Baryonic forces and hyperons in nuclear matter from SU(3) chiral effective field theory

Energy Technology Data Exchange (ETDEWEB)

Petschauer, Stefan Karl

2016-02-12

In this work the baryon-baryon interaction is studied at next-to-leading order in SU(3) chiral effective field theory and applied to hyperon-nucleon scattering. The properties of hyperons in isospin-symmetric as well as asymmetric nuclear matter are calculated within the Bruecker-Hartree-Fock formalism. Moreover, the leading three-baryon interaction is derived and its low-energy constants are estimated from decuplet intermediate states. We conclude, that chiral effective field theory is a well-suited tool to describe the baryonic forces.

Baryon axial-vector couplings and SU(3)-symmetry breaking in chiral quark models

International Nuclear Information System (INIS)

Horvat, D.; Ilakovac, A.; Tadic, D.

1986-01-01

SU(3)-symmetry breaking is studied in the framework of the chiral bag models. Comparisons are also made with the MIT bag model and the harmonic-oscillator quark model. An important clue for the nature of the symmetry breaking comes from the isoscalar axial-vector coupling constant g/sub A//sup S/ which can be indirectly estimated from the Bjorken sum rules for deep-inelastic scattering. The chiral bag model with two radii reasonably well accounts for the empirical values of g/sub A//sup S/ and of the axial-vector coupling constants measured in hyperon semileptonic decays

Operator realization of the SU(2) WZNW model

International Nuclear Information System (INIS)

Furlan, P.; Hadjiivanov, L.K.; Todorov, I.T.

1996-01-01

Decoupling the chiral dynamics in the canonical approach to the WZNW model requires an extended phase space that includes left and right monodromy variables M and M. Earlier work on the subject, which traced back the quantum group symmetry of the model to the Lie-Poisson symmetry of the chiral symplectic form, left some open questions: - How to reconcile the necessity to set MM -1 =1 (in order to recover the monodromy invariance of the local 2D group valued field g=uu) with the fact the M and M obey different exchange relations? - What is the status of the quantum symmetry in the 2D theory in which the chiral fields u(x-t) and u(x+t) commute? - Is there a consistent operator formalism in the chiral (and the extended 2D) theory in the continuum limit? We propose a constructive affirmative answer to these questions for G=SU(2) by presenting the quantum fields u and u as sums of products of chiral vertex operators and q-Bose creation and annihilation operators. (orig.)

Chiral Quark-Meson model of N and DELTA with vector mesons

International Nuclear Information System (INIS)

Broniowski, W.; Banerjee, M.K.

1985-10-01

Vector mesons rho, A 1 and ω are introduced in the Chiral Quark-Meson Theory (CQMT) of N and Δ. We propose a new viewpoint for developing CQMT from QCD at the mean-field level. The SU(2) x SU(2) chiral Lagrangian incorporates universal coupling. Accordingly, rho is coupled to the conserved isospin current, A to the partially conserved axial-vector current (PCAC), and ω to the conserved baryon current. As a result the only parameter of the model not directly related to experiment is the quark-pion coupling constant. A fully self-consistent mean-field solution to the model is found for fields in the hedgehog ansatz. The vector mesons play a very important role in the system. They contribute significantly to the values of observables and produce a high-quality fit to many data. The classical stability of the system with respect to hedgehog excitations is analyzed through the use of the Quark-Meson RPA equations (QMRPA)

Recent progress in understanding gauge topology, confinement and chiral symmetry breaking

Energy Technology Data Exchange (ETDEWEB)

Larsen, Rasmus, E-mail: rasmus.n.larsen@stonybrook.edu; Shuryak, Edward

2016-12-15

A model of interacting instanton-dyons as the dominant degrees of freedom was used to discuss confinement and chiral symmetry breaking in SU(2). The case without fermions and with two flavors of fermions was discussed. Numerical results show that within this model, both with and without fermions, confinement is induced by the repulsion between dyons of same type, as the density of dyons increase at lower temperature. With fermions, the result of confinement at lower temperature, combined with the increased density made the effective distance between fermionic zero-modes smaller, thus inducing a non-zero chiral condensate, obtained by fitting to a eigenvalue density formula from random matrix theory.

Operator realization of the SU(2) WZNW model

International Nuclear Information System (INIS)

Furlan, P.; Todorov, I.T.

1995-12-01

Decoupling the chiral dynamics in the canonical approach to the WZNW model requires an extended phase space that includes left and right monodromy variables M and M-bar. Earlier work on the subject, which traced back the quantum group symmetry of the model to the Lie-Poisson symmetry of the chiral symplectic form, left some open questions: How to reconcile the necessity to set M M-bar -1 = 1 (in order to recover the monodromy invariance of the local 2D group valued field g = uu-bar) with the fact the M and M-bar obey different exchange relations? What is the status of the quantum symmetry in the 2D theory in which the chiral fields u(x-t) and u-bar(x+t) commute? Is there a consistent operator formalism in the chiral (and the extended 2D) theory in the continuum limit? We propose a constructive affirmative answer to these questions for G = SU(2) by presenting the quantum field u and u-bar as sums of products of chiral vertex operators and q Bose creation and annihilation operators. (author). 17 refs

Hyperons in nuclear matter from SU(3) chiral effective field theory

Energy Technology Data Exchange (ETDEWEB)

Petschauer, Stefan; Kaiser, Norbert [Technische Universitaet Muenchen (Germany); Haidenbauer, Johann [Forschungszentrum Juelich (Germany); Meissner, Ulf G. [Forschungszentrum Juelich (Germany); Universitaet Bonn (Germany); Weise, Wolfram [Technische Universitaet Muenchen (Germany); ECT, Trento (Italy)

2016-07-01

Brueckner theory is used to investigate the properties of hyperons in nuclear matter. The hyperon-nucleon interaction is taken from chiral effective field theory at next-to-leading order with SU(3) symmetric low-energy constants. Furthermore, the underlying nucleon-nucleon interaction is also derived within chiral effective field theory. We present the single-particle potentials of Λ and Σ hyperons in symmetric and asymmetric nuclear matter computed with the continuous choice for intermediate spectra. The results are in good agreement with the empirical information. In particular, our calculation gives a repulsive Σ-nuclear potential and a weak Λ-nuclear spin-orbit force. The splittings among the Σ{sup +}, Σ{sup 0} and Σ{sup -} potentials have a non-linear dependence on the isospin asymmetry which goes beyond the usual parametrization in terms of an isovector Lane potential.

Systematic construction of spin liquids on the square lattice from tensor networks with SU(2) symmetry

Science.gov (United States)

Mambrini, Matthieu; Orús, Román; Poilblanc, Didier

2016-11-01

We elaborate a simple classification scheme of all rank-5 SU(2) spin rotational symmetric tensors according to (i) the onsite physical spin S , (ii) the local Hilbert space V⊗4 of the four virtual (composite) spins attached to each site, and (iii) the irreducible representations of the C4 v point group of the square lattice. We apply our scheme to draw a complete list of all SU(2)-symmetric translationally and rotationally invariant projected entangled pair states (PEPS) with bond dimension D ≤6 . All known SU(2)-symmetric PEPS on the square lattice are recovered and simple generalizations are provided in some cases. More generally, to each of our symmetry class can be associated a (D -1 )-dimensional manifold of spin liquids (potentially) preserving lattice symmetries and defined in terms of D -independent tensors of a given bond dimension D . In addition, generic (low-dimensional) families of PEPS explicitly breaking either (i) particular point-group lattice symmetries (lattice nematics) or (ii) time-reversal symmetry (chiral spin liquids) or (iii) SU(2) spin rotation symmetry down to U(1 ) (spin nematics or Néel antiferromagnets) can also be constructed. We apply this framework to search for new topological chiral spin liquids characterized by well-defined chiral edge modes, as revealed by their entanglement spectrum. In particular, we show how the symmetrization of a double-layer PEPS leads to a chiral topological state with a gapless edge described by a SU (2) 2 Wess-Zumino-Witten model.

Competitive chiral induction in a 2D molecular assembly: Intrinsic chirality versus coadsorber-induced chirality.

Science.gov (United States)

Chen, Ting; Li, Shu-Ying; Wang, Dong; Wan, Li-Jun

2017-11-01

Noncovalently introducing stereogenic information is a promising approach to embed chirality in achiral molecular systems. However, the interplay of the noncovalently introduced chirality with the intrinsic chirality of molecules or molecular aggregations has rarely been addressed. We report a competitive chiral expression of the noncovalent interaction-mediated chirality induction and the intrinsic stereogenic center-controlled chirality induction in a two-dimensional (2D) molecular assembly at the liquid/solid interface. Two enantiomorphous honeycomb networks are formed by the coassembly of an achiral 5-(benzyloxy)isophthalic acid (BIC) derivative and 1-octanol at the liquid/solid interface. The preferential formation of the globally homochiral assembly can be achieved either by using the chiral analog of 1-octanol, ( S )-6-methyl-1-octanol, as a chiral coadsorber to induce chirality to the BIC assembly via noncovalent hydrogen bonding or by covalently linking a chiral center in the side chain of BIC. Both the chiral coadsorber and the intrinsically chiral BIC derivative can act as a chiral seeds to induce a preferred handedness in the assembly of the achiral BIC derivatives. Furthermore, the noncovalent interaction-mediated chirality induction can restrain or even overrule the manifestation of the intrinsic chirality of the BIC molecule and dominate the handedness of the 2D molecular coassembly. This study provides insight into the interplay of intrinsically chiral centers and external chiral coadsorbers in the chiral induction, transfer, and amplification processes of 2D molecular assembly.

Induction of Chirality in Two-Dimensional Nanomaterials: Chiral 2D MoS2 Nanostructures.

Science.gov (United States)

Purcell-Milton, Finn; McKenna, Robert; Brennan, Lorcan J; Cullen, Conor P; Guillemeney, Lilian; Tepliakov, Nikita V; Baimuratov, Anvar S; Rukhlenko, Ivan D; Perova, Tatiana S; Duesberg, Georg S; Baranov, Alexander V; Fedorov, Anatoly V; Gun'ko, Yurii K

2018-02-27

Two-dimensional (2D) nanomaterials have been intensively investigated due to their interesting properties and range of potential applications. Although most research has focused on graphene, atomic layered transition metal dichalcogenides (TMDs) and particularly MoS 2 have gathered much deserved attention recently. Here, we report the induction of chirality into 2D chiral nanomaterials by carrying out liquid exfoliation of MoS 2 in the presence of chiral ligands (cysteine and penicillamine) in water. This processing resulted in exfoliated chiral 2D MoS 2 nanosheets showing strong circular dichroism signals, which were far past the onset of the original chiral ligand signals. Using theoretical modeling, we demonstrated that the chiral nature of MoS 2 nanosheets is related to the presence of chiral ligands causing preferential folding of the MoS 2 sheets. There was an excellent match between the theoretically calculated and experimental spectra. We believe that, due to their high aspect ratio planar morphology, chiral 2D nanomaterials could offer great opportunities for the development of chiroptical sensors, materials, and devices for valleytronics and other potential applications. In addition, chirality plays a key role in many chemical and biological systems, with chiral molecules and materials critical for the further development of biopharmaceuticals and fine chemicals, and this research therefore should have a strong impact on relevant areas of science and technology such as nanobiotechnology, nanomedicine, and nanotoxicology.

On exact correlation functions in SU(N) $ \\mathcal{N}=2 $ superconformal QCD

CERN Document Server

Baggio, Marco; Papadodimas, Kyriakos

2015-01-01

We consider the exact coupling constant dependence of extremal correlation functions of ${\\cal N} = 2$ chiral primary operators in 4d ${\\cal N} = 2$ superconformal gauge theories with gauge group SU(N) and N_f=2N massless fundamental hypermultiplets. The 2- and 3-point functions, viewed as functions of the exactly marginal coupling constant and theta angle, obey the tt* equations. In the case at hand, the tt* equations form a set of complicated non-linear coupled matrix equations. We point out that there is an ad hoc self-consistent ansatz that reduces this set of partial differential equations to a sequence of decoupled semi-infinite Toda chains, similar to the one encountered previously in the special case of SU(2) gauge group. This ansatz requires a surprising new non-renormalization theorem in ${\\cal N} = 2$ superconformal field theories. We derive a general 3-loop perturbative formula for 2- and 3-point functions in the ${\\cal N} = 2$ chiral ring of the SU(N) theory, and in all explicitly computed exampl...

The nucleon mass and pion-nucleon sigma term from a chiral analysis of Nf = 2 lattice QCD world data

Directory of Open Access Journals (Sweden)

Alvarez-Ruso L.

2014-03-01

Full Text Available We investigate the pion-mass dependence of the nucleon mass within the covariant SU(2 baryon chiral perturbation theory up to order p4 with and without explicit Δ (1232 degrees of freedom. We fit lattice QCD data from several collaborations for 2 and 2+1 flavor ensembles. Here, we emphasize our Nf = 2 study where the inclusion the Δ (1232 contributions stabilizes the fits. We correct for finite volume and spacing effects, set independently the lattice QCD scale by a Sommer-scale of r0 = 0.493(23 fm and also include one σπN lQCD data point at Mπ ≈ 290 MeV. We obtain low-energy constants of natural size which are compatible with the rather linear pion-mass dependence observed in lattice QCD. We report a value of σπN = 41(5(4 MeV for the 2 flavor case and σπN = 52(3(8 MeV for 2+1 flavors.

Chiral-symmetry restoration in baryon-rich environments

International Nuclear Information System (INIS)

Kogut, J.; Matsuoka, H.; Stone, M.; Wyld, H.W.; Shenker, S.; Shigemitsu, J.; Sinclair, D.K.

1983-04-01

Chiral symmetry restoration in an environment rich in baryons is studied by computer simulation methods in SU(2) and SU(3) gauge theories in the quenched approximation. The basic theory of symmetry restoration as a function of chemical potential is illustrated and the implementation of the ideas on a lattice is made explicit. A simple mean field model is presented to guide one's expectations. The second order conjugate-gradient iterative method and the pseudo-fermion Monte Carlo procedure are convergent methods of calculating the fermion propagator in an environment rich in baryons. Computer simulations of SU(3) gauge theory show an abrupt chiral symmetry restoring transition and the critical chemical potential and induced baryon density are estimated crudely. A smoother transition is observed for the color group SU(2)

SU(2) Chern-Simons theory at genus zero

International Nuclear Information System (INIS)

Gawedzki, K.; Kupiainen, A.

1991-01-01

We present a detailed study of the Schroedinger picture space of states in the SU(2) Chern-Simons topological gauge theory in the simplest geometry. The space coincides with that of the solutions of the chiral Ward identities for the WZW model. We prove that its dimension is given by E. Verlinde's formulae. (orig.)

Two-chiral component microemulsion EKC - chiral surfactant and chiral oil. Part 2: diethyl tartrate.

Science.gov (United States)

Kahle, Kimberly A; Foley, Joe P

2007-08-01

In this second study on dual-chirality microemulsions containing a chiral surfactant and a chiral oil, a less hydrophobic and lower interfacial tension chiral oil, diethyl tartrate, is employed (Part 1, Foley, J. P. et al.., Electrophoresis, DOI: 10.1002/elps.200600551). Six stereochemical combinations of dodecoxycarbonylvaline (DDCV: R, S, or racemic, 2.00% w/v), racemic 2-hexanol (1.65% v/v), and diethyl tartrate (D, L, or racemic, 0.88% v/v) were examined as pseudostationary phases (PSPs) for the enantioseparation of six chiral pharmaceutical compounds: pseudoephedrine, ephedrine, N-methyl ephedrine, metoprolol, synephrine, and atenolol. Average efficiencies increased with the addition of a chiral oil to R-DDCV PSP formulations. Modest improvements in resolution and enantioselectivity (alpha(enant)) were achieved with two-chiral-component systems over the one-chiral-component microemulsion. Slight enantioselective synergies were confirmed using a thermodynamic model. Results obtained in this study are compared to those obtained in Part 1 as well as those obtained with chiral MEEKC using an achiral, low-interfacial-tension oil (ethyl acetate). Dual-chirality microemulsions with the more hydrophobic oil dibutyl tartrate yielded, relative to diethyl tartrate, higher efficiencies (100,000-134,000 vs. 80,800-94,300), but lower resolution (1.64-1.91 vs. 2.08-2.21) due to lower enantioselectivities (1.060-1.067 vs. 1.078-1.081). Atenolol enantiomers could not be separated with the dibutyl tartrate-based microemulsions but were partially resolved using diethyl tartrate microemulsions. A comparable single-chirality microemulsion based on the achiral oil ethyl acetate yielded, relative to diethyl tartrate, lower efficiency (78 300 vs. 91 600), higher resolution (1.99 vs. 1.83), and similar enantioselectivities.

The baryon vector current in the combined chiral and 1/Nc expansions

Energy Technology Data Exchange (ETDEWEB)

Flores-Mendieta, Ruben; Goity, Jose L [JLAB

2014-12-01

The baryon vector current is computed at one-loop order in large-Nc baryon chiral perturbation theory, where Nc is the number of colors. Loop graphs with octet and decuplet intermediate states are systematically incorporated into the analysis and the effects of the decuplet-octet mass difference and SU(3) flavor symmetry breaking are accounted for. There are large-Nc cancellations between different one-loop graphs as a consequence of the large-Nc spin-flavor symmetry of QCD baryons. The results are compared against the available experimental data through several fits in order to extract information about the unknown parameters. The large-Nc baryon chiral perturbation theory predictions are in very good agreement both with the expectations from the 1/Nc expansion and with the experimental data. The effect of SU(3) flavor symmetry breaking for the |Delta S|=1 vector current form factors f1(0) results in a reduction by a few percent with respect to the corresponding SU(3) symmetric values.

Macdonald index and chiral algebra

Science.gov (United States)

Song, Jaewon

2017-08-01

For any 4d N = 2 SCFT, there is a subsector described by a 2d chiral algebra. The vacuum character of the chiral algebra reproduces the Schur index of the corresponding 4d theory. The Macdonald index counts the same set of operators as the Schur index, but the former has one more fugacity than the latter. We conjecture a prescription to obtain the Macdonald index from the chiral algebra. The vacuum module admits a filtration, from which we construct an associated graded vector space. From this grading, we conjecture a notion of refined character for the vacuum module of a chiral algebra, which reproduces the Macdonald index. We test this prescription for the Argyres-Douglas theories of type ( A 1 , A 2 n ) and ( A 1 , D 2 n+1) where the chiral algebras are given by Virasoro and \\widehat{su}(2) affine Kac-Moody algebra. When the chiral algebra has more than one family of generators, our prescription requires a knowledge of the generators from the 4d.

Mass generation and chiral symmetry breaking by pseudoparticles

International Nuclear Information System (INIS)

Hietarinta, J.; Palmer, W.F.; Pinsky, S.S.

1978-01-01

Massless QCD is studied with regard to mass generation and chiral SU(N/sub f/) symmetry breaking from pseudoparticle effects. While mass is generated when there is only one massless quark, and chiral U(1) is always broken, no rigorous indication of the breaking of chiral SU(N/sub f/) and mass generation is seen when there are more than one massless quarks in the original theory

Chiral perturbation theory approach to hadronic weak amplitudes

International Nuclear Information System (INIS)

Rafael, E. de

1989-01-01

We are concerned with applications to the non-leptonic weak interactions in the sector of light quark flavors: u, d and s. Both strangeness changing ΔS=1 and ΔS=2 non-leptonic transitions can be described as weak perturbations to the strong effective chiral Lagrangian; the chiral structure of the weak effective Lagrangian being dictated by the transformation properties of the weak non-leptonic Hamiltonian of the Standard Model under global SU(3) Left xSU(3) Right rotations of the quark-fields. These lectures are organized as follows. Section 2 gives a review of the basic properties of chiral symmetry. Section 3 explains the effective chiral realization of the non-leptonic weak Hamiltonian of the Standard Model to lowest order in derivatives and masses. Section 4 deals with non-leptonic weak transitions in the presence of electromagnetism. Some recent applications to radiative kaon decays are reviewed and the effect of the so called electromagnetic penguin like diagrams is also discussed. Section 5 explains the basic ideas of the QCD-hadronic duality approach to the evaluation of coupling constants of the non-leptonic chiral weak Lagrangian. (orig./HSI)

Vortex in the chiral quark model

Science.gov (United States)

Hadasz, Leszek

1995-02-01

We construct the classical vortex solution in the model of chiral field interacting with the non-Abelian SU(2) gauge field. This solution is topologically nontrivial and well localized. We discuss its relevance for effective hadron models based on the flux-tube picture and the possibility of its extension to the higher symmetry gauge groups SU(N).

Chiral SU(3) dynamics and antikaon-nuclear quasibound states

International Nuclear Information System (INIS)

Weise, W.; Haertle, R.

2008-01-01

Recent developments are summarised concerning low-energy K-bar N interactions as they relate to the possible existence of antikaon-nuclear quasibound states. An exploratory study of antikaons bound to finite nuclei is performed, with emphasis on the evolution of such states from light to heavy nuclei (A = 16-208). The energy dependent, driving attractive K-bar N interactions are constructed using the s-wave coupled-channel amplitudes involving the Λ(1405) and resulting from chiral SU(3) dynamics, plus p-wave amplitudes dominated by the Σ(1385). Effects of Pauli and short-range correlations are discussed. The decay width induced by K - NN two-body absorption is estimated and found to be substantial. It is concluded that K-bar-nuclear quasibound states can possibly exist with binding energies ranging from 60 to 100 MeV, but with short life times corresponding to decay widths of similar magnitudes

Chiral trace relations in Ω-deformed N=2 theories

Energy Technology Data Exchange (ETDEWEB)

Beccaria, Matteo; Fachechi, Alberto; Macorini, Guido [Dipartimento di Matematica e Fisica Ennio De Giorgi,Università del Salento, Via Arnesano, 73100 Lecce (Italy); INFN - Sezione di LecceVia Arnesano, 73100 Lecce (Italy)

2017-05-04

We consider N=2SU(2) gauge theories in four dimensions (pure or mass deformed) and discuss the properties of the simplest chiral observables in the presence of a generic Ω-deformation. We compute them by equivariant localization and analyze the structure of the exact instanton corrections to the classical chiral ring relations. We predict exact relations valid at all instanton number among the traces 〈Trφ{sup n}〉, where φ is the scalar field in the gauge multiplet. In the Nekrasov-Shatashvili limit, such relations may be explained in terms of the available quantized Seiberg-Witten curves. Instead, the full two-parameter deformation enjoys novel features and the ring relations require non trivial additional derivative terms with respect to the modular parameter. Higher rank groups are briefly discussed emphasizing non-factorization of correlators due to the Ω-deformation. Finally, the structure of the deformed ring relations in the N=2{sup ⋆} theory is analyzed from the point of view of the Alday-Gaiotto-Tachikawa correspondence proving consistency as well as some interesting universality properties.

The spectral density of the QCD Dirac operator and patterns of chiral symmetry breaking

International Nuclear Information System (INIS)

Toublan, D.; Verbaarschot, J.J.M.

1999-01-01

We study the spectrum of the QCD Dirac operator for two colors with fermions in the fundamental representation and for two or more colors with adjoint fermions. For N f flavors, the chiral flavor symmetry of these theories is spontaneously broken according to SU (2N f → Sp (2N f ) and SU (N f → O (N f ), respectively, rather than the symmetry breaking pattern SU (N f ) x SU (N f ) → SU (N f ) for QCD with three or more colors and fundamental fermions. In this paper we study the Dirac spectrum for the first two symmetry breaking patterns. Following previous work for the third case we find the Dirac spectrum in the domain λ QCD by means of partially quenched chiral perturbation theory. In particular, this result allows us to calculate the slope of the Dirac spectrum at λ = 0. We also show that for λ 2 Λ QCD (wing L the linear size of the system) the Dirac spectrum is given by a chiral Random Matrix Theory with the symmetries of the Dirac operator

ɛ '/ ɛ anomaly and neutron EDM in SU(2) L × SU(2) R × U(1) B- L model with charge symmetry

Science.gov (United States)

Haba, Naoyuki; Umeeda, Hiroyuki; Yamada, Toshifumi

2018-05-01

The Standard Model prediction for ɛ '/ ɛ based on recent lattice QCD results exhibits a tension with the experimental data. We solve this tension through W R + gauge boson exchange in the SU(2) L × SU(2) R × U(1) B- L model with `charge symmetry', whose theoretical motivation is to attribute the chiral structure of the Standard Model to the spontaneous breaking of SU(2) R × U(1) B- L gauge group and charge symmetry. We show that {M_W}{_R}study a correlation between ɛ ' /ɛ and the neutron EDM. We confirm that the model can solve the ɛ ' /ɛ anomaly without conflicting the current bound on the neutron EDM, and further reveal that almost all parameter regions in which the ɛ ' /ɛ anomaly is explained will be covered by future neutron EDM searches, which leads us to anticipate the discovery of the neutron EDM.

Chiral anomalies and constraints on the gauge group in higher-dimensional supersymmetric Yang-Mills theories

International Nuclear Information System (INIS)

Townsend, P.K.; Sierra, G.

1983-01-01

Chiral anomalies for gauge theories in any even dimension are computed and the results applied to supersymmetric theories in D=6, 8 and 10. For D=8 there is an anomalous chiral U(1) invariance, just as in D=4, except for certain special groups. For D=6 and D=10 there is no anomalous chiral U(1) symmetry, but the gauge current is anomalous except for certain ''anomaly-free'' groups. For D=6 the group is thereby constrained to be one of [SU(2), SU(3), exceptional], while for D=10 it is constrained to be one of [SU(n)n 8 ]. (orig.)

Hidden QCD in Chiral Gauge Theories

DEFF Research Database (Denmark)

Ryttov, Thomas; Sannino, Francesco

2005-01-01

The 't Hooft and Corrigan-Ramond limits of massless one-flavor QCD consider the two Weyl fermions to be respectively in the fundamental representation or the two index antisymmetric representation of the gauge group. We introduce a limit in which one of the two Weyl fermions is in the fundamental...... representation and the other in the two index antisymmetric representation of a generic SU(N) gauge group. This theory is chiral and to avoid gauge anomalies a more complicated chiral theory is needed. This is the generalized Georgi-Glashow model with one vector like fermion. We show that there is an interesting...... phase in which the considered chiral gauge theory, for any N, Higgses via a bilinear condensate: The gauge interactions break spontaneously to ordinary massless one-flavor SU(3) QCD. The additional elementary fermionic matter is uncharged under this SU(3) gauge theory. It is also seen that when...

Light-flavor sea-quark distributions in the nucleon in the SU(3) chiral quark soliton model. I. Phenomenological predictions

International Nuclear Information System (INIS)

Wakamatsu, M.

2003-01-01

Theoretical predictions are given for the light-flavor sea-quark distributions in the nucleon including the strange quark ones on the basis of the flavor SU(3) version of the chiral quark soliton model. Careful account is taken of the SU(3) symmetry breaking effects due to the mass difference Δm s between the strange and nonstrange quarks, which is the only one parameter necessary for the flavor SU(3) generalization of the model. A particular emphasis of study is put on the light-flavor sea-quark asymmetry as exemplified by the observables d-bar(x)-u-bar(x),d-bar(x)/u-bar(x),Δu-bar(x)-Δd-bar(x) as well as on the particle-antiparticle asymmetry of the strange quark distributions represented by s(x)-s-bar(x),s(x)/s-bar(x),Δs(x)-Δs-bar(x) etc. As for the unpolarized sea-quark distributions, the predictions of the model seem qualitatively consistent with the available phenomenological information provided by the NMC data for d-bar(x)-u-bar(x), the E866 data for d-bar(x)/u-bar(x), the CCFR data and the fit of Barone et al. for s(x)/s-bar(x), etc. The model is shown to give several unique predictions also for the spin-dependent sea-quark distribution, such that Δs(x)<<Δs-bar(x) < or approx. 0 and Δd-bar(x)<0<Δu-bar(x), although the verification of these predictions must await more elaborate experimental investigations in the near future

Instanton induced compactification and fermion chirality

International Nuclear Information System (INIS)

Randjbar-Daemi, S.; Strathdee, J.

1983-07-01

The question of fermion chirality in Kaluza-Klein theories with coupling to Yang-Mills fields is discussed. The argument is illustrated in eight dimensions where an SU(2) Yang-Mills field assumes the 1-instanton form on the internal space. This serves not only to trigger spontaneous compactification of the internal space but will ensure the emergence of nsub(L)-nsub(R)=2/3t(t+1) (2t+1) zero modes in an irreducible 8-spinor belonging to the (2t+1)-dimensional representation of SU(2). (author)

Chiral symmetry and strangeness at SIS energies

International Nuclear Information System (INIS)

Lutz, M.F.M.

2003-11-01

In this talk we review the consequences of the chiral SU(3) symmetry for strangeness propagation in nuclear matter. Objects of crucial importance are the meson-baryon scattering amplitudes obtained within the chiral coupled-channel effective field theory. Results for antikaon and hyperon-resonance spectral functions in cold nuclear matter are presented and discussed. The importance of the Σ(1385) resonance for the subthreshold antikaon production in heavy-ion reaction at SIS is pointed out. The in-medium properties of the latter together with an antikaon spectral function based on chiral SU(3) dynamics suggest a significant enhancement of the π Λ → anti Κ N reaction in nuclear matter. (orig.)

Instantons and chiral symmetry breaking

International Nuclear Information System (INIS)

Carneiro, C.E.I.; McDougall, N.A.

1984-01-01

A detailed investigation of chiral symmetry breaking due to instanton dynamics is carried out, within the framework of the dilute gas approximation, for quarks in both the fundamental and adjoint representations of SU(2). The momentum dependence of the dynamical mass is found to be very similar in each representation. (orig.)

Instantons and chiral symmetry breaking

Energy Technology Data Exchange (ETDEWEB)

Carneiro, C.E.I.; McDougall, N.A. (Oxford Univ. (UK). Dept. of Theoretical Physics)

1984-10-22

A detailed investigation of chiral symmetry breaking due to instanton dynamics is carried out, within the framework of the dilute gas approximation, for quarks in both the fundamental and adjoint representations of SU(2). The momentum dependence of the dynamical mass is found to be very similar in each representation.

The role of resonances in chiral perturbation theory

International Nuclear Information System (INIS)

Ecker, G.; Rafael, E. de

1988-09-01

The strong interactions of low-lying meson resonances (spin ≤ 1) with the octet of pseudoscalar mesons (π,Κ,η) are considered to lowest order in the derivative expansion of chiral SU(3). The resonance contributions to the coupling constants of the O(p 4 ) effective chiral lagrangian involving pseudoscalar fields only are determined. These low-energy coupling constants are found to be dominated by the resonance contributions. Although we do not treat the vector and axial-vector mesons as gauge bosons of local chiral symmetry, vector meson dominance emerges as a prominent result of our analysis. As a further application of chiral resonance couplings, we calculate the electromagnetic pion mass difference to lowest order in chiral perturbation theory with explicit resonance fields. 29 refs., 2 figs., 5 tabs. (Author)

Intersecting branes, Higgs sector, and chirality from N = 4 SYM with soft SUSY breaking

Science.gov (United States)

Sperling, Marcus; Steinacker, Harold C.

2018-04-01

We consider SU( N ) N = 4 super Yang-Mills with cubic and quadratic soft SUSY breaking potential, such that the global SU(4) R is broken to SU(3) or further. As shown recently, this set-up supports a rich set of non-trivial vacua with the geometry of self-intersecting SU(3) branes in 6 extra dimensions. The zero modes on these branes can be interpreted as 3 generations of bosonic and chiral fermionic strings connecting the branes at their intersections. Here, we uncover a large class of exact solutions consisting of branes connected by Higgs condensates, leading to Yukawa couplings between the chiral fermionic zero modes. Under certain decoupling conditions, the backreaction of the Higgs on the branes vanishes exactly. The resulting physics is that of a spontaneously broken chiral gauge theory on branes with fluxes. In particular, we identify combined brane plus Higgs configurations which lead to gauge fields that couple to chiral fermions at low energy. This turns out to be quite close to the Standard Model and its constructions via branes in string theory. As a by-product, we construct a G 2-brane solution corresponding to a squashed fuzzy coadjoint orbit of G 2.

New narrow boson resonances and SU(4) symmetry: Selection rules, SU(4) mixing, and mass formulas

International Nuclear Information System (INIS)

Takasugi, E.; Oneda, S.

1975-01-01

General SU(4) sum rules are obtained for bosons in the theoretical framework of asymptotic SU(4), chiral SU(4) direct-product SU(4) charge algebra, and a simple mechanism of SU(4) and chiral SU(4) direct-product SU(4) breaking. The sum rules exhibit a remarkable interplay of the masses, SU(4) mixing angles, and axial-vector matrix elements of 16-plet boson multiplets. Under a particular circumstance (i.e., in the ''ideal'' limit) this interplay produces selection rules which may explain the remarkable stability of the newly found narrow boson resonances. General SU(4) mass formulas and inter-SU(4) -multiplet mass relations are derived and SU(4) mixing parameters are completely determined. Ground state 1 -- and 0 -+ 16-plets are especially discussed and the masses of charmed and uncharmed new members of these multiplets are predicted

Condensates near the Argyres-Douglas point in SU (2) gauge theory with broken Ν = 2 supersymmetry

International Nuclear Information System (INIS)

Gorsky, A.

2002-01-01

The behaviour of the chiral condensates in the SU(2) gauge theory with broken N = 2 supersymmetry is reviewed. The calculation of monopole, dyon, and charge condensates is described. It is shown that the monopole and charge condensates vanish at the Argyres-Douglas point where the monopole and charge vacua collide. This phenomenon is interpreted as a deconfinement of electric and magnetic charges at the Argyres-Douglas point. (authors)

Scattering lengths in SU(2) gauge theory with two fundamental fermions

DEFF Research Database (Denmark)

Arthur, R.; Drach, V.; Hansen, Martin Rasmus Lundquist

2014-01-01

We investigate non perturbatively scattering properties of Goldstone Bosons in an SU(2) gauge theory with two Wilson fermions in the fundamental representation. Such a theory can be used to build extensions of the Standard Model that unifies Technicolor and pseudo Goldstone composite Higgs models...... the expected chiral symmetry breaking pattern. We then discuss how to compute them on the lattice and give preliminary results using finite size methods....

Chiral model for nucleon and delta

International Nuclear Information System (INIS)

Birse, M.C.; Banerjee, M.K.

1985-01-01

We propose a model of the nucleon and delta based on the idea that strong QCD forces on length scales approx.0.2--1 fm result in hidden chiral SU(2) x SU(2) symmetry and that there is a separation of roles between these forces which are also responsible for binding quarks in hadrons and the forces which produce absolute confinement. This leads us to study a linear sigma model describing the interactions of quarks, sigma mesons, and pions. We have solved this model in the semiclassical (mean-field) approximation for the hedgehog baryon state. We refer to this solution as a chiral soliton. In the semiclassical approximation the hedgehog state is a linear combination of N and Δ. We project this state onto states of good spin and isospin to calculate matrix elements of various operators in these states. Our results are in reasonable agreement with the observed properties of the nucleon. The mesonic contributions to g/sub A/ and sigma(πN) are about two to three times too large, suggesting the need for quantum corrections

Chirality Relay in 2,2'-Substituted 1,1'-Binaphthyl: Access to Propeller Chirality of the Tricoordinate Boron Center.

Science.gov (United States)

Wang, Chen; Sun, Zuo-Bang; Xu, Qing-Wen; Zhao, Cui-Hua

2016-11-14

It is a challenging issue to achieve propeller chirality for triarylboranes owing to the low transition barrier between the P and M forms of the boron center. Herein, we report a new strategy to achieve propeller chirality of triarylboranes. It was found that the chirality relay from axially chiral 1,1'-binaphthyl to propeller chirality of the trivalent boron center can be realized when a Me 2 N and a Mes 2 B group (Mes=mesityl) are introduced at the 2,2'-positions of the 1,1'-binaphthyl skeleton (BN-BNaph) owing to the strong π-π interaction between the Me 2 N-bonded naphthyl ring and the phenyl ring of one adjacent Mes group, which not only exerts great steric hindrance on the rotation of the two Mes groups but also gives unequal stability to the two configurations of the boron center for a given configuration of the binaphthyl moiety. The stereostructures of the boron center were fully characterized through 1 H NMR spectroscopy, X-ray crystal analyses, and theoretical calculations. Detailed comparisons with the analog BN-Ph-BNaph, in which the Mes 2 B group is separated from 1,1'-binaphthyl by a para-phenylene spacer, confirmed the essential role of π-π interaction for the successful chirality relay in BN-BNaph. © 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Spontaneous symmetry breaking and fermion chirality in higher-dimensional gauge theory

International Nuclear Information System (INIS)

Wetterich, C.

1985-01-01

The number of chiral fermions may change in the course of spontaneous symmetry breaking. We discuss solutions of a six-dimensional Einstein-Yang-Mills theory based on SO(12). In the resulting effective four-dimensional theory they can be interpreted as spontaneous breaking of a gauge group SO(10) to H=SU(3)sub(C)xSU(2)sub(L)xU(1)sub(R)xU(1)sub(B-L). For all solutions, the fermions which are chiral with respect to H form standard generations. However, the number of generations for the solutions with broken SO(10) may be different compared to the symmetric solutions. All solutions considered here exhibit a local generation group SU(2)sub(G)xU(1)sub(G). For the solutions with broken SO(10) symmetry, the leptons and quarks within one generation transform differently with respect to SU(2)sub(G)xU(1)sub(G). Spontaneous symmetry breaking also modifies the SO(10) relations among Yukawa couplings. All this has important consequences for possible fermion mass relations obtained from higher-dimensional theories. (orig.)

Chiral ward-Takahashi identities at finite temperature and chiral phase transition in (2+1) dimensional chiral Gross-Neveu model

International Nuclear Information System (INIS)

Shen Kun; Qiu Zhongping

1993-01-01

Chiral Ward-Takahashi identities at finite temperature are derived in (2+1) dimensional chiral Gross-Neveu model. In terms of these identities, fermion mass generation and the mass spectra of bound states are investigate at finite temperature. Taking the fermion mass as an order parameter, the authors discuss the phase structure and chiral phase transition and obtain the critical temperature

Chiral behaviour of the pion decay constant in N{sub f}=2 QCD

Energy Technology Data Exchange (ETDEWEB)

Lottini, Stefano [Deutsches Elektronen-Synchrotron (DESY), Zeuthen (Germany). John von Neumann-Inst. fuer Computing NIC; Collaboration: ALPHA Collaboration

2013-11-15

As increased statistics and new ensembles with light pions have become available within the CLS effort, we complete previous work by inspecting the chiral behaviour of the pion decay constant. We discuss the validity of Chiral Perturbation Theory ({chi}PT) and examine the results concerning the pion decay constant and the ensuing scale setting, the pion mass squared in units of the quark mass, and the ratio of decay constants f{sub K}=f{sub {pi}}; along the way, the relevant low-energy constants of SU(2) {chi}PT are estimated. All simulations were performed with two dynamical flavours of nonperturbatively O(a)-improved Wilson fermions, on volumes with m{sub {pi}}L{>=}4, pion masses{>=}192 MeV and lattice spacings down to 0.048 fm. Our error analysis takes into account the effect of slow modes on the autocorrelations.

Chiral symmetry breaking and the spin content of the ρ and ρ' mesons

International Nuclear Information System (INIS)

Glozman, L.Ya.; Lang, C.B.; Limmer, M.

2011-01-01

Using interpolators with different SU(2) L xSU(2) R transformation properties we study the chiral symmetry and spin contents of the ρ and ρ ' mesons in lattice simulations with dynamical quarks. A ratio of couplings of the q-bar γ i τq and q-bar σ 0i τq interpolators to a given meson state at different resolution scales tells one about the degree of chiral symmetry breaking in the meson wave function at these scales. Using a Gaussian gauge invariant smearing of the quark fields in the interpolators, we are able to extract the chiral content of mesons up to the infrared resolution of ∼1 fm. In the ground state ρ meson the chiral symmetry is strongly broken with comparable contributions of both the (0,1)+(1,0) and (1/2,1/2) b chiral representations with the former being the leading contribution. In contrast, in the ρ ' meson the degree of chiral symmetry breaking is manifestly smaller and the leading representation is (1/2,1/2) b . Using a unitary transformation from the chiral basis to the 2S+1 L J basis, we are able to define and measure the angular momentum content of mesons in the rest frame. This definition is different from the traditional one which uses parton distributions in the infinite momentum frame. The ρ meson is practically a 3 S 1 state with no obvious trace of a 'spin crisis'. The ρ ' meson has a sizeable contribution of the 3 D 1 wave, which implies that the ρ ' meson cannot be considered as a pure radial excitation of the ρ meson.

Disoriented Chiral Condensates in High-Energy Nuclear Collisions

Energy Technology Data Exchange (ETDEWEB)

Randrup, Jorgen

2000-10-18

This brief lecture series discusses how our current understanding of chiral symmetry may be tested more globally in high-energy nuclear collisions by suitable extraction of pionic observables. After briefly recalling the general features of chiral symmetry, we focus on the SU(2) linear sigma model and show how a semi-classical mean-field treatment makes it possible to calculate its statistical properties, including the chiral phase diagram. Subsequently, we consider scenarios of relevance to high-energy collisions and discuss the features of the ensuing non-equilibrium dynamics and the associated characteristic signals. Finally, we illustrate how the presence of vacuum fluctuations or the inclusion of strangeness may affect the results quantitatively.

Covariance fitting of highly-correlated data in lattice QCD

Science.gov (United States)

Yoon, Boram; Jang, Yong-Chull; Jung, Chulwoo; Lee, Weonjong

2013-07-01

We address a frequently-asked question on the covariance fitting of highly-correlated data such as our B K data based on the SU(2) staggered chiral perturbation theory. Basically, the essence of the problem is that we do not have a fitting function accurate enough to fit extremely precise data. When eigenvalues of the covariance matrix are small, even a tiny error in the fitting function yields a large chi-square value and spoils the fitting procedure. We have applied a number of prescriptions available in the market, such as the cut-off method, modified covariance matrix method, and Bayesian method. We also propose a brand new method, the eigenmode shift (ES) method, which allows a full covariance fitting without modifying the covariance matrix at all. We provide a pedagogical example of data analysis in which the cut-off method manifestly fails in fitting, but the rest work well. In our case of the B K fitting, the diagonal approximation, the cut-off method, the ES method, and the Bayesian method work reasonably well in an engineering sense. However, interpreting the meaning of χ 2 is easier in the case of the ES method and the Bayesian method in a theoretical sense aesthetically. Hence, the ES method can be a useful alternative optional tool to check the systematic error caused by the covariance fitting procedure.

Consistency tests of Ampcalculator and chiral amplitudes in SU(3) Chiral Perturbation Theory: A tutorial-based approach

International Nuclear Information System (INIS)

Ananthanarayan, B.; Sentitemsu Imsong, I.; Das, Diganta

2012-01-01

Ampcalculator (AMPC) is a Mathematica copyright based program that was made publicly available some time ago by Unterdorfer and Ecker. It enables the user to compute several processes at one loop (upto O(p 4 )) in SU(3) chiral perturbation theory. They include computing matrix elements and form factors for strong and non-leptonic weak processes with at most six external states. It was used to compute some novel processes and was tested against well-known results by the original authors. Here we present the results of several thorough checks of the package. Exhaustive checks performed by the original authors are not publicly available, and hence the present effort. Some new results are obtained from the software especially in the kaon odd-intrinsic parity non-leptonic decay sector involving the coupling G 27 . Another illustrative set of amplitudes at tree level we provide is in the context of τ-decays with several mesons including quark mass effects, of use to the BELLE experiment. All eight meson-meson scattering amplitudes have been checked. The Kaon-Compton amplitude has been checked and a minor error in the published results has been pointed out. This exercise is a tutorial-based one, wherein several input and output notebooks are also being made available as ancillary files on the arXiv. Some of the additional notebooks we provide contain explicit expressions that we have used for comparison with established results. The purpose is to encourage users to apply the software to suit their specific needs. An automatic amplitude generator of this type can provide error-free outputs that could be used as inputs for further simplification, and in varied scenarios such as applications of chiral perturbation theory at finite temperature, density and volume. This can also be used by students as a learning aid in low-energy hadron dynamics. (orig.)

Chiral symmetry breaking and the spin content of the ρ and ρ‧ mesons

Science.gov (United States)

Glozman, L. Ya.; Lang, C. B.; Limmer, M.

2011-11-01

Using interpolators with different SU(2)L × SU(2)R transformation properties we study the chiral symmetry and spin contents of the ρ and ρ‧ mesons in lattice simulations with dynamical quarks. A ratio of couplings of the qbarγi τq and qbarσ0i τq interpolators to a given meson state at different resolution scales tells one about the degree of chiral symmetry breaking in the meson wave function at these scales. Using a Gaussian gauge invariant smearing of the quark fields in the interpolators, we are able to extract the chiral content of mesons up to the infrared resolution of ∼ 1 fm. In the ground state ρ meson the chiral symmetry is strongly broken with comparable contributions of both the (0 , 1) + (1 , 0) and (1 / 2 , 1 / 2) b chiral representations with the former being the leading contribution. In contrast, in the ρ‧ meson the degree of chiral symmetry breaking is manifestly smaller and the leading representation is (1 / 2 , 1 / 2) b. Using a unitary transformation from the chiral basis to the LJ2S+1 basis, we are able to define and measure the angular momentum content of mesons in the rest frame. This definition is different from the traditional one which uses parton distributions in the infinite momentum frame. The ρ meson is practically a 3S1 state with no obvious trace of a "spin crisis". The ρ‧ meson has a sizeable contribution of the 3D1 wave, which implies that the ρ‧ meson cannot be considered as a pure radial excitation of the ρ meson.

An N = 2 worldsheet approach to D-branes in bihermitian geometries: I. Chiral and twisted chiral fields

International Nuclear Information System (INIS)

Sevrin, Alexander; Staessens, Wieland; Wijns, Alexander

2008-01-01

We investigate N = (2, 2) supersymmetric nonlinear σ-models in the presence of a boundary. We restrict our attention to the case where the bulk geometry is described by chiral and twisted chiral superfields corresponding to a bihermitian bulk geometry with two commuting complex structures. The D-brane configurations preserving an N = 2 worldsheet supersymmetry are identified. Duality transformations interchanging chiral for twisted chiral fields and vice versa while preserving all supersymmetries are explicitly constructed. We illustrate our results with various explicit examples such as the WZW-model on the Hopf surface S 3 x S 1 . The duality transformations provide e.g new examples of coisotropic A-branes on Kaehler manifolds (which are not necessarily hyper-Kaehler). Finally, by dualizing a chiral and a twisted chiral field to a semi-chiral multiplet, we initiate the study of D-branes in bihermitian geometries where the cokernel of the commutator of the complex structures is non-empty.

Global anomalies in chiral gauge theories on the lattice

International Nuclear Information System (INIS)

Baer, O.; Campos, I.

2000-01-01

We discuss the issue of global anomalies in chiral gauge theories on the lattice. In Luescher's approach, these obstructions make it impossible to define consistently a fermionic measure for the path integral. We show that an SU(2) theory has such a global anomaly if the Weyl fermion is in the fundamental representation. The anomaly in higher representations is also discussed. We finally show that this obstruction is the lattice analogue of the SU(2) anomaly first discovered by Witten. (orig.)

Chiral four-membered cyclic nitrones; asymmetric induction in the (4+2)-cycloaddition reaction of chiral ynamines and nitroalkenes

NARCIS (Netherlands)

van Elburg, P.A.; Honig, G.W.N.; Reinhoudt, David

1987-01-01

Chiral four-membered cyclic nitrones were synthesized by the asymmetric (4+2)-cycloaddition of nitroalkenes 1 and chiral ynamines 2. The subsequent stereoselective addition of nucleophiles to these nitrones enabled the synthesis of chiral N-hydroxyazetidines.

