133Xe release during post-irradiation annealing of uranium metal in the presence of a constant volume of air Pt. 1

International Nuclear Information System (INIS)

Marei, S.A.; El-Garhy, M.; El-Bayoumy, S.; Muenze, R.; Hladik, O.

1978-01-01

The fractional release of 133 Xe at different temperatures was studied as a function of time in the presence of air during post-irradiation annealing of uranium metal. The relation between the fractional release and tsup(1/2) was found to be irregular. There is an initial step in the annealing curves (at the temperature range of 400-710 deg C) which decreases by increasing temperature and totally disappears at the high temperature of 800-1000 deg C. The initial step was found to be due to the surface oxidation of uranium metal. The other two parts of the release curves are normal for 133 Xe release from uranium metal. Since in this work the irradiation temperature is low ( 133 Xe. (T.G.)

Effect of Fe and C doping on the thermal release of helium from aluminum

International Nuclear Information System (INIS)

Xiang, X.; Chen, C.A.; Liu, K.Z.; Peng, L.X.; Rao, Y.C.

2010-01-01

The effect of Fe and C doping on the thermal release of helium from Al implanted with 10 keV, 4.0 x 10 21 ion/m 2 He at room temperature (RT) has been investigated by thermal helium desorption spectrometry (THDS) and transmission electron microscope (TEM). The results show that Fe and C doping have significant impact on the release of helium from Al and the extent depends on the doping fluence. Proper fluence of Fe and C doping would lead to the retardation of the release of helium from Al, while excessive fluence of Fe and C doping would result in more desorption peaks and the release of helium in lower temperature ranges. Fe and C doping have different influence on the release of helium from Al, and the difference is related with the secondary phases forming in the samples.

Formation of oxygen related donors in step-annealed CZ–silicon

Indian Academy of Sciences (India)

The effect of step-annealing necessitated by the difficulties being faced in the long duration annealing treatments to be given to CZ–silicon has been studied. One pre-anneal of 10 h followed by annealing of 10 h causes a decrease in the absorption coefficient for carbon (c). Oxygen and carbon both accelerate thermal ...

Investigation of helium-induced embrittlement

International Nuclear Information System (INIS)

Sabelova, V.; Slugen, V.; Krsjak, V.

2014-01-01

In this work, the hardness of Fe-9%(wt.) Cr binary alloy implanted by helium ions up to 1000 nm was investigated. The implantations were performed using linear accelerator at temperatures below 80 grad C. Isochronal annealing up to 700 grad C with the step of 100 grad C was applied on the helium implanted samples in order to investigate helium induced embrittlement of material. Obtained results were compared with theoretical calculations of dpa profiles. Due to the results, the nano-hardness technique results to be an appropriate approach to the hardness determination of thin layers of implanted alloys. Both, experimental and theoretical calculation techniques (SRIM) show significant correlation of measured results of induced defects. (authors)

Helium mobility in advanced nuclear ceramics

International Nuclear Information System (INIS)

Agarwal, Shradha

2014-01-01

1100 and 1600 C. The values of the corresponding thermal activation energy are in the range 1 - 2.5 eV; - surface blistering only occurs for ZrC 0.92 ; - whatever the helium implantation dose, helium bubbles are formed near the ion end of range. Nevertheless, for as implanted samples, the bubble size remains less than the lateral resolution of TEM (≤ 1 nm); - when the annealing temperature increases, the average bubble size increases due to vacancy absorption while the density does not seem to vary. The activation energy corresponding to this mechanism has been evaluated around 0.40 eV; - after a high temperature thermal annealing (T ≥ 1500 C), the internal pressure of helium bubbles tends to reach the equilibrium value given by the classical law P = 2 γ/r with γ the surface energy and r the bubble radius; - near grain boundaries, the average helium bubble size tends to be larger and their density lower than within the grains; - when the helium implantation fluence decreases from 5 * 10 16 to 2.3 * 10 15 ions/cm 2 , helium release is quasi negligible for TiN 0.96 even after a 1600 C annealing treatment. Moreover, helium was shown to diffuse on a larger range. (author) [fr

Tritium and helium release from beryllium pebbles neutron-irradiated up to 230appm tritium and 3000appm helium

Directory of Open Access Journals (Sweden)

Vladimir Chakin

2016-12-01

Full Text Available Study of tritium and helium release from beryllium pebbles with diameters of 0.5 and 1mm after high-dose neutron irradiation at temperatures of 686–968K was performed. The release rate always has a single peak, and the peak temperatures at heating rates of 0.017K/s and 0.117K/s lie in the range of 1100–1350K for both tritium and helium release. The total tritium release from 1mm pebbles decreases considerably by increasing the irradiation temperature. The total tritium release from 0.5mm pebbles is less than that from 1mm pebbles and remains constant regardless of the irradiation temperature. At high irradiation temperatures, open channels are formed which contribute to the enhanced tritium release.

Effect of Annealing on Microstructures and Hardening of Helium-Hydrogen-Implanted Sequentially Vanadium Alloys

Science.gov (United States)

Jiang, Shaoning; Wang, Zhiming

2018-03-01

The effect of post-irradiation annealing on the microstructures and mechanical properties of V-4Cr-4Ti alloys was studied. Helium-hydrogen-irradiated sequentially V-4Cr-4Ti alloys at room temperature (RT) were undergone post-irradiation annealing at 450 °C over periods of up to 30 h. These samples were carried out by high-resolution transmission electron microscopy (HRTEM) observation and nanoindentation test. With the holding time, large amounts of point defects produced during irradiation at RT accumulated into large dislocation loops and then dislocation nets which promoted the irradiation hardening. Meanwhile, bubbles appeared. As annealing time extended, these bubbles grew up and merged, and finally broke up. In the process, the size of bubbles increased and the number density decreased. Microstructural changes due to post-irradiation annealing corresponded to the change of hardening. Dislocations and bubbles are co-contributed to irradiation hardening. With the holding time up to 30 h, the recovery of hardening is not obvious. The phenomenon was discussed by dispersed barrier hardening model and Friedel-Kroupa-Hirsch relationship.

Optical annealing of CaF2:Mn for cooled optically stimulated luminescence

International Nuclear Information System (INIS)

Miller, S.D.; Stahl, K.A.; Endres, G.W.R.; McDonald, J.C.

1989-01-01

Optical annealing of the cooled optically stimulated luminescence in CaF 2 :Mn at room temperature has been demonstrated. The laser of choice for optical annealing of CaF 2 : Mn is a 326 nm helium-cadmium ultraviolet laser. A complete cycle of readout and annealing of the CaF 2 :Mn cooled optically stimulated dosemeters can now be accomplished without heating the dosemeters above room temperature. This annealing work represents the next step toward creating a proton-recoil-based fast neutron dosimetry system based on the cooled optically stimulated luminescence technique. (author)

Preservation and release dose of helium implanted in nanocrystal titanium film

International Nuclear Information System (INIS)

Long Xinggui; Luo Shunzhong; Peng Shuming; Zheng Sixiao; Liu Zhongyang; Wang Peilu; Liao Xiaodong; Liu Ning

2003-01-01

Helium concentration profile, preservation dose and release rate from a nanocrystal titanium film implanted with helium at an energy of 100 keV and dose of 2.2 x 10 18 cm -2 are measured by proton Rutherford backscattering technique in a range from room temperature to 400 degree C. The implanted helium may be stably preserved up to the 68 percent after keeping a long time of 210 d in the nanocrystal titanium film at the room temperature environment, and the He-Ti atomic ratio reaches to 52.6%. When the temperature of specimen increases to 100 degree C, the helium concentration can be preserved to 89.6% of the keeping helium dose at room temperature and He-Ti atomic ratio reaches 44%. Even if the specimen temperature up to 400 degree C, the helium concentration still can be preserved to 32.6% of the keeping helium dose at room temperature and the He-Ti atomic ratio is 17.1%. Possible mechanism of helium effectively preserved in the nanocrystal titanium film is discussed based on the energy stability viewpoint

Helium generation and diffusion in graphite and some carbides

International Nuclear Information System (INIS)

Holt, J.B.; Guinan, M.W.; Hosmer, D.W.; Condit, R.H.; Borg, R.J.

1976-01-01

The cross section for the generation of helium in neutron irradiated carbon was found to be 654 mb at 14.4 MeV and 744 mb at 14.9 MeV. Extrapolating to 14.1 MeV (the fusion reactor spectrum) gives 615 mb. The diffusion of helium in dense polycrystalline graphite and in pyrographite was measured and found to be D = 7.2 x 10 -7 m 2 s -1 exp (-80 kJ/RT). It is assumed that diffusion is primarily in the basal plane direction in crystals of the graphite. In polycrystalline graphite the path length is a factor of √2 longer than the measured distance due to the random orientation mismatch between successive grains. Isochronal anneals (measured helium release as the specimen is steadily heated) were run and maximum release rates were found at 200 0 C in polycrystalline graphite, 1000 0 C in pyrographite, 1350 0 C in boron carbide, and 1350 0 and 2400 0 C (two peaks) in silicon carbide. It is concluded that in these candidates for curtain materials in fusion reactors the helium releases can probably occur without bubble formation in graphites, may occur in boron carbide, but will probably cause bubble formation in silicon carbide. 7 figures

Helium behaviour in implanted boron carbide

Directory of Open Access Journals (Sweden)

Motte Vianney

2015-01-01

Full Text Available When boron carbide is used as a neutron absorber in nuclear power plants, large quantities of helium are produced. To simulate the gas behaviour, helium implantations were carried out in boron carbide. The samples were then annealed up to 1500 °C in order to observe the influence of temperature and duration of annealing. The determination of the helium diffusion coefficient was carried out using the 3He(d,p4He nuclear reaction (NRA method. From the evolution of the width of implanted 3He helium profiles (fluence 1 × 1015/cm2, 3 MeV corresponding to a maximum helium concentration of about 1020/cm3 as a function of annealing temperatures, an Arrhenius diagram was plotted and an apparent diffusion coefficient was deduced (Ea = 0.52 ± 0.11 eV/atom. The dynamic of helium clusters was observed by transmission electron microscopy (TEM of samples implanted with 1.5 × 1016/cm2, 2.8 to 3 MeV 4He ions, leading to an implanted slab about 1 μm wide with a maximum helium concentration of about 1021/cm3. After annealing at 900 °C and 1100 °C, small (5–20 nm flat oriented bubbles appeared in the grain, then at the grain boundaries. At 1500 °C, due to long-range diffusion, intra-granular bubbles were no longer observed; helium segregates at the grain boundaries, either as bubbles or inducing grain boundaries opening.

Double-step annealing and ambient effects on phosphorus implanted emitters in silicon

International Nuclear Information System (INIS)

Koji, T.; Tseng, W.F.; Mayer, J.W.; Suganuma, T.

1979-01-01

Emitters of npn silicon bipolar transistors have been made by a phosphorus implantation at 50 keV P + to a dose of 1 x 10 16 cm -2 . This was followed by high temperature processes to reduce lattice disorder, to drive-in the phosphorus atoms, and to form oxide layers. The first process step was carried out by using single- and double-step anneals in various ambients (dry N 2 , dry 0 2 and steam) while the drive-in and oxidation steps were common for all structures. Electrical measurements on emitter/base leakage current, low frequency (popcorn) noise and current gain showed that the annealing ambient had a major influence. The transistors with implanted emitters annealed in a dry N 2 ambient are comparable to commercial ones with thermally-diffused emitters. Transmission electron microscopy observations on samples annealed in steam ambients revealed dislocations extending into the sidewall of the emitter/base junction. This sidewell penetration of dislocations is the main origin of the degradation of the emitter/base junction characteristics. (author)

Step dynamics and terrace-width distribution on flame-annealed gold films: The effect of step-step interaction

International Nuclear Information System (INIS)

Shimoni, Nira; Ayal, Shai; Millo, Oded

2000-01-01

Dynamics of atomic steps and the terrace-width distribution within step bunches on flame-annealed gold films are studied using scanning tunneling microscopy. The distribution is narrower than commonly observed for vicinal planes and has a Gaussian shape, indicating a short-range repulsive interaction between the steps, with an apparently large interaction constant. The dynamics of the atomic steps, on the other hand, appear to be influenced, in addition to these short-range interactions, also by a longer-range attraction of steps towards step bunches. Both types of interactions promote self-ordering of terrace structures on the surface. When current is driven through the films a step-fingering instability sets in, reminiscent of the Bales-Zangwill instability

Helium bubble formation and retention in Cu-Nb nanocomposites

International Nuclear Information System (INIS)

Dunn, A.Y.; McPhie, M.G.; Capolungo, L.; Martinez, E; Cherkaoui, M.

2013-01-01

A spatially dependent rate theory model for helium migration, clustering, and trapping on interfaces between Cu and Nb layers is introduced to predict the evolution of the concentrations of He clusters of various sizes during implantation and early annealing. Migration and binding energies of point defects and small clusters in bulk Cu and Nb are found using conjugate gradient minimization and the nudged elastic band method. The model is implemented in a three-dimensional framework and used to predict the relationship between helium bubble formation and the nano-composite microstructure, including interfacial free volume, grain size, and layer thickness. Interstitial and vacancy-like migration of helium is considered. The effects of changing layer thickness and interfacial misfit dislocation density on the threshold for helium bubble nucleation are found to match experiments. Accelerated helium release due to interfaces and grain boundaries is shown to occur only when diffusion rates on interfaces and grain boundaries are greatly increased relative to the bulk material.

Helium implanted AlHf as studied by 181 Ta TDPAC

Indian Academy of Sciences (India)

Measurements on helium implanted sample indicate the binding of helium associated defects by Hf solute clusters. Isochronal annealing measurements indicate the dissociation of the helium implantation induced defects from Hf solute clusters for annealing treatments beyond 650 K. On comparison of the present results ...

Effect of alpha self irradiation on helium migration in (U,Pu)O2 samples

International Nuclear Information System (INIS)

Pipon, Yves; Roudil, Daniele; Jegou, Christophe; Khodja, Hicham; Raepsaet, Caroline

2008-01-01

The helium behavior and its migration mechanisms in nuclear spent fuel (UOX and MOX) significantly impact the possible evolution of the spent fuel matrix in a closed system during interim storage or during a disposal repository. An experimental study has been conducted on (U,Pu)O 2 samples in order to investigate the impact of defects created by alpha decay on helium diffusion. One large part is devoted to thermal atomic diffusion and applied on 3 He implanted samples, annealed at 850 and 1000 deg. C. The He profiles, as implanted and after annealing, were investigated with the 3 He(d,p) 4 He nuclear reaction. Another part deals with the thermal release of 4 He amassed in the samples. The measured thermal diffusion coefficients are compared with previously published values, thereby highlighting the effect of the alpha self-irradiation on helium behavior. (authors)

Study and simulation of the behaviour under irradiation of helium in uranium dioxide; Etude et modelisation du comportement sous irradiation de l'helium dans le dioxyde d'uranium

Energy Technology Data Exchange (ETDEWEB)

Martin, G

2007-06-15

Large quantities of helium are produced from {alpha}-decay of actinides in nuclear fuels during its in-pile operating and its storage. It is important to understand the behaviour of helium in these matrix in order to well simulate the evolution and the resistance of the fuel element. During this thesis, we have used nuclear reaction analyses (NRA) to follow the evolution of the helium implanted in polycrystalline and monocrystalline uranium dioxide (UO{sub 2}). An experimental rig was developed to follow the on-line helium release in UO{sub 2} and the evolution of {sup 3}He profiles as a function of annealing temperature. An automated procedure taking into account the evolution of the depth resolution was developed. Analyses performed with a nuclear microprobe allowed to characterise the spatial distribution of helium at the grain scale and to study the influence of the sample microstructure on the helium migration. This work put into evidence the particular role of grain boundaries and irradiation defects in the helium release process. The analyse of experimental results with a diffusion model corroborates these interpretations. It allowed to determine quantitatively physical properties that characterise the helium behaviour in uranium dioxide (diffusion coefficient, activation energy..). (author)

Tailoring structures through two-step annealing process in nanostructured aluminum produced by accumulative roll-bonding

DEFF Research Database (Denmark)

Kamikawa, Naoya; Huang, Xiaoxu; Hansen, Niels

2008-01-01

temperature before annealing at high temperature. By this two-step process, the structure is homogenized and the stored energy is reduced significantly during the first annealing step. As an example, high-purity aluminum has been deformed to a total reduction of 98.4% (equivalent strain of 4.......8) by accumulative roll-bonding at room temperature. Isochronal annealing for 0.5 h of the deformed samples shows the occurrence of recrystallization at 200 °C and above. However, when introducing an annealing step for 6 h at 175 °C, no significant recrystallization is observed and relatively homogeneous structures...... are obtained when the samples afterwards are annealed at higher temperatures up to 300 °C. To underpin these observations, the structural evolution has been characterized by transmission electron microscopy, showing that significant annihilation of high-angle boundaries, low-angle dislocation boundaries...

A preliminary investigation of the diffusion of helium in zirconium

International Nuclear Information System (INIS)

Reed, D.J.; Faulkner, D.

1976-10-01

The out-diffusion of helium, introduced into polycrystalline zirconium at room temperature by ion-implantation at 100 keV to a peak concentration of 1ppm, was found to occur in two principal regions. Two evolution rate maxima, obtained during post-implantation target annealing at 2.6 0 K s -1 , were observed in close proximity at 330 0 C (0.28 Tsub(m)) and 450 0 C (0.34 Tsub(m)) comprising the principal stage, with a subordinate stage occurring at 600 0 C (0.4 Tsub(m)). These data were compared with similar maxima observed in nickel at 600 0 C (0.5 Tsub(m)) and 850 0 C (0.65 Tsub(m)). The results imply a high helium diffusivity over the 0.5 mm experimental range in comparison with nickel, and an exceptionally high diffusivity taking into account the melting temperature of zirconium. On the basis of a diffusion model proposed earlier for nickel, activation energies of 1.37 and 1.66 eV have been assigned to the principal maxima at 330 0 C and 450 0 C, and a value of 2.41 eV to the maximum at 600 0 C. The long range diffusivity of helium manifested by its thermal evolution from uniformly filled 120 mm thick foils was found to be much lower than that measured for short range migration. An empirical activation energy of approximately 3 eV was estimated for this process, thought to be a result of bubble migration. The release of helium from zirconium has been explained by comparison with nickel data. The proposed substitutional de-trapping mechanism has been invoked to account for the principal evolution rate maxima at 330 0 C. Helium release observed at 600 0 C has been explained by the annealing of radiation damage, so allowing gas trapped therein to be evolved. (author)

Modelling the behaviour of intergranular fission gas during out-of-pile annealing

International Nuclear Information System (INIS)

Valin, S.; Mocellin, A.; Eminet, G.; Ravel, S.

2002-01-01

Standard UO 2 fuel irradiated in a commercial PWR (burn-up: 14 GWd/t u ) and hyper-stoichiometric large-grained fuel irradiated in an experimental reactor (burn-up: 9 GWd/t u ) were submitted to out-of-pile annealing treatments under sweeping helium. The 85 Kr release was continuously monitored during the annealing experiments, with temperatures ranging from 1 400 to 1 760 deg C. The burst release was not systematically observed during the heating ramp but did sometimes appear during the isothermal period following the ramp. A model based on microstructural observations was developed to explain the experimental results. The release was shown to depend on gas diffusion towards grain boundaries and on temporary gas trapping in grain boundary bubbles. The gas saturation on grain boundaries, leading to release, depends on their crystallographic orientation. (authors)

Thermal desorption of deuterium from Be, and Be with helium bubbles

Energy Technology Data Exchange (ETDEWEB)

Fedorov, A.V.; Van Veen, A.; Busker, G.J. [Delft Univ. of Technology (Netherlands). Interfaculty Reactor Inst.

1998-01-01

Deuterium desorption measurements carried out on a single-crystalline beryllium sample are presented. Deuterium ions were implanted at room temperature at the energy of 0.7 and 1.2 keV up to doses ranging from 10{sup 19} to 3.6 x 10{sup 21} m{sup -2}. In order to eliminate the influence of the beryllium-oxide surface layer, before the implantation the surface of the sample was cleaned by argon sputtering. After the implantation the sample was annealed up to 1200 K at a constant rate of 10 K/s. Deuterium released from the sample was monitored by a calibrated quadrupole mass-spectrometer. The desorption spectra revealed two different contributions. One is a well defined and very narrow peak centered around 450 K. This peak is observed only at high implantation doses > 7.8 x 10{sup 20} m{sup -2}, which is close to the deuterium saturation limit of 0.3 D/Be and is related to deuterium release from blisters or interconnected bubbles. The activation energy of 1.1 eV and the threshold implantation dose are consistent with the values reported in literature. The second contribution in the release spectra is found in the temperature range from 600 to 900 K and is present throughout the whole range of the implantation doses. The activation energies corresponding to this release lie in the range between 1.8 and 2.5 eV and are ascribed to the release from deuterium-vacancy type of defects. In a number of experiments the deuterium implantation was preceded by helium implantation followed by partial annealing to create helium bubbles. The resulting deuterium desorption spectra indicate that deuterium detrapping from helium bubbles is characterized by an activation energy of 2.7 eV. (author)

Experimental studies on helium release and stratification within the AIHMS facility

International Nuclear Information System (INIS)

Prabhakar, Aneesh; Agrawal, Nilesh; Raghavan, V.; Das, Sarit K.

2015-01-01

Hydrogen is generated during core meltdown accidents in nuclear power plants. The study of hydrogen release and mixing within the containment is an important area of safety research. An experimental setup called the AERB-IIT Madras Hydrogen Mixing Studies (AIHMS) facility is setup at IIT Madras to study the distribution of helium (an inert surrogate to hydrogen) subsequent to release as a jet. The present paper gives details of the design, fabrication and instrumentation of the AIHMS facility. It then compares the features of the facility with respect to other facilities existing for hydrogen mitigation studies. Then it gives details of the experiments on concentration build-up studies as a result of injection of gases (air and helium) performed in this experimental facility. (author)

Sequential multiple-step europium ion implantation and annealing of GaN

KAUST Repository

Miranda, S. M C; Edwards, Paul R.; O'Donnell, Kevin Peter; Boćkowski, Michał X.; Alves, Eduardo Jorge; Roqan, Iman S.; Vantomme, André ; Lorenz, Katharina

2014-01-01

Sequential multiple Eu ion implantations at low fluence (1×1013 cm-2 at 300 keV) and subsequent rapid thermal annealing (RTA) steps (30 s at 1000 °C or 1100 °C) were performed on high quality nominally undoped GaN films grown by metal organic chemical vapour deposition (MOCVD) and medium quality GaN:Mg grown by hydride vapour phase epitaxy (HVPE). Compared to samples implanted in a single step, multiple implantation/annealing shows only marginal structural improvement for the MOCVD samples, but a significant improvement of crystal quality and optical activation of Eu was achieved in the HVPE films. This improvement is attributed to the lower crystalline quality of the starting material, which probably enhances the diffusion of defects and acts to facilitate the annealing of implantation damage and the effective incorporation of the Eu ions in the crystal structure. Optical activation of Eu3+ ions in the HVPE samples was further improved by high temperature and high pressure annealing (HTHP) up to 1400 °C. After HTHP annealing the main room temperature cathodo- and photoluminescence line in Mg-doped samples lies at ∼ 619 nm, characteristic of a known Mg-related Eu3+ centre, while after RTA treatment the dominant line lies at ∼ 622 nm, typical for undoped GaN:Eu. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Sequential multiple-step europium ion implantation and annealing of GaN

KAUST Repository

Miranda, S. M C

2014-01-20

Sequential multiple Eu ion implantations at low fluence (1×1013 cm-2 at 300 keV) and subsequent rapid thermal annealing (RTA) steps (30 s at 1000 °C or 1100 °C) were performed on high quality nominally undoped GaN films grown by metal organic chemical vapour deposition (MOCVD) and medium quality GaN:Mg grown by hydride vapour phase epitaxy (HVPE). Compared to samples implanted in a single step, multiple implantation/annealing shows only marginal structural improvement for the MOCVD samples, but a significant improvement of crystal quality and optical activation of Eu was achieved in the HVPE films. This improvement is attributed to the lower crystalline quality of the starting material, which probably enhances the diffusion of defects and acts to facilitate the annealing of implantation damage and the effective incorporation of the Eu ions in the crystal structure. Optical activation of Eu3+ ions in the HVPE samples was further improved by high temperature and high pressure annealing (HTHP) up to 1400 °C. After HTHP annealing the main room temperature cathodo- and photoluminescence line in Mg-doped samples lies at ∼ 619 nm, characteristic of a known Mg-related Eu3+ centre, while after RTA treatment the dominant line lies at ∼ 622 nm, typical for undoped GaN:Eu. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

A two-step annealing process for enhancing the ferroelectric properties of poly(vinylidene fluoride) (PVDF) devices

KAUST Repository

Park, Jihoon; Kurra, Narendra; AlMadhoun, M. N.; Odeh, Ihab N.; Alshareef, Husam N.

2015-01-01

We report a simple two-step annealing scheme for the fabrication of stable non-volatile memory devices employing poly(vinylidene fluoride) (PVDF) polymer thin-films. The proposed two-step annealing scheme comprises the crystallization

Modulation of drug release kinetics of shellac-based matrix tablets by in-situ polymerization through annealing process.

Science.gov (United States)

Limmatvapirat, Sontaya; Limmatvapirat, Chutima; Puttipipatkhachorn, Satit; Nunthanid, Jurairat; Luangtana-anan, Manee; Sriamornsak, Pornsak

2008-08-01

A new oral-controlled release matrix tablet based on shellac polymer was designed and developed, using metronidazole (MZ) as a model drug. The shellac-based matrix tablets were prepared by wet granulation using different amounts of shellac and lactose. The effect of annealing temperature and pH of medium on drug release from matrix tablets was investigated. The increased amount of shellac and increased annealing temperature significantly affected the physical properties (i.e., tablet hardness and tablet disintegration) and MZ release from the matrix tablets. The in-situ polymerization played a major role on the changes in shellac properties during annealing process. Though the shellac did not dissolve in acid medium, the MZ release in 0.1N HCl was faster than in pH 7.3 buffer, resulting from a higher solubility of MZ in acid medium. The modulation of MZ release kinetics from shellac-based matrix tablets could be accomplished by varying the amount of shellac or annealing temperature. The release kinetics was shifted from relaxation-controlled release to diffusion-controlled release when the amount of shellac or the annealing temperature was increased.

Study of CdTe quantum dots grown using a two-step annealing method

Science.gov (United States)

Sharma, Kriti; Pandey, Praveen K.; Nagpal, Swati; Bhatnagar, P. K.; Mathur, P. C.

2006-02-01

High size dispersion, large average radius of quantum dot and low-volume ratio has been a major hurdle in the development of quantum dot based devices. In the present paper, we have grown CdTe quantum dots in a borosilicate glass matrix using a two-step annealing method. Results of optical characterization and the theoretical model of absorption spectra have shown that quantum dots grown using two-step annealing have lower average radius, lesser size dispersion, higher volume ratio and higher decrease in bulk free energy as compared to quantum dots grown conventionally.

Damage, trapping and desorption at the implantation of helium and deuterium in graphite, diamond and silicon carbide

International Nuclear Information System (INIS)

Lopez, G.A.R.

1995-07-01

The production, thermal stability and structure of ion induced defects have been studied by Rutherford backscattering in channeling geometry for the implantation of helium and deuterium in graphite, diamond and silicon carbide with energies of 8 and 20 keV. At the implantation of deuterium and helium ions more defects were measured in graphite than in diamond or silicon carbide at equal experimental conditions. This is due to increased backscattering in graphite, which is caused by the splitting and tilting of crystallites and a local reordering of lattice atoms around defects. At 300 K, Helium produces more defects in all three materials than deuterium with equal depth distribution of defects. The ratio of the defects produced by helium and deuterium agrees very well with the corresponding ratio of the energy deposited in nuclear collisions. In graphite, only small concentrations of deuterium induced defects anneal below 800 K, while in diamond small concentrations of deuterium as well as of helium induced defects anneal mostly below 800 K. This annealing behavior is considered to be due to recombination of point defects. The buildup of helium and deuterium in graphite is different. The trapping of deuterium proceeds until saturation is reached, while in the case of helium trapping is interrupted by flaking. In diamond, deuterium as well as helium are trapped almost completely until at higher fluences reemission starts and saturation is reached. Two desorption mechanisms were identified for the thermal desorption of helium from base-oriented graphite. Helium implanted at low fluences desorbs diffusing to the surface, while for the implantation of high fluences the release of helium due to blistering dominates. The desorption of deuterium from graphite and diamond shows differences. While in graphite the desorption starts already at 800 K, in diamond up to 1140 K only little desorption can be observed. These differences can be explained by the different transport

Growth process of helium bubbles in aluminium

International Nuclear Information System (INIS)

Shiraishi, Haruki; Sakairi, Hideo; Yagi, Eiichi; Karasawa, Takashi; Hashiguti, R.R.

1975-01-01

The growth process of helium bubbles in α-particle bombarded pure aluminum during isothermal anneal ranging 200 to 645 0 C and 1 to 100 hr was observed by a transmission electron microscope and the possible growth mechanisms are discussed. The effects of helium concentration and cold work were investigated. The helium bubbles are detectable only at the anneal above 550 0 C in both annealed and cold worked samples. The cold work does not cause any extra coarsening trend of bubbles. The observed types of bubble distribution in the grain interior are divided into two categories, irrespective of helium concentration and cold work; (1) the fine and uniform bubble distribution, in which case the average size is limited to about 200 A or less in diameter even at the anneal just below the melting point, and (2) the coarsened and non-uniform bubble distribution ranging 500 to 4000 A in diameter. The intermediate size bubbles are scarcely found in any cases. In the above fine bubble distribution, the increase of helium concentration by a factor of two increases the density by the same factor of two, but does not change the mean size of bubbles. Corresponding to the above two characteristic bubble distributions, it is concluded that two different mechanisms are operative in this experiment; (1) the growth of bubbles by the Brownian motion, in which the growth rate of bubbles is decreased to almost zero by bubble faceting and this results in the bubble size constancy during the prolonged annealing, and (2) the growth of bubbles by the grain boundary sweep-out mechanism, by which the abrupt coarsening of bubbles is caused. The lack of existence of the intermediate size bubbles is explained in this way. (auth.)

Cooling performance of helium-gas/water coolers in HENDEL

International Nuclear Information System (INIS)

Inagaki, Yoshiyuki; Takada, Shoji; Hayashi, Haruyoshi; Kobayashi, Toshiaki; Ohta, Yukimaru; Shimomura, Hiroaki; Miyamoto, Yoshiaki

1994-01-01

The helium engineering demonstration loop (HENDEL) has four helium-gas/water coolers where the cooling water flows in the tubes and helium gas on the shell side. Their cooling performance was studied using the operational data from 1982 to 1991. The heat transfer of helium gas on the shell was obtained for segmental and step-up baffle type coolers. Also, the change with operation time was investigated. The cooling performance was lowered by the graphite powder released from the graphite components for several thousand hours and thereafter recovered because the graphite powder from the components was reduced and the powder in the cooler shell was blown off during the operation. (orig.)

Behavior of beryllium pebbles under irradiation

Energy Technology Data Exchange (ETDEWEB)

Dalle-Donne, M.; Scaffidi-Argentina, F. [Forschungszentrum Karlsruhe GmbH Technik und Umwelt (Germany). Inst. fuer Neutronenphysik und Reactortechnik; Baldwin, D.L.; Gelles, D.S.; Greenwood, L.R.; Kawamura, H.; Oliver, B.M.

1998-01-01

Beryllium pebbles are being considered in fusion reactor blanket designs as neutron multiplier. An example is the European `Helium Cooled Pebble Bed Blanket.` Several forms of beryllium pebbles are commercially available but little is known about these forms in response to fast neutron irradiation. Commercially available beryllium pebbles have been irradiated to approximately 1.3 x 10{sup 22} n/cm{sup 2} (E>1 MeV) at 390degC. Pebbles 1-mm in diameter manufactured by Brush Wellman, USA and by Nippon Gaishi Company, Japan, and 3-mm pebbles manufactured by Brush Wellman were included. All were irradiated in the below-core area of the Experimental Breeder Reactor-II in Idaho Falls, USA, in molybdenum alloy capsules containing helium. Post-irradiation results are presented on density change measurements, tritium release by assay, stepped-temperature anneal, and thermal ramp desorption tests, and helium release by assay and stepped-temperature anneal measurements, for Be pebbles from two manufacturing methods, and with two specimen diameters. The experimental results on density change and tritium and helium release are compared with the predictions of the code ANFIBE. (author)

Effect of two-step intercritical annealing on microstructure and mechanical properties of hot-rolled medium manganese TRIP steel containing δ-ferrite

International Nuclear Information System (INIS)

Xu, Yun-bo; Hu, Zhi-ping; Zou, Ying; Tan, Xiao-dong; Han, Ding-ting; Chen, Shu-qing; Ma, De-gang; Misra, R.D.K.

2017-01-01

The microstructure-properties relationship, work-hardening behavior and retained austenite stability have been systematically investigated in a hot-rolled medium manganese transformation-induced-plasticity (TRIP) steel containing δ-ferrite subjected to one-step and two-step intercritical annealing. The steel exhibited tensile strength of 752 MPa and total elongation of 52.7% for one-step intercritical annealing at 740 °C, tensile strength of 954 MPa and total elongation of 39.2% in the case of intercritical quenching at 800 °C and annealing at 740 °C. The austenite obtained by two-step annealing mostly consists of refined lath structures and increased fraction of block-type particles existing at various kinds of sites, which is highly distinguished from those characterized by long lath morphology and small amounts of granular shape in one-step annealed samples. In spite of a higher C and Mn content in austenite and finer austenite laths, two-step annealing can lead to an active and continuous TRIP effect provided by a mixed blocky and lath-type austenitic structure with lower stability, contributing to a higher UTS. In contrast, one-step annealing gave rise to a less active but sustained TRIP effect given by the dominant lath-like austenite having higher stability, leading to a very high elongation. The further precipitation of vanadium carbides and the presence of both dislocation substructure and fine equiaxed grain in ferrite matrix facilitate the increase of yield strength after double annealing. - Highlights: • A novel two-step process was applied to a hot-rolled Fe-0.2C-6.5Mn-3Al steel. • The interplay between different microstructures and mechanical properties was studied. • Two-step annealing led to an active and continuous TRIP. • An outstanding combination of strength of 954 MPa and elongation of 39.2% was obtained.

Effect of two-step intercritical annealing on microstructure and mechanical properties of hot-rolled medium manganese TRIP steel containing δ-ferrite

Energy Technology Data Exchange (ETDEWEB)

Xu, Yun-bo [State Key Laboratory of Rolling and Automation, Northeastern University, Shenyang 110819, People' s Republic China (China); Hu, Zhi-ping, E-mail: huzhiping900401@126.com [State Key Laboratory of Rolling and Automation, Northeastern University, Shenyang 110819, People' s Republic China (China); Zou, Ying; Tan, Xiao-dong; Han, Ding-ting; Chen, Shu-qing [State Key Laboratory of Rolling and Automation, Northeastern University, Shenyang 110819, People' s Republic China (China); Ma, De-gang [Tangshan Iron and Steel Company, Tangshan 063000, People' s Republic China (China); Misra, R.D.K. [Laboratory for Excellence in Advanced Steel Research, Department of Metallurgical, Materials and Biomedical Engineering, University of Texas at El Paso, TX 79968 (United States)

2017-03-14

The microstructure-properties relationship, work-hardening behavior and retained austenite stability have been systematically investigated in a hot-rolled medium manganese transformation-induced-plasticity (TRIP) steel containing δ-ferrite subjected to one-step and two-step intercritical annealing. The steel exhibited tensile strength of 752 MPa and total elongation of 52.7% for one-step intercritical annealing at 740 °C, tensile strength of 954 MPa and total elongation of 39.2% in the case of intercritical quenching at 800 °C and annealing at 740 °C. The austenite obtained by two-step annealing mostly consists of refined lath structures and increased fraction of block-type particles existing at various kinds of sites, which is highly distinguished from those characterized by long lath morphology and small amounts of granular shape in one-step annealed samples. In spite of a higher C and Mn content in austenite and finer austenite laths, two-step annealing can lead to an active and continuous TRIP effect provided by a mixed blocky and lath-type austenitic structure with lower stability, contributing to a higher UTS. In contrast, one-step annealing gave rise to a less active but sustained TRIP effect given by the dominant lath-like austenite having higher stability, leading to a very high elongation. The further precipitation of vanadium carbides and the presence of both dislocation substructure and fine equiaxed grain in ferrite matrix facilitate the increase of yield strength after double annealing. - Highlights: • A novel two-step process was applied to a hot-rolled Fe-0.2C-6.5Mn-3Al steel. • The interplay between different microstructures and mechanical properties was studied. • Two-step annealing led to an active and continuous TRIP. • An outstanding combination of strength of 954 MPa and elongation of 39.2% was obtained.

A two-step annealing process for enhancing the ferroelectric properties of poly(vinylidene fluoride) (PVDF) devices

KAUST Repository

Park, Jihoon

2015-01-01

We report a simple two-step annealing scheme for the fabrication of stable non-volatile memory devices employing poly(vinylidene fluoride) (PVDF) polymer thin-films. The proposed two-step annealing scheme comprises the crystallization of the ferroelectric gamma-phase during the first step and enhancement of the PVDF film dense morphology during the second step. Moreover, when we extended the processing time of the second step, we obtained good hysteresis curves down to 1 Hz, the first such report for ferroelectric PVDF films. The PVDF films also exhibit a coercive field of 113 MV m-1 and a ferroelectric polarization of 5.4 μC cm-2. © The Royal Society of Chemistry 2015.

Efficiency enhancement of the MAPbI3-xClx-based perovskite solar cell by a two-step annealing procedure

Science.gov (United States)

Huang, Jin; Wang, Minqiang; Ding, Lei; Deng, Jianping; Yao, Xi

2016-02-01

The development of a novel two-step annealing method has contributed to the significantly improved performance of the MAPbI3-xClx based perovskite solar cell (PSC). By utilizing a two-step annealing method, we obtained a high power conversion efficiency (PCE) of 12.72% with a current density (J sc) of 18.35 mA cm-2, an open circuit voltage (V oc) of 0.90 V and a fill factor (FF) of 0.71. Noticeably, the two-step annealed device shows no hysteresis and exhibits a PCE which is approximately 1.2 times greater than that of the one-step annealed device. The improvement in device efficiency is ascribed to the reduced series resistance, increased parallel resistance, better surface coverage, lower leakage current and stronger crystallization of the MAPbI3-xClx perovskite layer.

Thermal desorption of deuterium from polycrystalline nickel pre-implanted with helium

International Nuclear Information System (INIS)

Shi, S.Q.; Abramov, E.; Thompson, D.A.

1990-01-01

The thermal desorption technique has been used to study the trapping of deuterium atoms in high-purity polycrystalline nickel pre-implanted with helium for 1 x 10 19 to 5 x 10 20 ions/m 2 . The effect of post-implantation annealing at 703 K and 923 K on the desorption behavior was investigated. Measured values of the total amount of detrapped deuterium (Q T ) and helium concentration were used in a computer simulation of the desorption curve. It was found that the simulation using one or two discrete trap energies resulted in an inadequate fit between the simulated and the measured data. Both experimental and simulation results are explained using a stress-field trapping model. The effective binding energy, E b eff , was estimated to be in the range of 0.4-0.6 eV. Deuterium charging was found to stimulate a release of helium at a relatively low temperature

Depth-dependence recovery of helium-implanted 18 carats gold-silver alloy

Energy Technology Data Exchange (ETDEWEB)

Thome, T.; Grynszpan, R.I. [DCE-CTA-LOT, Arcueil (France); Lab. de Chimie Metallurgique des Terres Rares, Thiais (France); Fradin, J. [DCE-CTA-LOT, Arcueil (France); SINUMEF, Ecole Nationale Superieure d' Arts et Metiers, Paris (France); Anwand, W.; Brauer, G. [Forschungszentrum Rossendorf e.V. (FZR), Dresden (Germany)

2001-07-01

Helium diffusion in Au{sub 60}Ag{sub 40} is investigated using a variable energy positron beam. The positron diffusion length of the annealed material (66 {+-} 1 nm) is reduced after implantation of 2.2 x 10{sup 14} He ions/cm{sup 2} at 300 keV. During isochronal annealing up to 600 K, the recovery rate of the Doppler broadening lineshape parameter S strongly depends on the distance to the helium implantation peak, indicating an increase of the defect stabilization by He atoms. In contrast, for subsequent annealing, and irrespective of the depth, a maximum in S occurs at 670 K (around 0.5 T{sub m}) resulting from competing processes of growth and breaking up of helium bubbles. (orig.)

Tritium and helium behavior in irradiated beryllium

International Nuclear Information System (INIS)

Billone, M.C.; Lin, C.C.; Baldwin, D.L.

1990-11-01

Large quantities of Be (> 100 metric tons) are planned for use in the ITER blanket design to enhance tritium breeding and to act as a thermal barrier between coolant and breeder. Tritium retention/release and He-induced swelling are important issues in blanket design. The data base on tritium and helium behavior in Be is reviewed. New data on tritium retention/release and He bubble growth are presented for Be irradiated to 5 x 10 22 n(E > 1 MeV)/cm 2 at ∼75 degree C and postirradiation-annealed for 700 hours at 500 degree C. A model (diffusion/desorption) is proposed and tested against the data base to determine tritium diffusivity and the desorption rate constant. Similarly a model for He-induced swelling is developed and tested against the data base. The dependence of tritium retention and release on He content and impurities (e.g. BeO) is also explored. 11 refs., 6 figs

Efficient One-Step Fusion PCR Based on Dual-Asymmetric Primers and Two-Step Annealing

DEFF Research Database (Denmark)

Liu, Yilan; Chen, Jinjin; Thygesen, Anders

2018-01-01

Gene splicing by fusion PCR is a versatile and widely used methodology, especially in synthetic biology. We here describe a rapid method for splicing two fragments by one-round fusion PCR with a dual-asymmetric primers and two-step annealing (ODT) method. During the process, the asymmetric...... intermediate fragments were generated in the early stage. Thereafter, they were hybridized in the subsequent cycles to serve as template for the target full-length product. The process parameters such as primer ratio, elongation temperature and cycle numbers were optimized. In addition, the fusion products...

Helium behaviour in UO{sub 2} through low fluence ion implantation studies

Energy Technology Data Exchange (ETDEWEB)

Garcia, P., E-mail: philippe.garcia@cea.fr [CEA – DEN/DEC, Bât. 352, 13108 Saint-Paul-Lez-Durance Cedex (France); Gilabert, E. [Centre d’Et' udes Nucleáires de Bordeaux-Gradignan, Le Haut Vigneau, 33175 Gradignan (France); Martin, G.; Carlot, G.; Sabathier, C. [CEA – DEN/DEC, Bât. 352, 13108 Saint-Paul-Lez-Durance Cedex (France); Sauvage, T.; Desgardin, P.; Barthe, M.-F. [CNRS-CEMHTI, UPR3079, 45071 Orleáns (France)

2014-05-01

In this work we focus on experiments involving implantation of 500 keV {sup 3}He ions in sintered polycrystalline material. Samples are implanted at low fluences (∼2 ×10{sup 13} ions/cm{sup 2}) and subsequently isothermally annealed in a highly sensitive thermal desorption spectrometry (TDS) device PIAGARA (Plateforme Interdisciplinaire pour l’Analyse des GAz Rares en Aquitaine). The helium fluencies studied are two to three orders of magnitude lower than previous Nuclear Reaction Analysis (NRA) experiments carried out on identical samples implanted at identical energies. The fractional release of helium obtained in the TDS experiments is interpreted using a three-dimensional axisymmetric diffusion model which enables results to be quantitatively compared to previous NRA data. The analysis shows that helium behaviour is qualitatively independent of ion fluency over three orders of magnitude: helium diffusion appears to be strongly inhibited below 1273 K within the centre of the grains presumably as a result of helium bubble precipitation. The scenario involving diffusion at grain boundaries and in regions adjacent to them observed at higher fluencies is quantitatively confirmed at much lower doses. The main difference lies in the average width of the region in which uninhibited diffusion occurs.

Molecular dynamics and density functional simulations of tungsten nanostructure formation by helium plasma irradiation

International Nuclear Information System (INIS)

Ito, A.M.; Takayama, A.; Oda, Y.

2014-10-01

For the purposes of long-term use of tungsten diverter walls, it is necessary to suppress the surface deterioration due to the helium ash which induces the formations of helium bubbles and tungsten fuzzy nanostructures. In the present paper, the formation mechanisms of helium bubbles and tungsten fuzzy nanostructures were explained by the four-step process which is composed of the penetration process, the diffusion and agglomeration process, the helium bubble growth process and the tungsten fuzzy nanostructure formation process. The first to third step processes of the four-step process were investigated by using binary collision approximation, density functional theory and molecular dynamics, respectively. Furthermore, newly developed molecular dynamics and Monte-Carlo hybrid simulation has successfully reproduced the early formation process of tungsten fuzzy nanostructure. From these simulations, we here suggest the following key mechanisms of the formations of helium bubbles and tungsten fuzzy nanostructures: (1) By comparison between helium, neon, argon and hydrogen, the noble gas atoms can agglomerate limitlessly not only at a vacancy but also at an interstitial site. In particular, at the low incident energy, only helium atoms bring about the nucleation for helium bubble. (2) In the helium bubble growth process, the strain of the tungsten material around a helium atom is released as a dislocation loop, which is regarded as the loop punching phenomenon. (3) In the tungsten nanostructure formation process, the bursting of a helium bubble forms cavity and convexity in the surface. The helium bubbles tend to be grown and to burst at the cavity region, and then the difference of height between the cavity and convexity on the surface are enhanced. Consequently, the tungsten fuzzy nanostructure is formed. (author)

Study of helium diffusion, implanted at a cyclotron, in face-centered cubic metals: Au, Ag and Al

International Nuclear Information System (INIS)

Sciani, V.

1985-01-01

Helium in metals is produced by nuclear reactions of energetic particles. In nuclear technology the interest on helium in metals is import, due to its production by (n, α) reaction. Because helium has extremely low solubility in metals, the precipitation in the form of filled bubbles at elevated temperatures occurs, which have detrimental effects on mechanical properties and may limit the lifetime of structural components. One typical example is the high temperature embrittlement. The nucleation and growth of the bubbles strongly depends on the mobility of the helium. This work presents the study of helium diffusion in Au, Ag and Al at temperatures above room temperature. The helium created by (n, α) reactions has been simulated by homogeneous alpha particles implantation in cyclotron, at room temperature, in specimens of thicknesses between 5 and 50 μm and helium concentration between 10 -3 to 10 ppm. After implantation, the specimens were dropped in a furnace in a UHV-chamber and the diffusion was measured by observing the He-release during linear and isothermal annealings. The occurence of free diffusion was comparing the dependence of release kinetics on helium concentration, sample thickness, time and heating rate to diffusion theory and is clearly separeted from agglomeration process. The diffusion constants of helium in Au, Ag and Al follow an Arrhenius behavior, with: Au:D o =10 -1.0 cm 2 /s ΔH=1.70eV Ag:D 0 =10 -1.2 cm 2 /s ΔH=1.51eV Al:D o =10 +0.5 cm 2 /s ΔH=1.40eV. The results are compared to self-diffusion and to the diffusion of other gases in these metals. Comparison with theoretical estimates favours the vacancy mechanism for helium diffusion in Au, Ag and Al. (author) [pt

Helium retention in krypton ion pre-irradiated nanochannel W film

Science.gov (United States)

Qin, Wenjing; Ren, Feng; Zhang, Jian; Dong, Xiaonan; Feng, Yongjin; Wang, Hui; Tang, Jun; Cai, Guangxu; Wang, Yongqiang; Jiang, Changzhong

2018-02-01

Nanochannel tungsten (W) film is a promising candidate as an alternative to bulk W for use in fusion applications. In previous work it has been shown to have good radiation resistance under helium (He) irradiation. To further understand the influence of the irradiation-induced displacement cascade damage on helium retention behaviour in a fusion environment, in this work, nanochannel W film and bulk W were pre-irradiated by 800 keV Kr2+ ions to the fluence of 2.6  ×  1015 ions cm-2 and subsequently irradiated by 40 keV He+ ions to the fluence of 5  ×  1017 ions cm-2. The Kr2+ ion pre-irradiation greatly increases helium retention in the form of small clusters and retards the formation of large clusters. It can effectively inhibit surface helium blistering under high temperature annealing. Compared with bulk W, no cracks were found in the nanochannel W film post-irradiated by He+ ions at high fluence. The release of helium from the nanochannel W film is more than one order of magnitude higher than that of bulk W whether they are irradiated by single He+ ions or sequentially irradiated by Kr2+ and He+ ions. Moreover, swelling of the bulk W is more serious than that of the nanochannel film. Therefore, nanochannel W film has a higher radiation tolerance performance in the synergistic irradiation.

Radiation blistering of niobium in sequence irradiated by helium ions with different energy

International Nuclear Information System (INIS)

Das, S.K.; Kaminskij, M.S.; Guseva, M.I.; Gusev, V.M.; Krasulin, Yu.L.; Martynenko, Yu.V.; Rozina, I.A.

1977-01-01

The results of the investigation of the blistering of the surface of polycrystalline niobium foils subjected to successive irradiation by helium ions of energies of 3 to 50 keV are reported. The critical doses of irradiation, the types of blisters and the rate of erosion were determined. A comparative analysis of the formation of blisters on cold-rolled and annealed niobium has been made. On cold-rolled niobium the blistering is mainly due to ions with energies of 3 to 80 keV, on annealed niobium of 100 to 500 keV. The erosion of cold-rolled niobium takes place through blisters formed by the action of helium ions with energies of the order of 45 keV, and that of annealed niobium, through helium ions with energies of 100 to 500 keV. The observed differences in the formation of blisters on niobium irradiated with helium ions of a wide range of energies are explained by the change in the diffusion kinetics of implanted ions having a uniform distribution across the thickness of the target

Hydrogen and helium in metals: positron lifetime experiments. Quarterly report 3. quarter 1987

International Nuclear Information System (INIS)

Rajainmaeki, Hannu.

1987-09-01

This thesis reviews a new approach to studying the role of hydrogen and helium in defect recovery of metals by the positron lifetime technique. A cryostat has been built at the University of Jyvaeskylae for irradiating and/or implaning solids by high-energy proton or helium beams from the MC-20 cyclotron. The samples can be kept continuously below 20 K and the isochronal annealings and the subsequent positron lifetime measurements are carried ou in the same cryostat after the irradiations. During the implantations below 20 K both impuities (H or He) and Frenkel pairs are produced simultaneously. By measuring positron lifetimes during the annealing detailed information is obtained about radiation damage, impurity-defect interactions, lattice defect annealing, void nucleation and formation of helium bubbles. In this work positron lifetime spectroscopy has been utilized for the first time to study defect recovery below the liquid nitrogen temperature (77 K). The annealing stages are investigated in aluminium, nickel and molybdenum in the temperature range 20-700 K. Hydrogen is found to get trapped at vacancies in all the studied metals with binding energies 0.53+-0.04 and 1.6+-0.1 eV, respectively. Trapped hydrogen retards the vacancy migration in Al and Mo, while H-vancancy pairs dissociate in Ni below the free vacancy migration stage. helium gets deeply trapped at vacancies in Al and migrates substitutionally with the activation energy of 1.3+-0.1 eV. Helium-vacancy pairs are observed to nucleate into clusters and form helium bubbles which are stable up to the Al melting temperature. The growth mechanisms for the bubbles are established as thermal vacancy absorption and bubble migration/coalescence

Development of helium porosity near-by grain boundaries in nickel-carbon alloys

International Nuclear Information System (INIS)

Reutov, I.V.; Reutov, V.F.

1995-01-01

The peculiarities of development of helium porosity near grain boundaries in nickel with 0.002-0.065 at.% carbon uniformly doped with helium up to 2·10 -2 at.% in the process of post-irradiation isothermal annealing at 800 deg C for 1-50 hours are studied. It is stated that at this annealing temperature intensive nucleation and growth of bubbles are observed in near-boundary region whose width grows both with increase of annealing time and carbon content. The TEM studies have shown that in near-boundary zone itself the process of bubble growth is non-uniform: bubble size increases and their density decreases as the distance from grain boundary is increased. The effect observed is discussed from the point of view of formation of two zones with different level of swelling in a grain (near-by boundary and matrix) and consequently, hydrostatic stress as well conditioning the flux of vacancies and helium-vacancy complexes from matrix to grain boundary. 8 refs., 5 figs

Recent progress in the modelling of helium and tritium behaviour in irradiated beryllium pebbles

International Nuclear Information System (INIS)

Rabaglino, E.; Ronchi, C.; Cardella, A.

2003-01-01

One of the key issues of the European Helium Cooled Pebble Bed blanket is the behaviour under irradiation of beryllium pebbles, which have the function of neutron multiplier. An intense production of helium occurs in-pile, as well as a non negligible generation of tritium. Helium bubbles induce swelling and a high tritium inventory is a safety issue. Extensive studies for a better understanding, characterisation and modelling of the behaviour of helium and tritium in irradiated beryllium pebbles are being carried out, with the final aim to enable a reliable prediction of gas release and swelling in the full range of operating and accidental conditions of a Fusion Power Reactor. The general strategy consists in integrating studies on macroscopic phenomena (gas release) with the characterisation of corresponding microscopic diffusion phenomena (bubble kinetics) and the assessment of some fundamental diffusion parameter for the models (gas atomic diffusion coefficients). The present work gives a summary of the latest achievements in this context. By an inverse analysis of experimental out-of-pile gas release from weakly irradiated pebbles, coupled to the study of the characteristics of bubble population, it has been possible to assess the thermal diffusion coefficients of helium and tritium in and to improve and validate the classical model of gas precipitation into bubbles inside the grain. The improvement of the description of gas atomic diffusion and precipitation is the first step to enable a more reliable prediction of gas release

Behaviour of helium after implantation in molybdenum

International Nuclear Information System (INIS)

Viaud, C.; Maillard, S.; Carlot, G.; Valot, C.; Gilabert, E.; Sauvage, T.; Peaucelle, C.; Moncoffre, N.

2009-01-01

This study deals with the behaviour of helium in a molybdenum liner dedicated to the retention of fission products. More precisely this work contributes to evaluate the release of implanted helium when the gas has precipitated into nanometric bubbles close to the free surface. A simple model dedicated to calculate the helium release in such a condition is presented. The specificity of this model lays on the assumption that the gas is in equilibrium with a simple distribution of growing bubbles. This effort is encouraging since the calculated helium release fits an experimental dataset with a set of parameters in good agreement with the literature

Microstructural observation on helium injected and creep ruptured JPCA

International Nuclear Information System (INIS)

Yamamoto, N.; Shiraishi, H.; Hishinuma, A.

1986-01-01

Detailed and quantitative TEM observation was performed on high temperature helium injected and creep ruptured JPCA to seek the prominent TiC distribution developed for suppression of helium embrittlement. Three different preinjection treatments were adopted for changing the TiC distribution. Considerable degradation in creep rupture strength by helium occurred in solution-annealed specimens, although there was much less effect of other treatments which included aging prior to injection. The concentration of helium at grain boundaries and the promotion of precipitation by helium during injection were responsible for the degradation. Therefore, the presence of TiC precipitates before helium introduction will help prevent degradation. On the other hand, the rupture elongation was reduced by helium after all treatments, although helium trapping by TiC precipitates in the matrix was successfully achieved. Consequently, the combined use of several methods may be necessary for further suppression of helium embrittlement. (orig.)

