WorldWideScience

Sample records for surface impoundment performance

  1. Closure certification report: TA-35 TSL-125 surface impoundment

    International Nuclear Information System (INIS)

    1991-01-01

    This report summarizes the actions that were taken to clean close the TA-35 TSL-125 surface impoundment Building 125 is used for developing electron guns and related laser assemblies/equipment for a Laser Technology Research Program at the Laboratory. There is no permanent outfall from the surface impoundment; however, the impoundment accidentally overtopped on December 3, 1986, spilling an unknown volume of insulating oil and water into Ten Site Canyon. Sandbags were installed around the surface impoundment on June 25, 1988, to provide additional freeboard in the impoundment and reduce the risk of overtopping during a precipitation event. On July 1, 1988, the impoundment again overtopped releasing an unknown volume of insulating oil and water. Actions taken include removal of waste from the surface impoundment and its associated structures, decontamination of the floor trough and piping inside Building 125, grouting of the piping connecting the floor drain/trough system to the impoundment, decontamination, removal, and disposal of the impoundment liner and sandbags lining the top of the impoundment, and removal and disposal of contaminated soil underlying the impoundment area. Procedures followed to verify that clean closure objectives have been met are also documented in this report. Initial verification was performed through an extensive soil sampling and analysis program

  2. 40 CFR 268.4 - Treatment surface impoundment exemption.

    Science.gov (United States)

    2010-07-01

    ... residues may not be placed in any other surface impoundment for subsequent management. (iv) Recordkeeping... exemption. 268.4 Section 268.4 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID...), the residues from treatment are analyzed, as specified in § 268.7 or § 268.32, to determine if they...

  3. French Modular Impoundment: Final Cost and Performance Evaluation

    Energy Technology Data Exchange (ETDEWEB)

    Drown, Peter [French Development Enterprises, LLC, North Billerica, MA (United States); French, Bill [French Development Enterprises, LLC, North Billerica, MA (United States)

    2017-05-17

    This report comprises the Final Cost and Performance Report for the Department of Energy Award # EE0007244, the French Modular Impoundment (aka the “French Dam”.) The French Dam is a system of applying precast modular construction to water control structures. The “French Dam” is a term used to cover the construction means/methods used to construct or rehabilitate dams, diversion structures, powerhouses, and other hydraulic structures which impound water and are covered under FDE’s existing IP (Patents # US8414223B2; US9103084B2.)

  4. Closure certification report: TA-35 TSL-125 surface impoundment

    International Nuclear Information System (INIS)

    1991-01-01

    This closure report documents closure activities for the TA-35 TSL-125 surface impoundment and associated structures at Los Alamos National Laboratory (the Laboratory). Prior to formal approval of the closure plan, the decision was made to proceed with closure activities to prevent any further releases from the site following informal discussions with New Mexico Environment Department (NMED) personnel. The closure plan is a revision of the previously submitted draft dated July 1988. Clean closure of the TSL-125 site was accomplished through: Removal and proper disposal of all wastes contained within the surface impoundment system; Decontamination and/or removal and proper disposal of the surface impoundment, its associated structures, and contaminated soil underlying the impoundment area; Sampling and analysis of soil to determine the presence and concentrations of any hazardous constituents remaining in the soil at the TSL-125 site; and Demonstration through a risk assessment that any constituents remaining in the soil at the TSL-125 site pose no threat to human health and the environment. All remaining soil concentrations of hazardous constituents were below health-based action levels. Analytical results indicated that benzidine, n-nitrosodimethylamine, and n-nitrosodi-n-propylamine were not detected at or above their limits of quantitation and beryllium was not present at or above its laboratory detection limit. However, the limits of quantitation and detection for these constituents were greater than their calculated health-based action levels. To demonstrate that these constituents were not present, historical data was researched and it was determined that the constituents were not utilized at the Building 125 site. 4 refs., 8 figs., 1 tab

  5. Technical work plan for Surface Impoundments Operable Unit engineering support studies

    International Nuclear Information System (INIS)

    1995-11-01

    This document provides a comprehensive work plan which, when utilized as a data collection guide for field activities, will provide the necessary information required to complete a report on geotechnical properties of the sediments contained in the Surface Impoundments Operable Unit at Oak Ridge National Laboratory in Oak Ridge, Tennessee. Detailed guidance is provided for the following activities: collection of samples from the impoundments; compressive strength testing of the raw sediments; compressive strength testing of the structurally modified (lime and cement additives) sediments; testing for sediment physical properties and settling rates; testing for sediment dewatering characteristics; testing for radiation activity during the field work; testing for polymer additions that may enhance settling. The work plan additionally provides guidance and examples for the preparation of documents necessary to establish readiness for safe and satisfactory performance of the field activities. An outline for the format requested for a report of these data is also provided

  6. Technical work plan for Surface Impoundments Operable Unit engineering support studies

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-11-01

    This document provides a comprehensive work plan which, when utilized as a data collection guide for field activities, will provide the necessary information required to complete a report on geotechnical properties of the sediments contained in the Surface Impoundments Operable Unit at Oak Ridge National Laboratory in Oak Ridge, Tennessee. Detailed guidance is provided for the following activities: collection of samples from the impoundments; compressive strength testing of the raw sediments; compressive strength testing of the structurally modified (lime and cement additives) sediments; testing for sediment physical properties and settling rates; testing for sediment dewatering characteristics; testing for radiation activity during the field work; testing for polymer additions that may enhance settling. The work plan additionally provides guidance and examples for the preparation of documents necessary to establish readiness for safe and satisfactory performance of the field activities. An outline for the format requested for a report of these data is also provided.

  7. Post-remediation action radiological report for Surface Impoundments C (3539) and D (3540) at the Oak Ridge National Laboratory, Oak Ridge, Tennessee

    International Nuclear Information System (INIS)

    1998-12-01

    During August and September 1998, Bechtel Jacobs Company LLC performed a remedial action within Impoundments 3539 and 3540 (Impoundments C and D, respectively) in accordance with the Comprehensive Environmental Response, Compensation, and Liability Act Record of Decision (ROD) for the Surface Impoundments Operable Unit. The remedial action included removal of sediments and 0.1 ft of subimpoundment soil. A post-remedial action radiological survey was conducted to provide data to support the Bethel Valley ROD. Data was obtained from (1) a walkover survey for residual gamma radiation on the base of the impoundments, (2) smear surveys for transferable contamination on remaining riprap, and (3) representative sampling of subimpoundment soils. Walkover surveys identified no locations outside the impoundments with gamma exposure levels greater than three times background levels. Smear surveys detected no removable contamination above release limits as specified in 10 CFR 835, Appendix D. Subimpoundment soil samples quantified low levels of residual contamination

  8. Transport and dispersion of pollutants in surface impoundments: a finite difference model

    Energy Technology Data Exchange (ETDEWEB)

    Yeh, G.T.

    1980-07-01

    A surface impoundment model by finite-difference (SIMFD) has been developed. SIMFD computes the flow rate, velocity field, and the concentration distribution of pollutants in surface impoundments with any number of islands located within the region of interest. Theoretical derivations and numerical algorithm are described in detail. Instructions for the application of SIMFD and listings of the FORTRAN IV source program are provided. Two sample problems are given to illustrate the application and validity of the model.

  9. An experimental approach to determining subsurface leakage from a surface impoundment using a radioisotope tracer

    International Nuclear Information System (INIS)

    Ashwood, T.L.; Story, J.D.; Larsen, I.L.; Schultz, F.J.

    1987-01-01

    Bromine-82, a 35.3-h half-life radionuclide, was used as a tracer to determine the paths and rates of leakage from an unlined, 1,000,000-gal (3,785,000 L), surface impoundment at the Oak Ridge National Laboratory. Since the impoundment is underlain and surrounded by storm sewer and sanitary sewer lines (most of them predating the impoundment), known and suspected leak sites in storm drain catch basins and sanitary sewer manholes were sampled periodically and analyzed for 82 Br. A series of four ground water monitoring wells - three downgradient and one upgradient from the impoundment - were also sampled for 82 Br. Although the catch basin and manhole samples picked up 82 Br in leakage from the impoundment less than 5 h after application of the tracer, the monitoring well samples did not contain detectable levels of the radionuclide. It was concluded that the monitoring wells were sampling groundwater moving through the formation, whereas the storm drains and manholes were sampling water leading rapidly through secondary porosity and along preferred pathways. The decline in tracer concentration as a function of time was used to determine the residence time of water in the pond and hence the flow rate through the pond. This flow rate, when compared with the known outflow rate, indicated that the leakage flow was small. Hence, the main value of the test was to identify rapid leakage pathways. The experiment demonstrates the need for sampling subsurface drain systems as part of an integrated monitoring system for leak detection. The effectiveness of 82 Br as a tracer for rapid leaks was also shown

  10. Transport and dispersion of pollutants in surface impoundments: a finite element model

    International Nuclear Information System (INIS)

    Yeh, G.T.

    1980-07-01

    A surface impoundment model in finite element (SIMFE) is presented to enable the simulation of flow circulations and pollutant transport and dispersion in natural or artificial lakes, reservoirs or ponds with any number of islands. This surface impoundment model consists of two sub-models: hydrodynamic and pollutant transport models. Both submodels are simulated by the finite element method. While the hydrodynamic model is solved by the standard Galerkin finite element scheme, the pollutant transport model can be solved by any of the twelve optional finite element schemes built in the program. Theoretical approximations and the numerical algorithm of SIMFE are described. Detail instruction of the application are given and listing of FORTRAN IV source program are provided. Two sample problems are given. One is for an idealized system with a known solution to show the accuracy and partial validation of the models. The other is applied to Prairie Island for a set of hypothetical input data, typifying a class of problems to which SIMFE may be applied

  11. Transport and dispersion of pollutants in surface impoundments: a finite element model

    Energy Technology Data Exchange (ETDEWEB)

    Yeh, G.T.

    1980-07-01

    A surface impoundment model in finite element (SIMFE) is presented to enable the simulation of flow circulations and pollutant transport and dispersion in natural or artificial lakes, reservoirs or ponds with any number of islands. This surface impoundment model consists of two sub-models: hydrodynamic and pollutant transport models. Both submodels are simulated by the finite element method. While the hydrodynamic model is solved by the standard Galerkin finite element scheme, the pollutant transport model can be solved by any of the twelve optional finite element schemes built in the program. Theoretical approximations and the numerical algorithm of SIMFE are described. Detail instruction of the application are given and listing of FORTRAN IV source program are provided. Two sample problems are given. One is for an idealized system with a known solution to show the accuracy and partial validation of the models. The other is applied to Prairie Island for a set of hypothetical input data, typifying a class of problems to which SIMFE may be applied.

  12. Results of the measurement survey of elevation and environmental media in surface impoundments 3513 (B) and 3524 (A) at Oak Ridge National Laboratory, Oak Ridge, Tennessee

    International Nuclear Information System (INIS)

    Murray, M.E.; Rose, D.A.; Brown, K.S.; Coe, R.H.C. III; Lawrence, J.D.; Winton, W.

    1998-07-01

    A measurement survey of the elevation and environmental media in impoundments 3513 (B) and 3524 (A) at the Oak Ridge National Laboratory (ORNL) was conducted during April 1998. The investigation was performed by the Measurement Applications and Development Group of the Life Sciences Division of ORNL at the request of Bechtel Jacobs Company. Measurement activities were conducted at selected locations in order to determine the depth and appearance of the sediment and describe the clay underlying the impoundments prior to remediation. The survey was a follow-up to a previous elevation survey. The survey included the following: collection of sediment/clay cores from selected locations in each impoundment; measurement and documentation of the elevation at the water surface, at the top of sediment, at the top of clay, and at the bottom of each core; visual inspection of each core by a soil scientist to confirm the presence of clay and not material such as fly ash and soda lime compacted over the last 50 years; measurement and documentation of the background beta-gamma radiation level at the time and location of collection of each core, the highest beta-gamma level along the sediment portion of each core, and the highest beta-gamma level along the clay portion of each core; measurement and documentation of the length of the clay and of the sediment portion of each core; photographic documentation of each core; and replacement of each core in the impoundment

  13. Results of the radiological and chemical characterization of surface impoundments 3539 and 3540 at Oak Ridge National Laboratory, Oak Ridge, Tennessee

    International Nuclear Information System (INIS)

    Murray, M.E.; Rose, D.A.; Brown, K.S.; Winton, W.; Dean, R.A.; Coe, R.H. III

    1998-03-01

    A radiological and chemical characterization survey of impoundments 3539 and 3540 at the Oak Ridge National Laboratory (ORNL) was conducted during December 1997. Impoundments 3539 and 3540 are located in the Surface Impoundments Operable Unit (SIOU) of Waste Area Group 1. The investigation was performed by the Measurement Applications and Development Group of the Life Sciences Division of ORNL at the request of the Department of Energy (DOE) Office of Environmental Restoration. Sampling was conducted in order to quantify the presence of polychlorinated biphenyls (PCBs), Resource Conservation and Recovery Act (RCRA) constituents, and other contaminants of interest in support of the Comprehensive Environmental Response, Compensation and Liability Act (CERCLA) remediation for the SIOU> The survey included collection of sediment/clay samples, quality control blank water samples and equipment rinsate samples for chemical and radiological analysis. Results show the samples contain traces of various organic, inorganic, and radioactive materials. Of particular interest are PCB values which demonstrate the impoundments are not regulated under the Toxic Substances Control Act

  14. Probabilistic risk assessment for the Sandia National Laboratories Technical Area V Liquid Waste Disposal System surface impoundments

    International Nuclear Information System (INIS)

    Dawson, L.A.; Eidson, A.F.

    1996-01-01

    A probabilistic risk assessment was completed for a former radioactive waste disposal site. The site, two unlined surface impoundment, was designed as part of the Liquid Waste Disposal System (LWDS) to receive radioactive effluent from nuclear reactors in Technical Area-V (TA-V) at Sandia National Laboratories/New Mexico (SNL/NM). First, a statistical comparison of site sampling results to natural background, using EPA methods, and a spatial distribution analysis were performed. Risk assessment was conducted with SNL/NM's Probabilistic Risk Evaluation and Characterization Investigation System model. The risk assessment indicated that contamination from several constituents might have been high enough to require remediation. However, further analysis based on expected site closure activities and recent EPA guidance indicated that No Further Action was acceptable

  15. Coal combustion waste management at landfills and surface impoundments 1994-2004.

    Energy Technology Data Exchange (ETDEWEB)

    Elcock, D.; Ranek, N. L.; Environmental Science Division

    2006-09-08

    On May 22, 2000, as required by Congress in its 1980 Amendments to the Resource Conservation and Recovery Act (RCRA), the U.S. Environmental Protection Agency (EPA) issued a Regulatory Determination on Wastes from the Combustion of Fossil Fuels. On the basis of information contained in its 1999 Report to Congress: Wastes from the Combustion of Fossil Fuels, the EPA concluded that coal combustion wastes (CCWs), also known as coal combustion by-products (CCBs), did not warrant regulation under Subtitle C of RCRA, and it retained the existing hazardous waste exemption for these materials under RCRA Section 3001(b)(3)(C). However, the EPA also determined that national regulations under Subtitle D of RCRA were warranted for CCWs that are disposed of in landfills or surface impoundments. The EPA made this determination in part on the basis of its findings that 'present disposal practices are such that, in 1995, these wastes were being managed in 40 percent to 70 percent of landfills and surface impoundments without reasonable controls in place, particularly in the area of groundwater monitoring; and while there have been substantive improvements in state regulatory programs, we have also identified gaps in State oversight' (EPA 2000). The 1999 Report to Congress (RTC), however, may not have reflected the changes in CCW disposal practices that occurred since the cutoff date (1995) of its database and subsequent developments. The U.S. Department of Energy (DOE) and the EPA discussed this issue and decided to conduct a joint DOE/EPA study to collect new information on the recent CCW management practices by the power industry. It was agreed that such information would provide a perspective on the chronological adoption of control measures in CCW units based on State regulations. A team of experts from the EPA, industry, and DOE (with support from Argonne National Laboratory) was established to develop a mutually acceptable approach for collecting and analyzing data

  16. Influence of lake surface area and total phosphorus on annual bluegill growth in small impoundments of central Georgia

    Science.gov (United States)

    Jennings, Cecil A.; Sundmark, Aaron P.

    2017-01-01

    The relationships between environmental variables and the growth rates of fishes are important and rapidly expanding topics in fisheries ecology. We used an informationtheoretic approach to evaluate the influence of lake surface area and total phosphorus on the age-specific growth rates of Lepomis macrochirus (Bluegill) in 6 small impoundments in central Georgia. We used model averaging to create composite models and determine the relative importance of the variables within each model. Results indicated that surface area was the most important factor in the models predicting growth of Bluegills aged 1–4 years; total phosphorus was also an important predictor for the same age-classes. These results suggest that managers can use water quality and lake morphometry variables to create predictive models specific to their waterbody or region to help develop lake-specific management plans that select for and optimize local-level habitat factors for enhancing Bluegill growth.

  17. Erosion protection of uranium tailings impoundments

    International Nuclear Information System (INIS)

    Walters, W.H.; Skaggs, R.L.; Foley, M.G.; Beedlow, P.A.

    1986-09-01

    Pacific Northwest Laboratory (PNL) prepared this report to assist in the design and review of erosion protection works for decommissioned uranium tailings impoundments. The major causes of erosion over the long-term decommissioning period are from rainfall-runoff (overland flow) and stream channel flooding. The method of protection recommended for the impoundment side slopes and site drainage channels is rock riprap. Combinations of vegetation and rock mulch are recommended for the top surface. The design methods were developed from currently available procedures supplemented by field, laboratory, and mathematical model studies performed by PNL. Guidelines for the placement of riprap, inspection, and maintenance are presented. Other subjects discussed are rock selection and testing, slope stability, and overland erosion modeling

  18. 40 CFR 270.17 - Specific part B information requirements for surface impoundments.

    Science.gov (United States)

    2010-07-01

    ... migration of any hazardous constituents into the ground water or surface water at any future time; (2) The....19 of this chapter; (5) Proposed action leakage rate, with rationale, if required under § 264.222 of..., including the double liner system, leak detection system, cover system, and appurtenances for control of...

  19. Hydrologic effects of impoundments in Sherburne National Wildlife Refuge, Minnesota

    Science.gov (United States)

    Brown, R.G.

    1984-01-01

    The hydrologic effects of proposed impoundments in Sherburne National Wildlife Refuge were found to be insignificant with respect to both ground- and surface-water flow patterns and water quality. Monitoring of water levels in 23 observation wells and of discharge in the St. Francis River during 1980 and 1981 has shown that ground water in the surf icial aquifer responds quickly to areal recharge and subsequently discharges to the St. Francis River. The impoundment of surface water in the refuge was not found to affect water levels in the refuge significantly. The impoundments may affect ground-water-flow systems beneath and adjacent to the impoundments. Quality of ground and surface water was found to be similar except ground water contained higher concentrations of dissolved nitrite plus nitrate nitrogen than surface water. Phytoplankton removed dissolved nitrite plus nitrate nitrogen from surface water. The effects of impoundments on water quality are expected to be minor.

  20. 30 CFR 816.84 - Coal mine waste: Impounding structures.

    Science.gov (United States)

    2010-07-01

    ... control, the probable maximum precipitation of a 6-hour precipitation event, or greater event as specified.... Runoff from areas above the disposal facility or runoff from surface of the facility that may cause...-hour design precipitation event. (e) Impounding structures constructed of or impounding coal mine waste...

  1. Design and construction of an impoundment for precious metal mill tailings

    International Nuclear Information System (INIS)

    Moldt, S.F.; Miller, R.G.; Johnson, K.

    1985-01-01

    An engineering study and design of impoundments for the disposal of mill tailings is presented. The site is located in central Nevada, and the mill will incorporate conventional flotation followed by a carbon-in-pulp cyanide process for extraction of gold from ore. Mill process waste will be generated as flotation tailings and cyanide residue. Permeable site soils and environmental considerations required the prevention of infiltration of cyanide residue leachate into the subgrade. Geochemical modeling of flotation tailings indicated the potential for high concentration of iron and nickel to be present in the flotation tailings leachate. On-site soils were optimized for use in construction of the separate flotation tailings and cyanide residue impoundments. Embankments were constructed on compacted on-site sandy gravels. The cyanide residue impoundment was designed using a four-layer liner, utilizing all on-site soils and chemical soil additives. The liner consists of a leachate collection system over a low-permeability layer, which in turn is underlain by a leak detection drainage blanket and a low permeability subliner. The geochemical modeling performed in the analysis indicated that placement of a thin layer of oxidized surface soils, high in soluble sulfates, on the bottom of the flotation tailings impoundment would be sufficient to react with tailings leachate and cause precipitation of ferric oxide and the associated removal of nickel, permitting flotation tailings leachate to dilute acceptably with natural groundwater

  2. 30 CFR 816.49 - Impoundments.

    Science.gov (United States)

    2010-07-01

    ..., prudent, engineering practices and any design criteria established by the regulatory authority. The... surrounding landowners for agricultural, industrial, recreational, or domestic uses. (6) The impoundment will... safely removed in accordance with current, prudent, engineering practices. Such an impoundment shall be...

  3. Dewatering tailings impoundments : interior drains

    International Nuclear Information System (INIS)

    Charlie, W.A.; Doehring, D.O.; Durnford, D.S.

    1984-01-01

    For the design of a new uranium tailings impoundment in the western United States, it was proposed that an interior drainage system be considered to economically and reliably minimize potential short- and long-term environmental impacts. The objectives were to decrease the effective hydraulic head on the clay liner, to dewater and stabilize the tailings, and to increase the amount of water recycled to the mill. In addition, desaturation of the impoundment would induce capillary pressure (negative porewater pressure), further reducing the potential movement of dissolved pollutants. This paper presents saturated and unsaturated seepage principles and reviews the concept, criteria and design of the various interior drainage systems considered

  4. Microbial communities in flowback water impoundments from hydraulic fracturing for recovery of shale gas.

    Science.gov (United States)

    Murali Mohan, Arvind; Hartsock, Angela; Hammack, Richard W; Vidic, Radisav D; Gregory, Kelvin B

    2013-12-01

    Hydraulic fracturing for natural gas extraction from shale produces waste brine known as flowback that is impounded at the surface prior to reuse and/or disposal. During impoundment, microbial activity can alter the fate of metals including radionuclides, give rise to odorous compounds, and result in biocorrosion that complicates water and waste management and increases production costs. Here, we describe the microbial ecology at multiple depths of three flowback impoundments from the Marcellus shale that were managed differently. 16S rRNA gene clone libraries revealed that bacterial communities in the untreated and biocide-amended impoundments were depth dependent, diverse, and most similar to species within the taxa γ-proteobacteria, α-proteobacteria, δ-proteobacteria, Clostridia, Synergistetes, Thermotogae, Spirochetes, and Bacteroidetes. The bacterial community in the pretreated and aerated impoundment was uniform with depth, less diverse, and most similar to known iodide-oxidizing bacteria in the α-proteobacteria. Archaea were identified only in the untreated and biocide-amended impoundments and were affiliated to the Methanomicrobia class. This is the first study of microbial communities in flowback water impoundments from hydraulic fracturing. The findings expand our knowledge of microbial diversity of an emergent and unexplored environment and may guide the management of flowback impoundments. © 2013 Federation of European Microbiological Societies. Published by John Wiley & Sons Ltd. All rights reserved.

  5. Microbial communities in flowback water impoundments from hydraulic fracturing for recovery of shale gas

    Energy Technology Data Exchange (ETDEWEB)

    Mohan, Arvind Murali; Hartsock, Angela; Hammack, Richard W; Vidic, Radisav D; Gregory, Kelvin B

    2013-12-01

    Hydraulic fracturing for natural gas extraction from shale produces waste brine known as flowback that is impounded at the surface prior to reuse and/or disposal. During impoundment, microbial activity can alter the fate of metals including radionuclides, give rise to odorous compounds, and result in biocorrosion that complicates water and waste management and increases production costs. Here, we describe the microbial ecology at multiple depths of three flowback impoundments from the Marcellus shale that were managed differently. 16S rRNA gene clone libraries revealed that bacterial communities in the untreated and biocide-amended impoundments were depth dependent, diverse, and most similar to species within the taxa [gamma]-proteobacteria, [alpha]-proteobacteria, δ-proteobacteria, Clostridia, Synergistetes, Thermotogae, Spirochetes, and Bacteroidetes. The bacterial community in the pretreated and aerated impoundment was uniform with depth, less diverse, and most similar to known iodide-oxidizing bacteria in the [alpha]-proteobacteria. Archaea were identified only in the untreated and biocide-amended impoundments and were affiliated to the Methanomicrobia class. This is the first study of microbial communities in flowback water impoundments from hydraulic fracturing. The findings expand our knowledge of microbial diversity of an emergent and unexplored environment and may guide the management of flowback impoundments.

  6. Wind erosion of waste impoundments in arid climates and mitigation of dust pollution.

    Science.gov (United States)

    Blight, G E

    2008-12-01

    Wind can erode and disperse fine-grained material from an impoundment of mining, industrial or municipal waste that stands above the level of its surroundings. Such dust dispersion can be a serious nuisance as well as a health hazard to inhabitants and animals in nearby settlements. It can also degrade crops, making them less marketable, and pollute soil, surface water and ground water. Wind can seasonally erode waste impoundments in all types of climate, but the erosion intensifies and persists for more of each year as regional aridity increases. As clouds of dust are often observed billowing across the top surfaces of waste impoundments in dry windy weather, there is a common misconception that dust arises from erosion of the top surface of an impoundment, resulting in much effort and money being misspent on top treatments when in fact the sloped sides of the impoundments are the true source of blown dust. This paper offers a brief review of general waste impoundment wind erosion issues and then focuses in more detail on the mechanics of how wind erodes surfaces of waste impoundments. Recommendations are offered for mitigating the effects of wind-eroded dust.

  7. Distribution of aquifers, liquid-waste impoundments, and municipal water-supply sources, Massachusetts

    Science.gov (United States)

    Delaney, David F.; Maevsky, Anthony

    1980-01-01

    Impoundments of liquid waste are potential sources of ground-water contamination in Massachusetts. The map report, at a scale of 1 inch equals 4 miles, shows the idstribution of aquifers and the locations of municipal water-supply sources and known liquid-waste impoundments. Ground water, an important source of municipal water supply, is produced from shallow sand and gravel aquifers that are generally unconfined, less than 200 feet thick, and yield less than 2,000 gallons per minute to individual wells. These aquifers commonly occupy lowlands and stream valleys and are most extensive in eastern Massachusetts. Surface impoundments of liquid waste are commonly located over these aquifers. These impoundments may leak and allow waste to infiltrate underlying aquifers and alter their water quality. (USGS)

  8. Rehabilitation of uranium tailings impoundments

    International Nuclear Information System (INIS)

    Crawley, A.H.

    1983-01-01

    Under Australian environmental controls relating to the management of uranium tailings, it is no longer acceptable practice to search for a rehabilitation strategy at the end of production when the generation of tailings has ceased. The uranium projects currently in production and those being proposed are tightly regulated by the authorities. The waste management plans must consider site specific factors and must include selection of appropriate disposal sites and design for long term containment. The final encapsulation in engineered facilities must take into account the probable routes to the environment of the tailings. Rehabilitation shoud be undertaken by the mining and milling operators to standards approved by appropriate authorities. Appropriate administrative arrangements are required, by way of technical committees and financial bonds to ensure that agreed standards of rehabilitation may be achieved. Past and present experience with the rehabilitation of uranium tailings impoundments in Australia is discussed

  9. 49 CFR 193.2181 - Impoundment capacity: LNG storage tanks.

    Science.gov (United States)

    2010-10-01

    ... LIQUEFIED NATURAL GAS FACILITIES: FEDERAL SAFETY STANDARDS Design Impoundment Design and Capacity § 193.2181 Impoundment capacity: LNG storage tanks. Each impounding system serving an LNG storage tank must have a... 49 Transportation 3 2010-10-01 2010-10-01 false Impoundment capacity: LNG storage tanks. 193.2181...

  10. 50 CFR 28.42 - Impounding of domestic animals.

    Science.gov (United States)

    2010-10-01

    ... 50 Wildlife and Fisheries 6 2010-10-01 2010-10-01 false Impounding of domestic animals. 28.42... VIOLATIONS OF PARTS 25, 26, AND 27 Impoundment Procedures § 28.42 Impounding of domestic animals. (a) Any animal trespassing on the lands of any national wildlife refuge may be impounded and disposed of in...

  11. 30 CFR 817.84 - Coal mine waste: Impounding structures.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Coal mine waste: Impounding structures. 817.84... ACTIVITIES § 817.84 Coal mine waste: Impounding structures. New and existing impounding structures constructed of coal mine waste or intended to impound coal mine waste shall meet the requirements of § 817.81...

  12. Design, permitting, and construction issues associated with closure of the Panna Maria uranium tailings impoundment

    International Nuclear Information System (INIS)

    Strachan, C.L.; Raabe, K.L.

    1997-01-01

    In 1992, Panna Maria Uranium Operations (PMUO) initiated licensing and engineering activities for closure of the Panna Maria mill and 150-acre tailings impoundment located in southeast Texas. Closure of the tailings impoundment is permitted by license amendment through the Texas Natural Resources Conservation Commission (TNRCC), and based on closure criteria outlined in Texas regulations. The closure plan for the Panna Maria tailings impoundment was submitted for Texas regulatory agency review in April 1993, with details of the closure plan modified in 1994, 1995, and 1996. The closure plan included a multi-layered cover over the regraded tailings surface which was designed for long-term isolation of tailings, reduction of radon emanation to regulated levels, and reduction of infiltration to TNRCC-accepted levels. The cover and embankment slope surfaces and surrounding areas were designed to provide acceptable erosional stability as compared to runoff velocities from the Probable Maximum Precipitation event. Cover materials were selected from on-site materials and evaluated for suitability based on permeability, radon attenuation, and soil dispersivity characteristics. Off-site materials were used when necessary. The cover over the tailings has a maximum slope of 0.5 percent, and the regraded embankment slopes outside the perimeter of the impoundment have a maximum slope of 20 percent. All reclaimed slopes are covered with topsoil and revegetated. A riprap-lined channel is to be used to convey runoff from within the perimeter of the reclaimed impoundment to the north of the impoundment

  13. Effects of seasonal drawdowns on fish assemblages in sections of an impounded river-canal system in upstate New York

    Science.gov (United States)

    George, Scott D.; Baldigo, Barry P.; Wells, Scott M

    2016-01-01

    The Mohawk River and New York State Barge Canal run together as a series of permanent and temporary impoundments for most of the distance between Rome and Albany, New York. The downstream or lower section is composed of two permanent impoundments, the middle section of a series of temporary (seasonal) impoundments, and the upper section of a series of permanent impoundments. In the middle section, movable dams are lifted from the water during winter and the wetted surface area decreases by 36–56%. We used boat electrofishing during spring 2014 and 2015 to compare the relative abundance of fish populations and the composition of fish assemblages between the permanently and seasonally impounded sections of the Barge Canal and to infer the effects of the two flow management practices. A total of 3,264 individuals from 38 species were captured, and total catch per unit effort (CPUE) ranged from 46.0 to 134.7 fish/h at sites in the seasonally impounded section, compared with 140.0–342.0 fish/h in the permanent lower section and 89.0–282.0 fish/h in the permanent upper section. The amount of drawdown explained 55% of the variation in total CPUE and was a highly significant predictor variable. Mean total CPUE in the seasonally impounded section was significantly lower (by about 50%) than that in either permanently impounded section, and the assemblage composition differed significantly between sections. The relative abundance of many lentic species was markedly lower in the seasonally impounded section, while the relative abundance of several native cyprinids and the percentage of individuals belonging to species that are native to the watershed was greater in this section. Overall, these findings suggest that winter dam removal in impounded rivers may reduce the abundance of fish but may also create more natural riverine conditions that favor some native species.

  14. Gully potential in soil-covered uranium waste impoundments

    International Nuclear Information System (INIS)

    Abt, S.R.; Hogan, S.A.; Johnson, T.L.

    1994-01-01

    Soil covers are routinely considered a design alternative to stabilize uranium waste impoundments. Gully intrusion into the cover is one of the greatest potential threats to the long-term stability of an impoundment. An investigation was conducted to estimate the maximum depth of gully intrusion, the approximate top width of the gully at the point of maximum incision, and the approximate location of the maximum intrusion. A large-scale laboratory study was conducted on seven embankments in which approximately 200 years of rainfall was simulated and the resulting gullies were documented. In addition, 11 gullies occurring in actual reclaimed impoundments were documented. An analysis of the laboratory and field data sets was performed in which the maximum depth of gully incision, top width of the gully, and location of the maximum gully incision were related to the pile height, tributary volume of runoff, and soil composition. These relations provide the designers with a means for assessing the cover design to meet the long-term stability of the waste

  15. Methodologies for evaluating long-term stabilization designs of uranium mill tailings impoundments

    International Nuclear Information System (INIS)

    Nelson, J.D.; Abt, S.R.; Volpe, R.L.; Van Zye, D.; Hinkle, N.E.; Staub, W.P.

    1986-06-01

    Uranium mill tailings impoundments require long-term (200 to 1000 years) stabilization. This report reviews currently available methodologies for evaluating factors that can have a significant influence on tailings stabilization and develops methodologies in technical areas where none presently exist. Mill operators can use these methodologies to assist with (1) the selection of sites for mill tailings impoundments, (2) the design of stable impoundments, and (3) the development of reclamation plans for existing impoundments. These methodologies would also be useful for regulatory agency evaluations of proposals in permit or license applications. Methodologies were reviewed or developed in the following technical areas: (1) prediction of the Probable Maximum Precipitation (PMP) and an accompanying Probable Maximum Flood (PMF); (2) prediction of the stability of local and regional fluvial systems; (3) design of impoundment surfaces resistant to gully erosion; (4) evaluation of the potential for surface sheet erosion; (5) design of riprap for protecting embankments from channel flood flow and overland flow; (6) selection of riprap with appropriate durability for its intended use; and (7) evaluation of oversizing required for marginal quality riprap

  16. Effects of rock riprap design parameters on flood protection costs for uranium tailings impoundments

    International Nuclear Information System (INIS)

    Ecker, R.M.

    1984-07-01

    The Pacific Northwest Laboratory (PNL) is studying the problem of long-term protection of earthen covers on decommissioned uranium tailings impoundments. The major erosive forces acting on these covers will be river flooding and overland flow from rainfall-runoff. For impoundments adjacent to rivers, overbank flooding presents the greater potential for significant erosion. To protect the earthen covers against flood erosion, rock riprap armoring will be placed over the cover surface. Because of the large size rock usually required for riprap, the quarrying, transport, and placement of the rock could be a significant part of the decommissioning cost. This report examines the sensitivity of riprap protection costs to certain design parameters at tailings impoundments. The parameters include flood discharge, riprap materials, impoundment side slopes, and an added safety factor. Two decommissioned tailings impoundments are used as case studies for the evaluation. These are the Grand Junction, Colorado, impoundment located adjacent to the Colorado River and the Slickrock, Colorado, impoundment located adjacent to the Dolores River. The evaluation considers only the cost of riprap protection against flood erosion. The study results show that embankment side slope and rock specific gravity can have optimum values or ranges at a specific site. For both case study sites the optimum side slope is about 5H:1V. Of the rock sources considered at Grand Junction, the optimum specific gravity would be about 2.50; however, an optimum rock specific gravity for the Slickrock site could not be determined. Other results indicate that the arbitrary safety factor usually added in riprap design can lead to large increases in protection costs. 22 references, 19 figures, 15 tables

  17. Protection of uranium tailings impoundments against overland erosion

    International Nuclear Information System (INIS)

    Walters, W.H.; Skaggs, R.L.

    1986-01-01

    This study investigates the problems involved in designing protection methods to prevent erosion of a uranium tailings impoundment cover from rainfall and runoff (overland flow) processes. The study addresses the side slopes and top surface as separate elements. The side slopes are more subject to gully erosion and require absolute protection such as that provided by rock riprap. The flatter top surface needs much less protection (vegetation/rock combinations) but some estimate of erosion rates are needed to compare alternatives. A literature review indicated that, currently, procedures are not available for the design of rock riprap to prevent gully erosion. Therefore, rock protection on the side slope will have to be based upon engineering judgment determined by the particular site conditions. The Manning-kinetic equations (velocity and depth of runoff) were investigated as a possible aid to the design of gully erosion protection. Guidelines are suggested for the use of rock riprap to prevent gully erosion. Three mathematical models were used to compute erosion rates for the top surface of a hypothetical tailings impoundment. The results recommend that one or possibly both of the regression models could be used to evaluate preliminary protection designs for the top surface. A physical process simulation model should be used for the final design. 30 refs., 13 figs., 16 tabs

  18. 36 CFR 262.11 - Impounding of dogs.

    Science.gov (United States)

    2010-07-01

    ... 36 Parks, Forests, and Public Property 2 2010-07-01 2010-07-01 false Impounding of dogs. 262.11... ENFORCEMENT SUPPORT ACTIVITIES Impoundments and Removals § 262.11 Impounding of dogs. Any dog found running at large in a part of the National Forest System, which has been closed to dogs running at large, may be...

  19. 30 CFR 817.49 - Impoundments.

    Science.gov (United States)

    2010-07-01

    ... runoff from the design precipitation event when it is demonstrated by the operator and certified by a... constructed to safely pass the applicable design precipitation event specified in paragraph (a)(9)(ii) of this... this section, the required design precipitation event for an impoundment meeting the spillway...

  20. UAV Remote Sensing Surveillance of a Mine Tailings Impoundment in Sub-Arctic Conditions

    Directory of Open Access Journals (Sweden)

    Anssi Rauhala

    2017-12-01

    Full Text Available Mining typically involves extensive areas where environmental monitoring is spatially sporadic. New remote sensing techniques and platforms such as Structure from Motion (SfM and unmanned aerial vehicles (UAVs may offer one solution for more comprehensive and spatially continuous measurements. We conducted UAV campaigns in three consecutive summers (2015–2017 at a sub-Arctic mining site where production was temporarily suspended. The aim was to monitor a 0.5 km2 tailings impoundment and measure potential subsidence of tailings. SfM photogrammetry was used to produce yearly topographical models of the tailings surface, which allowed the amount of surface displacement between years to be tracked. Ground checkpoints surveyed in stable areas of the impoundment were utilized in assessing the vertical accuracy of the models. Observed surface displacements were linked to a combination of erosion, tailings settlement, and possible compaction of the peat layer underlying the tailings. The accuracy obtained indicated that UAV-assisted monitoring of tailings impoundments is sufficiently accurate for supporting impoundment management operations and for tracking surface displacements in the decimeter range.

  1. Distribution and migration of pesticide residues in mosquito control impoundments St. Lucie County, Florida, USA

    Science.gov (United States)

    Parkinson, R. W.; Wang, T. C.; White, J. R.; David, J. R.; Hoffman, M. E.

    1993-09-01

    This project was designed to: (1) document the distribution and migration of organochlorine pesticide residues within marsh substrates of 18 St. Lucie County mosquito control impoundments located along the Indian River Lagoon estuary, and (2) evaluate the impact of water management techniques on residue mobility. Our results indicate that detectible concentrations of organochlorine compounds, applied between the late 1940s and early 1950s, are present in 16 of the 18 St. Lucie County mosquito control impoundments. These compounds are primarily restricted to the surficial, organic-rich wetland sediment, which, based upon geotechnical analysis, was exposed to the atmosphere at a time when the impoundments were subjected to pesticide treatment. Contaminated sediments are present below the surficial, organic-rich layer, suggesting that some vertical migration of pesticides has occurred. It is unlikely that leaching associated with the downward percolation of impounded water was responsible for this migration as pesticide residues were never detected within the in situ pore waters. An alternative explanation is that biological processes (e.g., rooting, burrowing) facilitated the downward flux of organochlorine compounds into sediment horizons not subjected to direct treatment. Eighty-eight surface water samples obtained from two impoundments subjected to contrasting water management techniques were analyzed for pesticide content. None of the surficial water samples collected in association with these impoundments contained detectible concentrations of organochlorine compounds. These samples were unfiltered and contained as much as 25 mg/1 of particulate organic matter. This suggests that the currently preferred management technique (RIM), which is designed to maintain water quality, limit mosquito production, and provide for ecological continuity, does not hydraulically mobilize pesticide residues into the Indian River Lagoon estuary.

  2. The Role of Small Impoundments on Flow Alteration Within River Networks

    Science.gov (United States)

    Brogan, C. O.; Keys, T.; Scott, D.; Burgholzer, R.; Kleiner, J.

    2017-12-01

    Numerous water quality and quantity models have been established to illustrate the ecologic and hydrologic effects of large reservoirs. Smaller, unregulated ponds are often assumed to have a negligible impact on watershed flow regimes even though they overwhelmingly outnumber larger waterbodies. Individually, these small impoundments impart merely a fraction of the flow alteration larger reservoirs do; however, a network of ponds may act cumulatively to alter the flow regime. Many models have attempted to study smaller impoundments but rely on selectively available rating curves or bathymetry surveys. This study created a generalized process to model impoundments of varying size across a 58 square mile watershed exclusively using satellite imagery and publicly available information as inputs. With information drawn from public Army Corps of Engineers databases and LiDAR surveys, it was found that impoundment surface and drainage area served as useful explanatory variables, capable of predicting both pond bathymetry and outlet structure area across the 37 waterbodies modeled within the study area. Working within a flow routing model with inputs from the Chesapeake Bay HSPF model and verified with USGS gauge data, flow simulations were conducted with increasing number of impoundments to quantify how small ponds affect the overall flow regime. As the total impounded volume increased, simulations showed a notable reduction in both low and peak flows. Medium-sized floods increased as the network of ponds and reservoirs stabilized the catchment's streamflow. The results of this study illustrate the importance of including ponded waters into river corridor models to improve downstream management of both water quantity and quality.

  3. Evaluation of Co and Cr mobility in soil profiles collected in a scrapyard of impounded vehicles

    Energy Technology Data Exchange (ETDEWEB)

    Lange, Camila N.; Figueiredo, Ana Maria G., E-mail: clange@usp.br, E-mail: anamaria@ipen.br [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil); Enzweiler, Jacinta, E-mail: jacinta@ige.unicamp.br [Universidade Estadual de Campinas (UNICAMP), Campinas, SP (Brazil). Instituto de Geociencias

    2015-07-01

    The number of motor vehicles in urban environments has increased dramatically in the past years. As a result, so has the number of impounded and end-of-life vehicles. Car wastes can have a very high metal content, which can cause important environmental impacts to the soil where these vehicles are kept. Most Brazilian vehicle impound scrapyards are currently operating at their maximum capacity and soils may have become contaminated by past or current vehicle handling practices. Most of these areas do not present an impermeable surface. The level of soil contamination with heavy metals depends on the type of soil, climate and management practices. Metals, such as Co and Cr, that are present in many auto-parts, may be considered potentially toxic elements in these areas. The aim of this study was to evaluate Co and Cr levels and behavior in soil profiles located in a scrapyard of impounded vehicles of Ribeirao Pires-SP city. For this purpose, samples from distinct horizons of three soil profiles were collected. Element concentrations were determined by Instrumental Neutron Activation Analysis (INAA). Soil parameters such as pH, organic matter content and clay, silt and sand percentage were also determined. The obtained data were statistically analyzed in order to establish correlations between elemental concentrations and the impounded vehicles scrapyard soil. Soil acidity showed to be the most remarkable property for Cr and Co mobility through soil profile. (author)

  4. Evaluation of Co and Cr mobility in soil profiles collected in a scrapyard of impounded vehicles

    International Nuclear Information System (INIS)

    Lange, Camila N.; Figueiredo, Ana Maria G.; Enzweiler, Jacinta

    2015-01-01

    The number of motor vehicles in urban environments has increased dramatically in the past years. As a result, so has the number of impounded and end-of-life vehicles. Car wastes can have a very high metal content, which can cause important environmental impacts to the soil where these vehicles are kept. Most Brazilian vehicle impound scrapyards are currently operating at their maximum capacity and soils may have become contaminated by past or current vehicle handling practices. Most of these areas do not present an impermeable surface. The level of soil contamination with heavy metals depends on the type of soil, climate and management practices. Metals, such as Co and Cr, that are present in many auto-parts, may be considered potentially toxic elements in these areas. The aim of this study was to evaluate Co and Cr levels and behavior in soil profiles located in a scrapyard of impounded vehicles of Ribeirao Pires-SP city. For this purpose, samples from distinct horizons of three soil profiles were collected. Element concentrations were determined by Instrumental Neutron Activation Analysis (INAA). Soil parameters such as pH, organic matter content and clay, silt and sand percentage were also determined. The obtained data were statistically analyzed in order to establish correlations between elemental concentrations and the impounded vehicles scrapyard soil. Soil acidity showed to be the most remarkable property for Cr and Co mobility through soil profile. (author)

  5. Application of carbon isotopes to detect seepage out of coalbed natural gas produced water impoundments

    International Nuclear Information System (INIS)

    Sharma, Shikha; Baggett, Joshua K.

    2011-01-01

    Highlights: → Coalbed natural gas extraction results in large amount of produced water. → Risk of deterioration of ambient water quality. → Carbon isotope natural tracer for detecting seepage from produced water impoundments. - Abstract: Coalbed natural gas (CBNG) production from coal bed aquifers requires large volumes of produced water to be pumped from the subsurface. The produced water ranges from high quality that meets state and federal drinking water standards to low quality due to increased salinity and/or sodicity. The Powder River Basin of northeastern Wyoming is a major coalbed natural gas producing region, where water quality generally decreases moving from the southeastern portion of the basin towards the center. Most produced water in Wyoming is disposed into impoundments and other surface drainages, where it may infiltrate into shallow groundwater. Groundwater degradation caused by infiltration of CBNG produced water holding impoundments into arid, soluble salt-rich soils is an issue of immense importance because groundwater is a major source for stock water, irrigation, and drinking water for many small communities in these areas. This study examines the potential of using stable C isotope signatures of dissolved inorganic C (δ 13 C DIC ) to track the fate of CBNG produced water after it is discharged into the impoundments. Other geochemical proxies like the major cations and major anions were used in conjunction with field water quality measurements to understand the geochemical differences between CBNG produced waters and ambient waters in the study area. Samples were collected from the CBNG discharge outfalls, produced water holding impoundments, and monitoring wells from different parts of the Powder River Basin and analyzed for δ 13 C DIC . The CBNG produced waters from outfalls and impoundments have positive δ 13 C DIC values that fall within the range of +12 per mille to +22 per mille, distinct from the ambient regional surface and

  6. Surface engineering for enhanced performance against wear

    CERN Document Server

    2013-01-01

    Surface Engineering constitutes a variety of processes and sub processes. Each chapter of this work covers specific processes by experts working in the area. Included for each topic are tribological performances for each process as well as results of recent research. The reader also will benefit from in-depth studies of diffusion coatings, nanocomposite films for wear resistance, surfaces for biotribological applications, thin-film wear, tribology of thermal sprayed coatings, hardfacing, plating for tribology and high energy beam surface modifications. Material scientists as well as engineers working with surface engineering for tribology will be particularly interested in this work.

  7. Responsiveness summary for the engineering evaluation/cost analysis for the proposed management of contaminated water impounded at the Weldon Spring Chemical Plant Area

    International Nuclear Information System (INIS)

    Maxey, M.L.; MacDonell, M.M.; Peterson, J.M.

    1991-01-01

    The US Department of Energy (DOE) issued the Engineering Evaluation/Cost Analysis for the Proposed Management of Contaminated Water Impounded at the Weldon Spring Chemical Plant Area in July 1990. The engineering evaluation/cost analysis (EE/CA) examines various alternatives for the proposed action to manage contaminated surface water impounded at the chemical plant area. The primary objective is to minimize potential migration of contaminants from surface impoundments to the local environment. The EE/CA addresses water currently impounded in four waste raffinate pits and two small ponds and water that will be impounded in the future as a result of upcoming response actions. Radioactive and chemical contaminants are migrating from the currently impounded water to underlying on-site groundwater via seepage and to off-site surface water via runoff. The treatment process and facilities that will be provided for management of currently impounded water can subsequently be used to manage other contaminated water in the future. Based on the evaluation of various alternatives in the EE/CA, DOE determined that the best approach for managing surface water impounded at the chemical plant area would be to remove contaminants from the water and release the treatment water to the Missouri River via a natural drainage channel. To establish requirements for releasing this treated water, DOE applied for a modification to its existing discharge permit from the Missouri Department of Natural Resources (DNR) under the National Pollutant Discharge Elimination System (NPDES) program. The EE/CA provided a major source of technical input to the application for modifying the permit. This responsiveness summary has been prepared to address the major issues identified in oral and written comments on the proposed action. 1 tab

  8. Permanent isolation surface barrier: Functional performance

    International Nuclear Information System (INIS)

    Wing, N.R.

    1993-10-01

    This document presents the functional performance parameters for permanent isolation surface barriers. Permanent isolation surface barriers have been proposed for use at the Hanford Site (and elsewhere) to isolate and dispose of certain types of waste in place. Much of the waste that would be disposed of using in-place isolation techniques is located in subsurface structures, such as solid waste burial grounds, tanks, vaults, and cribs. Unless protected in some way, the wastes could be transported to the accessible environment via transport pathways, such as water infiltration, biointrusion, wind and water erosion, human interference, and/or gaseous release

  9. Moist Soil Management of Wetland Impoundments for Plants and Invertebrates

    Data.gov (United States)

    Department of the Interior — In year’s past an impoundment was drained (a drawdown) when floating-leaved plants covered more than 50% of the water area. Drawdowns encourage beneficial moist soil...

  10. 32 CFR 634.51 - Procedures for impoundment.

    Science.gov (United States)

    2010-07-01

    ... complete DD Form 2506 (Vehicle Impoundment Report) as a record of the actions taken. (i) An inventory... not be inventoried. Such articles should be opened only if necessary to identify the owner of the...

  11. An Object-Based Machine Learning Classification Procedure for Mapping Impoundments in Brazil's Amazon-Cerrado Agricultural Frontier

    Science.gov (United States)

    Solvik, K.; Macedo, M.; Graesser, J.; Lathuilliere, M. J.

    2017-12-01

    Large-scale agriculture and cattle ranching in Brazil has driving the creation of tens of thousands of small stream impoundments to provide water for crops and livestock. These impoundments are a source of methane emissions and have significant impacts on stream temperature, connectivity, and water use over a large region. Due to their large numbers and small size, they are difficult to map using conventional methods. Here, we present a two-stage object-based supervised classification methodology for identifying man-made impoundments in Brazil. First, in Google Earth Engine pixels are classified as water or non-water using satellite data and HydroSHEDS products as predictors. Second, using Python's scikit-learn and scikit-image modules the water objects are classified as man-made or natural based on a variety of shape and spectral properties. Both classifications are performed by a random forest classifier. Training data is acquired by visually identifying impoundments and natural water bodies using high resolution satellite imagery from Google Earth.This methodology was applied to the state of Mato Grosso using a cloud-free mosaic of Sentinel 1 (10m resolution) radar and Sentinel 2 (10-20m) multispectral data acquired during the 2016 dry season. Independent test accuracy was estimated at 95% for the first stage and 93% for the second. We identified 54,294 man-made impoundments in Mato Grosso in 2016. The methodology is generalizable to other high resolution satellite data and has been tested on Landsat 5 and 8 imagery. Applying the same approach to Landsat 8 images (30 m), we identified 35,707 impoundments in the 2015 dry season. The difference in number is likely because the coarser-scale imagery fails to detect small (work will apply this approach to satellite time series for the entire Amazon-Cerrado frontier, allowing us to track changes in the number, size, and distribution of man-made impoundments. Automated impoundment mapping over large areas may help with

  12. Characterization and assessment of potential environmental risk of tailings stored in seven impoundments in the Aries river basin, Western Romania

    Science.gov (United States)

    2013-01-01

    Background The objective of this study was to examine the potential environmental risk of tailings resulted after precious and base metal ores processing, stored in seven impoundments located in the Aries river basin, Romania. The tailings were characterized by mineralogical and elemental composition, contamination indices, acid rock drainage generation potential and water leachability of hazardous/priority hazardous metals and ions. Multivariate statistical methods were used for data interpretation. Results Tailings were found to be highly contaminated with several hazardous/priority hazardous metals (As, Cu, Cd, Pb), and pose potential contamination risk for soil, sediments, surface and groundwater. Two out of the seven studied impoundments does not satisfy the criteria required for inert wastes, shows acid rock drainage potential and thus can contaminate the surface and groundwater. Three impoundments were found to be highly contaminated with As, Pb and Cd, two with As and other two with Cu. The tailings impoundments were grouped based on the enrichment factor, geoaccumulation index, contamination factor and contamination degree of 7 hazardous/priority hazardous metals (As, Cd, Cr, Cu, Ni, Pb, Zn) considered typical for the studied tailings. Principal component analysis showed that 47% of the elemental variability was attributable to alkaline silicate rocks, 31% to acidic S-containing minerals, 12% to carbonate minerals and 5% to biogenic elements. Leachability of metals and ions was ascribed in proportion of 61% to silicates, 11% to acidic minerals and 6% to the organic matter. A variability of 18% was attributed to leachability of biogenic elements (Na, K, Cl-, NO3-) with no potential environmental risk. Pattern recognition by agglomerative hierarchical clustering emphasized the grouping of impoundments in agreement with their contamination degree and acid rock drainage generation potential. Conclusions Tailings stored in the studied impoundments were found to

  13. Characterization and assessment of potential environmental risk of tailings stored in seven impoundments in the Aries river basin, Western Romania

    Directory of Open Access Journals (Sweden)

    Levei Erika

    2013-01-01

    Full Text Available Abstract Background The objective of this study was to examine the potential environmental risk of tailings resulted after precious and base metal ores processing, stored in seven impoundments located in the Aries river basin, Romania. The tailings were characterized by mineralogical and elemental composition, contamination indices, acid rock drainage generation potential and water leachability of hazardous/priority hazardous metals and ions. Multivariate statistical methods were used for data interpretation. Results Tailings were found to be highly contaminated with several hazardous/priority hazardous metals (As, Cu, Cd, Pb, and pose potential contamination risk for soil, sediments, surface and groundwater. Two out of the seven studied impoundments does not satisfy the criteria required for inert wastes, shows acid rock drainage potential and thus can contaminate the surface and groundwater. Three impoundments were found to be highly contaminated with As, Pb and Cd, two with As and other two with Cu. The tailings impoundments were grouped based on the enrichment factor, geoaccumulation index, contamination factor and contamination degree of 7 hazardous/priority hazardous metals (As, Cd, Cr, Cu, Ni, Pb, Zn considered typical for the studied tailings. Principal component analysis showed that 47% of the elemental variability was attributable to alkaline silicate rocks, 31% to acidic S-containing minerals, 12% to carbonate minerals and 5% to biogenic elements. Leachability of metals and ions was ascribed in proportion of 61% to silicates, 11% to acidic minerals and 6% to the organic matter. A variability of 18% was attributed to leachability of biogenic elements (Na, K, Cl-, NO3- with no potential environmental risk. Pattern recognition by agglomerative hierarchical clustering emphasized the grouping of impoundments in agreement with their contamination degree and acid rock drainage generation potential. Conclusions Tailings stored in the studied

  14. Simulated effects of impoundment of lake seminole on ground-water flow in the upper Floridan Aquifer in southwestern Georgia and adjacent parts of Alabama and Florida

    Science.gov (United States)

    Jones, L. Elliott; Torak, Lynn J.

    2004-01-01

    Hydrologic implications of the impoundment of Lake Seminole in southwest Georgia and its effect on components of the surface- and ground-water flow systems of the lower Apalachicola?Chattahoochee?Flint (ACF) River Basin were investigated using a ground-water model. Comparison of simulation results of postimpoundment drought conditions (October 1986) with results of hypothetical preimpoundment conditions (a similar drought prior to 1955) provides a qualitative measure of the changes in hydraulic head and ground-water flow to and from streams and Lake Seminole, and across State lines caused by the impoundment. Based on the simulation results, the impoundment of Lake Seminole changed ground-water flow directions within about 20?30 miles of the lake, reducing the amount of ground water flowing from Florida to Georgia southeast of the lake. Ground-water storage was increased by the impoundment, as indicated by a simulated increase of as much as 26 feet in the water level in the Upper Floridan aquifer. The impoundment of Lake Seminole caused changes to simulated components of the ground-water budget, including reduced discharge from the Upper Floridan aquifer to streams (315 million gallons per day); reduced recharge from or increased discharge to regional ground-water flow at external model boundaries (totaling 183 million gallons per day); and reduced recharge from or increased discharge to the undifferentiated overburden (totaling 129 million gallons per day).

  15. Effect of weir impoundments on methane dynamics in a river

    Czech Academy of Sciences Publication Activity Database

    Bednařík, A.; Blaser, M.; Matoušů, Anna; Hekera, P.; Rulík, M.

    2017-01-01

    Roč. 584, April (2017), s. 164-174 ISSN 0048-9697 R&D Projects: GA ČR(CZ) GA13-00243S Institutional support: RVO:60077344 Keywords : methane production * methane emission * methane ebullition * river impoundment * river sediment Subject RIV: DA - Hydrology ; Limnology OBOR OECD: Marine biology, freshwater biology, limnology Impact factor: 4.900, year: 2016

  16. Acidity of Lakes and Impoundments in North-Central Minnesota

    Science.gov (United States)

    Elon S. Verry

    1981-01-01

    Measurements of lake and impoundment pH for several years, intensive sampling within years, and pH-calcium plots verify normal pH levels and do not show evidence of changes due to acid precipitation. These data in comparison with general lake data narrow the northern Lake States area in which rain or snow may cause lake acidification.

  17. SURFACE PROPERTIES AND CATALYTIC PERFORMANCE OF Pt ...

    African Journals Online (AJOL)

    various temperatures of precipitates obtained from aqueous solutions in the ... The oxidation reactivity of VOCs is in the following order: alcohols > aldheydes > aromatics ... Specific surface areas (SSA) were calculated by the BET method from ...

  18. 40 CFR 264.1085 - Standards: Surface impoundments.

    Science.gov (United States)

    2010-07-01

    ... materials of construction and designing the cover and closure devices shall include: Organic vapor... closure device in the closed position, as applicable. (B) To remove accumulated sludge or other residues... construction and designing the cover and closure devices shall include: Organic vapor permeability; the effects...

  19. 40 CFR 265.1086 - Standards: Surface impoundments.

    Science.gov (United States)

    2010-07-01

    ... materials of construction and designing the cover and closure devices shall include: Organic vapor... closure device in the closed position, as applicable. (B) To remove accumulated sludge or other residues... construction and designing the cover and closure devices shall include: Organic vapor permeability; the effects...

  20. Interfacial stability of soil covers on lined surface impoundments

    International Nuclear Information System (INIS)

    Mitchell, D.H.; Gates, T.E.

    1986-04-01

    The factors affecting the interfacial stability of soil covers on geomembranes were examined to determine the maximum stable slopes for soil cover/geomembrane systems. Several instances of instability of soil covers on geomembranes have occurred at tailings ponds, leaving exposed geomembranes with the potential for physical ddamage and possibly chemical and ultraviolet degradation. From an operator's viewpoint, it is desirable to maximize the slope of lined facilities in order to maximize the volume-to-area ratio; however, the likelihood for instability also increases with increasing slope. Frictional data obtained from direct shear tests are compared with stability data obtained using a nine-square-meter (m 2 ) engineering-scale test stand to verify that direct shear test data are valid in slope design calculations. Interfacial frictional data from direct shear tests using high-density polyethylene and a poorly graded sand cover agree within several degrees with the engineering-scale tests. Additional tests with other soils and geomembranes are planned. The instability of soil covers is not always an interfacial problem; soil erosion and limited drainage capacity are additional factors that must be considered in the design of covered slopes. 7 refs., 5 figs., 2 tabs

  1. Engineering evaluation/cost analysis for the proposed management of contaminated water impounded at the Weldon Spring chemical plant area

    International Nuclear Information System (INIS)

    MacDonell, M.M.; Maxey, M.L.; Peterson, J.M.; Joya, I.E.

    1990-07-01

    This engineering evaluation/cost analysis (EE/CA) report has been prepared to support the proposed removal action for managing contaminated surface waters impounded at the chemical plant area of the Weldon Spring site, located near Weldon Spring, Missouri. The US Department of Energy is responsible for cleanup activities at the site under its Surplus Facilities Management Program (SFMP). The major goals of SFMP are to eliminate potential hazards to human health and the environment that are associated with contamination at SFMP sites and to make surplus real property available for other uses, to the extent possible. The objectives of this EE/CA report are to identify the cleanup as a removal action, document the selection of a response that will mitigate the potential release of radioactive or chemical contaminants from the impounded waters into the nearby environment, and address environmental impacts associated with the proposed action. 41 refs., 8 figs., 8 tabs

  2. Evaluation of Major Dike-Impounded Ground-Water Reservoirs, Island of Oahu

    Science.gov (United States)

    Takasaki, Kiyoshi J.; Mink, John Francis

    1985-01-01

    Ground-water reservoirs impounded by volcanic dikes receive a substantial part of the total recharge to ground water on the island of Oahu because they generally underlie the rainiest areas. These reservoirs accumulate the infiltration from rainfall, store it temporarily, and steadily leak it to abutting basal reservoirs or to streams cutting into them. The dike reservoirs have high hydraulic heads and are mostly isolated from saline water. The most important and productive of the dike-impounded reservoirs are in an area of about 135 square miles in the main fissure zone of the Koolau volcano where the top of the dike-impounded water reaches an altitude of at least 1,000 feet. Water is impounded and stored both above and below sea level. The water stored above sea level in the 135 square mile area has been roughly estimated at 560 billion gallons. In comparison, the water stored above sea level in reservoirs underlying a dike-intruded area of about 53 square miles in the Waianae Range has been roughly estimated at 100 billion gallons. Storage below sea level is indeterminable, owing to uncertainties about the ability of the rock to store water as dike density increases and porosity decreases. Tunnels, by breaching dike controls, have reduced the water stored above sea level by at least 50 billion gallons in the Koolau Range and by 5 1/2 billion gallons in the Waianae Range, only a small part of the total water stored. Total leakage from storage in the Koolau Range has been estimated at about 280 Mgal/d (million gallons per day). This estimated leakage from the dike-impounded reservoirs makes up a significant part of the ground-water yield of the Koolau Range, which has been estimated to range from 450 to 580 Mgal/d. The largest unused surface leakage is in the Kaneohe, Kahana, and Punaluu areas, and the largest unused underflow occurs in the Waialee, Hauula-Laie, Punaluu, and Kahana areas. The unused underflow leakage is small in areas near and east of Waialae, but

  3. Assessment of sediments in the riverine impoundments of national wildlife refuges in the Souris River Basin, North Dakota

    Science.gov (United States)

    Tangen, Brian A.; Laubhan, Murray K.; Gleason, Robert A.

    2014-01-01

    Accelerated sedimentation of reservoirs and riverine impoundments is a major concern throughout the United States. Sediments not only fill impoundments and reduce their effective life span, but they can reduce water quality by increasing turbidity and introducing harmful chemical constituents such as heavy metals, toxic elements, and nutrients. U.S. Fish and Wildlife Service national wildlife refuges in the north-central part of the United States have documented high amounts of sediment accretion in some wetlands that could negatively affect important aquatic habitats for migratory birds and other wetland-dependent wildlife. Therefore, information pertaining to sediment accumulation in refuge impoundments potentially is important to guide conservation planning, including future management actions of individual impoundments. Lands comprising Des Lacs, Upper Souris, and J. Clark Salyer National Wildlife Refuges, collectively known as the Souris River Basin refuges, encompass reaches of the Des Lacs and Souris Rivers of northwestern North Dakota. The riverine impoundments of the Souris River Basin refuges are vulnerable to sedimentation because of the construction of in-stream dams that interrupt and slow river flows and because of post-European settlement land-use changes that have increased the potential for soil erosion and transport to rivers. Information regarding sediments does not exist for these refuges, and U.S. Fish and Wildlife Service personnel have expressed interest in assessing refuge impoundments to support refuge management decisions. Sediment cores and surface sediment samples were collected from impoundments within Des Lacs, Upper Souris, and J. Clark Salyer National Wildlife Refuges during 2004–05. Cores were used to estimate sediment accretion rates using radioisotope (cesium-137 [137Cs], lead-210 [210Pb]) dating techniques. Sediment cores and surface samples were analyzed for a suite of elements and agrichemicals, respectively. Examination of

  4. Stochastic Modelling of the Hydraulic Anisotropy of Ash Impoundment Sediment

    Science.gov (United States)

    Slávik, Ivan

    2017-12-01

    In the case reported here the impoundments of a 400 MW coal heated power plant with an annual production of about 1.5 million tons of fuel ash are of the cross-valley type, operated by the simple and cheap „upstream method”. The aim of the research was to determine overall and local values of the permeability in horizontal as well as in vertical direction and the anisotropy of the thin-layered sedimented ash. The coal ashes are hydraulically transported through pipelines in form of a slurry and periodically floated on the beach of the impoundment. The ashes are deposited in the form of a thin-layered sediment, with random alternation of layers with a coarser or finer granularity. The ash impoundment sediment is anthropogenic sediment with horizontally laminated texture. Therefore, the sediment is anisotropic from the viewpoint of water seepage. The knowledge of the permeability and the seepage anisotropy of the sediment is a basic requirement for the design of an appropriate dewatering system. The seepage anisotropy of the ash sediment has been checked by means of stochastic modelling, based on the correlation between the effective grain diameter and the coefficient of permeability of the ash: the effective grain diameter and the thickness of individual layers have been proposed to be random events.

  5. Investigation, assessment and remediation of the water pathway in the surroundings of the Culmitzsch A tailings impoundment

    International Nuclear Information System (INIS)

    Schulze, G.; Paul, M.; Priester, J.; Schoepfer, C.

    1998-01-01

    Several large tailings impoundments in Saxony and Thuringia are the result of the extensive uranium mining and milling in Eastern Germany after World War II. The Culmitzsch tailings pond in Eastern Thuringia was constructed within a former uranium open pit mine and is located within the Culmitzsch trench fault. The tailings impoundment includes two ponds (Culmitzsch A and B) which are separated by an internal dam with an impervious core. The Culmitzsch A pond covers an area of 158 ha, the maximum tailings thickness is 70 m. Between this pond (elevation of up to 340 m above sea-level) and the Lerchenbach creek (265.. 280 m above sea-level) a steep gradient exists. So the valley of the Lerchenbach is the general discharge area for the seepage of the pond which is a result of dewatering by gravity and consolidation. The seepage water migrates through the southern dam of the impoundment and through permeable layers which are in contact with the tailings. About 400 groundwater wells were installed within three aquifers in order to clarify the flow direction and the degree of contamination of the groundwater as well as to investigate the geohydraulic properties of the rocks in the surroundings of the pond. Based on the results of this investigation programme a three-dimensional hydrogeological model was built up which reflects the general relationships between the pond and its geological setting as well as the water balance of the whole system. Presently a catchment system exists which gathers all surface waters with significant uranium and salt concentrations. Moreover dewatering wells on the beach zone of the pond and catchment wells in the downstream area of the impoundment have been installed. Before being released to the receiving streams seepage and freewater are treated in a two-step water treatment plant in order to decrease their uranium, radium and arsenic contents. (orig.) [de

  6. Geochemical and mineralogical characterization of a neutral, low-sulfide/high-carbonate tailings impoundment, Markušovce, eastern Slovakia.

    Science.gov (United States)

    Hiller, Edgar; Petrák, Marián; Tóth, Roman; Lalinská-Voleková, Bronislava; Jurkovič, L'ubomír; Kučerová, Gabriela; Radková, Anežka; Sottník, Peter; Vozár, Jaroslav

    2013-11-01

    Tailings deposits generated from mining activities represent a potential risk for the aquatic environment through the release of potentially toxic metals and metalloids occurring in a variety of minerals present in the tailings. Physicochemical and mineralogical characteristics of tailings such as total concentrations of chemical elements, pH, ratio of acid-producing to acid-neutralizing minerals, and primary and secondary mineral phases are very important factors that control the actual release of potentially toxic metals and metalloids from the tailings to the environment. The aims of this study are the determination of geochemical and mineralogical characteristics of tailings deposited in voluminous impoundment situated near the village of Markušovce (eastern Slovakia) and identification of the processes controlling the mobility of selected toxic metals (Cu, Hg) and metalloids (As, Sb). The studied tailings have unique features in comparison with the other tailings investigated previously because of the specific mineral assemblage primarily consisting of barite, siderite, quartz, and minor sulfides. To meet the aims, samples of the tailings were collected from 3 boreholes and 15 excavated pits and subjected to bulk geochemical analyses (i.e., determination of chemical composition, pH, Eh, acid generation, and neutralization potentials) combined with detailed mineralogical characterization using optical microscopy, X-ray diffraction (XRD), electron microprobe analysis (EMPA), and micro-X-ray diffraction (μ-XRD). Additionally, the geochemical and mineralogical factors controlling the transfer of potentially toxic elements from tailings to waters were also determined using short-term batch test (European norm EN 12457), sampling of drainage waters and speciation-equilibrium calculations performed with PHREEQC. The tailings mineral assemblage consists of siderite, barite, quartz, and dolomite. Sulfide minerals constitute only a minor proportion of the tailings

  7. Characterization of transient groundwater flow through a high arch dam foundation during reservoir impounding

    Directory of Open Access Journals (Sweden)

    Yifeng Chen

    2016-08-01

    Full Text Available Even though a large number of large-scale arch dams with height larger than 200 m have been built in the world, the transient groundwater flow behaviors and the seepage control effects in the dam foundations under difficult geological conditions are rarely reported. This paper presents a case study on the transient groundwater flow behaviors in the rock foundation of Jinping I double-curvature arch dam, the world's highest dam of this type to date that has been completed. Taking into account the geological settings at the site, an inverse modeling technique utilizing the time series measurements of both hydraulic head and discharge was adopted to back-calculate the permeability of the foundation rocks, which effectively improves the uniqueness and reliability of the inverse modeling results. The transient seepage flow in the dam foundation during the reservoir impounding was then modeled with a parabolic variational inequality (PVI method. The distribution of pore water pressure, the amount of leakage, and the performance of the seepage control system in the dam foundation during the entire impounding process were finally illustrated with the numerical results.

  8. Recovery of the Three-Gorges Reservoir Impoundment Signal from ICESat altimetry and GRACE

    Science.gov (United States)

    Carabajal, C. C.; Boy, J.; Luthcke, S. B.; Harding, D. J.; Rowlands, D. D.; Lemoine, F. G.

    2006-12-01

    The Three Gorges Dam along the Yangtze River in China is one of the largest dams in the world. The water impoundment of the Three-Gorges Reservoir started in June 2003, and the volume of water will continuously increase up to about 40 km3 in 2009, over a length of about 600 km. Although water-level changes along the Yangtze River and the Three Gorges Reservoir are measured by in situ water gauges, access to these data can be quite difficult. Estimates of inland water height and extent can also be recovered from altimetry measurements performed from satellite platforms, such as those acquired by the Geoscience laser Altimetry System (GLAS) on board the Ice, Cloud and Land Elevation Satellite (ICESat). ICESat has produced a comprehensive, highly precise, set of along-track elevation measurements, every three months since its launch in 2003, which intersect the Yangtze River along its East-West extent. In addition, the water impoundment of major artificial reservoirs induces variations of global geodetic quantities, such as the gravity field and Earth rotation (Chao, 1995, Boy & Chao, 2002). Water level changes within the reservoir are compared to GRACE (Gravity Recovery And Climate Experiment) recovered water mass changes. In addition, we compare the GRACE observations of mass change in the Yangtze region to hydrological changes computed from different global soil-moisture and snow models, such as GLDAS (Global Land Data Assimilation System).

  9. Evaluation of behaviors of earth and rockfill dams during construction and initial impounding using instrumentation data and numerical modeling

    Directory of Open Access Journals (Sweden)

    Mohammad Rashidi

    2017-08-01

    Full Text Available In this study, the behavior of Gavoshan dam was evaluated during construction and the first impounding. A two-dimensional (2D numerical analysis was conducted based on a finite difference method on the largest cross-section of the dam using the results of instrument measurements and back analysis. These evaluations will be completed in the case that back analysis is carried out in order to control the degree of the accuracy and the level of confidence of the measured behavior since each of the measurements could be controlled by comparing it to the result obtained from the numerical model. Following that, by comparing the results of the numerical analysis with the measured values, it is indicated that there is a proper consistency between these two values. Moreover, it was observed that the dam performance was suitable regarding the induced pore water pressure, the pore water pressure ratio ru, settlement, induced stresses, arching degree, and hydraulic fracturing probability during the construction and initial impounding periods. The results demonstrated that the maximum settlement of the core was 238 cm at the end of construction. In the following 6 years after construction (initial impounding and exploitation period, the accumulative settlement of the dam was 270 cm. It is clear that 88% of the total settlement of the dam took place during dam construction. The reason is that the clay core was smashed in the wet side, i.e. the optimum moisture content. Whereas the average curving ratio was 0.64 during dam construction; at the end of the initial impounding, the maximum amount of curving ratio in the upstream was 0.81, and the minimum (critical amount in the downstream was 0.52. It was also concluded that this dam is safe in comparison with the behaviors of other similar dams in the world.

