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Sample records for statistical mechanics formulation

  1. Statistical-mechanical formulation of Lyapunov exponents

    International Nuclear Information System (INIS)

    Tanase-Nicola, Sorin; Kurchan, Jorge

    2003-01-01

    We show how the Lyapunov exponents of a dynamic system can, in general, be expressed in terms of the free energy of a (non-Hermitian) quantum many-body problem. This puts their study as a problem of statistical mechanics, whose intuitive concepts and techniques of approximation can hence be borrowed

  2. Brief introduction to Lie-admissible formulations in statistical mechanics

    International Nuclear Information System (INIS)

    Fronteau, J.

    1981-01-01

    The present article is a summary of the essential ideas and results published in previous articles, the aim here being to describe the situation in a schematic way for the benefit of non-specialists. The non-truncated Liouville theorem and equation, natural introduction of Lie-admissible formulations into statistical mechanics, the notion of a statistical quasi-particle, and transition towards the notion of fine thermodynamics are discussed

  3. Statistical mechanics

    CERN Document Server

    Davidson, Norman

    2003-01-01

    Clear and readable, this fine text assists students in achieving a grasp of the techniques and limitations of statistical mechanics. The treatment follows a logical progression from elementary to advanced theories, with careful attention to detail and mathematical development, and is sufficiently rigorous for introductory or intermediate graduate courses.Beginning with a study of the statistical mechanics of ideal gases and other systems of non-interacting particles, the text develops the theory in detail and applies it to the study of chemical equilibrium and the calculation of the thermody

  4. Statistical mechanics

    CERN Document Server

    Schwabl, Franz

    2006-01-01

    The completely revised new edition of the classical book on Statistical Mechanics covers the basic concepts of equilibrium and non-equilibrium statistical physics. In addition to a deductive approach to equilibrium statistics and thermodynamics based on a single hypothesis - the form of the microcanonical density matrix - this book treats the most important elements of non-equilibrium phenomena. Intermediate calculations are presented in complete detail. Problems at the end of each chapter help students to consolidate their understanding of the material. Beyond the fundamentals, this text demonstrates the breadth of the field and its great variety of applications. Modern areas such as renormalization group theory, percolation, stochastic equations of motion and their applications to critical dynamics, kinetic theories, as well as fundamental considerations of irreversibility, are discussed. The text will be useful for advanced students of physics and other natural sciences; a basic knowledge of quantum mechan...

  5. Statistical mechanics

    CERN Document Server

    Jana, Madhusudan

    2015-01-01

    Statistical mechanics is self sufficient, written in a lucid manner, keeping in mind the exam system of the universities. Need of study this subject and its relation to Thermodynamics is discussed in detail. Starting from Liouville theorem gradually, the Statistical Mechanics is developed thoroughly. All three types of Statistical distribution functions are derived separately with their periphery of applications and limitations. Non-interacting ideal Bose gas and Fermi gas are discussed thoroughly. Properties of Liquid He-II and the corresponding models have been depicted. White dwarfs and condensed matter physics, transport phenomenon - thermal and electrical conductivity, Hall effect, Magneto resistance, viscosity, diffusion, etc. are discussed. Basic understanding of Ising model is given to explain the phase transition. The book ends with a detailed coverage to the method of ensembles (namely Microcanonical, canonical and grand canonical) and their applications. Various numerical and conceptual problems ar...

  6. QUANTUM MECHANICS WITHOUT STATISTICAL POSTULATES

    International Nuclear Information System (INIS)

    Geiger, G.

    2000-01-01

    The Bohmian formulation of quantum mechanics describes the measurement process in an intuitive way without a reduction postulate. Due to the chaotic motion of the hidden classical particle all statistical features of quantum mechanics during a sequence of repeated measurements can be derived in the framework of a deterministic single system theory

  7. Semiclassical statistical mechanics

    International Nuclear Information System (INIS)

    Stratt, R.M.

    1979-04-01

    On the basis of an approach devised by Miller, a formalism is developed which allows the nonperturbative incorporation of quantum effects into equilibrium classical statistical mechanics. The resulting expressions bear a close similarity to classical phase space integrals and, therefore, are easily molded into forms suitable for examining a wide variety of problems. As a demonstration of this, three such problems are briefly considered: the simple harmonic oscillator, the vibrational state distribution of HCl, and the density-independent radial distribution function of He 4 . A more detailed study is then made of two more general applications involving the statistical mechanics of nonanalytic potentials and of fluids. The former, which is a particularly difficult problem for perturbative schemes, is treated with only limited success by restricting phase space and by adding an effective potential. The problem of fluids, however, is readily found to yield to a semiclassical pairwise interaction approximation, which in turn permits any classical many-body model to be expressed in a convenient form. The remainder of the discussion concentrates on some ramifications of having a phase space version of quantum mechanics. To test the breadth of the formulation, the task of constructing quantal ensemble averages of phase space functions is undertaken, and in the process several limitations of the formalism are revealed. A rather different approach is also pursued. The concept of quantum mechanical ergodicity is examined through the use of numerically evaluated eigenstates of the Barbanis potential, and the existence of this quantal ergodicity - normally associated with classical phase space - is verified. 21 figures, 4 tables

  8. Equilibrium statistical mechanics

    CERN Document Server

    Jackson, E Atlee

    2000-01-01

    Ideal as an elementary introduction to equilibrium statistical mechanics, this volume covers both classical and quantum methodology for open and closed systems. Introductory chapters familiarize readers with probability and microscopic models of systems, while additional chapters describe the general derivation of the fundamental statistical mechanics relationships. The final chapter contains 16 sections, each dealing with a different application, ordered according to complexity, from classical through degenerate quantum statistical mechanics. Key features include an elementary introduction t

  9. Lectures on statistical mechanics

    CERN Document Server

    Bowler, M G

    1982-01-01

    Anyone dissatisfied with the almost ritual dullness of many 'standard' texts in statistical mechanics will be grateful for the lucid explanation and generally reassuring tone. Aimed at securing firm foundations for equilibrium statistical mechanics, topics of great subtlety are presented transparently and enthusiastically. Very little mathematical preparation is required beyond elementary calculus and prerequisites in physics are limited to some elementary classical thermodynamics. Suitable as a basis for a first course in statistical mechanics, the book is an ideal supplement to more convent

  10. Equilibrium statistical mechanics

    CERN Document Server

    Mayer, J E

    1968-01-01

    The International Encyclopedia of Physical Chemistry and Chemical Physics, Volume 1: Equilibrium Statistical Mechanics covers the fundamental principles and the development of theoretical aspects of equilibrium statistical mechanics. Statistical mechanical is the study of the connection between the macroscopic behavior of bulk matter and the microscopic properties of its constituent atoms and molecules. This book contains eight chapters, and begins with a presentation of the master equation used for the calculation of the fundamental thermodynamic functions. The succeeding chapters highlight t

  11. Statistical mechanics in JINR

    International Nuclear Information System (INIS)

    Tonchev, N.; Shumovskij, A.S.

    1986-01-01

    The history of investigations, conducted at the JINR in the field of statistical mechanics, beginning with the fundamental works by Bogolyubov N.N. on superconductivity microscopic theory is presented. Ideas, introduced in these works and methods developed in them, have largely determined the ways for developing statistical mechanics in the JINR and Hartree-Fock-Bogolyubov variational principle has become an important method of the modern nucleus theory. A brief review of the main achievements, connected with the development of statistical mechanics methods and their application in different fields of physical science is given

  12. Statistical mechanics of superconductivity

    CERN Document Server

    Kita, Takafumi

    2015-01-01

    This book provides a theoretical, step-by-step comprehensive explanation of superconductivity for undergraduate and graduate students who have completed elementary courses on thermodynamics and quantum mechanics. To this end, it adopts the unique approach of starting with the statistical mechanics of quantum ideal gases and successively adding and clarifying elements and techniques indispensible for understanding it. They include the spin-statistics theorem, second quantization, density matrices, the Bloch–De Dominicis theorem, the variational principle in statistical mechanics, attractive interaction, and bound states. Ample examples of their usage are also provided in terms of topics from advanced statistical mechanics such as two-particle correlations of quantum ideal gases, derivation of the Hartree–Fock equations, and Landau’s Fermi-liquid theory, among others. With these preliminaries, the fundamental mean-field equations of superconductivity are derived with maximum mathematical clarity based on ...

  13. Playing at Statistical Mechanics

    Science.gov (United States)

    Clark, Paul M.; And Others

    1974-01-01

    Discussed are the applications of counting techniques of a sorting game to distributions and concepts in statistical mechanics. Included are the following distributions: Fermi-Dirac, Bose-Einstein, and most probable. (RH)

  14. Statistical mechanics rigorous results

    CERN Document Server

    Ruelle, David

    1999-01-01

    This classic book marks the beginning of an era of vigorous mathematical progress in equilibrium statistical mechanics. Its treatment of the infinite system limit has not been superseded, and the discussion of thermodynamic functions and states remains basic for more recent work. The conceptual foundation provided by the Rigorous Results remains invaluable for the study of the spectacular developments of statistical mechanics in the second half of the 20th century.

  15. Statistical formulation of gravitational radiation reaction

    International Nuclear Information System (INIS)

    Schutz, B.F.

    1980-01-01

    A new formulation of the radiation-reaction problem is proposed, which is simpler than alternatives which have been used before. The new approach is based on the initial-value problem, uses approximations which need be uniformly valid only in compact regions of space-time, and makes no time-asymmetric assumptions (no a priori introduction of retarded potentials or outgoing-wave asymptotic conditions). It defines radiation reaction to be the expected evolution of a source obtained by averaging over a statistical ensemble of initial conditions. The ensemble is chosen to reflect one's complete lack of information (in real systems) about the initial data for the radiation field. The approach is applied to the simple case of a weak-field, slow-motion source in general relativity, where it yields the usual expressions for radiation reaction when the gauge is chosen properly. There is a discussion of gauge freedom, and another of the necessity of taking into account reaction corrections to the particle-conservation equation. The analogy with the second law of thermodynamics is very close, and suggests that the electromagnetic and thermodynamic arrows of time are the same. Because the formulation is based on the usual initial-value problem, it has no spurious ''runaway'' solutions

  16. Statistical mechanics of anyons

    International Nuclear Information System (INIS)

    Arovas, D.P.

    1985-01-01

    We study the statistical mechanics of a two-dimensional gas of free anyons - particles which interpolate between Bose-Einstein and Fermi-Dirac character. Thermodynamic quantities are discussed in the low-density regime. In particular, the second virial coefficient is evaluated by two different methods and is found to exhibit a simple, periodic, but nonanalytic behavior as a function of the statistics determining parameter. (orig.)

  17. Einstein's statistical mechanics

    Energy Technology Data Exchange (ETDEWEB)

    Baracca, A; Rechtman S, R

    1985-08-01

    The foundation of equilibrium classical statistical mechanics were laid down in 1902 independently by Gibbs and Einstein. The latter's contribution, developed in three papers published between 1902 and 1904, is usually forgotten and when not, rapidly dismissed as equivalent to Gibb's. We review in detail Einstein's ideas on the foundations of statistical mechanics and show that they constitute the beginning of a research program that led Einstein to quantum theory. We also show how these ideas may be used as a starting point for an introductory course on the subject.

  18. Einstein's statistical mechanics

    International Nuclear Information System (INIS)

    Baracca, A.; Rechtman S, R.

    1985-01-01

    The foundation of equilibrium classical statistical mechanics were laid down in 1902 independently by Gibbs and Einstein. The latter's contribution, developed in three papers published between 1902 and 1904, is usually forgotten and when not, rapidly dismissed as equivalent to Gibb's. We review in detail Einstein's ideas on the foundations of statistical mechanics and show that they constitute the beginning of a research program that led Einstein to quantum theory. We also show how these ideas may be used as a starting point for an introductory course on the subject. (author)

  19. Statistical mechanics of solitons

    International Nuclear Information System (INIS)

    Bishop, A.

    1980-01-01

    The status of statistical mechanics theory (classical and quantum, statics and dynamics) is reviewed for 1-D soliton or solitary-wave-bearing systems. Primary attention is given to (i) perspective for existing results with evaluation and representative literature guide; (ii) motivation and status report for remaining problems; (iii) discussion of connections with other 1-D topics

  20. Wave Mechanics or Wave Statistical Mechanics

    International Nuclear Information System (INIS)

    Qian Shangwu; Xu Laizi

    2007-01-01

    By comparison between equations of motion of geometrical optics and that of classical statistical mechanics, this paper finds that there should be an analogy between geometrical optics and classical statistical mechanics instead of geometrical mechanics and classical mechanics. Furthermore, by comparison between the classical limit of quantum mechanics and classical statistical mechanics, it finds that classical limit of quantum mechanics is classical statistical mechanics not classical mechanics, hence it demonstrates that quantum mechanics is a natural generalization of classical statistical mechanics instead of classical mechanics. Thence quantum mechanics in its true appearance is a wave statistical mechanics instead of a wave mechanics.

  1. Journey Through Statistical Mechanics

    Science.gov (United States)

    Yang, C. N.

    2013-05-01

    My first involvement with statistical mechanics and the many body problem was when I was a student at The National Southwest Associated University in Kunming during the war. At that time Professor Wang Zhu-Xi had just come back from Cambridge, England, where he was a student of Fowler, and his thesis was on phase transitions, a hot topic at that time, and still a very hot topic today...

  2. Graphene Statistical Mechanics

    Science.gov (United States)

    Bowick, Mark; Kosmrlj, Andrej; Nelson, David; Sknepnek, Rastko

    2015-03-01

    Graphene provides an ideal system to test the statistical mechanics of thermally fluctuating elastic membranes. The high Young's modulus of graphene means that thermal fluctuations over even small length scales significantly stiffen the renormalized bending rigidity. We study the effect of thermal fluctuations on graphene ribbons of width W and length L, pinned at one end, via coarse-grained Molecular Dynamics simulations and compare with analytic predictions of the scaling of width-averaged root-mean-squared height fluctuations as a function of distance along the ribbon. Scaling collapse as a function of W and L also allows us to extract the scaling exponent eta governing the long-wavelength stiffening of the bending rigidity. A full understanding of the geometry-dependent mechanical properties of graphene, including arrays of cuts, may allow the design of a variety of modular elements with desired mechanical properties starting from pure graphene alone. Supported by NSF grant DMR-1435794

  3. Statistical mechanics of violent relaxation

    International Nuclear Information System (INIS)

    Shu, F.H.

    1978-01-01

    We reexamine the foundations of Lynden-Bell's statistical mechanical discussion of violent relaxation in collisionless stellar systems. We argue that Lynden-Bell's formulation in terms of a continuum description introduces unnecessary complications, and we consider a more conventional formulation in terms of particles. We then find the exclusion principle discovered by Lynden-Bell to be quantitatively important only at phase densities where two-body encounters are no longer negligible. Since the edynamical basis for the exclusion principle vanishes in such cases anyway, Lynden-Bell statistics always reduces in practice to Maxwell-Boltzmann statistics when applied to stellar systems. Lynden-Bell also found the equilibrium distribution function generally to be a sum of Maxwellians with velocity dispersions dependent on the phase density at star formation. We show that this difficulty vanishes in the particulate description for an encounterless stellar system as long as stars of different masses are initially well mixed in phase space. Our methods also demonstrate the equivalence between Gibbs's formalism which uses the microcanonical ensemble and Boltzmann's formalism which uses a coarse-grained continuum description. In addition, we clarify the concept of irreversible behavior on a macroscopic scale for an encounterless stellar system. Finally, we comment on the use of unusual macroscopic constraints to simulate the effects of incomplete relaxation

  4. Statistical mechanics and Lorentz violation

    International Nuclear Information System (INIS)

    Colladay, Don; McDonald, Patrick

    2004-01-01

    The theory of statistical mechanics is studied in the presence of Lorentz-violating background fields. The analysis is performed using the Standard-Model Extension (SME) together with a Jaynesian formulation of statistical inference. Conventional laws of thermodynamics are obtained in the presence of a perturbed hamiltonian that contains the Lorentz-violating terms. As an example, properties of the nonrelativistic ideal gas are calculated in detail. To lowest order in Lorentz violation, the scalar thermodynamic variables are only corrected by a rotationally invariant combination of parameters that mimics a (frame dependent) effective mass. Spin-couplings can induce a temperature-independent polarization in the classical gas that is not present in the conventional case. Precision measurements in the residual expectation values of the magnetic moment of Fermi gases in the limit of high temperature may provide interesting limits on these parameters

  5. Statistical crack mechanics

    International Nuclear Information System (INIS)

    Dienes, J.K.

    1993-01-01

    Although it is possible to simulate the ground blast from a single explosive shot with a simple computer algorithm and appropriate constants, the most commonly used modelling methods do not account for major changes in geology or shot energy because mechanical features such as tectonic stresses, fault structure, microcracking, brittle-ductile transition, and water content are not represented in significant detail. An alternative approach for modelling called Statistical Crack Mechanics is presented in this paper. This method, developed in the seventies as a part of the oil shale program, accounts for crack opening, shear, growth, and coalescence. Numerous photographs and micrographs show that shocked materials tend to involve arrays of planar cracks. The approach described here provides a way to account for microstructure and give a representation of the physical behavior of a material at the microscopic level that can account for phenomena such as permeability, fragmentation, shear banding, and hot-spot formation in explosives

  6. Topics in statistical mechanics

    International Nuclear Information System (INIS)

    Elser, V.

    1984-05-01

    This thesis deals with four independent topics in statistical mechanics: (1) the dimer problem is solved exactly for a hexagonal lattice with general boundary using a known generating function from the theory of partitions. It is shown that the leading term in the entropy depends on the shape of the boundary; (2) continuum models of percolation and self-avoiding walks are introduced with the property that their series expansions are sums over linear graphs with intrinsic combinatorial weights and explicit dimension dependence; (3) a constrained SOS model is used to describe the edge of a simple cubic crystal. Low and high temperature results are derived as well as the detailed behavior near the crystal facet; (4) the microscopic model of the lambda-transition involving atomic permutation cycles is reexamined. In particular, a new derivation of the two-component field theory model of the critical behavior is presented. Results for a lattice model originally proposed by Kikuchi are extended with a high temperature series expansion and Monte Carlo simulation. 30 references

  7. Statistical mechanics of nonequilibrium liquids

    CERN Document Server

    Evans, Denis J; Craig, D P; McWeeny, R

    1990-01-01

    Statistical Mechanics of Nonequilibrium Liquids deals with theoretical rheology. The book discusses nonlinear response of systems and outlines the statistical mechanical theory. In discussing the framework of nonequilibrium statistical mechanics, the book explains the derivation of a nonequilibrium analogue of the Gibbsian basis for equilibrium statistical mechanics. The book reviews the linear irreversible thermodynamics, the Liouville equation, and the Irving-Kirkwood procedure. The text then explains the Green-Kubo relations used in linear transport coefficients, the linear response theory,

  8. Statistical fluid mechanics

    CERN Document Server

    Monin, A S

    2007-01-01

    ""If ever a field needed a definitive book, it is the study of turbulence; if ever a book on turbulence could be called definitive, it is this book."" - ScienceWritten by two of Russia's most eminent and productive scientists in turbulence, oceanography, and atmospheric physics, this two-volume survey is renowned for its clarity as well as its comprehensive treatment. The first volume begins with an outline of laminar and turbulent flow. The remainder of the book treats a variety of aspects of turbulence: its statistical and Lagrangian descriptions, shear flows near surfaces and free turbulenc

  9. Statistical mechanics in a nutshell

    CERN Document Server

    Peliti, Luca

    2011-01-01

    Statistical mechanics is one of the most exciting areas of physics today, and it also has applications to subjects as diverse as economics, social behavior, algorithmic theory, and evolutionary biology. Statistical Mechanics in a Nutshell offers the most concise, self-contained introduction to this rapidly developing field. Requiring only a background in elementary calculus and elementary mechanics, this book starts with the basics, introduces the most important developments in classical statistical mechanics over the last thirty years, and guides readers to the very threshold of today

  10. The large deviation approach to statistical mechanics

    International Nuclear Information System (INIS)

    Touchette, Hugo

    2009-01-01

    The theory of large deviations is concerned with the exponential decay of probabilities of large fluctuations in random systems. These probabilities are important in many fields of study, including statistics, finance, and engineering, as they often yield valuable information about the large fluctuations of a random system around its most probable state or trajectory. In the context of equilibrium statistical mechanics, the theory of large deviations provides exponential-order estimates of probabilities that refine and generalize Einstein's theory of fluctuations. This review explores this and other connections between large deviation theory and statistical mechanics, in an effort to show that the mathematical language of statistical mechanics is the language of large deviation theory. The first part of the review presents the basics of large deviation theory, and works out many of its classical applications related to sums of random variables and Markov processes. The second part goes through many problems and results of statistical mechanics, and shows how these can be formulated and derived within the context of large deviation theory. The problems and results treated cover a wide range of physical systems, including equilibrium many-particle systems, noise-perturbed dynamics, nonequilibrium systems, as well as multifractals, disordered systems, and chaotic systems. This review also covers many fundamental aspects of statistical mechanics, such as the derivation of variational principles characterizing equilibrium and nonequilibrium states, the breaking of the Legendre transform for nonconcave entropies, and the characterization of nonequilibrium fluctuations through fluctuation relations.

  11. The large deviation approach to statistical mechanics

    Science.gov (United States)

    Touchette, Hugo

    2009-07-01

    The theory of large deviations is concerned with the exponential decay of probabilities of large fluctuations in random systems. These probabilities are important in many fields of study, including statistics, finance, and engineering, as they often yield valuable information about the large fluctuations of a random system around its most probable state or trajectory. In the context of equilibrium statistical mechanics, the theory of large deviations provides exponential-order estimates of probabilities that refine and generalize Einstein’s theory of fluctuations. This review explores this and other connections between large deviation theory and statistical mechanics, in an effort to show that the mathematical language of statistical mechanics is the language of large deviation theory. The first part of the review presents the basics of large deviation theory, and works out many of its classical applications related to sums of random variables and Markov processes. The second part goes through many problems and results of statistical mechanics, and shows how these can be formulated and derived within the context of large deviation theory. The problems and results treated cover a wide range of physical systems, including equilibrium many-particle systems, noise-perturbed dynamics, nonequilibrium systems, as well as multifractals, disordered systems, and chaotic systems. This review also covers many fundamental aspects of statistical mechanics, such as the derivation of variational principles characterizing equilibrium and nonequilibrium states, the breaking of the Legendre transform for nonconcave entropies, and the characterization of nonequilibrium fluctuations through fluctuation relations.

  12. Nonextensive statistical mechanics of ionic solutions

    International Nuclear Information System (INIS)

    Varela, L.M.; Carrete, J.; Munoz-Sola, R.; Rodriguez, J.R.; Gallego, J.

    2007-01-01

    Classical mean-field Poisson-Boltzmann theory of ionic solutions is revisited in the theoretical framework of nonextensive Tsallis statistics. The nonextensive equivalent of Poisson-Boltzmann equation is formulated revisiting the statistical mechanics of liquids and the Debye-Hueckel framework is shown to be valid for highly diluted solutions even under circumstances where nonextensive thermostatistics must be applied. The lowest order corrections associated to nonadditive effects are identified for both symmetric and asymmetric electrolytes and the behavior of the average electrostatic potential in a homogeneous system is analytically and numerically analyzed for various values of the complexity measurement nonextensive parameter q

  13. Introduction to quantum statistical mechanics

    International Nuclear Information System (INIS)

    Bogolyubov, N.N.; Bogolyubov, N.N.

    1980-01-01

    In a set of lectures, which has been delivered at the Physical Department of Moscow State University as a special course for students represented are some basic ideas of quantum statistical mechanics. Considered are in particular, the Liouville equations in classical and quantum mechanics, canonical distribution and thermodynamical functions, two-time correlation functions and Green's functions in the theory of thermal equilibrium

  14. What is Quantum Mechanics? A Minimal Formulation

    Science.gov (United States)

    Friedberg, R.; Hohenberg, P. C.

    2018-03-01

    This paper presents a minimal formulation of nonrelativistic quantum mechanics, by which is meant a formulation which describes the theory in a succinct, self-contained, clear, unambiguous and of course correct manner. The bulk of the presentation is the so-called "microscopic theory", applicable to any closed system S of arbitrary size N, using concepts referring to S alone, without resort to external apparatus or external agents. An example of a similar minimal microscopic theory is the standard formulation of classical mechanics, which serves as the template for a minimal quantum theory. The only substantive assumption required is the replacement of the classical Euclidean phase space by Hilbert space in the quantum case, with the attendant all-important phenomenon of quantum incompatibility. Two fundamental theorems of Hilbert space, the Kochen-Specker-Bell theorem and Gleason's theorem, then lead inevitably to the well-known Born probability rule. For both classical and quantum mechanics, questions of physical implementation and experimental verification of the predictions of the theories are the domain of the macroscopic theory, which is argued to be a special case or application of the more general microscopic theory.

  15. Renyi statistics in equilibrium statistical mechanics

    International Nuclear Information System (INIS)

    Parvan, A.S.; Biro, T.S.

    2010-01-01

    The Renyi statistics in the canonical and microcanonical ensembles is examined both in general and in particular for the ideal gas. In the microcanonical ensemble the Renyi statistics is equivalent to the Boltzmann-Gibbs statistics. By the exact analytical results for the ideal gas, it is shown that in the canonical ensemble, taking the thermodynamic limit, the Renyi statistics is also equivalent to the Boltzmann-Gibbs statistics. Furthermore it satisfies the requirements of the equilibrium thermodynamics, i.e. the thermodynamical potential of the statistical ensemble is a homogeneous function of first degree of its extensive variables of state. We conclude that the Renyi statistics arrives at the same thermodynamical relations, as those stemming from the Boltzmann-Gibbs statistics in this limit.

  16. Quantum mechanics from classical statistics

    International Nuclear Information System (INIS)

    Wetterich, C.

    2010-01-01

    Quantum mechanics can emerge from classical statistics. A typical quantum system describes an isolated subsystem of a classical statistical ensemble with infinitely many classical states. The state of this subsystem can be characterized by only a few probabilistic observables. Their expectation values define a density matrix if they obey a 'purity constraint'. Then all the usual laws of quantum mechanics follow, including Heisenberg's uncertainty relation, entanglement and a violation of Bell's inequalities. No concepts beyond classical statistics are needed for quantum physics - the differences are only apparent and result from the particularities of those classical statistical systems which admit a quantum mechanical description. Born's rule for quantum mechanical probabilities follows from the probability concept for a classical statistical ensemble. In particular, we show how the non-commuting properties of quantum operators are associated to the use of conditional probabilities within the classical system, and how a unitary time evolution reflects the isolation of the subsystem. As an illustration, we discuss a classical statistical implementation of a quantum computer.

  17. Modern Thermodynamics with Statistical Mechanics

    CERN Document Server

    Helrich, Carl S

    2009-01-01

    With the aim of presenting thermodynamics in as simple and as unified a form as possible, this textbook starts with an introduction to the first and second laws and then promptly addresses the complete set of the potentials in a subsequent chapter and as a central theme throughout. Before discussing modern laboratory measurements, the book shows that the fundamental quantities sought in the laboratory are those which are required for determining the potentials. Since the subjects of thermodynamics and statistical mechanics are a seamless whole, statistical mechanics is treated as integral part of the text. Other key topics such as irreversibility, the ideas of Ilya Prigogine, chemical reaction rates, equilibrium of heterogeneous systems, and transition-state theory serve to round out this modern treatment. An additional chapter covers quantum statistical mechanics due to active current research in Bose-Einstein condensation. End-of-chapter exercises, chapter summaries, and an appendix reviewing fundamental pr...

  18. Statistical ensembles in quantum mechanics

    International Nuclear Information System (INIS)

    Blokhintsev, D.

    1976-01-01

    The interpretation of quantum mechanics presented in this paper is based on the concept of quantum ensembles. This concept differs essentially from the canonical one by that the interference of the observer into the state of a microscopic system is of no greater importance than in any other field of physics. Owing to this fact, the laws established by quantum mechanics are not of less objective character than the laws governing classical statistical mechanics. The paradoxical nature of some statements of quantum mechanics which result from the interpretation of the wave functions as the observer's notebook greatly stimulated the development of the idea presented. (Auth.)

  19. Random path formulation of nonrelativistic quantum mechanics

    International Nuclear Information System (INIS)

    Roncadelli, M.

    1993-01-01

    Quantum amplitudes satisfy (almost) the same calculus that probabilities obey in the theory of classical stochastic diffusion processes. As a consequence of this structural analogy, a new formulation of (nonrelativistic) quantum mechanics naturally arises as the quantum counterpart of the Langevin description of (classical) stochastic diffusion processes. Quantum fluctuations are simulated here by a Fresnel white noise (FWN), which is a (real) white noise with imaginary diffusion constant, whose functional (pseudo) measure yields the amplitude distribution for its configurations. Central to this approach is the idea that classical dynamical trajectories in configuration space are perturbed by the FWN. Hence, a single (arbitrary) classical dynamical path gets replaced by a family of quantum random paths (QRPs) - one for each FWN sample - all originating from the same space-time point (x', t'). The QRPs are the basic objects of the present formulation and are given by a Langevin equation with the FWN, whose drift is controlled by a (arbitrary) solution to the classical Hamilton-Jacobi equation. So, our approach is manifestly based on classical dynamics. Now, a transition amplitude is associated with each QRP: it gives the amplitude that a particle starting from (x', t') will reach (x'', t'') by travelling just along the considered QRP. The quantum mechanical propagator (x'', t'' modul x', t') then emerges as the FWN average of the transition amplitude along a QRP. Thus, quantum mechanics looks like classical mechanics as perturbed by the FWN. The general structure of this formulation is discussed in detail, along with some practical and conceptual implications. (author). 14 refs

  20. Statistical mechanics of multipartite entanglement

    Science.gov (United States)

    Facchi, P.; Florio, G.; Marzolino, U.; Parisi, G.; Pascazio, S.

    2009-02-01

    We characterize the multipartite entanglement of a system of n qubits in terms of the distribution function of the bipartite purity over all balanced bipartitions. We search for those (maximally multipartite entangled) states whose purity is minimum for all bipartitions and recast this optimization problem into a problem of statistical mechanics.

  1. Statistical mechanics of multipartite entanglement

    Energy Technology Data Exchange (ETDEWEB)

    Facchi, P [Dipartimento di Matematica, Universita di Bari, I-70125 Bari (Italy); Florio, G; Pascazio, S [Istituto Nazionale di Fisica Nucleare, Sezione di Bari, I-70126 Bari (Italy); Marzolino, U [Dipartimento di Fisica Teorica, Universita di Trieste, Strada Costiera 11, 34014 Trieste (Italy); Parisi, G [Dipartimento di Fisica, Universita di Roma ' La Sapienza' , Piazzale Aldo Moro 2, 00185 Roma, Italy, Centre for Statistical Mechanics and Complexity (SMC), CNR-INFM, 00185 Roma (Italy)

    2009-02-06

    We characterize the multipartite entanglement of a system of n qubits in terms of the distribution function of the bipartite purity over all balanced bipartitions. We search for those (maximally multipartite entangled) states whose purity is minimum for all bipartitions and recast this optimization problem into a problem of statistical mechanics.

  2. Statistical mechanics of multipartite entanglement

    International Nuclear Information System (INIS)

    Facchi, P; Florio, G; Pascazio, S; Marzolino, U; Parisi, G

    2009-01-01

    We characterize the multipartite entanglement of a system of n qubits in terms of the distribution function of the bipartite purity over all balanced bipartitions. We search for those (maximally multipartite entangled) states whose purity is minimum for all bipartitions and recast this optimization problem into a problem of statistical mechanics

  3. Zeno dynamics in quantum statistical mechanics

    International Nuclear Information System (INIS)

    Schmidt, Andreas U

    2003-01-01

    We study the quantum Zeno effect in quantum statistical mechanics within the operator algebraic framework. We formulate a condition for the appearance of the effect in W*-dynamical systems, in terms of the short-time behaviour of the dynamics. Examples of quantum spin systems show that this condition can be effectively applied to quantum statistical mechanical models. Furthermore, we derive an explicit form of the Zeno generator, and use it to construct Gibbs equilibrium states for the Zeno dynamics. As a concrete example, we consider the X-Y model, for which we show that a frequent measurement at a microscopic level, e.g. a single lattice site, can produce a macroscopic effect in changing the global equilibrium

  4. Statistical Mechanics of Prion Diseases

    International Nuclear Information System (INIS)

    Slepoy, A.; Singh, R. R. P.; Pazmandi, F.; Kulkarni, R. V.; Cox, D. L.

    2001-01-01

    We present a two-dimensional, lattice based, protein-level statistical mechanical model for prion diseases (e.g., mad cow disease) with concomitant prion protein misfolding and aggregation. Our studies lead us to the hypothesis that the observed broad incubation time distribution in epidemiological data reflect fluctuation dominated growth seeded by a few nanometer scale aggregates, while much narrower incubation time distributions for innoculated lab animals arise from statistical self-averaging. We model ''species barriers'' to prion infection and assess a related treatment protocol

  5. Statistical mechanics of black holes

    International Nuclear Information System (INIS)

    Harms, B.; Leblanc, Y.

    1992-01-01

    We analyze the statistical mechanics of a gas of neutral and charged black holes. The microcanonical ensemble is the only possible approach to this system, and the equilibrium configuration is the one for which most of the energy is carried by a single black hole. Schwarzschild black holes are found to obey the statistical bootstrap condition. In all cases, the microcanonical temperature is identical to the Hawking temperature of the most massive black hole in the gas. U(1) charges in general break the bootstrap property. The problems of black-hole decay and of quantum coherence are also addressed

  6. Quantum field theory and statistical mechanics

    International Nuclear Information System (INIS)

    Jegerlehner, F.

    1975-01-01

    At first a heuristic understanding is given how the relation between quantum field theory and statistical mechanics near phase transitions comes about. A long range scale invariant theory is constructed, critical indices are calculated and the relations among them are proved, field theoretical Kadanoff-scale transformations are formulated and scaling corrections calculated. A precise meaning to many of Kadanoffs considerations and a model matching Wegners phenomenological scheme is given. It is shown, that soft parametrization is most transparent for the discussion of scaling behaviour. (BJ) [de

  7. Nonequilibrium statistical mechanics ensemble method

    CERN Document Server

    Eu, Byung Chan

    1998-01-01

    In this monograph, nonequilibrium statistical mechanics is developed by means of ensemble methods on the basis of the Boltzmann equation, the generic Boltzmann equations for classical and quantum dilute gases, and a generalised Boltzmann equation for dense simple fluids The theories are developed in forms parallel with the equilibrium Gibbs ensemble theory in a way fully consistent with the laws of thermodynamics The generalised hydrodynamics equations are the integral part of the theory and describe the evolution of macroscopic processes in accordance with the laws of thermodynamics of systems far removed from equilibrium Audience This book will be of interest to researchers in the fields of statistical mechanics, condensed matter physics, gas dynamics, fluid dynamics, rheology, irreversible thermodynamics and nonequilibrium phenomena

  8. Statistical mechanics of complex networks

    CERN Document Server

    Rubi, Miguel; Diaz-Guilera, Albert

    2003-01-01

    Networks can provide a useful model and graphic image useful for the description of a wide variety of web-like structures in the physical and man-made realms, e.g. protein networks, food webs and the Internet. The contributions gathered in the present volume provide both an introduction to, and an overview of, the multifaceted phenomenology of complex networks. Statistical Mechanics of Complex Networks also provides a state-of-the-art picture of current theoretical methods and approaches.

  9. Critical examination of logical formulations in quantum theory. Statistical inference and Hilbertian distance between quantum states

    International Nuclear Information System (INIS)

    Hadjisawas, Nicolas.

    1982-01-01

    After a critical study of the logical quantum mechanics formulations of Jauch and Piron, classical and quantum versions of statistical inference are studied. In order to do this, the significance of the Jaynes and Kulback principles (maximum likelihood, least squares principles) is revealed from the theorems established. In the quantum mechanics inference problem, a ''distance'' between states is defined. This concept is used to solve the quantum equivalent of the classical problem studied by Kulback. The ''projection postulate'' proposition is subsequently deduced [fr

  10. Statistical mechanics of economics I

    Energy Technology Data Exchange (ETDEWEB)

    Kusmartsev, F.V., E-mail: F.Kusmartsev@lboro.ac.u [Department of Physics, Loughborough University, Leicestershire, LE11 3TU (United Kingdom)

    2011-02-07

    We show that statistical mechanics is useful in the description of financial crisis and economics. Taking a large amount of instant snapshots of a market over an interval of time we construct their ensembles and study their statistical interference. This results in a probability description of the market and gives capital, money, income, wealth and debt distributions, which in the most cases takes the form of the Bose-Einstein distribution. In addition, statistical mechanics provides the main market equations and laws which govern the correlations between the amount of money, debt, product, prices and number of retailers. We applied the found relations to a study of the evolution of the economics in USA between the years 1996 to 2008 and observe that over that time the income of a major population is well described by the Bose-Einstein distribution which parameters are different for each year. Each financial crisis corresponds to a peak in the absolute activity coefficient. The analysis correctly indicates the past crises and predicts the future one.

  11. Statistical mechanics of economics I

    International Nuclear Information System (INIS)

    Kusmartsev, F.V.

    2011-01-01

    We show that statistical mechanics is useful in the description of financial crisis and economics. Taking a large amount of instant snapshots of a market over an interval of time we construct their ensembles and study their statistical interference. This results in a probability description of the market and gives capital, money, income, wealth and debt distributions, which in the most cases takes the form of the Bose-Einstein distribution. In addition, statistical mechanics provides the main market equations and laws which govern the correlations between the amount of money, debt, product, prices and number of retailers. We applied the found relations to a study of the evolution of the economics in USA between the years 1996 to 2008 and observe that over that time the income of a major population is well described by the Bose-Einstein distribution which parameters are different for each year. Each financial crisis corresponds to a peak in the absolute activity coefficient. The analysis correctly indicates the past crises and predicts the future one.

  12. Statistical mechanics of cellular automata

    International Nuclear Information System (INIS)

    Wolfram, S.

    1983-01-01

    Cellular automata are used as simple mathematical models to investigate self-organization in statistical mechanics. A detailed analysis is given of ''elementary'' cellular automata consisting of a sequence of sites with values 0 or 1 on a line, with each site evolving deterministically in discrete time steps according to p definite rules involving the values of its nearest neighbors. With simple initial configurations, the cellular automata either tend to homogeneous states, or generate self-similar patterns with fractal dimensions approx. =1.59 or approx. =1.69. With ''random'' initial configurations, the irreversible character of the cellular automaton evolution leads to several self-organization phenomena. Statistical properties of the structures generated are found to lie in two universality classes, independent of the details of the initial state or the cellular automaton rules. More complicated cellular automata are briefly considered, and connections with dynamical systems theory and the formal theory of computation are discussed

  13. Statistical mechanics and field theory

    International Nuclear Information System (INIS)

    Samuel, S.A.

    1979-05-01

    Field theory methods are applied to statistical mechanics. Statistical systems are related to fermionic-like field theories through a path integral representation. Considered are the Ising model, the free-fermion model, and close-packed dimer problems on various lattices. Graphical calculational techniques are developed. They are powerful and yield a simple procedure to compute the vacuum expectation value of an arbitrary product of Ising spin variables. From a field theorist's point of view, this is the simplest most logical derivation of the Ising model partition function and correlation functions. This work promises to open a new area of physics research when the methods are used to approximate unsolved problems. By the above methods a new model named the 128 pseudo-free vertex model is solved. Statistical mechanics intuition is applied to field theories. It is shown that certain relativistic field theories are equivalent to classical interacting gases. Using this analogy many results are obtained, particularly for the Sine-Gordon field theory. Quark confinement is considered. Although not a proof of confinement, a logical, esthetic, and simple picture is presented of how confinement works. A key ingredient is the insight gained by using an analog statistical system consisting of a gas of macromolecules. This analogy allows the computation of Wilson loops in the presence of topological vortices and when symmetry breakdown occurs in the topological quantum number. Topological symmetry breakdown calculations are placed on approximately the same level of rigor as instanton calculations. The picture of confinement that emerges is similar to the dual Meissner type advocated by Mandelstam. Before topological symmetry breakdown, QCD has monopoles bound linearly together by three topological strings. Topological symmetry breakdown corresponds to a new phase where these monopoles are liberated. It is these liberated monopoles that confine quarks. 64 references

  14. Introduction to quantum statistical mechanics

    CERN Document Server

    Bogolyubov, N N

    2010-01-01

    Introduction to Quantum Statistical Mechanics (Second Edition) may be used as an advanced textbook by graduate students, even ambitious undergraduates in physics. It is also suitable for non experts in physics who wish to have an overview of some of the classic and fundamental quantum models in the subject. The explanation in the book is detailed enough to capture the interest of the reader, and complete enough to provide the necessary background material needed to dwell further into the subject and explore the research literature.

  15. Annotations to quantum statistical mechanics

    CERN Document Server

    Kim, In-Gee

    2018-01-01

    This book is a rewritten and annotated version of Leo P. Kadanoff and Gordon Baym’s lectures that were presented in the book Quantum Statistical Mechanics: Green’s Function Methods in Equilibrium and Nonequilibrium Problems. The lectures were devoted to a discussion on the use of thermodynamic Green’s functions in describing the properties of many-particle systems. The functions provided a method for discussing finite-temperature problems with no more conceptual difficulty than ground-state problems, and the method was equally applicable to boson and fermion systems and equilibrium and nonequilibrium problems. The lectures also explained nonequilibrium statistical physics in a systematic way and contained essential concepts on statistical physics in terms of Green’s functions with sufficient and rigorous details. In-Gee Kim thoroughly studied the lectures during one of his research projects but found that the unspecialized method used to present them in the form of a book reduced their readability. He st...

  16. Statistical mechanics of program systems

    International Nuclear Information System (INIS)

    Neirotti, Juan P; Caticha, Nestor

    2006-01-01

    We discuss the collective behaviour of a set of operators and variables that constitute a program and the emergence of meaningful computational properties in the language of statistical mechanics. This is done by appropriately modifying available Monte Carlo methods to deal with hierarchical structures. The study suggests, in analogy with simulated annealing, a method to automatically design programs. Reasonable solutions can be found, at low temperatures, when the method is applied to simple toy problems such as finding an algorithm that determines the roots of a function or one that makes a nonlinear regression. Peaks in the specific heat are interpreted as signalling phase transitions which separate regions where different algorithmic strategies are used to solve the problem

  17. To a causal formulation of quantum mechanics

    International Nuclear Information System (INIS)

    Brody, T.A.; Cetto, A.M.; Pena, L. de la

    1979-01-01

    This paper consists of two parts. In the first one we analyze the elements that a theory of quantum mechanics (QM) must contain in order to provide a physical explanation of the most notable quantum features (random behaviour, wave-particle duality, discrete spectra). We conclude that the theory that possesses the qualitative elements required is stochastic electrodynamics (SED), according to which the quantum behavior of the electron arises from its interaction with the stochastic electromagnetic background fiel associated with the zero-point energy. In the second part we show that the postulates of SED are suitable for the construction of a theory of the motion of the electron from which QM may be derived as an approximate description; hence, the mathematical formalism of QM too is justified by SED. Thus, the present theory generalizes QM and moreover, provides an objective statistical interpretation of it. (author)

  18. Statistical Mechanics of Turbulent Flows

    International Nuclear Information System (INIS)

    Cambon, C

    2004-01-01

    This is a handbook for a computational approach to reacting flows, including background material on statistical mechanics. In this sense, the title is somewhat misleading with respect to other books dedicated to the statistical theory of turbulence (e.g. Monin and Yaglom). In the present book, emphasis is placed on modelling (engineering closures) for computational fluid dynamics. The probabilistic (pdf) approach is applied to the local scalar field, motivated first by the nonlinearity of chemical source terms which appear in the transport equations of reacting species. The probabilistic and stochastic approaches are also used for the velocity field and particle position; nevertheless they are essentially limited to Lagrangian models for a local vector, with only single-point statistics, as for the scalar. Accordingly, conventional techniques, such as single-point closures for RANS (Reynolds-averaged Navier-Stokes) and subgrid-scale models for LES (large-eddy simulations), are described and in some cases reformulated using underlying Langevin models and filtered pdfs. Even if the theoretical approach to turbulence is not discussed in general, the essentials of probabilistic and stochastic-processes methods are described, with a useful reminder concerning statistics at the molecular level. The book comprises 7 chapters. Chapter 1 briefly states the goals and contents, with a very clear synoptic scheme on page 2. Chapter 2 presents definitions and examples of pdfs and related statistical moments. Chapter 3 deals with stochastic processes, pdf transport equations, from Kramer-Moyal to Fokker-Planck (for Markov processes), and moments equations. Stochastic differential equations are introduced and their relationship to pdfs described. This chapter ends with a discussion of stochastic modelling. The equations of fluid mechanics and thermodynamics are addressed in chapter 4. Classical conservation equations (mass, velocity, internal energy) are derived from their

  19. Statistical Mechanics of Turbulent Dynamos

    Science.gov (United States)

    Shebalin, John V.

    2014-01-01

    Incompressible magnetohydrodynamic (MHD) turbulence and magnetic dynamos, which occur in magnetofluids with large fluid and magnetic Reynolds numbers, will be discussed. When Reynolds numbers are large and energy decays slowly, the distribution of energy with respect to length scale becomes quasi-stationary and MHD turbulence can be described statistically. In the limit of infinite Reynolds numbers, viscosity and resistivity become zero and if these values are used in the MHD equations ab initio, a model system called ideal MHD turbulence results. This model system is typically confined in simple geometries with some form of homogeneous boundary conditions, allowing for velocity and magnetic field to be represented by orthogonal function expansions. One advantage to this is that the coefficients of the expansions form a set of nonlinearly interacting variables whose behavior can be described by equilibrium statistical mechanics, i.e., by a canonical ensemble theory based on the global invariants (energy, cross helicity and magnetic helicity) of ideal MHD turbulence. Another advantage is that truncated expansions provide a finite dynamical system whose time evolution can be numerically simulated to test the predictions of the associated statistical mechanics. If ensemble predictions are the same as time averages, then the system is said to be ergodic; if not, the system is nonergodic. Although it had been implicitly assumed in the early days of ideal MHD statistical theory development that these finite dynamical systems were ergodic, numerical simulations provided sufficient evidence that they were, in fact, nonergodic. Specifically, while canonical ensemble theory predicted that expansion coefficients would be (i) zero-mean random variables with (ii) energy that decreased with length scale, it was found that although (ii) was correct, (i) was not and the expected ergodicity was broken. The exact cause of this broken ergodicity was explained, after much

  20. Current algebra, statistical mechanics and quantum models

    Science.gov (United States)

    Vilela Mendes, R.

    2017-11-01

    Results obtained in the past for free boson systems at zero and nonzero temperatures are revisited to clarify the physical meaning of current algebra reducible functionals which are associated to systems with density fluctuations, leading to observable effects on phase transitions. To use current algebra as a tool for the formulation of quantum statistical mechanics amounts to the construction of unitary representations of diffeomorphism groups. Two mathematical equivalent procedures exist for this purpose. One searches for quasi-invariant measures on configuration spaces, the other for a cyclic vector in Hilbert space. Here, one argues that the second approach is closer to the physical intuition when modelling complex systems. An example of application of the current algebra methodology to the pairing phenomenon in two-dimensional fermion systems is discussed.

  1. Mechanical properties of bioactive glass putty formulations

    NARCIS (Netherlands)

    van Gestel, N.A.P.; Geurts, J.A.P.; Hulsen, D.J.W.; Hofmann, S.; Ito, K.; van Rietbergen, B.; Arts, J.J.C.

    2016-01-01

    Introduction: Bioactive glass (BAG) has been studied widely and seems to be a very promising biomaterial in regeneration of large bone defects and osteomyelitis treatment, because of its bone bonding and antibacterial properties[1]-[5]. Its high stiffness could potentially also enable mechanical

  2. Quantum mechanics as applied mathematical statistics

    International Nuclear Information System (INIS)

    Skala, L.; Cizek, J.; Kapsa, V.

    2011-01-01

    Basic mathematical apparatus of quantum mechanics like the wave function, probability density, probability density current, coordinate and momentum operators, corresponding commutation relation, Schroedinger equation, kinetic energy, uncertainty relations and continuity equation is discussed from the point of view of mathematical statistics. It is shown that the basic structure of quantum mechanics can be understood as generalization of classical mechanics in which the statistical character of results of measurement of the coordinate and momentum is taken into account and the most important general properties of statistical theories are correctly respected.

  3. Statistical mechanics principles and selected applications

    CERN Document Server

    Hill, Terrell L

    1956-01-01

    ""Excellent … a welcome addition to the literature on the subject."" - ScienceBefore the publication of this standard, oft-cited book, there were few if any statistical-mechanics texts that incorporated reviews of both fundamental principles and recent developments in the field.In this volume, Professor Hill offers just such a dual presentation - a useful account of basic theory and of its applications, made accessible in a comprehensive format. The book opens with concise, unusually clear introductory chapters on classical statistical mechanics, quantum statistical mechanics and the relatio

  4. Thermalized solutions, statistical mechanics and turbulence

    Indian Academy of Sciences (India)

    2015-02-20

    Feb 20, 2015 ... In this study, we examine the intriguing connection between turbulence and equilibrium statistical mechanics. There are several recent works which emphasize this connection. Thus in the last ... Current Issue : Vol. 90, Issue 6.

  5. Science Academies' Refresher Course in Statistical Mechanics

    Indian Academy of Sciences (India)

    2018-02-27

    Feb 27, 2018 ... Post Graduate and Research Department of Physics. Bishop Moore ... The Course will cover the basic and advanced topics of Statistical. Mechanics ... Courses of good standing for promotion, vide notification. F3-1/2009 ...

  6. Is there a statistical mechanics of turbulence?

    International Nuclear Information System (INIS)

    Kraichnan, R.H.; Chen, S.Y.

    1988-09-01

    The statistical-mechanical treatment of turbulence is made questionable by strong nonlinearity and strong disequilibrium that result in the creation of ordered structures imbedded in disorder. Model systems are described which may provide some hope that a compact, yet faithful, statistical description of turbulence nevertheless is possible. Some essential dynamic features of the models are captured by low-order statistical approximations despite strongly non-Gaussian behavior. 31 refs., 5 figs

  7. Projection operator techniques in nonequilibrium statistical mechanics

    International Nuclear Information System (INIS)

    Grabert, H.

    1982-01-01

    This book is an introduction to the application of the projection operator technique to the statistical mechanics of irreversible processes. After a general introduction to the projection operator technique and statistical thermodynamics the Fokker-Planck and the master equation approach are described together with the response theory. Then, as applications the damped harmonic oscillator, simple fluids, and the spin relaxation are considered. (HSI)

  8. Significance of Strain in Formulation in Theory of Solid Mechanics

    Science.gov (United States)

    Patnaik, Surya N.; Coroneos, Rula M.; Hopkins, Dale A.

    2003-01-01

    The basic theory of solid mechanics was deemed complete circa 1860 when St. Venant provided the strain formulation or the field compatibility condition. The strain formulation was incomplete. The missing portion has been formulated and identified as the boundary compatibility condition (BCC). The BCC, derived through a variational formulation, has been verified through integral theorem and solution of problems. The BCC, unlike the field counterpart, do not trivialize when expressed in displacements. Navier s method and the stiffness formulation have to account for the extra conditions especially at the inter-element boundaries in a finite element model. Completion of the strain formulation has led to the revival of the direct force calculation methods: the Integrated Force Method (IFM) and its dual (IFMD) for finite element analysis, and the completed Beltrami-Michell formulation (CBMF) in elasticity. The benefits from the new methods in elasticity, in finite element analysis, and in design optimization are discussed. Existing solutions and computer codes may have to be adjusted for the compliance of the new conditions. Complacency because the discipline is over a century old and computer codes have been developed for half a century can lead to stagnation of the discipline.

  9. The Dirac equation in classical statistical mechanics

    International Nuclear Information System (INIS)

    Ord, G.N.

    2002-01-01

    The Dirac equation, usually obtained by 'quantizing' a classical stochastic model is here obtained directly within classical statistical mechanics. The special underlying space-time geometry of the random walk replaces the missing analytic continuation, making the model 'self-quantizing'. This provides a new context for the Dirac equation, distinct from its usual context in relativistic quantum mechanics

  10. Emergence of quantum mechanics from classical statistics

    International Nuclear Information System (INIS)

    Wetterich, C

    2009-01-01

    The conceptual setting of quantum mechanics is subject to an ongoing debate from its beginnings until now. The consequences of the apparent differences between quantum statistics and classical statistics range from the philosophical interpretations to practical issues as quantum computing. In this note we demonstrate how quantum mechanics can emerge from classical statistical systems. We discuss conditions and circumstances for this to happen. Quantum systems describe isolated subsystems of classical statistical systems with infinitely many states. While infinitely many classical observables 'measure' properties of the subsystem and its environment, the state of the subsystem can be characterized by the expectation values of only a few probabilistic observables. They define a density matrix, and all the usual laws of quantum mechanics follow. No concepts beyond classical statistics are needed for quantum physics - the differences are only apparent and result from the particularities of those classical statistical systems which admit a quantum mechanical description. In particular, we show how the non-commuting properties of quantum operators are associated to the use of conditional probabilities within the classical system, and how a unitary time evolution reflects the isolation of the subsystem.

  11. Algebraic methods in statistical mechanics and quantum field theory

    CERN Document Server

    Emch, Dr Gérard G

    2009-01-01

    This systematic algebraic approach concerns problems involving a large number of degrees of freedom. It extends the traditional formalism of quantum mechanics, and it eliminates conceptual and mathematical difficulties common to the development of statistical mechanics and quantum field theory. Further, the approach is linked to research in applied and pure mathematics, offering a reflection of the interplay between formulation of physical motivations and self-contained descriptions of the mathematical methods.The four-part treatment begins with a survey of algebraic approaches to certain phys

  12. Some connections between relativistic classical mechanics, statistical mechanics, and quantum field theory

    International Nuclear Information System (INIS)

    Remler, E.A.

    1977-01-01

    A gauge-invariant version of the Wigner representation is used to relate relativistic mechanics, statistical mechanics, and quantum field theory in the context of the electrodynamics of scalar particles. A unified formulation of quantum field theory and statistical mechanics is developed which clarifies the physics interpretation of the single-particle Wigner function. A covariant form of Ehrenfest's theorem is derived. Classical electrodynamics is derived from quantum field theory after making a random-phase approximation. The validity of this approximation is discussed

  13. An introduction to thermodynamics and statistical mechanics

    CERN Document Server

    Saxena, A K

    2016-01-01

    An Introduction to Thermodynamics and Statistical Mechanics aims to serve as a text book for undergraduate hons.and postgraduate students of physics. The book covers First Law of Thermodynamics, Entropy and Second Law ofThermodynamics, Thermodynamic Relations, The Statistical Basis of Thermodynamics, Microcanonical Ensemble,Classical Statistical and Canonical Distribution, Grand Canonical Ensemble, Quantum Statistical Mechanics, PhaseTransitions, Fluctuations, Irreversible Processes and Transport Phenomena (Diffusion).SALIENT FEATURES:iC* Offers students a conceptual development of the subjectiC* Review questions at the end of chapters.NEW TO THE SECOND EDITIONiC* PVT SurfacesiC* Real Heat EnginesiC* Van der Waals Models (Qualitative Considerations)iC* Cluster ExpansioniC* Brownian Motion (Einstein's Theory)

  14. Learning Predictive Statistics: Strategies and Brain Mechanisms.

    Science.gov (United States)

    Wang, Rui; Shen, Yuan; Tino, Peter; Welchman, Andrew E; Kourtzi, Zoe

    2017-08-30

    When immersed in a new environment, we are challenged to decipher initially incomprehensible streams of sensory information. However, quite rapidly, the brain finds structure and meaning in these incoming signals, helping us to predict and prepare ourselves for future actions. This skill relies on extracting the statistics of event streams in the environment that contain regularities of variable complexity from simple repetitive patterns to complex probabilistic combinations. Here, we test the brain mechanisms that mediate our ability to adapt to the environment's statistics and predict upcoming events. By combining behavioral training and multisession fMRI in human participants (male and female), we track the corticostriatal mechanisms that mediate learning of temporal sequences as they change in structure complexity. We show that learning of predictive structures relates to individual decision strategy; that is, selecting the most probable outcome in a given context (maximizing) versus matching the exact sequence statistics. These strategies engage distinct human brain regions: maximizing engages dorsolateral prefrontal, cingulate, sensory-motor regions, and basal ganglia (dorsal caudate, putamen), whereas matching engages occipitotemporal regions (including the hippocampus) and basal ganglia (ventral caudate). Our findings provide evidence for distinct corticostriatal mechanisms that facilitate our ability to extract behaviorally relevant statistics to make predictions. SIGNIFICANCE STATEMENT Making predictions about future events relies on interpreting streams of information that may initially appear incomprehensible. Past work has studied how humans identify repetitive patterns and associative pairings. However, the natural environment contains regularities that vary in complexity from simple repetition to complex probabilistic combinations. Here, we combine behavior and multisession fMRI to track the brain mechanisms that mediate our ability to adapt to

  15. Statistical mechanics and applications in condensed matter

    CERN Document Server

    Di Castro, Carlo

    2015-01-01

    This innovative and modular textbook combines classical topics in thermodynamics, statistical mechanics and many-body theory with the latest developments in condensed matter physics research. Written by internationally renowned experts and logically structured to cater for undergraduate and postgraduate students and researchers, it covers the underlying theoretical principles and includes numerous problems and worked examples to put this knowledge into practice. Three main streams provide a framework for the book; beginning with thermodynamics and classical statistical mechanics, including mean field approximation, fluctuations and the renormalization group approach to critical phenomena. The authors then examine quantum statistical mechanics, covering key topics such as normal Fermi and Luttinger liquids, superfluidity and superconductivity. Finally, they explore classical and quantum kinetics, Anderson localization and quantum interference, and disordered Fermi liquids. Unique in providing a bridge between ...

  16. Classical and quantum Fisher information in the geometrical formulation of quantum mechanics

    Energy Technology Data Exchange (ETDEWEB)

    Facchi, Paolo [Dipartimento di Matematica, Universita di Bari, I-70125 Bari (Italy); INFN, Sezione di Bari, I-70126 Bari (Italy); MECENAS, Universita Federico II di Napoli and Universita di Bari (Italy); Kulkarni, Ravi [Vivekananda Yoga Research Foundation, Bangalore 560 080 (India); Man' ko, V.I., E-mail: manko@na.infn.i [P.N. Lebedev Physical Institute, Leninskii Prospect 53, Moscow 119991 (Russian Federation); Marmo, Giuseppe [Dipartimento di Scienze Fisiche, Universita di Napoli ' Federico II' , I-80126 Napoli (Italy); INFN, Sezione di Napoli, I-80126 Napoli (Italy); MECENAS, Universita Federico II di Napoli and Universita di Bari (Italy); Sudarshan, E.C.G. [Department of Physics, University of Texas, Austin, TX 78712 (United States); Ventriglia, Franco [Dipartimento di Scienze Fisiche, Universita di Napoli ' Federico II' , I-80126 Napoli (Italy); INFN, Sezione di Napoli, I-80126 Napoli (Italy); MECENAS, Universita Federico II di Napoli and Universita di Bari (Italy)

    2010-11-01

    The tomographic picture of quantum mechanics has brought the description of quantum states closer to that of classical probability and statistics. On the other hand, the geometrical formulation of quantum mechanics introduces a metric tensor and a symplectic tensor (Hermitian tensor) on the space of pure states. By putting these two aspects together, we show that the Fisher information metric, both classical and quantum, can be described by means of the Hermitian tensor on the manifold of pure states.

  17. Classical and quantum Fisher information in the geometrical formulation of quantum mechanics

    International Nuclear Information System (INIS)

    Facchi, Paolo; Kulkarni, Ravi; Man'ko, V.I.; Marmo, Giuseppe; Sudarshan, E.C.G.; Ventriglia, Franco

    2010-01-01

    The tomographic picture of quantum mechanics has brought the description of quantum states closer to that of classical probability and statistics. On the other hand, the geometrical formulation of quantum mechanics introduces a metric tensor and a symplectic tensor (Hermitian tensor) on the space of pure states. By putting these two aspects together, we show that the Fisher information metric, both classical and quantum, can be described by means of the Hermitian tensor on the manifold of pure states.

  18. Fluctuations of physical values in statistical mechanics

    International Nuclear Information System (INIS)

    Zaripov, R.G.

    1999-01-01

    The new matrix inequalities for the boundary of measurement accuracy of physical values in the ensemble of quantum systems were obtained. The multidimensional thermodynamical parameter measurement is estimated. The matrix inequalities obtained are quantum analogs of the Cramer-Rao information inequalities in mathematical statistics. The quantity of information in quantum mechanical measurement, connected with the boundaries of jointly measurable values in one macroscopic experiment was determined. The lower boundary of the variance of estimation of multidimensional quantum mechanical parameter was found. (author)

  19. States in the Hilbert space formulation and in the phase space formulation of quantum mechanics

    International Nuclear Information System (INIS)

    Tosiek, J.; Brzykcy, P.

