International Nuclear Information System (INIS)
McGowan, F.K.; Stelson, P.H.
1974-01-01
The theory of Coulomb excitation and a brief review of pertinent treatments of the Coulomb excitation process that are useful for the analysis of experiments are given. Examples demonstrating the scope of nuclear structure information obtainable from gamma spectroscopy are presented. Direct Elambda excitation of 232 Th is discussed in terms of the one phonon octupole vibrational spectrum. B(MI) reduced transition probabilities resulting from Coulomb excitation of odd-A deformed nuclei with heavy ions are presented as a test of the rotational model. The use of gamma ray coincidence and particle-gamma coincidence as tools for investigating Coulomb excitation is discussed. (U.S.)
On some aspects of Coulomb excitation of nuclear rotational states
International Nuclear Information System (INIS)
Massmann, H.; Robotham, H.
1979-01-01
The Coulomb excitation of nuclear rotational states is studied with a semiclassical method using classical trajectories and the classical action in order to construct the excitation probabilities. This method allows one to consider the effect on the excitation probabilities of a weak nuclear potential. An explicit expression for the 'safe bombarding energy' that is the largest bombarding energy for which the nuclear force can be neglected, is found. Also the transfer of angular momentum to the projectile's orbit is considered. One finds that the dynamical distortion of the orbit has a measurable effect on the excitation probabilities for the case of very heavy ions. Furthermore, new dimensionless parameters measuring the dynamical distortion and the effect of the adiabaticity of the collision are introduced and discussed. (author)
Energy Technology Data Exchange (ETDEWEB)
Guevara, Z. E., E-mail: zjguevaram@unal.edu.co; Torres, D. A., E-mail: datorresg@unal.edu.co [Physics Department, Universidad Nacional de Colombia, Bogotá D.C. (Colombia)
2016-07-07
In this contribution the challenges in the use of a setup to simultaneously measure lifetimes and g-factor values will be presented. The simultaneous use of the transient field technique and the Doppler Shift Attenuation Method, to measure magnetic moments and lifetimes respectively, allows to obtain a complete characterization of the currents of nucleons and the deformation in excited states close to the ground state. The technique is at the moment limited to Coulomb excitation and alpha-transfer reactions, what opens an interesting perspective to consider this type of experiments with radioactive beams. The use of deep-inelastic and fusion-evaporation reactions will be discussed. An example of a setup that makes use of a beam of {sup 106}Cd to study excited states of {sup 110}Sn and the beam nuclei itself will be presented.
Relativistic Coulomb excitation
International Nuclear Information System (INIS)
Winther, A.; Alder, K.
1979-01-01
Coulomb excitation of both target and projectile in relativistic heavy ion collisions is evaluated including the lowest order correction for the deviation from a straight line trajectory. Explicit results for differential and total cross sections are given in the form of tables and figures. (Auth.)
International Nuclear Information System (INIS)
Brandao, S.B.
1987-01-01
The level structure of 189 Os has been studied by Coulomb excitation using 35 Cl, 28 Si, 16 O beams. GOSIA, a code written to analyze multiple Coulomb excitation, was used to obtain the reduced probabilities of transition B(E2). The results for interband and intraband turned out possible the classification of the states following Nilsson levels. Gamma-rays originating from deexcitation of 216.7 and 219.4 keV have been separated and the reduced probability of transition has been measured. (A.C.A.S.) [pt
International Nuclear Information System (INIS)
Bolotin, Yu.L.; Gonchar, V.Yu.; Chekanov, N.A.
1985-01-01
Coulomb excitation of rotational states induced in heavyion collisions is treated in the framework of the generalized semiclassical approximation. The Hamiltonian of the system under consideration involves not only Coulomb forces (monopole, quadrupole, and hexadecapole) but as well a real nuclear potential in the form of the deformed Woods-Saxon potential. Strong dependence of the excitation probability on the interference between the Coulomb and nuclear interactions is shown. Calculations are carried out for the reaction 40 Ar+ 162 Dy at E=148.6 MeV. The calculated Coulomb excitation probabilities agree satisfactory with the corresponding experimental values
The structure of low-lying states in ${}^{140}$Sm studied by Coulomb excitation
Klintefjord, M.; Görgen, A.; Bauer, C.; Bello Garrote, F.L.; Bönig, S.; Bounthong, B.; Damyanova, A.; Delaroche, J.P.; Fedosseev, V.; Fink, D.A.; Giacoppo, F.; Girod, M.; Hoff, P.; Imai, N.; Korten, W.; Larsen, A.C.; Libert, J.; Lutter, R.; Marsh, B.A.; Molkanov, P.L.; Naïdja, H.; Napiorkowski, P.; Nowacki, F.; Pakarinen, J.; Rapisarda, E.; Reiter, P.; Renstrøm, T.; Rothe, S.; Seliverstov, M.D.; Siebeck, B.; Siem, S.; Srebrny, J.; Stora, T.; Thöle, P.; Tornyi, T.G.; Tveten, G.M.; Van Duppen, P.; Vermeulen, M.J.; Voulot, D.; Warr, N.; Wenander, F.; De Witte, H.; Zielińska, M.
2016-05-02
The electromagnetic structure of $^{140}$Sm was studied in a low-energy Coulomb excitation experiment with a radioactive ion beam from the REX-ISOLDE facility at CERN. The $2^+$ and $4^+$ states of the ground-state band and a second $2^+$ state were populated by multi-step excitation. The analysis of the differential Coulomb excitation cross sections yielded reduced transition probabilities between all observed states and the spectroscopic quadrupole moment for the $2_1^+$ state. The experimental results are compared to large-scale shell model calculations and beyond-mean-field calculations based on the Gogny D1S interaction with a five-dimensional collective Hamiltonian formalism. Simpler geometric and algebraic models are also employed to interpret the experimental data. The results indicate that $^{140}$Sm shows considerable $\\gamma$ softness, but in contrast to earlier speculation no signs of shape coexistence at low excitation energy. This work sheds more light on the onset of deformation and collectivit...
Coulomb excitation of the 4+1 states of 194Pt, 196Pt and 198Pt
International Nuclear Information System (INIS)
Fewell, M.P.; Gyapong, G.J.; Spear, R.H.
1987-09-01
Probabilities for the Coulomb excitation of the 4 1 + states of 194 Pt, 196 Pt, 198 Pt by the backscattering of 4 He, 12 C and 16 O ions are reported. Model-independent values of the matrix elements 1 + ; M(E4), 4 1 + > and 1 + , M(E2), 4 1 + > are extracted. Agreement with previous measurements of these matrix elements is good. Values of β 2 and β 4 are determined for 194 Pt and compared with calculations of these quantities
Coulomb Excitation of a Neutron-Rich $^{88}$Kr Beam Search for Mixed Symmetry States
Andreoiu, C; Napiorkowski, P J; Iwanicki, J S
2002-01-01
We propose to use the ISOLDE/REX/MINIBALL/CD set-up to perform a Coulomb Excitation experiment with a $^{88}$Kr radioactive beam. The motivation includes a search for $Mixed$ $Symmetry$ states predicted by the IBM-2 model, gathering more spectroscopy data about the $^{88}$Kr nucleus and extending shape coexistence studies (performed previously by the proposers for neutron-deficient Kr isotopes) to the neutron-rich side. The proposed experiment will provide data complementary to the Coulomb Excitation of a relativistic $^{88}$Kr beam proposed by D. Tonev et al. for a RISING experiment. A total of 12 days of beam time is necessary for the experiment, equally divided into two runs. One run with a 2.2 MeV/A beam energy on a $^{48}$Ti target and a second run with the maximum available REX energy of 3.1 MeV/A on a $^{208}$Pb target are requested. Using either a UC$_{x}$ or ThC$_{x}$ fissioning primary target coupled with a plasma source by a cooled transfer line seems to be the best choice for the proposed experime...
International Nuclear Information System (INIS)
Poirier, M.
1997-01-01
Though one would expect that large-angular momentum doubly excited states exhibit weak electronic correlations, it is shown in this paper that a first-order perturbation theory ignoring such correlations may completely fail in predicting correct autoionization probabilities: quadrupolar transitions are poorly described by lowest-order perturbation theory, except for very large angular momenta. Inclusion of second-order dipole-dipole term considerably improves the accuracy of the method. This effect is computed using Coulomb Green's function in its analytical form, probably applied here for the first time to autoionization processes. Examples are given in barium for 5d j 5g [k[ states (j=3/2, 5/2) and for 5d 5/2 nl [k[ states with l > 4. (orig.)
International Nuclear Information System (INIS)
Guichard, R.
2007-12-01
We present a theoretical approach using Coulomb-Volkov states that appears useful for the study of atomic multi-photonic processes induced by intense XUV femtosecond laser pulses. It predicts hydrogen ionization spectra when it is irradiated by laser pulses in perturbations conditions. Three ways have been investigated. Extension to strong fields when ℎω > I p : it requires to include the hydrogen ground state population, introducing it in standard Coulomb-Volkov amplitude leads to saturated multi-photonic ionization. Extension to multi-photonic transitions with ℎω p : new quantum paths are open by the possibility to excite the lower hydrogen bound states. Multiphoton excitation of these states is investigated using a Coulomb-Volkov approach. Extension to helium: two-photon double ionization study shows the influence of electronic correlations in both ground and final state. Huge quantity of information such as angular and energetic distributions as well as total cross sections is available. (author)
Coulomb excitation of radioactive 20, 21Na
Schumaker, M. A.; Cline, D.; Hackman, G.; Pearson, C.; Svensson, C. E.; Wu, C. Y.; Andreyev, A.; Austin, R. A. E.; Ball, G. C.; Bandyopadhyay, D.; Becker, J. A.; Boston, A. J.; Boston, H. C.; Buchmann, L.; Churchman, R.; Cifarelli, F.; Cooper, R. J.; Cross, D. S.; Dashdorj, D.; Demand, G. A.; Dimmock, M. R.; Drake, T. E.; Finlay, P.; Gallant, A. T.; Garrett, P. E.; Green, K. L.; Grint, A. N.; Grinyer, G. F.; Harkness, L. J.; Hayes, A. B.; Kanungo, R.; Lisetskiy, A. F.; Leach, K. G.; Lee, G.; Maharaj, R.; Martin, J.-P.; Moisan, F.; Morton, A. C.; Mythili, S.; Nelson, L.; Newman, O.; Nolan, P. J.; Orce, J. N.; Padilla-Rodal, E.; Phillips, A. A.; Porter-Peden, M.; Ressler, J. J.; Roy, R.; Ruiz, C.; Sarazin, F.; Scraggs, D. P.; Waddington, J. C.; Wan, J. M.; Whitbeck, A.; Williams, S. J.; Wong, J.
2009-12-01
The low-energy structures of the radioactive nuclei 20, 21Na have been examined using Coulomb excitation at the TRIUMF-ISAC radioactive ion beam facility. Beams of ˜ 5×106 ions/s were accelerated to 1.7MeV/A and Coulomb excited in a 0.5mg/cm^2 natTi target. Two TIGRESS HPGe clover detectors perpendicular to the beam axis were used for γ -ray detection, while scattered nuclei were observed by the Si detector BAMBINO. For 21Na , Coulomb excitation from the 3/2+ ground state to the first excited 5/2+ state was observed, while for 20Na , Coulomb excitation was observed from the 2+ ground state to the first excited 3+ and 4+ states. For both beams, B ( λ L) values were determined using the 2+ rightarrow 0+ de-excitation in 48Ti as a reference. The resulting B( E2) ↓ value for 21Na is 137±9 e^2fm^4, while the resulting B( λ L) ↓ values for 20Na are 55±6 e^2fm^4 for the 3+ rightarrow 2+ , 35.7±5.7 e^2 fm^4 for the 4+ rightarrow 2+ , and 0.154±0.030 μ_ N^2 for the 4+ rightarrow 3+ transitions. This analysis significantly improves the measurement of the 21Na B( E2) value, and provides the first experimental determination of B( λ L) values for the proton dripline nucleus 20Na .-1
Coulomb excitation of radioactive {sup 79}Pb
Energy Technology Data Exchange (ETDEWEB)
Lister, C.J.; Blumenthal, D.; Davids, C.N. [and others
1995-08-01
The technical challenges expected in experiments with radioactive beams can already be explored by using ions produced in primary reactions. In addition, the re-excitation of these ions by Coulomb excitation allows a sensitive search for collective states that are well above the yrast line. We are building an experiment to study Coulomb excitation of radioactive ions which are separated from beam particles by the Fragment Mass Analyzer. An array of gamma detectors will be mounted at the focal plane to measure the gamma radiation following re-excitation. Five Compton-suppressed Ge detectors and five planar LEPS detectors will be used. The optimum experiment of this type appears to be the study of {sup 79}Rb following the {sup 24}Mg ({sup 58}Ni,3p) reaction. We calculate that about 5 x 10{sup 5} {sup 79}Rb nuclei/second will reach the excitation foil. This rubidium isotope was selected for study as it is strongly produced and is highly deformed, so easily re-excited. The use of a {sup 58}Ni re-excitation foil offers the best yields. After re-excitation the ions will be subsequently transported into a shielded beamdump to prevent the accumulation of activity.
It is proposed to investigate the structure of excited states in $^{68, 70}$Ni(Z =28, N=40, 42) via the measurement of electromagnetic matrix elements in a Coulomb excitation experiment in order to study the N = 40 harmonic-oscillator shell and the Z = 28 proton shell closures. The measured B(E2) values connecting low-lying 0$^{+}$ and 2$^{+}$ can be compared to shell-model predictions. It is also proposed to perform the one-neutron transfer reaction ${d}$($^{68}$Ni,$^{69}$Ni)${p}$, with the aim of populating excited states in $^{69}$Ni. Comparisons with the states populated in the recently performed ${d}$($^{66}$Ni,$^{67}$Ni)${p}$ reaction will be useful in determining the role of the neutron $d_{5/2}$ orbital in the semi-magic properties of $^{68}$Ni.
Coulomb excitation of {sup 8}Li
Energy Technology Data Exchange (ETDEWEB)
Assuncao, Marlete; Britos, Tatiane Nassar [Universidade Federal de Sao Paulo (UNIFESP), SP (Brazil). Dept. de Ciencias Exatas e da Terra; Descouvemont, Pierre [Universite Libre de Bruxelles (ULB), Brussels (Belgium). Physique Nucleaire Theorique et Physique Mathematique; Lepine-Szily, Alinka; Lichtenthaler Filho, Rubens; Barioni, Adriana; Silva, Diego Medeiros da; Pereira, Dirceu; Mendes Junior, Djalma Rosa; Pires, Kelly Cristina Cezaretto; Gasques, Leandro Romero; Morais, Maria Carmen; Added, Nemitala; Neto Faria, Pedro; Rec, Rafael [Universidade de Sao Paulo (IF/USP), SP (Brazil). Inst. de Fisica. Dept. de Fisica Nuclear
2012-07-01
Full text: This work shows the Coulomb Excitation of {sup 8}Li on targets that have effectively behavior of Rutherford in angles and energies of interest for determining the value of the B(E2) electromagnetic transition. Theoretical aspects involved in this type of measure, known as COULEX [1], and some results in the literature [2-3] will be presented. Some problems with the targets and measurement system while performing an experiment on Coulomb Excitation of {sup 8}Li will be discussed: the energy resolution, background, possible contributions of the primary beam and also the excited states of the target near the region of elastic and inelastic peaks. They will be illustrated by measurements of the Coulomb Excitation of {sup 8}Li on targets of {sup 197}Au and {sup 208}Pb using the system RIBRAS(Brazilian Radioactive Ion Beam). In this case, the {sup 8}Li beam(T{sub 1/2} = 838 ms)is produced by {sup 9}Be({sup 7}Li;{sup 8} Li){sup 8}Be reaction from RIBRAS system which is installed at Instituto de Fisica of the Universidade de Sao Paulo. The primary {sup 7L}i beam is provided by Pelletron Accelerator. [1] K. Alder and A. Winther, Electromagnetic Excitation, North-Holland, New York, 1975; [2] P. Descouvemont and D. Baye, Phys. Letts. B 292, 235-238, 1992; [3] J. A. Brown, F. D. Becchetti, J. W. Jaenecke, K, Ashktorab, and D. A. Roberts, J. J. Kolata, R. J. Smith, and K. Lamkin, R. E. Warner, Phys. Rev. Letts., 66, 19, 1991; [4] R. J. Smith, J. J Kolata, K. Lamkin and A. Morsard, F. D. Becchetti, J. A. Brown, W. Z. Liu, J. W. Jaenecke, and D. A. Roberts, R. E. Warner, Phys. Rev. C, 43, 5, 1991. (author)
Cold transfer between deformed, Coulomb excited nuclei
International Nuclear Information System (INIS)
Bauer, H.
1998-01-01
The scattering system 162 Dy → 116 Sn has been examined at energies in the vicinity of the Coulomb barrier using the Heidelberg-Darmstadt Crystal Ball spectrometer combined with 5 Germanium-CLUSTER detectors. In order to study pairing correlations as a function of angular momentum cold events were selected in the 2n stripping channel by identifying and suppressing the dominant hot part of the transfer with the Crystal Ball. The CLUSTER detectors with their high γ-efficiency were used to identify the transfer channel and to resolve individual final states. Cross sections for the population of individual yrast states in a cold transfer reaction have been measured for the first time indicating the strong influence of higher transfer multipolarities. At small surface distances Coulomb-nuclear interferences were found to be responsible for the stronger decline of the population of higher yrast states in the transfer channel as compared to the Coulex channel. As a preparatory study for 2n transfer measurements between high spin yrast states in the backbending region of deformed nuclei the Coulomb excitation process in the crossing region of two bands in 162 Dy has been analyzed. The gross properties of the measured population probabilities could be interpreted in a simple band mixing model. (orig.)
Coulomb excitation of {sup 123}Cd
Energy Technology Data Exchange (ETDEWEB)
Hartig, Anna-Lena; Kroell, Thorsten; Ilieva, Stoyanka; Boenig, Sabine; Thuerauf, Michael [IKP, TU Darmstadt (Germany); Simpson, Gary; Drouet, Floriane; Ramdhane, Mourad [LPSC, Grenoble (France); Georgiev, Georgi [CSNSM, Orsay (France); Kesteloot, Nele; Wrzosek-Lipska, Kasia [KU, Leuven (Belgium); Jungclaus, Andrea; Illana Sison, Andres [CSIC, Madrid (Spain); Balabanski, Dimiter [INRNE-BAS, Sofia (Bulgaria); Warr, Nigel [Koeln Univ. (Germany). IKP; Voulot, Didier; Wenander, Fredrik; Marsh, Bruce [CERN, Geneva (Switzerland)
2013-07-01
On the neutron-rich side of the valley of stability in the vicinity of the double magic nucleus {sup 132}Sn one can find the {sup 123}Cd isotope. Surprisingly the neutron-rich even-A Cd isotopes in this region are showing signs of collectivity beyond that calculated by modern shell-model predictions. In order to gain a deeper insight in this phenomenon we started to extend these studies to odd-A Cd isotopes. As first isotope the exotic nucleus {sup 123}Cd was produced for safe Coulomb excitation by the ISOLDE facility at CERN and post-accelerated by REX-ISOLDE. The γ-decay from excited states was detected with the MINIBALL array. A report on the status of the ongoing analysis is given.
Coulomb excitation of {sup 107}Sn
Energy Technology Data Exchange (ETDEWEB)
DiJulio, D.D.; Cederkall, J.; Fahlander, C. [Lund University, Physics Department, 118, Lund (Sweden); Ekstroem, A. [University of Oslo, Department of Physics and Center of Mathematics for Applications, Oslo (Norway); Hjorth-Jensen, M. [University of Oslo, Department of Physics and Center of Mathematics for Applications, Oslo (Norway); Michigan State University, National Superconducting Cyclotron Laboratory and Department of Physics and Astronomy, East Lansing, MI (United States); Albers, M.; Blazhev, A.; Fransen, C.; Geibel, K.; Hess, H.; Reiter, P.; Seidlitz, M.; Taprogge, J.; Warr, N. [University of Cologne, Institute of Nuclear Physics, Cologne (Germany); Bildstein, V.; Gernhaeuser, R.; Wimmer, K. [Technische Universitaet Muenchen, Physik Department E12, Garching (Germany); Darby, I.; Witte, H. de [Instituut voor Kern- en Stralingsfysica, Leuven (Belgium); Davinson, T. [University of Edinburgh, Department of Physics and Astronomy, Edinburgh (United Kingdom); Diriken, J. [Instituut voor Kern- en Stralingsfysica, Leuven (Belgium); Studiecentrum voor Kernenergie/Centre d' Etude de l' energie Nucleaire (SCK CEN), Mol (Belgium); Goergen, A.; Siem, S.; Tveten, G.M. [University of Oslo, Department of Physics, Oslo (Norway); Iwanicki, J. [University of Warsaw, Heavy Ion Laboratory, Warsaw (Poland); Lutter, R. [Ludwig-Maximilians-Universitaet Muenchen, Fakultaet fuer Physik, Garching (Germany); Scheck, M. [University of Liverpool, Oliver Lodge Laboratory, Liverpool (United Kingdom); Walle, J.V. de [PH Department, Geneva 23 (Switzerland); Voulot, D.; Wenander, F. [AB Department, Geneva 23 (Switzerland)
2012-07-15
The radioactive isotope {sup 107}Sn was studied using Coulomb excitation at the REX-ISOLDE facility at CERN. This is the lightest odd-Sn nucleus examined using this technique. The reduced transition probability of the lowest-lying 3/2{sup +} state was measured and is compared to shell-model predictions based on several sets of single-neutron energies relative to {sup 100}Sn. Similar to the transition probabilities for the 2{sup +} states in the neutron-deficient even-even Sn nuclei, the measured value is underestimated by shell-model calculations. Part of the strength may be recovered by considering the ordering of the d{sub 5/2} and g{sub 7/2} single-neutron states. (orig.)
Hyperon excitation in nuclear coulomb field
International Nuclear Information System (INIS)
Vanyashin, A.V.; Nikitin, Yu.P.; Shan'gin, A.A.
1981-01-01
A possibility is studied to measure radiative decay partial widths from the 3/2 + decuplet hyperon resonances by means of the Coulomb excitation method of the octet hyperons. The expected contributions from the strong and electromagnetic interactions in the coherence range to the hyperon excitation cross sections on heavy nuclei and on the 4 He nucleus are estimated. The particle angular distributions in the reactions Σ-+A→Σ-(1385)+A and Λ+A→Σ 0 (1385)+A are analysed in order to determine the energy range where the background conditions are the most favorable to extract the electromagnetic mechanism of the hyperon excitation [ru
Exclusion of nuclear forces in heavy-ion Coulomb excitation and Coulomb fission experiments
International Nuclear Information System (INIS)
Neese, R.E.; Guidry, M.W.
1982-01-01
A simple prescription for estimating the energy at which nuclear forces begin to play a role in heavy-ion Coulomb excitation and Coulomb fission experiments is presented. The method differs from most commonly used recipes in accounting for projectile and target nucleus deformation effects. Using a single adjustable parameter the formula reproduces the energy for the onset of Coulomb-nuclear interference effects for a broad range of heavy-ion systems. It is suggested that most Coulomb fission experiments which have been done involve both Coulomb and nuclear excitation processes and should more properly be termed Coulomb-nuclear fission experiments
Coulomb excitation of the proton-dripline nucleus Na20
Schumaker, M. A.; Cline, D.; Hackman, G.; Pearson, C. J.; Svensson, C. E.; Wu, C. Y.; Andreyev, A.; Austin, R. A. E.; Ball, G. C.; Bandyopadhyay, D.; Becker, J. A.; Boston, A. J.; Boston, H. C.; Buchmann, L.; Churchman, R.; Cifarelli, F.; Cooper, R. J.; Cross, D. S.; Dashdorj, D.; Demand, G. A.; Dimmock, M. R.; Drake, T. E.; Finlay, P.; Gallant, A. T.; Garrett, P. E.; Green, K. L.; Grint, A. N.; Grinyer, G. F.; Harkness, L. J.; Hayes, A. B.; Kanungo, R.; Lisetskiy, A. F.; Leach, K. G.; Lee, G.; Maharaj, R.; Martin, J.-P.; Moisan, F.; Morton, A. C.; Mythili, S.; Nelson, L.; Newman, O.; Nolan, P. J.; Orce, J. N.; Padilla-Rodal, E.; Phillips, A. A.; Porter-Peden, M.; Ressler, J. J.; Roy, R.; Ruiz, C.; Sarazin, F.; Scraggs, D. P.; Waddington, J. C.; Wan, J. M.; Whitbeck, A.; Williams, S. J.; Wong, J.
2009-10-01
The low-energy structure of the proton dripline nucleus Na20 has been studied using Coulomb excitation at the TRIUMF-ISAC radioactive ion beam facility. A 1.7-MeV/nucleon Na20 beam of ~5×106 ions/s was Coulomb excited by a 0.5-mg/cm2natTi target. Scattered beam and target particles were detected by the BAMBINO segmented Si detector while γ rays were detected by two TIGRESS HPGe clover detectors set perpendicular to the beam axis. Coulomb excitation from the 2+ ground state to the first excited 3+ and 4+ states was observed, and B(λL) values were determined using the 2+→0+ de-excitation in Ti48 as a reference. The resulting B(λL)↓ values are B(E2;3+→2+)=55±6e2fm4 (17.0±1.9 W.u.), B(E2;4+→2+)=35.7±5.7e2fm4 (11.1±1.8 W.u.), and B(M1;4+→3+)=0.154±0.030μN2 (0.086±0.017 W.u.). These measurements provide the first experimental determination of B(λL) values for this proton dripline nucleus of astrophysical interest.
Relativistic Coulomb excitation of giant resonances in the hydrodynamic model
International Nuclear Information System (INIS)
Vasconcellos Gomes, Ana Cristina de.
1990-05-01
We investigate the Coulomb excitation of giant dipole resonances in relativistic heavy ion collisions using a macroscopic hydrodynamical model for the harmonic vibrations of the nuclear fluid. The motion is treated as a combination of the Goldhaber-Teller displacement mode and the Steinwedel-Jensen acoustic mode, and the restoring forces are calculated using the droplet model. This model is used as input to study the characteristics of multiple excitation of giant dipole resonances in nuclei. Possible signatures for the existence of such states are also discussed quantitatively. (author). 52 refs., 14 figs., 3 tabs
Coulomb Excitation of the N = 50 nucleus 80Zn
International Nuclear Information System (INIS)
Van de Walle, J.; Cocolios, T. E.; Huyse, M.; Ivanov, O.; Mayet, P.; Raabe, R.; Sawicka, M.; Stefanescu, I.; Duppen, P. van; Aksouh, F.; Ames, F.; Habs, D.; Lutter, R.; Behrens, T.; Gernhauser, R.; Kroell, T.; Kruecken, R.; Bildstein, V.; Blazhev, A.; Eberth, J.
2008-01-01
Neutron rich Zinc isotopes, including the N = 50 nucleus 80 Zn, were produced and post-accelerated at the Radioactive Ion Beam (RIB) facility REX-ISOLDE (CERN). Low-energy Coulomb excitation was induced on these isotopes after post-acceleration, yielding B(E2) strengths to the first excited 2 + states. For the first time, an excited state in 80 Zn was observed and the 2 1 + state in 78 Zn was established. The measured B(E2,2 1 + →0 1 + ) values are compared to two sets of large scale shell model calculations. Both calculations reproduce the observed B(E2) systematics for the full Zinc isotopic chain. The results for N = 50 isotones indicate a good N = 50 shell closure and a strong Z = 28 proton core polarization. The new results serve as benchmarks to establish theoretical models, predicting the nuclear properties of the doubly magic nucleus 78 Ni
Unsafe Coulomb excitation of $^{240-244}Pu$
Wiedenhöver, I; Hackman, L; Ahmad, I; Greene, J P; Amro, H; Carpenter, M P; Nisius, D T; Reiter, P; Lauritsen, T; Lister, C J; Khoo, T L; Siem, S; Cizewski, J A; Seweryniak, D; Uusitalo, J; Macchiavelli, A O; Chowdhury, P; Seabury, E H; Cline, D; Wu, C Y
1999-01-01
The high spin states of /sup 240/Pu and /sup 244/Pu have been investigated with GAMMASPHERE at ATLAS, using Coulomb excitation with a /sup 208/Pb beam at energies above the Coulomb barrier. Data on a transfer channel leading to /sup 242/Pu were obtained as well. In the case of /sup 244/Pu, the yrast band was extended to 34h(cross), revealing the completed pi i/sub 13/2/ alignment, a "first" for actinide nuclei. The yrast sequence of /sup 242/Pu was also extended to higher spin and a similar backbend was delineated. In contrast, while the ground state band of /sup 240/Pu was measured up to the highest rotational frequencies ever reported in the actinide region (~300 keV), no sign of particle alignment was observed. (11 refs).
Energy Technology Data Exchange (ETDEWEB)
Guichard, R
2007-12-15
We present a theoretical approach using Coulomb-Volkov states that appears useful for the study of atomic multi-photonic processes induced by intense XUV femtosecond laser pulses. It predicts hydrogen ionization spectra when it is irradiated by laser pulses in perturbations conditions. Three ways have been investigated. Extension to strong fields when {Dirac_h}{omega} > I{sub p}: it requires to include the hydrogen ground state population, introducing it in standard Coulomb-Volkov amplitude leads to saturated multi-photonic ionization. Extension to multi-photonic transitions with {Dirac_h}{omega} < I{sub p}: new quantum paths are open by the possibility to excite the lower hydrogen bound states. Multiphoton excitation of these states is investigated using a Coulomb-Volkov approach. Extension to helium: two-photon double ionization study shows the influence of electronic correlations in both ground and final state. Huge quantity of information such as angular and energetic distributions as well as total cross sections is available. (author)
Energy Technology Data Exchange (ETDEWEB)
Guichard, R
2007-12-15
We present a theoretical approach using Coulomb-Volkov states that appears useful for the study of atomic multi-photonic processes induced by intense XUV femtosecond laser pulses. It predicts hydrogen ionization spectra when it is irradiated by laser pulses in perturbations conditions. Three ways have been investigated. Extension to strong fields when {Dirac_h}{omega} > I{sub p}: it requires to include the hydrogen ground state population, introducing it in standard Coulomb-Volkov amplitude leads to saturated multi-photonic ionization. Extension to multi-photonic transitions with {Dirac_h}{omega} < I{sub p}: new quantum paths are open by the possibility to excite the lower hydrogen bound states. Multiphoton excitation of these states is investigated using a Coulomb-Volkov approach. Extension to helium: two-photon double ionization study shows the influence of electronic correlations in both ground and final state. Huge quantity of information such as angular and energetic distributions as well as total cross sections is available. (author)
Coulomb excitation of $^{110}$Sn using REX-ISOLDE
Ekström, A; Hurst, A; Fahlander, C; Banu, A; Butler, P; Eberth, J; Górska, M; Habs, D; Huyse, M; Kester, O; Niedermayer, O; Nilsson, T; Pantea, M; Scheit, H; Schwalm, D; Sletten, G; Ushasi, D P; Van Duppen, P; Warr, N; Weisshaar, D
2006-01-01
In this paper, we report the preliminary result from the first Coulomb excitation experiment at REX-ISOLDE (Habs et al 1998 Nucl. Instrum. Methods B 139 128) using neutron-deficient Sn-beams. The motivation of the experiment is to deduce the reduced transition probability, B(E2 ; 2$^+\\rightarrow$ 0$^+$) , for the sequence of neutron deficient, unstable, even-even Sn-isotopes from using a radioactive beam opens up a new path to study the lifetime of the first excited 2$^+$ state in these isotopes. The de-excitation path following fusion-evaporation reactions will for the even-even Sn isotopes pass via an isomeric 6$^+$ state, located at higher energy, which thus hampers measurements of the lifetime of the first excited state using, e.g., recoil-distance methods. For this reason the reduced transition probability of the first excited 2$^+$ state has remained unknown in this chain of isotopes although the B(E2) value of the stable isotope $^{112}$Sn was measured approximately 30 years ago (see, e.g., Stelson et...
Lim, Edward C
1974-01-01
Excited States, Volume I reviews radiationless transitions, phosphorescence microwave double resonance through optical spectra in molecular solids, dipole moments in excited states, luminescence of polar molecules, and the problem of interstate interaction in aromatic carbonyl compounds. The book discusses the molecular electronic radiationless transitions; the double resonance techniques and the relaxation mechanisms involving the lowest triplet state of aromatic compounds; as well as the optical spectra and relaxation in molecular solids. The text also describes dipole moments and polarizab
Coulomb and nuclear excitations of narrow resonances in 17Ne
Directory of Open Access Journals (Sweden)
J. Marganiec
2016-08-01
Full Text Available New experimental data for dissociation of relativistic 17Ne projectiles incident on targets of lead, carbon, and polyethylene targets at GSI are presented. Special attention is paid to the excitation and decay of narrow resonant states in 17Ne. Distributions of internal energy in the O15+p+p three-body system have been determined together with angular and partial-energy correlations between the decay products in different energy regions. The analysis was done using existing experimental data on 17Ne and its mirror nucleus 17N. The isobaric multiplet mass equation is used for assignment of observed resonances and their spins and parities. A combination of data from the heavy and light targets yielded cross sections and transition probabilities for the Coulomb excitations of the narrow resonant states. The resulting transition probabilities provide information relevant for a better understanding of the 17Ne structure.
Vibrational motions in rotating nuclei studied by Coulomb excitations
Energy Technology Data Exchange (ETDEWEB)
Shimizu, Yoshifumi R [Kyushu Univ., Fukuoka (Japan). Dept. of Physics
1998-03-01
As is well-known Coulomb excitation is an excellent tool to study the nuclear collective motions. Especially the vibrational excitations in rotating nuclei, which are rather difficult to access by usual heavy-ion fusion reactions, can be investigated in detail. Combined with the famous 8{pi}-Spectrometer, which was one of the best {gamma}-ray detector and had discovered some of superdeformed bands, such Coulomb excitation experiments had been carried out at Chalk River laboratory just before it`s shutdown of physics division. In this meeting some of the experimental data are presented and compared with the results of theoretical investigations. (author)
The giant-dipole-resonance effect in coulomb excitation of 10B
International Nuclear Information System (INIS)
Vermeer, W.J.; Zabel, T.H.; Esat, M.T.; Kuehner, J.A.; Spear, R.H.; Baxter, A.M.
1982-04-01
Coulomb excitation of the 0.718-MeV, Jsup(π) = 1 + , first excited state of 10 B has been studied using projectile excitation by 208 Pb and observing the backward scattered particles. The results give a clear indication of the virtual excitation of the giant dipole resonance as a second-order effect. The observed magnitude is consistent with the usual hydrodynamic model estimate and with a recent shell-model calculation
Coulomb excitation of atoms by fast multicharged ions
International Nuclear Information System (INIS)
Yudin, G.L.
1980-01-01
Investigated is coulomb eXcitation of discrete levels of a hydrogen-like atom by a fast multicharged ion. Obtained are dependences of probabilities of channels 1S→nS and 1S→nP on the sight parameter in the zero order of sudden excitation theory. 1S-2S transition is considered in detail. Carried out are calculations for excitation of the hydrogen atom by the wholy bare carbon atom. It is shown, that at low values of excitation pr.ocess parameter eta excitation probability is a monotonously decreasing function of the impact parameter. With the growth of eta the situation is changed, and at low impact parameters the probability of 1S-2S transition is decreased. At high impact parameters approximation of sudden excitations is unacceptable, here lagging of coulomb interaction is essential
Unsafe Coulomb excitation of 240-244Pu
International Nuclear Information System (INIS)
Ahmad, I.; Amro, H.; Carpenter, M. P.; Chowdhury, P.; Cizewski, J.; Cline, D.; Greene, J. P.; Hackman, G.; Janssens, R. V. F.; Khoo, T. L.; Lauritsen, T.; Lister, C. J.; Macchiavelli, A. O.; Nisius, D. T.; Reiter, P.; Seabury, E. H.; Seweryniak, D.; Siem, S.; Uusitalo, J.; Wiedenhoever, I.; Wu, C. Y.
1999-01-01
The high spin states of 240 Pu and 244 Pu have been investigated with GAMMASPHERE at ATLAS, using Coulomb excitation with a 208 Pb beam at energies above the Coulomb barrier. Data on a transfer channel leading to 242 Pu were obtained as well. In the case of 244 Pu, the yrast band was extended to 34h b ar revealing the completed πi 13/2 alignment, a ''first'' for actinide nuclei. The yrast sequence of 242 Pu was also extended to higher spin and a similar backbend was delineated. In contrast, while the ground state band of 240 Pu was measured up to the highest rotational frequencies ever reported in the actinide region (approximately300 keV), no sign of particle alignment was observed. In this case, several observable such as the large B(E1)/B(E2) branching ratios in the negative parity band, and the vanishing energy staggering between the negative and positive parity bands suggest that the strength of octupole correlations increases with rotational frequency. These stronger correlations may well be responsible for delaying or suppressing the πi 13/2 particle alignment
Plunger lifetime measurements after Coulomb excitation at intermediate beam energies
Energy Technology Data Exchange (ETDEWEB)
Hackstein, Matthias; Dewald, Alfred; Fransen, Christoph; Ilie, Gabriela; Jolie, Jan; Melon, Barbara; Pissulla, Thomas; Rother, Wolfram; Zell, Karl-Oskar [University of Cologne (Germany); Petkov, Pavel [University of Cologne (Germany); INRNE (Bulgaria); Chester, Aaron; Adrich, Przemyslaw; Bazin, Daniel; Bowen, Matt; Gade, Alexandra; Glasmacher, Thomas; Miller, Dave; Moeller, Victoria; Starosta, Krzysztof; Stolz, Andreas; Vaman, Constantin; Voss, Philip; Weissharr, Dirk [Michigan State Univerity (United States); Moeller, Oliver [TU Darmstadt (Germany)
2008-07-01
Two recoil-distance-doppler-shift (RDDS) experiments were performed at the NSCL/MSU using Coulomb excitations of the projectile nuclei {sup 110}Pd, {sup 114}Pd at beam energies of 54 MeV/u in order to investigate the evolution of deformation of neutron rich paladium isotopes. The experimental set-up consisted of a dedicated plunger device, developed at the University of Cologne, the SEGA Ge-array and the S800 spectrometer. Lifetimes of the 2{sub 1}{sup +}-states in {sup 110}Pd and {sup 114}Pd were derived from the analysis of the {gamma}-line-shapes as well as from the measured decay-curves. Special features of the data analysis, e.g. features originating from the very high recoil velocities, are discussed.
Shape determination in Coulomb excitation of $^{72}$Kr
Reiter, P; Kruecken, R; Paul, E S; Wadsworth, R; Heenen, P
Nuclei with oblate shapes at low spins are very special in nature because of their rarity. Both theoretical and experimental shape co-existence studies in the mass 70 region for near proton drip-line nuclei suggest $^{72}$Kr to be the unique case with oblate low-lying and prolate high-lying levels. However, there is no direct experimental evidence in the literature to date for the oblate nature predicted for the first 2$^+$ state in $^{72}$Kr. We propose to determine the sign of the spectroscopic quadrupole moment of this state via the re-orientation effect in a low-energy Coulomb excitation measurement. In the inelastic excitation of the 2$^+$ state in $^{72}$Kr beam of 3.1 MeV/u with an intensity of 800 pps at REX-ISOLDE impinging on $^{104}$Pd target, the re-orientation effect plays a significant role. The cross section measurement for the 2$^+$ state should thus allow the model-independent determination of the sign of the quadrupole moment unambiguously and will shed light on the co-existing prolate and o...
Semiclassical treatment of nuclear effects in Coulomb excitation
Energy Technology Data Exchange (ETDEWEB)
Canto, L F; Donangelo, R [Universidade Federal do Rio de Janeiro, RJ (Brazil). Inst. de Fisica; Rasmussen, J O; Ring, P; Stoyer, M A [Lawrence Berkeley Lab., CA (USA). Nuclear Science Div.
1990-09-27
We introduce the effects of the nuclear potential in the semiclassical Alder-Winther-de Boer method, both in the coupling matrix elements and as corrections to the Rutherford orbit. We compare our results to those of pure Coulomb excitation and to coupled-channel calculations. (orig.).
Study of the N=40 shell by using Coulomb excitation
International Nuclear Information System (INIS)
Leenhardt, St.
2000-01-01
Two Coulomb excitation experiments on neutron rich exotic nuclei have been performed at GANIL. They allowed the measurement of the reduced transition probability B(E2) (from ground state to first excited state) of some nuclei around N = 40. This number, 40, is a half-magic number in the shell model. For nuclei with an important neutron excess, it is predicted that the shell closure is stronger at N = 40. The B(E2) is a good tool for testing this growing. We have measured, by using the LISE3 spectrometer and a γ multidetector, B(E2) of 68 Ni, 66 Ni and 72 Zn, unknown till now. We have used for the first time segmented germanium 'clovers' detector, for photon detection (v/c∼0.3). Results confirm the strong shell effect for 68 Ni. Indeed 68 Ni was shown to be the Nickel isotope with the lowest value of B(E2), and hence the most rigid isotope. Nevertheless it seems that the shell effect at N = 40 decreases rapidly, for other isotopes very close to 68 Ni(Z = 28) and N = 40). (authors)
Probing shape coexistence in neutron-deficient $^{72}$Se via low-energy Coulomb excitation
We propose to study the evolution of nuclear structure in neutron-deficient $^{72}$Se by performing a low-energy Coulomb excitation measurement. Matrix elements will be determined for low-lying excited states allowing for a full comparison with theoretical predictions. Furthermore, the intrinsic shape of the ground state, and the second 0$^{+}$ state, will be investigated using the quadrupole sum rules method.
Coulomb excitation of 206Hg at relativistic energies
Alexander, Tom
The region of the nuclear chart surrounding the doubly-magic nucleus 208Pb provides a key area to constrain and develop contemporary nuclear structure models. One aspect of particular interest is the transition strength of the first excited 2+ state in even-even nuclei; this work describes the measurement of this value for the case of 206Hg, where the Z=80 line meets the N=126 shell closure. The nuclei of interest were synthesized using relativistic-energy projectile fragmentation at the GSI facility in Germany. They were produced in the fragmentation of a primary 208Pb beam at an energy of 1 GeV per nucleon, and separated and identifed using the Fragment Separator. The secondary beams with an energy of 140 MeV per nucleon were Coulomb excited on a secondary target of 400 mg/cm. 2 gold. Gamma-rays were detected with the Advanced GAmma Tracking Array (AGATA). The precise scattering angle for Doppler-correction was determined with position information from the Lund-York-Cologne-CAlorimeter(LYCCA). Using the sophisticated tracking algorithm native to AGATA in conjunction with pulse-shape analysis, a precise Doppler-correction is performed on the gamma spectra, and using a complex n-dimensional analysis, the B(E2) value for 206Hg is extracted relative to the known value also measured in 206Pb. A total of 409 million 206Hg particles were measured, and a cross-section of 50 mb was determined for the 2+ state at 1068 keV. The measurement of the B(E2) transition strength was found to be 1.109 W.u. This result is compared to a number of theoretical calculations, including two Gogny forces, and a modified shell model parametrization and is found to be smaller than all calculated estimations, implying that the first excited 2. + state in . {206}Hg is uncollective in nature.
Prospects for coherently driven nuclear radiation by Coulomb excitation
International Nuclear Information System (INIS)
Karamyan, S.A.; Carroll, J.J.
2006-01-01
Possible experiments are discussed in which the Coulomb excitation of nuclear isomers would be followed by sequential energy release. The possibility of the coherent Coulomb excitation of nuclei ensconced in a crystal by channeled relativistic heavy projectiles is considered. The phase shift between neighbor-nuclei excitations can be identical to the photon phase shift for emission in forward direction. Thus, the elementary string of atoms can radiate coherently with emission of characteristic nuclear γ rays and the intensity of the radiation could be increased due to the summation of amplitudes. The Moessbauer conditions should be important for this new type of collective radiation that could be promising in the context of the γ-lasing problem
Electromagnetic excitation with very heavy ions at and above the Coulomb barrier
International Nuclear Information System (INIS)
Wollersheim, H.J.
1988-08-01
The present report is part of a systematic study of the electromagnetic properties of strongly deformed and shape transitional nuclei carried out at GSI. The high efficiency particle-gamma detector system is described to perform multiple Coulomb excitation experiments with very heavy projectiles. Some results obtained for the shape transitional nucleus 196 Pt will be presented to exemplify the importance of having access to both the level energies and the E2-transition matrix elements when discussing the possible structure of these states. The second part of this paper is devoted to transfer reactions between very heavy nuclei. In contrast to light projectiles heavy ions offer the possibility to study new phenomena which originate in the much larger Coulomb contribution to the total interaction. In particular, heavy deformed nuclei will be Coulomb excited by the strong electromagnetic field to high spin states already at the time when they start interacting through the nuclear forces. The particle transfer therefore takes place mainly between excited collective states and thus should give information about the interplay between single-particle degrees of freedom, pair correlations and collective excitations. In this paper results of experiments will be reported in which nuclei from the rare earth and the actinide region have been bombarded by 206,208 Pb projectiles at incident energies near the Coulomb barrier. (orig./HSI)
Coulomb excitation of neutron-deficient polonium isotopes studied at ISOLDE
Neven, Michiel
The polonium isotopes represent an interesting region of the nuclear chart having only two protons outside the Z = 82 closed shell. These isotopes have already been extensively studied theoretically and experimentally. The heavier isotopes (A > 200) seem to follow a "regular seniority-type regime" while for the lighter isotopes (A < 200) a more collective behavior is observed. Many questions remain regarding the transition between these two regimes and the configuration mixing between quantum states. Experiments in the lighter polonium isotopes point to the presence of shape coexistence, however the phenomenon is not fully understood. A Coulomb excitation study of the polonium isotopes whereby the dynamic properties are investigated can provide helpful insights in understanding the shape coexistence phenomena. In this thesis $^{202}$Po was studied via Coulomb excitation. The $^{202}$Po isotope was part of an experimental campaign in which the $^{196,198,200,206}$Po isotopes were studied as well via Coulomb...
Coulomb Excitation of Neutron Deficient Sn-Isotopes using REX-ISOLDE
Di julio, D D; Kownacki, J M; Marechal, F; Andreoiu, C; Siem, S; Perrot, F; Van duppen, P L E; Napiorkowski, P J; Iwanicki, J S
2002-01-01
It is proposed to study the evolution of the reduced transition probabilities, B(E2; 0$^{+} \\rightarrow$ 2$^{+}$), for neutron deficient Sn isotopes by Coulomb excitation in inverse kinematics using REX-ISOLDE and the MINIBALL detector array. Measurements of the reduced transition matrix element for the transition between the ground state and the first excited 2$^{+}$ state in light even-even Sn isotopes provide a means to study e.g. core polarization effects in the $^{100}$Sn core. Previous attempts to measure this quantity have been carried out using the decay of isomeric states populated in fusion evaporation reactions. We thus propose to utilize the unique opportunity provided by REX-ISOLDE, after the energy upgrade to 3.1 MeV/u, to use the more model-independent approach of Coulomb excitation to measure this quantity in a number of isotopes in this region.
Coulomb excitation of neutron-rich $^{134-136}$Sn isotopes
We propose to study excited states in the isotopes $^{134,136}$Sn by $\\gamma$-ray spectroscopy following "safe" Coulomb excitation. The experiment aims to investigate the evolution of quadrupole collectivity beyond the magic shell closure at N = 82 by the determination of B(E2) values and electric quadrupole moments $\\mathcal{Q}_2$. Recent shell-model calculations using realistic interactions predict possible enhanced collectivity in neutron-rich regions. Evidence for this could be obtained by this experiment. Furthermore, the currently unknown excitation energies of the 2$^+_{1}$ and 4$^+_{1}$ states in $^{136}$Sn will be measured for the first time.
Coulomb excitations for a short linear chain of metallic shells
Energy Technology Data Exchange (ETDEWEB)
Zhemchuzhna, Liubov, E-mail: lzhemchuzhna@unm.edu [Department of Physics and Astronomy, Hunter College of the City University of New York, 695 Park Avenue, New York, New York 10065 (United States); Center for High Technology Materials, University of New Mexico, Albuquerque, New Mexico 87106 (United States); Gumbs, Godfrey [Department of Physics and Astronomy, Hunter College of the City University of New York, 695 Park Avenue, New York, New York 10065 (United States); Donostia International Physics Center (DIPC), P de Manuel Lardizabal, 4, 20018 San Sebastian, Basque Country (Spain); Iurov, Andrii [Center for High Technology Materials, University of New Mexico, Albuquerque, New Mexico 87106 (United States); Huang, Danhong [Air Force Research Laboratory, Space Vehicles Directorate, Kirtland Air Force Base, New Mexico 87117 (United States); Gao, Bo [Department of Physics and Astronomy, Hunter College of the City University of New York, 695 Park Avenue, New York, New York 10065 (United States)
2015-03-15
A self-consistent-field theory is given for the electronic collective modes of a chain containing a finite number, N, of Coulomb-coupled spherical two-dimensional electron gases arranged with their centers along a straight line, for simulating electromagnetic response of a narrow-ribbon of metallic shells. The separation between nearest-neighbor shells is arbitrary and because of the quantization of the electron energy levels due to their confinement to the spherical surface, all angular momenta L of the Coulomb excitations, as well as their projections M on the quantization axis, are coupled. However, for incoming light with a given polarization, only one angular momentum quantum number is usually required. Therefore, the electromagnetic response of the narrow-ribbon of metallic shells is expected to be controlled externally by selecting different polarizations for incident light. We show that, when N = 3, the next-nearest-neighbor Coulomb coupling is larger than its value if they are located at opposite ends of a right-angle triangle forming the triad. Additionally, the frequencies of the plasma excitations are found to depend on the orientation of the line joining them with respect to the axis of quantization since the magnetic field generated from the induced oscillating electric dipole moment on one sphere can couple to the induced magnetic dipole moment on another. Although the transverse inter-shell electromagnetic coupling can be modeled by an effective dynamic medium, the longitudinal inter-shell Coulomb coupling, on the other hand, can still significantly modify the electromagnetic property of this effective medium between shells.
Energy Technology Data Exchange (ETDEWEB)
Hellgartner, Stefanie Christine
2015-11-13
In this work, the N=40 subshell closure is investigated with two complementary methods using a radioactive {sup 72}Zn ISOLDE beam: One- and two-neutron transfer reactions and multiple Coulomb excitation. In the one-neutron transfer reaction, two new levels of {sup 73}Zn were discovered. The two-neutron transfer channel allowed to study the differential cross section of the ground state and the 2{sup +}{sub 1} state of {sup 74}Zn. In the Coulomb excitation experiment, the measured B(E2) values and quadrupole moments of {sup 72}Zn showed that the yrast states 0{sup +}{sub 1}, 2{sup +}{sub 1} and 4{sup +}{sub 1} are moderately collective. Contrary, the 0{sup +}{sub 2} state has a different structure, since it features a stronger closed N=40 configuration compared to the ground state.
JANUS - A setup for low-energy Coulomb excitation at ReA3
Lunderberg, E.; Belarge, J.; Bender, P. C.; Bucher, B.; Cline, D.; Elman, B.; Gade, A.; Liddick, S. N.; Longfellow, B.; Prokop, C.; Weisshaar, D.; Wu, C. Y.
2018-03-01
A new experimental setup for low-energy Coulomb excitation experiments was constructed in a collaboration between the National Superconducting Cyclotron Laboratory (NSCL), Lawrence Livermore National Laboratory (LLNL), and the University of Rochester and was commissioned at the general purpose beam line of NSCL's ReA3 reaccelerator facility. The so-called JANUS setup combines γ-ray detection with the Segmented Ge Array (SeGA) and scattered particle detection using a pair of segmented double-sided Si detectors (Bambino 2). The low-energy Coulomb excitation program that JANUS enables will complement intermediate-energy Coulomb excitation studies that have long been performed at NSCL by providing access to observables that quantify collectivity beyond the first excited state, including the sign and magnitude of excited-state quadrupole moments. In this work, the setup and its performance will be described based on the commissioning run that used stable 78Kr impinging onto a 1.09 mg/cm2208Pb target at a beam energy of 3.9 MeV/u.
Energy Technology Data Exchange (ETDEWEB)
Barloutaud, R [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires
1958-06-15
The following nuclei were excited by protons of 5 MeV maximum energy: {sup 182}W - {sup 184}W - {sup 186}W - {sup 186}Os - {sup 188}Os - {sup 189}Os - {sup 190}Os - {sup 192}Os - {sup 194}Pt - {sup 196}Pt - {sup 198}Pt - {sup 198}Hg - {sup 200}Hg - {sup 202}Hg - {sup 204}Hg - {sup 206}Pb. The reduced probabilities of the various transitions were deduced from the coulomb excitation cross-section measurements. For some even-even nuclei two 2 + levels were excited. The properties of the excited levels are interpreted in terms of the collective model. (author) [French] Au moyen de protons d'energie inferieure a 5 MeV, l'excitation coulombienne des noyaux suivants a ete etudiee: {sup 182}W - {sup 184}W - {sup 186}W - {sup 186}Os - {sup 188}Os - {sup 189}Os - {sup 190}Os - {sup 192}Os - {sup 194}Pt - {sup 196}Pt - {sup 198}Pt - {sup 198}Hg - {sup 200}Hg - {sup 202}Hg - {sup 204}Hg - {sup 206}Pb. La mesure de la section efficace d'excitation coulombienne a permis de deduire les -probabilites reduites des diverses transitions observees. Dans certains noyaux pair-pair, deux niveaux de caractere 2 + ont ete excites. L'interpretation de ces niveaux en termes de niveaux de rotation et de niveaux de vibration a l'aide du modele collectif est discutee. En particulier, la variation des proprietes de ces niveaux avec la deformation nucleaire permet de fixer des limites a la validite des diverses hypotheses entrant dans le modele collectif. (auteur)
Coulomb excitation of the two proton-hole nucleus $^{206}$Hg
We propose to use Coulomb excitation of the single magic two-proton-hole nucleus $^{206}$Hg. In a single-step excitation both the first 2$^{+}$ and the highly collective octupole 3$^{-}$ states will be populated. Thus, information on both quadrupole and octupole collectivity will be gained in this neutron-rich nucleus. Due to the high beam intensity, we will be able to observe multi-step Coulomb excitation as well, providing further test on theoretical calculations. The results will be used to improve the predictive power of the shell model for more exotic nuclei as we move to lighter N=126 nuclei. The experiment will use the new HIE-ISOLDE facility and the MINIBALL array, and will take advantage of the recently developed $^{206}$Hg beam from the molten lead target.
No evidence of reduced collectivity in Coulomb-excited Sn isotopes
Kumar, R.; Saxena, M.; Doornenbal, P.; Jhingan, A.; Banerjee, A.; Bhowmik, R. K.; Dutt, S.; Garg, R.; Joshi, C.; Mishra, V.; Napiorkowski, P. J.; Prajapati, S.; Söderström, P.-A.; Kumar, N.; Wollersheim, H.-J.
2017-11-01
In a series of Coulomb excitation experiments the first excited 2+ states in semimagic Sn 112 ,116 ,118 ,120 ,122 ,124 isotopes were excited using a 58Ni beam at safe Coulomb energy. The B (E 2 ; 0+→2+) values were determined with high precision (˜3 %) relative to 58Ni projectile excitation. These results disagree with previously reported B (E 2 ↑) values [A. Jungclaus et al., Phys. Lett. B 695, 110 (2011)., 10.1016/j.physletb.2010.11.012] extracted from Doppler-shift attenuation lifetime measurements, whereas the reported mass dependence of B (E 2 ↑) values is very similar to a recent Coulomb excitation study [J. M. Allmond et al., Phys. Rev. C 92, 041303(R) (2015), 10.1103/PhysRevC.92.041303]. The stable Sn isotopes, key nuclei in nuclear structure, show no evidence of reduced collectivity and we, thus, reconfirm the nonsymmetric behavior of reduced transition probabilities with respect to the midshell A =116 .
Coulomb excitations of low lying levels in 127I and 197Au
International Nuclear Information System (INIS)
Singh, K.P.; Tayal, D.C.; Hans, H.S.
1988-01-01
The low-lying levels of 127 I and 197 Au were Coulomb excited with 3.54 to 4.2 MeV protons. The reduced quadrupole transition probabilities of the 203, 374.9, 418, 618.4, 628.7, 651.1 and 745.5 keV states of 127 I, and the 268.8, 278.9, 502, and 547.5 keV states of 197 Au was measured from Coulomb excitation by observing the de-excitation gamma rays with a high resolution Ge(Li) detector. The low-energy protons were used for the first time to Coulomb-excite the two levels at 618.4 and 651.1 keV of 127 I and one level at 502 keV of 197 Au. The present experimental results are found in agreement with the existing experimental data except the B(E2) value of the level at 268.8 keV of 197 Au. (author). 4 figs., 4 tabs., 32 refs
Bastin, B; Kruecken, R; Larsen, A; Rahkila, P J; Srebrny, J; Clement, E; Wadsworth, R; Syed naeemul, H; Peura, P J; Siem, S; Hadynska-klek, K; Habs, D; Napiorkowski, P J; Diriken, J V J; Iwanicki, J S
Coulomb excitation measurements to study the shape coexistence and quadrupole collectivity of the low-lying levels in neutron-deficient Pb nuclei are proposed. Even-mass $^{188−192}$Pb nuclei will be post-accelerated at REX-ISOLDE in order to measure transition probabilities and quadrupole moments for the first excited states. In combination with results obtained in lifetime measurements, this will allow the sign of the quadrupole deformation parameter to be extracted for the first time for 2$^{+}$ states in the even-mass $^{188−192}$Pb nuclei.
Coulomb states in atoms and solids
International Nuclear Information System (INIS)
Ortalano, D.M.
1988-05-01
In this dissertation, an empirical quantum defect approach to describe the valence excitons of the rare gas solids is developed. These Coulomb states are of s-symmetry and form a hydrogen-like series which converges to the bottom of the lowest conduction band. A non-zero quantum defect is found for all of the excitons of neon, argon and xenon. For these systems, then, there exists, in addition to the screened Coulombic component, a non-Coulombic component to the total exciton binding energy. The Wannier formalism is, therefore, inappropriate for the excitons of Ne, Ar and Xe. From the sign of the quantum defect, the non-Coulombic potential is repulsive for Ne and Ar, attractive for Xe, and nearly zero for Kr. This is opposite to that for the Rydberg states of the corresponding rare gas atoms, where the non-Coulombic potential between the electron and the cation is attractive for all of the atoms. The excitons then, are not simply perturbed Rydberg states of the corresponding rare gas atoms (i.e., the excitons do not possess atomic parentage). Interatomic term value/band gap energy correlations and reduced term value/reduced band gap correlations were performed. These correlations were exploited to provide further evidence against both the Wannier formalism and the atomic parentage view point. From these correlations, it was also discovered that the non-Coulombic potential varies smoothly across the valence isoelectronic series of solids, and that it becomes more attractive (or less repulsive) in going from neon to xenon. In order to address the atomic parentage controversy, it was necessary to compare the excitons to the low-n Rydberg states of the rare gas atoms. A review of the quantum defect description of the atomic Rydberg states is, therefore, presented. Also, Rydberg term value/ionization energy correlations are discussed and compared with the analogous exciton correlations. 7 refs., 10 figs., 5 tabs
On the sequentiality of the multiple Coulomb-excitation process
International Nuclear Information System (INIS)
Dannhaeuser, G.; Boer, J. de
1978-01-01
This paper describes the results of 'computer experiments' illustrating the meaning of a new concept called 'sequentiality'. This concept applies to processes in which the excitation of a given state is mainly accomplished by a large multiple of steps, and it deals with the question as to what extent a transition close to the ground state occurs before one between the highest excited states. (orig.) [de
Probing core polarization around 78Ni: intermediate energy Coulomb excitation of 74Ni
Directory of Open Access Journals (Sweden)
Marchi T.
2013-12-01
We have recently measured the B(E2; 0+ → 2+ of the 74Ni nucleus in an intermediate-energy Coulomb excitation experiment performed at the National Superconducting Cyclotron Laboratory of the Michigan State University. The 74Ni secondary beam has been produced by fragmentation of 86Kr at 140 AMeV on a thick Be target. Selected radioactive fragments impinged on a secondary 197Au target where the measurement of the emitted γ-rays allows to extract the Coulomb excitation cross section and related structure information. Preliminary B(E2 values do not point towards an enhancement of the transition matrix element and the comparison to what was already measured by Aoi and co-workers in [1] opens new scenarios in the interpretation of the shell evolution of the Z=28 isotopes.