  10. Investigation of Floor Surface Finishes for Optimal Slip Resistance Performance

    Directory of Open Access Journals (Sweden)

    In-Ju Kim

    2018-03-01

    Full Text Available Background: Increasing the slip resistance of floor surfaces would be desirable, but there is a lack of evidence on whether traction properties are linearly correlated with the topographic features of the floor surfaces or what scales of surface roughness are required to effectively control the slipperiness of floors. Objective: This study expands on earlier findings on the effects of floor surface finishes against slip resistance performance and determines the operative ranges of floor surface roughness for optimal slip resistance controls under different risk levels of walking environments. Methods: Dynamic friction tests were conducted among three shoes and nine floor specimens under wet and oily environments and compared with a soapy environment. Results: The test results showed the significant effects of floor surface roughness on slip resistance performance against all the lubricated environments. Compared with the floor-type effect, the shoe-type effect on slip resistance performance was insignificant against the highly polluted environments. The study outcomes also indicated that the oily environment required rougher surface finishes than the wet and soapy ones in their lower boundary ranges of floor surface roughness. Conclusion: The results of this study with previous findings confirm that floor surface finishes require different levels of surface coarseness for different types of environmental conditions to effectively manage slippery walking environments. Collected data on operative ranges of floor surface roughness seem to be a valuable tool to develop practical design information and standards for floor surface finishes to efficiently prevent pedestrian fall incidents. Keywords: floor surface finishes, operational levels of floor surface roughness, slip resistance, wet, soapy and oily environments

  11. Geometrical and hydrogeological impact on the behaviour of deep-seated rock slides during reservoir impoundment

    Science.gov (United States)

    Lechner, Heidrun; Zangerl, Christian

    2015-04-01

    destabilisation is highly dependent on the ratio of the rock mass volume affected by buoyancy forces to the total volume of the rock slide. If a large rock mass volume ratio is submerged, huge buoyancy forces evolve and destabilize the slope significantly. Additionally, the influence of impoundment velocity on the rock slide behaviour and the impact of material properties of the rock masses are analysed. Reservoir water rapidly infiltrates into high-permeable rock slide masses evolving high pore pressures at the basal shear zone which leads to destabilisation. Conversely, reservoir water infiltrates slowly into low-permeable rock masses and the destabilizing effect of the pore water pressure might be compensated by a buttressing reservoir load over the low-permeable rock masses. Preliminary steady state calculations show that the factor of safety decreases constantly with increasing reservoir level until a certain threshold reservoir level and minimum factor of safety is reached. After exceeding this threshold level a further increase in reservoir impoundment leads to an increase of the factor of safety. This threshold reservoir level is reliant on the rock slide geometry and rock mass volume affected by buoyancy. Upcoming research is expected to provide new fundamentals for a comprehensive understanding of deformation and failure processes of deep-seated rock slides in order to perform reliable forecasts.

  12. Characterization plan for the waste holding basin (3513 impoundment)

    International Nuclear Information System (INIS)

    Stansfield, R.G.; Francis, C.W.

    1986-09-01

    US Department of Energy (DOE) facilities are required to comply fully with all federal and state regulations. In response to this requirement, the Oak Ridge National Laboratory (ORNL) has established the remedial action program, to provide comprehensive management of areas where past research, development, and waste management activities have been conducted and have resulted in residual contamination of facilities or the environment. One of the objectives of this program is to define the extent of contamination at these sites. The intent is to document the known environmental characteristics of the sites and identify the additional actions, such as sampling, analytical measurements, and modeling, necessary to confirm contamination and the possible migration of contaminants from the sites. One of these sites is the waste holding basin (3513 impoundment). The 3513 impoundment is an unlined waste settling basin constructed in 1944 for collection of ORNL wastewater before its discharge into White Oak Creek. Operation of the facility ceased in 1976 when a new process waste treatment plant came into operation. Considerable site-specific environmental information has been developed over the years relative to the type and quantities of radionuclides and hazardous substances contained in the pond water and sediment. The concentrations and patterns of distribution for many of the radionuclides in the aquatic biota as well as for the terrestrial plants growing on the berm of the impoundment have been determined by DOE ecological studies. Recently, some data were collected that evaluate the extent of contaminant movement to the groundwater. Results from these studies are summarized in this report. Also included in this report is an outline of additional tasks needed to obtain the necessary information to model the transport and dose pathways of hazardous substances from the site

  13. Run-of-River Impoundments Can Remain Unfilled While Transporting Gravel Bedload: Numerical Modeling Results

    Science.gov (United States)

    Pearson, A.; Pizzuto, J. E.

    2015-12-01

    Previous work at run-of-river (ROR) dams in northern Delaware has shown that bedload supplied to ROR impoundments can be transported over the dam when impoundments remain unfilled. Transport is facilitated by high levels of sand in the impoundment that lowers the critical shear stresses for particle entrainment, and an inversely sloping sediment ramp connecting the impoundment bed (where the water depth is typically equal to the dam height) with the top of the dam (Pearson and Pizzuto, in press). We demonstrate with one-dimensional bed material transport modeling that bed material can move through impoundments and that equilibrium transport (i.e., a balance between supply to and export from the impoundment, with a constant bed elevation) is possible even when the bed elevation is below the top of the dam. Based on our field work and previous HEC-RAS modeling, we assess bed material transport capacity at the base of the sediment ramp (and ignore detailed processes carrying sediment up and ramp and over the dam). The hydraulics at the base of the ramp are computed using a weir equation, providing estimates of water depth, velocity, and friction, based on the discharge and sediment grain size distribution of the impoundment. Bedload transport rates are computed using the Wilcock-Crowe equation, and changes in the impoundment's bed elevation are determined by sediment continuity. Our results indicate that impoundments pass the gravel supplied from upstream with deep pools when gravel supply rate is low, gravel grain sizes are relatively small, sand supply is high, and discharge is high. Conversely, impoundments will tend to fill their pools when gravel supply rate is high, gravel grain sizes are relatively large, sand supply is low, and discharge is low. The rate of bedload supplied to an impoundment is the primary control on how fast equilibrium transport is reached, with discharge having almost no influence on the timing of equilibrium.

  14. Groundwater monitoring at three Oak Ridge National Laboratory inactive waste impoundments: results after one year

    Energy Technology Data Exchange (ETDEWEB)

    Francis, C. W.; Stansfield, R. G.

    1986-10-01

    To determine if the migration of potential contaminants from three inactive waste impoundments at Oak Ridge National Laboratory poses a threat to groundwater quality, at least one upgradient groundwater monitoring well and threee downgradient monitoring wells were installed at each impoundment in early 1985. These three unlined impoundments, formerly used to collect and, in some instances, treat wastewater are: the 3513 impoundment; the Old Hydrofracture Facility (OHF) impoundment; and the Homogeneous Reactor Experimnt No. 2 impoundment. Groundwater samples were collected quarterly for one year. Analyses were conducted for the groundwater protection parameters promulgated by the Resource Conservation and Recovery Act. The groundwater samples were also analyzed for polychlorinated biphenyls, copper, nickel, zinc, /sup 90/Sr, /sup 137/Cs, and tritium. The contaminants found most often to affect groundwater quality at all three waste impoundments were radionuclides. For example, mean concentrations of gross beta and gross alpha activity exceeded drinking water limits at all three sites. The gross beta limit was exceeded at the 3513 and OHF impoundments by either /sup 90/Sr or tritium levels. At the 3513 impoundment, there was substantial evidence that the downgradient groundwater has been contaminated by chromium and lead and possibly by halogenated organic compounds. At the OHF impoundment, the mean level of tritium measured in the upgradient well (about 91,000 Bq/L as compared with 80,000 Bq/L in the downgradient wells) indicated that the groundwater quality has been affected by the radioactive wastes buried in the low-level radioactive waste burial ground solid waste storage area-5 upgradient of the impoundment. Testing for groundwater contamination, disclosed statistically significant contamination at all three sites.

  15. Groundwater monitoring at three Oak Ridge National Laboratory inactive waste impoundments: results after one year

    International Nuclear Information System (INIS)

    Francis, C.W.; Stansfield, R.G.

    1986-10-01

    To determine if the migration of potential contaminants from three inactive waste impoundments at Oak Ridge National Laboratory poses a threat to groundwater quality, at least one upgradient groundwater monitoring well and threee downgradient monitoring wells were installed at each impoundment in early 1985. These three unlined impoundments, formerly used to collect and, in some instances, treat wastewater are: the 3513 impoundment; the Old Hydrofracture Facility (OHF) impoundment; and the Homogeneous Reactor Experimnt No. 2 impoundment. Groundwater samples were collected quarterly for one year. Analyses were conducted for the groundwater protection parameters promulgated by the Resource Conservation and Recovery Act. The groundwater samples were also analyzed for polychlorinated biphenyls, copper, nickel, zinc, 90 Sr, 137 Cs, and tritium. The contaminants found most often to affect groundwater quality at all three waste impoundments were radionuclides. For example, mean concentrations of gross beta and gross alpha activity exceeded drinking water limits at all three sites. The gross beta limit was exceeded at the 3513 and OHF impoundments by either 90 Sr or tritium levels. At the 3513 impoundment, there was substantial evidence that the downgradient groundwater has been contaminated by chromium and lead and possibly by halogenated organic compounds. At the OHF impoundment, the mean level of tritium measured in the upgradient well (about 91,000 Bq/L as compared with 80,000 Bq/L in the downgradient wells) indicated that the groundwater quality has been affected by the radioactive wastes buried in the low-level radioactive waste burial ground solid waste storage area-5 upgradient of the impoundment. Testing for groundwater contamination, disclosed statistically significant contamination at all three sites

  16. Evaluation of surface sampling method performance for Bacillus Spores on clean and dirty outdoor surfaces.

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Mollye C.; Einfeld, Wayne; Boucher, Raymond M.; Brown, Gary Stephen; Tezak, Matthew Stephen

    2011-06-01

    Recovery of Bacillus atrophaeous spores from grime-treated and clean surfaces was measured in a controlled chamber study to assess sampling method performance. Outdoor surfaces investigated by wipe and vacuum sampling methods included stainless steel, glass, marble and concrete. Bacillus atrophaeous spores were used as a surrogate for Bacillus anthracis spores in this study designed to assess whether grime-coated surfaces significantly affected surface sampling method performance when compared to clean surfaces. A series of chamber tests were carried out in which known amounts of spores were allowed to gravitationally settle onto both clean and dirty surfaces. Reference coupons were co-located with test coupons in all chamber experiments to provide a quantitative measure of initial surface concentrations of spores on all surfaces, thereby allowing sampling recovery calculations. Results from these tests, carried out under both low and high humidity conditions, show that spore recovery from grime-coated surfaces is the same as or better than spore recovery from clean surfaces. Statistically significant differences between method performance for grime-coated and clean surfaces were observed in only about half of the chamber tests conducted.

  17. Reestablishing the Dominance of Biogeochemical Pathways for Reducing Downstream Nutrient Losses from Aged Impounded Features

    Science.gov (United States)

    Shukla, S.; Shukla, A.

    2017-12-01

    Water and phosphorus (P) dynamics and loss pathways at two stormwater impoundments (SIs) were analyzed using measured fluxes between 2008 and 2011. These SIs are a decade old. Analyses of water and P budgets along with the discernment of various P pools and characterization of the intermediary processes revealed that soil adsorption and plant uptake are secondary to volume reduction apropos of P treatment. At one site, extreme wet conditions in a year combined with soil P saturation resulted in it being a P source rather than a sink. The impoundment (SI-1) discharged 12% more P than incoming due to soil P desorption, a consequence of dilution of incoming stormwater with large water input from an extreme tropical rain event. The second impoundment (SI-2) was a consistent sink of P; 55% and 95% of the incoming total P was retained in the two years, mainly as a result of 49% and 84% volume retention, respectively. Analysis of plant available aluminum, iron, and phosphorus showed the surface soil to be P saturated and at risk of releasing P to a limit of environmental concern. These results when seen in light of more frequent extreme precipitation events under the changed climate scenario call for alternatives to revive the role of biogeochemical processes in P treatment because volume reduction may not always be the viable option, especially for wet conditions. Aboveground biomass harvesting and removal was evaluated to transform the SIs from a frequent P source to sink and maintain the long-term sink functions of the SIs. Use of harvested biomass as a source of nutrients (N and P) and carbon to agricultural soil can result in beneficial use of biomass and offset the cost of harvesting. Other avenues such as altering the hydrology of the SIs by compartmentalizing the system and increasing the storage were also explored for short-term benefits. Results provided a combination of hydraulic and biochemical options for achieving long-term water and nutrient retentions in

  18. 25 CFR 700.727 - Impoundment and disposal of unauthorized livestock.

    Science.gov (United States)

    2010-04-01

    ... 25 Indians 2 2010-04-01 2010-04-01 false Impoundment and disposal of unauthorized livestock. 700... RELOCATION PROCEDURES New Lands Grazing § 700.727 Impoundment and disposal of unauthorized livestock. Unauthorized livestock within any range unit of the New Lands which are not removed therefrom within the...

  19. 25 CFR 168.16 - Impoundment and disposal of unauthorized livestock.

    Science.gov (United States)

    2010-04-01

    ... 25 Indians 1 2010-04-01 2010-04-01 false Impoundment and disposal of unauthorized livestock. 168... REGULATIONS FOR THE HOPI PARTITIONED LANDS AREA § 168.16 Impoundment and disposal of unauthorized livestock. Unauthorized livestock within any range unit of the Hopi Partitioned Lands which are not removed therefrom...

  20. The Authority of the President to Impound Funds Appropriated by Congress.

    Science.gov (United States)

    Adams, James R.

    During fiscal year 1973, President Nixon ordered the impoundment of about 18 billion dollars in Federal funds for domestic programs. A large portion of that amount was used to slash federal funding for education programs. The entire impoundment controversy revolves around the doctrine of separation of powers. Insofar as the President has refused…

  1. Influence of Coanda surface curvature on performance of bladeless fan

    Science.gov (United States)

    Li, Guoqi; Hu, Yongjun; Jin, Yingzi; Setoguchi, Toshiaki; Kim, Heuy Dong

    2014-10-01

    The unique Coanda surface has a great influence on the performance of bladeless fan. However, there is few studies to explain the relationship between the performance and Coanda surface curvature at present. In order to gain a qualitative understanding of effect of the curvature on the performance of bladeless fan, numerical studies are performed in this paper. Firstly, three-dimensional numerical simulation is done by Fluent software. For the purpose to obtain detailed information of the flow field around the Coanda surface, two-dimensional numerical simulation is also conducted. Five types of Coanda surfaces with different curvature are designed, and the flow behaviour and the performance of them are analyzed and compared with those of the prototype. The analysis indicates that the curvature of Coanda surface is strongly related to blowing performance, It is found that there is an optimal curvature of Coanda surfaces among the studied models. Simulation result shows that there is a special low pressure region. With increasing curvature in Y direction, several low pressure regions gradually enlarged, then begin to merge slowly, and finally form a large area of low pressure. From the analyses of streamlines and velocity angle, it is found that the magnitude of the curvature affects the flow direction and reasonable curvature can induce fluid flow close to the wall. Thus, it leads to that the curvature of the streamlines is consistent with that of Coanda surface. Meanwhile, it also causes the fluid movement towards the most suitable direction. This study will provide useful information to performance improvements of bladeless fans.

  2. Surface Coating of Plastic Parts for Business Machines (Industrial Surface Coating): New Source Performance Standards (NSPS)

    Science.gov (United States)

    Learn more about the new source performance standards (NSPS) for surface coating of plastic parts for business machines by reading the rule summary and history and finding the code of federal regulations as well as related rules.

  3. Fabrication and wear protection performance of superhydrophobic surface on zinc

    Energy Technology Data Exchange (ETDEWEB)

    Wan Yong, E-mail: wanyong@qtech.edu.cn [School of Mechanical Engineering, Qingdao Technological University, 11 Fushun Road, Qingdao 266033 (China); Wang Zhongqian; Xu Zhen; Liu Changsong [School of Mechanical Engineering, Qingdao Technological University, 11 Fushun Road, Qingdao 266033 (China); Zhang Junyan [State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Lanzhou 730000 (China)

    2011-06-15

    A simple two-step process has been developed to render zinc surface superhydrophobic, resulting in low friction coefficient and long wear resistance performance. The ZnO film with uniform and packed nanorod structure was firstly created by immersing the zinc substrates into 4% N,N-dimethylformamide solution. The as-fabricated surface was then coated a layer of fluoroalkylsilane (FAS) by gas phase deposition. Scanning electron microscopy (SEM) and water contact angle (WCA) measurement have been performed to characterize the morphological feature, chemical composition and superhydrophobicity of the surface. The resulting surfaces have a WCA as high as 156 deg. and provide effective friction-reducing and wear protection for zinc substrate.

  4. Fabrication and wear protection performance of superhydrophobic surface on zinc

    International Nuclear Information System (INIS)

    Wan Yong; Wang Zhongqian; Xu Zhen; Liu Changsong; Zhang Junyan

    2011-01-01

    A simple two-step process has been developed to render zinc surface superhydrophobic, resulting in low friction coefficient and long wear resistance performance. The ZnO film with uniform and packed nanorod structure was firstly created by immersing the zinc substrates into 4% N,N-dimethylformamide solution. The as-fabricated surface was then coated a layer of fluoroalkylsilane (FAS) by gas phase deposition. Scanning electron microscopy (SEM) and water contact angle (WCA) measurement have been performed to characterize the morphological feature, chemical composition and superhydrophobicity of the surface. The resulting surfaces have a WCA as high as 156 deg. and provide effective friction-reducing and wear protection for zinc substrate.

  5. Performance analysis of PV panel under varying surface temperature

    Directory of Open Access Journals (Sweden)

    Kumar Tripathi Abhishek

    2018-01-01

    Full Text Available The surface temperature of PV panel has an adverse impact on its performance. The several electrical parameters of PV panel, such as open circuit voltage, short circuit current, power output and fill factor depends on the surface temperature of PV panel. In the present study, an experimental work was carried out to investigate the influence of PV panel surface temperature on its electrical parameters. The results obtained from this experimental study show a significant reduction in the performance of PV panel with an increase in panel surface temperature. A 5W PV panel experienced a 0.4% decrease in open circuit voltage for every 1°C increase in panel surface temperature. Similarly, there was 0.6% and 0.32% decrease in maximum power output and in fill factor, respectively, for every 1°C increase in panel surface temperature. On the other hand, the short circuit current increases with the increase in surface temperature at the rate of 0.09%/°C.

  6. Performance evaluation of sea surface simulation methods for target detection

    Science.gov (United States)

    Xia, Renjie; Wu, Xin; Yang, Chen; Han, Yiping; Zhang, Jianqi

    2017-11-01

    With the fast development of sea surface target detection by optoelectronic sensors, machine learning has been adopted to improve the detection performance. Many features can be learned from training images by machines automatically. However, field images of sea surface target are not sufficient as training data. 3D scene simulation is a promising method to address this problem. For ocean scene simulation, sea surface height field generation is the key point to achieve high fidelity. In this paper, two spectra-based height field generation methods are evaluated. Comparison between the linear superposition and linear filter method is made quantitatively with a statistical model. 3D ocean scene simulating results show the different features between the methods, which can give reference for synthesizing sea surface target images with different ocean conditions.

  7. Performance of solar still with a concave wick evaporation surface

    Energy Technology Data Exchange (ETDEWEB)

    Kabeel, A.E. [Mechanical Power Department, Faculty of Engineering, Tanta University (Egypt)

    2009-10-15

    Surfaces used for evaporation and condensation phenomenon play important roles in the performance of basin type solar still. In the present study, a concave wick surface was used for evaporation, whereas four sides of a pyramid shaped still were used for condensation. Use of jute wick increased the amount of absorbed solar radiation and enhanced the evaporation surface area. A concave shaped wick surface increases the evaporation area due to the capillary effect. Results show that average distillate productivity in day time was 4.1 l/m{sup 2} and a maximum instantaneous system efficiency of 45% and average daily efficiency of 30% were recorded. The maximum hourly yield was 0.5 l/h. m{sup 2} after solar noon. An estimated cost of 1l of distillate was 0.065 $ for the presented solar still. (author)

  8. Performance of solar still with a concave wick evaporation surface

    International Nuclear Information System (INIS)

    Kabeel, A.E.

    2009-01-01

    Surfaces used for evaporation and condensation phenomenon play important roles in the performance of basin type solar still. In the present study, a concave wick surface was used for evaporation, whereas four sides of a pyramid shaped still were used for condensation. Use of jute wick increased the amount of absorbed solar radiation and enhanced the evaporation surface area. A concave shaped wick surface increases the evaporation area due to the capillary effect. Results show that average distillate productivity in day time was 4.1 l/m 2 and a maximum instantaneous system efficiency of 45% and average daily efficiency of 30% were recorded. The maximum hourly yield was 0.5 l/h. m 2 after solar noon. An estimated cost of 1 l of distillate was 0.065 $ for the presented solar still.

  9. Installation and performance evaluation of an indigenous surface area analyser

    International Nuclear Information System (INIS)

    Pillai, S.N.; Solapurkar, M.N.; Venkatesan, V.; Prakash, A.; Khan, K.B.; Kumar, Arun; Prasad, R.S.

    2014-01-01

    An indigenously available surface area analyser was installed inside glove box and checked for its performance by analyzing uranium oxide and thorium oxide powders at RMD. The unit has been made ready for analysis of Plutonium oxide powders after incorporating several important features. (author)

  10. Design methodology to enhance high impedance surfaces performances

    Directory of Open Access Journals (Sweden)

    M. Grelier

    2014-04-01

    Full Text Available A methodology is introduced for designing wideband, compact and ultra-thin high impedance surfaces (HIS. A parametric study is carried out to examine the effect of the periodicity on the electromagnetic properties of an HIS. This approach allows designers to reach the best trade-off for HIS performances.

  11. Reestablishment of woody plants on mine spoils and management of mine water impoundments: an overview of Forest Service research on the northern High Plain

    Energy Technology Data Exchange (ETDEWEB)

    Bjugstad, A J

    1977-01-01

    The function of the research unit at Rapid city, S. Dakota, is to provide guidelines for the reestablisment of shrubs and trees on land characteristic of the High Plains, and for the mitigation of possible detrimental effects of surface mining on ground water and surface water. One possible problem posed by surface mining concerns the formation of land drainage patterns that could result in post-mining formations of large salt playas. Surface mining could affect shallow ground water aquifers up to /sup 1///sub 4/ mile from the mine site. Research is being conducted on the reclamation of mine spoils and on the rehabilitation and management of impounded mine water.

  12. A generic model of contaminant migration from uranium tailings impoundments

    International Nuclear Information System (INIS)

    Shepherd, T.A.; Brown, S.E.

    1982-01-01

    This paper presents an analytical hydrogeochemical model based upon acid consumption-neutralization front movement. The development of contaminant plumes is discussed and distinct zones within these plumes are identified and characterized. The most important process influencing the rate and extent of contaminant migration at acid-leach uranium tailings impoundments is the neutralization of seepage water by soils along ground water flow paths. The chemical characteristics of the ground water is determined in order to identify and characterize zones within migrating plumes of tailings-derived water. It is concluded that the characterization of specific zones is useful in the interpretation of existing conditions, in the evaluation of future migration, and in the determination of appropriate models for the specific situation

  13. Eutrophication levels of some South African impoundments. IV. Vaal Dam

    CSIR Research Space (South Africa)

    Steyn, DJ

    1976-04-01

    Full Text Available inere;iae(l the \\G P In? between 7,1- and I 1,2 mg/r? lbr t?verv nile pet? t?t?ttt v/v) added_Nitrogen and phosphorus wert? the important algal growth?limiting ntltrients in the impoundment. Plant nntt-ients adsorbed onto clay particles could ht... stream_source_info Steyn2_1976.pdf.txt stream_content_type text/plain stream_size 20870 Content-Encoding ISO-8859-1 stream_name Steyn2_1976.pdf.txt Content-Type text/plain; charset=ISO-8859-1 Za~3n Abstract The Vital...

  14. Sedimentation in Lake Onalaska, Navigation Pool 7, upper Mississippi River, since impoundment

    Science.gov (United States)

    Korschgen, C.E.; Jackson, G.A.; Muessig, L.F.; Southworth, D.C.

    1987-01-01

    Sediment accumulation was evaluated in Lake Onalaska, a 2800-ha backwater impoundment on the Upper Mississippi River. Computer programs were used to process fathometric charts and generate an extensive data set on water depth for the lake. Comparison of 1983 survey data with pre-impoundment (before 1937) data showed that Lake Onalaska had lost less than 10 percent of its original mean depth in the 46 years since impoundment. Previous estimates of sedimentation rates based on Cesium-137 sediment core analysis appear to have been too high. (DBO)

  15. Frequency selective surfaces based high performance microstrip antenna

    CERN Document Server

    Narayan, Shiv; Jha, Rakesh Mohan

    2016-01-01

    This book focuses on performance enhancement of printed antennas using frequency selective surfaces (FSS) technology. The growing demand of stealth technology in strategic areas requires high-performance low-RCS (radar cross section) antennas. Such requirements may be accomplished by incorporating FSS into the antenna structure either in its ground plane or as the superstrate, due to the filter characteristics of FSS structure. In view of this, a novel approach based on FSS technology is presented in this book to enhance the performance of printed antennas including out-of-band structural RCS reduction. In this endeavor, the EM design of microstrip patch antennas (MPA) loaded with FSS-based (i) high impedance surface (HIS) ground plane, and (ii) the superstrates are discussed in detail. The EM analysis of proposed FSS-based antenna structures have been carried out using transmission line analogy, in combination with the reciprocity theorem. Further, various types of novel FSS structures are considered in desi...

  16. Experimental determinations of the performances of heat transfer surfaces

    International Nuclear Information System (INIS)

    Pirovano, Alain; Viannay, Stephane; Mazeas, C.Y.

    1974-01-01

    With the help of flow schemes and of assumptions on the heat transfer, it is possible, in some cases, to predict the thermal and aerodynamical performances of a new heat transfer surface with moderate accuracy. These estimates, valid for an approximate classification of a new surface among known surfaces, are not accurate enough to be taken as a basis for the design of heat exchangers. In the present state of knowledge, the performances of a new heat transfer surface can only be determined accurately with experimental measurements. Bertin and Co have at their disposal two air test rigs especially designed for this purpose. The first one, more directly concerned with the measurements on tube bundles with fluid flow perpendicular to the generatrices of the tubes, is a semi-closed loop equipped with a high-efficiency ejector which amplifies the air flow rate supplied by an external source and thus allows high values of Reynolds number to be reached. The second one is adapted to other types of surfaces: tubes with external flow parallel to the generatrices, tubes with sophisticated cross section and with internal flow, compact surfaces with finned plates, etc. Both test rigs, the relevant equipment, the methods of data acquisition and of test results analysis are described in this paper. During the 5 past years, 60 configurations were tested. It was possible to compare some of the test results with the results of measurements performed later, on entire heat exchangers working with numbers of tubes, fluids, and temperature levels different from those prevailing during the tests on the small scale mock-up; the agreement is quite good [fr

  17. Environmental performance assessment of a company of aluminum surface treatment

    Directory of Open Access Journals (Sweden)

    Susan Catieri Ramalho

    2013-08-01

    Full Text Available The purpose of this article was to evaluate the environmental performance of a medium-sized company that provides services for surface treatment of aluminum. The treatment is known as anodizing. The research method was qualitative numerical modeling. The environmental performance of the company was organized into five constructs: atmosphere, wastewater, energy and natural resources, solid waste, and legislation and management. Nineteen indicators were chosen to explain the five constructs. Ten employees of the company prioritized the constructs and evaluated the situation of the indicators by means of a scale of assessment. By means of a mathematical model, the general performance of the environmental operation was calculated at 74.5% of the maximum possible. The indicators that most contributed to the performance not to reach 100% were consumption of electricity and water consumption. The construct of worse performance was natural and energy resources. These are the priorities for future environmental improvement actions that the company may promote.

  18. Effects of impoundment and regulation upon the stomach contents of fish at Cow Green, Upper Teesdale

    Energy Technology Data Exchange (ETDEWEB)

    Crisp, D.T.; Mann, R.H.K.; McCormack, J.C.

    1978-04-01

    The stomach contents of 1003 brown trout, 1551 bullheads and 800 minnows taken from the reservoir basin and below the dam, before and after impoundment of the river Tees, were examined. Their composition reflected observations by other workers on river and reservoir benthos, except for the increase in numbers of Hydra and Nais below the dam, and Mollusca, Hirudinea and oligochaetes in the reservoir. Trout below the dam ate more Ephemeroptera nymphs and Chironomidae larvae but fewer terrestrial casualties after river regulation, whereas bullheads ate more Mollusca but fewer Plecoptera nymphs. In both species Baetidae nymphs increased in numerical importance relative to Ecdyonuridae. Trout, but not bullheads, took zooplankton discharged from the reservoir. Before impoundment, trout within the reservoir basin ate chiefly benthic organisms and terrestrial casualties. Inundated terrestrial material, mainly earthworms, formed the bulk of their food for at least three years after impoundment, whilst from the second year onwards Chironomidae and, in some years, Gammarus became increasingly important. Zooplankton was taken by all sizes of reservoir trout. Bullheads within the reservoir basin ate chiefly river benthos before impoundment, with Ephemeroptera and Plecoptera nymphs predominant in older fish, and aquatic Diptera and Coleoptera also important in the fry. After impoundment, Chironomidae and Gammarus were the main items taken by older bullheads, and Chironomidae and micro-crustacea by the fry. Among all sizes of minnow, Chironomidae, micro-crustacea and detritus increased in numerical importance after impoundment.

  19. Performance characteristics of solar air heater with surface mounted obstacles

    International Nuclear Information System (INIS)

    Bekele, Adisu; Mishra, Manish; Dutta, Sushanta

    2014-01-01

    Highlights: • Solar air heater with delta shaped obstacles have been studied. • Obstacle angle of incidence strongly affects the thermo-hydraulic performance. • Thermal performance of obstacle mounted collectors is superior to smooth collectors. • Thermo-hydraulic performance of the present SAH is higher than those in previous studies. - Abstract: The performance of conventional solar air heaters (SAHs) can be improved by providing obstacles on the heated wall (i.e. on the absorber plate). Experiments have been performed to collect heat transfer and flow-friction data from an air heater duct with delta-shaped obstacles mounted on the absorber surface and having an aspect ratio 6:1 resembling the conditions close to the solar air heaters. This study encompassed for the range of Reynolds number (Re) from 2100 to 30,000, relative obstacle height (e/H) from 0.25 to 0.75, relative obstacle longitudinal pitch (P l /e) from 3/2 to 11/2, relative obstacle transverse pitch (P t /b) from 1 to 7/3 and the angle of incidence (α) varied from 30° to 90°. The thermo-hydraulic performance characteristics of SAH have been compared with the previous published works and the optimum range of the geometries have been explored for the better performance of such air-heaters compared to the other designs of solar air heaters

  20. The surface roughness effect on the performance of supersonic ejectors

    Science.gov (United States)

    Brezgin, D. V.; Aronson, K. E.; Mazzelli, F.; Milazzo, A.

    2017-07-01

    The paper presents the numerical simulation results of the surface roughness influence on gas-dynamic processes inside flow parts of a supersonic ejector. These simulations are performed using two commercial CFD solvers (Star- CCM+ and Fluent). The results are compared to each other and verified by a full-scale experiment in terms of global flow parameters (the entrainment ratio: the ratio between secondary to primary mass flow rate - ER hereafter) and local flow parameters distribution (the static pressure distribution along the mixing chamber and diffuser walls). A detailed comparative study of the employed methods and approaches in both CFD packages is carried out in order to estimate the roughness effect on the logarithmic law velocity distribution inside the boundary layer. Influence of the surface roughness is compared with the influence of the backpressure (static pressure at the ejector outlet). It has been found out that increasing either the ejector backpressure or the surface roughness height, the shock position displaces upstream. Moreover, the numerical simulation results of an ejector with rough walls in the both CFD solvers are well quantitatively agreed with each other in terms of the mean ER and well qualitatively agree in terms of the local flow parameters distribution. It is found out that in the case of exceeding the "critical roughness height" for the given boundary conditions and ejector's geometry, the ejector switches to the "off-design" mode and its performance decreases considerably.

  1. Study on the energy performance of glazing surfaces

    Directory of Open Access Journals (Sweden)

    Ligia MOGA

    2014-12-01

    Full Text Available A proper thermal design of the building envelope represents an important factor for the energy economics. Glazing surfaces represent one of the important elements in the hygrothermal design activity of a building envelope. The window’s thermal performance has also a strong influence on the thermal performance of the opaque area of the wall. This fact imposed the research of the real interaction, of cooperation and of mutual influences of the characteristics between the two components of the wall of the building envelope, respectively the opaque and the glazing area. Optimal constructive details for the opaque and glazing area of the wall need to be properly designed in order to achieve the required thermal and energy performances imposed for new types of buildings, e.g. passive houses, zero energy buildings.

  2. Bone regeneration performance of surface-treated porous titanium.

    Science.gov (United States)

    Amin Yavari, Saber; van der Stok, Johan; Chai, Yoke Chin; Wauthle, Ruben; Tahmasebi Birgani, Zeinab; Habibovic, Pamela; Mulier, Michiel; Schrooten, Jan; Weinans, Harrie; Zadpoor, Amir Abbas

    2014-08-01

    The large surface area of highly porous titanium structures produced by additive manufacturing can be modified using biofunctionalizing surface treatments to improve the bone regeneration performance of these otherwise bioinert biomaterials. In this longitudinal study, we applied and compared three types of biofunctionalizing surface treatments, namely acid-alkali (AcAl), alkali-acid-heat treatment (AlAcH), and anodizing-heat treatment (AnH). The effects of treatments on apatite forming ability, cell attachment, cell proliferation, osteogenic gene expression, bone regeneration, biomechanical stability, and bone-biomaterial contact were evaluated using apatite forming ability test, cell culture assays, and animal experiments. It was found that AcAl and AnH work through completely different routes. While AcAl improved the apatite forming ability of as-manufactured (AsM) specimens, it did not have any positive effect on cell attachment, cell proliferation, and osteogenic gene expression. In contrast, AnH did not improve the apatite forming ability of AsM specimens but showed significantly better cell attachment, cell proliferation, and expression of osteogenic markers. The performance of AlAcH in terms of apatite forming ability and cell response was in between both extremes of AnH and AsM. AcAl resulted in significantly larger volumes of newly formed bone within the pores of the scaffold as compared to AnH. Interestingly, larger volumes of regenerated bone did not translate into improved biomechanical stability as AnH exhibited significantly better biomechanical stability as compared to AcAl suggesting that the beneficial effects of cell-nanotopography modulations somehow surpassed the benefits of improved apatite forming ability. In conclusion, the applied surface treatments have considerable effects on apatite forming ability, cell attachment, cell proliferation, and bone ingrowth of the studied biomaterials. The relationship between these properties and the bone

  3. Hydrologic considerations for rock RIPRAP protection of uranium tailings impoundments

    International Nuclear Information System (INIS)

    Walters, W.H.; Skaggs, R.L.

    1984-02-01

    Pacific Northwest Laboratory is conducting an in-depth study of the application of rock riprap for the long-term protection of uranium tailings impoundments. Decommissioned tailings sites at Grand Junction and Slickrock, Colorado were selected to review the application of riprap design methods and evaluate variable sensitivity and data requirements. Preliminary results from the Grand Junction case study indicate that the use of a safety factor in sizing the rock riprap may provide an overly conservative design that may not be justified. Some safety factor, usually a value of 1.5 to 2.0 is normally used in riprap design to allow for the uncertainties in the hydraulic calculations. The computation of the hydraulic designs variables using the probable maximum flood (PMF) event introduces conservatism into the design and the added safety factor may not be warranted. This paper presents some preliminary results from the Grand Junction site concerning the implications of using a safety factor for riprap design. 9 references, 2 figures, 2 tables

  4. Presentations from the 1992 Coal Mining Impoundment Informational Meeting

    Energy Technology Data Exchange (ETDEWEB)

    1993-12-31

    On May 20 and 21, 1992, the MSHA Coal Mining Impoundment Informational Meeting was held at the National Mine Health and Safety Academy in Beckley, West Virginia. Fifteen presentations were given on key issues involved in the design and construction of dams associated with coal mining. The attendees were told that to improve the consistency among the plan reviewers, engineers from the Denver and Pittsburgh Technical Support Centers meet twice annually to discuss specific technical issues. It was soon discovered that the topics being discussed needed to be shared with anyone involved with coal waste dam design, construction, or inspection. The only way to accomplish that goal was through the issuance of Procedure Instruction Letters. The Letters present a consensus of engineering philosophy that could change over time. They do not present policy or carry the force of law. Currently, thirteen position papers have been disseminated and more will follow as the need arises. The individual paper were not even entered into the database.

  5. Effect of Moving Surface on NACA 63218 Aerodynamic Performance

    Directory of Open Access Journals (Sweden)

    Yahiaoui Tayeb

    2015-01-01

    Full Text Available The main subject of this work is the numerical study control of flow separation on a NACA 63218 airfoil by using moving surface. Different numerical cases are considered: the first one is the numerical simulation of non-modified airfoil NACA 63218 according at different angle of attack and the second one a set of moving cylinder is placed on leading edge of the airfoil. The rotational velocity of the cylinder is varied to establish the effect of momentum injection on modified airfoil aerodynamic performances. The turbulence is modeled by two equations k-epsilon model.

  6. Conversion of a tailing impoundment to a freshwater reservoir, the Eagle Park Reservoir project, Climax Mine, Colorado

    Energy Technology Data Exchange (ETDEWEB)

    Romig, B.R.; Cupp, J.L.; Ford, R.C.

    1999-07-01

    The Climax Molybdenum Mine, located near Leadville, Colorado, is the site of a lengthy mining history spanning more than 80 years. In the 1960's, extraction of molybdenum from oxide ore located adjacent to the massive molybdenite sulfide deposit resulted in the construction of an earthen core dam to impound fine-grained oxide tailing in the Eagle River Valley. Through recognized value of water storage and reclamation opportunities, a tailing removal project was initiated in 1993 to convert the impoundment facilities to a post-mining beneficial land use of developed water resources. An evaluation of the effect residual materials and lake dynamics would have on in-stream water quality was performed. Eagle Park Reservoir stands as a model for future reclamation efforts that involve water delivery to highly sensitive receiving waters. This paper provides a case study on project development, the evolution of water quality assessment, and the regulatory framework that contributed to this project's success.

  7. The fish community of a small impoundment in upstate New York

    Science.gov (United States)

    McCoy, C. Mead; Madenjian, Charles P.; Adams, Jean V.; Harman, Willard N.

    2001-01-01

    Moe Pond is a dimictic impoundment with surface area of 15.6 ha, a mean depth of 1.8 m, and an unexploited fish community of only two species: brown bullhead (Ameiurus nebulosus) and golden shiner (Notemigonus crysoleucas). The age-1 and older brown bullhead population was estimated to be 4,057 individuals, based on the Schnabel capture-recapture method of population estimation. Density and biomass were respectively estimated at 260 individuals/ha and 13 kg/ha. Annual survival rate of age-2 through age-5 brown bullheads was estimated at 48%. The golden shiner length-frequency distribution was unimodal with modal length of 80 mm and maximum total length of 115 m. The golden shiner population estimate was 7,154 individuals, based on seven beach seine haul replicate samples; the density and biomass were 686 shiners/ha and 5 kg/ha, respectively. This study provides an information baseline that may be useful in understanding food web interactions and whole-pond nutrient flux.

  8. Surface engineered porous silicon for stable, high performance electrochemical supercapacitors

    Science.gov (United States)

    Oakes, Landon; Westover, Andrew; Mares, Jeremy W.; Chatterjee, Shahana; Erwin, William R.; Bardhan, Rizia; Weiss, Sharon M.; Pint, Cary L.

    2013-10-01

    Silicon materials remain unused for supercapacitors due to extreme reactivity of silicon with electrolytes. However, doped silicon materials boast a low mass density, excellent conductivity, a controllably etched nanoporous structure, and combined earth abundance and technological presence appealing to diverse energy storage frameworks. Here, we demonstrate a universal route to transform porous silicon (P-Si) into stable electrodes for electrochemical devices through growth of an ultra-thin, conformal graphene coating on the P-Si surface. This graphene coating simultaneously passivates surface charge traps and provides an ideal electrode-electrolyte electrochemical interface. This leads to 10-40X improvement in energy density, and a 2X wider electrochemical window compared to identically-structured unpassivated P-Si. This work demonstrates a technique generalizable to mesoporous and nanoporous materials that decouples the engineering of electrode structure and electrochemical surface stability to engineer performance in electrochemical environments. Specifically, we demonstrate P-Si as a promising new platform for grid-scale and integrated electrochemical energy storage.

  9. Surface engineered porous silicon for stable, high performance electrochemical supercapacitors

    Science.gov (United States)

    Oakes, Landon; Westover, Andrew; Mares, Jeremy W.; Chatterjee, Shahana; Erwin, William R.; Bardhan, Rizia; Weiss, Sharon M.; Pint, Cary L.

    2013-01-01

    Silicon materials remain unused for supercapacitors due to extreme reactivity of silicon with electrolytes. However, doped silicon materials boast a low mass density, excellent conductivity, a controllably etched nanoporous structure, and combined earth abundance and technological presence appealing to diverse energy storage frameworks. Here, we demonstrate a universal route to transform porous silicon (P-Si) into stable electrodes for electrochemical devices through growth of an ultra-thin, conformal graphene coating on the P-Si surface. This graphene coating simultaneously passivates surface charge traps and provides an ideal electrode-electrolyte electrochemical interface. This leads to 10–40X improvement in energy density, and a 2X wider electrochemical window compared to identically-structured unpassivated P-Si. This work demonstrates a technique generalizable to mesoporous and nanoporous materials that decouples the engineering of electrode structure and electrochemical surface stability to engineer performance in electrochemical environments. Specifically, we demonstrate P-Si as a promising new platform for grid-scale and integrated electrochemical energy storage. PMID:24145684

  10. The hydrogeochemistry of four inactive tailings impoundments: Perspectives on tailings pore-water evolution

    International Nuclear Information System (INIS)

    Blowes, D.W.; Cherry, J.A.; Reardon, E.J.

    1987-01-01

    Extensive hydrogeochemical investigations are currently underway at three inactive tailings impoundments in Canada. These programs include detailed measurements of pore-water and gas-phase geochemistry through the vadose zone and the groundwater zone. An extensive piezometer network has been installed at each location to monitor the groundwater flow regime. All of the impoundments studied have been inactive for 15 to 25 years, sufficient time for extensive tailings pore-water evolution. The study areas include a very high-sulfide impoundment, a low-sulfide, high-carbonate impoundment, a low-sulfide, very low-carbonate impoundment, and a moderately high-sulfide impoundment. The pore water at each of the sites has evolved in a distinctly different and characteristic manner, representing broad styles of tailings pore-water evolution. At the high sulfide impoundment the oxidation of sulfide minerals has resulted in low pH, high redox potential conditions, with Fe 2+ concentrations in excess of 60,000 mg/L. At a depth of about 40 cm a 10 cm thick layer of ferrous and calcium sulfate minerals has precipitated. This hardpan layer limits the downward movement of O 2 and infiltrating pore waters. As a result, the pore water chemistry, both above and below the hardpan layer, has remained relatively unchanged over the past 10 years. The low-sulfide, high-carbonate tailings are sufficiently well buffered that no low pH conditions are present. The high pH conditions limit the concentrations of the metals released by sulfide mineral oxidation to levels that are two or three orders of magnitude less than is observed at the high-sulfide site. Pore waters at the low-sulfide, low-carbonate site were sampled by other researchers from the University of Waterloo

  11. The role of cassiterite controlling arsenic mobility in an abandoned stanniferous tailings impoundment at Llallagua, Bolivia.

    Science.gov (United States)

    Romero, Francisco Martín; Canet, Carles; Alfonso, Pura; Zambrana, Rubén N; Soto, Nayelli

    2014-05-15

    The surface water contamination by potentially toxic elements (PTE) leached from mine tailings is a major environmental concern. However, the formation of insoluble solid phases can control the mobility of PTE, with subsequent decrease of the risk that tailings suppose to the environment. We characterized the tailings from a tin inactive mine in Llallagua, Bolivia in order to assess the risk for surface water quality. These tailings contain high concentrations of PTE, with up to 94,344 mg/kg Fe, 9,135 mg/kg Sn, 4,606 mg/kg As, 1,362 mg/kg Cu, 1,220 mg/kg Zn, 955 mg/kg Pb and 151 mg/kg Cd. Oxidation of sulfide minerals in these tailings generates acid leachates (pH=2.5-3.5), rich in SO4(2-) and dissolved PTE, thereby releasing contaminants to the surface waters. Nevertheless, the concentrations of dissolved Sn, As and Pb in acid leachates are low (Sntailing deposits; it should be the main solid phase controlling Sn and As mobility in the impoundment. Additionally, jarosite and plumbojarosite, identified among the secondary minerals, could also play an important role controlling the mobility of As and Pb. Taking into account (a) the low solubility constants of cassiterite (Ksp=10(-64.2)), jarosite (Ksp=10(-11)) and plumbojarosite (Ksp=10(-28.66)), and (b) the stability of these minerals under acidic conditions, we can conclude that they control the long-term fate of Sn, As and Pb in the studied tailings. Copyright © 2014 Elsevier B.V. All rights reserved.

  12. The impact of impoundment on the rotifer communities in two tropical floodplain environments: interannual pulse variations

    Directory of Open Access Journals (Sweden)

    CC. Bonecker

    Full Text Available Hydrological pulses are the main factor regulating the structure of biological communities in floodplains. Reservoirs above this ecosystem change the environment's dynamics and the community's biodiversity. This study evaluated the structure and stability of the rotifer community in response to changes in hydrological pulses after the Porto Primavera impoundment in the Upper Paraná River floodplain. The community was studied in a river and in a floodplain lake downstream of the dam over a four-year period before and after the impoundment. A decrease in species richness and abundance was observed soon after the impoundment, followed by an increase in these attributes and in specific diversity when the hydrometric level of the Paraná River rose and, consequently, increased the connectivity between the floodplain environments. Conochilus coenobasis, Filinia longiseta, Keratella cochlearis, Lecane proiecta and Polyarthra dolichoptera persisted throughout the study and contributed to community stability (the maintenance of rank in species abundance over time, which was high in the floodplain lake, mainly after the impoundment. Reductions in the frequency, intensity and amplitude of potamophase pulses after the impoundment led to the decrease in species richness and the increases in abundance, community stability, and species diversity, which determine community resilience.

  13. Using Helicopter Electromagnetic Surveys to Identify Potential Hazards at Mine Waste Impoundments

    Energy Technology Data Exchange (ETDEWEB)

    Hammack, R.W.

    2008-01-01

    In July 2003, helicopter electromagnetic surveys were conducted at 14 coal waste impoundments in southern West Virginia. The purpose of the surveys was to detect conditions that could lead to impoundment failure either by structural failure of the embankment or by the flooding of adjacent or underlying mine works. Specifically, the surveys attempted to: 1) identify saturated zones within the mine waste, 2) delineate filtrate flow paths through the embankment or into adjacent strata and receiving streams, and 3) identify flooded mine workings underlying or adjacent to the waste impoundment. Data from the helicopter surveys were processed to generate conductivity/depth images. Conductivity/depth images were then spatially linked to georeferenced air photos or topographic maps for interpretation. Conductivity/depth images were found to provide a snapshot of the hydrologic conditions that exist within the impoundment. This information can be used to predict potential areas of failure within the embankment because of its ability to image the phreatic zone. Also, the electromagnetic survey can identify areas of unconsolidated slurry in the decant basin and beneath the embankment. Although shallow, flooded mineworks beneath the impoundment were identified by this survey, it cannot be assumed that electromagnetic surveys can detect all underlying mines. A preliminary evaluation of the data implies that helicopter electromagnetic surveys can provide a better understanding of the phreatic zone than the piezometer arrays that are typically used.

  14. Enhanced propellant performance via environmentally friendly curable surface coating

    Directory of Open Access Journals (Sweden)

    Thelma Manning

    2017-06-01

    Full Text Available Surface coating of granular propellants is widely used in a multiplicity of propellants for small, medium and large caliber ammunition. All small caliber ball propellants exhibit burning progressivity due to application of effective deterrent coatings. Large perforated propellant grains have also begun utilizing plasticizing and impregnated deterrent coatings with the purpose of increasing charge weights for greater energy and velocity for the projectile. The deterrent coating and impregnation process utilizes volatile organic compounds (VOCs and hazardous air pollutants (HAPs which results in propellants that need to be forced air dried which impacts air quality. Propellants undergo temperature fluctuations during their life. Diffusion coefficients vary exponentially with variations in temperature. A small temperature increase can induce a faster migration, even over a short period of time, which can lead to large deviations in the concentration. This large concentration change in the ammunition becomes a safety or performance liability. The presence of both polymeric deterrents and nitroglycerin(NG in the nitrocellulose matrix and organic solvents leads to higher diffusion rates. This results in continued emissions of VOCs and HAPs. Conventional polymers tend to partition within the propellant matrix. In other words, localized mixing can occur between the polymer and underlying propellant. This is due to solvent induced softening of the polymer vehicle over the propellant grain. In effect this creates a path where migration can occur. Since nitrate esters, like NG, are relatively small, it can exude to the surface and create a highly unstable and dangerous situation for the warfighter. Curable polymers do not suffer from this partitioning due to “melting” because no VOC solvents are present. They remain surface coated. The small scale characterization testing, such as closed bomb testing, small scale sensitivity, thermal stability, and

  15. Effect of Surface Contaminants Remained on the Blasted Surface on Epoxy Coating Performance and Corrosion Resistance

    International Nuclear Information System (INIS)

    Baek, Kwang Ki; Park, Chung Seo; Kim, Ki Hong; Chung, Mong Kyu; Park, Jin Hwan

    2006-01-01

    One of the critical issues in the coating specification is the allowable limit of surface contaminant(s) - such as soluble salt(s), grit dust, and rust - after grit blasting. Yet, there is no universally accepted data supporting the relationship between the long-term coating performance and the amount of various surface contaminants allowed after grit blasting. In this study, it was attempted to prepare epoxy coatings applied on grit-blasted steel substrate dosed with controlled amount of surface contaminants - such as soluble salt(s), grit dust, and rust. Then, coating samples were subjected to 4,200 hours of cyclic test(NORSOK M-501), which were then evaluated in terms of resistance to rust creepage, blistering, chalking, rusting, cracking and adhesion strength. Additional investigations on the possible damage at the paint/steel interface were carried out using an Electrochemical Impedance Spectroscopy(EIS) and observations of under-film-corrosion. Test results suggested that the current industrial specifications were well matched with the allowable degree of rust, whereas the allowable amount of soluble salt and grit dust after grit blasting showed a certain deviation from the specifications currently employed for fabrication of marine vessels and offshore facilities

  16. Performance Evaluation Criterion at Equal Pumping Power for Enhanced Performance Heat Transfer Surfaces

    Directory of Open Access Journals (Sweden)

    Rajendra Karwa

    2013-01-01

    Full Text Available The existing equations for the thermal performance evaluation, at equal pumping power for the artificially roughened and smooth surfaced multitube and rectangular duct heat exchangers, have been critically reviewed because the literature survey indicates that a large number of researchers have not interpreted these equations correctly. Three of the most widely used equations have been restated with clearly defined constraints and conditions for their application. Two new equations have been developed for the design constraints not covered earlier.

  17. Diet and trophic structure of the fish fauna in a subtropical ecosystem: impoundment effects

    Directory of Open Access Journals (Sweden)

    Rosilene Luciana Delariva

    Full Text Available This study examined the diet and trophic structure of the fish fauna, over temporal and spatial scales, as affected by the impoundment of the Iguaçu River in the region of Salto Caxias, Paraná State, Brazil. Sampling was conducted before (March 1997 - February 1998 and after the impoundment (March 1999 - February 2000, at four sampling sites. The stomach contents were analyzed by the volumetric method. The species could be organized in 10 trophic guilds: algivores, carcinophages, detritivores, herbivores, aquatic insectivores, terrestrial insectivores, invertivores, omnivores, piscivores, and planktivores; the first and last guilds were represented only in the post-impoundment period. Similarity patterns and feeding changes were summarized by a non-metric Multi-dimensional Scaling (nMDS analysis and statistically tested by a Permutational multivariate analysis of variance (PERMANOVA. Most species showed feeding changes, except for the piscivores and detritivores. These changes were related to the temporal factor (impoundment phases, such as reduced intake of benthic organisms and allochthonous food, which were usually replaced by resources from the reservoir itself (algae, microcrustaceans, and fish, simplifying the food spectrum of the fish fauna. A different indicator of food resources (IndVal corroborated these changes in the feeding of the species. The proportions of the trophic guilds evaluated based on the catch per unit of effort (CPUE and tested by ANOSIM were significantly different before and after the impoundment. Herbivores and piscivores were the guilds that contributed (SIMPER to these differences, especially the high increase in biomass of the piscivore guild after the impoundment. Variations in the abundance of trophic guilds were more directly related to changes in the feeding habits of the fish fauna than to increases in the number and biomass of the species that constitute these guilds.

  18. Inferred performance of surface hydraulic barriers from landfill operational data

    International Nuclear Information System (INIS)

    Gross, B.A.; Bonaparte, R.; Othman, M.A.

    1997-01-01

    There are few published data on the field performance of surface hydraulic barriers (SHBs) used in waste containment or remediation applications. In contrast, operational data for liner systems used beneath landfills are widely available. These data are frequently collected and reported as a facility permit condition. This paper uses leachate collection system (LCS) and leak detection system (LDS) liquid flow rate and chemical quality data collected from modem landfill double-liner systems to infer the likely hydraulic performance of SHBs. Operational data for over 200 waste management unit liner systems are currently being collected and evaluated by the authors as part of an ongoing research investigation for the United States Environmental Protection Agency (USEPA). The top liner of the double-liner system for the units is either a geomembrane (GMB) alone, geomembrane overlying a geosynthetic clay liner (GMB/GCL), or geomembrane overlying a compacted clay liner (GMB/CCL). In this paper, select data from the USEPA study are used to: (i) infer the likely efficiencies of SHBs incorporating GMBs and overlain by drainage layers; and (ii) evaluate the effectiveness of SHBs in reducing water infiltration into, and drainage from, the underlying waste (i.e., source control). SHB efficiencies are inferred from calculated landfill liner efficiencies and then used to estimate average water percolation rates through SHBs as a function of site average annual rainfall. The effectiveness of SHBs for source control is investigated by comparing LCS liquid flow rates for open and closed landfill cells. The LCS flow rates for closed cells are also compared to the estimated average water percolation rates through SHBs presented in the paper

  19. Proceedings of the 15. annual British Columbia MEND ML/ARD workshop : the management of tailings and tailings impoundments

    International Nuclear Information System (INIS)

    2009-02-01

    This Mine Environment Neutral Drainage (MEND) workshop was held to promote the exchange of information and ideas on environmental protection and reclamation associated with mining. The workshop covered a broad spectrum of reclamation issues and the key environmental challenges facing the mining industry, such as acid mine drainage (AMD) control, and metal leaching and acid rock drainage (ML/ARD). The theme for the 2008 workshop was the management of tailings and tailings impoundments. Topics of discussion included hydrogeology and geochemistry; tailings disposal; mitigation; closure plans; and postclosure performance. The emphasis was on full-scale case studies, practical constraints and sustaining successful disposal strategies and remediation. The session on tailings management reviewed overarching policies and practices; methods of subaerial tailings disposal and case studies of tailings management; and detailed investigations of geochemical properties and processes. The conference featured 22 presentations, of which 4 have been catalogued separately for inclusion in this database. refs., tabs., figs

  20. Limnology and fisheries of three recently impounded reservoirs in Sri Lanka

    International Nuclear Information System (INIS)

    Silva, K.H.G.M De

    1990-01-01

    The hydroelectric reservoirs of Kotmale, Victoria, and Randenigala were impounded in 1985, 1984, and 1986, respectively, by damming the Mahaweli River. The surface area, maximum depth, and mean depth of the three reservoirs are 6.3 km 2 , 78 m, 27.6 m; 23.7 km 2 , 102 m, 30.8 m; and 23.5 km 2 , 90 m, 36.6 m respectively, at their full supply levels of 703, 438, and 232 m above mean sea level. Important physicochemical factors and phytoplankton were studied by sampling of subsurface waters every two weeks in 12 randomly chosen stations in Randenigala and Victoria, and in 10 stations in Kotmale over 24 months. Mean water temperature, pH, conductivity, and the total alkalinity during the study period were 25.6 degree C, 6.6, 50.7 μsieverts, and 0.31 millimoles/l in Kotmale, 26.9 degree C, 7.1, 77.4 μsieverts, and 0.62 millimoles/l in Victoria, and 28.3 degree C, 7.4, 90.0 μsieverts, and 0.79 millimoles/l in Randenigala. The gill-net catches of Kotmale and Victoria are ca 38 and 70 kg/hectare/y, respectively. Randenigala has a fishery potential of ca 70 kg/hectare/y. Tilapia formed ca 68%, 59%, and 69% of the catches of Kotmale, Victoria, and Randenigala, respectively. The catch at Kotmale was mainly Java tilapia and Nile tilapia, whereas at the other two reservoirs it was mainly Java tilapia. Indigenous species constituted only ca 10% of the catch. 16 refs., 2 figs., 4 tabs

  1. Performing chemical reactions in virtual capillary of surface tension ...

    Indian Academy of Sciences (India)

    The flow paths were fabricated by making parallel lines using permanent marker pen ink or other polymer on glass surfaces. Two mirror image patterned glass plates were then sandwiched one on top of the other, separated by a thin gap - created using a spacer. The aqueous liquid moves between the surfaces by capillary ...

  2. Effects of increased summer flooding on nitrogen dynamics in impounded mangroves

    NARCIS (Netherlands)

    Verhoeven, Jos T A; Laanbroek, Hendrikus J; Rains, Mark C; Whigham, Dennis F

    2014-01-01

    Mangroves are important for coastal protection, carbon sequestration and habitat provision for plants and animals in the tropics and subtropics. Mangroves are threatened by habitat destruction and sea level rise, but management activities such as impounding for mosquito control can also have

  3. Cumulative impoundment evaporation in water resource management within the mid-Atlantic: A case study in Virginia

    Science.gov (United States)

    Scott, D.; Burgholzer, R.; Kleiner, J.; Brogan, C. O.; Julson, C.; Withers, E.

    2017-12-01

    Across the eastern United States, successful management of water resources to satisfy the competing demands for human consumption, industry, agriculture, and ecosystems requires both water quality and water quantity considerations. Over the last 2 decades, low streamflows during dry summers have increased scrutiny on water supply withdrawals. Within Virginia, a statewide hydrologic model provides quantitative assessments on impacts from proposed water withdrawals to downstream river flow. Currently, evaporative losses are only accounted for from the large reservoirs. In this study, we sought to provide a baseline estimate for the cumulative evaporation from impoundments across all of the major river basins in Virginia. Virginia provides an ideal case study for the competing water demands in the mid-Atlantic region given the unique tracking of water withdrawals throughout the river corridor. In the over 73,000 Virginia impoundments, the cumulative annual impoundment evaporation was 706 MGD, or 49% of the permitted water withdrawal. The largest reservoirs (>100 acres) represented over 400 MGD, and 136 MGD for the smaller impoundments (water loss (evaporation + demand), with some areas where impoundment evaporation was greater than human water demand. Seasonally, our results suggest that cumulative impoundment evaporation in some watersheds greatly impacts streamflow during low flow periods. Our results demonstrate that future water supply planning will require not only understanding evaporation within large reservoirs, but also the thousands of small impoundments across the landscape.

  4. Morphing Flight Control Surface for Advanced Flight Performance, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — In this SBIR project, a new Morphing Flight Control Surface (MFCS) will be developed. The distinction of the research effort is that the SenAnTech team will employ...

  5. Investigation of surface roughness influence on hyperbolic metamaterial performance

    Directory of Open Access Journals (Sweden)

    S. Kozik

    2014-12-01

    Full Text Available The main goal of this work was to introduce simple model of surface roughness which does not involve objects with complicated shapes and could help to reduce computational costs. We described and proved numerically that the influence of surface roughness at the interfaces in metal-dielectric composite materials could be described by proper selection of refractive index of dielectric layers. Our calculations show that this model works for roughness with RMS value about 1 nm and below.

  6. Frictional Performance Assessment of Cemented Carbide Surfaces Textured by Laser

    Science.gov (United States)

    Fang, S.; Llanes, L.; Klein, S.; Gachot, C.; Rosenkranz, A.; Bähre, D.; Mücklich, F.

    2017-10-01

    Cemented carbides are advanced engineering materials often used in industry for manufacturing cutting tools or supporting parts in tribological system. In order to improve service life, special attention has been paid to change surface conditions by means of different methods, since surface modification can be beneficial to reduce the friction between the contact surfaces as well as to avoid unintended damage. Laser surface texturing is one of the newly developed surface modification methods. It has been successfully introduced to fabricate some basic patterns on cemented carbide surfaces. In this work, Direct Laser Interference Patterning Technique (DLIP) is implemented to produce special line-like patterns on a cobalt (Co) and nickel (Ni) based cemented tungsten carbide grade. It is proven that the laser-produced patterns have high geometrical precision and quality stability. Furthermore, tribology testing using a nano-tribometer unit shows that friction is reduced by the line-like patterns, as compared to the polished one, under both lubricated and dry testing regimes, and the reduction is more pronounced in the latter case.

  7. The importance of surface finish to energy performance

    Directory of Open Access Journals (Sweden)

    Smith Geoff B.

    2017-01-01

    Full Text Available Power generation in solar energy systems, thermal control in buildings and mitigation of the Urban Heat Island problem, are all sensitive to directional response to incoming radiation. The radiation absorption and emission profile also plays a crucial role in each system's response and depends strongly on surface finish. This important sensitivity needs wider recognition in materials data sheets, system modeling, plus in materials and environmental engineering. The impact of surface roughness on thermal response of natural and man-made external environments is examined. Important examples will be given of the role of surface finish within each class. Total emittance links to the way surface finish influences directional emittance E(θ. Smooth surface thermal emittance on PV module covers, many solar absorbers, some roof paints, polished concrete, and glass windows can be up to 15% different from insulator results based on fully diffuse models of the same material. Widespread evidence indicates smooth metals and low-E solar absorber surfaces cool faster, and smooth insulators slower than previously thought. Matt paint is cooler than low sheen paint under the same solar heating impacts and normal concrete cooler than polished. Emittance for water is the prime environmental example of oblique impacts as it reflects strongly at oblique incidence, which leads to a significant drop in E(θ. Ripples or waves however raise water's average emittance. A surprise in this work was the high sensitivity of total E and its angular components to roughness in the depth range of 0.1–0.8 μm, which are well under ambient thermal IR wavelengths of 3–30 μm but common in metal finishing. Parallel energy flows such as evaporation and convective cooling vary if emittance varies. Thermal image analysis can provide insights into angular radiative effects.

  8. The effect of surface roughness on the performances of liner-piston ...

    African Journals Online (AJOL)

    The effect of surface roughness on the performances of liner-piston ring contact in internal combustion engine. ... The surface roughness between the liner and the piston rings, plays an ... EMAIL FREE FULL TEXT EMAIL FREE FULL TEXT

  9. Investigation into the heat transfer performance of helically ribbed surfaces

    International Nuclear Information System (INIS)

    Firth, R.J.

    1981-12-01

    The first part of an investigation into flow and heat transfer in annular channels and seven pin clusters is described. One of the main aims of the project is to improve cluster heat transfer prediction codes for helically ribbed surfaces. A study is made of the heat transfer and flow characteristics of a helically ribbed pin in an annular channel. It is shown that the swirling flow, which is induced by the helical ribs, gives rise to substantially enhanced diffusivity levels. This phenomenon had not been taken into account by previous analysis techniques. The methods for analysing heat transfer and pressure drop data from annular channels which were originally developed for non-swirling flow are generalised to accommodate swirling flow. The new methods are shown to be consistent with empirical data. Roughness parameter data is presented for helically ribbed surfaces with an axial rib pitch into height ratio of about 7. (author)

  10. The Impact of Impoundment on Mercury Bioaccumulation in Fish Downstream from a Newly Constructed Reservoir, Wujiang River, Southwest China.

    Science.gov (United States)

    Li, Sixin; Zhou, Lianfeng; Chang, Jianbo; Yang, Zhi; Hu, Juxiang; Hongjun, Wang

    2017-11-01

    Mercury concentrations in fish were investigated downstream from a newly impounded subtropical reservoir in August 2008. After 6-7 months of reservoir impoundment, mean mercury concentration in fish from downstream is significantly increased by 1.9 times. Not only carnivorous fish but also benthic fish had significantly higher total mercury concentrations than others. No significant correlation was found between total mercury concentrations and body length or weight of 13 fish species. Compared with the pre-impoundment, total mercury in fish from downstream is significantly increased by reservoir impoundment, but the increased rate is lower than those in subarctic and temperate areas. Fish samples surpassed the Chinese hygienic standard for tolerances of mercury in foods increased by 4.3%. More attention should be given to fish mercury levels from downstream sites to prevent possible adverse effects on the health of local people.

  11. Organochlorine pesticide levels in Clarias gariepinus from polluted freshwater impoundments in South Africa and associated human health risks

    CSIR Research Space (South Africa)

    Barnhoorn, IEJ

    2014-02-01

    Full Text Available There are increasing concerns regarding the safe human consumption of fish from polluted, freshwater impoundments. The aim of this study was to analyse the muscle tissue of the sharptooth catfish Clarias gariepinus for selected organo-chlorine...

  12. 30 CFR 77.216-2 - Water, sediment, or slurry impoundments and impounding structures; minimum plan requirements...

    Science.gov (United States)

    2010-07-01

    ... SAFETY AND HEALTH MANDATORY SAFETY STANDARDS, SURFACE COAL MINES AND SURFACE WORK AREAS OF UNDERGROUND... instrumentation. (9) Graphs showing area-capacity curves. (10) A statement of the runoff attributable to the probable maximum precipitation of 6-hour duration and the calculations used in determining such runoff. (11...

  13. Improving the Performance of Semiconductor Sensor Devices Using Surface Functionalization

    Science.gov (United States)

    Rohrbaugh, Nathaniel W.

    As production and understanding of III-nitride growth has progressed, this class of material has been used for its semiconducting properties in the fields of computer processing, microelectronics, and LEDs. As understanding of materials properties has advanced, devices were fabricated to be sensitive to environmental surroundings such as pH, gas, or ionic concentration. Simultaneously the world of pharmaceuticals and environmental science has come to the age where the use of wearable devices and active environmental sensing can not only help us learn more about our surroundings, but help save lives. At the crossroads of these two fields work has been done in marrying the high stability and electrical properties of the III-nitrides with the needs of a growing sensor field for various environments and stimuli. Device architecture can only get one so far, and thus the need for well understood surface functionalization techniques has arisen in the field of III-nitride environmental sensing. Many existing schemes for functionalization involve chemistries that may be unfriendly to a biological environment, unstable in solution, or expensive to produce. One possible solution to these issues is the work presented here, which highlights a surface modification scheme utilizing phosphonic acid based chemistry and biomolecular attachment. This dissertation presents a set of studies and experiments quantifying and analyzing the response behaviors of AlGaN/GaN field effect transistor (FET) devices via their interfacial electronic properties. Additional investigation was done on the modification of these surfaces, effects of stressful environmental conditions, and the utility of the phosphonic acid surface treatments. Signals of AlGaN/GaN FETs were measured as IDrain values and in the earliest study an average signal increase of 96.43% was observed when surfaces were incubated in a solution of a known recognition peptide sequence (SVSVGMKPSPRP). This work showed that even without

  14. Immediate effect of laryngeal surface electrical stimulation on swallowing performance.

    Science.gov (United States)

    Takahashi, Keizo; Hori, Kazuhiro; Hayashi, Hirokazu; Fujiu-Kurachi, Masako; Ono, Takahiro; Tsujimura, Takanori; Magara, Jin; Inoue, Makoto

    2018-01-01

    Surface electrical stimulation of the laryngeal region is used to improve swallowing in dysphagic patients. However, little is known about how electrical stimulation affects tongue movements and related functions. We investigated the effect of electrical stimulation on tongue pressure and hyoid movement, as well as suprahyoid and infrahyoid muscle activity, in 18 healthy young participants. Electrical stimulation (0.2-ms duration, 80 Hz, 80% of each participant's maximal tolerance) of the laryngeal region was applied. Each subject swallowed 5 ml of barium sulfate liquid 36 times at 10-s intervals. During the middle 2 min, electrical stimulation was delivered. Tongue pressure, electromyographic activity of the suprahyoid and infrahyoid muscles, and videofluorographic images were simultaneously recorded. Tongue pressure during stimulation was significantly lower than before or after stimulation and was significantly greater after stimulation than at baseline. Suprahyoid activity after stimulation was larger than at baseline, while infrahyoid muscle activity did not change. During stimulation, the position of the hyoid at rest was descended, the highest hyoid position was significantly inferior, and the vertical movement was greater than before or after stimulation. After stimulation, the positions of the hyoid at rest and at the maximum elevation were more superior than before stimulation. The deviation of the highest positions of the hyoid before and after stimulation corresponded to the differences in tongue pressures at those times. These results suggest that surface electrical stimulation applied to the laryngeal region during swallowing may facilitate subsequent hyoid movement and tongue pressure generation after stimulation. NEW & NOTEWORTHY Surface electrical stimulation applied to the laryngeal region during swallowing may facilitate subsequent hyoid movement and tongue pressure generation after stimulation. Tongue muscles may contribute to overshot recovery

  15. Rock riprap design methods and their applicability to long-term protection of uranium mill tailings impoundments

    International Nuclear Information System (INIS)

    Walters, W.H.

    1982-08-01

    This report reviews the more accepted or recommended riprap design methods currently used to design rock riprap protection against soil erosion by flowing water. The basic theories used to develop the various methods are presented. The Riprap Design with Safety Factors Method is identified as the logical choice for uranium mill tailings impoundments. This method is compared to the other methods and its applicability to the protection requirements of tailings impoundments is discussed. Other design problems are identified and investigative studies recommended

  16. Geomorphological assessment of sites and impoundments for the long term containment of uranium mill tailings in the Alligator Rivers Region

    International Nuclear Information System (INIS)

    East, T.J.

    1986-01-01

    This paper presents a program of current and future research into those geomorphological processes likely to affect the long term containment of uranium mill tailings in the Alligator Rivers Region of the Northern Territory. Research is directed at three main areas: identification of geomorphic hazards at proposed impoundment sites; determination of erosion rates on impoundment slopes; and prediction of patterns of fluvial dispersal of released tailings. Each necessitates consideration of present and future geomorphic processes

  17. Robust Anti-Icing Performance of a Flexible Superhydrophobic Surface.

    Science.gov (United States)

    Wang, Lei; Gong, Qihua; Zhan, Shihui; Jiang, Lei; Zheng, Yongmei

    2016-09-01

    A material with superhydrophobic and anti-ice/de-icing properties, which has a micro-/nanostructured surface, is produced by a straightforward method. This material comprises a poly(dimethylsiloxane) (PDMS) microstructure with ZnO nanohairs and shows excellent water and ice repellency even at low temperatures (-20 °C) and relatively high humidity (90%) for over three months. These results are expected to be helpful for designing smart, non-wetting materials that can be adapted to low-temperature environments for the development of anti-icing systems. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  18. Influence of vegetation and sewage sludge on sealing layer of fly ashes in post-treatment of mine tailings impoundments; Inverkan av vegetation och roetslam paa taetskikt av flygaska vid efterbehandling av sandmagasin

    Energy Technology Data Exchange (ETDEWEB)

    Greger, Maria; Neuschuetz, Clara (Inst. of Bothany, Stockholm Univ., Stockholm (Sweden)); Isaksson, Karl-Erik (Boliden Mineral AB, Stockholm (Sweden))

    2009-03-15

    Mining industry produces 25 Mton mine tailings yearly that are deposited in impoundments in the nature. When this sand, containing sulphur rich minerals, reacts with oxygen and water it starts to weather and acidic metal rich water is formed. To prevent this, the sand can be covered with a sealing layer and a protective cover layer with vegetation. As sealing and cover materials fly ashes and sewage sludge can be used. The aim of this investigation was to find out: 1) how sealing layer of fly ashes with and without sewage sludge, and a cover with sewage sludge can be placed practically on mine tailings in a cold climate. 2) how such a cover should be constructed to minimize the risk of root penetration and leakage of nutrients and metals 3) which vegetation that is most suitable This was investigated in field- and greenhouse tests with a sealing layer of fly ash and/or sewage sludge with a cover layer of sewage sludge in which different plant species were established. The practical application was performed in 0.3-1 ha plots at a mine tailings impoundments at Boliden. The ability of plant roots to penetrate a sealing layer was investigated, as well as the effect of simulated root exudates on the penetration resistance in hardened ash. Leakage of nutrients and metals from cover layer of sewage sludge, in some cases with sealing layers beneath, was investigated in field and greenhouse lysimeters. Various plant species were compared on their ability to affect metal and nutrient leakage as well as root penetration and shattering of the hardened ashes. The project was a cooperation between Stockholm University and Boliden Mineral AB, and the field tests were performed at the impoundment Gillervattnet in Boliden and in Garpenberg. Cooperating were also Iggesund Paperboard, Skellefteaa Kraft, Stora Enso Fors, Umeaa Energi and Vattenfall, all producers of ashes that were used, as well as Stockholm Vatten AB, which produced the sewage sludge. The most important conclusions

  19. Profiling of Sediment Microbial Community in Dongting Lake before and after Impoundment of the Three Gorges Dam

    Directory of Open Access Journals (Sweden)

    Wei Huang

    2016-06-01

    Full Text Available The sediment microbial community in downstream-linked lakes can be affected by the operation of large-scale water conservancy projects. The present study determined Illumina reads (16S rRNA gene amplicons to analyze and compare the bacterial communities from sediments in Dongting Lake (China before and after impoundment of the Three Gorges Dam (TGD, the largest hydroelectric project in the world. Bacterial communities in sediment samples in Dongting Lake before impoundment of the TGD (the high water period had a higher diversity than after impoundment of the TGD (the low water period. The most abundant phylum in the sediment samples was Proteobacteria (36.4%–51.5%, and this result was due to the significant abundance of Betaproteobacteria and Deltaproteobacteria in the sediment samples before impoundment of the TGD and the abundance of Gammaproteobacteria in the sediment samples after impoundment of the TGD. In addition, bacterial sequences of the sediment samples are also affiliated with Acidobacteria (11.0% on average, Chloroflexi (10.9% on average, Bacteroidetes (6.7% on average, and Nitrospirae (5.1% on average. Variations in the composition of the bacterial community within some sediment samples from the river estuary into Dongting Lake were related to the pH values. The bacterial community in the samples from the three lake districts of Dongting Lake before and after impoundment of the TGD was linked to the nutrient concentration.