    2013-01-01

    We consider the problem of testing whether a given matrix in the Hilbert space formulation of quantum mechanics or a function considered in the phase space formulation of quantum theory represents a quantum state. We propose several practical criteria for recognising states in these two versions of quantum physics. After minor modifications, they can be applied to check positivity of any operators acting in a Hilbert space or positivity of any functions from an algebra with a ∗-product of Weyl type. -- Highlights: ► Methods of testing whether a given matrix represents a quantum state. ► The Stratonovich–Weyl correspondence on an arbitrary symplectic manifold. ► Criteria for checking whether a function on a symplectic space is a Wigner function

  20. (ajst) statistical mechanics model for orientational

    African Journals Online (AJOL)

    Science and Engineering Series Vol. 6, No. 2, pp. 94 - 101. STATISTICAL MECHANICS MODEL FOR ORIENTATIONAL. MOTION OF TWO-DIMENSIONAL RIGID ROTATOR. Malo, J.O. ... there is no translational motion and that they are well separated so .... constant and I is the moment of inertia of a linear rotator. Thus, the ...

  1. Multiparticle quantum mechanics obeying fractional statistics

    International Nuclear Information System (INIS)

    Wu, Y.

    1984-01-01

    We obtain the rule governing many-body wave functions for particles obeying fractional statistics in two (space) dimensions. It generalizes and continuously interpolates the usual symmetrization and antisymmetrization. Quantum mechanics of more than two particles is discussed and some new features are found

  2. Statistical mechanics and the foundations of thermodynamics

    International Nuclear Information System (INIS)

    Loef, A.M.

    1979-01-01

    An introduction to classical statistical mechanics and its relation to thermodynamics is presented. Emphasis is put on getting a detailed and logical presentation of the foundations of thermodynamics based on the maximum entropy principles which govern the values taken by macroscopic variables according to the laws of large numbers

  3. Statistical mechanics of systems of unbounded spins

    Energy Technology Data Exchange (ETDEWEB)

    Lebowitz, J L [Yeshiva Univ., New York (USA). Belfer Graduate School of Science; Presutti, E [L' Aquila Univ. (Italy). Istituto di Matematica

    1976-11-01

    We develop the statistical mechanics of unbounded n-component spin systems interacting via potentials which are superstable and strongly tempered. The uniqueness of the equilibrium state is then proven for one component ferromagnetic spins whose free energy is differentiable with respect to the magnetic field.

  4. Stability and equilibrium in quantum statistical mechanics

    International Nuclear Information System (INIS)

    Kastler, Daniel.

    1975-01-01

    A derivation of the Gibbs Ansatz, base of the equilibrium statistical mechanics is provided from a stability requirements, in technical connection with the harmonic analysis of non-commutative dynamical systems. By the same token a relation is established between stability and the positivity of Hamiltonian in the zero temperature case [fr

  5. Infinite Random Graphs as Statistical Mechanical Models

    DEFF Research Database (Denmark)

    Durhuus, Bergfinnur Jøgvan; Napolitano, George Maria

    2011-01-01

    We discuss two examples of infinite random graphs obtained as limits of finite statistical mechanical systems: a model of two-dimensional dis-cretized quantum gravity defined in terms of causal triangulated surfaces, and the Ising model on generic random trees. For the former model we describe a ...

  6. Bayesian approach to inverse statistical mechanics

    Science.gov (United States)

    Habeck, Michael

    2014-05-01

    Inverse statistical mechanics aims to determine particle interactions from ensemble properties. This article looks at this inverse problem from a Bayesian perspective and discusses several statistical estimators to solve it. In addition, a sequential Monte Carlo algorithm is proposed that draws the interaction parameters from their posterior probability distribution. The posterior probability involves an intractable partition function that is estimated along with the interactions. The method is illustrated for inverse problems of varying complexity, including the estimation of a temperature, the inverse Ising problem, maximum entropy fitting, and the reconstruction of molecular interaction potentials.

  7. Applying Statistical Mechanics to pixel detectors

    International Nuclear Information System (INIS)

    Pindo, Massimiliano

    2002-01-01

    Pixel detectors, being made of a large number of active cells of the same kind, can be considered as significant sets to which Statistical Mechanics variables and methods can be applied. By properly redefining well known statistical parameters in order to let them match the ones that actually characterize pixel detectors, an analysis of the way they work can be performed in a totally new perspective. A deeper understanding of pixel detectors is attained, helping in the evaluation and comparison of their intrinsic characteristics and performance

  8. An introduction to statistical mechanics and thermodynamics

    CERN Document Server

    Swendsen, Robert H

    2012-01-01

    This text presents the two complementary aspects of thermal physics as an integrated theory of the properties of matter. Conceptual understanding is promoted by thorough development of basic concepts. In contrast to many texts, statistical mechanics, including discussion of the required probability theory, is presented first. This provides a statistical foundation for the concept of entropy, which is central to thermal physics. A unique feature of the book is the development ofentropy based on Boltzmann's 1877 definition; this avoids contradictions or ad hoc corrections found in other texts. D

  9. Quantum mechanics as a natural generalization of classical statistical mechanics

    International Nuclear Information System (INIS)

    Xu Laizi; Qian Shangwu

    1994-01-01

    By comparison between equations of motion of geometrical optics (GO) and that of classical statistical mechanics (CSM), it is found that there should be an analogy between GO and CSM instead of GO and classical mechanics (CM). Furthermore, by comparison between the classical limit (CL) of quantum mechanics (QM) and CSM, the authors find that CL of QM is CSM not CM, hence they demonstrated that QM is a natural generalization of CSM instead of CM

  10. Analogies between classical statistical mechanics and quantum mechanics

    International Nuclear Information System (INIS)

    Uehara, M.

    1986-01-01

    Some analogies between nonequilibrium classical statistical mechanics and quantum mechanics, at the level of the Liouville equation and at the kinetic level, are commented on. A theorem, related to the Vlasov equation applied to a plasma, is proved. The theorem presents an analogy with Ehrenfest's theorem of quantum mechanics. An analogy between the plasma kinetic theory and Bohm's quantum theory with 'hidden variables' is also shown. (Author) [pt

  11. Cellular automata and statistical mechanical models

    International Nuclear Information System (INIS)

    Rujan, P.

    1987-01-01

    The authors elaborate on the analogy between the transfer matrix of usual lattice models and the master equation describing the time development of cellular automata. Transient and stationary properties of probabilistic automata are linked to surface and bulk properties, respectively, of restricted statistical mechanical systems. It is demonstrated that methods of statistical physics can be successfully used to describe the dynamic and the stationary behavior of such automata. Some exact results are derived, including duality transformations, exact mappings, disorder, and linear solutions. Many examples are worked out in detail to demonstrate how to use statistical physics in order to construct cellular automata with desired properties. This approach is considered to be a first step toward the design of fully parallel, probabilistic systems whose computational abilities rely on the cooperative behavior of their components

  12. Mathematical methods in quantum and statistical mechanics

    International Nuclear Information System (INIS)

    Fishman, L.

    1977-01-01

    The mathematical structure and closed-form solutions pertaining to several physical problems in quantum and statistical mechanics are examined in some detail. The J-matrix method, introduced previously for s-wave scattering and based upon well-established Hilbert Space theory and related generalized integral transformation techniques, is extended to treat the lth partial wave kinetic energy and Coulomb Hamiltonians within the context of square integrable (L 2 ), Laguerre (Slater), and oscillator (Gaussian) basis sets. The theory of relaxation in statistical mechanics within the context of the theory of linear integro-differential equations of the Master Equation type and their corresponding Markov processes is examined. Several topics of a mathematical nature concerning various computational aspects of the L 2 approach to quantum scattering theory are discussed

  13. Equilibrium statistical mechanics of lattice models

    CERN Document Server

    Lavis, David A

    2015-01-01

    Most interesting and difficult problems in equilibrium statistical mechanics concern models which exhibit phase transitions. For graduate students and more experienced researchers this book provides an invaluable reference source of approximate and exact solutions for a comprehensive range of such models. Part I contains background material on classical thermodynamics and statistical mechanics, together with a classification and survey of lattice models. The geometry of phase transitions is described and scaling theory is used to introduce critical exponents and scaling laws. An introduction is given to finite-size scaling, conformal invariance and Schramm—Loewner evolution. Part II contains accounts of classical mean-field methods. The parallels between Landau expansions and catastrophe theory are discussed and Ginzburg—Landau theory is introduced. The extension of mean-field theory to higher-orders is explored using the Kikuchi—Hijmans—De Boer hierarchy of approximations. In Part III the use of alge...

  14. Statistical mechanics and the physics of fluids

    CERN Document Server

    Tosi, Mario

    This volume collects the lecture notes of a course on statistical mechanics, held at Scuola Normale Superiore di Pisa for third-to-fifth year students in physics and chemistry. Three main themes are covered in the book. The first part gives a compact presentation of the foundations of statistical mechanics and their connections with thermodynamics. Applications to ideal gases of material particles and of excitation quanta are followed by a brief introduction to a real classical gas and to a weakly coupled classical plasma, and by a broad overview on the three states of matter.The second part is devoted to fluctuations around equilibrium and their correlations. Coverage of liquid structure and critical phenomena is followed by a discussion of irreversible processes as exemplified by diffusive motions and by the dynamics of density and heat fluctuations. Finally, the third part is an introduction to some advanced themes: supercooling and the glassy state, non-Newtonian fluids including polymers and liquid cryst...

  15. Nonextensive statistical mechanics and high energy physics

    Directory of Open Access Journals (Sweden)

    Tsallis Constantino

    2014-04-01

    Full Text Available The use of the celebrated Boltzmann-Gibbs entropy and statistical mechanics is justified for ergodic-like systems. In contrast, complex systems typically require more powerful theories. We will provide a brief introduction to nonadditive entropies (characterized by indices like q, which, in the q → 1 limit, recovers the standard Boltzmann-Gibbs entropy and associated nonextensive statistical mechanics. We then present somerecent applications to systems such as high-energy collisions, black holes and others. In addition to that, we clarify and illustrate the neat distinction that exists between Lévy distributions and q-exponential ones, a point which occasionally causes some confusion in the literature, very particularly in the LHC literature

  16. Introductory statistical mechanics for electron storage rings

    International Nuclear Information System (INIS)

    Jowett, J.M.

    1986-07-01

    These lectures introduce the beam dynamics of electron-positron storage rings with particular emphasis on the effects due to synchrotron radiation. They differ from most other introductions in their systematic use of the physical principles and mathematical techniques of the non-equilibrium statistical mechanics of fluctuating dynamical systems. A self-contained exposition of the necessary topics from this field is included. Throughout the development, a Hamiltonian description of the effects of the externally applied fields is maintained in order to preserve the links with other lectures on beam dynamics and to show clearly the extent to which electron dynamics in non-Hamiltonian. The statistical mechanical framework is extended to a discussion of the conceptual foundations of the treatment of collective effects through the Vlasov equation

  17. Statistical algebraic approach to quantum mechanics

    International Nuclear Information System (INIS)

    Slavnov, D.A.

    2001-01-01

    The scheme for plotting the quantum theory with application of the statistical algebraic approach is proposed. The noncommutative algebra elements (observed ones) and nonlinear functionals on this algebra (physical state) are used as the primary constituents. The latter ones are associated with the single-unit measurement results. Certain physical state groups are proposed to consider as quantum states of the standard quantum mechanics. It is shown that the mathematical apparatus of the standard quantum mechanics may be reproduced in such a scheme in full volume [ru

  18. Exactly soluble problems in statistical mechanics

    International Nuclear Information System (INIS)

    Yang, C.N.

    1983-01-01

    In the last few years, a number of two-dimensional classical and one-dimensional quantum mechanical problems in statistical mechanics have been exactly solved. Although these problems range over models of diverse physical interest, their solutions were obtained using very similar mathematical methods. In these lectures, the main points of the methods are discussed. In this introductory lecture, an overall survey of all these problems without going into the detailed method of solution is given. In later lectures, they shall concentrate on one particular problem: the delta function interaction in one dimension, and go into the details of that problem

  19. Classical statistical mechanics approach to multipartite entanglement

    Energy Technology Data Exchange (ETDEWEB)

    Facchi, P [Dipartimento di Matematica, Universita di Bari, I-70125 Bari (Italy); Florio, G; Pascazio, S [Istituto Nazionale di Fisica Nucleare, Sezione di Bari, I-70126 Bari (Italy); Marzolino, U [Dipartimento di Fisica, Universita di Trieste, and Istituto Nazionale di Fisica Nucleare, Sezione di Trieste, I-34014 Trieste (Italy); Parisi, G [Dipartimento di Fisica, Universita di Roma ' La Sapienza' , Piazzale Aldo Moro 2, Centre for Statistical Mechanics and Complexity (SMC), CNR-INFM (Italy)

    2010-06-04

    We characterize the multipartite entanglement of a system of n qubits in terms of the distribution function of the bipartite purity over balanced bipartitions. We search for maximally multipartite entangled states, whose average purity is minimal, and recast this optimization problem into a problem of statistical mechanics, by introducing a cost function, a fictitious temperature and a partition function. By investigating the high-temperature expansion, we obtain the first three moments of the distribution. We find that the problem exhibits frustration.

  20. Classical statistical mechanics approach to multipartite entanglement

    Science.gov (United States)

    Facchi, P.; Florio, G.; Marzolino, U.; Parisi, G.; Pascazio, S.

    2010-06-01

    We characterize the multipartite entanglement of a system of n qubits in terms of the distribution function of the bipartite purity over balanced bipartitions. We search for maximally multipartite entangled states, whose average purity is minimal, and recast this optimization problem into a problem of statistical mechanics, by introducing a cost function, a fictitious temperature and a partition function. By investigating the high-temperature expansion, we obtain the first three moments of the distribution. We find that the problem exhibits frustration.

  1. Classical statistical mechanics approach to multipartite entanglement

    International Nuclear Information System (INIS)

    Facchi, P; Florio, G; Pascazio, S; Marzolino, U; Parisi, G

    2010-01-01

    We characterize the multipartite entanglement of a system of n qubits in terms of the distribution function of the bipartite purity over balanced bipartitions. We search for maximally multipartite entangled states, whose average purity is minimal, and recast this optimization problem into a problem of statistical mechanics, by introducing a cost function, a fictitious temperature and a partition function. By investigating the high-temperature expansion, we obtain the first three moments of the distribution. We find that the problem exhibits frustration.

  2. Statistical Mechanics and Black Hole Thermodynamics

    OpenAIRE

    Carlip, Steven

    1997-01-01

    Black holes are thermodynamic objects, but despite recent progress, the ultimate statistical mechanical origin of black hole temperature and entropy remains mysterious. Here I summarize an approach in which the entropy is viewed as arising from ``would-be pure gauge'' degrees of freedom that become dynamical at the horizon. For the (2+1)-dimensional black hole, these degrees of freedom can be counted, and yield the correct Bekenstein-Hawking entropy; the corresponding problem in 3+1 dimension...

  3. Statistical mechanics of budget-constrained auctions

    OpenAIRE

    Altarelli, F.; Braunstein, A.; Realpe-Gomez, J.; Zecchina, R.

    2009-01-01

    Finding the optimal assignment in budget-constrained auctions is a combinatorial optimization problem with many important applications, a notable example being the sale of advertisement space by search engines (in this context the problem is often referred to as the off-line AdWords problem). Based on the cavity method of statistical mechanics, we introduce a message passing algorithm that is capable of solving efficiently random instances of the problem extracted from a natural distribution,...

  4. The statistical mechanics of learning a rule

    International Nuclear Information System (INIS)

    Watkin, T.L.H.; Rau, A.; Biehl, M.

    1993-01-01

    A summary is presented of the statistical mechanical theory of learning a rule with a neural network, a rapidly advancing area which is closely related to other inverse problems frequently encountered by physicists. By emphasizing the relationship between neural networks and strongly interacting physical systems, such as spin glasses, the authors show how learning theory has provided a workshop in which to develop new, exact analytical techniques

  5. Statistical mechanics of the majority game

    International Nuclear Information System (INIS)

    Kozlowski, P; Marsili, M

    2003-01-01

    The majority game, modelling a system of heterogeneous agents trying to behave in a similar way, is introduced and studied using methods of statistical mechanics. The stationary states of the game are given by the (local) minima of a particular Hopfield-like Hamiltonian. On the basis of replica symmetric calculations, we draw the phase diagram, which contains the analogue of a retrieval phase. The number of metastable states is estimated using the annealed approximation. The results are confronted with extensive numerical simulations

  6. Metastability in Field Theory and Statistical Mechanics

    International Nuclear Information System (INIS)

    Carvalho, C.A. de.

    1984-01-01

    After a phase transition analysis which can occur in the framework of a scalar field theory, at finite temperature and in presence of a external field, possibles metastable situations are studied and also how is their relationship with the transitions. In both cases it is used a semiclassical approximation to the theory which, in Statistical Mechanics, corresponds to the droplet-bubble model. (L.C.) [pt

  7. Statistical mechanics for a class of quantum statistics

    International Nuclear Information System (INIS)

    Isakov, S.B.

    1994-01-01

    Generalized statistical distributions for identical particles are introduced for the case where filling a single-particle quantum state by particles depends on filling states of different momenta. The system of one-dimensional bosons with a two-body potential that can be solved by means of the thermodynamic Bethe ansatz is shown to be equivalent thermodynamically to a system of free particles obeying statistical distributions of the above class. The quantum statistics arising in this way are completely determined by the two-particle scattering phases of the corresponding interacting systems. An equation determining the statistical distributions for these statistics is derived

  8. Thermodynamics and statistical mechanics. [thermodynamic properties of gases

    Science.gov (United States)

    1976-01-01

    The basic thermodynamic properties of gases are reviewed and the relations between them are derived from the first and second laws. The elements of statistical mechanics are then formulated and the partition function is derived. The classical form of the partition function is used to obtain the Maxwell-Boltzmann distribution of kinetic energies in the gas phase and the equipartition of energy theorem is given in its most general form. The thermodynamic properties are all derived as functions of the partition function. Quantum statistics are reviewed briefly and the differences between the Boltzmann distribution function for classical particles and the Fermi-Dirac and Bose-Einstein distributions for quantum particles are discussed.

  9. Statistical mechanics of lattice Boson field theory

    International Nuclear Information System (INIS)

    1976-01-01

    A lattice approximation to Euclidean, boson quantum field theory is expressed in terms of the thermodynamic properties of a classical statistical mechanical system near its critical point in a sufficiently general way to permit the inclusion of an anomalous dimension of the vacuum. Using the thermodynamic properties of the Ising model, one can begin to construct nontrivial (containing scattering) field theories in 2, 3 and 4 dimensions. It is argued that, depending on the choice of the bare coupling constant, there are three types of behavior to be expected: the perturbation theory region, the renormalization group fixed point region, and the Ising model region

  10. Statistical mechanics of spatial evolutionary games

    International Nuclear Information System (INIS)

    Miekisz, Jacek

    2004-01-01

    We discuss the long-run behaviour of stochastic dynamics of many interacting players in spatial evolutionary games. In particular, we investigate the effect of the number of players and the noise level on the stochastic stability of Nash equilibria. We discuss similarities and differences between systems of interacting players maximizing their individual payoffs and particles minimizing their interaction energy. We use concepts and techniques of statistical mechanics to study game-theoretic models. In order to obtain results in the case of the so-called potential games, we analyse the thermodynamic limit of the appropriate models of interacting particles

  11. Statistical mechanics out of equilibrium the irreversibility

    International Nuclear Information System (INIS)

    Alvarez Estrada, R. F.

    2001-01-01

    A Round Table about the issue of Irreversibility and related matters has taken place during the last (20th) Statistical Mechanics Conference, held in Paris (July 1998). This article tries to provide a view (necessarily limited, and hence, uncompleted) of some approaches to the subject: the one based upon deterministic chaos (which is currently giving rise to a very active research) and the classical interpretation due to Boltzmann. An attempt has been made to write this article in a self-contained way, and to avoid a technical presentation wherever possible. (Author) 29 refs

  12. Principles of thermodynamics and statistical mechanics

    CERN Document Server

    Lawden, D F

    2005-01-01

    A thorough exploration of the universal principles of thermodynamics and statistical mechanics, this volume explains the applications of these essential rules to a multitude of situations arising in physics and engineering. It develops their use in a variety of circumstances-including those involving gases, crystals, and magnets-in order to illustrate general methods of analysis and to provide readers with all the necessary background to continue in greater depth with specific topics.Author D. F. Lawden has considerable experience in teaching this subject to university students of varied abili

  13. Thermodynamics and statistical mechanics an integrated approach

    CERN Document Server

    Hardy, Robert J

    2014-01-01

    This textbook brings together the fundamentals of the macroscopic and microscopic aspects of thermal physics by presenting thermodynamics and statistical mechanics as complementary theories based on small numbers of postulates. The book is designed to give the instructor flexibility in structuring courses for advanced undergraduates and/or beginning graduate students and is written on the principle that a good text should also be a good reference. The presentation of thermodynamics follows the logic of Clausius and Kelvin while relating the concepts involved to familiar phenomena and the mod

  14. Statistical mechanics of lattice boson field theory

    International Nuclear Information System (INIS)

    Baker, G.A. Jr.

    1977-01-01

    A lattice approximation to Euclidean, boson quantum field theory is expressed in terms of the thermodynamic properties of a classical statistical mechanical system near its critical point in a sufficiently general way to permit the inclusion of an anomalous dimension of the vacuum. Using the thermodynamic properties of the Ising model, one can begin to construct nontrivial (containing scattering) field theories in 2, 3, and 4 dimensions. It is argued that, depending on the choice of the bare coupling constant, there are three types of behavior to be expected: the perturbation theory region, the renormalization group fixed point region, and the Ising model region. 24 references

  15. Early years of Computational Statistical Mechanics

    Science.gov (United States)

    Mareschal, Michel

    2018-05-01

    Evidence that a model of hard spheres exhibits a first-order solid-fluid phase transition was provided in the late fifties by two new numerical techniques known as Monte Carlo and Molecular Dynamics. This result can be considered as the starting point of computational statistical mechanics: at the time, it was a confirmation of a counter-intuitive (and controversial) theoretical prediction by J. Kirkwood. It necessitated an intensive collaboration between the Los Alamos team, with Bill Wood developing the Monte Carlo approach, and the Livermore group, where Berni Alder was inventing Molecular Dynamics. This article tells how it happened.

  16. Quality of comminuted sausages formulated from mechanically deboned poultry meat.

    Science.gov (United States)

    Mielnik, Maria B; Aaby, Kjersti; Rolfsen, Knut; Ellekjær, Marit R; Nilsson, Astrid

    2002-05-01

    Comminuted sausages formulated with mechanically deboned poultry meat-MDPM (turkey or chicken, frame or neck) treated in different ways before production (vacuum packed MDPM or air packed skeletons deboned at production) and stored frozen for 6 or 18 weeks have been studied using a full-factorial design and chemical, physical and sensory analysis. MDPM was obtained from a Beehive separator. Comminuted sausages with MDPM from turkey frames, stored at -25 °C as skeletons, packed in air for 18 weeks developed marked rancid odour and flavour which could also be detected by thiobarbituric acid reactive substances (TBARS) and the concentration of volatile compounds. Vacuum packed mechanically deboned meat irrespective of species and carcass part could be stored for up to 18 weeks and used in formulation of sausages without any serious changes in their sensory profiles. Instrumental colour differences between sausages were mainly due to species. Turkey sausages were darker, redder and less yellow than chicken sausages. Moisture and fat contents were influenced by carcass part and to a lesser extent depended on species and storage time. Principal least squares regression (PLS2) showed close relationships between instrumental parameters and sensory attributes. TBARS, hexanal and volatile compounds were highly correlated with rancid flavour while redness (a(∗)) was strongly related to sensory colour hue and colour strength.

  17. Statistical mechanics and the foundations of thermodynamics

    International Nuclear Information System (INIS)

    Martin-Loef, A.

    1979-01-01

    These lectures are designed as an introduction to classical statistical mechanics and its relation to thermodynamics. They are intended to bridge the gap between the treatment of the subject in physics text books and the modern presentations of mathematically rigorous results. We shall first introduce the probability distributions, ensembles, appropriate for describing systems in equilibrium and consider some of their basic physical applications. We also discuss the problem of approach to equilibrium and how irreversibility comes into the dynamics. We then give a detailed description of how the law of large numbers for macrovariables in equilibrium is derived from the fact that entropy is an extensive quantity in the thermodynamic limit. We show in a natural way how to split the energy changes in an thermodynamical process into work and heat leading to a derivation of the first and second laws of thermodynamics from the rules of thermodynamical equilibrium. We have elaborated this part in detail because we feel it is quite satisfactory, that the establishment of the limit of thermodynamic functions as achieved in the modern development of the mathematical aspects of statistical mechanics allows a more general and logically clearer presentation of the bases of thermodynamics. We close these lectures by presenting the basic facts about fluctuation theory. The treatment aims to be reasonably self-contained both concerning the physics and mathematics needed. No knowledge of quantum mechanics is presupposed. Since we spent a large part on mathematical proofs and give many technical facts these lectures are probably most digestive for the mathematically inclined reader who wants to understand the physics of the subject. (HJ)

  18. Hamiltonian formulation and statistics of an attracting system of nonlinear oscillators

    International Nuclear Information System (INIS)

    Tasso, H.

    1987-10-01

    An attracting system of r nonlinear oscillators of an extended van der Pol type was investigated with respect to Hamiltonian formulation. The case of r=2 is rather simple, though nontrivial. For r>2 the tests with Jacobi's identity and Frechet derivatives are negative if Hamiltonians in the natural variables are looked for. Independently, a Liouville theorem is proved and equilibrium statistics is made possible, which leads to a Gaussian distribution in the natural variables. (orig.)

  19. History Matching Through a Smooth Formulation of Multiple-Point Statistics

    DEFF Research Database (Denmark)

    Melnikova, Yulia; Zunino, Andrea; Lange, Katrine

    2014-01-01

    and the mismatch with multiple-point statistics. As a result, in the framework of the Bayesian approach, such a solution belongs to a high posterior region. The methodology, while applicable to any inverse problem with a training-image-based prior, is especially beneficial for problems which require expensive......We propose a smooth formulation of multiple-point statistics that enables us to solve inverse problems using gradient-based optimization techniques. We introduce a differentiable function that quantifies the mismatch between multiple-point statistics of a training image and of a given model. We...... show that, by minimizing this function, any continuous image can be gradually transformed into an image that honors the multiple-point statistics of the discrete training image. The solution to an inverse problem is then found by minimizing the sum of two mismatches: the mismatch with data...

  20. A signed particle formulation of non-relativistic quantum mechanics

    Energy Technology Data Exchange (ETDEWEB)

    Sellier, Jean Michel, E-mail: jeanmichel.sellier@parallel.bas.bg

    2015-09-15

    A formulation of non-relativistic quantum mechanics in terms of Newtonian particles is presented in the shape of a set of three postulates. In this new theory, quantum systems are described by ensembles of signed particles which behave as field-less classical objects which carry a negative or positive sign and interact with an external potential by means of creation and annihilation events only. This approach is shown to be a generalization of the signed particle Wigner Monte Carlo method which reconstructs the time-dependent Wigner quasi-distribution function of a system and, therefore, the corresponding Schrödinger time-dependent wave-function. Its classical limit is discussed and a physical interpretation, based on experimental evidences coming from quantum tomography, is suggested. Moreover, in order to show the advantages brought by this novel formulation, a straightforward extension to relativistic effects is discussed. To conclude, quantum tunnelling numerical experiments are performed to show the validity of the suggested approach.

  1. The probability representation as a new formulation of quantum mechanics

    International Nuclear Information System (INIS)

    Man'ko, Margarita A; Man'ko, Vladimir I

    2012-01-01

    We present a new formulation of conventional quantum mechanics, in which the notion of a quantum state is identified via a fair probability distribution of the position measured in a reference frame of the phase space with rotated axes. In this formulation, the quantum evolution equation as well as the equation for finding energy levels are expressed as linear equations for the probability distributions that determine the quantum states. We also give the integral transforms relating the probability distribution (called the tomographic-probability distribution or the state tomogram) to the density matrix and the Wigner function and discuss their connection with the Radon transform. Qudit states are considered and the invertible map of the state density operators onto the probability vectors is discussed. The tomographic entropies and entropic uncertainty relations are reviewed. We demonstrate the uncertainty relations for the position and momentum and the entropic uncertainty relations in the tomographic-probability representation, which is suitable for an experimental check of the uncertainty relations.

  2. A statistical mechanical interpretation of algorithmic information theory: Total statistical mechanical interpretation based on physical argument

    International Nuclear Information System (INIS)

    Tadaki, Kohtaro

    2010-01-01

    The statistical mechanical interpretation of algorithmic information theory (AIT, for short) was introduced and developed by our former works [K. Tadaki, Local Proceedings of CiE 2008, pp. 425-434, 2008] and [K. Tadaki, Proceedings of LFCS'09, Springer's LNCS, vol. 5407, pp. 422-440, 2009], where we introduced the notion of thermodynamic quantities, such as partition function Z(T), free energy F(T), energy E(T), statistical mechanical entropy S(T), and specific heat C(T), into AIT. We then discovered that, in the interpretation, the temperature T equals to the partial randomness of the values of all these thermodynamic quantities, where the notion of partial randomness is a stronger representation of the compression rate by means of program-size complexity. Furthermore, we showed that this situation holds for the temperature T itself, which is one of the most typical thermodynamic quantities. Namely, we showed that, for each of the thermodynamic quantities Z(T), F(T), E(T), and S(T) above, the computability of its value at temperature T gives a sufficient condition for T is an element of (0,1) to satisfy the condition that the partial randomness of T equals to T. In this paper, based on a physical argument on the same level of mathematical strictness as normal statistical mechanics in physics, we develop a total statistical mechanical interpretation of AIT which actualizes a perfect correspondence to normal statistical mechanics. We do this by identifying a microcanonical ensemble in the framework of AIT. As a result, we clarify the statistical mechanical meaning of the thermodynamic quantities of AIT.

  3. Two statistical mechanics aspects of complex networks

    Science.gov (United States)

    Thurner, Stefan; Biely, Christoly

    2006-12-01

    By adopting an ensemble interpretation of non-growing rewiring networks, network theory can be reduced to a counting problem of possible network states and an identification of their associated probabilities. We present two scenarios of how different rewirement schemes can be used to control the state probabilities of the system. In particular, we review how by generalizing the linking rules of random graphs, in combination with superstatistics and quantum mechanical concepts, one can establish an exact relation between the degree distribution of any given network and the nodes’ linking probability distributions. In a second approach, we control state probabilities by a network Hamiltonian, whose characteristics are motivated by biological and socio-economical statistical systems. We demonstrate that a thermodynamics of networks becomes a fully consistent concept, allowing to study e.g. ‘phase transitions’ and computing entropies through thermodynamic relations.

  4. Statistical mechanics of magnetized pair Fermi gas

    International Nuclear Information System (INIS)

    Daicic, J.; Frankel, N.E.; Kowalenko, V.

    1993-01-01

    Following previous work on the magnetized pair Bose gas this contribution presents the statistical mechanics of the charged relativistic Fermi gas with pair creation in d spatial dimensions. Initially, the gas in no external fields is studied. As a result, expansions for the various thermodynamic functions are obtained in both the μ/m→0 (neutrino) limit, and about the point μ/m =1, where μ is the chemical potential. The thermodynamics of a gas of quantum-number conserving massless fermions is also discussed. Then a complete study of the pair Fermi gas in a homogeneous magnetic field, is presented investigating the behavior of the magnetization over a wide range of field strengths. The inclusion of pairs leads to new results for the net magnetization due to the paramagnetic moment of the spins and the diamagnetic Landau orbits. 20 refs

  5. Thermodynamics and statistical mechanics an integrated approach

    CERN Document Server

    Shell, M Scott

    2015-01-01

    Learn classical thermodynamics alongside statistical mechanics with this fresh approach to the subjects. Molecular and macroscopic principles are explained in an integrated, side-by-side manner to give students a deep, intuitive understanding of thermodynamics and equip them to tackle future research topics that focus on the nanoscale. Entropy is introduced from the get-go, providing a clear explanation of how the classical laws connect to the molecular principles, and closing the gap between the atomic world and thermodynamics. Notation is streamlined throughout, with a focus on general concepts and simple models, for building basic physical intuition and gaining confidence in problem analysis and model development. Well over 400 guided end-of-chapter problems are included, addressing conceptual, fundamental, and applied skill sets. Numerous worked examples are also provided together with handy shaded boxes to emphasize key concepts, making this the complete teaching package for students in chemical engineer...

  6. Statistical mechanics of budget-constrained auctions

    International Nuclear Information System (INIS)

    Altarelli, F; Braunstein, A; Realpe-Gomez, J; Zecchina, R

    2009-01-01

    Finding the optimal assignment in budget-constrained auctions is a combinatorial optimization problem with many important applications, a notable example being in the sale of advertisement space by search engines (in this context the problem is often referred to as the off-line AdWords problem). On the basis of the cavity method of statistical mechanics, we introduce a message-passing algorithm that is capable of solving efficiently random instances of the problem extracted from a natural distribution, and we derive from its properties the phase diagram of the problem. As the control parameter (average value of the budgets) is varied, we find two phase transitions delimiting a region in which long-range correlations arise

  7. Statistical mechanics of budget-constrained auctions

    Science.gov (United States)

    Altarelli, F.; Braunstein, A.; Realpe-Gomez, J.; Zecchina, R.

    2009-07-01

    Finding the optimal assignment in budget-constrained auctions is a combinatorial optimization problem with many important applications, a notable example being in the sale of advertisement space by search engines (in this context the problem is often referred to as the off-line AdWords problem). On the basis of the cavity method of statistical mechanics, we introduce a message-passing algorithm that is capable of solving efficiently random instances of the problem extracted from a natural distribution, and we derive from its properties the phase diagram of the problem. As the control parameter (average value of the budgets) is varied, we find two phase transitions delimiting a region in which long-range correlations arise.

  8. Generalized bond percolation and statistical mechanics

    International Nuclear Information System (INIS)

    Tsallis, C.

    1978-05-01

    A generalization of traditional bond percolation is performed, in the sens that bonds have now the possibility of partially transmitting the information (a fact which leads to the concept of 'fidelity' of the bond), and also in the sens that, besides the normal tendency to equiprobability, the bonds are allowed to substantially change the information. Furthermore the fidelity is allowed, to become an aleatory variable, and the operational rules concerning the associated distribution laws are determined. Thermally quenched random bonds and the whole body of Statistical Mechanics become particular cases of this formalism, which is in general adapted to the treatment of all problems whose main characteristic is to preserve a part of the information through a long path or array (critical phenomena, regime changements, thermal random models, etc). Operationally it provides a quick method for the calculation of the equivalent probability of complex clusters within the traditional bond percolation problem [pt

  9. Statistical mechanics of dense granular media

    International Nuclear Information System (INIS)

    Coniglio, A; Fierro, A; Nicodemi, M; Ciamarra, M Pica; Tarzia, M

    2005-01-01

    We discuss some recent results on the statistical mechanics approach to dense granular media. In particular, by analytical mean field investigation we derive the phase diagram of monodisperse and bidisperse granular assemblies. We show that 'jamming' corresponds to a phase transition from a 'fluid' to a 'glassy' phase, observed when crystallization is avoided. The nature of such a 'glassy' phase turns out to be the same as found in mean field models for glass formers. This gives quantitative evidence for the idea of a unified description of the 'jamming' transition in granular media and thermal systems, such as glasses. We also discuss mixing/segregation transitions in binary mixtures and their connections to phase separation and 'geometric' effects

  10. Statistical mechanics of driven diffusive systems

    CERN Document Server

    Schmittmann, B

    1995-01-01

    Far-from-equilibrium phenomena, while abundant in nature, are not nearly as well understood as their equilibrium counterparts. On the theoretical side, progress is slowed by the lack of a simple framework, such as the Boltzmann-Gbbs paradigm in the case of equilibrium thermodynamics. On the experimental side, the enormous structural complexity of real systems poses serious obstacles to comprehension. Similar difficulties have been overcome in equilibrium statistical mechanics by focusing on model systems. Even if they seem too simplistic for known physical systems, models give us considerable insight, provided they capture the essential physics. They serve as important theoretical testing grounds where the relationship between the generic physical behavior and the key ingredients of a successful theory can be identified and understood in detail. Within the vast realm of non-equilibrium physics, driven diffusive systems form a subset with particularly interesting properties. As a prototype model for these syst...

  11. A 'general boundary' formulation for quantum mechanics and quantum gravity

    International Nuclear Information System (INIS)

    Oeckl, Robert

    2003-01-01

    I propose to formalize quantum theories as topological quantum field theories in a generalized sense, associating state spaces with boundaries of arbitrary (and possibly finite) regions of space-time. I further propose to obtain such 'general boundary' quantum theories through a generalized path integral quantization. I show how both, non-relativistic quantum mechanics and quantum field theory can be given a 'general boundary' formulation. Surprisingly, even in the non-relativistic case, features normally associated with quantum field theory emerge from consistency conditions. This includes states with arbitrary particle number and pair creation. I also note how three-dimensional quantum gravity is an example for a realization of both proposals and suggest to apply them to four-dimensional quantum gravity

  12. BOOK REVIEW: Statistical Mechanics of Turbulent Flows

    Science.gov (United States)

    Cambon, C.

    2004-10-01

    This is a handbook for a computational approach to reacting flows, including background material on statistical mechanics. In this sense, the title is somewhat misleading with respect to other books dedicated to the statistical theory of turbulence (e.g. Monin and Yaglom). In the present book, emphasis is placed on modelling (engineering closures) for computational fluid dynamics. The probabilistic (pdf) approach is applied to the local scalar field, motivated first by the nonlinearity of chemical source terms which appear in the transport equations of reacting species. The probabilistic and stochastic approaches are also used for the velocity field and particle position; nevertheless they are essentially limited to Lagrangian models for a local vector, with only single-point statistics, as for the scalar. Accordingly, conventional techniques, such as single-point closures for RANS (Reynolds-averaged Navier-Stokes) and subgrid-scale models for LES (large-eddy simulations), are described and in some cases reformulated using underlying Langevin models and filtered pdfs. Even if the theoretical approach to turbulence is not discussed in general, the essentials of probabilistic and stochastic-processes methods are described, with a useful reminder concerning statistics at the molecular level. The book comprises 7 chapters. Chapter 1 briefly states the goals and contents, with a very clear synoptic scheme on page 2. Chapter 2 presents definitions and examples of pdfs and related statistical moments. Chapter 3 deals with stochastic processes, pdf transport equations, from Kramer-Moyal to Fokker-Planck (for Markov processes), and moments equations. Stochastic differential equations are introduced and their relationship to pdfs described. This chapter ends with a discussion of stochastic modelling. The equations of fluid mechanics and thermodynamics are addressed in chapter 4. Classical conservation equations (mass, velocity, internal energy) are derived from their

  13. Aftershock Energy Distribution by Statistical Mechanics Approach

    Science.gov (United States)

    Daminelli, R.; Marcellini, A.

    2015-12-01

    The aim of our work is to research the most probable distribution of the energy of aftershocks. We started by applying one of the fundamental principles of statistical mechanics that, in case of aftershock sequences, it could be expressed as: the greater the number of different ways in which the energy of aftershocks can be arranged among the energy cells in phase space the more probable the distribution. We assume that each cell in phase space has the same possibility to be occupied, and that more than one cell in the phase space can have the same energy. Seeing that seismic energy is proportional to products of different parameters, a number of different combinations of parameters can produce different energies (e.g., different combination of stress drop and fault area can release the same seismic energy). Let us assume that there are gi cells in the aftershock phase space characterised by the same energy released ɛi. Therefore we can assume that the Maxwell-Boltzmann statistics can be applied to aftershock sequences with the proviso that the judgment on the validity of this hypothesis is the agreement with the data. The aftershock energy distribution can therefore be written as follow: n(ɛ)=Ag(ɛ)exp(-βɛ)where n(ɛ) is the number of aftershocks with energy, ɛ, A and β are constants. Considering the above hypothesis, we can assume g(ɛ) is proportional to ɛ. We selected and analysed different aftershock sequences (data extracted from Earthquake Catalogs of SCEC, of INGV-CNT and other institutions) with a minimum magnitude retained ML=2 (in some cases ML=2.6) and a time window of 35 days. The results of our model are in agreement with the data, except in the very low energy band, where our model resulted in a moderate overestimation.

  14. A quantum information approach to statistical mechanics

    International Nuclear Information System (INIS)

    Cuevas, G.

    2011-01-01

    The field of quantum information and computation harnesses and exploits the properties of quantum mechanics to perform tasks more efficiently than their classical counterparts, or that may uniquely be possible in the quantum world. Its findings and techniques have been applied to a number of fields, such as the study of entanglement in strongly correlated systems, new simulation techniques for many-body physics or, generally, to quantum optics. This thesis aims at broadening the scope of quantum information theory by applying it to problems in statistical mechanics. We focus on classical spin models, which are toy models used in a variety of systems, ranging from magnetism, neural networks, to quantum gravity. We tackle these models using quantum information tools from three different angles. First, we show how the partition function of a class of widely different classical spin models (models in different dimensions, different types of many-body interactions, different symmetries, etc) can be mapped to the partition function of a single model. We prove this by first establishing a relation between partition functions and quantum states, and then transforming the corresponding quantum states to each other. Second, we give efficient quantum algorithms to estimate the partition function of various classical spin models, such as the Ising or the Potts model. The proof is based on a relation between partition functions and quantum circuits, which allows us to determine the quantum computational complexity of the partition function by studying the corresponding quantum circuit. Finally, we outline the possibility of applying quantum information concepts and tools to certain models of dis- crete quantum gravity. The latter provide a natural route to generalize our results, insofar as the central quantity has the form of a partition function, and as classical spin models are used as toy models of matter. (author)

  15. The Brandeis Dice Problem and Statistical Mechanics

    Science.gov (United States)

    van Enk, Steven J.

    2014-11-01

    Jaynes invented the Brandeis Dice Problem as a simple illustration of the MaxEnt (Maximum Entropy) procedure that he had demonstrated to work so well in Statistical Mechanics. I construct here two alternative solutions to his toy problem. One, like Jaynes' solution, uses MaxEnt and yields an analog of the canonical ensemble, but at a different level of description. The other uses Bayesian updating and yields an analog of the micro-canonical ensemble. Both, unlike Jaynes' solution, yield error bars, whose operational merits I discuss. These two alternative solutions are not equivalent for the original Brandeis Dice Problem, but become so in what must, therefore, count as the analog of the thermodynamic limit, M-sided dice with M → ∞. Whereas the mathematical analogies between the dice problem and Stat Mech are quite close, there are physical properties that the former lacks but that are crucial to the workings of the latter. Stat Mech is more than just MaxEnt.

  16. The Statistical Mechanics of Ideal MHD Turbulence

    Science.gov (United States)

    Shebalin, John V.

    2003-01-01

    Turbulence is a universal, nonlinear phenomenon found in all energetic fluid and plasma motion. In particular. understanding magneto hydrodynamic (MHD) turbulence and incorporating its effects in the computation and prediction of the flow of ionized gases in space, for example, are great challenges that must be met if such computations and predictions are to be meaningful. Although a general solution to the "problem of turbulence" does not exist in closed form, numerical integrations allow us to explore the phase space of solutions for both ideal and dissipative flows. For homogeneous, incompressible turbulence, Fourier methods are appropriate, and phase space is defined by the Fourier coefficients of the physical fields. In the case of ideal MHD flows, a fairly robust statistical mechanics has been developed, in which the symmetry and ergodic properties of phase space is understood. A discussion of these properties will illuminate our principal discovery: Coherent structure and randomness co-exist in ideal MHD turbulence. For dissipative flows, as opposed to ideal flows, progress beyond the dimensional analysis of Kolmogorov has been difficult. Here, some possible future directions that draw on the ideal results will also be discussed. Our conclusion will be that while ideal turbulence is now well understood, real turbulence still presents great challenges.

  17. Plasma Soliton Turbulence and Statistical Mechanics

    International Nuclear Information System (INIS)

    Treumann, R.A.; Pottelette, R.

    1999-01-01

    Collisionless kinetic plasma turbulence is described approximately in terms of a superposition of non-interacting solitary waves. We discuss the relevance of such a description under astrophysical conditions. Several types of solitary waves may be of interest in this relation as generators of turbulence and turbulent transport. A consistent theory of turbulence can be given only in a few particular cases when the description can be reduced to the Korteweg-de Vries equation or some other simple equation like the Kadomtsev-Petviashvili equation. It turns out that the soliton turbulence is usually energetically harder than the ordinary weakly turbulent plasma description. This implies that interaction of particles with such kinds of turbulence can lead to stronger acceleration than in ordinary turbulence. However, the description in our model is only classical and non-relativistic. Transport in solitary turbulence is most important for drift wave turbulence. Such waves form solitary drift wave vortices which may provide cross-field transport. A more general discussion is given on transport. In a model of Levy flight trapping of particles in solitons (or solitary turbulence) one finds that the residence time of particles in the region of turbulence may be described by a generalized Lorentzian probability distribution. It is shown that under collisionless equilibrium conditions far away from thermal equilibrium such distributions are natural equilibrium distributions. A consistent thermodynamic description of such media can be given in terms of a generalized Lorentzian statistical mechanics and thermodynamics. (author)

  18. Statistical mechanics, gravity, and Euclidean theory

    International Nuclear Information System (INIS)

    Fursaev, Dmitri V.

    2002-01-01

    A review of computations of free energy for Gibbs states on stationary but not static gravitational and gauge backgrounds is given. On these backgrounds wave equations for free fields are reduced to eigenvalue problems which depend non-linearly on the spectral parameter. We present a method to deal with such problems. In particular, we demonstrate how some results of the spectral theory of second-order elliptic operators, such as heat kernel asymptotics, can be extended to a class of non-linear spectral problems. The method is used to trace down the relation between the canonical definition of the free energy based on summation over the modes and the covariant definition given in Euclidean quantum gravity. As an application, high-temperature asymptotics of the free energy and of the thermal part of the stress-energy tensor in the presence of rotation are derived. We also discuss statistical mechanics in the presence of Killing horizons where canonical and Euclidean theories are related in a non-trivial way

  19. Probabilistic cellular automata: Some statistical mechanical considerations

    International Nuclear Information System (INIS)

    Lebowitz, J.L.; Maes, C.; Speer, E.R.

    1990-01-01

    Spin systems evolving in continuous or discrete time under the action of stochastic dynamics are used to model phenomena as diverse as the structure of alloys and the functioning of neural networks. While in some cases the dynamics are secondary, designed to produce a specific stationary measure whose properties one is interested in studying, there are other cases in which the only available information is the dynamical rule. Prime examples of the former are computer simulations, via Glauber dynamics, of equilibrium Gibbs measures with a specified interaction potential. Examples of the latter include various types of majority rule dynamics used as models for pattern recognition and for error-tolerant computations. The present note discusses ways in which techniques found useful in equilibrium statistical mechanics can be applied to a particular class of models of the latter types. These are cellular automata with noise: systems in which the spins are updated stochastically at integer times, simultaneously at all sites of some regular lattice. These models were first investigated in detail in the Soviet literature of the late sixties and early seventies. They are now generally referred to as Stochastic or Probabilistic Cellular Automata (PCA), and may be considered to include deterministic automata (CA) as special limits. 16 refs., 3 figs

  20. A statistical mechanical model of economics

    Science.gov (United States)

    Lubbers, Nicholas Edward Williams

    Statistical mechanics pursues low-dimensional descriptions of systems with a very large number of degrees of freedom. I explore this theme in two contexts. The main body of this dissertation explores and extends the Yard Sale Model (YSM) of economic transactions using a combination of simulations and theory. The YSM is a simple interacting model for wealth distributions which has the potential to explain the empirical observation of Pareto distributions of wealth. I develop the link between wealth condensation and the breakdown of ergodicity due to nonlinear diffusion effects which are analogous to the geometric random walk. Using this, I develop a deterministic effective theory of wealth transfer in the YSM that is useful for explaining many quantitative results. I introduce various forms of growth to the model, paying attention to the effect of growth on wealth condensation, inequality, and ergodicity. Arithmetic growth is found to partially break condensation, and geometric growth is found to completely break condensation. Further generalizations of geometric growth with growth in- equality show that the system is divided into two phases by a tipping point in the inequality parameter. The tipping point marks the line between systems which are ergodic and systems which exhibit wealth condensation. I explore generalizations of the YSM transaction scheme to arbitrary betting functions to develop notions of universality in YSM-like models. I find that wealth vi condensation is universal to a large class of models which can be divided into two phases. The first exhibits slow, power-law condensation dynamics, and the second exhibits fast, finite-time condensation dynamics. I find that the YSM, which exhibits exponential dynamics, is the critical, self-similar model which marks the dividing line between the two phases. The final chapter develops a low-dimensional approach to materials microstructure quantification. Modern materials design harnesses complex

  1. Bohmian mechanics with complex action: A new trajectory-based formulation of quantum mechanics

    International Nuclear Information System (INIS)

    Goldfarb, Yair; Degani, Ilan; Tannor, David J.

    2006-01-01

    In recent years there has been a resurgence of interest in Bohmian mechanics as a numerical tool because of its local dynamics, which suggest the possibility of significant computational advantages for the simulation of large quantum systems. However, closer inspection of the Bohmian formulation reveals that the nonlocality of quantum mechanics has not disappeared--it has simply been swept under the rug into the quantum force. In this paper we present a new formulation of Bohmian mechanics in which the quantum action, S, is taken to be complex. This leads to a single equation for complex S, and ultimately complex x and p but there is a reward for this complexification - a significantly higher degree of localization. The quantum force in the new approach vanishes for Gaussian wave packet dynamics, and its effect on barrier tunneling processes is orders of magnitude lower than that of the classical force. In fact, the current method is shown to be a rigorous extension of generalized Gaussian wave packet dynamics to give exact quantum mechanics. We demonstrate tunneling probabilities that are in virtually perfect agreement with the exact quantum mechanics down to 10 -7 calculated from strictly localized quantum trajectories that do not communicate with their neighbors. The new formulation may have significant implications for fundamental quantum mechanics, ranging from the interpretation of non-locality to measures of quantum complexity

  2. A statistical mechanics approach to Granovetter theory

    Science.gov (United States)

    Barra, Adriano; Agliari, Elena

    2012-05-01

    In this paper we try to bridge breakthroughs in quantitative sociology/econometrics, pioneered during the last decades by Mac Fadden, Brock-Durlauf, Granovetter and Watts-Strogatz, by introducing a minimal model able to reproduce essentially all the features of social behavior highlighted by these authors. Our model relies on a pairwise Hamiltonian for decision-maker interactions which naturally extends the multi-populations approaches by shifting and biasing the pattern definitions of a Hopfield model of neural networks. Once introduced, the model is investigated through graph theory (to recover Granovetter and Watts-Strogatz results) and statistical mechanics (to recover Mac-Fadden and Brock-Durlauf results). Due to the internal symmetries of our model, the latter is obtained as the relaxation of a proper Markov process, allowing even to study its out-of-equilibrium properties. The method used to solve its equilibrium is an adaptation of the Hamilton-Jacobi technique recently introduced by Guerra in the spin-glass scenario and the picture obtained is the following: shifting the patterns from [-1,+1]→[0.+1] implies that the larger the amount of similarities among decision makers, the stronger their relative influence, and this is enough to explain both the different role of strong and weak ties in the social network as well as its small-world properties. As a result, imitative interaction strengths seem essentially a robust request (enough to break the gauge symmetry in the couplings), furthermore, this naturally leads to a discrete choice modelization when dealing with the external influences and to imitative behavior à la Curie-Weiss as the one introduced by Brock and Durlauf.

  3. Statistical Mechanics of Money, Income, and Wealth

    Science.gov (United States)

    Yakovenko, Victor

    2006-03-01

    In Ref. [1], we proposed an analogy between the exponential Boltzmann-Gibbs distribution of energy in physics and the equilibrium probability distribution of money in a closed economic system. Analogously to energy, money is locally conserved in interactions between economic agents, so the thermal Boltzmann-Gibbs distribution function is expected for money. Since then, many researchers followed and expanded this idea [2]. Much work was done on the analysis of empirical data, mostly on income, for which a lot of tax and census data is available. We demonstrated [3] that income distribution in the USA has a well-defined two-class structure. The majority of population (97-99%) belongs to the lower class characterized by the exponential Boltzmann-Gibbs (``thermal'') distribution. The upper class (1-3% of population) has a Pareto power-law (``superthermal'') distribution, whose parameters change in time with the rise and fall of stock market. We proposed a concept of equilibrium inequality in a society, based on the principle of maximal entropy, and quantitatively demonstrated that it applies to the majority of population. Income distribution in other countries shows similar patterns. For more references, see http://www2.physics.umd.edu/˜yakovenk/econophysics.html. References: [1] A. A. Dragulescu and V. M. Yakovenko, ``Statistical mechanics of money'', Eur. Phys. J. B 17, 723 (2000). [2] ``Econophysics of Wealth Distributions'', edited by A. Chatterjee, S. Yarlagadda, and B. K. Chakrabarti, Springer, 2005. [3] A. C. Silva and V. M. Yakovenko, ``Temporal evolution of the `thermal' and `superthermal' income classes in the USA during 1983-2001'', Europhys. Lett. 69, 304 (2005).

  4. Statistical Mechanics and Applications in Condensed Matter

    Science.gov (United States)

    Di Castro, Carlo; Raimondi, Roberto

    2015-08-01

    Preface; 1. Thermodynamics: a brief overview; 2. Kinetics; 3. From Boltzmann to Gibbs; 4. More ensembles; 5. The thermodynamic limit and its thermodynamic stability; 6. Density matrix and quantum statistical mechanics; 7. The quantum gases; 8. Mean-field theories and critical phenomena; 9. Second quantization and Hartree-Fock approximation; 10. Linear response and fluctuation-dissipation theorem in quantum systems: equilibrium and small deviations; 11. Brownian motion and transport in disordered systems; 12. Fermi liquids; 13. The Landau theory of the second order phase transitions; 14. The Landau-Wilson model for critical phenomena; 15. Superfluidity and superconductivity; 16. The scaling theory; 17. The renormalization group approach; 18. Thermal Green functions; 19. The microscopic foundations of Fermi liquids; 20. The Luttinger liquid; 21. Quantum interference effects in disordered electron systems; Appendix A. The central limit theorem; Appendix B. Some useful properties of the Euler Gamma function; Appendix C. Proof of the second theorem of Yang and Lee; Appendix D. The most probable distribution for the quantum gases; Appendix E. Fermi-Dirac and Bose-Einstein integrals; Appendix F. The Fermi gas in a uniform magnetic field: Landau diamagnetism; Appendix G. Ising and gas-lattice models; Appendix H. Sum over discrete Matsubara frequencies; Appendix I. Hydrodynamics of the two-fluid model of superfluidity; Appendix J. The Cooper problem in the theory of superconductivity; Appendix K. Superconductive fluctuations phenomena; Appendix L. Diagrammatic aspects of the exact solution of the Tomonaga Luttinger model; Appendix M. Details on the theory of the disordered Fermi liquid; References; Author index; Index.

  5. Statistical Mechanics of Temporal and Interacting Networks

    Science.gov (United States)

    Zhao, Kun

    In the last ten years important breakthroughs in the understanding of the topology of complexity have been made in the framework of network science. Indeed it has been found that many networks belong to the universality classes called small-world networks or scale-free networks. Moreover it was found that the complex architecture of real world networks strongly affects the critical phenomena defined on these structures. Nevertheless the main focus of the research has been the characterization of single and static networks. Recently, temporal networks and interacting networks have attracted large interest. Indeed many networks are interacting or formed by a multilayer structure. Example of these networks are found in social networks where an individual might be at the same time part of different social networks, in economic and financial networks, in physiology or in infrastructure systems. Moreover, many networks are temporal, i.e. the links appear and disappear on the fast time scale. Examples of these networks are social networks of contacts such as face-to-face interactions or mobile-phone communication, the time-dependent correlations in the brain activity and etc. Understanding the evolution of temporal and multilayer networks and characterizing critical phenomena in these systems is crucial if we want to describe, predict and control the dynamics of complex system. In this thesis, we investigate several statistical mechanics models of temporal and interacting networks, to shed light on the dynamics of this new generation of complex networks. First, we investigate a model of temporal social networks aimed at characterizing human social interactions such as face-to-face interactions and phone-call communication. Indeed thanks to the availability of data on these interactions, we are now in the position to compare the proposed model to the real data finding good agreement. Second, we investigate the entropy of temporal networks and growing networks , to provide

  6. The scientifiv way of thinking in statistics, statistical physics and quantum mechanics

    OpenAIRE

    Săvoiu, Gheorghe

    2008-01-01

    This paper focuses on the way of thinking in both classical and modern Physics and Statistics, Statistical Mechanics or Statistical Physics and Quantum Mechanics. These different statistical ways of thinking and their specific methods have generated new fields for new activities and new scientific disciplines, like Econophysics (between Economics and Physics), Sociophysics (between Sociology and Physics), Mediaphysics (between all media and comunication sciences), etc. After describing some r...

  7. The scientific way of thinking in statistics, statistical physics and quantum mechanics

    OpenAIRE

    Săvoiu, Gheorghe

    2008-01-01

    This paper focuses on the way of thinking in both classical and modern Physics and Statistics, Statistical Mechanics or Statistical Physics and Quantum Mechanics. These different statistical ways of thinking and their specific methods have generated new fields for new activities and new scientific disciplines, like Econophysics (between Economics and Physics), Sociophysics (between Sociology and Physics), Mediaphysics (between all media and comunication sciences), etc. After describing some r...

  8. The statistical mechanics of financial markets

    CERN Document Server

    Voit, Johannes

    2003-01-01

    From the reviews of the first edition - "Provides an excellent introduction for physicists interested in the statistical properties of financial markets. Appropriately early in the book the basic financial terms such as shorts, limit orders, puts, calls, and other terms are clearly defined. Examples, often with graphs, augment the reader’s understanding of what may be a plethora of new terms and ideas… [This is] an excellent starting point for the physicist interested in the subject. Some of the book’s strongest features are its careful definitions, its detailed examples, and the connection it establishes to physical systems." PHYSICS TODAY "This book is excellent at illustrating the similarities of financial markets with other non-equilibrium physical systems. [...] In summary, a very good book that offers more than just qualitative comparisons of physics and finance." (www.quantnotes.com) This highly-praised introductory treatment describes parallels between statistical physics and finance - both thos...

  9. Equilibrium statistical mechanics for self-gravitating systems: local ergodicity and extended Boltzmann-Gibbs/White-Narayan statistics

    Science.gov (United States)

    He, Ping

    2012-01-01

    The long-standing puzzle surrounding the statistical mechanics of self-gravitating systems has not yet been solved successfully. We formulate a systematic theoretical framework of entropy-based statistical mechanics for spherically symmetric collisionless self-gravitating systems. We use an approach that is very different from that of the conventional statistical mechanics of short-range interaction systems. We demonstrate that the equilibrium states of self-gravitating systems consist of both mechanical and statistical equilibria, with the former characterized by a series of velocity-moment equations and the latter by statistical equilibrium equations, which should be derived from the entropy principle. The velocity-moment equations of all orders are derived from the steady-state collisionless Boltzmann equation. We point out that the ergodicity is invalid for the whole self-gravitating system, but it can be re-established locally. Based on the local ergodicity, using Fermi-Dirac-like statistics, with the non-degenerate condition and the spatial independence of the local microstates, we rederive the Boltzmann-Gibbs entropy. This is consistent with the validity of the collisionless Boltzmann equation, and should be the correct entropy form for collisionless self-gravitating systems. Apart from the usual constraints of mass and energy conservation, we demonstrate that the series of moment or virialization equations must be included as additional constraints on the entropy functional when performing the variational calculus; this is an extension to the original prescription by White & Narayan. Any possible velocity distribution can be produced by the statistical-mechanical approach that we have developed with the extended Boltzmann-Gibbs/White-Narayan statistics. Finally, we discuss the questions of negative specific heat and ensemble inequivalence for self-gravitating systems.

  10. Statistical mechanics of microscopically thin thermalized shells

    Science.gov (United States)

    Kosmrlj, Andrej

    Recent explosion in fabrication of microscopically thin free standing structures made from graphene and other two-dimensional materials has led to a renewed interest in the mechanics of such structures in presence of thermal fluctuations. Since late 1980s it has been known that for flat solid sheets thermal fluctuations effectively increase the bending rigidity and reduce the bulk and shear moduli in a scale-dependent fashion. However, much is still unknown about the mechanics of thermalized flat sheets of complex geometries and about the mechanics of thermalized shells with non-zero background curvature. In this talk I will present recent development in the mechanics of thermalized ribbons, spherical shells and cylindrical tubes. Long ribbons are found to behave like hybrids between flat sheets with renormalized elastic constants and semi-flexible polymers, and these results can be used to predict the mechanics of graphene kirigami structures. Contrary to the anticipated behavior for ribbons, the non-zero background curvature of shells leads to remarkable novel phenomena. In shells, thermal fluctuations effectively generate negative surface tension, which can significantly reduce the critical buckling pressure for spherical shells and the critical axial load for cylindrical tubes. For large shells this thermally generated load becomes big enough to spontaneously crush spherical shells and cylindrical tubes even in the absence of external loads. I will comment on the relevance for crushing of microscopic shells (viral capsids, bacteria, microcapsules) due to osmotic shocks and for crushing of nanotubes.

  11. A statistical mechanical model for equilibrium ionization

    International Nuclear Information System (INIS)

    Macris, N.; Martin, P.A.; Pule, J.