Coulomb Correlations Intertwined with Spin and Orbital Excitations in LaCoO_{3}.
Tomiyasu, K; Okamoto, J; Huang, H Y; Chen, Z Y; Sinaga, E P; Wu, W B; Chu, Y Y; Singh, A; Wang, R-P; de Groot, F M F; Chainani, A; Ishihara, S; Chen, C T; Huang, D J
2017-11-10
We carried out temperature-dependent (20-550 K) measurements of resonant inelastic x-ray scattering on LaCoO_{3} to investigate the evolution of its electronic structure across the spin-state crossover. In combination with charge-transfer multiplet calculations, we accurately quantified the renomalized crystal-field excitation energies and spin-state populations. We show that the screening of the effective on-site Coulomb interaction of 3d electrons is orbital selective and coupled to the spin-state crossover in LaCoO_{3}. The results establish that the gradual spin-state crossover is associated with a relative change of Coulomb energy versus bandwidth, leading to a Mott-type insulator-to-metal transition.
Coulomb excitation of neutron-rich odd-$A$ Cd isotopes
Reiter, P; Kruecken, R; Gernhaeuser, R A; Kroell, T; Leske, J; Marginean, N M
We propose to study excited states in the odd-${A}$ isotopes $^{123,125,127}$Cd by ${\\gamma}$-ray spectroscopy following "safe" Coulomb excitation. The experiment aims to determine the B(E2) values connecting excited states with the ground state as well as the long-lived (11/2$^{-}$) isomer. The proposed study profits from the unique capability of ISOLDE to produce beams containing Cd in the ground state or in the isomeric state. Our recent results on the neutron-rich even-A Cd nuclei appear to show that these nuclei may possess some collectivity beyond that calculated by modern shell-model predictions. Beyond-mean-field calculations also predict these nuclei to be weakly deformed. These facets are surprising considering their proximity to the doubly magic $^{132}$Sn. Coulomb-excitation studies of odd-${A}$ Cd isotopes may give a unique insight into the deformation-driving roles played by different orbits in this region. Such studies of the onset of collectivity become especially important in light of recent...
Enhanced population of side band of {sup 155}Gd in heavy-ion Coulomb excitation
Energy Technology Data Exchange (ETDEWEB)
Oshima, Masumi; Hayakawa, Takehito; Hatsukawa, Yuichi [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment; and others
1998-03-01
In the Coulomb excitation of {sup 155}Gd with heavy projectiles, {sup 32}S, {sup 58}Ni and {sup 90}Zr, unexpectedly large enhancement of a positive-parity side band has been observed. This enhancement could not be reproduced by a Coulomb-excitation calculation taking into account the recommended upper limits of E1 or E3 transitions, which are compiled in the whole mass region, and is proportional to the electric field accomplished in the Coulomb-scattering process. (author)
Testing refined shell-model interactions in the sd shell: Coulomb excitation of Na26
Siebeck, B; Blazhev, A; Reiter, P; Altenkirch, R; Bauer, C; Butler, P A; De Witte, H; Elseviers, J; Gaffney, L P; Hess, H; Huyse, M; Kröll, T; Lutter, R; Pakarinen, J; Pietralla, N; Radeck, F; Scheck, M; Schneiders, D; Sotty, C; Van Duppen, P; Vermeulen, M; Voulot, D; Warr, N; Wenander, F
2015-01-01
Background: Shell-model calculations crucially depend on the residual interaction used to approximate the nucleon-nucleon interaction. Recent improvements to the empirical universal sd interaction (USD) describing nuclei within the sd shell yielded two new interactions—USDA and USDB—causing changes in the theoretical description of these nuclei. Purpose: Transition matrix elements between excited states provide an excellent probe to examine the underlying shell structure. These observables provide a stringent test for the newly derived interactions. The nucleus Na26 with 7 valence neutrons and 3 valence protons outside the doubly-magic 16O core is used as a test case. Method: A radioactive beam experiment with Na26 (T1/2=1,07s) was performed at the REX-ISOLDE facility (CERN) using Coulomb excitation at safe energies below the Coulomb barrier. Scattered particles were detected with an annular Si detector in coincidence with γ rays observed by the segmented MINIBALL array. Coulomb excitation cross sections...
Computer experiments of the time-sequence of individual steps in multiple Coulomb-excitation
International Nuclear Information System (INIS)
Boer, J. de; Dannhaueser, G.
1982-01-01
The way in which the multiple E2 steps in the Coulomb-excitation of a rotational band of a nucleus follow one another is elucidated for selected examples using semiclassical computer experiments. The role a given transition plays for the excitation of a given final state is measured by a quantity named ''importance function''. It is found that these functions, calculated for the highest rotational state, peak at times forming a sequence for the successive E2 transitions starting from the ground state. This sequential behaviour is used to approximately account for the effects on the projectile orbit of the sequential transfer of excitation energy and angular momentum from projectile to target. These orbits lead to similar deflection functions and cross sections as those obtained from a symmetrization procedure approximately accounting for the transfer of angular momentum and energy. (Auth.)
International Nuclear Information System (INIS)
Hoffmann, B.
1984-07-01
In three chapters different physical situations are described which have commonly the Coulomb interaction as driving force. The first two chapters study the Coulomb interactions in connection with the excitation of inner electron shells and the Coulomb excitation of nuclei in first order. In the third part on effect ofthe Coulomb interaction between electronic shell and nucleus is treated in second order (nuclear polarization), and its effect on the isotopic and isomeric shift is studied. (orig./HSI) [de
Coulomb excitation of $^{182-184}$ Hg: Shape coexistence in the neutron-deficient lead region
We put forward a study of the interplay between individual nucleon behavior and collective degrees of freedom in the nucleus, as manifested in shape coexistence in the neutron-deficient lead region. As a first step of this experimental campaign, we propose to perform Coulomb excitation on light mercury isotopes to probe their excited states and determine transitional and diagonal E2 matrix elements, especially reducing the current uncertainties. The results from previous Coulomb excitation measurements in this mass region performed with 2.85 MeV/u beams from REX-ISOLDE have shown the feasibility of these experiments. Based on our past experience and the results obtained, we propose a detailed study of the $^{182-184}$Hg nuclei, that exhibit a pronounced mixing between 2 low-lying excited states of apparently different deformation character, using the higher energy beams from HIE-ISOLDE which are crucial to reach our goal. The higher beam energy should result in an increased sensitivity with respect to the qua...
Measurements of shape co-existence in $^{182,184}$Hg using Coulomb excitation
Voulot, D; Paul, E S; Siem, S; Czosnyka, T; Napiorkowski, P J; Iwanicki, J S
2007-01-01
We propose to exploit the unique capability of ISOLDE to provide post-accelerated $^{182,184}$Hg ions from the REX facility to enable the lowest states of these nuclei to be Coulomb excited. By measuring the $\\gamma$-ray yields using the MINIBALL array we can measure the transition and diagonal E2 matrix elements for these states. This will give quantitative information about the nature of the shape coexistence in these nuclei and allow the sign of the quadrupole deformation be determined for the first time. We require 24 shifts to fulfill the aims of the experiment.
On alignment of deformed nucleus spins as the result of coulomb excitation
International Nuclear Information System (INIS)
Aleshin, V.P.; Ofengenden, S.R.
1981-01-01
In the framework of sudden impact approximation excitation probabilities and spiral distributions at Coulomb excitation of rotational levels by means of heavy ions are considered. Considerable attention is given to the accuracy of the qsub(ef)(THETA) approximation being a particular case of impact sudden approximation according to which at Coulomb of the even-even nuclei excitation the I spins of excited states are aligned perpendicularly to the symmetry axis of the Rutherford orbit. The analysis of the problem in the framework of a quasiclassical approximation has shown that the greatest deviations of qsub(ef)(THETA) approximation (at fixed constant of a quadrupole interaction q) occur for average scattering angles. Quanta calculation results are given at THETA=90 deg in the range q=0-10 for I=0-18. It has been found that excitation probabilities for dominating transitions are described in the qsub(ef)(THETA) approximation with an error being not higher than 1-2%. At I>=6 the greatest relative errors of the qsub(ef)(THETA) approximation when describing P 1 excitation probabilities do not exceed 30-40%. The relative errors at the description of spiral distributions may reach values being several times greater than the errors in corresponding excitation probabilities. It has been found that at I>=6 spiral distributions have two symmetrically situated maxima concentrated near h=+-hm, where hm=I cos (THETA/2). In the framework the of qsub(ef)(THETA) approximation in these maxima concentrated are from 50 to 70%, or to he exact - up to 80% of P 1 excitation probability [ru
Interference of Coulomb and nuclear excitation in inelastic scattering of 20Ne from 40Ca
International Nuclear Information System (INIS)
Ratel, Guy.
1976-01-01
Angular distributions at 54 and 63MeV and excitation functions from 35 to 95MeV for the elastic and inelastic scattering of 20 Ne by 40 Ca have been measured. Experimental data for the inelastic scattering leading to the 20 Ne (2 + , 1.63MeV) state show a characteristic minimum for the angular distributions and excitation functions. This phenomenon was explained by an interference effect between Coulomb and nuclear excitation amplitudes with the DWBA and the coupled-channel formalism. The existence of this interference minimum could be explained only by assuming a nuclear deformation stronger than these obtained with light ion scattering. However a small shift between the experimental data and theoretical curves suggests that effects of a stronger complex coupling or nuclear reorientation due to the large quadrupole moment of 20 Ne must be included [fr
Low-energy Coulomb excitation of neutron-rich zinc isotopes
Van de Walle, J; Behrens, T; Bildstein, V; Blazhev, A; Cederkäll, J; Clément, E; Cocolios, T E; Davinson, T; Delahaye, P; Eberth, J; Ekström, A; Fedorov, D V; Fedosseev, V; Fraile, L M; Franchoo, S; Gernhäuser, R; Georgiev, G; Habs, D; Heyde, K; Huber, G; Huyse, M; Ibrahim, F; Ivanov, O; Iwanicki, J; Jolie, J; Kester, O; Köster, U; Kröll, T; Krücken, R; Lauer, M; Lisetskiy, A F; Lutter, R; Marsh, B A; Mayet, P; Niedermaier, O; Pantea, M; Raabe, R; Reiter, P; Sawicka, M; Scheit, H; Schrieder, G; Schwalm, D; Seliverstov, M D; Sieber, T; Sletten, G; Smirnova, N; Stanoiu, M; Stefanescu, I; Thomas, J C; Valiente-Dobón, J J; Van Duppen, P; Verney, D; Voulot, D; Warr, N; Weisshaar, D; Wenander, F; Wolf, B H; Zielinska, M
2009-01-01
At the radioactive ion beam facility REX-ISOLDE, neutron-rich zinc isotopes were investigated using low-energy Coulomb excitation. These experiments have resulted in B(E2,20) values in 74-80Zn, B(E2,42) values in 74,76Zn and the determination of the energy of the first excited 2 states in 78,80Zn. The zinc isotopes were produced by high-energy proton- (A=74,76,80) and neutron- (A=78) induced fission of 238U, combined with selective laser ionization and mass separation. The isobaric beam was postaccelerated by the REX linear accelerator and Coulomb excitation was induced on a thin secondary target, which was surrounded by the MINIBALL germanium detector array. In this work, it is shown how the selective laser ionization can be used to deal with the considerable isobaric beam contamination and how a reliable normalization of the experiment can be achieved. The results for zinc isotopes and the N=50 isotones are compared to collective model predictions and state-of-the-art large-scale shell-model calculations, i...
Resonant Coulomb excitation of atomic nuclei propagating through a crystal in the channeling mode
International Nuclear Information System (INIS)
Stepanov, A.V.
1996-01-01
The Coulomb-excitation total cross section and the distribution of decay products originating from a resonant state of a nucleus interacting with a crystal lattice has been calculated for the case of a single inelastic collision (with respect to internal degrees of freedom in a nucleus). These observables have been expressed in terms of time-dependent correlators which describe thermal oscillations of lattice nuclei and the motion of the center of mass of a nucleus propagating across a crystal target in the channelling mode. An expression generalizing the spectrum of equivalent photons calculated by the Weizsaecker-Williams method is given
Lim, Edward C
1982-01-01
Excited States, Volume 6 is a collection of papers that discusses the excited states of molecules. The first paper discusses the linear polyene electronic structure and potential surfaces, considering both the theoretical and experimental approaches in such electronic states. This paper also reviews the theory of electronic structure and cites some experimental techniques on polyene excitations, polyene spectroscopic phenomenology, and those involving higher states of polyenes and their triplet states. Examples of these experimental studies of excited states involve the high-resolution one-pho
Coulomb excitation of the odd-odd isotopes {sup 106,108}In
Energy Technology Data Exchange (ETDEWEB)
Ekstroem, A.; Fahlander, C. [University of Lund, Physics Department, Box 118, Lund (Sweden); Cederkaell, J. [University of Lund, Physics Department, Box 118, Lund (Sweden); CERN, PH Department, Geneva 23 (Switzerland); Hjorth-Jensen, M.; Engeland, T. [University of Oslo, Physics Department and Center of Mathematics for Applications, Oslo (Norway); Blazhev, A.; Eberth, J.; Finke, F.; Reiter, P.; Warr, N.; Weisshaar, D. [University of Cologne, Institute of Nuclear Physics, Cologne (Germany); Butler, P.A.; Hurst, A.M. [University of Liverpool, Oliver Lodge Laboratory, Liverpool (United Kingdom); Davinson, T. [University of Edinburgh, Department of Physics and Astronomy, Edinburgh (United Kingdom); Goergen, A. [Service de Physique Nucleaire, CEA Saclay, Gif-sur-Yvette (France); Gorska, M. [Gesellschaft fuer Schwerionenforschung, Darmstadt (Germany); Ivanov, O.; Stefanescu, I. [Instituut voor Kern- en Stralingsfysica, K.U. Leuven (Belgium); Iwanicki, J. [University of Warsaw, Heavy Ion Laboratory, Warsaw (Poland); Koester, U. [CERN, PH Department, Geneva 23 (Switzerland); Institut Laue Langevin, Grenoble (France); Marsh, B.A. [University of Manchester, Department of Physics, Manchester (United Kingdom); CERN, AB Department, Geneva 23 (Switzerland); Mierzejewski, J. [University of Warsaw, Heavy Ion Laboratory, Warsaw (Poland); University of Warsaw, Institute of Experimental Physics, Warsaw (Poland); Siem, S. [University of Oslo, Department of Physics, Oslo (Norway); Sletten, G. [University of Copenhagen, Physics Department, Copenhagen (Denmark); Tveten, G.M. [CERN, PH Department, Geneva 23 (Switzerland); University of Oslo, Department of Physics, Oslo (Norway); Van de Walle, J. [CERN, PH Department, Geneva 23 (Switzerland); Instituut voor Kern- en Stralingsfysica, K.U. Leuven (Belgium); Voulot, D.; Wenander, F. [CERN, AB Department, Geneva 23 (Switzerland)
2010-06-15
The low-lying states in the odd-odd and unstable isotopes {sup 106,108}In have been Coulomb excited from the ground state and the first excited isomeric state at the REX-ISOLDE facility at CERN. With the additional data provided here the {pi}g{sub 9/2}{sup -1} x {nu}d{sub 5/2} and {pi}g{sub 9/2}{sup -1} x {nu} g{sub 7/2} multiplets have been re-analyzed and are modified compared to previous results. The observed {gamma} -ray de-excitation patterns were interpreted within a shell model calculation based on a realistic effective interaction. The agreement between theory and experiment is satisfactory and the calculations reproduce the observed differences in the excitation pattern of the two isotopes. The calculations exclude a 6{sup +} ground state in {sup 106}In. This is in agreement with the conclusions drawn using other techniques. Furthermore, based on the experimental results, it is also concluded that the ordering of the isomeric and ground state in {sup 108}In is inverted compared to the shell model prediction. Limits on B(E2) values have been extracted where possible. A previously unknown low-lying state at 367keV in {sup 106}In is also reported. (orig.)
Coulomb excitation of the odd-odd isotopes $^{106, 108}$In
Ekstrom, A; Blazhev, A; Van de Walle, J; Weisshaar, D; Zielinska, M; Tveten, G M; Marsh, B A; Siem, S; Gorska, M; Engeland, T; Hurst, A M; Cederkall, J; Finke, F; Iwanicki, J; Hjorth-Jensen, M; Davinson, T; Eberth, J; Sletten, G; Mierzejewski, J; Reiter, P; Warr, N; Butler, P A; Fahlander, C; Stefanescu, I; Koester, U; Ivanov, O; Wenander, F; Voulot, D
2010-01-01
The low-lying states in the odd-odd and unstable isotopes In-106,In-108 have been Coulomb excited from the ground state and the first excited isomeric state at the REX-ISOLDE facility at CERN. With the additional data provided here the pi g(9/2)(-1) circle times nu d(5/2) and pi g(9/2)(-1) circle times nu g7/2 multiplets have been re-analyzed and are modified compared to previous results. The observed gamma-ray de-excitation patterns were interpreted within a shell model calculation based on a realistic effective interaction. The agreement between theory and experiment is satisfactory and the calculations reproduce the observed differences in the excitation pattern of the two isotopes. The calculations exclude a 6(+) ground state in In-106. This is in agreement with the conclusions drawn using other techniques. Furthermore, based on the experimental results, it is also concluded that the ordering of the isomeric and ground state in In-108 is inverted compared to the shell model prediction. Limits on B(E2) val...
Lim, Edward C
2013-01-01
Excited States, Volume 2 is a collection of papers that deals with molecules in the excited states. The book describes the geometries of molecules in the excited electronic states. One paper describes the geometries of a diatomic molecule and of polyatomic molecules; it also discusses the determination of the many excited state geometries of molecules with two, three, or four atoms by techniques similar to diatomic spectroscopy. Another paper introduces an ordered theory related to excitons in pure and mixed molecular crystals. This paper also presents some experimental data such as those invo
Plunger lifetime measurements in {sup 128}Xe using Coulomb excitation in inverse kinematics
Energy Technology Data Exchange (ETDEWEB)
Rother, Wolfram; Dewald, Alfred; Ilie, Gabriela; Pissulla, Thomas; Melon, Barbara; Jolie, Jan; Pascovici, Gheorghe; Zell, Karl-Oskar [IKP, Universitaet zu Koeln, Koeln (Germany); Julin, Rauno; Jones, Peter; Greenless, Paul; Rahkila, Panu; Scholey, Cath [JYFL, University of Jyvaeskylae, Jyvaeskylae (Finland); Harissopulos, Sotirios; Lagoyannis, Anastasios; Konstantinopoulos, T. [INP, N.C.S.R. ' ' Demokritos' ' , Athens (Greece); Grahn, Tuomas [JYFL, University of Jyvaeskylae, Jyvaeskylae (Finland)]|[Oliver Lodge Lab., University of Liverpool, Liverpool (United Kingdom); Balabanski, Dimiter [INRNE, Sofia (Bulgaria)
2008-07-01
We report on an experiment using Coulomb excitation in inverse kinematics in combination with the plunger technique for measuring lifetimes of excited states of the projectile. Aside from the investigation of E(2) features in {sup 128}Xe, the aim was to explore the special features of such experiments which are also suited to be used with radioactive beams. The measurement was performed at the JYFL with the Koeln coincidence plunger device and the JuroGam spectrometer using a {sup 128}Xe beam impinging on a {sup nat}Fe target at a beam energy of 525 MeV. Recoils were detected by means of 32 solar cells placed at extrem forward angles. Recoil-gated {gamma}-singles and {gamma}{gamma}-coincidences were measured at different target-degrader distances. Details of the experiment and first results are presented.
Evolution of collectivity in the 78Ni region: Coulomb excitation of 74Ni at intermediate energies.
Directory of Open Access Journals (Sweden)
Marchi T.
2014-03-01
Full Text Available The study of the collective properties of nuclear excitations far from stability provides information about the shell structure at extreme conditions. Spectroscopic observables such as the energy or the transition probabilities of the lowest states, in nuclei with large neutron excess, allow to probe the density and isospin dependence of the effective interaction. Indeed, it was recently shown that tensor and three-body forces play an important role in breaking and creating magic numbers. Emblematic is the case of the evolution of the Ni isotopic chain where several features showed up moving from the most neutron rich stable isotope (64Ni towards the 78Ni nucleus where the large neutron excess coincides with a double shell closure. In this framework, we have recently performed an experiment with the goal to extract the B(E2; 0+ → 2+ value for the 74Ni nucleus in an intermediate-energy Coulomb excitation experiment: preliminary results are discussed.
Coulomb excitation of radioactive Na21 and its stable mirror Ne21
Schumaker, M. A.; Cline, D.; Hackman, G.; Morton, A. C.; Pearson, C. J.; Svensson, C. E.; Wu, C. Y.; Andreyev, A.; Austin, R. A. E.; Ball, G. C.; Bandyopadhyay, D.; Becker, J. A.; Boston, A. J.; Boston, H. C.; Buchmann, L.; Churchman, R.; Cifarelli, F.; Cooper, R. J.; Cross, D. S.; Dashdorj, D.; Demand, G. A.; Dimmock, M. R.; Drake, T. E.; Finlay, P.; Gallant, A. T.; Garrett, P. E.; Green, K. L.; Grint, A. N.; Grinyer, G. F.; Harkness, L. J.; Hayes, A. B.; Kanungo, R.; Leach, K. G.; Lee, G.; Maharaj, R.; Martin, J.-P.; Moisan, F.; Mythili, S.; Nelson, L.; Newman, O.; Nolan, P. J.; Orce, J. N.; Padilla-Rodal, E.; Phillips, A. A.; Porter-Peden, M.; Ressler, J. J.; Roy, R.; Ruiz, C.; Sarazin, F.; Scraggs, D. P.; Waddington, J. C.; Wan, J. M.; Whitbeck, A.; Williams, S. J.; Wong, J.
2008-10-01
The low-energy structures of the mirror nuclei Ne21 and radioactive Na21 have been examined by using Coulomb excitation at the TRIUMF-ISAC radioactive ion beam facility. Beams of ~5×106 ions/s were accelerated to 1.7 MeV/A and Coulomb excited in a 0.5 mg/cm2 natTi target. Scattered beam and target particles were detected by the segmented Si detector BAMBINO, while γ rays were observed by using two TIGRESS HPGe clover detectors perpendicular to the beam axis. For each isobar, Coulomb excitation from the (3)/(2)+ ground state to the first excited (5)/(2)+ state was observed and B(E2) values were determined by using the 2+→0+ de-excitation in Ti48 as a reference. The ϕ segmentation of BAMBINO was used to deduce tentative assignments for the signs of the mixing ratios between the E2 and M1 components of the transitions. The resulting B(E2)↑ values are 131±9e2 fm4 (25.4±1.7 W.u.) for Ne21 and 205±14e2 fm4 (39.7±2.7 W.u.) for Na21. The fit to the present data and the known lifetimes determined E2/M1 mixing ratios and B(M1)↓ values of δ=(-)0.0767±0.0027 and 0.1274±0.0025μN2 and δ=(+)0.0832±0.0028 and 0.1513±0.0017μN2 for Ne21 and Na21, respectively (with Krane and Steffen sign convention). By using the effective charges ep=1.5e and en=0.5e, the B(E2) values produced by the p-sd shell model are 30.7 and 36.4 W.u. for Ne21 and Na21, respectively. This analysis resolves a significant discrepancy between a previous experimental result for Na21 and shell-model calculations.
Probing intruder configurations in $^{186, 188}$Pb using Coulomb excitation
Columb excitation measurements to study the shape coexistence, mixing and quadrupole collectivity of the low-lying levels in neutron-deficient $^{188}$Pb nuclei are proposed with a view to extending similar studies to the $^{186}$Pb midshell nucleus. The HIE-ISOLDE beam of $^{186,188}$Pb nuclei will be delivered to MINIBALL+SPEDE set-up for simultaneous in-beam $\\gamma$-ray and conversion electron spectroscopy. The proposed experiment will allow the sign of the quadrupole deformation parameter to be extracted for the two lowest 2$^{+}$ states in $^{188}$Pb. Moreover, the advent of SPEDE will allow probing of the bandhead 0$^{+}$ states via direct measurements of E0 transitions. Beam development is requested to provide pure and instense $^{186}$Pb beam.
Scaling laws and higher-order effects in Coulomb excitation of neutron halo nuclei
International Nuclear Information System (INIS)
Typel, S.; Baur, G.
2008-01-01
Essential properties of halo nuclei can be described in terms of a few low-energy constants. For neutron halo nuclei, analytical results can be found for wave functions and electromagnetic transition matrix elements in simple but well-adapted models. These wave functions can be used to study nuclear reactions; an especially simple and instructive example is Coulomb excitation. A systematic expansion in terms of small parameters can be given. We present scaling laws for excitation amplitudes and cross-sections. The results can be used to analyze experiments like 11 Be Coulomb excitation. They also serve as benchmark tests for more involved reaction theories. (orig.)
Transfer reactions and multiple Coulomb excitation in the $^{100}$Sn Region
It is proposed to continue our REX-ISOLDE program in the $^{100}$Sn region at HIE-ISOLDE at ~5 MeV/u. Earlier measurements, with a precision of 10-20%, at 3 MeV/u with REX-ISOLDE point to a deviation between the measured B(E2) values for the first excited 2$^{+}$ states in $^{110,108,106}$Sn compared to theoretical predictions. In addition, the trend of B(E2) values for the lighter isotopes, in particular $^{106}$Sn, appear to differ between low- and high-energy measurements. In line with our letter-of-intent we aim in a first step to address the electromagnetic properties of the first 2$^{+}$and 4$^{+}$ states in $^{110,108,106}$Sn using Coulomb excitation. In these measurements we will directly access the lifetimes of the first excited 4$^{+}$ states in $^{110,108,106}$Sn for the first time. The yield of $^{104}$Sn from the LaC$_{x}$ target will be revisited to clarify if the new solid state RILIS gives sufficient yield to expand the measurements to this isotope. Following this proposal we plan similar meas...
Ground-state configuration of neutron-rich Aluminum isotopes through Coulomb Breakup
Directory of Open Access Journals (Sweden)
Chakraborty S.
2014-03-01
Full Text Available Neutron-rich 34,35Al isotopes have been studied through Coulomb excitation using LAND-FRS setup at GSI, Darmstadt. The method of invariant mass analysis has been used to reconstruct the excitation energy of the nucleus prior to decay. Comparison of experimental CD cross-section with direct breakup model calculation with neutron in p3/2 orbital favours 34Al(g.s⊗νp3/2 as ground state configuration of 35Al. But ground state configuration of 34Al is complicated as evident from γ-ray spectra of 33Al after Coulomb breakup of 34Al.
International Nuclear Information System (INIS)
Galetti, D.; Kodama, T.; Nemes, M.C.
1986-10-01
The quantum relativistic Coulomb excitation process including reccil effects is studied in the plane wave Born approximation. Quantum and relativistic recoil effects allow for relatively large transverse momentum transfers, usually neglected. This specific feature is shown to modify the angular distribution of Coulomb induced fission fragmentation in an essential manner. In contrast with usual treatments it is found that these results compare favourably with recent data. (Authors) [pt
Bound and resonant states in Coulomb-like potentials
International Nuclear Information System (INIS)
Papp, Z.
1985-12-01
The potential separable expansion method was generalized for calculating bound and resonant states in Coulomb-like potentials. The complete set of Coulomb-Sturmian functions was taken as the basis to expand the short-range potential. On this basis the matrix elements of the Coulomb-Green functions were given in closed form as functions of the (complex) energy. The feasibility of the method is demonstrated by a numerical example. (author)
Structure studies on 82Kr by means of the multiple Coulomb excitation
International Nuclear Information System (INIS)
Bruessermann, S.
1985-01-01
With a 82 Kr beam of the energy 4.6 MeV per nucleon a 208 Pb target was irradiated in order to study the Coulomb excitation of 82 Kr. The experiment has been performed at the Society for Heavy Ion Research (GSI) in Darmstadt. The 82 Kr ions backscattered on the 208 Pb target were detected in a position-sensitive parallel-plate avalanche detector. The γ radiation of the excited 82 Kr particles was detected in 4 Ge(Li) detectors in coincidence with the particles. The spectra corrected regarding the Doppler shift contained 16 lines which permitted to determine by means of known mixing and branching ratios 22 electrical quadrupole transition matrix elements. The experimental excitation energies and the transition probabilities determined in this thesis are compared with different nuclear models, like the asymmetric rotator model, the rotational-vibrational model, the harmonic-oscillator model, the nuclear field theory, the SU(5) limit of the IBA-1, and the IBA-2 model. Thereby within the IBA-2 model a criterium for the symmetry of the wavefunction relative to the proton and neutron contributions is elaborated. Because of this criterium to the 2 1 + state a symmetric structure and to the 2 2 + ,3 states an asymmetric structure is assigned. (orig.) [de
Kugler, E; Ratzinger, U; Wenander, F J C
2002-01-01
% IS347 \\\\ \\\\We propose to perform a pilot experiment to study very neutron rich (A<32) Na-Mg and (A<52) K-Ca isotopes in the region around the neutron shell closures of N=20 and N=28 after Coulomb excitation and neutron transfer, and to demonstrate highly efficient and cost-effective ways to bunch, charge-state breed and accelerate already existing mass-separated singly-charged radioactive ion beams. \\\\ \\\\To do this we plan to accelerate the ISOLDE beams up to 2~MeV/u by means of a novel acceleration scheme and to install an efficient $\\gamma$-ray array for low-multiplicity events around the target position.
Multiple Coulomb excitation effects in heavy ion compound and fusion cross sections
International Nuclear Information System (INIS)
Carlson, B.V.; Hussein, M.S.
1981-11-01
A simple model for the average S-matrix that describes heavy ion direct processes in the presence of absorption due to compound nucleus formation is developed. The fluctuation cross section and the fusion cross section are then calculated for deformed heavy ion systems where multiple Coulomb excitation is important. A simple expression for the fusion cross section valid for above-barrier energies is then obtained. The formula clearly displays the modification, due to Coulomb excitation, in the usual geometrical expression. (Author) [pt
Giant resonances on excited states
International Nuclear Information System (INIS)
Besold, W.; Reinhard, P.G.; Toepffer, C.
1984-01-01
We derive modified RPA equations for small vibrations about excited states. The temperature dependence of collective excitations is examined. The formalism is applied to the ground state and the first excited state of 90 Zr in order to confirm a hypothesis which states that not only the ground state but every excited state of a nucleus has a giant resonance built upon it. (orig.)
Generalized coherent states for the Coulomb problem in one dimension
International Nuclear Information System (INIS)
Nouri, S.
2002-01-01
A set of generalized coherent states for the one-dimensional Coulomb problem in coordinate representation is constructed. At first, we obtain a mapping for proper transformation of the one-dimensional Coulomb problem into a nonrotating four-dimensional isotropic harmonic oscillator in the hyperspherical space, and the generalized coherent states for the one-dimensional Coulomb problem is then obtained in exact closed form. This exactly soluble model can provide an adequate means for a quantum coherency description of the Coulomb problem in one dimension, sample for coherent aspects of the exciton model in one-dimension example in high-temperature superconductivity, semiconductors, and polymers. Also, it can be useful for investigating the coherent scattering of the Coulomb particles in one dimension
Coulomb excitation of doubly magic $^{132}$Sn with MINIBALL at HIE-ISOLDE
We propose to study the vibrational first 2$^{+}$ and 3$^{-}$ states of the doubly magic nucleus $^{132}$ Sn via Coulomb excitation using the HIE-ISOLDE facility coupled with the highly efficient MINIBALL array. The intense $^{132}$Sn beam at ISOLDE, the high beam energy of HIE-ISOLDE, the high energy resolution and good efficiency of the MINIBALL provide a unique combination and favourable advantages to master this demanding measurement. Reliable B(E2;0$^{+}\\rightarrow$ 2$^{+}$) values for neutron deficient $^{106,108,110}$Sn were obtained with the MINIBALL at REX-ISOLDE. These measurements can be extended up to and beyond the shell closure at the neutron-rich side with $^{132}$Sn. The results on excited collective states in $^{132}$Sn will provide crucial information on 2p-2h cross shell configurations which are expected to be dominated by a strong proton contribution. Predictions are made within various large scale shell model calculations and new mean field calculations within the framework of different a...
Nuclear structure studies of the neutron-rich Rubidium isotopes using Coulomb excitation
Reiter, P; Blazhev, A A; Voulot, D; Meot, V H; Simpson, G S; Georgiev, G P; Gaudefroy, L; Roig, O
We propose to study the properties of odd-mass neutron-rich rubidium isotopes by the Coulomb-excitation technique, using the Miniball array coupled to the REX-ISOLDE facility. The results from similar measurements from the recent years (e.g. for the odd-mass and the odd-odd Cu isotopes, IS435) have shown the strong potential in such measurements for gaining information both for single-particle-like and collective states in exotic nuclei. Since there is practically no experimental information for excited states in the odd-mass Rb isotopes beyond $^{93}$Rb, the present study should be able to provide new data in a region of spherical ($^{93}$Rb and $^{95}$Rb) as well as well-deformed nuclei ($^{97}$Rb and $^{99}$Rb). Of particular interest is the rapid shape change that occurs when going from $^{95}$Rb (${\\varepsilon}_{2}$=0.06) to $^{97}$Rb (${\\varepsilon}_{2}$=0.3). These results should be of significant astrophysical interest as well, due to the close proximity of the r-process path.
Shape coexistence in neutron-rich Sr isotopes : Coulomb excitation of $^{96}$Sr
Clement, E; Siem, S; Czosnyka, T
2007-01-01
The nuclei in the mass region A $\\cong$ 100 around Sr and Zr show a dramatic change of the nuclear ground-state shape from near spherical for N $\\leq$ 58 to strongly deformed for N $\\geq$ 60. Theoretical calculations predict the coexistence of slightly oblate and strongly prolate deformed configurations in the transitional region. However, excited rotational structures based on the highly deformed configuration, which becomes the ground state at N = 60, are not firmly established in the lighter isotopes, and the earlier interpretation of a very abrupt change of shape has been challenged by recent experimental results in favor of a rather gradual change. We propose to study the electromagnetic properties of the neutron-rich nucleus $_{38}^{96}$Sr$_{58}$ by low-energy Coulomb excitation using the REX-ISOLDE facility and the MINIBALL detector array. Both transitional and diagonal matrix elements will be extracted, resulting in a complete description of the transition strengths and quadrupole moments of the low-l...
Three-body Coulomb bound states
Bhatia, A. K.; Drachman, Richard J.
1987-01-01
The binding energies of three-particle systems containing two electrons and one positive particle of mass M are reexamined in an attempt to understand the approximate proportionality of the 1Se ground-state binding energies of the reduced masses, as pointed out by Botero and Green (1986). The contribution to the energy of the mass-polarization term is evaluated. No fundamental principle is involved, since the mass polarization merely decreases somewhat as the mass of the positive particle is reduced below the proton mass. In the case of the excited 3Pe state, this reduction is not sufficient to allow binding when M approaches the electron mass. Some properties of the recently observed negative muonium ion (e/-/ mu/+/ e/-/) are also computed.
Measurements of octupole collectivity in $^{220,222}$Rn and $^{222,224}$Ra using Coulomb excitation
Kruecken, R; Larsen, A; Hurst, A M; Voulot, D; Grahn, T; Clement, E; Wadsworth, R; Gernhaeuser, R A; Siem, S; Huyse, M L; Iwanicki, J S
2008-01-01
We propose to exploit the unique capability of ISOLDE to provide post-accelerated $^{220,222}$Rn and $^{222,224}$Ra ion beams from the REX facility to enable the Coulomb excitation of the first 3$^{-}$ states in these nuclei. By measuring the $\\gamma$-ray yields of the E1 decays from the 3$^{-}$ state using the MINIBALL array we can obtain the transition matrix elements. This will give quantitative information about octupole correlations in these nuclei. We require 22 shifts to fulfil the aims of the experiment.
Low-energy Coulomb excitation of $^{62}$Fe and $^{62}$Mn following in-beam decay of $^{62}$Mn
Gaffney, L P; Bastin, B; Bildstein, V; Blazhev, A; Bree, N; Darby, I; De Witte, H; DiJulio, D; Diriken, J; Fedosseev, V N; Fransen, Ch; Gernhäuser, R; Gustafsson, A; Hess, H; Huyse, M; Kesteloot, N; Kröll, Th; Lutter, R; Marsh, B A; Reiter, P; Seidlitz, M; Van Duppen, P; Voulot, D; Warr, N; Wenander, F; Wimmer, K; Wrzosek-Lipska, K
2015-01-01
Sub-barrier Coulomb-excitation was performed on a mixed beam of $^{62}$Mn and $^{62}$Fe, following in-trap $\\beta^{-}$ decay of $^{62}$Mn at REX-ISOLDE, CERN. The trapping and charge breeding times were varied in order to alter the composition of the beam, which was measured by means of an ionisation chamber at the zero-angle position of the Miniball array. A new transition was observed at 418 keV, which has been tentatively associated to a $2^{(+)},3^{(+)}\\rightarrow1^{+}_{g.s.}$ transition. This fixes the relative positions of the $\\beta$-decaying $4^{(+)}$ and $1^{+}$ states in $^{62}$Mn for the first time. Population of the $2^{+}_{1}$ state was observed in $^{62}$Fe and the cross-section determined by normalisation to the $^{109}$Ag target excitation. Combining this Coulomb-excitation cross-section with previously measured lifetimes of the $2^{+}_{1}$ state, the spectroscopic quadrupole moment, $Q_{s}(2^{+}_{1})$, is extracted, albeit with a large uncertainty.
Bree, N; Wrzosek-Lipska, K; Petts, A; Andreyev, A; Bastin, B; Bender, M; Blazhev, A; Bruyneel, B; Butler, P A; Butterworth, J; Carpenter, M P; Cederkäll, J; Clément, E; Cocolios, T E; Deacon, A; Diriken, J; Ekström, A; Fitzpatrick, C; Fraile, L M; Fransen, Ch; Freeman, S J; Gaffney, L P; García-Ramos, J E; Geibel, K; Gernhäuser, R; Grahn, T; Guttormsen, M; Hadinia, B; Hadyńska-Kle K, K; Hass, M; Heenen, P-H; Herzberg, R-D; Hess, H; Heyde, K; Huyse, M; Ivanov, O; Jenkins, D G; Julin, R; Kesteloot, N; Kröll, Th; Krücken, R; Larsen, A C; Lutter, R; Marley, P; Napiorkowski, P J; Orlandi, R; Page, R D; Pakarinen, J; Patronis, N; Peura, P J; Piselli, E; Rahkila, P; Rapisarda, E; Reiter, P; Robinson, A P; Scheck, M; Siem, S; Singh Chakkal, K; Smith, J F; Srebrny, J; Stefanescu, I; Tveten, G M; Van Duppen, P; Van de Walle, J; Voulot, D; Warr, N; Wenander, F; Wiens, A; Wood, J L; Zielińska, M
2014-04-25
Coulomb-excitation experiments to study electromagnetic properties of radioactive even-even Hg isotopes were performed with 2.85 MeV/nucleon mercury beams from REX-ISOLDE. Magnitudes and relative signs of the reduced E2 matrix elements that couple the ground state and low-lying excited states in Hg182-188 were extracted. Information on the deformation of the ground and the first excited 0+ states was deduced using the quadrupole sum rules approach. Results show that the ground state is slightly deformed and of oblate nature, while a larger deformation for the excited 0+ state was noted in Hg182,184. The results are compared to beyond mean field and interacting-boson based models and interpreted within a two-state mixing model. Partial agreement with the model calculations was obtained. The presence of two different structures in the light even-mass mercury isotopes that coexist at low excitation energy is firmly established.
Computational assignment of redox states to Coulomb blockade diamonds.
Olsen, Stine T; Arcisauskaite, Vaida; Hansen, Thorsten; Kongsted, Jacob; Mikkelsen, Kurt V
2014-09-07
With the advent of molecular transistors, electrochemistry can now be studied at the single-molecule level. Experimentally, the redox chemistry of the molecule manifests itself as features in the observed Coulomb blockade diamonds. We present a simple theoretical method for explicit construction of the Coulomb blockade diamonds of a molecule. A combined quantum mechanical/molecular mechanical method is invoked to calculate redox energies and polarizabilities of the molecules, including the screening effect of the metal leads. This direct approach circumvents the need for explicit modelling of the gate electrode. From the calculated parameters the Coulomb blockade diamonds are constructed using simple theory. We offer a theoretical tool for assignment of Coulomb blockade diamonds to specific redox states in particular, and a study of chemical details in the diamonds in general. With the ongoing experimental developments in molecular transistor experiments, our tool could find use in molecular electronics, electrochemistry, and electrocatalysis.
Coulomb excitation of Ca-44 and Ar-46
Czech Academy of Sciences Publication Activity Database
Calinescu, S.; Caceres, L.; Grévy, S.; Sorlin, O.; Dombradi, Z.; Stanoiu, M.; Astabatyan, R.; Borcea, C.; Borcea, R.; Bowry, M.; Catford, W.; Clement, E.; Franchoo, S.; Garcia, R.; Gillibert, R.; Guerin, I. H.; Kuti, I.; Lukyanov, S.; Lepailleur, A.; Maslov, V.; Morfouace, P.; Mrázek, Jaromír; Negoita, F.; Niikura, M.; Perrot, L.; Podolyak, Z.; Petrone, C.; Penionzhkevich, Y. E.; Roger, T.; Rotaru, F.; Sohler, D.; Stefan, I.; Thomas, J. C.; Vajta, Zs.; Wilson, E.
2016-01-01
Roč. 93, č. 4 (2016), s. 044333 ISSN 0556-2813 Institutional support: RVO:61389005 Keywords : neutron rich nuclei * low lying states * scattering Subject RIV: BG - Nuclear, Atomic and Molecular Physics, Colliders Impact factor: 3.820, year: 2016
Onset of collectivity in $^{96,98}$Sr studied via Coulomb excitation
Clement, E; Dijon, A; de France, G; Bastin, B; Blazhev, A; Bree, N; Butler, P; Delahaye, P; Ekstrom, A; Georgiev, G; Hasan, N; Iwanicki, J; Jenkins, D; Korten, W; Larsen, A C; Ljungvall, J; Moschner, K; Napiorkowski, P; Pakarinen, J; Petts, A; Renstrom, T; Seidlitz, M; Siem, S; Sotty, C; Srebrny, J; Stefanescu, I; Tveten, G M; Van de Walle, J; Warr, N; Wrzosek-Lipska, K; Zielinska, M; Bauer, C; Bruyneel, B; Butterworth, J; Fitzpatrick, C; Fransen, C; GernhäUser, R; Hess, H; Lutter, R; Marley, P; Reiter, P; Siebeck, B; Vermeulen, M; Wiens, A; De Witte, H
2014-01-01
A rapid onset of quadrupole deformation is known to occur around the neutron number 60 in the neutron-rich Zr and Sr isotopes. This shape change has made the neutron-rich A = 100 region an active area of experimental and theoretical studies for many decades now. We report in this contribution new experimental results in the neutron rich 96,98Sr investigated by safe Coulomb excitation of radioactive beams at the REX-ISOLDE facility, CERN. Reduced transition probabilities and spectroscopic quadrupole moments have been extracted from the differential Coulomb excitation cross section supporting the scenario of shape coexistence/change at N=60. Future perspectives are presented including the recent experimental campaign performed at ILL-Grenoble.
Onset of collectivity in 96,98Sr studied via Coulomb excitation
Directory of Open Access Journals (Sweden)
Clément E.
2014-03-01
Full Text Available A rapid onset of quadrupole deformation is known to occur around the neutron number 60 in the neutron-rich Zr and Sr isotopes. This shape change has made the neutron-rich A = 100 region an active area of experimental and theoretical studies for many decades now. We report in this contribution new experimental results in the neutron rich 96,98Sr investigated by safe Coulomb excitation of radioactive beams at the REX-ISOLDE facility, CERN. Reduced transition probabilities and spectroscopic quadrupole moments have been extracted from the differential Coulomb excitation cross section supporting the scenario of shape coexistence/change at N=60. Future perspectives are presented including the recent experimental campaign performed at ILL-Grenoble.
International Nuclear Information System (INIS)
Kumar, Rajiv; Sharma, Shagun; Singh, Pradeep; Kharab, Rajesh
2016-01-01
The energy-independent touching spheres schemes commonly used for the determination of the safe minimum value of the impact parameter for Coulomb excitation experiments are modified through the inclusion of an energy-dependent term. The touching spheres+3fm scheme after modification emerges out to be the best one while touching spheres+4fm scheme is found to be better in its unmodified form. (orig.)
Electron impact excitation of positive ions calculated in the Coulomb-Born approximation
International Nuclear Information System (INIS)
Nakazaki, Shinobu; Hashino, Tasuke
1979-08-01
Theoretical results on the electron impact excitation of positive ions are surveyed through the end of 1978. As a guide to the available data, a list of references is made. The list shows ion species, transitions, energy range and methods of calculation for the respective data. Based on the literature survey, the validity of the Coulomb-Born approximation is investigated. Comparisons with the results of the close-coupling and the distorted-wave methods are briefly summarized. (author)
Shape coexistence in the neutron-deficient mercury isotopes studied through Coulomb excitation
Bree, Nick
This thesis describes the analysis and results of a series of Coulomb-excitation experiments on even-even neutron-deficient mercury isotopes aimed at obtaining a more detailed description of shape coexistence. Two experimental campaigns have been undertaken in the Summer of 2007 and 2008. Pure beams of 182,184,186,188Hg were produced and accelerated at the REX-ISOLDE radioactive-beam facility, located at CERN (Geneva, Switzerland). The beams were guided to collide with a stable target to induce Coulomb excitation. The scattered particles were registered by a double-sided silicon strip detector, and the emitted gamma rays by the MINIBALL gamma-ray spectrometer. The motivation to study these mercury isotopes, focused around shape coexistence in atomic nuclei, is addressed in chapter 1, as well as an overview of the knowledge in this region of the nuclear chart. A theoretical description of Coulomb excitation is presented in the second chapter, while the third chapter describes the setup employed for the experim...
Coulomb Final State Interactions for Gaussian Wave Packets
Wiedemann, Urs Achim; Heinz, Ulrich W
1999-01-01
Two-particle like-sign and unlike-sign correlations including Coulomb final state interactions are calculated for Gaussian wave packets emitted from a Gaussian source. We show that the width of the wave packets can be fully absorbed into the spatial and momentum space widths of an effective emission function for plane wave states, and that Coulomb final state interaction effects are sensitive only to the latter, but not to the wave packet width itself. Results from analytical and numerical calculations are compared with recently published work by other authors.
Schumaker, M. A.; Hurst, A. M.; Svensson, C. E.; Wu, C. Y.; Becker, J. A.; Cline, D.; Hackman, G.; Pearson, C. J.; Stoyer, M. A.; Andreyev, A.; Austin, R. A. E.; Ball, G. C.; Bandyopadhyay, D.; Barton, C. J.; Boston, A. J.; Boston, H. C.; Buchmann, L.; Churchman, R.; Cifarelli, F.; Colosimo, S. J.; Cooper, R. J.; Cross, D. S.; Dashdorj, D.; Demand, G. A.; Dimmock, M. R.; Djongolov, M.; Drake, T. E.; Finlay, P.; Gallant, A. T.; Garrett, P. E.; Gray-Jones, C.; Green, K. L.; Grint, A. N.; Grinyer, G. F.; Harkness, L. J.; Hayes, A. B.; Kanungo, R.; Leach, K. G.; Kulp, W. D.; Lisetskiy, A. F.; Lee, G.; Lloyd, S.; Maharaj, R.; Martin, J.-P.; Millar, B. A.; Moisan, F.; Morton, A. C.; Mythili, S.; Nelson, L.; Newman, O.; Nolan, P. J.; Orce, J. N.; Oxley, D. C.; Padilla-Rodal, E.; Phillips, A. A.; Porter-Peden, M.; Ressler, J. J.; Rigby, S. V.; Roy, R.; Ruiz, C.; Sarazin, F.; Scraggs, D. P.; Sumithrarachchi, C. S.; Triambak, S.; Waddington, J. C.; Walker, P. M.; Wan, J.; Whitbeck, A.; Williams, S. J.; Wong, J.; Wood, J. L.
2009-03-01
The TRIUMF-ISAC Gamma-Ray Escape Suppressed Spectrometer (TIGRESS) is a state-of-the-art γ-ray spectrometer being constructed at the ISAC-II radioactive ion beam facility at TRIUMF. TIGRESS will be comprised of twelve 32-fold segmented high-purity germanium (HPGe) clover-type γ-ray detectors, with BGO/CsI(Tl) Compton-suppression shields, and is currently operational at ISAC-II in an early-implementation configuration of six detectors. Results have been obtained for the first experiments performed using TIGRESS, which examined the A = 20, 21, and 29 isotopes of Na by Coulomb excitation.
A new recoil distance technique using low energy coulomb excitation in inverse kinematics
Energy Technology Data Exchange (ETDEWEB)
Rother, W., E-mail: wolfram.rother@googlemail.com [Institut fuer Kernphysik der Universitaet zu Koeln, Zuelpicher Str. 77, D-50937 Koeln (Germany); Dewald, A.; Pascovici, G.; Fransen, C.; Friessner, G.; Hackstein, M. [Institut fuer Kernphysik der Universitaet zu Koeln, Zuelpicher Str. 77, D-50937 Koeln (Germany); Ilie, G. [Wright Nuclear Structure Laboratory, Yale University, New Haven, CT 06520 (United States); National Institute of Physics and Nuclear Engineering, P.O. Box MG-6, Bucharest-Magurele (Romania); Iwasaki, H. [National Superconducting Cyclotron Laboratory, Michigan State University, East Lansing, MI 48824 (United States); Department of Physics and Astronomy, Michigan State University, East Lansing, MI 48824 (United States); Jolie, J. [Institut fuer Kernphysik der Universitaet zu Koeln, Zuelpicher Str. 77, D-50937 Koeln (Germany); Melon, B. [Dipartimento di Fisica, Universita di Firenze and INFN Sezione di Firenze, Sesto Fiorentino (Firenze) I-50019 (Italy); Petkov, P. [Institut fuer Kernphysik der Universitaet zu Koeln, Zuelpicher Str. 77, D-50937 Koeln (Germany); INRNE-BAS, Sofia (Bulgaria); Pfeiffer, M. [Institut fuer Kernphysik der Universitaet zu Koeln, Zuelpicher Str. 77, D-50937 Koeln (Germany); Pissulla, Th. [Institut fuer Kernphysik der Universitaet zu Koeln, Zuelpicher Str. 77, D-50937 Koeln (Germany); Bundesumweltministerium, Robert-Schuman-Platz 3, D - 53175 Bonn (Germany); Zell, K.-O. [Institut fuer Kernphysik der Universitaet zu Koeln, Zuelpicher Str. 77, D-50937 Koeln (Germany); Jakobsson, U.; Julin, R.; Jones, P.; Ketelhut, S.; Nieminen, P.; Peura, P. [Department of Physics, University of Jyvaeskylae, P.O. Box 35, FI-40014 (Finland); and others
2011-10-21
We report on the first experiment combining the Recoil Distance Doppler Shift technique and multistep Coulomb excitation in inverse kinematics at beam energies of 3-10 A MeV. The setup involves a standard plunger device equipped with a degrader foil instead of the normally used stopper foil. An array of particle detectors is positioned at forward angles to detect target-like recoil nuclei which are used as a trigger to discriminate against excitations in the degrader foil. The method has been successfully applied to measure lifetimes in {sup 128}Xe and is suited to be a useful tool for experiments with radioactive ion beams.
On rate-state and Coulomb failure models
Gomberg, J.; Beeler, N.; Blanpied, M.
2000-01-01
We examine the predictions of Coulomb failure stress and rate-state frictional models. We study the change in failure time (clock advance) Δt due to stress step perturbations (i.e., coseismic static stress increases) added to "background" stressing at a constant rate (i.e., tectonic loading) at time t0. The predictability of Δt implies a predictable change in seismicity rate r(t)/r0, testable using earthquake catalogs, where r0 is the constant rate resulting from tectonic stressing. Models of r(t)/r0, consistent with general properties of aftershock sequences, must predict an Omori law seismicity decay rate, a sequence duration that is less than a few percent of the mainshock cycle time and a return directly to the background rate. A Coulomb model requires that a fault remains locked during loading, that failure occur instantaneously, and that Δt is independent of t0. These characteristics imply an instantaneous infinite seismicity rate increase of zero duration. Numerical calculations of r(t)/r0 for different state evolution laws show that aftershocks occur on faults extremely close to failure at the mainshock origin time, that these faults must be "Coulomb-like," and that the slip evolution law can be precluded. Real aftershock population characteristics also may constrain rate-state constitutive parameters; a may be lower than laboratory values, the stiffness may be high, and/or normal stress may be lower than lithostatic. We also compare Coulomb and rate-state models theoretically. Rate-state model fault behavior becomes more Coulomb-like as constitutive parameter a decreases relative to parameter b. This is because the slip initially decelerates, representing an initial healing of fault contacts. The deceleration is more pronounced for smaller a, more closely simulating a locked fault. Even when the rate-state Δt has Coulomb characteristics, its magnitude may differ by some constant dependent on b. In this case, a rate-state model behaves like a modified
Is the ground state of Yang-Mills theory Coulombic?
Heinzl, T.; Ilderton, A.; Langfeld, K.; Lavelle, M.; Lutz, W.; McMullan, D.
2008-08-01
We study trial states modelling the heavy quark-antiquark ground state in SU(2) Yang-Mills theory. A state describing the flux tube between quarks as a thin string of glue is found to be a poor description of the continuum ground state; the infinitesimal thickness of the string leads to UV artifacts which suppress the overlap with the ground state. Contrastingly, a state which surrounds the quarks with non-Abelian Coulomb fields is found to have a good overlap with the ground state for all charge separations. In fact, the overlap increases as the lattice regulator is removed. This opens up the possibility that the Coulomb state is the true ground state in the continuum limit.
Dynamic polarization by coulomb excitation in the closed formalism for heavy ion scattering
International Nuclear Information System (INIS)
Frahn, W.E.; Hill, T.F.
1978-01-01
We present a closed-form treatment of the effects of dynamic polarization by Coulomb excitation on the elastic scattering of deformed heavy ions. We assume that this interaction can be represented by an absorptive polarization potential. The relatively long range of this potential entails a relatively slow variation of the associated reflection function in l-space. This feature leads to a simple generalization of the closed formula derived previously for the elastic scattering amplitude of spherical heavy nuclei. We use both the polarization potential of Love et al. and the recent improved potential of Baltz et al. to derive explicit expressions for the associated reflection functions in a Coulomb-distorted eikonal approximation. As an example we analyze the elastic scattering of 90-MeV 18 O ions by 184 W and show that both results give a quantitative description of the data. (orig.) [de
Imaging of Coulomb-Driven Quantum Hall Edge States
Lai, Keji; Kundhikanjana, Worasom; Kelly, Michael A.; Shen, Zhi-Xun; Shabani, Javad; Shayegan, Mansour
2011-01-01
The edges of a two-dimensional electron gas (2DEG) in the quantum Hall effect (QHE) regime are divided into alternating metallic and insulating strips, with their widths determined by the energy gaps of the QHE states and the electrostatic Coulomb
/B(E2) values from low-energy Coulomb excitation at an ISOL facility: the /N=80,82 Te isotopes
Barton, C. J.; Caprio, M. A.; Shapira, D.; Zamfir, N. V.; Brenner, D. S.; Gill, R. L.; Lewis, T. A.; Cooper, J. R.; Casten, R. F.; Beausang, C. W.; Krücken, R.; Novak, J. R.
2003-01-01
B(E2;0+1→2+1) values for the unstable, neutron-rich nuclei 132,134Te were determined through Coulomb excitation, in inverse kinematics, of accelerated beams of these nuclei. The systematics of measured B(E2) values from the ground state to the first excited state have been extended to the N=82 shell closure in the Te nuclei and have been compared with the predictions of different theories. The measurements were performed at the Holifield Radioactive Ion Beam Facility (HRIBF) using the GRAFIK detector. The success of this approach, which couples a 5.7% efficient through-well NaI(Tl) γ-ray detector with thin foil microchannel plate beam detectors, also demonstrates the feasibility for Coulomb excitation studies of neutron-rich nuclei even further from the valley of beta stability, both at present-generation ISOL facilities and at the proposed Rare Isotope Accelerator.
Use of the Coulomb excitation by light and heavy ions for quantitative analysis
International Nuclear Information System (INIS)
Craciun, L.; Racolta, P. M.; Tripadus, V.; Dragulescu, E.; Serbanut, C.
2001-01-01
It is well known that in many cases thin layers with specific properties fulfil the same demands as former bulk materials and, although they seem to be more expensive, the general tendency has proven them to be cheaper. Therefore it might be a permanent task for physicists to develop methods, so far only applied in scientific laboratories, to a standard that might be feasible and economically justified to use them to a much larger extent. The reason for the very slow introduction of new analytical techniques is certainly the fear that instruments and apparatus used in basic research do not fulfil the standards of reliability, permanent availability and easy handling, which are important requirements for industrial applications. The knowledge of the slowing down of ions in crossing matter is of fundamental importance in methods of materials analysis using beams of charged atomic particles, Depth determination is based directly on the energy lost by the probing particles. The energy loss affects both quantitative and qualitative analyses. The physics of energy loss phenomena is very complex, involving many kinds of interactions between the projectile ion, target nuclei, and target electrons. Because of their significance in many fields of physics, these phenomena have been subject to intense studies since the beginning of the century. The theoretical treatment has been reviewed, among others, by Bohr (1948), Whaling (1958), Fano (1963), Jackson (1962,1975), Bichel (1970), Sigmund (1975), Ahlen (1980), Littmark and Ziegler (1980), Ziegler (1977, 1980), Ziegler et al. (1985). The experimental methods have been reviewed and investigated by, e.g., Chu (1979), Brauer (1987), Mertens (1987), Powers (1989). - Two well known phenomena can be used for the production of gamma-rays in bombardments with charged projectiles: a) nuclear reactions involving incident energies near and above the Coulomb barrier; in this case gamma-rays arise from the de-excitation of the product
Is the ground state of Yang-Mills theory Coulombic?
Heinzl, Thomas; Ilderton, Anton; Langfeld, Kurt; Lavelle, Martin; Lutz, Wolfgang; McMullan, David
2008-01-01
We study trial states modelling the heavy quark-antiquark ground state in SU(2) Yang-Mills theory. A state describing the flux tube between quarks as a thin string of glue is found to be a poor description of the continuum ground state; the infinitesimal thickness of the string leads to UV artifacts which suppress the overlap with the ground state. Contrastingly, a state which surrounds the quarks with non-abelian Coulomb fields is found to have a good overlap with the ground state for all ch...
Electric quadrupole excitation of the first excited state of 11B
International Nuclear Information System (INIS)
Fewell, M.P.; Spear, R.H.; Zabel, T.H.; Baxter, A.M.
1980-02-01
The Coulomb excitation of backscattered 11 B projectiles has been used to measure the reduced E2 transition probability B(E2; 3/2 - →1/2 - ) between the 3/2 - ground state and the 1/2 - first excited state of 11 B. It is found that B(E2; 3/2 - →1/2 - ) = 2.1 +- 0.4 e 2 fm 4 , which agrees with shell-model predictions but is a factor of 10 larger than the prediction of the core-excitation model
Lifetime measurements of excited states in 196Pt
International Nuclear Information System (INIS)
Bolotin, H.H.; Katayama, Ichiro; Sakai, Hideyuki; Fujita, Yoshitaka; Fujiwara, Mamoru
1979-01-01
The lifetimes of six excited states in 196 Pt up to an excitation energy of 1525 keV were measured by the recoil-distance method (RDM). These levels were populated by Coulomb excitation using both 90 MeV 20 Ne and 220 MeV 58 Ni ion beams. The measured lifetimes of the 2 1 + , 4 1 + , 6 1 + , 2 2 + , 4 2 + and 0 2 + states and the B(E2) values inferred for the depopulating transitions from these levels are presented. With the exception of the 2 1 + state, the meanlives of all other levels are the first such direct experimental determinations to be reported. (author)
We propose to exploit the unique capability of ISOLDE to provide intense post-accelerated $^{142}$Ba and $^{144}$Ba ion beams from the HIE-ISOLDE facility to enable the Coulomb excitation of the first 3$^-$ state in these nuclei. By measuring the $\\gamma$-ray yields of the E1 decays from the 3$^-$ state using the MINIBALL array, we can obtain the interesting transition matrix element. The results will give quantitative information about octupole correlations in these nuclei.