  20. Restoration of Tidal Flow to Impounded Salt Marsh Exerts Mixed Effect on Leaf Litter Decomposition

    Science.gov (United States)

    Henry, B. A.; Schade, J. D.; Foreman, K.

    2015-12-01

    Salt marsh impoundments (e.g. roads, levees) disconnect marshes from ocean tides, which impairs ecosystem services and often promotes invasive species. Numerous restoration projects now focus on removing impoundments. Leaf litter decomposition is a central process in salt marsh carbon and nutrient cycles, and this study investigated the extent to which marsh restoration alters litter decomposition rates. We considered three environmental factors that can potentially change during restoration: salinity, tidal regime, and dominant plant species. A one-month field experiment (Cape Cod, MA) measured decay of litter bags in impounded, restored, and natural marshes under ambient conditions. A two-week lab experiment measured litter decay in controlled incubations under experimental treatments for salinity (1ppt and 30 ppt), tidal regime (inundated and 12 hr wet-dry cycles), and plant species (native Spartina alterniflora and invasive Phragmites australis). S. alterniflora decomposed faster in situ than P. australis (14±1.0% mass loss versus 0.74±0.69%). Corroborating this difference in decomposition, S. alterniflora supported greater microbial respiration during lab incubation, measured as CO2 flux from leaf litter and biological oxygen demand of water containing leached organic matter (OM). However, nutrient analysis of plant tissue and leached OM show P. australis released more nitrogen than S. alterniflora. Low salinity treatments in both lab and field experiments decayed more rapidly than high salinity treatments, suggesting that salinity inhibited microbial activity. Manipulation of inundation regime did not affect decomposition. These findings suggest the reintroduction of tidal flow to an impounded salt marsh can have mixed effects; recolonization by the native cordgrass could supply labile OM to sediment and slow carbon sequestration, while an increase in salinity might inhibit decomposition and accelerate sequestration.

  1. Modelling of contaminant migration in acidic groundwater plumes at uranium tailings impoundments: ADNEUT3

    International Nuclear Information System (INIS)

    Cherry, J.A.; Morin, K.A.; Dubrovsky, N.M.

    1984-06-01

    This report describes the creation and application of ADNEUT3, the latest addition to the ADNEUT (Acid-Drainage NEUTralization) family of computer programs for simulating acid-drainage transport and neutralization. The creation of ADNEUT3 involved the expansion of ADNEUT1 to allow variable input conditions such as changing input solution with time, variable initial amounts of minerals through the simulated streamtube, variable velocities through the streamtube, and variable solubilities for relevant minerals dependent on aqueous chemical composition. Concepts for simulating acid-drainage neutralization are reviewed and ADNEUT3 is then applied to a field-study site of acidic contaminant migration from the Nordic Main uranium-tailings impoundment near Elliot Lake, Ontario. A sensitivity study is first implemented to calibrate ADNEUT3 to the results of the 1979 to 1983 field studies. Then ADNEUT3 is used to define probable past conditions at the site which are not reliably known. In particular, ADNEUT3 is used to help identify: 1) the approximate year when acidic seepage began leaving the tailings impoundment (1966-1967), 2) the past chemical composition of the seepage (somewhat more acidic for a short period of time), and 3) the location of the source area within the tailings for the acidic seepage (near the impoundment dam, close to the field site). Finally, ADNEUT3 is used to predict future contaminant migration. Results indicate that hundreds of years are required under present conditions for the most acidic water with associated high levels of contaminants to migrate about 100 m from the tailings impoundment. The cause of this slow movement is the significant neutralization capacity of the aquifer. If acid production within the tailings decreases in the future, migration rates of contaminants will also decrease

  2. Impacts of Freshwater Impoundment in the West Loch of Pearl Harbor

    Science.gov (United States)

    1993-05-01

    absence of applicable non-point standards, the "Yellow Book" criteria for freshwater aquatic life or domestic water supply could be applied to evaluate the...Waimalu, Waipahu, Wahiawa, and Ewa water use districts and contains the largest groundwater body on Oahu, supplying more than 50 percent of the island’s...irrigation; desalt existing brackish water supplies, and; 3 create a freshwater impoundment in West Loch. 6I I I The Board of Water Supply (BWS) and

  3. Performance Improvement of Friction Stir Welds by Better Surface Finish

    Science.gov (United States)

    Russell, Sam; Nettles, Mindy

    2015-01-01

    The as-welded friction stir weld has a cross section that may act as a stress concentrator. The geometry associated with the stress concentration may reduce the weld strength and it makes the weld challenging to inspect with ultrasound. In some cases, the geometry leads to false positive nondestructive evaluation (NDE) indications and, in many cases, it requires manual blending to facilitate the inspection. This study will measure the stress concentration effect and develop an improved phased array ultrasound testing (PAUT) technique for friction stir welding. Post-welding, the friction stir weld (FSW) tool would be fitted with an end mill that would machine the weld smooth, trimmed shaved. This would eliminate the need for manual weld preparation for ultrasonic inspections. Manual surface preparation is a hand operation that varies widely depending on the person preparing the welds. Shaving is a process that can be automated and tightly controlled.

  4. Morphing flight control surface for advanced flight performance

    Science.gov (United States)

    Detrick, Matt; Kwak, Seung-Keon; Yoon, Hwan-Sik

    2006-03-01

    A novel Morphing Flight Control Surface (MFCS) system has been developed. The distinction of this research effort is that the SenAnTech team has incorporated our innovative Highly Deformable Mechanism (HDM) into our MFCS. The feasibility of this novel technology for deformable wing structures, such as airfoil shaping, warping or twisting with a flexure-based high displacement PZT actuator has been demonstrated via computational simulations such as Finite Element Analysis (FEA) and Computational Fluid Dynamics (CFD). CFD was implemented to verify the accuracy of the complex potential flow theory for this application. Then, complex potential flow theory, kinematics, geometry, and static force analysis were incorporated into a multidisciplinary GUI simulation tool. This tool has been used to aid the design of the MFCS. The results show that we can achieve up to five degrees of wing twisting with our proposed system, while using minimal volume within the wing and adding little weight.

  5. The geo-environmental design of a coal refuse impoundment in Illinois

    International Nuclear Information System (INIS)

    Ripp, B.J.

    1997-01-01

    The coal refuse impoundment discussed was one of the first permitted under new regulatory standards within the State of Illinois. The new standards go beyond the geotechnial stability of the structure and must address the groundwater quality of the area and the impact of the impoundment on the groundwater system. The geotechnial design of the coal refuse impoundment dam and associated structures had its own particular challenges such as: 1) the construction of the structure over mined workings; 2) the close proximity of seismically active fault zones; and 3) the embankment configuration being controlled by the material balance of the mine refuse. The implementation of the groundwater protection plan included: 1) incorporating the groundwater quality standards and sampling protocols of several state agencies while the standards were being drafted; 2) sampling of the potential sources of groundwater impact; 3) establishing background levels; and 4) establishing the groundwater class. An initial groundwater transport model was developed and used as the basis for recommending a groundwater monitoring design in place of constructing a soil or synthetic liner. 15 refs., 2 figs., 3 tabs

  6. Effect of ship locking on sediment oxygen uptake in impounded rivers

    DEFF Research Database (Denmark)

    Lorke, A.; McGinnis, D. F.; Maeck, A.

    2012-01-01

    In the majority of large river systems, flow is regulated and/or otherwise affected by operational and management activities, such as ship locking. The effect of lock operation on sediment-water oxygen fluxes was studied within a 12.9 km long impoundment at the Saar River (Germany) using eddy....... Additional means by which the oxygen budget of the impoundment is affected by lock-induced flow variations are discussed. Citation: Lorke, A., D. F. McGinnis, A. Maeck, and H. Fischer (2012), Effect of ship locking on sediment oxygen uptake in impounded rivers, Water Resour. Res., 48, W12514, doi: 10....... These wave-induced flow variations cause variations in sediment-water oxygen fluxes. While the mean flux during time periods without lock operation was 0.5 +/- 0.1 g m(-2) d(-1), it increased by about a factor of 2 to 1.0 +/- 0.5 g m(-2) d(-1) within time periods with ship locking. Following the daily...

  7. Dose assessment of remedial action for uranium tailing impoundment of a nuclear factory

    International Nuclear Information System (INIS)

    Li Xutong; Ma Ruwei; Guo Zede

    2000-01-01

    A large uranium tailing impoundment in China will be closure and remedial action have been planned. The remedial action will include shaping and covering the dam and beach in order to prevent the impoundment from damage and restrict spread of tailing sands and emission of radon. The author presents the analysis and estimation of the exposure to workers for remedial action and to public after the remedial action. To estimate the exposure to workers, the pathway of inhalation of radon, tailing sands in suspension and external γ exposure were taken into consideration. The exposure scenario is considered as probably maximum exposure to the workers who work on the tailing pile without any protection measures, the dose is 6.0 mSv/a. Two situation for the exposure to public after remedial action were considered: normal and abnormal condition. For the normal condition, inhalation of radon emitted from impoundment is only the pathway to public for the exposure, and individual dose for critical group of public is 0.053 mSv/a, collective dose for population within 80 km is 1.0 man·Sv/a. For the abnormal conditions, four scenarios were considered, i.e. dwelling on tailing pile, farming on tailing pile, living in a house built by contaminated materials and some temporal activities on the pile. The scenarios of dwellings is living in a house on the pile and drinking contaminated water. The maximum individual dose is 27 mSv/a

  8. Design Methodology And Performance Studies Of A Flexible Electrotextile Surface

    Directory of Open Access Journals (Sweden)

    Kayacan Ozan

    2015-09-01

    Full Text Available ‘The smart textiles’ concept has to develop products based not only on design, fashion and comfort but also in terms of functions. The novel electro-textiles in the market open up new trends in smart and interactive gadgets. ‘Easy to care and durability’ properties are among the most important features of these products. On the other hand, wearable electronic knitwear has been gaining the attention of both researchers and industrial sectors. Combining knitting technology with electronics may become a dominant trend in the future because of the wide application possibilities. This research is concerned primarily with the design methodology of knitted fabrics containing electrically conductive textiles and especially in-use performance studies. The structural characteristics of the fabrics have been evaluated to enhance the performance properties.

  9. Effet de la rugosité de surface sur les performances du contact ...

    African Journals Online (AJOL)

    Effet de la rugosité de surface sur les performances du contact segment- chemise dans un moteur à combustion interne. The effect of surface roughness on the performances of liner-piston ring contact in internal combustion engine. Amar Ayad. *. , Amar Skendraoui & Ammar Haiahem. Laboratoire de Mécanique Industrielle ...

  10. Predictive Measures of Locomotor Performance on an Unstable Walking Surface

    Science.gov (United States)

    Bloomberg, J. J.; Peters, B. T.; Mulavara, A. P.; Caldwell, E. E.; Batson, C. D.; De Dios, Y. E.; Gadd, N. E.; Goel, R.; Wood, S. J.; Cohen, H. S.; hide

    2016-01-01

    Locomotion requires integration of visual, vestibular, and somatosensory information to produce the appropriate motor output to control movement. The degree to which these sensory inputs are weighted and reorganized in discordant sensory environments varies by individual and may be predictive of the ability to adapt to novel environments. The goals of this project are to: 1) develop a set of predictive measures capable of identifying individual differences in sensorimotor adaptability, and 2) use this information to inform the design of training countermeasures designed to enhance the ability of astronauts to adapt to gravitational transitions improving balance and locomotor performance after a Mars landing and enhancing egress capability after a landing on Earth.

  11. Pre- and post-impoundment nitrogen in the lower Missouri River

    Science.gov (United States)

    Blevins, Dale W.; Wilkison, Donald H.; Niesen, Shelley L.

    2013-01-01

    Large water-sample sets collected from 1899 through 1902, 1907, and in the early 1950s allow comparisons of pre-impoundment and post-impoundment (1969 through 2008) nitrogen concentrations in the lower Missouri River. Although urban wastes were not large enough to detectably increase annual loads of total nitrogen at the beginning of the 20th century, carcass waste, stock-yard manure, and untreated human wastes measurably increased ammonia and organic-nitrogen concentrations during low flows. Average total-nitrogen concentrations in both periods were about 2.5 mg/l, but much of the particulate-organic nitrogen, which was the dominant form of nitrogen around 1900, has been replaced by nitrate. This change in speciation was caused by the nearly 80% decrease in suspended-sediment concentrations that occurred after impoundment, modern agriculture, drainage of riparian wetlands, and sewage treatment. Nevertheless, bioavailable nitrogen has not been low enough to limit primary production in the Missouri River since the beginning of the 20th century. Nitrate concentrations have increased more rapidly from 2000 through 2008 (5 to 12% per year), thus increasing bioavailable nitrogen delivered to the Mississippi River and affecting Gulf Coast hypoxia. The increase in nitrate concentrations with distance downstream is much greater during the post-impoundment period. If strategies to decrease total-nitrogen loads focus on particulate N, substantial decreases will be difficult because particulate nitrogen is now only 23% of total nitrogen in the Missouri River. A strategy aimed at decreasing particulates also could further exacerbate land loss along the Gulf of Mexico, which has been sediment starved since Missouri River impoundment. In contrast, strategies or benchmarks aimed at decreasing nitrate loads could substantially decrease nitrogen loadings because nitrates now constitute over half of the Missouri's nitrogen input to the Mississippi. Ongoing restoration and creation

  12. Hydrogenated amorphous silicon nitride photonic crystals for improved-performance surface electromagnetic wave biosensors.

    Science.gov (United States)

    Sinibaldi, Alberto; Descrovi, Emiliano; Giorgis, Fabrizio; Dominici, Lorenzo; Ballarini, Mirko; Mandracci, Pietro; Danz, Norbert; Michelotti, Francesco

    2012-10-01

    We exploit the properties of surface electromagnetic waves propagating at the surface of finite one dimensional photonic crystals to improve the performance of optical biosensors with respect to the standard surface plasmon resonance approach. We demonstrate that the hydrogenated amorphous silicon nitride technology is a versatile platform for fabricating one dimensional photonic crystals with any desirable design and operating in a wide wavelength range, from the visible to the near infrared. We prepared sensors based on photonic crystals sustaining either guided modes or surface electromagnetic waves, also known as Bloch surface waves. We carried out for the first time a direct experimental comparison of their sensitivity and figure of merit with surface plasmon polaritons on metal layers, by making use of a commercial surface plasmon resonance instrument that was slightly adapted for the experiments. Our measurements demonstrate that the Bloch surface waves on silicon nitride photonic crystals outperform surface plasmon polaritons by a factor 1.3 in terms of figure of merit.

  13. Predictive geochemical modeling of contaminant concentrations in laboratory columns and in plumes migrating from uranium mill tailings waste impoundments

    International Nuclear Information System (INIS)

    Peterson, S.R.; Martin, W.J.; Serne, R.J.

    1986-04-01

    A computer-based conceptual chemical model was applied to predict contaminant concentrations in plumes migrating from a uranium mill tailings waste impoundment. The solids chosen for inclusion in the conceptual model were selected based on reviews of the literature, on ion speciation/solubility calculations performed on the column effluent solutions and on mineralogical characterization of the contacted and uncontacted sediments. The mechanism of adsorption included in the conceptual chemical model was chosen based on results from semiselective extraction experiments and from mineralogical characterization procedures performed on the sediments. This conceptual chemical model was further developed and partially validated in laboratory experiments where assorted acidic uranium mill tailings solutions percolated through various sediments. This document contains the results of a partial field and laboratory validation (i.e., test of coherence) of this chemical model. Macro constituents (e.g., Ca, SO 4 , Al, Fe, and Mn) of the tailings solution were predicted closely by considering their concentrations to be controlled by the precipitation/dissolution of solid phases. Trace elements, however, were generally predicted to be undersaturated with respect to plausible solid phase controls. The concentration of several of the trace elements were closely predicted by considering their concentrations to be controlled by adsorption onto the amorphous iron oxyhydroxides that precipitated

  14. Sediment transport to and from small impoundments in northeast Kansas, March 2009 through September 2011

    Science.gov (United States)

    Foster, Guy M.; Lee, Casey J.; Ziegler, Andrew C.

    2012-01-01

    The U.S. Geological Survey, in cooperation with the Kansas Water Office, investigated sediment transport to and from three small impoundments (average surface area of 0.1 to 0.8 square miles) in northeast Kansas during March 2009 through September 2011. Streamgages and continuous turbidity sensors were operated upstream and downstream from Atchison County, Banner Creek, and Centralia Lakes to study the effect of varied watershed characteristics and agricultural practices on sediment transport in small watersheds in northeast Kansas. Atchison County Lake is located in a predominantly agricultural basin of row crops, with wide riparian buffers along streams, a substantial amount of tile drainage, and numerous small impoundments (less than 0.05 square miles; hereafter referred to as “ponds”). Banner Creek Lake is a predominantly grassland basin with numerous small ponds located in the watershed, and wide riparian buffers along streams. Centralia Lake is a predominantly agricultural basin of row crops with few ponds, few riparian buffers along streams, and minimal tile drainage. Upstream from Atchison County, Banner Creek, and Centralia Lakes 24, 38, and 32 percent, respectively, of the total load was transported during less than 0.1 percent (approximately 0.9 days) of the time. Despite less streamflow in 2011, larger sediment loads during that year indicate that not all storm events transport the same amount of sediment; larger, extreme storms during the spring may transport much larger sediment loads in small Kansas watersheds. Annual sediment yields were 360, 400, and 970 tons per square mile per year at Atchison County, Banner, and Centralia Lake watersheds, respectively, which were less than estimated yields for this area of Kansas (between 2,000 and 5,000 tons per square mile per year). Although Centralia and Atchison County Lakes had similar percentages of agricultural land use, mean annual sediment yields upstream from Centralia Lake were about 2.7 times

  15. Dual-band frequency selective surface with large band separation and stable performance

    Science.gov (United States)

    Zhou, Hang; Qu, Shao-Bo; Peng, Wei-Dong; Lin, Bao-Qin; Wang, Jia-Fu; Ma, Hua; Zhang, Jie-Qiu; Bai, Peng; Wang, Xu-Hua; Xu, Zhuo

    2012-05-01

    A new technique of designing a dual-band frequency selective surface with large band separation is presented. This technique is based on a delicately designed topology of L- and Ku-band microwave filters. The two band-pass responses are generated by a capacitively-loaded square-loop frequency selective surface and an aperture-coupled frequency selective surface, respectively. A Faraday cage is located between the two frequency selective surface structures to eliminate undesired couplings. Based on this technique, a dual-band frequency selective surface with large band separation is designed, which possesses large band separation, high selectivity, and stable performance under various incident angles and different polarizations.

  16. Experimental investigations of sensor-based surface following performed by a mobile manipulator

    Energy Technology Data Exchange (ETDEWEB)

    Reister, D.B.; Unseren, M.A.; Baker, J.E.; Pin, F.G.

    1994-10-01

    We discuss a series of surface following experiments using a range finder mounted on the end of an arm that is mounted on a vehicle. The goal is to keep the range finder at a fixed distance from an unknown surface and to keep the orientation of the range finder perpendicular to the surface. During the experiments, the vehicle moves along a predefined trajectory while planning software determines the position and orientation of the arm. To keep the range finder perpendicular to the surface, the planning software calculates the surface normal for the unknown surface. We assume that the unknown surface is a cylinder (the surface depends on x and y but does not depend on z). To calculate the surface normal, the planning software must calculate the locations (x,y) of points on the surface in world coordinates. The calculation requires data on the position and orientation of the vehicle, the position and orientation of the arm, and the distance from the range finder to the surface. We discuss four series of experiments. During the first series of experiments, the calculated surface normal values had large high frequency random variations. A filter was used to produce an average value for the surface normal and we limited the rate of change in the yaw angle target for the arm. We performed the experiment for a variety of concave and convex surfaces. While the experiments were qualitative successes, the measured distance to the surface was significantly different than the target. The distance errors were systematic, low frequency, and had magnitudes up to 25 mm. During the second series of experiments, we reduced the variations in the calculated surface normal values. While reviewing the data collected while following the surface of a barrel, we found that the radius of the calculated surface was significantly different than the measured radius of the barrel.

  17. Effect of surface integrity of hard turned AISI 52100 steel on fatigue performance

    International Nuclear Information System (INIS)

    Smith, Stephen; Melkote, Shreyes N.; Lara-Curzio, Edgar; Watkins, Thomas R.; Allard, Larry; Riester, Laura

    2007-01-01

    This paper addresses the relationship between surface integrity and fatigue life of hard turned AISI 52100 steel (60-62 HRC), with grinding as a benchmark. The impact of superfinishing on the fatigue performance of hard turned and ground surfaces is also discussed. Specifically, the surface integrity and fatigue life of the following five distinct surface conditions are examined: hard turned with continuous white layer, hard turned with no white layer, ground, and superfinished hard turned and ground specimens. Surface integrity of the specimens is characterized via surface topography measurement, metallography, residual stress measurements, transmission electron microscopy (TEM), and nano-indentation tests. High cycle tension-tension fatigue tests show that the presence of white layer does not adversely affect fatigue life and that, on average, the hard turned surface performs as well or better than the ground surface. The effect of superfinishing is to exaggerate these differences in performance. The results obtained from this study suggest that the effect of residual stress on fatigue life is more significant than the effect of white layer. For the hard turned surfaces, the fatigue life is found to be directly proportional to both the surface compressive residual stress and the maximum compressive residual stress. Possible explanations for the observed effects are discussed

  18. Development of material measures for performance verifying surface topography measuring instruments

    International Nuclear Information System (INIS)

    Leach, Richard; Giusca, Claudiu; Rickens, Kai; Riemer, Oltmann; Rubert, Paul

    2014-01-01

    The development of two irregular-geometry material measures for performance verifying surface topography measuring instruments is described. The material measures are designed to be used to performance verify tactile and optical areal surface topography measuring instruments. The manufacture of the material measures using diamond turning followed by nickel electroforming is described in detail. Measurement results are then obtained using a traceable stylus instrument and a commercial coherence scanning interferometer, and the results are shown to agree to within the measurement uncertainties. The material measures are now commercially available as part of a suite of material measures aimed at the calibration and performance verification of areal surface topography measuring instruments

  19. Dam-break studies for mine tailings impoundments

    International Nuclear Information System (INIS)

    Jeyapalan, J.K.

    1982-01-01

    This paper describes simple procedures for performing dam-break analyses. Tailings from dam failures usually liquefy and flow for substantial distances as a viscous fluid. The prediction of the possible extent of flow slide movement is illustrated using two case histories. Topics considered include the flow behavior of liquefied talings, dimensionsless numbers for mine tailings and associated flow regimes, laminar flow, and turbulent flow. The potential inundation regions downstream of mine tailings dams are assessed. It is concluded that instances of flow slides of mine waste embankments indicate that the failure of these structures has considerable potential for damage to life and property in many cases

  20. Geomorphological assessment of sites and impoundments for the long term containment of uranium mill tailings in the Alligator Rivers Region

    International Nuclear Information System (INIS)

    East, T.J.

    1985-01-01

    Current and future research into the geomorphological processes likely to affect the long term containment of uranium mill tailings in the Alligator Rivers Region is directed at three main areas: identification of geomorphic hazards at proposed impoundment sites; determination of erosion rates on impoundment slopes; and prediction of patterns of fluvial dispersal of released tailings. Each necessitates consideration of present and future geomorphic processes. Process rates during the next few thousand years might be predictable by extrapolation of contemporary and past (i.e. Holocene) climates, sea-levels and depositional environments, evidence for which is preserved in the sedimentary record. In current projects, the Late Quarternary stratigraphy of Magela Creek are examined to provide data for modelling of present and future sedimentological processes. Site stability evaluation entails recognition of present and future geomorphic hazards at impoundment sites, and includes fluvial and hillslope erosion, extreme flood events and mass movements. The life of a tailings impoundment is further determined by the intensity of erosional processes acting upon its slopes and their cover materials. A knowledge of present and future erosion rates will allow the optimisation of slope characteristics and materials in the impoundment design

  1. Influence of surface texturing on the performance of tilting pad thrust bearings

    OpenAIRE

    Gropper, Daniel; Wang, Ling; Harvey, Terry J.; Meck, Klaus-Dieter; Gviniashvili, Vladimir

    2016-01-01

    Surface textures have been shown to have the potential of enhancing the performance of hydrodynamic bearings and many other applications. However, a comprehensive literature review by the authors has revealed that the application of surface texturing is still limited due to major challenges, such as the complexity of computational models and the large variety of operating conditions encountered in conventional industrial applications. In the present work, the potential of surface texturing fo...

  2. 40 CFR 63.134 - Process wastewater provisions-surface impoundments.

    Science.gov (United States)

    2010-07-01

    ..., and semi-annually thereafter, for improper work practices and control equipment failures in accordance... this subpart, when an improper work practice or a control equipment failure is identified, first... treats a Group 1 wastewater stream or a residual removed from a Group 1 wastewater stream, the owner or...

  3. Relationships among catch, angler catisfaction, and fish assemblage characteristics of an urban small impoundment fishery

    Science.gov (United States)

    Ivasauskas, Tomas J.; Xiong, Wilson N.; Engman, Augustin C.; Fischer, Jesse R.; Kwak, Thomas J.; Rundle, Kirk R.

    2017-01-01

    Urban fisheries provide unique angling opportunities for people from traditionally underrepresented demographics. Lake Raleigh is a 38-ha impoundment located on the North Carolina State University campus in Raleigh. Like many urban fisheries, little is known about angler use and satisfaction or how angling catch rate is related to fish availability in Lake Raleigh. We characterized the recreational fishery and fish assemblage with concurrent creel and boat electrofishing surveys over the course of one year. In total, 245 anglers were interviewed on 68 survey days. On average, anglers spent 1.7 h fishing per trip and caught 0.385 fish h –1. A large proportion of anglers (43.9%) targeted multiple species, whereas 36.5% targeted largemouth bass (Micropterus salmoides), 10.0% targeted panfish (i.e., sunfishes [Lepomis spp.] and crappies [Pomoxis spp.]), and 9.6% targeted catfish (Ameiurus spp. and Ictalurus spp.). Most anglers (69.4%) were satisfied with their experience, and overall satisfaction was unrelated to catch rate. Pulsed-DC boat electrofishing was conducted on 25 dates, and 617 fish were sampled. Angler catch rate was unrelated to electrofishing catch rate, implying that anglers' catch rate was independent of fish density or availability. Our results demonstrate that even minimally managed urban fisheries can provide high angler satisfaction, with limited dedication of management resources. Relationships Among Catch, Angler Satisfaction, and Fish Assemblage Characteristics of an Urban Small Impoundment Fishery (PDF Download Available). Available from: https://www.researchgate.net/publication/316636550_Relationships_Among_Catch_Angler_Satisfaction_and_Fish_Assemblage_Characteristics_of_an_Urban_Small_Impoundment_Fishery [accessed Aug 11, 2017].

  4. Cyanobacteria and cyanotoxins are present in drinking water impoundments and groundwater wells in desert environments.

    Science.gov (United States)

    Chatziefthimiou, Aspassia D; Metcalf, James S; Glover, W Broc; Banack, Sandra A; Dargham, Soha R; Richer, Renee A

    2016-05-01

    Desert environments and drylands experience a drastic scarcity of water resources. To alleviate dependence on freshwater for drinking water needs, countries have invested in infrastructure development of desalination plants. Collectively, the countries of the Arabian Gulf produce 45% of the world's desalinated water, which is stored in dams, mega-reservoirs and secondary house water tanks to secure drinking water beyond daily needs. Improper storage practices of drinking water in impoundments concomitant with increased temperatures and light penetration may promote the growth of cyanobacteria and accumulation of cyanotoxins. To shed light on this previously unexplored research area in desert environments, we examined drinking and irrigation water of urban and rural environments to determine whether cyanobacteria and cyanotoxins are present, and what are the storage and transportation practices as well as the environmental parameters that best predict their presence. Cyanobacteria were present in 80% of the urban and 33% of the rural water impoundments. Neurotoxins BMAA, DAB and anatoxin-a(S) were not detected in any of the water samples, although they have been found to accumulate in the desert soils, which suggests a bioaccumulation potential if they are leached into the aquifer. A toxic BMAA isomer, AEG, was found in 91.7% of rural but none of the urban water samples and correlated with water-truck transportation, light exposure and chloride ions. The hepatotoxic cyanotoxin microcystin-LR was present in the majority of all sampled impoundments, surpassing the WHO provisional guideline of 1 μg/l in 30% of the urban water tanks. Finally, we discuss possible management strategies to improve storage and transportation practices in order to minimize exposure to cyanobacteria and cyanotoxins, and actions to promote sustainable use of limited water resources. Copyright © 2016 Elsevier Ltd. All rights reserved.

  5. Pressure effects on interfacial surface contacts and performance of organic solar cells

    NARCIS (Netherlands)

    Agyei-Tuffour, B.; Doumon, Nutifafa Y.; Rwenyagila, E. R.; Asare, J.; Oyewole, O. K.; Shen, Z.; Petoukhoff, C. E.; Zebaze Kana, M. G.; Ocarroll, D. M.; Soboyejo, W. O.

    2017-01-01

    This paper explores the effects of pressure on the interfacial surface contacts and the performance of organic solar cells. A combination of experimental techniques and analytical/computational models is used to study the evolving surface contacts profiles that occur when compliant, semi-rigid and

  6. Challenges and opportunities of modeling plasma–surface interactions in tungsten using high-performance computing

    Energy Technology Data Exchange (ETDEWEB)

    Wirth, Brian D., E-mail: bdwirth@utk.edu [Department of Nuclear Engineering, University of Tennessee, Knoxville, TN 37996 (United States); Nuclear Science and Engineering Directorate, Oak Ridge National Laboratory, Oak Ridge, TN (United States); Hammond, K.D. [Department of Nuclear Engineering, University of Tennessee, Knoxville, TN 37996 (United States); Krasheninnikov, S.I. [University of California, San Diego, La Jolla, CA (United States); Maroudas, D. [University of Massachusetts, Amherst, Amherst, MA 01003 (United States)

    2015-08-15

    The performance of plasma facing components (PFCs) is critical for ITER and future magnetic fusion reactors. The ITER divertor will be tungsten, which is the primary candidate material for future reactors. Recent experiments involving tungsten exposure to low-energy helium plasmas reveal significant surface modification, including the growth of nanometer-scale tendrils of “fuzz” and formation of nanometer-sized bubbles in the near-surface region. The large span of spatial and temporal scales governing plasma surface interactions are among the challenges to modeling divertor performance. Fortunately, recent innovations in computational modeling, increasingly powerful high-performance computers, and improved experimental characterization tools provide a path toward self-consistent, experimentally validated models of PFC and divertor performance. Recent advances in understanding tungsten–helium interactions are reviewed, including such processes as helium clustering, which serve as nuclei for gas bubbles; and trap mutation, dislocation loop punching and bubble bursting; which together initiate surface morphological modification.

  7. Challenges and opportunities of modeling plasma–surface interactions in tungsten using high-performance computing

    International Nuclear Information System (INIS)

    Wirth, Brian D.; Hammond, K.D.; Krasheninnikov, S.I.; Maroudas, D.

    2015-01-01

    The performance of plasma facing components (PFCs) is critical for ITER and future magnetic fusion reactors. The ITER divertor will be tungsten, which is the primary candidate material for future reactors. Recent experiments involving tungsten exposure to low-energy helium plasmas reveal significant surface modification, including the growth of nanometer-scale tendrils of “fuzz” and formation of nanometer-sized bubbles in the near-surface region. The large span of spatial and temporal scales governing plasma surface interactions are among the challenges to modeling divertor performance. Fortunately, recent innovations in computational modeling, increasingly powerful high-performance computers, and improved experimental characterization tools provide a path toward self-consistent, experimentally validated models of PFC and divertor performance. Recent advances in understanding tungsten–helium interactions are reviewed, including such processes as helium clustering, which serve as nuclei for gas bubbles; and trap mutation, dislocation loop punching and bubble bursting; which together initiate surface morphological modification

  8. contaminant migration in a sand aquifer near an inactive uranium tailings impoundment, Elliot Lake, Ontario

    International Nuclear Information System (INIS)

    Morin, K.A.; Cherry, J.A.

    1982-01-01

    An investigation of the movement of contaminated groundwater from inactive uranium tailings through a sand aquifer is being conducted at the Nordic Main tailings impoundment near Elliot Lake, Ontario. During 1979 and 1980, multilevel bundle-type piezometers were installed at several locations around the edge of the tailings impoundment. Chemical analysis of water samples from the bundle piezometers indicate that a major contaminant plume extends outward through a sand aquifer from the southeastern part of the Nordic Main impoundment dam. In the vincinity of the contaminant plume, the sand aquifer varies in thickness from about 9 to 15 m. The plume has two distinct segments, referred to as the inner core and the outer zone. The inner core, which has a pH of 4.3-5.0 and extends about 15 m from the foot of the tailings dam, contains several grams per litre of iron and sulfate, and tens of pCi/L of 226 Ra and 210 Pb. Water levels in piezometers within the inner core show that groundwater is moving horizontally, away from the tailings impoundment, with a velocity of up to several hundred metres per year. The outer zone, which extends a few hundred metres downgradient from the dam, is characterized by hundreds to thousands of milligrams per litre of iron and sulfate, less than 15pCi/L of 226 Ra, and a pH greater than 5.7. Comparison of 1979 and 1980 data shows that the front of the inner core is advancing a few metres per year, which is less than a few percent of the groundwater velocity. This retardation of movement of the inner core is caused by neutralization of the acidic water as a result of dissolution of calcium carbonate in the sand. With the rise in pH, precipitation of iron carbonate and possibly some iron hydroxide occurs and the contaminants of main concern such as 226 Ra, 210 Pb, and uranium are removed from solution by adsorption or coprecipitation

  9. CFD simulation of rotor aerodynamic performance when using additional surface structure array

    Science.gov (United States)

    Wang, Bing; Kong, Deyi

    2017-10-01

    The present work analyses the aerodynamic performance of the rotor with additional surface structure array in an attempt to maximize its performance in hover flight. The unstructured grids and the Reynolds Average Navier-Stokes equations were used to calculate the performance of the prototype rotor and the rotor with additional surface structure array in the air. The computational fluid dynamics software FLUENT was used to simulate the thrust of the rotors. The results of the calculations are in reasonable agreement with experimental data, which shows that the calculation model used in this work is useful in simulating the performance of the rotor with additional surface structure array. With this theoretical calculation model, the thrusts of the rotors with arrays of surface structure in three different shapes were calculated. According to the simulation results and the experimental data, the rotor with triangle surface structure array has better aerodynamic performance than the other rotors. In contrast with the prototype rotor, the thrust of the rotor with triangle surface structure array increases by 5.2% at the operating rotating speed of 3000r/min, and the additional triangle surface structure array has almost no influence on the efficiency of the rotor.

  10. Thermal performance enhancement of erythritol/carbon foam composites via surface modification of carbon foam

    Science.gov (United States)

    Li, Junfeng; Lu, Wu; Luo, Zhengping; Zeng, Yibing

    2017-03-01

    The thermal performance of the erythritol/carbon foam composites, including thermal diffusivity, thermal capacity, thermal conductivity and latent heat, were investigated via surface modification of carbon foam using hydrogen peroxide as oxider. It was found that the surface modification enhanced the wetting ability of carbon foam surface to the liquid erythritol of the carbon foam surface and promoted the increase of erythritol content in the erythritol/carbon foam composites. The dense interfaces were formed between erythritol and carbon foam, which is due to that the formation of oxygen functional groups C=O and C-OH on the carbon surface increased the surface polarity and reduced the interface resistance of carbon foam surface to the liquid erythritol. The latent heat of the erythritol/carbon foam composites increased from 202.0 to 217.2 J/g through surface modification of carbon foam. The thermal conductivity of the erythritol/carbon foam composite before and after surface modification further increased from 40.35 to 51.05 W/(m·K). The supercooling degree of erythritol also had a large decrease from 97 to 54 °C. Additionally, the simple and effective surface modification method of carbon foam provided an extendable way to enhance the thermal performances of the composites composed of carbon foams and PCMs.

  11. Influence of surface error on electromagnetic performance of reflectors based on Zernike polynomials

    Science.gov (United States)

    Li, Tuanjie; Shi, Jiachen; Tang, Yaqiong

    2018-04-01

    This paper investigates the influence of surface error distribution on the electromagnetic performance of antennas. The normalized Zernike polynomials are used to describe a smooth and continuous deformation surface. Based on the geometrical optics and piecewise linear fitting method, the electrical performance of reflector described by the Zernike polynomials is derived to reveal the relationship between surface error distribution and electromagnetic performance. Then the relation database between surface figure and electric performance is built for ideal and deformed surfaces to realize rapidly calculation of far-field electric performances. The simulation analysis of the influence of Zernike polynomials on the electrical properties for the axis-symmetrical reflector with the axial mode helical antenna as feed is further conducted to verify the correctness of the proposed method. Finally, the influence rules of surface error distribution on electromagnetic performance are summarized. The simulation results show that some terms of Zernike polynomials may decrease the amplitude of main lobe of antenna pattern, and some may reduce the pointing accuracy. This work extracts a new concept for reflector's shape adjustment in manufacturing process.

  12. Simulation and analysis on thermodynamic performance of surface water source heat pump system

    Institute of Scientific and Technical Information of China (English)

    Nan Lv; Qing Zhang; Zhenqian Chen; Dongsheng Wu

    2017-01-01

    This work established a thermodynamic performance model of a heat pump system containing a heat pump unit model, an air conditioning cooling and heating load calculation model, a heat exchanger model and a water pump performance model based on mass and energy balances. The thermodynamic performance of a surface water source heat pump air conditioning system was simulated and verified by comparing the simulation results to an actual engineering project. In addition, the effects of the surface water temperature, heat exchanger structure and surface water pipeline transportation system on the thermodynamic performance of the heat pump air conditioning system were analyzed. Under the simulated conditions in this paper with a cooling load of 3400 kW, the results showed that a 1 ℃ decrease in the surface water temperature leads to a 2.3 percent increase in the coefficient of performance; furthermore, an additional 100 m of length for the closed-loop surface water heat exchanger tube leads to a 0.08 percent increase in the coefficient of performance. To decrease the system energy consumption, the optimal working point should be specified according to the surface water transportation length.

  13. Indium-tin oxide surface treatments: Effects on the performance of liquid crystal devices

    International Nuclear Information System (INIS)

    Abderrahmen, A.; Romdhane, F.F.; Ben Ouada, H.; Gharbi, A.

    2006-01-01

    In this work, we investigate the effect of indium tin oxide (ITO) substrate cleaning on the surface properties. Wettability technique was used to measure the contact angle and the surface energy of the different treated ITO substrates. It is found that treatment with the methanol without dehydration gives the lowest water contact angle (most hydrophilic surface) and the highest surface energy compared to other solvents. This result was confirmed by impedance measurements performed on nematic liquid crystal cells with ITO electrodes. Indeed, we check the decrease of ionic entities in the interface ITO/liquid crystal. The polarity and dielectric parameters of the used solvents explain the obtained results

  14. Indium-tin oxide surface treatments: Effects on the performance of liquid crystal devices

    Energy Technology Data Exchange (ETDEWEB)

    Abderrahmen, A. [Laboratoire de physique et chimie des interfaces, Faculte des sciences, 5000, Monastir (Tunisia)]. E-mail: asma_abderrahmen@yahoo.fr; Romdhane, F.F. [Laboratoire de la matiere molle, Faculte des sciences, Tunis (Tunisia); Ben Ouada, H. [Laboratoire de physique et chimie des interfaces, Faculte des sciences, 5000, Monastir (Tunisia); Gharbi, A. [Laboratoire de la matiere molle, Faculte des sciences, Tunis (Tunisia)

    2006-03-15

    In this work, we investigate the effect of indium tin oxide (ITO) substrate cleaning on the surface properties. Wettability technique was used to measure the contact angle and the surface energy of the different treated ITO substrates. It is found that treatment with the methanol without dehydration gives the lowest water contact angle (most hydrophilic surface) and the highest surface energy compared to other solvents. This result was confirmed by impedance measurements performed on nematic liquid crystal cells with ITO electrodes. Indeed, we check the decrease of ionic entities in the interface ITO/liquid crystal. The polarity and dielectric parameters of the used solvents explain the obtained results.

  15. Development of measurement standards for verifying functional performance of surface texture measuring instruments

    Energy Technology Data Exchange (ETDEWEB)

    Fujii, A [Life and Industrial Product Development Department Olympus Corporation, 2951 Ishikawa-machi, Hachiouji-shi, Tokyo (Japan); Suzuki, H [Industrial Marketing and Planning Department Olympus Corporation, Shinjyuku Monolith, 3-1 Nishi-Shinjyuku 2-chome, Tokyo (Japan); Yanagi, K, E-mail: a_fujii@ot.olympus.co.jp [Department of Mechanical Engineering, Nagaoka University of Technology, 1603-1 Kamitomioka-machi, Nagaoka-shi, Niigata (Japan)

    2011-08-19

    A new measurement standard is proposed for verifying overall functional performance of surface texture measuring instruments. Its surface is composed of sinusoidal surface waveforms of chirp signals along horizontal cross sections of the material measure. One of the notable features is that the amplitude of each cycle in the chirp signal form is geometrically modulated so that the maximum slope is kept constant. The maximum slope of the chirp-like signal is gradually decreased according to movement in the lateral direction. We fabricated the measurement standard by FIB processing, and it was calibrated by AFM. We tried to evaluate the functional performance of Laser Scanning Microscope by this standard in terms of amplitude response with varying slope angles. As a result, it was concluded that the proposed standard can easily evaluate the performance of surface texture measuring instruments.

  16. Microcrustaceans (Branchipoda and Copepoda) of Wetland Impoundments on the Savannah River Site, Aiken, South Carolina

    Energy Technology Data Exchange (ETDEWEB)

    DeBiase, Adrienne E; Taylor, Barbara E

    2005-09-21

    The United States Department of Energy’s Savannah River Site (SRS) in Aiken, Allendale, and Barnwell Counties, South Carolina, contains an abundance of freshwater wetlands and impoundments. Four large impoundments, as well as several small, abandoned farm and mill ponds, and about 400 Carolina bays and other small, isolated depression wetland ponds are located within the 893 km2 area of the SRS. Crustaceans of the orders Branchiopoda and Copepoda are nearly ubiquitous in these water bodies. Although small in size, these organisms are often very abundant. They consequently play an important trophic role in freshwater food webs supporting fish, larval salamanders, larval insects, and numerous other animals, aquatic and terrestrial. This report provides an introduction to the free-living microcrustaceans of lentic water bodies on the SRS and a comprehensive list of species known to occur there. Occurrence patterns are summarized from three extensive survey studies, supplemented with other published and unpublished records. In lieu of a key, we provide a guide to taxonomic resources and notes on undescribed species. Taxa covered include the orders Cladocera, Anostraca, Laevicaudata, and Spinicaudata of the Subclass Branchiopoda and the Superorders Calanoida and Cyclopoida of Subclass Copepoda. Microcrustaceans of the Superorder Harpacticoida of the Subclass Copepoda and Subclass Ostracoda are also often present in lentic water bodies. They are excluded from this report because they have not received much study at the species level on the SRS.

  17. Evaluation of Breaking Performance in Vibration-Assisted Electrostatic Surface Induction Actuator

    DEFF Research Database (Denmark)

    Nemoto, Takeru; Zsurzsan, Tiberiu-Gabriel; Yamamoto, Akio

    2015-01-01

    This paper evaluates breaking performance of an electrostatic surface induction actuator. The actuator is equipped with piezoelectric vibrator such that the friction between the slider and the stator electrodes can be dramatically reduced by squeeze-film effect. In such an actuator, the friction...... conditions. The result clearly shows the effect of friction change in breaking performance of the actuator....

  18. Effects of dimensional size and surface roughness on service performance for a micro Laval nozzle

    International Nuclear Information System (INIS)

    Cai, Yukui; Liu, Zhanqiang; Shi, Zhenyu

    2017-01-01

    Nozzles with large and small dimensions are widely used in various industries. The main objective of this research is to investigate the effects of dimensional size and surface roughness on the service performance of a micro Laval nozzle. The variation of nozzle service performance from the conventional macro to micro scale is presented in this paper. This shows that the dimensional nozzle size has a serious effect on the nozzle gas flow friction. With the decrease of nozzle size, the velocity performance and thrust performance deteriorate. The micro nozzle performance has less sensitivity to the variation of surface roughness than the large scale nozzle does. Surface quality improvement and burr prevention technologies are proposed to reduce the friction effect on the micro nozzle performance. A novel process is then developed to control and depress the burr generation during micro nozzle machining. The polymethyl-methacrylate as a coating material is coated on the rough machined surface before finish machining. Finally, the micro nozzle with a throat diameter of 1 mm is machined successfully. Thrust test results show that the implement and application of this machining process benefit the service performance improvement of the micro nozzle. (paper)

  19. Imaging performance of annular apertures. VI - Limitations by optical surface deviations

    Science.gov (United States)

    Tschunko, Hubert F. A.

    1987-01-01

    The performance of optical systems is limited by imperfect optical surfaces that degrade the images below the level set by wave theoretical limits. The central irradiance functions are derived for slit and circular apertures with five distributions of wavefront errors and for a range of maximal wavefront deviations. For practical frequency of occurrence distributions of wavefront deviations, the point spread and the image energy integral functions are determined. Practical performances of optical systems are derived and performance limits discussed.

  20. Surface Modification of MXenes: A Pathway to Improve MXene Electrode Performance in Electrochemical Energy Storage Devices

    KAUST Repository

    Ahmed, Bilal

    2017-12-31

    The recent discovery of layered transition metal carbides (MXenes) is one of the most important developments in two-dimensional (2D) materials. Preliminary theoretical and experimental studies suggest a wide range of potential applications for MXenes. The MXenes are prepared by chemically etching ‘A’-layer element from layered ternary metal carbides, nitrides and carbonitrides (MAX phases) through aqueous acid treatment, which results in various surface terminations such as hydroxyl, oxygen or fluorine. It has been found that surface terminations play a critical role in defining MXene properties and affects MXene performance in different applications such as electrochemical energy storage, electromagnetic interference shielding, water purification, sensors and catalysis. Also, the electronic, thermoelectric, structural, plasmonic and optical properties of MXenes largely depend upon surface terminations. Thus, controlling the surface chemistry if MXenes can be an efficient way to improve their properties. This research mainly aims to perform surface modifications of two commonly studied MXenes; Ti2C and Ti3C2, via chemical, thermal or physical processes to enhance electrochemical energy storage properties. The as-prepared and surface modified MXenes have been studied as electrode materials in Li-ion batteries (LIBs) and supercapacitors (SCs). In pursuit of desirable MXene surface, we have developed an in-situ room temperature oxidation process, which resulted in TiO2/MXene nanocomposite and enhanced Li-ion storage. The idea of making metal oxide and MXene nanocomposites was taken to the next level by combining a high capacity anode materials – SnO2 – and MXene. By taking advantage of already existing surface functional groups (–OH), we have developed a composite of SnO2/MXene by atomic layer deposition (ALD) which showed enhanced capacity and excellent cyclic stability. Thermal annealing of MXene at elevated temperature under different atmospheres was

  1. Use of special oedometer tests for the remediation of large uranium mill tailings impoundments at Wismut, Germany

    International Nuclear Information System (INIS)

    Barnekow, U.; Paul, M.

    2002-01-01

    The paper presents the use of recently developed special oedometer tests for designing the remediation of large uranium tailings ponds at WISMUT, Germany. Uranium ore mining and milling in eastern Germany by the former Soviet-German WISMUT company lasted from 1946 to 1990. Wastes from the hydrometallurgical uranium extraction processes were discharged into large tailings impoundments covering a total area of 5.5 km 2 and containing about 150 x 10 6 m 3 of uranium mill tailings. Tailings pond remediation is ongoing by in-place decommissioning with dewatering by technical means. Geotechnical properties and the most suitable so-called non-linear finite strain consolidation behaviour of fine uranium mill tailings are described. Decommissioning techniques comprise, among others, interim covering of under consolidated fine tailings, contouring of tailings surfaces and final covering. Contouring, in particular, has a huge potential for optimization in terms of cost reduction. For contouring total settlement portions, the spatial distribution of differential settlement portions and the time-dependent settlement rates, especially of the cohesive fine uranium mill tailings are of critical importance. A new special oedometer KD 314 S has been developed to generate all the input data needed to derive the fundamental geotechnical relationships of void ratio vs. effective stress and of permeability coefficient vs. void ratio for consolidation calculations. Since December 1999 the new special oedometer KD 314 S has been working successfully on fine uranium mill tailings from both acid and from soda alkaline milling. Results coincide with non-linear finite strain consolidation theory. The geotechnical functions derived were used as input parameters for consolidation modelling. An example of the consolidation modelling on Helmsdorf tailings pond is presented. (author)

  2. Density Functional Theory Study of Leaching Performance of Different Acids on Pyrochlore (100) Surface

    Science.gov (United States)

    Yang, Xiuli; Fang, Qing; Ouyang, Hui

    2018-06-01

    Pyrochlore leaching using hydrofluoric, sulfuric, and hydrochloric acids has been studied via experimental methods for years, but the interactions between niobium atoms on the pyrochlore surface and different acids have not been investigated. In this work, first-principles calculations based on density functional theory were used to elucidate the leaching performance of these three acids from the viewpoint of geometrical and electronic structures. The calculation results indicate that sulfate, chloride, and fluoride anions influence the geometric structure of pyrochlore (100) to different extents, decreasing in the order: sulfate, fluoride, chloride. Orbitals of O1 and O2 atoms of sulfate hybridized with those of surface niobium atom. Fluorine orbitals hybridized with those of surface niobium atoms. However, no obvious overlap exists between any orbitals of chlorine and surface niobium, revealing that chlorine does not interact chemically with surface niobium atoms.

  3. Dual-band frequency selective surface with large band separation and stable performance

    International Nuclear Information System (INIS)

    Zhou Hang; Qu Shao-Bo; Lin Bao-Qin; Wang Jia-Fu; Ma Hua; Zhang Jie-Qiu; Peng Wei-Dong; Bai Peng; Wang Xu-Hua; Xu Zhuo

    2012-01-01

    A new technique of designing a dual-band frequency selective surface with large band separation is presented. This technique is based on a delicately designed topology of L- and Ku-band microwave filters. The two band-pass responses are generated by a capacitively-loaded square-loop frequency selective surface and an aperture-coupled frequency selective surface, respectively. A Faraday cage is located between the two frequency selective surface structures to eliminate undesired couplings. Based on this technique, a dual-band frequency selective surface with large band separation is designed, which possesses large band separation, high selectivity, and stable performance under various incident angles and different polarizations. (electromagnetism, optics, acoustics, heat transfer, classical mechanics, and fluid dynamics)

  4. Enhancing the antibacterial performance of orthopaedic implant materials by fibre laser surface engineering

    DEFF Research Database (Denmark)

    Chan, Chi-Wai; Carson, Louise; Smith, Graham C.

    2017-01-01

    to the effort on enhancing osseointegration, wear and corrosion resistance of implant materials. In this study, the effects of laser surface treatment on enhancing the antibacterial properties of commercially pure (CP) Ti (Grade 2), Ti6Al4V (Grade 5) and CoCrMo alloy implant materials were studied and compared...... for the first time. Laser surface treatment was performed by a continuous wave (CW) fibre laser with a near-infrared wavelength of 1064 nm in a nitrogen-containing environment. Staphylococcus aureus, commonly implicated in infection associated with orthopaedic implants, was used to investigate the antibacterial...... properties of the laser-treated surfaces. The surface roughness and topography of the laser-treated materials were analysed by a 2D roughness testing and by AFM. The surface morphologies before and after 24 h of bacterial cell culture were captured by SEM, and bacterial viability was determined using live...

  5. The Effects of Surface Waves and Submergence on the Performance and Loading of a Tidal Turbine

    OpenAIRE

    Guo, Xiaoxian; Gao, Zhen; Yang, Jianmin; Moan, Torgeir; Lu, Haining; Li, Xin; Lu, Wenyue

    2017-01-01

    Tidal energy has the advantages of high predictability, high energy density, and limited environmental impacts. As tidal turbines are expected to be used in the most energetic waters where there might be significant waves, the assessment of unsteady hydrodynamic load due to surface waves is of great concern. The objective of this paper is to assess the effects of surface waves and submergence of the turbine on the power performance and loads of a tidal turbine by experimental approach. The ex...

  6. Durability and Mechanical Performance of PMMA/Stone Sludge Nanocomposites for Acrylic Solid Surface Applications

    Directory of Open Access Journals (Sweden)

    Samah EL-Bashir

    2017-11-01

    Full Text Available Acrylic solid surface sheets were prepared by mixing different kinds of stone sludge fillers (SSF in Poly (methyl methacrylate (PMMA nanocomposites. PMMA nanocomposite syrups were made using free radical polymerization of methylmethacrylate (MMA, then two kinds of nanofillers were added, namely, hydrophilic nanosilica and clay Halloysite nanotubules (HNTs. Acrylic solid surface sheets were manufactured by mixing the syrups with SSFs. The morphology of the produced sheets was studied using optical, and Scanning Electron Microscopy (SEM that revealed the uniform distribution of stone sludge in the polymeric matrix. The study of the physical properties showed promising mechanical performance and durability of PMMA/SSF nanocomposites for acrylic solid surface applications.

  7. Research on Fiber Micro-Surfacing Mixture Design and Pavement Performance in Interchange’s Connections

    OpenAIRE

    Wu Zhaoyang

    2015-01-01

    In order to use the micro-surfacing which is the existing micro-surfacing technology guide that has some technical defects, the method to determine the optimal dosage of emulsified asphalt and best whetstone is not very reasonable, and it impedes the application and development of micro-surfacing technology to improve the performance of the pavement. In this paper, the “graphical method” is first used to determine the optimal dosage range of emulsified asphalt. Nowadays, a large number of exp...

  8. The Plumbing of Land Surface Models: Is Poor Performance a Result of Methodology or Data Quality?

    Science.gov (United States)

    Haughton, Ned; Abramowitz, Gab; Pitman, Andy J.; Or, Dani; Best, Martin J.; Johnson, Helen R.; Balsamo, Gianpaolo; Boone, Aaron; Cuntz, Matthais; Decharme, Bertrand; hide

    2016-01-01

    The PALS Land sUrface Model Benchmarking Evaluation pRoject (PLUMBER) illustrated the value of prescribing a priori performance targets in model intercomparisons. It showed that the performance of turbulent energy flux predictions from different land surface models, at a broad range of flux tower sites using common evaluation metrics, was on average worse than relatively simple empirical models. For sensible heat fluxes, all land surface models were outperformed by a linear regression against downward shortwave radiation. For latent heat flux, all land surface models were outperformed by a regression against downward shortwave, surface air temperature and relative humidity. These results are explored here in greater detail and possible causes are investigated. We examine whether particular metrics or sites unduly influence the collated results, whether results change according to time-scale aggregation and whether a lack of energy conservation in fluxtower data gives the empirical models an unfair advantage in the intercomparison. We demonstrate that energy conservation in the observational data is not responsible for these results. We also show that the partitioning between sensible and latent heat fluxes in LSMs, rather than the calculation of available energy, is the cause of the original findings. Finally, we present evidence suggesting that the nature of this partitioning problem is likely shared among all contributing LSMs. While we do not find a single candidate explanation forwhy land surface models perform poorly relative to empirical benchmarks in PLUMBER, we do exclude multiple possible explanations and provide guidance on where future research should focus.

  9. Numerical simulation of unsteady free surface flow and dynamic performance for a Pelton turbine

    International Nuclear Information System (INIS)

    Xiao, Y X; Wang, Z W; Yan, Z G; Cui, T

    2012-01-01

    Different from the reaction turbines, the hydraulic performance of the Pelton turbine is dynamic due to the unsteady free surface flow in the rotating buckets in time and space. This paper aims to present the results of investigations conducted on the free surface flow in a Pelton turbine rotating buckets. The unsteady numerical simulations were performed with the CFX code by using the Realizable k-ε turbulence model coupling the two-phase flow volume of fluid method. The unsteady free surface flow patterns and torque varying with the bucket rotating were analysed. The predicted relative performance at five operating conditions was compared with the field test results. The study was also conducted the interactions between the bucket rear and the water jet.

  10. Numerical simulation of unsteady free surface flow and dynamic performance for a Pelton turbine

    Science.gov (United States)

    Xiao, Y. X.; Cui, T.; Wang, Z. W.; Yan, Z. G.

    2012-11-01

    Different from the reaction turbines, the hydraulic performance of the Pelton turbine is dynamic due to the unsteady free surface flow in the rotating buckets in time and space. This paper aims to present the results of investigations conducted on the free surface flow in a Pelton turbine rotating buckets. The unsteady numerical simulations were performed with the CFX code by using the Realizable k-ε turbulence model coupling the two-phase flow volume of fluid method. The unsteady free surface flow patterns and torque varying with the bucket rotating were analysed. The predicted relative performance at five operating conditions was compared with the field test results. The study was also conducted the interactions between the bucket rear and the water jet.

  11. The use of artificial impoundments by two amphibian species in the Delaware Water Gap National Recreation Area

    Science.gov (United States)

    Julian, J.T.; Snyder, C.D.; Young, J.A.

    2006-01-01

    We compared breeding activity of Ambystoma maculatum (Spotted Salamander) and Rana sylvatica (Wood Frog) in artificial impoundments to patterns in natural wetlands over a three-year period in the Delaware Water Gap National Recreation Area. Rana sylvatica were 5.6 times more likely to use natural bodies of water for breeding than artificial impoundments, while A. maculatum were 2.7 times more likely to use natural bodies of water. Both species were approximately 9 times more likely to breed in fishless bodies of water than in waters with predatory fish. Ambystoma maculatum were 6 times more likely to breed in wetlands with more stable seasonal hydroperiods, while R. sylvatica were only 2 times more likely to do so. We conclude that the high likelihood of fish presence in impoundments was the primary explanation for why both species were less likely to use impoundments than natural wetlands, while the tendency of A. maculatum to avoid natural wetlands with shorter hydroperiods explained why differences in use between pond types was more pronounced for R. sylvatica.

  12. Influence of the surface structure on the filtration performance of UV-modified PES membranes

    DEFF Research Database (Denmark)

    Kæselev, Bozena Alicja; Kingshott, P.; Jonsson, Gunnar Eigil

    2002-01-01

    chemically characterised using X-ray photoelectron spectroscopy (XPS) and time of flight-static secondary ion mass spectrometry (TOF-static SIMS). The filtration performance of irradiated/non-modified and irradiated/modified membranes was examined in a crossflow cell, using a dextran solution. The filtration...... in relation to dextran when compared to membranes modified by AAG and AAP. This work suggests that the structure of the presence of grafted chains seems to be responsible for the observed changes to filtration performance of the modified membrane. Surface analysis supports the claim that the specific surface...

  13. The New Horizons Radio Science Experiment: Expected Performance in Measurements of Pluto's Atmospheric Structure, Surface Pressure, and Surface Temperature

    Science.gov (United States)

    Hinson, D. P.; Linscott, I.; Woods, W. W.; Tyler, G. L.; Bird, M. K.; Paetzold, M.; Strobel, D. F.

    2014-12-01

    The New Horizons (NH) payload includes a Radio Science Experiment (REX) for investigating key characteristics of Pluto and Charon during the upcoming flyby in July 2015. REX flight equipment augments the NH radio transceiver used for spacecraft communications and tracking. The REX hardware implementation requires 1.6 W and 160 g. This presentation will focus on the final design and the predicted performance of two high-priority observations. First, REX will receive signals from a pair of 70-m antennas on Earth - each transmitting 20 kW at 4.2-cm wavelength - during a diametric radio occultation by Pluto. The data recorded by REX will reveal the surface pressure, the temperature structure of the lower atmosphere, and the surface radius. Second, REX will measure the thermal emission from Pluto at 4.2-cm wavelength during two linear scans across the disk at close range when both the dayside and the nightside are visible, allowing the surface temperature and its spatial variations to be determined. Both scans extend from limb to limb with a resolution of about 10 pixels; one bisects Pluto whereas the second crosses the winter pole. We will illustrate the capabilities of REX by reviewing the method of analysis and the precision achieved in a lunar occultation observed by New Horizons in May 2011. Re-analysis of radio occultation measurements by Voyager 2 at Triton is also under way. More generally, REX objectives include a radio occultation search for Pluto's ionosphere; examination of Charon through both radio occultation and radiometry; a search for a radar echo from Pluto's surface; and improved knowledge of the Pluto system mass and the Pluto-Charon mass ratio from a combination of two-way and one-way Doppler frequency measurements.

  14. Material Surface Characteristics and Plasma Performance in the Lithium Tokamak Experiment

    Science.gov (United States)

    Lucia, Matthew James

    The performance of a tokamak plasma and the characteristics of the surrounding plasma facing component (PFC) material surfaces strongly influence each other. Despite this relationship, tokamak plasma physics has historically been studied more thoroughly than PFC surface physics. The disparity is particularly evident in lithium PFC research: decades of experiments have examined the effect of lithium PFCs on plasma performance, but the understanding of the lithium surface itself is much less complete. This latter information is critical to identifying the mechanisms by which lithium PFCs affect plasma performance. This research focused on such plasma-surface interactions in the Lithium Tokamak Experiment (LTX), a spherical torus designed to accommodate solid or liquid lithium as the primary PFC. Surface analysis was accomplished via the novel Materials Analysis and Particle Probe (MAPP) diagnostic system. In a series of experiments on LTX, the MAPP x-ray photoelectron spectroscopy (XPS) and thermal desorption spectroscopy (TDS) capabilities were used for in vacuo interrogation of PFC samples. This represented the first application of XPS and TDS for in situ surface analysis of tokamak PFCs. Surface analysis indicated that the thin (dLi ˜ 100nm) evaporative lithium PFC coatings in LTX were converted to Li2O due to oxidizing agents in both the residual vacuum and the PFC substrate. Conversion was rapid and nearly independent of PFC temperature, forming a majority Li2O surface within minutes and an entirely Li2O surface within hours. However, Li2O PFCs were still capable of retaining hydrogen and sequestering impurities until the Li2 O was further oxidized to LiOH, a process that took weeks. For hydrogen retention, Li2O PFCs retained H+ from LTX plasma discharges, but no LiH formation was observed. Instead, results implied that H+ was only weakly-bound, such that it almost completely outgassed as H 2 within minutes. For impurity sequestration, LTX plasma performance

  15. Boiling performance and material robustness of modified surfaces with multi scale structures for fuel cladding development

    Energy Technology Data Exchange (ETDEWEB)

    Jo, HangJin; Kim, Jin Man [Division of Advanced Nuclear Engineering, POSTECH, Pohang 790-784, Gyungbuk (Korea, Republic of); Yeom, Hwasung [Department of Nuclear Engineering and Engineering physics, UW-Madison, Madison, WI 53706, Unities States (United States); Lee, Gi Cheol [Department of Mechanical Engineering, POSTECH, Pohang 790-784, Gyungbuk (Korea, Republic of); Park, Hyun Sun, E-mail: hejsunny@postech.ac.kr [Division of Advanced Nuclear Engineering, POSTECH, Pohang 790-784, Gyungbuk (Korea, Republic of); Kiyofumi, Moriyama; Kim, Moo Hwan [Division of Advanced Nuclear Engineering, POSTECH, Pohang 790-784, Gyungbuk (Korea, Republic of); Sridharan, Kumar; Corradini, Michael [Department of Nuclear Engineering and Engineering physics, UW-Madison, Madison, WI 53706, Unities States (United States)

    2015-09-15

    Highlights: • We improved boiling performance and material robustness using surface modification. • We combined micro/millimeter post structures and nanoparticles with heat treatments. • Compactly-arranged micrometer posts had improved boiling performance. • CHF increased significantly due to capillary pumping by the deposited NP layers. • Sintering procedure increased mechanical strength of the NP coating surface. - Abstract: By regulating the geometrical characteristics of multi-scale structures and by adopting heat treatment for protective layer of nanoparticles (NPs), we improved critical heat flux (CHF), boiling heat transfer (BHT), and mechanical robustness of the modified surface. We fabricated 1-mm and 100-μm post structures and deposited NPs on the structured surface as a nano-scale structured layer and protective layer at the same time, then evaluated the CHF and BHT and material robustness of the modified surfaces. On the structured surfaces without NPs, the surface with compactly-arranged micrometer posts had improved CHF (118%) and BHT (41%). On the surface with structures on which NPs had been deposited, CHF increased significantly (172%) due to capillary pumping by the deposited NP layers. The heat treatment improved robustness of coating layer in comparison to the one of before heat treatment. In particular, low-temperature sintering increased the hardness of the modified surface by 140%. The increased mechanical strength of the NP coating is attributed to reduction in coating porosity during sintering. The combination of micrometer posts structures and sintered NP coating can increase the safety, efficiency and reliability of advanced nuclear fuel cladding.

  16. Boiling performance and material robustness of modified surfaces with multi scale structures for fuel cladding development

    International Nuclear Information System (INIS)

    Jo, HangJin; Kim, Jin Man; Yeom, Hwasung; Lee, Gi Cheol; Park, Hyun Sun; Kiyofumi, Moriyama; Kim, Moo Hwan; Sridharan, Kumar; Corradini, Michael

    2015-01-01

    Highlights: • We improved boiling performance and material robustness using surface modification. • We combined micro/millimeter post structures and nanoparticles with heat treatments. • Compactly-arranged micrometer posts had improved boiling performance. • CHF increased significantly due to capillary pumping by the deposited NP layers. • Sintering procedure increased mechanical strength of the NP coating surface. - Abstract: By regulating the geometrical characteristics of multi-scale structures and by adopting heat treatment for protective layer of nanoparticles (NPs), we improved critical heat flux (CHF), boiling heat transfer (BHT), and mechanical robustness of the modified surface. We fabricated 1-mm and 100-μm post structures and deposited NPs on the structured surface as a nano-scale structured layer and protective layer at the same time, then evaluated the CHF and BHT and material robustness of the modified surfaces. On the structured surfaces without NPs, the surface with compactly-arranged micrometer posts had improved CHF (118%) and BHT (41%). On the surface with structures on which NPs had been deposited, CHF increased significantly (172%) due to capillary pumping by the deposited NP layers. The heat treatment improved robustness of coating layer in comparison to the one of before heat treatment. In particular, low-temperature sintering increased the hardness of the modified surface by 140%. The increased mechanical strength of the NP coating is attributed to reduction in coating porosity during sintering. The combination of micrometer posts structures and sintered NP coating can increase the safety, efficiency and reliability of advanced nuclear fuel cladding

  17. An in situ vapour phase hydrothermal surface doping approach for fabrication of high performance Co3O4 electrocatalysts with an exceptionally high S-doped active surface.

    Science.gov (United States)

    Tan, Zhijin; Liu, Porun; Zhang, Haimin; Wang, Yun; Al-Mamun, Mohammad; Yang, Hua Gui; Wang, Dan; Tang, Zhiyong; Zhao, Huijun

    2015-04-04

    A facile in situ vapour phase hydrothermal (VPH) surface doping approach has been developed for fabrication of high performance S-doped Co3O4 electrocatalysts with an unprecedentedly high surface S content (>47%). The demonstrated VPH doping approach could be useful for enrichment of surface active sites for other metal oxide electrocatalysts.

  18. Research on Fiber Micro-Surfacing Mixture Design and Pavement Performance in Interchange’s Connections

    Directory of Open Access Journals (Sweden)

    Wu Zhaoyang

    2015-01-01

    Full Text Available In order to use the micro-surfacing which is the existing micro-surfacing technology guide that has some technical defects, the method to determine the optimal dosage of emulsified asphalt and best whetstone is not very reasonable, and it impedes the application and development of micro-surfacing technology to improve the performance of the pavement. In this paper, the “graphical method” is first used to determine the optimal dosage range of emulsified asphalt. Nowadays, a large number of expressways reach the stage of repair and maintenance. Interchange ramp exit and entrance are always the accident-prone sections and, it’s easy to over-look the pavement’s skid resistance of those areas. Micro-surfacing can significantly improve the performance of pavement, especially the skid resistance. Verified with laboratory tests, it recommends that the dosage of emulsified asphalt corresponding to the peak of flexural strain measured with low temperature bending test as OAC of micro-surfacing mixture shows technical superiority. The use of fiber micro-surfacing at the ramp’s exit and entrance can reduce the braking distance.

  19. Analysis of spatial distribution and inventory of radioactivity within the uranium mill tailings impoundment

    Directory of Open Access Journals (Sweden)

    D. O. Bugai

    2015-10-01

    Full Text Available Results are presented of the characterization of radioactivity inventory of Zapadnoe uranium mill tailings impoundment situated at Pridneprovsky Chemical Plant (PChP; Dneprodzerzhinsk, Ukraine. Analyses of radioactivity data set based on analytical studies of core material from 15 characterization boreholes allowed significantly refining waste volume and radioactivity inventory estimates. Geostatistical analyses using variogram function have established that radioactivity distribution in Zapadnoe tailings is characterized by regular spatial correlation patterns. Ordinary kriging method was applied to assess distribution of radioactivity in 3D. Results of statistical analyses suggest significant redistribution of uranium in the dissolved form in the residues (presumably due to water infiltration process. The developed structural model for radioactivity distribution is used for further risk assessment analyses. Derived radioactivity correlation scales can be used for optimization of sample collection when characterizing the PChP Site and similar contaminated sites elsewhere.

  20. Chlorophyll Detection and Mapping of Shallow Water Impoundments Using Image Spectrometry

    International Nuclear Information System (INIS)

    Artigas, F.; Pechmann, I.; Marti, A.; Yao, N.; Pechmann, I.

    2008-01-01

    There exists a common perception that chlorophyll a concentrations in tidal coastal waters are unsuitable to be captured by remote sensing techniques because of high water turbidity. In this study, we use band index measurements to separate active chlorophyll pigments from other constituents in the water. Published single- and multiband spectral indices are used to establish a relationship between algal chlorophyll concentration and reflectance data. We find an index which is suitable to map chlorophyll gradients in the impoundments, ditches, and associated waterways of the Hackensack Meadow lands (NJ, USA). The resulting images clearly depict the spatial distribution of plant pigments and their relationship with the biological conditions of the waters in the estuary. Since these biological conditions are often determined by land usage, the methods in this paper provide a simple tool to address water quality management issues in fragmented urban estuaries.

  1. Effects of hydrologic variables on rock riprap design for uranium tailings impoundments

    International Nuclear Information System (INIS)

    Walters, W.H.; Skaggs, R.L.

    1985-01-01

    Pacific Northwest Laboratory is studying the mitigation of erosion of earthen radon suppression covers for uranium tailings impoundments. Because the covers will require erosion protection for upwards of 1000 years, rock riprap (armoring) has been proposed as the primary protection method. This study investigates the sensitivity of riprap design procedures to extreme flood events that can generate high flow velocities and shear stresses. The study uses two decommissioned tailings sites (Grand Junction and Slick Rock, Colorado) as case studies to evaluate the sensitivity of design rock size with respect to variables such as flood discharge, side slope, specific gravity, safety factor, and channel roughness. The results indicate that design rock size can vary significantly for different design procedures. Other significant results indicate that embankment side slopes of about 4H:1V are optimum for rock riprap and that the use of rock material with specific gravities less than about 2.50 may prove too costly

  2. A model for evaluating effects of climate, water availability, and water management on wetland impoundments--a case study on Bowdoin, Long Lake, and Sand Lake National Wildlife Refuges

    Science.gov (United States)

    Tangen, Brian A.; Gleason, Robert A.; Stamm, John F.