    1990-01-01

    A quantum electron interacts with a classical gas of hard spheres and is in thermal equilibrium with it. The interaction is attractive and the electron can form a bound state with the classical particles. It is rigorously shown that in a well defined low density and low temperature limit, the ionization probability for the electron tends to the value predicted by the Saha formula for thermal ionization. In this regime, the electron is found to be in a statistical mixture of a bound and a free state. (orig.)

  12. Sources of Error and the Statistical Formulation of M S: m b Seismic Event Screening Analysis

    Science.gov (United States)

    Anderson, D. N.; Patton, H. J.; Taylor, S. R.; Bonner, J. L.; Selby, N. D.

    2014-03-01

    The Comprehensive Nuclear-Test-Ban Treaty (CTBT), a global ban on nuclear explosions, is currently in a ratification phase. Under the CTBT, an International Monitoring System (IMS) of seismic, hydroacoustic, infrasonic and radionuclide sensors is operational, and the data from the IMS is analysed by the International Data Centre (IDC). The IDC provides CTBT signatories basic seismic event parameters and a screening analysis indicating whether an event exhibits explosion characteristics (for example, shallow depth). An important component of the screening analysis is a statistical test of the null hypothesis H 0: explosion characteristics using empirical measurements of seismic energy (magnitudes). The established magnitude used for event size is the body-wave magnitude (denoted m b) computed from the initial segment of a seismic waveform. IDC screening analysis is applied to events with m b greater than 3.5. The Rayleigh wave magnitude (denoted M S) is a measure of later arriving surface wave energy. Magnitudes are measurements of seismic energy that include adjustments (physical correction model) for path and distance effects between event and station. Relative to m b, earthquakes generally have a larger M S magnitude than explosions. This article proposes a hypothesis test (screening analysis) using M S and m b that expressly accounts for physical correction model inadequacy in the standard error of the test statistic. With this hypothesis test formulation, the 2009 Democratic Peoples Republic of Korea announced nuclear weapon test fails to reject the null hypothesis H 0: explosion characteristics.

  13. Maximum entropy principle and hydrodynamic models in statistical mechanics

    International Nuclear Information System (INIS)

    Trovato, M.; Reggiani, L.

    2012-01-01

    This review presents the state of the art of the maximum entropy principle (MEP) in its classical and quantum (QMEP) formulation. Within the classical MEP we overview a general theory able to provide, in a dynamical context, the macroscopic relevant variables for carrier transport in the presence of electric fields of arbitrary strength. For the macroscopic variables the linearized maximum entropy approach is developed including full-band effects within a total energy scheme. Under spatially homogeneous conditions, we construct a closed set of hydrodynamic equations for the small-signal (dynamic) response of the macroscopic variables. The coupling between the driving field and the energy dissipation is analyzed quantitatively by using an arbitrary number of moments of the distribution function. Analogously, the theoretical approach is applied to many one-dimensional n + nn + submicron Si structures by using different band structure models, different doping profiles, different applied biases and is validated by comparing numerical calculations with ensemble Monte Carlo simulations and with available experimental data. Within the quantum MEP we introduce a quantum entropy functional of the reduced density matrix, the principle of quantum maximum entropy is then asserted as fundamental principle of quantum statistical mechanics. Accordingly, we have developed a comprehensive theoretical formalism to construct rigorously a closed quantum hydrodynamic transport within a Wigner function approach. The theory is formulated both in thermodynamic equilibrium and nonequilibrium conditions, and the quantum contributions are obtained by only assuming that the Lagrange multipliers can be expanded in powers of ħ 2 , being ħ the reduced Planck constant. In particular, by using an arbitrary number of moments, we prove that: i) on a macroscopic scale all nonlocal effects, compatible with the uncertainty principle, are imputable to high-order spatial derivatives both of the

  14. Statistical mechanics of reacting dense plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Rogers, F.J.

    1978-11-22

    A review of the quantum statistical theory of strongly coupled many component plasmas is given. The theoretical development is shown to consist of six separate parts. Compensation between bound and scattering state contributions to the partition function and use of the shifted Debye energy levels are important aspects of the analysis. The results are valid when the electrons are moderately coupled to the heavy ions, i.e., ..lambda../sub e..cap alpha../* < 1, but no restriction is placed on the coupling between heavy ions. Another restriction is that lambda/lambda/sub D/ < 1, i.e., the thermal deBroglie wavelength is less than the Debye length. Numerical calculations of PV/N/sub 0/kT and C/sub V/ are given for a Rubidium plasma.

  15. Statistical mechanics of human resource allocation

    Science.gov (United States)

    Inoue, Jun-Ichi; Chen, He

    2014-03-01

    We provide a mathematical platform to investigate the network topology of agents, say, university graduates who are looking for their positions in labor markets. The basic model is described by the so-called Potts spin glass which is well-known in the research field of statistical physics. In the model, each Potts spin (a tiny magnet in atomic scale length) represents the action of each student, and it takes a discrete variable corresponding to the company he/she applies for. We construct the energy to include three distinct effects on the students' behavior, namely, collective effect, market history and international ranking of companies. In this model system, the correlations (the adjacent matrix) between students are taken into account through the pairwise spin-spin interactions. We carry out computer simulations to examine the efficiency of the model. We also show that some chiral representation of the Potts spin enables us to obtain some analytical insights into our labor markets. This work was financially supported by Grant-in-Aid for Scientific Research (C) of Japan Society for the Promotion of Science No. 25330278.

  16. Statistical Mechanics of Japanese Labor Markets

    Science.gov (United States)

    Chen, He

    We introduce a probabilistic model to analyze job-matching processes of recent Japanese labor markets, in particular, for university graduates by means of statistical physics. To make a model of the market efficiently, we take into account several hypotheses. Namely, each company fixes the (business year independent) number of opening positions for newcomers. The ability of gathering newcomers depends on the result of job matching process in past business years. This fact means that the ability of the company is weakening if the company did not make their quota or the company gathered applicants too much over the quota. All university graduates who are looking for their jobs can access the public information about the ranking of companies. By assuming the above essential key points, we construct the local energy function of each company and describe the probability that an arbitrary company gets students at each business year by a Boltzmann-Gibbs distribution. We evaluate the relevant physical quantities such as the employment rate and Gini index. We discuss social inequalities in labor markets, and provide some ways to improve these situations, such as the informal job offer rate, the job-worker mismatch between students and companies. Graduate School of Information Science and Technology.

  17. Statistical mechanics of a cat's cradle

    Science.gov (United States)

    Shen, Tongye; Wolynes, Peter G.

    2006-11-01

    It is believed that, much like a cat's cradle, the cytoskeleton can be thought of as a network of strings under tension. We show that both regular and random bond-disordered networks having bonds that buckle upon compression exhibit a variety of phase transitions as a function of temperature and extension. The results of self-consistent phonon calculations for the regular networks agree very well with computer simulations at finite temperature. The analytic theory also yields a rigidity onset (mechanical percolation) and the fraction of extended bonds for random networks. There is very good agreement with the simulations by Delaney et al (2005 Europhys. Lett. 72 990). The mean field theory reveals a nontranslationally invariant phase with self-generated heterogeneity of tautness, representing 'antiferroelasticity'.

  18. Statistical Mechanics of Thin Spherical Shells

    Directory of Open Access Journals (Sweden)

    Andrej Košmrlj

    2017-01-01

    Full Text Available We explore how thermal fluctuations affect the mechanics of thin amorphous spherical shells. In flat membranes with a shear modulus, thermal fluctuations increase the bending rigidity and reduce the in-plane elastic moduli in a scale-dependent fashion. This is still true for spherical shells. However, the additional coupling between the shell curvature, the local in-plane stretching modes, and the local out-of-plane undulations leads to novel phenomena. In spherical shells, thermal fluctuations produce a radius-dependent negative effective surface tension, equivalent to applying an inward external pressure. By adapting renormalization group calculations to allow for a spherical background curvature, we show that while small spherical shells are stable, sufficiently large shells are crushed by this thermally generated “pressure.” Such shells can be stabilized by an outward osmotic pressure, but the effective shell size grows nonlinearly with increasing outward pressure, with the same universal power-law exponent that characterizes the response of fluctuating flat membranes to a uniform tension.

  19. Application of few-body methods to statistical mechanics

    International Nuclear Information System (INIS)

    Bolle, D.

    1981-01-01

    This paper reviews some of the methods to study the thermodynamic properties of a macroscopic system in terms of the scattering processes between the constituent particles in the system. In particular, we discuss the time delay approach to the virial expansion and the use of the arrangement channel quantum mechanics formulation in kinetic theory. (orig.)

  20. Novel formulations and new mechanisms of delivering chemotherapy.

    Science.gov (United States)

    Stinchcombe, Thomas E

    2014-01-01

    The identification of epidermal growth factor receptor mutations and anaplastic lymphoma kinase rearrangements and the development of targeted therapy for patients with these molecular alterations has been a tremendous advance in the treatment of advanced stage or metastatic non-small cell lung cancer (NSCLC). However, the majority of patients with advanced stage NSCLC will not have one of these molecular alterations and will receive chemotherapy as their primary therapy. Chemotherapy remains a critical component of therapy for resected and locally advanced NSCLC, as well as for patients with limited-stage and extensive stage small cell lung cancer (SCLC). A significant unmet need exists to develop novel chemotherapy agents and to improve the efficacy and toxicity of currently available agents. Several novel formulations of currently available chemotherapy agents are in development for NSCLC and SCLC. Antibody conjugates are therapeutic agents that employ a tumor-specific monoclonal antibody conjugated to a cytotoxic or radionuclide agent. After the monoclonal antibody binds to the tumor antigen, these agents are internalized, and the link between the antibody and the therapeutic agent is dissolved and the cytotoxic agent is release intracellularly. This enhanced delivery of chemotherapy to malignant tissues has the potential to improve efficacy and reduce toxicity. Antibody conjugates to therapeutic agents are currently available for other malignancies and are in development for NSCLC and SCLC.

  1. A statistical mechanical approach to restricted integer partition functions

    Science.gov (United States)

    Zhou, Chi-Chun; Dai, Wu-Sheng

    2018-05-01

    The main aim of this paper is twofold: (1) suggesting a statistical mechanical approach to the calculation of the generating function of restricted integer partition functions which count the number of partitions—a way of writing an integer as a sum of other integers under certain restrictions. In this approach, the generating function of restricted integer partition functions is constructed from the canonical partition functions of various quantum gases. (2) Introducing a new type of restricted integer partition functions corresponding to general statistics which is a generalization of Gentile statistics in statistical mechanics; many kinds of restricted integer partition functions are special cases of this restricted integer partition function. Moreover, with statistical mechanics as a bridge, we reveal a mathematical fact: the generating function of restricted integer partition function is just the symmetric function which is a class of functions being invariant under the action of permutation groups. Using this approach, we provide some expressions of restricted integer partition functions as examples.

  2. Effect of Formulation Methods on the Mechanical and Release ...

    African Journals Online (AJOL)

    The mechanical properties of the tablets were assessed using the crushing strength (CS), friability(F) and crushing strength-friability ratio (CSFR) of the tablets, while drug release properties were assessed using disintegration time and dissolution profile. The granules possessed better flow properties than the powder ...

  3. Statistical mechanics for a system with imperfections: pt. 1

    International Nuclear Information System (INIS)

    Choh, S.T.; Kahng, W.H.; Um, C.I.

    1982-01-01

    Statistical mechanics is extended to treat a system where parts of the Hamiltonian are randomly varying. As the starting point of the theory, the statistical correlation among energy levels is neglected, allowing use of the central limit theorem of the probability theory. (Author)

  4. [Efficient Pharmaceutical Formulation Designs and Their Development Using Mathematical and Statistical Analysis].

    Science.gov (United States)

    Iwao, Yasunori

    2015-01-01

    With the aim of directly predicting the functionality and mechanism of pharmaceutical excipients, we investigated an analysis method based on available surface area (S(t)), which is the surface area of a drug in direct contact with the external solvent during dissolution. First, to study the effect of lubricant concentration on the dissolution rate of acetaminophen (APAP), the dissolution behaviors as well as the change over time in S(t) of APAP tablets were examined. In the dissolution tests, a retarded dissolution of APAP was not observed with new lubricant triglycerin full behenate (TR-FB), whereas magnesium stearate (Mg-St) retarded the dissolution. The S(t) profiles for APAP with Mg-St at>0.5% showed downward curvature indicating a gradual decrease in surface area over time. Conversely, with TR-FB, even when its concentration was increased, the S(t) profile for APAP had a maximum value. The differences between Mg-St and TR-FB could be explained by the differences in extensibility deriving from their morphology. Next, we evaluated the effect of disintegtant concentration using five disintegrants. When disintegrant was added to ethenzamide tablet formulation, an increase in the dissolution rate and S(t) dependent on disintegrant concentration was observed, according to the type of disintegrant. It was found that the water absorption ability of disintegrants had strong correlations with the parameters of S(t). Taken together, this study demonstrates that analysis of S(t) can directly provide useful information, especially about the functionality of pharmaceutical excipients.

  5. Preconditioned augmented Lagrangian formulation for nearly incompressible cardiac mechanics.

    Science.gov (United States)

    Campos, Joventino Oliveira; Dos Santos, Rodrigo Weber; Sundnes, Joakim; Rocha, Bernardo Martins

    2018-04-01

    Computational modeling of the heart is a subject of substantial medical and scientific interest, which may contribute to increase the understanding of several phenomena associated with cardiac physiological and pathological states. Modeling the mechanics of the heart have led to considerable insights, but it still represents a complex and a demanding computational problem, especially in a strongly coupled electromechanical setting. Passive cardiac tissue is commonly modeled as hyperelastic and is characterized by quasi-incompressible, orthotropic, and nonlinear material behavior. These factors are known to be very challenging for the numerical solution of the model. The near-incompressibility is known to cause numerical issues such as the well-known locking phenomenon and ill-conditioning of the stiffness matrix. In this work, the augmented Lagrangian method is used to handle the nearly incompressible condition. This approach can potentially improve computational performance by reducing the condition number of the stiffness matrix and thereby improving the convergence of iterative solvers. We also improve the performance of iterative solvers by the use of an algebraic multigrid preconditioner. Numerical results of the augmented Lagrangian method combined with a preconditioned iterative solver for a cardiac mechanics benchmark suite are presented to show its improved performance. Copyright © 2017 John Wiley & Sons, Ltd.

  6. Quantum mechanics and field theory with fractional spin and statistics

    International Nuclear Information System (INIS)

    Forte, S.

    1992-01-01

    Planar systems admit quantum states that are neither bosons nor fermions, i.e., whose angular momentum is neither integer nor half-integer. After a discussion of some examples of familiar models in which fractional spin may arise, the relevant (nonrelativistic) quantum mechanics is developed from first principles. The appropriate generalization of statistics is also discussed. Some physical effects of fractional spin and statistics are worked out explicitly. The group theory underlying relativistic models with fractional spin and statistics is then introduced and applied to relativistic particle mechanics and field theory. Field-theoretical models in 2+1 dimensions are presented which admit solitons that carry fractional statistics, and are discussed in a semiclassical approach, in the functional integral approach, and in the canonical approach. Finally, fundamental field theories whose Fock states carry fractional spin and statistics are discussed

  7. Statistical-mechanical entropy by the thin-layer method

    International Nuclear Information System (INIS)

    Feng, He; Kim, Sung Won

    2003-01-01

    G. Hooft first studied the statistical-mechanical entropy of a scalar field in a Schwarzschild black hole background by the brick-wall method and hinted that the statistical-mechanical entropy is the statistical origin of the Bekenstein-Hawking entropy of the black hole. However, according to our viewpoint, the statistical-mechanical entropy is only a quantum correction to the Bekenstein-Hawking entropy of the black-hole. The brick-wall method based on thermal equilibrium at a large scale cannot be applied to the cases out of equilibrium such as a nonstationary black hole. The statistical-mechanical entropy of a scalar field in a nonstationary black hole background is calculated by the thin-layer method. The condition of local equilibrium near the horizon of the black hole is used as a working postulate and is maintained for a black hole which evaporates slowly enough and whose mass is far greater than the Planck mass. The statistical-mechanical entropy is also proportional to the area of the black hole horizon. The difference from the stationary black hole is that the result relies on a time-dependent cutoff

  8. Fracture mechanics and statistical mechanics of reinforced elastomeric blends

    CERN Document Server

    Heinrich, Gert; Kaliske, Michael; Klüppel, Manfred; Schneider, Konrad; Vilgis, Thomas

    2013-01-01

    Elastomers are found in many applications ranging from technology to daily life applications for example in tires, drive systems, sealings and print rollers. Dynamical operation conditions put extremely high demands on the performance and stability of these materials and their elastic and flow properties can be easily adjusted by simple manipulations on their elastic and viscous properties. However, the required service life suffers often from material damage as a result of wear processes such as abrasion and wear fatigue, mostly caused by crack formation and propagation. This book covers interdisciplinary research between physics, physical chemistry, material sciences and engineering of elastomers within the range from nanometres to millimetres and connects these aspects with the constitutive material properties. The different chapters describe reliable lifetime and durability predictions based on new fracture mechanical testing concepts and advanced material-theoretical methods which are finally implemented...

  9. Statistics of Smoothed Cosmic Fields in Perturbation Theory. I. Formulation and Useful Formulae in Second-Order Perturbation Theory

    Science.gov (United States)

    Matsubara, Takahiko

    2003-02-01

    We formulate a general method for perturbative evaluations of statistics of smoothed cosmic fields and provide useful formulae for application of the perturbation theory to various statistics. This formalism is an extensive generalization of the method used by Matsubara, who derived a weakly nonlinear formula of the genus statistic in a three-dimensional density field. After describing the general method, we apply the formalism to a series of statistics, including genus statistics, level-crossing statistics, Minkowski functionals, and a density extrema statistic, regardless of the dimensions in which each statistic is defined. The relation between the Minkowski functionals and other geometrical statistics is clarified. These statistics can be applied to several cosmic fields, including three-dimensional density field, three-dimensional velocity field, two-dimensional projected density field, and so forth. The results are detailed for second-order theory of the formalism. The effect of the bias is discussed. The statistics of smoothed cosmic fields as functions of rescaled threshold by volume fraction are discussed in the framework of second-order perturbation theory. In CDM-like models, their functional deviations from linear predictions plotted against the rescaled threshold are generally much smaller than that plotted against the direct threshold. There is still a slight meatball shift against rescaled threshold, which is characterized by asymmetry in depths of troughs in the genus curve. A theory-motivated asymmetry factor in the genus curve is proposed.

  10. Hydrogen atom in the phase-space formulation of quantum mechanics

    International Nuclear Information System (INIS)

    Gracia-Bondia, J.M.

    1984-01-01

    Using a coordinate transformation which regularizes the classical Kepler problem, we show that the hydrogen-atom case may be analytically solved via the phase-space formulation of nonrelativistic quantum mechanics. The problem is essentially reduced to that of a four-dimensional oscillator whose treatment in the phase-space formulation is developed. Furthermore, the method allows us to calculate the Green's function for the H atom in a surprisingly simple way

  11. The road to Maxwell's demon conceptual foundations of statistical mechanics

    CERN Document Server

    Hemmo, Meir

    2012-01-01

    Time asymmetric phenomena are successfully predicted by statistical mechanics. Yet the foundations of this theory are surprisingly shaky. Its explanation for the ease of mixing milk with coffee is incomplete, and even implies that un-mixing them should be just as easy. In this book the authors develop a new conceptual foundation for statistical mechanics that addresses this difficulty. Explaining the notions of macrostates, probability, measurement, memory, and the arrow of time in statistical mechanics, they reach the startling conclusion that Maxwell's Demon, the famous perpetuum mobile, is consistent with the fundamental physical laws. Mathematical treatments are avoided where possible, and instead the authors use novel diagrams to illustrate the text. This is a fascinating book for graduate students and researchers interested in the foundations and philosophy of physics.

  12. Statistical mechanics of low-density parity-check codes

    Energy Technology Data Exchange (ETDEWEB)

    Kabashima, Yoshiyuki [Department of Computational Intelligence and Systems Science, Tokyo Institute of Technology, Yokohama 2268502 (Japan); Saad, David [Neural Computing Research Group, Aston University, Birmingham B4 7ET (United Kingdom)

    2004-02-13

    We review recent theoretical progress on the statistical mechanics of error correcting codes, focusing on low-density parity-check (LDPC) codes in general, and on Gallager and MacKay-Neal codes in particular. By exploiting the relation between LDPC codes and Ising spin systems with multi-spin interactions, one can carry out a statistical mechanics based analysis that determines the practical and theoretical limitations of various code constructions, corresponding to dynamical and thermodynamical transitions, respectively, as well as the behaviour of error-exponents averaged over the corresponding code ensemble as a function of channel noise. We also contrast the results obtained using methods of statistical mechanics with those derived in the information theory literature, and show how these methods can be generalized to include other channel types and related communication problems. (topical review)

  13. Statistical mechanics of low-density parity-check codes

    International Nuclear Information System (INIS)

    Kabashima, Yoshiyuki; Saad, David

    2004-01-01

    We review recent theoretical progress on the statistical mechanics of error correcting codes, focusing on low-density parity-check (LDPC) codes in general, and on Gallager and MacKay-Neal codes in particular. By exploiting the relation between LDPC codes and Ising spin systems with multi-spin interactions, one can carry out a statistical mechanics based analysis that determines the practical and theoretical limitations of various code constructions, corresponding to dynamical and thermodynamical transitions, respectively, as well as the behaviour of error-exponents averaged over the corresponding code ensemble as a function of channel noise. We also contrast the results obtained using methods of statistical mechanics with those derived in the information theory literature, and show how these methods can be generalized to include other channel types and related communication problems. (topical review)

  14. Characterization of absorption enhancers for orally administered therapeutic peptides in tablet formulations - Applying statistical learning

    DEFF Research Database (Denmark)

    Welling, Søren Havelund

    . In the Caco-2 model all reagents are pre-dissolved, and therefore the assay cannot predict critical solubility issues and bile salt interactions in the final tablet formulation. A QSAR solubility model was built to foresee and avoid slow tablet dissolution. Due to enzyme kinetics, slow tablet dissolution...

  15. Prolonged release matrix tablet of pyridostigmine bromide: formulation and optimization using statistical methods.

    Science.gov (United States)

    Bolourchian, Noushin; Rangchian, Maryam; Foroutan, Seyed Mohsen

    2012-07-01

    The aim of this study was to design and optimize a prolonged release matrix formulation of pyridostigmine bromide, an effective drug in myasthenia gravis and poisoning with nerve gas, using hydrophilic - hydrophobic polymers via D-optimal experimental design. HPMC and carnauba wax as retarding agents as well as tricalcium phosphate were used in matrix formulation and considered as independent variables. Tablets were prepared by wet granulation technique and the percentage of drug released at 1 (Y(1)), 4 (Y(2)) and 8 (Y(3)) hours were considered as dependent variables (responses) in this investigation. These experimental responses were best fitted for the cubic, cubic and linear models, respectively. The optimal formulation obtained in this study, consisted of 12.8 % HPMC, 24.4 % carnauba wax and 26.7 % tricalcium phosphate, had a suitable prolonged release behavior followed by Higuchi model in which observed and predicted values were very close. The study revealed that D-optimal design could facilitate the optimization of prolonged release matrix tablet containing pyridostigmine bromide. Accelerated stability studies confirmed that the optimized formulation remains unchanged after exposing in stability conditions for six months.

  16. Limiting processes in non-equilibrium classical statistical mechanics

    International Nuclear Information System (INIS)

    Jancel, R.

    1983-01-01

    After a recall of the basic principles of the statistical mechanics, the results of ergodic theory, the transient at the thermodynamic limit and his link with the transport theory near the equilibrium are analyzed. The fundamental problems put by the description of non-equilibrium macroscopic systems are investigated and the kinetic methods are stated. The problems of the non-equilibrium statistical mechanics are analyzed: irreversibility and coarse-graining, macroscopic variables and kinetic description, autonomous reduced descriptions, limit processes, BBGKY hierarchy, limit theorems [fr

  17. Quadratic Jordan formulation of quantum mechanics and construction of Lie (super)algebras from Jordan (super)algebras

    International Nuclear Information System (INIS)

    Guenaydin, M.

    1979-05-01

    Quadratic Jordan formulation of quantum mechanics in terms of Jordan triple product is presented. This formulation extends to the case of octonionic quantum mechanics for which no Hilbert space formulation exists. Using ternary algebraic techniques we then five the constructions of the derivation, structure and Tits-Koecher (Moebius) algebras of Jordan superalgebras. (orig.) [de

  18. Generalized statistical mechanics approaches to earthquakes and tectonics

    Science.gov (United States)

    Papadakis, Giorgos; Michas, Georgios

    2016-01-01

    Despite the extreme complexity that characterizes the mechanism of the earthquake generation process, simple empirical scaling relations apply to the collective properties of earthquakes and faults in a variety of tectonic environments and scales. The physical characterization of those properties and the scaling relations that describe them attract a wide scientific interest and are incorporated in the probabilistic forecasting of seismicity in local, regional and planetary scales. Considerable progress has been made in the analysis of the statistical mechanics of earthquakes, which, based on the principle of entropy, can provide a physical rationale to the macroscopic properties frequently observed. The scale-invariant properties, the (multi) fractal structures and the long-range interactions that have been found to characterize fault and earthquake populations have recently led to the consideration of non-extensive statistical mechanics (NESM) as a consistent statistical mechanics framework for the description of seismicity. The consistency between NESM and observations has been demonstrated in a series of publications on seismicity, faulting, rock physics and other fields of geosciences. The aim of this review is to present in a concise manner the fundamental macroscopic properties of earthquakes and faulting and how these can be derived by using the notions of statistical mechanics and NESM, providing further insights into earthquake physics and fault growth processes. PMID:28119548

  19. Statistical physics of black holes as quantum-mechanical systems

    OpenAIRE

    Giddings, Steven B.

    2013-01-01

    Some basic features of black-hole statistical mechanics are investigated, assuming that black holes respect the principles of quantum mechanics. Care is needed in defining an entropy S_bh corresponding to the number of microstates of a black hole, given that the black hole interacts with its surroundings. An open question is then the relationship between this entropy and the Bekenstein-Hawking entropy S_BH. For a wide class of models with interactions needed to ensure unitary quantum evolutio...

  20. A statistical mechanics approach to mixing in stratified fluids

    OpenAIRE

    Venaille , Antoine; Gostiaux , Louis; Sommeria , Joël

    2016-01-01

    Accepted for the Journal of Fluid Mechanics; Predicting how much mixing occurs when a given amount of energy is injected into a Boussinesq fluid is a longstanding problem in stratified turbulence. The huge number of degrees of freedom involved in these processes renders extremely difficult a deterministic approach to the problem. Here we present a statistical mechanics approach yielding a prediction for a cumulative, global mixing efficiency as a function of a global Richard-son number and th...

  1. Molecular dynamics and Monte Carlo calculations in statistical mechanics

    International Nuclear Information System (INIS)

    Wood, W.W.; Erpenbeck, J.J.

    1976-01-01

    Monte Carlo and molecular dynamics calculations on statistical mechanical systems is reviewed giving some of the more significant recent developments. It is noted that the term molecular dynamics refers to the time-averaging technique for hard-core and square-well interactions and for continuous force-law interactions. Ergodic questions, methodology, quantum mechanical, Lorentz, and one-dimensional, hard-core, and square and triangular-well systems, short-range soft potentials, and other systems are included. 268 references

  2. Continuum mechanics and thermodynamics in the Hamilton and the Godunov-type formulations

    Science.gov (United States)

    Peshkov, Ilya; Pavelka, Michal; Romenski, Evgeniy; Grmela, Miroslav

    2018-01-01

    Continuum mechanics with dislocations, with the Cattaneo-type heat conduction, with mass transfer, and with electromagnetic fields is put into the Hamiltonian form and into the form of the Godunov-type system of the first-order, symmetric hyperbolic partial differential equations (SHTC equations). The compatibility with thermodynamics of the time reversible part of the governing equations is mathematically expressed in the former formulation as degeneracy of the Hamiltonian structure and in the latter formulation as the existence of a companion conservation law. In both formulations the time irreversible part represents gradient dynamics. The Godunov-type formulation brings the mathematical rigor (the local well posedness of the Cauchy initial value problem) and the possibility to discretize while keeping the physical content of the governing equations (the Godunov finite volume discretization).

  3. SRB states and nonequilibrium statistical mechanics close to equilibrium

    OpenAIRE

    Gallavotti, Giovannni; Ruelle, David

    1996-01-01

    Nonequilibrium statistical mechanics close to equilibrium is studied using SRB states and a formula for their derivatives with respect to parameters. We write general expressions for the thermodynamic fluxes (or currents) and the transport coefficients, generalizing previous results. In this framework we give a general proof of the Onsager reciprocity relations.

  4. Two-dimensional models in statistical mechanics and field theory

    International Nuclear Information System (INIS)

    Koberle, R.

    1980-01-01

    Several features of two-dimensional models in statistical mechanics and Field theory, such as, lattice quantum chromodynamics, Z(N), Gross-Neveu and CP N-1 are discussed. The problems of confinement and dynamical mass generation are also analyzed. (L.C.) [pt

  5. Mathematics of statistical mechanics and the chaos theory

    International Nuclear Information System (INIS)

    Llave, R. de la; Haro, A.

    2000-01-01

    Statistical mechanics requires a language that unifies probabilistic and deterministic description of physical systems. We describe briefly some of the mathematical ideas needed for this unification. These ideas have also proved important in the study of chaotic systems. (Author) 17 refs

  6. Braid group, knot theory and statistical mechanics II

    CERN Document Server

    Yang Chen Ning

    1994-01-01

    The present volume is an updated version of the book edited by C N Yang and M L Ge on the topics of braid groups and knot theory, which are related to statistical mechanics. This book is based on the 1989 volume but has new material included and new contributors.

  7. Statistical mechanics and the evolution of polygenic quantitative traits

    NARCIS (Netherlands)

    Barton, N.H.; De Vladar, H.P.

    The evolution of quantitative characters depends on the frequencies of the alleles involved, yet these frequencies cannot usually be measured. Previous groups have proposed an approximation to the dynamics of quantitative traits, based on an analogy with statistical mechanics. We present a modified

  8. Grassmann methods in lattice field theory and statistical mechanics

    International Nuclear Information System (INIS)

    Bilgici, E.; Gattringer, C.; Huber, P.

    2006-01-01

    Full text: In two dimensions models of loops can be represented as simple Grassmann integrals. In our work we explore the generalization of these techniques to lattice field theories and statistical mechanic systems in three and four dimensions. We discuss possible strategies and applications for representations of loop and surface models as Grassmann integrals. (author)

  9. Geometry and topology in hamiltonian dynamics and statistical mechanics

    CERN Document Server

    Pettini, Marco

    2007-01-01

    Explores the foundations of hamiltonian dynamical systems and statistical mechanics, in particular phase transitions, from the point of view of geometry and topology. This book provides an overview of the research in the area. Using geometrical thinking to solve fundamental problems in these areas could be highly productive

  10. Statistical mechanics in the context of special relativity.

    Science.gov (United States)

    Kaniadakis, G

    2002-11-01

    In Ref. [Physica A 296, 405 (2001)], starting from the one parameter deformation of the exponential function exp(kappa)(x)=(sqrt[1+kappa(2)x(2)]+kappax)(1/kappa), a statistical mechanics has been constructed which reduces to the ordinary Boltzmann-Gibbs statistical mechanics as the deformation parameter kappa approaches to zero. The distribution f=exp(kappa)(-beta E+betamu) obtained within this statistical mechanics shows a power law tail and depends on the nonspecified parameter beta, containing all the information about the temperature of the system. On the other hand, the entropic form S(kappa)= integral d(3)p(c(kappa) f(1+kappa)+c(-kappa) f(1-kappa)), which after maximization produces the distribution f and reduces to the standard Boltzmann-Shannon entropy S0 as kappa-->0, contains the coefficient c(kappa) whose expression involves, beside the Boltzmann constant, another nonspecified parameter alpha. In the present effort we show that S(kappa) is the unique existing entropy obtained by a continuous deformation of S0 and preserving unaltered its fundamental properties of concavity, additivity, and extensivity. These properties of S(kappa) permit to determine unequivocally the values of the above mentioned parameters beta and alpha. Subsequently, we explain the origin of the deformation mechanism introduced by kappa and show that this deformation emerges naturally within the Einstein special relativity. Furthermore, we extend the theory in order to treat statistical systems in a time dependent and relativistic context. Then, we show that it is possible to determine in a self consistent scheme within the special relativity the values of the free parameter kappa which results to depend on the light speed c and reduces to zero as c--> infinity recovering in this way the ordinary statistical mechanics and thermodynamics. The statistical mechanics here presented, does not contain free parameters, preserves unaltered the mathematical and epistemological structure of

  11. The problem of phase transitions in statistical mechanics

    International Nuclear Information System (INIS)

    Martynov, Georgii A

    1999-01-01

    The first part of this review deals with the single-phase approach to the statistical theory of phase transitions. This approach is based on the assumption that a first-order phase transition is due to the loss of stability of the parent phase. We demonstrate that it is practically impossible to find the coordinates of the transition points using this criterion in the framework of the global Gibbs theory which describes the state of the entire macroscopic system. On the basis of the Ornstein-Zernike equation we formulate a local approach that analyzes the state of matter inside the correlation sphere of radius R c ∼ 10 A. This approach is proved to be as rigorous as the Gibbs theory. In the context of the local approach we formulate a criterion that allows finding the transition points without calculating the chemical potential and the pressure of the second conjugate phase. In the second part of the review we consider second-order phase transitions (critical phenomena). The Kadanoff-Wilson theory of critical phenomena is analyzed, based on the global Gibbs approach. Again we use the Ornstein-Zernike equation to formulate a local theory of critical phenomena. With regard to experimentally established quantities this theory yields precisely the same results as the Kadanoff-Wilson theory; secondly, the local approach allows the prediction of many previously unknown details of critical phenomena, and thirdly, the local approach paves the way for constructing a unified theory of liquids that will describe the behavior of matter not only in the regular domain of the phase diagram, but also at the critical point and in its vicinity. (reviews of topical problems)

  12. Fundamental link between system theory and statistical mechanics

    International Nuclear Information System (INIS)

    Atmanspacher, H.; Scheingraber, H.

    1987-01-01

    A fundamental link between system theory and statistical mechanics has been found to be established by the Kolmogorov entropy. By this quantity the temporal evolution of dynamical systems can be classified into regular, chaotic, and stochastic processes. Since K represents a measure for the internal information creation rate of dynamical systems, it provides an approach to irreversibility. The formal relationship to statistical mechanics is derived by means of an operator formalism originally introduced by Prigogine. For a Liouville operator L and an information operator M tilde acting on a distribution in phase space, it is shown that i[L, M tilde] = KI (I = identity operator). As a first consequence of this equivalence, a relation is obtained between the chaotic correlation time of a system and Prigogine's concept of a finite duration of presence. Finally, the existence of chaos in quantum systems is discussed with respect to the existence of a quantum mechanical time operator

  13. Statistical mechanics of two-dimensional and geophysical flows

    International Nuclear Information System (INIS)

    Bouchet, Freddy; Venaille, Antoine

    2012-01-01

    The theoretical study of the self-organization of two-dimensional and geophysical turbulent flows is addressed based on statistical mechanics methods. This review is a self-contained presentation of classical and recent works on this subject; from the statistical mechanics basis of the theory up to applications to Jupiter’s troposphere and ocean vortices and jets. Emphasize has been placed on examples with available analytical treatment in order to favor better understanding of the physics and dynamics. After a brief presentation of the 2D Euler and quasi-geostrophic equations, the specificity of two-dimensional and geophysical turbulence is emphasized. The equilibrium microcanonical measure is built from the Liouville theorem. Important statistical mechanics concepts (large deviations and mean field approach) and thermodynamic concepts (ensemble inequivalence and negative heat capacity) are briefly explained and described. On this theoretical basis, we predict the output of the long time evolution of complex turbulent flows as statistical equilibria. This is applied to make quantitative models of two-dimensional turbulence, the Great Red Spot and other Jovian vortices, ocean jets like the Gulf-Stream, and ocean vortices. A detailed comparison between these statistical equilibria and real flow observations is provided. We also present recent results for non-equilibrium situations, for the studies of either the relaxation towards equilibrium or non-equilibrium steady states. In this last case, forces and dissipation are in a statistical balance; fluxes of conserved quantity characterize the system and microcanonical or other equilibrium measures no longer describe the system.

  14. Statistical fracture mechanics approach to the strength of brittle rock

    International Nuclear Information System (INIS)

    Ratigan, J.L.

    1981-06-01

    Statistical fracture mechanics concepts used in the past for rock are critically reviewed and modifications are proposed which are warranted by (1) increased understanding of fracture provided by modern fracture mechanics and (2) laboratory test data both from the literature and from this research. Over 600 direct and indirect tension tests have been performed on three different rock types; Stripa Granite, Sierra White Granite and Carrara Marble. In several instances assumptions which are common in the literature were found to be invalid. A three parameter statistical fracture mechanics model with Mode I critical strain energy release rate as the variant is presented. Methodologies for evaluating the parameters in this model as well as the more commonly employed two parameter models are discussed. The experimental results and analysis of this research indicate that surfacially distributed flaws, rather than volumetrically distributed flaws are responsible for rupture in many testing situations. For several of the rock types tested, anisotropy (both in apparent tensile strength and size effect) precludes the use of contemporary statistical fracture mechanics models

  15. On the statistical-mechanical meaning of the Bousso bound

    International Nuclear Information System (INIS)

    Pesci, Alessandro

    2008-01-01

    The Bousso entropy bound, in its generalized form, is investigated for the case of perfect fluids at local thermodynamic equilibrium and evidence is found that the bound is satisfied if and only if a certain local thermodynamic property holds, emerging when the attempt is made to apply the bound to thin layers of matter. This property consists of the existence of an ultimate lower limit l* to the thickness of the slices for which a statistical-mechanical description is viable, depending l* on the thermodynamical variables which define the state of the system locally. This limiting scale, found to be in general much larger than the Planck scale (so that no Planck scale physics must be necessarily invoked to justify it), appears not related to gravity and this suggests that the generalized entropy bound is likely to be rooted on conventional flat-spacetime statistical mechanics, with the maximum admitted entropy being however actually determined also by gravity. Some examples of ideal fluids are considered in order to identify the mechanisms which can set a lower limit to the statistical-mechanical description and these systems are found to respect the lower limiting scale l*. The photon gas, in particular, appears to seemingly saturate this limiting scale and the consequence is drawn that for systems consisting of a single slice of a photon gas with thickness l*, the generalized Bousso bound is saturated. It is argued that this seems to open the way to a peculiar understanding of black hole entropy: if an entropy can meaningfully (i.e. with a second law) be assigned to a black hole, the value A/4 for it (where A is the area of the black hole) is required simply by (conventional) statistical mechanics coupled to general relativity

  16. A κ-generalized statistical mechanics approach to income analysis

    International Nuclear Information System (INIS)

    Clementi, F; Gallegati, M; Kaniadakis, G

    2009-01-01

    This paper proposes a statistical mechanics approach to the analysis of income distribution and inequality. A new distribution function, having its roots in the framework of κ-generalized statistics, is derived that is particularly suitable for describing the whole spectrum of incomes, from the low–middle income region up to the high income Pareto power-law regime. Analytical expressions for the shape, moments and some other basic statistical properties are given. Furthermore, several well-known econometric tools for measuring inequality, which all exist in a closed form, are considered. A method for parameter estimation is also discussed. The model is shown to fit remarkably well the data on personal income for the United States, and the analysis of inequality performed in terms of its parameters is revealed as very powerful

  17. A κ-generalized statistical mechanics approach to income analysis

    Science.gov (United States)

    Clementi, F.; Gallegati, M.; Kaniadakis, G.

    2009-02-01

    This paper proposes a statistical mechanics approach to the analysis of income distribution and inequality. A new distribution function, having its roots in the framework of κ-generalized statistics, is derived that is particularly suitable for describing the whole spectrum of incomes, from the low-middle income region up to the high income Pareto power-law regime. Analytical expressions for the shape, moments and some other basic statistical properties are given. Furthermore, several well-known econometric tools for measuring inequality, which all exist in a closed form, are considered. A method for parameter estimation is also discussed. The model is shown to fit remarkably well the data on personal income for the United States, and the analysis of inequality performed in terms of its parameters is revealed as very powerful.

  18. Statistical Mechanics Analysis of ATP Binding to a Multisubunit Enzyme

    International Nuclear Information System (INIS)

    Zhang Yun-Xin

    2014-01-01

    Due to inter-subunit communication, multisubunit enzymes usually hydrolyze ATP in a concerted fashion. However, so far the principle of this process remains poorly understood. In this study, from the viewpoint of statistical mechanics, a simple model is presented. In this model, we assume that the binding of ATP will change the potential of the corresponding enzyme subunit, and the degree of this change depends on the state of its adjacent subunits. The probability of enzyme in a given state satisfies the Boltzmann's distribution. Although it looks much simple, this model can fit the recent experimental data of chaperonin TRiC/CCT well. From this model, the dominant state of TRiC/CCT can be obtained. This study provide a new way to understand biophysical processe by statistical mechanics analysis. (interdisciplinary physics and related areas of science and technology)

  19. Generalized Statistical Mechanics at the Onset of Chaos

    Directory of Open Access Journals (Sweden)

    Alberto Robledo

    2013-11-01

    Full Text Available Transitions to chaos in archetypal low-dimensional nonlinear maps offer real and precise model systems in which to assess proposed generalizations of statistical mechanics. The known association of chaotic dynamics with the structure of Boltzmann–Gibbs (BG statistical mechanics has suggested the potential verification of these generalizations at the onset of chaos, when the only Lyapunov exponent vanishes and ergodic and mixing properties cease to hold. There are three well-known routes to chaos in these deterministic dissipative systems, period-doubling, quasi-periodicity and intermittency, which provide the setting in which to explore the limit of validity of the standard BG structure. It has been shown that there is a rich and intricate behavior for both the dynamics within and towards the attractors at the onset of chaos and that these two kinds of properties are linked via generalized statistical-mechanical expressions. Amongst the topics presented are: (i permanently growing sensitivity fluctuations and their infinite family of generalized Pesin identities; (ii the emergence of statistical-mechanical structures in the dynamics along the routes to chaos; (iii dynamical hierarchies with modular organization; and (iv limit distributions of sums of deterministic variables. The occurrence of generalized entropy properties in condensed-matter physical systems is illustrated by considering critical fluctuations, localization transition and glass formation. We complete our presentation with the description of the manifestations of the dynamics at the transitions to chaos in various kinds of complex systems, such as, frequency and size rank distributions and complex network images of time series. We discuss the results.

  20. Realistic thermodynamic and statistical-mechanical measures for neural synchronization.

    Science.gov (United States)

    Kim, Sang-Yoon; Lim, Woochang

    2014-04-15

    Synchronized brain rhythms, associated with diverse cognitive functions, have been observed in electrical recordings of brain activity. Neural synchronization may be well described by using the population-averaged global potential VG in computational neuroscience. The time-averaged fluctuation of VG plays the role of a "thermodynamic" order parameter O used for describing the synchrony-asynchrony transition in neural systems. Population spike synchronization may be well visualized in the raster plot of neural spikes. The degree of neural synchronization seen in the raster plot is well measured in terms of a "statistical-mechanical" spike-based measure Ms introduced by considering the occupation and the pacing patterns of spikes. The global potential VG is also used to give a reference global cycle for the calculation of Ms. Hence, VG becomes an important collective quantity because it is associated with calculation of both O and Ms. However, it is practically difficult to directly get VG in real experiments. To overcome this difficulty, instead of VG, we employ the instantaneous population spike rate (IPSR) which can be obtained in experiments, and develop realistic thermodynamic and statistical-mechanical measures, based on IPSR, to make practical characterization of the neural synchronization in both computational and experimental neuroscience. Particularly, more accurate characterization of weak sparse spike synchronization can be achieved in terms of realistic statistical-mechanical IPSR-based measure, in comparison with the conventional measure based on VG. Copyright © 2014. Published by Elsevier B.V.

  1. Statistical Mechanics of Disordered Systems - Series: Cambridge Series in Statistical and Probabilistic Mathematics (No. 18)

    Science.gov (United States)

    Bovier, Anton

    2006-06-01

    Our mathematical understanding of the statistical mechanics of disordered systems is going through a period of stunning progress. This self-contained book is a graduate-level introduction for mathematicians and for physicists interested in the mathematical foundations of the field, and can be used as a textbook for a two-semester course on mathematical statistical mechanics. It assumes only basic knowledge of classical physics and, on the mathematics side, a good working knowledge of graduate-level probability theory. The book starts with a concise introduction to statistical mechanics, proceeds to disordered lattice spin systems, and concludes with a presentation of the latest developments in the mathematical understanding of mean-field spin glass models. In particular, recent progress towards a rigorous understanding of the replica symmetry-breaking solutions of the Sherrington-Kirkpatrick spin glass models, due to Guerra, Aizenman-Sims-Starr and Talagrand, is reviewed in some detail. Comprehensive introduction to an active and fascinating area of research Clear exposition that builds to the state of the art in the mathematics of spin glasses Written by a well-known and active researcher in the field

  2. Compressional, mechanical and release properties of a novel gum in paracetamol tablet formulations

    Directory of Open Access Journals (Sweden)

    Adedokun Musiliu O.

    2014-09-01

    Full Text Available The binding properties of Eucalyptus gum obtained from the incised trunk of Eucalyptus tereticornis, were evaluated in paracetamol tablet formulations, in comparison with that of Gelatin B.P. In so doing, the compression properties were analyzed using density measurements and the compression equations of Heckel, Kawakita and Gurham. In our work, the mechanical properties of the tablets were assessed using the crushing strength and friability of the tablets, while the drug release properties of the tablets were assessed using disintegration and dissolution times. The results of the study reveal that tablet formulations incorporating Eucalyptus gum as binder, exhibited faster onset and higher amount of plastic deformation during compression than those containing gelatin. What is more, the Gurnham equation could be used as a substitute for the Kawakita equation in describing the compression properties of pharmaceutical tablets. Furthermore, the crushing strength, disintegration and dissolution times of the tablets increased with binder concentration, while friability values decreased. We noted that no significant differences in properties exist between formulations derived from the two binders (p > 0.05 exist. While tablets incorporating gelatin exhibited higher values for mechanical properties, Eucalyptus gum tablets had better balance between mechanical and release properties - as seen from the CSFR/Dt values. Tablets of good mechanical and release properties were prepared using Eucalyptus gum as a binder, and, therefore, it could serve as an alternative binder in producing tablets with good mechanical strength and fast drug release.

  3. Sustained release biodegradable solid lipid microparticles: Formulation, evaluation and statistical optimization by response surface methodology

    Directory of Open Access Journals (Sweden)

    Hanif Muhammad

    2017-12-01

    Full Text Available For preparing nebivolol loaded solid lipid microparticles (SLMs by the solvent evaporation microencapsulation process from carnauba wax and glyceryl monostearate, central composite design was used to study the impact of independent variables on yield (Y1, entrapment efficiency (Y2 and drug release (Y3. SLMs having a 10-40 μm size range, with good rheological behavior and spherical smooth surfaces, were produced. Fourier transform infrared spectroscopy, differential scanning calorimetry and X-ray diffractometry pointed to compatibility between formulation components and the zeta-potential study confirmed better stability due to the presence of negative charge (-20 to -40 mV. The obtained outcomes for Y1 (29-86 %, Y2 (45-83 % and Y3 (49-86 % were analyzed by polynomial equations and the suggested quadratic model were validated. Nebivolol release from SLMs at pH 1.2 and 6.8 was significantly (p 0.85 value (Korsmeyer- Peppas suggested slow erosion along with diffusion. The optimized SLMs have the potential to improve nebivolol oral bioavailability.

  4. Sustained release biodegradable solid lipid microparticles: Formulation, evaluation and statistical optimization by response surface methodology.

    Science.gov (United States)

    Hanif, Muhammad; Khan, Hafeez Ullah; Afzal, Samina; Mahmood, Asif; Maheen, Safirah; Afzal, Khurram; Iqbal, Nabila; Andleeb, Mehwish; Abbas, Nazar

    2017-12-20

    For preparing nebivolol loaded solid lipid microparticles (SLMs) by the solvent evaporation microencapsulation process from carnauba wax and glyceryl monostearate, central composite design was used to study the impact of independent variables on yield (Y1), entrapment efficiency (Y2) and drug release (Y3). SLMs having a 10-40 μm size range, with good rheological behavior and spherical smooth surfaces, were produced. Fourier transform infrared spectroscopy, differential scanning calorimetry and X-ray diffractometry pointed to compatibility between formulation components and the zeta-potential study confirmed better stability due to the presence of negative charge (-20 to -40 mV). The obtained outcomes for Y1 (29-86 %), Y2 (45-83 %) and Y3 (49-86 %) were analyzed by polynomial equations and the suggested quadratic model were validated. Nebivolol release from SLMs at pH 1.2 and 6.8 was significantly (p 0.85 value (Korsmeyer- Peppas) suggested slow erosion along with diffusion. The optimized SLMs have the potential to improve nebivolol oral bioavailability.

  5. Introduction to nonequilibrium statistical mechanics with quantum field theory

    International Nuclear Information System (INIS)

    Kita, Takafumi

    2010-01-01

    In this article, we present a concise and self-contained introduction to nonequilibrium statistical mechanics with quantum field theory by considering an ensemble of interacting identical bosons or fermions as an example. Readers are assumed to be familiar with the Matsubara formalism of equilibrium statistical mechanics such as Feynman diagrams, the proper self-energy, and Dyson's equation. The aims are threefold: (1) to explain the fundamentals of nonequilibrium quantum field theory as simple as possible on the basis of the knowledge of the equilibrium counterpart; (2) to elucidate the hierarchy in describing nonequilibrium systems from Dyson's equation on the Keldysh contour to the Navier-Stokes equation in fluid mechanics via quantum transport equations and the Boltzmann equation; (3) to derive an expression of nonequilibrium entropy that evolves with time. In stage (1), we introduce nonequilibrium Green's function and the self-energy uniquely on the round-trip Keldysh contour, thereby avoiding possible confusions that may arise from defining multiple Green's functions at the very beginning. We try to present the Feynman rules for the perturbation expansion as simple as possible. In particular, we focus on the self-consistent perturbation expansion with the Luttinger-Ward thermodynamic functional, i.e., Baym's Φ-derivable approximation, which has a crucial property for nonequilibrium systems of obeying various conservation laws automatically. We also show how the two-particle correlations can be calculated within the Φ-derivable approximation, i.e., an issue of how to handle the 'Bogoliubov-Born-Green-Kirkwood-Yvons (BBGKY) hierarchy'. Aim (2) is performed through successive reductions of relevant variables with the Wigner transformation, the gradient expansion based on the Groenewold-Moyal product, and Enskog's expansion from local equilibrium. This part may be helpful for convincing readers that nonequilibrium systems can be handled microscopically with

  6. Alternative derivations of the statistical mechanical distribution laws.

    Science.gov (United States)

    Wall, F T

    1971-08-01

    A new approach is presented for the derivation of statistical mechanical distribution laws. The derivations are accomplished by minimizing the Helmholtz free energy under constant temperature and volume, instead of maximizing the entropy under constant energy and volume. An alternative method involves stipulating equality of chemical potential, or equality of activity, for particles in different energy levels. This approach leads to a general statement of distribution laws applicable to all systems for which thermodynamic probabilities can be written. The methods also avoid use of the calculus of variations, Lagrangian multipliers, and Stirling's approximation for the factorial. The results are applied specifically to Boltzmann, Fermi-Dirac, and Bose-Einstein statistics. The special significance of chemical potential and activity is discussed for microscopic systems.

  7. Is quantum theory a form of statistical mechanics?

    Science.gov (United States)

    Adler, S. L.

    2007-05-01

    We give a review of the basic themes of my recent book: Adler S L 2004 Quantum Theory as an Emergent Phenomenon (Cambridge: Cambridge University Press). We first give motivations for considering the possibility that quantum mechanics is not exact, but is instead an accurate asymptotic approximation to a deeper level theory. For this deeper level, we propose a non-commutative generalization of classical mechanics, that we call "trace dynamics", and we give a brief survey of how it works, considering for simplicity only the bosonic case. We then discuss the statistical mechanics of trace dynamics and give our argument that with suitable approximations, the Ward identities for trace dynamics imply that ensemble averages in the canonical ensemble correspond to Wightman functions in quantum field theory. Thus, quantum theory emerges as the statistical thermodynamics of trace dynamics. Finally, we argue that Brownian motion corrections to this thermodynamics lead to stochastic corrections to the Schrödinger equation, of the type that have been much studied in the "continuous spontaneous localization" model of objective state vector reduction. In appendices to the talk, we give details of the existence of a conserved operator in trace dynamics that encodes the structure of the canonical algebra, of the derivation of the Ward identities, and of the proof that the stochastically-modified Schrödinger equation leads to state vector reduction with Born rule probabilities.

  8. Statistical mechanical analysis of LMFBR fuel cladding tubes

    International Nuclear Information System (INIS)

    Poncelet, J.-P.; Pay, A.

    1977-01-01

    The most important design requirement on fuel pin cladding for LMFBR's is its mechanical integrity. Disruptive factors include internal pressure from mixed oxide fuel fission gas release, thermal stresses and high temperature creep, neutron-induced differential void-swelling as a source of stress in the cladding and irradiation creep of stainless steel material, corrosion by fission products. Under irradiation these load-restraining mechanisms are accentuated by stainless steel embrittlement and strength alterations. To account for the numerous uncertainties involved in the analysis by theoretical models and computer codes statistical tools are unavoidably requested, i.e. Monte Carlo simulation methods. Thanks to these techniques, uncertainties in nominal characteristics, material properties and environmental conditions can be linked up in a correct way and used for a more accurate conceptual design. First, a thermal creep damage index is set up through a sufficiently sophisticated clad physical analysis including arbitrary time dependence of power and neutron flux as well as effects of sodium temperature, burnup and steel mechanical behavior. Although this strain limit approach implies a more general but time consuming model., on the counterpart the net output is improved and e.g. clad temperature, stress and strain maxima may be easily assessed. A full spectrum of variables are statistically treated to account for their probability distributions. Creep damage probability may be obtained and can contribute to a quantitative fuel probability estimation

  9. Representative volume size: A comparison of statistical continuum mechanics and statistical physics

    Energy Technology Data Exchange (ETDEWEB)

    AIDUN,JOHN B.; TRUCANO,TIMOTHY G.; LO,CHI S.; FYE,RICHARD M.

    1999-05-01

    In this combination background and position paper, the authors argue that careful work is needed to develop accurate methods for relating the results of fine-scale numerical simulations of material processes to meaningful values of macroscopic properties for use in constitutive models suitable for finite element solid mechanics simulations. To provide a definite context for this discussion, the problem is couched in terms of the lack of general objective criteria for identifying the size of the representative volume (RV) of a material. The objective of this report is to lay out at least the beginnings of an approach for applying results and methods from statistical physics to develop concepts and tools necessary for determining the RV size, as well as alternatives to RV volume-averaging for situations in which the RV is unmanageably large. The background necessary to understand the pertinent issues and statistical physics concepts is presented.

  10. An alternative formulation of classical mechanics based on an analogy with thermodynamics

    International Nuclear Information System (INIS)

    Teruel, Ginés R Pérez

    2013-01-01

    We study new Legendre transforms in classical mechanics and investigate some of their general properties. The behaviour of the new functions is analysed under coordinate transformations. When invariance under different kinds of transformations is considered the new formulation is found to be completely equivalent to the usual Lagrangian formulation, recovering well-established results such as conservation of angular momentum. Furthermore, a natural generalization of the Poisson bracket is found to be inherent to the formalism introduced. On the other hand, we find that with a convenient redefinition of the Lagrangian, L ' =-L, it is possible to establish an exact one-to-one mathematical correspondence between the thermodynamic potentials and the new potentials of classical mechanics. (paper)

  11. Statistical mechanics of sensing and communications: Insights and techniques

    International Nuclear Information System (INIS)

    Murayama, T; Davis, P

    2008-01-01

    In this article we review a basic model for analysis of large sensor networks from the point of view of collective estimation under bandwidth constraints. We compare different sensing aggregation levels as alternative 'strategies' for collective estimation: moderate aggregation from a moderate number of sensors for which communication bandwidth is enough that data encoding can be reversible, and large scale aggregation from very many sensors - in which case communication bandwidth constraints require the use of nonreversible encoding. We show the non-trivial trade-off between sensing quality, which can be increased by increasing the number of sensors, and communication quality under bandwidth constraints, which decreases if the number of sensors is too large. From a practical standpoint, we verify that such a trade-off exists in constructively defined communications schemes. We introduce a probabilistic encoding scheme and define rate distortion models that are suitable for analysis of the large network limit. Our description shows that the methods and ideas from statistical physics can play an important role in formulating effective models for such schemes

  12. A Look Behind the Salt Curve: An Examination of Thickening Mechanisms in Shampoo Formulations

    Science.gov (United States)

    Penfield, Kevin

    2008-07-01

    Dynamic oscillatory rheological measurements are used to examine two mechanisms for thickening simple shampoo formulations. The salt curve, in which viscosity of a surfactant solution is maximized at intermediate levels of salt, is shown to be due to the variation in relaxation time; this is found to correlate with variation in the degree of entanglement per micelle. This is contrasted with the effect of PEG-150 distearate, which alters viscosity through a change in modulus.

  13. Nonequilibrium statistical mechanics and stochastic thermodynamics of small systems

    International Nuclear Information System (INIS)

    Tu Zhanchun

    2014-01-01

    Thermodynamics is an old subject. The research objects in conventional thermodynamics are macroscopic systems with huge number of particles. In recent 30 years, thermodynamics of small systems is a frontier topic in physics. Here we introduce nonequilibrium statistical mechanics and stochastic thermodynamics of small systems. As a case study, we construct a Canot-like cycle of a stochastic heat engine with a single particle controlled by a time-dependent harmonic potential. We find that the efficiency at maximum power is 1 - √T c /T h , where Tc and Th are the temperatures of cold bath and hot bath, respectively. (author)

  14. Statistical mechanics of attractor neural network models with synaptic depression

    International Nuclear Information System (INIS)

    Igarashi, Yasuhiko; Oizumi, Masafumi; Otsubo, Yosuke; Nagata, Kenji; Okada, Masato

    2009-01-01

    Synaptic depression is known to control gain for presynaptic inputs. Since cortical neurons receive thousands of presynaptic inputs, and their outputs are fed into thousands of other neurons, the synaptic depression should influence macroscopic properties of neural networks. We employ simple neural network models to explore the macroscopic effects of synaptic depression. Systems with the synaptic depression cannot be analyzed due to asymmetry of connections with the conventional equilibrium statistical-mechanical approach. Thus, we first propose a microscopic dynamical mean field theory. Next, we derive macroscopic steady state equations and discuss the stabilities of steady states for various types of neural network models.

  15. From inverse problems to learning: a Statistical Mechanics approach

    Science.gov (United States)

    Baldassi, Carlo; Gerace, Federica; Saglietti, Luca; Zecchina, Riccardo

    2018-01-01

    We present a brief introduction to the statistical mechanics approaches for the study of inverse problems in data science. We then provide concrete new results on inferring couplings from sampled configurations in systems characterized by an extensive number of stable attractors in the low temperature regime. We also show how these result are connected to the problem of learning with realistic weak signals in computational neuroscience. Our techniques and algorithms rely on advanced mean-field methods developed in the context of disordered systems.

  16. Statistical mechanics of socio-economic systems with heterogeneous agents

    International Nuclear Information System (INIS)

    De Martino, Andrea; Marsili, Matteo

    2006-01-01

    We review the statistical mechanics approach to the study of the emerging collective behaviour of systems of heterogeneous interacting agents. The general framework is presented through examples in such contexts as ecosystem dynamics and traffic modelling. We then focus on the analysis of the optimal properties of large random resource-allocation problems and on Minority Games and related models of speculative trading in financial markets, discussing a number of extensions including multi-asset models, majority games and models with asymmetric information. Finally, we summarize the main conclusions and outline the major open problems and limitations of the approach. (topical review)

  17. Statistical mechanical analysis of LMFBR fuel cladding tubes

    International Nuclear Information System (INIS)

    Poncelet, J.-P.; Pay, A.

    1977-01-01

    The most important design requirement on fuel pin cladding for LMFBR's is its mechanical integrity. Disruptive factors include internal pressure from mixed oxide fuel fission gas release, thermal stresses and high temperature creep, neutron-induced differential void-swelling as a source of stress in the cladding and irradiation creep of stainless steel material, corrosion by fission products. Under irradiation these load-restraining mechanisms are accentuated by stainless steel embrittlement and strength alterations. To account for the numerous uncertainties involved in the analysis by theoretical models and computer codes statistical tools are unavoidably requested, i.e. Monte Carlo simulation methods. Thanks to these techniques, uncertainties in nominal characteristics, material properties and environmental conditions can be linked up in a correct way and used for a more accurate conceptual design. (Auth.)

  18. Multiple-shock initiation via statistical crack mechanics

    Energy Technology Data Exchange (ETDEWEB)

    Dienes, J.K.; Kershner, J.D.

    1998-12-31

    Statistical Crack Mechanics (SCRAM) is a theoretical approach to the behavior of brittle materials that accounts for the behavior of an ensemble of microcracks, including their opening, shear, growth, and coalescence. Mechanical parameters are based on measured strain-softening behavior. In applications to explosive and propellant sensitivity it is assumed that closed cracks act as hot spots, and that the heating due to interfacial friction initiates reactions which are modeled as one-dimensional heat flow with an Arrhenius source term, and computed in a subscale grid. Post-ignition behavior of hot spots is treated with the burn model of Ward, Son and Brewster. Numerical calculations using SCRAM-HYDROX are compared with the multiple-shock experiments of Mulford et al. in which the particle velocity in PBX 9501 is measured with embedded wires, and reactions are initiated and quenched.