Torons, chiral symmetry breaking and U(1) problem in σ-model and gauge theories. Part 2

International Nuclear Information System (INIS)

Zhitnitskij, A.R.

1989-01-01

The main point of this work is the physical consenquences of the existence of fractional charge in the σ-models and espesially in the physically interesting theory QCD. It is shown that the corresponding fluctuations ensure spontaneous breaking of the chiral symmetry and give a nonzero contribution to the chiral condensate. Toron solution is determined on the manifold with boundary. In this case many questions arise such as: global boundary conditions, the stability of the solution, self-adjointness of Dirac operator, single-valuedness of the physical values and so on. These questions are interconnected and turn out to be self cobsistent only for the special choice of the topological number (Q=1/2 for SU(2)). It is shown that in the Dirac's spectrum of the quarks the gap between zero and the continuum is absent. 50 refs.; 10 figs

The spontaneous breakdown of chiral symmetry in QCD

International Nuclear Information System (INIS)

Yoshida, K.

1980-02-01

It is suggested that the usual path integral representation of Euclidean vacuum amplitude (tunneling amplitude) in QCD must be supplemented by the explicit boundary condition corresponding to the spontaneous breaking of chiral SU(N) x SU(N). Adopting the trial wave function introduced by Nambu and Jona-Lasinio, one sees that such a path integral automatically breaks also the additional chiral U(1) symmetry of massless quarks. The catastrophe of semi-classical approach to QCD and 'U(1) problem' would be avoided in this way and one has, in principle, a better starting point for the self-consistent calculation

Stationary solutions of multicomponent chiral and gauge models

International Nuclear Information System (INIS)

Chudnovsky, D.V.; Chudnovsky, G.V.

1979-01-01

The authors examine stationary solutions of completely integrable systems in (x, t) dimensions having infinitely many components. Among the cases under investigation are: (1) the infinite-component non-linear Schroedinger equation; (2) infinite component CPsup(Ω) or SU(N) sigma-models; (3) general gauge and chiral completely integrable systems. (Auth.)

Asymmetric chiral colour

International Nuclear Information System (INIS)

Cuypers, F.

1990-01-01

Chiral colour is considered in a general framework where the coupling constants associated with each SU(3) component are allowed to be different. To reproduce QCD at low energy, gluons and axigluons cannot then be maximally mixed. Present data form e + e - colliders contrains the axigluon mass to values between 50 GeV and 375 GeV whilst the mixing angle is bounded by 13deg and 45deg. The lower limit of the axigluon mass is a definite bound at 90% C.L., whereas the upper limit only applies if chiral colour is to explain the anomalously high rates of hadron production at TRISTAN. (orig.)

Chiral gravitational waves and baryon superfluid dark matter

Science.gov (United States)

Alexander, Stephon; McDonough, Evan; Spergel, David N.

2018-05-01

We develop a unified model of darkgenesis and baryogenesis involving strongly interacting dark quarks, utilizing the gravitational anomaly of chiral gauge theories. In these models, both the visible and dark baryon asymmetries are generated by the gravitational anomaly induced by the presence of chiral primordial gravitational waves. We provide a concrete model of an SU(2) gauge theory with two massless quarks. In this model, the dark quarks condense and form a dark baryon charge superfluid (DBS), in which the Higgs-mode acts as cold dark matter. We elucidate the essential features of this dark matter scenario and discuss its phenomenological prospects.

Chirality in distorted square planar Pd(O,N)2 compounds.

Science.gov (United States)

Brunner, Henri; Bodensteiner, Michael; Tsuno, Takashi

2013-10-01

Salicylidenimine palladium(II) complexes trans-Pd(O,N)2 adopt step and bowl arrangements. A stereochemical analysis subdivides 52 compounds into 41 step and 11 bowl types. Step complexes with chiral N-substituents and all the bowl complexes induce chiral distortions in the square planar system, resulting in Δ/Λ configuration of the Pd(O,N)2 unit. In complexes with enantiomerically pure N-substituents ligand chirality entails a specific square chirality and only one diastereomer assembles in the lattice. Dimeric Pd(O,N)2 complexes with bridging N-substituents in trans-arrangement are inherently chiral. For dimers different chirality patterns for the Pd(O,N)2 square are observed. The crystals contain racemates of enantiomers. In complex two independent molecules form a tight pair. The (RC) configuration of the ligand induces the same Δ chirality in the Pd(O,N)2 units of both molecules with varying square chirality due to the different crystallographic location of the independent molecules. In complexes and atrop isomerism induces specific configurations in the Pd(O,N)2 bowl systems. The square chirality is largest for complex [(Diop)Rh(PPh3 )Cl)], a catalyst for enantioselective hydrogenation. In the lattice of two diastereomers with the same (RC ,RC) configuration in the ligand Diop but opposite Δ and Λ square configurations co-crystallize, a rare phenomenon in stereochemistry. © 2013 Wiley Periodicals, Inc.

Chiral quarks and proton decay

International Nuclear Information System (INIS)

Chadha, S.; Daniel, M.; Gounaris, G.J.; Murphy, A.J.

1984-04-01

The authors calculate the hadronic matrix elements of baryon decay operators using a chiral effective Lagrangian with quarks, gluons and Goldstone boson fields. The cases where the ΔB=1 operators arise from supersymmetric SU(5) GUT as well as the minimal SU(5) GUT model are studied. In each model the results depend on two parameters. In particular there is a range of values for the two parameters, where the dominant decay modes in the minimal SU(5) GUT are: p→etae + and n→π - e + . (author)

Enantiomeric Separation of 1-(Benzofuran-2-yl)alkylamines on Chiral Stationary Phases Based on Chiral Crown Ethers

International Nuclear Information System (INIS)

Park, Soohyun; Kim, Sang Jun; Hyun, Myung Ho

2012-01-01

Optically active chiral amines are important as building blocks for pharmaceuticals and as scaffolds for chiral ligands and, consequently, many efforts have been devoted to the development of efficient methods for their preparation. For example, reduction of amine precursors with chiral catalysts, enzymatic kinetic resolution or dynamic kinetic resolution of racemic amines and the direct amination of ketones with transaminases have been developed as the efficient methods for the preparation of optically active chiral amines. During the process of developing or utilizing optically active chiral amines, the methods for the determination of their enantiomeric composition are essential. Among various methods, liquid chromatographic resolution of enantiomers on chiral stationary phases (CSPs) have been known to be one of the most accurate and economic means for the determination of the enantiomeric composition of optically active chiral compounds. Especially, CSPs based on chiral crown ethers have been successfully used for the resolution of racemic primary amines. For example, CSPs based on (+)-(18-crown-6)-2,3,11,12-tetracarboxylic acid (CSP 1, Figure 1) or (3,3'-diphenyl-1,1'-binaphthyl)-20-crown-6 (CSP 2 and CSP 3, Figure 1) have been known to be quite effective for the resolution of cyclic and non-cyclic amines, various fluoroquinolone antibacterials containing a primary amino group, tocainide (antiarrhythmic agent) and its analogues, aryl-a-amino ketones and 3-amino-1,4-benzodiazepin-2-ones

QCD phase transition with chiral quarks and physical quark masses.

Science.gov (United States)

Bhattacharya, Tanmoy; Buchoff, Michael I; Christ, Norman H; Ding, H-T; Gupta, Rajan; Jung, Chulwoo; Karsch, F; Lin, Zhongjie; Mawhinney, R D; McGlynn, Greg; Mukherjee, Swagato; Murphy, David; Petreczky, P; Renfrew, Dwight; Schroeder, Chris; Soltz, R A; Vranas, P M; Yin, Hantao

2014-08-22

We report on the first lattice calculation of the QCD phase transition using chiral fermions with physical quark masses. This calculation uses 2+1 quark flavors, spatial volumes between (4 fm)(3) and (11 fm)(3) and temperatures between 139 and 196 MeV. Each temperature is calculated at a single lattice spacing corresponding to a temporal Euclidean extent of N(t) = 8. The disconnected chiral susceptibility, χ(disc) shows a pronounced peak whose position and height depend sensitively on the quark mass. We find no metastability near the peak and a peak height which does not change when a 5 fm spatial extent is increased to 10 fm. Each result is strong evidence that the QCD "phase transition" is not first order but a continuous crossover for m(π) = 135 MeV. The peak location determines a pseudocritical temperature T(c) = 155(1)(8) MeV, in agreement with earlier staggered fermion results. However, the peak height is 50% greater than that suggested by previous staggered results. Chiral SU(2)(L) × SU(2)(R) symmetry is fully restored above 164 MeV, but anomalous U(1)(A) symmetry breaking is nonzero above T(c) and vanishes as T is increased to 196 MeV.

Broken SU(3) antidecuplet for Θ+ and Ξ3/2

International Nuclear Information System (INIS)

Pakvasa, Sandip; Suzuki, Mahiko

2004-01-01

If the narrow exotic baryon resonances Θ + (1540) and Ξ 3/2 are members of the J P = 1/2 + antidecuplet with N*(1710), the octet-antidecuplet mixing is required not only by the mass spectrum but also by the decay pattern of N*(1710). This casts doubt on validity of the Θ + mass prediction by the chiral soliton model. While all pieces of the existing experimental information point to a small octet-decuplet mixing, the magnitude of mixing required by the mass spectrum is not consistent with the value needed to account for the hadronic decay rates. The discrepancy is not resolved even after the large experimental uncertainty is taken into consideration. We fail to find an alternative SU(3) assignment even with different spin-parity assignment. When we extend the analysis to mixing with a higher SU(3) multiplet, we find one experimentally testable scenario in the case of mixing with a 27-plet

Chiral symmetry breaking and the spin content of the {rho} and {rho}{sup '} mesons

Energy Technology Data Exchange (ETDEWEB)

Glozman, L.Ya., E-mail: leonid.glozman@uni-graz.at [Institut fuer Physik, FB Theoretische Physik, Universitaet Graz, A-8010 Graz (Austria); Lang, C.B., E-mail: christian.lang@uni-graz.at [Institut fuer Physik, FB Theoretische Physik, Universitaet Graz, A-8010 Graz (Austria); Limmer, M., E-mail: markus.limmer@uni-graz.at [Institut fuer Physik, FB Theoretische Physik, Universitaet Graz, A-8010 Graz (Austria)

2011-11-03

Using interpolators with different SU(2){sub L}xSU(2){sub R} transformation properties we study the chiral symmetry and spin contents of the {rho} and {rho}{sup '} mesons in lattice simulations with dynamical quarks. A ratio of couplings of the q-bar {gamma}{sup i}{tau}q and q-bar {sigma}{sup 0}i{tau}q interpolators to a given meson state at different resolution scales tells one about the degree of chiral symmetry breaking in the meson wave function at these scales. Using a Gaussian gauge invariant smearing of the quark fields in the interpolators, we are able to extract the chiral content of mesons up to the infrared resolution of {approx}1 fm. In the ground state {rho} meson the chiral symmetry is strongly broken with comparable contributions of both the (0,1)+(1,0) and (1/2,1/2){sub b} chiral representations with the former being the leading contribution. In contrast, in the {rho}{sup '} meson the degree of chiral symmetry breaking is manifestly smaller and the leading representation is (1/2,1/2){sub b}. Using a unitary transformation from the chiral basis to the {sup 2S+1}L{sub J} basis, we are able to define and measure the angular momentum content of mesons in the rest frame. This definition is different from the traditional one which uses parton distributions in the infinite momentum frame. The {rho} meson is practically a {sup 3}S{sub 1} state with no obvious trace of a 'spin crisis'. The {rho}{sup '} meson has a sizeable contribution of the {sup 3}D{sub 1} wave, which implies that the {rho}{sup '} meson cannot be considered as a pure radial excitation of the {rho} meson.

Enantioselective Diels-Alder Reaction Using Chiral Mg Complexes Derived from Chiral 2-[2-[(Alkyl- or 2-[2-[(Arylsulfonyl)amino]phenyl]-4-phenyl-1,3-oxazoline.

Science.gov (United States)

Ichiyanagi, Tsuyoshi; Shimizu, Makoto; Fujisawa, Tamotsu

1997-11-14

Magnesium complexes derived from (R)-2-[2-[(alkyl- or (R)-2-[2-[(arylsulfonyl)amino]phenyl]-4-phenyl-1,3-oxazolines and methylmagnesium iodide were found to be efficient Lewis acid catalysts for the Diels-Alder reaction of 3-alkenoyl-1,3-oxazolidin-2-one with cyclopentadiene. Chiral ligands were easily prepared from readily available D-phenylglycinol in good yields. The reaction of 3-acryloyl-1,3-oxazolidin-2-one with cyclopentadiene catalyzed by a stoichiometric amount of the Lewis acid gave exclusively the endo-cycloaddition product in up to 92% ee. The sulfonamide group on the chiral ligand strongly influenced the enantiofacial selectivity: the use of a toluene-, benzene-, 1- or 2-naphthalene-, or methanesulfonamide group in the chiral ligand gave the endo-(2R)-cycloaddition product, while a trifluoromethanesulfonamide group predominantly gave its enantiomer, the endo-(2S)-cycloaddition product, in 65% ee. The scope and limitations of the catalytic effect of chiral Mg(II) complexes on the enantioselectivity of the Diels-Alder reaction were investigated. The reaction mechanism of the Mg(II)-catalyzed reaction is also discussed on the basis of the experimental results.

On the twisted chiral potential in 2d and the analogue of rigid special geometry for 4-folds

CERN Document Server

Kaste, P

1999-01-01

We discuss how to obtain an N=(2,2) supersymmetric SU(3) gauge theory in two dimensions via geometric engineering from a Calabi-Yau 4-fold and compute its non-perturbative twisted chiral potential. The relevant compact part of the 4-fold geometry consists of two intersecting P^1's fibered over P^2. The rigid limit of the local mirror of this geometry is a complex surface that generalizes the Seiberg-Witten curve and on which there exist two holomorphic 2-forms. These stem from the same meromorphic 2-form as derivatives w.r.t. the two moduli, respectively. The middle periods of this meromorphic form give directly the twisted chiral potential. The explicit computation of these and of the four-point Yukawa couplings allows for a non-trivial test of the analogue of rigid special geometry for a 4-fold with several moduli.

One-loop divergences in chiral perturbation theory and right-invariant metrics on SU(3)

International Nuclear Information System (INIS)

Esposito-Farese, G.

1991-01-01

In the framework of chiral perturbation theory, we compute the one-loop divergences of the effective Lagrangian describing strong and non-leptonic weak interactions of pseudoscalar mesons. We use the background field method and the heat-kernel expansion, and underline the geometrical meaning of the different terms, showing how the right-invariance of the metrics on SU(3) allows to clarify and simplify the calculations. Our results are given in terms of a minimal set of independent counterterms, and shorten previous ones of the literature, in the particular case where the electromagnetic field is the only external source which is considered. We also show that a geometrical construction of the effective Lagrangian at order O(p 4 ) allows to derive some relations between the finite parts of the coupling constants. These relations do not depend on the scale μ used to renormalize. (orig.)

Bootstrapping N=2 chiral correlators

Science.gov (United States)

Lemos, Madalena; Liendo, Pedro

2016-01-01

We apply the numerical bootstrap program to chiral operators in four-dimensional N=2 SCFTs. In the first part of this work we study four-point functions in which all fields have the same conformal dimension. We give special emphasis to bootstrapping a specific theory: the simplest Argyres-Douglas fixed point with no flavor symmetry. In the second part we generalize our setup and consider correlators of fields with unequal dimension. This is an example of a mixed correlator and allows us to probe new regions in the parameter space of N=2 SCFTs. In particular, our results put constraints on relations in the Coulomb branch chiral ring and on the curvature of the Zamolodchikov metric.

Bootstrapping N=2 chiral correlators

Energy Technology Data Exchange (ETDEWEB)

Lemos, Madalena [Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany); Liendo, Pedro [Humboldt-Univ. Berlin (Germany). IMIP

2015-12-15

We apply the numerical bootstrap program to chiral operators in four-dimensional N=2 SCFTs. In the first part of this work we study four-point functions in which all fields have the same conformal dimension. We give special emphasis to bootstrapping a specific theory: the simplest Argyres-Douglas fixed point with no flavor symmetry. In the second part we generalize our setup and consider correlators of fields with unequal dimension. This is an example of a mixed correlator and allows us to probe new regions in the parameter space of N=2 SCFTs. In particular, our results put constraints on relations in the Coulomb branch chiral ring and on the curvature of the Zamolodchikov metric.

Bootstrapping N=2 chiral correlators

Energy Technology Data Exchange (ETDEWEB)

Lemos, Madalena [DESY Hamburg, Theory Group,Notkestrasse 85, D-22607 Hamburg (Germany); Liendo, Pedro [IMIP, Humboldt-Universität zu Berlin, IRIS Adlershof,Zum Großen Windkanal 6, 12489 Berlin (Germany)

2016-01-07

We apply the numerical bootstrap program to chiral operators in four-dimensional N=2 SCFTs. In the first part of this work we study four-point functions in which all fields have the same conformal dimension. We give special emphasis to bootstrapping a specific theory: the simplest Argyres-Douglas fixed point with no flavor symmetry. In the second part we generalize our setup and consider correlators of fields with unequal dimension. This is an example of a mixed correlator and allows us to probe new regions in the parameter space of N=2 SCFTs. In particular, our results put constraints on relations in the Coulomb branch chiral ring and on the curvature of the Zamolodchikov metric.

Nonleptonic decay of charmed mesons and chiral lagrangians

International Nuclear Information System (INIS)

Kalinovskij, Yu.L.; Pervushin, V.N.

1978-01-01

Nonleptonic decays of charmed mesons in chiral theory are considered. The lagrangian of strong interaction is taken to be invariant under the SU(4)xSU(4) group. Symmetry breaking is chosen according to the (4,4sup(*))+(4sup(*),4) simplest representation of the SU(4)xSU(4) group. The lagrangian of weak interaction is taken in the ''current x current'' form and satisfies exactly the rule probabilities of decays for D and F mesons are compared with available experimental data

On grand unified SU(8)sub(L) x SU(8)sub(R) model

International Nuclear Information System (INIS)

Pirogov, Yu.F.

1980-01-01

In the model of early chiral grand unification SU(8)sub(L)xSU(8)sub(R) with intermediate symmetry hierarchies the radiation corrections for sinsup(2)thetasub(W)(μ) and α(μ) are calculated and unification mass M 8 is found in the one loop approximation with Higgs fields contribution being neglected. It is shown that there exists a natural hierarchy, leading to the decrease of sinsup(2)thetasub(W)(Msub(W)) down to the value sinsup(2)thetasub(W)=1/5-1/4 and simultaneous decrease of M 8 down to M 8 =(10 6 -10 7 ) GeV as compared with the values when there is no hierarchy [ru

Lattice analysis of SU(2) chromodynamics with light quarks

International Nuclear Information System (INIS)

Laermann, E.

1986-01-01

I report on the Monte-Carlo simulation of a SU(2) lattice gauge theory which includes dynamical Kogut-Susskind quarks. On a 16*8 3 lattice the masses of ρ and π mesons are studied, the condensate measuring the chiral symmetry breaking determined, and the potential between static quarks measured. Extrapolations to vanishing quark mass yield a finite ρ mass but a value for the π mass which is compatible with zero, as well as a result different from zero for the quark condensate in accordance with the spontaneous breaking of the chiral symmetry of massless non-Abelian gauge theories. The shape of the q-anti q potential equals the pure gauge potential for small to intermediate distances. However at large distances (σ(fm)) deviations from the linear increase are indicated as they are expected due to the breakup of the flux tube between heavy quarks because of spontaneous quark-pair production. For all numerical calculations it is common that they favor a value for the scale parameter Λsub(anti Manti S)(N F =4) of quantum chromodynamics which is smaller than in the pure gauge field theory. (orig.) [de

A Study of ρ-ω Mixing in Resonance Chiral Theory

Science.gov (United States)

Chen, Yun-Hua; Yao, De-Liang; Zheng, Han-Qing

2018-01-01

The strong and electromagnetic corrections to ρ-ω mixing are calculated using an SU(2) version of resonance chiral theory up to next-to-leading orders in 1/{N}C expansion, respectively. Up to our accuracy, the effect of the momentum dependence of ρ-ω mixing is incorporated due to the inclusion of loop contributions. We analyze the impact of ρ-ω mixing on the pion vector form factor by performing numerical fit to the data extracted from {e}+{e}-\\to {π }+{π }- and τ \\to {ν }τ 2π , while the decay width of ω \\to {π }+{π }- is taken into account as a constraint. It is found that the momentum dependence is significant in a good description of the experimental data. In addition, based on the fitted values of the involved parameters, we analyze the decay width of ω \\to {π }+{π }-, which turns out to be highly dominated by the ρ-ω mixing effect. Supported in part by the Fundamental Research Funds for the Central Universities under Grant No. 06500077, the Spanish Ministerio de Economía y Competitividad and the European Regional Development Fund, under Grant Nos. FIS2014-51948-C2-1-P, FIS2014-51948-C2-2-P, SEV-2014-0398, and Generalitat Valenciana under Grant No. PROMETEOII/2014/0068

Investigation of the chiral antiferromagnetic Heisenberg model using projected entangled pair states

Science.gov (United States)

Poilblanc, Didier

2017-09-01

A simple spin-1/2 frustrated antiferromagnetic Heisenberg model (AFHM) on the square lattice—including chiral plaquette cyclic terms—was argued [A. E. B. Nielsen, G. Sierra, and J. I. Cirac, Nat. Commun. 4, 2864 (2013), 10.1038/ncomms3864] to host a bosonic Kalmeyer-Laughlin (KL) fractional quantum Hall ground state [V. Kalmeyer and R. B. Laughlin, Phys. Rev. Lett. 59, 2095 (1987), 10.1103/PhysRevLett.59.2095]. Here, we construct generic families of chiral projected entangled pair states (chiral PEPS) with low bond dimension (D =3 ,4 ,5 ) which, upon optimization, provide better variational energies than the KL Ansatz. The optimal D =3 PEPS exhibits chiral edge modes described by the Wess-Zumino-Witten SU(2) 1 model, as expected for the KL spin liquid. However, we find evidence that, in contrast to the KL state, the PEPS spin liquids have power-law dimer-dimer correlations and exhibit a gossamer long-range tail in the spin-spin correlations. We conjecture that these features are genuine to local chiral AFHM on bipartite lattices.

Topological fluctuations in SU(2) gauge theory with staggered fermions: An exploratory study

International Nuclear Information System (INIS)

Kogut, J.B.; Sinclair, D.K.; Teper, M.; Oxford Univ.

1991-01-01

We investigate some basic aspects of topological fluctuations in lattice QCD, in the version with two colours and four light flavours; and we do so in both the confining, chiral symmetry broken phase in the non-confining, chirally symmetric phase. This latter phase is found to occur not only at high temperatures, just as in the pure gauge system, but also in small spatial volumes, which is unlike the pure gauge case. We derive the way the topological susceptibility should vary with quark mass at small quark masses. We find that the calculated topological susceptibility decreases to zero with the quark mass, with the theoretically expected powers except - in the symmetric phase - at the very smallest values of the quark mass. We demonstrate that this anomalous behaviour can be understood as arising from the fact that the lattice topological 'zero modes' are in fact sufficiently far from being zero. We also show, in the chirally symmetric phase, that, just as expected, the average distance between instantons and anti-instantons decreases with decreasing quark mass. We finish with a new and more precise estimate of the location of the finite-temperature transition in SU(2) with four light flavours. (orig.)

Finite density two color chiral perturbation theory revisited

Science.gov (United States)

Adhikari, Prabal; Beleznay, Soma B.; Mannarelli, Massimo

2018-06-01

We revisit two-color, two-flavor chiral perturbation theory at finite isospin and baryon density. We investigate the phase diagram obtained varying the isospin and the baryon chemical potentials, focusing on the phase transition occurring when the two chemical potentials are equal and exceed the pion mass (which is degenerate with the diquark mass). In this case, there is a change in the order parameter of the theory that does not lend itself to the standard picture of first order transitions. We explore this phase transition both within a Ginzburg-Landau framework valid in a limited parameter space and then by inspecting the full chiral Lagrangian in all the accessible parameter space. Across the phase transition between the two broken phases the order parameter becomes an SU(2) doublet, with the ground state fixing the expectation value of the sum of the magnitude squared of the pion and the diquark fields. Furthermore, we find that the Lagrangian at equal chemical potentials is invariant under global SU(2) transformations and construct the effective Lagrangian of the three Goldstone degrees of freedom by integrating out the radial fluctuations.

Quark matter inside neutron stars in an effective chiral model

International Nuclear Information System (INIS)

Kotlorz, A.; Kutschera, M.

1994-02-01

An effective chiral model which describes properties of a single baryon predicts that the quark matter relevant to neutron stars, close to the deconfinement density, is in a chirally broken phase. We find the SU(2) model that pion-condensed up and down quark matter is preferred energetically at neutron star densities. It exhibits spin ordering and can posses a permanent magnetization. The equation of state of quark matter with chiral condensate is very well approximated by bag model equation of the state with suitably chosen parameters. We study quark cores inside neutron stars in this model using realistic nucleon equations of state. The biggest quark core corresponds to the second order phase transition to quark matter. Magnetic moment of the pion-condensed quark core is calculated. (author). 19 refs, 10 refs, 1 tab

Chiral rings and anomalies in supersymmetric gauge theory

International Nuclear Information System (INIS)

Cachazo, Freddy; Witten, Edward; Seiberg, Nathan; Douglas, Michael R.

2002-01-01

Motivated by recent work of Dijkgraaf and Vafa, we study anomalies and the chiral ring structure in a supersymmetric U(N) gauge theory with an adjoint chiral superfield and an arbitrary superpotential. A certain generalization of the Konishi anomaly leads to an equation which is identical to the loop equation of a bosonic matrix model. This allows us to solve for the expectation values of the chiral operators as functions of a finite number of 'integration constants'. From this, we can derive the Dijkgraaf-Vafa relation of the effective superpotential to a matrix model. Some of our results are applicable to more general theories. For example, we determine the classical relations and quantum deformations of the chiral ring of N=1 super Yang-Mills theory with SU(N) gauge group, showing, as one consequence, that all supersymmetric vacua of this theory have a nonzero chiral condensate. (author)

Classification of three-family grand unification in string theory. II. The SU(5) and SU(6) models

International Nuclear Information System (INIS)

Kakushadze, Z.; Tye, S.H.

1997-01-01

Requiring that supersymmetric SU(5) and SU(6) grand unifications in the heterotic string theory must have three chiral families, adjoint (or higher representation) Higgs fields in the grand unified gauge group, and a non-Abelian hidden sector, we construct such string models within the framework of free conformal field theory and asymmetric orbifolds. Within this framework, we construct all such string models via Z 6 asymmetric orbifolds that include a Z 3 outerautomorphism, the latter yielding a level-three current algebra for the grand unification gauge group SU(5) or SU(6). We then classify all such Z 6 asymmetric orbifolds that result in models with a non-Abelian hidden sector. All models classified in this paper have only one adjoint (but no other higher representation) Higgs field in the grand unified gauge group. This Higgs field is neutral under all other gauge symmetries. The list of hidden sectors for three-family SU(6) string models are SU(2), SU(3), and SU(2)circle-times SU(2). In addition to these, three-family SU(5) string models can also have an SU(4) hidden sector. Some of the models have an apparent anomalous U(1) gauge symmetry. copyright 1997 The American Physical Society

Pion-nucleon scattering in covariant baryon chiral perturbation theory with explicit Delta resonances

Energy Technology Data Exchange (ETDEWEB)

Yao, De-Liang [Institute for Advanced Simulation, Institut für Kernphysik and Jülich Center for Hadron Physics,Forschungszentrum Jülich, D-52425 Jülich (Germany); Siemens, D. [Institut für Theoretische Physik II, Ruhr-Universität Bochum, D-44780 Bochum (Germany); Bernard, V. [Groupe de Physique Théorique, Institut de Physique Nucléaire, UMR 8606,CNRS, University Paris-Sud, Université Paris-Saclay, 91405 Orsay Cedex (France); Epelbaum, E. [Institut für Theoretische Physik II, Ruhr-Universität Bochum, D-44780 Bochum (Germany); Gasparyan, A.M. [Institut für Theoretische Physik II, Ruhr-Universität Bochum, D-44780 Bochum (Germany); SSC RF ITEP, Bolshaya Cheremushkinskaya 25, 117218 Moscow (Russian Federation); Gegelia, J. [Institute for Advanced Simulation, Institut für Kernphysik and Jülich Center for Hadron Physics,Forschungszentrum Jülich, D-52425 Jülich (Germany); Tbilisi State University, 0186 Tbilisi (Georgia); Krebs, H. [Institut für Theoretische Physik II, Ruhr-Universität Bochum, D-44780 Bochum (Germany); Meißner, Ulf-G. [Helmholtz Institut für Strahlen- und Kernphysik andBethe Center for Theoretical Physics, Universität Bonn, D-53115 Bonn (Germany); Institute for Advanced Simulation, Institut für Kernphysik and Jülich Center for Hadron Physics,Forschungszentrum Jülich, D-52425 Jülich (Germany)

2016-05-05

We present the results of a third order calculation of the pion-nucleon scattering amplitude in a chiral effective field theory with pions, nucleons and delta resonances as explicit degrees of freedom. We work in a manifestly Lorentz invariant formulation of baryon chiral perturbation theory using dimensional regularization and the extended on-mass-shell renormalization scheme. In the delta resonance sector, the on mass-shell renormalization is realized as a complex-mass scheme. By fitting the low-energy constants of the effective Lagrangian to the S- and P-partial waves a satisfactory description of the phase shifts from the analysis of the Roy-Steiner equations is obtained. We predict the phase shifts for the D and F waves and compare them with the results of the analysis of the George Washington University group. The threshold parameters are calculated both in the delta-less and delta-full cases. Based on the determined low-energy constants, we discuss the pion-nucleon sigma term. Additionally, in order to determine the strangeness content of the nucleon, we calculate the octet baryon masses in the presence of decuplet resonances up to next-to-next-to-leading order in SU(3) baryon chiral perturbation theory. The octet baryon sigma terms are predicted as a byproduct of this calculation.

Hyperon decay form factors in chiral perturbation theory

International Nuclear Information System (INIS)

Lacour, Andre; Kubis, Bastian; Meissner, Ulf-G.

2007-01-01

We present a complete calculation of the SU(3)-breaking corrections to the hyperon vector form factors up to O(p 4 ) in covariant baryon chiral perturbation theory. Partial higher-order contributions are obtained, and we discuss chiral extrapolations of the vector form factor at zero momentum transfer. In addition we derive low-energy theorems for the subleading moments in hyperon decays, the weak Dirac radii and the weak anomalous magnetic moments, up to O(p 4 )

Siegel's chiral boson and the chiral Schwinger model

International Nuclear Information System (INIS)

Berger, T.

1992-01-01

In this paper Siegel's proposal for a Lagrangian formulation of a chiral boson is analyzed by applying recent results on 2d chiral quantum gravity. A model is derived whose solution consists of a massive scalar and two massless chiral scalars. Therefore it is a minimally bosonized two-fermion chiral Schwinger model

Dimensional reduction of exceptional E6,E8 gauge groups and flavour chirality

International Nuclear Information System (INIS)

Koca, M.

1984-01-01

Ten-dimensional Yang - Mills gauge theories based on the exceptional groups E 6 and E 8 are reduced to four-dimensional flavour-chiral Yang - Mills - Higgs theories where the extra six dimensions are identified with the compact G 2 /SU(3) and SO(7)/SO(6) coset spaces. A ten-dimensional E 8 theory leads to three families of SU(5), one of which lies in the 144-dimensional representation of SO(10)

Global anomalies in chiral lattice gauge theories

International Nuclear Information System (INIS)

Baer, O.

2000-07-01

We study global anomalies in a new approach to chiral gauge theories on the lattice, which is based on the Ginsparg-Wilson relation. In this approach, global anomalies make it impossible to define consistently a fermionic measure for the functional integral. We show that a global anomaly occurs in an SU(2) theory if the fundamental representation is used for the fermion fields. The generalization to higher representations is also discussed. In addition we establish a close relation between global anomalies and the spectral flow of the Dirac operator and employ it in a numerical computation to prove the existence of the global SU(2) anomaly in a different way. This method is inspired by an earlier work of Witten who first discovered this type of anomalies in continuum field theory. (orig.)

Asymmetric Alkylation and Aldol Reactions of D-Mannitol-Derived Chiral Oxazolidin-2-one Derivatives

International Nuclear Information System (INIS)

Maeng, Yun Hee; Jun, Jong Gab

2004-01-01

In the preceding article, we have introduced a new chiral oxazolidin-2-one auxiliary (1) derived from a cheap Dmannitol, and demonstrated the chiral selectivity in alkylation, aldol reaction and β-lactam synthesis.1 The present work began with a search for useful chiral directing groups with which to control the chiral selectivity. Because the rigidity of cyclic structures contributes significantly to control of chirality,2 the 1,2:5,6-di-O-cyclohexylidene-Dmannitol (2) was used for the synthesis of oxazolidin-2-one chiral auxiliary (3) comparing the selectivity with the auxiliary (1) in alkylation and aldol reactions.

Spectroscopy of SU(4) composite Higgs theory with two distinct fermion representations

Science.gov (United States)

Ayyar, Venkitesh; DeGrand, Thomas; Golterman, Maarten; Hackett, Daniel C.; Jay, William I.; Neil, Ethan T.; Shamir, Yigal; Svetitsky, Benjamin

2018-04-01

We have simulated the SU(4) lattice gauge theory coupled to dynamical fermions in the fundamental and two-index antisymmetric (sextet) representations simultaneously. Such theories arise naturally in the context of composite Higgs models that include a partially composite top quark. We describe the low-lying meson spectrum of the theory and fit the pseudoscalar masses and decay constants to chiral perturbation theory. We infer as well the mass and decay constant of the Goldstone boson corresponding to the nonanomalous U(1) symmetry of the model. Our results are broadly consistent with large-Nc scaling and vector-meson dominance.

Anomalies of hidden local chiral symmetries in sigma-models and extended supergravities

International Nuclear Information System (INIS)

Vecchia, P. di; Ferrara, S.; Girardello, L.

1985-01-01

Non-linear sigma-models with hidden gauge symmetries are anomalous, at the quantum level, when coupled to chiral fermions in not anomaly free representations of the hidden chiral symmetry. These considerations generally apply to supersymmetric kaehlerian sigma-models on coset spaces with hidden chiral symmetries as well as to extended supergravities in four dimensions with local SU(N) symmetry. The presence of the anomaly implies that the scenario of dynamical generation of gauge vector bosons has to be reconsidered in these theories. (orig.)

Chiral nucleon-nucleon forces in nuclear structure calculations

Directory of Open Access Journals (Sweden)

Coraggio L.

2016-01-01

Full Text Available Realistic nuclear potentials, derived within chiral perturbation theory, are a major breakthrough in modern nuclear structure theory, since they provide a direct link between nuclear physics and its underlying theory, namely the QCD. As a matter of fact, chiral potentials are tailored on the low-energy regime of nuclear structure physics, and chiral perturbation theory provides on the same footing two-nucleon forces as well as many-body ones. This feature fits well with modern advances in ab-initio methods and realistic shell-model. Here, we will review recent nuclear structure calculations, based on realistic chiral potentials, for both finite nuclei and infinite nuclear matter.

Two-chiral-component microemulsion electrokinetic chromatography-chiral surfactant and chiral oil: part 1. dibutyl tartrate.

Science.gov (United States)

Kahle, Kimberly A; Foley, Joe P

2007-06-01

The first simultaneous use of a chiral surfactant and a chiral oil for microemulsion EKC (MEEKC) is reported. Six stereochemical combinations of dodecoxycarbonylvaline (DDCV: R, S, or racemic, 2.00% w/v), racemic 2-hexanol (1.65% v/v), and dibutyl tartrate (D, L, or racemic, 1.23% v/v) were examined as chiral pseudostationary phases (PSPs) for the separation of six pairs of pharmaceutical enantiomers: pseudoephedrine, ephedrine, N-methyl ephedrine, metoprolol, synephrine, and atenolol. Subtle differences were observed for three chromatographic figures of merit (alpha(enant), alpha(meth), k) among the chiral microemulsions; a moderate difference was observed for efficiency (N) and elution range. Dual-chirality microemulsions provided both the largest and smallest enantioselectivities, due to small positive and negative synergies between the chiral microemulsion components. For the ephedrine family of compounds, dual-chiral microemulsions with surfactant and oil in opposite stereochemical configurations provided higher enantioselectivities than the single-chiral component microemulsion (RXX), whereas dual-chiral microemulsions with surfactant and oil in the same stereochemical configurations provided lower enantioselectivities than RXX. Slight to moderate enantioselective synergies were confirmed using a thermodynamic model. Efficiencies observed with microemulsions comprised of racemic dibutyl tartrate or dibutyl-D-tartrate were significantly higher than those obtained with dibutyl-L-tartrate, with an average difference in plate count of about 25 000. Finally, one two-chiral-component microemulsion (RXS) provided significantly better resolution than the remaining one- and two-chiral-component microemulsions for the ephedrine-based compounds, but only slightly better or equivalent resolution for non-ephedrine compounds.

The Chiral and Angular Momentum Content of the ρ-Meson

Science.gov (United States)

Glozman, L. Ya.; Lang, C. B.; Limmer, M.

2010-01-01

It is possible to define and calculate in a gauge-invariant manner the chiral as well as the partial wave content of the quark-antiquark Fock component of a meson in the infrared, where mass is generated. Using the variational method and a set of interpolators that span a complete chiral basis we extract in a lattice QCD Monte Carlo simulation with n f = 2 dynamical light quarks the orbital angular momentum and spin content of the ρ-meson. We obtain in the infrared a simple 3 S 1 component as a leading component of the ρ-meson with a small admixture of the 3 D 1 partial wave, in agreement with the SU(6) flavor-spin symmetry.

On integration over Fermi fields in chiral and supersymmetric theories

International Nuclear Information System (INIS)

Vainshtein, A.I.; Zakharov, V.I.

1982-01-01

Chiral and supersymmetric theories are considered which cannot be formulated directly in Euclidean space or regularized by means of massive fields in a manifestly gauge invariant fashion. In case of so called real representations a simple recipe is proposed which allows for unambiguous evaluation of the fermionic determinant circumventing the difficulties mentioned. As application of the general technique the effective fermionic interactions induced by instantons of small size within simplest chiral and supesymmetric theories are calculated (SU(2) as the gauge group and one doublet of Weyl spinors or a triplet of Majorana spinors, respectively). In the latter case the effective Lagrangian violates explicitly invariance under supersymmetric transformations on the fermionic and vector fields defined in standard way [ru

Geometrical theory of ghost and Higgs fields and SU(2/1)

International Nuclear Information System (INIS)

Ne'eman, Y.; Thierry-Mieg, J.

1979-10-01

That a Principal Fiber Bundle provides a precise geometrical representation of Yang-Mills gauge theories has been known since 1963 and used since 1975. This work presents an entirely new domain of applications. The Feynman-DeWitt-Fadeev-Popov ghost-fields required in the renormalization procedure are identified with geometrical objects in the Principal Bundle. This procedure directly yields the BRS equations guaranteeing unitarity and Slavnov-Taylor invariance of the quantum effective Lagrangian. Except for one ghost field and its variation, this entire symmetry thus corresponds to classical notions, in that it is geometrical, and completely independent of the gauge-fixing procedure, which determines the quantized Lagrangian. These results may be used to fix the signs associated with the various ghost loops of quantum supergravity. The result is based upon the identification of a geometrical Z(2) x Z(2) double-gradation of the generalized fields in supergravity: [physical/ghost] fields and [integer/half integer] spins. Then the case of a supergroup as an internal symmetry gauge is considered. Ghosts geometrically associated to odd generators may be identified with the Goldstone-Nambu Higgs-Kibble scalar fields of conventional models with spontaneous symmetry breakdown. As an example, the chiral SU(3)/sub L/ x SU(3)/sub R/ flavor symmetry is realized by gauging the supergroup Q(3).Lastly, the main results concerning asthenodynamics (Weak-EM Unification) as given by the ghost-gauge SU(2/1) supergroup are recalled. 1 table

Static properties of baryons in the SU(3) Skyrme model

International Nuclear Information System (INIS)

Sriram, M.S.; Mani, H.S.; Ramachandran, R.

1984-01-01

We study the SU(3) x SU(3) Skyrme model with explicit chiral- and flavor-symmetry-breaking terms. We evaluate the SU(3)-symmetric meson-baryon coupling-constant ratio α, SU(3) mass breaking in the octet and decuplet, and the ΔI = 1 part of the electromagnetic mass splitting in baryons. The theoretical numbers are in reasonable agreement with the experimental values

Thermodynamics of lattice QCD with massless quarks and chiral 4-fermion interactions

International Nuclear Information System (INIS)

Kogut, J. B.

1998-01-01

N f = 2 lattice QCD with massless quarks and a weak 4-fermion interaction appears to have the expected second order transition, at least for N t ≥ 6. More work is needed to clarify the N t = 4 case. With more statistics the N t = 6 simulations should produce an accurate determination of the critical exponent β m . Moving to finite mass at β = β c should allow an accurate determination of σ. Hadronic screening masses need further analysis. Other order parameters remain to be analyzed. Unfortunately, there is no obvious way to include 4-fermion interactions with full SU(2) x SU(2) chiral flavor symmetry

Sensitive criterion for chirality; Chiral doublet bands in 104Rh59

International Nuclear Information System (INIS)

Koike, T.; Starosta, K.; Vaman, C.; Ahn, T.; Fossan, D.B.; Clark, R.M.; Cromaz, M.; Lee, I.Y.; Macchiavelli, A.O.

2003-01-01

A particle plus triaxial rotor model was applied to odd-odd nuclei in the A ∼ 130 region in order to study the unique parity πh11/2xνh11/2 rotational bands. With maximum triaxiality assumed and the intermediate axis chosen as the quantization axis for the model calculations, the two lowest energy eigenstates of a given spin have chiral properties. The independence of the quantity S(I) on spin can be used as a new criterion for chirality. In addition, a diminishing staggering amplitude of S(I) with increasing spin implies triaxiality in neighboring odd-A nuclei. Chiral quartet bases were constructed specifically to examine electromagnetic properties for chiral structures. A set of selection rules unique to chirality was derived. Doublet bands built on the πg9/2xνh11/2 configuration have been discovered in odd-odd 104Rh using the 96Zr(11B, 3n) reaction. Based on the discussed criteria for chirality, it is concluded that the doublet bands observed in 104Rh exhibit characteristic chiral properties suggesting a new region of chirality around A ∼110. In addition, magnetic moment measurements have been performed to test the πh11/2xνh11/2 configuration in 128Cs and the πg9/2xνh11/2 configuration in 104Rh

Covariant meson-baryon scattering with chiral and large Nc constraints

International Nuclear Information System (INIS)

Lutz, M.F.M.; Kolomeitsev, E.E.

2001-05-01

We give a review of recent progress on the application of the relativistic chiral SU(3) Lagrangian to meson-baryon scattering. It is shown that a combined chiral and 1/N c expansion of the Bethe-Salpeter interaction kernel leads to a good description of the kaon-nucleon, antikaon-nucleon and pion-nucleon scattering data typically up to laboratory momenta of p lab ≅ 500 MeV. We solve the covariant coupled channel Bethe-Salpeter equation with the interaction kernel truncated to chiral order Q 3 where we include only those terms which are leading in the large N c limit of QCD. (orig.)

Mechanisms for the inversion of chirality: Global reaction route mapping of stereochemical pathways in a probable chiral extraterrestrial molecule, 2-aminopropionitrile

International Nuclear Information System (INIS)

Kaur, Ramanpreet; Vikas

2015-01-01

2-Aminopropionitrile (APN), a probable candidate as a chiral astrophysical molecule, is a precursor to amino-acid alanine. Stereochemical pathways in 2-APN are explored using Global Reaction Route Mapping (GRRM) method employing high-level quantum-mechanical computations. Besides predicting the conventional mechanism for chiral inversion that proceeds through an achiral intermediate, a counterintuitive flipping mechanism is revealed for 2-APN through chiral intermediates explored using the GRRM. The feasibility of the proposed stereochemical pathways, in terms of the Gibbs free-energy change, is analyzed at the temperature conditions akin to the interstellar medium. Notably, the stereoinversion in 2-APN is observed to be more feasible than the dissociation of 2-APN and intermediates involved along the stereochemical pathways, and the flipping barrier is observed to be as low as 3.68 kJ/mol along one of the pathways. The pathways proposed for the inversion of chirality in 2-APN may provide significant insight into the extraterrestrial origin of life

Chiral symmetry breaking parameters from QCD sum rules

Energy Technology Data Exchange (ETDEWEB)

Mallik, S [Karlsruhe Univ. (T.H.) (Germany, F.R.). Inst. fuer Theoretische Kernphysik; Bern Univ. (Switzerland). Inst. fuer Theoretische Physik)

1982-10-04

We obtain new QCD sum rules by considering vacuum expectation values of two-point functions, taking all the five quark bilinears into account. These sum rules are employed to extract values of different chiral symmetry breaking parameters in QCD theory. We find masses of light quarks, m=1/2msub(u)+msub(d)=8.4+-1.2 MeV, msub(s)=205+-65 MeV. Further, we obtain corrections to certain soft pion (kaon) PCAC relations and the violation of SU(3) flavour symmetry by the non-strange and strange quark-antiquark vacuum condensate.

SU(2 color NJL model and EOS of quark-hadron matter at finite temperature and density

Directory of Open Access Journals (Sweden)

Weise Wolfram

2012-02-01

Full Text Available We study the NJL model with the Polyakov loop in the SU(2-color case for the EOS of quark-hadron matter at finite temperature and density. We consider the spontaneous chiral symmetry breaking and the diquark condensation together with the behavior of the Polyakov loop for the phase diagram of quark-hadron matter. We discuss the spectrum of mesons and diquark baryons (boson at finite temperature and density.We derive also the linear sigma model Lagrangian for diquark baryon and mesons.

Sigma Terms and Strangeness Contents of Baryon Octet in Modified Chiral Perturbation Theory

Institute of Scientific and Technical Information of China (English)

LI Xiao-Ya; L(U) Xiao-Fu

2006-01-01

In the frame work of chiral perturbation theory, a modified effective Lagrangian for meson-baryon system is constructed, where the SU(3) breaking effect for meson is considered. The difference between physical and chiral limit decay constants is taken into account. Calculated to one loop at O(p3), the sigma terms and strangeness contents of baryon octet are obtained.

Chiral symmetry restoration and quasi-elastic electron-nucleus scattering

International Nuclear Information System (INIS)

Henley, E.M.; Krein, G.

1989-01-01

Chiral symmetry is known to be an important concept in hadronic interactions. It holds in QCD, but is known to be broken at low energies. It is therefore useful to study chiral symmetry and its breaking together with its consequences in nuclear physics. It is the latter phenomena we consider here. It is difficult to study nonperturbative QCD at low energies and models are needed. The Nambu-Jona-Lasinio (NJL) model fits this category; it incorporates chiral symmetry and its breaking, and allows one to study its effects in nucleons and nuclei. In particular, the constituent quark mass varies with density (ρ) and temperature (T). At high ρ and T chiral symmetry is restored. It is the ρ dependence which yields important effects in electron scattering due to partial restoration of chiral symmetry in nuclei. We begin with the NJL model with a small chiral symmetry breaking

θ-parameter evolution and topological-charge matching conditions in chiral-color theory

International Nuclear Information System (INIS)

Frampton, P.H.; Kephart, T.W.