Helium in inert matrix dispersion fuels

International Nuclear Information System (INIS)

Veen, A. van; Konings, R.J.M.; Fedorov, A.V.

2003-01-01

The behaviour of helium, an important decay product in the transmutation chains of actinides, in dispersion-type inert matrix fuels is discussed. A phenomenological description of its accumulation and release in CERCER and CERMET fuel is given. A summary of recent He-implantation studies with inert matrix metal oxides (ZrO 2 , MgAl 2 O 4 , MgO and Al 2 O 3 ) is presented. A general picture is that for high helium concentrations helium and vacancy defects form helium clusters which convert into over-pressurized bubbles. At elevated temperature helium is released from the bubbles. On some occasions thermal stable nano-cavities or nano-pores remain. On the basis of these results the consequences for helium induced swelling and helium storage in oxide matrices kept at 800-1000 deg. C will be discussed. In addition, results of He-implantation studies for metal matrices (W, Mo, Nb and V alloys) will be presented. Introduction of helium in metals at elevated temperatures leads to clustering of helium to bubbles. When operational temperatures are higher than 0.5 melting temperature, swelling and helium embrittlement might occur

Annealing effects on resistivity and Hall coefficient of neutron irradiated silicon

International Nuclear Information System (INIS)

Biggeri, U.

1995-01-01

High Temperature Annealing (HTA) treatment has been carried out on fast-neutron irradiated silicon samples with temperatures up to 300 C. Fluences of irradiation up to 1x10 14 n/cm 2 were used. Before annealing, samples irradiated with fluences higher than 1x10 13 n/cm 2 suffered the type conductivity inversion from n-type to p-type. The changes in the resisitivity and Hall coefficient during each annealing step have been measured by Hall effect analysis. Results indicate the possible creation of acceptors for low temperature annealing up to 150 C and the phosphorous release by E centres at annealing temperatures among 150 C and 200 C. Heating samples up to 300 C allows the recovering of the sample resistivity to its value before irradiation, with the peculiarity that bulks inverted to p-type after irradiation does not come back to n-type after annealing. (orig.)

Electron diffraction of CBr{sub 4} in superfluid helium droplets: A step towards single molecule diffraction

Energy Technology Data Exchange (ETDEWEB)

He, Yunteng; Zhang, Jie; Kong, Wei, E-mail: wei.kong@oregonstate.edu [Department of Chemistry, Oregon State University, Corvallis, Oregon 97331-4003 (United States)

2016-07-21

We demonstrate the practicality of electron diffraction of single molecules inside superfluid helium droplets using CBr{sub 4} as a testing case. By reducing the background from pure undoped droplets via multiple doping, with small corrections for dimers and trimers, clearly resolved diffraction rings of CBr{sub 4} similar to those of gas phase molecules can be observed. The experimental data from CBr{sub 4} doped droplets are in agreement with both theoretical calculations and with experimental results of gaseous species. The abundance of monomers and clusters in the droplet beam also qualitatively agrees with the Poisson statistics. Possible extensions of this approach to macromolecular ions will also be discussed. This result marks the first step in building a molecular goniometer using superfluid helium droplet cooling and field induced orientation. The superior cooling effect of helium droplets is ideal for field induced orientation, but the diffraction background from helium is a concern. This work addresses this background issue and identifies a possible solution. Accumulation of diffraction images only becomes meaningful when all images are produced from molecules oriented in the same direction, and hence a molecular goniometer is a crucial technology for serial diffraction of single molecules.

Recovery in dc and rf performance of off-state step-stressed AlGaN/GaN high electron mobility transistors with thermal annealing

International Nuclear Information System (INIS)

Kim, Byung-Jae; Hwang, Ya-Hsi; Ahn, Shihyun; Zhu, Weidi; Dong, Chen; Lu, Liu; Ren, Fan; Holzworth, M. R.; Jones, Kevin S.; Pearton, Stephen J.; Smith, David J.; Kim, Jihyun; Zhang, Ming-Lan

2015-01-01

The recovery effects of thermal annealing on dc and rf performance of off-state step-stressed AlGaN/GaN high electron mobility transistors were investigated. After stress, reverse gate leakage current and sub-threshold swing increased and drain current on-off ratio decreased. However, these degradations were completely recovered after thermal annealing at 450 °C for 10 mins for devices stressed either once or twice. The trap densities, which were estimated by temperature-dependent drain-current sub-threshold swing measurements, increased after off-state step-stress and were reduced after subsequent thermal annealing. In addition, the small signal rf characteristics of stressed devices were completely recovered after thermal annealing

Tensile properties of helium-injected V-15Cr-5Ti after irradiation in EBR-II

International Nuclear Information System (INIS)

Grossbeck, M.L.; Horak, J.A.

1985-01-01

Miniature specimens of V-15Cr-5Ti were prepared in the annealed condition and with 10, 20, and 30% cold work. The annealed specimens were cyclotron injected with helium and irradiated in sodium in EBR-II. The cold-worked specimens were irradiated in EBR-II but not helium injected. The specimens were irradiated at 400, 525, 625, and 700 0 C and received a fluence of 4.1 to 5.5 x 10 26 neutrons/m 2 (E > 0.1 meV). Tensile testing revealed very significant embrittlement as a result of the neutron irradiation but a much smaller change, mostly at 400 0 C, resulting from helium injection. 5 references, 9 figures, 2 tables

Effect of helium preinjection and prior thermomechanical treatment on the microstructure of Type 316 SS

International Nuclear Information System (INIS)

Kohyama, A.; Ayrault, G.; Turner, A.P.L.; Igata, N.

1982-10-01

Samples of 316 SS were preinjected with 15 appM helium either hot (650 0 C) or cold (room temperature) and irradiated with 3 MeV Ni + ions to a dose level of 25 dpa at 625 0 C in order to test the validity of helium preinjection as a means of simulation of transmutant helium production. Results for preinjected and single-ion irradiated samples were compared to samples irradiated with 3 MeV Ni + and simultaneously injected with helium at a rate of 15 appM He/dpa (dual-ion irradiated samples). Preinjected samples exhibited bimodal cavity size distributions. Preinjected samples of solution annealed or solution annealed and aged material showed lower swelling than dual-ion irradiated samples. However, He preinjection in 20% cold worked samples showed greater swelling than dual-ion irradiated samples 9 figures, 1 table

Helium-Charged La-Ni-Al Thin Films Deposited by Magnetron Sputtering

International Nuclear Information System (INIS)

Shi Liqun; Chen Deming; Xu Shilin; Liu Chaozhu; Hao Wanli; Zhou Zhuyin

2005-01-01

An advanced implantation of low energy helium-4 atoms during the La-Ni-Al film growth by adopting magnetron sputtering with Ar/He mixture gases is discussed. Both proton backscattering spectroscopy (PBS) and elastic recoil detection (ERD) analyses were adopted to measure helium concentration of the films and distribution in the near-surface region. Helium atoms with a high concentration incorporate evenly in deposited film. The introduction of the helium with no extra irradiation damage is expected by choosing suitable deposition conditions. It was found that amorphous and crystalline LaNi 5 -type structures can be achieved when sputtered with pure Ar and Ar/He mixture gases at room temperature, respectively. Thermal desorption experiments proposes that a part of hydrogen atoms are bound to trapped helium at crystal and releases together with helium. Only a small fraction of helium is released from the helium-vacancy clusters in lower temperature range and most of helium is released from small size helium bubbles in the high temperature range

Microstructural evolution in dual-ion irradiated 316SS under various helium injection schedules

International Nuclear Information System (INIS)

Kohyama, A.; Igata, N.; Ayrault, G.; Tokyo Univ.

1984-01-01

Dual-ion irradiated 316 SS samples with various helium injection schedules were studied. The intent of using different schedules was to either approximate the MFR condition, mimic the mixed spectrum reactor condition or mimic the fast reactor condition. The objective of this investigation is to study the influence of these different helium injection schedules on the microstructural development under irradiation. The materials for this study was 316 SS (MFE heat) with three thermomechanical pre-irradiation treatments: solution annealed, solution annealed and aged and 20% cold worked. The cavity nucleation and growth stages were investigated using high resolution TEM. (orig.)

Retention of hydrogen isotopes and helium in nickel

Energy Technology Data Exchange (ETDEWEB)

Okada, Mitsumasa; Sato, Rikiya; Yamaguchi, Kenji; Yamawaki, Michio [Tokyo Univ., Tokai, Ibaraki (Japan). Nuclear Engineering Research Lab.

1996-10-01

In the present study, a thin foil of nickel was irradiated by H{sub 2}{sup +}, D{sub 2}{sup +} and He{sup +} to a fluence of 1.2-6.0x10{sup 20}/m{sup 2} using the TBTS (Tritium Beam Test System) apparatus. The thermal desorption spectroscopy (TDS) technique was employed to evaluate the total amount of retained hydrogen isotope and helium atoms in nickel. In the spectra, two peaks appeared at 440-585K and 720-735K for helium. Hydrogen isotopes irradiation after helium preirradiation were found to enhance the helium release and to decrease the peak temperatures. Helium irradiation after hydrogen isotopes preirradiation were found to enhance the helium release, but the peak temperature showed little difference from that without preirradiation. (author)

Influence of Step Annealing Temperature on the Microstructure and Pitting Corrosion Resistance of SDSS UNS S32760 Welds

Science.gov (United States)

Yousefieh, M.; Shamanian, M.; Saatchi, A.

2011-12-01

In the present work, the influence of step annealing heat treatment on the microstructure and pitting corrosion resistance of super duplex stainless steel UNS S32760 welds have been investigated. The pitting corrosion resistance in chloride solution was evaluated by potentiostatic measurements. The results showed that step annealing treatments in the temperature ranging from 550 to 1000 °C resulted in a precipitation of sigma phase and Cr2N along the ferrite/austenite and ferrite/ferrite boundaries. At this temperature range, the metastable pits mainly nucleated around the precipitates formed in the grain boundary and ferrite phase. Above 1050 °C, the microstructure contains only austenite and ferrite phases. At this condition, the critical pitting temperature of samples successfully arrived to the highest value obtained in this study.

Fission gas release during post irradiation annealing of large grain size fuels from Hinkley point B

International Nuclear Information System (INIS)

Killeen, J.C.

1997-01-01

A series of post-irradiation anneals has been carried out on fuel taken from an experimental stringer from Hinkley Point B AGR. The stringer was part of an experimental programme in the reactor to study the effect of large grain size fuel. Three differing fuel types were present in separate pins in the stringer. One variant of large grain size fuel had been prepared by using an MgO dopant during fuel manufactured, a second by high temperature sintering of standard fuel and the third was a reference, 12μm grain size fuel. Both large grain size variants had similar grain sizes around 35μm. The present experiments took fuel samples from highly rated pins from the stringer with local burn-up in excess of 25GWd/tU and annealed these to temperature of up to 1535 deg. C under reducing conditions to allow a comparison of fission gas behaviour at high release levels. The results demonstrate the beneficial effect of large grain size on release rate of 85 Kr following interlinkage. At low temperatures and release rates there was no difference between the fuel types, but at temperatures in excess of 1400 deg. C the release rate was found to be inversely dependent on the fuel grain size. The experiments showed some differences between the doped and undoped large grains size fuel in that the former became interlinked at a lower temperature, releasing fission gas at an increased rate at this temperature. At higher temperatures the grain size effect was dominant. The temperature dependence for fission gas release was determined over a narrow range of temperature and found to be similar for all three types and for both pre-interlinkage and post-interlinkage releases, the difference between the release rates is then seen to be controlled by grain size. (author). 4 refs, 7 figs, 3 tabs

Fission gas release during post irradiation annealing of large grain size fuels from Hinkley point B

Energy Technology Data Exchange (ETDEWEB)

Killeen, J C [Nuclear Electric plc, Barnwood (United Kingdom)

1997-08-01

A series of post-irradiation anneals has been carried out on fuel taken from an experimental stringer from Hinkley Point B AGR. The stringer was part of an experimental programme in the reactor to study the effect of large grain size fuel. Three differing fuel types were present in separate pins in the stringer. One variant of large grain size fuel had been prepared by using an MgO dopant during fuel manufactured, a second by high temperature sintering of standard fuel and the third was a reference, 12{mu}m grain size fuel. Both large grain size variants had similar grain sizes around 35{mu}m. The present experiments took fuel samples from highly rated pins from the stringer with local burn-up in excess of 25GWd/tU and annealed these to temperature of up to 1535 deg. C under reducing conditions to allow a comparison of fission gas behaviour at high release levels. The results demonstrate the beneficial effect of large grain size on release rate of {sup 85}Kr following interlinkage. At low temperatures and release rates there was no difference between the fuel types, but at temperatures in excess of 1400 deg. C the release rate was found to be inversely dependent on the fuel grain size. The experiments showed some differences between the doped and undoped large grains size fuel in that the former became interlinked at a lower temperature, releasing fission gas at an increased rate at this temperature. At higher temperatures the grain size effect was dominant. The temperature dependence for fission gas release was determined over a narrow range of temperature and found to be similar for all three types and for both pre-interlinkage and post-interlinkage releases, the difference between the release rates is then seen to be controlled by grain size. (author). 4 refs, 7 figs, 3 tabs.

Two- and three-step annealing effects of metallic and semiconducting iron silicides formed by ion beam synthesis

Energy Technology Data Exchange (ETDEWEB)

Katsumata, Hiroshi [Meiji Univ., Tokyo (Japan); Makita, Yunosuke; Kobayashi, Naoto [and others

1997-03-01

Polycrystalline {beta}-FeSi{sub 2} was formed by ion beam synthesis (IBS). Annealing was made using two different procedures; 1) two-step annealing (2SA) ((T{sub 1} = 600degC, 1 hr) + (T{sub 2} = 900degC, 2 hrs)), 2) three-step annealing (3SA) ((T{sub 1} = 600degC, 1 hr) + (T{sub 2} = 1100degC, 1 min) + (T{sub 3} = 800 - 900degC, 18 hrs)). All the synthesized {beta}-FeSi{sub 2} layers presented an n-type conductivity with resistivities of 0.24 - 0.25 {Omega}{center_dot}cm, and they showed a direct band-gap of 0.801 - 0.824 eV with a moderate contribution of an indirect band-gap which is a few tens meV lower than the direct one. Although RBS and optical absorption measurements showed a superior crystalline quality of 3SA-samples to 2SA-samples, Raman scattering signals appeared only for 2SA-samples at 198 and 250 cm{sup -1}. This is explained by considering a decrease in the amount of {beta}-FeSi{sub 2} for 3SA-samples, which was deduced from the results of X-ray diffraction (XRD) analysis. The most adequate annealing temperature (T{sub 3}) for transforming {alpha}-Fe{sub 2}Si{sub 5} to {beta}-FeSi{sub 2} was found to be 850degC, in which the transformation process was observed by XRD and photomicroscope as a function of T{sub 3}. (author)

Room temperature desorption of helium-3 from metal tritides

International Nuclear Information System (INIS)

Beavis, L.C.; Kass, W.J.

1976-10-01

It has long been known that helium-3 accumulates in metal tritides as tritium decays. Early in life nearly 100% of the helium-3 is retained in the lattice, but when a critical concentration is reached (material dependent), the lattice will no longer retain the helium-3 and it is emitted at about the generation rate. Measurements were recently made on a number of erbium tritides with varying concentrations in the ditritide phase. The expected early release characteristics are observed for all of the samples. However, ditritides with higher tritium concentrations reach the rapid release state at much lower helium-3 concentrations. For instance, the helium to metal concentration for rapid release in the unsaturated ditritide is about 0.22, whereas it is only one-tenth this value in the saturated ditritide. The additional tritium in the tritide appears to be the cause of this effect

Effect of annealing temperature on a single step processed Cu{sub 2}ZnSnS{sub 4} thin film via solution method

Energy Technology Data Exchange (ETDEWEB)

Prabeesh, P.; Selvam, I. Packia; Potty, S.N.

2016-05-01

Cu{sub 2}ZnSnS{sub 4} (CZTS) is a promising material for thin film solar cell applications because of its excellent photovoltaic properties, high abundance and non-toxicity. Thin films of CZTS are generally fabricated by vacuum based techniques or by using toxic solvents and these routes reduce its attention as a low cost and environmental friendly material. In this study, we have prepared CZTS through a solution based single step approach using non-toxic chemicals by spin coating and studied the effect of annealing temperature in the range 350–550 °C in nitrogen atmosphere on structural, optical and electrical properties. XRD results revealed the formation of kesterite phase at all annealing temperatures, while the Raman studies indicated Cu{sub 2}SnS{sub 2} impurity phase in the film annealed at 550 °C. Band gap of the films annealed in nitrogen varies from 1.46 eV to 1.56 eV, depending on the annealing temperature. Optimum properties, such as, good crystallinity, dense structure, ideal band gap (1.49 eV) and good absorption coefficient (10{sup 4} cm{sup −1}), were obtained for the film annealed at 500 °C for 30 min in nitrogen. - Highlights: • Prepared CZTS film through one-step liquid based approach using non-toxic chemicals. • Studied the effect of N{sub 2} annealing on structural, optical and electrical properties. • The phase pure CZTS absorber film exhibited excellent photovoltaic properties • The film annealed at 500 °C for 30 min in nitrogen exhibited optimum properties.

Effects of a modular two-step ozone-water and annealing process on silicon carbide graphene

Energy Technology Data Exchange (ETDEWEB)

Webb, Matthew J., E-mail: matthew.webb@cantab.net; Lundstedt, Anna; Grennberg, Helena [Department of Chemistry—BMC, Uppsala University, Box 576, SE-751 23 Uppsala (Sweden); Polley, Craig; Niu, Yuran; Zakharov, Alexei A.; Balasubramanian, Thiagarajan [MAX IV Laboratory, Lund University, 22100 Lund (Sweden); Dirscherl, Kai [DFM—Danish Fundamental Metrology, Matematiktorvet 307, DK-2800 Lyngby (Denmark); Burwell, Gregory; Guy, Owen J. [College of Engineering, Faraday Tower, Singleton Park, Swansea University, Swansea SA2 8PP (United Kingdom); Palmgren, Pål [VG Scienta Scientific AB, Box 15120, Vallongatan 1, SE-750 15 Uppsala (Sweden); Yakimova, Rositsa [Department of Physics, Chemistry, and Biology, Linköping University, SE-581 83 Linköping (Sweden)

2014-08-25

By combining ozone and water, the effect of exposing epitaxial graphene on silicon carbide to an aggressive wet-chemical process has been evaluated after high temperature annealing in ultra high vacuum. The decomposition of ozone in water produces a number of oxidizing species, however, despite long exposure times to the aqueous-ozone environment, no graphene oxide was observed after the two-step process. The systems were comprehensively characterized before and after processing using Raman spectroscopy, core level photoemission spectroscopy, and angle resolved photoemission spectroscopy together with low energy electron diffraction, low energy electron microscopy, and atomic force microscopy. In spite of the chemical potential of the aqueous-ozone reaction environment, the graphene domains were largely unaffected raising the prospect of employing such simple chemical and annealing protocols to clean or prepare epitaxial graphene surfaces.

Study of thermal annealing effect on Bragg gratings photo-inscribed in step-index polymer optical fibers

Science.gov (United States)

Hu, X.; Kinet, D.; Mégret, P.; Caucheteur, C.

2016-04-01

In this paper, both non-annealed and annealed trans-4-stilbenemethanol-doped step-index polymer optical fibers were photo-inscribed using a 325 nm HeCd laser with two different beam power densities reaching the fiber core. In the high density regime where 637 mW/mm2 are used, the grating reflectivity is stable over time after the photo-writing process but the reflected spectrum is of limited quality, as the grating physical length is limited to 1.2 mm. To produce longer gratings exhibiting more interesting spectral features, the beam is enlarged to 6 mm, decreasing the power density to 127 mW/mm2. In this second regime, the grating reflectivity is not stable after the inscription process but tends to decay for both kinds of fibers. A fortunate property in this case results from the possibility to fully recover the initial reflectivity using a post-inscription thermal annealing, where the gratings are annealed at 80 °C during 2 days. The observed evolutions for both regimes are attributed to the behavior of the excited intermediate states between the excited singlet and the ground singlet state of trans- and cis-isomers as well as the temperature-dependent glassy polymer matrix.

Effect of helium irradiation on fracture modes

International Nuclear Information System (INIS)

Hanamura, T.; Jesser, W.A.

1982-01-01

The objective of this work is to determine the crack opening mode during in-situ HVEM tensile testing and how it is influenced by test temperature and helium irradiation. Most cracks were mixed mode I and II. However, between 250 0 C and room temperature the effect of helium irradiation is to increase the amount of mode I crack propagation. Mode II crack opening was observed as grain boundary sliding initiated by a predominantly mode I crack steeply intersecting the grain boundary. Mode II crack opening was absent in irradiated specimens tested between 250 0 C and room temperature, but could be restored by a post irradiation anneal

Interface strength of SiC/SiC composites with and without helium implantation using micro-indentation test

International Nuclear Information System (INIS)

Saito, M.; Ohtsuka, S.

1998-01-01

Helium implantation effects on interface strength of SiC/SiC composite were studied using the micro-indentation fiber push-out method. Helium implantation was carried out with an accelerator at about 400 K. Total amount of implanted helium was approximately 10000 appm. Increase of the fiber push-in load was observed in as-implanted specimen. After post-implantation-annealing at 1673 K for 1 h, the change of the fiber push-in load by helium implantation was not observed. Effects of helium implantation on the interface are discussed. (orig.)

Synthesis of CuInSe2 thin films from electrodeposited Cu11In9 precursors by two-step annealing

Directory of Open Access Journals (Sweden)

TSUNG-WEI CHANG

2014-02-01

Full Text Available In this study, copper indium selenide (CIS films were synthesized from electrodeposited Cu-In-Se precursors by two-step annealing. The agglomeration phenomenon of the electrodeposited In layer usually occurred on the Cu surface. A thermal process was adopted to turn Cu-In precursors into uniform Cu11In9 binary compounds. After deposition of the Se layer, annealing was employed to form chalcopyrite CIS. However, synthesis of CIS from Cu11In9 requires sufficient thermal energy. Annealing temperature and time were investigated to grow high quality CIS film. Various electrodeposition conditions were investigated to achieve the proper atomic ratio of CIS. The properties of the CIS films were characterized by scanning electron microscopy (SEM, X-ray Diffraction (XRD, and Raman spectra.

Low temperature calorimetry and transmission electron microscopy of helium bubbles in Cu

International Nuclear Information System (INIS)

Syskakis, E.

1985-08-01

Helium has been introduced into 100 μm thick pure Cu specimens by implantation of α-particles at T = 300 K. Post-implantation annealing of the specimens at high temperatures caused helium to precipitate into bubbles. We have measured the low-temperature heat capacity of helium confined in bubbles of average radius of less than 100 A. The size of the bubbles was obtained by transmission electron microscope investigations. We have observed that helium liquifies at low temperatures and undergoes the transition to the superfluid state in bubbles of average radius larger than 35 A. The confining geometry of bubbles is new and possesses unique features for investigations of confined helium. It provides the possibility to study properties of extremely small, spherical, completely isolated Bose ''particles'' consisting of 10 4 helium atoms each. Furthermore, as we show, it can be known with better accuracy than formerly investigated confining geometries. (orig./BHO)

Stored energy and annealing behavior of heavily deformed aluminium

DEFF Research Database (Denmark)

Kamikawa, Naoya; Huang, Xiaoxu; Kondo, Yuka

2012-01-01

It has been demonstrated in previous work that a two-step annealing treatment, including a low-temperature, long-time annealing and a subsequent high-temperature annealing, is a promising route to control the microstructure of a heavily deformed metal. In the present study, structural parameters...... are quantified such as boundary spacing, misorientation angle and dislocation density for 99.99% aluminium deformed by accumulative roll-bonding to a strain of 4.8. Two different annealing processes have been applied; (i) one-step annealing for 0.5 h at 100-400°C and (ii) two-step annealing for 6 h at 175°C...... followed by 0.5 h annealing at 200-600°C, where the former treatment leads to discontinuous recrystallization and the latter to uniform structural coarsening. This behavior has been analyzed in terms of the relative change during annealing of energy stored as elastic energy in the dislocation structure...

Behavior of helium gas atoms and bubbles in low activation 9Cr martensitic steels

Science.gov (United States)

Hasegawa, Akira; Shiraishi, Haruki; Matsui, Hideki; Abe, Katsunori

1994-09-01

The behavior of helium-gas release from helium-implanted 9Cr martensitic steels (500 appm implanted at 873 K) during tensile testing at 873 K was studied. Modified 9Cr-1Mo, low-activation 9Cr-2W and 9Cr-0.5V were investigated. Cold-worked AISI 316 austenitic stainless steel was also investigated as a reference which was susceptible helium embrittlement at high temperature. A helium release peak was observed at the moment of rupture in all the specimens. The total quantity of helium released from these 9Cr steels was in the same range but smaller than that of 316CW steel. Helium gas in the 9Cr steels should be considered to remain in the matrix at their lath-packets even if deformed at 873 K. This is the reason why the martensitic steels have high resistance to helium embrittlement.

Behavior of helium gas atoms and bubbles in low activation 9Cr martensitic steels

International Nuclear Information System (INIS)

Hasegawa, Akira; Shiraishi, Haruki; Matsui, Hideki; Abe, Katsunori

1994-01-01

The behavior of helium-gas release from helium-implanted 9Cr martensitic steels (500 appm implanted at 873 K) during tensile testing at 873 K was studied. Modified 9Cr-1Mo, low-activation 9Cr-2W and 9Cr-0.5V were investigated. Cold-worked AISI 316 austenitic stainless steel was also investigated as a reference which was susceptible helium embrittlement at high temperature. A helium release peak was observed at the moment of rupture in all the specimens. The total quantity of helium released from these 9Cr steels was in the same range but smaller than that of 316CW steel. Helium gas in the 9Cr steels should be considered to remain in the matrix at their lath-packets even if deformed at 873 K. This is the reason why the martensitic steels have high resistance to helium embrittlement. ((orig.))

Isothermal release of tritium from neutron-irradiated Li/sub 2/O pellets

Energy Technology Data Exchange (ETDEWEB)

O' Hira, Shigeru; Nagao, Hiroshi; Fujii, Yasuhiko; Okamoto, Makoto

1986-04-01

Li/sub 2/O pellets irradiated with thermal neutrons were isothermally annealed to release tritium in a helium atmosphere at temperatures ranging from 673 to 1073 K. The release rates were found to significantly increase at elevated temperatures and to depend on the density of the Li/sub 2/O pellet. The overall diffusion coefficients of the release process were calculated using the cylindrical geometry model for the pellets as D(cm/sup 2/ s/sup -1/)=1.02 x 10/sup -3/ exp(-51.0 kJ mol/sup -1//RT)(90% theoretical density pellets), and D (cm/sup 2/ s/sup -1/)=2.64 x 10/sup -3/ exp(-46.5 kJ mol/sup -1//RT)(ca. 80% T.D. pellets) over the region 773 <= T <= 1073/sup 0/K. The result of the release experiment at 673/sup 0/K sugested that the diffusion rate was controlled by the decomposition of lithium hydroxide on the surface of Li/sub 2/O grains.

High-temperature helium embrittlement (T>=0,45Tsub(M)) of metals

International Nuclear Information System (INIS)

Batfalsky, P.

1984-06-01

High temperature helium embrittlement, swelling and irradiation creep are the main technical problem of fusion reactor materials. The expected helium production will be very high. The helium produced by (n,α)-processes precipitates into helium bubbles because its solubility in solid metals is very low. Under continuous helium production at high temperature and stress the helium bubbles grow and lead to intergranular early failure. Solution annealed foil specimens of austenitic stainless steel AISI 316 were implanted with α-particles: 1. during creep tests at 1023 K (''in-beam'' test) 2. before the creep tests at high temperature (1023 K). The creep tests have been performed within large ranges of test parameter, e.g. applied stress, temperature, helium implantation rate and helium concentration. After the creep tests the microstructure was investigated using scanning (SEM) and transmission (TEM) electron microscopy. All the helium implanted specimens showed high temperature helium embrittlement, i.e. reduction of rupture time tsub(R) and ductility epsilonsub(R) and evidence of intergranular brittle fracture. The ''in-beam'' creep tests showed greater reduction of rupture time tsub(R) and ductility than the preimplanted creep tests. The comparison of this experimentally obtained data with various theoretical models of high temperature helium embrittlement showed that within the investigated parameter ranges the mechanism controlling the life time of the samples is probably the gas driven stable growth of the helium bubbles within the grain boundaries. (orig.)

Effects of helium content of microstructural development in Type 316 stainless steel under neutron irradiation

International Nuclear Information System (INIS)

Maziasz, P.J.

1985-11-01

This work investigated the sensitivity of microstructural evolution, particularly precipitate development, to increased helium content during thermal aging and during neutron irradiation. Helium (110 at. ppM) was cold preinjected into solution annealed (SA) DO-heat type 316 stainess steel (316) via cyclotron irradiation. These specimens were then exposed side by side with uninjected samples. Continuous helium generation was increased considerably relative to EBR-II irradiation by irradiation in HFIR. Data were obtained from quantitative analytical electron microscopy (AEM) in thin foils and on extraction replicas. 480 refs., 86 figs., 19 tabs

Effects of helium content of microstructural development in Type 316 stainless steel under neutron irradiation

Energy Technology Data Exchange (ETDEWEB)

Maziasz, P.J.

1985-11-01

This work investigated the sensitivity of microstructural evolution, particularly precipitate development, to increased helium content during thermal aging and during neutron irradiation. Helium (110 at. ppM) was cold preinjected into solution annealed (SA) DO-heat type 316 stainess steel (316) via cyclotron irradiation. These specimens were then exposed side by side with uninjected samples. Continuous helium generation was increased considerably relative to EBR-II irradiation by irradiation in HFIR. Data were obtained from quantitative analytical electron microscopy (AEM) in thin foils and on extraction replicas. 480 refs., 86 figs., 19 tabs.

The installation of helium auxiliary systems in HTGR

International Nuclear Information System (INIS)

Qin Zhenya; Fu Xiaodong

1993-01-01

The inert gas Helium was chosen as reactor coolant in high temperature gas coolant reactor, therefore a set of Special and uncomplex helium auxiliary systems will be installed, the safe operation of HTR-10 can be safeguarded. It does not effect the inherent safety of HTR-10 MW if any one of all those systems were damaged during operation condition. This article introduces the design function and the system principle of all helium auxiliary systems to be installed in HTR-10. Those systems include: helium purification and its regeneration system, helium supply and storage system, pressure control and release system of primary system, dump system for helium auxiliary system and fuel handling, gaseous waste storage system, water extraction system for helium auxiliary systems and evacuation system for primary system

Photoionization of helium dimers

International Nuclear Information System (INIS)

Havermeier, Tilo

2010-01-01

The helium dimer is one of the most weakly bound systems in the universe. This makes it an interesting quantum mechanical object for investigation. These Van der Waals Clusters can be produced in an expansion of a cryogenic gas jet through a small nozzle into vacuum. In the present experiment we examine the interaction of He dimers with synchrotron radiation at an energy range from 64 to 78 eV. We observed different pathways leading to single ionization of both He atoms of the dimer compound. This two close standing ions begin now to dissociate in cause of their coulomb potential. All charged fragments were detected in coincidence with a COLTRIMS system. Especially Interatomic Coulombic Decay (ICD) and the two step process (TS1) were clearly identified. Furthermore a distribution of the internuclear distance was obtained from the measured Kinetic Energy Release (KER). (orig.)

Computational algorithm for molybdenite concentrate annealing

International Nuclear Information System (INIS)

Alkatseva, V.M.

1995-01-01

Computational algorithm is presented for annealing of molybdenite concentrate with granulated return dust and that of granulated molybdenite concentrate. The algorithm differs from the known analogies for sulphide raw material annealing by including the calculation of return dust mass in stationary annealing; the latter quantity varies form the return dust mass value obtained in the first iteration step. Masses of solid products are determined by distribution of concentrate annealing products, including return dust and benthonite. The algorithm is applied to computations for annealing of other sulphide materials. 3 refs

Fission gas release behaviour of a 103 GWd/t{sub HM} fuel disc during a 1200 °C annealing test

Energy Technology Data Exchange (ETDEWEB)

Noirot, J., E-mail: jean.noirot@cea.fr [CEA, DEN, DEC, Cadarache, F-13108 St. Paul Lez Durance (France); Pontillon, Y. [CEA, DEN, DEC, Cadarache, F-13108 St. Paul Lez Durance (France); Yagnik, S. [EPRI, P.O. Box 10412, Palo Alto, CA 94303-0813 (United States); Turnbull, J.A. [Independent Consultant (United Kingdom); Tverberg, T. [IFE, P.O. Box 173, NO-1751 Halden (Norway)

2014-03-15

Within the Nuclear Fuel Industry Research (NFIR) program, several fuel variants, in the form of thin circular discs, were irradiated in the Halden Boiling Water Reactor (HBWR) to a range of burn-ups ∼100 GWd/t{sub HM}. The design of the assembly was similar to that used in other HBWR programs: the assembly contained several rods with fuel discs sandwiched between Mo discs, which limited temperature gradients within the fuel discs. One such rod contained standard grain UO{sub 2} discs (3D grain size = 18 μm) reaching a burn-up of 103 GWd/t{sub HM}. After the irradiation, the gas release upon rod puncturing was measured to be 2.9%. Detailed characterizations of one of these irradiated UO{sub 2} discs, using electron probe microanalysis (EPMA), scanning electron microscopy (SEM) and secondary ion mass spectrometry (SIMS), were performed in a CEA Cadarache hot laboratory. Examination revealed the high burn-up structure (HBS) formation throughout the whole of the disc, also the fission gas distribution within this HBS, with a very high proportion of the gas in the HBS bubbles. A sibling disc was submitted to a temperature transient up to 1200 °C in the out-of-pile (OOP) annealing test device “Merarg” at a relatively low temperature ramp rate (0.2 °C/s). In addition to the total gas release during this annealing test, the release peaks throughout the temperature range were monitored. The fuel was then characterized with the same microanalysis techniques as before the annealing test to investigate the effects of this test on the microstructure of the fuel and on the fission gases. It provided valuable insights into fission gas localization and the release behaviour in UO{sub 2} fuel with high burn-up structure (HBS)

Final report on the Controlled Cold Helium Spill Test in the LHC tunnel at CERN

CERN Document Server

Dufay-Chanat, L; Casas-Cubillos, J; Chorowski, M; Grabowski, M; Jedrusyna, A; Lindell, G; Nonis, M; Koettig, T; Vauthier, N; van Weelderen, R; Winkler, T

2015-01-01

The 27 km circumference LHC underground tunnel is a space in which the helium cooled LHC magnets are installed. The vacuum enclosures of the superconducting magnets are protected by over-pressure safety relief devices that open whenever cold helium escapes either from the magnet cold enclosure or from the helium supply headers, into this vacuum enclosure. A 3-m long no stay zone around these devices is defined based on scale model studies, protecting the personnel against cold burns or asphyxia caused by such a helium release event. Recently, several simulation studies have been carried out modelling the propagation of the helium/air mixture, resulting from the opening of such a safety device, along the tunnel. The released helium flows vary in the range between 1 kg/s and 0.1 kg/s. To validate these different simulation studies, real life mock-up tests have been performed inside the LHC tunnel, releasing helium flow rates of 1 kg/s, 0.3 kg/s and 0.1 kg/s. For each test, up to 1000 liters of liquid helium wer...

Management of the Bohunice RPVs annealing procedures

International Nuclear Information System (INIS)

Repka, M.

1994-01-01

The program of annealing regeneration procedure of RPVs units 1 and 2 of NPP V-1 (EBO) realization in the year 1993, is the topic of this paper. In the paper the following steps are described in detail: the preparation works, the annealing procedure realization schedule and safety management: starting with zero conditions, assembling of annealing apparatus, annealing procedure, cooling down and disassembling procedure of annealing apparatus. At the end the programs of annealing of both RPVs including the dosimetry measurements are discussed and evaluated. (author). 3 figs

Final report on the Controlled Cold Helium Spill Test in the LHC tunnel at CERN

International Nuclear Information System (INIS)

Dufay-Chanat, L; Bremer, J; Casas-Cubillos, J; Koettig, T; Vauthier, N; Van Weelderen, R; Winkler, T; Chorowski, M; Grabowski, M; Jedrusyna, A; Lindell, G; Nonis, M

2015-01-01

The 27 km circumference LHC underground tunnel is a space in which the helium cooled LHC magnets are installed. The vacuum enclosures of the superconducting magnets are protected by over-pressure safety relief devices that open whenever cold helium escapes either from the magnet cold enclosure or from the helium supply headers, into this vacuum enclosure. A 3-m long no stay zone around these devices is defined based on scale model studies, protecting the personnel against cold burns or asphyxia caused by such a helium release event. Recently, several simulation studies have been carried out modelling the propagation of the helium/air mixture, resulting from the opening of such a safety device, along the tunnel. The released helium flows vary in the range between 1 kg/s and 0.1 kg/s. To validate these different simulation studies, real life mock-up tests have been performed inside the LHC tunnel, releasing helium flow rates of 1 kg/s, 0.3 kg/s and 0.1 kg/s. For each test, up to 1000 liters of liquid helium were released under standard operational tunnel conditions. The data recorded include oxygen concentration, temperature and flow speed measurements, and video footage used to assess qualitatively the visibility. These measurements have been made in the up- and downstream directions, with respect to the air ventilation flow, of the spill point.This paper presents the experimental set-up under which these release tests were made, the effects of these releases on the atmospheric tunnel condition as a function of the release flow rate. We discuss the modification to the personnel access conditions to the LHC tunnel that are presently implemented as a result of these tests. (paper)

Final report on the Controlled Cold Helium Spill Test in the LHC tunnel at CERN

Science.gov (United States)

Dufay-Chanat, L.; Bremer, J.; Casas-Cubillos, J.; Chorowski, M.; Grabowski, M.; Jedrusyna, A.; Lindell, G.; Nonis, M.; Koettig, T.; Vauthier, N.; van Weelderen, R.; Winkler, T.

2015-12-01

The 27 km circumference LHC underground tunnel is a space in which the helium cooled LHC magnets are installed. The vacuum enclosures of the superconducting magnets are protected by over-pressure safety relief devices that open whenever cold helium escapes either from the magnet cold enclosure or from the helium supply headers, into this vacuum enclosure. A 3-m long no stay zone around these devices is defined based on scale model studies, protecting the personnel against cold burns or asphyxia caused by such a helium release event. Recently, several simulation studies have been carried out modelling the propagation of the helium/air mixture, resulting from the opening of such a safety device, along the tunnel. The released helium flows vary in the range between 1 kg/s and 0.1 kg/s. To validate these different simulation studies, real life mock-up tests have been performed inside the LHC tunnel, releasing helium flow rates of 1 kg/s, 0.3 kg/s and 0.1 kg/s. For each test, up to 1000 liters of liquid helium were released under standard operational tunnel conditions. The data recorded include oxygen concentration, temperature and flow speed measurements, and video footage used to assess qualitatively the visibility. These measurements have been made in the up- and downstream directions, with respect to the air ventilation flow, of the spill point. This paper presents the experimental set-up under which these release tests were made, the effects of these releases on the atmospheric tunnel condition as a function of the release flow rate. We discuss the modification to the personnel access conditions to the LHC tunnel that are presently implemented as a result of these tests.

Hybrid simulation research on formation mechanism of tungsten nanostructure induced by helium plasma irradiation

Energy Technology Data Exchange (ETDEWEB)

Ito, Atsushi M., E-mail: ito.atsushi@nifs.ac.jp [National Institute for Fusion Science, 322-6 Oroshi-cho, Toki 509-5292 (Japan); Takayama, Arimichi; Oda, Yasuhiro [National Institute for Fusion Science, 322-6 Oroshi-cho, Toki 509-5292 (Japan); Tamura, Tomoyuki; Kobayashi, Ryo; Hattori, Tatsunori; Ogata, Shuji [Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555 (Japan); Ohno, Noriyasu; Kajita, Shin [Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603 (Japan); Yajima, Miyuki [National Institute for Fusion Science, 322-6 Oroshi-cho, Toki 509-5292 (Japan); Noiri, Yasuyuki [Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603 (Japan); Yoshimoto, Yoshihide [University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan); Saito, Seiki [Kushiro National College of Technology, Kushiro, Hokkaido 084-0916 (Japan); Takamura, Shuichi [Aichi Institute of Technology, 1247 Yachigusa, Yakusa-cho, Toyota 470-0392 (Japan); Murashima, Takahiro [Tohoku University, 6-3, Aramaki-Aza-Aoba, Aoba-Ward, Sendai 980-8578 (Japan); Miyamoto, Mitsutaka [Shimane University, Matsue, Shimane 690-8504 (Japan); Nakamura, Hiroaki [National Institute for Fusion Science, 322-6 Oroshi-cho, Toki 509-5292 (Japan); Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603 (Japan)

2015-08-15

The generation of tungsten fuzzy nanostructure by exposure to helium plasma is one of the important problems for the use of tungsten material as divertor plates in nuclear fusion reactors. In the present paper, the formation mechanisms of the helium bubble and the tungsten fuzzy nanostructure were investigated by using several simulation methods. We proposed the four-step process which is composed of penetration step, diffusion and agglomeration step, helium bubble growth step, and fuzzy nanostructure formation step. As the fourth step, the formation of the tungsten fuzzy nanostructure was successfully reproduced by newly developed hybrid simulation combining between molecular dynamics and Monte-Carlo method. The formation mechanism of tungsten fuzzy nanostructure observed by the hybrid simulation is that concavity and convexity of the surface are enhanced by the bursting of helium bubbles in the region around the concavity.

Controlled Cold Helium Spill Test in the LHC Tunnel at CERN

Science.gov (United States)

Koettig, T.; Casas-Cubillos, J.; Chorowski, M.; Dufay-Chanat, L.; Grabowski, M.; Jedrusyna, A.; Lindell, G.; Nonis, M.; Vauthier, N.; van Weelderen, R.; Winkler, T.; Bremer, J.

The helium cooled magnets of the LHC particle accelerator are installed in a confined space, formed by a 27 km circumference 3.8 m diameter underground tunnel. The vacuum enclosures of the superconducting LHC magnets are protected by a lift plate against excessive overpressure created by eventual leaks from the magnet helium bath, or from the helium supply headers. A three-meter long no stay zone has been defined centered to these plates, based on earlier scale model studies, to protect the personnel against the consequences of an eventual opening of such a lift plate. More recently several simulation studies have been carried out modelling the propagation of the resulting helium/air mixture along the tunnel in case of such a cold helium release at a rate in the range of 1 kg/s. To validate the different scale models and simulation studies, real life mock-up tests have been performed in the LHC, releasing about 1000 liter of liquid helium under standard operational tunnel conditions. Data recorded during these tests include oxygen level, temperature and flow speed as well as video recordings, taken up- and downstream of the spill point (-100 m to +200 m) with respect to the ventilation direction in the LHC tunnel. The experimental set-up and measurement results are presented. Generic effects found during the tests will be discussed to allow the transposal to possible cold helium release cases in similar facilities.

Magnetic and structural properties of NdFeB thin film prepared by step annealing

International Nuclear Information System (INIS)

Serrona, Leo K.E.B.; Sugimura, A.; Fujisaki, R.; Okuda, T.; Adachi, N.; Ohsato, H.; Sakamoto, I.; Nakanishi, A.; Motokawa, M.

2003-01-01

The crystallization of the amorphous phase into the tetragonal Nd 2 Fe 14 B (PHI) phase and the corresponding changes in magnetic properties have been examined by step annealing experiment using a 2 μm thick NdFeB film sample. Microstructural and magnetic analysis indicate that the film was magnetically soft as deposited with the coercivity H ciperp -1 and the remnant magnetization 4πM rperp -1 was developed and diffraction analysis showed evidence of PHI phase 002l peaks being aligned perpendicular to the film plane. At an optimum annealing temperature of 575 deg. C, the remnant magnetization of this anisotropic thin film is around 0.60 T with intrinsic coercivity of ∼1340 kA m -1 . Annealing the film sample at 200 deg. C≤T ann ≤750 deg. C showed variations in magnetic properties that were mostly due to the change in the perpendicular anisotropy. Based on 4πM sperpendicular values plotted against T ann , a dip in 4πM sperpendicular values was observed as T ann increased in the soft-to-hard magnetic characteristics transition region and rose as the hard crystalline phase started to form. The results show that the magnetic properties of the NdFeB film were slightly influenced by the presence of NdO, film surface roughening and the small increase in crystal size as a consequence of repeated heat treatment. At T ann ∼300 deg. C, the nominal saturation magnetization indicated a certain degree of weak perpendicular magnetic anisotropy in the film sample considered to be essential in the enhancement of coercivity in crystallized films

Helium release rates and ODH calculations from RHIC magnet cooling line failure

Energy Technology Data Exchange (ETDEWEB)

Liaw, C.J.; Than, Y.; Tuozzolo, J.

2011-03-28

A catastrophic failure of the magnet cooling lines, similar to the LHC superconducting bus failure incident, could discharge cold helium into the RHIC tunnel and cause an Oxygen Deficiency Hazard (ODH) problem. A SINDA/FLUINT{reg_sign} model, which simulated the 4.5K/4 atm helium flowing through the magnet cooling system distribution lines, then through a line break into the insulating vacuum volumes and discharging via the reliefs into the RHIC tunnel, had been developed. Arc flash energy deposition and heat load from the ambient temperature cryostat surfaces are included in the simulations. Three typical areas: the sextant arc, the Triplet/DX/D0 magnets, and the injection area, had been analyzed. Results, including helium discharge rates, helium inventory loss, and the resulting oxygen concentration in the RHIC tunnel area, are reported. Good agreement had been achieved when comparing the simulation results, a RHIC sector depressurization test measurement, and some simple analytical calculations.

Fast resolution change in neutral helium atom microscopy

Science.gov (United States)

Flatabø, R.; Eder, S. D.; Ravn, A. K.; Samelin, B.; Greve, M. M.; Reisinger, T.; Holst, B.

2018-05-01

In neutral helium atom microscopy, a beam of atoms is scanned across a surface. Though still in its infancy, neutral helium microscopy has seen a rapid development over the last few years. The inertness and low energy of the helium atoms (less than 0.1 eV) combined with a very large depth of field and the fact that the helium atoms do not penetrate any solid material at low energies open the possibility for a non-destructive instrument that can measure topology on the nanoscale even on fragile and insulating surfaces. The resolution is determined by the beam spot size on the sample. Fast resolution change is an attractive property of a microscope because it allows different aspects of a sample to be investigated and makes it easier to identify specific features. However up till now it has not been possible to change the resolution of a helium microscope without breaking the vacuum and changing parts of the atom source. Here we present a modified source design, which allows fast, step wise resolution change. The basic design idea is to insert a moveable holder with a series of collimating apertures in front of the source, thus changing the effective source size of the beam and thereby the spot size on the surface and thus the microscope resolution. We demonstrate a design with 3 resolution steps. The number of resolution steps can easily be extended.

High temperature tensile properties of 316 stainless steel implanted with helium

International Nuclear Information System (INIS)

Hasegawa, Akira; Yamamoto, Norikazu; Shiraishi, Haruki

1993-01-01

Helium embrittlement is one of the problems in structural materials for fusion reactors. Recently, martensitic steels have been developed which have a good resistance to high-temperature helium embrittlement, but the mechanism has not yet been clarified. In this paper, tensile behaviors of helium implanted austenitic stainless steels, which are sensitive to the helium embrittlement, were studied and compared with those of martensitic steels under the same experimental conditions, and the effect of microstructure on helium embrittlement was discussed. Helium was implanted by 300 appm at 573-623 K to miniature tensile speciments of 316 austenitic steels using a cyclotron accelerator. Solution annealed (316SA) and 20% cold worked (316CW) specimens were used. Post-implantation tensile tests were carried out at 573, 873 and 973 K. Yield stress at 573 K increased with the helium implantation in 316SA and 316CW, but the yield stress changes of 316SA at 873 and 973 K were different from that of 316CW. Black-dots were observed in the as-implanted specimen and bubbles were observed in the speciments tensile-tested at 873 and 973 K. Intergranular fracture was observed at only 973 K in both of the 316SA and 316CW specimens. Therefore, cold work did not suppress the high-temperature helium embrittlement under this experimental condition. The difference in the influence of helium on type 316 steel and 9Cr martensitic steels were discussed. Test temperature change of reduction in are showed clearly that helium embrittlement did not occur in 9Cr martensitic steels but occurred in 316 austenitic steels. Fine microstructures of 9Cr martensitic steels should suppress helium embrittlement at high temperatures. (author)

Step-by-step approach to convective cooling of laser disc amplifiers

International Nuclear Information System (INIS)

Bourque, R.F.

1979-04-01

A step by step approach is presented to the problem of gas cooling of laser glass amplifiers. The basic equations are given for glass conduction, thermal stress, gas convection, and heat exchanger and blower design. An example calculation is then carried out for helium gas at one atmosphere with the gas flow in the direction orthogonal to the optical path. It is found that pumping powers and temperatures are acceptable for this case. Results are also presented for helium in the slant direction and for nitrogen in both directions. Included also are the effects on pumping power of gas temperature rise, gas pressure, flashtube rep rate, and flow channel width. It is found that, based on temperature rise and pumping power, nitrogen is as viable a coolant as helium

Investigation of impurity-helium solid phase decomposition

International Nuclear Information System (INIS)

Boltnev, R.E.; Gordon, E.B.; Krushinskaya, I.N.; Martynenko, M.V.; Pel'menev, A.A.; Popov, E.A.; Khmelenko, V.V.; Shestakov, A.F.

1997-01-01

The element composition of the impurity-helium solid phase (IHSP), grown by injecting helium gas jet, involving Ne, Ar, Kr, and Xe atoms and N 2 molecules, into superfluid helium, has been studied. The measured stoichiometric ratios, S = N H e / N I m, are well over the values expected from the model of frozen together monolayer helium clusters. The theoretical possibility for the freezing of two layers helium clusters is justified in the context of the model of IHSP helium subsystem, filled the space between rigid impurity centers. The process of decomposition of impurity-helium (IH)-samples taken out of liquid helium in the temperature range 1,5 - 12 K and the pressure range 10-500 Torr has been studied. It is found that there are two stages of samples decomposition: a slow stage characterized by sample self cooling and a fast one accompanied by heat release. These results suggest, that the IHSP consists of two types of helium - weakly bound and strongly bound helium - that can be assigned to the second and the first coordination helium spheres, respectively, formed around heavy impurity particles. A tendency for enhancement of IHSP thermo stability with increasing the impurity mass is observed. Increase of helium vapor pressure above the sample causes the improvement of IH sample stability. Upon destruction of IH samples, containing nitrogen atoms, a thermoluminescence induced by atom recombination has been detected in the temperature region 3-4,5 K. This suggests that numerous chemical reactions may be realized in solidified helium

Helium leak and chemical impurities control technology in HTTR

International Nuclear Information System (INIS)

Tochio, Daisuke; Shimizu, Atsushi; Hamamoto, Shimpei; Sakaba, Nariaki

2014-01-01

Japan Atomic Energy Agency (JAEA) has designed and developed high-temperature gas-cooled reactor (HTGR) hydrogen cogeneration system named gas turbine high-temperature reactor (GTHTR300C) as a commercial HTGR. Helium gas is used as the primary coolant in HTGR. Helium gas is easy to leak, and the primary helium leakage should be controlled tightly from the viewpoint of preventing the release of radioactive materials to the environment. Moreover from the viewpoint of preventing the oxidization of graphite and metallic material, the helium coolant chemistry should be controlled tightly. The primary helium leakage and the helium coolant chemistry during the operation is the major factor in the HTGR for commercialization of HTGR system. This paper shows the design concept and the obtained operational experience on the primary helium leakage control and primary helium impurity control in the high-temperature engineering test reactor (HTTR) of JAEA. Moreover, the future plan to obtain operational experience of these controls for commercialization of HTGR system is shown. (author)

Structure–mechanical property relationship in a high strength low carbon alloy steel processed by two-step intercritical annealing and intercritical tempering

International Nuclear Information System (INIS)

Zhou, W.H.; Wang, X.L.; Venkatsurya, P.K.C.; Guo, H.; Shang, C.J.; Misra, R.D.K.

2014-01-01

The influence of annealing and tempering temperature on the microstructure and mechanical properties was investigated in a low carbon alloy steel that was processed by a two-step intercritical annealing and intercritical tempering heat treatment. In general, the microstructure of the processed steel comprises intercritical lath-like ferrite, bainitic/martensitic lath and acicular-type retained austenite. The lower intercritical annealing temperature resulted in lower fraction of intercritical ferrite with finer grain size and consequently higher strength. On the other hand, the intercritical tempering temperature significantly influenced retained austenite content and precipitation. High fraction of retained austenite was obtained at a temperature slightly above Ac 1 temperature and retained austenite content decreased with increase in tempering temperature. This behavior is attributed to the competition between the enrichment of Mn and Ni and the fraction of reversed austenite. Fine niobium carbide precipitates of size ∼2–6 nm and copper precipitates of size range ∼10–30 nm were obtained. The optimal intercritical annealing and tempering temperatures to obtain the product of tensile strength and elongation % of ∼30 GPa% were 780 °C and 660 °C, respectively and the volume fraction of retained austenite was ∼29%

The Effect of Annealing at 15000C on Migration and Release of Ion Implanted Silver in CVD Silicon Carbide

International Nuclear Information System (INIS)

HJ MacLean; RG Ballinger; LE Kolaya; SA Simonson; N Lewis; M Hanson

2004-01-01

The transport of silver in CVD β-SiC has been studied using ion implantation. Silver ions were implanted in β-SiC using the ATLAS accelerator facility at the Argonne National Laboratory. Ion beams with energies of 93 and 161 MeV were used to achieve deposition with peak concentrations at depths of approximately 9 and 13 (micro)m, respectively. As-implanted samples were then annealed at 1500 C for 210 or 480 hours. XPS, SEM, TEM, STEM, and optical methods were used to analyze the material before and after annealing. Silver concentration profiles were determined using XPS before and after annealing. STEM and SEM equipped with quantitative chemical analysis capability were used to more fully characterize the location and morphology of the silver before and after annealing. The results show that, within the uncertainty of measurement techniques, there is no silver migration, via either inter- or intragrannular paths, for the times and temperature studied. Additionally, the silver was observed to phase separate within the SiC after annealing. The irradiation damage from the implantation process resulted in a three-layer morphology in the as-implanted condition: (1) a layer of unaltered SiC, followed by (2) a layer of crystallized SiC, followed by (3) an amorphized layer which contained essentially all of the implanted silver. After annealing the layer structure changed. Layer 1 was unaltered. The grains in layer 2 recrystallized to form an epitaxial (columnar) layer. Layer 3 recrystallized to form a fine grain equiaxed layer. The results of this work do not support the long held assumption that silver release from CVD SiC, used for gas-reactor coated particle fuel, is dominated by grain boundary diffusion

Tritium and helium-3 in metals

International Nuclear Information System (INIS)

Lasser, R.