  19. Quantum mechanics as classical statistical mechanics with an ontic extension and an epistemic restriction.

    Science.gov (United States)

    Budiyono, Agung; Rohrlich, Daniel

    2017-11-03

    Where does quantum mechanics part ways with classical mechanics? How does quantum randomness differ fundamentally from classical randomness? We cannot fully explain how the theories differ until we can derive them within a single axiomatic framework, allowing an unambiguous account of how one theory is the limit of the other. Here we derive non-relativistic quantum mechanics and classical statistical mechanics within a common framework. The common axioms include conservation of average energy and conservation of probability current. But two axioms distinguish quantum mechanics from classical statistical mechanics: an "ontic extension" defines a nonseparable (global) random variable that generates physical correlations, and an "epistemic restriction" constrains allowed phase space distributions. The ontic extension and epistemic restriction, with strength on the order of Planck's constant, imply quantum entanglement and uncertainty relations. This framework suggests that the wave function is epistemic, yet it does not provide an ontic dynamics for individual systems.

  20. A Gleason-Type Theorem for Any Dimension Based on a Gambling Formulation of Quantum Mechanics

    Science.gov (United States)

    Benavoli, Alessio; Facchini, Alessandro; Zaffalon, Marco

    2017-07-01

    Based on a gambling formulation of quantum mechanics, we derive a Gleason-type theorem that holds for any dimension n of a quantum system, and in particular for n=2. The theorem states that the only logically consistent probability assignments are exactly the ones that are definable as the trace of the product of a projector and a density matrix operator. In addition, we detail the reason why dispersion-free probabilities are actually not valid, or rational, probabilities for quantum mechanics, and hence should be excluded from consideration.

  1. Statistical mechanics in the context of special relativity. II.

    Science.gov (United States)

    Kaniadakis, G

    2005-09-01

    The special relativity laws emerge as one-parameter (light speed) generalizations of the corresponding laws of classical physics. These generalizations, imposed by the Lorentz transformations, affect both the definition of the various physical observables (e.g., momentum, energy, etc.), as well as the mathematical apparatus of the theory. Here, following the general lines of [Phys. Rev. E 66, 056125 (2002)], we show that the Lorentz transformations impose also a proper one-parameter generalization of the classical Boltzmann-Gibbs-Shannon entropy. The obtained relativistic entropy permits us to construct a coherent and self-consistent relativistic statistical theory, preserving the main features of the ordinary statistical theory, which is recovered in the classical limit. The predicted distribution function is a one-parameter continuous deformation of the classical Maxwell-Boltzmann distribution and has a simple analytic form, showing power law tails in accordance with the experimental evidence. Furthermore, this statistical mechanics can be obtained as the stationary case of a generalized kinetic theory governed by an evolution equation obeying the H theorem and reproducing the Boltzmann equation of the ordinary kinetics in the classical limit.

  2. Statistical mechanics of the vertex-cover problem

    Science.gov (United States)

    Hartmann, Alexander K.; Weigt, Martin

    2003-10-01

    We review recent progress in the study of the vertex-cover problem (VC). The VC belongs to the class of NP-complete graph theoretical problems, which plays a central role in theoretical computer science. On ensembles of random graphs, VC exhibits a coverable-uncoverable phase transition. Very close to this transition, depending on the solution algorithm, easy-hard transitions in the typical running time of the algorithms occur. We explain a statistical mechanics approach, which works by mapping the VC to a hard-core lattice gas, and then applying techniques such as the replica trick or the cavity approach. Using these methods, the phase diagram of the VC could be obtained exactly for connectivities c e, the solution of the VC exhibits full replica symmetry breaking. The statistical mechanics approach can also be used to study analytically the typical running time of simple complete and incomplete algorithms for the VC. Finally, we describe recent results for the VC when studied on other ensembles of finite- and infinite-dimensional graphs.

  3. Statistical mechanics of the vertex-cover problem

    International Nuclear Information System (INIS)

    Hartmann, Alexander K; Weigt, Martin

    2003-01-01

    We review recent progress in the study of the vertex-cover problem (VC). The VC belongs to the class of NP-complete graph theoretical problems, which plays a central role in theoretical computer science. On ensembles of random graphs, VC exhibits a coverable-uncoverable phase transition. Very close to this transition, depending on the solution algorithm, easy-hard transitions in the typical running time of the algorithms occur. We explain a statistical mechanics approach, which works by mapping the VC to a hard-core lattice gas, and then applying techniques such as the replica trick or the cavity approach. Using these methods, the phase diagram of the VC could be obtained exactly for connectivities c e, the solution of the VC exhibits full replica symmetry breaking. The statistical mechanics approach can also be used to study analytically the typical running time of simple complete and incomplete algorithms for the VC. Finally, we describe recent results for the VC when studied on other ensembles of finite- and infinite-dimensional graphs

  4. Statistical mechanics of learning orthogonal signals for general covariance models

    International Nuclear Information System (INIS)

    Hoyle, David C

    2010-01-01

    Statistical mechanics techniques have proved to be useful tools in quantifying the accuracy with which signal vectors are extracted from experimental data. However, analysis has previously been limited to specific model forms for the population covariance C, which may be inappropriate for real world data sets. In this paper we obtain new statistical mechanical results for a general population covariance matrix C. For data sets consisting of p sample points in R N we use the replica method to study the accuracy of orthogonal signal vectors estimated from the sample data. In the asymptotic limit of N,p→∞ at fixed α = p/N, we derive analytical results for the signal direction learning curves. In the asymptotic limit the learning curves follow a single universal form, each displaying a retarded learning transition. An explicit formula for the location of the retarded learning transition is obtained and we find marked variation in the location of the retarded learning transition dependent on the distribution of population covariance eigenvalues. The results of the replica analysis are confirmed against simulation

  5. Statistical learning: a powerful mechanism that operates by mere exposure.

    Science.gov (United States)

    Aslin, Richard N

    2017-01-01

    How do infants learn so rapidly and with little apparent effort? In 1996, Saffran, Aslin, and Newport reported that 8-month-old human infants could learn the underlying temporal structure of a stream of speech syllables after only 2 min of passive listening. This demonstration of what was called statistical learning, involving no instruction, reinforcement, or feedback, led to dozens of confirmations of this powerful mechanism of implicit learning in a variety of modalities, domains, and species. These findings reveal that infants are not nearly as dependent on explicit forms of instruction as we might have assumed from studies of learning in which children or adults are taught facts such as math or problem solving skills. Instead, at least in some domains, infants soak up the information around them by mere exposure. Learning and development in these domains thus appear to occur automatically and with little active involvement by an instructor (parent or teacher). The details of this statistical learning mechanism are discussed, including how exposure to specific types of information can, under some circumstances, generalize to never-before-observed information, thereby enabling transfer of learning. WIREs Cogn Sci 2017, 8:e1373. doi: 10.1002/wcs.1373 For further resources related to this article, please visit the WIREs website. © 2016 Wiley Periodicals, Inc.

  6. Formulation and optimization of chronomodulated press-coated tablet of carvedilol by Box–Behnken statistical design

    Directory of Open Access Journals (Sweden)

    Satwara RS

    2012-08-01

    Full Text Available Rohan S Satwara, Parul K PatelDepartment of Pharmaceutics, Babaria Institute of Pharmacy, Vadodara, Gujarat, IndiaObjective: The primary objective of the present investigation was to formulate and optimize chronomodulated press-coated tablets to deliver the antihypertensive carvedilol at an effective quantity predawn, when a blood pressure spike is typically observed in most hypertensive patients.Experimental work: Preformulation studies and drug excipient compatibility studies were carried out for carvedilol and excipients. Core tablets (6 mm containing carvedilol and 10-mm press-coated tablets were prepared by direct compression. The Box–Behnken experimental design was applied to these press-coated tablets (F1–F15 formula with differing concentrations of rate-controlling polymers. Hydroxypropyl methyl cellulose K4M, ethyl cellulose, and K-carrageenan were used as rate-controlling polymers in the outer layer. These tablets were subjected to various precompression and postcompression tests. The optimized batch was derived both by statistically (using desirability function and graphically (using Design Expert® 8; Stat-Ease Inc. Tablets formulated using the optimized formulas were then evaluated for lag time and in vitro dissolution.Results and discussion: Results of preformulation studies were satisfactory. No interaction was observed between carvedilol and excipients by ultraviolet, Fourier transform infrared spectroscopy, and dynamic light scattering analysis. The results of precompression studies and postcompression studies were within limits. The varying lag time and percent cumulative carvedilol release after 8 h was optimized to obtain a formulation that offered a release profile with 6 h lag time, followed by complete carvedilol release after 8 h. The results showed no significant bias between predicted response and actual response for the optimized formula.Conclusion: Bedtime dosing of chronomodulated press-coated tablets may offer a

  7. Statistical methods in the mechanical design of fuel assemblies

    Energy Technology Data Exchange (ETDEWEB)

    Radsak, C.; Streit, D.; Muench, C.J. [AREVA NP GmbH, Erlangen (Germany)

    2013-07-01

    The mechanical design of a fuel assembly is still being mainly performed in a de terministic way. This conservative approach is however not suitable to provide a realistic quantification of the design margins with respect to licensing criter ia for more and more demanding operating conditions (power upgrades, burnup increase,..). This quantification can be provided by statistical methods utilizing all available information (e.g. from manufacturing, experience feedback etc.) of the topic under consideration. During optimization e.g. of the holddown system certain objectives in the mechanical design of a fuel assembly (FA) can contradict each other, such as sufficient holddown forces enough to prevent fuel assembly lift-off and reducing the holddown forces to minimize axial loads on the fuel assembly structure to ensure no negative effect on the control rod movement.By u sing a statistical method the fuel assembly design can be optimized much better with respect to these objectives than it would be possible based on a deterministic approach. This leads to a more realistic assessment and safer way of operating fuel assemblies. Statistical models are defined on the one hand by the quanti le that has to be maintained concerning the design limit requirements (e.g. one FA quantile) and on the other hand by the confidence level which has to be met. Using the above example of the holddown force, a feasible quantile can be define d based on the requirement that less than one fuel assembly (quantile > 192/19 3 [%] = 99.5 %) in the core violates the holddown force limit w ith a confidence of 95%. (orig.)

  8. Vaccine instability in the cold chain: mechanisms, analysis and formulation strategies.

    Science.gov (United States)

    Kumru, Ozan S; Joshi, Sangeeta B; Smith, Dawn E; Middaugh, C Russell; Prusik, Ted; Volkin, David B

    2014-09-01

    Instability of vaccines often emerges as a key challenge during clinical development (lab to clinic) as well as commercial distribution (factory to patient). To yield stable, efficacious vaccine dosage forms for human use, successful formulation strategies must address a combination of interrelated topics including stabilization of antigens, selection of appropriate adjuvants, and development of stability-indicating analytical methods. This review covers key concepts in understanding the causes and mechanisms of vaccine instability including (1) the complex and delicate nature of antigen structures (e.g., viruses, proteins, carbohydrates, protein-carbohydrate conjugates, etc.), (2) use of adjuvants to further enhance immune responses, (3) development of physicochemical and biological assays to assess vaccine integrity and potency, and (4) stabilization strategies to protect vaccine antigens and adjuvants (and their interactions) during storage. Despite these challenges, vaccines can usually be sufficiently stabilized for use as medicines through a combination of formulation approaches combined with maintenance of an efficient cold chain (manufacturing, distribution, storage and administration). Several illustrative case studies are described regarding mechanisms of vaccine instability along with formulation approaches for stabilization within the vaccine cold chain. These include live, attenuated (measles, polio) and inactivated (influenza, polio) viral vaccines as well as recombinant protein (hepatitis B) vaccines. Copyright © 2014 The Authors. Published by Elsevier Ltd.. All rights reserved.

  9. Effect of formulation of alginate beads on their mechanical behavior and stiffness

    Institute of Scientific and Technical Information of China (English)

    Eng-Seng Chan; Tek-Kaun Lim; Wan-Ping Voo; Ravindra Pogaku; Beng Ti Tey; Zhibing Zhang

    2011-01-01

    The aim of this work was to determine the effect of formulation of alginate beads on their mechanical behavior and stiffness when compressed at high speed. The alginate beads were formulated using different types and concentrations of alginate and gelling cations and were produced using an extrusiondripping method. Single wet beads were compressed at a speed of 40 mm/min, and their elastic limits were investigated, and the corresponding force versus displacement data were obtained. The Young's moduli of the beads were determined from the force versus displacement data using the Hertz's contact mechanics theory. The alginate beads were found to exhibit plastic behavior when they were compressed beyond 50% with the exception of copper-alginate beads for which yield occured at lower deformation.Alginate beads made of higher guluronic acid contents and gelling cations of higher chemical affinity were found to have greater stiffness. Increasing the concentration of alginate and gelling ions also generated a similar effect. At such a compression speed, the values of Young's modulus of the beads were found to be in the range between 250 and 900 kPa depending on the bead formulation.

  10. Why irreversibility? The formulation of classical and quantum mechanics for nonintegrable systems

    International Nuclear Information System (INIS)

    Prigogine, I.

    1995-01-01

    Nonintegrable Poincare systems with a continuous spectrum lead to the appearance of diffusive terms in the frame of classical or quantum dynamics. These terms break time symmetry. They lead, therefore, to limitations to classical trajectory theory and of wave-function formalism. These diffusive terms correspond to well-defined classes of dynamical processes. The diffusive effects are amplified in situations corresponding to persistent interactions. As a result, we have to include, already, in the fundamental dynamical description the two basic aspects, probability and irreversibility, which are so conspicuous on the macroscopic level. We have to formulate both classical and quantum mechanics on the Liouville level of probability distributions. For integrable systems, we recover the usual formulation of classical or quantum mechanics. Instead of being primitive concepts, which cannot be further analyzed, trajectories and wave functions appear as special solutions of the Liouville-von Neumann equations. This extension of classical and quantum dynamics permits us to unify the two concepts of nature that we inherited from the nineteenth century, based, on the one hand, on dynamical time-reversible laws and, on the other, on an evolutionary view associated to entropy. It leads also to a unified formulation of quantum theory, avoiding the conventional dual structure based on Schroedinger's equation, on the one hand, and on the open-quotes collapseclose quotes of the wave function, on the other. A dynamical interpretation is given to processes such as decoherence or approach to equilibrium without any appeal to extra dynamic considerations. There is a striking parallelism between classical and quantum theory. For large Poincare systems (LPS), we have, in general, both a open-quotes collapseclose quotes of trajectories and of wave functions. In both cases, we need a generalized formulation of dynamics in terms of probability distributions or density matrices

  11. Some aspects of the formulation of alginate dental impression materials--setting characteristics and mechanical properties.

    Science.gov (United States)

    Nallamuthu, Navina A; Braden, Michael; Patel, Mangala P

    2012-07-01

    To study the role of the various components of alginate dental impression materials. Experimental materials were formulated and their physical properties characterized and compared to commercially available counterparts (Neocolloid, Palgat Plus and Blueprint Cremix). Properties examined were: dimensional stability and weight change in water and artificial saliva; setting behavior; Shore A hardness and tear energy. The role of magnesium oxide was also investigated. Weight changes in water and artificial saliva can be attributed to an initial thermodynamic potential owing to the ionic content of the alginate, causing water to diffuse into the material. Water is then driven back out following a reversal of this potential. Hardness results for experimental materials were within the range obtained from the commercial materials. The hardness value for an experimental formulation that did not contain magnesium oxide was lower than values from the other experimental materials that did. Tear energies for all three experimental materials were greater than those of the commercial products. There were statistically significant differences between the two experimental materials that contained magnesium oxide and one that did not. With regard to setting time, statistically significant differences were seen between commercial materials and two of the experimental materials. The experimental material that did not contain magnesium oxide had a considerably longer setting time than all of the other materials tested. The key role of magnesium oxide in the setting reaction and the effect on hardness have been demonstrated and discussed. Copyright © 2012 Academy of Dental Materials. Published by Elsevier Ltd. All rights reserved.

  12. From statistic mechanic outside equilibrium to transport equations

    International Nuclear Information System (INIS)

    Balian, R.

    1995-01-01

    This lecture notes give a synthetic view on the foundations of non-equilibrium statistical mechanics. The purpose is to establish the transport equations satisfied by the relevant variables, starting from the microscopic dynamics. The Liouville representation is introduced, and a projection associates with any density operator , for given choice of relevant observables, a reduced density operator. An exact integral-differential equation for the relevant variables is thereby derived. A short-memory approximation then yields the transport equations. A relevant entropy which characterizes the coarseness of the description is associated with each level of description. As an illustration, the classical gas, with its three levels of description and with the Chapman-Enskog method, is discussed. (author). 3 figs., 5 refs

  13. Statistical mechanics of lattice systems a concrete mathematical introduction

    CERN Document Server

    Friedli, Sacha

    2017-01-01

    This motivating textbook gives a friendly, rigorous introduction to fundamental concepts in equilibrium statistical mechanics, covering a selection of specific models, including the Curie–Weiss and Ising models, the Gaussian free field, O(n) models, and models with Kać interactions. Using classical concepts such as Gibbs measures, pressure, free energy, and entropy, the book exposes the main features of the classical description of large systems in equilibrium, in particular the central problem of phase transitions. It treats such important topics as the Peierls argument, the Dobrushin uniqueness, Mermin–Wagner and Lee–Yang theorems, and develops from scratch such workhorses as correlation inequalities, the cluster expansion, Pirogov–Sinai Theory, and reflection positivity. Written as a self-contained course for advanced undergraduate or beginning graduate students, the detailed explanations, large collection of exercises (with solutions), and appendix of mathematical results and concepts also make i...

  14. Statistical mechanics analysis of LDPC coding in MIMO Gaussian channels

    Energy Technology Data Exchange (ETDEWEB)

    Alamino, Roberto C; Saad, David [Neural Computing Research Group, Aston University, Birmingham B4 7ET (United Kingdom)

    2007-10-12

    Using analytical methods of statistical mechanics, we analyse the typical behaviour of a multiple-input multiple-output (MIMO) Gaussian channel with binary inputs under low-density parity-check (LDPC) network coding and joint decoding. The saddle point equations for the replica symmetric solution are found in particular realizations of this channel, including a small and large number of transmitters and receivers. In particular, we examine the cases of a single transmitter, a single receiver and symmetric and asymmetric interference. Both dynamical and thermodynamical transitions from the ferromagnetic solution of perfect decoding to a non-ferromagnetic solution are identified for the cases considered, marking the practical and theoretical limits of the system under the current coding scheme. Numerical results are provided, showing the typical level of improvement/deterioration achieved with respect to the single transmitter/receiver result, for the various cases.

  15. Statistical mechanics analysis of LDPC coding in MIMO Gaussian channels

    International Nuclear Information System (INIS)

    Alamino, Roberto C; Saad, David

    2007-01-01

    Using analytical methods of statistical mechanics, we analyse the typical behaviour of a multiple-input multiple-output (MIMO) Gaussian channel with binary inputs under low-density parity-check (LDPC) network coding and joint decoding. The saddle point equations for the replica symmetric solution are found in particular realizations of this channel, including a small and large number of transmitters and receivers. In particular, we examine the cases of a single transmitter, a single receiver and symmetric and asymmetric interference. Both dynamical and thermodynamical transitions from the ferromagnetic solution of perfect decoding to a non-ferromagnetic solution are identified for the cases considered, marking the practical and theoretical limits of the system under the current coding scheme. Numerical results are provided, showing the typical level of improvement/deterioration achieved with respect to the single transmitter/receiver result, for the various cases

  16. Statistical mechanics of the fashion game on random networks

    International Nuclear Information System (INIS)

    Sun, YiFan

    2016-01-01

    A model of fashion on networks is studied. This model consists of two groups of agents that are located on a network and have opposite viewpoints towards being fashionable: behaving consistently with either the majority or the minority of adjacent agents. Checking whether the fashion game has a pure Nash equilibrium (pure NE) is a non-deterministic polynomial complete problem. Using replica-symmetric mean field theory, the largest proportion of satisfied agents and the region where at least one pure NE should exist are determined for several types of random networks. Furthermore, a quantitive analysis of the asynchronous best response dynamics yields the phase diagram of existence and detectability of pure NE in the fashion game on some random networks. (paper: classical statistical mechanics, equilibrium and non-equilibrium).

  17. Statistical mechanics of sparse generalization and graphical model selection

    International Nuclear Information System (INIS)

    Lage-Castellanos, Alejandro; Pagnani, Andrea; Weigt, Martin

    2009-01-01

    One of the crucial tasks in many inference problems is the extraction of an underlying sparse graphical model from a given number of high-dimensional measurements. In machine learning, this is frequently achieved using, as a penalty term, the L p norm of the model parameters, with p≤1 for efficient dilution. Here we propose a statistical mechanics analysis of the problem in the setting of perceptron memorization and generalization. Using a replica approach, we are able to evaluate the relative performance of naive dilution (obtained by learning without dilution, following by applying a threshold to the model parameters), L 1 dilution (which is frequently used in convex optimization) and L 0 dilution (which is optimal but computationally hard to implement). Whereas both L p diluted approaches clearly outperform the naive approach, we find a small region where L 0 works almost perfectly and strongly outperforms the simpler to implement L 1 dilution

  18. Anomalous behavior of q-averages in nonextensive statistical mechanics

    International Nuclear Information System (INIS)

    Abe, Sumiyoshi

    2009-01-01

    A generalized definition of average, termed the q-average, is widely employed in the field of nonextensive statistical mechanics. Recently, it has however been pointed out that such an average value may behave unphysically under specific deformations of probability distributions. Here, the following three issues are discussed and clarified. Firstly, the deformations considered are physical and may be realized experimentally. Secondly, in view of the thermostatistics, the q-average is unstable in both finite and infinite discrete systems. Thirdly, a naive generalization of the discussion to continuous systems misses a point, and a norm better than the L 1 -norm should be employed for measuring the distance between two probability distributions. Consequently, stability of the q-average is shown not to be established in all of the cases

  19. Statistical mechanics of the interacting Yang-Mills instanton gas

    International Nuclear Information System (INIS)

    Ilgenfritz, E.-M.; Mueller-Preussker, M.

    1980-01-01

    Within the framework of the dilute gas approximation the instanton gas with dipole-like interaction is studied, including hard-core repulsion necessarily implied by the consistency of this approximation. A new, selfconsistent scheme is obtained of instanton calculations provided by a cooperative suppression of large instantons instead of the usual ad hoc infrared cut-off. Diluteness is better under control by a single, regularization prescription independent parameter. Functional methods known from statistical mechanics are used to treat the hard-core and dipole interactions simultaneously. The permeability of the instanton gas is calculated and used to discuss the Gell-Mann-Low β-function in the intermediate coupling range. The results are confronted with recent lattice calculations

  20. On the statistical mechanics of species abundance distributions.

    Science.gov (United States)

    Bowler, Michael G; Kelly, Colleen K

    2012-09-01

    A central issue in ecology is that of the factors determining the relative abundance of species within a natural community. The proper application of the principles of statistical physics to species abundance distributions (SADs) shows that simple ecological properties could account for the near universal features observed. These properties are (i) a limit on the number of individuals in an ecological guild and (ii) per capita birth and death rates. They underpin the neutral theory of Hubbell (2001), the master equation approach of Volkov et al. (2003, 2005) and the idiosyncratic (extreme niche) theory of Pueyo et al. (2007); they result in an underlying log series SAD, regardless of neutral or niche dynamics. The success of statistical mechanics in this application implies that communities are in dynamic equilibrium and hence that niches must be flexible and that temporal fluctuations on all sorts of scales are likely to be important in community structure. Copyright © 2012 Elsevier Inc. All rights reserved.

  1. Shrinkage / stress reduction and mechanical properties improvement in restorative composites formulated with thio-urethane oligomers.

    Science.gov (United States)

    Bacchi, Atais; Yih, Jonathan A; Platta, Jacqueline; Knight, Joseph; Pfeifer, Carmem S

    2018-02-01

    Thio-urethane oligomers (TUs) have been shown to favorably modify methacrylate networks to reduce stress and significantly increase fracture toughness. Since those are very desirable features in dental applications, the objective of this work was to characterize restorative composites formulated with the addition of TUs. TUs were synthesized by combining thiols - pentaerythritol tetra-3-mercaptopropionate (PETMP) or trimethylol-tris-3-mercaptopropionate (TMP) - with isocyanates - 1,6-Hexanediol-diissocyante (HDDI) (aliphatic) or 1,3-bis(1-isocyanato-1-methylethyl)benzene (BDI) (aromatic) or dicyclohexylmethane 4,4'-Diisocyanate (HMDI) (cyclic), at 1:2 isocyanate:thiol, leaving pendant thiols. 20wt% TU were added to BisGMA-TEGDMA (70-30%). To this organic matrix, 70wt% silanated inorganic fillers were added. Near-IR was used to follow methacrylate conversion and rate of polymerization (Rp max ). Mechanical properties were evaluated in three-point bending (ISO 4049) for flexural strength/modulus (FS/FM) and toughness (T), and notched specimens (ASTM Standard E399-90) for fracture toughness (K IC ). Polymerization stress (PS) was measured on the Bioman. Volumetric shrinkage (VS) was measured with the bonded disk technique. Glass transition temperature (Tg) and heterogeneity of network were obtained with dynamic mechanical analysis. The addition of TUs led to an increase in mechanical properties (except for Tg and FS). Fracture toughness ranged from 1.6-1.94MPam 1/2 for TU-modified groups, an increase of 33-61% in relation to the control (1.21 ± 0.1MPam 1/2 ). Toughness showed a two-fold increase in relation to the control: from 0.91MPa to values ranging from 1.70-1.95MPa. Flexural modulus was statistically higher for the TU-modified groups. The Tg, as expected, decreased for all TU groups due to the greater flexibility imparted to the network (which also explains the increase in toughness and fracture toughness). Narrower tan-delta peaks suggest more homogeneous

  2. An adhesive contact mechanics formulation based on atomistically induced surface traction

    Energy Technology Data Exchange (ETDEWEB)

    Fan, Houfu [Department of Civil and Environmental Engineering, University of California, Berkeley, CA 94720 (United States); Ren, Bo [Livermore Software Technology Corporation, 7374 Las Positas Road, Livermore, CA 94551 (United States); Li, Shaofan, E-mail: shaofan@berkeley.edu [Department of Civil and Environmental Engineering, University of California, Berkeley, CA 94720 (United States)

    2015-12-01

    In this work, we have developed a novel multiscale computational contact formulation based on the generalized Derjuguin approximation for continua that are characterized by atomistically enriched constitutive relations in order to study macroscopic interaction between arbitrarily shaped deformable continua. The proposed adhesive contact formulation makes use of the microscopic interaction forces between individual particles in the interacting bodies. In particular, the double-layer volume integral describing the contact interaction (energy, force vector, matrix) is converted into a double-layer surface integral through a mathematically consistent approach that employs the divergence theorem and a special partitioning technique. The proposed contact model is formulated in the nonlinear continuum mechanics framework and implemented using the standard finite element method. With no large penalty constant, the stiffness matrix of the system will in general be well-conditioned, which is of great significance for quasi-static analysis. Three numerical examples are presented to illustrate the capability of the proposed method. Results indicate that with the same mesh configuration, the finite element computation based on the surface integral approach is faster and more accurate than the volume integral based approach. In addition, the proposed approach is energy preserving even in a very long dynamic simulation.

  3. Statistical mechanics view of quantum chromodynamics: Lattice gauge theory

    International Nuclear Information System (INIS)

    Kogut, J.B.

    1984-01-01

    Recent developments in lattice gauge theory are discussed from a statistial mechanics viewpoint. The basic physics problems of quantum chromodynamics (QCD) are reviewed for an audience of critical phenomena theorists. The idea of local gauge symmetry and color, the connection between statistical mechanics and field theory, asymptotic freedom and the continuum limit of lattice gauge theories, and the order parameters (confinement and chiral symmetry) of QCD are reviewed. Then recent developments in the field are discussed. These include the proof of confinement in the lattice theory, numerical evidence for confinement in the continuum limit of lattice gauge theory, and perturbative improvement programs for lattice actions. Next, we turn to the new challenges facing the subject. These include the need for a better understanding of the lattice Dirac equation and recent progress in the development of numerical methods for fermions (the pseudofermion stochastic algorithm and the microcanonical, molecular dynamics equation of motion approach). Finally, some of the applications of lattice gauge theory to QCD spectrum calculations and the thermodynamics of QCD will be discussed and a few remarks concerning future directions of the field will be made

  4. Conceptual developments of non-equilibrium statistical mechanics in the early days of Japan

    Science.gov (United States)

    Ichiyanagi, Masakazu

    1995-11-01

    This paper reviews the research in nonequilibrium statistical mechanics made in Japan in the period between 1930 and 1960. Nearly thirty years have passed since the discovery of the exact formula for the electrical conductivity. With the rise of the linear response theory, the methods and results of which are quickly grasped by anyone, its rationale was pushed aside and even at the stage where the formulation was still incomplete some authors hurried to make physical applications. Such an attitude robbed it of most of its interest for the average physicist, who would approach an understanding of some basic concept, not through abstract and logical analysis but by simply increasing his technical experiences with the concept. The purpose of this review is to rescue the linear response theory from being labeled a mathematical tool and to show that it has considerable physical content. Many key papers, originally written in Japanese, are reproduced.

  5. Statistical characteristics of mechanical heart valve cavitation in accelerated testing.

    Science.gov (United States)

    Wu, Changfu; Hwang, Ned H C; Lin, Yu-Kweng M

    2004-07-01

    Cavitation damage has been observed on mechanical heart valves (MHVs) undergoing accelerated testing. Cavitation itself can be modeled as a stochastic process, as it varies from beat to beat of the testing machine. This in-vitro study was undertaken to investigate the statistical characteristics of MHV cavitation. A 25-mm St. Jude Medical bileaflet MHV (SJM 25) was tested in an accelerated tester at various pulse rates, ranging from 300 to 1,000 bpm, with stepwise increments of 100 bpm. A miniature pressure transducer was placed near a leaflet tip on the inflow side of the valve, to monitor regional transient pressure fluctuations at instants of valve closure. The pressure trace associated with each beat was passed through a 70 kHz high-pass digital filter to extract the high-frequency oscillation (HFO) components resulting from the collapse of cavitation bubbles. Three intensity-related measures were calculated for each HFO burst: its time span; its local root-mean-square (LRMS) value; and the area enveloped by the absolute value of the HFO pressure trace and the time axis, referred to as cavitation impulse. These were treated as stochastic processes, of which the first-order probability density functions (PDFs) were estimated for each test rate. Both the LRMS value and cavitation impulse were log-normal distributed, and the time span was normal distributed. These distribution laws were consistent at different test rates. The present investigation was directed at understanding MHV cavitation as a stochastic process. The results provide a basis for establishing further the statistical relationship between cavitation intensity and time-evolving cavitation damage on MHV surfaces. These data are required to assess and compare the performance of MHVs of different designs.

  6. The role of angular momentum conservation law in statistical mechanics

    Directory of Open Access Journals (Sweden)

    I.M. Dubrovskii

    2008-12-01

    Full Text Available Within the limits of Khinchin ideas [A.Y. Khinchin, Mathematical Foundation of Statistical Mechanics. NY, Ed. Dover, 1949] the importance of momentum and angular momentum conservation laws was analyzed for two cases: for uniform magnetic field and when magnetic field is absent. The law of momentum conservation does not change the density of probability distribution in both cases, just as it is assumed in the conventional theory. It is shown that in systems where the kinetic energy depends only on particle momenta canonically conjugated with Cartesian coordinates being their diagonal quadric form,the angular momentum conservation law changes the density of distribution of the system only in case the full angular momentum of a system is not equal to zero. In the gas of charged particles in a uniform magnetic field the density of distribution also varies if the angular momentum is zero [see Dubrovskii I.M., Condensed Matter Physics, 2206, 9, 23]. Two-dimensional gas of charged particles located within a section of an endless strip filled with gas in magnetic field is considered. Under such conditions the angular momentum is not conserved. Directional particle flows take place close to the strip boundaries, and, as a consequence, the phase trajectory of the considered set of particles does not remain within the limited volume of the phase space. In order to apply a statistical thermodynamics method, it was suggested to consider near-boundary trajectories relative to a reference system that moves uniformly. It was shown that if the diameter of an orbit having average thermal energy is much smaller than a strip width, the corrections to thermodynamic functions are small depending on magnetic field. Only the average velocity of near-boundary particles that form near-boundary electric currents creating the paramagnetic moment turn out to be essential.

  7. Intercomparison of chemical mechanisms for air quality policy formulation and assessment under North American conditions.

    Science.gov (United States)

    Derwent, Richard

    2017-07-01

    The intercomparison of seven chemical mechanisms for their suitability for air quality policy formulation and assessment is described. Box modeling techniques were employed using 44 sets of background environmental conditions covering North America to constrain the chemical development of the longer lived species. The selected mechanisms were modified to enable an unbiased assessment of the adequacy of the parameterizations of photochemical ozone production from volatile organic compound (VOC) oxidation in the presence of NO x . Photochemical ozone production rates responded differently to 30% NO x and VOC reductions with the different mechanisms, despite the striking similarities between the base-case ozone production rates. The 30% reductions in NO x and VOCs also produced changes in OH. The responses in OH to 30% reductions in NO x and VOCs appeared to be more sensitive to mechanism choice, compared with the responses in the photochemical ozone production rates. Although 30% NO x reductions generally led to decreases in OH, 30% reductions in VOCs led to increases in OH, irrespective of mechanism choice and background environmental conditions. The different mechanisms therefore gave different OH responses to NO x and VOC reductions and so would give different responses in terms of changes in the fate and behavior of air toxics, acidification and eutrophication, and fine particle formation compared with others, in response to ozone control strategies. Policymakers need to understand that there are likely to be inherent differences in the responses to ozone control strategies between different mechanisms, depending on background environmental conditions and the extents of NO x and VOC reductions under consideration. The purpose of this paper is to compare predicted ozone responses to NO x and VOC reductions with seven chemical mechanisms under North American conditions. The good agreement found between the tested mechanisms should provide some support for their

  8. On the geometry of the spin-statistics connection in quantum mechanics

    Energy Technology Data Exchange (ETDEWEB)

    Reyes, A.

    2006-07-01

    The Spin-Statistics theorem states that the statistics of a system of identical particles is determined by their spin: Particles of integer spin are Bosons (i.e. obey Bose-Einstein statistics), whereas particles of half-integer spin are Fermions (i.e. obey Fermi-Dirac statistics). Since the original proof by Fierz and Pauli, it has been known that the connection between Spin and Statistics follows from the general principles of relativistic Quantum Field Theory. In spite of this, there are different approaches to Spin-Statistics and it is not clear whether the theorem holds under assumptions that are different, and even less restrictive, than the usual ones (e.g. Lorentz-covariance). Additionally, in Quantum Mechanics there is a deep relation between indistinguishability and the geometry of the configuration space. This is clearly illustrated by Gibbs' paradox. Therefore, for many years efforts have been made in order to find a geometric proof of the connection between Spin and Statistics. Recently, various proposals have been put forward, in which an attempt is made to derive the Spin-Statistics connection from assumptions different from the ones used in the relativistic, quantum field theoretic proofs. Among these, there is the one due to Berry and Robbins (BR), based on the postulation of a certain single-valuedness condition, that has caused a renewed interest in the problem. In the present thesis, we consider the problem of indistinguishability in Quantum Mechanics from a geometric-algebraic point of view. An approach is developed to study configuration spaces Q having a finite fundamental group, that allows us to describe different geometric structures of Q in terms of spaces of functions on the universal cover of Q. In particular, it is shown that the space of complex continuous functions over the universal cover of Q admits a decomposition into C(Q)-submodules, labelled by the irreducible representations of the fundamental group of Q, that can be

  9. Statistical mechanics of normal grain growth in one dimension: A partial integro-differential equation model

    International Nuclear Information System (INIS)

    Ng, Felix S.L.

    2016-01-01

    We develop a statistical-mechanical model of one-dimensional normal grain growth that does not require any drift-velocity parameterization for grain size, such as used in the continuity equation of traditional mean-field theories. The model tracks the population by considering grain sizes in neighbour pairs; the probability of a pair having neighbours of certain sizes is determined by the size-frequency distribution of all pairs. Accordingly, the evolution obeys a partial integro-differential equation (PIDE) over ‘grain size versus neighbour grain size’ space, so that the grain-size distribution is a projection of the PIDE's solution. This model, which is applicable before as well as after statistically self-similar grain growth has been reached, shows that the traditional continuity equation is invalid outside this state. During statistically self-similar growth, the PIDE correctly predicts the coarsening rate, invariant grain-size distribution and spatial grain size correlations observed in direct simulations. The PIDE is then reducible to the standard continuity equation, and we derive an explicit expression for the drift velocity. It should be possible to formulate similar parameterization-free models of normal grain growth in two and three dimensions.

  10. Application of statistical experimental design to study the formulation variables influencing the coating process of lidocaine liposomes.

    Science.gov (United States)

    González-Rodríguez, M L; Barros, L B; Palma, J; González-Rodríguez, P L; Rabasco, A M

    2007-06-07

    In this paper, we have used statistical experimental design to investigate the effect of several factors in coating process of lidocaine hydrochloride (LID) liposomes by a biodegradable polymer (chitosan, CH). These variables were the concentration of CH coating solution, the dripping rate of this solution on the liposome colloidal dispersion, the stirring rate, the time since the liposome production to the liposome coating and finally the amount of drug entrapped into liposomes. The selected response variables were drug encapsulation efficiency (EE, %), coating efficiency (CE, %) and zeta potential. Liposomes were obtained by thin-layer evaporation method. They were subsequently coated with CH according the experimental plan provided by a fractional factorial (2(5-1)) screening matrix. We have used spectroscopic methods to determine the zeta potential values. The EE (%) assay was carried out in dialysis bags and the brilliant red probe was used to determine CE (%) due to its property of forming molecular complexes with CH. The graphic analysis of the effects allowed the identification of the main formulation and technological factors by the analysis of the selected responses and permitted the determination of the proper level of these factors for the response improvement. Moreover, fractional design allowed quantifying the interactions between the factors, which will consider in next experiments. The results obtained pointed out that LID amount was the predominant factor that increased the drug entrapment capacity (EE). The CE (%) response was mainly affected by the concentration of the CH solution and the stirring rate, although all the interactions between the main factors have statistical significance.

  11. A unified treatment of dynamics and scattering in classical and quantum statistical mechanics

    International Nuclear Information System (INIS)

    Prugovecki, E.

    1978-01-01

    The common formal features of classical and quantum statistical mechanics are investigated at three separate levels: at the level of L 2 spaces of wave-packets on GAMMA-space, of Liouville spaces B 2 consisting of density operators constructed from such wave-packets, and of phase-space representation spaces P of GAMMA distribution functions. It is shown that at the last level the formal similarities become so outstanding that all key quantities in P-space, such as Liouville operators, Hamiltonian functions, position and momentum observables, etc., are represented by expressions which to the zeroth order in (h/2π) coincide in the classical and quantum case, and in some instances coincide completely. Scattering theory on the B 2 Liouville spaces takes on the same formal appearance for classical and quantum statistical mechanics, and to the zeroth order in (h/2π) it coincides in both cases. This makes possible the formulation of a classical approximation to quantum scattering, and of a computational scheme for determining rhosup(out) from rhosup(in) for successive order of (h/2π). (Auth.)

  12. Statistical-Mechanical Analysis of Pre-training and Fine Tuning in Deep Learning

    Science.gov (United States)

    Ohzeki, Masayuki

    2015-03-01

    In this paper, we present a statistical-mechanical analysis of deep learning. We elucidate some of the essential components of deep learning — pre-training by unsupervised learning and fine tuning by supervised learning. We formulate the extraction of features from the training data as a margin criterion in a high-dimensional feature-vector space. The self-organized classifier is then supplied with small amounts of labelled data, as in deep learning. Although we employ a simple single-layer perceptron model, rather than directly analyzing a multi-layer neural network, we find a nontrivial phase transition that is dependent on the number of unlabelled data in the generalization error of the resultant classifier. In this sense, we evaluate the efficacy of the unsupervised learning component of deep learning. The analysis is performed by the replica method, which is a sophisticated tool in statistical mechanics. We validate our result in the manner of deep learning, using a simple iterative algorithm to learn the weight vector on the basis of belief propagation.

  13. Statistical mechanics of high-density bond percolation

    Science.gov (United States)

    Timonin, P. N.

    2018-05-01

    High-density (HD) percolation describes the percolation of specific κ -clusters, which are the compact sets of sites each connected to κ nearest filled sites at least. It takes place in the classical patterns of independently distributed sites or bonds in which the ordinary percolation transition also exists. Hence, the study of series of κ -type HD percolations amounts to the description of classical clusters' structure for which κ -clusters constitute κ -cores nested one into another. Such data are needed for description of a number of physical, biological, and information properties of complex systems on random lattices, graphs, and networks. They range from magnetic properties of semiconductor alloys to anomalies in supercooled water and clustering in biological and social networks. Here we present the statistical mechanics approach to study HD bond percolation on an arbitrary graph. It is shown that the generating function for κ -clusters' size distribution can be obtained from the partition function of the specific q -state Potts-Ising model in the q →1 limit. Using this approach we find exact κ -clusters' size distributions for the Bethe lattice and Erdos-Renyi graph. The application of the method to Euclidean lattices is also discussed.

  14. Nonextensive statistical mechanics: a brief review of its present status

    Directory of Open Access Journals (Sweden)

    CONSTANTINO TSALLIS

    2002-09-01

    Full Text Available We briefly review the present status of nonextensive statistical mechanics. We focus on (i the central equations of the formalism, (ii the most recent applications in physics and other sciences, (iii the a priori determination (from microscopic dynamics of the entropic index q for two important classes of physical systems, namely low-dimensional maps (both dissipative and conservative and long-range interacting many-body hamiltonian classical systems.Revisamos sumariamente o estado presente da mecânica estatística não-extensiva. Focalizamos em (i as equacões centrais do formalismo; (ii as aplicações mais recentes na física e em outras ciências, (iii a determinação a priori (da dinâmica microscópica do índice entrópico q para duas classes importantes de sistemas físicos, a saber, mapas de baixa dimensão (tanto dissipativos quanto conservativos e sistemas clássicos hamiltonianos de muitos corpos com interações de longo alcance.

  15. Universal biology and the statistical mechanics of early life

    Science.gov (United States)

    Goldenfeld, Nigel; Biancalani, Tommaso; Jafarpour, Farshid

    2017-11-01

    All known life on the Earth exhibits at least two non-trivial common features: the canonical genetic code and biological homochirality, both of which emerged prior to the Last Universal Common Ancestor state. This article describes recent efforts to provide a narrative of this epoch using tools from statistical mechanics. During the emergence of self-replicating life far from equilibrium in a period of chemical evolution, minimal models of autocatalysis show that homochirality would have necessarily co-evolved along with the efficiency of early-life self-replicators. Dynamical system models of the evolution of the genetic code must explain its universality and its highly refined error-minimization properties. These have both been accounted for in a scenario where life arose from a collective, networked phase where there was no notion of species and perhaps even individuality itself. We show how this phase ultimately terminated during an event sometimes known as the Darwinian transition, leading to the present epoch of tree-like vertical descent of organismal lineages. These examples illustrate concrete examples of universal biology: the quest for a fundamental understanding of the basic properties of living systems, independent of precise instantiation in chemistry or other media. This article is part of the themed issue 'Reconceptualizing the origins of life'.

  16. The statistical mechanics of vortex-acoustic ion wave turbulence

    International Nuclear Information System (INIS)

    Giles, M.J.

    1980-01-01

    The equilibrium statistical mechanics of electrostatic ion wave turbulence is studied within the framework of a continuum ion flow with adiabatic electrons. The wave field consists in general of two components, namely ion-acoustic and ion vortex modes. It is shown that the latter can significantly affect the equilibria on account of their ability both to emit and to scatter ion sound. Exact equilibria for the vortex-acoustic wave field are given in terms of a canonical distribution and the correlation functions are expressed in terms of a generating functional. Detailed calculations are carried out for the case in which the dominant coupling is an indirect interaction of the vortex modes mediated by the sound field. An equation for the spectrum of the vortex modes is obtained for this case, which is shown to possess a simple exact solution. This solution shows that the spectrum of fluctuations changes considerably as the total energy increases. Condensed vortex states could occur in the plasma sheet of the earth's magnetosphere and it is shown that the predicted ratio of the mean ion energy to the mean electron energy is consistent with the trend of observed values. (author)

  17. Statistical mechanics and stability of random lattice field theory

    International Nuclear Information System (INIS)

    Baskaran, G.

    1984-01-01

    The averaging procedure in the random lattice field theory is studied by viewing it as a statistical mechanics of a system of classical particles. The corresponding thermodynamic phase is shown to determine the random lattice configuration which contributes dominantly to the generating function. The non-abelian gauge theory in four (space plus time) dimensions in the annealed and quenched averaging versions is shown to exist as an ideal classical gas, implying that macroscopically homogeneous configurations dominate the configurational averaging. For the free massless scalar field theory with O(n) global symmetry, in the annealed average, the pressure becomes negative for dimensions greater than two when n exceeds a critical number. This implies that macroscopically inhomogeneous collapsed configurations contribute dominantly. In the quenched averaging, the collapse of the massless scalar field theory is prevented and the system becomes an ideal gas which is at infinite temperature. Our results are obtained using exact scaling analysis. We also show approximately that SU(N) gauge theory collapses for dimensions greater than four in the annealed average. Within the same approximation, the collapse is prevented in the quenched average. We also obtain exact scaling differential equations satisfied by the generating function and physical quantities. (orig.)

  18. Statistical mechanics approach to 1-bit compressed sensing

    International Nuclear Information System (INIS)

    Xu, Yingying; Kabashima, Yoshiyuki

    2013-01-01

    Compressed sensing is a framework that makes it possible to recover an N-dimensional sparse vector x∈R N from its linear transformation y∈R M of lower dimensionality M 1 -norm-based signal recovery scheme for 1-bit compressed sensing using statistical mechanics methods. We show that the signal recovery performance predicted by the replica method under the replica symmetric ansatz, which turns out to be locally unstable for modes breaking the replica symmetry, is in good consistency with experimental results of an approximate recovery algorithm developed earlier. This suggests that the l 1 -based recovery problem typically has many local optima of a similar recovery accuracy, which can be achieved by the approximate algorithm. We also develop another approximate recovery algorithm inspired by the cavity method. Numerical experiments show that when the density of nonzero entries in the original signal is relatively large the new algorithm offers better performance than the abovementioned scheme and does so with a lower computational cost. (paper)

  19. A Simulational approach to teaching statistical mechanics and kinetic theory

    International Nuclear Information System (INIS)

    Karabulut, H.

    2005-01-01

    A computer simulation demonstrating how Maxwell-Boltzmann distribution is reached in gases from a nonequilibrium distribution is presented. The algorithm can be generalized to the cases of gas particles (atoms or molecules) with internal degrees of freedom such as electronic excitations and vibrational-rotational energy levels. Another generalization of the algorithm is the case of mixture of two different gases. By choosing the collision cross sections properly one can create quasi equilibrium distributions. For example by choosing same atom cross sections large and different atom cross sections very small one can create mixture of two gases with different temperatures where two gases slowly interact and come to equilibrium in a long time. Similarly, for the case one kind of atom with internal degrees of freedom one can create situations that internal degrees of freedom come to the equilibrium much later than translational degrees of freedom. In all these cases the equilibrium distribution that the algorithm gives is the same as expected from the statistical mechanics. The algorithm can also be extended to cover the case of chemical equilibrium where species A and B react to form AB molecules. The laws of chemical equilibrium can be observed from this simulation. The chemical equilibrium simulation can also help to teach the elusive concept of chemical potential

  20. An Introduction to Thermodynamics and Statistical Mechanics - 2nd Edition

    Science.gov (United States)

    Stowe, Keith

    2003-03-01

    This introductory textbook for standard undergraduate courses in thermodynamics has been completely rewritten. Starting with an overview of important quantum behaviours, the book teaches students how to calculate probabilities, in order to provide a firm foundation for later chapters. It introduces the ideas of classical thermodynamics and explores them both in general and as they are applied to specific processes and interactions. The remainder of the book deals with statistical mechanics - the study of small systems interacting with huge reservoirs. The changes to this second edition have been made after more than 10 years classroom testing and student feedback. Each topic ends with a boxed summary of ideas and results, and every chapter contains numerous homework problems, covering a broad range of difficulties. Answers are given to odd numbered problems, and solutions to even problems are available to instructors at www.cambridge.org/9780521865579. The entire book has been re-written and now covers more topics It has a greater number of homework problems which range in difficulty from warm-ups to challenges It is concise and has an easy reading style

  1. Relationship between the generalized equivalent uniform dose formulation and the Poisson statistics-based tumor control probability model

    International Nuclear Information System (INIS)

    Zhou Sumin; Das, Shiva; Wang Zhiheng; Marks, Lawrence B.

    2004-01-01

    The generalized equivalent uniform dose (GEUD) model uses a power-law formalism, where the outcome is related to the dose via a power law. We herein investigate the mathematical compatibility between this GEUD model and the Poisson statistics based tumor control probability (TCP) model. The GEUD and TCP formulations are combined and subjected to a compatibility constraint equation. This compatibility constraint equates tumor control probability from the original heterogeneous target dose distribution to that from the homogeneous dose from the GEUD formalism. It is shown that this constraint equation possesses a unique, analytical closed-form solution which relates radiation dose to the tumor cell survival fraction. It is further demonstrated that, when there is no positive threshold or finite critical dose in the tumor response to radiation, this relationship is not bounded within the realistic cell survival limits of 0%-100%. Thus, the GEUD and TCP formalisms are, in general, mathematically inconsistent. However, when a threshold dose or finite critical dose exists in the tumor response to radiation, there is a unique mathematical solution for the tumor cell survival fraction that allows the GEUD and TCP formalisms to coexist, provided that all portions of the tumor are confined within certain specific dose ranges

  2. Finite Elements Based on Strong and Weak Formulations for Structural Mechanics: Stability, Accuracy and Reliability

    Directory of Open Access Journals (Sweden)

    Francesco Tornabene

    2017-07-01

    Full Text Available The authors are presenting a novel formulation based on the Differential Quadrature (DQ method which is used to approximate derivatives and integrals. The resulting scheme has been termed strong and weak form finite elements (SFEM or WFEM, according to the numerical scheme employed in the computation. Such numerical methods are applied to solve some structural problems related to the mechanical behavior of plates and shells, made of isotropic or composite materials. The main differences between these two approaches rely on the initial formulation – which is strong or weak (variational – and the implementation of the boundary conditions, that for the former include the continuity of stresses and displacements, whereas in the latter can consider the continuity of the displacements or both. The two methodologies consider also a mapping technique to transform an element of general shape described in Cartesian coordinates into the same element in the computational space. Such technique can be implemented by employing the classic Lagrangian-shaped elements with a fixed number of nodes along the element edges or blending functions which allow an “exact mapping” of the element. In particular, the authors are employing NURBS (Not-Uniform Rational B-Splines for such nonlinear mapping in order to use the “exact” shape of CAD designs.

  3. Electrochemical mechanism and kinetics studies of haloperidol and its assay in commercial formulations

    Energy Technology Data Exchange (ETDEWEB)

    Ribeiro, Francisco W.P. [Departamento de Quimica Analitica e Fisico-Quimica, Centro de Ciencias, Universidade Federal do Ceara, Bloco 940 Campus do Pici 60455-970, Fortaleza, CE (Brazil); Soares, Janete E.S. [Departamento de Farmacia, Faculdade de Farmacia, Odontologia e Enfermagem, Universidade Federal do Ceara, Rua Capitao Francisco Pedro, 1210 Rodolfo Teofilo 60430-370, Fortaleza, CE (Brazil); Becker, Helena; De Souza, Djenaine; Lima-Neto, Pedro de [Departamento de Quimica Analitica e Fisico-Quimica, Centro de Ciencias, Universidade Federal do Ceara, Bloco 940 Campus do Pici 60455-970, Fortaleza, CE (Brazil); Correia, Adriana N., E-mail: adriana@ufc.b [Departamento de Quimica Analitica e Fisico-Quimica, Centro de Ciencias, Universidade Federal do Ceara, Bloco 940 Campus do Pici 60455-970, Fortaleza, CE (Brazil)

    2011-02-01

    The kinetics and mechanism for electrochemical reduction of haloperidol, a psychotherapeutic drug used in the treatment of schizophrenia, were studied using square wave and cyclic voltammetries allied to a hanging mercury drop electrode. The experimental and voltammetric parameters were optimized at 0.04 mol L{sup -1} Brinton-Robinson buffer (pH 10), with a pulse potential frequency of 100 s{sup -1}, a pulse amplitude of 30 mV and scan increment of 2 mV. Two well-defined peaks were observed, which exhibited properties of fast electron transfer with a strong adsorption process of reactants and products on the electrode surface. The first peak was related to a fast and reversible anion-radical formation originating from the reduction of the carbonyl group, and the second was related to the irreversible reduction of the anion-radical previously formed. Analytical parameters such as: linearity range, equation of the analytical curves, correlation coefficients, detection and quantification limits, recovery efficiency, and relative standard deviation for intraday and interday were compared to similar results obtained by use of the UV-vis spectrophotometry technique, and the analytical results obtained in commercial formulations show that the voltammetric procedure using a hanging mercury drop electrode is suitable for analyzing haloperidol in complex commercial formulation samples.

  4. Electrochemical mechanism and kinetics studies of haloperidol and its assay in commercial formulations

    International Nuclear Information System (INIS)

    Ribeiro, Francisco W.P.; Soares, Janete E.S.; Becker, Helena; De Souza, Djenaine; Lima-Neto, Pedro de; Correia, Adriana N.

    2011-01-01

    The kinetics and mechanism for electrochemical reduction of haloperidol, a psychotherapeutic drug used in the treatment of schizophrenia, were studied using square wave and cyclic voltammetries allied to a hanging mercury drop electrode. The experimental and voltammetric parameters were optimized at 0.04 mol L -1 Brinton-Robinson buffer (pH 10), with a pulse potential frequency of 100 s -1 , a pulse amplitude of 30 mV and scan increment of 2 mV. Two well-defined peaks were observed, which exhibited properties of fast electron transfer with a strong adsorption process of reactants and products on the electrode surface. The first peak was related to a fast and reversible anion-radical formation originating from the reduction of the carbonyl group, and the second was related to the irreversible reduction of the anion-radical previously formed. Analytical parameters such as: linearity range, equation of the analytical curves, correlation coefficients, detection and quantification limits, recovery efficiency, and relative standard deviation for intraday and interday were compared to similar results obtained by use of the UV-vis spectrophotometry technique, and the analytical results obtained in commercial formulations show that the voltammetric procedure using a hanging mercury drop electrode is suitable for analyzing haloperidol in complex commercial formulation samples.

  5. Mechanical Properties Studies of Components Formulation for Mixing Process Contain of Polypropylene, Polyethylene, and Aluminium Powder

    Science.gov (United States)

    Hamsi, A.; Dinzi, R.

    2017-03-01

    Certain powder and others components can induce toxic reactions if not properly handled in the mixing stage. During handling, the small particles can become airborne and be trapped in the lungs, another concern is inhomogeneities in the mixing process. Uniform quantities of the particles of the components are needed in all portions of the mixture. This paper reports the results of mechanical properties studies of mixing three components formulation for mixing process. Contain of Polyethylene (PE), Polyprophylene (PP) and Aluminium Powder. Powder mixer, Autodesk mold flow and computer based on excell method was carried out to study the influence of each formulation component on the flow %, PE 20% and Aluminium powder 2%. Macroscopic optic and macro photo was carried out to identify the homogenity of mixing, tensile test for identify the strength of component after mixing. Finally the optimal tensile test with composition PP 785,PE 20% and Aluminium powder 2% at speed 52 rpm, temperature 1500C, the tensile strength 20,92 N/mm2. At temperature 1600C, speed 100 rpm the optimum tensile strength 17,91 N/mm2. The result of simulation autodesk mold flow adviser the filling time 6 seconds. Otherwise on manual hot hidraulic press the time of filling 10 seconds.

  6. Statistical mechanics of polymer networks of any topology

    International Nuclear Information System (INIS)

    Duplantier, B.

    1989-01-01

    The statistical mechanics is considered of any polymer network with a prescribed topology, in dimension d, which was introduced previously. The basic direct renormalization theory of the associated continuum model is established. It has a very simple multiplicative structure in terms of the partition functions of the star polymers constituting the vertices of the network. A calculation is made to O(ε 2 ), where d = 4 -ε, of the basic critical dimensions σ L associated with any L=leg vertex (L ≥ 1). From this infinite series of critical exponents, any topology-dependent critical exponent can be derived. This is applied to the configuration exponent γ G of any network G to O(ε 2 ), including L-leg star polymers. The infinite sets of contact critical exponents θ between multiple points of polymers or between the cores of several star polymers are also deduced. As a particular case, the three exponents θ 0 , θ 1 , θ 2 calculated by des Cloizeaux by field-theoretic methods are recovered. The limiting exact logarithmic laws are derived at the upper critical dimension d = 4. The results are generalized to the series of topological exponents of polymer networks near a surface and of tricritical polymers at the Θ-point. Intersection properties of networks of random walks can be studied similarly. The above factorization theory of the partition function of any polymer network over its constituting L-vertices also applies to two dimensions, where it can be related to conformal invariance. The basic critical exponents σ L and thus any topological polymer exponents are then exactly known. Principal results published elsewhere are recalled

  7. On some boundary value problems in quantum statistical mechanics

    International Nuclear Information System (INIS)

    Angelescu, N.

    1978-01-01

    The following two topics of equilibrium quantum statistical mechanics are discussed in this thesis: (i) the independence of the thermodynamic limit of grand-canonical pressure on the boundary conditions; (ii) the magnetic properties of free quantum gases. Problem (i) is handled with a functional integration technique. Wiener-type conditional measures are constructed for a given domain and a general class of mixed conditions on its boundary, these measures are used to write down Feynman-Kac formulae for the kernels of exp(-βH), where H is the Hamiltonian of N interacting particles in the given domain. These measures share the property that they assign the same mass as the usual Wiener measure to any set of trajectories not intersecting the boundary. Local estimates on the kernels of exp(-βH) are derived, which imply independence of the pressure on the boundary conditions in the thermodynamic limit. Problem (ii) has a historical development: since Landau's work (1930), much discussion has been devoted to the influence of the finite size on the susceptibility. In finite volume, Dirichlet boundary conditions are imposed, on the ground that they ensure gauge invariance. The thermodynamic limit of the pressure is proved, using again functional integration. The functional measure is now complex but absolutely continuous with respect to Wiener measure, so the usual local estimates hold true. The controversy in the literature was concentrated on the commutativity of the operations of H-derivation and thermodynamic limit, so the existence of this limit for the zero-field susceptibility and its surface term are proved separately, demonstrating this commutativity. The proof relies on the following result of independent interest: the perturbation theory of self-adjoint trace-class semigroups is trace-class convergent and analytic. (author)

  8. Formulation and statistical optimization of gastric floating alginate/oil/chitosan capsules loading procyanidins: in vitro and in vivo evaluations.

    Science.gov (United States)

    Chen, Rencai; Guo, Xiaomin; Liu, Xuecong; Cui, Haiming; Wang, Rui; Han, Jing

    2018-03-01

    The aim of the present work was to develop gastric floating capsules containing oil-entrapped beads loading procyanidins. The floating beads were prepared by ionotropic gelation method using sodium alginate, CaCl 2 and chitosan. The effect of three independent parameters (concentration of sodium alginate, CaCl 2 and chitosan) on entrapment efficiency were analyzed by Box-Behnken design. The floating beads were evaluated for surface morphology, particle size, density, entrapment efficiency, buoyancy, release behavior in vitro and floating ability in vivo. The prepared beads were grossly spherical in shape and the mean size was approximately 1.54±0.17mm. The density was 0.97g/cm 3 . And the optimal conditions were as follows: concentration of sodium alginate, CaCl 2 and chitosan were 33.75mg/mL, 9.84mg/mL and 9.05mg/mL, respectively. The optimized formulation showed entrapment efficiency of 88.84±1.04% within small error-value (0.65). The release mechanism of floating capsules followed Korsmeyer-Peppas model (r 2 =0.9902) with non-Fickian release. The gastric floating capsules exhibited 100% floating percentage in vitro and they could float on the top of gastric juice for 5h in vivo. Therefore, the floating capsules are able to prolong the gastroretentive delivery of procyanidins. Copyright © 2017 Elsevier B.V. All rights reserved.