1991-01-01

The θ parameter and topological charges are followed through spontaneous-symmetry-breaking phase transitions. The most interesting case is that of an irregular embedding of SU(3) C in a spontaneously broken larger group. The example of chiral color is shown to have no additional CP difficulties beyond the SU(3) C CP problem

Chiral superconductors.

Science.gov (United States)

Kallin, Catherine; Berlinsky, John

2016-05-01

Chiral superconductivity is a striking quantum phenomenon in which an unconventional superconductor spontaneously develops an angular momentum and lowers its free energy by eliminating nodes in the gap. It is a topologically non-trivial state and, as such, exhibits distinctive topological modes at surfaces and defects. In this paper we discuss the current theory and experimental results on chiral superconductors, focusing on two of the best-studied systems, Sr2RuO4, which is thought to be a chiral triplet p-wave superconductor, and UPt3, which has two low-temperature superconducting phases (in zero magnetic field), the lower of which is believed to be chiral triplet f-wave. Other systems that may exhibit chiral superconductivity are also discussed. Key signatures of chiral superconductivity are surface currents and chiral Majorana modes, Majorana states in vortex cores, and the possibility of half-flux quantum vortices in the case of triplet pairing. Experimental evidence for chiral superconductivity from μSR, NMR, strain, polar Kerr effect and Josephson tunneling experiments are discussed.

Towards a determination of the chiral couplings at NLO in 1/NC: L8r(μ) and C38r(μ)

International Nuclear Information System (INIS)

Rosell, Ignasi; Pich, Antonio; Sanz-Cillero, Juan Jose

2007-01-01

We present a dispersive method which allows to investigate the low-energy couplings of chiral perturbation theory at the next-to-leading order (NLO) in the 1/N C expansion, keeping full control of their renormalization scale dependence. Using the resonance chiral theory Lagrangian, we perform a NLO calculation of the scalar and pseudoscalar two-point functions, within the single-resonance approximation. Imposing the correct QCD short-distance constraints, one determines their difference Π(t)≡Π S (t)-Π P (t) in terms of the pion decay constant and resonance masses. Its low momentum expansion fixes then the low-energy chiral couplings L 8 and C 38 . At μ 0 = 0.77 GeV, we obtain L 8 r (μ 0 ) SU(3) (0.6±0.4).10 -3 and C 38 r (μ 0 ) SU(3) = (2±6).10 -6

The chiral and angular momentum content of the ρ-meson

International Nuclear Information System (INIS)

Glozman, L.Y.; Lang, C.B.; Limmer, M.

2010-01-01

It is possible to define and calculate in a gauge-invariant manner the chiral as well as the partial wave content of the quark-antiquark Fock component of a meson in the infrared, where mass is generated. Using the variational method and a set of interpolators that span a complete chiral basis we extract in a lattice QCD Monte Carlo ρ-meson with a small admixture of the 3 D 1 partial wave, in agreement with the SU (6) flavor-spin symmetry. (author)

Measuring the electromagnetic chirality of 2D arrays under normal illumination.

Science.gov (United States)

Garcia-Santiago, X; Burger, S; Rockstuhl, C; Fernandez-Corbaton, I

2017-10-15

We present an electromagnetic chirality measure for 2D arrays of subwavelength periodicities under normal illumination. The calculation of the measure uses only the complex reflection and transmission coefficients from the array. The measure allows the ordering of arrays according to their electromagnetic chirality, which further allows a quantitative comparison of different design strategies. The measure is upper bounded, and the extreme properties of objects with high values of electromagnetic chirality make them useful in both near- and far-field applications. We analyze the consequences that different possible symmetries of the array have on its electromagnetic chirality. We use the measure to study four different arrays. The results indicate the suitability of helices for building arrays of high electromagnetic chirality, and the low effectiveness of a substrate for breaking the transverse mirror symmetry.

Scattering of decuplet baryons in chiral effective field theory

Energy Technology Data Exchange (ETDEWEB)

Haidenbauer, J. [Institut fuer Kernphysik, Institute for Advanced Simulation and Juelich Center for Hadron Physics, Juelich (Germany); Petschauer, S.; Kaiser, N.; Weise, W. [Technische Universitaet Muenchen, Physik Department, Garching (Germany); Meissner, Ulf G. [Institut fuer Kernphysik, Institute for Advanced Simulation and Juelich Center for Hadron Physics, Juelich (Germany); Universitaet Bonn, Helmholtz-Institut fuer Strahlen- und Kernphysik and Bethe Center for Theoretical Physics, Bonn (Germany)

2017-11-15

A formalism for treating the scattering of decuplet baryons in chiral effective field theory is developed. The minimal Lagrangian and potentials in leading-order SU(3) chiral effective field theory for the interactions of octet baryons (B) and decuplet baryons (D) for the transitions BB → BB, BB <-> DB, DB → DB, BB <-> DD, DB <-> DD, and DD → DD are provided. As an application of the formalism we compare with results from lattice QCD simulations for ΩΩ and NΩ scattering. Implications of our results pertinent to the quest for dibaryons are discussed. (orig.)

On symmetry hierarchy and radiative corrections in the grand unified model SU(8)sub(L)xSU(8)sub(R)

International Nuclear Information System (INIS)

Pirogov, Yu.F.

1982-01-01

In the model of precocious chiral unification SU(8)sub(L)xSU(8)sub(R) radiative corrections are calculated for the effective parameters sin 2 thetaw(μ) and α(μ) and the unification mass M 8 is determifed in presence of a hierarchy of intermediate symmetries. The one-loop approximation is used and contributions from the Higgs fields are neglected. It is shown that a natural hierarchy exists leading to a decrease of sinsup(2)thetasub(w)(Msub(wsub(L))) up to sinsup(2)thetasub(w)=1/5-1/4 together with a decrease of M 8 up to M 8 =10 6 -10 7 GeV, as compared with the magnitudes without the hierarchy [ru

Evaluation of physical constants and operators in the SU(2) and SU(3) lattice gauge theory

International Nuclear Information System (INIS)

Tsuchida, R.H.

1987-01-01

Wilson loops and Wilson lines in the fundamental and the adjoint representations of SU(2) on the lattice are measured using the icosahedral subgroup and a noise reduction technique. The string tension was evaluated by fitting the expectation value of loops of all sizes to a 6-parameter curve. From the Wilson lines in the adjoint representation of SU(2), two kinds of gluon potentials were measured: the gluon-gluon interaction potential and the gluon-image interaction potential. The effective mass of the gluon was evaluated on each of those potentials and compared. In SU(3), the contribution of s anti σ/sub μnu/F/sub μnu/d operator to the correction of effective weak four-quark operator in the measurement of ΔI = 1/2 amplitude of kaon decay is examined. The renormalization of the critical hopping parameter is calculated perturbatively and compared with the Monte Carlo results. The VEV of psi anti psi operator is measured on the lattice. In the hopping parameter renormalization calculation and the psi anti psi measurements, the effects of expanding of Feynman diagrams in power of a, the lattice spacing, are examined

Deconfinement at the Argyres-Douglas point in SU(2) gauge theory with broken N=2 supersymmetry

International Nuclear Information System (INIS)

Gorsky, A.; Vainshtein, A.; Yung, A.

2000-01-01

We consider chiral condensates in SU(2) gauge theory with broken N=2 supersymmetry. The matter sector contains an adjoint multiplet and one fundamental flavor. Matter and gaugino condensates are determined by integrating out the adjoint field. The only nonperturbative input is the Affleck-Dine-Seiberg (ADS) superpotential generated by one instanton plus the Konishi anomaly. These results are consistent with those obtained by the 'integrating in' procedure, including a reproduction of the Seiberg-Witten curve from the ADS superpotential. We then calculate monopole, dyon, and charge condensates using the Seiberg-Witten approach. We show that the monopole and charge condensates vanish at the Argyres-Douglas point where the monopole and charge vacua collide. We interpret this phenomenon as a deconfinement of electric and magnetic charges at the Argyres-Douglas point

SU(3) breaking in hyperon transition vector form factors

International Nuclear Information System (INIS)

Shanahan, P.E.; Thomas, A.W.; Young, R.D.; Zanotti, J.M.; Rakow, P.E.L.

2015-08-01

We present a calculation of the SU(3)-breaking corrections to the hyperon transition vector form factors to O(p 4 ) in heavy baryon chiral perturbation theory with finite-range regularisation. Both octet and decuplet degrees of freedom are included. We formulate a chiral expansion at the kinematic point Q 2 =-(M B 1 -M B 2 ) 2 , which can be conveniently accessed in lattice QCD. The two unknown low-energy constants at this point are constrained by lattice QCD simulation results for the Σ - →n and Ξ 0 →Σ + transition form factors. Hence we determine lattice-informed values of f 1 at the physical point. This work constitutes progress towards the precise determination of vertical stroke V us vertical stroke from hyperon semileptonic decays.

Acylation of Chiral Alcohols: A Simple Procedure for Chiral GC Analysis

Directory of Open Access Journals (Sweden)

Mireia Oromí-Farrús

2012-01-01

Full Text Available The use of iodine as a catalyst and either acetic or trifluoroacetic acid as a derivatizing reagent for determining the enantiomeric composition of acyclic and cyclic aliphatic chiral alcohols was investigated. Optimal conditions were selected according to the molar ratio of alcohol to acid, the reaction time, and the reaction temperature. Afterwards, chiral stability of chiral carbons was studied. Although no isomerization was observed when acetic acid was used, partial isomerization was detected with the trifluoroacetic acid. A series of chiral alcohols of a widely varying structural type were then derivatized with acetic acid using the optimal conditions. The resolution of the enantiomeric esters and the free chiral alcohols was measured using a capillary gas chromatograph equipped with a CP Chirasil-DEX CB column. The best resolutions were obtained with 2-pentyl acetates (α=3.00 and 2-hexyl acetates (α=1.95. This method provides a very simple and efficient experimental workup procedure for analyzing chiral alcohols by chiral-phase GC.

Acylation of Chiral Alcohols: A Simple Procedure for Chiral GC Analysis.

Science.gov (United States)

Oromí-Farrús, Mireia; Torres, Mercè; Canela, Ramon

2012-01-01

The use of iodine as a catalyst and either acetic or trifluoroacetic acid as a derivatizing reagent for determining the enantiomeric composition of acyclic and cyclic aliphatic chiral alcohols was investigated. Optimal conditions were selected according to the molar ratio of alcohol to acid, the reaction time, and the reaction temperature. Afterwards, chiral stability of chiral carbons was studied. Although no isomerization was observed when acetic acid was used, partial isomerization was detected with the trifluoroacetic acid. A series of chiral alcohols of a widely varying structural type were then derivatized with acetic acid using the optimal conditions. The resolution of the enantiomeric esters and the free chiral alcohols was measured using a capillary gas chromatograph equipped with a CP Chirasil-DEX CB column. The best resolutions were obtained with 2-pentyl acetates (α = 3.00) and 2-hexyl acetates (α = 1.95). This method provides a very simple and efficient experimental workup procedure for analyzing chiral alcohols by chiral-phase GC.

Automorphisms of the affine SU(3) fusion rules

International Nuclear Information System (INIS)

Ruelle, P.

1994-01-01

We classify the automorphisms of the (chiral) level-k affine SU(3) fusion rules, for any value of k, by looking for all permutations that commute with the modular matrices S and T. This can be done by using the arithmetic of the cyclotomic extensions where the problem is naturally posed. When k is divisible by 3, the automorphism group ( similar Z 2 ) is generated by the charge conjugation C. If k is not divisible by 3, the automorphism group ( similar Z 2 xZ 2 ) is generated by C and the Altschueler-Lacki-Zaugg automorphism. Although the combinatorial analysis can become more involved, the techniques used here for SU(3) can be applied to other algebras. (orig.)

Chiral symmetry breaking in gauge theories from Reggeon diagram analysis

International Nuclear Information System (INIS)

White, A.R.

1991-01-01

It is argued that reggeon diagrams can be used to study dynamical properties of gauge theories containing a large number of massless fermions. SU(2) gauge theory is studied in detail and it is argued that there is a high energy solution which is analogous to the solution of the massless Schwinger model. A generalized winding-number condensate produces the massless pseudoscalar spectrum associated with chiral symmetry breaking and a ''trivial'' S-Matrix

Symmetry hierarchies and radiative corrections in the grand unified model SU(8)/sub L/ x SU(8)/sub R/

International Nuclear Information System (INIS)

Pirogov, Y.F.

1982-01-01

In the SU(8)/sub L/ x SU(8)/sub R/ model of precocious chiral unification, radiative corrections for the effective parameters sin 2 theta/sub W/(μ) and α(μ) are calculated in the one-loop approximation, neglecting contributions of the Higgs fields, and the unification mass M 8 is determined in the presence of a hierarchy of intermediate symmetries. It is shown that a natural hierarchy exists which leads to a decrease in sin 2 theta/sub W/(M/sub W/L) down to the value sin 2 theta/sub W/ = (1/5)--(1/4) together with a decrease in M 8 down to M 8 = 10 6 --10 7 GeV in comparison with the values in the absence of a hierarchy

Chirality invariance and 'chiral' fields

International Nuclear Information System (INIS)

Ziino, G.

1978-01-01

The new field model derived in the present paper actually gives a definite answer to three fundamental questions concerning elementary-particle physics: 1) The phenomenological dualism between parity and chirality invariance: it would be only an apparent display of a general 'duality' principle underlying the intrinsic nature itself of (spin 1/2) fermions and expressed by the anticommutativity property between scalar and pseudoscalar charges. 2) The real physical meaning of V - A current structure: it would exclusively be connected to the one (just pointed out) of chiral fields themselves. 3) The unjustified apparent oddness shown by Nature in weak interactions, for the fact of picking out only one of the two (left- and right-handed) fermion 'chiral' projections: the key to such a 'mystery' would just be provided by the consequences of the dual and partial character of the two fermion-antifermion field bases. (Auth.)

The SU(4), SU(2)xSU(2) chain

International Nuclear Information System (INIS)

Partensky, A.; Maguin, C.

1976-11-01

The main results of a work concerning the calculation of the matrices of the generators of SU(4) in a given (p,p',p'') irreducible representation, in which the states are labelled by the spin quantum numbers, S, MS, are given. Then the SU(4) algebra is defined, the labelling problem of the states is discussed and the Racah formula transformed, which facilitates the calculation. The semi-reduced matrix elements of the Q, Vsup(Q) and Wsup(Q) vectors are defined. Finally an explicit formulation of the matrix elements of Q is given, in the particular case T=p for any S, or S=p for any T; the example of the (3 2 0) irreducible representation is treated

Nonperturbative flipped SU(5) vacua in heterotic M-theory

Energy Technology Data Exchange (ETDEWEB)

Faraggi, Alon E. E-mail: faraggi@thphys.ox.ac.uk; Garavuso, Richard E-mail: garavuso@thphys.ox.ac.uk; Isidro, Jose M. E-mail: isidro@thphys.ox.ac.uk

2002-10-07

The evidence for neutrino masses in atmospheric and solar neutrino experiments provides further support for the embedding of the Standard Model fermions in the chiral 16 SO(10) representation. Such an embedding is afforded by the realistic free fermionic heterotic-string models. In this paper we advance the study of these string models toward a nonperturbative analysis by generalizing the work of Donagi, Pantev, Ovrut and Waldram from the case of G=SU(2n+1) to G=SU(2n) stable holomorphic vector bundles on elliptically fibered Calabi-Yau manifolds with fundamental group Z{sub 2}. We demonstrate existence of G=SU(4) solutions with three generations and SO(10) observable gauge group over Hirzebruch base surface, whereas we show that certain classes of del Pezzo base surface do not admit such solutions. The SO(10) symmetry is broken to SU(5)xU(1) by a Wilson line. The overlap with the realistic free fermionic heterotic-string models is discussed.

Intersecting Branes Flip SU(5)

CERN Document Server

Ellis, Jonathan Richard; Nanopoulos, Dimitri V; Ellis, John

2002-01-01

Within a toroidal orbifold framework, we exhibit intersecting brane-world constructions of flipped SU(5) \\times U(1) GUT models with various numbers of generations, other chiral matter representations and Higgs representations. We exhibit orientifold constructions with integer winding numbers that yield 8 or more conventional SU(5) generations, and orbifold constructions with fractional winding numbers that yield flipped SU(5) \\times U(1) models with just 3 conventional generations. Some of these models have candidates for the 5 and {\\bar 5} Higgs representations needed for electroweak symmetry breaking, but not for the 10 and {\\bar 10} representations needed for GUT symmetry breaking, or vice-versa.

Chiral near-fields around chiral dolmen nanostructure

International Nuclear Information System (INIS)

Fu, Tong; Wang, Tiankun; Chen, Yuyan; Wang, Yongkai; Qu, Yu; Zhang, Zhongyue

2017-01-01

Discriminating the handedness of the chiral molecule is of great importance in the field of pharmacology and biomedicine. Enhancing the chiral near-field is one way to increase the chiral signal of chiral molecules. In this paper, the chiral dolmen nanostructure (CDN) is proposed to enhance the chiral near-field. Numerical results show that the CDN can increase the optical chirality of the near-field by almost two orders of magnitude compared to that of a circularly polarized incident wave. In addition, the optical chirality of the near-field of the bonding mode is enhanced more than that of the antibonding mode. These results provide an effective method for tailoring the chiral near-field for biophotonics sensors. (paper)

Unconstrained SU(2) and SU(3) Yang-Mills classical mechanics

International Nuclear Information System (INIS)

Dahmen, B.; Raabe, B.

1992-01-01

A systematic study of contraints in SU(2) and SU(3) Yang-Mills classical mechanics is performed. Expect for the SU(2) case with spatial angular momenta they turn out to be nonholonomic. The complete elimination of the unphysical gauge and rotatinal degrees of freedom is achieved using Dirac's constraint formalism. We present an effective unconstrained formulation of the general SU(2) Yang-Mills classical mechanics as well as for SU(3) in the subspace of vanishing spatial angular momenta that is well suited for further explicit dynamical investigations. (orig.)

Nuclear matter from chiral effective field theory

International Nuclear Information System (INIS)

Drischler, Christian

2017-01-01

-ordering method to finite temperatures. Calculations of asymmetric matter require in addition reliable fit values for the low-energy couplings that contribute to the 3N forces. This was not the case for N 3 LO calculations. We present a novel Monte-Carlo framework for perturbative calculations with two-, three-, and four-nucleon interactions, which, including automatic code generation, allows to compute successive orders in MBPT as well as chiral EFT in an efficient way. The performance is such that it can be used for optimizing next-generation chiral potentials with respect to saturation properties. As a first step in this direction, we study nuclear matter based on chiral low-momentum interactions, exhibiting a very good many-body convergence up to fourth order. We then explore new chiral interactions up to N 3 LO, where simultaneous fits to the triton and to saturation properties can be achieved with natural 3N low-energy couplings. We perform a comprehensive Weinberg eigenvalue analysis of a representative set of modern local, semilocal, and nonlocal chiral NN potentials. Our detailed comparison of Weinberg eigenvalues provides various insights into idiosyncrasies of chiral potentials for different orders and partial waves. We demonstrate that a direct comparison of numerical cutoff values of different interactions is in general misleading due to the different analytic form of regulators. This shows that Weinberg eigenvalues also can be used as a helpful monitoring scheme when constructing new interactions. Furthermore, we present solutions of the BCS gap equation in the channels 1 S 0 and 3 P 2 - 3 F 2 in neutron matter. Our studies are based on nonlocal NN plus 3N interactions up to N 3 LO as well as the aforementioned local and semilocal chiral NN interactions up to N 2 LO and N 4 LO, respectively. In particular, we investigate the impact of N 3 LO 3N forces on pairing gaps and also derive uncertainty estimates by taking into account results at different orders in the

Nuclear matter from chiral effective field theory

Energy Technology Data Exchange (ETDEWEB)

Drischler, Christian

2017-11-15

normal-ordering method to finite temperatures. Calculations of asymmetric matter require in addition reliable fit values for the low-energy couplings that contribute to the 3N forces. This was not the case for N{sup 3}LO calculations. We present a novel Monte-Carlo framework for perturbative calculations with two-, three-, and four-nucleon interactions, which, including automatic code generation, allows to compute successive orders in MBPT as well as chiral EFT in an efficient way. The performance is such that it can be used for optimizing next-generation chiral potentials with respect to saturation properties. As a first step in this direction, we study nuclear matter based on chiral low-momentum interactions, exhibiting a very good many-body convergence up to fourth order. We then explore new chiral interactions up to N{sup 3}LO, where simultaneous fits to the triton and to saturation properties can be achieved with natural 3N low-energy couplings. We perform a comprehensive Weinberg eigenvalue analysis of a representative set of modern local, semilocal, and nonlocal chiral NN potentials. Our detailed comparison of Weinberg eigenvalues provides various insights into idiosyncrasies of chiral potentials for different orders and partial waves. We demonstrate that a direct comparison of numerical cutoff values of different interactions is in general misleading due to the different analytic form of regulators. This shows that Weinberg eigenvalues also can be used as a helpful monitoring scheme when constructing new interactions. Furthermore, we present solutions of the BCS gap equation in the channels {sup 1}S{sub 0} and {sup 3}P{sub 2}-{sup 3}F{sub 2} in neutron matter. Our studies are based on nonlocal NN plus 3N interactions up to N{sup 3}LO as well as the aforementioned local and semilocal chiral NN interactions up to N{sup 2}LO and N{sup 4}LO, respectively. In particular, we investigate the impact of N{sup 3}LO 3N forces on pairing gaps and also derive uncertainty

Mechanical separation of chiral dipoles by chiral light

International Nuclear Information System (INIS)

Canaguier-Durand, Antoine; Hutchison, James A; Genet, Cyriaque; Ebbesen, Thomas W

2013-01-01

We calculate optical forces and torques exerted on a chiral dipole by chiral light fields and reveal genuine chiral forces in combining the chiral contents of both light field and dipolar matter. Here, the optical chirality is characterized in a general way through the definition of optical chirality density and chirality flow. We show, in particular, that both terms have mechanical effects associated, respectively, with reactive and dissipative components of the chiral forces. Remarkably, these chiral force components are directly related to standard observables: optical rotation for the reactive component and circular dichroism for the dissipative one. As a consequence, the resulting forces and torques are dependent on the enantiomeric form of the chiral dipole. This suggests promising strategies for using chiral light forces to mechanically separate chiral objects according to their enantiomeric form. (paper)

String derived exophobic SU(6)×SU(2) GUTs

International Nuclear Information System (INIS)

Bernard, Laura; Faraggi, Alon E.; Glasser, Ivan; Rizos, John; Sonmez, Hasan

2013-01-01

With the apparent discovery of the Higgs boson, the Standard Model has been confirmed as the theory accounting for all sub-atomic phenomena. This observation lends further credence to the perturbative unification in Grand Unified Theories (GUTs) and string theories. The free fermionic formalism yielded fertile ground for the construction of quasi-realistic heterotic-string models, which correspond to toroidal Z 2 ×Z 2 orbifold compactifications. In this paper we study a new class of heterotic-string models in which the GUT group is SU(6)×SU(2) at the string level. We use our recently developed fishing algorithm to extract an example of a three generation SU(6)×SU(2) GUT model. We explore the phenomenology of the model and show that it contains the required symmetry breaking Higgs representations. We show that the model admits flat directions that produce a Yukawa coupling for a single family. The novel feature of the SU(6)×SU(2) string GUT models is that they produce an additional family universal anomaly free U(1) symmetry, and may remain unbroken below the string scale. The massless spectrum of the model is free of exotic states.

Unconstrained SU(2) and SU(3) Yang-Mills clasical mechanics

International Nuclear Information System (INIS)

Dahmen, B.; Raabe, B.

1992-01-01

A systematic study of constraints in SU(2) and SU(3) Yang-Mills classical mechanics is performed. Expect for the SU(2) case with vanishing spatial angular momenta they turn out to be non-holonomic. Using Dirac's constraint formalism we achieve a complete elimination of the unphysical gauge and rotational degrees of freedom. This leads to an effective unconstrained formulation both for the full SU(2) Yang-Mills classical mechanics and for the SU(3) case in the subspace of vanishing spatial angular momenta. We believe that our results are well suited for further explicit dynamical investigations. (orig.)

Chiral determinant formulae and subsingular vectors for the N=2 superconformal algebras

International Nuclear Information System (INIS)

Gato-Rivera, B.; Rosado, J.I.

1997-01-01

We derive conjectures for the N=2 ''chiral'' determinant formulae of the topological algebra, the antiperiodic NS algebra, and the periodic R-algebra, corresponding to incomplete Verma modules built on chiral topological primaries, chiral and antichiral NS primaries, and Ramond ground states, respectively. Our method is based on the analysis of the singular vectors in chiral Verma modules and their spectral flow symmetries, together with some computer exploration and some consistency checks. In addition, and as a consequence, we uncover the existence of subsingular vectors in these algebras, giving examples (subsingular vectors are non-highest-weight null vectors which are not descendants of any highest-weight singular vectors). (orig.)

[SU(2)]3 dark matter

Science.gov (United States)

Ma, Ernest

2018-05-01

An extra SU(2)D gauge factor is added to the well-known left-right extension of the standard model (SM) of quarks and leptons. Under SU(2)L × SU(2)R × SU(2)D, two fermion bidoublets (2 , 1 , 2) and (1 , 2 , 2) are assumed. The resulting model has an automatic dark U (1) symmetry, in the same way that the SM has automatic baryon and lepton U (1) symmetries. Phenomenological implications are discussed, as well as the possible theoretical origins of this proposal.

On the SU(2)× SU(2) symmetry in the Hubbard model

Science.gov (United States)

Jakubczyk, Dorota; Jakubczyk, Paweł

2012-08-01

We discuss the one-dimensional Hubbard model, on finite sites spin chain, in context of the action of the direct product of two unitary groups SU(2)× SU(2). The symmetry revealed by this group is applicable in the procedure of exact diagonalization of the Hubbard Hamiltonian. This result combined with the translational symmetry, given as the basis of wavelets of the appropriate Fourier transforms, provides, besides the energy, additional conserved quantities, which are presented in the case of a half-filled, four sites spin chain. Since we are dealing with four elementary excitations, two quasiparticles called "spinons", which carry spin, and two other called "holon" and "antyholon", which carry charge, the usual spin- SU(2) algebra for spinons and the so called pseudospin-SU(2) algebra for holons and antiholons, provide four additional quantum numbers.

Minimal Supersymmetric $SU(4) \\to SU(2)_L \\to SU(2)_R$

CERN Document Server

King, S F

1998-01-01

We present a minimal string-inspired supersymmetric $SU(4) \\times SU(2)_L potential in this model, based on a generalisation of that recently proposed by Dvali, Lazarides and Shafi. The model contains a global U(1) R-symmetry and reduces to the MSSM at low energies. However it improves on the MSSM since it explains the magnitude of its $\\mu$ term and gives a prediction for $\\tan \\beta both `cold' and `hot' dark matter candidates. A period of hybrid inflation above the symmetry breaking scale is also possible in this model. Finally it suggests the existence of `heavy' charge $\\pm e/6$ (colored) and $\\pm e/2$ (color singlet) states.

The SU(3)-Nambu-Jona-Lasinio soliton in the collective quantization formulation

International Nuclear Information System (INIS)

Blotz, A.; Goeke, K.; Diakonov, D.; Petrov, V.; Pobylitsa, P.V.; Park, N.W.

1992-01-01

On grounds of a semibosonized Nambu-Jona-Lasinio model, which has SU(3) R circle-times SU(3) L -symmetry in the chiral limit, mass splittings for spin 1/2 and spin 3/2 baryons are studied in the presence of an explicit chiral symmetry breaking strange quark mass. To this aim these strangeness carrying baryons are understood as SU(3)-rotational excitations of an SU(2)-embedded soliton solution. Therefore, within the framework of collective quantization, the fermion determinant with the strange quark mass is expanded up to the second order in the flavor rotation velocity and up to the first order in this quark mass. Besides the strange and non-strange moments of inertia, which have some counterparts within the Skyrme model, some so-called anomalous moments of inertia are obtained. These call be related to the imaginary part of the effective Euclidian action and contain among others the anomalous baryon current. This is shown in a gradient expansion up to the first non-vanishing order. Together with the Σ-commutator these are the solitonic ingredients of the collective hamiltonian, which is then diagonalized by means of strict perturbation theory in the strange quark mass and by the Yabu-Audo method. Both methods yield very good results for the masses of the spin 1/2 and 3/2 baryons. The former one reproduces some interesting mass formulas of Gell-Mann Okubo and Guadagnini and the latter one is able to describe the mass splittings up to a few MeV

Chiral Gold Nanoclusters: Atomic Level Origins of Chirality.

Science.gov (United States)

Zeng, Chenjie; Jin, Rongchao

2017-08-04

Chiral nanomaterials have received wide interest in many areas, but the exact origin of chirality at the atomic level remains elusive in many cases. With recent significant progress in atomically precise gold nanoclusters (e.g., thiolate-protected Au n (SR) m ), several origins of chirality have been unveiled based upon atomic structures determined by using single-crystal X-ray crystallography. The reported chiral Au n (SR) m structures explicitly reveal a predominant origin of chirality that arises from the Au-S chiral patterns at the metal-ligand interface, as opposed to the chiral arrangement of metal atoms in the inner core (i.e. kernel). In addition, chirality can also be introduced by a chiral ligand, manifested in the circular dichroism response from metal-based electronic transitions other than the ligand's own transition(s). Lastly, the chiral arrangement of carbon tails of the ligands has also been discovered in a very recent work on chiral Au 133 (SR) 52 and Au 246 (SR) 80 nanoclusters. Overall, the origins of chirality discovered in Au n (SR) m nanoclusters may provide models for the understanding of chirality origins in other types of nanomaterials and also constitute the basis for the development of various applications of chiral nanoparticles. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Rho meson decay width in SU(2) gauge theories with 2 fundamental flavours

CERN Document Server

Janowski, Tadeusz; Pica, Claudio

2016-01-01

SU(2) gauge theories with two quark flavours in the fundamental representation are among the most promising theories of composite dynamics describing the electroweak sector. Three out of five Goldstone bosons in these models become the longitudinal components of the W and Z bosons giving them mass. Like in QCD, we expect a spectrum of excitations which appear as resonances in vector boson scattering, in particular the vector resonance corresponding to the rho-meson in QCD. In this talk I will present the preliminary results of the first calculation of the rho-meson decay width in this theory, which is analogous to rho to two pions decay calculation in QCD. The results presented were calculated in a moving frame with total momentum (0,0,1) on two ensembles. Future plans include using 3 moving frames on a larger set of ensembles to extract the resonance parameters more reliably and also take the chiral and continuum limits.

Topology in the SU(Nf) chiral symmetry restored phase of unquenched QCD and axion cosmology

Science.gov (United States)

Azcoiti, Vicente

2018-03-01

The axion is one of the more interesting candidates to make the dark matter of the universe, and the axion potential plays a fundamental role in the determination of the dynamics of the axion field. Moreover, the way in which the U(1)A anomaly manifests itself in the chiral symmetry restored phase of QCD at high temperature could be tested when probing the QCD phase transition in relativistic heavy ion collisions. With these motivations, we investigate the physical consequences of the survival of the effects of the U(1)A anomaly in the chiral symmetric phase of QCD, and show that the free energy density is a singular function of the quark mass m, in the chiral limit, and that the σ and π susceptibilities diverge in this limit at any T ≥ Tc. We also show that the difference between the π and t;δ susceptibilities diverges in the chiral limit at any T ≥ Tc, a result that can be contrasted with the existing lattice calculations; and discuss on the generalization of these results to the Nf ≥ 3 model.

SU(2)xSU(2) coupling rule and a tensor glueball candidate

International Nuclear Information System (INIS)

Lanik, J.

1984-01-01

The data on the decay of THETA(1640) particles are considered. It is shown that the SU(2)xSU(2) mechanism for coupling of theta(1640) tensor glueball candidate to pseudoscalar Gold-stone mesons is in a remarkable agreement with existing experimental data

Chiral supramolecular organization from a sheet-like achiral gel: a study of chiral photoinduction.

Science.gov (United States)

Royes, Jorge; Polo, Víctor; Uriel, Santiago; Oriol, Luis; Piñol, Milagros; Tejedor, Rosa M

2017-05-31

Chiral photoinduction in a photoresponsive gel based on an achiral 2D architecture with high geometric anisotropy and low roughness has been investigated. Circularly polarized light (CPL) was used as a chiral source and an azobenzene chromophore was employed as a chiral trigger. The chiral photoinduction was studied by evaluating the preferential excitation of enantiomeric conformers of the azobenzene units. Crystallographic data and density functional theory (DFT) calculations show how chirality is transferred to the achiral azomaterials as a result of the combination of chiral photochemistry and supramolecular interactions. This procedure could be applied to predict and estimate chirality transfer from a chiral physical source to a supramolecular organization using different light-responsive units.

Interpolating Lagrangians and SU(2) gauge theory on the lattice

International Nuclear Information System (INIS)

Buckley, I.R.C.; Jones, H.F.

1992-01-01

We apply the linear δ expansion to non-Abelian gauge theory on the lattice, with SU(2) as the gauge group. We establish an appropriate parametrization and evaluate the average plaquette energy E P to O(δ). As a check on our results, we recover the large-β expansion up to O(1/β 2 ), which involves some O(δ 2 ) contributions. Using these contributions we construct a variant of the 1/β expansion which gives a good fit to the data down to the transition region

Chirality Made Simple: A 1 - and 2-Dimensional Introduction to Stereochemistry

Science.gov (United States)

Gawley, Robert E.

2005-01-01

The introduction of chirality in one and two dimensions, along with the concepts of internal and external reflection, can be combined with concepts familiar to all students. Once familiar with 1-Dimensional and 2-Dimensional chirality, the same concepts can be extended to 3-Dimensional and by projecting 3-D back to two, it is possible to interpret…

Enantiopure Ferrocene-Based Planar-Chiral Iridacycles: Stereospecific Control of Iridium-Centred Chirality.

Science.gov (United States)

Arthurs, Ross A; Ismail, Muhammad; Prior, Christopher C; Oganesyan, Vasily S; Horton, Peter N; Coles, Simon J; Richards, Christopher J

2016-02-24

Reaction of [IrCp*Cl2 ]2 with ferrocenylimines (Fc=NAr, Ar=Ph, p-MeOC6 H4 ) results in ferrocene C-H activation and the diastereoselective synthesis of half-sandwich iridacycles of relative configuration Sp *,RIr *. Extension to (S)-2-ferrocenyl-4-(1-methylethyl)oxazoline gave highly diastereoselective control over the new elements of planar chirality and metal-based pseudo-tetrahedral chirality, to give both neutral and cationic half-sandwich iridacycles of absolute configuration Sc ,Sp ,RIr . Substitution reactions proceed with retention of configuration, with the planar chirality controlling the metal-centred chirality through an iron-iridium interaction in the coordinatively unsaturated cationic intermediate. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Chiral Cliffs: Investigating the Influence of Chirality on Binding Affinity.

Science.gov (United States)

Schneider, Nadine; Lewis, Richard A; Fechner, Nikolas; Ertl, Peter

2018-05-11

Chirality is understood by many as a binary concept: a molecule is either chiral or it is not. In terms of the action of a structure on polarized light, this is indeed true. When examined through the prism of molecular recognition, the answer becomes more nuanced. In this work, we investigated chiral behavior on protein-ligand binding: when does chirality make a difference in binding activity? Chirality is a property of the 3D structure, so recognition also requires an appreciation of the conformation. In many situations, the bioactive conformation is undefined. We set out to address this by defining and using several novel 2D descriptors to capture general characteristic features of the chiral center. Using machine-learning methods, we built different predictive models to estimate if a chiral pair (a set of two enantiomers) might exhibit a chiral cliff in a binding assay. A set of about 3800 chiral pairs extracted from the ChEMBL23 database was used to train and test our models. By achieving an accuracy of up to 75 %, our models provide good performance in discriminating chiral cliffs from non-cliffs. More importantly, we were able to derive some simple guidelines for when one can reasonably use a racemate and when an enantiopure compound is needed in an assay. We critically discuss our results and show detailed examples of using our guidelines. Along with this publication we provide our dataset, our novel descriptors, and the Python code to rebuild the predictive models. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Chiral symmetry and chiral-symmetry breaking

International Nuclear Information System (INIS)

Peskin, M.E.

1982-12-01

These lectures concern the dynamics of fermions in strong interaction with gauge fields. Systems of fermions coupled by gauge forces have a very rich structure of global symmetries, which are called chiral symmetries. These lectures will focus on the realization of chiral symmetries and the causes and consequences of thier spontaneous breaking. A brief introduction to the basic formalism and concepts of chiral symmetry breaking is given, then some explicit calculations of chiral symmetry breaking in gauge theories are given, treating first parity-invariant and then chiral models. These calculations are meant to be illustrative rather than accurate; they make use of unjustified mathematical approximations which serve to make the physics more clear. Some formal constraints on chiral symmetry breaking are discussed which illuminate and extend the results of our more explicit analysis. Finally, a brief review of the phenomenological theory of chiral symmetry breaking is presented, and some applications of this theory to problems in weak-interaction physics are discussed

Tumbling and complementarity in a chiral gauge theory

International Nuclear Information System (INIS)

Goity, J.; Peccei, R.D.; Zeppenfeld, D.

1985-06-01

We consider in detail a chiral SU(N) gauge theory which undergoes multiple tumbling. An extension of the notion of complementarity is used which allows us to deduce the set of massless fermions, in the confining phase of the theory, which we needed for anomaly matching. The likelyhood of this confining phase ever being realized in practice is discussed. (orig.)

Gelation induced supramolecular chirality: chirality transfer, amplification and application.

Science.gov (United States)

Duan, Pengfei; Cao, Hai; Zhang, Li; Liu, Minghua

2014-08-14

Supramolecular chirality defines chirality at the supramolecular level, and is generated from the spatial arrangement of component molecules assembling through non-covalent interactions such as hydrogen bonding, van der Waals interactions, π-π stacking, hydrophobic interactions and so on. During the formation of low molecular weight gels (LMWGs), one kind of fascinating soft material, one frequently encounters the phenomenon of chirality as well as chiral nanostructures, either from chiral gelators or even achiral gelators. A view of gelation-induced supramolecular chirality will be very helpful to understand the self-assembly process of the gelator molecules as well as the chiral structures, the regulation of the chirality in the gels and the development of the "smart" chiral materials such as chiroptical devices, catalysts and chiral sensors. It necessitates fundamental understanding of chirality transfer and amplification in these supramolecular systems. In this review, recent progress in gelation-induced supramolecular chirality is discussed.

A three-flavor chiral effective model with four baryonic multiplets within the mirror assignment

Energy Technology Data Exchange (ETDEWEB)

Olbrich, Lisa; Zetenyi, Miklos; Giacosa, Francesco; Rischke, Dirk H. [Institute for Theoretical Physics, Goethe University Frankfurt am Main (Germany)

2016-07-01

Chiral symmetry requires the existence of chiral partners in the hadronic mass spectrum. In this talk, we address the question which is the chiral partner of the nucleon. We employ a chirally symmetric linear sigma model, where hadrons and their chiral partners are treated on the same footing. We construct four spin-1/2 baryon multiplets from left- and right-handed quarks as well as left- and right-handed diquarks. Two of these multiplets transform in a ''mirror'' way, which allows for chirally invariant mass terms. We then embed these baryonic multiplets into the Lagrangian of the extended Linear Sigma Model, which features (pseudo)scalar and (axial-)vector mesons, as well as glueballs. Reducing the Lagrangian to the two-flavor case, we obtain four doublets of nucleonic states. These mix to produce the positive-parity nucleon N(939) and the Roper resonance N(1440), as well as the negative-parity resonances N(1535) and N(1650). We determine the parameters of the nucleonic part of the Lagrangian from a fit to masses and decay properties of these states. Studying the limit of vanishing quark condensate, we conclude that N(939) and N(1535), as well as N(1440) and N(1650) form pairs of chiral partners.

Hidden charged dark matter and chiral dark radiation

Science.gov (United States)

Ko, P.; Nagata, Natsumi; Tang, Yong

2017-10-01

In the light of recent possible tensions in the Hubble constant H0 and the structure growth rate σ8 between the Planck and other measurements, we investigate a hidden-charged dark matter (DM) model where DM interacts with hidden chiral fermions, which are charged under the hidden SU(N) and U(1) gauge interactions. The symmetries in this model assure these fermions to be massless. The DM in this model, which is a Dirac fermion and singlet under the hidden SU(N), is also assumed to be charged under the U(1) gauge symmetry, through which it can interact with the chiral fermions. Below the confinement scale of SU(N), the hidden quark condensate spontaneously breaks the U(1) gauge symmetry such that there remains a discrete symmetry, which accounts for the stability of DM. This condensate also breaks a flavor symmetry in this model and Nambu-Goldstone bosons associated with this flavor symmetry appear below the confinement scale. The hidden U(1) gauge boson and hidden quarks/Nambu-Goldstone bosons are components of dark radiation (DR) above/below the confinement scale. These light fields increase the effective number of neutrinos by δNeff ≃ 0.59 above the confinement scale for N = 2, resolving the tension in the measurements of the Hubble constant by Planck and Hubble Space Telescope if the confinement scale is ≲1 eV. DM and DR continuously scatter with each other via the hidden U(1) gauge interaction, which suppresses the matter power spectrum and results in a smaller structure growth rate. The DM sector couples to the Standard Model sector through the exchange of a real singlet scalar mixing with the Higgs boson, which makes it possible to probe our model in DM direct detection experiments. Variants of this model are also discussed, which may offer alternative ways to investigate this scenario.

Chiral plaquette polaron theory of cuprate superconductivity

Science.gov (United States)

Tahir-Kheli, Jamil; Goddard, William A., III

2007-07-01

Ab initio density functional calculations on explicitly doped La2-xSrxCuO4 find that doping creates localized holes in out-of-plane orbitals. A model for cuprate superconductivity is developed based on the assumption that doping leads to the formation of holes on a four-site Cu plaquette composed of the out-of-plane A1 orbitals apical Opz , planar Cud3z2-r2 , and planar Opσ . This is in contrast to the assumption of hole doping into planar Cudx2-y2 and Opσ orbitals as in the t-J model. Allowing these holes to interact with the d9 spin background leads to chiral polarons with either a clockwise or anticlockwise charge current. When the polaron plaquettes percolate through the crystal at x≈0.05 for La2-xSrxCuO4 , a Cudx2-y2 and planar Opσ band is formed. The computed percolation doping of x≈0.05 equals the observed transition to the “metallic” and superconducting phase for La2-xSrxCuO4 . Spin exchange Coulomb repulsion with chiral polarons leads to d -wave superconducting pairing. The equivalent of the Debye energy in phonon superconductivity is the maximum energy separation between a chiral polaron and its time-reversed partner. This energy separation is on the order of the antiferromagnetic spin coupling energy, Jdd˜0.1eV , suggesting a higher critical temperature. An additive skew-scattering contribution to the Hall effect is induced by chiral polarons and leads to a temperature dependent Hall effect that fits the measured values for La2-xSrxCuO4 . The integrated imaginary susceptibility, observed by neutron spin scattering, satisfies ω/T scaling due to chirality and spin-flip scattering of polarons along with a uniform distribution of polaron energy splittings. The derived functional form is compatible with experiments. The static spin structure factor for chiral spin coupling of the polarons to the undoped antiferromagnetic Cud9 spins is computed for classical spins on large two-dimensional lattices and is found to be incommensurate with a

Chiral Responsive Liquid Quantum Dots.

Science.gov (United States)

Zhang, Jin; Ma, Junkai; Shi, Fangdan; Tian, Demei; Li, Haibing

2017-08-01

How to convert the weak chiral-interaction into the macroscopic properties of materials remains a huge challenge. Here, this study develops highly fluorescent, selectively chiral-responsive liquid quantum dots (liquid QDs) based on the hydrophobic interaction between the chiral chains and the oleic acid-stabilized QDs, which have been designated as (S)-1810-QDs. The fluorescence spectrum and liquidity of thermal control demonstrate the fluorescence properties and the fluidic behavior of (S)-1810-QDs in the solvent-free state. Especially, (S)-1810-QDs exhibit a highly chiral-selective response toward (1R, 2S)-2-amino-1,2-diphenyl ethanol. It is anticipated that this study will facilitate the construction of smart chiral fluidic sensors. More importantly, (S)-1810-QDs can become an attractive material for chiral separation. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Toy model for two chiral nonets

International Nuclear Information System (INIS)

Fariborz, Amir H.; Jora, Renata; Schechter, Joseph

2005-01-01

Motivated by the possibility that nonets of scalar mesons might be described as mixtures of 'two quark' and 'four quark' components, we further study a toy model in which corresponding chiral nonets (containing also the pseudoscalar partners) interact with each other. Although the 'two quark' and 'four quark' chiral fields transform identically under SU(3) L xSU(3) R transformations, they transform differently under the U(1) A transformation which essentially counts total (quark+antiquark) content of the mesons. To implement this, we formulate an effective Lagrangian which mocks up the U(1) A behavior of the underlying QCD. We derive generating equations which yield Ward identity type relations based only on the assumed symmetry structure. This is applied to the mass spectrum of the low lying pseudoscalars and scalars, as well as their 'excitations'. Assuming isotopic spin invariance, it is possible to disentangle the amount of 'two quark' vs 'four quark' content in the pseudoscalar π,K,η-type states and in the scalar κ-type states. It is found that a small 'four quark' content in the lightest pseudoscalars is consistent with a large 'four quark' content in the lightest of the scalar κ mesons. The present toy model also allows one to easily estimate the strength of a 'four quark' vacuum condensate. There seems to be a rich and interesting structure

Chirality: from QCD to condensed matter

International Nuclear Information System (INIS)

Kharzeev, D.

2015-01-01

This lecture is about chirality and consists of 4 parts. In the first part a general introduction of chirality is given and its implementation in nuclear and particle physics, in particular the chiral magnetic effect, as well as Chirality in quantum materials (CME, optoelectronics, photonics) are discussed. The 2nd lecture is about the chiral magnetic effect. The 3rd lecture deals with the chiral magnetic effect and hydrodynamics and the last part with chirality and light. (nowak)

Axions from chiral family symmetry

International Nuclear Information System (INIS)

Chang, D.; Pal, P.B.; Maryland Univ., College Park; Senjanovic, G.

1985-01-01

We investigate the possibility that family symmetry, Gsub(F), is spontaneously broken chiral global symmetry. We classify the interesting cases when family symmetry can result in an automatic Peccei-Quinn symmetry U(1)sub(PQ) and thus provide a solution to the strong CP problem. The result disfavors having two or four families. For more than four families, U(1)sub(PQ) is in general automatic. In the case of three families, a unique Higgs sector allows U(1)sub(PQ) in the simplest case of Gsub(F)=[SU(3)] 3 . Cosmological consideration also puts strong constraint on the number of families. For Gsub(F)=[SU(N)] 3 cosmology singles out the three-family (N=3) case as a unique solution if there are three light neutrinos. Possible implication of decoupling theorem as applied to family symmetry breaking is also discussed. (orig.)

