WorldWideScience

Sample records for surface mass concentration

  1. Estimation of surface area concentration of workplace incidental nanoparticles based on number and mass concentrations

    Science.gov (United States)

    Park, J. Y.; Ramachandran, G.; Raynor, P. C.; Kim, S. W.

    2011-10-01

    Surface area was estimated by three different methods using number and/or mass concentrations obtained from either two or three instruments that are commonly used in the field. The estimated surface area concentrations were compared with reference surface area concentrations (SAREF) calculated from the particle size distributions obtained from a scanning mobility particle sizer and an optical particle counter (OPC). The first estimation method (SAPSD) used particle size distribution measured by a condensation particle counter (CPC) and an OPC. The second method (SAINV1) used an inversion routine based on PM1.0, PM2.5, and number concentrations to reconstruct assumed lognormal size distributions by minimizing the difference between measurements and calculated values. The third method (SAINV2) utilized a simpler inversion method that used PM1.0 and number concentrations to construct a lognormal size distribution with an assumed value of geometric standard deviation. All estimated surface area concentrations were calculated from the reconstructed size distributions. These methods were evaluated using particle measurements obtained in a restaurant, an aluminum die-casting factory, and a diesel engine laboratory. SAPSD was 0.7-1.8 times higher and SAINV1 and SAINV2 were 2.2-8 times higher than SAREF in the restaurant and diesel engine laboratory. In the die casting facility, all estimated surface area concentrations were lower than SAREF. However, the estimated surface area concentration using all three methods had qualitatively similar exposure trends and rankings to those using SAREF within a workplace. This study suggests that surface area concentration estimation based on particle size distribution (SAPSD) is a more accurate and convenient method to estimate surface area concentrations than estimation methods using inversion routines and may be feasible to use for classifying exposure groups and identifying exposure trends.

  2. Estimation of surface area concentration of workplace incidental nanoparticles based on number and mass concentrations

    International Nuclear Information System (INIS)

    Park, J. Y.; Ramachandran, G.; Raynor, P. C.; Kim, S. W.

    2011-01-01

    Surface area was estimated by three different methods using number and/or mass concentrations obtained from either two or three instruments that are commonly used in the field. The estimated surface area concentrations were compared with reference surface area concentrations (SA REF ) calculated from the particle size distributions obtained from a scanning mobility particle sizer and an optical particle counter (OPC). The first estimation method (SA PSD ) used particle size distribution measured by a condensation particle counter (CPC) and an OPC. The second method (SA INV1 ) used an inversion routine based on PM1.0, PM2.5, and number concentrations to reconstruct assumed lognormal size distributions by minimizing the difference between measurements and calculated values. The third method (SA INV2 ) utilized a simpler inversion method that used PM1.0 and number concentrations to construct a lognormal size distribution with an assumed value of geometric standard deviation. All estimated surface area concentrations were calculated from the reconstructed size distributions. These methods were evaluated using particle measurements obtained in a restaurant, an aluminum die-casting factory, and a diesel engine laboratory. SA PSD was 0.7–1.8 times higher and SA INV1 and SA INV2 were 2.2–8 times higher than SA REF in the restaurant and diesel engine laboratory. In the die casting facility, all estimated surface area concentrations were lower than SA REF . However, the estimated surface area concentration using all three methods had qualitatively similar exposure trends and rankings to those using SA REF within a workplace. This study suggests that surface area concentration estimation based on particle size distribution (SA PSD ) is a more accurate and convenient method to estimate surface area concentrations than estimation methods using inversion routines and may be feasible to use for classifying exposure groups and identifying exposure trends.

  3. Comparison of two estimation methods for surface area concentration using number concentration and mass concentration of combustion-related ultrafine particles

    Science.gov (United States)

    Park, Ji Young; Raynor, Peter C.; Maynard, Andrew D.; Eberly, Lynn E.; Ramachandran, Gurumurthy

    Recent research has suggested that the adverse health effects caused by nanoparticles are associated with their surface area (SA) concentrations. In this study, SA was estimated in two ways using number and mass concentrations and compared with SA (SA meas) measured using a diffusion charger (DC). Aerosol measurements were made twice: once starting in October 2002 and again starting in December 2002 in Mysore, India in residences that used kerosene or liquefied petroleum gas (LPG) for cooking. Mass, number, and SA concentrations and size distributions by number were measured in each residence. The first estimation method (SA PSD) used the size distribution by number to estimate SA. The second method (SA INV) used a simple inversion scheme that incorporated number and mass concentrations while assuming a lognormal size distribution with a known geometrical standard deviation. SA PSD was, on average, 2.4 times greater (range = 1.6-3.4) than SA meas while SA INV was, on average, 6.0 times greater (range = 4.6-7.7) than SA meas. The logarithms of SA PSD and SA INV were found to be statistically significant predictors of the logarithm of SA meas. The study showed that particle number and mass concentration measurements can be used to estimate SA with a correction factor that ranges between 2 and 6.

  4. Determination of particle concentration rankings by spatial mapping of particle surface area, number, and mass concentrations in a restaurant and a die casting plant.

    Science.gov (United States)

    Park, Ji Young; Ramachandran, Gurumurthy; Raynor, Peter C; Olson, Gregory M

    2010-08-01

    Measurements using several exposure metrics were carried out in a restaurant and a die casting plant to compare the spatial distributions of particle surface area (SA), number, and mass concentrations and rank exposures in different areas by those metrics. The different exposure metrics for incidental nanoparticle and fine particle exposures were compared using the concentration rankings, statistical differences between areas, and concentration ratios between different areas. In the die casting plant, area concentration rankings and spatial distributions differed by the exposure metrics chosen. Surface area and fine particle number concentrations were greatest near incidental nanoparticle sources and were significantly different between three areas. However, mass and coarse particle number concentrations were similar throughout the facility, and rankings of the work areas based on these metrics were different from those of SA and fine number concentrations. In the restaurant, concentrations in the kitchen for all metrics except respirable mass concentration were significantly greater than in the serving area, although SA and fine particle number concentrations showed larger differences between the two areas than either the mass or coarse particle number concentrations. Thus, the choice of appropriate exposure metric has significant implications for exposure groupings in epidemiologic and occupational exposure studies.

  5. Size segregated aerosol mass concentration measurements over ...

    Indian Academy of Sciences (India)

    Mass concentration and mass size distribution of total (composite) aerosols near the surface are essential inputs needed in developing aerosol models for radiative forcing estimation as well as to infer the environment and air quality. Using extensive measurements onboard the oceanographic research vessel, Sagar Kanya ...

  6. Differences in activity level between cownose rays (Rhinoptera bonasus) and Atlantic stingrays (Dasyatis sabina) are related to differences in heart mass, hemoglobin concentration, and gill surface area.

    Science.gov (United States)

    Grim, Jeffrey M; Ding, A Adam; Bennett, Wayne A

    2012-10-01

    Aquatic animals are faced with the challenge of extracting oxygen from water, a medium that is metabolically expensive to ventilate and that contains just a fraction of the oxygen concentration relative to air, yet the physiologies of fishes have evolved to support a wide range of activity levels in nature. Oxygen delivery components, including gill surface area (oxygen uptake), blood chemistry (oxygen transport), and the heart (system pump), have been positively correlated to activity level in teleost fishes, yet relatively little is known about how these components are related to activity in elasmobranches. The current study addresses this question by examining heart mass, hemoglobin concentration, hematocrit level, and gill surface area in wild-caught representatives of the benthic Atlantic stingray (Dasyatis sabina) and active cownose ray (Rhinoptera bonasus). Allometric scaling exponents are similar for all four measures between the study species. Heart mass, gill surfaces areas, and hemoglobin concentrations were 2.1 times, approximately 7.1 times, and 2.0 times higher, respectively, in active cownose rays, when compared to benthic Atlantic stingrays, after correcting for differences in body mass. When considered in the context of functional plasticity within the oxygen delivery systems of benthic and active species, data from the current study indicate that higher activity levels in cownose rays are supported by modifications that, at least in part, are likely to enhance oxygen uptake.

  7. Real Time Cascade Impactor Based On Surface Acoustic Wave Delay Lines for PM10 and PM2.5 Mass Concentration Measurement.

    Science.gov (United States)

    Djoumi, Lyes; Vanotti, Meddy; Blondeau-Patissier, Virginie

    2018-01-16

    In this research, Surface Acoustic Wave (SAW) sensors are combined with a cascade impactor to perform real time PM10 and PM2.5 mass concentration measurements. The SAW sensors consist of 125 MHz delay lines based on Love waves propagating on an AT-cut quartz substrate. The Love waves are guided on the substrate's surface using a silica layer. SAW sensors themselves are not capable to discriminate particles by their size, therefore, particle separation based on aerodynamic diameter is achieved using a 3 Lpm dedicated cascade impactor. The latter was designed to integrate the SAW sensors which are monitored using a phase shift measurement. The collected particles impact on the acoustic sensor's surface inducing a gravimetric effect that modifies the acoustic wave propagation conditions. The resulted phase shift allows the measurement of the mass deposited on the sensitive zone. The novel cascade impactor with SAW sensors as particle collecting stages is exposed to different aerosols in the 0-150 μg/m³ concentration range and proved to be able to detect and differentiate particles based on their size in real time. The system's response was compared to a commercial optical counter based on light scattering technology and was found to be in good agreement with it.

  8. Size segregated aerosol mass concentration measurements over ...

    Indian Academy of Sciences (India)

    significant variations were observed over central and northern Arabian Sea as well as close to .... Arabian Sea. 4. Results and discussion. Total aerosol mass concentration (MT = Σmi, where mi is the mass concentration on the individ- ual stages) varied from the ..... Twomey S A 1977 The influence of pollution on the short-.

  9. Evaluation of on-line concentration coupled to liquid chromatography tandem mass spectrometry for the quantification of neonicotinoids and fipronil in surface water and tap water.

    Science.gov (United States)

    Montiel-León, Juan Manuel; Duy, Sung Vo; Munoz, Gabriel; Amyot, Marc; Sauvé, Sébastien

    2018-03-05

    A study was initiated to investigate a fast and reliable method for the determination of selected systemic insecticides in water matrixes and to evaluate potential sources of bias in their analysis. Acetamiprid, clothianidin, desnitro-imidacloprid, dinotefuran, fipronil, imidacloprid, nitenpyram, thiacloprid, and thiamethoxam were amenable to analysis via on-line sample enrichment hyphenated to ultra-high-performance liquid chromatography tandem mass spectrometry. The selection of on-line solid-phase extraction parameters was dictated by a multicriterion desirability approach. A 2-mL on-line injection volume with a 1500 μL min -1 loading flow rate met the objectives sought in terms of chromatographic requirements, extraction efficiency, sensitivity, and precision. A total analysis time of 8 min per sample was obtained with method limits of detection in the range of 0.1-5 ng L -1 for the scope of targeted analytes. Automation at the sample concentration step yielded intraday and interday precisions in the range of 1-23 and 2-26%, respectively. Factors that could affect the whole method accuracy were further evaluated in matrix-specific experiments. The impact of the initial filtration step on analyte recovery was evaluated in ultra-pure water, tap water, and surface water. Out of the nine membranes tested, glass fiber filters and polyester filters appeared as the most appropriate materials. Sample storage stability was also investigated across the three matrix types; the targeted analytes displayed suitable stability during 28 days at either 4 °C or - 20 °C, with little deviations (± 10%) with respect to the initial T 0 concentration. Method applicability was demonstrated in a range of tap water and surface water samples from the province of Québec, Canada. Results from the present survey indicated a predominance of thiamethoxam (tap water and river water, respectively), clothianidin (tap water and river water, respectively), and imidacloprid (tap

  10. Total mass and concentration of particles in dust clouds

    International Nuclear Information System (INIS)

    Gutmacher, R.G.; Higgins, G.H.; Tewes, H.A.

    1983-03-01

    The clouds from seven Pacific Proving Grounds nuclear tests and two Plowshare cratering experiments have been sampled to determine the mass loading of the clouds. The average value for the total mass of debris from surface bursts of megaton yield is 0.2 Mt mass/Mt yield; the measured particle concentration in air ranges from 6 x 10 -10 to 7 x 10 -9 g/cm 3 . The mass of debris per unit yield from cratering explosions is about two orders of magnitude higher than is the case for surface bursts, but only a small percentage of the mass is still present in the cloud after a few minutes. The average concentration of dust in explosion-produced clouds is in the same range as the mass concentration measured in naturally occurring high tropospheric clouds

  11. Isotope analysis of U using surface ionization mass spectrometry

    International Nuclear Information System (INIS)

    Cesario, Jean

    Surface ionization mass spectrometry is a good technique for the determination of U isotope concentrations. The principles of the method are described: ionization, optical systems, measuring systems. The sensitivity and accuracy of the method are presented [fr

  12. Effect of pesticides on surface ozone concentration

    International Nuclear Information System (INIS)

    Farag, S.A.; Rizk, H.F.S.; Elbahnasawy, R.M.; Meleigy, M.I.

    1992-01-01

    A comparative study through seasonal variation of surface ozone concentration was carried out recently (1991-1992) at a background area free from expected urban pollutants (Shebin ElKom) and industrial and urban areas (Cairo). Surface ozone concentrations in ppb were generally lower in such area compared with urban or industrial areas studied through the comparative seasonal variations. Notable smog values (>100 ppb) of hourly surface ozone concentrations appeared during summer season in this rural area; during this season, some pesticides were sprayed over cotton and other crops fields in near by agricultural areas. The unexpected jump in the values of diurnal concentrations of surface ozone in that area may be due to the photochemical reactions of these organic pesticides in the atmosphere. 1 fig, 3 tab

  13. GADEP Continuous PM2.5 mass concentration data, VIIRS Day Night Band SDR (SVDNB), MODIS Terra Level 2 water vapor profiles (infrared algorithm for atmospheric profiles for both day and night, NWS surface meteorological data

    Data.gov (United States)

    U.S. Environmental Protection Agency — Data descriptions are provided at the following urls: GADEP Continuous PM2.5 mass concentration data - https://aqs.epa.gov/aqsweb/documents/data_mart_welcome.html...

  14. Variations of surface ozone concentration across the Klang Valley, Malaysia

    Science.gov (United States)

    Latif, Mohd Talib; Huey, Lim Shun; Juneng, Liew

    2012-12-01

    Hourly air quality data covering the period 2004-2008 was obtained from the Air Quality Division, the Department of Environment (DOE) through long-term monitoring by Alam Sekitar Sdn. Bhd. (ASMA) were analysed to investigate the variations of surface ozone (O3) in the Klang Valley, Malaysia. A total of nine monitoring stations were selected for analysis in this study and the results show that there are distinct seasonal patterns in the surface O3 across the Klang Valley. A high surface O3 concentration is usually observed between January and April, while a low surface O3 concentration is found between June and August. Analysis of daily variations in surface O3 and the precursors - NO, NO2, CO, NMHC and UVb, indicate that the surface O3 photochemistry in this study area exhibits a positive response to the intensity and wavelength in UVb while being influenced by the concentration of NOx, particularly through tritration processes. Although results from our study suggested that NMHCs may influence the maximum O3 concentration, further investigation is required. Wind direction during different monsoons was found to influence the concentration of O3 around the Klang Valley. HYSPLIT back trajectories (-72 h) were used to indicate the air-mass transport patterns on days with high concentrations of surface O3 in the study area. Results show that 47% of the high O3 days was associated with the localized circulation. The remaining 32% and 22% were associated with mid-range and long-range transport across the South China Sea from the northeast.

  15. Concentration of involatile salts at evaporating water surfaces

    International Nuclear Information System (INIS)

    Gardner, G.C.

    1988-02-01

    Safety cases for the PWR often need to know how much of the soluble salts in the water will evaporate with the steam during flashing and when the steam is discharged to the atmosphere. Some ideal evaporating systems to give guidance. Simple formulae are derived for the surface concentration relative to the bulk concentration. An analysis is also presented which derives a formula for the mass transfer process in the steam due to both diffusion and convection, which arises from the evaporation process. The convection process will usually dominate. (author)

  16. Mass loading of soil particles on plant surfaces

    International Nuclear Information System (INIS)

    Pinder, J.E. III; McLeod, K.W.

    1989-01-01

    Radionuclide-bearing soil particles on plant surfaces can be ingested and contribute to human dose, but evaluating the potential dose is limited by the relatively few data available on the masses of soil particles present on plant surfaces. This report summarizes mass loading data (i.e., mass of soil per unit of vegetation) for crops in the southeastern United States and compares these data to (1) those from other regions and (2) the mass loadings used in radionuclide transfer models to predict soil contamination of plant surfaces. Mass loadings were estimated using the 238Pu content of crops as an indicator of soil on plant surfaces. Crops were grown in two soils: a sandy clay loam soil and a loamy sand soil. Concentrations of soil on southeastern crops (i.e., mg soil g-1 plant) differed by more than a factor of 100 due to differences in crop growth form and biomass. Mean concentrations ranged from 1.7 mg g-1 for corn to 260 mg g-1 for lettuce. Differences in mass loadings between soils were less than those among crops. Concentrations differed by less than a factor of two between the two soil types. Because of (1) the differences among crops and (2) the limited data available from other systems, it is difficult to draw conclusions regarding regional or climatic variation in mass loadings. There is, however, little evidence to suggest large differences among regions. The mass loadings used to predict soil contamination in current radionuclide transfer models appear to be less than those observed for most crops

  17. Surface ionization mass spectrometry of opiates

    International Nuclear Information System (INIS)

    Usmanov, D.T.

    2009-07-01

    Key words: surface ionization, adsorption, heterogeneous reactions, surface ionization mass spectrometry, thermodesorption surface ionization spectroscopy, thermoemitter, opiates, extracts of biosamples. Subjects of study. The mass - spectrometric study of thermal - ion emission: surface ionization of opiates by on the surface of oxidized refractory metals. Purpose of work is to establish the regularities of surface ionization (SI) of multi-atomic molecule opiates and their mixtures develop the scientific base of SI methods for high sensitive and selective detection and analysis of these substances in the different objects, including biosamples. Methods of study: surface ionization mass spectrometry, thermodesorption surface ionization spectroscopy. The results obtained and their novelty. For the first time, SI of molecule opiates on the oxidized tungsten surface has been studied and their SI mass-spectra and temperature dependences of ion currents have been obtained, the characteristic heterogeneous reactions of an adsorbed molecules and the channels of monomolecular decays vibrationally-excited ions on their way in mass-spectrometry have been revealed, sublimation energy has been defined, the activation energy of E act , of these decays has been estimated for given period of time. Additivity of the SI mass-spectra of opiate mixtures of has been established under conditions of joint opiate adsorption. High selectivity of SI allows the extracts of biosamples to be analyzed without their preliminary chromatographic separation. The opiates are ionized by SI with high efficiency (from 34 C/mol to 112 C/mol), which provides high sensitivity of opiate detection by SI/MS and APTDSIS methods from - 10 -11 g in the samples under analysis. Practical value. The results of these studies create the scientific base for novel SI methods of high sensitive detection and analysis of the trace amounts of opiates in complicated mixtures, including biosamples without their preliminary

  18. Comparison of microconcentric and membrane-desolvation sample introduction systems for determination of low rare earth element concentrations in surface and subsurface waters using sector field inductively coupled plasma mass spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Chung, C.-H. [Department of Earth Sciences and Earth Dynamic System Research Center (EDSRC), National Cheng Kung University, Tainan, 70101, Taiwan (China); Brenner, Isaac [Department of Earth Sciences and Earth Dynamic System Research Center (EDSRC), National Cheng Kung University, Tainan, 70101, Taiwan (China)], E-mail: Brenner@cc.huji.ac.il; You, C.-F. [Department of Earth Sciences and Earth Dynamic System Research Center (EDSRC), National Cheng Kung University, Tainan, 70101, Taiwan (China)

    2009-09-15

    Analytical performances of a microconcentric nebulizer (MCN) and a membrane-desolvation sample introduction system (Aridus) were compared for determination of low concentrations of rare earth elements (REEs) in surface and subsurface waters using a double focusing sector field inductively coupled plasma mass spectrometer. Conventional figures of merit were employed, such as sensitivities, limits of detection (LOD), REE-O{sup +} formation, matrix induced interferences, long term signal variations, and recovery from spiked sea water samples and a pristine water CRM. Sensitivity as a function of mass for the MCN was quite flat with the exception of light REE (LREE{sup +}) which was dependent on REE-O{sup +} generation. Signal responses using the Aridus were enhanced by factors of 4-10. Large sensitivity enhancements were observed for {sup 139}La{sup +}, {sup 140}Ce{sup +} and {sup 141}Pr{sup +}, due to the attenuation of their REE-O{sup +} (where the Aridus {sup 140}Ce{sup 16}O{sup +}/{sup 140}Ce{sup +} was three orders of magnitude lower than that determined using the MCN) as a result of water analysis reduction in the plasma. Despite higher sensitivities, Aridus LODs were not significantly different from those obtained using the MCN, and values varied from 0.05 to 0.2 ng L{sup - 1} and 0.1 to 0.2 ng L{sup - 1} for the MCN and Aridus systems, respectively. When using the MCN, LREE{sup +} signals were closely associated with REE-O bond strengths, implying that LREE-O{sup +} production and breakdown are related to the strength of REE-O bonds in REE-O{sup +} ions suggesting that medium REE (MREE)-O{sup +} and heavy REE (HREE)-O{sup +} if formed, were thermally unstable in the plasma. In the presence of conservative Na concentrations, MCN LREE{sup +} signal suppressions varied from about 15 to 25% and about 5 to 10% for MREE{sup +} and HREE{sup +}. In contrast, regular 15% signal suppressions for all REE{sup +} were observed for the Aridus. In the case of the MCN, more

  19. [Relationship between dust mass concentration and fiber number concentration of refractory ceramic fibers].

    Science.gov (United States)

    Zhu, Xiaojun; Li, Tao; Wang, Hongfei

    2015-04-01

    To explore the quantitative relationship between the dust mass concentration and fiber number concentration of refractory ceramic fibres. A typical refractory ceramic fiber plant was selected as the study site. Fifty-three paired samples of total dust mass concentration and fiber number concentration were collected using the long-time fixed site mode. The total dust mass concentration was measured according to the GBZ/T 192.1-2007 (Measurement of dust in the air of workplace, part 1: Total dust concentration). Membrane filter method/phase-contrast optical microscopy was used to determine the fiber number concentration. Univariate analysis was used to describe the distribution of the two concentrations and their ratio. Spearman rank correlation, as well as linear regression, logarithmic curve, polynomial, power function, and exponential curve model, were used to explore the relationship between the two concentrations. Results The range of the total dust mass concentration (x) was 0.45-13.82 mg/m3. The range of the fiber number concentration (y) was 0.01-1.04 f/ml. The range of the ratio (x/y) was 4-158. All of the three parameters did not follow normal distribution (Pfiber number concentration of refractory ceramic fibers. However, there is no fixed regression relationship between the two concentrations, and neither is a definite coefficient which can be used to convert each other. The two concentrations cannot be replaced by each other.

  20. Physicochemical properties of concentrated Martian surface waters

    Science.gov (United States)

    Tosca, Nicholas J.; McLennan, Scott M.; Lamb, Michael P.; Grotzinger, John P.

    2011-05-01

    Understanding the processes controlling chemical sedimentation is an important step in deciphering paleoclimatic conditions from the rock records preserved on both Earth and Mars. Clear evidence for subaqueous sedimentation at Meridiani Planum, widespread saline mineral deposits in the Valles Marineris region, and the possible role of saline waters in forming recent geomorphologic features all underscore the need to understand the physical properties of highly concentrated solutions on Mars in addition to, and as a function of, their distinct chemistry. Using thermodynamic models predicting saline mineral solubility, we generate likely brine compositions ranging from bicarbonate-dominated to sulfate-dominated and predict their saline mineralogy. For each brine composition, we then estimate a number of thermal, transport, and colligative properties using established models that have been developed for highly concentrated multicomponent electrolyte solutions. The available experimental data and theoretical models that allow estimation of these physicochemical properties encompass, for the most part, much of the anticipated variation in chemistry for likely Martian brines. These estimates allow significant progress in building a detailed analysis of physical sedimentation at the ancient Martian surface and allow more accurate predictions of thermal behavior and the diffusive transport of matter through chemically distinct solutions under comparatively nonstandard conditions.

  1. On the adsorbed mass of polymers on surfaces (NOTE

    Directory of Open Access Journals (Sweden)

    GEORGIOS K. STRATOURAS

    2001-06-01

    Full Text Available It is shown that for ideal polymers interacting with a surface via the pseudopotential of a delta function, the number of contacts between the monomer units and the surface as a function of concentration cb is a dependence of the form acb/(1–bcb. The architecture of the polymer, the degree of polymerization, the interaction energy between a monomer unit and the surface, the area of the surface and the monomer length are embodied in the parameters a and b. The above dependence of the adsorbed mass of a polymer on the concentration is confirmed by the experimental results of Takahashi and his collaborators. For linear polystyrene of molecular weight 134×105,interacting with a chrome plate, the parameters a and b are, respectively, about equal to (89938/273 ×10-6 m and (–19300/273 m3 kg-1.

  2. Satellite constraints on surface concentrations of particulate matter

    Science.gov (United States)

    Ford Hotmann, Bonne

    Because of the increasing evidence of the widespread adverse effects on human health from exposure to poor air quality and the recommendations of the World Health Organization to significantly reduce PM2.5 in order to reduce these risks, better estimates of surface air quality globally are required. However, surface measurements useful for monitoring particulate exposure are scarce, especially in developing countries which often experience the worst air pollution. Therefore, other methods are necessary to augment estimates in regions with limited surface observations. The prospect of using satellite observations to infer surface air quality is attractive; however, it requires knowledge of the complicated relationship between satellite-observed aerosol optical depth (AOD) and surface concentrations. This dissertation explores how satellite observations can be used in conjunction with a chemical transport model (GEOS-Chem) to better understand this relationship. First, we investigate the seasonality in aerosols over the Southeastern United States using observations from several satellite instruments (MODIS, MISR, CALIOP) and surface network sites (IMPROVE, SEARCH, AERONET). We find that the strong summertime enhancement in satellite-observed aerosol optical depth (factor 2-3 enhancement over wintertime AOD) is not present in surface mass concentrations (25-55% summertime enhancement). Goldstein et al. [2009] previously attributed this seasonality in AOD to biogenic organic aerosol; however, surface observations show that organic aerosol only accounts for ~35% of PM2.5 mass and exhibits similar seasonality to total surface PM2.5. The GEOS-Chem model generally reproduces these surface aerosol measurements, but under represents the AOD seasonality observed by satellites. We show that seasonal differences in water uptake cannot sufficiently explain the magnitude of AOD increase. As CALIOP profiles indicate the presence of additional aerosol in the lower troposphere

  3. Simple method for estimating soil mass loading onto plant surface using magnetic material content as a soil indicator - Influence of soil adhesion to vegetation on radioactive cesium concentration in forage.

    Science.gov (United States)

    Sunaga, Yoshihito; Harada, Hisatomi

    2016-11-01

    A simple technique for estimating soil mass loading on vegetation was developed using magnetic material content as an indicator of soil adhesion. Magnetic material contents in plant and soil samples were determined by a magnetic analyzer. High recovery rates of 85-97% were achieved in a recovery test in which additional soil was added to powdered plant materials [stem of forage corn (Zea mays L.), aboveground part of Italian ryegrass (Lolium multiflorum Lam.)] at addition rates of 12.3-200 g dry soil kg -1 dry plant material including soil. Samples of different Japanese cultivated soils were tested and showed a range of magnetic contents of 1.27-16.1 g kg -1 on a dry weight basis. These levels are considered adequate for determining soil contamination in plant materials. Then, we applied this method for confirming the effect of soil adhesion on radioactive cesium concentrations in plant samples obtained at the area affected by the 2011 nuclear accident in Japan. The mean soil mass loading (±standard deviation) on forage rye (Secale cereale L.) showing mild lodging was 0.8 ± 0.6 g kg -1 , but was 7.4 ± 5.0 g kg -1 for plants with serious lodging. No soil loading was detected on rye plants that showed no lodging. Radioactive cesium concentrations in the rye samples increased linearly with the increase in soil mass loading caused by plant lodging, and consequently mean radioactive cesium concentration for rye plants with serious lodging was about 2.7 times higher than that with no lodging. Cesium radioactivity in forage was affected by variations in soil mass loading onto forage plants caused by changes in plant growth and differences between plant species. Copyright © 2016 Elsevier Ltd. All rights reserved.

  4. Workplace aerosol mass concentration measurement using optical particle counters.

    Science.gov (United States)

    Görner, Peter; Simon, Xavier; Bémer, Denis; Lidén, Göran

    2012-02-01

    Direct-reading aerosol measurement usually uses the optical properties of airborne particles to detect and measure particle concentration. In the case of occupational hygiene, mass concentration measurement is often required. Two aerosol monitoring methods are based on the principle of light scattering: optical particle counting (OPC) and photometry. The former analyses the light scattered by a single particle, the latter by a cloud of particles. Both methods need calibration to transform the quantity of scattered light detected into particle concentration. Photometers are simpler to use and can be directly calibrated to measure mass concentration. However, their response varies not only with aerosol concentration but also with particle size distribution, which frequently contributes to biased measurement. Optical particle counters directly measure the particle number concentration and particle size that allows assessment of the particle mass provided the particles are spherical and of known density. An integrating algorithm is used to calculate the mass concentration of any conventional health-related aerosol fraction. The concentrations calculated thus have been compared with simultaneous measurements by conventional gravimetric sampling to check the possibility of field OPC calibration with real workplace aerosols with a view to further monitoring particle mass concentration. Aerosol concentrations were measured in the food industry using the OPC GRIMM® 1.108 and the CIP 10-Inhalable and CIP 10-Respirable (ARELCO®) aerosol samplers while meat sausages were being brushed and coated with calcium carbonate. Previously, the original OPC inlet had been adapted to sample inhalable aerosol. A mixed aerosol of calcium carbonate and fungi spores was present in the workplace. The OPC particle-size distribution and an estimated average particle density of both aerosol components were used to calculate the mass concentration. The inhalable and respirable aerosol fractions

  5. Toward understanding atmospheric physics impacting the relationship between columnar aerosol optical depth and near-surface PM2.5 mass concentrations in Nevada and California, U.S.A., during 2013

    Science.gov (United States)

    Loría-Salazar, S. Marcela; Panorska, Anna; Arnott, W. Patrick; Barnard, James C.; Boehmler, Jayne M.; Holmes, Heather A.

    2017-12-01

    Determining the relationship between columnar aerosol optical depth (τext) and surface particulate matter concentrations (PM2.5) is desired to estimate surface aerosol concentrations over broad spatial and temporal scales using satellite remote sensing. However, remote sensing studies incur challenges when surface aerosol pollution (i.e. PM2.5) is not correlated with columnar conditions (i.e., τext). PM2.5 data fusion models that rely on satellite data and statistical relationships of τext and PM2.5 may not be able to capture the physical conditions impacting the relationships that cause columnar and surface aerosols to not be correlated in the western U.S. Therefore, an extensive examination of the atmospheric conditions is required to improve surface estimates of PM2.5 that rely on columnar aerosol measurements. This investigation uses datasets from both routine monitoring networks and models of meteorological variables and aerosol physical parameters to understand the atmospheric conditions under which surface aerosol pollution can be explained by column measurements in California and Nevada during 2013. A novel quadrant method, that utilizes statistical analysis, was developed to investigate the relationship between τext and PM2.5. The results from this investigation show that τext and PM2.5 had a positive association (τext and PM2.5 increase together) when local sources of pollution or wildfires dominated aerosol pollution in the presence of a deep and well-mixed planetary boundary layer (PBL). Moreover, τext and PM2.5 had no association (where the variables are not related) when stable conditions, long-range transport, or entrainment of air from above the PBL were observed. It was found that seasonal categorization of the relationship between τext and PM2.5, an approach commonly used in statistical models to estimate surface concentrations with satellite remote sensing, may not be enough to account for the atmospheric conditions that drive the

  6. Contaminant mass estimation of powder contaminated surfaces

    Science.gov (United States)

    Gibbs, Timothy J.; Messinger, David W.

    2017-05-01

    How can we determine the physical characteristics of a mixture of multiple materials within a single pixel? Intimate mixing occurs when different materials within the region encompassed by a pixel interact with each other prior to reaching the sensor. For powder contaminated surfaces, nonlinear mixing is unavoidable. The Nonconventional Exploitation Factors Data System (NEFDS) Contamination Model can make longwave hyperspectral mixture signatures, but only for a small subset of their spectral library. In addition, the model uses percent coverage as its only physical property input despite it not being informative to the contaminants physical properties. Through a complex parameter inversion, the NEFDS contamination model can be used to derive various physical properties. These physical characteristics were estimated by using empirically measured data of varying contaminant amounts using a Designs and Prototypes Fourier transform infrared spectrometer. Once estimated parameters are found, the mixture spectra was recreated and compared to the measured data. The estimated areal coverage density is used to derive a total deposited mass on the surface based on the area of contaminated surface. This is compared to the known amount deposited that was measured during the experimental campaign. This paper presents some results of those measurements and model estimates.

  7. Influence of Body Mass Index on Hair Ethyl Glucuronide Concentrations.

    Science.gov (United States)

    Crunelle, Cleo L; Neels, Hugo; Maudens, Kristof; De Doncker, Mireille; Cappelle, Delphine; Matthys, Frieda; Dom, Geert; Fransen, Erik; Michielsen, Peter; De Keukeleire, Steven; Covaci, Adrian; Yegles, Michel

    2017-01-01

    Analysis of ethyl glucuronide (EtG) concentrations in hair is increasingly used to estimate the consumption of alcohol of the prior months. Linear correlations between the amount of alcohol consumed and the concentration of EtG in hair have been reported, and several variables that may influence this correlation have been investigated: e.g. cosmetic hair treatments, gender influences or hair color. Here, we investigate the influence of body mass index (BMI) on this correlation. A post hoc analysis on the influence of BMI on the relation between amounts of alcohol consumed and the measured EtG concentrations in hair in 199 participants. Our data show higher EtG concentrations in participants with high BMI (≥25) compared to participants with low BMI (hair EtG concentrations. Ethyl glucuronide concentrations in hair (hEtG) can be used to estimate the consumption of alcohol of the prior months. Body mass index (BMI) influences this relation and BMI should be taken into account when interpreting hEtG concentrations in participants with high BMI (≥25) compared to participants with low BMI (<25). © The Author 2016. Medical Council on Alcohol and Oxford University Press. All rights reserved.

  8. Stochastic evaluation of mass discharge from pointlike concentration measurements

    Science.gov (United States)

    Schwede, Ronnie L.; Cirpka, Olaf A.

    2010-01-01

    The contaminant mass discharge crossing a control plane is an important metric in the assessment of natural attenuation at contaminated sites. For risk-assessment purposes, the mass discharge must be estimated together with a level of uncertainty. We present a conditional Monte Carlo approach that allows estimating the statistical distribution of mass discharge. The approach is based on conditioning multiple realizations of the hydraulic conductivity field on all data available. We jointly determine a first-order decay coefficient in each realization, leading to conditional statistical distributions of all estimated parameters and the total mass discharge. The resulting statistical distribution of contaminant mass discharges can be used in the assessment of risks at the contaminated site. The method is applied to data of hypothetical test cases, which gives the opportunity to compare estimation results to the true field. As concentration data, we account for pointlike measurements obtained in multi-level sampling wells. The obtained empirical distribution of mass discharge crossing the multi-level sampling fence could be well fitted by a log-normal distribution.

  9. Surface sampling concentration and reaction probe

    Science.gov (United States)

    Van Berkel, Gary J; Elnaggar, Mariam S

    2013-07-16

    A method of analyzing a chemical composition of a specimen is described. The method can include providing a probe comprising an outer capillary tube and an inner capillary tube disposed co-axially within the outer capillary tube, where the inner and outer capillary tubes define a solvent capillary and a sampling capillary in fluid communication with one another at a distal end of the probe; contacting a target site on a surface of a specimen with a solvent in fluid communication with the probe; maintaining a plug volume proximate a solvent-specimen interface, wherein the plug volume is in fluid communication with the probe; draining plug sampling fluid from the plug volume through the sampling capillary; and analyzing a chemical composition of the plug sampling fluid with an analytical instrument. A system for performing the method is also described.

  10. Mass microscopy : imaging biomolecules on surfaces

    NARCIS (Netherlands)

    Luxembourg, Stefan Libertus

    2005-01-01

    Now, that mass spectrometry (MS) has been established as the analytical tool for the analysis of proteins a new challenge awaits: the development of spatial resolved mass spectrometry directly on biological tissue and cells at single cell level or beyond. The desire to study the complexity of

  11. Transport and transformation of surface water masses across the ...

    African Journals Online (AJOL)

    Transport and transformation of surface water masses across the Mascarene Plateau during the Northeast Monsoon season. ... Mixing occurs in the central gap between intermediate water masses (Red Sea Water [RSW] and Antarctic Intermediate Water [AAIW]) as well as in the upper waters (Subtropical Surface Water ...

  12. Natural variability in the surface ocean carbonate ion concentration

    OpenAIRE

    N. S. Lovenduski; M. C. Long; K. Lindsay

    2015-01-01

    We investigate variability in the surface ocean carbonate ion concentration ([CO32−]) on the basis of a long control simulation with a fully-coupled Earth System Model. The simulation is run with a prescribed, pre-industrial atmospheric CO2 concentration for 1000 years, permitting investigation of natural [CO32−] variability on interannual to multi-decadal timescales. We find high interannual variability in surface [CO32−] in the tropical...

  13. Natural variability in the surface ocean carbonate ion concentration

    OpenAIRE

    Lovenduski, N. S.; Long, M. C.; Lindsay, K.

    2015-01-01

    We investigate variability in the surface ocean carbonate ion concentration ([CO32−]) on the basis of a~long control simulation with an Earth System Model. The simulation is run with a prescribed, pre-industrial atmospheric CO2 concentration for 1000 years, permitting investigation of natural [CO32−] variability on interannual to multi-decadal timescales. We find high interannual variability in surface [CO32−] in the tropical Pacific and ...

  14. Accurate mass replacement method for the sediment concentration measurement with a constant volume container

    Science.gov (United States)

    Ban, Yunyun; Chen, Tianqin; Yan, Jun; Lei, Tingwu

    2017-04-01

    The measurement of sediment concentration in water is of great importance in soil erosion research and soil and water loss monitoring systems. The traditional weighing method has long been the foundation of all the other measuring methods and instrument calibration. The development of a new method to replace the traditional oven-drying method is of interest in research and practice for the quick and efficient measurement of sediment concentration, especially field measurements. A new method is advanced in this study for accurately measuring the sediment concentration based on the accurate measurement of the mass of the sediment-water mixture in the confined constant volume container (CVC). A sediment-laden water sample is put into the CVC to determine its mass before the CVC is filled with water and weighed again for the total mass of the water and sediments in the container. The known volume of the CVC, the mass of sediment-laden water, and sediment particle density are used to calculate the mass of water, which is replaced by sediments, therefore sediment concentration of the sample is calculated. The influence of water temperature was corrected by measuring water density to determine the temperature of water before measurements were conducted. The CVC was used to eliminate the surface tension effect so as to obtain the accurate volume of water and sediment mixture. Experimental results showed that the method was capable of measuring the sediment concentration from 0.5 up to 1200 kg m-3. A good liner relationship existed between the designed and measured sediment concentrations with all the coefficients of determination greater than 0.999 and the averaged relative error less than 0.2%. All of these seem to indicate that the new method is capable of measuring a full range of sediment concentration above 0.5 kg m-3 to replace the traditional oven-drying method as a standard method for evaluating and calibrating other methods.

  15. The music of clash: predictions on the concentration-mass relation

    International Nuclear Information System (INIS)

    Meneghetti, M.; Rasia, E.; Vega, J.; Yepes, G.; Sembolini, F.; Merten, J.; Ettori, S.; Postman, M.; Coe, D.; Donahue, M.; Umetsu, K.; Czakon, N.; Balestra, I.; Bartelmann, M.; Benítez, N.; Biviano, A.; Bouwens, R.; Bradley, L.; Broadhurst, T.; De Petris, M.

    2014-01-01

    We present an analysis of the MUSIC-2 N-body/hydrodynamical simulations aimed at estimating the expected concentration-mass relation for the CLASH (Cluster Lensing and Supernova Survey with Hubble) cluster sample. We study nearly 1,400 halos simulated at high spatial and mass resolution. We study the shape of both their density and surface-density profiles and fit them with a variety of radial functions, including the Navarro-Frenk-White (NFW), the generalized NFW, and the Einasto density profiles. We derive concentrations and masses from these fits. We produce simulated Chandra observations of the halos, and we use them to identify objects resembling the X-ray morphologies and masses of the clusters in the CLASH X-ray-selected sample. We also derive a concentration-mass relation for strong-lensing clusters. We find that the sample of simulated halos that resembles the X-ray morphology of the CLASH clusters is composed mainly of relaxed halos, but it also contains a significant fraction of unrelaxed systems. For such a heterogeneous sample we measure an average two-dimensional concentration that is ∼11% higher than is found for the full sample of simulated halos. After accounting for projection and selection effects, the average NFW concentrations of CLASH clusters are expected to be intermediate between those predicted in three dimensions for relaxed and super-relaxed halos. Matching the simulations to the individual CLASH clusters on the basis of the X-ray morphology, we expect that the NFW concentrations recovered from the lensing analysis of the CLASH clusters are in the range [3-6], with an average value of 3.87 and a standard deviation of 0.61.

  16. The MUSIC of CLASH: Predictions on the Concentration-Mass Relation

    Science.gov (United States)

    Meneghetti, M.; Rasia, E.; Vega, J.; Merten, J.; Postman, M.; Yepes, G.; Sembolini, F.; Donahue, M.; Ettori, S.; Umetsu, K.; Balestra, I.; Bartelmann, M.; Benítez, N.; Biviano, A.; Bouwens, R.; Bradley, L.; Broadhurst, T.; Coe, D.; Czakon, N.; De Petris, M.; Ford, H.; Giocoli, C.; Gottlöber, S.; Grillo, C.; Infante, L.; Jouvel, S.; Kelson, D.; Koekemoer, A.; Lahav, O.; Lemze, D.; Medezinski, E.; Melchior, P.; Mercurio, A.; Molino, A.; Moscardini, L.; Monna, A.; Moustakas, J.; Moustakas, L. A.; Nonino, M.; Rhodes, J.; Rosati, P.; Sayers, J.; Seitz, S.; Zheng, W.; Zitrin, A.

    2014-12-01

    We present an analysis of the MUSIC-2 N-body/hydrodynamical simulations aimed at estimating the expected concentration-mass relation for the CLASH (Cluster Lensing and Supernova Survey with Hubble) cluster sample. We study nearly 1,400 halos simulated at high spatial and mass resolution. We study the shape of both their density and surface-density profiles and fit them with a variety of radial functions, including the Navarro-Frenk-White (NFW), the generalized NFW, and the Einasto density profiles. We derive concentrations and masses from these fits. We produce simulated Chandra observations of the halos, and we use them to identify objects resembling the X-ray morphologies and masses of the clusters in the CLASH X-ray-selected sample. We also derive a concentration-mass relation for strong-lensing clusters. We find that the sample of simulated halos that resembles the X-ray morphology of the CLASH clusters is composed mainly of relaxed halos, but it also contains a significant fraction of unrelaxed systems. For such a heterogeneous sample we measure an average two-dimensional concentration that is ~11% higher than is found for the full sample of simulated halos. After accounting for projection and selection effects, the average NFW concentrations of CLASH clusters are expected to be intermediate between those predicted in three dimensions for relaxed and super-relaxed halos. Matching the simulations to the individual CLASH clusters on the basis of the X-ray morphology, we expect that the NFW concentrations recovered from the lensing analysis of the CLASH clusters are in the range [3-6], with an average value of 3.87 and a standard deviation of 0.61.

  17. The music of clash: predictions on the concentration-mass relation

    Energy Technology Data Exchange (ETDEWEB)

    Meneghetti, M. [INAF, Osservatorio Astronomico di Bologna, via Ranzani 1, I-40127 Bologna (Italy); Rasia, E. [Physics Department, University of Michigan, 450 Church Avenue, Ann Arbor, MI 48109 (United States); Vega, J.; Yepes, G.; Sembolini, F. [Departamento de Fsica Terica, Universidad Autnoma de Madrid, Cantoblanco, E-28049 Madrid (Spain); Merten, J.; Ettori, S. [Jet Propulsion Laboratory, California Institute of Technology, 4800 Oak Grove Drive, Pasadena, CA 91109 (United States); Postman, M.; Coe, D. [Space Telescope Science Institute, 3700 San Martin Drive, Baltimore, MD 21208 (United States); Donahue, M. [Department of Physics and Astronomy, Michigan State University, East Lansing, MI 48824 (United States); Umetsu, K.; Czakon, N. [Institute of Astronomy and Astrophysics, Academia Sinica, PO Box 23-141, Taipei 10617, Taiwan (China); Balestra, I. [INAF-Osservatorio Astronomico di Capodimonte, Via Moiariello 16, I-80131 Napoli (Italy); Bartelmann, M. [Institut fur Theoretische Astrophysik, Universität Heidelberg, Zentrum für Astronomie, Philosophenweg 12, D-69120 Heidelberg (Germany); Benítez, N. [Instituto de Astrofísica de Andalucía (CSIC), E-18080 Granada (Spain); Biviano, A. [INAF/Osservatorio Astronomico di Trieste, via G. B. Tiepolo 11, I-34143 Trieste (Italy); Bouwens, R. [Leiden Observatory, Leiden University, PO Box 9513, NL-2333 Leiden (Netherlands); Bradley, L. [Department of Physics and Astronomy, The Johns Hopkins University, 3400 North Charles Street, Baltimore, MD 21218 (United States); Broadhurst, T. [Department of Theoretical Physics and History of Science, University of the Basque Country UPV/EHU, PO Box 644, E-48080 Bilbao (Spain); De Petris, M. [Dipartimento di Fisica, Sapienza Universit di Roma, Piazzale Aldo Moro 5, I-00185 Roma (Italy); and others

    2014-12-10

    We present an analysis of the MUSIC-2 N-body/hydrodynamical simulations aimed at estimating the expected concentration-mass relation for the CLASH (Cluster Lensing and Supernova Survey with Hubble) cluster sample. We study nearly 1,400 halos simulated at high spatial and mass resolution. We study the shape of both their density and surface-density profiles and fit them with a variety of radial functions, including the Navarro-Frenk-White (NFW), the generalized NFW, and the Einasto density profiles. We derive concentrations and masses from these fits. We produce simulated Chandra observations of the halos, and we use them to identify objects resembling the X-ray morphologies and masses of the clusters in the CLASH X-ray-selected sample. We also derive a concentration-mass relation for strong-lensing clusters. We find that the sample of simulated halos that resembles the X-ray morphology of the CLASH clusters is composed mainly of relaxed halos, but it also contains a significant fraction of unrelaxed systems. For such a heterogeneous sample we measure an average two-dimensional concentration that is ∼11% higher than is found for the full sample of simulated halos. After accounting for projection and selection effects, the average NFW concentrations of CLASH clusters are expected to be intermediate between those predicted in three dimensions for relaxed and super-relaxed halos. Matching the simulations to the individual CLASH clusters on the basis of the X-ray morphology, we expect that the NFW concentrations recovered from the lensing analysis of the CLASH clusters are in the range [3-6], with an average value of 3.87 and a standard deviation of 0.61.

  18. Isotope dilution-surface ionization mass spectrometry of thallium

    International Nuclear Information System (INIS)

    Murozumi, Masayo; Nakamura, Seiji; Igarashi, Tatsushi

    1978-01-01

    An ultra-micro amount of thallium could be determined by the isotope dilution-surface ionization mass spectrometry by using 203 Tl as a spike. After thallium was separately extracted into 10 ml of 0.00125% dithizone chloroform solution from the solution of the sample isotopically equilibrated with the 203 Tl spike, it was back extracted into 5 ml of 1% nitric acid. The nitric acid solution was treated with a mixture of 0.2 ml of 14 N nitric acid and 0.1 ml of 60% perchloric acid, and evaporated to dryness in a pyrex glass oven supplied with highly pure nitrogen. The residue was dissolved in a mixture of 60 μl of water with 0.015% silica gel suspension and 5 μl of 2% phosphoric acid solution. An aliquot of this mixture was loaded onto a rhenium single filament as an ionization equipment of a Hitachi RMU-6 type mass spectrometer. The detection limit of the present method was 10 -15 -- 10 -14 g for thallium. The precision concerning mass spectroscopic analysis, as a coefficient of variation for the measurements of 205 Tl/ 203 Tl ratios, was 0.1 -- 0.5%. The application of the present method to environmental materials such as Japanese standard rocks and Orchard Leaves delivered by N.B.S. has shown that the precision of repeated analyses was 0.2 -- 0.7% for a concentration of ppm level. This method has revealed that concentration of thallium in the ocean increased with increasing depth at a ppt level. (author)

  19. Efficiency of a concentric matrix track detector surface scanning

    International Nuclear Information System (INIS)

    Bek-Uzarov, Dj.; Nikezic, D.; Kostic, D.; Krstic, D.; Cuknic, O.

    1995-01-01

    Heavy particle ionizing radiation track counting on the surface of a solid state round surface detector is made using the microscope and scanning step by step by a round field of vision. The whole solid state detector surface could not be fully or completely covered by round fields of visions. Therefore detector surface could be divided on the two parts, the larger surface, being under fields of vision, really scanned and no scanned missed or omitted surface. The ratio between omitted and scanned surfaces is so called track scanning efficiency. The knowledge of really counted, or scanned surface is a important value for evaluating the real surface track density an exposed solid state track detector. In the paper a matrix of a concentric field of vision made around the first microscope field of vision placed in center of the round disc of the scanned track detector is proposed. In a such scanning matrix the real scanned surface could be easy calculated and by the microscope scanning made as well. By this way scanned surface is very precisely obtained as well. Precise knowledge of scanned and omitted surface allows to obtain more precise scanning efficiency factor as well as real surface track density, the main parameter in solid state track detection measurements. (author)

  20. Particulate Matter Mass Concentration in Residential Prefabricated Buildings Related to Temperature and Moisture

    Science.gov (United States)

    Kraus, Michal; Juhásová Šenitková, Ingrid

    2017-10-01

    Building environmental audit and the assessment of indoor air quality (IAQ) in typical residential buildings is necessary process to ensure users’ health and well-being. The paper deals with the concentrations on indoor dust particles (PM10) in the context of hygrothermal microclimate in indoor environment. The indoor temperature, relative humidity and air movement are basic significant factors determining the PM10 concentration [μg/m3]. The experimental measurements in this contribution represent the impact of indoor physical parameters on the concentration of particulate matter mass concentration. The occurrence of dust particles is typical for the almost two-thirds of interiors of the buildings. Other parameters indoor environment, such as air change rate, volume of the room, roughness and porosity of the building material surfaces, static electricity, light ions and others, were set constant and they are not taken into account in this study. The mass concentration of PM10 is measured during summer season in apartment of residential prefabricated building. The values of global temperature [°C] and relative humidity of indoor air [%] are also monitored. The quantity of particulate mass matter is determined gravimetrically by weighing according to CSN EN 12 341 (2014). The obtained results show that the temperature difference of the internal environment does not have a significant effect on the concentration PM10. Vice versa, the difference of relative humidity exhibits a difference of the concentration of dust particles. Higher levels of indoor particulates are observed for low values of relative humidity. The decreasing of relative air humidity about 10% caused 10µg/m3 of PM10 concentration increasing. The hygienic limit value of PM10 concentration is not exceeded at any point of experimental measurement.

  1. Trapped surfaces due to concentration of gravitational radiation

    International Nuclear Information System (INIS)

    Beig, R.; O Murchadha, N.

    1991-01-01

    Sequences of global, asympotically flat solutions to the time-symmetric initial value constraints of general relativity in vacuo are constructed which develop outer trapped surfaces for large values of the argument. Thus all such configurations must gravitationally collapse. A new proof of the positivity of mass in the strong-field regime is also found. (Authors) 22 refs

  2. Concentration polarization, surface currents, and bulk advection in a microchannel

    DEFF Research Database (Denmark)

    Nielsen, Christoffer Peder; Bruus, Henrik

    2014-01-01

    We present a comprehensive analysis of salt transport and overlimiting currents in a microchannel during concentration polarization. We have carried out full numerical simulations of the coupled Poisson-Nernst-Planck-Stokes problem governing the transport and rationalized the behavior of the syst...... as in the limit of negligible surface charge. By including the effects of diffusion and advection in the diffuse part of the electric double layers, we extend a recently published analytical model of overlimiting current due to surface conduction....

  3. Retrieve Aerosol Concentration Based On Surface Model and Distribution of Concentration of PM2.5

    Science.gov (United States)

    Cui, Hongzhi

    2017-04-01

    As China's economy continues to grow, urbanization continues to advance, along with growth in all areas to pollutant emissions in the air industry, air quality also continued to deteriorate. Aerosol concentrations as a measure of air quality of the most important part of are more and more people's attention. Traditional monitoring stations measuring aerosol concentration method is accurate, but time-consuming and can't be done simultaneously measure a large area, can only rely on data from several monitoring sites to predict the concentration of the panorama. Remote Sensing Technology retrieves aerosol concentrations being by virtue of their efficient, fast advantages gradually into sight. In this paper, by the method of surface model to start with the physical processes of atmospheric transport, innovative aerosol concentration coefficient proposed to replace the traditional aerosol concentrations, pushed to a set of retrieval of aerosol concentration coefficient method, enabling fast and efficient Get accurate air pollution target area. At the same paper also monitoring data for PM2.5 in Beijing were analyzed from different angles, from the perspective of the data summarized in Beijing PM2.5 concentration of time, space, geographical distribution and concentration of PM2.5 and explored the relationship between aerosol concentration coefficient and concentration of PM2.5. Key words,Air Pollution, Aerosol concentration , PM2.5 , Retrieve

  4. Aquatic Exposure Predictions of Insecticide Field Concentrations Using a Multimedia Mass-Balance Model.

    Science.gov (United States)

    Knäbel, Anja; Scheringer, Martin; Stehle, Sebastian; Schulz, Ralf

    2016-04-05

    Highly complex process-driven mechanistic fate and transport models and multimedia mass balance models can be used for the exposure prediction of pesticides in different environmental compartments. Generally, both types of models differ in spatial and temporal resolution. Process-driven mechanistic fate models are very complex, and calculations are time-intensive. This type of model is currently used within the European regulatory pesticide registration (FOCUS). Multimedia mass-balance models require fewer input parameters to calculate concentration ranges and the partitioning between different environmental media. In this study, we used the fugacity-based small-region model (SRM) to calculate predicted environmental concentrations (PEC) for 466 cases of insecticide field concentrations measured in European surface waters. We were able to show that the PECs of the multimedia model are more protective in comparison to FOCUS. In addition, our results show that the multimedia model results have a higher predictive power to simulate varying field concentrations at a higher level of field relevance. The adaptation of the model scenario to actual field conditions suggests that the performance of the SRM increases when worst-case conditions are replaced by real field data. Therefore, this study shows that a less complex modeling approach than that used in the regulatory risk assessment exhibits a higher level of protectiveness and predictiveness and that there is a need to develop and evaluate new ecologically relevant scenarios in the context of pesticide exposure modeling.

  5. Determination of the Fundamental Frequency of Perforated Rectangular Plates: Concentrated Negative Mass Approach for the Perforation

    Directory of Open Access Journals (Sweden)

    Kiran D. Mali

    2013-01-01

    Full Text Available This paper is concerned with a vibration analysis of perforated rectangular plates with rectangular perforation pattern of circular holes. The study is particularly useful in the understanding of the vibration of sound absorbing screens, head plates, end covers, or supports for tube bundles typically including tube sheets and support plates used in the mechanical devices. An energy method is developed to obtain analytical frequencies of the perforated plates with clamped edge, support conditions. Perforated plate is considered as plate with uniformly distributed mass. Holes are considered as concentrated negative masses. The analytical procedure using the Galerkin method is adopted. The deflected surface of the plate is approximated by the cosine series which satisfies the boundary conditions. Finite element method (FEM results have been used to illustrate the validity of the analytical model. The comparisons show that the analytical model predicts natural frequencies reasonably well for holes of small size.

  6. Gravitational lensing by a smoothly variable surface mass density

    Science.gov (United States)

    Paczynski, Bohdan; Wambsganss, Joachim

    1989-01-01

    The statistical properties of gravitational lensing due to smooth but nonuniform distributions of matter are considered. It is found that a majority of triple images had a parity characteristic for 'shear-induced' lensing. Almost all cases of triple or multiple imaging were associated with large surface density enhancements, and lensing objects were present between the images. Thus, the observed gravitational lens candidates for which no lensing object has been detected between the images are unlikely to be a result of asymmetric distribution of mass external to the image circle. In a model with smoothly variable surface mass density, moderately and highly amplified images tended to be single rather than multiple. An opposite trend was found in models which had singularities in the surface mass distribution.

  7. Lead concentrations and risk exposure assessment in surface soils ...

    African Journals Online (AJOL)

    This study investigated lead concentrations in < 250 μm and < 75 μm of deposited dust and< 2000 μm, < 250 μm, and < 75 μm of surface soils at undeveloped residential lands leased to auto-mechanic artisans for a minimum of ten years and estimated exposure risk for children that will reside on the polluted lands after the ...

  8. Reconciling satellite aerosol optical thickness and surface fine particle mass through aerosol liquid water: ALW AND AOT

    Energy Technology Data Exchange (ETDEWEB)

    Nguyen, Thien Khoi V. [Department of Environmental Sciences, Rutgers University, New Brunswick New Jersey USA; Ghate, Virendra P. [Environmental Science Division, Argonne National Laboratory, Argonne Illinois USA; Carlton, Annmarie G. [Department of Chemistry, University of California, Irvine California USA

    2016-11-22

    Summertime aerosol optical thickness (AOT) over the Southeast U.S. is sharply enhanced over wintertime values. This seasonal pattern is unique and of particular interest because temperatures there have not warmed over the past 100 years. Patterns in surface fine particle mass are inconsistent with satellite reported AOT. In this work, we attempt to reconcile the spatial and temporal distribution of AOT over the U.S. with particle mass measurements at the surface by examining trends in aerosol liquid water (ALW), a particle constituent that scatters radiation affecting the satellite AOT, but is removed in mass measurements at routine surface monitoring sites. We employ the thermodynamic model ISORROPIAv2.1 to estimate ALW mass concentrations at IMRPOVE sites using measured ion mass concentrations and NARR meteorological data. Our findings suggest ALW provides a plausible explanation for the geographical and seasonal patterns in AOT and can reconcile previously noted discrepancies with surface mass measurements.

  9. Natural variability in the surface ocean carbonate ion concentration

    Directory of Open Access Journals (Sweden)

    N. S. Lovenduski

    2015-11-01

    Full Text Available We investigate variability in the surface ocean carbonate ion concentration ([CO32−] on the basis of a~long control simulation with an Earth System Model. The simulation is run with a prescribed, pre-industrial atmospheric CO2 concentration for 1000 years, permitting investigation of natural [CO32−] variability on interannual to multi-decadal timescales. We find high interannual variability in surface [CO32−] in the tropical Pacific and at the boundaries between the subtropical and subpolar gyres in the Northern Hemisphere, and relatively low interannual variability in the centers of the subtropical gyres and in the Southern Ocean. Statistical analysis of modeled [CO32−] variance and autocorrelation suggests that significant anthropogenic trends in the saturation state of aragonite (Ωaragonite are already or nearly detectable at the sustained, open-ocean time series sites, whereas several decades of observations are required to detect anthropogenic trends in Ωaragonite in the tropical Pacific, North Pacific, and North Atlantic. The detection timescale for anthropogenic trends in pH is shorter than that for Ωaragonite, due to smaller noise-to-signal ratios and lower autocorrelation in pH. In the tropical Pacific, the leading mode of surface [CO32−] variability is primarily driven by variations in the vertical advection of dissolved inorganic carbon (DIC in association with El Niño–Southern Oscillation. In the North Pacific, surface [CO32−] variability is caused by circulation-driven variations in surface DIC and strongly correlated with the Pacific Decadal Oscillation, with peak spectral power at 20–30-year periods. North Atlantic [CO32−] variability is also driven by variations in surface DIC, and exhibits weak correlations with both the North Atlantic Oscillation and the Atlantic Multidecadal Oscillation. As the scientific community seeks to detect the anthropogenic influence on ocean carbonate chemistry, these results

  10. Natural variability in the surface ocean carbonate ion concentration

    Science.gov (United States)

    Lovenduski, N. S.; Long, M. C.; Lindsay, K.

    2015-11-01

    We investigate variability in the surface ocean carbonate ion concentration ([CO32-]) on the basis of a~long control simulation with an Earth System Model. The simulation is run with a prescribed, pre-industrial atmospheric CO2 concentration for 1000 years, permitting investigation of natural [CO32-] variability on interannual to multi-decadal timescales. We find high interannual variability in surface [CO32-] in the tropical Pacific and at the boundaries between the subtropical and subpolar gyres in the Northern Hemisphere, and relatively low interannual variability in the centers of the subtropical gyres and in the Southern Ocean. Statistical analysis of modeled [CO32-] variance and autocorrelation suggests that significant anthropogenic trends in the saturation state of aragonite (Ωaragonite) are already or nearly detectable at the sustained, open-ocean time series sites, whereas several decades of observations are required to detect anthropogenic trends in Ωaragonite in the tropical Pacific, North Pacific, and North Atlantic. The detection timescale for anthropogenic trends in pH is shorter than that for Ωaragonite, due to smaller noise-to-signal ratios and lower autocorrelation in pH. In the tropical Pacific, the leading mode of surface [CO32-] variability is primarily driven by variations in the vertical advection of dissolved inorganic carbon (DIC) in association with El Niño-Southern Oscillation. In the North Pacific, surface [CO32-] variability is caused by circulation-driven variations in surface DIC and strongly correlated with the Pacific Decadal Oscillation, with peak spectral power at 20-30-year periods. North Atlantic [CO32-] variability is also driven by variations in surface DIC, and exhibits weak correlations with both the North Atlantic Oscillation and the Atlantic Multidecadal Oscillation. As the scientific community seeks to detect the anthropogenic influence on ocean carbonate chemistry, these results will aid the interpretation of trends

  11. Direct Analysis of Proteins from Solutions with High Salt Concentration Using Laser Electrospray Mass Spectrometry

    Science.gov (United States)

    Karki, Santosh; Shi, Fengjian; Archer, Jieutonne J.; Sistani, Habiballah; Levis, Robert J.

    2018-03-01

    The detection of lysozyme, or a mixture of lysozyme, cytochrome c, and myoglobin, from solutions with varying salt concentrations (0.1 to 250 mM NaCl) is compared using laser electrospray mass spectrometry (LEMS) and electrospray ionization-mass spectrometry (ESI-MS). Protonated protein peaks were observed up to a concentration of 250 mM NaCl in the case of LEMS. In the case of ESI-MS, a protein solution with salt concentration > 0.5 mM resulted in predominantly salt-adducted features, with suppression of the protonated protein ions. The constituents in the mixture of proteins were assignable up to 250 mM NaCl for LEMS and were not assignable above a NaCl concentration of 0.5 mM for ESI. The average sodium adducts () bound to the 7+ charge state of lysozyme for LEMS measurements from salt concentrations of 2.5, 25, 50, and 100 mM NaCl are 1.71, 5.23, 5.26, and 5.11, respectively. The conventional electrospray measurements for lysozyme solution containing salt concentrations of 0.1, 1, 2, and 5 mM NaCl resulted in of 2.65, 6.44, 7.57, and 8.48, respectively. LEMS displays an approximately two orders of magnitude higher salt tolerance in comparison with conventional ESI-MS. The non-equilibrium partitioning of proteins on the surface of the charged droplets is proposed as the mechanism for the high salt tolerance phenomena observed in the LEMS measurements. [Figure not available: see fulltext.

  12. Heat Transfer and Mass Diffusion in Nanofluids over a Moving Permeable Convective Surface

    Directory of Open Access Journals (Sweden)

    Muhammad Qasim

    2013-01-01

    Full Text Available Heat transfer and mass diffusion in nanofluid over a permeable moving surface are investigated. The surface exhibits convective boundary conditions and constant mass diffusion. Effects of Brownian motion and thermophoresis are considered. The resulting partial differential equations are reduced into coupled nonlinear ordinary differential equations using suitable transformations. Shooting technique is implemented for the numerical solution. Velocity, temperature, and concentration profiles are analyzed for different key parameters entering into the problem. Performed comparative study shows an excellent agreement with the previous analysis.

  13. Heavy metal concentration of settled surface dust in residential building

    International Nuclear Information System (INIS)

    Nor Aimi abdul Wahab; Fairus Muhamad Darus; Norain Isa; Siti Mariam Sumari; Nur Fatihah Muhamad Hanafi

    2012-01-01

    The concentrations of heavy metals (Cu, Ni, Pb and Zn) in settled surface dust were collected from nine residential buildings in different areas in Seberang Prai Tengah District, Pulau Pinang. The samples of settled surface dust were collected in 1 m 2 area by using a polyethylene brush and placed in the dust pan by sweeping the living room floor most accessible to the occupants. Heavy metals concentrations were determined by using inductively coupled plasma optical emission spectrometer (ICP-OES) after digestion with nitric acid and sulphuric acid. The results show that the range of heavy metals observed in residential buildings at Seberang Prai Tengah were in the range of 2.20-14.00 mg/ kg, 1.50-32.70 mg/ kg, 1.50-76.80 mg/ kg and 14.60-54.40 mg/ kg for Cu, Ni, Pb and Zn respectively. The heavy metal concentration in the investigated areas followed the order: Pb > Zn > Ni > Cu. Statistical analysis indicates significant correlation between all the possible pairs of heavy metal. The results suggest a likely common source for the heavy metal contamination, which could be traced most probably to vehicular emissions, street dust and other related activities. (author)

  14. Averaging of diffusing contaminant concentrations in atmosphere surface layer

    International Nuclear Information System (INIS)

    Ivanov, E.A.; Ramzina, T.V.

    1985-01-01

    Calculations permitting to average concentration fields of diffusing radioactive contaminant coming from the NPP exhaust stack in the atmospheric surface layer are given. Formulae of contaminant concentration field calculation are presented; it depends on the average wind direction value (THETA) for time(T) and stability of this direction (σsub(tgTHETA) or σsub(THETA)). Probability of wind direction deviation from the average value for time T is satisfactory described by the Gauss law. With instability increase in the atmosphere σ increases, when wind velocity increasing the values of σ decreases for all types of temperature gradients. Nonuniformity of σ value dependence on averaging time T is underlined, that requires accurate choice of σsub(tgTHETA) and σsub(THETA) parameters in calculations

  15. Estimates of surface methane emissions over Europe using observed surface concentrations and the FLEXPART trajectory model

    Science.gov (United States)

    Weaver, C. J.; Kiemle, C.; Kawa, S. R.; Aalto, T.; Necki, J.; Steinbacher, M.; Arduini, J.; Apadula, F.; Berkhout, H.; Hatakka, J.; O'Doherty, S.

    2013-12-01

    We use surface methane observations from nine European ground stations, and the FLEXPART Lagrangian transport model to obtain surface methane emissions for 2010. Our inversion shows the strongest emissions from the Netherlands and the coal mines in Upper Silesia Poland. This is qualitatively consistent with the EDGAR surface flux inventory. We also report significant surface fluxes from wetlands in southern Finland during July and August and reduced wetland fluxes later in the year. Our simulated methane surface concentration captures at least half of the daily variability in the observations, suggesting that the transport model is correctly simulating the regional transport pathways over Europe. We also use our trajectory model to determine whether future space-based remote sensing instruments (MERLIN) will be able to detect both natural and anthropogenic changes in the surface flux strengths.

  16. Numerical study of surface water waves generated by mass movement

    Energy Technology Data Exchange (ETDEWEB)

    Ghozlani, Belgacem; Hafsia, Zouhaier; Maalel, Khlifa, E-mail: ghozlanib@yahoo.fr [Ecole Nationale d' Ingenieurs de Tunis, Laboratoire de Modelisation en ' Hydraulique et Environnement, BP 37, Le Belvedere, 1002 Tunis (Tunisia)

    2013-10-01

    In this paper waves generated by two-dimensional mass movement are simulated using a numerical model based on the full hydrodynamic coupling between rigid-body motion and ambient fluid flow. This approach has the capability to represent the dynamics of the moving rigid body, which avoids the need to prescribe the body velocity based on the data measurements. This model is implemented in the CFX code and uses the Reynolds average Navier-Stokes equations solver coupled to the recently developed immersed solid technique. The latter technique allows us to follow implicitly the motion of the solid block based on the rigid body solver. The volume-of-fluid method is used to track the free surface locations. The accuracy of the present model is firstly examined against the simple physical case of a freely falling rigid body into water reproducing Scott Russell's solitary waves. More complex and realistic simulations of aerial and submarine mass-movement, simulated by a rigid wedge sliding into water along a 45 Degree-Sign slope, are then performed. Simulated results of the aerial mass movement show the complex flow patterns in terms of the velocity fields and free surface profiles. Results are in good agreement with the available experimental data. In addition, the physical processes associated with the generation of water wave by two-dimensional submarine mass-movement are explored. The effects of the initial submergence and specific gravity on the slide mass kinematics and maximum wave amplitude are investigated. The terminal velocity and initial acceleration of the slide mass are well predicted when compared to experimental results. It is found that the initial submergence did not have a significant effect on the initial acceleration of the slide block centre of mass. However, it depends nonlinearly on the specific gravity. The maximum wave amplitude and the time at which it occurred are also presented as a function of the initial submergence and specific gravity

  17. Secondary ions mass spectrometric signal enhancement of peptides on enlarged-gold nanoparticle surfaces.

    Science.gov (United States)

    Kim, Young-Pil; Lee, Tae Geol

    2012-06-05

    A high surface coverage of gold nanoparticles (AuNPs) is a prerequisite for enhancing the peptide signal intensity in time-of-flight secondary ion mass spectrometry (TOF-SIMS). Here, we demonstrate the TOF-SIMS signal amplification of peptides on a surface by enlarging surface-confined AuNPs using the NH(2)OH/Au(3+) seeding method. Because of the increased surface area and spherical structure of the Au, the SIMS intensity of the peptides became significantly enhanced on the enlarged-AuNPs surface, especially at high concentrations of peptide solution (>10 μM), compared to that of the bare gold surface or submonolyer of AuNPs. We are confident that this will be a useful method for diagnosis and bioassay with high sensitivity in a label-free manner.

  18. Ellipsoidal Correction in GRACE Surface Mass Change Estimation

    Science.gov (United States)

    Li, Jin; Chen, Jianli; Li, Ziang; Wang, Song-Yun; Hu, Xiaogong

    2017-11-01

    The Earth's shape is much closer to an ellipsoid than a sphere. The commonly used spherical approximation in mass change inversion is expected to cause bias by the spherical harmonic (SH) solutions from Gravity Recovery and Climate Experiment (GRACE), especially in high-latitude regions where significant present-day ice losses occur. This bias, or ellipsoidal correction, reaches up to 8% from the evaluation by simulations based on synthetic mass change rate models. Further evaluation using 14 plus years of GRACE monthly SH solutions (from April 2002 to December 2016) indicates that the ellipsoidal correction is also noticeable in the total mass change time series over polar regions. Before and after the ellipsoidal correction, the estimated linear rates from mass change time series differ by 4.3%, 4.7%, 5.2%, 5.7%, and 6.6% for five selected regions over Greenland, Antarctic Peninsula, Amundsen Sea Embayment, Alaska glacier, and Svalbard Islands, respectively. Although with amplitudes likely below the current GRACE's uncertainty level, these differences are consistently negative over the five regions. This indicates that the spherical approximation leads to systematic underestimation for polar mass change rates. Thus, the ellipsoidal correction needs to be considered for more precise mass recovery with GRACE SH solutions. It also depends on spatial scales of mass change signals (the smaller the spatial scale, the larger the correction). To more reliably estimate high-latitude surface mass changes by GRACE SH solutions, the ellipsoidal correction is recommended, especially for ice-loss signals over polar regions.

  19. Lung deposited surface area concentrations in a street canyon

    Science.gov (United States)

    Kuuluvainen, Heino; Hietikko, Riina; Järvinen, Anssi; Saukko, Erkka; Irjala, Matti; Niemi, Jarkko V.; Timonen, Hilkka; Keskinen, Jorma; Rönkkö, Topi

    2017-04-01

    Street canyons are interesting environments with respect to the dispersion of traffic emissions and human exposure. Pedestrians may be exposed to relatively high concentrations of fine particles and the vertical dispersion affects the human exposure above the ground level in buildings. Previously, particle concentrations have been measured in street canyons at a few different heights (Marini et al., 2015). The information on the lung deposited surface area (LDSA) concentration, which is a relevant metric for the negative health effects, is very limited even at the ground level of street canyons (Kuuluvainen et al., 2016). More information especially on the vertical dispersion and the ground level concentrations is needed, for instance, for the use of urban planning and the design of ventilation systems in buildings. Measurements were carried out in a busy street canyon in Helsinki, Finland, at an urban super-site measurement station (Mäkelänkatu 50). The data included vertical concentration profiles measured in an intensive measurement campaign with a Partector (Naneos GmbH) installed into a drone, long-term measurements with an AQ Urban particle sensor (Pegasor Ltd.), and an extensive comparison measurement in the field with different devices measuring the LDSA. These devices were an AQ Urban, Partector, DiSCmini (Testo AG), NSAM (TSI Inc.), and an ELPI+ (Dekati Ltd.). In addition, continuous measurements of gas phase components, particle size distributions, and meteorology were run at the supersite. The vertical profile measurements were con-ducted in November 2016 during two days. In the measurements, the drone was flown from the ground level to an altitude of 50 or 100 m, which is clearly above the roof level of the buildings. Altogether, 48 up-and-down flights were conducted during the two days. The vertical profiles were supported by continuous measurements at the ground level on both sides of the street canyon. The long-term measurements were conducted

  20. Evaluation of errors for mass-spectrometric analysis with surface-ionization type mass-spectrometer (statistical evaluation of mass-discrimination effect)

    International Nuclear Information System (INIS)

    Wada, Y.

