglacial dust, debris, ash and tephra geochemical composition from glaciers and ice fields in Iceland, Nepal, New Zealand and Switzerland. Surface glacier material was collected and analyzed via X-ray fluorescence spectroscopy (XRF) and X-ray diffraction (XRD) for geochemical composition and mineralogy. In situ data was used as ground truth for comparison with satellite derived geochemical results. Supraglacial debris spectral response patterns and emissivity-derived silica weight percent are presented. Qualitative spectral response patterns agreed well with XRF elemental abundances. Quantitative emissivity estimates of supraglacial SiO2 in continental areas were 67% (Switzerland) and 68% (Nepal), while volcanic supraglacial SiO2 averages were 58% (Iceland) and 56% (New Zealand), yielding general agreement. Ablation season supraglacial temperature variation due to differing dust and debris type and coverage was also investigated, with surface debris temperatures ranging from 5.9 to 26.6 C in the study regions. Applications of the supraglacial geochemical reflective and emissive characterization methods include glacier areal extent mapping, debris source identification, glacier kinematics and glacier energy balance considerations.

Estimation of Supraglacial Dust and Debris Geochemical Composition via Satellite Reflectance and Emissivity

Directory of Open Access Journals (Sweden)

Kimberly Casey

2012-09-01

Full Text Available We demonstrate spectral estimation of supraglacial dust, debris, ash and tephra geochemical composition from glaciers and ice fields in Iceland, Nepal, New Zealand and Switzerland. Surface glacier material was collected and analyzed via X-ray fluorescence spectroscopy (XRF and X-ray diffraction (XRD for geochemical composition and mineralogy. In situ data was used as ground truth for comparison with satellite derived geochemical results. Supraglacial debris spectral response patterns and emissivity-derived silica weight percent are presented. Qualitative spectral response patterns agreed well with XRF elemental abundances. Quantitative emissivity estimates of supraglacial SiO2 in continental areas were 67% (Switzerland and 68% (Nepal, while volcanic supraglacial SiO2 averages were 58% (Iceland and 56% (New Zealand, yielding general agreement. Ablation season supraglacial temperature variation due to differing dust and debris type and coverage was also investigated, with surface debris temperatures ranging from 5.9 to 26.6 C in the study regions. Applications of the supraglacial geochemical reflective and emissive characterization methods include glacier areal extent mapping, debris source identification, glacier kinematics and glacier energy balance considerations.

Geochemical characteristics of peat from two raised bogs of Germany

Science.gov (United States)

Mezhibor, A. M.

2016-11-01

Peat has a wide range of applications in different spheres of human activity, and this is a reason for a comprehensive study. This research represents the results of an ICP-MS study of moss and peat samples from two raised bogs of Germany. Because of the wide use of sphagnum moss and peat, determining their geochemical characteristics is an important issue. According to the results obtained, we can resume that the moss samples from Germany are rich in Cu, As, Y, Zr, Nb, and REE. The geochemical composition of the bogs reflects the regional environmental features and anthropogenic influence.

Investigations in hydrogeochemical samples for uranium exploration

International Nuclear Information System (INIS)

Krishnakumar, M.

2015-01-01

The primary mandate of Atomic Minerals Directorate for Exploration and Research (AMD) is to explore and establish the uranium and other atomic mineral resources required for the country's nuclear power programme. During the geochemical exploration, a large number of ground, surface, spring, stream and lake water samples are collected and analysed for various parameters. These include physical parameters such as temperature, pH, Eh, electrical conductivity etc., and concentrations of uranium and multi-ions at mg/L to ng/L using state-of-the-art instrumental analytical techniques. Hydrogeochemical analysis is considered to be a cost effective and rapid exploration tool for getting sub-surface information leading to finding of concealed uranium deposits. Water samples from a bore well, dug well, stream, spring which is in dynamic equilibrium with the rocks are collected in a white, thick walled, non-transparent, non-recycled and air-tight container, stored and analysed within eight hours if possible to avoid change in Eh-pH conditions and precipitation-dissolution of trace elements

Geochemical interpretation of gamma-ray spectrometry images from the Achala granite (Cordoba, Argentina)

International Nuclear Information System (INIS)

Lopez, Luis E.

1998-01-01

Data of an old spectrometry gamma-ray survey carried out in the Sierras Pampeanas Range by the National Atomic Energy Commission (Argentina) were reprocessed to obtain a corrected digital archive. The geochemical interpretation of the 250 x 250 meters spectrometric grids from the Achala batholith area was based on the behaviour of the radioelements in a peraluminous magma. Spectrometric maps of potassium, uranium, thorium and their ratios were used. In particular, the Th grid was very useful to define the primary magmatic evolution of the granitoids. K and U correlate roughly with Th distribution. The observed positive correlation between Th and U is thought to be the result of surficial leaching of U from uraninite. Finally, U/Th ratio allows to determine both, the magmatic evolution of the rocks and the mineral phase responsible for U content. (author)

Geochemical variations during the 2012 Emilia seismic sequence

Science.gov (United States)

Sciarra, Alessandra; Cantucci, Barbara; Galli, Gianfranco; Cinti, Daniele; Pizzino, Luca

2015-04-01

Several geochemical surveys (soil gas and shallow water) were performed in the Modena province (Massa Finalese, Finale Emilia, Medolla and S. Felice sul Panaro), during 2006-2014 period. In May-June 2012, a seismic sequence (main shocks of ML 5.9 and 5.8) was occurred closely to the investigated area. In this area 300 CO2 and CH4 fluxes measurements, 150 soil gas concentrations (He, H2, CO2, CH4 and C2H6), 30 shallow waters and their isotopic analyses (δ13C- CH4, δD- CH4 and δ13C- CO2) were performed in April-May 2006, October and December 2008, repeated in May and September 2012, June 2013 and July 2014 afterwards the 2012 Emilia seismic sequences. Chemical composition of soil gas are dominated by CH4 in the southern part by CO2 in the northern part. Very anomalous fluxes and concentrations are recorded in spot areas; elsewhere CO2 and CH4 values are very low, within the typical range of vegetative and of organic exhalation of the cultivated soil. After the seismic sequence the CH4 and CO2 fluxes are increased of one order of magnitude in the spotty areas, whereas in the surrounding area the values are within the background. On the contrary, CH4 concentration decrease (40%v/v in the 2012 surveys) and CO2 concentration increase until to 12.7%v/v (2013 survey). Isotopic gas analysis were carried out only on samples with anomalous values. Pre-seismic data hint a thermogenic origin of CH4 probably linked to leakage from a deep source in the Medolla area. Conversely, 2012/2013 isotopic data indicate a typical biogenic origin (i.e. microbial hydrocarbon production) of the CH4, as recognized elsewhere in the Po Plain and surroundings. The δ13C-CO2 value suggests a prevalent shallow origin of CO2 (i.e. organic and/or soil-derived) probably related to anaerobic oxidation of heavy hydrocarbons. Water samples, collected from domestic, industrial and hydrocarbons exploration wells, allowed us to recognize different families of waters. Waters are meteoric in origin and

Basic concepts and formulations for isotope geochemical modelling of groundwater systems

International Nuclear Information System (INIS)

Kalin, R.M.

1996-01-01

This chapter describes the basic chemical principles and methodologies for geochemical models and their use in the field of isotope hydrology. Examples of calculation procedures are given on actual field data. Summary information on available PC software for geochemical modeling is included. The specific software, NETPATH, which can be used for chemical speciation, mass balance and isotope balance along a flow path in groundwater systems, is discussed at some length with an illustrative example of its application to field data. (author). Refs, 14 figs, 15 tabs

Basic concepts and formulations for isotope geochemical modelling of groundwater systems

Energy Technology Data Exchange (ETDEWEB)

Kalin, R M [The Queen` s University, Belfast, Northern Ireland (United Kingdom). Dept. of Civil Engineering

1996-10-01

This chapter describes the basic chemical principles and methodologies for geochemical models and their use in the field of isotope hydrology. Examples of calculation procedures are given on actual field data. Summary information on available PC software for geochemical modeling is included. The specific software, NETPATH, which can be used for chemical speciation, mass balance and isotope balance along a flow path in groundwater systems, is discussed at some length with an illustrative example of its application to field data. (author). Refs, 14 figs, 15 tabs.

The Role of Geochemistry and Basin Modelling in the Exploration of Mature province

International Nuclear Information System (INIS)

Katz, A.J.

2002-01-01

Petroleum geochemistry and basin modelling has been an important tool in the reduction of risks in poorly explored basins. Historically the role of geochemistry is usually reduced once production is established and often in mature province is nonexistent. However, attempts to add reserves in mature provinces require an expansion of exploration programs based on new play concepts. Consequently, there is a clear role for geochemistry and basin modelling as this revitalization occurs.These new basin modelling and geochemical programs are aimed at answering three questions: . Can the petroleum system be extended? . Is a change in hydrocarbon character to be expected? . How much hydrocarbon potential remains?Unlike frontier exploration a significant sample base is normally available that can be used to more effectively constrain interpretations. Such programs have clearly aided exploration in the Niger Delta. For example, the collection of an extensive piston core dataset in conjunction with a basin modelling program provided strong support for the Niger Delta's petroleum system extending into deep water areas. While the geochemical character of the oils established the presence of multiple effective generative systems, each of which has different source characteristics and often-different ages. This information constraints model construction and hydrocarbon volume estimates. Oil data also established the importance of phase segregation. The presence of fractionated oils and maturation modelling results provides evidence for deeper hydrocarbon potential within the geographic limits of established hydrocarbon pays

Modeling the geochemical distribution of rare earth elements (REEs using multivariate statistics in the eastern part of Marvast placer, the Yazd province

Directory of Open Access Journals (Sweden)

Amin Hossein Morshedy

2017-07-01

, H. and Milodowski, A.E., 2012. Occurrence and paragenesis of diagenetic monazite in the upper Triassic black shales of the Marvast region, South Yazd, Iran. Mineralogy and Petrology, 104(3-4: 197-210. Castor, S.B. and Hedrick, J.B., 2006. Rare earth elements. In: J.E. Kogel (Editors, Industrial minerals & rocks: commodities, markets, and uses. Society for mining, metallurgy, and exploration, Inc. (SME, Colorado, pp. 769-792. Everitt, B., Landau, S., Leese, M. and Stahl, D., 2011. Cluster Analysis. 5th ed., Wiley Publishing, Hoboken, Geological Survey of Iran (GSI, 2004. Exploration of rare earth element and monazite in the alluvium of the southern Marvast (eastern area. Tehran, 66 pp. (in Persian Ghorbani, M., 2013. The economic geology of Iran: mineral deposits and natural resources. Springer, London, 569 pp. Jain, A.K., Murty, M.N. and Flynn, P.J., 1999. Data clustering: a review. Association for Computing Machinery computing surveys, 31(3: 264-323. Jaireth, S., Hoatson D.M. and Miezitis Y., 2014. Geological setting and resources of the major rare-earth-element deposits in Australia. Ore Geology Reviews, 62: 72-128. Ji, H., Zeng, D., Shi, Y., Wu, Y. and Wu, X., 2007. Semi-hierarchical correspondence cluster analysis and regional geochemical pattern recognition. Journal of Geochemical Exploration, 93(2: 109-119.

Some methodical questions of study of vertical geochemical zoning of ore deposits

International Nuclear Information System (INIS)

Sochevanov, N.N.; Gorelova, E.K.

1975-01-01

Taking a hydrothermal uranium deposit as an example, the advisability of dividing ore-localizing structures (for the purpose of making a calculation for a single geochemical zonality) into five zones, a supra-, an upper, a central, a lower and an infra-ore one, has been shown. It is recommended to determine the place of elements in the geochemical zonality sequence by taking into account the productivity of their aureoles and the location of the centre of gravity of their reserves in the ore, supra- and infra-ore horizons. When considering the peculiarities of a zonality, it is irrational to take account of elements determined with an insufficient sensitivity as well as of low-contrast or unstable ones. When calculating tracer ratios the most contrasting data can be obtained by using the most distant elements in the geochemical zonality sequence

75 FR 16830 - Geological and Geophysical Exploration (G&G) on the Mid- and South Atlantic Outer Continental...

Science.gov (United States)

2010-04-02

... DEPARTMENT OF THE INTERIOR Minerals Management Service Geological and Geophysical Exploration (G&G..., geological and geochemical sampling, and remote sensing. These activities could support siting needs for... Continental Shelf (see http://www.mms.gov/ld/PDFs/GreenBook-LeasingDocument.pdf ) and MMS's Geological and...