Study of Ground State Wave-function of the Neutron-rich 29,30Na Isotopes through Coulomb Breakup
Directory of Open Access Journals (Sweden)
Rahaman A.
2014-03-01
Full Text Available Coulomb breakup of unstable neutron rich nuclei 29,30Na around the ‘island of inversion’ has been studied at energy around 434 MeV/nucleon and 409 MeV/nucleon respectively. Four momentum vectors of fragments, decay neutron from excited projectile and γ-rays emitted from excited fragments after Coulomb breakup are measured in coincidence. For these nuclei, the low-lying dipole strength above one neutron threshold can be explained by direct breakup model. The analysis for Coulomb breakup of 29,30Na shows that large amount of the cross section yields the 28Na, 29Na core in ground state. The predominant ground-state configuration of 29,30Na is found to be 28Na(g.s⊗νs1/2 and 29Na(g.s⊗νs1/2,respectively.
Excited states in biological systems
International Nuclear Information System (INIS)
Cilento, G.; Zinner, K.; Bechara, E.J.H.; Duran, N.; Baptista, R.C. de; Shimizu, Y.; Augusto, O.; Faljoni-Alario, A.; Vidigal, C.C.C.; Oliveira, O.M.M.F.; Haun, M.
1979-01-01
Some aspects of bioluminescence related to bioenergetics are discussed: 1. chemical generation of excited species, by means of two general processes: electron transference and cyclic - and linear peroxide cleavage; 2. biological systems capable of generating excited states and 3. biological functions of these states, specially the non-emissive ones (tripletes). The production and the role of non-emissive excited states in biological systems are analysed, the main purpose of the study being the search for non-emissive states. Experiences carried out in biological systems are described; results and conclusions are given. (M.A.) [pt
International Nuclear Information System (INIS)
Rodrigues, C.L.; Rodrigues, M.R.D.; Borello-Lewin, T.; Horodynski-Matsushigue, L.B.; Duarte, J. L.M.; Hanninger, G.N.; Ukita, G.M.
2004-01-01
The study of the odd 99,101 Ru nuclei complements the investigation of the collectivity of the first quadrupolar excitations in 100,102,104 Ru. Angular distributions for the 99,101 Ru(d, d') reactions at 13 MeV were obtained in the Pelletron Laboratory using nuclear emulsion plates on the focal plane of the Enge spectrograph. A Coulomb- Nuclear Interference analysis employing DWBA-DOMP predictions with global optical potential parameters was applied to the excitation of states which could belong to the multiplet built on the first quadrupolar excitation of the core. In the analysis, three states were identified for each of the isotopes and associated, respectively, with adopted levels in the Nuclear Data Sheets Compilation of Jπ = 5=2 + , 7=2 + and 9=2 + . Through the comparison of experimental and predicted cross section angular distributions, the values of (δ L N ) 2 and of the ratio C = δ L C /δ L N were obtained. (author)
Energy Technology Data Exchange (ETDEWEB)
Rodrigues, C.L.; Rodrigues, M.R.D.; Borello-Lewin, T.; Horodynski-Matsushigue, L.B.; Duarte, J. L.M.; Hanninger, G.N. [Sao Paulo Univ., SP (Brazil). Inst. de Fisica; Ukita, G.M. [Universidade de Santo Amaro, SP (Brazil). Faculdade de Psicologia
2004-09-15
The study of the odd {sup 99,101}Ru nuclei complements the investigation of the collectivity of the first quadrupolar excitations in {sup 100,102,104}Ru. Angular distributions for the {sup 99,101}Ru(d, d') reactions at 13 MeV were obtained in the Pelletron Laboratory using nuclear emulsion plates on the focal plane of the Enge spectrograph. A Coulomb- Nuclear Interference analysis employing DWBA-DOMP predictions with global optical potential parameters was applied to the excitation of states which could belong to the multiplet built on the first quadrupolar excitation of the core. In the analysis, three states were identified for each of the isotopes and associated, respectively, with adopted levels in the Nuclear Data Sheets Compilation of J{pi} = 5=2{sup +}, 7=2{sup +} and 9=2{sup +}. Through the comparison of experimental and predicted cross section angular distributions, the values of ({delta}{sup L}{sub N}){sup 2} and of the ratio C = {delta}{sub L}{sup C} /{delta}{sub L}{sup N} were obtained. (author)
Energy Technology Data Exchange (ETDEWEB)
McGowan, F K; Milner, W T; Sayer, R O; Robinson, R L; Stelson, P H [Oak Ridge National Lab., Tenn. (USA)
1977-10-10
The Coulomb excitation reaction induced by /sup 4/He ions selectively excites 2/sup +/ and 3/sup -/ states by direct E2 and E3 Coulomb excitation. In this paper, new results are presented from ..gamma..-ray spectroscopy with 15 MeV /sup 4/He ions on a natural abundance target of W. In particular, a 3/sup -/ state in each isotope, /sup 182/ /sup 184/ /sup 186/W, was observed by direct E3 excitation. In addition to obtaining B(Elambda, 0 ..-->.. J = lambda for excitation of each state, information on the reduced transition probabilities for the different decay modes of these states is given. The Coulomb excitation probabilities of the 2'/sup +/ states at 786 keV in /sup 166/Er and at 737 keV in /sup 186/W were measured with /sup 16/O and /sup 4/He ions by the backscattered particle-gamma coincidence method in order to determine the static electric quadrupole moment Qsub(2'). For /sup 166/Er, Qsub(2')=2.11+-0.37 e.b which is in agreement with (Qsub(2'))sub(rot) and for /sup 186/W, Qsub(2')=1.17+-0.30 e.b which is in agreement with Kumar-Baranger model calculations and is significantly smaller than (Qsub(2'))sub(rot). This deviation of the measured Qsub(2') from (Qsub(2'))sub(rot) implies in the framework of the Kumar-Baranger calculations a strong coupling between ..beta..- and ..gamma..-vibrational bands. On the other hand, the observed upper limit for B(E2, 2'' ..-->.. 2') does not confirm this implication.
Energy Technology Data Exchange (ETDEWEB)
Clement, E
2006-06-15
The light krypton isotopes show two minima in their potential energy corresponding to elongated (prolate) and compressed (oblate) quadrupole deformation. Both configuration are almost equally bound and occur within an energy range of less than 1 MeV. Such phenomenon is called shape coexistence. An inversion of the ground state deformation from prolate in Kr{sup 78} to oblate in Kr{sup 72} with strong mixing of the configurations in Kr{sup 74} and Kr{sup 76} was proposed based on the systematic of isotopic chain. Coulomb excitation experiments are sensitive to the quadrupole moment. Coulomb excitation experiments of radioactive Kr{sup 74} and Kr{sup 76} beam were performed at GANIL using the SPIRAL facility and the EXOGAM spectrometer. The analysis of these experiments resulted in a complete description of the transition strength and quadrupole moments of the low-lying states. They establish the prolate character of the ground state and an oblate excited state. A complementary lifetime measurement using a 'plunger' device was also performed. Transition strength in neighboring nuclei were measured using the technique of intermediate energy Coulomb excitation at GANIL. The results on the Se{sup 68} nucleus show a sharp change in structure with respects to heavier neighboring nuclei. (author)
Preparation of actinide targets by molecular plating for Coulomb excitation studies at ATLAS
International Nuclear Information System (INIS)
Greene, J. P.
1998-01-01
Molecular plating is now routinely used to prepare sources and targets of actinide elements. Although the technique is simple and fairly reproducible, because of the radioactive nature of the target it is very useful to record various parameters in the preparation of such targets. At Argonne, ∼200 microg/cm 2 thick targets of Pu and Cm were required for Coulomb Excitation (COULEX) Studies with the Argonne-Notre Dame BGO gamma ray facility and later with the GAMMASPHERE. These targets were plated on 50 mg/cm 2 Au backing and were covered with 150 microg/cm 2 Au foil. Targets of 239 Pu, 240 Pu, 242 Pu, 244 Pu and 248 Cm were prepared by dissolving the material in isopropyl alcohol and electroplating the actinide ions by applying 600 volts. The amount of these materials on the target was determined by alpha particle counting and gamma ray counting. Details of the molecular plating and counting will be discussed
Entanglement entropy of excited states
International Nuclear Information System (INIS)
Alba, Vincenzo; Fagotti, Maurizio; Calabrese, Pasquale
2009-01-01
We study the entanglement entropy of a block of contiguous spins in excited states of spin chains. We consider the XY model in a transverse field and the XXZ Heisenberg spin chain. For the latter, we developed a numerical application of the algebraic Bethe ansatz. We find two main classes of states with logarithmic and extensive behavior in the dimension of the block, characterized by the properties of excitations of the state. This behavior can be related to the locality properties of the Hamiltonian having a given state as the ground state. We also provide several details of the finite size scaling
A study of the evolution of the nuclear structure along the zinc isotopic chain close to the doubly magic nucleus $^{78}$Ni is proposed to probe recent shell-model calculations in this area of the nuclear chart. Excitation energies and connecting B(E2) values will be measured through multiple Coulomb excitation experiment with laser ionized purified beams of $^{74-80}$Zn from HIE ISOLDE. The current proposal request 30 shifts.
Energy Technology Data Exchange (ETDEWEB)
Leenhardt, St
2000-01-01
Two Coulomb excitation experiments on neutron rich exotic nuclei have been performed at GANIL. They allowed the measurement of the reduced transition probability B(E2) (from ground state to first excited state) of some nuclei around N = 40. This number, 40, is a half-magic number in the shell model. For nuclei with an important neutron excess, it is predicted that the shell closure is stronger at N = 40. The B(E2) is a good tool for testing this growing. We have measured, by using the LISE3 spectrometer and a {gamma} multidetector, B(E2) of {sup 68}Ni, {sup 66}Ni and {sup 72}Zn, unknown till now. We have used for the first time segmented germanium 'clovers' detector, for photon detection (v/c{approx}0.3). Results confirm the strong shell effect for {sup 68}Ni. Indeed {sup 68}Ni was shown to be the Nickel isotope with the lowest value of B(E2), and hence the most rigid isotope. Nevertheless it seems that the shell effect at N = 40 decreases rapidly, for other isotopes very close to {sup 68}Ni(Z = 28) and N = 40). (authors)
Imaging of Coulomb-Driven Quantum Hall Edge States
Lai, Keji
2011-10-01
The edges of a two-dimensional electron gas (2DEG) in the quantum Hall effect (QHE) regime are divided into alternating metallic and insulating strips, with their widths determined by the energy gaps of the QHE states and the electrostatic Coulomb interaction. Local probing of these submicrometer features, however, is challenging due to the buried 2DEG structures. Using a newly developed microwave impedance microscope, we demonstrate the real-space conductivity mapping of the edge and bulk states. The sizes, positions, and field dependence of the edge strips around the sample perimeter agree quantitatively with the self-consistent electrostatic picture. The evolution of microwave images as a function of magnetic fields provides rich microscopic information around the ν=2 QHE state. © 2011 American Physical Society.
Photoionization of furan from the ground and excited electronic states.
Ponzi, Aurora; Sapunar, Marin; Angeli, Celestino; Cimiraglia, Renzo; Došlić, Nađa; Decleva, Piero
2016-02-28
Here we present a comparative computational study of the photoionization of furan from the ground and the two lowest-lying excited electronic states. The study aims to assess the quality of the computational methods currently employed for treating bound and continuum states in photoionization. For the ionization from the ground electronic state, we show that the Dyson orbital approach combined with an accurate solution of the continuum one particle wave functions in a multicenter B-spline basis, at the density functional theory (DFT) level, provides cross sections and asymmetry parameters in excellent agreement with experimental data. On the contrary, when the Dyson orbitals approach is combined with the Coulomb and orthogonalized Coulomb treatments of the continuum, the results are qualitatively different. In excited electronic states, three electronic structure methods, TDDFT, ADC(2), and CASSCF, have been used for the computation of the Dyson orbitals, while the continuum was treated at the B-spline/DFT level. We show that photoionization observables are sensitive probes of the nature of the excited states as well as of the quality of excited state wave functions. This paves the way for applications in more complex situations such as time resolved photoionization spectroscopy.
We propose to exploit the unique capability of ISOLDE to provide intense post-accelerated $^{144}$Ba ion beams from the REX facility to enable the Coulomb excitation of the first 3$^{-}$ state in this nucleus. By measuring the $\\gamma$-ray yields of the E1 decay connecting the 3$^{-}$ and 2$^{+}$ states using the MINIBALL array, we can obtain the interesting transition matrix element. The result will give quantitative information about octupole correlations in this nucleus. We require 27 shifts to fulfill the aims of the experiment.
Preparation of actinide targets by molecular plating for coulomb excitation studies at ATLAS
Greene, J P; Ahmad, I
1999-01-01
Molecular plating is now routinely used to prepare sources and targets of actinide elements. Although the technique is simple and fairly reproducible, because of the radioactive nature of the targets, it is very useful to record various parameters in the preparation process. At Argonne, approx 200 mu g/cm sup 2 thick targets of Pu and Cm were required for Coulomb Excitation (COULEX) studies with the Argonne-Notre Dame boron germanate (BGO) gamma-ray facility and later with the GAMMASPHERE. These targets were plated on 50 mg/cm sup 2 Au backings and were covered with 150 mu g/cm sup 2 Au foil. Targets of sup 2 sup 3 sup 9 Pu, sup 2 sup 4 sup 0 Pu, sup 2 sup 4 sup 2 Pu, sup 2 sup 4 sup 4 Pu and sup 2 sup 4 sup 8 Cm were prepared by dissolving the material in isopropyl alcohol and electroplating the actinide ions by applying 600 V. The amount of these materials on the target was determined by alpha particle counting and gamma-ray counting. Details of the molecular plating and counting will be discussed.
Coulomb-nuclear interference with 6Li: Isospin character of the 21+ excitation in 70,72,74Ge
International Nuclear Information System (INIS)
Barbosa, M.D.L.; Borello-Lewin, T.; Horodynski-Matsushigue, L.B.; Duarte, J.L.M.; Rodrigues, C.L.; Rodrigues, M.R.D.; Ukita, G.M.
2005-01-01
Ratios of B(E2) to B(IS2), that is, of the reduced quadrupole transition probabilities related, respectively, to charge and mass were extracted through Coulomb-nuclear interference (CNI) for the excitation of the 2 1 + states in 70,72,74 Ge, with a relative accuracy of less than 4%. For this purpose, the CNI angular distributions associated with the inelastic scattering of 28-MeV incident 6 Li ions accelerated by the Sao Paulo Pelletron, and momentum analyzed by the Enge magnetic spectrograph were interpreted within the DWBA-DOMP approach (distorted wave approximation for the scattering process and deformed optical model for the structure representation) with global 6 Li optical parameters. The present CNI results demonstrate an abrupt change in the B(E2)/B(IS2) ratio for 74 Ge: although for 70,72 Ge, values of the order of 1.0 or slightly higher were obtained, this ratio is 0.66 (7) for 74 Ge. The heavier Ge isotope is thus one of the few nuclei that, so far, have been shown to present clear mixed symmetry components in their ground-state band
International Nuclear Information System (INIS)
Rekab, S.; Zenine, N.
2006-01-01
We consider the three dimensional non relativistic eigenvalue problem in the case of a Coulomb potential plus linear and quadratic radial terms. In the framework of the Rayleigh-Schrodinger Perturbation Theory, using a specific choice of the unperturbed Hamiltonian, we obtain approximate analytic expressions for the eigenvalues of orbital excitations. The implications and the range of validity of the obtained analytic expression are discussed
Three-body Coulomb systems using generalized angular-momentum S states
Whitten, R. C.; Sims, J. S.
1974-01-01
An expansion of the three-body Coulomb potential in generalized angular-momentum eigenfunctions developed earlier by one of the authors is used to compute energy eigenvalues and eigenfunctions of bound S states of three-body Coulomb systems. The results for He, H(-), e(-)e(+)e(-), and pmu(-)p are compared with the results of other computational approaches.
Detection of a π-μ coulomb bound states
International Nuclear Information System (INIS)
Coombes, R.; Flexer, R.; Hall, A.
1977-01-01
The detection of hydrogen-like atoms is reported consisting of a negative (or positive) pion and a positive (or negative) muon in a coulomb bound state. These π-μ atoms are formed when the PI and μ from the decay have sufficiently small relative momentum to bind. Only the evidence related to the detection of these atoms is discussed. The Ksub(L)sup(0) particles which give rise to ''atomic beam'' are produced by 30 GeV proton beam striking a 10 cm beryllium target. From analysis of data 33 events are chosen. For each of these events the parameter α = Psub(π)-Psub(μ)/Psub(π)+Psub(μ) is plotted, where PPI is the pion momentum, and Pμ is the muon momentum. A study of this parameter through an examination of e + e - pairs indicates that the acceptance of apparatus is flat within 30%. The data shows a clear peak at the predicted point containing a total of 21 events with an estimated background of 3 events. The width of the peak is consistent with that expected from measurement errors
Excited states in stochastic electrodynamics
International Nuclear Information System (INIS)
Franca, H.M.; Marshall, T.W.
1987-12-01
It is shown that the set of Wigner functions associated with the excited states of the harmonic oscillator constitute a complete set of functions over the phase space. An arbitraty distribution can be expanded in terms of these Wigner functions. By studying the time evolution, according to Stochastic Electrodynamics, of the expansion coefficients, becomes feasible to separate explicity the contributionsof the radiative reaction and the vaccuum field to the Einsten. A coefficients for this system. A simple semiclassical explanation of the Weisskopf-Heitler phenomenon in resonance fluorescence is also supplied. (author) [pt
Coulomb displacement energies of the T=1, J=0 states of A=42 nuclei
International Nuclear Information System (INIS)
Sato, H.
1978-01-01
Coulomb displacement energies of the T=1, J=0 + and 6 1 + states of A=42 nuclei are analyzed with previously known charge dependent forces and effects, and with the available Hartree-Fock single-particle wave functions. From the study of the Coulomb displacement energies of the 6 1 + states it is found that the present knowledge on the charge dependence, including a phenomenological charge symmetry breaking force previously introduced so as to help explain the Nolen-Schiffer anomaly, gives a sufficient and consistent explanation for both single-particle and two-particle systems. From the study of the 0 + states, it is found that the Coulomb displacement energies of the second 0 2 + states can be explained with a compensation between the smaller Coulomb energies of the second lowest two-particle state and larger ones of the deformed 4p-2h state. (Auth.)
Investigation of beam purity after in-trap decay and Coulomb excitation of $^{62}$Mn-$^{62}$Fe
Clement, E; Gernhaeuser, R A; Diriken, J V J; Huyse, M L
2008-01-01
The in-trap decay of short lived radioactive ions is not well understood. This poses a problem for Coulomb excitation experiments at MINIBALL, where the normalization of the experiment depends strongly on observed secondary target excitation, which in turn strongly depends on the knowledge of the beam composition. For pure ISOLDE beams of short lived isotopes, the in-trap decay becomes important since a large fraction of the beam is transformed in unwanted daughter isotopes. In this proposal we intend to quantify the production of these daughter products in the REXTRAP accurately by making use of the short lived isotopes $^{61,62}$Mn and the newly installed Bragg ionization chamber at the end of the REX linear accelerator. Apart from the technical interest, the A=62 beam provides as well a good physics case, concerning the development of collectivity in neutron-rich Fe isotopes. Coulomb excitation, utilizing the standard MINIBALL setup, is proposed on both A=62 Mn and Fe. The Fe beam would be the first post-a...
Bircher, Martin P; Rothlisberger, Ursula
2018-06-12
Linear-response time-dependent density functional theory (LR-TD-DFT) has become a valuable tool in the calculation of excited states of molecules of various sizes. However, standard generalized-gradient approximation and hybrid exchange-correlation (xc) functionals often fail to correctly predict charge-transfer (CT) excitations with low orbital overlap, thus limiting the scope of the method. The Coulomb-attenuation method (CAM) in the form of the CAM-B3LYP functional has been shown to reliably remedy this problem in many CT systems, making accurate predictions possible. However, in spite of a rather consistent performance across different orbital overlap regimes, some pitfalls remain. Here, we present a fully flexible and adaptable implementation of the CAM for Γ-point calculations within the plane-wave pseudopotential molecular dynamics package CPMD and explore how customized xc functionals can improve the optical spectra of some notorious cases. We find that results obtained using plane waves agree well with those from all-electron calculations employing atom-centered bases, and that it is possible to construct a new Coulomb-attenuated xc functional based on simple considerations. We show that such a functional is able to outperform CAM-B3LYP in some cases, while retaining similar accuracy in systems where CAM-B3LYP performs well.
Quasi-stationary states and fermion pair creation from a vacuum in supercritical Coulomb field
Khalilov, V. R.
2017-12-01
Creation of charged fermion pair from a vacuum in so-called supercritical Coulomb potential is examined for the case when fermions can move only in the same (one) plane. In which case, quantum dynamics of charged massive or massless fermions can be described by the two-dimensional Dirac Hamiltonians with an usual (-a/r) Coulomb potential. These Hamiltonians are singular and require the additional definition in order for them to be treated as self-adjoint quantum-mechanical operators. We construct the self-adjoint two-dimensional Dirac Hamiltonians with a Coulomb potential and determine the quantum-mechanical states for such Hamiltonians in the corresponding Hilbert spaces of square-integrable functions. We determine the scattering amplitude in which the self-adjoint extension parameter is incorporated and then obtain equations implicitly defining possible discrete energy spectra of the self-adjoint Dirac Hamiltonians with a Coulomb potential. It is shown that this quantum system becomes unstable in the presence of a supercritical Coulomb potential which manifests in the appearance of quasi-stationary states in the lower (negative) energy continuum. The energy spectrum of those states is quasi-discrete, consists of broadened levels with widths related to the inverse lifetimes of the quasi-stationary states as well as the probability of creation of charged fermion pair by a supercritical Coulomb field. Explicit analytical expressions for the creation probabilities of charged (massive or massless) fermion pair are obtained in a supercritical Coulomb field.
Coulomb plus strong interaction bound states - momentum space numerical solutions
International Nuclear Information System (INIS)
Heddle, D.P.; Tabakin, F.
1985-01-01
The levels and widths of hadronic atoms are calculated in momentum space using an inverse algorithm for the eigenvalue problem. The Coulomb singularity is handled by the Lande substraction method. Relativistic, nonlocal, complex hadron-nucleus interactions are incorporated as well as vacuum polarization and finite size effects. Coordinate space wavefunctions are obtained by employing a Fourier Bessel transformation. (orig.)
Tricriticality for dimeric Coulomb molecular crystals in ground state
Travěnec, Igor; Šamaj, Ladislav
2017-12-01
We study the ground-state properties of a system of dimers. Each dimer consists in a pair of equivalent charges at a fixed distance, immersed in a neutralizing homogeneous background. All charges interact pairwisely by Coulomb potential. The dimer centers form a two-dimensional rectangular lattice with the aspect ratio α\\in [0, 1] and each dimer is allowed to rotate around its center. The previous numerical simulations, made for the more general Yukawa interaction, indicate that only two basic dimer configurations can appear: either all dimers are parallel or they have two different angle orientations within alternating (checkerboard) sublattices. As the dimer size increases, two second-order phase transitions, related to two kinds of the symmetry breaking in dimer’s orientations, were reported. In this paper, we use a recent analytic method based on an expansion of the interaction energy in Misra functions which converges quickly and provides an analytic derivation of the critical behaviour. Our main result is that there exists a specific aspect ratio of the rectangular lattice α^*=0.714 106 840 000 71\\ldots which divides the space of model’s phases onto two distinct regions. If the lattice aspect ratio α>α* , we recover both types of the second-order phase transitions and find that they are of mean-field type with the critical exponent β = 1/2 . If 0.711 535≤slantα<α* , the phase transition associated with the discontinuity of dimer’s angles on alternating sublattices becomes of first order. For α=α* , the first- and second-order phase transitions meet at the tricritical point, characterized by the different critical index β = 1/4 . Such phenomenon is known from literature about the Landau theory of one-component fields, but in our two-component version the scenario is more complicated: the component which is already in the symmetry-broken state at the tricritical point also interferes and exhibits unexpectedly the mean-field singular
Coulomb excitation of $^{94,96}$Kr beam Deformation in the neutron-rich krypton isotopes
Hass, M; Cederkall, J A; Di julio, D D; Zamfir, N - V; Srebrny, J; Wadsworth, R; Siem, S; Marginean, R; Iwanicki, J S
Recently the energy of the 2$_{1}^{+}$ state in the N=60 $^{96}$Kr nucleus was determinated to be 241 keV. This was the first experimental observation of an excited state in this highly exotic nucleus. The 2$_{1}^{+}$ state in $^{94}$Kr is located at 665.5 keV, i.e. E(2$_{1}^{+}$) drops by more than 400 keV at N=60. This lowering of the 2$_{1}^{+}$ energy indicates a sharp shape transition behavior which is somewhat similar to that discovered in the Sr and Zr isotopic chains at N=60. The deformation expected for the 2$_{1}^{+}$ state of $^{96}$Kr, as resulting from the E(2$_{1}^{+}$) energy based on the semi-empirical relation of Raman et al. is $\\beta_{2}$ = 0.31, which is, however, considerably smaller than that for Sr and Zr ($\\geq$0.40). The sudden decrease of E(2$_{1}^{+}$) from N=50 to N=60 does not fully agree with the more gradual change of deformation deduced from laser spectroscopy measurements of mean square charge radii, although for $^{96}$Kr, in particular, these are consistent with a $\\beta_{2}...
Coulomb excitation of $^{116}$Te and $^{118}$Te: a study of collectivity above the Z = 50 shell gap
Cederkall, J A; Smith, J F; Voulot, D; Rahkila, P J; Darby, I G; Hadinia, B; Grahn, T; Paul, E S; Wadsworth, R; Bree, N C F; Baeck, T M; Julin, R J; Diriken, J V J; Jenkins, D G; Kroell, T; Leske, J; Huyse, M L
We propose to study the nature and collectivity of low-energy excitations in $^{116}$Te and $^{118}$Te. We aim to measure the transition probability of the 0$^{+}$ $\\rightarrow$ 2$^{+}$ transition by means of Coulomb excitation, employing REX-ISOLDE and MINIBALL. The proposed study probes the systematics of B(E2) values in light Te nuclei, which lie in a region of the nuclear chart where unusual phenomena and evolution of collectivity have been observed. The proposed study will shed light on the role of the residual proton-neutron interactions in the development of collectivity when approaching the N = Z line. This is a resubmission of the P-277 proposal. The suggestions of INTC have been taken into account and the data from the Yale $^{120}$Te study has been included.
Excited state Intramolecular Proton Transfer in Anthralin
DEFF Research Database (Denmark)
Møller, Søren; Andersen, Kristine B.; Spanget-Larsen, Jens
1998-01-01
Quantum chemical calculations performed on anthralin (1,8-dihydroxy-9(10H)-anthracenone) predict the possibility of an excited-state intramolecular proton transfer process. Fluorescence excitation and emission spectra of the compound dissolved in n-hexane at ambient temperature results in an unus......Quantum chemical calculations performed on anthralin (1,8-dihydroxy-9(10H)-anthracenone) predict the possibility of an excited-state intramolecular proton transfer process. Fluorescence excitation and emission spectra of the compound dissolved in n-hexane at ambient temperature results......, associated with an excited-state intramolecular proton transfer process....
Excited-state density functional theory
International Nuclear Information System (INIS)
Harbola, Manoj K; Hemanadhan, M; Shamim, Md; Samal, P
2012-01-01
Starting with a brief introduction to excited-state density functional theory, we present our method of constructing modified local density approximated (MLDA) energy functionals for the excited states. We show that these functionals give accurate results for kinetic energy and exchange energy compared to the ground state LDA functionals. Further, with the inclusion of GGA correction, highly accurate total energies for excited states are obtained. We conclude with a brief discussion on the further direction of research that include the construction of correlation energy functional and exchange potential for excited states.
Excited states rotational effects on the behavior of excited molecules
Lim, Edward C
2013-01-01
Excited States, Volume 7 is a collection of papers that discusses the excited states of molecules. The first paper reviews the rotational involvement in intra-molecular in vibrational redistribution. This paper analyzes the vibrational Hamiltonian as to its efficacy in detecting the manifestations of intra-molecular state-mixing in time-resolved and time-averaged spectroscopic measurements. The next paper examines the temporal behavior of intra-molecular vibration-rotation energy transfer (IVRET) and the effects of IVRET on collision, reaction, and the decomposition processes. This paper also
Excited-state imaging of cold atoms
Sheludko, D.V.; Bell, S.C.; Vredenbregt, E.J.D.; Scholten, R.E.; Deshmukh, P.C.; Chakraborty, P.; Williams, J.F.
2007-01-01
We have investigated state-selective diffraction contrast imaging (DCI) of cold 85Rb atoms in the first excited (52P3/2) state. Excited-state DCI requires knowledge of the complex refractive index of the atom cloud, which was calculated numerically using a semi-classical model. The Autler-Townes
Multimode optical fibers: steady state mode exciter.
Ikeda, M; Sugimura, A; Ikegami, T
1976-09-01
The steady state mode power distribution of the multimode graded index fiber was measured. A simple and effective steady state mode exciter was fabricated by an etching technique. Its insertion loss was 0.5 dB for an injection laser. Deviation in transmission characteristics of multimode graded index fibers can be avoided by using the steady state mode exciter.
The mechanisms of Excited states in enzymes
DEFF Research Database (Denmark)
Petersen, Frederic Nicolas Rønne; Bohr, Henrik
2010-01-01
Enzyme catalysis is studied on the basis of excited state processes, which are of electronic, vibrational and thermal nature. The ways of achieving the excited state, such as photo-absorption and ligand binding, are discussed and exemplified by various cases of enzymes.......Enzyme catalysis is studied on the basis of excited state processes, which are of electronic, vibrational and thermal nature. The ways of achieving the excited state, such as photo-absorption and ligand binding, are discussed and exemplified by various cases of enzymes....
International Nuclear Information System (INIS)
Suzuki, Toshio; Sagawa, H.; Giai, N. van.
1992-01-01
Effects of CIB (charge independence breaking) and CSB (charge symmetry breaking) interactions on the Coulomb displacement energies of isobaric analog states are investigated for 48 Ca, 90 Zr and 208 Pb. Mass number dependence of the Coulomb energy anomalies is well explained when CIB and CSB interactions are used which reproduce the differences of the scattering lengths as well as those of the effective ranges of low energy nucleon-nucleon scattering. (author) 17 refs., 3 figs., 3 tabs
Andreoiu, C; Paul, E S; Czosnyka, T; Hammond, N
2002-01-01
We propose to study the Coulomb excitation of a radioactive beam of $^{70}$Se at 2.2 MeV/u obtained from the REX-ISOLDE facility in order to determine the sign of the quadrupole moment and, hence, the sign of the quadrupole deformation. Calculations suggest a 33~\\% sensitivity in Coulomb excitation yield for a nickel target depending on whether the nuclear shape is oblate or prolate. Such a determination would provide compelling evidence for the presence of oblate shapes in the vicinity of N=Z=34.
Excited state mass spectra of doubly heavy Ξ baryons
Energy Technology Data Exchange (ETDEWEB)
Shah, Zalak; Rai, Ajay Kumar [Sardar Vallabhbhai National Institute of Technology, Department of Applied Physics, Surat, Gujarat (India)
2017-02-15
In this paper, the mass spectra are obtained for doubly heavy Ξ baryons, namely, Ξ{sub cc}{sup +}, Ξ{sub cc}{sup ++}, Ξ{sub bb}{sup -}, Ξ{sub bb}{sup 0}, Ξ{sub bc}{sup 0} and Ξ{sub bc}{sup +}. These baryons consist of two heavy quarks (cc, bb, and bc) with a light (d or u) quark. The ground, radial, and orbital states are calculated in the framework of the hypercentral constituent quark model with Coulomb plus linear potential. Our results are also compared with other predictions, thus, the average possible range of excited states masses of these Ξ baryons can be determined. The study of the Regge trajectories is performed in (n, M{sup 2}) and (J, M{sup 2}) planes and their slopes and intercepts are also determined. Lastly, the ground state magnetic moments of these doubly heavy baryons are also calculated. (orig.)
International Nuclear Information System (INIS)
Ng, Kong Soon; Moo, Chin-Sien; Chen, Yi-Ping; Hsieh, Yao-Ching
2009-01-01
The coulomb counting method is expedient for state-of-charge (SOC) estimation of lithium-ion batteries with high charging and discharging efficiencies. The charging and discharging characteristics are investigated and reveal that the coulomb counting method is convenient and accurate for estimating the SOC of lithium-ion batteries. A smart estimation method based on coulomb counting is proposed to improve the estimation accuracy. The corrections are made by considering the charging and operating efficiencies. Furthermore, the state-of-health (SOH) is evaluated by the maximum releasable capacity. Through the experiments that emulate practical operations, the SOC estimation method is verified to demonstrate the effectiveness and accuracy.
Coulomb Excitation of Odd-Mass and Odd-Odd Cu Isotopes using REX-ISOLDE and Miniball
Lauer, M; Iwanicki, J S
2002-01-01
We propose to study the properties of the odd-mass and the odd-odd neutron-rich Cu nuclei applying the Coulomb excitation technique and using the REX-ISOLDE facility coupled to the Miniball array. The results from the Coulex experiments accomplished at REX-ISOLDE after its upgrade to 3 MeV/u during the last year have shown the power of this method and its importance in order to obtain information on the collective properties of even-even nuclei. Performing an experiment on the odd-mass and on the odd-odd neutron-rich Cu isotopes in the vicinity of N=40 should allow us to determine and interpret the effective proton and neutron charges in the region and to unravel the lowest proton-neutron multiplets in $^{68,70}$Cu. This experiment can take the advantage of the unique opportunity to accelerate isomerically separated beams using the RILIS ion source at ISOLDE.
Excited-state molecular photoionization dynamics
International Nuclear Information System (INIS)
Pratt, S.T.
1995-01-01
This review presents a survey of work using resonance-enhanced multiphoton ionization and double-resonance techniques to study excited-state photoionization dynamics in molecules. These techniques routinely provide detail and precision that are difficult to achieve in single-photon ionization from the ground state. The review not only emphasizes new aspects of photoionization revealed in the excited-state experiments but also shows how the excited-state techniques can provide textbook illustrations of some fundamental mechanisms in molecular photoionization dynamics. Most of the examples are confined to diatomic molecules. (author)
International Nuclear Information System (INIS)
Kar, S.; Ho, Y.K.
2009-01-01
We have investigated the doubly excited 1 D e resonance states of Ps - interacting with pure Coulomb and screened Coulomb (Yukawa) potentials employing highly correlated wave functions. For pure Coulomb interaction, in the framework of stabilization method and complex coordinate rotation method we have obtained two resonances below the n = 2 threshold of the Ps atom. For screened Coulomb interaction, we employ the stabilization method to extract resonance parameters. Resonance energies and widths for the 1 D e resonance states of Ps - for different screening parameter ranging from infinity (pure Coulomb case) to a small value are also reported. (author)
Excitation functions for deuterium-induced reactions on 194Pt near the coulomb barrier
Czech Academy of Sciences Publication Activity Database
Kulko, A. A.; Skobelev, N. K.; Kroha, Václav; Penionzhkevich, Y. E.; Mrázek, Jaromír; Burjan, Václav; Hons, Zdeněk; Šimečková, Eva; Piskoř, Štěpán; Kugler, Andrej; Demekhina, N. A.; Sobolev, Yu. G.; Chuvilskaya, T. V.; Shirokova, K.; Kuterbekov, K.
2012-01-01
Roč. 9, 6-7 (2012), s. 502-507 ISSN 1547-4771 R&D Projects: GA MŠk LA08002 Institutional support: RVO:61389005 Keywords : nucelar reactions * excitation functions * charged particle activation Subject RIV: BG - Nuclear, Atomic and Molecular Physics, Colliders
Photoionization dynamics of excited molecular states
International Nuclear Information System (INIS)
Dehmer, J.L.; O'Halloran, M.A.; Tomkins, F.S.; Dehmer, P.M.; Pratt, S.T.
1987-01-01
Resonance Enhanced Multiphoton Ionization (REMPI) utilizes tunable dye lasers to ionize an atom or molecule by first preparing an excited state by multiphoton absorption and then ionizing that state before it can decay. This process is highly selective with respect to both the initial and resonant intermediate states of the target, and it can be extremely sensitive. In addition, the products of the REMPI process can be detected as needed by analyzing the resulting electrons, ions, fluorescence, or by additional REMPI. This points to a number of opportunities for exploring excited state physics and chemistry at the quantum-state-specific level. Here we will first give a brief overview of the large variety of experimental approaches to excited state phenomena made possible by REMPI. Then we will examine in more detail, recent studies of the three photon resonant, four photon (3 + 1) ionization of H 2 via the C 'PI/sup u/ state. Strong non-Franck-Condon behavior in the photoelectron spectra of this nominally simple Rydberg state has led to the examination of a variety of dynamical mechanisms. Of these, the role of doubly excited autoionizing states now seems decisive. Progress on photoelectron studies of autoionizing states in H 2 , excited in a (2 + 1) REMPI process via the E, F 1 Σ/sub g/ + will also be briefly discussed. 26 refs., 7 figs
Rearrangements in ground and excited states
de Mayo, Paul
1980-01-01
Rearrangements in Ground and Excited States, Volume 3 presents essays on the chemical generation of excited states; the cis-trans isomerization of olefins; and the photochemical rearrangements in trienes. The book also includes essays on the zimmerman rearrangements; the photochemical rearrangements of enones; the photochemical rearrangements of conjugated cyclic dienones; and the rearrangements of the benzene ring. Essays on the photo rearrangements via biradicals of simple carbonyl compounds; the photochemical rearrangements involving three-membered rings or five-membered ring heterocycles;
Photoionization of excited molecular states using multiphoton excitation techniques
International Nuclear Information System (INIS)
Dehmer, P.M.; Pratt, S.T.; Dehmer, J.L.
1984-01-01
Photoelectron spectra are reported for three photon resonant, four photon ionization of H 2 via the B 1 Σ/sub u/ + , v = 7 (J = 2,4) and C 1 π/sub u'/, v = 0-4 (J = 1) levels and of N 2 via the o 3 1 π/sub u'/, v = 1,2, b 1 π/sub u'/, v = 3-5, and c 1 π/sub u'/, v = 0 levels. The results reflect both the spectroscopy and the dynamics of photoionization of excited molecular states and are discussed in terms of the selection rules for photoionization and the relative probabilities of photoionization from Rydberg and valence states. In some cases, in accordance with the Franck-Condon principle, the results demonstrate that resonant multiphoton ionization through Rydberg states may be a powerful technique for the production of electronic, vibrational, and rotational state selected ions. However, in other cases, systematic departures from Franck-Condon factors are observed, which reflect the more subtle dynamics of excited state photoionization. 23 references, 6 figures, 2 tables
Photoionization of excited molecular states using multiphoton excitation techniques
International Nuclear Information System (INIS)
Dehmer, P.M.; Pratt, S.T.; Dehmer, J.L.
1984-01-01
Photoelectron spectra are reported for three photon resonant, four photon ionization of H 2 via the B 1 Σ + /sub u/, v = 7 (J = 2,4) and C 1 Pi/sub u/, v = 0-4 (J = 1) levels and of N 2 via the o 3 1 Pi/sub u/, v = 1,2, b 1 Pi/sub u/, v = 3-5, and c 1 Pi/sub u/, v = 0 levels. The results reflect both the spectroscopy and the dynamics of photoionization of excited molecular states and are discussed in terms of the selection rules for photoionization and the relative probabilities of photoionization from Rydberg and valence states. In some cases, in accordance with the Franck-Condon principle, the results demonstrate that resonant multiphoton ionization through Rydberg states may be a powerful technique for the production of electronic, vibrational, and rotational state selected ions. However, in other cases, systematic departures from Franck-Condon factors are observed, which reflect the more subtle dynamics of excited state photoionization
Coulomb Excitation of Neutron-Rich $A\\approx$140 Nuclei
Van duppen, P L E
2002-01-01
Investigating the isospin dependence of the product between the B( E2; 0$_{1}^{+} \\rightarrow 2_{1}^{+}$)-value and the 2$_{1}^{+}$-excitation energy E$_{2^{+}}$ in even-even nuclei around $A\\!\\approx$140 one observes a rather smooth trend close to the valley of stability but clear indication for a reduction from the extrapolated B(E2)-values by one order of magnitude for some very neutron-rich nuclei. While close to the valley of stability the strong neutron-proton interaction results in an equilibration of the neutron and proton deformations with a predominate isoscalar character of the collective 2$^{+}$ excitation, it is conceivable that more loosely bound neutrons cannot polarize a close-to-magic proton core that well any more. This might result in a decoupling of the shape of the outer neutrons from the core and in a strong isovector admixture to the lowest lying 2$^{+}$ level. In this way the 2$^{+}$ -energies could be further lowered in neutron-rich nuclei, while the quadrupole moments of the proton c...
Optical studies of multiply excited states
International Nuclear Information System (INIS)
Mannervik, S.
1989-01-01
Optical studies of multiply-excited states are reviewed with emphasis on emission spectroscopy. From optical measurements, properties such as excitation energies, lifetimes and autoionization widths can be determined with high accuracy, which constitutes a challenge for modern computational methods. This article mainly covers work on two-, three- and four-electron systems, but also sodium-like quartet systems. Furthermore, some comments are given on bound multiply-excited states in negative ions. Fine structure effects on transition wavelengths and lifetimes (autoionization) are discussed. In particular, the most recent experimental and theoretical studies of multiply-excited states are covered. Some remaining problems, which require further attention, are discussed in more detail. (orig.) With 228 refs
Probability of collective excited state decay
International Nuclear Information System (INIS)
Manykin, Eh.A.; Ozhovan, M.I.; Poluehktov, P.P.
1987-01-01
Decay mechanisms of condensed excited state formed of highly excited (Rydberg) atoms are considered, i.e. stability of so-called Rydberg substance is analyzed. It is shown that Auger recombination and radiation transitions are the basic processes. The corresponding probabilities are calculated and compared. It is ascertained that the ''Rydberg substance'' possesses macroscopic lifetime (several seconds) and in a sense it is metastable
Excitation of giant resonances in heavy ion collisions
International Nuclear Information System (INIS)
Kuehn, W.
1991-01-01
Introduction: What are Giant Resonances? General Features of Giant Resonances, Macroscopic Description and Classification, Basic Excitation Mechanisms, Decay Modes, Giant Resonances Built on Excited States, Relativistic Coulomb Excitation of Giant Resonances, Experimental Situation. (orig.)
Partial radiative recombination cross sections for excited states of hydrogen
International Nuclear Information System (INIS)
Fazio, P.M.
1984-01-01
In calculating the radiative recombination cross sections for interstellar H II regions, usually only the electric dipole term in the expansion of the interaction Hamiltonian is kept. The dipole and quadrupole transition strengths in closed analytical form are calculated here using the Coulomb wave functions because results for any electron energy and for recombination into any angular momentum state of hydrogen are needed. Several interesting effects are found. First, the transition probabilities are maximum for recombination into specific intermediate angular momentum states at low energies (w < 2eV) and where the free state angular momentum is greater than that of the bound state. Further, that specific intermediate angular momentum state depends on the kinetic energy of the free electron. This behavior is in contrast to the normal behavior of the transition strengths where recombination into s states is greatest and decreases with increasing angular momentum. Second, the quadrupole matrix elements vanish for certain velocities of the free electron. This leads to minima in the corresponding quadrupole cross sections when plotted as a function of the free electron's kinetic energy. Finally, the partial cross sections for highly excited states are greater than previously calculated because of the additional effects of the quadrupole transitions
Extended Lagrangian Excited State Molecular Dynamics.
Bjorgaard, J A; Sheppard, D; Tretiak, S; Niklasson, A M N
2018-02-13
An extended Lagrangian framework for excited state molecular dynamics (XL-ESMD) using time-dependent self-consistent field theory is proposed. The formulation is a generalization of the extended Lagrangian formulations for ground state Born-Oppenheimer molecular dynamics [Phys. Rev. Lett. 2008 100, 123004]. The theory is implemented, demonstrated, and evaluated using a time-dependent semiempirical model, though it should be generally applicable to ab initio theory. The simulations show enhanced energy stability and a significantly reduced computational cost associated with the iterative solutions of both the ground state and the electronically excited states. Relaxed convergence criteria can therefore be used both for the self-consistent ground state optimization and for the iterative subspace diagonalization of the random phase approximation matrix used to calculate the excited state transitions. The XL-ESMD approach is expected to enable numerically efficient excited state molecular dynamics for such methods as time-dependent Hartree-Fock (TD-HF), Configuration Interactions Singles (CIS), and time-dependent density functional theory (TD-DFT).
Directory of Open Access Journals (Sweden)
Clément E.
2013-12-01
Full Text Available A rapid onset of quadrupole deformation is known to occur around the neutron number 60 in the neutron-rich Zr and Sr isotopes. This shape change has made the neutron-rich A = 100 region an active area of experimental and theoretical studies for many decades now. We report in this contribution new experimental results in the neutron rich 96,98Sr investigated by safe Coulomb excitation of radioactive beams at the REX-ISOLDE facility, CERN. Reduced transition probabilities and spectroscopic quadrupole moments have been extracted from the differential Coulomb excitation cross section supporting the scenario of shape coexistence/change at N = 60. Future perspectives are presented including the recent experimental campaign performed at ILL-Grenoble.
Computing correct truncated excited state wavefunctions
Bacalis, N. C.; Xiong, Z.; Zang, J.; Karaoulanis, D.
2016-12-01
We demonstrate that, if a wave function's truncated expansion is small, then the standard excited states computational method, of optimizing one "root" of a secular equation, may lead to an incorrect wave function - despite the correct energy according to the theorem of Hylleraas, Undheim and McDonald - whereas our proposed method [J. Comput. Meth. Sci. Eng. 8, 277 (2008)] (independent of orthogonality to lower lying approximants) leads to correct reliable small truncated wave functions. The demonstration is done in He excited states, using truncated series expansions in Hylleraas coordinates, as well as standard configuration-interaction truncated expansions.
From fusion hierarchy to excited state TBA
International Nuclear Information System (INIS)
Juettner, G.; Kluemper, A.
1998-01-01
Functional relations among the fusion hierarchy of quantum transfer matrices give a novel derivation of the TBA equations, namely without string hypothesis. This is demonstrated for two important models of 1D highly correlated electron systems, the supersymmetric t-J model and the supersymmetric extended Hubbard model. As a consequence, ''the excited state TBA'' equations, which characterize correlation lengths, are explicitly derived for the t-J model. To the authors' knowledge, this is the first explicit derivation of excited state TBA equations for 1D lattice electron systems. (orig.)
Measurements of octupole collectivity in Rn and Ra nuclei using Coulomb excitation
We propose to exploit the unique capability of HIE-ISOLDE to provide post-accelerated $^{221,222}$Rn and $^{222,226,228}$Ra ion beams for the study of octupole collectivity in these nuclei. We will measure E3 transition moments in $^{222}$Rn and $^{222,226,228}$Ra in order to fully map out the variation in E3 strength in the octupole mass region with Z$\\thicksim$88 and N$\\thicksim$134. This will validate model calculations that predict different behaviour as a function of N. We will also locate the position of the parity doublet partner of the ground state in $^{221}$Rn, in order to test the suitability of odd-A radon isotopes for EDM searches.
Rayleigh approximation to ground state of the Bose and Coulomb glasses
Ryan, S. D.; Mityushev, V.; Vinokur, V. M.; Berlyand, L.
2015-01-01
Glasses are rigid systems in which competing interactions prevent simultaneous minimization of local energies. This leads to frustration and highly degenerate ground states the nature and properties of which are still far from being thoroughly understood. We report an analytical approach based on the method of functional equations that allows us to construct the Rayleigh approximation to the ground state of a two-dimensional (2D) random Coulomb system with logarithmic interactions. We realize a model for 2D Coulomb glass as a cylindrical type II superconductor containing randomly located columnar defects (CD) which trap superconducting vortices induced by applied magnetic field. Our findings break ground for analytical studies of glassy systems, marking an important step towards understanding their properties. PMID:25592417
Static quadrupole moment of the first excited state of 24Mg
International Nuclear Information System (INIS)
Fewell, M.P.; Hinds, S.; Kean, D.C.; Zabel, T.H.
1979-01-01
The static quadrupole moment Qsub(2+) and the B(E2;0 + → 2 + ) value for the first excited state of 24 Mg have been determined using the reorientation effect in Coulomb excitation. Surface barrier detectors at 90 0 and 172 0 were used to detect 24 Mg ions scattered from 208 Pb. It is found that Qsub(2+) = -18.1 +- 1.3 e.fm 2 , suggesting that, contrary to most previous experimental evidence, the quadrupole moment is in agreement with theoretical predictions. For B(E2;0 + → 2 + ) the value 443 +- 24 e 2 . fm 4 was obtained
Giant dipole resonances built on excited states
International Nuclear Information System (INIS)
Snover, K.A.
1983-01-01
The properties of giant dipole resonances built on excited nuclear states are reviewed, with emphasis on recent results. Nonstatistical (p,γ) reactions in light nuclei, and statistical complex-particle reactions in light and heavy nuclei are discussed. 27 references
Excited state properties of aryl carotenoids
Czech Academy of Sciences Publication Activity Database
Fuciman, M.; Chábera, P.; Župčanová, Anita; Hříbek, P.; Arellano, J.B.; Vácha, František; Pšenčík, J.; Polívka, Tomáš
2010-01-01
Roč. 12, č. 13 (2010), s. 3112-3120 ISSN 1463-9076 R&D Projects: GA AV ČR IAA608170604 Institutional research plan: CEZ:AV0Z50510513 Keywords : carotenoids * excited-states * femtosecond spectroscopy Subject RIV: BO - Biophysics Impact factor: 3.454, year: 2010
Coulomb displacement energy of the f sub(7/2) state of the 48Ca
International Nuclear Information System (INIS)
Sato, Hiroshi.
1979-11-01
The Coulomb displacement energy of the T = 4, J = 0 state of the 48 Ca is analyzed. Modifying a previous method of the calculation of the core polarization correction, it is found that the charge symmetry breaking force, which is introduced previously so as to help explain the Nolen-Schiffer anomaly of the T = 1/2 system, is also needed in this system, while there still exists an ambituity in the type of the force. (author)
Excitation of nuclear states by synchrotron radiation
International Nuclear Information System (INIS)
Olariu, Albert
2003-01-01
We study the excitation of nuclear states by gamma ray beams of energy up to 200 keV produced as synchrotron radiation. We consider the possibility to populate an excited state |i> in two steps, from the ground state |g> to an intermediary state |n> which decays by gamma emission or internal conversion to a lower state |i>. The aim of this study is to establish that the probability P 2 of the two-step transition |g> → |n> → |i> should be greater than the probability P 1 of the direct transition |g> → |i>. The probabilities P 1 and P 2 correspond to a radiation pulse of duration equal to the half-time of the state |i>. We have written a computer program in C++ which computes the probability P 2 , the ratio P 2 /P 1 and the rate C 2 of the two-step transitions for any nuclei and different configurations of states. The program uses a database which contains information on the energy levels, half-lives, spins and parities of nuclear states and on the relative intensities of the nuclear transitions. If the half-lives or the relative intensities are not known the program uses the Weisskopf estimates for the transition half-lives. An interpolation program of internal conversion coefficients has also been used. We listed the values obtained for P 2 , P 2 /P 1 and C 2 in a number of cases in which P 2 is significant from the 2900 considered cases. The states |i> and |n> have the energies E i and E n , the corresponding half-lives being t i and t n . The spectral density of the synchrotron radiation has been considered to be 10 12 photons cm -2 s -1 eV -1 . We listed only the cases for which the relative intensities of the transitions from levels |n> and |i> to lower states are known. The calculations carried out in this study allowed us to identify nuclei for which P 2 has relatively great values. In the listed cases P 2 /P 1 >>1, so that the two-step excitation by synchrotron radiation is more efficient than the direct excitation |g> → |i>. For a sample having 10
Excitation of autoionizing states of helium by 100 keV proton impact: theory and experiment
International Nuclear Information System (INIS)
Godunov, A.L.; Moretto-Capelle, P.; Bordenave-Montesquieu, D.; Benhenni, M.; Bordenave-Montesquieu, A.
1997-01-01
A joint theoretical and experimental study of the excitation of the autoionizing (2s 2 ) 1 S, (2p 2 ) 1 D and (2s2p) 1 P states of helium by 100 keV proton impact is presented for the first time. The role of the three-body Coulomb interaction in the final state between the ejected electron, the scattered proton and the recoil helium ion is emphasized. Calculations have been carried out with inclusion of the three-body Coulomb interaction and within an expansion of a two-electron excitation amplitude in powers of projectile-target interaction up to the second order. A new parametrization is proposed to describe resonance profiles distorted by the Coulomb interaction in the final state (CIFS). New high-resolution (up to 68 meV) measurements of electron emission spectra made it possible to resolve the near-lying (2p 2 ) 1 D and (2s2p) 1 P resonances and reveal an evident distortion of the resonance profiles by CIFS for forward electron ejection angles below 40 o . (author)
Excitation of autoionizing states of helium by 100 keV proton impact: theory and experiment
Energy Technology Data Exchange (ETDEWEB)
Godunov, A.L.; Moretto-Capelle, P.; Bordenave-Montesquieu, D.; Benhenni, M.; Bordenave-Montesquieu, A. [Universite Paul Sabatier, Toulouse (France). Laboratoire Collisions, Agregats, Reactivite; Schipakov, V.A. [Troitsk Institute for Innovation and Fusion Research, Moscow (Russian Federation)
1997-12-14
A joint theoretical and experimental study of the excitation of the autoionizing (2s{sup 2}){sup 1}S, (2p{sup 2}){sup 1}D and (2s2p){sup 1}P states of helium by 100 keV proton impact is presented for the first time. The role of the three-body Coulomb interaction in the final state between the ejected electron, the scattered proton and the recoil helium ion is emphasized. Calculations have been carried out with inclusion of the three-body Coulomb interaction and within an expansion of a two-electron excitation amplitude in powers of projectile-target interaction up to the second order. A new parametrization is proposed to describe resonance profiles distorted by the Coulomb interaction in the final state (CIFS). New high-resolution (up to 68 meV) measurements of electron emission spectra made it possible to resolve the near-lying (2p{sup 2}){sup 1}D and (2s2p){sup 1}P resonances and reveal an evident distortion of the resonance profiles by CIFS for forward electron ejection angles below 40{sup o}. (author).
Analytical study of doubly excited ridge states
International Nuclear Information System (INIS)
Wong, H.Y.
1988-01-01
Two different non-separable problems are explored and analyzed. Non-perturbative methods need to be used to handle them, as the competing forces involved in these problems are equally strong and do not yield to a perturbative analysis. The first one is the study of doubly excited ridge states of atoms, in which two electrons are comparably excited. An analytical wavefunction for such states is introduced and is used to solve the two-electron Hamiltonian in the pair coordinates called hyperspherical coordinates variationally. The correlation between the electrons is built in analytically into the structure of the wavefunction. Sequences of ridge states out to very high excitation are computed and are organized as Rydberg series converging to the double ionization limit. Numerical results of such states in He and H - are compared with other theoretical calculations where available. The second problem is the analysis of the photodetachment of negative ions in an electric field via the frame transformation theory. The presence of the electron field requires a transformation from spherical to cylindrical symmetry for the outgoing photoelectron. This gives an oscillatory modulating factor as the effect of the electric field on cross-sections. All of this work is derived analytically in a general form applicable to the photodetachment of any negative ion. The expressions are applied to H - and S - for illustration
Excitation and decay of correlated atomic states
International Nuclear Information System (INIS)
Rau, A.R.P.
1992-01-01
Doubly excited states of atoms and ions in which two electrons are excited from the ground configuration display strong radial and angular electron correlations. They are prototypical examples of quantum-mechanical systems with strong coupling. Two distinguishing characteristics of these states are: (1) their organization into successive families, with only weak coupling between families, and (2) a hierarchical nature of this coupling, with states from one family decaying primarily to those in the next lower family. A view of the pair of electrons as a single entity, with the electron-electron repulsion between them divided into a adiabatic and nonadiabatic piece, accounts for many of the dominant features. The stronger, adiabatic part determines the family structure and the weaker, nonadiabatic part the excitation and decay between successive families. Similar considerations extend to three-electron atomic states, which group into five different classes. They are suggestive of composite models for quarks in elementary particle physics, which exhibit analogous groupings into families with a hierarchical arrangement of masses and electroweak decays. 49 refs., 6 figs., 2 tabs
International Nuclear Information System (INIS)
Liptak, J.; Kristiak, J.; Kristiakova, K.
1977-01-01
The β + -decay of 79 Rb has been studied with Ge(Li) detectors in single and coincidence modes. The half-life of the 147.06 keV level in 79 Kr has been determined to be (78+-6) ns. The relative electron intensities of seventeen transitions have been measured with a magnetic Si(Li) spectrometer. The internal conversion coefficients have been determined. The transition multipolarities have been deduced. The spin-parity assignments have been made for excited states of 79 Kr and a β-decaying sta 79 Rb(5/2 + ). The structure of excited states in 79 Kr is discussed in the framework of the Alaga and Coriolis coupling models. It is shown that the properties of some levels in 79 Kr can be explained by the existence of relatively pure rotational bands
Excited-state relaxation of some aminoquinolines
Directory of Open Access Journals (Sweden)
2006-01-01
Full Text Available The absorption and fluorescence spectra, fluorescence quantum yields and lifetimes, and fluorescence rate constants ( k f of 2-amino-3-( 2 ′ -benzoxazolylquinoline (I, 2-amino-3-( 2 ′ -benzothiazolylquinoline (II, 2-amino-3-( 2 ′ -methoxybenzothiazolyl-quinoline (III, 2-amino-3-( 2 ′ -benzothiazolylbenzoquinoline (IV at different temperatures have been measured. The shortwavelength shift of fluorescence spectra of compounds studied (23–49 nm in ethanol as the temperature decreases (the solvent viscosity increases points out that the excited-state relaxation process takes place. The rate of this process depends essentially on the solvent viscosity, but not the solvent polarity. The essential increasing of fluorescence rate constant k f (up to about 7 times as the solvent viscosity increases proves the existence of excited-state structural relaxation consisting in the mutual internal rotation of molecular fragments of aminoquinolines studied, followed by the solvent orientational relaxation.
Rearrangements in ground and excited states
de Mayo, Paul
1980-01-01
Rearrangements in Ground and Excited States, Volume 2 covers essays on the theoretical approach of rearrangements; the rearrangements involving boron; and the molecular rearrangements of organosilicon compounds. The book also includes essays on the polytopal rearrangement at phosphorus; the rearrangement in coordination complexes; and the reversible thermal intramolecular rearrangements of metal carbonyls. Chemists and people involved in the study of rearrangements will find the book invaluable.
Electron impact excitation of xenon from the metastable state to the excited states
Energy Technology Data Exchange (ETDEWEB)
Jiang Jun; Dong Chenzhong; Xie Luyou; Zhou Xiaoxin [College of Physics and Electronic Engineering, Northwest Normal University, Lanzhou 730070 (China); Wang Jianguo [Institute of Applied Physics and Computational Mathematic, Beijing 100088 (China)], E-mail: dongcz@nwnu.edu.cn
2008-12-28
The electron impact excitation cross sections from the lowest metastable state 5p{sup 5}6sJ = 2 to the six lowest excited states of the 5p{sup 5}6p configuration of xenon are calculated systematically by using the fully relativistic distorted wave method. In order to discuss the effects of target state descriptions on the electron impact excitation cross sections, two correlation models are used to describe the target states based on the multiconfiguration Dirac-Fock (MCDF) method. It is found that the correlation effects play a very important role in low energy impact. For high energy impact, however, the cross sections are not sensitive to the description of the target states, but many more partial waves must be included.