Chiral polarization scale of QCD vacuum and spontaneous chiral symmetry breaking

International Nuclear Information System (INIS)

Alexandru, Andrei; Horv, Ivan

2013-01-01

It has recently been found that dynamics of pure glue QCD supports the low energy band of Dirac modes with local chiral properties qualitatively different from that of a bulk: while bulk modes suppress chirality relative to statistical independence between left and right, the band modes enhance it. The width of such chirally polarized zone – chiral polarization scale bigwedge ch – has been shown to be finite in the continuum limit at fixed physical volume. Here we present evidence that bigwedge ch remains non-zero also in the infinite volume, and is therefore a dynamical scale in the theory. Our experiments in N f = 2+1 QCD support the proposition that the same holds in the massless limit, connecting bigwedge ch to spontaneous chiral symmetry breaking. In addition, our results suggest that thermal agitation in quenched QCD destroys both chiral polarization and condensation of Dirac modes at the same temperature T ch > T c .

On chiral and non chiral 1D supermultiplets

Energy Technology Data Exchange (ETDEWEB)

Toppan, Francesco, E-mail: toppan@cbpf.b [Centro Brasileiro de Pesquisas Fisicas (TEO/CBPF), Rio de Janeiro, RJ (Brazil). Coordenacao de Fisica Teorica

2011-07-01

In this talk I discuss and clarify some issues concerning chiral and non chiral properties of the one-dimensional supermultiplets of the N-extended supersymmetry. Quaternionic chirality can be defined for N = 4, 5, 6, 7, 8. Octonionic chirality for N = 8 and beyond. Inequivalent chiralities only arise when considering several copies of N = 4 or N = 8 supermultiplets. (author)

On chiral and non chiral 1D supermultiplets

International Nuclear Information System (INIS)

Toppan, Francesco

2011-01-01

In this talk I discuss and clarify some issues concerning chiral and non chiral properties of the one-dimensional supermultiplets of the N-extended supersymmetry. Quaternionic chirality can be defined for N = 4, 5, 6, 7, 8. Octonionic chirality for N = 8 and beyond. Inequivalent chiralities only arise when considering several copies of N = 4 or N = 8 supermultiplets. (author)

Charge radii of octet and decuplet baryons in chiral constituent ...

Indian Academy of Sciences (India)

in electron–baryon scattering experiments [4,5] giving rp = 0.877 ± 0.007 fm ... breaking of the SU(3) symmetry and a non-vanishing neutron charge mean square radius ... QCD Lagrangian is not invariant under the chiral transformation. ... of a constituent quark GBs [34–37], successfully explains the 'proton spin problem'.

Fabrication of Supramolecular Chirality from Achiral Molecules at the Liquid/Liquid Interface Studied by Second Harmonic Generation.

Science.gov (United States)

Lin, Lu; Zhang, Zhen; Guo, Yuan; Liu, Minghua

2018-01-09

We present the investigation into the supramolecular chirality of 5-octadecyloxy-2-(2-pyridylazo)phenol (PARC18) at water/1,2-dichloroethane interface by second harmonic generation (SHG). We observe that PARC18 molecules form supramolecular chirality through self-assembly at the liquid/liquid interface although they are achiral molecules. The bulk concentration of PARC18 in the organic phase has profound effects on the supramolecular chirality. By increasing bulk concentration, the enantiomeric excess at the interface first grows and then decreases until it eventually vanishes. Further analysis reveals that the enantiomeric excess is determined by the twist angle of PARC18 molecules at the interface rather than their orientational angle. At lower and higher bulk concentrations, the average twist angle of PARC18 molecules approaches zero, and the assemblies are achiral; whereas at medium bulk concentrations, the average twist angle is nonzero, so that the assemblies show supramolecular chirality. We also estimate the coverage of PARC18 molecules at the interface versus the bulk concentration and fit it to Langmuir adsorption model. The result indicates that PARC18 assemblies show strongest supramolecular chirality in a half-full monolayer. These findings highlight the opportunities for precise control of supramolecular chirality at liquid/liquid interfaces by manipulating the bulk concentration.

Chiral Dynamics 2006

Science.gov (United States)

Ahmed, Mohammad W.; Gao, Haiyan; Weller, Henry R.; Holstein, Barry

2007-10-01

pt. A. Plenary session. Opening remarks: experimental tests of chiral symmetry breaking / A. M. Bernstein. [Double pie symbols] scattering / H. Leutwyler. Chiral effective field theory in a [Triangle]-resonance region / V. Pascalutsa. Some recent developments in chiral perturbation theory / Ulf-G. Mei ner. Chiral extrapolation and nucleon structure from the lattice / R.D. Young. Recent results from HAPPEX / R. Michaels. Chiral symmetries and low energy searches for new physics / M.J. Ramsey-Musolf. Kaon physics: recent experimental progress / M. Moulson. Status of the Cabibbo angle / V. Cirigliano. Lattice QCD and nucleon spin structure / J.W. Negele. Spin sum rules and polarizabilities: results from Jefferson lab / J-P Chen. Compton scattering and nucleon polarisabilities / Judith A. McGovern. Virtual compton scattering at MIT-bates / R. Miskimen. Physics results from the BLAST detector at the BATES accelerator / R.P. Redwine. The [Pie sympbol]NN system, recent progress / C. Hanhart. Application of chiral nuclear forces to light nuclei / A. Nogga. New results on few-body experiments at low energy / Y. Nagai. Few-body lattice calculations / M.J. Savage. Research opportunities at the upgraded HI?S facility / H.R. Weller -- pt. B. Goldstone boson dynamics. Working group summary: Goldstone Boson dynamics / G. Colangelo and S. Giovannella. Recent results on radiative Kaon decays from NA48 and NA48/2 / S.G. López. Cusps in K-->3 [Pie symbol] decays / B. Kubis. Recent KTeV results on radiative Kaon decays / M.C. Ronquest. The [Double pie symbols] scattering amplitude / J.R. Peláez. Determination of the Regge parameters in the [Double pie symbols] scattering amplitude / I. Caprini. e+e- Hadronic cross section measurement at DA[symbol]NE with the KLOE detector / P. Beltrame. Measurement of the form factors of e+e- -->2([Pie symbol]+[Pie symbol]-), pp and the resonant parameters of the heavy charmonia at BES / H. Hu. Measurement of e+e- multihadronic cross section below 4

Studies on phenomenological hadron models with chiral symmetry

International Nuclear Information System (INIS)

Rathske, E.

1991-12-01

In this report we consider, in the context of phenomenological models for hadrons, several aspects of Skyrme-type and hybrid bag models. In the first of the two central parts we discuss two qualitatively different generalizations of the minimal SU(2) Skyrme model. One of these consists in adding to the Lagrangian density a symmetric term of fourth order in the field derivatives. Its consequences are determined for solutions and observables by analytical and numerical investigations. In the other we propose a contribution for explicit isospin symmetry breaking in the mesonic as well as the baryonic sector. Together with the standard nonlinear σ-model term it allows for exact time-dependent classical soliton solutions. Their quantization leads to a quantitative connection between the hadronic isospin mass differenced of pions and nucleons. The second main part of this report is devoted to the generalization of SU(2) bag models under the aspect of chiral symmetry. We first show that the construction of appropriate surface terms in the Lagrangian density necessitates the introduction of dynamical bosonic degrees of freedom. This allows for a variety of bag scenarios (including the 'endopionic' bag). We then consider explicit isospin symmetry breaking for hybrid bag models with a nonlinear mesonic sector. An intimate relationship is revealed between the effects of a quark mass difference and the time-dependent bosonic solutions found for the purely mesonic case. It is reflected in a nontrivial interdependence between quark and meson masses, bag radius and chiral angle. We provide an especially extensive list of references for the topics discussed in this report. (orig.) [de

On the chirality of the SM and the fermion content of GUTs

Directory of Open Access Journals (Sweden)

Renato M. Fonseca

2015-08-01

Full Text Available The Standard Model (SM is a chiral theory, where right- and left-handed fermion fields transform differently under the gauge group. Extra fermions, if they do exist, need to be heavy otherwise they would have already been observed. With no complex mechanisms at work, such as confining interactions or extra-dimensions, this can only be achieved if every extra right-handed fermion comes paired with a left-handed one transforming in the same way under the Standard Model gauge group, otherwise the new states would only get a mass after electroweak symmetry breaking, which would necessarily be small (∼100 GeV. Such a simple requirement severely constrains the fermion content of Grand Unified Theories (GUTs. It is known for example that three copies of the representations 5¯+10 of SU(5 or three copies of the 16 of SO(10 can reproduce the Standard Model's chirality, but how unique are these arrangements? In a systematic way, this paper looks at the possibility of having non-standard mixtures of fermion GUT representations yielding the correct Standard Model chirality. Family unification is possible with large special unitary groups — for example, the 171 representation of SU(19 may decompose as 3(16+120+3(1 under SO(10.

Influence of microemulsion chirality on chromatographic figures of merit in EKC: results with novel three-chiral-component microemulsions and comparison with one- and two-chiral-component microemulsions.

Science.gov (United States)

Kahle, Kimberly A; Foley, Joe P

2007-08-01

Novel microemulsion formulations containing all chiral components are described for the enantioseparation of six pairs of pharmaceutical enantiomers (atenolol, ephedrine, metoprolol, N-methyl ephedrine, pseudoephedrine, and synephrine). The chiral surfactant dodecoxycarbonylvaline (DDCV, R- and S-), the chiral cosurfactant S-2-hexanol, and the chiral oil diethyl tartrate (R- and S-) were combined to create four different chiral microemulsions, three of which were stable. Results obtained for enantioselectivity, efficiency, and resolution were compared for the triple-chirality systems and the single-chirality system that contained chiral surfactant only. Improvements in enantioselectivity and resolution were achieved by simultaneously incorporating three chiral components into the aggregate. The one-chiral-component microemulsion provided better efficiencies. Enantioselective synergies were identified for the three-chiral-component nanodroplets using a thermodynamic model. Additionally, two types of dual-chirality systems, chiral surfactant/chiral cosurfactant and chiral surfactant/chiral oil, were examined in terms of chromatographic figures of merit, with the former providing much better resolution. The two varieties of two-chiral-component microemulsions gave similar values for enantioselectivity and efficiency. Lastly, the microemulsion formulations were divided into categories based on the number of chiral microemulsion reagents and the average results for each pair of enantiomers were analyzed for trends. In general, enantioselectivity and resolution were enhanced while efficiency was decreased as more chiral components were used to create the pseudostationary phase (PSP).

Chiral gas chromatography for the determination of 1,2-O-isopropylidene-sn-glycerol stereoisomers

NARCIS (Netherlands)

Dröge, M.J; Bos, R.; Woerdenbag, H.J.; Quax, Wim; Droge, MJ

2003-01-01

A stereospecific gas chromatography (GC) method using a (6-O-tButyldimethylsilyl-2,3-di-O-methyl)-beta-cyclodextrin as the chiral stationary phase has been developed and validated for the determination of the enantiomers of 1,2-O-isopropylidene-sn-glycerol (IPG), an important chiral synthon, in

Independent SU(2)-loop variables

International Nuclear Information System (INIS)

Loll, R.

1991-04-01

We give a reduction procedure for SU(2)-trace variables and introduce a complete set of indepentent, gauge-invariant and almost local loop variables for the configuration space of SU(2)-lattice gauge theory in 2+1 dimensions. (orig.)

Computation of the chiral condensate using Nf=2 and Nf=2+1+1 dynamical flavors of twisted mass fermions

International Nuclear Information System (INIS)

Cichy, K.; Jansen, K.; Shindler, A.; Forschungszentrum Juelich; Forschungszentrum Juelich

2013-12-01

We apply the spectral projector method, recently introduced by Giusti and Luescher, to compute the chiral condensate using N f =2 and N f =2+1+1 dynamical flavors of maximally twisted mass fermions. We present our results for several quark masses at three different lattice spacings which allows us to perform the chiral and continuum extrapolations. In addition we report our analysis on the O(a) improvement of the chiral condensate for twisted mass fermions. We also study the effect of the dynamical strange and charm quarks by comparing our results for N f =2 and N f =2+1+1 dynamical flavors.

The half-skyrmion phase in a chiral-quark model

International Nuclear Information System (INIS)

Mantovani Sarti, Valentina; Vento, Vicente

2014-01-01

The Chiral Dilaton Model, where baryons arise as non-topological solitons built from the interaction of quarks and chiral mesons, shows in the high density low temperature regime a two phase scenario in the nuclear matter phase diagram. Dense soliton matter described by the Wigner–Seitz approximation generates a periodic potential in terms of the sigma and pion fields that leads to the formation of a band structure. The analysis up to three times nuclear matter density shows that soliton matter undergoes two separate phase transitions: a delocalization of the baryon number density leading to B=1/2 structures, as in skyrmion matter, at moderate densities, and quark deconfinement at larger densities. This description fits well into the so-called quarkyonic phase where, before deconfinement, nuclear matter should undergo structural changes involving the restoration of fundamental symmetries of QCD

Transfer and Dynamic Inversion of Coassembled Supramolecular Chirality through 2D-Sheet to Rolled-Up Tubular Structure.

Science.gov (United States)

Choi, Heekyoung; Cho, Kang Jin; Seo, Hyowon; Ahn, Junho; Liu, Jinying; Lee, Shim Sung; Kim, Hyungjun; Feng, Chuanliang; Jung, Jong Hwa

2017-12-13

Transfer and inversion of supramolecular chirality from chiral calix[4]arene analogs (3D and 3L) with an alanine moiety to an achiral bipyridine derivative (1) with glycine moieties in a coassembled hydrogel are demonstrated. Molecular chirality of 3D and 3L could transfer supramolecular chirality to an achiral bipyridine derivative 1. Moreover, addition of 0.6 equiv of 3D or 3L to 1 induced supramolecular chirality inversion of 1. More interestingly, the 2D-sheet structure of the coassembled hydrogels formed with 0.2 equiv of 3D or 3L changed to a rolled-up tubular structure in the presence of 0.6 equiv of 3D or 3L. The chirality inversion and morphology change are mainly mediated by intermolecular hydrogen-bonding interactions between the achiral and chiral molecules, which might be induced by reorientations of the assembled molecules, confirmed by density functional theory calculations.

Chiral correlators in Landau-Ginsburg theories and N=2 superconformal models

International Nuclear Information System (INIS)

Howe, P.S.; West, P.C.

1989-01-01

Chiral correlation functions are computed in N=2 Landau-Ginsburg models using the ε-expansion and the superconformal Ward identities for the Landau-Ginsburg effective action. They are also computed directly using superconformal model techniques. The same results are obtained yielding further confirmation of the identification of superconformal minimal models with Landau-Ginsburg models evaluated at their fixed points. The formulae for the chiral commutators that we compute are extremely simple when expressed in terms of effective actions. (orig.)

Flipped SU(5) from D-branes with type IIB fluxes

Energy Technology Data Exchange (ETDEWEB)

Chen Chingming [George P. and Cynthia W. Mitchell Institute for Fundamental Physics, Texas A and M University, College Station, TX 77843 (United States)]. E-mail: cchen@physics.tamu.edu; Mayes, V.E. [George P. and Cynthia W. Mitchell Institute for Fundamental Physics, Texas A and M University, College Station, TX 77843 (United States)]. E-mail: eric@physics.tamu.edu; Nanopoulos, D.V. [George P. and Cynthia W. Mitchell Institute for Fundamental Physics, Texas A and M University, College Station, TX 77843 (United States) and Astroparticle Physics Group, Houston Advanced Research Center (HARC), Mitchell Campus, Woodlands, TX 77381 (United States) and Academy of Athens, Division of Natural Sciences, 28 Panepistimiou Avenue, Athens 10679 (Greece)]. E-mail: dimitri@physics.tamu.edu

2006-02-16

We construct flipped SU(5) GUT models as type IIB flux vacua on Z{sub 2}xZ{sub 2} orientifolds. Turning on supergravity self-dual NSNS and RR three-form fluxes fixes the toroidal complex structure moduli and the dilaton. We give a specific example of a three-generation flipped SU(5) model with a complete Higgs sector where supersymmetry is softly broken by the supergravity fluxes in the closed string sector. All of the required Yukawa couplings are present if global U(1) factors resulting from a generalized Green-Schwarz mechanism are broken spontaneously or by world-sheet instantons. In addition, the model contains extra chiral and vector-like matter, potentially of mass O(M{sub string}) via trilinear superpotential couplings.

Self consistent propagation of hyperons and antikaons in nuclear matter based on relativistic chiral SU(3) dynamics

International Nuclear Information System (INIS)

Lutz, M.F.M.; Korpa, C.L.

2001-05-01

We evaluate the antikaon spectral density in isospin symmetric nuclear matter. The in-medium antikaon-nucleon scattering process and the antikaon propagation is treated in a self consistent and relativistic manner where a maximally scheme-independent formulation is derived by performing a partial density resummation in terms of the free-space antikaon-nucleon scattering amplitudes. The latter amplitudes are taken from a relativistic and chiral coupled-channel SU(3) approach which includes s-, p- and d-waves systematically. Particular care is taken on the proper evaluation of the in-medium mixing of the partial waves. Our analysis establishes a rich structure of the antikaon spectral function with considerable strength at small energies. At nuclear saturation density we predict attractive mass shifts for the Λ(1405), Σ(1385) and Λ(1520) of about 130 MeV, 60 MeV and 100 MeV respectively. The hyperon states are found to exhibit at the same time an increased decay width of about 150 MeV for the s-wave Λ(1405), 70 MeV for the p-wave Σ(1385) and 100 MeV for the d-wave Λ(1520) resonance. (orig.)

Chiral algebras for trinion theories

International Nuclear Information System (INIS)

Lemos, Madalena; Peelaers, Wolfger

2015-01-01

It was recently understood that one can identify a chiral algebra in any four-dimensional N=2 superconformal theory. In this note, we conjecture the full set of generators of the chiral algebras associated with the T n theories. The conjecture is motivated by making manifest the critical affine module structure in the graded partition function of the chiral algebras, which is computed by the Schur limit of the superconformal index for T n theories. We also explicitly construct the chiral algebra arising from the T 4 theory. Its null relations give rise to new T 4 Higgs branch chiral ring relations.

Finite size giant magnons in the SU(2) x SU(2) sector of AdS4 x CP3

International Nuclear Information System (INIS)

Lukowski, Tomasz; Sax, Olof Ohlsson

2008-01-01

We use the algebraic curve and Luescher's μ-term to calculate the leading order finite size corrections to the dispersion relation of giant magnons in the SU(2) x SU(2) sector of AdS 4 x CP 3 . We consider a single magnon as well as one magnon in each SU(2). In addition the algebraic curve computation is generalized to give the leading order correction for an arbitrary multi-magnon state in the SU(2) x SU(2) sector.

Path integrals and coherent states of SU(2) and SU(1,1)

CERN Document Server

Inomata, Akira; Kuratsuji, Hiroshi

1992-01-01

The authors examine several topical subjects, commencing with a general introduction to path integrals in quantum mechanics and the group theoretical backgrounds for path integrals. Applications of harmonic analysis, polar coordinate formulation, various techniques and path integrals on SU(2) and SU(1, 1) are discussed. Soluble examples presented include particle-flux system, a pulsed oscillator, magnetic monopole, the Coulomb problem in curved space and others.The second part deals with the SU(2) coherent states and their applications. Construction and generalization of the SU(2) coherent sta

Chiral properties of baryon interpolating fields

International Nuclear Information System (INIS)

Nagata, Keitaro; Hosaka, Atsushi; Dmitrasinovic, V.

2008-01-01

We study the chiral transformation properties of all possible local (non-derivative) interpolating field operators for baryons consisting of three quarks with two flavors, assuming good isospin symmetry. We derive and use the relations/identities among the baryon operators with identical quantum numbers that follow from the combined color, Dirac and isospin Fierz transformations. These relations reduce the number of independent baryon operators with any given spin and isospin. The Fierz identities also effectively restrict the allowed baryon chiral multiplets. It turns out that the non-derivative baryons' chiral multiplets have the same dimensionality as their Lorentz representations. For the two independent nucleon operators the only permissible chiral multiplet is the fundamental one, ((1)/(2),0)+(0,(1)/(2)). For the Δ, admissible Lorentz representations are (1,(1)/(2))+((1)/(2),1) and ((3)/(2),0)+(0,(3)/(2)). In the case of the (1,(1)/(2))+((1)/(2),1) chiral multiplet, the I(J)=(3)/(2)((3)/(2)) Δ field has one I(J)=(1)/(2)((3)/(2)) chiral partner; otherwise it has none. We also consider the Abelian (U A (1)) chiral transformation properties of the fields and show that each baryon comes in two varieties: (1) with Abelian axial charge +3; and (2) with Abelian axial charge -1. In case of the nucleon these are the two Ioffe fields; in case of the Δ, the (1,(1)/(2))+((1)/(2),1) multiplet has an Abelian axial charge -1 and the ((3)/(2),0)+(0,(3)/(2)) multiplet has an Abelian axial charge +3. (orig.)

Electromagnetic structure of the lowest-lying decuplet resonances in covariant chiral perturbation theory

International Nuclear Information System (INIS)

Geng, L. S.; Camalich, J. Martin; Vacas, M. J. Vicente

2009-01-01

We present a calculation of the leading SU(3)-breaking O(p 3 ) corrections to the electromagnetic moments and charge radius of the lowest-lying decuplet resonances in covariant chiral perturbation theory. In particular, the magnetic dipole moment of the members of the decuplet is predicted fixing the only low-energy constant (LEC) present up to this order with the well-measured magnetic dipole moment of the Ω - . We predict μ Δ ++ =6.04(13) and μ Δ + =2.84(2), which agree well with the current experimental information. For the electric quadrupole moment and the charge radius, we use state-of-the-art lattice QCD results to determine the corresponding LECs, whereas for the magnetic octupole moment there is no unknown LEC up to the order considered here, and we obtain a pure prediction. We compare our results with those reported in large N c , lattice QCD, heavy-baryon chiral perturbation theory, and other models.

Inflation and monopoles in supersymmetric SU(4)c x SU(2)L x SU(2)R

International Nuclear Information System (INIS)

Jeannerot, R.; Khalil, S.; Lazarides, G.; Shafi, Q.

2000-02-01

We show how hybrid inflation can be successfully realized in a supersymmetric model with gauge group G PS = SU(4) c x SU(2) L x SU(2) R . By including a non-renormalizable superpotential term, we generate an inflationary valley along which G PS is broken to the standard model gauge group. Thus, catastrophic production of the doubly charged magnetic monopoles, which are predicted by the model, cannot occur at the end of inflation. The results of the cosmic background explorer can be reproduced with natural values (of order 10 -3 ) of the relevant coupling constant, and symmetry breaking scale of G PS close to 10 16 GeV. The spectral index of density perturbations lies between unity and 0.94. Moreover, the μ-term is generated via a Peccei-Quinn symmetry and proton is practically stable. Baryogenesis in the universe takes place via leptogenesis. The low deuterium abundance constraint on the baryon asymmetry, the gravitino limit on the reheat temperature and the requirement of almost maximal ν μ - ν τ mixing from SuperKamiokande can be simultaneously met with m νμ , m ντ and heaviest Dirac neutrino mass determined from the large angle MSW resolution of the solar neutrino problem, the SuperKamiokande results and SU(4) c symmetry respectively. (author)

Anomaly constraints on deconfinement and chiral phase transition

Science.gov (United States)

Shimizu, Hiroyuki; Yonekura, Kazuya

2018-05-01

We study the constraints on thermal phase transitions of SU (Nc) gauge theories by using the 't Hooft anomaly involving the center symmetry and chiral symmetry. We consider two cases of massless fermions: (i) adjoint fermions and (ii) Nf flavors of fundamental fermions with a nontrivial greatest common divisor, gcd (Nc,Nf)≠1 . For the first case (i), we show that the chiral symmetry restoration in terms of the standard Landau-Ginzburg effective action is impossible at a temperature lower than that of deconfinement. For the second case (ii), we introduce a modified version of the center symmetry, which we call center-flavor symmetry, and draw similar conclusions under a certain definition of confinement. Moreover, at zero temperature, our results give a partial explanation of the appearance of dual magnetic gauge groups in (supersymmetric) QCD when gcd (Nc,Nf)≠1 .

Chiral and continuum extrapolation of partially-quenched hadron masses

International Nuclear Information System (INIS)

Chris Allton; Wes Armour; Derek Leinweber; Anthony Thomas; Ross Young

2005-01-01

Using the finite-range regularization (FRR) of chiral effective field theory, the chiral extrapolation formula for the vector meson mass is derived for the case of partially-quenched QCD. We re-analyze the dynamical fermion QCD data for the vector meson mass from the CP-PACS collaboration. A global fit, including finite lattice spacing effects, of all 16 of their ensembles is performed. We study the FRR method together with a naive polynomial approach and find excellent agreement (∼1%) with the experimental value of M ρ from the former approach. These results are extended to the case of the nucleon mass

Chiral and continuum extrapolation of partially-quenched hadron masses

Energy Technology Data Exchange (ETDEWEB)

Chris Allton; Wes Armour; Derek Leinweber; Anthony Thomas; Ross Young

2005-09-29

Using the finite-range regularization (FRR) of chiral effective field theory, the chiral extrapolation formula for the vector meson mass is derived for the case of partially-quenched QCD. We re-analyze the dynamical fermion QCD data for the vector meson mass from the CP-PACS collaboration. A global fit, including finite lattice spacing effects, of all 16 of their ensembles is performed. We study the FRR method together with a naive polynomial approach and find excellent agreement ({approx}1%) with the experimental value of M{sub {rho}} from the former approach. These results are extended to the case of the nucleon mass.

Chiral Recognition and Separation by Chirality-Enriched Metal-Organic Frameworks.

Science.gov (United States)

Das, Saikat; Xu, Shixian; Ben, Teng; Qiu, Shilun

2018-05-16

Endowed with chiral channels and pores, chiral metal-organic frameworks (MOFs) are highly useful; however, their synthesis remains a challenge given that most chiral building blocks are expensive. Although MOFs with induced chirality have been reported to avoid this shortcoming, no study providing evidence for the ee value of such MOFs has yet been reported. We herein describe the first study on the efficiency of chiral induction in MOFs using inexpensive achiral building blocks and fully recoverable chiral dopants to control the handedness of racemic MOFs. This method yielded chirality-enriched MOFs with accessible pores. The ability of the materials to form host-guest complexes was probed with enantiomers of varying size and coordination and in solvents with varying polarity. Furthermore, mixed-matrix membranes (MMMs) composed of chirality-enriched MOF particles dispersed in a polymer matrix demonstrated a new route for chiral separation. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Instability of the hedgehog shape for the octet baryon in the chiral quark soliton model

OpenAIRE

Akiyama, Satoru; Futami, Yasuhiko

2003-01-01

In this paper the stability of the hedgehog shape of the chiral soliton is studied for the octet baryon with the SU(3) chiral quark soliton model. The strangeness degrees of freedom are treated by a simplified bound-state approach, which omits the locality of the kaon wave function. The mean field approximation for the flavor rotation is applied to the model. The classical soliton changes shape according to the strangeness. The baryon appears as a rotational band of the combined system of the...

Heavy baryon chiral perturbation theory and the spin 3/2 delta resonances

Energy Technology Data Exchange (ETDEWEB)

Kambor, J.

1996-12-31

Heavy baryon chiral perturbation theory is briefly reviewed, paying particular attention to the role of the spin 3/2 delta resonances. The concept of resonance saturation for the baryonic sector is critically discussed. Starting from a relativistic formulation of the pion-nucleon-delta system, the heavy baryon chiral Lagrangian including spin 3/2 resonances is constructed by means of a 1/m-expansion. The effective theory obtained admits a systematic expansion in terms of soft momenta, the pion mass M{sub {pi}} and the delta-nucleon mass difference {Delta}. (author). 22 refs.

Novel electrochemical method for the characterization of the degree of chirality in chiral polyaniline.

Science.gov (United States)

Feng, Zhang; Li, Ma; Yan, Yang; Jihai, Tang; Xiao, Li; Wanglin, Li

2013-01-01

A novel method to indicate the degree of chirality in polyaniline (PANI) was developed. The (D-camphorsulfonic acid)- and (HCl)-PANI-based electrodes exhibited significantly different electrochemical performances in D- and L-Alanine (Ala) aqueous solution, respectively, which can be used for the characterization the optical activity of chiral PANI. Cyclic voltammogram, tafel, and open circuit potential of PANI-based electrodes were measured within D- and L-Ala electrolyte solution, respectively. The open circuit potentials under different reacting conditions were analyzed by Doblhofer model formula, in which [C(+)](poly1)/[C(+)](poly2) was used as a parameter to characterize the degree of chirality in chiral PANI. The results showed that [C(+)](poly1)/[C(+)](poly2) can be increased with increasing concentrations of (1S)-(+)- and (1R)-(-)-10-camphorsulfonic acid. In addition, we detected that appropriate response time and lower temperature are necessary to improve the degree of chirality. Copyright © 2012 Wiley Periodicals, Inc.

Chiral forces and molecular dissymmetry

International Nuclear Information System (INIS)

Mohan, R.

1992-01-01

Chiral molecules leading to helical macromolecules seem to preserve information and extend it better. In the biological world RNA is the very paradigm for self-replication, elongation and autocatalytic editing. The nucleic acid itself is not chiral. It acquires its chirality by association with D-sugars. Although the chiral information or selectivity put in by the unit monomer is no longer of much interest to the biologists - they tend to leave it to the Darwinian selection principle to take care of it as illustrated by Frank's model - it is vital to understand the origin of chirality. There are three different approaches for the chiral origin of life: (1) Phenomenological, (2) Electromagnetic molecular and Coriolis forces and (3) Atomic or nuclear force, the neutral weak current. The phenomenological approach involves spontaneous symmetry breaking fluctuations in far for equilibrium systems or nucleation and crystallization. Chance plays a major role in the chiral molecule selected

Flavor structure of the nucleon electromagnetic form factors and transverse charge densities in the chiral quark-soliton model

Science.gov (United States)

Silva, António; Urbano, Diana; Kim, Hyun-Chul

2018-02-01

We investigate the flavor decomposition of the electromagnetic form factors of the nucleon, based on the chiral quark-soliton model (χQSM) with symmetry-conserving quantization. We consider the rotational 1/N_c and linear strange-quark mass (ms) corrections. We discuss the results of the flavor-decomposed electromagnetic form factors in comparison with the recent experimental data. In order to see the effects of the strange quark, we compare the SU(3) results with those of SU(2). Finally, we discuss the transverse charge densities for both unpolarized and polarized nucleons. The transverse charge density inside a neutron turns out to be negative in the vicinity of the center within the SU(3) χQSM, which can be explained by the contribution of the strange quark.

An SU(2) x SU(2) symmetric Higgs-Fermion model with staggered fermions

International Nuclear Information System (INIS)

Berlin, J.; Heller, U.M.

1991-01-01

We have simulated on SU(2)xSU(2) symmetric Higgs-Fermion model with a four component scalar field coupled with a Yukawa type coupling to two flavours of staggered fermions. The results show two qualitatively different behaviours in the broken phase. One for weak coupling where the fermion masses obey the perturbative tree level relation M F =y , and one for strong coupling where the behaviour agrees with a 1/d expansion. (orig.)

Chiral Magnetic Spirals

International Nuclear Information System (INIS)

Basar, Goekce; Dunne, Gerald V.; Kharzeev, Dmitri E.

2010-01-01

We argue that the presence of a very strong magnetic field in the chirally broken phase induces inhomogeneous expectation values, of a spiral nature along the magnetic field axis, for the currents of charge and chirality, when there is finite baryon density or an imbalance between left and right chiralities. This 'chiral magnetic spiral' is a gapless excitation transporting the currents of (i) charge (at finite chirality), and (ii) chirality (at finite baryon density) along the direction of the magnetic field. In both cases it also induces in the transverse directions oscillating currents of charge and chirality. In heavy ion collisions, the chiral magnetic spiral possibly provides contributions both to the out-of-plane and the in-plane dynamical charge fluctuations recently observed at BNL RHIC.

Chiral 1,3,2-oxazaborolidines in asymmetric synthesis: recent advances

International Nuclear Information System (INIS)

Glushkov, Vladimir A; Tolstikov, Alexander G

2004-01-01

The use of chiral 1,3,2-oxazaborolidines in asymmetric organic synthesis, particularly, in enantioselective reduction of ketones, imines and oxime ethers, asymmetric Diels-Alder reactions, aldol condensation and atroposelective reduction of lactones is reviewed. Reactions of immobilised 1,3,2-oxazaborolidines are also considered.

Relativistic Chiral Kinetic Theory

International Nuclear Information System (INIS)

Stephanov, Mikhail

2016-01-01

This very brief review of the recent progress in chiral kinetic theory is based on the results of Refs. [J.-Y. Chen, D. T. Son, M. A. Stephanov, H.-U. Yee, Y. Yin, Lorentz Invariance in Chiral Kinetic Theory, Phys. Rev. Lett. 113 (18) (2014) 182302. doi: (10.1103/PhysRevLett.113.182302); J.-Y. Chen, D. T. Son, M. A. Stephanov, Collisions in Chiral Kinetic Theory, Phys. Rev. Lett. 115 (2) (2015) 021601. doi: (10.1103/PhysRevLett.115.021601); M. A. Stephanov, H.-U. Yee, The no-drag frame for anomalous chiral fluid, Phys. Rev. Lett. 116 (12) (2016) 122302. doi: (10.1103/PhysRevLett.116.122302)].

Relativistic Chiral Kinetic Theory

Energy Technology Data Exchange (ETDEWEB)

Stephanov, Mikhail

2016-12-15

This very brief review of the recent progress in chiral kinetic theory is based on the results of Refs. [J.-Y. Chen, D. T. Son, M. A. Stephanov, H.-U. Yee, Y. Yin, Lorentz Invariance in Chiral Kinetic Theory, Phys. Rev. Lett. 113 (18) (2014) 182302. doi: (10.1103/PhysRevLett.113.182302); J.-Y. Chen, D. T. Son, M. A. Stephanov, Collisions in Chiral Kinetic Theory, Phys. Rev. Lett. 115 (2) (2015) 021601. doi: (10.1103/PhysRevLett.115.021601); M. A. Stephanov, H.-U. Yee, The no-drag frame for anomalous chiral fluid, Phys. Rev. Lett. 116 (12) (2016) 122302. doi: (10.1103/PhysRevLett.116.122302)].

Chiral Spirals from Discontinuous Chiral Symmetry

Science.gov (United States)

Kojo, Toru

2014-09-01

Recently phases of the inhomongeneous chiral condensates (IChC) attract renewed attentions in quark matter context. A number of theoretical studies have suggested that in some domain of moderate quark density the IChC phases are energetically more favored than the normal, chiral symmetric phase. In particular, the NJL-type model studies indicate that the phase of IChCs may mask the usual 1st order chiral phase transition line and its critical end point, and might change the conventional wisdom. In this talk, I will discuss characteristic features of the IChC phases and their potential impacts on the compact star physics. In particular, some of the IChC phases open gaps near the quark Fermi surface, suppressing back-reaction from the quark to gluon sectors. This mechanism delays the chiral restoration in the strange quark sector, forbids the emergence of the large bag constant, and as a consequence, makes the quark matter EOS very stiff. Recently phases of the inhomongeneous chiral condensates (IChC) attract renewed attentions in quark matter context. A number of theoretical studies have suggested that in some domain of moderate quark density the IChC phases are energetically more favored than the normal, chiral symmetric phase. In particular, the NJL-type model studies indicate that the phase of IChCs may mask the usual 1st order chiral phase transition line and its critical end point, and might change the conventional wisdom. In this talk, I will discuss characteristic features of the IChC phases and their potential impacts on the compact star physics. In particular, some of the IChC phases open gaps near the quark Fermi surface, suppressing back-reaction from the quark to gluon sectors. This mechanism delays the chiral restoration in the strange quark sector, forbids the emergence of the large bag constant, and as a consequence, makes the quark matter EOS very stiff. NSF Grants PHY09-69790, PHY13-05891.

Chiral algebras of class S

CERN Document Server

Beem, Christopher; Rastelli, Leonardo; van Rees, Balt C.

2015-01-01

Four-dimensional N=2 superconformal field theories have families of protected correlation functions that possess the structure of two-dimensional chiral algebras. In this paper, we explore the chiral algebras that arise in this manner in the context of theories of class S. The class S duality web implies nontrivial associativity properties for the corresponding chiral algebras, the structure of which is best summarized in the language of generalized topological quantum field theory. We make a number of conjectures regarding the chiral algebras associated to various strongly coupled fixed points.

Direct Detection of Hardly Detectable Hidden Chirality of Hydrocarbons and Deuterated Isotopomers by a Helical Polyacetylene through Chiral Amplification and Memory.

Science.gov (United States)

Maeda, Katsuhiro; Hirose, Daisuke; Okoshi, Natsuki; Shimomura, Kouhei; Wada, Yuya; Ikai, Tomoyuki; Kanoh, Shigeyoshi; Yashima, Eiji

2018-03-07

We report the first direct chirality sensing of a series of chiral hydrocarbons and isotopically chiral compounds (deuterated isotopomers), which are almost impossible to detect by conventional optical spectroscopic methods, by a stereoregular polyacetylene bearing 2,2'-biphenol-derived pendants. The polyacetylene showed a circular dichroism due to a preferred-handed helix formation in response to the hardly detectable hidden chirality of saturated tertiary or chiroptical quaternary hydrocarbons, and deuterated isotopomers. In sharp contrast to the previously reported sensory systems, the chirality detection by the polyacetylene relies on an excess one-handed helix formation induced by the chiral hydrocarbons and deuterated isotopomers via significant amplification of the chirality followed by its static memory, through which chiral information on the minute and hidden chirality can be stored as an excess of a single-handed helix memory for a long time.

(Anti-) selfdual Riemann curvature tensor in four spacelike compactified dimensions, O5 isometry group and chiral fermion zero modes

International Nuclear Information System (INIS)

Minkowski, P.

1986-01-01

The metric and contorsion tensors are constructed which yield a combined Riemann curvature tensor of the form Rsup(+-)sub(μνsigmatau)=(1/2a 2 )(gsub(μsigma)gsub(νtau) - gsub(μtau)gsub(νsigma)+-√g epsilonsub(μνsigmatau)). The metric with euclidean signature (++++) describes a sphere S 4 with radius a, i.e. admits the isometry group O5. For selfdual (antiselfdual) curvature tensor the contorsion tensor is given by the antiselfdual (selfdual) instanton configuration with respect to the spin gauge group SU2sub(R) (SU2sub(L)). The selfdual (antiselfdual) Riemann tensor admits two covariantly constant right-handed (left-handed) spin 1/2 fermion zero modes, one J=1/2 and one J=3/2 right-handed (left-handed) multiplet corresponding to L=1, transforming as a pseudoreal representation of O4 (SU2sub(R(L))). The hermitean Dirac equation retains only the two constant chiral modes. (orig.)

Geometrical approach to central molecular chirality: a chirality selection rule

OpenAIRE

Capozziello, S.; Lattanzi, A.

2004-01-01

Chirality is of primary importance in many areas of chemistry and has been extensively investigated since its discovery. We introduce here the description of central chirality for tetrahedral molecules using a geometrical approach based on complex numbers. According to this representation, for a molecule having n chiral centres, it is possible to define an index of chirality. Consequently a chirality selection rule has been derived which allows the characterization of a molecule as achiral, e...

Diversity of off-shell twisted (4,4) multiplets in SU(2)xSU(2) harmonic superspace

International Nuclear Information System (INIS)

Ivanov, E.A.; Sutulin, A.O.

2004-01-01

We elaborate on four different types of twisted N=(4,4) supermultiplets in the SU(2)xSU(2), 2D harmonic superspace. In the conventional N=(4,4), 2D superspace they are described by the superfields q ia , q Ia , q IA , subjected to proper differential constraints, (i, I, a, A) being the doublet indices of four groups SU(2) which form the full R-symmetry group SO(4) L xSO(4) R of N=(4,4) supersymmetry. We construct the torsionful off-shell sigma-model actions for each type of these multiplets, as well as the corresponding invariant mass terms, in an analytic subspace of the SU(2)xSU(2) harmonic superspace. As an instructive example, N=(4,4) superconformal extension of the SU(2)xU(1) WZNW sigma-model action and its massive deformation are presented for the multiplet q iA . We prove that N=(4,4) supersymmetry requires the general sigma-model action of pair of different multiplets to split into a sum of sigma-model actions of each multiplet. This phenomenon also persists if a larger number of non-equivalent multiplets are simultaneously included. We show that different multiplets may interact with each other only through mixed mass terms which can be set up for multiplets belonging to 'self-dual' pairs (q ia , q IA ) and (q Ia , q iA ). The multiplets from different pairs cannot interact at all. For a 'self-dual' pair of the twisted multiplets we give the most general form of the on-shell scalar potential

Chiral nanophotonics chiral optical properties of plasmonic systems

CERN Document Server

Schäferling, Martin

2017-01-01

This book describes the physics behind the optical properties of plasmonic nanostructures focusing on chiral aspects. It explains in detail how the geometry determines chiral near-fields and how to tailor their shape and strength. Electromagnetic fields with strong optical chirality interact strongly with chiral molecules and, therefore, can be used for enhancing the sensitivity of chiroptical spectroscopy techniques. Besides a short review of the latest results in the field of plasmonically enhanced enantiomer discrimination, this book introduces the concept of chiral plasmonic near-field sources for enhanced chiroptical spectroscopy. The discussion of the fundamental properties of these light sources provides the theoretical basis for further optimizations and is of interest for researchers at the intersection of nano-optics, plasmonics and stereochemistry. .

Nucleon parton distributions in chiral perturbation theory

International Nuclear Information System (INIS)

Moiseeva, Alena

2013-01-01

Properties of the chiral expansion of nucleon light-cone operators have been studied. In the framework of the chiral perturbation theory we have demonstrated that convergency of the chiral expansion of nucleon parton distributions strongly depends on the value of the variable x. Three regions in x with essentially different analytical properties of the resulting chiral expansion for parton distributions were found. For each of the regions we have elaborated special power counting rules corresponding to the partial resummation of the chiral series. The nonlocal effective operators for the vector and the axial nucleon parton distributions have been constructed at the zeroth and the first chiral order. Using the derived nonlocal operators and the derived power counting rules we have obtained the second order expressions for the nucleon GPDs H(x,ξ,Δ 2 ), H(x,ξ,Δ 2 ),E(x,ξ,Δ 2 ) valid in the region x>or similar a 2 χ .

QCD and the chiral critical point

International Nuclear Information System (INIS)

Gavin, S.; Gocksch, A.; Pisarski, R.D.

1994-01-01

As an extension of QCD, consider a theory with ''2+1'' flavors, where the current quark masses are held in a fixed ratio as the overall scale of the quark masses is varied. At nonzero temperature and baryon density it is expected that in the chiral limit the chiral phase transition is of first order. Increasing the quark mass from zero, the chiral transition becomes more weakly first order, and can end in a chiral critical point. We show that the only massless field at the chiral critical point is a σ meson, with the universality class that of the Ising model. Present day lattice simulations indicate that QCD is (relatively) near to the chiral critical point

Chiral 2d theories from N=4 SYM with varying coupling

Energy Technology Data Exchange (ETDEWEB)

Lawrie, Craig [Institut für Theoretische Physik, Ruprecht-Karls-Universität,Philosophenweg 19, 69120 Heidelberg (Germany); Schäfer-Nameki, Sakura [Mathematical Institute, University of Oxford,Woodstock Road, Oxford, OX2 6GG (United Kingdom); Weigand, Timo [Institut für Theoretische Physik, Ruprecht-Karls-Universität,Philosophenweg 19, 69120 Heidelberg (Germany)

2017-04-19

We study 2d chiral theories arising from 4d N=4 Super-Yang Mills (SYM) with varying coupling τ. The 2d theory is obtained by dimensional reduction of N=4 SYM on a complex curve with a partial topological twist that accounts for the non-constant τ. The resulting 2d theories can preserve (0,n) with n=2,4,6,8 chiral supersymmetry, and have a natural realization in terms of strings from wrapped D3-branes in F-theory. We determine the twisted dimensional reduction, as well as the spectrum and anomaly polynomials of the resulting strings in various dimensions. We complement this by considering the dual M-theory configurations, which can either be realized in terms of M5-branes wrapped on complex surfaces, or M2-branes on curves that result in 1d supersymmetric quantum mechanics.

Low energy pion-pion phase shifts from chiral perturbation theory

International Nuclear Information System (INIS)

Borges, J. Sa; Barbosa, J. Soares; Oguri, V.

1997-01-01

The low energy pion-pion S- and P- experimental phase-shifts are fitted with chiral perturbation theory (Ch PT) amplitude. The low energy pion-pion S- and P- experimental phase-shifts. The parameters l 1 and l 2 of the one loop corrected amplitude are fixed and the corresponding values of the scattering lengths are calculated. We propose that the present method is the best way to fix Ch P T parameters. The unitarization program of current algebra is also discussed. (author)

Search for chirality in 109Ag

International Nuclear Information System (INIS)

Timar, J.; Nyako, B.M.; Berek, G.; Gal, J.; Kalinka, G.; Krasznahorkay, A.; Molnar, J.; Zolnai, L.

2007-01-01

Complete text of publication follows. The existence of nuclear chirality is one of the most intriguing questions of contemporary high-spin nuclear structure studies. Rotational doublet-band candidates for chiral structures have been observed mostly in two regions of the nuclear chart: around 134 Pr, and around 104 Rh. In this second region chirality in the Rh isotopes are rather well studied, chiral doubling have also been observed in 100 Tc, however, results obtained for chirality in the studied Ag nuclei ( 105 Ag and 106 Ag) look rather contradictory. Thus, it is interesting to study these doublet bands in the nearby higher-mass Ag nuclei. In order to search for a chiral-candidate partner band to the yrast πg 9/2 v(h 11/2 ) 2 band in 109 Ag, high-spin states of this nucleus have been studied using the 96 Zr( 18 O,p4n) reaction. The experiment was performed at iThemba LABS using 8 Clover detectors of the AFRODITE array and the DIAMANT charged-particle array to detect the γ-rays and the charged particles, respectively. Altogether ∼140 million γγ-coincidence events were collected. Approximately 10 million events of them correspond to the reaction channel producing 109 Ag. No chiral candidate partner band has been found to the πg 9/2 v(h 11/2 ) 2 band with this statistics, however, the level scheme could be extended by several new levels and γ-transitions. A preliminary level scheme of 109 Ag obtained from the ongoing data analysis is shown in Fig. 1

Supersymmetry and the chiral Schwinger model

International Nuclear Information System (INIS)

Amorim, R.; Das, A.

1998-01-01

We have constructed the N= (1) /(2) supersymmetric general Abelian model with asymmetric chiral couplings. This leads to a N= (1) /(2) supersymmetrization of the Schwinger model. We show that the supersymmetric general model is plagued with problems of infrared divergence. Only the supersymmetric chiral Schwinger model is free from such problems and is dynamically equivalent to the chiral Schwinger model because of the peculiar structure of the N= (1) /(2) multiplets. copyright 1998 The American Physical Society

Coherent states for polynomial su(2) algebra

International Nuclear Information System (INIS)

Sadiq, Muhammad; Inomata, Akira

2007-01-01

A class of generalized coherent states is constructed for a polynomial su(2) algebra in a group-free manner. As a special case, the coherent states for the cubic su(2) algebra are discussed. The states so constructed reduce to the usual SU(2) coherent states in the linear limit

Balanced Hermitian metrics from SU(2)-structures

International Nuclear Information System (INIS)

Fernandez, M.; Tomassini, A.; Ugarte, L.; Villacampa, R.