FY 1993 report on the survey of geothermal development promotion. Survey of geothermal water (No.36 - Amemasu-dake area); 1993 nendo chinetsu kaihatsu sokushin chosa. Nessui no chosa hokokusho (No.36 Amemasu dake chiiki)

Energy Technology Data Exchange (ETDEWEB)

NONE

1995-01-01

As a part of the survey of geothermal development promotion in FY 1993, survey of geothermal fluid was made using a precise structure drilling well N5-AM-5 as exploration well in the Amemasu-dake area, Hokkaido. The induced jetting of geothermal fluid was carried out by the Swabbing method in the total number of times of 185 in 11 days at 10-20 times/day, but did not result in the jetting of geothermal water. The sampling of geothermal water was conducted by guiding the geothermal water that overflowed the guide pipe to the tank. The temperature of geothermal water indicated approximately 20 degrees C in the 1st time and 40-60 degrees C in and after the 2nd time every day. The electric conductivity of geothermal water was 2.033 mS/cm, chlorine ion concentration was 420-500 ppm, and pH value was 7.17-7.72. As a result of the survey, it was presumed that the geothermal water of this well originated in the meteoric water around the area and formed slightly supported by emitted volcanic matters. As to the geochemical temperature, the silica temperature indicated about 120 degrees C and the alkali ratio temperature did about 180 degrees C. It was considered that there possibly existed geothermal reservoirs of approximately 180 degrees C in alkali ratio temperature around the well. (NEDO)

Geochemical studies in Alaska by the U.S. geological survey, 1989

International Nuclear Information System (INIS)

Goldfarb, R.J.; Nash, J.T.; Stoeser, J.W.

1990-01-01

This book contains six papers concerned with exploration geochemistry, and stable isotope and trace element chemistry of metallic ore deposits in Alaska. Application of geostatistical techniques to the National Uranium Resource Evaluation (NURE) program stream-sediment data allows to target new areas of southeastern Alaska that are favorable for Greens Creek-type volcanogenic massive sulfide (VMS) deposits

The application of integrated geophysical methods composed of AMT and high-precision ground magnetic survey to the exploration of granite uranium deposits

International Nuclear Information System (INIS)

Qiao Yong; Shen Jingbang; Wu Yong; Wang Zexia

2014-01-01

Introduced two methods composed of AMT and high-precision ground magnetic survey were used to the exploration of granite uranium deposits in the Yin gongshan areas middle part of the Nei Monggol. Through experiment of methods and analysis of applicated results, think that AMT have good vertical resolution and could preferably survey thickness of rockmass, position of fracture and deep conditions, space distribution features of fracture zone ect, but it is not clear for rockmass, xenolith of reflection. And high-precision ground magnetic survey could delineate rockmass, xenolith of distribution range and identify the rock contact zone, fracture ect, but it generally measure position and it is not clear for occurrence, extension. That can resolve some geological structures by using the integrated methods and on the basis of sharing their complementary advantages. Effective technological measures are provided to the exploration of deep buried uranium bodies in the granite uranium deposits and outskirt extension of the deposit. (authors)

Geochemical characterization of the siliciclastic rocks of Chitravati ...

Indian Academy of Sciences (India)

V Somasekhar

2018-05-23

May 23, 2018 ... Chitravati Group of Cuddapah Supergroup to decipher the provenance and depositional environment. Both the units ... Based on major element geochemical classification diagram, Pulivendla Quartzite .... The youngest age limit of the Nallamalai ...... eastern Oregon and western Idaho, USA: Implications for.

Uruguay Mining inventory. Florida fotoplano geochemical prospecting results

International Nuclear Information System (INIS)

Zeegers, H.; Artignan, D.; Vairon, P.

1982-01-01

This work is about the geochemical prospecting carried out in Florida fotoplano within the framework of Uruguay Mining inventory. In this work were covered 660 km2 obtaining 752 samples for study which were analyzed by Plasma Emission Spectrometry in Orleans BRGM laboratories

Geochemical porosity values obtained in core samples from different clay-rocks

International Nuclear Information System (INIS)

Fernandez, A.M.

2010-01-01

Document available in extended abstract form only. Argillaceous formations of low permeability are considered in many countries as potential host rocks for the disposal of high level radioactive wastes (HLRW). In order to determine their suitability for waste disposal, evaluations of the hydro-geochemistry and transport mechanisms from such geologic formations to the biosphere must be undertaken. One of the key questions about radionuclide diffusion and retention is to know the chemistry and chemical reactions and sorption processes that will occur in the rock and their effects on radionuclide mobility. In this context, the knowledge of the pore water chemistry is essential for performance assessment purposes. This information allows to establish a reliable model for the main water-rock interactions, which control the physico-chemical parameters and the chemistry of the major elements of the system. An important issue in order to model the pore water chemistry in clayey media is to determine the respective volume accessible to cations and anions, i.e, the amount of water actually available for chemical reactions/solute transport. This amount is usually referred as accessible porosity or geochemical porosity. By using the anion inventories, i.e. the anion content obtained from aqueous leaching, and assuming that all Cl - , Br - and SO4 2- leached in the aqueous extracts originates from pore water, the concentration of a conservative ion can be converted into the real pore water concentration if the accessible porosity is known. In this work, the accessible porosity or geochemical porosity has been determined in core samples belonging to four different formations: Boom Clay from Hades URL (Belgium, BE), Opalinus Clay from Mont Terri (Switzerland, CH), and Callovo-Oxfordian argillite from Bure URL (France, FR). The geochemical or chloride porosity was defined as the ratio between the pore water volume containing Cl-bearing pore water and the total volume of a sample

Analysis on geochemical conditions of uranium mineralization in Bashibulake uranium deposit, Xinjiang

International Nuclear Information System (INIS)

Liu Zhangyue; Dong Wenming; Cai Genqing; Liu Hongxu; Deng Huabo

2011-01-01

By studying the palaeoclimate and metallogenesis related geochemical indexes, this paper proposes that the hosting rocks should form in geochemical oxidation setting under arid palaeoclimate. The study on element assemblage associated with uranium mineralization indicates that the target hosting rocks suffered from different degrees of reworking of reducing fluid at first and then being superimposed by supergene oxidative fluid at tectonic uplifting stage. The uranium mineralization is located in reworked and superimposed places of two types of fluid. (authors)

Manual for the application of NURE 1974--1977 aerial gamma-ray spectrometer data

International Nuclear Information System (INIS)

Saunders, D.F.; Potts, M.J.

1977-09-01

This manual was prepared as an aid to those interested in the interpretation and application of high-sensitivity aerial gamma-ray spectrometer data in uranium exploration. Particular emphasis is on the first 10 radiometric surveys performed under the National Uranium Resource Evaluation (NURE) program. The primary purpose of aerial gamma-ray spectrometer surveys in the NURE program is to map regional distributions of near-surface natural radioelements, i.e., the uranium and thorium decay series, and potassium-40. These data along with an understanding of the geochemical behavior of the pertinent isotopes under a variety of conditions allow uranium-enriched areas of the earth's crust (uraniferous provinces) to be identified as part of the regional appraisal phase of prospecting. Uranium ore deposits tend to occur more frequently in these generally enriched regions than elsewhere, and, consequently, uraniferous provinces constitute preferred territory for follow-up exploration methods such as detailed aerial or surface radiometric prospecting, geological studies, etc., to define potential prospects. These in turn may be investigated by still more detailed surface geological studies perhaps supplemented by radon or uranium geochemical surveys and exploration drilling and logging. This manual outlines the fundamentals of uranium geology and geochemistry along with interpretive approaches which may be used to identify statistically and geochemically significant uranium anomalies and uraniferous provinces. Follow-up prospecting methods are summarized along with guides to recent literature. Specific suggestions are made as to interpretive approaches and applicable follow-up prospecting procedures tailored to fit the data characteristics and general environment of each of the first 10 NURE aerial gamma-ray spectrometer surveys performed by Geodata International, Inc. and Texas Instruments Incorporated

The geochemical chararateristics of the marble deposits east of ...

African Journals Online (AJOL)

), marbles were investigated with the view to establishing marble occurrences and their geochemical characteristics. Crystalline rocks of the Nigerian Basement Complex (migmatite – gneiss complex) underlie the area. Ten marble bodies were ...

Interface Induced Carbonate Mineralization: A Fundamental Geochemical Process Relevant to Carbon Sequestration

Energy Technology Data Exchange (ETDEWEB)

Teng, H. Henry [PI, The George Washington University; Xu, Huifang [Co-PI, University of Wisconsin-Madison

2013-07-17

We have approached the long-standing geochemical question why anhydrous high-Mg carbonate minerals (i.e., magnesite and dolomite) cannot be formed at ambient conditions from a new perspective by exploring the formation of MgCO{sub 3} and Mg{sub x}Ca{sub (1-x)}CO{sub 3} in non-aqueous solutions. Data collected from our experiments in this funding period suggest that a fundamental barrier, other than cation hydration, exists that prevents Mg{sup 2+} and CO{sub 3}{sup 2-} ions from forming long-range ordered structures. We propose that this barrier mainly stems from the lattice limitation on the spatial configuration of CO{sub 3} groups in magnesite crystals. On the other hand, the measured higher distribution coefficients of Mg between magnesian calcites formed in the absence and presence of water give us a first direct proof to support and quantify the cation hydration effect.

Comparison of thermodynamic databases used in geochemical modelling

International Nuclear Information System (INIS)

Chandratillake, M.R.; Newton, G.W.A.; Robinson, V.J.

1988-05-01

Four thermodynamic databases used by European groups for geochemical modelling have been compared. Thermodynamic data for both aqueous species and solid species have been listed. When the values are directly comparable any differences between them have been highlighted at two levels of significance. (author)

Uruguay Mining inventory. Minas fotoplano geochemical prospecting results

International Nuclear Information System (INIS)

Zeegers, H.; Artignan, D.; Vairon, P.

1982-01-01

This work is about the geochemical prospecting carried out in Minas fotoplano within the framework of Uruguay Mining inventory. In this work were covered 380 km2 obtaining with 433 samples for study which were analized by Plasma Emission Spectrometry in Orleans BRGM laboratories

Nuclear-fuel-cycle education: Module 2. Exploration, reserve estimation, mining, milling, conversion, and properties of uranium

International Nuclear Information System (INIS)

Brookins, D.G.

1981-12-01

In this module geological and geochemical data pertinent to locating, mining, and milling of uranium are examined. Chapters are devoted to: uranium source characteristics; uranium ore exploration methods; uranium reserve estimation for sandstone deposits; mining; milling; conversion processes for uranium; and properties of uranium, thorium, plutonium and their oxides and carbides

Geochemical orientation survey of stream sediment, stream water, and ground water near uranium prospects, Monticello area, New York. National Uranium Resource Evaluation Program

International Nuclear Information System (INIS)

Rose, A.W.; Smith, A.T.; Wesolowski, D.

1982-08-01

A detailed geochemical test survey has been conducted in a 570 sq km area around six small copper-uranium prospects in sandstones of the Devonian Catskill Formation near Monticello in southern New York state. This report summarizes and interprets the data for about 500 stream sediment samples, 500 stream water samples, and 500 ground water samples, each analyzed for 40 to 50 elements. The groundwater samples furnish distinctive anomalies for uranium, helium, radon, and copper near the mineralized localities, but the samples must be segregated into aquifers in order to obtain continuous well-defined anomalies. Two zones of uranium-rich water (1 to 16 parts per billion) can be recognized on cross sections; the upper zone extends through the known occurrences. The anomalies in uranium and helium are strongest in the deeper parts of the aquifers and are diluted in samples from shallow wells. In stream water, copper and uranium are slightly anomalous, as in an ore factor derived from factor analysis. Ratios of copper, uranium, and zinc to conductivity improve the resolution of anomalies. In stream sediment, extractable uranium, copper, niobium, vanadium, and an ore factor furnish weak anomalies, and ratios of uranium and copper to zinc improve the definition of anomalies. The uranium/thorium ratio is not helpful. Published analyses of rock samples from the nearby stratigraphic section show distinct anomalies in the zone containing the copper-uranium occurrences. This report is being issued without the normal detailed technical and copy editing, to make the data available to the public before the end of the National Uranium Reconnaissance Evaluation program

Geochemical orientation survey of stream sediment, stream water, and ground water near uranium prospects, Monticello area, New York. National Uranium Resource Evaluation Program

Energy Technology Data Exchange (ETDEWEB)

Rose, A. W.; Smith, A. T.; Wesolowski, D.

1982-08-01

A detailed geochemical test survey has been conducted in a 570 sq km area around six small copper-uranium prospects in sandstones of the Devonian Catskill Formation near Monticello in southern New York state. This report summarizes and interprets the data for about 500 stream sediment samples, 500 stream water samples, and 500 ground water samples, each analyzed for 40 to 50 elements. The groundwater samples furnish distinctive anomalies for uranium, helium, radon, and copper near the mineralized localities, but the samples must be segregated into aquifers in order to obtain continuous well-defined anomalies. Two zones of uranium-rich water (1 to 16 parts per billion) can be recognized on cross sections; the upper zone extends through the known occurrences. The anomalies in uranium and helium are strongest in the deeper parts of the aquifers and are diluted in samples from shallow wells. In stream water, copper and uranium are slightly anomalous, as in an ore factor derived from factor analysis. Ratios of copper, uranium, and zinc to conductivity improve the resolution of anomalies. In stream sediment, extractable uranium, copper, niobium, vanadium, and an ore factor furnish weak anomalies, and ratios of uranium and copper to zinc improve the definition of anomalies. The uranium/thorium ratio is not helpful. Published analyses of rock samples from the nearby stratigraphic section show distinct anomalies in the zone containing the copper-uranium occurrences. This report is being issued without the normal detailed technical and copy editing, to make the data available to the public before the end of the National Uranium Reconnaissance Evaluation program.