Excited state electron affinity calculations for aluminum
Hussein, Adnan Yousif
2017-08-01
Excited states of negative aluminum ion are reviewed, and calculations of electron affinities of the states (3s^23p^2)^1D and (3s3p^3){^5}{S}° relative to the (3s^23p)^2P° and (3s3p^2)^4P respectively of the neutral aluminum atom are reported in the framework of nonrelativistic configuration interaction (CI) method. A priori selected CI (SCI) with truncation energy error (Bunge in J Chem Phys 125:014107, 2006) and CI by parts (Bunge and Carbó-Dorca in J Chem Phys 125:014108, 2006) are used to approximate the valence nonrelativistic energy. Systematic studies of convergence of electron affinity with respect to the CI excitation level are reported. The calculated value of the electron affinity for ^1D state is 78.675(3) meV. Detailed Calculations on the ^5S°c state reveals that is 1216.8166(3) meV below the ^4P state.
Statistical density of nuclear excited states
Directory of Open Access Journals (Sweden)
V. M. Kolomietz
2015-10-01
Full Text Available A semi-classical approximation is applied to the calculations of single-particle and statistical level densities in excited nuclei. Landau's conception of quasi-particles with the nucleon effective mass m* < m is used. The approach provides the correct description of the continuum contribution to the level density for realistic finite-depth potentials. It is shown that the continuum states does not affect significantly the thermodynamic calculations for sufficiently small temperatures T ≤ 1 MeV but reduce strongly the results for the excitation energy at high temperatures. By use of standard Woods - Saxon potential and nucleon effective mass m* = 0.7m the A-dependency of the statistical level density parameter K was evaluated in a good qualitative agreement with experimental data.
The triplet excited state of bilirubin
International Nuclear Information System (INIS)
Land, E.J.
1976-01-01
Pulse radiolysis of benzene solutions of 40 μM bilirubin alone or with 0.1 M biphenyl has yielded evidence for the formation of the triplet excited state of bilirubin. Measurements were made of a number of properties, including the absorption spectrum (lambdasub(max)500nm), lifetime 9μs), extinction coefficient (8800 M -1 cm -1 ), energy level (approximately 150 kJ mol -1 ) and the rate of quenching by oxygen (rate constant, 8.2 x 10 8 M -1 s -1 ). An upper limit of 0.1 has also been obtained for the singlet to triplet crossover efficiency of bilirubin following excitation by 353 nm radiation. Consideration is given to the relevance of these data to the mechanism of bilirubin photo-destruction, both in vivo and in vitro. (U.K.)
Excited state kinetics of anthracene-bridge-aniline intramolecular exciplexes
DEFF Research Database (Denmark)
Thyrhaug, Erling; Hammershøj, Peter; Kjær, Kasper Skov
2014-01-01
excited anthracene state (LE) and an excited state complex (exciplex, EP) in non-polar solvents. The kinetics of the excited state processes were established in decalin from the time-resolved emission, and was shown to be strongly influenced by an electron-transfer state (ET). For quantitative studies...
Critical opalescence and the true dielectric state in a Coulomb system
Bobrov, V. B.; Trigger, S. A.
2015-04-01
To study the critical opalescence effect in a two-component Coulomb system consisting of single-type electrons and nuclei, we consider the limit relations for static structure factors and analyze the singularities of the dielectric permittivity. We show that the critical opalescence effect can be observed not only at the critical point corresponding to the gas-liquid phase transition but also near the true dielectric state with zero static conductivity. With the available experimental data taken into account, we assume that the true dielectric state is the limit state of the liquid-liquid phase transition accompanied by sharp variations in the electrical conduction of the substances. We find that if the thermodynamic parameters correspond to the true dielectric state, then the critical opalescence effect can arise in the case where the squared fluctuation in the total number of electrons and nuclei in a two-component Coulomb system becomes infinite, as this occurs at the critical point corresponding to the gas-liquid phase transition.
Generalized ladder operators for the Dirac-Coulomb problem via SUSY QM
International Nuclear Information System (INIS)
Rodrigues, R. de Lima; Universidade Federal de Campina Grande, PB
2003-12-01
The supersymmetry in quantum mechanics and shape invariance condition are applied as an algebraic method to solving the Dirac-Coulomb problem. The ground state and the excited states are investigated via new generalized ladder operators. (author)
First 3- excited state of 56Fe
International Nuclear Information System (INIS)
Fotiades, N.; Nelson, R. O.; Devlin, M.
2010-01-01
There is no reliable evidence for the existence of the 3.076 MeV (3 - ) level adopted in the ENSDF evaluation for 56 Fe although it has been reported in a few experiments. Previous reports of the observation of this level appear to be based on an incorrect assignment in early (e,e ' ) work. Recent neutron inelastic scattering measurements by Demidov et al. [Phys. At. Nucl. 67, 1884, (2004)] show that the assigned γ-ray decay of this state does not occur at a level consistent with known properties of inelastic scattering. In the present work the 56 Fe(n,n ' γ) reaction was used to populate excited states in 56 Fe. Neutrons in the energy range from 1 to 250 MeV were provided by the pulsed neutron source of the Los Alamos Neutron Science Center's WNR facility. Deexciting γ rays were detected with the GEANIE spectrometer, a Compton suppressed array of 26 Ge detectors. The γ-γ data obtained with GEANIE were used to establish coincidence relations between transitions. All previously reported levels up to E x =3.6 MeV excitation energy were observed except for the 3.076 MeV (3 - ) level. The 991- and 2229-keV transitions, previously reported to deexcite this level, were not observed in the γ-γ coincidence data obtained in the present experiment. The present work supports the assignment of the 4509.6 keV level as the first 3 - excited state in 56 Fe by observation of two previously known transitions deexciting this state.
International Nuclear Information System (INIS)
Bouchez, Emmanuelle
2003-01-01
The first part of this research thesis proposes an overview of the different theoretical calculations elaborated in the region of light krypton nuclei, and of published experimental results. The second part reports the electron and gamma isomeric spectroscopy of 72,74 Kr nuclei after fragmentation of the projectile by a magnetic separator (experimental installation, experimental results, discussion). The third part reports the study of the Coulomb excitation of the 76 Kr radioactive beam (method and experimental installation, data analysis and results in terms of germanium and silicon spectra, and form of the 76 Kr)
The structure of 83Sr excited states
International Nuclear Information System (INIS)
Liptak, J.; Kristiak, J.; Kristiakova, K.
1976-01-01
The β-decay of 83 Y isomers (7.06 min and 2.85 min) have been studied by means of Ge(Li) detectors. The proposed level scheme of the 83 Sr nucleus is based on the coincidence measurement and the analysis of energy sums. The intensity balance requirement leads to αsub(T)(35.5keV)=3.2 which is consistent with M1 multipolarity of this transition. A probable structure of some of the excited states in the 83 Sr nucleus is discussed in the frame work of Alaga's model and Kuriyama's model
Excited state dynamics of DNA bases
Czech Academy of Sciences Publication Activity Database
Kleinermanns, K.; Nachtigallová, Dana; de Vries, M. S.
2013-01-01
Roč. 32, č. 2 (2013), s. 308-342 ISSN 0144-235X R&D Projects: GA ČR GAP208/12/1318 Grant - others:National Science Foundation(US) CHE-0911564; NASA (US) NNX12AG77G; Deutsche Forschungsgemeinschaft(DE) SFB 663; Deutsche Forschungsgemeinschaft(DE) KI 531-29 Institutional support: RVO:61388963 Keywords : DNA bases * nucleobases * excited state * dynamics * computations * gas phase * conical intersections Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 4.920, year: 2013
Excited State Spectra and Dynamics of Phenyl-Substituted Butadienes
DEFF Research Database (Denmark)
Wallace-Williams, Stacie E.; Schwartz, Benjamin J.; Møller, Søren
1994-01-01
indicate that phenyl torsional motion is not important to the excited-state dynamics and reveal alternative excited-state reaction pathways. The results demonstrate how molecular systems that are structually similar can exhibit different electronic properties and excited-state dynamics....
Neutral excitations in the Gaffnian state
Kang, Byungmin; Moore, Joel E.
2017-06-01
We study a model fractional quantum Hall (FQH) wave function called the Gaffnian state, which is believed to represent a gapless, strongly correlated state that is very different from conventional metals. To understand this exotic gapless state better, we provide a representation based on work of Halperin in which the pairing structure of the Gaffnian state becomes more explicit. We employ the single-mode approximation introduced by Girvin, MacDonald, and Platzman, here extended to three-body interactions, in order to treat a neutral collective excitation mode in order to clarify the physical origin of the gaplessness of the Gaffnian state. We discuss approaches to extract systematically the relevant physics in the long-distance, large-electron-number limit of FQH states using numerical calculations with relatively few electrons. In Appendices, we provide second-quantized expressions for many-body Haldane pseudopotentials in various geometries including the plane, sphere, cylinder, and torus based on the proper definition of the relative angular momentum.
Butler, P; Cederkall, J A; Reiter, P; Wiens, A; Blazhev, A A; Kruecken, R; Voulot, D; Kalkuehler, M; Wadsworth, R; Gernhaeuser, R A; Hess, H E; Holler, A; Finke, F; Leske, J; Huyse, M L; Seidlitz, M
We propose to study the properties of neutron-rich nuclei $^{28,29,30}$Na via Coulomb excitation experiments using the REX-ISOLDE facility coupled with the highly efficient MINIBALL array. Reliable B(E2,0$^{+}$ $\\rightarrow$ 2$^{+}$) values for $^{30,32}$Mg were obtained at ISOLDE. Together with recent new results on $^{31}$Mg, collective and single particle properties are probed for Z=12 at the N=20 neutron closed shell, the 'island of inversion'. We would like to extend this knowledge to the neighbouring $^{28,29,30}$Na isotopes where a different transition from the usual filling of the neutron levels into the region with low lying 2p-2h cross shell configurations is predicted by theory. Detailed theoretical predictions on the transition strength in all three Na nuclei are awaiting experimental verification and are the subject of this proposal. At REX beam energies of 3.0 MeV /nucleon the cross-sections for Coulomb excitation are sufficient. Moreover the results from the close-by $^{30,31,32}$Mg nuclei de...
Butler, P; Bastin, B; Kruecken, R; Voulot, D; Rahkila, P J; Orr, N A; Srebrny, J; Grahn, T; Clement, E; Paul, E S; Gernhaeuser, R A; Dorsival, A; Diriken, J V J; Huyse, M L; Iwanicki, J S
The neutron-deficient polonium isotopes with two protons outside the closed Z=82 shell represent a set of nuclei with a rich spectrum of nucleus structure phenomena. While the onset of the deformation in the light Po isotopes is well established experimentally, questions remain concerning the sign of deformation and the magnitude of the mixing between different configurations. Furthermore, controversy is present with respect to the transition from the vibrational-like character of the heavier Po isotopes to the shape coexistence mode observed in the lighter Po isotopes. We propose to study this transition in the even-mass neutron-deficient $^{198,200,202}$Po isotopes by using post-accelerated beams from REX-ISOLDE and "safe"-energy Coulomb excitation. $\\gamma$- rays will be detected by the MINIBALL array. The measurements of the Coulomb excitation differential cross section will allow us to deduce both the transition and diagonal matrix elements for these nuclei and, combined with lifetime measurements, the s...
Radiative and Excited State Charmonium Physics
Energy Technology Data Exchange (ETDEWEB)
Jozef Dudek
2007-07-30
Renewed interest in the spectroscopy of charmonium has arisen from recent unexpected observations at $e^+e^-$ colliders. Here we report on a series of works from the previous two years examining the radiative physics of charmonium states as well as the mass spectrum of states of higher spin and internal excitation. Using new techniques applied to Domain-Wall and Clover quark actions on quenched isotropic and anisotropic lattices, radiative transitions and two-photon decays are considered for the first time. Comparisons are made with experimental results and with model approaches. Forthcoming application to the light-quark sector of relevance to experiments like Jefferson Lab's GlueX is discussed.
Electron affinity and excited states of methylglyoxal
Dauletyarov, Yerbolat; Dixon, Andrew R.; Wallace, Adam A.; Sanov, Andrei
2017-07-01
Using photoelectron imaging spectroscopy, we characterized the anion of methylglyoxal (X2A″ electronic state) and three lowest electronic states of the neutral methylglyoxal molecule: the closed-shell singlet ground state (X1A'), the lowest triplet state (a3A″), and the open-shell singlet state (A1A″). The adiabatic electron affinity (EA) of the ground state, EA(X1A') = 0.87(1) eV, spectroscopically determined for the first time, compares to 1.10(2) eV for unsubstituted glyoxal. The EAs (adiabatic attachment energies) of two excited states of methylglyoxal were also determined: EA(a3A″) = 3.27(2) eV and EA(A1A″) = 3.614(9) eV. The photodetachment of the anion to each of these two states produces the neutral species near the respective structural equilibria; hence, the a3A″ ← X2A″ and A1A″ ← X2A″ photodetachment transitions are dominated by intense peaks at their respective origins. The lowest-energy photodetachment transition, on the other hand, involves significant geometry relaxation in the X1A' state, which corresponds to a 60° internal rotation of the methyl group, compared to the anion structure. Accordingly, the X1A' ← X2A″ transition is characterized as a broad, congested band, whose vertical detachment energy, VDE = 1.20(4) eV, significantly exceeds the adiabatic EA. The experimental results are in excellent agreement with the ab initio predictions using several equation-of-motion methodologies, combined with coupled-cluster theory.
Interatomic Coulombic electron capture
International Nuclear Information System (INIS)
Gokhberg, K.; Cederbaum, L. S.
2010-01-01
In a previous publication [K. Gokhberg and L. S. Cederbaum, J. Phys. B 42, 231001 (2009)] we presented the interatomic Coulombic electron capture process--an efficient electron capture mechanism by atoms and ions in the presence of an environment. In the present work we derive and discuss the mechanism in detail. We demonstrate thereby that this mechanism belongs to a family of interatomic electron capture processes driven by electron correlation. In these processes the excess energy released in the capture event is transferred to the environment and used to ionize (or to excite) it. This family includes the processes where the capture is into the lowest or into an excited unoccupied orbital of an atom or ion and proceeds in step with the ionization (or excitation) of the environment, as well as the process where an intermediate autoionizing excited resonance state is formed in the capturing center which subsequently deexcites to a stable state transferring its excess energy to the environment. Detailed derivation of the asymptotic cross sections of these processes is presented. The derived expressions make clear that the environment assisted capture processes can be important for many systems. Illustrative examples are presented for a number of model systems for which the data needed to construct the various capture cross sections are available in the literature.
International Nuclear Information System (INIS)
Chen Changyuan; Sun Dongsheng; Lu Falin
2004-01-01
Properties of scattering states of the Klein-Gordon equation with Coulomb-like scalar plus vector potentials are investigated in an arbitrary dimension. Exact results of normalized wave functions of scattering states in the 'k/2π scale' and formula of phase shifts are presented
Role of the Coulomb interaction in the low-frequency density of states of DNA double helices
International Nuclear Information System (INIS)
Garcia, A.E.; Krumhansl, J.A.
1988-01-01
The complete vibrational frequency spectrum of several DNA double-helical oligomers is calculated using established pair potentials. Various cutoff values are used for the range of the Coulomb interactions. At very low frequency the integrated density of states shows a noninteger exponent with values ranging from 0.75 to 1.55, depending on the cutoff value for the Coulomb interactions. We conclude that the cumulative densities of states in those molecules depend more on competing interactions than on various proposed universal laws
McClarty, P. A.; O'Brien, A.; Pollmann, F.
2014-05-01
We consider a classical model of charges ±q on a pyrochlore lattice in the presence of long-range Coulomb interactions. This model first appeared in the early literature on charge order in magnetite [P. W. Anderson, Phys. Rev. 102, 1008 (1956), 10.1103/PhysRev.102.1008]. In the limit where the interactions become short ranged, the model has a ground state with an extensive entropy and dipolar charge-charge correlations. When long-range interactions are introduced, the exact degeneracy is broken. We study the thermodynamics of the model and show the presence of a correlated charge liquid within a temperature window in which the physics is well described as a liquid of screened charged defects. The structure factor in this phase, which has smeared pinch points at the reciprocal lattice points, may be used to detect charge ice experimentally. In addition, the model exhibits fractionally charged excitations ±q/2 which are shown to interact via a 1/r potential. At lower temperatures, the model exhibits a transition to a long-range ordered phase. We are able to treat the Coulombic charge ice model and the dipolar spin ice model on an equal footing by mapping both to a constrained charge model on the diamond lattice. We find that states of the two ice models are related by a staggering field which is reflected in the energetics of these two models. From this perspective, we can understand the origin of the spin ice and charge ice ground states as coming from a dipolar model on a diamond lattice. We study the properties of charge ice in an external electric field, finding that the correlated liquid is robust to the presence of a field in contrast to the case of spin ice in a magnetic field. Finally, we comment on the transport properties of Coulombic charge ice in the correlated liquid phase.
Gebremedhin, Daniel H; Weatherford, Charles A
2015-02-01
This is a response to the comment we received on our recent paper "Calculations for the one-dimensional soft Coulomb problem and the hard Coulomb limit." In that paper, we introduced a computational algorithm that is appropriate for solving stiff initial value problems, and which we applied to the one-dimensional time-independent Schrödinger equation with a soft Coulomb potential. We solved for the eigenpairs using a shooting method and hence turned it into an initial value problem. In particular, we examined the behavior of the eigenpairs as the softening parameter approached zero (hard Coulomb limit). The commenters question the existence of the ground state of the hard Coulomb potential, which we inferred by extrapolation of the softening parameter to zero. A key distinction between the commenters' approach and ours is that they consider only the half-line while we considered the entire x axis. Based on mathematical considerations, the commenters consider only a vanishing solution function at the origin, and they question our conclusion that the ground state of the hard Coulomb potential exists. The ground state we inferred resembles a δ(x), and hence it cannot even be addressed based on their argument. For the excited states, there is agreement with the fact that the particle is always excluded from the origin. Our discussion with regard to the symmetry of the excited states is an extrapolation of the soft Coulomb case and is further explained herein.
Identification of excited states in conjugated polymers
International Nuclear Information System (INIS)
Hartwell, Lewis John
2003-01-01
This thesis reports quasi steady state photoinduced absorption measurements from three conjugated polymers: polypyridine (PPy), polyfluorene (PFO) and the emeraldine base (EB) form of polyaniline. The aim of these experiments was to determine the nature of the photoexcited states existing in these materials in the millisecond time domain, as this has important consequences for the operation of real devices manufactured using these materials. The results from the photoinduced absorption experiments are closely compared with published results from pulse radiolysis experiments. In all cases there is very good correspondence between the two data sets, which has enabled the photoexcited states to be assigned with a high degree of confidence. Quasi steady-state photoinduced absorption involves the measurement of the change in absorption of a material in response to optical excitation with a laser beam. The changes in absorption are small, so a dedicated instrument was developed and optimised for each different sample. Lock-in techniques were used to recover the small signals from the samples. The samples involved were thin films of the polymer spin coated onto sapphire substrates in the cases of PPy and EB. Solution state experiments were conducted on EB. The experiments on PFO were conducted on aligned and unaligned thin films provided by Sony. In the case of the aligned PFO samples, the photoinduced absorption spectrometer was modified to enable polarisation-sensitive data collection. In PPy, both triplet excitons and polarons have been shown to be long-lived photoexcitations, with photoinduced absorption features at 2.29 eV (triplet exciton transition), 1.5 eV and 0.8 eV (polaron transitions). In PFO, the one observed photoinduced band at 1.52 eV is assigned to a triplet exciton. Two photoinduced absorption bands are observed in EB, at 1.4 eV and 0.8 eV. These are assigned to a self-trapped CT singlet exciton and triplet exciton, respectively. (author)
Application of Stochastic variational method with correlated Ground States to coulombic systems
Energy Technology Data Exchange (ETDEWEB)
Usukura, Junko; Suzuki, Yasuyuki [Niigata Univ. (Japan); Varga, K.
1998-07-01
Positronium molecule, Ps{sub 2} has not been found experimentally yet, and it has been believed theoretically that Ps{sub 2} has only one bound state with L = 0. We predicted the existence of new bound state of Ps{sub 2}, which is the excited state with L = 1 and comes from Pauli principle, by Stochastic variational method. There are two decay mode with respect to Ps{sub 2}(P); one is pair annihilation and another is electric dipole (E1) transition to the ground state. While it is difficult to tell {gamma}-ray caused by annihilation of Ps{sub 2} from that of Ps since both of them have same energy, Energy (4.94 eV) of the photon emitted in E1 transition is specific enough to distinguish from other spectra. Then the excited state is one of clues to observe Ps{sub 2}. (author)
Process to produce excited states of atomic nuclei
International Nuclear Information System (INIS)
Morita, M.; Morita, R.
The claims of a patented process which relates to the production of excited states of atomic nuclei are outlined. Among these are (1) production of nuclear excited states by bombarding the atoms with x rays or electrons under given conditions, (2) production of radioactive substances by nuclear excitation with x rays or electrons, (3) separation of specific isotopes from a mixture of isotopes of the same element by means of nuclear excitation followed by chemical treatment. The invention allows production of excited states of atomic nuclei in a relatively simple manner without the need of large apparatus and equipment
Butler, P; Voulot, D; Rahkila, P J; Darby, I G; Grahn, T; Bree, N C F; Julin, R J; Diriken, J V J; Jenkins, D G; Kroell, T; Huyse, M L
In regions near magic nuclei, seniority can be regarded as a good quantum number. In the N = 122 isotones above the Z = 82 shell closure relative high-$\\textit{j}\\,$ single-particle proton orbitals dominate the structure and thus levels up to $\\textit{I}$ = 2$\\textit{j}$ - 1 could, in principle, be understood within the seniority scheme. While B(E2) values usually increase within the band with increasing $\\textit{I}$, the seniority scheme can lead to a contrasting result. The present proposal addresses this phenomenon through the measurements of previously unknown B(E2; 0$^{+}\\rightarrow$ 2$^{+}$) values in $^{206}$Po and $^{208}$Rn. The proposed Coulomb excitation measurements of radioactive beams will be carried out at the REX-ISOLDE facility using the MINIBALL $\\gamma$-ray spectrometer.
Characterization of weakly excited final states by shakedown spectroscopy of laser-excited potassium
International Nuclear Information System (INIS)
Schulz, J.; Heinaesmaeki, S.; Aksela, S.; Aksela, H.; Sankari, R.; Rander, T.; Lindblad, A.; Bergersen, H.; Oehrwall, G.; Svensson, S.; Kukk, E.
2006-01-01
3p shakedown spectra of laser excited potassium atoms as well as direct 3p photoemission of ground state potassium have been studied. These two excitation schemes lead to the same final states and thereby provide a good basis for a detailed study of the 3p 5 (4s3d) 1 configurations of singly ionized potassium and the photoemission processes leading to these configurations. The comparison of direct photoemission from the ground state and conjugate shakedown spectra from 4p 1/2 laser excited potassium made it possible to experimentally determine the character of final states that are only weakly excited in the direct photoemission but have a much higher relative intensity in the shakedown spectrum. Based on considerations of angular momentum and parity conservation the excitation scheme of the final states can be understood
The quadrupole moment of the first excited state of 18O
International Nuclear Information System (INIS)
Fewel, M.P.; Baxter, A.M.; Kean, D.C.; Spear, R.H.
1976-11-01
Using the re-orientation effect in Coulomb excitation, the quadrupole moment, Qsub(2 + ), of the first excited state of 18 O is found to be -0.100 +- 0.030 eb. The analysis assumes, on the basis of previous measurements, that B(E2; 0 + → 2 + ) = 0.0044 +- 0.0004 e 2 b 2 . A correction (+0.032 eb) for the effect of the giant dipole resonance, based on the hydrodynamic model, has been applied. Evidence is presented that some other determinations of Qsub(2 + ) were performed at too high a bombarding energy. The present value of Qsub(2 + ) is smaller in magnitude than that reported by Kleinfeld et al. (1975), but remains larger than the value of -0.034 eb predicted by a recent shell-model calculation. (Author)
Molecular excited states from the SCAN functional
Tozer, David J.; Peach, Michael J. G.
2018-06-01
The performance of the strongly constrained and appropriately normed (SCAN) meta-generalised gradient approximation exchange-correlation functional is investigated for the calculation of time-dependent density-functional theory molecular excitation energies of local, charge-transfer and Rydberg character, together with the excited ? potential energy curve in H2. The SCAN results frequently resemble those obtained using a global hybrid functional, with either a standard or increased fraction of exact orbital exchange. For local excitations, SCAN can exhibit significant triplet instability problems, resulting in imaginary triplet excitation energies for a number of cases. The Tamm-Dancoff approximation offers a simple approach to improve the situation, but the excitation energies are still significantly underestimated. Understanding the origin of these (near)-triplet instabilities may provide useful insight into future functional development.
Vibronic coupling in the excited-states of carotenoids
Energy Technology Data Exchange (ETDEWEB)
Miki, Takeshi [Physikalisch-Chemisches Institut; Ruprecht-Karls-Universität Heidelberg; D-69120 Heidelberg; Germany; Buckup, Tiago [Physikalisch-Chemisches Institut; Ruprecht-Karls-Universität Heidelberg; D-69120 Heidelberg; Germany; Krause, Marie S. [Physikalisch-Chemisches Institut; Ruprecht-Karls-Universität Heidelberg; D-69120 Heidelberg; Germany; Southall, June [College of Medical; Veterinary, and Life Science; University of Glasgow; G12 8QQ Glasgow; UK; Cogdell, Richard J. [College of Medical; Veterinary, and Life Science; University of Glasgow; G12 8QQ Glasgow; UK; Motzkus, Marcus [Physikalisch-Chemisches Institut; Ruprecht-Karls-Universität Heidelberg; D-69120 Heidelberg; Germany
2016-01-01
The ultrafast femtochemistry of carotenoids is governed by the interaction between electronic excited states, which has been explained by the relaxation dynamics within a few hundred femtoseconds from the lowest optically allowed excited state S_{2}to the optically dark state S_{1}.
Shell structure in the vicinity of the doubly magic {sup 100}Sn via Coulomb excitation at PreSPEC
Energy Technology Data Exchange (ETDEWEB)
Guastalla, Giulia
2014-11-17
The PreSPEC setup in combination with the high intensity primary beams available at GSI provided unique opportunities for the key nuclear structure studies on exotic nuclei. The experiment performed on the neutron deficient {sup 104}Sn aimed to deduce the reduced transition probability of the first excited 2{sup +} state quantified by the B(E2; 0{sup +} → 2{sup +}) value. This result is the central point in the discussion of the evolution of nuclear structure in proximity of the doubly magic nucleus {sup 100}Sn. As {sup 100}Sn is not yet accessible for such measurements, a series of experiments have been performed for neutron-deficient Sn isotopes over the past few years. These data showed excessive experimental B(E2) strength compared to shell model calculations below neutron number N=64 and they are therefore not excluding a constant or even increasing collectivity below {sup 106}Sn. Hence, the measurement of the B(E2) value in the next even-even isotope toward {sup 100}Sn, i.e. {sup 104}Sn, was a crucial step to verify the robustness of the shell gap of {sup 100}Sn. Moreover, {sup 104}Sn is the heaviest isotope of the Sn isotopic chain for which a shell model calculation without significant truncation of the valence space can be performed and therefore with this experimental value the validity of Large Scale Shell Model (LSSM) calculations could be tested. As a main result of the experiment a B(E2) value corresponding to 0.10(4) e{sup 2}b{sup 2} has been extracted for {sup 104}Sn. The experimental value showed a very good agreement with the predicted one and, despite the large error bar, it clearly established a downward trend of the B(E2) values of the Sn isotopic chain toward A=100. This implied enhanced stability of the N = Z = 50 shell closure against ph-excited quadrupole modes. However, an experiment of this kind is very challenging for several reasons. First, {sup 104}Sn lies in proximity of the proton drip line and has therefore a small production
Coupled state analysis of electron excitations in asymmetric collision systems
International Nuclear Information System (INIS)
Mehler, G.; Reus, T. de; Mueller, U.; Reinhardt, J.; Mueller, B.; Greiner, W.; Soff, G.
1985-01-01
A coupled channel formalism is presented, using relativistic basis states of the target atom. Screening effects are incorporated by means of an effective potential of Hartree-Fock-Slater type. Relativistic wave packets are employed for the description of the continuum. The impact parameter dependence of the K-hole production in p-Ag collisions is calculated, including quadrupole contributions of the projectile Coulomb potential. The results are compared with experimental data. (orig.)
The triplet excited state of Bodipy: formation, modulation and application.
Zhao, Jianzhang; Xu, Kejing; Yang, Wenbo; Wang, Zhijia; Zhong, Fangfang
2015-12-21
Boron dipyrromethene (Bodipy) is one of the most extensively investigated organic chromophores. Most of the investigations are focused on the singlet excited state of Bodipy, such as fluorescence. In stark contrast, the study of the triplet excited state of Bodipy is limited, but it is an emerging area, since the triplet state of Bodipy is tremendously important for several areas, such as the fundamental photochemistry study, photodynamic therapy (PDT), photocatalysis and triplet-triplet annihilation (TTA) upconversion. The recent developments in the study of the production, modulation and application of the triplet excited state of Bodipy are discussed in this review article. The formation of the triplet state of Bodipy upon photoexcitation, via the well known approach such as the heavy atom effect (including I, Br, Ru, Ir, etc.), and the new methods, such as using a spin converter (e.g. C60), charge recombination, exciton coupling and the doubly substituted excited state, are summarized. All the Bodipy-based triplet photosensitizers show strong absorption of visible or near IR light and the long-lived triplet excited state, which are important for the application of the triplet excited state in PDT or photocatalysis. Moreover, the methods for switching (or modulation) of the triplet excited state of Bodipy were discussed, such as those based on the photo-induced electron transfer (PET), by controlling the competing Förster-resonance-energy-transfer (FRET), or the intermolecular charge transfer (ICT). Controlling the triplet excited state will give functional molecules such as activatable PDT reagents or molecular devices. It is worth noting that switching of the singlet excited state and the triplet state of Bodipy may follow different principles. Application of the triplet excited state of Bodipy in PDT, hydrogen (H2) production, photoredox catalytic organic reactions and TTA upconversion were discussed. The challenges and the opportunities in these areas were
Inelastic scattering of {sup 9}Li and excitation mechanism of its first excited state
Energy Technology Data Exchange (ETDEWEB)
Al Falou, H. [Astronomy and Physics Department, Saint Mary' s University, Halifax, Nova Scotia B3H 3C3 (Canada); TRIUMF, Vancouver, British Columbia V6T 2A3 (Canada); Kanungo, R., E-mail: ritu@triumf.ca [Astronomy and Physics Department, Saint Mary' s University, Halifax, Nova Scotia B3H 3C3 (Canada); Andreoiu, C.; Cross, D.S. [Department of Chemistry, Simon Fraser University, Burnaby, British Columbia V5A 1S6 (Canada); Davids, B.; Djongolov, M. [TRIUMF, Vancouver, British Columbia V6T 2A3 (Canada); Gallant, A.T. [TRIUMF, Vancouver, British Columbia V6T 2A3 (Canada); Department of Physics, University of British Columbia, British Columbia V6T 1Z4 (Canada); Galinski, N.; Howell, D. [TRIUMF, Vancouver, British Columbia V6T 2A3 (Canada); Department of Physics, Simon Fraser University, Burnaby, British Columbia V5A 1S6 (Canada); Kshetri, R.; Niamir, D. [TRIUMF, Vancouver, British Columbia V6T 2A3 (Canada); Orce, J.N. [TRIUMF, Vancouver, British Columbia V6T 2A3 (Canada); Department of Physics, University of the Western Cape, P/B X17, Bellville, ZA-7535 (South Africa); Shotter, A.C. [Department of Physics and Astronomy, University of Edinburgh, Edinburgh (United Kingdom); Sjue, S. [TRIUMF, Vancouver, British Columbia V6T 2A3 (Canada); Tanihata, I. [Research Center for Nuclear Physics, Osaka University, Mihogaoka, Ibaraki, Osaka 567 0047 (Japan); Thompson, I.J. [Lawrence Livermore National Laboratory, Livermore, CA 94551 (United States); Triambak, S. [TRIUMF, Vancouver, British Columbia V6T 2A3 (Canada); Uchida, M. [Astronomy and Physics Department, Saint Mary' s University, Halifax, Nova Scotia B3H 3C3 (Canada); Walden, P. [TRIUMF, Vancouver, British Columbia V6T 2A3 (Canada); Wiringa, R.B. [Physics Division, Argonne National Laboratory, Argonne, IL 60439 (United States)
2013-04-25
The first measurement of inelastic scattering of {sup 9}Li from deuterons at the ISAC facility is reported. The measured angular distribution for the first excited state confirms the nature of excitation to be an E2 transition. The quadrupole deformation parameter is extracted from an analysis of the angular distribution.
Inelastic scattering of 9Li and excitation mechanism of its first excited state
International Nuclear Information System (INIS)
Al Falou, H.; Kanungo, R.; Andreoiu, C.; Cross, D.S.; Davids, B.; Djongolov, M.; Gallant, A.T.; Galinski, N.; Howell, D.; Kshetri, R.; Niamir, D.; Orce, J.N.; Shotter, A.C.; Sjue, S.; Tanihata, I.; Thompson, I.J.; Triambak, S.; Uchida, M.; Walden, P.; Wiringa, R.B.
2013-01-01
The first measurement of inelastic scattering of 9 Li from deuterons at the ISAC facility is reported. The measured angular distribution for the first excited state confirms the nature of excitation to be an E2 transition. The quadrupole deformation parameter is extracted from an analysis of the angular distribution
DILEPTON YIELD FROM THE DECAY OF EXCITED SI-28 STATES
BACELAR, JC; BUDA, A; BALANDA, A; KRASZNAHORKAY, A; VANDERPLOEG, H; SUJKOWSKI, Z; VANDERWOUDE, A
1994-01-01
The first dilepton yield measurements from excited nuclear states obtained with a new Positron-Electron Pair Spectroscopic Instrument (PEPSI) are reported. Nuclear states in Si-28, with an initial excitation energy E* = 50 MeV, were populated via the isospin T = 0 reaction He-4 + Mg-24 and the
Study of a Quantum Dot in an Excited State
Slamet, Marlina; Sahni, Viraht
We have studied the first excited singlet state of a quantum dot via quantal density functional theory (QDFT). The quantum dot is represented by a 2D Hooke's atom in an external magnetostatic field. The QDFT mapping is from an excited singlet state of this interacting system to one of noninteracting fermions in a singlet ground state. The results of the study will be compared to (a) the corresponding mapping from a ground state of the quantum dot and (b) to the similar mapping from an excited singlet state of the 3D Hooke's atom.
Ultrafast excited state relaxation in long-chain polyenes
International Nuclear Information System (INIS)
Antognazza, Maria Rosa; Lueer, Larry; Polli, Dario; Christensen, Ronald L.; Schrock, Richard R.; Lanzani, Guglielmo; Cerullo, Giulio
2010-01-01
Graphical abstract: Excited state dynamics of a long-chain polyene studied by femtosecond pump-probe spectroscopy. - Abstract: We present a comprehensive study, by femtosecond pump-probe spectroscopy, of excited state dynamics in a polyene that approaches the infinite chain limit. By excitation with sub-10-fs pulses resonant with the 0-0 S 0 → S 2 transition, we observe rapid loss of stimulated emission from the bright excited state S 2 , followed by population of the hot S 1 state within 150 fs. Vibrational cooling of S 1 takes place within 500 fs and is followed by decay back to S 0 with 1 ps time constant. By excitation with excess vibrational energy we also observe the ultrafast formation of a long-living absorption, that is assigned to the triplet state generated by singlet fission.
Nonadiabatic excited-state molecular dynamics: On-the-fly limiting of essential excited states
Energy Technology Data Exchange (ETDEWEB)
Nelson, Tammie [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Naumov, Artem [Skolkovo Institute of Science and Technology, Moscow 143026 (Russian Federation); Fernandez-Alberti, Sebastian [Universidad Nacional de Quilmes, Roque Saenz Pea 352, B1876BXD Bernal (Argentina); Tretiak, Sergei, E-mail: serg@lanl.gov [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States)
2016-12-20
The simulation of nonadiabatic dynamics in extended molecular systems involving hundreds of atoms and large densities of states is particularly challenging. Nonadiabatic coupling terms (NACTs) represent a significant numerical bottleneck in surface hopping approaches. Rather than using unreliable NACT cutting schemes, here we develop “on-the-fly” state limiting methods to eliminate states that are no longer essential for the non-radiative relaxation dynamics as a trajectory proceeds. We propose a state number criteria and an energy-based state limit. The latter is more physically relevant by requiring a user-imposed energy threshold. For this purpose, we introduce a local kinetic energy gauge by summing contributions from atoms within the spatial localization of the electronic wavefunction to define the energy available for upward hops. The proposed state limiting schemes are implemented within the nonadiabatic excited-state molecular dynamics framework to simulate photoinduced relaxation in poly-phenylene vinylene (PPV) and branched poly-phenylene ethynylene (PPE) oligomers for benchmark evaluation.
Coulomb singularities in scattering wave functions of spin-orbit-coupled states
International Nuclear Information System (INIS)
Bogdanski, P.; Ouerdane, H.
2011-01-01
We report on our analysis of the Coulomb singularity problem in the frame of the coupled channel scattering theory including spin-orbit interaction. We assume that the coupling between the partial wave components involves orbital angular momenta such that Δl= 0, ±2. In these conditions, the two radial functions, components of a partial wave associated to two values of the angular momentum l, satisfy a system of two second-order ordinary differential equations. We examine the difficulties arising in the analysis of the behavior of the regular solutions near the origin because of this coupling. First, we demonstrate that for a singularity of the first kind in the potential, one of the solutions is not amenable to a power series expansion. The use of the Lippmann-Schwinger equations confirms this fact: a logarithmic divergence arises at the second iteration. To overcome this difficulty, we introduce two auxilliary functions which, together with the two radial functions, satisfy a system of four first-order differential equations. The reduction of the order of the differential system enables us to use a matrix-based approach, which generalizes the standard Frobenius method. We illustrate our analysis with numerical calculations of coupled scattering wave functions in a solid-state system.
Electronic properties of excited states in single InAs quantum dots
International Nuclear Information System (INIS)
Warming, Till
2009-01-01
The application of quantum-mechanical effects in semiconductor nanostructures enables the realization of novel opto-electronic devices. Examples are given by single-photon emitters and emitters of entangled photon pairs, both being essential for quantum cryptography, or for qubit systems as needed for quantum computing. InAs/GaAs quantum dots are one of the most promising candidates for such applications. A detailed knowledge of the electronic properties of quantum dots is a prerequisite for this development. The aim of this work is an experimental access to the detailed electronic structure of the excited states in single InAs/GaAs quantum dots including few-particle effects and in particular exchange interaction. The experimental approach is micro photoluminescence excitation spectroscopy (μPLE). One of the main difficulties using μPLE to probe single QDs is the unambiguous assignment of the observed resonances in the spectrum to specific transitions. By comparing micro photoluminescence (μPL) and μPLE spectra, the identification of the main resonances becomes possible. The key is given by the fine structure of the hot trion. Excitation spectroscopy on single charged QDs enables for the first time the complete observation of a non-trivial fine structure of an excitonic complex in a QD, the hot trion. Modelling based on eight-band k.p theory in combination with a configuration interaction scheme is in excellent agreement. Therewith the simulation also enables realistic predictions on the fine structure of the ground-state exciton which is of large importance for single quantum dot devices. Theory concludes from the observed transitions that the structural symmetry of the QDs is broken. Micro photoluminescence excitation spectroscopy combined with resonantly excited micro photoluminescence enables an optical access to the single particle states of the hole without the influence of few-particle coulomb interactions. Based on this knowledge the exciton binding
Direct conversion of graphite into diamond through electronic excited states
Nakayama, H
2003-01-01
An ab initio total energy calculation has been performed for electronic excited states in diamond and rhombohedral graphite by the full-potential linearized augmented plane wave method within the framework of the local density approximation (LDA). First, calculations for the core-excited state in diamond have been performed to show that the ab initio calculations based on the LDA describe the wavefunctions in the electronic excited states as well as in the ground state quite well. Fairly good coincidence with both experimental data and theoretical prediction has been obtained for the lattice relaxation of the core exciton state. The results of the core exciton state are compared with nitrogen-doped diamond. Next, the structural stability of rhombohedral graphite has been investigated to examine the possibility of the transition into the diamond structure through electronic excited states. While maintaining the rhombohedral symmetry, rhombohedral graphite can be spontaneously transformed to cubic diamond. Tota...
Unitary Pole Approximation For 16O S12state And 40ca P32state When Coulomb Interaction Is Included
Directory of Open Access Journals (Sweden)
A. Acharya
2015-08-01
Full Text Available Abstract The form factor of a separable interaction between a pair of particles is an important input in a three body calculation for a transfer reaction. The three body equations of Alt Grassberger and Sandhas have been solved for a system of three particles viz.p n and 16Oand p n and 40Ca when coulomb interaction is included between the particle pairs. The input in this calculation i.e. the two body t-matrices representing the interaction between the pairs of particles is taken to be of a separable form conforming to the bound state of the pair. The form factors of the total interaction between the particle pairs are constructed using the prescription of Ueta and Bund.
Systematics in Rydberg state excitations for ion-atom collisions
International Nuclear Information System (INIS)
Andresen, B.; Jensen, K.; Petersen, N.B.; Veje, E.
1976-01-01
Rydberg state excitations in the Ne + , Mg + -He collisions have been studied in the projectile energy range 10-75 keV by means of optical spectrometry in a search for systematic trends. The relative excitation cross sections for levels of a Rydberg term series are found to follow a general (nsup(x))sup(P) behaviour with P < approximately -3 varying with collision energy and particles, regardless of whether the excited state population results from direct excitation, single electron transfer, or double electron transfer. At higher collision energies P is approximately -3 as predicted by theory. Polarization of the emitted line radiation indicates that there is no general rule for the relative excitation of the different magnetic substates of the same level. A statistical distribution of excitation is found for levels within the same term when the fine structure splitting is small. (Auth.)
Kinetics studies following state-selective laser excitation
International Nuclear Information System (INIS)
Keto, J.W.
1994-04-01
The objective of this contract was the study of state-to-state, electronic energy transfer reactions relevant to the excited state chemistry observed in discharges. We studied deactivation reactions and excitation transfer in collisions of excited states of xenon and krypton atoms with Ar, Kr, Xe and chlorine. The reactant states were excited selectively in two-photon transitions using tunable u.v. and v.u.v. lasers. Excited states produced by the collision were observed by their fluorescence. Reaction rates were measured by observing the time dependent decay of signals from reactant and product channels. In addition we measured interaction potentials of the reactants by laser spectroscopy where the laser induced fluorescence or ionization is measured as a function of laser wavelength (excitation spectra) or by measuring fluorescence spectra at fixed laser frequencies with monochromators. The spectra were obtained in the form of either lineshapes or individual lines from rovibrational transitions of bound states. Our research then required several categories of experiments in order to fully understand a reaction process: 1. High resolution laser spectroscopy of bound molecules or lineshapes of colliding pairs is used to determine potential curves for reactants. 2. Direct measurements of state-to-state reaction rates were measured by studying the time dependent loss of excited reactants and the time dependent formation of products. 3. The energy selectivity of a laser can be used to excite reactants on an excited surface with controlled internuclear configurations. For free states of reactants (as exist in a gas cell) this has been termed laser assisted reactions, while for initially bound states (as chemically bound reactants or dimers formed in supersonic beams) the experiments have been termed photo-fragmentation spectroscopy
Excitation of spin-1 states in 166168170Er using bremsstrahlung
International Nuclear Information System (INIS)
Metzger, F.R.
1976-01-01
Some 40 states in 166 , 168 , 170 Er, most of them previously unknown, have been excited using bremsstrahlung with < or =4.2 MeV endpoint energy. For all but three of these levels, the angular distribution of the resonantly scattered radiation favors the assignment of spin 1. For some of the strongly excited levels, linear polarization measurements have been performed. They indicate that these levels have positive parity. The branching ratios further characterize them as K=1 excitations
Doubly excited P-wave resonance states of H− in Debye plasmas
International Nuclear Information System (INIS)
Jiao, L. G.; Ho, Y. K.
2013-01-01
We investigate the doubly excited P-wave resonance states of H − system in Debye plasmas modeled by static screened Coulomb potentials. The screening effects of the plasma environment on resonance parameters (energy and width) are investigated by employing the complex-scaling method with Hylleraas-type wave functions for both the shape and Feshbach resonances associated with the H(N = 2 to 6) thresholds. Under the screening conditions, the H(N) threshold states are no longer l degenerate, and all the H − resonance energy levels are shifted away from their unscreened values toward the continuum. The influence of Debye plasmas on resonance widths has also been investigated. The shape resonance widths are broadened with increasing plasma screening strength, whereas the Feshbach resonance widths would generally decrease. Our results associated with the H(N = 2) and H(N = 3) thresholds are compared with others in the literature
Excited states configurations of the quantum Toda lattice
International Nuclear Information System (INIS)
Matsuyama, A.
2001-01-01
Excited states configurations of the quantum Toda lattice are studied by the direct diagonalization of the Hamiltonian. The most probable configurations of one-hole and one-particle excitations are shown to be similar to the profiles of classical phonon and soliton excitations, respectively. One-hole excitation states, which are always ground states of definite E m -symmetry of the dihedral group D N , change those structures abruptly with the potential range varied. One-particle excitations, which are buried in complicated excitation spectra, have well-defined configurations similar to the conoidal profile of the classical periodic Toda lattice. The relationship that the hole (particle) excitations in quantum mechanics correspond to the phonon (soliton) excitations in classical mechanics, which has been suggested based on the similarity of dispersion relations, is confirmed in a geometrically understandable way. Based on the study of one-soliton and two-soliton states, the structure of multi-soliton states in quantum mechanics can be conjectured
Particle decay of (12)Be excited states
Charity, R. J.; Komarov, S. A.; Sobotka, L. G.; Clifford, J.; Bazin, D.; Gade, A.; Lee, Jenny; Lukyanov, S. M.; Lynch, W. G.; Mocko, M.; Lobastov, S. P.; Rogers, A. M.; Sanetullaev, A.; Tsang, M. B.; Wallace, M. S.; Hudan, S.; Metelko, C.; Famiano, M. A.; Wuosmaa, A. H.; van Goethem, M. J.
2007-01-01
The breakup of E/A=50 MeV (12)Be fragments following inelastic scattering off of hydrogen and carbon target nuclei has been studied. The breakup channels alpha+(8)He, (6)He+(6)He, t+(9)Li, and p+(11)Li were observed. Two doublets at excitation energies of 12.8 and 15.5 MeV were found for the
Coherent excitation of a single atom to a Rydberg state
DEFF Research Database (Denmark)
Miroshnychenko, Yevhen; Gaëtan, Alpha; Evellin, Charles
2010-01-01
We present the coherent excitation of a single Rubidium atom to the Rydberg state 58d3/2 using a two-photon transition. The experimental setup is described in detail, as are experimental techniques and procedures. The coherence of the excitation is revealed by observing Rabi oscillations between...
Anisotropy of electronic states excited in ion-atom collisions
International Nuclear Information System (INIS)
Boskamp, E.B.
1983-01-01
The author reports coincidence measurements made on the He + + Ne and He + + He systems. The complex population amplitudes for the magnetic sublevels of the investigated excited states, Ne(2p 4 3s 2 ) 1 D and He(2p 2 ) 1 D, were completely determined and possible excitation mechanisms are described. (Auth.)
Excitation of lowest electronic states of thymine by slow electrons
Chernyshova, I. V.; Kontros, E. J.; Markush, P. P.; Shpenik, O. B.
2013-11-01
Excitation of lowest electronic states of the thymine molecules in the gas phase is studied by elec- tron energy loss spectroscopy. In addition to dipole-allowed transitions to singlet states, transitions to the lowest triplet states were observed. The low-energy features of the spectrum at 3.66 and 4.61 eV are identified with the excitation of the first triplet states 13 A' (π → π*) and 13 A″ ( n → π*). The higher-lying features at 4.96, 5.75, 6.17, and 7.35 eV are assigned mainly to the excitation of the π → π* transitions to the singlet states of the molecule. The excitation dynamics of the lowest states is studied. It is found that the first triplet state 13 A'(π → π*) is most efficiently excited at a residual energy close to zero, while the singlet 21 A'(π → π*) state is excited with almost identical efficiency at different residual energies.
2002-01-01
We propose to perform Coulomb excitation experiments of neutron-rich nuclei in the vicinity of $^{68}$Ni towards $^{78}$Ni using the REX-ISOLDE facility coupled with the highly efficient MINIBALL array. Major changes in the structure of the atomic nucleus are expected around the N = 40 subshell closure. Recent B(E2) measurements suggested that $^{68}$Ni behaves like a doubly magic nucleus while neutron-rich Zn isotopes with N>38 exhibit a sudden increase of B(E2) values which may be the signature of deformation. We would like to check and test these predictions for neutron-rich nuclei in the vicinity of N = 40 and N = 50 shell closures like $^{72}$Zn, $^{74}$Zn, $^{76}$Zn, $^{68}$Ni, $^{70}$Ni. Our calculations show that an energy upgrade from 2.2 to 3 MeV/nucleon will be of crucial importance for a part of our study while some nuclei can still be very efficiently studied at an energy of 2.2 MeV/nucleon. Therefore, to perform our experiment in an efficient way, we request 21 shifts of beam time before the ene...
A note on calm excited states of inflation
International Nuclear Information System (INIS)
Ashoorioon, Amjad; Shiu, Gary
2011-01-01
We identify a two-parameter family of excited states within slow-roll inflation for which either the corrections to the two-point function or the characteristic signatures of excited states in the three-point function — i.e. the enhancement for the flattened momenta configurations– are absent. These excited states may nonetheless violate the adiabaticity condition maximally. We dub these initial states of inflation calm excited states. We show that these two sets do not intersect, i.e., those that leave the power-spectrum invariant can be distinguished from their bispectra, and vice versa. The same set of calm excited states that leave the two-point function invariant for slow-roll inflation, do the same task for DBI inflation. However, at the level of three-point function, the calm excited states whose flattened configuration signature is absent for slow-roll inflation, will lead to an enhancement for DBI inflation generally, although the signature is smaller than what suggested by earlier analysis. This example also illustrates that imposing the Wronskian condition is important for obtaining a correct estimate of the non-Gaussian signatures
Electron-impact excitation and ionization cross sections for ground state and excited helium atoms
International Nuclear Information System (INIS)
Ralchenko, Yu.; Janev, R.K.; Kato, T.; Fursa, D.V.; Bray, I.; Heer, F.J. de
2008-01-01
Comprehensive and critically assessed cross sections for the electron-impact excitation and ionization of ground state and excited helium atoms are presented. All states (atomic terms) with n≤4 are treated individually, while the states with n≥5 are considered degenerate. For the processes involving transitions to and from n≥5 levels, suitable cross section scaling relations are presented. For a large number of transitions, from both ground and excited states, convergent close coupling calculations were performed to achieve a high accuracy of the data. The evaluated/recommended cross section data are presented by analytic fit functions, which preserve the correct asymptotic behavior of the cross sections. The cross sections are also displayed in graphical form
Doubly and triply excited states for different plasma sources
International Nuclear Information System (INIS)
More, R.M.; Safronova, U.I.
2000-01-01
Autoionizing rates of doubly excited states as nln'l' configurations with n=2-9 and n'=2-9 are calculated. Analytical expressions of decay amplitude for two-electron system are derived. Expressions for autoionizing rates with averaging over LS are obtained for many-electron systems. The n and l dependence of doubly excited states as nln'l' configurations are investigated. (author)
Does the excited state of the 3He nucleus exist?
International Nuclear Information System (INIS)
Barabanov, A.L.
1994-01-01
The suggestion is made that the excited state of the 3 He nucleus found out recently in the reaction has spin and parity 1/2 + and the same configuration that the ground open of 6 He. It is shown that in an elastic nd-scattering a resonance associated with the excited state may be absent due to destructive interference of potential and resonant scattering phases
Localized excitations and the geometry of the 1nπ* excited states of pyrazine
International Nuclear Information System (INIS)
Kleier, D.A.; Martin, R.L.; Wadt, W.R.; Moomaw, W.R.
1982-01-01
Previous theoretical work has shown that the lowest excited singlet state of pyrazine, the π* 1 B 3 u state, is best described in terms of interacting excitations localized on each nitrogen. The present work refines the localized excitation model and considers its implications for the geometry of the 1 B 3 u state. Hartree-Fock calculations show that the best single configuration description of the nπ* state has broken ( 1 B 1 ) symmetry with the excitation strongly localized at one end of the molcule. If the symmetry-restricted hf result is used for reference, this localization describes an important correlation effect. The excited-state geometry was probed using configuration interaction wave functions based on the symmetry-restricted orbitals, as well as properly symmetrized ''valance-bond'' wave functions based on the broken symmetry solutions. Both descriptions lead to a very flat potential for a b/sub 1u/ vibrational mode. This mode reduces the molecular geometry from D/sub 2h/ to C/sub 2v/. We present spectroscopic evidence of our own and of other workers which is consistent with such a flat potential
Formation and role of excited states in radiolysis - a foreword
International Nuclear Information System (INIS)
Singh, A.
1976-01-01
It is stated that the choice of contributions to the special issue of this Journal has been limited to those which bear on the details of the mechanisms of excited state formation and are likely to be useful to radiation chemists. Since more than half the energy deposited in radiolysis goes into excitation, studies on the fate of the excited species formed are very important. A brief reference is made to the subject matter of each of the fifteen contributions, and its significance to the development of the technique of radiolysis is outlined. (U.K.)
Core polarization and Coulomb displacement energies
International Nuclear Information System (INIS)
Shlomo, S.; Love, W.G.
1982-01-01
The contributions of core polarization terms (other than the Auerbach-Kahana-Weneser (AKW) effect) to Coulomb displacement energies of mirror nuclei near A = 16 and A = 40 are examined within the particle-vibration coupling model. The parameters of the model are determined using updated data on the locations and strengths of multipole core excitations. In the absence of relevant data an energy-weighted sum rule (EWSR) is exploited. Taking into account multipole excitations up to L = 5 and subtracting the contributions which are due to short-range correlations, significant contributions (1-3%) to ΔEsub(c) are found. These corrections arise from particle coupling to low-lying collective states (long-range correlations). The implications of these results on the Coulomb energy problem are discussed. (Auth.)
Coulomb interaction in multiple scattering theory
International Nuclear Information System (INIS)
Ray, L.; Hoffmann, G.W.; Thaler, R.M.
1980-01-01
The treatment of the Coulomb interaction in the multiple scattering theories of Kerman-McManus-Thaler and Watson is examined in detail. By neglecting virtual Coulomb excitations, the lowest order Coulomb term in the Watson optical potential is shown to be a convolution of the point Coulomb interaction with the distributed nuclear charge, while the equivalent Kerman-McManus-Thaler Coulomb potential is obtained from an averaged, single-particle Coulombic T matrix. The Kerman-McManus-Thaler Coulomb potential is expressed as the Watson Coulomb term plus additional Coulomb-nuclear and Coulomb-Coulomb cross terms, and the omission of the extra terms in usual Kerman-McManus-Thaler applications leads to negative infinite total reaction cross section predictions and incorrect pure Coulomb scattering limits. Approximations are presented which eliminate these anomalies. Using the two-potential formula, the full projectile-nucleus T matrix is separated into two terms, one resulting from the distributed nuclear charge and the other being a Coulomb distorted nuclear T matrix. It is shown that the error resulting from the omission of the Kerman-McManus-Thaler Coulomb terms is effectively removed when the pure Coulomb T matrix in Kerman-McManus-Thaler is replaced by the analogous quantity in the Watson approach. Using the various approximations, theoretical angular distributions are obtained for 800 MeV p+ 208 Pb elastic scattering and compared with experimental data
International Nuclear Information System (INIS)
Bolotin, H.H.; Stuchbery, A.E.; Morrison, I.; Kennedy, D.L.; Ryan, C.G.; Sie, S.H.
1981-01-01
The lifetimes and lifetime limits of the low-lying excited states up to and including the 6 1 + levels in 196 198 Pt were determined by the rcoil-distance method (RDM). Gamma-ray angular distributions in 198 Pt were also measured. These states were populated by multiple Coulomb excitation using 220-MeV 58 Ni ion beams and the measurements carried out in coincidence with backscattered projectiles. The measured mean lives of the states and B(E2) values inferred for the transitions between levels are presented. These specific findings, and the observed structure systematics obtained from the combination of the present results and those of prior workers for the even 194 - 198 Pt isotopes, are critically compared with our structure calculations employing the Interacting Boson Approximation (IBA) model incorporating a symmetry-breaking quadrupole force. Evaluative comparisons are also made with Boson Expansion Theory (BET) calculations
Bolotin, H. H.; Stuchbery, A. E.; Morrison, I.; Kennedy, D. L.; Ryan, C. G.; Sie, S. H.
1981-11-01
The lifetimes and lifetime limits of the low-lying excited states up to and including the 6 1+ levels in 196, 198Pt were determined by the recoil-distance method (RDM). Gamma-ray angular distributions in 198Pt were also measured. These states were populated by multiple Coulomb excitation using 220 MeV 58Ni ion beams and the measurements were carried out in coincidence with back-scattered projectiles. The measured mean lives of the states and B(E2) values inferred for the transitions between levels are presented. These specific findings, and the observed structure systematics obtained from the combination of the present results and those of prior workers for the even 194-198Pt isotopes, are critically compared with our structure calculations employing the interacting boson approximation (IBA) model incorporating a symmetry-breaking quadrupole force; evaluative comparisons are also made with boson expansion theory (BET) calculations.
International Nuclear Information System (INIS)
Bolotin, H.H.; Stuchbery, A.E.; Morrison, I.; Kennedy, D.L.; Ryan, C.G.; Sie, S.H.
1981-01-01
The lifetimes and lifetime limits of the low-lying excited states up to and including the 6 + 1 levels in sup(196, 198)Pt were determined by the recoil-distance method (RDM). Gamma-ray angular distributions in 198 Pt were also measured. These states were populated by multiple Coulomb excitation using 220 MeV 58 Ni ion beams and the measurements were carried out in coincidence with backscattering projectiles. The measured mean lives of the states and B(E2) values inferred for the transitions between levels are presented. These specific findings, and the observed structure systematics obtained from the combination of the present results and those of prior workers for the even sup(194-198)Pt isotopes, are critically compared with our structure calculations employing the interacting boson approximation (IBA) model incorporating a symmetry-breaking quadrupole force; evaluative comparisons are also made with boson expansion theory (BET) calculations. (orig.)
Excited states of open strings from N=4 SYM
International Nuclear Information System (INIS)
Dzienkowski, Eric
2015-01-01
We continue the analysis of building open strings stretched between giant gravitons from N=4 SYM by going to second order in perturbation theory using the three-loop dilatation generator from the field theory. In the process we build a Fock-like space of states using Cuntz oscillators which can be used to access the excited open string states. We find a remarkable cancellation among the excited states that shows the ground state energy is consistent with a fully relativistic dispersion relation.
Ultrafast excited-state dynamics of 2,5-dimethylpyrrole.
Yang, Dongyuan; Min, Yanjun; Chen, Zhichao; He, Zhigang; Yuan, Kaijun; Dai, Dongxu; Yang, Xueming; Wu, Guorong
2018-04-17
The ultrafast excited-state dynamics of 2,5-dimethylpyrrole following excitation at wavelengths in the range of 265.7-216.7 nm is studied using the time-resolved photoelectron imaging method. It is found that excitation at longer wavelengths (265.7-250.2 nm) results in the population of the S1(1πσ*) state, which decays out of the photoionization window in about 90 fs. At shorter pump wavelengths (242.1-216.7 nm), the assignments are less clear-cut. We tentatively assign the initially photoexcited state(s) to the 1π3p Rydberg state(s) which has lifetimes of 159 ± 20, 125 ± 15, 102 ± 10 and 88 ± 10 fs for the pump wavelengths of 242.1, 238.1, 232.6 and 216.7 nm, respectively. Internal conversion to the S1(1πσ*) state represents at most a minor decay channel. The methyl substitution effects on the decay dynamics of the excited states of pyrrole are also discussed. Methyl substitution on the pyrrole ring seems to enhance the direct internal conversion from the 1π3p Rydberg state to the ground state, while methyl substitution on the N atom has less influence and the internal conversion to the S1(πσ*) state represents a main channel.
Charge transfer excitations from excited state Hartree-Fock subsequent minimization scheme
International Nuclear Information System (INIS)
Theophilou, Iris; Tassi, M.; Thanos, S.