2009-01-01

We study the intrinsic geometrical structure of hypersurfaces in six-manifolds carrying a balanced Hermitian SU(3)-structure, which we call balanced SU(2)-structure. We provide sufficient conditions, in terms of suitable evolution equations, which imply that a five-manifold with such structure can be isometrically embedded as a hypersurface in a balanced Hermitian SU(3)-manifold. Any five-dimensional compact nilmanifold has an invariant balanced SU(2)-structure, and we show how some of them can be evolved to give new explicit examples of balanced Hermitian SU(3)-structures. Moreover, for n=3,4, we present examples of compact solvmanifolds endowed with a balanced SU(n)-structure such that the corresponding Bismut connection has holonomy equal to SU(n)

Modeling chiral criticality and its consequences for heavy-ion collisions

Energy Technology Data Exchange (ETDEWEB)

Almasi, Gabor [Gesellschaft fuer Schwerionenforschung, GSI, Darmstadt (Germany); Friman, Bengt [Gesellschaft fuer Schwerionenforschung, GSI, Darmstadt (Germany); ExtreMe Matter Institute (EMMI), Darmstadt (Germany); Redlich, Krzysztof [ExtreMe Matter Institute (EMMI), Darmstadt (Germany); University of Wroclaw, Faculty of Physics and Astronomy, Wroclaw (Poland); Department of Physics, Duke University, Durham, NC (United States)

2016-07-01

We explore the critical fluctuations near the chiral critical endpoint (CEP), which belongs to the Z(2) universality class, in a chiral effective model and discuss possible signals of the CEP, recently explored in nuclear collision experiments. Particular attention is attributed to the dependence of such signals on the location of the phase boundary and the CEP relative to the hypothetical freeze-out conditions in nuclear collisions. We argue that in effective models freeze-out fits to heavy-ion results should not be used directly, and relevant quantities should be investigated on lines of the phase diagram, that are defined self-consistently in the framework of the model. We discuss possible choices for such an approach. Additionally we discuss the effect of the repulsive vector interaction of quarks on the location of the CEP and on the structure of the baryon number cumulant ratios.

Meson-baryon coupling constants from a chiral-invariant SU(3) Lagrangian and application to NN scattering

International Nuclear Information System (INIS)

Stoks, V.G.J.

1997-01-01

We present a chiral-invariant meson-baryon Lagrangian which describes the interactions of the baryon octet with the lowest-mass meson nonets. The nonlinear realization of the chiral symmetry generates pair-meson interaction vertices. The corresponding pair-meson coupling constants can all be expressed in terms of the meson-nucleon-nucleon pseudovector, scalar, and vector coupling constants, and their corresponding F/(F+D) ratios, and for which empirical estimates are given. We show that it is possible to construct an NN potential of reasonable quality satisfying these theoretical and empirical constraints. (orig.)

πK scattering in chiral perturbation theory to one loop

International Nuclear Information System (INIS)

Bernard, V.; Kaiser, N.; Strasbourg-1 Univ., 67; Meissner, U.G.

1991-01-01

We evaluate the πK scattering amplitude at next-to-leading order in the framework of chiral perturbation theory. All low-energy constants appearing in the effective lagrangian of the pseudoscalars have previously been determined. We calculate the scattering lengths of the S- and P-waves as well as the expansion parameters around the point ν triple bond (s-u)/4M K = t = 0 in the unphysical region. Furthermore, phase-shifts of the low partial ways are presented and compared to the data. In most cases, the chiral predictions are comparable to the trends set by the empirical information. For a precise comparison, however, more accurate experimental determinations of the πK scattering process at low and moderate energies would be necessary. We urge the experimenters to perform these. (orig.)

N=2 central charge bounds from 2d chiral algebras

Energy Technology Data Exchange (ETDEWEB)

Lemos, Madalena [DESY Hamburg, Theory Group,Notkestrasse 85, D-22607 Hamburg (Germany); Liendo, Pedro [IMIP, Humboldt-Universität zu Berlin, IRIS Adlershof,Zum Großen Windkanal 6, 12489 Berlin (Germany)

2016-04-01

We study protected correlation functions in N=2 SCFT whose description is captured by a two-dimensional chiral algebra. Our analysis implies a new analytic bound for the c-anomaly as a function of the flavor central charge k, valid for any theory with a flavor symmetry. Combining our result with older bounds in the literature puts strong constraints on the parameter space of N=2 theories. In particular, it singles out a special set of models whose value of c is uniquely fixed once k is given. This set includes the canonical rank one N=2 SCFTs given by Kodaira’s classification.

Enantioselective conjugate addition of diethylzinc to chalcone catalyzed by Co(acac)2 and chiral amino alcohols

NARCIS (Netherlands)

Vries, André H.M. de; Feringa, Bernard

1997-01-01

Co(acac)2 in the presence of chiral ligands has been employed as catalyst for the enantioselective conjugate addition of diethylzinc to chalcone. With chiral amino alcohols derived from (+)-camphor, enantioselectivities up to 83% were achieved.

Independent SU(2)-loop variables and the reduced configuration space of SU(2)-lattice gauge theory

International Nuclear Information System (INIS)

Loll, R.

1992-01-01

We give a reduction procedure for SU(2)-trace variables and an explicit description of the reduced configuration sace of pure SU(2)-gauge theory on the hypercubic lattices in two, three and four dimensions, using an independent subset of the gauge-invariant Wilson loops. (orig.)

Chiral memory via chiral amplification and selective depolymerization of porphyrin aggregates

NARCIS (Netherlands)

Helmich, F.A.; Lee, C.C.; Schenning, A.P.H.J.; Meijer, E.W.

2010-01-01

Chiral memory at the supramolecular level is obtained via a new approach using chiral Zn porphrins and achiral Cu porphyrins. In a "sergeant-and-soldiers" experiment, the Zn "sergeant" transfers its own chirality to Cu "soldiers" and, after chiral amplification, the "sergeant" is removed from the

Search for the characters of chiral rotation in excited bands for the idea chiral nuclei with A ∼ 130

International Nuclear Information System (INIS)

Chen Qibo; Yao Jiangming; Meng Jie; Zhang Shuangquan; Qi Bin

2010-01-01

Since the occurrence of chirality was originally suggested in 1997 by Frauendorf and Meng [1] and experimentally observed in 2001 [2] , the investigation of chiral symmetry in atomic nuclei becomes one of the most important topics in nuclear physics. More and more chiral doublet bands [3-7] in atomic nuclei [8] have been reported. There are also many discussions about the fingerprints of chirality. In the pioneer paper [1] , the two lowest near degenerate bands given by the particle-rotor model (PRM) are interpreted as chiral doublet bands. If the nucleus has chiral geometry with proper configuration, the character of chiral rotation may appear not only in the two lowest bands, but also in the other bands. Therefore, it is interesting to search for the character of chiral rotation, Based on the PRM model with configuration corresponding to A ∼ 130 mass region, we examine the theoretical spectroscopy of higher excited bands (band3, band4, band5 and band6) beyond the two lowest bands (bandl and band2), including energies, spin-alignments, projection of total angular momentum and electromagnetic transition probabilities. The results show that band3 and band4 have characters of chirality in some spin region. (authors)

Effects of Composite Pions on the Chiral Condensate within the PNJL Model at Finite Temperature

Science.gov (United States)

Blaschke, D.; Dubinin, A.; Ebert, D.; Friesen, A. V.

2018-05-01

We investigate the effect of composite pions on the behaviour of the chiral condensate at finite temperature within the Polyakov-loop improved NJL model. To this end we treat quark-antiquark correlations in the pion channel (bound states and scattering continuum) within a Beth-Uhlenbeck approach that uses medium-dependent phase shifts. A striking medium effect is the Mott transition which occurs when the binding energy vanishes and the discrete pion bound state merges the continuum. This transition is triggered by the lowering of the continuum edge due to the chiral restoration transition. This in turn also entails a modification of the Polyakov-loop so that the SU(3) center symmetry gets broken at finite temperature and dynamical quarks (and gluons) appear in the system, taking over the role of the dominant degrees of freedom from the pions. At low temperatures our model reproduces the chiral perturbation theory result for the chiral condensate while at high temperatures the PNJL model result is recovered. The new aspect of the current work is a consistent treatment of the chiral restoration transition region within the Beth-Uhlenbeck approach on the basis of mesonic phase shifts for the treatment of the correlations.

Enantioselective conjugate addition of diethylzinc to chalcone catalyzed by Co(acac)(2) and chiral amino alcohols

NARCIS (Netherlands)

de Vries, A.H.M.; Feringa, B.L.

1997-01-01

Co(acac)(2) in the presence of chiral ligands has been employed as catalyst for the enantioselective conjugate addition of diethylzinc to chalcone. With chiral amino alcohols derived from (+)-camphor, enantioselectivities up to 83% were achieved. (C) 1997 Elsevier Science Ltd.

Chiral Symmetry Restoration, Naturalness and the Absence of Fine-Tuning I: Global Theories

CERN Document Server

Lynn, Bryan W.

2013-01-01

The Standard Model (SM), and the scalar sector of its zero-gauge-coupling limit -- the chiral-symmetric limit of the Gell Mann-Levy Model (GML) -- have been shown not to suffer from a Higgs Fine-Tuning (FT) problem. All ultraviolet quadratic divergences (UVQD) are absorbed into the mass-squared of pseudo Nambu-Goldstone (pNGB) bosons, in GML. Since chiral SU(2)_{L-R} symmetry is restored as the pNGB mass-squared or as the Higgs vacuum expectation value (VEV) are taken to 0, small values of these quantities and of the Higgs mass are natural, and therefore not Fine-Tuned. In this letter, we extend our results on the absence of FT to a wide class of high-mass-scale (M_{Heavy}>>m_{Higgs}) extensions to a simplified SO(2) version of GML. We explicitly demonstrate naturalness and no-FT for two examples of heavy physics, both SO(2) singlets: a heavy (M_S >> m_{Higgs}) real scalar field (with or without a VEV); and a right-handed Type 1 See-Saw Majorana neutrino with M_R >> m_{Higgs}. We prove that for |q^2| <<...

Study on the determination and chiral inversion of R-salbutamol in human plasma and urine by liquid chromatography-tandem mass spectrometry.

Science.gov (United States)

Zhou, Ting; Zeng, Jing; Liu, Shan; Zhao, Ting; Wu, Jie; Lai, Wenshi; He, Mingzhi; Xu, Beining; Qu, Shanshan; Xu, Ling; Tan, Wen

2015-10-01

The chiral inversion has been a concerned issue during the research and development of a chiral drug. In this study, a sensitive chiral liquid chromatography-tandem mass spectrometry (LC-MS/MS) method was developed for determination of salbutamol enantiomers in human plasma and urine. The chiral inversion mechanism of R-salbutamol was fully investigated for the first time by studying the effects of physicochemical factors, including pH, temperature and time. A fitted model to predict the chiral inversion ratio of R-salbutamol was proposed using a Box-Behnken design. All the samples were separated on an Astec Chirobiotic T column and detected by a tandem mass spectrometer in multiple reaction monitoring mode. Lower limit of quantification of 0.100ng/mL was achieved under the optimized conditions. The method was fully validated and successfully applied to the clinical pharmacokinetic study of R-salbutamol in healthy volunteers. Chiral inversion of R-salbutamol to S-salbutamol has been detected in urine samples. The results indicated that pH and temperature were two dominant factors that caused the chiral inversion of R-salbutamol, which should be taken into consideration during the analysis of chiral drugs. The chiral inversion of R-salbutamol determined in this study was confirmed resulted from the gastric acid in stomach rather than caused by the analysis conditions. Moreover, the calculated results of the fitted model matched very well with the enantioselective pharmacokinetic study of R-salbutamol, and the individual difference of the chiral inversion ratio of R-salbutamol was related to the individual gastric environment. On the basis of the results, this study provides important and concrete information not only for the chiral analysis but also for the metabolism research of chiral drugs. Copyright © 2015 Elsevier B.V. All rights reserved.

Thermal chiral vortical and magnetic waves: New excitation modes in chiral fluids

Energy Technology Data Exchange (ETDEWEB)

Kalaydzhyan, Tigran, E-mail: tigran@caltech.edu [Department of Physics, University of Illinois, 845 W Taylor Street, Chicago, IL 60607 (United States); Jet Propulsion Laboratory, 4800 Oak Grove Dr, M/S 298, Pasadena, CA 91109 (United States); Murchikova, Elena [TAPIR, California Institute of Technology, MC 350-17, Pasadena, CA 91125 (United States)

2017-06-15

In certain circumstances, chiral (parity-violating) medium can be described hydrodynamically as a chiral fluid with microscopic quantum anomalies. Possible examples of such systems include strongly coupled quark–gluon plasma, liquid helium {sup 3}He-A, neutron stars and the Early Universe. We study first-order hydrodynamics of a chiral fluid on a vortex background and in an external magnetic field. We show that there are two previously undiscovered modes describing heat waves propagating along the vortex and magnetic field. We call them the Thermal Chiral Vortical Wave and Thermal Chiral Magnetic Wave. We also identify known gapless excitations of density (chiral vortical and chiral magnetic waves) and transverse velocity (chiral Alfvén wave). We demonstrate that the velocity of the chiral vortical wave is zero, when the full hydrodynamic framework is applied, and hence the wave is absent and the excitation reduces to the charge diffusion mode. We also comment on the frame-dependent contributions to the obtained propagation velocities.

Thermal chiral vortical and magnetic waves: New excitation modes in chiral fluids

International Nuclear Information System (INIS)

Kalaydzhyan, Tigran; Murchikova, Elena

2017-01-01

In certain circumstances, chiral (parity-violating) medium can be described hydrodynamically as a chiral fluid with microscopic quantum anomalies. Possible examples of such systems include strongly coupled quark–gluon plasma, liquid helium "3He-A, neutron stars and the Early Universe. We study first-order hydrodynamics of a chiral fluid on a vortex background and in an external magnetic field. We show that there are two previously undiscovered modes describing heat waves propagating along the vortex and magnetic field. We call them the Thermal Chiral Vortical Wave and Thermal Chiral Magnetic Wave. We also identify known gapless excitations of density (chiral vortical and chiral magnetic waves) and transverse velocity (chiral Alfvén wave). We demonstrate that the velocity of the chiral vortical wave is zero, when the full hydrodynamic framework is applied, and hence the wave is absent and the excitation reduces to the charge diffusion mode. We also comment on the frame-dependent contributions to the obtained propagation velocities.

Thermal chiral vortical and magnetic waves: New excitation modes in chiral fluids

Directory of Open Access Journals (Sweden)

Tigran Kalaydzhyan

2017-06-01

Full Text Available In certain circumstances, chiral (parity-violating medium can be described hydrodynamically as a chiral fluid with microscopic quantum anomalies. Possible examples of such systems include strongly coupled quark–gluon plasma, liquid helium 3He-A, neutron stars and the Early Universe. We study first-order hydrodynamics of a chiral fluid on a vortex background and in an external magnetic field. We show that there are two previously undiscovered modes describing heat waves propagating along the vortex and magnetic field. We call them the Thermal Chiral Vortical Wave and Thermal Chiral Magnetic Wave. We also identify known gapless excitations of density (chiral vortical and chiral magnetic waves and transverse velocity (chiral Alfvén wave. We demonstrate that the velocity of the chiral vortical wave is zero, when the full hydrodynamic framework is applied, and hence the wave is absent and the excitation reduces to the charge diffusion mode. We also comment on the frame-dependent contributions to the obtained propagation velocities.

SU(6)-strong breaking: structure functions and small momentum transfer properties of the nucleon

International Nuclear Information System (INIS)

Le Yaouanc, A.; Oliver, L.; Pene, O.; Raynal, J.C.

1975-01-01

A new approach in the study of the SU(6) symmetry breaking (in particular in deep inelastic electron-nucleon scattering) is presented. It is shown that there is a connection between deep inelastic and low momentum transfer or static properties of the nucleon, which extends much beyond the common SU(6) 56-assignments of the nucleon in both cases. This connection is provided by the realistic quark model (in which quarks are considered as real entities moving inside the hadron). Using this connection it is shown that the breaking of the prediction Fsub(2)sup(en)/Fsub(2)sup(ep)=2/3 is not truly related to chiral configuration mixings. An alternative solution, based on a true modification of the 56-assignment of the nucleon to a (56,L=0)+(70,L=0) mixing (called SU(6) strong mixing) is proposed. It is shown that the 'good' predictions of SU(6) are not much changed by this mixing. A complete description of the deep inelastic scattering including gluons and pairs is presented

SU (2) with fundamental fermions and scalars

DEFF Research Database (Denmark)

Hansen, Martin; Janowski, Tadeusz; Pica, Claudio

2018-01-01

We present preliminary results on the lattice simulation of an SU(2) gauge theory with two fermion flavors and one strongly interacting scalar field, all in the fundamental representation of SU(2). The motivation for this study comes from the recent proposal of "fundamental" partial compositeness...... the properties of light meson resonances previously obtained for the SU(2) model. Preprint: CP3-Origins-2017-047 DNRF90...

Non-uniform chiral phase in effective chiral quark models

International Nuclear Information System (INIS)

Sadzikowski, M.; Broniowski, W.

2000-01-01

We analyze the phase diagram in effective chiral quark models (the Nambu-Jona-Lasinio model, the σ-model with quarks) and show that at the mean-field level a phase with a periodically-modulated chiral fields separates the usual phases with broken and restored chiral symmetry. A possible signal of such a phase is the production of multipion jets travelling in opposite directions, with individual pions having momenta of the order of several hundred MeV. This signal can be interpreted in terms of disoriented chiral condensates. (author)

Insight into the chiral induction in supramolecular stacks through preferential chiral salvation

NARCIS (Netherlands)

George, S.J.; Tomovic, Z.; Schenning, A.P.H.J.; Meijer, E.W.

2011-01-01

Preferred handedness in the supramolecular chirality of self-assembled achiral oligo(p-phenylenevinylene) (OPV) derivatives is induced by chiral solvents and spectroscopic probing provides insight into the mechanistic aspects of this chiral induction through chiral solvation

Weak mixing angle and the SU(3)CxSU(3) model on M4xS1/(Z2xZ'2)

International Nuclear Information System (INIS)

Li Tianjun; Wei Liao

2002-05-01

We show that the desirable weak mixing angle sin 2 θ W =0.2312 at m Z scale can be generated naturally in the SU(3) C xSU(3) model on M 4 xS 1 /(Z 2 x Z 2 ') where the gauge symmetry SU(3) is broken down to SU(2) L xU(1) Y by orbifold projection. For a supersymmetric model with a TeV scale extra dimension, the SU(3) unification scale is about hundreds of TeVs at which the gauge couplings for SU(3) C and SU(3) can also be equal in the mean time. For the non-supersymmetric model, SU(2) L xU(1) Y are unified at order of 10 TeV. These models may serve as good candidates for physics beyond the SM or MSSM. (author)

Chiral phase transition of QCD with N{sub f}=2+1 flavors from holography

Energy Technology Data Exchange (ETDEWEB)

Li, Danning [Department of Physics, Jinan University,Guangzhou 510632 (China); Huang, Mei [Institute of High Energy Physics, Chinese Academy of Sciences,Beijing 100049 (China); University of Chinese Academy of Sciences,Beijing 100049 (China); Theoretical Physics Center for Science Facilities, Chinese Academy of Sciences,Beijing 100049 (China)

2017-02-08

Chiral phase transition for three-flavor N{sub f}=2+1 QCD with m{sub u}=m{sub d}≠m{sub s} is investigated in a modified soft-wall holographic QCD model. Solving temperature dependent chiral condensates from equations of motion of the modified soft-wall model, we extract the quark mass dependence of the order of chiral phase transition in the case of N{sub f}=2+1, and the result is in agreement with the “Columbia Plot”, which is summarized from lattice simulations and other non-perturbative methods. First order phase transition is observed around the three flavor chiral limit m{sub u/d}=0,m{sub s}=0, while at sufficient large quark masses it turns to be a crossover phase transition. The first order and crossover regions are separated by a second order phase transition line. The second order line is divided into two parts by the m{sub u/d}=m{sub s} line, and the m{sub s} dependence of the transition temperature in these two parts are totally contrast, which might indicate that the two parts are governed by different universality classes.

Modeling chiral criticality and its consequences for heavy-ion collisions

Energy Technology Data Exchange (ETDEWEB)

Almási, Gábor András, E-mail: g.almasi@gsi.de [Gesellschaft für Schwerionenforschung, GSI, D-64291 Darmstadt (Germany); Friman, Bengt, E-mail: b.friman@gsi.de [Gesellschaft für Schwerionenforschung, GSI, D-64291 Darmstadt (Germany); ExtreMe Matter Institute (EMMI), D-64291 Darmstadt (Germany); Redlich, Krzysztof, E-mail: krzysztof.redlich@ift.uni.wroc.pl [ExtreMe Matter Institute (EMMI), D-64291 Darmstadt (Germany); University of Wrocław - Faculty of Physics and Astronomy, PL-50-204 Wrocław (Poland); Department of Physics, Duke University, Durham, NC 27708 (United States)

2016-12-15

We explore the critical fluctuations near the chiral critical endpoint (CEP) in a chiral effective model and discuss possible signals of the CEP, recently explored experimentally in nuclear collision. Particular attention is paid to the dependence of such signals on the location of the phase boundary and the CEP relative to the chemical freeze-out conditions in nuclear collisions. We argue that in effective models, standard freeze-out fits to heavy-ion data should not be used directly. Instead, the relevant quantities should be examined on lines in the phase diagram that are defined self-consistently, within the framework of the model. We discuss possible choices for such an approach.

SU(2) and SU(1,1) squeezing of interacting radiation modes

International Nuclear Information System (INIS)

Abdalla Sebawe, M.; Faisal El-Orany, A.A.; Perina, J.

2000-01-01

In this communication we discuss SU(1,1) and SU(2) squeezing of an interacting system of radiation modes in a quadratic medium in the framework of Lie algebra. We show that regardless of which state being initially considered, squeezing can be periodically generated. (authors)

Autoamplification of molecular chirality through the induction of supramolecular chirality

NARCIS (Netherlands)

van Dijken, Derk Jan; Beierle, John M.; Stuart, Marc C. A.; Szymanski, Wiktor; Browne, Wesley R.; Feringa, Ben L.

2014-01-01

The novel concept for the autoamplification of molecular chirality, wherein the amplification proceeds through the induction of supramolecular chirality, is presented. A solution of prochiral, ring-open diarylethenes is doped with a small amount of their chiral, ring-closed counterpart. The

Active chiral fluids.

Science.gov (United States)

Fürthauer, S; Strempel, M; Grill, S W; Jülicher, F

2012-09-01

Active processes in biological systems often exhibit chiral asymmetries. Examples are the chirality of cytoskeletal filaments which interact with motor proteins, the chirality of the beat of cilia and flagella as well as the helical trajectories of many biological microswimmers. Here, we derive constitutive material equations for active fluids which account for the effects of active chiral processes. We identify active contributions to the antisymmetric part of the stress as well as active angular momentum fluxes. We discuss four types of elementary chiral motors and their effects on a surrounding fluid. We show that large-scale chiral flows can result from the collective behavior of such motors even in cases where isolated motors do not create a hydrodynamic far field.

On meson resonances and chiral symmetry

International Nuclear Information System (INIS)

Lutz, M.F.M.

2003-07-01

We study meson resonances with quantum numbers J P = 1 + in terms of the chiral SU(3) Lagrangian. At leading order a parameter-free prediction is obtained for the scattering of Goldstone bosons off vector mesons with J P = 1 - once we insist on approximate crossing symmetry of the unitarized scattering amplitude. A resonance spectrum arises that is remarkably close to the empirical pattern. In particular, we find that the strangeness-zero resonances h 1 (1380), f 1 (1285) and b 1 (1235) are formed due to strong K anti K μ and K K μ channels. This leads to large coupling constants of those resonances to the latter states. (orig.)

Deformed chiral nucleons

Energy Technology Data Exchange (ETDEWEB)

Price, C E; Shepard, J R [Colorado Univ., Boulder (USA). Dept. of Physics

1991-04-18

We compute properties of the nucleon in a hybrid chiral model based on the linear {sigma}-model with quark degrees of freedom treated explicity. In contrast to previous calculations, we do not use the hedgehog ansatz. Instead we solve self-consistently for a state with well defined spin and isospin projections. We allow this state to be deformed and find that, although d- and g-state admixtures in the predominantly s-state single quark wave functions are not large, they have profound effects on many nucleon properties including magnetic moments and g{sub A}. Our best fit parameters provide excellent agreement with experiment but are much different from those determined in hedgehog calculations. (orig.).

Chiral fermions on the lattice

International Nuclear Information System (INIS)

Randjbar Daemi, S.; Strathdee, J.

1995-01-01

The overlap approach to chiral gauge theories on arbitrary D-dimensional lattices is studied. The doubling problem and its relation to chiral anomalies for D = 2 and 4 is examined. In each case it is shown that the doublers can be eliminated and the well known perturbative results for chiral anomalies can be recovered. We also consider the multi-flavour case and give the general criteria for the construction of anomaly free chiral gauge theories on arbitrary lattices. We calculate the second order terms in a continuum approximation to the overlap formula in D dimensions and show that they coincide with the bilinear part of the effective action of D-dimensional Weyl fermions coupled to a background gauge field. Finally, using the same formalism we reproduce the correct Lorentz, diffeomorphism and gauge anomalies in the coupling of a Weyl fermion to 2-dimensional gravitation and Maxwell fields. (author). 15 refs

trans-2-Tritylcyclohexanol as a chiral auxiliary in permanganate-mediated oxidative cyclization of 2-methylenehept-5-enoates: application to the synthesis of trans-(+)-linalool oxide.

Science.gov (United States)

Al Hazmi, Ali M; Sheikh, Nadeem S; Bataille, Carole J R; Al-Hadedi, Azzam A M; Watkin, Sam V; Luker, Tim J; Camp, Nicholas P; Brown, Richard C D

2014-10-03

The permanganate-mediated oxidative cyclization of a series of 2-methylenehept-5-eneoates bearing different chiral auxiliaries was investigated, leading to the discovery of trans-2-tritylcyclohexanol (TTC) as a highly effective chiral controller for the formation of the 2,5-substituted THF diol product with high diastereoselectivity (dr ∼97:3). Chiral resolution of (±)-TTC, prepared in one step from cyclohexene oxide, afforded (-)-(1S,2R)-TTC (er >99:1), which was applied to the synthesis of (+)-trans-(2S,5S)-linalool oxide.

Vector mesons and chiral symmetry

International Nuclear Information System (INIS)

Ecker, G.

1989-01-01

The ambiguities in the off-shell behaviour of spin-1 exchange can be resolved to O(p 4 ) in the chiral low-energy expansion if the asymptotic behaviour of QCD is properly incorporated. As a consequence, the chiral version of vector (and axial-vector) meson dominance is model independent. Additional high-energy constraints motivated by QCD determine the V,A resonance couplings uniquely. In particular, QCD in its effective chiral realization sucessfully predicts Γ(ρ→2π). 10 refs. (Author)

Electromagnetic couplings of the chiral perturbation theory Lagrangian from the perturbative chiral quark model

International Nuclear Information System (INIS)

Lyubovitskij, V.E.; Gutsche, Th.; Faessler, Amand; Mau, R. Vinh

2002-01-01

We apply the perturbative chiral quark model to the study of the low-energy πN interaction. Using an effective chiral Lagrangian we reproduce the Weinberg-Tomozawa result for the S-wave πN scattering lengths. After inclusion of the photon field we give predictions for the electromagnetic O(p 2 ) low-energy couplings of the chiral perturbation theory effective Lagrangian that define the electromagnetic mass shifts of nucleons and first-order (e 2 ) radiative corrections to the πN scattering amplitude. Finally, we estimate the leading isospin-breaking correction to the strong energy shift of the π - p atom in the 1s state, which is relevant for the experiment 'pionic hydrogen' at PSI

Chiral doublet bands in odd-A nuclei 103,105Rh

International Nuclear Information System (INIS)

Qi Bin; Wang Shouyu; Zhang Shuangquan; Meng Jie

2010-01-01

Spontaneous chiral symmetry breaking is a phenomenon of general interest in chemistry, biology and particle physics. Since the pioneering work of nuclear chirality in 1997 [1] , much effort has been devoted to further explore this interesting phenomenon. Following the observation of chiral doublet bands in N = 75 isotones [2] more candidates have been reported over more than 20 nuclei experimentally in A∼100, 130 and 190 mass regions including odd-odd, odd-A and even-even nuclei. However, the identification and the intrinsic mechanism of candidate chiral doublet bands are still under debate. Although various versions of particle rotor model (PRM) and titled axis cranking model (TAC) had been applied to study chiral bands, the essential starting point for understanding their properties is based on the ideal picture, i.e. one particle and one hole coupled with a γ = 30 rigid triaxial rotor. On the other hand, from the investigation of semiclassical TAC based on the mean field, it is shown that the chiral doublet bands in the real nuclei are not always consistent with the static chirality, but mixed with the character of dynamic chirality. Thus it is necessary to construct a fully quantal model for the description of chiral doublet bands in the real nuclei, which is aimed to understand the properties of chiral doublet bands in real nuclei, and to present clearly the picture and character of chiral motion [3] . Recently, we have developed the multi-particle multi-hole coupled with the triaxial rotor model, which is able to describe the nuclear rotation related to many valence nucleons. Adopting this model, chirality in odd-A nuclei 103,105 Rh with πg 9/2 -1 ⊗νh 11/2 2 configuration and in odd-A nucleus 135 Nd with πh 11/2 2 ⊗νh 11/2 1 configuration [4] are studied in a fully quantal approach. For the chiral doublet bands, the observed energies and the B(M1) and B(E2) values are reproduced very well. Root mean square values of the angular momentum components

Computation of the chiral condensate using N{sub f}=2 and N{sub f}=2+1+1 dynamical flavors of twisted mass fermions

Energy Technology Data Exchange (ETDEWEB)

Cichy, K. [Deutsches Elektronen-Synchrotron (DESY), Zeuthen (Germany). John von Neumann-Inst. fuer Computing NIC; Poznan Univ. (Poland). Faculty of Physics; Garcia-Ramos, E. [Deutsches Elektronen-Synchrotron (DESY), Zeuthen (Germany). John von Neumann-Inst. fuer Computing NIC; Humboldt-Universitaet, Berlin (Germany); Jansen, K. [Deutsches Elektronen-Synchrotron (DESY), Zeuthen (Germany). John von Neumann-Inst. fuer Computing NIC; Shindler, A. [Forschungszentrum Juelich (Germany). IAS; Forschungszentrum Juelich (Germany). IKP; Forschungszentrum Juelich (Germany). JCHP; Collaboration: European Twisted Mass Collaboration

2013-12-15

We apply the spectral projector method, recently introduced by Giusti and Luescher, to compute the chiral condensate using N{sub f}=2 and N{sub f}=2+1+1 dynamical flavors of maximally twisted mass fermions. We present our results for several quark masses at three different lattice spacings which allows us to perform the chiral and continuum extrapolations. In addition we report our analysis on the O(a) improvement of the chiral condensate for twisted mass fermions. We also study the effect of the dynamical strange and charm quarks by comparing our results for N{sub f}=2 and N{sub f}=2+1+1 dynamical flavors.

Aldol Reactions of Axially Chiral 5-Methyl-2-(o-arylimino-3-(o-aryl-thiazolidine-4-ones

Directory of Open Access Journals (Sweden)

Sule Erol Gunal

2016-06-01

Full Text Available Axially chiral 5-methyl-2-(o-arylimino-3-(o-aryl-thiazolidine-4-ones have been subjected to aldol reactions with benzaldehyde to produce secondary carbinols which have been found to be separable by HPLC on a chiral stationary phase. Based on the reaction done on a single enantiomer resolved via a chromatographic separation from a racemic mixture of 5-methyl-2-(α-naphthylimino-3-(α-naphthyl-thiazolidine-4-one by HPLC on a chiral stationary phase, the aldol reaction was shown to proceed via an enolate intermediate. The axially chiral enolate of the thiazolidine-4-one was found to shield one face of the heterocyclic ring rendering face selectivity with respect to the enolate. The selectivities observed at C-5 of the ring varied from none to 11.5:1 depending on the size of the ortho substituent. Although the aldol reaction proceeded with a lack of face selectivity with respect to benzaldehyde, recrystallization returned highly diastereomerically enriched products.

Self-assembly of chiral molecular polygons.

Science.gov (United States)

Jiang, Hua; Lin, Wenbin

2003-07-09

Treatment of 2,2'-diacetyl-1,1'-binaphthyl-6,6'-bis(ethyne), L-H2, with 1 equiv of trans-Pt(PEt3)2Cl2 led to a mixture of different sizes of chiral metallocycles [trans-(PEt3)2Pt(L)]n (n = 3-8, 1-6). Each of the chiral molecular polygons 1-6 was purified by silica gel column chromatography and characterized by 1H, 13C{1H}, and 31P{1H} NMR spectroscopy, MS, IR, UV-vis, and circular dichroism spectroscopies, and microanalysis. The presence of tunable cavities (1.4-4.3 nm) and chiral functionalities in these molecular polygons promises to make them excellent receptors for a variety of guests.

Contraction of graded su(2) algebra

International Nuclear Information System (INIS)

Patra, M.K.; Tripathy, K.C.

1989-01-01

The Inoenu-Wigner contraction scheme is extended to Lie superalgebras. The structure and representations of extended BRS algebra are obtained from contraction of the graded su(2) algebra. From cohomological consideration, we demonstrate that the graded su(2) algebra is the only superalgebra which, on contraction, yields the full BRS algebra. (orig.)

Concentration-dependent multiple chirality transition in halogen-bond-driven 2D self-assembly process

Science.gov (United States)

Miao, Xinrui; Li, Jinxing; Zha, Bao; Miao, Kai; Dong, Meiqiu; Wu, Juntian; Deng, Wenli

2018-03-01

The concentration-dependent self-assembly of iodine substituted thienophenanthrene derivative (5,10-DITD) is investigated at the 1-octanic acid/graphite interface using scanning tunneling microscopy. Three kinds of chiral arrangement and transition of 2D molecular assembly mainly driven by halogen bonding is clearly revealed. At high concentration the molecules self-assembled into a honeycomb-like chiral network. Except for the interchain van der Waals forces, this pattern is stabilized by intermolecular continuous Cdbnd O⋯I⋯S halogen bonds in each zigzag line. At moderate concentration, a chiral kite-like nanoarchitecture are observed, in which the Cdbnd O⋯I⋯S and I⋯Odbnd C halogen bonds, along with the molecule-solvent Cdbnd O⋯I⋯H halogen bonds are the dominated forces to determine the structural formation. At low concentration, the molecules form a chiral cyclic network resulting from the solvent coadsorption mainly by molecule-molecule Cdbnd O⋯I⋯S halogen bonds and molecule-solvent Cdbnd O⋯I⋯H halogen bonds. The density of molecular packing becomes lower with the decreasing of the solution concentration. The solution-concentration dependent self-assembly of thienophenanthrene derivative with iodine and ester chain moieties reveals that the type of intermolecular halogen bond and the number of the co-adsorbing 1-octanic acids by molecule-solvent Cdbnd O⋯I⋯H halogen bonds determine the formation and transformation of chirality. This research emphasizes the role of different types of halogen (I) bonds in the controllable supramolecular structures and provides an approach for the fabrication of chirality.

Torons, chiral symmetry breaking and U(1) problem in σ-model and in gauge theories. Part 1

International Nuclear Information System (INIS)

Zhitnitskij, A.R.

1989-01-01

A novel class of self-dual solutions in σ-models and in SU(2) gauge theories is considered. The solution is defined on manifold with boundary, it has topological charge Q=1/2. The contribution of the corresponding fluctuations and toron configurations to chiral condensate is calculated. This contribution has finite nonzero value. The APS (Atiyah, Patodi, Singer) theorem for a manifold with a boundary is discussed for the O(3) σ model. The necessity of imposing non-local boundary conditions for the Dirac operator is explained. 30 refs.; 4 figs

Chiral effective potential in N = {1/2} non-commutative Wess-Zumino model

International Nuclear Information System (INIS)

Banin, A.T.; Buchbinder, I.L.; Pletnev, N.G.

2004-01-01

We study a structure of holomorphic quantum contributions to the effective action for N = {1/2} noncommutative Wess-Zumino model. Using the symbol operator techniques we present the one-loop chiral effective potential in a form of integral over proper time of the appropriate heat kernel. We prove that this kernel can be exactly found. As a result we obtain the exact integral representation of the one-loop effective potential. Also we study the expansion of the effective potential in a series in powers of the chiral superfield φ and derivative D 2 φ and construct a procedure for systematic calculation of the coefficients in the series. We show that all terms in the series without derivatives can be summed up in an explicit form. (author)

Chiral Models in Noncommutative N=1/2 Four Dimensional Superspace

DEFF Research Database (Denmark)

Ryttov, Thomas; Sannino, Francesco

2005-01-01

We derive the component Lagrangian for a generic N=1/2 supersymmetric chiral model with an arbitrary number of fields in four space-time dimensions. We then investigate a toy model in which the deformation parameter modifies the undeformed potential near the origin of the field space in a way which...

Chiral stationary phase optimized selectivity liquid chromatography: A strategy for the separation of chiral isomers.

Science.gov (United States)

Hegade, Ravindra Suryakant; De Beer, Maarten; Lynen, Frederic

2017-09-15

Chiral Stationary-Phase Optimized Selectivity Liquid Chromatography (SOSLC) is proposed as a tool to optimally separate mixtures of enantiomers on a set of commercially available coupled chiral columns. This approach allows for the prediction of the separation profiles on any possible combination of the chiral stationary phases based on a limited number of preliminary analyses, followed by automated selection of the optimal column combination. Both the isocratic and gradient SOSLC approach were implemented for prediction of the retention times for a mixture of 4 chiral pairs on all possible combinations of the 5 commercial chiral columns. Predictions in isocratic and gradient mode were performed with a commercially available and with an in-house developed Microsoft visual basic algorithm, respectively. Optimal predictions in the isocratic mode required the coupling of 4 columns whereby relative deviations between the predicted and experimental retention times ranged between 2 and 7%. Gradient predictions led to the coupling of 3 chiral columns allowing baseline separation of all solutes, whereby differences between predictions and experiments ranged between 0 and 12%. The methodology is a novel tool allowing optimizing the separation of mixtures of optical isomers. Copyright © 2017 Elsevier B.V. All rights reserved.

Enantioselectively controlled release of chiral drug (metoprolol) using chiral mesoporous silica materials

Energy Technology Data Exchange (ETDEWEB)

Guo Zhen; Liu Xianbin; Ng, Siu-Choon; Chen Yuan; Yang Yanhui [School of Chemical and Biomedical Engineering, Nanyang Technological University, Singapore 637459 (Singapore); Du Yu, E-mail: du_yu@jlu.edu.cn, E-mail: yhyang@ntu.edu.sg [College of Electronic Science and Engineering, Jilin University, Changchun 130012 (China)

2010-04-23

Chiral porous materials have attracted burgeoning attention on account of their potential applications in many areas, such as enantioseparation, chiral catalysis, chemical sensors and drug delivery. In this report, chiral mesoporous silica (CMS) materials with various pore sizes and structures were prepared using conventional achiral templates (other than chiral surfactant) and a chiral cobalt complex as co-template. The synthesized CMS materials were characterized by x-ray diffraction, nitrogen physisorption, scanning electron microscope and transmission electron microscope. These CMS materials, as carriers, were demonstrated to be able to control the enantioselective release of a representative chiral drug (metoprolol). The release kinetics, as modeled by the power law equation, suggested that the release profiles of metoprolol were remarkably dependent on the pore diameter and pore structure of CMS materials. More importantly, R- and S-enantiomers of metoprolol exhibited different release kinetics on CMS compared to the corresponding achiral mesoporous silica (ACMS), attributable to the existence of local chirality on the pore wall surface of CMS materials. The chirality of CMS materials on a molecular level was further substantiated by vibrational circular dichroism measurements.

Enantioselectively controlled release of chiral drug (metoprolol) using chiral mesoporous silica materials

International Nuclear Information System (INIS)

Guo Zhen; Liu Xianbin; Ng, Siu-Choon; Chen Yuan; Yang Yanhui; Du Yu

2010-01-01

Chiral porous materials have attracted burgeoning attention on account of their potential applications in many areas, such as enantioseparation, chiral catalysis, chemical sensors and drug delivery. In this report, chiral mesoporous silica (CMS) materials with various pore sizes and structures were prepared using conventional achiral templates (other than chiral surfactant) and a chiral cobalt complex as co-template. The synthesized CMS materials were characterized by x-ray diffraction, nitrogen physisorption, scanning electron microscope and transmission electron microscope. These CMS materials, as carriers, were demonstrated to be able to control the enantioselective release of a representative chiral drug (metoprolol). The release kinetics, as modeled by the power law equation, suggested that the release profiles of metoprolol were remarkably dependent on the pore diameter and pore structure of CMS materials. More importantly, R- and S-enantiomers of metoprolol exhibited different release kinetics on CMS compared to the corresponding achiral mesoporous silica (ACMS), attributable to the existence of local chirality on the pore wall surface of CMS materials. The chirality of CMS materials on a molecular level was further substantiated by vibrational circular dichroism measurements.

Partition function of a chiral boson on a 2-torus from the Floreanini–Jackiw Lagrangian

International Nuclear Information System (INIS)

Chen, Wei-Ming; Ho, Pei-Ming; Kao, Hsien-chung; Khoo, Fech Scen; Matsuo, Yutaka

2014-01-01

We revisit the problem of quantizing a chiral boson on a torus. The conventional approach is to extract the partition function of a chiral boson from the path integral of a non-chiral boson. Instead we compute it directly from the chiral boson Lagrangian of Floreanini and Jackiw modified by topological terms involving an auxiliary field. A careful analysis of the gauge-fixing condition for the extra gauge symmetry reproduces the correct results for the free chiral boson, and has the advantage of being applicable to a wider class of interacting chiral boson theories

Even- and Odd-Parity Charmed Meson Masses in Heavy Hadron Chiral Perturbation Theory

Energy Technology Data Exchange (ETDEWEB)

Thomas Mehen; Roxanne Springer

2005-03-01

We derive mass formulae for the ground state, J{sup P} = 0{sup -} and 1{sup -}, and first excited even-parity, J{sup P} = 0{sup +} and 1{sup +}, charmed mesons including one loop chiral corrections and {Omicron}(1/m{sub c}) counterterms in heavy hadron chiral perturbation theory. We show a variety of fits to the current data. We find that certain parameter relations in the parity doubling model are not renormalized at one loop, providing a natural explanation for the equality of the hyperfine splittings of ground state and excited doublets.

Chiral discotics; expression and amplification of chirality

NARCIS (Netherlands)

Brunsveld, L.; Meijer, E.W.; Rowan, A.E.; Nolte, R.J.M.; Denmark, S.E.; Nolte, R.J.M.; Meijer, E.W.

2003-01-01

In this contribution, chirality and discotic liquid crystals are discussed as a tool for studying the self-assembly of these molecules, both in solution and in the solid state. Therefore, the objective of this chapter is to summarize and elucidate how molecular chirality can be expressed in discotic

Static and dynamical anomalies caused by chiral soliton lattice in molecular-based chiral magnets

International Nuclear Information System (INIS)

Kishine, Jun-ichiro; Inoue, Katsuya; Kikuchi, Koichi

2007-01-01

Interplay of crystallographic chirality and magnetic chirality has been of great interest in both chemist's and physicist's viewpoints. Crystals belonging to chiral space groups are eligible to stabilize macroscopic chiral magnetic order. This class of magnetic order is described by the chiral XY model, where the transverse magnetic field perpendicular to the chiral axis causes the chiral soliton lattice (CSL) formation. As a clear evidence of the chiral magnetic order, the temperature dependence of the transverse magnetization exhibits sharp cusp just below the mean field ferrimagnetic transition temperature, indicating the formation of the CSL. In addition to the static anomaly, we expect the CSL formation also causes dynamical anomalies such as induction of the spin supercurrent

Light pseudoscalar mesons in a nonlocal SU(3) chiral quark model

International Nuclear Information System (INIS)

Scarpettini, A.; Gomez Dumm, D.; Scoccola, Norberto N.

2004-01-01

We study the properties of the light pseudoscalar mesons in a three-flavor chiral quark model with nonlocal separable interactions. We concentrate on the evaluation of meson masses and decay constants, considering both the cases of Gaussian and Lorentzian nonlocal regulators. The results are found to be in quite good agreement with the empirical values, in particular in the case of the ratio f K /f π and the anomalous decay π 0 →γγ. In addition, the model leads to a reasonable description of the observed phenomenology in the η-η ' sector, even though it implies the existence of two significantly different state mixing angles

Moduli stabilisation for chiral global models

International Nuclear Information System (INIS)

Cicoli, Michele; Mayrhofer, Christoph; Valandro, Roberto

2011-10-01

We combine moduli stabilisation and (chiral) model building in a fully consistent global set-up in Type IIB/F-theory. We consider compactifications on Calabi-Yau orientifolds which admit an explicit description in terms of toric geometry. We build globally consistent compactifications with tadpole and Freed-Witten anomaly cancellation by choosing appropriate brane set-ups and world-volume fluxes which also give rise to SU(5)- or MSSM-like chiral models. We fix all the Kaehler moduli within the Kaehler cone and the regime of validity of the 4D effective field theory. This is achieved in a way compatible with the local presence of chirality. The hidden sector generating the non-perturbative effects is placed on a del Pezzo divisor that does not have any chiral intersections with any other brane. In general, the vanishing D-term condition implies the shrinking of the rigid divisor supporting the visible sector. However, we avoid this problem by generating r< n D-term conditions on a set of n intersecting divisors. The remaining (n-r) flat directions are fixed by perturbative corrections to the Kaehler potential. We illustrate our general claims in an explicit example. We consider a K3-fibred Calabi-Yau with four Kaehler moduli, that is an hypersurface in a toric ambient space and admits a simple F-theory up-lift. We present explicit choices of brane set-ups and fluxes which lead to three different phenomenological scenarios: the first with GUT-scale strings and TeV-scale SUSY by fine-tuning the background fluxes; the second with an exponentially large value of the volume and TeV-scale SUSY without fine-tuning the background fluxes; and the third with a very anisotropic configuration that leads to TeV-scale strings and two micron-sized extra dimensions. The K3 fibration structure of the Calabi-Yau three-fold is also particularly suitable for cosmological purposes. (orig.)

Moduli stabilisation for chiral global models

Energy Technology Data Exchange (ETDEWEB)

Cicoli, Michele [Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany); Abdus Salam International Centre for Theoretical Physics, Trieste (Italy); Mayrhofer, Christoph [Heidelberg Univ. (Germany). Inst. fuer Theoretische Physik; Valandro, Roberto [Hamburg Univ. (Germany). 2. Inst. fuer Theoretische Physik

2011-10-15

We combine moduli stabilisation and (chiral) model building in a fully consistent global set-up in Type IIB/F-theory. We consider compactifications on Calabi-Yau orientifolds which admit an explicit description in terms of toric geometry. We build globally consistent compactifications with tadpole and Freed-Witten anomaly cancellation by choosing appropriate brane set-ups and world-volume fluxes which also give rise to SU(5)- or MSSM-like chiral models. We fix all the Kaehler moduli within the Kaehler cone and the regime of validity of the 4D effective field theory. This is achieved in a way compatible with the local presence of chirality. The hidden sector generating the non-perturbative effects is placed on a del Pezzo divisor that does not have any chiral intersections with any other brane. In general, the vanishing D-term condition implies the shrinking of the rigid divisor supporting the visible sector. However, we avoid this problem by generating r

Fast algorithms for chiral fermions in 2 dimensions

Directory of Open Access Journals (Sweden)

Hyka (Xhako Dafina

2018-01-01

Full Text Available In lattice QCD simulations the formulation of the theory in lattice should be chiral in order that symmetry breaking happens dynamically from interactions. In order to guarantee this symmetry on the lattice one uses overlap and domain wall fermions. On the other hand high computational cost of lattice QCD simulations with overlap or domain wall fermions remains a major obstacle of research in the field of elementary particles. We have developed the preconditioned GMRESR algorithm as fast inverting algorithm for chiral fermions in U(1 lattice gauge theory. In this algorithm we used the geometric multigrid idea along the extra dimension.The main result of this work is that the preconditioned GMRESR is capable to accelerate the convergence 2 to 12 times faster than the other optimal algorithms (SHUMR for different coupling constant and lattice 32x32. Also, in this paper we tested it for larger lattice size 64x64. From the results of simulations we can see that our algorithm is faster than SHUMR. This is a very promising result that this algorithm can be adapted also in 4 dimension.