1989-01-01

The book surveys recent results on the behaviour of tritium and its decay product helium-3 metals. In contrast to many earlier books which discuss the properties of the stable hydrogen isotopes without mentioning tritium, this book reviews mainly the results on tritium in metals. Due to the difficulties in preparing metal tritide samples, very important quantities such as diffusivity, superconductivity, solubility, etc. have only been determined very recently. The book not only presents the measured tritium data, but also the isotopic dependency of the different physical properties by comparing H, D and T results. A chapter is devoted to helium-3 in metals. Aspects such as helium release, generation of helium bubbles, swelling, and change of the lattice parameter upon aging are discussed. The book provides the reader with up-to-date information and deep insight into the behaviour of H, D, T and He-3 in metals. Further important topics such a tritium production, its risks, handling and discharge to the environment are also addressed

Post-annealing effects on shallow-junction characteristics caused by 20 keV BGe molecular ion implantation

International Nuclear Information System (INIS)

Liang, J.H.; Sang, Y.J.; Wang, C.-H.; Wang, T.W.; Hsu, J.Y.; Niu, H.; Tseng, M.S.

2005-01-01

This study examines the post-annealing-dependent behaviors of the shallow junction produced by implanting 10 15 cm -2 20 keV BGe ions into n-type silicon specimens. Post-annealing treatments consisted of one- and two-step annealing including both furnace annealing (FA) and rapid thermal annealing (RTA). Comparison of the one-step FA at 550 deg. C and the one-step RTA at 1050 deg. C revealed that boron depth profiles were slightly diffused in the former but exhibited considerable transient-enhanced diffusion (TED) in the latter. However, both the one-step FA- and RTA-annealed germanium depth profiles barely diffused, while the latter diffusing slightly deeper than the former. The optimum value of junction depth (x j ) times sheet resistance (R s ) was obtained with one-step FA at 550 deg. C for 1 h. The two-step annealing (FA at 550 deg. C and RTA at 1050 deg. C) results showed that the RTA-induced TED in the boron depth profiles could be effectively retarded only when FA took place for more than 3 h. Again, germanium depth profiles are also barely diffused while the corresponding TEDs were larger than those in one-step FA but smaller than those in one-step RTA. Furthermore, the two-step annealing of FA at 550 deg. C for 3 h followed by RTA at 1050 deg. C for 30 s is suggested when attempting to obtain an optimum value of x j R s

Structure–mechanical property relationship in a high strength low carbon alloy steel processed by two-step intercritical annealing and intercritical tempering

Energy Technology Data Exchange (ETDEWEB)

Zhou, W.H. [School of Materials Science and Engineering, University of Science and Technology, Beijing (China); Laboratory for Excellence in Advanced Steel Research, Center for Structural and Functional Materials, Institute for Material Research and Innovation, University of Louisiana at Lafayette, P.O. Box 44130, Lafayette, LA 70503 (United States); Wang, X.L. [School of Materials Science and Engineering, University of Science and Technology, Beijing (China); Venkatsurya, P.K.C. [Laboratory for Excellence in Advanced Steel Research, Center for Structural and Functional Materials, Institute for Material Research and Innovation, University of Louisiana at Lafayette, P.O. Box 44130, Lafayette, LA 70503 (United States); Guo, H. [School of Materials Science and Engineering, University of Science and Technology, Beijing (China); Shang, C.J., E-mail: cjshang@ustb.edu.cn [School of Materials Science and Engineering, University of Science and Technology, Beijing (China); Misra, R.D.K. [Laboratory for Excellence in Advanced Steel Research, Center for Structural and Functional Materials, Institute for Material Research and Innovation, University of Louisiana at Lafayette, P.O. Box 44130, Lafayette, LA 70503 (United States)

2014-06-01

The influence of annealing and tempering temperature on the microstructure and mechanical properties was investigated in a low carbon alloy steel that was processed by a two-step intercritical annealing and intercritical tempering heat treatment. In general, the microstructure of the processed steel comprises intercritical lath-like ferrite, bainitic/martensitic lath and acicular-type retained austenite. The lower intercritical annealing temperature resulted in lower fraction of intercritical ferrite with finer grain size and consequently higher strength. On the other hand, the intercritical tempering temperature significantly influenced retained austenite content and precipitation. High fraction of retained austenite was obtained at a temperature slightly above Ac{sub 1} temperature and retained austenite content decreased with increase in tempering temperature. This behavior is attributed to the competition between the enrichment of Mn and Ni and the fraction of reversed austenite. Fine niobium carbide precipitates of size ∼2–6 nm and copper precipitates of size range ∼10–30 nm were obtained. The optimal intercritical annealing and tempering temperatures to obtain the product of tensile strength and elongation % of ∼30 GPa% were 780 °C and 660 °C, respectively and the volume fraction of retained austenite was ∼29%.

Determination of occluded helium and oxygen in irradiated borosilicate glass samples

International Nuclear Information System (INIS)

Ramanjaneyulu, P.S.; Kulkarni, A.S.; Shrivastava, K.C.; Yadav, C.S.; Saxena, M.K.; Tomar, B.S.; Ramakumar, K.L.; Shah, J.G.

2015-01-01

Occluded gases in irradiated borosilicate glass were determined at 573, 873 and 1273 K for understanding the radiation damage in glass matrix. Hot vacuum extraction coupled with a quadrupole mass spectrometer technique was employed for the measurements. Relative sensitivity factors of various gases in QMS system were also determined and used for gas composition calculations. At 573 K only helium was found to get released whereas at 873 and 1273 K both helium and oxygen were released with major fraction of oxygen. (author)

One-step synthesis of magnetic chitosan for controlled release of 5-hydroxytryptophan

Energy Technology Data Exchange (ETDEWEB)

Santos Menegucci, Jucély dos; Santos, Mac-Kedson Medeiros Salviano; Dias, Diego Juscelino Santos; Chaker, Juliano Alexandre; Sousa, Marcelo Henrique, E-mail: mhsqui@gmail.com

2015-04-15

In this work, nanoparticles of chitosan embedded with 25% (w/w) of iron oxide magnetic nanoparticles (magnetite/maghemite) with narrow size-distribution and with a loading efficiency of about 80% for 5-hydroxytryptophan (5-HTP), which is a chemical precursor in the biosynthesis of important neurotransmitters as serotonin, were synthesized with an initial mass ratio of 5-HTP/magnetic chitosan=1.2, using homogeneous precipitation by urea decomposition, in an efficient one-step procedure. Characterization of morphology, structure and surface were performed by XRD, TEM, FTIR, TGA, magnetization and zeta potential measurements, while drug loading and drug releasing were investigated using UV–vis spectroscopy. Kinetic drug release experiments under different pH conditions revealed a pH-sensitivecontrolled-release system, ruled by polymer swelling and/or particle dissolution. - Highlights: • One-step synthesis and incorporation of drug in magnetic chitosan. • Synthesis utilizes a cost-effective and environmentally friendly procedure. • Narrow size distribution of magnetic nanoparticles in the composite. • Composite is a basis for a magnetic pH triggered drug release system.

Effects of annealing on the physical properties of therapeutic proteins during freeze drying process.

Science.gov (United States)

Lim, Jun Yeul; Lim, Dae Gon; Kim, Ki Hyun; Park, Sang-Koo; Jeong, Seong Hoon

2018-02-01

Effects of annealing steps during the freeze drying process on etanercept, model protein, were evaluated using various analytical methods. The annealing was introduced in three different ways depending on time and temperature. Residual water contents of dried cakes varied from 2.91% to 6.39% and decreased when the annealing step was adopted, suggesting that they are directly affected by the freeze drying methods Moreover, the samples were more homogenous when annealing was adopted. Transition temperatures of the excipients (sucrose, mannitol, and glycine) were dependent on the freeze drying steps. Size exclusion chromatography showed that monomer contents were high when annealing was adopted and also they decreased less after thermal storage at 60°C. Dynamic light scattering results exhibited that annealing can be helpful in inhibiting aggregation and that thermal storage of freeze-dried samples preferably induced fragmentation over aggregation. Shift of circular dichroism spectrum and of the contents of etanercept secondary structure was observed with different freeze drying steps and thermal storage conditions. All analytical results suggest that the physicochemical properties of etanercept formulation can differ in response to different freeze drying steps and that annealing is beneficial for maintaining stability of protein and reducing the time of freeze drying process. Copyright © 2017 Elsevier B.V. All rights reserved.

Interdiffusion of krypton and xenon in high-pressure helium

International Nuclear Information System (INIS)

Campana, R.J.; Jensen, D.D.; Epstein, B.D.; Hudson, R.G.; Baldwin, N.L.

1980-01-01

The interdiffusion of gaseous fission products in high-pressure helium is an important factor in the control of radioactivity in gas-cooled fast breeder reactors (GCFRs). As presently conceived, GCFRs use pressure-equalized and vented fuel in which fission gases released from the solid matrix oxide fuel are transported through the fuel rod interstices and internal fission product traps to the fuel assembly vents, where they are swept away to external traps and storage. Since the predominant transport process under steady-state operating conditions is interdiffusion of gaseous fission products in helium, the diffusion properties of krypton-helium and xenon-helium couples have been measured over the range of GCFR temperature and pressure conditions ( -1 ) and expected temperature dependence to the 1.66 power (Tsup(1.66)) at lower pressures and temperatures. Additional work is in progress to measure the behaviour of the krypton-helium and xenon-helium couples in GCFR fuel rod charcoal delay traps. (author)

Helium behaviour in nuclear glasses

International Nuclear Information System (INIS)

Fares, T.

2011-01-01

The present thesis focuses on the study of helium behavior in R7T7 nuclear waste glass. Helium is generated by the minor actinides alpha decays incorporated in the glass matrix. Therefore, four types of materials were used in this work. These are non radioactive R7T7 glasses saturated with helium under pressure, glasses implanted with 3 He + ions, glasses doped with curium and glasses irradiated in nuclear reactor. The study of helium solubility in saturated R7T7 glass has shown that helium atoms are inserted in the glass free volume. The results yielded a solubility of about 10 16 at. cm -3 atm. -1 . The incorporation limit of helium in this type of glass has been determined; its value amounted to about 2*10 21 at. cm -3 , corresponding to 2.5 at.%. Diffusion studies have shown that the helium migration is controlled by the single population dissolved in the glass free volume. An ideal diffusion model was used to simulate the helium release data which allowed to determine diffusion coefficients obeying to the following Arrhenius law: D = D 0 exp(-E a /kBT), where D 0 = 2.2*10 -2 and 5.4*10 -3 cm 2 s -1 and E a = 0.61 eV for the helium saturated and the curium doped glass respectively. These results reflect a thermally activated diffusion mechanism which seems to be not influenced by the glass radiation damage and helium concentrations studied in the present work (up to 8*10 19 at. g -1 , corresponding to 0.1 at.%). Characterizations of the macroscopic, structural and microstructural properties of glasses irradiated in nuclear reactor did not reveal any impact associated with the presence of helium at high concentrations. The observed modifications i.e. a swelling of 0.7 %, a decrease in hardness by 38 %, an increase between 8 and 34 % of the fracture toughness and a stabilization of the glass structure under irradiation, were attributed to the glass nuclear damage induced by the irradiation in reactor. Characterizations by SEM and TEM of R7T7 glasses implanted

Resistivity behavior in isothermal annealing of Pd-H(D) alloys around 50 K

International Nuclear Information System (INIS)

Yamakawa, Kohji; Maeta, Hiroshi

2004-01-01

The behavior of electrical resistivity during hydrogen (deuterium) ordering is investigated for Pd-H(D) alloys of various hydrogen concentrations around 50 K. The disordered hydrogen (deuterium) atoms are introduced by quenching from 100 K into liquid helium immediately before isothermal annealings. The disordered atoms order by migration of the atoms during the heating-up of the specimens. On the isothermal curves of the resistivity in the high temperature range, the resistivity increases at first and then adopts a constant value dependent on the annealing temperature. On the other hand, the resistivity increases and then decreases during isothermal annealing in the low temperature range, nevertheless the ordering is progressing. The annealing time, at which the resistivity maximum appears, and the resistivity value of the maximum increase with decreasing annealing temperature. Furthermore, the decreasing resistivity after the maximum saturates to a value dependent on each annealing temperature. Therefore, it becomes clear that an equilibrium amount of ordering depends on the temperature and the resistivity increases in the early stage of hydrogen (deuterium) ordering and decreases in the later stage. The resistivity maximum in the isothermal annealing curve is caused by the nucleation and growth of ordered domains of hydrogen (deuterium) atoms

Photoionization of helium dimers; Photoionisation von Heliumdimeren

Energy Technology Data Exchange (ETDEWEB)

Havermeier, Tilo

2010-06-09

The helium dimer is one of the most weakly bound systems in the universe. This makes it an interesting quantum mechanical object for investigation. These Van der Waals Clusters can be produced in an expansion of a cryogenic gas jet through a small nozzle into vacuum. In the present experiment we examine the interaction of He dimers with synchrotron radiation at an energy range from 64 to 78 eV. We observed different pathways leading to single ionization of both He atoms of the dimer compound. This two close standing ions begin now to dissociate in cause of their coulomb potential. All charged fragments were detected in coincidence with a COLTRIMS system. Especially Interatomic Coulombic Decay (ICD) and the two step process (TS1) were clearly identified. Furthermore a distribution of the internuclear distance was obtained from the measured Kinetic Energy Release (KER). (orig.)

Control of O-H bonds at a-IGZO/SiO2 interface by long time thermal annealing for highly stable oxide TFT

Directory of Open Access Journals (Sweden)

Jae Kwon Jeon

2017-12-01

Full Text Available We report two-step annealing, high temperature and sequent low temperature, for amorphous indium-gallium-zinc-oxide (a-IGZO thin-film transistor (TFT to improve its stability and device performance. The annealing is carried out at 300 oC in N2 ambient for 1 h (1st step annealing and then at 250 oC in vacuum for 10 h (2nd step annealing. It is found that the threshold voltage (VTH changes from 0.4 V to -2.0 V by the 1st step annealing and to +0.6 V by 2nd step annealing. The mobility changes from 18 cm2V-1s-1 to 25 cm2V-1s-1 by 1st step and decreases to 20 cm2V-1s-1 by 2nd step annealing. The VTH shift by positive bias temperature stress (PBTS is 3.7 V for the as-prepared TFT, and 1.7 V for the 1st step annealed TFT, and 1.3 V for the 2nd step annealed TFT. The XPS (X-ray photoelectron spectroscopy depth analysis indicates that the reduction in O-H bonds at the top interface (SiO2/a-IGZO by 2nd step annealing appears, which is related to the positive VTH shift and smaller VTH shift by PBTS.

Control of O-H bonds at a-IGZO/SiO2 interface by long time thermal annealing for highly stable oxide TFT

Science.gov (United States)

Jeon, Jae Kwon; Um, Jae Gwang; Lee, Suhui; Jang, Jin

2017-12-01

We report two-step annealing, high temperature and sequent low temperature, for amorphous indium-gallium-zinc-oxide (a-IGZO) thin-film transistor (TFT) to improve its stability and device performance. The annealing is carried out at 300 oC in N2 ambient for 1 h (1st step annealing) and then at 250 oC in vacuum for 10 h (2nd step annealing). It is found that the threshold voltage (VTH) changes from 0.4 V to -2.0 V by the 1st step annealing and to +0.6 V by 2nd step annealing. The mobility changes from 18 cm2V-1s-1 to 25 cm2V-1s-1 by 1st step and decreases to 20 cm2V-1s-1 by 2nd step annealing. The VTH shift by positive bias temperature stress (PBTS) is 3.7 V for the as-prepared TFT, and 1.7 V for the 1st step annealed TFT, and 1.3 V for the 2nd step annealed TFT. The XPS (X-ray photoelectron spectroscopy) depth analysis indicates that the reduction in O-H bonds at the top interface (SiO2/a-IGZO) by 2nd step annealing appears, which is related to the positive VTH shift and smaller VTH shift by PBTS.

Evaluating tamsulosin hydrochloride-released microparticles prepared using single-step matrix coating.

Science.gov (United States)

Maeda, Atsushi; Shinoda, Tatsuki; Ito, Naoki; Baba, Keizo; Oku, Naoto; Mizumoto, Takao

2011-04-15

The objective of the present study was to determine the optimum composition for sustained-release of tamsulosin hydrochloride from microparticles intended for orally disintegrating tablets. Microparticles were prepared from an aqueous ethylcellulose dispersion (Aquacoa®), and an aqueous copolymer based on ethyl acrylate and methyl methacrylate dispersion (Eudragit®) NE30D), with microcrystalline cellulose as core particles with a fluidized bed coating process. Prepared microparticles were about 200 μm diameter and spherical. The microparticles were evaluated for in vitro drug release and in vivo absorption to assess bioequivalence in a commercial product, Harnal® pellets. The optimum ratio of Aquacoat® and Eudragit® NE30D in the matrix was 9:1. We observed similar drug release profiles in microparticles and Harnal® pellets. Higuchi model analysis of the in vitro drug release from microparticles was linear up to 80% release, typical of Fickian diffusion sustained-release profile. The in vivo absorption properties from microparticles were comparable to Harnal® pellets, and there was a linear relationship between in vitro drug release and in vivo drug release. In conclusion, this development produces microparticles in single-step coating, that provided a sustained-release of tamsulosin hydrochloride comparable to Harnal® pellets. Copyright © 2011 Elsevier B.V. All rights reserved.

Sintering and annealing effects on undoped yttria transparent ceramics

Energy Technology Data Exchange (ETDEWEB)

Letue, Laetitia; Petit, Johan, E-mail: johan.petit@onera.fr; Ritti, Marie-Hélène; Lalanne, Sylvie; Landais, Stéphane

2017-06-15

Transparent yttrium oxide (Y{sub 2}O{sub 3}) ceramics were processed by several densifications steps without any doping species. The green bodies were obtained by the aqueous way and sintered at high temperature under vacuum and then under high pressure. We studied the effects of different sintering cycles and air annealing at different steps of the process on the density and the grain growth. We also focused on the reaction between yttria ceramics and BN-coated graphite crucible which occurs during HIP. We noted that a low heating rate and two annealing steps are necessary to improve our samples’ transparency. - Highlights: • The quality of transparent ceramics is compared with the tested process parameters. • Air annealing is critical when using a carbon environment in the process. • Intra-granular pores, and so the final transparency, are directly linked to the sintering heating rates.

Effect of the duration of a wet KCN etching step and post deposition annealing on the efficiency of Cu2ZnSnSe4 solar cells

OpenAIRE

Sahayaraj, Sylvester; Brammertz, Guy; Vermang, Bart; Ranjbar, Samaneh; Meuris, Marc; Vleugels, Jef; Poortmans, Jef

2016-01-01

The influence of the duration of the KCN etching step on the efficiency of Cu2ZnSnSe4 (CZTSe) solar cells and Post deposition annealing (PDA) has been explored. CZTSe thin film absorbers prepared by selenization at 450 degrees C were etched by 5 wt% KCN/KOH from 30s up to 360 s before solar cell processing. KCN etching times above 120 s resulted in poor efficiencies. The fill factor (FF) and short circuit current density Jsc) of these devices were affected severely. After annealing the solar ...

Experiments for post accident hydrogen dispersion in F.M. vault using helium

International Nuclear Information System (INIS)

Bajaj, S.S.; Bhattacharyya, D.; Mishra, S.

1994-01-01

Under certain postulated accident scenarios involving a Loss of Coolant Accident (LOCA) simultaneous with impairment of Emergency Core Cooling (ECC), generation of hydrogen due to reaction between the zirconium clad and coolant is predicted in the coolant channel. The hydrogen generated in the coolant channels would eventually get released either in Fuelling Machine (FM) vault or in the pump room atmosphere depending on the location of the break. Analytical studies carried out so far to estimate the time dependent hydrogen concentration in the accident FM Vault consider the entire vault as a single volume. Tests were, therefore, planned to assess the mixing within the FM vault atmosphere with and without the availability of cooling fan units by releasing a known quantity of helium (instead of hydrogen) at selected locations and monitoring the relative concentration of helium in air at various locations. Test was conducted by releasing about 360 1 helium over a period of to 4 minutes at preselected locations and by measuring the relative concentration (leak rates indicated by helium leak detectors) at various locations in the FM vault. The results of cases with fans operating indicate repeatable and consistent trends of good mixing in the vault. For other cases (non turbulent, still condition) the results are sensitive to various factors including orientation of release. The former set of cases (turbulent. fans operating) are more relevant for postulated accident conditions. (author). 1 tab., 18 figs

Helium as a tracer for fluids released from Juan de Fuca lithosphere beneath the Cascadia forearc

Science.gov (United States)

McCrory, Patricia A.; Constantz, James E.; Hunt, Andrew G.; Blair, James Luke

2016-01-01

The ratio between helium isotopes (3He/4He) provides an excellent geochemical tracer for investigating the sources of fluids sampled at the Earth's surface. 3He/4He values observed in 25 mineral springs and wells above the Cascadia forearc document a significant component of mantle-derived helium above Juan de Fuca lithosphere, as well as variability in 3He enrichment across the forearc. Sample sites arcward of the forearc mantle corner (FMC) generally yield significantly higher ratios (1.2-4.0 RA) than those seaward of the corner (0.03-0.7 RA). The highest ratios in the Cascadia forearc coincide with slab depths (40-45 km) where metamorphic dehydration of young oceanic lithosphere is expected to release significant fluid and where tectonic tremor occurs, whereas little fluid is expected to be released from the slab depths (25-30 km) beneath sites seaward of the corner.Tremor (considered a marker for high fluid pressure) and high RA values in the forearc are spatially correlated. The Cascadia tremor band is centered on its FMC, and we tentatively postulate that hydrated forearc mantle beneath Cascadia deflects a significant portion of slab-derived fluids updip along the subduction interface, to vent in the vicinity of its corner. Furthermore, high RA values within the tremor band just arcward of the FMC, suggest that the innermost mantle wedge is relatively permeable.Conceptual models require: (1) a deep fluid source as a medium to transport primordial 3He; (2) conduits through the lithosphere which serve to speed fluid ascent to the surface before significant dilution from radiogenic 4He can occur; and (3) near lithostatic fluid pressure to keep conduits open. Our spatial correlation between high RA values and tectonic tremor provides independent evidence that tremor is associated with deep fluids, and it further suggests that high pore pressures associated with tremor may serve to keep fractures open for 3He migration through ductile upper mantle and lower crust.

Study on the behavior of irradiated light water reactor fuel during out-of-pile annealing

International Nuclear Information System (INIS)

Yanagisawa, Kazuaki; Kanazawa, Hiroyuki; Uno, Hisao; Sasajima, Hideo

1988-11-01

Using the pre-irradiated light water reactor fuel (burnup: 35 MWd/kgU) and the slightly irradiated NSRR fuel (burnup: 5.6 x 10 -6 MWd/kgU), FP gas release rate up to the temperature of 2273 K was measured through out-of-pile annealing test. Results of this experiment were compared with those of ORNL annealing test (SFD/HI-test series) performed in USA. Obtained conclusions are: (1) Maximum release rate of Kr gas in light water reactor fuel was 6.4 % min -1 at temperature of 2273 K. This was in good agreement with ORNL data. FP gas release rate during annealing test was increased greatly with increasing fuel burnup and annealing temperature. (2) No FP was detected in NSRR slightly irradiated fuel up to the temperature of 1913 K. (author)

Effects of alloying elements on thermal desorption of helium in Ni alloys

International Nuclear Information System (INIS)

Xu, Q.; Cao, X.Z.; Sato, K.; Yoshiie, T.

2012-01-01

It is well known that the minor elements Si and Sn can suppress the formation of voids in Ni alloys. In the present study, to investigate the effects of Si and Sn on the retention of helium in Ni alloys, Ni, Ni–Si, and Ni–Sn alloys were irradiated by 5 keV He ions at 723 K. Thermal desorption spectroscopy (TDS) was performed at up to 1520 K, and microstructural observations were carried out to identify the helium trapping sites during the TDS analysis. Two peaks, at 1350 and 1457 K, appeared in the TDS spectrum of Ni. On the basis of the microstructural observations, the former peak was attributed to the release of trapped helium from small cavities and the latter to its release from large cavities. Small-cavity helium trapping sites were also found in the Ni–Si and Ni–Sn alloys, but no large cavities were observed in these alloys. In addition, it was found that the oversized element Sn could trap He atoms in the Ni–Sn alloy.

Effects of alloying elements on thermal desorption of helium in Ni alloys

Energy Technology Data Exchange (ETDEWEB)

Xu, Q., E-mail: xu@rri.kyoto-u.ac.jp [Research Reactor Institute, Kyoto University, Osaka 590-0494 (Japan); Cao, X.Z.; Sato, K.; Yoshiie, T. [Research Reactor Institute, Kyoto University, Osaka 590-0494 (Japan)

2012-12-15

It is well known that the minor elements Si and Sn can suppress the formation of voids in Ni alloys. In the present study, to investigate the effects of Si and Sn on the retention of helium in Ni alloys, Ni, Ni-Si, and Ni-Sn alloys were irradiated by 5 keV He ions at 723 K. Thermal desorption spectroscopy (TDS) was performed at up to 1520 K, and microstructural observations were carried out to identify the helium trapping sites during the TDS analysis. Two peaks, at 1350 and 1457 K, appeared in the TDS spectrum of Ni. On the basis of the microstructural observations, the former peak was attributed to the release of trapped helium from small cavities and the latter to its release from large cavities. Small-cavity helium trapping sites were also found in the Ni-Si and Ni-Sn alloys, but no large cavities were observed in these alloys. In addition, it was found that the oversized element Sn could trap He atoms in the Ni-Sn alloy.

Effects of alloying elements on thermal desorption of helium in Ni alloys

Science.gov (United States)

Xu, Q.; Cao, X. Z.; Sato, K.; Yoshiie, T.

2012-12-01

It is well known that the minor elements Si and Sn can suppress the formation of voids in Ni alloys. In the present study, to investigate the effects of Si and Sn on the retention of helium in Ni alloys, Ni, Ni-Si, and Ni-Sn alloys were irradiated by 5 keV He ions at 723 K. Thermal desorption spectroscopy (TDS) was performed at up to 1520 K, and microstructural observations were carried out to identify the helium trapping sites during the TDS analysis. Two peaks, at 1350 and 1457 K, appeared in the TDS spectrum of Ni. On the basis of the microstructural observations, the former peak was attributed to the release of trapped helium from small cavities and the latter to its release from large cavities. Small-cavity helium trapping sites were also found in the Ni-Si and Ni-Sn alloys, but no large cavities were observed in these alloys. In addition, it was found that the oversized element Sn could trap He atoms in the Ni-Sn alloy.

One - step nanosecond laser microstructuring, sulfur hyperdoping, and annealing of silicon surfaces in liquid carbondisulfide

Science.gov (United States)

Van Luong, Nguyen; Danilov, P. A.; Ionin, A. A.; Khmel'nitskii, P. A.; Kudryashov, S. I.; Mel'nik, N. N.; Saraeva, I. N.; Смirnov, H. A.; Rudenko, A. A.; Zayarny, D. A.

2017-09-01

We perform a single-shot IR nanosecond laser processing of commercial silicon wafers in ambient air and under a 2 mm thick carbon disulfide liquid layer. We characterize the surface spots modified in the liquid ambient and the spots ablated under the same conditions in air in terms of its surface topography, chemical composition, band-structure modification, and crystalline structure by means of SEM and EDX microscopy, as well as of FT-IR and Raman spectroscopy. These studies indicate that single-step microstructuring and deep (up to 2-3% on the surface) hyperdoping of the crystalline silicon in its submicron surface layer, preserving via pulsed laser annealing its crystallinity and providing high (103 - 104 cm-1) spectrally at near- and mid-IR absorption coefficients, can be obtained in this novel approach, which is very promising for thin - film silicon photovoltaic devices

Anneal-induced transformations in the transport and magnetic properties of CoCu granulars

International Nuclear Information System (INIS)

Miranda, M.G.M.; Antunes, A.B.; Bracho Rodriguez, G.J.; Baibich, M.N.

2001-01-01

The electrical and magnetic properties of granular Co 5 Cu 95 , Co 10 Cu 90 and Co 15 Cu 85 ribbons treated with different annealing procedures were measured from helium to room temperatures. The isochronous anneals had fixed heating rate and the transformations were followed by 'in situ' resistivity measurements. We found that the transformation occurs at nearly the same region of temperature for the three compositions. Besides, our results for magnetoresistance on Co 10 Cu 90 could be understood in the light of the re-dissolution of Co into the Cu matrix, as suggested in previous works (Miranda et al., J. Magn. Magn. Mater. 185 (1998) 331; da Silva et al., IEEE Trans. Mag., to appear)

Annealing behavior of alpha recoil tracks in phlogopite

International Nuclear Information System (INIS)

Gao Shaokai; Yuan Wanming; Dong Jinquan; Bao Zengkuan

2005-01-01

Alpha recoil tracks (ARTs) formed during the a-decay of U, Th as well as their daughter nuclei are used as a new dating method which is to some extent a complementarity of fission track dating due to its ability to determine the age of young mineral. ARTs can be observable under phase-contrast interference microscope through chemical etching. In order to study the annealing behavior of ARTs in phlogopite, two methods of annealing experiments were executed. Samples were annealed in the electronic tube furnace at different temperatures ranging from 250 degree C to 450 degree C in steps of 50 degree C. For any given annealing temperature, different annealing times were used until total track fading were achieved. It is found that ARTs anneal much more easily than fission tracks, the annealing ratio increase non-linearly with annealing time and temperature. Using the Arrhenius plot, an activation energy of 0.68ev is finally found for 100% removal of ARTs, which is less than the corresponding value for fission tracks (FTs). Through extending the annealing time to geological time, a much lower temperature range of the sample's cooling history can be got.

Effect of 3.0 MeV helium implantation on electrical characteristics of 4H-SiC BJTs

International Nuclear Information System (INIS)

Usman, Muhammad; Hallen, Anders; Ghandi, Reza; Domeij, Martin

2010-01-01

Degradation of 4H-SiC power bipolar junction transistors (BJTs) under the influence of a high-energy helium ion beam was studied. Epitaxially grown npn BJTs were implanted with 3.0 MeV helium in the fluence range of 10 10 -10 11 cm -2 . The devices were characterized by their current-voltage (I-V) behaviour before and after the implantation, and the results showed a clear degradation of the output characteristics of the devices. Annealing these implanted devices increased the interface traps between passivation oxide and the semiconductor, resulting in an increase of base current in the low-voltage operation range.

Release characteristics of tritium from high-purity lithium oxide

International Nuclear Information System (INIS)

O'Kula, K.R.; Vogelsang, W.F.

1985-01-01

Rates of tritium release from neutronirradiated lithium oxide were determined from isothermal release experiments. High-purity, monocrystalline lithium oxide was purged ex-reactor with helium and helium-hydrogen gas streams. Overall release was found to be controlled by solid-phase diffusion, and was predominantly in the form of condensible species. The result of an independent concentration profile analysis at 923 K was in agreement with the gas release diffusion coefficient. Sweeping the Li 2 O with hydrogen-containing gas was found to enhance tritium removal during the early stage of each run

Commercial helium reserves, continental rifting and volcanism

Science.gov (United States)

Ballentine, C. J.; Barry, P. H.; Hillegonds, D.; Fontijn, K.; Bluett, J.; Abraham-James, T.; Danabalan, D.; Gluyas, J.; Brennwald, M. S.; Pluess, B.; Seneshens, D.; Sherwood Lollar, B.

2017-12-01

Helium has many industrial applications, but notably provides the unique cooling medium for superconducting magnets in medical MRI scanners and high energy beam lines. In 2013 the global supply chainfailed to meet demand causing significant concern - the `Liquid Helium Crisis' [1]. The 2017 closure of Quatar borders, a major helium supplier, is likely to further disrupt helium supply, and accentuates the urgent need to diversify supply. Helium is found in very few natural gas reservoirs that have focused 4He produced by the dispersed decay (a-particle) of U and Th in the crust. We show here, using the example of the Rukwa section of the Tanzanian East African Rift, how continental rifting and local volcanism provides the combination of processes required to generate helium reserves. The ancient continental crust provides the source of 4He. Rifting and associated magmatism provides the tectonic and thermal mechanism to mobilise deep fluid circulation, focusing flow to the near surface along major basement faults. Helium-rich springs in the Tanzanian Great Rift Valley were first identified in the 1950's[2]. The isotopic compositions and major element chemistry of the gases from springs and seeps are consistent with their release from the crystalline basement during rifting [3]. Within the Rukwa Rift Valley, helium seeps occur in the vicinity of trapping structures that have the potential to store significant reserves of helium [3]. Soil gas surveys over 6 prospective trapping structures (1m depth, n=1486) show helium anomalies in 5 out of the 6 at levels similar to those observed over a known helium-rich gas reservoir at 1200m depth (7% He - Harley Dome, Utah). Detailed macroseep gas compositions collected over two days (n=17) at one site allows us to distinguish shallow gas contributions and shows the deep gas to contain between 8-10% helium, significantly increasing resource estimates based on uncorrected values (1.8-4.2%)[2,3]. The remainder of the deep gas is

Determination of end-of-life-failure fractions of HTGR-fuel particles by postirradiation annealing and beta autoradiography

International Nuclear Information System (INIS)

Thiele, B.A.; Herren, M.

1978-11-01

Fission-product contamination of the helium coolant of High-Temperature Gas-Cooled Reactors (HTGR) is strongly influenced by the end-of-life (EOL) failed-particle fraction. Knowledge of the EOL-failure fraction is the basis for model calculations to predict the total fission product release from the reactor core. After disintegration of irradiation fuel rods, fuel particles are placed in individual holes of a graphite tray. During a 5-h heat treatment at 1000 0 C in a helium atmosphere failed particles leak fission products, especially the volatile cesium, into the graphite. After unloading a β-autoradiograph of the tray is made. Holes that housed defective particles are identified from black spots on the β-sensitive film. The EOL-failure fraction is the ratio of defective particles to the total number of particles tested. The technique is called PIAA, PostIrradiation Annealing and Autoradiography. The PIAA technique was applied to particles of a Trisocoated highly-enriched UO 2 fissile batch irradiated to a burnup of 35% FIMA at an irradiation temperature of 1250 0 C. Visual examination showed all particles to be intact. From 11 to 47% of the particles had failed, as determined by PIAA. Further, postirradiation examination showed that localized corrosion of the silicon carbide coating by fission-product rare-earth chlorides had occurred

Hydrogen and helium trapping in tungsten deposition layers formed by RF plasma sputtering

International Nuclear Information System (INIS)

Kazunari Katayama; Kazumi Imaoka; Takayuki Okamura; Masabumi Nishikawa

2006-01-01

Understanding of tritium behavior in plasma facing materials is an important issue for fusion reactor from viewpoints of fuel control and radiation safety. Tungsten is used as a plasma facing material in the divertor region of ITER. However, investigation of hydrogen isotope behavior in tungsten deposition layer is not sufficient so far. It is also necessary to evaluate an effect of helium on a formation of deposition layer and an accumulation of hydrogen isotopes because helium generated by fusion reaction exists in fusion plasma. In this study, tungsten deposition layers were formed by sputtering method using hydrogen and helium RF plasma. An erosion rate and a deposition rate of tungsten were estimated by weight measurement. Hydrogen and helium retention were investigated by thermal desorption method. Tungsten deposition was performed using a capacitively-coupled RF plasma device equipped with parallel-plate electrodes. A tungsten target was mounted on one electrode which is supplied with RF power at 200 W. Tungsten substrates were mounted on the other electrode which is at ground potential. The plasma discharge was continued for 120 hours where pressure of hydrogen or helium was controlled to be 10 Pa. The amounts of hydrogen and helium released from deposition layers was quantified by a gas chromatograph. The erosion rate of target tungsten under helium plasma was estimated to be 1.8 times larger than that under hydrogen plasma. The deposition rate on tungsten substrate under helium plasma was estimated to be 4.1 times larger than that under hydrogen plasma. Atomic ratio of hydrogen to tungsten in a deposition layer formed by hydrogen plasma was estimated to be 0.17 by heating to 600 o C. From a deposition layer formed by helium plasma, not only helium but also hydrogen was released by heating to 500 o C. Atomic ratios of helium and hydrogen to tungsten were estimated to be 0.080 and 0.075, respectively. The trapped hydrogen is probably impurity hydrogen

The effect of humidity on annealing of polymer optical fibre bragg gratings

DEFF Research Database (Denmark)

Woyessa, Getinet; Nielsen, Kristian; Bang, Ole

2015-01-01

The effect of humidity on annealing of PMMA based microstructured polymer optical fiber (mPOF) Bragg gratings is studied. Polymer optical fibers (POFs) are annealed in order to release stress formed during the fabrication process. Un-annealed fibers will have high hysteresis and low sensitivity...... to humidity, particularly when operated at high temperature. Typically annealing of PMMA POFs is done at 80oC in an oven with no humidity control and therefor at low humidity. The response to humidity of PMMA FBGs annealed at different levels of humidity at the same temperature has also been studied. PMMA...

Dynamics of Superfluid Helium in Low-Gravity

Science.gov (United States)

Frank, David J.

1997-01-01

This report summarizes the work performed under a contract entitled 'Dynamics of Superfluid Helium in Low Gravity'. This project performed verification tests, over a wide range of accelerations of two Computational Fluid Dynamics (CFD) codes of which one incorporates the two-fluid model of superfluid helium (SFHe). Helium was first liquefied in 1908 and not until the 1930s were the properties of helium below 2.2 K observed sufficiently to realize that it did not obey the ordinary physical laws of physics as applied to ordinary liquids. The term superfluidity became associated with these unique observations. The low temperature of SFHe and it's temperature unifonrmity have made it a significant cryogenic coolant for use in space applications in astronomical observations with infrared sensors and in low temperature physics. Superfluid helium has been used in instruments such as the Shuttle Infrared Astronomy Telescope (IRT), the Infrared Astronomy Satellite (IRAS), the Cosmic Background Observatory (COBE), and the Infrared Satellite Observatory (ISO). It is also used in the Space Infrared Telescope (SIRTF), Relativity Mission Satellite formally called Gravity Probe-B (GP-B), and the Test of the Equivalence Principle (STEP) presently under development. For GP-B and STEP, the use of SFHE is used to cool Superconducting Quantum Interference Detectors (SQUIDS) among other parts of the instruments. The Superfluid Helium On-Orbit Transfer (SHOOT) experiment flown in the Shuttle studied the behavior of SFHE. This experiment attempted to get low-gravity slosh data, however, the main emphasis was to study the low-gravity transfer of SFHE from tank to tank. These instruments carried tanks of SFHE of a few hundred liters to 2500 liters. The capability of modeling the behavior of SFHE is important to spacecraft control engineers who must design systems that can overcome disturbances created by the movement of the fluid. In addition instruments such as GP-B and STEP are very

Effects of homogenization treatment on recrystallization behavior of 7150 aluminum sheet during post-rolling annealing

International Nuclear Information System (INIS)

Guo, Zhanying; Zhao, Gang; Chen, X.-Grant

2016-01-01

The effects of two homogenization treatments applied to the direct chill (DC) cast billet on the recrystallization behavior in 7150 aluminum alloy during post-rolling annealing have been investigated using the electron backscatter diffraction (EBSD) technique. Following hot and cold rolling to the sheet, measured orientation maps, the recrystallization fraction and grain size, the misorientation angle and the subgrain size were used to characterize the recovery and recrystallization processes at different annealing temperatures. The results were compared between the conventional one-step homogenization and the new two-step homogenization, with the first step being pretreated at 250 °C. Al_3Zr dispersoids with higher densities and smaller sizes were obtained after the two-step homogenization, which strongly retarded subgrain/grain boundary mobility and inhibited recrystallization. Compared with the conventional one-step homogenized samples, a significantly lower recrystallized fraction and a smaller recrystallized grain size were obtained under all annealing conditions after cold rolling in the two-step homogenized samples. - Highlights: • Effects of two homogenization treatments on recrystallization in 7150 Al sheets • Quantitative study on the recrystallization evolution during post-rolling annealing • Al_3Zr dispersoids with higher densities and smaller sizes after two-step treatment • Higher recrystallization resistance of 7150 sheets with two-step homogenization

Effects of post-annealing and cobalt co-doping on superconducting properties of (Ca,Pr)Fe{sub 2}As{sub 2} single crystals

Energy Technology Data Exchange (ETDEWEB)

Okada, T., E-mail: 8781303601@mail.ecc.u-tokyo.ac.jp; Ogino, H.; Yakita, H.; Yamamoto, A.; Kishio, K.; Shimoyama, J.

2014-10-15

Highlights: • Post-annealing at 400 °C killed superconductivity for Co-free sample. • Pr,Co co-doped samples maintained superconductivity even after annealing. • Two-step superconducting transition was observed via magnetization measurement. • Bulk superconductivity of low-T{sub c} component was confirmed. • Superconducting volume fraction of high-T{sub c} component was always small. - Abstract: In order to clarify the origin of anomalous superconductivity in (Ca,RE)Fe{sub 2}As{sub 2} system, Pr doped and Pr,Co co-doped CaFe{sub 2}As{sub 2} single crystals were grown by the FeAs flux method. These samples showed two-step superconducting transition with T{sub c1} = 25–42 K, and T{sub c2} < 16 K, suggesting that (Ca,RE)Fe{sub 2}As{sub 2} system has two superconducting components. Post-annealing performed for these crystals in evacuated quartz ampoules at various temperatures revealed that post-annealing at ∼400 °C increased the c-axis length for all samples. This indicates that as-grown crystals have a certain level of strain, which is released by post-annealing at ∼400 °C. Superconducting properties also changed dramatically by post-annealing. After annealing at 400 °C, some of the co-doped samples showed large superconducting volume fraction corresponding to the perfect diamagnetism below T{sub c2} and high J{sub c} values of 10{sup 4}–10{sup 5} A cm{sup −2} at 2 K in low field, indicating the bulk superconductivity of (Ca,RE)Fe{sub 2}As{sub 2} phase occurred below T{sub c2}. On the contrary, the superconducting volume fraction above T{sub c2} was always very small, suggesting that 40 K-class superconductivity observed in this system is originating in the local superconductivity in the crystal.

Evolution of microstructure at hot band annealing of ferritic FeSi steels

Energy Technology Data Exchange (ETDEWEB)

Schneider, Jürgen, E-mail: juergen.schneider@t-online.de [Institute of Metal Forming, Technische Universität Bergakademie Freiberg, Bernhard-von Cotta-Str. 4, D-09596 Freiberg (Germany); Stahlzentrum Freiberg e.V., Leipziger Straße 34, D-09599 Freiberg (Germany); Li, Guangqiang [State Key Lab. of Refractories and Metallurgy, Wuhan University of Science and Technology, No. 947 Heping Avenue, Qingshan District, Wuhan 430081 (China); Franke, Armin [Stahlzentrum Freiberg e.V., Leipziger Straße 34, D-09599 Freiberg (Germany); Zhou, Bowen [State Key Lab. of Refractories and Metallurgy, Wuhan University of Science and Technology, No. 947 Heping Avenue, Qingshan District, Wuhan 430081 (China)

2017-02-15

The magnetic properties of the finally fabricated nonoriented FeSi steels critically depend on the microstructure and on the occurring crystallographic texture. The fabrication route comprises hot rolling, coiling and cooling, hot band annealing before cold rolling (optional), cold rolling and the final thermal treatment. As well known there is an interplay between the microstructure and texture during the various processing steps. For that reason, it is of interest to know more on the evolution of the microstructure at hot band annealing of hot band prepared in different ways. In this paper we will summarize our recent results on the evolution of microstructure during thermal annealing of hot band: thermal treatment following immediately the last pass of hot rolling or a hot band annealing as a separate processing step before cold rolling.

Consideration of heat transfer performance of helium-gas/water coolers in HENDEL

International Nuclear Information System (INIS)

Inagaki, Yoshiyuki; Miyamoto, Yoshiaki

1986-10-01

The helium engineering loop (HENDEL) has four helium-gas/water coolers, where the cooling water flows in the tubes and the helium gas flows on the shell side. Their cooling performance depends on mainly the heat transfer of helium gas on the shell side. This report describes the operational data of the coolers and the consideration of the heat transfer performance which is important for the design of coolers. It becomes clear that Donohue's equation is close to the operational data and conservative for the segmental baffle type cooler and preduction by Fishenden-Saunders or Zukauskas' equation is conservation for the step-up baffle type cooler. (author)

Diffuse Helium Emission as a Precursory Sign of Volcanic Unrest

Science.gov (United States)

Padron, E.; Perez, N.; Hernandez Perez, P. A.; Sumino, H.; Melian Rodriguez, G.; Barrancos, J.; Nolasco, D.; Padilla, G.; Dionis, S.; Rodriguez, F.; Hernandez, I.; Calvo, D.; Peraza, M.; Nagao, K.

2012-12-01

Since July 16, 2011, an anomalous seismicity at El Hierro island, the youngest and smallest of the Canary Islands, was recorded by IGN seismic network. After the occurrence of more than 10,000 seismic events, volcanic tremor was recorded since 05:15 of the October 10, by all of the seismic stations on the island, with highest amplitudes recorded in the southernmost station. During the afternoon of October 12 a large light-green coloured area was observed in the sea to the souht of La Restinga village (at the southernmost part of El Hierro island), suggesting the existence of a submarine eruption. Since October 12, frequent episodes of, turbulent gas emission and foaming, and the appearance of steamy lava fragments has been observed on the sea surface. As part of the volcanic surveillance of the island, the Instituto Volcanologico de Canarias (INVOLCAN) geochemical monitoring program is carrying out diffuse helium surveys on the surface environment of El Hierro (soil atmosphere). This nobel gas has been investigated because it has been considered an almost ideal geochemical indicator because it is chemically inert, physically stable, nonbiogenic, sparingly soluble in water under ambient conditions and almost non-adsorbable. At each survey, 600 sampling sites covering the whole island and following an homogeneous distribution are selected for helium measurements in the soil gases, The helium concentration gradients with respect to its value on air (5.24 ppm) allow us to estimate a pure diffusive emission rate of helium throughout the island. The first survey was carried out on the summer of 2003, when the island was on a quiescence period. At this survey, the amount of helium released by the volcanic system of El Hierro was estimated in 6 kg/d. Since the beginning of the seismic unrest, 13 helium emission surveys have been carried out. The helium emission rate has shown an excellent agreement with the evolution of the volcanic crisis of the island, reaching 30 kg

An interbubble fracture mechanism of blister formation on helium-irradiated metals

International Nuclear Information System (INIS)

Evans, J.H.

1977-01-01

This paper describes a new model of surface blister formation in which a blister is nucleated by the interbubble fracture of highly overpressurized helium bubbles. As in other gas-driven models, the internal release of helium then provides the driving force for blister lid deformation. The high pressures required for the suggested mode of fracture are a result of the difficulty, experienced by the bubbles in acquiring vacancies. By considering the bubble growth mechanisms, the critical conditions for interbubble fracture are shown to depend on the helium dose and energy, the bubble size, and their depth in the irradiated material. These parameters and other aspects of blister formation are discussed on the basis of the proposed model. One important result concerns the position of the fracture plane; because of the usual displacement of damage and helium peaks relative to depth, this plane can lie well beyond the helium peak. Thus, the disagreement inherent in previous gas models between helium range and measured blister lid thickness values can be resolved without recourse to lateral stress arguments. (Auth.)

Anneal-induced transformations in the transport and magnetic properties of CoCu granulars

Energy Technology Data Exchange (ETDEWEB)

Miranda, M.G.M. E-mail: mari@if.ufrgs.br; Antunes, A.B.; Bracho Rodriguez, G.J.; Baibich, M.N

2001-05-01

The electrical and magnetic properties of granular Co{sub 5}Cu{sub 95}, Co{sub 10}Cu{sub 90} and Co{sub 15}Cu{sub 85} ribbons treated with different annealing procedures were measured from helium to room temperatures. The isochronous anneals had fixed heating rate and the transformations were followed by 'in situ' resistivity measurements. We found that the transformation occurs at nearly the same region of temperature for the three compositions. Besides, our results for magnetoresistance on Co{sub 10}Cu{sub 90} could be understood in the light of the re-dissolution of Co into the Cu matrix, as suggested in previous works (Miranda et al., J. Magn. Magn. Mater. 185 (1998) 331; da Silva et al., IEEE Trans. Mag., to appear)

Vacancy effects on the formation of helium and krypton cavities in 3-C-SiC irradiated and annealed at elevated temperatures

Energy Technology Data Exchange (ETDEWEB)

Zang, Hang; Liu, Wenbo; Li, Tao; He, Chaohui; Yun, Di; Jiang, Weilin; Devaraj, Arun; Edwards, Danny J.; Henager, Charles H.; Kurtz, Richard J.; Wang, Zhiguang

2017-02-27

Polycrystalline 3C-SiC was sequentially irradiated at 400 and 750°C with 120 keV He²⁺ and 4 MeV Kr¹⁵⁺ ions to 10¹⁷ and 41016 cm^-2, respectively. The Kr¹⁵⁺ ions penetrated the entire depth of the He²⁺ ion implantation region. Three areas of He²⁺, Kr¹⁵⁺ and He²⁺ + Kr¹⁵⁺ ion implanted 3C-SiC were created through masked overlapping irradiations. The sample was subsequently annealed at 1600°C in vacuum and characterized using cross-sectional transmission electron microscopy and energy-dispersive x-ray spectroscopy. Compared to the He²⁺ ion only implanted 3C-SiC, helium cavities in the He²⁺ and Kr15+ co-implanted 3C-SiC had a smaller size but higher density. At 25 dpa, presence of He in the co-implanted 3C-SiC significantly promoted cavity growth; much smaller voids were formed in the Kr¹⁵⁺ ion only irradiated 3C-SiC at the same dose. In addition, local Kr migration and trapping at cavities occurred, but long-range Kr diffusion in 3C-SiC was not observed up to 1600°C.

One step electrodeposition of Cu2ZnSnS4 thin films in a novel bath with sulfurization free annealing

Science.gov (United States)

Tang, Aiyue; Li, Zhilin; Wang, Feng; Dou, Meiling; Pan, Youya; Guan, Jingyu

2017-04-01

Cu2ZnSnS4 (CZTS) is a quaternary kesterite compound with suitable band gap for thin film solar cells. In most electrodeposition-anneal routes, sulfurization is inevitable because the as-deposited film is lack of S. In this work, a novel green electrolyte was designed for synthesizing CZTS thin films with high S content. In the one-step electrodeposition, K4P2O7 and C7H6O6S were added to form complex with metallic ions in the electrolyte, which could attribute to co-deposition. The as-deposited film obtained high S content satisfying stoichiometry. After a sulfurization free annealing, the continuous and uniform CZTS thin film was obtained, which had pure kesterite structure and a suitable band gap of 1.53 eV. Electrodeposition mechanism investigation revealed that the K4P2O7 prevented the excessive deposition of Cu2+ and Sn2+. The C7H6O6S promoted the reduction of Zn2+. So the additives narrowed the co-deposition potentials of the metallic elements through a synergetic effect. They also promoted the reduction of S2O32- to ensure the co-deposition of the four elements and the stoichiometry. The sulfurization free annealing process can promote the commercialization of CZTS films and the successful design principle of environmental friendly electrolytes could be applied in other electrodeposition systems.

Helium solubility and bubble growth in metals under high pressure

International Nuclear Information System (INIS)

Laakmann, J.

1985-07-01

Helium solubility and bubble growth in metals under high pressure polycrystals and single crystals of gold were heated in helium at temperatures between 475 K and 1250 K in a pressure regime of 200 to 2700 bar to measure the solubility of helium in gold. After quenching to room temperature the helium content, measured by mass spectrometry, showed the following properties: 1) A linear dependence of the He solubility on pressure. 2) Thinning of the specimen reduces the helium content by a factor 10 to 100 but does not change the linear pressure dependence. 3) The thermal release of He from thinned polycrystals and single crystals occurs mainly in a single peak at 500 K. 4) The He concentration of the thinned single crystals was lower by a factor of 10 to 50 than that of the thinned polycrystals. 5) The He solubility in single crystals can be described by an enthalpy of solution Hsub(s)sup(f) = 0.85 +- 0.7 eV and a non-configurational entropy of Ssub(s)sup(f) between 0 k and 1 k (k: Boltzmann-constant). In order to measure the pressure dependence of helium bubble growth in nickel polycrystal Ni-foils were α-implanted to a helium content of 130 appm. The evaluation of the size distribution of the helium bubbles after heat treatments shows 1) The helium content of the observable bubbles - assumed to be in equilibrium - equals the amount of helium implanted into the specimen. 2) The activation energy for the growth of helium bubbles is 1.25 +- 0.3 eV. The comparison of specimen which had been heated at low pressures up to 10 bar with others heated at 2500-2700 bar does not show an unequivocal pressure dependence for helium bubble growth. (orig./IHOE) [de

Effect of 3.0 MeV helium implantation on electrical characteristics of 4H-SiC BJTs

Energy Technology Data Exchange (ETDEWEB)

Usman, Muhammad; Hallen, Anders; Ghandi, Reza; Domeij, Martin, E-mail: musman@kth.s [Microelectronics and Applied Physics, School of Communication and Information Technology, Royal Institute of Technology (KTH), Electrum 229, 16440 Kista (Sweden)

2010-11-01

Degradation of 4H-SiC power bipolar junction transistors (BJTs) under the influence of a high-energy helium ion beam was studied. Epitaxially grown npn BJTs were implanted with 3.0 MeV helium in the fluence range of 10{sup 10}-10{sup 11} cm{sup -2}. The devices were characterized by their current-voltage (I-V) behaviour before and after the implantation, and the results showed a clear degradation of the output characteristics of the devices. Annealing these implanted devices increased the interface traps between passivation oxide and the semiconductor, resulting in an increase of base current in the low-voltage operation range.

A description of stress driven bubble growth of helium implanted tungsten

International Nuclear Information System (INIS)

Sharafat, Shahram; Takahashi, Akiyuki; Nagasawa, Koji; Ghoniem, Nasr

2009-01-01

Low energy (<100 keV) helium implantation of tungsten has been shown to result in the formation of unusual surface morphologies over a large temperature range (700-2100 deg. C). Simulation of these macroscopic phenomena requires a multiscale approach to modeling helium transport in both space and time. We present here a multiscale helium transport model by coupling spatially-resolved kinetic rate theory (KRT) with kinetic Monte Carlo (KMC) simulation to model helium bubble nucleation and growth. The KRT-based HEROS Code establishes defect concentrations as well as stable helium bubble nuclei as a function of implantation parameters and position from the implanted surface and the KMC-based Mc-HEROS Code models the growth of helium bubbles due to migration and coalescence. Temperature- and stress-gradients can act as driving forces, resulting in biased bubble migration. The Mc-HEROS Code was modified to simulate the impact of stress gradients on bubble migration and coalescence. In this work, we report on bubble growth and gas release of helium implanted tungsten W/O stress gradients. First, surface pore densities and size distributions are compared with available experimental results for stress-free helium implantation conditions. Next, the impact of stress gradients on helium bubble evolution is simulated. The influence of stress fields on bubble and surface pore evolution are compared with stress-free simulations. It is shown that near surface stress gradients accelerate helium bubbles towards the free surface, but do not increasing average bubble diameters significantly.

Observations on 3He release from ErT2 films

International Nuclear Information System (INIS)

Venhaus, T.J.; Poths, J.

2004-01-01

We have loaded thin (500nm) films of erbium to a stoichiometry of ErT 2 , and have been observing their 3 He release characteristics. The films are stored in vacuum-tight metal vessels and the headspace helium is analyzed after accumulation for times ranging from a day to several months. Analysis is performed with very high sensitivity using a static noble gas mass spectrometer. For the first several years, 3 He release is a fairly constant function of helium generation, and does not depend on the substrate or the amount of helium accumulated in the film. We find a somewhat higher helium release (up to 3%) at very early times, decreasing over 6 months to a fairly consistent value (0.8%). This observation is consistent with a bubble nucleation and growth mechanism. The very early release behavior does not appear to be dependent upon the presence or growth of surface oxide layers. We also observed that, despite the very low vapor pressure of ErT 2 , our vacuum system became contaminated with low levels of tritium, representing perhaps a few ppm of the tritium in a sample.