Snowmelt induced hydrologic perturbations drive dynamic microbiological and geochemical behaviors across a shallow riparian aquifer

Directory of Open Access Journals (Sweden)

Robert eDanczak

2016-05-01

Full Text Available Shallow riparian aquifers represent hotspots of biogeochemical activity in the arid western US. While these environments provide extensive ecosystem services, little is known of how natural environmental perturbations influence subsurface microbial communities and associated biogeochemical processes. Over a six-month period we tracked the annual snowmelt-driven incursion of groundwater into the vadose zone of an aquifer adjacent to the Colorado River, leading to increased dissolved oxygen (DO concentrations in the normally suboxic saturated zone. Strong biogeochemical heterogeneity was measured across the site, with abiotic reactions between DO and sulfide minerals driving rapid DO consumption and mobilization of redox active species in reduced aquifer regions. Conversely, extensive DO increases were detected in less reduced sediments. 16S rRNA gene surveys tracked microbial community composition within the aquifer, revealing strong correlations between increases in putative oxygen-utilizing chemolithoautotrophs and heterotrophs and rising DO concentrations. The gradual return to suboxic aquifer conditions favored increasing abundances of 16S rRNA sequences matching members of the Microgenomates (OP11 and Parcubacteria (OD1 that have been strongly implicated in fermentative processes. Microbial community stability measurements indicated that deeper aquifer locations were relatively less affected by geochemical perturbations, while communities in shallower locations exhibited the greatest change. Reactive transport modeling of the geochemical and microbiological results supported field observations, suggesting that a predictive framework can be applied to develop a greater understanding of such environments.

Snowmelt induced hydrologic perturbations drive dynamic microbiological and geochemical behaviors across a shallow riparian aquifer

Science.gov (United States)

Danczak, Robert; Yabusaki, Steven; Williams, Kenneth; Fang, Yilin; Hobson, Chad; Wilkins, Michael

2016-05-01

Shallow riparian aquifers represent hotspots of biogeochemical activity in the arid western US. While these environments provide extensive ecosystem services, little is known of how natural environmental perturbations influence subsurface microbial communities and associated biogeochemical processes. Over a six-month period we tracked the annual snowmelt-driven incursion of groundwater into the vadose zone of an aquifer adjacent to the Colorado River, leading to increased dissolved oxygen (DO) concentrations in the normally suboxic saturated zone. Strong biogeochemical heterogeneity was measured across the site, with abiotic reactions between DO and sulfide minerals driving rapid DO consumption and mobilization of redox active species in reduced aquifer regions. Conversely, extensive DO increases were detected in less reduced sediments. 16S rRNA gene surveys tracked microbial community composition within the aquifer, revealing strong correlations between increases in putative oxygen-utilizing chemolithoautotrophs and heterotrophs and rising DO concentrations. The gradual return to suboxic aquifer conditions favored increasing abundances of 16S rRNA sequences matching members of the Microgenomates (OP11) and Parcubacteria (OD1) that have been strongly implicated in fermentative processes. Microbial community stability measurements indicated that deeper aquifer locations were relatively less affected by geochemical perturbations, while communities in shallower locations exhibited the greatest change. Reactive transport modeling of the geochemical and microbiological results supported field observations, suggesting that a predictive framework can be applied to develop a greater understanding of such environments.

Coupling between a geochemical model and a transport model of dissolved elements

International Nuclear Information System (INIS)

Jacquier, P.

1988-10-01

In order to assess the safety analysis of an underground repository, the transport of radioelements in groundwater and their interactions with the geological medium are modelled. The objective of this work is the setting up and experimental validation of the coupling of a geochemical model with a transport model of dissolved elements. A laboratory experiment was developed at the CEA center of Cadarache. Flow-through experiments were carried out on columns filled with crushed limestone, where several inflow conditions were taken into account as the temperature, the presence of a pollutant (strontium chloride) at different concentrations. The results consist of the evolution of the chemical composition of the water at the outlet of the column. The final aim of the study is to explain these results with a coupled model where geochemical and transport phenomena are modelled in a two-step procedure. This code, called STELE, was built by introducing a geochemical code, CHIMERE, into an existing transport code, METIS. At this stage, the code CHIMERE can take into account: any chemical reaction in aqueous phase (complexation, acid-base reaction, redox equilibrium), dissolution-precipitation of minerals and solid phases, dissolution-degassing of gas. The paper intends to describe the whole process leading to the coupling which can be forecasted over the next years between geochemical and transport models

Establishing geochemical background levels of selected trace elements in areas having geochemical anomalies: The case study of the Orbetello lagoon (Tuscany, Italy)

International Nuclear Information System (INIS)

Romano, Elena; Bergamin, Luisa; Croudace, Ian W.; Ausili, Antonella; Maggi, Chiara; Gabellini, Massimo

2015-01-01

The determination of background concentration values (BGVs) in areas, characterised by the presence of natural geochemical anomalies and anthropogenic impact, appears essential for a correct pollution assessment. For this purpose, it is necessary to establish a reliable method for determination of local BGVs. The case of the Orbetello lagoon, a geologically complex area characterized by Tertiary volcanism, is illustrated. The vertical concentration profiles of As, Cd, Cr, Cu, Hg, Ni, Pb and Zn were studied in four sediment cores. Local BGVs were determined considering exclusively samples not affected by anthropogenic influence, recognized by means of multivariate statistics and radiochronological dating ( 137 Cs and 210 Pb). Results showed BGVs well-comparable with mean crustal or shale values for most of the considered elements except for Hg (0.87 mg/kg d.w.) and As (16.87 mg/kg d.w.), due to mineralization present in the catchment basin draining into the lagoon. - Highlights: • Pollution assessment in areas with geochemical anomalies needs local reference values. • A new method for the determination of background values (BGV) was established. • Geochemical data from unpolluted samples of sediment cores were used. • Statistics and geochronology were applied to recognize unpolluted sediments. • Anthropogenically influenced samples were not considered for BGV determination. - A method including multivariate statistics and radiochronological dating is proposed for determining local background values for trace elements using analytical data form sediment cores

Identifying high-grade uranium deposits in the Proterozoic basins of India- a challenge to exploration

International Nuclear Information System (INIS)

Mahadevan, T.M.

1995-01-01

The favorability factors that bestow on the Proterozoic formation of India, a potential to host high grade uranium deposits are discussed in the light of the known features of the new class of unconformity- related and strata bound uranium deposits. The need to reorient several past approaches is emphasised and it is suggested that future programmes must avail of the constraining benefits of a spectrum of geophysical, geochemical, and sedimentological studies in the choice of target areas for detailed exploration and development. A synthesis of geological and geochemical data with such geophysical features as magnetic and gravity anomalies, velocity structure, seismic reflectivity, electrical conductivity, and radioactivity can effectively lead to relatively more favourable exploration targets. Such efforts may lead to the generation of more than one model of the deep basinal features, which then provide wider options for drilling and proving of ore bodies. The alternative to the above approach is saturation drilling, which is a costly and time-consuming process and, therefore, very often self-defeating. (author). 28 refs., 2 figs., 2 tabs

Exploration of Global Trend on Biomedical Application of Polyhydroxyalkanoate (PHA): A Patent Survey.

Science.gov (United States)

Ponnaiah, Paulraj; Vnoothenei, Nagiah; Chandramohan, Muruganandham; Thevarkattil, Mohamed Javad Pazhayakath

2018-01-30

Polyhydroxyalkanoates are bio-based, biodegradable naturally occurring polymers produced by a wide range of organisms, from bacteria to higher mammals. The properties and biocompatibility of PHA make it possible for a wide spectrum of applications. In this context, we analyze the potential applications of PHA in biomedical science by exploring the global trend through the patent survey. The survey suggests that PHA is an attractive candidate in such a way that their applications are widely distributed in the medical industry, drug delivery system, dental material, tissue engineering, packaging material as well as other useful products. In our present study, we explored patents associated with various biomedical applications of polyhydroxyalkanoates. Patent databases of European Patent Office, United States Patent and Trademark Office and World Intellectual Property Organization were mined. We developed an intensive exploration approach to eliminate overlapping patents and sort out significant patents. We demarcated the keywords and search criterions and established search patterns for the database request. We retrieved documents within the recent 6 years, 2010 to 2016 and sort out the collected data stepwise to gather the most appropriate documents in patent families for further scrutiny. By this approach, we retrieved 23,368 patent documents from all the three databases and the patent titles were further analyzed for the relevance of polyhydroxyalkanoates in biomedical applications. This ensued in the documentation of approximately 226 significant patents associated with biomedical applications of polyhydroxyalkanoates and the information was classified into six major groups. Polyhydroxyalkanoates has been patented in such a way that their applications are widely distributed in the medical industry, drug delivery system, dental material, tissue engineering, packaging material as well as other useful products. There are many avenues through which PHA & PHB could be

Mineralogical and geochemical studies of phosphorite nodules in ...

African Journals Online (AJOL)

Mineralogical and geochemical studies of phosphorite nodules in the Dange Formation Sokoto Basin, Northwestern Niveria. OA Adekeye, SO Akande. Abstract. No Abstract Available Journal of Mining and Geology Vol.40(2) 2004: 101-106. Full Text: EMAIL FULL TEXT EMAIL FULL TEXT · DOWNLOAD FULL TEXT ...

Uranium(VI) transport modeling: geochemical data and submodels

International Nuclear Information System (INIS)

Tripathi, V.S.

1984-01-01

Understanding the geochemical mobility of U(VI) and modeling its transport is important in several contexts including ore genesis, uranium exploration, nuclear and mill-tailings waste management, and solution mining of uranium ores. Adsorption is a major control on partitioning of solutes at the mineral/solution interface. The effect of carbonate, fluoride, and phosphate complexing on adsorption of uranium was investigated. A critical compilation of stability constants of inorganic complexes and solid compounds of U(VI) necessary for proper design of experiment and for modeling transport of uranium was prepared. The general features of U(VI) adsorption in ligand-free systems are similar to those characteristic of other hydrolyzable metal ions. The adsorption processes studied were found to be reversible. The adsorption model developed in ligand-free systems, when solution complexing is taken into account, proved remarkably successful in describing adsorption of uranium in the presence of carbonate and fluoride. The presence of phosphate caused a much smaller decrease in the extent of adsorption than expected; however, a critical reassessment of the stability of UO 2 2+ .HPO 4 2- complexes, showed that phosphato complexes, if any, are extremely weak under experimental conditions. Removal of uranium may have occurred due to precipitation of sodium uranyl phosphates in addition to adsorption

Application of organic-geochemistry, coal-petrology and isotope-geochemistry to facies-analysis and hydrocarbon exploration in the NE-Paris Basin (Trias-Lias Luxemburg)

International Nuclear Information System (INIS)

Flekken, P.M.

1978-01-01

Triassic and Liassic sediments of NE-Paris Basin (Luxemburg) were investigated by organic-geochemical, coal petrographical and isotope-geochemical methods. The objective was to characterize the stratigraphic stages and to investigate the facies relations between them with a view to possible hydrocarbon exploration. The sediments contain an average of 3.1% organic carbon, 413 ug/g extractable organic matter (bitumen) and 0.65% insoluble, isolatable organic particles which constitute part of the kerogen. The non-isolatable kerogen is 2.4% of the whole rock. (orig./BR) [de

Geochemical consequences of the Chernobyl accident.; Geokhimicheskie posledstviya Chernobyl`skoj katastrofy.

Energy Technology Data Exchange (ETDEWEB)

Kopejkin, V A [VNIIGEOLNERUD, Kazan` (Russian Federation)

1994-12-31

Geochemical features of Cs, Sr, U, Pu behaviour in the zone of their hypergenesis are presented in the article. Necessary conditions for these elements filtration on the natural geochemical barriers are shown. Data of radionuclide composition of water for five years of observation in << Ryzhiy Les >> and dissolved forms of radionuclides are described. Geologic and hydrogeologic conditions of the Chernobyl NPP site are shortly characterized. Radionuclide composition in the ground water of contaminated water pools is analyzed. It is proposed to cover by the law all {alpha}-elements (Pu, Am, Np) and not only plutonium as it currently takes place.

PHREEQCI; a graphical user interface for the geochemical computer program PHREEQC

Science.gov (United States)

Charlton, Scott R.; Macklin, Clifford L.; Parkhurst, David L.

1997-01-01

PhreeqcI is a Windows-based graphical user interface for the geochemical computer program PHREEQC. PhreeqcI provides the capability to generate and edit input data files, run simulations, and view text files containing simulation results, all within the framework of a single interface. PHREEQC is a multipurpose geochemical program that can perform speciation, inverse, reaction-path, and 1D advective reaction-transport modeling. Interactive access to all of the capabilities of PHREEQC is available with PhreeqcI. The interface is written in Visual Basic and will run on personal computers under the Windows(3.1), Windows95, and WindowsNT operating systems.

Hydrologic-geochemical modeling needs for nuclear waste disposal systems performance assessments from the NEA perspective

International Nuclear Information System (INIS)

Muller, A.B.