2014-01-01
Photoinduced charge-transfer processes play a key role for novel photovoltaic phenomena and devices. Thus, the development of ab initio methods that allow for an accurate and computationally inexpensive treatment of charge-transfer excitations is a topic that nowadays attracts a lot of scientific attention. In this paper we extend an approach recently introduced for the description of single and double excitations [M. Tassi, I. Theophilou, and S. Thanos, Int. J. Quantum Chem. 113, 690 (2013); M. Tassi, I. Theophilou, and S. Thanos, J. Chem. Phys. 138, 124107 (2013)] to allow for the description of intermolecular charge-transfer excitations. We describe an excitation where an electron is transferred from a donor system to an acceptor one, keeping the excited state orthogonal to the ground state and avoiding variational collapse. These conditions are achieved by decomposing the space spanned by the Hartree-Fock (HF) ground state orbitals into four subspaces: The subspace spanned by the occupied orbitals that are localized in the region of the donor molecule, the corresponding for the acceptor ones and two more subspaces containing the virtual orbitals that are localized in the neighborhood of the donor and the acceptor, respectively. Next, we create a Slater determinant with a hole in the subspace of occupied orbitals of the donor and a particle in the virtual subspace of the acceptor. Subsequently we optimize both the hole and the particle by minimizing the HF energy functional in the corresponding subspaces. Finally, we test our approach by calculating the lowest charge-transfer excitation energies for a set of tetracyanoethylene-hydrocarbon complexes that have been used earlier as a test set for such kind of excitations
Low-lying excited states by constrained DFT
Ramos, Pablo; Pavanello, Michele
2018-04-01
Exploiting the machinery of Constrained Density Functional Theory (CDFT), we propose a variational method for calculating low-lying excited states of molecular systems. We dub this method eXcited CDFT (XCDFT). Excited states are obtained by self-consistently constraining a user-defined population of electrons, Nc, in the virtual space of a reference set of occupied orbitals. By imposing this population to be Nc = 1.0, we computed the first excited state of 15 molecules from a test set. Our results show that XCDFT achieves an accuracy in the predicted excitation energy only slightly worse than linear-response time-dependent DFT (TDDFT), but without incurring into problems of variational collapse typical of the more commonly adopted ΔSCF method. In addition, we selected a few challenging processes to test the limits of applicability of XCDFT. We find that in contrast to TDDFT, XCDFT is capable of reproducing energy surfaces featuring conical intersections (azobenzene and H3) with correct topology and correct overall energetics also away from the intersection. Venturing to condensed-phase systems, XCDFT reproduces the TDDFT solvatochromic shift of benzaldehyde when it is embedded by a cluster of water molecules. Thus, we find XCDFT to be a competitive method among single-reference methods for computations of excited states in terms of time to solution, rate of convergence, and accuracy of the result.
Rydberg energies using excited state density functional theory
International Nuclear Information System (INIS)
Cheng, C.-L.; Wu Qin; Van Voorhis, Troy
2008-01-01
We utilize excited state density functional theory (eDFT) to study Rydberg states in atoms. We show both analytically and numerically that semilocal functionals can give quite reasonable Rydberg energies from eDFT, even in cases where time dependent density functional theory (TDDFT) fails catastrophically. We trace these findings to the fact that in eDFT the Kohn-Sham potential for each state is computed using the appropriate excited state density. Unlike the ground state potential, which typically falls off exponentially, the sequence of excited state potentials has a component that falls off polynomially with distance, leading to a Rydberg-type series. We also address the rigorous basis of eDFT for these systems. Perdew and Levy have shown using the constrained search formalism that every stationary density corresponds, in principle, to an exact stationary state of the full many-body Hamiltonian. In the present context, this means that the excited state DFT solutions are rigorous as long as they deliver the minimum noninteracting kinetic energy for the given density. We use optimized effective potential techniques to show that, in some cases, the eDFT Rydberg solutions appear to deliver the minimum kinetic energy because the associated density is not pure state v-representable. We thus find that eDFT plays a complementary role to constrained DFT: The former works only if the excited state density is not the ground state of some potential while the latter applies only when the density is a ground state density.
Dinamical polarizability of highly excited hydrogen-like states
International Nuclear Information System (INIS)
Delone, N.B.; Krajnov, V.P.
1982-01-01
Analytic expressions are derived for the dynamic polarizability of highly excited hydrogen-like atomic states. It is shown that in the composite matrix element which determines the dynamic polarizability there is a strong compensation of the terms as a result of which the resulting magnitude of the dynamic polarizability is quasiclasically small compared to the individual terms of the composite matrix. It is concluded that the resonance behaviour of the dynamic polarizability of highly excited states differs significantly from the resonance behaviour of the polarizability for the ground and low-lying atomic states. The static limit and high-frequency limit of on electromagnetic field are considered
Microscopic description and excitation of unitary analog states
Energy Technology Data Exchange (ETDEWEB)
Kisslinger, L S [Carnegie-Mellon Univ., Pittsburgh, Pa. (USA); Van Giai, N [Paris-11 Univ., 91 - Orsay (France). Inst. de Physique Nucleaire
1977-12-05
A microscopic investigation in a self-consistent particle-hole model reveals approximate unitary analog states in spite of large symmetry breaking. The K-nucleus elastic scattering and (K/sup -/, ..pi../sup -/) excitation of these states are studied, showing strong surface effects.
Beck, Warren F; Bishop, Michael M; Roscioli, Jerome D; Ghosh, Soumen; Frank, Harry A
2015-04-15
A consideration of the excited state potential energy surfaces of carotenoids develops a new hypothesis for the nature of the conformational motions that follow optical preparation of the S2 (1(1)Bu(+)) state. After an initial displacement from the Franck-Condon geometry along bond length alternation coordinates, it is suggested that carotenoids pass over a transition-state barrier leading to twisted conformations. This hypothesis leads to assignments for several dark intermediate states encountered in femtosecond spectroscopic studies. The Sx state is assigned to the structure reached upon the onset of torsional motions near the transition state barrier that divides planar and twisted structures on the S2 state potential energy surface. The X state, detected recently in two-dimensional electronic spectra, corresponds to a twisted structure well past the barrier and approaching the S2 state torsional minimum. Lastly, the S(∗) state is assigned to a low lying S1 state structure with intramolecular charge transfer character (ICT) and a pyramidal conformation. It follows that the bent and twisted structures of carotenoids that are found in photosynthetic light-harvesting proteins yield excited-state structures that favor the development of an ICT character and optimized energy transfer yields to (bacterio)chlorophyll acceptors. Copyright © 2015 Elsevier Inc. All rights reserved.
Electronic excited states and relaxation dynamics in polymer heterojunction systems
Ramon, John Glenn Santos
The potential for using conducting polymers as the active material in optoelectronic devices has come to fruition in the past few years. Understanding the fundamental photophysics behind their operations points to the significant role played by the polymer interface in their performance. Current device architectures involve the use of bulk heterojunctions which intimately blend the donor and acceptor polymers to significantly increase not only their interfacial surface area but also the probability of exciton formation within the vicinity of the interface. In this dissertation, we detail the role played by the interface on the behavior and performance of bulk heterojunction systems. First, we explore the relation between the exciton binding energy to the band offset in determining device characteristics. As a general rule, when the exciton binding energy is greater than the band offset, the exciton remains the lowest energy excited state leading to efficient light-emitting properties. On the other hand, if the offset is greater than the binding energy, charge separation becomes favorable leading to better photovoltaic behavior. Here, we use a Wannier function, configuration interaction based approach to examine the essential excited states and predict the vibronic absorption and emission spectra of the PPV/BBL, TFB/F8BT and PFB/F8BT heterojunctions. Our results underscore the role of vibrational relaxation in the formation of charge-transfer states following photoexcitation. In addition, we look at the relaxation dynamics that occur upon photoexcitation. For this, we adopt the Marcus-Hush semiclassical method to account for lattice reorganization in the calculation of the interconversion rates in TFB/F8BT and PFB/F8BT. We find that, while a tightly bound charge-transfer state (exciplex) remains the lowest excited state, a regeneration pathway to the optically active lowest excitonic state in TFB/F8BT is possible via thermal repopulation from the exciplex. Finally
Analysis of 165Er excited state properties
International Nuclear Information System (INIS)
Morozov, V.A.; Budzynski, M.
1982-01-01
It is shown by the analysis of 165 Tm decay that the precision measurements of γ-ray and internal conversion electron intensities together with the measurements o.f angular correlation coefficients provide more data for the determination of γ-ray multipole composition and intensities of γ-transitions with small enerqy difference. The spin of the 589.868 ke tate is found to be I=1/2 - . Doublet transitions of different parity from the states 1103.495, 920.645 and 745.968 keV to the levels of the 590 keV region with energy difference ΔE=(108+-22) eV are identified
The Sommerfeld enhancement for dark matter with an excited state
International Nuclear Information System (INIS)
Slatyer, Tracy R.
2010-01-01
We present an analysis of the Sommerfeld enhancement to dark matter annihilation in the presence of an excited state, where the interaction inducing the enhancement is purely off-diagonal, such as in models of exciting or inelastic dark matter. We derive a simple and accurate semi-analytic approximation for the s-wave enhancement, which is valid provided the mass splitting between the ground and excited states is not too large, and discuss the cutoff of the enhancement for large mass splittings. We reproduce previously derived results in the appropriate limits, and demonstrate excellent agreement with numerical calculations of the enhancement. We show that the presence of an excited state leads to generically larger values of the Sommerfeld enhancement, larger resonances, and shifting of the resonances to lower mediator masses. Furthermore, in the presence of a mass splitting the enhancement is no longer a monotonic function of velocity: the enhancement where the kinetic energy is close to that required to excite the higher state can be up to twice as large as the enhancement at zero velocity
Quantum entanglement of localized excited states at finite temperature
Energy Technology Data Exchange (ETDEWEB)
Caputa, Paweł [Yukawa Institute for Theoretical Physics (YITP), Kyoto University,Kyoto 606-8502 (Japan); Nordita, KTH Royal Institute of Technology and Stockholm University,Roslagstullsbacken 23, SE-106 91 Stockholm (Sweden); Simón, Joan; Štikonas, Andrius [School of Mathematics and Maxwell Institute for Mathematical Sciences,University of Edinburgh,King’s Buildings, Edinburgh EH9 3FD (United Kingdom); Takayanagi, Tadashi [Yukawa Institute for Theoretical Physics (YITP), Kyoto University,Kyoto 606-8502 (Japan); Kavli Institute for the Physics and Mathematics of the Universe (Kavli IPMU),University of Tokyo,Kashiwa, Chiba 277-8582 (Japan)
2015-01-20
In this work we study the time evolutions of (Renyi) entanglement entropy of locally excited states in two dimensional conformal field theories (CFTs) at finite temperature. We consider excited states created by acting with local operators on thermal states and give both field theoretic and holographic calculations. In free field CFTs, we find that the growth of Renyi entanglement entropy at finite temperature is reduced compared to the zero temperature result by a small quantity proportional to the width of the localized excitations. On the other hand, in finite temperature CFTs with classical gravity duals, we find that the entanglement entropy approaches a characteristic value at late time. This behaviour does not occur at zero temperature. We also study the mutual information between the two CFTs in the thermofield double (TFD) formulation and give physical interpretations of our results.
Energies and lifetimes of excited states in copperlike Kr VIII
International Nuclear Information System (INIS)
Livingston, A.E.; Curtis, L.J.; Schectman, R.M.; Berry, H.G.
1980-01-01
The spectrum of Kr VIII has been observed between 180 and 2000 A by using foil excitation of 2.5--3.5-MeV krypton ions. Twenty new transitions have been classified and eleven new excited-state energies have been determined within the n=4 --7 shells. The ionization potential is derived to be 1 015 800 +- 200 cm -1 . The excited-state energies and fine structures are compared with recent relativistic Hartree-Fock calculations. The 4p-state lifetime has been measured by performing a simultaneous analysis of decay data for the 4p level and for its dominant cascade-repopulating levels. The 4p lifetime is found to be 30% shorter than previously measured values and is in excellent agreement with the result of a recent multiconfiguration Hartree-Fock calculation. The source of the discrepancy between this result and earlier measurements is discussed
Method of producing excited states of atomic nuclei
International Nuclear Information System (INIS)
Morita, M.; Morita, R.
1976-01-01
A method is claimed of producing excited states of atomic nuclei which comprises bombarding atoms with x rays or electrons, characterized in that (1) in the atoms selected to be produced in the excited state of their nuclei, (a) the difference between the nuclear excitation energy and the difference between the binding energies of adequately selected two electron orbits is small enough to introduce the nuclear excitation by electron transition, and (b) the system of the nucleus and the electrons in the case of ionizing an orbital electron in said atoms should satisfy the spin and parity conservation laws; and (2) the energy of the bombarding x rays or electrons should be larger than the binding energy of one of the said two electron orbits which is located at shorter distance from the atomic nucleus. According to the present invention, atomic nuclei can be excited in a relatively simple manner without requiring the use of large scale apparatus, equipment and production facilities, e.g., factories. It is also possible to produce radioactive substances or separate a particular isotope with an extremely high purity from a mixture of isotopes by utilizing nuclear excitation
Coulomb energy, vortices, and confinement
International Nuclear Information System (INIS)
Greensite, Jeff; Olejnik, Stefan
2003-01-01
We estimate the Coulomb energy of static quarks from a Monte Carlo calculation of the correlator of timelike link variables in the Coulomb gauge. We find, in agreement with Cucchieri and Zwanziger, that this energy grows linearly with distance at large quark separations. The corresponding string tension, however, is several times greater than the accepted asymptotic string tension, indicating that a state containing only static sources, with no constituent gluons, is not the lowest energy flux tube state. The Coulomb energy is also measured on thermalized lattices with center vortices removed by the de Forcrand-D'Elia procedure. We find that when vortices are removed, the Coulomb string tension vanishes
Equations of state for self-excited MHD generator studies
Energy Technology Data Exchange (ETDEWEB)
Rogers, F.J.; Ross, M.; Haggin, G.L.; Wong, L.K.
1980-02-26
We have constructed a state-of-the-art equation of state (EOS) for argon covering the temperature density range attainable by currently proposed self-excited MHD generators. The EOS for conditions in the flow channel was obtained primarily by a non-ideal plasma code (ACTEX) that is based on a many body activity expansion. For conditions in the driver chamber the EOS was primarily obtained from a fluid code (HDFP) that calculates the fluid properties from perturbation theory based on the insulator interatomic pair potential but including electronic excitations. The results are in agreement with several sets of experimental data in the 0.6 - 91 GPa pressure range.
Can $\\beta$-decay probe excited state halos?
2002-01-01
In the first experiment at the newly constructed ISOLDE Facility the first-forbidden $\\beta$-decay of $^{17}$Ne into the first excited state of $^{17}$F has been measured. It is a factor two faster than the corresponding mirror decay and thus gives one of the largest recorded asymmetries for $\\beta$-decays feeding bound final states. Shell-model calculations can only reproduce the asymmetry if the halo structure of the $^{17}$F state is taken into account.
Energy Technology Data Exchange (ETDEWEB)
Amusia, M.Ya. [The Racah Institute of Physics, Hebrew University, 91904 Jerusalem (Israel); A F Ioffe Physical-Technical Institute, 194921 St Petersburg (Russian Federation); Mikhailov, A.I.; Mikhailov, I.A. [St Petersburg Nuclear Physics Institute, Gatchina, 188350 St Petersburg (Russian Federation)
1999-10-28
Double ionization and ionization with excitation of helium-like ions with Z>>1 from 2 {sup 1}S and 2 {sup 3}S states on the absorption of a high-frequency photon have been considered. The analytical calculation is performed in the non-relativistic photon energy range in the lowest order of perturbation theory in the inter-electron interaction. Coulomb wavefunctions and the Coulomb Green function are used as a zeroth-order approximation. Differential and total cross sections of the processes are expressed via the corresponding values for the single photoionization. The photoelectron energy spectrum is obtained in the marginal energy range (i.e. for p{sub 1}>>p{sub 2}, p{sub 1} and p{sub 2} momenta of photoelectrons) for the double-ionization process. Simple relations between the cross sections of double ionization and ionization with excitation are derived. (author)
The formation and decay of triply excited He- states in e-He scattering
International Nuclear Information System (INIS)
Heideman, H.G.M.
1988-01-01
A description is given of doubly and triply excited negative-ion states and their effects on the electron impact excitation of atomic states. Mechanisms for indirect excitation of singly excited states are discussed with respect to:- negative-ion resonance, autoionisation and post-collision interaction, and excitation of an autoionising state via a negative ion resonance. A classification of doubly excited states is considered. Experimental results on the excitation of the n'S states of helium as a function of the incident electron energy are presented, along with theoretical PCI (post collision interaction) profiles in excitation functions, and an interpretation of the results. (UK)
International Nuclear Information System (INIS)
Bolotin, H.H.; Kennedy, D.L.; Linard, B.J.; Stuchbery, A.E.
1979-01-01
The lifetimes of five excited states in 197 Au up to an excitation energy of 885 keV were measured by the recoil-distance method (RDM). These levels were populated by Coulomb excitation using both 90 MeV 20 Ne and 120 MeV 35 Cl ion beams. The experimentally determined spectroscopy of the low-lying levels 3/2 + (ground state) and 1/2 + , (3/2) + 2 , 5/2 + and 7/2 + at 77.3, 268.8, 278.9, and 547.5 keV excitation energy, respectively, has been critically compared with the detailed predictions of the de-Shalit weak-coupling core-excitation model. When the model is taken to represent the case of a dsub(3/2) proton hole coupled to a 198 Hg core, the model parameters obtained are in accord with the criteria implicit for weak core coupling and, at the same time, are in remarkably good agreement with virtually all measured E2 and M1 transition rates. (Auth.)
Electronically excited negative ion resonant states in chloroethylenes
Energy Technology Data Exchange (ETDEWEB)
Khvostenko, O.G., E-mail: khv@mail.ru; Lukin, V.G.; Tuimedov, G.M.; Khatymova, L.Z.; Kinzyabulatov, R.R.; Tseplin, E.E.
2015-02-15
Highlights: • Several novel dissociative negative ion channels were revealed in chloroethylenes. • The electronically excited resonant states were recorded in all chloroethylenes under study. • The states were assigned to the inter-shell types, but not to the core-excited Feshbach one. - Abstract: The negative ion mass spectra of the resonant electron capture by molecules of 1,1-dichloroethylene, 1,2-dichloroethylene-cis, 1,2-dichloroethylene-trans, trichloroethylene and tetrachloroethylene have been recorded in the 0–12 eV range of the captured electron energy using static magnetic sector mass spectrometer modified for operation in the resonant electron capture regime. As a result, several novel low-intensive dissociation channels were revealed in the compounds under study. Additionally, the negative ion resonant states were recorded at approximately 3–12 eV, mostly for the first time. These resonant states were assigned to the electronically excited resonances of the inter-shell type by comparing their energies with those of the parent neutral molecules triplet and singlet electronically excited states known from the energy-loss spectra obtained by previous studies.
Excited State Structural Dynamics of Carotenoids and Charge Transfer Systems
International Nuclear Information System (INIS)
Van Tassle, Aaron Justin
2006-01-01
This dissertation describes the development and implementation of a visible/near infrared pump/mid-infrared probe apparatus. Chapter 1 describes the background and motivation of investigating optically induced structural dynamics, paying specific attention to solvation and the excitation selection rules of highly symmetric molecules such as carotenoids. Chapter 2 describes the development and construction of the experimental apparatus used throughout the remainder of this dissertation. Chapter 3 will discuss the investigation of DCM, a laser dye with a fluorescence signal resulting from a charge transfer state. By studying the dynamics of DCM and of its methyl deuterated isotopomer (an otherwise identical molecule), we are able to investigate the origins of the charge transfer state and provide evidence that it is of the controversial twisted intramolecular (TICT) type. Chapter 4 introduces the use of two-photon excitation to the S1 state, combined with one-photon excitation to the S2 state of the carotenoid beta-apo-8'-carotenal. These 2 investigations show evidence for the formation of solitons, previously unobserved in molecular systems and found only in conducting polymers Chapter 5 presents an investigation of the excited state dynamics of peridinin, the carotenoid responsible for the light harvesting of dinoflagellates. This investigation allows for a more detailed understanding of the importance of structural dynamics of carotenoids in light harvesting
Fay, Temple H.
2012-01-01
Viscous damping is commonly discussed in beginning differential equations and physics texts but dry friction or Coulomb friction is not despite dry friction being encountered in many physical applications. One reason for avoiding this topic is that the equations involve a jump discontinuity in the damping term. In this article, we adopt an energy…
On satellite lines anomalies in OH excited states
International Nuclear Information System (INIS)
Elitzur, M.
1976-01-01
It is argued that different pumps produce similar distributions of populations in the first two excited states of OH. The pattern observed recently in G 219.3 - 07 by Whiteoak and Gardner can be due either to radiative or collisional pump. (author)
Core excitations to the low lying states of thallium isotopes
International Nuclear Information System (INIS)
Gruenbaum, L.; Tomaselli, M.; Herold, D.
1977-08-01
The admixture of core excitations to the low lying states of A = 203 and A = 205 thallium isotopes has been calculated. The wave functions obtained reproduce the electromagnetic properties as well as the hyperfine splittings and the isomershifts of both thallium isotopes. (orig.) [de
Excited state intramolecular charge transfer reaction in non-aqueous ...
Indian Academy of Sciences (India)
polar phase and thus leading to less swelling of reverse .... ues were restricted up to the limit at which no phase separation was ..... The lower panel of figure 1 also indicates that the slopes of ... probe in its ground and excited states.55.
Size dependent deactivation of the excited state of DHICA
DEFF Research Database (Denmark)
Gauden, Magdalena; Pezzella, Alessandro; Panzella, Lucia
2008-01-01
Melanin is a natural pigment mainly responsible for the protection of skin and eyes from UV damage. 5,6- dihydroxyindole- 2 carboxylic acid (DHICA) is a key melanin building block. We have investigated the excited state dynamics of DHICA as well as its derivatives and oligomeric units using...
Optimal control of peridinin excited-state dynamics
Czech Academy of Sciences Publication Activity Database
Dietzek, B.; Chábera, P.; Hanf, R.; Tschierlei, S.; Popp, J.; Pascher, T.; Yartsev, A.; Polívka, Tomáš
2010-01-01
Roč. 373, 1-2 (2010), s. 129-136 ISSN 0301-0104 Institutional research plan: CEZ:AV0Z50510513 Keywords : peridin * excited-state dynamics * coherent control Subject RIV: BO - Biophysics Impact factor: 2.017, year: 2010
Dark excited states of carotenoids: Consensus and controversy
Czech Academy of Sciences Publication Activity Database
Polívka, Tomáš; Sundström, V.
2009-01-01
Roč. 477, 1-3 (2009), s. 1-11 ISSN 0009-2614 Institutional research plan: CEZ:AV0Z50510513 Keywords : carotenoids * excited states * relaxation pathways * femtosecond spectroscopy Subject RIV: BO - Biophysics Impact factor: 2.291, year: 2009
Energy Technology Data Exchange (ETDEWEB)
Ojeda-Guillén, D., E-mail: dogphysics@gmail.com [Escuela Superior de Física y Matemáticas, Instituto Politécnico Nacional, Ed. 9, Unidad Profesional Adolfo López Mateos, C.P. 07738, México D.F. (Mexico); Mota, R.D. [Escuela Superior de Ingeniería Mecánica y Eléctrica, Unidad Culhuacán, Instituto Politécnico Nacional, Av. Santa Ana No. 1000, Col. San Francisco Culhuacán, Delegación Coyoacán, C.P. 04430, México D.F. (Mexico); Granados, V.D. [Escuela Superior de Física y Matemáticas, Instituto Politécnico Nacional, Ed. 9, Unidad Profesional Adolfo López Mateos, C.P. 07738, México D.F. (Mexico)
2014-08-14
We decouple the Dirac's radial equations in D+1 dimensions with Coulomb-type scalar and vector potentials through appropriate transformations. We study each of these uncoupled second-order equations in an algebraic way by using an su(1,1) algebra realization. Based on the theory of irreducible representations, we find the energy spectrum and the radial eigenfunctions. We construct the Perelomov coherent states for the Sturmian basis, which is the basis for the unitary irreducible representation of the su(1,1) Lie algebra. The physical radial coherent states for our problem are obtained by applying the inverse original transformations to the Sturmian coherent states. - Highlights: • We solve the most general Dirac–Kepler–Coulomb problem. • The eigenfunctions and energy spectrum are obtained in a purely algebraic way. • We construct the radial SU(1,1) coherent states for the Kepler–Coulomb problem.
International Nuclear Information System (INIS)
Ojeda-Guillén, D.; Mota, R.D.; Granados, V.D.
2014-01-01
We decouple the Dirac's radial equations in D+1 dimensions with Coulomb-type scalar and vector potentials through appropriate transformations. We study each of these uncoupled second-order equations in an algebraic way by using an su(1,1) algebra realization. Based on the theory of irreducible representations, we find the energy spectrum and the radial eigenfunctions. We construct the Perelomov coherent states for the Sturmian basis, which is the basis for the unitary irreducible representation of the su(1,1) Lie algebra. The physical radial coherent states for our problem are obtained by applying the inverse original transformations to the Sturmian coherent states. - Highlights: • We solve the most general Dirac–Kepler–Coulomb problem. • The eigenfunctions and energy spectrum are obtained in a purely algebraic way. • We construct the radial SU(1,1) coherent states for the Kepler–Coulomb problem
On analytical solutions to the problem of the Coulomb and confining potentials
International Nuclear Information System (INIS)
Dineykhan, M.; Nazmitdinov, R.G.
1997-01-01
The oscillator representation method is presented and applied to calculate the energy spectrum of the superposition of the Coulomb and the power-law potentials, the Coulomb and the Yukawa potentials. The method provides an efficient way to obtain analytical results for arbitrary set of parameters of the considered potentials. The energies of ground and excited states of a quantum system are in good agreement with the exact results
Calculation of neutral beam deposition accounting for excited states
International Nuclear Information System (INIS)
Gianakon, T.A.
1992-09-01
Large-scale neutral-beam auxillary heating of plasmas has led to new plasma operational regimes which are often dominated by fast ions injected via the absorption of an energetic beam of hydrogen neutrals. An accurate simulation of the slowing down and transport of these fast ions requires an intimate knowledge of the hydrogenic neutral deposition on each flux surface of the plasma. As a refinement to the present generation of transport codes, which base their beam deposition on ground-state reaction rates, a new set of routines, based on the excited states of hydrogen, is presented as mechanism for computing the attenuation and deposition of a beam of energetic neutrals. Additionally, the numerical formulations for the underlying atomic physics for hydrogen impacting on the constiuent plasma species is developed and compiled as a numerical database. Sample results based on this excited state model are compared with the ground-state model for simple plasma configurations
Sub-50 fs excited state dynamics of 6-chloroguanine upon deep ultraviolet excitation.
Mondal, Sayan; Puranik, Mrinalini
2016-05-18
The photophysical properties of natural nucleobases and their respective nucleotides are ascribed to the sub-picosecond lifetime of their first singlet states in the UV-B region (260-350 nm). Electronic transitions of the ππ* type, which are stronger than those in the UV-B region, lie at the red edge of the UV-C range (100-260 nm) in all isolated nucleobases. The lowest energetic excited states in the UV-B region of nucleobases have been investigated using a plethora of experimental and theoretical methods in gas and solution phases. The sub-picosecond lifetime of these molecules is not a general attribute of all nucleobases but specific to the five primary nucleobases and a few xanthine and methylated derivatives. To determine the overall UV photostability, we aim to understand the effect of more energetic photons lying in the UV-C region on nucleobases. To determine the UV-C initiated photophysics of a nucleobase system, we chose a halogen substituted purine, 6-chloroguanine (6-ClG), that we had investigated previously using resonance Raman spectroscopy. We have performed quantitative measurements of the resonance Raman cross-section across the Bb absorption band (210-230 nm) and constructed the Raman excitation profiles. We modeled the excitation profiles using Lee and Heller's time-dependent theory of resonance Raman intensities to extract the initial excited state dynamics of 6-ClG within 30-50 fs after photoexcitation. We found that imidazole and pyrimidine rings of 6-ClG undergo expansion and contraction, respectively, following photoexcitation to the Bb state. The amount of distortions of the excited state structure from that of the ground state structure is reflected by the total internal reorganization energy that is determined at 112 cm(-1). The contribution of the inertial component of the solvent response towards the total reorganization energy was obtained at 1220 cm(-1). In addition, our simulation also yields an instantaneous response of the first
Two-dimensional QCD in the Coulomb gauge
International Nuclear Information System (INIS)
Kalashnikova, Yu.S.; Nefed'ev, A.V.
2002-01-01
Various aspects of the 't Hooft model for two-dimensional QCD in the limit of infinite number of colours in the Coulomb gauge are discussed. The properties of mesonic excitations are studied, with special emphasis on the pion. Attention is paid to the dual role of the pion. which, while a genuine qq-bar state, is a Goldstone boson of two-dimensional QCD as well. In particular, the validity of the soft-pion theorems is demonstrated. It is shown that the Coulomb gauge is the most suitable choice for the study of hadronic observables involving pions [ru
Clustered chimera states in systems of type-I excitability
International Nuclear Information System (INIS)
Vüllings, Andrea; Omelchenko, Iryna; Hövel, Philipp; Hizanidis, Johanne
2014-01-01
The chimera state is a fascinating phenomenon of coexisting synchronized and desynchronized behaviour that was discovered in networks of nonlocally coupled identical phase oscillators over ten years ago. Since then, chimeras have been found in numerous theoretical and experimental studies and more recently in models of neuronal dynamics as well. In this work, we consider a generic model for a saddle-node bifurcation on a limit cycle representative of neural excitability type I. We obtain chimera states with multiple coherent regions (clustered chimeras/multi-chimeras) depending on the distance from the excitability threshold, the range of nonlocal coupling and the coupling strength. A detailed stability diagram for these chimera states and other interesting coexisting patterns (like traveling waves) is presented. (paper)
Deciphering excited state evolution in halorhodopsin with stimulated emission pumping.
Bismuth, Oshrat; Komm, Pavel; Friedman, Noga; Eliash, Tamar; Sheves, Mordechai; Ruhman, Sanford
2010-03-04
The primary photochemical dynamics of Hb. pharaonis Halorhodopsin (pHR) are investigated by femtosecond visible pump-near IR dump-hyperspectral probe spectroscopy. The efficiency of excited state depletion is deduced from transient changes in absorption, recorded with and without stimulated emission pumping (SEP), as a function of the dump delay. The concomitant reduction of photocycle population is assessed by probing the "K" intermediate difference spectrum. Results show that the cross section for stimulating emission is nearly constant throughout the fluorescent state lifetime. Probing "K" demonstrates that dumping produces a proportionate reduction in photocycle yields. We conclude that, despite its nonexponential internal conversion (IC) kinetics, the fluorescent state in pHR constitutes a single intermediate in the photocycle. This contrasts with conclusions drawn from the study of primary events in the related chloride pump from Hb. salinarum (sHR), believed to produce the "K" intermediate from a distinct short-lived subpopulation in the excited state. Our discoveries concerning internal conversion dynamics in pHR are discussed in light of recent expectations for similar excited state dynamics in both proteins.
Controlling excited-state contamination in nucleon matrix elements
Energy Technology Data Exchange (ETDEWEB)
Yoon, Boram; Gupta, Rajan; Bhattacharya, Tanmoy; Engelhardt, Michael; Green, Jeremy; Joó, Bálint; Lin, Huey-Wen; Negele, John; Orginos, Kostas; Pochinsky, Andrew; Richards, David; Syritsyn, Sergey; Winter, Frank
2016-06-01
We present a detailed analysis of methods to reduce statistical errors and excited-state contamination in the calculation of matrix elements of quark bilinear operators in nucleon states. All the calculations were done on a 2+1 flavor ensemble with lattices of size $32^3 \\times 64$ generated using the rational hybrid Monte Carlo algorithm at $a=0.081$~fm and with $M_\\pi=312$~MeV. The statistical precision of the data is improved using the all-mode-averaging method. We compare two methods for reducing excited-state contamination: a variational analysis and a two-state fit to data at multiple values of the source-sink separation $t_{\\rm sep}$. We show that both methods can be tuned to significantly reduce excited-state contamination and discuss their relative advantages and cost-effectiveness. A detailed analysis of the size of source smearing used in the calculation of quark propagators and the range of values of $t_{\\rm sep}$ needed to demonstrate convergence of the isovector charges of the nucleon to the $t_{\\rm sep} \\to \\infty $ estimates is presented.
Embedding potentials for excited states of embedded species
International Nuclear Information System (INIS)
Wesolowski, Tomasz A.
2014-01-01
Frozen-Density-Embedding Theory (FDET) is a formalism to obtain the upper bound of the ground-state energy of the total system and the corresponding embedded wavefunction by means of Euler-Lagrange equations [T. A. Wesolowski, Phys. Rev. A 77(1), 012504 (2008)]. FDET provides the expression for the embedding potential as a functional of the electron density of the embedded species, electron density of the environment, and the field generated by other charges in the environment. Under certain conditions, FDET leads to the exact ground-state energy and density of the whole system. Following Perdew-Levy theorem on stationary states of the ground-state energy functional, the other-than-ground-state stationary states of the FDET energy functional correspond to excited states. In the present work, we analyze such use of other-than-ground-state embedded wavefunctions obtained in practical calculations, i.e., when the FDET embedding potential is approximated. Three computational approaches based on FDET, that assure self-consistent excitation energy and embedded wavefunction dealing with the issue of orthogonality of embedded wavefunctions for different states in a different manner, are proposed and discussed
Jailaubekov, Askat E.; Song, Sang-Hun; Vengris, Mikas; Cogdell, Richard J.; Larsen, Delmar S.
2010-02-01
The hypothesis that S∗ is a vibrationally-excited ground-state population is tested and discarded for two carotenoid samples: β-carotene in solution and rhodopin glucoside embedded in the light harvesting 2 protein from Rhodopseudomonas acidophila. By demonstrating that the transient absorption signals measured in both systems that are induced by broadband (1000 cm -1) and narrowband (50 cm -1) excitation pulses are near identical and hence bandwidth independent, the impulsive stimulated Raman scattering mechanism proposed as the primary source for S∗ generation is discarded. To support this conclusion, previously published multi-pulse pump-dump-probe signals [17] are revisited to discard secondary mechanisms for S∗ formation.
Doubly excited 2s2p 1,3Po resonance states of helium in dense plasmas
International Nuclear Information System (INIS)
Kar, Sabyasachi; Ho, Y.K.
2005-01-01
We have made an investigation on the 2s2p 1,3 P o resonance states of helium embedded in dense plasma environments. A screened Coulomb potential obtained from the Debye model is used to represent the interaction between the charge particles. A correlated wave function consisting of a generalized exponential expansion has been used to represent the correlation effect. Resonance energies and widths for the doubly excited He embedded in plasmas with various Debye lengths are determined using the stabilization method by calculating the density of resonance states. The resonance energies and widths for various Debye parameters ranging from infinity to a small value for the lowest 1,3 P o resonance states are reported
International Nuclear Information System (INIS)
Novikov, N.V.; Teplova, Ya.A.
2011-01-01
It is shown that the Coulomb interaction of ions in the final state must be taken into account in the estimation of the cross section of electron capture by fast ions. The cross section of electron capture decreases considerably, and the dependence of the cross section on the collision energy becomes close to the experimental one if the interaction of charged particles after collision is taken into account. -- Highlights: → Coulomb interaction of ions in the final state must be taken into account. → This interaction leads to a considerable decrease in the cross section. → The dependence on energy close to the experimental one.
Excited neutral atomic fragments in the strong-field dissociation of N2 molecules
International Nuclear Information System (INIS)
Nubbemeyer, T; Eichmann, U; Sandner, W
2009-01-01
Excited neutral N* fragments with energies between 3 eV and 15 eV have been observed from the dissociation of N 2 molecules in strong laser fields. The kinetic energy spectrum of the excited neutral atoms corresponds to Coulomb explosion processes involving N + ions. This supports the assumption that the production of excited neutral fragments stems from a process in which one of the participating ions in the Coulomb explosion captures an electron into a Rydberg state.
Collective and single-particle states at high excitation energy
International Nuclear Information System (INIS)
Van den Berg, A.M.; Van der Molen, H.K.T.; Harakeh, M.N.; Akimune, H.; Daito, I.; Fujimura, H.; Fujiwara, M.; Ihara, F.; Inomata, T.
2000-01-01
Complete text of publication follows. Damping of high-lying single-particle states was investigated by the study of proton decay from high-lying states in 91 Nb, populated by the 90 Zr(α,t) reaction with E α = 180 MeV. In addition to decay to the ground state of 90 Zr, semi-direct decay was observed to the low-lying (2 + and 3 - ) phonon states, confirming the conclusion from other experiments that these phonon states play an important role in the damping process of the single-particle states. Furthermore, the population and decay of Isobaric Analogue States of 91 Zr, which are located at an excitation energy of about 10 - 12 MeV in 91 Nb, has been studied in the same reaction. (author)
Huang, K.-N.
1977-01-01
A computational procedure for calculating correlated wave functions is proposed for three-particle systems interacting through Coulomb forces. Calculations are carried out for the muonic helium atom. Variational wave functions which explicitly contain interparticle coordinates are presented for the ground and excited states. General Hylleraas-type trial functions are used as the basis for the correlated wave functions. Excited-state energies of the muonic helium atom computed from 1- and 35-term wave functions are listed for four states.
Mirror symmetry and Coulomb effects in light N ≅ Z nuclei
International Nuclear Information System (INIS)
Bentley, M.A.; Williams, S.J.; Joss, D.T.
2002-01-01
Some latest results from gamma-ray spectroscopic studies of high spin states of isobaric multiplets are presented. An experimental programme is underway to examine exited states of isobaric multiplets of total isospin T 1/2 and T = 1 and the comparison of energies of excited states can be interpreted in terms of Coulomb effects. Through a systematic study of these Coulomb effects, and through examination of the calculated Coulomb energies from full pf-shell model calculations, it is now becoming clear that measurement of Coulomb energies can yield very detailed information on the evolution of nuclear structure phenomena as a function of energy and angular momentum. In this contribution, latest results of studies of isobaric analogue states at high spin in the A = 50, 51 and 53 systems are presented. (author)
Calculations of core-excited states in Li
International Nuclear Information System (INIS)
Verbockhaven, G.; Hansen, J.E.
1999-01-01
We report on progress in the calculation of three-electron states making use of B-spline basis sets. In particular we discuss the advantages and disadvantages of using a Hartree-Fock basis (expanded in B-splines) compared to the use of hydrogenic basis states. Preliminary results are presented for the 2 S terms in Li below the 1s2s 3 S limit at 64.4 eV. The 2 S terms have been studied less extensively than other core-excited states in Li. In this particular case the choice of basis has a large influence on the quality of the results. (orig.)
Excited states by analytic continuation of TBA equations
International Nuclear Information System (INIS)
Dorey, P.; Tateo, R.
1996-01-01
We suggest an approach to the problem of finding integral equations for the excited states of an integrable model, starting from the thermodynamic Bethe ansatz equations for its ground state. The idea relies on analytic continuation through complex values of the coupling constant, and an analysis of the monodromies that the equations and their solutions undergo. For the scaling Lee-Yang model, we find equations in this way for the one- and two-particle states in the spin-zero sector, and suggest various generalisations. Numerical results show excellent agreement with the truncated conformal space approach, and we also treat some of the ultraviolet and infrared asymptotics analytically. (orig.)
Effect of the moment-of-inertia variation on Coulomb-nuclear interference in heavy ion scattering
International Nuclear Information System (INIS)
Bolotin, Yu.L.; Gonchar, V.Yu.; Inopin, E.V.; Chekanov, N.A.
1987-01-01
Effect of moment-of-inertia (MI) variation on probabilities of the Coulomb excitation of nucleus rotational states (RS) is investigated. The calculation is performed in the generalized quasiclassical approximation. Cillisions with an aimed parameter equal to 0 and recording of scattered ion at angles close to 180 deg were considered. Effect of MI dependence on angular momentum (AM) on the RS Coulomb excitation probability in the 86 Kr+ 238 U process at 400 MeV 86 Kr has been studied. For small AMs (I < 10), when the MI variation can be neglected, the Coulomb-nuclear interference leads to a marked shift of RS excitation probability maxima. However, with increasing transferred AM the convergence of probabilities conditioned with mutual compensation of phases shift related to the MI variation and Coulomb-nucleus interference, is noted. It is also noted that correct parameters of deformed nuclei extracted from experiments on the Coulomb excitation of high-spin states can be obtained only during simultaneous accountancy of both the Coulomb-nuclear interference and the MI variation of excited nuclei
Energy Technology Data Exchange (ETDEWEB)
Abrusci, Agnese; Snaith, Henry J. [Clarendon Laboratory, Department of Physics, University of Oxford (United Kingdom); Santosh Kumar, R. Sai; Petrozza, Annamaria [Center for Nano Science and Technology of IIT, Milano (Italy); Al-Hashimi, Mohammed; Heeney, Martin [Department of Chemistry and Centre for Plastic Electronics, Imperial College London (United Kingdom)
2011-07-08
Dye-sensitized solar cells (DSSC) are a realistic option for converting light to electrical energy. Hybrid architectures offer a vast materials library for device optimization, including a variety of metal oxides, organic and inorganic sensitizers, molecular, polymeric and electrolytic hole-transporter materials. In order to further improve the efficiency of solid-state dye-sensitized solar cells, recent attention has focused on using light absorbing polymers such as poly(3-hexylthiophene) (P3HT), to replace the more commonly used ''transparent'' 2,2',7,7'-tetrakis-(N,N-di-p-methoxyphenyl-amine)9,9'spiro-bifluorene (spiro-OMeTAD), in order to enhance the light absorption within thin films. As is the case with spiro-OMeTAD based solid-state DSSC, the P3HT-based devices improve significantly with the addition of lithium bis(trifluoromethylsulfonyl)imide salts (Li-TFSI), although the precise role of these additives has not yet been clarified in solid-state DSCs. Here, we present a thorough study on the effect of Li-TFSI in P3HT based solid-state DSSC incorporating an indolene-based organic sensitizer termed D102. Employing ultrafast transient absorption and cw-emission spectroscopy together with electronic measurements, we demonstrate a fine tuning of the energetic landscape of the active cell components by the local Coulomb field induced by the ions. This increases the charge transfer nature of the excited state on the dye, significantly accelerating electron injection into the TiO{sub 2}. We demonstrate that this ionic influence on the excited state energy is the primary reason for enhanced charge generation with the addition of ionic additives. The deepening of the relative position of the TiO{sub 2} conduction band, which has previously been thought to be the cause for enhanced charge generation in dye sensitized solar cells with the addition of lithium salts, appears to be of minor importance in this system. (Copyright copyright
Lifetimes of low-lying excited states in 50 36 86Kr
Henderson, J.; Chester, A.; Ball, G. C.; Caballero-Folch, R.; Domingo, T.; Drake, T. E.; Evitts, L. J.; Garnsworthy, A. B.; Hackman, G.; Hallam, S.; Moukaddam, M.; Ruotsalainen, P.; Smallcombe, J.; Smith, J. K.; Starosta, K.; Svensson, C. E.; Williams, J.
2018-04-01
Background: The evolution of nuclear magic numbers at extremes of isospin is a topic at the forefront of contemporary nuclear physics. N =50 is a prime example, with increasing experimental data coming to light on potentially doubly magic 100Sn and 78Ni at the proton-rich and proton-deficient extremes, respectively; however, experimental discrepancies exist in the data for less exotic systems. Purpose: In 86Kr the B (E 2 ;21+→01+) value—a key indicator of shell evolution—has been experimentally determined by two different methodologies, with the results deviating by 3 σ . Here, we report on a new high-precision measurement of this value, as well as the first measured lifetimes and hence transition strengths for the 22+ and 3(2) - states in the nucleus. Methods: The Doppler-shift attenuation method was implemented using the TRIUMF-ISAC γ -ray escape-suppressed spectrometer (TIGRESS) γ -ray spectrometer and the TIGRESS integrated plunger device. High-statistics Monte Carlo simulations were utilized to extract lifetimes in accordance with state-of-the-art methodologies. Results: Lifetimes of τ (21+)=336 ±4 (stat.)±20 (sys.) fs, τ (22+)=263 ±9 (stat.)±19 (sys.) fs, and τ (3(2) -)=73 ±6 (stat.)±32 (sys.) fs were extracted. This yields a transition strength for the first-excited state of B (E 2 ;21+→01+)=259 ±3 (stat.)±16 (sys.) e2 fm4. Conclusions: The measured lifetime disagrees with the previous Doppler-shift attenuation method measurement by more than 3 σ , while agreeing well with a previous value extracted from Coulomb excitation. The newly extracted B (E 2 ;21+→01+) value indicates a more significant reduction in the N =50 isotones approaching Z =40 .
Energy Technology Data Exchange (ETDEWEB)
Djouder, M., E-mail: djouder-madjid@ummto.dz; Kermoun, F.; Mitiche, M. D.; Lamrous, O. [Laboratoire de Physique et Chimie Quantique, Université Mouloud Mammeri Tizi-Ouzou, BP 17 RP, 15000 Tizi-Ouzou (Algeria)
2016-01-15
Dust particles observed in universe as well as in laboratory and technological plasma devices are still under investigation. At low temperature, these particles are strongly negatively charged and are able to form a 2D or 3D coulomb crystal. In this work, our aim was to check the ideal gas law validity for a 2D single-layer dust crystal recently reported in the literature. For this purpose, we have simulated, using the molecular dynamics method, its thermodynamic properties for different values of dust particles number and confinement parameters. The obtained results have allowed us to invalidate the ideal gas behaviour and to propose an effective equation of state which assumes a near zero dust temperature. Furthermore, the value of the calculated sound velocity was found to be in a good agreement with experimental data published elsewhere.
International Nuclear Information System (INIS)
Djouder, M.; Kermoun, F.; Mitiche, M. D.; Lamrous, O.
2016-01-01
Dust particles observed in universe as well as in laboratory and technological plasma devices are still under investigation. At low temperature, these particles are strongly negatively charged and are able to form a 2D or 3D coulomb crystal. In this work, our aim was to check the ideal gas law validity for a 2D single-layer dust crystal recently reported in the literature. For this purpose, we have simulated, using the molecular dynamics method, its thermodynamic properties for different values of dust particles number and confinement parameters. The obtained results have allowed us to invalidate the ideal gas behaviour and to propose an effective equation of state which assumes a near zero dust temperature. Furthermore, the value of the calculated sound velocity was found to be in a good agreement with experimental data published elsewhere
Integral equation for Coulomb problem
International Nuclear Information System (INIS)
Sasakawa, T.
1986-01-01
For short range potentials an inhomogeneous (homogeneous) Lippmann-Schwinger integral equation of the Fredholm type yields the wave function of scattering (bound) state. For the Coulomb potential, this statement is no more valid. It has been felt difficult to express the Coulomb wave function in a form of an integral equation with the Coulomb potential as the perturbation. In the present paper, the author shows that an inhomogeneous integral equation of a Volterra type with the Coulomb potential as the perturbation can be constructed both for the scattering and the bound states. The equation yielding the binding energy is given in an integral form. The present treatment is easily extended to the coupled Coulomb problems
Nonlinear phenomena in the highly excited state of C60
International Nuclear Information System (INIS)
Byrne, H.J.; Maser, W.K.; Kaiser, M.; Akselrod, L.; Anders, J.; Ruehle, W.W.; Zhou, X.Q.; Mittelbach, A.; Roth, S.
1993-01-01
Under high intensity illumination, the optical and electronic properties of fullerenes are seen to undergo dramatic, nonlinear changes. The photoluminescence emission is seen to increase with approximately the third power of the input intensity above an apparent threshold intensity. Associated with this nonlinear increase is the emergence of a long lifetime emission component and a redshifting of the emission spectrum. Above the threshold intensity the photoconductive response increases with approximately the cube of the input power. In the highly excited state, the photoconductive response becomes relatively temperature independent compared to the thermally activated behaviour observed at low intensities. The characteristics of the temperature dependence are associated with a metallic-like phase in the highly excited state and therefore an optically driven insulator to metal transition is proposed as a description of the observed phenomena. (orig.)
Lifetime measurements of the excited states in {sup 145} Sm
Energy Technology Data Exchange (ETDEWEB)
El-Badry, A M; Abdel Samie, Sh; Ahmad, A A [Depatment of Physics, Faculty of Science, ElMinia University, ElMinia, (Egypt); Kuroyanagi, T; Odahara, A; Gono, Y; Morinobu, S [Tandem Accelerator Laboratory, Department of Physics, Kyushu University, (Japan)
1997-12-31
Lifetime of the excited levels in {sup 145} Sm has been measured through the {sup 139} La ({sup 10} B, 4 n){sup 145} Sm nuclear reaction. The optimal beam energy of 49 MeV was determined from the measurements of the excitation function and Cascade program. With the possibility of studying lifetime of this nucleus a conventional plunger system have been designed and constructed at kyushu University tandem accelerator laboratory. A La target of 0.22 mg/cm{sup 2} thickness which was evaporated onto a Au foil of 2 mg/cm{sup 2} thickness was used. Since the recoil velocity was estimated to be 1.76 mm/ns (beta 0.00585), the measurable time range resulted in the range from 5 Ps to 5 ns. The single spectra measurements were performed at the 20 plunger positions in the range from 10 {mu} to 10 mm. Analyses of the data were carried using hypermet and/or GF2 program to obtain the lifetimes. A new list of lifetimes for 12 excited states up to 3.922 MeV excitations for {sup 145} Sm were determined for the first time. Decay curves of the these transitions are discussed. The new lifetimes of excited states in {sup 145} Sm enabled us to understand the electromagnetic properties. The deduced transition probabilities were established and compared with that of N = 83 isotones and the closed shell nucleus {sup 144} Sm. In addition, a nuclear structure of {sup 145} Sm have been discussed and proposed in framework of the shell model. 4 figs., 1 tab.
On the Coulomb displacement energy
International Nuclear Information System (INIS)
Sato, H.
1976-01-01
The Coulomb displacement energies of the T=1/2 mirror nuclei (A=15,17,27,29,31,33,39 and 41) are re-examined with the best available HF wave functions (the DME and the Skyrme II interaction), with the inclusion of all electromagnetic corrections. The results are compared with the experimental s.p. charge dependent energies extracted from the experimental data taking into account admixtures of core-excitation corrections with the help of present shell-model and co-existence model calculations. Although the so-called Nolen-Schiffer anomaly is not removed by these improvements, it is found that the remaining observed anomalies in the ground states of s.p. and s.h. systems can be resolved with the introduction of a simple, phenomenological charge symmetry breaking nucleon-nucleon force. This force can also account for the observed anomalies in the higher excited s.p. states, while those of the deeper s.h. states need further explanation. (Auth.)
Magnetic excitations in intermediate valence semiconductors with singlet ground state
International Nuclear Information System (INIS)
Kikoin, K.A.; Mishchenko, A.S.
1994-01-01
The explanation of the origin inelastic peaks in magnetic neutron scattering spectra of the mixed-valent semiconductor SmB 6 is proposed. It is shown that the excitonic theory of intermediate valence state not only gives the value of the peak frequency but also explains the unusual angular dependence of intensity of inelastic magnetic scattering and describes the dispersion of magnetic excitations in good agreement with experiment
Density-dependent phonoriton states in highly excited semiconductors
International Nuclear Information System (INIS)
Nguyen Hong Quang; Nguyen Minh Khue; Nguyen Que Huong
1995-09-01
The dynamical aspects of the phonoriton state in highly-photoexcited semiconductors is studied theoretically. The effect of the exciton-exciton interaction and nonbosonic character of high-density excitons are taken into account. Using Green's function method and within the Random Phase Approximation it is shown that the phonoriton dispersion and damping are very sensitive to the exciton density, characterizing the excitation degree of semiconductors. (author). 18 refs, 3 figs
Stuchbery, A. E.; Ryan, C. G.; Bolotin, H. H.; Morrison, I.; Sie, S. H.
1981-07-01
The enhanced transient hyperfine field manifest at the nuclei of swiftly recoiling ions traversing magnetized ferromagnetic materials was utilized to measure the gyromagnetic ratios of the 2 +1, 2 +2 and 4 +1 states in 198Pt by the thin-foil technique. The states of interest were populated by Coulomb excitation using a beam of 220 MeV 58Ni ions. The results obtained were: g(2 +1) = 0.324 ± 0.026; g(2 +2) = 0.34 ± 0.06; g(4 +1) = 0.34 ± 0.06. In addition, these measurements served to discriminate between the otherwise essentially equally probable values previously reported for the E2/M1 ratio of the 2 +2 → 2 +1 transition in 198Pt. We also performed interacting boson approximation (IBA) model-based calculations in the O(6) limit symmetry, with and without inclusion of a small degree of symmetry breaking, and employed the M1 operator in both first- and second-order to obtain M1 selection rules and to calculate gyromagnetic ratios of levels. When O(6) symmetry is broken, there is a predicted departure from constancy of the g-factors which provides a good test of the nuclear wave function. Evaluative comparisons are made between these experimental and predicted g-factors.
Molecular and excited state properties of isomeric scarlet disperse dyes
Lim, Jihye; Szymczyk, Malgorzata; Mehraban, Nahid; Ding, Yi; Parrillo-Chapman, Lisa; El-Shafei, Ahmed; Freeman, Harold S.
2018-06-01
This work was part of an investigation aimed at characterizing the molecular and excited state properties of currently available disperse dyes developed to provide stability to extensive sunlight exposures when adsorbed on poly(ethylene terephthalate) (PET) fibers. Having completed the characterization of yellow, magenta, and cyan disperse dyes for PET-based fabrics used outdoors, our attention turned to the colors designed to enhance the color gamut of a standard 4-member (cyan/yellow/magenta/black) color set. The present study pertained specifically to the characterization of commercially available scarlet dyes. In this regard, HPLC analysis showed that a scarlet product used for PET coloration was mainly a 70/30 mixture of dyes, and the use of HRMS and single crystal X-ray diffraction analyses indicated that these two dyes were azo compounds derived from isomeric pyridine-based couplers which differed in the location of the primary amino (sbnd NH2) and anilino (sbnd NHPh) groups attached to the pyridine ring. One dye structure has the sbnd NHPh group para to the azo group (Sc2), while the other has that group in the ortho position (Sc3). The presence of either ortho substituent provides photostabilization through intramolecular H-bonding with the azo moiety. Further, results from molecular modeling studies showed that the lower excited state oxidation potential of Sc3 relative to that of Sc2 allows Sc3 to function as an energy quencher for the excited state of Sc2 - through thermodynamically favorable electron transfer.
Wigner function for the generalized excited pair coherent state
International Nuclear Information System (INIS)
Meng Xiangguo; Wang Jisuo; Liang Baolong; Li Hongqi
2008-01-01
This paper introduces the generalized excited pair coherent state (GEPCS). Using the entangled state |η> representation of Wigner operator, it obtains the Wigner function for the GEPCS. In the ρ-γ phase space, the variations of the Wigner function distributions with the parameters q, α, k and l are discussed. The tomogram of the GEPCS is calculated with the help of the Radon transform between the Wigner operator and the projection operator of the entangled state |η 1 , η 2 , τ 1 , τ 2 >. The entangled states |η> and η 1 , η 2 , τ 1 , τ 2 > provide two good representative space for studying the Wigner functions and tomograms of various two-mode correlated quantum states
Rotational Spectra in 29 Vibrationally Excited States of Interstellar Aminoacetonitrile
Energy Technology Data Exchange (ETDEWEB)
Kolesniková, L.; Alonso, E. R.; Mata, S.; Alonso, J. L. [Grupo de Espectroscopia Molecular (GEM), Edificio Quifima, Área de Química-Física, Laboratorios de Espectroscopia y Bioespectroscopia, Parque Científico UVa, Unidad Asociada CSIC, Universidad de Valladolid, E-47011 Valladolid (Spain)
2017-04-01
We report a detailed spectroscopic investigation of the interstellar aminoacetonitrile, a possible precursor molecule of glycine. Using a combination of Stark and frequency-modulation microwave and millimeter wave spectroscopies, we observed and analyzed the room-temperature rotational spectra of 29 excited states with energies up to 1000 cm{sup −1}. We also observed the {sup 13}C isotopologues in the ground vibrational state in natural abundance (1.1%). The extensive data set of more than 2000 new rotational transitions will support further identifications of aminoacetonitrile in the interstellar medium.
Excitation of higher lying energy states in a rubidium DPAL
Wallerstein, A. J.; Perram, Glen; Rice, Christopher A.
2018-02-01
The spontaneous emission in a cw rubidium diode dumped alkali laser (DPAL) system was analyzed. The fluorescence from higher lying states decreases with additional buffer gas. The intermediate states (7S, 6P, 5D) decay more slowly with buffer gas and scale super-linearly with alkali density. A detailed kinetic model has been constructed, where the dominant mechanisms are energy pooling and single photon ionization. It also includes pumping into the non-Lorentzian wings of absorption profiles, fine structure mixing, collisional de-excitation, and Penning ionization. Effects of ionization in a high powered CW rubidium DPAL were assessed.
Chemical modulation of electronic structure at the excited state
Li, F.; Song, C.; Gu, Y. D.; Saleem, M. S.; Pan, F.
2017-12-01
Spin-polarized electronic structures are the cornerstone of spintronics, and have thus attracted a significant amount of interest; in particular, researchers are looking into how to modulate the electronic structure to enable multifunctional spintronics applications, especially in half-metallic systems. However, the control of the spin polarization has only been predicted in limited two-dimensional systems with spin-polarized Dirac structures and is difficult to achieve experimentally. Here, we report the modulation of the electronic structure in the light-induced excited state in a typical half-metal, L a1 /2S r1 /2Mn O3 -δ . According to the spin-transport measurements, there appears a light-induced increase in magnetoresistance due to the enhanced spin scattering, which is closely associated with the excited spin polarization. Strikingly, the light-induced variation can be enhanced via alcohol processing and reduced by oxygen annealing. X-ray photoelectron spectroscopy measurements show that in the chemical process, a redox reaction occurs with a change in the valence of Mn. Furthermore, first-principles calculations reveal that the change in the valence of Mn alters the electronic structure and consequently modulates the spin polarization in the excited state. Our findings thus report a chemically tunable electronic structure, demonstrating interesting physics and the potential for multifunctional applications and ultrafast spintronics.
Liu, Xiaosong; Wang, Yung Jui; Barbiellini, Bernardo; Hafiz, Hasnain; Basak, Susmita; Liu, Jun; Richardson, Thomas; Shu, Guojiun; Chou, Fangcheng; Weng, Tsu-Chien; Nordlund, Dennis; Sokaras, Dimosthenis; Moritz, Brian; Devereaux, Thomas P; Qiao, Ruimin; Chuang, Yi-De; Bansil, Arun; Hussain, Zahid; Yang, Wanli
2015-10-21
LiFePO4 is a battery cathode material with high safety standards due to its unique electronic structure. We performed systematic experimental and theoretical studies based on soft X-ray emission, absorption, and hard X-ray Raman spectroscopy of LixFePO4 nanoparticles and single crystals. The results clearly show a non-rigid electron-state reconfiguration of both the occupied and unoccupied Fe-3d and O-2p states during the (de)lithiation process. We focus on the energy configurations of the occupied states of LiFePO4 and the unoccupied states of FePO4, which are the critical states where electrons are removed and injected during the charge and discharge process, respectively. In LiFePO4, the soft X-ray emission spectroscopy shows that, due to the Coulomb repulsion effect, the occupied Fe-3d states with the minority spin sit close to the Fermi level. In FePO4, the soft X-ray absorption and hard X-ray Raman spectroscopy show that the unoccupied Fe-3d states again sit close to the Fermi level. These critical 3d electron state configurations are consistent with the calculations based on modified Becke and Johnson potentials GGA+U (MBJGGA+U) framework, which improves the overall lineshape prediction compared with the conventionally used GGA+U method. The combined experimental and theoretical studies show that the non-rigid electron state reshuffling guarantees the stability of oxygen during the redox reaction throughout the charge and discharge process of LiFePO4 electrodes, leading to the intrinsic safe performance of the electrodes.
International Nuclear Information System (INIS)
Dobryakov, A. L.; Quick, M.; Ioffe, I. N.; Granovsky, A. A.; Ernsting, N. P.; Kovalenko, S. A.