    2013-01-01

    Many wetland impoundments managed by the U.S. Fish and Wildlife Service (USFWS) National Wildlife Refuge System throughout the northern Great Plains rely on rivers as a primary water source. A large number of these impoundments currently are being stressed from changes in water supplies and quality, and these problems are forecast to worsen because of projected changes to climate and land use. For example, many managed wetlands in arid regions have become degraded owing to the long-term accumulation of salts and increased salinity associated with evapotranspiration. A primary goal of the USFWS is to provide aquatic habitats for a diversity of waterbirds; thus, wetland managers would benefit from a tool that facilitates evaluation of wetland habitat quality in response to current and anticipated impacts of altered hydrology and salt balances caused by factors such as climate change, water availability, and management actions. A spreadsheet model that simulates the overall water and salinity balance (WSB model) of managed wetland impoundments is presented. The WSB model depicts various habitat metrics, such as water depth, salinity, and surface areas (inundated, dry), which can be used to evaluate alternative management actions under various water-availability and climate scenarios. The WSB model uses widely available spreadsheet software, is relatively simple to use, relies on widely available inputs, and is readily adaptable to specific locations. The WSB model was validated using data from three National Wildlife Refuges with direct and indirect connections to water resources associated with rivers, and common data limitations are highlighted. The WSB model also was used to conduct simulations based on hypothetical climate and management scenarios to demonstrate the utility of the model for evaluating alternative management strategies and climate futures. The WSB model worked well across a range of National Wildlife Refuges and could be a valuable tool for USFWS

  3. Fishers' knowledge identifies environmental changes and fish abundance trends in impounded tropical rivers.

    Science.gov (United States)

    Hallwass, Gustavo; Lopes, Priscila F; Juras, Anastácio A; Silvano, Renato A M

    2013-03-01

    The long-term impacts of large hydroelectric dams on small-scale fisheries in tropical rivers are poorly known. A promising way to investigate such impacts is to compare and integrate the local ecological knowledge (LEK) of resource users with biological data for the same region. We analyzed the accuracy of fishers' LEK to investigate fisheries dynamics and environmental changes in the Lower Tocantins River (Brazilian Amazon) downstream from a large dam. We estimated fishers' LEK through interviews with 300 fishers in nine villages and collected data on 601 fish landings in five of these villages, 22 years after the dam's establishment (2006-2008). We compared these two databases with each other and with data on fish landings from before the dam's establishment (1981) gathered from the literature. The data obtained based on the fishers' LEK (interviews) and from fisheries agreed regarding the primary fish species caught, the most commonly used type of fishing gear (gill nets) and even the most often used gill net mesh sizes but disagreed regarding seasonal fish abundance. According to the interviewed fishers, the primary environmental changes that occurred after the impoundment were an overall decrease in fish abundance, an increase in the abundance of some fish species and, possibly, the local extinction of a commercial fish species (Semaprochilodus brama). These changes were corroborated by comparing fish landings sampled before and 22 years after the impoundment, which indicated changes in the composition of fish landings and a decrease in the total annual fish production. Our results reinforce the hypothesis that large dams may adversely affect small-scale fisheries downstream and establish a feasible approach for applying fishers' LEK to fisheries management, especially in regions with a low research capacity.

  4. Biofouling behavior and performance of forward osmosis membranes with bioinspired surface modification in osmotic membrane bioreactor.

    Science.gov (United States)

    Li, Fang; Cheng, Qianxun; Tian, Qing; Yang, Bo; Chen, Qianyuan

    2016-07-01

    Forward osmosis (FO) has received considerable interest for water and energy related applications in recent years. Biofouling behavior and performance of cellulose triacetate (CTA) forward osmosis membranes with bioinspired surface modification via polydopamine (PD) coating and poly (ethylene glycol) (PEG) grafting (PD-g-PEG) in a submerged osmotic membrane bioreactor (OMBR) were investigated in this work. The modified membranes exhibited lower flux decline than the pristine one in OMBR, confirming that the bioinspired surface modification improved the antifouling ability of the CTA FO membrane. The result showed that the decline of membrane flux related to the increase of the salinity and MLSS concentration of the mixed liquid. It was concluded that the antifouling ability of modified membranes ascribed to the change of surface morphology in addition to the improvement of membrane hydrophilicity. The bioinspired surface modifications might improve the anti-adhesion for the biopolymers and biocake. Copyright © 2016 Elsevier Ltd. All rights reserved.

  5. Yeast cell surface display: An efficient strategy for improvement of bioethanol fermentation performance.

    Science.gov (United States)

    Chen, Xianzhong

    2017-03-04

    The cell surface serves as a functional interface between the inside and the outside of the cell. Within the past 20 y the ability of yeast (Saccharomyces cerevisiae) to display heterologous proteins on the cell surface has been demonstrated. Furthermore, S. cerevisiae has been both developed and applied in expression of various proteins on the cell surface. Using this novel and useful strategy, proteins and peptides of various kinds can be displayed on the yeast cell surface by fusing the protein of interest with the glycosylphosphatidylinositol (GPI)-anchoring system. Consolidated bioprocessing (CBP) using S. cerevisiae represents a promising technology for bioethanol production. However, further work is needed to improve the fermentation performance. There is some excellent previous research regarding construction of yeast biocatalyst using the surface display system to decrease cost, increase efficiency of ethanol production and directly utilize starch or biomass for fuel production. In this commentary, we reviewed the yeast surface display system and highlighted recent work. Additionally, the strategy for decrease of phytate phosphate content in dried distillers grains with solubles (DDGS) by display of phytase on the yeast cell surface is discussed.

  6. Fabrication and characterization of stable superhydrophobic surface with good friction-reducing performance on Al foil

    Energy Technology Data Exchange (ETDEWEB)

    Li, Peipei [Key Laboratory of Ministry of Education for Special Functional Materials, Henan University, Kaifeng 475004 (China); Chen, Xinhua, E-mail: xuc0374@hotmail.com [College of Chemistry and Chemical Engineering, Xuchang University, Xuchang 461000 (China); Yang, Guangbin; Yu, Laigui [Key Laboratory of Ministry of Education for Special Functional Materials, Henan University, Kaifeng 475004 (China); Zhang, Pingyu, E-mail: pingyu@henu.edu.cn [Key Laboratory of Ministry of Education for Special Functional Materials, Henan University, Kaifeng 475004 (China)

    2014-05-01

    Graphical abstract: A lotus-leaf-like hierarchical structure was successfully created on Al foil by a facile three-step solution–immersion method. As-obtained etched-immersed Al/STA rough surface contains interconnected convex–concave micro-structure and uniformly distributed nano-sheets that endow the surface with excellent superhydrophobicity (WCA: 164.2°; WSA: below 5°). Besides, the as-prepared etched-immersed Al/STA superhydrophobic surface on Al foil exhibits good friction-reducing ability and stable superhydrophobicity. - Highlights: • A stable superhydrophobic surface was created on aluminum foil by a facile three-step solution–immersion method. • A lotus-leaf-like hierarchical structure consists of interconnected convex–concave micro-structure and uniformly distributed nano-sheets has been constructed on the aluminum surface. • The superhydrophobic surfaces on aluminum substrate showing effective friction-reducing performance and self-cleaning ability. - Abstract: A lotus-leaf-like hierarchical structure with superhydrophobicity was created on Al foil by a facile three-step solution–immersion method involving etching in hydrochloric acid solution and immersing in hot water as well as surface-modification by stearic acid (denoted as STA). As-prepared etched-immersed Al/STA rough surface was characterized by means of scanning electron microscopy and X-ray photoelectron spectroscopy. Moreover, the water contact angles and water sliding angles of as-prepared etched-immersed Al/STA rough surface were measured, and the friction-reducing performance and self-cleaning ability of the as-prepared surface were also evaluated. Results indicate that the etched-immersed Al/STA rough surface consists of interconnected convex–concave micro-structure and uniformly distributed nano-sheets. Besides, it exhibits stable superhydrophobicity and good friction-reducing ability. Namely, it has a contact angle of water as high as 164.2° and a water sliding

  7. Fabrication and characterization of stable superhydrophobic surface with good friction-reducing performance on Al foil

    International Nuclear Information System (INIS)

    Li, Peipei; Chen, Xinhua; Yang, Guangbin; Yu, Laigui; Zhang, Pingyu

    2014-01-01

    Graphical abstract: A lotus-leaf-like hierarchical structure was successfully created on Al foil by a facile three-step solution–immersion method. As-obtained etched-immersed Al/STA rough surface contains interconnected convex–concave micro-structure and uniformly distributed nano-sheets that endow the surface with excellent superhydrophobicity (WCA: 164.2°; WSA: below 5°). Besides, the as-prepared etched-immersed Al/STA superhydrophobic surface on Al foil exhibits good friction-reducing ability and stable superhydrophobicity. - Highlights: • A stable superhydrophobic surface was created on aluminum foil by a facile three-step solution–immersion method. • A lotus-leaf-like hierarchical structure consists of interconnected convex–concave micro-structure and uniformly distributed nano-sheets has been constructed on the aluminum surface. • The superhydrophobic surfaces on aluminum substrate showing effective friction-reducing performance and self-cleaning ability. - Abstract: A lotus-leaf-like hierarchical structure with superhydrophobicity was created on Al foil by a facile three-step solution–immersion method involving etching in hydrochloric acid solution and immersing in hot water as well as surface-modification by stearic acid (denoted as STA). As-prepared etched-immersed Al/STA rough surface was characterized by means of scanning electron microscopy and X-ray photoelectron spectroscopy. Moreover, the water contact angles and water sliding angles of as-prepared etched-immersed Al/STA rough surface were measured, and the friction-reducing performance and self-cleaning ability of the as-prepared surface were also evaluated. Results indicate that the etched-immersed Al/STA rough surface consists of interconnected convex–concave micro-structure and uniformly distributed nano-sheets. Besides, it exhibits stable superhydrophobicity and good friction-reducing ability. Namely, it has a contact angle of water as high as 164.2° and a water sliding

  8. Site specificity of biosphere parameter values in performance assessments of near-surface repositories

    International Nuclear Information System (INIS)

    Zeevaert, Th.; Volckaert, G.; Vandecasleele

    1993-01-01

    The contribution is dealing with the performance assessment model for near surface repositories in Belgium. It consists of four submodels called: site, aquifer, biosphere and dose. For some characteristic radionuclides, results of the study are shown for a typical site, and differences in doses assessed with the generic approach discussed. Shortcomings are indicated

  9. Surface Texturing-Plasma Nitriding Duplex Treatment for Improving Tribological Performance of AISI 316 Stainless Steel

    Directory of Open Access Journals (Sweden)

    Naiming Lin

    2016-10-01

    Full Text Available Surface texturing-plasma nitriding duplex treatment was conducted on AISI 316 stainless steel to improve its tribological performance. Tribological behaviors of ground 316 substrates, plasma-nitrided 316 (PN-316, surface-textured 316 (ST-316, and duplex-treated 316 (DT-316 in air and under grease lubrication were investigated using a pin-on-disc rotary tribometer against counterparts of high carbon chromium bearing steel GCr15 and silicon nitride Si3N4 balls. The variations in friction coefficient, mass loss, and worn trace morphology of the tested samples were systemically investigated and analyzed. The results showed that a textured surface was formed on 316 after electrochemical processing in a 15 wt % NaCl solution. Grooves and dimples were found on the textured surface. As plasma nitriding was conducted on a 316 substrate and ST-316, continuous and uniform nitriding layers were successfully fabricated on the surfaces of the 316 substrate and ST-316. Both of the obtained nitriding layers presented thickness values of more than 30 μm. The nitriding layers were composed of iron nitrides and chromium nitride. The 316 substrate and ST-316 received improved surface hardness after plasma nitriding. When the tribological tests were carried out under dry sliding and grease lubrication conditions, the tested samples showed different tribological behaviors. As expected, the DT-316 samples revealed the most promising tribological properties, reflected by the lowest mass loss and worn morphologies. The DT-316 received the slightest damage, and its excellent tribological performance was attributed to the following aspects: firstly, the nitriding layer had high surface hardness; secondly, the surface texture was able to capture wear debris, store up grease, and then provide continuous lubrication.

  10. The New Horizons Radio Science Experiment: Performance and Measurements of Pluto's Atmospheric Structure, Surface Pressure, and Surface Temperature

    Science.gov (United States)

    Linscott, I.; Hinson, D. P.; Bird, M. K.; Stern, A.; Weaver, H. A., Jr.; Olkin, C.; Young, L. A.; Ennico Smith, K.

    2015-12-01

    The New Horizons (NH) spacecraft payload contained the Radio Science Experiment (REX) for determining key characteristics of Pluto and Charon during the July 14, 2015, flyby of the Pluto/Charon system. The REX flight equipment augments the NH X-band radio transceiver by providing a high precision, narrow band recording of high power uplink transmissions from Earth stations, as well as a record of broadband radiometric power. This presentation will review the performance and initial results of two high- priority observations. First, REX received two pair of 20-kW signals, one pair per polarization, transmitted from the DSN at 4.2-cm wavelength during a diametric radio occultation by Pluto. REX recorded these uplink signals and determined precise measurement of the surface pressure, the temperature structure of the lower atmosphere, and the surface radius of Pluto. The ingress portion of one polarization was played back from the spacecraft in July and processed to obtain the pressure and temperature structure of Pluto's atmosphere. Second, REX measured the thermal emission from Pluto at 4.2- cm wavelength during two linear scans across the disk at close range when both the dayside and the night side are visible. Both scans extend from limb to limb with a resolution of one-tenth Pluto's disk and temperature resolution of 0.1 K. Occultation and radiometric temperature results presented here will encompass additional data scheduled for playback in September.

  11. Performance of five surface energy balance models for estimating daily evapotranspiration in high biomass sorghum

    Science.gov (United States)

    Wagle, Pradeep; Bhattarai, Nishan; Gowda, Prasanna H.; Kakani, Vijaya G.

    2017-06-01

    Robust evapotranspiration (ET) models are required to predict water usage in a variety of terrestrial ecosystems under different geographical and agrometeorological conditions. As a result, several remote sensing-based surface energy balance (SEB) models have been developed to estimate ET over large regions. However, comparison of the performance of several SEB models at the same site is limited. In addition, none of the SEB models have been evaluated for their ability to predict ET in rain-fed high biomass sorghum grown for biofuel production. In this paper, we evaluated the performance of five widely used single-source SEB models, namely Surface Energy Balance Algorithm for Land (SEBAL), Mapping ET with Internalized Calibration (METRIC), Surface Energy Balance System (SEBS), Simplified Surface Energy Balance Index (S-SEBI), and operational Simplified Surface Energy Balance (SSEBop), for estimating ET over a high biomass sorghum field during the 2012 and 2013 growing seasons. The predicted ET values were compared against eddy covariance (EC) measured ET (ETEC) for 19 cloud-free Landsat image. In general, S-SEBI, SEBAL, and SEBS performed reasonably well for the study period, while METRIC and SSEBop performed poorly. All SEB models substantially overestimated ET under extremely dry conditions as they underestimated sensible heat (H) and overestimated latent heat (LE) fluxes under dry conditions during the partitioning of available energy. METRIC, SEBAL, and SEBS overestimated LE regardless of wet or dry periods. Consequently, predicted seasonal cumulative ET by METRIC, SEBAL, and SEBS were higher than seasonal cumulative ETEC in both seasons. In contrast, S-SEBI and SSEBop substantially underestimated ET under too wet conditions, and predicted seasonal cumulative ET by S-SEBI and SSEBop were lower than seasonal cumulative ETEC in the relatively wetter 2013 growing season. Our results indicate the necessity of inclusion of soil moisture or plant water stress

  12. Surface Modification of AISI 440B Stainless Steel and its Influence on Surgical Drill Bits Performance

    Directory of Open Access Journals (Sweden)

    Łępicka M.

    2016-09-01

    Full Text Available The development of modern invasive surgery is highly dependent on the performance of surgical instruments, understood as long-term efficiency arising from high resistance to wear and corrosion. In order to maintain sufficient reliability, surgical cutting instruments are often made of martensitic stainless steels. Nevertheless, the use of ferrous alloys in medical applications is still a concern due to their questionable corrosion and wear resistance. To extend their biocompatibility, improve stability in variable environmental conditions, improve ease of handling, and maximize their performance, diffusion layers and coatings are applied to the surface. The aim of this work was to evaluate the effect of TiN and diamond-like carbon (DLC surface modification on the performance of surgical drill bits, that is, wear and corrosion resistance, measured in model and field tests. Based on the findings presented, DLC layers can be recommended as anti-wear and anti-corrosion coatings for surgical drill bits.

  13. Liquid lithium surface control and its effect on plasma performance in the HT-7 tokamak

    Energy Technology Data Exchange (ETDEWEB)

    Zuo, G.Z.; Ren, J. [Institute of Plasma Physics, Chinese Academy of Sciences, Hefei 230031 (China); Hu, J.S., E-mail: hujs@ipp.ac.cn [Institute of Plasma Physics, Chinese Academy of Sciences, Hefei 230031 (China); Sun, Z.; Yang, Q.X.; Li, J.G. [Institute of Plasma Physics, Chinese Academy of Sciences, Hefei 230031 (China); Zakharov, L.E. [Princeton University Plasma Physics Laboratory Princeton, NJ 08543 (United States); Ruzic, David N. [University of Illinois, Urbana, IL 61801 (United States)

    2014-12-15

    Highlights: • Strong interaction between plasma and Li would cause strong Li emission and lead to disruptive plasmas, and probable reasons were analyzed. • Serious Li would be emitted from the free statics surface mainly due to J × B force leading to plasma instable and disruptions. • CPS surface would partially suppress the emission and be beneficial for plasma operation. • Li emission from flowing LLLs on free surfaces on SS trenches and on SS plate were compared. - Abstract: Experiments with liquid lithium limiters (LLLs) have been successfully performed in HT-7 since 2009 and the effects of different limiter surface structures on the ejection of Li droplets have been studied and compared. The experiments have demonstrated that strong interaction between the plasma and the liquid surface can cause intense Li efflux in the form of ejected Li droplets – which can, in turn, lead to plasma disruptions. The details of the LLL plasma-facing surface were observed to be extremely important in determining performance. Five different LLLs were evaluated in this work: two types of static free-surface limiters and three types of flowing liquid Li (FLLL) structures. It has been demonstrated that a FLLL with a slowly flowing thin liquid Li film on vertical flow plate which was pre-treated with evaporated Li was much less susceptible to Li droplet ejection than any of the other structures tested in this work. It was further observed that the plasmas run against this type of limiter were reproducibly well-behaved. These results provide technical references for the design of FLLLs in future tokamaks so as to avoid strong Li ejection and to decrease disruptive plasmas.

  14. Enhancing the antibacterial performance of orthopaedic implant materials by fibre laser surface engineering

    Science.gov (United States)

    Chan, Chi-Wai; Carson, Louise; Smith, Graham C.; Morelli, Alessio; Lee, Seunghwan

    2017-05-01

    Implant failure caused by bacterial infection is extremely difficult to treat and usually requires the removal of the infected components. Despite the severe consequence of bacterial infection, research into bacterial infection of orthopaedic implants is still at an early stage compared to the effort on enhancing osseointegration, wear and corrosion resistance of implant materials. In this study, the effects of laser surface treatment on enhancing the antibacterial properties of commercially pure (CP) Ti (Grade 2), Ti6Al4V (Grade 5) and CoCrMo alloy implant materials were studied and compared for the first time. Laser surface treatment was performed by a continuous wave (CW) fibre laser with a near-infrared wavelength of 1064 nm in a nitrogen-containing environment. Staphylococcus aureus, commonly implicated in infection associated with orthopaedic implants, was used to investigate the antibacterial properties of the laser-treated surfaces. The surface roughness and topography of the laser-treated materials were analysed by a 2D roughness testing and by AFM. The surface morphologies before and after 24 h of bacterial cell culture were captured by SEM, and bacterial viability was determined using live/dead staining. Surface chemistry was analysed by XPS and surface wettability was measured using the sessile drop method. The findings of this study indicated that the laser-treated CP Ti and Ti6Al4V surfaces exhibited a noticeable reduction in bacterial adhesion and possessed a bactericidal effect. Such properties were attributable to the combined effects of reduced hydrophobicity, thicker and stable oxide films and presence of laser-induced nano-features. No similar antibacterial effect was observed in the laser-treated CoCrMo.

  15. Performing in-feed type centerless grinding process on a surface grinder

    International Nuclear Information System (INIS)

    Xu, W.; Wu, Y.; Sato, T.; Lin, W.

    2011-01-01

    In our previous study, a new centerless grinding method using surface grinder was proposed. In this method, centerless grinding operations are performed by installing a compact centerless grinding unit, consisting mainly of an ultrasonic elliptic-vibration shoe, a blade and their respective holders, on the worktable of a surface grinder. During grinding, the cylindrical workpiece is held on the ultrasonic shoe and the blade, and its rotational motion is controlled by the elliptic motion of the shoe end-face. An actual unit had been produced and its performance in tangential-feed type centerless grinding using a surface grinder had been confirmed in the previous workd. In this paper, the performance of the grinding unit in in-feed centerless grinding operation was confirmed, and the effects of the main process parameter, i.e., eccentric angle, on the workpiece roundness was investigated experimentally. The obtained results showed that: (1) the centerless grinding unit performed well in in-feed type centerless grinding; (2) the eccentric angle affects roundness significantly, and its optimal angle is 6 deg.; (3) the workpiece roundness can be further improved by varying the eccentric angle during grinding, and the final roundness reached 0.65 μm after grinding as the eccentric angle varied from 9 deg. to 6 deg. and to 3 deg.

  16. Performance evaluation for different sensing surface of BICELLs bio-transducers for dry eye biomarkers

    Science.gov (United States)

    Laguna, M. F.; Holgado, M.; Santamaría, B.; López, A.; Maigler, M.; Lavín, A.; de Vicente, J.; Soria, J.; Suarez, T.; Bardina, C.; Jara, M.; Sanza, F. J.; Casquel, R.; Otón, A.; Riesgo, T.

    2015-03-01

    Biophotonic Sensing Cells (BICELLs) are demonstrated to be an efficient technology for label-free biosensing and in concrete for evaluating dry eye diseases. The main advantage of BICELLs is its capability to be used by dropping directly a tear into the sensing surface without the need of complex microfluidics systems. Among this advantage, compact Point of Care read-out device is employed with the capability of evaluating different types of BICELLs packaged on Biochip-Kits that can be fabricated by using different sensing surfaces material. In this paper, we evaluate the performance of the combination of three sensing surface materials: (3-Glycidyloxypropyl) trimethoxysilane (GPTMS), SU-8 resist and Nitrocellulose (NC) for two different biomarkers relevant for dry eye diseases: PRDX-5 and ANXA-11.

  17. Influences of surface temperature on a low camber airfoil aerodynamic performances

    Directory of Open Access Journals (Sweden)

    Valeriu DRAGAN

    2016-03-01

    Full Text Available The current note refers to the comparison between a NACA 2510 airfoil with adiabatic walls and the same airfoil with heated patches. Both suction and pressure sides were divided into two regions covering the leading edge (L.E. and trailing edge (T.E.. A RANS method sensitivity test has been performed in the preliminary stage while for the extended 3D cases a DES-SST approach was used. Results indicate that surface temperature distribution influences the aerodynamics of the airfoil, in particular the viscous drag component but also the lift of the airfoil. Moreover, the influence depends not only on the surface temperature but also on the positioning of the heated surfaces, particularly in the case of pressure lift and drag. Further work will be needed to optimize the temperature distribution for airfoil with higher camber.

  18. Tribological performance of sub-100-nm femtosecond laser-induced periodic surface structures on titanium

    Energy Technology Data Exchange (ETDEWEB)

    Bonse, J., E-mail: joern.bonse@bam.de [BAM Bundesanstalt für Materialforschung und -prüfung, Unter den Eichen 87, D-12205 Berlin (Germany); Höhm, S. [Max-Born-Institut für Nichtlineare Optik und Kurzzeitspektroskopie (MBI), Max-Born-Straße 2A, D-12489 Berlin (Germany); Koter, R.; Hartelt, M.; Spaltmann, D.; Pentzien, S. [BAM Bundesanstalt für Materialforschung und -prüfung, Unter den Eichen 87, D-12205 Berlin (Germany); Rosenfeld, A. [Max-Born-Institut für Nichtlineare Optik und Kurzzeitspektroskopie (MBI), Max-Born-Straße 2A, D-12489 Berlin (Germany); Krüger, J. [BAM Bundesanstalt für Materialforschung und -prüfung, Unter den Eichen 87, D-12205 Berlin (Germany)

    2016-06-30

    Graphical abstract: - Highlights: • Large areas covered with sub-100 nm LIPSS (HSFL) were manufactured by fs-laser irradiation on titanium surfaces. • Tribological performance of HSFL covered areas was qualified in reciprocal sliding tests in two different lubricating oils. • HSFL on titanium do not endure the tribological tests. • For a beneficial tribological performance, the tribological sample deformation must be smaller than the LIPSS modulation depth. - Abstract: Sub-100-nm laser-induced periodic surface structures (LIPSS) were processed on bulk titanium (Ti) surfaces by femtosecond laser pulse irradiation in air (30 fs pulse duration, 790 nm wavelength). The laser peak fluence, the spatial spot overlap, and the number of overscans were optimized in a sample-scanning geometry in order to obtain large surface areas (5 mm × 5 mm) covered homogeneously by the LIPSS. The laser-processed regions were characterized by optical microscopy (OM), white light interference microscopy (WLIM) and scanning electron microscopy (SEM). The friction coefficient of the nanostructured surfaces was tested during 1000 cycles under reciprocal sliding conditions (1 Hz, 1.0 N normal load) against a 10-mm diameter ball of hardened 100Cr6 steel, both in paraffin oil and in engine oil used as lubricants. Subsequently, the corresponding wear tracks were qualified by OM, SEM, and energy dispersive X-ray analyses (EDX). The results of the tribological tests are discussed and compared to that obtained for near wavelength-sized fs-LIPSS, processed under somewhat different irradiation conditions. Some constraints for a beneficial effect of LIPSS on the tribological performance are provided.

  19. Tribological performance of sub-100-nm femtosecond laser-induced periodic surface structures on titanium

    International Nuclear Information System (INIS)

    Bonse, J.; Höhm, S.; Koter, R.; Hartelt, M.; Spaltmann, D.; Pentzien, S.; Rosenfeld, A.; Krüger, J.

    2016-01-01

    Graphical abstract: - Highlights: • Large areas covered with sub-100 nm LIPSS (HSFL) were manufactured by fs-laser irradiation on titanium surfaces. • Tribological performance of HSFL covered areas was qualified in reciprocal sliding tests in two different lubricating oils. • HSFL on titanium do not endure the tribological tests. • For a beneficial tribological performance, the tribological sample deformation must be smaller than the LIPSS modulation depth. - Abstract: Sub-100-nm laser-induced periodic surface structures (LIPSS) were processed on bulk titanium (Ti) surfaces by femtosecond laser pulse irradiation in air (30 fs pulse duration, 790 nm wavelength). The laser peak fluence, the spatial spot overlap, and the number of overscans were optimized in a sample-scanning geometry in order to obtain large surface areas (5 mm × 5 mm) covered homogeneously by the LIPSS. The laser-processed regions were characterized by optical microscopy (OM), white light interference microscopy (WLIM) and scanning electron microscopy (SEM). The friction coefficient of the nanostructured surfaces was tested during 1000 cycles under reciprocal sliding conditions (1 Hz, 1.0 N normal load) against a 10-mm diameter ball of hardened 100Cr6 steel, both in paraffin oil and in engine oil used as lubricants. Subsequently, the corresponding wear tracks were qualified by OM, SEM, and energy dispersive X-ray analyses (EDX). The results of the tribological tests are discussed and compared to that obtained for near wavelength-sized fs-LIPSS, processed under somewhat different irradiation conditions. Some constraints for a beneficial effect of LIPSS on the tribological performance are provided.

  20. Enhanced photoelectrochemical water splitting performance of anodic TiO(2) nanotube arrays by surface passivation.

    Science.gov (United States)

    Gui, Qunfang; Xu, Zhen; Zhang, Haifeng; Cheng, Chuanwei; Zhu, Xufei; Yin, Min; Song, Ye; Lu, Linfeng; Chen, Xiaoyuan; Li, Dongdong

    2014-10-08

    One-dimensional anodic titanium oxide nanotube (TONT) arrays provide a direct pathway for charge transport, and thus hold great potential as working electrodes for electrochemical energy conversion and storage devices. However, the prominent surface recombination due to the large amount surface defects hinders the performance improvement. In this work, the surface states of TONTs were passivated by conformal coating of high-quality Al2O3 onto the tubular structures using atomic layer deposition (ALD). The modified TONT films were subsequently employed as anodes for photoelectrochemical (PEC) water splitting. The photocurrent (0.5 V vs Ag/AgCl) recorded under air mass 1.5 global illumination presented 0.8 times enhancement on the electrode with passivation coating. The reduction of surface recombination rate is responsible for the substantially improved performance, which is proposed to have originated from a decreased interface defect density in combination with a field-effect passivation induced by a negative fixed charge in the Al2O3 shells. These results not only provide a physical insight into the passivation effect, but also can be utilized as a guideline to design other energy conversion devices.

  1. Effect of engine-based thermal aging on surface morphology and performance of Lean NOx Traps

    International Nuclear Information System (INIS)

    Toops, Todd J.; Bunting, Bruce G.; Nguyen, Ke; Gopinath, Ajit

    2007-01-01

    A small single-cylinder diesel engine is used to thermally age model (Pt + Rh/Ba/γ-Al 2 O 3 ) lean NO x traps (LNTs) under lean/rich cycling at target temperatures of 600 C, 700 C, and 800 C. During an aging cycle, fuel is injected into the exhaust to achieve reproducible exotherms under lean and rich conditions with the average temperature approximating the target temperature. Aging is performed until the cycle-average NO x conversion measured at 400 C is approximately constant. Engine-based NO x conversion decreased by 42% after 60 cycles at 600 C, 36% after 76 cycles at 700 C and 57% after 46 cycles at 800 C. The catalyst samples were removed and characterized by XRD and using a microreactor that allowed controlled measurements of surface area, precious metal size, NO x storage, and reaction rates. Three aging mechanisms responsible for the deactivation of LNTs have been identified: (1) loss of dispersion of the precious metals, (2) phase transitions in the washcoat materials, and (3) loss of surface area of the storage component and support. These three mechanisms are accelerated when the aging temperature exceeds 850 C - the γ to (delta) transition temperature of Al 2 O 3 . Normalization of rates of NO reacted at 400 C to total surface area demonstrates the biggest impact on performance stems from surface area losses rather than from precious metal sintering. (author)

  2. Study of Bio-Mimicry Surfaces for Optimization of Coupling Performance in Wheelchair Racing Gloves

    Directory of Open Access Journals (Sweden)

    Clara Usma

    2018-03-01

    Full Text Available In wheelchair racing, the optimal pair of gloves, as well as knowledge of conditioning of glove-rim contact surfaces can have a significant impact on race performance. Extreme temperatures, humidity, wet or dry conditions can considerably influence not only the hand-rim friction coupling (effectiveness of the athlete’s push cycle but also the risk of injuries, blisters or sore areas which in turn, can influence the endurance of the athlete across long distance events. This paper reports an experimental study of the effect of bio-mimicry surface textures as a supplement for heightening glove-rim coupling for dry and wet weather conditions. The paper also provides recommendations for the practical implementation of the study findings through a proposal for the design and development of a pair of bespoke gloves for a wheelchair racing athlete for initial prototyping and performance trials.

  3. The effect of texture on the shaft surface on the sealing performance of radial lip seals

    Science.gov (United States)

    Guo, Fei; Jia, XiaoHong; Gao, Zhi; Wang, YuMing

    2014-07-01

    On the basis of elastohydrodynamic model, the present study numerically analyzes the effect of various microdimple texture shapes, namely, circular, square, oriented isosceles triangular, on the pumping rate and the friction torque of radial lip seals, and determines the microdimple texture shape that can produce positive pumping rate. The area ratio, depth and shape dimension of a single texture are the most important geometric parameters which influence the tribological performance. According to the selected texture shape, parameter analysis is conducted to determine the optimal combination for the above three parameters. Simultaneously, the simulated performances of radial lip seal with texture on the shaft surface are compared with those of the conventional lip seal without any texture on the shaft surface.

  4. Excess Li-Ion Storage on Reconstructed Surfaces of Nanocrystals To Boost Battery Performance

    Energy Technology Data Exchange (ETDEWEB)

    Duan, Yandong; Zhang, Bingkai; Zheng, Jiaxin; Hu, Jiangtao; Wen, Jianguo; Miller, Dean; Yan, Pengfei; Liu, Tongchao; Guo, Hua; Li, Wen; Song, Xiaohe; Zhou, Zengquing; Liu, Chaokun; Tang, Hanting; Tan, Rui; Chen, Zonghai; Ren, Yang; Lin, Yuan; Yang, Wanli; Wang, Chongmin; Wang, Lin-Wang; Lu, Jun; Amine, Khalil; Pan, Feng

    2017-08-03

    Abstract. Due to the enhanced kinetic properties, nanocrystallites have received much attention as potential electrode materials for energy storage. However, because of the large specific surface areas of nanocrystallites, they usually suffer from decreased energy density, reduced cycling stability and total electrode capacity. In this work, we report a size-dependent excess capacity beyond the theoretical value of 170 mAhg-1 in a special carbon coated LiFePO4 composite cathode material, which delivers capacities of 191.2 and 213.5 mAhg-1 with the mean particle sizes of 83 nm and 42 nm, respectively. Moreover, this LiFePO4 composite also shows excellent cycling stability and high rate performance. Our further experimental tests and ab initio calculations reveal that the excess capacity comes from the charge passivation for which the C-O-Fe bonds would lead to charge redistribution on the surface of LiFePO4 and hence to enhance the bonding interaction between surface O atoms and Li-ions. The surface reconstruction for excess Li-ion storage makes full use of the large specific surface area for the nanocrystallites, which can maintain the fast Li-ion transport and enhance the capacity greatly that the nanocrystallites usually suffers.

  5. BIOPHYSICAL PROPERTIES OF NUCLEIC ACIDS AT SURFACES RELEVANT TO MICROARRAY PERFORMANCE.

    Science.gov (United States)

    Rao, Archana N; Grainger, David W

    2014-04-01

    Both clinical and analytical metrics produced by microarray-based assay technology have recognized problems in reproducibility, reliability and analytical sensitivity. These issues are often attributed to poor understanding and control of nucleic acid behaviors and properties at solid-liquid interfaces. Nucleic acid hybridization, central to DNA and RNA microarray formats, depends on the properties and behaviors of single strand (ss) nucleic acids (e.g., probe oligomeric DNA) bound to surfaces. ssDNA's persistence length, radius of gyration, electrostatics, conformations on different surfaces and under various assay conditions, its chain flexibility and curvature, charging effects in ionic solutions, and fluorescent labeling all influence its physical chemistry and hybridization under assay conditions. Nucleic acid (e.g., both RNA and DNA) target interactions with immobilized ssDNA strands are highly impacted by these biophysical states. Furthermore, the kinetics, thermodynamics, and enthalpic and entropic contributions to DNA hybridization reflect global probe/target structures and interaction dynamics. Here we review several biophysical issues relevant to oligomeric nucleic acid molecular behaviors at surfaces and their influences on duplex formation that influence microarray assay performance. Correlation of biophysical aspects of single and double-stranded nucleic acids with their complexes in bulk solution is common. Such analysis at surfaces is not commonly reported, despite its importance to microarray assays. We seek to provide further insight into nucleic acid-surface challenges facing microarray diagnostic formats that have hindered their clinical adoption and compromise their research quality and value as genomics tools.

  6. Electromechanical performance of an ionic polymer–metal composite actuator with hierarchical surface texture

    International Nuclear Information System (INIS)

    He, Qingsong; Yu, Min; Zhang, Xiaoqing; Dai, Zhendong

    2013-01-01

    Two stainless steel templates were fabricated using electric-spark machining, and a hierarchical surface texture of ionic polymer was produced using both polishing and replication methods, which produced microscale and nanoscale groove-shaped microstructures at the surface of the polymer. The surface morphology of the Nafion membrane and metal electrode were observed using scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). SEM and EDS line-scan analysis indicated that the interfacial surface area was considerably increased and an excellent metal electrode was obtained with the production of a hierarchical surface texture. The displacement, blocking force, and electric current were measured using home-built apparatus. The results revealed that the combined polishing and replication method significantly improved the electromechanical performance of the ionic polymer–metal composite (IPMC). Compared with sandblasted Nafion-based IPMC, the blocking force, displacement, and electric current of the replicated Nafion-based IPMC were 4.39, 2.35, and 1.87 times higher, respectively. The IPMC fabricated in this work exhibited a competitive blocking force compared with recently reported actuators. (paper)

  7. BIOPHYSICAL PROPERTIES OF NUCLEIC ACIDS AT SURFACES RELEVANT TO MICROARRAY PERFORMANCE

    Science.gov (United States)

    Rao, Archana N.; Grainger, David W.

    2014-01-01

    Both clinical and analytical metrics produced by microarray-based assay technology have recognized problems in reproducibility, reliability and analytical sensitivity. These issues are often attributed to poor understanding and control of nucleic acid behaviors and properties at solid-liquid interfaces. Nucleic acid hybridization, central to DNA and RNA microarray formats, depends on the properties and behaviors of single strand (ss) nucleic acids (e.g., probe oligomeric DNA) bound to surfaces. ssDNA’s persistence length, radius of gyration, electrostatics, conformations on different surfaces and under various assay conditions, its chain flexibility and curvature, charging effects in ionic solutions, and fluorescent labeling all influence its physical chemistry and hybridization under assay conditions. Nucleic acid (e.g., both RNA and DNA) target interactions with immobilized ssDNA strands are highly impacted by these biophysical states. Furthermore, the kinetics, thermodynamics, and enthalpic and entropic contributions to DNA hybridization reflect global probe/target structures and interaction dynamics. Here we review several biophysical issues relevant to oligomeric nucleic acid molecular behaviors at surfaces and their influences on duplex formation that influence microarray assay performance. Correlation of biophysical aspects of single and double-stranded nucleic acids with their complexes in bulk solution is common. Such analysis at surfaces is not commonly reported, despite its importance to microarray assays. We seek to provide further insight into nucleic acid-surface challenges facing microarray diagnostic formats that have hindered their clinical adoption and compromise their research quality and value as genomics tools. PMID:24765522

  8. Towards Enhanced Performance Thin-film Composite Membranes via Surface Plasma Modification

    Science.gov (United States)

    Reis, Rackel; Dumée, Ludovic F.; Tardy, Blaise L.; Dagastine, Raymond; Orbell, John D.; Schutz, Jürg A.; Duke, Mikel C.

    2016-01-01

    Advancing the design of thin-film composite membrane surfaces is one of the most promising pathways to deal with treating varying water qualities and increase their long-term stability and permeability. Although plasma technologies have been explored for surface modification of bulk micro and ultrafiltration membrane materials, the modification of thin film composite membranes is yet to be systematically investigated. Here, the performance of commercial thin-film composite desalination membranes has been significantly enhanced by rapid and facile, low pressure, argon plasma activation. Pressure driven water desalination tests showed that at low power density, flux was improved by 22% without compromising salt rejection. Various plasma durations and excitation powers have been systematically evaluated to assess the impact of plasma glow reactions on the physico-chemical properties of these materials associated with permeability. With increasing power density, plasma treatment enhanced the hydrophilicity of the surfaces, where water contact angles decreasing by 70% were strongly correlated with increased negative charge and smooth uniform surface morphology. These results highlight a versatile chemical modification technique for post-treatment of commercial membrane products that provides uniform morphology and chemically altered surface properties. PMID:27363670

  9. Multi-Scale Texturing of Metallic Surfaces for High Performance Military Systems

    Science.gov (United States)

    2015-08-17

    AISI 440C stainless steel balls of 3 mm radius and 690 HV hardness. The sliding time (20 min), amplitude (10.5 mm), frequency (1.5 Hz) and normal...texture form (e. g., micro-scale topography) on surface integrity measures and tribological wear performance were quantified. The ensuing results are... Tribological Applications, Submitted for publication (08 2015) TOTAL: 2 Books Number of Manuscripts: Patents Submitted Patents Awarded Awards Graduate Students

  10. Design and performance evaluation of a 1000-year evapotranspiration-capillary surface barrier

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Zhuanfang Fred; Strickland, Christopher E.; Link, Steven O.

    2017-02-01

    Surface barrier technology is used to isolate radioactive waste and to reduce or eliminate recharge water to the waste zone for 1000 years or longer. However, the design and evaluation of such a barrier is challenging because of the extremely long design life. The Prototype Hanford Barrier (PHB) was designed as a 1000-year barrier with pre-determined design and performance objectives and demonstrated in field from 1994 to present. The barrier was tested to evaluate surface-barrier design and performance at the field scale under conditions of enhanced and natural precipitation and of no vegetation. The monitoring data demonstrate that the barrier satisfied nearly all key objectives. The PHB far exceeded the Resource Conservation and Recovery Act criteria, functioned in Hanford’s semiarid climate, limited drainage to well below the 0.5 mm yr-1 performance criterion, limited runoff, and minimized erosion. Given the two-decade record of successful performance and consideration of all the processes and mechanisms that could degrade the stability and hydrology in the future, the results suggest the PHB is very likely to perform for its 1000-year design life. This conclusion is based on two assumptions: (1) the exposed subgrade receives protection against erosion and (2) institutional controls prevent inadvertent human activity at the barrier. The PHB design can serve as the base for site-specific barriers over waste sites containing underground nuclear waste, uranium mine tailings, and hazardous mine waste.

  11. Performance improvement of haptic collision detection using subdivision surface and sphere clustering.

    Directory of Open Access Journals (Sweden)

    A Ram Choi

    Full Text Available Haptics applications such as surgery simulations require collision detections that are more precise than others. An efficient collision detection method based on the clustering of bounding spheres was proposed in our prior study. This paper analyzes and compares the applied effects of the five most common subdivision surface methods on some 3D models for haptic collision detection. The five methods are Butterfly, Catmull-Clark, Mid-point, Loop, and LS3 (Least Squares Subdivision Surface. After performing a number of experiments, we have concluded that LS3 method is the most appropriate for haptic simulations. The more we applied surface subdivision, the more the collision detection results became precise. However, it is observed that the performance becomes better until a certain threshold and degrades afterward. In order to reduce the performance degradation, we adopted our prior work, which was the fast and precise collision detection method based on adaptive clustering. As a result, we obtained a notable improvement of the speed of collision detection.

  12. Thermal performance of a phase change material on a nickel-plated surface

    International Nuclear Information System (INIS)

    Nurmawati, M.H.; Siow, K.S.; Rasiah, I.J.

    2004-01-01

    Thermal control becomes increasingly vital with IC chips becoming faster and smaller. The need to keep chips within acceptable operating temperatures is a growing challenge. Thermal interface materials (TIM) form the interfaces that improve heat transfer from the heat-generating chip to the heat dissipating thermal solution. One of the most commonly used materials in today's electronics industry is phase change material (PCM). Typically, the heat spreader is a nickel-plated copper surface. The compatibility of the PCM to this surface is crucial to the performance of the TIM. In this paper, we report on the performance of this interface. To that end, an instrument to suitably measure critical parameters, like the apparent and contact thermal resistance of the TIM, is developed according to the ASTM D5470 and calibrated. A brief theory of TIM is described and the properties of the PCM were investigated using the instrument. Thermal resistance measurements were made to investigate the effects of physical parameters like pressure, temperature and supplied power on the thermal performance of the material on nickel-plated surface. Conclusions were drawn on the effectiveness of the interface and their application in IC packages

  13. [Influence of 175-m-impoundment in Three Gorges Reservoir area on the food web energy sources of main commercial fishes in backwater area of xiaojiang River].

    Science.gov (United States)

    Li, Bin; Wang, Zhi-Jian; Yue, Xing-Jian; Wang, Yong-Ming; Jin, Li; Zhang, Yao-Guang

    2013-06-01

    The impoundment in the Three Gorges Reservoir Area (TGRA) was first reached 175 m in 2010. To approach the influence of this impoundment on the food web energy sources of fishes in the tributaries of TRGA, an analysis was made on the food web energy sources of seven economically important fishes (Carassius auratus, Cyprinus carpio, Silurus asotus, Culter mongolicus mongolicus, Mystus macropterus, Pelteobagrus vachelli, and Pelteobagrus nitidus) in the backwater area of Xiaojiang River by using stable isotope method in combining with IsoSource Model. The results showed that before this impoundment (July 2010), microalgae were the main energy sources for the seven species. After this impoundment (December 2010), the contribution ratio of the microalgae decreased somewhat, while the relative contribution of terrestrial C4 plants had an obvious increase. Especially for crucian carp (C. auratus) and catfish (S. asotus), the contribution rate of the C4 plants reached 38-54% and 32-50%, respectively. After the impoundment, at least 30% of the energy resources of these two fishes were come from terrestrial C4 plants, suggesting that the impoundment in TGRA increased the contribution rate of exogenous terrestrial C4 plants as the energy sources of fishes.

  14. Arsenic mobility from anthropogenic impoundment sediments - Consequences of contamination to biota, water and sediments, Posa, Eastern Slovakia

    Energy Technology Data Exchange (ETDEWEB)

    Hiller, E.; Jurkovic, L.; Kordik, J.; Slaninka, I.; Jankular, M.; Majzlan, J.; Gottlicher, J.; Steininger, R. [Geological Survey of Slovak Republic, Bratislava (Slovakia). Dept. of Environmental Geochemistry

    2009-11-15

    An impoundment located near the village of Posa, Slovakia, is a significant source of contamination with As originating from the deposited coal fly-ash. Waters penetrating the impoundment are enriched in As and other potentially toxic elements. As a consequence of the contamination, the Kyjov Brook and the Ondava River have been extensively polluted. The mobility and solid-state partitioning of As in the impoundment material and stream sediments were investigated using column leaching and batch extraction tests, and a five-step sequential extraction procedure. Moreover, to investigate the bioavailability of As, two native plant species (Typha latifolia, or cattail, and Phragmites australis, or common reed) growing at the site were collected and analyzed. The As concentrations in representative sediment and water samples ranged from 36.3 to 3210 mg/kg and from 4.05 to 613 {mu} g/L, respectively, both being many times above the background levels. Although a part of As was present in a readily soluble form (6.6%), the majority of As was mainly associated with Fe and Mn oxides (37%) and residual phases (51%). Combined results of the column leaching, batch extraction, and sequential extraction tests, as well as mineralogical analysis, indicated that As mobilisation potential from the sediments is likely controlled by Fe, Al and Mn oxides, and by pH. There was no influence of various anions (PO{sub 4}{sup 3-}, SO{sub 4}{sup 2-}, NO{sup 3-}, Cl{sup -} and HCO{sub 3}{sup -}) on As mobility when present in aqueous solution at concentrations analogous to those in the water of the Kyjov Brook. Plants growing in the impoundment had As concentrations 10-100 times greater than did the same plants growing in a relatively non-polluted area.

  15. Low-level radioactive waste disposal in the USA - Use of mill tailings impoundments as a new policy option

    International Nuclear Information System (INIS)

    Farrell, C.W.

    2006-01-01

    Disposal of low-level radioactive waste (LLW) in the United States is facing severe and immediate capacity limitations. Seemingly intractable regulatory and jurisdictional conflicts make establishment of new LLW disposal sites effectively impossible. Uranium mill tailings impoundments constructed at conventional uranium open-cast and underground mines could offer approximately 40 to 80+ million tons of disposal capacity for low activity radioactive waste. Such impoundments would provide an enhanced, high level of environmental and health and safety protection for the direct disposal of depleted uranium, special nuclear material, technologically-enhanced, naturally-occurring radioactive material (TENORM) and mixed waste. Many waste streams, such as TENORM and decommissioning rubble, will be high-volume, low activity materials and ideally suited for disposal in such structures. Materials in a given decay chain with a total activity from all radionuclides present of ∼820 Bq/g (2.22 x 10 -08 Ci/g) with no single radionuclide present in an activity greater than ∼104 Bq/g (2,800 pCi/g) should be acceptable for disposal. Materials of this type could be accepted without any site-specific dose modelling, so long as the total activity of the tailings impoundment not exceed its design capacity (generally 82 x 10 07 Bq/metric tonne) (0.020 Ci/short ton) and the cover design requirements to limit radon releases are satisfied. This paper provides background on US LLW disposal regulations, examines LLW disposal options under active consideration by the US Environmental Protection Agency and Department of Energy, develops generic waste acceptance criteria and identifies policy needs for federal and state governments to facilitate use of uranium mill tailings impoundments for LLW disposal. (author)

  16. Hypersalinity reduces the risk of cyanide toxicosis to insectivorous bats interacting with wastewater impoundments at gold mines.

    Science.gov (United States)

    Griffiths, Stephen R; Donato, David B; Lumsden, Linda F; Coulson, Graeme

    2014-01-01

    Wildlife and livestock that ingest bioavailable cyanide compounds in gold mining tailings dams are known to experience cyanide toxicosis. Elevated levels of salinity in open impoundments have been shown to prevent wildlife cyanide toxicosis by reducing drinking and foraging. This finding appears to be consistent for diurnal wildlife interacting with open impoundments, however the risks to nocturnal wildlife of cyanide exposure are unknown. We investigated the activity of insectivorous bats in the airspace above both fresh (potable to wildlife) and saline water bodies at two gold mines in the goldfields of Western Australian. During this study, cyanide-bearing solutions stored in open impoundments at both mine sites were hypersaline (range=57,000-295,000 mg/L total dissolved solids (TDS)), well above known physiological tolerance of any terrestrial vertebrate. Bats used the airspace above each water body monitored, but were more active at fresh than saline water bodies. In addition, considerably more terminal echolocation buzz calls were recorded in the airspace above fresh than saline water bodies at both mine sites. However, it was not possible to determine whether these buzz calls corresponded to foraging or drinking bouts. No drinking bouts were observed in 33 h of thermal video footage recorded at one hypersaline tailings dam, suggesting that this water is not used for drinking. There is no information on salinity tolerances of bats, but it could be assumed that bats would not tolerate salinity in drinking water at concentrations greater than those documented as toxic for saline-adapted terrestrial wildlife. Therefore, when managing wastewater impoundments at gold mines to avoid wildlife mortalities, adopting a precautionary principle, bats are unlikely to drink solutions at salinity levels ≥50,000 mg/L TDS. © 2013 Published by Elsevier Inc.

  17. Design and performance evaluation of a 1000-year evapotranspiration-capillary surface barrier.

    Science.gov (United States)

    Zhang, Zhuanfang Fred; Strickland, Christopher E; Link, Steven O

    2017-02-01

    Surface barrier technology is used to isolate radioactive waste and to reduce or eliminate recharge water to the waste zone for 1000 years or longer. However, the design and evaluation of such a barrier is challenging because of the extremely long design life. After establishing a set of design and performance objectives, a package of design solutions was developed for 1000-year surface barriers over nuclear waste sites. The Prototype Hanford Barrier (PHB) was then constructed in 1994 in the field over an existing waste site as a demonstration. The barrier was tested to evaluate surface-barrier design and performance at the field scale under conditions of enhanced and natural precipitation and of no vegetation. The monitoring data demonstrate that the barrier satisfied nearly all objectives in the past two decades. The PHB far exceeded the Resource Conservation and Recovery Act criteria, functioned in Hanford's semiarid climate, limited drainage to well below the 0.5 mm yr -1 performance criterion, limited runoff, and minimized erosion and bio-intrusion. Given the two-decade record of successful performance and consideration of the processes and mechanisms that could affect barrier stability and hydrology in the future, the results suggest the PHB is very likely to perform for its 1000-year design life. This conclusion is based on two assumptions: (1) the exposed subgrade receives protection against erosion and (2) institutional controls prevent inadvertent human activity at the barrier. The PHB design can serve as the basis for site-specific barriers over waste sites containing underground nuclear waste, uranium mine tailings, and hazardous mine waste. Copyright © 2016 Elsevier Ltd. All rights reserved.

  18. Modeling and Simulation of Long-Term Performance of Near-Surface Barriers

    International Nuclear Information System (INIS)

    Piet, S. J.; Jacobson, J. J.; Martian, P.; Martineau, R.; Soto, R.

    2003-01-01

    Society has and will continue to generate hazardous wastes whose risks must be managed. For exceptionally toxic, long-lived, and feared waste, the solution is deep burial, e.g., deep geological disposal at Yucca Mtn. For some waste, recycle or destruction/treatment is possible. The alternative for other wastes is storage at or near the ground level (in someone's back yard); most of these storage sites include a surface barrier (cap) to prevent migration of the waste due to infiltration of surface water. The design lifespan for such barriers ranges from 30 to 1000 years, depending on hazard and regulations. In light of historical performance, society needs a better basis for predicting barrier performance over long time periods and tools for optimizing maintenance of barriers while in service. We believe that, as in other industries, better understanding of the dynamics of barrier system degradation will enable improved barriers (cheaper, longer-lived, simpler, easier to maintain) and improved maintenance. We are focusing our research on earthen caps, especially those with evapo-transpiration and capillary breaks. Typical cap assessments treat the barrier's structure as static prior to some defined lifetime. Environmental boundary conditions such as precipitation and temperature are treated as time dependent. However, other key elements of the barrier system are regarded as constant, including engineered inputs (e.g., fire management strategy, irrigation, vegetation control), surface ecology (critical to assessment of plant transpiration), capillary break interface, material properties, surface erosion rate, etc. Further, to be conservative, only harmful processes are typically considered. A more holistic examination of both harmful and beneficial processes will provide more realistic pre-service prediction and in-service assessment of performance as well as provide designers a tool to encourage beneficial processes while discouraging harmful processes. Thus, the

  19. Modulation of Extreme Flood Levels by Impoundment Significantly Offset by Floodplain Loss Downstream of the Three Gorges Dam

    Science.gov (United States)

    Mei, Xuefei; Dai, Zhijun; Darby, Stephen E.; Gao, Shu; Wang, Jie; Jiang, Weiguo

    2018-04-01

    River flooding—the world's most significant natural hazard—is likely to increase under anthropogenic climate change. Most large rivers have been regulated by damming, but the extent to which these impoundments can mitigate extreme flooding remains uncertain. Here the catastrophic 2016 flood on the Changjiang River is first analyzed to assess the effects of both the Changjiang's reservoir cascade and the Three Gorges Dam (TGD), the world's largest hydraulic engineering project on downstream flood discharge and water levels. We show that the Changjiang's reservoir cascade impounded over 30.0 × 103 m3/s of flow at the peak of the flood on 25 July 2016, preventing the occurrence of what would otherwise have been the second largest flood ever recorded in the reach downstream of the TGD. Half of this flood water storage was retained by the TGD alone, meaning that impoundment by the TGD reduced peak water levels at the Datong hydrometric station (on 25 July) by 1.47 m, compared to pre-TGD conditions. However, downstream morphological changes, in particular, extensive erosion of the natural floodplain, offset this reduction in water level by 0.22 m, so that the full beneficial impact of floodwater retention by the TGD was not fully realized. Our results highlight how morphological adjustments downstream of large dams may inhibit their full potential to mitigate extreme flood risk.

  20. Evaluation of factors related to increased zooplankton biomass and altered species composition following impoundment of a Newfoundland reservoir

    International Nuclear Information System (INIS)

    Campbell, C.E.; Knoechel, R.; Copeman, D.

    1998-01-01

    An 11-year study of the zooplankton community in Cat Arm Hydroelectric Reservoir in Newfoundland was conducted to assess long-term zooplankton community dynamics in a subarctic system. Zooplankton biomass and species compositions were monitored from 1983 to 1993. The monitoring program documented the trophic evolution of the Cat Arm system as it changed from a shallow lake with short water retention time to a deep reservoir with a much lower flushing rate. Zooplankton biomass increased approximately 19-fold in the oligotrophic hydroelectric reservoir following impoundment in 1984, relative to biomass in the preexisting lake. During the first three years of impoundment, there were no increases in either phytoplankton biomass or primary productivity. Natality of the dominant cladoceran (Daphnia catawba) did not increase. Summer water retention time increased from pre-impoundment levels of 4 days in 1983 to 338 days in 1993. The study showed that zooplankton biomass was greatly correlated with water retention time, and showed no major correlation with phytoplankton biomass, primary productivity, nutrient concentrations, pH, colour, or epilimnetic temperature. It was concluded that changes in the zooplankton community in the hydroelectric reservoir were a result of decreases in losses due to washout. 41 refs., 2 tabs., 6 figs

  1. [Effects of Three Gorges Reservoir impoundment on the wetland ecosystem service value of Dongting Lake, South-central China].

    Science.gov (United States)

    Li, Jing-Bao; Dai, Yong; Yin, Ri-Xin; Yang, Yan; Li, Yu-dan; Wang, Ke-ying

    2013-03-01

    Based on the field investigation and measurement, and by using the monetary method, this paper estimated the wetland ecosystem service value of Dongting Lake before and after the impoundment of Three Gorges Reservoir (in 1996 and 2010, respectively). After the impoundment, the total ecosystem service value increased from 156.69x10(8) yuan in 1996 to 177.11x10(8) yuan in 2010. The main services value in 1996 was in the order of flood storage and regulation > water storage and supply > air regulation > scientific research and education, while that in 2010 was leisure tourism > shipping transportation > air regulation > water storage and supply. In the total service value of the wetland ecosystem, the direct value associated with water decreased from 110. 85x10(8) in 1996 to 27.47x10(8) in 2010, with a decrement of 75.2%. Though the proportion of the direct value in the production and supply of material products had somewhat increase, the indirect value in ecological environment regulation and maintenance and in culture and society still maintained at about 80% of the total value. In addition to climate factors, the impoundment of Three Gorges Reservoir and the reduction of water and sediment from Yangtze River to the Lake were the crucial reasons leading to the changes of the wetland ecosystem service value of Dongting Lake.

  2. Chloride Penetration through Cracks in High-Performance Concrete and Surface Treatment System for Crack Healing

    Directory of Open Access Journals (Sweden)

    In-Seok Yoon

    2012-01-01

    Full Text Available For enhancing the service life of concrete structures, it is very important to minimize crack at surface. Even if these cracks are very small, the problem is to which extend these cracks may jeopardize the durability of these decks. It was proposed that crack depth corresponding with critical crack width from the surface is a crucial factor in view of durability design of concrete structures. It was necessary to deal with chloride penetration through microcracks characterized with the mixing features of concrete. This study is devoted to examine the effect of high strength concrete and reinforcement of steel fiber on chloride penetration through cracks. High strength concrete is regarded as an excellent barrier to resist chloride penetration. However, durability performance of cracked high strength concrete was reduced seriously up to that of ordinary cracked concrete. Steel fiber reinforcement is effective to reduce chloride penetration through cracks because steel fiber reinforcement can lead to reduce crack depth significantly. Meanwhile, surface treatment systems are put on the surface of the concrete in order to seal the concrete. The key-issue is to which extend a sealing is able to ensure that chloride-induced corrosion can be prevented. As a result, penetrant cannot cure cracks, however, coating and combined treatment can prevent chloride from flowing in concrete with maximum crack width of 0.06 mm and 0.08 mm, respectively.

  3. Optimizing pentacene thin-film transistor performance: Temperature and surface condition induced layer growth modification.

    Science.gov (United States)

    Lassnig, R; Hollerer, M; Striedinger, B; Fian, A; Stadlober, B; Winkler, A

    2015-11-01

    In this work we present in situ electrical and surface analytical, as well as ex situ atomic force microscopy (AFM) studies on temperature and surface condition induced pentacene layer growth modifications, leading to the selection of optimized deposition conditions and entailing performance improvements. We prepared p ++ -silicon/silicon dioxide bottom-gate, gold bottom-contact transistor samples and evaluated the pentacene layer growth for three different surface conditions (sputtered, sputtered + carbon and unsputtered + carbon) at sample temperatures during deposition of 200 K, 300 K and 350 K. The AFM investigations focused on the gold contacts, the silicon dioxide channel region and the highly critical transition area. Evaluations of coverage dependent saturation mobilities, threshold voltages and corresponding AFM analysis were able to confirm that the first 3-4 full monolayers contribute to the majority of charge transport within the channel region. At high temperatures and on sputtered surfaces uniform layer formation in the contact-channel transition area is limited by dewetting, leading to the formation of trenches and the partial development of double layer islands within the channel region instead of full wetting layers. By combining the advantages of an initial high temperature deposition (well-ordered islands in the channel) and a subsequent low temperature deposition (continuous film formation for low contact resistance) we were able to prepare very thin (8 ML) pentacene transistors of comparably high mobility.

  4. The impact of surface chemistry on the performance of localized solar-driven evaporation system.

    Science.gov (United States)

    Yu, Shengtao; Zhang, Yao; Duan, Haoze; Liu, Yanming; Quan, Xiaojun; Tao, Peng; Shang, Wen; Wu, Jianbo; Song, Chengyi; Deng, Tao

    2015-09-04

    This report investigates the influence of surface chemistry (or wettability) on the evaporation performance of free-standing double-layered thin film on the surface of water. Such newly developed evaporation system is composed of top plasmonic light-to-heat conversion layer and bottom porous supporting layer. Under solar light illumination, the induced plasmonic heat will be localized within the film. By modulating the wettability of such evaporation system through the control of surface chemistry, the evaporation rates are differentiated between hydrophilized and hydrophobized anodic aluminum oxide membrane-based double layered thin films. Additionally, this work demonstrated that the evaporation rate mainly depends on the wettability of bottom supporting layer rather than that of top light-to-heat conversion layer. The findings in this study not only elucidate the role of surface chemistry of each layer of such double-layered evaporation system, but also provide additional design guidelines for such localized evaporation system in applications including desalination, distillation and power generation.

  5. The Effect of Laser Surface Reconstruction of Disordered Carbons on Performance

    International Nuclear Information System (INIS)

    EVEN JR., WILLIAM R.; GUIDOTTI, RONALD A.

    1999-01-01

    The reconstruction of the surface of disordered carbons was examined by heating carbons derived from polymethacrylonitrile (PMAN) and divinylbenzene (DVB) with a pulsed infrared laser in an argon or helium atmosphere, both fluidized and under static conditions. By graphitizing the outer surface of the carbons, it was hoped to reduce the high first-cycle losses associated with such disordered materials in Li-ion cells. The power to the sample was varied to observed the effects on surface morphology and electrochemical performance in 1M LiPF(sub 6) ethylene carbonate-dimethyl carbonate. The use various reactive atmosphere such as ethylene, 2-vinylpyridine, pyrrole, and furfuryl alcohol were also evaluated as an alternative means of hopefully forming a thin graphitic layer on the carbon particles to reduce first-cycle irreversibility. While some improvement was realized, these losses were still unacceptably high. The laser heating did improve the rate capabilities of the carbons, however. More work in this area is necessary to fully understand surface and bulk effects

  6. EXPERIMENTAL EVALUATION OF THE THERMAL PERFORMANCE OF A WATER SHIELD FOR A SURFACE POWER REACTOR

    International Nuclear Information System (INIS)

    Reid, Robert S.; Pearson, J. Bosie; Stewart, Eric T.

    2007-01-01

    Water based reactor shielding is being investigated for use on initial lunar surface power systems. A water shield may lower overall cost (as compared to development cost for other materials) and simplify operations in the setup and handling. The thermal hydraulic performance of the shield is of significant interest. The mechanism for transferring heat through the shield is natural convection. Natural convection in a 100 kWt lunar surface reactor shield design is evaluated with 2 kW power input to the water in the Water Shield Testbed (WST) at the NASA Marshall Space Flight Center. The experimental data from the WST is used to validate a CFD model. Performance of the water shield on the lunar surface is then predicted with a CFD model anchored to test data. The experiment had a maximum water temperature of 75 C. The CFD model with 1/6-g predicts a maximum water temperature of 88 C with the same heat load and external boundary conditions. This difference in maximum temperature does not greatly affect the structural design of the shield, and demonstrates that it may be possible to use water for a lunar reactor shield.

  7. Simulating the performance of a distance-3 surface code in a linear ion trap

    Science.gov (United States)

    Trout, Colin J.; Li, Muyuan; Gutiérrez, Mauricio; Wu, Yukai; Wang, Sheng-Tao; Duan, Luming; Brown, Kenneth R.

    2018-04-01

    We explore the feasibility of implementing a small surface code with 9 data qubits and 8 ancilla qubits, commonly referred to as surface-17, using a linear chain of 171Yb+ ions. Two-qubit gates can be performed between any two ions in the chain with gate time increasing linearly with ion distance. Measurement of the ion state by fluorescence requires that the ancilla qubits be physically separated from the data qubits to avoid errors on the data due to scattered photons. We minimize the time required to measure one round of stabilizers by optimizing the mapping of the two-dimensional surface code to the linear chain of ions. We develop a physically motivated Pauli error model that allows for fast simulation and captures the key sources of noise in an ion trap quantum computer including gate imperfections and ion heating. Our simulations showed a consistent requirement of a two-qubit gate fidelity of ≥99.9% for the logical memory to have a better fidelity than physical two-qubit operations. Finally, we perform an analysis of the error subsets from the importance sampling method used to bound the logical error rates to gain insight into which error sources are particularly detrimental to error correction.

  8. Studies on Gas Sensing Performance of Pure and Surface Chrominated Indium Oxide Thick Film Resistors

    Directory of Open Access Journals (Sweden)

    D. N. CHAVAN

    2010-12-01

    Full Text Available The thick films of AR grade In2O3 were prepared by standard screen-printing technique. The gas sensing performance of thick film was tested for various gases. It showed maximum gas response to ethanol vapor at 350 oC for 80 ppm. To improve the gas response and selectivity of the film towards a particular gas, In2O3 thick films were modified by dipping them in an aqueous solution of 0.1 M CrO3 for different intervals of time. The surface chrominated (20 min In2O3 thick film showed maximum response to H2S gas (40 ppm than pure In2O3 thick film at 250 oC. Chromium oxide on the surface of the film shifts the gas response from ethanol vapor to H2S gas. A systematic study of sensing performance of the sensor indicates the key role played by chromium oxide on the surface of thick film. The selectivity, gas response and recovery time of the sensor were measured and presented.

  9. EXPERIMENTAL EVALUATION OF THE THERMAL PERFORMANCE OF A WATER SHIELD FOR A SURFACE POWER REACTOR

    Energy Technology Data Exchange (ETDEWEB)

    REID, ROBERT S. [Los Alamos National Laboratory; PEARSON, J. BOSIE [Los Alamos National Laboratory; STEWART, ERIC T. [Los Alamos National Laboratory

    2007-01-16

    Water based reactor shielding is being investigated for use on initial lunar surface power systems. A water shield may lower overall cost (as compared to development cost for other materials) and simplify operations in the setup and handling. The thermal hydraulic performance of the shield is of significant interest. The mechanism for transferring heat through the shield is natural convection. Natural convection in a 100 kWt lunar surface reactor shield design is evaluated with 2 kW power input to the water in the Water Shield Testbed (WST) at the NASA Marshall Space Flight Center. The experimental data from the WST is used to validate a CFD model. Performance of the water shield on the lunar surface is then predicted with a CFD model anchored to test data. The experiment had a maximum water temperature of 75 C. The CFD model with 1/6-g predicts a maximum water temperature of 88 C with the same heat load and external boundary conditions. This difference in maximum temperature does not greatly affect the structural design of the shield, and demonstrates that it may be possible to use water for a lunar reactor shield.

  10. Experimental Evaluation of the Thermal Performance of a Water Shield for a Surface Power Reactor

    International Nuclear Information System (INIS)

    Pearson, J. Boise; Stewart, Eric T.; Reid, Robert S.

    2007-01-01

    Water based reactor shielding is being investigated for use on initial lunar surface power systems. A water shield may lower overall cost (as compared to development cost for other materials) and simplify operations in the setup and handling. The thermal hydraulic performance of the shield is of significant interest. The mechanism for transferring heat through the shield is natural convection. Natural convection in a 100 kWt lunar surface reactor shield design is evaluated with 2 kW power input to the water in the Water Shield Testbed (WST) at the NASA Marshall Space Flight Center. The experimental data from the WST is used to validate a CFD model. Performance of the water shield on the lunar surface is then predicted with a CFD model anchored to test data. The experiment had a maximum water temperature of 75 deg. C. The CFD model with 1/6-g predicts a maximum water temperature of 88 deg. C with the same heat load and external boundary conditions. This difference in maximum temperature does not greatly affect the structural design of the shield, and demonstrates that it may be possible to use water for a lunar reactor shield

  11. Improving Dry Powder Inhaler Performance by Surface Roughening of Lactose Carrier Particles.

    Science.gov (United States)

    Tan, Bernice Mei Jin; Chan, Lai Wah; Heng, Paul Wan Sia

    2016-08-01

    This study investigated the impact of macro-scale carrier surface roughness on the performance of dry powder inhaler (DPI) formulations. Fluid-bed processing and roller compaction were explored as processing methods to increase the surface roughness (Ra) of lactose carrier particles. DPI formulations containing either (a) different concentrations of fine lactose at a fixed concentration of micronized drug (isoniazid) or (b) various concentrations of drug in the absence of fine lactose were prepared. The fine particle fraction (FPF) and aerodynamic particle size of micronized drug of all formulations were determined using the Next Generation Impactor. Fluid-bed processing resulted in a modest increase in the Ra from 562 to 907 nm while roller compaction led to significant increases in Ra > 1300 nm. The roller compacted carriers exhibited FPF > 35%, which were twice that of the smoothest carriers. The addition of up to 5%, w/w of fine lactose improved the FPF of smoother carriers by 60-200% whereas only lactose carrier particles by roller compaction was immensely beneficial to improving DPI performance, primarily due to increased surface roughness at the macro-scale.

  12. Binder-induced surface structure evolution effects on Li-ion battery performance

    Science.gov (United States)

    Rezvani, S. J.; Pasqualini, M.; Witkowska, A.; Gunnella, R.; Birrozzi, A.; Minicucci, M.; Rajantie, H.; Copley, M.; Nobili, F.; Di Cicco, A.

    2018-03-01

    A comparative investigation on binder induced chemical and morphological evolution of Li4Ti5O12 electrodes was performed via X-ray photoemission spectroscopy, scanning electron microscopy, and electrochemical measurements. Composite electrodes were obtained using three different binders (PAA, PVdF, and CMC) with 80:10:10 ratio of active material:carbon:binder. The electrochemical performances of the electrodes, were found to be intimately correlated with the evolution of the microstructure of the electrodes, probed by XPS and SEM analysis. Our analysis shows that the surface chemistry, thickness of the passivation layers and the morphology of the electrodes are strongly dependent on the type of binders that significantly influence the electrochemical properties of the electrodes. These results point to a key role played by binders in optimization of the battery performance and improve our understanding of the previously observed and unexplained electrochemical properties of these electrodes.

  13. The role of diffusive architectural surfaces on auditory spatial discrimination in performance venues.

    Science.gov (United States)

    Robinson, Philip W; Pätynen, Jukka; Lokki, Tapio; Jang, Hyung Suk; Jeon, Jin Yong; Xiang, Ning

    2013-06-01

    In musical or theatrical performance, some venues allow listeners to individually localize and segregate individual performers, while others produce a well blended ensemble sound. The room acoustic conditions that make this possible, and the psycho-acoustic effects at work are not fully understood. This research utilizes auralizations from measured and simulated performance venues to investigate spatial discrimination of multiple acoustic sources in rooms. Signals were generated from measurements taken in a small theater, and listeners in the audience area were asked to distinguish pairs of speech sources on stage with various spatial separations. This experiment was repeated with the proscenium splay walls treated to be flat, diffusive, or absorptive. Similar experiments were conducted in a simulated hall, utilizing 11 early reflections with various characteristics, and measured late reverberation. The experiments reveal that discriminating the lateral arrangement of two sources is possible at narrower separation angles when reflections come from flat or absorptive rather than diffusive surfaces.

  14. Effect of fishing effort on catch rate and catchability of largemouth bass in small impoundments

    Science.gov (United States)

    Wegener, M. G.; Schramm, Harold; Neal, J. W.; Gerard, P.D.

    2018-01-01

    Largemouth bass Micropterus salmoides (Lacepède) catch rates decline with sustained fishing effort, even without harvest. It is unclear why declines in catch rate occur, and little research has been directed at how to improve catch rate. Learning has been proposed as a reason for declining catch rate, but has never been tested on largemouth bass. If catch rate declines because fish learn to avoid lures, periods of no fishing could be a management tool for increasing catch rate. In this study, six small impoundments with established fish populations were fished for two May to October fishing seasons to evaluate the effect of fishing effort on catch rate. Closed seasons were implemented to test whether a 2‐month period of no fishing improved catch rates and to determine whether conditioning from factors other than being captured reduced catch rate. Mixed‐model analysis indicated catch rate and catchability declined throughout the fishing season. Catch rate and catchability increased after a 2‐month closure but soon declined to the lowest levels of the fishing season. These changes in catch rate and catchability support the conclusion of learned angler avoidance, but sustained catchability of fish not previously caught does not support that associative or social learning affected catchability.

  15. Evidence for serial discontinuity in the fish community of a heavily impounded river

    Science.gov (United States)

    Miranda, Leandro E.; Dembkowski, D.J.

    2016-01-01

    In the Tennessee River, USA, we examined lengthwise patterns in fish community structure and species richness within and among nine reservoirs organized in sequence and connected through navigational locks. Within reservoirs, the riverine, transition and lacustrine zones supported distinct, although overlapping, nearshore fish assemblages; differences were also reflected in measures of species richness. Spatial patterns were most apparent for rheophilic species, which increased in species richness and representation upstream within each reservoir and downstream across the chain of reservoirs. This pattern resembled a sawtooth wave, with the amplitude of the wave peaking in the riverine zone below each dam, and progressively higher wave amplitude developing downstream in the reservoir chain. The observed sawtooth pattern supports the serial discontinuity concept in that the continuity of the riverine fish community is interrupted by the lacustrine conditions created behind each dam. Upstream within each reservoir, and downstream in the chain of reservoirs, habitat characteristics become more riverine. To promote sustainability of rheophilic fishes and maintain biodiversity in impounded rivers, conservation plans could emphasize maintenance and preservation of riverine environments of the reservoir's upper reaches, while remaining cognizant of the broader basin trends that provide opportunities for a lengthwise array of conservation and management policy. 