1986-01-01

Credible scenarios for releases from high level nuclear waste repositories require radionuclides to be mobilized and transported by ground water. The capability to predict ground water flow velocities and directions as well as radionuclide concentrations in the flow system as a function of time are essential for assessing the performance of disposal systems. The first of these parameters can be estimated by hydrologic modeling while the concentrations can be predicted by geochemical modeling. The complementary use of empirical and phenomenological approaches to the geochemical modeling, when effectively coupled with hydrologic models can provide the tools needed for realistic performance assessment. An overview of the activities of the NEA in this area, with emphasis on the geochemical data bases (ISIRS for Ksub(d) data and the thermochemical data base critical review), rock/water interaction modeling (code development and short-courses), and hydrologic-geochemical code coupling (workshop and in-house activities) is presented in this paper from the perspective of probabilistic risk assessment needs. (author)

PROMETHEE II: A knowledge-driven method for copper exploration

Science.gov (United States)

Abedi, Maysam; Ali Torabi, S.; Norouzi, Gholam-Hossain; Hamzeh, Mohammad; Elyasi, Gholam-Reza

2012-09-01

This paper describes the application of a well-known Multi Criteria Decision Making (MCDM) technique called Preference Ranking Organization METHod for Enrichment Evaluation (PROMETHEE II) to explore porphyry copper deposits. Various raster-based evidential layers involving geological, geophysical, and geochemical geo-datasets are integrated to prepare a mineral prospectivity mapping (MPM). In a case study, thirteen layers of the Now Chun copper deposit located in the Kerman province of Iran are used to explore the region of interest. The PROMETHEE II technique is applied to produce the desired MPM, and the outputs are validated using twenty-one boreholes that have been classified into five classes. This proposed method shows a high performance when providing the MPM while reducing the cost of exploratory drilling in the study area.

In situ geochemical properties of clays subject to thermal loading

International Nuclear Information System (INIS)

Chapman, N.A.

1980-01-01

Compositional variation and geochemical environment in an argillaceous unit are a function of age, depth of burial and mode of origin. This paper considers the variation limits likely to be encountered in potential repository host rocks and examines the significance of factors such as porosity, pore-fluid pressure, total fluid content, and major and accessory mineral component behaviors in controlling the geochemical environment in the neighbourhood of a thermally active waste canister. Particular attention is paid to the use of Eh-pH diagrams in assessing corrosion environments and nuclide speciation. The paper outlines the variables which must be considered when endeavouring to interpret such plots (e.g. temperature, concentration, concurrent reactions and probabilities) and uses the behavior of various iron minerals found in clay deposits under specific conditions to illustrate the complexities. The overall thermal stability of various clay and accessory minerals is discussed and extended to attempt to predict behavior under deep repository conditions, using available data on the diagenetic characteristics of clay-rich sediments. The physical behavior of fluids in plastic clays is considered and methods evaluated for deriving induced geochemical conditions in a thermally active repository. The latter section is particularly related to canister corrosion studies, in situ experiments, and waste dissolution parameters

Geochemical and Isotopic Interpretations of Groundwater Flow in the Oasis Valley Flow System, Southern Nevada

International Nuclear Information System (INIS)

Thomas, J.M.; Benedict, F.C. Jr.; Rose, T.P.; Hershey, R.L.; Paces, J.B.; Peterman, Z.E.; Farnham, I.M.; Johannesson, K.H.; Singh, A.K.; Stetzenbach, K.J.; Hudson, G.B.; Kenneally, J.M.; Eaton, G.F.; Smith, D.K.

2003-01-01

This report summarizes the findings of a geochemical investigation of the Pahute Mesa-Oasis Valley groundwater flow system in southwestern Nevada. It is intended to provide geochemical data and interpretations in support of flow and contaminant transport modeling for the Western and Central Pahute Mesa Corrective Action Units

Geochemical reactivity of rocks of the Czech Republic

Czech Academy of Sciences Publication Activity Database

Chuman, T.; Gürtlerová, P.; Hruška, Jakub; Adamová, M.

2014-01-01

Roč. 10, č. 2 (2014), s. 341-349 ISSN 1744-5647 R&D Projects: GA MŠk(CZ) ED1.1.00/02.0073 Institutional support: RVO:67179843 Keywords : geochemical reactivity * Czech Republic * susceptibility to weathering Subject RIV: EH - Ecology, Behaviour Impact factor: 1.193, year: 2014

MID-INFRARED SELECTION OF ACTIVE GALACTIC NUCLEI WITH THE WIDE-FIELD INFRARED SURVEY EXPLORER. I. CHARACTERIZING WISE-SELECTED ACTIVE GALACTIC NUCLEI IN COSMOS

International Nuclear Information System (INIS)

Stern, Daniel; Assef, Roberto J.; Eisenhardt, Peter; Benford, Dominic J.; Blain, Andrew; Cutri, Roc; Griffith, Roger L.; Jarrett, T. H.; Masci, Frank; Tsai, Chao-Wei; Yan, Lin; Dey, Arjun; Lake, Sean; Petty, Sara; Wright, E. L.; Stanford, S. A.; Harrison, Fiona; Madsen, Kristin

2012-01-01

The Wide-field Infrared Survey Explorer (WISE) is an extremely capable and efficient black hole finder. We present a simple mid-infrared color criterion, W1 – W2 ≥ 0.8 (i.e., [3.4]–[4.6] ≥0.8, Vega), which identifies 61.9 ± 5.4 active galactic nucleus (AGN) candidates per deg 2 to a depth of W2 ∼ 15.0. This implies a much larger census of luminous AGNs than found by typical wide-area surveys, attributable to the fact that mid-infrared selection identifies both unobscured (type 1) and obscured (type 2) AGNs. Optical and soft X-ray surveys alone are highly biased toward only unobscured AGNs, while this simple WISE selection likely identifies even heavily obscured, Compton-thick AGNs. Using deep, public data in the COSMOS field, we explore the properties of WISE-selected AGN candidates. At the mid-infrared depth considered, 160 μJy at 4.6 μm, this simple criterion identifies 78% of Spitzer mid-infrared AGN candidates according to the criteria of Stern et al. and the reliability is 95%. We explore the demographics, multiwavelength properties and redshift distribution of WISE-selected AGN candidates in the COSMOS field.

Rapid coastal survey of anthropogenic radionuclides, metals, and organic compounds in surficial marine sediments

International Nuclear Information System (INIS)

Noakes, J.E.; Noakes, S.E.; Dvoracek, D.K.; Culp, R.A.; Bush, P.B.

1999-01-01

A towed survey system, the GIMS/CS 3 , has been developed to enable the rapid measurement and mapping of a variety of physical and geochemical parameters in the surficial sediments of aquatic environments while the survey vessel is underway. With its capability for measuring radiometric, elemental and organic compound constituents of sediments, as well as bathymetry and water quality parameters, the GIMS/CS 3 provides a cost-effective means of performing reconnaissance determinations of contaminant distributions and environmental monitoring tasks over broad geographic regions

Haemorrhagic diarrhoea and reproductive failure in Bonsmara cattle resulting from anomalous heavy metal concentrations in soils, forages and drinking water associated with geochemical anomalies of toxic elements on the farm Puntlyf, South Africa

Science.gov (United States)

Elsenbroek, J. H.; Meyer, J.; Myburgh, J.

2003-05-01

Poor livestock health conditions are associated with geochemical Pb anomalies on a farm approximately 40km east of Pretoria, South Africa. A generic risk assessment of drinking water for Bonsmara cattle obtained from three separate subterranean water sources on the farm, revealed the presence of several potentially hazardous constituents suspected for the development of adverse health effects in the herd. The two main symptoms of the herd, namely, severe haemorrhagic diarrhoea in calves and reproductive failure in cows, have been investigated. A selenium-induced copper deficiency was proposed as the main cause to the calf diarrhoea, due to complexing between high concentrations of Se, Mo, Hg and Pb in drinking water. It was also anticipated that such Cu deficiencies would lead to low systemic Se inducing hypothyroidism in the cows due to inadequate iodine activation required for thyroid hormone formation and consequently adversely affect reproduction. The anomalous Pb in borehole drinking water on the southem part of the farm, suggests a clear genetic link with the underlying geochemical Pb anomalies detected by means of an ongoing regional geochemical survey.

Geochemical indicators of gold ore fields

International Nuclear Information System (INIS)

Shcherbakov, Yu.G.

1995-01-01

The principles of selection of indicators for genetic reconstructions and prognostic valuations of gold mineralization of diverse morphological and geochemical types have been substantiated. The neutron-activation analysis with radiochemical separation and detection limit of 1-10 -8 %, instrumental neutron-activation analysis and atomic-absorption analysis are the main methods of determination of gold low contents in the rocks, as well as diverse elements, including transition, rare earth elements and tellurium, in gold. 50 refs.; 1 fig.; 3 tabs

Lead transport in intra-oceanic subduction zones: 2D geochemical-thermo-mechanical modeling of isotopic signatures

NARCIS (Netherlands)

Baitsch-Ghirardello, B.; Stracke, A.; Connolly, J.A.D.; Nikolaeva, K.M.; Gerya, T.V.

2014-01-01

Understanding the physical-chemical mechanisms and pathways of geochemical transport in subduction zones remains a long-standing goal of subduction-related research. In this study, we perform fully coupled geochemical-thermo-mechanical (GcTM) numerical simulations to investigate Pb isotopic

Report on fundamental survey on developing coal resources in fiscal 1999 - summarized edition. Survey and development of new exploration technology (exploration of shallow land area beds); 1999 nendo shintansa gijutsu chosa kaihatsu (rikuiki senso tansa) hokokusho (yoyakuban)

Energy Technology Data Exchange (ETDEWEB)

NONE

2000-03-01

Coal resource surveys have been performed using mainly the physical exploration method on the NSW State of Australia as the object. The Caroona area has a Permian period ground bed distributed, in which multiple number of coal layers exist. The ground bed is covered with sedimentary layers of the Triassic period inconsistently, and this Triassic period system is covered by volcanic rocks of the Jurassic period inconsistently. Faults are going through the coal beds in their upper or lower layers at locations having soft rock beds. The faults were identified by seismic exploration using the two-dimensional reflection method, assisted by the result of the physical logging. The results of pursuit on reflective events and the result of test drilling were unified to identify the summary of basset lines of the major coal beds. Furthermore, the seismic exploration using the three-dimensional reflective method capable of high-level imaging of underground structures was applied to coal beds existing in depths less than 480 m. Multiple number of local and small-scale sinking were detected with time difference of 5 ms and depth conversion to 7 m. Locations, runs, and inclination were interpreted also on faults having small fall whose details have been unclear in the exploration using the two-dimensional method. The seismic exploration using the three-dimensional reflective method was found capable of identifying micro structural changes and fault runs that cannot be tracked by the two-dimensional method. (NEDO)

Geochemical databases. Part 1. Pmatch: a program to manage thermochemical data. Part 2. The experimental validation of geochemical computer models

International Nuclear Information System (INIS)

Pearson, F.J. Jr.; Avis, J.D.; Nilsson, K.; Skytte Jensen, B.

1993-01-01

This work is carried out under cost-sharing contract with European Atomic Energy Community in the framework of its programme on Management and Storage of Radioactive Wastes. Part 1: PMATCH, A Program to Manage Thermochemical Data, describes the development and use of a computer program, by means of which new thermodynamic data from literature may be referenced to a common frame and thereby become internally consistent with an existing database. The report presents the relevant thermodynamic expressions and their use in the program is discussed. When there is not sufficient thermodynamic data available to describe a species behaviour under all conceivable conditions, the problems arising are thoroughly discussed and the available data is handled by approximating expressions. Part II: The Experimental Validation of Geochemical Computer models are the results of experimental investigations of the equilibria established in aqueous suspensions of mixtures of carbonate minerals (Calcium, magnesium, manganese and europium carbonates) compared with theoretical calculations made by means of the geochemical JENSEN program. The study revealed that the geochemical computer program worked well, and that its database was of sufficient validity. However, it was observed that experimental difficulties could hardly be avoided, when as here a gaseous component took part in the equilibria. Whereas the magnesium and calcium carbonates did not demonstrate mutual solid solubility, this produced abnormal effects when manganese and calcium carbonates were mixed resulting in a diminished solubility of both manganese and calcium. With tracer amounts of europium added to a suspension of calcite in sodium carbonate solutions long term experiments revealed a transition after 1-2 months, whereby the tracer became more strongly adsorbed onto calcite. The transition is interpreted as the nucleation and formation of a surface phase incorporating the 'species' NaEu(Co 3 ) 2

Geological and Geochemical Criteria for the Estimation of the Area of The Lesser Hinggan for the Endogenous Gold Mineralization (The Far East, Russia)

Science.gov (United States)