  9. Statistical mechanics of directed models of polymers in the square lattice

    International Nuclear Information System (INIS)

    Rensburg, E J Janse van

    2003-01-01

    Directed square lattice models of polymers and vesicles have received considerable attention in the recent mathematical and physical sciences literature. These are idealized geometric directed lattice models introduced to study phase behaviour in polymers, and include Dyck paths, partially directed paths, directed trees and directed vesicles models. Directed models are closely related to models studied in the combinatorics literature (and are often exactly solvable). They are also simplified versions of a number of statistical mechanics models, including the self-avoiding walk, lattice animals and lattice vesicles. The exchange of approaches and ideas between statistical mechanics and combinatorics have considerably advanced the description and understanding of directed lattice models, and this will be explored in this review. The combinatorial nature of directed lattice path models makes a study using generating function approaches most natural. In contrast, the statistical mechanics approach would introduce partition functions and free energies, and then investigate these using the general framework of critical phenomena. Generating function and statistical mechanics approaches are closely related. For example, questions regarding the limiting free energy may be approached by considering the radius of convergence of a generating function, and the scaling properties of thermodynamic quantities are related to the asymptotic properties of the generating function. In this review the methods for obtaining generating functions and determining free energies in directed lattice path models of linear polymers is presented. These methods include decomposition methods leading to functional recursions, as well as the Temperley method (that is implemented by creating a combinatorial object, one slice at a time). A constant term formulation of the generating function will also be reviewed. The thermodynamic features and critical behaviour in models of directed paths may be

  10. Quality by design approach for formulation, evaluation and statistical optimization of diclofenac-loaded ethosomes via transdermal route.

    Science.gov (United States)

    Jain, Shashank; Patel, Niketkumar; Madan, Parshotam; Lin, Senshang

    2015-06-01

    The objective of this study was to fabricate and understand ethosomal formulations of diclofenac (DF) for enhanced anti-inflammatory activity using quality by design approach. DF-loaded ethosomal formulations were prepared using 4 × 5 full-factorial design with phosphatidylcholine:cholesterol (PC:CH) ratios ranging between 50:50 and 90:10, and ethanol concentration ranging between 0% and 30% as formulation variables. These formulations were characterized in terms of physicochemical properties and skin permeation kinetics. The interaction of formulation variables had a significant effect on both physicochemical properties and permeation kinetics. The results of multivariate regression analysis illustrated that vesicle size and elasticity of ethosomes were the dominating physicochemical properties affecting skin permeation, and could be suitably controlled by manipulation of formulation variables to optimize the formulation and enhance the skin permeation of DF-loaded ethosomes. The optimized formulation had ethanol concentration of 22.9% and PC:CH ratio of 88.4:11.6, with vesicle size of 144 ± 5 nm, zeta potential of -23.0 ± 3.76 mV, elasticity of 2.48 ± 0.75 and entrapment efficiency of 71 ± 4%. Permeation flux for the optimized formulation was 12.9 ± 1.0 µg/h cm(2), which was significantly higher than the drug-loaded conventional liposome, ethanolic or aqueous solution. The in vivo study indicated that optimized ethosomal hydrogel exhibited enhanced anti-inflammatory activity compared with liposomal and plain drug hydrogel formulations.

  11. Counting in Lattices: Combinatorial Problems from Statistical Mechanics.

    Science.gov (United States)

    Randall, Dana Jill

    In this thesis we consider two classical combinatorial problems arising in statistical mechanics: counting matchings and self-avoiding walks in lattice graphs. The first problem arises in the study of the thermodynamical properties of monomers and dimers (diatomic molecules) in crystals. Fisher, Kasteleyn and Temperley discovered an elegant technique to exactly count the number of perfect matchings in two dimensional lattices, but it is not applicable for matchings of arbitrary size, or in higher dimensional lattices. We present the first efficient approximation algorithm for computing the number of matchings of any size in any periodic lattice in arbitrary dimension. The algorithm is based on Monte Carlo simulation of a suitable Markov chain and has rigorously derived performance guarantees that do not rely on any assumptions. In addition, we show that these results generalize to counting matchings in any graph which is the Cayley graph of a finite group. The second problem is counting self-avoiding walks in lattices. This problem arises in the study of the thermodynamics of long polymer chains in dilute solution. While there are a number of Monte Carlo algorithms used to count self -avoiding walks in practice, these are heuristic and their correctness relies on unproven conjectures. In contrast, we present an efficient algorithm which relies on a single, widely-believed conjecture that is simpler than preceding assumptions and, more importantly, is one which the algorithm itself can test. Thus our algorithm is reliable, in the sense that it either outputs answers that are guaranteed, with high probability, to be correct, or finds a counterexample to the conjecture. In either case we know we can trust our results and the algorithm is guaranteed to run in polynomial time. This is the first algorithm for counting self-avoiding walks in which the error bounds are rigorously controlled. This work was supported in part by an AT&T graduate fellowship, a University of

  12. Derivation of the Schrodinger Equation from the Hamilton-Jacobi Equation in Feynman's Path Integral Formulation of Quantum Mechanics

    Science.gov (United States)

    Field, J. H.

    2011-01-01

    It is shown how the time-dependent Schrodinger equation may be simply derived from the dynamical postulate of Feynman's path integral formulation of quantum mechanics and the Hamilton-Jacobi equation of classical mechanics. Schrodinger's own published derivations of quantum wave equations, the first of which was also based on the Hamilton-Jacobi…

  13. Student Understanding of Taylor Series Expansions in Statistical Mechanics

    Science.gov (United States)

    Smith, Trevor I.; Thompson, John R.; Mountcastle, Donald B.

    2013-01-01

    One goal of physics instruction is to have students learn to make physical meaning of specific mathematical expressions, concepts, and procedures in different physical settings. As part of research investigating student learning in statistical physics, we are developing curriculum materials that guide students through a derivation of the Boltzmann…

  14. Statistical mechanics of learning: A variational approach for real data

    International Nuclear Information System (INIS)

    Malzahn, Doerthe; Opper, Manfred

    2002-01-01

    Using a variational technique, we generalize the statistical physics approach of learning from random examples to make it applicable to real data. We demonstrate the validity and relevance of our method by computing approximate estimators for generalization errors that are based on training data alone

  15. A Statistical Mechanics Approach to Approximate Analytical Bootstrap Averages

    DEFF Research Database (Denmark)

    Malzahn, Dorthe; Opper, Manfred

    2003-01-01

    We apply the replica method of Statistical Physics combined with a variational method to the approximate analytical computation of bootstrap averages for estimating the generalization error. We demonstrate our approach on regression with Gaussian processes and compare our results with averages...

  16. Effect of thermal and chemical modifications on the mechanical and release properties of paracetamol tablet formulations containing corn, cassava and sweet potato starches as filler-binders

    Directory of Open Access Journals (Sweden)

    Mariam Vbamiunomhene Lawal

    2015-07-01

    Conclusions: Modification of the experimental starches improved the mechanical and release properties of directly compressed paracetamol tablet formulations. Thus, they can be developed for use as pharmaceutical excipients in specific formulations.

  17. The time-local view of nonequilibrium statistical mechanics. I. Linear theory of transport and relaxation

    Science.gov (United States)

    der, R.

    1987-01-01

    The various approaches to nonequilibrium statistical mechanics may be subdivided into convolution and convolutionless (time-local) ones. While the former, put forward by Zwanzig, Mori, and others, are used most commonly, the latter are less well developed, but have proven very useful in recent applications. The aim of the present series of papers is to develop the time-local picture (TLP) of nonequilibrium statistical mechanics on a new footing and to consider its physical implications for topics such as the formulation of irreversible thermodynamics. The most natural approach to TLP is seen to derive from the Fourier-Laplace transformwidetilde{C}(z)) of pertinent time correlation functions, which on the physical sheet typically displays an essential singularity at z=∞ and a number of macroscopic and microscopic poles in the lower half-plane corresponding to long- and short-lived modes, respectively, the former giving rise to the autonomous macrodynamics, whereas the latter are interpreted as doorway modes mediating the transfer of information from relevant to irrelevant channels. Possible implications of this doorway mode concept for socalled extended irreversible thermodynamics are briefly discussed. The pole structure is used for deriving new kinds of generalized Green-Kubo relations expressing macroscopic quantities, transport coefficients, e.g., by contour integrals over current-current correlation functions obeying Hamiltonian dynamics, the contour integration replacing projection. The conventional Green-Kubo relations valid for conserved quantities only are rederived for illustration. Moreover,widetilde{C}(z) may be expressed by a Laurent series expansion in positive and negative powers of z, from which a rigorous, general, and straightforward method is developed for extracting all macroscopic quantities from so-called secularly divergent expansions ofwidetilde{C}(z) as obtained from the application of conventional many-body techniques to the calculation

  18. Reliability, Sensitivity, and Specificity of Case Formulations for Comorbid Profiles in Interpersonal Reconstructive Therapy: Addressing Mechanisms of Psychopathology.

    Science.gov (United States)

    Critchfield, Kenneth L; Benjamin, Lorna Smith; Levenick, Kathleen

    2015-08-01

    Interpersonal Reconstructive Therapy (IRT) case formulations describe psychosocial mechanisms of affective and personality pathology in ways that enhance the effectiveness of psychotherapy for individuals. With a valid and reliable IRT case formulation, a clinician is in a better position to draw upon effective techniques to maximize treatment effects. The case formulation and treatment models for IRT were described in depth along with the IRT treatment model by Benjamin (2003/2006). Data in this report from 93 adult inpatients with complex and comorbid presentations suggest that the case formulation is highly reliable and unique to individuals, and that symptoms reflect current interpersonal stresses linked to early interactions involving forms of hostility in relation with attachment figures and corresponding to three basic patterns in adulthood: identification (be like him or her), recapitulation (act as you did with him or her), and introjection (treat yourself as you were treated).

  19. Statistical mechanics and the description of the early universe I

    DEFF Research Database (Denmark)

    Pessah, Martin Elias; F. Torres, Diego; Vucetich, H.

    2001-01-01

    We analyze how the thermal history of the universe is influenced by the statistical description, assuming a deviation from the usual Bose-Einstein, Fermi-Dirac and Boltzmann-Gibbs distribution functions. These deviations represent the possible appearance of non-extensive effects related with the ......We analyze how the thermal history of the universe is influenced by the statistical description, assuming a deviation from the usual Bose-Einstein, Fermi-Dirac and Boltzmann-Gibbs distribution functions. These deviations represent the possible appearance of non-extensive effects related...... and to place limits to the range of its validity. The corrections obtained will change with temperature, and consequently, the bounds on the possible amount of non-extensivity will also change with time. We generalize results which can be used in other contexts as well, as the Boltzmann equation and the Saha...

  20. Erwin Schroedinger: Collected papers V. 1. Contributions to statistical mechanics

    International Nuclear Information System (INIS)

    Schroedinger, E.

    1984-01-01

    38 publications reprinted in this volume show that the interest for statistical problems accompanied Schroedinger during his entire scientific career. Already in his second paper he worked on the magnetism of solid states. The classical considerations come close to the heart of diamagnetism and also to the origin of paramagnetism. In classical investigations of the specific heat Schroedinger helped through abstract theory but also by analysing a gigantic amount of experimental material. In 1926 he and F. Kohlrausch actually played the 'Urngame of Ehrenfest' as a model of the H-curve and published the results. Inclination towards experimenting, sequences of measurements and statistical evaluation of experimental data led to papers on the foundation of the theory of probability, where he tries to put the subjective probability concept on into a systematic framework. Two earlier papers on dynamics of the elastic chain remained particularly valuable. By solving the initial value problem with Bessel-functions this many-body-problem is led to an explicit discussion. These studies are likely to be the roots of another keynote in Schroedinger's thinking, namely, the irreversibility. 1945 a statistical theory of chain-reactions was published under the inconspicuous title of 'Probability Problems in Nuclear Chemistry'. In his last work Schroedinger turns off in a wrong direction: it is that energy should only be a statistical concept and should not be conserved in elementary processes, but somehow only in the mean. These short remarks only illuminate the diversity of the material in this volume, but testify Schroedinger's deep understanding in this field. (W.K.)

  1. Statistical mechanics of complex neural systems and high dimensional data

    International Nuclear Information System (INIS)

    Advani, Madhu; Lahiri, Subhaneil; Ganguli, Surya

    2013-01-01

    Recent experimental advances in neuroscience have opened new vistas into the immense complexity of neuronal networks. This proliferation of data challenges us on two parallel fronts. First, how can we form adequate theoretical frameworks for understanding how dynamical network processes cooperate across widely disparate spatiotemporal scales to solve important computational problems? Second, how can we extract meaningful models of neuronal systems from high dimensional datasets? To aid in these challenges, we give a pedagogical review of a collection of ideas and theoretical methods arising at the intersection of statistical physics, computer science and neurobiology. We introduce the interrelated replica and cavity methods, which originated in statistical physics as powerful ways to quantitatively analyze large highly heterogeneous systems of many interacting degrees of freedom. We also introduce the closely related notion of message passing in graphical models, which originated in computer science as a distributed algorithm capable of solving large inference and optimization problems involving many coupled variables. We then show how both the statistical physics and computer science perspectives can be applied in a wide diversity of contexts to problems arising in theoretical neuroscience and data analysis. Along the way we discuss spin glasses, learning theory, illusions of structure in noise, random matrices, dimensionality reduction and compressed sensing, all within the unified formalism of the replica method. Moreover, we review recent conceptual connections between message passing in graphical models, and neural computation and learning. Overall, these ideas illustrate how statistical physics and computer science might provide a lens through which we can uncover emergent computational functions buried deep within the dynamical complexities of neuronal networks. (paper)

  2. Design of a dual nanostructured lipid carrier formulation based on physicochemical, rheological, and mechanical properties

    Energy Technology Data Exchange (ETDEWEB)

    Vitorino, Carla [University of Coimbra, Centro de Estudos Farmaceuticos (CEF), Faculty of Pharmacy (Portugal); Alves, Luis; Antunes, Filipe E. [University of Coimbra, Department of Chemistry (Portugal); Sousa, Joao J. [University of Coimbra, Centro de Estudos Farmaceuticos (CEF), Faculty of Pharmacy (Portugal); Pais, Alberto A. C. C., E-mail: pais@qui.uc.pt [University of Coimbra, Department of Chemistry (Portugal)

    2013-10-15

    The synergy between nanostructured lipid carriers (NLC) and chemical penetration enhancers provides the basis for a promising strategy to effectively deliver drugs through the skin. In the present work, focus is given to the study of the interaction of limonene, ethanol, and Carbopol Ultrez{sup Registered-Sign} 10NF, as the gelling agent, with a co-encapsulating NLC dispersion, containing both olanzapine and simvastatin. The analysis is based on rheological, mechanical, and physicochemical properties. The nanoparticle size ranged from 130 to 400 nm, depending on the system considered. The inclusion of carbopol resulted in a considerable increase in the NLC particle size, which was attributed to carbomer bridging nanoparticles, resulting in some particle aggregation. Rheological measurements indicated that the viscosity of the neat carbopol hydrogel was reduced by the enhancers and to a higher extent by the presence of NLC. A more apolar medium can be pointed out as a general explanation, while a polymer/nanoparticle hydrophobic interaction coupled with surfactant/polymer H-bonding provides the rationale for the NLC effect. The inclusion of enhancers and a carbomer largely contributed to the physicochemical stability of the NLC formulation, as revealed by the low transmission profiles and more negative zeta potential values.

  3. Design of a dual nanostructured lipid carrier formulation based on physicochemical, rheological, and mechanical properties

    International Nuclear Information System (INIS)

    Vitorino, Carla; Alves, Luís; Antunes, Filipe E.; Sousa, João J.; Pais, Alberto A. C. C.

    2013-01-01

    The synergy between nanostructured lipid carriers (NLC) and chemical penetration enhancers provides the basis for a promising strategy to effectively deliver drugs through the skin. In the present work, focus is given to the study of the interaction of limonene, ethanol, and Carbopol Ultrez ® 10NF, as the gelling agent, with a co-encapsulating NLC dispersion, containing both olanzapine and simvastatin. The analysis is based on rheological, mechanical, and physicochemical properties. The nanoparticle size ranged from 130 to 400 nm, depending on the system considered. The inclusion of carbopol resulted in a considerable increase in the NLC particle size, which was attributed to carbomer bridging nanoparticles, resulting in some particle aggregation. Rheological measurements indicated that the viscosity of the neat carbopol hydrogel was reduced by the enhancers and to a higher extent by the presence of NLC. A more apolar medium can be pointed out as a general explanation, while a polymer/nanoparticle hydrophobic interaction coupled with surfactant/polymer H-bonding provides the rationale for the NLC effect. The inclusion of enhancers and a carbomer largely contributed to the physicochemical stability of the NLC formulation, as revealed by the low transmission profiles and more negative zeta potential values

  4. Controlled-release, pegylation, liposomal formulations: new mechanisms in the delivery of injectable drugs.

    Science.gov (United States)

    Reddy, K R

    2000-01-01

    To review recent developments in novel injectable drug delivery mechanisms and outline the advantages and disadvantages of each. A MEDLINE (1995-January 2000) search using the terms polyethylene glycol, liposomes, polymers, polylactic acid, and controlled release was conducted. Additional references were identified by scanning bibliographies. All articles were considered for inclusion. Abstracts were included only if they were judged to add critical information not otherwise available in the medical literature. A number of systems that alter the delivery of injectable drugs have been developed in attempts to improve pharmacodynamic and pharmacokinetic properties of therapeutic agents. New drug delivery systems can be produced either through a change in formulation (e.g., continuous-release products, liposomes) or an addition to the drug molecule (e.g., pegylation). Potential advantages of new delivery mechanisms include an increased or prolonged duration of pharmacologic activity, a decrease in adverse effects, and increased patient compliance and quality of life. Injectable continuous-release systems deliver drugs in a controlled, predetermined fashion and are particularly appropriate when it is important to avoid large fluctuations in plasma drug concentrations. Encapsulating a drug within a liposome can produce a prolonged half-life and a shift of distribution toward tissues with increased capillary permeability (e.g., tumors, infected tissue). Pegylation provides a method for modification of therapeutic proteins to minimize many of the limitations (e.g., poor stability, short half-life, immunogenicity) associated with these agents. Pegylation of therapeutic proteins is an established process with new applications. However, not all pegylated proteins are alike, and each requires optimization on a protein-by-protein basis to derive maximum clinical benefit. The language required to describe each pegylated therapeutic protein must be more precise to accurately

  5. Bioreducible liposomes for gene delivery: from the formulation to the mechanism of action.

    Directory of Open Access Journals (Sweden)

    Gabriele Candiani

    Full Text Available BACKGROUND: A promising strategy to create stimuli-responsive gene delivery systems is to exploit the redox gradient between the oxidizing extracellular milieu and the reducing cytoplasm in order to disassemble DNA/cationic lipid complexes (lipoplexes. On these premises, we previously described the synthesis of SS14 redox-sensitive gemini surfactant for gene delivery. Although others have attributed the beneficial effects of intracellular reducing environment to reduced glutathione (GSH, these observations cannot rule out the possible implication of the redox milieu in its whole on transfection efficiency of bioreducible transfectants leaving the determinants of DNA release largely undefined. METHODOLOGY/PRINCIPAL FINDINGS: With the aim of addressing this issue, SS14 was here formulated into binary and ternary 100 nm-extruded liposomes and the effects of the helper lipid composition and of the SS14/helper lipids molar ratio on chemical-physical and structural parameters defining transfection effectiveness were investigated. Among all formulations tested, DOPC/DOPE/SS14 at 25:50:25 molar ratio was the most effective in transfection studies owing to the presence of dioleoyl chains and phosphatidylethanolamine head groups in co-lipids. The increase in SS14 content up to 50% along DOPC/DOPE/SS14 liposome series yielded enhanced transfection, up to 2.7-fold higher than that of the benchmark Lipofectamine 2000, without altering cytotoxicity of the corresponding lipoplexes at charge ratio 5. Secondly, we specifically investigated the redox-dependent mechanisms of gene delivery into cells through tailored protocols of transfection in GSH-depleted and repleted vs. increased oxidative stress conditions. Importantly, GSH specifically induced DNA release in batch and in vitro. CONCLUSIONS/SIGNIFICANCE: The presence of helper lipids carrying unsaturated dioleoyl chains and phosphatidylethanolamine head groups significantly improved transfection efficiencies

  6. Student understanding of Taylor series expansions in statistical mechanics

    Directory of Open Access Journals (Sweden)

    Trevor I. Smith

    2013-08-01

    Full Text Available One goal of physics instruction is to have students learn to make physical meaning of specific mathematical expressions, concepts, and procedures in different physical settings. As part of research investigating student learning in statistical physics, we are developing curriculum materials that guide students through a derivation of the Boltzmann factor using a Taylor series expansion of entropy. Using results from written surveys, classroom observations, and both individual think-aloud and teaching interviews, we present evidence that many students can recognize and interpret series expansions, but they often lack fluency in creating and using a Taylor series appropriately, despite previous exposures in both calculus and physics courses.

  7. Student understanding of Taylor series expansions in statistical mechanics

    Science.gov (United States)

    Smith, Trevor I.; Thompson, John R.; Mountcastle, Donald B.

    2013-12-01

    One goal of physics instruction is to have students learn to make physical meaning of specific mathematical expressions, concepts, and procedures in different physical settings. As part of research investigating student learning in statistical physics, we are developing curriculum materials that guide students through a derivation of the Boltzmann factor using a Taylor series expansion of entropy. Using results from written surveys, classroom observations, and both individual think-aloud and teaching interviews, we present evidence that many students can recognize and interpret series expansions, but they often lack fluency in creating and using a Taylor series appropriately, despite previous exposures in both calculus and physics courses.

  8. Quantum statistical mechanics selected works of N N Bogolubov

    CERN Document Server

    Bogolyubov, N N

    2015-01-01

    In this book we have solved the complicated problem of constructing upper bounds for many-time averages for the case of a fairly broad class of model systems with four-fermion interaction. The methods proposed in this book for solving this problem will undoubtedly find application not only for the model systems associated with the theory of superconductivity considered here. The theoretical methods developed in Chapters 1 and 2 are already applicable to a much broader class of model systems from statistical physics and the theory of elementary particles. Contents: On the Theory of Superfluidit

  9. On second quantization methods applied to classical statistical mechanics

    International Nuclear Information System (INIS)

    Matos Neto, A.; Vianna, J.D.M.

    1984-01-01

    A method of expressing statistical classical results in terms of mathematical entities usually associated to quantum field theoretical treatment of many particle systems (Fock space, commutators, field operators, state vector) is discussed. It is developed a linear response theory using the 'second quantized' Liouville equation introduced by Schonberg. The relationship of this method to that of Prigogine et al. is briefly analyzed. The chain of equations and the spectral representations for the new classical Green's functions are presented. Generalized operators defined on Fock space are discussed. It is shown that the correlation functions can be obtained from Green's functions defined with generalized operators. (Author) [pt

  10. Studies on quantum field theory and statistical mechanics

    International Nuclear Information System (INIS)

    Zhang, S.

    1987-01-01

    This dissertation is a summary of research in various areas of theoretical physics and is divided into three parts. In the first part, quantum fluctuations of the recently proposed superconducting cosmic strings are studied. It is found that vortices on the string world sheet represent an important class of fluctuation modes which tend to disorder the system. Both heuristic arguments and detailed renormalization group analysis reveal that these vortices do not appear in bound pairs but rather from a gas of free vortices. Based on this observation we argue that this fluctuation mode violates the topological conservation law on which superconductivity is based. Anomalies and topological aspects of supersymmetric quantum field theories are studied in the second part of this dissertation. Using the superspace formulation of the N = 1 spinning string, we obtain a path integral measure which is free from the world-sheet general coordinate as well as the supersymmetry anomalies and therefore determine the conformal anomaly and critical dimension of the spinning string. We also apply Fujikawa's formalism to computer the chiral anomaly in conformal as well as ordinary supergravity. Finally, we given a Noether-method construction of the supersymmetrized Chern-Simons term in five dimensional supergravity. In the last part of this dissertation, the soliton excitations in the quarter-filled Peierls-Hubbard model are investigated in both the large and the small U limit. For a strictly one dimensional system at zero temperature, we find that solitons in both limits are in one-to-one correspondence, while in the presence of weak three dimensional couplings or at finite temperature, the large U systems differ qualitatively from the small U systems in that the spin associated with the solitons ceases to be a sharp quantum observable

  11. Statistics

    CERN Document Server

    Hayslett, H T

    1991-01-01

    Statistics covers the basic principles of Statistics. The book starts by tackling the importance and the two kinds of statistics; the presentation of sample data; the definition, illustration and explanation of several measures of location; and the measures of variation. The text then discusses elementary probability, the normal distribution and the normal approximation to the binomial. Testing of statistical hypotheses and tests of hypotheses about the theoretical proportion of successes in a binomial population and about the theoretical mean of a normal population are explained. The text the

  12. Nonequilibrium statistical mechanics of systems with long-range interactions

    Energy Technology Data Exchange (ETDEWEB)

    Levin, Yan, E-mail: levin@if.ufrgs.br; Pakter, Renato, E-mail: pakter@if.ufrgs.br; Rizzato, Felipe B., E-mail: rizzato@if.ufrgs.br; Teles, Tarcísio N., E-mail: tarcisio.teles@fi.infn.it; Benetti, Fernanda P.C., E-mail: fbenetti@if.ufrgs.br

    2014-02-01

    Systems with long-range (LR) forces, for which the interaction potential decays with the interparticle distance with an exponent smaller than the dimensionality of the embedding space, remain an outstanding challenge to statistical physics. The internal energy of such systems lacks extensivity and additivity. Although the extensivity can be restored by scaling the interaction potential with the number of particles, the non-additivity still remains. Lack of additivity leads to inequivalence of statistical ensembles. Before relaxing to thermodynamic equilibrium, isolated systems with LR forces become trapped in out-of-equilibrium quasi-stationary states (qSSs), the lifetime of which diverges with the number of particles. Therefore, in the thermodynamic limit LR systems will not relax to equilibrium. The qSSs are attained through the process of collisionless relaxation. Density oscillations lead to particle–wave interactions and excitation of parametric resonances. The resonant particles escape from the main cluster to form a tenuous halo. Simultaneously, this cools down the core of the distribution and dampens out the oscillations. When all the oscillations die out the ergodicity is broken and a qSS is born. In this report, we will review a theory which allows us to quantitatively predict the particle distribution in the qSS. The theory is applied to various LR interacting systems, ranging from plasmas to self-gravitating clusters and kinetic spin models.

  13. Nonequilibrium statistical mechanics in the general theory of relativity. I. A general formalism

    International Nuclear Information System (INIS)

    Israel, W.; Kandrup, H.E.

    1984-01-01

    This is the first in a series of papers, the overall objective of which is the formulation of a new covariant approach to nonequilibrium statistical mechanics in classical general relativity. The objecct here is the development of a tractable theory for self-gravitating systems. It is argued that the ''state'' of an N-particle system may be characterized by an N-particle distribution function, defined in an 8N-dimensional phase space, which satisfies a collection of N conservation equations. By mapping the true physics onto a fictitious ''background'' spacetime, which may be chosen to satisfy some ''average'' field equations, one then obtains a useful covariant notion of ''evolution'' in response to a fluctuating ''gravitational force.'' For many cases of practical interest, one may suppose (i) that these fluctuating forces satisfy linear field equations and (ii) that they may be modeled by a direct interaction. In this case, one can use a relativistic projection operator formalism to derive exact closed equations for the evolution of such objects as an appropriately defined reduced one-particle distribution function. By capturing, in a natural way, the notion of a dilute gas, or impulse, approximation, one is then led to a comparatively simple equation for the one-particle distribution. If, furthermore, one treats the effects of the fluctuating forces as ''localized'' in space and time, one obtains a tractable kinetic equation which reduces, in the Newtonian limit, to the stardard Landau equation

  14. Statistical mechanics of flux lines in high-temperature superconductors

    International Nuclear Information System (INIS)

    Dasgupta, C.

    1992-01-01

    The shortness of the low temperature coherence lengths of high T c materials leads to new mechanisms of pinning of flux lines. Lattice periodic modulations of the order parameters itself acts to pin vortex lines in regions of the unit cell were the order parameter is small. A presentation of flux creep and flux noise at low temperature and magnetic fields in terms of motion of simple metastable defects on flux lines is made, with a calculation of flux lattice melting. 12 refs

  15. Nonextensive statistical mechanics approach to electron trapping in degenerate plasmas

    Science.gov (United States)

    Mebrouk, Khireddine; Gougam, Leila Ait; Tribeche, Mouloud

    2016-06-01

    The electron trapping in a weakly nondegenerate plasma is reformulated and re-examined by incorporating the nonextensive entropy prescription. Using the q-deformed Fermi-Dirac distribution function including the quantum as well as the nonextensive statistical effects, we derive a new generalized electron density with a new contribution proportional to the electron temperature T, which may dominate the usual thermal correction (∼T2) at very low temperatures. To make the physics behind the effect of this new contribution more transparent, we analyze the modifications arising in the propagation of ion-acoustic solitary waves. Interestingly, we find that due to the nonextensive correction, our plasma model allows the possibility of existence of quantum ion-acoustic solitons with velocity higher than the Fermi ion-sound velocity. Moreover, as the nonextensive parameter q increases, the critical temperature Tc beyond which coexistence of compressive and rarefactive solitons sets in, is shifted towards higher values.

  16. Combined use of MSWI bottom ash and fly ash as aggregate in concrete formulation: environmental and mechanical considerations.

    Science.gov (United States)

    Ginés, O; Chimenos, J M; Vizcarro, A; Formosa, J; Rosell, J R

    2009-09-30

    This paper reports the experimental results obtained after casting concrete formulated with different mix proportions of municipal solid waste incineration (MSWI) by-products, bottom ash (BA) and air pollution control fly ash (APCFA), as aggregates. Several tests were performed to determine the properties of the mixed proportions. Mechanical properties of the formulations, such as compressive strength, were also determined, and two different leaching tests were performed to study their environmental effects. Some suitable concrete formulations were obtained for the 95/5 and 90/10 BA/APCFA mix proportions. These formulations showed the highest compressive strength test results, above 15 MPa, and the lowest amount of released trace metals in reference to the leaching test. The leaching mechanisms involved in the release of trace metals for the best formulations were also studied, revealing that the washing-off process may play an important role. Given the experimental data it can be concluded that these concrete mix proportions are suitable for use as non-structural concrete.

  17. Einstein's Approach to Statistical Mechanics: The 1902-04 Papers

    Science.gov (United States)

    Peliti, Luca; Rechtman, Raúl

    2017-05-01

    We summarize the papers published by Einstein in the Annalen der Physik in the years 1902-1904 on the derivation of the properties of thermal equilibrium on the basis of the mechanical equations of motion and of the calculus of probabilities. We point out the line of thought that led Einstein to an especially economical foundation of the discipline, and to focus on fluctuations of the energy as a possible tool for establishing the validity of this foundation. We also sketch a comparison of Einstein's approach with that of Gibbs, suggesting that although they obtained similar results, they had different motivations and interpreted them in very different ways.

  18. Physical-Mechanical characterization of cosmetic formulations and correlation between instrumental measurements and sensorial properties.

    Science.gov (United States)

    Calixto, L S; Maia Campos, P M B G

    2017-10-01

    The correct choice of raw materials in the development of cosmetic formulations is essential for obtaining stable and pleasant skin care products. Therefore, rheological, texture and sensory analyses are important to understand the behaviour and stability of the formulations. In this context, the aim of this study was to develop cosmetic formulations containing or not (vehicle) UV filters and chicory root extract, to evaluate their stability as well as to characterize their physical and texture properties and correlate them with the sensory attributes. Four formulations containing organic UV filters and chicory extract, each alone or in combination, were developed and evaluated for 180 days with a cone and plate rheometer, a texture analyzer and consumer's sensorial analysis. Thus, the data obtained were correlated to observe the different influences. The developed formulations remained stable after 180 days regarding macroscopic aspects, organoleptic characteristics and pH values. The addition of the UV filters alone and in combination with the active substance resulted in significant increases in rheology properties, viscosity and consistency. The formulation with the active ingredient showed significant decreases in the texture parameters after 180 days, mainly due to its polysaccharide inulin. All formulations obtained high scores in sensorial parameters. A strong correlation was mainly found between spreadability and work of shear, and between the texture parameters. The raw materials strongly influenced the physical, texture and sensorial parameters. Finally, the UV filters showed a greater influence on the results of the formulations than the chicory root extract. In conclusion, the association of the mentioned methods allows the correct choice of ingredients and their combinations. © 2017 Society of Cosmetic Scientists and the Société Française de Cosmétologie.

  19. Statistics

    Science.gov (United States)

    Links to sources of cancer-related statistics, including the Surveillance, Epidemiology and End Results (SEER) Program, SEER-Medicare datasets, cancer survivor prevalence data, and the Cancer Trends Progress Report.

  20. PGT: A Statistical Approach to Prediction and Mechanism Design

    Science.gov (United States)

    Wolpert, David H.; Bono, James W.

    One of the biggest challenges facing behavioral economics is the lack of a single theoretical framework that is capable of directly utilizing all types of behavioral data. One of the biggest challenges of game theory is the lack of a framework for making predictions and designing markets in a manner that is consistent with the axioms of decision theory. An approach in which solution concepts are distribution-valued rather than set-valued (i.e. equilibrium theory) has both capabilities. We call this approach Predictive Game Theory (or PGT). This paper outlines a general Bayesian approach to PGT. It also presents one simple example to illustrate the way in which this approach differs from equilibrium approaches in both prediction and mechanism design settings.

  1. Impact initiation of explosives and propellants via statistical crack mechanics

    Science.gov (United States)

    Dienes, J. K.; Zuo, Q. H.; Kershner, J. D.

    2006-06-01

    A statistical approach has been developed for modeling the dynamic response of brittle materials by superimposing the effects of a myriad of microcracks, including opening, shear, growth and coalescence, taking as a starting point the well-established theory of penny-shaped cracks. This paper discusses the general approach, but in particular an application to the sensitivity of explosives and propellants, which often contain brittle constituents. We examine the hypothesis that the intense heating by frictional sliding between the faces of a closed crack during unstable growth can form a hot spot, causing localized melting, ignition, and fast burn of the reactive material adjacent to the crack. Opening and growth of a closed crack due to the pressure of burned gases inside the crack and interactions of adjacent cracks can lead to violent reaction, with detonation as a possible consequence. This approach was used to model a multiple-shock experiment by Mulford et al. [1993. Initiation of preshocked high explosives PBX-9404, PBX-9502, PBX-9501, monitored with in-material magnetic gauging. In: Proceedings of the 10th International Detonation Symposium, pp. 459-467] involving initiation and subsequent quenching of chemical reactions in a slab of PBX 9501 impacted by a two-material flyer plate. We examine the effects of crack orientation and temperature dependence of viscosity of the melt on the response. Numerical results confirm our theoretical finding [Zuo, Q.H., Dienes, J.K., 2005. On the stability of penny-shaped cracks with friction: the five types of brittle behavior. Int. J. Solids Struct. 42, 1309-1326] that crack orientation has a significant effect on brittle behavior, especially under compressive loading where interfacial friction plays an important role. With a reasonable choice of crack orientation and a temperature-dependent viscosity obtained from molecular dynamics calculations, the calculated particle velocities compare well with those measured using

  2. Application of nonequilibrium quantum statistical mechanics to homogeneous nucleation

    International Nuclear Information System (INIS)

    Larson, A.R.; Cantrell, C.D.

    1978-01-01

    The master equation for cluster growth and evaporation is derived from many-body quantum mechanics and from a modified version of quantum damping theory used in laser physics. For application to nucleation theory, the quantum damping theory has been generalized to include system and reservoir states that are not separate entities. Formulae for rate constants are obtained. Solutions of the master equation yield equations of state and system-averaged quantities recognized as thermodynamic variables. Formulae for Helmholtz free energies of clusters in a Debye approximation are derived. Coexistence-line equations for pressure volume, and number of clusters are obtained from equations-of-state analysis. Coexistence-line and surface-tension data are used to obtain values of parameters for the Debye approximation. These data are employed in calculating both the nucleation current in diffusion cloud chamber experiments and the onset of condensation in expansion nozzle experiments. Theoretical and experimental results are similar for both cloud-chamber and nozzle experiments, which measure water

  3. Parallelism in computations in quantum and statistical mechanics

    International Nuclear Information System (INIS)

    Clementi, E.; Corongiu, G.; Detrich, J.H.

    1985-01-01

    Often very fundamental biochemical and biophysical problems defy simulations because of limitations in today's computers. We present and discuss a distributed system composed of two IBM 4341 s and/or an IBM 4381 as front-end processors and ten FPS-164 attached array processors. This parallel system - called LCAP - has presently a peak performance of about 110 Mflops; extensions to higher performance are discussed. Presently, the system applications use a modified version of VM/SP as the operating system: description of the modifications is given. Three applications programs have been migrated from sequential to parallel: a molecular quantum mechanical, a Metropolis-Monte Carlo and a molecular dynamics program. Descriptions of the parallel codes are briefly outlined. Use of these parallel codes has already opened up new capabilities for our research. The very positive performance comparisons with today's supercomputers allow us to conclude that parallel computers and programming, of the type we have considered, represent a pragmatic answer to many computationally intensive problems. (orig.)

  4. Homogeneous nucleation: a problem in nonequilibrium quantum statistical mechanics

    International Nuclear Information System (INIS)

    1978-08-01

    The master equation for cluster growth and evaporation is derived for many-body quantum mechanics and from a modified version of quantum damping theory used in laser physics. For application to nucleation theory, the quantum damping theory is generalized to include system and reservoir states that are not separate entities. Formulas for rate constants are obtained. Solutions of the master equation yield equations of state and system-averaged quantities recognized as thermodynamic variables. Formulas for Helmholtz free energies of clusters in a Debye approximation are derived. Coexistence-line equations for pressure, volume, and number of clusters are obtained from equations-of-state analysis. Coexistence-line and surface-tension data are used to obtain values of parameters for the Debye approximation. These data are employed in calculating both the nucleation current in diffusion cloud chamber experiments and the onset of condensation in expansion nozzle experiments. Theoretical and experimental results are similar for both cloud chamber and nozzle experiments, which measure water. Comparison with other theories reveals that classical theory only accidently agrees with experiment and that the Helmholtz free-energy formula used in the Lothe--Pound theory is incomplete. 27 figures, 3 tables, 149 references

  5. Statistics

    International Nuclear Information System (INIS)

    2005-01-01

    For the years 2004 and 2005 the figures shown in the tables of Energy Review are partly preliminary. The annual statistics published in Energy Review are presented in more detail in a publication called Energy Statistics that comes out yearly. Energy Statistics also includes historical time-series over a longer period of time (see e.g. Energy Statistics, Statistics Finland, Helsinki 2004.) The applied energy units and conversion coefficients are shown in the back cover of the Review. Explanatory notes to the statistical tables can be found after tables and figures. The figures presents: Changes in GDP, energy consumption and electricity consumption, Carbon dioxide emissions from fossile fuels use, Coal consumption, Consumption of natural gas, Peat consumption, Domestic oil deliveries, Import prices of oil, Consumer prices of principal oil products, Fuel prices in heat production, Fuel prices in electricity production, Price of electricity by type of consumer, Average monthly spot prices at the Nord pool power exchange, Total energy consumption by source and CO 2 -emissions, Supplies and total consumption of electricity GWh, Energy imports by country of origin in January-June 2003, Energy exports by recipient country in January-June 2003, Consumer prices of liquid fuels, Consumer prices of hard coal, natural gas and indigenous fuels, Price of natural gas by type of consumer, Price of electricity by type of consumer, Price of district heating by type of consumer, Excise taxes, value added taxes and fiscal charges and fees included in consumer prices of some energy sources and Energy taxes, precautionary stock fees and oil pollution fees

  6. Statistics

    International Nuclear Information System (INIS)

    2001-01-01

    For the year 2000, part of the figures shown in the tables of the Energy Review are preliminary or estimated. The annual statistics of the Energy Review appear in more detail from the publication Energiatilastot - Energy Statistics issued annually, which also includes historical time series over a longer period (see e.g. Energiatilastot 1999, Statistics Finland, Helsinki 2000, ISSN 0785-3165). The inside of the Review's back cover shows the energy units and the conversion coefficients used for them. Explanatory notes to the statistical tables can be found after tables and figures. The figures presents: Changes in the volume of GNP and energy consumption, Changes in the volume of GNP and electricity, Coal consumption, Natural gas consumption, Peat consumption, Domestic oil deliveries, Import prices of oil, Consumer prices of principal oil products, Fuel prices for heat production, Fuel prices for electricity production, Carbon dioxide emissions from the use of fossil fuels, Total energy consumption by source and CO 2 -emissions, Electricity supply, Energy imports by country of origin in 2000, Energy exports by recipient country in 2000, Consumer prices of liquid fuels, Consumer prices of hard coal, natural gas and indigenous fuels, Average electricity price by type of consumer, Price of district heating by type of consumer, Excise taxes, value added taxes and fiscal charges and fees included in consumer prices of some energy sources and Energy taxes and precautionary stock fees on oil products

  7. Statistics

    International Nuclear Information System (INIS)

    2000-01-01

    For the year 1999 and 2000, part of the figures shown in the tables of the Energy Review are preliminary or estimated. The annual statistics of the Energy Review appear in more detail from the publication Energiatilastot - Energy Statistics issued annually, which also includes historical time series over a longer period (see e.g., Energiatilastot 1998, Statistics Finland, Helsinki 1999, ISSN 0785-3165). The inside of the Review's back cover shows the energy units and the conversion coefficients used for them. Explanatory notes to the statistical tables can be found after tables and figures. The figures presents: Changes in the volume of GNP and energy consumption, Changes in the volume of GNP and electricity, Coal consumption, Natural gas consumption, Peat consumption, Domestic oil deliveries, Import prices of oil, Consumer prices of principal oil products, Fuel prices for heat production, Fuel prices for electricity production, Carbon dioxide emissions, Total energy consumption by source and CO 2 -emissions, Electricity supply, Energy imports by country of origin in January-March 2000, Energy exports by recipient country in January-March 2000, Consumer prices of liquid fuels, Consumer prices of hard coal, natural gas and indigenous fuels, Average electricity price by type of consumer, Price of district heating by type of consumer, Excise taxes, value added taxes and fiscal charges and fees included in consumer prices of some energy sources and Energy taxes and precautionary stock fees on oil products

  8. Statistics

    International Nuclear Information System (INIS)

    1999-01-01

    For the year 1998 and the year 1999, part of the figures shown in the tables of the Energy Review are preliminary or estimated. The annual statistics of the Energy Review appear in more detail from the publication Energiatilastot - Energy Statistics issued annually, which also includes historical time series over a longer period (see e.g. Energiatilastot 1998, Statistics Finland, Helsinki 1999, ISSN 0785-3165). The inside of the Review's back cover shows the energy units and the conversion coefficients used for them. Explanatory notes to the statistical tables can be found after tables and figures. The figures presents: Changes in the volume of GNP and energy consumption, Changes in the volume of GNP and electricity, Coal consumption, Natural gas consumption, Peat consumption, Domestic oil deliveries, Import prices of oil, Consumer prices of principal oil products, Fuel prices for heat production, Fuel prices for electricity production, Carbon dioxide emissions, Total energy consumption by source and CO 2 -emissions, Electricity supply, Energy imports by country of origin in January-June 1999, Energy exports by recipient country in January-June 1999, Consumer prices of liquid fuels, Consumer prices of hard coal, natural gas and indigenous fuels, Average electricity price by type of consumer, Price of district heating by type of consumer, Excise taxes, value added taxes and fiscal charges and fees included in consumer prices of some energy sources and Energy taxes and precautionary stock fees on oil products

  9. Performance of mixed formulations for the particle finite element method in soil mechanics problems

    Science.gov (United States)

    Monforte, Lluís; Carbonell, Josep Maria; Arroyo, Marcos; Gens, Antonio

    2017-07-01

    This paper presents a computational framework for the numerical analysis of fluid-saturated porous media at large strains. The proposal relies, on one hand, on the particle finite element method (PFEM), known for its capability to tackle large deformations and rapid changing boundaries, and, on the other hand, on constitutive descriptions well established in current geotechnical analyses (Darcy's law; Modified Cam Clay; Houlsby hyperelasticity). An important feature of this kind of problem is that incompressibility may arise either from undrained conditions or as a consequence of material behaviour; incompressibility may lead to volumetric locking of the low-order elements that are typically used in PFEM. In this work, two different three-field mixed formulations for the coupled hydromechanical problem are presented, in which either the effective pressure or the Jacobian are considered as nodal variables, in addition to the solid skeleton displacement and water pressure. Additionally, several mixed formulations are described for the simplified single-phase problem due to its formal similitude to the poromechanical case and its relevance in geotechnics, since it may approximate the saturated soil behaviour under undrained conditions. In order to use equal-order interpolants in displacements and scalar fields, stabilization techniques are used in the mass conservation equation of the biphasic medium and in the rest of scalar equations. Finally, all mixed formulations are assessed in some benchmark problems and their performances are compared. It is found that mixed formulations that have the Jacobian as a nodal variable perform better.

  10. Statistics

    International Nuclear Information System (INIS)

    2003-01-01

    For the year 2002, part of the figures shown in the tables of the Energy Review are partly preliminary. The annual statistics of the Energy Review also includes historical time-series over a longer period (see e.g. Energiatilastot 2001, Statistics Finland, Helsinki 2002). The applied energy units and conversion coefficients are shown in the inside back cover of the Review. Explanatory notes to the statistical tables can be found after tables and figures. The figures presents: Changes in GDP, energy consumption and electricity consumption, Carbon dioxide emissions from fossile fuels use, Coal consumption, Consumption of natural gas, Peat consumption, Domestic oil deliveries, Import prices of oil, Consumer prices of principal oil products, Fuel prices in heat production, Fuel prices in electricity production, Price of electricity by type of consumer, Average monthly spot prices at the Nord pool power exchange, Total energy consumption by source and CO 2 -emissions, Supply and total consumption of electricity GWh, Energy imports by country of origin in January-June 2003, Energy exports by recipient country in January-June 2003, Consumer prices of liquid fuels, Consumer prices of hard coal, natural gas and indigenous fuels, Price of natural gas by type of consumer, Price of electricity by type of consumer, Price of district heating by type of consumer, Excise taxes, value added taxes and fiscal charges and fees included in consumer prices of some energy sources and Excise taxes, precautionary stock fees on oil pollution fees on energy products

  11. Statistics

    International Nuclear Information System (INIS)

    2004-01-01

    For the year 2003 and 2004, the figures shown in the tables of the Energy Review are partly preliminary. The annual statistics of the Energy Review also includes historical time-series over a longer period (see e.g. Energiatilastot, Statistics Finland, Helsinki 2003, ISSN 0785-3165). The applied energy units and conversion coefficients are shown in the inside back cover of the Review. Explanatory notes to the statistical tables can be found after tables and figures. The figures presents: Changes in GDP, energy consumption and electricity consumption, Carbon dioxide emissions from fossile fuels use, Coal consumption, Consumption of natural gas, Peat consumption, Domestic oil deliveries, Import prices of oil, Consumer prices of principal oil products, Fuel prices in heat production, Fuel prices in electricity production, Price of electricity by type of consumer, Average monthly spot prices at the Nord pool power exchange, Total energy consumption by source and CO 2 -emissions, Supplies and total consumption of electricity GWh, Energy imports by country of origin in January-March 2004, Energy exports by recipient country in January-March 2004, Consumer prices of liquid fuels, Consumer prices of hard coal, natural gas and indigenous fuels, Price of natural gas by type of consumer, Price of electricity by type of consumer, Price of district heating by type of consumer, Excise taxes, value added taxes and fiscal charges and fees included in consumer prices of some energy sources and Excise taxes, precautionary stock fees on oil pollution fees

  12. Statistics

    International Nuclear Information System (INIS)

    2000-01-01

    For the year 1999 and 2000, part of the figures shown in the tables of the Energy Review are preliminary or estimated. The annual statistics of the Energy also includes historical time series over a longer period (see e.g., Energiatilastot 1999, Statistics Finland, Helsinki 2000, ISSN 0785-3165). The inside of the Review's back cover shows the energy units and the conversion coefficients used for them. Explanatory notes to the statistical tables can be found after tables and figures. The figures presents: Changes in the volume of GNP and energy consumption, Changes in the volume of GNP and electricity, Coal consumption, Natural gas consumption, Peat consumption, Domestic oil deliveries, Import prices of oil, Consumer prices of principal oil products, Fuel prices for heat production, Fuel prices for electricity production, Carbon dioxide emissions, Total energy consumption by source and CO 2 -emissions, Electricity supply, Energy imports by country of origin in January-June 2000, Energy exports by recipient country in January-June 2000, Consumer prices of liquid fuels, Consumer prices of hard coal, natural gas and indigenous fuels, Average electricity price by type of consumer, Price of district heating by type of consumer, Excise taxes, value added taxes and fiscal charges and fees included in consumer prices of some energy sources and Energy taxes and precautionary stock fees on oil products

  13. THE STUDY ON THE EFFECT OF FORMULATION VARIABLES ON IN VITRO FLOATING TIME AND THE RELEASE PROPERTIES OF A FLOATING DRUG DELIVERY SYSTEM BY A STATISTICAL OPTIMIZATION TECHNIQUE

    Directory of Open Access Journals (Sweden)

    C. NARENDRA

    2008-03-01

    Full Text Available The present investigation concerns the evaluation of the effect of formulation variables on in vitro floating time and the release properties in developing a floating drug delivery system (FDDS containing a highly water soluble drug metoprolol tartrate (MT in the presence of a gas generating agent. A 32 full factorial design was employed in formulating the FDDS containing hydroxyl propylmethylcellulose (HPMC K4M and sodium carboxymethylcellulose (NaCMC as swellable polymers. Drug-to-polymer ratio and polymer-to-polymer ratio were included as independent variables. The main effect and the interaction terms were quantitatively evaluated by a quadratic model to predict formulations with the floating time desired, and the release properties. It was found that only drug-to-polymer ratio and its quadratic term were found to be significantly affective for all the response variables. Non-Fickian transport was confirmed as a release mechanism from the optimized formulations. The desirability function was used to optimize the response variables, each having a different target, and the observed responses were highly agreed with experimental values. The results demonstrate the feasibility of the model in the development of FDDS containing a highly water-soluble drug MT.

  14. Statistical model for the mechanical behavior of the tissue engineering non-woven fibrous matrices under large deformation.

    Science.gov (United States)

    Rizvi, Mohd Suhail; Pal, Anupam

    2014-09-01

    The fibrous matrices are widely used as scaffolds for the regeneration of load-bearing tissues due to their structural and mechanical similarities with the fibrous components of the extracellular matrix. These scaffolds not only provide the appropriate microenvironment for the residing cells but also act as medium for the transmission of the mechanical stimuli, essential for the tissue regeneration, from macroscopic scale of the scaffolds to the microscopic scale of cells. The requirement of the mechanical loading for the tissue regeneration requires the fibrous scaffolds to be able to sustain the complex three-dimensional mechanical loading conditions. In order to gain insight into the mechanical behavior of the fibrous matrices under large amount of elongation as well as shear, a statistical model has been formulated to study the macroscopic mechanical behavior of the electrospun fibrous matrix and the transmission of the mechanical stimuli from scaffolds to the cells via the constituting fibers. The study establishes the load-deformation relationships for the fibrous matrices for different structural parameters. It also quantifies the changes in the fiber arrangement and tension generated in the fibers with the deformation of the matrix. The model reveals that the tension generated in the fibers on matrix deformation is not homogeneous and hence the cells located in different regions of the fibrous scaffold might experience different mechanical stimuli. The mechanical response of fibrous matrices was also found to be dependent on the aspect ratio of the matrix. Therefore, the model establishes a structure-mechanics interdependence of the fibrous matrices under large deformation, which can be utilized in identifying the appropriate structure and external mechanical loading conditions for the regeneration of load-bearing tissues. Copyright © 2014 Elsevier Ltd. All rights reserved.

  15. A general contact mechanical formulation of multilayered structures and its application to deconvolute thickness/mechanical properties of glue used in surface force apparatus.

    Science.gov (United States)

    Math, Souvik; Horn, Roger; Jayaram, Vikram; Biswas, Sanjay Kumar

    2007-04-15

    Currently data obtained from surface force apparatus experiments are convoluted with the mechanical response of glue of unknown thickness, used to bond mica sheets to the substrates. This paper describes a formulation to precisely deconvolute out the forces between the mica sheets by determining the thickness of glue, knowing the mechanical properties of the glue. The formulation consists of a general solution based on the noniterative Hankel transform of the Laplace equation. The generality is achieved by treating all the layers except the one in contact as an effective lumped system consisting of a set of springs in series, where each spring represents a layer. The solution is validated by nanoindentation of trilayer systems consisting of layers with widely diverse mechanical properties, some differing from each other by three orders of magnitude. SFA experiments are done with carefully metered slabs of glue. The proposed method is validated by comparing the actual glue thicknesses with those determined using the present analysis.

  16. STATISTICAL DISTRIBUTION PATTERNS IN MECHANICAL AND FATIGUE PROPERTIES OF METALLIC MATERIALS

    OpenAIRE

    Tatsuo, SAKAI; Masaki, NAKAJIMA; Keiro, TOKAJI; Norihiko, HASEGAWA; Department of Mechanical Engineering, Ritsumeikan University; Department of Mechanical Engineering, Toyota College of Technology; Department of Mechanical Engineering, Gifu University; Department of Mechanical Engineering, Gifu University

    1997-01-01

    Many papers on the statistical aspect of materials strength have been collected and reviewed by The Research Group for Statistical Aspects of Materials Strength.A book of "Statistical Aspects of Materials Strength" was written by this group, and published in 1992.Based on the experimental data compiled in this book, distribution patterns of mechanical properties are systematically surveyed paying an attention to metallic materials.Thus one can obtain the fundamental knowledge for a reliabilit...

  17. Casein Films: The Effects of Formulation, Environmental Conditions and the Addition of Citric Pectin on the Structure and Mechanical Properties

    Directory of Open Access Journals (Sweden)

    Laetitia M. Bonnaillie

    2014-07-01

    Full Text Available Thin casein films for food packaging applications reportedly possess good strength and low oxygen permeability, but low elasticity and high sensitivity to moisture. Modifying the films to target specific behaviors depending on environmental conditions can enable a variety of commercial applications for casein-based films. The mechanical properties of solvent-cast (15% solids calcium-caseinate/glycerol films (CaCas:Gly ratio of 3:1 were characterized as a function of processing and environmental conditions, including film thickness, solution formulation and ambient humidity (from 22% to 70% relative humidity (RH at ~20 °C. At constant RH, the elongation at break (EAB had a strong positive dependence on the film thickness. When RH increased, the tensile strength (TS and modulus (E decreased approximately linearly, while EAB increased. From 0.05% to 1% (w/w of citric pectin (CP was then incorporated into CaCas/Gly films following seven different formulations (mixing sequences, to alter the protein network and to evaluate the effects of CP on the tensile properties of CaCas/Gly/CP films. At constant film thickness and ~60% RH, the addition of 0.1% or 1.0% CP to the films considerably increased or decreased EAB, TS and E in different directions and to different extents, depending on the formulation, while optical micrographs also showed vastly differing network configurations, suggesting complex formulation- and stoichiometry-dependent casein-pectin interactions within the dried films. Depending on the desired film properties and utilization conditions, pectin may be a useful addition to casein film formulations for food packaging applications.

  18. Principles of classical statistical mechanics: A perspective from the notion of complementarity

    International Nuclear Information System (INIS)

    Velazquez Abad, Luisberis

    2012-01-01

    Quantum mechanics and classical statistical mechanics are two physical theories that share several analogies in their mathematical apparatus and physical foundations. In particular, classical statistical mechanics is hallmarked by the complementarity between two descriptions that are unified in thermodynamics: (i) the parametrization of the system macrostate in terms of mechanical macroscopic observablesI=(I i ), and (ii) the dynamical description that explains the evolution of a system towards the thermodynamic equilibrium. As expected, such a complementarity is related to the uncertainty relations of classical statistical mechanics ΔI i Δη i ≥k. Here, k is the Boltzmann constant, η i =∂S(I|θ)/∂I i are the restituting generalized forces derived from the entropy S(I|θ) of a closed system, which is found in an equilibrium situation driven by certain control parameters θ=(θ α ). These arguments constitute the central ingredients of a reformulation of classical statistical mechanics from the notion of complementarity. In this new framework, Einstein postulate of classical fluctuation theory dp(I|θ)∼exp[S(I|θ)/k]dI appears as the correspondence principle between classical statistical mechanics and thermodynamics in the limit k→0, while the existence of uncertainty relations can be associated with the non-commuting character of certain operators. - Highlights: ► There exists a direct analogy between quantum and classical statistical mechanics. ► Statistical form of Le Chatellier principle leads to the uncertainty principle. ► Einstein postulate is simply the correspondence principle. ► Complementary quantities are associated with non-commuting operators.

  19. Main formulations of the finite element method for the problems of structural mechanics. Part 2

    Directory of Open Access Journals (Sweden)

    Ignat’ev Aleksandr Vladimirovich

    Full Text Available The author offers a classification of Finite Element formulations, which allows orienting in a great number of the published and continuing to be published works on the problem of raising the efficiency of this widespread numerical method. The second part of the article offers examination of straight formulations of FEM in the form of displacement approach, area method and classical mixed-mode method. The question of solution convergence according to FEM in the form of classical mixed-mode method is considered on the example of single-input single-output system of a beam in case of finite element grid refinement. The author draws a conclusion, that extinction of algebraic equations system of FEM in case of passage to the limit is not a peculiar feature of this method in general, but manifests itself only in some particular cases. At the same time the obtained results prove that FEM in mixed-mode form provides obtaining more stable results in case of finite element grid refinement in comparison with FEM in the form of displacement approach. It is quite obvious that the same qualities will appear also in two-dimensional systems.

  20. Main formulations of the finite element method for the problems of structural mechanics. Part 3

    Directory of Open Access Journals (Sweden)

    Ignat’ev Aleksandr Vladimirovich

    2015-01-01

    Full Text Available In this paper the author offers is the classification of the formulae of Finite Element Method. This classification help to orient in a huge number of published articles, as well as those to be published, which are dedicated to the problem of enhancing the efficiency of the most commonly used method. The third part of the article considers the variation formulations of FEM and the energy principles lying in the basis of it. If compared to the direct method, which is applied only to finite elements of a simple geometrical type, the variation formulations of FEM are applicable to the elements of any type. All the variation methods can be conventionally divided into two groups. The methods of the first group are based on the principle of energy functional stationarity - a potential system energy, additional energy or on the basis of these energies, which means the full energy. The methods of the second group are based on the variants of mathematical methods of weighted residuals for solving the differential equations, which in some cases can be handled according to the principle of possible displacements or extreme energy principles. The most widely used and multipurpose is the approach based on the use of energy principles coming from the energy conservation law: principle of possible changes in stress state, principle of possible change in stress-strain state.

  1. Statistics, synergy, and mechanism of multiple photogeneration of excitons in quantum dots: Fundamental and applied aspects

    International Nuclear Information System (INIS)

    Oksengendler, B. L.; Turaeva, N. N.; Uralov, I.; Marasulov, M. B.

    2012-01-01

    The effect of multiple exciton generation is analyzed based on statistical physics, quantum mechanics, and synergetics. Statistical problems of the effect of multiple exciton generation (MEG) are broadened and take into account not only exciton generation, but also background excitation. The study of the role of surface states of quantum dots is based on the synergy of self-catalyzed electronic reactions. An analysis of the MEG mechanism is based on the idea of electronic shaking using the sudden perturbation method in quantum mechanics. All of the above-mentioned results are applied to the problem of calculating the limiting efficiency to transform solar energy into electric energy. (authors)

  2. Post electrical or lightning injury syndrome: a proposal for an American Psychiatric Association's Diagnostic and Statistical Manual formulation with implications for treatment.

    Science.gov (United States)

    Andrews, Christopher J; Reisner, Andrew D; Cooper, Mary Ann

    2017-09-01

    In the past, victims of electrical and lightning injuries have been assessed in a manner lacking a systematic formulation, and against ad hoc criteria, particularly in the area of neuropsychological disability. In this manner patients have, for example, only been partially treated, been poorly or incorrectly diagnosed, and have been denied the full benefit of compensation for their injuries. This paper contains a proposal for diagnostic criteria particularly for the neuropsychological aspects of the post injury syndrome. It pays attention to widely published consistent descriptions of the syndrome, and a new cluster analysis of post electrical injury patients. It formulates a proposal which could be incorporated into future editions of the American Psychiatric Association's Diagnostic and Statistical Manual (DSM). The major neuropsychological consequences include neurocognitive dysfunction, and memory subgroup dysfunction, with ongoing consequences, and sometimes including progressive or delayed psychiatric, cognitive, and/or neurological symptoms. The proposed diagnostic criteria insist on a demonstrated context for the injury, both specifying the shock circumstance, and also physical consequences. It allows for a certain delay in onset of symptoms. It recognizes exclusory conditions. The outcome is a proposal for a DSM classification for the post electrical or lightning injury syndrome. This proposal is considered important for grounding patient treatment, and for further treatment trials. Options for treatment in electrical or lightning injury are summarised, and future trials are foreshadowed.

  3. Comparison of algebraic and analytical approaches to the formulation of the statistical model-based reconstruction problem for X-ray computed tomography.

    Science.gov (United States)

    Cierniak, Robert; Lorent, Anna

    2016-09-01

    The main aim of this paper is to investigate properties of our originally formulated statistical model-based iterative approach applied to the image reconstruction from projections problem which are related to its conditioning, and, in this manner, to prove a superiority of this approach over ones recently used by other authors. The reconstruction algorithm based on this conception uses a maximum likelihood estimation with an objective adjusted to the probability distribution of measured signals obtained from an X-ray computed tomography system with parallel beam geometry. The analysis and experimental results presented here show that our analytical approach outperforms the referential algebraic methodology which is explored widely in the literature and exploited in various commercial implementations. Copyright © 2016 Elsevier Ltd. All rights reserved.