Chiral derivatives of 2-(1-naphthyl)-2-phenylacetic acid

Czech Academy of Sciences Publication Activity Database

Vávra, J.; Vodička, Petr; Streinz, Ludvík; Buděšínský, Miloš; Koutek, Bohumír; Ondráček, Jan; Císařová, I.

2004-01-01

Roč. 16, - (2004), s. 652-660 ISSN 0899-0042 R&D Projects: GA ČR GA203/01/0116 Institutional research plan: CEZ:AV0Z4055905 Keywords : chiral analysis * NMR * derivatization Subject RIV: CC - Organic Chemistry Impact factor: 1.976, year: 2004

Supersymmetric SU(5) GUT with Stabilized Moduli

CERN Document Server

Antoniadis, Ignatios; Panda, Binata

2008-01-01

We construct a minimal example of a supersymmetric grand unified model in a toroidal compactification of type I string theory with magnetized D9-branes. All geometric moduli are stabilized in terms of the background internal magnetic fluxes which are of "oblique" type (mutually non-commuting). The gauge symmetry is just SU(5) and the gauge non-singlet chiral spectrum contains only three families of quarks and leptons transforming in the $10+{\\bar 5}$ representations.

Deracemization of Racemic Amino Acids Using (R)- and (S)-Alanine Racemase Chiral Analogues as Chiral Converters

International Nuclear Information System (INIS)

Paik, Manjeong; Jeon, So Hee; Lee, Wonjae; Kang, Jong Seong; Kim, Kwan Mook

2014-01-01

Our findings show that both (R)- and (S)-ARCA can be practical chiral converters for L- and D-amino acids, respectively, in the deracemization of racemic amino acids. The overall stereoselectivities of both chiral converters are generally greater than 90%. In addition, we developed chiral and achiral HPLC methods for the analysis of stereoselectivity determination. This chromatographic method proved much more accurate and convenient at determining both enantiomer and diastereomer purity than did those previously reported. Deracemization is the stereoselective process of converting a racemate into either a pure enantiomer or a mixture in which one enantiomer is present in excess.1 Previous studies have shown that (S)-alanine racemase chiral analogue (ARCA) [(S)-2-hydroxy-2'-(3-phenyluryl-benzyl)-1,1'-binaphthyl-3-carboxaldehyde], developed as a chiral convertor compound that imitates the function of alanine racemase, plays an essential role in the stereoselective conversion of amino acid. Since (S)-ARCA showed a higher stability with D-amino acids than with L-amino acids, several L-amino acids were preferentially converted to D-amino acids via (S)-ARCA/D-amino acid imine diastereomer formation. For the deracemization process undertaken in this study, we utilized both (R)-ARCA and (S)-ARCA as chiral converters, which were expected to generate L- and D-amino acids, respectively, from the starting racemic mixtures

Chiral measurements with the Fixed-Point Dirac operator and construction of chiral currents

International Nuclear Information System (INIS)

Hasenfratz, P.; Hauswirth, S.; Holland, K.; Joerg, T.; Niedermayer, F.

2002-01-01

In this preliminary study, we examine the chiral properties of the parametrized Fixed-Point Dirac operator D FP , see how to improve its chirality via the Overlap construction, measure the renormalized quark condensate Σ-circumflex and the topological susceptibility χ t , and investigate local chirality of near zero modes of the Dirac operator. We also give a general construction of chiral currents and densities for chiral lattice actions

Synthesis, structure, and properties of a series of chiral tweezer-diamine complexes consisting of an achiral zinc(II) bisporphyrin host and chiral diamine guest: induction and rationalization of supramolecular chirality.

Science.gov (United States)

Brahma, Sanfaori; Ikbal, Sk Asif; Rath, Sankar Prasad

2014-01-06

We report here the synthesis, structure, and spectroscopic properties of a series of supramolecular chiral 1:1 tweezer-diamine complexes consisting of an achiral Zn(II) bisporphyrin (Zn2DPO) host and five different chiral diamine guests, namely, (R)-diaminopropane (DAP), (1S,2S)-diaminocyclohexane (CHDA), (S)-phenylpropane diamine (PPDA), (S)-phenyl ethylenediamine (PEDA), and (1R,2R)-diphenylethylene diamine (DPEA). The solid-state structures are preserved in solution, as reflected in their (1)H NMR spectra, which also revealed the remarkably large upfield shifts of the NH2 guest protons with the order Zn2DPO·DAP > Zn2DPO·CHDA > Zn2DPO·PPDA> Zn2DPO·PEDA ≫ Zn2DPO·DPEA, which happens to be the order of binding constants of the respective diamines with Zn2DPO. As the bulk of the substituent at the chiral center of the guest ligand increases, the Zn-Nax distance of the tweezer-diamine complex also increases, which eventually lowers the binding of the guest ligand toward the host. Also, the angle between the two porphyrin rings gradually increases with increasing bulk of the guest in order to accommodate the guest within the bisporphyrin cavity with minimal steric clash. The notably high amplitude bisignate CD signal response by Zn2DPO·DAP, Zn2DPO·CHDA, and Zn2DPO·PPDA can be ascribed to the complex's high stability and the formation of a unidirectional screw as observed in the X-ray structures of the complexes. A relatively lower value of CD amplitude shown by Zn2DPO·PEDA is due to the lower stability of the complex. The projection of the diamine binding sites of the chiral guest would make the two porphyrin macrocycles oriented in either a clockwise or anticlockwise direction in order to minimize host-guest steric clash. In sharp contrast, Zn2DPO·DPEA shows a very low amplitude bisignate CD signal due to the presence of both left- (dictated by the pre-existing chirality of (1R,2R)-DPEA) and right-handed screws (dictated by the steric differentiation at

Chiral charge erasure via thermal fluctuations of magnetic helicity

International Nuclear Information System (INIS)

Long, Andrew J.; Sabancilar, Eray

2016-01-01

We consider a relativistic plasma of fermions coupled to an Abelian gauge field and carrying a chiral charge asymmetry, which might arise in the early Universe through baryogenesis. It is known that on large length scales, λ≳1/(αμ_5), the chiral anomaly opens an instability toward the erasure of chiral charge and growth of magnetic helicity. Here the chemical potential μ_5 parametrizes the chiral asymmetry and α is the fine-structure constant. We study the process of chiral charge erasure through the thermal fluctuations of magnetic helicity and contrast with the well-studied phenomenon of Chern-Simons number diffusion. Through the fluctuation-dissipation theorem we estimate the amplitude and time scale of helicity fluctuations on the length scale λ, finding δ H∼λT and τ∼αλ"3T"2 for a relativistic plasma at temperature T. We argue that the presence of a chiral asymmetry allows the helicity to grow diffusively for a time t∼T"3/(α"5μ_5"4) until it reaches an equilibrium value H∼μ_5T"2/α, and the chiral asymmetry is partially erased. If the chiral asymmetry is small, μ_5< T/α, this avenue for chiral charge erasure is found to be slower than the chiral magnetic effect for which t∼T/(α"3μ_5"2). This mechanism for chiral charge erasure can be important for the hypercharge sector of the Standard Model as well as extensions including U(1) gauge interactions, such as asymmetric dark matter models.

Effects of chirality and surface stresses on the bending and buckling of chiral nanowires

International Nuclear Information System (INIS)

Wang, Jian-Shan; Shimada, Takahiro; Kitamura, Takayuki; Wang, Gang-Feng

2014-01-01

Due to their superior optical, elastic and electrical properties, chiral nanowires have many applications as sensors, probes, and building blocks of nanoelectromechanical systems. In this paper, we develop a refined Euler–Bernoulli beam model for chiral nanowires with surface effects and material chirality incorporated. This refined model is employed to investigate the bending and buckling of chiral nanowires. It is found that surface effects and material chirality significantly affect the elastic behaviour of chiral nanowires. This study is helpful not only for understanding the size-dependent behaviour of chiral nanowires, but also for characterizing their mechanical properties. (paper)

Chiral heat wave and mixing of magnetic, vortical and heat waves in chiral media

International Nuclear Information System (INIS)

Chernodub, M.N.

2016-01-01

We show that a hot rotating fluid of relativistic chiral fermions possesses a new gapless collective mode associated with coherent propagation of energy density and chiral density waves along the axis of rotation. This mode, which we call the Chiral Heat Wave, emerges due to a mixed gauge-gravitational anomaly. At finite density the Chiral Heat Wave couples to the Chiral Vortical Wave while in the presence of an external magnetic field it mixes with the Chiral Magnetic Wave. The coupling of the Chiral Magnetic and Chiral Vortical Waves is also demonstrated. We find that the coupled waves — which are coherent fluctuations of the vector, axial and energy currents — have generally different velocities compared to the velocities of the individual waves.

Enantioseparation and chiral recognition mechanism of new chiral derivatives of xanthones on macrocyclic antibiotic stationary phases.

Science.gov (United States)

Fernandes, Carla; Tiritan, Maria Elizabeth; Cass, Quezia; Kairys, Visvaldas; Fernandes, Miguel Xavier; Pinto, Madalena

2012-06-08

A chiral HPLC method using four macrocyclic antibiotic chiral stationary phases (CSPs) has been investigated for determination of the enantiomeric purity of fourteen new chiral derivatives of xanthones (CDXs). The separations were performed with the CSPs Chirobiotic T, Chirobiotic TAG, Chirobiotic V and Chirobiotic R under multimodal elution conditions (normal-phase, reversed-phase and polar ionic mode). The analyses were performed at room temperature in isocratic mode and UV and CD detection at a wavelength of 254 nm. The best enantioselectivity and resolution were achieved on Chirobiotic R and Chirobiotic T CSPs, under normal elution conditions, with R(S) ranging from 1.25 to 2.50 and from 0.78 to 2.06, respectively. The optimized chromatographic conditions allowed the determination of the enantiomeric ratio of eight CDXs, always higher than 99%. In order to better understand the chromatographic behavior at a molecular level, and the structural features associated with the chiral recognition mechanism, computational studies by molecular docking were carried out using VDock. These studies shed light on the mechanisms involved in the enantioseparation for this important class of chiral compounds. Copyright © 2012 Elsevier B.V. All rights reserved.

Nf=2 Lattice QCD and Chiral Perturbation Theory

International Nuclear Information System (INIS)

Scorzato, L.; Farchioni, F.; Hofmann, P.; Jansen, K.; Montvay, I.; Muenster, G.; Papinutto, M.; Scholz, E.E.; Shindler, A.; Ukita, N.; Urbach, C.; Wenger, U.; Wetzorke, I.

2006-01-01

By employing a twisted mass term, we compare recent results from lattice calculations of N f =2 dynamical Wilson fermions with Wilson Chiral Perturbation Theory (WChPT). The final goal is to determine some com- binations of Gasser-Leutwyler Low Energy Constants (LECs). A wide set of data with different lattice spacings (a ∼ 0.2 - 0.12 fm), different gauge actions (Wilson plaquette, DBW2) and different quark masses (down to the lowest pion mass allowed by lattice artifacts and including negative quark masses) provide a strong check of the applicability of WChPT in this regime and the scaling behaviours in the continuum limit

Universality in random matrix theory and chiral symmetry breaking in QCD

International Nuclear Information System (INIS)

Akemann, G.

2000-05-01

In this work we review the topic of random matrix model universality with particular stress on its application to the study of chiral symmetry breaking in QCD. We highlight the role of microscopic and macroscopic matrix model correlation functions played in the description of the deep infrared eigenvalue spectrum of the Dirac operator. The universal microscopic correlation functions are presented for all three chiral symmetry breaking patterns, and the corresponding random matrix universality proofs are given for massless and massive fermions in a unified way. These analytic results have been widely confirmed from QCD lattice data and we present a comparison with the most recent analytic calculations describing data for dynamical SU(2) staggered fermions. The microscopic matrix model results are then re-expressed in terms of the finite-volume partition functions of Leutwyler and Smilga, where some of these expressions have been recently obtained using field theory only. The macroscopic random matrix universality is reviewed for the most simplest examples of bosonic and supersymmetric models. We also give an example for a non-universal deformation of a random matrix model - the restricted trace ensemble. (orig.)

Macroscopic chirality of a liquid crystal from nonchiral molecules

International Nuclear Information System (INIS)

Jakli, A.; Nair, G. G.; Lee, C. K.; Sun, R.; Chien, L. C.

2001-01-01

The transfer of chirality from nonchiral polymer networks to the racemic B2 phase of nonchiral banana-shaped molecules is demonstrated. This corresponds to the transfer of chirality from an achiral material to another achiral material. There are two levels of chirality transfers. (a) On a microscopic level the presence of a polymer network (chiral or nonchiral) favors a chiral state over a thermodynamically stable racemic state due to the inversion symmetry breaking at the polymer-liquid crystal interfaces. (b) A macroscopically chiral (enantimerically enriched) sample can be produced if the polymer network has a helical structure, and/or contains chemically chiral groups. The chirality transfer can be locally suppressed by exposing the liquid crystal to a strong electric field treatment

Entropy of entangled states and SU(1,1) and SU(2) symmetries

International Nuclear Information System (INIS)

Santana, A.E.; Khanna, F.C.; Revzen, M.

2002-01-01

Based on a recent definition of a measure for entanglement [Plenio and Vedral, Contemp. Phys. 39, 431 (1998)], examples of maximum entangled states are presented. The construction of such states, which have symmetry SU(1,1) and SU(2), follows the guidance of thermofield dynamics formalism

Chiral Induction with Chiral Conformational Switches in the Limit of Low "Sergeants to Soldiers" Ratio

DEFF Research Database (Denmark)

Nuermaimaiti, Ajiguli; Bombis, Christian; Knudsen, Martin Markvard

2014-01-01

Molecular-level insights into chiral adsorption phenomena are highly relevant within the fields of asymmetric heterogeneous catalysis or chiral separation and may contribute to understand the origins of homochirality in nature. Here, we investigate chiral induction by the "sergeants and soldiers......" mechanism for an oligo(phenylene ethynylene) based chiral conformational switch by coadsorbing it with an intrinsically chiral seed on Au(111). Through statistical analysis of scanning tunneling microscopy (STM) data we demonstrate successful chiral induction with a very low concentration of seeding...... molecules down to 3%. The microscopic mechanism for the observed chiral induction is suggested to involve nucleation of the intrinsically chiral seeds, allowing for effective transfer and amplification of chirality to large numbers of soldier target molecules....

Chiral dynamics of baryons in the perturbative chiral quark model

Energy Technology Data Exchange (ETDEWEB)

Pumsa-ard, K.

2006-07-01

In this work we develop and apply variants of a perturbative chiral quark model (PCQM) to the study of baryonic properties dominantly in the low-energy region. In a first step we consider a noncovariant form of the PCQM, where confinement is modelled by a static, effective potential and chiral corrections are treated to second order, in line with similar chiral quark models. We apply the PCQM to the study of the electromagnetic form factors of the baryon octet. We focus in particular on the low-energy observables such as the magnetic moments, the charge and magnetic radii. In addition, the electromagnetic N-delta transition is also studied in the framework of the PCQM. In the chiral loop calculations we consider a quark propagator, which is restricted to the quark ground state, or in hadronic language to nucleon and delta intermediate states, for simplicity. We furthermore include the low-lying excited states to the quark propagator. In particular, the charge radius of the neutron and the transverse helicity amplitudes of the N-delta transition are considerably improved by this additional effect. In a next step we develop a manifestly Lorentz covariant version of the PCQM, where in addition higher order chiral corrections are included. The full chiral quark Lagrangian is motivated by and in analogy to the one of Chiral Perturbation Theory (ChPT). This Lagrangian contains a set of low energy constants (LECs), which are parameters encoding short distance effects and heavy degrees of freedom. We evaluate the chiral Lagrangian to order O(p{sup 4}) and to one loop to generate the dressing of the bare quark operators by pseudoscalar mesons. In addition we include the vector meson degrees of freedom in our study. Projection of the dressed quark operators on the baryonic level serves to calculate the relevant matrix elements. In a first application of this scheme, we resort to a parameterization of the valence quark form factors in the electromagnetic sector. Constraints

Chiral dynamics and peripheral transverse densities

Energy Technology Data Exchange (ETDEWEB)

Granados, Carlos G. [Uppsala University (Sweden); Weiss, Christian [JLAB, Newport News, VA (United States)

2014-01-01

In the partonic (or light-front) description of relativistic systems the electromagnetic form factors are expressed in terms of frame-independent charge and magnetization densities in transverse space. This formulation allows one to identify the chiral components of nucleon structure as the peripheral densities at transverse distances b = O(M{sub {pi}}{sup -1}) and compute them in a parametrically controlled manner. A dispersion relation connects the large-distance behavior of the transverse charge and magnetization densities to the spectral functions of the Dirac and Pauli form factors near the two--pion threshold at timelike t = 4 M{ sub {pi}}{sup 2}, which can be computed in relativistic chiral effective field theory. Using the leading-order approximation we (a) derive the asymptotic behavior (Yukawa tail) of the isovector transverse densities in the "chiral" region b = O(M{sub {pi}}{sup -1}) and the "molecular" region b = O(M{sub N}{sup 2}/M{sub {pi}}{sup 3}); (b) perform the heavy-baryon expansion of the transverse densities; (c) explain the relative magnitude of the peripheral charge and magnetization densities in a simple mechanical picture; (d) include Delta isobar intermediate states and study the peripheral transverse densities in the large-N{ sub c} limit of QCD; (e) quantify the region of transverse distances where the chiral components of the densities are numerically dominant; (f) calculate the chiral divergences of the b{sup 2}-weighted moments of the isovector transverse densities (charge and anomalous magnetic radii) in the limit M{sub {pi}} -> 0 and determine their spatial support. Our approach provides a concise formulation of the spatial structure of the nucleon's chiral component and offers new insights into basic properties of the chiral expansion. It relates the information extracted from low-t elastic form factors to the generalized parton distributions probed in peripheral high-energy scattering processes.

S-wave Kπ scattering in chiral perturbation theory with resonances

International Nuclear Information System (INIS)

Jamin, Matthias; Oller, Jose Antonio; Pich, Antonio

2000-01-01

We present a detailed analysis of S-wave Kπ scattering up to 2 GeV, making use of the resonance chiral Lagrangian predictions together with a suitable unitarisation method. Our approach incorporates known theoretical constraints at low and high energies. The present experimental status, with partly conflicting data from different experiments, is discussed. Our analysis allows to resolve some experimental ambiguities, but better data are needed in order to determine the cross-section in the higher-energy range. Our best fits are used to determine the masses and widths of the relevant scalar resonances in this energy region

Chiral Recognition by Fluorescence: One Measurement for Two Parameters

Directory of Open Access Journals (Sweden)

Shanshan Yu

2014-01-01

Full Text Available This outlook describes two strategies to simultaneously determine the enantiomeric composition and concentration of a chiral substrate by a single fluorescent measurement. One strategy utilizes a pseudoenantiomeric sensor pair that is composed of a 1,1′-bi-2-naphthol-based amino alcohol and a partially hydrogenated 1,1′-bi-2-naphthol-based amino alcohol. These two molecules have the opposite chiral configuration with fluorescent enhancement at two different emitting wavelengths when treated with the enantiomers of mandelic acid. Using the sum and difference of the fluorescent intensity at the two wavelengths allows simultaneous determination of both concentration and enantiomeric composition of the chiral acid. The other strategy employs a 1,1′-bi-2-naphthol-based trifluoromethyl ketone that exhibits fluorescent enhancement at two emission wavelengths upon interaction with a chiral diamine. One emission responds mostly to the concentration of the chiral diamine and the ratio of the two emissions depends on the chiral configuration of the enantiomer but independent of the concentration, allowing both the concentration and enantiomeric composition of the chiral diamine to be simultaneously determined. These strategies would significantly simplify the practical application of the enantioselective fluorescent sensors in high-throughput chiral assay.

Quenched chiral logarithms

International Nuclear Information System (INIS)

Sharpe, S.R.

1992-04-01

I develop a diagrammatic method for calculating chiral logarithms in the quenched approximation. While not rigorous, the method is based on physically reasonable assumptions, which can be tested by numerical simulations. The main results are that, at leading order in the chiral expansion, (a) there are no chiral logarithms in quenched f π m u = m d ; (b) the chiral logarithms in B K and related kaon B-parameters are, for m d = m s the same in the quenched approximation as in the full theory (c) for m π and the condensate, there are extra chiral logarithms due to loops containing the η', which lead to a peculiar non-analytic dependence of these quantities on the bare quark mass. Following the work of Gasser and Leutwyler, I discuss how there is a predictable finite volume dependence associated with each chiral logarithm. I compare the resulting predictions with numerical results: for most quantities the expected volume dependence is smaller than the errors. but for B V and B A there is an observed dependence which is consistent with the predictions

Transport coefficients from SU(3) Polyakov linear-σ model

International Nuclear Information System (INIS)

Tawfik, A.; Diab, A.

2015-01-01

In the mean field approximation, the grand potential of SU(3) Polyakov linear-σ model (PLSM) is analyzed for the order parameter of the light and strange chiral phase-transitions, σ l and σ s , respectively, and for the deconfinement order parameters φ and φ*. Furthermore, the subtracted condensate Δ l,s and the chiral order-parameters M b are compared with lattice QCD calculations. By using the dynamical quasiparticle model (DQPM), which can be considered as a system of noninteracting massive quasiparticles, we have evaluated the decay width and the relaxation time of quarks and gluons. In the framework of LSM and with Polyakov loop corrections included, the interaction measure Δ/T 4 , the specific heat c v and speed of sound squared c s 2 have been determined, as well as the temperature dependence of the normalized quark number density n q /T 3 and the quark number susceptibilities χ q /T 2 at various values of the baryon chemical potential. The electric and heat conductivity, σ e and κ, and the bulk and shear viscosities normalized to the thermal entropy, ζ/s and η/s, are compared with available results of lattice QCD calculations.

Strangeness S = -2 baryon-baryon interactions using chiral effective field theory

NARCIS (Netherlands)

Polinder, H.; Haidenbauer, J.; Meissner, U.G.

2007-01-01

We derive the leading order strangeness S =−2 baryon–baryon interactions in chiral effective field theory. The potential consists of contact terms without derivatives and of one-pseudoscalar-meson exchanges. The contact terms and the couplings of the pseudoscalar mesons to the baryons are related

Field-dependent spin chirality and frustration in V3 and Cu3 nanomagnets in transverse magnetic field. 2. Spin configurations, chirality and intermediate spin magnetization in distorted trimers

International Nuclear Information System (INIS)

Belinsky, Moisey I.

2014-01-01

Highlights: • Distorted spin configurations determine field behavior of the variable chiralities. • Distortions change spin chiralities, intermediate M 12 ± and staggered magnetization. • Magnetizations, distorted vector and scalar chiralities are strongly correlated. • Distorted V 3 , Cu 3 nanomagnets possess large vector chirality in the ground state in B ⊥ . • Chiralities and distortions in EPR, INS and NMR spectra were considered. - Abstract: Correlated spin configurations, magnetizations, frustration, vector κ ¯ z and scalar χ ¯ chiralities are considered for distorted V ‾ 3 , /Cu 3 / anisotropic DM nanomagnets in transverse B x ‖X and longitudinal B‖Z fields. Different planar configurations in the ground and excited states of distorted nanomagnets in B x determine different field behavior of the vector chiralities and the degenerate frustration in these states correlated with the M ~ 12 ± (B x ) intermediate spin (IS) magnetization which describes the S 12 characteristics, χ=0. Distortion results in the reduced κ ¯ z <1 chirality in the ground distorted configuration and in the maximum κ z =±1 in the excited states with the planar 120° configurations at avoided level crossing. In B‖Z, distorted longitudinal spin-collinear configurations are characterized by the reduced degenerate frustration, out-of-plane staggered and IS M ~ 12 ± (B z ) magnetizations, and in-plane toroidal moments, correlated with the κ ¯ z , χ ¯ chiralities, χ ¯ =±|κ ¯ z |. The chiralities and IS magnetization in EPR, INS and NMR spectra are considered. The quantitative correlations describe variable spin chirality, frustration and field manipulation of chiralities in nanomagnets

Nonlinear spectroscopic studies of chiral media

International Nuclear Information System (INIS)

Belkin, Mikhail Alexandrovich

2004-01-01

Molecular chirality plays an important role in chemistry, biology, and medicine. Traditional optical techniques for probing chirality, such as circular dichroism and Raman optical activity rely on electric-dipole forbidden transitions. As a result, their intrinsic low sensitivity limits their use to probe bulk chirality rather than chiral surfaces, monolayers or thin films often important for chemical or biological systems. Contrary to the traditional chirality probes, chiral signal in sum-frequency generation (SFG) is electric-dipole allowed both on chiral surface and in chiral bulk making it a much more promising tool for probing molecular chirality. SFG from a chiral medium was first proposed in 1965, but had never been experimentally confirmed until this thesis work was performed. This thesis describes a set of experiments successfully demonstrating that chiral SFG responses from chiral monolayers and liquids are observable. It shows that, with tunable inputs, SFG can be used as a sensitive spectroscopic tool to probe chirality in both electronic and vibrational resonances of chiral molecules. The monolayer sensitivity is feasible in both cases. It also discusses the relevant theoretical models explaining the origin and the strength of the chiral signal in vibrational and electronic SFG spectroscopies

No-scale SU(5) super-GUTs

Energy Technology Data Exchange (ETDEWEB)

Ellis, John [King' s College London, Theoretical Physics and Cosmology Group, Department of Physics, London (United Kingdom); CERN, Theoretical Physics Department, Geneva 23 (Switzerland); Evans, Jason L. [KIAS, School of Physics, Seoul (Korea, Republic of); Nagata, Natsumi [University of Tokyo, Department of Physics, Tokyo, Bunkyo-ku (Japan); Nanopoulos, Dimitri V. [Texas A and M University, George P. and Cynthia W. Mitchell Institute for Fundamental Physics and Astronomy, College Station, TX (United States); Houston Advanced Research Center (HARC), Astroparticle Physics Group, Woodlands, TX (United States); Academy of Athens, Division of Natural Sciences, Athens (Greece); Olive, Keith A. [University of Minnesota, School of Physics and Astronomy, William I. Fine Theoretical Physics Institute, Minneapolis, MN (United States)

2017-04-15

We reconsider the minimal SU(5) grand unified theory (GUT) in the context of no-scale supergravity inspired by string compactification scenarios, assuming that the soft supersymmetry-breaking parameters satisfy universality conditions at some input scale M{sub in} above the GUT scale M{sub GUT}. When setting up such a no-scale super-GUT model, special attention must be paid to avoiding the Scylla of rapid proton decay and the Charybdis of an excessive density of cold dark matter, while also having an acceptable mass for the Higgs boson. We do not find consistent solutions if none of the matter and Higgs fields are assigned to twisted chiral supermultiplets, even in the presence of Giudice-Masiero terms. However, consistent solutions may be found if at least one fiveplet of GUT Higgs fields is assigned to a twisted chiral supermultiplet, with a suitable choice of modular weights. Spin-independent dark matter scattering may be detectable in some of these consistent solutions. (orig.)

Molecular-Level Design of Heterogeneous Chiral Catalysis

International Nuclear Information System (INIS)

Zaera, Francisco

2012-01-01

The following is a proposal to continue our multi-institutional research on heterogeneous chiral catalysis. Our team combines the use of surface-sensitive analytical techniques for the characterization of model systems with quantum and statistical mechanical calculations to interpret experimental data and guide the design of future research. Our investigation focuses on the interrelation among the three main mechanisms by which enantioselectivity can be bestowed to heterogeneous catalysts, namely: (1) by templating chirality via the adsorption of chiral supramolecular assemblies, (2) by using chiral modifiers capable of forming chiral complexes with the reactant and force enantioselective surface reactions, and (3) by forming naturally chiral surfaces using imprinting chiral agents. Individually, the members of our team are leaders in these various aspects of chiral catalysis, but the present program provides the vehicle to generate and exploit the synergies necessary to address the problem in a comprehensive manner. Our initial work has advanced the methodology needed for these studies, including an enantioselective titration procedure to identify surface chiral sites, infrared spectroscopy in situ at the interface between gases or liquids and solids to mimic realistic catalytic conditions, and DFT and Monte Carlo algorithms to simulate and understand chirality on surfaces. The next step, to be funded by the monies requested in this proposal, is to apply those methods to specific problems in chiral catalysis, including the identification of the requirements for the formation of supramolecular surface structures with enantioselective behavior, the search for better molecules to probe the chiral nature of the modified surfaces, the exploration of the transition from supramolecular to one-to-one chiral modification, the correlation of the adsorption characteristics of one-to-one chiral modifiers with their physical properties, in particular with their configuration

The renormalization group in effective chiral theories

International Nuclear Information System (INIS)

Varin, T.

2007-09-01

The dilepton production within the heavy ions collisions (CERN/SPS, SIS/HADES, RHIC) and the behaviour of vector mesons (in particular the rho meson) are among the main topics of quantum chromodynamics (QCD) in hadronic matter. One of the main goals is the study of partial or total restoration of chiral symmetry SU(2) x SU(2), for which effective theories need to be used. One of the important difficulties is to build a theory which allows to obtain predictions when approaching the phase transition by taking into account the phenomenological constraints at low temperature and/or density. The model used here (developed by M. Urban) is based on the gauged (rho and al mesons) linear sigma model adjusted (in practice the local symmetry is only approximate) to reproduce the phenomenology very well. The first part of this thesis consists in presenting a new cut-off based regularization scheme preserving symmetry requirements. The motivation of such a method is a correct accounting of quadratic and logarithmic divergences in view of their intensive use for the renormalisation group equations. For illustrative purposes we have applied it to QED in 4 and 5 dimensions. The second part of this work is devoted to the derivation of the RGE and their resolution. In particular, we show that both restorations (traditional and vector manifestation) can be obtained from our equations, but the most likely remains the 'traditional' Ginzburg-Landau scenario. (author)

Probing chiral superconductivity in Sr_2RuO_4 underneath the surface by point contact measurements

International Nuclear Information System (INIS)

Wang, He; Luo, Jiawei; Lou, Weijian

2017-01-01

Sr2RuO4 (SRO) is the prime candidate for a chiral p-wave superconductor with critical temperature T_c(SRO)∼1.5 K. Chiral domains with opposite chiralities p_x±ip_y have been proposed, but are yet to be confirmed. We measure the field dependence of the point contact (PC) resistance between a tungsten tip and an SRO–Ru eutectic crystal, where micrometer-sized Ru inclusions are embedded in SRO with an atomically sharp interface. Ruthenium is an s-wave superconductor with T_c(Ru)∼0.5 K; flux pinned near the Ru inclusions can suppress its superconductivity, as reflected in the PC resistance and spectra. This flux pinning effect originates from SRO underneath the surface and is very strong once flux is introduced. To fully remove flux pinning, one needs to thermally cycle the sample above T_c(SRO) or apply alternating fields with decreasing amplitude. With alternating fields, the observed hysteresis in magnetoresistance can be explained by domain dynamics, providing support for the existence of chiral domains. The origin of the strong pinning could be the chiral domains themselves.

Rationalization of chirality induction and inversion in a zinc trisporphyrinate by a chiral monoalcohol.

Science.gov (United States)

Li, Li; Hu, Chuanjiang; Shi, Bo; Wang, Yong

2016-05-10

A new host-guest system is formed between a benzene tricarboxamide linked zinc trisporphyrinate and a chiral monoalcohol (1-phenylethylalcohol). CD spectra show the chirality induction and inversion processes, which are controlled by the corresponding 1 : 1 and 1 : 2 coordination complexes. The binding constants calculated by UV-vis and CD spectral data are much larger than that for [Zn(TPP)] (TPP = tetraphenylporphyrin). The crystallographic structure of the host-guest complex reveals that multiple intramolecular hydrogen bonds and π-π interactions could contribute to its high binding affinity to 1-phenylethylalcohol. The DFT calculations suggest that the spatial orientations of porphyrin moieties change from the 1 : 1 complex to the 1 : 2 complex. The chirality induction and inversion processes are rationalized by the summation of pairwise interactions among multichromophores according to pairwise additivity.

Host–Guest Chirality Interplay: A Mutually Induced Formation of a Chiral ZMOF and Its Double-Helix Polymer Guests

KAUST Repository

Luo, Xiaolong

2016-01-12

A novel homochiral zeolite-like metal-organic framework (ZMOF), [(Cu4I4) (dabco)2]·[Cu2(bbimb)]·3DMF (JLU-Liu23, dabco =1,4-diazabicyclo[2.2.2]-octane, H2bbimb =1,3-bis(2-benzimidazol)benzene, DMF = N,N-dimethylformamide), has been successfully constructed to host unprecedented DNA-like [Cu2(bbimb)]n polymers with double-helicity. The host-guest chirality interplay permitted the induced formation of an unusual gyroid MOF with homochirality and helical channels in the framework for the first time, JLU-Liu23. Importantly, the enantiomeric pairs (23P, 23M) can be promoted and isolated in the presence of appropriate chiral inducing agents, affording enantioselective separation of chiral molecules as well as small gas molecules. © 2016 American Chemical Society.

Probing neutrino and Higgs sectors in { SU(2) }_1 × { SU(2) }_2 × { U(1) }_Y model with lepton-flavor non-universality

Science.gov (United States)

Hue, L. T.; Arbuzov, A. B.; Ngan, N. T. K.; Long, H. N.

2017-05-01

The neutrino and Higgs sectors in the { SU(2) }_1 × { SU(2) }_2 × { U(1) }_Y model with lepton-flavor non-universality are discussed. We show that active neutrinos can get Majorana masses from radiative corrections, after adding only new singly charged Higgs bosons. The mechanism for the generation of neutrino masses is the same as in the Zee models. This also gives a hint to solving the dark matter problem based on similar ways discussed recently in many radiative neutrino mass models with dark matter. Except the active neutrinos, the appearance of singly charged Higgs bosons and dark matter does not affect significantly the physical spectrum of all particles in the original model. We indicate this point by investigating the Higgs sector in both cases before and after singly charged scalars are added into it. Many interesting properties of physical Higgs bosons, which were not shown previously, are explored. In particular, the mass matrices of charged and CP-odd Higgs fields are proportional to the coefficient of triple Higgs coupling μ . The mass eigenstates and eigenvalues in the CP-even Higgs sector are also presented. All couplings of the SM-like Higgs boson to normal fermions and gauge bosons are different from the SM predictions by a factor c_h, which must satisfy the recent global fit of experimental data, namely 0.995<|c_h|<1. We have analyzed a more general diagonalization of gauge boson mass matrices, then we show that the ratio of the tangents of the W-W' and Z-Z' mixing angles is exactly the cosine of the Weinberg angle, implying that number of parameters is reduced by 1. Signals of new physics from decays of new heavy fermions and Higgs bosons at LHC and constraints of their masses are also discussed.

Silver Films with Hierarchical Chirality.

Science.gov (United States)

Ma, Liguo; Cao, Yuanyuan; Duan, Yingying; Han, Lu; Che, Shunai

2017-07-17

Physical fabrication of chiral metallic films usually results in singular or large-sized chirality, restricting the optical asymmetric responses to long electromagnetic wavelengths. The chiral molecule-induced formation of silver films prepared chemically on a copper substrate through a redox reaction is presented. Three levels of chirality were identified: primary twisted nanoflakes with atomic crystal lattices, secondary helical stacking of these nanoflakes to form nanoplates, and tertiary micrometer-sized circinates consisting of chiral arranged nanoplates. The chiral Ag films exhibited multiple plasmonic absorption- and scattering-based optical activities at UV/Vis wavelengths based on their hierarchical chirality. The Ag films showed chiral selectivity for amino acids in catalytic electrochemical reactions, which originated from their primary atomic crystal lattices. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

On the SU2 unit tensor

International Nuclear Information System (INIS)

Kibler, M.; Grenet, G.

1979-07-01

The SU 2 unit tensor operators tsub(k,α) are studied. In the case where the spinor point group G* coincides with U 1 , then tsub(k α) reduces up to a constant to the Wigner-Racah-Schwinger tensor operator tsub(kqα), an operator which produces an angular momentum state. One first investigates those general properties of tsub(kα) which are independent of their realization. The tsub(kα) in terms of two pairs of boson creation and annihilation operators are realized. This leads to look at the Schwinger calculus relative to one angular momentum of two coupled angular momenta. As a by-product, a procedure is given for producing recursion relationships between SU 2 Wigner coefficients. Finally, some of the properties of the Wigner and Racah operators for an arbitrary compact group and the SU 2 coupling coefficients are studied

Illuminating the chirality of Weyl fermions

Science.gov (United States)

Ma, Qiong; Xu, Su-Yang; Chan, Ching-Kit; Zhang, Cheng-Long; Chang, Guoqing; Lin, Hsin; Jia, Shuang; Lee, Patrick; Gedik, Nuh; Jarillo-Herrero, Pablo

In particle physics, Weyl fermions (WF) are elementary particles that travel at the speed of light and have a definite chirality. In condensed matter, it has been recently realized that WFs can arise as magnetic monopoles in the momentum space of a novel topological metal, the Weyl semimetal (WSM). Their chirality, given by the sign of the monopole charge, is the defining property of a WSM, since it directly serves as the topological number and gives rise to exotic properties such as Fermi arcs and the chiral anomaly. Moreover, the two chiralities, analogous to the two valleys in 2D materials, lead to a new degree of freedom in a 3D crystal, suggesting novel pathways to store and carry information. By shining circularly polarized light on the WSM TaAs, we illuminate the chirality of the WFs and achieve an electrical current that is highly controllable based on the WFs' chirality. Our results open up a wide range of new possibilities for experimentally studying and controlling the WFs and their associated quantum anomalies by optical and electrical means, which suggest the exciting prospect of ``Weyltronics''.

Chiral 1,2- and 1,3-diol-functionalized chromophores as Lego building blocks for coupled structures.

Science.gov (United States)

Spange, Stefan; Hofmann, Katja; Walfort, Bernhard; Rüffer, Tobias; Lang, Heinrich

2005-10-14

Chiral nitroanilines containing 1,2- or 1,3-diol functionalities have been synthesized by nucleophilic aromatic substitution of fluoronitroanilines with 1-aminopropane-2,3-diols and 2-aminopropane-1,3-diol in the melt. X-ray structure analyses confirm retention of the configuration of the chiral center. The novel chromophores are suitable to link reversibly to various substituted arylboronic acids which allows the construction of new solvatochromic sensor molecules suitable to response to solvent and anion coordination by fluoride. The solvatochromism of the new compounds has been studied using the Kamlet-Taft LSE relationship.

Some aspects of chirality: Fermion masses and chiral p-forms

Energy Technology Data Exchange (ETDEWEB)

Kleppe, A

1997-05-01

The properties of fermion mass matrices are investigated from different points of view, both within the minimal Standard Model and in extensions of the model. It is shown how mass matrix invariants are used to define the measurables of the quark mixing matrix as invariant functions of the mass matrices. One model is presented where the family pattern is suggested to originate from a kind of mass scaling. A Lagrangian density is defined for an entire charge sector, such that the existence of a Dirac field with mass m{sub 0} implies the existence of other Dirac fields where the corresponding quanta have masses Rm{sub 0}, R{sup 2}m{sub 0}, .. which are obtained by a discrete scale transformation. This suggests a certain type of democratic fermion mass matrices. Also extensions of the minimal Standard Model are investigated, obtained by including right-handed neutrinos in the model. The Standard Model extended by two right-handed neutrinos gives rise to a mass spectrum with two massive and three massless neutrinos. The phenomenological consequences of this model are discussed. The neutrino mass matrix in such a scheme has what is defined as a democratic texture. They are studied for the cases with two and three right-handed neutrinos, resp. The chiral fields that we find in the Standard Model have certain similarities with self-dual fields. Among other things, both chiral and self-dual fields suffer species doubling on the lattice. Chiral p-forms are self-dual fields that appear in twice odd dimensions. Chiral p-forms violate manifest covariance, in the same sense as manifest covariance is violated by non-covariant gauges in electrodynamics. It is shown that a covariant action can nevertheless be formulated for chiral p-forms, by introducing an infinite set of gauge fields in a carefully controlled way.

Some aspects of chirality: Fermion masses and chiral p-forms

International Nuclear Information System (INIS)

Kleppe, A.

1997-05-01

The properties of fermion mass matrices are investigated from different points of view, both within the minimal Standard Model and in extensions of the model. It is shown how mass matrix invariants are used to define the measurables of the quark mixing matrix as invariant functions of the mass matrices. One model is presented where the family pattern is suggested to originate from a kind of mass scaling. A Lagrangian density is defined for an entire charge sector, such that the existence of a Dirac field with mass m 0 implies the existence of other Dirac fields where the corresponding quanta have masses Rm 0 , R 2 m 0 , .. which are obtained by a discrete scale transformation. This suggests a certain type of democratic fermion mass matrices. Also extensions of the minimal Standard Model are investigated, obtained by including right-handed neutrinos in the model. The Standard Model extended by two right-handed neutrinos gives rise to a mass spectrum with two massive and three massless neutrinos. The phenomenological consequences of this model are discussed. The neutrino mass matrix in such a scheme has what is defined as a democratic texture. They are studied for the cases with two and three right-handed neutrinos, resp. The chiral fields that we find in the Standard Model have certain similarities with self-dual fields. Among other things, both chiral and self-dual fields suffer species doubling on the lattice. Chiral p-forms are self-dual fields that appear in twice odd dimensions. Chiral p-forms violate manifest covariance, in the same sense as manifest covariance is violated by non-covariant gauges in electrodynamics. It is shown that a covariant action can nevertheless be formulated for chiral p-forms, by introducing an infinite set of gauge fields in a carefully controlled way

Vector coherent state representations of SO5 contains SU2 + SU2 contains U1 + U1 and SO5 contains U1 + U1

International Nuclear Information System (INIS)

Pan Feng

1991-01-01

VCS representations of SO 5 contains SU 2 + SU 2 contains U 1 + U 1 and SO 5 contains U 1 + U 1 are discussed. Reduced matrix elements for SO 5 contains SU 2 + SU 2 are derived. The multiplicity of a weight for SO 5 is determined by using the K-matrix technique

A separate SU(2) for the third family: Topflavor

International Nuclear Information System (INIS)

Muller, D.J.; Nandi, S.; Univ. of Texas, Austin, TX

1996-01-01

The authors consider the extended electroweak gauge group SU(2) 1 xSU(2) x xU(1) Y where the first and second families of fermions couple to SU(2) 1 while the third family couples to SU(2) 2 . Bounds based on precision electroweak observables and heavy gauge boson searches are placed on the new parameters of the theory. The extra gauge bosons can be as light as about a TeV and can be discovered at future colliders such as the NLC and LHC for a wide range of the parameter space. FCNC interactions are also considered

Synthesis and characterization of mesoporous silica modified with chiral auxiliaries for their potential application as chiral stationary phase.

Science.gov (United States)

Mayani, Vishal J; Abdi, S H R; Kureshy, R I; Khan, N H; Agrawal, Santosh; Jasra, R V

2008-05-16

Novel chiral stationary phase (CSP) based on chiral aminoalcohol immobilized on ordered mesoporous silica SBA-15 1a and standard silica 1b and their copper complexes 1a' and 1b', respectively, was synthesized as potential material for chiral ligand exchange chromatography (CLEC). Microanalysis, inductively coupled plasma spectroscopy (ICP), thermo-gravimetric analysis (TGA), cross polarized magic angle spinning (CP-MAS) (13)C NMR, Powder X-ray diffraction (PXRD), FTIR, N(2) adsorption isotherm, scanning electron microscopy (SEM), transmitted electron microscope (TEM) and solid reflectance UV-vis spectroscopy were used to characterize these materials. All the chiral stationary phases thus synthesized were used for the separation of different racemic compounds such as mandelic acid, 2,2'-dihydroxy-1,1'-binaphthalene BINOL) and diethyl tartrate by simple medium-pressure column chromatography. Successful enantio-separation of racemic mandelic acid was achieved with all the stationary phases but 1a and 1b gave slightly better resolution than their copper complexes 1a' and 1b'. Remarkably these materials are stable under the given experimental conditions and can be used repeatedly for several cycles of enantioresolution. It was observed that the porosity and surface area of the stationary phase play an important role in the chiral separation.

Random SU(2) invariant tensors

Science.gov (United States)

Li, Youning; Han, Muxin; Ruan, Dong; Zeng, Bei

2018-04-01

SU(2) invariant tensors are states in the (local) SU(2) tensor product representation but invariant under the global group action. They are of importance in the study of loop quantum gravity. A random tensor is an ensemble of tensor states. An average over the ensemble is carried out when computing any physical quantities. The random tensor exhibits a phenomenon known as ‘concentration of measure’, which states that for any bipartition the average value of entanglement entropy of its reduced density matrix is asymptotically the maximal possible as the local dimensions go to infinity. We show that this phenomenon is also true when the average is over the SU(2) invariant subspace instead of the entire space for rank-n tensors in general. It is shown in our earlier work Li et al (2017 New J. Phys. 19 063029) that the subleading correction of the entanglement entropy has a mild logarithmic divergence when n  =  4. In this paper, we show that for n  >  4 the subleading correction is not divergent but a finite number. In some special situation, the number could be even smaller than 1/2, which is the subleading correction of random state over the entire Hilbert space of tensors.

Chirality, Metallicity, and Transition Dependent Asymmetries in Resonance Raman Excitation Profiles of Chirality-Enriched Carbon Nanotubes

Science.gov (United States)

Doorn, Stephen; Duque, Juan; Telg, Hagen; Haroz, Erik; Tu, Xiaomin; Zheng, Ming

2014-03-01

Access to carbon nanotube samples enriched in single chiralities allows the observation of new photophysical behaviors obscured or difficult to demonstrate in mixed-chirality ensembles. Recent examples include the observation of strongly asymmetric G-band excitation profiles resulting from non-Condon effects1 and the unambiguous demonstration of Raman interference effects.2 We present here our most recent results demonstrating the generality of the non-Condon behavior to include metallic species (specifically several armchair chiralities). Additionally, the Eii dependence in non-Condon behavior with excitations from E11 thru E44 for both RBM and G modes will be discussed. 1. J.G. Duque, et. al., ACS Nano, 5, 5233 (2011). 2. J.G. Duque, et. al., Phys. Rev. Lett. 108, 117404 (2012).