Yurchenko, Yuriy

2015-04-01

The Area of the Lesser Hinggan in the middle of the XIX century has been known as one of the Gold areas of the Far East. Exploration of gold in different years were engaged by P.K. Yavorovskiy (1904), E.E. Anert (1928), G.V. Itsikson (1961), V.A. Buryak (1999, 2002, 2003), A.M. Zhirnov (1998, 2000, 2008), L.V. Eyrish (1960, 1964, 1995, 1999, 2002, 2008) and many others. But despite the abundance of factual materials in the problem of the gold metallogeny of the Lesser Hinggan are more aspects that still have not received a answer. Among them is the key issue about indigenous sources of the gold. First for the Lesser Hinggan area, structural-geochemical zoning at 1:200 000 scale was carried out based on the results of the precise analyses of over 2,600 soil and sediment stream samples. Three anomalous geochemical zones and nine anomalous geochemical clusters in their contours specialized for gold mineralization were revealed. Regional clarkes (fersms) for 19 chemical elements were calculated. Geological formations geochemically specialized for gold and their role in endogenous ore-forming processes were defined. Geochemical criteria for endogenous gold mineralization and its ore-formational affiliation were defined as well. Thus, from the geological and geochemical data, are the following signs of the gold mineralization of the Lesser Hinggan: 1. Some geological formations are geochemical specialized by the gold (carbon ("black") schists and ferruginous quartzite Vendian-Cambrian Hinggan series). They're considered as a source of the gold, involved in younger epigenetic processes of mobilization and redistribution of this element; 2. Contrasting geochemical anomalies of the gold and elements satellites in the secondary halos and stream sediments displayed in the contours of the geological formations of a wide age range - terrigenous-carbonate rocks of the Hinggan series, the Paleozoic granitoid massives, the Cretaceous volcanic fields ; 3. Samples of the native gold

Application of soil radon survey to searching for sandstone-type uranium deposit at western margin of Ordos basin

International Nuclear Information System (INIS)

Liu Hanbin; Yin Jinshuang; Cui Yonghui

2006-01-01

On the basis of condition tests of soil radon survey at certain uranium deposit in Ordos basin, regional soil radon survey was carried but in a study area of western margin of Ordos basin. By processing of soil radon survey data, five anomalous areas with certain metallogenic potential have been delineated. Then, discovered anomalies have been interpreted and evaluated for providing important reference for further drilling work. Research results indicate that by soil radon survey, anomalies may be distinguished in a basin, and soil radon survey could be an important geochemical prospecting method for rapid evaluation of sandstone-type uranium deposit in basin areas. (authors)

Geochemical studies of potential source minerals of radon: case studies in Hungary

Energy Technology Data Exchange (ETDEWEB)

Rajnai, G.; Nagy-Balogh, J.; Gal-Solymos, K.; Konc, Z.; Breitner, D.; Barabas, A.; Szabo, C. [Eotvos Univ., Lithosphere Fluid Research Lab, Dept. of Petrology and Geochemistry, Budapest (Hungary); Barabas, A. [Eotvos Univ., Dept. of Geophysics, Budapest (Hungary)

2006-07-01

In Hungary, during the past decade five distinct regions have been chosen to find possible explanations of the uncommonly high radon background radiation values. The main aim of the research is to study U- and Th-bearing minerals in petrographic and geochemical characters. Besides the microscopic techniques, whole rock and in situ geochemical analytical methods were applied to determine the bulk U and Th content of the studied geological samples. We assume that some of the radon measured is related to the U and Th contents of the samples. (authors)

Geochemical evolution of the near field of a KBS-3 repository

International Nuclear Information System (INIS)

Arcos, David; Grandia, Fidel; Domenech, Cristina

2006-09-01

The Swedish concept developed by SKB for deep radioactive waste disposal, envisages an engineered multi-barrier system surrounding the nuclear waste (near field). In the present study we developed a numerical model to assess the geochemical evolution of the near field in the frame of the SKB's safety assessment SR-Can. These numerical models allow us to predict the long-term geochemical evolution of the near field system by means of reactive-transport codes and the information gathered in underground laboratory experiments and natural analogues. Two different scenarios have been defined to model this near field evolution, according to the pathway used by groundwater to contact the near field: a) through a fracture in the host rock intersecting the deposition hole; and b) through the material used to backfill the deposition tunnel. Moreover, we also modelled the effect of different groundwater compositions reaching the near field, as the up-rise of deep-seated brines and the intrusion of ice-melting derived groundwater. We also modelled the effect of the thermal stage due to the heat generated by spent fuel on the geochemical evolution of the bentonite barrier

Geochemical properties and nuclear chemical characteristics of Oklo natural fission reactors

Energy Technology Data Exchange (ETDEWEB)

Hidaka, Hiroshi [Hiroshima Univ., Higashi-Hiroshima (Japan). Faculty of Science

1997-07-01

There are six uranium deposits in the Gabonese Republic in the cnetral Africa. `Fission reactor zone`, the fission chain reactions generated about 200 billion years ago, was existed in a part of them. CEA begun geochemical researches of Oklo deposits etc. in 1991. The geochemical and nuclear chemical properties of Oklo were reviewed from the results of researches. Oklo deposits is consisted of main five sedimentary faces such as sandstone (FA), Black Shale formation (FB), mudstone (FC), tuff (FD) and volcaniclastic sandstone (FE) from the bottom on the base rock of granite in the Precambrian era. Uranium is enriched in the upper part of FA layer and the under part of FB layer. {sup 235}U/{sup 238}U, U content, fission proportion, duration time, neutron fluence, temperature, restitution factor of {sup 235}U and epithermal index ({gamma}) were investigated and compared. The geochemical properties of Oklo are as followed: large enrich of uranium, the abundance ratio of {sup 235}U as same as that of enriched uranium, interaction of natural water and small rear earth elements. These factors made casually Oklo fission reactor. (S.Y.)

Geochemical evolution of the near field of a KBS-3 repository

Energy Technology Data Exchange (ETDEWEB)

Arcos, David; Grandia, Fidel; Domenech, Cristina [Enviros Spain S.L., Barcelona (Spain)

2006-09-15

The Swedish concept developed by SKB for deep radioactive waste disposal, envisages an engineered multi-barrier system surrounding the nuclear waste (near field). In the present study we developed a numerical model to assess the geochemical evolution of the near field in the frame of the SKB's safety assessment SR-Can. These numerical models allow us to predict the long-term geochemical evolution of the near field system by means of reactive-transport codes and the information gathered in underground laboratory experiments and natural analogues. Two different scenarios have been defined to model this near field evolution, according to the pathway used by groundwater to contact the near field: a) through a fracture in the host rock intersecting the deposition hole; and b) through the material used to backfill the deposition tunnel. Moreover, we also modelled the effect of different groundwater compositions reaching the near field, as the up-rise of deep-seated brines and the intrusion of ice-melting derived groundwater. We also modelled the effect of the thermal stage due to the heat generated by spent fuel on the geochemical evolution of the bentonite barrier.

Establishing nursery estuary otolith geochemical tags for Sea Bass (Dicentrarchus labrax): Is temporal stability estuary dependent?

Science.gov (United States)

Ryan, Diarmuid; Wögerbauer, Ciara; Roche, William

2016-12-01

The ability to determine connectivity between juveniles in nursery estuaries and adult populations is an important tool for fisheries management. Otoliths of juvenile fish contain geochemical tags, which reflect the variation in estuarine elemental chemistry, and allow discrimination of their natal and/or nursery estuaries. These tags can be used to investigate connectivity patterns between juveniles and adults. However, inter-annual variability of geochemical tags may limit the accuracy of nursery origin determinations. Otolith elemental composition was used to assign a single cohort of 0-group sea bass Dicentrarchus labrax to their nursery estuary thus establishing an initial baseline for stocks in waters around Ireland. Using a standard LDFA model, high classification accuracies to nursery sites (80-88%) were obtained. Temporal stability of otolith geochemical tags was also investigated to assess if annual sampling is required for connectivity studies. Geochemical tag stability was found to be strongly estuary dependent.

Wide-Field Infrared Survey Explorer Observations of the Evolution of Massive Star-Forming Regions

Science.gov (United States)

Koenig, X. P.; Leisawitz, D. T.; Benford, D. J.; Rebull, L. M.; Padgett, D. L.; Asslef, R. J.

2012-01-01

We present the results of a mid-infrared survey of II outer Galaxy massive star-forming regions and 3 open clusters with data from the Wide-field Infrared Survey Explorer (WISE). Using a newly developed photometric scheme to identify young stellar objects and exclude extragalactic contamination, we have studied the distribution of young stars within each region. These data tend to support the hypothesis that latter generations may be triggered by the interaction of winds and radiation from the first burst of massive star formation with the molecular cloud material leftover from that earlier generation of stars. We dub this process the "fireworks hypothesis" since star formation by this mechanism would proceed rapidly and resemble a burst of fireworks. We have also analyzed small cutout WISE images of the structures around the edges of these massive star-forming regions. We observe large (1-3 pc size) pillar and trunk-like structures of diffuse emission nebulosity tracing excited polycyclic aromatic hydrocarbon molecules and small dust grains at the perimeter of the massive star-forming regions. These structures contain small clusters of emerging Class I and Class II sources, but some are forming only a single to a few new stars.

WIDE-FIELD INFRARED SURVEY EXPLORER OBSERVATIONS OF THE EVOLUTION OF MASSIVE STAR-FORMING REGIONS

International Nuclear Information System (INIS)

Koenig, X. P.; Leisawitz, D. T.; Benford, D. J.; Padgett, D. L.; Rebull, L. M.; Assef, R. J.

2012-01-01

We present the results of a mid-infrared survey of 11 outer Galaxy massive star-forming regions and 3 open clusters with data from the Wide-field Infrared Survey Explorer (WISE). Using a newly developed photometric scheme to identify young stellar objects and exclude extragalactic contamination, we have studied the distribution of young stars within each region. These data tend to support the hypothesis that latter generations may be triggered by the interaction of winds and radiation from the first burst of massive star formation with the molecular cloud material leftover from that earlier generation of stars. We dub this process the 'fireworks hypothesis' since star formation by this mechanism would proceed rapidly and resemble a burst of fireworks. We have also analyzed small cutout WISE images of the structures around the edges of these massive star-forming regions. We observe large (1-3 pc size) pillar and trunk-like structures of diffuse emission nebulosity tracing excited polycyclic aromatic hydrocarbon molecules and small dust grains at the perimeter of the massive star-forming regions. These structures contain small clusters of emerging Class I and Class II sources, but some are forming only a single to a few new stars.

Report on the geothermal survey of the Kitayuzawa district of Otaki Village, Iburi Province, Hokkaido. Hokkaido Kitayuzawa chiikino chinetsu chosa

Energy Technology Data Exchange (ETDEWEB)

Hayakawa, F; Konoya, M; Yokoyama, H; Wake, T; Kakiichi, K

1974-01-01

Cumulative data from a three year survey of the Kitayuzawa district of Otaki Village (Iburi, Hokkaido) are analyzed. The district is a well known hot spring area, where spring temperatures exceed 90/sup 0/C. The three-year study included geological, geochemical, and geophysical surveys; electrical, magnetic, and microearthquake studies; and a test well of 500 ..pi.. depth. The hot spas are associated with intrusive zones (dikes) near the Kitayuzawa-Osaru River. These zones can be detected by magnetic surveys. Studies of rock alteration indicated that positive thermal anomalies are associated with zeolite zones. Based on the geochemical and geophysical data, it is estimated that the thermal energy discharged in the Kitayuzawa district is about 14.4 Mcal/s. The waters of these springs are characterized as simple, vadose hot-water. A low-resistivity zone surrounds the springs and extends to the eastern sector of the district. Future studies of the area will include more numerous and deeper exploratory boreholes in the eastern sector. About 40 illustrations are provided, and 29 references are given.

Exploration Review

Science.gov (United States)

Wilburn, D.R.; Stanley, K.A.

2013-01-01

This summary of international mineral exploration activities for 2012 draws upon information from industry sources, published literature and U.S. Geological Survey (USGS) specialists. The summary provides data on exploration budgets by region and mineral commodity, identifies significant mineral discoveries and areas of mineral exploration, discusses government programs affecting the mineral exploration industry and presents analyses of exploration activities performed by the mineral industry. Three sources of information are reported and analyzed in this annual review of international exploration for 2012: 1) budgetary statistics expressed in U.S. nominal dollars provided by SNL Metals Economics Group (MEG) of Halifax, Nova Scotia; 2) regional and site-specific exploration activities that took place in 2012 as compiled by the USGS and 3) regional events including economic, social and political conditions that affected exploration activities, which were derived from published sources and unpublished discussions with USGS and industry specialists.

Overview of the geochemical code MINTEQ: applications to performance assessment for low-level wastes

International Nuclear Information System (INIS)

Graham, M.J.; Peterson, S.R.