Effect of microstructure on helium bubble growth in irradiated nickel

International Nuclear Information System (INIS)

Sattler, M.L.

1986-01-01

Thin nickel films were irradiated with 80 keV helium ions at varying doses and varying temperatures in order to obtain a variety of final microstructures. The growth of bubbles was examined during in-situ irradiations at 950 0 C where migration and coalescence events were observed for bubbles as large as 60 nm. Further direct observations of bubble growth were made during annealing of the irradiated specimens. For sample with no visible bubbles before annealing, the heating to 0.51 T/sub M/ produced bubbles that increased in diameter with annealing time to the power n. For bubbles in the grain interior, n ∼ 1, and on the grain boundaries, n ∼ 0.6. Since no migration and coalescence or ripening theories predict this behavior, a theory described by transient diffusion to spherical sinks was developed to discuss the behavior. This theory predicts that n = 1 for bubbles growing in the grain interior and n = 0.5 for bubbles on the grain boundary. In other annealing of irradiated samples containing large bubble populations, the growth of large bubbles and shrinking of small bubbles was observed at a temperature equal to 0.54 T/sub M/. The theory of Ostwald ripening properly described this type of bubble growth. Mass spectrometer measurements of He content in the irradiated specimens showed a greater He retention in the Ni films that contained a significant bubble population than those with no visible bubbles

Apparatus to measure low level helium for neutron dosimetry

Energy Technology Data Exchange (ETDEWEB)

Ozaki, Shuji; Takao, Yoshiyuki; Muramasu, Masatomo; Hida, Tomoya; Sou, Hirofumi; Nakashima, Hideki [Kyushu Univ., Fukuoka (Japan); Kanda, Yukinori

1998-03-01

An apparatus to measure low level helium in a solid sample for neutron dosimetry in the practical use such as area monitoring in the long-term and reactor surveillance was reported. In our previous work, the helium atoms measurement system (HAMS) was developed. A sample was evaporated in the furnace and the released gas from the sample was analyzed with the mass spectrometer of the system to determine the amount of helium contained in it. The system has been improved to advance the lower helium measurement limit in a solid sample for its application to an area monitoring system. The mass of a solid is up to 100mg. Two important points should be considered to advance the lower limit. One was to produce a high quality vacuum in the system chamber for suppressing background gases during the sample measurement. The other important point was to detect very small output from the mass spectrometer. A pulse counting system was used to get high sensitivity in the mass 4 analyzing. (author)

Influence of helium-injection schedule and prior thermomechanical treatment on the microstructure of Type 316 SS

International Nuclear Information System (INIS)

Kohyama, A.; Ayrault, G.; Turner, A.P.L.

1982-10-01

The influence of different helium-injection schedules on microstructure development Ni + ion irradiated 316 SS at 625 0 C is discussed. Injection schedules were chosen to (1) approximate the magnetic fusion reactor condition and (2) mimic the mixed-spectrum reactor condition. Dual-ion irradiation to 25 dpa produced strongly bimodal cavity size distributions in solution-annealed and solution-annealed and aged samples, whereas single-ion irradiation followed by dual-ion irradiation to the same dose produced a cavity size distribution with a substantial component of intermediate-size cavities. Dual-ion irradiation produced only very small cavities in 20% CW material, while single-ion followed by dual-ion irradiation produced some intermediate size cavities and greater swelling. 10 figures

Effect of titanium impurities on helium bubble growth in nickel

International Nuclear Information System (INIS)

Amarendra, G.; Viswanathan, B.; Rajaraman, R.; Srinivasan, S.; Gopinathan, K.P.

1992-01-01

Positron lifetime measurements in He-implanted Ni and Ni-Ti alloys containing dilute concentrations of Ti, during isochronal annealing, are reported. In the initial annealing stage of Ni-Ti alloys, only a single lifetime ranging from 160 to 180 ps is observed, in contrast with the two lifetimes seen in pure Ni. This indicates saturation positron trapping at helium-bound Ti-vacancy complexes, formed in high concentrations. Lattice statics calculations of the He binding energy at various defect complexes in Ni-containing Ti give credence to the above interpretation. Above 800K, two lifetimes are resolved in Ni-Ti alloys, where the longer lifetime τ 2 increases with a sharp reduction in its intensity. This is indicative of He bubble growth. The bubble radius r B and bubble concentration C B are obtained from an analysis of positron lifetime parameters. These results indicate that, for a given annealing temperature, r B is smaller by a factor of two and C B higher by nearly an order of magnitude in Ni-Ti than the corresponding values in pure Ni. This is explained as due to significant retardation of bubble growth on the addition of Ti to Ni, where the Ti impurities cause an impediment to bubble migration and coalescence. (author)

Computer experiment studies on mechanisms for irradiation induced defect production and annealing processes. Final report

International Nuclear Information System (INIS)

Beeler, J.R. Jr.; Beeler, M.F.

1979-06-01

This research is based on pair potentials used in the Brookhaven work. It extends their use in defect production simulations to the 5 MeV range and characterizes the short term annealing of the primary defect states. Defect properties and interactions are studied. Defect interactions include carbon, helium, and misfit metallic substitutional impurity interactions with vacancy and interstitial defects as well as vacancy-vacancy, interstitial-interstitial and vacancy-interstitial interactions

Computer experiment studies on mechanisms for irradiation induced defect production and annealing processes. Final report

Energy Technology Data Exchange (ETDEWEB)

Beeler, J.R. Jr.; Beeler, M.F.

1979-06-01

This research is based on pair potentials used in the Brookhaven work. It extends their use in defect production simulations to the 5 MeV range and characterizes the short term annealing of the primary defect states. Defect properties and interactions are studied. Defect interactions include carbon, helium, and misfit metallic substitutional impurity interactions with vacancy and interstitial defects as well as vacancy-vacancy, interstitial-interstitial and vacancy-interstitial interactions. (FS)

Martensitic transformation in helium implanted 316 stainless steel

International Nuclear Information System (INIS)

Ishimatsu, Manabu; Tsukuda, Noboru

1997-01-01

In order to simulate surface deterioration phenomenon due to particle loading of SUS-316 steel which is one of candidate materials for nuclear fusion reactor vacuum wall structure material, helium ion implanting was conducted at room temperature, 473 K and 573 K. To martensitic phase formed as a results, implantation dose dependence, implanting temperature dependence, and annealing under 1073 K were conducted. Formation of the martensitic phase was suppressed at high implanting temperature. At room temperature implantation, the martensitic phase disappeared at more than 873 K, but at high temperature implantation, it increased abnormally near at 973 K. This showed that deterioration of materials depended extremely upon using temperature and temperature history. (G.K.)

Growth rate effects on the formation of dislocation loops around deep helium bubbles in Tungsten

International Nuclear Information System (INIS)

Sandoval, Luis; Perez, Danny; Uberuaga, Blas P.; Voter, Arthur Ford

2016-01-01

Here, the growth process of spherical helium bubbles located 6 nm below a (100) surface is studied using molecular dynamics and parallel replica dynamics simulations, over growth rates from 10"6 to 10"1"2 helium atoms per second. Slower growth rates lead to a release of pressure and lower helium content as compared with fast growth cases. In addition, at slower growth rates, helium bubbles are not decorated by multiple dislocation loops, as these tend to merge or emit given sufficient time. At faster rates, dislocation loops nucleate faster than they can emit, leading to a more complicated dislocation structure around the bubble.

Checking the sealing of fuel elements by helium sweating - case of the reactors G2 (1960); Controle de l'etancheite des elements combustibles par ressuage d'helium - cas du reacteur G2 (1960)

Energy Technology Data Exchange (ETDEWEB)

Blanc, B; D' Orival, M [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires; Choumoff, S [Compagnie Francaise Thomson-Houston, 75 - Paris (France)

1960-07-01

The G2 slug is a welded, hermetically sealed unit; the seal is checked by placing the fuel element in a helium atmosphere under pressure, then measuring the quantity of helium it releases in a vessel under vacuum. The theoretical aspect and the conditions of industrial application are reviewed, and the installations described. (author) [French] La cartouche G2 se presente comme un ensemble soude, hermetique; le controle d'etancheite s'effectue en immergeant l'element combustible dans une atmosphere d'helium sous pression puis en mesurant la quantite d'helium qu'il restitue dans une enceinte sous vide. L'aspect theorique et les conditions d'exploitation industrielle sont evoques et les installations decrites. (auteur)

In-situ observation of damage evolution in TiC crystals during helium ion irradiation

International Nuclear Information System (INIS)

Hojou, K.; Otsu, H.; Furuno, S.; Izui, K.; Tsukamoto, T.

1994-01-01

In-situ observations were performed on bubble formation and growth in TiC during 20 keV helium ion irradiation over the wide range of irradiation temperatures from 12 to 1523 K. No amorphization occurred over this temperature range. The bubble densities and sizes were almost independent of irradiation temperatures from 12 to 1273 K. Remarkable growth and coalescence occurred during irradiation at high temperature above 1423 K and during annealing above 1373 K after irradiation. ((orig.))

Annealing of defects in indium antimonide after ion bombardment

International Nuclear Information System (INIS)

Bogatyrev, V.A.; Kachurin, G.A.

1977-01-01

Indium antimonide electric properties are investigated after ion bombardment of different mass (with energy of 60 and 300 keV) and isochrone annealing in the 20-450 deg C temperature range. It is shown that 100-150 deg C n- type stable layers are formed after proton irradiation at room temperature only. Indium antimonide exposure by average mass ions under the same conditions and also by helium ions of 300 keV energy brings to p-type layer formation with high hole concentration. Subsequent heating at the temperature over 150 deg C results in electron conductivity of irradiated layers. Electron volume density and mobility efficiency reaches 10 18 cm -3 and 10 4 cm 2 /Vs respectively. N-type formed layers are stable up to 350 deg C allowing its usage for n-p transition formation admitting thermal treatment. Analysis is given of defect behaviour peculiarities depending upon the irradiation and annealing conditions. Hole conductivity in irradiated indium antimonide is supposed to be stipulated by regions of disorder, while electron conductivity - by relatively simpler disorders

Cyclical Annealing Technique To Enhance Reliability of Amorphous Metal Oxide Thin Film Transistors.

Science.gov (United States)

Chen, Hong-Chih; Chang, Ting-Chang; Lai, Wei-Chih; Chen, Guan-Fu; Chen, Bo-Wei; Hung, Yu-Ju; Chang, Kuo-Jui; Cheng, Kai-Chung; Huang, Chen-Shuo; Chen, Kuo-Kuang; Lu, Hsueh-Hsing; Lin, Yu-Hsin

2018-02-26

This study introduces a cyclical annealing technique that enhances the reliability of amorphous indium-gallium-zinc-oxide (a-IGZO) via-type structure thin film transistors (TFTs). By utilizing this treatment, negative gate-bias illumination stress (NBIS)-induced instabilities can be effectively alleviated. The cyclical annealing provides several cooling steps, which are exothermic processes that can form stronger ionic bonds. An additional advantage is that the total annealing time is much shorter than when using conventional long-term annealing. With the use of cyclical annealing, the reliability of the a-IGZO can be effectively optimized, and the shorter process time can increase fabrication efficiency.

Graphite moderator annealing of the experimental reactor for irradiation (0.5 MW)

International Nuclear Information System (INIS)

Oliveira Avila, Carlos Alberto de; Pires, Luis Fernando Goncalves

1995-01-01

This work describes an operational procedure for the annealing of the graphite moderator in the 0,5 MW Experimental Reactor for Irradiation. A theoretical methodology has been developed for calculating the temperature field during the annealing process. The equations for mass, momentum, and energy conservation for the coolant as well as for the energy conservation in the moderator are solved numerically. The energy stored in the graphite and released in the annealing is accounted for by the use of a modified source term in the energy conservation equation for the moderator. A good agreement has been found for comparisons of the calculations with annealing data from the BEPO reactor. The major parameters affecting annealing have also been determined. (author). 8 refs, 11 figs

The 1/3-scale aerodynamics performance test of helium compressor for GTHTR300 turbo machine of JAERI (step 1)

International Nuclear Information System (INIS)

Takada, Shoji; Takizuka, Takakazu; Kunitomi, Kazuhiko; Xing, Yan

2003-01-01

A program for research and development on aerodynamics in a helium gas compressor was planned for the power conversion system of the Gas Turbine High Temperature Reactor (GTHTR300). The three-dimensional aerodynamic design of the compressor achieved a high polytropic efficiency of 90%, keeping a sufficient surge margin over 30%. To validate the design of the helium gas compressor of GTHTR300, aerodynamic performance tests were planned, and a 1/3-scale, 4-stage compressor model was designed. In the tests, the performance data of the helium gas compressor model will be acquired by using helium gas as a working fluid. The maximum design pressure at the model inlet is 0.88 MPa, which allows the Reynolds number to be sufficiently high. The present study is entrusted from the Ministry of Education, Culture, Sports, Science and Technology of Japan. (author)

Fatigue and Creep Crack Propagation behaviour of Alloy 617 in the Annealed and Aged Conditions

Energy Technology Data Exchange (ETDEWEB)

Julian K. Benz; Richard N. Wright

2013-10-01

The crack propagation behaviour of Alloy 617 was studied under various conditions. Elevated temperature fatigue and creep-fatigue crack growth experiments were conducted at 650 and 800 degrees C under constant stress intensity (triangle K) conditions and triangular or trapezoidal waveforms at various frequencies on as-received, aged, and carburized material. Environmental conditions included both laboratory air and characteristic VHTR impure helium. As-received Alloy 617 displayed an increase in the crack growth rate (da/dN) as the frequency was decreased in air which indicated a time-dependent contribution component in fatigue crack propagation. Material aged at 650°C did not display any influence on the fatigue crack growth rates nor the increasing trend of crack growth rate with decreasing frequency even though significant microstructural evolution, including y’ (Ni3Al) after short times, occurred during aging. In contrast, carburized Alloy 617 showed an increase in crack growth rates at all frequencies tested compared to the material in the standard annealed condition. Crack growth studies under quasi-constant K (i.e. creep) conditions were also completed at 650 degrees C and a stress intensity of K = 40 MPa9 (square root)m. The results indicate that crack growth is primarily intergranular and increased creep crack growth rates exist in the impure helium environment when compared to the results in laboratory air. Furthermore, the propagation rates (da/dt) continually increased for the duration of the creep crack growth either due to material aging or evolution of a crack tip creep zone. Finally, fatigue crack propagation tests at 800 degrees C on annealed Alloy 617 indicated that crack propagation rates were higher in air than impure helium at the largest frequencies and lowest stress intensities. The rates in helium, however, eventually surpass the rates in air as the frequency is reduced and the stress intensity is decreased which was not observed at 650

Effects of annealing on the properties of atomic layer deposited Ru thin films deposited by NH{sub 3} and H{sub 2} as reactants

Energy Technology Data Exchange (ETDEWEB)

Lee, Seung-Joon; Kim, Soo-Hyun, E-mail: soohyun@ynu.ac.kr

2016-08-01

Atomic layer deposition (ALD) of Ru using a non-oxidizing reactant is indispensable considering its application as a seed layer for Cu electroplating and a bottom electrode for dynamic random access memory capacitors. In this study, ALD-Ru films were deposited using a sequential supply of dicarbonyl-bis(5-methyl-2,4-hexanediketonato) Ru(II) (C{sub 16}H{sub 22}O{sub 6}Ru) and potential non-oxidizing reducing agents, NH{sub 3} or H{sub 2}, as the reactants at a substrate temperature of 250 °C, and the effects of post-annealing in a H{sub 2} ambient on the film properties were investigated. The highly conformal deposition of Ru films was possible using the present reaction scheme but its resistivity was as high as ~ 750 μΩ-cm due to carbon incorporation into the film and the formation of an amorphous structure. Low temperature annealing at 300 °C at H{sub 2} ambient after deposition was found to improve the properties significantly in terms of the resistivity, impurities contents and crystallinity. For example, the film resistivity was decreased drastically to ~ 40 μΩ-cm with both the release of C in the film and crystallization after annealing based on secondary ion mass spectrometry and transmission electron microscopy, whereas perfect step coverage at a very small-sized dual trench (aspect ratio: ~ 3, the top opening size of 45 nm and bottom size of 20 nm) was maintained after annealing. - Highlights: • Ru thin films were deposited by atomic layer deposition (ALD) using NH{sub 3} and H{sub 2} molecules. • Effects of low temperature (300 °C) post-annealing on the film properties were investigated. • Post annealing improved the properties of ALD-Ru films. • Perfect step coverage of ALD-Ru was confirmed at trench structure (top opening width: 45 nm).

Positron annihilation investigation and nuclear reaction analysis of helium and oxygen-implanted zirconia

International Nuclear Information System (INIS)

Grynszpan, R.I.; Saude, S.; Anwand, W.; Brauer, G.

2005-01-01

Since irradiation affects in-service properties of zirconia, we investigated the fluence dependence on production and thermal stability of defects induced by helium and oxygen-ion implantation in single crystals of yttria-fully-stabilized zirconia. In either case, depth profiling by slow positron implantation spectroscopy (SPIS) detects a distribution of vacancy-type defects peaking at 60% of the projected ion range R p . Owing to the saturation of positron-trapping occurring for low fluences, which depends on the ion mass, we could estimate a critical size of clusters ranging from 0.4 to 1.6 nm. The lack of SPIS-evidence of an open-volume excess at R p is explained by the presence of over-pressurized gas bubbles. This assumption is confirmed by Nuclear Reaction Analysis of 3 He concentration profiles, which shows that helium remains partly trapped at R p , even after annealing above 400 o C

Annealing of magnetic nanoparticles for their encapsulation into microcarriers guided by vascular magnetic resonance navigation

Energy Technology Data Exchange (ETDEWEB)

Pouponneau, Pierre; Segura, Vincent [Ecole Polytechnique de Montreal (EPM), NanoRobotics Laboratory, Department of Computer and Software Engineering and Institute of Biomedical Engineering (Canada); Savadogo, Oumarou [Ecole Polytechnique de Montreal (EPM), Laboratoire de Nouveaux Materiaux pour l' electrochimie et l' energie (Canada); Leroux, Jean-Christophe [Universite de Montreal, Faculty of Pharmacy (Canada); Martel, Sylvain, E-mail: sylvain.martel@polymtl.ca [Ecole Polytechnique de Montreal (EPM), NanoRobotics Laboratory, Department of Computer and Software Engineering and Institute of Biomedical Engineering (Canada)

2012-12-15

Iron, cobalt and iron-cobalt nanoparticle properties, such as diameter, saturation magnetization (Ms), crystal structure, surface composition and stability in physiological solutions, were investigated according to the annealing temperature used prior to their encapsulation into poly(d, l-lactic-co-glycolic acid) (PLGA) microcarriers. These new 60-{mu}m microparticles should exhibit an Ms around 70 emu g{sup -1} to be guided in real time from their intravascular injection site to a tumor with a magnetic resonance imaging scanner. The challenge in the preparation of the nanoparticles consisted in limiting Ms loss by oxidation and the release of metallic ions. It was found that when the annealing temperature reached 650 Degree-Sign C, Fe nanoparticles coalesced, the mean diameter reached (O) 361 {+-} 138 nm and Ms increased to 171 emu g{sup -1}. These nanoparticles exhibited a core of {alpha}-Fe and a shell of Fe{sub 3}O{sub 4}. On the opposite, Co nanoparticle properties were not affected by the annealing temperature: O and Ms were around 120 nm and 140 emu g{sup -1}, respectively. FeCo (60:40, atomic percent) nanoparticles coalesced at an annealing temperature >550 Degree-Sign C, O and Ms reached 217 nm and 213 emu g{sup -1}, respectively. Co and FeCo nanoparticles with a Co atomic proportion >15 % were coated with a graphite shell when the temperature was set to 550 Degree-Sign C. In physiological solution, Fe and Co nanoparticles significantly released more ions than FeCo nanoparticles. After the preparation steps prior to their encapsulation, the Ms of Fe and FeCo nanoparticles decreased by 25 and 3 %, respectively. FeCo-PLGA microparticles possessed a relatively high Ms (73 emu g{sup -1}) while that of Fe-PLGA microparticle (20 emu g{sup -1}) was too low for efficient targeting. The graphite shell was efficient to preserve Ms during the encapsulation.

Inert annealing of irradiated graphite by inductive heating

International Nuclear Information System (INIS)

Botzem, W.; Woerner, J.

2001-01-01

Fission neutrons change physical properties of graphite being used in nuclear reactors as moderator and as structural material. The understanding of these effects on an atomic model is expressed by dislocations of carbon atoms within the graphite and the thereby stored energy is known as Wigner Energy. The dismantling of the Pile 1 core may necessitate the thermal treatment of the irradiated but otherwise undamaged graphite. This heat treatment - usually called annealing - initiates the release of stored Wigner Energy in a controlled manner. This energy could otherwise give rise to an increase in temperature under certain conditions during transport or preparation for final storage. In order to prevent such an effect it is intended to anneal the major part of Pile 1 graphite before it is packed into boxes suitable for final disposal. Different heating techniques have been assessed. Inductive heating in an inert atmosphere was selected for installation in the Pile 1 Waste Processing Facility built for the treatment and packaging of the dismantled Pile 1 waste. The graphite blocks will be heated up to 250 deg. C in the annealing ovens, which results in the release of significant amount of the stored energy. External heat sources in a final repository will never heat up the storage boxes to such a temperature. (author)

Cryogenic filter method produces super-pure helium and helium isotopes

Science.gov (United States)

Hildebrandt, A. F.

1964-01-01

Helium is purified when cooled in a low pressure environment until it becomes superfluid. The liquid helium is then filtered through iron oxide particles. Heating, cooling and filtering processes continue until the purified liquid helium is heated to a gas.

Re-Condensation and Liquefaction of Helium and Hydrogen Using Coolers

International Nuclear Information System (INIS)

Green, Michael A.

2009-01-01

Coolers are used to cool cryogen free devices at temperatures from 5 to 30 K. Cryogen free cooling involves a temperature drop within the device being cooled and between the device and the cooler cold heads. Liquid cooling with a liquid cryogen distributed over the surface of a device combined with re-condensation can result in a much lower temperature drop between the cooler and the device being cooled. The next logical step beyond simple re-condensation is using a cooler to liquefy the liquid cryogen in the device. A number of tests of helium liquefaction and re-condensation of helium have been run using a pulse tube cooler in the drop-in mode. This report discusses the parameter space over which re-condensation and liquefaction for helium and hydrogen can occur.

Helium abundance and speed difference between helium ions and protons in the solar wind from coronal holes, active regions, and quiet Sun

Science.gov (United States)

Fu, Hui; Madjarska, M. S.; Li, Bo; Xia, LiDong; Huang, ZhengHua

2018-05-01

Two main models have been developed to explain the mechanisms of release, heating and acceleration of the nascent solar wind, the wave-turbulence-driven (WTD) models and reconnection-loop-opening (RLO) models, in which the plasma release processes are fundamentally different. Given that the statistical observational properties of helium ions produced in magnetically diverse solar regions could provide valuable information for the solar wind modelling, we examine the statistical properties of the helium abundance (AHe) and the speed difference between helium ions and protons (vαp) for coronal holes (CHs), active regions (ARs) and the quiet Sun (QS). We find bimodal distributions in the space of AHeand vαp/vA(where vA is the local Alfvén speed) for the solar wind as a whole. The CH wind measurements are concentrated at higher AHeand vαp/vAvalues with a smaller AHedistribution range, while the AR and QS wind is associated with lower AHeand vαp/vA, and a larger AHedistribution range. The magnetic diversity of the source regions and the physical processes related to it are possibly responsible for the different properties of AHeand vαp/vA. The statistical results suggest that the two solar wind generation mechanisms, WTD and RLO, work in parallel in all solar wind source regions. In CH regions WTD plays a major role, whereas the RLO mechanism is more important in AR and QS.

Non-vacuum, single-step conductive transparent ZnO patterning by ultra-short pulsed laser annealing of solution-deposited nanoparticles

Energy Technology Data Exchange (ETDEWEB)

Lee, Daeho; Pan, Heng; Kim, Eunpa; Grigoropoulos, Costas P. [University of California, Department of Mechanical Engineering, Berkeley, CA (United States); Ko, Seung Hwan [Korea Advanced Institute of Science and Technology (KAIST), Department of Mechanical Engineering, Daejeon (Korea, Republic of); Park, Hee K. [AppliFlex LLC, Sunnyvale, CA (United States)

2012-04-15

A solution-processable, high-concentration transparent ZnO nanoparticle (NP) solution was successfully synthesized in a new process. A highly transparent ZnO thin film was fabricated by spin coating without vacuum deposition. Subsequent ultra-short-pulsed laser annealing at room temperature was performed to change the film properties without using a blanket high temperature heating process. Although the as-deposited NP thin film was not electrically conductive, laser annealing imparted a large conductivity increase and furthermore enabled selective annealing to write conductive patterns directly on the NP thin film without a photolithographic process. Conductivity enhancement could be obtained by altering the laser annealing parameters. Parametric studies including the sheet resistance and optical transmittance of the annealed ZnO NP thin film were conducted for various laser powers, scanning speeds and background gas conditions. The lowest resistivity from laser-annealed ZnO thin film was about 4.75 x 10{sup -2} {omega} cm, exhibiting a factor of 10{sup 5} higher conductivity than the previously reported furnace-annealed ZnO NP film and is even comparable to that of vacuum-deposited, impurity-doped ZnO films within a factor of 10. The process developed in this work was applied to the fabrication of a thin film transistor (TFT) device that showed enhanced performance compared with furnace-annealed devices. A ZnO TFT performance test revealed that by just changing the laser parameters, the solution-deposited ZnO thin film can also perform as a semiconductor, demonstrating that laser annealing offers tunability of ZnO thin film properties for both transparent conductors and semiconductors. (orig.)

HEINBE; the calculation program for helium production in beryllium under neutron irradiation

International Nuclear Information System (INIS)

Shimakawa, Satoshi; Ishitsuka, Etsuo; Sato, Minoru

1992-11-01

HEINBE is a program on personal computer for calculating helium production in beryllium under neutron irradiation. The program can also calculate the tritium production in beryllium. Considering many nuclear reactions and their multi-step reactions, helium and tritium productions in beryllium materials irradiated at fusion reactor or fission reactor may be calculated with high accuracy. The calculation method, user's manual, calculated examples and comparison with experimental data were described. This report also describes a neutronics simulation method to generate additional data on swelling of beryllium, 3,000-15,000 appm helium range, for end-of-life of the proposed design for fusion blanket of the ITER. The calculation results indicate that helium production for beryllium sample doped lithium by 50 days irradiation in the fission reactor, such as the JMTR, could be achieved to 2,000-8,000 appm. (author)

Helium cryogenics

CERN Document Server

Van Sciver, Steven W

2012-01-01

Twenty five years have elapsed since the original publication of Helium Cryogenics. During this time, a considerable amount of research and development involving helium fluids has been carried out culminating in several large-scale projects. Furthermore, the field has matured through these efforts so that there is now a broad engineering base to assist the development of future projects. Helium Cryogenics, 2nd edition brings these advances in helium cryogenics together in an updated form. As in the original edition, the author's approach is to survey the field of cryogenics with emphasis on helium fluids. This approach is more specialized and fundamental than that contained in other cryogenics books, which treat the associated range of cryogenic fluids. As a result, the level of treatment is more advanced and assumes a certain knowledge of fundamental engineering and physics principles, including some quantum mechanics. The goal throughout the work is to bridge the gap between the physics and engineering aspe...

Through-vial impedance spectroscopy of the mechanisms of annealing in the freeze-drying of maltodextrin: the impact of annealing hold time and temperature on the primary drying rate.

Science.gov (United States)

Smith, Geoff; Arshad, Muhammad Sohail; Polygalov, Eugene; Ermolina, Irina

2014-06-01

The study aims to investigate the impact of annealing hold time and temperature on the primary drying rate/duration of a 10% (w/v) solution of maltodextrin with an emphasis on how the mechanisms of annealing might be understood from the in-vial measurements of the ice crystal growth and the glass transition. The electrical impedance of the solution within a modified glass vial was recorded between 10 and 10(6) Hz during freeze-drying cycles with varying annealing hold times (1-5 h) and temperatures. Primary drying times decreased by 7%, 27% and 34% (1.1, 4.3 and 5.5 h) with the inclusion of an annealing step at temperatures of -15°C, -10°C and -5°C, respectively. The glass transition was recorded at approximately -16°C during the re-heating and re-cooling steps, which is close to the glass transition (Tg ') reported for 10% (w/v) maltodextrin and therefore indicates that a maximum freeze concentration (∼86%, w/w, from the Gordon-Taylor equation) was achieved during first freezing, with no further ice being formed on annealing. This observation, coupled to the decrease in electrical resistance that was observed during the annealing hold time, suggests that the reduction in the drying time was because of improved connectivity of ice crystals because of Ostwald ripening rather than devitrification. © 2014 Wiley Periodicals, Inc. and the American Pharmacists Association.

Alloying and microstructural changes in platinum–titanium milled and annealed powders

International Nuclear Information System (INIS)

Maweja, Kasonde; Phasha, M.J.; Yamabe-Mitarai, Y.

2012-01-01

Graphical abstract: (a) SE-SEM micrographs of PtTi martensite formed in powder milled for short time annealed at 1500 °C and quenched in helium gas flow (b) BSE-SEM of structure formed after slow cooling. Highlights: ► A disordered metastable FCC Pt(Ti) solid solution was formed after longer milling period. ► HCP Ti crystals were first deformed and then the atoms were dissolved in strained FCC Pt lattices. ► Longer milling time suppressed the occurrence of martensitic transformation after annealing. ► Martensite phase was formed in products that went through a short milling time then annealed and quenched. ► The width of the martensite features formed was smaller at higher cooling rates. - Abstract: Equiatomic platinum–titanium powder mixtures were processed by high energy ball milling under argon atmosphere and sintered under vacuum. Evolution of the crystal structures and microstructures of the products formed were investigated by XRD and SEM techniques, respectively. The HCP crystals of Ti were first deformed and then a disordered metastable FCC Pt(Ti) solid solution was formed during milling due to semi-coherency of FCC lattices. A nanostructured Pt(Ti) product was formed after long milling time, which contained 44–47 at.% Ti and 53–56 at.% Pt. An ordered PtTi intermetallic was formed by annealing the metastable Pt(Ti) at temperature above 1300 °C. The crystal structure and microstructure of the TiPt phase depended on the milling time, annealing temperature and the cooling rate. The B19 PtTi plate martensite was formed after annealing at 1500 °C and quenching at a cooling rate of 23 °C/min to 200 °C/min for short time milled products. The width of martensite features was smaller at high cooling rate. In PtTi products milled for longer time, no martensitic transformation was observed on cooling the annealed samples. Small amounts of Pt 5 Ti 3 were formed in the powders milled for 16 h or more, followed by annealing at 1500 °C and furnace

Liquid helium

CERN Document Server

Atkins, K R

1959-01-01

Originally published in 1959 as part of the Cambridge Monographs on Physics series, this book addresses liquid helium from the dual perspectives of statistical mechanics and hydrodynamics. Atkins looks at both Helium Three and Helium Four, as well as the properties of a combination of the two isotopes. This book will be of value to anyone with an interest in the history of science and the study of one of the universe's most fundamental elements.

Introduction to Density Functional Theory: Calculations by Hand on the Helium Atom

Science.gov (United States)

Baseden, Kyle A.; Tye, Jesse W.

2014-01-01

Density functional theory (DFT) is a type of electronic structure calculation that has rapidly gained popularity. In this article, we provide a step-by-step demonstration of a DFT calculation by hand on the helium atom using Slater's X-Alpha exchange functional on a single Gaussian-type orbital to represent the atomic wave function. This DFT…

Design concept of cryogenic falling liquid film helium separator

International Nuclear Information System (INIS)

Kinoshita, M.; Yamanishi, T.; Bartlit, J.R.; Sherman, R.H.

1986-01-01

A design concept is developed for a cryogenic falling liquid film helium separator by clarifying the differences between this process and a cryogenic distillation column. The process characteristics are greatly improved by the idea of adding an H 2 gas flow to a point near the upper end of the packed section. The flow rate of tritium lost from the top is kept extremely low with an adequately short packed section, and the column pressure is reduced to 1 atm. The addition causes no appreciable increase in the protium percentage (approx. =1%) in the bottom liquid flow. A design procedure applying the Colburn-Hougen method is proposed for determining specifications of the refrigerated section. It is shown that the presence of noncondensible helium requires a significantly larger heat transfer area mainly because the mass transfer resistance increases enormously as the condensation of hydrogen isotopes proceeds. Control schemes are also proposed: The tritium concentration in the top gas is controlled by the H 2 gas flow rate. The pressure rise caused by an increase of the helium percentage within the refrigerated section, which cannot readily be eliminated by changing input specifications of the refrigerant gas, is avoided by increasing the top gas flow rate to release more helium from the top

Defects and morphological changes in nanothin Cu films on polycrystalline Mo analyzed by thermal helium desorption spectrometry

International Nuclear Information System (INIS)

Venugopal, V.; Seijbel, L.J.; Thijsse, B.J.

2005-01-01

Thermal helium desorption spectrometry (THDS) has been used for the investigation of defects and thermal stability of thin Cu films (5-200 A ) deposited on a polycrystalline Mo substrate in ultrahigh vacuum. These films are metastable at room temperature. On heating, the films transform into islands, giving rise to a relatively broad peak in the helium desorption spectra. The temperature of this island formation is dependent on film thickness, being 417 K for 10 A and 1100 K for a 200 A film. The activation energy for island formation was found to be 0.3±0.1 eV for 75 A film. Grain boundaries have a strong effect on island formation. The defect concentration in the as-deposited films is ∼5x10 -4 , for films thicker than 50 A and more for thinner films. Helium release from monovacancies was identified in the case of a 200 A film. Helium release was also seen during sublimation of the Cu film (∼1350 K). Overlayer experiments were used to identify helium trapped close to the film surface. An increase of the substrate temperature during deposition resulted in a film that had already formed islands. Argon-ion assistance (250 eV) during film deposition with an ion/atom ratio of ∼0.1 resulted in a significant enhancement of helium trapping in the films. The argon concentration in the films was found to be 10 -3 . The temperature of island formation was increased due to argon-ion assistance. The helium and argon desorption spectra are found to be similar, which is due to most of the helium becoming trapped in the defects created by the argon beam. The role of the Mo surface in affecting the defects at the film-substrate interface is investigated. The effect of variation of helium fluence and helium implantation energy is also considered. The present THDS results of Cu/poly-Mo are compared to those of Cu/Mo(100) and Cu/Mo(100) reported earlier

CALCULATED REGENERATOR PERFORMANCE AT 4 K WITH HELIUM-4 AND HELIUM-3

International Nuclear Information System (INIS)

Radebaugh, Ray; Huang Yonghua; O'Gallagher, Agnes; Gary, John

2008-01-01

The helium-4 working fluid in regenerative cryocoolers operating with the cold end near 4 K deviates considerably from an ideal gas. As a result, losses in the regenerator, given by the time-averaged enthalpy flux, are increased and are strong functions of the operating pressure and temperature. Helium-3, with its lower boiling point, behaves somewhat closer to an ideal gas in this low temperature range and can reduce the losses in 4 K regenerators. An analytical model is used to find the fluid properties that strongly influence the regenerator losses as well as the gross refrigeration power. The thermodynamic and transport properties of helium-3 were incorporated into the latest NIST regenerator numerical model, known as REGEN3.3, which was used to model regenerator performance with either helium-4 or helium-3. With this model we show how the use of helium-3 in place of helium-4 can improve the performance of 4 K regenerative cryocoolers. The effects of operating pressure, warm-end temperature, and frequency on regenerators with helium-4 and helium-3 are investigated and compared. The results are used to find optimum operating conditions. The frequency range investigated varies from 1 Hz to 30 Hz, with particular emphasis on higher frequencies

FREVAP-6, Metal Fission Products Release from HTGR Fuel Elements

International Nuclear Information System (INIS)

Pierce, V.H.

2005-01-01

1 - Description of problem or function: The FREVAP type of code for estimating the release of longer-lived metallic fission products from HTGR fuel elements has been developed to take into account the combined effects of the retention of metallic fission products by fuel particles and the rather strong absorption of these fission products by the graphite of the fuel elements. Release calculations are made on the basis that the loss of fission product nuclides such as strontium, cesium, and barium is determined by their evaporation from the graphite surfaces and their transpiration induced by the flowing helium coolant. The code is devised so that changes of fission rate (fuel element power), fuel temperature, and graphite temperature may be incorporated into the calculation. Temperature is quite important in determining release because, in general, both release from fuel particles and loss by evaporation (transpiration) vary exponentially with the reciprocal of the absolute temperature. NESC0301/02: This version differs from the previous one in the following points: The source and output files were converted from BCD to ASCII coding. 2 - Method of solution: A problem is defined as having a one-dimensional segment made up of three parts - (1) the fission product source (fuel particles) in series with, (2) a non-source and absorption part (element graphite) and (3) a surface for evaporation to the coolant (graphite-helium interface). More than one segment may be connected (possibly segments stacked axially) by way of the coolant. At any given segment, a continuity equation is solved assuming equilibrium between the source term, absorption term, evaporation at coolant interface and the partial pressure of the fission product isotope in the coolant. 3 - Restrictions on the complexity of the problem - Maxima of: 5 isotopes; 10 time intervals for time-dependent variable; 49 segments (times number of isotopes); 5 different output print time-steps

Effect of increased exposure times on amount of residual monomer released from single-step self-etch adhesives.

Science.gov (United States)

Altunsoy, Mustafa; Botsali, Murat Selim; Tosun, Gonca; Yasar, Ahmet

2015-10-16

The aim of this study was to evaluate the effect of increased exposure times on the amount of residual Bis-GMA, TEGDMA, HEMA and UDMA released from single-step self-etch adhesive systems. Two adhesive systems were used. The adhesives were applied to bovine dentin surface according to the manufacturer's instructions and were polymerized using an LED curing unit for 10, 20 and 40 seconds (n = 5). After polymerization, the specimens were stored in 75% ethanol-water solution (6 mL). Residual monomers (Bis-GMA, TEGDMA, UDMA and HEMA) that were eluted from the adhesives (after 10 minutes, 1 hour, 1 day, 7 days and 30 days) were analyzed by high-performance liquid chromatography (HPLC). The data were analyzed using 1-way analysis of variance and Tukey HSD tests. Among the time periods, the highest amount of released residual monomers from adhesives was observed in the 10th minute. There were statistically significant differences regarding released Bis-GMA, UDMA, HEMA and TEGDMA between the adhesive systems (p<0.05). There were no significant differences among the 10, 20 and 40 second polymerization times according to their effect on residual monomer release from adhesives (p>0.05). Increasing the polymerization time did not have an effect on residual monomer release from single-step self-etch adhesives.

Analysis of the absorption coefficient by annealing in carbon implanted Nd: YVO4

International Nuclear Information System (INIS)

Sanchez-Morales, M E; Vazquez, G V; Lifante, G; Cantelar, E; Rickards, J; Trejo-Luna, R

2011-01-01

Low loss in optical waveguides is very important in order to achieve high laser efficiency. Waveguide fabrication by ion implantation generates color centers, leading to absorption losses which can be reduced by annealing; however, this process may eliminate the waveguide and hence it is necessary to consider both the optimum annealing time and temperature. This work reports the behavior of the absorption coefficient by successive annealing steps in Nd:YVO 4 implanted with a dose of 5xl0 14 ions/cm 2 .

Is cold better ? - exploring the feasibility of liquid-helium-cooled optics

International Nuclear Information System (INIS)

Assoufid, L.; Mills, D.; Macrander, A.; Tajiri, G.

1999-01-01

Both simulations and recent experiments conducted at the Advanced Photon Source showed that the performance of liquid-nitrogen-cooled single-silicon crystal monochromators can degrade in a very rapid nonlinear fashion as the power and for power density is increased. As a further step towards improving the performance of silicon optics, we propose cooling with liquid helium, which dramatically improves the thermal properties of silicon beyond that of liquid nitrogen and brings the performance of single silicon-crystal-based synchrotrons radiation optics up to the ultimate limit. The benefits of liquid helium cooling as well as some of the associated technical challenges will be discussed, and results of thermal and structural finite elements simulations comparing the performance of silicon monochromators cooled with liquid nitrogen and helium will be given

Damage recovery in ZnO by post-implantation annealing

International Nuclear Information System (INIS)

Audren, A.; Hallen, A.; Linnarsson, M.K.; Possnert, G.

2010-01-01

ZnO bulk samples were implanted with 200 keV-Co ions at room temperature with two fluences, 1 x 10 16 and 8 x 10 16 cm -2 , and then annealed in air for 30 min at different temperatures up to 900 o C. After the implantation and each annealing step, the samples were analyzed by Rutherford backscattering spectrometry (RBS) in random and channeling directions to follow the evolution of the disorder profile. The RBS spectra reveal that disorder is created during implantation in proportion to the Co fluence. The thermal treatments induce a disorder recovery, which is however, not complete after annealing at 900 o C, where about 15% of the damage remains. To study the Co profile evolution during annealing, the samples were, in addition to RBS, characterized by secondary ion mass spectrometry (SIMS). The results show that Co diffusion starts at 800 o C, but also that a very different behavior is seen for Co concentrations below and above the solubility limit.

New helium spectrum variable and a new helium-rich star

International Nuclear Information System (INIS)

Walborn, N.R.

1974-01-01

HD 184927, known previously as a helium-rich star, has been found to have a variable helium spectrum; the equivalent widths of five He I lines are larger by an average of 46 percent on a 1974 spectrogram than on one obtained with the same equipment in 1970. HD 186205 has been found to be a new, pronounced helium-rich star. (auth)

Helium the disappearing element

CERN Document Server

Sears, Wheeler M

2015-01-01

The subject of the book is helium, the element, and its use in myriad applications including MRI machines, particle accelerators, space telescopes, and of course balloons and blimps. It was at the birth of our Universe, or the Big Bang, where the majority of cosmic helium was created; and stellar helium production continues. Although helium is the second most abundant element in the Universe, it is actually quite rare here on Earth and only exists because of radioactive elements deep within the Earth. This book includes a detailed history of the discovery of helium, of the commercial industry built around it, how the helium we actually encounter is produced within the Earth, and the state of the helium industry today. The gas that most people associate with birthday party balloons is running out. “Who cares?” you might ask. Well, without helium, MRI machines could not function, rockets could not go into space, particle accelerators such as those used by CERN could not operate, fiber optic cables would not...

Drug release from core-shell PVA/silk fibroin nanoparticles fabricated by one-step electrospraying.

Science.gov (United States)

Cao, Yang; Liu, Fengqiu; Chen, Yuli; Yu, Tao; Lou, Deshuai; Guo, Yuan; Li, Pan; Wang, Zhigang; Ran, Haitao

2017-09-20

Silk fibroin (SF), a FDA-approved natural protein, is renowned for its great biocompatibility, biodegradability, and mechanical properties. SF-based nanoparticles provide new options for drug delivery with their tunable drug loading and release properties. To take advantage of the features of carrier polymers, we present a one-step electrospraying method that combines SF, polyvinyl alcohol (PVA) and therapeutic drugs without an emulsion process. A distinct core-shell structure was obtained with the PVA core and silk shell after the system was properly set up. The model drug, doxorubicin, was encapsulated in the core with a greater than 90% drug encapsulation efficiency. Controllable drug release profiles were achieved by alternating the PVA/SF ratio. Although the initial burst release of the drug was minimized by the SF coating, a large number of drug molecules remained entrapped by the carrier polymers. To promote and trigger drug release on demand, low intensity focused ultrasound (US) was applied. The US was especially advantageous for accelerating the drug diffusion and release. The apoptotic activity of MDA-MB-231 cells incubated with drug-loaded nanoparticles was found to increase with time. In addition, we also observed PVA/SF nanoparticles that could elicit a drug release in response to pH.

Ultrafast quenching of metals to liquid-helium temperatures - investigation of the low-temperature mobility of hydrogen in niobium

International Nuclear Information System (INIS)

Blanz, M.; Blocher, R.; Carstanjen, H.D.; Messer, R.; Plachke, D.; Seeger, A.

1989-01-01

A novel technique for ultrafast quenching from 300 K to 4.2 K has been developed. It employs a fast jet of liquid helium with a speed of about 10 2 m/s and allows us to quench metal samples in about 6 ms. This corresponds to a quenching rate of about 4.5x10 4 K/s, which exceeds that achievable by conventional quenching in liquid helium by more than one order of magnitude. The technique has been used for a resistometric study of the behaviour of hydrogen in niobium quenched-in from the α-phase by means of isochronal and isothermal annealing. Even in the low-temperature region below 20 K a considerable recovery of the resistivity has been found, which cannot be seen in conventional quenching experiments. (orig.)

Liquid helium target

International Nuclear Information System (INIS)

Fujii, Y.; Kitami, T.; Torikoshi, M.

1984-12-01

A liquid helium target system has been built and used for the experiment on the reaction 4 He(γ, p). The target system has worked satisfactorily; the consumption rate of liquid helium is 360 ml/h and the cryogenic system retains liquid helium for about ten hours. The structure, operation and performance of the target system are reported. (author)

Why new neutron detector materials must replace helium-3

Science.gov (United States)

Hurd, Alan J.; Kouzes, Richard T.

2014-10-01

Helium-3 has such unique physical and nuclear properties that to a physicist it seems appalling the isotope was once indiscriminately released to the atmosphere as a waste gas. Not gravitationally bound to our planet, a He-3 atom is effectively lost to the human race once released. Consequently, when a confluence of independent factors in national security and research in the last decade created a "custody battle" over this scarce isotope, an intense search for substitutes and alternative technologies ensued for various applications. This Focus Point of EPJ Plus is dedicated to neutron detector alternatives.

Study of shallow junction formation by boron-containing cluster ion implantation of silicon and two-stage annealing

Science.gov (United States)

Lu, Xin-Ming

Shallow junction formation made by low energy ion implantation and rapid thermal annealing is facing a major challenge for ULSI (ultra large scale integration) as the line width decreases down to the sub micrometer region. The issues include low beam current, the channeling effect in low energy ion implantation and TED (transient enhanced diffusion) during annealing after ion implantation. In this work, boron containing small cluster ions, such as GeB, SiB and SiB2, was generated by using the SNICS (source of negative ion by cesium sputtering) ion source to implant into Si substrates to form shallow junctions. The use of boron containing cluster ions effectively reduces the boron energy while keeping the energy of the cluster ion beam at a high level. At the same time, it reduces the channeling effect due to amorphization by co-implanted heavy atoms like Ge and Si. Cluster ions have been used to produce 0.65--2keV boron for low energy ion implantation. Two stage annealing, which is a combination of low temperature (550°C) preannealing and high temperature annealing (1000°C), was carried out to anneal the Si sample implanted by GeB, SiBn clusters. The key concept of two-step annealing, that is, the separation of crystal regrowth, point defects removal with dopant activation from dopant diffusion, is discussed in detail. The advantages of the two stage annealing include better lattice structure, better dopant activation and retarded boron diffusion. The junction depth of the two stage annealed GeB sample was only half that of the one-step annealed sample, indicating that TED was suppressed by two stage annealing. Junction depths as small as 30 nm have been achieved by two stage annealing of sample implanted with 5 x 10-4/cm2 of 5 keV GeB at 1000°C for 1 second. The samples were evaluated by SIMS (secondary ion mass spectrometry) profiling, TEM (transmission electron microscopy) and RBS (Rutherford Backscattering Spectrometry)/channeling. Cluster ion implantation

Kinetic coupling of phosphate release, force generation and rate-limiting steps in the cross-bridge cycle.

Science.gov (United States)

Stehle, Robert; Tesi, Chiara

2017-08-01

A basic goal in muscle research is to understand how the cyclic ATPase activity of cross-bridges is converted into mechanical force. A direct approach to study the chemo-mechanical coupling between P i release and the force-generating step is provided by the kinetics of force response induced by a rapid change in [P i ]. Classical studies on fibres using caged-P i discovered that rapid increases in [P i ] induce fast force decays dependent on final [P i ] whose kinetics were interpreted to probe a fast force-generating step prior to P i release. However, this hypothesis was called into question by studies on skeletal and cardiac myofibrils subjected to P i jumps in both directions (increases and decreases in [P i ]) which revealed that rapid decreases in [P i ] trigger force rises with slow kinetics, similar to those of calcium-induced force development and mechanically-induced force redevelopment at the same [P i ]. A possible explanation for this discrepancy came from imaging of individual sarcomeres in cardiac myofibrils, showing that the fast force decay upon increase in [P i ] results from so-called sarcomere 'give'. The slow force rise upon decrease in [P i ] was found to better reflect overall sarcomeres cross-bridge kinetics and its [P i ] dependence, suggesting that the force generation coupled to P i release cannot be separated from the rate-limiting transition. The reasons for the different conclusions achieved in fibre and myofibril studies are re-examined as the recent findings on cardiac myofibrils have fundamental consequences for the coupling between P i release, rate-limiting steps and force generation. The implications from P i -induced force kinetics of myofibrils are discussed in combination with historical and recent models of the cross-bridge cycle.

Effect of annealing induced residual stress on the resonance frequency of SiO2 microcantilevers

Science.gov (United States)

Balasubramanian, S.; Prabakar, K.; Tripura Sundari, S.

2018-04-01

In the present work, effect of residual stress, induced due to annealing of SiO2 microcantilevers (MCs) on their resonance frequency is studied. SiO2MCs of various dimensions were fabricated using direct laser writer & wet chemical etching method and were annealed at 800 °C in oxygen environment, post release. The residual stress was estimated from the deflection profile of the MCs measured using 3D optical microscope, before and after annealing. Resonance frequency of the MCs was measured using nano-vibration analyzer and was found to change after annealing. Further the frequency shift was found to depend on the MC dimensions. This is attributed to the large stress gradients induced by annealing and associated stiffness changes.

A liquid helium saver

International Nuclear Information System (INIS)

Avenel, O.; Der Nigohossian, G.; Roubeau, P.

1976-01-01

A cryostat equipped with a 'liquid helium saver' is described. A mass flow rate M of helium gas at high pressure is injected in a counter-flow heat exchanger extending from room to liquid helium temperature. After isenthalpic expansion through a calibrated flow impedance this helium gas returns via the low pressure side of the heat exchanger. The helium boil-off of the cryostat represents a mass flow rate m, which provides additional precooling of the incoming helium gas. Two operating regimes appear possible giving nearly the same efficiency: (1) high pressure (20 to 25 atm) and minimum flow (M . L/W approximately = 1.5) which would be used in an open circuit with helium taken from a high pressure cylinder; and (2) low pressure (approximately = 3 atm), high flow (M . L/W > 10) which would be used in a closed circuit with a rubber diaphragm pumping-compressing unit; both provide a minimum theoretical boil-off factor of about 8%. Experimental results are reported. (U.K.)

Modification of the grain boundary microstructure of the austenitic PCA stainless steel to improve helium embrittlement resistance

International Nuclear Information System (INIS)

Maziasz, P.J.; Braski, D.N.

1986-01-01

Grain boundary MC precipitation was produced by a modified thermal-mechanical pretreatment in 25% cold worked (CW) austenitic prime candidate alloy (PCA) stainless steel prior to HFIR irradiation. Postirradiation tensile results and fracture analysis showed that the modified material (B3) resisted helium embrittlement better than either solution annealed (SA) or 25% CW PCA irradiated at 500 to 600 0 C to approx.21 dpa and 1370 at. ppM He. PCA SA and 25% CW were not embrittled at 300 to 400 0 C. Grain boundary MC survives in PCA-B3 during HFIR irradiation at 500 0 C but dissolves at 600 0 C; it does not form in either SA or 25% CW PCA during similar irradiation. The grain boundary MC appears to play an important role in the helium embrittlement resistance of PCA-B3

Study of diffusion mechanisms of helium atoms in face-centered cubic metals after α - implantation in a cyclotron

International Nuclear Information System (INIS)

Sciani, V.; Lucki, G.; Jung, P.

1984-01-01

Helium has been homogeneously introduced into gold foils at room temperature by alpha implantation in a CV-28 cyclotron. After implantation the helium release was observed in isothermal and linear heating experiments. The diffusion coefficient follows an Arrhenius behaviour with D sub(o) = 0.1 cm 2 /s and ΔH = 1.7 eV. Possible diffusion mechanisms are discussed. (Author) [pt

The solubility and diffusion coefficient of helium in uranium dioxide

International Nuclear Information System (INIS)

Nakajima, Kunihisa; Serizawa, Hiroyuki; Shirasu, Noriko; Haga, Yoshinori; Arai, Yasuo

2011-01-01

Highlights: ► The solubility and diffusivity of He in single-crystal UO 2 were determined. ► The determined He solubility lay within the scatter of the available data. ► The determined He diffusivity was in good agreement with recent experimental data. ► The He behavior was analyzed in terms of a simple interstitial diffusion mechanism. ► The experimental diffusivity was much lower than that analyzed theoretically. - Abstract: The solubility and diffusion coefficient of helium in the single-crystal UO 2 samples were determined by a Knudsen-effusion mass-spectrometric method. The measured helium solubilities were found to lie within the scatter of the available data, but to be much lower than those for the polycrystalline samples. The diffusion analysis was conducted based on a hypothetical equivalent sphere model and the simple Fick’s law. The helium diffusion coefficient was determined by using the pre-exponential factor and activation energy as the fitting parameters for the measured and calculated fractional releases of helium. The optimized diffusion coefficients were in good agreement with those obtained by a nuclear reaction method reported in the past. It was also found that the pre-exponential factors of the determined diffusion coefficients were much lower than those analyzed in terms of a simple interstitial diffusion mechanism.

Canada's helium output rising fast

Energy Technology Data Exchange (ETDEWEB)

1966-12-01

About 12 months from now, International Helium Limited will be almost ready to start up Canada's second helium extraction plant at Mankota, in Saskatchewan's Wood Mountain area about 100 miles southwest of Moose Jaw. Another 80 miles north is Saskatchewan's (and Canada's) first helium plant, operated by Canadian Helium and sitting on a gas deposit at Wilhelm, 9 miles north of Swift Current. It contains almost 2% helium, some COD2U, and the rest nitrogen. One year in production was apparently enough to convince Canadian Helium that the export market (it sells most of its helium in W. Europe) can take a lot more than it's getting. Construction began this summer on an addition to the Swift Current plant that will raise its capacity from 12 to 36MMcf per yr when it goes on stream next spring. Six months later, International Helium's 40 MMcf per yr plant to be located about 4 miles from its 2 Wood Mountain wells will double Canada's helium output again.