The interplay of covalency, hydrogen bonding, and dispersion leads to a long range chiral network: The example of 2-butanol

Energy Technology Data Exchange (ETDEWEB)

Liriano, Melissa L.; Lewis, Emily A.; Murphy, Colin J.; Lawton, Timothy J.; Marcinkowski, Matthew D.; Therrien, Andrew J.; Sykes, E. Charles H., E-mail: charles.sykes@tufts.edu [Department of Chemistry, Tufts University, Medford, Massachusetts 02155 (United States); Carrasco, Javier [CIC Energigune, Albert Einstein 48, 01510 Miñano, Álava (Spain); Michaelides, Angelos [Thomas Young Centre, London Centre for Nanotechnology and Department of Physics and Astronomy, University College London, London WC1E 6BT (United Kingdom)

2016-03-07

The assembly of complex structures in nature is driven by an interplay between several intermolecular interactions, from strong covalent bonds to weaker dispersion forces. Understanding and ultimately controlling the self-assembly of materials requires extensive study of how these forces drive local nanoscale interactions and how larger structures evolve. Surface-based self-assembly is particularly amenable to modeling and measuring these interactions in well-defined systems. This study focuses on 2-butanol, the simplest aliphatic chiral alcohol. 2-butanol has recently been shown to have interesting properties as a chiral modifier of surface chemistry; however, its mode of action is not fully understood and a microscopic understanding of the role non-covalent interactions play in its adsorption and assembly on surfaces is lacking. In order to probe its surface properties, we employed high-resolution scanning tunneling microscopy and density functional theory (DFT) simulations. We found a surprisingly rich degree of enantiospecific adsorption, association, chiral cluster growth and ultimately long range, highly ordered chiral templating. Firstly, the chiral molecules acquire a second chiral center when adsorbed to the surface via dative bonding of one of the oxygen atom lone pairs. This interaction is controlled via the molecule’s intrinsic chiral center leading to monomers of like chirality, at both chiral centers, adsorbed on the surface. The monomers then associate into tetramers via a cyclical network of hydrogen bonds with an opposite chirality at the oxygen atom. The evolution of these square units is surprising given that the underlying surface has a hexagonal symmetry. Our DFT calculations, however, reveal that the tetramers are stable entities that are able to associate with each other by weaker van der Waals interactions and tessellate in an extended square network. This network of homochiral square pores grows to cover the whole Au(111) surface. Our

The interplay of covalency, hydrogen bonding, and dispersion leads to a long range chiral network: The example of 2-butanol

International Nuclear Information System (INIS)

Liriano, Melissa L.; Lewis, Emily A.; Murphy, Colin J.; Lawton, Timothy J.; Marcinkowski, Matthew D.; Therrien, Andrew J.; Sykes, E. Charles H.; Carrasco, Javier; Michaelides, Angelos

2016-01-01

The assembly of complex structures in nature is driven by an interplay between several intermolecular interactions, from strong covalent bonds to weaker dispersion forces. Understanding and ultimately controlling the self-assembly of materials requires extensive study of how these forces drive local nanoscale interactions and how larger structures evolve. Surface-based self-assembly is particularly amenable to modeling and measuring these interactions in well-defined systems. This study focuses on 2-butanol, the simplest aliphatic chiral alcohol. 2-butanol has recently been shown to have interesting properties as a chiral modifier of surface chemistry; however, its mode of action is not fully understood and a microscopic understanding of the role non-covalent interactions play in its adsorption and assembly on surfaces is lacking. In order to probe its surface properties, we employed high-resolution scanning tunneling microscopy and density functional theory (DFT) simulations. We found a surprisingly rich degree of enantiospecific adsorption, association, chiral cluster growth and ultimately long range, highly ordered chiral templating. Firstly, the chiral molecules acquire a second chiral center when adsorbed to the surface via dative bonding of one of the oxygen atom lone pairs. This interaction is controlled via the molecule’s intrinsic chiral center leading to monomers of like chirality, at both chiral centers, adsorbed on the surface. The monomers then associate into tetramers via a cyclical network of hydrogen bonds with an opposite chirality at the oxygen atom. The evolution of these square units is surprising given that the underlying surface has a hexagonal symmetry. Our DFT calculations, however, reveal that the tetramers are stable entities that are able to associate with each other by weaker van der Waals interactions and tessellate in an extended square network. This network of homochiral square pores grows to cover the whole Au(111) surface. Our

How supersymmetry naturally suppresses Higgs-boson-mediated baryon-number violation in SU/sub c/(4) x SU/sub L/(2) x SU/sub R/(2) and SO(10)

International Nuclear Information System (INIS)

Gipson, J.M.; Marshak, R.E.

1984-01-01

The supersymmetric versions of the left-right-symmetric SU/sub C/(4) x SU/sub L/(2) x SU/sub R/(2) Pati-Salam theory and the grand unified SO(10) theory are studied. In the minimal versions of these models the requirement of soft or spontaneous breaking of supersymmetry, together with renormalizibility, leads to an accidental global U(1) symmetry which leads to baryon-number conservation. A necessary condition for this symmetry to be broken is the existence of fields which are antisymmetric in at least two SU/sub C/(4) indices. The introduction of such fields may allow for observable neutron oscillation

Asymmetric Synthesis via Chiral Aziridines

DEFF Research Database (Denmark)

Tanner, David Ackland; Harden, Adrian; Wyatt, Paul

1996-01-01

A series of chiral bis(aziridines) has been synthesised and evaluated as chelating ligands for a variety of asymmetric transformations mediated by metals [Os (dihydroxylation), Pd (allylic alkylation) Cu (cyclopropanation and aziridination, Li (1,2-addition of organolithiums to imines)]. In the b......A series of chiral bis(aziridines) has been synthesised and evaluated as chelating ligands for a variety of asymmetric transformations mediated by metals [Os (dihydroxylation), Pd (allylic alkylation) Cu (cyclopropanation and aziridination, Li (1,2-addition of organolithiums to imines...

Precision electroweak tests of the minimal and flipped SU(5) supergravity models

Energy Technology Data Exchange (ETDEWEB)

Lopez, J.L.; Nanopoulos, D.V.; Park, G.T.; Pois, H.; Yuan, K. (Center for Theoretical Physics, Department of Physics, Texas A M University, College Station, Texas 77843-4242 (United States) Astroparticle Physics Group, Houston Advanced Research Center (HARC), The Woodlands, Texas 77381 (United States))

1993-10-01

We explore the one-loop electroweak radiative corrections in the minimal SU(5) and the no-scale flipped SU(5) supergravity models via explicit calculation of vacuum polarization contributions to the [epsilon][sub 1,2,3] parameters. Experimentally, [epsilon][sub 1,2,3] are obtained from a global fit to the CERN LEP observables, and [ital M][sub [ital W

Chiral 2π exchange at fourth order and peripheral NN scattering

International Nuclear Information System (INIS)

Entem, D.R.; Machleidt, R.

2002-01-01

We calculate the impact of the complete set of two-pion exchange contributions at chiral fourth order (also known as next-to-next-to-next-to-leading order) on peripheral partial waves of nucleon-nucleon scattering. Our calculations are based upon the analytical studies by Kaiser. It turns out that the contribution of fourth order is substantially smaller than the one of third order, indicating convergence of the chiral expansion. We compare the prediction from chiral pion exchange with the corresponding one from conventional meson theory as represented by the Bonn full model and find, in general, good agreement. Our calculations provide a sound basis for investigating the issue whether the low-energy constants determined from πN lead to reasonable predictions for NN

Intrinsic Chirality and Prochirality at Air/R-(+)- and S-(-)-Limonene Interfaces: Spectral Signatures with Interference Chiral Sum-Frequency Generation Vibrational Spectroscopy

Energy Technology Data Exchange (ETDEWEB)

Fu, Li; Zhang, Yun; Wei, Zhehao; Wang, Hongfei

2014-06-04

We report in this work detailed measurements on the chiral and achiral sum-frequency vibrational spectra in the C-H stretching vibration region (2800-3050cm-1) of the air/liquid interfaces of R-limonene and S-limonene, using the recently developed high-resolution broadband sum-frequency generation vibrational spectroscopy (HR-BB-SFG-VS). The achiral SFG spectra of R-limonene and S-limonene, as well as the equal amount (50/50) racemic mixture show that the enantiomers are with the same interfacial orientations. The interference chiral SFG spectra of the limonene enantiomers exhibit spectral signature from chiral response of the Cα-H stretching mode, and spectral signature from prochiral response of the CH2 asymmetric stretching mode, respectively. The chiral spectral feature of the Cα-H stretching mode changes sign from R-limonene to S-limonene, and disappears for the 50/50 racemic mixture. While the prochiral spectral feature of the CH2 asymmetric stretching mode is the same for R-limonene and S-limonene, and also surprisingly remains the same for the 50/50 racemic mixture. These results provided detail information in understanding the structure and chirality of molecular interfaces, and demonstrated the sensitivity and potential of SFG-VS as unique spectroscopic tool for chirality characterization and chiral recognition at the molecular interface.

Measurement of chirality of charge-density-waves in TiSe2 by using STM

International Nuclear Information System (INIS)

Ishioka, J.; Liu, Y.H.; Shimatake, K.; Kurosawa, T.; Ichimura, K.; Toda, Y.; Oda, M.; Tanda, S.

2010-01-01

We report the chirality of charge density waves (CDW) in 1T-TiSe 2 by using scanning tunneling microscopy (STM) measurements. We found that the CDW intensity becomes Ia 1 :Ia 2 :Ia 3 =1:0.7±0.1:0.5±0.1, where Ia i (i=1, 2, 3) is the amplitude of the tunneling current contributed by the CDWs. We found two states, in which the three intensity peaks of the CDW decrease clockwise and anticlockwise when we index each nesting vector in order of intensity in the Fourier transformation of the STM images. We found that this difference arises from CDW stacking along the c-axis at intervals of 2c 0 /3. This chirality is attributed to the helical stacking such as cholesteric liquid crystals.

SU(2) with fundamental fermions and scalars

Science.gov (United States)

Hansen, Martin; Janowski, Tadeusz; Pica, Claudio; Toniato, Arianna

2018-03-01

We present preliminary results on the lattice simulation of an SU(2) gauge theory with two fermion flavors and one strongly interacting scalar field, all in the fundamental representation of SU(2). The motivation for this study comes from the recent proposal of "fundamental" partial compositeness models featuring strongly interacting scalar fields in addition to fermions. Here we describe the lattice setup for our study of this class of models and a first exploration of the lattice phase diagram. In particular we then investigate how the presence of a strongly coupled scalar field affects the properties of light meson resonances previously obtained for the SU(2) model. Preprint: CP3-Origins-2017-047 DNRF90

Chirality of magneto-electrodeposited metal film electrodes

International Nuclear Information System (INIS)

Mogi, Iwao; Watanabe, Kazuo

2008-01-01

The chiral electrode behaviors of magneto-electrodeposited (MED) Ag and Cu films were examined for the electrochemical reactions of D-glucose, L-glucose and L-cysteine. The Ag and Cu films were electrodeposited under a magnetic field of 2 T parallel (+2 T) or antiparallel (-2 T) to the faradaic current. For MED films of both Ag and Cu, the oxidation current of L-glucose was larger than that of D-glucose on the +2 T-film electrodes, and the results were opposite on the - 2 T-film electrodes. These facts demonstrate that the MED metal films possess the ability of chiral recognition for D- and L-glucoses. The MED Ag film electrodes also exhibited chiral behavior for the oxidation of L-cysteine

Chirality in adsorption on solid surfaces.

Science.gov (United States)

Zaera, Francisco

2017-12-07

In the present review we survey the main advances made in recent years on the understanding of chemical chirality at solid surfaces. Chirality is an important topic, made particularly relevant by the homochiral nature of the biochemistry of life on Earth, and many chiral chemical reactions involve solid surfaces. Here we start our discussion with a description of surface chirality and of the different ways that chirality can be bestowed on solid surfaces. We then expand on the studies carried out to date to understand the adsorption of chiral compounds at a molecular level. We summarize the work published on the adsorption of pure enantiomers, of enantiomeric mixtures, and of prochiral molecules on chiral and achiral model surfaces, especially on well-defined metal single crystals but also on other flat substrates such as highly ordered pyrolytic graphite. Several phenomena are identified, including surface reconstruction and chiral imprinting upon adsorption of chiral agents, and the enhancement or suppression of enantioselectivity seen in some cases upon adsorption of enantiomixtures of chiral compounds. The possibility of enhancing the enantiopurity of adsorbed layers upon the addition of chiral seeds and the so-called "sergeants and soldiers" phenomenon are presented. Examples are provided where the chiral behavior has been associated with either thermodynamic or kinetic driving forces. Two main approaches to the creation of enantioselective surface sites are discussed, namely, via the formation of supramolecular chiral ensembles made out of small chiral adsorbates, and by adsorption of more complex chiral molecules capable of providing suitable chiral environments for reactants by themselves, via the formation of individual adsorbate:modifier adducts on the surface. Finally, a discussion is offered on the additional effects generated by the presence of the liquid phase often required in practical applications such as enantioselective crystallization, chiral

Quantum SU(2|1) supersymmetric Calogero-Moser spinning systems

Science.gov (United States)

Fedoruk, Sergey; Ivanov, Evgeny; Lechtenfeld, Olaf; Sidorov, Stepan

2018-04-01

SU(2|1) supersymmetric multi-particle quantum mechanics with additional semi-dynamical spin degrees of freedom is considered. In particular, we provide an N=4 supersymmetrization of the quantum U(2) spin Calogero-Moser model, with an intrinsic mass parameter coming from the centrally-extended superalgebra \\widehat{su}(2\\Big|1) . The full system admits an SU(2|1) covariant separation into the center-of-mass sector and the quotient. We derive explicit expressions for the classical and quantum SU(2|1) generators in both sectors as well as for the total system, and we determine the relevant energy spectra, degeneracies, and the sets of physical states.

The chiral bosonization in non-Abelian gauge theories

International Nuclear Information System (INIS)

Andrianov, A.A.; Novozhilov, Y.

1985-01-01

The chiral bosonization in non-Abelian gauge theories is described starting directly from the QCD functional. For a given mass scale Λ, the QCD may be equivalently represented by colour chiral fields, gauge fields and high energy fermions. The effective action for colour chiral fields may admit the existence of a colour Skyrmion-boson with the baryon number 2/3. (author)

C2-symmetric bisamidines: Chiral Brønsted bases catalysing the Diels-Alder reaction of anthrones

Directory of Open Access Journals (Sweden)

2008-08-01

Full Text Available C2-symmetric bisamidines 8 have been tested as chiral Brønsted bases in the Diels-Alder reaction of anthrones and N-substituted maleimides. High yields of cycloadducts and significant asymmetric inductions up to 76% ee are accessible. The proposed mechanism involves proton transfer between anthrone and bisamidine, association of the resulting ions and finally a cycloaddition step stereoselectively controlled by the chiral ion pair.

NMR-based Enantiodifferentiation of Chiral trans-2-Phenylcyclopropane Derivatives Using a Chiral Lanthanide Shift Reagent

International Nuclear Information System (INIS)

Cho, Nam Sook; Kim, Hyun Sook; Song, Mi Sook

2011-01-01

In contrast with optical methods, there is no need to characterize the pure enantiomers. Instead, the NMR method makes use of chiral reagents that convert a mixture of enantiomers into a mixture of diastereomeric complexes. Integration of the resulting NMR spectra yields a direct measurement of enantiomeric purity as long as there is a sufficiently large difference between the chemical shifts of the two diastereoisomeric complexes to produce baseline-resolved peaks. Absolute enantiomeric configurations can also be determined using this method. Chiral lanthanide shift reagents have been used since the 1970s to form addition complexes with various compounds through interactions with electron donor sites. Lanthanide-induced, pseudo-contact shifts (LIS) are a function of the distance, r, between the nuclei under observation and the lanthanide center, and the angle, θ, between the line connecting the metal ion with the observed nucleus and the line representing the CLSR magnetic axis

Chirality in molecular collision dynamics

Science.gov (United States)

Lombardi, Andrea; Palazzetti, Federico

2018-02-01

Chirality is a phenomenon that permeates the natural world, with implications for atomic and molecular physics, for fundamental forces and for the mechanisms at the origin of the early evolution of life and biomolecular homochirality. The manifestations of chirality in chemistry and biochemistry are numerous, the striking ones being chiral recognition and asymmetric synthesis with important applications in molecular sciences and in industrial and pharmaceutical chemistry. Chiral discrimination phenomena, due to the existence of two enantiomeric forms, very well known in the case of interaction with light, but still nearly disregarded in molecular collision studies. Here we review some ideas and recent advances about the role of chirality in molecular collisions, designing and illustrating molecular beam experiments for the demonstration of chiral effects and suggesting a scenario for a stereo-directional origin of chiral selection.

The chirality operators for Heisenberg spin systems

International Nuclear Information System (INIS)

Subrahmanyam, V.

1994-01-01

The ground state of closed Heisenberg spin chains with an odd number of sites has a chiral degeneracy, in addition to a two-fold Kramers degeneracy. A non-zero chirality implies that the spins are not coplanar, and is a measure of handedness. The chirality operator, which can be treated as a spin-1/2 operator, is explicitly constructed in terms of the spin operators, and is given as commutator of permutation operators. (author). 3 refs

Fluxionally chiral DMAP catalysts: kinetic resolution of axially chiral biaryl compounds.

Science.gov (United States)

Ma, Gaoyuan; Deng, Jun; Sibi, Mukund P

2014-10-27

Can organocatalysts that incorporate fluxional groups provide enhanced selectivity in asymmetric transformations? To address this issue, we have designed chiral 4-dimethylaminopyridine (DMAP) catalysts with fluxional chirality. These catalysts were found to be efficient in promoting the acylative kinetic resolution of secondary alcohols and axially chiral biaryl compounds with selectivity factors of up to 37 and 51, respectively. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Effective SU(2) theory for the pseudogap state

Science.gov (United States)

Montiel, X.; Kloss, T.; Pépin, C.

2017-03-01

This paper exposes in a detailed manner the recent findings about the SU(2) scenario for the underdoped phase of the cuprate superconductors. The SU(2) symmetry is formulated as a rotation between the d -wave superconducting (SC) phase and a d -wave charge order. We define the operators responsible for the SU(2) rotations and we derive the nonlinear σ model associated with it. In this framework, we demonstrate that SU(2) fluctuations are massless in finite portions of the Brillouin zone corresponding to the antinodal regions (0 ,π ) and (π ,0 ). We argue that the presence of SU(2) fluctuations in the antinodal region leads to the opening of Fermi arcs around the Fermi surface and to the formation of the pseudogap. Moreover, we show that SU(2) fluctuations lead, in turn, to the emergence of a finite momentum SC order—or pair density wave (PDW)—and more importantly to a new kind of excitonic particle-hole pairs liquid, the resonant excitonic state (RES), which is made of patches of preformed particle-hole pairs with multiple momenta. When the RES liquid becomes critical, we demonstrate that electronic scattering through the critical modes leads to anomalous transport properties. This new finding can account for the strange metal (SM) phase at finite temperature, on the right-hand side of the SC dome, shedding light on another notoriously mysterious part of the phase diagram of the cuprates.

Chiral pyrrolidinium salts derived from menthol as precursor – synthesis and properties

Directory of Open Access Journals (Sweden)

Janus Ewa

2017-09-01

Full Text Available Six new chiral pyrolidinium salts with chiral substituent at quaternary nitrogen atom were synthesized with high overall yields from (--menthol as cheap chiral precursor and were identified by NMR and HRMS spectroscopy. It was shown that anion type had the effect on chemical shift of protons adjacent to quaternary nitrogen atom and physical properties of these salts. Salts with NTf2 or NPf2 were in a liquid state at room temperature and characterized with the highest thermal stability among others. Furthermore, chiral ionic liquid with NTf2 anion was used as solvent in Diels-Alder reaction and gave higher yield and stereoselectivity than in ionic liquids with achiral cations. Synthesized chiral salts have the potential as chiral solvents in synthesis and auxiliaries in analytical methods to improve chiral recognition.

Laminar and Turbulent Dynamos in Chiral Magnetohydrodynamics. II. Simulations

Science.gov (United States)

Schober, Jennifer; Rogachevskii, Igor; Brandenburg, Axel; Boyarsky, Alexey; Fröhlich, Jürg; Ruchayskiy, Oleg; Kleeorin, Nathan

2018-05-01

Using direct numerical simulations (DNS), we study laminar and turbulent dynamos in chiral magnetohydrodynamics with an extended set of equations that accounts for an additional contribution to the electric current due to the chiral magnetic effect (CME). This quantum phenomenon originates from an asymmetry between left- and right-handed relativistic fermions in the presence of a magnetic field and gives rise to a chiral dynamo. We show that the magnetic field evolution proceeds in three stages: (1) a small-scale chiral dynamo instability, (2) production of chiral magnetically driven turbulence and excitation of a large-scale dynamo instability due to a new chiral effect (α μ effect), and (3) saturation of magnetic helicity and magnetic field growth controlled by a conservation law for the total chirality. The α μ effect becomes dominant at large fluid and magnetic Reynolds numbers and is not related to kinetic helicity. The growth rate of the large-scale magnetic field and its characteristic scale measured in the numerical simulations agree well with theoretical predictions based on mean-field theory. The previously discussed two-stage chiral magnetic scenario did not include stage (2), during which the characteristic scale of magnetic field variations can increase by many orders of magnitude. Based on the findings from numerical simulations, the relevance of the CME and the chiral effects revealed in the relativistic plasma of the early universe and of proto-neutron stars are discussed.

Photoexcitation circular dichroism in chiral molecules

Science.gov (United States)

Beaulieu, S.; Comby, A.; Descamps, D.; Fabre, B.; Garcia, G. A.; Géneaux, R.; Harvey, A. G.; Légaré, F.; Mašín, Z.; Nahon, L.; Ordonez, A. F.; Petit, S.; Pons, B.; Mairesse, Y.; Smirnova, O.; Blanchet, V.

2018-05-01

Chiral effects appear in a wide variety of natural phenomena and are of fundamental importance in science, from particle physics to metamaterials. The standard technique of chiral discrimination—photoabsorption circular dichroism—relies on the magnetic properties of a chiral medium and yields an extremely weak chiral response. Here, we propose and demonstrate an orders of magnitude more sensitive type of circular dichroism in neutral molecules: photoexcitation circular dichroism. This technique does not rely on weak magnetic effects, but takes advantage of the coherent helical motion of bound electrons excited by ultrashort circularly polarized light. It results in an ultrafast chiral response and the efficient excitation of a macroscopic chiral density in an initially isotropic ensemble of randomly oriented chiral molecules. We probe this excitation using linearly polarized laser pulses, without the aid of further chiral interactions. Our time-resolved study of vibronic chiral dynamics opens a way to the efficient initiation, control and monitoring of chiral chemical change in neutral molecules at the level of electrons.

Inversion of Supramolecular Chirality by Sonication-Induced Organogelation

Science.gov (United States)

Maity, Sibaprasad; Das, Priyadip; Reches, Meital

2015-01-01

Natural helical structures have inspired the formation of well-ordered peptide-based chiral nanostructures in vitro. These structures have drawn much attention owing to their diverse applications in the area of asymmetric catalysts, chiral photonic materials, and nanoplasmonics. The self-assembly of two enantiomeric fluorinated aromatic dipeptides into ordered chiral fibrillar nanostructures upon sonication is described. These fibrils form organogels. Our results clearly indicate that fluorine-fluorine interactions play an important role in self-assembly. Circular dichroism analysis revealed that both peptides (peptides 1 and 2), containing two fluorines, depicted opposite cotton effects in their monomeric form compared with their aggregated form. This shows that supramolecular chirality inversion took place during the stimuli-responsive self-aggregation process. Conversely, peptide 3, containing one fluorine, did not exhibit chirality inversion in sonication-induced organogelation. Therefore, our results clearly indicate that fluorination plays an important role in the organogelation process of these aromatic dipeptides. Our findings may have broad implications regarding the design of chiral nanostructures for possible applications such as chiroptical switches, asymmetric catalysis, and chiral recognitions. PMID:26553508

Observation of chiral phonons

KAUST Repository

Zhu, Hanyu; Yi, Jun; Li, Ming-yang; Xiao, Jun; Zhang, Lifa; Yang, Chih-Wen; Kaindl, Robert A.; Li, Lain-Jong; Wang, Yuan; Zhang, Xiang

2018-01-01

Chirality reveals symmetry breaking of the fundamental interaction of elementary particles. In condensed matter, for example, the chirality of electrons governs many unconventional transport phenomena such as the quantum Hall effect. Here we show that phonons can exhibit intrinsic chirality in monolayer tungsten diselenide. The broken inversion symmetry of the lattice lifts the degeneracy of clockwise and counterclockwise phonon modes at the corners of the Brillouin zone. We identified the phonons by the intervalley transfer of holes through hole-phonon interactions during the indirect infrared absorption, and we confirmed their chirality by the infrared circular dichroism arising from pseudoangular momentum conservation. The chiral phonons are important for electron-phonon coupling in solids, phonon-driven topological states, and energy-efficient information processing.

Observation of chiral phonons

KAUST Repository

Zhu, Hanyu

2018-02-01

Chirality reveals symmetry breaking of the fundamental interaction of elementary particles. In condensed matter, for example, the chirality of electrons governs many unconventional transport phenomena such as the quantum Hall effect. Here we show that phonons can exhibit intrinsic chirality in monolayer tungsten diselenide. The broken inversion symmetry of the lattice lifts the degeneracy of clockwise and counterclockwise phonon modes at the corners of the Brillouin zone. We identified the phonons by the intervalley transfer of holes through hole-phonon interactions during the indirect infrared absorption, and we confirmed their chirality by the infrared circular dichroism arising from pseudoangular momentum conservation. The chiral phonons are important for electron-phonon coupling in solids, phonon-driven topological states, and energy-efficient information processing.

Chiral algebras in Landau-Ginzburg models

Science.gov (United States)

Dedushenko, Mykola

2018-03-01

Chiral algebras in the cohomology of the {\\overline{Q}}+ supercharge of two-dimensional N=(0,2) theories on flat spacetime are discussed. Using the supercurrent multiplet, we show that the answer is renormalization group invariant for theories with an R-symmetry. For N=(0,2) Landau-Ginzburg models, the chiral algebra is determined by the operator equations of motion, which preserve their classical form, and quantum renormalization of composite operators. We study these theories and then specialize to the N=(2,2) models and consider some examples.

Chirality in microbial biofilms is mediated by close interactions between the cell surface and the substratum

Science.gov (United States)

Jauffred, Liselotte; Munk Vejborg, Rebecca; Korolev, Kirill S; Brown, Stanley; Oddershede, Lene B

2017-01-01

From microbial biofilms to human migrations, spatial competition is central to the evolutionary history of many species. The boundary between expanding populations is the focal point of competition for space and resources and is of particular interest in ecology. For all Escherichia coli strains studied here, these boundaries move in a counterclockwise direction even when the competing strains have the same fitness. We find that chiral growth of bacterial colonies is strongly suppressed by the expression of extracellular features such as adhesive structures and pili. Experiments with other microbial species show that chiral growth is found in other bacteria and exclude cell wall biosynthesis and anisotropic shape as the primary causes of chirality. Instead, intimate contact with the substratum is necessary for chirality. Our results demonstrate that through a handful of surface molecules cells can fundamentally reorganize their migration patterns, which might affect intra- and interspecific competitions through colony morphology or other mechanisms. PMID:28362723

Fusion rules of chiral algebras

International Nuclear Information System (INIS)

Gaberdiel, M.

1994-01-01

Recently we showed that for the case of the WZW and the minimal models fusion can be understood as a certain ring-like tensor product of the symmetry algebra. In this paper we generalize this analysis to arbitrary chiral algebras. We define the tensor product of conformal field theory in the general case and prove that it is associative and symmetric up to equivalence. We also determine explicitly the action of the chiral algebra on this tensor product. In the second part of the paper we demonstrate that this framework provides a powerful tool for calculating restrictions for the fusion rules of chiral algebras. We exhibit this for the case of the W 3 algebra and the N=1 and N=2 NS superconformal algebras. (orig.)

Quenched QED in the chiral limit

International Nuclear Information System (INIS)

Vandermark, S.W.

1993-01-01

The main goal in this project has been to understand, through analytical methods, whether there could be a continuum limit for QED. This possibility is motivated by recent lattice simulations on quenched QED which apparently exhibit a chiral phase transition at strong coupling in the chiral limit. Another goal is to develop a novel perturbation expansion which may also be usefully applied to other theories. The author begins with the general expression for the chiral order parameter, (bar ψψ), in the quenched limit of euclidean QED, where the number of fermion flavors goes to zero, using the path integral formulation. A cutoff scale, Λ, is introduced into the photon propagator and a new expansion, the open-quotes wormhole expansion,close quotes in powers of Λ 2 /m 2 , where m is the fermion mass, is derived. Graphical rules for the wormhole expansion of left-angle bar ψψ right-angle are described in detail. The author then devises algorithms to generate recursively the graphs at each successive order and to perform the loop momentum integral and γ matrix trace involved in the evaluation of each graph. These algorithms are implemented in Mathmatica and the left-angle bar ψψ right-angle expansion is carried out to order (Λ 2 / m 2 ) 6 . The author employs pade techniques to extrapolate this expansion to the chiral limit (Λ 2 /m 2 → ∞) and looks for a singularity at strong coupling to signal a phase transition. Indications have been found that there may be a phase transition but apparently there are not enough terms in the wormhole expansion to attain stability in our pade analysis. The author therefore cannot conclude that there is a chiral phase transition, although the results are consistent with the existence of one

Alternative Experimental Evidence for Chiral Restoration in Excited Baryons

International Nuclear Information System (INIS)

Glozman, L. Ya.

2007-01-01

It has been suggested that chiral symmetry is approximately restored in excited hadrons at zero temperature and density (effective symmetry restoration). Using very general chiral symmetry arguments, it is shown that those excited nucleons that are assumed from the spectroscopic patterns to be in approximate chiral multiplets must only weakly decay into the Nπ channel (f N*Nπ /f NNπ ) 2 NNπ . It turns out that for all those well-established excited nucleons which can be classified into chiral doublets the ratio is (f N*Nπ /f NNπ ) 2 ∼0.1 or much smaller for the high-spin states. In contrast, the only well-established excited nucleon for which the chiral partner cannot be identified from the spectroscopic data, N(1520), has a decay constant into the Nπ channel that is comparable with f NNπ

Identifying chiral bands in real nuclei

International Nuclear Information System (INIS)

Shirinda, O.; Lawrie, E.A.

2012-01-01

The application of the presently used fingerprints of chiral bands (originally derived for strongly broken chirality) is investigated for real chiral systems. In particular the chiral fingerprints concerning the B(M1) staggering patterns and the energy staggering are studied. It is found that both fingerprints show considerable changes for real chiral systems, a behaviour that creates a significant risk for misinterpretation of the experimental data and can lead to a failure to identify real chiral systems. (orig.)

Model with a gauged lepton flavor SU(2) symmetry

Science.gov (United States)

Chiang, Cheng-Wei; Tsumura, Koji

2018-05-01

We propose a model having a gauged SU(2) symmetry associated with the second and third generations of leptons, dubbed SU(2) μτ , of which U{(1)}_{L_{μ }-L_{τ }} is an Abelian subgroup. In addition to the Standard Model fields, we introduce two types of scalar fields. One exotic scalar field is an SU(2) μτ doublet and SM singlet that develops a nonzero vacuum expectation value at presumably multi-TeV scale to completely break the SU(2) μτ symmetry, rendering three massive gauge bosons. At the same time, the other exotic scalar field, carrying electroweak as well as SU(2) μτ charges, is induced to have a nonzero vacuum expectation value as well and breaks mass degeneracy between the muon and tau. We examine how the new particles in the model contribute to the muon anomalous magnetic moment in the parameter space compliant with the Michel decays of tau.

Chirality-controlled crystallization via screw dislocations.

Science.gov (United States)

Sung, Baeckkyoung; de la Cotte, Alexis; Grelet, Eric

2018-04-11

Chirality plays an important role in science from enantiomeric separation in chemistry to chiral plasmonics in nanotechnology. However, the understanding of chirality amplification from chiral building blocks to ordered helical superstructures remains a challenge. Here, we demonstrate that topological defects, such as screw dislocations, can drive the chirality transfer from particle to supramolecular structure level during the crystallization process. By using a model system of chiral particles, which enables direct imaging of single particle incorporation into growing crystals, we show that the crystallization kinetic pathway is the key parameter for monitoring, via the defects, the chirality amplification of the crystalline structures from racemic to predominantly homohelical. We provide an explanation based on the interplay between geometrical frustration, racemization induced by thermal fluctuations, and particle chirality. Our results demonstrate that screw dislocations not only promote the growth, but also control the chiral morphology and therefore the functionality of crystalline states.

Argyres-Douglas theories, chiral algebras and wild Hitchin characters

Science.gov (United States)

Fredrickson, Laura; Pei, Du; Yan, Wenbin; Ye, Ke

2018-01-01

We use Coulomb branch indices of Argyres-Douglas theories on S 1 × L( k, 1) to quantize moduli spaces M_H of wild/irregular Hitchin systems. In particular, we obtain formulae for the "wild Hitchin characters" — the graded dimensions of the Hilbert spaces from quantization — for four infinite families of M_H , giving access to many interesting geometric and topological data of these moduli spaces. We observe that the wild Hitchin characters can always be written as a sum over fixed points in M_H under the U(1) Hitchin action, and a limit of them can be identified with matrix elements of the modular transform ST k S in certain two-dimensional chiral algebras. Although naturally fitting into the geometric Langlands program, the appearance of chiral algebras, which was known previously to be associated with Schur operators but not Coulomb branch operators, is somewhat surprising.

Spin Chirality of Cu3 and V3 Nanomagnets. 1. Rotation Behavior of Vector Chirality, Scalar Chirality, and Magnetization in the Rotating Magnetic Field, Magnetochiral Correlations.

Science.gov (United States)

Belinsky, Moisey I

2016-05-02

The rotation behavior of the vector chirality κ, scalar chirality χ, and magnetization M in the rotating magnetic field H1 is considered for the V3 and Cu3 nanomagnets, in which the Dzialoshinsky-Moriya coupling is active. The polar rotation of the field H1 of the given strength H1 results in the energy spectrum characterized by different vector and scalar chiralities in the ground and excited states. The magnetochiral correlations between the vector and scalar chiralities, energy, and magnetization in the rotating field were considered. Under the uniform polar rotation of the field H1, the ground-state chirality vector κI performs sawtooth oscillations and the magnetization vector MI performs the sawtooth oscillating rotation that is accompanied by the correlated transformation of the scalar chirality χI. This demonstrates the magnetochiral effect of the joint rotation behavior and simultaneous frustrations of the spin chiralities and magnetization in the rotating field, which are governed by the correlation between the chiralities and magnetization.

First-order chiral to non-chiral transition in the angular dependence of the upper critical induction of the Scharnberg–Klemm p-wave pair state

International Nuclear Information System (INIS)

Zhang, J; Gu, Q; Lörscher, C; Klemm, R A

2014-01-01

We calculate the temperature T and angular (θ, ϕ) dependencies of the upper critical induction B c2 (θ, ϕ, T) for parallel-spin superconductors with an axially symmetric p-wave pairing interaction pinned to the lattice and a dominant ellipsoidal Fermi surface (FS). For all FS anisotropies, the chiral Scharnberg–Klemm (SK) state B c2 (θ, ϕ, T) exceeds that of the chiral Anderson–Brinkman–Morel (ABM) state and exhibits a kink at θ = θ * (T, ϕ), indicative of a first-order transition from its chiral, nodal-direction behavior to its non-chiral, antinodal-direction behavior. Applicabilities to Sr 2 RuO 4 , UCoGe and the candidate topological superconductor Cu x Bi 2 Se 3 are discussed. (fast track communication)

Chirality and chiroptical properties of amyloid fibrils.

Science.gov (United States)

Dzwolak, Wojciech

2014-09-01

Chirality of amyloid fibrils-linear beta-sheet-rich aggregates of misfolded protein chains-often manifests in morphological traits such as helical twist visible in atomic force microscopy and in chiroptical properties accessible to vibrational circular dichroism (VCD). According to recent studies the relationship between molecular chirality of polypeptide building blocks and superstructural chirality of amyloid fibrils may be more intricate and less deterministic than previously assumed. Several puzzling experimental findings have put into question earlier intuitive ideas on: 1) the bottom-up chirality transfer upon amyloidogenic self-assembly, and 2) the structural origins of chiroptical properties of protein aggregates. For example, removal of a single amino acid residue from an amyloidogenic all-L peptide was shown to reverse handedness of fibrils. On the other hand, certain types of amyloid aggregates revealed surprisingly strong VCD spectra with the sign and shape dependent on the conditions of fibrillation. Hence, microscopic and chiroptical studies have highlighted chirality as one more aspect of polymorphism of amyloid fibrils. This brief review is intended to outline the current state of research on amyloid-like fibrils from the perspective of their structural and superstructural chirality and chiroptical properties. © 2014 Wiley Periodicals, Inc.

Introduction to Chiral Symmetry

Energy Technology Data Exchange (ETDEWEB)

Koch, Volker [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

2017-05-09

These lectures are an attempt to a pedagogical introduction into the elementary concepts of chiral symmetry in nuclear physics. We will also discuss some effective chiral models such as the linear and nonlinear sigma model as well as the essential ideas of chiral perturbation theory. We will present some applications to the physics of ultrarelativistic heavy ion collisionsd.

Introduction to chiral symmetry

International Nuclear Information System (INIS)

Koch, V.

1996-01-01

These lectures are an attempt to a pedagogical introduction into the elementary concepts of chiral symmetry in nuclear physics. Effective chiral models such as the linear and nonlinear sigma model will be discussed as well as the essential ideas of chiral perturbation theory. Some applications to the physics of ultrarelativistic heavy ion collisions will be presented

The paradigm of Pseudodual Chiral Models

International Nuclear Information System (INIS)

Zachos, C.K.; Curtright, T.L.

1994-01-01

This is a synopsis and extension of Phys. Rev. D49 5408 (1994). The Pseudodual Chiral Model illustrates 2-dimensional field theories which possess an infinite number of conservation laws but also allow particle production, at variance with naive expectations-a folk theorem of integrable models. We monitor the symmetries of the pseudodual model, both local and nonlocal, as transmutations of the symmetries of the (very different) usual Chiral Model. We refine the conventional algorithm to more efficiently produce the nonlocal symmetries of the model. We further find the canonical transformation which connects the usual chiral model to its fully equivalent dual model, thus contradistinguishing the pseudodual theory

Geometrical meaning of winding number and its characterization of topological phases in one-dimensional chiral non-Hermitian systems

Science.gov (United States)

Yin, Chuanhao; Jiang, Hui; Li, Linhu; Lü, Rong; Chen, Shu

2018-05-01

We unveil the geometrical meaning of winding number and utilize it to characterize the topological phases in one-dimensional chiral non-Hermitian systems. While chiral symmetry ensures the winding number of Hermitian systems are integers, it can take half integers for non-Hermitian systems. We give a geometrical interpretation of the half integers by demonstrating that the winding number ν of a non-Hermitian system is equal to half of the summation of two winding numbers ν1 and ν2 associated with two exceptional points, respectively. The winding numbers ν1 and ν2 represent the times of the real part of the Hamiltonian in momentum space encircling the exceptional points and can only take integers. We further find that the difference of ν1 and ν2 is related to the second winding number or energy vorticity. By applying our scheme to a non-Hermitian Su-Schrieffer-Heeger model and an extended version of it, we show that the topologically different phases can be well characterized by winding numbers. Furthermore, we demonstrate that the existence of left and right zero-mode edge states is closely related to the winding number ν1 and ν2.

SU(2) X SU(2) X U(1) basis for symmetric SO(6) representations: matrix elements of the generators

International Nuclear Information System (INIS)

Piepenbring, R.; Silvestre-Brac, B.; Szymanski, Z.

1987-01-01

Matrix elements of the group generators for the symmetric irreducible representations of SO(6) are explicitly calculated in a closed form employing thedecomposition chain SO(6) is contained in SU(2) X SU(2) X U(1) (which is different from the well known Wigner supermultiplet scheme). The relation to the Gel'fand Tsetlin method using SO(6) contained in SO(5) up to ... SO(2) is indicated. An example of a physical application is given

Simplified chiral superfield propagators for chiral constant mass superfields

International Nuclear Information System (INIS)

Srivastava, P.P.

1983-01-01

Unconstrained superfield potentials are introduced to derive Feynman rules for chiral superfields following conventional procedure which is easy and instructive. Propagators for the case when the mass parameters are constant chiral superfields are derived. The propagators reported here are very simple compared to those available in literature and allow a manageable calculation of higher loops. (Author) [pt

Role of Achiral Nucleobases in Multicomponent Chiral Self-Assembly: Purine-Triggered Helix and Chirality Transfer.

Science.gov (United States)

Deng, Ming; Zhang, Li; Jiang, Yuqian; Liu, Minghua

2016-11-21

Chiral self-assembly is a basic process in biological systems, where many chiral biomolecules such as amino acids and sugars play important roles. Achiral nucleobases usually covalently bond to saccharides and play a significant role in the formation of the double helix structure. However, it remains unclear how the achiral nucleobases can function in chiral self-assembly without the sugar modification. Herein, we have clarified that purine nucleobases could trigger N-(9-fluorenylmethox-ycarbonyl) (Fmoc)-protected glutamic acid to self-assemble into helical nanostructures. Moreover, the helical nanostructure could serve as a matrix and transfer the chirality to an achiral fluorescence probe, thioflavin T (ThT). Upon chirality transfer, the ThT showed not only supramolecular chirality but also circular polarized fluorescence (CPL). Without the nucleobase, the self-assembly processes cannot happen, thus providing an example where achiral molecules played an essential role in the expression and transfer of the chirality. © 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Timoshenko beam model for chiral materials

Science.gov (United States)

Ma, T. Y.; Wang, Y. N.; Yuan, L.; Wang, J. S.; Qin, Q. H.

2018-06-01

Natural and artificial chiral materials such as deoxyribonucleic acid (DNA), chromatin fibers, flagellar filaments, chiral nanotubes, and chiral lattice materials widely exist. Due to the chirality of intricately helical or twisted microstructures, such materials hold great promise for use in diverse applications in smart sensors and actuators, force probes in biomedical engineering, structural elements for absorption of microwaves and elastic waves, etc. In this paper, a Timoshenko beam model for chiral materials is developed based on noncentrosymmetric micropolar elasticity theory. The governing equations and boundary conditions for a chiral beam problem are derived using the variational method and Hamilton's principle. The static bending and free vibration problem of a chiral beam are investigated using the proposed model. It is found that chirality can significantly affect the mechanical behavior of beams, making materials more flexible compared with nonchiral counterparts, inducing coupled twisting deformation, relatively larger deflection, and lower natural frequency. This study is helpful not only for understanding the mechanical behavior of chiral materials such as DNA and chromatin fibers and characterizing their mechanical properties, but also for the design of hierarchically structured chiral materials.

Oriented circular dichroism analysis of chiral surface-anchored metal-organic frameworks grown by liquid-phase epitaxy and upon loading with chiral guest compounds

KAUST Repository

Gu, Zhigang

2014-06-17

Oriented circular dichroism (OCD) is explored and successfully applied to investigate chiral surface-anchored metal-organic frameworks (SURMOFs) based on camphoric acid (D- and Lcam) with the composition [Cu2(Dcam) 2x(Lcam)2-2x(dabco)]n (dabco=1,4-diazabicyclo- [2.2.2]-octane). The three-dimensional chiral SURMOFs with high-quality orientation were grown on quartz glass plates by using a layer-by-layer liquid-phase epitaxy method. The growth orientation, as determined by X-ray diffraction (XRD), could be switched between the [001] and [110] direction by using either OH- or COOH-terminated substrates. These SURMOFs were characterized by using OCD, which confirmed the ratio as well as the orientation of the enantiomeric linker molecules. Theoretical computations demonstrate that the OCD band intensities of the enantiopure [Cu2(Dcam)2(dabco)] n grown in different orientations are a direct result of the anisotropic nature of the chiral SURMOFs. Finally, the enantiopure [Cu 2(Dcam)2(dabco)]n and [Cu2(Lcam) 2(dabco)]n SURMOFs were loaded with the two chiral forms of ethyl lactate [(+)-ethyl-D-lactate and (-)-ethyl-L-lactate)]. An enantioselective enrichment of >60 % was observed by OCD when the chiral host scaffold was loaded from the racemic mixture. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Oriented circular dichroism analysis of chiral surface-anchored metal-organic frameworks grown by liquid-phase epitaxy and upon loading with chiral guest compounds

KAUST Repository

Gu, Zhigang; Bü rck, Jochen; Bihlmeier, Angela; Liu, Jinxuan; Shekhah, Osama; Weidler, Peter G.; Azucena, Carlos; Wang, Zhengbang; Heiß ler, Stefan; Gliemann, Hartmut; Klopper, Wim; Ulrich, Anne S.; Wö ll, Christof H.

2014-01-01

Oriented circular dichroism (OCD) is explored and successfully applied to investigate chiral surface-anchored metal-organic frameworks (SURMOFs) based on camphoric acid (D- and Lcam) with the composition [Cu2(Dcam) 2x(Lcam)2-2x(dabco)]n (dabco=1,4-diazabicyclo- [2.2.2]-octane). The three-dimensional chiral SURMOFs with high-quality orientation were grown on quartz glass plates by using a layer-by-layer liquid-phase epitaxy method. The growth orientation, as determined by X-ray diffraction (XRD), could be switched between the [001] and [110] direction by using either OH- or COOH-terminated substrates. These SURMOFs were characterized by using OCD, which confirmed the ratio as well as the orientation of the enantiomeric linker molecules. Theoretical computations demonstrate that the OCD band intensities of the enantiopure [Cu2(Dcam)2(dabco)] n grown in different orientations are a direct result of the anisotropic nature of the chiral SURMOFs. Finally, the enantiopure [Cu 2(Dcam)2(dabco)]n and [Cu2(Lcam) 2(dabco)]n SURMOFs were loaded with the two chiral forms of ethyl lactate [(+)-ethyl-D-lactate and (-)-ethyl-L-lactate)]. An enantioselective enrichment of >60 % was observed by OCD when the chiral host scaffold was loaded from the racemic mixture. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Amino-acid- and peptide-directed synthesis of chiral plasmonic gold nanoparticles.

Science.gov (United States)

Lee, Hye-Eun; Ahn, Hyo-Yong; Mun, Jungho; Lee, Yoon Young; Kim, Minkyung; Cho, Nam Heon; Chang, Kiseok; Kim, Wook Sung; Rho, Junsuk; Nam, Ki Tae

2018-04-01

Understanding chirality, or handedness, in molecules is important because of the enantioselectivity that is observed in many biochemical reactions 1 , and because of the recent development of chiral metamaterials with exceptional light-manipulating capabilities, such as polarization control 2-4 , a negative refractive index 5 and chiral sensing 6 . Chiral nanostructures have been produced using nanofabrication techniques such as lithography 7 and molecular self-assembly 8-11 , but large-scale and simple fabrication methods for three-dimensional chiral structures remain a challenge. In this regard, chirality transfer represents a simpler and more efficient method for controlling chiral morphology 12-18 . Although a few studies 18,19 have described the transfer of molecular chirality into micrometre-sized helical ceramic crystals, this technique has yet to be implemented for metal nanoparticles with sizes of hundreds of nanometres. Here we develop a strategy for synthesizing chiral gold nanoparticles that involves using amino acids and peptides to control the optical activity, handedness and chiral plasmonic resonance of the nanoparticles. The key requirement for achieving such chiral structures is the formation of high-Miller-index surfaces ({hkl}, h ≠ k ≠ l ≠ 0) that are intrinsically chiral, owing to the presence of 'kink' sites 20-22 in the nanoparticles during growth. The presence of chiral components at the inorganic surface of the nanoparticles and in the amino acids and peptides results in enantioselective interactions at the interface between these elements; these interactions lead to asymmetric evolution of the nanoparticles and the formation of helicoid morphologies that consist of highly twisted chiral elements. The gold nanoparticles that we grow display strong chiral plasmonic optical activity (a dis-symmetry factor of 0.2), even when dispersed randomly in solution; this observation is supported by theoretical calculations and direct

TaRh2B2 and NbRh2B2: Superconductors with a chiral noncentrosymmetric crystal structure.