    1981-01-01

    The surface-ionization type mass-spectrometer is widely used as an apparatus for quality assurance, accountability and safeguarding of nuclear materials, and for this analysis it has become an important factor to statistically evaluate an analytical error which consists of a random error and a systematic error. The major factor of this systematic error was the mass-discrimination effect. In this paper, various assays for evaluating the factor of variation on the mass-discrimination effect were studied and the data obtained were statistically evaluated. As a result of these analyses, it was proved that the factor of variation on the mass-discrimination effect was not attributed to the acid concentration of sample, sample size on the filament and supplied voltage for a multiplier, but mainly to the filament temperature during the mass-spectrometric analysis. The mass-discrimination effect values β which were usually calculated from the measured data of uranium, plutonium or boron isotopic standard sample were not so significant dependently of the difference of U-235, Pu-239 or B-10 isotopic abundance. Furthermore, in the case of U and Pu, measurement conditions and the mass range of these isotopes were almost similar, and these values β were not statistically significant between U and Pu. On the other hand, the value β for boron was about a third of the value β for U or Pu, but compared with the coefficient of the correction on the mass-discrimination effect for the difference of mass-number, ΔM, these coefficient values were almost the same among U, Pu, and B.As for the isotopic analysis error of U, Pu, Nd and B, it was proved that the isotopic abundance of these elements and the isotopic analysis error were in a relationship of quadratic curves on a logarithmic-logarithmic scale

  1. Irradiation induced surface segregation in concentrated alloys: a contribution

    International Nuclear Information System (INIS)

    Grandjean, Y.

    1996-01-01

    A new computer modelization of irradiation induced surface segregation is presented together with some experimental determinations in binary and ternary alloys. The model we propose handles the alloy thermodynamics and kinetics at the same level of sophistication. Diffusion is described at the atomistic level and proceeds vis the jumps of point defects (vacancies, dumb-bell interstitials): the various jump frequencies depend on the local composition in a manner consistent with the thermodynamics of the alloy. For application to specific alloys, we have chosen the simplest statistical approximation: pair interactions in the Bragg Williams approximation. For a system which exhibits the thermodynamics and kinetics features of Ni-Cu alloys, the model generates the behaviour parameters (flux and temperature) and of alloy composition. Quantitative agreement with the published experimental results (two compositions, three temperatures) is obtained with a single set of parameters. Modelling austenitic steels used in nuclear industry requires taking into account the contribution of dumbbells to mass transport. The effects of this latter contribution are studied on a model of Ni-Fe. Interstitial trapping on dilute impurities is shown to delay or even suppress the irradiation induced segregation. Such an effect is indeed observed in the experiments we report on Fe 50 Ni 50 and Fe 49 Ni 50 Hf 1 alloys. (author)

  2. The plasma leptin concentration is closely associated with the body fat mass in nondiabetic uremic patients

    DEFF Research Database (Denmark)

    Clausen, P; Nielsen, P K; Olgaard, K

    1999-01-01

    filtration rate seemed to have a limited influence on the plasma leptin concentration in nondiabetic uremic subjects matched by body fat mass to controls. The plasma leptin concentration was closely associated with the body fat mass, and the leptin level might, therefore, be useful as an indicator of the fat......Plasma leptin is associated with the body mass index and, more precisely, with the body fat mass. Plasma leptin has been found to be elevated in uremic patients. This study aimed at investigating the plasma leptin concentration and associations between plasma leptin, body fat mass, and glomerular.......4 (3.1-59.5) ng/ml versus 5.4 (1.6-47.5) ng/ml (median and range in parentheses; p

  3. An experimental study on mass loading of soil particles on plant surfaces

    International Nuclear Information System (INIS)

    Li, J.; Gerzabek, M.H.; Mueck, K.

    1994-03-01

    Radionuclide contaminated soil adhered to plant surfaces can contribute to human ingestion dose. To determine this contribution, a method of 46 Sc neutron activation analysis was established and tested, by which a detection limit of 0.05 mg soil per g dry plant biomass can be obtained. In the field and greenhouse experiment the mass loading of soil on ryegrass (Lolium perenne L.) and broad bean (Vicia faba L.) was investigated and the contribution from rainsplash and wind erosion were evaluated separately. Soil retained on plant surfaces in field conditions in Seibersdorf/Austria was 5.77 ± 1.44 mg soil per g dry plant for ryegrass and 9.51 ± 0.73 mg soil per g dry plant for broad bean. Estimates of contribution from rainsplash and wind erosion to soil contamination of plant during the experimental period are 68 % and 32 % for broadbean, 47 % and 53 % for ryegrass, respectively. Mass loading results from field studies indicate that soil adhesion on plant surfaces can contribute up to 23 % of plant 137 Cs contamination, the transfer factors modified by mass loading decline differently, depending on 137 Cs concentration of the soil and the soil mass adhered to plant surfaces. (authors)

  4. An experimental study on mass loading of soil particles on plant surfaces

    International Nuclear Information System (INIS)

    Li, J. G.; Gerzabek, M. H.; Mueck, K.

    1994-01-01

    Radionuclide contaminated soil adhered to plant surfaces can contribute to human ingestion dose. To determine this contribution, a method of 46 Sc neutron activation analysis was established and tested, by which a detection limit of 0.05 mg soil per g dry plant biomass can be obtained. In the field and greenhouse experiment the mass loading of soil on ryegrass (Lolium perenne L.) and broadbean (Vicia faba L.) was investigated and the contribution from rainsplash and wind erosion were evaluated separately. Soil retained on plant surfaces in field conditions in Seibersdorf/Austria was 5.77 ± 1.44 mg soil per g dry plant for ryegrass and 9.51 ± 0.73 mg soil per g dry plant for broadbean. Estimates of contribution from rainsplash and wind erosion to soil contamination of plants during the experimental period are 68 % and 32 % for broadbean 47 % and 53 % for ryegrass respectively. Mass loading results from field studies indicate that soil adhesion on plant surfaces can contribute up to 23 % of plant 137 Cs contamination, the transfer factors modified by mass loading decline differently, depending on 137 Cs concentration of the soil and the soil mass adhered to plant surfaces. (author)

  5. Dynamics and mass accommodation of HCl molecules on sulfuric acid-water surfaces.

    Science.gov (United States)

    Behr, P; Scharfenort, U; Ataya, K; Zellner, R

    2009-09-28

    A molecular beam technique has been used to study the dynamics and mass accommodation of HCl molecules in collision with sulfuric acid-water surfaces. The experiments were performed by directing a nearly mono-energetic beam of HCl molecules onto a continuously renewed liquid film of 54-76 wt% sulfuric acid at temperatures between 213 K and 243 K. Deuterated sulfuric acid was used to separate sticking but non-reactive collisions from those that involved penetration through the phase boundary followed by dissociation and recombination with D+. The results indicate that the mass accommodation of HCl on sulfuric acid-water surfaces decreases sharply with increasing acidity over the concentration range 54-76 wt%. Using the capillary wave theory of mass accommodation this effect is explained by a change of the surface dynamics. Regarding the temperature dependence it is found that the mass accommodation of HCl increases with increasing temperature and is limited by the bulk phase viscosity and driven by the restoring forces of the surface tension. These findings imply that under atmospheric conditions the uptake of HCl from the gas phase depends crucially on the bulk phase parameters of the sulfuric acid aerosol.

  6. Hydrogen concentration and mass density of diamondlike carbon films obtained by x-ray and neutron reflectivity

    DEFF Research Database (Denmark)

    Findeisen, E.; Feidenhans'l, R.; Vigild, Martin Etchells

    1994-01-01

    the mass density, but also the concentration of hydrogen, which varies in our case between 0 and 30 at.%. This method is a new and nondestructive way to determine the concentration of hydrogen within an error of less than 2 at.% in samples with sharp interfaces. It is especially suited for diamondlike......Specular reflectivity of neutrons and x rays can be used to determine the scattering length density profile of a material perpendicular to its surface. We have applied these techniques to study amorphous, diamondlike, hydrocarbon films. By the combination of these two techniques we obtain not only...

  7. Spatial Gradients in Trace Metal Concentrations in the Surface Microlayer of the Mediterranean Sea

    Directory of Open Access Journals (Sweden)

    Antonio eTovar-Sanchez

    2014-12-01

    Full Text Available The relationship between dust deposition and surface water metal concentrations is poorly understood. Dissolution, solubility, and partitioning reactions of trace metals from dust particles are governed by complex chemical, biological, and physical processes occurring in the surface ocean. Despite that, the role of the sea surface microlayer (SML, a thin, but fundamental component modulating the air-sea exchange of materials has not been properly evaluated. Our study revealed that the SML of the Mediterranean Sea is enriched with bioactive trace metals (i.e., Cd, Co, Cu and Fe, ranging from 8 (for Cd to 1000 (for Fe times higher than the dissolved metal pool in the underlying water column. The highest enrichments were spatially correlated with the atmospheric deposition of mineral particles. Our mass balance results suggest that the SML in the Mediterranean Sea contains about 2 tonnes of Fe. However, we did not detect any trends between the concentrations of metals in SML with the subsurface water concentrations and biomass distributions. These findings suggest that future studies are needed to quantify the rate of metal exchange between the SML and the bioavailable pool and that the SML should be considered to better understand the effect of atmospheric inputs on the biogeochemistry of trace metals in the ocean.

  8. Surface-ionization field mass-spectrometry studies of nonequilibrium surface ionization

    International Nuclear Information System (INIS)

    Blashenkov, Nikolai M; Lavrent'ev, Gennadii Ya

    2007-01-01

    The ionization of polyatomic molecules on tungsten and tungsten oxide surfaces is considered for quasiequilibrium or essentially nonequilibrium conditions (in the latter case, the term nonequilibrium surface ionization is used for adsorbate ionization). Heterogeneous reactions are supposed to proceed through monomolecular decay of polyatomic molecules or fragments of multimolecular complexes. The nonequilibrium nature of these reactions is established. The dependences of the current density of disordered ions on the surface temperature, electric field strength, and ionized particle energy distribution are obtained in analytical form. Heterogeneous dissociation energies, the ionization potentials of radicals, and the magnitude of reaction departure from equilibrium are determined from experimental data, as are energy exchange times between reaction products and surfaces, the number of molecules in molecular complexes, and the number of effective degrees of freedom in molecules and complexes. In collecting the data a new technique relying on surface-ionization field mass-spectrometry was applied. (instruments and methods of investigation)

  9. A Plasmaspheric Mass Density Model and Constraints on its Heavy Ion Concentration

    Science.gov (United States)

    Berube, D.; Moldwin, M. B.; Green, J. L.

    2004-01-01

    The first empirical model of the equatorial mass density of the plasmasphere is constructed using ground-based ULF wave diagnostics. Plasmaspheric mass density between L=l.7 and L=3.2 has been determined using over 5200 hours of data from pairs of stations in the MEASURE array of ground magnetometers. The least-squares fit to the data as a function of L shows that mass density falls logarithmically with L. Average ion mass as a function of L is also estimated by combining the mass density model with plasmaspheric electron density profiles determined from the IMAGE Radio Plasma Imager (RPI). Additionally, we use the RPI electron density database to examine how the average ion mass changes under different levels of geomagnetic activity. We find that average ion mass is greatest under the most disturbed conditions. This result indicates that heavy ion concentrations are enhanced during large geomagnetic disturbances, and therefore play an important role in storm-time plasmaspheric dynamics. The average ion mass is also used to constrain the concentrations of He(+) and O(+). Estimates of the He(+) concentration determined this way can be useful for interpreting IMAGE Extreme Ultraviolet Imager (EUV) images.

  10. The plasma leptin concentration is closely associated with the body fat mass in nondiabetic uremic patients

    DEFF Research Database (Denmark)

    Clausen, P; Nielsen, P K; Olgaard, K

    1999-01-01

    Plasma leptin is associated with the body mass index and, more precisely, with the body fat mass. Plasma leptin has been found to be elevated in uremic patients. This study aimed at investigating the plasma leptin concentration and associations between plasma leptin, body fat mass, and glomerular...... filtration rate in nondiabetic predialysis uremic patients and in nondiabetic patients on chronic hemodialysis. Plasma leptin, body fat mass, and creatinine clearance were measured in 22 predialysis uremic patients, 18 hemodialysis patients, and 24 healthy control subjects. The logarithmically transformed...... plasma leptin concentration was closely associated with the body fat mass in all groups (r = 0.93, r = 0.83, and r = 0.72, respectively; p

  11. A surface structural model for ferrihydrite I: Sites related to primary charge, molar mass, and mass density

    NARCIS (Netherlands)

    Hiemstra, T.; Riemsdijk, van W.H.

    2009-01-01

    A multisite surface complexation (MUSIC) model for ferrihydrite (Fh) has been developed. The surface structure and composition of Fh nanoparticles are described in relation to ion binding and surface charge development. The site densities of the various reactive surface groups, the molar mass, the

  12. Changes in ground-level PM mass concentration and column aerosol optical depth over East Asia during 2004-2014

    Science.gov (United States)

    Nam, J.; Kim, S. W.; Park, R.; Yoon, S. C.; Sugimoto, N.; Park, J. S.; Hong, J.

    2015-12-01

    Multi-year records of moderate resolution imaging spectroradiometer (MODIS), ground-level particulate matter (PM) mass concentration, cloud-aerosol lidar with orthogonal polarization (CALIOP), and ground-level lidar were analyzed to investigate seasonal and annual changes of aerosol optical depth (AOD) and PM mass concentration over East Asia. Least mean square fit method is applied to detect the trends and their magnitudes for each selected regions and stations. Eleven-year MODIS measurements show generally increasing trends in both AOD (1.18 % yr-1) and Ångström exponent (0.98 % yr-1), especially over the east coastal industrialized region in China. Monthly variation of AOD show maximum value at April-July, which were related to the progress of summer monsoon rain band and stationary continental air mass on the northeast of Asia. Increasing trends of AOD were found for eight cites in China (0.80 % yr-1) and Seoul site, Korea (0.40 % yr-1), whereas no significant change were shown in Gosan background site (0.04 % yr-1) and decreasing trend at five background sites in Japan (-0.42 % yr-1). Contrasting to AOD trend, all fifteen sites in China (-1.28 % yr-1), Korea (-2.77 % yr-1), and Japan (-2.03 % yr-1) showed decreasing trend of PM10 mass concentration. Also, PM2.5 mass concentration at Beijing, Seoul, Rishiri, and Oki show significant decreasing trend of -1.16 % yr-1. To further discuss the opposite trend of surface PM mass concentration and column AOD, we investigate vertical aerosol profile from lidar measurements. AOD estimated for planetary boundary layer (surface~1.5 km altitude; AODPBL) from CALIOP measurements over East China show decreasing trend of -1.71 % yr-1 over the period of 2007-2014, wherever AOD estimated for free troposphere (1.5 km~5 km altitude; AODFT) show increasing trend of 2.92 % yr-1. In addition, ground-level lidar measurements in Seoul show decreasing AODPBL trend of -2.57 % yr-1, whereas, AODFT show no significant change (-0.44 % yr

  13. Perfluoroalkyl substances in the Daling River with concentrated fluorine industries in China: seasonal variation, mass flow, and risk assessment.

    Science.gov (United States)

    Zhu, Zhaoyun; Wang, Tieyu; Meng, Jing; Wang, Pei; Li, Qifeng; Lu, Yonglong

    2015-07-01

    In the present study, we investigated concentrations and composition profiles of perfluoroalkyl substances (PFASs) in surface water from the Daling River in different seasons. The highest concentration of ΣPFASs (9540 ng L(-1)) and dominant homologues were found in surface water collected in summer. Perfluorobutanoic acid (PFBA), perfluorobutane sulfonate (PFBS), and perfluorooctanoic acid (PFOA) were the dominant PFASs in four seasons with a total contribution of over 90%. The discharge of two fluorine chemical industry parks was predicted to be the main contamination source of PFASs in the study area. The daily and annual mass flows were calculated according to data of detected PFAS concentrations and water discharge, and the annual mass loading of PFASs into the Bohai Sea from the Daling River reached to 461 kg year(-1). Hazard assessment indicated that concentrations of PFASs in study area had little risk to aquatic organisms and wildlife. However, the multiple health risk would be relatively high if the water was served as drinking water in the study area.

  14. Size resolved mass concentration and elemental composition of atmospheric aerosols over the Eastern Mediterranean area

    Directory of Open Access Journals (Sweden)

    J. Smolík

    2003-01-01

    Full Text Available A Berner low pressure impactor was used to collect size-segregated aerosol samples at Finokalia, located on the north-eastern coast of Crete, Greece during July 2000 and January 2001. Several samples were also collected during the summer campaign aboard the research vessel "AEGAIEO" in the Aegean Sea. Gravimetric analysis and inversion techniques yielded daily PM1 and PM10 mass concentrations. The samples were also analysed by PIXE giving the elemental size distributions of Al, Si, K, Ca, Ti, Mn, Fe, Sr, S, Cl, Ni, V, Cu, Cr, Zn, and Pb. The crustal elements and sea-salt had a unimodal supermicron size distribution. Sulphur was found predominantly in submicron fractions. K, V, and Ni exhibited a bimodal distribution with a submicron mode produced by forest fires and oil combustion. The anthropogenic elements had broad and not well-defined distributions. The time series for PM1 and PM10 mass and elemental concentrations showed both daily and seasonal variation. Higher mass concentrations were observed during two incursions of Saharan dust, whilst higher concentrations of S, Cu, Zn, and Pb were encountered in samples collected in air masses arriving from northern Greece or the western coast of Turkey. Elevated concentrations of chlorine were found in samples with air masses either originating above the Atlantic Ocean and arriving at Finokalia via western Europe or recirculating over the western coast of the Black Sea.

  15. Comparison of gas chromatography/mass spectrometry and immunoassay techniques on concentrations of atrazine in storm runoff

    Science.gov (United States)

    Lydy, Michael J.; Carter, D.S.; Crawford, Charles G.

    1996-01-01

    Gas chromatography/mass spectrometry (GC/MS) and enzyme-linked immunosorbent assay (ELISA) techniques were used to measure concentrations of dissolved atrazine in 149 surface-water samples. Samples were collected during May 1992–September 1993 near the mouth of the White River (Indiana) and in two small tributaries of the river. GC/MS was performed on a Hewlett-Packard 5971 A, with electron impact ionization and selected ion monitoring of filtered water samples extracted by C-18 solid phase extraction; ELISA was performed with a magnetic-particle-based assay with photometric analysis. ELISA results compared reasonably well to GC/MS measurements at concentrations below the Maximum Contaminant Level for drinking water set by the U.S. Environmental Protection Agency (3.0 μg/L), but a systematic negative bias was observed at higher concentrations. When higher concentration samples were diluted into the linear range of calibration, the relation improved. A slight positive bias was seen in all of the ELISA data compared to the GC/MS results, and the bias could be partially explained by correcting the ELISA data for cross reactivity with other triazine herbicides. The highest concentrations of atrazine were found during the first major runoff event after the atrazine was applied. Concentrations decreased throughout the rest of the sampling period even though large runoff events occurred during this time, indicating that most atrazine loading to surface waters in the study area occurs within a few weeks after application.

  16. Metal concentration at surface water using multivariate analysis and ...

    African Journals Online (AJOL)

    This study defined the concentration of metals in Kerteh and Paka River water and their potential health risk towards human. 54 water samples were collected and analyzed using ICP-OES. Results revealed that most of the stations in Kerteh River gave the higher concentration of Cd, Cu, Zn, Co, Ni, As, Cr and Pb compared ...

  17. Development of a Linear Ion Trap Mass Spectrometer (LITMS) Investigation for Future Planetary Surface Missions

    Science.gov (United States)

    Brinckerhoff, W.; Danell, R.; Van Ameron, F.; Pinnick, V.; Li, X.; Arevalo, R.; Glavin, D.; Getty, S.; Mahaffy, P.; Chu, P.; hide

    2014-01-01

    Future surface missions to Mars and other planetary bodies will benefit from continued advances in miniature sensor and sample handling technologies that enable high-performance chemical analyses of natural samples. Fine-scale (approx.1 mm and below) analyses of rock surfaces and interiors, such as exposed on a drill core, will permit (1) the detection of habitability markers including complex organics in association with their original depositional environment, and (2) the characterization of successive layers and gradients that can reveal the time-evolution of those environments. In particular, if broad-based and highly-sensitive mass spectrometry techniques could be brought to such scales, the resulting planetary science capability would be truly powerful. The Linear Ion Trap Mass Spectrometer (LITMS) investigation is designed to conduct fine-scale organic and inorganic analyses of short (approx.5-10 cm) rock cores such as could be acquired by a planetary lander or rover arm-based drill. LITMS combines both pyrolysis/gas chromatograph mass spectrometry (GCMS) of sub-sampled core fines, and laser desorption mass spectrometry (LDMS) of the intact core surface, using a common mass analyzer, enhanced from the design used in the Mars Organic Molecule Analyzer (MOMA) instrument on the 2018 ExoMars rover. LITMS additionally features developments based on the Sample Analysis at Mars (SAM) investigation on MSL and recent NASA-funded prototype efforts in laser mass spectrometry, pyrolysis, and precision subsampling. LITMS brings these combined capabilities to achieve its four measurement objectives: (1) Organics: Broad Survey Detect organic molecules over a wide range of molecular weight, volatility, electronegativity, concentration, and host mineralogy. (2) Organic: Molecular Structure Characterize internal molecular structure to identify individual compounds, and reveal functionalization and processing. (3) Inorganic Host Environment Assess the local chemical

  18. A free vibration of beams carrying a concentrated mass under distributed axial forces

    International Nuclear Information System (INIS)

    Nagai, Ken-ichi; Nagaya, Kosuke; Takeda, Sadahiko; Arai, Noriyuki.

    1988-01-01

    The free bending vibrations of beams with a concentrated mass subjected to axial forces caused by axial acceleration are analyzed by the Galerkin method, introducing the mode shape functions which are the sum of the products of the finite power series and the trigonometrical function. This analytical method makes it easy to construct the equations of motion in each boundary condition only by exchanging the coefficients of the finite power series. Numerical calculations are carried out under four sets of boundary conditions combined with simply supported and clamped edges. The natural frequencies and the corresponding modes of vibration are determined under both various locations of the concentrated mass and axial forces. it is found that the transverse inertia force and the axial force, due to the concentrated mass, have significant effects on the change of the natural frequencies for beams. Furthermore the distinction of boundary conditions gives predominant influence to the variation of natural frequencies. (author)

  19. Mass transfer during sulfuric acid concentration by evaporation into the air flow

    Directory of Open Access Journals (Sweden)

    V. K. Lukashov

    2016-12-01

    Full Text Available This article shows the results of the study of mass transfer under periodic concentration of sulfuric acid by evaporation inthe gas flow, neutral with respect to the components of acid.Used mathematical model for mass transferbases on the proposed simplified physical representations.This model has allowed to construct an algorithm for calculation the coefficient of mass transfer from the liquid phase into the gas flow. The algorithm uses the experimental data of change the amount of acid and concentration of the water taken from the laboratory tests. Time-based Nusselt diffusion criterion represent the results of the study at different modes of the evaporation process.It has been found that the character of the influence of temperature and initial acid concentration on Nusselt diffusion criterion depends on the variation range of the mass fraction of water in the acid.It is shown that these dependences are well approximated by an exponential function from the dimensionless parameters of the process. This allows usingthem for calculation the mass transfer coefficient into the gas phase in a batch process of concentrating in the range of investigated modes.

  20. Standard test method for uranium and plutonium concentrations and isotopic abundances by thermal ionization mass spectrometry

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    2005-01-01

    1.1 This test method covers the determination of the concentration and isotopic composition of uranium and plutonium in solutions. The purified uranium or plutonium from samples ranging from nuclear materials to environmental or bioassay matrices is loaded onto a mass spectrometric filament. The isotopic ratio is determined by thermal ionization mass spectrometry, the concentration is determined by isotope dilution. 1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish safety and health practices and determine the applicability of regulatory limitations prior to use.

  1. Serum Prostate-Specific Antigen (PSA) Concentration, PSA Mass, and Obesity: A Mathematical Analysis.

    Science.gov (United States)

    Vollmer, Robin T

    2018-02-17

    To provide a mathematical background for understanding the phenomenon of analyte hemodilution using a kinetic analysis. The first assumption for this analysis is that change in concentration of any analyte, such as prostate-specific antigen (PSA), is due to the flux of the analyte from an organ into the blood minus its flux from the blood. What results is a relatively simple differential equation that emphasizes the importance of plasma volume, organ mass, and two rate constants. The analyses demonstrate how serum PSA can be affected by plasma volume as well as body mass and how hemodilution due to obesity can be at least partly corrected for by expressing PSA in units of total mass or total mass density. At a time when obesity is prevalent, expressing analytes in units of total mass may make them relate more closely to disease status and prognosis.

  2. Power System Mass Analysis for Hydrogen Reduction Oxygen Production on the Lunar Surface

    Science.gov (United States)

    Colozza, Anthony J.

    2009-01-01

    The production of oxygen from the lunar regolith requires both thermal and electrical power in roughly similar proportions. This unique power requirement is unlike most applications on the lunar surface. To efficiently meet these requirements, both solar PV array and solar concentrator systems were evaluated. The mass of various types of photovoltaic and concentrator based systems were calculated to determine the type of power system that provided the highest specific power. These were compared over a range of oxygen production rates. Also a hybrid type power system was also considered. This system utilized a photovoltaic array to produce the electrical power and a concentrator to provide the thermal power. For a single source system the three systems with the highest specific power were a flexible concentrator/Stirling engine system, a rigid concentrator/Stirling engine system and a tracking triple junction solar array system. These systems had specific power values of 43, 34, and 33 W/kg, respectively. The hybrid power system provided much higher specific power values then the single source systems. The best hybrid combinations were the triple junction solar array with the flexible concentrator and the rigid concentrator. These systems had a specific power of 81 and 68 W/kg, respectively.

  3. Quantification of four artificial sweeteners in Finnish surface waters with isotope-dilution mass spectrometry

    International Nuclear Information System (INIS)

    Perkola, Noora; Sainio, Pirjo

    2014-01-01

    The artificial sweeteners sucralose (SCL), acesulfame (ACS), saccharin (SAC), and cyclamate (CYC) have been detected in environmental waters in Europe and North America. Higher environmental levels are expected in view of the increasing consumption of these food additives. In this study, an isotope-dilution mass spectrometry (IDMS) LC–MS/MS method was developed and validated for quantifying the four artificial sweeteners in boreal lakes (n = 3) and rivers (n = 12). The highest concentrations of ACS, SAC, CYC and SCL were 9,600, 490, 210 and 1000 ng/L, respectively. ACS and SAC were detected in all studied samples, and CYC and SCL in 98% and 56% of the samples. Seasonal trends of ACS and SAC were observed in some rivers. ACS and SCL concentrations in rivers correlated linearly with population equivalents of the wastewater treatment plants in the catchment areas, whereas SAC and CYC concentrations depend more on the source. -- Highlights: • A reliable method for analysing artificial sweeteners in water was validated. • Artificial sweeteners were quantified in boreal rivers and lakes. • Most concentrations were in accordance with previous European studies. • Acesulfame and saccharine concentrations were high in the most contaminated rivers. • Correlation observed between concentrations and mean water throughflow in rivers. -- High concentrations of artificial sweeteners were obtained, which indicates slow or negligible degradation of these compounds in boreal surface waters

  4. ACCURATE UNIVERSAL MODELS FOR THE MASS ACCRETION HISTORIES AND CONCENTRATIONS OF DARK MATTER HALOS

    International Nuclear Information System (INIS)

    Zhao, D. H.; Jing, Y. P.; Mo, H. J.; Boerner, G.

    2009-01-01

    A large amount of observations have constrained cosmological parameters and the initial density fluctuation spectrum to a very high accuracy. However, cosmological parameters change with time and the power index of the power spectrum dramatically varies with mass scale in the so-called concordance ΛCDM cosmology. Thus, any successful model for its structural evolution should work well simultaneously for various cosmological models and different power spectra. We use a large set of high-resolution N-body simulations of a variety of structure formation models (scale-free, standard CDM, open CDM, and ΛCDM) to study the mass accretion histories, the mass and redshift dependence of concentrations, and the concentration evolution histories of dark matter halos. We find that there is significant disagreement between the much-used empirical models in the literature and our simulations. Based on our simulation results, we find that the mass accretion rate of a halo is tightly correlated with a simple function of its mass, the redshift, parameters of the cosmology, and of the initial density fluctuation spectrum, which correctly disentangles the effects of all these factors and halo environments. We also find that the concentration of a halo is strongly correlated with the universe age when its progenitor on the mass accretion history first reaches 4% of its current mass. According to these correlations, we develop new empirical models for both the mass accretion histories and the concentration evolution histories of dark matter halos, and the latter can also be used to predict the mass and redshift dependence of halo concentrations. These models are accurate and universal: the same set of model parameters works well for different cosmological models and for halos of different masses at different redshifts, and in the ΛCDM case the model predictions match the simulation results very well even though halo mass is traced to about 0.0005 times the final mass, when

  5. Sensitive Detection and Identification of Isovanillin Aerosol Particles at the pg/cm3 Mass Concentration Level using Raman Spectroscopy

    Science.gov (United States)

    2017-04-24

    mass 152.15; Density 1.41) aerosol particles of mass concentration MC of 1.8...Aerosol Particles at the pg/cm3 Mass Concentration Level Using Raman Spectroscopy* R. L. Aggarwal1, S. Di Cecca, L. W. Farrar, Shabshelowitz, A...detect isovanillin aerosols with mass concentration of 12 pg/cm3 in a 15 s signal integration period with a signal‐to‐noise ratio of 32. We

  6. Complex Surface Concentration Gradients by Stenciled "Electro Click Chemistry"

    DEFF Research Database (Denmark)

    Hansen, Thomas Steen; Lind, Johan Ulrik; Daugaard, Anders Egede

    2010-01-01

    Complex one- or two-dimensional concentration gradients of alkynated molecules are produced on azidized conducting polymer substrates by stenciled "electro click chemistry". The latter describes the local electrochemical generation of catalytically active Cu(I) required to complete a "click...... reaction" between alkynes and azides at room temperature. A stencil on the counter electrode defines the shape and multiplicity of the gradient(s) on the conducting polymer substrate, while the specific reaction conditions control gradient steepness and the maximum concentration deposited. Biologically...

  7. The comparative assessment of welders’ exposure to welding fumes based on mass and number concentration

    Directory of Open Access Journals (Sweden)

    Javad Sajedifar

    2016-12-01

    Full Text Available Introduction: Nowadays, Shielded Metal Arc Welding (SMAW is the most widely used arc welding. During the welding operation, typically, various harmful agents such as fumes, gases, heat, sound and ultraviolet radiation are produced of which fume is the most important component from the viewpoint of occupational health. The present study aims to compare the number and the mass concentration emitted in SMAW to determine the most appropriate index of exposure to fumes in the welding processes. Material and Method: In this study, the portable laser aerosol spectrometer and dust monitor of GRIMM, model 1.106, was used to measure the number and mass concentration of fumes emitted from SMAW on 304 stainless steel with a thickness of 0.4 mm. Air sampling was performed at a distance of 41 cm representing the welder’s breathing zone. The measurements of number concentration (NC and mass concentration (MC were taken under the condition of 25 volt voltage and direct current of the electrode polarity. Result: The total NC and MC of welding fumes in welder’s breathing zone was 1140451 particles per liter and 1631.11 micrograms per cubic meter, respectively. The highest number concentration was found to correspond to the particles with 0.35 to 0.5 micrometer-sized distribution (NC1; 938976 particles per liter and the lowest was related to the particles with 5 to 6.5 micrometer-sized distribution (NC7; 288 particles per liter and the particles larger than 6.5 micrometer (NC8; 463 particles per liter. Moreover, the highest mass concentration was related to the particles with 0.35 to 0.5 micrometer-sized distribution (MC1; 450 micrograms per cubic meter and the particles larger than 6.5 micrometer (MC8; 355 micrograms per cubic meter. Conclusion: The findings indicated that there is no agreement between number and mass concentration as two particles assessment index, and as the particles’ size become smaller, the mismatch of them is becoming more apparent

  8. The effect of high lead concentrations on the mortality, mass and ...

    African Journals Online (AJOL)

    ... for the mortalities and mass losses observed, as lead at those concentrations could have disturbed the normal physiological functioning of the animals. The isopods avoided lead contaminated leaves in the behavioural tests, which could cause accumulation of leaf litter and thus a reduction of the decomposition rate.

  9. Contribution of creatine kinase MB mass concentration at admission to early diagnosis of acute myocardial infarction

    NARCIS (Netherlands)

    Bakker, A. J.; Gorgels, J. P.; van Vlies, B.; Koelemay, M. J.; Smits, R.; Tijssen, J. G.; Haagen, F. D.

    1994-01-01

    OBJECTIVE: To assess the diagnostic value at admission of creatine kinase MB mass concentration, alone or in combination with electrocardiographic changes, in suspected myocardial infarction. DESIGN: Prospective study of all consecutive patients admitted within 12 hours after onset of chest pain to

  10. Body mass index, gestational weight gain and fatty acid concentrations during pregnancy: the Generation R Study

    NARCIS (Netherlands)

    A.J. Vidakovic (Aleksandra Jelena); V.W.V. Jaddoe (Vincent); O. Gishti (Olta); J.F. Felix (Janine); M.A. Williams (Michelle); A. Hofman (Albert); H. Demmelmair (Hans); B. Koletzko (Berthold); H.W. Tiemeier (Henning); R. Gaillard (Romy)

    2015-01-01

    textabstractObesity during pregnancy may be correlated with an adverse nutritional status affecting pregnancy and offspring outcomes. We examined the associations of prepregnancy body mass index and gestational weight gain with plasma fatty acid concentrations in mid-pregnancy. This study was

  11. PM mass and elemental species concentration data for I-96 monitoring sites

    Data.gov (United States)

    U.S. Environmental Protection Agency — PM2.5 (fine) and PM10-2.5 (coarse) mass concentrations for monitoring sites located 10 m, 100 m and 300 m north of Interstate I-96 in Detroit, the water-soluble and...

  12. Assessment of Heavy Metals Concentrations in the Surface Water of ...

    African Journals Online (AJOL)

    The digested samples were analyzed for Fe, Cr, Cu, Zn and Pb using Atomic Absorption Spectrophotometer (Model IL250). The seasonal sequence of heavy metals concentrations showed Zn>Fe>Cr>Cu>Pb and Fe>Zn>Cr>Cu>Pb in dry and wet seasons respectively, while that of annual was Cr>Fe>Zn>Cu>Pb. The results ...

  13. Lead Concentrations and Risk Exposure Assessment in Surface ...

    African Journals Online (AJOL)

    ADOWIE PERE

    µm, < 250 µm, and < 75 µm of surface soils at undeveloped residential lands leased to auto-mechanic artisans for a minimum of ten years and estimated exposure risk for children that will reside on the polluted lands after the lease periods. Soil-Pb levels ranges obtained were ... Other factors considered were closeness to.

  14. Investigation of PM2.5mass concentration over India using a regional climate model.

    Science.gov (United States)

    Bran, Sherin Hassan; Srivastava, Rohit

    2017-05-01

    Seasonal variation of PM 2.5 (Particulate Matter region, however significant bias is observed in the model. PM 2.5 mass concentrations are highest over West Bengal (82± 33 μg m -3 ) and the lowest in Jammu & Kashmir (14± 11 μg m -3 ). Annual mean of simulated PM 2.5 mass over the Indian region is found to be 35± 9 μg m -3 . Higher values of PM 2.5 are found over the states, where the reported respiratory disorders are high. WRF-Chem simulated PM 2.5 mass concentration gives a clear perspective of seasonal and spatial distribution of fine aerosols over the Indian region. The outcomes of the study have significant impacts on environment, human health and climate. Copyright © 2017 Elsevier Ltd. All rights reserved.

  15. First observations of surface ozone concentration from the summit region of Mount Everest

    Science.gov (United States)

    Semple, John L.; Moore, G. W. K.

    2008-10-01

    The extreme height of Mount Everest is such that its summit region may periodically be in the lower stratosphere. In this regard it provides a unique location for observing the exchange of ozone between the upper troposphere and lower stratosphere. Here we report the first surface ozone measurements from the summit region of Mount Everest. Simultaneous measurements were recorded at different elevations on the north side from base camp (5676 m) to the summit (8848 m) during May 2005. The concentrations measured were as high as 70 ppb. Meteorological diagnostics suggest that the stratosphere as well as the long range transport of polluted tropospheric air masses from South East Asia are sources of the observed ozone. There is evidence that the source region for ozone in the vicinity of Mount Everest may vary with the onset of the summer monsoon.

  16. Correlations between urban atmospheric light extinction coefficients and fine particle mass concentrations

    Energy Technology Data Exchange (ETDEWEB)

    Trier, A.; Cabrini, N.; Ferrer, J. [Facultad de Ciencia, Universidad de Santiago de Chile, Santiago 2 (Chile); Olaeta, I. [SESMA, Santiago 1 (Chile)

    1997-07-01

    Total horizontal atmospheric light extinction coefficients as well as particle mass concentrations have been measured in downtown areas of Santiago de Chile, a heavily polluted city. Measurement campaigns were carried out in 1994 in 1995. Extinction measurements were made by a telephotometric technique in four wavelength bands; oscillating mass balance type instruments were used to measure PM2.5 and PM10 mass concentrations. The latter type instrument had not been available heretofore. The extensive continuous PM2.5 measurements are the first for this city. Strong and highly significant statistical correlations were found between extinction coefficients and mass concentrations, especially with the fine respirable or PM2.5 mass concentrations. Angstrom exponents and, in one case, mass extinction coefficients have been estimated. [Spanish] Se ha medido coeficientes atmosfericos totales horizontales de extincion de luz asi como concentraciones de masa de particulas atmosfericas en zonas centricas de Santiago de Chile, una ciudad altamente contaminada. Las campanas de medicion se han hecho en 1994 y en 1995. Las mediciones de extincion se han hecho por un metodo telefotometrico en cuatro bandas espectrales; las concentraciones de masa PM2.5 y PM10 se han medido con instrumentos del tipo de balanzas de masa oscilantes. Tales instrumentos no han estado disponibles durante trabajos anteriores. Las extensas mediciones continuas de concentraciones de masa PM2.5 son las primeras para Santiago de Chile. Se han encontrado fuertes correlaciones estadisticas, altamente significativas, entre coeficientes de extincion y concentraciones de masa, especialmente las concentraciones de particulas finas respirables PM2.5. Se han estimado tambien exponentes de Angstrom y, en un caso, coeficientes masicos de extincion.

  17. Application research of computational mass-transfer differential equation in MBR concentration field simulation.

    Science.gov (United States)

    Li, Chunqing; Tie, Xiaobo; Liang, Kai; Ji, Chanjuan

    2016-01-01

    After conducting the intensive research on the distribution of fluid's velocity and biochemical reactions in the membrane bioreactor (MBR), this paper introduces the use of the mass-transfer differential equation to simulate the distribution of the chemical oxygen demand (COD) concentration in MBR membrane pool. The solutions are as follows: first, use computational fluid dynamics to establish a flow control equation model of the fluid in MBR membrane pool; second, calculate this model by adopting direct numerical simulation to get the velocity field of the fluid in membrane pool; third, combine the data of velocity field to establish mass-transfer differential equation model for the concentration field in MBR membrane pool, and use Seidel iteration method to solve the equation model; last but not least, substitute the real factory data into the velocity and concentration field model to calculate simulation results, and use visualization software Tecplot to display the results. Finally by analyzing the nephogram of COD concentration distribution, it can be found that the simulation result conforms the distribution rule of the COD's concentration in real membrane pool, and the mass-transfer phenomenon can be affected by the velocity field of the fluid in membrane pool. The simulation results of this paper have certain reference value for the design optimization of the real MBR system.

  18. Synergistic effect of alcohol consumption and body mass on serum concentrations of cytokeratin-18.

    Science.gov (United States)

    Gonzalez-Quintela, Arturo; Tomé, Santiago; Fernandez-Merino, Carmen; Rey, Jesus; Meijide, Luis; Gude, Francisco

    2011-12-01

    Cytokeratin-18 is an essential component of the cytoskeleton of epithelial cells (including hepatocytes). Serum concentrations of cytokeratin-18 (tissue polypeptide-specific antigen [TPS]) are used as a marker of epithelial neoplasms. Here, we investigated the potential interaction between alcohol and obesity in relation to serum TPS concentrations. Alcohol consumption, body mass index, and components of metabolic syndrome were measured in a random sample (n = 420) of the adult population (aged 18 to 92 years, 45% men) from a single municipality. Regular alcohol intake of >20 g/d (women) or >30 g/d (men) was considered risky drinking. Serum TPS was measured with a commercial immunoassay. Risky drinking was associated with increased serum concentrations of TPS, which was particularly evident among obese individuals. Among individuals without risky drinking, TPS concentrations were similar for all levels of body mass. Conversely, among risky drinkers, serum TPS concentrations increased in parallel with body mass (p = 0.002). The odds ratio of a high (>100 U/l) TPS concentration for the combination of risky drinking and obesity was greater than the additive effect of the 2 separate factors, after adjusting for age and sex. A similar interaction was observed between risky drinking and abdominal adiposity, a major component of the metabolic syndrome. Serum TPS concentrations were correlated with markers of liver damage. Serum TPS was not superior to standard markers (gamma-glutamyl transferase and red blood cell mean volume) for the detection of risky drinking. There is a synergism between risky alcohol consumption and common metabolic disorders (particularly obesity) in relation to serum concentrations of cytokeratin-18 (TPS), which probably reflect liver disease. Copyright © 2011 by the Research Society on Alcoholism.

  19. Heat and mass transfer in magnetohydrodynamic Casson fluid over an exponentially permeable stretching surface

    Directory of Open Access Journals (Sweden)

    C.S.K. Raju

    2016-03-01

    Full Text Available In this study we analyzed the flow, heat and mass transfer behavior of Casson fluid past an exponentially permeable stretching surface in presence of thermal radiation, magneticfield, viscous dissipation, heat source and chemical reaction. We presented dual solutions by comparing the results of the Casson fluid with the Newtonian fluid. The governing partial nonlinear differential equations of the flow, heat and mass transfer are transformed into ordinary differential equations by using similarity transformation and solved numerically by using Matlab bvp4c package. The effects of various non-dimensional governing parameters on velocity, temperature and concentration profiles are discussed and presented graphically. Also, the friction factor, Nusselt and Sherwood numbers are analyzed and presented in tabular form for both Casson and Newtonian fluids separately. Under some special conditions the results of the present study have an excellent agreement with existing studies for both Casson and Newtonian fluid cases.

  20. Concentration distributions of thoron and radon near the ground surface

    Energy Technology Data Exchange (ETDEWEB)

    Katase, Akira [Tohwa Univ., Fukuoka (Japan). Faculty of Engineering

    1996-12-01

    One dimensional diffusion model with a constant diffusion coefficient is applied to the thoron concentration distributions in air above the ground. The experimental distributions are well described by the exponential function obtained from the model. Diffusion coefficients and thoron exhalation rates are estimated from the measured distributions, which are the average values for three months. The present values of thoron exhalation are however several times as small as those measured by other researchers. (author)

  1. Bayesian Estimation of the Active Concentration and Affinity Constants Using Surface Plasmon Resonance Technology.

    Directory of Open Access Journals (Sweden)

    Feng Feng

    Full Text Available Surface plasmon resonance (SPR has previously been employed to measure the active concentration of analyte in addition to the kinetic rate constants in molecular binding reactions. Those approaches, however, have a few restrictions. In this work, a Bayesian approach is developed to determine both active concentration and affinity constants using SPR technology. With the appropriate prior probabilities on the parameters and a derived likelihood function, a Markov Chain Monte Carlo (MCMC algorithm is applied to compute the posterior probability densities of both the active concentration and kinetic rate constants based on the collected SPR data. Compared with previous approaches, ours exploits information from the duration of the process in its entirety, including both association and dissociation phases, under partial mass transport conditions; do not depend on calibration data; multiple injections of analyte at varying flow rates are not necessary. Finally the method is validated by analyzing both simulated and experimental datasets. A software package implementing our approach is developed with a user-friendly interface and made freely available.

  2. INFLUENCE OF SURFACE-ACTIVE AGENT CONCENTRATION ON THE SPECTROPHOTOMETRIC BIOMASS ESTIMATION DURING SUBMERGED GROWTH OF Mycobacterium bovis

    Directory of Open Access Journals (Sweden)

    Sakai M.C.

    1997-01-01

    Full Text Available The influence of the surface-active agent Tween 80 (polyoxyethylene 20 sorbitan monoleate on the dispersed growth of Mycobacterium bovis - BCG - was studied. The slopes of the bacterial dry mass / absorbance curves, were significantly reduced, by the increase of the Tween 80 concentration in the medium. Such an influence was probably due to the effect Tween 80 had on the average size of bacterial clumps during the culture carried out in a bench fermenter

  3. A preformulation evaluation of a photosensitive surface active compound, explaining concentration dependent degradation.

    Science.gov (United States)

    Sigfridsson, Kalle; Carlsson, Karin E

    2017-11-15

    A candidate drug within the cardiovascular area was identified during early research and evaluated for further development. The aim was to understand and explain the degradation mechanisms for the present compound. The stability of the active pharmaceutical ingredient (API) in solution and solid state was studied during different conditions. The bulk compound was exposed to elevated temperatures, increased relative humidity and stressed light conditions. Degradation of the drug in solutions was followed in the presence versus absence of ethylenediaminetetraacetic acid (EDTA), during aerobic versus anaerobic conditions, stored protected from light versus exposed to light and as a function of pH and concentration. It was possible to improve the stability by adding EDTA and completely abolish degradation by storing dissolved compound at anaerobic conditions. Solutions of API were stable between pH3 and 7, with some degradation at pH1, when stored protected from light and at 22°C, but degrade rapidly when exposed to ambient light conditions. The degradation products were identified by mass spectroscopy. Degradation schemes were drawn. There was concentration dependence in the degradation of dissolved drug when exposed to light, showing a titration behavior that concurred with the measured critical micelle/aggregation concentration (CMC/CAC) of the compound. The compound was stable in solution during the investigated time period, at concentrations above CMC/CAC, where the molecule was protected from photodegradation when the compound aggregated. Below CMC/CAC, a significant degradation of the API occurred. This may be a potential explanation why other surface active compounds show concentration dependent degradation. The photosensitivity was also observed for the neutral compound in crystalline and amorphous form, as well as for the crystalline chloride salt of the drug. However, the degradation of amorphous form was faster compared to crystalline material. No

  4. Modeling of surface dust concentrations using neural networks and kriging

    Science.gov (United States)

    Buevich, Alexander G.; Medvedev, Alexander N.; Sergeev, Alexander P.; Tarasov, Dmitry A.; Shichkin, Andrey V.; Sergeeva, Marina V.; Atanasova, T. B.

    2016-12-01

    Creating models which are able to accurately predict the distribution of pollutants based on a limited set of input data is an important task in environmental studies. In the paper two neural approaches: (multilayer perceptron (MLP)) and generalized regression neural network (GRNN)), and two geostatistical approaches: (kriging and cokriging), are using for modeling and forecasting of dust concentrations in snow cover. The area of study is under the influence of dust emissions from a copper quarry and a several industrial companies. The comparison of two mentioned approaches is conducted. Three indices are used as the indicators of the models accuracy: the mean absolute error (MAE), root mean square error (RMSE) and relative root mean square error (RRMSE). Models based on artificial neural networks (ANN) have shown better accuracy. When considering all indices, the most precision model was the GRNN, which uses as input parameters for modeling the coordinates of sampling points and the distance to the probable emissions source. The results of work confirm that trained ANN may be more suitable tool for modeling of dust concentrations in snow cover.

  5. Isopleths of surface air concentration and surface air kerma rate due to a radioactive cloud released from a stack (3)

    International Nuclear Information System (INIS)

    Tachibana, Haruo; Kikuchi, Masamitsu; Sekita, Tsutomu; Yamaguchi, Takenori

    2004-06-01

    This report is a revised edition of 'Isopleths of Surface Air Concentration and Surface Air Absorbed Dose Rate due to a Radioactive Cloud Released from a Stack(II) '(JAERI-M 90-206) and based on the revised Nuclear Safety Guidelines reflected the ICRP1990 Recommendation. Characteristics of this report are the use of Air Karma Rate (Gy/h) instead of Air Absorbed Dose Rate (Gy/h), and the record of isopleths of surface air concentration and surface air karma rate on CD-ROM. These recorded data on CD-ROM can be printed out on paper and/or pasted on digital map by personal computer. (author)

  6. Program for estimating surface air concentrations of NPP discharge radionuclides

    International Nuclear Information System (INIS)

    Ivanov, E.A.; Ramzina, T.V.; Sokolova, E.Yu.

    1986-01-01

    Methods for calculating short-term values of ground-level specific activity in the NPP region and the values averaged for an extended period are described. These methods are realized in the LAURA program on the FORTRAN 4 language for the ES-1033 computer with the OS ES translator and the EMQ-666 computer. As a result of program execution, the user receives the following information: 1) the table for radionuclide surface specific activity values depending on the direction and distance from the source; the wind rose matrix and conditional probabilities of the atmosphere stability category; 2) the map of isolines of radionuclide specific activity in a grid given in polar coordinates with marks of level lines according to their values

  7. Stochastic Evaluation of Mass Fluxes from Point-Like Concentration Measurements

    Science.gov (United States)

    Cirpka, O. A.; Schwede, R. L.

    2009-12-01

    The contaminant mass flux crossing a control plane is an important metric in the assessment of natural attenuation at contaminated sites. For risk-assessment purpose, the mass flux must be estimated together with a level of uncertainty. We present a conditional Monte Carlo approach that allows estimating the full statistical distribution of mass flux. The approach is based on conditioning multiple realizations of the hydraulic conductivity field on all data available. We jointly determine a first-order decay coefficient in each realization, leading to conditional statistical distribution of all estimated parameters and the total mass flux. The resulting statistical distribution of contaminant mass fluxes can be used in contaminant risk analysis. The method is applied to data of hypothetical test cases, which gives the opportunity to compare estimation results to the true field. As concentration data we account for point-like measurements obtained in multi-level sampling wells. The obtained empirical distribution of mass flux crossing the multi-level sampling fence could be fitted very well by a log-normal distribution.

  8. Ozone-surface interactions: Investigations of mechanisms, kinetics, mass transport, and implications for indoor air quality

    Energy Technology Data Exchange (ETDEWEB)

    Morrison, Glenn Charles [Univ. of California, Berkeley, CA (United States)

    1999-12-01

    In this dissertation, results are presented of laboratory investigations and mathematical modeling efforts designed to better understand the interactions of ozone with surfaces. In the laboratory, carpet and duct materials were exposed to ozone and measured ozone uptake kinetics and the ozone induced emissions of volatile organic compounds. To understand the results of the experiments, mathematical methods were developed to describe dynamic indoor aldehyde concentrations, mass transport of reactive species to smooth surfaces, the equivalent reaction probability of whole carpet due to the surface reactivity of fibers and carpet backing, and ozone aging of surfaces. Carpets, separated carpet fibers, and separated carpet backing all tended to release aldehydes when exposed to ozone. Secondary emissions were mostly n-nonanal and several other smaller aldehydes. The pattern of emissions suggested that vegetable oils may be precursors for these oxidized emissions. Several possible precursors and experiments in which linseed and tung oils were tested for their secondary emission potential were discussed. Dynamic emission rates of 2-nonenal from a residential carpet may indicate that intermediate species in the oxidation of conjugated olefins can significantly delay aldehyde emissions and act as reservoir for these compounds. The ozone induced emission rate of 2-nonenal, a very odorous compound, can result in odorous indoor concentrations for several years. Surface ozone reactivity is a key parameter in determining the flux of ozone to a surface, is parameterized by the reaction probability, which is simply the probability that an ozone molecule will be irreversibly consumed when it strikes a surface. In laboratory studies of two residential and two commercial carpets, the ozone reaction probability for carpet fibers, carpet backing and the equivalent reaction probability for whole carpet were determined. Typically reaction probability values for these materials were 10

  9. The life-time of galactic bars: central mass concentrations and gravity torques

    OpenAIRE

    Bournaud, F.; Combes, F.; Semelin, B.

    2005-01-01

    Bars in gas-rich spiral galaxies are short-lived. They drive gas inflows through their gravity torques, and at the same time self-regulate their strength. Their robustness has been subject of debate, since it was thought that only the resulting central mass concentrations (CMCs) were weakening bars, and only relatively rare massive CMCs were able to completely destroy them. Through numerical simulations including gas dynamics, we find that with the gas parameters of normal spiral galaxies, th...

  10. Surface-MALDI mass spectrometry in biomaterials research

    DEFF Research Database (Denmark)

    Griesser, H.J.; Kingshott, P.; McArthur, S.L.

    2004-01-01

    Matrix-assisted laser desorption ionization mass spectrometry (MALDI-MS) has been used for over a decade for the determination of purity and accurate molecular masses of macromolecular analytes, such as proteins, in solution. In the last few years the technique has been adapted to become a new...

  11. Submicron particle mass concentrations and sources in the Amazonian wet season (AMAZE-08)

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Q.; Farmer, D. K.; Rizzo, L. V.; Pauliqueivis, T.; Kuwata, Mikinori; Karl, Thomas G.; Guenther, Alex B.; Allan, James D.; Coe, H.; Andreae, M. O.; Poeschl, U.; Jiminez, J. L.; Artaxo, Paulo; Martin, Scot T.

    2015-01-01

    Real-time mass spectra of non-refractory component of submicron aerosol particles were recorded in a tropical rainforest in the central Amazon basin during the wet season of 2008, as a part of the Amazonian Aerosol Characterization Experiment (AMAZE-08). Organic components accounted on average for more than 80% of the non-refractory submicron particle mass concentrations during the period of measurements. Ammonium was present in sufficient quantities to halfway neutralize sulfate. In this acidic, isoprene-dominated, low-NOx environment the high-resolution mass spectra as well as mass closures with ion chromatography measurements did not provide evidence for significant contributions of organosulfate species, at least at concentrations above uncertainty levels. Positive-matrix factorization of the time series of particle mass spectra identified four statistical factors to account for the variance of the signal intensities of the organic constituents: a factor HOA having a hydrocarbon-like signature and identified as regional emissions of primary organic material, a factor OOA-1 associated with fresh production of secondary organic material by a mechanism of BVOC oxidation followed by gas-to-particle conversion, a factor OOA-2 consistent with reactive uptake of isoprene oxidation products, especially epoxydiols by acidic particles, and a factor OOA-3 associated with long range transport and atmospheric aging. The OOA-1, -2, and -3 factors had progressively more oxidized signatures. Diameter-resolved mass spectral markers also suggested enhanced reactive uptake of isoprene oxidation products to the accumulation mode for the OOA-2 factor, and such size partitioning can be indicative of in-cloud process. The campaign-average factor loadings were in a ratio of 1.1:1.0 for the OOA-1 compared to the OOA-2 pathway, suggesting the comparable importance of gas-phase compared to particle-phase (including cloud waters) production pathways of secondary organic material during

  12. Influences mass concentration of P3HT and PCBM to application of organic solar cells

    International Nuclear Information System (INIS)

    Supriyanto, A.; Maya; Iriani, Y.; Ramelan, A. H.; Nurosyid, F; Rosa, E. S.

    2016-01-01

    Poly (3-hexylthiophene) (P3HT) and [6, 6] -phenyl-C61-butyric acid methyl ester (PCBM) are used for the organic solar cell applications. P3HT and PCBM act as donors and acceptors, respectively. In this study the efficiency of the P3HT: PCBM organic solar cells as function of the mass concentration of the blend P3HT: PCBM with 1, 2, 8, 16 mg/ml. Deposition P3HT:PCBM film using spin coating with a rotary speed of 2500 rpm for 10 seconds. Optical properties of absorption spectra characteristic using a UV-Visible Spectrometer Lambda 25 and electrical properties of I-V characteristic using Keithley 2602 instrument. The results of absoption spectra for P3HT:PCBM within different mass concentration obtained 500-600 nm wavelengths. The Energy-gap obtained about 1.9eV. The organic solar cells device performance were investigated using I-V cahractyeristic. For mass concentration of 1, 2, 8 and 16 mg/ml P3HT:PCBM were obtained 0.5×10"-"3%, 2.2×10"-"3%, 5.9×10"-"3%, and 6.1×10"-"3% efficiency of organics solar cells respectively. (paper)

  13. [Near surface CO2 concentration and its quantitative relationship with character of underlying surface in Shanghai City, China].

    Science.gov (United States)

    Pan, Chen; Zhu, Xi-yang; Jia, Wen-xiao; Yang, Fang; Liu, Ming; Xiang, Wei-ning

    2015-07-01

    Land use change and fossil fuel combustion due to urbanization have a significant effect on global carbon cycle and climate change. It's important to have an explicit understanding of the spatial distribution of CO2 to recognize and control GHG emission, which is helpful to reduce human-induced contribution to global climate change. The study area of this project was set in the city of Shanghai with intensive human activity and rapid urbanization. The monitoring of near surface CO2 concentration along 3 transects was conducted across an urban-rural gradient by means of near infrared gas analyzer Li-840A in spring, 2014. Remote sensing data were also used to derive underlying surface information. Further quantitative analysis of the mechanism of CO2 concentration's response to the characteristics of underlying surface was presented in this paper. The results showed that the average near surface CO2 concentration was (443.4±22.0) µmol . mol-1. CO2 concentration in city center was in average 12.5% (52.5 µLmol . mol-1) higher than that in the suburban area. Also, CO2 concentration showed a significant spatial differentiation, with the highest CO2 concentration in the northwest, the second highest in the southwest, and the lowest in the southeast, which was in accordance with the urbanization level of the underlying surface. The results revealed that the vegetation coverage rate (CVeg) was an important indicator to describe near surface CO2 concentration with a negative correlation, and the impervious surface area coverage rate (CISA) had lower explanatory power with a positive correlation. The study also found that the determination coefficient (R2) between CO2 concentration (CCO2) and CISA or CVeg achieved its highest value when the buffer distance was 5 km, and their quantitative relationships be described by a stepwise regression equation: CCO2=0.32CISA-0.89CVeg+445.13 (R2 =0.66, P<0.01).

  14. Spatial pattern of hormone and antibiotic concentrations in surface waters in Delaware

    Science.gov (United States)

    Vaicunas, R.; Inamdar, S. P.; Dutta, S.; Aga, D.; Zimmerman, L. R.

    2011-12-01

    Water quality surveys of the U.S. have confirmed the presence of hormones and antibiotics in some surface waters. Although the reported concentrations of these substances are extremely low, there is substantial concern about their effect on aquatic species. For example, chronic exposure to estradiol (E2β) concentrations as low as 40 ng/L have been shown to cause endocrine disruption in fish. Furthermore, there is potential for contaminants to enter our drinking supply. Significant sources of hormones and antibiotics include discharge from concentrated animal feeding operations (CAFOs) and wastewater treatment plants as well as runoff from agricultural land receiving application of animal manure. Since Sussex County, Delaware is one of the leading poultry producing counties in the nation, and many farmers in the state use poultry litter as fertilizer for their crops, it is critical to study the concentrations of contaminants in surface waters. Fifty surface water (streams, lakes, and ponds) sampling locations throughout the state of Delaware were chosen based on DNREC (Delaware Department of Natural Resources and Environmental Control) data. Locations with the highest nitrogen and phosphorus levels were assumed to be associated with agriculture and wastewater sources and therefore were likely to be contaminated with hormones and antibiotics. The first set of sampling occurred in April representing high-flow conditions, and the second set will occur in September representing low-flow conditions. Water samples will be screened through the cost-effective enzyme-linked immunosorbent assay (ELISA) method followed by more rigorous analyses of selected samples using liquid chromatography-mass spectrometry (LC/MS/MS). ELISA screening includes estradiol (E2β), sulfamethazine and triclosan, while LC/MS/MS will quantify both free and conjugated forms of estrone (E1), estradiol (E2β), estriol (E3), as well as selected sulfa and tetracycline antibiotics. Initial ELISA results

  15. Body mass index, neighborhood fast food and restaurant concentration, and car ownership.

    Science.gov (United States)

    Inagami, Sanae; Cohen, Deborah A; Brown, Arleen F; Asch, Steven M

    2009-09-01

    Eating away from home and particularly fast food consumption have been shown to contribute to weight gain. Increased geographic access to fast food outlets and other restaurants may contribute to higher levels of obesity, especially in individuals who rely largely on the local environment for their food purchases. We examined whether fast food and restaurant concentrations are associated with body mass index and whether car ownership might moderate this association. We linked the 2000 US Census data and information on locations of fast food and other restaurants with the Los Angeles Family and Neighborhood Study database, which consists of 2,156 adults sampled from 63 neighborhoods in Los Angeles County. Multilevel modeling was used to estimate associations between body mass index (BMI), fast food and restaurant concentration, and car ownership after adjustment for individual-level factors and socioeconomic characteristics of residential neighborhoods. A high concentration of local restaurants is associated with BMI. Car owners have higher BMIs than non-car owners; however, individuals who do not own cars and reside in areas with a high concentration of fast food outlets have higher BMIs than non-car owners who live in areas with no fast food outlets, approximately 12 lb more (p = 0.02) for an individual with a height of 5 ft. 5 in. Higher restaurant density is associated with higher BMI among local residents. The local fast food environment has a stronger association with BMI for local residents who do not have access to cars.

  16. (137)Cs concentrations in Atlantic and western Antarctic surface waters: results of the 7th Ukrainian Antarctic Expedition, 2002.

    Science.gov (United States)

    Gulin, S B; Stokozov, N A

    2005-01-01

    The latitudinal distribution of (137)Cs in the Atlantic--western Antarctic surface waters was studied during the 7th Ukrainian Antarctic Expedition in January--May 2002. The (137)Cs concentrations have also been measured in the upper ice of the coastal glacier Woozle Hill located near the Ukrainian Antarctic station "Akademik Vernadsky" (western Antarctica, 65 degrees 15' S-64 degrees 16' W). Comparison of these data with results of previous same-route expeditions SWEDARP (Swedish Antarctic Research Expedition, 1988/1989) and the French R/V "Jeanne d'Arc" (1992/1993), has shown practically parallel changes of (137)Cs surface concentrations between 40 degrees N and 20 degrees S, pointing to decrease of (137)Cs radioactivity at these latitudes with an apparent half-life of 10--15 years (12.5+/-2.1 years on average). This suggests that decrease of (137)Cs surface concentration within this latitude band is controlled, besides the radioactive decay of (137)Cs (half-life=30 years), by vertical mixing of the upper water masses. South of 20 degrees S, the (137)Cs concentrations in surface water have decreased more rapidly because of the influence of the less contaminated Antarctic waters. At 50--60 degrees S and near the Antarctic coast, the (137)Cs activity in 2002 was similar to those measured during the SWEDARP and "Jeanne d'Arc" expeditions, suggesting an additional input of (137)Cs to these waters from the melted ice from the adjacent glaciers.

  17. The deconvolution of sputter-etching surface concentration measurements to determine impurity depth profiles

    International Nuclear Information System (INIS)

    Carter, G.; Katardjiev, I.V.; Nobes, M.J.

    1989-01-01

    The quasi-linear partial differential continuity equations that describe the evolution of the depth profiles and surface concentrations of marker atoms in kinematically equivalent systems undergoing sputtering, ion collection and atomic mixing are solved using the method of characteristics. It is shown how atomic mixing probabilities can be deduced from measurements of ion collection depth profiles with increasing ion fluence, and how this information can be used to predict surface concentration evolution. Even with this information, however, it is shown that it is not possible to deconvolute directly the surface concentration measurements to provide initial depth profiles, except when only ion collection and sputtering from the surface layer alone occur. It is demonstrated further that optimal recovery of initial concentration depth profiles could be ensured if the concentration-measuring analytical probe preferentially sampled depths near and at the maximum depth of bombardment-induced perturbations. (author)

  18. Influence of inundation of ground surface on 222Rn concentrations in shallow groundwater

    International Nuclear Information System (INIS)

    Hamada, Hiromasa; Abenney-Mickson, Stephen; Komae, Takami

    2004-01-01

    Radon-222 ( 222 Rn) is a good indicator for analyzing the speed at which surface water infiltrates the ground and reaches groundwater. Preferential flow, which is very fast, is expected to occur when the ground surface is inundated. Piston flow, which is very slow, is expected to occur when the ground surface is not inundated but is only sprinkled with water such as during a light rainfall. We hypothesized that preferential flow would reduce the 222 Rn concentration in groundwater but that piston flow would not; our study verified this hypothesis experimentally. We then measured 222 Rn concentration in groundwater for one year in low-land and upland locations. 222 Rn concentrations in groundwater decreased at the lowland site, where the ground surface was inundated by irrigation and heavy rainfall, while 222 Rn concentrations in groundwater did not decrease at the upland site, where the ground surface was not inundated. (author)

  19. Dependence of SOA oxidation on organic aerosol mass concentration and OH exposure: experimental PAM chamber studies

    Directory of Open Access Journals (Sweden)

    E. Kang

    2011-02-01

    Full Text Available The oxidation of secondary organic aerosol (SOA is studied with mass spectra analysis of SOA formed in a Potential Aerosol Mass (PAM chamber, a small flow-through photo-oxidation chamber with extremely high OH and ozone levels. The OH exposure from a few minutes in the PAM chamber is similar to that from days to weeks in the atmosphere. The mass spectra were measured with a Quadrupole Aerosol Mass Spectrometer (Q-AMS for SOA formed from oxidation of α-pinene, m-xylene, p-xylene, and a mixture of the three. The organic mass fractions of m/z 44 (CO2+ and m/z 43 (mainly C2H3O+, named f44 and f43 respectively, are used as indicators of the degree of organic aerosol (OA oxidation that occurs as the OA mass concentration or the OH exposure are varied. The degree of oxidation is sensitive to both. For a fixed OH exposure, the degree of oxidation initially decreases rapidly and then more slowly as the OA mass concentration increases. For fixed initial precursor VOC amounts, the degree of oxidation increases linearly with OH exposure, with f44 increasing and f43 decreasing. In this study, the degree of SOA oxidation spans much of the range observed in the atmosphere. These results, while sensitive to the determination of f44 and f43, provide evidence that some characteristics of atmospheric OA oxidation can be generated in a PAM chamber. For all measurements in this study, the sum of f44 and f43 is 0.25 ± 0.03, so that the slope of a linear regression is approximately −1 on an f44 vs. f43 plot. This constancy of the sum suggests that these ions are complete proxies for organic mass in the OA studied.

  20. Greenland surface mass-balance observations from the ice-sheet ablation area and local glaciers

    DEFF Research Database (Denmark)

    Machguth, Horst; Thomsen, Henrik H.; Weidick, Anker

    2016-01-01

    Glacier surface mass-balance measurements on Greenland started more than a century ago, but no compilation exists of the observations from the ablation area of the ice sheet and local glaciers. Such data could be used in the evaluation of modelled surface mass balance, or to document changes in g...

  1. Greenland surface mass-balance observations from the ice-sheet ablation area and local glaciers

    NARCIS (Netherlands)

    Machguth, Horst; Thomsen, Henrik H.; Weidick, Anker; Ahlstrøm, Andreas P.; Abermann, Jakob; Andersen, Morten L.; Andersen, Signe B.; Bjørk, Anders A.; Box, Jason E.; Braithwaite, Roger J.; Bøggild, Carl E.; Citterio, Michele; Clement, Poul; Colgan, William; Fausto, Robert S.; Gleie, Karin; Gubler, Stefanie; Hasholt, Bent; Hynek, Bernhard; Knudsen, Niels T.; Larsen, Signe H.; Mernild, Sebastian H.; Oerlemans, Johannes; Oerter, Hans; Olesen, Ole B.; Smeets, C. J P Paul; Steffen, Konrad; Stober, Manfred; Sugiyama, Shin; Van As, Dirk; Van Den Broeke, Michiel R.; Van De Wal, Roderik S W

    2016-01-01

    Glacier surface mass-balance measurements on Greenland started more than a century ago, but no compilation exists of the observations from the ablation area of the ice sheet and local glaciers. Such data could be used in the evaluation of modelled surface mass balance, or to document changes in

  2. Sensitivity of Greenland Ice Sheet surface mass balance to surface albedo parameterization: a study with a regional climate model

    Directory of Open Access Journals (Sweden)

    J. H. van Angelen

    2012-10-01

    Full Text Available We present a sensitivity study of the surface mass balance (SMB of the Greenland Ice Sheet, as modeled using a regional atmospheric climate model, to various parameter settings in the albedo scheme. The snow albedo scheme uses grain size as a prognostic variable and further depends on cloud cover, solar zenith angle and black carbon concentration. For the control experiment the overestimation of absorbed shortwave radiation (+6% at the K-transect (west Greenland for the period 2004–2009 is considerably reduced compared to the previous density-dependent albedo scheme (+22%. To simulate realistic snow albedo values, a small concentration of black carbon is needed, which has strongest impact on melt in the accumulation area. A background ice albedo field derived from MODIS imagery improves the agreement between the modeled and observed SMB gradient along the K-transect. The effect of enhanced meltwater retention and refreezing is a decrease of the albedo due to an increase in snow grain size. As a secondary effect of refreezing the snowpack is heated, enhancing melt and further lowering the albedo. Especially in a warmer climate this process is important, since it reduces the refreezing potential of the firn layer that covers the Greenland Ice Sheet.

  3. Controlled Dissolution of Surface Layers for Elemental Analysis by Inductively Coupled Plasma-Mass Spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Lorge, Susan Elizabeth [Iowa State Univ., Ames, IA (United States)

    2007-01-01

    Determining the composition of thin layers is increasingly important for a variety of industrial materials such as adhesives, coatings and microelectronics. Secondary ion mass spectrometry (SIMS), Auger electron spectroscopy (AES), X-ray photoelectron spectroscopy (XPS), glow discharge optical emission spectroscopy (GDOES), glow discharge mass spectrometry (GDMS), and laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) are some of the techniques that are currently employed for the direct analysis of the sample surface. Although these techniques do not suffer from the contamination problems that often plague sample dissolution studies, they do require matrix matched standards for quantification. Often, these standards are not readily available. Despite the costs of clean hoods, Teflon pipette tips and bottles, and pure acids, partial sample dissolution is the primary method used in the semiconductor industry to quantify surface impurities. Specifically, vapor phase decomposition (VPD) coupled to ICP-MS or total reflection x-ray fluorescence (TXRF) provides elemental information from the top most surface layers at detection sensitivities in the 107-1010atoms/cm2 range. The ability to quantify with standard solutions is a main advantage of these techniques. Li and Houk applied a VPD-like technique to steel. The signal ratio of trace element to matrix element was used for quantification. Although controlled dissolution concentrations determined for some of the dissolved elements agreed with the certified values, concentrations determined for refractory elements (Ti, Nb and Ta) were too low. LA-ICP-MS and scanning electron microscopy (SEM) measurements indicated that carbide grains distributed throughout the matrix were high in these refractory elements. These elements dissolved at a slower rate than the matrix element, Fe. If the analyte element is not removed at a rate similar to the matrix element a true

  4. Mass concentrations and elemental composition of urban atmospheric aerosols in Addis Ababa, Ethiopia

    Directory of Open Access Journals (Sweden)

    E. Sahle-Demissie

    2010-06-01

    Full Text Available Aerosol samples were collected from 22 February 2008 to 15 April 2008 and 17 June 2008 to 23 July 2008 in urban and peri-urban areas of Addis Ababa, Ethiopia, with the aim to assess the spatial and temporal aspects of total suspended particulate (TSP and particulate matter with aerodynamic diameter less than 10 μm (PM10 and their composition in terms of metallic elements. Sixty six filter samples were collected from seven distinct sites using I.O.M. multi fraction dust samplers and fiber glass filter papers. The mass of each particulate matter sample was measured gravimetrically and the composition of PM10 samples was analyzed using ICP-OAES and SEM-EDAX. The concentration of TSP was in the range of 17-556 μg/m3 and that of PM10 was in the range of 17-285 μg/m3. The highest TSP and PM10 peak values were observed in February 2008 at two sites, whereas the lowest TSP and PM10 values were observed in June and July 2008 at two sites. The mean TSP concentration surpassed the WHO safe guideline value of 150 μg/m3 and 79 % of the PM10 values were below the WHO guideline value. The PM10 to TSP mass ratio was in the range 0.26-0.59 and PM10 mass contributed about 39% to the TSP mass. The average element concentration in PM10 filter sample was in the order of Ca > Na > K > Zn > Sb > B > Al > V > Mg > S > Fe. All the analyzed elements contributed about 0.1% to the PM10 mass. SEM-EDAX analysis of PM10 samples showed that Si, Al, Na, Zn, Ba, K and C were the predominant species. Crustal materials contributed 76-95% of the filter mass, and C and Cu represented 5-24%. The size distribution of aerosol particles as derived from SEM analysis was in 0.43-9.3 μm range.

  5. Greenland surface mass-balance observations from the ice-sheet ablation area and local glaciers

    DEFF Research Database (Denmark)

    Machguth, Horst; Thomsen, Henrik H.; Weidick, Anker

    2016-01-01

    Glacier surface mass-balance measurements on Greenland started more than a century ago, but no compilation exists of the observations from the ablation area of the ice sheet and local glaciers. Such data could be used in the evaluation of modelled surface mass balance, or to document changes...... in glacier melt independently from model output. Here, we present a comprehensive database of Greenland glacier surface mass-balance observations from the ablation area of the ice sheet and local glaciers. The database spans the 123 a from 1892 to 2015, contains a total of similar to 3000 measurements from......-term time series of which there are only two exceeding 20 a. We use the data to analyse uncertainties in point measurements of surface mass balance, as well as to estimate surface mass-balance profiles for most regions of Greenland....

  6. An Integrated Instrumentation System for Velocity, Concentration and Mass Flow Rate Measurement of Solid Particles Based on Electrostatic and Capacitance Sensors

    Directory of Open Access Journals (Sweden)

    Jian Li

    2015-12-01

    Full Text Available The online and continuous measurement of velocity, concentration and mass flow rate of pneumatically conveyed solid particles for the high-efficiency utilization of energy and raw materials has become increasingly significant. In this paper, an integrated instrumentation system for the velocity, concentration and mass flow rate measurement of dense phase pneumatically conveyed solid particles based on electrostatic and capacitance sensorsis developed. The electrostatic sensors are used for particle mean velocity measurement in combination with the cross-correlation technique, while the capacitance sensor with helical surface-plate electrodes, which has relatively homogeneous sensitivity distribution, is employed for the measurement of particle concentration and its capacitance is measured by an electrostatic-immune AC-based circuit. The solid mass flow rate can be further calculated from the measured velocity and concentration. The developed instrumentation system for velocity and concentration measurement is verified and calibrated on a pulley rig and through static experiments, respectively. Finally the system is evaluated with glass beads on a gravity-fed rig. The experimental results demonstrate that the system is capable of the accurate solid mass flow rate measurement, and the relative error is within −3%–8% for glass bead mass flow rates ranging from 0.13 kg/s to 0.9 kg/s.