2014-01-01
We show that femtosecond stimulated Raman spectroscopy can record excited-state spectra in the absence of actinic excitation, if the Raman pump is in resonance with an electronic transition. The approach is illustrated by recording S 1 and S 0 spectra of trans-azobenzene in n-hexane. The S 1 spectra were also measured conventionally, upon nπ* (S 0 → S 1 ) actinic excitation. The results are discussed and compared to earlier reports
Lifetime measurements of excited states in 73As
International Nuclear Information System (INIS)
Singh, K.P.; Kavakand, T.; Hajivaliei, M.
2004-01-01
The excited states of 73 As have been investigated via the 73 Ge(p, nγ) 73 As reaction with proton beam energies from 2.5–4.3 MeV. The lifetimes of the levels at 769.6, 860.5, 1177.8, 1188.7, 1274.9, 1344.1, 1557.1 and 1975.2 keV excitation energies have been measured for the first time using the Doppler shift attenuation method. The angular distributions have been used to assign the spins and the multipole mixing ratios using statistical theory for compound nuclear reactions. The ambiguity in the spin values for the various levels has been removed. The multipole mixing ratios for eight γ-transitions have been newly measured. (author)
Application of spectroscopy and super-resolution microscopy: Excited state
Energy Technology Data Exchange (ETDEWEB)
Bhattacharjee, Ujjal [Iowa State Univ., Ames, IA (United States)
2016-02-19
Photophysics of inorganic materials and organic molecules in complex systems have been extensively studied with absorption and emission spectroscopy.1-4 Steady-state and time-resolved fluorescence studies are commonly carried out to characterize excited-state properties of fluorophores. Although steady-state fluorescence measurements are widely used for analytical applications, time-resolved fluorescence measurements provide more detailed information about excited-state properties and the environment in the vicinity of the fluorophore. Many photophysical processes, such as photoinduced electron transfer (PET), rotational reorientation, solvent relaxation, and energy transfer, occur on a nanosecond (10^{-9} s) timescale, thus affecting the lifetime of the fluorophores. Moreover, time-resolved microscopy methods, such as lifetimeimaging, combine the benefits of the microscopic measurement and information-rich, timeresolved data. Thus, time-resolved fluorescence spectroscopy combined with microscopy can be used to quantify these processes and to obtain a deeper understanding of the chemical surroundings of the fluorophore in a small area under investigation. This thesis discusses various photophysical and super-resolution microscopic studies of organic and inorganic materials, which have been outlined below.
The Coulomb gap and low energy statistics for Coulomb glasses
International Nuclear Information System (INIS)
Glatz, Andreas; Vinokur, Valerii M; Bergli, Joakim; Kirkengen, Martin; Galperin, Yuri M
2008-01-01
We study the statistics of local energy minima in the configuration space of two-dimensional lattice Coulomb glasses with site disorder and the behavior of the Coulomb gap depending on the strength of random site energies. At intermediate disorder, i.e., when the typical strength of the disorder is of the same order as the nearest-neighbor Coulomb energy, the high energy tail of the distribution of the local minima is exponential. We furthermore analyze the structure of the local minima and show that most sites of the system have the same occupation numbers in all of these states. The density of states (DOS) shows a transition from the crystalline state at zero disorder (with a hard gap) to an intermediate, probably glassy state with a Coulomb gap. We analyze this Coulomb gap in some detail and show that the DOS deviates slightly from the traditional linear behavior in 2D. For finite systems these intermediate Coulomb gap states disappear for large disorder strengths and only a random localized state in which all electrons are in the minima of the random potential exists. Dedication: This paper is dedicated to Thomas Nattermann, our dearest friend, brilliant colleague, and outstanding teacher
DEFF Research Database (Denmark)
Bohr, Henrik; Malik, F. Bary
2013-01-01
The observed multiple de-excitation pathways of photo-absorbed electronic excited state in the peridinin–chlorophyll complex, involving both energy and charge transfers among its constituents, are analyzed using the bio-Auger (B-A) theory. It is also shown that the usually used F¨orster–Dexter...
Supersymmetric quantum mechanics and higher excited states of a non-polynomial potential
International Nuclear Information System (INIS)
Drigo Filho, E.; Ricotta, R.M.
1989-03-01
Supersymmetric quantum mechanics is used to evaluate new excited states of a non-polynomial potential. This illustrates a method of evaluating higher excited states of quantum mechanical potentials. (A.C.A.S.) [pt
Spectroscopic properties of the S1 state of linear carotenoids after excess energy excitation
Kuznetsova, Valentyna; Southall, June; Cogdell, Richard J.; Fuciman, Marcel; Polívka, Tomáš
2017-09-01
Properties of the S1 state of neurosporene, spheroidene and lycopene were studied after excess energy excitation in the S2 state. Excitation of carotenoids into higher vibronic levels of the S2 state generates excess vibrational energy in the S1 state. The vibrationally hot S1 state relaxes faster when carotenoid is excited into the S2 state with excess energy, but the S1 lifetime remains constant regardless of which vibronic level of the S2 state is excited. The S∗ signal depends on excitation energy only for spheroidene, which is likely due to asymmetry of the molecule, facilitating conformations responsible for the S∗ signal.
Excited states in 146Sm and 147Sm
International Nuclear Information System (INIS)
Kownacki, J.; Sujkowski, Z.; Hammaren, E.; Liukkonen, E.; Piiparinen, M.; Lindblad, Th.; Ryde, H.
1979-10-01
The sup(144,146)Nd(α,xn) and sup(146,148)Nd( 3 He,xn) reactions with Esub(α) = 20 - 43 MeV and E 3 sub(He) = 19 - 27 MeV are used to investigate excited states in the isotopes 146 Sm and 147 Sm. The experiments involve measurements of singles γ-ray spectra and conversion electron spectra, γ-ray angular distributions and three parameter (E sub(γ)E sub(γ) time) coincidences. From these experiments information is obtained for states with spin up to I = 13 + and I = 27/2 - , respectively, These states are interpeted within the framework of the cluster-vibration model (CVM) as well as the shell model. (author)
Isoelectronic study of triply excited Li-like states
International Nuclear Information System (INIS)
Benis, E P; Zouros, T J M; Gorczyca, T W; Zamkov, M; Richard, P
2003-01-01
Absolute doubly differential cross sections (DDCSs) for the production and Auger decay of the intra-shell 2s2p 22 D triply excited state formed in collisions of He-like ions (Z = 5-9) with H 2 were determined experimentally, using zero-degree Auger projectile electron spectroscopy. The 2 D e state was directly produced by 180 deg. resonant scattering of the quasi-free H 2 electrons from the 1s2s 3 S metastable state of the ion. Resonant energies and DDCSs calculated using the R-matrix approach within the electron scattering model were found to be in good overall agreement with experiment. (letter to the editor)
Psoralen phototherapy and the possible involvement of triplet excited states
International Nuclear Information System (INIS)
Bensasson, R.V.; Salet, E.J.; Land, E.J.
1979-01-01
Psoralens are important drugs used in the phototherapy of psoriasis and vitiligo. It has been predicted that the triplet excited state of psoralen is photoactive. The authors have employed pulse radiolysis and laser flash photolysis to determine the quantum yields of formation of the triplet states of psoralens and related molecules including 4'5' dihydropsoralen, a model for 4'5' psoralenpyrimidine mono-adducts. The triplet spectra were used to follow the reactions of the triplets with thymine and tryptophan. Such reactions may take place via a charge transfer mechanism. For 8-methoxy psoralen, in addition to triplet formation, photoionization was detected using high laser intensities. Although significant yields of psoralen triplets are formed, and some such triplets react with thymine, it is too early yet to say definitely whether or not the therapeutic action of psoralens is mediated via such triplet states. (Auth.)
Excited states above the proton threshold in {sup 26}Si
Energy Technology Data Exchange (ETDEWEB)
Komatsubara, T. [Institute for Basic Science (IBS), Rare Isotope Science Project, Yuseong-gu Daejeon (Korea, Republic of); Kubono, S.; Ito, Y. [RIKEN, Saitama (Japan); Hayakawa, T.; Shizuma, T. [Japan Atomic Energy Agency, Tokai, Ibaraki (Japan); Ozawa, A.; Ishibashi, Y. [University of Tsukuba, Institute of Physics, Tsukuba, Ibaraki (Japan); Moriguchi, T. [National Cerebral and Cardiovascular Center Research Institute, Suita, Osaka (Japan); Yamaguchi, H.; Kahl, D. [University of Tokyo, Wako Branch, Center for Nuclear Study (CNS), Wako, Saitama (Japan); Hayakawa, S. [Laboratori Nazionali del Sud-INFN, Catania (Italy); Nguyen Binh, Dam [Vietnamese Academy for Science and Technology, Institute of Physics, Hanoi (Viet Nam); Chen, A.A.; Chen, J. [McMaster University, Hamilton, Ontario (Canada); Setoodehnia, K. [University of Notre Dame, Department of Physics, Notre Dame, Indiana (United States); Kajino, T. [National Astronomical Observatory, Tokyo (Japan); University of Tokyo, Department of Astronomy, Graduate School of Science, Tokyo (Japan)
2014-09-15
The level scheme above the proton threshold in {sup 26}Si is crucial for evaluating the {sup 25}Al(p, γ){sup 26}Si stellar reaction, which is important for understanding the astrophysical origin of the long-lived cosmic radioactivity {sup 26}Al(T{sub 1/2} = 7.17 x 10{sup 5} y) in the Galaxy. The excited states in {sup 26}Si have been studied using an in-beam γ-ray spectroscopy technique with the {sup 24}Mg({sup 3}He, nγ){sup 26}Si reaction. γ-rays with energies up to 4.6 MeV emitted from excited states in {sup 26}Si have been measured using large volume HPGe detectors. The spin-parity of one of the most important states reported recently at 5890.0keV has been assigned as 0{sup +} by γ-γ angular correlation measurements in this work. (orig.)
Excited-State Dynamics of Oxyluciferin in Firefly Luciferase
Snellenburg, Joris J.
2016-11-23
The color variations of light emitted by some natural and mutant luciferases are normally attributed to collective factors referred to as microenvironment effects; however, the exact nature of these interactions between the emitting molecule (oxyluciferin) and the active site remains elusive. Although model studies of noncomplexed oxyluciferin and its variants have greatly advanced the understanding of its photochemistry, extrapolation of the conclusions to the real system requires assumptions about the polarity and proticity of the active site. To decipher the intricate excited-state dynamics, global and target analysis is performed here for the first time on the steady-state and time-resolved spectra of firefly oxyluciferin complexed with luciferase from the Japanese firefly (Luciola cruciata). The experimental steady-state and time resolved luminescence spectra of the oxyluciferin/luciferase complex in solution are compared with the broadband time-resolved firefly bioluminescence recorded in vivo. The results demonstrate that de-excitation of the luminophore results in a complex cascade of photoinduced proton transfer processes and can be interpreted by the pH dependence of the emitted light. It is confirmed that proton transfer is the central event in the spectrochemistry of this system for which any assignment of the pH dependent emission to a single chemical species would be an oversimplification.
Excited-State Dynamics of Oxyluciferin in Firefly Luciferase
Snellenburg, Joris J.; Laptenok, Sergey P.; DeSa, Richard J.; Naumov, Pance; Solntsev, Kyril M.
2016-01-01
The color variations of light emitted by some natural and mutant luciferases are normally attributed to collective factors referred to as microenvironment effects; however, the exact nature of these interactions between the emitting molecule (oxyluciferin) and the active site remains elusive. Although model studies of noncomplexed oxyluciferin and its variants have greatly advanced the understanding of its photochemistry, extrapolation of the conclusions to the real system requires assumptions about the polarity and proticity of the active site. To decipher the intricate excited-state dynamics, global and target analysis is performed here for the first time on the steady-state and time-resolved spectra of firefly oxyluciferin complexed with luciferase from the Japanese firefly (Luciola cruciata). The experimental steady-state and time resolved luminescence spectra of the oxyluciferin/luciferase complex in solution are compared with the broadband time-resolved firefly bioluminescence recorded in vivo. The results demonstrate that de-excitation of the luminophore results in a complex cascade of photoinduced proton transfer processes and can be interpreted by the pH dependence of the emitted light. It is confirmed that proton transfer is the central event in the spectrochemistry of this system for which any assignment of the pH dependent emission to a single chemical species would be an oversimplification.
An excited state underlies gene regulation of a transcriptional riboswitch
Zhao, Bo; Guffy, Sharon L.; Williams, Benfeard; Zhang, Qi
2017-01-01
Riboswitches control gene expression through ligand-dependent structural rearrangements of the sensing aptamer domain. However, we found that the Bacillus cereus fluoride riboswitch aptamer adopts identical tertiary structures in solution with and without ligand. Using chemical exchange saturation transfer (CEST) NMR spectroscopy, we revealed that the structured ligand-free aptamer transiently accesses a low-populated (~1%) and short-lived (~3 ms) excited conformational state that unravels a conserved ‘linchpin’ base pair to signal transcription termination. Upon fluoride binding, this highly localized fleeting process is allosterically suppressed to activate transcription. We demonstrated that this mechanism confers effective fluoride-dependent gene activation over a wide range of transcription rates, which is essential for robust toxicity response across diverse cellular conditions. These results unveil a novel switching mechanism that employs ligand-dependent suppression of an aptamer excited state to coordinate regulatory conformational transitions rather than adopting distinct aptamer ground-state tertiary architectures, exemplifying a new mode of ligand-dependent RNA regulation. PMID:28719589
Gamma decays, lifetimes and spins of 47V excited states
International Nuclear Information System (INIS)
Thompson, J.V.; Bell, R.A.I.; Carlson, E.; Najam, M.R.
1974-11-01
The nucleus 47 V has been studied using the 47 Ti(p,nγ) 47 V reaction, with isotopically enriched 47 Ti targets, incident proton energies from 4.7 to 5.4 MeV, and Ge(Li) gamma-ray detectors. The previously unreported gamma decay of the second excited state was observed. Energies of the first seven excited states were deduced to be 87.5 +- 0.1, 145.7 +- 0.2, 259.6 +-0.4, 660.1 +- 0.3, 1138.3 +- 0.4, 1272.2 +- 0.4 and 1295.1 +- 0.4 keV. Their gamma-decay branching ratios were measured. The lifetimes of the last four mentioned states were deduced from attenuated Doppler shifts to be [680-340, 680+1400], [960-440, 960+1700], [390-150, 390+390], and > 750 fs respectively. Angular distribution measurements resulted in the assignment of Jsup(π) = 9/2 - to the 1272 keV level and J = 9/2 or 11/2 to the 1295 keV level. The results are discussed in the light of the Coriolis coupling model. (author)
Splitting of the luminescent excited state of the uranyl ion
International Nuclear Information System (INIS)
Flint, C.D.; Sharma, P.; Tanner, P.A.
1982-01-01
The luminescence spectra of some uranyl compounds has been studied. It has been proposed that the splitting of the luminescent excited state of the uranyl ion is due to a descent in symmetry experienced by the uranyl ion when it is placed in a crystal field. In recent years there has been developed a highly successful model of the electronic structure of the uranyl ion. In this paper the authors use this model to interpret the luminescence spectra of a variety of uranyl compounds
Linear-scaling quantum mechanical methods for excited states.
Yam, ChiYung; Zhang, Qing; Wang, Fan; Chen, GuanHua
2012-05-21
The poor scaling of many existing quantum mechanical methods with respect to the system size hinders their applications to large systems. In this tutorial review, we focus on latest research on linear-scaling or O(N) quantum mechanical methods for excited states. Based on the locality of quantum mechanical systems, O(N) quantum mechanical methods for excited states are comprised of two categories, the time-domain and frequency-domain methods. The former solves the dynamics of the electronic systems in real time while the latter involves direct evaluation of electronic response in the frequency-domain. The localized density matrix (LDM) method is the first and most mature linear-scaling quantum mechanical method for excited states. It has been implemented in time- and frequency-domains. The O(N) time-domain methods also include the approach that solves the time-dependent Kohn-Sham (TDKS) equation using the non-orthogonal localized molecular orbitals (NOLMOs). Besides the frequency-domain LDM method, other O(N) frequency-domain methods have been proposed and implemented at the first-principles level. Except one-dimensional or quasi-one-dimensional systems, the O(N) frequency-domain methods are often not applicable to resonant responses because of the convergence problem. For linear response, the most efficient O(N) first-principles method is found to be the LDM method with Chebyshev expansion for time integration. For off-resonant response (including nonlinear properties) at a specific frequency, the frequency-domain methods with iterative solvers are quite efficient and thus practical. For nonlinear response, both on-resonance and off-resonance, the time-domain methods can be used, however, as the time-domain first-principles methods are quite expensive, time-domain O(N) semi-empirical methods are often the practical choice. Compared to the O(N) frequency-domain methods, the O(N) time-domain methods for excited states are much more mature and numerically stable, and
Normalized Excited Squeezed Vacuum State and Its Applications
International Nuclear Information System (INIS)
Meng Xiangguo; Wang Jisuo; Liang Baolong
2007-01-01
By using the intermediate coordinate-momentum representation in quantum optics and generating function for the normalization of the excited squeezed vacuum state (ESVS), the normalized ESVS is obtained. We find that its normalization constants obtained via two new methods are uniform and a new form which is different from the result obtained by Zhang and Fan [Phys. Lett. A 165 (1992) 14]. By virtue of the normalization constant of the ESVS and the intermediate coordinate-momentum representation, the tomogram of the normalized ESVS and some useful formulae are derived.
Study of the first excited state in 5Li
International Nuclear Information System (INIS)
Gagne, R.M.; Fou, C.M.; Ward, S.
1975-01-01
The reaction 6 Li( 3 He,α) 5 Li(α)p was studied with a 1.8MeV incident 3 He beam. Coincidence spectra (α-α) were measured at theta 1 =25 deg, 35 deg, 40 deg and theta 2 =-150 deg. The purpose was to locate the first excited state of 5 Li. The analysis yields E(x)=3.2+0.2MeV and GAMMA=1.5+-0.5MeV
Excited state dynamics of beta-carotene explored with dispersed multi-pulse transient absorption
Larsen, D.S.; Papagiannakis, E.; van Stokkum, I.H.M.; Vengris, M.; Kennis, J.T.M.; van Grondelle, R.
2003-01-01
The excited-state dynamics of β-carotene in hexane was studied with dispersed ultrafast transient absorption techniques. A new excited state is produced after blue-edge excitation. Pump-repump-probe and pump-dump-probe measurements identified and characterized this state, termed S‡, which exhibits a
Energy Technology Data Exchange (ETDEWEB)
Egidi, Franco, E-mail: franco.egidi@sns.it; Segado, Mireia; Barone, Vincenzo, E-mail: vincenzo.barone@sns.it [Scuola Normale Superiore, Piazza dei Cavalieri, 7 I-56126 Pisa (Italy); Koch, Henrik [Department of Chemistry, Norwegian University of Science and Technology, 7491 Trondheim (Norway); Cappelli, Chiara [Dipartimento di Chimica e Chimica Industriale, Università di Pisa, via G. Moruzzi, 3 I-56124 Pisa (Italy)
2014-12-14
In this work, we report a comparative study of computed excitation energies, oscillator strengths, and excited-state energy gradients of (S)-nicotine, chosen as a test case, using multireference methods, coupled cluster singles and doubles, and methods based on time-dependent density functional theory. This system was chosen because its apparent simplicity hides a complex electronic structure, as several different types of valence excitations are possible, including n-π{sup *}, π-π{sup *}, and charge-transfer states, and in order to simulate its spectrum it is necessary to describe all of them consistently well by the chosen method.
International Nuclear Information System (INIS)
Kapshay, V.N.; Skachkov, N.B.
1979-01-01
A composite system of two relativistic particles is studied on the basis of the Kadyshevsky quasipotential equation, in which the ''Coulomb'' potential is taken in the form of a propagator of the massless-scalar-particle exchange. The obtained exact solutions to this equation are shown to be a geometrical generalization of nonrelativistic Coulomb wave functions in the sense of change of the Euclidean geometry of momentum space to the Lobachevsky geometry
The Astrophysical Weeds: Rotational Transitions in Excited Vibrational States
Alonso, José L.; Kolesniková, Lucie; Alonso, Elena R.; Mata, Santiago
2017-06-01
The number of unidentified lines in the millimeter and submillimeter wave surveys of the interstellar medium has grown rapidly. The major contributions are due to rotational transitions in excited vibrational states of a relatively few molecules that are called the astrophysical weeds. necessary data to deal with spectral lines from astrophysical weeds species can be obtained from detailed laboratory rotational measurements in the microwave and millimeter wave region. A general procedure is being used at Valladolid combining different time and/or frequency domain spectroscopic tools of varying importance for providing the precise set of spectroscopic constants that could be used to search for this species in the ISM. This is illustrated in the present contribution through its application to several significant examples. Fortman, S. M., Medvedev, I. R., Neese, C.F., & De Lucia, F.C. 2010, ApJ,725, 1682 Rotational Spectra in 29 Vibrationally Excited States of Interstellar Aminoacetonitrile, L. Kolesniková, E. R. Alonso, S. Mata, and J. L. Alonso, The Astrophysical Journal Supplement Series 2017, (in press).
Probing the Locality of Excited States with Linear Algebra.
Etienne, Thibaud
2015-04-14
This article reports a novel theoretical approach related to the analysis of molecular excited states. The strategy introduced here involves gathering two pieces of physical information, coming from Hilbert and direct space operations, into a general, unique quantum mechanical descriptor of electronic transitions' locality. Moreover, the projection of Hilbert and direct space-derived indices in an Argand plane delivers a straightforward way to visually probe the ability of a dye to undergo a long- or short-range charge-transfer. This information can be applied, for instance, to the analysis of the electronic response of families of dyes to light absorption by unveiling the trend of a given push-pull chromophore to increase the electronic cloud polarization magnitude of its main transition with respect to the size extension of its conjugated spacer. We finally demonstrate that all the quantities reported in this article can be reliably approximated by a linear algebraic derivation, based on the contraction of detachment/attachment density matrices from canonical to atomic space. This alternative derivation has the remarkable advantage of a very low computational cost with respect to the previously used numerical integrations, making fast and accurate characterization of large molecular systems' excited states easily affordable.
Excited state mass spectra of singly charmed baryons
Energy Technology Data Exchange (ETDEWEB)
Shah, Zalak; Kumar Rai, Ajay [Sardar Vallabhbhai National Institute of Technology, Department of Applied Physics, Surat, Gujarat (India); Thakkar, Kaushal [GIDC Degree Engineering College, Department of Applied Sciences and Humanities, Abrama (India); Vinodkumar, P.C. [Sardar Patel University, Department of Physics, V.V. Nagar (India)
2016-10-15
Mass spectra of excited states of the singly charmed baryons are calculated using the hypercentral description of the three-body system. The baryons consist of a charm quark and light quarks (u, d and s) are studied in the framework of QCD motivated constituent quark model. The form of the confinement potential is hyper-Coloumb plus power potential with potential index ν, varying from 0.5 to 2.0. The first-order correction to the confinement potential is also incorporated in this approach. The radial as well as orbital excited state masses of Σ{sub c}{sup ++}, Σ{sub c}{sup +}, Σ{sub c}{sup 0}, Ξ{sub c}{sup +}, Ξ{sub c}{sup 0}, Λ{sub c}{sup +}, Ω{sub c}{sup 0} baryons, are reported in this paper. We have incorporated spin-spin, spin-orbit and tensor interactions perturbatively in the present study. The semi-electronic decay of Ω{sub c} and Ξ{sub c} are also calculated using the spectroscopic parameters of these baryons. The computed results are compared with other theoretical predictions as well as with the available experimental observations. We also construct the Regge trajectory in (n{sub r},M{sup 2}) and (J,M{sup 2}) planes for these baryons. (orig.)
Calculation of nuclear excitation in an electron transition
Energy Technology Data Exchange (ETDEWEB)
Pisk, K. (Institut Rudjer Boskovic, Zagreb (Yugoslavia)); Kaliman, Z. (Rijeka Univ. (Yugoslavia). Faculty of Pedagogics); Logan, B.A. (Ottawa Univ., ON (Canada). Ottawa-Carleton Centre for Physics)
1989-11-06
We have made a theoretical investigation of nuclear excitation during an electron transition (NEET). Our approach allows us to express the NEET probabilities in terms of the excited nuclear level width, the energy difference between the nuclear and electron transition, the Coulomb interaction between the initial electron states, and the electron level width. A comparison is made with the available experimental results. (orig.).
Dependence of isobar-analog state properties on variable part of Coulomb potential
International Nuclear Information System (INIS)
Dzhafarov, I.G.; Kuliev, A.A.; Salamov, D.I.
1986-01-01
Within the framework of the self-consistent approach and with the method of strength functions the fragmentation of isobar-analog state (IAS) properties for all isobarie 0 + -states is investigated. Microscopic values of IAS energy, matrix elements of allowed and forbidden Fermi transitions as well as isospin impurity values in ground states of parent nuclei are obtained. Numerical calculations carried out for 42 Ca 42 Sc, 48 Ca 48 Sc, 64 Zn 64 Ga, 66 Zn 66 Ga, 90 Zr 90 Nb, 208 Pb 208 Bi isobaric nuclei with Woods-Saxon potential, are compared with predictions of different approches and experiment. The developed model by the authors permits to describe sufficiently well the experimental data
New approximation to the bound states of Schroedinger operators with coulomb interaction
International Nuclear Information System (INIS)
Nunez, M.A.; Izquierdo B., G.
1994-01-01
In this work, the authors present a mathematical formulation of the physical fact that the bound states of a quantum system confined into a box Ω (with impenetrable walls) are similar to those of the unconfined system, if the box Ω is sufficiently large, and it is shown how the bound states of atomic and molecular Hamiltonians can be approximated by those of the system confined for a box Ω large enough (Dirichlet eigenproblem in Ω). Thus, a method for computing bound states is obtained which has the advantage of reducing the problem to the case of compact operators. This implies that a broad class of numerical and analytic techniques used for solving the Dirichlet problem, may be applied in full strength to obtain accurate computations of energy levels, wave functions, and other physical properties of interest
Trapped electronic states in YAG crystal excited by femtosecond radiation
Energy Technology Data Exchange (ETDEWEB)
Zavedeev, E.V.; Kononenko, V.V.; Konov, V.I. [General Physics Institute of RAS, Moscow (Russian Federation); National Research Nuclear University MEPhI (Moscow Engineering Physics Institute), Moscow (Russian Federation)
2017-07-15
The excitation of an electronic subsystem of an yttrium aluminum garnet by 800 nm femtosecond radiation was studied theoretically and experimentally. The spatio-temporal dynamics of the refractive index (n) inside the beam waist was explored by means of the pump-probe interferometric technique with a submicron resolution. The observed increase in n indicated the formation of bound electronic states relaxed for ∝ 150 ps. We showed that the experimental data agreed with the computational simulation based on the numerical solution of the nonlinear Schroedinger equation only if these transient states were considered to arise from a direct light-induced process but not from the decay of radiatively generated free-electron-hole pairs. (orig.)
Excited state dynamics & optical control of molecular motors
Wiley, Ted; Sension, Roseanne
2014-03-01
Chiral overcrowded alkenes are likely candidates for light driven rotary molecular motors. At their core, these molecular motors are based on the chromophore stilbene, undergoing ultrafast cis/trans photoisomerization about their central double bond. Unlike stilbene, the photochemistry of molecular motors proceeds in one direction only. This unidirectional rotation is a result of helicity in the molecule induced by steric hindrance. However, the steric hindrance which ensures unidirectional excited state rotation, has the unfortunate consequence of producing large ground state barriers which dramatically decrease the overall rate of rotation. These molecular scale ultrafast motors have only recently been studied by ultrafast spectroscopy. Our lab has studied the photochemistry and photophysics of a ``first generation'' molecular motor with UV-visible transient absorption spectroscopy. We hope to use optical pulse shaping to enhance the efficiency and turnover rate of these molecular motors.
Excitation gap of fractal quantum hall states in graphene
International Nuclear Information System (INIS)
Luo, Wenchen; Chakraborty, Tapash
2016-01-01
In the presence of a magnetic field and an external periodic potential the Landau level spectrum of a two-dimensional electron gas exhibits a fractal pattern in the energy spectrum which is described as the Hofstadter’s butterfly. In this work, we develop a Hartree–Fock theory to deal with the electron-electron interaction in the Hofstadter’s butterfly state in a finite-size graphene with periodic boundary conditions, where we include both spin and valley degrees of freedom. We then treat the butterfly state as an electron crystal so that we could obtain the order parameters of the crystal in the momentum space and also in an infinite sample. A phase transition between the liquid phase and the fractal crystal phase can be observed. The excitation gaps obtained in the infinite sample is comparable to those in the finite-size study, and agree with a recent experimental observation. (paper)
Electron capture into excited states of multi-charged ions
International Nuclear Information System (INIS)
Dijkkamp, D.
1985-01-01
This thesis deals with charge exchange reactions in slow collisions of multi-charged ions with neutral atoms or molecules. These reactions proceed very efficiently via a curve crossing mechanism, which leads to preferential population of excited states of the ion. The subsequent decay of these states leads to the emission of characteristic radiation. From wavelength resolved measurements of the absolute intensity of this radiation, cross sections for selective population of the excited (n,l-) states of the ion were determined. In addition, for some systems the total capture cross section was measured directly by means of charge state analysis of the secondary projectile ions. The role of charge exchange processes in fusion plasmas and in astrophysical plasmas is indicated. An experimental set-up is described with emphasis on the Electron Cyclotron Resonance Ion Source that was used in the experiments. Results for collisions of C 6+ , N 6+ , O 6+ and Ne 6+ with He, H 2 and Ar are presented as well as for electron capture from Li atoms by C 4+ and He 2+ . The interaction of the iso-electronic sequence C 4+ , N 5+ , O 6+ with atomic hydrogen, molecular hydrogen and helium is studied. First results for partial and total cross sections in collisions of fully stripped carbon, nitrogen and oxygen ions with atomic hydrogen are presented. These data are of particular importance for applications in fusion diagnostics. The data indicate that calculations of both molecular and atomic orbital type yield correct results, if an extended basis set is used. (Auth.)
Benzonitrile: Electron affinity, excited states, and anion solvation
Dixon, Andrew R.; Khuseynov, Dmitry; Sanov, Andrei
2015-10-01
We report a negative-ion photoelectron imaging study of benzonitrile and several of its hydrated, oxygenated, and homo-molecularly solvated cluster anions. The photodetachment from the unsolvated benzonitrile anion to the X ˜ 1 A 1 state of the neutral peaks at 58 ± 5 meV. This value is assigned as the vertical detachment energy (VDE) of the valence anion and the upper bound of adiabatic electron affinity (EA) of benzonitrile. The EA of the lowest excited electronic state of benzonitrile, a ˜ 3 A 1 , is determined as 3.41 ± 0.01 eV, corresponding to a 3.35 eV lower bound for the singlet-triplet splitting. The next excited state, the open-shell singlet A ˜ 1 A 1 , is found about an electron-volt above the triplet, with a VDE of 4.45 ± 0.01 eV. These results are in good agreement with ab initio calculations for neutral benzonitrile and its valence anion but do not preclude the existence of a dipole-bound state of similar energy and geometry. The step-wise and cumulative solvation energies of benzonitrile anions by several types of species were determined, including homo-molecular solvation by benzonitrile, hydration by 1-3 waters, oxygenation by 1-3 oxygen molecules, and mixed solvation by various combinations of O2, H2O, and benzonitrile. The plausible structures of the dimer anion of benzonitrile were examined using density functional theory and compared to the experimental observations. It is predicted that the dimer anion favors a stacked geometry capitalizing on the π-π interactions between the two partially charged benzonitrile moieties.
Ultrafast electronic relaxation of excited state vitamin B12 in the gas phase
International Nuclear Information System (INIS)
Shafizadeh, Niloufar; Poisson, Lionel; Soep, Benoit
2008-01-01
The time evolution of electronically excited vitamin B 12 (cyanocobalamin) has been observed for the first time in the gas phase. It reveals an ultrafast decay to a state corresponding to metal excitation. This decay is interpreted as resulting from a ring to metal electron transfer. This opens the observation of the excited state of other complex biomimetic systems in the gas phase, the key to the characterisation of their complex evolution through excited electronic states
International Nuclear Information System (INIS)
Sotty, C.
2013-01-01
The underlying structure in the region A ∼ 100, N ∼ 60 has been under intensive and extensive investigation, mainly by β-decay and γ-ray spectroscopy from fission processes. Around N ∼ 60, by adding just few neutrons, protons a rapid shape change occurs from spherical-like to well deformed g.s. shape. Shape coexistence has been observed in the Sr and Zr nuclei, and is expected to take place in the whole region. The mechanisms involved in the appearance of the deformation is not well understood. The interplay between down-sloping and up-sloping neutron Nilsson orbital is evoked as one of the main reasons for the sudden shape change. However, a clear identification of the active proton and neutron orbitals was still on-going. For that purpose, the neutron rich 93;95;97;99 Rb isotopes have been studied by Coulomb excitation at CERN (ISOLDE) using the REX-ISOLDE post-accelerator and the MINIBALL setup. The completely unknown structures of 97;99 Rb have been populated and observed. Prompt γ-ray coincidences of low-lying states have been observed and time-correlated in order to build level schemes. The associated transition strengths have been extracted with the GOSIA code. The observed matrix elements of the electromagnetic operator constituted new inputs of further theoretical calculations giving new insight on the involved orbitals. The sensitivity of such experiment can be increased using nuclear spin polarized radioactive ion beam. For that purpose the Tilted Foils Technique (TFT) of polarization has been investigated at CERN. This technique consists to spin polarize the ion beam, passing through thin foils tilted at an oblique angle with respect to the beam direction. The initially obtained atomic polarization is transferred to the nucleus by hyperfine interaction. This technique does not depend on the chemical nature of the element. Short lived nuclei can be polarized in-flight without any need to be stopped in a catcher. It opens up the possibility to
Energy Technology Data Exchange (ETDEWEB)
Salmon, G A [Leeds Univ. (UK). Cookridge High Energy Radiation Research Centre
1976-01-01
This paper reviews the work of the author and his co-workers on the radiation-induced formation of excited states of aromatic compounds in solution. The experimental methods used are surveyed and in particular the method of measuring the yields of triplet and singlet excited states of the solute are described. The problems discussed are: (1) the effect of solvent on the yields of excited states, (2) formation of excited states in cyclohexane and other alicyclic hydrocarbons, (3) the formation of excited states in benzene and (4) the identification of T-T absorption spectra.
Kinetic studies following state-selective laser excitation
International Nuclear Information System (INIS)
Keto, J.W.
1992-01-01
We have made measurements of state-to-state deactivation cross sections and radiative lifetimes for Xe*(6p,6p',7p) and Kr*(5p) states in xenon and krypton buffer gases. These results are relevant to kinetic models and both excimer lasers and the infrared xenon laser; and they are a significant improvement in the precision of the known radiative lifetimes. This type of experiment can now be compared with recent calculations of state-to-state collisional relaxation in rare-gases by Hickman, Huestis, and Saxon. We have also made significant progress in the study of the electronic spectra of small molecules of the rare gases. Spectra have been obtained for Xe 2 , Xe 3 , Xe 4 , and larger clusters. As guidance for the larger clusters of the rare gases we have obtained the first multiphoton spectra for excitons in condensed xenon. In collaboration with research on the multiphoton spectra of the rare gases, we have continued experiments using synchrotron radiation in collaboration with the University of Hamburg. In experiments there we have observed excitation and fluorescence spectra for single xenon atoms at the surface, within the second layer, and within the bulk of large argon clusters
Influences of temperature on asymmetric quantum dot qubit in Coulombic impunity potential
Chen, Y.-J.; Song, H.-T.; Xiao, J.-L.
2018-05-01
Using the variational method of the Pekar-type, we study the influences of the temperature on the asymmetric quantum dot (QD) qubit in the Coulombic impunity potential. Then we derive the numerical results and formulate the derivative relationships of the electron probability density and the electron oscillation period in the superposition state of the ground state and the first-excited state with the electron-phonon coupling constant, the Coulombic impurity potential, the transverse and longitudinal confinement strengths at different temperatures, respectively.
DEFF Research Database (Denmark)
Reynisson, J.; Wilbrandt, R.; Brinck, V.
2002-01-01
. The physical and chemical properties of the excited singlet state of the trioxatriangulenium (TOTA(+)) carbenium ion are investigated by experimental and Computational means. The degeneracy of the lowest excited states is counteracted by Jahn-Teller-type distortion, which leads to vibronic broadening...... of the long wavelength absorption band. A strong fluorescence is observed at 520 nm (tau(n) = 14.6 ns, phi(n) = 0.12 in deaerated acetonitrile). The fluorescence is quenched by 10 aromatic electron donors predominantly via a dynamic charge transfer mechanism, but ground state complexation is shown...... triphenylenes is studied separately. Phosphorescence spectra, triplet lifetimes, and triplet-triplet absorption spectra are provided. In the discussion, TOTA(+) is compared to the unsubstituted xanthenium ion and its 9-phenyl derivative with respect to the excited state properties....
Interference between radiative emission and autoionization in the decay of excited states of atoms
International Nuclear Information System (INIS)
Armstrong, L. Jr.; Theodosiou, C.E.; Wall, M.J.
1978-01-01
An excited state of an atom which can autoionize can also undergo radiative decay. We consider the interaction between the final states resulting from these two modes of decay, and its effects on such quantities as the fluorescence yield of the excited state, excitation profile of the excited state, and the spectra of the emitted photons and electrons. It is shown that the fraction of decays of the excited state resulting in a photon (fluorescence yield) is particularly sensitive to the details of the final-state interaction. In lowest order in the final-state interaction, the fluorescence yield is increased by a factor (1 + 1/q 2 ) from the traditional value, where q is the Fano q parameter relating to the excited state and the final atomic state
Energy Technology Data Exchange (ETDEWEB)
Dobryakov, A. L.; Quick, M.; Ioffe, I. N.; Granovsky, A. A.; Ernsting, N. P.; Kovalenko, S. A. [Department of Chemistry, Humboldt-Universität zu Berlin, Brook-Taylor-Str. 2, D-12489 Berlin (Germany)
2014-05-14
We show that femtosecond stimulated Raman spectroscopy can record excited-state spectra in the absence of actinic excitation, if the Raman pump is in resonance with an electronic transition. The approach is illustrated by recording S{sub 1} and S{sub 0} spectra of trans-azobenzene in n-hexane. The S{sub 1} spectra were also measured conventionally, upon nπ* (S{sub 0} → S{sub 1}) actinic excitation. The results are discussed and compared to earlier reports.
Theoretical description of excited state dynamics in nanostructures
Rubio, Angel
2009-03-01
There has been much progress in the synthesis and characterization of nanostructures however, there remain immense challenges in understanding their properties and interactions with external probes in order to realize their tremendous potential for applications (molecular electronics, nanoscale opto-electronic devices, light harvesting and emitting nanostructures). We will review the recent implementations of TDDFT to study the optical absorption of biological chromophores, one-dimensional polymers and layered materials. In particular we will show the effect of electron-hole attraction in those systems. Applications to the optical properties of solvated nanostructures as well as excited state dynamics in some organic molecules will be used as text cases to illustrate the performance of the approach. Work done in collaboration with A. Castro, M. Marques, X. Andrade, J.L Alonso, Pablo Echenique, L. Wirtz, A. Marini, M. Gruning, C. Rozzi, D. Varsano and E.K.U. Gross.
2He decay from excited states: the 18Ne case
International Nuclear Information System (INIS)
Raciti, G.; Sfienti, C.; De Napoli, M.; Rapisarda, E.; Cardella, G.; Giacoppo, F.
2011-01-01
Two-proton radioactivity studies have been performed on excited states of 18 Ne produced by 20 Ne fragmentation at the FRIBs facility of the Laboratori Nazionali del Sud. The study of the relative-momentum correlations of the two protons allowed to disentangle the diproton, democratic and sequential decay contributions to the 2p emission. In order to extend the study on two-proton decay to other light-masses nuclei, an upgrade of the FRIBs facility is planned. A new configuration of the Fragment Separator would be able to increase the acceptance of the beam line and therefore the yield of the produced radioactive beams. Also the present tagging setup will be modified in view of the gain intensity, in order to sustain the higher foreseen incoming rate. Status and perspectives of the facility will be presented. (author)
Selective excitation of atoms or molecules to high-lying states
International Nuclear Information System (INIS)
Ducas, T.W.
1978-01-01
This specification relates to the selective excitation of atoms or molecules to high lying states and a method of separating different isotopes of the same element by selective excitation of the isotopes. (U.K.)
Transfer matrices and excitations with matrix product states
International Nuclear Information System (INIS)
Zauner, V; Rams, M M; Verstraete, F; Draxler, D; Vanderstraeten, L; Degroote, M; Haegeman, J; Stojevic, V; Schuch, N
2015-01-01
We use the formalism of tensor network states to investigate the relation between static correlation functions in the ground state of local quantum many-body Hamiltonians and the dispersion relations of the corresponding low-energy excitations. In particular, we show that the matrix product state transfer matrix (MPS-TM)—a central object in the computation of static correlation functions—provides important information about the location and magnitude of the minima of the low-energy dispersion relation(s), and we present supporting numerical data for one-dimensional lattice and continuum models as well as two-dimensional lattice models on a cylinder. We elaborate on the peculiar structure of the MPS-TM’s eigenspectrum and give several arguments for the close relation between the structure of the low-energy spectrum of the system and the form of the static correlation functions. Finally, we discuss how the MPS-TM connects to the exact quantum transfer matrix of the model at zero temperature. We present a renormalization group argument for obtaining finite bond dimension approximations of the MPS, which allows one to reinterpret variational MPS techniques (such as the density matrix renormalization group) as an application of Wilson’s numerical renormalization group along the virtual (imaginary time) dimension of the system. (paper)
International Nuclear Information System (INIS)
Borovik, A; Roman, V; Zatsarinny, O; Bartschat, K
2013-01-01
Electron impact excitation of the (4p 5 5s 2 ) 2 P 3/2,1/2 and (4p 5 4d5s) 4 P 1/2,3/2,5/2 autoionizing states in rubidium atoms was studied experimentally by measuring the ejected-electron excitation functions and theoretically by employing a fully relativistic Dirac B-spline R-matrix (close-coupling) model. The experimental data were collected in an impact energy range from the respective excitation thresholds up to 50 eV with an incident electron energy resolution of 0.2 eV and an observation angle of 54.7°. Absolute values of the excitation cross sections were obtained by normalizing to the theoretical predictions. The observed near-threshold resonance structures were also analysed by comparison with theory. For the 2 P 3/2,1/2 doublet states, a detailed analysis of the R-matrix results reveals that the most intense resonances are related to odd-parity negative-ion states with dominant configurations 4p 5 5s5p 2 and 4p 5 4d5s6s. The measured excitation functions for the 2 P 1/2 and 4 P J states indicate a noticeable cascade population due to the radiative decay from high-lying autoionizing states. A comparative analysis with similar data for other alkali atoms is also presented.
Dielectronic recombination rate coefficients to the excited states of CI from CII
International Nuclear Information System (INIS)
Dubau, J.; Kato, T.; Safronova, U.I.
1998-01-01
The dielectronic recombination rate coefficients to the excited states for n=2-6 are calculated including 1s 2 2l 1 2l 2 2l 3 nl (n=2-6, l≤(n-1)) states. The values for the excited states higher than n=6 are extrapolated and the total dielectronic recombination rate coefficients are derived. The rate coefficients to the excited states are fitted to an analytical formula and the fit parameters are given. (author)
Excited state populations and charge-exchange of fast ions in solids
International Nuclear Information System (INIS)
Miller, P.D.; Sofield, C.J.; Woods, C.J.
1984-01-01
Excited state populations and charge state fractions of 445 MeV Cl ions have been measured for a range of thicknesses of solid C targets. Cross sections for electron capture, loss, excitation and excited state quenching have been determined and these data are found to predict a quantitative difference between equilibrium charge state distributions from gases and solids for a special case of the Bohr-Lindhard density effect model. 8 references, 1 figure, 1 table
Dynamics of the excited state intramolecular charge transfer
International Nuclear Information System (INIS)
Joo, T.; Kim, C.H.
2006-01-01
The 6-dodecanoyl-2-dimethylaminonaphtalene (laurdan), a derivative of 6-propanoyl- 2-dimethylaminonaphthalene (prodan), has been used as a fluorescent probe in cell imaging, especially in visualizing the lipid rafts by the generalized polarization (GP) images, where GP=(I 440 -I 490 )/(I 440 +I 490 ) with I being the fluorescence intensity. The fluorescence spectrum of laurdan is sensitive to its dipolar environment due to the intramolecular charge transfer (ICT) process in S 1 state, which results in a dual emission from the locally excited (LE) and the ICT states. The ICT process and the solvation of the ICT state are very sensitive to the dipolar nature of the environment. In this work, the ICT of laurdan in ethanol has been studied by femtosecond time resolved fluorescence (TRF), especially TRF spectra measurement without the conventional spectral reconstruction method. TRF probes the excited states exclusively, a unique advantage over the pump/probe transient absorption technique, although time resolution of the TRF is generally lower than transient absorption and the TRF spectra measurement was possible only though the spectral reconstruction. Over the years, critical advances in TRF technique have been made in our group to achieve <50 fs time resolution with direct full spectra measurement capability. Detailed ICT and the subsequent solvation processes can be visualized unambiguously from the TRF spectra. Fig. 1 shows the TRF spectra of laurdan in ethanol at several time delays. Surprisingly, two bands at 433 and 476 nm are clearly visible in the TRF spectra of laurdan even at T = 0 fs. As time increases, the band at 476 nm shifts to the red while its intensity increases. The band at 433 nm also shifts slightly to the red, but loses intensity as time increases. The intensity of the 476 nm band reaches maximum at around 5 ps, where it is roughly twice as intense as that at 0 fs, and stays constant until lifetime decay is noticeable. The spectra were fit by
Stability of quantum-dot excited-state laser emission under simultaneous ground-state perturbation
Energy Technology Data Exchange (ETDEWEB)
Kaptan, Y., E-mail: yuecel.kaptan@physik.tu-berlin.de; Herzog, B.; Schöps, O.; Kolarczik, M.; Woggon, U.; Owschimikow, N. [Institut für Optik und Atomare Physik, Technische Universität Berlin, Berlin (Germany); Röhm, A.; Lingnau, B.; Lüdge, K. [Institut für Theoretische Physik, Technische Universität Berlin, Berlin (Germany); Schmeckebier, H.; Arsenijević, D.; Bimberg, D. [Institut für Festkörperphysik, Technische Universität Berlin, Berlin (Germany); Mikhelashvili, V.; Eisenstein, G. [Technion Institute of Technology, Faculty of Electrical Engineering, Haifa (Israel)
2014-11-10
The impact of ground state amplification on the laser emission of In(Ga)As quantum dot excited state lasers is studied in time-resolved experiments. We find that a depopulation of the quantum dot ground state is followed by a drop in excited state lasing intensity. The magnitude of the drop is strongly dependent on the wavelength of the depletion pulse and the applied injection current. Numerical simulations based on laser rate equations reproduce the experimental results and explain the wavelength dependence by the different dynamics in lasing and non-lasing sub-ensembles within the inhomogeneously broadened quantum dots. At high injection levels, the observed response even upon perturbation of the lasing sub-ensemble is small and followed by a fast recovery, thus supporting the capacity of fast modulation in dual-state devices.
Toda, S.; Stein, R.S.; Lin, J.
2011-01-01
We report on a broad and unprecedented increase in seismicity rate following the M=9.0 Tohoku mainshock for M ≥ 2 earthquakes over inland Japan, parts of the Japan Sea and Izu islands, at distances of up to 425 km from the locus of high (≥15 m) seismic slip on the megathrust. Such an increase was not seen for the 2004 M=9.1 Sumatra or 2010 M=8.8 Chile earthquakes, but they lacked the seismic networks necessary to detect such small events. Here we explore the possibility that the rate changes are the product of static Coulomb stress transfer to small faults. We use the nodal planes of M ≥ 3.5 earthquakes as proxies for such small active faults, and find that of fifteen regions averaging ~80 by 80 km in size, 11 show a positive association between calculated stress changes and the observed seismicity rate change, 3 show a negative correlation, and for one the changes are too small to assess. This work demonstrates that seismicity can turn on in the nominal stress shadow of a mainshock as long as small geometrically diverse active faults exist there, which is likely quite common.
DEFF Research Database (Denmark)
Zhang, Wenkai; Kjær, Kasper Skov; Alonso-Mori, Roberto
2017-01-01
iron complexes with four cyanide (CN-;) ligands and one 2,2′-bipyridine (bpy) ligand. This enables MLCT excited state and metal-centered excited state energies to be manipulated with partial independence and provides a path to suppressing spin crossover. We have combined X-ray Free-Electron Laser (XFEL...... state lifetime of iron based complexes due to spin crossover-the extremely fast intersystem crossing and internal conversion to high spin metal-centered excited states. We revitalize a 30 year old synthetic strategy for extending the MLCT excited state lifetimes of iron complexes by making mixed ligand...
Coulomb blockade induced by magnetic field
International Nuclear Information System (INIS)
Kusmartsev, F.V.
1992-01-01
In this paper, the authors found that a Coulomb blockade can be induced by magnetic field. The authors illustrated this effect on the example of a ring consisting of two and many Josephson junctions. For the ring with two junctions we present an exact solution. The transition into Coulomb blockade state on a ring transforms into a linear array of Josephson junctions, although in latter case the effect of magnetic field disappears. In the state of Coulomb blockade the magnetization may be both diamagnetic and paramagnetic. The Coulomb blockade may also be removed by external magnetic field
Excited-state dynamics of acetylene excited to individual rotational level of the V04K01 subband
Makarov, Vladimir I.; Kochubei, Sergei A.; Khmelinskii, Igor V.
2006-01-01
Dynamics of the IR emission induced by excitation of the acetylene molecule using the (32Ka0,1,2,ÃAu1←41la1,X˜Σg+1) transition was investigated. The observed IR emission was assigned to transitions between the ground-state vibrational levels. Acetylene fluorescence quenching induced by external electric and magnetic fields acting upon the system prepared using the (34Ka1,ÃAu1←00la0,X˜Σg+1) excitation was also studied. External electric field creates an additional radiationless pathway to the ground-state levels, coupling levels of the ÃAu1 excited state to the quasiresonant levels of the X˜Σg+1 ground state. The level density of the ground state in the vicinity of the excited state is very high, thus the electric-field-induced transition is irreversible, with the rate constant described by the Fermi rule. Magnetic field alters the decay profile without changing the fluorescence quantum yield in collisionless conditions. IR emission from the CCH transient was detected, and was also affected by the external electric and magnetic fields. Acetylene predissociation was demonstrated to proceed by the direct S1→S0 mechanism. The results were explained using the previously developed theoretical approach, yielding values of the relevant model parameters.
Effective temperature in relaxation of Coulomb glasses.
Somoza, A M; Ortuño, M; Caravaca, M; Pollak, M
2008-08-01
We study relaxation in two-dimensional Coulomb glasses up to macroscopic times. We use a kinetic Monte Carlo algorithm especially designed to escape efficiently from deep valleys around metastable states. We find that, during the relaxation process, the site occupancy follows a Fermi-Dirac distribution with an effective temperature much higher than the real temperature T. Long electron-hole excitations are characterized by T(eff), while short ones are thermalized at T. We argue that the density of states at the Fermi level is proportional to T(eff) and is a good thermometer to measure it. T(eff) decreases extremely slowly, roughly as the inverse of the logarithm of time, and it should affect hopping conductance in many experimental circumstances.
Examination of excited state populations in sputtering using Multiphoton Resonance Ionization
International Nuclear Information System (INIS)
Kimock, F.M.; Baxter, J.P.; Pappas, D.L.; Kobrin, P.H.; Winograd, N.
1984-01-01
Multiphoton Resonance Ionization has been employed to study the populations of excited state atoms ejected from ion bombarded metal surfaces. Preliminary investigations have focused on three model systems: aluminum, indium and cobalt. In this paper the authors examine the effect of primary ion energy (2 to 12 keV Ar + ) on excited state yields for these three systems. The influence of the sample matrix on excited state populations of sputtered atoms is also discussed
Examination of excited state populations in sputtering using multiphoton resonance ionization
International Nuclear Information System (INIS)
Kimock, F.M.; Baxter, J.P.; Pappas, D.L.; Kobrin, P.H.; Winograd, N.
1984-01-01
Multiphoton Resonance Ionization has been employed to study the populations of excited state atoms ejected from ion bombarded metal surfaces. Preliminary investigations have focused on three model systems: aluminum, indium and cobalt. In this paper we examine the effect of primary ion energy (2 to 12 keV Ar + ) on excited state yields for these three systems. The influence of the sample matrix on excited state populations of sputtered atoms is also discussed. 8 refs., 4 figs
Studies of photoionization processes from ground-state and excited-state atoms and molecules
International Nuclear Information System (INIS)
Ederer, D.L.; Parr, A.C.; West, J.B.
1982-01-01
Recent triply-differential photoelectron spectroscopy experiments designed for the study of correlation effects in atoms and molecules are described. Final-state symmetry of the n=2 state of helium has been determined. The non-Franck-Condon behavior of vibrational branching ratios and large variations of the angular asymmetry parameter has been observed for shape resonances and autoionizing resonances in CO and other molecules. Recent observations of the photoionization of excited sodium atoms are also described
Technique for description of nonrotational excited states in a semiphenomenological nuclear theory
International Nuclear Information System (INIS)
Krutov, V.A.
1985-01-01
A non-standard technique for microscopic description of excited nonrotational states is considered; it is suitable for inseparable force application. Besides, an additional binding operator, mixing quasi-particle excitations and E1-resonance states, is considered. Instead of the standard technique of state ''collectivization'' of the random phase approximation type it is used the so-called ''method of bound amplitudes''
Hertzian spectroscopy application to excited states in accelerated ion beams
Energy Technology Data Exchange (ETDEWEB)
Gaillard, M L
1974-01-01
Accelerated ion beams enables the application of optical hertzian spectrometry methods to be extended to research on the excited states of free ionic systems. The photon beat method has proved especially simple to apply in beam foil geometry because of the unidirectional beam velocity while the beam gas device is suitable for experiments of the energy level crossing type. Only the resonance technique involving direct application of high-frequency magnetic fields poses serious problems because of the high HF powers necessary. So far structure intervals have been measured in ions carrying up to three charges (seven in the special case of Lamb shift measurements) with a precision of a few percent. Study of hydrogen-like or helium-like ions of high Z allows the fundamental calculations of quantum electrodynamics to be checked with regard to the Lamb shift or the spontaneous emission theory. In more complex electronic systems, optical spectroscopy of accelerated ion beams gives wavelengths with a resolution reaching 10/sup -5/, lifetimes with an accuracy better than 10% when the cascade effects are properly studied, and Lande factors with a precision of several % under present technical conditions. The photon beat method concerns hyperfine nuclear effects in light atoms of Z < = 20. (FR)
The Structure of the Nucleon and its Excited States
International Nuclear Information System (INIS)
None
1995-01-01
The past year has been an exciting and productive one for particle physics research at Abilene Christian University. The thrust of our experimental investigations is the study of the nucleon and its excited states. Laboratories where these investigations are presently being conducted are the AGS at Brookhaven, Fermilab and LAMPF. Some analysis of the data for experiments at the Petersburg Nuclear Physics Institute (Gatchina, Russia) is still in progress. Scheduling of activities at different laboratories inevitably leads to occasional conflicts. This likelihood is increased by the present budget uncertainties at the laboratories that make long-term scheduling difficult. For the most part, the investigators have been able to avoid such conflicts. Only one experiment received beam time in 1994 (E890 at the AGS). The situation for 1995-1996 also appears manageable at this point. E890 and another AGS experiment (E909) will run through May, 1995. El 178 at LAMPF is presently scheduled for August/September 1995. E866 at Fermilab is scheduled to start in Spring/Summer 1996. Undergraduate student involvement has been a key element in this research contract since its inception. Summer students participated at all of the above laboratories in 1994 and the same is planned in 1995. A transition to greater involvement by graduate students will provide cohesiveness to ACU involvement at a given laboratory and full-time on-site involvement in the longer running experiments at FNAL and BNL. Funds to support a full-time graduate student are requested this year. Finally, collaboration by Russian, Croatian and Bosnian scientists has proven to be mutually beneficial to these experimental programs and to the overall programs at the institutions involved. Past support has been augmented by other grants from government agencies and from the Research Council at Abilene Christian University. Additional funds are requested in this renewal to enable more programmatic support for these
Self-excited vibration control for axially fast excited beam by a time delay state feedback
International Nuclear Information System (INIS)
Hamdi, Mustapha; Belhaq, Mohamed
2009-01-01
This work examines the control of self-excited vibration of a simply-supported beam subjected to an axially high-frequency excitation. The investigation of the resonant cases are not considered in this paper. The control is implemented via a corrective position feedback with time delay. The objective of this control is to eliminate the undesirable self-excited vibrations with an appropriate choice of parameters. The issue of stability is also addressed in this paper. Using the technique of direct partition of motion, the dynamic of discretized equations is separated into slow and fast components. The multiple scales method is then performed on the slow dynamic to obtain a slow flow for the amplitude and phase. Analysis of this slow flow provides analytical approximations locating regions in parameters space where undesirable self-excited vibration can be eliminated. A numerical study of these regions is performed on the original discretized system and compared to the analytical prediction showing a good agreement.
Filatov, Mikhail A.
2015-10-13
The synthesis and photophysical characterization of a palladium(II) porphyrin – anthracene dyad bridged via short and conformationally rigid bicyclo[2.2.2]octadiene spacer were achieved. A spectroscopic investigation of the prepared molecule in solution has been undertaken to study electronic energy transfer in excited singlet and triplet states between the anthracene and porphyrin units. By using steady-state and time-resolved photoluminescence spectroscopy it was shown that excitation of the singlet excited state of the anthracene leads to energy transfer to the lower-lying singlet state of porphyrin. Alternatively, excitation of the porphyrin followed by intersystem crossing to the triplet state leads to very fast energy transfer to the triplet state of anthracene. The rate of this energy transfer has been determined by transient absorption spectroscopy. Comparative studies of the dynamics of triplet excited states of the dyad and reference palladium octaethylporphyrin (PdOEP) have been performed.
Filatov, Mikhail A.; Etzold, Fabian; Gehrig, Dominik; Laquai, Fré dé ric; Busko, Dmitri; Landfester, Katharina; Baluschev, Stanislav
2015-01-01
The synthesis and photophysical characterization of a palladium(II) porphyrin – anthracene dyad bridged via short and conformationally rigid bicyclo[2.2.2]octadiene spacer were achieved. A spectroscopic investigation of the prepared molecule in solution has been undertaken to study electronic energy transfer in excited singlet and triplet states between the anthracene and porphyrin units. By using steady-state and time-resolved photoluminescence spectroscopy it was shown that excitation of the singlet excited state of the anthracene leads to energy transfer to the lower-lying singlet state of porphyrin. Alternatively, excitation of the porphyrin followed by intersystem crossing to the triplet state leads to very fast energy transfer to the triplet state of anthracene. The rate of this energy transfer has been determined by transient absorption spectroscopy. Comparative studies of the dynamics of triplet excited states of the dyad and reference palladium octaethylporphyrin (PdOEP) have been performed.
In-gap corner states in core-shell polygonal quantum rings.
Sitek, Anna; Ţolea, Mugurel; Niţă, Marian; Serra, Llorenç; Gudmundsson, Vidar; Manolescu, Andrei
2017-01-10
We study Coulomb interacting electrons confined in polygonal quantum rings. We focus on the interplay of localization at the polygon corners and Coulomb repulsion. Remarkably, the Coulomb repulsion allows the formation of in-gap states, i.e., corner-localized states of electron pairs or clusters shifted to energies that were forbidden for non-interacting electrons, but below the energies of corner-side-localized states. We specify conditions allowing optical excitation to those states.
In-gap corner states in core-shell polygonal quantum rings
Sitek, Anna; Ţolea, Mugurel; Niţă, Marian; Serra, Llorenç; Gudmundsson, Vidar; Manolescu, Andrei
2017-01-01
We study Coulomb interacting electrons confined in polygonal quantum rings. We focus on the interplay of localization at the polygon corners and Coulomb repulsion. Remarkably, the Coulomb repulsion allows the formation of in-gap states, i.e., corner-localized states of electron pairs or clusters shifted to energies that were forbidden for non-interacting electrons, but below the energies of corner-side-localized states. We specify conditions allowing optical excitation to those states.
Excited state intramolecular charge transfer reaction in 4-(1 ...