  16. Survivability of ancient man-made earthen mounds: implications for uranium mill tailings impoundments

    International Nuclear Information System (INIS)

    Lindsey, C.G.; Mishima, J.; King, S.E.; Walters, W.H.

    1983-06-01

    As part of a study for the Nuclear Regulatory Commission (NRC), the Pacific Northwest Laboratory (PNL) is investigating long-term stabilization techniques for uranium mill impoundments. Part of this investigation involves the design of a rock armoring blanket (riprap) to mitigate wind and water erosion of the underlying soil cover, which in turn prevents exposure of the tailings to the environment. However, the need for the armoring blanket, as well as the blanket's effectiveness, depends on the stability of the underlying soil cap (radon suppression cover) and on the tailings themselves. Compelling evidence in archaeological records suggests that large man-made earthen structures can remain sound and intact for time periods comparable to those required for the stabilization of the tailings piles if properly constructed. We present archaeological evidence on the existence and survivability of man-made earthen and rock structures through specific examples of such structures from around the world. We also review factors contributing to their survival or destruction and address the influence of climate, building materials, and construction techniques on survivability

  17. Methane Oxidation and Molecular Characterization of Methanotrophs from a Former Mercury Mine Impoundment

    Directory of Open Access Journals (Sweden)

    Shaun M. Baesman

    2015-06-01

    Full Text Available The Herman Pit, once a mercury mine, is an impoundment located in an active geothermal area. Its acidic waters are permeated by hundreds of gas seeps. One seep was sampled and found to be composed of mostly CO2 with some CH4 present. The δ13CH4 value suggested a complex origin for the methane: i.e., a thermogenic component plus a biological methanogenic portion. The relatively 12C-enriched CO2 suggested a reworking of the ebullitive methane by methanotrophic bacteria. Therefore, we tested bottom sediments for their ability to consume methane by conducting aerobic incubations of slurried materials. Methane was removed from the headspace of live slurries, and subsequent additions of methane resulted in faster removal rates. This activity could be transferred to an artificial, acidic medium, indicating the presence of acidophilic or acid-tolerant methanotrophs, the latter reinforced by the observation of maximum activity at pH = 4.5 with incubated slurries. A successful extraction of sterol and hopanoid lipids characteristic of methanotrophs was achieved, and their abundances greatly increased with increased sediment methane consumption. DNA extracted from methane-oxidizing enrichment cultures was amplified and sequenced for pmoA genes that aligned with methanotrophic members of the Gammaproteobacteria. An enrichment culture was established that grew in an acidic (pH 4.5 medium via methane oxidation.

  18. Methane oxidation and molecular characterization of methanotrophs from a former mercury mine impoundment

    Science.gov (United States)

    Baesman, Shaun; Miller, Laurence G.; Wei, Jeremy H.; Cho, Yirang; Matys, Emily D.; Summons, Roger E.; Welander, Paula V.; Oremland, Ronald S.

    2015-01-01

    The Herman Pit, once a mercury mine, is an impoundment located in an active geothermal area. Its acidic waters are permeated by hundreds of gas seeps. One seep was sampled and found to be composed of mostly CO2 with some CH4 present. The δ13CH4 value suggested a complex origin for the methane: i.e., a thermogenic component plus a biological methanogenic portion. The relatively 12C-enriched CO2 suggested a reworking of the ebullitive methane by methanotrophic bacteria. Therefore, we tested bottom sediments for their ability to consume methane by conducting aerobic incubations of slurried materials. Methane was removed from the headspace of live slurries, and subsequent additions of methane resulted in faster removal rates. This activity could be transferred to an artificial, acidic medium, indicating the presence of acidophilic or acid-tolerant methanotrophs, the latter reinforced by the observation of maximum activity at pH = 4.5 with incubated slurries. A successful extraction of sterol and hopanoid lipids characteristic of methanotrophs was achieved, and their abundances greatly increased with increased sediment methane consumption. DNA extracted from methane-oxidizing enrichment cultures was amplified and sequenced for pmoA genes that aligned with methanotrophic members of the Gammaproteobacteria. An enrichment culture was established that grew in an acidic (pH 4.5) medium via methane oxidation.

  19. The Effect of Zebra Mussels on Algal Community Structure in an Impounded River System

    Science.gov (United States)

    Trumble, A. F.; Luttenton, M.

    2005-05-01

    The zebra mussel, Dreissena polymorpha, invaded the Great Lakes Region in the mid 1980's, and subsequently colonized inland lakes and coastal river systems through secondary invasions. The Muskegon River below Croton Dam was colonized by zebra mussels in 2000 following their introduction into Croton impoundment in the late 1990's. No zebra mussels were found below Croton Dam in 1999 but had increased to 25,000 m-2 by 2001. We examined the affect of zebra mussels on epilithic periphyton communities by comparing plots that were and were not colonized by zebra mussels. Chlorophyll a increased in both treatments over time but was significantly higher in control plots than in zebra mussel plots. The concentration of chlorophyll a in the control plots increased from 14 µgcm-2 to 26 µgcm-2 and the concentration in the zebra mussel plots started at 12 µgcm-2, peaked at 19 µgcm-2, and then decreased to 15 µgcm-2 over a 6 week period. In a related experiment using artificial streams, chlorophyll a increased with increasing zebra mussel density, but differences were not significant. The different trends observed between the two experiments may be explained in part by arthropod invertebrates associated with zebra mussel populations.

  20. Quantifying downstream impacts of impoundment on flow regime and channel planform, lower Trinity River, Texas

    Science.gov (United States)

    Wellmeyer, Jessica L.; Slattery, Michael C.; Phillips, Jonathan D.

    2005-07-01

    As human population worldwide has grown, so has interest in harnessing and manipulating the flow of water for the benefit of humans. The Trinity River of eastern Texas is one such watershed greatly impacted by engineering and urbanization. Draining the Dallas-Fort Worth metroplex, just under 30 reservoirs are in operation in the basin, regulating flow while containing public supplies, supporting recreation, and providing flood control. Lake Livingston is the lowest, as well as largest, reservoir in the basin, a mere 95 km above the Trinity's outlet near Galveston Bay. This study seeks to describe and quantify channel activity and flow regime, identifying effects of the 1968 closure of Livingston dam. Using historic daily and peak discharge data from USGS gauging stations, flow duration curves are constructed, identifying pre- and post-dam flow conditions. A digital historic photo archive was also constructed using six sets of aerial photographs spanning from 1938 to 1995, and three measures of channel activity applied using a GIS. Results show no changes in high flow conditions following impoundment, while low flows are elevated. However, the entire post-dam period is characterized by significantly higher rainfall, which may be obscuring the full impact of flow regulation. Channel activity rates do not indicate a more stabilized planform following dam closure; rather they suggest that the Trinity River is adjusting itself to the stress of Livingston dam in a slow, gradual process that may not be apparent in a modern time scale.

  1. Automated Surface Classification of SRF Cavities for the Investigation of the Influence of Surface Properties onto the Operational Performance

    International Nuclear Information System (INIS)

    Wenskat, Marc

    2015-07-01

    Superconducting niobium radio-frequency cavities are fundamental for the European XFEL and the International Linear Collider. To use the operational advantages of superconducting cavities, the inner surface has to fulfill quite demanding requirements. The surface roughness and cleanliness improved over the last decades and with them, the achieved maximal accelerating field. Still, limitations of the maximal achieved accelerating field are observed, which are not explained by localized geometrical defects or impurities. The scope of this thesis is a better understanding of these limitations in defect free cavities based on global, rather than local, surface properties. For this goal, more than 30 cavities underwent subsequent surface treatments, cold RF tests and optical inspections within the ILC-HiGrade research program and the XFEL cavity production. An algorithm was developed which allows an automated surface characterization based on an optical inspection robot. This algorithm delivers a set of optical surface properties, which describes the inner cavity surface. These optical surface properties deliver a framework for a quality assurance of the fabrication procedures. Furthermore, they shows promising results for a better understanding of the observed limitations in defect free cavities.

  2. Automated Surface Classification of SRF Cavities for the Investigation of the Influence of Surface Properties onto the Operational Performance

    Energy Technology Data Exchange (ETDEWEB)

    Wenskat, Marc

    2015-07-15

    Superconducting niobium radio-frequency cavities are fundamental for the European XFEL and the International Linear Collider. To use the operational advantages of superconducting cavities, the inner surface has to fulfill quite demanding requirements. The surface roughness and cleanliness improved over the last decades and with them, the achieved maximal accelerating field. Still, limitations of the maximal achieved accelerating field are observed, which are not explained by localized geometrical defects or impurities. The scope of this thesis is a better understanding of these limitations in defect free cavities based on global, rather than local, surface properties. For this goal, more than 30 cavities underwent subsequent surface treatments, cold RF tests and optical inspections within the ILC-HiGrade research program and the XFEL cavity production. An algorithm was developed which allows an automated surface characterization based on an optical inspection robot. This algorithm delivers a set of optical surface properties, which describes the inner cavity surface. These optical surface properties deliver a framework for a quality assurance of the fabrication procedures. Furthermore, they shows promising results for a better understanding of the observed limitations in defect free cavities.

  3. Drag-reducing performance of obliquely aligned superhydrophobic surface in turbulent channel flow

    Energy Technology Data Exchange (ETDEWEB)

    Watanabe, Sho; Fukagata, Koji [Department of Mechanical Engineering, Keio University, Hiyoshi 3-14-1, Kohoku-ku, Yokohama 223-8522 (Japan); Mamori, Hiroya, E-mail: fukagata@mech.keio.ac.jp [Department of Mechanical Engineering, Tokyo University of Science, Niijuku 6-3-1, Katsushika-ku, Tokyo 125-8585 (Japan)

    2017-04-15

    Friction drag reduction effect by superhydrophobic surfaces in a turbulent channel flow is investigated by means of direct numerical simulation. The simulations are performed under a constant pressure gradient at the friction Reynolds number of 180. A special focus is laid upon the influence of the angle of microridge structure to flow direction, while the gas area fraction on the surface is kept at 50% and the groove width is kept constant at 33.75 wall units. Larger drag reduction effect is observed for a smaller angle: the bulk-mean velocity is increased about 15% when the microridge is parallel to the flow. The drag reduction effect is found to deteriorate rapidly with the microridge angle due to a decrease in the slip velocity. The Reynolds stress budgets show that the modification in each physical effect is qualitatively similar but more pronounced when the microridge is aligned with the stream. (paper)

  4. Cavity-enhanced surface-plasmon resonance sensing: modeling and performance

    International Nuclear Information System (INIS)

    Giorgini, A; Avino, S; Malara, P; Zullo, R; Gagliardi, G; Homola, J; De Natale, P

    2014-01-01

    We investigate the performance of a surface-plasmon-resonance refractive-index (RI) sensor based on an optical resonator. The resonator transforms RI changes of liquid samples, interacting with the surface plasmon excited by near-infrared light, into a variation of the intra-cavity optical loss. Cavity ring-down measurements are provided as a proof of concept of RI sensing on calibrated mixtures. A characterization of the overall sensor response and noise features as well as a discussion on possible improvements is carried out. A reproducibility analysis shows that a resolution of 10 −7 –10 −8  RIU is within reach over observation times of 1–30 s. The ultimate resolution is set only by intrinsic noise features of the cavity-based method, pointing to a potential limit below 10 −10  RIU/√Hz. (paper)

  5. Performance of a novel SQUID-based superconducting imaging-surface magnetoencephalography system

    Science.gov (United States)

    Kraus, R. H.; Volegov, P.; Maharajh, K.; Espy, M. A.; Matlashov, A. N.; Flynn, E. R.

    2002-03-01

    Performance for a recently completed whole-head magnetoencephalography system using a superconducting imaging surface (SIS) surrounding an array of 150 SQUID magnetometers is reported. The helmet-like SIS is hemispherical in shape with a brim. Conceptually, the SIS images nearby sources onto the SQUIDs while shielding sensors from distant “noise” sources. A finite element method (FEM) description using the as-built geometry was developed to describe the SIS effect on source fields by imposing B⊥( surface)=0 . Sensors consist of 8×8 mm 2 SQUID magnetometers with 0.84 nT/ Φ0 sensitivity and positions and orientations was found. Good agreement was found between modeled and measured shielding of the SQUIDs from sources external to the array showing significant frequency-independent shielding. Phantom localization precision was better than 0.5 mm at all locations with a mean of better than 0.3 mm.

  6. Aggregation performance of CdO grains grown on surface of N silicon crystal

    International Nuclear Information System (INIS)

    Zhang Jizhong; Zhao Huan

    2010-01-01

    Four kinds of aggregation patterns of CdO grains were formed on the surface of N silicon substrate heated at 580 deg. C for 1 h in an evaporation-deposition device. They were ellipse-shaped or quasi-circular-shaped aggregate, long ribbon-shaped aggregate, long chain-shaped or long double-chain-shaped aggregate, and long ellipse-chain-shaped aggregate. These aggregates consisted of numerous grains or tiny crystals, and deposited on top of the CdO bush-like long crystal clusters grown earlier. They exhibited clearly spontaneous self-organization aggregation performance. Surface defects of the virgin N silicon crystal were analyzed, and mechanism of the self-organization aggregation was discussed with a defect induced aggregation (DIA) model.

  7. Enhancing performance and surface antifouling properties of polysulfone ultrafiltration membranes with salicylate-alumoxane nanoparticles

    Science.gov (United States)

    Mokhtari, Samaneh; Rahimpour, Ahmad; Shamsabadi, Ahmad Arabi; Habibzadeh, Setareh; Soroush, Masoud

    2017-01-01

    To improve the hydrophilicity and antifouling properties of polysulfone (PS) ultrafiltration membranes, we studied the use of salicylate-alumoxane (SA) nanoparticles as a novel hydrophilic additive. The effects of SA nanoparticles on the membrane characteristics and performance were investigated in terms of membrane structure, permeation flux, solute rejection, hydrophilicity, and antifouling ability. The new mixed-matrix membranes (MMMs) possess asymmetric structures. They have smaller finger-like pores and smoother surfaces than the neat PS membranes. The embedment of SA nanoparticles in the polymer matrix and the improvement of surface hydrophilicity were investigated. Ultrafiltration experiments indicated that the pure-water flux of the new MMMs initially increases with SA nanoparticles loading followed by a decrease at high loadings. Higher BSA solution flux was achieved for the MMMs compared to the neat PS membranes. Membranes with 1 wt.% SA nanoparticles exhibit the highest flux recovery ratio of 87% and the lowest irreversible fouling of 13%.

  8. Why did the bear cross the road? Comparing the performance of multiple resistance surfaces and connectivity modeling methods

    Science.gov (United States)

    Samuel A. Cushman; Jesse S. Lewis; Erin L. Landguth

    2014-01-01

    There have been few assessments of the performance of alternative resistance surfaces, and little is known about how connectivity modeling approaches differ in their ability to predict organism movements. In this paper, we evaluate the performance of four connectivity modeling approaches applied to two resistance surfaces in predicting the locations of highway...

  9. The influence of log soaking temperature on surface quality and integrity performance of birch (Betula pendula Roth) veneer

    Science.gov (United States)

    Anti Rohumaa; Toni Antikainen; Christopher G. Hunt; Charles R. Frihart; Mark Hughes

    2016-01-01

    Wood material surface properties play an important role in adhesive bond formation and performance. In the present study, a test method was developed to evaluate the integrity of the wood surface, and the results were used to understand bond performance. Materials used were rotary cut birch (Betula pendula Roth) veneers, produced from logs soaked at 20 or 70 °C prior...

  10. Photo-induced surface modification to improve the performance of lead sulfide quantum dot solar cell.

    Science.gov (United States)

    Tulsani, Srikanth Reddy; Rath, Arup Kumar

    2018-07-15

    The solution-processed quantum dot (QD) solar cell technology has seen significant advancements in recent past to emerge as a potential contender for the next generation photovoltaic technology. In the development of high performance QD solar cell, the surface ligand chemistry has played the important role in controlling the doping type and doping density of QD solids. For instance, lead sulfide (PbS) QDs which is at the forefront of QD solar cell technology, can be made n-type or p-type respectively by using iodine or thiol as the surfactant. The advancements in surface ligand chemistry enable the formation of p-n homojunction of PbS QDs layers to attain high solar cell performances. It is shown here, however, that poor Fermi level alignment of thiol passivated p-type PbS QD hole transport layer with the n-type PbS QD light absorbing layer has rendered the photovoltaic devices from realizing their full potential. Here we develop a control surface oxidation technique using facile ultraviolet ozone treatment to increase the p-doping density in a controlled fashion for the thiol passivated PbS QD layer. This subtle surface modification tunes the Fermi energy level of the hole transport layer to deeper values to facilitate the carrier extraction and voltage generation in photovoltaic devices. In photovoltaic devices, the ultraviolet ozone treatment resulted in the average gain of 18% in the power conversion efficiency with the highest recorded efficiency of 8.98%. Copyright © 2018 Elsevier Inc. All rights reserved.

  11. High Performance Carbon Nanotube Yarn Supercapacitors with a Surface-Oxidized Copper Current Collector.

    Science.gov (United States)

    Zhang, Daohong; Wu, Yunlong; Li, Ting; Huang, Yin; Zhang, Aiqing; Miao, Menghe

    2015-11-25

    Threadlike linear supercapacitors have demonstrated high potential for constructing fabrics to power electronic textiles (eTextiles). To improve the cyclic electrochemical performance and to produce power fabrics large enough for practical applications, a current collector has been introduced into the linear supercapcitors to transport charges produced by active materials along the length of the supercapacitor with high efficiency. Here, we first screened six candidate metal filaments (Pt, Au, Ag, AuAg, PtCu, and Cu) as current collectors for carbon nanotube (CNT) yarn-based linear supercapacitors. Although all of the metal filaments significantly improved the electrochemical performance of the linear supercapacitor, two supercapacitors constructed from Cu and PtCu filaments, respectively, demonstrate far better electrochemical performance than the other four supercapacitors. Further investigation shows that the surfaces of the two Cu-containing filaments are oxidized by the surrounding polymer electrolyte in the electrode. While the unoxidized core of the Cu-containing filaments remains highly conductive and functions as a current collector, the resulting CuO on the surface is an electrochemically active material. The linear supercapacitor architecture incorporating dual active materials CNT + Cu extends the potential window from 1.0 to 1.4 V, leading to significant improvement to the energy density and power density.

  12. Air-side performance of a micro-channel heat exchanger in wet surface conditions

    Directory of Open Access Journals (Sweden)

    Srisomba Raviwat

    2017-01-01

    Full Text Available The effects of operating conditions on the air-side heat transfer, and pressure drop of a micro-channel heat exchanger under wet surface conditions were studied experimentally. The test section was an aluminum micro-channel heat exchanger, consisting of a multi-louvered fin and multi-port mini-channels. Experiments were conducted to study the effects of inlet relative humidity, air frontal velocity, air inlet temperature, and refrigerant temperature on air-side performance. The experimental data were analyzed using the mean enthalpy difference method. The test run was performed at relative air humidities ranging between 45% and 80%; air inlet temperature ranges of 27, 30, and 33°C; refrigerant-saturated temperatures ranging from 18 to 22°C; and Reynolds numbers between 128 and 166. The results show that the inlet relative humidity, air inlet temperature, and the refrigerant temperature had significant effects on heat transfer performance and air-side pressure drop. The heat transfer coefficient and pressure drop for the micro-channel heat exchanger under wet surface conditions are proposed in terms of the Colburn j factor and Fanning f factor.

  13. Aerodynamic Influence of Added Surfaces on the Performance Characteristics of a Sports Car

    Science.gov (United States)

    Thangadurai, Murugan; Kumar, Rajesh; Rana, Subhas Chandra; Chatterjee, Dipankar

    2018-05-01

    External aerodynamics plays a vital role in designing high-speed vehicles since a reduction in drag and positive lift generation are principal concerns in vehicle aerodynamics to ensure superior performance, comfort, and vehicle stability. In the present study, the effect of added surfaces such as NACA 2412 wings and wedge type spoiler at the rear end of a sports car are examined in detail using three-dimensional numerical simulations substantiated with lab scale experiments. The simulations are performed by solving Reynolds-averaged Navier-Stokes equations with a realizable k-ɛ turbulence model using ANSYS Fluent software for Reynolds numbers 9.1 × 106, 1.37 × 107 and 1.82 × 107. The results obtained from simulations are validated with the experiments performed on a scale down model at the low-speed wind tunnel using a six component external pyramidal balance. The variation in the wake flow field of the vehicles with different added surfaces are demonstrated using pressure and velocity contours, velocity vectors at the rear end, and the turbulent kinetic energy distribution plots. It is observed that the positive lift coefficient of the base model is reduced drastically by incorporating a single wing at the rear end of the vehicle. The aerodynamics coefficients obtained from different configurations suggest that the two wing configuration has lesser drag than the wedge type spoiler though, the negative lift is higher with a wedge than the two wing configuration.

  14. Thermal-Hydraulic Performance of a Corrugated Cooling Fin with Louvered Surfaces

    DEFF Research Database (Denmark)

    Sønderby, Simon Kaltoft; Hosseini, Seyed Mojtaba Mir; Rezaniakolaei, Alireza

    2017-01-01

    The main objective of the article is to investigate thermal-hydraulic performance of a corrugated cooling fin with louvered surfaces. The investigation is carried out using the fin geometry of one most commonly used liquid-to-air heat exchangers. The investigation was carried out by numerically...... simulating the airflow with louvered fin geometry. The simulation model was verified by comparing simulated j- and f-factors with the corresponding values of several experimental correlations. The j-factors deviated less than 10.7 % from two of the experimental correlations, whereas deviations ranging...

  15. Characterization of the Effect of Wing Surface Instrumentation on UAV Airfoil Performance

    Science.gov (United States)

    Ratnayake, Nalin A.

    2009-01-01

    Recently proposed flight research at NASA Dryden Flight Research Center (DFRC) has prompted study into the aerodynamic effects of modifications made to the surfaces of laminar airfoils. The research is focused on the high-aspect ratio, laminar-flow type wings commonly found on UAVs and other aircraft with a high endurance requirement. A broad range of instrumentation possibilities, such as structural, pressure, and temperature sensing devices may require the alteration of the airfoil outer mold line as part of the installation process. This study attempts to characterize the effect of installing this additiona1 instrumentation on key airfoil performance factors, such as transition location, lift and drag curves, and stall point. In particular, the general case of an airfoil that is channeled in the spanwise direction is considered, and the impact on key performance characteristics is assessed. Particular attention is focused on exploring the limits of channel depth and low-Reynolds number on performance and stall characteristics. To quantify the effect of increased skin friction due to premature transition caused by protruding or recessed instrumentation, two simplified, conservative scenarios are used to consider two potential sources of diaturbance: A) that leading edge alterations would cause linearly expanding areas (triangles) of turbulent flow on both surfaces of the wing upstream of the natural transition point, and B) that a channel or bump on the upper surface would trip turbulent flow across the whole upper surface upstream of the natural transition point. A potentially more important consideration than the skin friction drag increment is the change in overall airfoil performance due to the installation of instrumentation along most of the wingspan. To quantify this effect, 2D CFD simulations of the flow over a representative mid-span airfoil section were conducted in order to assess the change in lift and drag curves for the airfoil in the presence of

  16. Novel types of surface acoustic wave microreflectors - Performance analysis and simulations

    Science.gov (United States)

    Golan, G.; Griffel, G.; Seidman, A.; Croitoru, N.

    1990-06-01

    Surface acoustic waves for micrograting reflectors have been characterized. Based on the perturbation theory, eight different types of structures on an acoustic waveguide were analyzed. Results of simulations of all eight types of corrugation structures were evaluated in order to find the least leaky waveguide, the most efficient reflector (with minimum necessary perturbations), and the optimal mode shape for improved performances. General design curves are presented in order to illustrate the behavior of the incident and reflected waves under a variety of structural conditions. Analytic expressions for the calculations of the mode amplitude and mode shape, and for general acoustic corrugations are derived and then the simulations results are presented.

  17. Performances study of UWB monopole antennas using half-elliptic radiator conformed on elliptical surface

    Energy Technology Data Exchange (ETDEWEB)

    Djidel, S.; Bouamar, M.; Khedrouche, D., E-mail: dkhedrouche@yahoo.com [LASS (Laboratoired’Analyse des Signaux et Systèmes), Department of Electronics, University of M’sila BP.166, Route Ichebilia, M’sila, 28000 Algeria (Algeria)

    2016-04-21

    This paper presents a performances study of UWB monopole antenna using half-elliptic radiator conformed on elliptical surface. The proposed antenna, simulated using microwave studio computer CST and High frequency simulator structure HFSS, is designed to operate in frequency interval over 3.1 to 40 GHz. Good return loss and radiation pattern characteristics are obtained in the frequency band of interest. The proposed antenna structure is suitable for ultra-wideband applications, which is, required for many wearable electronics applications.

  18. First-order dissolution rate law and the role of surface layers in glass performance assessment

    Science.gov (United States)

    Grambow, B.; Müller, R.

    2001-09-01

    The first-order dissolution rate law is used for nuclear waste glass performance predictions since 1984. A first discussion of the role of saturation effects was initiated at the MRS conference that year. In paper (1) it was stated that "For glass dissolution A* (the reaction affinity) cannot become zero since saturation only involves the reacting surface while soluble elements still might be extracted from the glass" [B. Grambow, J. Mater. Res. Soc. Symp. Proc. 44 (1985) 15]. Saturation of silica at the surface and condensation of surface silanol groups was considered as being responsible for the slow down of reaction rates by as much as a factor of 1000. Precipitation of Si containing secondary phases such as quartz was invoked as a mechanism for keeping final dissolution affinities higher than zero. Another (2) paper [A.B. Barkatt, P.B. Macedo, B.C. Gibson, C.J. Montrose, J. Mater. Res. Soc. Symp. Proc. 44 (1985) 3] stated that "… under repository conditions the extent of glass dissolution will be moderate due to saturation with respect to certain major elements (in particular, Si, Al and Ca). Consequently, the concentration levels of the more soluble glass constituents in the aqueous medium are expected to fall appreciable below their solubility limit." The formation of dense surface layers was considered responsible for explaining the saturation effect. The mathematical model assumed stop of reaction in closed systems, once solubility limits were achieved. For more than 15 years the question of the correctness of one or the other concept has seldom been posed and has not yet been resolved. The need of repository performance assessment for validated rate laws demands a solution, particularly since the consequences of the two concepts and research requirements for the long-term glass behavior are quite different. In concept (1) the stability of the `equilibrium surface region' is not relevant because, by definition, this region is stable chemically and after a

  19. Study of double porous silicon surfaces for enhancement of silicon solar cell performance

    Science.gov (United States)

    Razali, N. S. M.; Rahim, A. F. A.; Radzali, R.; Mahmood, A.

    2017-09-01

    In this work, design and simulation of double porous silicon surfaces for enhancement of silicon solar cell is carried out. Both single and double porous structures are constructed by using TCAD ATHENA and TCAD DEVEDIT tools of the SILVACO software respectively. After the structures were created, I-V characteristics and spectral response of the solar cell were extracted using ATLAS device simulator. Finally, the performance of the simulated double porous solar cell is compared with the performance of both single porous and bulk-Si solar cell. The results showed that double porous silicon solar cell exhibited 1.8% efficiency compared to 1.3% and 1.2% for single porous silicon and bulk-Si solar cell.

  20. Review on Electroless Plating Ni-P Coatings for Improving Surface Performance of Steel

    Science.gov (United States)

    Zhang, Hongyan; Zou, Jiaojuan; Lin, Naiming; Tang, Bin

    2014-04-01

    Electroless plating has been considered as an effective approach to provide protection and enhancement for metallic materials with many excellent properties in engineering field. This paper begins with a brief introduction of the fundamental aspects underlying the technological principles and conventional process of electroless nickel-phosphorus (Ni-P) coatings. Then this paper discusses different electroless nickel plating, including binary plating, ternary composite plating and nickel plating with nanoparticles and rare earth, with the intention of improving the surface performance on steel substrate in recent years in detail. Based on different coating process, the varied features depending on the processing parameters are highlighted. Separately, diverse preparation techniques aiming at improvement of plating efficiency are summarized. Moreover, in view of the outstanding performance, such as corrosion resistance, abrasive resistance and fatigue resistance, this paper critically reviews the behaviors and features of various electroless coatings under different conditions.

  1. Tuning of perovskite solar cell performance via low-temperature brookite scaffolds surface modifications

    Directory of Open Access Journals (Sweden)

    Trilok Singh

    2017-01-01

    Full Text Available The nature of metal oxide scaffold played a pivotal role for the growth of high quality perovskites and subsequently facilitates efficient photovoltaics devices. We demonstrate an effective way to fabricate a low-temperature TiO2 brookite scaffold layer with a uniform and pinhole-free layer for enhancing photovoltaic properties of perovskite solar cells. Various concentrations of TiCl4 were used to modify brookite TiO2 for efficient charge generation and fast charge extraction. We observed that the brookite layer with an appropriate TiCl4 treatment possesses a smooth surface with full coverage of the substrates, whereas TiCl4 treatment further improves the contact of the TiO2/perovskite interface which facilitates charge extraction and drastically influenced charge recombination. The surface treated brookite scaffolds perovskite devices showed an improved performance with an average power conversion efficiency more than 17%. The time resolved photoluminescence showed that the treated samples have obvious effect on the charge carrier dynamics. The striking observation of this study was very low appearance of hysteresis and high reproducibility in the treated samples, which opens up the possibilities for the fabrication of high efficient devices at relatively low temperatures with negligible hysteresis via facile surface modifications.

  2. Effect of nanofluids on the performance of a miniature plate heat exchanger with modulated surface

    International Nuclear Information System (INIS)

    Pantzali, M.N.; Kanaris, A.G.; Antoniadis, K.D.; Mouza, A.A.; Paras, S.V.

    2009-01-01

    In the present work, the effect of the use of a nanofluid in a miniature plate heat exchanger (PHE) with modulated surface has been studied both experimentally and numerically. First, the thermophysical properties (i.e., thermal conductivity, heat capacity, viscosity, density and surface tension) of a typical nanofluid (CuO in water, 4% v/v) were systematically measured. The effect of surface modulation on heat transfer augmentation and friction losses was then investigated by simulating the existing miniature PHE as well as a notional similar PHE with flat plate using a CFD code. Finally, the effect of the nanofluid on the PHE performance was studied and compared to that of a conventional cooling fluid (i.e., water). The results suggest that, for a given heat duty, the nanofluid volumetric flow rate required is lower than that of water causing lower pressure drop. As a result, smaller equipment and less pumping power are required. In conclusion, the use of the nanofluids seems to be a promising solution towards designing efficient heat exchanging systems, especially when the total volume of the equipment is the main issue. The only drawbacks so far are the high price and the possible instability of the nanoparticle suspensions.

  3. Surface-Modified Electrodes: Enhancing Performance Guided by Insitu Spectroscopy and Microscopy

    Energy Technology Data Exchange (ETDEWEB)

    Chueh, William [Stanford Univ., CA (United States)

    2016-12-01

    The aim of this project is to understand the nature of active sites and degradation mechanisms in solid-oxide fuel cells cathodes. Using Co and Fe-based perovskite oxides as model systems, we developed a comprehensive understanding of the active site and degradation. In particular, we correlated cation segregation, precipitation and surface reconstruction to electrochemical activity and stability. We show that in conventional materials, the most active cathodes are not the most stable ones. A novel strategy of cation segregation buffer layer was proposed and developed to overcome this limitation. A nanoscale barrier layer was inserted a few nanometer below the surface of the cathodes which prevents the cations from diffusing from the bulk to the surface. We report a LSCF-based cathode with record performance and stability, reach an impressive 0.03 Ω cm2 at 650 °C in air. This modification strategy is expected to lead to more active and stable solid-oxide fuel cells, and ultimately lead to lower cost in commercial systems.

  4. Effects of self-assembled monolayer structural order, surface homogeneity and surface energy on pentacene morphology and thin film transistor device performance.

    Science.gov (United States)

    Hutchins, Daniel Orrin; Weidner, Tobias; Baio, Joe; Polishak, Brent; Acton, Orb; Cernetic, Nathan; Ma, Hong; Jen, Alex K-Y

    2013-01-04

    A systematic study of six phosphonic acid (PA) self-assembled monolayers (SAMs) with tailored molecular structures is performed to evaluate their effectiveness as dielectric modifying layers in organic field-effect transistors (OFETs) and determine the relationship between SAM structural order, surface homogeneity, and surface energy in dictating device performance. SAM structures and surface properties are examined by near edge X-ray absorption fine structure (NEXAFS) spectroscopy, contact angle goniometry, and atomic force microscopy (AFM). Top-contact pentacene OFET devices are fabricated on SAM modified Si with a thermally grown oxide layer as a dielectric. For less ordered methyl- and phenyl-terminated alkyl ~(CH 2 ) 12 PA SAMs of varying surface energies, pentacene OFETs show high charge carrier mobilities up to 4.1 cm 2 V -1 s -1 . It is hypothesized that for these SAMs, mitigation of molecular scale roughness and subsequent control of surface homogeneity allow for large pentacene grain growth leading to high performance pentacene OFET devices. PA SAMs that contain bulky terminal groups or are highly crystalline in nature do not allow for a homogenous surface at a molecular level and result in charge carrier mobilities of 1.3 cm 2 V -1 s -1 or less. For all molecules used in this study, no causal relationship between SAM surface energy and charge carrier mobility in pentacene FET devices is observed.

  5. Surface detection performance evaluation of pseudo-random noise continuous wave laser radar

    Science.gov (United States)

    Mitev, Valentin; Matthey, Renaud; Pereira do Carmo, Joao

    2017-11-01

    A number of space missions (including in the ESA Exploration Programme) foreseen a use of laser radar sensor (or lidar) for determination of range between spacecrafts or between spacecraft and ground surface (altimetry). Such sensors need to be compact, robust and power efficient, at the same time with high detection performance. These requirements can be achieved with a Pseudo-Random Noise continuous wave lidar (PRN cw lidar). Previous studies have pointed to the advantages of this lidar with respect to space missions, but they also identified its limitations in high optical background. The progress of the lasers and the detectors in the near IR spectral range requires a re-evaluation of the PRN cw lidar potential. Here we address the performances of this lidar for surface detection (altimetry) in planetary missions. The evaluation is based on the following system configuration: (i) A cw fiber amplifier as lidar transmitter. The seeding laser exhibits a single-frequency spectral line, with subsequent amplitude modulation. The fiber amplifier allows high output power level, keeping the spectral characteristics and the modulation of the seeding light input. (ii) An avalanche photodiode in photon counting detection; (iii) Measurement scenarios representative for Earth, Mercury and Mars.

  6. Why Did the Bear Cross the Road? Comparing the Performance of Multiple Resistance Surfaces and Connectivity Modeling Methods

    Directory of Open Access Journals (Sweden)

    Samuel A. Cushman

    2014-12-01

    Full Text Available There have been few assessments of the performance of alternative resistance surfaces, and little is known about how connectivity modeling approaches differ in their ability to predict organism movements. In this paper, we evaluate the performance of four connectivity modeling approaches applied to two resistance surfaces in predicting the locations of highway crossings by American black bears in the northern Rocky Mountains, USA. We found that a resistance surface derived directly from movement data greatly outperformed a resistance surface produced from analysis of genetic differentiation, despite their heuristic similarities. Our analysis also suggested differences in the performance of different connectivity modeling approaches. Factorial least cost paths appeared to slightly outperform other methods on the movement-derived resistance surface, but had very poor performance on the resistance surface obtained from multi-model landscape genetic analysis. Cumulative resistant kernels appeared to offer the best combination of high predictive performance and sensitivity to differences in resistance surface parameterization. Our analysis highlights that even when two resistance surfaces include the same variables and have a high spatial correlation of resistance values, they may perform very differently in predicting animal movement and population connectivity.

  7. Stormwater infiltration and surface runoff pollution reduction performance of permeable pavement layers.

    Science.gov (United States)

    Niu, Zhi-Guang; Lv, Zhi-Wei; Zhang, Ying; Cui, Zhen-Zhen

    2016-02-01

    In this paper, the laboratory-scale permeable pavement layers, including a surface permeable brick layer, coarse sand bedding layers (thicknesses = 2, 3.5, and 5 cm), and single-graded gravel sub-base layers (thicknesses = 15, 20, 25, and 30 cm), were built to evaluate stormwater infiltration and surface runoff pollution reduction performance. And, the infiltration rate (I) and concentrations of suspended solids (SS), total phosphorus (TP), chemical oxygen demand (COD), ammonia nitrogen, and total nitrogen (TN) were measured under the simulated rainfall intensity of 72.4 mm/h over duration of 60 min. The results indicate that the thickness factor primarily influences the infiltration rate and pollutant removal rate. The highest steady infiltration rate was for surface brick layer 51.0 mm/h, for 5-cm sand bedding layer 32.3 mm/h, and for 30-cm gravel sub-base layer 42.3 mm/h, respectively. The SS average removal rate was relative higher (79.8 ∼ 98.6 %) for all layers due to the interception and filtration. The average removal rates of TP and COD were for surface layer 71.2 and 24.1 %, for 5-cm bedding layer 54.8 and 9.0 %, and for 20-cm sub-base layer 72.2 and 26.1 %. Ammonia nitrogen and TN cannot steadily be removed by layers according to the experiment results. The optimal thickness of bedding sands was 5 cm, and that of sub-base gravels was 20 ∼ 30 cm.

  8. Performance of surface on ultrafine grained Ti-0.2Pd in simulated body fluid

    Science.gov (United States)

    Wang, Xiu-Lai; Zhou, Qing; Yang, Kai; Zou, Cheng-Hong; Wang, Lei

    2018-03-01

    Ti-0.2 wt% Pd (Ti-0.2Pd) which has high crevice corrosion resistance is highlighted for implant applications. In this work, Ti-0.2Pd alloy is subjected to equal channel angular pressing (ECAP) for grain refinement. The effect of the microstructure on the surface performance of Ti-0.2Pd in a simulated body fluid (SBF) adding bovine serum albumin is investigated. Heat-treated specimens including furnace cooled (FC) and water quenched (WQ) specimens are also prepared for comparison. The corrosion resistance is evaluated by the tests of potentiodynamic polarization and the measurement of electrochemical impedance spectroscopy (EIS). The composition and morphology of the surface after exposing to SBF 60 days were examined by X-ray photoelectronic spectroscopy (XPS), scanning electron microscope (SEM) and energy dispersive spectrometer (EDS). The results show an ultrafine grained microstructure with average grain size of 3.6 μm is obtained after ECAP. The ultrafine grained Ti-0.2Pd has higher corrosion resistance than AR(as-received), WQ and FC specimens. The quantitative analysis of the surface shows larger numbers of precipitations formed on ECAPed Ti-0.2Pd than those formed on heat-treated. The precipitation contains more oxygen, calcium and phosphorus on ECAPed specimen than those on other specimens. The Ca:P ratio is ranged from 1:0.7 to 1:4.4, no dependent on the specimen type. A larger Warburg resistance is obtained on WQ specimen indicating a denser layer formation on WQ specimen. The precipitation formed on WQ specimens is the least among three kinds of specimens. Palladium is not found on the surfaces after exposure to SBF.

  9. Effects of surface roughness on deviation angle and performance losses in wet steam turbines

    International Nuclear Information System (INIS)

    Bagheri Esfe, H.; Kermani, M.J.; Saffar Avval, M.

    2015-01-01

    In this paper, effects of turbine blade roughness and steam condensation on deviation angle and performance losses of the wet stages are investigated. The steam is assumed to obey non-equilibrium thermodynamic model, in which abrupt formation of liquid droplets produces condensation shocks. An AUSM-van Leer hybrid scheme is used to solve two-phase turbulent transonic steam flow around turbine rotor tip sections. The dominant solver of the computational domain is taken to be the AUSM scheme (1993) that in regions with large gradients smoothly switches to van Leer scheme (1979). This guarantees a robust hybrid scheme throughout the domain. It is observed that as a result of condensation, the aerothermodymics of the flow field changes. For example for a supersonic wet case with exit isentropic Mach number M e,is  = 1.45, the deviation angle and total pressure loss coefficient change by 65% and 200%, respectively, when compared with dry case. It is also observed that losses due to surface roughness in subsonic regions are much larger than those in supersonic regions. Hence, as a practical guideline for maintenance sequences, cleaning of subsonic parts of steam turbines should be considered first. - Highlights: • Two-phase turbulent transonic steam flow is numerically studied in this paper. • As a result of condensation, aerothermodynamics of the flow field changes. • Surface roughness has almost negligible effect on deviation angle. • Surface roughness plays an important role in performance losses. • Contribution of different loss mechanisms for smooth and rough blades are computed.

  10. Automated detection of submerged navigational obstructions in freshwater impoundments with hull mounted sidescan sonar

    Science.gov (United States)

    Morris, Phillip A.

    The prevalence of low-cost side scanning sonar systems mounted on small recreational vessels has created improved opportunities to identify and map submerged navigational hazards in freshwater impoundments. However, these economical sensors also present unique challenges for automated techniques. This research explores related literature in automated sonar imagery processing and mapping technology, proposes and implements a framework derived from these sources, and evaluates the approach with video collected from a recreational grade sonar system. Image analysis techniques including optical character recognition and an unsupervised computer automated detection (CAD) algorithm are employed to extract the transducer GPS coordinates and slant range distance of objects protruding from the lake bottom. The retrieved information is formatted for inclusion into a spatial mapping model. Specific attributes of the sonar sensors are modeled such that probability profiles may be projected onto a three dimensional gridded map. These profiles are computed from multiple points of view as sonar traces crisscross or come near each other. As lake levels fluctuate over time so do the elevation points of view. With each sonar record, the probability of a hazard existing at certain elevations at the respective grid points is updated with Bayesian mechanics. As reinforcing data is collected, the confidence of the map improves. Given a lake's current elevation and a vessel draft, a final generated map can identify areas of the lake that have a high probability of containing hazards that threaten navigation. The approach is implemented in C/C++ utilizing OpenCV, Tesseract OCR, and QGIS open source software and evaluated in a designated test area at Lake Lavon, Collin County, Texas.

  11. Impoundment effects in the population of Auchenipterus osteomystax (Siluriformes: Auchenipteridae: a Neotropical reservoir case

    Directory of Open Access Journals (Sweden)

    Elcio Barili

    2012-06-01

    Full Text Available New impoundments provide opportunities to check whether species that present enough feeding flexibility in natural conditions may take advantage of this situation and, without reproductive restriction, can occupy the most conspicuous habitat in a large reservoir (open areas and present higher success in the colonization of the new environment. We examined variations in the abundance and feeding of A. osteomystax in two environments, one natural (Sinha Mariana floodplain lake and one dammed (Manso Reservoir, during two periods: the first year after the filling phase and three years later. Our goal was to evaluate the occupation of the new hábitat (Manso Reservoir, by this species, as well as to test the hypothesis that in the reservoir, unlike the natural environment, there are remarkable changes in diet between the periods. Fish were sampled monthly in the floodplain lake and in the reservoir during two annual periods using gillnets. To evaluate the differences in abundance of A. osteomystax we employed the Kruskal -Wallis test, and the diet analysis was carried out using frequency of occurrence and volumetric methods. Temporal differences in the diet were tested by Kruskal-Wallis test using the scores from a detrended correspondence analysis. A. osteomystax was significantly more abundant in the floodplain lake, where the captures were higher than in the reservoir in almost all months analyzed, and significant variations in abundance between the two periods were not recorded in either the reservoir or the floodplain lake. The diet variation between the two periods, which had a time lag of three years between them, was much less pronounced in the natural environment, where the resource availability is essentially regulated by seasonality. Thus, our hypothesis was accepted; that is, the interannual variations in the diet of A. osteomystax are more relevant in an artificial environment than in a natural one. Rev. Biol. Trop. 60 (2: 699-708. Epub

  12. Surface functionalization of hexagonal boron nitride and its effect on the structure and performance of composites

    Energy Technology Data Exchange (ETDEWEB)

    Jin, Wenqin; Zhang, Wei; Gao, Yuwen [Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Materials Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123 (China); Liang, Guozheng, E-mail: lgzheng@suda.edu.cn [Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Materials Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123 (China); Gu, Aijuan, E-mail: ajgu@suda.edu.cn [Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Materials Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123 (China); Yuan, Li [Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Materials Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123 (China)

    2013-04-01

    A new organized hexagonal boron nitride (OhBN) with significantly increased amount of amine groups was synthesized, and characterized by Fourier Transform Infrared (FTIR), X-ray Photoelectron Spectroscopy (XPS), Thermogravimetric (TG) analysis, UV–vis Transmittance Spectra, Transmission Electron Microscope (TEM) and the potentiometric titration. The content of amine groups for OhBN is about 5 times of that for original hexagonal boron nitride (hBN). Based on the preparation of OhBN, new composites consisting of OhBN and bismaleimide (BD) resin were developed, which show greatly improved integrated performance (including dynamic mechanical, dielectric and thermal properties) compared with BD resin and the hBN/BD composites. In the case of the OhBN/BD composite with 15 wt% OhBN, its storage modulus, dielectric loss, thermal conductivity and coefficient of thermal expansion are about 1.2, 0.56, 1.11 and 0.92 times of the corresponding values of hBN/BD composite, respectively; moreover, the glass transition temperature of the former is 15 °C higher than that of the latter. These interesting results suggest that the integrated performance of the composites is closely related to the surface nature of the fillers because the change in the surface nature not only varies the chemical structure, free volume and crosslinking density of the composite, but also determines the interfacial nature between inorganic fillers and the resin matrix. This investigation demonstrates that the method proposed herein provides a new approach to prepare organized inorganic fillers as well as corresponding composites with controlled structure and expected performances for cutting-edge industries.

  13. Sharptooth catfish shows its metal: a case study of metal contamination at two impoundments in the Olifants River, Limpopo river system, South Africa.

    Science.gov (United States)

    Jooste, Antoinette; Marr, Sean M; Addo-Bediako, Abraham; Luus-Powell, Wilmien J

    2015-02-01

    Clarias gariepinus is increasing in importance as a global aquaculture species with a 100 fold increase in production over the past decade but this species still remains one of the most important wild harvested freshwater food fish throughout rural Africa. However, this species has been shown to accumulate metals from contaminated inland waters. In this paper, the metal concentrations in muscle tissue of C. gariepinus from two main-stem impoundments in the Olifants River, Limpopo Basin, were measured and a desktop risk assessment based on the US-EPA methodology completed to evaluate whether long-term consumption of C. gariepinus from these impoundments may pose a health risk to rural communities. Our results show that metals are accumulating in the muscle tissue of C. gariepinus and have appeared to have increased in the last two decades. Risk assessment generated Hazard quotients (HQ) greater than 1 indicate that long term consumption of fish from these impoundments may cause adverse health impacts. We found that lead (HQ=9), antimony (HQ=14), cobalt (HQ=2) and chromium (HQ=1) at one impoundment and lead (HQ=2) at the other impoundment were above acceptable levels for weekly consumption of 150 g C. gariepinus muscle tissue. Copyright © 2014 Elsevier Inc. All rights reserved.

  14. A review of nanostructured surfaces and materials for dental implants: surface coating, patterning and functionalization for improved performance.

    Science.gov (United States)

    Rasouli, Rahimeh; Barhoum, Ahmed; Uludag, Hasan

    2018-05-10

    The emerging field of nanostructured implants has enormous scope in the areas of medical science and dental implants. Surface nanofeatures provide significant potential solutions to medical problems by the introduction of better biomaterials, improved implant design, and surface engineering techniques such as coating, patterning, functionalization and molecular grafting at the nanoscale. This review is of an interdisciplinary nature, addressing the history and development of dental implants and the emerging area of nanotechnology in dental implants. After a brief introduction to nanotechnology in dental implants and the main classes of dental implants, an overview of different types of nanomaterials (i.e. metals, metal oxides, ceramics, polymers and hydrides) used in dental implant together with their unique properties, the influence of elemental compositions, and surface morphologies and possible applications are presented from a chemical point of view. In the core of this review, the dental implant materials, physical and chemical fabrication techniques and the role of nanotechnology in achieving ideal dental implants have been discussed. Finally, the critical parameters in dental implant design and available data on the current dental implant surfaces that use nanotopography in clinical dentistry have been discussed.

  15. Analysis of the behaviour of embankment dams during and after impoundment; Analyse du comportement de barrages en remblai pendant et apres leur mise en eau

    Energy Technology Data Exchange (ETDEWEB)

    Massiera, M. [Moncton Univ., Moncton, NB (Canada). Dept. of Civil Engineering; Szostak-Chrzanowski, A; Bazanowski, M. [New Brunswick Univ., Fredericton, NB (Canada). Canadian Centre for Geodetic Engineering; Withaker, C. [Metropolitan Water District of Southern California MWD, Glendora, CA (United States)

    2009-07-01

    This paper analyzed the behaviour of 2 embankment dams during impoundment. The study compared the values of the observed and calculated displacements of the crest during the initial filling of the reservoirs at the zoned earth West Dam in California and the Tounustouc concrete face rockfill dam (CFRD) in Quebec. The calculations were performed using finite element analysis. Rock and earthfill dams constructed on moraine deposits are known to deform under the influence of water load as the reservoir is filled. Therefore, this study also analyzed the long term deformations of the West Dam during 4 subsequent years of operation of the reservoir. Modelling rock and earthfill dams takes into account the nonlinear behaviour of the construction materials; interaction between the structure and the underlying soil and rock strata; influence of water load on the structure and on the foundation bedrock; and the effects of water saturation. This paper showed that geotechnical and geodetic monitoring may provide a warning system in case of abnormal behaviour of the embankment dam. In tectonically active zones, monitoring surveys may also provide information on the effects of seismic disturbances. 18 refs., 11 figs.

  16. Infiltration performance of engineered surfaces commonly used for distributed stormwater management.

    Science.gov (United States)

    Valinski, N A; Chandler, D G

    2015-09-01

    Engineered porous media are commonly used in low impact development (LID) structures to mitigate excess stormwater in urban environments. Differences in infiltrability of these LID systems arise from the wide variety of materials used to create porous surfaces and subsequent maintenance, debris loading, and physical damage. In this study, the infiltration capacity of six common materials was tested by multiple replicate experiments with automated mini-disk infiltrometers. The tested materials included porous asphalt, porous concrete, porous brick pavers, flexible porous pavement, engineered soils, and native soils. Porous asphalt, large porous brick pavers, and curb cutout rain gardens showed the greatest infiltration rates. Most engineered porous pavements and soils performed better than the native silt loam soils. Infiltration performance was found to be related more to site design and environmental factors than material choice. Sediment trap zones in both pavements and engineered soil rain gardens were found to be beneficial to the whole site performance. Winter chloride application had a large negative impact on poured in place concrete, making it a poor choice for heavily salted areas. Copyright © 2015 Elsevier Ltd. All rights reserved.

  17. A Near-Zero Refractive Index Meta-Surface Structure for Antenna Performance Improvement

    Directory of Open Access Journals (Sweden)

    Mohammad Habib Ullah

    2013-11-01

    Full Text Available A new meta-surface structure (MSS with a near-zero refractive index (NZRI is proposed to enhance the performance of a square loop antenna array. The main challenge to improve the antenna performance is increment of the overall antenna volume that is mitigated by assimilating the planar NZRI MSS at the back of the antenna structure. The proposed NZRI MSS-loaded CPW-fed (Co-Planar Waveguide four-element array antenna is designed on ceramic-bioplastic-ceramic sandwich substrate using high-frequency structure simulator (HFSS, a finite-element-method-based simulation tool. The gain and directivity of the antenna are significantly enhanced by incorporating the NZRI MSS with a 7 × 6 set of elements at the back of the antenna structure. Measurement results show that the maximum gains of the antenna increased from 6.21 dBi to 8.25 dBi, from 6.52 dBi to 9.05 dBi and from 10.54 dBi to 12.15 dBi in the first, second and third bands, respectively. The effect of the slot configuration in the ground plane on the reflection coefficient of the antenna was analyzed and optimized. The overall performance makes the proposed antenna appropriate for UHFFM (Ultra High Frequency Frequency Modulation telemetry-based space applications as well as mobile satellite, microwave radiometry and radio astronomy applications.

  18. Performance analysis of three-dimensional ridge acquisition from live finger and palm surface scans

    Science.gov (United States)

    Fatehpuria, Abhishika; Lau, Daniel L.; Yalla, Veeraganesh; Hassebrook, Laurence G.

    2007-04-01

    Fingerprints are one of the most commonly used and relied-upon biometric technology. But often the captured fingerprint image is far from ideal due to imperfect acquisition techniques that can be slow and cumbersome to use without providing complete fingerprint information. Most of the diffculties arise due to the contact of the fingerprint surface with the sensor platen. To overcome these diffculties we have been developing a noncontact scanning system for acquiring a 3-D scan of a finger with suffciently high resolution which is then converted into a 2-D rolled equivalent image. In this paper, we describe certain quantitative measures evaluating scanner performance. Specifically, we use some image software components developed by the National Institute of Standards and Technology, to derive our performance metrics. Out of the eleven identified metrics, three were found to be most suitable for evaluating scanner performance. A comparison is also made between 2D fingerprint images obtained by the traditional means and the 2D images obtained after unrolling the 3D scans and the quality of the acquired scans is quantified using the metrics.

  19. Performance Characteristics of Bio-Inspired Metal Nanostructures as Surface-Enhanced Raman Scattered (SERS) Substrates.

    Science.gov (United States)

    Areizaga-Martinez, Hector I; Kravchenko, Ivan; Lavrik, Nickolay V; Sepaniak, Michael J; Hernández-Rivera, Samuel P; De Jesús, Marco A

    2016-09-01

    The fabrication of high-performance plasmonic nanomaterials for bio-sensing and trace chemical detection is a field of intense theoretical and experimental research. The use of metal-silicon nanopillar arrays as analytical sensors has been reported with reasonable results in recent years. The use of bio-inspired nanocomposite structures that follow the Fibonacci numerical architecture offers the opportunity to develop nanostructures with theoretically higher and more reproducible plasmonic fields over extended areas. The work presented here describes the nanofabrication process for a series of 40 µm × 40 µm bio-inspired arrays classified as asymmetric fractals (sunflower seeds and romanesco broccoli), bilaterally symmetric (acacia leaves and honeycombs), and radially symmetric (such as orchids and lily flowers) using electron beam lithography. In addition, analytical capabilities were evaluated using surface-enhanced Raman scattering (SERS). The substrate characterization and SERS performance of the developed substrates as the strategies to assess the design performance are presented and discussed. © The Author(s) 2016.

  20. Dynamics of dissolved organic matter in riverine sediments affected by weir impoundments: Production, benthic flux, and environmental implications.

    Science.gov (United States)

    Chen, Meilian; Kim, Sung-Han; Jung, Heon-Jae; Hyun, Jung-Ho; Choi, Jung Hyun; Lee, Hyo-Jin; Huh, In-Ae; Hur, Jin

    2017-09-15

    In order to understand the characteristics and dynamics of dissolved organic matter (DOM) in the sediment of rivers affected by impoundments, we examined the vertical profiles and the benthic fluxes of DOM in four different core sediments located at upstream sites of weirs in major rivers of South Korea. In three out of four sites, exponential accumulation of dissolved organic carbon (DOC) with depth was observed with the signature of seasonal variability. Except for the site displaying a below-detection limit of Fe(II), the general accumulation trends of DOC with depth was concurrent with the increases of Fe(II) and NH 4 + and the decrease of PO 4 3- , signifying a close linkage of the DOM dynamics with anaerobic respiration via iron reduction, an important early diagenesis pathway. The estimated benthic fluxes from the cores revealed that the sediments likely serve as DOC, chromophoric DOM (CDOM), and fluorescent DOM (FDOM) sources to the overlying water. The benthic effluxes based on DOC were comparable to the ranges previously reported in lake and coastal areas, and those of CDOM and FDOM showed even higher levels. These findings imply that impoundment-affected river systems would change the DOM composition of the overlying water, ultimately influencing the subsequent water treatment processes such as disinfection byproducts production and membrane fouling. A simple mass balance model indicated that the impoundment-affected river sediments may operate as a net carbon sink in the environments due to a greater extent of sedimentation compared to the estimated benthic efflux and sediment biological respiration. Copyright © 2017 Elsevier Ltd. All rights reserved.

  1. Effect of heavy metals on soil mineral surfaces and bioretention pond performance

    Science.gov (United States)

    Zhang, H.; Olson, M. S.

    2009-12-01

    Haibo Zhang and Mira S. Olson Department of Civil, Architectural, and Environmental Engineering, Drexel University, 3141 Chestnut Street, Philadelphia, PA 19104 As urban stormwater runoff flows across impervious surfaces, it collects and accumulates pollutants that are detrimental to the quality of local receiving water bodies. Heavy metal pollution, such as copper, lead and zinc, has been a concern in urban stormwater runoff. In addition, the presence of bacteria in stormwater has been frequently reported. The co-existence of both heavy metals and bacteria in stormwater and their complex interactions determine their transport and removal through bioretention pond. Stormwater runoff was sampled from a bioretention pond in Philadelphia, PA. The concentration of copper, lead and zinc were measured as 0.086ppm, 0.083ppm and 0.365ppm, respectively. Batch experiments were conducted with solutions of pure copper, lead and zinc, and with a synthetic stormwater solution amended with copper, lead and zinc. The solution was buffered to pH 7, within the range of the observed stormwater pH. In pure heavy metal solutions, the sorption of copper, lead and zinc onto soil are 96%, 99% and 85%, respectively. In synthetic stormwater containing nutrients and all three metals, the sorption of lead is 97%, while copper and zinc decrease to 29% and 71%, respectively. Mineralogy of a soil sample taken from the bioretention pond was analyzed using a scanning electron microscope (SEM) and compared before and after sorption experiments. Sorption and complexation of heavy metals is likely to change the mineralogy of soil particle surfaces, which will affect the attachment of bacteria and therefore its transport through soil. This study will benefit long-term predictions of the performance of bioretention ponds for urban stormwater runoff treatment. Keyword: Heavy metal pollution, sorption, surface complexation, urban stormwater runoff, bioretention pond

  2. High performance workflow implementation for protein surface characterization using grid technology

    Directory of Open Access Journals (Sweden)

    Clematis Andrea

    2005-12-01

    Full Text Available Abstract Background This study concerns the development of a high performance workflow that, using grid technology, correlates different kinds of Bioinformatics data, starting from the base pairs of the nucleotide sequence to the exposed residues of the protein surface. The implementation of this workflow is based on the Italian Grid.it project infrastructure, that is a network of several computational resources and storage facilities distributed at different grid sites. Methods Workflows are very common in Bioinformatics because they allow to process large quantities of data by delegating the management of resources to the information streaming. Grid technology optimizes the computational load during the different workflow steps, dividing the more expensive tasks into a set of small jobs. Results Grid technology allows efficient database management, a crucial problem for obtaining good results in Bioinformatics applications. The proposed workflow is implemented to integrate huge amounts of data and the results themselves must be stored into a relational database, which results as the added value to the global knowledge. Conclusion A web interface has been developed to make this technology accessible to grid users. Once the workflow has started, by means of the simplified interface, it is possible to follow all the different steps throughout the data processing. Eventually, when the workflow has been terminated, the different features of the protein, like the amino acids exposed on the protein surface, can be compared with the data present in the output database.

  3. A high-performance lab-on-a-chip liquid sensor employing surface acoustic wave resonance

    Science.gov (United States)

    Kustanovich, K.; Yantchev, V.; Kirejev, V.; Jeffries, G. D. M.; Lobovkina, T.; Jesorka, A.

    2017-11-01

    We demonstrate herein a new concept for lab-on-a-chip in-liquid sensing, through integration of surface acoustic wave resonance (SAR) in a one-port configuration with a soft polymer microfluidic delivery system. In this concept, the reflective gratings of a one-port surface acoustic wave (SAW) resonator are employed as mass loading-sensing elements, while the SAW transducer is protected from the measurement environment. We describe the design, fabrication, implementation, and characterization using liquid medium. The sensor operates at a frequency of 185 MHz and has demonstrated a comparable sensitivity to other SAW in-liquid sensors, while offering quality factor (Q) value in water of about 250, low impedance and fairly low susceptibility to viscous damping. For proof of principle, sensing performance was evaluated by means of binding 40 nm neutravidin-coated SiO2 nanoparticles to a biotin-labeled lipid bilayer deposited over the reflectors. Frequency shifts were determined for every step of the affinity assay. Demonstration of this integrated technology highlights the potential of SAR technology for in-liquid sensing.

  4. Popcorn-Derived Porous Carbon Flakes with an Ultrahigh Specific Surface Area for Superior Performance Supercapacitors.

    Science.gov (United States)

    Hou, Jianhua; Jiang, Kun; Wei, Rui; Tahir, Muhammad; Wu, Xiaoge; Shen, Ming; Wang, Xiaozhi; Cao, Chuanbao

    2017-09-13

    Popcorn-derived porous carbon flakes have been successfully fabricated from the biomass of maize. Utilizing the "puffing effect", the nubby maize grain turned into materials with an interconnected honeycomb-like porous structure composed of carbon flakes. The following chemical activation method enabled the as-prepared products to possess optimized porous structures for electrochemical energy-storage devices, such as multilayer flake-like structures, ultrahigh specific surface area (S BET : 3301 m 2 g -1 ), and a high content of micropores (microporous surface area of 95%, especially the optimized sub-nanopores with the size of 0.69 nm) that can increase the specific capacitance. The as-obtained sample displayed excellent specific capacitance of 286 F g -1 at 90 A g -1 for supercapacitors. Moreover, the unique porous structure demonstrated an ideal way to improve the volumetric energy density performance. A high energy density of 103 Wh kg -1 or 53 Wh L -1 has been obtained in the case of ionic liquid electrolyte, which is the highest among reported biomass-derived carbon materials and will satisfy the urgent requirements of a primary power source for electric vehicles. This work may prove to be a fast, green, and large-scale synthesis route by using the large nubby granular materials to synthesize applicable porous carbons in energy-storage devices.

  5. An investigation on the performance characteristics of solar flat plate collector with different selective surface coatings

    Energy Technology Data Exchange (ETDEWEB)

    Madhukeshwara, N. [Department of Mechanical Engineering, B.I.E.T, Davanagere, Karnataka (India); Prakash, E.S. [Department of Studies in Mechanical Engineering, U.B.D.T.C.E, Davanagere, Karnataka (India)

    2012-07-01

    In the present work, investigations are made to study performance characteristics of solar flat plate collector with different selective surface coatings. Flat plate collector is one of the important solar energy trapping device which uses air or water as working fluid. Of the many solar collector concepts presently being developed, the relative simple flat plate solar collector has found the widest application so far. Its characteristics are known, and compared with other collector types, it is the easiest and least expensive to fabricate, install, and maintain. Moreover, it is capable of using both the diffuse and the direct beam solar radiation. For residential and commercial use, flat plate collectors can produce heat at sufficiently high temperatures to heat swimming pools, domestic hot water, and buildings; they also can operate a cooling unit, particularly if the incident sunlight is increased by the use of reflector. Temperatures up to 70 C are easily attained by flat plate collectors. With very careful engineering using special surfaces, reflectors to increase the incident radiation and heat resistant materials, higher operating temperatures are feasible.

  6. Vapor Phase Polymerization Deposition Conducting Polymer Nanocomposites on Porous Dielectric Surface as High Performance Electrode Materials

    Institute of Scientific and Technical Information of China (English)

    Ya jie Yang; Luning Zhang; Shibin Li; Zhiming Wang; Jianhua Xu; Wenyao Yang; Yadong Jiang

    2013-01-01

    We report chemical vapor phase polymerization(VPP) deposition of poly(3,4-ethylenedioxythiophene)(PEDOT) and PEDOT/graphene on porous dielectric tantalum pentoxide(Ta2O5) surface as cathode films for solid tantalum electrolyte capacitors. The modified oxidant/oxidant-graphene films were first deposited on Ta2O5 by dip-coating, and VPP process was subsequently utilized to transfer oxidant/oxidant-graphene into PEDOT/PEDOT-graphene films. The SEM images showed PEDOT/PEDOT-graphene films was successfully constructed on porous Ta2O5 surface through VPP deposition, and a solid tantalum electrolyte capacitor with conducting polymer-graphene nano-composites as cathode films was constructed. The high conductivity nature of PEDOT-graphene leads to resistance decrease of cathode films and lower contact resistance between PEDOT/graphene and carbon paste. This nano-composite cathode films based capacitor showed ultralow equivalent series resistance(ESR) ca. 12 m? and exhibited excellent capacitance-frequency performance, which can keep 82% of initial capacitance at 500 KHz. The investigation on leakage current revealed that the device encapsulation process has no influence on capacitor leakage current, indicating the excellent mechanical strength of PEDOT/PEDOT-gaphene films. This high conductivity and mechanical strength of graphene-based polymer films shows promising future for electrode materials such as capacitors, organic solar cells and electrochemical energy storage devices.

  7. Laser surface modification of electrically conductive fabrics: Material performance improvement and design effects

    Science.gov (United States)

    Tunakova, Veronika; Hrubosova, Zuzana; Tunak, Maros; Kasparova, Marie; Mullerova, Jana

    2018-01-01

    Development of lightweight flexible materials for electromagnetic interference shielding has obtained increased attention in recent years particularly for clothing, textiles in-house use and technical applications especially in areas of aircraft, aerospace, automobiles and flexible electronics such as portable electronics and wearable devices. There are many references in the literature concerning development and investigation of electromagnetic shielding lightweight flexible materials especially textile based with different electrically conductive additives. However, only little attention is paid to designing and enhancing the properties of these special fabrics by textile finishing processes. Laser technology applied as a physical treatment method is becoming very popular and can be used in different applications to make improvement and even overcome drawbacks of some of the traditional processes. The main purpose of this study is firstly to analyze the possibilities of transferring design onto the surface of electrically conductive fabrics by laser beam and secondly to study of effect of surface modification degree on performance of conductive fabric including electromagnetic shielding ability and mechanical properties. Woven fabric made of yarns containing 10% of extremely thin stainless steel fiber was used as a conductive substrate.

  8. Label-Enhanced Surface Plasmon Resonance: A New Concept for Improved Performance in Optical Biosensor Analysis

    Directory of Open Access Journals (Sweden)

    Niko Granqvist

    2013-11-01

    Full Text Available Surface plasmon resonance (SPR is a well-established optical biosensor technology with many proven applications in the study of molecular interactions as well as in surface and material science. SPR is usually applied in the label-free mode which may be advantageous in cases where the presence of a label may potentially interfere with the studied interactions per se. However, the fundamental challenges of label-free SPR in terms of limited sensitivity and specificity are well known. Here we present a new concept called label-enhanced SPR, which is based on utilizing strongly absorbing dye molecules in combination with the evaluation of the full shape of the SPR curve, whereby the sensitivity as well as the specificity of SPR is significantly improved. The performance of the new label-enhanced SPR method was demonstrated by two simple model assays: a small molecule assay and a DNA hybridization assay. The small molecule assay was used to demonstrate the sensitivity enhancement of the method, and how competitive assays can be used for relative affinity determination. The DNA assay was used to demonstrate the selectivity of the assay, and the capabilities in eliminating noise from bulk liquid composition variations.

  9. Label-Enhanced Surface Plasmon Resonance: A New Concept for Improved Performance in Optical Biosensor Analysis

    Science.gov (United States)

    Granqvist, Niko; Hanning, Anders; Eng, Lars; Tuppurainen, Jussi; Viitala, Tapani

    2013-01-01

    Surface plasmon resonance (SPR) is a well-established optical biosensor technology with many proven applications in the study of molecular interactions as well as in surface and material science. SPR is usually applied in the label-free mode which may be advantageous in cases where the presence of a label may potentially interfere with the studied interactions per se. However, the fundamental challenges of label-free SPR in terms of limited sensitivity and specificity are well known. Here we present a new concept called label-enhanced SPR, which is based on utilizing strongly absorbing dye molecules in combination with the evaluation of the full shape of the SPR curve, whereby the sensitivity as well as the specificity of SPR is significantly improved. The performance of the new label-enhanced SPR method was demonstrated by two simple model assays: a small molecule assay and a DNA hybridization assay. The small molecule assay was used to demonstrate the sensitivity enhancement of the method, and how competitive assays can be used for relative affinity determination. The DNA assay was used to demonstrate the selectivity of the assay, and the capabilities in eliminating noise from bulk liquid composition variations. PMID:24217357

  10. Preliminary measurement performance evaluation of a new white light interferometer for cylindrical surfaces

    International Nuclear Information System (INIS)

    Albertazzi, Armando Jr; Pont, Alex Dal

    2005-01-01

    This paper introduces a new design of a white light interferometer, suitable for measurement of cylindrical or quasi-cylindrical parts. A high precision 45 deg. conical mirror is used to direct collimated light radially, making it possible to measure in true cylindrical coordinates. The image of the measurand, distorted by the conical mirror, is projected in a high resolution digital camera. A mapping algorithm is used to reconstruct the cylindrical geometry from the distorted image. The rest of the interferometer is quite similar to a conventional white light interferometer: A flat reference mirror is scanned through the measurement range while an algorithm is searching for the maximum contrast position of the interference pattern. The performance evaluation of a configuration suitable for measurement of external cylindrical surfaces is also presented in this paper. A master cylinder was used as reference. Uncertainties of about 1.0 μm were found at the present stage of development

  11. BEGe detectors in GERDA Phase I - performance, physics analysis and surface events

    Energy Technology Data Exchange (ETDEWEB)

    Lazzaro, Andrea [Physik-Department E15, Technische Universitaet Muenchen (Germany); Collaboration: GERDA-Collaboration

    2014-07-01

    The Phase I of the Gerda experiment, which has concluded its data taking in Summer 2013, was based on coaxial HPGe detectors already used for IGEX and HdM experiments. In the upcoming Phase II customized Broad Energy Germanium (BEGe) detectors will provide the major contribution to the total exposure. The first set of BEGe detectors has been deployed in Gerda since June 2012. The data collected in Phase I show the performance achieved in terms of spectroscopy and pulse shape discrimination. In particular the strongest background source, the {sup 42}K beta decay from the liquid argon surrounding the detectors, has been effectively rejected. The signals due to beta decay on the detector surface are indeed characterized by a longer charge collection time. This talk focuses on this key feature of the BEGe-PSD.

  12. Effect of surface roughness and Reynolds number on compressor cascade performance

    International Nuclear Information System (INIS)

    Back, Seung Chul; Song, Seung Jin

    2009-01-01

    An experimental work has been conducted in a linear compressor cascade to find out the effect of surface roughness and Reynolds number. Surveys were conducted with different roughness size and Reynolds number. The k s /c value of each roughness is 0.0006, 0.0090, 0.00150, 0.00213, and 0.00425. The range of Reynolds number is 300,000∼600,000 and conducted with roughened blade, which roughness Ra is 2.89 microns. Flow pressure, velocity, and angle have been found out via 5 hole probe. Pressure loss and deviation increased with increasing roughness. In the low Reynolds number under 500,000, tested roughness does not affect to the performance of compressor cascade. However, roughness is very sensitive to pressure loss in high Reynolds number over 550,000.

  13. Performance of coils wound from long lengths of surface-coated, reacted, BSCCO-2212 conductor

    Energy Technology Data Exchange (ETDEWEB)

    Walker, M.S.; Hazelton, D.W.; Gardner, M.T. [Intermagnetics General Corp., Latham, NY (United States)] [and others

    1996-10-01

    React-before-wind surface-coated BSCCO-2212 is being established as a relatively low cost HTS conductor for practical applications. Quality tape is presently being manufactured in 450-500m lengths at a cost estimated to be 1/3-1/5 of the industry costs of BSCCO-2223 powder-in-tube tape. Robust, mechanically sound coils for applications ranging from NMR insert magnets to transformer windings are being made from this BSCCO-2212 tape. The coils have performed consistently through test and thermal cycling without degradation and as projected from short sample measurements. A hybrid approach, which uses mainly BSCCO- 2212 augmented by BSCCO-2223 conductor in the high radial field end regions, is expected to halve magnet system costs.

  14. Performance/Noise Optimization of Centrifugal Fan Using Response Surface Method

    Energy Technology Data Exchange (ETDEWEB)

    Shin, Donghui; Cheong, Cheolung [Pusan Nat’l Univ., Busan (Korea, Republic of); Heo Seung [Korea Aerospace Industries, Sacheon (Korea, Republic of); Kim, Tae-Hoon; Jung, Jiwon [LG Electronics, Seoul (Korea, Republic of)

    2017-03-15

    In this study, centrifugal fan blades used to circulate cold air inside a household refrigerator were optimized to achieve high performance and low noise by using the response surface method, which is frequently employed as an optimization algorithm when multiple independent variables affect one dependent variable. The inlet and outlet blade angles, and the inner radius, were selected as the independent variables. First, the fan blades were optimized to achieve the maximum volume flow rate. Based on this result, a prototype fan blade was manufactured using a 3-D printer. The measured P-Q curves confirmed the increased volume flow rate of the proposed fan. Then, the rotation speed of the new fan was decreased to match the P-Q curve of the existing fan. It was found that a noise reduction of 1.7 dBA could be achieved using the new fan at the same volume flow rate.