  4. To the problem of the statistical basis of evaluation of the mechanical safety factor

    International Nuclear Information System (INIS)

    Tsyganov, S.V.

    2009-01-01

    The methodology applied for the safety factor assessment of the WWER fuel cycles uses methods and terms of statistics. Value of the factor is calculated on the basis of estimation of probability to meet predefined limits. Such approach demands the special attention to the statistical properties of parameters of interest. Considering the mechanical constituents of the engineering factor it is assumed uncertainty factors of safety parameters are stochastic values. It characterized by probabilistic distributions that can be unknown. Traditionally in the safety factor assessment process the unknown parameters are estimated from the conservative points of view. This paper analyses how the refinement of the factors distribution parameters is important for the assessment of the mechanical safety factor. For the analysis the statistical approach is applied for modelling of different type of factor probabilistic distributions. It is shown the significant influence of the shape and parameters of distributions for some factors on the value of mechanical safety factor. (Authors)

  5. Statistical mechanics of directed models of polymers in the square lattice

    CERN Document Server

    Rensburg, J V

    2003-01-01

    Directed square lattice models of polymers and vesicles have received considerable attention in the recent mathematical and physical sciences literature. These are idealized geometric directed lattice models introduced to study phase behaviour in polymers, and include Dyck paths, partially directed paths, directed trees and directed vesicles models. Directed models are closely related to models studied in the combinatorics literature (and are often exactly solvable). They are also simplified versions of a number of statistical mechanics models, including the self-avoiding walk, lattice animals and lattice vesicles. The exchange of approaches and ideas between statistical mechanics and combinatorics have considerably advanced the description and understanding of directed lattice models, and this will be explored in this review. The combinatorial nature of directed lattice path models makes a study using generating function approaches most natural. In contrast, the statistical mechanics approach would introduce...

  6. To the problem of the statistical basis of evaluation of the mechanical safety factor

    International Nuclear Information System (INIS)

    Tsyganov, S.

    2009-01-01

    The methodology applied for the safety factor assessment of the VVER fuel cycles uses methods and terms of statistics. Value of the factor is calculated on the basis of estimation of probability to meet predefined limits. Such approach demands the special attention to the statistical properties of parameters of interest. Considering the mechanical constituents of the engineering factor it is assumed uncertainty factors of safety parameters are stochastic values. It characterized by probabilistic distributions that can be unknown. Traditionally in the safety factor assessment process the unknown parameters are estimated from the conservative points of view. This paper analyses how the refinement of the factors distribution parameters is important for the assessment of the mechanical safety factor. For the analysis the statistical approach is applied for modelling of different type of factor probabilistic distributions. It is shown the significant influence of the shape and parameters of distributions for some factors on the value of mechanical safety factor. (author)

  7. Menzerath-Altmann Law: Statistical Mechanical Interpretation as Applied to a Linguistic Organization

    Science.gov (United States)

    Eroglu, Sertac

    2014-10-01

    The distribution behavior described by the empirical Menzerath-Altmann law is frequently encountered during the self-organization of linguistic and non-linguistic natural organizations at various structural levels. This study presents a statistical mechanical derivation of the law based on the analogy between the classical particles of a statistical mechanical organization and the distinct words of a textual organization. The derived model, a transformed (generalized) form of the Menzerath-Altmann model, was termed as the statistical mechanical Menzerath-Altmann model. The derived model allows interpreting the model parameters in terms of physical concepts. We also propose that many organizations presenting the Menzerath-Altmann law behavior, whether linguistic or not, can be methodically examined by the transformed distribution model through the properly defined structure-dependent parameter and the energy associated states.

  8. Effects of the Formulations of Silicon-Based Composite Anodes on their Mechanical, Storage, and Electrochemical Properties.

    Science.gov (United States)

    Assresahegn, Birhanu Desalegn; Bélanger, Daniel

    2017-10-23

    In this work, the effects of the formulation of silicon-based composite anodes on their mechanical, storage, and electrochemical properties were investigated. The electrode formulation was changed through the use of hydrogenated or modified (through the covalent attachment of a binding additive such as polyacrylic acid) silicon and acetylene black or graphene sheets as conducting additives. A composite anode with a covalently grafted binder had the highest elongation without breakages and strong adhesion to the current collector. These mechanical properties depend significantly on the conductive carbon additive used and the use of graphene sheets instead of acetylene black can improve elongation and adhesion significantly. After 180 days of storage under ambient conditions, the electronic conductivity and discharge capacity of the modified silicon electrode showed much smaller decreases in these properties than those of the hydrogenated silicon composite electrode, indicating that the modification can result in passivation and a constant composition of the active material. Moreover, the composite Si anode has a high packing density. Consequently, thin-film electrodes with very high material loadings can be prepared without decreased electrochemical performance. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  9. Remarks on the formulation of quantum mechanics on noncommutative phase spaces

    International Nuclear Information System (INIS)

    Muthukumar, Balasundaram

    2007-01-01

    We consider the probabilistic description of nonrelativistic, spinless one-particle classical mechanics, and immerse the particle in a deformed noncommutative phase space in which position coordinates do not commute among themselves and also with canonically conjugate momenta. With a postulated normalized distribution function in the quantum domain, the square of the Dirac delta density distribution in the classical case is properly realised in noncommutative phase space and it serves as the quantum condition. With only these inputs, we pull out the entire formalisms of noncommutative quantum mechanics in phase space and in Hilbert space, and elegantly establish the link between classical and quantum formalisms and between Hilbert space and phase space formalisms of noncommutative quantum mechanics. Also, we show that the distribution function in this case possesses 'twisted' Galilean symmetry

  10. The origin of the algebra of quantum operators in the stochastic formulation of quantum mechanics

    International Nuclear Information System (INIS)

    Davidson, M.

    1979-01-01

    The origin of the algebra of the non-commuting operators of quantum mechanics is explained in the general Fenyes-Nelson stochastic models in which the diffusion constant is a free parameter. This is achieved by continuing the diffusion constant to imaginary values, a continuation which destroys the physical interpretation, but does not affect experimental predictions. This continuation leads to great mathematical simplification in the stochastic theory, and to an understanding of the entire mathematical formalism of quantum mechanics. It is more than a formal construction because the diffusion parameter is not an observable in these theories. (Auth.)

  11. The Double-Well Potential in Quantum Mechanics: A Simple, Numerically Exact Formulation

    Science.gov (United States)

    Jelic, V.; Marsiglio, F.

    2012-01-01

    The double-well potential is arguably one of the most important potentials in quantum mechanics, because the solution contains the notion of a state as a linear superposition of "classical" states, a concept which has become very important in quantum information theory. It is therefore desirable to have solutions to simple double-well potentials…

  12. The mechanism of action of MF59 - an innately attractive adjuvant formulation.

    Science.gov (United States)

    O'Hagan, D T; Ott, G S; De Gregorio, E; Seubert, A

    2012-06-19

    MF59 is a safe and effective vaccine adjuvant which was originally approved to be included in a licensed influenza vaccine to be used in the elderly in Europe in 1997. The MF59 adjuvanted influenza vaccine (Fluad™) is now licensed in more than 20 countries worldwide and more than 85 million doses have been administered. More recently the vaccine adjuvant has also been shown to be safe and effective in young children and resulted in a significant increase in influenza vaccine efficacy in a controlled clinical trial in Europe. Since the early days of its discovery we have explored the mechanism of action of MF59, using a variety of available techniques. In recent years we have explored more thoroughly the mechanism of action using new and more sophisticated techniques. It is remarkable how consistent the data has been, using a variety of different approaches both in several small animal models and also using human immune cells in vitro. Here we present a summary of all the work performed to date on the mechanism of action of MF59 and we present a unified theory based on the accumulated data of how it exerts its adjuvant effects. A key element of the mechanism of action appears to be the creation of a transient 'immunocompetent' local environment at the injection site, resulting in the recruitment of key immune cells, which are able to take up antigen and adjuvant and transport them to the local lymph nodes, where the immune response is induced. This recruitment appears to be triggered by the induction of a chemokine driven gradient by the impact of MF59 on local cells, which are activated to secrete further chemokines, which are recruitment factors for more immune cells. Copyright © 2011 Elsevier Ltd. All rights reserved.

  13. Quantum mechanics: new experiments, new applications, and new formulations of old questions

    International Nuclear Information System (INIS)

    Menskii, Mikhail B

    2000-01-01

    Some of the quantum mechanical conceptual problems, their current status, and related theoretical developments are reviewed. The characteristics of the entangled quantum states are analyzed, and new experiments and quantum information applications involving such states are discussed. The well-known paradox of Schroedinger's cat (the impossibility of observing superpositions of macroscopically distinct states that are predicted by quantum mechanics) is discussed. It is shown that decoherence (arising when a quantum system is measured in such a way that some information about its state is recorded in its environment) prevents the distinguishing of a superposition and the corresponding mixture. This overcomes the difficulties associated with the paradoxical nature of quantum measurement provided we remain within the framework of the theory of open systems. Other conceptual difficulties, while actually lying outside physics, are now the subject of much research and have already led to new interesting interpretations of quantum mechanics. The suggestion of Wigner and others that the observer's consciousness be included in the theory of quantum measurement is discussed in this context. A hypothesis is put forward which might enable the functioning of consciousness to be described in quantum measurement terms. (reviews of topical problems)

  14. Ergodic theory, interpretations of probability and the foundations of statistical mechanics

    NARCIS (Netherlands)

    van Lith, J.H.

    2001-01-01

    The traditional use of ergodic theory in the foundations of equilibrium statistical mechanics is that it provides a link between thermodynamic observables and microcanonical probabilities. First of all, the ergodic theorem demonstrates the equality of microcanonical phase averages and infinite time

  15. An introduction to conformal invariance in quantum field theory and statistical mechanics

    International Nuclear Information System (INIS)

    Boyanovsky, D.; Naon, C.M.

    1990-01-01

    The subject of conformal invariance provides an extraordinarly successful and productive symbiosis between statistical mechanics and quantum field theory. The main goal of this paper, which is tailored to a wide audience, is to give an introduction to such vast subject (C.P.)

  16. The steady state of heterogeneous catalysis, studied by first-principles statistical mechanics

    NARCIS (Netherlands)

    Reuter, K.; Frenkel, D.; Scheffler, M.

    2004-01-01

    The turnover frequency of the catalytic oxidation of CO at RuO2(110) was calculated as a function of temperature and partial pressures using ab initio statistical mechanics. The underlying energetics of the gas-phase molecules, dissociation, adsorption, surface diffusion, surface chemical reactions,

  17. Completely X-symmetric S-matrices corresponding to theta functions and models of statistical mechanics

    International Nuclear Information System (INIS)

    Chudnovsky, D.V.; Chudnovsky, G.V.

    1981-01-01

    We consider general expressions of factorized S-matrices with Abelian symmetry expressed in terms of theta-functions. These expressions arise from representations of the Heisenberg group. New examples of factorized S-matrices lead to a large class of completely integrable models of statistical mechanics which generalize the XYZ-model of the eight-vertex model. (orig.)

  18. Metamodelling Messages Conveyed in Five Statistical Mechanical Textbooks from 1936 to 2001

    Science.gov (United States)

    Niss, Martin

    2009-01-01

    Modelling is a significant aspect of doing physics and it is important how this activity is taught. This paper focuses on the explicit or implicit messages about modelling conveyed to the student in the treatments of phase transitions in statistical mechanics textbooks at beginning graduate level. Five textbooks from the 1930s to the present are…

  19. Statistical mechanical perturbation theory of solid-vapor interfacial free energy

    NARCIS (Netherlands)

    Kalikmanov, Vitalij Iosifovitsj; Hagmeijer, Rob; Venner, Cornelis H.

    2017-01-01

    The solid–vapor interfacial free energy γsv plays an important role in a number of physical phenomena, such as adsorption, wetting, and adhesion. We propose a closed form expression for the orientation averaged value of this quantity using a statistical mechanical perturbation approach developed in

  20. Statistical Mechanical Perturbation Theory of Solid−Vapor Interfacial Free Energy

    NARCIS (Netherlands)

    Kalikmanov, V.I.; Hagmeijer, R.; Venner, C.H.

    2017-01-01

    The solid–vapor interfacial free energy γsv plays an important role in a number of physical phenomena, such as adsorption, wetting, and adhesion. We propose a closed form expression for the orientation averaged value of this quantity using a statistical mechanical perturbation approach developed in

  1. Quantum Statistical Mechanics, L-Series and Anabelian Geometry I: Partition Functions

    NARCIS (Netherlands)

    Marcolli, Matilde; Cornelissen, Gunther

    2014-01-01

    The zeta function of a number field can be interpreted as the partition function of an associated quantum statistical mechanical (QSM) system, built from abelian class field theory. We introduce a general notion of isomorphism of QSM-systems and prove that it preserves (extremal) KMS equilibrium

  2. Fundamental problems in statistical mechanics VI. Proceedings of the sixth international summer school

    Energy Technology Data Exchange (ETDEWEB)

    Cohen, E G.D.

    1985-01-01

    The following topics were dealt with: walks, walls and ordering in low dimensions; renormalisation of fluids; wetting transition; phases and phase transitions; liquid-vapour interface; statistical mechanics in lattice gauge theory; hydrodynamic instabilities; complex dynamics and chaos; dynamical transitions; phase separation and pattern formation; kinetic theory of clustering; localisation.

  3. Nonadditive entropy and nonextensive statistical mechanics - Some central concepts and recent applications

    International Nuclear Information System (INIS)

    Tsallis, Constantino; Tirnakli, Ugur

    2010-01-01

    We briefly review central concepts concerning nonextensive statistical mechanics, based on the nonadditive entropy shown. Among others, we focus on possible realizations of the q-generalized Central Limit Theorem, including at the edge of chaos of the logistic map, and for quasi-stationary states of many-body long-range-interacting Hamiltonian systems.

  4. Statistical evaluation of the mechanical properties of high-volume class F fly ash concretes

    KAUST Repository

    Yoon, Seyoon; Monteiro, Paulo J.M.; Macphee, Donald E.; Glasser, Fredrik P.; Imbabi, Mohammed Salah-Eldin

    2014-01-01

    the authors experimentally and statistically investigated the effects of mix-design factors on the mechanical properties of high-volume class F fly ash concretes. A total of 240 and 32 samples were produced and tested in the laboratory to measure compressive

  5. Some properties of the representation of the quasilocal observables in statistical mechanics and quantum field theory

    International Nuclear Information System (INIS)

    Testard, D.; Centre National de la Recherche Scientifique, 13 - Marseille

    1977-09-01

    For a finite non zero temperature state in Statistical Mechanics it is proved that the factor obtained in the corresponding representation of the quasilocal algebra has the property of Araki. The same result also holds for the 'wedge-algebras' of a hermitian scalar Wightman field

  6. Statistical and stochastic aspects of the delocalization problem in quantum mechanics

    International Nuclear Information System (INIS)

    Claverie, P.; Diner, S.

    1976-01-01

    The space-time behaviour of electrons in atoms and molecules is reviewed. The wave conception of the electron is criticized and the poverty of the non-reductionist attitude is underlined. Further, the two main interpretations of quantum mechanics are recalled: the Copenhagen and the Statistical Interpretations. The meaning and the successes of the Statistical Interpretation are explained and it is shown that it does not solve all problems because quantum mechanics is irreducible to a classical statistical theory. The fluctuation of the particle number and its relationship to loge theory, delocalization and correlation is studied. Finally, different stochastic models for microphysics are reviewed. The markovian Fenyes-Nelson process allows an interpretation of the original heuristic considerations of Schroedinger. Non-markov processes with Schroedinger time evolution are shown to be equivalent to the base state analysis of Feynmann but they are unsatisfactory from a probabilistic point of view. Stochastic electrodynamics is presented as the most satisfactory conception nowadays

  7. Derivation of some new distributions in statistical mechanics using maximum entropy approach

    Directory of Open Access Journals (Sweden)

    Ray Amritansu

    2014-01-01

    Full Text Available The maximum entropy principle has been earlier used to derive the Bose Einstein(B.E., Fermi Dirac(F.D. & Intermediate Statistics(I.S. distribution of statistical mechanics. The central idea of these distributions is to predict the distribution of the microstates, which are the particle of the system, on the basis of the knowledge of some macroscopic data. The latter information is specified in the form of some simple moment constraints. One distribution differs from the other in the way in which the constraints are specified. In the present paper, we have derived some new distributions similar to B.E., F.D. distributions of statistical mechanics by using maximum entropy principle. Some proofs of B.E. & F.D. distributions are shown, and at the end some new results are discussed.

  8. Polycaprolactone/maltodextrin nanocarrier for intracellular drug delivery: formulation, uptake mechanism, internalization kinetics, and subcellular localization.

    Science.gov (United States)

    Korang-Yeboah, Maxwell; Gorantla, Yamini; Paulos, Simon A; Sharma, Pankaj; Chaudhary, Jaideep; Palaniappan, Ravi

    2015-01-01

    Prostate cancer (PCa) disease progression is associated with significant changes in intracellular and extracellular proteins, intracellular signaling mechanism, and cancer cell phenotype. These changes may have direct impact on the cellular interactions with nanocarriers; hence, there is the need for a much-detailed understanding, as nanocarrier cellular internalization and intracellular sorting mechanism correlate directly with bioavailability and clinical efficacy. In this study, we report the differences in the rate and mechanism of cellular internalization of a biocompatible polycaprolactone (PCL)/maltodextrin (MD) nanocarrier system for intracellular drug delivery in LNCaP, PC3, and DU145 PCa cell lines. PCL/MD nanocarriers were designed and characterized. PCL/MD nanocarriers significantly increased the intracellular concentration of coumarin-6 and fluorescein isothiocyanate-labeled bovine serum albumin, a model hydrophobic and large molecule, respectively. Fluorescence microscopy and flow cytometry analysis revealed rapid internalization of the nanocarrier. The extent of nanocarrier cellular internalization correlated directly with cell line aggressiveness. PCL/MD internalization was highest in PC3 followed by DU145 and LNCaP, respectively. Uptake in all PCa cell lines was metabolically dependent. Extraction of endogenous cholesterol by methyl-β-cyclodextrin reduced uptake by 75%±4.53% in PC3, 64%±6.01% in LNCaP, and 50%±4.50% in DU145, indicating the involvement of endogenous cholesterol in cellular internalization. Internalization of the nanocarrier in LNCaP was mediated mainly by macropinocytosis and clathrin-independent pathways, while internalization in PC3 and DU145 involved clathrin-mediated endocytosis, clathrin-independent pathways, and macropinocytosis. Fluorescence microscopy showed a very diffused and non-compartmentalized subcellular localization of the PCL/MD nanocarriers with possible intranuclear localization and minor colocalization in

  9. Chemical stability of insulin. 4. Mechanisms and kinetics of chemical transformations in pharmaceutical formulation.

    Science.gov (United States)

    Brange, J

    1992-01-01

    Insulin decomposes by a multitude of chemical reactions [1-3]. It deamidates at two different residues by entirely different mechanisms. In acid, deamidation at AsnA21 is intramolecularly catalyzed by the protonated C-terminal, whereas above pH 6 an intermediate imide formation at residue AsnB3 leads to isoAsp and Asp derivatives. The imide formation requires a large rotation around the alpha-carbon/peptide carbonyl carbon bond at B3, corresponding to a 10 A movement of the B-chain N-terminal. The main determinant for the rate of B3 deamidation, as well as for the ratio between the two products formed, is the local conformational structure, which is highly influenced by various excipients and the physical state of the insulin. An amazing thermolysin-like, autoproteolytic cleavage of the A-chain takes place in rhombohedral insulin crystals, mediated by a concerted catalytic action by several, inter-hexameric functional groups and Zn2+. Intermolecular, covalent cross-linking of insulin molecules occurs via several mechanisms. The most prominent type of mechanism is aminolysis by the N-terminals, leading to isopeptide linkages with the A-chain side-chain amides of residues GlnA15, AsnA18 and AsnA21. The same type of reaction also leads to covalent cross-linking of the N-terminal in protamine with insulin. Disulfide exchange reactions, initiated by lysis of the A7-B7 disulfide bridge, lead mainly to formation of covalent oligo- and polymers. Activation energy (Ea) for the neutral deamidation and the aminolysis reactions was found to be 80 and 119 KJ/mol, respectively.

  10. Statistical mechanics provides novel insights into microtubule stability and mechanism of shrinkage.

    Directory of Open Access Journals (Sweden)

    Ishutesh Jain

    2015-02-01

    Full Text Available Microtubules are nano-machines that grow and shrink stochastically, making use of the coupling between chemical kinetics and mechanics of its constituent protofilaments (PFs. We investigate the stability and shrinkage of microtubules taking into account inter-protofilament interactions and bending interactions of intrinsically curved PFs. Computing the free energy as a function of PF tip position, we show that the competition between curvature energy, inter-PF interaction energy and entropy leads to a rich landscape with a series of minima that repeat over a length-scale determined by the intrinsic curvature. Computing Langevin dynamics of the tip through the landscape and accounting for depolymerization, we calculate the average unzippering and shrinkage velocities of GDP protofilaments and compare them with the experimentally known results. Our analysis predicts that the strength of the inter-PF interaction (E(s(m has to be comparable to the strength of the curvature energy (E(b(m such that E(s(m - E(b(m ≈ 1kBT, and questions the prevalent notion that unzippering results from the domination of bending energy of curved GDP PFs. Our work demonstrates how the shape of the free energy landscape is crucial in explaining the mechanism of MT shrinkage where the unzippered PFs will fluctuate in a set of partially peeled off states and subunit dissociation will reduce the length.

  11. Nonequilibrium phase transitions and bifurcations of limit cycles and tori- a new research topic for statistical mechanics mechanics

    International Nuclear Information System (INIS)

    Haken, H.

    1980-01-01

    In the development of statistical mechanics we can more or less distinguish between two steps. First of all the main objective of statistical mechanics had been to give thermodynamics a solid theoretical basis starting from the microscopic world. The next step has then been performed in parallel with the development of irreversible thermodynamics dealing with processes close to thermal equilibrium. The problems dealt with here are mainly transport and relaxation processes. Over the past years it has become apparent that there is a third field, namely processes far away from thermal equilibrium. The particular interest in those processes stems from the fact that in such situations order can be generated on a macroscopic scale. The ordered states can be maintained by a flux of energy or matter through, these systems. In the realm of synergetjcs we have studied numerous examples and we now know that the occurrence of many of the ordered structures is governed by the same basic principles. (author)

  12. Statistical mechanics of dense plasmas and implications for the plasma polarization shift

    International Nuclear Information System (INIS)

    Rogers, F.J.

    1984-01-01

    A brief description of the statistical mechanics of reacting, dense, plasmas is given. The results do not support a Debye-like polarization shift at low density. It is shown that the electronic charge density factors into a strongly quantum mechanical part, that is not much affected by many body correlations and a weakly quantum mechanical part, that is considerably effected by many body correlations. The few body charge density is obtained from direct solution of the Schroedinger equation and the many body charge density is obtained from the hypernetted chain equation through the introduction of a pseudopotential

  13. Global and Local Mechanical Responses for Necking of Rectangular Bars Using Updated and Total Lagrangian Finite Element Formulations

    Directory of Open Access Journals (Sweden)

    Claudio A. Careglio

    2016-01-01

    Full Text Available In simulations of forged and stamping processes using the finite element method, load displacement paths and three-dimensional stress and strains states should be well and reliably represented. The simple tension test is a suitable and economical tool to calibrate constitutive equations with finite strains and plasticity for those simulations. A complex three-dimensional stress and strain states are developed when this test is done on rectangular bars and the necking phenomenon appears. In this work, global and local numerical results of the mechanical response of rectangular bars subjected to simple tension test obtained from two different finite element formulations are compared and discussed. To this end, Updated and Total Lagrangian formulations are used in order to get the three-dimensional stress and strain states. Geometric changes together with strain and stress distributions at the cross section where necking occurs are assessed. In particular, a detailed analysis of the effective plastic strain, stress components in axial and transverse directions and pressure, and deviatoric stress components is presented. Specific numerical results are also validated with experimental measurements comparing, in turn, the performance of the two numerical approaches used in this study.

  14. Many-body problem in quantum mechanics and quantum statistical mechanics

    International Nuclear Information System (INIS)

    Lee, T.D.; Yang, C.N.

    1983-01-01

    This is a progress report on some work concerning the quantum mechanical calculation of the fugacity coefficients b/sub l/ (which correspond to the classical cluster integrals) of a Bose, a Fermi, and a Boltzmann gas at low temperatures. A binary collision expansion method is developed which allows for the systematic calculation of b/sub l/ as expansions in powers of a/λ, where a represents the parameters of the dimensions of length that characterize the low-energy two-body collision and λ is the thermal wavelength. To any power of (a/λ) the calculation of any specific b/sub l/ is reduced to a finite number of quadratures. The method, therefore, is the low-temperature counterpart of the high-temperature expansion of b/sub l/

  15. Spectral theory and quantum mechanics mathematical foundations of quantum theories, symmetries and introduction to the algebraic formulation

    CERN Document Server

    Moretti, Valter

    2017-01-01

    This book discusses the mathematical foundations of quantum theories. It offers an introductory text on linear functional analysis with a focus on Hilbert spaces, highlighting the spectral theory features that are relevant in physics. After exploring physical phenomenology, it then turns its attention to the formal and logical aspects of the theory. Further, this Second Edition collects in one volume a number of useful rigorous results on the mathematical structure of quantum mechanics focusing in particular on von Neumann algebras, Superselection rules, the various notions of Quantum Symmetry and Symmetry Groups, and including a number of fundamental results on the algebraic formulation of quantum theories. Intended for Master's and PhD students, both in physics and mathematics, the material is designed to be self-contained: it includes a summary of point-set topology and abstract measure theory, together with an appendix on differential geometry. The book also benefits established researchers by organizing ...

  16. Mechanical evaluation of bone gap filled with rigid formulations castor oil polyurethane and chitosan in horses

    Directory of Open Access Journals (Sweden)

    Rodrigo Crispim Moreira

    Full Text Available ABSTRACT: Often fractures of long bones in horses are comminuted and form bone gaps, which represent a major challenge for the fixation of these fractures by loss of contact between the fragments. Bone grafts help in treating this kind of fracture and synthetic materials have been gaining ground because of the limitations of autologous and heterologous grafts. In this study were performed compressive non destructive test in 10 bones with complete cross-bone gap in mid-diaphyseal of the third metacarpal bone of horses. Using a mechanism of "crossing" the 10 bones were used in the three groups (control, castor oil poliuretane and chitosan according to the filling material. After the test with maximum load of 1000N bone had a gap filled by another material and the test was repeated. Deformations caused on the whole bone, plate and bone tissue near and distant of gap were evaluated, using strain gauges adhered to the surface at these locations. There was a reduction in bone deformation from 14% (control to 3,5% and 4,8% by filling the gap with Chitosan and castor oil respectively, and a reduction of strain on the plate of 96% and 85% by filling gap with chitosan and castor respectively. An increase in intensity and direction of deformations occurred in bone near to gap after its filling; however, there was no difference in bone deformations occurring far the gap.

  17. Statistical mechanical analysis of the linear vector channel in digital communication

    International Nuclear Information System (INIS)

    Takeda, Koujin; Hatabu, Atsushi; Kabashima, Yoshiyuki

    2007-01-01

    A statistical mechanical framework to analyze linear vector channel models in digital wireless communication is proposed for a large system. The framework is a generalization of that proposed for code-division multiple-access systems in Takeda et al (2006 Europhys. Lett. 76 1193) and enables the analysis of the system in which the elements of the channel transfer matrix are statistically correlated with each other. The significance of the proposed scheme is demonstrated by assessing the performance of an existing model of multi-input multi-output communication systems

  18. Rapid Discrimination of Chlorpheniramine Maleate and Assessment of Its Surface Content Uniformity in a Pharmaceutical Formulation by NIR-CI Coupled with Statistical Measurement

    Directory of Open Access Journals (Sweden)

    Luwei Zhou

    2014-01-01

    Full Text Available This study demonstrated that near infrared chemical imaging (NIR-CI was a rapid and nondestructive technique for discrimination of chlorpheniramine maleate (CPM and assessment of its surface content uniformity (SCU in a pharmaceutical formulation. The characteristic wavenumber method was used for discriminating CPM distribution on the tablet surface. To assess the surface content uniformity of CPM, binary image and statistical measurement were proposed. Furthermore, high-performance liquid chromatography (HPLC was used as reference method for accurately determining volume content of CPM in the sample. Moreover, HPLC was performed to assess volume content uniformity (VCU of CPM in whole region and part region of the tablets. The NIR-CI result showed that the spatial distribution of CPM was heterogeneous on the tablet surface. Through the comparison of content uniformity of CPM determined by NIR-CI and HPLC, respectively, it demonstrated that a high degree of VCU did not imply a high degree of SCU of the samples. These results indicate that HPLC method is not suitable for testing SCU, and this has been verified by NIR-CI. This study proves the feasibility of NIR-CI for rapid discrimination of CPM and assessment of its SCU, which is helpful for the quality control of commercial CPM tablets.

  19. Three-Dimensional Color Code Thresholds via Statistical-Mechanical Mapping

    Science.gov (United States)

    Kubica, Aleksander; Beverland, Michael E.; Brandão, Fernando; Preskill, John; Svore, Krysta M.

    2018-05-01

    Three-dimensional (3D) color codes have advantages for fault-tolerant quantum computing, such as protected quantum gates with relatively low overhead and robustness against imperfect measurement of error syndromes. Here we investigate the storage threshold error rates for bit-flip and phase-flip noise in the 3D color code (3DCC) on the body-centered cubic lattice, assuming perfect syndrome measurements. In particular, by exploiting a connection between error correction and statistical mechanics, we estimate the threshold for 1D stringlike and 2D sheetlike logical operators to be p3DCC (1 )≃1.9 % and p3DCC (2 )≃27.6 % . We obtain these results by using parallel tempering Monte Carlo simulations to study the disorder-temperature phase diagrams of two new 3D statistical-mechanical models: the four- and six-body random coupling Ising models.

  20. Equilibration, thermalisation, and the emergence of statistical mechanics in closed quantum systems.

    Science.gov (United States)

    Gogolin, Christian; Eisert, Jens

    2016-05-01

    We review selected advances in the theoretical understanding of complex quantum many-body systems with regard to emergent notions of quantum statistical mechanics. We cover topics such as equilibration and thermalisation in pure state statistical mechanics, the eigenstate thermalisation hypothesis, the equivalence of ensembles, non-equilibration dynamics following global and local quenches as well as ramps. We also address initial state independence, absence of thermalisation, and many-body localisation. We elucidate the role played by key concepts for these phenomena, such as Lieb-Robinson bounds, entanglement growth, typicality arguments, quantum maximum entropy principles and the generalised Gibbs ensembles, and quantum (non-)integrability. We put emphasis on rigorous approaches and present the most important results in a unified language.

  1. Statistical mechanical foundation of the peridynamic nonlocal continuum theory: energy and momentum conservation laws.

    Science.gov (United States)

    Lehoucq, R B; Sears, Mark P

    2011-09-01

    The purpose of this paper is to derive the energy and momentum conservation laws of the peridynamic nonlocal continuum theory using the principles of classical statistical mechanics. The peridynamic laws allow the consideration of discontinuous motion, or deformation, by relying on integral operators. These operators sum forces and power expenditures separated by a finite distance and so represent nonlocal interaction. The integral operators replace the differential divergence operators conventionally used, thereby obviating special treatment at points of discontinuity. The derivation presented employs a general multibody interatomic potential, avoiding the standard assumption of a pairwise decomposition. The integral operators are also expressed in terms of a stress tensor and heat flux vector under the assumption that these fields are differentiable, demonstrating that the classical continuum energy and momentum conservation laws are consequences of the more general peridynamic laws. An important conclusion is that nonlocal interaction is intrinsic to continuum conservation laws when derived using the principles of statistical mechanics.

  2. Statistical mechanics of neocortical interactions: Path-integral evolution of short-term memory

    Science.gov (United States)

    Ingber, Lester

    1994-05-01

    Previous papers in this series of statistical mechanics of neocortical interactions (SMNI) have detailed a development from the relatively microscopic scales of neurons up to the macroscopic scales as recorded by electroencephalography (EEG), requiring an intermediate mesocolumnar scale to be developed at the scale of minicolumns (~=102 neurons) and macrocolumns (~=105 neurons). Opportunity was taken to view SMNI as sets of statistical constraints, not necessarily describing specific synaptic or neuronal mechanisms, on neuronal interactions, on some aspects of short-term memory (STM), e.g., its capacity, stability, and duration. A recently developed c-language code, pathint, provides a non-Monte Carlo technique for calculating the dynamic evolution of arbitrary-dimension (subject to computer resources) nonlinear Lagrangians, such as derived for the two-variable SMNI problem. Here, pathint is used to explicitly detail the evolution of the SMNI constraints on STM.

  3. Statistical-mechanical lattice models for protein-DNA binding in chromatin

    International Nuclear Information System (INIS)

    Teif, Vladimir B; Rippe, Karsten

    2010-01-01

    Statistical-mechanical lattice models for protein-DNA binding are well established as a method to describe complex ligand binding equilibria measured in vitro with purified DNA and protein components. Recently, a new field of applications has opened up for this approach since it has become possible to experimentally quantify genome-wide protein occupancies in relation to the DNA sequence. In particular, the organization of the eukaryotic genome by histone proteins into a nucleoprotein complex termed chromatin has been recognized as a key parameter that controls the access of transcription factors to the DNA sequence. New approaches have to be developed to derive statistical-mechanical lattice descriptions of chromatin-associated protein-DNA interactions. Here, we present the theoretical framework for lattice models of histone-DNA interactions in chromatin and investigate the (competitive) DNA binding of other chromosomal proteins and transcription factors. The results have a number of applications for quantitative models for the regulation of gene expression.

  4. Addressing the statistical mechanics of planet orbits in the solar system

    Science.gov (United States)

    Mogavero, Federico

    2017-10-01

    The chaotic nature of planet dynamics in the solar system suggests the relevance of a statistical approach to planetary orbits. In such a statistical description, the time-dependent position and velocity of the planets are replaced by the probability density function (PDF) of their orbital elements. It is natural to set up this kind of approach in the framework of statistical mechanics. In the present paper, I focus on the collisionless excitation of eccentricities and inclinations via gravitational interactions in a planetary system. The future planet trajectories in the solar system constitute the prototype of this kind of dynamics. I thus address the statistical mechanics of the solar system planet orbits and try to reproduce the PDFs numerically constructed by Laskar (2008, Icarus, 196, 1). I show that the microcanonical ensemble of the Laplace-Lagrange theory accurately reproduces the statistics of the giant planet orbits. To model the inner planets I then investigate the ansatz of equiprobability in the phase space constrained by the secular integrals of motion. The eccentricity and inclination PDFs of Earth and Venus are reproduced with no free parameters. Within the limitations of a stationary model, the predictions also show a reasonable agreement with Mars PDFs and that of Mercury inclination. The eccentricity of Mercury demands in contrast a deeper analysis. I finally revisit the random walk approach of Laskar to the time dependence of the inner planet PDFs. Such a statistical theory could be combined with direct numerical simulations of planet trajectories in the context of planet formation, which is likely to be a chaotic process.

  5. Mechanism for enhanced absorption of a solid dispersion formulation of LY2300559 using the artificial stomach duodenum model.

    Science.gov (United States)

    Polster, Christopher S; Wu, Sy-Juen; Gueorguieva, Ivelina; Sperry, David C

    2015-04-06

    An artificial stomach duodenum (ASD) model has been used to demonstrate the performance difference between two formulations of LY2300559, a low-solubility acidic developmental drug. The two formulations investigated were a conventional high-shear wet granulation (HSWG) formulation and a solid dispersion formulation. A pharmacokinetic study in humans demonstrated the enhanced performance of the solid dispersion formulation relative to the HSWG formulation. The Cmax and AUC of the solid dispersion was 2.6 and 1.9 times greater, respectively, compared to the HSWG formulation. In the ASD, the solid dispersion formulation performance was characterized by three main phases: (1) rapid release in the stomach, creating a supersaturated concentration of drug, (2) precipitation in the stomach, and (3) rapid redissolution of the precipitate in the duodenum to concentration levels that are supersaturated relative to crystalline drug. A series of complementary experiments were employed to describe this performance behavior mechanistically. Imaging experiments with a pH indicating dye showed that local pH gradients from meglumine in the solid dispersion formulation were responsible for creating a high initial supersaturation concentration in the stomach. Upon dissipation of meglumine, the drug precipitated in the stomach as an amorphous solid. Because the precipitated drug is in an amorphous form, it can then rapidly redissolve as it transits to the more neutral environment of the duodenum. This unexpected sequence of physical state changes gives a mechanistic explanation for the enhanced in vivo performance of the solid dispersion formulation relative to the HSWG formulation.

  6. A study of outliers in statistical distributions of mechanical properties of structural steels

    International Nuclear Information System (INIS)

    Oefverbeck, P.; Oestberg, G.

    1977-01-01

    The safety against failure of pressure vessels can be assessed by statistical methods, so-called probabilistic fracture mechanics. The data base for such estimations is admittedly rather meagre, making it necessary to assume certain conventional statistical distributions. Since the failure rates arrived at are low, for nuclear vessels of the order of 10 - to 10 - per year, the extremes of the variables involved, among other things the mechanical properties of the steel used, are of particular interest. A question sometimes raised is whether outliers, or values exceeding the extremes in the assumed distributions, might occur. In order to explore this possibility a study has been made of strength values of three qualities of structural steels, available in samples of up to about 12,000. Statistical evaluation of these samples with respect to outliers, using standard methods for this purpose, revealed the presence of such outliers in most cases, with a frequency of occurrence of, typically, a few values per thousand, estimated by the methods described. Obviously, statistical analysis alone cannot be expected to shed any light on the causes of outliers. Thus, the interpretation of these results with respect to their implication for the probabilistic estimation of the integrety of pressure vessels must await further studies of a similar nature in which the test specimens corresponding to outliers can be recovered and examined metallographically. For the moment the results should be regarded only as a factor to be considered in discussions of the safety of pressure vessels. (author)

  7. Geometric Approach to Quantum Statistical Mechanics and Application to Casimir Energy and Friction Properties

    International Nuclear Information System (INIS)

    Ichinose, Shoichi

    2010-01-01

    A geometric approach to general quantum statistical systems (including the harmonic oscillator) is presented. It is applied to Casimir energy and the dissipative system with friction. We regard the (N+1)-dimensional Euclidean coordinate system (X i ,τ) as the quantum statistical system of N quantum (statistical) variables (X τ ) and one Euclidean time variable (t). Introducing paths (lines or hypersurfaces) in this space (X τ ,t), we adopt the path-integral method to quantize the mechanical system. This is a new view of (statistical) quantization of the mechanical system. The system Hamiltonian appears as the area. We show quantization is realized by the minimal area principle in the present geometric approach. When we take a line as the path, the path-integral expressions of the free energy are shown to be the ordinary ones (such as N harmonic oscillators) or their simple variation. When we take a hyper-surface as the path, the system Hamiltonian is given by the area of the hyper-surface which is defined as a closed-string configuration in the bulk space. In this case, the system becomes a O(N) non-linear model. We show the recently-proposed 5 dimensional Casimir energy (ArXiv:0801.3064,0812.1263) is valid. We apply this approach to the visco-elastic system, and present a new method using the path-integral for the calculation of the dissipative properties.

  8. PREFACE: Counting Complexity: An international workshop on statistical mechanics and combinatorics

    Science.gov (United States)

    de Gier, Jan; Warnaar, Ole

    2006-07-01

    On 10-15 July 2005 the conference `Counting Complexity: An international workshop on statistical mechanics and combinatorics' was held on Dunk Island, Queensland, Australia in celebration of Tony Guttmann's 60th birthday. Dunk Island provided the perfect setting for engaging in almost all of Tony's life-long passions: swimming, running, food, wine and, of course, plenty of mathematics and physics. The conference was attended by many of Tony's close scientific friends from all over the world, and most talks were presented by his past and present collaborators. This volume contains the proceedings of the meeting and consists of 24 refereed research papers in the fields of statistical mechanics, condensed matter physics and combinatorics. These papers provide an excellent illustration of the breadth and scope of Tony's work. The very first contribution, written by Stu Whittington, contains an overview of the many scientific achievements of Tony over the past 40 years in mathematics and physics. The organizing committee, consisting of Richard Brak, Aleks Owczarek, Jan de Gier, Emma Lockwood, Andrew Rechnitzer and Ole Warnaar, gratefully acknowledges the Australian Mathematical Society (AustMS), the Australian Mathematical Sciences Institute (AMSI), the ARC Centre of Excellence for Mathematics and Statistics of Complex Systems (MASCOS), the ARC Complex Open Systems Research Network (COSNet), the Institute of Physics (IOP) and the Department of Mathematics and Statistics of The University of Melbourne for financial support in organizing the conference. Tony, we hope that your future years in mathematics will be numerous. Count yourself lucky! Tony Guttman

  9. The statistical mechanics of the classical two-dimensional Coulomb gas is exactly solved

    International Nuclear Information System (INIS)

    Samaj, L

    2003-01-01

    The model under consideration is a classical 2D Coulomb gas of pointlike positive and negative unit charges, interacting via a logarithmic potential. In the whole stability range of temperatures, the equilibrium statistical mechanics of this fluid model is exactly solvable via an equivalence with the integrable 2D sine-Gordon field theory. The exact solution includes the bulk thermodynamics, special cases of the surface thermodynamics and the large-distance asymptotic behaviour of the two-body correlation functions

  10. Dimensionally regularized Tsallis' statistical mechanics and two-body Newton's gravitation

    Science.gov (United States)

    Zamora, J. D.; Rocca, M. C.; Plastino, A.; Ferri, G. L.

    2018-05-01

    Typical Tsallis' statistical mechanics' quantifiers like the partition function and the mean energy exhibit poles. We are speaking of the partition function Z and the mean energy 〈 U 〉 . The poles appear for distinctive values of Tsallis' characteristic real parameter q, at a numerable set of rational numbers of the q-line. These poles are dealt with dimensional regularization resources. The physical effects of these poles on the specific heats are studied here for the two-body classical gravitation potential.

  11. Evaluation of mechanical properties of steel wire ropes by statistical methods

    Directory of Open Access Journals (Sweden)

    Boroška Ján

    1999-12-01

    Full Text Available The contribution deals with the evaluation of mechanical properties of steel wire ropes using statistical methods from the viewpoint of the quality of single wires as well as the internal construction of the wire ropes. The evaluation is based on the loading capacity calculated from the strength, number of folds and torsions. For the better ilustration, a box plot has been constructed.

  12. A reductionist perspective on quantum statistical mechanics: Coarse-graining of path integrals.

    Science.gov (United States)

    Sinitskiy, Anton V; Voth, Gregory A

    2015-09-07

    Computational modeling of the condensed phase based on classical statistical mechanics has been rapidly developing over the last few decades and has yielded important information on various systems containing up to millions of atoms. However, if a system of interest contains important quantum effects, well-developed classical techniques cannot be used. One way of treating finite temperature quantum systems at equilibrium has been based on Feynman's imaginary time path integral approach and the ensuing quantum-classical isomorphism. This isomorphism is exact only in the limit of infinitely many classical quasiparticles representing each physical quantum particle. In this work, we present a reductionist perspective on this problem based on the emerging methodology of coarse-graining. This perspective allows for the representations of one quantum particle with only two classical-like quasiparticles and their conjugate momenta. One of these coupled quasiparticles is the centroid particle of the quantum path integral quasiparticle distribution. Only this quasiparticle feels the potential energy function. The other quasiparticle directly provides the observable averages of quantum mechanical operators. The theory offers a simplified perspective on quantum statistical mechanics, revealing its most reductionist connection to classical statistical physics. By doing so, it can facilitate a simpler representation of certain quantum effects in complex molecular environments.

  13. Introduction to conformal invariance in statistical mechanics and to random surface models

    International Nuclear Information System (INIS)

    David, F.

    1995-01-01

    In the first part of these lectures I give a brief and somewhat superficial introduction to the techniques of conformal invariance and to a few applications in statistical mechanics in two dimensions. My purpose is to introduce the basic ideas and some standard results for the students who are not familiar with the theory, and to introduce concepts and tools which will be useful for the other lecturers, rather than to give a complete and up to date review of the subject. In the second part I discuss several problems in the statistical mechanics of two dimensional random surfaces and membranes. As an introduction, I present some basic facts about the statistical mechanics of one-dimensional objects and polymers, which are classical examples of objects with critical properties. Then I emphasize the special role of curvature energy and of the elastic energy associated with the internal structure of membranes, and the corresponding models of random surfaces. Finally, I discuss the specific problem of self-avoiding tethered surfaces, whose critical properties are still poorly understood, and for which the applicability of some basic techniques of field theory, such as renormalization group calculations, has been understood only recently. (orig.)

  14. A reductionist perspective on quantum statistical mechanics: Coarse-graining of path integrals

    International Nuclear Information System (INIS)

    Sinitskiy, Anton V.; Voth, Gregory A.

    2015-01-01

    Computational modeling of the condensed phase based on classical statistical mechanics has been rapidly developing over the last few decades and has yielded important information on various systems containing up to millions of atoms. However, if a system of interest contains important quantum effects, well-developed classical techniques cannot be used. One way of treating finite temperature quantum systems at equilibrium has been based on Feynman’s imaginary time path integral approach and the ensuing quantum-classical isomorphism. This isomorphism is exact only in the limit of infinitely many classical quasiparticles representing each physical quantum particle. In this work, we present a reductionist perspective on this problem based on the emerging methodology of coarse-graining. This perspective allows for the representations of one quantum particle with only two classical-like quasiparticles and their conjugate momenta. One of these coupled quasiparticles is the centroid particle of the quantum path integral quasiparticle distribution. Only this quasiparticle feels the potential energy function. The other quasiparticle directly provides the observable averages of quantum mechanical operators. The theory offers a simplified perspective on quantum statistical mechanics, revealing its most reductionist connection to classical statistical physics. By doing so, it can facilitate a simpler representation of certain quantum effects in complex molecular environments

  15. Mixing monoclonal antibody formulations using bottom-mounted mixers: impact of mechanism and design on drug product quality.

    Science.gov (United States)

    Gikanga, Benson; Chen, Yufei; Stauch, Oliver B; Maa, Yuh-Fun

    2015-01-01

    raised concerns about their impact on drug product quality and process performance. However, investigations into the effects of their use for biopharmaceutical products, particularly monoclonal antibody formulations, are rarely published. The purpose of this study is three-fold: (1) to understand the impact of bottom-mounted disposable mixer design on drug product quality and process performance, (2) to identify the mixing mechanism that is most gentle to protein particle formation, (3) to apply the learning to practical mixing operations using bottom-mounted mixers. The outcomes of this study will benefit scientists and engineers who develop biologic product manufacturing process by providing a better understanding of mixing principles and challenges. © PDA, Inc. 2015.

  16. An Explicit Formulation of Singularity-Free Dynamic Equations of Mechanical Systems in Lagrangian Form---Part Two: Multibody Systems

    Directory of Open Access Journals (Sweden)

    Pål Johan From

    2012-04-01

    Full Text Available This paper presents the explicit dynamic equations of multibody mechanical systems. This is the second paper on this topic. In the first paper the dynamics of a single rigid body from the Boltzmann--Hamel equations were derived. In this paper these results are extended to also include multibody systems. We show that when quasi-velocities are used, the part of the dynamic equations that appear from the partial derivatives of the system kinematics are identical to the single rigid body case, but in addition we get terms that come from the partial derivatives of the inertia matrix, which are not present in the single rigid body case. We present for the first time the complete and correct derivation of multibody systems based on the Boltzmann--Hamel formulation of the dynamics in Lagrangian form where local position and velocity variables are used in the derivation to obtain the singularity-free dynamic equations. The final equations are written in global variables for both position and velocity. The main motivation of these papers is to allow practitioners not familiar with differential geometry to implement the dynamic equations of rigid bodies without the presence of singularities. Presenting the explicit dynamic equations also allows for more insight into the dynamic structure of the system. Another motivation is to correct some errors commonly found in the literature. Unfortunately, the formulation of the Boltzmann-Hamel equations used here are presented incorrectly. This has been corrected by the authors, but we present here, for the first time, the detailed mathematical details on how to arrive at the correct equations. We also show through examples that using the equations presented here, the dynamics of a single rigid body is reduced to the standard equations on a Lagrangian form, for example Euler's equations for rotational motion and Euler--Lagrange equations for free motion.

  17. Physical, thermal and mechanical study of MPC formulated with LG-MgO incorporating Phase Change Materials as admixture

    Science.gov (United States)

    Maldonado-Alameda, A.; Lacasta, A. M.; Giro-Paloma, J.; Chimenos, J. M.; Formosa, J.

    2017-10-01

    The high environmental impact generated by using of Ordinary Portland Cement (OPC) has lead to the search for alternative materials in the field of civil and building engineering. In addition, there is a tendency to develop cements from industrial by-products, thus reducing pollution and emissions generated by their production. One of the best positioned cements to compete with OPC is Magnesium Phosphate Cement (MPC). The present work studies different dosages of MPC mortars formulated with low-grade MgO by-product (sustainable MPC) incorporating Microencapsulated Phase Change Materials (MPCM) and air entraining additive (AEA) as admixtures (Thermal Sustainable MPC) to improve the thermal behaviour of the material. The aim is developed a new eco-friendly material that leads to reducing energy consumption in buildings. The study is focused on the physical, thermal, and mechanical characterization of TS-MPC mortars to assess their potential use as a thermal prefabricated panel. The results allow to relate the amount of the MPCM and the additive percentage with the thermal and mechanical properties of the TS- MPC. Furthermore, is important to highlight the influence of MPCM not only in the thermal behaviour but also on the increase of the porosity. The experimental results show that the addition of both additives contributes substantially to the improvement of the thermal behaviour of the mortars and converts them on a suitable material to reduce thermal oscillations in buildings.

  18. Statistical learning and probabilistic prediction in music cognition: mechanisms of stylistic enculturation.

    Science.gov (United States)

    Pearce, Marcus T

    2018-05-11

    Music perception depends on internal psychological models derived through exposure to a musical culture. It is hypothesized that this musical enculturation depends on two cognitive processes: (1) statistical learning, in which listeners acquire internal cognitive models of statistical regularities present in the music to which they are exposed; and (2) probabilistic prediction based on these learned models that enables listeners to organize and process their mental representations of music. To corroborate these hypotheses, I review research that uses a computational model of probabilistic prediction based on statistical learning (the information dynamics of music (IDyOM) model) to simulate data from empirical studies of human listeners. The results show that a broad range of psychological processes involved in music perception-expectation, emotion, memory, similarity, segmentation, and meter-can be understood in terms of a single, underlying process of probabilistic prediction using learned statistical models. Furthermore, IDyOM simulations of listeners from different musical cultures demonstrate that statistical learning can plausibly predict causal effects of differential cultural exposure to musical styles, providing a quantitative model of cultural distance. Understanding the neural basis of musical enculturation will benefit from close coordination between empirical neuroimaging and computational modeling of underlying mechanisms, as outlined here. © 2018 The Authors. Annals of the New York Academy of Sciences published by Wiley Periodicals, Inc. on behalf of New York Academy of Sciences.

  19. Multiscale representation of generating and correlation functions for some models of statistical mechanics and quantum field theory

    International Nuclear Information System (INIS)

    O'Carroll, M.

    1993-01-01

    The author considers models of statistical mechanics and quantum field theory (in the Euclidean formulation) which are treated using renormalization group methods and where the action is a small perturbation of a quadratic action. The author obtains multiscale formulas for the generating and correlation functions after n renormalization group transformations which bring out the relation with the nth effective action. The author derives and compares the formulas for different RGs. The formulas for correlation functions involve (1) two propagators which are determined by a sequence of approximate wave function renormalization constants and renormalization group operators associated with the decomposition into scales of the quadratic form and (2) field derivatives of the nth effective action. For the case of the block field open-quotes δ-functionclose quotes RG the formulas are especially simple and for asymptotic free theories only the derivatives at zero field are needed; the formulas have been previously used directly to obtain bounds on correlation functions using information obtained from the analysis of effective actions. The simplicity can be traced to an open-quotes orthogonality-of-scalesclose quotes property which follows from an implicit wavelet structure. Other commonly used RGs do not have the open-quotes orthogonality of scalesclose quotes property. 19 refs

  20. Introduction to the Lie-admissible treatment of non-potential interactions in Newtonian, statistical, and particle mechanics

    International Nuclear Information System (INIS)

    Santilli, R.M.

    1982-01-01

    Views on the experimental origin, theoretical formulation, and mathematical structure of nonpotential interactions in Newtonian, statistical, and particle mechanics are presented. The simplest but most dominant consideration of this introduction is the expectation that the charge distribution of hadrons is not perfectly rigid, but admits deformations under suitable impacts with other hadrons. These rather natural deformations then imply: (1) the breaking of the SU(2)-spin symmetry for the interior strong problem, with the understanding that conventional, conserved, total spin quantities are recovered in the exterior treatment; (2) the consequential necessary breaking of the T- and P-symmetries, also for the interior strong problem, owing to the explicit dependence of the discrete operators on spin, with the understanding that the center-of-mass trajectories of closed strong systems recover the T- and P-symmetries; and (3) the origin of irreversibility at the most elemental level of nature, via the nonpotential interactions originating from mutual penetrations and overlappings of hadrons under strong interactions

  1. Artificial intelligence in pharmaceutical product formulation: neural computing

    OpenAIRE

    Svetlana Ibrić; Jelena Petrović; Jelena Parojčić; Zorica Djurić

    2009-01-01

    The properties of a formulation are determined not only by the ratios in which the ingredients are combined but also by the processing conditions. Although the relationships between the ingredient levels, processing conditions, and product performance may be known anecdotally, they can rarely be quantified. In the past, formulators tended to use statistical techniques to model their formulations, relying on response surfaces to provide a mechanism for optimazation. However, the optimization b...

  2. Formulation optimization of transdermal meloxicam potassium-loaded mesomorphic phases containing ethanol, oleic acid and mixture surfactant using the statistical experimental design methodology.

    Science.gov (United States)

    Huang, Chi-Te; Tsai, Chia-Hsun; Tsou, Hsin-Yeh; Huang, Yaw-Bin; Tsai, Yi-Hung; Wu, Pao-Chu

    2011-01-01

    Response surface methodology (RSM) was used to develop and optimize the mesomorphic phase formulation for a meloxicam transdermal dosage form. A mixture design was applied to prepare formulations which consisted of three independent variables including oleic acid (X(1)), distilled water (X(2)) and ethanol (X(3)). The flux and lag time (LT) were selected as dependent variables. The result showed that using mesomorphic phases as vehicles can significantly increase flux and shorten LT of drug. The analysis of variance showed that the permeation parameters of meloxicam from formulations were significantly influenced by the independent variables and their interactions. The X(3) (ethanol) had the greatest potential influence on the flux and LT, followed by X(1) and X(2). A new formulation was prepared according to the independent levels provided by RSM. The observed responses were in close agreement with the predicted values, demonstrating that RSM could be successfully used to optimize mesomorphic phase formulations.

  3. Bayesian Statistical Mechanics: Entropy-Enthalpy Compensation and Universal Equation of State at the Tip of Pen

    Directory of Open Access Journals (Sweden)

    Evgeni B. Starikov

    2018-02-01

    Full Text Available This work has shown the way to put the formal statistical-mechanical basement under the hotly debated notion of enthalpy-entropy compensation. The possibility of writing down the universal equation of state based upon the statistical mechanics is discussed here.

  4. Solvability of a class of systems of infinite-dimensional integral equations and their application in statistical mechanics

    International Nuclear Information System (INIS)

    Gonchar, N.S.

    1986-01-01

    This paper presents a mathematical method developed for investigating a class of systems of infinite-dimensional integral equations which have application in statistical mechanics. Necessary and sufficient conditions are obtained for the uniqueness and bifurcation of the solution of this class of systems of equations. Problems of equilibrium statistical mechanics are considered on the basis of this method

  5. A statistical mechanics model for free-for-all airplane passenger boarding

    Energy Technology Data Exchange (ETDEWEB)

    Steffen, Jason H.; /Fermilab

    2008-08-01

    I discuss a model for free-for-all passenger boarding which is employed by some discount air carriers. The model is based on the principles of statistical mechanics where each seat in the aircraft has an associated energy which reflects the preferences of travelers. As each passenger enters the airplane they select their seats using Boltzmann statistics, proceed to that location, load their luggage, sit down, and the partition function seen by remaining passengers is modified to reflect this fact. I discuss the various model parameters and make qualitative comparisons of this passenger boarding model with those that involve assigned seats. The model can be used to predict the probability that certain seats will be occupied at different times during the boarding process. These results might provide a useful description of this boarding method. The model is a relatively unusual application of undergraduate level physics and describes a situation familiar to many students and faculty.

  6. A statistical mechanics model for free-for-all airplane passenger boarding

    Science.gov (United States)

    Steffen, Jason H.

    2008-12-01

    I discuss a model for free-for-all passenger boarding which is employed by some discount air carriers. The model is based on the principles of statistical mechanics, where each seat in the aircraft has an associated energy which reflects the preferences of travelers. As each passenger enters the airplane they select their seats using Boltzmann statistics, proceed to that location, load their luggage, sit down, and the partition function seen by remaining passengers is modified to reflect this fact. I discuss the various model parameters and make qualitative comparisons of this passenger boarding model with those that involve assigned seats. The model can be used to predict the probability that certain seats will be occupied at different times during the boarding process. These results might provide a useful description of this boarding method. The model is a relatively unusual application of undergraduate level physics and describes a situation familiar to many students and faculty.

  7. Statistical mechanics of gravitons in a box and the black hole entropy

    Science.gov (United States)

    Viaggiu, Stefano

    2017-05-01

    This paper is devoted to the study of the statistical mechanics of trapped gravitons obtained by 'trapping' a spherical gravitational wave in a box. As a consequence, a discrete spectrum dependent on the Legendre index ℓ similar to the harmonic oscillator one is obtained and a statistical study is performed. The mean energy 〈 E 〉 results as a sum of two discrete Planck distributions with different dependent frequencies. As an important application, we derive the semiclassical Bekenstein-Hawking entropy formula for a static Schwarzschild black hole by only requiring that the black hole internal energy U is provided by its ADM rest energy, without invoking particular quantum gravity theories. This seriously suggests that the interior of a black hole can be composed of trapped gravitons at a thermodynamical temperature proportional by a factor ≃ 2 to the horizon temperature Th.

  8. A statistical mechanics model for free-for-all airplane passenger boarding

    International Nuclear Information System (INIS)

    Steffen, Jason H.; Fermilab

    2008-01-01

    I discuss a model for free-for-all passenger boarding which is employed by some discount air carriers. The model is based on the principles of statistical mechanics where each seat in the aircraft has an associated energy which reflects the preferences of travelers. As each passenger enters the airplane they select their seats using Boltzmann statistics, proceed to that location, load their luggage, sit down, and the partition function seen by remaining passengers is modified to reflect this fact. I discuss the various model parameters and make qualitative comparisons of this passenger boarding model with those that involve assigned seats. The model can be used to predict the probability that certain seats will be occupied at different times during the boarding process. These results might provide a useful description of this boarding method. The model is a relatively unusual application of undergraduate level physics and describes a situation familiar to many students and faculty

  9. Multi-agent Negotiation Mechanisms for Statistical Target Classification in Wireless Multimedia Sensor Networks

    Directory of Open Access Journals (Sweden)

    Sheng Wang

    2007-10-01

    Full Text Available The recent availability of low cost and miniaturized hardware has allowedwireless sensor networks (WSNs to retrieve audio and video data in real worldapplications, which has fostered the development of wireless multimedia sensor networks(WMSNs. Resource constraints and challenging multimedia data volume makedevelopment of efficient algorithms to perform in-network processing of multimediacontents imperative. This paper proposes solving problems in the domain of WMSNs fromthe perspective of multi-agent systems. The multi-agent framework enables flexible networkconfiguration and efficient collaborative in-network processing. The focus is placed ontarget classification in WMSNs where audio information is retrieved by microphones. Todeal with the uncertainties related to audio information retrieval, the statistical approachesof power spectral density estimates, principal component analysis and Gaussian processclassification are employed. A multi-agent negotiation mechanism is specially developed toefficiently utilize limited resources and simultaneously enhance classification accuracy andreliability. The negotiation is composed of two phases, where an auction based approach isfirst exploited to allocate the classification task among the agents and then individual agentdecisions are combined by the committee decision mechanism. Simulation experiments withreal world data are conducted and the results show that the proposed statistical approachesand negotiation mechanism not only reduce memory and computation requi

  10. Implementation of Statistical Process Control: Evaluating the Mechanical Performance of a Candidate Silicone Elastomer Docking Seal

    Science.gov (United States)

    Oravec, Heather Ann; Daniels, Christopher C.

    2014-01-01

    The National Aeronautics and Space Administration has been developing a novel docking system to meet the requirements of future exploration missions to low-Earth orbit and beyond. A dynamic gas pressure seal is located at the main interface between the active and passive mating components of the new docking system. This seal is designed to operate in the harsh space environment, but is also to perform within strict loading requirements while maintaining an acceptable level of leak rate. In this study, a candidate silicone elastomer seal was designed, and multiple subscale test articles were manufactured for evaluation purposes. The force required to fully compress each test article at room temperature was quantified and found to be below the maximum allowable load for the docking system. However, a significant amount of scatter was observed in the test results. Due to the stochastic nature of the mechanical performance of this candidate docking seal, a statistical process control technique was implemented to isolate unusual compression behavior from typical mechanical performance. The results of this statistical analysis indicated a lack of process control, suggesting a variation in the manufacturing phase of the process. Further investigation revealed that changes in the manufacturing molding process had occurred which may have influenced the mechanical performance of the seal. This knowledge improves the chance of this and future space seals to satisfy or exceed design specifications.