1985-09-01

The MINTEQ geochemical computer code, developed at Pacific Northwest Laboratory, integrates many of the capabilities of its two immediate predecessors, WATEQ3 and MINEQL. MINTEQ can be used to perform the calculations necessary to simulate (model) the contact of low-level waste solutions with heterogeneous sediments or the interaction of ground water with solidified low-level wastes. The code is capable of performing calculations of ion speciation/solubility, adsorption, oxidation-reduction, gas phase equilibria, and precipitation/dissolution of solid phases. Under the Special Waste Form Lysimeters-Arid program, the composition of effluents (leachates) from column and batch experiments, using laboratory-scale waste forms, will be used to develop a geochemical model of the interaction of ground water with commercial solidified low-level wastes. The wastes being evaluated include power reactor waste streams that have been solidified in cement, vinyl ester-styrene, and bitumen. The thermodynamic database for the code is being upgraded before the geochemical modeling is performed. Thermodynamic data for cobalt, antimony, cerium, and cesium solid phases and aqueous species are being added to the database. The need to add these data was identified from the characterization of the waste streams. The geochemical model developed from the laboratory data will then be applied to predict the release from a field-lysimeter facility that contains full-scale waste samples. The contaminant concentrations migrating from the wastes predicted using MINTEQ will be compared to the long-term lysimeter data. This comparison will constitute a partical field validation of the geochemical model. 28 refs

Report on the geological-geochemical research carried out within the area of geochemical anomaly P7, Vathyrema, Drama Department

International Nuclear Information System (INIS)

Stavropoulos, Athanasios.

1982-08-01

The investigated area covering about 30 km 2 is situated in the crystalline massive of Rhodope (north of Drama deparment, E. Macedonia) where granitoids constitute its main petrological type. The geological-geochemical and radiometric investigations carried out so far in the area have localized a large number of places with high values of γ-radiation (1.000 - 15.000 c/s), as well as high concentrations of uranium (50-500 ppm). The uranium mineralization within the zone of oxidation is expressed by the uranium mineral autunite, accompanied by intensive hematitization-limonitization and chloritization-kaolinization, and additionally by small spots and veinlets of pyrite and galena. It seems that tectonic control exists on the uranium mineralization, since most of the anomalous concentrations of uranium are sitting along mylonite zones rich in chlorite and kaolin. There have been discerned seven more anomalous part areas which will have to be covered by geochemical stream sediment sampling (phase 3), as well as geological mapping (scale 1:5.000). The results from the research conducted within the concerned anomaly lead us to the conclusion that this area is very promising and possibilities of localization of uranium payable concentrations are very high. (N.Ch.)

Uranium exploration in Central and Eastern Macedonia and Thrace (Greece)

International Nuclear Information System (INIS)

Kampanellos, John; Persianis, Demetrios.

1983-04-01

In accordance with the agreement between the U.N. Development Programme, the IAEA and the Greek AEC, carborne scintillometer, ground scintillometer and geochemical stream sediment surveys, along with reconnaissance geological mapping, have been carried out in the area of map sheets 2423-2422 (Iasmos, Komotini department, Thrace). The results of these surveys, presented in a series of 15 maps, indicate that six areas totalling 356 km 2 will require further detailed examination in order to test their potential of economic uranium deposits. Three of these areas, Melitena, Medousa and Nimfea, covering in total 143 km 2 , should be given first priority and be further tested by detailed stream sediment and bank soil gas sampling, detailed ground scintillometer measurements, grid soil sampling and radon soil gas sampling, as well as by detailed geological mapping. (N.Ch.)

Report on the mineral exploration in the San Jose and Arroyo Grande area Oriental Republic of Uruguay

International Nuclear Information System (INIS)

2001-01-01

This survey is based on the scope of work signed between the Japanese government and the Oriental Republic of Uruguay on 24 November 2000. The purpose of this is to clarify both the geologic appearance and the occurrence of the ore fields of mineral deposits in the San Jose and Arroyo Grande area in this country, with the aim of discovering new ore deposits. In addition, another purpose is to transfer the technology to the involved organizations of the object country. The survey is conceived as a three year project initiated in 2000, and this fiscal year falls on the first phase.This survey consist of this existing data analysis, the geological interpretation of satellite image data, the geological survey and geochemical prospecting

Report on the mineral exploration in the San Jose and Arroyo Grande area Oriental Republic of Uruguay

Energy Technology Data Exchange (ETDEWEB)

NONE

2001-07-01

This survey is based on the scope of work signed between the Japanese government and the Oriental Republic of Uruguay on 24 November 2000. The purpose of this is to clarify both the geologic appearance and the occurrence of the ore fields of mineral deposits in the San Jose and Arroyo Grande area in this country, with the aim of discovering new ore deposits. In addition, another purpose is to transfer the technology to the involved organizations of the object country. The survey is conceived as a three year project initiated in 2000, and this fiscal year falls on the first phase.This survey consist of this existing data analysis, the geological interpretation of satellite image data, the geological survey and geochemical prospecting

Exploring the Milky Way halo with SDSS-II SN survey RR Lyrae stars

Science.gov (United States)

De Lee, Nathan

This thesis details the creation of a large catalog of RR Lyrae stars, their lightcurves, and their associated photometric and kinematic parameters. This catalog contains 421 RR Lyrae stars with 305 RRab and 116 RRc. Of these, 241 stars have stellar spectra taken with either the Blanco 4m RC spectrograph or the SDSS/SEGUE survey, and in some cases taken by both. From these spectra and photometric methods derived from them, an analysis is conducted of the RR lyrae's distribution, metallicity, kinematics, and photometric properties within the halo. All of these RR Lyrae originate from the SDSS-II Supernova Survey. The SDSS-II SN Survey covers a 2.5 degree equatorial stripe ranging from -60 to +60 degrees in RA. This corresponds to relatively high southern galactic latitudes in the anti-center direction. The full catalog ranges from g 0 magnitude 13 to 20 which covers a distance of 3 to 95 kpc from the sun. Using this sample, we explore the Oosterhoff dichotomy through the D log P method as a function of | Z | distance from the plane. This results in a clear division of the RRab stars into OoI and OoII groups at lower | Z |, but the population becomes dominated by OoI stars at higher | Z |. The idea of a dual halo is explored primarily in the context of radial velocity distributions as a function of | Z |. In particular, V gsr , the radial velocity in the galactic standard of rest, is used as a proxy for V [straight phi] , the cylindrical rotational velocity. This is then compared against a single halo model galaxy, which results in very similar V gsr histograms for both at low to medium | Z |. However, at high | Z | there is a clear separation into two distinct velocity groups for the data without a corresponding separation in the model, suggesting that at least a two-component model for the halo is necessary. The final part of the analysis involves [Fe/H] measurements from both spectra and photometric relations cut in both | Z | and radial velocity. In this case

Gamma radiometric survey of Jamaica

International Nuclear Information System (INIS)

Lalor, G.C.; Robotham, H.; Miller, J.M.; Simpson, P.R.

1989-01-01

The results of a total gamma radiometric survey of Jamaica, carried out with car-borne instrumentation, are presented and the data compared with the contents of potassium, thorium and uranium in rocks and in surface (soil, stream-sediment, pan concentrate and water) samples obtained at six sites selected to be representative of the principal rock types and surface environments of Jamaica. The work formed part of an orientation study for a regional geochemical survey of the CARICOM countries of the Caribbean. The initial results indicate that enhanced gamma activity is correlated with enrichment in uranium and thorium, but not potassium, in terra rossa soils and/or bauxite deposits in limestone. Elsewhere, gamma levels are increased on the Above Rocks Cretaceous basement Inlier, where they correlate generally with the presence of volcanogenic sediments and a granodiorite intrusion. The lowest radioactivity was recorded in the vicinity of ultrabasic rocks in the Blue Mountains Inlier. (author)

Geochemical characterization and miospore biochronostratigraphy of the Frasnian anoxic event in the Parnaiba basin, Northeast Brazil

International Nuclear Information System (INIS)

Rodrigues, R.; De Melo, J.H.G.; Alves, D.B.; Loboziak, S.

1995-01-01

Radioactive shales of Frasnian age in the Parnaiba Basin present high concentrations of organic matter. They correspond to a condensed section related to the Devonian maximum marine transgression. Combined geochemical, palynological and clay mineral data point out to a dominant algal contribution in the composition of the organic matter, as well as to anoxic depositional settings. This radioactive shale interval corresponds to the onset of a long-lasting, global anoxic event which was to be intensified in the Late Frasnian, and thus can be regarded as a marker for chronostratigraphic correlations. It includes the main source rocks of Devonian age in the Palaeozoic basins of north Brazil, and therefore represents a target of potential interest for hydrocarbon exploration. (authors). 16 refs., 10 figs., 1 tab., 17 photos

Geochemical characterization and miospore biochronostratigraphy of the Frasnian anoxic event in the Parnaiba basin, Northeast Brazil

Energy Technology Data Exchange (ETDEWEB)

Rodrigues, R.; De Melo, J.H.G.; Alves, D.B. [Universidade Federal, Rio de Janeiro, RJ (Brazil); Loboziak, S. [Lille-1 Univ., 59 - Villeneuve-d`Ascq (France)

1995-12-31

Radioactive shales of Frasnian age in the Parnaiba Basin present high concentrations of organic matter. They correspond to a condensed section related to the Devonian maximum marine transgression. Combined geochemical, palynological and clay mineral data point out to a dominant algal contribution in the composition of the organic matter, as well as to anoxic depositional settings. This radioactive shale interval corresponds to the onset of a long-lasting, global anoxic event which was to be intensified in the Late Frasnian, and thus can be regarded as a marker for chronostratigraphic correlations. It includes the main source rocks of Devonian age in the Palaeozoic basins of north Brazil, and therefore represents a target of potential interest for hydrocarbon exploration. (authors). 16 refs., 10 figs., 1 tab., 17 photos.

Geochemical and hydrodynamic phosphorus retention mechanisms in lowland catchments

NARCIS (Netherlands)

van der Grift, B.

2017-01-01

The release of phosphorus (P) to surface water from heavily fertilised agricultural fields is of major importance for surface water quality. The research reported in this thesis examined the role of geochemical and hydrodynamic processes controlling P speciation and transport in lowland catchments

Mining inventory of Uruguay. Polanco fotoplano geochemical prospecting results

International Nuclear Information System (INIS)

Zeegers, H; Artignan, D; Vairon, P

1982-01-01

This work is about the geochemical prospecting carried out in Polanco fotoplano within the framework of Uruguay Mining inventory . In this work were covered 660 km2 obtaining 685 samples for study which were analyzed by Plasma Emission Spectrometry in Orleans BRGM laboratories

Mineral and Geochemical Classification From Spectroscopy/Diffraction Through Neural Networks

Science.gov (United States)

Ferralis, N.; Grossman, J.; Summons, R. E.

2017-12-01

Spectroscopy and diffraction techniques are essential for understanding structural, chemical and functional properties of geological materials for Earth and Planetary Sciences. Beyond data collection, quantitative insight relies on experimentally assembled, or computationally derived spectra. Inference on the geochemical or geophysical properties (such as crystallographic order, chemical functionality, elemental composition, etc.) of a particular geological material (mineral, organic matter, etc.) is based on fitting unknown spectra and comparing the fit with consolidated databases. The complexity of fitting highly convoluted spectra, often limits the ability to infer geochemical characteristics, and limits the throughput for extensive datasets. With the emergence of heuristic approaches to pattern recognitions though machine learning, in this work we investigate the possibility and potential of using supervised neural networks trained on available public spectroscopic database to directly infer geochemical parameters from unknown spectra. Using Raman, infrared spectroscopy and powder x-ray diffraction from the publicly available RRUFF database, we train neural network models to classify mineral and organic compounds (pure or mixtures) based on crystallographic structure from diffraction, chemical functionality, elemental composition and bonding from spectroscopy. As expected, the accuracy of the inference is strongly dependent on the quality and extent of the training data. We will identify a series of requirements and guidelines for the training dataset needed to achieve consistent high accuracy inference, along with methods to compensate for limited of data.

A geostatistical method applied to the geochemical study of the Chichinautzin Volcanic Field in Mexico

Science.gov (United States)

Robidoux, P.; Roberge, J.; Urbina Oviedo, C. A.

2011-12-01

The origin of magmatism and the role of the subducted Coco's Plate in the Chichinautzin volcanic field (CVF), Mexico is still a subject of debate. It has been established that mafic magmas of alkali type (subduction) and calc-alkali type (OIB) are produced in the CVF and both groups cannot be related by simple fractional crystallization. Therefore, many geochemical studies have been done, and many models have been proposed. The main goal of the work present here is to provide a new tool for the visualization and interpretation of geochemical data using geostatistics and geospatial analysis techniques. It contains a complete geodatabase built from referred samples over the 2500 km2 area of CVF and its neighbour stratovolcanoes (Popocatepetl, Iztaccihuatl and Nevado de Toluca). From this database, map of different geochemical markers were done to visualise geochemical signature in a geographical manner, to test the statistic distribution with a cartographic technique and highlight any spatial correlations. The distribution and regionalization of the geochemical signatures can be viewed in a two-dimensional space using a specific spatial analysis tools from a Geographic Information System (GIS). The model of spatial distribution is tested with Linear Decrease (LD) and Inverse Distance Weight (IDW) interpolation technique because they best represent the geostatistical characteristics of the geodatabase. We found that ratio of Ba/Nb, Nb/Ta, Th/Nb show first order tendency, which means visible spatial variation over a large scale area. Monogenetic volcanoes in the center of the CVF have distinct values compare to those of the Popocatepetl-Iztaccihuatl polygenetic complex which are spatially well defined. Inside the Valley of Mexico, a large quantity of monogenetic cone in the eastern portion of CVF has ratios similar to the Iztaccihuatl and Popocatepetl complex. Other ratios like alkalis vs SiO2, V/Ti, La/Yb, Zr/Y show different spatial tendencies. In that case, second

Geochemical investigations at Maxey Flats radioactive waste disposal site

International Nuclear Information System (INIS)

Dayal, R.; Pietrzak, R.F.; Clinton, J.