  15. Combining surface enhanced Raman scattering (SERS) and high-performance thin-layer chromatography (HPTLC)

    Science.gov (United States)

    Koglin, E.

    A new method for preparing SERS active surfaces using silver colloidal spheres deposited on HPTLC plates, used for thin-layer chromatography, is discussed in detail. The sensitivity of these activated HPTLC plates is so high that in-situ vibrational investigations of chromatogram spots are possible at the nanogram level. The HPTLC/SERS spectra of purine, benzoic acid and 1-nitro-pyrene adsorbed on silver colloidal activated silica gel plates are measured in the nanogram region. In addition we also report in this paper on the results of a feasibility study performed to evaluate the analytical potential of micro-Raman spectroscopy (triple monochromator, multichannel detection system) in SERS/HPTLC spot characterization. It permits the acquisition of Raman spectra from HPTLC spots down to 1 μm in size or other forms of microsamples approaching the picogram level in mass.

  16. Performance/Noise Optimization of Centrifugal Fan Using Response Surface Method

    International Nuclear Information System (INIS)

    Shin, Donghui; Cheong, Cheolung; Heo Seung; Kim, Tae-Hoon; Jung, Jiwon

    2017-01-01

    In this study, centrifugal fan blades used to circulate cold air inside a household refrigerator were optimized to achieve high performance and low noise by using the response surface method, which is frequently employed as an optimization algorithm when multiple independent variables affect one dependent variable. The inlet and outlet blade angles, and the inner radius, were selected as the independent variables. First, the fan blades were optimized to achieve the maximum volume flow rate. Based on this result, a prototype fan blade was manufactured using a 3-D printer. The measured P-Q curves confirmed the increased volume flow rate of the proposed fan. Then, the rotation speed of the new fan was decreased to match the P-Q curve of the existing fan. It was found that a noise reduction of 1.7 dBA could be achieved using the new fan at the same volume flow rate.

  17. Enhanced photovoltaic performance of Sb2S3-sensitized solar cells through surface treatments

    Science.gov (United States)

    Ye, Qing; Xu, Yafeng; Chen, Wenyong; Yang, Shangfeng; Zhu, Jun; Weng, Jian

    2018-05-01

    Efficient antimony sulfide (Sb2S3)-sensitized solar cells were obtained by a sequential treatment with thioacetamide (TA) and 1-decylphosphonic acid (DPA). Compared with the untreated Sb2S3-sensitized solar cells, the power conversion efficiency of the treated Sb2S3 solar cells was improved by 1.80% to 3.23%. The TA treatment improved the Sb2S3 films by reducing impurities and decreasing the film's surface defects, which inhibited the emergence of recombination centers. The DPA treatment reduced the recombination between hole transport materials (HTMs) and the Sb2S3. Therefore, we have presented an efficient strategy to improve the performance of Sb2S3-sensitized solar cells.

  18. Evaluating the effect of vehicle impoundment policy on illegal construction and demolition waste dumping: Israel as a case study.

    Science.gov (United States)

    Seror, Nissim; Hareli, Shlomo; Portnov, Boris A

    2014-08-01

    Construction and demolition (C&D) waste dumped alongside roads and in open areas is a major source of soil and underground water pollution. Since 2006, Israeli ministry for environmental protection enacted a policy of vehicle impoundment (VI) according to which track drivers caught while dumping C&D waste illegally have their vehicles impounded. The present study attempted to determine whether the VI policy was effective in increasing the waste hauling to authorized landfill sites, thus limiting the number of illegal unloads of C&D waste at unauthorized landfill sites and in open areas. During the study, changes in the ratio between the monthly amount of C&D waste brought to authorized landfills sites and the estimated total amount of C&D waste generated in different administrative districts of Israel were examined, before and after the enactment of the 2006 VI policy. Short questionnaires were also distributed among local track drivers in order to determine the degree of awareness about the policy in question and estimate its deterrence effects. According to the study's results, in the district of Haifa, in which the VI policy was stringently enacted, the ratio between C&D waste, dumped in authorized landfill sites, and the total amount of generated C&D waste, increased, on the average, from 20% in January 2004 to 35% in October 2009, with the effect attributed to the number of vehicle impoundments being highly statistically significant (t=2.324; p0.1). The analysis of the questionnaires, distributed among the local truck drivers further indicated that the changes observed in the district of Haifa are not coincident and appeared to be linked to the VI policy's enactment. In particular, 62% of the truck drivers, participated in the survey, were aware of the policy and 47% of them personally knew a driver whose vehicle was impounded. Furthermore, the drivers estimated the relative risk of being caught for unloading C&D waste in unauthorized sites, on the average, as

  19. Corrosion inhibition performance of imidazolium ionic liquids and their influence on surface ferrous carbonate layer formation

    Science.gov (United States)

    Yang, Dongrui

    Corrosion inhibitors as effective anti-corrosion applications were widely studied and drawn much attention in both academe and industrial area. In this work, a systematic work, including inhibitors selection, anti-corrosion property and characterization, influence on scale formation, testing system design and so on, were reported. The corrosion inhibition performance of four imidazolium ionic liquids in carbon dioxide saturated NaCl solution was investigated by using electrochemical and surface analysis technologies. The four compounds are 1-ethyl-3-methylimidazolium chloride (a), 1-butyl-3-methylimidazolium chloride (b), 1-hexyl-3-methylimidazolium chloride (c), 1-decyl-3-methylimidazolium chloride (d). Under the testing conditions, compound d showed the highest inhibition efficiency and selected as the main object of further study. As a selected representative formula, 1-decyl-3-methylimidazolium chloride was studied in detail about its corrosion inhibition performance on mild steel in carbon dioxide saturated NaCl brine at pH 3.8 and 6.8. Electrochemical and surface analysis techniques were used to characterize the specimen corrosion process during the immersion in the blank and inhibiting solutions. The precorrosion of specimen surface showed significant and different influences on the anti-corrosion property of DMICL at pH 3.8 and 6.8. The corrosion inhibition efficiency (IE) was calculated based on parameters obtained from electrochemical techniques; the achieved IE was higher than 98% at the 25th hour for the steel with a well-polished surface at pH 3.8. The fitting parameters obtained from electrochemical data helped to account for the interfacial changes. As proved in previous research, 1-decyl-3-methylimidazolium chloride could be used as good corrosion inhibitors under certain conditions. However, under other conditions, such chemicals, as well as other species in oil transporting system, could be a factor influencing the evolution of protective surface

  20. The Impact of Surface Chemistry on Bio-derived Carbon Performance as Supercapacitor Electrodes

    KAUST Repository

    Alshareef, Husam N.

    2016-12-23

    In this study, we demonstrate that highly functionalized and porous carbons can be derived from palm-leaf waste using the template-free facile synthesis process. The derived carbons have high content of nitrogen dopant, high surface area, and various defects. Moreover, these carbons exhibit a high electrical conductivity (107 S m−1). Thanks to the high content of edge N (64.3%) and highly microporous nature (82% of microspores), these biomass-derived carbons show promising performance when used as supercapacitor electrodes. To be specific, these carbonaceous materials show a specific capacitance as high as 197 and 135 F g−1 at 2 and 20 A g−1 in three-electrode configuration, respectively. Furthermore, the symmetrical cells using palm-leaf-derived carbon show an energy density of 8.4 Wh Kg−1 at a power density of 0.64 kW Kg−1, with high cycling life stability (∼8% loss after 10,000 continuous charge–discharge cycles at 20 A g−1). Interestingly, as the power density increases from 4.4 kW kg−1 to 36.8 kW kg−1, the energy density drops slowly from 8.4 Wh kg−1 to 3.4 Wh kg−1. Getting such extremely high power density without significant loss of energy density indicates that these palm-leaf-derived carbons have excellent electrode performance as supercapacitor electrodes.

  1. Surface-bonded ionic liquid stationary phases in high-performance liquid chromatography--a review.

    Science.gov (United States)

    Pino, Verónica; Afonso, Ana M

    2012-02-10

    Ionic liquids (ILs) are a class of ionic, nonmolecular solvents which remain in liquid state at temperatures below 100°C. ILs possess a variety of properties including low to negligible vapor pressure, high thermal stability, miscibility with water or a variety of organic solvents, and variable viscosity. IL-modified silica as novel high-performance liquid chromatography (HPLC) stationary phases have attracted considerable attention for their differential behavior and low free-silanol activity. Indeed, around 21 surface-confined ionic liquids (SCIL) stationary phases have been developed in the last six years. Their chromatographic behavior has been studied, and, despite the presence of a positive charge on the stationary phase, they showed considerable promise for the separation of neutral solutes (not only basic analytes), when operated in reversed phase mode. This aspect points to the potential for truly multimodal stationary phases. This review attempts to summarize the state-of-the-art about SCIL phases including their preparation, chromatographic behavior, and analytical performance. Copyright © 2011 Elsevier B.V. All rights reserved.

  2. Surface-restrained growth of vertically aligned carbon nanotube arrays with excellent thermal transport performance.

    Science.gov (United States)

    Ping, Linquan; Hou, Peng-Xiang; Liu, Chang; Li, Jincheng; Zhao, Yang; Zhang, Feng; Ma, Chaoqun; Tai, Kaiping; Cong, Hongtao; Cheng, Hui-Ming

    2017-06-22

    A vertically aligned carbon nanotube (VACNT) array is a promising candidate for a high-performance thermal interface material in high-power microprocessors due to its excellent thermal transport property. However, its rough and entangled free tips always cause poor interfacial contact, which results in serious contact resistance dominating the total thermal resistance. Here, we employed a thin carbon cover to restrain the disorderly growth of the free tips of a VACNT array. As a result, all the free tips are seamlessly connected by this thin carbon cover and the top surface of the array is smoothed. This unique structure guarantees the participation of all the carbon nanotubes in the array in the heat transport. Consequently the VACNT array grown on a Cu substrate shows a record low thermal resistance of 0.8 mm 2 K W -1 including the two-sided contact resistances, which is 4 times lower than the best result previously reported. Remarkably, the VACNT array can be easily peeled away from the Cu substrate and act as a thermal pad with excellent flexibility, adhesive ability and heat transport capability. As a result the CNT array with a thin carbon cover shows great potential for use as a high-performance flexible thermal interface material.

  3. Safety performance of a near surface repository subject to a fuel burning

    International Nuclear Information System (INIS)

    Stefanini, Lorenzo; Frano, Rosa Lo; Forasassi, Giuseppe

    2015-01-01

    This study aims to investigate the performances of a near surface repository subject to fuel burning occurring simultaneously or subsequently to a large commercial aircraft impact. Specifically the thermal effects caused by a Boeing-747 crushing (considered like “beyond design basis accident”) are studied. An important part of this study is the analysis of the possible (thermo-mechanical) degradation effects, as dehydration, degasification, pressurization, etc. that the concrete may undergo, particularly in the case of prolonged fire, and of the resistance of structure itself in this condition. Conservative assumptions and restrictions have been made with regard to the fire scenario, the maximum temperature of which is calculated on the basis of the fuel airplane amount, the normal impact, the variation of the material properties along with the temperature as well the damaging phenomena of concrete. The airplane impact load, calculated with the Riera approach, and the maximum temperature, reached during the fuel combustion, are used as input (boundary condition) in the numerical simulations performed by MARC© code. The obtained results showed that a repository wall thickness, ranging from 0.6 to 0.9 m, is not sufficient to prevent the local penetration of wall. To reduce the computational cost, the analyses have been made only on a half part of the structure, highlighting the dominance of thermal effects. Despite the ongoing concrete degradation phenomena, the overall integrity of the repository seemed to be guaranteed as well as the containment and the confinement of radioactive waste. (author)

  4. The Impact of Surface Chemistry on Bio-derived Carbon Performance as Supercapacitor Electrodes

    KAUST Repository

    Alshareef, Husam N.; Whitehair, Daniel; Xia, Chuan

    2016-01-01

    In this study, we demonstrate that highly functionalized and porous carbons can be derived from palm-leaf waste using the template-free facile synthesis process. The derived carbons have high content of nitrogen dopant, high surface area, and various defects. Moreover, these carbons exhibit a high electrical conductivity (107 S m−1). Thanks to the high content of edge N (64.3%) and highly microporous nature (82% of microspores), these biomass-derived carbons show promising performance when used as supercapacitor electrodes. To be specific, these carbonaceous materials show a specific capacitance as high as 197 and 135 F g−1 at 2 and 20 A g−1 in three-electrode configuration, respectively. Furthermore, the symmetrical cells using palm-leaf-derived carbon show an energy density of 8.4 Wh Kg−1 at a power density of 0.64 kW Kg−1, with high cycling life stability (∼8% loss after 10,000 continuous charge–discharge cycles at 20 A g−1). Interestingly, as the power density increases from 4.4 kW kg−1 to 36.8 kW kg−1, the energy density drops slowly from 8.4 Wh kg−1 to 3.4 Wh kg−1. Getting such extremely high power density without significant loss of energy density indicates that these palm-leaf-derived carbons have excellent electrode performance as supercapacitor electrodes.

  5. The effect of surface characteristics of reduced graphene oxide on the performance of a pseudocapacitor

    International Nuclear Information System (INIS)

    Chang, M S; Kim, T; Kang, J H; Park, J; Park, C R

    2015-01-01

    In this research, we have analyzed the electrochemical characteristics of the different rGO/Co 3 O 4 composites prepared by controlling the rGO surface characteristics and its relationship between the growth of Co 3 O 4 nanoparticles and the performance of the pseudocapacitor. Reduced graphene oxide/cobalt oxide (rGO/Co 3 O 4 ) nanocomposites of different morphologies were prepared through the simple hydrothermal method. First, different kinds of graphite precursors, crumpled and planar with different properties, were used to determine the most suitable substrate to grow Co 3 O 4 nanoparticles. As a result, rGO/Co 3 O 4 composite synthesized from planar graphite shows a higher specific capacitance of 207.2, 170.1, and 141.5 Fg −1 at 1, 2, and 5 Ag −1 than the one prepared from crumpled graphite. In the second part, planar graphite, confirmed to be the most suitable substrate from the previous part, was oxidized under various oxidation conditions to increase the oxygen functional groups attached on the GO surfaces and observed to see how it affects the growth of Co 3 O 4 nanoparticles and its influence on the electrochemical performance of the rGO/Co 3 O 4 pseudocapacitor. As a result, the one with the largest amount of functional groups had the Co 3 O 4 nanoparticles well dispersed and grown on the rGO substrate in small nanoparticle sizes, as small as 5.9 nm, leading to an improved electrochemical performance. Thus, the specific capacitance with the least amount of oxygen functional groups are 207.2, 170.1, and 141.5 Fg −1 and for the largest amount of functional groups are 411.5, 371.4, and 292.7 Fg −1 , at 1, 2, and 5 Ag −1 respectively. This approach could become a guideline for the ideal fabrication of rGO/metal oxide composite for further research involving rGO based pseudocapacitors. (paper)

  6. Interaction of phosphorylcholine with fibronectin coatings: Surface characterization and biological performances

    Energy Technology Data Exchange (ETDEWEB)

    Montaño-Machado, Vanessa, E-mail: vanessa.montano-machado.1@ulaval.ca [Laboratory for Biomaterials and Bioengineering, Dept. of Min-Met-Materials Eng., & University Hospital Research Center, Laval University, University Campus, PLT-1745G, Québec, Québec, G1 V 0A6 (Canada); ERRMECe, University of Cergy-Pontoise, Site Saint-Martin, 2 Avenue Adolphe Chauvin, 95302 Cergy-Pontoise Cedex (France); Noël, Céline, E-mail: celine.noel@unamur.be [Research Centre in Physics of Matter and Radiation (PMR), Université de Namur, 61 rue de Bruxelles, B-5000 Namur (Belgium); Chevallier, Pascale, E-mail: pascale.chevallier@crchudequebec.ulaval.ca [Laboratory for Biomaterials and Bioengineering, Dept. of Min-Met-Materials Eng., & University Hospital Research Center, Laval University, University Campus, PLT-1745G, Québec, Québec, G1 V 0A6 (Canada); Turgeon, Stéphane, E-mail: stephane.turgeon@crchudequebec.ulaval.ca [Laboratory for Biomaterials and Bioengineering, Dept. of Min-Met-Materials Eng., & University Hospital Research Center, Laval University, University Campus, PLT-1745G, Québec, Québec, G1 V 0A6 (Canada); Houssiau, Laurent, E-mail: laurent.houssiau@unamur.be [Research Centre in Physics of Matter and Radiation (PMR), Université de Namur, 61 rue de Bruxelles, B-5000 Namur (Belgium); Pauthe, Emmanuel, E-mail: emmanuel.pauthe@u-cergy.fr [ERRMECe, University of Cergy-Pontoise, Site Saint-Martin, 2 Avenue Adolphe Chauvin, 95302 Cergy-Pontoise Cedex (France); and others

    2017-02-28

    Highlights: • Fibronectin/phosphorylcholine coatings on plasma deposited fluorocarbon films were created. • The effect of several coating techniques on the surface biological performances was evaluated. • XPS, DWCA, immunostaining and ToF-SIMS (imaging and depth profiling) techniques were applied. • Potential for cardiovascular applications was showed by endothelial cell and blood interactions. - Abstract: Coating medical devices with several bioactive molecules is an interesting approach to achieve specific biological targets upon the interaction of the biomaterial with the living environment. In this work, a fluorocarbon polymer (CF{sub x}) was first deposited by plasma treatment on stainless steel (SS) substrate and thereafter, coatings containing fibronectin (FN) and phosphorylcholine (PRC) were created for cardiovascular applications. These two biomolecules were chosen to promote endothelialization and to avoid thrombus formation, respectively. Adsorption and grafting techniques were applied – and combined – to accomplish 4 different coatings containing both molecules. However, big challenge was found to characterize a small molecule (PRC: 184 g/mol) interacting with a protein (FN: 450 kD). For the first time XPS, dynamic water contact angle, immunostaining and ToF-SIMS (imaging and depth profiling) analyses were combined to accomplish the characterization of such a coating. The most encouraging biological performances were obtained for samples where FN was grafted to the CF{sub x} film followed by the adsorption of PRC: proliferation of endothelial cells and hemocompatibility properties were observed. Promising coatings for cardiovascular applications were developed. The relevance of characterizing the coatings with high sensitive techniques and the further correlation with their biological performances were evidenced.

  7. Evaluating the Performance of a Surface Barrier on Reducing Soil-Water Flow

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Z. F.; Strickland, Christopher E.; Field, Jim G.; Parker, Danny L.; Clayton, Ray E.

    2012-08-31

    One of the most common effective techniques for contaminant remediation in the vadose zone is to use a surface barrier to reduce or eliminate soil-water flow to reduce the contaminant flux to the underlying groundwater. Confirming the reduction of the soil-water flux rate is challenging because of the difficulty of determining the very low soil-water flux beneath the barrier. We propose a hydraulic-conductivity factor, fK, as a conservative indicator for quantifying the reduction of soil-water flow. The factor can be calculated using the measured soil-water content or pressure but does not require the knowledge of the saturated hydraulic conductivity or the hydraulic gradient. The formulas were tested by comparing with changes in hydraulic conductivity, K, from a drainage experiment. The pressure-based formula was further applied to evaluate the performance of the interim surface barrier at T Tank Farm on Hanford Site. Three years after barrier emplacement, the hydraulic conductivity decreased by a factor between 3.8 and 13.0 at the 1-, 2- and 5-m depths. The difference between the conductivity-reduction factor and the flux-rate-reduction factor, fq, was quantified with a numerical simulation. With the calculated fK, the numerically determined fK/fq ratio, and the assumed pre-barrier soil-water flux rate of 100 mm yr-1, the estimated soil-water flux rate 3 years after barrier emplacement was no more than 8.5 mm yr-1 at or above the 5-m depth.

  8. Experimental assessment of film cooling performance of short cylindrical holes on a flat surface

    Science.gov (United States)

    Singh, Kuldeep; Premachandran, B.; Ravi, M. R.

    2016-12-01

    The present study is an experimental investigation of film-cooling over a flat surface from the short cylindrical holes. The film cooling holes used in the combustion chamber and the afterburner liner of an aero engine has length-to-diameter (L/D) typically in the range 1-2, while the cooling holes used in turbine blades has L/D > 3. Based on the classification given in the literature, cooling holes with L/D ≤ 3 are named as short holes and cooling holes with L/D > 3 are named as long holes. Short film cooling holes cause jetting of the secondary fluid whereas the secondary fluid emerging from long holes has characteristics similar to fully developed turbulent flow in pipe. In order to understand the difference in the film cooling performance of long and short cooling holes, experimental study is carried out for five values of L/D in the range 1-5, five injection angles, α = 15°-90° and five mainstream Reynolds number 1.25 × 105-6.25 × 105 and two blowing ratios, M = 0.5-1.0. The surface temperature of the test plate is monitored using infrared thermography. The results obtained from the present study showed that the film-cooling effectiveness is higher for the longest holes (L/D = 5) investigated in the present work in comparison to that for the shorter holes. Short holes are found to give better effectiveness at the lowest investigated injection angle i.e. α = 15° in the near cooling hole region, whereas film cooling effectiveness obtained at injection angle, α = 45° is found to be better than other injection angles for longest investigated holes, i.e. L/D = 5.

  9. Thirteen-year hardwood tree performance on a Midwest surface mine

    International Nuclear Information System (INIS)

    Ashby, W.C.; Kolar, C.A.

    1998-01-01

    Black walnut (Juglans nigra L.), sweetgum (Liquidambar styraciflua L.), tuliptree (Liriodendron tulipifera L.), white oak (Quercus alba L.), bur oak (Q. macrocarpa Michx.), and pin oak (Q. palustris Muenchh.) seedlings were planted both fall 1980 and spring 1981 on mixed overburden strip-mining banks (ungraded), mixed overburden graded to approximate original contour (AOC) (graded), mixed overburden graded to AOC wit h 60 cm of replaced pre-mining surface soil materials (topsoil), and on old fields near the strip-mine (unmined). Black walnut and pin oak were also planted as seed, with a total of 6000 seedlings/seed spots in the study. Initial species field viability ranged from 86 to 100%. With one exception, after 3 growing seasons oak seedlings had 50% or greater survival. Survival was mostly lower after 3 years with some additional mortality by years 8 and 13. Height and diameter breast height were measured after 13 years. Survival and growth of trees planted fall or spring was similar overall with variable performance by species. Seedlings of several species on the ungraded site had over 50% survival after 13 years, with fewer trees where planted as seed. Mean height of all species combined was significantly greater on the ungraded than on any other site and was lowest on the topsoil site. The unmined sites had high variability in species survival and height. Better reclamation with trees resulted from a deep, well-drained rooting medium with minimal compaction and a mineral-rich surface soil including coarse fragments over 2 mm in size for long-term productivity

  10. Microcrustaceans (Branchiopoda and Copepoda) of Wetland Ponds and Impoundments on the Savannah River Site, Aiken, South Carolina

    Energy Technology Data Exchange (ETDEWEB)

    Adrienne E. DeBiase; Barbara E. Taylor

    2005-09-21

    The United States Department of Energy's Savannah River Site (SRS) in Aiken, Allendale, and Barnwell Counties, South Carolina, contains an abundance of freshwater wetlands and impoundments. Four large impoundments, as well as several small, abandoned farm and mill ponds, and about 400 Carolina bays and other small, isolated depression wetland ponds are located within the 893 km2 area of the SRS. Crustaceans of the orders Branchiopoda and Copepoda are nearly ubiquitous in these water bodies. Although small in size, these organisms are often very abundant. They consequently play an important trophic role in freshwater food webs supporting fish, larval salamanders, larval insects, and numerous other animals, aquatic and terrestrial. This report provides an introduction to the free-living microcrustaceans of lentic water bodies on the SRS and a comprehensive list of species known to occur there. Occurrence patterns are summarized from three extensive survey studies, supplemented with other published and unpublished records. In lieu of a key, we provide a guide to taxonomic resources and notes on undescribed species. Taxa covered include the orders Cladocera, Anostraca, Laevicaudata, and Spinicaudata of the Subclass Branchiopoda and the Superorders Calanoida and Cyclopoida of Subclass Copepoda. Microcrustaceans of the Superorder Harpacticoida of the Subclass Copepoda and Subclass Ostracoda are also often present in lentic water bodies. They are excluded from this report because they have not received much study at the species level on the SRS.

  11. Hydrologic Change during the Colonial Era of the United States: Beavers and the Energy Cost of Impoundments (Invited)

    Science.gov (United States)

    Green, M. B.; Bain, D. J.; Arrigo, J. S.; Duncan, J. M.; Kumar, S.; Parolari, A.; Salant, N.; Vorosmarty, C. J.; Aloysius, N. R.; Bray, E. N.; Ruffing, C. M.; Witherell, B. B.

    2009-12-01

    Europeans colonized North America in the early 17th century with intentions ranging between long-term inhabitation and quick extraction of resources for economic gain in Europe. Whatever the intentions, the colonists relied on the landscape for resources resulting in dramatic change to the forest and fur-bearing mammal population. We demonstrate that initial exploitation of North American forest and furs caused a substantial decrease in mean water residence time (τ) between 1600 and 1800 A.D. That loss, which regionally changed from 51 to 41 days, contrasts with conventional wisdom that humans tend to diminish variability in water resources by increasing storage capacity and thus increasing τ. The loss of τ resulted from over-hunted beaver for the hat market in Europe. Analysis suggests that colonial era demographics and economics did not allow human resource allocation to impoundment construction on a level matching the historic beaver effort. However, the τ appears to have regionally increased during the 19th century, suggesting that humans eventually began replacing the water storage lost with the beaver. The analysis highlights the energy cost of impounding water, which is likely to continue to be an important factor given the increasing need for stable water resources and finite energy resources.

  12. A Risk Assessment Approach to Manage Inundation of Elseya albagula Nests in Impounded Waters: A Win-Win Situation?

    Science.gov (United States)

    McDougall, A. J.; Espinoza, T.; Hollier, C.; Limpus, D. J.; Limpus, C. J.

    2015-03-01

    A risk assessment process was used to trial the impact of potential new operating rules on the frequency of nest inundation for the White-throated snapping turtle, Elseya albagula, in the impounded waters of the Burnett River, Queensland, Australia. The proposed operating rules would increase the barrage storage level during the turtle nesting season (May-July) and then would be allowed to reduce to a lower level for incubation for the rest of the year. These proposed operating rules reduce rates of nest inundation by altering water levels in the Ben Anderson Barrage impoundment of the Burnett River. The rules operate throughout the turtle reproductive period and concomitantly improve stability of littoral habitat and fishway operation. Additionally, the proposed rules are expected to have positive socio-economic benefits within the region. While regulated water resources will inherently have a number of negative environmental implications, these potential new operating rules have the capacity to benefit the environment while managing resources in a more sustainable manner. The operating rules have now been enacted in subordinate legislation and require the operator to maintain water levels to minimize turtle nest inundation.

  13. High-Performance, Large Format Surfaces for Surface-Enhanced Raman Spectroscopy: Increasing the Accessibility of an Analytical Platform

    Science.gov (United States)

    Kanipe, Katherine Nicole

    Although surface-enhanced Raman spectroscopy (SERS) is a spectroscopic technique with unusually high sensitivity and molecular specificity, few practical analytical applications have been implemented that take advantage of its power. Based on what is understood about SERS from the experimental and theoretical research of the past forty years, we developed a few well-defined design principles on the basis of which a reliable and reproducibly manufacturable SERS-active substrate could be fabricated that is highly enhancing, highly uniform, stable, and based on a broad range of metals so that various chemical processes could be probed. Finally, we restricted ourselves to using only readily scalable fabrication techniques. The resulting SERS-active device was a metal over silica, two-dimensional nano-grating that was shown to produce enhancements of ˜107 when compared to a smooth surface of the same metal. This SERS substrate also shows unprecedented signal uniformity over square centimeters, and is fabricated using commonly-available foundry-based approaches exclusively. Initially, we explored the properties of a gold-coated substrates in which a first-order grating resonance due to long-range symmetry is augmented by a local resonance due to the individual core-shell grating elements. The SERS properties of such grating systems were systematically studied as a function of various structural parameters such as the grating pitch, the inter-element gap and the thickness of the metal layer. The most enhancing substrates were found to have a grating parameter with a radiative, rather than evanescent, first-order resonance; a sufficiently small gap between nearest neighbor grating elements to produce near-field interactions; and a gold layer whose thickness was larger than the electronic mean-free-path of the conduction electrons, so as to ensure a high conductivity for the metal layer to sustain strong surface plasmons. We applied these same architectural principles to

  14. Cellular Performance Comparison of Biomimetic Calcium Phosphate Coating and Alkaline-Treated Titanium Surface

    Directory of Open Access Journals (Sweden)

    Xiaohua Yu

    2013-01-01

    Full Text Available The influence of biomimetic calcium phosphate coating on osteoblasts behavior in vitro is not well established yet. In this study, we investigated the behavior of osteoblastic rat osteosarcoma 17/2.8 cells (ROS17/2.8 on two groups of biomaterial surfaces: alkaline-treated titanium surface (ATT and biomimetic calcium phosphate coated ATT (CaP. The cell attachment, proliferation, differentiation, and morphology on these surfaces were extensively evaluated to reveal the impact of substrate surface on osteoblastic cell responses. It was found that the ROS17/2.8 cells cultured on the ATT surface had higher attachment and proliferation rates compared to those on the CaP surface. Our results also showed that the calcium phosphate coatings generated in this work have an inhibiting effect on osteoblast adhesion and further influenced the proliferation and differentiation of osteoblast compared to the ATT surface in vitro. Cells on the ATT surface also exhibited a higher alkaline phosphatase activity than on the CaP surface after two weeks of culture. Immunofluorescence staining and scanning electron microscopy results showed that the cells adhered and spread faster on the ATT surface than on the CaP surface. These results collectively suggested that substrate surface properties directly influence cell adhesion on different biomaterials, which would result in further influence on the cell proliferation and differentiation.

  15. Towards a Performance Evaluation Method for Durable and Sustainable Thin Surfacings

    NARCIS (Netherlands)

    Xiao, Y.

    2013-01-01

    Thin surfacings are widely used as surface layers to provide additional functions and to extend the service life of existing pavements. They can protect the treated road surfaces from external aggressive substances, the degeneration process of weather and the ageing caused by Ultraviolet light and

  16. Optical performance of random anti-reflection structured surfaces (rARSS) on spherical lenses

    Science.gov (United States)

    Taylor, Courtney D.

    Random anti-reflection structured surfaces (rARSS) have been reported to improve transmittance of optical-grade fused silica planar substrates to values greater than 99%. These textures are fabricated directly on the substrates using reactive-ion/inductively-coupled plasma etching (RIE/ICP) techniques, and often result in transmitted spectra with no measurable interference effects (fringes) for a wide range of wavelengths. The RIE/ICP processes used in the fabrication process to etch the rARSS is anisotropic and thus well suited for planar components. The improvement in spectral transmission has been found to be independent of optical incidence angles for values from 0° to +/-30°. Qualifying and quantifying the rARSS performance on curved substrates, such as convex lenses, is required to optimize the fabrication of the desired AR effect on optical-power elements. In this work, rARSS was fabricated on fused silica plano-convex (PCX) and plano-concave (PCV) lenses using a planar-substrate optimized RIE process to maximize optical transmission in the range from 500 to 1100 nm. An additional set of lenses were etched in a non-optimized ICP process to provide additional comparisons. Results are presented from optical transmission and beam propagation tests (optimized lenses only) of rARSS lenses for both TE and TM incident polarizations at a wavelength of 633 nm and over a 70° full field of view in both singlet and doublet configurations. These results suggest optimization of the fabrication process is not required, mainly due to the wide angle-of-incidence AR tolerance performance of the rARSS lenses. Non-optimized recipe lenses showed low transmission enhancement, and confirmed the need to optimized etch recipes prior to process transfer of PCX/PCV lenses. Beam propagation tests indicated no major beam degradation through the optimized lens elements. Scanning electron microscopy (SEM) images confirmed different structure between optimized and non-optimized samples

  17. Development of performance assessment methodology for establishment of quantitative acceptance criteria of near-surface radioactive waste disposal

    Energy Technology Data Exchange (ETDEWEB)

    Kim, C. R.; Lee, E. Y.; Park, J. W.; Chang, G. M.; Park, H. Y.; Yeom, Y. S. [Korea Hydro and Nuclear Power Co., Ltd., Seoul (Korea, Republic of)

    2002-03-15

    The contents and the scope of this study are as follows : review of state-of-the-art on the establishment of waste acceptance criteria in foreign near-surface radioactive waste disposal facilities, investigation of radiological assessment methodologies and scenarios, investigation of existing models and computer codes used in performance/safety assessment, development of a performance assessment methodology(draft) to derive quantitatively radionuclide acceptance criteria of domestic near-surface disposal facility, preliminary performance/safety assessment in accordance with the developed methodology.

  18. La modified TiO{sub 2} photoanode and its effect on DSSC performance: A comparative study of doping and surface treatment on deep and surface charge trapping

    Energy Technology Data Exchange (ETDEWEB)

    Ako, Rajour Tanyi [Faculty of Science, Universiti Brunei Darussalam, Jalan Tungku Link, BE1410, Negara Brunei Darussalam (Brunei Darussalam); Ekanayake, Piyasiri, E-mail: piyasiri.ekanayake@ubd.edu.bn [Faculty of Science, Universiti Brunei Darussalam, Jalan Tungku Link, BE1410, Negara Brunei Darussalam (Brunei Darussalam); Centre for Advanced Material and Energy Sciences (CAMES), Universiti Brunei Darussalam, Jalan Tungku Link, BE1410, Negara Brunei Darussalam (Brunei Darussalam); Tan, Ai Ling [Faculty of Science, Universiti Brunei Darussalam, Jalan Tungku Link, BE1410, Negara Brunei Darussalam (Brunei Darussalam); Young, David James [Faculty of Science, Universiti Brunei Darussalam, Jalan Tungku Link, BE1410, Negara Brunei Darussalam (Brunei Darussalam); Faculty of Science, Health, Education and Engineering, University of the Sunshine Coast, Maroochydore DC, Queensland, 4558 (Australia); Institute of Materials Research and Engineering (IMRE), Agency for Science, Technology and Research - A*STAR, #08-03, 2 Fusionopolis Way, Innovis, 138634 (Singapore)

    2016-04-01

    The effect of Lanthanum ions (La{sup 3+}) on charge trapping in dye-sensitized solar cell (DSSC) photoanodes has been investigated with doped and surface-treated TiO{sub 2} nanoparticles. Doped nanoparticles consisting of 0.5 mol.% Mg and La co-doped TiO{sub 2}, 0.5 mol.% Mg doped TiO{sub 2} and pure TiO{sub 2} were synthesized by the sol gel method. Surface-treated nanoparticles of Mg doped TiO{sub 2} and pure TiO{sub 2} were prepared by ball milling in 0.05 M aqueous La{sup 3+} solution. All materials were analyzed by XRD, XPS and UV–Vis DRS. Cell performance, surface free energy state changes and electron injection efficiency of DSSCs based on these nanoparticles were evaluated using current –voltage measurements, EIS and Incident photon to current conversion efficiency. Doped materials had La and Mg ions incorporated into the TiO{sub 2} lattice, while no lattice changes were observed for the surface-treated materials. Less visible light was absorbed by treated oxides compared with doped oxide samples. The overall power conversion efficiencies (PCE) of DSSC photoanodes based on doped materials were twice those of photoanodes fabricated from treated nanoparticles. Doping establishes deep traps that reduce the recombination of electron–hole (e–h) pairs. Conversely, the presence of absorbed oxygen in treated materials enhances e–h recombination with electrolyte at surface trap sites. - Highlights: • DSSC performance is investigated using photoanodes of doped and La{sup 3+} surface treated TiO{sub 2}. • TiO{sub 2} and Mg–TiO{sub 2} treated with La{sup 3+} absorbed less visible light. • A high concentration of absorbed oxygen on surface treated oxides reduced band bending. • Increased surface free energy in the modified DSSC anodes is caused more by Mg{sup 2+} at Ti{sup 4+} than by La{sup 3+} at the surfaces. • Near surface charge traps due to La{sup 3+} treatment promotes e–h recombination.

  19. Model development and optimization of operating conditions to maximize PEMFC performance by response surface methodology

    International Nuclear Information System (INIS)

    Kanani, Homayoon; Shams, Mehrzad; Hasheminasab, Mohammadreza; Bozorgnezhad, Ali

    2015-01-01

    Highlights: • The optimization of the operating parameters in a serpentine PEMFC is done using RSM. • The RSM model can predict the cell power over the wide range of operating conditions. • St-An, St-Ca and RH-Ca have an optimum value to obtain the best performance. • The interactions of the operating conditions affect the output power significantly. • The cathode and anode stoichiometry are the most effective parameters on the power. - Abstract: Optimization of operating conditions to obtain maximum power in PEMFCs could have a significant role to reduce the costs of this emerging technology. In the present experimental study, a single serpentine PEMFC is used to investigate the effects of operating conditions on the electrical power production of the cell. Four significant parameters including cathode stoichiometry, anode stoichiometry, gases inlet temperature, and cathode relative humidity are studied using Design of Experiment (DOE) to obtain an optimal power. Central composite second order Response Surface Methodology (RSM) is used to model the relationship between goal function (power) and considered input parameters (operating conditions). Using this statistical–mathematical method leads to obtain a second-order equation for the cell power. This model considers interactions and quadratic effects of different operating conditions and predicts the maximum or minimum power production over the entire working range of the parameters. In this range, high stoichiometry of cathode and low stoichiometry of anode results in the minimum cell power and contrary the medium range of fuel and oxidant stoichiometry leads to the maximum power. Results show that there is an optimum value for the anode stoichiometry, cathode stoichiometry and relative humidity to reach the best performance. The predictions of the model are evaluated by experimental tests and they are in a good agreement for different ranges of the parameters

  20. Clinical performance of a new hepatitis B surface antigen quantitative assay with automatic dilution

    Directory of Open Access Journals (Sweden)

    Ta-Wei Liu

    2015-01-01

    Full Text Available Hepatitis B virus surface antigen (HBsAg levels reflect disease status and can predict the clinical response to antiviral treatment; however, the emergence of HBsAg mutant strains has become a challenge. The Abbott HBsAg quantification assay provides enhanced detection of HBsAg and HBsAg mutants. We aimed to evaluate the performance of the Abbott HBsAg quantification assay with automatic sample dilutions (shortened as automatic Architect assay, compared with the Abbott HBsAg quantification assay with manual sample dilutions (shortened as manual Architect assay and the Roche HBsAg quantification assay with automatic sample dilutions (shortened as Elecsys. A total of 130 sera samples obtained from 87 hepatitis B virus (HBV-infected patients were collected to assess the correlation between the automatic and manual Architect assays. Among the 87 patients, 41 provided 42 sera samples to confirm the linearity and reproducibility of the automatic Architect assay, and find out the correlation among the Elecsys and two Architect assays. The coefficients of variation (0.44–9.53% and R2 = 0.996–1, which were both determined using values obtained from the automatic Architect assay, showed good reproducibility and linearity. Results of the two Architect assays demonstrated a feasible correlation (n = 130 samples; R = 0.898, p  0.93 in all cases. In conclusion, the correlation between the automatic and manual dilution Architect assays was feasible, particularly in the HBeAg-negative and low DNA groups. With lower labor costs and less human error than the manual version, the Abbott automatic dilution Architect assay provided a good clinical performance with regard to the HBsAg levels.

  1. Effect of longitudinal grooves of the scallop surface on aerodynamic performance

    International Nuclear Information System (INIS)

    Kim, Tae Hun; Choi, Hae Cheon

    2008-01-01

    Some of the scallops like Amesium balloti have an excellent level-swimming ability, i.e. they can swim about 20m by single level swimming with a maximum swimming velocity of about 1.6m/s in the sea. On the other hand, some species like Patinopecten yessoensis have longitudinal grooves on the upper and lower surfaces and others do not. Therefore, in the present study, we measure the lift and drag forces on a real scallop model (Patinopecten yessoensis) in a wind tunnel. Experiments are performed at the Reynolds number of 75,000 based on the maximum chord length, which is within the swimming condition of real scallop (Re=30,000∼300,000). To see the effect of longitudinal grooves, we measure the aerodynamic forces on a scallop model by removing the grooves. With the grooves, the lift force increases at low angles of attack (α<10 .deg.). The drag force increases slightly at all the attack angles considered. The lift-to-drag ratio is increased by about 10% at α<10 .deg.

  2. Performance Evaluation of a Modular Design of Wind Tower with Wetted Surfaces

    Directory of Open Access Journals (Sweden)

    Sajad M.R. Khani

    2017-06-01

    Full Text Available Wind towers or wind catchers, as passive cooling systems, can provide natural ventilation in buildings located in hot, arid regions. These natural cooling systems can provide thermal comfort for the building inhabitants throughout the warm months. In this paper, a modular design of a wind tower is introduced. The design, called a modular wind tower with wetted surfaces, was investigated experimentally and analytically. To determine the performance of the wind tower, air temperature, relative humidity (RH and air velocity were measured at different points. Measurements were carried out when the wind speed was zero. The experimental results were compared with the analytical ones. The results illustrated that the modular wind tower can decrease the air temperature significantly and increase the relative humidity of airflow into the building. The average differences for air temperature and air relative humidity between ambient air and air exiting from the wind tower were approximately 10 °C and 40%, respectively. The main advantage of the proposed wind tower is that it is a modular design that can reduce the cost of wind tower construction.

  3. Effect of filler surface functionalization on the performance of Nafion/Titanium oxide composite membranes

    International Nuclear Information System (INIS)

    Bonis, Catia de; Cozzi, Dafne; Mecheri, Barbara; D'Epifanio, Alessandra; Rainer, Alberto; De Porcellinis, Diana; Licoccia, Silvia

    2014-01-01

    The phenylsulfonic functionalized nanometric titania (TiO 2 -PhSO 3 H) was synthesized to be used as filler in Nafion-based composite membranes for direct methanol fuel cell (DMFC) applications. The organic moieties were covalently bound on the surface of TiO 2 nanoparticles and the hybrid product was characterized by Fourier transform infrared (FT-IR) spectroscopy, thermogravimetric and differential thermal analysis (TG/DTA), field emission scanning electron microscopy (FE-SEM), and X-ray diffraction (XRD) analysis. TiO 2 -PhSO 3 H showed higher ion exchange capacity (IEC) and proton conductivity values with respect to those of TiO 2 . The incorporation of TiO 2 -PhSO 3 H in Nafion led to a mechanical reinforcement of the membranes and higher conductivity than that obtained with unfilled Nafion. The composite membrane containing 10 wt.% of TiO 2 -PhSO 3 H showed an increased crystallinity and the highest conductivity, reaching 0.11 S cm −1 at 140 °C. DMFC tests were carried out showing that the use of the organic-inorganic hybrid filler leads to a general improvement in the cell performance, in terms of higher current and power density and reduced methanol crossover

  4. Influence of hummocks and emergent vegetation on hydraulic performance in a surface flow wastewater treatment wetland

    Science.gov (United States)

    Keefe, Steffanie H.; Daniels, Joan S.; Runkel, Robert L.; Wass, Roland D.; Stiles, Eric A.; Barber, Larry B.

    2010-01-01

    A series of tracer experiments were conducted biannually at the start and end of the vegetation growing season in a surface flow wastewater treatment wetland located near Phoenix, AZ. Tracer experiments were conducted prior to and following reconfiguration and replanting of a 1.2 ha treatment wetland from its original design of alternating shallow and deep zones to incorporate hummocks (shallow planting beds situated perpendicular to flow). Tracer test data were analyzed using analysis of moments and the one‐dimensional transport with inflow and storage numerical model to evaluate the effects of the seasonal vegetation growth cycle and hummocks on solute transport. Following reconfiguration, vegetation coverage was relatively small, and minor changes in spatial distribution influenced wetland hydraulics. During start‐up conditions, the wetland underwent an acclimation period characterized by small vegetation coverage and large transport cross‐sectional areas. At the start of the growing season, new growth of emergent vegetation enhanced hydraulic performance. At the end of the growing season, senescing vegetation created short‐circuiting. Wetland hydrodynamics were associated with high volumetric efficiencies and velocity heterogeneities. The hummock design resulted in breakthrough curves characterized by multiple secondary tracer peaks indicative of varied flow paths created by bottom topography.

  5. Thermal performance of a spirally coiled finned tube heat exchanger under wet-surface conditions

    International Nuclear Information System (INIS)

    Wongwises, Somchai; Naphon, Paisarn

    2006-01-01

    This paper is a continuation of the author's previous work on spiral coil heat exchangers. In the present study, the heat transfer characteristics and the performance of a spirally coiled finned tube heat exchanger under wet-surface conditions are theoretically and experimentally investigated. The test section is a spiral-coil heat exchanger which consists of a steel shell and a spirally coiled tube unit. The spiral-coil unit consists of six layers of concentric spirally coiled finned tubes. Each tube is fabricated by bending a 9.6 mm diameter straight copper tube into a spiral-coil of four turns. The innermost and outermost diameters of each spiral-coil are 145.0 and 350.4 mm, respectively. Aluminium crimped spiral fins with thickness of 0.6 mm and outer diameter of 28.4 mm are placed around the tube. The edge of fin at the inner diameter is corrugated. Air and water are used as working fluids in shell side and tube side, respectively. The experiments are done under dehumidifying conditions. A mathematical model based on the conservation of mass and energy is developed to simulate the flow and heat transfer characteristics of working fluids flowing through the heat exchanger. The results obtained from the present model show reasonable agreement with the experimental data

  6. Performance improvement studies for cutting tools with perforated surface in turning of titanium alloy

    Directory of Open Access Journals (Sweden)

    Charitha Rao

    2018-01-01

    Full Text Available In turning process, the cutting tool is essential for shaping materials. The cutting tools with various perforated surfaces help to increase the cutting tool life. Also, advances in CNC machining technologies have enhanced the productivity of machining process. One of the best or futuristic approaches in modern manufacturing engineering is the use of FEM Simulation for the metal cutting process. FEM simulation helps in understanding the metal deformation process and also helps in the reduction of experiments. The simulation helps the researchers to predict the major influencing cutting variable values without carrying out any experiment which is time-consuming and expensive. This research presents the simulation study of the performance of micro-hole patterned Polycrystalline Diamond cutting insert in machining Titanium alloy (Ti-6Al-4V. Micro-holes are drilled using Electrical Discharge Wire Drilling machine on the rake face of Polycrystalline Diamond (PCD cutting inserts. FEM analysis is carried out to evaluate the effect of perforations on the mechanical integrity of insert. The micro-hole patterned insert is modeled in PRO-E modeler and simulated using DEFORM-3D software. The effective stress, strain, and temperature distribution are analyzed and the results are compared with the normal insert.

  7. AlScN thin film based surface acoustic wave devices with enhanced microfluidic performance

    International Nuclear Information System (INIS)

    Wang, W B; Xuan, W P; Chen, J K; Wang, X Z; Luo, J K; Fu, Y Q; Chen, J J; Duan, P F; Mayrhofer, P; Bittner, A; Schmid, U

    2016-01-01

    This paper reports the characterization of scandium aluminum nitride (Al 1−xS c xN , x   =  27%) films and discusses surface acoustic wave (SAW) devices based on them. Both AlScN and AlN films were deposited on silicon by sputtering and possessed columnar microstructures with (0 0 0 2) crystal orientation. The AlScN/Si SAW devices showed improved electromechanical coupling coefficients ( K 2 , ∼2%) compared with pure AlN films (<0.5%). The performance of the two types of devices was also investigated and compared, using acoustofluidics as an example. The AlScN/Si SAW devices achieved much lower threshold powers for the acoustic streaming and pumping of liquid droplets, and the acoustic streaming and pumping velocities were 2  ×  and 3  ×  those of the AlN/Si SAW devices, respectively. Mechanical characterization showed that the Young’s modulus and hardness of the AlN film decreased significantly when Sc was doped, and this was responsible for the decreased acoustic velocity and resonant frequency, and the increased temperature coefficient of frequency, of the AlScN SAW devices. (paper)

  8. Screening Assessment of Radionuclide Migration in Groundwater from the “Dneprovskoe” Tailings Impoundment (Dneprodzerzhynsk City) and Evaluation of Remedial Options

    Energy Technology Data Exchange (ETDEWEB)

    Skalskyi, O.; Bugai, D. [Institute of Geological Sciences, National Academy of Sciences of Ukraine (Ukraine); Ryazantsev, V. [State Nuclear Regularity Committee of Ukraine, Kiev (Ukraine)

    2014-05-15

    The paper presents results of mathematical modeling of the hydrogeological conditions at the “Dneprovskoe” (“D”) tailings impoundment –object of the former industrial association of “Pridneprovsky Chemical Plant”, which contains uranium ore processing wastes. This radioactively polluted site is located in a densely populated region (at the outskirts of Dneprodzerginsk City) near the major watercourse of the Ukraine — Dnieper River.The mathematical modeling utilized Visual Modflow (for groundwater flow) and Ecolego (Facilia AB, Sweden) radioecology modeling software (for radionuclide transport).Modeling results indicate the possibility of essential radioactive contamination in future of the phreatic aquifer in alluvial deposits between the “D” tailings and the Dnieper River (mainly due to migration of uranium). Therefore long-term management strategies should preclude water usage from the aquifer in the zone of the in-fluence of the “D” tailings. Filtration discharge of uranium to the Dnepr River does not represent a significant risk due to large dilution by surface waters. The important modeling conclusion is that besides the uranium ore processing wastes inside the tailings, the major source of radionuclide migration to groundwater is represented by contaminated geological deposits below the tailings. This last source was formed due to leakage of wastewaters during the operational period of the “D” tailings (1954–1968). Therefore an exemption and re-disposal of wastes from the “D” tailings to a more safe storage location (proposed by some remedial plans) will not provide significant benefit from the viewpoint of minimizing of radionuclide transport to the groundwater and Dnieper River (especially in short-and medium-term perspective). The rational remedial strategy for the “D” tailings is conservation of tailing wastes in-situ by means of specially designed “zero flux” soil screen, which would minimize infiltration of

  9. Surface flashover performance of epoxy resin microcomposites improved by electron beam irradiation

    Energy Technology Data Exchange (ETDEWEB)

    Huang, Yin; Min, Daomin [State Key Laboratory of Electrical Insulation and Power Equipment, Xi' an Jiaotong University, Xi' an 710049 (China); Li, Shengtao, E-mail: stli@mail.xjtu.edu.cn [State Key Laboratory of Electrical Insulation and Power Equipment, Xi' an Jiaotong University, Xi' an 710049 (China); Li, Zhen; Xie, Dongri [State Key Laboratory of Electrical Insulation and Power Equipment, Xi' an Jiaotong University, Xi' an 710049 (China); Wang, Xuan [Key Laboratory of Engineering Dielectric and its Application, Ministry of Education, Harbin University of Science and Technology, Harbin 150040 (China); Lin, Shengjun [State Key Laboratory of Electrical Insulation and Power Equipment, Xi' an Jiaotong University, Xi' an 710049 (China); Pinggao Group Company Ltd., State Grid High Voltage Switchgear Insulation Materials Laboratory, Pingdingshan 467001 (China)

    2017-06-01

    Highlights: • Epoxy resin microcomposites were irradiated by electron beam with energies of 10 and 20 keV. • Surface flashover voltage increase with the increase of electron beam energy. • Both the untreated and irradiated samples have two trap centers, which are labeled as shallow and deep traps. • Deposition energy in epoxy resin microcomposites increases with electron beam energy, and surface trap properties are determined by deposition energy. • The influence of surface conductivity and trap distribution on flashover voltage is discussed. - Abstract: The influencing mechanism of electron beam irradiation on surface flashover of epoxy resin/Al{sub 2}O{sub 3} microcomposite was investigated. Epoxy resin/Al{sub 2}O{sub 3} microcomposite samples with a diameter of 50 mm and a thickness of 1 mm were prepared. The samples were irradiated by electron beam with energies of 10 and 20 keV and a beam current of 5 μA for 5 min. Surface potential decay, surface conduction, and surface flashover properties of untreated and irradiated samples were measured. Both the decay rate of surface potential and surface conductivity decrease with an increase in the energy of electron beam. Meanwhile, surface flashover voltage increase. It was found that both the untreated and irradiated samples have two trap centers, which are labeled as shallow and deep traps. The increase in the energy and density of deep surface traps enhance the ability to capture primary emitted electrons. In addition, the decrease in surface conductivity blocks electron emission at the cathode triple junction. Therefore, electron avalanche at the interface between gas and an insulating material would be suppressed, eventually improving surface flashover voltage of epoxy resin microcomposites.

  10. Surface engineering of ferroelectric polymer for the enhanced electrical performance of organic transistor memory

    Science.gov (United States)

    Kim, Do-Kyung; Lee, Gyu-Jeong; Lee, Jae-Hyun; Kim, Min-Hoi; Bae, Jin-Hyuk

    2018-05-01

    We suggest a viable surface control method to improve the electrical properties of organic nonvolatile memory transistors. For viable surface control, the surface of the ferroelectric insulator in the memory field-effect transistors was modified using a smooth-contact-curing process. For the modification of the ferroelectric polymer, during the curing of the ferroelectric insulators, the smooth surface of a soft elastomer contacts intimately with the ferroelectric surface. This smooth-contact-curing process reduced the surface roughness of the ferroelectric insulator without degrading its ferroelectric properties. The reduced roughness of the ferroelectric insulator increases the mobility of the organic field-effect transistor by approximately eight times, which results in a high memory on–off ratio and a low-voltage reading operation.

  11. Performance verification of focus variation and confocal microscopes measuring tilted ultra-fine surfaces

    DEFF Research Database (Denmark)

    Quagliotti, Danilo; Baruffi, Federico; Tosello, Guido

    2016-01-01

    The behaviour of two optical instruments, scilicet a laser scanning confocal microscope and a focus-variation microscope, was investigated considering measurements of tilted surfaces. The measured samples were twelve steel artefacts for mould surface finish reference, covering Sa roughness...... parameter in the range (101—103) nm. The 3D surface texture parameters considered were Sa, Sq and Sdq. The small working distance of the confocal microscope objectives influenced the measurement setup, preventing from selecting a high tilting angle. The investigation was carried out comparing measurements...... of flat surfaces (0° tilt) with measurements of 12.5° tilted surfaces. The confocal microscope results showed a high sensitivity to tilting due to the laser beam reflection on the metal surfaces. The focus variation microscope results were more robust with respect to the considered angular variation...

  12. Improved laser damage threshold performance of calcium fluoride optical surfaces via Accelerated Neutral Atom Beam (ANAB) processing

    Science.gov (United States)

    Kirkpatrick, S.; Walsh, M.; Svrluga, R.; Thomas, M.

    2015-11-01

    Optics are not keeping up with the pace of laser advancements. The laser industry is rapidly increasing its power capabilities and reducing wavelengths which have exposed the optics as a weak link in lifetime failures for these advanced systems. Nanometer sized surface defects (scratches, pits, bumps and residual particles) on the surface of optics are a significant limiting factor to high end performance. Angstrom level smoothing of materials such as calcium fluoride, spinel, magnesium fluoride, zinc sulfide, LBO and others presents a unique challenge for traditional polishing techniques. Exogenesis Corporation, using its new and proprietary Accelerated Neutral Atom Beam (ANAB) technology, is able to remove nano-scale surface damage and particle contamination leaving many material surfaces with roughness typically around one Angstrom. This surface defect mitigation via ANAB processing can be shown to increase performance properties of high intensity optical materials. This paper describes the ANAB technology and summarizes smoothing results for calcium fluoride laser windows. It further correlates laser damage threshold improvements with the smoothing produced by ANAB surface treatment. All ANAB processing was performed at Exogenesis Corporation using an nAccel100TM Accelerated Particle Beam processing tool. All surface measurement data for the paper was produced via AFM analysis on a Park Model XE70 AFM, and all laser damage testing was performed at Spica Technologies, Inc. Exogenesis Corporation's ANAB processing technology is a new and unique surface modification technique that has demonstrated to be highly effective at correcting nano-scale surface defects. ANAB is a non-contact vacuum process comprised of an intense beam of accelerated, electrically neutral gas atoms with average energies of a few tens of electron volts. The ANAB process does not apply mechanical forces associated with traditional polishing techniques. ANAB efficiently removes surface

  13. The performance of a surface-applied corrosion inhibitor for the carbon steel in saturated Ca(OH)2 solutions

    International Nuclear Information System (INIS)

    Zheng, Haibing; Li, Weihua; Ma, Fubin; Kong, Qinglin

    2014-01-01

    In the present work, the performance of an amino alcohol based surface applied inhibitor was studied by the electrochemical techniques in saturated Ca(OH) 2 solutions. The surface morphology of the carbon steel was observed by scanning electron microscope, and the energy diffraction spectrum was also tested. Results showed that the inhibitor used in this work demonstrated obvious inhibition efficiency on the carbon steel in saturated Ca(OH) 2 solutions. The inhibition mechanism of the inhibitor lies in the quick adsorption of the active component on carbon steel surface

  14. Influences of the wavy surface inserted in the middle of a circular tube heat exchanger on thermal performance

    Energy Technology Data Exchange (ETDEWEB)

    Jedsadaratanancai, Withada [King Mongkut' s Institute of Technology Ladkrabang, Bangkok (Thailand); Boonloi, Amnart [King Mongkut' s University of Technology North Bangkok, Bangkok (Thailand)

    2015-09-15

    Numerical investigations on flow topology, heat transfer behavior and performance evaluation in a circular tube inserted with various configurations of wavy surfaces, Inclined wavy surface (IWS), V-downstream wavy surface (VDWS), V-Upstream wavy surface (VUWS) are presented. The effects of the flow attack angles; 20 .deg., 30 .deg., 45.deg. and 60.deg. are studied for the Reynolds numbers, Re = 100-2000. The numerical results are compared with the smooth circular tube with no wavy surface and the previous works. It is found that the IWS, VDWS and VUWS can produce longitudinal vortex flow and impinging jet of the fluid flow like inclined baffle, V-downstream baffle and V-Upstream baffle, respectively, but give lower friction loss. The flow phenomena created by the wavy surfaces help to augment the heat transfer rate and thermal performance in the test tube. In the range studied, the order of enhancement for heat transfer rate is around 1.40-3.75, 1.60-6.25 and 1.30-5.80 times higher than the smooth tube for IWS, VDWS and VUWS, respectively. Moreover, the maximum thermal performance, presented in terms of the Thermal enhancement factor (TEF), is found to be about 1.60, 2.40 and 2.10, respectively, for IWS, VUWS and VDWS.

  15. A long-term comparison of carbon sequestration rates in impounded and naturally tidal freshwater marshes along the lower Waccamaw River, South Carolina

    Science.gov (United States)

    Drexler, Judith Z.; Krauss, Ken W.; Sasser, M. Craig; Fuller, Christopher C.; Swarzenski, Christopher M.; Powell, Amber; Swanson, Kathleen M.; Orlando, James L.

    2013-01-01

    Carbon storage was compared between impounded and naturally tidal freshwater marshes along the Lower Waccamaw River in South Carolina, USA. Soil cores were collected in (1) naturally tidal, (2) moist soil (impounded, seasonally drained since ~1970), and (3) deeply flooded “treatments” (impounded, flooded to ~90 cm since ~2002). Cores were analyzed for % organic carbon, % total carbon, bulk density, and 210Pb and 137Cs for dating purposes. Carbon sequestration rates ranged from 25 to 200 g C m−2 yr−1 (moist soil), 80–435 g C m−2 yr−1 (naturally tidal), and 100–250 g C m−2 yr−1 (deeply flooded). The moist soil and naturally tidal treatments were compared over a period of 40 years. The naturally tidal treatment had significantly higher carbon storage (mean = 219 g C m−2 yr−1 vs. mean = 91 g C m−2 yr−1) and four times the vertical accretion rate (mean = 0.84 cm yr−1 vs. mean = 0.21 cm yr−1) of the moist soil treatment. The results strongly suggest that the long drainage period in moist soil management limits carbon storage over time. Managers across the National Wildlife Refuge system have an opportunity to increase carbon storage by minimizing drainage in impoundments as much as practicable.

  16. Water-quality study of Tulpehocken Creek, Berks County, Pennsylvania, prior to impoundment of Blue Marsh Lake

    Science.gov (United States)

    Barker, James L.

    1977-01-01

    Blue Marsh Lake is planned as a multipurpose impoundment to be constructed on Tulpehocken Creek near Bernville, Berks County, Pennsylvania. Prior to construction, samples of water, bed material, and soil were collected throughout the impoundment site to determine concentrations of nutrients, insecticides, trace metals, suspended sediment, and bacteria. Analyses of water suggest the Tulpehocken Creek basin to be a highly fertile environment. Nitrogen and phosphorus concentrations near the proposed dam site had median values of 4.5 and 0.13 mg/L, respectively. Suspended sediment discharges average between 100 and 200 tons (90.7 to 181.4 metric tons) per day during normal flows but may exceed 10,000 tons (9,070 metric tons) per day during storm runoff. Highest yields were measured during winter and early spring. Concentrations range from 3 mg/L to more than 500 mg/L. Bed material samples contain trace quantities of aldrin, DDT, DDD, DDE, dieldrin, and chlordane. Polychlorinated biphyenyls (PCB's) ranged from 10 to 100 μg/kg. Soils at the impoundment site are of average fertility. However, the silt loam texture is ideal for attachment and growth of aquatic plants. Bacteria populations indicative of recent fecal contamination are prevalent in the major inflows to the proposed lake. Fecal Coliform exceeded the standards recommended by the Federal Water Pollution Administration Committee on Water Quality Criteria for public water supply in 29 percent of the monthly samples, and exceeded the recommended public bathing waters standard in 83 percent of the samples collected from June to September. Arsenic from an industrial waste was found in the water, suspended sediment, and bed material of Tulpehocken Creek in concentrations of 0 to 30 μg/l, 2 to 879 μg/l, and 1 to 79 μg/g, respectively. It represents a potential environmental hazard; however, the measured concentrations are less than that known to be harmful to man, fish, or wildlife, according to published water

  17. Coatings and surface treatments for enhanced performance suspensions for future gravitational wave detectors

    Science.gov (United States)

    Birney, R.; Cumming, A. V.; Campsie, P.; Gibson, D.; Hammond, G. D.; Hough, J.; Martin, I. W.; Reid, S.; Rowan, S.; Song, S.; Talbot, C.; Vine, D.; Wallace, G.

    2017-12-01

    Further improvements in the low frequency sensitivity of gravitational wave detectors are important for increasing the observable population of astrophysical sources, such as intermediate mass compact black hole binary systems. Improvements in the lower stage mirror and suspension systems will set challenging targets for the required thermal noise performance of the cantilever blade springs, which provide vertical softness and, thus, isolation to the mirror suspension stack. This is required due to the coupling between the vertical and horizontal axes due to the curvature of the Earth. This can be achieved through use of high mechanical Q materials, which are compatible with cryogenic cooling, such as crystalline silicon. However, such materials are brittle, posing further challenges for assembly/jointing and, more generally, for long-term robustness. Here, we report on experimental studies of the breaking strength of silicon at room temperature, via both tensile and 4-point flexural testing; and on the effects of various surface treatments and coatings on durability and strength. Single- and multi-layer DLC (diamond-like carbon) coatings, together with magnetron-sputtered silica and thermally-grown silica, are investigated, as are the effects of substrate preparation and argon plasma pre-treatment. Application of single- or multi-layer DLC coatings can significantly improve the failure stress of silicon flexures, in addition to improved robustness for handling (assessed through abrasion tests). Improvements of up to 80% in tensile strength, a twofold increase in flexural strength, in addition to a 6.4 times reduction in the vertical thermal noise contribution of the suspension stack at 10 Hz are reported (compared to current Advanced LIGO design). The use of silicon blade springs would also significantly reduce potential ‘crackling noise’ associated with the underlying discrete events associated with plastic deformation in loaded flexures.

  18. Performance of a Surface Barrier for Waste Isolation and Flux Reduction at the Hanford Site

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Z. F.; Wellman, Dawn M.; Morse, John G.; Leary, Kevin D.; Freshley, Mark D.

    2016-05-13

    Based on the knowledge gained from a decade of laboratory, field, and numerical studies, the Prototype Hanford Barrier (PHB) was designed and constructed between late 1993 and late 1994 over the 216-B-57 Crib in the 200-BP-1 Operable Unit at the Hanford Site. The PHB has been monitored since 1994 to evaluate the physical, hydrologic, and ecological performance. Two stress tests were carried out in the past: (1) an enhanced (about 3 times the multi-year average of 160 mm/year) precipitation test from water year (WY) 1995 to WY1997, which included a man-made 1000-year return 24-hour rainstorms in March each year, and (2) a controlled fire test in 2008. The purpose of this article is to present the main findings of the PHB demonstration since 1994. From 1994 to present, the PHB has limited drainage of less than 0.2 mm yr-1, which is below the 0.5 mm yr-1 design goal, and minimized erosion. The observations suggest the PHB is robust enough to endure the hydrological stress of three times average precipitation and 1000-year return 24-hour rainstorms. After the controlled fire, far less vegetation grows and grasses are the dominant vegetation (compared to shrubs on the unburned section). Even so, the grasses can remove nearly all the stored water in the burned section, although during a longer period of time than in the unburned section. The findings at the PHB are useful for the design and monitoring of future surface barriers at Hanford and elsewhere.

  19. Evaluation of ultra-high-performance-fiber reinforced concrete binder content using the response surface method

    International Nuclear Information System (INIS)

    Aldahdooh, M.A.A.; Muhamad Bunnori, N.; Megat Johari, M.A.

    2013-01-01

    Highlights: • We develop a practical method for adjusting the binder content of UHP-FRC. • We adjust the binder content of UHP-FRC mixtures using RSM. • Increasing the cement content does not contribute to enhance strength. • Increasing the content of cement will increase the flow of UHP-FRC mixtures. - Abstract: One of the major disadvantages in ultra-high-performance-fiber reinforced concrete (UHP-FRC) is its high ordinary Portland cement (OPC) content, which directly translates into an increase in OPC production. More OPC production results in increased emission of greenhouse gases, as well increased electrical energy consumption and concrete price. This study is aimed at adjusting the binder content (OPC and silica fume (SF) contents) of UHP-FRC using the response surface method. The present investigation shows that, for a given water/binder and superplasticizer/OPC, the compressive strength is independent of the binder content, whereas the flow depends on the binder content. Increasing the binder content does not enhance the strength compared with the required design strength because the capillary porosity increases with increasing OPC content; however, the workability increases. The final result is the production of a UHP-FRC with an OPC content of 720.49 kg/m 3 , an SF content of 214.25 kg/m 3 , a compressive strength of 181.41 MPa, a direct tensile strength of 12.49 MPa, a bending tensile strength of 30.31 MPa, and a flow of 167 mm

  20. Validity and Reliability of Surface Electromyography Measurements from a Wearable Athlete Performance System

    Directory of Open Access Journals (Sweden)

    Scott K. Lynn, Casey M. Watkins, Megan A. Wong, Katherine Balfany, Daniel F. Feeney

    2018-06-01

    Full Text Available The Athos ® wearable system integrates surface electromyography (sEMG electrodes into the construction of compression athletic apparel. The Athos system reduces the complexity and increases the portability of collecting EMG data and provides processed data to the end user. The objective of the study was to determine the reliability and validity of Athos as compared with a research grade sEMG system. Twelve healthy subjects performed 7 trials on separate days (1 baseline trial and 6 repeated trials. In each trial subjects wore the wearable sEMG system and had a research grade sEMG system’s electrodes placed just distal on the same muscle, as close as possible to the wearable system’s electrodes. The muscles tested were the vastus lateralis (VL, vastus medialis (VM, and biceps femoris (BF. All testing was done on an isokinetic dynamometer. Baseline testing involved performing isometric 1 repetition maximum tests for the knee extensors and flexors and three repetitions of concentric-concentric knee flexion and extension at MVC for each testing speed: 60, 180, and 300 deg/sec. Repeated trials 2-7 each comprised 9 sets where each set included three repetitions of concentric-concentric knee flexion-extension. Each repeated trial (2-7 comprised one set at each speed and percent MVC (50%, 75%, 100% combination. The wearable system and research grade sEMG data were processed using the same methods and aligned in time. The amplitude metrics calculated from the sEMG for each repetition were the peak amplitude, sum of the linear envelope, and 95th percentile. Validity results comprise two main findings. First, there is not a significant effect of system (Athos or research grade system on the repetition amplitude metrics (95%, peak, or sum. Second, the relationship between torque and sEMG is not significantly different between Athos and the research grade system. For reliability testing, the variation across trials and averaged across speeds was 0.8%, 7

  1. A Facile Surface Reconstruction Mechanism toward Better Electrochemical Performance of Li

    NARCIS (Netherlands)

    Qian, Kun; Tang, Linkai; Wagemaker, M.; He, Yan Bing; Liu, Dongqing; Li, Hai; Shi, Ruiying; Li, Baohua; Kang, Feiyu

    2017-01-01

    Through a facile sodium sulfide (Na2S)-assisted hydrothermal treatment, clean and nondefective surfaces are constructed on micrometer-sized Li4Ti5O12 particles. The remarkable improvement of surface quality shows a higher first cycle Coulombic

  2. Plasma surface modification of polypropylene track-etched membrane to improve its performance properties

    Science.gov (United States)

    Kravets, L. I.; Elinson, V. M.; Ibragimov, R. G.; Mitu, B.; Dinescu, G.

    2018-02-01

    The surface and electrochemical properties of polypropylene track-etched membrane treated by plasma of nitrogen, air and oxygen are studied. The effect of the plasma-forming gas composition on the surface morphology is considered. It has been found that the micro-relief of the membrane surface formed under the gas-discharge etching, changes. Moreover, the effect of the non-polymerizing gas plasma leads to formation of oxygen-containing functional groups, mostly carbonyl and carboxyl. It is shown that due to the formation of polar groups on the surface and its higher roughness, the wettability of the plasma-modified membranes improves. In addition, the presence of polar groups on the membrane surface layer modifies its electrochemical properties so that conductivity of plasma-treated membranes increase.

  3. Adding a Performance-Based Component to Surface Warfare Officer Bonuses: Will it Affect Retention?

    National Research Council Canada - National Science Library

    Carman, Aron S; Mudd, Ryan M

    2008-01-01

    ... to Lieutenant Commander (0-4). Probit regressions showed that top performers exhibited higher retention rates than lower-performing peers, though pay had a stronger retention effect among low performers...

  4. Advanced portrayal of SMIL coating by allying CZE performance with in-capillary topographic and charge-related surface characterization

    Energy Technology Data Exchange (ETDEWEB)

    Stock, Lorenz G. [Division of Chemistry and Bioanalytics, University Salzburg, Hellbrunnerstrasse 34, 5020 Salzburg (Austria); Christian Doppler Laboratory for Innovative Tools for the Characterization of Biosimilars, Hellbrunnerstrasse 34, 5020 Salzburg (Austria); Leitner, Michael; Traxler, Lukas [Institute of Biophysics, Johannes Kepler University Linz, Gruberstrasse 40, 4020 Linz (Austria); Bonazza, Klaus [Institute of Chemical Technologies and Analytics, Vienna University of Technology, Getreidemarkt 9/164, 1060 Vienna (Austria); Leclercq, Laurent; Cottet, Hervé [Institut des Biomolécules Max Mousseron (IBMM), UMR 5247, CNRS, Université de Montpellier, Ecole Nationale Supérieure de Chimie de Montpellier, Place Eugène Bataillon, CC 1706, 34095 Montpellier (France); Friedbacher, Gernot [Institute of Chemical Technologies and Analytics, Vienna University of Technology, Getreidemarkt 9/164, 1060 Vienna (Austria); Ebner, Andreas [Institute of Biophysics, Johannes Kepler University Linz, Gruberstrasse 40, 4020 Linz (Austria); Stutz, Hanno, E-mail: hanno.stutz@sbg.ac.at [Division of Chemistry and Bioanalytics, University Salzburg, Hellbrunnerstrasse 34, 5020 Salzburg (Austria); Christian Doppler Laboratory for Innovative Tools for the Characterization of Biosimilars, Hellbrunnerstrasse 34, 5020 Salzburg (Austria)

    2017-01-25

    A successive multiple ionic polymer layer (SMIL) coating composed of four layers improved the capillary electrophoretic separation of a recombinant major birch pollen allergen and closely related variants when poly(acrylamide-co-2-acrylamido-2-methyl-1-propansulfonate) (55% PAMAMPS) replaced dextran sulfate as terminal SMIL layer. 55% PAMAMPS decelerated the electroosmotic flow (EOF) due to its lower charge density. Atomic force microscopy (AFM) was used to investigate SMIL properties directly on the inner capillary surface and to relate them to EOF measurements and results of associated CZE separations of a mixture of model proteins and peptides that were performed in the same capillary. For the first time, AFM-based biosensing topography and recognition imaging mode (TREC) under liquid conditions was applied for a sequential characterization of the inner surface of a SMIL coated capillary after selected treatments including pristine SMIL, SMIL after contact with the model mixture, after alkaline rinsing, and the replenishment of the terminal polyelectrolyte layer. A cantilever with tip-tethered avidin was used to determine the charge homogeneity of the SMIL surface in the TREC mode. SMIL coated rectangular capillaries with 100 μm internal diameter assured accessibility of the inner surface for this cantilever type. Observed changes in CZE performance and EOF mobility during capillary treatment were also reflected by alterations in surface roughness and charge distribution of the SMIL coating. A renewal of the terminal SMIL layer restored the original surface properties of SMIL and the separation performance. The alliance of the novel TREC approach and CZE results allows for an improved understanding and a comprehensive insight in effects occurring on capillary coatings. - Highlights: • SMIL coating with a terminal layer of reduced charge density improves CZE separation. • Capillaries with rectangular diameter allow for in-capillary TREC-AFM measurement.