Diffusion of helium and nucleation-growth of helium-bubbles in metallic materials

International Nuclear Information System (INIS)

Zhang Chonghong; Chen Keqin; Wang Yinshu

2001-01-01

Studies of diffusion and aggregation behaviour of helium in metallic materials are very important to solve the problem of helium embrittlement in structural materials used in the environment of nuclear power. Experimental studies on helium diffusion and aggregation in austenitic stainless steels in a wide temperature range have been performed in authors' research group and the main results obtained are briefly summarized. The mechanism of nucleation-growth of helium-bubbles has been discussed and some problems to be solved are also given

Numerical investigation of potential stratification caused by a cryogenic helium spill inside a tunnel

Science.gov (United States)

Sinclair, Cameron; Malecha, Ziemowit; Jedrusyna, Artur

2018-04-01

The sudden release of cryogenic fluid into an accelerator tunnel can pose a significant health and safety risk. For this reason, it is important to evaluate the consequences of such a spill. Previous publications concentrated on either Oxygen Deficiency Hazard or the evaluation of mathematical models using experimental data. No studies to date have focussed on the influence of cryogen inlet conditions on flow development. In this paper, the stratification behaviour of low-temperature helium released into an air-filled accelerator tunnel is investigated for varying helium inlet diameters. A numerical model was constructed using the OpenFOAM Toolbox of a generalised 3D geometry, with similar hydraulic characteristics to the CERN and SLAC tunnels. This model has been validated against published experimental and numerical data. A dimensionless parameter, based on Bakke number, was then determined for the onset of stratification, taking into account the helium inlet diameter; a dimensionless parameter for the degree of stratification was also employed. The simulated flow behaviour is described in terms of these dimensionless parameters, as well as the temperature and oxygen concentration at various heights throughout the tunnel.

Design analysis of a Helium re-condenser

Science.gov (United States)

Muley, P. K.; Bapat, S. L.; Atrey, M. D.

2017-02-01

Modern helium cryostats deploy a cryocooler with a re-condenser at its II stage for in-situ re-condensation of boil-off vapor. The present work is a vital step in the ongoing research work of design of cryocooler based 100 litre helium cryostat with in-situ re-condensation. The cryostat incorporates a two stage Gifford McMahon cryocooler having specified refrigerating capacity of 40 W at 43 K for I stage and 1 W at 4.2 K for II stage. Although design of cryostat ensures thermal load for cryocooler below its specified refrigerating capacity at the second stage, successful in-situ re-condensation depends on proper design of re-condenser which forms the objective of this work. The present work proposes design of helium re-condenser with straight rectangular fins. Fins are analyzed for optimization of thermal performance parameters such as condensation heat transfer coefficient, surface area for heat transfer, re-condensing capacity, efficiency and effectiveness. The present work provides design of re-condenser with 19 integral fins each of 10 mm height and 1.5 mm thickness with a gap of 1.5 mm between two fins, keeping in mind the manufacturing feasibility, having efficiency of 80.96 % and effectiveness of 10.34.

Comparison of platelet formation in hydrogen and helium-implanted silicon

International Nuclear Information System (INIS)

Hebras, X.; Nguyen, P.; Bourdelle, K.K.; Letertre, F.; Cherkashin, N.; Claverie, A.

2007-01-01

A comparative transmission electron microscopy study of the extended defects formed in (0 0 1) Si after hydrogen or helium implantation was performed. Quantitative data on the size and density of the defects with different crystallographic variants have been obtained. Common defects observed after implants with a dose of 1 x 10 16 cm -2 and isothermal anneals at 350 o C in the presence of a stiffener were platelet-like structures lying on {1 0 0} habit planes parallel and perpendicular to the wafer surface. The differences in the defect morphology and in the variant platelet population are correspondingly related to the different chemical reactivity of H and He and the different compressive biaxial stresses generated by the H and He implants

Flaking and wave-like structure on metallic glasses induced by MeV-energy helium ions

International Nuclear Information System (INIS)

Paszti, F.; Fried, M.; Pogany, L.; Manuaba, A.; Mezey, G.; Kotai, E.; Lovas, I.; Lohner, T.; Pocs, L.

1982-11-01

Ten samples prepared from different kinds of metallic glasses (different in composition and manufacturing technology) were bombarded by 2 or 1 MeV helium ions with high fluence under different experimental circumstances. During bombardment the temperature increase of the samples caused by irradiation heating was estimated and kept below the temperature needed for the investigated metallic glass to be crystallized. In all cases the surface deformation processes were dominated by flaking i.e. nearly from the whole implanted area a layer suddenly flaked off with a uniform thickness of the applied ion projected range. The surface left behind the flaked layer can be characterized by a wave-like structure i.e. by a regular series of asymmetrical elevations. These elevations, which did not appear on the annealed samples, are caused by a mechanism developed during the bombardment of the amorphous structure (of metallic glasses) by high energy helium ions. Details of this unusual phenomenon are discussed. (author)

Advanced Gas Cooled Reactor Materials Program. Reducing helium impurity depletion in HTGR materials testing

International Nuclear Information System (INIS)

Baldwin, D.H.

1984-08-01

Moisture depletion in HTGR materials testing rigs has been empirically studied in the GE High Temperature Reactor Materials Testing Laboratory (HTRMTL). Tests have shown that increased helium flow rates and reduction in reactive (oxidizable) surface area are effective means of reducing depletion. Further, a portion of the depletion has been shown to be due to the presence of free C released by the dissociation of CH 4 . This depletion component can be reduced by reducing the helium residence time (increasing the helium flow rate) or by reducing the CH 4 concentration in the test gas. Equipment modifications to reduce depletion have been developed, tested, and in most cases implemented in the HTRMTL to date. These include increasing the Helium Loop No. 1 pumping capacity, conversion of metallic retorts and radiation shields to alumina, isolation of thermocouple probes from the test gas by alumina thermowells, and substitution of non-reactive Mo-TZM for reactive metallic structural components

Tritium release from lithium ceramics at constant temperature

International Nuclear Information System (INIS)

Verrall, R.A.; Miller, J.M.

1992-02-01

Analytic methods for post-irradiation annealing tests to measure tritium release from lithium ceramics at constant temperature are examined. Modifications to the Bertone (1) relations for distinguishing diffusion-controlled release from desorption-controlled release are shown. The methods are applied to tests on sintered LiA10 2 ; first-order desorption is shown to control tritium release for these tests

Investigation of tritium release and retention in lithium aluminate

International Nuclear Information System (INIS)

Kopasz, J.P.; Tistchenko, S.; Botter, F.

1991-01-01

Tritium release from lithium aluminate, although previously investigated by both in-reactor and ex-reactor experiments, remains poorly understood. Agreement between experiments is lacking, and the mechanisms responsible for tritium release from lithium aluminate are under debate. In an effort to improve our understanding of the mechanisms of tritium release from lithium ceramics, we have investigated tritium release from pure lithium aluminate and lithium aluminate doped with impurities. The results of these experiments on large grain size material indicate that after anneals at low temperature, a large fraction of the tritium present before the anneal remains in the sample. We have modeled this behavior based on first-order release from three types of sites. At the lowest temperature, the release is dominated by one site, while the tritium in the other sites is retained in the solid. Adding magnesium dopant to the ceramic appears to alter the distribution of tritium between the sites. This addition decreases the fraction of tritium released at 777 degree C, while increasing the fractions released at 538 and 950 degree C. 11 refs., 8 figs., 1 tab

Serial single molecule electron diffraction imaging: diffraction background of superfluid helium droplets

Science.gov (United States)

Zhang, Jie; He, Yunteng; Lei, Lei; Alghamdi, Maha; Oswalt, Andrew; Kong, Wei

2017-08-01

In an effort to solve the crystallization problem in crystallography, we have been engaged in developing a method termed "serial single molecule electron diffraction imaging" (SS-EDI). The unique features of SS-EDI are superfluid helium droplet cooling and field-induced orientation: together the two features constitute a molecular goniometer. Unfortunately, the helium atoms surrounding the sample molecule also contribute to a diffraction background. In this report, we analyze the properties of a superfluid helium droplet beam and its doping statistics, and demonstrate the feasibility of overcoming the background issue by using the velocity slip phenomenon of a pulsed droplet beam. Electron diffraction profiles and pair correlation functions of ferrocene-monomer-doped droplets and iodine-nanocluster-doped droplets are presented. The timing of the pulsed electron gun and the effective doping efficiency under different dopant pressures can both be controlled for size selection. This work clears any doubt of the effectiveness of superfluid helium droplets in SS-EDI, thereby advancing the effort in demonstrating the "proof-of-concept" one step further.

Tritium release from neutron-irradiated Li2O: Transport in porous sintered pellets

International Nuclear Information System (INIS)

Tanifuji, Takaaki; Yamaki, Daiju; Jitsukawa, Shiro

2006-01-01

The tritium release behavior from Li 2 O sintered pellets (81-88% T.D.) is examined by isothermal heating tests. (1) For the 88% T.D. specimens, the fraction of residual tritium is found to follow the square-root law of the annealing time. The rate-determining process is the migration in the connected micro-pore. (2) For the 81% T.D. specimens, which are annealed after irradiation at 630 K for 4 h, the fraction of residual tritium is also found to follow the square-root law of the annealing time. The rate-determining process is the migration in the connected micro-pore. (3) For the 81% T.D. specimens as irradiated, the tritium release rate is found to follow the square-root law of the annealing time. The rate-determining process is controlled by Kohlrauch stretched exponential form. Tritium trapped in irradiation defects released with recovering the defects by isothermal heating

Steric effects in release of amides from linkers in solid-phase synthesis. Molecular mechanics modeling of key step in peptide and combinatorial chemistry

DEFF Research Database (Denmark)

Norrby, Per-Ola; Jensen, Knud Jørgen

2006-01-01

Acidolytic release of an amide from a solid support by C-N bond cleavage is all ubiquitous and crucial step in many solid-phase syntheses. We have used molecular modeling of a pseudo-equilibrium to explore substituent and steric effects in the release of peptides. The high acid-lability of the ba......Acidolytic release of an amide from a solid support by C-N bond cleavage is all ubiquitous and crucial step in many solid-phase syntheses. We have used molecular modeling of a pseudo-equilibrium to explore substituent and steric effects in the release of peptides. The high acid......-lability of the backbone amide linkage (BAL), which releases sec. amides, compared to C-terminal amide anchoring, which releases primary amides, was rationalized by steric relief upon cleavage. Thus, the relative stability of the carbenium ion formed from the linker in the acidolytic release is an insufficient measure...

New white dwarf and subdwarf stars in the Sloan Digital Sky Survey Data Release 12

OpenAIRE

Kepler, S. O.; Pelisoli, Ingrid; Koester, Detlev; Ourique, Gustavo; Romero, Alejandra Daniela; Reindl, Nicole; Kleinman, Scot J.; Eisenstein, Daniel J.; Valois, A. Dean M.; Amaral, Larissa A.

2015-01-01

We report the discovery of 6576 new spectroscopically confirmed white dwarf and subdwarf stars in the Sloan Digital Sky Survey Data Release 12. We obtain Teff, log g and mass for hydrogen atmospherewhite dwarf stars (DAs) and helium atmospherewhite dwarf stars (DBs), estimate the calcium/helium abundances for the white dwarf stars with metallic lines (DZs) and carbon/helium for carbon-dominated spectra (DQs). We found one central star of a planetary nebula, one ultracompact helium binary (AM ...

Fabrication of different pore shapes by multi-step etching technique in ion-irradiated PET membranes

Science.gov (United States)

Mo, D.; Liu, J. D.; Duan, J. L.; Yao, H. J.; Latif, H.; Cao, D. L.; Chen, Y. H.; Zhang, S. X.; Zhai, P. F.; Liu, J.

2014-08-01

A method for the fabrication of different pore shapes in polyethylene terephthalate (PET)-based track etched membranes (TEMs) is reported. A multi-step etching technique involving etchant variation and track annealing was applied to fabricate different pore shapes in PET membranes. PET foils of 12-μm thickness were irradiated with Bi ions (kinetic energy 9.5 MeV/u, fluence 106 ions/cm2) at the Heavy Ion Research Facility (HIRFL, Lanzhou). The cross-sections of fundamental pore shapes (cylinder, cone, and double cone) were analyzed. Funnel-shaped and pencil-shaped pores were obtained using a two-step etching process. Track annealing was carried out in air at 180 °C for 120 min. After track annealing, the selectivity of the etching process decreased, which resulted in isotropic etching in subsequent etching steps. Rounded cylinder and rounded cone shapes were obtained by introducing a track-annealing step in the etching process. Cup and spherical funnel-shaped pores were fabricated using a three- and four-step etching process, respectively. The described multi-step etching technique provides a controllable method to fabricate new pore shapes in TEMs. Introduction of a variety of pore shapes may improve the separation properties of TEMs and enrich the series of TEM products.

Rapid preparation of solution-processed InGaZnO thin films by microwave annealing and photoirradiation

International Nuclear Information System (INIS)

Cheong, Heajeong; Ogura, Shintaro; Ushijima, Hirobumi; Yoshida, Manabu; Fukuda, Nobuko; Uemura, Sei

2015-01-01

We fabricated solution-processed indium–gallium–zinc oxide (IGZO) thin-film transistors (TFTs) by microwave (MW) annealing an IGZO precursor film followed by irradiating with vacuum ultraviolet (VUV) light. MW annealing allows more rapid heating of the precursor film than conventional annealing processes using a hot plate or electric oven and promotes the crystallization of IGZO. VUV irradiation was used to reduce the duration and temperature of the post-annealing step. Consequently, the IGZO TFTs fabricated through MW annealing for 5 min and VUV irradiation for 1 min exhibited an on/off current ratio of 10 8 and a field-effect mobility of 0.3 cm 2  V −1  s −1 . These results indicate that MW annealing and photoirradiation is an effective combination for annealing solution processed IGZO precursor films to prepare the semiconductor layers of TFTs

The consequences of helium production on microstructural development in isotopically tailored ferritic alloys

International Nuclear Information System (INIS)

Gelles, D.S.

1996-01-01

A series of alloys have been made adding various isotopes of nickel in order to vary the production of helium during irradiation by a two step nuclear reaction in a mixed spectrum reactor. The alloys use a base composition of Fe-12Cr with an addition of 1.5% nickel, either in the form of 60 Ni which produces no helium, 59 Ni which produces helium at a rate of about 10 appm He/dpa, or natural nickel ( Nat Ni) which provides an intermediate level of helium due to delayed development of 59 Ni. Specimens were irradiated in the HFIR at Oak Ridge, TN to ∼7 dpa at 300 and 400 degrees C. Microstructural examinations indicated that nickel additions promote precipitation in all alloys, but the effect appears to be much stronger at 400 degrees C than at 300 degrees C. There is sufficient dose by 7 dpa (and with 2 appm He) to initiate void swelling in ferritic/martensitic alloys. Little difference was found between response from 59 Ni and Nat Ni. Also, helium bubble development for high helium generation conditions appeared to be very different at 300 and 400 degrees C. At 300 degrees C, it appeared that high densities of bubbles formed whereas at 400 degrees C, bubbles could not be identified, possibly because of the complexity of the microstructure, but more likely because helium accumulated at precipitate interfaces

The consequences of helium production on microstructural development in isotopically tailored ferritic alloys

Energy Technology Data Exchange (ETDEWEB)

Gelles, D.S. [Pacific Northwest Lab., Richland, WA (United States)

1996-10-01

A series of alloys have been made adding various isotopes of nickel in order to vary the production of helium during irradiation by a two step nuclear reaction in a mixed spectrum reactor. The alloys use a base composition of Fe-12Cr with an addition of 1.5% nickel, either in the form of {sup 60}Ni which produces no helium, {sup 59}Ni which produces helium at a rate of about 10 appm He/dpa, or natural nickel ({sup Nat}Ni) which provides an intermediate level of helium due to delayed development of {sup 59}Ni. Specimens were irradiated in the HFIR at Oak Ridge, TN to {approx}7 dpa at 300 and 400{degrees}C. Microstructural examinations indicated that nickel additions promote precipitation in all alloys, but the effect appears to be much stronger at 400{degrees}C than at 300{degrees}C. There is sufficient dose by 7 dpa (and with 2 appm He) to initiate void swelling in ferritic/martensitic alloys. Little difference was found between response from {sup 59}Ni and {sup Nat}Ni. Also, helium bubble development for high helium generation conditions appeared to be very different at 300 and 400{degrees}C. At 300{degrees}C, it appeared that high densities of bubbles formed whereas at 400{degrees}C, bubbles could not be identified, possibly because of the complexity of the microstructure, but more likely because helium accumulated at precipitate interfaces.

Screw compressor system for industrial-scale helium refrigerators or industrial ammonia screw compressors for helium refrigeration systems; Schraubenkompressor-System fuer Helium-Grosskaelteanlage oder Ammoniak-Schraubenverdichter aus Industrieanwendungen fuer Helium-Kaelteanlagen

Energy Technology Data Exchange (ETDEWEB)

Fredrich, O.; Mosemann, D.; Zaytsev, D. [GEA Grasso GmbH Refrigeration Technology, Berlin (Germany)

2007-07-01

Material characteristics, requirements and measured data of ammonia and helium compression are compared. The compressor lines for industrial ammonia and helium refrigerators are presented, and important characteristics of the compressors are explained. The test stand for performance measurements with helium and ammonia is described, and results are presented. In spite of the different characteristics of the fluids, the compressor-specific efficiencies (supply characteristic, quality characteristic) were found to be largely identical. The values calculated for helium on the basis of NH3 test runs were found to be realistic, which means that the decades of experience with ammonia in industrial applications can be applied to helium compression as well. The design of screw compressor aggregates (skids) in industrial refrigeration is discussed and illustrated by examples. (orig.)

Focal cryotherapy: step by step technique description

Directory of Open Access Journals (Sweden)

Cristina Redondo

Full Text Available ABSTRACT Introduction and objective: Focal cryotherapy emerged as an efficient option to treat favorable and localized prostate cancer (PCa. The purpose of this video is to describe the procedure step by step. Materials and methods: We present the case of a 68 year-old man with localized PCa in the anterior aspect of the prostate. Results: The procedure is performed under general anesthesia, with the patient in lithotomy position. Briefly, the equipment utilized includes the cryotherapy console coupled with an ultrasound system, argon and helium gas bottles, cryoprobes, temperature probes and an urethral warming catheter. The procedure starts with a real-time trans-rectal prostate ultrasound, which is used to outline the prostate, the urethra and the rectal wall. The cryoprobes are pretested and placed in to the prostate through the perineum, following a grid template, along with the temperature sensors under ultrasound guidance. A cystoscopy confirms the right positioning of the needles and the urethral warming catheter is installed. Thereafter, the freeze sequence with argon gas is started, achieving extremely low temperatures (-40°C to induce tumor cell lysis. Sequentially, the thawing cycle is performed using helium gas. This process is repeated one time. Results among several series showed a biochemical disease-free survival between 71-93% at 9-70 month- follow-up, incontinence rates between 0-3.6% and erectile dysfunction between 0-42% (1–5. Conclusions: Focal cryotherapy is a feasible procedure to treat anterior PCa that may offer minimal morbidity, allowing good cancer control and better functional outcomes when compared to whole-gland treatment.

Gas Release as a Deformation Signal

Energy Technology Data Exchange (ETDEWEB)

Bauer, Stephen J. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

2017-09-01

Radiogenic noble gases are contained in crustal rock at inter and intra granular sites. The gas composition depends on lithology, geologic history, fluid phases, and the aging effect by decay of U, Th, and K. The isotopic signature of noble gases found in rocks is vastly different than that of the atmosphere which is contributed by a variety of sources. When rock is subjected to stress conditions exceeding about half its yield strength, micro-cracks begin to form. As rock deformation progresses a fracture network evolves, releasing trapped noble gases and changing the transport properties to gas migration. Thus, changes in gas emanation and noble gas composition from rocks could be used to infer changes in stress-state and deformation. The purpose of this study has been to evaluate the effect of deformation/strain rate upon noble gas release. Four triaxial experiments were attempted for a strain rate range of %7E10-8 /s (180,000s) to %7E 10-4/s (500s); the three fully successful experiments (at the faster strain rates) imply the following: (1) helium is measurably released for all strain rates during deformation, this release is in amounts 1-2 orders of magnitude greater than that present in the air, and (2) helium gas release increases with decreasing strain rate.

The ATP hydrolysis and phosphate release steps control the time course of force development in rabbit skeletal muscle.

Science.gov (United States)

Sleep, John; Irving, Malcolm; Burton, Kevin

2005-03-15

The time course of isometric force development following photolytic release of ATP in the presence of Ca(2+) was characterized in single skinned fibres from rabbit psoas muscle. Pre-photolysis force was minimized using apyrase to remove contaminating ATP and ADP. After the initial force rise induced by ATP release, a rapid shortening ramp terminated by a step stretch to the original length was imposed, and the time course of the subsequent force redevelopment was again characterized. Force development after ATP release was accurately described by a lag phase followed by one or two exponential components. At 20 degrees C, the lag was 5.6 +/- 0.4 ms (s.e.m., n = 11), and the force rise was well fitted by a single exponential with rate constant 71 +/- 4 s(-1). Force redevelopment after shortening-restretch began from about half the plateau force level, and its single-exponential rate constant was 68 +/- 3 s(-1), very similar to that following ATP release. When fibres were activated by the addition of Ca(2+) in ATP-containing solution, force developed more slowly, and the rate constant for force redevelopment following shortening-restretch reached a maximum value of 38 +/- 4 s(-1) (n = 6) after about 6 s of activation. This lower value may be associated with progressive sarcomere disorder at elevated temperature. Force development following ATP release was much slower at 5 degrees C than at 20 degrees C. The rate constant of a single-exponential fit to the force rise was 4.3 +/- 0.4 s(-1) (n = 22), and this was again similar to that after shortening-restretch in the same activation at this temperature, 3.8 +/- 0.2 s(-1). We conclude that force development after ATP release and shortening-restretch are controlled by the same steps in the actin-myosin ATPase cycle. The present results and much previous work on mechanical-chemical coupling in muscle can be explained by a kinetic scheme in which force is generated by a rapid conformational change bracketed by two

Double ionization of atomic helium under heavy ion impact

International Nuclear Information System (INIS)

Presnyakov, L.P.; Uskov, D.B.

1995-01-01

Cross sections for double ionization of helium by multiply-charged ion impact and the corresponding ratios of double-to-single ionization are presented as a sum of the contributions given by the one-step (shake-off) and two-step (TS) processes. An analytic form is found for the continuum wavefunction which is valid in both limiting cases of low and high velocities of the relative motion. Using this wavefunction, the TS cross sections are calculated within the independent-event model. The results for the ratios of double-to-single ionization show satisfactory agreement with the experimental data available. (author)

Self-trapping of helium in metals

International Nuclear Information System (INIS)

Wilson, W.D.; Bisson, C.L.; Baskes, M.I.

1981-01-01

Atomistic calculations are presented which demonstrate that helium atoms in a metal lattice are able to cluster with each other, producing vacancies and nearby self-interstitial defects. Even a small number of helium atoms is found to be sufficient to create these large distortions. As few as five interstitial helium can spontaneously produce a lattice vacancy and nearby self-interstitial. An eight-helium-atom cluster gives rise to two such defects, and 16 helium atoms to more than five self-interstitial vacancy pairs. It was noted that the self-interstitials prefer to agglomerate on the same ''side'' of the helium cluster rather than to spread themselves out uniformly. The binding energy of each additional helium atom to these clusters increases with helium concentration and the trap is apparently unsaturable. A rate theory using these atomistic binding energies has been used to calculate the kinetics of helium-bubble nucleation and growth. The results are consistent with measurements of the properties of helium resulting from tritium decay

Void nucleation by the helium atoms during lifetime of reactor pressure vessel

International Nuclear Information System (INIS)

Rahman, F.A.

1984-01-01

Void formation and growth has a great influence on the reactor pressure vessel steels during its lifetime and during post-irradiation annealing to increase its life. The present investigation aimed at the fact that if one can prevent void nucleation, accordingly one would not wary about void formation and growth. From that concept a model for helium production by transmutation reaction and corresponding swelling under irradiation conditions for several number of steels have been developed. This was done for recommending a steel type that can oppose such a phenomena. In the same time the present investigation gives a procedure utilizing such phenomena for checking the validity of pressure vessel steel used in the NPP

Temperature distribution in graphite during annealing in air cooled reactors

International Nuclear Information System (INIS)

Oliveira Avila, C.R. de.

1989-01-01

A model for the evaluation temperature distributions in graphite during annealing operation in graphite. Moderated an-cooled reactors, is presented. One single channel and one dimension for air and graphite were considered. A numerical method based on finite control volumes was used for partioning the mathematical equations. The problem solution involves the use of unsteady equations of mass, momentum and energy conservation for air, and energy conservation for graphite. The source term was considered as stored energy release during annealing for describing energy conservation in the graphite. The coupling of energy conservation equations in air and graphite is performed by the heat transfer term betwen air and graphite. The results agree with experimental data. A sensitivity analysis shown that the termal conductivity of graphite and the maximum inlet channel temperature have great effect on the maximum temperature reached in graphite during the annealing. (author)

Neutronics study on hybrid reactor cooled by helium, water and molten salt

International Nuclear Information System (INIS)

Li Zaixin; Feng Kaiming; Zhang Guoshu; Zheng Guoyao; Zhao Fengchao

2009-01-01

There is no serious magnetohydrodynamics (MHD) problem when helium,water or molten salt of Flibe flows in high magnetic field. Thus helium, water and Flibe were proposed as candidate of coolant for fusion-fission hybrid reactor based on magnetic confinement. The effect on neutronics of hybrid reactor due to coolant was investigated. The analyses of neutron spectra and fuel breeding of blanket with different coolants were performed. Variations of tritium breeding ratio (TBR), blanket energy multiplication (M) and keff with operating time were also studied. MCNP code was used for neutron transport simulation. It is shown that spectra change greatly with different coolants. The blanket with helium exhibits very hard spectrum and good tritium breeding ability. And fission reactions are mainly from fast neutron. The blanket with water has soft spectrum and high energy multiplication factor. However, it needs to improve TBR. The blanket with Flibe has hard spectrum and less energy release. (authors)

Implant Monitoring Measurements On Ultra Shallow Implants Before And After Anneal Using Photomodulated Reflection And Junction Photovoltage Measurement Techniques

Science.gov (United States)

Tallian, M.; Pap, A.; Mocsar, K.; Somogyi, A.; Nadudvari, Gy.; Kosztka, D.; Pavelka, T.

2011-01-01

Ultra shallow junctions are becoming widely used in the micro- and nanoelectronic devices, and novel measurement methods are needed to monitor the manufacturing processes. Photomodulated Reflection measurements before anneal and Junction Photovoltage-based sheet resistance measurements after anneal are non-contact, nondestructive techniques suitable for characterizing both the implantation and the annealing process. Tests verify that these methods are consistent with each other and by using them together, defects originating in the implantation and anneal steps can be separated.

Rapid preparation of solution-processed InGaZnO thin films by microwave annealing and photoirradiation

Energy Technology Data Exchange (ETDEWEB)

Cheong, Heajeong; Ogura, Shintaro; Ushijima, Hirobumi; Yoshida, Manabu; Fukuda, Nobuko; Uemura, Sei, E-mail: sei-uemura@aist.go.jp [Flexible Electronics Research Center (FLEC), National Institute of Advanced Industrial Science and Technology, Central 5, 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565 (Japan)

2015-06-15

We fabricated solution-processed indium–gallium–zinc oxide (IGZO) thin-film transistors (TFTs) by microwave (MW) annealing an IGZO precursor film followed by irradiating with vacuum ultraviolet (VUV) light. MW annealing allows more rapid heating of the precursor film than conventional annealing processes using a hot plate or electric oven and promotes the crystallization of IGZO. VUV irradiation was used to reduce the duration and temperature of the post-annealing step. Consequently, the IGZO TFTs fabricated through MW annealing for 5 min and VUV irradiation for 1 min exhibited an on/off current ratio of 10{sup 8} and a field-effect mobility of 0.3 cm{sup 2} V{sup −1} s{sup −1}. These results indicate that MW annealing and photoirradiation is an effective combination for annealing solution processed IGZO precursor films to prepare the semiconductor layers of TFTs.

Rapid thermal pulse annealing

International Nuclear Information System (INIS)

Miller, M.G.; Koehn, B.W.; Chaplin, R.L.

1976-01-01

Characteristics of recovery processes have been investigated for cases of heating a sample to successively higher temperatures by means of isochronal annealing or by using a rapid pulse annealing. A recovery spectra shows the same features independent of which annealing procedure is used. In order to determine which technique provides the best resolution, a study was made of how two independent first-order processes are separated for different heating rates and time increments of the annealing pulses. It is shown that the pulse anneal method offers definite advantages over isochronal annealing when annealing for short time increments. Experimental data by means of the pulse anneal techniques are given for the various substages of stage I of aluminium. (author)

Comparative studies of laser annealing technique and furnace annealing by X-ray diffraction and Raman analysis of lithium manganese oxide thin films for lithium-ion batteries

International Nuclear Information System (INIS)

Pröll, J.; Weidler, P.G.; Kohler, R.; Mangang, A.; Heißler, S.; Seifert, H.J.; Pfleging, W.

2013-01-01

The structure and phase formations of radio frequency magnetron sputtered lithium manganese oxide thin films (Li 1.1 Mn 1.9 O 4 ) under ambient air were studied. The influence of laser annealing and furnace annealing, respectively, on the bulk structure and surface phases was compared by using ex-situ X-ray diffraction and Raman analysis. Laser annealing technique formed a dominant (440)-reflection, furnace annealing led to both, (111)- and (440)-reflections within a cubic symmetry (S.G. Fd3m (227)). Additionally, in-situ Raman and in-situ X-ray diffraction were applied for online detection of phase transformation temperatures. In-situ X-ray diffraction measurements clearly identified the starting temperature for the (111)- and (440)-reflections around 525 °C and 400 °C, respectively. The 2θ Bragg peak positions of the characteristic (111)- and (440)-reflections were in good agreement with those obtained through conventional furnace annealing. Laser annealing of lithium manganese oxide films provided a quick and efficient technique and delivered a dominant (440)-reflection which showed the expected electrochemical behavior of the well-known two-step de-/intercalation process of lithium-ions into the cubic spinel structure within galvanostatic testing and cyclic voltammetry. - Highlights: ► Formation of cubic spinel-like phase of Li–Mn–O thin films by rapid laser annealing ► Laser annealing at 680 °C and 100 s was demonstrated as quick crystallization method. ► 400 °C was identified as characteristic onset temperature for (440)-reflex formation

Convective mixing in helium white dwarfs

International Nuclear Information System (INIS)

Vauclair, G.; Fontaine, G.

1979-01-01

The conditions under which convective mixing episodes take place between the helium envelopes and the underlying carbon layers in helium-rich white dwarfs are investigated. It is found that, for essentially any value of the initial helium content less than the maximum mass a helium convection zone can have, mixing does occur, and leads, in the vast majority of cases, to an almost pure carbon superficial composition. Mixing products that show only traces of carbon while retaining helium-dominated envelopes are possible only if the initial helium content is quite close to the maximum possible mass of the helium convection zone. In the presence of turbulence, this restriction could be relaxed, however, and the helium-rich lambda4670 stars may possibly be explained in this fashion

Friendly fermions of helium-three

International Nuclear Information System (INIS)

Leggatt, T.

1976-01-01

The importance of helium in showing up the effects of atomic indistinguishability and as a material by which to test some of the most fundamental principles of quantum mechanics is discussed. Helium not only remains liquid down to zero temperature but of the two isotopes helium-three has intrinsic spin 1/2 and should therefore obey the Pauli principle, while helium-four has spin zero and is expected to undergo Bose condensation. Helium-three becomes superfluid at temperatures of a few thousandths of a degree above absolute zero by the bulk liquid collecting its atoms into spinning pairs. There are three different superfluid phases, now conveniently called A, B and A 1 and each is characterised by a different behaviour of the spin and/or relative angular motion of the atoms composing the Cooper pairs. Problems surrounding the complicated physical system of helium-three are discussed. It is suggested that the combined coherence and directionality of superfluid helium-three should create some fascinating physics. (U.K.)

Helium-filled proportional counter and its operation mechanism at low temperatures

CERN Document Server

Isozumi, Y; Kishimoto, S

2002-01-01

The operation mechanism of helium-filled proportional counter (HFPC) at about 4.2 K is explained. Unstable behavior of HFPC is caused by releasing secondary-electron from the cathode by four kinds of active particles such as He sub n sup + , non-resonance photon from excited helium atom, non-resonance photon from He sub 2 sup * (A sup 1 Su sup +) and He sub 2 sup m (a sup 3 Su sup +). On experiments of HFPC behavior at low temperature, the following facts were observed; 1) main charge formation process in the electron avalanche is direct ionization by electron without Hornbeck-Molnar process. Accordingly, the gas amplification factor becomes small at low temperature. 2) Stable helium cation is He sub 2 sup + at room temperature, but cluster at low temperature. Large after-pulse is observed in output signal depends on cluster ion. The probability of secondary-electron emission decreased. The gas gain increased with increasing anode voltage. 3) By decreasing reaction rate of atom and molecule collision at low t...

Helium turbo-expander with an alternator

International Nuclear Information System (INIS)

Akiyama, Yoshitane

1980-01-01

Study was made on a helium turbo-expander, the heart of helium refrigerator systems, in order to develop a system which satisfies the required conditions. A helium turbo-expander with externally pressurized helium gas bearings at the temperature of liquid nitrogen and an alternator as a brake have been employed. The essential difference between a helium turbo-expander and a nitrogen turbo-expander was clarified. The gas bearing lubricated with nitrogen at room temperature and the gas bearing lubricated with helium at low temperature were tested. The flow rate of helium in a helium refrigerator for a large superconducting magnet is comparatively small, therefore a helium turbine must be small, but the standard for large turbine design can be applied to such small turbine. Using the alternator as a brake, the turbo-expander was easily controllable electrically. The prototype turbo-expander was made, and the liquefaction test with it and MHD power generation test were carried out. (Kako, I.)

In situ observation of structural change of nanostructured tungsten during annealing

International Nuclear Information System (INIS)

Yajima, Miyuki; Yoshida, Naoaki; Kajita, Shin; Tokitani, Masayuki; Baba, Tomotsugu; Ohno, Noriyasu

2014-01-01

Deformation of fiberform nanostructure and the dynamic behavior of helium (He) bubbles in fuzz tungsten (W) during annealing have been investigated by means of in situ cross-section observation using transmission electron microscopy and He desorption rate observation using thermal desorption spectroscopy (TDS). Thermal recovery of the nanostructure, such as shrinkage and coalescence of fine structure, annihilation of He bubbles, and large desorption of He gas, occurred around 1073–1173 K. The activation energy of He was estimated from a TDS peak that appeared around 300–400 K by using the Kissinger–Akahira–Sunose model-free-kinetics method. In addition, the TDS results of fiberform nanostructured tungsten were compared with those of tungsten samples irradiated with a high-energy He ion beam

Annealing and deposition effects of the chemical composition of silicon rich nitride

DEFF Research Database (Denmark)

Andersen, Karin Nordström; Svendsen, Winnie Edith; Stimpel-Lindner, T.

2005-01-01

Silicon-rich nitride, deposited by LPCVD, is a low stress amorphous material with a high refractive index. After deposition the silicon-rich nitride thin film is annealed at temperatures above 1100 oC to break N-H bonds, which have absorption peaks in the wavelength band important for optical...... in optical waveguides. This means that the annealing temperature must be high enough to break the N-H bonds, but no so high as to produce clusters. Therefore, the process window for an annealing step lies between 1100 and 1150 oC. The chemical composition of amorphous silicon-rich nitride has been...... investigated by Rutherford back scattering (RBS) and X-ray photoelectron spectroscopy (XPS). The influence of deposition parameters and annealing temperatures on the stoichiometry and the chemical bonds will be discussed. The origin of the clusters has been found to be silicon due to severe silicon out...

Microstructural modifications induced by rapid thermal annealing in plasma deposited SiOxNyHz films

International Nuclear Information System (INIS)

Prado, A. del; San Andres, E.; Martil, I.; Gonzalez-Diaz, G.; Bravo, D.; Lopez, F.J.; Fernandez, M.; Martinez, F.L.

2003-01-01

The effect of rapid thermal annealing (RTA) processes on the structural properties of SiO x N y H z films was investigated. The samples were deposited by the electron cyclotron resonance plasma method, using SiH 4 , O 2 and N 2 as precursor gases. For SiO x N y H z films with composition close to that of SiO 2 , which have a very low H content, RTA induces thermal relaxation of the lattice and improvement of the structural order. For films of intermediate composition and of compositions close to SiN y H z , the main effect of RTA is the release of H at high temperatures (T>700 deg. C). This H release is more significant in films containing both Si-H and N-H bonds, due to cooperative reactions between both kinds of bonds. In these films the degradation of structural order associated to H release prevails over thermal relaxation, while in those films with only N-H bonds, thermal relaxation predominates. For annealing temperatures in the 500-700 deg. C range, the passivation of dangling bonds by the nonbonded H in the films and the transition from the paramagnetic state to the diamagnetic state of the K center result in a decrease of the density of paramagnetic defects. The H release observed at high annealing temperatures is accompanied by an increase of density of paramagnetic defects

Self-Organization and Annealed Disorder in a Fracturing Process

DEFF Research Database (Denmark)

Caldarelli, Guido; Di Tolla, Francesco; Petri, Alberto

1996-01-01

We show that a vectorial model for inhomogeneous elastic media self-organizes under external stress. An onset of crack avalanches of every duration and length scale compatible with the lattice size is observed. The behavior is driven by the introduction of annealed disorder, i.e., by lowering...... condition for reproducing the algebraic distribution of the energy released during cracks formation....

Operating Manual of Helium Refrigerator (Rev. 2)

Energy Technology Data Exchange (ETDEWEB)

Song, K.M.; Son, S.H.; Kim, K.S.; Lee, S.K.; Kim, M.S. [Korea Electric Power Research Institute, Taejon (Korea)

2002-07-01

A helium refrigerator was installed as a supplier of 20K cold helium to the cryogenic distillation system of WTRF pilot plant. The operating procedures of the helium refrigerator, helium compressor and auxiliary apparatus are described for the safety and efficient operation in this manual. The function of the helium refrigerator is to remove the impurities from the compressed helium of about 250psig, to cool down the helium from ambient temperature to 20K through the heat exchanger and expansion engine and to transfer the cold helium to the cryogenic distillation system. For the smoothly operation of helium refrigerator, the preparation, the start-up, the cool-down and the shut-down of the helium refrigerator are described in this operating manual. (author). 3 refs., 14 tabs.

The afforestation problem: a heuristic method based on simulated annealing

DEFF Research Database (Denmark)

Vidal, Rene Victor Valqui

1992-01-01

This paper presents the afforestation problem, that is the location and design of new forest compartments to be planted in a given area. This optimization problem is solved by a two-step heuristic method based on simulated annealing. Tests and experiences with this method are also presented....

Electrical properties and annealing kinetics study of laser-annealed ion-implanted silicon

International Nuclear Information System (INIS)

Wang, K.L.; Liu, Y.S.; Kirkpatrick, C.G.; Possin, G.E.

1979-01-01

This paper describes measurements of electrical properties and the regrowth behavior of ion-implanted silicon annealed with an 80-ns (FWHM) laser pulse at 1.06 μm. The experimental results include: (1) a determination of threshold energy density required for melting using a transient optical reflectivity technique, (2) measurements of dopant distribution using Rutherford backscattering spectroscopy, (3) characterization of electrical properties by measuring reverse leakage current densities of laser-annealed and thermal-annealed mesa diodes, (4) determination of annealed junction depth using an electron-beam-induced-current technique, and (5) a deep-level-transient spectroscopic study of residual defects. In particular, by measuring these properties of a diode annealed at a condition near the threshold energy density for liquid phase epitaxial regrowth, we have found certain correlations among these various annealing behaviors and electrical properties of laser-annealed ion-implanted silicon diodes

Thermoelectric properties by high temperature annealing

Science.gov (United States)

Ren, Zhifeng (Inventor); Chen, Gang (Inventor); Kumar, Shankar (Inventor); Lee, Hohyun (Inventor)

2009-01-01

The present invention generally provides methods of improving thermoelectric properties of alloys by subjecting them to one or more high temperature annealing steps, performed at temperatures at which the alloys exhibit a mixed solid/liquid phase, followed by cooling steps. For example, in one aspect, such a method of the invention can include subjecting an alloy sample to a temperature that is sufficiently elevated to cause partial melting of at least some of the grains. The sample can then be cooled so as to solidify the melted grain portions such that each solidified grain portion exhibits an average chemical composition, characterized by a relative concentration of elements forming the alloy, that is different than that of the remainder of the grain.

Relation between the conditions of helium ion implantation and helium void equilibrium parameters

International Nuclear Information System (INIS)

Neklyudov, I.M.; Rybalko, V.F.; Ruzhitskij, V.V.; Tolstolutskaya, G.D.

1981-01-01

The conditions of helium thermodynamic equilibrium in a system of voids produced by helium ion bombardment of a metal sample are studied. As an initial equation for description of the equilibrium the Clapeyron equation was used. The equation is obtained relating basic parameters of helium voids (average diameter and density) to irradiation parameters (dose, ion energy (straggling)) and properties of the metal (surface tension coefficient, yield strength). Comparison of the calculations with experimental data on helium in nickel found in literature shows that the equation yields satisfactory resutls for the dose range 1.10 16 -1x10 17 cm -2 and temperatures T [ru

Annealing of proton-damaged GaAs and 1/f noise

NARCIS (Netherlands)

Chen, X.Y.; Folter, de L.C.

1997-01-01

GaAs layers were grown by MBE. The layers were then damaged by 3 MeV proton irradiation and later annealed. We performed Hall effect and low-frequency noise measurements at temperatures between 77 K and 300 K after each step. Several generation - recombination noise components created by proton

Cooling with Superfluid Helium

Energy Technology Data Exchange (ETDEWEB)

Lebrun, P; Tavian, L [European Organization for Nuclear Research, Geneva (Switzerland)

2014-07-01

The technical properties of helium II (‘superfluid’ helium) are presented in view of its applications to the cooling of superconducting devices, particularly in particle accelerators. Cooling schemes are discussed in terms of heat transfer performance and limitations. Large-capacity refrigeration techniques below 2 K are reviewed, with regard to thermodynamic cycles as well as process machinery. Examples drawn from existing or planned projects illustrate the presentation. Keywords: superfluid helium, cryogenics.

Effect of annealing temperature on the stress and structural properties of Ge core fibre

Science.gov (United States)

Zhao, Ziwen; Cheng, Xueli; Xue, Fei; He, Ting; Wang, Tingyun

2017-09-01

Effect of annealing temperature on the stress and structural properties of a Ge core fibre via the molten core drawing (MCD) method is investigated using Raman spectroscopy, Scanning electronic microscopy (SEM), and X-ray diffraction. The experimental results showed that the Raman peak position of the Ge fibre shifted from 297.6 cm-1 to 300.5 cm-1, and the FWHM value decreased from 4.53 cm-1 to 4.31 cm-1, when the annealing is carried out at 700 °C, 800 °C, and 900 °C, respectively. For the Ge core annealed at 900 °C, an apparent crystal grain can be seen in the SEM image, and the diffraction peaks of the (3 3 1) plane are generated in the X-ray diffraction spectra. These results show that optimising the annealing temperature allows the release of the residual stress in the Ge core. When the Ge core fibre is annealed at 900 °C, it exhibits the lowest residual stress and the highest crystal quality, and the quality improvement relative to that of the sample annealed at 800 °C is significant. Hence, annealing at around 900 °C can greatly improve the quality of a Ge core fibre. Further performance improvement of the Ge core fibre by annealing techniques can be anticipated.

Bed system performance in helium circulation mode

Energy Technology Data Exchange (ETDEWEB)

Kim, Yean Jin; Jung, Kwang Jin; Ahn, Do Hee; Chung, Hong Suk [UST, Daejeon (Korea, Republic of); Kang, Hee Suk [KAERI, Daejeon (Korea, Republic of); Yun, Sei Hun [NFRI, Deajeon (Korea, Republic of)

2016-05-15

As a part of the International Thermonuclear Experimental Reactor (ITER) Project, We have conducted an experiment for storing hydrogen to depleted uranium and zirconium cobalt. The helium blanket effect has been observed in experiments using metal hydrides. The collapse of the hydrogen isotopes are accompanied by the decay heat and helium-3. Helium-3 dramatically reduces the hydrogen isotope storage capacity by surrounding the metal. This phenomenon is called a helium blanket effect. In addition the authors are working on the recovery and removal techniques of helium-3. In this paper, we discuss the equipment used to test the helium blanket effect and the results of a helium circulation experiment. The helium-3 produced surrounds the storage material surface and thus disturbs the reaction of the storage material and the hydrogen isotope. Even if the amount of helium-3 is small, the storage capacity of the SDS bed significantly drops. This phenomenon is the helium blanket effect. To resolve this phenomenon, a circulating loop was introduced. Using a circulating system, helium can be separated from the storage material. We made a helium loop that includes a ZrCo bed. Then using a metal bellows pump, we tested the helium circulation.

Helium supply demand in future years

International Nuclear Information System (INIS)

Laverick, C.

1975-01-01

Adequate helium will be available to the year 2000 AD to meet anticipated helium demands for present day applications and the development of new superconducting technologies of potential importance to the nation. It is almost certain that there will not be enough helium at acceptable financial and energy cost after the turn of the century to meet the needs of the many promising helium based technologies now under development. Serious consideration should be given to establishing priorities in development and application based upon their relative value to the country. In the first half of the next century, three ways of estimating helium demand lead to cumulative ranges of from 75 to 125 Gcf (economic study), 89 to 470 Gcf (projected national energy growth rates) and 154 to 328 Gcf (needs for new technologies). These needs contrast with estimated helium resources in natural gas after 2000 AD which may be as low as 10 or 126 Gcf depending upon how the federal helium program is managed and the nation's natural gas resources are utilized. The technological and financial return on a modest national investment in further helium storage and a rational long term helium program promises to be considerable

Observations of a fcc helium gas-bubble superlattice in copper, nickel, and stainless steel

International Nuclear Information System (INIS)

Johnson, P.B.; Mazey, D.J.

1980-01-01

Transmission electron microscopy is used to investigate the spatial arrangement of the small gas bubbles produced in several fcc metals by 30 keV helium ion irradiation to high dose at 300 K. In what is a new result for this important class of metals it is found that the helium gas bubbles lie on a superlattice having an fcc structure with principal axes aligned with those of the metal matrix. The bubble lattice constant asub(i), is measured for a helium fluence just below the critical dose for radiation blistering of the metal surface (approximately 4 x 10 17 He/cm 2 ). Implantation rates are typically approximately 10 14 He ions cm -2 sec -1 . The values of asub(i) obtained for copper, nickel and stainless steel are (7.6 +- 0.3)nm, (6.6 +- 0.5)nm and (6.4 +- 0.5)nm respectively. Above the critical dose the bubble lattice is seen to survive in some blister caps as well as in the region between blisters. Bubble alignment is also observed in the case of hydrogen bubbles produced in copper by low energy proton irradiation to high fluence at 300 K. The presentation of this data was accompanied by a cine film illustrating the behaviour of the gas bubble lattice in copper during post-irradiation annealing in the electron microscope. A summary of the film is given in the appendix. (author)

Annealing Temperature Dependent Structural and Optical Properties of RF Sputtered ZnO Thin Films.

Science.gov (United States)

Sharma, Shashikant; Varma, Tarun; Asokan, K; Periasamy, C; Boolchandani, Dharmendar

2017-01-01

This work investigates the effect of annealing temperature on structural and optical properties of ZnO thin films grown over Si 100 and glass substrates using RF sputtering technique. Annealing temperature has been varied from 300 °C to 600 °C in steps of 100, and different microstructural parameters such as grain size, dislocation density, lattice constant, stress and strain have been evaluated. The structural and surface morphological characterization has been done using X-ray Diffraction (XRD) and Scanning Electron Microscope (SEM). XRD analysis reveals that the peak intensity of 002 crystallographic orientation increases with increased annealing temperature. Optical characterization of deposited films have been done using UV-Vis-NIR spectroscopy and photoluminescence spectrometer. An increase in optical bandgap of deposited ZnO thin films with increasing annealing temperature has been observed. The average optical transmittance was found to be more than 85% for all deposited films. Photoluminiscense spectra (PL) suggest that the crystalline quality of deposited film has increased at higher annealing temperature.

Arsenic ambient conditions preventing surface degradation of GaAs during capless annealing at high temperatures

Science.gov (United States)

Kang, C. H.; Kondo, K.; Lagowski, J.; Gatos, H. C.

1987-01-01

Changes in surface morphology and composition caused by capless annealing of GaAs were studied as a function of annealing temperature, T(GaAs), and the ambient arsenic pressure controlled by the temperature, T(As), of an arsenic source in the annealing ampul. It was established that any degradation of the GaAs surface morphology could be completely prevented, providing that T(As) was more than about 0.315T(GaAs) + 227 C. This empirical relationship is valid up to the melting point temperature of GaAs (1238 C), and it may be useful in some device-processing steps.

A novel approach to process carbonate samples for radiocarbon measurements with helium carrier gas

Energy Technology Data Exchange (ETDEWEB)

Wacker, L., E-mail: wacker@phys.ethz.ch [Laboratory of Ion Beam Physics, ETH Zurich, 8093 Zurich (Switzerland); Fueloep, R.-H. [Institute of Geology and Mineralogy, University of Cologne, 50674 Cologne (Germany); Hajdas, I. [Laboratory of Ion Beam Physics, ETH Zurich, 8093 Zurich (Switzerland); Molnar, M. [Laboratory of Ion Beam Physics, ETH Zurich, 8093 Zurich (Switzerland); Institute of Nuclear Research, Hungarian Academy of Sciences, 4026 Debrecen (Hungary); Rethemeyer, J. [Institute of Geology and Mineralogy, University of Cologne, 50674 Cologne (Germany)

2013-01-15

Most laboratories prepare carbonates samples for radiocarbon analysis by acid decomposition in evacuated glass tubes and subsequent reduction of the evolved CO{sub 2} to graphite in self-made reduction manifolds. This process is time consuming and labor intensive. In this work, we have tested a new approach for the preparation of carbonate samples, where any high-vacuum system is avoided and helium is used as a carrier gas. The liberation of CO{sub 2} from carbonates with phosphoric acid is performed in a similar way as it is often done in stable isotope ratio mass spectrometry where CO{sub 2} is released with acid in septum sealed tube under helium atmosphere. The formed CO{sub 2} is later flushed in a helium flow by means of a double-walled needle mounted from the tubes to the zeolite trap of the automated graphitization equipment (AGE). It essentially replaces the elemental analyzer normally used for the combustion of organic samples. The process can be fully automated from sampling the released CO{sub 2} in the septum-sealed tubes with a commercially available auto-sampler to the graphitization with the automated graphitization. The new method yields in low sample blanks of about 50000 years. Results of processed reference materials (IAEA-C2, FIRI-C) are in agreement with their consensus values.

Surface electrons of helium films

International Nuclear Information System (INIS)

Studart, N.; Hipolito, O.

1986-01-01

Theoretical calculations of some properties of two-dimensional electrons on a liquid helium film adsorbed on a solid substrate are reviewed. We describe the spectrum of electron bound states on bulk helium as well on helium films. The correlational properties, such as the structure factor and correlation energy, are determined as functions of the film thickness for different types of substrates in the framework of a Generalized Random-Phase Approximation. The collective excitations of this system are also described. The results for electrons on the surface of thin films and bulk helium are easily obtained. we examine the electron interaction with the excitations of the liquid helium surface resulting in a new polaron state, which was observed very recently. The ground state energy and the effective mass of this polaron are determined by using the path-integral formalism and unitary-transformation method. Recent speculations about the phase diagram of electrons on the helium film are also discussed. (Author) [pt

Diffusion length of minority carriers in scanning electron beam annealed silicon

International Nuclear Information System (INIS)

Smith, H.J.; Cilliers, R.; Bontemps, A.

1982-01-01

Ion implantation has advantages for solar cell production, but necessitates an annealing step. Various new transitory annealing methods have appeared recently. A particularly attractive method is multi-scan electron beam annealing of thermally isolated wafers. Energy is applied homogeneously over the whole target surface and the temperature rises throughout the thickness. Backscattering analysis shows good recrystallization in seconds. However the effect of this total heating on the diffusion length (Lsub(D)) must be investigated particularly in view of the degradation of Lsub(D) due to high temperature oven annealing. The semiconductor-electrolyte diode method was set up to measure the current generated in the cell due to the creation and diffusion of carriers in the silicon under photon irradiation. Comparison with a theoretical model yields Lsub(D). It appears that 3mA.cm - 2 of 15keV electrons recrystallizes damage in 2.5 seconds and does not decrease Lsub(D) in the bulk. In 4 seconds the Lsub(D) decreases and dopant diffusion occurs. On technical grounds this method can thus be applied for solar cell production. (Auth.)

Helium dilution refrigerator

International Nuclear Information System (INIS)

1973-01-01

A new system of continuous heat exchange for a helium dilution refrigerator is proposed. The 3 He effluent tube is concurrent with the affluent mixed helium tube in a vertical downward direction. Heat exchange efficiency is enhanced by placing in series a number of elements with an enlarged surface area

Magnetic structure of Fe-based amorphous and thermal annealed microwires

International Nuclear Information System (INIS)

Olivera, J.; Provencio, M.; Prida, V.M.; Hernando, B.; Santos, J.D.; Perez, M.J.; Gorria, P.; Sanchez, M.L.; Belzunce, F.J.

2005-01-01

The magnetic structure of amorphous and thermal annealed glass coated microwires is studied by thermomagnetic, DSC, and Bitter domain pattern techniques. The long-range dipolar interaction between parallel aligned microwires and the appearance of large Barkhausen jumps steps in the axially magnetized loops are discussed in terms of reversal magnetization process

Phase-stepping optical profilometry of atom mirrors

International Nuclear Information System (INIS)

MacLaren, D A; Goldrein, H T; Holst, B; Allison, W

2003-01-01

Electrically deformed single crystal mirrors will be a vital part of a first generation of scanning helium microscope (SHeM). Optimized mirrors will be used to focus thermal energy helium atoms into a surface-sensitive, low-energy probe, with a resolution that depends upon the precise mirror shape. Here, we present surface profilometry measurements of a prototype atom mirror. A temporal phase-stepping Mach-Zender fibre interferometer is used to profile the mirror surface with an accuracy of a few tens of nanometres. Results are compared with the theory of small deflections of an elastic thin plate. Our experiments suggest that relatively simple apparatus can induce the mirror profiles required to demagnify a conventional helium source into a microprobe suitable for a SHeM. Use of elliptical boundary conditions in the clamping mechanism afford biaxial bending in the crystal whilst a simple double-electrode design is demonstrated to be capable of asymmetric control of the mirror deformation

Backscattered Helium Spectroscopy in the Helium Ion Microscope: Principles, Resolution and Applications

NARCIS (Netherlands)

van Gastel, Raoul; Hlawacek, G.; Dutta, S.; Poelsema, Bene

2015-01-01

We demonstrate the possibilities and limitations for microstructure characterization using backscattered particles from a sharply focused helium ion beam. The interaction of helium ions with matter enables the imaging, spectroscopic characterization, as well as the nanometer scale modification of

Annealing of radiation-induced defects in vanadium and vanadium-titanium alloys

International Nuclear Information System (INIS)

Leguey, T.