  7. Daily Estimation of Fine Particulate Matter Mass Concentration Through Satellite Based Aerosol Optical Depth

    Science.gov (United States)

    Karimian, H.; Li, Q.; Li, C. C.; Fan, J.; Jin, L.; Gong, C.; Mo, Y.; Hou, J.; Ahmad, A.

    2017-10-01

    Estimating exposure to fine Particulate Matter (PM2.5) requires surface with high spatial resolution. Aerosol optical depth (AOD) is one of MODIS products, being used to monitor PM2.5 concentration on ground level indirectly. In this research, AOD was derived in fine spatial resolution of 1×1 Km by utilizing an algorithm developed in which local aerosol models and conditions were took into account. Afterwards, due to spatial varying the relation between AOD-PM2.5, a regional scale geographically weighted regression model (GWR) was developed to derive daily seamless surface concentration of PM2.5 over Beijing, Tianjin and Hebei. For this purpose , various combinations of explanatory variables were investigated in the base of data availability, among which the best one includes AOD, PBL height, mean value of RH in boundary layer, mean value of temperature in boundary layer, wind speed and pressure was selected for the proposed GWR model over study area. The results show that, our model produces surface concentration of PM2.5 with annual RMSE of 18.6μg/m3. Besides, the feasibility of our model in estimating air pollution level was also assessed and high compatibility between model and ground monitoring was observed, which demonstrates the capability of the MODIS AOD and proposed model to estimate ground level PM2.5.

  8. High frequency analysis of a plate carrying a concentrated nonlinear spring-mass system

    Science.gov (United States)

    Culver, Dean; Dowell, Earl

    2016-09-01

    Examining the behavior of dynamical systems with many degrees of freedom undergoing random excitation at high frequency often requires substantial computation. These requirements are even more stringent for nonlinear systems. One approach for describing linear systems, Asymptotic Modal Analysis (AMA), has been extended to nonlinear systems in this paper. A prototypical system, namely a thin plate carrying a concentrated hardening cubic spring-mass, is explored. The study focuses on the response of three principal variables to random, frequency-bounded excitation: the displacement of the mounting location of the discrete spring-mass, the relative displacement of the discrete mass to this mounting location, and the absolute displacement of the discrete mass. The results indicate that extending AMA to nonlinear systems for input frequency bands containing a large number of modes is feasible. Several advantageous properties of nonlinear AMA are found, and an additional reduced frequency-domain modal method, Dominance-Reduced Classical Modal Analysis (DRCMA), is proposed that is intermediate in accuracy and the cost of computation between AMA and Classical Modal Analysis (CMA).

  9. A miniature system for separating aerosol particles and measuring mass concentrations.

    Science.gov (United States)

    Liang, Dao; Shih, Wen-Pin; Chen, Chuin-Shan; Dai, Chi-An

    2010-01-01

    We designed and fabricated a new sensing system which consists of two virtual impactors and two quartz-crystal microbalance (QCM) sensors for measuring particle mass concentration and size distribution. The virtual impactors utilized different inertial forces of particles in air flow to classify different particle sizes. They were designed to classify particle diameter, d, into three different ranges: d3.20 μm. The QCM sensors were coated with a hydrogel, which was found to be a reliable adhesive for capturing aerosol particles. The QCM sensor coated with hydrogel was used to measure the mass loading of particles by utilizing its characteristic of resonant frequency shift. An integrated system has been demonstrated.

  10. A Miniature System for Separating Aerosol Particles and Measuring Mass Concentrations

    Directory of Open Access Journals (Sweden)

    Dao Liang

    2010-04-01

    Full Text Available We designed and fabricated a new sensing system which consists of two virtual impactors and two quartz-crystal microbalance (QCM sensors for measuring particle mass concentration and size distribution. The virtual impactors utilized different inertial forces of particles in air flow to classify different particle sizes. They were designed to classify particle diameter, d, into three different ranges: d < 2.28 μm, 2.28 μm ≤ d ≤ 3.20 μm, d > 3.20 μm. The QCM sensors were coated with a hydrogel, which was found to be a reliable adhesive for capturing aerosol particles. The QCM sensor coated with hydrogel was used to measure the mass loading of particles by utilizing its characteristic of resonant frequency shift. An integrated system has been demonstrated.

  11. Quantifying the impact of climate change on enteric waterborne pathogen concentrations in surface water

    NARCIS (Netherlands)

    Hofstra, N.

    2011-01-01

    Climate change, among other factors, will impact waterborne pathogen concentrations in surface water worldwide, possibly increasing the risk of diseases caused by these pathogens. So far, the impacts are only determined qualitatively and thorough quantitative estimates of future pathogen

  12. Effects of mass transfer between Martian satellites on surface geology

    Science.gov (United States)

    2015-12-21

    suspected. Published by Elsevier Inc.1. Introduction Several features about the surface geology on the moons of Mars remain poorly understood. The grooves on...Deimos may have an effect on Phobos’ geology ; we shall attempt to estimate the magnitude of that effect in Section 4. For impacts with Mars, Phobos or...global surface geology , particularly in the 100+ Ma since the last Voltaire-sized impact. Therefore we believe it unlikely that the red veneer of

  13. Mass transfer from smooth alabaster surfaces in turbulent flows

    Science.gov (United States)

    Opdyke, Bradley N.; Gust, Giselher; Ledwell, James R.

    1987-11-01

    The mass transfer velocity for alabaster plates in smooth-wall turbulent flow is found to vary with the friction velocity according to an analytic solution of the advective diffusion equation. Deployment of alabaster plates on the sea floor can perhaps be used to estimate the viscous stress, and transfer velocities for other species.

  14. How effective would solar geoengineering be at offsetting surface mass balance losses of the ice-sheets?

    Science.gov (United States)

    Irvine, P. J.; Keith, D.

    2016-12-01

    Studies of the sea-level rise response to solar geoengineering suggest that it could be highly effective at reducing sea-level rise by reducing thermal expansion of ocean waters and reducing the melting of land ice. However, all studies to date have employed simplistic treatments of surface mass balance where melt is a function only of surface air temperature and many have not had explicit treatments of accumulation. Solar geoengineering would counteract the longwave forcing of elevated greenhouse gas concentrations by reducing incoming solar radiation, changing the seasonal, latitudinal and vertical distribution of energy within the climate system. Climate model simulations suggest that solar geoengineering deployed to counter future warming from rising greenhouse gas concentrations could partially offset many climate trends associated with rising greenhouse gas concentrations, however it would lead to a suppression of the hydrological cycle as well as leading to substantial residual regional climate changes. In this study the response of the surface mass balance of the Greenland and Antarctic ice sheets to solar geoengineering will be investigated. Multi-model results from G1, the idealized solar insolation reduction experiment of the Geoengineering Model Intercomparison Project (GeoMIP), will be compared against results from the abrupt4×CO2 and piControl experiment. The energy and mass balance of the ice sheets, as well as the broader climate response in the polar regions will be analysed in the GeoMIP ensemble. This analysis will be complemented by offline surface mass balance simulations, including both those which directly simulate the energy balance and by those which use approximations based on surface air temperatures. This analysis will help to determine whether previous studies have over- or under-estimated the efficacy of solar geoengineering at offsetting future sea-level rise.

  15. Laser surface processing with controlled nitrogen-argon concentration levels for regulated surface life time

    Science.gov (United States)

    Obeidi, M. Ahmed; McCarthy, E.; Brabazon, D.

    2018-03-01

    Laser surface modification can be used to enhance the mechanical properties of a material, such as hardness, toughness, fatigue strength, and corrosion resistance. Surface nitriding is a widely used thermochemical method of surface modification, in which nitrogen is introduced into a metal or other material at an elevated temperature within a furnace. It is used on parts where there is a need for increased wear resistance, corrosion resistance, fatigue life, and hardness. Laser nitriding is a novel method of nitriding where the surface is heated locally by a laser, either in an atmosphere of nitrogen or with a jet of nitrogen delivered to the laser heated site. It combines the benefits of laser modification with those of nitriding. Recent work on high toughness tool steel samples has shown promising results due to the increased nitrogen gas impingement onto the laser heated region. Increased surface activity and nitrogen adsorption was achieved which resulted in a deeper and harder surface compared to conventional hardening methods. In this work, the effects of the laser power, pulse repetition frequency, and overlap percentage on laser surface treatment of 316 L SST steel samples with an argon-nitrogen jet will be presented. Resulting microstructure, phase type, microhardness, and wear resistance are presented.

  16. A Miniature System for Separating Aerosol Particles and Measuring Mass Concentrations

    OpenAIRE

    Liang; Shih; Chen; Dai

    2010-01-01

    We designed and fabricated a new sensing system which consists of two virtual impactors and two quartz-crystal microbalance (QCM) sensors for measuring particle mass concentration and size distribution. The virtual impactors utilized different inertial forces of particles in air flow to classify different particle sizes. They were designed to classify particle diameter, d, into three different ranges: d < 2.28 μm, 2.28 μm ≤ d ≤ 3.20 μm, d > 3.20 μm. The QCM sensors were coated with a hy...

  17. Effect of soil surface management on radiocesium concentrations in apple orchard and fruit

    International Nuclear Information System (INIS)

    Kusaba, Shinnosuke; Matsuoka, Kaori; Abe, Kazuhiro

    2016-01-01

    We investigated the effect of soil surface management on radiocesium accumulation in an apple orchard in Fukushima Prefecture over 4 years after Tokyo Electric Power Company’s Fukushima Daiichi nuclear power plant accident in mid-March 2011. Different types of soil surface management such as clean cultivation, intertillage management, intertillage with bark compost application, sod culture, and zeolite application were employed. The radiocesium concentrations in soil were higher in the surface layer (0–5 cm) than in the other layers. The radiocesium concentration in the surface layer soil with sod culture in 2014 increased non-significantly compared with that observed in 2011. The radiocesium concentration in the mid-layer soil (5–15 cm) managed with intertillage was higher than that in soil managed using other types of management. The radiocesium amount in the organic matter on the soil surface was the highest in sod culture, and was significantly lower in the management with intertillage. The radiocesium concentration in fruit decreased exponentially during the 4 years in each types of soil surface management. The decrease in radiocesium concentration showed similar trends with each type of soil surface management, even if the concentration in each soil layer varied according to the management applied. Furthermore, intertillage with bark compost application did not affect the radiocesium concentration in fruit. These results suggest that the soil surface management type that affected the radiocesium distribution in the soil or the compost application with conventional practice did not affect its concentration in fruit of apple trees for at least 4 years since the nuclear power plant accident, at a radiocesium deposition level similar to that recorded in Fukushima City. (author)

  18. The Relationship between Gastric Juice Nitrate/Nitrite Concentrations and Gastric Mucosal Surface pH

    OpenAIRE

    Lee, Hae Kyung; Kim, Hyunjung; Kim, Hyung-Keun; Cho, Young-Seok; Kim, Byung-Wook; Han, Sok-Won; Maeng, Lee So; Chae, Hiun-Suk; Kim, Hee Na

    2012-01-01

    Purpose To investigate gastric juice nitrate/nitrite concentration according to mucosal surface pH extent (area) of gastric corpus intimately contacting the gastric juice. Materials and Methods We included ninety-nine patients with dyspepsia. To evaluate gastric mucosal surface pH and its extent, gastric chromosocpy was performed by spraying phenol red dye on the corpus mucosa and estimating the extent of area with color changed. Nitrate/nitrite concentrations and pH of gastric juice were mea...

  19. Combined use of atomic force microscopy, X-ray photoelectron spectroscopy, and secondary ion mass spectrometry for cell surface analysis.

    Science.gov (United States)

    Dague, Etienne; Delcorte, Arnaud; Latgé, Jean-Paul; Dufrêne, Yves F

    2008-04-01

    Understanding the surface properties of microbial cells is a major challenge of current microbiological research and a key to efficiently exploit them in biotechnology. Here, we used three advanced surface analysis techniques with different sensitivity, probing depth, and lateral resolution, that is, in situ atomic force microscopy, X-ray photoelectron spectroscopy, and secondary ion mass spectrometry, to gain insight into the surface properties of the conidia of the human fungal pathogen Aspergillus fumigatus. We show that the native ultrastructure, surface protein and polysaccharide concentrations, and amino acid composition of three mutants affected in hydrophobin production are markedly different from those of the wild-type, thereby providing novel insight into the cell wall architecture of A. fumigatus. The results demonstrate the power of using multiple complementary techniques for probing microbial cell surfaces.

  20. Seaweed allelopathy against coral: surface distribution of a seaweed secondary metabolite by imaging mass spectrometry.

    Science.gov (United States)

    Andras, Tiffany D; Alexander, Troy S; Gahlena, Asiri; Parry, R Mitchell; Fernandez, Facundo M; Kubanek, Julia; Wang, May D; Hay, Mark E

    2012-10-01

    Coral reefs are in global decline, with seaweeds increasing as corals decrease. Although seaweeds inhibit coral growth, recruitment, and survivorship, the mechanism of these interactions is poorly understood. Here, we used field experiments to show that contact with four common seaweeds induces bleaching on natural colonies of Porites rus. Controls in contact with inert, plastic mimics of seaweeds did not bleach, suggesting seaweed effects resulted from allelopathy rather than shading, abrasion, or physical contact. Bioassay-guided fractionation of the hydrophobic extract from the red alga Phacelocarpus neurymenioides revealed a previously characterized antibacterial metabolite, neurymenolide A, as the main allelopathic agent. For allelopathy of lipid-soluble metabolites to be effective, the compounds would need to be deployed on algal surfaces where they could transfer to corals on contact. We used desorption electrospray ionization mass spectrometry (DESI-MS) to visualize and quantify neurymenolide A on the surface of P. neurymenioides, and we found the molecule on all surfaces analyzed, with highest concentrations on basal portions of blades.

  1. Numerical simulation of the double pits stress concentration in a curved casing inner surface

    Directory of Open Access Journals (Sweden)

    Wei Yan

    2016-12-01

    Full Text Available Sour or sweet oil fields development is common in recent years. Casing and tubing are usually subjected to pitting corrosion because of exposure to the strong corrosion species, such as CO2, H2S, and saline water. When the corrosion pits formed in the casing inner surface, localized stress concentration will occur and the casing strength will be degraded. Thus, it is essential to evaluate the degree of stress concentration factor accurately. This article performed a numerical simulation on double pits stress concentration factor in a curved inner surface using the finite element software ABAQUS. The results show that the stress concentration factor of double pits mainly depends on the ratio of two pits distance to the pit radius (L/R. It should not be only assessed by the absolute distance between the two pits. When the two pits are close and tangent, the maximum stress concentration factor will appear on the inner tangential edges. Stress concentration increased by double pits in a curved casing inner surface is more serious than that in a flat surface. A correction factor of 1.9 was recommended in the curved inner surface double pits stress concentration factor predict model.

  2. Establishing human heart chromium, cobalt and vanadium concentrations by inductively coupled plasma mass spectrometry.

    Science.gov (United States)

    Day, Patrick L; Eckdahl, Steven J; Maleszewski, Joseph J; Wright, Thomas C; Murray, David L

    2017-05-01

    Chromium, cobalt, and vanadium are used in metallic joint prosthesis. Case studies have associated elevated heart tissue cobalt concentrations with myocardial injury. To document the long term heart metal ion concentrations, a validated inductively coupled plasma mass spectroscopy (ICP-MS) method was needed. The method utilized a closed-vessel microwave digestion system to digest the samples. An ICP-MS method utilizing Universal Cell Technology was used to determine our target analyte concentrations. Accuracy was verified using reference materials. Precision, sensitivity, recovery and linearity studies were performed. This method was used to establish a reference range for a non-implant containing cohort of 80 autopsy human heart tissues RESULTS: This method demonstrated an analytic measurement range of 0.5-100ng/mL for each element. Accuracy was within ±10% of target value for each element. Within-run precision for each element was below 20% CV. The chromium, vanadium and cobalt concentrations (mean±SD) were 0.1523±0.2157μg/g, 0.0094±0.0211μg/g and 0.1039±0.1305μg/g respectively in 80 non-implant containing human heart tissue samples. This method provides acceptable recovery of the chromium, cobalt and vanadium in heart tissue; allowing assessment of the effects of metallic joint prosthesis on myocardial health. Copyright © 2017 Elsevier GmbH. All rights reserved.

  3. Significancy in atomic mass measurements and the topography of the mass-surface

    International Nuclear Information System (INIS)

    Audi, G.

    1991-01-01

    It is discussed how to explore new regions of the chart of the nuclides through masses, and what has to be understood under significant mass measurements. In the exploratory phase of a new region of the chart, a result with almost any accuracy is appropriate. The higher the accuracy is, the better the possibility is to see finer structures. (G.P.) 24 refs.; 10 figs

  4. Effect of dimethylamine on the gas phase sulfuric acid concentration measured by Chemical Ionization Mass Spectrometry

    CERN Document Server

    Rondo, L.; Kürten, A.; Adamov, A.; Bianchi, F.; Breitenlechner, M.; Duplissy, J.; Franchin, A.; Dommen, J.; Donahue, N. M.; Dunne, E. M.; Flagan, R. C.; Hakala, J.; Hansel, A.; Keskinen, H.; Kim, J.; Jokinen, T.; Lehtipalo, K.; Leiminger, M.; Praplan, A.; Riccobono, F.; Rissanen, M. P.; Sarnela, N.; Schobesberger, S.; Simon, M.; Sipilä, M.; Smith, J. N.; Tomé, A.; Tröstl, J.; Tsagkogeorgas, G.; Vaattovaara, P.; Winkler, P. M.; Williamson, C.; Wimmer, D.; Baltensperger, U.; Kirkby, J.; Kulmala, M.; Petäjä, T.; Worsnop, D. R.; Curtius, J.

    2016-01-01

    Sulfuric acid is widely recognized as a very important substance driving atmospheric aerosolnucleation. Based on quantum chemical calculations it has been suggested that the quantitative detectionof gas phase sulfuric acid (H2SO4) by use of Chemical Ionization Mass Spectrometry (CIMS) could be biased inthe presence of gas phase amines such as dimethylamine (DMA). An experiment (CLOUD7 campaign) was setup at the CLOUD (Cosmics Leaving OUtdoor Droplets) chamber to investigate the quantitative detection ofH2SO4in the presence of dimethylamine by CIMS at atmospherically relevant concentrations. For the first time inthe CLOUD experiment, the monomer sulfuric acid concentration was measured by a CIMS and by two CI-APi-TOF(Chemical Ionization-Atmospheric Pressure interface-Time Of Flight) mass spectrometers. In addition, neutralsulfuric acid clusters were measured with the CI-APi-TOFs. The CLOUD7 measurements show that in the presenceof dimethylamine (<5 to 70 pptv) the sulfuric acid monomer measured by the CIMS...

  5. Effect of dimethylamine on the gas phase sulfuric acid concentration measured by Chemical Ionization Mass Spectrometry

    Science.gov (United States)

    Rondo, L.; Ehrhart, S.; Kürten, A.; Adamov, A.; Bianchi, F.; Breitenlechner, M.; Duplissy, J.; Franchin, A.; Dommen, J.; Donahue, N. M.; Dunne, E. M.; Flagan, R. C.; Hakala, J.; Hansel, A.; Keskinen, H.; Kim, J.; Jokinen, T.; Lehtipalo, K.; Leiminger, M.; Praplan, A.; Riccobono, F.; Rissanen, M. P.; Sarnela, N.; Schobesberger, S.; Simon, M.; Sipilä, M.; Smith, J. N.; Tomé, A.; Tröstl, J.; Tsagkogeorgas, G.; Vaattovaara, P.; Winkler, P. M.; Williamson, C.; Wimmer, D.; Baltensperger, U.; Kirkby, J.; Kulmala, M.; Petäjä, T.; Worsnop, D. R.; Curtius, J.

    2016-03-01

    Sulfuric acid is widely recognized as a very important substance driving atmospheric aerosol nucleation. Based on quantum chemical calculations it has been suggested that the quantitative detection of gas phase sulfuric acid (H2SO4) by use of Chemical Ionization Mass Spectrometry (CIMS) could be biased in the presence of gas phase amines such as dimethylamine (DMA). An experiment (CLOUD7 campaign) was set up at the CLOUD (Cosmics Leaving OUtdoor Droplets) chamber to investigate the quantitative detection of H2SO4 in the presence of dimethylamine by CIMS at atmospherically relevant concentrations. For the first time in the CLOUD experiment, the monomer sulfuric acid concentration was measured by a CIMS and by two CI-APi-TOF (Chemical Ionization-Atmospheric Pressure interface-Time Of Flight) mass spectrometers. In addition, neutral sulfuric acid clusters were measured with the CI-APi-TOFs. The CLOUD7 measurements show that in the presence of dimethylamine (growth. Although it was found that the addition of dimethylamine dramatically changes the H2SO4 cluster distribution compared to binary (H2SO4-H2O) conditions, the CIMS detection efficiency does not seem to depend substantially on whether an individual H2SO4 monomer is clustered with a DMA molecule. The experimental observations are supported by numerical simulations based on A Self-contained Atmospheric chemistry coDe coupled with a molecular process model (Sulfuric Acid Water NUCleation) operated in the kinetic limit.

  6. Effect of mass concentration of immobilized Spirulina platensis on nitrogen removal from simulated shrimp pond water

    Directory of Open Access Journals (Sweden)

    Patama Lerksasen

    2007-11-01

    Full Text Available Spirulina platensis strain BP immobilized on fibrous polyester mat was applied for nitrogen removal from simulated shrimp pond water. Different S. platensis mass on mat was built up during immobilizing process by varying the amount of batch fed suspended S. platensis cells. During immobilization, 0.2 OD560 S. platensis was replenished to reactor and chlorophyll-a in the solution was monitored. The immobilized S. platensis mass was 63, 49 and 19 g dw-S. platensis/m2 for Sp V-1, Sp IV-1 and Sp II-1 mat reactors adding five, four and two times of 0.2 OD560 S. platensis respectively. In accordance with statistic, the results of nitrogen removal tests by applying those immobilized mats in circulated batch system reactors loaded with 1.94 gN/m2-d showed that there were significant differences on ammonia removal among the different initial S. platensis mass on mats (ANOVA; P<0.05. The Sp V-1, Sp IV-1 and Sp II-1 mats could reduce the ammonia nitrogen concentration from 1 mg-N/L to the level as low as 0.18 mg-N/L within 2 weeks. Transformation of 75-81% ammonia nitrogen to organic nitrogen in microalgal cells, of which 27-43% were detached to solution, resulted to 44-58% total nitrogen removed from the system.

  7. Surface modification of platelet concentrate bags to reduce biofilm formation and transfusion sepsis.

    Science.gov (United States)

    Wilson-Nieuwenhuis, Joels S T; Dempsey-Hibbert, Nina; Liauw, Christopher M; Whitehead, Kathryn A

    2017-12-01

    Bacterial contamination of blood products poses a major risk in transfusion medicine, including transfusions involving platelet products. Although testing systems are in place for routine screening of platelet units, the formation of bacterial biofilms in such units may decrease the likelihood that bacteria will be detected. This work determined the surface properties of p-PVC platelet concentrate bags and investigated how these characteristics influenced biofilm formation. Serratia marcescens and Staphylococcus epidermidis, two species commonly implicated in platelet contamination, were used to study biofilm growth. The platelet concentrate bags were physically flattened to determine if reducing the surface roughness altered biofilm formation. The results demonstrated that the flattening process of the platelet bags affected the chemistry of the surface and reduced the surface hydrophobicity. Flattening of the surfaces resulted in a reduction in biofilm formation for both species after 5 days, with S. marcescens demonstrating a greater reduction. However, there was no significant difference between the smooth and flat surfaces following 7 days' incubation for S. marcescens and no significant differences between any of the surfaces following 7 days' incubation for S. epidermidis. The results suggest that flattening the p-PVC surfaces may limit potential biofilm formation for the current duration of platelet storage time of 5 days. It is hoped that this work will enhance the understanding of how surface properties influence the development of microbial biofilms in platelet concentrate bags in order to devise a solution to discourage biofilm formation. Copyright © 2017 Elsevier B.V. All rights reserved.

  8. Effects of Exogenous Melatonin on Body Mass Regulation and Hormone Concentrations in Eothenomys miletus

    Directory of Open Access Journals (Sweden)

    Zhu, Wan-Long

    2013-04-01

    Full Text Available By regulating the pineal hormone, photoperiods affect many physiological characteristics in small mammals. Thus, melatonin might take part in the thermoregulation of seasonal variations in small mammals. This study determined the influence of melatonin treatment on thermogenic pattern, we measured body mass, thermogenic activities and hormone concentrations of Eothenomys miletus were given exogenous melatonin (MLT for 28 days. The results shown that body mass was reduced significantly, whereas resting metabolic rate (RMR and nonshivering thermogenesis (NST increased at 28 days in MLT group compared to control group as well as the oxidative capacities of mitochondria in liver and brown adipose tissue (BAT were enhanced; the contents of total and mitochodrial protein increased markedly. Melatonin treatment significantly increased the State 3, State 4 respiration of liver mitochondria, and the activity of cytochrome C oxidase (COX in liver; but the α-glerocephasphate oxidase (α-PGO capacity showed no differences during the acclimation in liver. Furthermore, the State 4 respiration, the activities of COX and α-PGO in BAT increased, respectively. The activity of thyroxin 5’-deiodinase ( T45’-DII in BAT increased remarkably. The serum content of thyroxine (T 4 decreased, and that of tri-iodothyronine (T 3 increased. Moreover, serum leptin levels showed no significant differences in MLT group compared to control group. Together, these data indicate that melatonin enhances thermogenic capacity in E. miletus. Our results suggested that melatonin is potentially involved in the regulation of body mass, adaptive thermogenic capacity and hormone concentrations in E. miletus.

  9. Anthropogenic Pollution in Izmit Bay: Heavy Metal Concentrations in Surface Sediments

    OpenAIRE

    YAŞAR, D.

    2014-01-01

    The extent of marine pollution in İzmit Bay is studied using geochemical data in surface sediments. The concentrations of 41 elements in 24 samples establish that surface sediments in inner and central İzmit Bay display significant enrichments in Ag, As, Cd, Cr, Co, Cu, Hg, Mo, P, Pb, Sb, Ti, V, and Zn associated with high concentrations of total organic carbon and sulphur. Geo-accumulation indices indicate that the inner and central İzmit Bay surface sediments are moderately to very...

  10. Effect of concentration and temperature on surface tension of sodium hyaluronate saline solutions.

    Science.gov (United States)

    Ribeiro, Walkiria; Mata, José Luis; Saramago, Benilde

    2007-06-19

    The effect of concentration and temperature on the surface tension of sodium hyaluronate (NaHA) saline solutions was investigated using the technique of the shape of pendant drops. The decay rate of the surface tension with the increase of NaHA concentration was well-described by the empirical Hua-Rosen equation. Adsorption at the air-liquid interface was estimated using the Gibbs equation. The temperature dependence of a dilute solution and a semidilute entangled solution was numerically fitted with a second-order polynomial equation. The surface behavior of the NaHA saline solutions was interpreted in terms of their known viscoelastic properties.

  11. Soret and Dufour effects on convective heat and mass transfer in stagnation-point flow towards a shrinking surface

    International Nuclear Information System (INIS)

    Bhattacharyya, Krishnendu; Layek, G C; Seth, G S

    2014-01-01

    A mathematical model is presented to study the Soret and Dufour effects on the convective heat and mass transfer in stagnation-point flow of viscous incompressible fluid towards a shrinking surface. Suitable similarity transformations are used to convert the governing partial differential equations into self-similarity ordinary differential equations that are then numerically solved by shooting method. Dual solutions for temperature and concentration are obtained in the presence of Soret and Dufour effects. Graphical representations of the heat and mass transfer coefficients, the dimensionless thermal and solute profiles for various values of Prandtl number, Lewis number, Soret number and Dufour number are demonstrated. With Soret number the mass transfer coefficient which is related to mass transfer rate increases for both solutions and the heat transfer coefficient (related to heat transfer rate) for both solutions becomes larger with Dufour number. The Prandtl number causes reduction in heat and the mass transfer coefficients and similarly with the Lewis number mass transfer coefficient decreases. Also, double crossing over is found in dual dimensionless temperature profiles for increasing Soret number and in dual dimensionless concentration profiles for the increase in Dufour number. Due to the larger values of Dufour number the thermal boundary layer increases and for Prandtl number increment it decreases; whereas, the solute boundary layer thickness reduces with increasing values of Prandtl number and Lewis number. (paper)

  12. Dependence of Ideality Factor in Lateral PNP Transistors on Surface Carrier Concentration

    Science.gov (United States)

    Li, Xingji; Yang, Jianqun; Barnaby, Hugh J.; Galloway, Kenneth F.; Schrimpf, Ronald D.; Fleetwood, Daniel M.; Liu, Chaoming

    2017-06-01

    The influence of surface carrier concentration on the ideality factor of excess base current (ΔIB) in gated lateral PNP (GLPNP) bipolar junction transistors (BJTs) induced by 1-MeV electrons is investigated. ΔIB in LPNP BJTs is impacted by the surface carrier density and radiation-induced interface traps. In GLPNP BJTs, the surface carrier concentration can be controlled by the voltage applied to a gate over the base region. The ideality factor changes after irradiation, and its dependence on emitter-base voltage (VEB) is a function of gate voltage. For the irradiated devices, as the gate voltage decreases from +20 to -5 V, the ideality factor for excess base current changes from a single slope to two-slope behavior. The majority carrier concentration at the surface of the base, controlled by the gate voltage, impacts the excess base current and its ideality factor.

  13. Active renin mass concentration to determine aldosterone-to-renin ratio in screening for primary aldosteronism

    Directory of Open Access Journals (Sweden)

    Corbin F

    2011-07-01

    Full Text Available François Corbin1, Pierre Douville2, Marcel Lebel3 1Division of Biochemistry, l'Université de Sherbrooke, Sherbrooke, Quebec, Canada; 2Division of Biochemistry; 3Division of Nephrology, L'Hôtel-Dieu de Québec Hospital and l'Université Laval, Quebec, CanadaBackground: Active renin mass concentration (ARC is independent of the endogenous level of angiotensinogen, and less variable and more reproducible than plasma renin activity. Reference values for the aldosterone-to-renin ratio (ARR using ARC are still undefined. The objective of the present study was to determine the threshold of ARR using ARC measurement to screen for primary aldosteronism.Methods: A total of 211 subjects were included in the study, comprising 78 healthy normotensive controls, 95 patients with essential hypertension, and 38 patients with confirmed primary aldosteronism (20 with surgery-confirmed aldosterone-producing adenoma and 18 with idiopathic adrenal hyperplasia. Blood samples were drawn from ambulatory patients and volunteers in the mid-morning without specific dietary restriction for measuring plasma aldosterone concentration, ARC, and serum potassium.Results: Most normotensive controls and essential hypertension patients had ARR results below 100 pmol/ng, a value which corresponded to 3.3 times the median of these two groups.Conclusion: Patients with ARR values above this level should be considered for further investigation (confirmatory tests or for repeat testing should ARR values be borderline. This study indicates that ARC can be used reliably in determining ARR for primary aldosteronism screening.Keywords: primary aldosteronism, active renin mass concentration, aldosterone-to-renin ratio

  14. Online sample concentration in partial-filling chiral electrokinetic chromatography – mass spectrometry.

    Science.gov (United States)

    Wuethrich, Alain; Haddad, Paul R; Quirino, Joselito P

    2014-11-01

    The concentration sensitivity of a racemic drug (chlorpheniramine maleate) in chiral capillary electrophoresis with electrospray ionization – mass spectrometric detection was improved ~500-fold via stacking. Enantiomeric separation was achieved through the use of a neutral chiral pseudostationary phase (2-hydroxpropyl-β-cyclodextrin), untreated fused-silica capillaries, and the application of a partial-filling technique to prevent the pseudostationary phase from entering the detector. A concentration factor of 50 resulted from field-enhanced sample injection(FESI). However, the higher concentration factor was achieved by combining FESI with micelle-to-solvent stacking (MSS) to increase sample load and focus the analyte band. MSS was achieved by injection of an ammonium lauryl sulfate micellar plug prior to sample injection. The sample diluent was a 20-fold dilution of the background electrolyte (50 mM ammonium acetate, pH 3.5) with 60% acetonitrile. This methodology provided a limit of detection (LOD) of as low as 5 ng/ml of the racemate.

  15. The effects of large-scale atmospheric flows on berylium-7 activity concentration in surface air.

    Science.gov (United States)

    Arkian, Foroozan; Meshkatee, Amir-Hussain; Bidokhti, Ali Akbar

    2010-09-01

    Understanding the exchange mechanism between stratosphere and troposphere is one of the most important concerns of meteorologists and climatologists for decades. Different methods are being adopted to study those mechanisms. One of those methods is the study upon the tropospheric concentration of conserve or passive entities with stratospheric origin. One of those passive entities is (7)Be that is produced upon the incident of cosmic rays on light atmospheric nuclei in the stratosphere. The availability of 5 years observations of (7)Be concentration in surface air in Tehran (35 degrees 41(') N, 51 degrees 18(') E) encouraged us to investigate meteorological condition effect on the surface concentration of (7)Be. Also, the intention was to see if there was any intrusion of stratospheric air into the troposphere at the time of high surface concentration of (7)Be and scavenging mechanism when the concentration was low. During the course of this study, it has been found that (7)Be concentration is high whenever there is a jet stream over Tehran. Since high-level jet streams normally form near tropopause folding, it could be interpreted as a sign of the intrusion of stratospheric air into the troposphere. It was also found that high concentration of (7)Be in the Tehran surface air in summer is associated with an upper ridge on 500 hPa surface located east of the city, and low concentration in winter is associated with an upper trough. The latter normally is seen whenever there is precipitation that suggests wet scavenging could be the reason for that observed low concentration.

  16. Fabrication of Hierarchically Micro- and Nano-structured Mold Surfaces Using Laser Ablation for Mass Production of Superhydrophobic Surfaces

    Science.gov (United States)

    Noh, Jiwhan; Lee, Jae-Hoon; Na, Suckjoo; Lim, Hyuneui; Jung, Dae-Hwan

    2010-10-01

    Many studies have examined the formation of surfaces with mixed patterns of micro- and nano-sized lotus leaves that have hydrophobic properties. In this study, micro- and nano-shapes such as lotus leaves were fabricated on a metal mold surface using laser ablation and ripple formation. A microstructure on the mold surface was replicated onto poly(dimethylsiloxane) (PDMS) using the polymer casting method to manufacture low-cost hydrophobic surfaces. A PDMS surface with micro- and nano-structures that were the inverse image of a lotus leaf showed hydrophobic characteristics (water contact angle: 157°). From these results, we deduced that portions of the microstructures were wet and that air gaps existed between the microstructures and the water drops. In this paper we suggest the possibility of the mass production of hydrophobic plastic surfaces and the development of a methodology for the hydrophobic texturing of various polymer surfaces, using the polymer casting method with laser-processed molds.

  17. Effects of different sulfuric acid etching concentrations on PEEK surface bonding to resin composite.

    Science.gov (United States)

    Chaijareenont, Pisaisit; Prakhamsai, Sasiprapha; Silthampitag, Patcharawan; Takahashi, Hidekazu; Arksornnukit, Mansuang

    2018-01-26

    This study evaluated the effects of surface pretreatment with different concentrations of sulfuric acid etching on surface properties and bonding between Polyetheretherketone (PEEK) and a resin composite. Six groups of surface pretreatment (no pretreatment, etched with 70, 80, 85, 90, and 98% sulfuric acid for 60 s) were treated on PEEK. Surface roughness, scanning electron microscopy (SEM) and atomic force microscopy (AFM) analyses were examined. Shear bond strength (SBS) and cross-sectional observations of the interfaces were performed. One-way ANOVA analysis revealed differences in surface roughness and SBS between groups. The 90 and 98% sulfuric acid etching significantly achieved the highest SBS (psulfuric acid etching were suggested to be the optimal concentration to improve adhesion between PEEK and the resin composite.

  18. Surface profiling of lithium with a laser-desorption mass-spectrometer microprobe

    International Nuclear Information System (INIS)

    Bickel, G.A.; Adams, H.M.

    1999-01-01

    A laser-desorption mass-spectrometer microprobe has been developed to profile Li distributions on the crevice surfaces of Cr-plated rolled-joint hubs. A single laser pulse is used to desorb and ionize the surface species followed by detection of Li + in a time-of-flight mass spectrometer. Images of the surface Li distribution are obtained with are solution of <10 μm. These images are directly compared with Li images from the more conventional secondary ion mass spectrometry technique and evaluated with respect to surface topographical features measured by secondary electron microscopy and atomic force microscopy. The laser-desorption images are shown to provide the same qualitative information as that available from secondary ion mass spectrometry. (author)

  19. STELLAR MASS-GAP AS A PROBE OF HALO ASSEMBLY HISTORY AND CONCENTRATION: YOUTH HIDDEN AMONG OLD FOSSILS

    Energy Technology Data Exchange (ETDEWEB)

    Deason, A. J.; Conroy, C. [Department of Astronomy and Astrophysics, University of California Santa Cruz, Santa Cruz, CA 95064 (United States); Wetzel, A. R. [Department of Astronomy, Yale University, New Haven, CT 06520 (United States); Tinker, J. L., E-mail: alis@ucolick.org [Center for Cosmology and Particle Physics, Department of Physics, New York University, New York, NY 10013 (United States)

    2013-11-10

    We investigate the use of the halo mass-gap statistic—defined as the logarithmic difference in mass between the host halo and its most massive satellite subhalo—as a probe of halo age and concentration. A cosmological N-body simulation is used to study N ∼ 25, 000 group/cluster-sized halos in the mass range 10{sup 12.5} < M{sub halo}/M{sub ☉} < 10{sup 14.5}. In agreement with previous work, we find that halo mass-gap is related to halo formation time and concentration. On average, older and more highly concentrated halos have larger halo mass-gaps, and this trend is stronger than the mass-concentration relation over a similar dynamic range. However, there is a large amount of scatter owing to the transitory nature of the satellite subhalo population, which limits the use of the halo mass-gap statistic on an object-by-object basis. For example, we find that 20% of very large halo mass-gap systems (akin to {sup f}ossil groups{sup )} are young and have likely experienced a recent merger between a massive satellite subhalo and the central subhalo. We relate halo mass-gap to the observable stellar mass-gap via abundance matching. Using a galaxy group catalog constructed from the Sloan Digital Sky Survey Data Release 7, we find that the star formation and structural properties of galaxies at fixed mass show no trend with stellar mass-gap. This is despite a variation in halo age of ≈2.5 Gyr over ≈1.2 dex in stellar mass-gap. Thus, we find no evidence to suggest that the halo formation history significantly affects galaxy properties.

  20. Particle number and mass exposure concentrations by commuter transport modes in Milan, Italy

    Directory of Open Access Journals (Sweden)

    Senem Ozgen

    2016-03-01

    Full Text Available There is increasing awareness amongst the general public about exposure to atmospheric pollution while travelling in urban areas especially when taking active travelling modes such as walking and cycling. This study presents a comparative investigation of ultrafine particles (UFP, PM10, PM2.5, PM1 exposure levels associated with four transport modes (i.e., walking, cycling, car, and subway in the city of Milan measured by means of portable instruments. Significant differences in particle exposure between transport modes were found. The subway mode was characterized by the highest PM mass concentrations: PM10, PM2.5, PM1 subway levels were respectively about 2-4-3 times higher than those of the car and open air active modes (i.e. cycling and walking. Conversely, these latter modes displayed the highest UFP levels about 2 to 3 times higher than the subway and car modes, highlighting the influence of direct traffic emissions. The car mode (closed windows, air conditioning and air recirculation on reported the lowest PM and UFP concentration levels. In particular, the open-air/car average concentration ratio varied from about 2 for UFP up to 4 for PM1 and 6 for PM10 and PM2.5, showing differences that increase with increasing particle size. This work points out that active mode travelling in Milan city centre in summertime results in higher exposure levels than the car mode. Walkers’ and cyclists’ exposure levels is expected to be even higher during wintertime, due to the higher ambient PM and UFP concentration. Interventions intended to re-design the urban mobility should therefore include dedicated routes in order to limit their exposure to PM and UFP by increasing their distance from road traffic.

  1. Reanalysis of and attribution to near-surface ozone concentrations in Sweden during 1990-2013

    Science.gov (United States)

    Andersson, Camilla; Alpfjord, Heléne; Robertson, Lennart; Karlsson, Per Erik; Engardt, Magnuz

    2017-11-01

    We have constructed two data sets of hourly resolution reanalyzed near-surface ozone (O3) concentrations for the period 1990-2013 for Sweden. Long-term simulations from a chemistry-transport model (CTM) covering Europe were combined with hourly ozone concentration observations at Swedish and Norwegian background measurement sites using retrospective variational data analysis. The reanalysis data sets show improved performance over the original CTM when compared to independent observations. In one of the reanalyses, we included all available hourly near-surface O3 observations, whilst in the other we carefully selected time-consistent observations. Based on the second reanalysis we investigated statistical aspects of the distribution of the near-surface O3 concentrations, focusing on the linear trend over the 24-year period. We show that high near-surface O3 concentrations are decreasing and low O3 concentrations are increasing, which is reflected in observed improvement of many health and vegetation indices (apart from those with a low threshold). Using the CTM we also conducted sensitivity simulations to quantify the causes of the observed change, focusing on three factors: change in hemispheric background concentrations, meteorology and anthropogenic emissions. The rising low concentrations of near-surface O3 in Sweden are caused by a combination of all three factors, whilst the decrease in the highest O3 concentrations is caused by European O3 precursor emissions reductions. While studying the impact of anthropogenic emissions changes, we identified systematic differences in the modeled trend compared to observations that must be caused by incorrect trends in the utilized emissions inventory or by too high sensitivity of our model to emissions changes.

  2. Monitoring salivary melatonin concentrations in children with sleep disorders using liquid chromatography-tandem mass spectrometry.

    Science.gov (United States)

    Khan, Sohil A; George, Rani; Charles, Bruce G; Taylor, Paul J; Heussler, Helen S; Cooper, David M; McGuire, Treasure M; Pache, David; Norris, Ross L G

    2013-06-01

    Melatonin is synthesized in the pineal gland and is an important circadian phase marker, especially in the determination of sleep patterns. Both temporary and permanent abnormal sleep patterns occur in children; therefore, it is desirable to have methods for monitoring melatonin in biological fluids in the diagnosis and treatment of such disorders. The objective of the study is to develop a liquid chromatography-tandem mass spectrometry method for the determination of melatonin in saliva and to apply it to monitoring salivary concentrations in children with sleep disorders. A deuterated internal standard (d7-melatonin) was added to a diluted saliva sample (20 µL) in an autosampler vial insert, and 50 µL were injected. Plasticware was strictly avoided, and all glassware was scrupulously cleaned and then baked at 120°C for at least 48 hours to obtain satisfactory performance. Reverse-phase chromatography was performed on a C8 column using a linear gradient elution profile comprising mobile phases A (0.1% aqueous formic acid) and B (15% methanol in acetonitrile containing 0.1% formic acid), pumped at a total flow rate of 0.8 mL/min. The run time was 8 minutes. After atmospheric pressure chemical ionization, mass spectrometric detection was in positive ion mode. Mass detection was by selected reaction monitoring mode with the following mass transitions used for quantification: melatonin, m/z 233.0 → 173.8 and d7-melatonin, m/z 240.0 → 178.3. Linearity (r > 0.999) was established from 3.9 to 1000 pg/mL. Imprecision (coefficient of variation percent) was less than 11%, and accuracy was 100-105% (7.0-900 pg/mL). The method was selective, and the mean (range) ratio of the slopes of calibrations in water to those in daytime saliva samples collected from 10 healthy adult subjects was 0.989 (0.982-0.997), indicating negligible matrix effects. The application of the assay was demonstrated in healthy adults and in children being clinically investigated for sleep

  3. Dual-Wavelength Surface Plasmon Resonance for Determining the Size and Concentration of Sub-Populations of Extracellular Vesicles.

    Science.gov (United States)

    Rupert, Deborah L M; Shelke, Ganesh V; Emilsson, Gustav; Claudio, Virginia; Block, Stephan; Lässer, Cecilia; Dahlin, Andreas; Lötvall, Jan O; Bally, Marta; Zhdanov, Vladimir P; Höök, Fredrik

    2016-10-04

    Accurate concentration determination of subpopulations of extracellular vesicles (EVs), such as exosomes, is of importance both in the context of understanding their fundamental biological role and of potentially using them as disease biomarkers. In principle, this can be achieved by measuring the rate of diffusion-limited mass uptake to a sensor surface modified with a receptor designed to only bind the subpopulation of interest. However, a significant error is introduced if the targeted EV subpopulation has a size, and thus hydrodynamic diffusion coefficient, that differs from the mean size and diffusion coefficient of the whole EV population and/or if the EVs become deformed upon binding to the surface. We here demonstrate a new approach to determine the mean size (or effective film thickness) of bound nanoparticles, in general, and EV subpopulation carrying a marker of interest, in particular. The method is based on operating surface plasmon resonance simultaneously at two wavelengths with different sensing depths and using the ratio of the corresponding responses to extract the particle size on the surface. By estimating in this way the degree of deformation of adsorbed EVs, we markedly improved their bulk concentration determination and showed that EVs carrying the exosomal marker CD63 correspond to not more than around 10% of the EV sample.

  4. The pattern of anthropogenic signal emergence in Greenland Ice Sheet surface mass balance

    NARCIS (Netherlands)

    Fyke, J.G.; Vizcaino, M.; Lipscomb, W.H.

    2014-01-01

    Surface mass balance (SMB) trends influence observed Greenland Ice Sheet (GrIS) mass loss, but the component of these trends related to anthropogenic forcing is unclear. Here we study the simulated spatial pattern of emergence of an anthropogenically derived GrIS SMB signal between 1850 and 2100

  5. Analysis of the lipidated recombinant outer surface protein A from Borrelia burgdorferi by mass spectrometry

    NARCIS (Netherlands)

    Bouchon, B.; Klein, Michele; Bischoff, Rainer; Van Dorsselaer, A.; Roitsch, C.

    1997-01-01

    The outer surface protein A, OspA, from the spirochete Borrelia burgdorferi is a lipoprotein of 25 kDa. The recombinant OspA (rOspA) expressed in Escherichia coli has been purified and analyzed by electrospray mass spectrometry (ESMS). A heterogenous spectrum gave a measured mass of 28,462 +/- 9 Da

  6. Is vacuum ultraviolet detector a concentration or a mass dependent detector?

    Science.gov (United States)

    Liu, Huian; Raffin, Guy; Trutt, Guillaume; Randon, Jérôme

    2017-12-29

    The vacuum ultraviolet detector (VUV) is a very effective tool for chromatogram deconvolution and peak identification, and can also be used for quantification. To avoid quantitative issues in relation to time drift, such as variation of peak area or peak height, the detector response type has to be well defined. Due to the make-up flow and pressure regulation of make-up, the detector response (height of the peak) and peak area appeared to be dependent on experimental conditions such as inlet pressure and make-up pressure. Even if for some experimental conditions, VUV looks like mass-flow sensitive detector, it has been demonstrated that VUV is a concentration sensitive detector. Copyright © 2017 Elsevier B.V. All rights reserved.

  7. C-reactive protein concentration predicts change in body mass index during childhood.

    Directory of Open Access Journals (Sweden)

    Barbara H Lourenço

    Full Text Available OBJECTIVE: Inflammation may constitute an underlying mechanism for increased risk of developing chronic diseases in later years, but few prospective studies have assessed the influence of low-grade inflammation on body weight gain, particularly among children in low- to middle-income settings with lower prevalence of overweight and obesity. We aimed to investigate whether C-reactive protein (CRP, as a biomarker of low-grade inflammation, predicts changes in body mass index-for-age z scores (BAZ during childhood. METHODS: A population-based longitudinal study was conducted in the Brazilian Amazon among children aged ≤10 years in 2007, with follow-up visits in 2009 and 2012. Outcome was annual change in BAZ. As the main exposure of interest, CRP concentrations were divided into four categories, with values 5 years, children in the highest tertile of CRP 5 years.

  8. 40 CFR Table F-5 to Subpart F of... - Estimated Mass Concentration Measurement of PM2.5 for Idealized “Typical” Coarse Aerosol Size...

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 5 2010-07-01 2010-07-01 false Estimated Mass Concentration... 53—Estimated Mass Concentration Measurement of PM2.5 for Idealized “Typical” Coarse Aerosol Size... Concentration (µg/m3) Estimated Mass Concentration Measurement (µg/m3) Ideal Sampler Fractional Sampling...

  9. The Role of the North Atlantic Oscillation (NAO) on Recent Greenland Surface Mass Loss and Mass Partitioning

    Science.gov (United States)

    Tedesco, M.; Alexander, P.; Porter, D. F.; Fettweis, X.; Luthcke, S. B.; Mote, T. L.; Rennermalm, A.; Hanna, E.

    2017-12-01

    Despite recent changes in Greenland surface mass losses and atmospheric circulation over the Arctic, little attention has been given to the potential role of large-scale atmospheric processes on the spatial and temporal variability of mass loss and partitioning of the GrIS mass loss. Using a combination of satellite gravimetry measurements, outputs of the MAR regional climate model and reanalysis data, we show that changes in atmospheric patterns since 2013 over the North Atlantic region of the Arctic (NAA) modulate total mass loss trends over Greenland together with the spatial and temporal distribution of mass loss partitioning. For example, during the 2002 - 2012 period, melting persistently increased, especially along the west coast, as a consequence of increased insulation and negative NAO conditions characterizing that period. Starting in 2013, runoff along the west coast decreased while snowfall increased substantially, when NAO turned to a more neutral/positive state. Modeled surface mass balance terms since 1950 indicate that part of the GRACE-period, specifically the period between 2002 and 2012, was exceptional in terms of snowfall over the east and northeast regions. During that period snowfall trend decreased to almost 0 Gt/yr from a long-term increasing trend, which presumed again in 2013. To identify the potential impact of atmospheric patterns on mass balance and its partitioning, we studied the spatial and temporal correlations between NAO and snowfall/runoff. Our results indicate that the correlation between summer snowfall and NAO is not stable during the 1950 - 2015 period. We further looked at changes in patterns of circulation using self organizing maps (SOMs) to identify the atmospheric patterns characterizing snowfall during different periods. We discuss potential implications for past changes and future GCM and RCM simulations.

  10. Surface photometry and mass distributions of spiral galaxies

    International Nuclear Information System (INIS)

    Blackman, C.P.

    1979-01-01

    U, B, V and R surface photometry is presented for the two luminosity class I-II galaxies NGC 1084 and 7331. The reduced profiles of both galaxies have well-defined outer components similar to that described in an earlier paper for NGC 157. The radial variation of M/L has been studied by extrapolating the observed rotation curves. The gross structure and detailed colour and M/L variations for both galaxies are described in terms of the density wave theory of spiral structure, which implies that the rotation curves are not flat at large radii. The outer components of both galaxies are too luminous to form conventional massive haloes. In both galaxies the total luminosity exceeds that expected from their luminosity class. (author)

  11. Association of urinary phthalate metabolites concentrations with body mass index and waist circumference.

    Science.gov (United States)

    Amin, Mohammad Mehdi; Parastar, Saeed; Ebrahimpour, Karim; Shoshtari-Yeganeh, Bahareh; Hashemi, Majid; Mansourian, Marjan; Kelishadi, Roya

    2018-04-01

    This study aims to investigate the association of urinary concentration of phthalate metabolites with body mass index (BMI) and waist circumference (WC) in 2016 on 242 children and adolescents, aged 6-18 years living in Isfahan, Iran. Urinary concentration of mono-butyl phthalate (MBP), mono-benzyl phthalate (MBzP), mono-2-ethylhexyl phthalate (MEHP), mono-methyl phthalate (MMP), mono (2-ethyl-5-exohexyl) phthalate (MEOHP), and mono (2-ethyl-5hydroxyhexyl) phthalate (MEHHP) metabolites were determined. For comparison of means, t test and to evaluate the association of analytes in different groups according to weight ANOVA was used. The correlation was applied to determine the association between phthalate metabolites with age, sex, WC, BMI, and BMI z-score. The univariate and multivariate regression models were used to determine the association of metabolites concentration with BMI z-score and WC. Mean (SD) BMI, BMI z-score and WC were 23.89 (4.41) kg/m 2 , 1.37 (1.3), and 82.37 (12.71) cm, respectively. There was a significant correlation between boys' age with BMI z-score (p value = 0.03) and WC (p value = 0.01), while the corresponding figures were not statistically significant in girls (p value = 0.48, and 0.4, respectively). Of the total population, 37 participants (15.3%) were obese. MMP, MBP, and MBzP metabolites were observed in all samples while MEHP, MEOHP, and MEHHP in 99.6, 95.86, and 96.28% of the studied population. Mean concentration of MMP (64.38 μg/L) and MBzP (268 μg/L) had the lowest and highest concentrations of metabolites, respectively. A significant relationship was observed among all studied metabolites and weight groups (p value ≤ 0.02). After adjustment for potential confounders, all metabolites (except MMP) showed a low-to-moderate positive and significant relationship with BMI z-score (β = 0.17-0.3). A weak to moderate positive and significant relationship was observed between all phthalate metabolites and WC (

  12. Surface modification of hexatriacontane by CF_4 plasmas studied by optical emission and threshold ionization mass spectrometries

    Science.gov (United States)

    Poncin-Epaillard, F.; Wang, W.; Ausserré, D.; Scharzenbach, W.; Derouard, J.; Sadeghi, N.

    1998-11-01

    The behavior of tetrafluoromethane microwave plasma (2% argon included) has been studied by emission spectroscopy during the treatment of hexatriacontane, a model for high density polyethylene. The evolution of the densities of F* atoms, and CF, CF^*2, radicals has been followed by using the actinometric technique with 2% argon added to the gas. The surface properties, such as surface energy and surface roughness were correlated to the emission intensity of reactives species in the plasma gas phase. We found that the evolution of the fluorinated species emissions in the plasma gas phase can be a direct indication of the surface modifications by the plasma. A mild exposure to the plasma can result in a great decrease of surface energy corresponding to the fluorination. The surface roughness only changes under drastic plasma conditions. Threshold ionization mass spectroscopy is applied to detect the fluorine atoms and CFx radicals. Time resolved measurements in pulsed plasma, give access to the decay rate of F atoms concentration in the afterglow, and to their sticking coefficient on different surfaces. The influences of the discharge parameters and of the surfaces (metal, silicon or hexatriacontane) in contact with the plasma are investigated. The results show that the plasma generated ions and/or UV radiations highly enhance the reactivity of the F atoms on polymer surface.

  13. Effect of dimethylamine on the gas phase sulfuric acid concentration measured by Chemical Ionization Mass Spectrometry.

    Science.gov (United States)

    Rondo, L; Ehrhart, S; Kürten, A; Adamov, A; Bianchi, F; Breitenlechner, M; Duplissy, J; Franchin, A; Dommen, J; Donahue, N M; Dunne, E M; Flagan, R C; Hakala, J; Hansel, A; Keskinen, H; Kim, J; Jokinen, T; Lehtipalo, K; Leiminger, M; Praplan, A; Riccobono, F; Rissanen, M P; Sarnela, N; Schobesberger, S; Simon, M; Sipilä, M; Smith, J N; Tomé, A; Tröstl, J; Tsagkogeorgas, G; Vaattovaara, P; Winkler, P M; Williamson, C; Wimmer, D; Baltensperger, U; Kirkby, J; Kulmala, M; Petäjä, T; Worsnop, D R; Curtius, J

    2016-03-27

    Sulfuric acid is widely recognized as a very important substance driving atmospheric aerosol nucleation. Based on quantum chemical calculations it has been suggested that the quantitative detection of gas phase sulfuric acid (H 2 SO 4 ) by use of Chemical Ionization Mass Spectrometry (CIMS) could be biased in the presence of gas phase amines such as dimethylamine (DMA). An experiment (CLOUD7 campaign) was set up at the CLOUD (Cosmics Leaving OUtdoor Droplets) chamber to investigate the quantitative detection of H 2 SO 4 in the presence of dimethylamine by CIMS at atmospherically relevant concentrations. For the first time in the CLOUD experiment, the monomer sulfuric acid concentration was measured by a CIMS and by two CI-APi-TOF (Chemical Ionization-Atmospheric Pressure interface-Time Of Flight) mass spectrometers. In addition, neutral sulfuric acid clusters were measured with the CI-APi-TOFs. The CLOUD7 measurements show that in the presence of dimethylamine (sulfuric acid monomer measured by the CIMS represents only a fraction of the total H 2 SO 4 , contained in the monomer and the clusters that is available for particle growth. Although it was found that the addition of dimethylamine dramatically changes the H 2 SO 4 cluster distribution compared to binary (H 2 SO 4 -H 2 O) conditions, the CIMS detection efficiency does not seem to depend substantially on whether an individual H 2 SO 4 monomer is clustered with a DMA molecule. The experimental observations are supported by numerical simulations based on A Self-contained Atmospheric chemistry coDe coupled with a molecular process model (Sulfuric Acid Water NUCleation) operated in the kinetic limit.

  14. AFM Studies of Salt Concentration Effects on the (110) Surface Structure of Tetragonal Lysozyme Crystals

    Science.gov (United States)

    Pusey, Marc Lee; Gorti, Sridhar; Forsythe, Elizabeth; Konnert, John

    2002-01-01

    Previous high resolution AFM studies of the (110) surface of tetragonal chicken egg white lysozyme crystals had shown that only one of two possible molecular surfaces is present, those constituting the completed 43 helices. These suggested that the crystal growth process was by the solution-phase assembly of the growth units, which then attach to the surface. However, the best fit for the imaged surfaces, vs. those predicted based upon the bulk crystallographic coordinates, were obtained when the packing about the 43 helices was "tightened up", while maintaining the underlying crystallographic unit cell spacing. This results in a widening of the gap between adjacent helices, and the top- most layer(s) may no longer be in contact. We postulated that the tightened packing about the helices is a result of the high salt concentrations in the bulk solution, used to crystallize the protein, driving hydrophobic interactions. Once the crystal surface is sufficiently buried by subsequent growth layers the ratio of salt to protein molecules decreases and the helices relax to their bulk crystallographic coordinates. The crystal surface helix structure is thus a reflection of the solution structure, and the tightness of the packing about the 43 helices would be a function of the bulk salt concentration. AFM images of the (110) surface of tetragonal lysozyme crystals grown under low (2%) and high (5%) NaCl concentrations reveal differences in the packing about the 43 helices consistent with the above proposal.

  15. {sup 137}Cs concentrations in Atlantic and western Antarctic surface waters: results of the 7th Ukrainian Antarctic Expedition, 2002

    Energy Technology Data Exchange (ETDEWEB)

    Gulin, S.B. [Institute of Biology of the Southern Seas (IBSS), 2, Nakhimov Av., Sevastopol, 99011 (Ukraine)]. E-mail: sergei@gulin.sebastopol.ua; Stokozov, N.A. [Institute of Biology of the Southern Seas (IBSS), 2, Nakhimov Av., Sevastopol, 99011 (Ukraine)

    2005-07-01

    The latitudinal distribution of {sup 137}Cs in the Atlantic-western Antarctic surface waters was studied during the 7th Ukrainian Antarctic Expedition in January-May 2002. The {sup 137}Cs concentrations have also been measured in the upper ice of the coastal glacier Woozle Hill located near the Ukrainian Antarctic station 'Akademik Vernadsky' (western Antarctica, 65 deg 15' S-64 deg 16' W). Comparison of these data with results of previous same-route expeditions SWEDARP (Swedish Antarctic Research Expedition, 1988/1989) and the French R/V 'Jeanne d'Arc' (1992/1993), has shown practically parallel changes of {sup 137}Cs surface concentrations between 40 deg N and 20 deg S, pointing to decrease of {sup 137}Cs radioactivity at these latitudes with an apparent half-life of 10-15 years (12.5{+-}2.1 years on average). This suggests that decrease of {sup 137}Cs surface concentration within this latitude band is controlled, besides the radioactive decay of {sup 137}Cs (half-life=30 years), by vertical mixing of the upper water masses. South of 20 deg S, the {sup 137}Cs concentrations in surface water have decreased more rapidly because of the influence of the less contaminated Antarctic waters. At 50-60 deg S and near the Antarctic coast, the {sup 137}Cs activity in 2002 was similar to those measured during the SWEDARP and 'Jeanne d'Arc' expeditions, suggesting an additional input of {sup 137}Cs to these waters from the melted ice from the adjacent glaciers.

  16. Long-term variations in the surface air 7Be concentration and climatic changes.

    Science.gov (United States)

    Jiwen, Liu; Starovoitova, Valeriia N; Wells, Douglas P

    2013-02-01

    We have used EML Surface Air Sampling Program (SASP) data to analyze the long-term trend in (7)Be surface concentration and address possible correlation between this long-term trend and climatic changes, namely changes in precipitation patterns and temperature. In this paper we present (7)Be concentration data from 23 sites, spanning over 25 years, all over the world, and extract long-term trend parameter using two independent techniques. The (7)Be concentrations in most stations show a pronounced decreasing trend, potentially corresponding to statistically significant changes in transporting (7)Be from upper atmosphere source to these sites. Weak negative correlation between (7)Be concentration and amount of precipitation was also observed. However, more data from more representative sites around the world are needed the statistical robustness of this trend. Published by Elsevier Ltd.

  17. The osmolyte xylitol reduces the salt concentration of airway surface liquid and may enhance bacterial killing

    Science.gov (United States)

    Zabner, Joseph; Seiler, Michael P.; Launspach, Janice L.; Karp, Philip H.; Kearney, William R.; Look, Dwight C.; Smith, Jeffrey J.; Welsh, Michael J.

    2000-10-01

    The thin layer of airway surface liquid (ASL) contains antimicrobial substances that kill the small numbers of bacteria that are constantly being deposited in the lungs. An increase in ASL salt concentration inhibits the activity of airway antimicrobial factors and may partially explain the pathogenesis of cystic fibrosis (CF). We tested the hypothesis that an osmolyte with a low transepithelial permeability may lower the ASL salt concentration, thereby enhancing innate immunity. We found that the five-carbon sugar xylitol has a low transepithelial permeability, is poorly metabolized by several bacteria, and can lower the ASL salt concentration in both CF and non-CF airway epithelia in vitro. Furthermore, in a double-blind, randomized, crossover study, xylitol sprayed for 4 days into each nostril of normal volunteers significantly decreased the number of nasal coagulase-negative Staphylococcus compared with saline control. Xylitol may be of value in decreasing ASL salt concentration and enhancing the innate antimicrobial defense at the airway surface.

  18. Detection of Adriamycin-DNA adducts by accelerator mass spectrometry at clinically relevant Adriamycin concentrations.

    Science.gov (United States)

    Coldwell, Kate E; Cutts, Suzanne M; Ognibene, Ted J; Henderson, Paul T; Phillips, Don R

    2008-09-01

    Limited sensitivity of existing assays has prevented investigation of whether Adriamycin-DNA adducts are involved in the anti-tumour potential of Adriamycin. Previous detection has achieved a sensitivity of a few Adriamycin-DNA adducts/10(4) bp DNA, but has required the use of supra-clinical drug concentrations. This work sought to measure Adriamycin-DNA adducts at sub-micromolar doses using accelerator mass spectrometry (AMS), a technique with origins in geochemistry for radiocarbon dating. We have used conditions previously validated (by less sensitive decay counting) to extract [(14)C]Adriamycin-DNA adducts from cells and adapted the methodology to AMS detection. Here we show the first direct evidence of Adriamycin-DNA adducts at clinically-relevant Adriamycin concentrations. [(14)C]Adriamycin treatment (25 nM) resulted in 4.4 +/- 1.0 adducts/10(7) bp ( approximately 1300 adducts/cell) in MCF-7 breast cancer cells, representing the best sensitivity and precision reported to date for the covalent binding of Adriamycin to DNA. The exceedingly sensitive nature of AMS has enabled over three orders of magnitude increased sensitivity of Adriamycin-DNA adduct detection and revealed adduct formation within an hour of drug treatment. This method has been shown to be highly reproducible for the measurement of Adriamycin-DNA adducts in tumour cells in culture and can now be applied to the detection of these adducts in human tissues.

  19. Helium concentration in tungsten nano-tendril surface morphology using Elastic Recoil Detection

    International Nuclear Information System (INIS)

    Woller, K.B.; Whyte, D.G.; Wright, G.M.; Doerner, R.P.; De Temmerman, G.

    2013-01-01

    Helium (He) concentrations in tungsten nano-tendrils (W fuzz) have been measured for the first time using Elastic Recoil Detection (ERD). Fuzzy and non-fuzzy W surfaces were analyzed in order to illuminate the role of He in the transition in surface morphologies. Samples grown in the PISCES-A and PILOT-PSI experiments allowed a survey of surface temperature ranging from T s = 470–2595 K and of He fluence on the order of Φ He ∼ 10 24 –10 27 ions/m 2 . He concentrations measured in the bulk of W fuzz layers are roughly uniform with bulk He concentration 1–4 at.% while samples with just He in the near surface peaked at 1–2 at.%. This confirms that the nano-tendrils are filled with high pressure He bubbles since the solubility of He in W is ∼10 −5 at.%. This indicates that the ∼1000 K temperature fuzz-growth threshold is determined by the response of the W, not the near-surface He concentration

  20. Concentration of uranium in the drinking and surface water around the WIPP site

    International Nuclear Information System (INIS)

    Khaing, H.; Lemons, B.G.; Thakur, P.

    2016-01-01

    Activity concentration of uranium isotopes ( 238 U, 234 U and 235 U) were analyzed in drinking and surface water samples collected in the vicinity of the WIPP site using alpha spectroscopy. The purpose of this study was to investigate the changes in uranium concentrations (if any) in the vicinity of the WIPP site and whether the February 14, 2014 radiation release event at the WIPP had any detectable impact on the water bodies around the WIPP. (author)

  1. Charge Retention by Monodisperse Gold Clusters on Surfaces Prepared Using Soft Landing of Mass Selected Ions

    Science.gov (United States)

    Johnson, Grant; Priest, Thomas; Laskin, Julia

    2012-02-01

    Monodisperse gold clusters have been prepared on surfaces in different charge states through soft landing of mass-selected ions. Gold clusters were synthesized in methanol solution by reduction of a gold precursor with a weak reducing agent in the presence of a diphosphine capping ligand. Electrospray ionization was used to introduce the clusters into the gas-phase and mass-selection was employed to isolate a single ionic cluster species which was delivered to surfaces at well controlled kinetic energies. Using in-situ time of flight secondary ion mass spectrometry (SIMS) it is demonstrated that the cluster retains its 3+ charge state when soft landed onto the surface of a fluorinated self assembled monolayer on gold. In contrast, when deposited onto carboxylic acid terminated and conventional alkyl thiol surfaces on gold the clusters exhibit larger relative abundances of the 2+ and 1+ charge states, respectively. The kinetics of charge reduction on the surface have been investigated using in-situ Fourier Transform Ion Cyclotron Resonance SIMS. It is shown that an extremely slow interfacial charge reduction occurs on the fluorinated monolayer surface while an almost instantaneous neutralization takes place on the surface of the alkyl thiol monolayer. Our results demonstrate that the size and charge state of small gold clusters on surfaces, both of which exert a dramatic influence on their chemical and physical properties, may be tuned through soft landing of mass-selected ions onto selected substrates.

  2. Sensitivity of Greenland Ice Sheet surface mass balance to surface albedo parameterization: a study with a regional climate model

    NARCIS (Netherlands)

    van Angelen, J.H.|info:eu-repo/dai/nl/325922470; Lenaerts, J.T.M.|info:eu-repo/dai/nl/314850163; Lhermitte, S.; Fettweis, X.; Kuipers Munneke, P.|info:eu-repo/dai/nl/304831891; van den Broeke, M.R.|info:eu-repo/dai/nl/073765643; van Meijgaard, E.; Smeets, C.J.P.P.|info:eu-repo/dai/nl/191522236

    2012-01-01

    We present a sensitivity study of the surface mass balance (SMB) of the Greenland Ice Sheet, as modeled using a regional atmospheric climate model, to various parameter settings in the albedo scheme. The snow albedo scheme uses grain size as a prognostic variable and further depends on cloud cover,

  3. Concentration polarization and desalination in nanochannels: Effect of surface charge dynamics

    Science.gov (United States)

    Andersen, Mathias B.; Bruus, Henrik; Mani, Ali; Bazant, Martin Z.

    2011-11-01

    Mani, Zangle, and Santiago (Langmuir, 25, 3898-3916) have shown that at microchannel-nanochannel junctions the coupled effect of concentration polarization and surface conduction can lead to long range propagation of bulk ion-depletion shocks. Essential for this phenomena is the surface charge which for many materials depends on both the concentration and the pH of the local bulk electrolyte. Standard models predict that the surface charge decreases with decreasing concentration leading to the contradictory expectation that there is little or no surface charge in the depleted region and hence no mechanism to sustain long range propagation of desalination shocks. We show that this simple prediction fails to take into account axial transport terms. As such, we couple a surface charge model with the Poisson-Nernst-Planck equations for electric potential and ionic species combined with the Navier-Stokes and continuity equations for fluid velocity. Motivated by experimental work we consider steady-state solutions at the dead end of a nanochannel against a membrane, a scenario where especially space charge and electroosmotic flow are important. Our results suggest that the surface charge density remains finite and does not vanish, and even grows, as the depletion front propagates through the channel.

  4. Californium-252 plasma desorption mass analysis of proteins adsorbed on polymer and modified-polymer surfaces

    International Nuclear Information System (INIS)

    Hill, J.C.

    1987-01-01

    A new Cf-252 plasma desorption mass spectrometer has been built specifically for the analysis of large biomolecules. This mass spectrometer was used to investigate the interactions between proteins adsorbed onto polymer surfaces and how the chemical nature of the polymer surface influences the production of stable, gas-phase molecule ions. Chemical modification of the polymer surfaces was achieved by means of ultra-violet irradiation, resulting in the production of a more hydrophilic surface. Analysis of a series of model compounds adsorbed onto modified and non-modified polymer surfaces indicates that the wettability of the surface is an important influence in the production of stable molecular ions. This information was then utilized to aid in the analysis of lysozyme, myoglobin, and porcine trypsin

  5. Surface analytical investigation of diamond coatings and nucleation processes by secondary ion mass spectrometry

    International Nuclear Information System (INIS)

    Steiner, R.

    1993-10-01

    Imaging SIMS for the investigation of substrate surfaces: the influence of the substrate surface on diamond nucleation is a major topic in the investigation of the chemical vapour deposition (CVD) of diamond. It is well known that the nucleation density can be enhanced by scratching the substrate surface with abrasive powders. Diamond can nucleate at scratches or at residues of the polishing material. In the present work the surface of refractory metals (Mo, Nb, Ta, W) polished with silicon carbide and diamond powder is studied by imaging (2- or 3-D) secondary ion mass spectrometry (SIMS). In first experiments the distribution of SiC and/or diamond residues after polishing was determined. The reaction of diamond with the substrate during heating to deposition temperatures was investigated. Investigation of WC/Co hardmetal substrates: it is well known that Co contained in the binder phase of the hard metal inhibits a strong adhesion between the diamond film and the substrate, which is need for an application as cutting tool. Several attempts to improve the adhesion have been reported up to now. In this work a pre-treatment procedure leading to the formation of Co compounds (borides and silicides) which are stable under diamond deposition conditions were investigated. Furthermore, the application of intermediate sputter layers consisting of chromium and titanium were studied. Investigation of P-doped diamond coatings: in the quaternary phase diagram C-P-B-N exist some phases with diamond structure and superhard phases (e.g BP, c-BN). Also a hypothetical superhard phase of the composition C 3 N 4 is predicted. A scientific objective is the synthesis of such phases by chemical vapour deposition. An increase of the phosphorus concentration effects a distinct change in the morphology of the deposited coatings. A major advantage of SIMS is that the concentration profiles can be measured through the whole film, due to the sputter removal of the sample, and the interface

  6. Application of Full Factorial Experimental Design and Response Surface Methodology for Chromite Beneficiation by Knelson Concentrator

    Directory of Open Access Journals (Sweden)

    Gul Akar Sen

    2016-01-01

    Full Text Available The present work is undertaken to determine the effect of operational variables, namely: feed rate, centrifugal force and fluidization water flow rate on the efficiency of Knelson concentrator for chromite ore beneficiation. A full factorial design with three factors at three levels and response surface methodology (RSM were applied for this purpose. The quadratic models were developed to predict the concentrate Cr2O3 grade and recovery as the process responses. The results suggest that all the variables affect the grade and recovery of the Cr2O3 concentrate to some degree. However, the fluidization water rate was found as the most effective parameter.

  7. Polycyclic aromatic hydrocarbons in urban street dust and surface soil: comparisons of concentration, profile, and source.

    Science.gov (United States)

    Wang, De-Gao; Yang, Meng; Jia, Hong-Liang; Zhou, Lei; Li, Yi-Fan

    2009-02-01

    Street dust and surface soil samples in urban areas of Dalian, a coastal city in Liaoning Province, China, were collected and analyzed for 25 polycyclic aromatic hydrocarbons (PAHs). The concentrations, distribution, and sources of PAHs in dust and soil were determined. The concentrations of total PAHs in street dust ranged between 1890 and 17,070 ng/g (dry weight), with an average of 7460 ng/g, whereas the concentrations of total PAHs in surface soil varied greatly, from 650 to 28,900 ng/g, with a mean value of 6440 ng/g. Statistical paired t-test confirmed that total PAH concentrations have no significant difference between street dust and surface soil. Mean PAH concentrations in two type samples were much higher at industrial sites than at business/residential or garden sites. PAHs were dominated by higher molecular weight PAH (4- to 6-ring) homologues, which accounted for about 73% and 72% of total PAHs in street dust and surface soil, respectively. Principal component analysis was used in source apportionment of PAHs in dust and soil. Pyrogenic and petrogenic sources contributed 70% and 22.4% of total PAHs in street dusts, and fossil fuel (coal and petroleum) and biomass combustion accounted for 64.4% and 5.6% of total PAHs in pyrogenic sources, respectively. In surface soil, total PAHs were dominated by pyrogenic sources. The diagnostic ratios of benz[a]anthracene/chrysene confirmed that PAHs in street dust and surface soil of a Dalian urban zone might come mostly from the emission of local sources.