Indian Academy of Sciences (India)
Administrator
cal reactions to the determination of paleotempera- tures from isotopic ... ordered liquid than H2O due to stronger H-bond in- teractions in the deuterated water ... layer chromatography and monitoring the excitation wavelength dependence of ...
de Angelis, G.; Wiedemann, K. T.; Martinez, T.; Orlandi, R.; Petrovici, A.; Sahin, E.; Valiente-Dobón, J. J.; Tonev, D.; Lunardi, S.; Nara Singh, B. S.; Wadsworth, R.; Gadea, A.; Kaneko, K.; Bizzeti, P. G.; Bizzeti-Sona, A. M.; Blank, B.; Bracco, A.; Carpenter, M. P.; Chiara, C. J.; Farnea, E.; Gottardo, A.; Greene, J. P.; Lenzi, S. M.; Leoni, S.; Lister, C. J.; Mengoni, D.; Napoli, D. R.; Pechenaya, O. L.; Recchia, F.; Reviol, W.; Sarantites, D. G.; Seweryniak, D.; Ur, C. A.; Zhu, S.
2012-03-01
Excited states of the N=Z=33 nucleus 66As have been populated in a fusion-evaporation reaction and studied using γ-ray spectroscopic techniques. Special emphasis was put into the search for candidates for the T=1 states. A new 3+ isomer has been observed with a lifetime of 1.1(3) ns. This is believed to be the predicted oblate shape isomer. The excited levels are discussed in terms of the shell model and of the complex excited Vampir approaches. Coulomb energy differences are determined from the comparison of the T=1 states with their analog partners. The unusual behavior of the Coulomb energy differences in the A=70 mass region is explained through different shape components (oblate and prolate) within the members of the same isospin multiplets. This breaking of the isospin symmetry is attributed to the correlations induced by the Coulomb interaction.
Wigner function and tomogram of the excited squeezed vacuum state
International Nuclear Information System (INIS)
Meng Xiangguo; Wang Jisuo; Fan Hongyi
2007-01-01
The excited squeezed light (ESL) can be the outcome of interaction between squeezed light probe and excited atom, which can explore the status and the structure of the atom. We calculate the Wigner function and tomogram of ESL that may be comparable to the experimental measurement of quadrature-amplitude distribution for the light field obtained using balanced homodyne detection. The method of calculation seems new
Wigner function and tomogram of the excited squeezed vacuum state
Energy Technology Data Exchange (ETDEWEB)
Meng Xiangguo [Department of Physics, Liaocheng University, Shandong Province 252059 (China); Wang Jisuo [Department of Physics, Liaocheng University, Shandong Province 252059 (China)]. E-mail: jswang@lcu.edu.cn; Fan Hongyi [Department of Physics, Liaocheng University, Shandong Province 252059 (China); CCAST (World Laboratory), P.O. Box 8730, 100080 Beijing (China)
2007-01-29
The excited squeezed light (ESL) can be the outcome of interaction between squeezed light probe and excited atom, which can explore the status and the structure of the atom. We calculate the Wigner function and tomogram of ESL that may be comparable to the experimental measurement of quadrature-amplitude distribution for the light field obtained using balanced homodyne detection. The method of calculation seems new.
Energy Technology Data Exchange (ETDEWEB)
Godunov, A.L. [Department of Physics, Tulane University, New Orleans, LA 70118-5698 (United States); Ivanov, P.B.; Schipakov, V.A. [Troitsk Institute of Innovation and Fusion Research Troitsk, Moscow region, 142092 (Russian Federation); Moretto-Capelle, P.; Bordenave-Montesquieu, D.; Bordenave-Montesquieu, A. [Laboratoire Collisions, Agregats, Reactivite, IRSAMC, UMR 5589, CNRS-Universite Paul Sabatier, 31062 Toulouse Cedex (France)
2000-03-14
Mechanisms of two-electron excitation of the (2s{sup 2}){sup 1} S, (2p{sup 2} ){sup 1} D and (2s2p){sup 1} P autoionizing states of helium are studied both experimentally and theoretically. It is shown that an explicit introduction of a kinematic factor, with a process-specific phase leads to a productive parametrization of experimental cross sections of ionization, allowing one to extract cross sections of excitation of autoionizing states. Using a new fitting procedure together with the proposed parametrization made it possible to obtain the excitation cross sections and magnetic sublevel population from electron spectra as well as, for the first time, to resolve the contribution of resonance and interference components to resonance profiles. Interference with direct ionization is shown to contribute significantly into resonance formation even for backward ejection angles. We demonstrate theoretically that the excitation cross sections thus extracted from experimental electron spectra hold information about the interaction of autoionizing states with an adjacent continuum. (author)
Excited-State Dynamics of Carotenoids Studied by Femtosecond Transient Absorption Spectroscopy
International Nuclear Information System (INIS)
Lee, Ingu; Pang, Yoonsoo; Lee, Sebok
2014-01-01
Carotenoids, natural antenna pigments in photosynthesis share a symmetric backbone of conjugated polyenes. Contrary to the symmetric and almost planar geometries of carotenoids, excited state structure and dynamics of carotenoids are exceedingly complex. In this paper, recent infrared and visible transient absorption measurements and excitation dependent dynamics of 8'-apo-β-caroten-8'-al and 7',7'-dicyano-7'-apo-β-carotene will be reviewed. The recent visible transient absorption measurements of 8'-apo-β-caroten-8'-al in polar and nonpolar solvents will also be introduced to emphasize the complex excited-state dynamics and unsolved problems in the S 2 and S 1 excited states
Cho, Dae Won; Kim, Yong Hee; Yoon, Minjoong; Jeoung, Sae Chae; Kim, Dongho
1994-08-01
The picosecond time-resolved fluorescence and transient absorption behavior of piroxicam at room temperature are reported. The keto tautomer in the excited singlet state ( 1K*) formed via the fast intramolecular proton transfer (≈ 20 ps) is observed. The short-lived (7.5 ns) triplet state of keto tauomer ( 3K*) is generated from 1K * in toluene whereas it is hardly observed in ethanol. Consequently, rapid reverse proton transfer takes place from 3K * to the enol triplet state ( 3E *.
Magnetic Coulomb phase in the spin ice Ho2Ti2O7.
Fennell, T; Deen, P P; Wildes, A R; Schmalzl, K; Prabhakaran, D; Boothroyd, A T; Aldus, R J; McMorrow, D F; Bramwell, S T
2009-10-16
Spin-ice materials are magnetic substances in which the spin directions map onto hydrogen positions in water ice. Their low-temperature magnetic state has been predicted to be a phase that obeys a Gauss' law and supports magnetic monopole excitations: in short, a Coulomb phase. We used polarized neutron scattering to show that the spin-ice material Ho2Ti2O7 exhibits an almost perfect Coulomb phase. Our result proves the existence of such phases in magnetic materials and strongly supports the magnetic monopole theory of spin ice.
Excited state mass spectra of doubly heavy baryons Ω{sub cc}, Ω{sub bb} and Ω{sub bc}
Energy Technology Data Exchange (ETDEWEB)
Shah, Zalak; Rai, Ajay Kumar [Sardar Vallabhbhai National Institute of Technology, Department of Applied Physics, Surat, Gujarat (India); Thakkar, Kaushal [GIDC Degree Engineering college, Department of Applied Sciences and Humanities, Abrama, Navsari (India)
2016-10-15
We discuss the mass spectrum of Ω baryon with two heavy quarks and one light quark (ccs, bbs, and bcs). The main goal of the paper is to calculate the ground state masses and after that, the positive and negative parity excited states masses are also obtained within a hypercentral constituent quark model, using Coulomb plus linear potential framework. We also added a first order correction to the potential. The mass spectra up to 5S for radial excited states and 1P-5P, 1D-4D, and 1F-2F states for orbital excited states are computed for Ω{sub cc}, Ω{sub bb} and Ω{sub bc} baryons. Our obtained results are compared with other theoretical predictions, which could be a useful complementary tool for the interpretation of experimentally unknown heavy baryon spectra. The Regge trajectory is constructed in both the (n{sub r}, M{sup 2}) and the (J, M{sup 2}) planes for Ω{sub cc}, Ω{sub bb} and Ω{sub bc} baryons and their slopes and intercepts are also determined. Magnetic moments of doubly heavy Ω{sup '}s are also calculated. (orig.) 8.
Coulomb singularity effects in tunnelling spectroscopy of individual impurities
Arseyev, P. I.; Maslova, N. S.; Panov, V. I.; Savinov, S. V.
2002-01-01
Non-equilibrium Coulomb effects in resonant tunnelling processes through deep impurity states are analyzed. It is shown that Coulomb vertex corrections to the tunnelling transfer amplitude lead to a power-law singularity in current- voltage characteristics
Cathodoluminescence imaging and spectroscopy of excited states in InAs self-assembled quantum dots
International Nuclear Information System (INIS)
Khatsevich, S.; Rich, D.H.; Kim, Eui-Tae; Madhukar, A.
2005-01-01
We have examined state filling and thermal activation of carriers in buried InAs self-assembled quantum dots (SAQDs) with excitation-dependent cathodoluminescence (CL) imaging and spectroscopy. The InAs SAQDs were formed during molecular-beam epitaxial growth of InAs on undoped planar GaAs (001). The intensities of the ground- and excited-state transitions were analyzed as a function of temperature and excitation density to study the thermal activation and reemission of carriers. The thermal activation energies associated with the thermal quenching of the luminescence were measured for ground- and excited-state transitions of the SAQDs, as a function of excitation density. By comparing these activation energies with the ground- and excited-state transition energies, we have considered various processes that describe the reemission of carriers. Thermal quenching of the intensity of the QD ground- and first excited-state transitions at low excitations in the ∼230-300-K temperature range is attributed to dissociation of excitons from the QD states into the InAs wetting layer. At high excitations, much lower activation energies of the ground and excited states are obtained, suggesting that thermal reemission of single holes from QD states into the GaAs matrix is responsible for the observed temperature dependence of the QD luminescence in the ∼230-300-K temperature range. The dependence of the CL intensity of the ground-and first excited-state transition on excitation density was shown to be linear at all temperatures at low-excitation density. This result can be understood by considering that carriers escape and are recaptured as excitons or correlated electron-hole pairs. At sufficiently high excitations, state-filling and spatial smearing effects are observed together with a sublinear dependence of the CL intensity on excitation. Successive filling of the ground and excited states in adjacent groups of QDs that possess different size distributions is assumed to
Local density approximation for exchange in excited-state density functional theory
Harbola, Manoj K.; Samal, Prasanjit
2004-01-01
Local density approximation for the exchange energy is made for treatment of excited-states in density-functional theory. It is shown that taking care of the state-dependence of the LDA exchange energy functional leads to accurate excitation energies.
Excited-state dynamics of pentacene derivatives with stable radical substituents.
Ito, Akitaka; Shimizu, Akihiro; Kishida, Noriaki; Kawanaka, Yusuke; Kosumi, Daisuke; Hashimoto, Hideki; Teki, Yoshio
2014-06-23
The excited-state dynamics of pentacene derivatives with stable radical substituents were evaluated in detail through transient absorption measurements. The derivatives showed ultrafast formation of triplet excited state(s) in the pentacene moiety from a photoexcited singlet state through the contributions of enhanced intersystem crossing and singlet fission. Detailed kinetic analyses for the transient absorption data were conducted to quantify the excited-state characteristics of the derivatives. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
International Nuclear Information System (INIS)
Tolstikhin, Oleg I.; Namba, Chusei
2003-08-01
A program to solve the quantum-mechanical collinear three-body Coulomb problem is described and illustrated by calculations for a number of representative systems and processes. In the internal region, the Schroedinger equation is solved in hyperspherical coordinates using the slow/smooth variable discretization method. In asymptotic regions, the solution is obtained in Jacobi coordinates using the asymptotic package GAILIT from the CPC library. Only bound states and scattering processes below the three-body disintegration threshold are considered here; resonances and fragmentation processes will be discussed in subsequent parts of this series. (author)
The role of the excited electronic states in the C++H2O reaction
International Nuclear Information System (INIS)
Flores, Jesus R.; Gonzalez, Adan B.
2008-01-01
The electronic excited states of the [COH 2 ] + system have been studied in order to establish their role in the dynamics of the C + +H 2 O→[COH] + +H reaction, which is a prototypical ion-molecule reaction. The most relevant minima and saddle points of the lowest excited state have been determined and energy profiles for the lowest excited doublet and quartet electronic states have been computed along the fragmentation and isomerization coordinates. Also, nonadiabatic coupling strengths between the ground and the first excited state have been computed where they can be large. Our analysis suggests that the first excited state could play an important role in the generation of the formyl isomer, which has been detected in crossed beam experiments [D. M. Sonnenfroh et al., J. Chem. Phys. 83, 3985 (1985)], but could not be explained in quasiclassical trajectory computations [Y. Ishikawa et al., Chem. Phys. Lett. 370, 490 (2003); J. R. Flores, J. Chem. Phys. 125, 164309 (2006)
Bound state and localization of excitation in many-body open systems
Cui, H. T.; Shen, H. Z.; Hou, S. C.; Yi, X. X.
2018-04-01
We study the exact bound state and time evolution for single excitations in one-dimensional X X Z spin chains within a non-Markovian reservoir. For the bound state, a common feature is the localization of single excitations, which means the spontaneous emission of excitations into the reservoir is prohibited. Exceptionally, the pseudo-bound state can be found, for which the single excitation has a finite probability of emission into the reservoir. In addition, a critical energy scale for bound states is also identified, below which only one bound state exists, and it is also the pseudo-bound state. The effect of quasirandom disorder in the spin chain is also discussed; such disorder induces the single excitation to locate at some spin sites. Furthermore, to display the effect of bound state and disorder on the preservation of quantum information, the time evolution of single excitations in spin chains is studied exactly. An interesting observation is that the excitation can stay at its initial location with high probability only when the bound state and disorder coexist. In contrast, when either one of them is absent, the information of the initial state can be erased completely or becomes mixed. This finding shows that the combination of bound state and disorder can provide an ideal mechanism for quantum memory.
Cluster decay of Ba isotopes from ground state and as an excited ...
Indian Academy of Sciences (India)
otherwise, inclusion of excitation energy decreases the T1/2 values. ... penetrates the nuclear barrier and reaches scission configuration after running .... between the ground-state energy levels of the parent nuclei and the ground-state energy.
Search for the two-photon decay of the 2+ first excited states in 18O and 28Si
International Nuclear Information System (INIS)
Music, M.
1986-01-01
The present work describes an attempt to measure the probability for the two-photon transition between two adjacent nuclear states in the presence of an allowed, strongly predominant one-photon decay, using the Heidelberg-Darmstadt Crystal Ball Spectrometer. The branching ratios of the two-photon decay of the first excited, 2 + levels of 18 O and 28 Si relative to the one-photon, E2 transitions to the 0 + ground states were determined to be: Wγγ/Wγ = (0.7±2.4) x 10 -6 for the 2 + >0 + transition in 18 O and Wγγ/Wγ = (1.6±1.8) x 10 -6 for the 2 + >0 + transition in 28 Si. Since both results are consistent with zero, it is possible to express them as the upper limits for the two-photon decay (3 δ) of 7.9 x 10 -6 of 18 O and 6.9 x 10 -6 of 28 Si 2 + levels. These values are by far the smallest ones reported to be observed in a two-photon decay of a nuclear state. For 18 O, the result disproves theoretical estimates of the corresponding two-photon E1F1 matrix element was well as experimental values deduced from multiple-Coulomb-excitation measurements. The main experimental difficulties were caused by the gamma rays from one-photon transitions and were found to be connected with cross-talk events due to Bremsstrahlung of Compton electrons and not - as generally believed - positron annihilation in flight. (orig.)
Inner shell coulomb ionization by heavy charged particles studied by the SCA model
International Nuclear Information System (INIS)
Hansteen, J.M.
1976-06-01
An outline is given of the development of and some achievements hitherto gained from the semi-classical approximation (SCA) model of atomic Coulomb excitation by heavy charged particles. A few very recent results (1975-1976) are incorporated in the discussion. The SCA model has by now reached a mature state. Hence it seems reasonable to regard the atomic Coulomb excitation phenomenon as part of the extremely complicated excitation mechanism operative in the general ion-atom collision. A clear understanding of the complicated X-ray producing mechanisms in heavy-ion-atom collisions is lacking at present. Despite these facts, the conceptually simple SCA model has furthered our understanding far beyond initial expectations. Moreover, this model has at the same time provided a well-founded starting point for continued researches in this rapidly expanding field of physics. (JIW)
International Nuclear Information System (INIS)
Ho, Yew Kam; Lin, Chien-Hao
2015-01-01
In this work, we study the quantum entanglement for doubly excited resonance states in two-electron atomic systems such as the H - and Ps - ions and the He atom by using highly correlated Hylleraas type functions The resonance states are determined by calculation of density of resonance states with the stabilization method. The spatial (electron-electron orbital) entanglement entropies (linear and von Neumann) for the low-lying doubly excited states are quantified using the Schmidt-Slater decomposition method. (paper)
Optimized RVB states of the 2-d antiferromagnet: ground state and excitation spectrum
Chen, Yong-Cong; Xiu, Kai
1993-10-01
The Gutzwiller projection of the Schwinger-boson mean-field solution of the 2-d spin- {1}/{2} antiferromagnet in a square lattice is shown to produce the optimized, parameter-free RVB ground state. We get -0.6688 J/site and 0.311 for the energy and the staggered magnetization. The spectrum of the excited states is found to be linear and gapless near k≅0. Our calculation suggests, upon breaking of the rotational symmetry, ɛ k≅2JZ r1-γ 2k with Zr≅1.23.
Oh, Juwon; Sung, Young Mo; Hong, Yongseok; Kim, Dongho
2018-03-06
Aromaticity, the special energetic stability derived from cyclic [4 n + 2]π-conjugated electronic structures, has been the topic of intense interest in chemistry because it plays a critical role in rationalizing molecular stability, reactivity, and physical/chemical properties. Recently, the pioneering work by Colin Baird on aromaticity reversal, postulating that aromatic (antiaromatic) character in the ground state reverses to antiaromatic (aromatic) character in the lowest excited triplet state, has attracted much scientific attention. The completely reversed aromaticity in the excited state provides direct insight into understanding the photophysical/chemical properties of photoactive materials. In turn, the application of aromatic molecules to photoactive materials has led to numerous studies revealing this aromaticity reversal. However, most studies of excited-state aromaticity have been based on the theoretical point of view. The experimental evaluation of aromaticity in the excited state is still challenging and strenuous because the assessment of (anti)aromaticity with conventional magnetic, energetic, and geometric indices is difficult in the excited state, which practically restricts the extension and application of the concept of excited-state aromaticity. Time-resolved optical spectroscopies can provide a new and alternative avenue to evaluate excited-state aromaticity experimentally while observing changes in the molecular features in the excited states. Time-resolved optical spectroscopies take advantage of ultrafast laser pulses to achieve high time resolution, making them suitable for monitoring ultrafast changes in the excited states of molecular systems. This can provide valuable information for understanding the aromaticity reversal. This Account presents recent breakthroughs in the experimental assessment of excited-state aromaticity and the verification of aromaticity reversal with time-resolved optical spectroscopic measurements. To
Energy Technology Data Exchange (ETDEWEB)
Warming, Till
2009-02-20
The application of quantum-mechanical effects in semiconductor nanostructures enables the realization of novel opto-electronic devices. Examples are given by single-photon emitters and emitters of entangled photon pairs, both being essential for quantum cryptography, or for qubit systems as needed for quantum computing. InAs/GaAs quantum dots are one of the most promising candidates for such applications. A detailed knowledge of the electronic properties of quantum dots is a prerequisite for this development. The aim of this work is an experimental access to the detailed electronic structure of the excited states in single InAs/GaAs quantum dots including few-particle effects and in particular exchange interaction. The experimental approach is micro photoluminescence excitation spectroscopy ({mu}PLE). One of the main difficulties using {mu}PLE to probe single QDs is the unambiguous assignment of the observed resonances in the spectrum to specific transitions. By comparing micro photoluminescence ({mu}PL) and {mu}PLE spectra, the identification of the main resonances becomes possible. The key is given by the fine structure of the hot trion. Excitation spectroscopy on single charged QDs enables for the first time the complete observation of a non-trivial fine structure of an excitonic complex in a QD, the hot trion. Modelling based on eight-band k.p theory in combination with a configuration interaction scheme is in excellent agreement. Therewith the simulation also enables realistic predictions on the fine structure of the ground-state exciton which is of large importance for single quantum dot devices. Theory concludes from the observed transitions that the structural symmetry of the QDs is broken. Micro photoluminescence excitation spectroscopy combined with resonantly excited micro photoluminescence enables an optical access to the single particle states of the hole without the influence of few-particle coulomb interactions. Based on this knowledge the exciton
International Nuclear Information System (INIS)
Kimura, M.; Rice Univ., Houston, TX
1990-01-01
The two-electron capture or excitation process resulting from collisions of H + and O 6+ ions with He atoms in the energy range from 0.5 keV/amu to 5 keV/amu is studied within a molecular representation. The collision dynamics for formation of doubly excited O 4+ ions and He** atoms and their (n ell, n'ell ') populations are analyzed in conjunction with electron correlations. Autoionizing states thus formed decay through the Auger process. An experimental study of an ejected electron energy spectrum shows ample structures in addition to two characteristic peaks that are identified by atomic and molecular autoionizations. These structures are attributable to various interferences among electronic states and trajectories. We examine the dominant sources of the interferences. 12 refs., 5 figs
Doubly excited states of the LiI isoelectronic sequence
International Nuclear Information System (INIS)
To, K.X.; Knystautas, E.; Drouin, R.; Berry, H.G.
1978-01-01
The term level diagrams of the doubly excited quartet systems of the LiI isoelectronic sequence up to Ne VIII are presented. The identifications are based on recent theoretical and experimental work which suggest a revision particularly of the 2s3p/sup 4po/ terms. 11 references
On the nature of highly vibrationally excited states of thiophosgene
Indian Academy of Sciences (India)
Understanding the nature of the highly excited molecu- lar eigenstates is equivalent to deciphering the mecha- nism of intramolecular vibrational energy redistribution. (IVR) occurring in the molecule.1 However, the assign- ment of eigenstates is far from simple. The existence of and interplay of several strong anharmonic ...
Self-Consistent Optimization of Excited States within Density-Functional Tight-Binding.
Kowalczyk, Tim; Le, Khoa; Irle, Stephan
2016-01-12
We present an implementation of energies and gradients for the ΔDFTB method, an analogue of Δ-self-consistent-field density functional theory (ΔSCF) within density-functional tight-binding, for the lowest singlet excited state of closed-shell molecules. Benchmarks of ΔDFTB excitation energies, optimized geometries, Stokes shifts, and vibrational frequencies reveal that ΔDFTB provides a qualitatively correct description of changes in molecular geometries and vibrational frequencies due to excited-state relaxation. The accuracy of ΔDFTB Stokes shifts is comparable to that of ΔSCF-DFT, and ΔDFTB performs similarly to ΔSCF with the PBE functional for vertical excitation energies of larger chromophores where the need for efficient excited-state methods is most urgent. We provide some justification for the use of an excited-state reference density in the DFTB expansion of the electronic energy and demonstrate that ΔDFTB preserves many of the properties of its parent ΔSCF approach. This implementation fills an important gap in the extended framework of DFTB, where access to excited states has been limited to the time-dependent linear-response approach, and affords access to rapid exploration of a valuable class of excited-state potential energy surfaces.
Dielectronic recombination rate coefficients to the excited states of CI from CII
Energy Technology Data Exchange (ETDEWEB)
Dubau, J. [Observatoire of Paris, 92 MEUDON (France); Kato, T.; Safronova, U.I.
1998-01-01
The dielectronic recombination rate coefficients to the excited states for n=2-6 are calculated including 1s{sup 2}2l{sub 1}2l{sub 2}2l{sub 3}nl (n=2-6, l{<=}(n-1)) states. The values for the excited states higher than n=6 are extrapolated and the total dielectronic recombination rate coefficients are derived. The rate coefficients to the excited states are fitted to an analytical formula and the fit parameters are given. (author)
σ-SCF: A direct energy-targeting method to mean-field excited states.
Ye, Hong-Zhou; Welborn, Matthew; Ricke, Nathan D; Van Voorhis, Troy
2017-12-07
The mean-field solutions of electronic excited states are much less accessible than ground state (e.g., Hartree-Fock) solutions. Energy-based optimization methods for excited states, like Δ-SCF (self-consistent field), tend to fall into the lowest solution consistent with a given symmetry-a problem known as "variational collapse." In this work, we combine the ideas of direct energy-targeting and variance-based optimization in order to describe excited states at the mean-field level. The resulting method, σ-SCF, has several advantages. First, it allows one to target any desired excited state by specifying a single parameter: a guess of the energy of that state. It can therefore, in principle, find all excited states. Second, it avoids variational collapse by using a variance-based, unconstrained local minimization. As a consequence, all states-ground or excited-are treated on an equal footing. Third, it provides an alternate approach to locate Δ-SCF solutions that are otherwise hardly accessible by the usual non-aufbau configuration initial guess. We present results for this new method for small atoms (He, Be) and molecules (H 2 , HF). We find that σ-SCF is very effective at locating excited states, including individual, high energy excitations within a dense manifold of excited states. Like all single determinant methods, σ-SCF shows prominent spin-symmetry breaking for open shell states and our results suggest that this method could be further improved with spin projection.
International Nuclear Information System (INIS)
Hiskes, J.R.
1991-01-01
The excitation cross sections, σ(v,v double-prime), for an H 2 molecule initially in any one of the 15 vibrational levels, v belonging to the ground electronic state and excited to a final vibrational level, v double-prime are evaluated for direct excitations via all members of the excited electronic singlet spectrum. Account is taken of predissociation, autoionization, and radiative decay of the excited electronic spectrum that leads to a final population distribution for the ground electronic state, X 1 Σ + g (v double-prime). For v=0, account is taken explicitly of transitions via the B, C, B', and D electronic states in evaluating the cross sections. The additional contribution of excitations via all Rydberg states lying above the D state enhances these cross sections by approximately 10%. For v>0, cross sections are evaluated taking explicit account of transitions through the B and C states; higher singlet excitations enhance these values by 25%. The choice of the reference total cross sections remains a subjective one, causing the values calculated here to have a possible uncertainty of +20% -30% . For excitations occurring within a hydrogen discharge, collisional excitation-ionization events among the intermediate singlet states will effectively quench the v, v double-prime excitation process for discharge densities in excess of the range 10 15 --10 16 electrons/cm -3
Selfconsistent theory of Coulomb mixing in nuclei
International Nuclear Information System (INIS)
Pyatov, N.I.
1978-01-01
The theory of isobaric states is considered according to the Coulomb mixing in nuclei. For a given form of the isovestor potential the separable residual interactions are constructed by means of the isotopic invariance principle. The strength parameter of the force is found from a selfconsistency condition. The charge dependent force is represented by the Coulomb effective potential. The theory of the isobaric states is developed using the random phase approximation. The Coulomb mixing effects in the ground and isobaric 0 + states of even-mass nuclei are investigated
"Inverted" Solvent Effect on Charge Transfer in the Excited State.
Nau; Pischel
1999-10-04
Faster in cyclohexane than in acetonitrile is the fluorescence quenching of the azoalkane 2,3-diazabicyclo[2.2.2]oct-2-ene (DBO) by amines and sulfides. Although this photoreaction is induced by charge transfer (CT; see picture) and exciplexes are formed, the increase in the dipole moment of the exciplex is not large enough to offset the solvent stabilization of the excited reactants, and an "inverted" solvent effect results.
Sensitivity of (α,α') cross sections to excited-state quadrupole moments
International Nuclear Information System (INIS)
Baker, F.T.; Scott, A.; Ronningen, R.M.; Hamilton, J.H.; Kruse, T.H.; Suchannek, R.; Savin, W.
1977-01-01
Inelastic α particle scattering at 21 and 24 MeV has been used to estimate the electric quadrupole moment of the second 2 + state in 180 Hf. Sensitivity to the assumed quadrupole moment is due almost entirely to reorientation via the nuclear force. Results suggest that the technique may be a useful method of estimating excited state quadrupole moments, particularly for states with high excitation energies or with J greater than 2
Excited-state formation as H+ and He+ ions scatter from metal surfaces
International Nuclear Information System (INIS)
Baird, W.E.; Zivitz, M.; Thomas, E.W.
1975-01-01
Impact of 10-to30KeV H + or He + ions on polycrystalline metal surfaces causes some projectiles to be backscattered in a neutral excited state. These projectiles subsequently radiatively decay, emitting Doppler-broadened spectral lines. By analysis of the spectral shape of these lines, we are able to determine the probability of radiationless deexcitation of the excited backscattered atoms. Quantitative measurements of spectral intensity indicate that less than 1% of all projectiles are backscattered in an excited state. The relative variation of total spectral line intensity with angle of projectile incidence and with projectile primary energy has been successfully predicted using a model which assumes that the probability for excited-state formation is independent of the scattered projectile's energy and direction. The variation in total spectral line intensity with target atomic number is predicted, and the sputtering and excitation of Al under He + impact is briefly examined
Production of autoionizing di-excited states of barium with high angular momentum
International Nuclear Information System (INIS)
Roussel, F.; Breger, P.; Gounand, F.; Spiess, G.
1988-01-01
Autoionizing di-excited states Ba(6p 1/2 27l) with 7 ≤l≤26, have been experimentally detected. They have been produced by a method combining excitation by two lasers and l-mixing collisions between barium and xenon. Results show that a long delay between the two laser excitation steps is favourable to the production of these states. The method has proved to be very efficient (measured cross-section: σ = 3.1 . 10 -13 cm 2 ) for populating high-angular-momentum autoionizing states of barium
Ioniclike energy structure of neutral core-excited states in free Kr clusters
International Nuclear Information System (INIS)
Peredkov, S.; Sorensen, S.L.; Kivimaeki, A.; Schulz, J.; Maartensson, N.; Oehrwall, G.; Lundwall, M.; Rander, T.; Lindblad, A.; Bergersen, H.; Svensson, S.; Bjoerneholm, O.; Tchaplyguine, M.
2005-01-01
The development of electronic states in krypton clusters is investigated by high-resolution core-level electron spectroscopy. The energy ordering of bulk versus surface 3d -1 np(n>5) core-excited states in neutral clusters is demonstrated to be reversed to the 3d -1 5p level situation. The cluster 3d -1 6p,7p states are proven to be at a lower energy than the corresponding atomic levels. These findings reveal the ioniclike energy structure of the neutral cluster core-excited levels. The phenomenon is explained by a spatial spread of the excited orbitals over the cluster lattice
Kowalski, Karol
2009-05-21
In this article we discuss the problem of proper balancing of the noniterative corrections to the ground- and excited-state energies obtained with approximate coupled cluster (CC) and equation-of-motion CC (EOMCC) approaches. It is demonstrated that for a class of excited states dominated by single excitations and for states with medium doubly excited component, the newly introduced nested variant of the method of moments of CC equations provides mathematically rigorous way of balancing the ground- and excited-state correlation effects. The resulting noniterative methodology accounting for the effect of triples is tested using its parallel implementation on the systems, for which iterative CC/EOMCC calculations with full inclusion of triply excited configurations or their most important subset are numerically feasible.
The influence of autoionizing states on the excitation of helium by electrons
International Nuclear Information System (INIS)
Ittersum, T. van
1976-01-01
The work described in this thesis deals with resonance effects in the scattering of electrons by helium at energies near the threshold of the autoionizing states (50-70 eV). The investigation is performed by studying light emission following the excitation of singly excited states. In some cases, the polarization of the radiation was also investigated. The purpose of the research was (i) to enlarge our knowledge of triply excited negative ion states, i.e. resonance states which are formed by temporary binding of the incident electron to a doubly excited (autoionizing) state of neutral helium, and (ii) to clear up the nature of some resonance structures which could not be explained in terms of negative ion resonances
Signatures of Coulomb fission: a theoretical study
International Nuclear Information System (INIS)
Oberacker, V.; Kruse, H.; Pinkston, W.T.; Greiner, W.
1979-01-01
Evidence for Coulomb fission (CF) is noted first. Then the Hamiltonian is set down and explained, and an expression for the CF probability of CF is obtained. Results are summarized. Figures show the CF probability of 238 U as a function of projectile charge number and the excitation functions for CF of 238 U by 184 W and 136 Xe. 3 figures
σ-SCF: A direct energy-targeting method to mean-field excited states
Ye, Hong-Zhou; Welborn, Matthew; Ricke, Nathan D.; Van Voorhis, Troy
2017-12-01
The mean-field solutions of electronic excited states are much less accessible than ground state (e.g., Hartree-Fock) solutions. Energy-based optimization methods for excited states, like Δ-SCF (self-consistent field), tend to fall into the lowest solution consistent with a given symmetry—a problem known as "variational collapse." In this work, we combine the ideas of direct energy-targeting and variance-based optimization in order to describe excited states at the mean-field level. The resulting method, σ-SCF, has several advantages. First, it allows one to target any desired excited state by specifying a single parameter: a guess of the energy of that state. It can therefore, in principle, find all excited states. Second, it avoids variational collapse by using a variance-based, unconstrained local minimization. As a consequence, all states—ground or excited—are treated on an equal footing. Third, it provides an alternate approach to locate Δ-SCF solutions that are otherwise hardly accessible by the usual non-aufbau configuration initial guess. We present results for this new method for small atoms (He, Be) and molecules (H2, HF). We find that σ-SCF is very effective at locating excited states, including individual, high energy excitations within a dense manifold of excited states. Like all single determinant methods, σ-SCF shows prominent spin-symmetry breaking for open shell states and our results suggest that this method could be further improved with spin projection.
International Nuclear Information System (INIS)
Johnson, Matthew P.; Zia, Ahmad; Horton, Peter; Ruban, Alexander V.
2010-01-01
Xanthophyll excited states have been implicated by transient absorption and two-photon excitation studies in playing a key role in the regulation of photosynthetic light harvesting via photoprotective energy dissipation. For any proposed quenching mechanism to be effective it must reduce the chlorophyll excited state lifetime from 2 ns to ∼0.5-0.4 ns. In the presented study the effect of xanthophyll composition on the chlorophyll excited state lifetime in Arabidopsis leaves in the light harvesting (F m ) and photoprotective (NPQ) states was determined. The data was compared to the chlorophyll excited state lifetime of native isolated LHCII and CP26 in detergent micelles with varying xanthophyll composition. It was found that although the differences in xanthophyll composition between LHC complexes from various Arabidopsis mutants were sufficient to explain the varying F m lifetime (and varying PSII efficiency), they were not of a sufficient scale to fully explain the observed differences in the NPQ lifetimes. Only when the LHC complexes were exposed to a low detergent/low pH media, a condition known to mimic the conformational state of LHCII associated with NPQ in vivo, were variations in excited state lifetime large enough to explain the differences observed in leaves. Furthermore, the data reveal that the replacement of lutein by either zeaxanthin or violaxanthin in the internal xanthophyll binding sites of LHCII and CP26 reduces the efficiency of energy dissipation in the photoprotective state in leaves and isolated complexes.
Effects of crossed states on photoluminescence excitation spectroscopy of InAs quantum dots
Directory of Open Access Journals (Sweden)
Lin Chien-Hung
2011-01-01
Full Text Available Abstract In this report, the influence of the intrinsic transitions between bound-to-delocalized states (crossed states or quasicontinuous density of electron-hole states on photoluminescence excitation (PLE spectra of InAs quantum dots (QDs was investigated. The InAs QDs were different in size, shape, and number of bound states. Results from the PLE spectroscopy at low temperature and under a high magnetic field (up to 14 T were compared. Our findings show that the profile of the PLE resonances associated with the bound transitions disintegrated and broadened. This was attributed to the coupling of the localized QD excited states to the crossed states and scattering of longitudinal acoustical (LA phonons. The degree of spectral linewidth broadening was larger for the excited state in smaller QDs because of the higher crossed joint density of states and scattering rate.
Hydrogenlike nitrogen ions collision with helium into excited states
International Nuclear Information System (INIS)
Pan Guangyan; Yang Feng; Li Dawan; Xu Qian; Liu Huiping; Zhao Mengchun
1991-01-01
The emission spectra have been measured in collisions between N 6+ and He using the LHT-30 VUV Monochromator. The wavelength range is 10 nm-80 nm, the energy of N 6+ ions is 90 keV, the current of ion beam in the collision region is about 10 μA. Recently, the authors have investigated the electron capture processes and incident ions excitation in the velocity of N 6+ ions about 0.5 atomic unit. The emission spectrum of N V, N VI and N VII liens is given in collisions of N 6+ with He at 90 keV of ions energy
Coulomb gap triptych in a periodic array of metal nanocrystals.
Chen, Tianran; Skinner, Brian; Shklovskii, B I
2012-09-21
The Coulomb gap in the single-particle density of states (DOS) is a universal consequence of electron-electron interaction in disordered systems with localized electron states. Here we show that in arrays of monodisperse metallic nanocrystals, there is not one but three identical adjacent Coulomb gaps, which together form a structure that we call a "Coulomb gap triptych." We calculate the DOS and the conductivity in two- and three-dimensional arrays using a computer simulation. Unlike in the conventional Coulomb glass models, in nanocrystal arrays the DOS has a fixed width in the limit of large disorder. The Coulomb gap triptych can be studied via tunneling experiments.
Optically induced structural phase transitions in ion Coulomb crystals
DEFF Research Database (Denmark)
Horak, Peter; Dantan, Aurelien Romain; Drewsen, Michael
2012-01-01
We investigate numerically the structural dynamics of ion Coulomb crystals confined in a three-dimensional harmonic trap when influenced by an additional one-dimensional optically induced periodical potential. We demonstrate that transitions between thermally excited crystal structures, such as b......We investigate numerically the structural dynamics of ion Coulomb crystals confined in a three-dimensional harmonic trap when influenced by an additional one-dimensional optically induced periodical potential. We demonstrate that transitions between thermally excited crystal structures...
International Nuclear Information System (INIS)
Love, J.C.; Demas, J.N.
1983-01-01
The Foerster equation describes excited-state decay curves involving resonance intermolecular energy transfer. A linearized solution based on the phase-plane method has been developed. The new method is quick, insensitive to the fitting region, accurate, and precise
Generalized Bethe-Negele inequalities for excited states in muonic atoms
International Nuclear Information System (INIS)
Klarsfeld, S.
1976-11-01
Rigorous upper and lower bounds are derived for the Bethe logarithms in excited states of muonic atoms. Comparison with previous empirical estimates shows that the latter are inadequate in certain cases
Study of highly excited high spin states via the (HI, α) reaction
International Nuclear Information System (INIS)
Kubono, S.
1982-01-01
Three subjects are discussed in this paper. 1) The mechanism of (HI, α) reactions is briefly studied. 2) Possible excitation of molecular resonance states of 12 C- 12 C in 24 Mg through the 12 C( 16 O, α) 24 Mg reaction were investigated. A precise measurement of the level widths in 24 Mg did not support the previous report that the molecular states seen in 12 C + 12 C scattering had been excited in the transfer reaction 12 C( 16 O, α) 24 Mg. 3) Highly excited states in 28 Si, which have a large parentage of 12 C- 16 O, were also studied via the 12 C( 20 Ne, α) 28 Si reaction. An angular correlation measurement revealed the lowest 8 + and 10 + states at 14.00 and 15.97 MeV, respectively, which were selectively excited in the 12 C( 20 Ne, α) reaction. These results suggest a possible new band in 28 Si. (author)
Metastable states in parametrically excited multimode Hamiltonian systems
Kirr, E
2003-01-01
Consider a linear autonomous Hamiltonian system with time periodic bound state solutions. In this paper we study their dynamics under time almost periodic perturbations which are small, localized and Hamiltonian. The analysis proceeds through a reduction of the original infinite dimensional dynamical system to the dynamics of two coupled subsystems: a dominant m-dimensional system of ordinary differential equations (normal form), governing the projections onto the bound states and an infinite dimensional dispersive wave equation. The present work generalizes previous work of the authors, where the case of a single bound state is considered. Here, the interaction picture is considerably more complicated and requires deeper analysis, due to a multiplicity of bound states and the very general nature of the perturbation's time dependence. Parametric forcing induces coupling of bound states to continuum radiation modes, bound states directly to bound states, as well as coupling among bound states, which is mediate...
Radiative and nonradiative lifetimes in excited states of Ar, Kr and Xe atoms in Ne matrix
International Nuclear Information System (INIS)
Hahn, U.; Schwentner, N.
1979-10-01
Synchrotron radiation with its intense continuum and its excellent time structure has been exploited for time resolved luminescence spectroscopy in the solid state. By selective excitation of n = 1, n' = 1 and n = 2 exciton states of Xe, Kr and Ar atoms in Ne matrix we were able to identify the emitting states involved. Lifetimes within the cascade of radiative and radiationless relaxation between excited states as well as the radiative lifetimes for transitions to the ground state have been derived from the decay curves. Energy positions and radiative lifetimes of the emitting states correspond quite well with those of the free atoms. Radiative and radiationless relaxation processes take place within the manifold of excited states of the guest atoms. The rate constants for radiationless decay confirm an energy gap law. The order of the radiationless processes reaches in some cases extremely high values. Selection rules for spin and angular momentum are essential to understand the observed radiationless transition rates. (orig.)
Excitation of compound states in the subsystems as indirect tool in nuclear astrophysics
Directory of Open Access Journals (Sweden)
Tribble R.E.
2010-03-01
Full Text Available Astrophysical reactions proceeding through compound states represent one of the crucial part of nuclear astrophysics. However, due to the presence of the Coulomb barrier, it is often very difficult or even impossible to obtain the astrophysical S (E factor from measurements in the laboratory at astrophysically relevant energies. The Trojan Horse method (THM provides a unique tool to obtain the information about resonant astrophysical reactions at astrophysically relevant energies. Here the theory and application of the THM for the resonant reactions is addressed.
Chang, Xue-Ping; Fang, Qiu; Cui, Ganglong
2014-10-01
Photodissociation dynamics of pyruvic acid experimentally differs from that of commonly known ketones. We have employed the complete active space self-consistent field and its multi-state second-order perturbation methods to study its photodissociation mechanism in the S0, T1, and S1 states. We have uncovered four nonadiabatic photodecarboxylation paths. (i) The S1 system relaxes via an excited-state intramolecular proton transfer (ESIPT) to a hydrogen-transferred tautomer, near which an S1/S0 conical intersection funnels the S1 to S0 state. Then, some trajectories continue completing the decarboxylation reaction in the S0 state; the remaining trajectories via a reverse hydrogen transfer return to the S0 minimum, from which a thermal decarboxylation reaction occurs. (ii) Due to a small S1 -T1 energy gap and a large S1/T1 spin-orbit coupling, an efficient S1 → T1 intersystem crossing process happens again near this S1/S0 conical intersection. When decaying to T1 state, a direct photodecarboxylation proceeds. (iii) Prior to ESIPT, the S1 system first decays to the T1 state via an S1 → T1 intersystem crossing; then, the T1 system evolves to a hydrogen-transferred tautomer. Therefrom, an adiabatic T1 decarboxylation takes place due to a small barrier of 7.7 kcal/mol. (iv) Besides the aforementioned T1 ESIPT process, there also exists a comparable Norrish type I reaction in the T1 state, which forms the ground-state products of CH3CO and COOH. Finally, we have found that ESIPT plays an important role. It closes the S1-T1 and S1-S0 energy gaps, effecting an S1/T1/S0 three-state intersection region, and mediating nonadiabatic photodecarboxylation reactions of pyruvic acid.
Triplet Excited States as a Source of Relevant (Bio)Chemical Information
Jiménez Molero, María Consuelo; Miranda Alonso, Miguel Ángel
2014-01-01
The properties of triplet excited states are markedly medium-dependent, which turns this species into valuable tools for investigating the microenvironments existing in protein binding pockets. Monitoring of the triplet excited state behavior of drugs within transport proteins (serum albumins and alpha(1)-acid glycoproteins) by laser flash photolysis constitutes a valuable source of information on the strength of interaction, conformational freedom and protection from oxygen or other external...
Excitation of the lowest 1- state in 18O by scattering from 16O
International Nuclear Information System (INIS)
Carter, J.; Sellschop, J.P.F.; Clarkson, R.G.; Hnizdo, V.; Osterfeld, F.; Frahn, W.E.; Richter, A.
1981-01-01
The 1 - (4.45 MeV) state in 18 O, together with the 2 + (1.98 MeV) and 3 - (5.09 MeV) states, were excited by inelastic scattering from 16 O at E(lab)=35 MeV. In an attempt to understand the 1 - excitation, various macroscopic models, including a ralationship derived recently by Frahn, were considered. However, this excitation was found to be best explained by a microscopic description. A comparison is made with inelastic α-scattering from 18 O [af
Non-orthogonal configuration interaction for the calculation of multielectron excited states
Energy Technology Data Exchange (ETDEWEB)
Sundstrom, Eric J., E-mail: eric.jon.sundstrom@berkeley.edu; Head-Gordon, Martin [Department of Chemistry, University of California Berkeley, Berkeley, California 94720, USA and Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States)
2014-03-21
We apply Non-orthogonal Configuration Interaction (NOCI) to molecular systems where multielectron excitations, in this case double excitations, play a substantial role: the linear polyenes and β-carotene. We demonstrate that NOCI when applied to systems with extended conjugation, provides a qualitatively correct wavefunction at a fraction of the cost of many other multireference treatments. We also present a new extension to this method allowing for purification of higher-order spin states by utilizing Generalized Hartree-Fock Slater determinants and the details for computing 〈S{sup 2}〉 for the ground and excited states.
Statistical decay of dipole-excited states of Zr isotopes
Energy Technology Data Exchange (ETDEWEB)
Gayer, Udo; Zweidinger, Markus; Beck, Tobias; Mertes, Laura; Pai, Haridas; Pietralla, Norbert; Ries, Philipp; Romig, Christopher; Werner, Volker [IKP, TU Darmstadt (Germany); Cooper, Nathan [University of Richmond, Richmond (United States); Isaak, Johann [EMMI, GSI, Darmstadt (Germany); FIAS, Frankfurt (Germany); Loeher, Bastian; Savran, Deniz [GSI, Darmstadt (Germany); Scheck, Marcus [School of Engineering, UWS, Paisley (United Kingdom); SUPA, Glasgow (United Kingdom); Tornow, Werner [Duke University, Durham (United States)
2016-07-01
Decay properties of electric dipole excitations below the neutron separation threshold of {sup 92,94,96}Zr have been determined in several (γ,γ') and (vector γ,γ') experiments at the Darmstadt High Intensity Photon Setup and the High-Intensity Gamma-Ray Source in Durham, USA. The model of statistical decay is used to guide an interpretation of this low-lying dipole strength which is frequently discussed to arise from the low-energy tail of the giant dipole resonance and potentially an additional resonance structure often referred to as the pygmy dipole resonance. The availability of three complete data sets in the Zr isotopic chain allowed for a precise test of these extrapolations to low energies using different models for the level density and the photon strength function. In the talk, data and calculations are presented, and the suitability of photon scattering data for this kind of analysis is discussed.
Directory of Open Access Journals (Sweden)
Sakai S.
2013-03-01
Full Text Available Vibrational dynamics of dark excited states in carotenoids have been investigated using tunable Raman pump pulses. The S1 state has same vibrational dynamics in light-harvesting complex (LH1 and solution. The S* state in LH1 has similar vibrational modes with the triplet state of carotenoid. However, the so-called S* state in solution does not have the modes and is concluded to be different from the S* state in LH1.
Dynamic study of excited state hydrogen-bonded complexes of harmane in cyclohexane-toluene mixtures.
Carmona, Carmen; Balón, Manuel; Galán, Manuel; Guardado, Pilar; Muñoz, María A
2002-09-01
Photoinduced proton transfer reactions of harmane or 1-methyl-9H-pyrido[3,4-b]indole (HN) in the presence of the proton donor hexafluoroisopropanol (HFIP) in cyclohexane-toluene mixtures (CY-TL; 10% vol/vol of TL) have been studied. Three excited state species have been identified: a 1:2 hydrogen-bonded proton transfer complex (PTC), between the pyridinic nitrogen of the substrate and the proton donor, a hydrogen-bonded cation-like exciplex (CL*) with a stoichiometry of at least 1:3 and a zwitterionic exciplex (Z*). Time-resolved fluorescence measurements evidence that upon excitation of ground state PTC, an excited state equilibrium is established between PTC* and the cationlike exciplex, CL*, lambdaem approximately/= 390 nm. This excited state reaction is assisted by another proton donor molecule. Further reaction of CL* with an additional HFIP molecule produces the zwitterionic species, Z*, lambda(em) approximately/= 500 nm. From the analysis of the multiexponential decays, measured at different emission wavelengths and as a function of HFIP concentration, the mechanism of these excited state reactions has been established. Thus, three rate constants and three reciprocal lifetimes have been determined. The simultaneous study of 1,9-dimethyl-9H-pyrido[3,4-b]indole (MHN) under the same experimental conditions has helped to understand the excited state kinetics of these processes.
Noll, Ellis; Koehlinger, Mervin; Kowalski, Ludwik; Swackhamer, Gregg
1998-01-01
Describes the use of a computer-linked camera to demonstrate Coulomb's law. Suggests a way of reducing the difficulties in presenting Coulomb's law by teaching the inverse square law of gravity and the inverse square law of electricity in the same unit. (AIM)
Diffusion in Coulomb crystals.
Hughto, J; Schneider, A S; Horowitz, C J; Berry, D K
2011-07-01
Diffusion in Coulomb crystals can be important for the structure of neutron star crusts. We determine diffusion constants D from molecular dynamics simulations. We find that D for Coulomb crystals with relatively soft-core 1/r interactions may be larger than D for Lennard-Jones or other solids with harder-core interactions. Diffusion, for simulations of nearly perfect body-centered-cubic lattices, involves the exchange of ions in ringlike configurations. Here ions "hop" in unison without the formation of long lived vacancies. Diffusion, for imperfect crystals, involves the motion of defects. Finally, we find that diffusion, for an amorphous system rapidly quenched from Coulomb parameter Γ=175 to Coulomb parameters up to Γ=1750, is fast enough that the system starts to crystalize during long simulation runs. These results strongly suggest that Coulomb solids in cold white dwarf stars, and the crust of neutron stars, will be crystalline and not amorphous.
Kinetic studies following state-selective laser excitation
International Nuclear Information System (INIS)
Keto, J.W.
1991-01-01
During the past year, we have made measurements of state-to-state energy transfer cross sections and radiative lifetimes for Xe*(6p,6p',7p) and Kr*(5p) states in xenon and krypton buffer gases. These results are relevant to kinetic models of both excimer lasers and the infrared xenon laser; and they are a significant improvement in the precision of the known radiative lifetimes. 3 refs., 2 figs., 2 tabs
On excited states in real-time AdS/CFT
Energy Technology Data Exchange (ETDEWEB)
Botta-Cantcheff, Marcelo; Martínez, Pedro J.; Silva, Guillermo A. [Instituto de Física de La Plata - CONICET & Departamento de Física - UNLP,C.C. 67, 1900 La Plata (Argentina)
2016-02-25
The Skenderis-van Rees prescription, which allows the calculation of time-ordered correlation functions of local operators in CFT’s using holographic methods is studied and applied for excited states. Calculation of correlators and matrix elements of local CFT operators between generic in/out states are carried out in global Lorentzian AdS. We find the precise form of such states, obtain an holographic formula to compute the inner product between them, and using the consistency with other known prescriptions, we argue that the in/out excited states built according to the Skenderis-Van Rees prescription correspond to coherent states in the (large-N) AdS-Hilbert space. This is confirmed by explicit holographic computations. The outcome of this study has remarkable implications on generalizing the Hartle-Hawking construction for wave functionals of excited states in AdS quantum gravity.
Study of the giant dipole resonance built on highly excited states in Sn and Dy nuclei
International Nuclear Information System (INIS)
Stolk, A.
1988-01-01
A study is presented of the giant dipole resonance built on highly excited states. The aim is to get more detailed information on the properties of the GDR and to use it as a tool for the investigation of nuclear structure at high excitation energy. The high energy γ-rays seen from the decay of excited state GDRs in heavy ion fusion reactions reflect the average properties of the states populated by the γ-emission. The measurements at different initial excitation energies of 114 Sn provide information on the nuclear level density near the particle separation energy at an average angular momentum of 10ℎ. The study of shape changes at very high spin in 152-156 Dy nuclei is presented. A theoretical model developed to describe fusion-evaporation reactions is presented. 149 refs.; 63 figs.; 13 tabs
Particle hole excitations coupled to complex states in heavy-ion collisions
International Nuclear Information System (INIS)
Jolos, R.V.; Schmidt, R.
1982-01-01
The excitation of uncorrelated 1p-1h states in one nucleus due to the action of the time-dependent mean field of the other nucleus was studied earlier. No statistical assumptions or average procedures were made. Such a mechanism can be responsible for an appreciable excitation of the two nuclei during the short approach phase of the reaction (E* approximately> 100 MeV). The reversibility of the equations of motion leads to a deexcitation of the initially stored excitation energy into that of the relative motion for later times. This feedback behaviour of the internal excitation energy which results in particular to the deexcitation of high energetic 1p-1h pairs is probably not realistic due to the coupling of this states to more complex states with high density. It is studied the influence of this coupling due to the residual interaction between the nucleons on the dynamics of two colliding heavy ions
Excited-State Dynamics of Carotenoids Studied by Femtosecond Transient Absorption Spectroscopy
Energy Technology Data Exchange (ETDEWEB)
Lee, Ingu; Pang, Yoonsoo [Department of Physics and Photon Science, Gwangju (Korea, Republic of); Lee, Sebok [Gwangju Institute of Science and Technology, Gwangju (Korea, Republic of)
2014-03-15
Carotenoids, natural antenna pigments in photosynthesis share a symmetric backbone of conjugated polyenes. Contrary to the symmetric and almost planar geometries of carotenoids, excited state structure and dynamics of carotenoids are exceedingly complex. In this paper, recent infrared and visible transient absorption measurements and excitation dependent dynamics of 8'-apo-β-caroten-8'-al and 7',7'-dicyano-7'-apo-β-carotene will be reviewed. The recent visible transient absorption measurements of 8'-apo-β-caroten-8'-al in polar and nonpolar solvents will also be introduced to emphasize the complex excited-state dynamics and unsolved problems in the S{sub 2} and S{sub 1} excited states.
Dynamics of Excited State Proton Transfer in Nitro Substituted 10-Hydroxybenzo[h]quinolines
DEFF Research Database (Denmark)
Marciak, H; Hristova, S.; Deneva, V
2017-01-01
The ground state tautomerism and excited state intramolecular proton transfer (ESIPT) of 10-hydroxybenzo[h]quinoline (HBQ) and its nitro derivatives, 7-nitrobenzo[h]quinolin-10-ol (2) and 7,9-dinitrobenzo[h]quinolin-10-ol (3), have been studied in acetonitrile using steady state as well as time d...
EPR studies of excited state exchange and crystal-field effects in rare earth compounds
International Nuclear Information System (INIS)
Huang, C.Y.; Sugawara, K.; Cooper, B.R.
1976-01-01
EPR in excited crystal-field states of Tm 3+ , Pr 3+ , and Tb 3+ in singlet-ground-state systems and in the excited state of Ce 3+ in CeP are reviewed. Because one is looking at a crystal-field excited state resonance, the exchange, even if isotropic, does not act as a secular perturbation. This means that one obtains different effects and has access to more information about the dynamic effects of exchange than in conventional paramagnetic resonance experiments. The Tm and Pr monopnictides studied are paramagnetic at all temperatures. The most striking feature of the behavior of the GAMMA 5 /sup (2)/ EPR in the Tm compounds is the presence of an anomalous maximum in the temperature dependence of the g-factor. The relationship of this effect to anisotropic exchange is discussed. The results of the EPR of the excited GAMMA 5 /sup (2)/ level of Tb 3 + (g-factor becomes very large at T/sub N/ in antiferromagnetic TbX (X = P, As, Sb) and that of the excited GAMMA 8 level of Ce 3+ in antiferromagnetic CeP will also be reported. For sufficient dilution of the Tb 3+ in the terbium monopnictides, the systems become paramagnetic (Van Vleck paramagnets) down to 0 0 K. The Tb 3+ excited state resonance EPR in Tb/sub 0.1/ La/sub 0.9/P was studied as an example of behavior in such systems. 10 fig
Coulomb dissociation of N 20,21
Röder, Marko; Adachi, Tatsuya; Aksyutina, Yulia; Alcantara, Juan; Altstadt, Sebastian; Alvarez-Pol, Hector; Ashwood, Nicholas; Atar, Leyla; Aumann, Thomas; Avdeichikov, Vladimir; Barr, M.; Beceiro, Saul; Bemmerer, Daniel; Benlliure, Jose; Bertulani, Carlos
2016-01-01
Neutron-rich light nuclei and their reactions play an important role in the creation of chemical elements. Here, data from a Coulomb dissociation experiment on N20,21 are reported. Relativistic N20,21 ions impinged on a lead target and the Coulomb dissociation cross section was determined in a kinematically complete experiment. Using the detailed balance theorem, the N19(n,γ)N20 and N20(n,γ)N21 excitation functions and thermonuclear reaction rates have been determined. The N19(n,γ)N20 rate is...
Structure of high excited nuclear states and elastic scattering
International Nuclear Information System (INIS)
Zhivopistsev, F.A.; Rzhevskij, E.S.
1979-01-01
An approach to a unified description of nuclear reactions and nuclear structure based on the formalism of the quantum Green functions and on the ideas of the theory of finite Fermi systems has been formulated. New structural vertices are introduced, which are responsible for nucleon collectivization in an atomic nucleus and for the excitation of many-phonon, quasideuteron, quasitriton and other configurations. The vertices define both the processes of particle scattering by atomic nuclei (T matrix and optical potentials) and the nuclear structure (secular equations and wave functions). The vertices are determined from the equations with effective many-particle forces Fsub(nm)sup(c). In their turn the Fsub(nm)sup(c) forces are either determined from a comparison of theory and experiment, or calculated from the equations with more fundamental nucleon-nucleon forces in a nucleus. The effective forces Fsub(nm)sup(c) are more universal than the constants of the theory of finite Fermi-systems, which extends the boundaries of applicability of the particle-hole formalism in the description of nuclear processes. In this approach the traditional methods of description of the nuclear structure, based on particular models of hamiltonian and wave functions, acquire a natural interpretation
DEFF Research Database (Denmark)
Kjær, Kasper Skov; Kunnus, Kristjan; Harlang, Tobias C. B.
2018-01-01
The excited state dynamics of solvated [Fe(bpy)(CN)4]2-, where bpy = 2,2'-bipyridine, show significant sensitivity to the solvent Lewis acidity. Using a combination of optical absorption and X-ray emission transient spectroscopies, we have previously shown that the metal to ligand charge transfer...... the MLCT excited state relaxation dynamics of [Fe(bpy)(CN)4]2- in water, a strong Lewis acid solvent. The charge-transfer excited state is now found to decay in less than 100 femtoseconds, forming a quasi-stable metal centered excited state with a 13 picosecond lifetime. We find that this MC excited state...... developed for solar applications....
Multiphoton Rabi oscillations between highly excited Stark states of potassium
International Nuclear Information System (INIS)
He Yonglin
2011-01-01
We have applied a nonperturbative resonant theory to study the Rabi frequency of microwave multiphoton transitions between two Rydberg states of potassium in a static electric field. The Stark electric dipole moments used to calculate the Rabi frequency are determined by the Stark states' wave functions, which are obtained by the diagonalization method. The frequencies of the Rabi oscillations are in good agreement with either experimental ones or ones calculated by the time-dependent close-coupling method and the Floquet theory. Furthermore, we are able to show that the size of avoided crossings between the (n+2)s and (n,3) states can be predicted from the Stark electric dipole moment and the difference of the two Stark states' energy at a given resonance.
International Nuclear Information System (INIS)
Dallinger, R.F.; Farquharson, S.; Woodruff, W.H.; Rodgers, M.A.J.