1996-01-01

The annealing of defects induced by electron irradiation up to a dose of 6.10 21 m -2 at T<293 K has been investigated in single-crystals of pure vanadium and in vanadium-titanium alloys with compositions 0.3, 1 and 5 at.% Ti using positron annihilation spectroscopy. The recovery of the positron annihilation parameters in V single-crystals indicates that the defect annealing takes place in the temperature range 410-470 K without formation of microvoids for the present irradiation conditions. For the alloys the recovery onset is shifted to 460 K, the width of the annealing stage is gradually broadened with increasing Ti content, and microvoids are formed for annealing temperatures at the end of the recovery stage. The results show that the vacancy release from vacancy-interstitial impurity pairs and subsequent recombination with interstitial loops is the mechanism of the recovery in pure V. For V-Ti alloys, vacancy-Ti-interstitial impurity complexes and vacancy-Ti pairs appear to be the defects responsible for the positron trapping. The broadening of the recovery stage with increasing Ti content indicates that solute Ti is a very effective trap for vacancies in V. (orig.)

HeREF-2003: Helium Refrigeration Techniques

CERN Multimedia

2003-01-01

CERN Technical Training 2003: Learning for the LHC ! Theory, Technology, Maintenance and Control of Helium Refrigerators HeREF-2003 is a course in the framework of the 2002 Technical Training Programme, that will provide a complete introduction to Helium refrigeration, with a practical approach to theory, technology, maintenance and control of Helium refrigeration installations. Theoretical aspects and equations will be limited to a minimum. HeREF-2003 targets an audience of technicians and operators of Helium refrigeration plants at CERN, as well as physicists and engineers needing an overview of current Helium refrigeration techniques. HeREF-2003 will address, among other, issues related to component technology, installation maintenance, process control and Helium purity. A commented visit to a couple of CERN Helium refrigeration or liquefaction plants will also take place. Duration: 7 half days (4 mornings and 3 afternoons), 6-10 October, 2003 Cost per participant: 500.- CHF Language: Bilingual English...

HeREF-2003 : Helium Refrigeration Techniques

CERN Multimedia

2003-01-01

CERN Technical Training 2003: Learning for the LHC ! Theory, Technology, Maintenance and Control of Helium Refrigerators HeREF-2003 is a course in the framework of the 2002 Technical Training Programme, that will provide a complete introduction to Helium refrigeration, with a practical approach to theory, technology, maintenance and control of Helium refrigeration installations. Theoretical aspects and equations will be limited to a minimum. HeREF-2003 targets an audience of technicians and operators of Helium refrigeration plants at CERN, as well as physicists and engineers needing an overview of current Helium refrigeration techniques. HeREF-2003 will address, among other, issues related to component technology, installation maintenance, process control and Helium purity. A commented visit to a couple of CERN Helium refrigeration or liquefaction plants will also take place. • Duration: 7 half days (4 mornings and 3 afternoons), 6-10 October, 2003 • Cost per participant: 500.- CHF
...

GeO2/Ge structure submitted to annealing in deuterium: Incorporation pathways and associated oxide modifications

Science.gov (United States)

Bom, N. M.; Soares, G. V.; Hartmann, S.; Bordin, A.; Radtke, C.

2014-10-01

Deuterium (D) incorporation in GeO2/Ge structures following D2 annealing was investigated. Higher D concentrations were obtained for GeO2/Ge samples in comparison to their SiO2/Si counterparts annealed in the same conditions. Oxygen vacancies produced during the annealing step in D2 constitute defect sites for D incorporation, analogous to defects at the SiO2/Si interfacial region. Besides D incorporation, volatilization of the oxide layer is also observed as a consequence of D2 annealing, especially in the high temperature regime of the present study (>450 °C). In parallel to this volatilization, the stoichiometry and chemical structure of remnant oxide are modified as well. These results evidence the broader impact of forming gas annealing in dielectric/Ge structures with respect to SiO2/Si counterparts.

Scalable effective-temperature reduction for quantum annealers via nested quantum annealing correction

Science.gov (United States)

Vinci, Walter; Lidar, Daniel A.

2018-02-01

Nested quantum annealing correction (NQAC) is an error-correcting scheme for quantum annealing that allows for the encoding of a logical qubit into an arbitrarily large number of physical qubits. The encoding replaces each logical qubit by a complete graph of degree C . The nesting level C represents the distance of the error-correcting code and controls the amount of protection against thermal and control errors. Theoretical mean-field analyses and empirical data obtained with a D-Wave Two quantum annealer (supporting up to 512 qubits) showed that NQAC has the potential to achieve a scalable effective-temperature reduction, Teff˜C-η , with 0 temperature of a quantum annealer. Such effective-temperature reduction is relevant for machine-learning applications. Since we demonstrate that NQAC achieves error correction via a reduction of the effective-temperature of the quantum annealing device, our results address the problem of the "temperature scaling law for quantum annealers," which requires the temperature of quantum annealers to be reduced as problems of larger sizes are attempted to be solved.

Helium localization around the microscopic impurities embedded to liquid helium

International Nuclear Information System (INIS)

Gordon, E.B.; Shestakov, A.F.

2000-01-01

The structure and properties of the environment round the impurity atoms (Im) embedded in liquid helium are considered. It is shown that there are two qualitatively different types of structure of the He atom layer next to Im - attraction and repulsion structures. For the center attraction structure (strong Im-He interaction) the Im-He separation is longer than the equilibrium one for the pair Im-He potential, and the density and localization of He atoms are higher than in the bulk. It this case the He atom content in the layer, n, is almost independent of applied pressure. In the repulsion structure realized for alkaline metal atoms the Im-He separation is shorter than the equilibrium one and the density is lower than in the helium bulk. At T approx 1 K occupied are several states with different n and their energies differ only by approx 0.1 K, an increase in pressure resulting in a considerable reduction of n. The optical and EPR spectra of the atoms embedded to liquid and solid helium are interpreted on the basis of the analysis carried out. A simple model is proposed to evaluate the helium surroundings characteristics from the experimental pressure dependences of atomic line shifts in the absorption and emission spectra. The attraction structures in 3 He - 4 He mixtures are suggested to be highly enriched by 4 He atoms which the repulsion structures - by 3 He atoms. a possibility for existence of phase transitions in helium shells surrounding impurity atoms is considered

Gas release from pressurized closed pores in nuclear fuels

International Nuclear Information System (INIS)

Bailey, P.; Donnelly, S.E.; Armour, D.G.; Matzke, H.

1988-01-01

Gas release from the nuclear fuels UO 2 and UN out of pressurized closed pores produced by autoclave anneals has been studied by Thermal Desorption Spectrometry (TDS). Investigation of gas release during heating and cooling has indicated stress related mechanical effects leading to gas release. This release occurred in a narrow temperature range between about 1000 and 1500 K for UO 2 , but it continued down to ambient temperature for UN. No burst release was observed above 1500 K for UO 2 . (orig.)

Test of a cryogenic helium pump

International Nuclear Information System (INIS)

Lue, J.W.; Miller, J.R.; Walstrom, P.L.; Herz, W.

1981-01-01

The design of a cryogenic helium pump for circulating liquid helium in a magnet and the design of a test loop for measuring the pump performance in terms of mass flow vs pump head at various pump speeds are described. A commercial cryogenic helium pump was tested successfully. Despite flaws in the demountable connections, the piston pump itself has performed satisfactorily. A helium pump of this type is suitable for the use of flowing supercritical helium through Internally Cooled Superconductor (ICS) magnets. It has pumped supercritical helium up to 7.5 atm with a pump head up to 2.8 atm. The maximum mass flow rate obtained was about 16 g/s. Performance of the pump was degraded at lower pumping speeds

Deconvoluting the mechanism of microwave annealing of block copolymer thin films.

Science.gov (United States)

Jin, Cong; Murphy, Jeffrey N; Harris, Kenneth D; Buriak, Jillian M

2014-04-22

The self-assembly of block copolymer (BCP) thin films is a versatile method for producing periodic nanoscale patterns with a variety of shapes. The key to attaining a desired pattern or structure is the annealing step undertaken to facilitate the reorganization of nanoscale phase-segregated domains of the BCP on a surface. Annealing BCPs on silicon substrates using a microwave oven has been shown to be very fast (seconds to minutes), both with and without contributions from solvent vapor. The mechanism of the microwave annealing process remains, however, unclear. This work endeavors to uncover the key steps that take place during microwave annealing, which enable the self-assembly process to proceed. Through the use of in situ temperature monitoring with a fiber optic temperature probe in direct contact with the sample, we have demonstrated that the silicon substrate on which the BCP film is cast is the dominant source of heating if the doping of the silicon wafer is sufficiently low. Surface temperatures as high as 240 °C are reached in under 1 min for lightly doped, high resistivity silicon wafers (n- or p-type). The influence of doping, sample size, and BCP composition was analyzed to rule out other possible mechanisms. In situ temperature monitoring of various polymer samples (PS, P2VP, PMMA, and the BCPs used here) showed that the polymers do not heat to any significant extent on their own with microwave irradiation of this frequency (2.45 GHz) and power (∼600 W). It was demonstrated that BCP annealing can be effectively carried out in 60 s on non-microwave-responsive substrates, such as highly doped silicon, indium tin oxide (ITO)-coated glass, glass, and Kapton, by placing a piece of high resistivity silicon wafer in contact with the sample-in this configuration, the silicon wafer is termed the heating element. Annealing and self-assembly of polystyrene-block-poly(2-vinylpyridine) (PS-b-P2VP) and polystyrene-block-poly(methyl methacrylate) (PS

Cascade annealing: an overview

International Nuclear Information System (INIS)

Doran, D.G.; Schiffgens, J.O.

1976-04-01

Concepts and an overview of radiation displacement damage modeling and annealing kinetics are presented. Short-term annealing methodology is described and results of annealing simulations performed on damage cascades generated using the Marlowe and Cascade programs are included. Observations concerning the inconsistencies and inadequacies of current methods are presented along with simulation of high energy cascades and simulation of longer-term annealing

Post-giant evolution of helium stars

International Nuclear Information System (INIS)

Schoenberner, D.

1977-01-01

Extremely hydrogen deficient stars (helium stars and R Coronae Borealis variables) are considered to be remnants of double shell source stars (of the asymptotic giant branch). The evolution of stars with a condensed C/O-core and a helium envelope is followed numerically from the red giant stage to the white dwarf domain, crossing the regions of R CrB- and helium stars (so far analyzed). They have typically masses M/M(sun) = 0.7 and luminosities log L/L(sun) = 4.1. The time for crossing the helium star domain is some 10 3 years. The corresponding times in the R CrB-region amounts up to several 10 4 years. The lower limit of the death rate of helium stars is estimated to be 4 x 10 -14 pc -3 yr -1 . This value is only a factor of ten lower than the birth rate of all non-DA white dwarfs. It is therefore possible that the helium stars are the precursors of helium rich white dwarfs. As a consequence, a significant fraction of all stars which end their lives as white dwarfs should pass through the helium star phase. (orig.) [de

Manufacture of Radio Frequency Micromachined Switches with Annealing

OpenAIRE

Lin, Cheng-Yang; Dai, Ching-Liang

2014-01-01

The fabrication and characterization of a radio frequency (RF) micromachined switch with annealing were presented. The structure of the RF switch consists of a membrane, coplanar waveguide (CPW) lines, and eight springs. The RF switch is manufactured using the complementary metal oxide semiconductor (CMOS) process. The switch requires a post-process to release the membrane and springs. The post-process uses a wet etching to remove the sacrificial silicon dioxide layer, and to obtain the suspe...

Mixed helium-3 - helium-4 calorimeter. Very low temperature calorimetry; Calorimetre mixte a helium-3 et helium-4. Calorimetrie a tres basse temperature

Energy Technology Data Exchange (ETDEWEB)

Testard, O [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

1966-06-01

A description is given of a double-racket calorimeter using helium-4 and helium-3 as the cryogenic fluids and making it possible to vary the temperature continuously from 0.35 K to 4.2 K. By using an electric thermal regulator together with liquid hydrogen it is possible to extend this range up to about 30 K. In the second part, a review is made of the various, methods available for measuring specific heats. The method actually used in the apparatus previously described is described in detail. The difficulties arising from the use of an exchange gas for the thermal contact have been solved by the use of adsorption pumps. (author) [French] On decrit un calorimetre a double enceinte utilisant comme fluide cryogenique l'helium-4 et l'helium-3 et permettant de varier continuement la temperature de 0,35 K a 4,2 K. L'utilisation d'un regulateur thermique electrique ainsi que celle d'hydrogene, liquide permettent d'etendre cette gamme jusqu'a 30 K environ. Dans une deuxieme partie, on passe en revue les diverses methodes de mesure des chaleurs specifiques. La methode concrete utilisee dans l'appareil precedemment decrit est exposee en detail. Les difficultes inherentes a l'utilisation de gaz d'echange comme agent de contact thermique ont ete levees par la mise en oeuvre de pompes a adsorbant. (auteur)

Calorimetric features of release of plastic deformation induced internal stresses, and approach to equilibrium state on annealing of crystals and glasses

Energy Technology Data Exchange (ETDEWEB)

Johari, G.P., E-mail: joharig@mcmaster.ca

2014-04-01

Highlights: • Stress release in a glass occurs at a faster rate than structural relaxation. • Plastically-deformed glass would show two exothermic minima, and no glass transition. • Enthalpy matching procedure would yield an inaccurate fictive temperature. • Complex heat capacity may distinguish plastically-deformed from quench-formed glass. - Abstract: Plastic deformation of crystals and glasses produces internal strains (stresses), which change their energy and other thermodynamic properties. On annealing, these stresses decrease at a rate faster than the structure relaxes toward the equilibrium state. Mechanism of such relaxations in crystals differs from that in glasses and it also differs for glasses of different types. In all cases, the energy related properties decrease with time isothermally and on heating, resembling the structure relaxation of a stress-free glass. We consider these features and argue that kinetics of enthalpy loss with time yields the rate constants of the stress release and of the structure change, and not the viscosity determining α-relaxation time. Since thermal cycling does not recover the enthalpy from internal stresses, a glass with stresses has neither a glass-softening temperature, T{sub g}, nor a fictive temperature, T{sub f}. Plastic deformation would not rejuvenate a physically aged glass to the properties of its un-aged state. The Prigogine–Defay ratio can be extended to all T{sub f}s, and used to investigate the effect of distribution of relaxation times on its value, but it can not be defined for an internally stressed glass. After discussing the effects of annealing on the heat capacity and DSC scans, we conclude that on slow heating, glass with deformation-induced stresses would show two exothermic minima, and normal glass would show only one such minimum. Temperature-modulated scanning calorimetry would also distinguish an internally stressed glass from an equally high-enthalpy, stress-free glass. Enthalpy

Nanorods on surface of GaN-based thin-film LEDs deposited by post-annealing after photo-assisted chemical etching

Science.gov (United States)

Chen, Lung-Chien; Lin, Wun-Wei; Liu, Te-Yu

2017-01-01

This study investigates the optoelectronic characteristics of gallium nitride (GaN)-based thin-film light-emitting diodes (TF-LEDs) that are formed by a two-step transfer process that involves wet etching and post-annealing. In the two-step transfer process, GaN LEDs were stripped from sapphire substrates by the laser lift-off (LLO) method using a KrF laser and then transferred onto ceramic substrates. Ga-K nanorods were formed on the surface of the GaN-based TF-LEDs following photo-assisted chemical etching and photo-enhanced post-annealing at 100 °C for 1 min. As a result, the light output power of GaN-based TF-LEDs with wet etching and post-annealing was over 72% more than that of LEDs that did not undergo these treatments.

Rapid Annealing of Iron Implanted Hg(1-x)Cd(x)Te

Science.gov (United States)

1990-03-01

Alnrroveii rFoi’ PubikI Release; distributin tilIntl ted DTICELECTEJUN 12 IMU’ BEest Available Cop, D i ..:6 (J,•, 4iL& , AD Rapid Annealing of Ion...Recently, we have received from Or.J. Dinan of the Night Vision and Electro-optic Army Labs at Fort Belvoir a few electrically uncharacterized Hg

Influence of alloying and secondary annealing on anneal hardening ...

Indian Academy of Sciences (India)

Unknown

Influence of alloying and secondary annealing on anneal hardening effect at sintered copper alloys. SVETLANA NESTOROVIC. Technical Faculty Bor, University of Belgrade, Bor, Yugoslavia. MS received 11 February 2004; revised 29 October 2004. Abstract. This paper reports results of investigation carried out on sintered ...

Controllable nitrogen doping in as deposited TiO{sub 2} film and its effect on post deposition annealing

Energy Technology Data Exchange (ETDEWEB)

Deng, Shaoren; Devloo-Casier, Kilian; Devulder, Wouter; Dendooven, Jolien; Deduytsche, Davy; Detavernier, Christophe, E-mail: Christophe.Detavernier@ugent.be [Department of Solid State Sciences, Ghent University, Krijgslaan 281/S1, B-9000 Gent (Belgium); Verbruggen, Sammy W. [Department of Bio-Engineering Sciences, University of Antwerp, Groenenborgerlaan 171, B-2020 Antwerp, Belgium and Center for Surface Chemistry and Catalysis, KU Leuven, Kasteelpark Arenberg 23, B-3001 Heverlee (Belgium); Lenaerts, Silvia [Department of Bio-Engineering Sciences, University of Antwerp, Groenenborgerlaan 171, B-2020 Antwerp (Belgium); Martens, Johan A. [Center for Surface Chemistry and Catalysis, KU Leuven, Kasteelpark Arenberg 23, B-3001 Heverlee (Belgium); Van den Berghe, Sven [SCK-CEN, Boeretang 200, B-2400 Mol (Belgium)

2014-01-15

In order to narrow the band gap of TiO{sub 2}, nitrogen doping by combining thermal atomic layer deposition (TALD) of TiO{sub 2} and plasma enhanced atomic layer deposition (PEALD) of TiN has been implemented. By altering the ratio between TALD TiO{sub 2} and PEALD TiN, the as synthesized TiO{sub x}N{sub y} films showed different band gaps (from 1.91 eV to 3.14 eV). In situ x-ray diffraction characterization showed that the crystallization behavior of these films changed after nitrogen doping. After annealing in helium, nitrogen doped TiO{sub 2} films crystallized into rutile phase while for the samples annealed in air a preferential growth of the anatase TiO{sub 2} along (001) orientation was observed. Photocatalytic tests of the degradation of stearic acid were done to evaluate the effect of N doping on the photocatalytic activity.

Determination of helium in beryl minerals

International Nuclear Information System (INIS)

Souza Barcellos, E. de.

1985-08-01

In order to obtain the diffusion coefficients of helium in beryl and phenacite samples at various temperatures, helium leak rates were measured in these minerals at these temperatures. Mass spectrometry (MS) was used to obtain helium leak rates and the gas flow was plotted against time. The gas quantity determined by MS was first obtained at various temperatures until no helium leak rate was detected. After that, these samples were irradiated with fast neutrons to produce helium which was measured again. This procedure was used to estimate the experimental error. The quantity of helium produced by interaction of gamma radiation with beryl minerals was theoretically calculated from the amount of thorium-232 at the neighbourhood of the samples. The quantity of helium produced in the minerals due to uranium and thorium decay was calculated using the amount of these heavy elements, and the results were compared with the amounts determined by MS. The amount of potassium-40 was determined in order to derive the quantity of argonium-40, since some workers found argonium in excess in these minerals. The quantity of helium in the beryl samples (s) was determined in the center and in the surface of the samples in order to obtain informations about the effectiveness of the Be(α, η) He reaction. Beryl and phenacite minerals were choosen in this research since they are opposite each other with respect to the helium contents. Both have beryllium in their compositon but beryl hold a large amount of helium while phenacite, in spite of having about three times more beryllium than beryl, do not hold the gas. (author) [pt

Helium localisation in tritides

International Nuclear Information System (INIS)

Flament, J.L.; Lozes, G.

1982-06-01

Study of titanium and LaNi 5 type alloys tritides lattice parameters evolution revealed that helium created by tritium decay remains in interstitial sites up to a limit material dependant concentration. Beyond this one exceeding helium precipites in voids [fr

Measurement of OH density and air-helium mixture ratio in an atmospheric-pressure helium plasma jet

International Nuclear Information System (INIS)

Yonemori, Seiya; Ono, Ryo; Nakagawa, Yusuke; Oda, Tetsuji

2012-01-01

The absolute density of OH radicals in an atmospheric-pressure helium plasma jet is measured using laser-induced fluorescence (LIF). The plasma jet is generated in room air by applying a pulsed high voltage onto a quartz tube with helium gas flow. The time-averaged OH density is 0.10 ppm near the quartz tube nozzle, decreasing away from the nozzle. OH radicals are produced from water vapour in the helium flow, which is humidified by water adsorbed on the inner surface of the helium line and the quartz tube. When helium is artificially humidified using a water bubbler, the OH density increases with humidity and reaches 2.5 ppm when the water vapour content is 200 ppm. Two-dimensional distribution of air-helium mixture ratio in the plasma jet is also measured using the decay rate of the LIF signal waveform which is determined by the quenching rate of laser-excited OH radicals. (paper)

Annealing of hydrogen-induced defects in RF-plasma-treated Si wafers: ex situ and in situ transmission electron microscopy studies

International Nuclear Information System (INIS)

Ghica, C; Nistor, L C; Vizireanu, S; Dinescu, G

2011-01-01

The smart-cut(TM) process is based on inducing and processing structural defects below the free surface of semiconductor wafers. The necessary defects are currently induced by implantation of light elements such as hydrogen or helium. An alternative softer way to induce shallow subsurface defects is by RF-plasma hydrogenation. To facilitate the smart-cut process, the wafers containing the induced defects need to be subjected to an appropriate thermal treatment. In our experiments, (0 0 1) Si wafers are submitted to 200 and 50 W hydrogen RF-plasma and are subsequently annealed. The samples are studied by transmission electron microscopy (TEM), before and after annealing. The plasma-introduced defects are {1 1 1} and {1 0 0} planar-like defects and nanocavities, all of them involving hydrogen. Many nanocavities are aligned into strings almost parallel to the wafer surface. The annealing is performed either by furnace thermal treatment at 550 deg. C, or by in situ heating in the electron microscope at 450, 650 and 800 deg. C during the TEM observations. The TEM microstructural studies indicate a partial healing of the planar defects and a size increase of the nanometric cavities by a coalescence process of the small neighbouring nanocavities. By annealing, the lined up nanometric voids forming chains in the as-hydrogenated sample coalesced into well-defined cracks, mostly parallel to the wafer surface.

Precipitation response of annealed type 316 stainless steel in HFIR irradiations at 550 to 6800C

International Nuclear Information System (INIS)

Maziasz, P.J.

1978-01-01

Precipitation in annealed type 316 stainless steel after HFIR irradiation at 550--680 0 C to fluences producing 2000--3300 at. ppM He and 30--47 dpa is changed relative to fast reactor or thermal aging exposure to similar temperatures and times. The phases observed after HFIR irradiation are the same as those observed after aging to temperatures 70--200 0 C higher or for much longer times. There is a similar temperature shift in addition to different phases observed for HFIR irradiation compared with EBR-II. The changes observed are coincident with including simultaneous helium production to high levels in the irradiation damage products of the material

Resistivity studies of interstitial helium mobility in niobium

International Nuclear Information System (INIS)

Chen, C.G.; Birnbaum, H.K.; Johnson, A.B. Jr.

1979-01-01

The mobility of interstitial helium in Nb and Nb-O alloys was studied in the temperature range of 10-383 K using resistivity measurements. The helium was introduced by radioactive decay of solute tritium (approximately 1 at%). At T < 100 K the resistivity increased due to conversion of tritium trapped at oxygen interstititals to helium. The formation of helium caused a very significant resistance increase at room temperature and above. The results suggest that helium is mobile at temperatures above 295 K and that the precipitation of large helium bubbles occurs along grain boundaries. The mobile helium species may either be single interstitials or small helium clusters. The activation enthalpy for the diffusion of the mobile helium species was estimated to be about 55 kJ/mol (0.66 eV). (Auth.)

Helium-induced hardening effect in polycrystalline tungsten

Science.gov (United States)

Kong, Fanhang; Qu, Miao; Yan, Sha; Zhang, Ailin; Peng, Shixiang; Xue, Jianming; Wang, Yugang

2017-09-01

In this paper, helium induced hardening effect of tungsten was investigated. 50 keV He2+ ions at fluences vary from 5 × 1015 cm-2 to 5 × 1017 cm-2 were implanted into polycrystalline tungsten at RT to create helium bubble-rich layers near the surface. The microstructure and mechanical properties of the irradiated specimens were studied by TEM and nano-indentor. Helium bubble rich layers are formed in near surface region, and the layers become thicker with the rise of fluences. Helium bubbles in the area of helium concentration peak are found to grow up, while the bubble density is almost unchanged. Obvious hardening effect is induced by helium implantation in tungsten. Micro hardness increases rapidly with the fluence firstly, and more slowly when the fluence is above 5 × 1016 cm-2. The hardening effect of tungsten can be attributed to helium bubbles, which is found to be in agreement with the Bacon-Orowan stress formula. The growing diameter is the major factor rather than helium bubbles density (voids distance) in the process of helium implantation at fluences below 5 × 1017 cm-2.

Low helium flux from the mantle inferred from simulations of oceanic helium isotope data

Science.gov (United States)

Bianchi, Daniele; Sarmiento, Jorge L.; Gnanadesikan, Anand; Key, Robert M.; Schlosser, Peter; Newton, Robert

2010-09-01

The high 3He/ 4He isotopic ratio of oceanic helium relative to the atmosphere has long been recognized as the signature of mantle 3He outgassing from the Earth's interior. The outgassing flux of helium is frequently used to normalize estimates of chemical fluxes of elements from the solid Earth, and provides a strong constraint to models of mantle degassing. Here we use a suite of ocean general circulation models and helium isotope data obtained by the World Ocean Circulation Experiment to constrain the flux of helium from the mantle to the oceans. Our results suggest that the currently accepted flux is overestimated by a factor of 2. We show that a flux of 527 ± 102 mol year - 1 is required for ocean general circulation models that produce distributions of ocean ventilation tracers such as radiocarbon and chlorofluorocarbons that match observations. This new estimate calls for a reevaluation of the degassing fluxes of elements that are currently tied to the helium fluxes, including noble gases and carbon dioxide.

Manufacture of Radio Frequency Micromachined Switches with Annealing

Directory of Open Access Journals (Sweden)

Cheng-Yang Lin

2014-01-01

Full Text Available The fabrication and characterization of a radio frequency (RF micromachined switch with annealing were presented. The structure of the RF switch consists of a membrane, coplanar waveguide (CPW lines, and eight springs. The RF switch is manufactured using the complementary metal oxide semiconductor (CMOS process. The switch requires a post-process to release the membrane and springs. The post-process uses a wet etching to remove the sacrificial silicon dioxide layer, and to obtain the suspended structures of the switch. In order to improve the residual stress of the switch, an annealing process is applied to the switch, and the membrane obtains an excellent flatness. The finite element method (FEM software CoventorWare is utilized to simulate the stress and displacement of the RF switch. Experimental results show that the RF switch has an insertion loss of 0.9 dB at 35 GHz and an isolation of 21 dB at 39 GHz. The actuation voltage of the switch is 14 V.

Manufacture of radio frequency micromachined switches with annealing.

Science.gov (United States)

Lin, Cheng-Yang; Dai, Ching-Liang

2014-01-17

The fabrication and characterization of a radio frequency (RF) micromachined switch with annealing were presented. The structure of the RF switch consists of a membrane, coplanar waveguide (CPW) lines, and eight springs. The RF switch is manufactured using the complementary metal oxide semiconductor (CMOS) process. The switch requires a post-process to release the membrane and springs. The post-process uses a wet etching to remove the sacrificial silicon dioxide layer, and to obtain the suspended structures of the switch. In order to improve the residual stress of the switch, an annealing process is applied to the switch, and the membrane obtains an excellent flatness. The finite element method (FEM) software CoventorWare is utilized to simulate the stress and displacement of the RF switch. Experimental results show that the RF switch has an insertion loss of 0.9 dB at 35 GHz and an isolation of 21 dB at 39 GHz. The actuation voltage of the switch is 14 V.

Effects of annealing temperature on the characteristics of ALD-deposited HfO2 in MIM capacitors

International Nuclear Information System (INIS)

Jeong, S.-W.; Lee, H.J.; Kim, K.S.; You, M.T.; Roh, Y.; Noguchi, T.; Xianyu, W.; Jung, J.

2006-01-01

We have investigated the annealing effects of HfO 2 films deposited by an atomic layer deposition (ALD) method on the electrical and physical properties in the Si/SiO 2 /Pt/ALD-HfO 2 /Pd metal-insulator-metal (MIM) capacitors. If the annealing temperature for HfO 2 films was restricted below 500 deg. C, an annealing step using a rapid thermal processor (RTP) improves the electrical properties such as the dissipation factor and the dielectric constant. On the other hand, annealing at 700 deg. C degrades the electrical characteristics in general; the dissipation factor increases over the frequency range of 1∼4 MHz, and the leakage current increases up to 2 orders at the low electric field regions. We found that the degradation of electrical properties is due to the grain growth in the HfO 2 film (i.e., poly-crystallization of the film) by the high temperature annealing processing. We suggested that the annealing temperature must be restricted below 500 deg. C to obtain the high quality high-k film for the MIM capacitors

Observation of visible emission from the molecular helium ion in the afterglow of a dense helium Z-pinch plasma

International Nuclear Information System (INIS)

Tucker, J.E.; Brake, M.L.; Gilgenbach, R.M.

1986-01-01

The authors present the results of axial and radial time resolved visible emission spectroscopy from the afterglow of a dense helium Z-pinch. These results show that the visible emissions in the pinch afterglow are dominated by line emissions from molecular helium and He II. Axial spectroscopy measurements show the occurrence of several absorption bands which cannot be identified as molecular or atomic helium nor impurities from the discharge chamber materials. The authors believe that these absorption bands are attributable to the molecular helium ion which is present in the discharge. The molecular ion has been observed by others in low pressure and temperature helium discharges directly by means of mass spectrometry and indirectly by the presence of helium atoms in the 2/sup 3/S state, (the He 2/sup 3/S state is believed to result from molecular helium ion recombination). However, the molecular helium ion has not previously been observed spectroscopically

Annealing Time Effect on Nanostructured n-ZnO/p-Si Heterojunction Photodetector Performance

Science.gov (United States)

Habubi, Nadir. F.; Ismail, Raid. A.; Hamoudi, Walid K.; Abid, Hassam. R.

2015-02-01

In this work, n-ZnO/p-Si heterojunction photodetectors were prepared by drop casting of ZnO nanoparticles (NPs) on single crystal p-type silicon substrates, followed by (15-60) min; step-annealing at 600∘C. Structural, electrical, and optical properties of the ZnO NPs films deposited on quartz substrates were studied as a function of annealing time. X-ray diffraction studies showed a polycrystalline, hexagonal wurtizte nanostructured ZnO with preferential orientation along the (100) plane. Atomic force microscopy measurements showed an average ZnO grain size within the range of 75.9 nm-99.9 nm with a corresponding root mean square (RMS) surface roughness between 0.51 nm-2.16 nm. Dark and under illumination current-voltage (I-V) characteristics of the n-ZnO/p-Si heterojunction photodetectors showed an improving rectification ratio and a decreasing saturation current at longer annealing time with an ideality factor of 3 obtained at 60 min annealing time. Capacitance-voltage (C-V) characteristics of heterojunctions were investigated in order to estimate the built-in-voltage and junction type. The photodetectors, fabricated at optimum annealing time, exhibited good linearity characteristics. Maximum sensitivity was obtained when ZnO/Si heterojunctions were annealed at 60 min. Two peaks of response, located at 650 nm and 850 nm, were observed with sensitivities of 0.12-0.19 A/W and 0.18-0.39 A/W, respectively. Detectivity of the photodetectors as function of annealing time was estimated.

Helium Extraction from LNG End Flash

OpenAIRE

Kim, Donghoi

2014-01-01

Helium is an invaluable element as it is widely used in industry such as cryo-genics and welding due to its unique properties. However, helium shortage is expected in near future because of increasing demand and the anxiety of sup-ply. Consequently, helium production has attracted the attention of industry. The main source of He is natural gas and extracting it from LNG end-flash is considered as the most promising way of producing crude helium. Thus, many process suppliers have proposed proc...

Reactor pressure vessel thermal annealing

International Nuclear Information System (INIS)

Lee, A.D.

1997-01-01

The steel plates and/or forgings and welds in the beltline region of a reactor pressure vessel (RPV) are subject to embrittlement from neutron irradiation. This embrittlement causes the fracture toughness of the beltline materials to be less than the fracture toughness of the unirradiated material. Material properties of RPVs that have been irradiated and embrittled are recoverable through thermal annealing of the vessel. The amount of recovery primarily depends on the level of the irradiation embrittlement, the chemical composition of the steel, and the annealing temperature and time. Since annealing is an option for extending the service lives of RPVs or establishing less restrictive pressure-temperature (P-T) limits; the industry, the Department of Energy (DOE) and the Nuclear Regulatory Commission (NRC) have assisted in efforts to determine the viability of thermal annealing for embrittlement recovery. General guidance for in-service annealing is provided in American Society for Testing and Materials (ASTM) Standard E 509-86. In addition, the American Society of Mechanical Engineers (ASME) Code Case N-557 addresses annealing conditions (temperature and duration), temperature monitoring, evaluation of loadings, and non-destructive examination techniques. The NRC thermal annealing rule (10 CFR 50.66) was approved by the Commission and published in the Federal Register on December 19, 1995. The Regulatory Guide on thermal annealing (RG 1.162) was processed in parallel with the rule package and was published on February 15, 1996. RG 1.162 contains a listing of issues that need to be addressed for thermal annealing of an RPV. The RG also provides alternatives for predicting re-embrittlement trends after the thermal anneal has been completed. This paper gives an overview of methodology and recent technical references that are associated with thermal annealing. Results from the DOE annealing prototype demonstration project, as well as NRC activities related to the

Development of Bake Hardening Effect by Plastic Deformation and Annealing Conditions

Directory of Open Access Journals (Sweden)

Kvačkaj, T.

2006-01-01

Full Text Available The paper deals with the classification of steel sheets for automotives industry on the basis of strength and structural characteristics. Experimental works were aimed to obtain the best possible strengthening parameters as well as work hardening and solid solution ferrite hardening, which are the result of thermal activation of interstitial carbon atoms during paint-baking of auto body. Hardening process coming from interstitial atoms is realized as two-step process. The first step is BH (bake hardening effect achieved by interaction of interstitial atoms with dislocations. The Cottrels atmosphere is obtained. The second step of BH effect is to produced the hardening from precipitation of the carbon atoms in e-carbides, or formation of Fe32C4 carbides. WH (work hardening effect is obtained as dislocation hardening from plastic deformations during sheet deep drawing. Experimental works were aimed at as to achieve such plastic material properties after cold rolling, annealing and skin-pass rolling, which would be able to classify the material ZStE220BH into the drawing categories at the level of DQ – DDQ. As resulting from the experimental results, the optimal treatment conditions for the maximal sum (WH+BH = 86 MPa are as follows: total cold rolling deformation ecold = 65 %, annealing temperature Tanneal. = 700 °C.

Use of separating nozzles or ultra-centrifuges for obtaining helium from gas mixtures containing helium

International Nuclear Information System (INIS)

Reimann, T.

1987-01-01

To obtain helium from gas mixtures containing helium, particularly from natural gas, it is proposed to match the dimensions of the separation devices for a ratio of the molecular weights to be separated of 4:1 of more, which ensures a higher separation factor and therefore a smaller number of separation stages to be connected in series. The process should make reasonably priced separation of helium possible. (orig./HP) [de

Thermal annealing of high dose radiation induced damage at room temperature in alkali halides. Stored energy, thermoluminiscence and colouration

International Nuclear Information System (INIS)

Delgado, L.

1980-01-01

The possible relation between stored energy, thermoluminiscence and colour centre annealing in gamma and electron irradiated alkali halides is studied. Thermoluminiscence occurs at temperature higher than the temperature at which the main stored energy peak appears. No stored energy release is detected in additively coloured KCl samples. Plastic deformation and doping with Ca and Sr induce a stored energy spectrum different from the spectrum observed in pure and as cleaved samples, but the amount of stored energy does not change for a given irradiation dose. Capacity of alkali halides to sotore energy by irradiation increases as the cation size decreases. It appears that most of the observed release is not related to annealing processes of the radiation induced anion Frenkel pairs. The existence of damage in the cation sublattice with which this energy release might be related is considered. (auth.)

Annealing effect on the performance of sputtering deposited Metglas thin films

KAUST Repository

Cai, Liang

2010-12-01

Magnetostrictive sensors based on ferromagnetic materials have been widely used in detecting chemicals and biological species. The Metglas™ 2826MB is one of the bulk strip materials that is employed as the sensor platform. However, the sensitivity is limited by the large size of the sensors itself. In order to improve the sensitivity, we have developed a process to fabricate microscale sensors of 500 × 100 μm in size using conventional MEMS technology. As-deposited, the sensors suffered from internal stress, which was released by a annealing the sensors at 215 °C for two hours under vacuum condition. The annealing process improved the magnetic properties of the thin films and increased the resonant frequency of the sensor by 214 kHz.

Annealing effect on the performance of sputtering deposited Metglas thin films

KAUST Repository

Cai, Liang; Hu, Jing; Prorok, Barton C.; Gooneratne, Chinthaka Pasan; Kosel, Jü rgen

2010-01-01

Magnetostrictive sensors based on ferromagnetic materials have been widely used in detecting chemicals and biological species. The Metglas™ 2826MB is one of the bulk strip materials that is employed as the sensor platform. However, the sensitivity is limited by the large size of the sensors itself. In order to improve the sensitivity, we have developed a process to fabricate microscale sensors of 500 × 100 μm in size using conventional MEMS technology. As-deposited, the sensors suffered from internal stress, which was released by a annealing the sensors at 215 °C for two hours under vacuum condition. The annealing process improved the magnetic properties of the thin films and increased the resonant frequency of the sensor by 214 kHz.

Helium diffusion in nickel at high temperatures

International Nuclear Information System (INIS)

Philipps, V.

1980-09-01

Helium has been implanted at certain temperatures between 800 and 1250 0 C into single and polycrystalline Ni-samples with implantation depths between 15 and 90 μm. Simultaneously the helium reemission from the sample is measured by a mass-spectrometer. It has been shown that the time dependence of the observed reemission rate is governed by volume diffusion of the helium. Measuring this time dependence as a function of temperature the helium diffusion constant has been determined. The He-diffusion is interpreted as a interstitial diffusion hindered by thermal vacancies. Depending on the implantation depth more or less of the implanted helium remains in the sample and forms large helium bubbles. (orig./GSCH)

Neutron-induced helium implantation in GCFR cladding

International Nuclear Information System (INIS)

Yamada, H.; Poeppel, R.B.; Sevy, R.H.

1980-10-01

The neutron-induced implantation of helium atoms on the exterior surfaces of the cladding of a prototypic gas-cooled fast reactor (GCFR) has been investigated analytically. A flux of recoil helium particles as high as 4.2 x 10 10 He/cm 2 .s at the cladding surface has been calculated at the peak power location in the core of a 300-MWe GCFR. The calculated profile of the helium implantation rates indicates that although some helium is implanted as deep as 20 μm, more than 99% of helium particles are implanted in the first 2-μm-deep layer below the cladding surface. Therefore, the implanted helium particles should mainly affect surface properties of the GCFR cladding

Very fast simulated re-annealing

OpenAIRE

L. Ingber

1989-01-01

Draft An algorithm is developed to statistically find the best global fit of a nonlinear non-convex cost-function over a D-dimensional space. It is argued that this algorithm permits an annealing schedule for ‘‘temperature’’ T decreasing exponentially in annealing-time k, T = T0 exp(−ck1/D). The introduction of re-annealing also permits adaptation to changing sensitivities in the multidimensional parameter-space. This annealing schedule is faster than fast Cauchy annealing, ...

Quantum statistics and liquid helium 3 - helum 4 mixtures

International Nuclear Information System (INIS)

Cohen, E.G.D.

1979-01-01

The behaviour of liquid helium 3-helium 4 mixtures is considered from the point of view of manifestation of quantum statistics effects in macrophysics. The Boze=Einstein statistics is shown to be of great importance for understanding superfluid helium-4 properties whereas the Fermi-Dirac statistics is of importance for understanding helium-3 properties. Without taking into consideration the interaction between the helium atoms it is impossible to understand the basic properties of liquid helium 33 - helium 4 mixtures at constant pressure. Proposed is a simple model of the liquid helium 3-helium 4 mixture, namely the binary mixture consisting of solid spheres of two types subjecting to the Fermi-Dirac and Bose-Einstein statistics relatively. This model predicts correctly the most surprising peculiarities of phase diagrams of concentration dependence on temperature for helium solutions. In particular, the helium 4 Bose-Einstein statistics is responsible for the phase lamination of helium solutions at low temperatures. It starts in the peculiar critical point. The helium 4 Fermi-Dirac statistics results in incomplete phase lamination close to the absolute zero temperatures, that permits operation of a powerful cooling facility, namely refrigerating machine on helium solution

High Efficiency Regenerative Helium Compressor, Phase I

Data.gov (United States)

National Aeronautics and Space Administration — Helium plays several critical rolls in spacecraft propulsion. High pressure helium is commonly used to pressurize propellant fuel tanks. Helium cryocoolers can be...

Hydrogen and helium recycling from stirred liquid lithium under steady state plasma bombardment

Energy Technology Data Exchange (ETDEWEB)

Hirooka, Yoshi, E-mail: hirooka.yoshihiko@nifs.ac.jp [National Institute for Fusion Science, 322-6 Oroshi, Toki, Gifu 509-5292 (Japan); The Graduate School for Advanced Studies, 322-6 Oroshi, Toki, Gifu 509-5292 (Japan); Zhou, Haishan [The Graduate School for Advanced Studies, 322-6 Oroshi, Toki, Gifu 509-5292 (Japan); Ono, Masa [Princeton Plasma Physics Laboratory, PO Box 451, Princeton, NJ 08543 (United States)

2014-12-15

For improved core performance via edge plasma-wall boundary control, solid and liquid lithium has been used as a plasma-facing material in a number of confinement experiments over the past several decades. Unfortunately, it is unavoidable that lithium is saturated in the surface region with implanted hydrogenic species as well as oxygen-containing impurities. For steady state operation, a flowing liquid lithium divertor with forced convection would probably be required. In the present work, the effects of liquid stirring to simulate forced convection have been investigated on the behavior of hydrogen and helium recycling from molten lithium at temperatures up to ∼350 °C. Data indicate that liquid stirring reactivates hydrogen pumping via surface de-saturation and/or uncovering impurity films, but can also induce helium release via surface temperature change.

Effects of post-growth annealing on InGaAs quantum posts embedded in Schottky diodes

International Nuclear Information System (INIS)

Schramm, A; Polojärvi, V; Hakkarainen, T V; Tukiainen, A; Guina, M

2011-01-01

We study effects of rapid thermal annealing on photoluminescence and electron confinement of InGaAs quantum posts by means of photoluminescence experiments and capacitance–voltage spectroscopy. The quantum posts are embedded in n-type Schottky diodes grown by molecular beam epitaxy on GaAs(1 0 0). The observed photoluminescence spectra arise from the quantum posts as well as from a contribution of a wetting-layer superlattice. With increasing annealing temperatures, the quantum-post photoluminescence blueshifts toward the wetting-layer superlattice, and upon the highest annealing step, the wetting-layer superlattice luminescence dominates. In capacitance–voltage experiments, we clearly observe a charge accumulation in the quantum-post layer as well as from the wetting-layer superlattice. Capacitance–voltage spectra and carrier-density profiles only experience slight changes upon annealing treatments. We suggest that the main electron accumulation takes place in the wetting-layer superlattice

Seismological measurement of solar helium abundance

International Nuclear Information System (INIS)

Vorontsov, S.V.; Pamyatnykh, A.A.

1991-01-01

The internal structure and evolution of the Sun depends on its chemical composition, particularly the helium abundance. In addition, the helium abundance in the solar envelope is thought to represent the protosolar value, making it a datum of cosmological significance. Spectroscopic measurements of the helium abundance are uncertain, and the most reliable estimates until now have come from the calibration of solar evolutionary models. The frequencies of solar acoustic oscillations are sensitive, however, to the behaviour of the speed of sound in the Sun's helium ionization zone, which allows a helioseismological determination of the helium abundance. Sound-speed inversion of helioseismological data can be used for this purpose, but precise frequency measurements of high-degree oscillation modes are needed. Here we describe a new approach based on an analysis of the phase shift of acoustic waves of intermediate-degree modes. From the accurate intermediate-mode data now available, we obtain a helium mass fraction Y=0.25±0.01 in the solar convection zone, significantly smaller than the value Y=0.27-0.29 predicted by recent solar evolutionary models. The discrepancy indicates either that initial helium abundance was reduced in the envelope by downward diffusion or that the protosolar value was lower than currently accepted. (author)

Review of Membranes for Helium Separation and Purification

Directory of Open Access Journals (Sweden)

Colin A. Scholes

2017-02-01

Full Text Available Membrane gas separation has potential for the recovery and purification of helium, because the majority of membranes have selectivity for helium. This review reports on the current state of the research and patent literature for membranes undertaking helium separation. This includes direct recovery from natural gas, as an ancillary stage in natural gas processing, as well as niche applications where helium recycling has potential. A review of the available polymeric and inorganic membranes for helium separation is provided. Commercial gas separation membranes in comparable gas industries are discussed in terms of their potential in helium separation. Also presented are the various membrane process designs patented for the recovery and purification of helium from various sources, as these demonstrate that it is viable to separate helium through currently available polymeric membranes. This review places a particular focus on those processes where membranes are combined in series with another separation technology, commonly pressure swing adsorption. These combined processes have the most potential for membranes to produce a high purity helium product. The review demonstrates that membrane gas separation is technically feasible for helium recovery and purification, though membranes are currently only applied in niche applications focused on reusing helium rather than separation from natural sources.

Interactions of solid and liquid lithium with steady state hydrogen and helium plasmas

International Nuclear Information System (INIS)

Hirooka, Y.; Nishikawa, M.; Ohgaki, H.; Ohtsuka, Y.

2005-01-01

A variety of innovative Plasma-Facing Component (PFC) concepts, employing moving solid or liquid surfaces, have recently been proposed in order to resolve technical issues, associated with the applications of currently used PFCs in future steady state fusion devices. As the first step to evaluate the concept using flowing-liquids for PFCs, steady state hydrogen and helium plasma interactions with solid and standing liquid lithium have been investigated in the present work, using the H α and He-I spectroscopy at the ion bombarding energies up to 150eV and at the lithium temperatures between room temperature and 480 deg C. Data indicate that hydrogen recycling over liquid lithium is clearly reduced, relative to that over solid lithium, whereas helium recycling does not show the same trend. From the kinetic analysis of these recycling time constant data, the activation energies for the overall recycling processes have been evaluated to be 0.02±0.01eV, both for hydrogen and helium plasmas. Also, it has been found that the activation energy is nearly independent of ion bombarding energy. (author)

Separation of compressor oil from helium

International Nuclear Information System (INIS)

Strauss, R.; Perrotta, K.A.

1982-01-01

Compression of helium by an oil-sealed rorary screw compressor entrains as much as 4000 parts per million by weight of liquid and vapor oil impurities in the gas. The reduction below about 0.1 ppm for cryogenic applications is discussed. Oil seperation equipment designed for compressed air must be modified significantly to produce the desired results with helium. The main differences between air and helium filtration are described. A description of the coalescers is given with the continuous coalescing of liquid mist from air or other gas illustrated. Oil vapor in helium is discussed in terms of typical compressor oils, experimental procedure for measuring oil vapor concentration, measured volatile hydrocarbons in the lubricants, and calculated concentration of oil vapor in Helium. Liquid oil contamination in helium gas can be reduced well below 0.1 ppm by a properly designed multiple state coalescing filter system containing graded efficiency filter elements. The oil vapor problem is best attached by efficiently treating the oil to remove most of the colatiles before charging the compressor

Effect of rhenium addition on tungsten fuzz formation in helium plasmas

Energy Technology Data Exchange (ETDEWEB)

Khan, Aneeqa, E-mail: aneeqa.khan-3@postgrad.manchester.ac.uk [School of Mechanical, Aerospace and Civil Engineering, The University of Manchester, M13 9PL (United Kingdom); De Temmerman, Gregory [ITER Organization, Route de Vinon-sur-Verdon, CS 90 046 - 13067 St Paul Lez Durance Cedex (France); Morgan, Thomas W. [FOM Institute DIFFER – Dutch Institute for Fundamental Energy Research, Partner in the Trilateral Euregio Cluster, Eindhoven (Netherlands); Ward, Michael B. [Institute for Materials Research, School of Chemical Process Engineering, University of Leeds, Leeds, LS2 9JT (United Kingdom)

2016-06-15

The effect of the addition of rhenium to tungsten on the formation of a nanostructure referred to as ‘fuzz’ when exposed to helium plasmas at fusion relevant ion fluxes was investigated in the Magnum and Pilot PSI devices at the FOM Institute DIFFER. The effect rhenium had on fuzz growth was seen to be dependent on time, temperature and flux. Initial fuzz growth was seen to be highly dependent on grain orientation, with rhenium having little effect. Once the fuzz was fully developed, the effect of grain orientation disappeared and the rhenium had an inhibiting effect on growth. This could be beneficial for inhibiting fuzz growth in a future fusion reactor, where transmutation of tungsten to rhenium is expected. It also appears that erosion or annealing of the fuzz is limiting growth of fuzz at higher temperatures in the range of ∼1340 °C.

Effect of rhenium addition on tungsten fuzz formation in helium plasmas

International Nuclear Information System (INIS)

Khan, Aneeqa; De Temmerman, Gregory; Morgan, Thomas W.; Ward, Michael B.

2016-01-01

The effect of the addition of rhenium to tungsten on the formation of a nanostructure referred to as ‘fuzz’ when exposed to helium plasmas at fusion relevant ion fluxes was investigated in the Magnum and Pilot PSI devices at the FOM Institute DIFFER. The effect rhenium had on fuzz growth was seen to be dependent on time, temperature and flux. Initial fuzz growth was seen to be highly dependent on grain orientation, with rhenium having little effect. Once the fuzz was fully developed, the effect of grain orientation disappeared and the rhenium had an inhibiting effect on growth. This could be beneficial for inhibiting fuzz growth in a future fusion reactor, where transmutation of tungsten to rhenium is expected. It also appears that erosion or annealing of the fuzz is limiting growth of fuzz at higher temperatures in the range of ∼1340 °C.

Precipitate-induced R-phase in martensitic transformation of as-spun and annealed Ti51Ni49 ribbons

International Nuclear Information System (INIS)

Wu, Ling-Mei; Chang, Shih-Hang; Wu, Shyi-Kaan

2010-01-01

Differential scanning calorimetry (DSC) results indicate that a two-step B2 → R → B19' martensitic transformation and a one-step B19' → B2 transformation exhibit in as-spun and in 200-600 o C annealed Ti 51 Ni 49 ribbons. Guinier-Preston (GP) zones and Ti 2 Ni precipitates are formed in ribbons annealed at ≤300 o C and ≥400 o C, respectively, and a conspicuous increase of DSC transformation peak temperature occurs in between 300 o C and 400 o C. The sizes of GP zones and Ti 2 Ni precipitates increase with increased annealing temperature. Transmission electron microscope (TEM) observations show that GP zones can induce the R-phase and both of them are formed along B2 directions. DSC and TEM tests show that Ti 2 Ni precipitates can induce the R-phase more than GP zones and the induced R-phase plates are also found along B2 directions. Experimental results show that the growing direction of R-phase plates is strongly confined by that of GP zones and Ti 2 Ni precipitates. The length of R-phase plates can reach about 2 μm in 300 o C annealed ribbon.

Nuclear fuel rod helium leak inspection apparatus and method

International Nuclear Information System (INIS)

Ahmed, H.J.

1991-01-01

This patent describes an inspection apparatus for testing nuclear fuel rods for helium leaks. It comprises a test chamber being openable and closable for receiving at least one nuclear fuel rod; means separate from the fuel rod for supplying helium and constantly leaking helium at a predetermined known positive value into the test chamber to constantly provide an atmosphere of helium at the predetermined known positive value in the test chamber; and means for sampling the atmosphere within the chamber and measuring the helium in the atmosphere such that a measured helium value below a preset minimum helium value substantially equal to the predetermined known positive value of the atmosphere of helium being constantly provided in the test chamber indicates a malfunction in the inspection apparatus, above a preset maximum helium value greater than the predetermined known positive in the test chamber indicates the existence of a helium leak from the fuel rod, or between the preset minimum and maximum helium values indicates the absence of a helium leak from the fuel rod

Effect of low thermal budget annealing on surface passivation of silicon by ALD based aluminum oxide films.

Science.gov (United States)

Vandana; Batra, Neha; Gope, Jhuma; Singh, Rajbir; Panigrahi, Jagannath; Tyagi, Sanjay; Pathi, P; Srivastava, S K; Rauthan, C M S; Singh, P K

2014-10-21

Thermal ALD deposited Al2O3 films on silicon show a marked difference in surface passivation quality as a function of annealing time (using a rapid thermal process). An effective and quality passivation is realized in short anneal duration (∼100 s) in nitrogen ambient which is reflected in the low surface recombination velocity (SRV passivation. Both as-deposited and low thermal budget annealed films show the presence of positive fixed charges and this is never been reported in the literature before. The role of field and chemical passivation is investigated in terms of fixed charge and interface defect densities. Further, the importance of the annealing step sequence in the MIS structure fabrication protocol is also investigated from the view point of its effect on the nature of fixed charges.

High temperature annealing effect on structural and magnetic properties of Ti/Ni multilayers

International Nuclear Information System (INIS)

Bhatt, Pramod; Ganeshan, V.; Reddy, V.R.; Chaudhari, S.M.

2006-01-01

High temperature annealing effect on structural and magnetic properties of Ti/Ni multilayer (ML) up to 600 deg. C have been studied and reported in this paper. Ti/Ni multilayer samples having constant layer thicknesses of 50 A each are deposited on float glass and Si(1 1 1) substrates using electron-beam evaporation technique under ultra-high vacuum (UHV) conditions at room temperatures. The micro-structural parameters and their evolution with temperature for as-deposited as well as annealed multilayer samples up to 600 deg. C in a step of 100 deg. C for 1 h are determined by using X-ray diffraction (XRD) and grazing incidence X-ray reflectivity techniques. The X-ray diffraction pattern recorded at 300 deg. C annealed multilayer sample shows interesting structural transformation (from crystalline to amorphous) because of the solid-state reaction (SSR) and subsequent re-crystallization at higher temperatures of annealing, particularly at ≥400 deg. C due to the formation of TiNi 3 and Ti 2 Ni alloy phases. Sample quality and surface morphology are examined by using atomic force microscopy (AFM) technique for both as-deposited as well as annealed multilayer samples. In addition to this, a temperature dependent dc resistivity measurement is also used to study the structural transformation and subsequent alloy phase formation due to annealing treatment. The corresponding magnetization behavior of multilayer samples after each stage of annealing has been investigated by using Magneto-Optical Kerr Effect (MOKE) technique and results are interpreted in terms of observed micro-structural changes

Helium storage and control system for the PBMR

International Nuclear Information System (INIS)

Verkerk, E.C.