  11. Multi-agent Negotiation Mechanisms for Statistical Target Classification in Wireless Multimedia Sensor Networks

    Science.gov (United States)

    Wang, Xue; Bi, Dao-wei; Ding, Liang; Wang, Sheng

    2007-01-01

    The recent availability of low cost and miniaturized hardware has allowed wireless sensor networks (WSNs) to retrieve audio and video data in real world applications, which has fostered the development of wireless multimedia sensor networks (WMSNs). Resource constraints and challenging multimedia data volume make development of efficient algorithms to perform in-network processing of multimedia contents imperative. This paper proposes solving problems in the domain of WMSNs from the perspective of multi-agent systems. The multi-agent framework enables flexible network configuration and efficient collaborative in-network processing. The focus is placed on target classification in WMSNs where audio information is retrieved by microphones. To deal with the uncertainties related to audio information retrieval, the statistical approaches of power spectral density estimates, principal component analysis and Gaussian process classification are employed. A multi-agent negotiation mechanism is specially developed to efficiently utilize limited resources and simultaneously enhance classification accuracy and reliability. The negotiation is composed of two phases, where an auction based approach is first exploited to allocate the classification task among the agents and then individual agent decisions are combined by the committee decision mechanism. Simulation experiments with real world data are conducted and the results show that the proposed statistical approaches and negotiation mechanism not only reduce memory and computation requirements in WMSNs but also significantly enhance classification accuracy and reliability. PMID:28903223

  12. Statistical analysis of the factors that influenced the mechanical properties improvement of cassava starch films

    Science.gov (United States)

    Monteiro, Mayra; Oliveira, Victor; Santos, Francisco; Barros Neto, Eduardo; Silva, Karyn; Silva, Rayane; Henrique, João; Chibério, Abimaelle

    2017-08-01

    In order to obtain cassava starch films with improved mechanical properties in relation to the synthetic polymer in the packaging production, a complete factorial design 23 was carried out in order to investigate which factor significantly influences the tensile strength of the biofilm. The factors to be investigated were cassava starch, glycerol and modified clay contents. Modified bentonite clay was used as a filling material of the biofilm. Glycerol was the plasticizer used to thermoplastify cassava starch. The factorial analysis suggested a regression model capable of predicting the optimal mechanical property of the cassava starch film from the maximization of the tensile strength. The reliability of the regression model was tested by the correlation established with the experimental data through the following statistical analyse: Pareto graph. The modified clay was the factor of greater statistical significance on the observed response variable, being the factor that contributed most to the improvement of the mechanical property of the starch film. The factorial experiments showed that the interaction of glycerol with both modified clay and cassava starch was significant for the reduction of biofilm ductility. Modified clay and cassava starch contributed to the maximization of biofilm ductility, while glycerol contributed to the minimization.

  13. Statistical mechanics of neocortical interactions: A scaling paradigm applied to electroencephalography

    Science.gov (United States)

    Ingber, Lester

    1991-09-01

    A series of papers has developed a statistical mechanics of neocortical interactions (SMNI), deriving aggregate behavior of experimentally observed columns of neurons from statistical electrical-chemical properties of synaptic interactions. While not useful to yield insights at the single-neuron level, SMNI has demonstrated its capability in describing large-scale properties of short-term memory and electroencephalographic (EEG) systematics. The necessity of including nonlinear and stochastic structures in this development has been stressed. In this paper, a more stringent test is placed on SMNI: The algebraic and numerical algorithms previously developed in this and similar systems are brought to bear to fit large sets of EEG and evoked-potential data being collected to investigate genetic predispositions to alcoholism and to extract brain ``signatures'' of short-term memory. Using the numerical algorithm of very fast simulated reannealing, it is demonstrated that SMNI can indeed fit these data within experimentally observed ranges of its underlying neuronal-synaptic parameters, and the quantitative modeling results are used to examine physical neocortical mechanisms to discriminate high-risk and low-risk populations genetically predisposed to alcoholism. Since this study is a control to span relatively long time epochs, similar to earlier attempts to establish such correlations, this discrimination is inconclusive because of other neuronal activity which can mask such effects. However, the SMNI model is shown to be consistent with EEG data during selective attention tasks and with neocortical mechanisms describing short-term memory previously published using this approach. This paper explicitly identifies similar nonlinear stochastic mechanisms of interaction at the microscopic-neuronal, mesoscopic-columnar, and macroscopic-regional scales of neocortical interactions. These results give strong quantitative support for an accurate intuitive picture, portraying

  14. Exploring the Connection Between Sampling Problems in Bayesian Inference and Statistical Mechanics

    Science.gov (United States)

    Pohorille, Andrew

    2006-01-01

    The Bayesian and statistical mechanical communities often share the same objective in their work - estimating and integrating probability distribution functions (pdfs) describing stochastic systems, models or processes. Frequently, these pdfs are complex functions of random variables exhibiting multiple, well separated local minima. Conventional strategies for sampling such pdfs are inefficient, sometimes leading to an apparent non-ergodic behavior. Several recently developed techniques for handling this problem have been successfully applied in statistical mechanics. In the multicanonical and Wang-Landau Monte Carlo (MC) methods, the correct pdfs are recovered from uniform sampling of the parameter space by iteratively establishing proper weighting factors connecting these distributions. Trivial generalizations allow for sampling from any chosen pdf. The closely related transition matrix method relies on estimating transition probabilities between different states. All these methods proved to generate estimates of pdfs with high statistical accuracy. In another MC technique, parallel tempering, several random walks, each corresponding to a different value of a parameter (e.g. "temperature"), are generated and occasionally exchanged using the Metropolis criterion. This method can be considered as a statistically correct version of simulated annealing. An alternative approach is to represent the set of independent variables as a Hamiltonian system. Considerab!e progress has been made in understanding how to ensure that the system obeys the equipartition theorem or, equivalently, that coupling between the variables is correctly described. Then a host of techniques developed for dynamical systems can be used. Among them, probably the most powerful is the Adaptive Biasing Force method, in which thermodynamic integration and biased sampling are combined to yield very efficient estimates of pdfs. The third class of methods deals with transitions between states described

  15. Portfolio selection problem with liquidity constraints under non-extensive statistical mechanics

    International Nuclear Information System (INIS)

    Zhao, Pan; Xiao, Qingxian

    2016-01-01

    In this study, we consider the optimal portfolio selection problem with liquidity limits. A portfolio selection model is proposed in which the risky asset price is driven by the process based on non-extensive statistical mechanics instead of the classic Wiener process. Using dynamic programming and Lagrange multiplier methods, we obtain the optimal policy and value function. Moreover, the numerical results indicate that this model is considerably different from the model based on the classic Wiener process, the optimal strategy is affected by the non-extensive parameter q, the increase in the investment in the risky asset is faster at a larger parameter q and the increase in wealth is similar.

  16. Portfolio optimization problem with nonidentical variances of asset returns using statistical mechanical informatics

    Science.gov (United States)

    Shinzato, Takashi

    2016-12-01

    The portfolio optimization problem in which the variances of the return rates of assets are not identical is analyzed in this paper using the methodology of statistical mechanical informatics, specifically, replica analysis. We defined two characteristic quantities of an optimal portfolio, namely, minimal investment risk and investment concentration, in order to solve the portfolio optimization problem and analytically determined their asymptotical behaviors using replica analysis. Numerical experiments were also performed, and a comparison between the results of our simulation and those obtained via replica analysis validated our proposed method.

  17. PREFACE: International Workshop on Statistical-Mechanical Informatics 2008 (IW-SMI 2008)

    Science.gov (United States)

    Hayashi, Masahito; Inoue, Jun-ichi; Kabashima, Yoshiyuki; Tanaka, Kazuyuki

    2009-01-01

    Statistical mechanical informatics (SMI) is an approach that applies physics to information science, in which many-body problems in information processing are tackled using statistical mechanics methods. In the last decade, the use of SMI has resulted in great advances in research into classical information processing, in particular, theories of information and communications, probabilistic inference and combinatorial optimization problems. It is expected that the success of SMI can be extended to quantum systems. The importance of many-body problems is also being recognized in quantum information theory (QIT), for which quantification of entanglement of bipartite systems has recently been almost completely established after considerable effort. SMI and QIT are sufficiently well developed that it is now appropriate to consider applying SMI to quantum systems and developing many-body theory in QIT. This combination of SMI and QIT is highly likely to contribute significantly to the development of both research fields. The International Workshop on Statistical-Mechanical Informatics has been organized in response to this situation. This workshop, held at Sendai International Conference Center, Sendai, Japan, 14-17 September 2008, and sponsored by the Grant-in-Aid for Scientific Research on Priority Areas `Deepening and Expansion of Statistical Mechanical Informatics (DEX-SMI)' (Head investigator: Yoshiyuki Kabashima, Tokyo Institute of Technology) (Project http://dex-smi.sp.dis.titech.ac.jp/DEX-SMI), was intended to provide leading researchers with strong interdisciplinary interests in QIT and SMI with the opportunity to engage in intensive discussions. The aim of the workshop was to expand SMI to quantum systems and QIT research on quantum (entangled) many-body systems, to discuss possible future directions, and to offer researchers the opportunity to exchange ideas that may lead to joint research initiatives. We would like to thank the contributors of the workshop

  18. Statistical mechanics of Fermi-Pasta-Ulam chains with the canonical ensemble

    Science.gov (United States)

    Demirel, Melik C.; Sayar, Mehmet; Atılgan, Ali R.

    1997-03-01

    Low-energy vibrations of a Fermi-Pasta-Ulam-Β (FPU-Β) chain with 16 repeat units are analyzed with the aid of numerical experiments and the statistical mechanics equations of the canonical ensemble. Constant temperature numerical integrations are performed by employing the cubic coupling scheme of Kusnezov et al. [Ann. Phys. 204, 155 (1990)]. Very good agreement is obtained between numerical results and theoretical predictions for the probability distributions of the generalized coordinates and momenta both of the chain and of the thermal bath. It is also shown that the average energy of the chain scales linearly with the bath temperature.

  19. Statistical mechanics of a one-component fluid of charged hard rods in 1D

    International Nuclear Information System (INIS)

    Vericat, F.; Blum, L.

    1986-09-01

    The statistical mechanics of a classical one component system of charged hard rods in a neutralizing background is investigated in 1D stressing on the effects of the hard core interactions over the thermodynamic and the structure of the system. The crystalline status of the system at all temperatures and densities and the absence of phase transitions is shown by extending previous results of Baxter and Kunz on the one-component plasma of point particles. Explicit expressions for the thermodynamic functions and the one-particle correlation function are given in the limits of small and strong couplings. (author)

  20. Reason of method of density functional in classical and quantum statistical mechanisms

    International Nuclear Information System (INIS)

    Dinariev, O.Yu.

    2000-01-01

    Interaction between phenomenological description of a multi-component mixture on the basis of entropy functional with members, square in terms of component density gradients and temperature, on the one hand, and description in the framework of classical and quantum statistical mechanics, on the other hand, was investigated. Explicit expressions for the entropy functional in the classical and quantum theory were derived. Then a square approximation for the case of minor disturbances of uniform state was calculated. In the approximation the addends square in reference to the gradient were singlet out. It permits calculation of the relevant phenomenological coefficients from the leading principles [ru

  1. Statistical mechanics of neocortical interactions. Derivation of short-term-memory capacity

    Science.gov (United States)

    Ingber, Lester

    1984-06-01

    A theory developed by the author to describe macroscopic neocortical interactions demonstrates that empirical values of chemical and electrical parameters of synaptic interactions establish several minima of the path-integral Lagrangian as a function of excitatory and inhibitory columnar firings. The number of possible minima, their time scales of hysteresis and probable reverberations, and their nearest-neighbor columnar interactions are all consistent with well-established empirical rules of human short-term memory. Thus, aspects of conscious experience are derived from neuronal firing patterns, using modern methods of nonlinear nonequilibrium statistical mechanics to develop realistic explicit synaptic interactions.

  2. Existence and uniqueness of Gibbs states for a statistical mechanical polyacetylene model

    International Nuclear Information System (INIS)

    Park, Y.M.

    1987-01-01

    One-dimensional polyacetylene is studied as a model of statistical mechanics. In a semiclassical approximation the system is equivalent to a quantum XY model interacting with unbounded classical spins in one-dimensional lattice space Z. By establishing uniform estimates, an infinite-volume-limit Hilbert space, a strongly continuous time evolution group of unitary operators, and an invariant vector are constructed. Moreover, it is proven that any infinite-limit state satisfies Gibbs conditions. Finally, a modification of Araki's relative entropy method is used to establish the uniqueness of Gibbs states

  3. Non-extensive statistical mechanics and black hole entropy from quantum geometry

    Directory of Open Access Journals (Sweden)

    Abhishek Majhi

    2017-12-01

    Full Text Available Using non-extensive statistical mechanics, the Bekenstein–Hawking area law is obtained from microstates of black holes in loop quantum gravity, for arbitrary real positive values of the Barbero–Immirzi parameter (γ. The arbitrariness of γ is encoded in the strength of the “bias” created in the horizon microstates through the coupling with the quantum geometric fields exterior to the horizon. An experimental determination of γ will fix this coupling, leaving out the macroscopic area of the black hole to be the only free quantity of the theory.

  4. The nano-mechanical signature of Ultra High Performance Concrete by statistical nanoindentation techniques

    International Nuclear Information System (INIS)

    Sorelli, Luca; Constantinides, Georgios; Ulm, Franz-Josef; Toutlemonde, Francois

    2008-01-01

    Advances in engineering the microstructure of cementitious composites have led to the development of fiber reinforced Ultra High Performance Concretes (UHPC). The scope of this paper is twofold, first to characterize the nano-mechanical properties of the phases governing the UHPC microstructure by means of a novel statistical nanoindentation technique; then to upscale those nanoscale properties, by means of continuum micromechanics, to the macroscopic scale of engineering applications. In particular, a combined investigation of nanoindentation, scanning electron microscope (SEM) and X-ray Diffraction (XRD) indicates that the fiber-matrix transition zone is relatively defect free. On this basis, a four-level multiscale model with defect free interfaces allows to accurately determine the composite stiffness from the measured nano-mechanical properties. Besides evidencing the dominant role of high density calcium silicate hydrates and the stiffening effect of residual clinker, the suggested model may become a useful tool for further optimizing cement-based engineered composites

  5. Influence of dioctyl phthalate (DOP) on the mechanical, optical and thermal properties of formulations for the industrial manufacture of radiation sterilizable medical disposables

    International Nuclear Information System (INIS)

    Ahmed, Shamshad; Mehmood, Mazhar; Iqbal, Rashid

    2010-01-01

    Shelf life of the formulations designed for the industrial manufacture of radiation sterilizable syringes and other medical disposables is a very important issue world over. Radiation compatible formulations were developed earlier in the laboratory by the incorporation of primary and secondary antioxidants along with processing stabilizers in a random polypropylene copolymer. It has been reported in literature that the mobilizing agents namely hydrocarbons, greases, wax and the plasticizer, dioctyl phthalate (DOP) impart radiation resistance to the polypropylene by providing free volume. It was envisaged that the addition of DOP to the afore-mentioned formulation might favorably influence the mechanical, optical and thermal properties of our formulation. To study the influence of addition of DOP on the afore-mentioned properties, the addition of 1%, 2% and 3% of the mobilizer was made, followed by the irradiation of resulting heat pressed sheets to the industrial standard dose of 25 kGy. Two important characteristic mechanical properties to determine the suitability of the radiation sterilized materials comprise angle of breakage and the haze percent. After irradiation and even on accelerated ageing of the irradiated material, the angle of breakage of heat press sheets of formulations containing 1%, 2% and 3% of DOP was found to be 180 deg, demonstrating the role of DOP, in imparting additional radiation stability. In case of the irradiated control sample, the angle of breakage was much lower. In the heat pressed sheets containing the DOP, a remarkable retention in the tensile strength, percentage elongation at break, along with improved thermal stability was observed. The formulation devoid of DOP demonstrated poor retention of the afore-mentioned characteristic properties .The observed improvement in thermal stability of the formulations containing DOP hints at the likely possibility of reuse of these materials by autoclaving which is considered an additional

  6. Influence of dioctyl phthalate (DOP) on the mechanical, optical and thermal properties of formulations for the industrial manufacture of radiation sterilizable medical disposables

    Science.gov (United States)

    Ahmed, Shamshad; Mehmood, Mazhar; Iqbal, Rashid

    2010-03-01

    Shelf life of the formulations designed for the industrial manufacture of radiation sterilizable syringes and other medical disposables is a very important issue world over. Radiation compatible formulations were developed earlier in the laboratory by the incorporation of primary and secondary antioxidants along with processing stabilizers in a random polypropylene copolymer. It has been reported in literature that the mobilizing agents namely hydrocarbons, greases, wax and the plasticizer, dioctyl phthalate (DOP) impart radiation resistance to the polypropylene by providing free volume. It was envisaged that the addition of DOP to the afore-mentioned formulation might favorably influence the mechanical, optical and thermal properties of our formulation. To study the influence of addition of DOP on the afore-mentioned properties, the addition of 1%, 2% and 3% of the mobilizer was made, followed by the irradiation of resulting heat pressed sheets to the industrial standard dose of 25 kGy. Two important characteristic mechanical properties to determine the suitability of the radiation sterilized materials comprise angle of breakage and the haze percent. After irradiation and even on accelerated ageing of the irradiated material, the angle of breakage of heat press sheets of formulations containing 1%, 2% and 3% of DOP was found to be 180°, demonstrating the role of DOP, in imparting additional radiation stability. In case of the irradiated control sample, the angle of breakage was much lower. In the heat pressed sheets containing the DOP, a remarkable retention in the tensile strength, percentage elongation at break, along with improved thermal stability was observed. The formulation devoid of DOP demonstrated poor retention of the afore-mentioned characteristic properties .The observed improvement in thermal stability of the formulations containing DOP hints at the likely possibility of reuse of these materials by autoclaving which is considered an additional

  7. Statistical evaluation of low cycle loading curves parameters for structural materials by mechanical characteristics

    International Nuclear Information System (INIS)

    Daunys, Mykolas; Sniuolis, Raimondas

    2006-01-01

    About 300 welded joint materials that are used in nuclear power energy were tested under monotonous tension and low cycle loading in Kaunas University of Technology together with St. Peterburg Central Research Institute of Structural Materials in 1970-2000. The main mechanical, low cycle loading and fracture characteristics of base metals, weld metals and some heat-affected zones of welded joints metals were determined during these experiments. Analytical dependences of low cycle fatigue parameters on mechanical characteristics of structural materials were proposed on the basis of a large number of experimental data, obtained by the same methods and testing equipment. When these dependences are used, expensive low cycle fatigue tests may be omitted and it is possible to compute low cycle loading curves parameters and lifetime for structural materials according to the main mechanical characteristics given in technical manuals. Dependences of low cycle loading curves parameters on mechanical characteristics for several groups of structural materials used in Russian nuclear power energy are obtained by statistical methods and proposed in this paper

  8. Statistical mechanics of binary mixture adsorption in metal-organic frameworks in the osmotic ensemble

    Science.gov (United States)

    Dunne, Lawrence J.; Manos, George

    2018-03-01

    Although crucial for designing separation processes little is known experimentally about multi-component adsorption isotherms in comparison with pure single components. Very few binary mixture adsorption isotherms are to be found in the literature and information about isotherms over a wide range of gas-phase composition and mechanical pressures and temperature is lacking. Here, we present a quasi-one-dimensional statistical mechanical model of binary mixture adsorption in metal-organic frameworks (MOFs) treated exactly by a transfer matrix method in the osmotic ensemble. The experimental parameter space may be very complex and investigations into multi-component mixture adsorption may be guided by theoretical insights. The approach successfully models breathing structural transitions induced by adsorption giving a good account of the shape of adsorption isotherms of CO2 and CH4 adsorption in MIL-53(Al). Binary mixture isotherms and co-adsorption-phase diagrams are also calculated and found to give a good description of the experimental trends in these properties and because of the wide model parameter range which reproduces this behaviour suggests that this is generic to MOFs. Finally, a study is made of the influence of mechanical pressure on the shape of CO2 and CH4 adsorption isotherms in MIL-53(Al). Quite modest mechanical pressures can induce significant changes to isotherm shapes in MOFs with implications for binary mixture separation processes. This article is part of the theme issue `Modern theoretical chemistry'.

  9. A statistical model of uplink inter-cell interference with slow and fast power control mechanisms

    KAUST Repository

    Tabassum, Hina

    2013-09-01

    Uplink power control is in essence an interference mitigation technique that aims at minimizing the inter-cell interference (ICI) in cellular networks by reducing the transmit power levels of the mobile users while maintaining their target received signal quality levels at base stations. Power control mechanisms directly impact the interference dynamics and, thus, affect the overall achievable capacity and consumed power in cellular networks. Due to the stochastic nature of wireless channels and mobile users\\' locations, it is important to derive theoretical models for ICI that can capture the impact of design alternatives related to power control mechanisms. To this end, we derive and verify a novel statistical model for uplink ICI in Generalized-K composite fading environments as a function of various slow and fast power control mechanisms. The derived expressions are then utilized to quantify numerically key network performance metrics that include average resource fairness, average reduction in power consumption, and ergodic capacity. The accuracy of the derived expressions is validated via Monte-Carlo simulations. Results are generated for multiple network scenarios, and insights are extracted to assess various power control mechanisms as a function of system parameters. © 1972-2012 IEEE.

  10. Neocortical dynamics at multiple scales: EEG standing waves, statistical mechanics, and physical analogs.

    Science.gov (United States)

    Ingber, Lester; Nunez, Paul L

    2011-02-01

    The dynamic behavior of scalp potentials (EEG) is apparently due to some combination of global and local processes with important top-down and bottom-up interactions across spatial scales. In treating global mechanisms, we stress the importance of myelinated axon propagation delays and periodic boundary conditions in the cortical-white matter system, which is topologically close to a spherical shell. By contrast, the proposed local mechanisms are multiscale interactions between cortical columns via short-ranged non-myelinated fibers. A mechanical model consisting of a stretched string with attached nonlinear springs demonstrates the general idea. The string produces standing waves analogous to large-scale coherent EEG observed in some brain states. The attached springs are analogous to the smaller (mesoscopic) scale columnar dynamics. Generally, we expect string displacement and EEG at all scales to result from both global and local phenomena. A statistical mechanics of neocortical interactions (SMNI) calculates oscillatory behavior consistent with typical EEG, within columns, between neighboring columns via short-ranged non-myelinated fibers, across cortical regions via myelinated fibers, and also derives a string equation consistent with the global EEG model. Copyright © 2010 Elsevier Inc. All rights reserved.

  11. A statistical model of uplink inter-cell interference with slow and fast power control mechanisms

    KAUST Repository

    Tabassum, Hina; Yilmaz, Ferkan; Dawy, Zaher; Alouini, Mohamed-Slim

    2013-01-01

    Uplink power control is in essence an interference mitigation technique that aims at minimizing the inter-cell interference (ICI) in cellular networks by reducing the transmit power levels of the mobile users while maintaining their target received signal quality levels at base stations. Power control mechanisms directly impact the interference dynamics and, thus, affect the overall achievable capacity and consumed power in cellular networks. Due to the stochastic nature of wireless channels and mobile users' locations, it is important to derive theoretical models for ICI that can capture the impact of design alternatives related to power control mechanisms. To this end, we derive and verify a novel statistical model for uplink ICI in Generalized-K composite fading environments as a function of various slow and fast power control mechanisms. The derived expressions are then utilized to quantify numerically key network performance metrics that include average resource fairness, average reduction in power consumption, and ergodic capacity. The accuracy of the derived expressions is validated via Monte-Carlo simulations. Results are generated for multiple network scenarios, and insights are extracted to assess various power control mechanisms as a function of system parameters. © 1972-2012 IEEE.

  12. Brownian motion or Lévy walk? Stepping towards an extended statistical mechanics for animal locomotion.

    Science.gov (United States)

    Gautestad, Arild O

    2012-09-07

    Animals moving under the influence of spatio-temporal scaling and long-term memory generate a kind of space-use pattern that has proved difficult to model within a coherent theoretical framework. An extended kind of statistical mechanics is needed, accounting for both the effects of spatial memory and scale-free space use, and put into a context of ecological conditions. Simulations illustrating the distinction between scale-specific and scale-free locomotion are presented. The results show how observational scale (time lag between relocations of an individual) may critically influence the interpretation of the underlying process. In this respect, a novel protocol is proposed as a method to distinguish between some main movement classes. For example, the 'power law in disguise' paradox-from a composite Brownian motion consisting of a superposition of independent movement processes at different scales-may be resolved by shifting the focus from pattern analysis at one particular temporal resolution towards a more process-oriented approach involving several scales of observation. A more explicit consideration of system complexity within a statistical mechanical framework, supplementing the more traditional mechanistic modelling approach, is advocated.

  13. A Note on Burg’s Modified Entropy in Statistical Mechanics

    Directory of Open Access Journals (Sweden)

    Amritansu Ray

    2016-02-01

    Full Text Available Burg’s entropy plays an important role in this age of information euphoria, particularly in understanding the emergent behavior of a complex system such as statistical mechanics. For discrete or continuous variable, maximization of Burg’s Entropy subject to its only natural and mean constraint always provide us a positive density function though the Entropy is always negative. On the other hand, Burg’s modified entropy is a better measure than the standard Burg’s entropy measure since this is always positive and there is no computational problem for small probabilistic values. Moreover, the maximum value of Burg’s modified entropy increases with the number of possible outcomes. In this paper, a premium has been put on the fact that if Burg’s modified entropy is used instead of conventional Burg’s entropy in a maximum entropy probability density (MEPD function, the result yields a better approximation of the probability distribution. An important lemma in basic algebra and a suitable example with tables and graphs in statistical mechanics have been given to illustrate the whole idea appropriately.

  14. Statistical mechanical analysis of linear programming relaxation for combinatorial optimization problems.

    Science.gov (United States)

    Takabe, Satoshi; Hukushima, Koji

    2016-05-01

    Typical behavior of the linear programming (LP) problem is studied as a relaxation of the minimum vertex cover (min-VC), a type of integer programming (IP) problem. A lattice-gas model on the Erdös-Rényi random graphs of α-uniform hyperedges is proposed to express both the LP and IP problems of the min-VC in the common statistical mechanical model with a one-parameter family. Statistical mechanical analyses reveal for α=2 that the LP optimal solution is typically equal to that given by the IP below the critical average degree c=e in the thermodynamic limit. The critical threshold for good accuracy of the relaxation extends the mathematical result c=1 and coincides with the replica symmetry-breaking threshold of the IP. The LP relaxation for the minimum hitting sets with α≥3, minimum vertex covers on α-uniform random graphs, is also studied. Analytic and numerical results strongly suggest that the LP relaxation fails to estimate optimal values above the critical average degree c=e/(α-1) where the replica symmetry is broken.

  15. Statistical mechanical analysis of linear programming relaxation for combinatorial optimization problems

    Science.gov (United States)

    Takabe, Satoshi; Hukushima, Koji

    2016-05-01

    Typical behavior of the linear programming (LP) problem is studied as a relaxation of the minimum vertex cover (min-VC), a type of integer programming (IP) problem. A lattice-gas model on the Erdös-Rényi random graphs of α -uniform hyperedges is proposed to express both the LP and IP problems of the min-VC in the common statistical mechanical model with a one-parameter family. Statistical mechanical analyses reveal for α =2 that the LP optimal solution is typically equal to that given by the IP below the critical average degree c =e in the thermodynamic limit. The critical threshold for good accuracy of the relaxation extends the mathematical result c =1 and coincides with the replica symmetry-breaking threshold of the IP. The LP relaxation for the minimum hitting sets with α ≥3 , minimum vertex covers on α -uniform random graphs, is also studied. Analytic and numerical results strongly suggest that the LP relaxation fails to estimate optimal values above the critical average degree c =e /(α -1 ) where the replica symmetry is broken.

  16. Statistical mechanics of relativistic spin-1 bosons in a magnetic field

    International Nuclear Information System (INIS)

    Daicic, J.; Frankel, N.E.

    1993-01-01

    This paper investigates the statistical mechanics of a gas of spin-1 particles with pair creation in a homogeneous magnetic field. It is shown that expansions for the thermodynamic potential and magnetization in fields below the mass scale of the constituent particles are well behaved. However, when the field is at or above the mass scale, an intrinsic pathology of the single-particle energy spectrum manifests itself in the statistical mechanics of the system. Whilst for the spin-0 and spin-1/2 analog of this system there seemed to be no barrier ab initio to the field strength, the nature of the vacuum, and the role of interactions, were always borne in mind as matters to be considered in a high-order treatment, particularly when the field was at or above the mass scale. In the spin-1 case, the pathology in the single-particle energy spectrum heralds this from the beginning, and seems to be a warning that a single particle non-interacting picture of physics at high energies needs some reconsideration. 10 refs

  17. The non-equilibrium statistical mechanics of a simple geophysical fluid dynamics model

    Science.gov (United States)

    Verkley, Wim; Severijns, Camiel

    2014-05-01

    Lorenz [1] has devised a dynamical system that has proved to be very useful as a benchmark system in geophysical fluid dynamics. The system in its simplest form consists of a periodic array of variables that can be associated with an atmospheric field on a latitude circle. The system is driven by a constant forcing, is damped by linear friction and has a simple advection term that causes the model to behave chaotically if the forcing is large enough. Our aim is to predict the statistics of Lorenz' model on the basis of a given average value of its total energy - obtained from a numerical integration - and the assumption of statistical stationarity. Our method is the principle of maximum entropy [2] which in this case reads: the information entropy of the system's probability density function shall be maximal under the constraints of normalization, a given value of the average total energy and statistical stationarity. Statistical stationarity is incorporated approximately by using `stationarity constraints', i.e., by requiring that the average first and possibly higher-order time-derivatives of the energy are zero in the maximization of entropy. The analysis [3] reveals that, if the first stationarity constraint is used, the resulting probability density function rather accurately reproduces the statistics of the individual variables. If the second stationarity constraint is used as well, the correlations between the variables are also reproduced quite adequately. The method can be generalized straightforwardly and holds the promise of a viable non-equilibrium statistical mechanics of the forced-dissipative systems of geophysical fluid dynamics. [1] E.N. Lorenz, 1996: Predictability - A problem partly solved, in Proc. Seminar on Predictability (ECMWF, Reading, Berkshire, UK), Vol. 1, pp. 1-18. [2] E.T. Jaynes, 2003: Probability Theory - The Logic of Science (Cambridge University Press, Cambridge). [3] W.T.M. Verkley and C.A. Severijns, 2014: The maximum entropy

  18. Theoretical physics vol. 2. Quantum mechanics, relativistic quantum mechanics, quantum field theory, elementar-particle theory, thermodynamics and statistics

    International Nuclear Information System (INIS)

    Rebhan, E.

    2005-01-01

    The present second volume treats quantum mechanics, relativistic quantum mechanics, the foundations of quantum-field and elementary-particle theory as well as thermodynamics and statistics. Both volumes comprehend all fields, which are usually offered in a course about theoretical physics. In all treated fields a very careful introduction to the basic natural laws forms the starting point, whereby it is thoroughly analysed, which of them is based on empirics, which is logically deducible, and which role play basic definitions. Extendingly the matter extend of the corresponding courses starting from the relativistic quantum theory an introduction to the elementary particles is developed. All problems are very thoroughly and such extensively studied, that each step is singularly reproducible. On motivation and good understandability is cared much about. The mixing of mathematical difficulties with problems of physical nature often obstructive in the learning is so circumvented, that important mathematical methods are presented in own chapters (for instance Hilbert spaces, Lie groups). By means of many examples and problems (for a large part with solutions) the matter worked out is deepened and exercised. Developments, which are indeed important, but seem for the first approach abandonable, are pursued in excurses. This book starts from courses, which the author has held at the Heinrich-Heine university in Duesseldorf, and was in many repetitions fitted to the requirements of the students. It is conceived in such a way, that it is also after the study suited as dictionary or for the regeneration

  19. Statistical evaluation of the mechanical properties of high-volume class F fly ash concretes

    KAUST Repository

    Yoon, Seyoon

    2014-03-01

    High-Volume Fly Ash (HVFA) concretes are seen by many as a feasible solution for sustainable, low embodied carbon construction. At the moment, fly ash is classified as a waste by-product, primarily of thermal power stations. In this paper the authors experimentally and statistically investigated the effects of mix-design factors on the mechanical properties of high-volume class F fly ash concretes. A total of 240 and 32 samples were produced and tested in the laboratory to measure compressive strength and Young\\'s modulus respectively. Applicability of the CEB-FIP (Comite Euro-international du Béton - Fédération Internationale de la Précontrainte) and ACI (American Concrete Institute) Building Model Code (Thomas, 2010; ACI Committee 209, 1982) [1,2] to the experimentally-derived mechanical property data for HVFA concretes was established. Furthermore, using multiple linear regression analysis, Mean Squared Residuals (MSRs) were obtained to determine whether a weight- or volume-based mix proportion is better to predict the mechanical properties of HVFA concrete. The significance levels of the design factors, which indicate how significantly the factors affect the HVFA concrete\\'s mechanical properties, were determined using analysis of variance (ANOVA) tests. The results show that a weight-based mix proportion is a slightly better predictor of mechanical properties than volume-based one. The significance level of fly ash substitution rate was higher than that of w/b ratio initially but reduced over time. © 2014 Elsevier Ltd. All rights reserved.

  20. Physics colloquium: Single-electron counting in quantum metrology and in statistical mechanics

    CERN Multimedia

    Geneva University

    2011-01-01

    GENEVA UNIVERSITY Ecole de physique Département de physique nucléaire et corspusculaire 24, quai Ernest-Ansermet 1211 Genève 4 Tél.: (022) 379 62 73 Fax: (022) 379 69 92olé   Lundi 17 octobre 2011 17h00 - Ecole de Physique, Auditoire Stueckelberg PHYSICS COLLOQUIUM « Single-electron counting in quantum metrology and in statistical mechanics » Prof. Jukka Pekola Low Temperature Laboratory, Aalto University Helsinki, Finland   First I discuss the basics of single-electron tunneling and its potential applications in metrology. My main focus is in developing an accurate source of single-electron current for the realization of the unit ampere. I discuss the principle and the present status of the so-called single- electron turnstile. Investigation of errors in transporting electrons one by one has revealed a wealth of observations on fundamental phenomena in mesoscopic superconductivity, including individual Andreev...

  1. Statistical mechanics of competitive resource allocation using agent-based models

    Science.gov (United States)

    Chakraborti, Anirban; Challet, Damien; Chatterjee, Arnab; Marsili, Matteo; Zhang, Yi-Cheng; Chakrabarti, Bikas K.

    2015-01-01

    Demand outstrips available resources in most situations, which gives rise to competition, interaction and learning. In this article, we review a broad spectrum of multi-agent models of competition (El Farol Bar problem, Minority Game, Kolkata Paise Restaurant problem, Stable marriage problem, Parking space problem and others) and the methods used to understand them analytically. We emphasize the power of concepts and tools from statistical mechanics to understand and explain fully collective phenomena such as phase transitions and long memory, and the mapping between agent heterogeneity and physical disorder. As these methods can be applied to any large-scale model of competitive resource allocation made up of heterogeneous adaptive agent with non-linear interaction, they provide a prospective unifying paradigm for many scientific disciplines.

  2. Excitation functions of parameters in Erlang distribution, Schwinger mechanism, and Tsallis statistics in RHIC BES program

    International Nuclear Information System (INIS)

    Gao, Li-Na; Liu, Fu-Hu; Lacey, Roy A.

    2016-01-01

    Experimental results of the transverse-momentum distributions of φ mesons and Ω hyperons produced in gold-gold (Au-Au) collisions with different centrality intervals, measured by the STAR Collaboration at different energies (7.7, 11.5, 19.6, 27, and 39 GeV) in the beam energy scan (BES) program at the relativistic heavy-ion collider (RHIC), are approximately described by the single Erlang distribution and the two-component Schwinger mechanism. Moreover, the STAR experimental transverse-momentum distributions of negatively charged particles, produced in Au-Au collisions at RHIC BES energies, are approximately described by the two-component Erlang distribution and the single Tsallis statistics. The excitation functions of free parameters are obtained from the fit to the experimental data. A weak softest point in the string tension in Ω hyperon spectra is observed at 7.7 GeV. (orig.)

  3. Statistical mechanical model of gas adsorption in porous crystals with dynamic moieties.

    Science.gov (United States)

    Simon, Cory M; Braun, Efrem; Carraro, Carlo; Smit, Berend

    2017-01-17

    Some nanoporous, crystalline materials possess dynamic constituents, for example, rotatable moieties. These moieties can undergo a conformation change in response to the adsorption of guest molecules, which qualitatively impacts adsorption behavior. We pose and solve a statistical mechanical model of gas adsorption in a porous crystal whose cages share a common ligand that can adopt two distinct rotational conformations. Guest molecules incentivize the ligands to adopt a different rotational configuration than maintained in the empty host. Our model captures inflections, steps, and hysteresis that can arise in the adsorption isotherm as a signature of the rotating ligands. The insights disclosed by our simple model contribute a more intimate understanding of the response and consequence of rotating ligands integrated into porous materials to harness them for gas storage and separations, chemical sensing, drug delivery, catalysis, and nanoscale devices. Particularly, our model reveals design strategies to exploit these moving constituents and engineer improved adsorbents with intrinsic thermal management for pressure-swing adsorption processes.

  4. Statistical-mechanics analysis of Gaussian labeled-unlabeled classification problems

    International Nuclear Information System (INIS)

    Tanaka, Toshiyuki

    2013-01-01

    The labeled-unlabeled classification problem in semi-supervised learning is studied via statistical-mechanics approach. We analytically investigate performance of a learner with an equal-weight mixture of two symmetrically-located Gaussians, performing posterior mean estimation of the parameter vector on the basis of a dataset consisting of labeled and unlabeled data generated from the same probability model as that assumed by the learner. Under the assumption of replica symmetry, we have analytically obtained a set of saddle-point equations, which allows us to numerically evaluate performance of the learner. On the basis of the analytical result we have observed interesting phenomena, in particular the coexistence of good and bad solutions, which may happen when the number of unlabeled data is relatively large compared with that of labeled data

  5. Granular statistical mechanics - Building on the legacy of Sir Sam Edwards

    Science.gov (United States)

    Blumenfeld, Raphael

    When Sir Sam Edwards laid down the foundations for the statistical mechanics of jammed granular materials he opened a new field in soft condensed matter and many followed. In this presentation we review briefly the Edwards formalism and some of its less discussed consequences. We point out that the formalism is useful for other classes of systems - cellular and porous materials. A certain shortcoming of the original formalism is then discussed and a modification to overcome it is proposed. Finally, a derivation of an equation of state with the new formalism is presented; the equation of state is analogous to the PVT relation for thermal gases, relating the volume, the boundary stress and measures of the structural and stress fluctuations. NUDT, Changsha, China, Imperial College London, UK, Cambridge University, UK.

  6. Noise and the statistical mechanics of distributed transport in a colony of interacting agents

    Science.gov (United States)

    Katifori, Eleni; Graewer, Johannes; Ronellenfitsch, Henrik; Mazza, Marco G.

    Inspired by the process of liquid food distribution between individuals in an ant colony, in this work we consider the statistical mechanics of resource dissemination between interacting agents with finite carrying capacity. The agents move inside a confined space (nest), pick up the food at the entrance of the nest and share it with other agents that they encounter. We calculate analytically and via a series of simulations the global food intake rate for the whole colony as well as observables describing how uniformly the food is distributed within the nest. Our model and predictions provide a useful benchmark to assess which strategies can lead to efficient food distribution within the nest and also to what level the observed food uptake rates and efficiency in food distribution are due to stochastic fluctuations or specific food exchange strategies by an actual ant colony.

  7. Multiscale Monte Carlo algorithms in statistical mechanics and quantum field theory

    Energy Technology Data Exchange (ETDEWEB)

    Lauwers, P G

    1990-12-01

    Conventional Monte Carlo simulation algorithms for models in statistical mechanics and quantum field theory are afflicted by problems caused by their locality. They become highly inefficient if investigations of critical or nearly-critical systems, i.e., systems with important large scale phenomena, are undertaken. We present two types of multiscale approaches that alleveate problems of this kind: Stochastic cluster algorithms and multigrid Monte Carlo simulation algorithms. Another formidable computational problem in simulations of phenomenologically relevant field theories with fermions is the need for frequently inverting the Dirac operator. This inversion can be accelerated considerably by means of deterministic multigrid methods, very similar to the ones used for the numerical solution of differential equations. (orig.).

  8. Moral foundations in an interacting neural networks society: A statistical mechanics analysis

    Science.gov (United States)

    Vicente, R.; Susemihl, A.; Jericó, J. P.; Caticha, N.

    2014-04-01

    The moral foundations theory supports that people, across cultures, tend to consider a small number of dimensions when classifying issues on a moral basis. The data also show that the statistics of weights attributed to each moral dimension is related to self-declared political affiliation, which in turn has been connected to cognitive learning styles by the recent literature in neuroscience and psychology. Inspired by these data, we propose a simple statistical mechanics model with interacting neural networks classifying vectors and learning from members of their social neighbourhood about their average opinion on a large set of issues. The purpose of learning is to reduce dissension among agents when disagreeing. We consider a family of learning algorithms parametrized by δ, that represents the importance given to corroborating (same sign) opinions. We define an order parameter that quantifies the diversity of opinions in a group with homogeneous learning style. Using Monte Carlo simulations and a mean field approximation we find the relation between the order parameter and the learning parameter δ at a temperature we associate with the importance of social influence in a given group. In concordance with data, groups that rely more strongly on corroborating evidence sustain less opinion diversity. We discuss predictions of the model and propose possible experimental tests.

  9. Ants in a labyrinth: a statistical mechanics approach to the division of labour.

    Directory of Open Access Journals (Sweden)

    Thomas Owen Richardson

    2011-04-01

    Full Text Available Division of labour (DoL is a fundamental organisational principle in human societies, within virtual and robotic swarms and at all levels of biological organisation. DoL reaches a pinnacle in the insect societies where the most widely used model is based on variation in response thresholds among individuals, and the assumption that individuals and stimuli are well-mixed. Here, we present a spatially explicit model of DoL. Our model is inspired by Pierre de Gennes' 'Ant in a Labyrinth' which laid the foundations of an entire new field in statistical mechanics. We demonstrate the emergence, even in a simplified one-dimensional model, of a spatial patterning of individuals and a right-skewed activity distribution, both of which are characteristics of division of labour in animal societies. We then show using a two-dimensional model that the work done by an individual within an activity bout is a sigmoidal function of its response threshold. Furthermore, there is an inverse relationship between the overall stimulus level and the skewness of the activity distribution. Therefore, the difference in the amount of work done by two individuals with different thresholds increases as the overall stimulus level decreases. Indeed, spatial fluctuations of task stimuli are minimised at these low stimulus levels. Hence, the more unequally labour is divided amongst individuals, the greater the ability of the colony to maintain homeostasis. Finally, we show that the non-random spatial distribution of individuals within biological and social systems could be caused by indirect (stigmergic interactions, rather than direct agent-to-agent interactions. Our model links the principle of DoL with principles in the statistical mechanics and provides testable hypotheses for future experiments.

  10. Statistical physics as an approximate method of many-body quantum mechanics in the representation of occupation numbers

    International Nuclear Information System (INIS)

    Kushnirenko, A.N.

    1989-01-01

    An attempt was made to substantiate statistical physics from the viewpoint of many-body quantum mechanics in the representation of occupation numbers. This approach enabled to develop the variation method for solution of stationary and nonstationary nonequilibrium problems

  11. Thermo-dynamical contours of electronic-vibrational spectra simulated using the statistical quantum-mechanical methods

    DEFF Research Database (Denmark)

    Pomogaev, Vladimir; Pomogaeva, Anna; Avramov, Pavel

    2011-01-01

    Three polycyclic organic molecules in various solvents focused on thermo-dynamical aspects were theoretically investigated using the recently developed statistical quantum mechanical/classical molecular dynamics method for simulating electronic-vibrational spectra. The absorption bands of estradiol...

  12. A general formulation of discrete-time quantum mechanics: Restrictions on the action and the relation of unitarity to the existence theorem for initial-value problems

    International Nuclear Information System (INIS)

    Khorrami, M.

    1995-01-01

    A general formulation for discrete-time quantum mechanics, based on Feynman's method in ordinary quantum mechanics, is presented. It is shown that the ambiguities present in ordinary quantum mechanics (due to noncommutativity of the operators), are no longer present here. Then the criteria for the unitarity of the evolution operator are examined. It is shown that the unitarity of the evolution operator puts restrictions on the form of the action, and also implies the existence of a solution for the classical initial-value problem. 13 refs

  13. Sustained ocular delivery of Dorzolamide-HCl via proniosomal gel formulation: in-vitro characterization, statistical optimization, and in-vivo pharmacodynamic evaluation in rabbits.

    Science.gov (United States)

    Fouda, Nagwa Hussein; Abdelrehim, Randa Tag; Hegazy, Doaa Abdelmagid; Habib, Basant Ahmed

    2018-11-01

    Glaucoma is the second cause of blindness worldwide. Frequent administration of traditional topical dosage forms may lead to patient incompliance and failure of treatment. Our study aims to formulate proniosomal gel formulations that sustain the release of the water-soluble anti-glaucoma drug Dorzolamide-HCl (Dorz). Proniosomal gel formulations were prepared using coacervation phase separation method according to a 5 2 full factorial design. The effects of Cholesterol and surfactant (Span 40) amounts (independent variables) on the percentage entrapment efficiency (EE%), particle size (PS), and the percent of drug released after 8 h (Q8h) (dependent variables (DVs)) were investigated. An optimized formulation (OF) was chosen based on maximizing EE% and Q8h and minimizing PS. An intraocular pressure (IOP) pharmacodynamic study was performed in rabbits to evaluate the in-vivo performance of the OF-gel compared to the marketed Trusopt ® eye drops. The results showed that the independent variables studied significantly affected EE%, PS, and Q8h. OF was the one containing 60 mg Cholesterol and 540 mg Span 40. It had desirability of 0.885 and its actually measured DVs deviated from the predicted ones by a maximum of 4.8%. The in-vivo pharmacodynamic study showed that OF could result in higher reduction in IOP, significantly sustain that reduction in IOP and increase Dorz bioavailability compared to Trusopt ® eye drops. Thus the OF-gel is very promising for being used in glaucoma treatment.

  14. Statistical models based on conditional probability distributions

    International Nuclear Information System (INIS)

    Narayanan, R.S.

    1991-10-01

    We present a formulation of statistical mechanics models based on conditional probability distribution rather than a Hamiltonian. We show that it is possible to realize critical phenomena through this procedure. Closely linked with this formulation is a Monte Carlo algorithm, in which a configuration generated is guaranteed to be statistically independent from any other configuration for all values of the parameters, in particular near the critical point. (orig.)

  15. An in vivo mechanism for the reduced peripheral neurotoxicity of NK105: a paclitaxel-incorporating polymeric micellar nanoparticle formulation

    Directory of Open Access Journals (Sweden)

    Nakamura I

    2017-02-01

    Full Text Available Iwao Nakamura, Eiji Ichimura, Rika Goda, Hitomi Hayashi, Hiroko Mashiba, Daichi Nagai, Hirofumi Yokoyama, Takeshi Onda, Akira Masuda Nanomedicine Group, Pharmaceutical Research Laboratories, Nippon Kayaku Co., Ltd., Tokyo, Japan Abstract: In our previous rodent studies, the paclitaxel (PTX-incorporating polymeric micellar nanoparticle formulation NK105 had showed significantly stronger antitumor effects and reduced peripheral neurotoxicity than PTX dissolved in Cremophor® EL and ethanol (PTX/CRE. Thus, to elucidate the mechanisms underlying reduced peripheral neurotoxicity due to NK105, we performed pharmacokinetic analyses of NK105 and PTX/CRE in rats. Among neural tissues, the highest PTX concentrations were found in the dorsal root ganglion (DRG. Moreover, exposure of DRG to PTX (Cmax_PTX and AUC0-inf._PTX in the NK105 group was almost half that in the PTX/CRE group, whereas exposure of sciatic and sural nerves was greater in the NK105 group than in the PTX/CRE group. In histopathological analyses, damage to DRG and both peripheral nerves was less in the NK105 group than in the PTX/CRE group. The consistency of these pharmacokinetic and histopathological data suggests that high levels of PTX in the DRG play an important role in the induction of peripheral neurotoxicity, and reduced distribution of PTX to the DRG of NK105-treated rats limits the ensuing peripheral neurotoxicity. In further analyses of PTX distribution to the DRG, Evans blue (Eb was injected with BODIPY®-labeled NK105 into rats, and Eb fluorescence was observed only in the DRG. Following injection, most Eb dye bound to albumin particles of ~8 nm and had penetrated the DRG. In contrast, BODIPY®–NK105 particles of ~90 nm were not found in the DRG, suggesting differential penetration based on particle size. Because PTX also circulates as PTX–albumin particles of ~8 nm following injection of PTX/CRE, reduced peripheral neurotoxicity of NK105 may reflect exclusion from the

  16. 8th Liblice Conference on the Statistical Mechanics of Liquids - Brno, Czech Republic, 13-18 June 2010 FOREWORD

    Czech Academy of Sciences Publication Activity Database

    Jackson, G.; Nezbeda, Ivo

    2011-01-01

    Roč. 190, 1 Sp.I:Sl (2011), s. 1-2 ISSN 0026-8976. [Liblice Conference on the Statistical Mechanics of Liquids /8./. Brno, 13.06.2010-18.06.2010] Institutional research plan: CEZ:AV0Z40720504 Keywords : editorial material * theories of liquids * statistical mechanics Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 1.819, year: 2011

  17. Statistical mechanics and dynamics of solvable models with long-range interactions

    International Nuclear Information System (INIS)

    Campa, Alessandro; Dauxois, Thierry; Ruffo, Stefano

    2009-01-01

    For systems with long-range interactions, the two-body potential decays at large distances as V(r)∼1/r α , with α≤d, where d is the space dimension. Examples are: gravitational systems, two-dimensional hydrodynamics, two-dimensional elasticity, charged and dipolar systems. Although such systems can be made extensive, they are intrinsically non additive: the sum of the energies of macroscopic subsystems is not equal to the energy of the whole system. Moreover, the space of accessible macroscopic thermodynamic parameters might be non convex. The violation of these two basic properties of the thermodynamics of short-range systems is at the origin of ensemble inequivalence. In turn, this inequivalence implies that specific heat can be negative in the microcanonical ensemble, and temperature jumps can appear at microcanonical first order phase transitions. The lack of convexity allows us to easily spot regions of parameter space where ergodicity may be broken. Historically, negative specific heat had been found for gravitational systems and was thought to be a specific property of a system for which the existence of standard equilibrium statistical mechanics itself was doubted. Realizing that such properties may be present for a wider class of systems has renewed the interest in long-range interactions. Here, we present a comprehensive review of the recent advances on the statistical mechanics and out-of-equilibrium dynamics of solvable systems with long-range interactions. The core of the review consists in the detailed presentation of the concept of ensemble inequivalence, as exemplified by the exact solution, in the microcanonical and canonical ensembles, of mean-field type models. Remarkably, the entropy of all these models can be obtained using the method of large deviations. Long-range interacting systems display an extremely slow relaxation towards thermodynamic equilibrium and, what is more striking, the convergence towards quasi-stationary states. The

  18. A review of formulation techniques that impact the disintegration and mechanical properties of oradispersible drug delivery technologies.

    Science.gov (United States)

    Manyikana, Martina; Choonara, Yahya E; Tomar, Lomas K; Tyagi, Charu; Kumar, Pradeep; du Toit, Lisa C; Pillay, Viness

    2016-01-01

    The drug treatment of acute disorders such as neuropathic pain, migraines, insomnia, vomiting, allergic rhinitis or erectile dysfunction requires an immediate pharmacological effect that may be achieved through parenteral drug administration. However, the parenteral route is not always convenient for reasons that are well known. Therefore, in the recent past there has been a barrage of interest in formulating new, non-invasive, reliable and convenient oradispersible drug delivery technologies (ODDTs). Research in this area has focused extensively on developing ODDTs that are capable of releasing drugs immediately when they come into contact with saliva. This disregards the necessity of water during administration and several other advantages that is an attribute that makes this technology lucrative for groups such as pediatrics, geriatrics, psychiatrics and unconscious patients. Many reviews have been compiled on the salient features of ODDTs. However, none to date has focused on the actual formulation techniques used to produce these technologies and how this may impact their disintegration and physical stability for fulfilling their purpose. Therefore this review provides a concise incursion on the recent formulation techniques, excipients used as well as methods of testing the performance of ODDTs and critically assesses these in terms of improving their performance.

  19. Protein logic: a statistical mechanical study of signal integration at the single-molecule level.

    Science.gov (United States)

    de Ronde, Wiet; Rein ten Wolde, Pieter; Mugler, Andrew

    2012-09-05

    Information processing and decision-making is based upon logic operations, which in cellular networks has been well characterized at the level of transcription. In recent years, however, both experimentalists and theorists have begun to appreciate that cellular decision-making can also be performed at the level of a single protein, giving rise to the notion of protein logic. Here we systematically explore protein logic using a well-known statistical mechanical model. As an example system, we focus on receptors that bind either one or two ligands, and their associated dimers. Notably, we find that a single heterodimer can realize any of the 16 possible logic gates, including the XOR gate, by variation of biochemical parameters. We then introduce what to our knowledge is a novel idea: that a set of receptors with fixed parameters can encode functionally unique logic gates simply by forming different dimeric combinations. An exhaustive search reveals that the simplest set of receptors (two single-ligand receptors and one double-ligand receptor) can realize several different groups of three unique gates, a result for which the parametric analysis of single receptors and dimers provides a clear interpretation. Both results underscore the surprising functional freedom readily available to cells at the single-protein level. Copyright © 2012 Biophysical Society. Published by Elsevier Inc. All rights reserved.

  20. A Framework for Structural Systems Based on the Principles of Statistical Mechanics

    Directory of Open Access Journals (Sweden)

    Rabindranath Andujar

    2014-11-01

    Full Text Available A framework is proposed in which certain well-known concepts of statistical mechanics and thermodynamics can be used and applied to characterize structural systems of interconnected Timoshenko beam elements. We first make the assimilation to a network of nodes linked by potential energy functions that are derived from the stiffness properties of the beams. Then we define a series of thermodynamic quantities inherent to a given structure (i.e., internal energy, heat, pressure, temperature, entropy, and kinetic energy. With the exception of entropy, all of them have the dimensions of energy. In order to test this new framework, a series of experiments was performed on four structural specimens within the elastic regime. Their configurations were taken from the seismic regulations known as Eurocode 8 in order to have a better based reference for our comparisons. The results are then explained within this new framework. Very interesting correlations have been found between the parameters given in the code and our concepts.

  1. Statistical mechanics of few-particle systems: exact results for two useful models

    Science.gov (United States)

    Miranda, Enrique N.

    2017-11-01

    The statistical mechanics of small clusters (n ˜ 10-50 elements) of harmonic oscillators and two-level systems is studied exactly, following the microcanonical, canonical and grand canonical formalisms. For clusters with several hundred particles, the results from the three formalisms coincide with those found in the thermodynamic limit. However, for clusters formed by a few tens of elements, the three ensembles yield different results. For a cluster with a few tens of harmonic oscillators, when the heat capacity per oscillator is evaluated within the canonical formalism, it reaches a limit value equal to k B , as in the thermodynamic case, while within the microcanonical formalism the limit value is k B (1-1/n). This difference could be measured experimentally. For a cluster with a few tens of two-level systems, the heat capacity evaluated within the canonical and microcanonical ensembles also presents differences that could be detected experimentally. Both the microcanonical and grand canonical formalism show that the entropy is non-additive for systems this small, while the canonical ensemble reaches the opposite conclusion. These results suggest that the microcanonical ensemble is the most appropriate for dealing with systems with tens of particles.

  2. Molecular Mechanism of Enhanced Anticancer Effect of Nanoparticle Formulated LY2835219 via p16-CDK4/6-pRb Pathway in Colorectal Carcinoma Cell Line

    Directory of Open Access Journals (Sweden)

    Xu Tang

    2016-01-01

    Full Text Available LY2835219 is a dual inhibitor to CDK4 and CDK6. This study was to prepare LY2835219-loaded chitosan nanoparticles (CNP/LY and LY2835219-loaded hyaluronic acid-conjugated chitosan nanoparticles (HACNP/LY and revealed their anticancer effect and influence on p16-CDK4/6-pRb pathway against colon cell line. The nanoparticle sizes of CNP/LY and HACNP/LY were approximately 195±39.6 nm and 217±31.1 nm, respectively. The zeta potentials of CNP/LY and HACNP/LY were 37.3±1.5 mV and 30.3±2.2 mV, respectively. And the preparation process showed considerable drug encapsulation efficiency and loading efficiency. LY2835219, CNP/LY, and HACNP/LY inhibited HT29 cell proliferation with 0.68, 0.54, and 0.30 μM of IC50, respectively. G1 phase was arrested by LY2835219 and its formulations. Furthermore, inhibition of CDK4/6 by LY2835219 formulations induced CDK4, CDK6, cyclin D1, and pRb decrease and p16 increase at both protein and mRNA levels. Overall, nanoparticle formulated LY2835219 could enhance the cytotoxicity and cell cycle arrest, and HACNP/LY strengthened the trend furtherly compared to CNP/LY. It is the first time to demonstrate the anticancer effect and mechanism against HT29 by LY2835219 and its nanoparticles. The drug and its nanoparticle formulations delay the cell growth and arrest cell cycle through p16-CDK4/6-pRb pathway, while the nanoparticle formulated LY2835219 could strengthen the process.

  3. A novel experimental design method to optimize hydrophilic matrix formulations with drug release profiles and mechanical properties.

    Science.gov (United States)

    Choi, Du Hyung; Lim, Jun Yeul; Shin, Sangmun; Choi, Won Jun; Jeong, Seong Hoon; Lee, Sangkil

    2014-10-01

    To investigate the effects of hydrophilic polymers on the matrix system, an experimental design method was developed to integrate response surface methodology and the time series modeling. Moreover, the relationships among polymers on the matrix system were studied with the evaluation of physical properties including water uptake, mass loss, diffusion, and gelling index. A mixture simplex lattice design was proposed while considering eight input control factors: Polyethylene glycol 6000 (x1 ), polyethylene oxide (PEO) N-10 (x2 ), PEO 301 (x3 ), PEO coagulant (x4 ), PEO 303 (x5 ), hydroxypropyl methylcellulose (HPMC) 100SR (x6 ), HPMC 4000SR (x7 ), and HPMC 10(5) SR (x8 ). With the modeling, optimal formulations were obtained depending on the four types of targets. The optimal formulations showed the four significant factors (x1 , x2 , x3 , and x8 ) and other four input factors (x4 , x5 , x6 , and x7 ) were not significant based on drug release profiles. Moreover, the optimization results were analyzed with estimated values, targets values, absolute biases, and relative biases based on observed times for the drug release rates with four different targets. The result showed that optimal solutions and target values had consistent patterns with small biases. On the basis of the physical properties of the optimal solutions, the type and ratio of the hydrophilic polymer and the relationships between polymers significantly influenced the physical properties of the system and drug release. This experimental design method is very useful in formulating a matrix system with optimal drug release. Moreover, it can distinctly confirm the relationships between excipients and the effects on the system with extensive and intensive evaluations. © 2014 Wiley Periodicals, Inc. and the American Pharmacists Association.