  5. False negative rate and other performance measures of a sponge-wipe surface sampling method for low contaminant concentrations.

    Energy Technology Data Exchange (ETDEWEB)

    Einfeld, Wayne; Krauter, Paula A.; Boucher, Raymond M.; Tezak, Mathew; Amidan, Brett G. (Pacific Northwest National Laboratory, Richland, WA); Piepel, Greg F. (Pacific Northwest National Laboratory, Richland, WA)

    2011-05-01

    Recovery of spores from environmental surfaces is known to vary due to sampling methodology, techniques, spore size and characteristics, surface materials, and environmental conditions. A series of tests were performed to evaluate a new, validated sponge-wipe method. Specific factors evaluated were the effects of contaminant concentrations and surface materials on recovery efficiency (RE), false negative rate (FNR), limit of detection (LOD) - and the uncertainties of these quantities. Ceramic tile and stainless steel had the highest mean RE values (48.9 and 48.1%, respectively). Faux leather, vinyl tile, and painted wood had mean RE values of 30.3, 25.6, and 25.5, respectively, while plastic had the lowest mean RE (9.8%). Results show a roughly linear dependence of surface roughness on RE, where the smoothest surfaces have the highest mean RE values. REs were not influenced by the low spore concentrations tested (3 x 10{sup -3} to 1.86 CFU/cm{sup 2}). The FNR data were consistent with RE data, showing a trend of smoother surfaces resulting in higher REs and lower FNRs. Stainless steel generally had the lowest mean FNR (0.123) and plastic had the highest mean FNR (0.479). The LOD{sub 90} varied with surface material, from 0.015 CFU/cm{sup 2} on stainless steel up to 0.039 on plastic. Selecting sampling locations on the basis of surface roughness and using roughness to interpret spore recovery data can improve sampling. Further, FNR values, calculated as a function of concentration and surface material, can be used pre-sampling to calculate the numbers of samples for statistical sampling plans with desired performance, and post-sampling to calculate the confidence in characterization and clearance decisions.

  6. Surface modification of seawater desalination reverse osmosis membranes: Characterization studies & performance evaluation

    KAUST Repository

    Matin, Asif

    2014-06-01

    In this work we report surface modification of commercial reverse osmosis membranes by depositing ultrathin copolymer coatings, which could potentially enhance the biofouling resistance of RO membranes. Hydrophilic monomer hydroxyethyl methacrylate (HEMA) and a hydrophobic monomer, perfluorodecyl acrylate (PFDA) were copolymerized directly on the active layer of commercial aromatic polyamide reverse osmosis (RO) membranes using an initiated Chemical Vapor Deposition (iCVD) technique. Attenuated total reflective Fourier transform infrared spectra (ATR-FTIR) verified the successful modification of the membrane surfaces as a new FTIR adsorption band around 1730cm-1 corresponding to carbonyl groups in the copolymer film appeared after the deposition. X-ray Photoelectron spectroscopy (XPS) analysis also confirmed the presence of the copolymer film on the membrane surface by showing strong fluorine peaks emanating from the fluorinated alkyl side chains of the PFA molecules. Contact angle measurements with deionized water showed the modified membrane surfaces to be initially very hydrophobic but quickly assumed a hydrophilic character within few minutes. Atomic Force Microscopy (AFM) revealed that the deposited films were smooth and conformal as the surface topology of the underlying membrane surface remained virtually unchanged after the deposition. FESEM images of the top surface also showed that the typical ridge-and-valley structure associated with polyamide remained intact after the deposition. Short-term permeation tests using DI water and 2000ppm NaCl water showed that the deposited copolymer coatings had negligible effect on permeate water flux and salt rejection. © 2013 Elsevier B.V.

  7. Sealing layer of fly ashes and sewage sludge and vegetation establishment in treatment of mine tailings impoundments; Flygaska och roetslam som taetskikt vid efterbehandling av sandmagasin med vegetationsetablering

    Energy Technology Data Exchange (ETDEWEB)

    Greger, Maria; Neuschuetz, Clara [Stockholm Univ. (Sweden). Dept. of Botany; Isaksson, Karl-Erik [Boliden Mineral AB (Sweden)

    2006-02-15

    Each year the Swedish mining industry produces 25 Mtonnes of mine tailings that are disposed of in extensive natural impoundments. As this sand, containing more or less sulphide-rich minerals, is penetrated by oxygen and water, it starts weathering resulting in formation of acidic and metal-rich drainage water. To prevent oxygen penetration the mine tailings can be covered with a sealing layer covered with a protective cover that facilitates establishment of vegetation. The aim of this study has been to examine the function of fly ash and sewage sludge in sealing layers at impoundments of pyrite rich mine tailings, and the ability of different plant species, which are suitable for establishment in these areas, to penetrate the sealing layer with their roots and what impact they have on the drainage water. Experiments have been performed in field and greenhouse environment, with sealing layers consisting of fly ash and sewage sludge mixtures, covered with protective covers of sewage sludge or till. Plant establishment has been studied in a survey of naturally established plants at sewage sludge disposal sites close to mining areas, and by sowing and planting of selected plants, for instance fast growing grass species and fibre hemp at the test plots in field and in greenhouse experiments. Large scale application of ashes, sewage sludge and an ash/sludge mixture have been performed in field at three test plots with the size of 0.3-1 ha. Leakage of nutrients and metals from sealing layers has been studied in field and greenhouse tests. In addition, the ability of plant roots to penetrate sealing layers made of different ash/sludge mixtures have been examined in greenhouse experiments. This investigation is a cooperation between Stockholm University and Boliden Mineral AB, and the field experiments have been performed at the mine tailings impoundments at Gillervattnet, Boliden. Other collaborating participants are Skellefteaa Kraft and Munksund, who have produced the

  8. Zwitterionic sulfobetaine-grafted poly(vinylidene fluoride) membrane surface with stably anti-protein-fouling performance via a two-step surface polymerization

    International Nuclear Information System (INIS)

    Li Qian; Bi Qiuyan; Zhou Bo; Wang Xiaolin

    2012-01-01

    A zwitterionic polymer, poly(3-(methacryloylamino) propyl-dimethyl-(3-sulfopropyl) ammonium hydroxide) (poly(MPDSAH)) was successfully grafted in high density from the surface of poly(vinylidene fluoride) (PVDF) hollow fiber membrane via a two-step polymerization. Poly(2-hydroxyethyl methacrylate) (poly(HEMA)) chains were firstly grafted from outside surface of PVDF membrane through atom transfer radical polymerization (ATRP) to provide the initiation sites for subsequent cerium (Ce (IV))-induced graft copolymerization of polyMPDSAH in the presence of N,N′-ethylene bisacrylamide (EBAA) as a cross-linking agent. Attenuated total reflectance-Fourier transform infrared (ATR-FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS) confirmed that the EBAA could stimulate zwitterionic polymers grafting onto the membrane surface. The dense poly(MPDSAH) layers on the PVDF membrane surface were revealed by the scanning electron microscope (SEM). The mechanical property of PVDF membrane was improved by the zwitterionic surface layers. The gravimetry results indicated the grafting amount increased to 520 μg/cm 2 for a copolymerization time of more than 3 h. Static and dynamic water contact angle measurements showed that the surface hydrophilicity of the PVDF membranes was significantly enhanced. As the grafting amount reached 513 μg cm -2 , the value of contact angle dropped to 22.1° and the amount of protein adsorption decreased to zero. The cyclic experiments for BSA solution filtration demonstrated that the extent of protein fouling was significantly reduced and most of the fouling was reversible. The grafted polymer layer on the PVDF membrane showed a good stability during the membrane cleaning process. The experimental results concluded a good prospect in obtaining the sulfobetaine-modified PVDF membranes with high mechanical strength, good anti-protein-fouling performance, and long-term stability via the two-step polymerization.

  9. Zwitterionic sulfobetaine-grafted poly(vinylidene fluoride) membrane surface with stably anti-protein-fouling performance via a two-step surface polymerization

    Energy Technology Data Exchange (ETDEWEB)

    Li Qian; Bi Qiuyan; Zhou Bo [Membrane Technology and Engineering Research Center, Department of Chemical Engineering, Tsinghua University, Beijing 100084 (China); Wang Xiaolin, E-mail: xl-wang@tsinghua.edu.cn [Membrane Technology and Engineering Research Center, Department of Chemical Engineering, Tsinghua University, Beijing 100084 (China)

    2012-03-01

    A zwitterionic polymer, poly(3-(methacryloylamino) propyl-dimethyl-(3-sulfopropyl) ammonium hydroxide) (poly(MPDSAH)) was successfully grafted in high density from the surface of poly(vinylidene fluoride) (PVDF) hollow fiber membrane via a two-step polymerization. Poly(2-hydroxyethyl methacrylate) (poly(HEMA)) chains were firstly grafted from outside surface of PVDF membrane through atom transfer radical polymerization (ATRP) to provide the initiation sites for subsequent cerium (Ce (IV))-induced graft copolymerization of polyMPDSAH in the presence of N,N Prime -ethylene bisacrylamide (EBAA) as a cross-linking agent. Attenuated total reflectance-Fourier transform infrared (ATR-FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS) confirmed that the EBAA could stimulate zwitterionic polymers grafting onto the membrane surface. The dense poly(MPDSAH) layers on the PVDF membrane surface were revealed by the scanning electron microscope (SEM). The mechanical property of PVDF membrane was improved by the zwitterionic surface layers. The gravimetry results indicated the grafting amount increased to 520 {mu}g/cm{sup 2} for a copolymerization time of more than 3 h. Static and dynamic water contact angle measurements showed that the surface hydrophilicity of the PVDF membranes was significantly enhanced. As the grafting amount reached 513 {mu}g cm{sup -2}, the value of contact angle dropped to 22.1 Degree-Sign and the amount of protein adsorption decreased to zero. The cyclic experiments for BSA solution filtration demonstrated that the extent of protein fouling was significantly reduced and most of the fouling was reversible. The grafted polymer layer on the PVDF membrane showed a good stability during the membrane cleaning process. The experimental results concluded a good prospect in obtaining the sulfobetaine-modified PVDF membranes with high mechanical strength, good anti-protein-fouling performance, and long-term stability via the two-step polymerization.

  10. Uptake of uranium, thorium and radium isotopes by plants growing in dam impoundment Tasotkel and the Lower Shu region (Kazakhstan)

    Energy Technology Data Exchange (ETDEWEB)

    Matveyeva, Ilona; Burkitbayev, Mukhambetkali [al-Farabi Kazakh National University, Almaty (Kazakhstan). Faculty of Chemistry and Chemical Technology; Jacimovic, Radojko [Jozef Stefan Institute, Ljubljana (Slovenia). Dept. of Environmental Sciences; Planinsek, Petra; Smodis, Borut [Jozef Stefan Institute, Ljubljana (Slovenia). Dept. of Environmental Sciences; Jozef Stefan International Postgraduate School, Ljubljana (Slovenia)

    2016-04-01

    The activity concentrations of isotopes of uranium, thorium and radium-226 in dominant species of plants (Xantium strumarium, Phragmites communis, Artemisia nitrosa and Artemisia serotina) growing on the territories contaminated by uranium industry of Kazakhstan (close to dam impoundment Tasotkel and the Lower Shu region) are presented. The obtained data showed the significant variations of activity concentrations of isotopes of uranium, thorium and radium-226 in above ground parts. The concentrations of most of the investigated radionuclides in the root system are higher than in the aboveground parts; it can be explained by root barrier. It was found that the highest root barrier has Xantium strumarium, especially for uranium isotopes. The concentration ratios of radionuclides were calculated, and as the result it was found that the highest accumulation ability in the investigated region has Artemisia serotina.

  11. Uptake of uranium, thorium and radium isotopes by plants growing in dam impoundment Tasotkel and the Lower Shu region (Kazakhstan)

    International Nuclear Information System (INIS)

    Matveyeva, Ilona; Burkitbayev, Mukhambetkali

    2016-01-01

    The activity concentrations of isotopes of uranium, thorium and radium-226 in dominant species of plants (Xantium strumarium, Phragmites communis, Artemisia nitrosa and Artemisia serotina) growing on the territories contaminated by uranium industry of Kazakhstan (close to dam impoundment Tasotkel and the Lower Shu region) are presented. The obtained data showed the significant variations of activity concentrations of isotopes of uranium, thorium and radium-226 in above ground parts. The concentrations of most of the investigated radionuclides in the root system are higher than in the aboveground parts; it can be explained by root barrier. It was found that the highest root barrier has Xantium strumarium, especially for uranium isotopes. The concentration ratios of radionuclides were calculated, and as the result it was found that the highest accumulation ability in the investigated region has Artemisia serotina.

  12. Effects of bulk and surface conductivity on the performance of CdZnTe pixel detectors

    DEFF Research Database (Denmark)

    Bolotnikov, A.E.; Chen, C.M.H.; Cook, W.R.

    2002-01-01

    , the existence of a thin (10-100 A) oxide layer on the surface of CZT, formed during the fabrication process, affects both bulk and surface leakage currents. We demonstrate that the measured I-V dependencies of bulk current can be explained by considering the CZT detector as a metal-semiconductor-metal system......-collection efficiency in detectors with multicontact geometry; some fraction of the electric field lines that originated on the cathode intersects the surface areas between the pixel contacts where the charge produced by an ionizing particle gets trapped. To overcome this effect, we place a grid of thin electrodes...

  13. Reservoir Operation Rules for Controlling Algal Blooms in a Tributary to the Impoundment of Three Gorges Dam

    Directory of Open Access Journals (Sweden)

    Jijian Lian

    2014-10-01

    Full Text Available Since the first impoundment of Three Gorges Dam in 2003, algal blooms occur frequently in the near-dam tributaries. It is widely recognized that the impoundment-induced change in hydrodynamic condition with the lower current velocity will make the eutrophication problem even more severe when an excessive amount of nutrients is already loaded into a reservoir and/or its tributaries. Operation tests carried out by Three Gorges Corporation in 2010 point to some feasible reservoir operation schemes that may have positive impacts on reducing the algal bloom level. In our study, an attempt is made to obtain, through a numerical hydrodynamic and water quality modeling and analysis, the reservoir operation rules that would reduce the level of algal blooms in the Xiangxi River (XXR, a near-dam tributary. Water movements and algal blooms in XXR are simulated and analyzed under different scenarios of one-day water discharge fluctuation or two-week water level variation. The model results demonstrate that the reservoir operations can further increase the water exchange between the mainstream of the Three Gorges Reservoir (TGR and the XXR tributary and thus move a larger amount of algae into the deep water where it will die. Analysis of the model results indicate that the water discharge fluctuation constituted of a lower valley-load flow and a larger flow difference for the short-term operation (within a day, the rise in water level for the medium-term operation (e.g., over weeks, and the combination of the above two for the long-term operation (e.g., over months can be the feasible reservoir operation rules in the non-flood season for TGR.

  14. Evaluation of workers' perceived sense of slip and effect of prior knowledge of slipperiness during task performance on slippery surfaces.

    Science.gov (United States)

    Chiou, S; Bhattacharya, A; Succop, P A

    2000-01-01

    Forty healthy industrial workers (age: 41.0+/-14.9 years) were tested for postural stability for three simulated tasks: (1) standing upright; (2) rapid trunk movement; and (3) lateral reach during lifting. These tasks were performed on four levels of slippery surfaces under different environmental lighting with new or workers' own old shoes. Prior to postural stability tests, each subject was given the opportunity to assess the surface slipperiness that he or she would encounter in the subsequent postural stability tests. A perceived sense of slip (PSOS) scale was administrated immediately after each test to determine subjects' PSOS. Subjects' postural sway and instability during task performance was determined by using a strain gauge type force platform. Results from this study indicate that subjects who were cautious in assessing surface slipperiness had less postural instability during task performance. Subjects could perceive the likely slips due to the change in task (p=0.0001) and surface slipperiness (p=0.0001). The PSOS scale is reproducible, easy to use, and provides a simple way to evaluate potential slip hazards in the workplace. Results from this study should aid understanding of the factors critical to maintaining postural stability on slippery surfaces, and will help to develop guidelines for safety training and identify slip hazards in the workplace.

  15. Evaluating the performance of free-formed surface parts using an analytic network process

    Science.gov (United States)

    Qian, Xueming; Ma, Yanqiao; Liang, Dezhi

    2018-03-01

    To successfully design parts with a free-formed surface, the critical issue of how to evaluate and select a favourable evaluation strategy before design is raised. The evaluation of free-formed surface parts is a multiple criteria decision-making (MCDM) problem that requires the consideration of a large number of interdependent factors. The analytic network process (ANP) is a relatively new MCDM method that can systematically deal with all kinds of dependences. In this paper, the factors, which come from the life-cycle and influence the design of free-formed surface parts, are proposed. After analysing the interdependence among these factors, a Hybrid ANP (HANP) structure for evaluating the part’s curved surface is constructed. Then, a HANP evaluation of an impeller is presented to illustrate the application of the proposed method.

  16. Surface patterning of polymeric separation membranes and its influence on the filtration performance

    Science.gov (United States)

    Maruf, Sajjad

    Polymeric membrane based separation technologies are crucial for addressing the global issues such as water purification. However, continuous operations of these processes are often hindered by fouling which increases mass transport resistance of the membrane to permeation and thus the energy cost, and eventually replacement of the membrane in the system. In comparison to other anti-fouling strategies, the use of controlled surface topography to mitigate fouling has not been realized mainly due to the lack of methods to create targeted topography on the porous membrane surface. This thesis aims to develop a new methodology to create surface-patterned polymeric separation membrane to improve their anti-fouling characteristics during filtration. First, successful fabrication of sub-micron surface patterns directly on a commercial ultrafiltration (UF) membrane surface using nanoimprint lithographic (NIL) technique was demonstrated. Comprehensive filtration studies revealed that the presence of these sub-micron surface patterns mitigates not only the onset of colloidal particle deposition, but also lowers the rate of growth of cake layer after initial deposition, in comparison with un-patterned membranes. The anti-fouling effects were also observed for model protein solutions. Staged filtration experiments, with backwash cleaning, revealed that the permeate flux of the patterned membrane after protein fouling was considerably higher than that of the pristine or un-patterned membrane. In addition to the surface-patterning of UF membranes, successful fabrication of a surface-patterned thin film composite (TFC) membrane was shown for the first time. A two-step fabrication process was carried out by (1) nanoimprinting a polyethersulfone (PES) support using NIL, and (2) forming a thin dense film atop the PES support via interfacial polymerization (IP). Fouling experiments suggest that the surface patterns alter the hydrodynamics at the membrane-feed interface, which is

  17. Effect of surface roughness on performance of magnetoelastic biosensors for the detection of Escherichia coli

    Energy Technology Data Exchange (ETDEWEB)

    Possan, A.L. [Centro de Ciências Exatas e Tecnologia, Universidade de Caxias do Sul, Caxias do Sul, RS (Brazil); Menti, C. [Instituto de Biotecnologia, Universidade de Caxias do Sul, Caxias do Sul, RS (Brazil); Beltrami, M. [Centro de Ciências Exatas e Tecnologia, Universidade de Caxias do Sul, Caxias do Sul, RS (Brazil); Santos, A.D. [Instituto de Física, Universidade de São Paulo, São Paulo, SP (Brazil); Roesch-Ely, M. [Instituto de Biotecnologia, Universidade de Caxias do Sul, Caxias do Sul, RS (Brazil); Missell, F.P., E-mail: fmissell@yahoo.com [Centro de Ciências Exatas e Tecnologia, Universidade de Caxias do Sul, Caxias do Sul, RS (Brazil)

    2016-01-01

    Escherichia coli are bacteria that must be controlled in the food industry and the hospital sector. Magnetoelastic biosensors offer the promise of rapid identification of these and other harmful antigens. In this work, strips of amorphous Metglas 2826MB3 were cut to size (5 mm × 1 mm) with a microdicing saw and were then coated with thin layers of Cr and Au, as verified by Rutherford backscattering spectroscopy (RBS). Several sensor surfaces were studied: 1) as-cast strip, wheel side; 2) as-cast strip, free surface; and 3) thinned and polished surface. A layer of cystamine was applied to the Au-covered magnetoelastic substrate, forming a self-assembled monolayer (SAM), followed by antibodies, using a modified Hermanson protocol. The cystamine layer growth was verified by Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). The biosensors were exposed to solutions of bacteria and the resonant frequency of the sensors was measured with an impedance analyzer for times up to 100 min. Reductions in the resonant frequency, corresponding to bacteria capture, were measured after optimizing the signal amplitude. For times up to 40 min, high capture rates were observed and thereafter saturation occurred. Saturation values of the frequency shifts were compared with the number of bacteria observed on the sensor using fluorescence microscopy. Parameters associated with capture kinetics were studied for different sensor surfaces. The rough surfaces were found to show a faster response, while the thinned and polished sensors showed the largest frequency shift. - Highlights: • Magnetoelastic biosensors to capture Escherichia coli were produced. • Surface roughness of biosensors was varied in the range R{sub a} = 0.3–0.52 μm. • Rough surfaces show faster response, polished surfaces have larger frequency shift.

  18. Effect of surface roughness on performance of magnetoelastic biosensors for the detection of Escherichia coli

    International Nuclear Information System (INIS)

    Possan, A.L.; Menti, C.; Beltrami, M.; Santos, A.D.; Roesch-Ely, M.; Missell, F.P.

    2016-01-01

    Escherichia coli are bacteria that must be controlled in the food industry and the hospital sector. Magnetoelastic biosensors offer the promise of rapid identification of these and other harmful antigens. In this work, strips of amorphous Metglas 2826MB3 were cut to size (5 mm × 1 mm) with a microdicing saw and were then coated with thin layers of Cr and Au, as verified by Rutherford backscattering spectroscopy (RBS). Several sensor surfaces were studied: 1) as-cast strip, wheel side; 2) as-cast strip, free surface; and 3) thinned and polished surface. A layer of cystamine was applied to the Au-covered magnetoelastic substrate, forming a self-assembled monolayer (SAM), followed by antibodies, using a modified Hermanson protocol. The cystamine layer growth was verified by Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). The biosensors were exposed to solutions of bacteria and the resonant frequency of the sensors was measured with an impedance analyzer for times up to 100 min. Reductions in the resonant frequency, corresponding to bacteria capture, were measured after optimizing the signal amplitude. For times up to 40 min, high capture rates were observed and thereafter saturation occurred. Saturation values of the frequency shifts were compared with the number of bacteria observed on the sensor using fluorescence microscopy. Parameters associated with capture kinetics were studied for different sensor surfaces. The rough surfaces were found to show a faster response, while the thinned and polished sensors showed the largest frequency shift. - Highlights: • Magnetoelastic biosensors to capture Escherichia coli were produced. • Surface roughness of biosensors was varied in the range R a = 0.3–0.52 μm. • Rough surfaces show faster response, polished surfaces have larger frequency shift.

  19. Influence of the convective surface transfer coefficients on the Heat, Air, and Moisture (HAM) building performance

    DEFF Research Database (Denmark)

    Steskens, Paul Wilhelmus Maria Hermanus; Janssen, Hans; Rode, Carsten

    2009-01-01

    Current models to predict heat, air and moisture (HAM) conditions in buildings assume constant boundary conditions for the temperature and relative humidity of the neighbouring air and for the surface heat and moisture transfer coefficients. These assumptions may introduce errors in the predicted...... influence on the predicted hygrothermal conditions at the surface of a building component and on the heat and vapour exchange with the indoor environment....

  20. Influence of surface morphology and microstructure on performance of CVD tungsten coating under fusion transient thermal loads

    Energy Technology Data Exchange (ETDEWEB)

    Lian, Youyun, E-mail: lianyy@swip.ac.cn [Southwestern Institute of Physics, Chengdu (China); Liu, Xiang; Wang, Jianbao; Feng, Fan [Southwestern Institute of Physics, Chengdu (China); Lv, Yanwei; Song, Jiupeng [China National R& D Center for Tungsten Technology, Xiamen Tungsten Co. Ltd, 361026 Xiamen (China); Chen, Jiming [Southwestern Institute of Physics, Chengdu (China)

    2016-12-30

    Highlights: • Thick CVD-W coatingswere deposited at a rapid growth rate. • The polished CVD-W coatings have highly textured structure and exhibited a very strong preferred orientation. • The polished CVD tungsten coatings show superior thermal shock resistance as compared with that of the as-deposited coatings. • The crack formation of the polished CVD-W was almost suppressed at an elevated temperature. - Abstract: Thick tungsten coatings have been deposited by chemical vapor deposition (CVD) at a rapid growth rate. A series of tungsten coatings with different thickness and surface morphology were prepared. The surface morphology, microstructure and preferred orientation of the CVD tungsten coatings were investigated. Thermal shock analyses were performed by using an electron beam facility to study the influence of the surface morphology and the microstructure on the thermal shock resistance of the CVD tungsten coatings. Repetitive (100 pulses) ELMs-like thermal shock loads were applied at various temperatures between room temperature and 600 °C with pulse duration of 1 ms and an absorbed power density of up to 1 GW/m{sup 2}. The results of the tests demonstrated that the specific surface morphology and columnar crystal structure of the CVD tungsten have significant influence on the surface cracking threshold and crack propagation of the materials. The CVD tungsten coatings with a polished surface show superior thermal shock resistance as compared with that of the as-deposited coatings with a rough surface.

  1. Effect of Surface Treatment on Performance of Electrode Material Based on Carbon Fiber Cloth

    Directory of Open Access Journals (Sweden)

    XU Jian

    2018-01-01

    Full Text Available The carbon fiber cloth was treated by surface treatment, and then it was used as the electrode substrate. The electrode material based on carbon fibers was synthesized by a galvanostatic electrodeposition method. The interface resistivity, electrochemical property and corrosion resistance of the CF/β-PbO2 electrode were characterized by four-probe method and electrochemical workstation, respectively. The results show that the surface roughness and chemical activity of the carbon fibers can be significantly improved through surface treatment. The carbon fibers possess the best chemical activity on the surface at the hot-air oxidation temperature of 400℃. Joint hot-air and liquid-phase oxidations show that the chemical activity of the carbon fibers on the surface is further improved, the grooves and pits on the surface of the carbon fibers are more obvious, after this treatment, the interface resistivity of the CF/β-PbO2 electrode reaches the minimum value of 6.19×10-5Ω·m, meanwhile, the conductivity and the electrochemical property of the CF/β-PbO2 electrode reaches the best, and with the best corrosion resistance, the corrosion rate is only 1.44×10-3g·cm-2·h-1.Thus, the interface resistivity, electrochemical property and corrosion resistance of the CF/β-PbO2 electrode depend on the the interface structure of the CF/β-PbO2 electrode obtained under different surface treatments.

  2. Construction and performance test of apparatus for permeation experiments with controlled surfaces

    International Nuclear Information System (INIS)

    Hatano, Yuji; Nomura, Mamoru; Watanabe, Kuniaki; Livshits, Alexander I.; Busnyuk, Andrei O.; Nakamura, Yukio; Ohyabu, Nobuyoshi

    2003-01-01

    A new apparatus was constructed to examine gas-, atom- and plasma-driven permeation of hydrogen isotopes through group VA metal membranes with precisely controlled surface states. Absorption and desorption experiments are also possible. The new apparatus consists of two vacuum chambers, an upstream chamber and a downstream chamber, separated by a specimen membrane. Both chambers are evacuated by turbo-molecular pumps and sputter-ion pumps. The upstream chamber is equipped with Ta filaments serving as atomizers in atom-driven permeation experiments and cathodes in plasma-driven permeation experiments. The specimen membrane is formed into a tubular shape and electrically isolated from the chamber. Hence, ohmic heating of the membrane is possible, and this feature of the membrane is suitable for surface cleaning by high-temperature heating an impurity doping for the control of surface chemical composition through surface segregation. Both chambers were evacuated to 1 x 10 -7 Pa after baking. The main component of residual gas was H 2 , and the partial pressures of impurity gases other than H 2 were ca. 1 x 10 -8 Pa. Gas- and atom-driven permeation experiments were successfully carried out with hydrogen gas for Nb membrane activated by heating in vacuum at 1173 K. Superpermeation was observed in the atom-driven permeation experiments. Absorption experiments with a clean surface were also carried out. The surface was, however, cleaned only partially, because the temperature distribution was not uniform during high-temperature heating. Nevertheless, surface cleanliness was retained during absorption experiments under the present vacuum conditions. A new membrane assembly that will enable a uniform temperature distribution is now under construction. (author)

  3. Impoundment effects in the population of Auchenipterus osteomystax (Siluriformes: Auchenipteridae: a Neotropical reservoir case

    Directory of Open Access Journals (Sweden)

    Elcio Barili

    2012-06-01

    Full Text Available New impoundments provide opportunities to check whether species that present enough feeding flexibility in natural conditions may take advantage of this situation and, without reproductive restriction, can occupy the most conspicuous habitat in a large reservoir (open areas and present higher success in the colonization of the new environment. We examined variations in the abundance and feeding of A. osteomystax in two environments, one natural (Sinha Mariana floodplain lake and one dammed (Manso Reservoir, during two periods: the first year after the filling phase and three years later. Our goal was to evaluate the occupation of the new hábitat (Manso Reservoir, by this species, as well as to test the hypothesis that in the reservoir, unlike the natural environment, there are remarkable changes in diet between the periods. Fish were sampled monthly in the floodplain lake and in the reservoir during two annual periods using gillnets. To evaluate the differences in abundance of A. osteomystax we employed the Kruskal -Wallis test, and the diet analysis was carried out using frequency of occurrence and volumetric methods. Temporal differences in the diet were tested by Kruskal-Wallis test using the scores from a detrended correspondence analysis. A. osteomystax was significantly more abundant in the floodplain lake, where the captures were higher than in the reservoir in almost all months analyzed, and significant variations in abundance between the two periods were not recorded in either the reservoir or the floodplain lake. The diet variation between the two periods, which had a time lag of three years between them, was much less pronounced in the natural environment, where the resource availability is essentially regulated by seasonality. Thus, our hypothesis was accepted; that is, the interannual variations in the diet of A. osteomystax are more relevant in an artificial environment than in a natural one. Rev. Biol. Trop. 60 (2: 699-708. Epub

  4. Chemical Reactive Anchoring Lipids with Different Performance for Cell Surface Re-engineering Application.

    Science.gov (United States)

    Vabbilisetty, Pratima; Boron, Mallorie; Nie, Huan; Ozhegov, Evgeny; Sun, Xue-Long

    2018-02-28

    Introduction of selectively chemical reactive groups at the cell surface enables site-specific cell surface labeling and modification opportunity, thus facilitating the capability to study the cell surface molecular structure and function and the molecular mechanism it underlies. Further, it offers the opportunity to change or improve a cell's functionality for interest of choice. In this study, two chemical reactive anchor lipids, phosphatidylethanolamine-poly(ethylene glycol)-dibenzocyclooctyne (DSPE-PEG 2000 -DBCO) and cholesterol-PEG-dibenzocyclooctyne (CHOL-PEG 2000 -DBCO) were synthesized and their potential application for cell surface re-engineering via lipid fusion were assessed with RAW 264.7 cells as a model cell. Briefly, RAW 264.7 cells were incubated with anchor lipids under various concentrations and at different incubation times. The successful incorporation of the chemical reactive anchor lipids was confirmed by biotinylation via copper-free click chemistry, followed by streptavidin-fluorescein isothiocyanate binding. In comparison, the cholesterol-based anchor lipid afforded a higher cell membrane incorporation efficiency with less internalization than the phospholipid-based anchor lipid. Low cytotoxicity of both anchor lipids upon incorporation into the RAW 264.7 cells was observed. Further, the cell membrane residence time of the cholesterol-based anchor lipid was evaluated with confocal microscopy. This study suggests the potential cell surface re-engineering applications of the chemical reactive anchor lipids.

  5. Global Performance of a Fast Parameterization Scheme for Estimating Surface Solar Radiation from MODIS data

    Science.gov (United States)

    Tang, W.; Yang, K.; Sun, Z.; Qin, J.; Niu, X.

    2016-12-01

    A fast parameterization scheme named SUNFLUX is used in this study to estimate instantaneous surface solar radiation (SSR) based on products from the Moderate Resolution Imaging Spectroradiometer (MODIS) sensor onboard both Terra and Aqua platforms. The scheme mainly takes into account the absorption and scattering processes due to clouds, aerosols and gas in the atmosphere. The estimated instantaneous SSR is evaluated against surface observations obtained from seven stations of the Surface Radiation Budget Network (SURFRAD), four stations in the North China Plain (NCP) and 40 stations of the Baseline Surface Radiation Network (BSRN). The statistical results for evaluation against these three datasets show that the relative root-mean-square error (RMSE) values of SUNFLUX are less than 15%, 16% and 17%, respectively. Daily SSR is derived through temporal upscaling from the MODIS-based instantaneous SSR estimates, and is validated against surface observations. The relative RMSE values for daily SSR estimates are about 16% at the seven SURFRAD stations, four NCP stations, 40 BSRN stations and 90 China Meteorological Administration (CMA) radiation stations.

  6. Surface modification of Polycaprolactone (PCL) microcarrier for performance improvement of human skin fibroblast cell culture

    Science.gov (United States)

    Samsudin, N.; Hashim, Y. Z. H.; Arifin, M. A.; Mel, M.; Salleh, H. Mohd; Sopyan, I.; Hamid, M. Abdul

    2018-01-01

    Polycaprolactone (PCL) has many advantages for use in biomedical engineering field. In the present work PCL microcarriers of 150-200 μm were fabricated using oil-in-water (o/w) emulsification coupled with solvent evaporation method. The surface charge of PCL microcarrier was then been improved by using ultraviolet/ozone treatment to introduce oxygen functional group. Immobilisation of gelatin onto PCL microspheres using zero-length crosslinker provides a stable protein-support complex, with no diffusional barrier which is ideal for mass processing. The optimum concentration of carboxyl group (COOH) absorbed on the surface was 1495.9 nmol/g and the amount of gelatin immobilized was 1797.3 μg/g on UV/O3 treated microcarriers as compared to the untreated (320 μg/g) microcarriers. The absorption of functional oxygen groups on the surface and the immobilized gelatin was confirmed with Fourier Transformed Infrared spectroscopy and the enhancement of hydrophilicity of the surface was confirmed using water contact angle measurement which decreased (86.93° - 49.34°) after UV/O3 treatment and subsequently after immobilisation of gelatin. The attachment and growth kinetics for human skin fibroblast cell (HSFC) showed that adhesion occurred much more rapidly for gelatin immobilised surface as compared to untreated PCL and UV/O3 PCL microcarrier.

  7. Chemical Reactive Anchoring Lipids with Different Performance for Cell Surface Re-engineering Application

    Science.gov (United States)

    2018-01-01

    Introduction of selectively chemical reactive groups at the cell surface enables site-specific cell surface labeling and modification opportunity, thus facilitating the capability to study the cell surface molecular structure and function and the molecular mechanism it underlies. Further, it offers the opportunity to change or improve a cell’s functionality for interest of choice. In this study, two chemical reactive anchor lipids, phosphatidylethanolamine–poly(ethylene glycol)–dibenzocyclooctyne (DSPE–PEG2000–DBCO) and cholesterol–PEG–dibenzocyclooctyne (CHOL–PEG2000–DBCO) were synthesized and their potential application for cell surface re-engineering via lipid fusion were assessed with RAW 264.7 cells as a model cell. Briefly, RAW 264.7 cells were incubated with anchor lipids under various concentrations and at different incubation times. The successful incorporation of the chemical reactive anchor lipids was confirmed by biotinylation via copper-free click chemistry, followed by streptavidin-fluorescein isothiocyanate binding. In comparison, the cholesterol-based anchor lipid afforded a higher cell membrane incorporation efficiency with less internalization than the phospholipid-based anchor lipid. Low cytotoxicity of both anchor lipids upon incorporation into the RAW 264.7 cells was observed. Further, the cell membrane residence time of the cholesterol-based anchor lipid was evaluated with confocal microscopy. This study suggests the potential cell surface re-engineering applications of the chemical reactive anchor lipids. PMID:29503972

  8. Performance assessment and licensing issues for United States commercial near-surface low-level radioactive waste disposal facilities

    International Nuclear Information System (INIS)

    Birk, S.M.

    1997-10-01

    The final objective of performance assessment for a near-surface LLW disposal facility is to demonstrate that potential radiological impacts for each of the human exposure pathways will not violate applicable standards. This involves determining potential pathways and specific receptor locations for human exposure to radionuclides; developing appropriate scenarios for each of the institutional phases of a disposal facility; and maintaining quality assurance and control of all data, computer codes, and documentation. The results of a performance assessment should be used to demonstrate that the expected impacts are expected to be less than the applicable standards. The results should not be used to try to predict the actual impact. This is an important distinction that results from the uncertainties inherent in performance assessment calculations. The paper discusses performance objectives; performance assessment phases; scenario selection; mathematical modeling and computer programs; final results of performance assessments submitted for license application; institutional control period; licensing issues; and related research and development activities

  9. Surface characteristics modeling and performance evaluation of urban building materials using LiDAR data.

    Science.gov (United States)

    Li, Xiaolu; Liang, Yu

    2015-05-20

    Analysis of light detection and ranging (LiDAR) intensity data to extract surface features is of great interest in remote sensing research. One potential application of LiDAR intensity data is target classification. A new bidirectional reflectance distribution function (BRDF) model is derived for target characterization of rough and smooth surfaces. Based on the geometry of our coaxial full-waveform LiDAR system, the integration method is improved through coordinate transformation to establish the relationship between the BRDF model and intensity data of LiDAR. A series of experiments using typical urban building materials are implemented to validate the proposed BRDF model and integration method. The fitting results show that three parameters extracted from the proposed BRDF model can distinguish the urban building materials from perspectives of roughness, specular reflectance, and diffuse reflectance. A comprehensive analysis of these parameters will help characterize surface features in a physically rigorous manner.

  10. Thermal-hydraulic performance of the finned surface of a compact heat exchanger

    International Nuclear Information System (INIS)

    Errasti Cabrera, Michel

    2015-01-01

    In this work the thermal-hydraulic behavior of the finned surface of a compact heat exchanger is obtained in tube-fin configuration corrugated (wavy). Through numerical simulation are determined average values ​​of intensification of heat transfer and pressure loss in the inter-channel finned. The objective is to characterize the surface to use as a reference, to make comparisons with other heat exchange surfaces enhanced using traditional techniques combined with more current, such as vortex generators. The study is conducted in laminar flow, with Reynolds numbers below 1000. In the working model compact exchanger tubes and corrugated fins (wavy) heat is described, and the results of the coefficient of overall heat transfer and the pressure drop are explained from the local characteristics of the velocity field and temperature inside the heat exchanger. (Full text)

  11. An experimental result of surface roughness machining performance in deep hole drilling

    Directory of Open Access Journals (Sweden)

    Mohamad Azizah

    2016-01-01

    Full Text Available This study presents an experimental result of a deep hole drilling process for Steel material at different machining parameters which are feed rate (f, spindle speed (s, the depth of the hole (d and MQL, number of drops (m on surface roughness, Ra. The experiment was designed using two level full factorial design of experiment (DoE with centre points to collect surface roughness, Ra values. The signal to noise (S/N ratio analysis was used to discover the optimum level for each machining parameters in the experiment.

  12. Performance Assessment of Low-Noise Road Surfaces in the Leopoldo Project: Comparison and Validation of Different Measurement Methods

    Directory of Open Access Journals (Sweden)

    Gaetano Licitra

    2015-01-01

    Full Text Available In almost all urban contexts and in many extra-urban conurbations, where road traffic is the main noise pollution source, the use of barriers is not allowed. In these cases, low-noise road surfaces are the most used mitigation action together with traffic flow reduction. Selecting the optimal surface is only the first problem that the public administration has to face. In the second place, it has to consider the issue of assessing the efficacy of the mitigation action. The purpose of the LEOPOLDO project was to improve the knowledge in the design and the characterization of low-noise road surfaces, producing guidelines helpful to the public administrations. Several experimental road surfaces were tested. Moreover, several measurement methods were implemented aiming to select those that are suitable for a correct assessment of the pavement performances laid as mitigation planning. In this paper, the experience gained in the LEOPOLDO project will be described, focusing on both the measurement methods adopted to assess the performance of a low-noise road surface and the criteria by which the experimental results have to be evaluated, presenting a comparison of the obtained results and their monitoring along time.

  13. Experimental study of surface pattern effects on the propulsive performance and wake of a bio-inspired pitching panel

    Science.gov (United States)

    King, Justin; Kumar, Rajeev; Green, Melissa

    2016-11-01

    Force measurements and stereoscopic particle image velocimetry (PIV) were used to characterize the propulsive performance and wake structure of rigid, bio-inspired trapezoidal pitching panels. In the literature, it has been demonstrated that quantities such as thrust coefficient and propulsive efficiency are affected by changes in the surface characteristics of a pitching panel or foil. More specifically, the variation of surface pattern produces significant changes in wake structure and dynamics, especially in the distribution of vorticity in the wake. Force measurements and PIV data were collected for multiple surface patterns chosen to mimic fish surface morphology over a Strouhal number range of 0.17 to 0.56. Performance quantities are compared with the three-dimensional vortex wake structure for both the patterned and smooth panels to determine the nature and magnitude of surface pattern effects in terms of thrust produced, drag reduced, and wake vortices reshaped and reorganized. This work was supported by the Office of Naval Research under ONR Award No. N00014-14-1-0418.

  14. Effects of piston surface treatments on performance and emissions of a methanol-fueled, direct injection, stratified charge engine

    Energy Technology Data Exchange (ETDEWEB)

    West, B.; Green, J.B. [Oak Ridge National Lab., TN (United States)

    1994-07-01

    The purpose of this study was to investigate the effects of thermal barrier coatings and/or surface treatments on the performance and emissions of a methanol-fueled, direct-injection, stratified-charge (DISC) engine. A Ricardo Hydra Mark III engine was used for this work and in previous experiments at Oak Ridge National Laboratory (ORNL). The primary focus of the study was to examine the effects of various piston insert surface treatments on hydrocarbon (HC) and oxides of nitrogen (NO{sub x}) emissions. Previous studies have shown that engines of this class have a tendency to perform poorly at low loads and have high unburned fuel emissions. A blank aluminum piston was modified to employ removable piston bowl inserts. Four different inserts were tested in the experiment: aluminum, stainless steel with a 1.27-mm (0.050-in.) air gap (to act as a thermal barrier), and two stainless steel/air-gap inserts with coatings. Two stainless steel inserts were dimensionally modified to account for the coating thickness (1.27-mm) and coated identically with partially stabilized zirconia (PSZ). One of the coated inserts then had an additional seal-coat applied. The coated inserts were otherwise identical to the stainless steel/air-gap insert (i.e., they employed the same 1.27-mm air gap). Thermal barrier coatings were employed in an attempt to increase combustion chamber surface temperatures, thereby reducing wall quenching and promoting more complete combustion of the fuel in the quench zone. The seal-coat was applied to the zirconia to reduce the surface porosity; previous research suggested that despite the possibly higher surface temperatures obtainable with a ceramic coating, the high surface area of a plasma-sprayed coating may actually allow fuel to adhere to the surface and increase the unburned fuel emissions and fuel consumption.

  15. Experimental study of the effect of the reduced graphene oxide films on nucleate boiling performances of inclined surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Ji Hoon; Kong, Byeong Tak [Incheon National University, Incheon (Korea, Republic of); Kim, Ji Min [POSTECH, Pohang (Korea, Republic of); and others

    2016-05-15

    For the enhancing the CHF, surface coating techniques are available. Yang et al. performed small scale boiling experiments for the vessel lower head, which was coated by aluminum/copper micro particles. Recently, graphene has received much attention for applications in thermal engineering due to its large thermal conductivity. Ahn et al. used a silicon dioxide substrate, which was coated graphene films, as a heating surface during pool boiling experiments. The graphene films inhibited the formation of hot spots, increasing the CHF. For applying novel material 'Graphene' in nuclear industry, here we investigated the effects of graphene film coatings on boiling performances. The experimental pool boiling facility, copying the geometry of lower head of reactor, was designed for verifying orientation effects. The effects of graphene films coating on varied inclined heater surfaces were investigated. The CHF values were increased at every case, but the increased amounts were decreased for downward heater surfaces. At the downward-facing region, however, coating the RGO films would change the CHF mechanisms and boiling heat transfer performances. Generally, RGO films, made by colloidal fabrication, has defects on each flakes.

  16. Experimental study of the effect of the reduced graphene oxide films on nucleate boiling performances of inclined surfaces

    International Nuclear Information System (INIS)

    Kim, Ji Hoon; Kong, Byeong Tak; Kim, Ji Min

    2016-01-01

    For the enhancing the CHF, surface coating techniques are available. Yang et al. performed small scale boiling experiments for the vessel lower head, which was coated by aluminum/copper micro particles. Recently, graphene has received much attention for applications in thermal engineering due to its large thermal conductivity. Ahn et al. used a silicon dioxide substrate, which was coated graphene films, as a heating surface during pool boiling experiments. The graphene films inhibited the formation of hot spots, increasing the CHF. For applying novel material 'Graphene' in nuclear industry, here we investigated the effects of graphene film coatings on boiling performances. The experimental pool boiling facility, copying the geometry of lower head of reactor, was designed for verifying orientation effects. The effects of graphene films coating on varied inclined heater surfaces were investigated. The CHF values were increased at every case, but the increased amounts were decreased for downward heater surfaces. At the downward-facing region, however, coating the RGO films would change the CHF mechanisms and boiling heat transfer performances. Generally, RGO films, made by colloidal fabrication, has defects on each flakes.

  17. Performance of fire behavior fuel models developed for the Rothermel Surface Fire Spread Model

    Science.gov (United States)

    Robert Ziel; W. Matt Jolly

    2009-01-01

    In 2005, 40 new fire behavior fuel models were published for use with the Rothermel Surface Fire Spread Model. These new models are intended to augment the original 13 developed in 1972 and 1976. As a compiled set of quantitative fuel descriptions that serve as input to the Rothermel model, the selected fire behavior fuel model has always been critical to the resulting...

  18. Effect of surface transport properties on the performance of carbon plastic electrodes for flow battery applications

    International Nuclear Information System (INIS)

    Sun, Xihe; Souier, Tewfik; Chiesa, Matteo; Vassallo, Anthony

    2014-01-01

    Due to their high electrical conductivity and corrosion resistance, carbon nanotube (MWNT)-high density polyethylene (HDPE) composites are potential candidates to replace traditional activated carbon electrodes for the next generation of fuel-cells, super capacitors and flow batteries. Electrochemical impedance spectroscopy (EIS) is employed to separate the surface conduction from bulk conduction in 15% HDPE-MWNT and 19% carbon black (CB)-HDPE composites for zinc-bromine flow battery electrodes. While exhibiting superior bulk conductivity, the interfacial conductivity of MWNT-filled composites is lower than that of CB-filled composites. High resolution conductive atomic force microscopy (C-AFM) imaging and current-voltage (I-V) spectroscopy were employed to investigate the sub-surface electronic transport of the composite. Unlike the CB-composite, the fraction of conducting MWNTs near the surface is very low compared to their volume fraction. In addition, the non-linear I-V curves reveal the presence of a tunneling junction between the tip and the polymer-coated MWNTs. The tunneling resistance is as high as 1 GΩ, which strongly affects the electronic/electrochemical transfer at the interface of the electrolyte and the surface of the composite, which is evident in the voltammetric and EIS observations

  19. Engineering of poly(ethylene glycol) chain-tethered surfaces to obtain high-performance bionanoparticles

    International Nuclear Information System (INIS)

    Nagasaki, Yukio

    2010-01-01

    A poly(ethylene glycol)-b-poly[2-(N,N-dimethylamino)ethyl methacrylate] block copolymer possessing a reactive acetal group at the end of the poly(ethylene glycol) (PEG) chain, that is, acetal-PEG-b-PAMA, was synthesized by a proprietary polymerization technique. Gold nanoparticles (GNPs) were prepared using the thus-synthesized acetal-PEG-b-PAMA block copolymer. The PEG-b-PAMA not only acted as a reducing agent of aurate ions but also attached to the nanoparticle surface. The GNPs obtained had controlled sizes and narrow size distributions. They also showed high dispersion stability owing to the presence of PEG tethering chains on the surface. The same strategy should also be applicable to the fabrication of semiconductor quantum dots and inorganic porous nanoparticles. The preparation of nanoparticles in situ, i.e. in the presence of acetal-PEG-b-PAMA, gave the most densely packed polymer layer on the nanoparticle surface; this was not observed when coating preformed nanoparticles. PEG/polyamine block copolymer was more functional on the metal surface than PEG/polyamine graft copolymer, as confirmed by angle-dependent x-ray photoelectron spectroscopy. We successfully solubilized the C 60 fullerene into aqueous media using acetal-PEG-b-PAMA. A C 60 /acetal-PEG-b-PAMA complex with a size below 5 nm was obtained by dialysis. The preparation and characterization of these materials are described in this review. (topical review)

  20. Metacognitive and Motivational Predictors of Surface Approach to Studying and Academic Examination Performance

    Science.gov (United States)

    Spada, Marcantonio M.; Moneta, Giovanni B.

    2014-01-01

    The objective of this study was to verify the structure of a model of how surface approach to studying is influenced by the trait variables of motivation and metacognition and the state variables of avoidance coping and evaluation anxiety. We extended the model to include: (1) the investigation of the relative contribution of the five…

  1. A high performance GPU implementation of Surface Energy Balance System (SEBS) based on CUDA-C

    NARCIS (Netherlands)

    Abouali, Mohammad; Timmermans, J.; Castillo, Jose E.; Su, Zhongbo

    2013-01-01

    This paper introduces a new implementation of the Surface Energy Balance System (SEBS) algorithm harnessing the many cores available on Graphics Processing Units (GPUs). This new implementation uses Compute Unified Device Architecture C (CUDA-C) programming model and is designed to be executed on a

  2. Estimations of Atmospheric Conditions for Input to the Radar Performance Surface

    Science.gov (United States)

    2007-12-01

    distribution is unlimited 12b. DISTRIBUTION CODE 13. ABSTRACT (maximum 200 words) This study addresses the support of non- acoustic ASW operations by...BLANK v ABSTRACT This study addresses the support of non- acoustic ASW operations by timely atmospheric and ocean surface descriptions on features...24 Figure 12. Infrared Radiation Pyrometers , model KT15.82, Wintronics 2007

  3. Polydiagnostic calibration performed on a low pressure surface wave sustained argon plasma

    NARCIS (Netherlands)

    Vries, de N.; Palomares, J.M.; Iordanova, E.I.; Veldhuizen, van E.M.; Mullen, van der J.J.A.M.

    2008-01-01

    The electron density and electron temperature of a low pressure surface wave sustained argon plasma have been determined using passive and active (laser) spectroscopic methods simultaneously. In this way the validity of the various techniques is established while the plasma properties are determined

  4. Surface-modified polymeric pads for enhanced performance during chemical mechanical planarization

    International Nuclear Information System (INIS)

    Deshpande, S.; Dakshinamurthy, S.; Kuiry, S.C.; Vaidyanathan, R.; Obeng, Y.S.; Seal, S.

    2005-01-01

    The chemical mechanical planarization (CMP) process occurs at an atomic level at the slurry/wafer interface and hence slurries and polishing pads play a critical role in their successful implementation. Polyurethane is a commonly used polymer in the manufacturing of CMP pads. These pads are incompatible with some chemicals present in the CMP slurries, such as hydrogen peroxide. To overcome these problems, Psiloquest has developed new Application Specific Pads (ASP). Surface of such pads has been modified by depositing a thin film of tetraethyl orthosilicate using plasma-enhanced chemical vapor deposition (PECVD) process. In the present study, mechanical properties of such coated pads have been investigated using nanoindentation. The surface morphology and the chemistry of the ASP were studied using scanning electron microcopy, X-ray photoelectron spectroscopy, and Fourier transform infrared spectroscopy techniques. It was observed that mechanical and chemical properties of the pad top surface are a function of the PECVD coating time. Such PECVD-treated pads are found to be hydrophilic and do not require storage in aqueous media during the not-in-use period. The metal removal rate using such surface-modified polishing pads was found to increase linearly with the PECVD coating time

  5. Enhanced performance of solar cells with optimized surface recombination and efficient photon capturing via anisotropic-etching of black silicon

    International Nuclear Information System (INIS)

    Chen, H. Y.; Peng, Y.; Hong, M.; Zhang, Y. B.; Cai, Bin; Zhu, Y. M.; Yuan, G. D.; Zhang, Y.; Liu, Z. Q.; Wang, J. X.; Li, J. M.

    2014-01-01

    We report an enhanced conversion efficiency of femtosecond-laser treated silicon solar cells by surface modification of anisotropic-etching. The etching improves minority carrier lifetime inside modified black silicon area substantially; moreover, after the etching, an inverted pyramids/upright pyramids mixed texture surface is obtained, which shows better photon capturing capability than that of conventional pyramid texture. Combing of these two merits, the reformed solar cells show higher conversion efficiency than that of conventional pyramid textured cells. This work presents a way for fabricating high performance silicon solar cells, which can be easily applied to mass-production

  6. Biomechanical differences of arm swing countermovement jumps on sand and rigid surface performed by elite beach volleyball players.

    Science.gov (United States)

    Giatsis, George; Panoutsakopoulos, Vassilios; Kollias, Iraklis A

    2018-05-01

    The purpose of this study was to investigate the possible arm swing effect on the biomechanical parameters of vertical counter movement jump due to differences of the compliance of the take-off surface. Fifteen elite male beach-volleyball players (26.2 ± 5.9 years; 1.87 ± 0.05 m; 83.4 ± 6.0 kg; mean ± standard deviation, respectively) performed counter movement jumps on sand and on a rigid surface with and without an arm swing. Results showed significant (p volleyball.

  7. Surface damage mitigation of TC4 alloy via micro arc oxidation for oil and gas exploitation application: Characterizations of microstructure and evaluations on surface performance

    Science.gov (United States)

    Xie, Ruizhen; Lin, Naiming; Zhou, Peng; Zou, Jiaojuan; Han, Pengju; Wang, Zhihua; Tang, Bin

    2018-04-01

    Because of its excellent corrosion resistance, high specific strength and high tensile strength, TC4 titanium alloys used as petroleum tubes have received wide interest from material engineers after many technical investigations and estimations. However, because of its low surface hardness values, high coefficient of friction and poor wear resistance, the TC4 alloy is seldom adopted in tribological-related engineering components. In this work, micro-arc oxidation (MAO) coatings were fabricated on TC4 alloys in NaAlO2 and (NaPO3)6 electrolytes with and without ultrasonic assistance. The microstructural characterizations of the produced MAO coatings were investigated. Comparative estimations of electrochemical corrosion in CO2-saturated simulated oilfield brine and tribological behaviours on MAO coatings and TC4 alloys were conducted. The results showed that the introduction of ultrasound increased the thickness of the MAO coatings. The thickness increased by 34% and 15% in the NaAlO2 and (NaPO3)6 electrolytes, respectively. There was no significant discrepancy in phase constitutions when the MAO processes were conducted with and without ultrasonic assistance. Both MAO coatings obtained with and without ultrasonic assistance were found to improve the corrosion and wear resistance of the TC4 alloy. MAO treatments made it possible to ensure the working surface of a TC4 alloy with an enhanced surface performance for oil and gas exploitation applications.

  8. In vitro performance of DIAGNOdent laser fluorescence device for dental calculus detection on human tooth root surfaces.

    Science.gov (United States)

    Rams, Thomas E; Alwaqyan, Abdulaziz Y

    2017-10-01

    This study assessed the reproducibility of a red diode laser device, and its capability to detect dental calculus in vitro on human tooth root surfaces. On each of 50 extracted teeth, a calculus-positive and calculus-free root surface was evaluated by two independent examiners with a low-power indium gallium arsenide phosphide diode laser (DIAGNOdent) fitted with a periodontal probe-like sapphire tip and emitting visible red light at 655 nm wavelength. Laser autofluorescence intensity readings of examined root surfaces were scored on a 0-99 scale, with duplicate assessments performed using the laser probe tip directed both perpendicular and parallel to evaluated tooth root surfaces. Pearson correlation coefficients of untransformed measurements, and kappa analysis of data dichotomized with a >40 autofluorescence intensity threshold, were calculated to assess intra- and inter-examiner reproducibility of the laser device. Mean autofluorescence intensity scores of calculus-positive and calculus-free root surfaces were evaluated with the Student's t -test. Excellent intra- and inter-examiner reproducibility was found for DIAGNOdent laser autofluorescence intensity measurements, with Pearson correlation coefficients above 94%, and kappa values ranging between 0.96 and 1.0, for duplicate readings taken with both laser probe tip orientations. Significantly higher autofluorescence intensity values were measured when the laser probe tip was directed perpendicular, rather than parallel, to tooth root surfaces. However, calculus-positive roots, particularly with calculus in markedly-raised ledges, yielded significantly greater mean DIAGNOdent laser autofluorescence intensity scores than calculus-free surfaces, regardless of probe tip orientation. DIAGNOdent autofluorescence intensity values >40 exhibited a stronger association with calculus (36.6 odds ratio) then measurements of ≥5 (20.1 odds ratio) when the laser probe tip was advanced parallel to root surfaces. Excellent

  9. Improved performance of dye-sensitized solar cells with surface-treated TiO2 as a photoelectrode

    International Nuclear Information System (INIS)

    Park, Su Kyung; Chung, Chinkap; Kim, Dae-Hwan; Kim, Cham; Lee, Sang-Ju; Han, Yoon Soo

    2012-01-01

    We report on the effects of surface-modified TiO 2 on the performance of dye-sensitized solar cells (DSSCs). TiO 2 surface was modified with Na 2 CO 3 via a simple dip coating process and the modified TiO 2 was applied to photoelectrodes of DSSCs. By dipping of TiO 2 layer into aqueous Na 2 CO 3 solution, the DSSC showed a power conversion efficiency of 9.98%, compared to that (7.75%) of the reference device without surface treatment. The UV–vis absorption spectra, the impedance spectra and the dark current studies revealed that the increase of all parameters was attributed to the enhanced dye adsorption, the prolonged electron lifetime and the reduced interfacial resistance.

  10. Flotation performances and surface properties of chalcopyrite with xanthate collector added before and after grinding

    Science.gov (United States)

    Peng, Huiqing; Wu, Di; Abdelmonem, Mohamed

    In this study, effects of the collector added before grinding and after grinding on the subsequent flotation and mineral surface properties were investigated. The pH was controlled at 10 during the grinding and flotation processes opened to the atmosphere. With enough amounts of sodium butyl xanthate addition, adding the collector before grinding recovered more chalcopyrite than adding it after grinding in single mineral flotation. The Eh of each ground pulp before and after conditioning were measured and it was found that adding collector before grinding obtained higher and relatively suitable pulp potential for chalcopyrite flotation. Particle size analyses of the flotation products indicate that the different flotation recoveries occurred due to the different flotation losses in fine particles (flotation feedings and found that more carbon and oxygen, and less iron were remained on mineral surfaces when the collector was added before grinding, due to the higher collector adsorption capacity, larger free oxygen adsorbance and less iron oxide/hydroxide species.

  11. Influence of surface effects on the performance of lead-niobium-germanate optical waveguides

    International Nuclear Information System (INIS)

    Munoz-Martin, D.; Gonzalo, J.; Fernandez-Navarro, J.M.; Siegel, J.; Afonso, C.N.

    2007-01-01

    Lead-niobium-germanate planar waveguides have been produced by pulsed laser deposition. The composition of the waveguides is found to be relatively weakly dependent on the laser fluence, while their surface morphology is affected dramatically. Smooth surfaces are obtained for a narrow fluence range centered at 2.0 J/cm 2 , while particulates having typical diameters of 2 , which is close to the value of the bulk glass, and remains constant at higher fluences. Propagation losses show instead a minimum (∼6.5 dB/cm) at 2.0 J/cm 2 . The characteristics of the ablation process that leads to the ejection of solid particulates or molten droplets as well as the increase of the waveguides density on increasing the fluence are discussed to be responsible for the observed optical behavior

  12. Performance of multi-junction cells due to illumination distribution across the cell surface

    International Nuclear Information System (INIS)

    Schultz, R.D.; Vorster, F.J; Dyk, E.E van

    2012-01-01

    This paper addresses the influence of illumination distribution on the performance of a high concentration photovoltaic (HCPV) module. CPV systems comprise of optical elements as well as mechanical tracking to concentrate the solar flux onto the solar receiver as well as to keep the system on track with the sun. The performance of the subcells of the multi-junction concentrator cell depends on the optical alignment of the system. Raster scanning of the incident intensity in the optical plane of the receiver and corresponding I–V measurements were used to investigate the influence of illumination distribution on performance. The results show that the illumination distribution that differs between cells does affect the performance of the module. The performance of the subcells of the multi-junction concentrator cell also depends on the optical alignment of the system.

  13. Performance of multi-junction cells due to illumination distribution across the cell surface

    Energy Technology Data Exchange (ETDEWEB)

    Schultz, R.D., E-mail: s206029578@live.nmmu.ac.za [Nelson Mandela University, Physics Department, P.O. Box 77000, 6031, Port Elizabeth (South Africa); Vorster, F.J; Dyk, E.E van [Nelson Mandela University, Physics Department, P.O. Box 77000, 6031, Port Elizabeth (South Africa)

    2012-05-15

    This paper addresses the influence of illumination distribution on the performance of a high concentration photovoltaic (HCPV) module. CPV systems comprise of optical elements as well as mechanical tracking to concentrate the solar flux onto the solar receiver as well as to keep the system on track with the sun. The performance of the subcells of the multi-junction concentrator cell depends on the optical alignment of the system. Raster scanning of the incident intensity in the optical plane of the receiver and corresponding I-V measurements were used to investigate the influence of illumination distribution on performance. The results show that the illumination distribution that differs between cells does affect the performance of the module. The performance of the subcells of the multi-junction concentrator cell also depends on the optical alignment of the system.

  14. Spectral and parameter estimation problems arising in the metrology of high performance mirror surfaces

    International Nuclear Information System (INIS)

    Church, E.L.; Takacs, P.Z.

    1986-04-01

    The accurate characterization of mirror surfaces requires the estimation of two-dimensional distribution functions and power spectra from trend-contaminated profile measurements. The rationale behind this, and our measurement and processing procedures, are described. The distinction between profile and area spectra is indicated, and since measurements often suggest inverse-power-law forms, a discussion of classical and fractal models of processes leading to these forms is included. 9 refs

  15. BIOPHYSICAL PROPERTIES OF NUCLEIC ACIDS AT SURFACES RELEVANT TO MICROARRAY PERFORMANCE

    OpenAIRE

    Rao, Archana N.; Grainger, David W.

    2014-01-01

    Both clinical and analytical metrics produced by microarray-based assay technology have recognized problems in reproducibility, reliability and analytical sensitivity. These issues are often attributed to poor understanding and control of nucleic acid behaviors and properties at solid-liquid interfaces. Nucleic acid hybridization, central to DNA and RNA microarray formats, depends on the properties and behaviors of single strand (ss) nucleic acids (e.g., probe oligomeric DNA) bound to surface...

  16. Performance Improvement of Polymer Solar Cells by Surface-Energy-Induced Dual Plasmon Resonance.

    Science.gov (United States)

    Yao, Mengnan; Shen, Ping; Liu, Yan; Chen, Boyuan; Guo, Wenbin; Ruan, Shengping; Shen, Liang

    2016-03-09

    The surface plasmon resonance (SPR) effect of metal nanoparticles (MNPs) is effectively applied on polymer solar cells (PSCs) to improve power conversion efficiency (PCE). However, universality of the reported results mainly focused on utilizing single type of MNPs to enhance light absorption only in specific narrow wavelength range. Herein, a surface-energy-induced dual MNP plasmon resonance by thermally evaporating method was presented to achieve the absorption enhancement in wider range. The differences of surface energy between silver (Ag), gold (Au), and tungsten trioxide (WO3) compared by contact angle images enable Ag and Au prefer to respectively aggregate into isolated islands rather than films at the initial stage of the evaporation process, which was clearly demonstrated in the atomic force microscopy (AFM) measurement. The sum of plasmon-enhanced wavelength range induced by both Ag NPs (350-450 nm) and Au NPs (450-600 nm) almost cover the whole absorption spectra of active layers, which compatibly contribute a significant efficiency improvement from 4.57 ± 0.16 to 6.55 ± 0.12% compared to the one without MNPs. Besides, steady state photoluminescence (PL) measurements provide strong evidence that the SPR induced by the Ag-Au NPs increase the intensity of light absorption. Finally, ultraviolet photoelectron spectroscopy (UPS) reveals that doping Au and Ag causes upper shift of both the work function and valence band of WO3, which is directly related to hole collection ability. We believe the surface-energy-induced dual plasmon resonance enhancement by simple thermally evaporating technique might pave the way toward higher-efficiency PSCs.

  17. The Role of Surface Protection for High-Temperature Performance of TiAl Alloys

    Science.gov (United States)

    Schütze, Michael

    2017-12-01

    In the temperature range where TiAl alloys are currently being used in jet engine and automotive industries, surface reaction with the operating environment is not yet a critical issue. Surface treatment may, however, be needed in order to provide improved abrasion resistance. Development routes currently aim at a further increase in operation temperatures in gas turbines up to 800°C and higher, and in automotive applications for turbocharger rotors, even up to 1050°C. In this case, oxidation rates may reach levels where significant metal consumption of the load-bearing cross-section can occur. Another possibly even more critical issue can be high-temperature-induced oxygen and nitrogen up-take into the metal subsurface zone with subsequent massive ambient temperature embrittlement. Solutions for these problems are based on a deliberate phase change of the metal subsurface zone by diffusion treatments and by using effects such as the halogen effect to change the oxidation mechanism at high temperatures. Other topics of relevance for the use of TiAl alloys in high-temperature applications can be high-temperature abrasion resistance, thermal barrier coatings on TiAl and surface quality in additive manufacturing, in all these cases-focusing on the role of the operation environment. This paper addresses the recent developments in these areas and the requirements for future work.

  18. Surface Modification by Friction Stir Processing of Low-Carbon Steel: Microstructure Investigation and Wear Performance

    Science.gov (United States)

    Sattari, Behnoosh; Shamanian, Morteza; Salimijazi, Farshid; Salehi, Mehdi

    2018-02-01

    A low-carbon steel sheet with a thickness of 5 mm was subjected to friction stir processing (FSP) by one to four different passes. The microstructures of different regions were characterized using the optical microscopy and electron backscatter diffraction. The Vickers micro-harness was measured at the distance of 200 μm below the processed surfaces. The influence of pass numbers (PNs) on wear resistance was studied in terms of coefficients of friction (CoFs), weight losses and wear rates. SEM topographies of the worn surfaces were also studied to evaluate the wear mechanisms. Microstructure observations showed that Widmänstatten ferrite plates were formed in stir zones (SZs) and heat affected zones. As PN increased, these grains were widened due to the increment of the carbon diffusivity and lengthened because of the high heat input and microstructure anisotropy. Besides, increasing the PN causes increasing of the hardness and wear resistance, simultaneously. Specifically, the wear rate in the SZ was reduced from 2.8 × 10-2 mm3 m-1 in base metal to 0.3 × 10-2 mm3 m-1 in sample which was subjected to 4 FSP passes. However, variation in PN had no considerable effect on CoFs. Oxidative wear mechanism was observed on the worn surface of the steel and the FSPed samples while more debris was formed by increasing the PNs.

  19. Surface-directed molecular assembly of pentacene on monolayer graphene for high-performance organic transistors.

    Science.gov (United States)

    Lee, Wi Hyoung; Park, Jaesung; Sim, Sung Hyun; Lim, Soojin; Kim, Kwang S; Hong, Byung Hee; Cho, Kilwon

    2011-03-30

    Organic electronic devices that use graphene electrodes have received considerable attention because graphene is regarded as an ideal candidate electrode material. Transfer and lithographic processes during fabrication of patterned graphene electrodes typically leave polymer residues on the graphene surfaces. However, the impact of these residues on the organic semiconductor growth mechanism on graphene surface has not been reported yet. Here, we demonstrate that polymer residues remaining on graphene surfaces induce a stand-up orientation of pentacene, thereby controlling pentacene growth such that the molecular assembly is optimal for charge transport. Thus, pentacene field-effect transistors (FETs) using source/drain monolayer graphene electrodes with polymer residues show a high field-effect mobility of 1.2 cm(2)/V s. In contrast, epitaxial growth of pentacene having molecular assembly of lying-down structure is facilitated by π-π interaction between pentacene and the clean graphene electrode without polymer residues, which adversely affects lateral charge transport at the interface between electrode and channel. Our studies provide that the obtained high field-effect mobility in pentacene FETs using monolayer graphene electrodes arises from the extrinsic effects of polymer residues as well as the intrinsic characteristics of the highly conductive, ultrathin two-dimensional monolayer graphene electrodes.

  20. Ventilation Inception and Washout, Scaling, and Effects on Hydrodynamic Performance of a Surface Piercing Strut

    Science.gov (United States)

    Harwood, Casey; Young, Yin Lu; Ceccio, Steven

    2014-11-01

    High-lift devices that operate at or near a fluid free surface (such as surface-piercing or shallowly-submerged propellers and hydrofoils) are prone to a multiphase flow phenomenon called ventilation, wherein non-condensable gas is entrained in the low-pressure flow, forming a cavity around the body and dramatically altering the global hydrodynamic forces. Experiments are being conducted at the University of Michigan's towing tank using a canonical surface-piercing strut to investigate atmospheric ventilation. The goals of the work are (i) to gain an understanding of the dominant physics in fully wetted, partially ventilated, and fully ventilated flow regimes, (ii) to quantify the effects of governing dimensionless parameters on the transition between flow regimes, and (iii) to develop scaling relations for the transition between flow regimes. Using theoretical arguments and flow visualization techniques, new criteria are developed for classifying flow regimes and transition mechanisms. Unsteady transition mechanisms are described and mapped as functions of the governing non-dimensional parameters. A theoretical scaling relationship is developed for ventilation washout, which is shown to adequately capture the experimentally-observed washout boundary. This material is based upon work supported by the National Science Foundation Graduate Student Research Fellowship under Grant No. DGE 1256260. Support also comes from the Naval Engineering Education Center (Award No. N65540-10-C-003).

  1. Wind-Tunnel Investigation of the Aerodynamic Performance of Surface-Modification Cables

    Directory of Open Access Journals (Sweden)

    Hiroshi Katsuchi

    2017-12-01

    Full Text Available The wind-induced vibration of stay cables of cable-stayed bridges, which includes rain-wind-induced vibration (RWIV and dry galloping (DG, has been studied for a considerable amount of time. In general, mechanical dampers or surface modification are applied to suppress the vibration. In particular, several types of surface-modification cable, including indentation, longitudinally parallel protuberance, helical fillet, and U-shaped grooving, have been developed. Recently, a new type of aerodynamically stable cable with spiral protuberances was developed. It was confirmed that the cable has a low drag force coefficient, like an indented cable, and that it prevented the formation of water rivulets on the cable surface. In this study, the stability for RWIV of this cable was investigated with various flow angles and protuberance dimensions in a wind-tunnel test. It was found that the spiral protuberance cable is aerodynamically stable against both RWIV and DG for all test wind angles. The effects of the protuberance dimensions were also clarified. Keywords: Rain-wind-induced vibration, Dry galloping, Stay cable, Wind-tunnel test

  2. Evaluation of the performance of three diffuse hourly irradiation models on tilted surfaces according to the utilizability concept

    International Nuclear Information System (INIS)

    Posadillo, R.; Lopez Luque, R.

    2009-01-01

    The performance of three diffuse hourly irradiation models on tilted surfaces was evaluated by making a database of hourly global and diffuse solar irradiation on a horizontal surface, as well as global solar irradiation on a tilted surface, recorded in a solar radiation station located at Cordoba University (Spain). The method for a comparison of the performance of these models was developed from a study of the 'utilizable energy' statistics, a value representing, for a specific period of time, the mean monthly radiation that exceeded a critical level of radiation. This model comparison method seemed to us to be highly suitable since it provides a way of comparing the capacity of these models to estimate, however, much energy is incident on a tilted surface above a critical radiation level. Estimated and measured values were compared using the normalized RMBE and RRMSE statistics. According to the results of the method let us verify that, of the three models evaluated, one isotropic and two anisotropic, the Reindl et al. anisotropic model was the one giving the best results.

  3. Electroless Ni–B Coating of Pure Titanium Surface for Enhanced Tribocorrosion Performance in Artificial Saliva and Antibacterial Activity

    Directory of Open Access Journals (Sweden)

    F. Mindivan

    2017-05-01

    Full Text Available In the present study, the surface of commercial pure (Grade 2 titanium was coated with electroless Ni–B. The surface morphology, microstructure and phase identification were analysed by X-Ray Diffraction (XRD and Field Emission Gun Scanning Electron Microscope (FEG-SEM equipped with Energy Dispersive X-ray Spectroscopy (EDS. The tribocorrosion performance in a laboratory simulated artificial saliva was investigated using a reciprocating ball-on-plate tribometer coupled to an electrochemical cell. The antibacterial property of the electroless Ni–B film coated on pure titanium was basically investigated. From this study, it may be concluded that this electroless Ni–B coating process cannot only improve the hardness and tribocorrosion performance of the pure titanium, but can also provide antimicrobial activity.