1997-01-01

The power conversion unit will convert the heat energy in the reactor core to electrical power. The direct-closed cycle recuperated Brayton Cycle employed for this concept consists of a primary helium cycle with helium powered turbo compressors and a power turbine. The helium is actively cooled with water before the compression stages. A recuperator is used to preheat the helium before entering the core. The start of the direct cycle is initiated by a mass flow from the helium inventory and control system via a jet pump. When the PBMR is connected to the grid, changes in power demand can be followed by changing the helium flow and pressure inside the primary loop. Small rapid adjustments can be performed without changing the helium inventory of the primary loop. The stator blade settings on the turbines and compressors are adjustable and it is possible to bypass reactor and turbine. This temporarily reduces the efficiency at which the power conversion unit is operating. Larger or long term adjustments require storage or addition of helium in order to maintain a sufficient level of efficiency in the power conversion unit. The helium will be temporarily stored in high pressure tanks. After a rise in power demand it will be injected back into the system. Some possibilities how to store the helium are presented in this paper. The change of helium inventory will cause transients in the primary helium loop in order to acquire the desired power level. At this stage, it seems that the change of helium inventory does not strongly effect the stability of the power conversion unit. (author)

Thermal annealing of carbon nanotubes reveals a toxicological impact of the structural defects

Energy Technology Data Exchange (ETDEWEB)

Figarol, Agathe, E-mail: figarol@emse.fr [Ecole Nationale Supérieure des Mines, SPIN-EMSE, CNRS: UMR 5307, LGF (France); Pourchez, Jérémie, E-mail: pourchez@emse.fr [Ecole Nationale Supérieure des Mines, CIS-EMSE, EA 4624, SFR IFRESIS, LINA (France); Boudard, Delphine [Université Jean Monnet Saint-Etienne, EA 4624, SFR IFRESIS, LINA (France); Forest, Valérie [Ecole Nationale Supérieure des Mines, CIS-EMSE, EA 4624, SFR IFRESIS, LINA (France); Berhanu, Sarah [Armines - Mines ParisTech, Centre des Matériaux, CNRS UMR 7633 (France); Tulliani, Jean-Marc [Politecnico di Torino, Department of Applied Science and Technology (Italy); Lecompte, Jean-Pierre [Centre Européen de la céramique CNRS: UMR 7315, SPCTS (France); Cottier, Michèle [Université Jean Monnet Saint-Etienne, EA 4624, SFR IFRESIS, LINA (France); Bernache-Assollant, Didier [Ecole Nationale Supérieure des Mines, CIS-EMSE, EA 4624, SFR IFRESIS, LINA (France); Grosseau, Philippe [Ecole Nationale Supérieure des Mines, SPIN-EMSE, CNRS: UMR 5307, LGF (France)

2015-04-15

The biological response to pristine and annealed multi-walled carbon nanotubes (MWCNT) was assessed on murine macrophages (RAW 264.7). First, the physicochemical features of the as-produced MWCNT and annealed at 2125 °C for 1 h were fully characterized. A decrease in structural defects, hydrophobicity and catalytic impurities was detected after annealing. Thereafter, their impact on cytotoxicity, oxidative stress, and pro-inflammatory response was investigated at concentrations ranging from 15 to 120 µg mL{sup −1}. No effect of the 2125 °C treatment was detected on the cytotoxicity. In contrast, the annealed carbon nanotubes showed a significant increase of the pro-inflammatory response. We assumed that this behavior was due to the reduction in structural defects that may modify the layer of adsorbed biomolecules. Surprisingly, the purification of metallic catalysts did not have any significant impact on the oxidative stress. We suggested that the structural improvements from the 2125 °C treatment can decrease the carbon nanotube scavenging capacity and thus allow a higher free radical release which may counterbalance the decrease of oxidative stress due to a lower content of metallic impurities.

Helium behaviour in aluminium under hydrostatic pressure

International Nuclear Information System (INIS)

Sokurskij, Yu.N.; Tebus, V.N.; Zudilin, V.A.; Tumanova, G.M.

1989-01-01

Effect of hydrostatic compression on equilibrium helium bubbles in low aluminium-lithium alloy irradiated in reactor at 570 K is investigated. Measurements of hydrostatic density and electron-microscopic investigations have shown, that application of up to 2 GPa pressure reduces equilibrium size of helium bubbles and reduces helium swelling. Kinetics and thermodynamics of the process are considered with application of 'rigid sphere' equation which describes helium state in bubbles

Preliminary Overview of a Helium Cooling System for the Secondary Helium Loop in VHTR-based SI Hydrogen Production Facilities

Energy Technology Data Exchange (ETDEWEB)

Shin, Youngjoon; Cho, Mintaek; Kim, Dahee; Lee, Taehoon; Lee, Kiyoung; Kim, Yongwan [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

2014-05-15

Nuclear hydrogen production facilities consist of a very high temperature gas-cooled nuclear reactor (VHTR) system, intermediate heat exchanger (IHX) system, and a sulfur-iodine (SI) thermochemical process. This study focuses on the coupling system between the IHX system and SI thermochemical process. To prevent the propagation of the thermal disturbance owing to the abnormal operation of the SI process components from the IHX system to the VHTR system, a helium cooling system for the secondary helium of the IHX is required. In this paper, the helium cooling system has been studied. The temperature fluctuation of the secondary helium owing to the abnormal operation of the SI process was then calculated based on the proposed coupling system model. Finally, the preliminary conceptual design of the helium cooling system with a steam generator and forced-draft air-cooled heat exchanger to mitigate the thermal disturbance has been carried out. A conceptual flow diagram of a helium cooling system between the IHX and SI thermochemical processes in VHTR-based SI hydrogen production facilities has been proposed. A helium cooling system for the secondary helium of the IHX in this flow diagram prevents the propagation of the thermal disturbance from the IHX system to the VHTR system, owing to the abnormal operation of the SI process components. As a result of a dynamic simulation to anticipate the fluctuations of the secondary helium temperature owing to the abnormal operation of the SI process components with a hydrogen production rate of 60 mol·H{sub 2}/s, it is recommended that the maximum helium cooling capacity to recover the normal operation temperature of 450 .deg. C is 31,933.4 kJ/s. To satisfy this helium cooling capacity, a U-type steam generator, which has a heat transfer area of 12 m{sup 2}, and a forced-draft air-cooled condenser, which has a heat transfer area of 12,388.67 m{sup 2}, are required for the secondary helium cooling system.

Strong white photoluminescence from annealed zeolites

International Nuclear Information System (INIS)

Bai, Zhenhua; Fujii, Minoru; Imakita, Kenji; Hayashi, Shinji

2014-01-01

The optical properties of zeolites annealed at various temperatures are investigated for the first time. The annealed zeolites exhibit strong white photoluminescence (PL) under ultraviolet light excitation. With increasing annealing temperature, the emission intensity of annealed zeolites first increases and then decreases. At the same time, the PL peak red-shifts from 495 nm to 530 nm, and then returns to 500 nm. The strongest emission appears when the annealing temperature is 500 °C. The quantum yield of the sample is measured to be ∼10%. The PL lifetime monotonously increases from 223 μs to 251 μs with increasing annealing temperature. The origin of white PL is ascribed to oxygen vacancies formed during the annealing process. -- Highlights: • The optical properties of zeolites annealed at various temperatures are investigated. • The annealed zeolites exhibit strong white photoluminescence. • The maximum PL enhancement reaches as large as 62 times. • The lifetime shows little dependence on annealing temperature. • The origin of white emission is ascribed to the oxygen vacancies

Nucleation path of helium bubbles in metals during irradiation

International Nuclear Information System (INIS)

Morishita, Kazunori

2008-01-01

Thermodynamical formalization is made for description of the nucleation and growth of helium bubbles in metals during irradiation. The proposed formalization is available or evaluating both microstructural changes in fusion first wall materials where helium is produced by (n, α) nuclear transmutation reactions, and those in fusion divertor materials where helium particles with low energy are directly implanted. Calculated nucleation barrier is significantly reduced by the presence of helium, showing that a helium bubble with an appropriate number of helium atoms depending on bubble size can nucleate without any large nucleation barriers, even at a condition where an empty void has very large nucleation barrier without helium. With the proposed thermodynamical formalization, the nucleation and growth process of helium bubbles in iron during irradiation is simulated by the kinetic Monte-Carlo (KMC) technique. It shows the nucleation path of a helium bubble on the (N He , N V ) space as functions of temperatures and the concentration of helium in the matrix, where N He and N V are the number of helium atoms and vacancies in the helium bubble, respectively. Bubble growth rates depend on the nucleation path and suggest that two different mechanisms operate for bubble growth: one is controlled by vacancy diffusion and the other is controlled by interstitial helium diffusion. (author)

DOE's annealing prototype demonstration projects

International Nuclear Information System (INIS)

Warren, J.; Nakos, J.; Rochau, G.

1997-01-01

One of the challenges U.S. utilities face in addressing technical issues associated with the aging of nuclear power plants is the long-term effect of plant operation on reactor pressure vessels (RPVs). As a nuclear plant operates, its RPV is exposed to neutrons. For certain plants, this neutron exposure can cause embrittlement of some of the RPV welds which can shorten the useful life of the RPV. This RPV embrittlement issue has the potential to affect the continued operation of a number of operating U.S. pressurized water reactor (PWR) plants. However, RPV material properties affected by long-term irradiation are recoverable through a thermal annealing treatment of the RPV. Although a dozen Russian-designed RPVs and several U.S. military vessels have been successfully annealed, U.S. utilities have stated that a successful annealing demonstration of a U.S. RPV is a prerequisite for annealing a licensed U.S. nuclear power plant. In May 1995, the Department of Energy's Sandia National Laboratories awarded two cost-shared contracts to evaluate the feasibility of annealing U.S. licensed plants by conducting an anneal of an installed RPV using two different heating technologies. The contracts were awarded to the American Society of Mechanical Engineers (ASME) Center for Research and Technology Development (CRTD) and MPR Associates (MPR). The ASME team completed its annealing prototype demonstration in July 1996, using an indirect gas furnace at the uncompleted Public Service of Indiana's Marble Hill nuclear power plant. The MPR team's annealing prototype demonstration was scheduled to be completed in early 1997, using a direct heat electrical furnace at the uncompleted Consumers Power Company's nuclear power plant at Midland, Michigan. This paper describes the Department's annealing prototype demonstration goals and objectives; the tasks, deliverables, and results to date for each annealing prototype demonstration; and the remaining annealing technology challenges

Measurement of helium production cross sections of iron for d-T neutrons by helium accumulation method

Energy Technology Data Exchange (ETDEWEB)

Takao, Yoshiyuki; Kanda, Yukinori; Nagae, Koji; Fujimoto, Toshihiro [Kyushu Univ., Fukuoka (Japan); Ikeda, Yujiro

1997-03-01

Helium production cross sections of Iron were measured by helium accumulation method for neutron energies from 13.5 to 14.9 MeV. Iron samples were irradiated with FNS, an intense d-T neutron source of JAERI. As the neutron energy varies according to the emission angle at the neutron source, the samples were set around the neutron source and were irradiated by neutrons of different energy depending on each sample position. The amount of helium produced in a sample was measured by Helium Atoms Measurement System at Kyushu University. The results of this work are in good agreement with other experimental data in the literature and also compared with the evaluated values in JENDL-3. (author)

High-temperature helium-loop facility

International Nuclear Information System (INIS)

Tokarz, R.D.

1981-09-01

The high-temperature helium loop is a facility for materials testing in ultrapure helium gas at high temperatures. The closed loop system is capable of recirculating high-purity helium or helium with controlled impurities. The gas loop maximum operating conditions are as follows: 300 psi pressure, 500 lb/h flow rate, and 2100 0 F temperature. The two test sections can accept samples up to 3.5 in. diameter and 5 ft long. The gas loop is fully instrumented to continuously monitor all parameters of loop operation as well as helium impurities. The loop is fully automated to operate continuously and requires only a daily servicing by a qualified operator to replenish recorder charts and helium makeup gas. Because of its versatility and high degree of parameter control, the helium loop is applicable to many types of materials research. This report describes the test apparatus, operating parameters, peripheral systems, and instrumentation system. The experimental capabilities and test conand presents the results that have been obtained. The study has been conducted using a four-phase approach. The first phase develops the solution to the steady-state radon-diffusion equation in one-dimensieered barriers; disposal charge analysis; analysis of spent fuel policy implementation; spent f water. Field measurements and observations are reported for each site. Analytical data and field measurements are presented in tables and maps. Uranium concentrations in the sediments which were above detection limits ranged from 0.10 t 51.2 ppM. The mean of the logarithms of the uranium concentrations was 0.53. A group of high uranium concentrations occurs near the junctions of quadrangles AB, AC, BB, a 200 mK. In case 2), x-ray studies of isotopic phase separation in 3 He-- 4 He bcc solids were carried out by B. A. Fraass

Cesium lead iodide solar cells controlled by annealing temperature.

Science.gov (United States)

Kim, Yu Geun; Kim, Tae-Yoon; Oh, Jeong Hyeon; Choi, Kyoung Soon; Kim, Youn-Jea; Kim, Soo Young

2017-02-22

An inorganic lead halide perovskite film, CsPbI 3 , used as an absorber in perovskite solar cells (PSCs) was optimized by controlling the annealing temperature and the layer thickness. The CsPbI 3 layer was synthesized by one-step coating of CsI mixed with PbI 2 and a HI additive in N,N-dimethylformamide. The annealing temperature of the CsPbI 3 film was varied from 80 to 120 °C for different durations and the thickness was controlled by changing the spin-coating rpm. After annealing the CsPbI 3 layer at 100 °C under dark conditions for 10 min, a black phase of CsPbI 3 was formed and the band gap was 1.69 eV. Most of the yellow spots disappeared, the surface coverage was almost 100%, and the rms roughness was minimized to 3.03 nm after annealing at 100 °C. The power conversion efficiency (PCE) of the CsPbI 3 based PSC annealed at 100 °C was 4.88%. This high PCE value is attributed to the low yellow phase ratio, high surface coverage, low rms roughness, lower charge transport resistance, and lower charge accumulation. The loss ratio of the PCE of the CH 3 NH 3 PbI x Cl 3-x and CsPbI 3 based PSCs after keeping in air was 47 and 26%, respectively, indicating that the stability of the CsPbI 3 based PSC is better than that of the CH 3 NH 3 PbI x Cl 3-x based PSC. From these results, it is evident that CsPbI 3 is a potential candidate for solar cell applications.

Simulations of the dissociation of small helium clusters with ab initio molecular dynamics in electronically excited states

International Nuclear Information System (INIS)

Closser, Kristina D.; Head-Gordon, Martin; Gessner, Oliver

2014-01-01

The dynamics resulting from electronic excitations of helium clusters were explored using ab initio molecular dynamics. The simulations were performed with configuration interaction singles and adiabatic classical dynamics coupled to a state-following algorithm. 100 different configurations of He 7 were excited into the 2s and 2p manifold for a total of 2800 trajectories. While the most common outcome (90%) was complete fragmentation to 6 ground state atoms and 1 excited state atom, 3% of trajectories yielded bound, He 2 * , and <0.5% yielded an excited helium trimer. The nature of the dynamics, kinetic energy release, and connections to experiments are discussed

Effect of helium on void swelling in vanadium

International Nuclear Information System (INIS)

Brimhall, J.L.; Simonen, E.P.

1975-01-01

Little difference in void microstructural swelling of vanadium is observed when helium is injected simultaneously with a 46- or 5-MeV nickel beam as compared to no helium injection, at least at high dose rates. At lower dose rates, a strong helium effect is seen when the helium is injected prior to heavy ion bombardment. The effect of the helium is shown to be a strong function of the overall displacement damage rate

Clustering of Helium Atoms at a ½

NARCIS (Netherlands)

Berg, F. v.d.; Heugten, W. v.; Caspers, L.M.; Veen, A. v.; Hosson, J.Th.M. de

1977-01-01

Atomistic calculations on a ½<111>{110} edge dislocation show a restricted tendency of clustering of helium atom along this dislocation. Clusters with up to 4 helium atoms have been studied. A cluster with 3 helium proved to be most stable.

Effect of helium on void formation in nickel

International Nuclear Information System (INIS)

Brimhall, J.L.; Simonen, E.P.

1977-01-01

This study examines the influence of helium on void formation in self-ion irradiated nickel. Helium was injected either simultaneously with, or prior to, the self-ion bombardment. The void microstructure was characterized as a function of helium deposition rate and the total heavy-ion dose. In particular, at 575 0 C and 5 X 10 -3 displacements per atom per second the void density is found to be proportional to the helium deposition rate. The dose dependence of swelling is initially dominated by helium driven nucleation. The void density rapidly saturates after which swelling continues with increasing dose only from void growth. It is concluded that helium promotes void nucleation in nickel with either helium implantation technique, pre-injection or simultaneous injection. Qualitative differences, however, are recognized. (Auth.)

Thirty years of screw compressors for helium; Dreissig Jahre Schraubenkompressoren fuer Helium

Energy Technology Data Exchange (ETDEWEB)

Wahl, H. [Kaeser Kompressoren GmbH, Coburg (Germany). Technisches Buero/Auftragskonstruktion

2007-07-01

KAESER helium compressors, as well as their other industrial compressors, will be further developed with the intention to improve the availability and reliability of helium liquefaction systems. Further improvement of compressor and control system efficiency will ensure a low and sustainable operating cost. Fast supply of replacement parts with several years of warranty is ensured by a world-wide distribution system and is also worked on continuously. (orig.)

A pyroloysis technique for determining microamounts of hydrogen in lunar soil using the helium ionization detector

Science.gov (United States)

Bustin, R.

1983-01-01

A method has been developed which will determine hydrogen in sub-milligram samples of lunar soil. It consists of heating the sample in a pyroprobe followed by the gas chromatographic determination of hydrogen using the helium ionization detector. Using a 7 foot, 1/8 OD stainless steel column packed with Carbosieve S, 120/140 mesh, hydrogen was well-separated from the other gases released from lunar soil. Standards of hydrogen in helium were used for calibration. The limit to detection under the conditions used was about 2 ng. The method was linear from 2 ng to 270 ng. The method was checked using some actual lunar samples. Results were typical of those obtained for lunar soils using other methods.

Cathode fall parameters of a self-sustained normal glow discharge in atmospheric-pressure helium

International Nuclear Information System (INIS)

Arkhipenko, V.I.; Zgirovskii, S.M.; Kirillov, A.A.; Simonchik, L.V.

2002-01-01

Results from comprehensive studies of a high-current self-sustained glow discharge in atmospheric-pressure helium are presented. The main parameters of the cathode fall, namely, the electric field profile, cathode fall thickness, current density, gas temperature, and heat flux to the cathode are determined. The results obtained are discussed using one-dimensional models of the cathode fall with allowance for volumetric heat release

Analysis of helium purification system capability during water ingress accident in RDE

Science.gov (United States)

Sriyono; Kusmastuti, Rahayu; Bakhri, Syaiful; Sunaryo, Geni Rina

2018-02-01

The water ingress accident caused by steam generator tube rupture (SGTR) in RDE (Experimental Power Reactor) must be anticipated. During the accident, steam from secondary system diffused and mixed with helium gas in the primary coolant. To avoid graphite corrosion in the core, steam will be removed by Helium purification system (HPS). There are two trains in HPS, first train for normal operation and the second for the regeneration and accident. The second train is responsible to clean the coolant during accident condition. The second train is equipped with additional component, i.e. water cooler, post accident blower, and water separator to remove this mixture gas. During water ingress, the water release from rupture tube is mixed with helium gas. The water cooler acts as a steam condenser, where the steam will be separated by water separator from the helium gas. This paper analyses capability of HPS during water ingress accident. The goal of the research is to determine the time consumed by HPS to remove the total amount of water ingress. The method used is modelling and simulation of the HPS by using ChemCAD software. The BDBA and DBA scenarios will be simulated. In BDBA scenario, up to 110 kg of water is assumed to infiltrate to primary coolant while DBA is up to 35 kg. By using ChemCAD simulation, the second train will purify steam ingress maximum in 0.5 hours. The HPS of RDE has a capability to anticipate the water ingress accident.

Mass spectrometric analysis of helium in stainless steel

International Nuclear Information System (INIS)

Isagawa, Hiroto; Wada, Yukio; Asakura, Yoshiro; Tsuji, Nobuo; Sato, Hitoshi; Tsutsumi, Kenichi

1974-01-01

Vacuum fusion mass-spectrometry was adopted for the analysis of helium in stainless steel. Samples were heated in a vacuum crucible, and helium in the samples was extracted and collected into a reservoir tank. The gas was then introduced through an orifice into a mass spectrometer, where the amount of helium was determined. The maspeq 070 quadrupole type mass spectrometer made by Shimazu Seisakusho, Ltd. was used. The resolving power was 150, and the mass range of the apparatus was 0-150. The determination limit of helium was about 2 x 10 -3 μg when standard helium gas was analyzed, and was about 10 -2 μg when the helium in stainless steel was analyzed. The relative standard deviation of helium intensity in repetitive measurement was about 2% in the amount of helium of 0.05 μg. Helium was injected into stainless steel by means of alpha particle irradiation with a cyclotron. The amount of helium in stainless steel was then determined. The energy of alpha particles was 34 MeV, and the beam area was 10 mm x 10 mm. The experimental data were higher than the expected value in one case, and were lower in the other case. This difference was attributable to the fluctuation of alpha particle beam, misplacement of sample plates, and unevenness of the alpha beam. (Fukutomi, T.)

Semiconductor annealing

International Nuclear Information System (INIS)

Young, J.M.; Scovell, P.D.

1982-01-01

A process for annealing crystal damage in ion implanted semiconductor devices in which the device is rapidly heated to a temperature between 450 and 900 0 C and allowed to cool. It has been found that such heating of the device to these relatively low temperatures results in rapid annealing. In one application the device may be heated on a graphite element mounted between electrodes in an inert atmosphere in a chamber. (author)

Maintenance of heartburn relief after step-down from twice-daily proton pump inhibitor to once-daily dexlansoprazole modified release.

Science.gov (United States)

Fass, Ronnie; Inadomi, John; Han, Cong; Mody, Reema; O'Neil, Janet; Perez, M Claudia

2012-03-01

Many patients with gastroesophageal reflux disease (GERD) take a proton pump inhibitor (PPI) twice daily to control symptoms. Once-daily dexlansoprazole modified release (MR) has a dual-delayed release formulation, making it attractive for step-down management of patients whose symptoms are well controlled on twice-daily PPIs. We investigated whether step-down to once-daily dexlansoprazole controls heartburn in patients with GERD who were receiving twice-daily PPI therapy. Patients 18 years and older taking a twice-daily PPI for symptom control were enrolled (n = 178) in a single-blind, multicenter study; 163 patients completed the study and 142 patients met criteria for the efficacy analysis. During the 6-week screening and treatment periods, patients recorded the presence of heartburn symptoms twice daily in electronic diaries. Patients' heartburn was considered well controlled if they had an average of 1 symptom or fewer per week during the last 4 weeks of screening and treatment. After screening, qualified patients were switched to masked dexlansoprazole MR 30 mg and placebo for 6 weeks. The primary efficacy end point was the proportion of patients whose heartburn remained well controlled after step-down. GERD-related symptoms and quality of life (QOL) also were evaluated using the Patient Assessment of Upper Gastrointestinal Disorders Symptom Severity Index (PAGI-SYM) and the PAGI-QOL questionnaires, respectively. After step-down to once-daily dexlansoprazole MR 30 mg, heartburn remained well controlled in 88% of patients (125 of 142). These patients were able to maintain their GERD-related symptom severity and QOL, indicated by marginal changes in the PAGI-SYM and PAGI-QOL total and subscale scores, respectively. Most patients with GERD who take twice-daily PPI to control heartburn are able to successfully step down to once-daily dexlansoprazole 30 mg. Copyright © 2012 AGA Institute. Published by Elsevier Inc. All rights reserved.

Helium cooling of fusion reactors

International Nuclear Information System (INIS)

Wong, C.P.C.; Baxi, C.; Bourque, R.; Dahms, C.; Inamati, S.; Ryder, R.; Sager, G.; Schleicher, R.

1994-01-01

On the basis of worldwide design experience and in coordination with the evolution of the International Thermonuclear Experimental Reactor (ITER) program, the application of helium as a coolant for fusion appears to be at the verge of a transition from conceptual design to engineering development. This paper presents a review of the use of helium as the coolant for fusion reactor blanket and divertor designs. The concept of a high-pressure helium cooling radial plate design was studied for both ITER and PULSAR. These designs can resolve many engineering issues, and can help with reaching the goals of low activation and high performance designs. The combination of helium cooling, advanced low-activation materials, and gas turbine technology may permit high thermal efficiency and reduced costs, resulting in the environmental advantages and competitive economics required to make fusion a 21st century power source. ((orig.))

Helium induced fine structure in the electronic spectra of anthracene derivatives doped into superfluid helium nanodroplets

International Nuclear Information System (INIS)

Pentlehner, D.; Slenczka, A.

2015-01-01

Electronic spectra of organic molecules doped into superfluid helium nanodroplets show characteristic features induced by the helium environment. Besides a solvent induced shift of the electronic transition frequency, in many cases, a spectral fine structure can be resolved for electronic and vibronic transitions which goes beyond the expected feature of a zero phonon line accompanied by a phonon wing as known from matrix isolation spectroscopy. The spectral shape of the zero phonon line and the helium induced phonon wing depends strongly on the dopant species. Phonon wings, for example, are reported ranging from single or multiple sharp transitions to broad (Δν > 100 cm −1 ) diffuse signals. Despite the large number of example spectra in the literature, a quantitative understanding of the helium induced fine structure of the zero phonon line and the phonon wing is missing. Our approach is a systematic investigation of related molecular compounds, which may help to shed light on this key feature of microsolvation in superfluid helium droplets. This paper is part of a comparative study of the helium induced fine structure observed in electronic spectra of anthracene derivatives with particular emphasis on a spectrally sharp multiplet splitting at the electronic origin. In addition to previously discussed species, 9-cyanoanthracene and 9-chloroanthracene will be presented in this study for the first time

The future of helium as a natural resource

CERN Document Server

Glowacki, Bartek A; Nuttall, William J

2012-01-01

The book reveals the changing dynamics of the helium industry on both the supply-side and the demand-side. The helium industry has a long-term future and this important gas will have a role to play for many decades to come. Major new users of helium are expected to enter the market, especially in nuclear energy (both fission and fusion). Prices and volumes supplied and expected to rise and this will prompt greater efforts towards the development of new helium sources and helium conservation and recycling.

Electronic properties of physisorbed helium

International Nuclear Information System (INIS)

Kossler, Sarah

2011-01-01

This thesis deals with electronic excitations of helium physisorbed on metal substrates. It is studied to what extent the electronic properties change compared to the gas phase due to the increased helium density and the proximity of the metal. Furthermore, the influence of different substrate materials is investigated systematically. To this end, up to two helium layers were adsorbed onto Ru (001), Pt (111), Cu (111), and Ag (111) surfaces in a custom-made cryostat. These samples were studied spectroscopically using synchrotron radiation and a time-of-flight detector. The experimental results were then analyzed in comparison with extensive theoretical model calculations.

Electronic properties of physisorbed helium

Energy Technology Data Exchange (ETDEWEB)

Kossler, Sarah

2011-09-22

This thesis deals with electronic excitations of helium physisorbed on metal substrates. It is studied to what extent the electronic properties change compared to the gas phase due to the increased helium density and the proximity of the metal. Furthermore, the influence of different substrate materials is investigated systematically. To this end, up to two helium layers were adsorbed onto Ru (001), Pt (111), Cu (111), and Ag (111) surfaces in a custom-made cryostat. These samples were studied spectroscopically using synchrotron radiation and a time-of-flight detector. The experimental results were then analyzed in comparison with extensive theoretical model calculations.

Diabetes PSA (:30) Step By Step

Centers for Disease Control (CDC) Podcasts

2009-10-24

First steps to preventing diabetes. For Hispanic and Latino American audiences.  Created: 10/24/2009 by National Diabetes Education Program (NDEP), a joint program of the Centers for Disease Control and Prevention and the National Institutes of Health.   Date Released: 10/24/2009.

Diabetes PSA (:60) Step By Step

Centers for Disease Control (CDC) Podcasts

2009-10-24

First steps to preventing diabetes. For Hispanic and Latino American audiences.  Created: 10/24/2009 by National Diabetes Education Program (NDEP), a joint program of the Centers for Disease Control and Prevention and the National Institutes of Health.   Date Released: 10/24/2009.

Phase transformation from cubic ZnS to hexagonal ZnO by thermal annealing

Science.gov (United States)

Mahmood, K.; Asghar, M.; Amin, N.; Ali, Adnan

2015-03-01

We have investigated the mechanism of phase transformation from ZnS to hexagonal ZnO by high-temperature thermal annealing. The ZnS thin films were grown on Si (001) substrate by thermal evaporation system using ZnS powder as source material. The grown films were annealed at different temperatures and characterized by X-ray diffraction (XRD), photoluminescence (PL), four-point probe, scanning electron microscope (SEM) and energy dispersive X-ray diffraction (EDX). The results demonstrated that as-deposited ZnS film has mixed phases but high-temperature annealing leads to transition from ZnS to ZnO. The observed result can be explained as a two-step process: (1) high-energy O atoms replaced S atoms in lattice during annealing process, and (2) S atoms diffused into substrate and/or diffused out of the sample. The dissociation energy of ZnS calculated from the Arrhenius plot of 1000/T versus log (resistivity) was found to be 3.1 eV. PL spectra of as-grown sample exhibits a characteristic green emission at 2.4 eV of ZnS but annealed samples consist of band-to-band and defect emission of ZnO at 3.29 eV and 2.5 eV respectively. SEM and EDX measurements were additionally performed to strengthen the argument.

Laser spectroscopy of antiprotonic helium

CERN Document Server

Hori, M

2005-01-01

When antiprotons (i.e. the antimatter counterpart of protons) are stopped in helium gas, 97% of them annihilate within picoseconds by reacting with the helium nuclei; a 3% fraction, however, survive with an anomalously long lifetime of several microseconds. This longevity is due to the formation of antiprotonic helium, which is a three-body Rydberg atom composed of an antiproton, electron, and helium nucleus. The ASACUSA experimental collaboration has recently synthesized large numbers of these atoms using CERN's Antiproton Decelerator facility, and measured the atom's transition frequencies to 60 parts per billion by laser spectroscopy. By comparing the experimental results with recent three-body QED calculations and the known antiproton cyclotron frequency, we were able to show that the antiproton mass and charge are the same as the corresponding proton values to a precision of 10 parts per billion. Ongoing and future series of experiments will further improve the experimental precision by using chirp-compe...

Femtosecond spectroscopy on alkali-doped helium nanodroplets; Femtosekundenspektroskopie an alkalidotierten Helium-Nanotroepfchen

Energy Technology Data Exchange (ETDEWEB)

Claas, P.

2006-01-15

In the present thesis first studies on the short-time dynamics in alkali dimers and microclusters, which were bound on the surface of superfluid helium droplets, were presented. The experiments comprehended pump-probe measurements on the fs scale on the vibration dynamics on the dimers and on the fragmentation dynamics on the clusters. Generally by the studies it was shown that such extremely short slopes can also be observed on helium droplets by means of the femtosecond spectroscopy.

Analysis of fuel centre temperatures and fission gas release data from the IFPE Database

International Nuclear Information System (INIS)

Schubert, A.; Lassmann, K.; Van Uffelen, P.; Van de Laar, J.; Elenkov, D.; Asenov, S.; Boneva, S.; Djourelov, N.; Georgieva, M.

2003-01-01

The present work has continued the analysis of fuel centre temperatures and fission gas release, calculated with standard options of the TRANSURANUS code. The calculations are compared to experimental data from the International Fuel Performance Experiments (IFPE) database. It is reported an analysis regarding UO 2 fuel for Western-type reactors: Fuel centre temperatures measured in the experiments Contact 1 and Contact 2 (in-pile tests of 2 rods performed at the Siloe reactor in Grenoble, France, closely simulating commercial PWR conditions); Fission gas release data derived from post-irradiation examinations of 9 fuel rods belonging to the High-Burnup Effects Programme, task 3 (HBEP3). The results allow for a comparison of predictions by TRANSURANUS for the mentioned Western-type fuels with those done previously for Russian-type WWER fuel. The comparison has been extended to include fuel centre temperatures as well as fission gas release. The present version of TRANSURANUS includes a model that calculates the production of Helium. The amount of produced Helium is compared to the measured and to the calculated release of the fission gases Xenon and Krypton

Helium implanted Eurofer97 characterized by positron beam Doppler broadening and Thermal Desorption Spectroscopy

Energy Technology Data Exchange (ETDEWEB)

Carvalho, I., E-mail: i.carvalho@m2i.nl [Materials Innovation Institute (M2i), Delft (Netherlands); Schut, H. [Delft University of Technology, Faculty of Applied Sciences, Delft (Netherlands); Fedorov, A.; Luzginova, N. [Nuclear Research and Consultancy Group (NRG), Petten (Netherlands); Desgardin, P. [CEMHTI-CNRS, 3A Rue de la Férolerie, 45071 Orléans Cedex (France); Sietsma, J. [Delft University of Technology, Faculty of Mechanical, Maritime and Materials Engineering, Delft (Netherlands)

2013-11-15

Reduced Activation Ferritic/Martensitic steels are being extensively studied because of their foreseen application in fusion and Generation IV fission reactors. To produce irradiation induced defects, Eurofer97 samples were implanted with helium at energies of 500 keV and 2 MeV and doses of 1 × 10{sup 15}–10{sup 16} He/cm{sup 2}, creating atomic displacements in the range 0.07–0.08 dpa. The implantation induced defects were characterized by positron beam Doppler Broadening (DB) and Thermal Desorption Spectroscopy (TDS). Results show that up to ∼600 K peaks that can be attributed to He desorption from overpressured He{sub n}V{sub m} (n > m) clusters and vacancy assisted mechanism in the case of helium in the substitutional position. The temperature range 600–1200 K is related to the formation of larger clusters He{sub n}V{sub m} (n < m). The dissociation of the HeV and the phase transition attributed to a sharp peak in the TDS spectra at 1200 K. Above this temperature, the release of helium from bubbles is observed.

Helium 3 precipitation in AISI 316L stainless steel induced by radioactive decay of tritium: Microstructural study of helium bubble precipitation

International Nuclear Information System (INIS)

Brass, A.M.; Chene, J.

1994-01-01

The development of the thermonuclear technology has given rise to a renewed interest in the study of the behavior of helium in metals. A great amount of work is still required for the understanding of the role of helium on the mechanical properties of structural materials for fusion technology, especially austenitic stainless steels. This article deals with the study of the influence of thermomechanical heat treatments, aging conditions (temperature and time), and helium concentration of helium bubble precipitation in a 316L austenitic steel. Helium was generated by the radioactive decay of tritium (tritium trick). Helium bubbles impede the grain growth in 316L steel aged at 1,373 K and also the recrystallization reaction at this temperature if cold working is performed prior to aging. Transmission electron microscopy (TEM) observations indicated a weak helium precipitation at 1,073 and 1,223 K, presumably due to the presence of trapping sites for tritium, and no bubble growth after aging up to 100 hours. Precipitation sites are mainly dislocations in the matrix at 1,073 K and grain boundaries and individual dislocations in the matrix at 1,223 K. The large bubble size (50 nm) observed at 1,373 K, even for short aging times (0.083), can partly be attributed to bubble dragging by dislocations toward the grain boundaries. Cold deformation prior to aging leads to a larger bubble size due to growth enhancement during recrystallization. Decreasing the helium content leads to a smaller helium bubble size and density. Tritium trapping at helium bubbles may favor helium 3 accumulation on defects such as grain boundaries, as observed by tritium autoradiography

The adsorption of helium atoms on coronene cations

Energy Technology Data Exchange (ETDEWEB)

Kurzthaler, Thomas; Rasul, Bilal; Kuhn, Martin; Scheier, Paul, E-mail: Paul.Scheier@uibk.ac.at, E-mail: andrew.ellis@le.ac.uk [Institut für Ionenphysik und Angewandte Physik, Universität Innsbruck, Technikerstr. 25, A-6020 Innsbruck (Austria); Lindinger, Albrecht [Institut für Experimentalphysik, Freie Universität Berlin, Arnimallee 14, 14195 Berlin (Germany); Ellis, Andrew M., E-mail: Paul.Scheier@uibk.ac.at, E-mail: andrew.ellis@le.ac.uk [Department of Chemistry, University of Leicester, University Road, Leicester LE1 7RH (United Kingdom)

2016-08-14

We report the first experimental study of the attachment of multiple foreign atoms to a cationic polycyclic aromatic hydrocarbon (PAH). The chosen PAH was coronene, C{sub 24}H{sub 12}, which was added to liquid helium nanodroplets and then subjected to electron bombardment. Using mass spectrometry, coronene cations decorated with helium atoms were clearly seen and the spectrum shows peaks with anomalously high intensities (“magic number” peaks), which represent ion-helium complexes with added stability. The data suggest the formation of a rigid helium layer consisting of 38 helium atoms that completely cover both faces of the coronene ion. Additional magic numbers can be seen for the further addition of 3 and 6 helium atoms, which are thought to attach to the edge of the coronene. The observation of magic numbers for the addition of 38 and 44 helium atoms is in good agreement with a recent path integral Monte Carlo prediction for helium atoms on neutral coronene. An understanding of how atoms and molecules attach to PAH ions is important for a number of reasons including the potential role such complexes might play in the chemistry of the interstellar medium.

Helium-burning flashes on accreting neutron stars: effects of stellar mass, radius, and magnetic field

International Nuclear Information System (INIS)

Joss, P.C.; Li, F.K.

1980-01-01

We have computed the evolution of the helium-burning shell in an accreting neutron star for various values of the stellar mass (M), radius (R), and surface magnetic fields strength (B). As shown in previous work, the helium-burning shell is often unstable and undergoes thermonuclear flashes that result in the emission of X-ray bursts from the neutron-star surface. The dependence of the properties of these bursts upon the values of M and R can be described by simple scaling relations. A strong magnetic field decreases the radiative and conductive opacities and inhibits convection in the neutron-star surface layers. For B 12 gauss, these effects are unimportant; for B> or approx. =10 13 gauss, the enhancement of the electron thermal conductivity is sufficiently large to stabilize the helium-burning shell against thermonuclear flashes. For intermediate values of B, the reduced opacities increase the recurrence intervals between bursts and the energy released per burst, while the inhibition of convection increases the burst rise times to about a few seconds. If the magnetic field funnels the accreting matter onto the magnetic polar caps, the instability of the helium-burning shell will be very strongly suppressed. These results suggest that it may eventually be possible to extract information on the macroscopic properties of neutron stars from the observed features of X-ray burst sources

Annealing dependence of residual stress and optical properties of TiO2 thin film deposited by different deposition methods.

Science.gov (United States)

Chen, Hsi-Chao; Lee, Kuan-Shiang; Lee, Cheng-Chung

2008-05-01

Titanium oxide (TiO(2)) thin films were prepared by different deposition methods. The methods were E-gun evaporation with ion-assisted deposition (IAD), radio-frequency (RF) ion-beam sputtering, and direct current (DC) magnetron sputtering. Residual stress was released after annealing the films deposited by RF ion-beam or DC magnetron sputtering but not evaporation, and the extinction coefficient varied significantly. The surface roughness of the evaporated films exceeded that of both sputtered films. At the annealing temperature of 300 degrees C, anatase crystallization occurred in evaporated film but not in the RF ion-beam or DC magnetron-sputtered films. TiO(2) films deposited by sputtering were generally more stable during annealing than those deposited by evaporation.

Recent developments in liquid helium 3

International Nuclear Information System (INIS)

Ramarao, I.

1977-01-01

The current status of the theories for the ground state of liquid helium 3, are reviewed. To begin with, a brief summary of the experimental results on the thermodynamic properties of liquid helium 3 including its recently discovered superfulid phases is given. The basic ideas of the Landau theory of a normal Fermi liquid are then introduced. A qualitative discussion of the current understanding of the anisotropic phases of superfluid helium 3 is given, the microscopic calculaations for the binding energy of liquid helium 3 are reviewed and the results obtained for the two-body contributions to the binding energy using the Brueckner-Goldstone formulation and that of Mohling and his collaborators are summarized and discussed. The importance of a proper estimate of the three-body contributions to the binding energy is stressed. The results obtained in the literature using variational methods and constrained variational methods are discussed. A critical analysis of the results by various methods is given. Despite much effort the basic problem of the ground state of liquid helium 3, remains unresolved. (author)

Cosmological helium production simplified

International Nuclear Information System (INIS)

Bernstein, J.; Brown, L.S.; Feinberg, G.

1988-01-01

We present a simplified model of helium synthesis in the early universe. The purpose of the model is to explain clearly the physical ideas relevant to the cosmological helium synthesis, in a manner that does not overlay these ideas with complex computer calculations. The model closely follows the standard calculation, except that it neglects the small effect of Fermi-Dirac statistics for the leptons. We also neglect the temperature difference between photons and neutrinos during the period in which neutrons and protons interconvert. These approximations allow us to express the neutron-proton conversion rates in a closed form, which agrees to 10% accuracy or better with the exact rates. Using these analytic expressions for the rates, we reduce the calculation of the neutron-proton ratio as a function of temperature to a simple numerical integral. We also estimate the effect of neutron decay on the helium abundance. Our result for this quantity agrees well with precise computer calculations. We use our semi-analytic formulas to determine how the predicted helium abundance varies with such parameters as the neutron life-time, the baryon to photon ratio, the number of neutrino species, and a possible electron-neutrino chemical potential. 19 refs., 1 fig., 1 tab

Low-temperature centrifugal helium compressor

International Nuclear Information System (INIS)

Kawada, M.; Togo, S.; Akiyama, Y.; Wada, R.

1974-01-01

A centrifugal helium compressor with gas bearings, which can be operated at the temperature of liquid nitrogen, has been investigated. This compressor has the advantages that the compression ratio should be higher than the room temperature operation and that the contamination of helium could be eliminated. The outer diameter of the rotor is 112 mm. The experimental result for helium gas at low temperature shows a flow rate of 47 g/s and a compression ratio of 1.2 when the inlet pressure was 1 ata and the rotational speed 550 rev/s. The investigation is now focused on obtaining a compression ratio of 1.5. (author)

GPU accelerated population annealing algorithm

Science.gov (United States)

Barash, Lev Yu.; Weigel, Martin; Borovský, Michal; Janke, Wolfhard; Shchur, Lev N.

2017-11-01

Population annealing is a promising recent approach for Monte Carlo simulations in statistical physics, in particular for the simulation of systems with complex free-energy landscapes. It is a hybrid method, combining importance sampling through Markov chains with elements of sequential Monte Carlo in the form of population control. While it appears to provide algorithmic capabilities for the simulation of such systems that are roughly comparable to those of more established approaches such as parallel tempering, it is intrinsically much more suitable for massively parallel computing. Here, we tap into this structural advantage and present a highly optimized implementation of the population annealing algorithm on GPUs that promises speed-ups of several orders of magnitude as compared to a serial implementation on CPUs. While the sample code is for simulations of the 2D ferromagnetic Ising model, it should be easily adapted for simulations of other spin models, including disordered systems. Our code includes implementations of some advanced algorithmic features that have only recently been suggested, namely the automatic adaptation of temperature steps and a multi-histogram analysis of the data at different temperatures. Program Files doi:http://dx.doi.org/10.17632/sgzt4b7b3m.1 Licensing provisions: Creative Commons Attribution license (CC BY 4.0) Programming language: C, CUDA External routines/libraries: NVIDIA CUDA Toolkit 6.5 or newer Nature of problem: The program calculates the internal energy, specific heat, several magnetization moments, entropy and free energy of the 2D Ising model on square lattices of edge length L with periodic boundary conditions as a function of inverse temperature β. Solution method: The code uses population annealing, a hybrid method combining Markov chain updates with population control. The code is implemented for NVIDIA GPUs using the CUDA language and employs advanced techniques such as multi-spin coding, adaptive temperature

Influence of displacement damage on deuterium and helium retention in austenitic and ferritic-martensitic alloys considered for ADS service

Energy Technology Data Exchange (ETDEWEB)

Voyevodin, V.N.; Karpov, S.A.; Kopanets, I.E.; Ruzhytskyi, V.V. [National Science Center “Kharkov Institute of Physics and Technology” Kharkov, 1, Akademicheskaya St., Kharkov, 61108 (Ukraine); Tolstolutskaya, G.D., E-mail: g.d.t@kipt.kharkov.ua [National Science Center “Kharkov Institute of Physics and Technology” Kharkov, 1, Akademicheskaya St., Kharkov, 61108 (Ukraine); Garner, F.A. [Radiation Effects Consulting, Richland, WA (United States)

2016-01-15

The behavior of ion-implanted hydrogen (deuterium) and helium in austenitic 18Cr10NiTi stainless steel, EI-852 ferritic steel and ferritic/martensitic steel EP-450 and their interaction with displacement damage were investigated. Energetic argon irradiation was used to produce displacement damage and bubble formation to simulate nuclear power environments. The influence of damage morphology and the features of radiation-induced defects on deuterium and helium trapping in structural alloys was studied using ion implantation, the nuclear reaction D({sup 3}He,p){sup 4}He, thermal desorption spectrometry and transmission electron microscopy. It was found in the case of helium irradiation that various kinds of helium-radiation defect complexes are formed in the implanted layer that lead to a more complicated spectra of thermal desorption. Additional small changes in the helium spectra after irradiation with argon ions to a dose of ≤25 dpa show that the binding energy of helium with these traps is weakly dependent on the displacement damage. It was established that retention of deuterium in ferritic and ferritic-martensitic alloys is three times less than in austenitic steel at damage of ∼1 dpa. The retention of deuterium in steels is strongly enhanced by presence of radiation damages created by argon ion irradiation, with a shift in the hydrogen release temperature interval of 200 K to higher temperature. At elevated temperatures of irradiation the efficiency of deuterium trapping is reduced by two orders of magnitude.

Helium sources to groundwater in active volcanic terrain, and implications for tritium-helium dating at Mount St. Helens

Energy Technology Data Exchange (ETDEWEB)

Gates, John B. [Department of Earth and Atmospheric Sciences, University of Nebraska-Lincoln, 217 Bessey Hall, Lincoln NE 68588 (United States)

2013-07-01

Groundwater helium sources and residence times were investigated using groundwater discharging from springs surrounding Mount St. Helens in the Cascades region of the United States. Significant contributions of mantle helium were found in all samples and are attributable to interaction between groundwater and magmatic gases. Bounding calculations for residence times were made on the basis of helium isotope mixing plots and historical tritium data. (authors)

Explosive helium burning in white dwarf stars

Energy Technology Data Exchange (ETDEWEB)

Khokhlov, A.M. (AN SSSR, Moscow. Astronomicheskij Sovet)

1984-04-01

Helium burning kinetics in white dwarfs has been considered at constant temperatures T >= 10/sup 9/ K and densities rho >10/sup 5/ g/cm/sup 3/. It is found, that helium detonation in white dwarfs does not lead to formation of light (A < 56) elements. Thus, helium white dwarf model for supernova 1 is inconsistent with observations.

The effect of thermal annealing on pentacene thin film transistor with micro contact printing.

Science.gov (United States)

Shin, Hong-Sik; Yun, Ho-Jin; Baek, Kyu-Ha; Ham, Yong-Hyun; Park, Kun-Sik; Kim, Dong-Pyo; Lee, Ga-Won; Lee, Hi-Deok; Lee, Kijun; Do, Lee-Mi

2012-07-01

We used micro contact printing (micro-CP) to fabricate inverted coplanar pentacene thin film transistors (TFTs) with 1-microm channels. The patterning of micro-scale source/drain electrodes without etch process was successfully achieved using Polydimethylsiloxane (PDMS) elastomer stamp. We used the Ag nano particle ink as an electrode material, and the sheet resistance and surface roughness of the Ag electrodes were effectively reduced with the 2-step thermal annealing on a hotplate, which improved the mobility, the on-off ratio, and the subthreshold slope (SS) of the pentacene TFTs. In addition, the device annealing on a hotplate in a N2 atmosphere for 30 sec can enhance the off-current and the mobility properties of OTFTs without damaging the pentacene thin films and increase the adhesion between pentacene and dielectric layer (SiO2), which was investigated with the pentacene films phase change of the XRD spectrum after device annealing.

A new helium gas recovery and purification system

International Nuclear Information System (INIS)

Yamamotot, T.; Suzuki, H.; Ishii, J.; Hamana, I.; Hayashi, S.; Mizutani, S.; Sanjo, S.

1974-01-01

A helium gas recovery and purification system, based on the principle of gas permeation through a membrane, is described. The system can be used for the purification of helium gas containing air as a contaminant. The apparatus, operating at ambient temperature does not need constant attention, the recovery ratio of helium gas is satisfactory and running costs are low. Gases other than helium can be processed with the apparatus. (U.K.)

The growth of intra-granular bubbles in post-irradiation annealed UO2 fuel

International Nuclear Information System (INIS)

White, R.J.

2001-01-01

Post-irradiation examinations of low temperature irradiated UO 2 reveal large numbers of very small intra-granular bubbles, typically of around 1 nm diameter. During high temperature reactor transients these bubbles act as sinks for fission gas atoms and vacancies and can give rise to large volumetric swellings, sometimes of the order of 10%. Under irradiation conditions, the nucleation and growth of these bubbles is determined by a balance between irradiation-induced nucleation, diffusional growth and an irradiation induced re-solution mechanism. This conceptual picture is, however, incomplete because in the absence of irradiation the model predicts that the bubble population present from the pre-irradiation would act as the dominant sink for fission gas atoms resulting in large intra-granular swellings and little or no fission gas release. In practice, large fission gas releases are observed from post-irradiation annealed fuel. A recent series of experiments addressed the issue of fission gas release and swelling in post-irradiation annealed UO 2 originating from Advanced Gas Cooled Reactor (AGR) fuel which had been ramp tested in the Halden Test reactor. Specimens of fuel were subjected to transient heating at ramp rates of 0.5 deg. C/s and 20 deg. C/s to target temperatures between 1600 deg. C and 1900 deg. C. The release of fission gas was monitored during the tests. Subsequently, the fuel was subjected to post-irradiation examination involving detailed Scanning Electron Microscopy (SEM) analysis. Bubble-size distributions were obtained from seventeen specimens, which entailed the measurement of nearly 26,000 intra-granular bubbles. The analysis reveals that the bubble densities remain approximately invariant during the anneals and the bubble-size distributions exhibit long exponential tails in which the largest bubbles are present in concentrations of 10 4 or 10 5 lower than the concentrations of the average sized bubbles. Detailed modelling of the bubble

Release enhancement of tritium from graphite by addition of hydrogen

International Nuclear Information System (INIS)

Saeki, Masakatsu; Masaki, N.M.

1989-01-01

The release behavior of tritium from graphite was studied in pure He and He + H 2 atmosphere. The release from powdered graphite was significantly enhanced in hydrogen environment. Apparent diffusion coefficients of tritium in graphite also became much higher in an atmosphere containing hydrogen than values obtained in pure helium atmosphere. A careful investigation of the release processes resulted in the conclusion that the most important process of tritium behaviour in graphite was diffusion, but the desorption process of tritium from the surface played a significant role. The enhancement of the desorption process was controlled by atomic hydrogen. (orig.)

Tritium release kinetics in lithium orthosilicate ceramic pebbles irradiated with low thermal-neutron fluence

International Nuclear Information System (INIS)

Xiao, Chengjian; Gao, Xiaoling; Kobayashi, Makoto; Kawasaki, Kiyotaka; Uchimura, Hiromichi; Toda, Kensuke; Kang, Chunmei; Chen, Xiaojun; Wang, Heyi; Peng, Shuming; Wang, Xiaolin; Oya, Yasuhisa; Okuno, Kenji

2013-01-01

Tritium release kinetics in lithium orthosilicate (Li 4 SiO 4 ) ceramic pebbles irradiated with low thermal-neutron fluence was studied by out-of-pile annealing experiments. It was found that the tritium produced in Li 4 SiO 4 pebbles was mainly released as tritiated water vapor (HTO). The apparent desorption activation energy of tritium on the pebble surface was consistent with the diffusion activation energy of tritium in the crystal grains, indicating that tritium release was mainly controlled by diffusion process. The diffusion coefficients of tritium in the crystal grains at temperatures ranging from 450 K to 600 K were obtained by isothermal annealing tests, and the Arrhenius relation was determined to be D = 1 × 10 −7.0 exp (−40.3 × 10 3 /RT) cm 2 s −1

Data on trapping and re-emission of energetic hydrogen isotopes and helium in materials, supplement 1

International Nuclear Information System (INIS)

Yamaguchi, Sadae; Sugizaki, Yasuaki; Ozawa, Kunio; Nakai, Yohta.

1984-05-01

This is the supplement to the data on trapping and re-emission of energetic hydrogen isotopes and helium in materials (JAERI-M 82-118). It contains 32 data up to end of 1982, dividing it into following 6 sections: 1) Dose Dependence, 2) Target Material Dependence, 3) Target Temperature Dependence, 4) Incident Energy Dependence, 5) Damage Effects and 6) Ion-Induced Release. (author)

Helium heater design for the helium direct cycle component test facility. [for gas-cooled nuclear reactor power plant

Science.gov (United States)

Larson, V. R.; Gunn, S. V.; Lee, J. C.

1975-01-01

The paper describes a helium heater to be used to conduct non-nuclear demonstration tests of the complete power conversion loop for a direct-cycle gas-cooled nuclear reactor power plant. Requirements for the heater include: heating the helium to a 1500 F temperature, operating at a 1000 psia helium pressure, providing a thermal response capability and helium volume similar to that of the nuclear reactor, and a total heater system helium pressure drop of not more than 15 psi. The unique compact heater system design proposed consists of 18 heater modules; air preheaters, compressors, and compressor drive systems; an integral control system; piping; and auxiliary equipment. The heater modules incorporate the dual-concentric-tube 'Variflux' heat exchanger design which provides a controlled heat flux along the entire length of the tube element. The heater design as proposed will meet all system requirements. The heater uses pressurized combustion (50 psia) to provide intensive heat transfer, and to minimize furnace volume and heat storage mass.

Revision of the design model for a cryogenic falling liquid film helium separator

International Nuclear Information System (INIS)

Kinoshita, Masahiro; Bartlit, J.R.; Sherman, R.H.

1983-05-01

The present paper reports revision of the design model previously developed by the authors for the cryogenic falling liquid film helium separator. The revised design procedure is composed of three steps : 1) calculation of distributions of phase flow rates, temperature and phase compositions within the refrigerated section and the packed section ; 2) calculation of more detailed distributions of these variables within the refrigerated section ; and 3) estimation of column dimensions and determination of operating conditions. It is assumed that the vacant refrigerated section has two theoretical stages for hydrogen isotope separation. The mixture within the refrigerated section is considered in step 2) as two component system of He-HD. (author)

A reciprocating liquid helium pump used for forced flow of supercritical helium

International Nuclear Information System (INIS)

Krafft, G.; Zahn, G.