  4. The formulation of dynamical contact problems with friction in the case of systems of rigid bodies and general discrete mechanical systems—Painlevé and Kane paradoxes revisited

    Science.gov (United States)

    Charles, Alexandre; Ballard, Patrick

    2016-08-01

    The dynamics of mechanical systems with a finite number of degrees of freedom (discrete mechanical systems) is governed by the Lagrange equation which is a second-order differential equation on a Riemannian manifold (the configuration manifold). The handling of perfect (frictionless) unilateral constraints in this framework (that of Lagrange's analytical dynamics) was undertaken by Schatzman and Moreau at the beginning of the 1980s. A mathematically sound and consistent evolution problem was obtained, paving the road for many subsequent theoretical investigations. In this general evolution problem, the only reaction force which is involved is a generalized reaction force, consistently with the virtual power philosophy of Lagrange. Surprisingly, such a general formulation was never derived in the case of frictional unilateral multibody dynamics. Instead, the paradigm of the Coulomb law applying to reaction forces in the real world is generally invoked. So far, this paradigm has only enabled to obtain a consistent evolution problem in only some very few specific examples and to suggest numerical algorithms to produce computational examples (numerical modeling). In particular, it is not clear what is the evolution problem underlying the computational examples. Moreover, some of the few specific cases in which this paradigm enables to write down a precise evolution problem are known to show paradoxes: the Painlevé paradox (indeterminacy) and the Kane paradox (increase in kinetic energy due to friction). In this paper, we follow Lagrange's philosophy and formulate the frictional unilateral multibody dynamics in terms of the generalized reaction force and not in terms of the real-world reaction force. A general evolution problem that governs the dynamics is obtained for the first time. We prove that all the solutions are dissipative; that is, this new formulation is free of Kane paradox. We also prove that some indeterminacy of the Painlevé paradox is fixed in this

  5. A statistical mechanical approach for the computation of the climatic response to general forcings

    Directory of Open Access Journals (Sweden)

    V. Lucarini

    2011-01-01

    Full Text Available The climate belongs to the class of non-equilibrium forced and dissipative systems, for which most results of quasi-equilibrium statistical mechanics, including the fluctuation-dissipation theorem, do not apply. In this paper we show for the first time how the Ruelle linear response theory, developed for studying rigorously the impact of perturbations on general observables of non-equilibrium statistical mechanical systems, can be applied with great success to analyze the climatic response to general forcings. The crucial value of the Ruelle theory lies in the fact that it allows to compute the response of the system in terms of expectation values of explicit and computable functions of the phase space averaged over the invariant measure of the unperturbed state. We choose as test bed a classical version of the Lorenz 96 model, which, in spite of its simplicity, has a well-recognized prototypical value as it is a spatially extended one-dimensional model and presents the basic ingredients, such as dissipation, advection and the presence of an external forcing, of the actual atmosphere. We recapitulate the main aspects of the general response theory and propose some new general results. We then analyze the frequency dependence of the response of both local and global observables to perturbations having localized as well as global spatial patterns. We derive analytically several properties of the corresponding susceptibilities, such as asymptotic behavior, validity of Kramers-Kronig relations, and sum rules, whose main ingredient is the causality principle. We show that all the coefficients of the leading asymptotic expansions as well as the integral constraints can be written as linear function of parameters that describe the unperturbed properties of the system, such as its average energy. Some newly obtained empirical closure equations for such parameters allow to define such properties as an explicit function of the unperturbed forcing

  6. Natural time analysis and Tsallis non-additive entropy statistical mechanics.

    Science.gov (United States)

    Sarlis, N. V.; Skordas, E. S.; Varotsos, P.

    2016-12-01

    Upon analyzing the seismic data in natural time and employing a sliding natural time window comprising a number of events that would occur in a few months, it has been recently uncovered[1] that a precursory Seismic Electric Signals activity[2] initiates almost simultaneously with the appearance of a minimum in the fluctuations of the order parameter of seismicity [3]. Such minima have been ascertained [4] during periods of the magnitude time series exhibiting long range correlations [5] a few months before all earthquakes of magnitude 7.6 or larger that occurred in the entire Japanese area from 1 January 1984 to 11 March 2011 (the day of the M9 Tohoku-Oki earthquake). Before and after these minima, characteristic changes of the temporal correlations between earthquake magnitudes are observed which cannot be captured by Tsallis non-additive entropy statistical mechanics in the frame of which it has been suggested that kappa distributions arise [6]. Here, we extend the study concerning the existence of such minima in a large area that includes Aegean Sea and its surrounding area which exhibits in general seismo-tectonics [7] different than that of the entire Japanese area. References P. A. Varotsos et al., Tectonophysics, 589 (2013) 116. P. Varotsos and M. Lazaridou, Tectonophysics 188 (1991) 321. P.A. Varotsos et al., Phys Rev E 72 (2005) 041103. N. V. Sarlis et al., Proc Natl Acad Sci USA 110 (2013) 13734. P. A. Varotsos, N. V. Sarlis, and E. S. Skordas, J Geophys Res Space Physics 119 (2014), 9192, doi: 10.1002/2014JA0205800. G. Livadiotis, and D. J. McComas, J Geophys Res 114 (2009) A11105, doi:10.1029/2009JA014352. S. Uyeda et al., Tectonophysics, 304 (1999) 41.

  7. Statistical Comparison of the Baseline Mechanical Properties of NBG-18 and PCEA Graphite

    Energy Technology Data Exchange (ETDEWEB)

    Mark C. Carroll; David T. Rohrbaugh

    2013-08-01

    High-purity graphite is the core structural material of choice in the Very High Temperature Reactor (VHTR), a graphite-moderated, helium-cooled design that is capable of producing process heat for power generation and for industrial process that require temperatures higher than the outlet temperatures of present nuclear reactors. The Baseline Graphite Characterization Program is endeavoring to minimize the conservative estimates of as-manufactured mechanical and physical properties by providing comprehensive data that captures the level of variation in measured values. In addition to providing a comprehensive comparison between these values in different nuclear grades, the program is also carefully tracking individual specimen source, position, and orientation information in order to provide comparisons and variations between different lots, different billets, and different positions from within a single billet. This report is a preliminary comparison between the two grades of graphite that were initially favored in the two main VHTR designs. NBG-18, a medium-grain pitch coke graphite from SGL formed via vibration molding, was the favored structural material in the pebble-bed configuration, while PCEA, a smaller grain, petroleum coke, extruded graphite from GrafTech was favored for the prismatic configuration. An analysis of the comparison between these two grades will include not only the differences in fundamental and statistically-significant individual strength levels, but also the differences in variability in properties within each of the grades that will ultimately provide the basis for the prediction of in-service performance. The comparative performance of the different types of nuclear grade graphites will continue to evolve as thousands more specimens are fully characterized from the numerous grades of graphite being evaluated.

  8. Statistical mechanics of a time-homogeneous system of money and antimoney

    Science.gov (United States)

    Schmitt, Matthias; Schacker, Andreas; Braun, Dieter

    2014-03-01

    Financial crises appear throughout human history. While there are many schools of thought on what the actual causes of such crises are, it has been suggested that the creation of credit money might be a source of financial instability. We discuss how the credit mechanism in a system of fractional reserve banking leads to non-local transfers of purchasing power that also affect non-involved agents. To overcome this issue, we impose the local symmetry of time homogeneity on the monetary system. A bi-currency system of non-bank assets (money) and bank assets (antimoney) is considered. A payment is either made by passing on money or by receiving antimoney. As a result, a free floating exchange rate between non-bank assets and bank assets is established. Credit creation is replaced by the simultaneous transfer of money and antimoney at a negotiated exchange rate. This is in contrast to traditional discussions of full reserve banking, which stalls creditary lending. With money and antimoney, the problem of credit crunches is mitigated while a full time symmetry of the monetary system is maintained. As a test environment for such a monetary system, we discuss an economy of random transfers. Random transfers are a strong criterion to probe the stability of monetary systems. The analysis using statistical physics provides analytical solutions and confirms that a money-antimoney system could be functional. Equally important to the probing of the stability of such a monetary system is the question of how to implement the credit default dynamics. This issue remains open.

  9. Statistical mechanics of a time-homogeneous system of money and antimoney

    International Nuclear Information System (INIS)

    Schmitt, Matthias; Schacker, Andreas; Braun, Dieter

    2014-01-01

    Financial crises appear throughout human history. While there are many schools of thought on what the actual causes of such crises are, it has been suggested that the creation of credit money might be a source of financial instability. We discuss how the credit mechanism in a system of fractional reserve banking leads to non-local transfers of purchasing power that also affect non-involved agents. To overcome this issue, we impose the local symmetry of time homogeneity on the monetary system. A bi-currency system of non-bank assets (money) and bank assets (antimoney) is considered. A payment is either made by passing on money or by receiving antimoney. As a result, a free floating exchange rate between non-bank assets and bank assets is established. Credit creation is replaced by the simultaneous transfer of money and antimoney at a negotiated exchange rate. This is in contrast to traditional discussions of full reserve banking, which stalls creditary lending. With money and antimoney, the problem of credit crunches is mitigated while a full time symmetry of the monetary system is maintained. As a test environment for such a monetary system, we discuss an economy of random transfers. Random transfers are a strong criterion to probe the stability of monetary systems. The analysis using statistical physics provides analytical solutions and confirms that a money–antimoney system could be functional. Equally important to the probing of the stability of such a monetary system is the question of how to implement the credit default dynamics. This issue remains open

  10. A Statistical Study on VLF Subionospheric Perturbations Associated with Major Earthquakes: A View from Focal Mechanism

    Science.gov (United States)

    Kawano, T.; Tatsuta, K.; Hobara, Y.

    2015-12-01

    Continuous monitoring of signal amplitudes of worldwide VLF transmitters is a powerful tool to study the lower ionospheric condition. Although, lower ionospheric perturbations prior to some of the major earthquakes have been reported for years, their occurrence and coupling mechanism between the ground and overlaying ionosphere prior to the earthquakes are not clear yet. In this paper, we carried out a statistical analysis based on the nighttime averaged signal amplitude data from the UEC's VLF/LF transmitter observation network. Two hundred forty three earthquakes were occurred within the 5th Fresnel zone of transmitter-receiver paths around Japan during the time period of 2007 to 2012. These earthquakes were characterized into three different groups based on the Centroid-Moment-Tensor (CMT) solution such as reverse fault type, normal fault type and stress slip type. The ionospheric anomaly was identified by a large change in the VLF/LF amplitude during nighttime. As a result, we found the ionospheric perturbations associated with both ground and sea earthquakes. Remarkably, the reverse fault type earthquakes have the highest occurrence rate of ionospheric perturbation among the three types both for sea (41%) and ground events (61%). The occurrence rates for normal type fault are 35% and 56% for sea and ground earthquakes respectively and the same for stress slip type are 39% and 20% for sea and ground earthquakes respectively. In both cases the occurrence rates are smaller than the reverse fault type. The clear difference of occurrence rate of the ionospheric perturbations may indicate that the coupling efficiency of seismic activity into the overlaying ionosphere is controlled by the pressure in the earth's crust. This gives us further physical insight of Lithosphere-Atmosphere-Ionosphere (LAI) coupling processes.

  11. Microcanonical ensemble formulation of lattice gauge theory

    International Nuclear Information System (INIS)

    Callaway, D.J.E.; Rahman, A.

    1982-01-01

    A new formulation of lattice gauge theory without explicit path integrals or sums is obtained by using the microcanonical ensemble of statistical mechanics. Expectation values in the new formalism are calculated by solving a large set of coupled, nonlinear, ordinary differential equations. The average plaquette for compact electrodynamics calculated in this fashion agrees with standard Monte Carlo results. Possible advantages of the microcanonical method in applications to fermionic systems are discussed

  12. Mechanical behaviour of alkali-activated blast furnace slag-activated metakaolin blended pastes. Statistical study

    Directory of Open Access Journals (Sweden)

    Higuera, I.

    2012-06-01

    Full Text Available The study and development of alternative, more ecoefficient binders than portland cement are attracting a good deal of scientific and technological interest. Binders obtained from the chemical interaction between calcium silico-aluminous materials and highly alkaline solutions are one of several types of such possible cements. The present paper discusses the mechanical behaviour and mineralogical composition of blended pastes made from NaOH-activated vitreous blast furnace slag and metakaolin. The aim of the study was to determine how parameters such as the slag/metakaolin ratio, activating solution concentration and curing temperature affect strength development in these binders. A statistical study was conducted to establish the impact of each variable and model strength behaviour in these alkaline cements. The conclusion drawn is that activator concentration and the slag/metakaolin ratio are both determinant parameters.

    El estudio y desarrollo de cementos alternativos y más eco-eficientes que el cemento Portland es un tema de gran impacto a nivel científico y tecnológico. Entre esos posibles cementos se encuentran los cementos alcalinos que son materiales conglomerantes obtenidos por la interacción química de materiales silico-aluminosos cálcicos y disoluciones fuertemente alcalinas. En el presente trabajo se estudia el comportamiento mecánico y la composición mineralógica de mezclas de escoria vítrea de horno alto y metacaolín activadas alcalinamente con disoluciones de NaOH. El objetivo de este estudio es conocer cómo afectan parámetros tales como la relación escoria/metacaolín, la concentración de la disolución activadora y la temperatura de curado, al desarrollo resistente de las mezclas. A través del estudio estadístico realizado se ha podido establecer la influencia de cada variable y modelizar el comportamiento resistente de estos cementos alcalinos. Se concluye que la concentración del activador y la relaci

  13. Mathematics of statistical mechanics and the chaos theory; Las matematicas de la mecanica estadistica y de la teoria del caos

    Energy Technology Data Exchange (ETDEWEB)

    Llave, R. de la; Haro, A.

    2000-07-01

    Statistical mechanics requires a language that unifies probabilistic and deterministic description of physical systems. We describe briefly some of the mathematical ideas needed for this unification. These ideas have also proved important in the study of chaotic systems. (Author) 17 refs.

  14. Infinite-mode squeezed coherent states and non-equilibrium statistical mechanics (phase-space-picture approach)

    International Nuclear Information System (INIS)

    Yeh, L.

    1992-01-01

    The phase-space-picture approach to quantum non-equilibrium statistical mechanics via the characteristic function of infinite- mode squeezed coherent states is introduced. We use quantum Brownian motion as an example to show how this approach provides an interesting geometrical interpretation of quantum non-equilibrium phenomena

  15. The Sigmoid Transfer Function and the Gain-threshold Exponential Dependence for Neurons from Statistical Mechanics Treatment

    Czech Academy of Sciences Publication Activity Database

    Andrey, Ladislav; Erzan, R.

    2002-01-01

    Roč. 52, č. 12 (2002), s. 1349-1356 ISSN 0011-4626 R&D Projects: GA ČR GA305/02/1487 Institutional research plan: AV0Z1030915 Keywords : nonlinear gain curve * gain-threshold dependence * non-monotone transfer function * statistical mechanics Subject RIV: BA - General Mathematics Impact factor: 0.311, year: 2002

  16. Phase Transitions in Combinatorial Optimization Problems Basics, Algorithms and Statistical Mechanics

    CERN Document Server

    Hartmann, Alexander K

    2005-01-01

    A concise, comprehensive introduction to the topic of statistical physics of combinatorial optimization, bringing together theoretical concepts and algorithms from computer science with analytical methods from physics. The result bridges the gap between statistical physics and combinatorial optimization, investigating problems taken from theoretical computing, such as the vertex-cover problem, with the concepts and methods of theoretical physics. The authors cover rapid developments and analytical methods that are both extremely complex and spread by word-of-mouth, providing all the necessary

  17. On the SU(2 vertical stroke 1) WZNW model and its statistical mechanics applications

    Energy Technology Data Exchange (ETDEWEB)

    Saleur, H [CEA Centre d' Etudes de Saclay, 91 - Gif-sur-Yvette (France). Service de Physique Theorique; [University of Southern California, Los Angeles, CA (United States). Dept. of Physics; Schomerus, V [Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany)

    2006-11-15

    Motivated by a careful analysis of the Laplacian on the supergroup SU(2 vertical stroke 1) we formulate a proposal for the state space of the SU(2 vertical stroke 1) WZNW model. We then use properties of sl(2 vertical stroke 1) characters to compute the partition function of the theory. In the special case of level k=1 the latter is found to agree with the properly regularized partition function for the continuum limit of the integrable sl(2 vertical stroke 1)3- anti 3 super-spin chain. Some general conclusions applicable to other WZNW models (in particular the case k=-1/2) are also drawn. (orig.)

  18. Nuclear multifragmentation, its relation to general physics. A rich test ground of the fundamentals of statistical mechanics

    International Nuclear Information System (INIS)

    Gross, D.H.E.

    2006-01-01

    Heat can flow from cold to hot at any phase separation even in macroscopic systems. Therefore also Lynden-Bell's famous gravo-thermal catastrophe must be reconsidered. In contrast to traditional canonical Boltzmann-Gibbs statistics this is correctly described only by microcanonical statistics. Systems studied in chemical thermodynamics (ChTh) by using canonical statistics consist of several homogeneous macroscopic phases. Evidently, macroscopic statistics as in chemistry cannot and should not be applied to non-extensive or inhomogeneous systems like nuclei or galaxies. Nuclei are small and inhomogeneous. Multifragmented nuclei are even more inhomogeneous and the fragments even smaller. Phase transitions of first order and especially phase separations therefore cannot be described by a (homogeneous) canonical ensemble. Taking this serious, fascinating perspectives open for statistical nuclear fragmentation as test ground for the basic principles of statistical mechanics, especially of phase transitions, without the use of the thermodynamic limit. Moreover, there is also a lot of similarity between the accessible phase space of fragmenting nuclei and inhomogeneous multistellar systems. This underlines the fundamental significance for statistical physics in general. (orig.)

  19. An approach for generating trajectory-based dynamics which conserves the canonical distribution in the phase space formulation of quantum mechanics. II. Thermal correlation functions.

    Science.gov (United States)

    Liu, Jian; Miller, William H

    2011-03-14

    We show the exact expression of the quantum mechanical time correlation function in the phase space formulation of quantum mechanics. The trajectory-based dynamics that conserves the quantum canonical distribution-equilibrium Liouville dynamics (ELD) proposed in Paper I is then used to approximately evaluate the exact expression. It gives exact thermal correlation functions (of even nonlinear operators, i.e., nonlinear functions of position or momentum operators) in the classical, high temperature, and harmonic limits. Various methods have been presented for the implementation of ELD. Numerical tests of the ELD approach in the Wigner or Husimi phase space have been made for a harmonic oscillator and two strongly anharmonic model problems, for each potential autocorrelation functions of both linear and nonlinear operators have been calculated. It suggests ELD can be a potentially useful approach for describing quantum effects for complex systems in condense phase.

  20. On application of non—extensive statistical mechanics to studying ecological diversity

    International Nuclear Information System (INIS)

    Van Xuan, Le; Lan, Nguyen Tri; Viet, Nguyen Ai

    2016-01-01

    The concept of Tsallis entropy provides an extension of thermodynamics and statistical physics. In the ecology, Tsallis entropy is proposed to be a new class of diversity indices S_q which covers many common diversity indices found in ecological literature. As a new statistical model for the Whittaker plots describing species abundance distribution, the truncated exponential distribution is used to calculate the diversity and evenness indices. The obtained results in new model are graphically compared with those in previous publication in the same field of interests, and shows a good agreement. A further development of a thermodynamic theory of ecological systems that is consistent with entropic approach of statistical physics is motivated. (paper)

  1. Casein films: effects of formulation, environmental conditions, and addition of citric pectin on the structure and mechanical properties

    Science.gov (United States)

    Thin casein films for food packaging applications reportedly possess good strength and low oxygen permeability, but low water-resistance and elasticity. Modifying and customizing the mechanical properties of the films to target specific behaviors depending on environmental conditions would enable a...

  2. Statistical-mechanical theory of the overall magnetic properties of mesocrystals.

    Science.gov (United States)

    Huang, J P

    2004-10-01

    The mesocrystal showing both electrorheological and magnetorheological effects is called electro-magnetorheological (EMR) solids. Prediction of the overall magnetic properties of the EMR solids is a challenging task due to the coexistence of the uniaxially anisotropic behavior and structural transition as well as long-range interaction between the suspended particles. To consider the uniaxial anisotropy effect, we present an anisotropic Kirkwood-Fröhlich equation for calculating the effective permeabilities by adopting an explicit characteristic spheroid rather than a characteristic sphere used in the derivation of the usual Kirkwood-Fröhlich equation. Further, by applying an Ewald-Kornfeld formulation we are able to investigate the effective permeability by including the structural transition and long-range interaction explicitly. Our theory can reduce to the usual Kirkwood-Fröhlich equation and Onsager equation naturally. To this end, the numerical simulation shows the validity of monitoring the structure of EMR solids by detecting their effective permeabilities.

  3. Nonequilibrium statistical mechanics of shear flow: invariant quantities and current relations

    International Nuclear Information System (INIS)

    Baule, A; Evans, R M L

    2010-01-01

    In modeling nonequilibrium systems one usually starts with a definition of the microscopic dynamics, e.g., in terms of transition rates, and then derives the resulting macroscopic behavior. We address the inverse question for a class of steady state systems, namely complex fluids under continuous shear flow: how does an externally imposed shear current affect the microscopic dynamics of the fluid? The answer can be formulated in the form of invariant quantities, exact relations for the transition rates in the nonequilibrium steady state, as discussed in a recent letter (Baule and Evans, 2008 Phys. Rev. Lett. 101 240601). Here, we present a more pedagogical account of the invariant quantities and the theory underlying them, known as the nonequilibrium counterpart to detailed balance (NCDB). Furthermore, we investigate the relationship between the transition rates and the shear current in the steady state. We show that a fluctuation relation of the Gallavotti–Cohen type holds for systems satisfying NCDB

  4. Study of energy fluctuation effect on the statistical mechanics of equilibrium systems

    International Nuclear Information System (INIS)

    Lysogorskiy, Yu V; Wang, Q A; Tayurskii, D A

    2012-01-01

    This work is devoted to the modeling of energy fluctuation effect on the behavior of small classical thermodynamic systems. It is known that when an equilibrium system gets smaller and smaller, one of the major quantities that becomes more and more uncertain is its internal energy. These increasing fluctuations can considerably modify the original statistics. The present model considers the effect of such energy fluctuations and is based on an overlapping between the Boltzmann-Gibbs statistics and the statistics of the fluctuation. Within this o verlap statistics , we studied the effects of several types of energy fluctuations on the probability distribution, internal energy and heat capacity. It was shown that the fluctuations can considerably change the temperature dependence of internal energy and heat capacity in the low energy range and at low temperatures. Particularly, it was found that, due to the lower energy limit of the systems, the fluctuations reduce the probability for the low energy states close to the lowest energy and increase the total average energy. This energy increasing is larger for lower temperatures, making negative heat capacity possible for this case.

  5. Classical and statistical mechanics of celestial-scale spinning strings: Rotating space elevators

    Science.gov (United States)

    Golubović, L.; Knudsen, S.

    2009-05-01

    We introduce novel and unique class of dynamical systems, Rotating Space Elevators (RSE). The RSEs are multiply rotating systems of strings reaching into outer space. Objects sliding along RSE strings do not require internal engines or propulsion to be transported from the Earth's surface into outer space. The RSEs exhibit interesting nonlinear dynamics and statistical physics phenomena.

  6. Learning Curves and Bootstrap Estimates for Inference with Gaussian Processes: A Statistical Mechanics Study

    DEFF Research Database (Denmark)

    Malzahn, Dorthe; Opper, Manfred

    2003-01-01

    We employ the replica method of statistical physics to study the average case performance of learning systems. The new feature of our theory is that general distributions of data can be treated, which enables applications to real data. For a class of Bayesian prediction models which are based...... on Gaussian processes, we discuss Bootstrap estimates for learning curves....

  7. An Explicit Formulation of Singularity-Free Dynamic Equations of Mechanical Systems in Lagrangian Form---Part one: Single Rigid Bodies

    Directory of Open Access Journals (Sweden)

    Pål Johan From

    2012-04-01

    Full Text Available This paper presents the explicit dynamic equations of a mechanical system. The equations are presented so that they can easily be implemented in a simulation software or controller environment and are also well suited for system and controller analysis. The dynamics of a general mechanical system consisting of one or more rigid bodies can be derived from the Lagrangian. We can then use several well known properties of Lie groups to guarantee that these equations are well defined. This will, however, often lead to rather abstract formulation of the dynamic equations that cannot be implemented in a simulation software directly. In this paper we close this gap and show what the explicit dynamic equations look like. These equations can then be implemented directly in a simulation software and no background knowledge on Lie theory and differential geometry on the practitioner's side is required. This is the first of two papers on this topic. In this paper we derive the dynamics for single rigid bodies, while in the second part we study multibody systems. In addition to making the equations more accessible to practitioners, a motivation behind the papers is to correct a few errors commonly found in literature. For the first time, we show the detailed derivations and how to arrive at the correct set of equations. We also show through some simple examples that these correspond with the classical formulations found from Lagrange's equations. The dynamics is derived from the Boltzmann--Hamel equations of motion in terms of local position and velocity variables and the mapping to the corresponding quasi-velocities. Finally we present a new theorem which states that the Boltzmann--Hamel formulation of the dynamics is valid for all transformations with a Lie group topology. This has previously only been indicated through examples, but here we also present the formal proof. The main motivation of these papers is to allow practitioners not familiar with

  8. Density-Dependent Formulation of Dispersion-Repulsion Interactions in Hybrid Multiscale Quantum/Molecular Mechanics (QM/MM) Models

    DEFF Research Database (Denmark)

    Curutchet, Carles; Cupellini, Lorenzo; Kongsted, Jacob

    2018-01-01

    embedding approaches, respectively, nonelectrostatic dispersion and repulsion interactions are instead commonly described through classical potentials despite their quantum mechanical origin. Here we present an extension of the Tkatchenko-Scheffler semiempirical van der Waals (vdWTS) scheme aimed......Mixed multiscale quantum/molecular mechanics (QM/MM) models are widely used to explore the structure, reactivity, and electronic properties of complex chemical systems. Whereas such models typically include electrostatics and potentially polarization in so-called electrostatic and polarizable...... at describing dispersion and repulsion interactions between quantum and classical regions within a QM/MM polarizable embedding framework. Starting from the vdWTSexpression, we define a dispersion and a repulsion term, both of them density-dependent and consistently based on a Lennard-Jones-like potential. We...

  9. Mechanical properties and antibiotic release characteristics of poly(methyl methacrylate)-based bone cement formulated with mesoporous silica nanoparticles.

    Science.gov (United States)

    Letchmanan, Kumaran; Shen, Shou-Cang; Ng, Wai Kiong; Kingshuk, Poddar; Shi, Zhilong; Wang, Wilson; Tan, Reginald B H

    2017-08-01

    The influence of mesoporous silica nanoparticles (MSNs) loaded with antibiotics on the mechanical properties of functional poly(methyl methacrylate)-(PMMA) based bone cements is investigated. The incorporation of MSNs to the bone cements (8.15wt%) shows no detrimental effects on the biomechanical properties of the freshly solidified bone cements. Importantly, there are no significant changes in the compression strength and bending modulus up to 6 months of aging in PBS buffer solution. The preserved mechanical properties of MSN-functionalized bone cements is attributed to the unchanged microstructures of the cements, as more than 96% of MSNs remains in the bone cement matrix to support the cement structures after 6 months of aging. In addition, the MSN-functionalized bone cements are able to increase the drug release of gentamicin (GTMC) significantly as compared with commercially available antibiotic-loaded bone cements. It can be attributed to the loaded nano-sized MSNs with uniform pore channels which build up an effective nano-network path enable the diffusion and extended release of GTMC. The combination of excellent mechanical properties and sustainable drug delivery efficiency demonstrates the potential applicability of MSN-functionalized PMMA bone cements for orthopedic surgery to prevent post-surgery infection. Copyright © 2017 Elsevier Ltd. All rights reserved.

  10. Neocortical Dynamics at Multiple Scales: EEG Standing Waves, Statistical Mechanics, and Physical Analogs

    OpenAIRE

    Ingber, Lester; Nunez, Paul L.

    2010-01-01

    The dynamic behavior of scalp potentials (EEG) is apparently due to some combination of global and local processes with important top-down and bottom-up interactions across spatial scales. In treating global mechanisms, we stress the importance of myelinated axon propagation delays and periodic boundary conditions in the cortical-white matter system, which is topologically close to a spherical shell. By contrast, the proposed local mechanisms are multiscale interactions between cortical colum...

  11. Phase Transitions in Combinatorial Optimization Problems: Basics, Algorithms and Statistical Mechanics

    Science.gov (United States)

    Hartmann, Alexander K.; Weigt, Martin

    2005-10-01

    A concise, comprehensive introduction to the topic of statistical physics of combinatorial optimization, bringing together theoretical concepts and algorithms from computer science with analytical methods from physics. The result bridges the gap between statistical physics and combinatorial optimization, investigating problems taken from theoretical computing, such as the vertex-cover problem, with the concepts and methods of theoretical physics. The authors cover rapid developments and analytical methods that are both extremely complex and spread by word-of-mouth, providing all the necessary basics in required detail. Throughout, the algorithms are shown with examples and calculations, while the proofs are given in a way suitable for graduate students, post-docs, and researchers. Ideal for newcomers to this young, multidisciplinary field.

  12. Quantum mechanics of the fractional-statistics gas: Random-phase approximation

    International Nuclear Information System (INIS)

    Dai, Q.; Levy, J.L.; Fetter, A.L.; Hanna, C.B.; Laughlin, R.B.

    1992-01-01

    A description of the fractional-statistics gas based on the complete summation of Hartree, Fock, ladder and bubble diagrams is presented. The superfluid properties identified previously in the random-phase-approximation (RPA) calculation of Fetter, Hanna, and Laughlin [Phys. Rev. B 39, 9679 (1989)] are substantially confirmed. The discrepancy between the RPA sound speed and the Hartree-Fock bulk modulus is found to be eliminated. The unusual Hall-effect behavior is found to vanish for the Bose gas test case but not for the fractional-statistics gas, implying that it is physically correct. Excellent agreement is obtained with the collective-mode dispersion obtained numerically by Xie, He, and Das Sarma [Phys. Rev. Lett. 65, 649 (1990)

  13. Statistical state dynamics-based analysis of the physical mechanisms sustaining and regulating turbulence in Couette flow

    Science.gov (United States)

    Farrell, Brian F.; Ioannou, Petros J.

    2017-08-01

    This paper describes a study of the self-sustaining process in wall turbulence. The study is based on a second order statistical state dynamics model of Couette flow in which the state variables are the streamwise mean flow (first cumulant) and perturbation covariance (second cumulant). This statistical state dynamics model is closed by either setting the third cumulant to zero or by replacing it with a stochastic parametrization. Statistical state dynamics models with this form are referred to as S3T models. S3T models have been shown to self-sustain turbulence with a mean flow and second order perturbation structure similar to that obtained by direct numerical simulation of the equations of motion. The use of a statistical state dynamics model to study the physical mechanisms underlying turbulence has important advantages over the traditional approach of studying the dynamics of individual realizations of turbulence. One advantage is that the analytical structure of S3T statistical state dynamics models isolates the interaction between the mean flow and the perturbation components of the turbulence. Isolation of the interaction between these components reveals how this interaction underlies both the maintenance of the turbulence variance by transfer of energy from the externally driven flow to the perturbation components as well as the enforcement of the observed statistical mean turbulent state by feedback regulation between the mean and perturbation fields. Another advantage of studying turbulence using statistical state dynamics models of S3T form is that the analytical structure of S3T turbulence can be completely characterized. For example, the perturbation component of turbulence in the S3T system is demonstrably maintained by a parametric perturbation growth mechanism in which fluctuation of the mean flow maintains the perturbation field which in turn maintains the mean flow fluctuations in a synergistic interaction. Furthermore, the equilibrium

  14. Appplication of statistical mechanical methods to the modeling of social networks

    Science.gov (United States)

    Strathman, Anthony Robert

    With the recent availability of large-scale social data sets, social networks have become open to quantitative analysis via the methods of statistical physics. We examine the statistical properties of a real large-scale social network, generated from cellular phone call-trace logs. We find this network, like many other social networks to be assortative (r = 0.31) and clustered (i.e., strongly transitive, C = 0.21). We measure fluctuation scaling to identify the presence of internal structure in the network and find that structural inhomogeneity effectively disappears at the scale of a few hundred nodes, though there is no sharp cutoff. We introduce an agent-based model of social behavior, designed to model the formation and dissolution of social ties. The model is a modified Metropolis algorithm containing agents operating under the basic sociological constraints of reciprocity, communication need and transitivity. The model introduces the concept of a social temperature. We go on to show that this simple model reproduces the global statistical network features (incl. assortativity, connected fraction, mean degree, clustering, and mean shortest path length) of the real network data and undergoes two phase transitions, one being from a "gas" to a "liquid" state and the second from a liquid to a glassy state as function of this social temperature.

  15. Density-Dependent Formulation of Dispersion-Repulsion Interactions in Hybrid Multiscale Quantum/Molecular Mechanics (QM/MM) Models.

    Science.gov (United States)

    Curutchet, Carles; Cupellini, Lorenzo; Kongsted, Jacob; Corni, Stefano; Frediani, Luca; Steindal, Arnfinn Hykkerud; Guido, Ciro A; Scalmani, Giovanni; Mennucci, Benedetta

    2018-03-13

    Mixed multiscale quantum/molecular mechanics (QM/MM) models are widely used to explore the structure, reactivity, and electronic properties of complex chemical systems. Whereas such models typically include electrostatics and potentially polarization in so-called electrostatic and polarizable embedding approaches, respectively, nonelectrostatic dispersion and repulsion interactions are instead commonly described through classical potentials despite their quantum mechanical origin. Here we present an extension of the Tkatchenko-Scheffler semiempirical van der Waals (vdW TS ) scheme aimed at describing dispersion and repulsion interactions between quantum and classical regions within a QM/MM polarizable embedding framework. Starting from the vdW TS expression, we define a dispersion and a repulsion term, both of them density-dependent and consistently based on a Lennard-Jones-like potential. We explore transferable atom type-based parametrization strategies for the MM parameters, based on either vdW TS calculations performed on isolated fragments or on a direct estimation of the parameters from atomic polarizabilities taken from a polarizable force field. We investigate the performance of the implementation by computing self-consistent interaction energies for the S22 benchmark set, designed to represent typical noncovalent interactions in biological systems, in both equilibrium and out-of-equilibrium geometries. Overall, our results suggest that the present implementation is a promising strategy to include dispersion and repulsion in multiscale QM/MM models incorporating their explicit dependence on the electronic density.

  16. Non-equilibrium statistical mechanical approach for describing heavy ion reactions

    International Nuclear Information System (INIS)

    Sventek, J.S.

    1979-01-01

    With the availability of heavy-ion projectiles (A > 4) at low to intermediate energies (4 < E/A < 10), products showing various stages of relaxation for certain macroscopic variables (center-of-mass energy, orbital angular momentum, etc.) were produced in various reactions. The distributions for these macroscopic variables showed a correlation between the stage of relaxation reached and the net amount of mass transfer which had occurred in the reaction. There was also evidence that there was an asymmetry in the number of net transfers necessary for complete relaxation between stripping ad pickup reactions. A model for describing the time-evolution of these reactions has been formulated, the keystone of which is a master-equation approach for describing the time-dependence of the mass-asymmetry. This, coupled with deterministic equations of motion for the other macroscopic coordinates in the reaction lead to calculated distributions which provide an excellent qualitative description of these reactions, and, in some cases, quantitatively reproduce the experimental data quite well

  17. Statistical mechanics of fluids under internal constraints: Rigorous results for the one-dimensional hard rod fluid

    International Nuclear Information System (INIS)

    Corti, D.S.; Debenedetti, P.G.

    1998-01-01

    The rigorous statistical mechanics of metastability requires the imposition of internal constraints that prevent access to regions of phase space corresponding to inhomogeneous states. We derive exactly the Helmholtz energy and equation of state of the one-dimensional hard rod fluid under the influence of an internal constraint that places an upper bound on the distance between nearest-neighbor rods. This type of constraint is relevant to the suppression of boiling in a superheated liquid. We determine the effects of this constraint upon the thermophysical properties and internal structure of the hard rod fluid. By adding an infinitely weak and infinitely long-ranged attractive potential to the hard core, the fluid exhibits a first-order vapor-liquid transition. We determine exactly the equation of state of the one-dimensional superheated liquid and show that it exhibits metastable phase equilibrium. We also derive statistical mechanical relations for the equation of state of a fluid under the action of arbitrary constraints, and show the connection between the statistical mechanics of constrained and unconstrained ensembles. copyright 1998 The American Physical Society

  18. For a science of layered mechanisms: beyond laws, statistics, and correlations.

    Science.gov (United States)

    Castelfranchi, Cristiano

    2014-01-01

    Two general claims are made in this work. First, we need several different layers of "theory," in particular for understanding human behavior. These layers should concern: the cognitive (mental) representations and mechanisms; the neural underlying processes; the evolutionary history and adaptive functions of our cognition and behaviors; the emergent and complex social structures and dynamics, their relation and feedbacks on individual minds and behaviors, and the relationship between internal regulating goals and the external functions/roles of our conduct; the historical and cultural mechanisms shaping our minds and behaviors; the developmental paths. Second, we do not just need "predictions" and "laws" but also "explanations"; that is, we need to identify the mechanisms producing (here-and-now, or diachronically) a given phenomenon. "Laws" are not enough; they are simply descriptive and predictive; we need the "why" and "how." Correlations are not enough (and they are frequently misleading). We need computational models of the processes postulated in our theories.

  19. The role of nonequilibrium thermo-mechanical statistics in modern technologies and industrial processes: an overview

    OpenAIRE

    Rodrigues, Clóves G.; Silva, Antônio A. P.; Silva, Carlos A. B.; Vasconcellos, Áurea R.; Ramos, J. Galvão; Luzzi, Roberto

    2010-01-01

    The nowadays notable development of all the modern technology, fundamental for the progress and well being of world society, imposes a great deal of stress in the realm of basic Physics, more precisely on Thermo-Statistics. We do face situations in electronics and optoelectronics involving physical-chemical systems far-removed-from equilibrium, where ultrafast (in pico- and femto-second scale) and non-linear processes are present. Further, we need to be aware of the rapid unfolding of nano-te...

  20. Quantum-statistical mechanics of an atom-dimer mixture: Lee-Yang cluster expansion approach

    International Nuclear Information System (INIS)

    Ohkuma, Takahiro; Ueda, Masahito

    2006-01-01

    We use the Lee-Yang cluster expansion method to study quantum-statistical properties of a mixture of interconvertible atoms and dimers, where the dimers form in a two-body bound state of the atoms. We point out an infinite series of cluster diagrams whose summation leads to the Bose-Einstein condensation of the dimers below a critical temperature. Our theory captures some important features of a cold atom-dimer mixture such as interconversion of atoms and dimers and properties of the mixture at the unitarity limit

  1. Thermodynamics and statistical mechanics of some hydrides of the lanthanides and actinides

    International Nuclear Information System (INIS)

    Mintz, M.H.

    1976-06-01

    This work deals mainly with the thermodynamic and physical properties of the hydrides of the lanthanides and actinides. In addition, statistical models have been developed and applied to metal-hydrogen systems. A kinetic study of the uranium-hydrogen system was performed. The thermodynamic properties of the hydrides of neptunium, thorium, praseodymium, neodymium, samarium and europium were determined. In addition the samarium-europium-hydrogen ternary system was investigated. Moessbauer effect measurements of cubic neptunium hydrides were interpreted according to a model presented. A comparison. (author)

  2. Applied statistical thermodynamics

    CERN Document Server

    Lucas, Klaus

    1991-01-01

    The book guides the reader from the foundations of statisti- cal thermodynamics including the theory of intermolecular forces to modern computer-aided applications in chemical en- gineering and physical chemistry. The approach is new. The foundations of quantum and statistical mechanics are presen- ted in a simple way and their applications to the prediction of fluid phase behavior of real systems are demonstrated. A particular effort is made to introduce the reader to expli- cit formulations of intermolecular interaction models and to show how these models influence the properties of fluid sy- stems. The established methods of statistical mechanics - computer simulation, perturbation theory, and numerical in- tegration - are discussed in a style appropriate for newcom- ers and are extensively applied. Numerous worked examples illustrate how practical calculations should be carried out.

  3. Modular reweighting software for statistical mechanical analysis of biased equilibrium data

    Science.gov (United States)

    Sindhikara, Daniel J.

    2012-07-01

    Here a simple, useful, modular approach and software suite designed for statistical reweighting and analysis of equilibrium ensembles is presented. Statistical reweighting is useful and sometimes necessary for analysis of equilibrium enhanced sampling methods, such as umbrella sampling or replica exchange, and also in experimental cases where biasing factors are explicitly known. Essentially, statistical reweighting allows extrapolation of data from one or more equilibrium ensembles to another. Here, the fundamental separable steps of statistical reweighting are broken up into modules - allowing for application to the general case and avoiding the black-box nature of some “all-inclusive” reweighting programs. Additionally, the programs included are, by-design, written with little dependencies. The compilers required are either pre-installed on most systems, or freely available for download with minimal trouble. Examples of the use of this suite applied to umbrella sampling and replica exchange molecular dynamics simulations will be shown along with advice on how to apply it in the general case. New version program summaryProgram title: Modular reweighting version 2 Catalogue identifier: AEJH_v2_0 Program summary URL:http://cpc.cs.qub.ac.uk/summaries/AEJH_v2_0.html Program obtainable from: CPC Program Library, Queen's University, Belfast, N. Ireland Licensing provisions: GNU General Public License, version 3 No. of lines in distributed program, including test data, etc.: 179 118 No. of bytes in distributed program, including test data, etc.: 8 518 178 Distribution format: tar.gz Programming language: C++, Python 2.6+, Perl 5+ Computer: Any Operating system: Any RAM: 50-500 MB Supplementary material: An updated version of the original manuscript (Comput. Phys. Commun. 182 (2011) 2227) is available Classification: 4.13 Catalogue identifier of previous version: AEJH_v1_0 Journal reference of previous version: Comput. Phys. Commun. 182 (2011) 2227 Does the new

  4. For a science of layered mechanisms: beyond laws, statistics, and correlations

    Directory of Open Access Journals (Sweden)

    Cristiano eCastelfranchi

    2014-06-01

    Full Text Available Two general claims are made in this work. First, we need several different layers of theory, in particular for understanding human behavior. These layers should concern: the cognitive (mental representations and mechanisms; the neural underlying processes; the evolutionary history and adaptive functions of our cognition and behaviors; the emergent and complex social structures and dynamics, their relation and feedbacks on individual minds and behaviors, and the relationship between internal regulating goals and the external functions/roles of our conduct; the historical and cultural mechanisms shaping our minds and behaviors; the developmental paths. Second, we do not just need predictions and laws but also explanations; that is, we need to identify the mechanisms producing (here-and-now, or diachronically a given phenomenon. Laws are not enough; they are simply descriptive and predictive; we need the why and how. Correlations are not enough (and they are frequently misleading. We need computational models of the processes postulated in our theories.Reductionism, Cognitive architecture, Emergence, Intentions, Functions, Computer modeling and simulation, Proximate causes

  5. Statistical grand rounds: understanding the mechanism: mediation analysis in randomized and nonrandomized studies.

    Science.gov (United States)

    Mascha, Edward J; Dalton, Jarrod E; Kurz, Andrea; Saager, Leif

    2013-10-01

    In comparative clinical studies, a common goal is to assess whether an exposure, or intervention, affects the outcome of interest. However, just as important is to understand the mechanism(s) for how the intervention affects outcome. For example, if preoperative anemia was shown to increase the risk of postoperative complications by 15%, it would be important to quantify how much of that effect was due to patients receiving intraoperative transfusions. Mediation analysis attempts to quantify how much, if any, of the effect of an intervention on outcome goes though prespecified mediator, or "mechanism" variable(s), that is, variables sitting on the causal pathway between exposure and outcome. Effects of an exposure on outcome can thus be divided into direct and indirect, or mediated, effects. Mediation is claimed when 2 conditions are true: the exposure affects the mediator and the mediator (adjusting for the exposure) affects the outcome. Understanding how an intervention affects outcome can validate or invalidate one's original hypothesis and also facilitate further research to modify the responsible factors, and thus improve patient outcome. We discuss the proper design and analysis of studies investigating mediation, including the importance of distinguishing mediator variables from confounding variables, the challenge of identifying potential mediators when the exposure is chronic versus acute, and the requirements for claiming mediation. Simple designs are considered, as well as those containing multiple mediators, multiple outcomes, and mixed data types. Methods are illustrated with data collected by the National Surgical Quality Improvement Project (NSQIP) and utilized in a companion paper which assessed the effects of preoperative anemic status on postoperative outcomes.

  6. Path integrals in quantum mechanics, statistics, polymer physics, and financial markets

    CERN Document Server

    Kleinert, Hagen

    2009-01-01

    This is the fifth, expanded edition of the comprehensive textbook published in 1990 on the theory and applications of path integrals. It is the first book to explicitly solve path integrals of a wide variety of nontrivial quantum-mechanical systems, in particular the hydrogen atom. The solutions have been made possible by two major advances. The first is a new euclidean path integral formula which increases the restricted range of applicability of Feynman's time-sliced formula to include singular attractive 1/r- and 1/r2-potentials. The second is a new nonholonomic mapping principle carrying p

  7. Predicting the lung compliance of mechanically ventilated patients via statistical modeling

    International Nuclear Information System (INIS)

    Ganzert, Steven; Kramer, Stefan; Guttmann, Josef

    2012-01-01

    To avoid ventilator associated lung injury (VALI) during mechanical ventilation, the ventilator is adjusted with reference to the volume distensibility or ‘compliance’ of the lung. For lung-protective ventilation, the lung should be inflated at its maximum compliance, i.e. when during inspiration a maximal intrapulmonary volume change is achieved by a minimal change of pressure. To accomplish this, one of the main parameters is the adjusted positive end-expiratory pressure (PEEP). As changing the ventilator settings usually produces an effect on patient's lung mechanics with a considerable time delay, the prediction of the compliance change associated with a planned change of PEEP could assist the physician at the bedside. This study introduces a machine learning approach to predict the nonlinear lung compliance for the individual patient by Gaussian processes, a probabilistic modeling technique. Experiments are based on time series data obtained from patients suffering from acute respiratory distress syndrome (ARDS). With a high hit ratio of up to 93%, the learned models could predict whether an increase/decrease of PEEP would lead to an increase/decrease of the compliance. However, the prediction of the complete pressure–volume relation for an individual patient has to be improved. We conclude that the approach is well suitable for the given problem domain but that an individualized feature selection should be applied for a precise prediction of individual pressure–volume curves. (paper)

  8. Short-period atmospheric gravity waves - A study of their statistical properties and source mechanisms

    Science.gov (United States)

    Gedzelman, S. D.

    1983-01-01

    Gravity waves for the one year period beginning 19 October 1976 around Palisades, New York, are investigated to determine their statistical properties and sources. The waves have typical periods of 10 min, pressure amplitudes of 3 Pa and velocities of 30 m/s. In general, the largest, amplitude waves occur during late fall and early winter when the upper tropospheric winds directly overhead are fastest and the static stability of the lower troposphere is greatest. Mean wave amplitudes correlate highly with the product of the mean maximum wind speed and the mean low level stratification directly aloft. A distinct diurnal variation of wave amplitudes with the largest waves occurring in the pre-dawn hours is also observed as a result of the increased static stability then. The majority of waves are generated by shear instability; however, a number of waves are generated by distant sources such as nuclear detonations or large thunderstorms. The waves with distant sources can be distinguished on the basis of their generally much higher coherency across the grid and velocities that depart markedly from the wind velocity at any point in the sounding.

  9. An analysis of a large dataset on immigrant integration in Spain. The Statistical Mechanics perspective on Social Action

    Science.gov (United States)

    Barra, Adriano; Contucci, Pierluigi; Sandell, Rickard; Vernia, Cecilia

    2014-02-01

    How does immigrant integration in a country change with immigration density? Guided by a statistical mechanics perspective we propose a novel approach to this problem. The analysis focuses on classical integration quantifiers such as the percentage of jobs (temporary and permanent) given to immigrants, mixed marriages, and newborns with parents of mixed origin. We find that the average values of different quantifiers may exhibit either linear or non-linear growth on immigrant density and we suggest that social action, a concept identified by Max Weber, causes the observed non-linearity. Using the statistical mechanics notion of interaction to quantitatively emulate social action, a unified mathematical model for integration is proposed and it is shown to explain both growth behaviors observed. The linear theory instead, ignoring the possibility of interaction effects would underestimate the quantifiers up to 30% when immigrant densities are low, and overestimate them as much when densities are high. The capacity to quantitatively isolate different types of integration mechanisms makes our framework a suitable tool in the quest for more efficient integration policies.

  10. Degradation of creatinine using boron-doped diamond electrode: Statistical modeling and degradation mechanism.

    Science.gov (United States)

    Zhang, Zhefeng; Xian, Jiahui; Zhang, Chunyong; Fu, Degang

    2017-09-01

    This study investigated the degradation performance and mechanism of creatinine (a urine metabolite) with boron-doped diamond (BDD) anodes. Experiments were performed using a synthetic creatinine solution containing two supporting electrolytes (NaCl and Na 2 SO 4 ). A three-level central composite design was adopted to optimize the degradation process, a mathematical model was thus constructed and used to explore the optimum operating conditions. A maximum mineralization percentage of 80% following with full creatinine removal had been achieved within 120 min of electrolysis, confirming the strong oxidation capability of BDD anodes. Moreover, the results obtained suggested that supporting electrolyte concentration should be listed as one of the most important parameters in BDD technology. Lastly, based on the results from quantum chemistry calculations and LC/MS analyses, two different reaction pathways which governed the electrocatalytic oxidation of creatinine irrespective of the supporting electrolytes were identified. Copyright © 2017 Elsevier Ltd. All rights reserved.

  11. Statistical mechanical characteristics of slip-ring induction motors when direct current braking

    Energy Technology Data Exchange (ETDEWEB)

    Kedzior, W; Muchorowski, J; Pienkowski, K

    1980-09-01

    This paper evaluates methods of braking high capacity belt conveyors used in brown coal surface mines in Poland. Complications associated with belt conveyor braking, particularly when a conveyor moves down a slope, are analyzed. A method of calculating mechanical characteristics of wound-rotor induction motors during direct current braking taking into account saturation of magnetic circuit is presented. Characteristics of the SZUr motor with 630 kW power, used in brown coal mining, are also given. Analyses show that motor operation can be efficiently braked in two ways: 1. by changing additional resistance in rotor circuit (e.g. using thyristor controller); 2. by changing intensity of electric current supplied to stator winding (e.g. using a rectifier). (3 refs.) (In Polish)

  12. Molecular Dynamics Simulation and Statistics Analysis Reveals the Defense Response Mechanism in Plants

    Science.gov (United States)

    Liu, Zhichao; Zhao, Yunjie; Zeng, Chen; Computational Biophysics Lab Team

    As the main protein of the bacterial flagella, flagellin plays an important role in perception and defense response. The newly discovered locus, FLS2, is ubiquitously expressed. FLS2 encodes a putative receptor kinase and shares many homologies with some plant resistance genes and even with some components of immune system of mammals and insects. In Arabidopsis, FLS2 perception is achieved by the recognition of epitope flg22, which induces FLS2 heteromerization with BAK1 and finally the plant immunity. Here we use both analytical methods such as Direct Coupling Analysis (DCA) and Molecular Dynamics (MD) Simulations to get a better understanding of the defense mechanism of FLS2. This may facilitate a redesign of flg22 or de-novo design for desired specificity and potency to extend the immune properties of FLS2 to other important crops and vegetables.

  13. Maximum entropy approach to H-theory: Statistical mechanics of hierarchical systems.

    Science.gov (United States)

    Vasconcelos, Giovani L; Salazar, Domingos S P; Macêdo, A M S

    2018-02-01

    A formalism, called H-theory, is applied to the problem of statistical equilibrium of a hierarchical complex system with multiple time and length scales. In this approach, the system is formally treated as being composed of a small subsystem-representing the region where the measurements are made-in contact with a set of "nested heat reservoirs" corresponding to the hierarchical structure of the system, where the temperatures of the reservoirs are allowed to fluctuate owing to the complex interactions between degrees of freedom at different scales. The probability distribution function (pdf) of the temperature of the reservoir at a given scale, conditioned on the temperature of the reservoir at the next largest scale in the hierarchy, is determined from a maximum entropy principle subject to appropriate constraints that describe the thermal equilibrium properties of the system. The marginal temperature distribution of the innermost reservoir is obtained by integrating over the conditional distributions of all larger scales, and the resulting pdf is written in analytical form in terms of certain special transcendental functions, known as the Fox H functions. The distribution of states of the small subsystem is then computed by averaging the quasiequilibrium Boltzmann distribution over the temperature of the innermost reservoir. This distribution can also be written in terms of H functions. The general family of distributions reported here recovers, as particular cases, the stationary distributions recently obtained by Macêdo et al. [Phys. Rev. E 95, 032315 (2017)10.1103/PhysRevE.95.032315] from a stochastic dynamical approach to the problem.

  14. Statistical mechanics of the self-gravitating gas: II. Local physical magnitudes and fractal structures

    International Nuclear Information System (INIS)

    Vega, H.J. de; Sanchez, N.

    2002-01-01

    We complete our study of the self-gravitating gas by computing the fluctuations around the saddle point solution for the three statistical ensembles (grand canonical, canonical and microcanonical). Although the saddle point is the same for the three ensembles, the fluctuations change from one ensemble to the other. The zeroes of the small fluctuations determinant determine the position of the critical points for each ensemble. This yields the domains of validity of the mean field approach. Only the S-wave determinant exhibits critical points. Closed formulae for the S- and P-wave determinants of fluctuations are derived. The local properties of the self-gravitating gas in thermodynamic equilibrium are studied in detail. The pressure, energy density, particle density and speed of sound are computed and analyzed as functions of the position. The equation of state turns out to be locally p(r→ )=Tρ V (r→ ) as for the ideal gas. Starting from the partition function of the self-gravitating gas, we prove in this microscopic calculation that the hydrostatic description yielding locally the ideal gas equation of state is exact in the N=∞ limit. The dilute nature of the thermodynamic limit (N∼L→∞ with N/L fixed) together with the long range nature of the gravitational forces play a crucial role in obtaining such ideal gas equation. The self-gravitating gas being inhomogeneous, we have PV/[NT]=f(η)≤1 for any finite volume V. The inhomogeneous particle distribution in the ground state suggests a fractal distribution with Haussdorf dimension D, D is slowly decreasing with increasing density, 1< D<3. The average distance between particles is computed in Monte Carlo simulations and analytically in the mean field approach. A dramatic drop at the phase transition is exhibited, clearly illustrating the properties of the collapse

  15. High order ADER schemes for a unified first order hyperbolic formulation of continuum mechanics: Viscous heat-conducting fluids and elastic solids

    International Nuclear Information System (INIS)

    Dumbser, Michael; Peshkov, Ilya; Romenski, Evgeniy; Zanotti, Olindo

    2016-01-01

    Highlights: • High order schemes for a unified first order hyperbolic formulation of continuum mechanics. • The mathematical model applies simultaneously to fluid mechanics and solid mechanics. • Viscous fluids are treated in the frame of hyper-elasticity as generalized visco-plastic solids. • Formal asymptotic analysis reveals the connection with the Navier–Stokes equations. • The distortion tensor A in the model appears to be well-suited for flow visualization. - Abstract: This paper is concerned with the numerical solution of the unified first order hyperbolic formulation of continuum mechanics recently proposed by Peshkov and Romenski [110], further denoted as HPR model. In that framework, the viscous stresses are computed from the so-called distortion tensor A, which is one of the primary state variables in the proposed first order system. A very important key feature of the HPR model is its ability to describe at the same time the behavior of inviscid and viscous compressible Newtonian and non-Newtonian fluids with heat conduction, as well as the behavior of elastic and visco-plastic solids. Actually, the model treats viscous and inviscid fluids as generalized visco-plastic solids. This is achieved via a stiff source term that accounts for strain relaxation in the evolution equations of A. Also heat conduction is included via a first order hyperbolic system for the thermal impulse, from which the heat flux is computed. The governing PDE system is hyperbolic and fully consistent with the first and the second principle of thermodynamics. It is also fundamentally different from first order Maxwell–Cattaneo-type relaxation models based on extended irreversible thermodynamics. The HPR model represents therefore a novel and unified description of continuum mechanics, which applies at the same time to fluid mechanics and solid mechanics. In this paper, the direct connection between the HPR model and the classical hyperbolic–parabolic Navier

  16. High order ADER schemes for a unified first order hyperbolic formulation of continuum mechanics: Viscous heat-conducting fluids and elastic solids

    Energy Technology Data Exchange (ETDEWEB)

    Dumbser, Michael, E-mail: michael.dumbser@unitn.it [Department of Civil, Environmental and Mechanical Engineering, University of Trento, Via Mesiano 77, 38123 Trento (Italy); Peshkov, Ilya, E-mail: peshkov@math.nsc.ru [Open and Experimental Center for Heavy Oil, Université de Pau et des Pays de l' Adour, Avenue de l' Université, 64012 Pau (France); Romenski, Evgeniy, E-mail: evrom@math.nsc.ru [Sobolev Institute of Mathematics, 4 Acad. Koptyug Avenue, 630090 Novosibirsk (Russian Federation); Novosibirsk State University, 2 Pirogova Str., 630090 Novosibirsk (Russian Federation); Zanotti, Olindo, E-mail: olindo.zanotti@unitn.it [Department of Civil, Environmental and Mechanical Engineering, University of Trento, Via Mesiano 77, 38123 Trento (Italy)

    2016-06-01

    Highlights: • High order schemes for a unified first order hyperbolic formulation of continuum mechanics. • The mathematical model applies simultaneously to fluid mechanics and solid mechanics. • Viscous fluids are treated in the frame of hyper-elasticity as generalized visco-plastic solids. • Formal asymptotic analysis reveals the connection with the Navier–Stokes equations. • The distortion tensor A in the model appears to be well-suited for flow visualization. - Abstract: This paper is concerned with the numerical solution of the unified first order hyperbolic formulation of continuum mechanics recently proposed by Peshkov and Romenski [110], further denoted as HPR model. In that framework, the viscous stresses are computed from the so-called distortion tensor A, which is one of the primary state variables in the proposed first order system. A very important key feature of the HPR model is its ability to describe at the same time the behavior of inviscid and viscous compressible Newtonian and non-Newtonian fluids with heat conduction, as well as the behavior of elastic and visco-plastic solids. Actually, the model treats viscous and inviscid fluids as generalized visco-plastic solids. This is achieved via a stiff source term that accounts for strain relaxation in the evolution equations of A. Also heat conduction is included via a first order hyperbolic system for the thermal impulse, from which the heat flux is computed. The governing PDE system is hyperbolic and fully consistent with the first and the second principle of thermodynamics. It is also fundamentally different from first order Maxwell–Cattaneo-type relaxation models based on extended irreversible thermodynamics. The HPR model represents therefore a novel and unified description of continuum mechanics, which applies at the same time to fluid mechanics and solid mechanics. In this paper, the direct connection between the HPR model and the classical hyperbolic–parabolic Navier

  17. Exact matrix treatment of statistical mechanical lattice model of adsorption induced gate opening in metal-organic frameworks

    International Nuclear Information System (INIS)

    Dunne, Lawrence J; Manos, George

    2015-01-01

    Here we present a statistical mechanical lattice model which is exactly solvable using a matrix method and allows treatment of adsorption induced gate opening structural transformations of metal-organic frameworks which are nanoporous materials with exceptional adsorption properties. Modelling of these structural changes presents a serious theoretical challenge when the solid and gas species are treated in an even handed way. This exactly solvable model complements other simulation based approaches. The methodology presented here highlights the competition between the potential for adsorption and the energy required for structural transition as a driving force for the features in the adsorption isotherms. (paper)

  18. Non-Gaussian Closed Form Solutions for Geometric Average Asian Options in the Framework of Non-Extensive Statistical Mechanics

    Directory of Open Access Journals (Sweden)

    Pan Zhao

    2018-01-01

    Full Text Available In this paper we consider pricing problems of the geometric average Asian options under a non-Gaussian model, in which the underlying stock price is driven by a process based on non-extensive statistical mechanics. The model can describe the peak and fat tail characteristics of returns. Thus, the description of underlying asset price and the pricing of options are more accurate. Moreover, using the martingale method, we obtain closed form solutions for geometric average Asian options. Furthermore, the numerical analysis shows that the model can avoid underestimating risks relative to the Black-Scholes model.

  19. Multiplicative formulation of quantum mechanics

    International Nuclear Information System (INIS)

    Voros, A.; Leboeuf, P.

    1991-01-01

    A general semi-classical description for the eigenfunctions of the multidimensional Schroedinger operator cannot be based on the WKB method which is incompatible with classically ergodic behavior. An alternative, more general multiplicative parametrization of quantum wave functions is suggested, whereby the semi-classical behavior of eigenfunctions can be traced in the presence of classical ergodicity, in the form of diffusive patterns of phase-space zeros in the quantum wave functions. (author) 24 refs.; 4 figs

  20. Quantum and Statistical Mechanics Applied to Singlet Carbenes, Pericyclic Reactions, and Condensed Phase Phenomena

    Science.gov (United States)

    Evanseck, Jeffrey Donald

    The completed research covers a broad range of theoretical applications in organic chemistry. It is divided into three chapters which covers the chemistry of singlet carbenes (Chapter 1), substituent effects in pericyclic rearrangements (Chapter 2), and the effects of solvent on the reactivity of organic reactions (Chapter 3). The selectivity between 1,2- and 1,4-intramolecular additions to restricted diene systems has been investigated. A decrease in activation energy for the intramolecular cycloaddition is noted for systems which approach the idealized geometry found with intermolecular addition of carbenes to olefins. Direct substitution at the carbene site dramatically effects the predicted activation barriers for 1,2-hydrogen shifts. An excellent correlation between the activation energy and a substituents sigma_sp {rm R}{rm o} parameters has been demonstrated. The long standing problem of orbital alignment influences on the selectivity of 1,2-hydrogen arrangements shows significant geometric distortions, yet has little influence on the rates of singlet alkylcarbene rearrangements. The exo-selectivities observed for 1,2-shifts in rigid systems are explained by torsional and steric interactions which develop in the transition structures. Substituent effects on pericyclic reactions have been computed for several conrotatory and disrotatory electrocyclizations. The six-electron disrotatory electrocyclization of 1-substituted hexatrienes displays a strong electronic component in determining stereoselectivity, despite incredible steric interference. The eight-electron conrotatory electrocyclization transition structure of 1-substituted octatetraene has an unusual helical transition structure which does not differentiate between substituent position. The effects of solvents on the acidity differences between E and Z esters has supplemented earlier ab initio quantum mechanical results on the enhanced acidity of Meldrum's acid. Monte Carlo simulations predict a