1984-09-01

As part of the NRC efforts to develop a data base on source term characteristics for low level wastes, Brookhaven National Laboratory (BNL) has produced and analyzed a large amount of data on trench leachate chemistry at existing shallow land burial sites. In this report, we present the results of our investigations at the Maxey Flats, Kentucky disposal site. In particular, data on trench leachate chemistry are reviewed and discussed in terms of mechanisms and processes controlling the composition of trench solutes. Particular emphasis is placed on identifying both intra- and extra-trench factors and processes contributing to source term characteristics, modifications, and uncertainties. BNL research on the Maxey Flats disposal site has provided important information not only on the source term characteristics and the factors contributing to uncertainties in the source term but also some generic insights into such geochemical processes and controls as the mechanics of leachate formation, microbial degradation and development of anoxia, organic complexation and radionuclide mobility, redox inversion and modification of the source term, solubility constraints on solute chemistry, mineral authigenesis, corrosion products and radionuclide scavenging, and the role of organic complexants in geochemical partitioning of radionuclides. A knowledge of such processes and controls affecting the geochemical cycling of radionuclides as well as an understanding of the important factors that contribute to variability and uncertainties in the source term is essential for evaluating the performance of waste package and the site, making valid predictions of release for dose calculations, and for planning site performance monitoring as well as remedial actions. 43 references, 47 figures, 30 tables

Exploring dark matter microphysics with galaxy surveys

Energy Technology Data Exchange (ETDEWEB)

Escudero, Miguel; Mena, Olga [Instituto de Física Corpuscular (IFIC), CSIC-Universitat de València, Apartado de Correos 22085, E-46071 Valencia (Spain); Vincent, Aaron C.; Wilkinson, Ryan J.; Boehm, Céline, E-mail: miguel.Escudero@uv.es, E-mail: omena@ific.uv.es, E-mail: aaron.vincent@durham.ac.uk, E-mail: ryan.wilkinson@durham.ac.uk, E-mail: c.m.boehm@durham.ac.uk [Institute for Particle Physics Phenomenology (IPPP), Durham University, South Road, Durham DH1 3LE (United Kingdom)

2015-09-01

We use present cosmological observations and forecasts of future experiments to illustrate the power of large-scale structure (LSS) surveys in probing dark matter (DM) microphysics and unveiling potential deviations from the standard ΛCDM scenario. To quantify this statement, we focus on an extension of ΛCDM with DM-neutrino scattering, which leaves a distinctive imprint on the angular and matter power spectra. After finding that future CMB experiments (such as COrE+) will not significantly improve the constraints set by the Planck satellite, we show that the next generation of galaxy clustering surveys (such as DESI) could play a leading role in constraining alternative cosmologies and even have the potential to make a discovery. Typically we find that DESI would be an order of magnitude more sensitive to DM interactions than Planck, thus probing effects that until now have only been accessible via N-body simulations.

Experimental insights into geochemical changes in hydraulically fractured Marcellus Shale

International Nuclear Information System (INIS)

Marcon, Virginia; Joseph, Craig; Carter, Kimberly E.; Hedges, Sheila W.; Lopano, Christina L.; Guthrie, George D.; Hakala, J. Alexandra

2017-01-01

Hydraulic fracturing applied to organic-rich shales has significantly increased the recoverable volume of methane available for U.S. energy consumption. Fluid-shale reactions in the reservoir may affect long-term reservoir productivity and waste management needs through changes to fracture mineral composition and produced fluid chemical composition. We performed laboratory experiments with Marcellus Shale and lab-generated hydraulic fracturing fluid at elevated pressures and temperatures to evaluate mineral reactions and the release of trace elements into solution. Results from the experiment containing fracturing chemicals show evidence for clay and carbonate dissolution, secondary clay and anhydrite precipitation, and early-stage (24–48 h) fluid enrichment of certain elements followed by depletion in later stages (i.e. Al, Cd, Co, Cr, Cu, Ni, Sc, Zn). Other elements such as As, Fe, Mn, Sr, and Y increased in concentration and remained elevated throughout the duration of the experiment with fracturing fluid. Geochemical modeling of experimental fluid data indicates primary clay dissolution, and secondary formation of smectites and barite, after reaction with fracturing fluid. Changes in aqueous organic composition were observed, indicating organic additives may be chemically transformed or sequestered by the formation after hydraulic fracturing. The NaCl concentrations in our fluids are similar to measured concentrations in Marcellus Shale produced waters, showing that these experiments are representative of reservoir fluid chemistries and can provide insight on geochemical reactions that occur in the field. These results can be applied towards evaluating the evolution of hydraulically-fractured reservoirs, and towards understanding geochemical processes that control the composition of produced water from unconventional shales. - Highlights: • Metal concentrations could be at their peak in produced waters recovered 24–48 after fracturing. • Carbonate

Geothermal development promotion survey report. No. 29. Upper reach region of Oita river; 1988-1990 chinetsu kaihatsu sokushin chosa hokokusho. No. 29 Oitagawa joryu chiiki

Energy Technology Data Exchange (ETDEWEB)

NONE

1991-03-01

The results of surveys conducted in the Oita river region, Oita Prefecture, in fiscal 1988-1989 are compiled in this report. Conducted were a geological/alteration zone survey, geochemical survey, electric prospecting (Schlumberger method), electromagnetic surveillance (simplified magnetotelluric method), electromagnetic surveillance (EMAP - Environmental Monitoring and Assessment Program method), heat flow rate survey, test boring, environmental impact survey, and so forth. Conclusions are mentioned below. It is inferred that the geothermal fluid results from groundwater originating in meteoric water, that the meteoric water takes many years to flow from the mountainous region into the ground where it is stored mainly in the Shonai stratum, that the stored water is warmed by heat from rocks in the neighborhood for development into a geothermal fluid, and that the geothermal fluid finally forms a hot spring water reservoir. Hot spring water reservoirs are found widely distributed in the basin of the Oita river. In view of the ground temperature distribution and the hot spring water geochemical temperature determined by structure boring, it is concluded that possibilities are quite low that there exists a high-temperature geothermal fluid usable for power generation. (NEDO)

NURE aerial gamma ray and magnetic detail survey of portions of northeast Washington. Volume I. Data acquisition, reduction and interpretation. Final report

International Nuclear Information System (INIS)

1981-11-01

As part of the Department of Energy (DOE) National Uranium Evaluation Program a rotary wing detailed high sensitivity radiometric and magnetic survey was performed which encompassed 8 areas in the northeastern portion of Washington State. The total area surveyed consisted of approximately 9105 line miles. The survey was flown with a Sikorsky S58T helicopter equipped with a high sensitivity gamma ray spectrometer and magnetometer. The airborne spectrometer system was calibrated at the DOE calibration facilities at Walker Field in Grand Junction, Colorado and at the Dynamic Test Range at Lake Mead, Arizona. The radiometric data was corrected and normalized to 400 feet terrain clearance and identified as to rock type by correlating each sample with existing geologic map information. A multi-variate analysis was performed, which together with the radiometric and magnetic contour maps was utilized in the geochemical analysis of each area. The survey data is presented in the form of contour maps, stacked profiles, histograms and microfiche copies of the data listings. This graphic material is presented in the individual area reports. The results of the geologic and geochemical evaluation are presented as individual chapters of this narrative report

Uruguay Mining inventory. Las Animas fotoplano geochemical prospecting results

International Nuclear Information System (INIS)

Zeegers, H.; Spangenberg, J.

1981-01-01

This work is about the geochemical prospecting carried out in Las Animas fotoplano within the framework of Uruguay Mining inventory. In this work were covered 660 km2 obtaining 738 samples for study which were analyzed by Plasma Emission Spectrometry in Orleans BRGM laboratories.

Overview of geochemical modeling needs for nuclear waste management

International Nuclear Information System (INIS)

Isherwood, D.J.; Wolery, T.J.

1985-01-01

Geochemical modeling needs for nuclear waste management are discussed with an emphasis on data base development and computer code. Other areas for future research include: precipitation kinetics, fixed fugacity, sorption, glasslt. slashwater interactions, redox disequilibrium and kinetics, radiolysis, solid solutions, and isotopic fractionation. 15 references

Preliminary delineation of natural geochemical reactions, Snake River Plain aquifer system, Idaho National Engineering Laboratory and vicinity, Idaho

International Nuclear Information System (INIS)

Knobel, L.L.; Bartholomay, R.C.; Orr, B.R.

1997-05-01

The U.S. Geological Survey, in cooperation with the U.S. Department of Energy, is conducting a study to determine the natural geochemistry of the Snake River Plain aquifer system at the Idaho National Engineering Laboratory (INEL), Idaho. As part of this study, a group of geochemical reactions that partially control the natural chemistry of ground water at the INEL were identified. Mineralogy of the aquifer matrix was determined using X-ray diffraction and thin-section analysis and theoretical stabilities of the minerals were used to identify potential solid-phase reactants and products of the reactions. The reactants and products that have an important contribution to the natural geochemistry include labradorite, olivine, pyroxene, smectite, calcite, ferric oxyhydroxide, and several silica phases. To further identify the reactions, analyses of 22 representative water samples from sites tapping the Snake River Plain aquifer system were used to determine the thermodynamic condition of the ground water relative to the minerals in the framework of the aquifer system. Principal reactions modifying the natural geochemical system include congruent dissolution of olivine, diopside, amorphous silica, and anhydrite; incongruent dissolution of labradorite with calcium montmorillonite as a residual product; precipitation of calcite and ferric oxyhydroxide; and oxidation of ferrous iron to ferric iron. Cation exchange reactions retard the downward movement of heavy, multivalent waste constituents where infiltration ponds are used for waste disposal

First European Workshop on 'Remote sensing in mineral exploration'

International Nuclear Information System (INIS)

Van Wambeke, L.; Sanderson, D.J.; Dolan, J.M.

1986-01-01

The First European Workshop on 'Remote sensing in mineral exploration' organized by the Commission of the European Communities in February 1985 took stock of the results obtained within the European Community on the application of remote sensing techniques in exploration. The papers presented in this publication are essentially based on data obtained with the first generation of satellites and some airborne experiments. Important progress in data processing and interpretation has been made in the EEC since 1979 and is continuing to be made. The main aim is to provide the EC mining industry with a new tool for exploration. Significant results have already been obtained with the EEC playing an important role in the promotion of this relatively new technique. The main R and D trend is towards an integration of multidata sets (remote sensing, geochemical, geophysical and other data) to improve the methodology for delineating new targets in exploration. Another general trend is the participation of mining companies in remote sensing experiments. Further improvement for exploration is expected in the near future with the thematic mapper and the spot imageries as well as new airborne sensors

Geochemical monitoring using noble gases and carbon isotopes: study of a natural reservoir

International Nuclear Information System (INIS)

Jeandel, E.

2008-12-01

To limit emissions of greenhouse gases in the atmosphere, CO 2 geological sequestration appears as a solution in the fight against climate change. The development of reliable monitoring tools to ensure the sustainability and the safety of geological storage is a prerequisite for the implementation of such sites. In this framework, a geochemical method using noble gas and carbon isotopes geochemistry has been tested on natural and industrial analogues. The study of natural analogues from different geological settings showed systematic behaviours of the geochemical parameters, depending on the containment sites, and proving the effectiveness of these tools in terms of leak detection and as tracers of the behaviour of CO 2 . Moreover, an experience of geochemical tracing on a natural gas storage has demonstrated that it is possible to identify the physical-chemical processes taking place in the reservoir to a human time scale, increasing interest in the proposed tool and providing general information on its use. (author)

Geology and structure of major uranium-bearing zones in India and their exploration

International Nuclear Information System (INIS)

Nagabhushana, J.C.; Vasudeva Rao, M.; Sahasrabudhe, G.H.; Krishnamoorthy, B.; Suryanarayana Rao, C.; Rama Rao, Y.N.