  8. Resin bead-thermal ionization mass spectrometry for determination of plutonium concentration in irradiated fuel dissolver solution

    International Nuclear Information System (INIS)

    Paul, Sumana; Shah, R.V.; Aggarwal, S.K.; Pandey, A.K.

    2015-01-01

    Determination of isotopic composition (IC) and concentration of plutonium (Pu) is necessary at various stages of nuclear fuel cycle which involves analysis of complex matrices like dissolver solution of irradiated fuel, nuclear waste stream etc. Mass spectrometry, e.g. thermal ionization mass spectrometry (TIMS) and inductively coupled plasma mass spectrometry (ICP-MS) are commonly used for determination of IC and concentration of plutonium. However, to circumvent matrix interferences, efficient separation as well as preconcentration of Pu is required prior to mass spectrometric analysis. Purification steps employing ion-exchange resins are widely used for the separation of Pu from dissolver solution or from mixture of other actinides e.g. U, Am. However, an alternative way is to selectively preconcentrate Pu on a resin bead, followed by direct loading of the bead on the filament of thermal ionization mass spectrometer

  9. Effects of contact time and concentration on bactericidal efficacy of 3 disinfectants on hard nonporous surfaces.

    Science.gov (United States)

    Hong, Yingying; Teska, Peter J; Oliver, Haley F

    2017-11-01

    This study investigated the influence of contact time and concentration on bactericidal efficacy of 3 types of disinfectants (accelerated hydrogen peroxide [AHP], quaternary ammonium compounds [Quats], and sodium hypochlorite) on stainless steel surfaces using Environmental Protection Agency procedure MB-25-02. We found that bactericidal efficacy was not reduced at contact times or concentrations immediate lower than label use values, but all 3 disinfectants were significantly less bactericidal at significantly lower than label use contact times and concentrations. Overall, the bactericidal efficacy of the sodium hypochlorite disinfectant was most tolerant to the decreases of contact times and concentrations, followed closely by AHP disinfectant, and Quat disinfectant was most affected by contact time and concentration. Copyright © 2017 Association for Professionals in Infection Control and Epidemiology, Inc. Published by Elsevier Inc. All rights reserved.

  10. SEMIC: an efficient surface energy and mass balance model applied to the Greenland ice sheet

    Directory of Open Access Journals (Sweden)

    M. Krapp

    2017-07-01

    Full Text Available We present SEMIC, a Surface Energy and Mass balance model of Intermediate Complexity for snow- and ice-covered surfaces such as the Greenland ice sheet. SEMIC is fast enough for glacial cycle applications, making it a suitable replacement for simpler methods such as the positive degree day (PDD method often used in ice sheet modelling. Our model explicitly calculates the main processes involved in the surface energy and mass balance, while maintaining a simple interface and requiring minimal data input to drive it. In this novel approach, we parameterise diurnal temperature variations in order to more realistically capture the daily thaw–freeze cycles that characterise the ice sheet mass balance. We show how to derive optimal model parameters for SEMIC specifically to reproduce surface characteristics and day-to-day variations similar to the regional climate model MAR (Modèle Atmosphérique Régional, version 2 and its incorporated multilayer snowpack model SISVAT (Soil Ice Snow Vegetation Atmosphere Transfer. A validation test shows that SEMIC simulates future changes in surface temperature and surface mass balance in good agreement with the more sophisticated multilayer snowpack model SISVAT included in MAR. With this paper, we present a physically based surface model to the ice sheet modelling community that is general enough to be used with in situ observations, climate model, or reanalysis data, and that is at the same time computationally fast enough for long-term integrations, such as glacial cycles or future climate change scenarios.

  11. Seasonal differences in aerosol water may reconcile AOT and surface mass measurements in the Southeast U.S.

    Science.gov (United States)

    Nguyen, T. K. V.; Ghate, V. P.; Carlton, A. M. G.

    2015-12-01

    Summertime aerosol optical thickness (AOT) in the Southeast U.S. is high and sharply enhanced (2-3 times) compared to wintertime AOT. This seasonal pattern is unique to the Southeast U.S. and is of particular interest because temperatures there have not warmed over the past 100 years, contrasting with trends in other U.S. regions. Some investigators hypothesize the Southeast temperature trend is due to secondary organic aerosols (SOA) formed from interactions of biogenic volatile organic compounds (BVOCs) and anthropogenic emissions that create a cooling haze. However, aerosol measurements made at the surface do not exhibit strong seasonal differences in mass or organic fraction to support this hypothesis. In this work, we attempt to reconcile the spatial and temporal distribution of AOT over the U.S. with surface mass measurements by examining trends in particle-phase liquid water, an aerosol constituent that effectively scatters radiation and is removed from aerosols in mass measurements at routine surface monitoring sites. We employ the thermodynamic model ISORROPIA (v2.1) to estimate surface and aloft aerosol water mass concentrations at locations of Interagency Monitoring of Protected Visual Environments (IMPROVE) sites using measured speciated ion mass concentrations and NCEP North American Regional Reanalysis (NARR) meteorological data. Results demonstrate strong seasonal differences in aerosol water in the eastern compared to the western part of the U.S., consistent with geographic patterns in AOT. The highest mean regional seasonal difference from 2000 to 2007 is 5.5 μg m-3 and occurs the Southeast, while the lowest is 0.44 μg m-3 and occurs in the dry Mountain West. Our findings suggest 1) similarity between spatial trends in aerosol water in the U.S. and previously published AOT data from the MODIS-TERRA instrument and 2) similar interannual trends in mean aerosol water and previously published interannual AOT trends from MISR, MODIS-TERRA, MODIS

  12. Surface concentration nonuniformities resulting from chronoamperometry of a reversible reaction at an ultramicrodisk electrode

    DEFF Research Database (Denmark)

    Britz, Dieter H.; Strutwolf, Jörg

    2016-01-01

    The chronoamperometric experiment at a disk electrode was simulated, assuming a reversible reaction. When the diffusion coefficients of the two substances involved are different, there appears a surface concentration non- uniformity in the radial direction, exhibiting a maximum effect in time...

  13. Nocturnal intermittency in surface CO2 concentrations in sub-Saharan Africa

    Science.gov (United States)

    Data obtained over four adjacent fields of differing management practices in Zimbabwe illustrate the role of atmospheric intermittency as a mechanism for transferring CO2 between the surface and the atmosphere above. At night, limited atmospheric mixing permits CO2 concentrations to increase to leve...

  14. Parametric uncertainties in global model simulations of black carbon column mass concentration

    Science.gov (United States)

    Pearce, Hana; Lee, Lindsay; Reddington, Carly; Carslaw, Ken; Mann, Graham

    2016-04-01

    Previous studies have deduced that the annual mean direct radiative forcing from black carbon (BC) aerosol may regionally be up to 5 W m-2 larger than expected due to underestimation of global atmospheric BC absorption in models. We have identified the magnitude and important sources of parametric uncertainty in simulations of BC column mass concentration from a global aerosol microphysics model (GLOMAP-Mode). A variance-based uncertainty analysis of 28 parameters has been performed, based on statistical emulators trained on model output from GLOMAP-Mode. This is the largest number of uncertain model parameters to be considered in a BC uncertainty analysis to date and covers primary aerosol emissions, microphysical processes and structural parameters related to the aerosol size distribution. We will present several recommendations for further research to improve the fidelity of simulated BC. In brief, we find that the standard deviation around the simulated mean annual BC column mass concentration varies globally between 2.5 x 10-9 g cm-2 in remote marine regions and 1.25 x 10-6 g cm-2 near emission sources due to parameter uncertainty Between 60 and 90% of the variance over source regions is due to uncertainty associated with primary BC emission fluxes, including biomass burning, fossil fuel and biofuel emissions. While the contributions to BC column uncertainty from microphysical processes, for example those related to dry and wet deposition, are increased over remote regions, we find that emissions still make an important contribution in these areas. It is likely, however, that the importance of structural model error, i.e. differences between models, is greater than parametric uncertainty. We have extended our analysis to emulate vertical BC profiles at several locations in the mid-Pacific Ocean and identify the parameters contributing to uncertainty in the vertical distribution of black carbon at these locations. We will present preliminary comparisons of

  15. Quantification of Hydrogen Concentrations in Surface and Interface Layers and Bulk Materials through Depth Profiling with Nuclear Reaction Analysis.

    Science.gov (United States)

    Wilde, Markus; Ohno, Satoshi; Ogura, Shohei; Fukutani, Katsuyuki; Matsuzaki, Hiroyuki

    2016-03-29

    Nuclear reaction analysis (NRA) via the resonant (1)H((15)N,αγ)(12)C reaction is a highly effective method of depth profiling that quantitatively and non-destructively reveals the hydrogen density distribution at surfaces, at interfaces, and in the volume of solid materials with high depth resolution. The technique applies a (15)N ion beam of 6.385 MeV provided by an electrostatic accelerator and specifically detects the (1)H isotope in depths up to about 2 μm from the target surface. Surface H coverages are measured with a sensitivity in the order of ~10(13) cm(-2) (~1% of a typical atomic monolayer density) and H volume concentrations with a detection limit of ~10(18) cm(-3) (~100 at. ppm). The near-surface depth resolution is 2-5 nm for surface-normal (15)N ion incidence onto the target and can be enhanced to values below 1 nm for very flat targets by adopting a surface-grazing incidence geometry. The method is versatile and readily applied to any high vacuum compatible homogeneous material with a smooth surface (no pores). Electrically conductive targets usually tolerate the ion beam irradiation with negligible degradation. Hydrogen quantitation and correct depth analysis require knowledge of the elementary composition (besides hydrogen) and mass density of the target material. Especially in combination with ultra-high vacuum methods for in-situ target preparation and characterization, (1)H((15)N,αγ)(12)C NRA is ideally suited for hydrogen analysis at atomically controlled surfaces and nanostructured interfaces. We exemplarily demonstrate here the application of (15)N NRA at the MALT Tandem accelerator facility of the University of Tokyo to (1) quantitatively measure the surface coverage and the bulk concentration of hydrogen in the near-surface region of a H2 exposed Pd(110) single crystal, and (2) to determine the depth location and layer density of hydrogen near the interfaces of thin SiO2 films on Si(100).

  16. Experimental Measurements of Concentration Fluctuations and Scales in a Dispersing Plume in the Atmospheric Surface Layer Obtained Using a Very Fast Response Concentration Detector

    Science.gov (United States)

    2016-06-14

    VOLUME 33 Experimental Measurements of Concentration Fluctuations and Scales in a Dispersing Plume in the Atmospheric Surface Layer Obtained Using a...Very Fast Response Concentration Detector EUGENE YEE Defence Research Establishment Suffield, Medicine Hat, Alberta , Canada R. CHAN AND P. R...various concentration timescales, length scales , and microscales (e.g., Taylor microscale, correlation scale , length scale based on the spectral

  17. Chemical analysis and surface morphology of enamel following ozone application with different concentrations and exposure times

    Directory of Open Access Journals (Sweden)

    Iman I. Elsayad

    2011-04-01

    Full Text Available This study aimed to determine the effect of different ozone concentrations applied with different exposure times on the chemical composition and the surface morphology of enamel. Twenty human mandibular molars were divided into four groups according to ozone concentration and exposure times. Group A received 90 μg of ozone/ml oxygen for 1 min, group B received 90 μg of ozone/ml oxygen for 2 min, group C received 120 μg of ozone/ml oxygen for 1 min and group D received 120 μg of ozone/ml oxygen for 2 min. The ozone source was from a medical ozone generator equipped with a device to adjust the concentration. Buccal surfaces of teeth were tested before and after ozone application so that each tooth served as a control for itself, using Environmental Scanning Electron Microscope (ESEM connected to an Electron Dispersive Analytical X-ray (EDAX. Changes in calcium and phosphorus percentage levels were recorded and the Ca/P ratio was calculated. The values were statistically analyzed using the one-way ANOVA test with a level of significance set at P ⩽ 0.05. No statistical significant difference was found between the control and the tested groups in minerals content or ratio as P > 0.05. ESEM images showed enamel surface roughness with 2 min ozone exposure times. High ozone concentration with prolonged exposure time does not change the chemical composition of enamel. Applying ozone for 2 min alters the surface morphology of enamel causing variable degrees of roughness. Using high ozone concentrations with prolonged exposure times for caries reversal or prevention and for bleaching may be contraindicated if this changes the surface morphology of enamel.

  18. The accretion history of dark matter haloes - III. A physical model for the concentration-mass relation

    Science.gov (United States)

    Correa, Camila A.; Wyithe, J. Stuart B.; Schaye, Joop; Duffy, Alan R.

    2015-09-01

    We present a semi-analytic, physically motivated model for dark matter halo concentration as a function of halo mass and redshift. The semi-analytic model combines an analytic model for the halo mass accretion history (MAH), based on extended Press-Schechter (EPS) theory, with an empirical relation between concentration and formation time obtained through fits to the results of numerical simulations. Because the semi-analytic model is based on EPS theory, it can be applied to wide ranges in mass, redshift and cosmology. The resulting concentration-mass (c-M) relations are found to agree with the simulations, and because the model applies only to relaxed haloes, they do not exhibit the upturn at high masses or high redshifts found by some recent works. We predict a change of slope in the z ˜ 0 c-M relation at a mass-scale of 1011 M⊙. We find that this is due to the change in the functional form of the halo MAH, which goes from being dominated by an exponential (for high-mass haloes) to a power law (for low-mass haloes). During the latter phase, the core radius remains approximately constant, and the concentration grows due to the drop of the background density. We also analyse how the c-M relation predicted by this work affects the power produced by dark matter annihilation, finding that at z = 0 the power is two orders of magnitude lower than that obtained from extrapolating best-fitting c-M relations. We provide fits to the c-M relations as well as numerical routines to compute concentrations and MAHs.†

  19. Correlation between sub-micron surface roughness of iron oxide encrustations and trace element concentrations

    International Nuclear Information System (INIS)

    Fischer, Cornelius; Karius, Volker; Luettge, Andreas

    2009-01-01

    Iron oxide encrustations are formed on black slate surfaces during oxidative weathering of iron sulfide and phosphate bearing, organic matter-rich slates. Synchronously, trace elements are released during ongoing weathering. Laser ablation ICP-MS analyses of a weathered and encrusted slate showed that major portions of the V, Cu, As, Mo, Pb, Th, and U reside in the encrustation. Recently a potential relationship between several micrometer to 500 nm surface topography roughness of such encrustations and its uranium concentration was shown. Based on laser scanning microscopy measurements, the present study shows that this interrelation must be expanded to small submicron-sized half-pores with diameters between 100 nm and 500 nm. We demonstrate that the relationship is not limited to topography variations of a single encrustation in the hand-specimen scale. Surface topography and geochemical analyses of iron oxide encrustations from several locations but from the same geochemical environment and with similar weathering history showed that the concentrations of U, P, Cu, and Zn correlate inversely with the surface roughness parameter F. This parameter represents the total surface area and is - in this case - a proxy for the root-mean square surface roughness Rq. This study substantiates the environmental importance that micrometer- to submicrometer topography variations of fluid-rock interfaces govern the trapping of trace elements.

  20. Correlation between sub-micron surface roughness of iron oxide encrustations and trace element concentrations

    Energy Technology Data Exchange (ETDEWEB)

    Fischer, Cornelius, E-mail: cornelius@rice.edu [Department of Earth Science, MS-126, Rice University, 6100 Main Street, Houston, TX 77005 (United States); Geowissenschaftliches Zentrum der Universitaet Goettingen, Abt. Sedimentologie and Umweltgeologie, Goldschmidtstr. 3, D-37077 Goettingen (Germany); Karius, Volker [Geowissenschaftliches Zentrum der Universitaet Goettingen, Abt. Sedimentologie and Umweltgeologie, Goldschmidtstr. 3, D-37077 Goettingen (Germany); Luettge, Andreas [Department of Earth Science, MS-126, Rice University, 6100 Main Street, Houston, TX 77005 (United States); Department of Chemistry, Rice University, 6100 Main Street, Houston, TX 77005 (United States)

    2009-08-01

    Iron oxide encrustations are formed on black slate surfaces during oxidative weathering of iron sulfide and phosphate bearing, organic matter-rich slates. Synchronously, trace elements are released during ongoing weathering. Laser ablation ICP-MS analyses of a weathered and encrusted slate showed that major portions of the V, Cu, As, Mo, Pb, Th, and U reside in the encrustation. Recently a potential relationship between several micrometer to 500 nm surface topography roughness of such encrustations and its uranium concentration was shown. Based on laser scanning microscopy measurements, the present study shows that this interrelation must be expanded to small submicron-sized half-pores with diameters between 100 nm and 500 nm. We demonstrate that the relationship is not limited to topography variations of a single encrustation in the hand-specimen scale. Surface topography and geochemical analyses of iron oxide encrustations from several locations but from the same geochemical environment and with similar weathering history showed that the concentrations of U, P, Cu, and Zn correlate inversely with the surface roughness parameter F. This parameter represents the total surface area and is - in this case - a proxy for the root-mean square surface roughness Rq. This study substantiates the environmental importance that micrometer- to submicrometer topography variations of fluid-rock interfaces govern the trapping of trace elements.

  1. 40 CFR Table F-4 to Subpart F of... - Estimated Mass Concentration Measurement of PM2.5 for Idealized Coarse Aerosol Size Distribution

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 5 2010-07-01 2010-07-01 false Estimated Mass Concentration... Concentration Measurement of PM2.5 for Idealized Coarse Aerosol Size Distribution Particle Aerodynamic Diameter (µm) Test Sampler Fractional Sampling Effectiveness Interval Mass Concentration (µg/m3) Estimated Mass...

  2. 40 CFR Table F-6 to Subpart F of... - Estimated Mass Concentration Measurement of PM2.5 for Idealized Fine Aerosol Size Distribution

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 5 2010-07-01 2010-07-01 false Estimated Mass Concentration... Concentration Measurement of PM2.5 for Idealized Fine Aerosol Size Distribution Particle Aerodynamic Diameter (µm) Test Sampler Fractional Sampling Effectiveness Interval Mass Concentration (µg/m3) Estimated Mass...

  3. Concentrations and geographic distribution of selected organic pollutants in Scottish surface soils

    International Nuclear Information System (INIS)

    Rhind, S.M.; Kyle, C.E.; Kerr, C.; Osprey, M.; Zhang, Z.L.; Duff, E.I.; Lilly, A.; Nolan, A.; Hudson, G.; Towers, W.; Bell, J.; Coull, M.; McKenzie, C.

    2013-01-01

    Concentrations of selected persistent organic pollutants (POPs) representing three chemical classes (polycyclic aromatic hydrocarbons (PAH), polybrominated diphenyl ethers (PBDE) and polychlorinated biphenyls (PCB) and the organic pollutant diethylhexyl phthalate (DEHP), were determined in surface soil samples (0–5 cm) collected at 20 km grid intersects throughout Scotland over a three-year period. Detectable amounts of all chemical classes and most individual congeners were present in all samples. There were no consistent effects of soil or vegetation type, soil carbon content, pH, altitude or distance from centres of population on concentrations which exhibited extreme variation, even in adjacent samples. It is concluded that soil POPs and DEHP concentrations and associated rates of animal and human exposure were highly variable, influenced by multiple, interacting factors, and not clearly related to local sources but possibly related to wet atmospheric deposition and the organic carbon content of the soil. -- Highlights: •Concentrations of selected organic pollutants in Scottish soils were determined. •Concentrations were highly variable. •There were few effects of soil or vegetation type, soil carbon, pH or altitude. •Distance from cities was not an important determinant of concentrations. •Atmospheric deposition and soil organic carbon content may affect concentrations. -- Soil concentrations of anthropogenic persistent organic pollutants are not clearly related to soil type or pH, vegetation, altitude, or distance from pollutant sources

  4. Impact of regional ventilation changes on surface particulate matter concentrations in South Korea

    Science.gov (United States)

    Kim, H. C.; Stein, A. F.; Chai, T.; Ngan, F.; Kim, B. U.; Jin, C. S.; Hong, S. Y.; Park, R.; Son, S. W.; Bae, C.; Bae, M.; Song, C. K.; Kim, S.

    2017-12-01

    The recent increase in surface particulate matter (PM) concentrations in South Korea is intriguing due to its disagreement with current intensive emission reduction efforts. The long-term trend of surface PM concentrations in South Korea declined in the 2000s, but since 2012 its concentrations have tended to increase, resulting in frequent severe haze events in the region. This study demonstrates that the interannual variation of surface PM concentrations in South Korea is not only affected by changes in local or regional emission sources, but also closely linked with the interannual variations in regional ventilation. Using EPA Community Multiscale Air Quality modeling system, a 12-year (2004-2015) regional air quality simulation was conducted to assess the impact of the meteorological conditions under constant anthropogenic emissions. In addition, NOAA HYSPLIT dispersion model was utilized to estimate the strength of regional ventilation that dissipates local pollutions. Simulated PM concentrations show a strong negative correlation (i.e. R=-0.86) with regional wind speed, implying that reduced regional ventilation is likely associated with more stagnant conditions that cause severe pollutant episodes in South Korea. We conclude that the current PM concentration trend in South Korea is a combination of long-term decline by emission control efforts and short-term fluctuations in regional wind speed interannual variability. When the meteorology-driven variations are removed, PM concentrations in South Korea have declined continuously even after 2012, with -1.45±0.12, -1.41±0.16, and -1.09±0.16 mg/m3 per year in Seoul, the Seoul Metropolitan Area, and South Korea, respectively.

  5. Effect of temperature and concentration on the surface tension of chia seed mucilage

    Science.gov (United States)

    Fu, Yuting; Arye, Gilboa

    2017-04-01

    The production of mucilage by the seed coat during hydration is a common adaptation of many different plant species. The mucilage may play many ecological roles in adaptation and seed germination in diverse environments, especially in extreme desert conditions. The major compound of the seed mucilage is polysaccharides (e.g. pectins and hemicelluloses), which makes it highly hydrophilic. Consequently, it can hydrate quickly in the presence of water; forming a gel like coating surrounding the seed. However, the seed mucilage also reported to contain small amounts of protein and lipid which may exhibit surface activity at the water-air interface. As a result, decay in the surface tension of water can be occur and consequently a reduction in soil capillary pressure. This in turn may affect the water retention and transport during seed germination. The physical properties of the seeds mucilage have been studied mainly in conjunction with its rheological properties. To the best of our knowledge, its surface activity at the water-air interface has been reported mainly in the realms of food engineering, using a robust method of extraction. The main objective of this study was to quantify the effect of temperature and concentration on the surface tension of seed mucilage. The mucilage in this study was extracted from chia (Salvia hispanica L.) seeds, using distilled water (1:20 w/w) by shaking for 12 h at 4°C. The extracts were freeze dried after centrifuge (5000rpm for 20min). Fresh samples of different concentrations, ranging from 0.5 to 6 mg/ml, were prepared before each surface tension measurements. The equilibrium surface tension was measured by the Wilhelmy plate method using a tensiometer (DCAT 11, Data Physics) with temperature control unit. For a given mucilage concentration, surface tension measurements carried out at 5, 15, 25, 35, 45 °C. The quantitative and thermodynamic analysis of the results will be presented and discussed.

  6. Differences in surface roughness of nanohybrid composites immersed in varying concentrations of citric acid

    Directory of Open Access Journals (Sweden)

    Gabriela Kevina Alifen

    2017-06-01

    Full Text Available Background: The surface roughness of restoration is important in predicting the length of time it might remain in the mouth. Conditions within the oral cavity can affect the surface roughness of a restoration. Nanohybrid composite is widely used in dentistry because it can be applied to restore anterior and posterior teeth. Athletes routinely consume isotonic drinks which are acidic and even more erosive than the carbonated variety because they contain a range of acids; the highest content of which being citric acid. Purpose: The aim of the study was to analyze the surface roughness of nanohybrid composite after having been subjected to immersion in varying concentrations of citric acid. Methods: Two isotonic drinks (Pocari Sweat and Mizone were analyzed using high performance liquid chromatography (HPLC to quantify the respective concentrations of citric acid which they contained. A total of 27 samples of cylindrical nanohybrid composite were prepared before being divided into three groups. In Group 1, samples were immersed in citric acid solution derived from Pocari Sweat. Those of Group 2 were immersed in citric acid solution derived from Mizone; while Group 3, samples were immersed in distilled water as a control. All samples were immersed for 7 days, before their surface roughness was tested by means of a surface roughness tester (Mitutoyo SJ-201. Data was analyzed using a one-way ANOVA test. Results: The results showed that there was no significant difference in surface roughness between Groups 1, 2 and 3 (p=0.985. Conclusion: No difference in surface roughness of nanohybrid composites results from prolonged immersion in varying concentrations of citric acid.

  7. Determination of long-lived radionuclide (10Be, 41Ca, 129I) concentrations in nuclear waste by accelerator mass spectrometry

    International Nuclear Information System (INIS)

    Nottoli, Emmanuelle; Bienvenu, Philippe; Labet, Alexandre; Bertaux, Maite; Bourles, Didier; Arnold, Maurice

    2013-01-01

    Bethe-Block law (1). (1) dE/dx=(k * Z 2 )/v 2 . The use of a particle accelerator in conjunction with a selective ion source, mass and energy filters and a high-performance detector thus allow unambiguously identifying and measuring analyte concentration against much more abundant interfering isobars. The development of AMS and of related applications have recently been extensively reviewed. Up to now, the potentialities of the accelerator mass spectrometry technique were explored for the measurement of cosmogenic radionuclides produced in the Earth's environment either in the atmosphere or in the Earth's crust (in situ-production). Many applications aiming to date and/or quantify Earth surface processes have been developed in the fields of geology, geomorphology and planetary sciences as well as archaeology paleo-anthropology and biomedicine. The present study extends the scope of AMS to nuclear industry. Because AMS facilities are not widely accessible and difficult to handle, LLRN concentrations in nuclear waste are usually determined using Inductively Coupled Plasma Mass Spectrometry (ICP-MS) and radiometric techniques. However for the measurement of very low LLRN concentrations, AMS becomes the most effective measurement method with detection limits of 10 5 -10 6 atoms per sample. In this study, AMS measurements were performed using the French AMS national facility ASTER located at the Centre Europeen de Recherche et d'Enseignement des Geosciences de l'Environnement (CEREGE). The challenge was to define a chemical treatment procedure allowing the measurement of the three nuclides, 10 Be, 41 Ca and 129 I, by AMS. Each method selection was based on three main requirements: 1) a quantitative recovery in solution of Be, Ca, I and key radionuclides after resin mineralization, 2) a selective extraction from the sample matrix and the separation from β-γ emitters ( 3 H, 14 C, 55 Fe, 59 Ni, 60 Co, 63 Ni, 90 Sr, 125 Sb, 134 Cs, 137 Cs) and isobars, 3

  8. Monitoring the on-surface synthesis of graphene nanoribbons by mass spectrometry

    KAUST Repository

    Zhang, Wen

    2017-06-14

    We present a mass spectrometric approach to monitor and characterize the intermediates of graphene nanoribbon (GNR) formation by chemical vapor deposition (CVD) on top of Au(111) surfaces. Information regarding the repeating units, lengths, and termini can be obtained directly from the surface sample by a modified matrix assisted laser desorption/ionization (MALDI) method. The mass spectrometric results reveal ample oxidative side reactions under CVD conditions which can, however, be diminished drastically by introduction of protective H2 gas at ambient pressure. Simultaneously, addition of hydrogen extends the lengths of the oligophenylenes and thus the final GNRs. Moreover, the prematurely formed cyclodehydrogenation products during the oligomer growth can be assigned by the mass spectrometric method. The obtained mechanistic insights provide valuable information for optimizing and upscaling the bottom-up fabrication of GNRs. Given the important role of GNRs as semiconductors, the mass spectrometric characterization provides a readily available tool to improve and characterize their structural perfection.

  9. Muscle conduction velocity, surface electromyography variables, and echo intensity during concentric and eccentric fatigue.

    Science.gov (United States)

    Gonzalez-Izal, Miriam; Lusa Cadore, Eduardo; Izquierdo, Mikel

    2014-03-01

    Concentric (CON) and eccentric (ECC) contractions may involve different mechanisms related to changes in sarcolemma status and the consequent alteration of action potential transmission along muscle fibers. Muscle conduction velocity (CV), surface electromyography signal (sEMG), muscle quality, and blood lactate concentrations were analyzed during CON and ECC actions. Compared with ECC, the CON protocol resulted in greater muscle force losses, blood lactate concentrations, and changes in sEMG parameters. Similar reductions in CV were detected in both protocols. Higher echo intensity values were observed 2 days after ECC due to greater muscle damage. The effects of the muscle damage produced by ECC exercise on the transmission of action potentials along muscle fibers (measured as the CV) may be comparable with the effects of hydrogen accumulation produced by CON exercise (related to greater lactate concentrations), which causes greater force loss and change in other sEMG variables during CON than during ECC actions.

  10. The influence of surface roughness and solution concentration on pool boiling process in Diethanolamine aqueous solution

    Science.gov (United States)

    Khoshechin, Mohsen; Salimi, Farhad; Jahangiri, Alireza

    2018-04-01

    In this research, the effect of surface roughness and concentration of solution on bubble departing frequency and nucleation site density for pool boiling of water/diethanolamine (DEA) binary solution were investigated experimentally. In this investigation, boiling heat transfer coefficient, bubble departing frequency and nucleation site density have been experimentally investigated in various concentrations and heat fluxes. Microstructured surfaces with a wide range of well-defined surface roughness were fabricated, and a heat flux between 1.5-86 kW/m2 was achieved under atmospheric conditions. The Results indicated that surface roughness and concentration of solution increase the bubble departing frequency and nucleation site density with increasing heat flux. The boiling heat transfer coefficient in mixtures of water/DEA increases with increasing concentration of DEA in water. The experimental results were compared with predictions of several used correlations in the literatures. Results showed that the boiling heat transfer coefficients of this case study are much higher than the predicted values by major existing correlations and models. The excellent agreement for bubble departing frequency found between the models of Jackob and Fritz (1966) and experimental data and also the nucleation site density were in close agreement with the model of Paul (1983) data. f bubble departure frequency, 1/s or Hz N Number of nucleation sites per area per time R c Minimum cavity size, m D c critical diameter, m g gravitational acceleration, m/s2 ρ density, kg/m3 T temperature, °c ΔT temperature difference, °c d d vapor bubble diameter, m h fg enthalpy of vaporization, J/kg R Roughness, μm Ja Jakob number cp specific heat, J/kg °c Pr Prandtl number Ar Archimedes number h Heat transfer coefficient, J/(m2 °c) tg time it takes to grow a bubble, s q/A heat flux (kW/m2) tw time required to heat the layer, s gc Correction coefficient of incompatible units R a Surface

  11. Paint Spray Mass Spectrometry for the Detection of Additives from Polymers on Conducting Surfaces

    OpenAIRE

    Martin R. L. Paine; Philip J. Barker; Stephen J. Blanksby

    2012-01-01

    Paint Spray is developed as a direct sampling ionisation method for mass spectrometric analysis of additives in polymer-based surface coatings. The technique simply involves applying an external high voltage (5 kV) to the wetted sample placed in front of the mass spectrometer inlet and represents a much simpler ionisation technique compared to those currently available.The capabilities of Paint Spray are demonstrated herein with the detection of four commercially available hindered amine ligh...

  12. Estimation of atmospheric columnar organic matter (OM) mass concentration from remote sensing measurements of aerosol spectral refractive indices

    Science.gov (United States)

    Zhang, Ying; Li, Zhengqiang; Sun, Yele; Lv, Yang; Xie, Yisong

    2018-04-01

    Aerosols have adverse effects on human health and air quality, changing Earth's energy balance and lead to climate change. The components of aerosol are important because of the different spectral characteristics. Based on the low hygroscopic and high scattering properties of organic matter (OM) in fine modal atmospheric aerosols, we develop an inversion algorithm using remote sensing to obtain aerosol components including black carbon (BC), organic matter (OM), ammonium nitrate-like (AN), dust-like (DU) components and aerosol water content (AW). In the algorithm, the microphysical characteristics (i.e. volume distribution and complex refractive index) of particulates are preliminarily separated to fine and coarse modes, and then aerosol components are retrieved using bimodal parameters. We execute the algorithm using remote sensing measurements of sun-sky radiometer at AERONET site (Beijing RADI) in a period from October of 2014 to January of 2015. The results show a reasonable distribution of aerosol components and a good fit for spectral feature calculations. The mean OM mass concentration in atmospheric column is account for 14.93% of the total and 56.34% of dry and fine-mode aerosol, being a fairly good correlation (R = 0.56) with the in situ observations near the surface layer.

  13. The determination of carbon dioxide concentration using atmospheric pressure ionization mass spectrometry/isotopic dilution and errors in concentration measurements caused by dryers.

    Science.gov (United States)

    DeLacy, Brendan G; Bandy, Alan R

    2008-01-01

    An atmospheric pressure ionization mass spectrometry/isotopically labeled standard (APIMS/ILS) method has been developed for the determination of carbon dioxide (CO(2)) concentration. Descriptions of the instrumental components, the ionization chemistry, and the statistics associated with the analytical method are provided. This method represents an alternative to the nondispersive infrared (NDIR) technique, which is currently used in the atmospheric community to determine atmospheric CO(2) concentrations. The APIMS/ILS and NDIR methods exhibit a decreased sensitivity for CO(2) in the presence of water vapor. Therefore, dryers such as a nafion dryer are used to remove water before detection. The APIMS/ILS method measures mixing ratios and demonstrates linearity and range in the presence or absence of a dryer. The NDIR technique, on the other hand, measures molar concentrations. The second half of this paper describes errors in molar concentration measurements that are caused by drying. An equation describing the errors was derived from the ideal gas law, the conservation of mass, and Dalton's Law. The purpose of this derivation was to quantify errors in the NDIR technique that are caused by drying. Laboratory experiments were conducted to verify the errors created solely by the dryer in CO(2) concentration measurements post-dryer. The laboratory experiments verified the theoretically predicted errors in the derived equations. There are numerous references in the literature that describe the use of a dryer in conjunction with the NDIR technique. However, these references do not address the errors that are caused by drying.

  14. Volumes, Masses, and Surface Areas for Shippingport LWBR Spent Nuclear Fuel in a DOE SNF Canister

    International Nuclear Information System (INIS)

    J.W. Davis

    1999-01-01

    The purpose of this calculation is to estimate volumes, masses, and surface areas associated with (a) an empty Department of Energy (DOE) 18-inch diameter, 15-ft long spent nuclear fuel (SNF) canister, (b) an empty DOE 24-inch diameter, 15-ft long SNF canister, (c) Shippingport Light Water Breeder Reactor (LWBR) SNF, and (d) the internal basket structure for the 18-in. canister that has been designed specifically to accommodate Seed fuel from the Shippingport LWBR. Estimates of volumes, masses, and surface areas are needed as input to structural, thermal, geochemical, nuclear criticality, and radiation shielding calculations to ensure the viability of the proposed disposal configuration

  15. Modification of sea surface temperature by chlorophyll concentration in the Atlantic upwelling systems

    Science.gov (United States)

    Hernandez, O.; Jouanno, J.; Echevin, V.; Aumont, O.

    2017-07-01

    The influence of the chlorophyll on the upper Tropical Atlantic Ocean is investigated with long-term (1979-2012) regional oceanic simulations with 1/4° horizontal resolution based on the NEMO3.6 model. The model solar radiation penetration scheme depends on the chlorophyll concentration. Simulations with time and spatially varying concentrations obtained from satellite ocean color observations are compared with a simulation forced with constant chlorophyll concentration of 0.05 mg m-3, representative of chlorophyll depleted waters. Results indicate that regions of the Tropical Atlantic with chlorophyll concentrations larger than in the reference simulation (i.e., [chl] > 0.05 mg m-3) get warmer at the surface, with the exception of the main upwelling regions where high chlorophyll concentrations are associated with a significant cooling of the sea surface (˜1°C in the Benguela upwelling). The analysis of the model heat balance shows that the biological differential heating causes negative temperature anomalies in subsurface source waters prior to their upwelling at the coast. The shallow mixed-layer in the eastern equatorial and tropical Atlantic favors the persistence of these subsurface anomalies and may explain why the Benguela is particularly sensitive to the biological differential heating. In spite of the presence of high chlorophyll concentrations in the upwelling regions, both the larger amount of shortwave radiation captured in the surface layers and the modifications of the horizontal and vertical advection at the coast are found to play a secondary role in the SST change in the upwelling region.

  16. The effect of some soil characteristics on soil radon concentration and radon exhalation from soil surface

    International Nuclear Information System (INIS)

    Sun, Kainan; Cheng, Jianping; Guo, Qiuju

    2004-01-01

    To find out the impacts of soil characters on radon concentration in soil and radon exhalation from soil, field measurements on soil radon concentrations (60 cm under the soil surface) and radon exhalation rate from soil surface were carried out in totally 31 points with different types of soil in three cities in both South and North China. Soil radium contents, water contents, soil porosity and grain size were concretely analyzed in our laboratory. The linear simulation was used to analyze the above data. The results showed that radon exhalation rate from soil and radon concentrations in soil have direct proportion to soil radium contents. Rather high radium content and radon exhalation rate were measured in Guiyang area, 67±28Bq/Kg and 40±59 mBq/m 2 ·s, however no high soil radon concentration was found due to the difficulties in the measurements on clay soils with high saturation. Compared with soil radium contents, radon exhalation rate from soil and soil radon concentrations are more easily impacted by soil characters and change in a rather large range. (author)

  17. Genotoxic effects of daily personal exposure to particle mass and number concentrations on buccal cells

    Science.gov (United States)

    de Almeida, Daniela S.; da Costa, Silvano César; Ribeiro, Marcos; Moreira, Camila A. B.; Beal, Alexandra; Squizzato, Rafaela; Rudke, Anderson Paulo; Rafee, Sameh Adib Abou; Martins, Jorge A.; Palioto, Graciana Freitas; Kumar, Prashant; Martins, Leila D.

    2018-03-01

    The aim of this study is to assess personal exposure to Particle Number Concentrations (PNC) in four size ranges between 0.3 and 10 μm, and particulate matter (PM1; PM2.5; PM4; PM10) in order to evaluate possible genotoxic effects through a comet assay in buccal cells. A convenience cohort of 30 individuals from a Brazilian medium-sized city was selected. These individuals aged between 20 and 61 and worked in typical job categories (i.e., administrative, commerce, education, general services and transport). They were recruited to perform personal exposure measurements during their typical daily routine activities, totaling 240 h of sampling. The 8-h average mass concentrations in air for volunteers ranged from 2.4 to 31.8 μg m-3 for PM1, 4.2-45.1 μg m-3 for PM2.5, 7.9-66.1 μg m-3 for PM4 and from 23.1 to 131.7 μg m-3 for PM10. The highest PNC variation was found for 0.3-0.5 range, between 14 and 181 particles cm-3, 1 to 14 particles cm-3 for the 0.5-1.0 range, 0.2 to 2 particles cm-3 for the 1.0-2.5 range, and 0.06 to 0.7 particles cm-3 for the 2.5-10 range. Volunteers in the 'education' category experienced the lowest inhaled dose of PM2.5, as opposed to those involved in 'commercial' activities with the highest doses for PM10 (1.63 μg kg-1 h-1) and PM2.5 (0.61 μg kg-1 h-1). The predominant cause for these high doses was associated with the proximity of the workplace to the street and vehicle traffic. The comet assay performed in buccal cells indicated that the volunteers in 'commerce' category experienced the highest damage to their DeoxyriboNucleic Acid (DNA) compared with the control category (i.e. 'education'). These results indicate the variability in personal exposure of the volunteers in different groups, and the potential damage to DNA was much higher for those spending time in close proximity to the vehicle sources (e.g. commercial services) leading to exposure to a higher fraction of fine particles. This study builds understanding on the exposure

  18. Body mass index predicts plasma aldosterone concentrations in overweight-obese primary hypertensive patients.

    Science.gov (United States)

    Rossi, Gian Paolo; Belfiore, Anna; Bernini, Giampaolo; Fabris, Bruno; Caridi, Graziella; Ferri, Claudio; Giacchetti, Gilberta; Letizia, Claudio; Maccario, Mauro; Mannelli, Massimo; Palumbo, Gaetana; Patalano, Anna; Rizzoni, Damiano; Rossi, Ermanno; Pessina, Achille C; Mantero, Franco

    2008-07-01

    Body mass index (BMI) shows a direct correlation with plasma aldosterone concentration (PAC) and urinary aldosterone excretion in normotensive individuals; whether the same applies to hypertensive patients is unknown. Our objective was to determine if BMI predicts PAC and the PAC/plasma renin activity ratio [aldosterone renin ratio (ARR)] in hypertensive patients, and if this affects the identification of primary aldosteronism (PA). This was a prospective evaluation of consecutive hypertensive patients referred nationwide to specialized hypertension centers. Sitting PAC, plasma renin activity, and the ARR, baseline and after 50 mg captopril orally with concomitant assessment of parameters, including BMI and daily sodium intake, were calculated. Complete biochemical data and a definite diagnosis were obtained in 1125 consecutive patients. Of them 999 had primary (essential) hypertension (PH) and 126 (11.2%) PA caused by an aldosterone-producing adenoma in 54 (4.8%). BMI independently predicted PAC (beta = 0.153; P < 0.0001) in PH, particularly in the overweight-obese, but not in the PA group. Covariance analysis and formal comparison of the raw, and the BMI-, sex-, and sodium intake-adjusted ARR with receiver operator characteristic curves, showed no significant improvement for the discrimination of aldosterone-producing adenoma from PH patients with covariate-adjusted ARR. BMI correlated with PAC independent of age, sex, and sodium intake in PH, but not in PA patients. This association of BMI is particularly evident in overweight-obese PH patients, and suggests a pathophysiological link between visceral adiposity and aldosterone secretion. However, it does not impact on the diagnostic accuracy of the ARR for discriminating PA from PH patients.

  19. Charge retention by gold clusters on surfaces prepared using soft landing of mass selected ions.

    Science.gov (United States)

    Johnson, Grant E; Priest, Thomas; Laskin, Julia

    2012-01-24

    Monodisperse gold clusters have been prepared on surfaces in different charge states through soft landing of mass-selected ions. Ligand-stabilized gold clusters were prepared in methanol solution by reduction of chloro(triphenylphosphine)gold(I) with borane tert-butylamine complex in the presence of 1,3-bis(diphenylphosphino)propane. Electrospray ionization was used to introduce the clusters into the gas phase, and mass selection was employed to isolate a single ionic cluster species (Au(11)L(5)(3+), L = 1,3-bis(diphenylphosphino)propane), which was delivered to surfaces at well-controlled kinetic energies. Using in situ time-of-flight secondary ion mass spectrometry (TOF-SIMS), it is demonstrated that the Au(11)L(5)(3+) cluster retains its 3+ charge state when soft landed onto the surface of a 1H,1H,2H,2H-perfluorodecanethiol self-assembled monolayer (FSAM) on gold. In contrast, when deposited onto 16-mercaptohexadecanoic acid (COOH-SAM) and 1-dodecanethiol (HSAM) surfaces on gold, the clusters exhibit larger relative abundances of the 2+ and 1+ charge states, respectively. The kinetics of charge reduction on the FSAM and HSAM surfaces are investigated using in situ Fourier transform ion cyclotron resonance (FT-ICR) SIMS. It is shown that an extremely slow interfacial charge reduction occurs on the FSAM surface while an almost instantaneous neutralization takes place on the surface of the HSAM. Our results demonstrate that the size and charge state of small gold clusters on surfaces, both of which exert a dramatic influence on their chemical and physical properties, may be tuned through soft landing of mass-selected ions onto carefully selected substrates. © 2011 American Chemical Society

  20. Surface topography of cylindrical gear wheels after smoothing in abrasive mass, honing and shot peening

    International Nuclear Information System (INIS)

    Michalski, J; Pawlus, P; Zelasko, W

    2011-01-01

    The present paper presents the analysis of surface topography of gear teeth as the result of final machining processes. Teeth of multiple cylindrical gears shaped by grinding were smoothed in abrasive mass, honed or shot peened. The measurement of gears were made using coordinate measuring machine and 3D surface topography stylus instrument. The following deviations were studied; pitch deviation, total pitches deviations, variation of teeth thickness and deviation of gear radial run-out. Changes in teeth surface topography during machining process were determined. 3D surface topography parameters, surface directionality as well as areal autocorrelation and power spectral density functions were taken into consideration. As the results of the analysis, the best surface topography with regard to gear operational properties was recommended.

  1. Probabilistic risk assessment of insecticide concentrations in agricultural surface waters: a critical appraisal.

    Science.gov (United States)

    Stehle, Sebastian; Knäbel, Anja; Schulz, Ralf

    2013-08-01

    Due to the specific modes of action and application patterns of agricultural insecticides, the insecticide exposure of agricultural surface waters is characterized by infrequent and short-term insecticide concentration peaks of high ecotoxicological relevance with implications for both monitoring and risk assessment. Here, we apply several fixed-interval strategies and an event-based sampling strategy to two generalized and two realistic insecticide exposure patterns for typical agricultural streams derived from FOCUS exposure modeling using Monte Carlo simulations. Sampling based on regular intervals was found to be inadequate for the detection of transient insecticide concentrations, whereas event-triggered sampling successfully detected all exposure incidences at substantially lower analytical costs. Our study proves that probabilistic risk assessment (PRA) concepts in their present forms are not appropriate for a thorough evaluation of insecticide exposure. Despite claims that the PRA approach uses all available data to assess exposure and enhances risk assessment realism, we demonstrate that this concept is severely biased by the amount of insecticide concentrations below detection limits and therefore by the sampling designs. Moreover, actual insecticide exposure is of almost no relevance for PRA threshold level exceedance frequencies and consequential risk assessment outcomes. Therefore, we propose a concept that features a field-relevant ecological risk analysis of agricultural insecticide surface water exposure. Our study quantifies for the first time the environmental and economic consequences of inappropriate monitoring and risk assessment concepts used for the evaluation of short-term peak surface water pollutants such as insecticides.

  2. Impact of Donor Age, Gender and Handling Time on the DNA Concentration Left on Different Surfaces

    Directory of Open Access Journals (Sweden)

    Branka Gršković

    2014-09-01

    Full Text Available Background: We analyzed the correlation between several factors (donor age and gender, and handling time and trace DNA concentration that participants left on different surfaces (paper, plastic, plastic coated metal while holding items in their hands or rubbing them with their fingers, their palms, and the side of the palm of the dominant hand. Material and Methods: Sixty participants took part in the study. Items were swabbed with a moistened cotton swab. DNA was isolated using the Chelex procedure and quantified by real-time PCR. Results: We found that DNA concentration transferred to an item was independent of the handling time. On the contrary, it was dependent on the item’s texture; the greatest concentration was left on plastic coated metal (PCM and the least on paper. The greatest concentration of trace DNA was left by participants from 35 to 44 years of age. Results of the study showed that men deposit a higher DNA concentration than do women. Conclusion: Item texture, donor age, and gender influence trace DNA concentration. Further investigations are necessary to fully understand the process of DNA transfer from donors to handled items.

  3. Irradiation induced surface segregation in concentrated alloys: a contribution; Contribution a l`etude de la segregation de surface induite par irradiation dans les alliages concentres

    Energy Technology Data Exchange (ETDEWEB)

    Grandjean, Y.

    1996-12-31

    A new computer modelization of irradiation induced surface segregation is presented together with some experimental determinations in binary and ternary alloys. The model we propose handles the alloy thermodynamics and kinetics at the same level of sophistication. Diffusion is described at the atomistic level and proceeds vis the jumps of point defects (vacancies, dumb-bell interstitials): the various jump frequencies depend on the local composition in a manner consistent with the thermodynamics of the alloy. For application to specific alloys, we have chosen the simplest statistical approximation: pair interactions in the Bragg Williams approximation. For a system which exhibits the thermodynamics and kinetics features of Ni-Cu alloys, the model generates the behaviour parameters (flux and temperature) and of alloy composition. Quantitative agreement with the published experimental results (two compositions, three temperatures) is obtained with a single set of parameters. Modelling austenitic steels used in nuclear industry requires taking into account the contribution of dumbbells to mass transport. The effects of this latter contribution are studied on a model of Ni-Fe. Interstitial trapping on dilute impurities is shown to delay or even suppress the irradiation induced segregation. Such an effect is indeed observed in the experiments we report on Fe{sub 50}Ni{sub 50} and Fe{sub 49}Ni{sub 50}Hf{sub 1} alloys. (author). 190 refs.

  4. Basin-scale heterogeneity in Antarctic precipitation and its impact on surface mass variability

    Directory of Open Access Journals (Sweden)

    J. Fyke

    2017-11-01

    Full Text Available Annually averaged precipitation in the form of snow, the dominant term of the Antarctic Ice Sheet surface mass balance, displays large spatial and temporal variability. Here we present an analysis of spatial patterns of regional Antarctic precipitation variability and their impact on integrated Antarctic surface mass balance variability simulated as part of a preindustrial 1800-year global, fully coupled Community Earth System Model simulation. Correlation and composite analyses based on this output allow for a robust exploration of Antarctic precipitation variability. We identify statistically significant relationships between precipitation patterns across Antarctica that are corroborated by climate reanalyses, regional modeling and ice core records. These patterns are driven by variability in large-scale atmospheric moisture transport, which itself is characterized by decadal- to centennial-scale oscillations around the long-term mean. We suggest that this heterogeneity in Antarctic precipitation variability has a dampening effect on overall Antarctic surface mass balance variability, with implications for regulation of Antarctic-sourced sea level variability, detection of an emergent anthropogenic signal in Antarctic mass trends and identification of Antarctic mass loss accelerations.

  5. Concentration Dependences of the Surface Tension and Density of Solutions of Acetone-Ethanol-Water Systems at 293 K

    Science.gov (United States)

    Dadashev, R. Kh.; Dzhambulatov, R. S.; Mezhidov, V. Kh.; Elimkhanov, D. Z.

    2018-05-01

    Concentration dependences of the surface tension and density of solutions of three-component acetone-ethanol-water systems and the bounding binary systems at 273 K are studied. The molar volume, adsorption, and composition of surface layers are calculated. Experimental data and calculations show that three-component solutions are close to ideal ones. The surface tensions of these solutions are calculated using semi-empirical and theoretical equations. Theoretical equations qualitatively convey the concentration dependence of surface tension. A semi-empirical method based on the Köhler equation allows us to predict the concentration dependence of surface tension within the experimental error.

  6. Ambient Surface Analysis of Organic Monolayers using Direct Analysis in Real Time Orbitrap Mass Spectrometry

    NARCIS (Netherlands)

    Manova, R.K.; Joshi, S.; Debrassi, A.; Bhairamadgi, N.S.; Roeven, E.; Gagnon, J.; Tahir, M.N.; Claassen, F.W.; Scheres, L.M.W.; Wennekes, T.; Schroën, C.G.P.H.; Beek, van T.A.; Zuilhof, H.; Nielen, M.W.F.

    2014-01-01

    A better characterization of nanometer-thick organic layers (monolayers) as used for engineering surface properties, biosensing, nanomedicine, and smart materials will widen their application. The aim of this study was to develop direct analysis in real time high-resolution mass spectrometry

  7. The Minimum-Mass Surface Density of the Solar Nebula using the Disk Evolution Equation

    Science.gov (United States)

    Davis, Sanford S.

    2005-01-01

    The Hayashi minimum-mass power law representation of the pre-solar nebula (Hayashi 1981, Prog. Theo. Phys.70,35) is revisited using analytic solutions of the disk evolution equation. A new cumulative-planetary-mass-model (an integrated form of the surface density) is shown to predict a smoother surface density compared with methods based on direct estimates of surface density from planetary data. First, a best-fit transcendental function is applied directly to the cumulative planetary mass data with the surface density obtained by direct differentiation. Next a solution to the time-dependent disk evolution equation is parametrically adapted to the planetary data. The latter model indicates a decay rate of r -1/2 in the inner disk followed by a rapid decay which results in a sharper outer boundary than predicted by the minimum mass model. The model is shown to be a good approximation to the finite-size early Solar Nebula and by extension to extra solar protoplanetary disks.

  8. Higher surface mass balance of the Greenland ice sheet revealed by high-resolution climate modeling

    NARCIS (Netherlands)

    Ettema, J.|info:eu-repo/dai/nl/304831913; van den Broeke, M.R.|info:eu-repo/dai/nl/073765643; van Meijgaard, E.; van de Berg, W.J.|info:eu-repo/dai/nl/304831611; Bamber, Jonathan L.; Box, J.E.; Bales, R.C.

    2009-01-01

    High-resolution (∼11 km) regional climate modeling shows total annual precipitation on the Greenland ice sheet for 1958–2007 to be up to 24% and surface mass balance up to 63% higher than previously thought. The largest differences occur in coastal southeast Greenland, where the much higher

  9. Future climate warming increases Greenland ice sheet surface mass balance variability

    NARCIS (Netherlands)

    Fyke, J.G.; Vizcaino, M.; Lipscomb, W.; Price, S.

    2014-01-01

    The integrated surface mass balance (SMB) of the Greenland ice sheet (GrIS) has large interannual variability. Long-term future changes to this variability will affect GrIS dynamics, freshwater fluxes, regional oceanography, and detection of changes in ice volume trends. Here we analyze a simulated

  10. Greenland ice sheet surface mass balance: evaluating simulations and making projections with regional climate models

    NARCIS (Netherlands)

    Rae, J.G.L.; Aðalgeirsdóttir, G.; Edwards, T.L.; Fettweis, X.; Gregory, J.M.; Hewitt, H.T.; Lowe, J.A.; Lucas-Picher, P.; Mottram, R.H.; Payne, A.J.; Ridley, J.K.; Shannon, S.R.; van de Berg, W.J.|info:eu-repo/dai/nl/304831611; van de Wal, R.S.W.|info:eu-repo/dai/nl/101899556; van den Broeke, M.R.|info:eu-repo/dai/nl/073765643

    2012-01-01

    Four high-resolution regional climate models (RCMs) have been set up for the area of Greenland, with the aim of providing future projections of Greenland ice sheet surface mass balance (SMB), and its contribution to sea level rise, with greater accuracy than is possible from coarser-resolution

  11. Aeolian vertical mass flux profiles above dry and moist sandy beach surfaces

    Science.gov (United States)

    Rotnicka, Joanna

    2013-04-01

    The vertical distribution of aeolian mass flux was investigated in a natural beach environment. Field experiments conducted on the beach of the Łeba Barrier, southern Baltic coast, Poland, measured the sand transport rate and the vertical mass flux distribution above dry rippled sand and a moist flat sandy surface. The experiments were intended to show the changes in the vertical distribution of sand with changing wind speed. All the data represent saturated flux conditions. Sand transport was measured using 0.5 m-high vertically segmented passive sand traps, while the wind speed and direction were monitored at 1 m elevation. The obtained dataset comprises 65 measurements on dry surfaces and 51 measurements on moist sandy surfaces. The sand transport rate above the moist surface was up to 90% higher than above the dry surface for wind speeds of 7-11 m/s, but higher velocities gave smaller differences between the surfaces. The saltation layer was thicker above the moist surface than above the dry surface. All the vertical sand flux profiles are best described by exponential decay functions. Analysis of the normalised flux profiles grouped by wind velocity shows that the fitted curves are less inclined for moist surfaces than dry surfaces. Moreover, the regression coefficients depict a marked trend in which the intercept decreases and the slope increases with increasing wind speed; this indicates that more sand is transported at higher elevations above the bed and less at lower elevations. The proportion of total transport seems to be independent of wind speed at elevations of approximately 35 mm and 50 mm above the dry and moist surfaces, respectively. Differences between the measured- and exponential-fit values of mass flux are particularly distinct close to the bed, where the exponential fit either over- or under-predicts the measured values. Over-predictions occur in weaker winds (up to 6-7 m/s), whereas under-predictions become more pronounced as the wind

  12. Corporal surface as indicator of muscular mass in the adult of the masculine sex

    International Nuclear Information System (INIS)

    Fernandez Vieitez, Jorge Alberto

    2003-01-01

    With the objective of finding out the body surface area equation (BSA, m2) that is most suitable as indicator of musculature because of its higher correlation with the muscle mass (MM,kg), a correlation analysis was made between the MM and the BSA estimated by 11 weight and height-based formulae. Primary weight, height and MM data were obtained from these studies (N=41) in which MM was determined by cadaver dissection or by computerized axial tomography. A remarkable variability was observed in the BSA values estimated by 11 equations (F=59,7; p< 0,05). The correlation coefficients between the body surface estimated by different equations and the muscle mass were statistically significant and very similar. It was concluded that there is no BSA equation that is far better than the rest as muscle mass indicator. Mostellers equation is recommended due to its calculation simplicity

  13. Exploring surface photoreaction dynamics using pixel imaging mass spectrometry (PImMS)

    Science.gov (United States)

    Kershis, Matthew D.; Wilson, Daniel P.; White, Michael G.; John, Jaya John; Nomerotski, Andrei; Brouard, Mark; Lee, Jason W. L.; Vallance, Claire; Turchetta, Renato

    2013-08-01

    A new technique for studying surface photochemistry has been developed using an ion imaging time-of-flight mass spectrometer in conjunction with a fast camera capable of multimass imaging. This technique, called pixel imaging mass spectrometry (PImMS), has been applied to the study of butanone photooxidation on TiO2(110). In agreement with previous studies of this system, it was observed that the main photooxidation pathway for butanone involves ejection of an ethyl radical into vacuum which, as confirmed by our imaging experiment, undergoes fragmentation after ionization in the mass spectrometer. This proof-of-principle experiment illustrates the usefulness and applicability of PImMS technology to problems of interest within the surface science community.

  14. Determination of glycerol concentrations and glycerol isotopic enrichments in human plasma by gas chromatography/mass spectrometry

    NARCIS (Netherlands)

    Ackermans, M. T.; Ruiter, A. F.; Endert, E.

    1998-01-01

    An analytical method is presented to determine glycerol concentrations and stable isotope tracer enrichments in human plasma after intravenous tracer infusion in a single analytical run, using gas chromatography coupled to mass spectrometry. The method uses an internal standard, which is also a

  15. Past and future sea-level change from the surface mass balance of glaciers

    Directory of Open Access Journals (Sweden)

    B. Marzeion

    2012-11-01

    Full Text Available We present estimates of sea-level change caused by the global surface mass balance of glaciers, based on the reconstruction and projection of the surface mass balance of all the individual glaciers of the world, excluding the ice sheets in Greenland and Antarctica. The model is validated using a leave-one-glacier-out cross-validation scheme against 3997 observed surface mass balances of 255 glaciers, and against 756 geodetically observed, temporally integrated volume and surface area changes of 341 glaciers. When forced with observed monthly precipitation and temperature data, the glaciers of the world are reconstructed to have lost mass corresponding to 114 ± 5 mm sea-level equivalent (SLE between 1902 and 2009. Using projected temperature and precipitation anomalies from 15 coupled general circulation models from the Coupled Model Intercomparison Project phase 5 (CMIP5 ensemble, they are projected to lose an additional 148 ± 35 mm SLE (scenario RCP26, 166 ± 42 mm SLE (scenario RCP45, 175 ± 40 mm SLE (scenario RCP60, or 217 ± 47 mm SLE (scenario RCP85 during the 21st century. Based on the extended RCP scenarios, glaciers are projected to approach a new equilibrium towards the end of the 23rd century, after having lost either 248 ± 66 mm SLE (scenario RCP26, 313 ± 50 mm SLE (scenario RCP45, or 424 ± 46 mm SLE (scenario RCP85. Up until approximately 2100, ensemble uncertainty within each scenario is the biggest source of uncertainty for the future glacier mass loss; after that, the difference between the scenarios takes over as the biggest source of uncertainty. Ice mass loss rates are projected to peak 2040 ∼ 2050 (RCP26, 2050 ∼ 2060 (RCP45, 2070 ∼ 2090 (RCP60, or 2070 ∼ 2100 (RCP85.

  16. Effect of Fe3O4 Magnetic Nanoparticle Concentration on the Signal of Surface Plasmon Resonance (SPR) Spectroscopy

    Science.gov (United States)

    Oktivina, M.; Nurrohman, D. T.; Rinto, A. N. Q. Z.; Suharyadi, E.; Abraha, K.

    2017-05-01

    Effect of Fe3O4 magnetic nanoparticle concentration on the signal of surface plasmon resonance (SPR) spectra has been successfully observed. The Fe3O4 nanoparticles with a particle size of about 10.5 ± 0.2 nm were used as active materials to increase the SPR response. X-ray diffraction (XRD) pattern showed that Fe3O4 nanoparticles have a high degree of crystallinity with spinel structure. The SPR system was successfully set up by using a glass prism coupler in a Kretschmann configuration in which gold (Au) thin film was thermally evaporated on the prism base. A green laser of wavelength 543 nm was used as light source. The angular scan in the attenuated total reflection (ATR) spectra showed a dropping intensity. Those things clearly indicated the appearance of SPR coupling phenomenon on the interface of Au thin film. The SPR spectra of fixed Au masses were also performed with same angular positions of dips. The Fe3O4 nanoparticles were deposited on gold thin film as a third layer which was synthesized via co-precipitation method. Hence, it was observed that the variation of Fe3O4 concentration affected the SPR spectra profile. The concentrations of Fe3O4 nanoparticles are 1, 3, 5, 7, 9, and 11 mg/ml which correspond to the angle shift of 0.1°, 0.3°, 0.5°, 0.7°, 0.9°, and 1.0°, respectively. The SPR angle of the dip was shifted to higher value due to change of refractive index of the medium as Fe3O4 nanoparticles concentration increases. Based on this result, we can conclude that the angle shift of SPR increases with increasing concentration of Fe3O4 nanoparticles.

  17. In Situ Measurements of Aerosol Mass Concentration and Spectral Absorption at Three Location in and Around Mexico City

    Science.gov (United States)

    Chaudhry, Z.; Martins, V.; Li, Z.

    2006-12-01

    As a result of population growth and increasing industrialization, air pollution in heavily populated urban areas is one of the central environmental problems of the century. As a part of the MILAGRO (Megacity Initiative: Local and Global Research Observations) study, Nuclepore filters were collected in two size ranges (PM10 and PM2.5) at 12 hour intervals at three location in Mexico during March, 2006. Sampling stations were located at the Instituto Mexicano del Petroleo (T0), at the Rancho La Bisnago in the State of Hidalgo (T2) and along the Gulf Coast in Tampico (Tam). Each filter was analyzed for mass concentration, aerosol scattering and absorption efficiencies. Mass concentrations at T0 ranged from 47 to 179 μg/m3 for PM10 with an average concentration of 96 μg/m3, and from 20 to 93 μg/m3 for PM2.5 with an average concentration of 41 μg/m3. Mass concentrations at T2 ranged from 12 to 154 μg/m3 for PM10 with an average concentration of 51 μg/m3, and from 7 to 50 μg/m3 for PM2.5 with an average concentration of 25 μg/m3. Mass concentrations at Tam ranged from 34 to 80 μg/m3 for PM10 with an average concentration of 52 μg/m3, and from 8 to 23 μg/m3 for PM2.5 with an average concentration of 13 μg/m3. While some of the extreme values are likely linked to local emissions, regional air pollution episodes also played important roles. Each of the sampling stations experienced a unique atmospheric condition. The site at T0 was influenced by urban air pollution and dust storms, the site at T2 was significantly less affected by air pollution but more affected by regional dust storms and local dust devils while Tam was influenced by air pollution, dust storms and the natural marine environment. The spectral mass absorption efficiency was measured from 350 to 2500 nm and shows large differences between the absorption properties of soil dust, black carbon, and organic aerosols. The strong spectral differences observed can be related to differences in

  18. Defining an Abrasion Index for Lunar Surface Systems as a Function of Dust Interaction Modes and Variable Concentration Zones

    Science.gov (United States)

    Kobrick, Ryan L.; Klaus, David M.; Street, Kenneth W., Jr.

    2010-01-01

    Unexpected issues were encountered during the Apollo era of lunar exploration due to detrimental abrasion of materials upon exposure to the fine-grained, irregular shaped dust on the surface of the Moon. For critical design features involving contact with the lunar surface and for astronaut safety concerns, operational concepts and dust tolerance must be considered in the early phases of mission planning. To systematically define material selection criteria, dust interaction can be characterized by two-body or three-body abrasion testing, and subcategorically by physical interactions of compression, rolling, sliding and bending representing specific applications within the system. Two-body abrasion occurs when a single particle or asperity slides across a given surface removing or displacing material. Three-body abrasion occurs when multiple particles interact with a solid surface, or in between two surfaces, allowing the abrasives to freely rotate and interact with the material(s), leading to removal or displacement of mass. Different modes of interaction are described in this paper along with corresponding types of tests that can be utilized to evaluate each configuration. In addition to differential modes of abrasion, variable concentrations of dust in different zones can also be considered for a given system design and operational protocol. These zones include: (1) outside the habitat where extensive dust exposure occurs, (2) in a transitional zone such as an airlock or suitport, and (3) inside the habitat or spacesuit with a low particle count. These zones can be used to help define dust interaction frequencies, and corresponding risks to the systems and/or crew can be addressed by appropriate mitigation strategies. An abrasion index is introduced that includes the level of risk, R, the hardness of the mineralogy, H, the severity of the abrasion mode, S, and the frequency of particle interactions, F.

  19. Reconstruction of the 1979–2006 Greenland ice sheet surface mass balance using the regional climate model MAR

    Directory of Open Access Journals (Sweden)

    X. Fettweis

    2007-10-01

    Full Text Available Results from a 28-year simulation (1979–2006 over the Greenland ice sheet (GrIS reveal an increase of solid precipitation (+0.4±2.5 km3 yr−2 and run-off (+7.9±3.3 km3 yr−2 of surface meltwater. The net effect of these competing factors is a significant Surface Mass Balance (SMB loss of −7.2±5.1 km3 yr−2. The contribution of changes in the net water vapour flux (+0.02±0.09 km3 yr−2 and rainfall (+0.2±0.2 km3 yr−2 to the SMB variability is negligible. The meltwater supply has increased because the GrIS surface has been warming up +2.4°C since 1979. Sensible heat flux, latent heat flux and net solar radiation have not varied significantly over the last three decades. However, the simulated downward infrared flux has increased by 9.3 W m−2 since 1979. The natural climate variability (e.g. the North Atlantic Oscillation does not explain these changes. The recent global warming, due to the greenhouse gas concentration increase induced by human activities, could be a cause of these changes. The doubling of surface meltwater flux into the ocean over the period 1979–2006 suggests that the overall ice sheet mass balance has been increasingly negative, given the likely meltwater-induced acceleration of outlet glaciers. This study suggests that increased melting overshadows over an increased accumulation in a warming scenario and that the GrIS is likely to keep losing mass in the future. An enduring GrIS melting will probably affect in the future an certain effect on the stability of the thermohaline circulation and the global sea level rise.

  20. Extending and refining the nuclear mass surface with ISOLTRAP and MISTRAL

    International Nuclear Information System (INIS)

    Lunney, D.; Bollen, G.

    2000-01-01

    Through the nuclear binding energy, the atomic mass gives us important information about nuclear structure. Viewing the ensemble of mass data over the nuclear chart, we can examine the hills and valleys that form this surface and make hypotheses about the effects of certain nuclear configurations. To unveil these effects, mass measurements of very high precision ( -6 ) are required. Two experiments at ISOLDE pursue this effort of nuclear cartography: the tandem Penning trap spectrometer ISOLTRAP and the radiofrequency transmission spectrometer MISTRAL. Between them, the masses of almost 150 nuclides have been measured from stable isotopes to those with half-lives as short as 30 ms. Both experiments rely on good optical properties of a low energy ion beam and are thus well suited to the ISOLDE facility

  1. Accurate determination of 41Ca concentrations in spent resins from the nuclear industry by Accelerator Mass Spectrometry

    International Nuclear Information System (INIS)

    Nottoli, Emmanuelle; Bourlès, Didier; Bienvenu, Philippe; Labet, Alexandre; Arnold, Maurice; Bertaux, Maité

    2013-01-01

    The radiological characterisation of nuclear waste is essential for managing storage sites. Determining the concentration of Long‐Lived RadioNuclides (LLRN) is fundamental for their long-term management. This paper focuses on the measurement of low 41 Ca concentrations in ions exchange resins used for primary fluid purification in Pressurised Water Reactors (PWR). 41 Ca concentrations were successfully measured by Accelerator Mass Spectrometry (AMS) after the acid digestion of resin samples, followed by radioactive decontamination and isobaric suppression through successive hydroxide, carbonate, nitrate and final CaF 2 precipitations. Measured 41 Ca concentrations ranged from 0.02 to 0.03 ng/g, i.e. from 0.06 to 0.09 Bq/g. The 41 Ca/ 60 Co activity ratios obtained were remarkably reproducible and in good agreement with the current ratio used for resins management. - Highlights: • In the context of radioactive waste management, this study aimed at measuring 41 Ca in spent resins using Accelerator Mass Spectrometry. • A chemical treatment procedure was developed to quantitatively recover calcium in solution and selectively extract it. • Developed firstly on synthetic matrices, the chemical treatment procedure was then successfully applied to real resin samples. • Accelerator mass spectrometry allowed measuring concentrations of 41 Ca in spent resins as low as 0.02 ng/g of dry resin. • Final results are in agreement with current data used for spent resins management

  2. Optimization of artificial neural network models through genetic algorithms for surface ozone concentration forecasting.

    Science.gov (United States)

    Pires, J C M; Gonçalves, B; Azevedo, F G; Carneiro, A P; Rego, N; Assembleia, A J B; Lima, J F B; Silva, P A; Alves, C; Martins, F G

    2012-09-01

    This study proposes three methodologies to define artificial neural network models through genetic algorithms (GAs) to predict the next-day hourly average surface ozone (O(3)) concentrations. GAs were applied to define the activation function in hidden layer and the number of hidden neurons. Two of the methodologies define threshold models, which assume that the behaviour of the dependent variable (O(3) concentrations) changes when it enters in a different regime (two and four regimes were considered in this study). The change from one regime to another depends on a specific value (threshold value) of an explanatory variable (threshold variable), which is also defined by GAs. The predictor variables were the hourly average concentrations of carbon monoxide (CO), nitrogen oxide, nitrogen dioxide (NO(2)), and O(3) (recorded in the previous day at an urban site with traffic influence) and also meteorological data (hourly averages of temperature, solar radiation, relative humidity and wind speed). The study was performed for the period from May to August 2004. Several models were achieved and only the best model of each methodology was analysed. In threshold models, the variables selected by GAs to define the O(3) regimes were temperature, CO and NO(2) concentrations, due to their importance in O(3) chemistry in an urban atmosphere. In the prediction of O(3) concentrations, the threshold model that considers two regimes was the one that fitted the data most efficiently.

  3. Variation in glyphosate and AMPA concentrations of surface water and groundwater

    Science.gov (United States)

    Caprile, Ana Clara; Aparicio, Virginia; Sasal, Carolina; Andriulo, Enrique

    2017-04-01

    The presence of pesticides in various environmental matrices indicate that the soil's ability to function as a bio-physical-chemical reactor is declining. As it operates as an interface between air and water, it causes a negative impact on these two vital resources. Currently, the pampa agriculture is simplified with a marked tendency towards spring-summer crops, where the main crops are RR soybean and corn. Herbicides are neither retained nor degraded in the soil, which results in polluted groundwater and surface waters. The objectives of this study were: a) to verify the presence of glyphosate and aminomethylphosphonic acid (AMPA) in Pergamino stream (a typical representative of the most productive agricultural region of Argentina) under different land use and to detect if in the detections there was a space-time pattern, and b) to verify the detection of these molecules in groundwater of the upper same basin under exclusively rural land use. Surface stream was sampling in six sites (five under rural land use and one under urban-industrial land use) at a rate of one sample by spring, summer and winter seasons (2010-2013, 54 total samples). Groundwater glyphosate and AMPA concentrations were determined in 24 piezometers constructed at two positions of the landscape, across the groundwater flow direction, sampled at two sampling dates (2010 and 2012, 45 total samples). In surface water, glyphosate and AMPA were detected in 54 and 69% of the samples analyzed, respectively. The median concentrations were 0.9 and 0.8 µg L-1 for glyphosate and AMPA and maximal concentrations 258 and 5865 µg L-1, respectively. The sampling site under urban-industrial land use had abnormally high concentrations of glyphosate in the spring (attributed to point pollution), a fact that not allowed to see differences in the remaining sampling times under different land uses. AMPA concentrations under urban-industrial land use were high and higher than rural land use in 3 studied seasons

  4. Studying the microlenses mass function from statistical analysis of the caustic concentration

    Energy Technology Data Exchange (ETDEWEB)

    Mediavilla, T; Ariza, O [Departamento de Estadistica e Investigacion Operativa, Universidad de Cadiz, Avda de Ramon Puyol, s/n 11202 Algeciras (Spain); Mediavilla, E [Instituto de Astrofisica de Canarias, Avda Via Lactea s/n, La Laguna (Spain); Munoz, J A, E-mail: teresa.mediavilla@ca.uca.es, E-mail: octavio.ariza@uca.es, E-mail: emg@iac.es [Departamento de Astrofisica y Astronomia, Universidad de Valencia, Burjassot, Valencia (Spain)

    2011-09-22

    The statistical distribution of caustic crossings by the images of a lensed quasar depends on the properties of the distribution of microlenses in the lens galaxy. We use a procedure based in Inverse Polygon Mapping to easily identify the critical and caustic curves generated by a distribution of stars in the lens galaxy. We analyze the statistical distributions of the number of caustic crossings by a pixel size source for several projected mass densities and different mass distributions. We compare the results of simulations with theoretical binomial distributions. Finally we apply this method to the study of the stellar mass distribution in the lens galaxy of QSO 2237+0305.