Science.gov (United States)

Carnicom, Elizabeth M; Xie, Weiwei; Klimczuk, Tomasz; Lin, Jingjing; Górnicka, Karolina; Sobczak, Zuzanna; Ong, Nai Phuan; Cava, Robert J

2018-05-01

It is a fundamental truth in solid compounds that the physical properties follow the symmetry of the crystal structure. Nowhere is the effect of symmetry more pronounced than in the electronic and magnetic properties of materials-even the projection of the bulk crystal symmetry onto different crystal faces is known to have a substantial impact on the surface electronic states. The effect of bulk crystal symmetry on the properties of superconductors is widely appreciated, although its study presents substantial challenges. The effect of a lack of a center of symmetry in a crystal structure, for example, has long been understood to necessitate that the wave function of the collective electron state that gives rise to superconductivity has to be more complex than usual. However, few nonhypothetical materials, if any, have actually been proven to display exotic superconducting properties as a result. We introduce two new superconductors that in addition to having noncentrosymmetric crystal structures also have chiral crystal structures. Because the wave function of electrons in solids is particularly sensitive to the host material's symmetry, crystal structure chirality is expected to have a substantial effect on their superconducting wave functions. Our two experimentally obtained chiral noncentrosymmetric superconducting materials have transition temperatures to superconductivity that are easily experimentally accessible, and our basic property characterization suggests that their superconducting properties may be unusual. We propose that their study may allow for a more in-depth understanding of how chirality influences the properties of superconductors and devices that incorporate them.

Synthesis of New Chiral Amines with a Cyclic 1,2-Diacetal Skeleton Derived from (2R, 3R-(+-Tartaric Acid

Directory of Open Access Journals (Sweden)

Ana Maria Faísca Phillips

2006-03-01

Full Text Available The syntheses of new chiral cyclic 1,2-diacetals from (2R, 3R-( -tartaric acidare described. C2-symmetrical diamines were prepared via direct amidation of the tartrate orfrom the corresponding bismesylate via reaction with sodium azide. For C1-symmetricalcompounds, the Appel reaction was used to form the key intermediate, amonochlorocarbinol, from the diol. Some of the new chiral compounds, produced in good tohigh yields, may be potentially useful as asymmetric organocatalysts or as nitrogen andsulfur chelating ligands for asymmetric metal catalyzed reactions. Thus, a bis-N-methyl-methanamine derivative, used in substoichiometric amounts, was found to catalyze theenantioselective addition of cyclohexanone to (E-β-nitrostyrene with highdiastereoselectivity (syn / anti = 92:8, albeit giving moderate optical purity (syn: 30 %.

Synthesis and structural and photoswitchable properties of novel chiral host molecules: axis chiral 2,2'-dihydroxy-1,1'-binaphthyl-appended stiff-stilbene.

Science.gov (United States)

Shimasaki, Toshiaki; Kato, Shin-ichiro; Ideta, Keiko; Goto, Kenta; Shinmyozu, Teruo

2007-02-16

Novel photoswitchable chiral hosts having an axis chiral 2,2'-dihydroxy-1,1'-binaphthyl (BINOL)-appended stiff-stilbene, trans-(R,R)- and -(S,S)-1, were synthesized by palladium-catalyzed Suzuki-Miyaura coupling and low-valence titanium-catalyzed McMurry coupling as key steps, and they were fully characterized by various NMR spectral techniques. The enantiomers of trans-1 showed almost complete mirror images in the CD spectra, where two split Cotton effects (exciton coupling) were observed in the beta-transitions of the naphthyl chromophore at 222 and 235 nm, but no Cotton effect was observed in the stiff-stilbene chromophore at 365 nm. The structures of (R)-10 and trans-(R,R)-1 were confirmed by X-ray structural analysis. The optimized structure of cis-1 by MO calculations has a wide chiral cavity of 7-8 A in diameter, whereas trans-1 cannot form an intramolecular cavity based on the X-ray data. Irradiation of (R,R)-trans-1 with black light (lambda = 365 nm) in CH3CN or benzene at 23 degrees C led to the conversion to the corresponding cis-isomer, as was monitored by 1H NMR, UV-vis, and CD spectra. At the photostationary state, the cis-1/trans-1 ratio was 86/14 in benzene or 75/25 in CH3CN. On the other hand, irradiation of the cis-1/trans-1 (75/25) mixture in CH3CN with an ultra-high-pressure Hg lamp at 23 degrees C (lambda = 410 nm) led to the photostationary state, where the cis-1/trans-1 ratio was estimated to be 9/91 on the basis of the 1H NMR spectra. The cis-trans and trans-cis interconversions could be repeated 10 times without decomposition of the C=C double bond. Thus, a new type of photoswitchable molecule has been developed, and trans-1 and cis-1 were quite durable under irradiation conditions. The guest binding properties of the BINOL moieties of trans- and cis-(R,R)-1 with F-, Cl-, and H2PO4- were examined by 1H NMR titration in CDCl3. Similar interaction with F- and Cl- was observed in trans-1 (host/guest = 1/1, Kassoc = (1.0 +/- 0.13) x 103 for F

Magnetic test of chiral dynamics in QCD

International Nuclear Information System (INIS)

Simonov, Yu.A.

2014-01-01

Strong magnetic fields in the range eB≫m π 2 effectively probe internal quark structure of chiral mesons and test basic parameters of the chiral theory, such as 〈q-barq〉,f π . We argue on general grounds that 〈q-barq〉 should grow linearly with eB when charged quark degrees of freedom come into play. To make explicit estimates we extend the previously formulated chiral theory, including quark degrees of freedom, to the case of strong magnetic fields and show that the quark condensate |〈q-barq〉| u,d grows quadratically with eB for eB<0.2 GeV 2 and linearly for higher field values. These results agree quantitatively with recent lattice data and differ from χPT predictions

Intrinsic Chirality Origination in Carbon Nanotubes.

Science.gov (United States)

Pierce, Neal; Chen, Gugang; P Rajukumar, Lakshmy; Chou, Nam Hawn; Koh, Ai Leen; Sinclair, Robert; Maruyama, Shigeo; Terrones, Mauricio; Harutyunyan, Avetik R

2017-10-24

Elucidating the origin of carbon nanotube chirality is key for realizing their untapped potential. Currently, prevalent theories suggest that catalyst structure originates chirality via an epitaxial relationship. Here we studied chirality abundances of carbon nanotubes grown on floating liquid Ga droplets, which excludes the influence of catalyst features, and compared them with abundances grown on solid Ru nanoparticles. Results of growth on liquid droplets bolsters the intrinsic preference of carbon nuclei toward certain chiralities. Specifically, the abundance of the (11,1)/χ = 4.31° tube can reach up to 95% relative to (9,4)/χ = 17.48°, although they have exactly the same diameter, (9.156 Å). However, the comparative abundances for the pair, (19,3)/χ = 7.2° and (17,6)/χ = 14.5°, with bigger diameter, (16.405 Å), fluctuate depending on synthesis temperature. The abundances of the same pairs of tubes grown on floating solid polyhedral Ru nanoparticles show completely different trends. Analysis of abundances in relation to nucleation probability, represented by a product of the Zeldovich factor and the deviation interval of a growing nuclei from equilibrium critical size, explain the findings. We suggest that the chirality in the nanotube in general is a result of interplay between intrinsic preference of carbon cluster and induction by catalyst structure. This finding can help to build the comprehensive theory of nanotube growth and offers a prospect for chirality-preferential synthesis of carbon nanotubes by the exploitation of liquid catalyst droplets.

Relationship between harmonic analysis on SU(2) and on SL(2,C)/SU(2)

International Nuclear Information System (INIS)

Healy, D.M. Jr.

1986-01-01

A topic of interest in harmonic analysis is the comparison of Fourier transforms on compact and noncompact spaces. The Poisson summation formula provides a classical example of this idea by providing an explicit relationship between harmonic analysis on the real line R and on the circle S 1 . This dissertation provides a new geometric proof of this formula, and then generalizes this approach to obtain a relationship between Fourier transforms on Upsilon, the space of positive matrices in SL(2,C), and Fourier transforms on SU(2)

Applications of chiral symmetry

International Nuclear Information System (INIS)

Pisarski, R.D.

1995-03-01

The author discusses several topics in the applications of chiral symmetry at nonzero temperature. First, where does the rho go? The answer: up. The restoration of chiral symmetry at a temperature T χ implies that the ρ and a 1 vector mesons are degenerate in mass. In a gauged linear sigma model the ρ mass increases with temperature, m ρ (T χ ) > m ρ (0). The author conjectures that at T χ the thermal ρ - a 1 , peak is relatively high, at about ∼1 GeV, with a width approximately that at zero temperature (up to standard kinematic factors). The ω meson also increases in mass, nearly degenerate with the ρ, but its width grows dramatically with temperature, increasing to at least ∼100 MeV by T χ . The author also stresses how utterly remarkable the principle of vector meson dominance is, when viewed from the modern perspective of the renormalization group. Secondly, he discusses the possible appearance of disoriented chiral condensates from open-quotes quenchedclose quotes heavy ion collisions. It appears difficult to obtain large domains of disoriented chiral condensates in the standard two flavor model. This leads to the last topic, which is the phase diagram for QCD with three flavors, and its proximity to the chiral critical point. QCD may be very near this chiral critical point, and one might thereby generated large domains of disoriented chiral condensates

Strongly coupled SU(2v boson and LEP1 versus LEP2

Directory of Open Access Journals (Sweden)

M. Bilenky

1993-10-01

Full Text Available If new strong interactions exist in the electroweak bosonic sector (e.g., strong Higgs sector, dynamical electroweak breaking, etc., it is natural to expect new resonances, with potentially strong couplings. We consider an additional vector-boson triplet, V+-, V0, associated with an SU(2v local symmetry under the specific (but rather natural assumption that ordinary fermions are SU(2v singlets. Mixing of the V triplet with the W+-, Z0 bosons effectively leads to an SU(2L×U(1Y violating vector-boson-fermion interaction which is strongly bounded by LEP1 data. In contrast, the potentially large deviation of the Z0W+W- coupling from its SU(2L×U(1Y value is hardly constrained by LEP1 data. Results from experiments with direct access to the trilinear Z0W+W− coupling (LEP200, NLC are urgently needed.

Helical Polyacetylenes Induced via Noncovalent Chiral Interactions and Their Applications as Chiral Materials.

Science.gov (United States)

Maeda, Katsuhiro; Yashima, Eiji

2017-08-01

Construction of predominantly one-handed helical polyacetylenes with a desired helix sense utilizing noncovalent chiral interactions with nonracemic chiral guest compounds based on a supramolecular approach is described. As with the conventional dynamic helical polymers possessing optically active pendant groups covalently bonded to the polymer chains, this noncovalent helicity induction system can show significant chiral amplification phenomena, in which the chiral information of the nonracemic guests can transfer with high cooperativity through noncovalent bonding interactions to induce an almost single-handed helical conformation in the polymer backbone. An intriguing "memory effect" of the induced macromolecular helicity is observed for some polyacetylenes, which means that the helical conformations induced in dynamic helical polyacetylene can be transformed into metastable static ones by tuning their helix-inversion barriers. Potential applications of helical polyacetylenes with controlled helix sense constructed by the "noncovalent helicity induction and/or memory effect" as chiral materials are also described.

Increments to chiral recognition facilitating enantiomer separations of chiral acids, bases, and ampholytes using Cinchona-based zwitterion exchanger chiral stationary phases.

Science.gov (United States)

Wernisch, Stefanie; Pell, Reinhard; Lindner, Wolfgang

2012-07-01

The intramolecular distances of anion and cation exchanger sites of zwitterionic chiral stationary phases represent potential tuning sites for enantiomer selectivity. In this contribution, we investigate the influence of alkanesulfonic acid chain length and flexibility on enantiomer separations of chiral acids, bases, and amphoteric molecules for six Cinchona alkaloid-based chiral stationary phases in comparison with structurally related anion and cation exchangers. Employing polar-organic elution conditions, we observed an intramolecular counterion effect for acidic analytes which led to reduced retention times but did not impair enantiomer selectivities. Retention of amphoteric analytes is based on simultaneous double ion pairing of their charged functional groups with the acidic and basic sites of the zwitterionic selectors. A chiral center in the vicinity of the strong cation exchanger site is vital for chiral separations of bases. Sterically demanding side chains are beneficial for separations of free amino acids. Enantioseparations of free (un-derivatized) peptides were particularly successful in stationary phases with straight-chain alkanesulfonic acid sites, pointing to a beneficial influence of more flexible moieties. In addition, we observed pseudo-enantiomeric behavior of quinine and quinidine-derived chiral stationary phases facilitating reversal of elution orders for all analytes. © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Unified theory in the worldline approach

Directory of Open Access Journals (Sweden)

James P. Edwards

2015-11-01

Full Text Available We explore unified field theories based on the gauge groups SU(5 and SO(10 using the worldline approach for chiral fermions with a Wilson loop coupling to a background gauge field. Representing path ordering and chiral projection operators with functional integrals has previously reproduced the sum over the chiralities and representations of standard model particles in a compact way. This paper shows that for SU(5 the 5¯ and 10 representations – into which the Georgi–Glashow model places the left-handed fermionic content of the standard model – appear naturally and with the familiar chirality. We carry out the same analysis for flipped SU(5 and uncover a link to SO(10 unified theory. We pursue this by exploring the SO(10 theory in the same framework, the less established unified theory based on SU(6 and briefly consider the Pati–Salam model using SU(4×SU(2×SU(2.

Chiral Synthons in Pesticide Syntheses

NARCIS (Netherlands)

Feringa, Bernard

1988-01-01

The use of chiral synthons in the preparation of enantiomerically pure pesticides is described in this chapter. Several routes to chiral synthons based on asymmetric synthesis or on natural products are illustrated. Important sources of chiral building blocks are reviewed. Furthermore the

Spectral statistics in chiral-orthogonal disordered systems

International Nuclear Information System (INIS)

Evangelou, S N; Katsanos, D E

2003-01-01

We describe the singularities in the averaged density of states and the corresponding statistics of the energy levels in two- (2D) and three-dimensional (3D) chiral symmetric and time-reversal invariant disordered systems, realized in bipartite lattices with real off-diagonal disorder. For off-diagonal disorder of zero mean, we obtain a singular density of states in 2D which becomes much less pronounced in 3D, while the level-statistics can be described by a semi-Poisson distribution with mostly critical fractal states in 2D and Wigner surmise with mostly delocalized states in 3D. For logarithmic off-diagonal disorder of large strength, we find behaviour indistinguishable from ordinary disorder with strong localization in any dimension but in addition one-dimensional 1/ vertical bar E vertical bar Dyson-like asymptotic spectral singularities. The off-diagonal disorder is also shown to enhance the propagation of two interacting particles similarly to systems with diagonal disorder. Although disordered models with chiral symmetry differ from non-chiral ones due to the presence of spectral singularities, both share the same qualitative localization properties except at the chiral symmetry point E=0 which is critical

Chiral bag model

International Nuclear Information System (INIS)

Musakhanov, M.M.

1980-01-01

The chiral bag model is considered. It is suggested that pions interact only with the surface of a quark ''bag'' and do not penetrate inside. In the case of a large bag the pion field is rather weak and goes to the linearized chiral bag model. Within that model the baryon mass spectrum, β decay axial constant, magnetic moments of baryons, pion-baryon coupling constants and their form factors are calculated. It is shown that pion corrections to the calculations according to the chiral bag model is essential. The obtained results are found to be in a reasonable agreement with the experimental data

N = 1 SU(2) supersymmetric Yang-Mills theory on the lattice with light dynamical Wilson gluinos

International Nuclear Information System (INIS)

Demmouche, Kamel

2009-01-01

The supersymmetric Yang-Mills (SYM) theory with one supercharge (N=1) and one additional Majorana matter-field represents the simplest model of supersymmetric gauge theory. Similarly to QCD, this model includes gauge fields, gluons, with color gauge group SU(N c ) and fermion fields, describing the gluinos. The non-perturbative dynamical features of strongly coupled supersymmetric theories are of great physical interest. For this reason, many efforts are dedicated to their formulation on the lattice. The lattice regularization provides a powerful tool to investigate non-perturbatively the phenomena occurring in SYM such as confinement and chiral symmetry breaking. In this work we perform numerical simulations of the pure SU(2) SYM theory on large lattices with small Majorana gluino masses down to about m g approx 115 MeV with lattice spacing up to a ≅0.1 fm. The gluino dynamics is simulated by the Two-Step Multi-Boson (TSMB) and the Two-Step Polynomial Hybrid Monte Carlo (TS-PHMC) algorithms. Supersymmetry (SUSY) is broken explicitly by the lattice and the Wilson term and softly by the presence of a non-vanishing gluino mass m g ≠0. However, the recovery of SUSY is expected in the infinite volume continuum limit by tuning the bare parameters to the SUSY point in the parameter space. This scenario is studied by the determination of the low-energy mass spectrum and by means of lattice SUSY Ward-Identities (WIs). (orig.)

Quantization of the Poisson SU(2) and its Poisson homogeneous space - the 2-sphere

International Nuclear Information System (INIS)

Sheu, A.J.L.

1991-01-01

We show that deformation quantizations of the Poisson structures on the Poisson Lie group SU(2) and its homogeneous space, the 2-sphere, are compatible with Woronowicz's deformation quantization of SU(2)'s group structure and Podles' deformation quantization of 2-sphere's homogeneous structure, respectively. So in a certain sense the multiplicativity of the Lie Poisson structure on SU(2) at the classical level is preserved under quantization. (orig.)

Topology in SU(2) lattice gauge theory and parallelization of functional magnetic resonance imaging

Energy Technology Data Exchange (ETDEWEB)

Solbrig, Stefan

2008-07-01

In this thesis, I discuss topological properties of quenched SU(2) lattice gauge fields. In particular, clusters of topological charge density exhibit a power-law. The exponent of that power-law can be used to validate models for lattice gauge fields. Instead of working with fixed cutoffs of the topological charge density, using the notion of a ''watermark'' is more convenient. Furthermore, I discuss how a parallel computer, originally designed for lattice gauge field simulations, can be used for functional magnetic resonance imaging. Multi parameter fits can be parallelized to achieve almost real-time evaluation of fMRI data. (orig.)

Topology in SU(2) lattice gauge theory and parallelization of functional magnetic resonance imaging

International Nuclear Information System (INIS)

Solbrig, Stefan

2008-01-01

In this thesis, I discuss topological properties of quenched SU(2) lattice gauge fields. In particular, clusters of topological charge density exhibit a power-law. The exponent of that power-law can be used to validate models for lattice gauge fields. Instead of working with fixed cutoffs of the topological charge density, using the notion of a ''watermark'' is more convenient. Furthermore, I discuss how a parallel computer, originally designed for lattice gauge field simulations, can be used for functional magnetic resonance imaging. Multi parameter fits can be parallelized to achieve almost real-time evaluation of fMRI data. (orig.)

Cell Chirality Drives Left-Right Asymmetric Morphogenesis.

Science.gov (United States)

Inaki, Mikiko; Sasamura, Takeshi; Matsuno, Kenji

2018-01-01

Most macromolecules found in cells are chiral, meaning that they cannot be superimposed onto their mirror image. However, cells themselves can also be chiral, a subject that has received little attention until very recently. In our studies on the mechanisms of left-right (LR) asymmetric development in Drosophila , we discovered that cells can have an intrinsic chirality to their structure, and that this "cell chirality" is generally responsible for the LR asymmetric development of certain organs in this species. The actin cytoskeleton plays important roles in the formation of cell chirality. In addition, Myosin31DF ( Myo31DF ), which encodes Drosophila Myosin ID, was identified as a molecular switch for cell chirality. In other invertebrate species, including snails and Caenorhabditis elegans , chirality of the blastomeres, another type of cell chirality, determines the LR asymmetry of structures in the body. Thus, chirality at the cellular level may broadly contribute to LR asymmetric development in various invertebrate species. Recently, cell chirality was also reported for various vertebrate cultured cells, and studies suggested that cell chirality is evolutionarily conserved, including the essential role of the actin cytoskeleton. Although the biological roles of cell chirality in vertebrates remain unknown, it may control LR asymmetric development or other morphogenetic events. The investigation of cell chirality has just begun, and this new field should provide valuable new insights in biology and medicine.

Isotopic chirality

Energy Technology Data Exchange (ETDEWEB)

Floss, H.G. [Univ. of Washington, Seattle, WA (United States)

1994-12-01

This paper deals with compounds that are chiral-at least in part, due to isotope substitution-and their use in tracing the steric course of enzyme reaction in vitro and in vivo. There are other applications of isotopically chiral compounds (for example, in analyzing the steric course of nonenzymatic reactions and in probing the conformation of biomolecules) that are important but they will not be discussed in this context.

Pure chiral optical fibres.

Science.gov (United States)

Poladian, L; Straton, M; Docherty, A; Argyros, A

2011-01-17

We investigate the properties of optical fibres made from chiral materials, in which a contrast in optical activity forms the waveguide, rather than a contrast in the refractive index; we refer to such structures as pure chiral fibres. We present a mathematical formulation for solving the modes of circularly symmetric examples of such fibres and examine the guidance and polarisation properties of pure chiral step-index, Bragg and photonic crystal fibre designs. Their behaviour is shown to differ for left- and right-hand circular polarisation, allowing circular polarisations to be isolated and/or guided by different mechanisms, as well as differing from equivalent non-chiral fibres. The strength of optical activity required in each case is quantified.

Chiral perturbation theory with nucleons

International Nuclear Information System (INIS)

Meissner, U.G.

1991-09-01

I review the constraints posed on the interactions of pions, nucleons and photons by the spontaneously broken chiral symmetry of QCD. The framework to perform these calculations, chiral perturbation theory, is briefly discussed in the meson sector. The method is a simultaneous expansion of the Greens functions in powers of external moments and quark masses around the massless case, the chiral limit. To perform this expansion, use is made of a phenomenological Lagrangian which encodes the Ward-identities and pertinent symmetries of QCD. The concept of chiral power counting is introduced. The main part of the lectures of consists in describing how to include baryons (nucleons) and how the chiral structure is modified by the fact that the nucleon mass in the chiral limit does not vanish. Particular emphasis is put on working out applications to show the strengths and limitations of the methods. Some processes which are discussed are threshold photopion production, low-energy compton scattering off nucleons, πN scattering and the σ-term. The implications of the broken chiral symmetry on the nuclear forces are briefly described. An alternative approach, in which the baryons are treated as very heavy fields, is touched upon

Asymmetric transfer hydrogenation of ketones in aqueous solution catalyzed by Rhodium(III) complexes with C2-symmetric fluorene-ligands containing chiral (1R,2R)-cyclohexane-1,2-diamine

International Nuclear Information System (INIS)

Montalvo-Gonzalez, Ruben; Chavez, Daniel; Aguirre, Gerardo; Parra-Hake, Miguel; Somanathan, Ratnasamy

2010-01-01

Two C 2 -symmetric bis(sulfonamide) ligands containing fluorene-chiral (1R, 2R)-cyclohexane-1,2-diamine were complexed to Rh III (Cp * ) and used as catalyst to reduce aromatic ketones. The corresponding chiral secondary alcohols were obtained in 87-100% ee and 85-99% yield, under asymmetric transfer hydrogenation (ATH) conditions using aqueous sodium formate as the hydride source. With acetophenone, 94% ee and 86-97% yield was achieved with substrate/catalyst (S/C) ratio of 10,000. (author)

Transfer of chirality from light to a Disperse Red 1 molecular glass surface.

Science.gov (United States)

Mazaheri, Leila; Lebel, Olivier; Nunzi, Jean-Michel

2017-12-01

Chiral structures and materials interact with light in well-documented ways, but light can also interact with achiral materials to generate chirality by inscribing its asymmetric configuration on photoresponsive materials, such as azobenzene derivatives. While it is thus possible to generate both two-dimensional (2D) and three-dimensional (3D) chirality, 2D chirality is especially attractive because of its non-reciprocity. Herein, 2D chirality is induced on the surface of a glass-forming Disperse Red 1 derivative by irradiation with a single laser beam, yielding crossed spontaneous surface relief gratings with different pitches. Azimuth rotations up to 10° have been observed, and the absence of 3D chirality has been confirmed. This method thus allows generating non-reciprocal planar chiral objects by a simple, single irradiation process on a thin film of a material that can easily be processed over large areas or onto small objects.

Lattice QCD at the physical point meets S U (2 ) chiral perturbation theory

Science.gov (United States)

Dürr, Stephan; Fodor, Zoltán; Hoelbling, Christian; Krieg, Stefan; Kurth, Thorsten; Lellouch, Laurent; Lippert, Thomas; Malak, Rehan; Métivet, Thibaut; Portelli, Antonin; Sastre, Alfonso; Szabó, Kálmán; Budapest-Marseille-Wuppertal Collaboration

2014-12-01

We perform a detailed, fully correlated study of the chiral behavior of the pion mass and decay constant, based on 2 +1 flavor lattice QCD simulations. These calculations are implemented using tree-level, O (a )-improved Wilson fermions, at four values of the lattice spacing down to 0.054 fm and all the way down to below the physical value of the pion mass. They allow a sharp comparison with the predictions of S U (2 ) chiral perturbation theory (χ PT ) and a determination of some of its low energy constants. In particular, we systematically explore the range of applicability of next-to-leading order (NLO) S U (2 ) χ PT in two different expansions: the first in quark mass (x expansion), and the second in pion mass (ξ expansion). We find that these expansions begin showing signs of failure for Mπ≳300 MeV , for the typical percent-level precision of our Nf=2 +1 lattice results. We further determine the LO low energy constants (LECs), F =88.0 ±1.3 ±0.2 and BMS ¯(2 GeV )=2.61 (6 )(1 ) GeV , and the related quark condensate, ΣMS ¯(2 GeV )=(272 ±4 ±1 MeV )3 , as well as the NLO ones, ℓ¯3=2.6 (5 )(3 ) and ℓ¯4=3.7 (4 )(2 ), with fully controlled uncertainties. We also explore the next-to-next-to-leading order (NNLO) expansions and the values of NNLO LECs. In addition, we show that the lattice results favor the presence of chiral logarithms. We further demonstrate how the absence of lattice results with pion masses below 200 MeV can lead to misleading results and conclusions. Our calculations allow a fully controlled, ab initio determination of the pion decay constant with a total 1% error, which is in excellent agreement with experiment.

Quantum critical spin-2 chain with emergent SU(3) symmetry.

Science.gov (United States)

Chen, Pochung; Xue, Zhi-Long; McCulloch, I P; Chung, Ming-Chiang; Huang, Chao-Chun; Yip, S-K

2015-04-10

We study the quantum critical phase of an SU(2) symmetric spin-2 chain obtained from spin-2 bosons in a one-dimensional lattice. We obtain the scaling of the finite-size energies and entanglement entropy by exact diagonalization and density-matrix renormalization group methods. From the numerical results of the energy spectra, central charge, and scaling dimension we identify the conformal field theory describing the whole critical phase to be the SU(3)_{1} Wess-Zumino-Witten model. We find that, while the Hamiltonian is only SU(2) invariant, in this critical phase there is an emergent SU(3) symmetry in the thermodynamic limit.

Synthesis of new chiral amines with a cyclic 1,2-diacetal skeleton derived from (2R, 3R)-(+)-tartaric acid.

Science.gov (United States)

Barros, M Teresa; Phillips, Ana Maria Faísca

2006-03-17

The syntheses of new chiral cyclic 1,2-diacetals from (2R, 3R)-( )-tartaric acid are described. C(2)-symmetrical diamines were prepared via direct amidation of the tartrate or from the corresponding bismesylate via reaction with sodium azide. For C1-symmetrical compounds, the Appel reaction was used to form the key intermediate, a monochlorocarbinol, from the diol. Some of the new chiral compounds, produced in good to high yields, may be potentially useful as asymmetric organocatalysts or as nitrogen and sulfur chelating ligands for asymmetric metal catalyzed reactions. Thus, a bis-N-methyl-methanamine derivative, used in substoichiometric amounts, was found to catalyze the enantioselective addition of cyclohexanone to (E)-beta-nitrostyrene with high diastereoselectivity (syn / anti = 92:8), albeit giving moderate optical purity (syn: 30 %).

Chiral magnetic effect of light

Science.gov (United States)

Hayata, Tomoya

2018-05-01

We study a photonic analog of the chiral magnetic (vortical) effect. We discuss that the vector component of magnetoelectric tensors plays a role of "vector potential," and its rotation is understood as "magnetic field" of a light. Using the geometrical optics approximation, we show that "magnetic fields" cause an anomalous shift of a wave packet of a light through an interplay with the Berry curvature of photons. The mechanism is the same as that of the chiral magnetic (vortical) effect of a chiral fermion, so that we term the anomalous shift "chiral magnetic effect of a light." We further study the chiral magnetic effect of a light beyond geometric optics by directly solving the transmission problem of a wave packet at a surface of a magnetoelectric material. We show that the experimental signal of the chiral magnetic effect of a light is the nonvanishing of transverse displacements for the beam normally incident to a magnetoelectric material.

On the exact S-matrix from CP sup(n-1) and SU(n) chiral Thirring model

International Nuclear Information System (INIS)

Abdalla, E.; Abdalla, M.C.B.

1980-03-01

The S-matrix of CP sub(n-1) and SU(n) Thirring model is calculated, perturbatively, up to 2 loops. The calculation shows striking similarities, but the S -matrix has some deviations from the expected exact one. (Author) [pt

Topological susceptibility and chiral condensate with Nf=2+1+1 dynamical flavors of maximally twisted mass fermions

International Nuclear Information System (INIS)

Cichy, K.

2012-03-01

We study the 'spectral projector' method for the computation of the chiral condensate and the topological susceptibility, using N f =2+1+1 dynamical flavors of maximally twisted mass Wilson fermions. In particular, we perform a study of the quark mass dependence of the chiral condensate Σ and topological susceptibility χ top in the range 270 MeV π top in the quenched approximation where we match the lattice spacing to the N f =2+1+1 dynamical simulations. Using the Kaon, η and η' meson masses computed on the N f =2+1+1 ensembles, we then perform a preliminary test of the Witten-Veneziano relation.

Bosonization of the generalized SU(3) Nambu-Jona-Lasinio model in the 1/N expansion; Bosonizacao do modelo de Nambu-Jona-Lasinio SU(3) generalizado na expansao 1/N

Energy Technology Data Exchange (ETDEWEB)

Campos, Francisco Antonio Pena

1995-12-31

The present work consists in a 1/N expansion of extended version of the SU(3) Nambu-Jona-Lasinio model in the context of the Functional Integral. The gap equations, meson propagators, triangle diagram, etc, appear quite naturally as different orders in the expansion. The new features of this approach is the inclusion of high order corrections in the 1/N leading orders, which have never included in the previous one. The method also allows for the construction of a chiral Lagrangian of interacting mesons based on the SU(3) NJL model, here obtained for the first time. (author) 32 refs., 11 figs., 5 tabs.

Chirality-dependent cellular uptake of chiral nanocarriers and intracellular delivery of different amounts of guest molecules

Science.gov (United States)

Kehr, Nermin Seda; Jose, Joachim

2017-12-01

We demonstrate the organic molecules loaded and chiral polymers coated periodic mesoporous organosilica (PMO) to generate chiral nanocarriers that we used to study chirality-dependent cellular uptake in serum and serum-free media and the subsequent delivery of different amounts of organic molecules into cells. Our results show that the amount of internalized PMO and thus the transported amount of organic molecules by nanocarrier PMO into cells was chirality dependent and controlled by hard/soft protein corona formation on the PMO surfaces. Therefore, this study demonstrate that chiral porous nanocarriers could potentially be used as advanced drug delivery systems which are able to use the specific chiral surface-protein interactions to influence/control the amount of (bio)active molecules delivered to cells in drug delivery and/or imaging applications.

Anisotropy and Strong-Coupling Effects on the Collective Mode Spectrum of Chiral Superconductors: Application to Sr₂RuO₄

Directory of Open Access Journals (Sweden)

James Avery Sauls

2015-06-01

Full Text Available Recent theories of Sr2RuO4 based on the interplay of strong interactions, spin-orbit coupling and multi-band anisotropy predict chiral or helical ground states with strong anisotropy of the pairing states, with deep minima in the excitation gap, as well as strong phase anisotropy for the chiral ground state. We develop time-dependent mean field theory to calculate the Bosonic spectrum for the class of 2D chiral superconductors spanning 3He-A to chiral superconductors with strong anisotropy. Chiral superconductors support a pair of massive Bosonic excitations of the time-reversed pairs labeled by their parity under charge conjugation. These modes are degenerate for 2D 3He-A. Crystal field anisotropy lifts the degeneracy. Strong anisotropy also leads to low-lying Fermions, and thus to channels for the decay of the Bosonic modes. Selection rules and phase space considerations lead to large asymmetries in the lifetimes and hybridization of the Bosonic modes with the continuum of un-bound Fermion pairs. We also highlight results for the excitation of the Bosonic modes by microwave radiation that provide clear signatures of the Bosonic modes of an anisotropic chiral ground state.

Static forces in d=2+1 SU(N) gauge theories

International Nuclear Information System (INIS)

Meyer, H.B.

2006-07-01

Using a three-level algorithm we perform a high-precision lattice computation of the static force up to 1fm in the 2+1 dimensional SU(5) gauge theory. Discretization errors and the continuum limit are discussed in detail. By comparison with existing SU(2) and SU(3) data it is found that σr 2 0 =1.65-(π)/(24) holds at an accuracy of 1% for all N≥2, where r 0 is the Sommer reference scale. The effective central charge c(r) is obtained and an intermediate distance r s is defined via the property c(r s )=(π)/(24). It separates in a natural way the short-distance regime governed by perturbation theory from the long-distance regime described by an effective string theory. The ratio τ s /τ 0 decreases significantly from SU(2) to SU(3) to SU(5), where r s 0 . We give a preliminary estimate of its value in the large-N limit. The static force in the smallest representation of N-ality 2, which tends to the k=2 string tension as r→∞, is also computed up to 0.7 fm. The deviation from Casimir scaling is positive and grows from 0.1% to 1% in that range. (Orig.)

BRST quantization of 2d-Yang Mills theory with anomalies

International Nuclear Information System (INIS)

Kalau, Wolfgang

1992-01-01

The BRST-quantization of anomalous 2d-Yang Mills (YM) theory is discussed. Since an oscillator basis for the YM-Fock-space is used the anomaly appears already for a pure YM-system and the constraints form a Kac-Moody algebra with negative central charge. The coupling of chiral fermions is also discussed and it is found that the BRST-cohomology for systems with chiral fermions in a sufficiently large representation of the gauge group is completely equivalent to the cohomology of the finite dimensional gauge group. For pure YM theory or YM theory coupled to chiral fermions in small representations there exists an infinite number of inequivalent cohomology classes. This is discussed in some detail for the example of SU(2). (author). 15 refs

Comparison of lattice gauge theories with gauge groups Z2 and SU(2)

International Nuclear Information System (INIS)

Mack, G.; Petkova, B.

1978-11-01

We study a model of a pure Yang Mills theory with gauge group SU(2) on a lattice in Euclidean space. We compare it with the model obtained by restricting varibales to 2 . An inequality relating expectation values of the Wilson loop integral in the two theories is established. It shows that confinement of static quarks is true in our SU(2) model whenever it holds for the corresponding 2 -model. The SU(2) model is shown to have high and low temperature phases that are distinguished by a qualitatively different behavior of the t'Hooft disorder parameter. (orig.) [de

Enantiomeric determination of amino compounds with high sensitivity using the chiral reagents (+)- and (-)-1-(9-anthryl)-2-propyl chloroformate.

Science.gov (United States)

Thorsén, G; Engström, A; Josefsson, B

1997-10-31

New chiral precolumn reagents, (+)- and (-)-1-(9-anthryl)-2-propyl chloroformate (APOC), are introduced for the chiral separation of amino acids and small peptides in capillary electrophoresis. Chiral separation of 17 amino acids and four small peptides as their diastereomeric 1-(9-anthryl)-2-propyl carbamate derivatives have been achieved by micellar electrokinetic chromatography. The detection limit for the derivatives is in the femtomole range with UV detection and in the attomole range with laser-induced fluorescence (LIF) detection. LIF detection was used to determine the enantiomeric excess of four APOC-derivatised peptides. The use of the new, anthracene-based reagents in conjunction with argon ion LIF makes enantiomeric determinations at ppm levels feasible. In this paper determinations below promille levels are performed without overloading the separation system.

Detecting the chirality for coupled quantum dots

International Nuclear Information System (INIS)

Cao Huijuan; Hu Lian

2008-01-01

We propose a scheme to detect the chirality for a system consisting of three coupled quantum dots. The chirality is found to be determined by the frequency of the transition between chiral states under the chiral symmetry broken perturbation. The results are important to construct quantum gates and to demonstrate chiral entangle states in the triangle spin dots

Synthesis of a new chiral cyclic aminal derived from rac-1,2-propanediamine

Czech Academy of Sciences Publication Activity Database

Rivera, A.; Pacheco, D.J.; Ríos-Motta, J.; Fejfarová, Karla; Dušek, Michal

2012-01-01

Roč. 53, č. 45 (2012), s. 6132-6135 ISSN 0040-4039 Grant - others:AV ČR(CZ) AP0701 Program:Akademická prémie - Praemium Academiae Institutional research plan: CEZ:AV0Z10100521 Keywords : aminal cage * axial chirality * imidazolidine-bridged bis(phenols) * Mannich condensation * 1,2-propanediamine Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 2.397, year: 2012

Asymmetric transfer hydrogenation of ketones in aqueous solution catalyzed by Rhodium(III) complexes with C2-symmetric fluorene-ligands containing chiral (1R,2R)-cyclohexane-1,2-diamine

Energy Technology Data Exchange (ETDEWEB)

Montalvo-Gonzalez, Ruben [Universidad Autonoma de Nayarit, Tepic, Nay (Mexico). Unidad Academica de Ciencias Quimico Biologicas y Farmaceuticas; Chavez, Daniel; Aguirre, Gerardo; Parra-Hake, Miguel; Somanathan, Ratnasamy, E-mail: somanatha@sundown.sdsu.ed [Instituto Tecnologico de Tijuana, B.C. (Mexico). Centro de Graduados e Investigacion

2010-07-01

Two C{sub 2}-symmetric bis(sulfonamide) ligands containing fluorene-chiral (1R, 2R)-cyclohexane-1,2-diamine were complexed to Rh{sup III}(Cp{sup *}) and used as catalyst to reduce aromatic ketones. The corresponding chiral secondary alcohols were obtained in 87-100% ee and 85-99% yield, under asymmetric transfer hydrogenation (ATH) conditions using aqueous sodium formate as the hydride source. With acetophenone, 94% ee and 86-97% yield was achieved with substrate/catalyst (S/C) ratio of 10,000. (author)

Chiral and parity anomalies at finite temperature and density

International Nuclear Information System (INIS)

Sisakyan, A.N.; Shevchenko, O.Yu.; Solganik, S.B.

1997-01-01

Two closely related topological phenomena are studied at finite density and temperature. These are chiral anomaly and Chern-Simons term. By using different methods it is shown that μ 2 =m 2 is the crucial point for Chern-Simons term at zero temperature. So when μ 2 2 , μ influence disappears and we get the usual Chern-Simons term. On the other hand, when μ 2 >m 2 , the Chern-Simons term vanishes because of nonzero density of background fermions. It occurs that the chiral anomaly doesn't depend on density and temperature. The connection between parity anomalous Chern-Simons term and chiral anomaly is generalized on finite density. These results hold in any dimension both in Abelian and in non-Abelian cases

Oscillation damping of chiral string loops

International Nuclear Information System (INIS)

Babichev, Eugeny; Dokuchaev, Vyacheslav

2002-01-01

Chiral cosmic string loops tend to the stationary (vorton) configuration due to energy loss into gravitational and electromagnetic radiation. We describe the asymptotic behavior of near stationary chiral loops and their fading to vortons. General limits on the gravitational and electromagnetic energy losses by near stationary chiral loops are found. For these loops we estimate the oscillation damping time. We present solvable examples of gravitational radiation energy loss by some chiral loop configurations. The analytical dependence of string energy with time is found in the case of the chiral ring with small amplitude radial oscillations

Quasiparticle scattering image in hidden order phases and chiral superconductors

Energy Technology Data Exchange (ETDEWEB)

Thalmeier, Peter [Max Planck Institute for Chemical Physics of Solids, 01187 Dresden (Germany); Akbari, Alireza, E-mail: alireza@apctp.org [Asia Pacific Center for Theoretical Physics, Pohang, Gyeongbuk 790-784 (Korea, Republic of); Department of Physics, and Max Planck POSTECH Center for Complex Phase Materials, POSTECH, Pohang 790-784 (Korea, Republic of)

2016-02-15

The technique of Bogoliubov quasiparticle interference (QPI) has been successfully used to investigate the symmetry of unconventional superconducting gaps, also in heavy fermion compounds. It was demonstrated that QPI can distinguish between the d-wave singlet candidates in CeCoIn{sub 5}. In URu{sub 2}Si{sub 2} presumably a chiral d-wave singlet superconducting (SC) state exists inside a multipolar hidden order (HO) phase. We show that hidden order leaves an imprint on the symmetry of QPI pattern that may be used to determine the essential question whether HO in URu{sub 2}Si{sub 2} breaks the in-plane rotational symmetry or not. We also demonstrate that the chiral d-wave SC gap leads to a crossover to a quasi-2D QPI spectrum below T{sub c} which sharpens the HO features. Furthermore we investigate the QPI image of chiral p-wave multigap superconductor Sr{sub 2}RuO{sub 4}. - Highlights: • The chiral multigap structure of Sr{sub 2}RuO{sub 4} leads to rotation of QPI spectrum with bias voltage. • 5f band reconstruction in hidden order phase of URu{sub 2}Si{sub 2} is obtained from two orbital model. • The chiral superconductivity in URu{sub 2}Si{sub 2} leads to quasi-2D quasiparticle interference (QPI).

Nanoscale chirality in metal and semiconductor nanoparticles.

Science.gov (United States)

Kumar, Jatish; Thomas, K George; Liz-Marzán, Luis M

2016-10-18

The field of chirality has recently seen a rejuvenation due to the observation of chirality in inorganic nanomaterials. The advancements in understanding the origin of nanoscale chirality and the potential applications of chiroptical nanomaterials in the areas of optics, catalysis and biosensing, among others, have opened up new avenues toward new concepts and design of novel materials. In this article, we review the concept of nanoscale chirality in metal nanoclusters and semiconductor quantum dots, then focus on recent experimental and theoretical advances in chiral metal nanoparticles and plasmonic chirality. Selected examples of potential applications and an outlook on the research on chiral nanomaterials are additionally provided.

1/N perturbation theory and quantum conservation laws for supersymmetrical chiral field. 2

International Nuclear Information System (INIS)

Aref'eva, I.Ya.; Krivoshchekov, V.K.; Medvedev, P.B.; Gosudarstvennyj Komitet Standartov Soveta Ministrov SSSR, Moscow; Gosudarstvennyj Komitet po Ispol'zovaniyu Atomnoj Ehnergii SSSR, Moscow. Inst. Teoreticheskoj i Ehksperimental'noj Fiziki)

1980-01-01

The renormalizability of the supersymmetric chiral model (supersymmetric nonlinear σ-model) is proved in the framework of the 1/N perturbation theory expansion proposed in the previous paper. The renormalizability proof is essentially based on the quantum supersymmetric chirality condition. The supersymmetric formulation of equations of motion is given. The first non-trivial quantum conservation laws are derived

Chiral Thirring–Wess model

Energy Technology Data Exchange (ETDEWEB)

Rahaman, Anisur, E-mail: anisur.rahman@saha.ac.in

2015-10-15

The vector type of interaction of the Thirring–Wess model was replaced by the chiral type and a new model was presented which was termed as chiral Thirring–Wess model in Rahaman (2015). The model was studied there with a Faddeevian class of regularization. Few ambiguity parameters were allowed there with the apprehension that unitarity might be threatened like the chiral generation of the Schwinger model. In the present work it has been shown that no counter term containing the regularization ambiguity is needed for this model to be physically sensible. So the chiral Thirring–Wess model is studied here without the presence of any ambiguity parameter and it has been found that the model not only remains exactly solvable but also does not lose the unitarity like the chiral generation of the Schwinger model. The phase space structure and the theoretical spectrum of this new model have been determined in the present scenario. The theoretical spectrum is found to contain a massive boson with ambiguity free mass and a massless boson.

Chiral Thirring–Wess model

International Nuclear Information System (INIS)

Rahaman, Anisur

2015-01-01

The vector type of interaction of the Thirring–Wess model was replaced by the chiral type and a new model was presented which was termed as chiral Thirring–Wess model in Rahaman (2015). The model was studied there with a Faddeevian class of regularization. Few ambiguity parameters were allowed there with the apprehension that unitarity might be threatened like the chiral generation of the Schwinger model. In the present work it has been shown that no counter term containing the regularization ambiguity is needed for this model to be physically sensible. So the chiral Thirring–Wess model is studied here without the presence of any ambiguity parameter and it has been found that the model not only remains exactly solvable but also does not lose the unitarity like the chiral generation of the Schwinger model. The phase space structure and the theoretical spectrum of this new model have been determined in the present scenario. The theoretical spectrum is found to contain a massive boson with ambiguity free mass and a massless boson

Flipped SU(5) from manifold compactification of the ten-dimensional heterotic string

Energy Technology Data Exchange (ETDEWEB)

Campbell, B.A.; Ellis, J.; Hagelin, J.S.; Ticciati, R.; Nanopoulos, D.V.

1987-11-19

We show that a recently proposed flipped SU(5) x U(1) GUT cannot be obtained from a conventional SO(10) GUT, nor from the heterotic string by Hosotani gauge symmetry breaking of E/sub 6/ on a manifold with (2,2) world-sheet supersymmetry. It can in principle be obtained by Hosotani gauge symmetry breaking of SO(10) on a manifold with (1,2) world-sheet supersymmetry. We identify the topological conditions under which the required chiral matter generations, Higgs multiplets, and gauge singlet fields can be light. In particular we show that non-perturbative world-sheet instanton effects neither destabilize the manifold nor give masses to the gauge singlets. The required Yukawa couplings are not forbidden by any known selection rules.

SO(2N) and SU(N) gauge theories

OpenAIRE

Lau, Richard; Teper, Michael

2013-01-01

We present our preliminary results of SO(2N) gauge theories, approaching the large-N limit. SO(2N) theories may help us to understand QCD at finite chemical potential since there is an orbifold equivalence between SO(2N) and SU(N) gauge theories at large-N and SO(2N) theories do not have the sign problem present in QCD. We consider the string tensions, mass spectra, and deconfinement temperatures in the SO(2N) pure gauge theories in 2+1 dimensions, comparing them to their corresponding SU(N) ...

Broadband reflection of polymer-stabilized chiral nematic liquid crystals induced by a chiral azobenzene compound.

Science.gov (United States)

Chen, Xingwu; Wang, Ling; Chen, Yinjie; Li, Chenyue; Hou, Guoyan; Liu, Xin; Zhang, Xiaoguang; He, Wanli; Yang, Huai

2014-01-21

A chiral nematic liquid crystal-photopolymerizable monomer-chiral azobenzene compound composite was prepared and then polymerized under UV irradiation. The reflection wavelength of the composite can be extended to cover the 1000-2400 nm range and also be adjusted to the visible light region by controlling the concentration of chiral compounds.