1976-01-01

Radiogeologic, lithostratigraphic, tectonic, and crustal evolutionary considerations have enabled the recognition of three major uranium provinces in India: the Singhbhum Province in the north-east; the Rajasthan Province in the north-west; and the Madhya Pradesh Province in central India. The paper describes the salient features of the three uranium provinces, with particular emphasis on their structural set-up, magmatectonics, and the controls of uranium mineralization, and presents a few recent case histories of individual deposits (Bagjata and Turamdih in Singhbhum, and Dhabi-Dumhat in Madhya Pradesh) discovered by integrated exploration techniques. The three uranium provinces are related to major deep-seated faults: the Singhbhum Province lies at the arcuate north-east end of the deep fault of the Eastern Ghats; the Rajasthan Province parallels the great boundary fault; and the Madhya Pradesh Province aligns with the Mahanadi-Son rift system. Some of the plausible explanations for these remarkable features are: localization of uranium ore during episodes of crustal fracturing in Precambrian times; reactivation and rejuvenation of favourable basement structures; and the role of local 'hot spots' (aided by compressional and vertical tectonics) in crustal zones anomalously enriched in the heat-producing elements. Uranium exploration strategy in India during the last three decades reveals two significant trends - the application of conventional radiometric techniques during the period 1950-65; and introduction of sophisticated methodology comprising non-radiometric geophysical techniques, emanometry, aerial and car-borne gamma-ray spectrometry, geochemical surveys, and photogeological techniques as supplements to conventional radiometry, during the period 1965-75. It is concluded that extension of such integrated exploration techniques to favourable virgin terrains in India would lead to newer and richer uranium ore discoveries. (author)

Computer finds ore

Science.gov (United States)

Bell, Peter M.

Artificial intelligence techniques are being used for the first time to evaluate geophysical, geochemical, and geologic data and theory in order to locate ore deposits. After several years of development, an intelligent computer code has been formulated and applied to the Mount Tolman area in Washington state. In a project funded by the United States Geological Survey and the National Science Foundation a set of computer programs, under the general title Prospector, was used successfully to locate a previously unknown ore-grade porphyry molybdenum deposit in the vicinity of Mount Tolman (Science, Sept. 3, 1982).The general area of the deposit had been known to contain exposures of porphyry mineralization. Between 1964 and 1978, exploration surveys had been run by the Bear Creek Mining Company, and later exploration was done in the area by the Amax Corporation. Some of the geophysical data and geochemical and other prospecting surveys were incorporated into the programs, and mine exploration specialists contributed to a set of rules for Prospector. The rules were encoded as ‘inference networks’ to form the ‘expert system’ on which the artificial intelligence codes were based. The molybdenum ore deposit discovered by the test is large, located subsurface, and has an areal extent of more than 18 km2.

Analysis of the geochemical gradient created by surface-groundwater interactions within riverbanks of the East River in Crested Butte, Colorado

Science.gov (United States)

Lunzer, J.; Williams, K. H.; Malenda, H. F.; Nararne-Sitchler, A.

2016-12-01

An improved understanding of the geochemical gradient created by the mixing of surface and groundwater of a river system will have considerable impact on our understanding of microorganisms, organic cycling and biogeochemical processes within these zones. In this study, the geochemical gradient in the hyporheic zone is described using a variety of geochemical properties. A system of shallow groundwater wells were installed in a series of transects along a stream bank. Each transect consists of several wells that progress away from the river bank in a perpendicular fashion. From these wells, temperature, conductivity and pH of water samples were obtained via hand pumping or bailing. These data show a clear geochemical gradient that displays a distinct zone in the subsurface where the geochemical conditions change from surface water dominated to groundwater dominated. For this study, the East River near Crested Butte, Colorado has been selected as the river of interest due the river being a relatively undisturbed floodplain. Additionally, the specific section chosen on the East River displays relatively high sinuosity meaning that these meandering sections will produce hyporheic zones that are more laterally expansive than what would be expected on a river of lower sinuosity. This increase in lateral extension of the hyporheic zone will make depicting the subtle changes in the geochemical gradient much easier than that of a river system in which the hyporheic zone is not as laterally extensive. Data has been and will be continued to be collected at different river discharges to evaluate the geochemical gradient at differing rates. Overall, this characterization of the geochemical gradient along stream banks will produce results that will aid in the further use of geochemical methods to classify and understand hyporheic exchange zones and the potential expansion of these techniques to river systems of differing geologic and geographic conditions.

Drift pumice in the central Indian Ocean Basin: Geochemical evidence

Digital Repository Service at National Institute of Oceanography (India)

Pattan, J.N.; Mudholkar, A.V.; JaiSankar, S.; Ilangovan, D.

Abundant white to light grey-coloured pumice without ferromanganese oxide coating occurs within the Quaternary sediments of the Central Indian Ocean Basin (CIOB). Two distinct groups of pumice are identified from their geochemical composition, which...

Pilot studies for the North American Soil Geochemical Landscapes Project - Site selection, sampling protocols, analytical methods, and quality control protocols

Science.gov (United States)

Smith, D.B.; Woodruff, L.G.; O'Leary, R. M.; Cannon, W.F.; Garrett, R.G.; Kilburn, J.E.; Goldhaber, M.B.

2009-01-01

In 2004, the US Geological Survey (USGS) and the Geological Survey of Canada sampled and chemically analyzed soils along two transects across Canada and the USA in preparation for a planned soil geochemical survey of North America. This effort was a pilot study to test and refine sampling protocols, analytical methods, quality control protocols, and field logistics for the continental survey. A total of 220 sample sites were selected at approximately 40-km intervals along the two transects. The ideal sampling protocol at each site called for a sample from a depth of 0-5 cm and a composite of each of the O, A, and C horizons. The Ca, Fe, K, Mg, Na, S, Ti, Ag, As, Ba, Be, Bi, Cd, Ce, Co, Cr, Cs, Cu, Ga, In, La, Li, Mn, Mo, Nb, Ni, P, Pb, Rb, Sb, Sc, Sn, Sr, Te, Th, Tl, U, V, W, Y, and Zn by inductively coupled plasma-mass spectrometry and inductively coupled plasma-atomic emission spectrometry following a near-total digestion in a mixture of HCl, HNO3, HClO4, and HF. Separate methods were used for Hg, Se, total C, and carbonate-C on this same size fraction. Only Ag, In, and Te had a large percentage of concentrations below the detection limit. Quality control (QC) of the analyses was monitored at three levels: the laboratory performing the analysis, the USGS QC officer, and the principal investigator for the study. This level of review resulted in an average of one QC sample for every 20 field samples, which proved to be minimally adequate for such a large-scale survey. Additional QC samples should be added to monitor within-batch quality to the extent that no more than 10 samples are analyzed between a QC sample. Only Cr (77%), Y (82%), and Sb (80%) fell outside the acceptable limits of accuracy (% recovery between 85 and 115%) because of likely residence in mineral phases resistant to the acid digestion. A separate sample of 0-5-cm material was collected at each site for determination of organic compounds. A subset of 73 of these samples was analyzed for a suite of

Development of thermodynamic databases and geochemical/transport models for prediction of long-term radionuclide migration (Germany)

International Nuclear Information System (INIS)

Kienzler, B.

2000-01-01

The isolation capacity of a repository system for radionuclides is described by geochemical modeling. The models for interpretation of experimental findings and for long-term extrapolation of experimental results are based on thermodynamic approaches. The geochemical models include dissolution reactions of waste forms, the evolution of the geochemical milieu, interactions of radionuclides with constituents of the groundwater (brines) and the precipitation of new solid phases. Reliable thermodynamic data, understanding of radionuclide complexation in aqueous multi-electrolyte solutions at the relevant ionic strength and knowledge on the formation of pure and mixed solids and on sorption processes are urgently needed for such model calculations. (author)

High-level radioactive waste disposal: Key geochemical issues and information needs for site characterization

International Nuclear Information System (INIS)

Brooks, D.J.; Bembia, P.J.; Bradbury, J.W.; Jackson, K.C.; Kelly, W.R.; Kovach, L.A.; Mo, T.; Tesoriero, J.A.

1986-01-01

Geochemistry plays a key role in determining the potential of a high-level radioactive waste disposal site for long-term radionuclide containment and isolation. The Nuclear Regulatory Commission (NRC) has developed a set of issues and information needs important for characterizing geochemistry at the potential sites being investigated by the Department of Energy Basalt Waste Isolation Project, Nevada Nuclear Waste Storage Investigations project, and Salt Repository Project. The NRC site issues and information needs consider (1) the geochemical environment of the repository, (2) changes to the initial geochemical environment caused by construction and waste emplacement, and (3) interactions that affect the transport of waste radionuclides to the accessible environment. The development of these issues and information needs supports the ongoing effort of the NRC to identify and address areas of geochemical data uncertainty during prelicensing interactions

A Guide for Using Geochemical Methods in Dredged Material, Sediment Tracking, and Sediment Budget Studies

Science.gov (United States)

2017-06-26

geochemical markers such as radioisotopes and stable isotopes, organic matter, and mineralogy/elemental composition are recognized and established methods ...further elucidate the original erosion source of accumulating sediment (Hoefs 2009). 2.3 Radioisotopes Radioisotopic dating is based on measuring the...ER D C TR -1 7- 3 Dredging Operations and Environmental Research Program A Guide for Using Geochemical Methods in Dredged Material

Information needs of the exploration geoscientist - proceedings

Energy Technology Data Exchange (ETDEWEB)

Campbell, G.E. (ed.)

1984-01-01

Papers were presented describing the data bases of exploration data which have been created by the following Australian organisations: Bureau of Mineral Resources; Geological Survey of Western Australia; Northern Territory Geological Survey; South Australian Department of Mines and Energy; Tasmanian Department of Mines; Geological Survey of Queensland; South Australian Land Information System; New South Wales Department of Mineral Resources; Shell; and Western Mining Corporation. The information needs of Australian mineral and petroleum exploration companies were discussed.

Spatial data analysis for exploration of regional scale geothermal resources

Science.gov (United States)

Moghaddam, Majid Kiavarz; Noorollahi, Younes; Samadzadegan, Farhad; Sharifi, Mohammad Ali; Itoi, Ryuichi

2013-10-01

Defining a comprehensive conceptual model of the resources sought is one of the most important steps in geothermal potential mapping. In this study, Fry analysis as a spatial distribution method and 5% well existence, distance distribution, weights of evidence (WofE), and evidential belief function (EBFs) methods as spatial association methods were applied comparatively to known geothermal occurrences, and to publicly-available regional-scale geoscience data in Akita and Iwate provinces within the Tohoku volcanic arc, in northern Japan. Fry analysis and rose diagrams revealed similar directional patterns of geothermal wells and volcanoes, NNW-, NNE-, NE-trending faults, hotsprings and fumaroles. Among the spatial association methods, WofE defined a conceptual model correspondent with the real world situations, approved with the aid of expert opinion. The results of the spatial association analyses quantitatively indicated that the known geothermal occurrences are strongly spatially-associated with geological features such as volcanoes, craters, NNW-, NNE-, NE-direction faults and geochemical features such as hotsprings, hydrothermal alteration zones and fumaroles. Geophysical data contains temperature gradients over 100 °C/km and heat flow over 100 mW/m2. In general, geochemical and geophysical data were better evidence layers than geological data for exploring geothermal resources. The spatial analyses of the case study area suggested that quantitative knowledge from hydrothermal geothermal resources was significantly useful for further exploration and for geothermal potential mapping in the case study region. The results can also be extended to the regions with nearly similar characteristics.

Exploring the Application of Volunteered Geographic Information to Catchment Management: a Survey Approach

Science.gov (United States)

Paudyal, D. R.; McDougall, K.; Apan, A.

2012-07-01

The participation and engagement of grass-root level community groups and citizens for natural resource management has a long history. With recent developments in ICT tools and spatial technology, these groups are seeking a new opportunity to manage natural resource data. There are lot of spatial information collected/generated by landcare groups, land holders and other community groups at the grass-root level through their volunteer initiatives. State government organisations are also interested in gaining access to this spatial data/information and engaging these groups to collect spatial information under their mapping programs. The aim of this paper is to explore the possible utilisation of volunteered geographic information (VGI) for catchment management activities. This research paper discusses the importance of spatial information and spatial data infrastructure (SDI) for catchment management and the emergence of VGI. A conceptual framework has been developed to illustrate how these emerging spatial information applications and various community volunteer activities can contribute to a more inclusive spatial data infrastructure (SDI) development at local level. A survey of 56 regional NRM bodies in Australia was utilised to explore the current community-driven volunteer initiatives for NRM activities and the potential of utilisation of VGI initiatives for NRM decision making process. This research paper concludes that VGI activities have great potential to contribute to SDI development at the community level to achieve better natural resource management (NRM) outcomes.

The Nasca and Palpa geoglyphs: geophysical and geochemical data

Science.gov (United States)

Hartsch, Kerstin; Weller, Andreas; Rosas, Silvia; Reppchen, Gunter

2009-10-01

The Nasca geoglyphs in the stone desert in southern Peru are part of our world cultural heritage. These remarkable drawings have roused the interest of scientists from different disciplines. Here we report the results of integrated geophysical, petrophysical, mineralogical, and geochemical investigations of the geoglyphs at six test sites in the stone desert around Nasca and Palpa. The geomagnetic measurements revealed clear indications of subsurface structures that differ from the visible surface geoglyphs. The high-resolution geoelectrical images show unexpected resistivity anomalies underneath the geoglyphs down to a depth of about 2 m. Remarkable structures were revealed in both vertical and lateral directions. No evidence was found of geochemical or mineralogical alterations of the natural geogenic materials (desert pavement environment versus geoglyphs). Neither salts nor other mineral materials were used by the Nasca people to alter or prepare the surfaces of geoglyphs. This supports the hypothesis that the Nasca people simply removed stone material down to the natural hard pan horizon to create the geoglyphs.