1978-01-01

The performance of a small double acting piston pump for circulating helium in a closed heat transfer loop is described. The pump was manufactured by LINDE AG, Munich, West Germany. The measured flow rate of supercritical helium was about 17 gs -1 (500 lhr -1 ) with a differential pressure of Δp = 0.5 x 10 5 Nm -2 at a working pressure of p = 6 x 10 5 Nm -2 . At differential pressures beyond 0.5 x 10 5 Nm -2 the volumetric efficiency decreases. (author)

Effect of helium irradiation on deuterium permeation behavior in tungsten

Energy Technology Data Exchange (ETDEWEB)

Uemura, Yuki; Sakurada, Shodai; Fujita, Hiroe; Azuma, Keisuke; Zhou, Quilai [Graduate School of Science & Technology, Shizuoka University, 836 Ohya, Suruga, Shizuoka, 422-8529 Japan (Japan); Hatano, Yuji [Hydrogen Isotope Research Center, University of Toyama, 3190 Gofuku, Toyama, 930-8555 Japan (Japan); Yoshida, Naoaki; Watanabe, Hideo [Institute for Applied Mechanics, Kyushu University, 6-1 Kasuga-koen, Kasuga, Fukuoka, 816-8580 Japan (Japan); Oyaizu, Makoto; Isobe, Kanetsugu [National Institutes for Quantum and Radiological Science and Technology, 2166 Obuchi, Rokkasho, Aomori, 039-3212 Japan (Japan); Shimada, Masashi [Idaho National Laboratory, 1955 N. Fremont Avenue, Idaho Falls, ID 83415 (United States); Buchenauer, Dean; Kolasinski, Robert [Sandia National Laboratories, Chemistry, Combustion and Materials Center, Livermore, CA 94550 (United States); Chikada, Takumi [Graduate School of Science & Technology, Shizuoka University, 836 Ohya, Suruga, Shizuoka, 422-8529 Japan (Japan); Oya, Yasuhisa, E-mail: oya.yasuhisa@shizuoka.ac.jp [Graduate School of Science & Technology, Shizuoka University, 836 Ohya, Suruga, Shizuoka, 422-8529 Japan (Japan)

2017-07-15

In this study, we measured deuterium (D) gas-driven permeation through tungsten (W) foils that had been pre-damaged by helium ions (He{sup +}). The goal of this work was to determine how ion-induced damage affects hydrogen isotope permeation. At 873 K, the D permeability for W irradiated by 3.0 keV He{sup +} was approximately one order of magnitude lower than that for un-damaged W. This difference diminished with increasing temperature. Even after heating to 1173 K, the permeability returned to less than half of the value measured for un-damaged W. We propose that this is due to nucleation of He bubbles near the surface which potentially serve as a barrier to diffusion deeper into the bulk. Exposure at higher temperatures shows that the D permeability and diffusion coefficients return to levels observed for undamaged material. It is possible that these effects are linked to annealing of defects introduced by ion damage, and whether the defects are stabilized by the presence of trapped He.

Semiconductor annealing

International Nuclear Information System (INIS)

Young, J.M.; Scovell, P.D.

1981-01-01

A process for annealing crystal damage in ion implanted semiconductor devices is described in which the device is rapidly heated to a temperature between 450 and 600 0 C and allowed to cool. It has been found that such heating of the device to these relatively low temperatures results in rapid annealing. In one application the device may be heated on a graphite element mounted between electrodes in an inert atmosphere in a chamber. The process may be enhanced by the application of optical radiation from a Xenon lamp. (author)

Influence of cold deformation and annealing on hydrogen embrittlement of cold hardening bainitic steel for high strength bolts

Energy Technology Data Exchange (ETDEWEB)

Hui, Weijun, E-mail: wjhui@bjtu.edu.cn [School of Mechanical, Electronic and Control Engineering, Beijing Jiaotong University, Beijing 100044 (China); Zhang, Yongjian; Zhao, Xiaoli; Shao, Chengwei [School of Mechanical, Electronic and Control Engineering, Beijing Jiaotong University, Beijing 100044 (China); Wang, Kaizhong; Sun, Wei; Yu, Tongren [Technical Center, Maanshan Iron & Steel Co., Ltd., Maanshan 243002, Anhui (China)

2016-04-26

The influence of cold drawing and annealing on hydrogen embrittlement (HE) of newly developed cold hardening bainitic steel was investigated by using slow strain rate testing (SSRT) and thermal desorption spectrometry (TDS), for ensuring safety performance of 10.9 class high strength bolts made of this kind of steel against HE under service environments. Hydrogen was introduced into the specimen by electrochemical charging. TDS analysis shows that the hydrogen-charged cold drawn specimen exhibits an additional low-temperature hydrogen desorption peak besides the original high-temperature desorption peak of the as-rolled specimen, causing remarkable increase of absorbed hydrogen content. It is found that cold drawing significantly enhances the susceptibility to HE, which is mainly attributed to remarkable increase of diffusible hydrogen absorption, the occurrence of strain-induced martensite as well as the increase of strength level. Annealing after cold deformation is an effective way to improve HE resistance and this improvement strongly depends on annealing temperature, i.e. HE susceptibility decreases slightly with increasing annealing temperature up to 200 °C and then decreases significantly with further increasing annealing temperature. This phenomenon is explained by the release of hydrogen, the recovery of cold worked microstructure and the decrease of strength with increasing annealing temperature.

The TEXTOR helium self-pumping experiment: Design, plans, and supporting ion-beam data on helium retention in nickel

International Nuclear Information System (INIS)

Brooks, J.N.; Krauss, A.; Mattas, R.F.; Smith, D.L.; Nygren, R.E.; Doyle, B.L.; McGrath, R.T.; Walsh, D.; Dippel, K.H.; Finken, K.H.

1990-01-01

A proof-of-principle experiment to demonstrate helium self-pumping in a tokamak is being undertaken in TEXTOR. The experiment will use a helium self-pumping module installed in a modified ALT-I limiter head. The module consists of two, ≅ 25x25 cm 2 heated nickel alloy trapping plates, a nickel deposition filament array, and associated diagnostics. Between plasma shots a coating of ≅ 50A nickel will be deposited on the two trapping plates. During a shot helium and hydrogen ions will impinge on the plates through a ≅ 3 cm wide entrance slot. The helium removal capability, due to trapping in the nickel, will be assessed for a variety of plasma conditions. In support of the tokamak experiment, the trapping of helium over a range of ion fluences and surface temperatures, and detrapping during subsequent exposure to hydrogen, were measured in ion beam experiments using evaporated nickel surfaces similar to that expected in TEXTOR. Also, the retention of H and He after exposure of a nickel surface to mixed He/H plasmas has been measured. The results appear favorable, showing high helium trapping (≅ 10-50% He/Ni) and little or no detrapping by hydrogen. The TEXTOR experiment is planned to begin in 1991. (orig.)

The TEXTOR helium self-pumping experiment: Design, plans, and supporting ion-beam data on helium retention in nickel

International Nuclear Information System (INIS)

Brooks, J.N.; Krauss, A.; Mattas, R.F.; Smith, D.L.; Nygren, R.E.; Doyle, B.L.; McGrath, R.T.; Walsh, D.; Dippel, K.H.; Finken, K.H.

1990-01-01

A proof-of-principle experiment to demonstrate helium self-pumping in a tokamak is being undertaken in TEXTOR. The experiment will use a helium self-pumping module installed in a modified ALT-I limiter head. The module consists of two, ∼25 x 25 cm 2 heated nickel alloy trapping plates, a nickel deposition filament array, and associated diagnostics. Between plasma shots a coating of ∼50 angstrom nickel will be deposited on the two trapping plates. During a shot helium and hydrogen ions will impinge on the plates through a ∼3 cm wide entrance slot. The helium removal capability, due to trapping in the nickel, will be assessed for a variety of plasma conditions. In support of the tokamak experiment, the trapping of helium over a range of ion fluences and surface temperatures, and detrapping during subsequent exposure to hydrogen, were measured in ion beam experiments using evaporated nickel surfaces similar to that expected in TEXTOR. Also, the retention of H and He after exposure of a nickel surface to mixed He/H plasmas has bee measured. The results appear favorable, showing high helium trapping (∼10--50% He/Ni) and little or no detrapping by hydrogen. The TEXTOR experiment is planned to begin in 1991. 12 refs., 2 figs., 2 tabs

Absolute calibration of TFTR helium proportional counters

International Nuclear Information System (INIS)

Strachan, J.D.; Diesso, M.; Jassby, D.; Johnson, L.; McCauley, S.; Munsat, T.; Roquemore, A.L.; Loughlin, M.

1995-06-01

The TFTR helium proportional counters are located in the central five (5) channels of the TFTR multichannel neutron collimator. These detectors were absolutely calibrated using a 14 MeV neutron generator positioned at the horizontal midplane of the TFTR vacuum vessel. The neutron generator position was scanned in centimeter steps to determine the collimator aperture width to 14 MeV neutrons and the absolute sensitivity of each channel. Neutron profiles were measured for TFTR plasmas with time resolution between 5 msec and 50 msec depending upon count rates. The He detectors were used to measure the burnup of 1 MeV tritons in deuterium plasmas, the transport of tritium in trace tritium experiments, and the residual tritium levels in plasmas following 50:50 DT experiments

Sonic Helium Detectors in the Fermilab Tevatron

Science.gov (United States)

Bossert, R. J.

2006-04-01

In the Fermilab Tevatron cryogenic system there are many remotely located low-pressure plate relief valves that must vent large volumes of cold helium gas when magnet quenches occur. These valves can occasionally stick open or not reseat completely, resulting in a large helium loss. As such, the need exists for a detector to monitor the relief valve's discharge area for the presence of helium. Due to the quantity needed, cost is an important factor. A unit has been developed and built for this purpose that is quite inexpensive. Its operating principle is based on the speed of sound, where two closely matched tubes operate at their acoustic resonant frequency. When helium is introduced into one of these tubes, the resulting difference in acoustic time of flight is used to trigger an alarm. At present, there are 39 of these units installed and operating in the Tevatron. They have detected many minor and major helium leaks, and have also been found useful in detecting a rise in the helium background in the enclosed refrigerator buildings. This paper covers the construction, usage and operational experience gained with these units over the last several years.

Sonic helium detectors in the Fermilab Tevatron

International Nuclear Information System (INIS)

Bossert, R.J.; Fermilab

2006-01-01

In the Fermilab Tevatron cryogenic system there are many remotely located low-pressure plate relief valves that must vent large volumes of cold helium gas when magnet quenches occur. These valves can occasionally stick open or not reseat completely, resulting in a large helium loss. As such, the need exists for a detector to monitor the relief valve's discharge area for the presence of helium. Due to the quantity needed, cost is an important factor. A unit has been developed and built for this purpose that is quite inexpensive. Its operating principle is based on the speed of sound, where two closely matched tubes operate at their acoustic resonant frequency. When helium is introduced into one of these tubes, the resulting difference in acoustic time of flight is used to trigger an alarm. At present, there are 39 of these units installed and operating in the Tevatron. They have detected many minor and major helium leaks, and have also been found useful in detecting a rise in the helium background in the enclosed refrigerator buildings. This paper covers the construction, usage and operational experience gained with these units over the last several years

Helium production in reactor materials

International Nuclear Information System (INIS)

Lippincott, E.P.; McElroy, W.N.; Farrar, H. IV.

1975-02-01

Comparisons of integral helium production measurements with predictions based on ENDF/B Version IV cross sections have been made. It is concluded that an ENDF/B helium production cross section file should be established in order to ensure a complete and consistent cross section evaluation to meet accuracies required for LMFBR, CTR, and LWR applications. (U.S.)

Pressurized helium II-cooled magnet test facility

International Nuclear Information System (INIS)

Warren, R.P.; Lambertson, G.R.; Gilbert, W.S.; Meuser, R.B.; Caspi, S.; Schafer, R.V.

1980-06-01

A facility for testing superconducting magnets in a pressurized bath of helium II has been constructed and operated. The cryostat accepts magnets up to 0.32 m diameter and 1.32 m length with current to 3000 A. In initial tests, the volume of helium II surrounding the superconducting magnet was 90 liters. Minimum temperature reached was 1.7 K at which point the pumping system was throttled to maintain steady temperature. Helium II reservoir temperatures were easily controlled as long as the temperature upstream of the JT valve remained above T lambda; at lower temperatures control became difficult. Positive control of the temperature difference between the liquid and cold sink by means of an internal heat source appears necessary to avoid this problem. The epoxy-sealed vessel closures, with which we have had considerable experience with normal helium vacuum, also worked well in the helium II/vacuum environment

Modeling Secondary Neutral Helium in the Heliosphere

International Nuclear Information System (INIS)

Müller, Hans-Reinhard; Möbius, Eberhard; Wood, Brian E.

2016-01-01

An accurate, analytic heliospheric neutral test-particle code for helium atoms from the interstellar medium (ISM) is coupled to global heliospheric models dominated by hydrogen and protons from the solar wind and the ISM. This coupling enables the forward-calculation of secondary helium neutrals from first principles. Secondaries are produced predominantly in the outer heliosheath, upwind of the heliopause, by charge exchange of helium ions with neutral atoms. The forward model integrates the secondary production terms along neutral trajectories and calculates the combined neutral helium phase space density in the innermost heliosphere where it can be related to in-situ observations. The phase space density of the secondary component is lower than that of primary neutral helium, but its presence can change the analysis of primaries and the ISM, and can yield valuable insight into the characteristics of the plasma in the outer heliosheath. (paper)

Annealing helicase HARP closes RPA-stabilized DNA bubbles non-processively.

Science.gov (United States)

Burnham, Daniel R; Nijholt, Bas; De Vlaminck, Iwijn; Quan, Jinhua; Yusufzai, Timur; Dekker, Cees

2017-05-05

We investigate the mechanistic nature of the Snf2 family protein HARP, mutations of which are responsible for Schimke immuno-osseous dysplasia. Using a single-molecule magnetic tweezers assay, we construct RPA-stabilized DNA bubbles within torsionally constrained DNA to investigate the annealing action of HARP on a physiologically relevant substrate. We find that HARP closes RPA-stabilized bubbles in a slow reaction, taking on the order of tens of minutes for ∼600 bp of DNA to be re-annealed. The data indicate that DNA re-anneals through the removal of RPA, which is observed as clear steps in the bubble-closing traces. The dependence of the closing rate on both ionic strength and HARP concentration indicates that removal of RPA occurs via an association-dissociation mechanism where HARP does not remain associated with the DNA. The enzyme exhibits classical Michaelis-Menten kinetics and acts cooperatively with a Hill coefficient of 3 ± 1. Our work also allows the determination of some important features of RPA-bubble structures at low supercoiling, including the existence of multiple bubbles and that RPA molecules are mis-registered on the two strands. © The Author(s) 2017. Published by Oxford University Press on behalf of Nucleic Acids Research.

Use of helium in uranium exploration, Grants district

International Nuclear Information System (INIS)

DeVoto, R.H.; Mead, R.H.; Martin, J.P.; Bergquist, L.E.

1980-01-01

The continuous generation of inert helium gas from uranium and its daughter products provides a potentially useful means for remote detection of uranium deposits. The practicality of conducting helium surveys in the atmosphere, soil gas, and ground water to explore for buried uranium deposits has been tested in the Grants district and in the Powder River Basin of Wyoming. No detectable helium anomalies related to buried or surface uranium deposits were found in the atmosphere. However, reproducible helium-in-soil-gas anomalies were detected spatially related to uranium deposits buried from 50 to 800 ft deep. Diurnal and atmospheric effects can cause helium content variations (noise) in soil gas that are as great as the anomalies observed from instantaneous soil-gas samples. Cumulative soil-gas helium analyses, such as those obtained from collecting undisturbed soil samples and degassing them in the laboratory, may reveal anomalies from 5 to 100 percent above background. Ground water samples from the Grants district, New Mexico, and the Powder River Basin, Wyoming, have distinctly anomalous helium values spatially related to buried uranium deposits. In the southern Powder River Basin, helium values 20 to 200 percent above background occur 2 to 18 mile down the ground-water flow path from known uranium roll-front deposits. In the Grants district, helium contents 40 to 700 percent above background levels are present in ground waters from the host sandstone in the vicinity of uranium deposits and from aquifers up to 3,000 ft stratigraphically above the deep uranium deposits. The use of helium in soil and ground-water surveys, along with uranium and radon analyses of the same materials, is strongly recommended is expensive, deep, uranium-exploration programs such as those being conducted in the Grants district

Manufacturing cycle for pure neon-helium mixture production

International Nuclear Information System (INIS)

Batrakov, B.P.; Kravchenko, V.A.

1980-01-01

The manufacturing cycle for pure neon-helium mixture production with JA-300 nitrogen air distributing device has been developed. Gas mixture containing 2-3% of neon-helium mixture (the rest is mainly nitrogen 96-97%) is selected out of the cover of the JA-300 column condensator and enters the deflegmator under the 2.3-2.5 atm. pressure. The diflegmator presents a heat exchange apparatus in which at 78 K liquid nitrogen the condensation of nitrogen from the mixture of gases entering from the JA-300 column takes place. The enriched gas mixture containing 65-70% of neon-helium mixture and 30-35% of nitrogen goes out from the deflegmator. This enriched neon-helium mixture enters the gasgoeder for impure (65-70%) neon-helium mixture. Full cleaning of-neon helium mixture of nitrogen is performed by means of an adsorber. As adsorbent an activated coal has been used. Adsorption occurs at the 78 K temperature of liquid nitrogen and pressure P=0.1 atm. As activated coal cooled down to nitrogen temperature adsorbs nitrogen better than neon and helium, the nitrogen from the mixture is completely adsorbed. Pure neon-helium mixture from the adsorber comes into a separate gasgolder. In one campaign the cycle allows obtaining 2 m 3 of the mixture. The mixture contains 0.14% of nitrogen, 0.01% of oxygen and 0.06% of hydrogen

CoFe Layers Thickness and Annealing Effect on the Magnetic Behavior of the CoFe/Cu Multilayer Nanowires

Directory of Open Access Journals (Sweden)

M. Ahmadzadeh

2015-04-01

Full Text Available CoFe/Cu multilayer nanowires were electrodeposited into anodic aluminum oxide templates prepared by a two-step mild anodization method, using the single-bath technique. Nanowires with 30 nm diameter and the definite lengths were obtained. The effect of CoFe layers thickness and annealing on the magnetic behavior of the multilayer nanowires was investigated. The layers thickness was controlled through the pulses numbers: 200, 260, 310,360 and 410 pulses were used to deposit the CoFe layers, while 300 pulse for the Cu layers. A certain increase in coercivity and squareness of CoFe/Cu multilayer nanowires observed with increasing the CoFe layer thickness and annealing improved the coercivity and decrease squareness of CoFe/Cu multilayer nanowires. First order reversal curves after annealed showed amount domains with soft magnetic phase, it also shows decreasing spreading of distribution function along the Hu axis after annealed

Mathematical foundation of quantum annealing

International Nuclear Information System (INIS)

Morita, Satoshi; Nishimori, Hidetoshi

2008-01-01

Quantum annealing is a generic name of quantum algorithms that use quantum-mechanical fluctuations to search for the solution of an optimization problem. It shares the basic idea with quantum adiabatic evolution studied actively in quantum computation. The present paper reviews the mathematical and theoretical foundations of quantum annealing. In particular, theorems are presented for convergence conditions of quantum annealing to the target optimal state after an infinite-time evolution following the Schroedinger or stochastic (Monte Carlo) dynamics. It is proved that the same asymptotic behavior of the control parameter guarantees convergence for both the Schroedinger dynamics and the stochastic dynamics in spite of the essential difference of these two types of dynamics. Also described are the prescriptions to reduce errors in the final approximate solution obtained after a long but finite dynamical evolution of quantum annealing. It is shown there that we can reduce errors significantly by an ingenious choice of annealing schedule (time dependence of the control parameter) without compromising computational complexity qualitatively. A review is given on the derivation of the convergence condition for classical simulated annealing from the view point of quantum adiabaticity using a classical-quantum mapping

Dynamics of cold helium flow inside a cryoline used for large cryogenic distribution system

International Nuclear Information System (INIS)

Kumar, Uday; Jadon, Mohit; Choukekar, Ketan; Shukla, Vinit; Patel, Pratik; Kapoor, Himanshu; Shah, Nitin; Muralidhara, Srinivasa; Sarkar, Biswanath

2015-01-01

The Cryolines, which by definition transfers cryogens from the source, normally a cryogenic plant, to several systems requiring cooling at cryogenic temperature to the level of 4 K and 80 K. The operations of cryolines are normally assumed to be steady state following a cool down from room temperature to the cryogenic temperature. It is to be noted that in a distributed cryogenic system, especially in a nuclear facility such as ITER having confinement definition due to the regulatory requirements, do also attract the attention in the system design that the release from safety valves cannot be allowed inside a building. Therefore, all safety valves need to be discharged inside a confined space, which is a specific space requiring fulfillment of definition for a cryogenic line. The specificity in such cases is that such cryogenic lines will realize dynamic conditions for each release of safety valves or a combination of safety valves in terms of pressure, temperature and flow, leading to unexpected failures. Such operating scenarios also lead to serious impact on fatigue with a question mark on the reliability. Therefore, one can define such cryolines as Relief Collection Header (RCH) which collects discharged helium and transport it to the appropriate place as defined in the system design. The discharges of cold helium from safety relief discharge ports of equipment can result into significantly unsteady and compressible flow in RCH. The proper design of the RCH has to be supported by detailed dynamic of expected flow phenomena for specific cases. The paper presents the dynamics of cold helium flow inside the typical RCH that has been performed to investigate the variation in flow parameters (pressure, temperature, velocity and density) along the axis of RCH and predictions on its reliability. (author)

Placement by thermodynamic simulated annealing

International Nuclear Information System (INIS)

Vicente, Juan de; Lanchares, Juan; Hermida, Roman

2003-01-01

Combinatorial optimization problems arise in different fields of science and engineering. There exist some general techniques coping with these problems such as simulated annealing (SA). In spite of SA success, it usually requires costly experimental studies in fine tuning the most suitable annealing schedule. In this Letter, the classical integrated circuit placement problem is faced by Thermodynamic Simulated Annealing (TSA). TSA provides a new annealing schedule derived from thermodynamic laws. Unlike SA, temperature in TSA is free to evolve and its value is continuously updated from the variation of state functions as the internal energy and entropy. Thereby, TSA achieves the high quality results of SA while providing interesting adaptive features

Modernizing quantum annealing using local searches

International Nuclear Information System (INIS)

Chancellor, Nicholas

2017-01-01

I describe how real quantum annealers may be used to perform local (in state space) searches around specified states, rather than the global searches traditionally implemented in the quantum annealing algorithm (QAA). Such protocols will have numerous advantages over simple quantum annealing. By using such searches the effect of problem mis-specification can be reduced, as only energy differences between the searched states will be relevant. The QAA is an analogue of simulated annealing, a classical numerical technique which has now been superseded. Hence, I explore two strategies to use an annealer in a way which takes advantage of modern classical optimization algorithms. Specifically, I show how sequential calls to quantum annealers can be used to construct analogues of population annealing and parallel tempering which use quantum searches as subroutines. The techniques given here can be applied not only to optimization, but also to sampling. I examine the feasibility of these protocols on real devices and note that implementing such protocols should require minimal if any change to the current design of the flux qubit-based annealers by D-Wave Systems Inc. I further provide proof-of-principle numerical experiments based on quantum Monte Carlo that demonstrate simple examples of the discussed techniques. (paper)

Thermoluminiscence and thermal annealing of F centres in KCL gamma irradiated

International Nuclear Information System (INIS)

Ausin Alonso, Vicente.

1976-01-01

The thermoluminiscence spectrum and phosphorescence decays of Harshaw KCl samples gamma irradiated at room temperature have been studied up to 400 0 C. For the six peaks found, the order of recombination kinetics, the pre-exponential factor and the activation energy have been obtained. It has been observed that the area under the thermoluminiscence curve is always proportional to the F centre concentration in the sample before heating. It was also found that there is an annealing step of F centres corresponding to each thermoluminiscence peak, when the temperature of the sample is raised at a constant rate. It is concluded that the F centres play the role of recombination centres in the annealing process, the interstitials being the mobile entities moving towards there combination centre. At some stage in the process light is emitted. (author)

Improving Simulated Annealing by Replacing Its Variables with Game-Theoretic Utility Maximizers

Science.gov (United States)

Wolpert, David H.; Bandari, Esfandiar; Tumer, Kagan

2001-01-01

The game-theory field of Collective INtelligence (COIN) concerns the design of computer-based players engaged in a non-cooperative game so that as those players pursue their self-interests, a pre-specified global goal for the collective computational system is achieved as a side-effect. Previous implementations of COIN algorithms have outperformed conventional techniques by up to several orders of magnitude, on domains ranging from telecommunications control to optimization in congestion problems. Recent mathematical developments have revealed that these previously developed algorithms were based on only two of the three factors determining performance. Consideration of only the third factor would instead lead to conventional optimization techniques like simulated annealing that have little to do with non-cooperative games. In this paper we present an algorithm based on all three terms at once. This algorithm can be viewed as a way to modify simulated annealing by recasting it as a non-cooperative game, with each variable replaced by a player. This recasting allows us to leverage the intelligent behavior of the individual players to substantially improve the exploration step of the simulated annealing. Experiments are presented demonstrating that this recasting significantly improves simulated annealing for a model of an economic process run over an underlying small-worlds topology. Furthermore, these experiments reveal novel small-worlds phenomena, and highlight the shortcomings of conventional mechanism design in bounded rationality domains.

Standard Guide for Simulation of Helium Effects in Irradiated Metals

CERN Document Server

American Society for Testing and Materials. Philadelphia

1996-01-01

1.1 This guide provides advice for conducting experiments to investigate the effects of helium on the properties of metals where the technique for introducing the helium differs in some way from the actual mechanism of introduction of helium in service. Simulation techniques considered for introducing helium shall include charged particle implantation, exposure to α-emitting radioisotopes, and tritium decay techniques. Procedures for the analysis of helium content and helium distribution within the specimen are also recommended. 1.2 Two other methods for introducing helium into irradiated materials are not covered in this guide. They are the enhancement of helium production in nickel-bearing alloys by spectral tailoring in mixed-spectrum fission reactors, and isotopic tailoring in both fast and mixed-spectrum fission reactors. These techniques are described in Refs (1-5). Dual ion beam techniques (6) for simultaneously implanting helium and generating displacement damage are also not included here. This lat...

Annealing effects on the structural, optical and magnetic properties of Mn implanted GaN

International Nuclear Information System (INIS)

Majid, Abdul; Ali, Akbar; Sharif, Rehana; Husnain, G

2009-01-01

Mn ions were implanted into GaN thin films with six doses ranging from 10 14 to 5 x 10 16 cm -2 and the samples were subsequently annealed isochronically in three steps at 800, 850 and 900 deg. C. Structural, optical and magnetic properties of the implanted samples were studied after each annealing. X-ray diffraction measurements exhibited new peaks on the lower angle side of the main GaN peak which are attributed to the implantation induced damage as well as the formation of a GaMnN phase. A dose dependent decrease in the optical band gap and an increase in the Urbach tail were observed from optical transmission measurements. The clear magnetic hysteresis loops were recorded by the magnetometer which revealed the room temperature ferromagnetic ordering in all the implanted samples. Unusual behaviour in the magnetic measurements was observed when saturation magnetic moment decreased in all the samples with an increase in annealing temperature from 850 to 900 deg. C. This is explained by the out-diffusion of Mn atoms from the samples during high temperature annealing. Annealing temperature of 850 deg. C for Mn implanted GaN has been suggested as suitable since the samples annealed at this temperature exhibited maximum M s and minimum Urbach energy. Bound magnetic polarons are suggested to be the origin of room temperature ferromagnetic exchange in the samples. XPS measurements indicated that the Mn ions have been incorporated into the wurtzite structure of the host lattice by substituting the Ga sites.

Annealing effects on the structural, optical and magnetic properties of Mn implanted GaN

Energy Technology Data Exchange (ETDEWEB)

Majid, Abdul; Ali, Akbar [Advance Materials Physics Laboratory, Physics Department, Quaid-i-Azam University, Islamabad (Pakistan); Sharif, Rehana [Department of Physics, University of Engineering and Technology, Lahore (Pakistan); Husnain, G, E-mail: abdulmajid40@yahoo.co, E-mail: akbar@qau.edu.p [Key Laboratory of Nuclear Physics and Technology, Peking University, Beijing 100871 (China)

2009-07-07

Mn ions were implanted into GaN thin films with six doses ranging from 10{sup 14} to 5 x 10{sup 16} cm{sup -2} and the samples were subsequently annealed isochronically in three steps at 800, 850 and 900 deg. C. Structural, optical and magnetic properties of the implanted samples were studied after each annealing. X-ray diffraction measurements exhibited new peaks on the lower angle side of the main GaN peak which are attributed to the implantation induced damage as well as the formation of a GaMnN phase. A dose dependent decrease in the optical band gap and an increase in the Urbach tail were observed from optical transmission measurements. The clear magnetic hysteresis loops were recorded by the magnetometer which revealed the room temperature ferromagnetic ordering in all the implanted samples. Unusual behaviour in the magnetic measurements was observed when saturation magnetic moment decreased in all the samples with an increase in annealing temperature from 850 to 900 deg. C. This is explained by the out-diffusion of Mn atoms from the samples during high temperature annealing. Annealing temperature of 850 deg. C for Mn implanted GaN has been suggested as suitable since the samples annealed at this temperature exhibited maximum M{sub s} and minimum Urbach energy. Bound magnetic polarons are suggested to be the origin of room temperature ferromagnetic exchange in the samples. XPS measurements indicated that the Mn ions have been incorporated into the wurtzite structure of the host lattice by substituting the Ga sites.

Ensemble annealing of complex physical systems

OpenAIRE

Habeck, Michael

2015-01-01

Algorithms for simulating complex physical systems or solving difficult optimization problems often resort to an annealing process. Rather than simulating the system at the temperature of interest, an annealing algorithm starts at a temperature that is high enough to ensure ergodicity and gradually decreases it until the destination temperature is reached. This idea is used in popular algorithms such as parallel tempering and simulated annealing. A general problem with annealing methods is th...

Effects of substrate temperature and post-deposition anneal on properties of evaporated cadmium telluride films

International Nuclear Information System (INIS)

Bacaksiz, E.; Basol, B.M.; Altunbas, M.; Novruzov, V.; Yanmaz, E.; Nezir, S.

2007-01-01

The effects of substrate temperature and post-deposition heat treatment steps on the morphology, structural, optical and electrical properties of thin film CdTe layers grown by vacuum evaporation were investigated. Scanning electron microscopy and X-ray diffraction (XRD) techniques were employed to study the structural changes. It was observed that the grain sizes and morphologies of as-deposited layers were similar for substrate temperatures of - 173 deg. C and - 73 deg. C. However, CdTe films produced at a substrate temperature of 27 deg. C had substantially larger grain size and clearly facetted morphology. Annealing at 200-400 deg. C in air did not cause any appreciable grain growth in any of the films irrespective of their growth temperature. However, annealing at 400 deg. C reduced faceting in all cases and initiated fusing between grains. XRD studies showed that this behavior after annealing at 400 deg. C coincided with an onset of a degree of randomization in the originally strong (111) texture of the as-grown layers. Optical band gap measurements showed sharpening of the band-edge upon annealing at 400 deg. C and a band gap value in the range of 1.46-1.49 eV. Resistivity measurements indicated that annealing at 400 deg. C in air forms a highly resistive compensated CdTe film. All results point to 400 deg. C to be a critical annealing temperature at which optical, structural and electrical properties of CdTe layers start to change

Helium-induced weld degradation of HT-9 steel

International Nuclear Information System (INIS)

Wang, Chin-An; Chin, B.A.; Lin, Hua T.; Grossbeck, M.L.

1992-01-01

Helium-bearing Sandvik HT-9 ferritic steel was tested for weldability to simulate the welding of structural components of a fusion reactor after irradiation. Helium was introduced into HT-9 steel to 0.3 and 1 atomic parts per million (appm) by tritium doping and decay. Autogenous single pass full penetration welds were produced using the gas tungsten arc (GTA) welding process under laterally constrained conditions. Macroscopic examination showed no sign of any weld defect in HT-9 steel containing 0.3 appm helium. However, intergranular micro cracks were observed in the HAZ of HT-9 steel containing 1 appm helium. The microcracking was attributed to helium bubble growth at grain boundaries under the influence of high stresses and temperatures that were present during welding. Mechanical test results showed that both yield strength (YS) and ultimate tensile strength (UTS) decreased with increasing temperature, while the total elongation increased with increasing temperature for all control and helium-bearing HT-9 steels

Comparison of pulsed electron beam-annealed and pulsed ruby laser-annealed ion-implanted silicon

International Nuclear Information System (INIS)

Wilson, S.R.; Appleton, B.R.; White, C.W.; Narayan, J.; Greenwald, A.C.

1978-11-01

Recently two new techniques, pulsed electron beam annealing and pulsed laser annealing, have been developed for processing ion-implanted silicon. These two types of anneals have been compared using ion-channeling, ion back-scattering, and transmission electron microscopy (TEM). Single crystal samples were implanted with 100 keV As + ions to a dose of approx. 1 x 10 16 ions/cm 2 and subsequently annealed by either a pulsed Ruby laser or a pulsed electron beam. Our results show in both cases that the near-surface region has melted and regrown epitaxially with nearly all of the implanted As (97 to 99%) incroporated onto lattice sites. The analysis indicates that the samples are essentially defect free and have complete electrical recovery

Temperature-modulated annealing of c-plane sapphire for long-range-ordered atomic steps

International Nuclear Information System (INIS)

Yatsui, Takashi; Kuribara, Kazunori; Sekitani, Tsuyoshi; Someya, Takao; Yoshimoto, Mamoru

2016-01-01

High-quality single-crystalline sapphire is used to prepare various semiconductors because of its thermal stability. Here, we applied the tempering technique, which is well known in the production of chocolate, to prepare a sapphire substrate. Surprisingly, we successfully realised millimetre-range ordering of the atomic step of the sapphire substrate. We also obtained a sapphire atomic step with nanometre-scale uniformity in the terrace width and atomic-step height. Such sapphire substrates will find applications in the preparation of various semiconductors and devices. (paper)

Influence of Carrier Gas Composition on the Stress of Al₂O₃ Coatings Prepared by the Aerosol Deposition Method.

Science.gov (United States)

Schubert, Michael; Exner, Jörg; Moos, Ralf

2014-08-05

Al₂O₃ films were prepared by the aerosol deposition method at room temperature using different carrier gas compositions. The layers were deposited on alumina substrates and the film stress of the layer was calculated by measuring the deformation of the substrate. It was shown that the film stress can be halved by using oxygen instead of nitrogen or helium as the carrier gas. The substrates were annealed at different temperature steps to gain information about the temperature dependence of the reduction of the implemented stress. Total relaxation of the stress can already be achieved at 300 °C. The XRD pattern shows crystallite growth and reduction of microstrain while annealing.

Tritium release kinetics in lithium orthosilicate ceramic pebbles irradiated with low thermal-neutron fluence

Energy Technology Data Exchange (ETDEWEB)

Xiao, Chengjian; Gao, Xiaoling [Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, Box 919-214, Mian Yang 621900 (China); Kobayashi, Makoto; Kawasaki, Kiyotaka; Uchimura, Hiromichi; Toda, Kensuke [China Academy of Engineering Physics, Box 919-1, Mian Yang 621900 (China); Kang, Chunmei; Chen, Xiaojun; Wang, Heyi; Peng, Shuming [Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, Box 919-214, Mian Yang 621900 (China); Wang, Xiaolin, E-mail: xlwang@caep.ac.cn [China Academy of Engineering Physics, Box 919-1, Mian Yang 621900 (China); Oya, Yasuhisa; Okuno, Kenji [Radiochemistry Research Laboratory, Faculty of Science, Shizuoka University, 836 Ohya, Shizuoka 422-8529 (Japan)

2013-07-15

Tritium release kinetics in lithium orthosilicate (Li{sub 4}SiO{sub 4}) ceramic pebbles irradiated with low thermal-neutron fluence was studied by out-of-pile annealing experiments. It was found that the tritium produced in Li{sub 4}SiO{sub 4} pebbles was mainly released as tritiated water vapor (HTO). The apparent desorption activation energy of tritium on the pebble surface was consistent with the diffusion activation energy of tritium in the crystal grains, indicating that tritium release was mainly controlled by diffusion process. The diffusion coefficients of tritium in the crystal grains at temperatures ranging from 450 K to 600 K were obtained by isothermal annealing tests, and the Arrhenius relation was determined to be D = 1 × 10{sup −7.0} exp (−40.3 × 10{sup 3}/RT) cm{sup 2} s{sup −1}.

Charged condensate and helium dwarf stars

Energy Technology Data Exchange (ETDEWEB)

Gabadadze, Gregory; Rosen, Rachel A, E-mail: gg32@nyu.edu, E-mail: rar339@nyu.edu [Center for Cosmology and Particle Physics, Department of Physics, New York University, New York, NY 10003 (United States)

2008-10-15

White dwarf stars composed of carbon, oxygen and heavier elements are expected to crystallize as they cool down below certain temperatures. Yet, simple arguments suggest that the helium white dwarf cores may not solidify, mostly because of zero-point oscillations of the helium ions that would dissolve the crystalline structure. We argue that the interior of the helium dwarfs may instead form a macroscopic quantum state in which the charged helium-4 nuclei are in a Bose-Einstein condensate, while the relativistic electrons form a neutralizing degenerate Fermi liquid. We discuss the electric charge screening, and the spectrum of this substance, showing that the bosonic long-wavelength fluctuations exhibit a mass gap. Hence, there is a suppression at low temperatures of the boson contribution to the specific heat-the latter being dominated by the specific heat of the electrons near the Fermi surface. This state of matter may have observational signatures.

On the helium gas leak test

International Nuclear Information System (INIS)

Nishikawa, Akira; Ozaki, Susumu

1975-01-01

The helium gas leak test (Helium mass spectrometer testing) has a leak detection capacity of the highest level in practical leak tests and is going to be widely applied to high pressure vessels, atomic and vacuum equipments that require high tightness. To establish a standard test procedure several series of experiments were conducted and the results were investigated. The conclusions are summarized as follows: (1) The hood method is quantitatively the most reliable method. The leak rate obtained by tests using 100% helium concentration should be the basis of the other method of test. (2) The integrating method, bell jar method, and vacuum spray method can be considered quantitative when particular conditions are satisfied. (3) The sniffer method is not to be considered quantitive. (4) The leak rate of the hood, integrating, and bell jar methods is approximately proportional to the square of the helium partial pressure. (auth.)

Effect of thermal annealing on the structural and optical properties of tris-(8-hydroxyquinoline)aluminum(III) (Alq3 ) films.

Science.gov (United States)

Cuba, M; Muralidharan, G

2015-05-01

Tris-(8-hydroxyquionoline)aluminum (Alq3 ) was synthesized and coated on to a glass substrate using the dip coating method. The structural and optical properties of the Alq3 film after thermal annealing from 50°C to 300°C in 50° steps was studied. The films have been prepared with 2 to 16 layers (42-324 nm). The thickness and thermal annealing of Alq3 films were optimized for maximum luminescence yield. The Fourier transform infrared spectrum confirms the formation of quinoline with absorption in the region 700 - 500/cm. Partial sublimation and decomposition of quinoline ion was observed with the Alq3 films annealed at 300°C. The X-ray diffraction pattern of the Alq3 film annealed at 50°C to 150°C reveals the amorphous nature of the films. The Alq3 film annealed above 150°C were crystalline nature. Film annealed at 150°C exhibits a photoluminescence intensity maximum at 512 nm when excited at 390 nm. The Alq3 thin film deposited with 10 layers (220 nm) at 150°C exhibited maximum luminescence yield. Copyright © 2014 John Wiley & Sons, Ltd.

Helium-3 and helium-4 acceleration by high power laser pulses for hadron therapy

Directory of Open Access Journals (Sweden)

S. S. Bulanov

2015-06-01

Full Text Available The laser driven acceleration of ions is considered a promising candidate for an ion source for hadron therapy of oncological diseases. Though proton and carbon ion sources are conventionally used for therapy, other light ions can also be utilized. Whereas carbon ions require 400 MeV per nucleon to reach the same penetration depth as 250 MeV protons, helium ions require only 250 MeV per nucleon, which is the lowest energy per nucleon among the light ions (heavier than protons. This fact along with the larger biological damage to cancer cells achieved by helium ions, than that by protons, makes this species an interesting candidate for the laser driven ion source. Two mechanisms (magnetic vortex acceleration and hole-boring radiation pressure acceleration of PW-class laser driven ion acceleration from liquid and gaseous helium targets are studied with the goal of producing 250 MeV per nucleon helium ion beams that meet the hadron therapy requirements. We show that He^{3} ions, having almost the same penetration depth as He^{4} with the same energy per nucleon, require less laser power to be accelerated to the required energy for the hadron therapy.

Annealing effects in solid-state track recorders

International Nuclear Information System (INIS)

Gold, R.; Roberts, J.H.; Ruddy, F.H.

1981-01-01

Current analyses of the annealing process in Solid State Track Recorders (SSTR) reveal fundamental misconceptions. The use of the Arrhenius equation to describe the decrease in track density resulting from annealing is shown to be incorrect. To overcome these deficiencies, generalized reaction rate theory is used to describe the annealing process in SSTR. Results of annealing experiments are used to guide this theoretical formulation. Within this framework, the concept of energy per etchable defect for SSTR is introduced. A general correlation between sensitivity and annealing susceptibility in SSTR is deduced. In terms of this general theory, the apparent correlation between fission track size and fission track density observed under annealing is readily explained. Based on this theoretical treatment of annealing phenomena, qualitative explanations are advanced for current enigmas in SSTR cosmic ray work

Studies of isothermal annealing of fission fragment and alpha particle tracks in Cr-39 polymer detectors

International Nuclear Information System (INIS)

Zaky, M.F.; Youssef, A.A.

2002-01-01

Two groups of CR-39 detectors samples are exposed to two types of charged particle radiation. The first group are severe damaged with fission fragment tracks from 2 52C f source. The second accepted alpha particles resulting from the interaction of highly energetic 1 9F -ions and a copper disk with thickness 1 cm, which are of less damage tracks than fission fragments. , The isothermal annealing of tracks in the temperature range from 175 to 300 degree C in step 25 degree C for annealing time of 10,15,20,25 and 30 minutes has been investigated. The changes introduced in the track density and track diameter for two types of irradiation in the detector have been observed and compared between them. The results indicate that the track density and the size of the tracks are considerably changed due to annealing

Superfluid helium at subcritical active core

International Nuclear Information System (INIS)

Vasil'ev, V.V.; Lopatkin, A.V.; Muratov, V.G.; Rakhno, I.L.

2002-01-01

Power range and neutron flux wherein super thermal source was realized at high volume of superfluid helium were investigated. MCU, BRAND, MCNP codes were used for the calculation of reactors. It is shown that the availability of full-size diameter for cryogenic source of ultracold neutrons, as the source with superfluid helium is considered, is possible in the reflector of subcritical assembly. Results obtained from the MCNP-4B code application demonstrated that the density of thermal neutron flux in helium must be not higher than 2.3 x 10 11 s -1 cm -2 [ru

Helium leak testing methods in nuclear applications

International Nuclear Information System (INIS)

Ahmad, Anis

2004-01-01

Helium mass-spectrometer leak test is the most sensitive leak test method. It gives very reliable and sensitive test results. In last few years application of helium leak testing has gained more importance due to increased public awareness of safety and environment pollution caused by number of growing chemical and other such industries. Helium leak testing is carried out and specified in most of the critical area applications like nuclear, space, chemical and petrochemical industries

Pressurized-helium breakdown at very low temperatures

Energy Technology Data Exchange (ETDEWEB)

Metas, R J

1972-06-01

An investigation of the electrical-breakdown behavior of helium at very low temperatures has been carried out to assist the design and development of superconducting power cables. At very high densities, both liquid and gaseous helium showed an enhancement in electric strength when pressurized to a few atmospheres; conditioned values of breakdown fields then varied between 30 and 45 MV/m. Breakdown processes occurring over a wide range of helium densities are discussed. 24 references.

Strengthening mechanisms in nanostructured high-purity aluminium deformed to high strain and annealed

DEFF Research Database (Denmark)

Kamikawa, Naoya; Huang, Xiaoxu; Tsuji, Nobuhiro

2009-01-01

Samples of pure aluminium (99.99%) have been produced by accumulative roll-bonding to a large strain followed by a heat treatment, where a two-step annealing process has been used to produce samples with large variations in structural parameters such as boundary spacing, misorientation angle...... and dislocation density. These parameters have been quantified by a structural analysis applying transmission electron microscopy and electron backscatter diffraction, and the mechanical properties have been determined by tensile testing at room temperature. Strength–structure relationships have been analysed...... based on the operation of two strengthening mechanisms—grain boundary and dislocation strengthening—and good agreement with experiments has been found for the deformed sample. However, for samples where the density of dislocation sources has been reduced significantly by annealing, an additional...

Dipole moments of molecules solvated in helium nanodroplets

International Nuclear Information System (INIS)

Stiles, Paul L.; Nauta, Klaas; Miller, Roger E.

2003-01-01

Stark spectra are reported for hydrogen cyanide and cyanoacetylene solvated in helium nanodroplets. The goal of this study is to understand the influence of the helium solvent on measurements of the permanent electric dipole moment of a molecule. We find that the dipole moments of the helium solvated molecules, calculated assuming the electric field is the same as in vacuum, are slightly smaller than the well-known gas-phase dipole moments of HCN and HCCCN. A simple elliptical cavity model quantitatively accounts for this difference, which arises from the dipole-induced polarization of the helium

Research and development of a high-temperature helium-leak detection system (joint research). Part 1 survey on leakage events and current leak detection technology

Energy Technology Data Exchange (ETDEWEB)

Sakaba, Nariaki; Nakazawa, Toshio; Kawasaki, Kozo [Japan Atomic Energy Research Inst., Oarai, Ibaraki (Japan). Oarai Research Establishment; Urakami, Masao; Saisyu, Sadanori [Japan Atomic Power Co., Tokyo (Japan)

2003-03-01

In High Temperature Gas-cooled Reactors (HTGR), the detection of leakage of helium at an early stage is very important for the safety and stability of operations. Since helium is a colourless gas, it is generally difficult to identify the location and the amount of leakage when very little leakage has occurred. The purpose of this R and D is to develop a helium leak detection system for the high temperature environment appropriate to the HTGR. As the first step in the development, this paper describes the result of surveying leakage events at nuclear facilities inside and outside Japan and current gas leakage detection technology to adapt optical-fibre detection technology to HTGRs. (author)

Annealing tests of in-pile irradiated oxide coated U-Mo/Al-Si dispersed nuclear fuel

Science.gov (United States)

Zweifel, T.; Valot, Ch.; Pontillon, Y.; Lamontagne, J.; Vermersch, A.; Barrallier, L.; Blay, T.; Petry, W.; Palancher, H.

2014-09-01

U-Mo/Al based nuclear fuels have been worldwide considered as a promising high density fuel for the conversion of high flux research reactors from highly enriched uranium to lower enrichment. In this paper, we present the annealing test up to 1800 °C of in-pile irradiated U-Mo/Al-Si fuel plate samples. More than 70% of the fission gases (FGs) are released during two major FG release peaks around 500 °C and 670 °C. Additional characterisations of the samples by XRD, EPMA and SEM suggest that up to 500 °C FGs are released from IDL/matrix interfaces. The second peak at 670 °C representing the main release of FGs originates from the interaction between U-Mo and matrix in the vicinity of the cladding.

Release of fission products from irradiated aluminide fuel at high temperature

International Nuclear Information System (INIS)

Shibata, Toshikazu; Kanda, Keiji; Mishima, Kaichiro; Tamai, Tadaharu; Hayashi, Masatoshi; Snelgrove, James L.; Stahl, David; Matos, James E.; Travelli, Armando; Case, F. Neil; Posey, John C.

1983-01-01

Irradiated uranium aluminide fuel plates of 40% U-235 enrichment were heated for the determination of fission products released under flowing helium gas at temperatures up to and higher than the melting point of fuel cladding material. The release of fission products from the fuel plate at temperature below 500 deg. C was found negligible. The first rapid release of fission products was observed with the occurrence of blistering at 561±1 deg. C on the plates. The next release at 585. C might be caused by melting of the cladding material of 6061-Al alloy. The last release of fission product gases was occurred at the eutectic temperature of 640 deg. C of U-Al x . The released material was mostly xenon, but small amounts of iodine and cesium were observed. (author)

Release of fission products from irradiated aluminide fuel at high temperature

International Nuclear Information System (INIS)

Shibata, T.; Kanda, K.; Mishima, K.

1982-01-01

Irradiated uranium aluminide fuel plates of 40% U-235 enrichment were heated for the determination of fission products released under flowing helium gas at temperatures up to and higher than the melting point of fuel-cladding material. The release of fission products from the fuel plate at temperature below 500 0 C was found negligible. The firist rapid release of fission products was observed with the occurrence of blistering at 561 +- 1 0 C on the plates. The next release at 585 0 C might be caused by melting of the cladding material of 6061-Al alloy. The last release of fission product gases was occurred at the eutectic temperature of 640 0 C of U-Al/sub x/. The released material was mostly xenon, but small amounts of iodine and cesium were observed

The influence of irradiation defects on tritium release from Li{sub 2}O

Energy Technology Data Exchange (ETDEWEB)

Tanaka, Satoru; Grishmanov, V [Tokyo Univ. (Japan). Faculty of Engineering

1996-10-01

During reactor irradiation of Li{sub 2}O defects are introduced by neutrons, triton and helium ions produced by {sup 6}Li(n, {alpha}){sup 3}H reactions and {gamma}-rays. Simultaneous measurements of luminescence emission and tritium release were performed under various conditions (temperature, sweep gas chemical composition) for Li{sub 2}O single crystal and polycrystal in order to elucidate possible influence of defects on tritium release. (author)

Meteoritic anomalies and explosive neutron processing of helium-burning shells

International Nuclear Information System (INIS)

Thielemann, F.K.; Arnould, M.; Hillebrandt, W.

1978-07-01

The late addition to the average solar mix of some heavy elements, and particularly r-process nuclei of exotic composition seems to be compatible with recent meteoritic analyses. The very origin of such alien components and their peculiar composition have to be understood on grounds of astrophysical models. As a first step in this direction, the present work analyses the explosive nuclear processing associated with the passage of a supernova shock front through the helium-burning shell of a massive presupernova star, and particularly examines the resulting heavy (A >= 60) element yields. (orig.) 891 WL [de

Helium atoms and molecules in strong magnetic fields

Science.gov (United States)

Mori, K.

Recent theoretical studies have shown that the neutron star surface may be composed of helium or heavier elements as hydrogen may be quickly depleted by diffuse nuclear burning Chang Bildsten However while Hydrogen atmospheres have been studied in great details atomic data for helium is available only for He ion Pavlov Bezchastnov 2005 We performed Hartree-Fock type calculation for Helium atom and molecules and computed their binding ionization and dissociation energies in strong magnetic fields B sim10 12 -- 10 15 G We will present ionization balance of Helium atmospheres at typical magnetic field strengths and temperatures to radio-quiet neutron stars and AXPs We will also discuss several implications of helium atmosphere to X-ray data of isolated neutron stars focusing on the detected spectral features

Helium cosmic ray flux measurements at Mars

International Nuclear Information System (INIS)

Lee, Kerry; Pinsky, Lawrence; Andersen, Vic; Zeitlin, Cary; Cleghorn, Tim; Cucinotta, Frank; Saganti, Premkumar; Atwell, William; Turner, Ron

2006-01-01

The helium energy spectrum in Martian orbit has been observed by the MARIE charged particle spectrometer aboard the 2001 Mars Odyssey spacecraft. The orbital data were taken from March 13, 2002 to October 28, 2003, at which time a very intense Solar Particle Event caused a loss of communication between the instrument and the spacecraft. The silicon detector stack in MARIE is optimized for the detection of protons and helium in the energy range below 100MeV/n, which typically includes almost all of the flux during SPEs. This also makes MARIE an efficient detector for GCR helium in the energy range of 50-150MeV/n. We will present the first fully normalized flux results from MARIE, using helium ions in this energy range

Helium cosmic ray flux measurements at Mars

Energy Technology Data Exchange (ETDEWEB)

Lee, Kerry [University of Houston, 4800 Calhoun Rd. Houston, TX 77204 (United States)]. E-mail: ktlee@ems.jsc.nasa.gov; Pinsky, Lawrence [University of Houston, 4800 Calhoun Rd. Houston, TX 77204 (United States); Andersen, Vic [University of Houston, 4800 Calhoun Rd. Houston, TX 77204 (United States); Zeitlin, Cary [National Space Biomedical Research Institute, Baylor College of Medicine, Houston, TX (United States); Cleghorn, Tim [NASA Johnson Space Center, 2101 NASA Road 1, Houston, TX 77058 (United States); Cucinotta, Frank [NASA Johnson Space Center, 2101 NASA Road 1, Houston, TX 77058 (United States); Saganti, Premkumar [Prairie View A and M University, P.O. Box 519, Prairie View, TX 77446-0519 (United States); Atwell, William [The Boeing Company, Houston, TX (United States); Turner, Ron [Advancing National Strategies and Enabling Results (ANSER), Arlington, Virginia (United States)

2006-10-15

The helium energy spectrum in Martian orbit has been observed by the MARIE charged particle spectrometer aboard the 2001 Mars Odyssey spacecraft. The orbital data were taken from March 13, 2002 to October 28, 2003, at which time a very intense Solar Particle Event caused a loss of communication between the instrument and the spacecraft. The silicon detector stack in MARIE is optimized for the detection of protons and helium in the energy range below 100MeV/n, which typically includes almost all of the flux during SPEs. This also makes MARIE an efficient detector for GCR helium in the energy range of 50-150MeV/n. We will present the first fully normalized flux results from MARIE, using helium ions in this energy range.

The calculating methods of the release of airborne radionuclides to environment during the normal operation of a module high temperature gas-cooled reactor

International Nuclear Information System (INIS)

Liu Yuanzhong

1993-01-01

The calculations of the release of radionuclides to environment are the basis of environmental impact assessment during the normal operation of a module high temperature gas-cooled reactor of the Institute of Nuclear Energy Technology, Tsinghua University, China. According to the features of the reactor it is pointed out that only five sources of the airborne radioactive materials released to environment are important. They are: (1) the activation of the air in the reactor cavity; (2) the escape from the primary coolant systems; (3) the release of radioactively contaminated helium from storage tanks; (4) the release of radioactively contaminated helium from the gas evacuation system of fuel load and unload system; (5) the leakage of the vapour from water-steam loop. In accordance with five release sources the calculating methods of radionuclides released to environment are worked out respectively and the respective calculating formulas are derived for the normal operation of the reactor

Rapid fabrication of transparent conductive films with controllable sheet resistance on glass substrates by laser annealing of diamond-like carbon films

International Nuclear Information System (INIS)

Lee, Keunhee; Ki, Hyungson

2016-01-01

We report a laser-based method for directly fabricating large-area, transparent conductive films with customizable electrical resistance on glass. In this method, a diamond-like carbon (DLC) film is deposited first on a glass substrate by pulsed laser deposition, which is then annealed in a helium shielding environment by a 2 kW continuous-wave fiber laser with a wavelength of 1070 nm, which is transparent to glass but is absorbed by DLC to transform the amorphous carbons to graphene. When a 510 nm thick film was annealed at a scanning speed of 1 m/s by a 200 μm top-hat laser beam, the sp 3 fraction was decreased from 43.1% to 8.1% after the annealing process, and the transformed film showed a transparency of ∼80% (at 550 nm) and a sheet resistance of ∼2050 Ω/sq. We also showed that sheet resistance and transparency can be controlled by changing processing parameters. To show the scalability of the method, a 15 mm wide line beam was used to produce a 15 mm × 15 mm film. This method is simple, fully scalable, transfer-free and catalyst-free, and we believe that the fabricated films can have many applications with further research, such as transparent heating films, electromagnetic shielding films, and transparent electrodes.

Atomistic simulation of helium bubble nucleation in palladium