  5. Geographical altitude, size, mass and body surface area in children (1-4 years) in the Province of Jujuy (Argentina).

    Science.gov (United States)

    Román, Estela María; Bejarano, Ignacio Felipe; Alfaro, Emma Laura; Abdo, Guadalupe; Dipierri, José Edgardo

    2015-01-01

    Highland child populations show low growth rates. To evaluate the variation of size, mass and body surface area of Jujenean infants (1-4 years) as a function of geographic altitude. Nutritional status of 8059 healthy infants was determined based on weight and height data; body mass index, ponderal index, body surface area, body surface area/mass and ectomorphy were calculated. Variables were standardized with a provincial mean and WHO references. Data were grouped by age, sex and geographic altitude: Highlands (≥2500 masl) and Lowlands (children differ in size, mass and body surface area based on the geographical altitude and adverse nutritional and socioeconomic factors.

  6. Quantitative kinetics of proteolytic enzymes determined by a surface concentration-based assay using peptide arrays.

    Science.gov (United States)

    Jung, Se-Hui; Kong, Deok-Hoon; Park, Seoung-Woo; Kim, Young-Myeong; Ha, Kwon-Soo

    2012-08-21

    Peptide arrays have emerged as a key technology for drug discovery, diagnosis, and cell biology. Despite the promise of these arrays, applications of peptide arrays to quantitative analysis of enzyme kinetics have been limited due to the difficulty in obtaining quantitative information of enzymatic reaction products. In this study, we developed a new approach for the quantitative kinetics analysis of proteases using fluorescence-conjugated peptide arrays, a surface concentration-based assay with solid-phase peptide standards using dry-off measurements, and compared it with an applied concentration-based assay. For fabrication of the peptide arrays, substrate peptides of cMMP-3, caspase-3, caspase-9, and calpain-1 were functionalized with TAMRA and cysteine, and were immobilized onto amine-functionalized arrays using a heterobifunctional linker, N-[γ-maleimidobutyloxy]succinimide ester. The proteolytic activities of the four enzymes were quantitatively analyzed by calculating changes induced by enzymatic reactions in the concentrations of peptides bound to array surfaces. In addition, this assay was successfully applied for calculating the Michaelis constant (K(m,surf)) for the four enzymes. Thus, this new assay has a strong potential for use in the quantitative evaluation of proteases, and for drug discovery through kinetics studies including the determination of K(m) and V(max).

  7. Biofunctionalization of the implant surface with different concentrations of a synthetic peptide (P-15).

    Science.gov (United States)

    Lutz, R; Prechtl, C; Nonhoff, J; Weisel, T; Damien, C J; Schlegel, K A

    2013-07-01

    This study aimed at identifying the ideal concentration of a biofunctional surface coating of dental implants with a synthetic peptide (P-15). In a previous study, P-15 was shown to enhance osseointegration parameters. Implants (modified ANKYLOS(®) A8; FRIADENT Plus(®) surface) with five different concentrations (0-400 μg/ml) of a P-15 coating as well as uncoated controls were inserted in the frontal bone of 45 adult domestic pigs. The histomorphometric and microradiographic findings for the coated implants were compared to those for the uncoated ones after 7, 14, and 30 days. No significant differences were observed comparing the peri-implant bone density between the coated and uncoated implants The bone-to-implant contact, as the primary histological parameter for osseointegration, showed high rates for all surfaces investigated (between 73.3 ± 17.9% for the control and 81.9 ± 15.2% for P15 20 μg/ml after 30 days). No significant benefit on osseointegration of a biofunctional P-15 coating of dental implants could be displayed in the present study. © 2012 John Wiley & Sons A/S.

  8. Optimization of sampling for the determination of the mean Radium-226 concentration in surface soil

    International Nuclear Information System (INIS)

    Williams, L.R.; Leggett, R.W.; Espegren, M.L.; Little, C.A.

    1987-08-01

    This report describes a field experiment that identifies an optimal method for determination of compliance with the US Environmental Protection Agency's Ra-226 guidelines for soil. The primary goals were to establish practical levels of accuracy and precision in estimating the mean Ra-226 concentration of surface soil in a small contaminated region; to obtain empirical information on composite vs. individual soil sampling and on random vs. uniformly spaced sampling; and to examine the practicality of using gamma measurements in predicting the average surface radium concentration and in estimating the number of soil samples required to obtain a given level of accuracy and precision. Numerous soil samples were collected on each six sites known to be contaminated with uranium mill tailings. Three types of samples were collected on each site: 10-composite samples, 20-composite samples, and individual or post hole samples; 10-composite sampling is the method of choice because it yields a given level of accuracy and precision for the least cost. Gamma measurements can be used to reduce surface soil sampling on some sites. 2 refs., 5 figs., 7 tabs

  9. Mass

    International Nuclear Information System (INIS)

    Quigg, Chris

    2007-01-01

    In the classical physics we inherited from Isaac Newton, mass does not arise, it simply is. The mass of a classical object is the sum of the masses of its parts. Albert Einstein showed that the mass of a body is a measure of its energy content, inviting us to consider the origins of mass. The protons we accelerate at Fermilab are prime examples of Einsteinian matter: nearly all of their mass arises from stored energy. Missing mass led to the discovery of the noble gases, and a new form of missing mass leads us to the notion of dark matter. Starting with a brief guided tour of the meanings of mass, the colloquium will explore the multiple origins of mass. We will see how far we have come toward understanding mass, and survey the issues that guide our research today.

  10. Near-surface Heating of Young Rift Sediment Causes Mass Production and Discharge of Reactive Dissolved Organic Matter

    Science.gov (United States)

    Lin, Yu-Shih; Koch, Boris P.; Feseker, Tomas; Ziervogel, Kai; Goldhammer, Tobias; Schmidt, Frauke; Witt, Matthias; Kellermann, Matthias Y.; Zabel, Matthias; Teske, Andreas; Hinrichs, Kai-Uwe

    2017-03-01

    Ocean margin sediments have been considered as important sources of dissolved organic carbon (DOC) to the deep ocean, yet the contribution from advective settings has just started to be acknowledged. Here we present evidence showing that near-surface heating of sediment in the Guaymas Basin, a young extensional depression, causes mass production and discharge of reactive dissolved organic matter (DOM). In the sediment heated up to ~100 °C, we found unexpectedly low DOC concentrations in the pore waters, reflecting the combined effect of thermal desorption and advective fluid flow. Heating experiments suggested DOC production to be a rapid, abiotic process with the DOC concentration increasing exponentially with temperature. The high proportions of total hydrolyzable amino acids and presence of chemical species affiliated with activated hydrocarbons, carbohydrates and peptides indicate high reactivity of the DOM. Model simulation suggests that at the local scale, near-surface heating of sediment creates short and massive DOC discharge events that elevate the bottom-water DOC concentration. Because of the heterogeneous distribution of high heat flow areas, the expulsion of reactive DOM is spotty at any given time. We conclude that hydrothermal heating of young rift sediments alter deep-ocean budgets of bioavailable DOM, creating organic-rich habitats for benthic life.

  11. Near-surface Heating of Young Rift Sediment Causes Mass Production and Discharge of Reactive Dissolved Organic Matter.

    Science.gov (United States)

    Lin, Yu-Shih; Koch, Boris P; Feseker, Tomas; Ziervogel, Kai; Goldhammer, Tobias; Schmidt, Frauke; Witt, Matthias; Kellermann, Matthias Y; Zabel, Matthias; Teske, Andreas; Hinrichs, Kai-Uwe

    2017-03-22

    Ocean margin sediments have been considered as important sources of dissolved organic carbon (DOC) to the deep ocean, yet the contribution from advective settings has just started to be acknowledged. Here we present evidence showing that near-surface heating of sediment in the Guaymas Basin, a young extensional depression, causes mass production and discharge of reactive dissolved organic matter (DOM). In the sediment heated up to ~100 °C, we found unexpectedly low DOC concentrations in the pore waters, reflecting the combined effect of thermal desorption and advective fluid flow. Heating experiments suggested DOC production to be a rapid, abiotic process with the DOC concentration increasing exponentially with temperature. The high proportions of total hydrolyzable amino acids and presence of chemical species affiliated with activated hydrocarbons, carbohydrates and peptides indicate high reactivity of the DOM. Model simulation suggests that at the local scale, near-surface heating of sediment creates short and massive DOC discharge events that elevate the bottom-water DOC concentration. Because of the heterogeneous distribution of high heat flow areas, the expulsion of reactive DOM is spotty at any given time. We conclude that hydrothermal heating of young rift sediments alter deep-ocean budgets of bioavailable DOM, creating organic-rich habitats for benthic life.

  12. The influence of changes in glacier extent and surface elevation on modeled mass balance

    Directory of Open Access Journals (Sweden)

    F. Paul

    2010-12-01

    Full Text Available Glaciers are widely recognized as unique demonstration objects for climate change impacts, mostly due to the strong change of glacier length in response to small climatic changes. However, glacier mass balance as the direct response to the annual atmospheric conditions can be better interpreted in meteorological terms. When the climatic signal is deduced from long-term mass balance data, changes in glacier geometry (i.e. surface extent and elevation must be considered as such adjustments form an essential part of the glacier reaction to new climatic conditions. In this study, a set of modelling experiments is performed to assess the influence of changes in glacier geometry on mass balance for constant climatic conditions. The calculations are based on a simplified distributed energy/mass balance model in combination with information on glacier extent and surface elevation for the years 1850 and 1973/1985 for about 60 glaciers in the Swiss Alps. The results reveal that over this period about 50–70% of the glacier reaction to climate change (here a one degree increase in temperature is "hidden" in the geometric adjustment, while only 30–50% can be measured as the long-term mean mass balance. For larger glaciers, the effect of the areal change is partly reduced by a lowered surface elevation, which results in a slightly more negative balance despite a potential increase of topographic shading. In view of several additional reinforcement feedbacks that are observed in periods of strong glacier decline, it seems that the climatic interpretation of long-term mass balance data is rather complex.

  13. Spatial and seasonal variability of the mass concentration and chemical composition of PM2.5in Poland.

    Science.gov (United States)

    Rogula-Kozłowska, Wioletta; Klejnowski, Krzysztof; Rogula-Kopiec, Patrycja; Ośródka, Leszek; Krajny, Ewa; Błaszczak, Barbara; Mathews, Barbara

    2014-01-01

    The seasonal changes in ambient mass concentrations and chemical composition of fine particulate matter (PM 2.5 ) were investigated in three locations in Poland. The analyses included PM 2.5 -bound hazardous benzo( a )pyrene (BaP), As, Ni, Cd, and Pb. The samples of PM 2.5 were collected daily in Katowice (southern Poland, urban background site), Gdańsk, and Diabla Góra (northern Poland, urban and regional background sites, respectively) during 1-year-long campaign in 2010. Based on monthly ambient concentrations of PM 2.5 -bound carbon (organic and elemental), water-soluble ions (Na + , NH 4 + , K + , Mg 2+ , Ca 2+ , Cl - , NO 3 - , SO 4 2- ), and elements As, Ni, Cd, Pb, Ti, Al, Fe, the chemical mass closure of PM 2.5 was checked for each of the four seasons of the year and for the heating and non-heating periods at each site. Also, the annual concentrations of PM 2.5 were determined and the annual PM 2.5 mass closure checked. At each measuring point, the PM 2.5 concentrations were high compared to its Polish yearly permissible value, 25 μg/m 3 , and its concentrations elsewhere in Europe. The highest annual PM 2.5 concentration, 43 μg/m 3 , occurred in Katowice; it was twice the annual PM 2.5 concentration in Gdańsk, and thrice the one in Diabla Góra. The high annual averages were due to very high monthly concentrations in the heating period, which were highest in the winter. PM 2.5 consisted mainly of carbonaceous matter (elemental carbon (EC) + organic matter (OM), the sum of elemental carbon, EC, and organic matter, OM; its annual mass contributions to PM 2.5 were 43, 31, and 33 % in Katowice, Gdansk, and Diabla Góra, respectively), secondary inorganic aerosol (SIA), the Na_Cl group, and crustal matter (CM)-in the decreasing order of their yearly mass contributions to PM 2.5 . OM, EC, SIA, Na_Cl, and CM accounted for almost 81 % of the PM 2.5 mass in Katowice, 74 % in Gdańsk, and 90 % in Diabla Góra. The annual average toxic metal contribution

  14. Effect of fat free mass on serum and plasma BDNF concentrations during exercise and recovery in healthy young men.

    Science.gov (United States)

    Gilder, M; Ramsbottom, R; Currie, J; Sheridan, B; Nevill, A M

    2014-02-07

    Exercise results in release of brain derived neurotrophic factor into the circulation; however, little is known about the changes in serum and plasma brain derived neurotrophic factor concentrations and factors influencing brain derived neurotrophic factor during exercise and recovery. Serum (n=23) and plasma (n=10) brain derived neurotrophic factor concentrations were measured in healthy young men at rest, during steady-rate and after exercise to determine the maximum aerobic power. A two-way analysis of variance was used to investigate brain derived neurotrophic factor levels in blood during exercise and recovery, with one between-subject factor (a median split on: age, height, body mass, fat free mass, body mass index and aerobic fitness), and one within-subject factor (time). Serum brain derived neurotrophic factor concentrations increased in response to exercise and declined rapidly in recovery. Plasma brain derived neurotrophic factor had a greater proportional increase relative to exhaustive exercise compared with serum brain derived neurotrophic factor and was slower to return to near baseline values. There was a significant group-by-time interaction indicating a greater release and faster recovery for serum brain derived neurotrophic factor in high- compared with low-fat free mass individuals. Copyright © 2013 Elsevier Ireland Ltd. All rights reserved.

  15. Application of gas chromatography-surface ionization organic mass spectrometry to forensic toxicology.

    Science.gov (United States)

    Ishii, Akira; Watanabe-Suzuki, Kanako; Seno, Hiroshi; Suzuki, Osamu; Katsumata, Yoshinao

    2002-08-25

    Surface ionization (SI), which consists in the formation of positive and negative ions along the course of thermal desorption of particles from a solid surface, was first applied as a detector for gas chromatography (GC), GC-surface ionization detection (SID); we developed many new sensitive methods for the determination of abused and other drugs by GC-SID. Recently, Fujii has devised a combination of SI and a quadrupole mass spectrometer and named this system a surface ionization organic mass spectrometer (SIOMS), which is highly selective and sensitive for organic compounds containing tertiary amino groups. We have tried to apply this mass spectrometer to forensic toxicological study; so far we have succeeded in determining important drugs-of-abuse and toxic compounds, such as phencyclidine (PCP), pethidine, pentazocine, MPTP and its derivatives from human body fluids with high sensitivity and selectivity. In this review, we describe our recent studies on the application of GC-SIOMS to forensic toxicology. Copyright 2002 Elsevier Science B.V.

  16. Application of »Mass Titration« to Determination of Surface Charge of Metal Oxides

    OpenAIRE

    1998-01-01

    The mass titration method, used for the point of zero charge determination, was extended to the measurement of the surface charge density. The results agree with the common method, which is the acid-base titration of the colloidal suspension. The advantage of mass titration is that one does not need to perform blank titration, instead one simply adds metal oxide powder to the electrolyte aqueous solution of known pH. To cover the pH range above and below the point of zero charge, two experime...

  17. Lower serum albumin concentration and change in muscle mass: the Health, Aging and Body Composition Study

    NARCIS (Netherlands)

    Visser, M.; Kritchevsky, S.B.; Newman, A.B.; Goodpaster, B.H.; Tylavsky, F.A.; Nevitt, M.C.; Harris, T.B.

    2005-01-01

    BACKGROUND: Low albumin concentrations in older persons increase the risk of poor health outcomes, including functional decline. OBJECTIVE: The aim of the study was to investigate the association between serum albumin concentration and skeletal muscle loss (sarcopenia) in old age. DESIGN: Serum

  18. Determinants of black carbon, particle mass and number concentrations in London transport microenvironments

    NARCIS (Netherlands)

    Rivas, Ioar; Kumar, Prashant; Hagen-Zanker, Alex; Andrade, Maria de Fatima; Slovic, Anne Dorothee; Pritchard, John P.; Geurs, Karst T.

    2017-01-01

    We investigated the determinants of personal exposure concentrations of commuters’ to black carbon (BC), ultrafine particle number concentrations (PNC), and particulate matter (PM1, PM2.5 and PM10) in different travel modes. We quantified the contribution of key factors that explain the variation of

  19. The influence of meteorological factors and biomass burning on surface ozone concentrations at Tanah Rata, Malaysia

    Science.gov (United States)

    Toh, Ying Ying; Lim, Sze Fook; von Glasow, Roland

    2013-05-01

    The surface ozone concentrations at the Tanah Rata regional Global Atmosphere Watch (GAW) station, Malaysia (4°28‧N, 101°23‧E, 1545 m above Mean Sea Level (MSL)) from June 2006 to August 2008 were analyzed in this study. Overall the ozone mixing ratios are very low; the seasonal variations show the highest mixing ratios during the Southwest monsoon (average 19.1 ppb) and lowest mixing ratios during the spring intermonsoon (average 14.2 ppb). The diurnal variation of ozone is characterised by an afternoon maximum and night time minimum. The meteorological conditions that favour the formation of high ozone levels at this site are low relative humidity, high temperature and minimum rainfall. The average ozone concentration is lower during precipitation days compared to non-precipitation days. The hourly averaged ozone concentrations show significant correlations with temperature and relative humidity during the Northeast monsoon and spring intermonsoon. The highest concentrations are observed when the wind is blowing from the west. We found an anticorrelation between the atmospheric pressure tide and ozone concentrations. The ozone mixing ratios do not exceed the recommended Malaysia Air Quality Guidelines for 1-h and 8-h averages. Five day backward trajectories on two high ozone episodes in 07 August 2006 (40.0 ppb) and 24 February 2008 (45.7 ppb) are computed using the HYbrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model to investigate the origin of the pollutants and influence of regional transport. The high ozone episode during 07 August 2006 (burning season during southwest monsoon) is mainly attributed to regional transport from biomass burning in Sumatra, whereas favourable meteorological conditions (i.e. low relative humidity, high temperature and solar radiation, zero rainfall) and long range transport from Indo-China have elevated the ozone concentrations during 24 February 2008.

  20. Temperature and concentration stratification effects on non-Newtonian fluid flow past a cylindrical surface

    Science.gov (United States)

    Rehman, Khalil Ur; Khan, Abid Ali; Malik, M. Y.; Zehra, Iffat; Ali, Usman

    The theme of present work is to report the numerical solution of mixed convection tangent hyperbolic fluid flow towards stretching cylindrical surface immersed in a double stratified media. The fluid flow is attained through no slip condition. The flow regime characteristics are modelled in terms of partial differential equations. A similarity transformation is used to transform partial differential equations into coupled non-linear ordinary differential equations. A computational algorithm is executed to predict numerical results. The effects of flow controlling parameters namely, mixed convection parameter, thermal stratification and solutal stratification parameters on velocity, temperature and concentration are examined and offered by means of graphical outcomes. It is noticed that in the presence of mixed convection effect both the fluid temperature and concentration are decreasing function of thermal stratification and solutal stratification parameters respectively. The obtained values are certified by developing comparison with existing values and an excellent agreement is observed which confirms the execution of computational algorithm.

  1. Estimating sub-surface dispersed oil concentration using acoustic backscatter response.

    Science.gov (United States)

    Fuller, Christopher B; Bonner, James S; Islam, Mohammad S; Page, Cheryl; Ojo, Temitope; Kirkey, William

    2013-05-15

    The recent Deepwater Horizon disaster resulted in a dispersed oil plume at an approximate depth of 1000 m. Several methods were used to characterize this plume with respect to concentration and spatial extent including surface supported sampling and autonomous underwater vehicles with in situ instrument payloads. Additionally, echo sounders were used to track the plume location, demonstrating the potential for remote detection using acoustic backscatter (ABS). This study evaluated use of an Acoustic Doppler Current Profiler (ADCP) to quantitatively detect oil-droplet suspensions from the ABS response in a controlled laboratory setting. Results from this study showed log-linear ABS responses to oil-droplet volume concentration. However, the inability to reproduce ABS response factors suggests the difficultly in developing meaningful calibration factors for quantitative field analysis. Evaluation of theoretical ABS intensity derived from the particle size distribution provided insight regarding method sensitivity in the presence of interfering ambient particles. Copyright © 2013 Elsevier Ltd. All rights reserved.

  2. Measurement of the radon exhalation rate from the medium surface by tracing the radon concentration

    International Nuclear Information System (INIS)

    Yanliang Tan; Detao Xiao

    2013-01-01

    The paper will present a method based on the accumulation chamber technique for measuring of radon exhalation from the medium surface. A radon monitor traces the change of radon concentration in the accumulation chamber, and then the radon exhalation can be obtained accurately through linear fit. Based on our recent experiments, the radon exhalation rate from the medium surface obtained from this method is in good agreement with the actual exhalation rate of our simulation facility. This method is superior to the competition method which obtains the radon exhalation through the exponential fit by an external PC-system. The calculation for the exponential fit is very easy by computer and related software. However, for portable instruments, the single chip microcomputer can't calculate the exponential fit rapidly. Thus, this method is usable for developing the new portable instrument to classify building materials, etc. (author)

  3. The measurement of the isotope ratios and concentrations of zinc by thermal ionization mass spectrometry using double isotope dilution

    International Nuclear Information System (INIS)

    Deng Zhongguo

    1994-01-01

    The isotope ratios and concentrations of zinc are measured by silicagel-thermal ionization mass spectrometry using the double isotope spikers. The double isotope spikers ( 70 Zn and 67 Zn-enriched isotopes) are used to correct the isotope mass fractionation for the zinc isotope ratios, and to certify the zinc concentrations in the unknown samples. The zinc concentrations of these double isotope spikers are surveyed by a spiker made of pure (99.99%) natural zinc metal powder. The correcting factors (f a , f t and f n ) of the zinc isotope ratios in the spiked mixture, spike and unspiked samples for the isotope mass fractionation, and the spike-to-unspiked ratios (X r ) of the zinc isotope r in the spiked mixture samples can be obtained to solve the matrix equations by numerical approximation. The natural zinc isotope ratios are: 64 Zn/ 67 Zn = 11.8498, 66 Zn/ 67 Zn = 6.7977, 68 Zn/ 67 Zn = 4.5730 and 70 Zn/ 67 Zn = 0.1520. The uncertainties determined of the isotope ratios and concentrations of zinc are +- 0.16% and +-0.31%, respectively

  4. Comparison of Respirable Mass Concentrations Measured by a Personal Dust Monitor and a Personal DataRAM to Gravimetric Measurements.

    Science.gov (United States)

    Halterman, Andrew; Sousan, Sinan; Peters, Thomas M

    2017-12-15

    In 2016, the Mine Safety and Health Administration required the use of continuous monitors to measure respirable dust in mines and better protect miner health. The Personal Dust Monitor, PDM3700, has met stringent performance criteria for this purpose. In a laboratory study, respirable mass concentrations measured with the PDM3700 and a photometer (personal DataRam, pDR-1500) were compared to those measured gravimetrically for five aerosols of varying refractive index and density (diesel exhaust fume, welding fume, coal dust, Arizona road dust (ARD), and salt [NaCl] aerosol) at target concentrations of 0.38, 0.75, and 1.5 mg m-3. For all aerosols except coal dust, strong, near-one-to-one, linear relationships were observed between mass concentrations measured with the PDM3700 and gravimetrically (diesel fume, slope = 0.99, R2 = 0.99; ARD, slope = 0.98, R2 = 0.99; and NaCl, slope = 0.95, R2 = 0.99). The slope deviated substantially from unity for coal dust (slope = 0.55; R2 = 0.99). Linear relationships were also observed between mass concentrations measured with the pDR-1500 and gravimetrically, but one-to-one behavior was not exhibited (diesel fume, slope = 0.23, R2 = 0.76; coal dust, slope = 0.54, R2 = 0.99; ARD, slope = 0.61, R2 = 0.99; NaCl, slope = 1.14, R2 = 0.98). Unlike the pDR-1500, mass concentrations measured with the PDM3700 appear independent of refractive index and density, suggesting that it could have applications in a variety of occupational settings. © The Author(s) 2017. Published by Oxford University Press on behalf of the British Occupational Hygiene Society.

  5. Mass spectrometric investigation of synthetic glycoside of muramyl dipeptide immobilized on fumed silica surface

    International Nuclear Information System (INIS)

    Kulik, Tetiana V.; Azizova, Liana R.; Palyanytsya, Borys B.; Zemlyakov, Alexander E.; Tsikalova, Victoria N.

    2010-01-01

    N-Acetylmuramyl-L-alanyl-D-isoglutamine or muramyl dipeptide is a cleavage product of peptidoglycan by lysozyme. This study explored the use of the temperature-programmed desorption mass spectrometry (TPDMS) in analysis of glycoside of muramyl dipeptide: O-{(4-tert-butylcyclohexyl)-2-acetamido-2, 3-dideoxy-β-D-glucopyranoside-3-yl}-D-lactoyl-L-alanyl-D-isoglutamine (MDP) on the surface of fumed silica. Stages of pyrolysis of MDP in condensed state and on the silica surface have been determined. Three stages have been clear identified under pyrolysis of MDP on the silica surface. Kinetic parameters of thermal reactions on the fumed silica surface and in the condensed state have been calculated.

  6. Reducing surface water total and methyl mercury concentrations and bioavailability using a coagulation-wetland system

    Science.gov (United States)

    Kraus, T. E.; Fleck, J.; Henneberry, Y. K.; Stumpner, E. B.; Krabbenhoft, D. P.; Bachand, P.; Randall, P.

    2013-12-01

    With the recent passage of laws regulating concentrations and loads of mercury (Hg) in surface waters, there is a need to develop management practices that will reduce the export of Hg from both point and non-point sources. Coagulation with metal based salts to remove particles and dissolved organic matter (DOM) from solution is a practice commonly employed by drinking water utilities. Because dissolved Hg is associated with particles and DOM, it follows that Hg should also be removed during the coagulation process and end up associated with the organo-metal precipitate, termed flocculate (floc). The effectiveness of iron- and aluminum-based coagulants for removing both inorganic and methyl mercury (IHg and MeHg, respectively) from solution was demonstrated in laboratory studies conducted on agricultural drainage waters of the Sacramento-San Joaquin Delta: dissolved concentrations of MeHg decreased by 80% while IHg decreased by 97% following coagulation. To test the field application of this technology, samples were collected from the inflows and outflows of wetland treatment cells constructed in the central Delta of California. This replicated field experiment includes three replicates each of three inflow waters treatments: (1) iron sulfate addition, (2) polyaluminum chloride addition, and (3) untreated controls. Water entering and exiting the nine treatment cells was sampled approximately monthly over a 1-year period for total Hg and MeHg in both the dissolved and particulate aqueous phases. Initial results confirm that coagulant addition is removing Hg (total and methyl, particulate and dissolved) from solution and sequestering it in the floc. Seasonal effects on DOM concentration and other factors appear to effect whether passage through the wetland cells alters surface water dissolved organic carbon (DOC) and Hg concentrations. Related studies will examine whether the presence of the floc affects the production and fate of MeHg within the wetland cells. If

  7. X-ray overluminous elliptical galaxies: A new class of mass concentrations in the universe?

    DEFF Research Database (Denmark)

    Vikhlinin, A.; McNamara, B.R.; Hornstrup, Allan

    1999-01-01

    density of OLEGs is n = 2.4(-1.2)(+3.1) x 10(-7) (h/0.5)(-3) Mpc(-3) at the 90% confidence level. They comprise 20% of all clusters and groups of comparable X-ray luminosity, and nearly all field galaxies brighter than M-R = -22.5. The estimated contribution of OLEGs to the total mass density......We detect four isolated, X-ray overluminous [L-x > 2 x 10(43) (h/0.5)(-2) ergs s(-1)] elliptical galaxies (OLEGs) in our 160 deg(2) ROSAT PSPC survey. The extent of their X-ray emission, total X-ray luminosity, total mass, and mass of the hot gas in these systems corresponds to poor clusters......, and the optical luminosity of the central galaxies (M-Rmass-to-light ratio within the radius of detectable X-ray emission...

  8. Polymethyl methacrylate-co-methacrylic acid coatings with controllable concentration of surface carboxyl groups: A novel approach in fabrication of polymeric platforms for potential bio-diagnostic devices

    Energy Technology Data Exchange (ETDEWEB)

    Hosseini, Samira; Ibrahim, Fatimah [Center for Innovation in Medical Engineering, Department of Biomedical Engineering, Faculty of Engineering, University of Malaya, Kuala Lumpur 50603 (Malaysia); Djordjevic, Ivan, E-mail: ivan.djordjevic@um.edu.my [Center for Innovation in Medical Engineering, Department of Biomedical Engineering, Faculty of Engineering, University of Malaya, Kuala Lumpur 50603 (Malaysia); Koole, Leo H. [Center for Innovation in Medical Engineering, Department of Biomedical Engineering, Faculty of Engineering, University of Malaya, Kuala Lumpur 50603 (Malaysia); Department of Biomedical Engineering, Faculty of Health. Medicine and Life Science, Maastricht University, PO Box 616, NL 6200 MD Maastricht (Netherlands)

    2014-05-01

    Highlights: • Synthesis and processing of PMMA-co-MAA spin-coatings on silicon wafers. • Surface chemistry and morphology as a function of tailored co-polymer structure. • Polymer coatings with controlled number of surface carboxyl groups. - Abstract: The generally accepted strategy in development of bio-diagnostic devices is to immobilize proteins on polymeric surfaces as a part of detection process for diseases and viruses through antibody/antigen coupling. In that perspective, polymer surface properties such as concentration of functional groups must be closely controlled in order to preserve the protein activity. In order to improve the surface characteristics of transparent polymethacrylate plastics that are used for diagnostic devices, we have developed an effective fabrication procedure of polymethylmetacrylate-co-metacrylic acid (PMMA-co-MAA) coatings with controlled number of surface carboxyl groups. The polymers were processed effectively with the spin-coating technique and the detailed control over surface properties is here by demonstrated through the variation of a single synthesis reaction parameter. The chemical structure of synthesized and processed co-polymers has been investigated with nuclear magnetic resonance spectroscopy (NMR) and matrix-assisted laser desorption time-of-flight mass spectrometry (MALDI-ToF-MS). The surface morphology of polymer coatings have been analyzed with atomic force microscopy (AFM) and scanning electron microscopy (SEM). We demonstrate that the surface morphology and the concentration of surface –COOH groups (determined with UV–vis surface titration) on the processed PMMA-co-MAA coatings can be precisely controlled by variation of initial molar ratio of reactants in the free-radical polymerization reaction. The wettability of developed polymer surfaces also varies with macromolecular structure.

  9. Aerosol mass and black carbon concentrations, a two year record at NCO-P (5079 m, Southern Himalayas

    Directory of Open Access Journals (Sweden)

    A. Marinoni

    2010-09-01

    Full Text Available Aerosol mass and the absorbing fraction are important variables, needed to constrain the role of atmospheric particles in the Earth radiation budget, both directly and indirectly through CCN activation. In particular, their monitoring in remote areas and mountain sites is essential for determining source regions, elucidating the mechanisms of long range transport of anthropogenic pollutants, and validating regional and global models. Since March 2006, aerosol mass and black carbon concentration have been monitored at the Nepal Climate Observatory-Pyramid, a permanent high-altitude research station located in the Khumbu valley at 5079 m a.s.l. below Mt. Everest. The first two-year averages of PM1 and PM1−10 mass were 1.94 μg m−3 and 1.88 μg m−3, with standard deviations of 3.90 μg m−3 and 4.45 μg m−3, respectively, while the black carbon concentration average is 160.5 ng m−3, with a standard deviation of 296.1 ng m−3. Both aerosol mass and black carbon show well defined annual cycles, with a maximum during the pre-monsoon season and a minimum during the monsoon. They also display a typical diurnal cycle during all the seasons, with the lowest particle concentration recorded during the night, and a considerable increase during the afternoon, revealing the major role played by thermal winds in influencing the behaviour of atmospheric compounds over the high Himalayas. The aerosol concentration is subject to high variability: in fact, as well as frequent "background conditions" (55% of the time when BC concentrations are mainly below 100 ng m−3, concentrations up to 5 μg m−3 are reached during some episodes (a few days every year in the pre-monsoon seasons. The variability of PM and BC is the result of both short-term changes due to thermal wind development in the valley, and long-range transport/synoptic circulation

  10. Mass spectrometric analysis of illicit drugs in wastewater and surface water.

    Science.gov (United States)

    Castiglioni, Sara; Zuccato, Ettore; Chiabrando, Chiara; Fanelli, Roberto; Bagnati, Renzo

    2008-01-01

    Residues of illicit drugs have been recently found in urban wastewater and surface water. Their levels reflect the amount of drugs collectively excreted by consumers and can therefore be used to estimate drug abuse. An overview of the most widely used illicit drugs and of the analytical methods used for their detection in wastewater and surface water is presented here. Solid-phase extraction and high performance liquid chromatography-tandem mass spectrometry are the techniques that have been used for these investigations. Instrumental conditions and fragmentation patterns of illicit drugs and their metabolites are described. (c) 2008 Wiley Periodicals, Inc.

  11. Re-discovering surface mass spectrometry: chemical mapping from micro to macro

    International Nuclear Information System (INIS)

    Lloyd, K.G.; O'Keefe, D.P.

    2004-01-01

    New developments in electronics, devices, micro-encapsulation, and other areas demand the ability to acquire molecularly-specific information from smaller and smaller features. ToF-SIMS provides molecularly-specific mass spectral data, but sufficient high-mass signal has historically been difficult to obtain from organic/polymeric surfaces in the point-mapping mode of operation. Use of chemometric data reduction methods and the development of heavier primary ion sources enhance and extend the chemical information in the mapping data. Large-area chemical mapping via sample stage rastering has also opened up new applications. This capability allows single-experiment mapping of large or multiple features, provides information on surface uniformity over end-use-relevant areas, and offers potential for combinatorial and other screening applications. Examples of these applications are presented

  12. Atmospheric pressure surface sampling/ionization techniques for direct coupling of planar separations with mass spectrometry.

    Science.gov (United States)

    Pasilis, Sofie P; Van Berkel, Gary J

    2010-06-18

    Planar separations, which include thin layer chromatography and gel electrophoresis, are in widespread use as important and powerful tools for conducting separations of complex mixtures. To increase the utility of planar separations, new methods are needed that allow in situ characterization of the individual components of the separated mixtures. A large number of atmospheric pressure surface sampling and ionization techniques for use with mass spectrometry have emerged in the past several years, and several have been investigated as a means for mass spectrometric read-out of planar separations. In this article, we review the atmospheric pressure surface sampling and ionization techniques that have been used for the read-out of planar separation media. For each technique, we briefly explain the operational basics and discuss the analyte type for which it is appropriate and some specific applications from the literature. Copyright (c) 2010 Elsevier B.V. All rights reserved.

  13. Laser-based mass spectrometry for in situ chemical composition analysis of planetary surfaces

    Science.gov (United States)

    Frey, Samira; Neuland, Maike B.; Grimaudo, Valentine; Moreno-García, Pavel; Riedo, Andreas; Tulej, Marek; Broekmann, Peter; Wurz, Peter

    2016-04-01

    Mass spectrometry is an important analytical technique in space research. The chemical composition of planetary surface material is a key scientific question on every space mission to a planet, moon or asteroid. Chemical composition measurements of rocky material on the surface are of great importance to understand the origin and evolution of the planetary body.[1] A miniature laser ablation/ionisation reflectron- type time-of-flight mass spectrometer (instrument name LMS) was designed and built at the University of Bern for planetary research.[2] Despite its small size and light weight, the LMS instrument still maintains the same capabilities as large laboratory systems, which makes it suitable for its application on planetary space missions.[3-5] The high dynamic range of about eight orders of magnitude, high lateral (μm-level) and vertical (sub-nm level) resolution and high detection sensitivity for almost all elements (10 ppb, atomic fraction) make LMS a versatile instrument for various applications. LMS is a suitable instrument for in situ measurements of elemental and isotope composition with high precision and accuracy. Measurements of Pb- isotope abundances can be used for dating of planetary material. Measurements of bio-relevant elements allow searching for past or present life on a planetary surface. The high spatial resolution, both in lateral and vertical direction, is of considerable interest, e.g. for analysis of inhomogeneous, extraterrestrial samples as well as weathering processes of planetary material. References [1] P. Wurz, D. Abplanalp, M. Tulej, M. Iakovleva, V.A. Fernandes, A. Chumikov, and G. Managadze, "Mass Spectrometric Analysis in Planetary Science: Investigation of the Surface and the Atmosphere", Sol. Sys. Res., 2012, 46, 408. [2] U. Rohner, J.A. Whitby, P. Wurz, "A miniature laser ablation time of flight mass spectrometer for in situ planetary exploration" Meas. Sci. Tch., 2003, 14, 2159. [3] M. Tulej, A. Riedo, M.B. Neuland, S

  14. Quantitative Caffeine Analysis Using a Surface Sampling Probe Electrospray Ionization Tandem Mass Spectrometry System

    Energy Technology Data Exchange (ETDEWEB)

    Ford, Michael J [ORNL; Deibel, Michael A. [Earlham College; Tomkins, Bruce A [ORNL; Van Berkel, Gary J [ORNL

    2005-01-01

    Quantitative determination of caffeine on reversed-phase C8 thin-layer chromatography plates using a surface sampling electrospray ionization system with tandem mass spectrometry detection is reported. The thin-layer chromatography/electrospray tandem mass spectrometry method employed a deuterium-labeled caffeine internal standard and selected reaction monitoring detection. Up to nine parallel caffeine bands on a single plate were sampled in a single surface scanning experiment requiring 35 min at a surface scan rate of 44 {mu}m/s. A reversed-phase HPLC/UV caffeine assay was developed in parallel to assess the mass spectrometry method performance. Limits of detection for the HPLC/UV and thin-layer chromatography/electrospray tandem mass spectrometry methods determined from the calibration curve statistics were 0.20 ng injected (0.50 {mu}L) and 1.0 ng spotted on the plate, respectively. Spike recoveries with standards and real samples ranged between 97 and 106% for both methods. The caffeine content of three diet soft drinks (Diet Coke, Diet Cherry Coke, Diet Pepsi) and three diet sport drinks (Diet Turbo Tea, Speed Stack Grape, Speed Stack Fruit Punch) was measured. The HPLC/UV and mass spectrometry determinations were in general agreement, and these values were consistent with the quoted values for two of the three diet colas. In the case of Diet Cherry Coke and the diet sports drinks, the determined caffeine amounts using both methods were consistently higher (by 8% or more) than the literature values.

  15. Stark effect of excitons in corrugated lateral surface superlattices: effect of centre-of-mass quantization

    International Nuclear Information System (INIS)

    Hong Sun

    1998-11-01

    The quantum confined Stark effect (QCSE) of excitons in GaAs/AlAs corrugated lateral surface superlattices (CLSSLs) is calculated. Blue and red shifts in the exciton energies are predicted for the heavy- and light-excitons in the CLSSLs, respectively, comparing with those in the unmodulated quantum well due to the different effective hole masses in the parallel direction. Sensitive dependence of the QCSE on the hole effective mass in the parallel direction is expected because of the ''centre-of-mass'' quantization (CMQ) induced by the periodic corrugated interfaces of the CLSSLs. The effect of the CMQ on the exciton mini-bands and the localization of the excitons in the CLSSLs is discussed. (author)

  16. Fine and Coarse Particle Mass Concentrations and Emission Rates in the Workplace of a Detergent Industry

    Czech Academy of Sciences Publication Activity Database

    Glytsos, T.; Ondráček, Jakub; Džumbová, Lucie; Eleftheriadis, K.; Lazaridis, M.

    2014-01-01

    Roč. 23, č. 6 (2014), s. 881-889 ISSN 1420-326X Institutional support: RVO:67985858 Keywords : emission rates * PM 10 * PM2,5 * mass balance model Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 1.225, year: 2014

  17. Detection of alkylmethylphosphonic acids on leaf surfaces by static secondary ion mass spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Ingram, J.C.; Groenewold, G.S.; Appelhans, A.D.; Delmore, J.E.; Dahl, D.A. (Idaho National Engineering Lab., Idaho Falls, ID (United States))

    1995-01-01

    Detection of environmental degradation products of nerve agents directly from the surface of plant leaves using static secondary ion mass spectrometry (SIMS) is demonstrated. Pinacolylmethylphosphonic acid (PMPA), isopropylmethylphosphonic acid (IMPA), and ethylmethylphosphonic acid (EMPA) were spiked from aqueous solutions onto philodendron leaves prior to analysis by static SIMS. Fragment ions were observed in the anion SIMS spectra from all three compounds at m/z 63, 77, 79, and 95, which are attributed to PO[sub 2][sup [minus

  18. Ambient mass spectrometry: From the planar to the non-planar surface analysis

    Czech Academy of Sciences Publication Activity Database

    Rejšek, Jan; Vrkoslav, Vladimír; Cvačka, Josef

    2017-01-01

    Roč. 15, č. 1 (2017), s. 31 ISSN 2336-7202. [Mezioborové setkání mladých biologů, biochemiků a chemiků /17./. 30.05.2017-01.06.2017, Milovy] Institutional support: RVO:61388963 Keywords : ambient mass spectrometry * thin layer chromatography * non-planar surface analysis Subject RIV: CB - Analytical Chemistry, Separation

  19. Protein surface topology-probing by selective chemical modification and mass spectrometric peptide mapping.

    OpenAIRE

    Suckau, D; Mak, M; Przybylski, M

    1992-01-01

    Aminoacetylation of lysine residues and the modification of arginine by 1,2-cyclohexanedione to N7,N8-(dihydroxy-1,2-cyclohexylidene)arginine were used for probing the surface topology of hen-eggwhite lysozyme as a model protein. The molecular identification of lysine and arginine modification sites was provided by molecular weight determinations of modified and unmodified tryptic peptide mixtures (peptide mapping) using 252Cf plasma desorption mass spectrometry. At conditions of limited chem...

  20. The impact of anthropogenic and biogenic emissions on surface ozone concentrations in Istanbul.

    Science.gov (United States)

    Im, Ulas; Poupkou, Anastasia; Incecik, Selahattin; Markakis, Konstantinos; Kindap, Tayfun; Unal, Alper; Melas, Dimitros; Yenigun, Orhan; Topcu, Sema; Odman, M Talat; Tayanc, Mete; Guler, Meltem

    2011-03-01

    Surface ozone concentrations at Istanbul during a summer episode in June 2008 were simulated using a high resolution and urban scale modeling system coupling MM5 and CMAQ models with a recently developed anthropogenic emission inventory for the region. Two sets of base runs were performed in order to investigate for the first time the impact of biogenic emissions on ozone concentrations in the Greater Istanbul Area (GIA). The first simulation was performed using only the anthropogenic emissions whereas the second simulation was performed using both anthropogenic and biogenic emissions. Biogenic NMVOC emissions were comparable with anthropogenic NMVOC emissions in terms of magnitude. The inclusion of biogenic emissions significantly improved the performance of the model, particularly in reproducing the low night time values as well as the temporal variation of ozone concentrations. Terpene emissions contributed significantly to the destruction of the ozone during nighttime. Biogenic NMVOCs emissions enhanced ozone concentrations in the downwind regions of GIA up to 25ppb. The VOC/NO(x) ratio almost doubled due to the addition of biogenic NMVOCs. Anthropogenic NO(x) and NMVOCs were perturbed by ±30% in another set of simulations to quantify the sensitivity of ozone concentrations to the precursor emissions in the region. The sensitivity runs, as along with the model-calculated ozone-to-reactive nitrogen ratios, pointed NO(x)-sensitive chemistry, particularly in the downwind areas. On the other hand, urban parts of the city responded more to changes in NO(x) due to very high anthropogenic emissions. Copyright © 2010 Elsevier B.V. All rights reserved.

  1. Effects of trans-Eurasian transport of anthropogenic pollutants on surface ozone concentrations over China

    Science.gov (United States)

    Liu, J.; Li, X.; Mauzerall, D. L.; Emmons, L. K.; Horowitz, L. W.; Guo, Y.; Tao, S.

    2015-12-01

    Due to a lack of industrialization in Western China, surface air there was, until recently, believed to be relatively unpolluted. However, recent measurements and modeling studies have found high levels of ozone (O3) there. Based on the state-of-the-science global chemical transport model MOZART-4, we identify the origin, pathway, and mechanism of trans-Eurasian transport of air pollutants to Western China in 2000. MOZART-4 generally simulates well the observed surface O3 over inland areas of China. Simulations find surface ozone concentrations over Western China on average to be about 10 ppbv higher than Eastern China. Using sensitivity studies as well as a fully-tagged approach, we find that anthropogenic emissions from all Eurasian regions except China contribute 10-15 ppbv surface O3 over Western China, superimposed upon a 35-40 ppbv natural background. Transport from European anthropogenic sources to Northwestern China results in 2-6 ppbv O3 enhancements in spring and summer. Indian anthropogenic sources strongly influence O3 over the Tibetan Plateau during the summer monsoon. Transport of O3 originating from emissions in the Middle East occasionally reach Western China and increase surface ozone there by about 1-4 ppbv. These influences are of similar magnitude as trans-Pacific and transatlantic transport of O3 and its precursors, indicating the significance of trans-Eurasian ozone transport in hemispheric transport of air pollution. Our study further indicates that mitigation of anthropogenic emissions from Europe, the Indian subcontinent, and the Middle East could benefit public health and agricultural productivity in Western China.

  2. Winter mass concentrations of carbon species in PM10, PM 2.5 and PM1 in Zagreb air, Croatia.

    Science.gov (United States)

    Godec, Ranka; Čačković, Mirjana; Šega, Krešimir; Bešlić, Ivan

    2012-11-01

    The purpose of our investigation was to examine the mass concentrations of EC, OC and TC (EC + OC) in PM(10), PM(2.5) and PM(1) particle fractions. Daily PM(10), PM(2.5) and PM(1) samples were collected at an urban background monitoring site in Zagreb during winter 2009. Average OC and EC mass concentrations were 11.9 and 1.8 μg m(-3) in PM(10), 9.0 and 1.4 μg m(-3) in PM(2.5), and 5.5 and 1.1 μg m(-3) in PM(1). Average OC/EC ratios in PM(10), PM(2.5), and PM(1) were 7.4, 6.9 and 5.4, respectively.

  3. Determinants of black carbon, particle mass and number concentrations in London transport microenvironments

    Science.gov (United States)

    Rivas, Ioar; Kumar, Prashant; Hagen-Zanker, Alex; Andrade, Maria de Fatima; Slovic, Anne Dorothee; Pritchard, John P.; Geurs, Karst T.

    2017-07-01

    We investigated the determinants of personal exposure concentrations of commuters' to black carbon (BC), ultrafine particle number concentrations (PNC), and particulate matter (PM1, PM2.5 and PM10) in different travel modes. We quantified the contribution of key factors that explain the variation of the previous pollutants in four commuting routes in London, each covered by four transport modes (car, bus, walk and underground). Models were performed for each pollutant, separately to assess the effect of meteorology (wind speed) or ambient concentrations (with either high spatial or temporal resolution). Concentration variations were mainly explained by wind speed or ambient concentrations and to a lesser extent by route and period of the day. In multivariate models with wind speed, the wind speed was the common significant predictor for all the pollutants in the above-ground modes (i.e., car, bus, walk); and the only predictor variable for the PM fractions. Wind speed had the strongest effect on PM during the bus trips, with an increase in 1 m s-1 leading to a decrease in 2.25, 2.90 and 4.98 μg m-3 of PM1, PM2.5 and PM10, respectively. PM2.5 and PM10 concentrations in car trips were better explained by ambient concentrations with high temporal resolution although from a single monitoring station. On the other hand, ambient concentrations with high spatial coverage but lower temporal resolution predicted better the concentrations in bus trips, due to bus routes passing through streets with a high variability of traffic intensity. In the underground models, wind speed was not significant and line and type of windows on the train explained 42% of the variation of PNC and 90% of all PM fractions. Trains in the district line with openable windows had an increase in concentrations of 1 684 cm-3 for PNC and 40.69 μg m-3 for PM2.5 compared with trains that had non-openable windows. The results from this work can be used to target efforts to reduce personal exposures of

  4. Mechanical Q-factor measurements on a test mass with a structured surface

    Energy Technology Data Exchange (ETDEWEB)

    Nawrodt, R [Institut fuer Festkoerperphysik, Friedrich-Schiller-Universitaet Jena, Helmholtzweg 5, D-07743 Jena (Germany); Zimmer, A [Institut fuer Festkoerperphysik, Friedrich-Schiller-Universitaet Jena, Helmholtzweg 5, D-07743 Jena (Germany); Koettig, T [Institut fuer Festkoerperphysik, Friedrich-Schiller-Universitaet Jena, Helmholtzweg 5, D-07743 Jena (Germany); Clausnitzer, T [Institut fuer Angewandte Physik, Friedrich-Schiller-Universitaet Jena, Max-Wien-Platz 1, D-07743 Jena (Germany); Bunkowski, A [Max-Planck-Institut fuer Gravitationsphysik (Albert-Einstein-Institut) and Institut fuer Gravitationsphysik, Leibniz Universitaet Hannover, Callinstr. 38, D-30167 Hannover (Germany); Kley, E B [Institut fuer Angewandte Physik, Friedrich-Schiller-Universitaet Jena, Max-Wien-Platz 1, D-07743 Jena (Germany); Schnabel, R [Max-Planck-Institut fuer Gravitationsphysik (Albert-Einstein-Institut) and Institut fuer Gravitationsphysik, Leibniz Universitaet Hannover, Callinstr. 38, D-30167 Hannover (Germany); Danzmann, K [Max-Planck-Institut fuer Gravitationsphysik (Albert-Einstein-Institut) and Institut fuer Gravitationsphysik, Leibniz Universitaet Hannover, Callinstr. 38, D-30167 Hannover (Germany); Nietzsche, S [Institut fuer Festkoerperphysik, Friedrich-Schiller-Universitaet Jena, Helmholtzweg 5, D-07743 Jena (Germany); Vodel, W [Institut fuer Festkoerperphysik, Friedrich-Schiller-Universitaet Jena, Helmholtzweg 5, D-07743 Jena (Germany); Tuennermann, A [Institut fuer Angewandte Physik, Friedrich-Schiller-Universitaet Jena, Max-Wien-Platz 1, D-07743 Jena (Germany); Seidel, P [Institut fuer Festkoerperphysik, Friedrich-Schiller-Universitaet Jena, Helmholtzweg 5, D-07743 Jena (Germany)

    2007-07-15

    We present mechanical Q-factors (quality factors) of a crystalline quartz test mass with a nano-structured surface, measured in the temperature regime from 5 to 300 K. The nano-structure was a grating with a period of 2 {mu}m and a depth of about 0.1 {mu}m. Comparative measurements were performed on the plain substrate and on the structured test mass with different numbers of SiO{sub 2}/Ta{sub 2}O{sub 5} coating layers. The measurements at different stages of the test mass fabrication process show that the surface distortion induced by the nanostructure does not severely lower the mechanical Q-factor of the substrate. Damping due to a multi-layer coating stack was found to be orders of magnitude higher. The results provide vital information concerning the potential usage of low-thermal noise nano-structured test masses in future generations of high-precision laser interferometers and in current attempts to measure quantum effects of macroscopic mirror oscillators.

  5. Investigation into Mass Loading Sensitivity of Sezawa Wave Mode-Based Surface Acoustic Wave Sensors

    Directory of Open Access Journals (Sweden)

    N. Ramakrishnan

    2013-02-01

    Full Text Available In this work mass loading sensitivity of a Sezawa wave mode based surface acoustic wave (SAW device is investigated through finite element method (FEM simulation and the prospects of these devices to function as highly sensitive SAW sensors is reported. A ZnO/Si layered SAW resonator is considered for the simulation study. Initially the occurrence of Sezawa wave mode and displacement amplitude of the Rayleigh and Sezawa wave mode is studied for lower ZnO film thickness. Further, a thin film made of an arbitrary material is coated over the ZnO surface and the resonance frequency shift caused by mass loading of the film is estimated. It was observed that Sezawa wave mode shows significant sensitivity to change in mass loading and has higher sensitivity (eight times higher than Rayleigh wave mode for the same device configuration. Further, the mass loading sensitivity was observed to be greater for a low ZnO film thickness to wavelength ratio. Accordingly, highly sensitive SAW sensors can be developed by coating a sensing medium over a layered SAW device and operating at Sezawa mode resonance frequency. The sensitivity can be increased by tuning the ZnO film thickness to wavelength ratio.

  6. Secondary ion mass spectrometric signal enhancement of phosphatidylcholine dioleoyl on enlarged nanoparticles surface

    Energy Technology Data Exchange (ETDEWEB)

    Gulin, A. [N.N. Semenov Institute of Chemical Physics, RAS, Kosigin str. 4, Moscow 119991 (Russian Federation); Mochalova, M. [Moscow Institute of Physics and Technology, Institutskii per. 9, Dolgoprudny, Moscow 141700 (Russian Federation); Denisov, N. [Institute of Problem of Chemical Physics, RAS, Semenov av. 1, Chernogolovka, 142432 (Russian Federation); Nadtochenko, V., E-mail: nadtochenko@gmail.com [N.N. Semenov Institute of Chemical Physics, RAS, Kosigin str. 4, Moscow 119991 (Russian Federation); Moscow Institute of Physics and Technology, Institutskii per. 9, Dolgoprudny, Moscow 141700 (Russian Federation); Institute of Problem of Chemical Physics, RAS, Semenov av. 1, Chernogolovka, 142432 (Russian Federation)

    2014-10-15

    Graphical abstract: - Highlights: • TOF-SIMS mass-spectra of DOPC lipid on enlarged nanoparticles surface were studied. • Metallic, semiconductor, dielectric and hybrid nanoparticles were examined. • Effect of nanoparticles on mass-spectral peaks intensity was investigated. • The highest signal enhancement of 42 times was found for hybrid core–shell Au/SiO{sub 2} nanoparticles. - Abstract: A silicon wafer surface coverage of nanoparticles (NPs) can enhance the L-α-phosphatidylcholine dioleoyl (DOPC) signal intensity in time-of-flight secondary ion mass spectrometry (TOF-SIMS). A ToF-SIMS mass spectrometer was used with a pulsed primary beam of focused 30 keV Bi{sub 3}{sup +} ions. The signal enhancing effect has been studied for metallic (Ag, Au, Pb), semiconductor (TiO{sub 2}), dielectric (SiO{sub 2}) and hybrid (Au/TiO{sub 2}NPs, core–shell Au/SiO{sub 2}) nanoparticles. Ag NPs can attenuate secondary ions signal, whereas all other studied NPs show the signal enhancement. The emission of DOPC lipid secondary ions immobilized on core–shell Au/SiO{sub 2}NPs was enhanced up to 42 times. This technique is a simple preparatory method enabling an overall increase in molecular lipid ions.

  7. Secondary ion mass spectrometric signal enhancement of phosphatidylcholine dioleoyl on enlarged nanoparticles surface

    International Nuclear Information System (INIS)

    Gulin, A.; Mochalova, M.; Denisov, N.; Nadtochenko, V.

    2014-01-01

    Graphical abstract: - Highlights: • TOF-SIMS mass-spectra of DOPC lipid on enlarged nanoparticles surface were studied. • Metallic, semiconductor, dielectric and hybrid nanoparticles were examined. • Effect of nanoparticles on mass-spectral peaks intensity was investigated. • The highest signal enhancement of 42 times was found for hybrid core–shell Au/SiO 2 nanoparticles. - Abstract: A silicon wafer surface coverage of nanoparticles (NPs) can enhance the L-α-phosphatidylcholine dioleoyl (DOPC) signal intensity in time-of-flight secondary ion mass spectrometry (TOF-SIMS). A ToF-SIMS mass spectrometer was used with a pulsed primary beam of focused 30 keV Bi 3 + ions. The signal enhancing effect has been studied for metallic (Ag, Au, Pb), semiconductor (TiO 2 ), dielectric (SiO 2 ) and hybrid (Au/TiO 2 NPs, core–shell Au/SiO 2 ) nanoparticles. Ag NPs can attenuate secondary ions signal, whereas all other studied NPs show the signal enhancement. The emission of DOPC lipid secondary ions immobilized on core–shell Au/SiO 2 NPs was enhanced up to 42 times. This technique is a simple preparatory method enabling an overall increase in molecular lipid ions

  8. Study of the interaction of liquid with the surface of mass standards of high accuracy stainless steel

    International Nuclear Information System (INIS)

    Ramirez Varas, Lautaro; Castro, Claudio S.C.; Cacais, Fabio L.; Pires, Manoel J. M.; Loayza Mendoza, Victor M.

    2011-01-01

    The long term stability of mass standards depends on the interaction between the surface and environment molecules. From this point of view, a study was investigated of the effect on stainless steel surfaces by liquids frequently used in hydrostatic weighing (FC40) and in cleaning procedures of mass standards (isopropyl alcohol). Firstly, mass weighing difference was measured as function of time with a gravimetric method. Additionally, stainless steel samples were analyzed by X-ray Photoelectron Spectroscopy (XPS). The standard used for the gravimetric mass difference determination was immersed in FC40. The samples analyzed by XPS were previously immersed in both FC40 and isopropyl alcohol. Mass differences were obtained with an uncertainty of 1 μg when FC40 was used. Preliminary results have suggested that FC40 is not chemically bound to stainless steel surfaces and the mass gain was due to physisorbed molecules on the surface. (author) [es

  9. Contribution from indoor sources to particle number and mass concentrations in residential houses

    Science.gov (United States)

    He, Congrong; Morawska, Lidia; Hitchins, Jane; Gilbert, Dale

    As part of a large study investigating indoor air in residential houses in Brisbane, Australia, the purpose of this work was to quantify emission characteristics of indoor particle sources in 15 houses. Submicrometer particle number and approximation of PM 2.5 concentrations were measured simultaneously for more than 48 h in the kitchen of all the houses by using a condensation particle counter (CPC) and a photometer (DustTrak), respectively. In addition, characterizations of particles resulting from cooking conducted in an identical way in all the houses were measured by using a scanning mobility particle sizer (SMPS), an aerodynamic particle sizer (APS) and a DustTrak. All the events of elevated particle concentrations were linked to indoor activities using house occupants diary entries, and catalogued into 21 different types of indoor activities. This enabled quantification of the effect of indoor sources on indoor particle concentrations as well as quantification of emission rates from the sources. For example, the study found that frying, grilling, stove use, toasting, cooking pizza, cooking, candle vaporizing eucalyptus oil and fan heater use, could elevate the indoor submicrometer particle number concentration levels by more than five times, while PM 2.5 concentrations could be up to 3, 30 and 90 times higher than the background levels during smoking, frying and grilling, respectively.

  10. Maternal plasma n-3 and n-6 polyunsaturated fatty acid concentrations during pregnancy and subcutaneous fat mass in infancy.

    Science.gov (United States)

    Jelena Vidakovic, Aleksandra; Santos, Susana; Williams, Michelle A; Duijts, Liesbeth; Hofman, Albert; Demmelmair, Hans; Koletzko, Berthold; Jaddoe, Vincent W V; Gaillard, Romy

    2016-08-01

    The associations of maternal plasma n-3 and n-6 polyunsaturated fatty acid (PUFA) concentrations during pregnancy with infant subcutaneous fat were examined. In a population-based prospective cohort study among 904 mothers and their infants, maternal plasma n-3 and n-6 PUFA concentrations were measured at midpregnancy. Body mass index, total subcutaneous fat, and central-to-total subcutaneous fat ratio were calculated at 1.5, 6, and 24 months. Maternal n-3 PUFA levels were not consistently associated with infant body mass index or total subcutaneous fat. Higher maternal total n-3 PUFA levels, and specifically eicosapentaenoic acid, docosapentaenoic acid, and docosahexaenoic acid, were associated with higher central-to-total subcutaneous fat ratio at 1.5 months, whereas higher maternal total n-3 PUFA levels were associated with lower central-to-total subcutaneous fat ratio at 6 months (all P values fat. A higher n-6/n-3 ratio was associated with lower central-to-total subcutaneous fat ratio at 1.5 months only (P value fat. Further studies are needed to assess the effects of maternal PUFA concentrations on fat mass development during early infancy. © 2016 The Obesity Society.

  11. Simultaneous measurement of gas concentration and temperature by the ball surface acoustic wave sensor

    Science.gov (United States)

    Yamanaka, Kazushi; Akao, Shingo; Takeda, Nobuo; Tsuji, Toshihiro; Oizumi, Toru; Tsukahara, Yusuke

    2017-07-01

    We have developed a ball surface acoustic wave (SAW) trace moisture sensor with an amorphous silica sensitive film and realized wide-range measurement from 0.017 ppmv [a frost point (FP) of -99 °C] to 6.0 × 103 ppmv (0 °C FP). However, since the sensitivity of the sensor depends on the temperature, measurement results are disturbed when the temperature largely changes. To overcome this problem, we developed a method to simultaneously measure temperature and gas concentration using a ball SAW sensor. Temperature and concentration is derived by solving equations for the delay time change at two frequencies. When the temperature had a large jump, the delay time change was significantly disturbed, but the water concentration was almost correctly measured, by compensating the sensitivity change using measured temperature. The temperature measured by a ball SAW sensor will also be used to control the ball temperature. This method will make a ball SAW sensor reliable in environments of varying temperatures.

  12. The potential of LIRIC to validate the vertical profiles of the aerosol mass concentration estimated by an air quality model

    Science.gov (United States)

    Siomos, Nikolaos; Filoglou, Maria; Poupkou, Anastasia; Liora, Natalia; Dimopoulos, Spyros; Melas, Dimitris; Chaikovsky, Anatoli; Balis, Dimitris

    2015-04-01

    Vertical profiles of the aerosol mass concentration derived by a retrieval algorithm that uses combined sunphotometer and LIDAR data (LIRIC) were used in order to validate the mass concentration profiles estimated by the air quality model CAMx. LIDAR and CIMEL measurements of the Laboratory of Atmospheric Physics of the Aristotle University of Thessaloniki were used for this validation.The aerosol mass concentration profiles of the fine and coarse mode derived by CAMx were compared with the respective profiles derived by the retrieval algorithm. For the coarse mode particles, forecasts of the Saharan dust transportation model BSC-DREAM8bV2 were also taken into account. Each of the retrieval algorithm's profiles were matched to the models' profile with the best agreement within a time window of four hours before and after the central measurement. OPAC, a software than can provide optical properties of aerosol mixtures, was also employed in order to calculate the angstrom exponent and the lidar ratio values for 355nm and 532nm for each of the model's profiles aiming in a comparison with the angstrom exponent and the lidar ratio values derived by the retrieval algorithm for each measurement. The comparisons between the fine mode aerosol concentration profiles resulted in a good agreement between CAMx and the retrieval algorithm, with the vertical mean bias error never exceeding 7 μgr/m3. Concerning the aerosol coarse mode concentration profiles both CAMx and BSC-DREAM8bV2 values are severely underestimated, although, in cases of Saharan dust transportation events there is an agreement between the profiles of BSC-DREAM8bV2 model and the retrieval algorithm.

  13. Charge carrier effective mass and concentration derived from combination of Seebeck coefficient and 125Te NMR measurements in complex tellurides

    Science.gov (United States)

    Levin, E. M.

    2016-06-01

    Thermoelectric materials utilize the Seebeck effect to convert heat to electrical energy. The Seebeck coefficient (thermopower), S , depends on the free (mobile) carrier concentration, n , and effective mass, m*, as S ˜m*/n2 /3 . The carrier concentration in tellurides can be derived from 125Te nuclear magnetic resonance (NMR) spin-lattice relaxation measurements. The NMR spin-lattice relaxation rate, 1 /T1 , depends on both n and m* as 1 /T1˜(m*)3/2n (within classical Maxwell-Boltzmann statistics) or as 1 /T1˜(m*)2n2 /3 (within quantum Fermi-Dirac statistics), which challenges the correct determination of the carrier concentration in some materials by NMR. Here it is shown that the combination of the Seebeck coefficient and 125Te NMR spin-lattice relaxation measurements in complex tellurides provides a unique opportunity to derive the carrier effective mass and then to calculate the carrier concentration. This approach was used to study A gxS bxG e50-2xT e50 , well-known GeTe-based high-efficiency tellurium-antimony-germanium-silver thermoelectric materials, where the replacement of Ge by [Ag+Sb] results in significant enhancement of the Seebeck coefficient. Values of both m* and n derived using this combination show that the enhancement of thermopower can be attributed primarily to an increase of the carrier effective mass and partially to a decrease of the carrier concentration when the [Ag+Sb] content increases.

  14. Wintertime particulate mass concentrations in urban environment and the impact of economic crisis.

    Science.gov (United States)

    Gaidajis, Georgios; Angelakoglou, Komninos; Aktsoglou, Despoina

    2014-01-01

    The aim of the specific study is to discuss the impact of economic crisis on air quality in Greece in terms of particulate matter (PM) concentrations. For this purpose, three sampling campaigns were conducted during the winter period of 2012, 2013 and 2014 in two medium sized cities in North Greece (Kavala and Drama). The average concentrations measured ranged from 33-56, 28-47 and 25-44 μg/m(3) for PM10, PM2.5 and PM1, respectively. The analysis of the daily concentration profile for all measurements indicated two distinct periods of elevated concentrations: a) during 08:00 to 10:00 and b) during 19:00 to 22:00. The observed periods of increased concentration coincided with the periods of increased urban traffic in the morning and basic heating needs in late evening. Significant correlation was observed between PM10-PM2.5 (R(2)>0.9) and PM2.5-PM1 (R(2)∼1.0) suggesting that coarse and fine particles originate from similar sources. The PM2.5/PM10 ratio values ranged from 0.84 to 0.85 indicating a major impact of PM2.5 to the final concentration levels recorded. The results presented in the specific study support the notion that a significant alteration is undergoing to the atmospheric air quality in Greece due to the economic crisis and the subsequent increase of biomass products combustion for residential heating. Supplemental materials are available for this article.

  15. Can We Trust Real Time Measurements of Lung Deposited Surface Area Concentrations in Dust from Powder Nanomaterials?

    DEFF Research Database (Denmark)

    Levin, Marcus; Witschger, Olivier; Bau, Sebastien

    2016-01-01

    A comparison between various methods for real-time measurements of lung deposited surface area (LDSA) using spherical particles and powder dust with specific surface area ranging from 0.03 to 112 m2 g-1 was conducted. LDSA concentrations measured directly using Nanoparticle Surface Area Monitor...... (NSAM) and Aerotrak and were compared to LDSA concentrations recalculated from size distribution measurements using Electrical Low Pressure Impactor (ELPI) and Fast Mobility Particle Sizer (FMPS). FMPS and ELPI measurements were also compared to dust surface area concentrations estimated from...... gravimetrical filter measurements and specific surface areas. Measurement of LDSA showed very good correlation in measurements of spherical particles (R2 > 0.97, Ratio 1.0 to 1.04). High surface area nanomaterial powders showed a fairly reliable correlation between NSAM and Aerotrak (R2 0...

  16. Mass transfer of CO2 to groundwaters from a near-surface waste disposal site

    International Nuclear Information System (INIS)

    Caron, F.; Wilkinson, S.R.; Manni, G.; Torok, J.

    1995-01-01

    Gaseous 14 CO 2 originating from buried low-level radioactive wastes (LLRW) in a near-surface disposal site can be released to the environment via two major paths: gas-phase diffusion through soils to the atmosphere, and dissolution in groundwater, followed by aqueous migration. Aqueous migration would give the highest dose to an individual, especially if C-14 was converted to an organic form and ingested. Gaseous diffusion would give a lower dose, largely because of atmospheric dispersion and dilution. The objective of this study was to develop the capability to estimate which of the two paths will likely be dominant for typical near-surface disposal facilities. The main missing parameter for making this estimate was a mass-transfer coefficient (K L ) of 14 CO 2 to groundwaters, which was determined experimentally using a large sand box. The K L thus determined was approximately 10 to 20 times smaller than for an open liquid surface. This suggests that there is a potential resistance to mass transfer, probably caused by the capillary fringe. The value obtained was incorporated into a simple model of CO 2 transport around a typical near-surface disposal site. The model suggests that CO 2 transport via both gaseous release and aqueous migration paths are of similar magnitude for a repository located ∼2 m above the water table. (author). 11 refs., 2 tabs., 2 figs

  17. Mass balance and surface movement of the Greenland Ice Sheet at Summit, Central Greenland

    DEFF Research Database (Denmark)

    Hvidberg, C.S.; Keller, K.; Gundestrup, N.S.

    1997-01-01

    During the GRIP deep drilling in Central Greenland, the ice sheet topography and surface movement at Summit has been mapped with GPS. Measurements of the surface velocity are presented for a strain net consisting of 13 poles at distances of 25-60 km from the GRIP site. Some results are: The GRIP...... site is located approximately 2 km NW of the topographic summit; the surface velocity at the GISP 2 site is 1.7 m/yr in the W direction. The present mass balance at Summit is calculated to be -0.03+/-0.04 m/yr, i.e. close to steady state. This result is the best now available for Summit. A small...... thinning rate might be a transient response of the Greenland Ice Sheet due to the temperature increase at the Wisconsin-Holocene transition....

  18. A method of estimating multicomponent nonaqueous-phase liquid mass in porous media using aqueous concentration ratios.

    Science.gov (United States)

    Devlint, J F; Barbaro, J R

    2001-11-01

    A simple dissolution model based on Raoult's Law was used to derive a log-linear equation for the estimation of multicomponent nonaqueous-phase liquid (NAPL) mass in porous media. The analysis, referred to here as the ratio mass estimation (RME) method, requires aqueous concentration ratios for two components of the NAPL mixture as well as their pure phase liquid solubilities. Application of the equation using data from a previously reported column experiment, in which 1.22 g of a benzene/toluene NAPL were flushed with water, yielded an estimate of 1.2 g of NAPL. In addition, data from two in situ field column experiments of gasoline dissolution were examined. In those experiments, three ratio pairs, benzene/toluene, ethylbenzene/toluene, and ethylbenzene/benzene, were considered from each cell, and the initial NAPL masses were estimated to be between 39 and 42 kg NAPL, within 30% of the true NAPL masses of 54 kg in each cell. Finally, data from the flushing of a controlled release of chlorinated solvents (chloroform, trichloroethene, and tetrachloroethene) inside a sheet pile cell were examined, and the initial NAPL mass was estimated to within 15% of the true value. The RME analysis is based on several simplifying assumptions and should be used with caution. However, this work shows it to be potentially useful under conditions that might be encountered at sites. The analysis is simple and based on data that are often collected routinely.

  19. Accurate determination of 129I concentrations and 129I/137Cs ratios in spent nuclear resins by Accelerator Mass Spectrometry

    International Nuclear Information System (INIS)

    Nottoli, Emmanuelle; Bienvenu, Philippe; Labet, Alexandre; Bourlès, Didier; Arnold, Maurice; Bertaux, Maité

    2014-01-01

    Determining long-lived radionuclide concentrations in radioactive waste has fundamental implications for the long-term management of storage sites. This paper focuses on the measurement of low 129 I contents in ion exchange resins used for primary fluid purification in Pressurised Water Reactors (PWR). Iodine-129 concentrations were successfully determined using Accelerator Mass Spectrometry (AMS) following a chemical procedure which included (1) acid digestion of resin samples in HNO 3 /HClO 4 , (2) radioactive decontamination by selective iodine extraction using a new chromatographic resin (CL Resin), and (3) AgI precipitation. Measured 129 I concentrations ranged from 4 to 12 ng/g, i.e. from 0.03 to 0.08 Bq/g. The calculation of 129 I/ 137 Cs activity ratios used for routine waste management produced values in agreement with the few available data for PWR resin samples. - Highlights: • In the context of radioactive waste management, this study aimed at measuring 129 I in spent resins using accelerator mass spectrometry. • The treatment procedure included microwave acid digestion of samples, iodine extraction by CL resins and AgI precipitation. • Developed first on synthetic matrices, the chemical treatment procedure was then successfully applied to real resin samples. • 129 I concentrations ranged from 4 to 12 ng/g of dry resin. • Results are in agreement with previous measurements and support reference values currently used for nuclear resin management

  20. The galactic disk surface mass density and the Galactic force K(z) at z = 1.1 kiloparsecs

    International Nuclear Information System (INIS)

    Kuijken, K.; Gilmore, G.

    1991-01-01

    A set of distance and velocity data previously obtained and analyzed is rediscussed to determine the surface mass density of the Galactic disk. These data reliably determine the integral surface mass density of all (disk + halo) Galactic components within 1.1 kpc from the Galactic plane near the sun to be 71 + or 6 solar masses/sq pc, independent of the disk/halo ratio. Determination of the fraction of this total mass which is distributed in the Galactic disk and the fraction which is associated with an extended halo remains highly model-dependent. The best available estimate of the relative contributions of disk mass and halo mass to the local integral surface density, obtained from modeling of the Galactic rotation curve, yields a surface mass density of 48 + or - 9 solar masses/sq pc for mass associated with the Galactic disk near the sun. The corresponding mass of identified disk matter is 48 + or - 8 solar masses/sq pc. 7 refs

  1. Artificial neural network and response surface methodology modeling in mass transfer parameters predictions during osmotic dehydration of Carica papaya L.

    Directory of Open Access Journals (Sweden)

    J. Prakash Maran

    2013-09-01

    Full Text Available In this study, a comparative approach was made between artificial neural network (ANN and response surface methodology (RSM to predict the mass transfer parameters of osmotic dehydration of papaya. The effects of process variables such as temperature, osmotic solution concentration and agitation speed on water loss, weight reduction, and solid gain during osmotic dehydration were investigated using a three-level three-factor Box-Behnken experimental design. Same design was utilized to train a feed-forward multilayered perceptron (MLP ANN with back-propagation algorithm. The predictive capabilities of the two methodologies were compared in terms of root mean square error (RMSE, mean absolute error (MAE, standard error of prediction (SEP, model predictive error (MPE, chi square statistic (χ2, and coefficient of determination (R2 based on the validation data set. The results showed that properly trained ANN model is found to be more accurate in prediction as compared to RSM model.