  4. Improved battery performance using Pd nanoparticles synthesized on the surface of LiFePO4/C by ultrasound irradiation

    Science.gov (United States)

    Saliman, Muhammad Ali; Okawa, Hirokazu; Takai, Misaki; Ono, Yuki; Kato, Takahiro; Sugawara, Katsuyasu; Sato, Mineo

    2016-07-01

    LiFePO4 has been attracting interest as a cathode material for Li-ion batteries due to its high energy density, low cost, and eco-friendliness. The electrochemical performance of LiFePO4 is limited because it exhibits low Li-ion diffusivity and low electronic conductivity. Numerous solutions have been considered, such as carbon coating, which is widely known to improve the electronic conductivity of LiFePO4. The deposition of metal nanoparticles (NPs) on the surface of carbon-coated LiFePO4 further enhances the electronic conductivity. In this study, we deposited Pd NPs onto the surface of LiFePO4/C and investigated the resulting electrochemical performance. Sonochemical synthesis was used to prepare the metal NPs; the procedure did not require any surfactants and the reaction was rapid.

  5. Is Handwriting Performance Affected by the Writing Surface? Comparing Preschoolers', Second Graders', and Adults' Writing Performance on a Tablet vs. Paper.

    Science.gov (United States)

    Gerth, Sabrina; Klassert, Annegret; Dolk, Thomas; Fliesser, Michael; Fischer, Martin H; Nottbusch, Guido; Festman, Julia

    2016-01-01

    Due to their multifunctionality, tablets offer tremendous advantages for research on handwriting dynamics or for interactive use of learning apps in schools. Further, the widespread use of tablet computers has had a great impact on handwriting in the current generation. But, is it advisable to teach how to write and to assess handwriting in pre- and primary schoolchildren on tablets rather than on paper? Since handwriting is not automatized before the age of 10 years, children's handwriting movements require graphomotor and visual feedback as well as permanent control of movement execution during handwriting. Modifications in writing conditions, for instance the smoother writing surface of a tablet, might influence handwriting performance in general and in particular those of non-automatized beginning writers. In order to investigate how handwriting performance is affected by a difference in friction of the writing surface, we recruited three groups with varying levels of handwriting automaticity: 25 preschoolers, 27 second graders, and 25 adults. We administered three tasks measuring graphomotor abilities, visuomotor abilities, and handwriting performance (only second graders and adults). We evaluated two aspects of handwriting performance: the handwriting quality with a visual score and the handwriting dynamics using online handwriting measures [e.g., writing duration, writing velocity, strokes and number of inversions in velocity (NIV)]. In particular, NIVs which describe the number of velocity peaks during handwriting are directly related to the level of handwriting automaticity. In general, we found differences between writing on paper compared to the tablet. These differences were partly task-dependent. The comparison between tablet and paper revealed a faster writing velocity for all groups and all tasks on the tablet which indicates that all participants-even the experienced writers-were influenced by the lower friction of the tablet surface. Our results

  6. Is handwriting performance affected by the writing surface? Comparing preschoolers’, second graders’ and adults’ writing performance on a tablet versus paper

    Directory of Open Access Journals (Sweden)

    Sabrina Gerth

    2016-09-01

    Full Text Available Due to their multifunctionality, tablets offer tremendous advantages for research on handwriting dynamics or for interactive use of learning apps in schools. Further, the widespread use of tablet computers has had a great impact on handwriting in the current generation. But, is it advisable to teach how to write and to assess handwriting in pre- and primary schoolchildren on tablets rather than on paper? Since handwriting is not automatized before the age of ten years, children’s handwriting movements require graphomotor and visual feedback as well as permanent control of movement execution during handwriting. Modifications in writing conditions, for instance the smoother writing surface of a tablet, might influence handwriting performance in general, and in particular those of non-automatized beginning writers.In order to investigate how handwriting performance is affected by a difference in friction of the writing surface, we recruited three groups with varying levels of handwriting automaticity: 25 preschoolers, 27 second graders and 25 adults. We administered three tasks measuring graphomotor abilities, visuomotor abilities and handwriting performance (only second graders and adults. We evaluated two aspects of handwriting performance: the handwriting quality with a visual score and the handwriting dynamics using online handwriting measures (e.g. writing duration, writing velocity, strokes and number of inversions in velocity (NIV. In particular, NIVs which describe the number of velocity peaks during handwriting, are directly related to the level of handwriting automaticity.In general, we found differences between writing on paper compared to the tablet. These differences were partly task-dependent. The comparison between tablet and paper revealed a faster writing velocity for all groups and all tasks on the tablet which indicates that all participants – even the experienced writers – were influenced by the lower friction of the

  7. Is Handwriting Performance Affected by the Writing Surface? Comparing Preschoolers', Second Graders', and Adults' Writing Performance on a Tablet vs. Paper

    Science.gov (United States)

    Gerth, Sabrina; Klassert, Annegret; Dolk, Thomas; Fliesser, Michael; Fischer, Martin H.; Nottbusch, Guido; Festman, Julia

    2016-01-01

    Due to their multifunctionality, tablets offer tremendous advantages for research on handwriting dynamics or for interactive use of learning apps in schools. Further, the widespread use of tablet computers has had a great impact on handwriting in the current generation. But, is it advisable to teach how to write and to assess handwriting in pre- and primary schoolchildren on tablets rather than on paper? Since handwriting is not automatized before the age of 10 years, children's handwriting movements require graphomotor and visual feedback as well as permanent control of movement execution during handwriting. Modifications in writing conditions, for instance the smoother writing surface of a tablet, might influence handwriting performance in general and in particular those of non-automatized beginning writers. In order to investigate how handwriting performance is affected by a difference in friction of the writing surface, we recruited three groups with varying levels of handwriting automaticity: 25 preschoolers, 27 second graders, and 25 adults. We administered three tasks measuring graphomotor abilities, visuomotor abilities, and handwriting performance (only second graders and adults). We evaluated two aspects of handwriting performance: the handwriting quality with a visual score and the handwriting dynamics using online handwriting measures [e.g., writing duration, writing velocity, strokes and number of inversions in velocity (NIV)]. In particular, NIVs which describe the number of velocity peaks during handwriting are directly related to the level of handwriting automaticity. In general, we found differences between writing on paper compared to the tablet. These differences were partly task-dependent. The comparison between tablet and paper revealed a faster writing velocity for all groups and all tasks on the tablet which indicates that all participants—even the experienced writers—were influenced by the lower friction of the tablet surface. Our

  8. Tribological performance of femtosecond laser-induced periodic surface structures on titanium and a high toughness bearing steel

    Energy Technology Data Exchange (ETDEWEB)

    Bonse, J., E-mail: joern.bonse@bam.de [BAM Bundesanstalt für Materialforschung und -prüfung, Unter den Eichen 87, D-12205 Berlin (Germany); Koter, R.; Hartelt, M.; Spaltmann, D.; Pentzien, S. [BAM Bundesanstalt für Materialforschung und -prüfung, Unter den Eichen 87, D-12205 Berlin (Germany); Höhm, S.; Rosenfeld, A. [Max-Born-Institut für Nichtlineare Optik und Kurzzeitspektroskopie (MBI), Max-Born-Straße 2A, D-12489 Berlin (Germany); Krüger, J. [BAM Bundesanstalt für Materialforschung und -prüfung, Unter den Eichen 87, D-12205 Berlin (Germany)

    2015-05-01

    Graphical abstract: - Highlights: • Large LIPSS covered areas were manufactured by fs-laser irradiation on steel (X30CrMoN15-1) and titanium (Ti). • LIPSS with spatial periods around 500 nm were formed homogeneously on both materials. • Tribological performance of LIPSS covered areas was qualified in reciprocal sliding tests in two different lubricating oils. • LIPSS on titanium significantly reduced the friction coefficient and wear when a fully formulated engine oil was used. - Abstract: Laser-induced periodic surface structures (LIPSS, ripples) were processed on steel (X30CrMoN15-1) and titanium (Ti) surfaces by irradiation in air with linear polarized femtosecond laser pulses with a pulse duration of 30 fs at 790 nm wavelength. For the processing of large LIPSS covered surface areas (5 mm × 5 mm), the laser fluence and the spatial spot overlap were optimized in a sample-scanning geometry. The laser-processed surfaces were characterized by optical microscopy (OM), white light interference microscopy (WLIM) and scanning electron microscopy (SEM). Spatial LIPSS periods between 450 and 600 nm were determined. The nanostructured surface regions were tribologically tested under reciprocal sliding conditions against a 10-mm diameter ball of hardened 100Cr6 steel. Paraffin oil and engine oil were used as lubricants for 1000 sliding cycles at 1 Hz with a normal load of 1.0 N. The corresponding wear tracks were analyzed by OM and SEM. In particular cases, the laser-generated nanostructures endured the tribological treatment. Simultaneously, a significant reduction of the friction coefficient and the wear was observed in the laser-irradiated (LIPSS-covered) areas when compared to the non-irradiated surface. The experiments reveal the potential benefit of laser surface structuring for tribological applications.

  9. Tribological performance of femtosecond laser-induced periodic surface structures on titanium and a high toughness bearing steel

    International Nuclear Information System (INIS)

    Bonse, J.; Koter, R.; Hartelt, M.; Spaltmann, D.; Pentzien, S.; Höhm, S.; Rosenfeld, A.; Krüger, J.

    2015-01-01

    Graphical abstract: - Highlights: • Large LIPSS covered areas were manufactured by fs-laser irradiation on steel (X30CrMoN15-1) and titanium (Ti). • LIPSS with spatial periods around 500 nm were formed homogeneously on both materials. • Tribological performance of LIPSS covered areas was qualified in reciprocal sliding tests in two different lubricating oils. • LIPSS on titanium significantly reduced the friction coefficient and wear when a fully formulated engine oil was used. - Abstract: Laser-induced periodic surface structures (LIPSS, ripples) were processed on steel (X30CrMoN15-1) and titanium (Ti) surfaces by irradiation in air with linear polarized femtosecond laser pulses with a pulse duration of 30 fs at 790 nm wavelength. For the processing of large LIPSS covered surface areas (5 mm × 5 mm), the laser fluence and the spatial spot overlap were optimized in a sample-scanning geometry. The laser-processed surfaces were characterized by optical microscopy (OM), white light interference microscopy (WLIM) and scanning electron microscopy (SEM). Spatial LIPSS periods between 450 and 600 nm were determined. The nanostructured surface regions were tribologically tested under reciprocal sliding conditions against a 10-mm diameter ball of hardened 100Cr6 steel. Paraffin oil and engine oil were used as lubricants for 1000 sliding cycles at 1 Hz with a normal load of 1.0 N. The corresponding wear tracks were analyzed by OM and SEM. In particular cases, the laser-generated nanostructures endured the tribological treatment. Simultaneously, a significant reduction of the friction coefficient and the wear was observed in the laser-irradiated (LIPSS-covered) areas when compared to the non-irradiated surface. The experiments reveal the potential benefit of laser surface structuring for tribological applications

  10. Change characteristics of DSi and nutrition structure at the Yangtze River Estuary after Three Gorges Project impounding and their ecological effect

    Directory of Open Access Journals (Sweden)

    Li Lei

    2017-06-01

    Full Text Available The variation law of dissolved silica (DSi, dissolved inorganic nitrogen (DIN, dissolved inorganic phosphorus (DIP and nutrition structure after the Three Gorges Project (TGP impounding as well as their ecological effect were analyzed according to monitoring survey of the Yangtze River Estuary in spring (May and summer (August from 2004-2009. The results showed that after impounding, DSi and DIN concentration decreased and increased, respectively. During the study period, DSi decreased by about 63%, while DIN almost tripled. DIP concentration fluctuated slightly. With respect to nutrition structure, N:P increased, whereas Si:P and Si:N declined. According to chemometry standard of nutrient limits, nutrition structure tended to be imbalanced and the limiting factor of phytoplankton growth (P was studied. Changes of nutrition structure have largely decreased diatom and caused different composition of dominant phytoplankton species. This may change ecosystem structure of the Yangtze River Estuary.

  11. Surface and 60 FSW Performance Testing of the Modified MBS 2000 Closed Circuit Oxygen Rebreather

    National Research Council Canada - National Science Library

    Fothergill, David

    2007-01-01

    ... into the system during a treatment. Since all previous testing had been performed at 1 ATA, a second major objective for the FY06 tests was to evaluate the modified MBS 2000 rebreather at 60 fsw in a hyperbaric chamber...

  12. Adding a Performance-Based Component to Surface Warfare Officer Bonuses: Will it Affect Retention?

    National Research Council Canada - National Science Library

    Carman, Aron S; Mudd, Ryan M

    2008-01-01

    ... Authorization and the current officer inventory beginning at 9 years of commissioned service. The objective of this study was to analyze the 13-year retention effect of adding a performance-based component to the SWO Critical Skills Bonus (CSB...

  13. Investigation on multi-objective performance optimization algorithm application of fan based on response surface method and entropy method

    Science.gov (United States)

    Zhang, Li; Wu, Kexin; Liu, Yang

    2017-12-01

    A multi-objective performance optimization method is proposed, and the problem that single structural parameters of small fan balance the optimization between the static characteristics and the aerodynamic noise is solved. In this method, three structural parameters are selected as the optimization variables. Besides, the static pressure efficiency and the aerodynamic noise of the fan are regarded as the multi-objective performance. Furthermore, the response surface method and the entropy method are used to establish the optimization function between the optimization variables and the multi-objective performances. Finally, the optimized model is found when the optimization function reaches its maximum value. Experimental data shows that the optimized model not only enhances the static characteristics of the fan but also obviously reduces the noise. The results of the study will provide some reference for the optimization of multi-objective performance of other types of rotating machinery.

  14. The effects of surface-charged submicron polystyrene particles on the structure and performance of PSF forward osmosis membrane

    Science.gov (United States)

    Zuo, Hao-Ran; Fu, Jia-Bei; Cao, Gui-Ping; Hu, Nian; Lu, Hui; Liu, Hui-Qing; Chen, Peng-Peng; Yu, Jie

    2018-04-01

    Monodisperse surface-charged submicron polystyrene particles were designed, synthesized, and blended into polysulfone (PSF) support layer to prepare forward osmosis (FO) membrane with high performance. The membrane incorporated with particles were characterized with respect to morphology, porosity, and internal osmotic pressure (IOP). Results showed that the polymer particles not only increased the hydrophilicity and porosity of support layer, but also generated considerable IOP, which helped markedly decreasing the structure parameter from 1550 to 670 μm. The measured mass transfer parameters further confirmed the beneficial effects of the surface-charged submicron polymer particles on the performance of FO membrane. For instance, the water permeability coefficient (5.37 L m-2 h-1 bar-1) and water flux (49.7 L m-2 h-1) of the FO membrane incorporated with 5 wt% particles were almost twice as much as that of FO membrane without incorporation. This study suggests that monodisperse surface-charged submicron polymer particles are potential modifiers for improving the performance of FO membranes.

  15. Improving polymer/nanocrystal hybrid solar cell performance via tuning ligand orientation at CdSe quantum dot surface.

    Science.gov (United States)

    Fu, Weifei; Wang, Ling; Zhang, Yanfang; Ma, Ruisong; Zuo, Lijian; Mai, Jiangquan; Lau, Tsz-Ki; Du, Shixuan; Lu, Xinhui; Shi, Minmin; Li, Hanying; Chen, Hongzheng

    2014-11-12

    Achieving superior solar cell performance based on the colloidal nanocrystals remains challenging due to their complex surface composition. Much attention has been devoted to the development of effective surface modification strategies to enhance electronic coupling between the nanocrystals to promote charge carrier transport. Herein, we aim to attach benzenedithiol ligands onto the surface of CdSe nanocrystals in the "face-on" geometry to minimize the nanocrystal-nanocrystal or polymer-nanocrystal distance. Furthermore, the "electroactive" π-orbitals of the benzenedithiol are expected to further enhance the electronic coupling, which facilitates charge carrier dissociation and transport. The electron mobility of CdSe QD films was improved 20 times by tuning the ligand orientation, and high performance poly[2,6-(4,4-bis(2-ethylhexyl)-4H-cyclopenta[2,1-b;3,4-b']-dithiophene)-alt-4,7-(2,1,3-benzothiadiazole)] (PCPDTBT):CdSe nanocrystal hybrid solar cells were also achieved, showing a highest power conversion efficiency of 4.18%. This research could open up a new pathway to improve further the performance of colloidal nanocrystal based solar cells.

  16. Effect of the linseed oil surface treatment on the performance of resistive plate chambers

    International Nuclear Information System (INIS)

    Abbrescia, M.; Colaleo, A.; Iaselli, G.; Maggi, M.; Marangelli, B.; Natali, S.; Nuzzo, S.; Ranieri, A.; Romano, F.; Arena, V.; Bonomi, G.; Braj, A.; Gianini, G.; Liguori, G.; Ratti, S.P.; Riccardi, C.; Viola, L.; Vitulo, P.

    1997-01-01

    Results on the behaviour of several bakelite resistive plate chambers (RPCs) without the linseed oil treatment of the internal electrodes will be presented. Efficiency, collected charge and cluster size distributions will be compared to the ones of a standard oiled RPC. Currents and single rate are the quantities most affected by the surface treatment of the electrodes beyond the optical/mechanical properties. A factor 4 less in currents and at least a factor 10 less in single rate is achieved using standard oiled RPCs operated in streamer mode. (orig.)

  17. Investigation of micro burner performance during porous media combustion for surface and submerged flames

    Science.gov (United States)

    Janvekar, Ayub Ahmed; Abdullah, M. Z.; Ahmad, Z. A.; Abas, Aizat; Hussien, Ahmed A.; Kataraki, Pramod S.; Mohamed, Mazlan; Husin, Azmi; Fadzli, Khairil

    2018-05-01

    Porous media combustion is considered to be one of the popular choice due to its tremendous advantages. Such type of combustion liberates not only super stable flame but also maintains emissions parameters below thresholds level. Present study incorporates reaction and preheat layer with discrete and foam type of materials respectively. Burner was made to run in ultra-lean mode. Optimum equivalence ratio was found out to be 0.7 for surface flame, while 0.6 during submerged flame condition. Maximum thermal efficiency was noted to be 81%. Finally, emissions parameters where recorded continuously to measure NOx and CO, which were under global limits.

  18. AlScN thin film based surface acoustic wave devices with enhanced microfluidic performance

    OpenAIRE

    Wang, Wenbo; Fu, Yong Qing; Chen, Jinju; Xuan, Weipeng; Chen, Jinkai; Mayrhofer, Paul; Duan, Pengfei; Bittner, Elmar; Luo, Jikui

    2016-01-01

    This paper reports the characterization of scandium aluminum nitride (Al1−x Sc x N, x  =  27%) films and discusses surface acoustic wave (SAW) devices based on them. Both AlScN and AlN films were deposited on silicon by sputtering and possessed columnar microstructures with (0 0 0 2) crystal orientation. The AlScN/Si SAW devices showed improved electromechanical coupling coefficients (K 2, ~2%) compared with pure AlN films (

  19. Field performance assessment of synthetic liners for uranium tailings ponds: a status report

    International Nuclear Information System (INIS)

    Mitchell, D.H.; Spanner, G.E.

    1984-03-01

    The objective of this study is to provide a database to support US Nuclear Regulatory Commission (NRC) licensing of uranium tailings leachate isolation impoundments. This objective is being accomplished by determining the effectiveness of design, installation, and quality assurance practices associated with uranium mill tailings impoundments with flexible membrane liners. The program includes testing of chemical resistance and physical performance of liners, leak detection systems, and seam inspection techniques. This report presents the status of the program through September 1983. The report addresses impoundment design, installation, and inspection techniques used by the uranium milling industry. To determine the relative successes of these techniques, information has been collected from consultants, mill operators, and the synthetic liner industry. Progress in experimental tasks on chemical resistance of liners, physical properties of liners, and nondestructive examination of seams is reported. 25 references, 9 figures, 13 tables

  20. Synchronous response of sedimentary organic carbon accumulation on the inner shelf of the East China Sea to the water impoundment of Three Gorges and Gezhouba Dams

    Science.gov (United States)

    Lin, Jia; Zhu, Qing; Hong, Yuehui; Yuan, Lirong; Liu, Jinzhong; Xu, Xiaoming; Wang, Jianghai

    2018-01-01

    Coastal seas, located between continents and the open ocean, are an important active carbon pool. The sedimentary total organic carbon (TOC) in these areas is a mixture of terrestrial and marine sources, and can be a powerful proxy for tracing natural processes and human activities. In this study, one fine-grained sediment core (DH5-1) from the inner shelf of the East China Sea was systematically analyzed for TOC and black carbon (BC) contents and TOC stable carbon isotope ratios (δ13C). By combining these data with 210Pb dating, an improved carbon correction model and a two end-member mixing model, we reconstructed century-scale high-resolution sequences of corrected TOC, terrestrial TOC and marine TOC contents and identified two carbon depletion events in the DH5-1 record. The two events, shown as two minima in the TOC profiles, correspond temporally to 1985-1987 AD and 2003-2006 AD, which exactly matches the water impoundment of the Gezhouba Dam and Three Gorges Dam, respectively. In addition, the variations in TOC contents and δ13C values before, during or after the minima demonstrate a relationship between the depletion events and water impoundment of the dams on the Changjiang River. The TOC reductions may represent synchronous responses of sedimentary TOC and resultant ecological effects on the inner shelf of the East China Sea to the water impoundment of the dams. These new TOC records reflect the interaction between natural and anthropogenic processes and, accordingly, provide a deep insight and important references for assessing marine ecological effects resulting from water impoundment of largescale dams.

  1. Performance enhancement in organic photovoltaic solar cells using iridium (Ir) ultra-thin surface modifier (USM)

    Science.gov (United States)

    Pandey, Rina; Lim, Ju Won; Kim, Jung Hyuk; Angadi, Basavaraj; Choi, Ji Won; Choi, Won Kook

    2018-06-01

    In this study, Iridium (Ir) metallic layer as an ultra-thin surface modifier (USM) was deposited on ITO coated glass substrate using radio frequency magnetron sputtering for improving the photo-conversion efficiency of organic photovoltaic cells. Ultra-thin Ir acts as a surface modifier replacing the conventional hole transport layer (HTL) PEDOT:PSS in organic photovoltaic (OPV) cells with two different active layers P3HT:PC60BM and PTB7:PC70BM. The Ir USM (1.0 nm) coated on ITO glass substrate showed transmittance of 84.1% and work function of >5.0 eV, which is higher than that of ITO (4.5-4.7 eV). The OPV cells with Ir USM (1.0 nm) exhibits increased power conversion efficiency of 3.70% (for P3HT:PC60BM active layer) and 7.28% (for PTB7:PC70BM active layer) under 100 mW/cm2 illumination (AM 1.5G) which are higher than those of 3.26% and 6.95% for the same OPV cells but with PEDOT:PSS as HTL instead of Ir USM. The results reveal that the chemically stable Ir USM layer could be used as an alternative material for PEDOT:PSS in organic photovoltaic cells.

  2. Performance of Electrocoagulation Process in the Removal of Total Coliform and Hetrotrophic Bacteria from Surface Water

    Directory of Open Access Journals (Sweden)

    Jamshid Derayat

    2015-03-01

    Full Text Available Electrocoagulation is an electrochemical method for the treatment of water and wastewater. The present cross-sectional study was designed to investigate the removal efficiency of total coliform and heterotrophic bacteria from surface water using the process. For this purpose, water samples were taken from the drinking water intake at Suleiman-Shahsonghur Dam. The electrocoagulation process was carried out in a Plexiglas reactor in the batch mode with Al and Fe used electrodes. The experiment design was carried out using the Design Expert Software (Stat-Ease Inc., Ver. 6.0.6. After each run, the values of metals dissolved due to anode electrode dissolution were measured using the Inductively Coupled Plasma (ICP and the results were analyzed using the RSM model. Results revealed maximum removal efficiencies of 100% and 89.1% for total coliform and heterotrophic bacteria using the Al electrode, respectively. Also, maximum removal efficiencies using the Fe electrode for the same pollutants were 100% and 76.1%. The measurements clearly indicate that the quantities of Al and Fe released in water were higher than the recommended values. While the electrocoagulation process showed to be effective in removing microbial agents from surface waters, the high concentrations of dissolved metals due to the dissolution of the anode electrode seem to remain a health problem that requires optimal conditions to be determined for acheiving standard concentrations of the dissolved metals.

  3. Nitrogen-doped Carbon Microfiber with Wrinkled Surface for High Performance Supercapacitors

    Science.gov (United States)

    Liu, Ruili; Pan, Lixia; Jiang, Jianzhong; Xi, Xin; Liu, Xiaoxue; Wu, Dongqing

    2016-02-01

    In this work, nitrogen-doped carbon microfiber (NCMF) is fabricated via a facile co-assembly of natural silk and graphene oxide (GO) and the following thermal treatment. The amphiphilic nature of GO endows NCMF a crumpled surface with a high surface area of 115 m2 g-1. As the binder-free electrode in electrical double-layer capacitors, NCMF shows an excellent capacitance of 196 F g-1 at scan rate of 5 mV s-1, which is almost four times higher than that of the pristine CMF from silk (55 F g-1). Additionally, the capacitance of NCMF can be kept around 92 F g-1 at a high scan rate of 300 mV s-1 even after 10000 cycles. More importantly, a high energy density (≈22.7 μW h cm-2) and power density (≈10.26 mW cm-2) are achieved by the all-solid-state supercapacitor based on NCMF.

  4. High performance multi-spectral interrogation for surface plasmon resonance imaging sensors.

    Science.gov (United States)

    Sereda, A; Moreau, J; Canva, M; Maillart, E

    2014-04-15

    Surface plasmon resonance (SPR) sensing has proven to be a valuable tool in the field of surface interactions characterization, especially for biomedical applications where label-free techniques are of particular interest. In order to approach the theoretical resolution limit, most SPR-based systems have turned to either angular or spectral interrogation modes, which both offer very accurate real-time measurements, but at the expense of the 2-dimensional imaging capability, therefore decreasing the data throughput. In this article, we show numerically and experimentally how to combine the multi-spectral interrogation technique with 2D-imaging, while finding an optimum in terms of resolution, accuracy, acquisition speed and reduction in data dispersion with respect to the classical reflectivity interrogation mode. This multi-spectral interrogation methodology is based on a robust five parameter fitting of the spectral reflectivity curve which enables monitoring of the reflectivity spectral shift with a resolution of the order of ten picometers, and using only five wavelength measurements per point. In fine, such multi-spectral based plasmonic imaging system allows biomolecular interaction monitoring in a linear regime independently of variations of buffer optical index, which is illustrated on a DNA-DNA model case. © 2013 Elsevier B.V. All rights reserved.

  5. Mercury concentrations of fish in Southern Indian Lake and Issett Lake, Manitoba 1975-88: The effect of lake impoundment and Churchill River diversion

    International Nuclear Information System (INIS)

    Strange, N.E.; Bodaly, R.A.; Fudge, R.J.P.

    1991-01-01

    Southern Indian and Issett Lakes in northern Manitoba were flooded in 1976 as part of Manitoba Hydro's Churchill River diversion project. Fish were collected from 1975 to 1988 from five regional sites on the lakes to examine the effects of impoundment and river diversion on muscle mercury concentrations. Raw data for individual fish caught in 1987 and 1988 are presented, along with means and analyses calculated over the entire 1975-1988 study period. Mercury concentrations in whitefish, pike, and walleye increased significantly after impoundment. Whitefish mercury levels peaked in 1978 and have since declined to near pre-flooding levels. Northern pike and walleye mercury levels were much higher than for whitefish. Pike mercury concentrations showed no indication of declining after 12 years of impoundment, but walleye mercury levels at 2 of the 5 Southern Indian Lake sites declined from maximum recorded levels. Significant variability in fish mercury concentrations was noted both from year to year and among the sites. It is suggested that site-to-site variations are due to varying conditions in the reservoir which stimulate mercury methylation. Since there appears to be an ongoing long-term source of mercury and organic material from the eroding shorelines, pike and walleye mercury concentrations are expected to remain high for many years. 25 refs., 7 figs., 20 tabs

  6. Geochemical characterisation of seepage and drainage water quality from two sulphide mine tailings impoundments: Acid mine drainage versus neutral mine drainage

    Science.gov (United States)

    Heikkinen, P.M.; Raisanen, M.L.; Johnson, R.H.

    2009-01-01

    Seepage water and drainage water geochemistry (pH, EC, O2, redox, alkalinity, dissolved cations and trace metals, major anions, total element concentrations) were studied at two active sulphide mine tailings impoundments in Finland (the Hitura Ni mine and Luikonlahti Cu mine/talc processing plant). The data were used to assess the factors influencing tailings seepage quality and to identify constraints for water treatment. Changes in seepage water quality after equilibration with atmospheric conditions were evaluated based on geochemical modelling. At Luikonlahti, annual and seasonal changes were also studied. Seepage quality was largely influenced by the tailings mineralogy, and the serpentine-rich, low sulphide Hitura tailings produced neutral mine drainage with high Ni. In contrast, drainage from the high sulphide, multi-metal tailings of Luikonlahti represented typical acid mine drainage with elevated contents of Zn, Ni, Cu, and Co. Other factors affecting the seepage quality included weathering of the tailings along the seepage flow path, process water input, local hydrological settings, and structural changes in the tailings impoundment. Geochemical modelling showed that pH increased and some heavy metals were adsorbed to Fe precipitates after net alkaline waters equilibrated with the atmosphere. In the net acidic waters, pH decreased and no adsorption occurred. A combination of aerobic and anaerobic treatments is proposed for Hitura seepages to decrease the sulphate and metal loading. For Luikonlahti, prolonged monitoring of the seepage quality is suggested instead of treatment, since the water quality is still adjusting to recent modifications to the tailings impoundment.

  7. 30 CFR 780.25 - Reclamation plan: Siltation structures, impoundments, and refuse piles.

    Science.gov (United States)

    2010-07-01

    ... is capable of being done after consideration of cost, logistics, and available technology. The fact... COAL EXPLORATION SYSTEMS UNDER REGULATORY PROGRAMS SURFACE MINING PERMIT APPLICATIONS-MINIMUM..., and refuse piles. (a) General. Each application must include a general plan and a detailed design plan...

  8. Overland erosion of uranium-mill-tailings impoundments: physical processes and computational methods

    International Nuclear Information System (INIS)

    Walters, M.H.

    1983-03-01

    The surface runoff and erosional processes of watersheds caused by rainfall-runoff are reviewed. Soil properties, topography, and rainstorm distribution are discussed with respect to their effects on soil erosion. The effects of climate and vegetation are briefly presented. Regression models and physical process simulation models are reviewed

  9. Assessment of the Performance of Three Dynamical Climate Downscaling Methods Using Different Land Surface Information over China

    Directory of Open Access Journals (Sweden)

    Peng Liu

    2018-03-01

    Full Text Available This study aims to assess the performance of different dynamical downscaling methods using updated land surface information. Particular attention is given to obtaining high-resolution climate information over China by the combination of an appropriate dynamical downscaling method and updated land surface information. Two group experiments using two land surface datasets are performed, including default Weather Research and Forecasting (WRF land surface data (OLD and accurate dynamically accordant MODIS data (NEW. Each group consists of three types of experiments for the summer of 2014, including traditional continuous integration (CT, spectral nudging (SN, and re-initialization (Re experiments. The Weather Research and Forecasting (WRF model is used to dynamically downscale ERA-Interim (reanalysis of the European Centre for Medium-Range Weather Forecast, ECMWF data with a grid spacing of 30 km over China. The simulations are evaluated via comparison with observed conventional meteorological variables, showing that the CT method, which notably overestimates 2 m temperature and underestimates 2 m relative humidity across China, performs the worst; the SN and Re runs outperform the CT method, and the Re shows the smallest RMSE (root means square error. A comparison of observed and simulated precipitation shows that the SN simulation is closest to the observed data, while the CT and Re simulations overestimate precipitation south of the Yangtze River. Compared with the OLD group, the RMSE values of temperature and relative humidity are significantly improved in CT and SN, and there is smaller improved in Re. However, obvious improvements in precipitation are not evident.

  10. Performance analysis of nitride alternative plasmonic materials for localized surface plasmon applications

    DEFF Research Database (Denmark)

    Guler, U.; Naik, G. V.; Boltasseva, Alexandra

    2012-01-01

    . Titanium nitride and zirconium nitride, which were recently suggested as alternative plasmonic materials in the visible and near-infrared ranges, are compared to the performance of gold. In contrast to the results from quasistatic methods, both nitride materials are very good alternatives to the usual...

  11. Influence of microscale surface modification on impinging flow heat transfer performance

    NARCIS (Netherlands)

    Taha, T.J.; Lefferts, Leonardus; van der Meer, Theodorus H.

    2016-01-01

    An experimental approach has been used to investigate the influence of a thin layer of carbon nanotubes (CNTs) on the convective heat transfer performance under impinging flow conditions. A successful synthesis of CNT layers was achieved using a thermal catalytic vapor deposition process (TCVD) on

  12. Enhanced electrochemical performance of LiMnPO4 by Li+-conductive Li3VO4 surface coatings

    International Nuclear Information System (INIS)

    Dong, Youzhong; Zhao, Yanming; Duan, He; Liang, Zhiyong

    2014-01-01

    By a simple wet ball-milling method, Li 3 VO 4 -coated LiMnPO 4 samples were prepared successfully for the first time. The thin Li 3 VO 4 coating layer with a three-dimensional Li + -ion transport path and high mobility of Li + -ion strongly adhered to the LiMnPO 4 material reduces Mn dissolution and increases the Li + flux through the surface of the LiMnPO 4 itself by preventing formation of phases on the surface that would normally block Li + as well as Li + -ion permeation into the surface of the LiMnPO 4 electrode and therefore improve the rate capability as well as the cycling stability of LiMnPO 4 materials. The electrochemical testing shows that the 5% Li 3 VO 4 -coated LiMnPO 4 sample shows a clear voltage plateau in the charge curves and a much higher reversible capacity at different discharge rates compared with the pristine LiMnPO 4 . EIS results also show that the surface charge transfer resistance and Warburg impedance of the Li 3 VO 4 -coated LiMnPO 4 samples significantly decreased. The surface charge transfer resistance and Warburg impedance for the pristine LiMnPO 4 are 955.1 Ω and 400.3 Ω, respectively. While, for the 5% Li 3 VO 4 -coated LiMnPO 4 , the value are only 400.2 Ω and 283.6 Ω, respectively. The surface charge transfer resistance decreases more than half. All of the improved performance will be favorable for application of the LiMnPO 4 in high-power lithium ion batteries

  13. Impact of the surface quality on the thermal shock performance of beryllium armor tiles for first wall applications

    Energy Technology Data Exchange (ETDEWEB)

    Spilker, B., E-mail: b.spilker@fz-juelich.de; Linke, J.; Pintsuk, G.; Wirtz, M.

    2016-11-01

    Highlights: • Different surface qualities of S-65 beryllium are tested under high heat flux conditions. • After 1000 thermal shocks, the loaded area exhibits a crucial destruction. • Stress accelerated grain boundary oxidation/dynamic embrittlement effects are linked to the thermal shock performance of beryllium. • Thermally induced cracks form between 1 and 10 pulses and grow wider and deeper between 10 and 100 pulses. • Thermally induced cracks form and propagate independently from surface grooves and the surface quality. - Abstract: Beryllium will be applied as first wall armor material in ITER. The armor has to sustain high steady state and transient power fluxes. For transient events like edge localized modes, these transient power fluxes rise up to 1.0 GW m{sup −2} with a duration of 0.5–0.75 ms in the divertor region and a significant fraction of this power flux is deposited on the first wall as well. In the present work, the reference beryllium grade for the ITER first wall application S-65 was prepared with various surface conditions and subjected to transient power fluxes (thermal shocks) with ITER relevant loading parameters. After 1000 thermal shocks, a crucial destruction of the entire loaded area was observed and linked to the stress accelerated grain boundary oxidation (SAGBO)/dynamic embrittlement (DE) effect. Furthermore, the study revealed that the majority of the thermally induced cracks formed between 1 and 10 pulses and then grew wider and deeper with increasing pulse number. The surface quality did not influence the cracking behavior of beryllium in any detectable way. However, the polished surface demonstrated the highest resistance against the observed crucial destruction mechanism.

  14. Performance of free water surface flow constructed wetland with floating aquatic macrophytes

    Directory of Open Access Journals (Sweden)

    C. Soler

    2018-04-01

    Full Text Available The aim of this study was to evaluate the behavior of constructed wetlands with aquatic macrophytes in decreasing the concentration of pollutants from urban effluents. A pilot-scale system with two coverages of floating plants and two hydraulic residence times, working with continuous flow laminar was built. The lower concentration of chemical oxygen demand and biological oxygen demand, were obtained with the lower coverage and higher hydraulic residence times. With little influence of the variables on the concentration of total nitrogen and total suspended solids, being the significant response for total phosphorus with the lowest plant coverage. There was a highly significant removal of total coliforms, regardless of coverage and in favor of higher hydraulic residence times. The use of free water surface wetlands is auspicious for sanitary control, showing low incidence on total nitrogen and total phosphorus.

  15. Fabrication of high surface area graphene electrodes with high performance towards enzymatic oxygen reduction

    International Nuclear Information System (INIS)

    Di Bari, Chiara; Goñi-Urtiaga, Asier; Pita, Marcos; Shleev, Sergey; Toscano, Miguel D.; Sainz, Raquel; De Lacey, Antonio L.

    2016-01-01

    High surface area graphene electrodes were prepared by simultaneous electrodeposition and electroreduction of graphene oxide. The electrodeposition process was optimized in terms of pH and conductivity of the solution and the obtained graphene electrodes were characterized by X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, scanning electron microscopy and electrochemical methods (cyclic voltammetry and impedance spectroscopy). Electrodeposited electrodes were further functionalized to carry out covalent immobilization of two oxygen-reducing multicopper oxidases: laccase and bilirubin oxidase. The enzymatic electrodes were tested as direct electron transfer based biocathodes and catalytic currents as high as 1 mA/cm 2 were obtained. Finally, the mechanism of the enzymatic oxygen reduction reaction was studied for both enzymes calculating the Tafel slopes and transfer coefficients.

  16. Effects of Surface and Morphological Properties of Zeolite on Impedance Spectroscopy-Based Sensing Performance

    Directory of Open Access Journals (Sweden)

    Prabir K. Dutta

    2012-10-01

    Full Text Available Measurement by impedance spectroscopy of the changes in intrazeolitic cation motion of pressed pellets of zeolite particles upon adsorption of dimethylmethylphosphonate (DMMP provides a strategy for sensing DMMP, a commonly used simulant for highly toxic organophosphate nerve agents. In this work, two strategies for improving the impedance spectroscopy based sensing of DMMP on zeolites were investigated. The first one is the use of cerium oxide (CeO2 coated on the zeolite surface to neutralize acidic groups that may cause the decomposition of DMMP, and results in better sensor recovery. The second strategy was to explore the use of zeolite Y membrane. Compared to pressed pellets, the membranes have connected supercages of much longer length scales. The zeolite membranes resulted in higher sensitivity to DMMP, but recovery of the device was significantly slower as compared to pressed zeolite pellets.

  17. Surface chemistry analysis of lithium conditioned NSTX graphite tiles correlated to plasma performance

    Energy Technology Data Exchange (ETDEWEB)

    Taylor, C.N., E-mail: chase.taylor@inl.gov [Purdue University, School of Nuclear Engineering, West Lafayette, IN 47906 (United States); Birck Nanotechnology Center, Discovery Park, West Lafayette, IN 47907 (United States); Luitjohan, K.E. [Purdue University, School of Nuclear Engineering, West Lafayette, IN 47906 (United States); Heim, B. [Purdue University, School of Nuclear Engineering, West Lafayette, IN 47906 (United States); Birck Nanotechnology Center, Discovery Park, West Lafayette, IN 47907 (United States); Kollar, L. [Purdue University, School of Nuclear Engineering, West Lafayette, IN 47906 (United States); Allain, J.P. [Purdue University, School of Nuclear Engineering, West Lafayette, IN 47906 (United States); Birck Nanotechnology Center, Discovery Park, West Lafayette, IN 47907 (United States); Skinner, C.H.; Kugel, H.W.; Kaita, R.; Roquemore, A.L. [Princeton Plasma Physics Laboratory, Princeton, NJ 08543 (United States); Maingi, R. [Oak Ridge National Laboratory, Oak Ridge, TN 37831 (United States)

    2013-12-15

    Lithium wall conditioning in NSTX has resulted in reduced divertor recycling, improved energy confinement, and reduced frequency of edge-localized modes (ELMs), up to the point of complete ELM suppression. NSTX tiles were removed from the vessel following the 2008 campaign and subsequently analyzed using X-ray photoelectron spectroscopy as well as nuclear reaction ion beam analysis. In this paper we relate surface chemistry to deuterium retention/recycling, develop methods for cleaning of passivated NSTX tiles, and explore a method to effectively extract bound deuterium from lithiated graphite. Li–O–D and Li–C–D complexes characteristic of deuterium retention that form during NSTX operations are revealed by sputter cleaning and heating. Heating to ∼850 °C desorbed all deuterium complexes observed in the O 1s and C 1s photoelectron energy ranges. Tile locations within approximately ±2.5 cm of the lower vertical/horizontal divertor corner appear to have unused Li-O bonds that are not saturated with deuterium, whereas locations immediately outboard of this region indicate high deuterium recycling. X-ray photo electron spectra of a specific NSTX tile with wide ranging lithium coverage indicate that a minimum lithium dose, 100–500 nm equivalent thickness, is required for effective deuterium retention. This threshold is suspected to be highly sensitive to surface morphology. The present analysis may explain why plasma discharges in NSTX continue to benefit from lithium coating thickness beyond the divertor deuterium ion implantation depth, which is nominally <10 nm.

  18. Towards vibrational spectroscopy on surface-attached colloids performed with a quartz crystal microbalance

    Directory of Open Access Journals (Sweden)

    Diethelm Johannsmann

    2016-12-01

    Full Text Available Colloidal spheres attached to a quartz crystal microbalance (QCM produce the so-called “coupled resonances”. They are resonators of their own, characterized by a particle resonance frequency, a resonance bandwidth, and a modal mass. When the frequency of the main resonator comes close to the frequency of the coupled resonance, the bandwidth goes through a maximum. A coupled resonance can be viewed as an absorption line in acoustic shear-wave spectroscopy. The known concepts from spectroscopy apply. This includes the mode assignment problem, selection rules, and the oscillator strength. In this work, the mode assignment problem was addressed with Finite Element calculations. These reveal that a rigid sphere in contact with a QCM displays two modes of vibration, termed “slipping” and “rocking”. In the slipping mode, the sphere rotates about its center; it exerts a tangential force onto the resonator surface at the point of contact. In the rocking mode, the sphere rotates about the point of contact; it exerts a torque onto the substrate. In liquids, both axes of rotation are slightly displaced from their ideal positions. Characteristic for spectroscopy, the two modes do not couple to the mechanical excitation equally well. The degree of coupling is quantified by an oscillator strength. Because the rocking mode mostly exerts a torque (rather than a tangential force, its coupling to the resonator's tangential motion is weak; the oscillator strength consequently is small. Recent experiments on surface-adsorbed colloidal spheres can be explained by the mode of vibration being of the rocking type. Keywords: Quartz crystal microbalance, Coupled resonance, Biocolloids, Adsorption

  19. Performance of surface and subsurface flow constructed wetlands treating eutrophic waters.

    Science.gov (United States)

    Hernández-Crespo, C; Gargallo, S; Benedito-Durá, V; Nácher-Rodríguez, Beatriz; Rodrigo-Alacreu, M A; Martín, M

    2017-10-01

    Three medium size constructed wetlands (CWs) with a total surface of 90ha are working since 2009 in the Albufera de Valencia Natural Park (Spain). Two of them are fed with eutrophic waters from l'Albufera Lake. Their objectives are both reduce the phytoplankton biomass and increase the biodiversity; consequently, improved water quality is returned to the lake. A "science based governance" of these CWs is ongoing inside the LIFE+12 Albufera Project to demonstrate the environmental benefits of these features. In this paper, results and relationships among hydraulic operation, physicochemical variables and plankton in two different CWs typologies, five free water surface CW (FWSCW) and one horizontal subsurface flow CW (HSSFCW), were analysed showing that CWs were capable of improving the water quality and biodiversity but showing clear differences depending on the CW type. The CWs worked under different hydraulic load rates (HLR) from <0.12 to 54.75myr -1 . Inflow water quality was typical from eutrophic waters with mean values of chlorophyll a (Chl a) about 22-90μgChlal -1 and mean total phosphorus (TP) between 0.122 and 0.337mgl -1 . The main conclusion is that HSSFCW was much more efficient than FWSCW in the removal of organic matter, suspended solids and nutrients. The biological role of several shallow lagoons located at the end of the CWs has also been evaluated, showing that they contribute to increase the zooplankton biomass, a key factor to control the phytoplankton blooms. Copyright © 2017 Elsevier B.V. All rights reserved.

  20. Restoring tides to reduce methane emissions in impounded wetlands: A new and potent Blue Carbon climate change intervention.

    Science.gov (United States)

    Kroeger, Kevin D; Crooks, Stephen; Moseman-Valtierra, Serena; Tang, Jianwu

    2017-09-20

    Coastal wetlands are sites of rapid carbon (C) sequestration and contain large soil C stocks. Thus, there is increasing interest in those ecosystems as sites for anthropogenic greenhouse gas emission offset projects (sometimes referred to as "Blue Carbon"), through preservation of existing C stocks or creation of new wetlands to increase future sequestration. Here we show that in the globally-widespread occurrence of diked, impounded, drained and tidally-restricted salt marshes, substantial methane (CH 4 ) and CO 2 emission reductions can be achieved through restoration of disconnected saline tidal flows. Modeled climatic forcing indicates that tidal restoration to reduce emissions has a much greater impact per unit area than wetland creation or conservation to enhance sequestration. Given that GHG emissions in tidally-restricted, degraded wetlands are caused by human activity, they are anthropogenic emissions, and reducing them will have an effect on climate that is equivalent to reduced emission of an equal quantity of fossil fuel GHG. Thus, as a landuse-based climate change intervention, reducing CH 4 emissions is an entirely distinct concept from biological C sequestration projects to enhance C storage in forest or wetland biomass or soil, and will not suffer from the non-permanence risk that stored C will be returned to the atmosphere.

  1. Restoring tides to reduce methane emissions in impounded wetlands: A new and potent Blue Carbon climate change intervention

    Science.gov (United States)

    Kroeger, Kevin D.; Crooks, Stephen; Moseman-Valtierra, Serena; Tang, Jianwu

    2017-01-01

    Coastal wetlands are sites of rapid carbon (C) sequestration and contain large soil C stocks. Thus, there is increasing interest in those ecosystems as sites for anthropogenic greenhouse gas emission offset projects (sometimes referred to as “Blue Carbon”), through preservation of existing C stocks or creation of new wetlands to increase future sequestration. Here we show that in the globally-widespread occurrence of diked, impounded, drained and tidally-restricted salt marshes, substantial methane (CH4) and CO2 emission reductions can be achieved through restoration of disconnected saline tidal flows. Modeled climatic forcing indicates that tidal restoration to reduce emissions has a much greater impact per unit area than wetland creation or conservation to enhance sequestration. Given that GHG emissions in tidally-restricted, degraded wetlands are caused by human activity, they are anthropogenic emissions, and reducing them will have an effect on climate that is equivalent to reduced emission of an equal quantity of fossil fuel GHG. Thus, as a landuse-based climate change intervention, reducing CH4 emissions is an entirely distinct concept from biological C sequestration projects to enhance C storage in forest or wetland biomass or soil, and will not suffer from the non-permanence risk that stored C will be returned to the atmosphere.

  2. Tailored lithium storage performance of graphene aerogel anodes with controlled surface defects for lithium-ion batteries

    International Nuclear Information System (INIS)

    Shan, Hui; Xiong, Dongbin; Li, Xifei; Sun, Yipeng; Yan, Bo; Li, Dejun; Lawes, Stephen; Cui, Yanhua; Sun, Xueliang

    2016-01-01

    Graphical abstract: - Highlights: • The graphene aerogel (GA) with controllable surface defects was synthesized. • The graphene aerogel anodes showed high specific capacity and excellent cyclability. • Surface defects on the GA significantly function for lithium storage. • This study can extend the application of the graphene anodes for LIBs. - Abstract: Three dimensional self-assembled graphene aerogel (GA) anode materials with some surface defects have been successfully generated through a facile hydrothermal procedure using graphene oxide as precursor. The morphologies and textural properties of as-obtained GA were investigated by scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, Raman and other spectroscopy techniques. The surface defects and electrical conductivities of GA can be controlled by adjusting the hydrothermal reaction time. The results indicate that GA with a reaction time of 6 h exhibits extremely high reversible capacity (1430 mAh g"−"1 at the current density of 100 mA g"−"1) and superior rate capability (587 mAh g"−"1 at 800 mA g"−"1) with excellent cycling stability (maintaining a reversible capacity of 960 mAh g"−"1 at 100 mA g"−"1 after 100 cycles). It is demonstrated that the 3D porous network with increased defect density, as well as the considerable electrical conductivity, results in the excellent electrochemical performance of the as-made GA anodes in lithium-ion batteries.

  3. Influence of Different Surface Modifications on the Photovoltaic Performance and Dark Current of Dye-Sensitized Solar Cells

    Institute of Scientific and Technical Information of China (English)

    XU Weiwei; DAI Songyuan; HU Linhua; ZHANG Changneng; XIAO Shangfeng; LUO Xiangdong; JING Weiping; WANG Kongjia

    2007-01-01

    The TiO2 nanoporous film photoelectrode, as a crucial component of dye-sensitized solar cells, has been investigated. The photovoltaic properties and the dark current were studied by two surface modification methods. One was to apply a compact layer between the conductive glass substrate and nanoporous TiO2 film. Another was to produce TiO2 nanoparticles among the microstructure by TiCU treatment. A suitable concentration and number of times for TiCU treatment were found in our experiment. The dark current is suppressed by surface modifications, leading to a significant improvement in the solar cells performance. An excessive concentration of TiCU will produce more surface states and introduce a larger dark current reversely. The dye is also regarded as a source of charge recombination in dark to some extent, due to an amount of surface protonations introduced by the interfacial link in the conductive glass substrate/dye interface and dye/TiO2 interface.

  4. Liquid lens with double tunable surfaces for large power tunability and improved optical performance

    International Nuclear Information System (INIS)

    Li, Lei; Wang, Qiong-Hua; Jiang, Wei

    2011-01-01

    In this paper we propose a liquid lens with two tunable interfaces formed by two kinds of immiscible liquids. The proposed liquid lens uses liquid pressure to change the shape of the interfaces. It can provide a large tunable range of optical power and improved optical performance. By applying suitable liquids the gravity effect can also be negligible. To prove the principles, a liquid lens with 7 mm aperture was fabricated. The optical performance indicates that the proposed liquid lens can provide a large tunable range of both positive and negative powers even using liquids with small differences in refractive indices. The resolution is better than 50 lp mm −1 under white light environment. The spherical aberration and coma are also largely reduced. The proposed liquid lens can also provide the optical designer with the freedom to choose the combination of liquids to reduce or even correct aberrations

  5. Better Organic Ternary Memory Performance through Self-Assembled Alkyltrichlorosilane Monolayers on Indium Tin Oxide (ITO) Surfaces.

    Science.gov (United States)

    Hou, Xiang; Cheng, Xue-Feng; Zhou, Jin; He, Jing-Hui; Xu, Qing-Feng; Li, Hua; Li, Na-Jun; Chen, Dong-Yun; Lu, Jian-Mei

    2017-11-16

    Recently, surface engineering of the indium tin oxide (ITO) electrode of sandwich-like organic electric memory devices was found to effectively improve their memory performances. However, there are few methods to modify the ITO substrates. In this paper, we have successfully prepared alkyltrichlorosilane self-assembled monolayers (SAMs) on ITO substrates, and resistive random access memory devices are fabricated on these surfaces. Compared to the unmodified ITO substrates, organic molecules (i.e., 2-((4-butylphenyl)amino)-4-((4-butylphenyl)iminio)-3-oxocyclobut-1-en-1-olate, SA-Bu) grown on these SAM-modified ITO substrates have rougher surface morphologies but a smaller mosaicity. The organic layer on the SAM-modified ITO further aged to eliminate the crystalline phase diversity. In consequence, the ternary memory yields are effectively improved to approximately 40-47 %. Our results suggest that the insertion of alkyltrichlorosilane self-assembled monolayers could be an efficient method to improve the performance of organic memory devices. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  6. Studies on Gas Sensing Performance of Pure and Surface Modified SrTiO3 Thick Film Resistors

    Directory of Open Access Journals (Sweden)

    V. B. Gaikwad

    2009-08-01

    Full Text Available Strontium Titanate (SrTiO3 (ST was prepared mechanochemically from Sr(OH2 and TiO2. XRD confirms the Perovskite phase of material. Thick films of ST were prepared by screen-printing technique. The gas sensing performances of thick films were tested for various gases. It showed maximum sensitivity to CO gas at 350 oC for 100 ppm gas concentration. To improve the sensitivity and selectivity of the film towards a particular gas, ST thick films were surface modified by dipping them in a solution of nano copper for different intervals of time. These surface modified ST films showed larger sensitivity to H2S gas (100 ppm at 300 oC than pure ST film. A systematic study, of sensing performance of the sensor, indicates the key role-played by the nano copper species on the surface .The sensitivity, selectivity, response and recovery time of the sensor were measured and presented.

  7. Synthesis and electrochemical performance of surface-modified nano-sized core/shell tin particles for lithium ion batteries

    International Nuclear Information System (INIS)

    Schmuelling, Guido; Meyer, Hinrich-Wilhelm; Placke, Tobias; Winter, Martin; Oehl, Nikolas; Knipper, Martin; Kolny-Olesiak, Joanna; Plaggenborg, Thorsten; Parisi, Jürgen

    2014-01-01

    Tin is able to lithiate and delithiate reversibly with a high theoretical specific capacity, which makes it a promising candidate to supersede graphite as the state-of-the-art negative electrode material in lithium ion battery technology. Nevertheless, it still suffers from poor cycling stability and high irreversible capacities. In this contribution, we show the synthesis of three different nano-sized core/shell-type particles with crystalline tin cores and different amorphous surface shells consisting of SnO x and organic polymers. The spherical size and the surface shell can be tailored by adjusting the synthesis temperature and the polymer reagents in the synthesis, respectively. We determine the influence of the surface modifications with respect to the electrochemical performance and characterize the morphology, structure, and thermal properties of the nano-sized tin particles by means of high-resolution transmission electron microscopy, x-ray diffraction, and thermogravimetric analysis. The electrochemical performance is investigated by constant current charge/discharge cycling as well as cyclic voltammetry. (paper)

  8. The political economy of regulation: Investigation of the relationship between design and performance standards in surface coal mining

    International Nuclear Information System (INIS)

    Walker, K.R.

    1991-01-01

    Research concerning political and economic regulatory policy was conducted on 15 randomly selected surface coal mines in Tennessee. Data on violations were collected over a 6-year period from 1979 through 1984. The primary purpose of this study was to investigate the approaches of the Carter and Reagan administrations concerning the implementation of design and performance regulations of Public Law 95-87. The study concluded that: (1) A change in political administration affects regulatory policy concerning enforcement practices. (2) Regulatory policy is altered in the direction of economic activity believed by an administration to be desirable to society and its constituents. (3) Elaborate rule making activity constrains market activity. (4) The coupling of design and performance standards should be retained. No difference was found in the number of violations for design and associated performance standards. Findings support the theory that it is the administration that affects change in regulatory policy, and not the regulatory construct for compliance with a mandate

  9. Electrical Performance of Distribution Insulators with Chlorella vulgaris Growth on its Surface

    Directory of Open Access Journals (Sweden)

    Herbert Enrique Rojas Cubides

    2015-06-01

    Full Text Available This paper presents a study about electrical performance of ceramic and polymeric insulators bio-contaminated with alga Chlorella vulgaris. The performed tests involve ANSI 55-2 and ANSI 52-1 ceramic insulators and ANSI DS-15 polymeric insulators, all of them used in distribution systems of Colombia. Biological contamination of insulators is realized using a controlled environment chamber that adjusts the temperature, humidity and light radiation. The laboratory tests include measurements of flashover voltages and leakage currents and they were performed to determine how insulators are affected by biological contamination. After a series of laboratory tests, it was concluded that the presence of Chlorella vulgaris on the contaminated ceramic insulators reduces the wet flashover voltage up to 12% and increases their leakage currents up to 80%. On the other hand, for polymeric insulators the effect of algae growth on flashover voltages was not to strong, although the leakage currents increase up to 60%.

  10. Increased cathode performance using a thin film LSM layer on a structured 8YSZ electrolyte surface

    Energy Technology Data Exchange (ETDEWEB)

    Herbstritt, D.; Weber, A.; Ivers-Tiffee, E. [Karlsruhe Univ. (T.H.) (DE). Inst. fuer Werkstoffkunde der Elektrotechnik (IWE); Guntow, U.; Mueller, G. [Fraunhofer-Institut fuer Silicatforschung (ISC), Wuerzburg (Germany)

    2000-07-01

    A considerable part of the power losses in a SOFC single cell occurs due to the polarization resistance of the cathode/electrolyte interface. The resulting high cathodic overvoltage corresponds to an enhanced degradation of the cell. In case of a screen printed LSM cathode layer (LSM: La{sub 1-x}Sr{sub x}MnO{sub 3}) on a YSZ electrolyte substrate (YSZ: Y{sub 2}O{sub 3} stabilised ZrO{sub 2}) the cathodic reaction is generally assumed to be restricted to the three phase boundary (tpb) between cathode, oxidant and the electrolyte surface. The electrochemical active area was increased by a modification of the cathode/electrolyte interface. Single cells with a thin film LSM layer on a structured 8YSZ electrolyte showed a power output of about 0.95 W/cm{sup 2} at 0.7 V cell voltage (950 C; oxidant: air, 0.7 1/min; fuel: hydrogen, 0.5 1/min, 15% fuel utilization). (orig.)

  11. Performance of Grass Filter Strip in Copper and Zinc Removal in Surface and Subsurface Runoff

    Directory of Open Access Journals (Sweden)

    Huo Weijie

    2017-01-01

    Full Text Available Three filter strips were conducted on self-designed soil bins. Taking a filter strip with no vegetation as contrast, the effectiveness of vegetation and soil conditions on heavy metals (including copper and zinc removal efficiencies were investigated by simulated runoff experiment. The results showed that the adsorbed state is the main existing form of heavy metal. For surface runoff, most of total copper and total zinc are trapped in first 4m and it is ineffective to increase the distance beyond 4m for removal. Vegetation has no significant effect on total copper and total zinc removal, while the soil with higher content of organic matter is contributing to total Zn interception. For subsurface runoff, the removal efficiencies of total copper and total zinc can reach to above 95.38% and both vegetation and soil conditions have no significant effects. Vegetation is contributing to copper ion and zinc ion removal significantly. Soil condition is only a significant factor to zinc ion, with higher content of organic matter as a contributing factor.

  12. High-performance wearable supercapacitors fabricated with surface activated continuous filament graphite fibers

    Science.gov (United States)

    Jia, Dedong; Yu, Xin; Chen, Tinghan; Wang, Shu; Tan, Hua; Liu, Hong; Wang, Zhong Lin; Li, Linlin

    2017-08-01

    Generally, carbon or graphite fibers (GFs) are used as the supporting materials for the preparation of flexible supercapacitors (SCs) by assembling various electrochemically active nanomaterials on them. A facile and rapid electrochemical oxidation method with a voltage of 3 V in a mixed H2SO4-HNO3 solution for 2-15 min is proposed to active continuous filament GFs. Detailed structural characterization, SEM, TEM, XRD, Raman and XPS demonstrate that the GFs-8 (oxidized for 8 min) possessing high specific surface area which provided numerous electrochemical sites and a large number of oxygen-containing functional groups producing pseudocapacitance. Cyclic voltammetric (CV), galvanostatic charge-discharge measurements and electrochemical impedance spectroscopy (EIS) are conducted to test the capacitive of GFs and activated GFs. The capacitance of GFs-8 reaches as high as 570 mF cm-1 at the current density of 1 mA cm-1 in LiCl electrolyte, a 1965-fold enhancement with respect to the pristine GFs (0.29 mF cm-1). The fabricated fiber solid-state supercapacitors (SSCs) provide high energy density of 0.68 mWh cm-3 at the power density 3.3 W cm-3 and have excellent durability with 90% capacitance retention after 10000 cycles. In addition, such fiber SSCs features flexibility and mechanical stability, which may have wide applications in wearable electronic devices.

  13. Antibacterial performance of polypropylene nonwoven fabric wound dressing surfaces containing passive and active components

    Energy Technology Data Exchange (ETDEWEB)

    Xin, Zhirong, E-mail: xinzhirong2012@126.com [School of Chemistry and Chemical Engineering, Yantai University, Yantai 264005 (China); Du, Shanshan; Zhao, Chunyu; Chen, Hao; Sun, Miao [School of Chemistry and Chemical Engineering, Yantai University, Yantai 264005 (China); Yan, Shunjie [State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022 (China); University of Chinese Academy of Sciences, Beijing 100049 (China); Luan, Shifang, E-mail: sfluan@ciac.ac.cn [State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022 (China); Yin, Jinghua [State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022 (China)

    2016-03-01

    Graphical abstract: - Highlights: • PNVP and PHMG components were covalently immobilized on PP{sub NWF} surface. • PP{sub NWF}-g-PNVP-PHMG possessed bacterial adhesion-resistant and bactericidal capabilities. • PP{sub NWF}-g-PNVP-PHMG obviously suppressed platelet and red blood cell adhesion. - Abstract: A growing number of wound dressing-related nosocomial infections necessitate the development of novel antibacterial strategies. Herein, polypropylene non-woven fabric (PP{sub NWF}) was facilely modified with passive and active antibacterial components, namely photografting polymerization both N-Vinyl-2-pyrrolidone (NVP) and glycidyl methacrylate (GMA) monomers, and the introduction of guanidine polymer through the reaction between active amino groups and epoxy groups. The modified samples were confirmed by attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR), X-ray photoelectron spectroscopy (XPS), respectively. Water contact angle measurement, antibacterial test, platelet and red blood cell adhesion were used to evaluate the hydrophilicity, antibacterial properties and hemocompatibility of the samples. It was found that the antibacterial properties were obviously enhanced, meanwhile significantly suppressing platelet and red blood cell adhesion after the above modification. This PP{sub NWF} samples that possess antifouling and antimicrobial properties, have great potential in wound dressing applications.

  14. Antibacterial performance of polypropylene nonwoven fabric wound dressing surfaces containing passive and active components

    International Nuclear Information System (INIS)

    Xin, Zhirong; Du, Shanshan; Zhao, Chunyu; Chen, Hao; Sun, Miao; Yan, Shunjie; Luan, Shifang; Yin, Jinghua

    2016-01-01

    Graphical abstract: - Highlights: • PNVP and PHMG components were covalently immobilized on PP_N_W_F surface. • PP_N_W_F-g-PNVP-PHMG possessed bacterial adhesion-resistant and bactericidal capabilities. • PP_N_W_F-g-PNVP-PHMG obviously suppressed platelet and red blood cell adhesion. - Abstract: A growing number of wound dressing-related nosocomial infections necessitate the development of novel antibacterial strategies. Herein, polypropylene non-woven fabric (PP_N_W_F) was facilely modified with passive and active antibacterial components, namely photografting polymerization both N-Vinyl-2-pyrrolidone (NVP) and glycidyl methacrylate (GMA) monomers, and the introduction of guanidine polymer through the reaction between active amino groups and epoxy groups. The modified samples were confirmed by attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR), X-ray photoelectron spectroscopy (XPS), respectively. Water contact angle measurement, antibacterial test, platelet and red blood cell adhesion were used to evaluate the hydrophilicity, antibacterial properties and hemocompatibility of the samples. It was found that the antibacterial properties were obviously enhanced, meanwhile significantly suppressing platelet and red blood cell adhesion after the above modification. This PP_N_W_F samples that possess antifouling and antimicrobial properties, have great potential in wound dressing applications.

  15. Performance of engineered barriers materials in near surface disposal facilities in Spain. Appendix 11: Spain

    International Nuclear Information System (INIS)

    Zuloaga, P.

    2001-01-01

    In October 1992 the Ministry of Industry and Energy issued the Operating License of El Cabril Near Surface Disposal Facility, in the province of Cordoba, some 100 km away from Cordoba city. Waste packages, mainly 0.22 m 3 steel drums, containing solidified waste in a cement based waste form or pellets coming from the super-compaction process, are placed inside concrete disposal containers. These containers are made of reinforced concrete and in their construction fabrication joints have been avoided. Once these containers are filled with 18 drums (0.22 m 3 ) or 30 to 60 compaction pellets, they are backfilled and sealed with a mortar grout, resulting into a solid block. These blocks are then disposed of inside concrete vaults, called disposal cells, each one with a capacity for 320 containers. The full vaults are backfilled with gravel in the existing central gap left to absorb fabrication and handling tolerances. Then a plastic film is placed on the containers to prevent a true union between the last layer of disposal containers and the massed concrete layer cast to protect the workers during the construction of the closing slab. This 0.5 m thick closing slab is made of reinforced concrete and is protected by acrylic/fibreglass unperceived film. Galleries are made of a 300 kg/cm 2 characteristic strength concrete

  16. Selenium fuel: Surface engineering of U(Mo) particles to optimise fuel performance

    International Nuclear Information System (INIS)

    Van den Berghe, S.; Leenaers, A.; Detavernier, C.

    2010-01-01

    Recent developments on the stabilisation of U(Mo) in-pile behaviour in plate-type fuel have focussed almost exclusively on the addition of Si to the Al matrix of the fuel. This has now culminated in a qualification effort in the form of the European LEONIDAS initiative for which irradiations will start in 2010. In this framework, many discussions have been held on the Si content of the matrix needed for stabilisation of the interaction phase and the requirement for the formation of Si-rich layers around the particles during the fabrication steps. However, it is clear that the Si needs to be incorporated in the interaction phase for it to be effective, for which the currently proposed methods depend on a diffusion mechanism, which is difficult to control. This has lead to the concept of a Si coated particle as a more efficient way of incorporating the Si in the fuel by putting it immediately where it will be required : at the fuel-matrix interface. As part of the SELENIUM (Surface Engineered Low ENrIched Uranium-Molybdenum fuel) project, SCK CEN has built a sputter coater for PVD magnetron sputter coating of particles in collaboration with the University of Ghent. The coater is equipped with three 3 inch magnetron sputter heads, allowing deposition of 3 different elements or a single element at high deposition speed. The particles are slowly rotated in a drum to produce homogeneous layer thicknesses. (author)

  17. Analysis of the performance of interferometry, surface plasmon resonance and luminescence as biosensors and chemosensors

    International Nuclear Information System (INIS)

    Ince, R.; Narayanaswamy, R.

    2006-01-01

    Sensitivity, dynamic range and resolution have been calculated and compared from a range of analytes sensed in the literature using the techniques of interferometry, surface plasmon resonance (SPR) and luminescence. A detailed explanation of the physical and chemical/biological properties required of optical sensors is included along with the principle of operation of the sensors. Theoretical sensitivities of interferometry and SPR are also detailed along with parameters affecting these sensitivities. In the literature discussed in this review paper, the technique of luminescence, which relies intrinsically on 'labelling', offers the best resolutions for sensing of biomolecules (protein and DNA). Interference techniques offer the best resolutions for low molecular weight chemical liquids/vapours. Techniques which are 'label-free' are often desirable and it is demonstrated here that by combining the techniques of SPR with interferometry, it is possible to sense proteins with a resolution similar to that of luminescence. The future of chemo- and bio-sensing is discussed in terms of potential for multi-channel analysis, their continuous miniaturisation and their impending nanotechnology revolution

  18. Response surface methodology for sensitivity and uncertainty analysis: performance and perspectives

    International Nuclear Information System (INIS)

    Olivi, L.; Brunelli, F.; Cacciabue, P.C.; Parisi, P.

    1985-01-01

    Two main aspects have to be taken into account in studying a nuclear accident scenario when using nuclear safety codes as an information source. The first one concerns the behavior of the code response and the set of assumptions to be introduced for its modelling. The second one is connected with the uncertainty features of the code input, often modelled as a probability density function (pdf). The analyst can apply two well-defined approaches depending on whether he wants major emphasis put on either of the aspects. Response Surface Methodology uses polynomial and inverse polynomial models together with the theory of experimental design, expressly developed for the identification procedure. It constitutes a well-established body of techniques able to cover a wide spectrum of requirements, when the first aspect plays the crucial role in the definition of the objectives. Other techniques such as Latin hypercube sampling, stratified sampling or even random sampling can fit better, when the second aspect affects the reliability of the analysis. The ultimate goal for both approaches is the selection of the variable, i.e. the identification of the code input variables most effective on the output and the uncertainty propagation, i.e. the assessment of the pdf to be attributed to the code response. The main aim of this work is to present a sensitivity analysis method, already tested on a real case, sufficiently flexible to be applied in both approaches mentioned

  19. Radiative cooling test facility and performance evaluation of 4-MIL aluminized polyvinyl fluoride and white-paint surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Kruskopf, M.S.; Berdahl, P.; Martin, M.; Sakkal, F.; Sobolewski, M.

    1980-11-01

    A test facility designed to measure the amount of radiative cooling a specific material or assembly of materials will produce when exposed to the sky is described. Emphasis is placed upon assemblies which are specifically designed to produce radiative cooling and which therefore offer promise for the reduction of temperatures and/or humidities in occupied spaces. The hardware and software used to operate the facility are documented and the results of the first comprehensive experiments are presented. A microcomputer-based control/data acquisition system was employed to study the performance of two prototype radiator surfaces: 4-mil aluminized polyvinyl fluoride (PVF) and white painted surfaces set below polyethylene windscreens. The cooling rates for materials tested were determined and can be approximated by an equation (given). A computer model developed to simulate the cooling process is presented. (MCW)

  20. What is happening under the surface? Power, conflict and the performance of medical teams.

    Science.gov (United States)

    Janss, Rozemarijn; Rispens, Sonja; Segers, Mien; Jehn, Karen A

    2012-09-01

    The effect of teamwork on team performance is broadly recognised in the medical field. This recognition is manifested in educational programmes in which attention to interpersonal behaviours during teamwork is growing. Conflict and power differences influence interpersonal behaviours and are marked topics in studies of group functioning in the social and organisational psychology literature. Insights from the domain of social sciences put the ongoing improvement of teamwork into broader perspective. This paper shows how knowledge from the domain of social and organisational psychology contributes to the understanding of teamwork in the medical environment. More specifically, this paper suggests that unfolding the underlying issues of power and conflict within medical teams can be of extra help in the development of educational interventions aimed at improving team performance. We review the key social psychology and organisational behaviour literature concerning power and conflict, and relate the insights derived from this to the team process of ad hoc medical action teams. We present a theoretical framework in which insights into power and conflict are used to explain and predict team dynamics in ad hoc medical action teams. Power and conflict strongly influence interpersonal behaviour. Characteristics of medical action teams give rise to all kinds of issues of disagreement and are accompanied by complex issues of intra-team power distribution. We argue that how team members coordinate, cooperate and communicate is steered by members' personal motivations, which, in turn, strongly depend on their perceptions of power and conflict. Given the importance of the performance of these teams, we suggest future directions for the development of training interventions building on knowledge and theories derived from social and organisational psychology. © Blackwell Publishing Ltd 2012.

  1. Performance assessment and microbial diversity of two pilot scale multi-stage sub-surface flow constructed wetland systems.

    Science.gov (United States)

    Babatunde, A O; Miranda-CasoLuengo, Raul; Imtiaz, Mehreen; Zhao, Y Q; Meijer, Wim G

    2016-08-01

    This study assessed the performance and diversity of microbial communities in multi-stage sub-surface flow constructed wetland systems (CWs). Our aim was to assess the impact of configuration on treatment performance and microbial diversity in the systems. Results indicate that at loading rates up to 100gBOD5/(m(2)·day), similar treatment performances can be achieved using either a 3 or 4 stage configuration. In the case of phosphorus (P), the impact of configuration was less obvious and a minimum of 80% P removal can be expected for loadings up to 10gP/(m(2)·day) based on the performance results obtained within the first 16months of operation. Microbial analysis showed an increased bacterial diversity in stage four compared to the first stage. These results indicate that the design and configuration of multi-stage constructed wetland systems may have an impact on the treatment performance and the composition of the microbial community in the systems, and such knowledge can be used to improve their design and performance. Copyright © 2016. Published by Elsevier B.V.

  2. Preparation and Evaluation of Surface Modified Lactose Particles for Improved Performance of Fluticasone Propionate Dry Powder Inhaler.

    Science.gov (United States)

    Singh, Deepak J; Jain, Rajesh R; Soni, P S; Abdul, Samad; Darshana, Hegde; Gaikwad, Rajiv V; Menon, Mala D

    2015-08-01

    Dry powder inhalers (DPI) are generally formulated by mixing micronized drug particles with coarse lactose carrier particles to assist powder handling during the manufacturing and powder aerosol delivery during patient use. In the present study, surface modified lactose (SML) particles were produced using force control agents, and their in vitro performance on dry powder inhaler (DPI) formulation of Fluticasone propionate was stu