1981-01-01
Resonance Raman and electronic absorption spectra are reported for the S 0 and T 1 states of the carotenoids β-carotene, zeaxanthin, echinenone, canthaxanthin, dihydroxylycopene, astaxanthin, decapreno(C 50 )-β-carotene, β-apo-8'-carotenal, and ethyl β-apo-8'-carotenoate. The results reveal qualitatively similar ground-state spectra and similar frequency shifts in all observed resonance Raman modes between S 0 and T 1 , regardless of carotenoid structure. Examinations of the relationship of the putative C--C and C==C frequencies in S 0 and T 1 reveals anomalous shifts to lower frequency in the ''single-bond'' mode upon electronic excitation. These shifts may be due to molecular distortions in the excited state which force changes in molecular motions comprising the observed modes. However, another possibility requiring no distortion is that the interaction (off-diagonal) force constants connecting the C--C and C==C modes change sign upon electronic excitation. This latter phenomenon may provide a unitary explanation for the ''anomalous'' frequency shifts in the C--C and C==C modes, both in the T 1 states of carotenoids and in the S 1 states of simpler polyenes, without postulating large, unpredicted structural changes upon excitation or general errors in existing vibrational or theoretical analyses. Resonance Raman and absorbance studies with 35-ps time resolution suggest that S 1 lifetime (of the 1 B/sub u/ and/or the 1 A/sub g/* states) of β-carotene in benzene is less than 1 ps
Effect of excited states on thermonuclear reaction rates
International Nuclear Information System (INIS)
Sargood, D.G.
1983-01-01
Values of the ratio of the thermonuclear reaction rate of a reaction, with target nuclei in a thermal distribution of energy states, to the reaction rate with all target nuclei in their ground states are tabulated for neutron, proton and α-particle induced reactions on the naturally occurring nuclei from 20 Ne to 70 Zn, at temperatures of 1, 2, 3.5 and 5x10 9 K. The ratios are determined from reaction rates based on statistical model cross sections
International Nuclear Information System (INIS)
Balakrishna, Jayashree; Bondarescu, Ruxandra; Daues, Gregory; Bondarescu, Mihai
2008-01-01
Excited state soliton stars are studied numerically for the first time. The stability of spherically symmetric S-branch excited state oscillatons under radial perturbations is investigated using a 1D code. We find that these stars are inherently unstable either migrating to the ground state or collapsing to black holes. Higher excited state configurations are observed to cascade through intermediate excited states during their migration to the ground state. This is similar to excited state boson stars [J. Balakrishna, E. Seidel, and W.-M. Suen, Phys. Rev. D 58, 104004 (1998).]. Ground state oscillatons are then studied in full 3D numerical relativity. Finding the appropriate gauge condition for the dynamic oscillatons is much more challenging than in the case of boson stars. Different slicing conditions are explored, and a customized gauge condition that approximates polar slicing in spherical symmetry is implemented. Comparisons with 1D results and convergence tests are performed. The behavior of these stars under small axisymmetric perturbations is studied and gravitational waveforms are extracted. We find that the gravitational waves damp out on a short time scale, enabling us to obtain the complete waveform. This work is a starting point for the evolution of real scalar field systems with arbitrary symmetries
Isospin quantum number and structure of the excited states in halo nuclei. Halo-isomers
International Nuclear Information System (INIS)
Izosimov, I.N.
2015-01-01
It has been shown that isobar-analog (IAS), double isobar-analog (DIAS), configuration (CS), and double configuration states (DCS) can simultaneously have n-n, n-p, and p-p halo components in their wave functions. Differences in halo structure of the excited and ground states can result in the formation of isomers (halo-isomers). Both the Borromean and tango halo types can be observed for n-p configurations of atomic nuclei. The structure of the ground and excited states with different isospin quantum number in halo-like nuclei is discussed. B(Mλ) and B(Eλ) for γ-transitions in 6-8 Li, 8-10 Be, 8,10,11 B, 10-14 C, 13-17 N, 15-17,19 O, and 17 F are analyzed. Special attention is given to nuclei whose ground state does not exhibit halo structure, but the excited state may have one.
Valkunas, L; Trinkunas, G; Müller, M G; Holzwarth, A R
1999-01-01
The excited state mixing effect is taken into account considering the difference spectra of dimers. Both the degenerate (homo) dimer as well as the nondegenerate (hetero) dimer are considered. Due to the higher excited state mixing with the two-exciton states in the homodimer, the excited state absorption (or the difference spectrum) can be strongly affected in comparison with the results obtained in the Heitler-London approximation. The difference spectrum of the heterodimer is influenced by two resonance effects (i) mixing of the ground state optical transitions of both monomers in the dimer and (ii) mixing of the excited state absorption of the excited monomer with the ground state optical transition in the nonexcited monomer. These effects have been tested by simulating the difference absorption spectra of the light-harvesting complex of photosystem II (LHC II) experimentally obtained with the 60 fs excitation pulses at zero delay times and various excitation wavelengths. The pairs of coupled chlorophylls...
Energy Technology Data Exchange (ETDEWEB)
Pietralla, N., E-mail: pietralla@ikp.tu-darmstadt.d [Institut fuer Kernphysik, Technische Universitaet Darmstadt, 64289 Darmstadt (Germany); Nuclear Structure Laboratory, SUNY at Stony Brook, Stony Brook, NY 11794-3800 (United States); Institut fuer Kernphysik, Universitaet zu Koeln, 50937 Koeln (Germany); Li, T.C. [Nuclear Structure Laboratory, SUNY at Stony Brook, Stony Brook, NY 11794-3800 (United States); Fritzsche, M. [Institut fuer Kernphysik, Technische Universitaet Darmstadt, 64289 Darmstadt (Germany); Ahmed, M.W. [Triangle Universities Nuclear Laboratory (TUNL), Duke University, Durham, NC 27708 (United States); Ahn, T.; Costin, A. [Institut fuer Kernphysik, Technische Universitaet Darmstadt, 64289 Darmstadt (Germany); Nuclear Structure Laboratory, SUNY at Stony Brook, Stony Brook, NY 11794-3800 (United States); Institut fuer Kernphysik, Universitaet zu Koeln, 50937 Koeln (Germany); Enders, J. [Institut fuer Kernphysik, Technische Universitaet Darmstadt, 64289 Darmstadt (Germany); Li, J. [Duke Free Electron Laser Laboratory (DFELL), Duke University, Durham, NC 27708 (United States); Mueller, S.; Neumann-Cosel, P. von [Institut fuer Kernphysik, Technische Universitaet Darmstadt, 64289 Darmstadt (Germany); Pinayev, I.V. [Duke Free Electron Laser Laboratory (DFELL), Duke University, Durham, NC 27708 (United States); Ponomarev, V.Yu.; Savran, D. [Institut fuer Kernphysik, Technische Universitaet Darmstadt, 64289 Darmstadt (Germany); Tonchev, A.P.; Tornow, W.; Weller, H.R. [Triangle Universities Nuclear Laboratory (TUNL), Duke University, Durham, NC 27708 (United States); Werner, V. [A.W. Wright Nuclear Structure Laboratory (WNSL), Yale University, New Haven, CT (United States); Wu, Y.K. [Duke Free Electron Laser Laboratory (DFELL), Duke University, Durham, NC 27708 (United States); Zilges, A. [Institut fuer Kernphysik, Universitaet zu Koeln, 50937 Koeln (Germany)
2009-10-26
The Pb(gamma{sup -}>,gamma{sup '}) photon scattering reaction has been studied with the nearly monochromatic, linearly polarized photon beams at the High Intensity gamma-ray Source (HIgammaS) at the DFELL. Azimuthal scattering intensity asymmetries measured with respect to the polarization plane of the beam have been used for the first time to assign both the spin and parity quantum numbers of dipole excited states of {sup 206,207,208}Pb at excitation energies in the vicinity of 5.5 MeV. Evidence for dominant particle-core coupling is deduced from these results along with information on excitation energies and electromagnetic transition matrix elements. Implications of the existence of weakly coupled states built on highly excited core states in competition with 1homega single particle (hole) excitations at comparable energies are discussed.
Exciplex formation and excited state deactivation of difluoroborondipyrromethene (Bodipy) dyads.
Benniston, Andrew C; Copley, Graeme; Lemmetyinen, Helge; Tkachenko, Nikolai V
2010-06-07
Two series of geometrically-related dyads are discussed based on the difluoroborondipyrromethene (Bodipy) unit, and incorporating covalently attached hydroquinone/quinone groups. These units are anchored directly, or via a phenylene spacer, to the Bodipy core at the meso position in one series (BD-MHQ, BD-MQ, BD-MPHQ, BD-MPQ), but for the second series the attachment site is the 2-position (BD-SHQ, BD-SQ, BD-SPHQ, BD-SPQ). The compounds show various levels of fluorescence depending on the oxidation state of the appended group and the substitution pattern. In non-polar solvents such as toluene, diethyl ether and dichlorobenzene, the S(1) state deactivation of the Bodipy unit in BD-SPQ and BD-MPQ is dominated by (1, 3)exciplex formation, which has not been reported for Bodipy derivatives so far. In the latter molecule, the decay of the exciplex is divided between population of the Bodipy triplet state (13 %-21 %) and ground state reformation. This partitioning is not seen for the side-on substituted derivative, BD-SPQ, and only ground state reformation is observed following decay of the exciplex. This difference in behavior is explained by the radical-pair inter-system-crossing mechanism, which more effectively operates in BD-MPQ because of the orthogonality of the donor-acceptor units. In the more polar solvent CH(3)CN all the quinone derivatives show fast formation of the charge-separated state (k(CS)) followed by slower charge recombination (k(CR)). The ratio k(CS)/k(CR)
Directory of Open Access Journals (Sweden)
Yuyuan Zhang
2016-11-01
Full Text Available Melamine may have been an important prebiotic information carrier, but its excited-state dynamics, which determine its stability under UV radiation, have never been characterized. The ability of melamine to withstand the strong UV radiation present on the surface of the early Earth is likely to have affected its abundance in the primordial soup. Here, we studied the excited-state dynamics of melamine (a proto-nucleobase and its lysine derivative (a proto-nucleoside using the transient absorption technique with a UV pump, and UV and infrared probe pulses. For melamine, the excited-state population decays by internal conversion with a lifetime of 13 ps without coupling significantly to any photochemical channels. The excited-state lifetime of the lysine derivative is slightly longer (18 ps, but the dominant deactivation pathway is otherwise the same as for melamine. In both cases, the vast majority of excited molecules return to the electronic ground state on the aforementioned time scales, but a minor population is trapped in a long-lived triplet state.
The structure of nuclear states at low, intermediate and high excitation energies
International Nuclear Information System (INIS)
Soloviev, V.G.
1976-01-01
It is shown that within the model based on the quasiparticle-phonon interaction one can obtain the description of few-quasiparticle components of nuclear states at low, intermediate and high excitation energies. For the low-lying states the energy of each level is calculated. The few-quasiparticle components at intermediate and high excitation energies are represented to be averaged in certain energy intervals and their characteri stics are given as the corresponding strength functions. The fragmentation of single-particle states in deformed nuclei is studied. It is shown that in the distribution of the single-particle strength alongside with a large maximum there appear local maxima and the distribution itself has a long tail. The dependence of neutron strength functions on the excitation energy is investigated for the transfer reaction of the type (d,p) and (d,t). The s,- p,- and d-wave neutron strength functions are calculated at the neutron binding energy Bn. A satisfactory agreement with experiment is obtained. The energies and Elambda-strength functions for giant multipole resonances in deformed nuclei are calculated. The energies of giant quadrupole and octupole resonances are calculated. Their widths and fine structure are being studied. It is stated that to study the structure of highly excited states it is necessary to find the values of many-quasiparticle components of the wave functions. The ways of experimental determination of these components based on the study of γ-transitions between highly excited states are discussed
International Nuclear Information System (INIS)
Suzuki, D.; Iwasaki, H.; Ong, H.J.; Imai, N.; Sakurai, H.; Nakao, T.; Aoi, N.; Baba, H.; Bishop, S.; Ichikawa, Y.; Ishihara, M.; Kondo, Y.; Kubo, T.; Kurita, K.; Motobayashi, T.; Nakamura, T.; Okumura, T.; Onishi, T.K.; Ota, S.; Suzuki, M.K.
2008-01-01
Lifetime measurements were performed on low-lying excited states of the neutron-rich isotope 17 C using the recoil shadow method. The γ-decay mean lifetimes were determined to be 583±21(stat)±35(syst) ps for the first excited state at 212 keV and 18.9±0.6(stat)±4.7(syst) ps for the second excited state at 333 keV. Based on a comparison with the empirical upper limits for the electromagnetic transition strengths, these decays are concluded to be predominantly M1 transitions. The reduced M1 transition probabilities to the ground state were deduced to be (1.0±0.1)x10 -2 μ N 2 and (8.2 -1.8 +3.2 )x10 -2 μ N 2 , respectively, for the first and second excited states. The strongly hindered M1 strength as well as the lowered excitation energy represents unique nature of the 212-keV state
The properties of 4'-N,N-dimethylaminoflavonol in the ground and excited states
Moroz, V. V.; Chalyi, A. G.; Roshal, A. D.
2008-09-01
The mechanism of protonation of 4-N,N-dimethylaminoflavonol and the structure of its protolytic forms in the ground and excited states were studied by electron absorption and fluorescence (steady-state and time-resolved) spectroscopy and with the use of the RM1 quantum-chemical method. A comparison of equilibrium constants and the theoretical enthalpies of formation showed that excitation should be accompanied by the inversion of the basicity of the electron acceptor groups of this compound and, as a consequence, changes in the structure of its monocationic form. An analysis of the spectral parameters of the protolytic 4-N,N-dimethylaminoflavonol forms, however, showed that their structure and the sequence of protonation in the excited state were the same as in the ground state. Changes in the structure of the monocation in the excited state were not observed because of the fast radiationless deactivation of this form and the occurrence of excited state intramolecular proton transfer in aprotic solvents.
Coherent secondary emission from resonantly excited two-exciton states
DEFF Research Database (Denmark)
Birkedal, Dan
2000-01-01
The coherent interaction of light and the electronic states of semiconductors near the fundamental bandgap has been a very active topic of research since the advent of ultrafast lasers. While many of the ultrafast nonlinear properties of semiconductors have been well explained within mean field...
On the nature of highly vibrationally excited states of thiophosgene
Indian Academy of Sciences (India)
SCCl2) is made in order to gain insights into some of the experimental observations and spectral features. The states analysed here lie in a spectrally complex region where strong mode mixings are expected due to the overlap of several ...
Energy Technology Data Exchange (ETDEWEB)
Chang, Xue-Ping; Fang, Qiu, E-mail: fangqiu917@bnu.edu.cn; Cui, Ganglong, E-mail: ganglong.cui@bnu.edu.cn [Key Laboratory of Theoretical and Computational Photochemistry, Ministry of Education, College of Chemistry, Beijing Normal University, Beijing 100875 (China)
2014-10-21
Photodissociation dynamics of pyruvic acid experimentally differs from that of commonly known ketones. We have employed the complete active space self-consistent field and its multi-state second-order perturbation methods to study its photodissociation mechanism in the S{sub 0}, T{sub 1}, and S{sub 1} states. We have uncovered four nonadiabatic photodecarboxylation paths. (i) The S{sub 1} system relaxes via an excited-state intramolecular proton transfer (ESIPT) to a hydrogen-transferred tautomer, near which an S{sub 1}/S{sub 0} conical intersection funnels the S{sub 1} to S{sub 0} state. Then, some trajectories continue completing the decarboxylation reaction in the S{sub 0} state; the remaining trajectories via a reverse hydrogen transfer return to the S{sub 0} minimum, from which a thermal decarboxylation reaction occurs. (ii) Due to a small S{sub 1} −T{sub 1} energy gap and a large S{sub 1}/T{sub 1} spin-orbit coupling, an efficient S{sub 1} → T{sub 1} intersystem crossing process happens again near this S{sub 1}/S{sub 0} conical intersection. When decaying to T{sub 1} state, a direct photodecarboxylation proceeds. (iii) Prior to ESIPT, the S{sub 1} system first decays to the T{sub 1} state via an S{sub 1} → T{sub 1} intersystem crossing; then, the T{sub 1} system evolves to a hydrogen-transferred tautomer. Therefrom, an adiabatic T{sub 1} decarboxylation takes place due to a small barrier of 7.7 kcal/mol. (iv) Besides the aforementioned T{sub 1} ESIPT process, there also exists a comparable Norrish type I reaction in the T{sub 1} state, which forms the ground-state products of CH{sub 3}CO and COOH. Finally, we have found that ESIPT plays an important role. It closes the S{sub 1}-T{sub 1} and S{sub 1}-S{sub 0} energy gaps, effecting an S{sub 1}/T{sub 1}/S{sub 0} three-state intersection region, and mediating nonadiabatic photodecarboxylation reactions of pyruvic acid.
Theory of g-shift and linewidth in CeP excited state EPR
International Nuclear Information System (INIS)
Yang, D.; Cooper, B.R.; Huang, C.Y.; Sugawara, K.
1979-01-01
The Mori-Zwanzig memory function formalism was used to analyze the observed excited state EPR mode in CeP. The mixing of the Zeeman-split crystal-field excitation by the exchange, particularly among those with degenerate frequencies, yields a normal mode determining the observed low-frequency spectrum. This is illustrated by calculation with Heisenberg exchange which yields a single peak in qualitative agreement with the experiment
Localized excitations in nonlinear complex systems current state of the art and future perspectives
Cuevas-Maraver, Jesús; Frantzeskakis, Dimitri; Karachalios, Nikos; Kevrekidis, Panayotis; Palmero-Acebedo, Faustino
2014-01-01
The study of nonlinear localized excitations is a long-standing challenge for research in basic and applied science, as well as engineering, due to their importance in understanding and predicting phenomena arising in nonlinear and complex systems, but also due to their potential for the development and design of novel applications. This volume is a compilation of chapters representing the current state-of-the-art on the field of localized excitations and their role in the dynamics of complex physical systems.
Watson-Crick base pairing controls excited-state decay in natural DNA.
Bucher, Dominik B; Schlueter, Alexander; Carell, Thomas; Zinth, Wolfgang
2014-10-13
Excited-state dynamics are essential to understanding the formation of DNA lesions induced by UV light. By using femtosecond IR spectroscopy, it was possible to determine the lifetimes of the excited states of all four bases in the double-stranded environment of natural DNA. After UV excitation of the DNA duplex, we detected a concerted decay of base pairs connected by Watson-Crick hydrogen bonds. A comparison of single- and double-stranded DNA showed that the reactive charge-transfer states formed in the single strands are suppressed by base pairing in the duplex. The strong influence of the Watson-Crick hydrogen bonds indicates that proton transfer opens an efficient decay path in the duplex that prohibits the formation or reduces the lifetime of reactive charge-transfer states. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Zhou, Qiao; Du, Can; Yang, Li; Zhao, Meiyu; Dai, Yumei; Song, Peng
2017-06-22
The single and dual cooperated proton transfer dynamic process in the excited state of 1,5-dihydroxyanthraquinone (1,5-DHAQ) was theoretically investigated, taking solvent effects (ethanol) into account. The absorption and fluorescence spectra were simulated, and dual fluorescence exhibited, which is consistent with previous experiments. Analysis of the calculated IR and Raman vibration spectra reveals that the intramolecular hydrogen bonding interactions (O 20 -H 21 ···O 24 and O 22 -H 23 ···O 25 ) are strengthened following the excited proton transfer process. Finally, by constructing the potential energy surfaces of the ground state, first excited singlet state, and triplet state, the mechanism of the intramolecular proton transfer of 1,5-DHAQ can be revealed.
Tracking excited-state charge and spin dynamics in iron coordination complexes
DEFF Research Database (Denmark)
Zhang, Wenkai; Alonso-Mori, Roberto; Bergmann, Uwe
2014-01-01
to spin state, can elucidate the spin crossover dynamics of [Fe(2,2'-bipyridine)(3)](2+) on photoinduced metal-to-ligand charge transfer excitation. We are able to track the charge and spin dynamics, and establish the critical role of intermediate spin states in the crossover mechanism. We anticipate......Crucial to many light-driven processes in transition metal complexes is the absorption and dissipation of energy by 3d electrons(1-4). But a detailed understanding of such non-equilibrium excited-state dynamics and their interplay with structural changes is challenging: a multitude of excited...... states and possible transitions result in phenomena too complex to unravel when faced with the indirect sensitivity of optical spectroscopy to spin dynamics(5) and the flux limitations of ultrafast X-ray sources(6,7). Such a situation exists for archetypal poly-pyridyl iron complexes, such as [Fe(2...
International Nuclear Information System (INIS)
Gadaczek, Immanuel Patrick
2013-01-01
Theoretical background, parameterization and performance of the newly developed semiempirical configuration interaction singles (CIS) method MSINDO-sCIS (scaled configuration interaction singles) are presented. The CIS Hamiltonian is modified by scaling of the Coulomb and exchange integrals and a semiempirical correction of the diagonal elements. For a recently proposed benchmark set of 28 medium-sized organic molecules, vertical excitation energies for singlet and triplet states have been calculated and statistically evaluated. A full reparameterization of the MSINDO method for both ground and excited state properties was performed. The results of the reparameterized MSINDO-sCIS method are compared to the currently best semiempirical method for excited states, OM3-CISDTQ by Thiel et al., and to other standard methods, such as time-dependent density- functional theory. The mean absolute deviation with respect to the theoretical best estimates (TBEs) for MSINDO-sCIS is 0.44 eV, comparable to the OM3 method but significantly smaller than for Zerner's INDO/S. The computational effort is strongly reduced compared to OM3-CISDTQ and OM3-MRCISD, since only single excitations are taken into account. Higher excitations are implicitly included by parameterization and the empirical correction term. By application of the Davidson-Liu block diagonalization method high computational efficiency is achieved. Furthermore it is demonstrated, that the MSINDO-sCIS method correctly describes charge-transfer (CT) states, that represent a crucial problem for time-dependent density functional theory (TD-DFT) methods. Additionally this method is extended to open-shell systems by the UCIS (unrestricted CIS) approach. MSINDO allows the calculation of periodic systems via the cyclic cluster model (CCM) which is a direct-space approach and therefore can be in principle combined with all molecular quantum-chemical techniques. The sCIS/UCIS equations are solved for a cluster with periodic
Luminescent materials: probing the excited state of emission centers by spectroscopic methods
International Nuclear Information System (INIS)
Mihóková, E; Nikl, M
2015-01-01
We review recent methods employed to study the excited state of rare-earth centers in various luminescent and scintillating materials. The focus is on processes that help determine localization of the excited state within the material band gap, namely photoionization and thermally stimulated ionization. Then the tunneling process between the luminescence center and the trapping state is addressed. We describe the experimental implementation of methods recently developed to study these processes. We report theoretical models helping the data interpretation. We also present application to currently investigated materials. (topical review)
International Nuclear Information System (INIS)
Kazanskii, A.K.
1982-01-01
An exactly solvable model is constructed for the description of the processes that take place when a slow electron collides with a diatomic molecule (vibrational excitation, associative detachment, and dissociative attachment). As a particular model of the variant, the case of an antibonding (virtual) state of an intermediate state is considered, and a term of this state is parametrized in a very simple manner. The vibrational excitation and dissociative attachment are calculated for a system corresponding to the HCl molecule. The results are in good qualitative agreement with experiment
Photoemission from excited states in rare gas solids by combining synchrotronradiation with a laser
International Nuclear Information System (INIS)
Bernstorff, S.
1984-09-01
A new spectroscopic method has been developed to study excited states in rare gas solids: Excitons and conductionband-states are populated by synchrotron radiation (photon energy hw SR =5 - 30 eV). Subsequently electrons from these bound or conduction band-states are excited above the vacuum level of the solid by a pulsed dye laser (hw L =1.9 - 3.7 eV). This experimental technique was applied to solid Xe, Kr, Ar and Ne. (orig./GSCH)
Directory of Open Access Journals (Sweden)
Chien-Hao Lin
2015-09-01
Full Text Available In the present work, we report an investigation on quantum entanglement in the doubly excited 2s2 1Se resonance state of the positronium negative ion by using highly correlated Hylleraas type wave functions, determined by calculation of the density of resonance states with the stabilization method. Once the resonance wave function is obtained, the spatial (electron-electron orbital entanglement entropies (von Neumann and linear can be quantified using the Schmidt decomposition method. Furthermore, Shannon entropy in position space, a measure for localization (or delocalization for such a doubly excited state, is also calculated.
International Nuclear Information System (INIS)
Kalman, C.S.; Tran, B.; Hall, R.L.
1987-01-01
The hypothesis that the interquark potential in the baryon is the sum of a Coulomb and a linear potential is evalutated in terms of the model of Isgur and Karl as modified by Kalman, Hal and Misra. Six parameters are used to fit the eight ground-state baryon masses. The closeness of the predicted values to the experimental values verifies the hypothesis
Properties of the Excited States of Molecular Ions.
1981-04-13
FIg. 1). techniques have beest applied to the study of quartet states of Oi. The four potential curves most relevant Guyon et al., using a synchrotron...8217 a’ a a C ’U ~ ~ ~ ~ ~ ~ ~ 2 2,~ C a ’I C~- C ’ ’ ’ C- ~ C-E-38- ’- u A() A09a 265 SRI INTERNATIONAL 14FNLO PARK CA MOLECULAR PHYSICS LAB F
Charge-carrier dynamics and Coulomb effects in semiconductor tetrapods
International Nuclear Information System (INIS)
Mauser, Christian
2011-01-01
In this thesis the Coulomb interaction and its influence on localization effects and dynamics of charge carriers in semiconductor nanocrystals were studied. In the studied nanostructures it deals with colloidal tetrapod heterostructures, which consist of a cadmium selenide (CdSe) core and four tetraedrical grown cadmium sulfide (CdS) respectively cadmium telluride (CdTe) legs, which exhibit a type-I respectively type-II band transition. The dynamics and interactions were studied by means of photoluminescence (PL) and absorption measurements both on the ensemble and on single nanoparticles, as well as time-resolved PL and transient absorption spectroscopy. Additionally theoretical simulations of the wave-function distributions were performed, which are based on the effective-mass approximation. The special band structure of the CdSe/CdS tetrapods offers a unique possibility to study the Coulomb interaction. The flat conduction band in these heterostructures makes the electron via the Coulomb interaction sensitive to the localization position of the hole within the structure. The valence band has instead a potential maximum in the CdSe, which leads to a directed localization of the hole and the photoluminescence of the core. Polarization-resolved measurements showed hereby an anisotropy of the photoluminescence, which could be explained by means of simulations of the wave-function distribution with an asymmetry at the branching point. Charge-carrier localization occur mainly both in longer structures and in trap states in the CdS leg and can be demonstrated in form of a dual emission from a nanocrystal. The charge-carrier dynamics of electron and hole in tetrapods is indeed coupled by the Coulomb interaction, however it cannot be completely described in an exciton picture. The coupled dynamics and the Coulomb interaction were studied concerning a possible influence of the geometry in CdSe/CdS nanorods and compared with those of the tetrapods. The interactions of the
Proton emission from high spin states of proton rich excited 94Ag
International Nuclear Information System (INIS)
Aggarwal, Mamta
2008-01-01
Recent observation of direct 1P and 2P decay of 21 + isomer in proton rich 94 Ag has led to the present theoretical investigation of proton radioactivity from 94 Ag in ground state and excited state and it's dependence on the structural transitions
Thermality and excited state Rényi entropy in two-dimensional CFT
Energy Technology Data Exchange (ETDEWEB)
Lin, Feng-Li [Department of Physics, National Taiwan Normal University,Taipei 11677, Taiwan (China); Wang, Huajia [Department of Physics, University of Illinois,Urbana-Champaign, IL 61801 (United States); Zhang, Jia-ju [Dipartimento di Fisica, Università degli Studi di Milano-Bicocca,Piazza della Scienza 3, I-20126 Milano (Italy); Theoretical Physics Division, Institute of High Energy Physics, Chinese Academy of Sciences,19B Yuquan Rd, Beijing 100049 (China); Theoretical Physics Center for Science Facilities, Chinese Academy of Sciences,19B Yuquan Rd, Beijing 100049 (China)
2016-11-21
We evaluate one-interval Rényi entropy and entanglement entropy for the excited states of two-dimensional conformal field theory (CFT) on a cylinder, and examine their differences from the ones for the thermal state. We assume the interval to be short so that we can use operator product expansion (OPE) of twist operators to calculate Rényi entropy in terms of sum of one-point functions of OPE blocks. We find that the entanglement entropy for highly excited state and thermal state behave the same way after appropriate identification of the conformal weight of the state with the temperature. However, there exists no such universal identification for the Rényi entropy in the short-interval expansion. Therefore, the highly excited state does not look thermal when comparing its Rényi entropy to the thermal state one. As the Rényi entropy captures the higher moments of the reduced density matrix but the entanglement entropy only the average, our results imply that the emergence of thermality depends on how refined we look into the entanglement structure of the underlying pure excited state.
van Delden, Richard A.; Huck, N.P.M.; Piet, J.J.; Warman, J.M.; Meskers, S.C.J.; Dekkers, H.P J M; Feringa, B.L.
2003-01-01
The photochemical control of ground- and excited-state chirality of (M)-cis-(1) and (P)-trans(2)-2-nitro-7-(dimethylamino)-9-(2',3'-dihydro-1'H-naphtho[2,1-b]-thiopyran-1'-ylidene)-9H-thioxanthene is described. It is shown that while ground state chirality can be controlled photochemically by
Delden, van R.A.; Huck, H.P.M.; Piet, J.J.; Warman, J.M.; Meskers, S.C.J.; Dekkers, H.P.J.M.; Feringa, B.L.
2003-01-01
The photochemical control of ground- and excited-state chirality of (M)-cis-(1) and (P)-trans-(2)-2-nitro-7-(dimethylamino)-9-(2',3' -dihydro-1'H-naphtho[2,1-b]-thiopyran-1'-ylidene)-9H-thioxanthene is described. It is shown that while ground state chirality can be controlled photochemically by
Substituent effects on the excited states of phenyl-capped phenylene vinylene tetramers
Candeias, L.P.; Gelinck, G.H.; Piet, J.J.; Piris, J.; Wegewijs, B.; Peeters, E.; Wildeman, J.; Hadziioannou, G.; Müllen, K.
2001-01-01
The singlet and triplet excited states of phenyl-capped tetramers of phenylene vinylene with different alkyl, alkoxy or cyano substituents, were investigated in benzene solution. The lowest singlet states were studied by laser flash-photolysis with time-resolved microwave conductivity and
Coulomb interactions in charged fluids.
Vernizzi, Graziano; Guerrero-García, Guillermo Iván; de la Cruz, Monica Olvera
2011-07-01
The use of Ewald summation schemes for calculating long-range Coulomb interactions, originally applied to ionic crystalline solids, is a very common practice in molecular simulations of charged fluids at present. Such a choice imposes an artificial periodicity which is generally absent in the liquid state. In this paper we propose a simple analytical O(N(2)) method which is based on Gauss's law for computing exactly the Coulomb interaction between charged particles in a simulation box, when it is averaged over all possible orientations of a surrounding infinite lattice. This method mitigates the periodicity typical of crystalline systems and it is suitable for numerical studies of ionic liquids, charged molecular fluids, and colloidal systems with Monte Carlo and molecular dynamics simulations.
Contribution to the heavy-ion optical potential from coupling to vibrational states
Energy Technology Data Exchange (ETDEWEB)
Donangelo, R; Canto, L F; Hussein, M S
1978-11-01
The component of the optical potential in the elastic channel due to the coupling to vibrational states in Coulomb excitation is derived using a previously developed semiclassical method. Several numerical examples are worked out.
Dibaryon resonances as rotational excitations of six-quark states
International Nuclear Information System (INIS)
Kondratyuk, L.A.; Martem'yanov, B.V.; Shchepkin, M.G.
1986-01-01
Using the model of streched rotating (stringlike) bags with spin-orbit interaction of quarks the properties of nonstrange dibaryon spectrum are considered. The resonance d'(T=0, J P =2 - ) near the πNN threshold with the mass 1.95+2.05 GeV is predicted. Two other members of this family in spin-orbit are also predicted: d''(1 - ) and d'''(0 - ) (δE ls =30-40 MeV). Possible exostence of narrow dibaryon states with isospin T=1 and 2 is doscussed
International Nuclear Information System (INIS)
Greensite, J.; Olejnik, S.
2003-01-01
We study the phase structure of SU(2) gauge theories at zero and high temperature, with and without scalar matter fields, in terms of the symmetric/broken realization of the remnant gauge symmetry which exists after fixing to Coulomb gauge. The symmetric realization is associated with a linearly rising color Coulomb potential (which we compute numerically), and is a necessary but not sufficient condition for confinement.
Production of excited beauty states in Z decays
Buskulic, Damir; De Bonis, I; Décamp, D; Ghez, P; Goy, C; Lees, J P; Lucotte, A; Minard, M N; Odier, P; Pietrzyk, B; Ariztizabal, F; Chmeissani, M; Crespo, J M; Efthymiopoulos, I; Fernández, E; Fernández-Bosman, M; Gaitan, V; Garrido, L; Martínez, M; Orteu, S; Pacheco, A; Padilla, C; Palla, Fabrizio; Pascual, A; Perlas, J A; Sánchez, F; Teubert, F; Colaleo, A; Creanza, D; De Palma, M; Farilla, A; Gelao, G; Girone, M; Iaselli, Giuseppe; Maggi, G; Maggi, M; Marinelli, N; Natali, S; Nuzzo, S; Ranieri, A; Raso, G; Romano, F; Ruggieri, F; Selvaggi, G; Silvestris, L; Tempesta, P; Zito, G; Huang, X; Lin, J; Ouyang, Q; Wang, T; Xie, Y; Xu, R; Xue, S; Zhang, J; Zhang, L; Zhao, W; Bonvicini, G; Cattaneo, M; Comas, P; Coyle, P; Drevermann, H; Engelhardt, A; Forty, Roger W; Frank, M; Hagelberg, R; Harvey, J; Jacobsen, R; Janot, P; Jost, B; Knobloch, J; Lehraus, Ivan; Markou, C; Martin, E B; Mato, P; Meinhard, H; Minten, Adolf G; Miquel, R; Oest, T; Palazzi, P; Pater, J R; Pusztaszeri, J F; Ranjard, F; Rensing, P E; Rolandi, Luigi; Schlatter, W D; Schmelling, M; Schneider, O; Tejessy, W; Tomalin, I R; Venturi, A; Wachsmuth, H W; Wiedenmann, W; Wildish, T; Witzeling, W; Wotschack, J; Ajaltouni, Ziad J; Bardadin-Otwinowska, Maria; Barrès, A; Boyer, C; Falvard, A; Gay, P; Guicheney, C; Henrard, P; Jousset, J; Michel, B; Monteil, S; Montret, J C; Pallin, D; Perret, P; Podlyski, F; Proriol, J; Rossignol, J M; Saadi, F; Fearnley, Tom; Hansen, J B; Hansen, J D; Hansen, J R; Hansen, P H; Nilsson, B S; Kyriakis, A; Simopoulou, Errietta; Siotis, I; Vayaki, Anna; Zachariadou, K; Blondel, A; Bonneaud, G R; Brient, J C; Bourdon, P; Passalacqua, L; Rougé, A; Rumpf, M; Tanaka, R; Valassi, Andrea; Verderi, M; Videau, H L; Candlin, D J; Parsons, M I; Focardi, E; Parrini, G; Corden, M; Delfino, M C; Georgiopoulos, C H; Jaffe, D E; Antonelli, A; Bencivenni, G; Bologna, G; Bossi, F; Campana, P; Capon, G; Chiarella, V; Felici, G; Laurelli, P; Mannocchi, G; Murtas, F; Murtas, G P; Pepé-Altarelli, M; Dorris, S J; Halley, A W; ten Have, I; Knowles, I G; Lynch, J G; Morton, W T; O'Shea, V; Raine, C; Reeves, P; Scarr, J M; Smith, K; Smith, M G; Thompson, A S; Thomson, F; Thorn, S; Turnbull, R M; Becker, U; Braun, O; Geweniger, C; Graefe, G; Hanke, P; Hepp, V; Kluge, E E; Putzer, A; Rensch, B; Schmidt, M; Sommer, J; Stenzel, H; Tittel, K; Werner, S; Wunsch, M; Beuselinck, R; Binnie, David M; Cameron, W; Colling, D J; Dornan, Peter J; Konstantinidis, N P; Moneta, L; Moutoussi, A; Nash, J; San Martin, G; Sedgbeer, J K; Stacey, A M; Dissertori, G; Girtler, P; Kneringer, E; Kuhn, D; Rudolph, G; Bowdery, C K; Brodbeck, T J; Colrain, P; Crawford, G; Finch, A J; Foster, F; Hughes, G; Sloan, Terence; Whelan, E P; Williams, M I; Galla, A; Greene, A M; Kleinknecht, K; Quast, G; Raab, J; Renk, B; Sander, H G; Wanke, R; Zeitnitz, C; Aubert, Jean-Jacques; Bencheikh, A M; Benchouk, C; Bonissent, A; Bujosa, G; Calvet, D; Carr, J; Diaconu, C A; Etienne, F; Thulasidas, M; Nicod, D; Payre, P; Rousseau, D; Talby, M; Abt, I; Assmann, R W; Bauer, C; Blum, Walter; Brown, D; Dietl, H; Dydak, Friedrich; Ganis, G; Gotzhein, C; Jakobs, K; Kroha, H; Lütjens, G; Lutz, Gerhard; Männer, W; Moser, H G; Richter, R H; Rosado-Schlosser, A; Schael, S; Settles, Ronald; Seywerd, H C J; Stierlin, U; Saint-Denis, R; Wolf, G; Alemany, R; Boucrot, J; Callot, O; Cordier, A; Courault, F; Davier, M; Duflot, L; Grivaz, J F; Heusse, P; Jacquet, M; Kim, D W; Le Diberder, F R; Lefrançois, J; Lutz, A M; Musolino, G; Nikolic, I A; Park, H J; Park, I C; Schune, M H; Simion, S; Veillet, J J; Videau, I; Abbaneo, D; Azzurri, P; Bagliesi, G; Batignani, G; Bettarini, S; Bozzi, C; Calderini, G; Carpinelli, M; Ciocci, M A; Ciulli, V; Dell'Orso, R; Fantechi, R; Ferrante, I; Foà, L; Forti, F; Giassi, A; Giorgi, M A; Gregorio, A; Ligabue, F; Lusiani, A; Marrocchesi, P S; Messineo, A; Rizzo, G; Sanguinetti, G; Sciabà, A; Spagnolo, P; Steinberger, Jack; Tenchini, Roberto; Tonelli, G; Triggiani, G; Vannini, C; Verdini, P G; Walsh, J; Betteridge, A P; Blair, G A; Bryant, L M; Cerutti, F; Gao, Y; Green, M G; Johnson, D L; Medcalf, T; Mir, L M; Perrodo, P; Strong, J A; Bertin, V; Botterill, David R; Clifft, R W; Edgecock, T R; Haywood, S; Edwards, M; Maley, P; Norton, P R; Thompson, J C; Bloch-Devaux, B; Colas, P; Duarte, H; Emery, S; Kozanecki, Witold; Lançon, E; Lemaire, M C; Locci, E; Marx, B; Pérez, P; Rander, J; Renardy, J F; Rossowsky, A; Roussarie, A; Schuller, J P; Schwindling, J; Si Mohand, D; Trabelsi, A; Vallage, B; Johnson, R P; Kim, H Y; Litke, A M; McNeil, M A; Taylor, G; Beddall, A; Booth, C N; Boswell, R; Cartwright, S L; Combley, F; Dawson, I; Köksal, A; Letho, M; Newton, W M; Rankin, C; Thompson, L F; Böhrer, A; Brandt, S; Cowan, G D; Feigl, E; Grupen, Claus; Lutters, G; Minguet-Rodríguez, J A; Rivera, F; Saraiva, P; Smolik, L; Van Gemmeren, P; Apollonio, M; Bosisio, L; Della Marina, R; Giannini, G; Gobbo, B; Ragusa, F; Rothberg, J E; Wasserbaech, S R; Armstrong, S R; Bellantoni, L; Elmer, P; Feng, Z; Ferguson, D P S; Gao, Y S; González, S; Grahl, J; Harton, J L; Hayes, O J; Hu, H; McNamara, P A; Nachtman, J M; Orejudos, W; Pan, Y B; Saadi, Y; Schmitt, M; Scott, I J; Sharma, V; Turk, J; Walsh, A M; Wu Sau Lan; Wu, X; Yamartino, J M; Zheng, M; Zobernig, G
1996-01-01
A data sample of about 3.0 million hadronic Z decays collected by the ALEPH experiment at LEP in the years 1991 through 1994, is used to make an inclusive selection of B~hadron events. In this event sample 4227 \\pm 140 \\pm 252 B^* mesons in the decay B^* \\to B \\gamma and 1944 \\pm 108 \\pm 161 B^{**} mesons decaying into a B~meson and a charged pion are reconstructed. For the well established B^* meson the following quantities areobtained: \\Delta M = M_{B^*} - M_{B} = (45.30\\pm 0.35\\pm 0.87)~\\mathrm{MeV}/c^2 and N_{B^*}/(N_B+N_{B^*}) = (77.1 \\pm 2.6 \\pm 7.0)\\%. The angular distribution of the photons in the B^* rest frame is used to measure the relative contribution of longitudinal B^* polarization states to be \\sigma_L/(\\sigma_L + \\sigma_T)= (33 \\pm 6 \\pm 5)\\%. \\\\ Resonance structure in the M(B\\pi)-M(B) mass difference is observed at (424 \\pm 4 \\pm 10)~\\mathrm{MeV}/c^2. Its shape and position is in agreement with the expectation for B^{**}_{u,d} states decaying into B_{u,d}^{(*)} \\pi^\\pm. The signal is therefo...
Excited-state properties from ground-state DFT descriptors: A QSPR approach for dyes.
Fayet, Guillaume; Jacquemin, Denis; Wathelet, Valérie; Perpète, Eric A; Rotureau, Patricia; Adamo, Carlo
2010-02-26
This work presents a quantitative structure-property relationship (QSPR)-based approach allowing an accurate prediction of the excited-state properties of organic dyes (anthraquinones and azobenzenes) from ground-state molecular descriptors, obtained within the (conceptual) density functional theory (DFT) framework. The ab initio computation of the descriptors was achieved at several levels of theory, so that the influence of the basis set size as well as of the modeling of environmental effects could be statistically quantified. It turns out that, for the entire data set, a statistically-robust four-variable multiple linear regression based on PCM-PBE0/6-31G calculations delivers a R(adj)(2) of 0.93 associated to predictive errors allowing for rapid and efficient dye design. All the selected descriptors are independent of the dye's family, an advantage over previously designed QSPR schemes. On top of that, the obtained accuracy is comparable to the one of the today's reference methods while exceeding the one of hardness-based fittings. QSPR relationships specific to both families of dyes have also been built up. This work paves the way towards reliable and computationally affordable color design for organic dyes. Copyright 2009 Elsevier Inc. All rights reserved.
Excited-state dynamics of mononucleotides and DNA strands in a deep eutectic solvent.
Zhang, Yuyuan; de La Harpe, Kimberly; Hariharan, Mahesh; Kohler, Bern
2018-04-17
The photophysics of several mono- and oligonucleotides were investigated in a deep eutectic solvent for the first time. The solvent glyceline, prepared as a 1 : 2 mole ratio mixture of choline chloride and glycerol, was used to study excited-state deactivation in a non-aqueous solvent by the use of steady-state and time-resolved spectroscopy. DNA strands in glyceline retain the secondary structures that are present in aqueous solution to some degree, thus enabling a study of the effects of solvent properties on the excited states of stacked bases and stacked base pairs. The excited-state lifetime of the mononucleotide 5'-AMP in glyceline is 630 fs, or twice as long as in aqueous solution. Even slower relaxation is seen for 5'-TMP in glyceline, and a possible triplet state with a lifetime greater than 3 ns is observed. Circular dichroism spectra show that the single strand (dA)18 and the duplex d(AT)9·d(AT)9 adopt similar structures in glyceline and in aqueous solution. Despite having similar conformations in both solvents, femtosecond transient absorption experiments reveal striking changes in the dynamics. Excited-state decay and vibrational cooling generally take place more slowly in glyceline than in water. Additionally, the fraction of long-lived excited states in both oligonucleotide systems is lower in glyceline than in aqueous solution. For a DNA duplex, water is suggested to favor decay pathways involving intrastrand charge separation, while the deep eutectic solvent favors interstrand deactivation channels involving neutral species. Slower solvation dynamics in the viscous deep eutectic solvent may also play a role. These results demonstrate that the dynamics of excitations in stacked bases and stacked base pairs depend not only on conformation, but are also highly sensitive to the solvent.
Hubert, Mickaël; Olsen, Jeppe; Loras, Jessica; Fleig, Timo
2013-11-21
We present a new implementation of general excitation rank coupled cluster theory for electronically excited states based on the single-reference multi-reference formalism. The method may include active-space selected and/or general higher excitations by means of the general active space concept. It may employ molecular integrals over the four-component Lévy-Leblond Hamiltonian or the relativistic spin-orbit-free four-component Hamiltonian of Dyall. In an initial application to ground- and excited states of the scandium monohydride molecule we report spectroscopic constants using basis sets of up to quadruple-zeta quality and up to full iterative triple excitations in the cluster operators. Effects due to spin-orbit interaction are evaluated using two-component multi-reference configuration interaction for assessing the accuracy of the coupled cluster results.
Excitation of the (2p2)1D and (2s2p)1P autoionizing states of helium by 200 eV electron impact
International Nuclear Information System (INIS)
Godunov, A.L.; McGuire, J.H.; Schipakov, V.S.; Crowe, A.
2002-01-01
We report full second Born calculations with inclusion of post-collision interactions for excitation of the (2p 2 ) 1 D and (2s2p) 1 P autoionizing states of helium by 200 eV electron impact. The calculations are compared to (e, 2e) measurements of McDonald and Crowe (McDonald D G and Crowe A 1993 J. Phys. B: At. Mol. Opt. Phys. 26 2887-97) and Lower and Weigold (Lower J and Weigold E 1990 J. Phys. B: At. Mol. Opt. Phys. 23 2819-45). It is shown that post-collision interactions or Coulomb interactions in the final state between the scattered particle, the ejected electron and the recoil ion have a strong influence on both the direct ionization and resonance profiles around the binary lobe. The second-order terms in the amplitude of double electron excitation also play an observable role under these kinematic conditions. Reasonable agreement is found between the full-scale calculations and the experimental data. (author). Letter-to-the-editor
Bottom-up excited state dynamics of two cinnamate-based sunscreen filter molecules.
Peperstraete, Yoann; Staniforth, Michael; Baker, Lewis A; Rodrigues, Natércia D N; Cole-Filipiak, Neil C; Quan, Wen-Dong; Stavros, Vasilios G
2016-10-12
Methyl-E-4-methoxycinnamate (E-MMC) is a model chromophore of the commonly used commercial sunscreen agent, 2-ethylhexyl-E-4-methoxycinnamate (E-EHMC). In an effort to garner a molecular-level understanding of the photoprotection mechanisms in operation with E-EHMC, we have used time-resolved pump-probe spectroscopy to explore E-MMC's and E-EHMC's excited state dynamics upon UV-B photoexcitation to the S 1 (1 1 ππ*) state in both the gas- and solution-phase. In the gas-phase, our studies suggest that the excited state dynamics are driven by non-radiative decay from the 1 1 ππ* to the S 3 (1 1 nπ*) state, followed by de-excitation from the 1 1 nπ* to the ground electronic state (S 0 ). Using both a non-polar-aprotic solvent, cyclohexane, and a polar-protic solvent, methanol, we investigated E-MMC and E-EHMC's photochemistry in a more realistic, 'closer-to-shelf' environment. A stark change to the excited state dynamics in the gas-phase is observed in the solution-phase suggesting that the dynamics are now driven by efficient E/Z isomerisation from the initially photoexcited 1 1 ππ* state to S 0 .
Structural Influence on Excited State Dynamics in Simple Amines
DEFF Research Database (Denmark)
Klein, Liv Bærenholdt
experiments with calculations, provides new insight into the nature of the internal conversion processes that mediate the dynamical evolution between Rydberg states, and how structural variations in simple amine system have a large impact on the non-adiabatic processes. The experimental method of choice...... is femtosecond time-resolved photoelectron velocity map imaging (VMI), which is a newtechnique in the Copenhagen lab. The design, building and implementation of the VMI spectrometer has been a very substantial part of the thesis work. This techniques oers enhanced information content in the form of ecient...... and sensitive collection of photoelectron spectra. In particular, the angleresolved data available from the VMI approach provides highly detailed mechanistic insight about the relaxation pathways. One striking novel nding is that for tertiary amines, the critical factor driving the non-adiabatic dynamics...
Czech Academy of Sciences Publication Activity Database
Polívka, Tomáš; Kaligotla, S.; Chábera, P.; Frank, H.A.
2011-01-01
Roč. 13, č. 22 (2011), s. 1463-9076 ISSN 1463-9076 Institutional research plan: CEZ:AV0Z50510513 Keywords : carotenoid * retinal * excited-state dynamics * charge-transfer state Subject RIV: BO - Biophysics Impact factor: 3.573, year: 2011
Energy-Looping Nanoparticles: Harnessing Excited-State Absorption for Deep-Tissue Imaging.
Levy, Elizabeth S; Tajon, Cheryl A; Bischof, Thomas S; Iafrati, Jillian; Fernandez-Bravo, Angel; Garfield, David J; Chamanzar, Maysamreza; Maharbiz, Michel M; Sohal, Vikaas S; Schuck, P James; Cohen, Bruce E; Chan, Emory M
2016-09-27
Near infrared (NIR) microscopy enables noninvasive imaging in tissue, particularly in the NIR-II spectral range (1000-1400 nm) where attenuation due to tissue scattering and absorption is minimized. Lanthanide-doped upconverting nanocrystals are promising deep-tissue imaging probes due to their photostable emission in the visible and NIR, but these materials are not efficiently excited at NIR-II wavelengths due to the dearth of lanthanide ground-state absorption transitions in this window. Here, we develop a class of lanthanide-doped imaging probes that harness an energy-looping mechanism that facilitates excitation at NIR-II wavelengths, such as 1064 nm, that are resonant with excited-state absorption transitions but not ground-state absorption. Using computational methods and combinatorial screening, we have identified Tm(3+)-doped NaYF4 nanoparticles as efficient looping systems that emit at 800 nm under continuous-wave excitation at 1064 nm. Using this benign excitation with standard confocal microscopy, energy-looping nanoparticles (ELNPs) are imaged in cultured mammalian cells and through brain tissue without autofluorescence. The 1 mm imaging depths and 2 μm feature sizes are comparable to those demonstrated by state-of-the-art multiphoton techniques, illustrating that ELNPs are a promising class of NIR probes for high-fidelity visualization in cells and tissue.
Excitation of non-normal parity states by inelastic proton scattering
Energy Technology Data Exchange (ETDEWEB)
Emery, G. T. [Indiana Univ. (USA). Cyclotron Facility; Ikegami, Hidetsugu; Muraoka, Mitsuo [eds.; Osaka Univ., Suita (Japan). Research Center for Nuclear Physics
1980-01-01
This is a review of the works done at the Indiana University Cyclotron Facility. The purposes of works are to find excitations that should have especially simple particle-hole structure in proton inelastic scattering, to use the data on these excitations to try to understand the mechanism and the effective interaction for the (p, p') reaction in this energy range, and to go on to study the nuclear structure involved in less simple excitation. As an example, the single-nucleon level diagram for the region of Si-28 is presented. A high spin state was made, and its spin-parity was 6/sup -/. It was tried to interpret the data in terms of a on-step distorted-wave impulse approximation. The optical model parameters derived from the extensive and precise elastic scattering results were used. The cross sections for the excitation of the 6/sup -/ states found in various reactions were not large. The T = 1 state is mainly excited by the direct tensor interaction, while the T = 0 state gets its strength mainly from the knock-on exchange contribution of both the tensor and spin-orbit interactions. Experiments on Pb-208 and Fe-54 are being performed.
Di-lepton yield from the decay of excited 28Si states
International Nuclear Information System (INIS)
Bacelar, J.C.; Buda, A.; Balanda, A.; Krasznahorkay, A.; Ploeg, H. van der; Sujkowski, Z.; Woude, A. van der
1994-01-01
The first dilepton yield measurements from excited nuclear states obtained with a new Positron-Electron Pair Spectroscopic Instrument (PEPSI) are reported. Nuclear states in 28 Si, with an initial excitation energy E * =50 MeV, were populated via the isospin T=0 reaction 4 He+ 24 Mg and the mixed-isospin 3 He+ 25 Mg reaction. In both reactions the dilepton (e + e - ) and photon decay yields were measured concurrently. An excess of counts in the e + e - spectrum, over the converted photon yield, is observed in the energy region above 15 MeV. An analyses is discussed whereby the observed excess counts are assumed to represent the isoscalar E0 strength in excited nuclear states. (orig.)
International Nuclear Information System (INIS)
Giambiagi, M.S. de; Giambiagi, M.
1982-01-01
Direct PPP-type calculations of self-consistent (SC) density matrices for excited states are described and the corresponding 'thawn' molecular orbitals (MO) are discussed. Special attention is addressed to particular solutions arising in conjugated systems of a certain symmetry, and to their chemical implications. The U(2) and U(3) algebras are applied respectively to the 4-electron and 6-electron cases: a natural separation of excited states in different cases follows. A simple approach to the convergence problem for excited states is given. The complementarity relations, an alternative formulation of the pairing theorem valid for heteromolecules and non-alternant systems, allow some fruitful experimental applications. Together with the extended pairing relations shown here, they may help to rationalize general trends. (Author) [pt
Structure and Spectrum of Dust Coulomb Clusters
International Nuclear Information System (INIS)
Cheung, F.M.H.; Ford, C.; Barkby, S.; Samarian, A.A.; Vladimirov, S.V.
2005-01-01
In our study, the dynamics of Coulomb cluster systems were simulated for different number of particles. The spectra of energy states of dust Coulomb clusters corresponding to various packing sequences were obtained. The broadening of the spectrum due to inter-ring twist was discovered. It was found that the inter-ring twist will lead to a change in the energy spectrum of Coulomb cluster. This change was accompanied by a distortion of stable shells such that particles are able to compensate for any additional Coulomb energy (owing to the inter-ring twist) by further reducing their radial distance as much as possible. The overall effect is a change in the shape of the outer-shell from circular to elliptical
Partial radiative-recombination cross sections for excited states of hydrogen
International Nuclear Information System (INIS)
Fazio, P.M.; Copeland, G.E.
1985-01-01
The squares of the dipole and quadrupole matrix elements for the free-to-bound transitions of hydrogen up to bound states Vertical Barn = 20,l = 19> are derived in closed analytic form as a function of the kinetic energy of the free electron. Coulomb wave functions are used for the free as well as the bound states and, thus, the results are good for any electron energy. Several interesting effects are found. First, the transition probabilities are maximum for recombination into specific intermediate-angular-momentum states at low energies (w<1 eV) and where the free-state angular momentum is greater than that of the bound state. Further, that specific intermediate-angular-momentum state depends on the kinetic energy of the free electron. This behavior is in contrast to the ''normal'' behavior of the transition strengths where recombination into s states is greatest and decreases with increasing angular momentum. Second, the quadrupole matrix elements vanish for certain velocities of the free electron. These ''zeros'' produce minima in the corresponding quadrupole cross sections. Finally, the calculated partial cross sections for recombination into high-angular-momentum states are greater when quadrupole transitions are included
Pulsed radiation studies of carotenoid radicals and excited states
International Nuclear Information System (INIS)
Burke, M.
2001-04-01
The one-electron reduction potentials of the radical cations of five dietary carotenoids, in aqueous micellar environments, have been obtained from a pulse radiolysis study of electron transfer between the carotenoids and tryptophan radical cations as a function of pH, and lie in the range 980 to 1060 mV. The decays of the carotenoid radical cations suggest a distribution of exponential lifetimes. The radicals persist for up to about one second, depending on the medium and may re-orientate within a biological environment to react with other biomolecules, such as tyrosine, cysteine or ascorbic acid, which was indeed confirmed. Spectral information of carotenoid pigmented liposomes has been collected, subsequently pulse radiolysis was used to generate the radical cations of β-carotene, zeaxanthin and lutein, in unilamellar vesicles of dipalmitoyl phosphatidyl choline. The rate constants for the 'repair' of these carotenoid radical cations by water-soluble vitamin C were found to be similar (∼1 x 10 7 M -1 s -1 ) for β-carotene and zeaxanthin and somewhat lower (∼0.5 x 10 7 M -1 s -1 ) for lutein. The results are discussed in terms of the microenvironment of the carotenoids and suggest that for β-carotene, a hydrocarbon carotenoid, the radical cation is able to interact with a water-soluble species even though the parent hydrocarbon carotenoid is probably entirely in the non-polar region of the liposome. Studies investigating the ability of ingested lycopene to protect human lymphoid cells against singlet oxygen and nitrogen dioxide radical mediated cell damage have shown that a high lycopene diet is beneficial in protecting human cells against reactive oxygen species. Triplet states of carotenoids were produced in benzene solvent and their triplet lifetimes were found to depend on the concentration of the parent molecule. The rate constants obtained for ground state quenching correlate with the number of conjugated double bonds, the longer chain systems having
Zhu, Ruixue; Li, Ming-de; Du, Lili; Phillips, David Lee
2017-04-06
Photoinduced dehalogenation of the antifungal drug itraconazole (ITR) in acetonitrile (ACN) and ACN/water mixed solutions was investigated using femtosecond and nanosecond time-resolved transient absorption (fs-TA and ns-TA, respectively) and nanosecond time-resolved resonance Raman spectroscopy (ns-TR 3 ) experiments. An excited resonance energy transfer is found to take place from the 4-phenyl-4,5-dihydro-3H-1,2,4-triazol-3-one part of the molecule to the 1,3-dichlorobenzene part of the molecule when ITR is excited by ultraviolet light. This photoexcitation is followed by a fast carbon-halogen bond cleavage that leads to the generation of radical intermediates via either triplet and/or singlet excited states. It is found that the singlet excited state-mediated carbon-halogen cleavage is the predominant dehalogenation process in ACN solvent, whereas a triplet state-mediated carbon-halogen cleavage prefers to occur in the ACN/water mixed solutions. The singlet-to-triplet energy gap is decreased in the ACN/water mixed solvents and this helps facilitate an intersystem crossing process, and thus, the carbon-halogen bond cleavage happens mostly through an excited triplet state in the aqueous solutions examined. The ns-TA and ns-TR 3 results also provide some evidence that radical intermediates are generated through a homolytic carbon-halogen bond cleavage via predominantly the singlet excited state pathway in ACN but via mainly the triplet state pathway in the aqueous solutions. In strong acidic solutions, protonation at the oxygen and/or nitrogen atoms of the 1,2,4-triazole-3-one group appears to hinder the dehalogenation reactions. This may offer the possibility that the phototoxicity of ITR due to the generation of aryl or halogen radicals can be reduced by protonation of certain moieties in suitably designed ITR halogen-containing derivatives.
Describing excited state relaxation and localization in TiO2 nanoparticles using TD-DFT
International Nuclear Information System (INIS)
Berardo, Enrico; Hu, Han-Shi; Van Dam, Hubertus J. J.; Shevlin, Stephen A.; Woodley, Scott M.; Kowalski, Karol; Zwijnenburg, Martijn A.
2014-01-01
We have investigated the description of excited state relaxation in naked and hydrated TiO 2 nanoparticles using Time-Dependent Density Functional Theory (TD-DFT) with three common hybrid exchange-correlation (XC) potentials; B3LYP, CAM-B3LYP and BHLYP. Use of TD-CAM-B3LYP and TD-BHLYP yields qualitatively similar results for all structures, which are also consistent with predictions of coupled cluster theory for small particles. TD-B3LYP, in contrast, is found to make rather different predictions; including apparent conical intersections for certain particles that are not observed with TD-CAM-B3LYP nor with TD-BHLYP. In line with our previous observations for vertical excitations, the issue with TD-B3LYP appears to be the inherent tendency of TD-B3LYP, and other XC potentials with no or a low percentage of Hartree-Fock Like Exchange, to spuriously stabilize the energy of charge-transfer (CT) states. Even in the case of hydrated particles, for which vertical excitations are generally well described with all XC potentials, the use of TD-B3LYP appears to result in CT-problems for certain particles. We hypothesize that the spurious stabilization of CT-states by TD-B3LYP even may drive the excited state optimizations to different excited state geometries than those obtained using TD-CAM-B3LYP or TD-BHLYP. In conclusion, focusing on the TD-CAM-B3LYP and TD-BHLYP results, excited state relaxation in naked and hydrated TiO 2 nanoparticles is predicted to be associated with a large Stokes' shift