  2. Spatial Evaluation of Heavy Metals Concentrations in the Surface Sediment of Taihu Lake

    Science.gov (United States)

    Niu, Yong; Jiao, Wei; Yu, Hui; Niu, Yuan; Pang, Yong; Xu, Xiangyang; Guo, Xiaochun

    2015-01-01

    With regard to the size of China’s freshwater lakes, Taihu Lake ranks third and it plays an important role in the supply of drinking water, flood prevention, farming and navigation, as well as in the travelling industry. The problem of environmental pollution has attracted widespread attention in recent years. In order to understand the levels, distribution and sources of heavy metals in sediments of Taihu Lake, random selection was carried out to obtain 59 samples of surface sediment from the entire lake and study the concentrations of Pb, Cd, Cu, Zn, Cr and Ni. Toxic units were also calculated to normalize the toxicities caused by various heavy metals. As a result, Cd and Cu in sediment were considered lower than the effect range low (ERL) at all regions where samples were gathered, while Pb and Ni were categorized into ERL-effect range median (ERM) at over 22% of the regions where samples were obtained. Nevertheless, all average concentrations of the samples were below the level of potential effect. According to the findings of this research, significant spatial heterogeneity existed in the above heavy metals. In conclusion, the distribution areas of heavy metals with higher concentrations were mainly the north bays, namely Zhushan Bay, Meiliang Bay as well as Gonghu Bay. The distribution areas of Cu, Zn, Cr and Ni with higher concentration also included the lake’s central region, whereas the uniform distribution areas of those with lower concentrations were the lake’s southeast region. In addition, it was most probable that the spatial distribution of heavy metals was determined by river inputs, whereas atmospheric precipitation caused by urban and traffic contamination also exerted considerable effects on the higher concentrations of Pb and Cd. Through evaluating the total amount of toxic units (ΣTU), it was found that higher toxicity existed primarily in the north bays and central region of the lake. If the heavy metals were sorted by the reduction of

  3. Analysis of concentric and eccentric contractions in biceps brachii muscles using surface electromyography signals and multifractal analysis.

    Science.gov (United States)

    Marri, Kiran; Swaminathan, Ramakrishnan

    2016-06-23

    Muscle contractions can be categorized into isometric, isotonic (concentric and eccentric) and isokinetic contractions. The eccentric contractions are very effective for promoting muscle hypertrophy and produce larger forces when compared to the concentric or isometric contractions. Surface electromyography signals are widely used for analyzing muscle activities. These signals are nonstationary, nonlinear and exhibit self-similar multifractal behavior. The research on surface electromyography signals using multifractal analysis is not well established for concentric and eccentric contractions. In this study, an attempt has been made to analyze the concentric and eccentric contractions associated with biceps brachii muscles using surface electromyography signals and multifractal detrended moving average algorithm. Surface electromyography signals were recorded from 20 healthy individuals while performing a single curl exercise. The preprocessed signals were divided into concentric and eccentric cycles and in turn divided into phases based on range of motion: lower (0°-90°) and upper (>90°). The segments of surface electromyography signal were subjected to multifractal detrended moving average algorithm, and multifractal features such as strength of multifractality, peak exponent value, maximum exponent and exponent index were extracted in addition to conventional linear features such as root mean square and median frequency. The results show that surface electromyography signals exhibit multifractal behavior in both concentric and eccentric cycles. The mean strength of multifractality increased by 15% in eccentric contraction compared to concentric contraction. The lowest and highest exponent index values are observed in the upper concentric and lower eccentric contractions, respectively. The multifractal features are observed to be helpful in differentiating surface electromyography signals along the range of motion as compared to root mean square and median

  4. Evaluation of Relation between Mercury Concentration in Saliva with Number and Surfaces of Amalgam Fillings

    Directory of Open Access Journals (Sweden)

    F. Agha Hosseini

    2004-09-01

    Full Text Available Statement of Problem: Amalgam is the most widely used dental restorative material.However, because of continuous low-level release of Mercury from amalgam fillings, its safety has been questionable.Purpose: The aim of this study was the evaluation of concentration of Mercury in saliva before and after amalgam fillings and its relation with numbers and surfaces of amalgam fillings.Materials and Methods: In an analytic interventional study we surveyed concentration Mercury in saliva before and after amalgam fillings. Twenty-five Patients (9 male, 16 female who referred to oral medicine department of Tehran university of medical scienceand Haj- Abdol- Vahab medical center who had no amalgam fillings were selected and the samples of saliva (5cc was collected before fillings. After that all of posterior decayed teeth were filled in an appointment with amalgam and, 24 hours later, the second samplesof saliva (5cc was collected. The amount of saliva Mercury before and after filling was measured and its difference was analyzed by paired t- test.Results: In this study the mean of Mercury in saliva was 0.00896 μg/ml before and 0.16404 μg/ml after amalgam fillings. The mean of number of fillings was 1.96 and mean of size of surfaces was 76.43 mm2 and mean of consumption amalgam was 4.1 units.Conclusion: There was no significant correlation between age (P=0.677, sex, number of fillings (P=0.055, number of surface of filling (P=0.059 and size of surfaces of fillings (P=0.072, with Mercury levels in saliva after amalgam fillings. There was a significant relation between Mercury level of saliva after fillings and amalgam amount (P= 0.036.Therefore amalgam may be designate a significant source for Mercury release in saliva.Since this is a preliminary study, it needs supplementary evaluations in saliva, blood and urine in different periods after amalgam fillings.

  5. Surface Mass Balance of the Greenland Ice Sheet Derived from Paleoclimate Reanalysis

    Science.gov (United States)

    Badgeley, J.; Steig, E. J.; Hakim, G. J.; Anderson, J.; Tardif, R.

    2017-12-01

    Modeling past ice-sheet behavior requires independent knowledge of past surface mass balance. Though models provide useful insight into ice-sheet response to climate forcing, if past climate is unknown, then ascertaining the rate and extent of past ice-sheet change is limited to geological and geophysical constraints. We use a novel data-assimilation framework developed under the Last Millennium Reanalysis Project (Hakim et al., 2016) to reconstruct past climate over ice sheets with the intent of creating an independent surface mass balance record for paleo ice-sheet modeling. Paleoclimate data assimilation combines the physics of climate models and the time series evidence of proxy records in an offline, ensemble-based approach. This framework allows for the assimilation of numerous proxy records and archive types while maintaining spatial consistency with known climate dynamics and physics captured by the models. In our reconstruction, we use the Community Climate System Model version 4, CMIP5 last millennium simulation (Taylor et al., 2012; Landrum et al., 2013) and a nearly complete database of ice core oxygen isotope records to reconstruct Holocene surface temperature and precipitation over the Greenland Ice Sheet on a decadal timescale. By applying a seasonality to this reconstruction (from the TraCE-21ka simulation; Liu et al., 2009), our reanalysis can be used in seasonally-based surface mass balance models. Here we discuss the methods behind our reanalysis and the performance of our reconstruction through prediction of unassimilated proxy records and comparison to paleoclimate reconstructions and reanalysis products.

  6. Surface Energy and Mass Balance Model for Greenland Ice Sheet and Future Projections

    Science.gov (United States)

    Liu, Xiaojian

    The Greenland Ice Sheet contains nearly 3 million cubic kilometers of glacial ice. If the entire ice sheet completely melted, sea level would raise by nearly 7 meters. There is thus considerable interest in monitoring the mass balance of the Greenland Ice Sheet. Each year, the ice sheet gains ice from snowfall and loses ice through iceberg calving and surface melting. In this thesis, we develop, validate and apply a physics based numerical model to estimate current and future surface mass balance of the Greenland Ice Sheet. The numerical model consists of a coupled surface energy balance and englacial model that is simple enough that it can be used for long time scale model runs, but unlike previous empirical parameterizations, has a physical basis. The surface energy balance model predicts ice sheet surface temperature and melt production. The englacial model predicts the evolution of temperature and meltwater within the ice sheet. These two models can be combined with estimates of precipitation (snowfall) to estimate the mass balance over the Greenland Ice Sheet. We first compare model performance with in-situ observations to demonstrate that the model works well. We next evaluate how predictions are degraded when we statistically downscale global climate data. We find that a simple, nearest neighbor interpolation scheme with a lapse rate correction is able to adequately reproduce melt patterns on the Greenland Ice Sheet. These results are comparable to those obtained using empirical Positive Degree Day (PDD) methods. Having validated the model, we next drove the ice sheet model using the suite of atmospheric model runs available through the CMIP5 atmospheric model inter-comparison, which in turn built upon the RCP 8.5 (business as usual) scenarios. From this exercise we predict how much surface melt production will increase in the coming century. This results in 4-10 cm sea level equivalent, depending on the CMIP5 models. Finally, we try to bound melt water

  7. Mass or total surface area with aerosol size distribution as exposure metrics for inflammatory, cytotoxic and oxidative lung responses in rats exposed to titanium dioxide nanoparticles.

    Science.gov (United States)

    Noël, A; Truchon, G; Cloutier, Y; Charbonneau, M; Maghni, K; Tardif, R

    2017-04-01

    There is currently no consensus on the best exposure metric(s) for expressing nanoparticle (NP) dose. Although surface area has been extensively studied for inflammatory responses, it has not been as thoroughly validated for cytotoxicity or oxidative stress effects. Since inhaled NPs deposit and interact with lung cells based on agglomerate size, we hypothesize that mass concentration combined with aerosol size distribution is suitable for NP risk assessment. The objective of this study was to evaluate different exposure metrics for inhaled 5 nm titanium dioxide aerosols composed of small (SA 100 nm) agglomerates at 2, 7, and 20 mg/m 3 on rat lung inflammatory, cytotoxicity, and oxidative stress responses. We found a significant positive correlation ( r = 0.98, p 0.91, p 0.97, p < 0.01). These data show that mass or total surface area concentrations alone are insufficient to adequately predict oxidant and cytotoxic pulmonary effects. Overall, our study indicates that considering NP size distribution along with mass or total surface area concentrations contributes to a more mechanistic discrimination of pulmonary responses to NP exposure.

  8. Quantification of captopril in urine through surface-assisted laser desorption/ionization mass spectrometry using 4-mercaptobenzoic acid-capped gold nanoparticles as an internal standard.

    Science.gov (United States)

    Chen, Wen-Tsen; Chiang, Cheng-Kang; Lin, Yang-Wei; Chang, Huan-Tsung

    2010-05-01

    We have developed a new internal standard method for the determination of the concentration of captopril (CAP) through surface-assisted laser desorption/ionization mass spectrometry (SALDI-MS) using gold nanoparticles (Au NPs). This approach provided linearity for CAP over the concentration range 2.5-25 microM (R(2) = 0.987), with a limit of detection (signal-to-noise ratio = 3) of 1.0 microM. The spot-to-spot variations in the concentration of CAP through SALDI-MS analyses performed in the absence and presence of the internal standard were 26% and 9%, respectively (15 measurements). This approach provides simplicity, accuracy, precision, and great reproducibility to the determination of the levels of CAP in human urine samples. Copyright 2010 American Society for Mass Spectrometry. Published by Elsevier Inc. All rights reserved.

  9. Heavy metal concentrations in the surface marine sediments of Sfax Coast, Tunisia.

    Science.gov (United States)

    Gargouri, Dorra; Azri, Chafai; Serbaji, Mohamed Moncef; Jedoui, Younes; Montacer, Mabrouk

    2011-04-01

    Sixty-seven surface marine sediment samples in the Sfax (Tunisia) were analyzed by inductively coupled plasma-atomic emission spectrometry for seven heavy metals (Pb, Ni, Cu, Cr, Zn, Cd, and Fe). Metal concentrations were compared with natural values, marine sediment quality standards, and also with other results concerning sediments from several Mediterranean coasts. The study of their spatial distributions refined by complementary approaches including principal component analysis, enrichment factors, and geoaccumulation index showed a significant impact of multiple anthropogenic sources. These included industrial sources and municipal discharges of the urban Sfax and also non-controlled discharges in rural zones close to the coastline. Moderate pollution of sediments, especially by Pb, Zn, and Ni, was shown to exist in localized sites. Besides, it was shown that other sites, slightly to highly enriched in terms of Cu, Cr, and Cd, are characterized by a quality of sediments varying from unpolluted to moderately polluted.

  10. Heavy metal concentration in mangrove surface sediments from the north-west coast of South America.

    Science.gov (United States)

    Fernández-Cadena, J C; Andrade, S; Silva-Coello, C L; De la Iglesia, R

    2014-05-15

    Mangrove ecosystems are coastal estuarine systems confined to the tropical and subtropical regions. The Estero Salado mangrove located in Guayaquil, Ecuador, has suffered constant disturbances during the past 20 years, due to industrial wastewater release. However, there are no published data for heavy metals present in its sediments and the relationship with anthropogenic disturbance. In the present study, metal concentrations were evaluated in surface sediment samples of the mangrove, showing that B, Cd, Cu, Pb, Se, V, and Zn levels exceeded those declared in international environmental quality standards. Moreover, several metals (Pb, Sn, Cd, Ag, Mo, Zn and Ni) could be linked to the industrial wastewater present in the studied area. In addition, heavy metal levels detected in this mangrove are higher than previous reports on mangrove sediments worldwide, indicating that this mangrove ecosystem is one of the most disrupted on earth. Copyright © 2014 Elsevier Ltd. All rights reserved.

  11. Shape of shock wave produced by a concentrated impact on a surface

    International Nuclear Information System (INIS)

    Nutt, G.; Klein, L.

    1981-01-01

    An approximate similarity solution, derived by Raizer, of a concentrated impact (or intense explosion) at the boundary of a semi-infinite volume of a perfect gas is used to determine the propagation velocity of the shock front as a function of its position. This velocity function is then used to obtain the shape of the propagating shock wave. It is shown that dish-shaped shock fronts are formed when the movement of the gas at the surface is into the gas region and that cup-shaped shock fronts are formed when the movement is out of the gas region. Comparison of these results with the shapes of explosions and meteorite craters are discussed

  12. Measurement of Atmospheric Isoprene Concentrations using an Automated Cylindrical Ion Trap Mass Spectrometer

    Science.gov (United States)

    Edwards, G. D.; Shepson, P. B.; Grossenbacher, J. W.; Wells, J. M.; Patterson, G.; Barkett, D. J.

    2005-12-01

    Volatile organic compounds (VOCs) released from the biosphere have been shown to substantially influence both ozone and aerosol chemistry. However, field instruments for the detection of these trace gases are often limited by instrument portability and the ability to distinguish compounds of interest from background or other interfering compounds. We have developed an automated sampling system that is coupled to a lightweight, low power cylindrical ion trap mass spectrometer. This instrument was used for high frequency isoprene measurements at a recent field campaign at the University of Michigan Biological Station PROPHET lab. The inlet uses a sample loop and 6-port valves to trap ambient air samples without the aid of cryogens. VOCs are preconcentrated by sampling directly into a pre-cooled capillary column that is then heated by moving the column to a pre-heated region to obtain rapid separation of isoprene from other species. Isoprene eluting from the end of the column is then introduced to the mass spectrometer. The commercially available cylindrical ion trap (Minotaur 400) interfaced with our preconcentrator yields limits of detection of <80 ppt. The data obtained during the PROPHET 2005 campaign suggest the new inlet system, when coupled with the Minotaur 400 detector provides a feasible field instrument for the fast and accurate evaluation of trace gases over a variety of atmospheric conditions.

  13. Mass concentration of Hirnantian cephalopods from the Siljan District, Sweden; taxonomy, palaeoecology and palaeobiogeographic relationships

    Directory of Open Access Journals (Sweden)

    B. Kröger

    2011-02-01

    Full Text Available The Hirnantian Glisstjärn Formation (Normalograptus persculptus graptolite Biozone is a succession of limestones and shales onlapping the Katian Boda Limestone in the Siljan District, Sweden. It contains a conspicuous, up to several decimeter thick bed densely packed with bipolarly oriented, orthoconic cephalopod conchs that can reach lengths of more than 120 cm. Conch fragmentation, bioereosion and the generally poor preservation of the conchs indicate time averaging and the conchs are tentatively interpreted as beached, and a result of winnowing. Ten nautiloid species were collected from the Glisstjärn Formation of which five are new: Dawsonoceras gregarium n. sp., Discoceras siljanense n. sp., Isorthoceras dalecarlense n. sp., Retizitteloceras rarum gen. et sp. n., and Transorthoceras osmundsbergense gen. et sp. n. The non-endemic taxa in most cases are known from elsewhere in Baltoscandia, except one species which is known from Siberia, and North America respectively. Proteocerid orthoceridans dominate the association, of which T. osmundsbergense is the predominant species. Oncocerids are diverse but together with tarphycerids very rare. Notable is the lack of many higher taxa, that are typical for other Late Ordovician shallow water depositional settings. Based on the taxonomical composition of the cephalopod mass occurrence it is interpreted as an indicator of eutrophication of the water masses in the area. doi:10.1002/mmng.201000014

  14. Gold-enhanced biomolecular surface imaging of cells and tissue by SIMS and MALDI mass spectrometry.

    Science.gov (United States)

    Altelaar, A F Maarten; Klinkert, Ivo; Jalink, Kees; de Lange, Robert P J; Adan, Roger A H; Heeren, Ron M A; Piersma, Sander R

    2006-02-01

    Surface metallization by plasma coating enhances desorption/ionization of membrane components such as lipids and sterols in imaging time-of-flight secondary ion mass spectrometry (TOF-SIMS) of tissues and cells. High-resolution images of cholesterol and other membrane components were obtained for neuroblastoma cells and revealed subcellular details (resolving power 1.5 mum). Alternatively, in matrix-enhanced SIMS, 2,5-dihydroxybenzoic acid electrosprayed on neuroblastoma cells allowed intact molecular ion imaging of phosphatidylcholine and sphingomyelin at the cellular level. Gold deposition on top of matrix-coated rat brain tissue sections strongly enhanced image quality and signal intensity in stigmatic matrix-assisted laser desorption/ionization imaging mass spectrometry. High-quality total ion count images were acquired, and the neuropeptide vasopressin was localized in the rat brain tissue section at the hypothalamic area around the third ventricle. Although the mechanism of signal enhancement by gold deposition is under debate, the results we have obtained for cells and tissue sections illustrate the potential of this sample preparation technique for biomolecular surface imaging by mass spectrometry.

  15. Controlled-Resonant Surface Tapping-Mode Scanning Probe Electrospray Ionization Mass Spectrometry Imaging

    Energy Technology Data Exchange (ETDEWEB)

    Lorenz, Matthias [ORNL; Ovchinnikova, Olga S [ORNL; Kertesz, Vilmos [ORNL; Van Berkel, Gary J [ORNL

    2014-01-01

    This paper reports on the advancement of a controlled-resonance surface tapping-mode single capillary liquid junction extraction/ESI emitter for mass spectrometry imaging. The basic instrumental setup and the general operation of the system were discussed and optimized performance metrics were presented. The ability to spot sample, lane scan and chemically image in an automated and controlled fashion were demonstrated. Rapid, automated spot sampling was demonstrated for a variety of compound types including the cationic dye basic blue 7, the oligosaccharide cellopentaose, and the protein equine heart cytochrome c. The system was used for lane scanning and chemical imaging of the cationic dye crystal violet in inked lines on glass and for lipid distributions in mouse brain thin tissue sections. Imaging of the lipids in mouse brain tissue under optimized conditions provided a spatial resolution of approximately 35 m based on the ability to distinguish between features observed both in the optical and mass spectral chemical images. The sampling spatial resolution of this system was comparable to the best resolution that has been reported for other types of atmospheric pressure liquid extraction-based surface sampling/ionization techniques used for mass spectrometry imaging.

  16. NOAA JPSS Visible Infrared Imaging Radiometer Suite (VIIRS) Ice Concentration and Ice Surface Temperature Environmental Data Records (EDRs) from NDE

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This dataset contains a high quality operational Environmental Data Record (EDR) of Sea Ice Concentration (SIC) and Ice Surface Temperature (IST) from the Visible...

  17. Constructing a mass measurement error surface to improve automatic annotations in liquid chromatography/mass spectrometry based metabolomics

    NARCIS (Netherlands)

    Shahaf, N.; Franceschi, P.; Arapitsas, P.; Rogachev, I.; Vrhovsek, U.; Wehrens, H.R.M.J.

    2013-01-01

    RATIONALE Estimation of mass measurement accuracy is an elementary step in the application of mass spectroscopy (MS) data towards metabolite annotations and has been addressed several times in the past. However, the reproducibility of mass measurements over a diverse set of analytes and in variable

  18. Imaging spectroscopy to assess the composition of ice surface materials and their impact on glacier mass balance

    Science.gov (United States)

    Naegeli, Kathrin; Huss, Matthias; Damm, Alexander; de Jong, Rogier; Schaepman, Michael; Hoelzle, Martin

    2014-05-01

    The ice-albedo feedback plays a crucial role in various glaciological processes, but especially influences ice melt. Glacier surface albedo is one of the most important variables in the energy balance of snow and ice, but depends in a complicated way on many factors, such as cryoconite concentration, impurities due to mineral dust, soot or organic matter, grain size or ice surface morphology. Our understanding on how these various factors influence glacier albedo is still limited hindering a spatially and temporally explicit parameterization of energy balance models and requiring strongly simplified assumptions on actual albedo values. Over the last two decades, several studies have focused on glacier surface albedo using automatic in-situ weather stations in combination with radiation measurement setups or satellite images. Due to limitations of both approaches in matching either the spatial or the temporal length scale of glacier albedo, still fairly little is known about the state, changes and impact of glacier surface albedo in the Swiss Alps, although there are obvious changes in surface characteristics on most alpine glaciers over the last years. With use of the APEX (Airborne Prism EXperiment) image spectrometer, measurements of reflected radiation were acquired in high spatial and spectral resolution on Glacier de la Plaine Morte, Switzerland, to explicitly analyse the ice surface. In-situ radiometric measurements were acquired with an ASD field spectrometer in parallel to APEX overflights. These data are intended to be used for validation purposes as well as input data for the linear spectral unmixing analysis of the APEX data. Seasonal glacier mass balance is monitored since five years using the direct glaciological method. This contribution presents a first evaluation of the data collected in summer 2013. The obtained in-situ and airborne reflectance measurements were used in combination with a spectral mixture analysis (SMA) approach to assess the

  19. Step velocity in tetragonal lysozyme growth as a function of impurity concentration and mass transport conditions

    Science.gov (United States)

    Dold, P.; Ono, E.; Tsukamoto, K.; Sazaki, G.

    2006-07-01

    The step velocity on {1 1 0} faces of tetragonal lysozyme crystals has been measured in situ by high-resolution phase contrast microscopy. The movement of the steps shows a distinct anisotropy with respect to the growth velocity and the interaction with impurities. Under high-purity conditions (using lysozyme of 99.99% purity), the step velocity vstep in the direction exceeds the one in the direction by a factor of 6. Spiral hillocks as well as 2D islands show an elongated, lens shaped morphology with pronounced tips in the direction. The ratio of vstep/ vstep is reduced to ≈2-4 when commercial grade lysozyme (purity: 98.5%) is used. The morphology of the hillocks/islands changes from the lens-shaped one to a rounded one. The step velocity into the fast growing direction is significantly more affected by impurities than the growth into the direction. The step velocity of monolayer islands (5.6 nm in height), of multilayer islands and of growth spirals is similar within the accuracy of the measurements. On the topside, the crystal is exposed to protein solution of ≈0.5 mm width. This results in convective mass transport conditions. On the backside of the crystal, there is a small gap of a few hundred nanometers. Within this gap, the crystal is growing under diffusive transport conditions. Changing the focus position from the topside of the crystal to the backside, the growth can be observed on the same crystal under convective as well as under diffusive conditions. Using commercial grade lysozyme, the growth velocity is higher under diffusive conditions than under convectively dominated ones. The morphology of the islands grown from a commercial grade solution under diffusive mass transport conditions is similar to the island morphology obtained otherwise only from high-purity solutions. Using high-purity solution, the step velocity and the island morphology does not differ as a function of the mass transport conditions. These results prove the extension of the

  20. The Complete Solution of Fick's Second Law of Diffusion with Time-dependent Diffusion Coefficient and Surface Concentration

    DEFF Research Database (Denmark)

    Mejlbro, Leif

    1996-01-01

    Fick's Second Law of Diffusion with time-dependent diffusioncoefficient and surface concentration is solved. Mimicking the classicalsolution, special time-dependent surface concentration functions areconsidered. These models are used in giving estimates of the lifetimeof the structure, when the c...... the concrete cover is given, as well as estimatesof the thickness of the concrete cover, when the expected lifetime is given.*Note: Book tilte: Durability of Concrete in Saline Environment...

  1. The concentration of 137Cs in the surface of the Greek marine environment

    International Nuclear Information System (INIS)

    The radiological status of the Greek marine environment, prior to the Chernobyl accident, was characterized mainly by the fallout from nuclear weapon tests. However, the release of radioactivity into the environment from the accident in the Chernobyl Nuclear Power Plant and its deposition in the Greek marine environment resulted in an increase of the 137 Cs activity concentration by approximately one order of magnitude. In addition, the direct transport of radiocaesium into the North Aegean Sea has been further influenced by the late impact of the Chernobyl accident on the Greek marine environment, related to the transfer of 137 Cs, mainly through the Dnieper but also the Danube rivers, to the Black Sea and further to the North Aegean Sea through the Straits of Dardanelles. The aim of this work is to provide a present day picture of the geographic variation of the concentration of 137 Cs in the surface layer of the Greek marine environment and hence, to evaluate the annual committed effective dose delivered to humans through the ingestion pathway from marine sources.

  2. Climate dependent contrast in surface mass balance in East Antarctica over the past 216 ka

    Science.gov (United States)

    Parrenin, Frédéric; Fujita, Shuji; Abe-Ouchi, Ayako; Kawamura, Kenji; Masson-Delmotte, Valérie; Motoyama, Hideaki; Saito, Fuyuki; Severi, Mirko; Stenni, Barbara; Uemura, Ryu; Wolff, Eric

    2017-04-01

    Documenting past changes in the East Antarctic surface mass balance is important to improve ice core chronologies and to constrain the ice-sheet contribution to global mean sea-level change. Here we reconstruct past changes in the ratio of surface mass balance (SMB ratio) between the EPICA Dome C (EDC) and Dome Fuji (DF) East Antarctica ice core sites, based on a precise volcanic synchronization of the two ice cores and on corrections for the vertical thinning of layers. During the past 216 000 a, this SMB ratio, denoted SMB EDC /SMB DF , varied between 0.7 and 1.1, being small during cold periods and large during warm periods. Our results therefore reveal larger amplitudes of changes in SMB at EDC compared with DF, consistent with previous results showing larger amplitudes of changes in water stable isotopes and estimated surface temperature at EDC compared with DF. Within the last glacial inception (Marine Isotope Stages, MIS-5c and MIS-5d), the SMB ratio deviates by up to 0.2 from what is expected based on differences in water stable isotope records. Moreover, the SMB ratio is constant throughout the late parts of the current and last interglacial periods, despite contrasting isotopic trends.

  3. Concentration, enrichment and distribution of heavy metals in surface sediments of the Tangier Bay, Morocco

    Directory of Open Access Journals (Sweden)

    María Rocío Rodríguez-Barroso

    2010-11-01

    Full Text Available The distribution, enrichment, and accumulation of heavy metals in the surface sediments of the Tangier Bay, Morocco, were investigated. Surface sediment samples from eleven locations in the Bay of Tangier were collected in 2007 and characterized for grain size, organic matter and metal content (e.g. Fe, Mn, Cr, Cu, Ni, Pb, Zn and Cd. The evaluation of the heavy metal contamination status of the bay showed minor enrichment by the enrichment factors (EF calculation, corroborated by the metal pollution index (MPI. The results of a Pearson correlation showed high positive correlations among organic carbon and most metals (0.788 < r < 0.939 and cluster analysis grouped the stations inside the harbour (stations 1, 10 and 9 and in the vicinity of the principal rivers in the bay (stations 3 and 11, which showed the highest concentrations of metal content. The main sources of contamination are domestic and industrial effluents, which arise due to the lack of sewage treatment. However, these areas could not be classified as polluted when the data were compared with sediment quality guidelines (USEPA, 1997.

  4. Geostatistical integration and uncertainty in pollutant concentration surface under preferential sampling

    Directory of Open Access Journals (Sweden)

    Laura Grisotto

    2016-04-01

    Full Text Available In this paper the focus is on environmental statistics, with the aim of estimating the concentration surface and related uncertainty of an air pollutant. We used air quality data recorded by a network of monitoring stations within a Bayesian framework to overcome difficulties in accounting for prediction uncertainty and to integrate information provided by deterministic models based on emissions meteorology and chemico-physical characteristics of the atmosphere. Several authors have proposed such integration, but all the proposed approaches rely on representativeness and completeness of existing air pollution monitoring networks. We considered the situation in which the spatial process of interest and the sampling locations are not independent. This is known in the literature as the preferential sampling problem, which if ignored in the analysis, can bias geostatistical inferences. We developed a Bayesian geostatistical model to account for preferential sampling with the main interest in statistical integration and uncertainty. We used PM10 data arising from the air quality network of the Environmental Protection Agency of Lombardy Region (Italy and numerical outputs from the deterministic model. We specified an inhomogeneous Poisson process for the sampling locations intensities and a shared spatial random component model for the dependence between the spatial location of monitors and the pollution surface. We found greater predicted standard deviation differences in areas not properly covered by the air quality network. In conclusion, in this context inferences on prediction uncertainty may be misleading when geostatistical modelling does not take into account preferential sampling.

  5. Impact-induced concerted mass transport on W surfaces by a voidion mechanism

    Science.gov (United States)

    Mazilova, T. I.; Sadanov, E. V.; Voyevodin, V. N.; Ksenofontov, V. A.; Mikhailovskij, I. M.

    2018-03-01

    Using low-temperature field ion microscope techniques, we studied at the atomic level morphological evolution of the W surface through bombardment by a beam of several keV He atoms. This technique allows the direct observation of the results of the high energy He atom impact on the elementary damage stages. The formation of the 〈110〉 and 〈100〉 linear vacancy chains and the high relaxation of the near-neighbors of the surface vacancy clusters were revealed. Performed molecular dynamics simulations shows that a single He atom impact triggers the relaxation process of the linear vacancy chain by a substantial decrease of the distance between atoms at both sides of the chain. The observed inward relaxations in W and Mo are an order of magnitude more than that for a single vacancy. It was revealed a novel highly cooperative impact-induced mass transport mechanism on the stepped surface: the formation and motion of a surface spatially delocalized vacancies (voidions). Surface voidions are extremely mobile: the mean velocity of atoms in voidions equals to a substantial portion of the sound velocity. Successive collective translations of the 〈111〉 lines of atoms in adjacent voidions give rise to a concerted gliding motion of great atomic clusters.

  6. The impact of a seasonally ice free Arctic Ocean on the temperature, precipitation and surface mass balance of Svalbard

    Directory of Open Access Journals (Sweden)

    J. J. Day

    2012-01-01

    Full Text Available The observed decline in summer sea ice extent since the 1970s is predicted to continue until the Arctic Ocean is seasonally ice free during the 21st Century. This will lead to a much perturbed Arctic climate with large changes in ocean surface energy flux. Svalbard, located on the present day sea ice edge, contains many low lying ice caps and glaciers and is expected to experience rapid warming over the 21st Century. The total sea level rise if all the land ice on Svalbard were to melt completely is 0.02 m.

    The purpose of this study is to quantify the impact of climate change on Svalbard's surface mass balance (SMB and to determine, in particular, what proportion of the projected changes in precipitation and SMB are a result of changes to the Arctic sea ice cover. To investigate this a regional climate model was forced with monthly mean climatologies of sea surface temperature (SST and sea ice concentration for the periods 1961–1990 and 2061–2090 under two emission scenarios. In a novel forcing experiment, 20th Century SSTs and 21st Century sea ice were used to force one simulation to investigate the role of sea ice forcing. This experiment results in a 3.5 m water equivalent increase in Svalbard's SMB compared to the present day. This is because over 50 % of the projected increase in winter precipitation over Svalbard under the A1B emissions scenario is due to an increase in lower atmosphere moisture content associated with evaporation from the ice free ocean. These results indicate that increases in precipitation due to sea ice decline may act to moderate mass loss from Svalbard's glaciers due to future Arctic warming.

  7. Mass Sensitivity Optimization of a Surface Acoustic Wave Sensor Incorporating a Resonator Configuration

    Directory of Open Access Journals (Sweden)

    Wenchang Hao

    2016-04-01

    Full Text Available The effect of the sensitive area of the two-port resonator configuration on the mass sensitivity of a Rayleigh surface acoustic wave (R-SAW sensor was investigated theoretically, and verified in experiments. A theoretical model utilizing a 3-dimensional finite element method (FEM approach was established to extract the coupling-of-modes (COM parameters in the absence and presence of mass loading covering the electrode structures. The COM model was used to simulate the frequency response of an R-SAW resonator by a P-matrix cascading technique. Cascading the P-matrixes of unloaded areas with mass loaded areas, the sensitivity for different sensitive areas was obtained by analyzing the frequency shift. The performance of the sensitivity analysis was confirmed by the measured responses from the silicon dioxide (SiO2 deposited on different sensitive areas of R-SAW resonators. It is shown that the mass sensitivity varies strongly for different sensitive areas, and the optimal sensitive area lies towards the center of the device.

  8. The role of mass balance equations in growth mechanics illustrated in surface and volume dissolutions.

    Science.gov (United States)

    Ateshian, Gerard A

    2011-01-01

    Growth mechanics problems require the solution of mass balance equations that include supply terms and account for mass exchanges among constituents of a mixture. Though growth may often be accompanied by a variety of concomitant phenomena that increase modeling complexity, such as solid matrix deformation, evolving traction-free configurations, cell division, and active cell contraction, it is important to distinguish these accompanying phenomena from the fundamental growth process that consists of deposition or removal of mass from the solid matrix. Therefore, the objective of this study is to present a canonical problem of growth, namely, dissolution of a rigid solid matrix in a solvent. This problem illustrates a case of negative growth (loss of mass) of the solid in a mixture framework that includes three species, a solid, a solvent, and a solute, where the solute is the product of the solid dissolution. By analyzing both volumetric and surface dissolutions, the two fundamental modes of growth are investigated within the unified framework of mixture theory.

  9. Surface-assisted laser desorption ionization mass spectrometry techniques for application in forensics.

    Science.gov (United States)

    Guinan, Taryn; Kirkbride, Paul; Pigou, Paul E; Ronci, Maurizio; Kobus, Hilton; Voelcker, Nicolas H

    2015-01-01

    Matrix-assisted laser desorption ionization (MALDI) mass spectrometry (MS) is an excellent analytical technique for the rapid and sensitive analysis of macromolecules (>700 Da), such as peptides, proteins, nucleic acids, and synthetic polymers. However, the detection of smaller organic molecules with masses below 700 Da using MALDI-MS is challenging due to the appearance of matrix adducts and matrix fragment peaks in the same spectral range. Recently, nanostructured substrates have been developed that facilitate matrix-free laser desorption ionization (LDI), contributing to an emerging analytical paradigm referred to as surface-assisted laser desorption ionization (SALDI) MS. Since SALDI enables the detection of small organic molecules, it is rapidly growing in popularity, including in the field of forensics. At the same time, SALDI also holds significant potential as a high throughput analytical tool in roadside, work place and athlete drug testing. In this review, we discuss recent advances in SALDI techniques such as desorption ionization on porous silicon (DIOS), nano-initiator mass spectrometry (NIMS) and nano assisted laser desorption ionization (NALDI™) and compare their strengths and weaknesses with particular focus on forensic applications. These include the detection of illicit drug molecules and their metabolites in biological matrices and small molecule detection from forensic samples including banknotes and fingerprints. Finally, the review highlights recent advances in mass spectrometry imaging (MSI) using SALDI techniques. © 2014 Wiley Periodicals, Inc.

  10. Glucose and glycerol concentrations and their tracer enrichment measurements using liquid chromatography tandem mass spectrometry

    DEFF Research Database (Denmark)

    Bornø, Andreas; Foged, Lene; van Hall, Gerrit

    2014-01-01

    The present study describes a new liquid chromatography tandem mass spectrometry method for high-throughput quantification of glucose and glycerol in human plasma using stable isotopically labeled internal standards and is suitable for simultaneous measurements of glucose and glycerol enrichments...... in connection to in vivo metabolic studies investigating glucose turnover and lipolytic rate. Moreover, in order to keep up with this new fast analysis, simple derivatization procedures have been developed. Prior to analysis, glucose and glycerol were derivatized using benzoyl chloride in order to form...... benzoylated derivatives via new simplified fast procedures. For glucose, two internal standards were evaluated, [U-(13) C(6)]glucose and [U-(13) C(6), D(7)]glucose, and for glycerol, [U-(13) C(3), D(8)]glycerol was used. The method was validated by means of calibration curves, quality control samples...

  11. Assessing metaldehyde concentrations in surface water catchments and implications for drinking water abstraction

    Science.gov (United States)

    Asfaw, Alemayehu; Shucksmith, James; Smith, Andrea; Cherry, Katherine

    2015-04-01

    Metaldehyde is an active ingredient in agricultural pesticides such as slug pellets, which are heavily applied to UK farmland during the autumn application season. There is current concern that existing drinking water treatment processes may be inadequate in reducing potentially high levels of metaldehyde in surface waters to below the UK drinking water quality regulation limit of 0.1 µg/l. In addition, current water quality monitoring methods can miss short term fluctuations in metaldehyde concentration caused by rainfall driven runoff, hampering prediction of the potential risk of exposure. Datasets describing levels, fate and transport of metaldehyde in river catchments are currently very scarce. This work presents results from an ongoing study to quantify the presence of metaldehyde in surface waters within a UK catchment used for drinking water abstraction. High resolution water quality data from auto-samplers installed in rivers are coupled with radar rainfall, catchment characteristics and land use data to i) understand which hydro-meteorological characteristics of the catchment trigger the peak migration of metaldehyde to surface waters; ii) assess the relationship between measured metaldehyde levels and catchment characteristics such as land use, topographic index, proximity to water bodies and runoff generation area; iii) describe the current risks to drinking water supply and discuss mitigation options based on modelling and real-time control of water abstraction. Identifying the correlation between catchment attributes and metaldehyde generation will help in the development of effective catchment management strategies, which can help to significantly reduce the amount of metaldehyde finding its way into river water. Furthermore, the effectiveness of current water quality monitoring strategy in accurately quantifying the generation of metaldehyde from the catchment and its ability to benefit the development of effective catchment management practices

  12. Investigation of silicate surface chemistry and reaction mechanisms associated with mass transport in geologic media

    International Nuclear Information System (INIS)

    White, A.F.; Perry, D.L.

    1982-01-01

    The concentration and rate of transport of radionuclides through geologic media can be strongly influenced by the extent of sorption on aquifer surfaces. Over time intervals relevant to such transport processes, rock and mineral surfaces cannot be considered as inert, unreactive substrates but rather as groundwater/solidphase interfaces which are commonly in a state of natural or artificially induced disequilibrium. The goal of the present research is to define experimentally the type of water/rock interactions that will influence surface chemistry and hence sorption characteristics and capacities of natural aquifers. As wide a range of silicate minerals as possible was selected for study to represent rock-forming minerals in basalt, tuff, and granite. The minerals include K-feldspar, plagioclase feldspar, olivine, hornblende, biotite, and volcanic glass

  13. Improving Surface Mass Balance Over Ice Sheets and Snow Depth on Sea Ice

    Science.gov (United States)

    Koenig, Lora Suzanne; Box, Jason; Kurtz, Nathan

    2013-01-01

    Surface mass balance (SMB) over ice sheets and snow on sea ice (SOSI) are important components of the cryosphere. Large knowledge gaps remain in scientists' abilities to monitor SMB and SOSI, including insufficient measurements and difficulties with satellite retrievals. On ice sheets, snow accumulation is the sole mass gain to SMB, and meltwater runoff can be the dominant single loss factor in extremely warm years such as 2012. SOSI affects the growth and melt cycle of the Earth's polar sea ice cover. The summer of 2012 saw the largest satellite-recorded melt area over the Greenland ice sheet and the smallest satellite-recorded Arctic sea ice extent, making this meeting both timely and relevant.

  14. Secondary ion mass spectrometric signal enhancement of phosphatidylcholine dioleoyl on enlarged nanoparticles surface

    Science.gov (United States)

    Gulin, A.; Mochalova, M.; Denisov, N.; Nadtochenko, V.

    2014-10-01

    A silicon wafer surface coverage of nanoparticles (NPs) can enhance the L-α-phosphatidylcholine dioleoyl (DOPC) signal intensity in time-of-flight secondary ion mass spectrometry (TOF-SIMS). A ToF-SIMS mass spectrometer was used with a pulsed primary beam of focused 30 keV Bi3+ ions. The signal enhancing effect has been studied for metallic (Ag, Au, Pb), semiconductor (TiO2), dielectric (SiO2) and hybrid (Au/TiO2NPs, core-shell Au/SiO2) nanoparticles. Ag NPs can attenuate secondary ions signal, whereas all other studied NPs show the signal enhancement. The emission of DOPC lipid secondary ions immobilized on core-shell Au/SiO2NPs was enhanced up to 42 times. This technique is a simple preparatory method enabling an overall increase in molecular lipid ions.

  15. Ion optics of a new time-of-flight mass spectrometer for quantitative surface analysis

    International Nuclear Information System (INIS)

    Veryovkin, Igor V.; Calaway, Wallis F.; Pellin, Michael J.

    2004-01-01

    A new time-of-flight instrument for quantitative surface analysis was developed and constructed at Argonne National Laboratory. It implements ion sputtering and laser desorption for probing analyzed samples and can operate in regimes of secondary neutral mass spectrometry with laser post-ionization and secondary ion mass spectrometry. The instrument incorporates two new ion optics developments: (1) 'push-pull' front end ion optics and (2) focusing and deflecting lens. Implementing these novel elements significantly enhance analytical capabilities of the instrument. Extensive three-dimensional computer simulations of the instrument were conducted in SIMION 3D (c) to perfect its ion optics. The operating principles of the new ion optical systems are described, and a scheme of the new instrument is outlined together with its operating modes

  16. Determination of breath isoprene and acetone concentration with a needle-type extraction device in gas chromatography-mass spectrometry.

    Science.gov (United States)

    Ueta, Ikuo; Mizuguchi, Ayako; Okamoto, Mitsuyoshi; Sakamaki, Hiroyuki; Hosoe, Masahiko; Ishiguro, Motoyuki; Saito, Yoshihiro

    2014-03-20

    Isoprene in human breath is said to be related to cholesterol metabolism, and the possibility of the correlations with some clinical parameters has been studied. However, at this stage, no clear benefit of breath isoprene has been reported for clinical diagnosis. In this work, isoprene and acetone concentrations were measured in the breath of healthy and obese subjects using a needle-type extraction device for subsequent analysis in gas chromatography-mass spectrometry (GC-MS) to investigate the possibility of these compounds as an indicator of possible diseases. After measuring intraday and interday variations of isoprene and acetone concentrations in breath samples of healthy subjects, their concentrations were also determined in 80 healthy and 17 obese subjects. In addition, correlation between these breath concentrations and the blood tests result was studied for these healthy and obese subjects. The results indicated successful determination of breath isoprene and acetone in this work, however, no clear correlation was observed between these measured values and the blood test results. Breath isoprene concentration may not be a useful indicator for obesity or hypercholesterolemia. Copyright © 2014 Elsevier B.V. All rights reserved.

  17. Determination of surface heterogeneity of D-mannitol by sessile drop contact angle and finite concentration inverse gas chromatography.

    Science.gov (United States)

    Ho, Raimundo; Hinder, Steven J; Watts, John F; Dilworth, Sarah E; Williams, Daryl R; Heng, Jerry Y Y

    2010-03-15

    The sensitivity of two techniques in tracking changes in surface energetics was investigated for a crystalline excipient, D-mannitol. Macroscopic crystals of D-mannitol were grown from saturated water solution by slow cooling, and sessile drop contact angle was employed to measure the anisotropic surface energy. The facet-specific surface energy was consistent with localised hydroxyl group concentrations determined by X-ray photoelectron spectroscopy (XPS), and was also in excellent agreement with the surface energy distribution of the powder form of mannitol measured via a new methodology using inverse gas chromatography (IGC) at finite concentrations. The gamma(SV)(d) was found to vary between 39.5 mJ/m(2) and 44.1 mJ/m(2) for contact angle and between 40 mJ/m(2) and 49 mJ/m(2) for IGC measurements. We report here, a high level of surface heterogeneity on the native mannitol crystal surfaces. When the surfaces of both D-mannitol samples (powder and large single crystals) were modified by dichlorodimethylsilane to induce surface hydrophobicity, both IGC and contact angle revealed a homogeneous surface due to functionalisation of mannitol crystal surface with methyl groups resulting in gamma(SV)(d) of approximately 34 mJ/m(2). It was shown that both IGC and contact angle techniques are able to detect surface chemical variations and detailed surface energetic distribution. 2010 Elsevier B.V. All rights reserved.

  18. Surface acoustic wave nebulization of peptides as a microfluidic interface for mass spectrometry.

    Science.gov (United States)

    Heron, Scott R; Wilson, Rab; Shaffer, Scott A; Goodlett, David R; Cooper, Jonathan M

    2010-05-15

    We describe the fabrication of a surface acoustic wave (SAW) device on a LiNbO(3) piezoelectric transducer for the transfer of nonvolatile analytes to the gas phase at atmospheric pressure (a process referred to as nebulization or atomization). We subsequently show how such a device can be used in the field of mass spectrometry (MS) detection, demonstrating that SAW nebulization (SAWN) can be performed either in a discontinuous or pulsed mode, similar to that for matrix assisted laser desorption ionization (MALDI) or in a continuous mode like electrospray ionization (ESI). We present data showing the transfer of peptides to the gas phase, where ions are detected by MS. These peptide ions were subsequently fragmented by collision-induced dissociation, from which the sequence was assigned. Unlike MALDI mass spectra, which are typically contaminated with matrix ions at low m/z, the SAWN generated spectra had no such interference. In continuous mode, the SAWN plume was sampled on a microsecond time scale by a linear ion trap mass spectrometer and produced multiply charged peptide precursor ions with a charge state distribution shifted to higher m/z compared to an identical sample analyzed by ESI. The SAWN technology also provides the opportunity to re-examine a sample from a flat surface, repeatedly. The process can be performed without the need for capillaries, which can clog, reservoirs, which dilute the sample, and electrodes, which when in direct contact with sample, cause unwanted electrochemical oxidation. In both continuous and pulsed sampling modes, the quality of precursor ion scans and tandem mass spectra of peptides was consistent across the plume's lifetime.

  19. Physicochemical properties and in vitro cytocompatibility of modified titanium surfaces prepared via micro-arc oxidation with different calcium concentrations

    International Nuclear Information System (INIS)

    Wu, Sui-Dan; Zhang, Hui; Dong, Xu-Dong; Ning, Cheng-Yun; Fok, Alex S.L.; Wang, Yan

    2015-01-01

    Highlights: • MAO coating improves the surface characteristics and cytocompatibility of titanium. • Composition of MAO coating varies with the electrolyte concentration. • MAO coating properties can be optimized by adjusting the electrolyte concentration. • Higher CA concentration contributes to more favorable MAO coating cytocompatibility. - Abstract: Objective: To explore the effect of calcium concentration in the electrolyte solution on the physicochemical properties and biocompatibility of coatings formed by micro-arc oxidation (MAO) on titanium surfaces. Methods: The surfaces of pure titanium plates were modified by MAO in an electrolytic solution containing calcium acetate (CA; C 4 H 6 CaO 4 ) at concentrations of 0.05, 0.1, 0.2, or 0.3 M and β-glycerophosphate disodium salt pentahydrate (β-GP; C 3 H 7 Na 2 O 6 P·5H 2 O) at a fixed concentration of 0.02 M. Surface topography, elemental characteristics, phase composition, and roughness were investigated by scanning electron microscopy, energy-dispersive X-ray analysis, X-ray diffraction, and a surface roughness tester, respectively. To assess the cytocompatibility and osteoinductivity of the surfaces, MC3T3-E1 preosteoblasts were cultured on the surfaces in vitro, and cell morphology, adhesion, proliferation, and differentiation were observed. Results: The porous MAO coating was composed primarily of TiO 2 rutile and anatase. The amount of TiO 2 rutile, the Ca/P ratio, and the surface roughness of the MAO coating increased with increasing CA concentration in the electrolyte solution. Ca 3 (PO 4 ) 2 , CaCO 3 , and CaTiO 3 were formed on MAO-treated surfaces prepared with CA concentrations of 0.2 and 0.3 M. Cell proliferation and differentiation increased with increasing CA concentration, with MC3T3-E1 cells exhibiting favorable morphologies for bone–implant integration. Conclusions: MAO coating improves the surface characteristics and cytocompatibility of titanium for osseointegration. Higher CA

  20. Physicochemical properties and in vitro cytocompatibility of modified titanium surfaces prepared via micro-arc oxidation with different calcium concentrations

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Sui-Dan; Zhang, Hui [Guanghua School of Stomatology, Hospital of Stomatology, Guangdong Key Laboratory of Stomatology, Sun Yat-sen University, Guangzhou 510055 (China); Dong, Xu-Dong [Faculty of Pharmaceutical Sciences, University of British Columbia, Vancouver, BC V6T 1Z3 (Canada); Ning, Cheng-Yun [College of Material Science and Engineering, South China University of Technology, Guangzhou 510641 (China); Fok, Alex S.L. [Minnesota Dental Research Center of Biomaterials and Biomechanics, School of Dentistry, University of Minnesota, Minneapolis, MN 55414 (United States); Wang, Yan, E-mail: wyan65@163.com [Guanghua School of Stomatology, Hospital of Stomatology, Guangdong Key Laboratory of Stomatology, Sun Yat-sen University, Guangzhou 510055 (China)

    2015-02-28

    Highlights: • MAO coating improves the surface characteristics and cytocompatibility of titanium. • Composition of MAO coating varies with the electrolyte concentration. • MAO coating properties can be optimized by adjusting the electrolyte concentration. • Higher CA concentration contributes to more favorable MAO coating cytocompatibility. - Abstract: Objective: To explore the effect of calcium concentration in the electrolyte solution on the physicochemical properties and biocompatibility of coatings formed by micro-arc oxidation (MAO) on titanium surfaces. Methods: The surfaces of pure titanium plates were modified by MAO in an electrolytic solution containing calcium acetate (CA; C{sub 4}H{sub 6}CaO{sub 4}) at concentrations of 0.05, 0.1, 0.2, or 0.3 M and β-glycerophosphate disodium salt pentahydrate (β-GP; C{sub 3}H{sub 7}Na{sub 2}O{sub 6}P·5H{sub 2}O) at a fixed concentration of 0.02 M. Surface topography, elemental characteristics, phase composition, and roughness were investigated by scanning electron microscopy, energy-dispersive X-ray analysis, X-ray diffraction, and a surface roughness tester, respectively. To assess the cytocompatibility and osteoinductivity of the surfaces, MC3T3-E1 preosteoblasts were cultured on the surfaces in vitro, and cell morphology, adhesion, proliferation, and differentiation were observed. Results: The porous MAO coating was composed primarily of TiO{sub 2} rutile and anatase. The amount of TiO{sub 2} rutile, the Ca/P ratio, and the surface roughness of the MAO coating increased with increasing CA concentration in the electrolyte solution. Ca{sub 3}(PO{sub 4}){sub 2}, CaCO{sub 3}, and CaTiO{sub 3} were formed on MAO-treated surfaces prepared with CA concentrations of 0.2 and 0.3 M. Cell proliferation and differentiation increased with increasing CA concentration, with MC3T3-E1 cells exhibiting favorable morphologies for bone–implant integration. Conclusions: MAO coating improves the surface characteristics and

  1. Distribution of 210Pb activity concentrations in marine surface sediments within East Coast Peninsula Malaysia Exclusive Economic Zone (EEZ)

    International Nuclear Information System (INIS)

    Ahmad Sanadi Abu Bakar; Zaharudin Ahmad

    2010-01-01

    A sampling expedition into the East Coast Peninsula Malaysia Exclusive Economic Zone (EEZ) was carried in June 2008. Marine surface sediment samples were taken and the activity concentrations of 210 Pb have been determined. Its distribution was plotted and the findings show that the activity concentrations decline from north to south. On the other hand, the activity concentrations are increasing from west to east right to the edge of the EEZ. The highest activity concentrations were found to be near offshore oil platforms. The 210 Pb activity concentrations were found to be in the range of 18.3 - 123.1 Bq/ kg. (author)

  2. Monitoring glacier albedo as a proxy to derive summer and annual surface mass balances from optical remote-sensing data

    Science.gov (United States)

    Davaze, Lucas; Rabatel, Antoine; Arnaud, Yves; Sirguey, Pascal; Six, Delphine; Letreguilly, Anne; Dumont, Marie

    2018-01-01

    Less than 0.25 % of the 250 000 glaciers inventoried in the Randolph Glacier Inventory (RGI V.5) are currently monitored with in situ measurements of surface mass balance. Increasing this archive is very challenging, especially using time-consuming methods based on in situ measurements, and complementary methods are required to quantify the surface mass balance of unmonitored glaciers. The current study relies on the so-called albedo method, based on the analysis of albedo maps retrieved from optical satellite imagery acquired since 2000 by the MODIS sensor, on board the TERRA satellite. Recent studies revealed substantial relationships between summer minimum glacier-wide surface albedo and annual surface mass balance, because this minimum surface albedo is directly related to the accumulation-area ratio and the equilibrium-line altitude. On the basis of 30 glaciers located in the French Alps where annual surface mass balance data are available, our study conducted on the period 2000-2015 confirms the robustness and reliability of the relationship between the summer minimum surface albedo and the annual surface mass balance. For the ablation season, the integrated summer surface albedo is significantly correlated with the summer surface mass balance of the six glaciers seasonally monitored. These results are promising to monitor both annual and summer glacier-wide surface mass balances of individual glaciers at a regional scale using optical satellite images. A sensitivity study on the computed cloud masks revealed a high confidence in the retrieved albedo maps, restricting the number of omission errors. Albedo retrieval artifacts have been detected for topographically incised glaciers, highlighting limitations in the shadow correction algorithm, although inter-annual comparisons are not affected by systematic errors.

  3. Measuring variation of indoor radon concentration using bare nuclear tracks detectors, scintillation counters and surface barrier detectors

    International Nuclear Information System (INIS)

    Ishak, I.; Mahat, R.H.; Amin, Y.M.

    1996-01-01

    Bare LRI 15 nuclear track detectors , scintillators counter and surface barrier detectors were used to measured the indoor radon concentration in various location within two rooms. Spatial variation of the radon concentration is caused by positioning of the door, windows, furniture, cracks in the building and also distances from floor, wall and ceiling. It is found that the change in temperature are causing radon concentration to increase at certain time of the day

  4. Nanofluidic transport over a curved surface with viscous dissipation and convective mass flux

    Energy Technology Data Exchange (ETDEWEB)

    Mehmood, Zaffar; Iqbal, Z.; Azhar, Ehtsham; Maraj, E.N. [HITEC Univ., Taxila (Pakistan). Dept. of Mathematics

    2017-06-01

    This article is a numerical investigation of boundary layer flow of nanofluid over a bended stretching surface. The study is carried out by considering convective mass flux condition. Contribution of viscous dissipation is taken into the account along with thermal radiation. Suitable similarity transformations are employed to simplify the system of nonlinear partial differential equations into a system of nonlinear ordinary differential equations. Computational results are extracted by means of a shooting method embedded with a Runge-Kutta Fehlberg technique. Key findings include that velocity is a decreasing function of curvature parameter K. Moreover, Nusselt number decreases with increase in curvature of the stretching surface while skin friction and Sherwood number enhance with increase in K.

  5. Ultrasensitive probing of the protein resistance of PEG surfaces by secondary ion mass spectrometry

    DEFF Research Database (Denmark)

    Kingshott, P.; McArthur, S.; Thissen, H.

    2002-01-01

    The highly sensitive surface analytical techniques X-ray photoelectron spectroscopy (XPS) and time-of-flight static secondary ion mass spectrometry (ToF-SIMS) were used to test the resistance of poly(ethylene glycol) (PEG) coatings towards adsorption of lysozyme (LYS) and fibronectin (FN). PEG...... temperature to maximise the graft density of the PEG chains. XPS showed that the grafted density of PEG chains was slightly higher on the allylamine surface. XPS detected no adsorption of either protein on either PEG coating. ToF-SIMS analysis, on the other hand, found, in the positive ion spectra, minute...... but statistically significant signals assignable to amino acid fragment ions from both proteins adsorbed to the lower density PEG coating and from LYS but not FN on the higher density PEG coating. Negative ion spectra contained relatively more intense protein fragment ion signals for the lower density PEG coating...

  6. Conformational Analysis of Proteins in Highly Concentrated Solutions by Dialysis-Coupled Hydrogen/Deuterium Exchange Mass Spectrometry

    DEFF Research Database (Denmark)

    Houde, Damian; Esmail Nazari, Zeinab; Bou-Assaf, George M

    2016-01-01

    for these phenomena can be due to short range electrostatic and/or hydrophobic protein-protein interactions. Hydrogen/deuterium exchange mass spectrometry (HDX-MS) is a useful tool for investigating protein conformation, dynamics, and interactions. However, "traditional" continuous dilution labeling HDX......-MS experiments have limited utility for the direct analysis of solutions with high concentrations of protein. Here, we present a dialysis-based HDX-MS (di-HDX-MS) method as an alternative HDX-MS labeling format, which takes advantage of passive dialysis rather than the classic dilution workflow. We applied...

  7. SURFACE BRIGHTNESS PROFILES OF DWARF GALAXIES. II. COLOR TRENDS AND MASS PROFILES

    Energy Technology Data Exchange (ETDEWEB)

    Herrmann, Kimberly A. [Penn State Mont Alto, 1 Campus Drive, Mont Alto, PA 17237 (United States); Hunter, Deidre A. [Lowell Observatory, 1400 West Mars Hill Road, Flagstaff, AZ 86001 (United States); Elmegreen, Bruce G., E-mail: kah259@psu.edu, E-mail: dah@lowell.edu, E-mail: bge@us.ibm.com [IBM T. J. Watson Research Center, 1101 Kitchawan Road, Yorktown Heights, NY 10598 (United States)

    2016-06-01

    In this second paper of a series, we explore the B  −  V , U  −  B , and FUV−NUV radial color trends from a multi-wavelength sample of 141 dwarf disk galaxies. Like spirals, dwarf galaxies have three types of radial surface brightness profiles: (I) single exponential throughout the observed extent (the minority), (II) down-bending (the majority), and (III) up-bending. We find that the colors of (1) Type I dwarfs generally become redder with increasing radius, unlike spirals which have a blueing trend that flattens beyond ∼1.5 disk scale lengths, (2) Type II dwarfs come in six different “flavors,” one of which mimics the “U” shape of spirals, and (3) Type III dwarfs have a stretched “S” shape where the central colors are flattish, become steeply redder toward the surface brightness break, then remain roughly constant beyond, which is similar to spiral Type III color profiles, but without the central outward bluing. Faint (−9 >  M{sub B}  > −14) Type II dwarfs tend to have continuously red or “U” shaped colors and steeper color slopes than bright (−14 >  M{sub B}  > −19) Type II dwarfs, which additionally have colors that become bluer or remain constant with increasing radius. Sm dwarfs and BCDs tend to have at least some blue and red radial color trend, respectively. Additionally, we determine stellar surface mass density (Σ) profiles and use them to show that the break in Σ generally remains in Type II dwarfs (unlike Type II spirals) but generally disappears in Type III dwarfs (unlike Type III spirals). Moreover, the break in Σ is strong, intermediate, and weak in faint dwarfs, bright dwarfs, and spirals, respectively, indicating that Σ may straighten with increasing galaxy mass. Finally, the average stellar surface mass density at the surface brightness break is roughly 1−2  M {sub ⊙} pc{sup −2} for Type II dwarfs but higher at 5.9  M {sub ⊙} pc{sup −2} or 27  M {sub ⊙} pc{sup −2} for

  8. Atmospheric summer teleconnections and Greenland Ice Sheet surface mass variations: insights from MERRA-2

    International Nuclear Information System (INIS)

    Lim, Young-Kwon; Schubert, Siegfried D; Molod, Andrea M; Cullather, Richard I; Zhao, Bin; Nowicki, Sophie M J; Lee, Jae N; Velicogna, Isabella

    2016-01-01

    The relationship between leading atmospheric teleconnection patterns and Greenland Ice Sheet (GrIS) temperature, precipitation, and surface mass balance (SMB) are investigated for the last 36 summers (1979–2014) based on Modern-Era Retrospective analysis for Research and Applications version 2 reanalyses. The results indicate that the negative phase of both the North Atlantic Oscillation (NAO) and Arctic Oscillation, associated with warm and dry conditions for the GrIS, lead to SMB decreases within 0–1 months. Furthermore, the positive phase of the East Atlantic (EA) pattern often lags the negative NAO, reflecting a dynamical linkage between these modes that acts to further enhance the warm and dry conditions over the GrIS, leading to a favorable environment for enhanced surface mass loss. The development of a strong negative NAO in combination with a strong positive EA in recent years leads to significantly larger GrIS warming compared to when the negative NAO occurs in combination with a negative or weak positive EA (0.69 K versus 0.13 K anomaly). During 2009 and 2011, weakened (as compared to conditions during the severe surface melt cases of 2010 and 2012) local high pressure blocking produced colder northerly flow over the GrIS inhibiting warming despite the occurrence of a strong negative NAO, reflecting an important role for the EA during those years. In particular, the EA acts with the NAO to enhance warming in 2010 and 2012, and weaken high pressure blocking in 2009 and 2011. In general, high pressure blocking primarily impacts the western areas of the GrIS via advective temperature increases, while changes in net surface radiative fluxes account for both western and eastern GrIS temperature changes. (letter)

  9. Monitoring of nutrients concentration in surface waters of small mid-field water bodies in agricultural watershed

    Directory of Open Access Journals (Sweden)

    Katarzyna Ligocka

    2018-04-01

    Full Text Available Studies were conducted on surface waters of mid-field ponds in agricultural watershed. The resarch were aimed to perform introductory assessment of ammoniacal nitrogen's and nitric nitrogen's aswell as phosphates concentrations in surface waters. The studies have been performed from March to October, 2015 to 2017. The highest concentration of phosphates were detected in year 2017, whereas the highest concentrations of these were experienced in June in every year. The lowest concentration of phosphates were detected in the first year of studies (2015. The average concentration of phosphate got higher every year. Phosphates' concentrations got higher from March to October, however, the decline were experienced in later period. Conducted research confirmed the dependence, that in lower temperatures the concentrations of ammonia cal nitrogen were generally lower than in the months with higher average temperature. The highest average concentration of ammonia cal nitrogen (0,29 mg•kg -1 was detected in the first year of studies (2015. Average concentrations of nitric nitrogen’s fluctuates from from 0,15 to 0,24 mg•kg -1 . In every year, the concentrations of nitrates were highest in June. The lowest concentrations of nitrates in 2015 and 2016 were experienced in August, and in July of 2017.

  10. Mass concentrations and indoor-outdoor relationships of PM in selected educational buildings in Niš, Serbia

    Directory of Open Access Journals (Sweden)

    Kovačević Renata

    2015-01-01

    Full Text Available Mass concentrations of particulate matter (PM fractions were measured in educational buildings in the city of Niš, Republic of Serbia. Two sampling campaigns were conducted in winter periods. The first campaign was in the period from 21 February to 15 April 2010 at the Faculty of Occupational Safety (FOS and the second campaign was from 20 March to 4 April 2013 at the primary school Vožd Karađorđe (VK. PM measurements were carried out with low volume samplers Sven/Leckel LVS3. The average daily PM10 concentration inside the FOS (47.0 ±21.8 μg/m3 was lower than PM10 concentration in outdoor air (50.7 ±28.1 μg/m3. The average daily PM10 concentration inside the VK (54.6 ± 17.6 μg/m3 was higher than in outdoor air (47.9 ± 22.8 μg/m3. The 24 hours average PM10 concentrations at FOS exceeded the EU limit value (50 mg/m3 during 34 % of days outdoors, and 39 % of days indoors. The 24 hours average PM10 concentrations at VK exceeded the limit value during 35 % of days outdoors, and 53 % of days indoors. The 24 hours average PM2.5 concentrations at VK exceeded the WHO daily mean guideline value (25 mg/m3 during 71 % of days outdoors, and 88 % of days indoors. The average PM10 I/O ratio at VK was 1.57 during teaching hours, and 1.00 during no teaching hours. Similarly, average PM2.5 I/O ratio at VK was 1.11 during teaching hours and 0.90 during no teaching hours. Average daily PM2.5/PM10 ratio in the ambient air at VK was 0.87, and 0.82 at FOS. Very strong correlations between the indoor and outdoor PM concentrations were observed at VK during no teaching hours (r>0.8. Moderate to strong negative correlations were found between the wind speed and PM at both schools. High outdoor PM concentrations and resuspension of particles are probably the most possible reasons for the elevated indoor PM concentrations found in the study. [Projekat Ministartsva nauke Republike Srbije, br. III42008: Evaluation of Energy Performances and Indoor Environment

  11. Mineral composition and dry mass production of the corn plants in response to phosphorus sources and aluminum concentration

    Directory of Open Access Journals (Sweden)

    Marcelo Augusto Batista

    2009-06-01

    Full Text Available The corn plants were evaluated with different phosphate fertilizer sources and aluminum (Al concentrations in a sandy substrate. A totally randomized experiment design was set up with two corn plants in the pots containing 2 kg of a sandy substrate, two phosphate sources (Triple Super Phosphate - TSP or Arad Phosphate - AP and four Al concentrations. When Al concentrations increased, pH (CaCl2 substrate values decreased. There was an increase in the calcium and phosphorus contents in the sandy substrates that received the TSP and AP sources. The calcium, magnesium, phosphorus, and potassium concentrations of the corn plant's shoot were higher in the TSP than without P and AP sources. When the Al concentration increased, the concentration values of the former elements decreased. The dry mass production of the corn plants responded positively to P sources. As the Al concentration increased, the dry mass values decreased significantly in the TSP source.Foram avaliadas plantas de milho submetidas a diferentes fontes de fertilizantes fosfatados e diferentes concentrações de alumínio em um substrato de areia. O experimento foi conduzido com duas plantas por vaso contendo 2 kg de areia, duas fontes de fósforo (Fosfato Supertriplo -TSP ou Fosfato de Arad -AP e quatro concentrações de Al. Com o aumento das concentrações de Al houve diminuição dos valores de pH (CaCl2 do substrato. Os valores de cálcio e fósforo aumentaram no substrato nos tratamentos com TSP e AP. As concentrações de cálcio, magnésio, fósforo e de potássio das plantas de milho foram maiores em TSP do que nos tratamentos sem P ou com AP. Como o aumento da concentração de Al observou-se redução na concentração de cálcio, magnésio, fósforo e de potássio nas plantas. A produção de massa seca da parte aérea respondeu positivamente com as fontes de P. Com o aumentou da concentração de Al os valores de massa seca diminuíram significativamente com TSP.

  12. Surface deformation induced by water pumping for construction of Mass Rapid Transportation in Taipei basin

    Science.gov (United States)

    Hu, J. C.; Wu, P. C.; Tung, H.; Tsai, M. C.

    2017-12-01

    In 1968, there were 2,200 wells in the Taipei Basin used for water supply to meet the requirement of high population density. The overuse of ground water lead to the land subsidence rate up to 5 cm/yr. Although the government had already begun to limit groundwater pumping since 1968, the groundwater in the Taipei Basin demonstrated temporary fluctuation induced by pumping water for large deep excavation site or engineering usage. The previous study based on precise leveling suggested that the surface deformation was highly associated with the recovery of water level. In 1989, widespread uplift dominated in Taipei basin due to the recovery of ground water Table. In this study, we use 37 high-resolution X-band COSMO-SkyMed radar images from May 2011 to April 2015 to characterize deformation pattern in the period of construction of Mass Rapid Transportation (MRT). We also use 30 wells and 380 benchmarks of precise leveling in Taipei basin to study the correlation of surface deformation and change of ground water table. The storability is roughly constant across most of the aquifer with values between 0.8 x 10-4 and 1.3 x 10-3. Moreover, the high water pumping in two major aquifers, Jignme and Wuku Foramtions, before the underground construction for MRT led to inflict surface deformation and no time delay observed for surface deformation during the water pumping. It implies that the poro-elastic effect dominates in major aquifers in Taipei basin.

  13. Fractional-Slot Surface Mounted PM Motors with Concentrated Windings for HEV Traction Drives

    Energy Technology Data Exchange (ETDEWEB)

    Bailey, J.M.

    2005-10-24

    High-power density and efficiency resulting from elimination of rotor windings and reduced magnetic-flux losses have made the rare earth permanent magnet (PM) motor a leading candidate for the Department of Energy's Office of FreedomCAR and Vehicle Technologies (FCVTs) traction drive motor. These traction drives are generally powered by radial-gap motors, having the magnets on or embedded in a rotating cylinder separated from the inside surface of a slotted cylindrical stator by an annular gap. The two main types of radial-gap PM rotors are those with magnets mounted on the surface of a supporting back iron, called PM surface mounted (PMSM) motors, and those with magnets mounted in slots in the rotor, called interior PM (IPM) motors. Most early PM motor research was on the PMSM motor, which was thought to have an inherently low stator inductance. A low stator inductance can lead to currents dangerously exceeding rated current as the back-emf across the inductance increases with speed; consequently, part of the attempted solution has been to increase the stator inductance to reduce the rate of current rise. Although analysis suggested that there should be no problem designing sufficiently high stator inductance into PMSMs, attempts to do so were often not successful and a motor design was sought that would have a higher intrinsic inductance. Commercial research at Toyota has focused on IPM motors because they can achieve a high-saliency ratio, which helps them operate over a high constant power speed ratio (CPSR), but they are more difficult to fabricate. The Oak Ridge National Laboratory's (ORNL) position has been to continue research on brushless direct current (dc) motors (BDCMs) because of ease of fabrication and increased power output. Recently there has been a revival of interest in a fractional-slot PMSMs [15] made with concentrated windings because they possess three important features. First, they can increase the motor's inductance

  14. Planetesimal Initial Mass Functions and Creation Rates Under Turbulent Concentration Using Scale-Dependent Cascades

    Science.gov (United States)

    Cuzzi, J. N.; Hartlep, T.; Estrada, P.

    2016-01-01

    The initial accretion of primitive bodies from freely-floating nebula particles remains problematic. Traditional growth-by-sticking models in turbulent nebulae encounter a "meter-size barrier" due to both drift and destruction, or even a millimeter-to-centimeter-size "bouncing" barrier. Recent suggestions have been made that some "lucky" particles might be able to outgrow the collision and/or drift barriers, and lead to so-called "streaming instabilities" or SI. However, new full models of growth by sticking in the presence of radial drift show that lucky particles (the largest particles, at the tail of the size distribution, that grow beyond the nominal fragmentation and drift barriers) are far too rare to lead to any collective effects such as streaming or gravitational instabilities. Thus we need to focus on typical radii gamma(sub M) which contain most of the mass. Our models of disks with weak-to-moderate turbulence, which include all the most recent experimental constraints on collisional growth, erosion, bouncing, and fragmentation, as well as radial drift, find that growth stalls quite generally at sizes gamma(sub M) which are too small to settle into layers which are dense enough for any collective effects (streaming or gravitational instabilities) to arise. Even if growth by sticking could somehow breach the nominal barriers (perhaps if the actual sticking or strength is larger than current estimates for pure ice or pure silicate, with specific grain sizes), turbulent nebulae present subsequent formidable obstacles to incremental growth through the 1-10km size range. On the other hand, non-turbulent nebulae alpha is less than 10(Sup -4).

  15. Modulation of ATP/ADP concentration at the endothelial surface by shear stress: effect of flow recirculation.

    Science.gov (United States)

    Choi, Hyo Won; Ferrara, Katherine W; Barakat, Abdul I

    2007-04-01

    The extracellular presence of the adenine nucleotides ATP and ADP induces calcium mobilization in vascular endothelial cells (ECs). ATP/ADP concentration at the EC surface is determined by a balance of convective-diffusive transport to and from the EC surface, hydrolysis by ectonucleotidases at the cell surface, and flow-induced ATP release from ECs. Our previous numerical simulations in a parallel plate geometry had demonstrated that flow-induced ATP release has a profound effect on nucleotide concentration at the EC surface. In the present study, we have extended the modeling to probe the impact of flow separation and recirculation downstream of a backward facing step (BFS) on ATP/ADP concentration at the EC surface. The results show that for both steady and pulsatile flow over a wide range of wall shear stresses, the ATP+ADP concentration at the EC surface is considerably lower within the flow recirculation region than in areas of undisturbed flow outside the recirculation zone. Pulsatile flow also leads to sharp temporal gradients in nucleotide concentration. If confirmed experimentally, the present findings suggest that disturbed and undisturbed flow may affect EC calcium mobilization differently. Such differences might, in turn, contribute to the observed endothelial dysfunction in regions of disturbed flow.

  16. Distribution of Mercury Concentrations in Tree Rings and Surface Soils Adjacent to a Phosphate Fertilizer Plant in Southern Korea.

    Science.gov (United States)

    Jung, Raae; Ahn, Young Sang

    2017-08-01

    This study aimed to determine mercury concentrations in tree rings and surface soils at distances of 4, 26 and 40 km from a fertilizer plant located in Yeosu City, Korea. Mercury concentrations in all tree rings were low prior to the establishment of the plant in 1977 and became elevated thereafter. The highest average mercury concentration in the tree rings was 11.96 ng g -1 at the Yeosu site located nearest to the plant, with the lowest average mercury concentration of 4.45 ng g -1 at the Suncheon site furthest away from the plant. In addition, the highest mercury content in the surface soil was 108.51 ng cm -3 at the Yeosu site, whereas the lowest mercury content in the surface soil was 31.47 ng cm -3 at the Suncheon site. The mercury levels decreased gradually with increasing distance from the plant.

  17. Conformational Analysis of Proteins in Highly Concentrated Solutions by Dialysis-Coupled Hydrogen/Deuterium Exchange Mass Spectrometry

    Science.gov (United States)

    Houde, Damian; Nazari, Zeinab E.; Bou-Assaf, George M.; Weiskopf, Andrew S.; Rand, Kasper D.

    2016-04-01

    When highly concentrated, an antibody solution can exhibit unusual behaviors, which can lead to unwanted properties, such as increased levels of protein aggregation and unusually high viscosity. Molecular modeling, along with many indirect biophysical measurements, has suggested that the cause for these phenomena can be due to short range electrostatic and/or hydrophobic protein-protein interactions. Hydrogen/deuterium exchange mass spectrometry (HDX-MS) is a useful tool for investigating protein conformation, dynamics, and interactions. However, "traditional" continuous dilution labeling HDX-MS experiments have limited utility for the direct analysis of solutions with high concentrations of protein. Here, we present a dialysis-based HDX-MS (di-HDX-MS) method as an alternative HDX-MS labeling format, which takes advantage of passive dialysis rather than the classic dilution workflow. We applied this approach to a highly concentrated antibody solution without dilution or significant sample manipulation, prior to analysis. Such a method could pave the way for a deeper understanding of the unusual behavior of proteins at high concentrations, which is highly relevant for development of biopharmaceuticals in industry.

  18. Quantitative estimation of hydrogen concentration on the Ni3Al specimens surface in the process of hydrogen release

    International Nuclear Information System (INIS)

    Katano, Gen; Sano, Shogo; Saito, Hideo; Mori, Minoru

    2000-01-01

    The method to calculate the hydrogen concentration in metal specimens is given by tritium counts with the liquid scintillation counter. As segments to measure, Ni 3 Al intermetallic compound crystals were used. Tritium was charged to crystals with the method of cathode charging. The charged tritium was transported by diffusion and released from specimen surface. The tritium releasing rate was calculated from the increasing rate of tritium activity. Then the concentration of hydrogen at the surface was calculated from tritium counts. The outcome showed that the hydrogen concentration decreases at specimens surface by elapsed time. Then, the behavior of tritium diffusion was affected by doped boron (up to 0.235 atom% B and 0.470 atom% B) in Ni 3 Al crystals. As the amount of boron increased, the tritium diffusion coefficient decreased. And the hydrogen concentration varied with the amount of boron. After passing enough time, the hydrogen concentration in crystals with boron was much larger than the one without boron. Since it is very likely that the hydrogen concentration is affected by the number of hydrogen sites in the crystal, it is obvious judging by these phenomena, that by doping boron, numbers of hydrogen trapping sites were created. As the hydrogen distribution becomes homogenous after passing enough time, it is possible to measure the hydrogen concentration in all the crystals from β-ray counts at specimens surface. (author)

  19. Metal concentrations in surface water and sediments from Pardo River, Brazil: human health risks.

    Science.gov (United States)

    Alves, Renato I S; Sampaio, Carolina F; Nadal, Martí; Schuhmacher, Marta; Domingo, José L; Segura-Muñoz, Susana I

    2014-08-01

    Pardo River (Brazil) is suffering from an important anthropogenic impact due to the pressure of highly populated areas and the influence of sugarcane cultivation. The objective of the present study was to determine the levels of 13 trace elements (As, Be, Cd, Cr, Cu, Pb, Mn, Hg, Ni, Tl, Sn, V and Zn) in samples of surface water and sediments from the Pardo River. Furthermore, the human health risks associated with exposure to those metals through oral intake and dermal absorption were also evaluated. Spatial and seasonal trends of the data were closely analyzed from a probabilistic approach. Manganese showed the highest mean concentrations in both water and sediments, remarking the incidence of the agricultural activity and the geological characteristics within the basin. Thallium and arsenic were identified as two priority pollutants, being the most important contributors to the Hazard Index (HI). Since non-carcinogenic risks due to thallium exposure slightly exceeded international guidelines (HI>1), a special effort should be made on this trace element. However, the current concentrations of arsenic, a carcinogenic element, were in accordance to acceptable lifetime risks. Nowadays, there is a clear increasing growth in human population and economic activities in the Pardo River, whose waters have become a serious strategic alternative for the potential supply of drinking water. Therefore, environmental monitoring studies are required not only to assure that the current state of pollution of Pardo River does not mean a risk for the riverside population, but also to assess the potential trends in the environmental levels of those elements. Copyright © 2014 Elsevier Inc. All rights reserved.

  20. Rapid Adjustments Cause Weak Surface Temperature Response to Increased Black Carbon Concentrations

    Science.gov (United States)

    Stjern, Camilla Weum; Samset, Bjørn Hallvard; Myhre, Gunnar; Forster, Piers M.; Hodnebrog, Øivind; Andrews, Timothy; Boucher, Olivier; Faluvegi, Gregory; Iversen, Trond; Kasoar, Matthew; Kharin, Viatcheslav; Kirkevâg, Alf; Lamarque, Jean-François; Olivié, Dirk; Richardson, Thomas; Shawki, Dilshad; Shindell, Drew; Smith, Christopher J.; Takemura, Toshihiko; Voulgarakis, Apostolos

    2017-11-01

    We investigate the climate response to increased concentrations of black carbon (BC), as part of the Precipitation Driver Response Model Intercomparison Project (PDRMIP). A tenfold increase in BC is simulated by nine global coupled-climate models, producing a model median effective radiative forcing of 0.82 (ranging from 0.41 to 2.91) W m-2, and a warming of 0.67 (0.16 to 1.66) K globally and 1.24 (0.26 to 4.31) K in the Arctic. A strong positive instantaneous radiative forcing (median of 2.10 W m-2 based on five of the models) is countered by negative rapid adjustments (-0.64 W m-2 for the same five models), which dampen the total surface temperature signal. Unlike other drivers of climate change, the response of temperature and cloud profiles to the BC forcing is dominated by rapid adjustments. Low-level cloud amounts increase for all models, while higher-level clouds are diminished. The rapid temperature response is particularly strong above 400 hPa, where increased atmospheric stabilization and reduced cloud cover contrast the response pattern of the other drivers. In conclusion, we find that this substantial increase in BC concentrations does have considerable impacts on important aspects of the climate system. However, some of these effects tend to offset one another, leaving a relatively small median global warming of 0.47 K per W m-2—about 20% lower than the response to a doubling of CO2. Translating the tenfold increase in BC to the present-day impact of anthropogenic BC (given the emissions used in this work) would leave a warming of merely 0.07 K.

  1. Kernel density surface modelling as a means to identify significant concentrations of vulnerable marine ecosystem indicators.

    Directory of Open Access Journals (Sweden)

    Ellen Kenchington

    Full Text Available The United Nations General Assembly Resolution 61/105, concerning sustainable fisheries in the marine ecosystem, calls for the protection of vulnerable marine ecosystems (VME from destructive fishing practices. Subsequently, the Food and Agriculture Organization (FAO produced guidelines for identification of VME indicator species/taxa to assist in the implementation of the resolution, but recommended the development of case-specific operational definitions for their application. We applied kernel density estimation (KDE to research vessel trawl survey data from inside the fishing footprint of the Northwest Atlantic Fisheries Organization (NAFO Regulatory Area in the high seas of the northwest Atlantic to create biomass density surfaces for four VME indicator taxa: large-sized sponges, sea pens, small and large gorgonian corals. These VME indicator taxa were identified previously by NAFO using the fragility, life history characteristics and structural complexity criteria presented by FAO, along with an evaluation of their recovery trajectories. KDE, a non-parametric neighbour-based smoothing function, has been used previously in ecology to identify hotspots, that is, areas of relatively high biomass/abundance. We present a novel approach of examining relative changes in area under polygons created from encircling successive biomass categories on the KDE surface to identify "significant concentrations" of biomass, which we equate to VMEs. This allows identification of the VMEs from the broader distribution of the species in the study area. We provide independent assessments of the VMEs so identified using underwater images, benthic sampling with other gear types (dredges, cores, and/or published species distribution models of probability of occurrence, as available. For each VME indicator taxon we provide a brief review of their ecological function which will be important in future assessments of significant adverse impact on these habitats here

  2. Re-assessment of recent (2008–2013 surface mass balance over Dome Argus, Antarctica

    Directory of Open Access Journals (Sweden)

    Minghu Ding

    2016-04-01

    Full Text Available At Dome Argus, East Antarctica, the surface mass balance (SMB from 2008 to 2013 was evaluated using 49 stakes installed across a 30×30 km area. Spatial analysis showed that at least 12 and 20 stakes are needed to obtain reliable estimates of SMB at local scales (a few hundred square metres and regional scales (tens of square kilometres, respectively. The estimated annual mean SMB was 22.9±5.9 kg m−2 yr−1, including a net loss by sublimation of −2.22±0.02 kg m−2 yr−1 and a mass gain by deposition of 1.37±0.01 kg m−2 yr−1. Therefore, ca. 14.3% of precipitation was modified after deposition, which should be considered when interpreting snow or ice core records produced by future drilling projects. The surface snow density and SMB in the western portion of Dome Argus are higher than in other areas, and these differences are likely related to the katabatic wind, which is strengthened by topography in this sector. A new digital elevation model (DEM of Dome Argus was generated, confirming that both peaks of the dome can be considered as the summit of the East Antarctic Ice Sheet. Findings from this study should be valuable for validating SMB estimates obtained from regional climate models and DEMs established using remote-sensing data.

  3. Upper limit of the muon-neutrino mass and charged-pion mass from the momentum analysis of a surface muon beam

    International Nuclear Information System (INIS)

    Kettle, P.R.

    1996-01-01

    Using a surface muon beam and a magnetic spectrometer equipped with a position-sensitive detector, we have measured the muon momentum from pion decay at rest π + →μ + ν μ , to be p μ + =(29.79200±0.00011)MeV/c. This value together with the muon mass and the favoured pion mass leads to an upper limit of 0.17 MeV (90%CL) for the muon-neutrino mass. (author) 4 figs., 5 refs

  4. Upper limit of the muon-neutrino mass and charged-pion mass from the momentum analysis of a surface muon beam

    Energy Technology Data Exchange (ETDEWEB)

    Kettle, P.R. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1996-11-01

    Using a surface muon beam and a magnetic spectrometer equipped with a position-sensitive detector, we have measured the muon momentum from pion decay at rest {pi}{sup +}{yields}{mu}{sup +}{nu}{sub {mu}}, to be p{sub {mu}{sup +}}=(29.79200{+-}0.00011)MeV/c. This value together with the muon mass and the favoured pion mass leads to an upper limit of 0.17 MeV (90%CL) for the muon-neutrino mass. (author) 4 figs., 5 refs.

  5. Metallographic examination of hardened layers after surface treatments by highly concentrated plasma jet

    Directory of Open Access Journals (Sweden)

    Сергій Савелійович Самотугін

    2017-07-01

    Full Text Available The microstructure of carbon and alloy steels with various carbon contents before and after the gradient hardening by means of highly concentrated plasma jet have been investigated. It is shown that the resulting structure after the surface hardening has a substantially smaller grain size as compared to the bulk hardening. The steels with different carbon content, that is hypoeutectic steels 45 and 50HN, eutectic steels – M76, U8, hypereutectoid steels – 90HF, U10 have been researched. Processing was carried out under the optimal conditions to ensure the highest hardness of the surface without melting. Metalgraphical studies were carried out using optical and scanning electron microscopes. High-dispersed martensite is the main structural component for hypoeutectic steels. Despite the fact that the heating temperature and the cooling rate in different parts of the plasma exposure zone differ greatly, the structure of the tempered zone is uniform by both the degree of dispersion and by the values of hardness. Plasma treatment of eutectic steels results in fine-grained structure of martensite of mainly lamellar morphology. High-dispersed martensite with microparticles of secondary carbides is characteristic of the hardened zones for hypereutectic steels. But austenite grains do not grow at heating as it usually happens in bulk hardening. The structure of the transition zone corresponds to part-hardened steels. So excess ferrite as well as martensite retains in hypoeutectic steels while excess cementite retains in hypereutectic steels. Eutectic steels are free from the intercritical interval, and the transition zone does not practically develop, there being a very sharp boundary between the zone of full hardening and the parent metal. Due to this structure of the plasma hardening zone of the surface layer there arises 3,5...4,5-fold increase in the hardness of the steel as compared with the normalized condition. This is due to the increase in

  6. Graphene Surface Acoustic Wave Sensor for Simultaneous Detection of Charge and Mass.

    Science.gov (United States)

    Okuda, Satoshi; Ono, Takao; Kanai, Yasushi; Ikuta, Takashi; Shimatani, Masaaki; Ogawa, Shinpei; Maehashi, Kenzo; Inoue, Koichi; Matsumoto, Kazuhiko

    2018-01-26

    We have combined a graphene field-effect transistor (GFET) and a surface acoustic wave (SAW) sensor on a LiTaO 3 substrate to create a graphene surface acoustic wave (GSAW) sensor. When a SAW propagates in graphene, an acoustoelectric current (I A ) flows between two attached electrodes. This current has unique electrical characteristics, having both positive and negative peak values with respect to the electrolyte-gate voltage (V Eg ) in solution. We found that I A is controlled by V Eg and the amplitude of the SAW. It was also confirmed that the GSAW sensor detects changes of electrical charge in solution like conventional GFET sensors. Furthermore, the detection of amino-group-modified microbeads was performed by employing a GSAW sensor in a phthalate buffer solution at pH 4.1. The hole current peak shifted to the lower left in the I A -V Eg characteristics. The left shift was caused by charge detection by the GFET and can be explained by an increase of amino groups that have positive charges at pH 4.1. In contrast, the downward shift is thought to be due to a reduction in the amplitude of the propagating SAW because of an increase in the mass loading of microbeads. This mass loading was detected by the SAW sensor. Thus, we have demonstrated that the GSAW sensor is a transducer capable of the simultaneous detection of charge and mass, which indicates that it is an attractive platform for highly sensitive and multifunctional solution sensing.

  7. Atmospheric river impacts on Greenland Ice Sheet surface melt and mass balance

    Science.gov (United States)

    Mattingly, K.; Mote, T. L.

    2017-12-01

    Mass loss from the Greenland Ice Sheet (GrIS) has accelerated during the early part of the 21st Century. Several episodes of widespread GrIS melt in recent years have coincided with intense poleward moisture transport by atmospheric rivers (ARs), suggesting that variability in the frequency and intensity of these events may be an important driver of the surface mass balance (SMB) of the GrIS. ARs may contribute to GrIS surface melt through the greenhouse effect of water vapor, the radiative effects of clouds, condensational latent heating within poleward-advected air masses, and the energy provided by liquid precipitation. However, ARs may also provide significant positive contributions to GrIS SMB through enhanced snow accumulation. Prior research on the role of ARs in Arctic climate has consisted of case studies of ARs associated with major GrIS melt events or examined the effects of poleward moisture flux on Arctic sea ice. In this study, a long-term (1979-2016) record of intense moisture transport events affecting Greenland is compiled using a conventional AR identification algorithm as well as a self-organizing map (SOM) classification applied to integrated water vapor transport (IVT) data from several atmospheric reanalysis datasets. An analysis of AR effects on GrIS melt and SMB is then performed with GrIS surface melt data from passive microwave satellite observations and the Modèle Atmosphérique Régional (MAR) regional climate model. Results show that meltwater production is above normal during and after AR impact days throughout the GrIS during all seasons, with surface melt enhanced most by strong (> 85th percentile IVT) and extreme (> 95th percentile IVT) ARs. This relationship holds at the seasonal scale, as the total amount of water vapor transported to the GrIS by ARs is significantly greater during above-normal melt seasons. ARs exert a more complex influence on SMB. Normal (< 85th percentile IVT) ARs generally do not have a substantial impact on

  8. Extending and refining the mass surface around $^{208}$Pb by high-precision Penning-trap mass spectrometry with ISOLTRAP

    CERN Multimedia

    Herfurth, F; Stora, T; Blaum, K; Beck, D; Kowalska, M; Schwarz, S; Stanja, J; Herlert, A J; Yamaguchi, T

    We propose high-precision mass spectrometry of nuclides around the doubly magic $^{208}$Pb. On the neutron-rich side, we aim to extend the knowledge of Fr, At, Hg, and Au masses to study the robustness of the N = 126 shell closure and to provide mass data necessary for modeling the rapid-neutron-capture process. On the proton-rich side, we aim at high-resolution mass spectrometry of selected Au, At, and Fr isotopes to verify the predicted existence of very low-lying isomeric states. The proposal will make use of newly-available laser-ionization schemes for Au and At. Finally, the recently implemented multi-reflection time-of-flight mass separator for auxiliary isobaric purification now allows measurements which were not feasible before.

  9. Effect of different concentrations of sodium hyaluronate on the ocular surface change of dry eye in New Zealand rabbits

    Directory of Open Access Journals (Sweden)

    Shuang-Yong Wang

    2015-10-01

    Full Text Available AIM:To observe the effect of different concentrations of sodium hyaluronate on ocular surface change of dry eye. METHODS: New Zealand rabbits with dry eye was prepared and treated with 0.1% and 0.3% sodium hyaluronate drops fluid respectively, which were regarded as low concentration treatment group(group Band high concentration treatment group(group Crespectively. However, the rabbits treated with saline were regarded as control group(group A. And then, corneal fluorescein staining, Schirmer test, conjunctival goblet cells, mucin expression and histological changes were observed.RESULTS: On D7 and D14 after treatment, corneal fluorescein staining scores were lower in group B and group C than that in group A(PP PCONCLUSION: The sodium hyaluronate can improve ocular surface damage of dry eye in New Zealand rabbits. The high concentration of sodium hyaluronate has better effect than low concentration.

  10. Effect of energy source, salt concentration and loading force on colloidal interactions between Acidithiobacillus ferrooxidans cells and mineral surfaces.

    Science.gov (United States)

    Diao, Mengxue; Nguyen, Tuan A H; Taran, Elena; Mahler, Stephen M; Nguyen, Anh V

    2015-08-01

    The surface appendages and extracellular polymeric substances of cells play an important role in the bacterial adhesion process. In this work, colloidal forces and nanomechanical properties of Acidithiobacillus ferrooxidans (A. f) interacted with silicon wafer and pyrite (FeS2) surfaces in solutions of varying salt concentrations were quantitatively examined using the bacterial probe technique with atomic force microscopy. A. f cells were cultured with either ferrous sulfate or elemental sulfur as key energy sources. Our results show that A. f cells grown with ferrous ion and elemental sulfur exhibit distinctive retraction force vs separation distance curves with stair-step and saw tooth shapes, respectively. During the approach of bacterial probes to the substrate surfaces, surface appendages and biopolymers of cells are sequentially compressed. The conformations of surface appendages and biopolymers are significantly influenced by the salt concentrations. Copyright © 2015 Elsevier B.V. All rights reserved.

  11. The effect of different fiber concentrations on the surface roughness of provisional crown and fixed partial denture resin.

    Science.gov (United States)

    Zortuk, Mustafa; Kılıc, Kerem; Uzun, Gulay; Ozturk, Ahmet; Kesim, Bulent

    2008-07-01

    The aim of this study was to investigate surface roughness in provisional crown acrylics, after polishing, reinforced with different concentrations of glass fibers. A total of 48 disk-shaped specimens were prepared using autopolymerizing acrylic resin. These specimens were divided into four groups according to the level of glass fiber added: Group A (no fiber), Group B (0.5%), Group C (1%) and Group D (2%). After polishing the specimens, an average surface roughness (Ra) value was calculated using a profilometer from four randomly selected points on the surface. A significant difference was determined among the surface roughness values of provisional crown resins to which different concentrations of fiber had been added (Pprovisional crown and fixed partial denture resin with glass fibers increases surface roughness.

  12. Integration of Multiplexed Microfluidic Electrokinetic Concentrators with a Morpholino Microarray via Reversible Surface Bonding for Enhanced DNA Hybridization.

    Science.gov (United States)

    Martins, Diogo; Wei, Xi; Levicky, Rastislav; Song, Yong-Ak

    2016-04-05

    We describe a microfluidic concentration device to accelerate the surface hybridization reaction between DNA and morpholinos (MOs) for enhanced detection. The microfluidic concentrator comprises a single polydimethylsiloxane (PDMS) microchannel onto which an ion-selective layer of conductive polymer poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) ( PSS) was directly printed and then reversibly surface bonded onto a morpholino microarray for hybridization. Using this electrokinetic trapping concentrator, we could achieve a maximum concentration factor of ∼800 for DNA and a limit of detection of 10 nM within 15 min. In terms of the detection speed, it enabled faster hybridization by around 10-fold when compared to conventional diffusion-based hybridization. A significant advantage of our approach is that the fabrication of the microfluidic concentrator is completely decoupled from the microarray; by eliminating the need to deposit an ion-selective layer on the microarray surface prior to device integration, interfacing between both modules, the PDMS chip for electrokinetic concentration and the substrate for DNA sensing are easier and applicable to any microarray platform. Furthermore, this fabrication strategy facilitates a multiplexing of concentrators. We have demonstrated the proof-of-concept for multiplexing by building a device with 5 parallel concentrators connected to a single inlet/outlet and applying it to parallel concentration and hybridization. Such device yielded similar concentration and hybridization efficiency compared to that of a single-channel device without adding any complexity to the fabrication and setup. These results demonstrate that our concentrator concept can be applied to the development of a highly multiplexed concentrator-enhanced microarray detection system for either genetic analysis or other diagnostic assays.

  13. Confirmatory determination of organochlorine pesticides in surface waters using LC/APCI/tandem mass spectrometry open diamond.

    Science.gov (United States)

    Chusaksri, S; Sutthivaiyakit, S; Sutthivaiyakit, P

    2006-03-01

    A confirmatory method for the determination of organochlorine pesticides (OCPs) and their metabolites (endrin, alpha-endosulfan, beta-endosulfan, endosulfan sulfate, heptachlor, heptachlor epoxide, 2,4'-DDD, 4,4'-DDD, 2,4'-DDE 4,4'-DDE, 2,4'-DDT, and 4,4'-DDT) in surface waters using liquid chromatography /APCI/tandem mass spectrometry has been developed. Chromatographic separation was carried out on a ChromSpher 5 Pesticide column using a gradient elution with mobile phase 1mM ammonium acetate-acetonitrile. Endrin, alpha-endosulfan, beta-endosulfan , endosulfan sulfate, heptachlor and heptachlor epoxide were determined in the negative ionization mode, while the rest compounds in positive ionization mode. For the identification of the analytes, two multireaction monitoring transitions were selected per compounds except for the heptachlor which selected ion monitoring was used. The linearity of the optimized method ranges after SPE concentration, from 0.009 to 30.60 microgL(-1) with correlation coefficients greater than 0.99. The method recovery values varied from 72 to 119 % for the different fortification levels . The developed method was successfully applied to determine OCPs and their metabolites in surface water samples collected near paddy fields in growing season of rice, at year 2005 in Pathumthani province, Thailand. Endosulfan sulfate was detected in five out of seven samples and three of them could be quantitated in the range of 0.31 to 0.50 microgL(-1).

  14. Modelling non-adiabatic effects in H{sub 3}{sup +}: Solution of the rovibrational Schrödinger equation with motion-dependent masses and mass surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Mátyus, Edit, E-mail: matyus@chem.elte.hu [Institute of Chemistry, Eötvös University, P.O. Box 32, H-1518 Budapest 112 (Hungary); Szidarovszky, Tamás [MTA-ELTE Research Group on Complex Chemical Systems, Pázmány Péter sétány 1/A, H-1117 Budapest (Hungary); Császár, Attila G., E-mail: csaszar@chem.elte.hu [Institute of Chemistry, Eötvös University, P.O. Box 32, H-1518, Budapest 112, Hungary and MTA-ELTE Research Group on Complex Chemical Systems, Pázmány Péter sétány 1/A, H-1117 Budapest (Hungary)

    2014-10-21

    Introducing different rotational and vibrational masses in the nuclear-motion Hamiltonian is a simple phenomenological way to model rovibrational non-adiabaticity. It is shown on the example of the molecular ion H{sub 3}{sup +}, for which a global adiabatic potential energy surface accurate to better than 0.1 cm{sup −1} exists [M. Pavanello, L. Adamowicz, A. Alijah, N. F. Zobov, I. I. Mizus, O. L. Polyansky, J. Tennyson, T. Szidarovszky, A. G. Császár, M. Berg et al., Phys. Rev. Lett. 108, 023002 (2012)], that the motion-dependent mass concept yields much more accurate rovibrational energy levels but, unusually, the results are dependent upon the choice of the embedding of the molecule-fixed frame. Correct degeneracies and an improved agreement with experimental data are obtained if an Eckart embedding corresponding to a reference structure of D{sub 3h} point-group symmetry is employed. The vibrational mass of the proton in H{sub 3}{sup +} is optimized by minimizing the root-mean-square (rms) deviation between the computed and recent high-accuracy experimental transitions. The best vibrational mass obtained is larger than the nuclear mass of the proton by approximately one third of an electron mass, m{sub opt,p}{sup (v)}=m{sub nuc,p}+0.31224 m{sub e}. This optimized vibrational mass, along with a nuclear rotational mass, reduces the rms deviation of the experimental and computed rovibrational transitions by an order of magnitude. Finally, it is shown that an extension of the algorithm allowing the use of motion-dependent masses can deal with coordinate-dependent mass surfaces in the rovibrational Hamiltonian, as well.

  15. Pteropods are excellent recorders of surface temperature and carbonate ion concentration.

    Science.gov (United States)

    Keul, N; Peijnenburg, K T C A; Andersen, N; Kitidis, V; Goetze, E; Schneider, R R

    2017-10-03

    Pteropods are among the first responders to ocean acidification and warming, but have not yet been widely explored as carriers of marine paleoenvironmental signals. In order to characterize the stable isotopic composition of aragonitic pteropod shells and their variation in response to climate change parameters, such as seawater temperature, pteropod shells (Heliconoides inflatus) were collected along a latitudinal transect in the Atlantic Ocean (31° N to 38° S). Comparison of shell oxygen isotopic composition to depth changes in the calculated aragonite equilibrium oxygen isotope values implies shallow calcification depths for H. inflatus (75 m). This species is therefore a good potential proxy carrier for past variations in surface ocean properties. Furthermore, we identified pteropod shells to be excellent recorders of climate change, as carbonate ion concentration and temperature in the upper water column have dominant influences on pteropod shell carbon and oxygen isotopic composition. These results, in combination with a broad distribution and high abundance, make the pteropod species studied here, H. inflatus, a promising new proxy carrier in paleoceanography.

  16. On the Control of Solute Mass Fluxes and Concentrations Below Fields Irrigated With Low-Quality Water: A Numerical Study

    Science.gov (United States)

    Russo, David

    2017-11-01

    The main goal of this study was to test the capability of irrigation water-based and soil-based approaches to control nitrate and chloride mass fluxes and concentrations below the root zone of agricultural fields irrigated with treated waste water (TWW). Using numerical simulations of flow and transport in relatively a fine-textured, unsaturated, spatially heterogeneous, flow domain, scenarios examined include: (i) irrigating with TWW only (REF); (ii) irrigation water is substituted between TWW and desalinized water (ADW); (iii) soil includes a capillary barrier (CB) and irrigating with TWW only (CB + TWW); and (iv) combination of (ii) and a CB (CB + ADW). Considering groundwater quality protection, plausible goals are: (i) to minimize solute discharges leaving the root zone, and, (ii) to maximize the probability that solute concentrations leaving the root zone will not exceed a prescribed, critical value. Results of the analyses suggest that in the case of a seasonal crop (a corn field) subject to irrigations only, with respect to the first goal, the CB + TWW and CB + ADW scenarios provide similar, excellent results, better than the ADW scenario; with respect to the second goal, however, the CB + ADW scenario gave substantially better results than the CB + TWW scenario. In the case a multiyear, perennial crop (a citrus orchard), subject to a sequence of irrigation and rainfall periods, for both solutes, and, particularly, nitrate, with respect to the two goals, both the ADW and CB + ADW scenarios perform better than the CB + TWW scenario. As compared with the REF and CB + TWW scenarios, the ADW and CB + ADW scenarios substantially reduce nitrogen mass fluxes to the groundwater and to the atmosphere, and, essentially, did not reduce nitrogen mass fluxes to the trees. Similar results, even better, were demonstrated for a relatively coarse-textured, spatially heterogeneous soil.

  17. Surface Tension Estimates for Droplet Formation in Slurries with Low Concentrations of Hydrophobic Particles, Polymer Flocculants or Surface-Active Contaminants

    Energy Technology Data Exchange (ETDEWEB)

    Gauglitz, Phillip A.; Mahoney, Lenna A.; Blanchard, Jeremy; Bamberger, Judith A.

    2011-06-10

    In support of the K-Basin project, Pacific Northwest National Laboratory (PNNL) was requested to evaluate the appropriate surface tension value to use in models predicting the formation of droplets from spray leaks of K-Basin slurries. The specific issue was whether it was more appropriate to use the surface tension of pure water in model predictions for all plausible spray leaks or to use a lower value. The surface tension of K-Basin slurries is potentially affected not only by particles but by low concentrations of nonionic polyacrylamide flocculant and perhaps by contaminants with surfactant properties, which could decrease the surface tension below that of water. A lower surface tension value typically results in smaller droplets being formed with a larger fraction of droplets in the respirable size range, so using the higher surface tension value of pure water is not conservative and thus needs a strong technical basis.

  18. Annual and Seasonal Glacier-Wide Surface Mass Balance Quantified from Changes in Glacier Surface State: A Review on Existing Methods Using Optical Satellite Imagery

    Directory of Open Access Journals (Sweden)

    Antoine Rabatel

    2017-05-01

    Full Text Available Glaciers are one of the terrestrial essential climate variables (ECVs as they respond very sensitively to climate change. A key driver of their response is the glacier surface mass balance that is typically derived from field measurements. It deserves to be quantified over long time scales to better understand the accumulation and ablation processes at the glacier surface and their relationships with inter-annual changes in meteorological conditions and long-term climate changes. Glaciers with in situ monitoring of surface mass balance are scarce at the global scale, and satellite remote sensing provides a powerful tool to increase the number of monitored glaciers. In this study, we present a review of three optical remote sensing methods developed to quantify seasonal and annual glacier surface mass balances. These methodologies rely on the multitemporal monitoring of the end-of-summer snow line for the equilibrium-line altitude (ELA method, the annual cycle of glacier surface albedo for the albedo method and the mapping of the regional snow cover at the seasonal scale for the snow-map method. Together with a presentation of each method, an application is illustrated. The ELA method shows promising results to quantify annual surface mass balance and to reconstruct multi-decadal time series. The other two methods currently need a calibration on the basis of existing in situ data; however, a generalization of these methods (without calibration could be achieved. The two latter methods show satisfying results at the annual and seasonal scales, particularly for the summer surface mass balance in the case of the albedo method and for the winter surface mass balance in the case of the snow-map method. The limits of each method (e.g., cloud coverage, debris-covered glaciers, monsoon-regime and cold glaciers, their complementarities and the future challenges (e.g., automating of the satellite images processing, generalization of the methods needing

  19. Properties of the surface snow in Princess Elizabeth Land, East Antarctica - climate and non-climate dependent variability of the surface mass balance and stable water isotopic composition

    Science.gov (United States)

    Vladimirova, D.; Ekaykin, A.; Lipenkov, V.; Popov, S. V.; Petit, J. R.; Masson-Delmotte, V.

    2017-12-01

    Glaciological and meteorological observations conducted during the past four decades in Princess Elizabeth Land, East Antarctica, are compiled. The database is used to investigate spatial patterns of surface snow isotopic composition and surface mass balance, including detailed information near subglacial lake Vostok. We show diverse relationships between snow isotopic composition and surface temperature. In the most inland part (elevation 3200-3400 m a.s.l.), surface snow isotopic composition varies independently from surface temperature, and is closely related to the distance to the open water source (with a slope of 0.98±0.17 ‰ per 100 km). Surface mass balance values are higher along the ice sheet slope, and relatively evenly distributed inland. The minimum values of snow isotopic composition and surface mass balance are identified in an area XX km southwestward from Vostok station. The spatial distribution of deuterium excess delineates regions influenced by the Indian Ocean and Pacific Ocean air masses, with Vostok area being situated close to their boundary. Anomalously high deuterium excess values are observed near Dome A, suggesting high kinetic fractionation for its moisture source, or specifically high post-deposition artifacts. The dataset is available for further studies such as the assessment of skills of general circulation or regional atmospheric models, and the search for the oldest ice.

  20. Assessing modeled Greenland surface mass balance in the GISS Model E2 and its sensitivity to surface albedo

    Science.gov (United States)

    Alexander, Patrick; LeGrande, Allegra N.; Koenig, Lora S.; Tedesco, Marco; Moustafa, Samiah E.; Ivanoff, Alvaro; Fischer, Robert P.; Fettweis, Xavier

    2016-04-01

    The surface mass balance (SMB) of the Greenland Ice Sheet (GrIS) plays an important role in global sea level change. Regional Climate Models (RCMs) such as the Modèle Atmosphérique Régionale (MAR) have been employed at high spatial resolution with relatively complex physics to simulate ice sheet SMB. Global climate models (GCMs) incorporate less sophisticated physical schemes and provide outputs at a lower spatial resolution, but have the advantage of modeling the interaction between different components of the earth's oceans, climate, and land surface at a global scale. Improving the ability of GCMs to represent ice sheet SMB is important for making predictions of future changes in global sea level. With the ultimate goal of improving SMB simulated by the Goddard Institute for Space Studies (GISS) Model E2 GCM, we compare simulated GrIS SMB against the outputs of the MAR model and radar-derived estimates of snow accumulation. In order to reproduce present-day climate variability in the Model E2 simulation, winds are constrained to match the reanalysis datasets used to force MAR at the lateral boundaries. We conduct a preliminary assessment of the sensitivity of the simulated Model E2 SMB to surface albedo, a parameter that is known to strongly influence SMB. Model E2 albedo is set to a fixed value of 0.8 over the entire ice sheet in the initial configuration of the model (control case). We adjust this fixed value in an ensemble of simulations over a range of 0.4 to 0.8 (roughly the range of observed summer GrIS albedo values) to examine the sensitivity of ice-sheet-wide SMB to albedo. We prescribe albedo from the Moderate Resolution Imaging Spectroradiometer (MODIS) MCD43A3 v6 to examine the impact of a more realistic spatial and temporal variations in albedo. An age-dependent snow albedo parameterization is applied, and its impact on SMB relative to observations and the RCM is assessed.

  1. Concentrations of the UV filter ethylhexyl methoxycinnamate in the aquatic compartment: a comparison of modelled concentrations for Swiss surface waters with empirical monitoring data.

    Science.gov (United States)

    Straub, Jürg Oliver

    2002-05-10

    UV filters in sunscreens and cosmetics protect the skin from damage through UV radiation. Many tonnes per year of UV filters are being used in Europe and will be present, at least seasonally, in detectable concentrations in surface waters similar to common pharmaceutically active substances. Predicted environmental concentrations (PECs) of ethylhexyl methoxycinnamate (EHMC; CAS 5466-77-3) were extrapolated for Switzerland, taking into consideration substance-specific environmental fate data and marketing estimates, by crude worst-case reckoning and by applying two environmental models (Mackay Level III; USES 3.0), both configured for Swiss hydrological and area data. By worst-case reckoning the summer PEC is 70.8-81.3 ng/l while for the remaining 8 months of the year the PEC is 13.1-15.1 ng/l. The Level III model results in concentrations of 2.4 ng/l during the summer and 0.44 ng/l during the rest of the year, while the USES 3.0 model gives an average PEC for the whole year of 7.6 ng/l. Pooling summer monitoring data (90 single analyses) from the River Rhine below Basel in the year 1997 (Water Protection Board of Basel) and from Lakes Zurich and Hüttner in 1998 (Poiger et al., in preparation) allowed a derivation of a probabilistic median concentration of 4.6 ng/l, a 95th-percentile concentration of 18.6 ng/l and a 99th-percentile concentration of 33.5 ng/l. The 6-fold range from the median value to the maximum calls for caution in interpreting published monitoring concentrations. Comparison of modelled PECs with realistic median concentrations shows that crude reckoning overestimates actual concentrations by a factor of about 10, probably through insufficient consideration of (further) degradation of EHMC in sewage works, surface waters, sediments or river banks. Both computer models, in contrast, are within the same order of magnitude as the actual summer concentrations. Based on the available data, both these environmental fate and distribution models give

  2. Increased MMA concentration and body mass index are associated with spontaneous abortion in Brazilian women: a pilot study.

    Science.gov (United States)

    Guerra-Shinohara, Elvira M; Pereira, Perla M; Kubota, Ananka M; Silva, Thaiomara A; Reis, Jucilene L; Miyashita, Gerson S; D'Almeida, Vânia; Allen, Robert H; Stabler, Sally P

    2010-03-01

    The pathophysiology of spontaneous abortion is complex and may involve the interaction of genetic and environmental factors. We evaluated the predictors of spontaneous abortion in Brazilian pregnant women. The effects of age, gestational age, body mass index (BMI), cigarette smoking, alcohol ingestion, use of multivitamins and concentrations of vitamins (folate, cobalamin and vitamin B6) and vitamin-dependent metabolites were analyzed. Study population included 100 healthy women that attended pre-natal care in 2 health centers of Sao Paulo, Brazil, and in whom pregnancy outcome was known. Folate and cobalamin status was measured in blood specimens collected between 4 and 16 weeks. The genotypes for 8 gene polymorphisms were evaluated by PCR-RFLP. Eighty-eight women had normal pregnancy outcome (Group 1), while 12 experienced a miscarriage after blood collection (Group 2). Increased methylmalonic acid (MMA) concentrations were found in Group 2 (median [25th-75th percentile]=274 [149-425] nmol/l) relative to Group 1 (138 [98-185]) (PMMA, cystathionine, body mass index (BMI), cigarette smoking, alcohol ingestion and use of multivitamins the risk of abortion was significantly associated with MMA (OR [95% CI]=3.80 [1.36, 10.62] per quartile increase in MMA), BMI (OR [95% CI]=5.49 [1.29, 23.39] per quartile) and gestational age (OR [95% CI]=0.10 [0.01, 0.77] per increase of interval in gestational age). Increased serum MMA and BMI concentrations are associated with spontaneous abortion in Brazilian women. Copyright 2009 Elsevier B.V. All rights reserved.

  3. Evaluation of number concentration quantification by single-particle inductively coupled plasma mass spectrometry: microsecond vs. millisecond dwell times.

    Science.gov (United States)

    Abad-Álvaro, Isabel; Peña-Vázquez, Elena; Bolea, Eduardo; Bermejo-Barrera, Pilar; Castillo, Juan R; Laborda, Francisco

    2016-07-01

    The quality of the quantitative information in single-particle inductively coupled plasma mass spectrometry (SP-ICP-MS) depends directly on the number concentration of the nanoparticles in the sample analyzed, which is proportional to the flux of nanoparticles through the plasma. Particle number concentrations must be selected in accordance with the data acquisition frequency, to control the precision from counting statistics and the bias, which is produced by the occurrence of multiple-particle events recorded as single-particle events. With quadrupole mass spectrometers, the frequency of data acquisition is directly controlled by the dwell time. The effect of dwell times from milli- to microseconds (10 ms, 5 ms, 100 μs, and 50 μs) on the quality of the quantitative data has been studied. Working with dwell times in the millisecond range, precision figures about 5 % were achieved, whereas using microsecond dwell times, the suitable fluxes of nanoparticles are higher and precision was reduced down to 1 %; this was independent of the dwell time selected. Moreover, due to the lower occurrence of multiple-nanoparticle events, linear ranges are wider when dwell times equal to or shorter than 100 μs are used. A calculation tool is provided to determine the optimal concentration for any instrument or experimental conditions selected. On the other hand, the use of dwell times in the microsecond range reduces significantly the contribution of the background and/or the presence of dissolved species, in comparison with the use of millisecond dwell times. Although the use of dwell times equal to or shorter than 100 μs offers improved performance working in single-particle mode, the use of conventional dwell times (3-10 ms) should not be discarded, once their limitations are known.

  4. Quantification of four artificial sweeteners in Finnish surface waters with isotope-dilution mass spectrometry.

    Science.gov (United States)

    Perkola, Noora; Sainio, Pirjo

    2014-01-01

    The artificial sweeteners sucralose (SCL), acesulfame (ACS), saccharin (SAC), and cyclamate (CYC) have been detected in environmental waters in Europe and North America. Higher environmental levels are expected in view of the increasing consumption of these food additives. In this study, an isotope-dilution mass spectrometry (IDMS) LC-MS/MS method was developed and validated for quantifying the four artificial sweeteners in boreal lakes (n = 3) and rivers (n = 12). The highest concentrations of ACS, SAC, CYC and SCL were 9,600, 490, 210 and 1000 ng/L, respectively. ACS and SAC were detected in all studied samples, and CYC and SCL in 98% and 56% of the samples. Seasonal trends of ACS and SAC were observed in some rivers. ACS and SCL concentrations in rivers correlated linearly with population equivalents of the wastewater treatment plants in the catchment areas, whereas SAC and CYC concentrations depend more on the source. Copyright © 2013 Elsevier Ltd. All rights reserved.

  5. In situ analysis of ion-induced polymer surface modification using secondary ion mass spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Okuji, Shigeto, E-mail: s-okuji@post.lintec.co.jp [Lintec Corporation, 5-14-42 Nishiki-cho, Warabi, Saitama 335-0005 (Japan); Quantum Beam Unit, National Institute for Materials Science, 3-13 Sakura, Tsukuba, Ibaraki 305-0003 (Japan); University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8577 (Japan); Kitazawa, Hideaki [Quantum Beam Unit, National Institute for Materials Science, 3-13 Sakura, Tsukuba, Ibaraki 305-0003 (Japan); Takeda, Yoshihiko, E-mail: TAKEDA.Yoshihiko@nims.go.jp [Quantum Beam Unit, National Institute for Materials Science, 3-13 Sakura, Tsukuba, Ibaraki 305-0003 (Japan); University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8577 (Japan)

    2016-06-15

    We have investigated the surface modification process consisting of ion irradiation immediately followed by exposure to ambient gas for three types of polymers having the same main chain, −C−C−, but different atoms bound to the main chain, using in situ secondary ion mass spectroscopy. The polymers’ surface was irradiated with 30 keV Au ions at a total fluence for up to 1 × 10{sup 17} cm{sup −2} and exposed to ambient gas in a ultra-high-vacuum chamber (1 × 10{sup −6} Pa) for 30 min after the ion irradiation. Low density polyethylene mainly exhibited a hydrogen dissociation during the ion irradiation and a recombination with hydrogen atoms by the exposure, polytetrafluoroethylene mainly showed a main chain scission and no recombination during the exposure, and polyvinylidene difluoride lost hydrogen and fluorine atoms by the ion irradiation and partially recombined with hydrogen and fluorine atoms upon the exposure. The deposited energy density on the polymer surfaces reflects the dependence of the modification on the incident ion species, Au or Ga ions.

  6. 21st century changes in the surface mass balance of the Greenland ice sheet simulated with the global model CESM

    Science.gov (United States)

    Vizcaíno, M.; Lipscomb, W. H.; Van den Broeke, M.

    2012-04-01

    We present here the first projections of 21st century surface mass balance change of the Greenland ice sheet simulated with the Community Earth System Model (CESM). CESM is a fully-coupled, global climate model developed at many research centers and universities, primarily in the U.S. The model calculates the surface mass balance in the land component (the Community Land Model, CLM), at the same resolution as the atmosphere (1 degree), with an energy-balance scheme. The snow physics included in CLM for non-glaciated surfaces (SNiCAR model, Flanner and Zender, 2005) are used over the ice sheet. The surface mass balance is calculated for 10 elevation classes, and then downscaled to the grid of the ice sheet model (5 km in this case) via vertical linear interpolation between elevation classes combined with horizontal bilinear interpolation. The ice sheet topography is fixed at present-day values for the simulations presented here. The use of elevation classes reduces computational costs while giving results that reproduce well the mass balance gradients at the steep margins of the ice sheet. The simulated present-day surface mass balance agrees well with results from regional models. We focus on the regional model RACMO (Ettema et al. 2009) to compare the results on 20th-century surface mass balance evolution and two-dimensional patterns. The surface mass balance of the ice sheet under RCP8.5. forcing becomes negative in the last decades of the 21st century. The equilibrium line becomes ~500 m higher on average. Accumulation changes are positive in the accumulation zone. We examine changes in refreezing, accumulation, albedo, surface fluxes, and the timing of the melt season.

  7. Lead concentrations and isotope ratios in street dust determined by electrothermal atomic absorption spectrometry and inductively coupled plasma mass spectrometry.

    Science.gov (United States)

    Nageotte, S M; Day, J P

    1998-01-01

    A major source of environmental lead, particularly in urban areas, has been from the combustion of leaded petrol. Street dust has previously been used to assess urban lead contamination, and the dust itself can also be a potential source of lead ingestion, particularly to children. The progressive reduction of lead in petrol, in recent years, would be expected to have been reflected in a reduction of lead in urban dust. We have tested this hypothesis by repeating an earlier survey of Manchester street dust and carrying out a comparable survey in Paris. Samples were collected from streets and parks, lead was extracted by digestion with concentrated nitric acid and determined by electrothermal atomic absorption spectrometry. Lead isotope ratios were measured by inductively coupled plasma mass spectrometry. Results for Manchester show that lead concentrations have fallen by about 40% (street dust averages, 941 micrograms g-1 (ppm) in 1975 down to 569 ppm in 1997). In Paris, the lead levels in street dust are much higher and significant differences were observed between types of street (not seen in Manchester). Additionally, lead levels in parks were much lower than in Manchester. Samples collected under the Eiffel Tower had very high concentrations and lead isotope ratios showed that this was unlikely to be fallout from motor vehicles but could be due to the paint used on the tower. Isotope ratios measurements also revealed that lead additives used in France and the UK come from different sources.

  8. In situ investigation of titanium nitride surface dynamics: The role of surface and bulk mass transport processes

    Science.gov (United States)

    Bareno, Javier

    NaCl-structure TiN and related transition-metal (TM) nitrides are widely used as hard wear-resistant coatings on cutting tools, diffusion-barriers in microelectronic devices, corrosion-resistant layers on mechanical components, and abrasion-resistant thin films on optics and architectural glass. Since the elastic and physical properties of TiN are highly anisotropic, controlling the microstructural and surface morphological evolution of polycrystalline TM nitride films is important for all of the above applications. In this thesis, I used in-situ high-temperature low-energy electron microscopy (LEEM) to gain insight into film growth and microstructure development dynamics by studying mass-transport processes occurring during annealing of three dimensional (3D) structures on TiN surfaces. Additionally, in order to extend the current understanding of nanostructure development in binary nitride films to more complex ternary TM-nitride-based nanocomposites, I employed in-situ scanning tunneling microscopy (STM) and low-energy electron diffraction (LEED), as well as ab-initio modeling, to investigate the atomic structure of the SiNx/TiN heterointerfaces which control the properties of SiNx-TiN nanocomposites. The LEEM studies of mass transport on TiN(111) focus on two specific surface morphologies which are observed to be present during growth of TiN single-crystals. (1) I investigated the temperature-dependent coarsening/decay kinetics of three-dimensional TiN island mounds on large (>1000 A) atomically-flat terraces; showing that TiN(111) steps are highly permeable and exhibit strong repulsive temperature-dependent step-step interactions that vary from 0.03 eV-A at 1559 K to 0.76 eV-A at 1651 K. (2) I studied the nucleation and growth of spiral steps originating at surface-terminated screw dislocations; I developed a model of spiral growth relating the emission rate of point defects from the bulk to the temperature-dependent spiral rotation frequency o(T); and I

  9. Elevation change of the Greenland Ice Sheet due to surface mass balance and firn processes, 1960-2014

    NARCIS (Netherlands)

    Kuipers Munneke, P.; Ligtenberg, S. R M; Noël, B. P Y; Howat, I. M.; Box, J. E.; Mosley-Thompson, E.; McConnell, J. R.; Steffen, K.; Harper, J. T.; Das, S. B.; Van Den Broeke, M. R.

    2015-01-01

    Observed changes in the surface elevation of the Greenland Ice Sheet are caused by ice dynamics, basal elevation change, basal melt, surface mass balance (SMB) variability, and by compaction of the overlying firn. The last two contributions are quantified here using a firn model that includes

  10. Greenland Surface Mass Balance as Simulated by the Community Earth System Model. Part II: Twenty-First-Century Changes

    NARCIS (Netherlands)

    Vizcaino, M.; Lipscomb, W.H.; Sacks, W.J.; van den Broeke, M.R.

    2014-01-01

    This study presents the first twenty-first-century projections of surface mass balance (SMB) changes for the Greenland Ice Sheet (GIS) with the Community Earth System Model (CESM), which includes a new ice sheet component. For glaciated surfaces, CESM includes a sophisticated calculation of energy

  11. Determination of platinum surface contamination in veterinary and human oncology centres using inductively coupled plasma mass spectrometry

    NARCIS (Netherlands)

    Janssens, T.; Brouwers, E. E M; de Vos, J. P.; de Vries, N.; Schellens, J. H M; Beijnen, J. H.

    2015-01-01

    The objective of this study was to determine the surface contamination with platinum-containing antineoplastic drugs in veterinary and human oncology centres. Inductively coupled plasma mass spectrometry was used to measure platinum levels in surface samples. In veterinary and human oncology

  12. Assessment of the surface mass balance along the K-transect (Greenland ice sheet) from satellite-derived albedos

    NARCIS (Netherlands)

    Oerlemans, J.; Greuell, W.

    This paper explores the potential of using satellite-derived albedos to estimate the surface mass balance of the Kangerlussuaq transect (K-transect; Greenland ice sheet). We first retrieved surface albedos from Advanced Very High Resolution Radar data by using, among other techniques, a new

  13. Measurement of total and free docetaxel concentration in human plasma by ultra-performance liquid chromatography-tandem mass spectrometry.

    Science.gov (United States)

    Rigo-Bonnin, Raül; Cobo-Sacristán, Sara; Gonzalo-Diego, Núria; Colom, Helena; Muñoz-Sánchez, Carmen; Urruticoechea, Ander; Falo, Catalina; Alía, Pedro

    2016-01-05

    Docetaxel is a semi-synthetic taxane with cytotoxic anti-neoplastic activity and, currently used as anticancer agent in several types of cancer. Docetaxel is highly bound to plasma proteins, and this significantly determines its clearance and activity. Therefore, measurement of free docetaxel in plasma is pharmacologically important when pharmacokinetics is investigated. We developed and validated chromatographic methods by ultra-performance liquid chromatography-tandem mass spectrometry to measure total and free docetaxel concentration in human plasma. The final validated methods involved liquid-liquid extraction followed by dryness under nitrogen evaporation. To measure free docetaxel concentration, sample preparation was preceded by ultrafiltration. Chromatographic separation was achieved using an Acquity(®) UPLC(®) BEH™ (2.1×100 mm id, 1.7 μm) reverse-phase C18 column at a flow rate of 0.4 mL/min, using isocratic elution mode containing ammonium acetate/formic acid in water/methanol (30:70 v/v) as mobile phase. Docetaxel and its internal standard (paclitaxel) were detected by electrospray ionization mass spectrometry in positive ion multiple reaction monitoring mode using mass-to-charge (m/z) transitions of 808.3→527.0 (quantifier) and 808.3→509.0 (qualifier); and 854.3→569.0 (quantifier) and 854,3→509,0 (qualifier), respectively. The run time per sample was 3.5 min. The limits of quantification were 1,95 and 0.42 μg/L and linearity was observed between 1.95 and 1000 and 0.42-100 μg/L for total and free docetaxel, respectively. Coefficients of variation and absolute relative biases were less than 13.8% and 10.0%. Recovery values were greater than 79.4%. Evaluation of the matrix effect showed ion suppression and no carry-over was observed. The validated methods could be useful for both therapeutic drug monitoring and pharmacokinetic studies. They could be applied to daily clinical laboratory practice to measure the concentration of total and free

  14. Mass balance of the Greenland ice sheet - a study of ICESat data, surface density and firn compaction modelling

    DEFF Research Database (Denmark)

    Sørensen, L. S.; Simonsen, Sebastian Bjerregaard; Nielsen, K.

    2010-01-01

    in estimating the mass balance of the Greenland ice sheet. We find firn dynamics and surface densities to be important factors in deriving the mass loss from remote sensing altimetry. The volume change derived from ICESat data is corrected for firn compaction, vertical bedrock movement and an intercampaign...... elevation bias in the ICESat data. Subsequently, the corrected volume change is converted into mass change by surface density modelling. The firn compaction and density models are driven by a dynamically downscaled simulation of the HIRHAM5 regional climate model using ERA-Interim reanalysis lateral......ICESat has provided surface elevation measurements of the ice sheets since the launch in January 2003, resulting in a unique data set for monitoring the changes of the cryosphere. Here we present a novel method for determining the mass balance of the Greenland ice sheet derived from ICESat...

  15. Radionuclide mass transfer rates from a pinhole in a waste container for an inventory-limited and a constant concentration source

    International Nuclear Information System (INIS)

    LeNeveu, D.M.

    1996-03-01

    Analytical solutions for transient and steady state diffusive mass transfer rates from a pinhole in a waste container are developed for constant concentration and inventory-limited source conditions. Mass transport in three media are considered, inside the pinhole (medium 2), outside the container (medium 3) and inside the container (medium 1). Simple equations are developed for radionuclide mass transfer rates from a pinhole. It is shown that the medium with the largest mass transfer resistance need only be considered to provide a conservative estimate of mass transfer rates. (author) 11 refs., 3 figs

  16. Producing the surface structures with required properties with the help of concentrated fluxes of particles

    International Nuclear Information System (INIS)

    Li, I.P.; Rukhlyada, N.Ya.

    2005-01-01

    Pulsed plasma treatment has been proposed for modification of the surface layers of metal-matrix-porous cathodes and parts of electronic-vacuum devices. Surface plasma treatment leads to improvement of thermal emission properties of effective cathodes: work function decreases, secondary electron emission coefficient increases, and surface emission uniformity improves. With the help of pulse plasma, surface smoothing as well as formation of composite coatings can be done [ru

  17. Arsenic, cadmium and lead concentrations in Yerba mate commercialized in Southern Brazil by inductively coupled plasma mass spectrometry

    Directory of Open Access Journals (Sweden)

    Lisia Maria Gobbo dos Santos

    2017-12-01

    Full Text Available ABSTRACT: “Mate” or “Yerba Mate” (Ilex paraguariensis is a native South American plant, commonly consumed in Argentina, Paraguay, Uruguay and southern Brazil. Recent research has detected the presence of many vitamins and metals in this plant. Theses metals are also part of yerba mate’s mineral composition, due to soil and water contamination by pesticides and fertilizers, coal and oil combustion, vehicle emissions, mining, smelting, refining and the incineration of urban and industrial waste. Regardless of their origin, some inorganic elements, such as arsenic, cadmium and lead, are considered toxic, since they accumulate in all plant tissues and are, thus, introduced into the food chain. In this context, the aim of the present study was to determine and compare arsenic, cadmium, lead concentrations in 104 samples of yerba mate (Ilex paraguariensis marketed, and consumed in three southern Brazilian States, namely Paraná (PR, Santa Catarina (SC and Rio Grande do Sul (RS. Each element was determined by inductively coupled plasma mass spectrometry (ICP-MS, on a Nexion 300D equipment (Perkin Elmer. As, Cd and Pb concentrations in yerba mate leaves ranged from 0.015 to 0.15mg kg-1, 0.18 to 1.25mg kg-1 and 0.1 to 1.20mg kg-1, respectively. Regarding Cd, 84% of the samples from RS, 63% from PR and 75% from SC showed higher concentrations than the maximum permissible limit of 0.4mg kg-1 established by the Brazilian National Sanitary Surveillance Agency (ANVISA, while 7% of the samples from RS and 5% from PR were unsatisfactory for Pb. Concentrations were below the established ANVISA limit of 0.6mg kg-1 for all samples.

  18. Surface Mass Balance Distributions: Downscaling of Coarse Climates to drive Ice Sheet Models realistically

    Science.gov (United States)

    Rodehacke, Christian; Mottram, Ruth; Langen, Peter; Madsen, Marianne; Yang, Shuting; Boberg, Fredrik; Christensen, Jens

    2017-04-01

    The surface mass balance (SMB) is the most import boundary conditions for the state of glaciers and ice sheets. Hence its representation in numerical model simulations is of highest interest for glacier, ice cap and ice sheet modeling efforts. While descent SMB distributions of the current climate could be interfered with the help of various observation techniques and platforms, its construction for older past and future climates relies on input from spatially coarse resolved global climate models or reconstructions. These coarse SMB estimates with a footprint in the order of 100 km could hardly resolve the marginal ablations zones where the Greenland ice sheets, for instance, loses snow and ice. We present a downscaling method that is based on the physical calculation of the surface mass and energy balance. By the consequent application of universal and computationally cheap parameterizations we get an astonishing good representation of the SMB distribution including its marginal ablation zone. However the method has its limitations; for example wrong accumulation rates due to an insufficient precipitation field leaves its imprint on the SMB distribution. Also the still not satisfactory description of the bare ice albedo, in particular, in parts of Greenland is a challenge. We inspect our Greenland SMB fields' for various forcings and compare them with some widely used reference fields in the community to highlight the weakness and strength of our approach. We use the ERA-Interim reanalyzes period starting in 1979 directly as well as dynamically downscaled by our regional climate model HIRHAM (5 km resolution). Also SMB distributions obtained from the climate model EC-Earth with a resolution of T159 (approx. 125 km resolution in Greenland) are used either directly or downscaled with our regional climate model HIRHAM. Model-based End-of-the-century SMB estimates give an outlook of the future.

  19. Greenland ice sheet surface mass balance: evaluating simulations and making projections with regional climate models

    Directory of Open Access Journals (Sweden)

    J. G. L. Rae

    2012-11-01

    Full Text Available Four high-resolution regional climate models (RCMs have been set up for the area of Greenland, with the aim of providing future projections of Greenland ice sheet surface mass balance (SMB, and its contribution to sea level rise, with greater accuracy than is possible from coarser-resolution general circulation models (GCMs. This is the first time an intercomparison has been carried out of RCM results for Greenland climate and SMB. Output from RCM simulations for the recent past with the four RCMs is evaluated against available observations. The evaluation highlights the importance of using a detailed snow physics scheme, especially regarding the representations of albedo and meltwater refreezing. Simulations with three of the RCMs for the 21st century using SRES scenario A1B from two GCMs produce trends of between −5.5 and −1.1 Gt yr−2 in SMB (equivalent to +0.015 and +0.003 mm sea level equivalent yr−2, with trends of smaller magnitude for scenario E1, in which emissions are mitigated. Results from one of the RCMs whose present-day simulation is most realistic indicate that an annual mean near-surface air temperature increase over Greenland of ~ 2°C would be required for the mass loss to increase such that it exceeds accumulation, thereby causing the SMB to become negative, which has been suggested as a threshold beyond which the ice sheet would eventually be eliminated.

  20. Concentrations of Semivolatile Organic Compounds Associated with African Dust Air Masses in Mali, Cape Verde, Trinidad and Tobago, and the U.S. Virgin Islands, 2001-2008

    Science.gov (United States)

    Garrison, Virginia H.; Foreman, William T.; Genualdi, Susan A.; Majewski, Michael S.; Mohammed, Azad; Simonich, Staci Massey

    2011-01-01

    Every year, billions of tons of fine particles are eroded from the surface of the Sahara Desert and the Sahel of West Africa, lifted into the atmosphere by convective storms, and transported thousands of kilometers downwind. Most of the dust is carried west to the Americas and the Caribbean in the Saharan Air Layer (SAL). Dust air masses predominately impact northern South America during the Northern Hemisphere winter and the Caribbean and Southeastern United States in summer. Dust concentrations vary considerably temporally and spatially. In a dust source region (Mali), concentrations range from background levels of 575 micrograms per cubic meter (mu/u g per m3) to 13,000 mu/u g per m3 when visibility degrades to a few meters (Gillies and others, 1996). In the Caribbean, concentrations of 200 to 600 mu/u g per m3 in the mid-Atlantic and Barbados (Prospero and others, 1981; Talbot and others, 1986), 3 to 20 mu/u g per m3 in the Caribbean (Prospero and Nees, 1986; Perry and others, 1997); and >100 mu/u g per m3 in the Virgin Islands (this dataset) have been reported during African dust conditions. Mean dust particle size decreases as the SAL traverses from West Africa to the Caribbean and Americas as a result of gravitational settling. Mean particle size reaching the Caribbean is human lungs. A large body of literature has shown that increased PM2.5 concentrations are linked to increased cardiovascular/respiratory morbidity and mortality (for example, Dockery and others, 1993; Penn and others, 2005).

  1. The Effect of Different Fiber Concentrations on the Surface Roughness of Provisional Crown and Fixed Partial Denture Resin

    OpenAIRE

    Zortuk, Mustafa; K?l?c, Kerem; Uzun, Gulay; Ozturk, Ahmet; Kesim, Bulent

    2008-01-01

    Objectives The aim of this study was to investigate surface roughness in provisional crown acrylics, after polishing, reinforced with different concentrations of glass fibers. Methods A total of 48 disk-shaped specimens were prepared using autopolymerizing acrylic resin. These specimens were divided into four groups according to the level of glass fiber added: Group A (no fiber), Group B (0.5%), Group C (1%) and Group D (2%). After polishing the specimens, an average surface roughness (Ra) va...

  2. Diffusive mass transport in agglomerated glassy fallout from a near-surface nuclear test

    Science.gov (United States)

    Weisz, David G.; Jacobsen, Benjamin; Marks, Naomi E.; Knight, Kim B.; Isselhardt, Brett H.; Matzel, Jennifer E.

    2018-02-01

    Aerodynamically-shaped glassy fallout is formed when vapor phase constituents from the nuclear device are incorporated into molten carriers (i.e. fallout precursor materials derived from soil or other near-field environmental debris). The effects of speciation and diffusive transport of condensing constituents are not well defined in models of fallout formation. Previously we reported observations of diffuse micrometer scale layers enriched in Na, Fe, Ca, and 235U, and depleted in Al and Ti, at the interfaces of agglomerated fallout objects. Here, we derive the timescales of uranium mass transport in such fallout as it cools from 2500 K to 1500 K by applying a 1-dimensional planar diffusion model to the observed 235U/30Si variation at the interfaces. By modeling the thermal transport between the fireball and the carrier materials, the time of mass transport is calculated to be <0.6 s, <1 s, <2 s, and <3.5 s for fireball yields of 0.1 kt, 1 kt, 10 kt, and 100 kt respectively. Based on the calculated times of mass transport, a maximum temperature of deposition of uranium onto the carrier material of ∼2200 K is inferred (1σ uncertainty of ∼200 K). We also determine that the occurrence of micrometer scale layers of material enriched in relatively volatile Na-species as well as more refractory Ca-species provides evidence for an oxygen-rich fireball based on the vapor pressure of the two species under oxidizing conditions. These results represent the first application of diffusion-based modeling to derive material transport, thermal environments, and oxidation-speciation in near-surface nuclear detonation environments.

  3. Gaussian Process Model for Antarctic Surface Mass Balance and Ice Core Site Selection

    Science.gov (United States)

    White, P. A.; Reese, S.; Christensen, W. F.; Rupper, S.

    2017-12-01

    Surface mass balance (SMB) is an important factor in the estimation of sea level change, and data are collected to estimate models for prediction of SMB on the Antarctic ice sheet. Using Favier et al.'s (2013) quality-controlled aggregate data set of SMB field measurements, a fully Bayesian spatial model is posed to estimate Antarctic SMB and propose new field measurement locations. Utilizing Nearest-Neighbor Gaussian process (NNGP) models, SMB is estimated over the Antarctic ice sheet. An Antarctic SMB map is rendered using this model and is compared with previous estimates. A prediction uncertainty map is created to identify regions of high SMB uncertainty. The model estimates net SMB to be 2173 Gton yr-1 with 95% credible interval (2021,2331) Gton yr-1. On average, these results suggest lower Antarctic SMB and higher uncertainty than previously purported [Vaughan et al. (1999); Van de Berg et al. (2006); Arthern, Winebrenner and Vaughan (2006); Bromwich et al. (2004); Lenaerts et al. (2012)], even though this model utilizes significantly more observations than previous models. Using the Gaussian process' uncertainty and model parameters, we propose 15 new measurement locations for field study utilizing a maximin space-filling, error-minimizing design; these potential measurements are identied to minimize future estimation uncertainty. Using currently accepted Antarctic mass balance estimates and our SMB estimate, we estimate net mass loss [Shepherd et al. (2012); Jacob et al. (2012)]. Furthermore, we discuss modeling details for both space-time data and combining field measurement data with output from mathematical models using the NNGP framework.

  4. The Potential of The Synergy of Sunphotometer and Lidar Data to Validate Vertical Profiles of The Aerosol Mass Concentration Estimated by An Air Quality Model

    Directory of Open Access Journals (Sweden)

    Siomos N.

    2016-01-01

    Full Text Available Vertical profiles of the aerosol mass concentration derived by the Lidar/Radiometer Inversion Code (LIRIC, that uses combined sunphotometer and lidar data, were used in order to validate the aerosol mass concentration profiles estimated by the air quality model CAMx. Lidar and CIMEL measurements performed at the Laboratory of Atmospheric Physics of the Aristotle University of Thessaloniki, Greece (40.5N, 22.9E from the period 2013-2014 were used in this study.

  5. Exciton diffusion length and concentration of holes in MEH-PPV polymer using the surface voltage and surface photovoltage methods

    Czech Academy of Sciences Publication Activity Database

    Toušek, J.; Toušková, J.; Remeš, Zdeněk; Čermák, Jan; Kousal, J.; Kindl, Dobroslav; Kuřitka, I.

    2012-01-01

    Roč. 552, NOV (2012), s. 49-52 ISSN 0009-2614 R&D Projects: GA ČR(CZ) GBP108/12/G108 Institutional research plan: CEZ:AV0Z10100521 Keywords : surface photovoltage * Kelvin probe force microscopy * conjugated polymers Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 2.145, year: 2012

  6. The effect of sub-minimum inhibitory concentration of ciprofloxacin concentrations on enteroaggregative Escherichia coli and the role of the surface protein dispersin

    Energy Technology Data Exchange (ETDEWEB)

    Mortensen, Ninell P [ORNL; Fowlkes, Jason Davidson [ORNL; Trevino-Dopatka, Sonia [ORNL; Maggart, Michael J [ORNL; Boisen, Nadia [University of Virginia School of Medicine; Doktycz, Mitchel John [ORNL; Nataro, James [University of Virginia School of Medicine; Allison, David P [ORNL

    2011-01-01

    Enteroaggregative Escherichia coli (EAEC) are bacterial pathogens that cause watery diarrhea, which is often persistent and can be inflammatory. The antibiotic ciprofloxacin is used to treat EAEC infections, but a full understanding of the antimicrobial effects of ciprofloxacin is needed for more efficient treatment of bacterial infections. In this study, it was found that sub-minimum inhibitory concentrations (sub-MICs) of ciprofloxacin had an inhibitory effect on EAEC adhesion to glass and mammalian HEp-2 cells. It was also observed that bacterial surface properties play an important role in bacterial sensitivity to ciprofloxacin. In an EAEC mutant strain where the hydrophobic positively charged surface protein dispersin was absent, sensitivity to ciprofloxacin was reduced compared with the wild-type strain. Identified here are several antimicrobial effects of ciprofloxacin at sub-MIC concentrations indicating that bacterial surface hydrophobicity affects the response to ciprofloxacin. Investigating the effects of sub-MIC doses of antibiotics on targeted bacteria could help to further our understanding of bacterial pathogenicity and elucidate future antibiotic treatment modalities.

  7. Fine mapping the spatial distribution and concentration of unlabeled drugs within tissue micro-compartments using imaging mass spectrometry.

    Directory of Open Access Journals (Sweden)

    Anna Nilsson

    Full Text Available Readouts that define the physiological distributions of drugs in tissues are an unmet challenge and at best imprecise, but are needed in order to understand both the pharmacokinetic and pharmacodynamic properties associated with efficacy. Here we demonstrate that it is feasible to follow the in vivo transport of unlabeled drugs within specific organ and tissue compartments on a platform that applies MALDI imaging mass spectrometry to tissue sections characterized with high definition histology. We have tracked and quantified the distribution of an inhaled reference compound, tiotropium, within the lungs of dosed rats, using systematic point by point MS and MS/MS sampling at 200 microm intervals. By comparing drug ion distribution patterns in adjacent tissue sections, we observed that within 15 min following exposure, tiotropium parent MS ions (mass-to-charge; m/z 392.1 and fragmented daughter MS/MS ions (m/z 170.1 and 152.1 were dispersed in a concentration gradient (80 fmol-5 pmol away from the central airways into the lung parenchyma and pleura. These drug levels agreed well with amounts detected in lung compartments by chemical extraction. Moreover, the simultaneous global definition of molecular ion signatures localized within 2-D tissue space provides accurate assignment of ion identities within histological landmarks, providing context to dynamic biological processes occurring at sites of drug presence. Our results highlight an important emerging technology allowing specific high resolution identification of unlabeled drugs at sites of in vivo uptake and retention.

  8. Biobased carbon content of resin extracted from polyethylene composite by carbon-14 concentration measurements using accelerator mass spectrometry.

    Science.gov (United States)

    Taguchi, Kazuhiro; Kunioka, Masao; Funabashi, Masahiro; Ninomiya, Fumi

    2014-01-01

    An estimation procedure for biobased carbon content of polyethylene composite was studied using carbon-14 ((14)C) concentration ratios as measured by accelerated mass spectrometry (AMS). Prior to the measurement, additives and fillers in composites should be removed because they often contain a large amount of biobased carbon and may shift the estimation. Samples of resin with purity suitable for measurement were isolated from composites with a Soxhlet extractor using heated cyclohexanone. After cooling of extraction solutions, the resin was recovered as a fine semi-crystalline precipitate, which was easily filtered. Recovery rates were almost identical (99%), even for low-density polyethylene and linear low-density polyethylene, which may have lower crystallinity. This procedure could provide a suitable approach for estimation of biobased carbon content by AMS on the basis of the standard ASTM D 6866. The biobased carbon content for resin extracted from polyethylene composites allow for the calculation of biosynthetic polymer content, which is an indicator of mass percentage of the biobased plastic resin in the composite.

  9. False negative rate and other performance measures of a sponge-wipe surface sampling method for low contaminant concentrations.

    Energy Technology Data Exchange (ETDEWEB)

    Einfeld, Wayne; Krauter, Paula A.; Boucher, Raymond M.; Tezak, Mathew; Amidan, Brett G. (Pacific Northwest National Laboratory, Richland, WA); Piepel, Greg F. (Pacific Northwest National Laboratory, Richland, WA)

    2011-05-01

    Recovery of spores from environmental surfaces is known to vary due to sampling methodology, techniques, spore size and characteristics, surface materials, and environmental conditions. A series of tests were performed to evaluate a new, validated sponge-wipe method. Specific factors evaluated were the effects of contaminant concentrations and surface materials on recovery efficiency (RE), false negative rate (FNR), limit of detection (LOD) - and the uncertainties of these quantities. Ceramic tile and stainless steel had the highest mean RE values (48.9 and 48.1%, respectively). Faux leather, vinyl tile, and painted wood had mean RE values of 30.3, 25.6, and 25.5, respectively, while plastic had the lowest mean RE (9.8%). Results show a roughly linear dependence of surface roughness on RE, where the smoothest surfaces have the highest mean RE values. REs were not influenced by the low spore concentrations tested (3 x 10{sup -3} to 1.86 CFU/cm{sup 2}). The FNR data were consistent with RE data, showing a trend of smoother surfaces resulting in higher REs and lower FNRs. Stainless steel generally had the lowest mean FNR (0.123) and plastic had the highest mean FNR (0.479). The LOD{sub 90} varied with surface material, from 0.015 CFU/cm{sup 2} on stainless steel up to 0.039 on plastic. Selecting sampling locations on the basis of surface roughness and using roughness to interpret spore recovery data can improve sampling. Further, FNR values, calculated as a function of concentration and surface material, can be used pre-sampling to calculate the numbers of samples for statistical sampling plans with desired performance, and post-sampling to calculate the confidence in characterization and clearance decisions.

  10. Effect of concentration and pH on the surface-enhanced Raman scattering of captopril on nano-colloidal silver surface

    Science.gov (United States)

    Gao, Junxiang; Gu, Huaimin; Liu, Fangfang; Dong, Xiao; Xie, Min; Hu, Yongjun

    2011-07-01

    In this report, Raman and surface-enhanced Raman scattering (SERS) spectra of captopril are studied in detail. Herein, the Raman bands are assigned by the density functional theory (DFT) calculations and potential energy distributions (PED) based on internal coordinates of the molecule, which are found to be in good agree with the experimental values. Furthermore, the concentration and pH dependence of the SERS intensity of the molecule is discussed. By analyzing the intensities variation of SERS bands of the different concentrations of captopril solution, it can be concluded that the molecules orientation adsorbed on the silver nanoparticles surface change with the change of the concentrations. The variation of SERS spectra of captopril with the change of pH suggests that the interaction among the adsorbates with Ag cluster depend on the protonated state of the adsorbate and the aggregation of silver nanoparticles.

  11. Observational assessment of the role of nocturnal residual-layer chemistry in determining daytime surface particulate nitrate concentrations

    Directory of Open Access Journals (Sweden)

    G. Prabhakar

    2017-12-01

    Full Text Available This study discusses an analysis of combined airborne and ground observations of particulate nitrate (NO3−(p concentrations made during the wintertime DISCOVER-AQ (Deriving Information on Surface Conditions from COlumn and VERtically resolved observations relevant to Air Quality study at one of the most polluted cities in the United States – Fresno, CA – in the San Joaquin Valley (SJV and focuses on developing an understanding of the various processes that impact surface nitrate concentrations during pollution events. The results provide an explicit case-study illustration of how nighttime chemistry can influence daytime surface-level NO3−(p concentrations, complementing previous studies in the SJV. The observations exemplify the critical role that nocturnal chemical production of NO3−(p aloft in the residual layer (RL can play in determining daytime surface-level NO3−(p concentrations. Further, they indicate that nocturnal production of NO3−(p in the RL, along with daytime photochemical production, can contribute substantially to the buildup and sustaining of severe pollution episodes. The exceptionally shallow nocturnal boundary layer (NBL heights characteristic of wintertime pollution events in the SJV intensify the importance of nocturnal production aloft in the residual layer to daytime surface concentrations. The observations also demonstrate that dynamics within the RL can influence the early-morning vertical distribution of NO3−(p, despite low wintertime wind speeds. This overnight reshaping of the vertical distribution above the city plays an important role in determining the net impact of nocturnal chemical production on local and regional surface-level NO3−(p concentrations. Entrainment of clean free-tropospheric (FT air into the boundary layer in the afternoon is identified as an important process that reduces surface-level NO3−(p and limits buildup during pollution episodes. The influence of dry deposition of HNO

  12. Observational assessment of the role of nocturnal residual-layer chemistry in determining daytime surface particulate nitrate concentrations

    Science.gov (United States)

    Prabhakar, Gouri; Parworth, Caroline L.; Zhang, Xiaolu; Kim, Hwajin; Young, Dominique E.; Beyersdorf, Andreas J.; Ziemba, Luke D.; Nowak, John B.; Bertram, Timothy H.; Faloona, Ian C.; Zhang, Qi; Cappa, Christopher D.

    2017-12-01

    This study discusses an analysis of combined airborne and ground observations of particulate nitrate (NO3-(p)) concentrations made during the wintertime DISCOVER-AQ (Deriving Information on Surface Conditions from COlumn and VERtically resolved observations relevant to Air Quality) study at one of the most polluted cities in the United States - Fresno, CA - in the San Joaquin Valley (SJV) and focuses on developing an understanding of the various processes that impact surface nitrate concentrations during pollution events. The results provide an explicit case-study illustration of how nighttime chemistry can influence daytime surface-level NO3-(p) concentrations, complementing previous studies in the SJV. The observations exemplify the critical role that nocturnal chemical production of NO3-(p) aloft in the residual layer (RL) can play in determining daytime surface-level NO3-(p) concentrations. Further, they indicate that nocturnal production of NO3-(p) in the RL, along with daytime photochemical production, can contribute substantially to the buildup and sustaining of severe pollution episodes. The exceptionally shallow nocturnal boundary layer (NBL) heights characteristic of wintertime pollution events in the SJV intensify the importance of nocturnal production aloft in the residual layer to daytime surface concentrations. The observations also demonstrate that dynamics within the RL can influence the early-morning vertical distribution of NO3-(p), despite low wintertime wind speeds. This overnight reshaping of the vertical distribution above the city plays an important role in determining the net impact of nocturnal chemical production on local and regional surface-level NO3-(p) concentrations. Entrainment of clean free-tropospheric (FT) air into the boundary layer in the afternoon is identified as an important process that reduces surface-level NO3-(p) and limits buildup during pollution episodes. The influence of dry deposition of HNO3 gas to the surface on

  13. Analysis of supramolecular surface nanostructures using secondary ion mass spectrometry (poster)

    International Nuclear Information System (INIS)

    Halaszova, S.; Velic, D.

    2013-01-01

    Our system consists of host molecules β-cyclodextrin (C 42 H 70 O 35 ), of implemented Iron nanoparticles (guest). Whole supramolecular complex is placed on a gold substrate. In our project we work with monotiolated β-cyclodextrin (C 42 H 70 O 34 S), consisting of seven α-D-1-4 glucopyranose units. Cyclodextrins have been selected deliberately because of their ability to form inclusion complexes .They are also capable of forming structures similar to self-assembly monolayers. To study the formation of these supramolecular surface nanostructures mass secondary ion spectrometry is used. With this technique fragmentation of monotiolated β-cyclodextrin and the presence of the supramolecular complex on a gold surface can be examined. The observed fragments of monotiolated cyclodextrines films can be divided into three groups: Au X H Y S Z , fragments originating from cyclodextrin molecules associated with Au. Fragments as (C 42 H 70 O 34 S)Na + , (C 42 H 70 O 35 )Na + and (AuC 42 H 69 O 34 S)Na + were identified as well as fragments thereof in cationized form with K + . The main objective of the project is a detailed study and preparation of supramolecular nanostructures consisting of complex guest-host monotiolated β-cyclodextrin host-iron), and a gold substrate. (Authors)

  14. Greenland ice sheet surface mass-balance modeling in a 131-Yr perspective, 1950-2080

    DEFF Research Database (Denmark)

    Mernild, Sebastian H.; Liston, Glen E.; Hiemstra, Christopher A.

    2010-01-01

    and correct RCM output data before they were used as input for SnowModel. Satellite observations and independent SMB studies were used to validate the SnowModel output and confirmthemodel's robustness. The authors simulated an ~90% increase in end-of-summer surface melt extent (0.483 × 106 km2) from 1950......Fluctuations in the Greenland ice sheet (GrIS) surface mass balance (SMB) and freshwater influx to the surrounding oceans closely follow climate fluctuations and are of considerable importance to the global eustatic sea level rise.Astate-of-the-art snow-evolution modeling system(SnowModel) was used...... to 2080 and a melt index (above 2000-m elevation) increase of 138% (1.96 × 106 km2 × days). The greatest difference in melt extent occurred in the southern part of theGrIS, and the greatest changes in the number of melt dayswere seen in the eastern part of the GrIS (~50%-70%) and were lowest in the west...

  15. Analysis of personal care products on model skin surfaces using DESI and PADI ambient mass spectrometry.

    Science.gov (United States)

    Salter, Tara L; Green, Felicia M; Faruqui, Nilofar; Gilmore, Ian S

    2011-08-21

    Two ambient ionisation techniques, desorption electrospray ionisation (DESI) and plasma assisted desorption ionisation (PADI), have been used to analyse personal care products (PCPs) on fixed fibroblast cell surfaces. The similarities and differences between the two techniques for this type of analysis have been explored in various ways. Here, we show the results of DESI and PADI analysis of individual PCP ingredients as well as the analysis of these as complex creams on model skin surfaces, with minimal sample preparation. Typically, organosiloxanes and small molecules were detected from the creams. A study of the morphological damage of the fibroblast cells by the two ionisation techniques showed that for a less than 10% reduction in cell number, acquisition times should be limited to 5 s for PADI, which gives good signal levels; with DESI, the morphological damage was negligible. The operating parameters for the plasma source were optimised, and it was also found that the parameters could be modified to vary the relative intensity of different ions in the mass spectrum.

  16. EVALUATION OF ALTERNATE STAINLESS STEEL SURFACE TREATMENTS FOR MASS SPECTROSCOPY AND OTHER TRITIUM SYSTEMS

    Energy Technology Data Exchange (ETDEWEB)

    Clark, E.; Mauldin, C.; Neikirk, K.

    2012-02-29

    There are specific components in the SRS Tritium Facilities that are required to introduce as few chemical impurities (such as protium and methane) as possible into the process gas. Two such components are the inlet systems for the mass spectroscopy facilities and hydrogen isotope mix standard containers. Two vendors now passivate stainless steel components for these systems, and both are relatively small businesses whose future viability can be questioned, which creates the need for new sources. Stainless steel containers were designed to evaluate alternate surface treatment vendors for tritium storage and handling for these high purity tritium systems. Five vendors applied their own 'best' surface treatments to two containers each - one was a current vendor, another was a chemical vapor deposited silicon coating, and the other three were electropolishing and chemical cleaning vendors. Pure tritium gas was introduced into all ten containers and the composition was monitored over time. The only observed impurities in the gas were some HT, less CT{sub 4}, and very small amounts of T{sub 2}O in all cases. The currently used vendor treated containers contained the least impurities. The chemical vapor deposited silicon treatment resulted in the highest impurity levels. Sampling one set of containers after about one month of tritium exposure revealed the impurity level to be nearly the same as that after more than a year of exposure - this result suggests that cleaning new stainless steel components by tritium gas contact for about a month may be a worthy operation.

  17. Monitoring the concentrations of nonsteroidal anti-inflammatory drugs and cyclooxygenase-inhibiting activities in the surface waters of the Tone Canal and Edo River Basin.

    Science.gov (United States)

    Nishi, Iwaki; Kawakami, Tsuyoshi; Onodera, Sukeo

    2015-01-01

    Environmental pollution by pharmaceuticals has become a major problem in many countries worldwide. However, little is known about the concentrations of pharmaceuticals in water sources in Japan. The objective of this study was to clarify variations in the concentrations of seven nonsteroidal anti-inflammatory drugs (NSAIDs) and in cyclooxygenase(COX)-inhibiting activities in river water and domestic wastewater collected from the Tone Canal and the Edo River Basin in Japan. Total NSAID concentrations were higher in the Tone Canal than in the Edo River, and the highest concentration was observed at the domestic wastewater inflow point located in the Tone Canal (concentration averages of salicylic acid, ibuprofen, felbinac, naproxen, mefenamic acid, diclofenac, and ketoprofen in wastewater samples were 55.3, 162.9, 39.7, 11.8, 30.8, 259.7, and 48.3 ng L(-1), respectively). Gas chromatography-tandem mass spectrometry showed that wastewater samples collected during cooler seasons contained higher levels of COX-inhibiting activity. COX-inhibiting activities were highly correlated with NSAID concentrations (particularly for ketoprofen and diclofenac); however, other COX inhibitors, such as NSAIDs that were not examined in this study and/or other chemicals with COX-inhibiting activity, could exist in the water samples because the concentrations of NSAIDs obtained from the water samples did not account for the total COX-inhibiting activities observed. Therefore, COX inhibition assays may be helpful for evaluating the aquatic toxicity of COX inhibitors. In this study, we demonstrated that COX inhibitors in surface water may influence aquatic organisms more than was expected based on NSAID concentrations. Thus, further studies examining other COX inhibitors in the aquatic environment are necessary.

  18. Greenland ice sheet surface mass-balance modeling in a 131-year perspective, 1950-2080

    Energy Technology Data Exchange (ETDEWEB)

    Mernild, Sebastian Haugard [Los Alamos National Laboratory; Liston, Glen [COLORADO STATE UNIV.; Hiemstra, Christopher [COLORADO STATE UNIV.; Christensen, Jens [DANISH METEOROLOGICAL INS.

    2009-01-01

    Fluctuations in the Greenland Ice Sheet (GrIS) surface mass-balance (SMB) and freshwater influx to the surrounding oceans closely follow climate fluctuations and are of considerable importance to the global eustatic sea level rise. SnowModel, a state-of-the-art snow-evolution modeling system, was used to simulate variations in the GrIS melt extent, surface water balance components, changes in SMB, and freshwater influx to the ocean. The simulations are based on the IPCC scenario AlB modeled by the HIRHAM4 RCM (using boundary conditions from ECHAM5 AOGCM) from 1950 through 2080. In-situ meteorological station (GC-Net and WMO DMI) observations from inside and outside the GrIS were used to validate and correct RCM output data before it was used as input for SnowModel. Satellite observations and independent SMB studies were used to validate the SnowModel output and confirm the model's robustness. We simulated a {approx}90% increase in end-of-summer surface melt extent (0.483 x 10{sup 6} km{sup 2}) from 1950 to 2080, and a melt index (above 2,000-m elevation) increase of 138% (1.96 x 10{sup 6} km{sup 2} x days). The greatest difference in melt extent occured in the southern part of the GrIS, and the greatest changes in the number of melt days was seen in the eastern part of the GrIS ({approx}50-70%) and was lowest in the west ({approx}20-30%). The rate of SMB loss, largely tied to changes in ablation processes, lead to an enhanced average loss of 331 km{sup 3} from 1950 to 2080, an average 5MB level of -99 km{sup 3} for the period 2070-2080. GrIS surface freshwater runoff yielded an eustatic rise in sea level from 0.8 {+-} 0.1 (1950-1959) to 1.9 {+-} 0.1 mm (2070-2080) sea level equivalent (SLE) y{sup -1}. The accumulated GrIS freshwater runoff contribution from surface melting equaled 160 mm SLE from 1950 through 2080.

  19. Evolution of size-segregated aerosol mass concentration during the Antarctic summer at Northern Foothills, Victoria Land

    Science.gov (United States)

    Illuminati, Silvia; Bau, Sébastien; Annibaldi, Anna; Mantini, Caterina; Libani, Giulia; Truzzi, Cristina; Scarponi, Giuseppe

    2016-01-01

    Within the framework of the Italian National Programm for Antarctic Research (PNRA), the first direct gravimetric measurements of size-segregated aerosol fractions were carried out at Faraglione Camp, ˜3-km far from the Italian station "M. Zucchelli" (Terra Nova Bay, Ross Sea), during the 2014-2015 austral summer. A six-stage high-volume cascade impactor with size classes between 10 μm and 0.49 μm, and, in parallel, for comparison purposes, a PM10 high-volume sampler (50% cut-off aerodynamic diameter of 10 μm) were used. A 10-day sampling strategy was adopted. Aerosol mass measurements were carried out before and after exposure by using a microbalance specifically designed for the filter weight and placed inside a glove bag in order to maintain stable temperature and humidity conditions during weighing sessions. Measured atmospheric concentrations (referred to the "actual air conditions" of mean temperature of 268 K and mean pressure of 975 hPa) of size-segregated aerosol fractions showed the following values, given as size range, means (interquartile range): Dp range 0.1-1.0 μm) and two coarse modes (CM1 in the range 1.0-3.0 μm, and CM2 in the range 3.0-10 μm). From 50% to 90% of the PM10 mass comes from particles of a size smaller than 1.0 μm. The two coarse modes represented from ˜5% to ˜35% of the PM10, showing opposite seasonal trends (CM1 decreased while CM2 increased). During summer, PM10 mass concentration increased to a maximum of ˜1.6 μg m-3 at mid-December, while in January it decreased to values that are typical of November. Both accumulation and upper super-micron fractions showed a maximum in the same period contributing to the PM10 peak of mid-summer.

  20. Surface-sampling and analysis of TATP by swabbing and gas chromatography/mass spectrometry.

    Science.gov (United States)

    Romolo, Francesco Saverio; Cassioli, Luigi; Grossi, Silvana; Cinelli, Giuseppe; Russo, Mario Vincenzo

    2013-01-10

    The method of sample recovery for trace detection and identification of explosives plays a critical role in several criminal investigations. After bombing, there can be difficulties in sending big objects to a laboratory for analysis. Traces can also be searched for on large surfaces, on hands of suspects or on surfaces where the explosive was placed during preparatory phases (e.g. places where an IED was assembled, vehicles used for transportation, etc.). In this work, triacetone triperoxide (TATP) was synthesized from commercial precursors following reported methods. Several portions of about 6mg of TATP were then spread on different surfaces (e.g. floors, tables, etc.) or used in handling tests. Three different swabbing systems were used: a commercial swab, pre-wetted with propan-2-ol (isopropanol) and water (7:3), dry paper swabs, and cotton swabs wetted with propan-2-ol. Paper and commercial swabs were also used to sample a metal plate, where a small charge of about 4g of TATP was detonated. Swabs were sealed in small glass jars with screw caps and Parafilm(®) M and sent to the laboratory for analysis. Swabs were extracted and analysed several weeks later by gas chromatography/mass spectrometry. All the three systems gave positive results, but wetted swabs collected higher amounts of TATP. The developed procedure showed its suitability for use in real cases, allowing TATP detection in several simulations, including a situation in which people wash their hands after handling the explosive. Copyright © 2012 Elsevier Ireland Ltd. All rights reserved.

  1. High-spatial and high-mass resolution imaging of surface metabolites of Arabidopsis thaliana by laser desorption-ionization mass spectrometry using colloidal silver.

    Science.gov (United States)

    Jun, Ji Hyun; Song, Zhihong; Liu, Zhenjiu; Nikolau, Basil J; Yeung, Edward S; Lee, Young Jin

    2010-04-15

    High-spatial resolution and high-mass resolution techniques are developed and adopted for the mass spectrometric imaging of epicuticular lipids on the surface of Arabidopsis thaliana. Single cell level spatial resolution of approximately 12 mum was achieved by reducing the laser beam size by using an optical fiber with 25 mum core diameter in a vacuum matrix-assisted laser desorption ionization-linear ion trap (vMALDI-LTQ) mass spectrometer and improved matrix application using an oscillating capillary nebulizer. Fine chemical images of a whole flower were visualized in this high spatial resolution showing substructure of an anther and single pollen grains at the stigma and anthers. The LTQ-Orbitrap with a MALDI ion source was adopted to achieve MS imaging in high mass resolution. Specifically, isobaric silver ion adducts of C29 alkane (m/z 515.3741) and C28 aldehyde (m/z 515.3377), indistinguishable in low-resolution LTQ, can now be clearly distinguished and their chemical images could be separately constructed. In the application to roots, the high spatial resolution allowed molecular MS imaging of secondary roots and the high mass resolution allowed direct identification of lipid metabolites on root surfaces.

  2. High-Spatial and High-Mass Resolution Imaging of Surface Metabolites of Arabidopsis thaliana by Laser Desorption-Ionization Mass Spectrometry Using Colloidal Silver

    Energy Technology Data Exchange (ETDEWEB)

    Jun, Ji Hyun; Song, Zhihong; Liu, Zhenjiu; Nikolau, Basil J.; Yeung, Edward S.; and Lee, Young Jin

    2010-03-17

    High-spatial resolution and high-mass resolution techniques are developed and adopted for the mass spectrometric imaging of epicuticular lipids on the surface of Arabidopsis thaliana. Single cell level spatial resolution of {approx}12 {micro}m was achieved by reducing the laser beam size by using an optical fiber with 25 {micro}m core diameter in a vacuum matrix-assisted laser desorption ionization-linear ion trap (vMALDI-LTQ) mass spectrometer and improved matrix application using an oscillating capillary nebulizer. Fine chemical images of a whole flower were visualized in this high spatial resolution showing substructure of an anther and single pollen grains at the stigma and anthers. The LTQ-Orbitrap with a MALDI ion source was adopted to achieve MS imaging in high mass resolution. Specifically, isobaric silver ion adducts of C29 alkane (m/z 515.3741) and C28 aldehyde (m/z 515.3377), indistinguishable in low-resolution LTQ, can now be clearly distinguished and their chemical images could be separately constructed. In the application to roots, the high spatial resolution allowed molecular MS imaging of secondary roots and the high mass resolution allowed direct identification of lipid metabolites on root surfaces.

  3. The Dependence of CNT Aerogel Synthesis on Sulfur-driven Catalyst Nucleation Processes and a Critical Catalyst Particle Mass Concentration.

    Science.gov (United States)

    Hoecker, Christian; Smail, Fiona; Pick, Martin; Weller, Lee; Boies, Adam M

    2017-11-06

    The floating catalyst chemical vapor deposition (FC-CVD) process permits macro-scale assembly of nanoscale materials, enabling continuous production of carbon nanotube (CNT) aerogels. Despite the intensive research in the field, fundamental uncertainties remain regarding how catalyst particle dynamics within the system influence the CNT aerogel formation, thus limiting effective scale-up. While aerogel formation in FC-CVD reactors requires a catalyst (typically iron, Fe) and a promotor (typically sulfur, S), their synergistic roles are not fully understood. This paper presents a paradigm shift in the understanding of the role of S in the process with new experimental studies identifying that S lowers the nucleation barrier of the catalyst nanoparticles. Furthermore, CNT aerogel formation requires a critical threshold of Fe x C y  > 160 mg/m 3 , but is surprisingly independent of the initial catalyst diameter or number concentration. The robustness of the critical catalyst mass concentration principle is proved further by producing CNTs using alternative catalyst systems; Fe nanoparticles from a plasma spark generator and cobaltocene and nickelocene precursors. This finding provides evidence that low-cost and high throughput CNT aerogel routes may be achieved by decoupled and enhanced catalyst production and control, opening up new possibilities for large-scale CNT synthesis.

  4. TASTRAK spectroscopy of polonium-210 alpha-particle activity at bone surfaces: Evidence for a concentrated surface deposit less than 3 μm deep

    International Nuclear Information System (INIS)

    Salmon, P.L.; Henshaw, D.L.; Keitch, P.A.; Allen, J.E.; Fews, A.P.

    1994-01-01

    The technique of α-particle spectroscopy by CR-39 type TASTRAK plastic has been used to study the depth distribution of natural α-particle emitters at the surface of human bone. The predominant component of this α-particle activity was 210 Po supported by 210 Pb, although a smaller activity of 226 Ra was also detected. Autopsy samples of human femur and cranium were obtained from subjects age 63 to 86. Both cortical and trabecular surfaces were analyzed. The results indicate that 210 Pb-supported 210 Po is concentrated at the surfaces of human bone from elderly subjects, in a narrow band 3 μm deep or less, by a factor of about four. As a result, the α-particle dose to the nuclei of cells lining bone surfaces is around 1.8 times greater than that calculated for a uniform volume distribution. Polonium-210 activity indicates the distribution of 210 Pb, and of stable lead, received by continuous intake throughout life at a very low level. A persistent bone surface concentration of lead and other osteotropic metals may be associated with the hypermineralized layer about 1 μm thick which occurs at the surface of resting bone mineral. 31 refs., 9 figs., 3 tabs

  5. Incorporation of the Mass Concentration and the New Snow Albedo Schemes into the Global Forecasting Model, GEOS-5 and the Impact of the New Schemes over Himalayan Glaciers

    Science.gov (United States)

    Yasunari, Teppei

    2012-01-01

    Recently the issue on glacier retreats comes up and many factors should be relevant to the issue. The absorbing aerosols such as dust and black carbon (BC) are considered to be one of the factors. After they deposited onto the snow surface, it will reduce snow albedo (called snow darkening effect) and probably contribute to further melting of glacier. The Goddard Earth Observing System version 5 (GEOS-5) has developed at NASA/GSFC. However, the original snowpack model used in the land surface model in the GEOS-5 did not consider the snow darkening effect. Here we developed the new snow albedo scheme which can consider the snow darkening effect. In addition, another scheme on calculating mass concentrations on the absorbing aerosols in snowpack was also developed, in which the direct aerosol depositions from the chemical transport model in the GEOS-5 were used. The scheme has been validated with the observed data obtained at backyard of the Institute of Low Temperature Science, Hokkaido University, by Dr. Teruo Aoki (Meteorological Research Institute) et aL including me. The observed data was obtained when I was Ph.D. candidate. The original GEOS-5during 2007-2009 over the Himalayas and Tibetan Plateau region showed more reductions of snow than that of the new GEOS-5 because the original one used lower albedo settings. On snow cover fraction, the new GEOS-5 simulated more realistic snow-covered area comparing to the MODIS snow cover fraction. The reductions on snow albedo, snow cover fraction, and snow water equivalent were seen with statistically significance if we consider the snow darkening effect comparing to the results without the snow darkening effect. In the real world, debris cover, inside refreezing process, surface flow of glacier, etc. affect glacier mass balance and the simulated results immediately do not affect whole glacier retreating. However, our results indicate that some surface melting over non debris covered parts of the glacier would be

  6. Investigation Into Accessible Surface Vinyl Concentrations of Nonstoichiometric PDMS Microspheres from Hydrosilylation Reactions and Their Further Crosslinking Reactions

    DEFF Research Database (Denmark)

    Ma, Baoguang; Hansen, Jens Henrik; Hvilsted, Søren

    2015-01-01

    titration method, which is based on efficiently and covalently bonding mono-functional hydride to vinyl, is employed to determine surface vinyl concentration. The titration method exhibits good reproducibility in detection, thereby underlining its potential applicability as a general titration method...

  7. Estimating daily surface NO2 concentrations from satellite data - a case study over Hong Kong using land use regression models

    Science.gov (United States)

    Anand, Jasdeep S.; Monks, Paul S.

    2017-07-01

    Land use regression (LUR) models have been used in epidemiology to determine the fine-scale spatial variation in air pollutants such as nitrogen dioxide (NO2) in cities and larger regions. However, they are often limited in their temporal resolution, which may potentially be rectified by employing the synoptic coverage provided by satellite measurements. In this work a mixed-effects LUR model is developed to model daily surface NO2 concentrations over the Hong Kong SAR during the period 2005-2015. In situ measurements from the Hong Kong Air Quality Monitoring Network, along with tropospheric vertical column density (VCD) data from the OMI, GOME-2A, and SCIAMACHY satellite instruments were combined with fine-scale land use parameters to provide the spatiotemporal information necessary to predict daily surface concentrations. Cross-validation with the in situ data shows that the mixed-effects LUR model using OMI data has a high predictive power (adj. R2 = 0. 84), especially when compared with surface concentrations derived using the MACC-II reanalysis model dataset (adj. R2 = 0. 11). Time series analysis shows no statistically significant trend in NO2 concentrations during 2005-2015, despite a reported decline in NOx emissions. This study demonstrates the utility in combining satellite data with LUR models to derive daily maps of ambient surface NO2 for use in exposure studies.

  8. Chemical characterization of neonicotinoids in surface waters by high performance liquid chromatography with Tandem Mass Spectrometry (HPLC MS/MS)

    International Nuclear Information System (INIS)

    Amaral, Priscila Oliveira

    2017-01-01

    The present study aimed to develop a method for the determination and validation of a method for the identification and quantification of Neonicotinoids in surface waters collected in the Bauru region, in the state of São Paulo. The analytical techniques studied for the development of this method were the high performance liquid chromatography with tandem mass spectrometry (HPLC - MS / MS), gas chromatography with mass spectrometry (GC / MS) and gas chromatography with electron capture detector (GC / ECD). The class of pesticides Neonicotinoids was chosen for this work because it is related to a sudden disappearance of bees in colonies around the world. This phenomenon is known as Colony Collapse Disorder (CCD) and it is characterized by a rapid loss in the population of adult bees. The Neonicotinoids used in this study were the compounds Clothianidin, Imidacloprid and Thiamethoxam which were banned in their use as pesticides in Europe by Implementing Regulation No. 540/2011. The samples were concentrated using solid phase extraction (SPE) and liquid liquid extraction (LLE) techniques and injected into HPLC-MS / MS, GC / MS and GC / ECD. The GC / ECD and GC / MS techniques were not satisfactory for determination in the water matrix because the detection limit (10 mg L -1 ) is above the maximum allowed by the US Environmental Protection Agency (0.6 μg L -1 ). The HPLC - MS / MS technique using the multiple reaction monitoring (MRM) proved to be adequate for this study because it obtained quantification limits between 5.89 and 8.06 μg L -1 and a linearity between 0.9963 and 0.9999 for the three compounds. (author)

  9. Influence of the surface permeability on the GRACE water mass variations. Case of the Lake Chad basin.

    Science.gov (United States)

    Lopez, T.; Ramillien, G.; Antoine, R.; Darrozes, J.; Rabinowicz, M.

    2017-12-01

    Since its launch in 2002, the Gravity Recovery And Climate Experiment (GRACE) has been measured the tiny variations of the gravity field due to redistributions of water mass in the surface envelops of Earth. At a spatial resolution of 400 km, these satellite data offer a unique perspective to understand the evolution of continental water storage at regional and global scales, and therefore they enable the monitoring of the hydrological systems such as river basins. It is well known that seasonal cycle, droughts, vegetation and human extractions are the main contributors of the hydrology signals sensed by GRACE. However, the coupling between land surface and the atmosphere is important in semi-arid and arid regions, in particular in West Africa [1]. We propose to quantify the surface water fluxes in the Lake Chad region by using the 10-day water mass solutions of the GRACE mission in the context of the regular West African monsoon. Alternation of the evaporation/condensation cycles during the recent period are interpreted in terms of surface vertical permeability changes that control the thermal evolution in this region [2]. GRACE solutions reveal an interannual increase of surface water mass at the beginning of the dry seasons, especially between 2005 and 2008. We propose that this gain of surface water mass is caused by a seasonal cycle of clay fracturing that controls the evaporation/condensation cycle. [1] Koster et al. (2004). Science, 305, 1138-1140. [2] Lopez et al. (2016). Surv. Geophys., 37 (2), 471-502.

  10. Determination of surface concentrations of individual molecule-layers used in nanoscale biosensors by in situ ATR-FTIR spectroscopy

    KAUST Repository

    Punzet, Manuel

    2012-01-01

    For the development of nanowire sensors for chemical and medical detection purposes, the optimal functionalization of the surface is a mandatory component. Quantitative ATR-FTIR spectroscopy was used in situ to investigate the step-by-step layer formation of typical functionalization protocols and to determine the respective molecule surface concentrations. BSA, anti-TNF-α and anti-PSA antibodies were bound via 3-(trimethoxy)butylsilyl aldehyde linkers to silicon-oxide surfaces in order to investigate surface functionalization of nanowires. Maximum determined surface concentrations were 7.17 × 10 -13 mol cm -2 for BSA, 1.7 × 10 -13 mol cm -2 for anti-TNF-α antibody, 6.1 × 10 -13 mol cm -2 for anti-PSA antibody, 3.88 × 10 -13 mol cm -2 for TNF-α and 7.0 × 10 -13 mol cm -2 for PSA. Furthermore we performed antibody-antigen binding experiments and determined the specific binding ratios. The maximum possible ratio of 2 was obtained at bulk concentrations of the antigen in the μg ml -1 range for TNF-α and PSA. © 2012 The Royal Society of Chemistry.

  11. CONCENTRATION DEPENDENCE OF STERN LAYER CAPACITANCES AND SURFACE EQUILIBRIUM CONSTANTS IN SILICA-BASED NANOFLUIDIC CHANNELS

    DEFF Research Database (Denmark)

    Andersen, Mathias Bækbo; Frey, J.; Bruus, Henrik

    2010-01-01

    ]. The current models used to describe surface phenomena in nanofluidics can differ by orders of magnitude from experimentally measured values [2]. To mitigate the discrepancies, we hypothesize that the Stern-layer capacitance Cs and the surface equilibrium constants pKa, vary with the composition of the solid...

  12. Spatial and temporal analysis of pesticides concentrations in surface water: Pesticides atlas

    NARCIS (Netherlands)

    Vijver, M.G.; Zelfde, van 't M.; Tamis, W.L.M.; Snoo, de G.R.

    2008-01-01

    Dutch water boards have a well-established program for monitoring pesticide contamination of surface waters. These monitoring data have been processed into a graphic format accessible online and designed to provide insight into pesticide presence in Dutch surface waters and trends over time: the

  13. Prediction of sub-surface 37 Ar concentrations at locations in the Northwestern United States

    Energy Technology Data Exchange (ETDEWEB)

    Fritz, Bradley G.; Aalseth, Craig E.; Back, Henning O.; Hayes, James C.; Humble, Paul H.; Ivanusa, Pavlo; Mace, Emily K.

    2018-01-01

    The Comprehensive Nuclear Test-Ban Treaty, which is intended to prevent nuclear weapon testing, includes a verification regime, which provides monitoring to identify potential nuclear testing. The presence of elevated 37Ar is one way to identify subsurface nuclear testing. However, the naturally occurring formation of 37Ar in the subsurface adds a complicating factor. Prediction of the naturally occurring concentration of 37Ar can help to determine if a measured 37Ar concentration is elevated. The naturally occurring 37Ar background concentration has been shown to vary between less than 1 mBq/m3 to greater than 100 mBq/m3 (Riedmann and Purtschert 2011). Here, we evaluate a model for predicting the average concentration of 37Ar at any depth under transient barometric pressures, and compare it with measurements. This model is shown to compare favorably with concentrations of 37Ar measured at multiple locations in the Northwestern United States.

  14. Heterogeneity of soil surface ammonium concentration and other characteristics, related to plant specific variability in a Mediterranean-type ecosystem

    International Nuclear Information System (INIS)

    Cruz, Cristina; Bio, Ana M.F.; Jullioti, Aldo; Tavares, Alice; Dias, Teresa; Martins-Loucao, Maria Amelia

    2008-01-01

    Heterogeneity and dynamics of eight soil surface characteristics essential for plants-ammonium and nitrate concentrations, water content, temperature, pH, organic matter, nitrification and ammonification rates-were studied in a Mediterranean-type ecosystem on four occasions over a year. Soil properties varied seasonally and were influenced by plant species. Nitrate and ammonium were present in the soil at similar concentrations throughout the year. The positive correlation between them at the time of greatest plant development indicates that ammonium is a readily available nitrogen source in Mediterranean-type ecosystems. The results presented here suggest that plant cover significantly affects soil surface characteristics. - In Mediterranean-type ecosystems ammonium is present in the soil throughout the year and its concentration is dependent on plant cover

  15. Numerical study for nanofluid flow due to a nonlinear curved stretching surface with convective heat and mass conditions

    Directory of Open Access Journals (Sweden)

    Tasawar Hayat

    Full Text Available This article presents the simultaneous effects of convective heat and mass conditions in boundary-layer flow of nanoliquid due to a nonlinear curved stretching surface. A nonlinear curved stretching surface is used to generate the flow. Thermophoretic diffusion and random motion features are also incorporated. Convective heat and mass conditions are imposed at boundary. Suitable variables are utilized to convert the nonlinear partial differential system into nonlinear ordinary differential system. The obtained nonlinear systems are solved numerically through shooting technique. Plots are displayed in order to explore the role of physical flow variables on the solutions. The skin-friction coefficient and local Nusselt and Sherwood numbers are computed and examined. Our findings indicate that the local Nusselt and Sherwood numbers are reduced for larger values of thermophoresis parameter. Keywords: Nonlinear curved stretching surface, Nanoparticles, Convective heat and mass conditions, Numerical solution

  16. Ecology of ontogenetic body-mass scaling of gill surface area in a freshwater crustacean.

    Science.gov (United States)

    Glazier, Douglas S; Paul, David A

    2017-06-01

    Several studies have documented ecological effects on intraspecific and interspecific body-size scaling of metabolic rate. However, little is known about how various ecological factors may affect the scaling of respiratory structures supporting oxygen uptake for metabolism. To our knowledge, our study is the first to provide evidence for ecological effects on the scaling of a respiratory structure among conspecific populations of any animal. We compared the body-mass scaling of gill surface area (SA) among eight spring-dwelling populations of the amphipod crustacean Gammarus minus Although gill SA scaling was not related to water temperature, conductivity or G. minus population density, it was significantly related to predation regime (and secondarily to pH). Body-mass scaling slopes for gill SA were significantly lower in four populations inhabiting springs with fish predators than for four populations in springs without fish (based on comparing means of the population slopes, or slopes calculated from pooled raw data for each comparison group). As a result, gill SA was proportionately smaller in adult amphipods from springs with versus without fish. This scaling difference paralleled similar differences in the scaling exponents for the rates of growth and resting metabolic rate. We hypothesized that gill SA scaling is shallower in fish-containing versus fishless spring populations of G. minus because of effects of size-selective predation on size-specific growth and activity that in turn affect the scaling of oxygen demand and concomitantly the gill capacity (SA) for oxygen uptake. Although influential theory claims that metabolic scaling is constrained by internal body design, our study builds on previous work to show that the scaling of both metabolism and the respiratory structures supporting it may be ecologically sensitive and evolutionarily malleable. © 2017. Published by The Company of Biologists Ltd.

  17. Modeling uranium(VI) adsorption onto montmorillonite under varying carbonate concentrations: A surface complexation model accounting for the spillover effect on surface potential

    Science.gov (United States)

    Tournassat, C.; Tinnacher, R. M.; Grangeon, S.; Davis, J. A.

    2018-01-01

    The prediction of U(VI) adsorption onto montmorillonite clay is confounded by the complexities of: (1) the montmorillonite structure in terms of adsorption sites on basal and edge surfaces, and the complex interactions between the electrical double layers at these surfaces, and (2) U(VI) solution speciation, which can include cationic, anionic and neutral species. Previous U(VI)-montmorillonite adsorption and modeling studies have typically expanded classical surface complexation modeling approaches, initially developed for simple oxides, to include both cation exchange and surface complexation reactions. However, previous models have not taken into account the unique characteristics of electrostatic surface potentials that occur at montmorillonite edge sites, where the electrostatic surface potential of basal plane cation exchange sites influences the surface potential of neighboring edge sites ('spillover' effect). A series of U(VI) - Na-montmorillonite batch adsorption experiments was conducted as a function of pH, with variable U(VI), Ca, and dissolved carbonate concentrations. Based on the experimental data, a new type of surface complexation model (SCM) was developed for montmorillonite, that specifically accounts for the spillover effect using the edge surface speciation model by Tournassat et al. (2016a). The SCM allows for a prediction of U(VI) adsorption under varying chemical conditions with a minimum number of fitting parameters, not only for our own experimental results, but also for a number of published data sets. The model agreed well with many of these datasets without introducing a second site type or including the formation of ternary U(VI)-carbonato surface complexes. The model predictions were greatly impacted by utilizing analytical measurements of dissolved inorganic carbon (DIC) concentrations in individual sample solutions rather than assuming solution equilibration with a specific partial pressure of CO2, even when the gas phase was

  18. Liquid chromatography-tandem mass spectrometry direct injection analysis of organophosphorus flame retardants in Ontario surface water and wastewater effluent.

    Science.gov (United States)

    Hao, Chunyan; Helm, Paul A; Morse, David; Reiner, Eric J

    2018-01-01

    Organophosphorus flame retardants (OPFRs) started to be used in plastics, electronics and furnishings back in the 1960s and became popular again last decade. They are now widely present in the environment and regarded as "new" emerging organic pollutants. An effective liquid chromatography-tandem mass spectrometry (LC-MS/MS) direct injection analysis (DIA) method was developed to monitor OPFR levels in aquatic environment. The removal of sample extraction and concentration steps not only improved operation efficiency, but also reduced the potential contamination commonly observed during the sample preparation process before. Positive background signals from the analytical instrument were eliminated by employing a "trap" column in front of the sample injector while an ACE C18 and an ACE C18-PFP column were compared for the separation of OPFRs. Nineteen OPFR related compounds were evaluated and rapid signal drops were observed for seven of them including TOTP, TMTP, TPTP, TEHP, T35DMPP, T2iPPP and EHDP, due to their low water solubility. The other twelve compounds, TMP, TEP, TPrP, TiPP, TBP, TCEP, TCPP, TDCPP, TPP, TBEP, BDCP and BEHP, were included for the measurement of OPFRs in drinking water, surface water, ground water and wastewater effluent samples. The instrumental detection limits of these twelve OPFRs at signal-to-noise ≥3 were in the 1.5-30 ng/L range. The method was applied for the determination of OPFRs in surface water and wastewater samples in Ontario, Canada, and BEHP, TBEP, TBP, TCEP, TCPP, TDCPP, and TEP were commonly detected. Crown Copyright © 2017. Published by Elsevier Ltd. All rights reserved.

  19. Surface Water Qualit: Revisiting Nitrate Concentrations in the Des Moines River: 1945 and 1976-2001

    Science.gov (United States)

    McIsaac, G.F.; Libra, R.D.

    2003-01-01

    Recent compilations of historical and contemporary riverine nitrate (NO3) concentrations indicate that concentrations in many rivers in the north-central USA increased during the second half of the 20th century. The Des Moines River near Des Moines, Iowa, however, was reported to have had similar NO3 concentrations in 1945 and the 1980s, in spite of substantially greater N input to the watershed during the latter period. The objective of this study was to reconsider the comparison of historical and contemporary NO3 concentrations in the Des Moines River near Des Moines in light of the following: (i) possible errors in the historical data used, (ii) variations in methods of sample collection, (iii) variations in location of sampling, and (iv) additional data collected since 1990. We discovered that an earlier study had compared the flow-weighted average concentration in 1945 to arithmetic annual average concentrations in the 1980s. The intertemporal comparison also appeared to be influenced by differences in sample collection methods and locations used at different times. Depending on the model used and the estimated effects of composite sample collection, the 1945 arithmetic average NO3 concentration was between 44 and 57% of the expected mean value at a similar water yield during 1976-2001. The flow-weighted average NO3 concentration for 1945 was between 54 and 73% of the expected mean value at a similar water yield during 1976-2001. The difference between NO3 concentrations in 1945 and the contemporary period are larger than previously reported for the Des Moines River.

  20. Elemental concentrations of aquatic insect larvae and attached algae on tone surfaces in an uncontaminated stream

    International Nuclear Information System (INIS)

    Momoshima, N.; Sugihara, S.; Hibino, K.; Nakamura, Y.

    2009-01-01

    Elemental concentrations of aquatic insect larvae and attached algae in an uncontaminated river were analyzed by instrumental neutron activation analysis (INAA) via the k 0 -standardization method. The aquatic insect larvae found were all intolerant species. No significant difference was observed int he elemental concentrations of aquatic insect larvae and attached algae long the river. Similar elemental concentrations were observed in the aquatic insect larvae collected at a fixed sampling point for two years. An analysis by the ratio-matching technique indicated a higher generic relationship between aquatic insect larvae and attached algae than river water. (author)

  1. Concentration Levels and Ecological Risks of Persistent Organic Pollutants in the Surface Sediments of Tianjin Coastal Area, China

    Directory of Open Access Journals (Sweden)

    Xiaoxia Lu

    2013-01-01

    Full Text Available Sediments were sampled from different surface water bodies in Tianjin coastal area, China, and persistent organic pollutants (POPs including polycyclic aromatic hydrocarbons (PAHs, organochlorine pesticides (OCPs, polychlorinated biphenyls (PCBs, and polybrominated diphenyl ethers (PBDEs were measured using GC/MS or GC/ECD. The purposes were to investigate the concentration levels of the POPs and to assess their ecological risks. The results showed that all the 16 priority PAHs were detected from the 10 sediments sampled with the total concentrations of the 16 PAHs ranging from 274.06 μg/kg to 2656.65 μg/kg, while the concentrations of the halogenated POPs were generally low except in the Dagu waste discharging river where the total concentrations of 24 OCPs, 35 PCBs, and 14 PBDEs were 3103.36 μg/kg, 87.31 μg/kg, and 13.88 μg/kg, respectively. In the studied sediments, PAHs exhibited risks to benthonic organisms; particularly the concentrations of naphthalene and/or acenaphthene exceeded their probable effect concentrations in several locations. In comparison, only in the Dagu waste discharging river, OCPs exhibited risks with the concentrations of heptachlor epoxide and lindane exceeding their probable effect concentrations. PCBs and PBDEs posed rare risks in the studied area.

  2. Quantitative Thin-Layer Chromatography/Mass Spectrometry Analysis of Caffeine Using a Surface Sampling Probe Electrospray Ionization Tandem Mass Spectrometry System

    Energy Technology Data Exchange (ETDEWEB)

    Ford, Michael J [ORNL; Deibel, Michael A. [Earlham College; Tomkins, Bruce A [ORNL; Van Berkel, Gary J [ORNL

    2005-01-01

    Quantitative determination of caffeine on reversed-phase C8 thin-layer chromatography plates using a surface sampling electrospray ionization system with tandem mass spectrometry detection is reported. The thin-layer chromatography/electrospray tandem mass spectrometry method employed a deuterium-labeled caffeine internal standard and selected reaction monitoring detection. Up to nine parallel caffeine bands on a single plate were sampled in a single surface scanning experiment requiring 35 min at a surface scan rate of 44 {mu}m/s. A reversed-phase HPLC/UV caffeine assay was developed in parallel to assess the mass spectrometry method performance. Limits of detection for the HPLC/UV and thin-layer chromatography/electrospray tandem mass spectrometry methods determined from the calibration curve statistics were 0.20 ng injected (0.50 {mu}L) and 1.0 ng spotted on the plate, respectively. Spike recoveries with standards and real samples ranged between 97 and 106% for both methods. The caffeine content of three diet soft drinks (Diet Coke, Diet Cherry Coke, Diet Pepsi) and three diet sport drinks (Diet Turbo Tea, Speed Stack Grape, Speed Stack Fruit Punch) was measured. The HPLC/UV and mass spectrometry determinations were in general agreement, and these values were consistent with the quoted values for two of the three diet colas. In the case of Diet Cherry Coke and the diet sports drinks, the determined caffeine amounts using both methods were consistently higher (by 8% or more) than the literature values.

  3. Effects of Ce concentrations on ignition temperature and surface tension of Mg-9wt.%Al alloy

    Directory of Open Access Journals (Sweden)

    Deng Zhenghua

    2013-03-01

    Full Text Available Magnesium alloys are well known for their excellent properties, but the potential issues with oxidation and burning during melting and casting largely limit its industrial applications. The addition of Ce in magnesium alloys can significantly raise ignition-proof performance and change the structure of the oxide film on the surface of the molten metal as well as the surface tension values. Surface tension is an important physical parameter of the metal melts, and it plays an important role in the formation of surface oxide film. In this present work, the ignition temperature and the surface tension of Mg-9wt.%Al alloy with different Ce concentrations were studied. Surface tensions was measured using the maximum bubble pressure method (MBPM. Ignition temperature was measured using NiCr-NiSi type thermocouples and was monitored and recorded via a WXT-604 desk recording device. The results show that the ignition point of Mg-9wt.%Al alloy can be effectively elevated by adding Ce. The ignition temperature reaches its highest point of 720 ℃ when the addition of Ce is 1wt.%. The surface tension of the molten Mg-9wt.%Al alloy decreases exponentially with the increase of Ce addition at the same temperature. Similarly, the experiment also shows that the surface tension of Mg-9wt.%Al alloy decreases exponentially with the increase of temperature.

  4. Glacier surface mass balance and freshwater runoff modeling for the entire Andes Cordillera

    Science.gov (United States)

    Mernild, Sebastian H.; Liston, Glen E.; Yde, Jacob C.

    2017-04-01

    Glacier surface mass balance (SMB) observations for the Andes Cordillera are limited and, therefore, estimates of the SMB contribution from South America to sea-level rise are highly uncertain. Here, we simulate meteorological, snow, glacier surface, and hydrological runoff conditions and trends for the Andes Cordillera (1979/80-2013/14), covering the tropical latitudes in the north down to the sub-polar latitudes in the far south, including the Northern Patagonia Ice Field (NPI) and Southern Patagonia Ice Field (SPI). SnowModel - a fully integrated energy balance, blowing-snow distribution, multi-layer snowpack, and runoff routing model - was used to simulate glacier SMBs for the Andes Cordillera. The Randolph Glacier Inventory and NASA Modern-Era Retrospective Analysis for Research and Applications products, downscaled in SnowModel, allowed us to conduct relatively high-resolution simulations. The simulated glacier SMBs were verified against independent directly-observed and satellite gravimetry and altimetry-derived SMB, indicating a good statistical agreement. For glaciers in the Andes Cordillera, the 35-year mean annual SMB was found to be -1.13 m water equivalent. For both NPI and SPI, the mean SMB was positive (where calving is the likely reason for explaining why geodetic estimates are negative). Further, the spatio-temporal freshwater river runoff patterns from individual basins, including their runoff magnitude and change, were simulated. For the Andes Cordillera rivers draining to the Pacific Ocean, 86% of the simulated runoff originated from rain, 12% from snowmelt, and 2% from ice melt, whereas, for example, for Chile, the water-source distribution was 69, 24, and 7%, respectively. Along the Andes Cordillera, the 35-year mean basin outlet-specific runoff (L s-1 km-2) showed a characteristic regional hourglass shape pattern with highest runoff in both Colombia and Ecuador and in Patagonia, and lowest runoff in the Atacama Desert area.

  5. Calibration of PM2.5 mass concentrations used in the Pittsburgh Aerosol Research and Inhalation Epidemiology Study

    Science.gov (United States)

    Bilonick, Richard A.; Connell, Daniel P.; Talbott, Evelyn O.; Xue, Tao; Rager, Judith R.

    2015-08-01

    Fifteen different types of PM2.5 mass concentration samplers were used by seven different monitoring networks at 47 locations in the Pittsburgh, Pennsylvania, region from 1999 to 2008. The samplers included Federal Reference Method (FRM) samplers, speciation samplers, tapered element oscillating microbalance (TEOM) samplers, and others. The different measurement principles used in these designs tended to lead to systematic differences (biases) when measuring the same quantity, and to differences in the typical size of random errors (imprecision) introduced by each type of sampler. Bias can take different forms either as a constant bias or as a non-constant (scale) bias, which depends on the size of the quantity being measured. The objective of the work presented here was to simultaneously calibrate the measurements made by these different samplers to remove relative biases (both constant and non-constant) so that all of the available PM2.5 data could be used interchangeably to develop exposure estimates for a retrospective epidemiology study. In order to accomplish this, we used linked temperature-stratified structural equation models, nonlinear regression models, and nonlinear mixed effects models. Applying these methods we constructed a comprehensive measurement error model that included both systematic error and random error components, and derived calibration equations that can be applied to place all of the PM2.5 mass concentration measurements on the same scale. The FRM sampler was used as the reference scale although the parameter estimates are invariant to this choice. Results showed that: (1) 50 °C TEOM samplers tended to show a large downward bias relative to the FRM sampler at low temperatures, and the magnitude of this bias decreased according to a nonlinear (sigmoidal) pattern with increasing temperature, (2) speciation samplers and other integrated samplers generally showed smaller biases relative to the FRM sampler that were not temperature

  6. Source tracking swine fecal waste in surface water proximal to swine concentrated animal feeding operations

    OpenAIRE

    Heaney, Christopher D.; Myers, Kevin; Wing, Steve; Hall, Devon; Baron, Dothula; Stewart, Jill R.

    2015-01-01

    Swine farming has gone through many changes in the last few decades, resulting in operations with a high animal density known as confined animal feeding operations (CAFOs). These operations produce a large quantity of fecal waste whose environmental impacts are not well understood. The purpose of this study was to investigate microbial water quality in surface waters proximal to swine CAFOs including microbial source tracking of fecal microbes specific to swine. For one year, surface water sa...

  7. Friction wear cast iron casting surface hardened by concentrated source of heat

    Directory of Open Access Journals (Sweden)

    W. Orlowicz

    2009-04-01

    Full Text Available In this study surface fusion by the GTAW (in argon atmosphere surfacing process on plate of cast iron with electric arc advance speedsfrom 200 to 800 mm/min and current range I=300A were performed. The geometry, microstructure, hardness, friction wear intensity weremeasured. A stepwise regression method was used to develop relationships between the electric arc advance speed, parameters of fusion geometry, microhardness and friction wear intensity.

  8. Determination of Se at low concentration in coal by collision/reaction cell technology inductively coupled plasma mass spectrometry

    Science.gov (United States)

    Henn, Alessandra S.; Rondan, Filipe S.; Mesko, Marcia F.; Mello, Paola A.; Perez, Magali; Armstrong, Joseph; Bullock, Liam A.; Parnell, John; Feldmann, Joerg; Flores, Erico M. M.

    2018-05-01

    A method is proposed for the determination of selenium at low concentration in coal by collision/reaction cell technology inductively coupled plasma mass spectrometry (CRC-ICP-MS). Samples were decomposed by high pressure microwave-assisted wet digestion (MAWD) using 250 mg of coal, a mixture of 5 mL of 14.4 mol L-1 HNO3 and 1 mL of 40% HF and 70 min of heating program (200 °C and 40 bar). Hydrogen gas used in the collision/reaction cell was investigated to minimize the argon-based interferences at m/z 77, 78 and 80. The rejection parameter (RPq) and the H2 gas flow rate were set to 0.45 and 4.8 mL min-1, respectively. The use of H2 in the cell resulted in other polyatomic interferences, such as 76Ge1H+, 79Br1H+ and 81Br1H+, which impaired Se determination using 77Se, 80Se and 82Se isotopes, thus Se determination was carried out by monitoring only 78Se isotope. Selenium was determined in certified reference materials of coal (NIST 1635 and SARM 20) and an agreement better than 95% was observed between the results obtained by CRC-ICP-MS and the certified values. Under optimized conditions, the instrumental limit of detection was 0.01 μg L-1 and the method limit of detection was 0.01 μg g-1, which was suitable for Se determination at very low concentration in coal.

  9. Concentration determination of urinary metabolites of N,N-dimethylacetamide by high-performance liquid chromatography-tandem mass spectrometry.

    Science.gov (United States)

    Yamamoto, Shinobu; Matsumoto, Akiko; Yui, Yuko; Miyazaki, Shota; Kumagai, Shinji; Hori, Hajime; Ichiba, Masayoshi

    2018-03-27

    N,N-Dimethylacetamide (DMAC) is widely used in industry as a solvent. It can be absorbed through human skin. Therefore, it is necessary to determine exposure to DMAC via biological monitoring. However, the precision of traditional gas chromatography (GC) is low due to the thermal decomposition of metabolites in the high-temperature GC injection port. To overcome this problem, we have developed a new method for the simultaneous separation and quantification of urinary DMAC metabolites using liquid chromatography-tandem mass spectrometry (LC-MS/MS). Urine samples were diluted 10-fold in formic acid, and 1-μl aliquots were injected into the LC-MS/MS equipment. A C18 reverse-phase Octa Decyl Silyl (ODS) column was used as the analytical column, and the mobile phase consisted of a mixture of methanol and aqueous formic acid solution. Urinary concentrations of DMAC and its known metabolites (N-hydroxymethyl-N-methylacetamide (DMAC-OH), N-methylacetamide (NMAC), and S- (acetamidomethyl) mercapturic acid (AMMA) ) were determined in a single run. The dynamic ranges of the calibration curves were 0.05-5 mg/l (r≥0.999) for all four compounds. The limits of detection for DMAC, DMAC-OH, NMAC, and AMMA in urine were 0.04, 0.02, 0.05, and 0.02 mg/l, respectively. Within-run accuracies were 96.5%-109.6% with relative standard deviations of precision being 3.43%-10.31%. The results demonstrated that the proposed method could successfully quantify low concentrations of DMAC and its metabolites with high precision. Hence, this method is useful for evaluating DMAC exposure. In addition, this method can be used to examine metabolite behaviors in human bodies after exposure and to select appropriate biomarkers.

  10. Pyrethroid insecticide concentrations and toxicity in streambed sediments and loads in surface waters of the San Joaquin Valley, California, USA

    Science.gov (United States)

    Domagalski, Joseph L.; Weston, Donald P.; Zhang, Minghua; Hladik, Michelle L.

    2010-01-01

    Pyrethroid insecticide use in California, USA, is growing, and there is a need to understand the fate of these compounds in the environment. Concentrations and toxicity were assessed in streambed sediment of the San Joaquin Valley of California, one of the most productive agricultural regions of the United States. Concentrations were also measured in the suspended sediment associated with irrigation or storm‐water runoff, and mass loads during storms were calculated. Western valley streambed sediments were frequently toxic to the amphipod, Hyalella azteca, with most of the toxicity attributable to bifenthrin and cyhalothrin. Up to 100% mortality was observed in some locations with concentrations of some pyrethroids up to 20 ng/g. The western San Joaquin Valley streams are mostly small watersheds with clay soils, and sediment‐laden irrigation runoff transports pyrethroid insecticides throughout the growing season. In contrast, eastern tributaries and the San Joaquin River had low bed sediment concentrations (pyrethroids in irrigation and storm water runoff. Esfenvalerate, fenpropathrin, and resmethrin were also detected. All sampled streams contributed to the insecticide load of the San Joaquin River during storms, but some compounds detected in the smaller creeks were not detected in the San Joaquin River. The two smallest streams, Ingram and Hospital Creeks, which had high sediment toxicity during the irrigation season, accounted for less than 5% of the total discharge of the San Joaquin River during storm conditions, and as a result their contribution to the pyrethroid mass load of the larger river was minimal. 

  11. The Influence of Electrolytic Concentration on the Electrochemical Deposition of Calcium Phosphate Coating on a Direct Laser Metal Forming Surface

    Directory of Open Access Journals (Sweden)

    Qianyue Sun

    2017-01-01

    Full Text Available A calcium phosphate (CaP coating on titanium surface enhances its biocompatibility, thus facilitating osteoconduction and osteoinduction with the inorganic phase of the human bone. Electrochemical deposition has been suggested as an effective means of fabricating CaP coatings on porous surface. The purpose of this study was to develop CaP coatings on a direct laser metal forming implant using electrochemical deposition and to investigate the effect of electrolytic concentration on the coating’s morphology and structure by X-ray diffraction, scanning electron microscopy, water contact angle analysis, and Fourier transform infrared spectroscopy. In group 10−2, coatings were rich in dicalcium phosphate, characterized to be thick, layered, and disordered plates. In contrast, in groups 10−3 and 10−4, the relatively thin and well-ordered coatings predominantly consisted of granular hydroxyapatite. Further, the hydrophilicity and cell affinity were improved as electrolytic concentration increased. In particular, the cells cultured in group 10−3 appeared to have spindle morphology with thick pseudopodia on CaP coatings; these spindles and pseudopodia strongly adhered to the rough and porous surface. By analyzing and evaluating the surface properties, we provided further knowledge on the electrolytic concentration effect, which will be critical for improving CaP coated Ti implants in the future.

  12. Arsenic Concentration in the Surface Water of a Former Mining Area: The La Junta Creek, Baja California Sur, Mexico

    Science.gov (United States)

    Imaz Lamadrid, Miguel; Acosta Vargas, Baudilio

    2018-01-01

    The mining activity in the San Antonio-El Triunfo district, located in a mountainous region at 60 km southeast of La Paz, occured for more than 250 years and left behind severe contamination of soils and riverbed sediments which led to elevated concentrations of arsenic and other trace elements in the surface- and groundwater of the region. Although the main mining activity ended around 1911, contamination is still beeing distributed, especially from left behind tailings and mine waste piles. The contamination levels in the groundwater have been reported in several studies, but there is little information available on the surface water quality, and especially the temporal variation. In this study, we analyzed the surface water of the La Junta creek, in the southern part of the San Antonio-El Triunfo mining district. The working hypothesis was that by means of a spatial analysis of surface water and shallow groundwater, in combination with the temporal observation of the concentrations in runoff water, the effects of different sources of arsenic (natural geogene anomalies, due to historic mining activity, and hydrothermal related impact) in the La Junta creek can be recognized. This present study revealed that historic mining activity caused a mojor impact of arsenic but less contamination was observed than in the northern part of the district and elevated arsenic concentrations in stream water generally occurred during times of low streamflow. PMID:29498700

  13. Explaining global surface aerosol number concentrations in terms of primary emissions and particle formation

    Directory of Open Access Journals (Sweden)

    D. V. Spracklen

    2010-05-01

    Full Text Available We synthesised observations of total particle number (CN concentration from 36 sites around the world. We found that annual mean CN concentrations are typically 300–2000 cm−3 in the marine boundary layer and free troposphere (FT and 1000–10 000 cm−3 in the continental boundary layer (BL. Many sites exhibit pronounced seasonality with summer time concentrations a factor of 2–10 greater than wintertime concentrations. We used these CN observations to evaluate primary and secondary sources of particle number in a global aerosol microphysics model. We found that emissions of primary particles can reasonably reproduce the spatial pattern of observed CN concentration (R2=0.46 but fail to explain the observed seasonal cycle (R2=0.1. The modeled CN concentration in the FT was biased low (normalised mean bias, NMB=−88% unless a secondary source of particles was included, for example from binary homogeneous nucleation of sulfuric acid and water (NMB=−25%. Simulated CN concentrations in the continental BL were also biased low (NMB=−74% unless the number emission of anthropogenic primary particles was increased or a mechanism that results in particle formation in the BL was included. We ran a number of simulations where we included an empirical BL nucleation mechanism either using the activation-type mechanism (nucleation rate, J, proportional to gas-phase sulfuric acid concentration to the power one or kinetic-type mechanism (J proportional to sulfuric acid to the power two with a range of nucleation coefficients. We found that the seasonal CN cycle observed at continental BL sites was better simulated by BL particle formation (R2=0.3 than by increasing the number emission from primary anthropogenic sources (R2=0.18. The nucleation constants that resulted in best overall match between model and observed CN concentrations were

  14. Electrochemical separation and isotopic determination of thallium at the nanogram level by surface ionisation mass spectrometry

    International Nuclear Information System (INIS)

    Arden, J.W.

    1983-01-01

    A rapid low-blank procedure is described for the co-separation of thallium and lead by sequential cathodic and anodic electrodeposition from natural samples, especially complex natural silicates, for subsequent mass spectrometry. A micro anion-exchange procedure is also described for the separation of thallium and lead. Ion currents of 10 - 10 A can be obtained from 1 ng of thallium. The isotopic composition of 1 ng of thallium can be measured on a Faraday detector with a precision of 0.05-0.1%. The total procedural blank is 3 pg. By using stable isotope dilution, 0.2 ng of thallium can be measured with a precision of 0.6% with only a 2% blank correction. This allows the accurate determination of thallium in natural samples down to concentration levels of about 50 pg g - 1 . The detection limit is 50 fg. This procedure has been applied to meteorites and terrestrial rocks. The stable isotope dilution technique is suitable for geochemical, environmental and toxicological studies requiring a highly sensitive, accurate and precise method for the determination of thallium. (Auth.)

  15. Short-term temperature-dependent air-surface exchange and atmospheric concentrations of polychlorinated naphthalenes and organochlorine pesticides

    Energy Technology Data Exchange (ETDEWEB)

    Lee, R.G.M.; Burnett, V.; Harner, T.; Jones, K.C.

    2000-02-01

    Atmospheric concentrations of five organochlorine (OC) pesticides, some of which have been banned for a number of years, and polychlorinated naphthalenes (PCNs) were measured at a U.K. site over periods of 6 h for 7 days resulting in 28 samples. Mean concentrations of the pesticides were {alpha}-HCH 90 pg m{sup {minus}3}, {gamma}-HCH 500, {rho},{rho}{prime}-DDE 8, dieldrin 63, endrin 22, and HCB 39. PCN mean homologue concentrations were {sub 3}CNs 67 pg m{sup {minus}3}, {sub 4}CNs 78, {sub 5}CNs 5, {sub 6}CNs 0.6, {sub 7}CNs 0.6, and {Sigma}PCNs 152. TEQ concentrations for those PCNs ascribed TEF values ranged between 0.36 and 3.6 fg m{sup {minus}3} which corresponds to {approximately}3.0--30% of the TEQ concentrations of PCDD/Fs at the same site. All the compounds measured, except HCB, exhibited a strong temperature-dependent diurnal cycling. Results from Clausius-Clapeyron plots show that pesticide concentrations were controlled by temperature-driven air-surface recycling throughout the first 5 days when stable atmospheric conditions were dominant, while during the last 2 days advection became more influential as more unstable and cooler weather started to influence the site. PCN concentrations were controlled primarily by a mixture of recycling and advection throughout the first 5 days and then by advection in the final 2 days, suggesting that there are ongoing emissions from diffuse point sources of PCNs into the U.K. atmosphere. This study provides further evidence of the rapid air-surface exchange of semivolatile organic compounds (SOCs) and shows how different factors alone or in combination can produce rapid changes in the atmospheric concentrations of past and present SOCs.

  16. Heat and mass transfer boundary conditions at the surface of a heated sessile droplet

    Science.gov (United States)

    Ljung, Anna-Lena; Lundström, T. Staffan

    2017-12-01

    This work numerically investigates how the boundary conditions of a heated sessile water droplet should be defined in order to include effects of both ambient and internal flow. Significance of water vapor, Marangoni convection, separate simulations of the external and internal flow, and influence of contact angle throughout drying is studied. The quasi-steady simulations are carried out with Computational Fluid Dynamics and conduction, natural convection and Marangoni convection are accounted for inside the droplet. For the studied conditions, a noticeable effect of buoyancy due to evaporation is observed. Hence, the inclusion of moisture increases the maximum velocities in the external flow. Marangoni convection will, in its turn, increase the velocity within the droplet with up to three orders of magnitude. Results furthermore show that the internal and ambient flow can be simulated separately for the conditions studied, and the accuracy is improved if the internal temperature gradient is low, e.g. if Marangoni convection is present. Simultaneous simulations of the domains are however preferred at high plate temperatures if both internal and external flows are dominated by buoyancy and natural convection. The importance of a spatially resolved heat and mass transfer boundary condition is, in its turn, increased if the internal velocity is small or if there is a large variation of the transfer coefficients at the surface. Finally, the results indicate that when the internal convective heat transport is small, a rather constant evaporation rate may be obtained throughout the drying at certain conditions.

  17. Mass transfer behavior of tritium from air to water through the water surface

    International Nuclear Information System (INIS)

    Takata, Hiroki; Nishikawa, Masabumi; Kamimae, Kozo

    2005-01-01

    It is anticipated that a certain amount of tritiated water exists in the atmosphere of tritium handling facilities, and it is recognized that the hazardous potential of tritiated water is rather high. Then, it is important to grasp the behavior of tritiated water for preserving of the radiation safety. The mass transfer behavior of tritium from air to water through the water surface was discussed in this study. The evaporation rate of water and the condensation rate of water were experimentally examined from measurement of change of the weight of distilled water. The tritium transfer rate from the tritiated water in air to the distilled water was also experimentally examined by using a liquid scintillation counter. Experimental results about change of tritium level in a small beaker placed in the atmosphere with tritiated water showed that diffusion of tritium in water and gas flow in the atmosphere gives considerable effect on tritium transfer. The estimation method of the tritium transfer made in this study was applied to explain the data at The Japan Atomic Power Company second power station at Tsuruga and good agreement was obtained. (author)

  18. Antibiotics in riverine runoff of the Pearl River Delta and Pearl River Estuary, China: Concentrations, mass loading and ecological risks

    International Nuclear Information System (INIS)

    Xu, Weihai; Yan, Wen; Li, Xiangdong; Zou, Yongde; Chen, Xiaoxiang; Huang, Weixia; Miao, Li; Zhang, Ruijie; Zhang, Gan; Zou, Shichun

    2013-01-01

    Ten antibiotics belonging to three groups (macrolides, fluoroquinolones and sulfonamides) were investigated in riverine runoff of the Pearl River Delta (PRD) and Pearl River Estuary (PRE), South China for assessing the importance of riverine runoff in the transportation of contaminants from terrestrial sources to the open ocean. All antibiotics were detected in the eight outlets with concentrations ranging from 0.7 to 127 ng L −1 . The annual mass loadings of antibiotics from the PRD to the PRE and coast were 193 tons with 102 tons from the fluoroquinolone group. It showed that antibiotics decreased from the riverine outlets to the PRE and open ocean. Risk assessment showed that most of these antibiotics showed various ecological risks to the relevant aquatic organisms, in which ofloxacin (OFL), erythromycin (ETM) and ciprofloxacin (CIP) posed high ecological risks to the studied aquatic environments. -- Highlights: •Antibiotics were ubiquitous in the river water and costal water in the Pearl River Delta. •Antibiotics exhibited distinct temporal and spatial trends in the riverine runoff outlets. •Annual outflows of antibiotics were 193 tons from the Pearl River to coastal ocean. •Some antibiotics posed high risks to some organisms in the PRD environments. -- Antibiotics were ubiquitous in the river and coastal water in the Pearl River Delta and posed various ecological risks to the relevant aquatic organisms

  19. Mass spectrometric detection and formation of D-amino acids in processed plant saps, syrups, and fruit juice concentrates.

    Science.gov (United States)

    Pätzold, Ralf; Brückner, Hans

    2005-12-14

    Liquid and syrupy dietary saps and juices of plant origin, characterized by the presence of large quantities of saccharides (glucose, fructose, or sucrose) and containing amino acids, were analyzed for the presence of D-amino acids using enantioselective gas chromatography-mass spectrometry. D-amino acids were detected in processed saps and juices of trees (maple, palm, birch), fruits (grape, apple, pear, pomegranate, date), and various other plants (agave, beetroot, sugar cane, carob). D-Ala was detected in all plant products and amounted to approximately 34% D-Ala (relative to L-Ala + D-Ala) in Canadian maple syrups, to approximately 13% in palm saps, and to 48 and 13% D-Ala, respectively, in concentrated grape juices (Spanish Arrope and Turkish Pekmez). Varying amounts and kinds of other D-amino acids were also detected. To test the hypothesis that racemization, that is, partial conversion of L-amino acids into their corresponding D-enantiomers, occurs at reversible stages of the Maillard reaction, the Amadori compound fructose-L-phenylalanine was synthesized. On heating at 200 degrees C for 5 (20) min, release of 10.8% (24.2%) D-Phe was detected. From the data it is concluded that the Amadori compounds formed in the course of the Maillard reaction are pecursors of D-amino acids in foodstuffs.

  20. Waist-to-Hip Ratio, but Not Body Mass Index, Is Associated with Testosterone and Estradiol Concentrations in Young Women

    Directory of Open Access Journals (Sweden)

    Ricardo Mondragón-Ceballos

    2015-01-01

    Full Text Available We studied if testosterone and estradiol concentrations are associated with specific female waist-to-hip ratios (WHRs and body mass indices (BMIs. Participants were 187 young women from which waist, hips, weight, and height were measured. In addition, participants informed on which day of their menstrual cycle they were and provided a 6 mL saliva sample. Ninety-one of them were in the follicular phase and 96 in the luteal phase. Only in the fertile phase of the menstrual cycle we found a significant interaction between testosterone and estradiol affecting WHR (b±s.e.=-0.000003±0.000001; t94=-2.12, adjusted R2=-0.008, P=0.03. Women with the highest levels of both hormones had the lowest WHRs, while women with low estradiol and high testosterone showed the highest WHRs. BMI significantly increased as testosterone increased in female in their nonfertile days.

  1. In Situ SIMS and IR Spectroscopy of Well-Defined Surfaces Prepared by Soft Landing of Mass-Selected Ions

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, Grant E.; Gunaratne, Kalupathirannehelage Don D.; Laskin, Julia

    2014-06-16

    Soft landing of mass-selected ions onto surfaces is a powerful approach for the highly-controlled preparation of materials that are inaccessible using conventional synthesis techniques. Coupling soft landing with in situ characterization using secondary ion mass spectrometry (SIMS) and infrared reflection absorption spectroscopy (IRRAS) enables analysis of well-defined surfaces under clean vacuum conditions. The capabilities of three soft-landing instruments constructed in our laboratory are illustrated for the representative system of surface-bound organometallics prepared by soft landing of mass-selected ruthenium tris(bipyridine) dications, [Ru(bpy)3]2+, onto carboxylic acid terminated self-assembled monolayer surfaces on gold (COOH-SAMs). In situ time-of-flight (TOF)-SIMS provides insight into the reactivity of the soft-landed ions. In addition, the kinetics of charge reduction, neutralization and desorption occurring on the COOH-SAM both during and after ion soft landing are studied using in situ Fourier transform ion cyclotron resonance (FT-ICR)-SIMS measurements. In situ IRRAS experiments provide insight into how the structure of organic ligands surrounding metal centers is perturbed through immobilization of organometallic ions on COOH-SAM surfaces by soft landing. Collectively, the three instruments provide complementary information about the chemical composition, reactivity and structure of well-defined species supported on surfaces.

  2. In situ SIMS and IR spectroscopy of well-defined surfaces prepared by soft landing of mass-selected ions.

    Science.gov (United States)

    Johnson, Grant E; Gunaratne, K Don Dasitha; Laskin, Julia

    2014-06-16

    Soft landing of mass-selected ions onto surfaces is a powerful approach for the highly-controlled preparation of materials that are inaccessible using conventional synthesis techniques. Coupling soft landing with in situ characterization using secondary ion mass spectrometry (SIMS) and infrared reflection absorption spectroscopy (IRRAS) enables analysis of well-defined surfaces under clean vacuum conditions. The capabilities of three soft-landing instruments constructed in our laboratory are illustrated for the representative system of surface-bound organometallics prepared by soft landing of mass-selected ruthenium tris(bipyridine) dications, [Ru(bpy)3](2+) (bpy = bipyridine), onto carboxylic acid terminated self-assembled monolayer surfaces on gold (COOH-SAMs). In situ time-of-flight (TOF)-SIMS provides insight into the reactivity of the soft-landed ions. In addition, the kinetics of charge reduction, neutralization and desorption occurring on the COOH-SAM both during and after ion soft landing are studied using in situ Fourier transform ion cyclotron resonance (FT-ICR)-SIMS measurements. In situ IRRAS experiments provide insight into how the structure of organic ligands surrounding metal centers is perturbed through immobilization of organometallic ions on COOH-SAM surfaces by soft landing. Collectively, the three instruments provide complementary information about the chemical composition, reactivity and structure of well-defined species supported on surfaces.

  3. Utilization of surface Plasmon resonance band of silver nanoparticles for determination of critical micelle concentration of cationic surfactants

    Science.gov (United States)

    Salem, Jamil K.; El-Nahhal, Issa M.; Najri, Bassam A.; Hammad, Talaat M.

    2016-11-01

    We have utilized surface Plasmon resonance (SPR) band sensitivity to surfactant concentration to investigate the critical micelle concentration (cmc) of CTAB, HY and CPB. The process is based upon an in situ formation of silver nanoparticles (AgNPs) through the reduction of silver ions (Ag+) by diethylene triamine (DETA) at 25 °C. In the presence of cationic surfactants, Ag+ ions can be reduced to AgNPs in a few minutes, accompanied by changes in intensity and wavelength of the SPR band. The spectral shifts of SPR band and the change of color have been used to determine CMC values of cationic surfactants.

  4. CONCENTRATION DEPENDENCE OF STERN LAYER CAPACITANCES AND SURFACE EQUILIBRIUM CONSTANTS IN SILICA-BASED NANOFLUIDIC CHANNELS

    DEFF Research Database (Denmark)

    Andersen, Mathias Bækbo; Frey, J.; Bruus, Henrik

    2010-01-01

    Fundamental understanding of the unique physics at the solid-liquid interface in nanofluidic channels is essential for the advancement of basic scientific knowledge and the development of novel applications for pharmaceuticals, environmental health and safety, energy harvesting and biometrics [1......]. The current models used to describe surface phenomena in nanofluidics can differ by orders of magnitude from experimentally measured values [2]. To mitigate the discrepancies, we hypothesize that the Stern-layer capacitance Cs and the surface equilibrium constants pKa, vary with the composition of the solid...

  5. Do galaxy global relationships emerge from local ones? The SDSS IV MaNGA surface mass density-metallicity relation

    Science.gov (United States)

    Barrera-Ballesteros, Jorge K.; Heckman, Timothy M.; Zhu, Guangtun B.; Zakamska, Nadia L.; Sánchez, Sebastian F.; Law, David; Wake, David; Green, Jenny E.; Bizyaev, Dmitry; Oravetz, Daniel; Simmons, Audrey; Malanushenko, Elena; Pan, Kaike; Roman Lopes, Alexandre; Lane, Richard R.

    2016-12-01

    We present the stellar surface mass density versus gas metallicity (Σ*-Z) relation for more than 500 000 spatially resolved star-forming resolution elements (spaxels) from a sample of 653 disc galaxies included in the SDSS IV MaNGA survey. We find a tight relation between these local properties, with higher metallicities as the surface density increases. This relation extends over three orders of magnitude in the surface mass density and a factor of 4 in metallicity. We show that this local relationship can simultaneously reproduce two well-known properties of disc galaxies: their global mass-metallicity relationship and their radial metallicity gradients. We also find that the Σ*-Z relation is largely independent of the galaxy's total stellar mass and specific star formation rate (sSFR), except at low stellar mass and high sSFR. These results suggest that in the present-day universe local properties play a key role in determining the gas-phase metallicity in typical disc galaxies.

  6. Surface Acoustic Wave Nebulisation Mass Spectrometry for the Fast and Highly Sensitive Characterisation of Synthetic Dyes in Textile Samples

    NARCIS (Netherlands)

    Astefanei, A.; van Bommel, M.; Corthals, G.L.

    2017-01-01

    Surface acoustic wave nebulisation (SAWN) mass spectrometry (MS) is a method to generate gaseous ions compatible with direct MS of minute samples at femtomole sensitivity. To perform SAWN, acoustic waves are propagated through a LiNbO3 sampling chip, and are conducted to the liquid sample, which

  7. Salinity maxima associated with some sub-surface water masses in the upper layers of the Bay of Bengal

    Digital Repository Service at National Institute of Oceanography (India)