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Sample records for spiro pyran ring

  1. Temperature dependence of (+)-catechin pyran ring proton coupling constants as measured by NMR and modeled using GMMX search methodology

    Science.gov (United States)

    Fred L. Tobiason; Stephen S. Kelley; M. Mark Midland; Richard W. Hemingway

    1997-01-01

    The pyran ring proton coupling constants for (+)-catechin have been experimentally determined in deuterated methanol over a temperature range of 213 K to 313 K. The experimental coupling constants were simulated to 0.04 Hz on the average at a 90 percent confidence limit using a LAOCOON method. The temperature dependence of the coupling constants was reproduced from the...

  2. Spiro annulation of cage polycycles via Grignard reaction and ring-closing metathesis as key steps

    Directory of Open Access Journals (Sweden)

    Sambasivarao Kotha

    2015-08-01

    Full Text Available A simple synthetic strategy to C2-symmetric bis-spiro-pyrano cage compound 7 involving ring-closing metathesis is reported. The hexacyclic dione 10 was prepared from simple and readily available starting materials such as 1,4-naphthoquinone and cyclopentadiene. The synthesis of an unprecedented octacyclic cage compound through intramolecular Diels–Alder (DA reaction as a key step is described. The structures of three new cage compounds 7, 12 and 18 were confirmed by single crystal X-ray diffraction studies.

  3. Transformation of Zwitterionic Pyridine Derivatives to a Spiro-Fused Ring System: Azoniabenzo[de]fluorine. Synthesis and Mechanistic Rationalization.

    Science.gov (United States)

    Palkó, Roberta; Egyed, Orsolya; Rokob, Tibor András; Bombicz, Petra; Riedl, Zsuzsanna; Hajós, György

    2015-01-02

    Reaction of aryl- and benzylsulfanopyridinium amidates bearing a methyl group in position 6 with 2 equiv of diphenylketene afforded a spiro-fused ring system: azoniabenzo[de]fluorine. By use of an excess amount of ketene, a distinct reaction was observed via which a 1H-pyrrolo[3,2-b]pyridin-2(3H)-one derivative was furnished. The structure of the tetracyclic spiro-fused ring system was unambiguously confirmed by X-ray diffraction, and its formation was rationalized by DFT calculations.

  4. New regioselective multicomponent reaction: one pot synthesis of spiro heterobicyclic aliphatic rings.

    Science.gov (United States)

    Byk, G; Gottlieb, H E; Herscovici, J; Mirkin, F

    2000-01-01

    In the context of our high-throughput organic synthesis program, we have studied the reactivity of special beta-keto esters toward the Biginelli reaction. We have found that a cyclic beta-keto ester reacts with one molecule of urea and two molecules of aldehyde to give a new family of spiro heterobicyclic aliphatic rings in good yields. Interestingly, the Biginelli product was not detected. After analysis of products using HPLC, 1H NMR, and 13C NMR, we have found that the reaction is driven by a regio-specific condensation of two molecules of aldehyde with the other reagents to afford only products harboring substituents exclusively in cis configuration. Monte Carlo minimization studies using MM2 force field suggest that cis products are energetically more stable than the trans counterparts. Together with previously reported data, these results suggest that the trans products were not obtained as result of steric hindrance produced by the equatorial position of one of the ring substituents. This new reaction is useful for high-throughput organic synthesis. Indeed, the new scaffold can be used to introduce additional groups in the molecules through remaining functional groups by a "domino strategy".

  5. pyran Derivatives

    African Journals Online (AJOL)

    NICO

    Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad, (MS) – 431 004, India. Received 20 August 2010, revised ... synthesis of tetrahydrobenzo[b]pyran under mild reaction conditions. In continuation of .... successful under environmental benign conditions. 4. Experimental. All chemicals ...

  6. Anomalous regioselective four-member multicomponent Biginelli reaction II: one-pot parallel synthesis of spiro heterobicyclic aliphatic rings.

    Science.gov (United States)

    Byk, Gerardo; Kabha, Eihab

    2004-01-01

    In a previous preliminary study, we found that a cyclic five-member ring beta-keto ester (lactone) reacts with one molecule of urea and two of aldehyde to give a new family of spiro heterobicyclic aliphatic rings in good yields with no traces of the expected dihydropyrimidine (Biginelli) products. The reaction is driven by a regiospecific condensation of two molecules of aldehyde with urea and beta-keto-gamma-lactone to afford only products harboring substitutions exclusively in a syn configuration (Byk, G.; Gottlieb, H. E.; Herscovici, J.; Mirkin, F. J. Comb. Chem. 2000, 2, 732-735). In the present work ((a) Presented in part at ISCT Combitech, October 15, 2002, Israel, and Eurocombi-2, Copenhagen 2003 (oral and poster presentation). (b) Also in American Peptide Society Symposium, Boston, 2003 (poster presentation). (c) Abstract in Biopolymers 2003, 71 (3), 354-355), we report a large and exciting extension of this new reaction utilizing parallel organic synthesis arrays, as demonstrated by the use of chiral beta-keto-gamma-lactams, derived from natural amino acids, instead of tetronic acid (beta-keto-gamma-lactone) and the potential of the spirobicyclic products for generating "libraries from libraries". Interestingly, we note an unusual and important anisotropy effect induced by perpendicular interactions between rigid pi systems and different groups placed at the alpha position of the obtained spirobicyclic system. Stereo/regioselectivity of the aldehyde condensation is driven by the nature of the substitutions on the starting beta-keto-gamma-lactam. Aromatic aldehydes can be used as starting reagents with good yields; however, when aliphatic aldehydes are used, the desired products are obtained in poor yields, as observed in the classical Biginelli reaction. The possible reasons for these poor yields are addressed and clarify, to some extent, the complexity of the Biginelli multicomponent reaction mechanism and, in particular, the mechanism of the present

  7. Hybrid macrocycle formation and spiro annulation on cis-syn-cis-tricyclo[6.3.0.02,6]undeca-3,11-dione and its congeners via ring-closing metathesis

    Directory of Open Access Journals (Sweden)

    Sambasivarao Kotha

    2015-07-01

    Full Text Available We have developed a simple methodology to transform cis-syn-cis-triquinane derivative 2 into the diindole based macrocycle 6 involving Fischer indolization and ring-closing metathesis (RCM. Various spiro-polyquinane derivatives have been assembled via RCM as a key step.

  8. Spiro Meroterpenoids from Ganoderma applanatum.

    Science.gov (United States)

    Luo, Qi; Wei, Xiao-Yi; Yang, Jing; Luo, Jin-Feng; Liang, Rui; Tu, Zheng-Chao; Cheng, Yong-Xian

    2017-01-27

    Spiroapplanatumines A-Q (1-12, 14-16, 18, and 20), new spiro meroterpenoids respectively bearing a 6/5/7 or 6/5/5 ring system, along with three known compounds, spirolingzhines A, B, and D, were isolated from the fruiting bodies of the fungus Ganoderma applanatum. Their structures including absolute configurations were assigned by using spectroscopic methods, ECD and 13 C NMR calculations, and single-crystal X-ray diffraction analysis. Biological evaluation of all the compounds disclosed that compounds 7 and 8 inhibited JAK3 kinase with IC 50 values of 7.0 ± 3.2 and 34.8 ± 21.1 μM, respectively.

  9. (R,S-2′-Amino-6′-methyl-2,5′,5′-trioxo-6′H-spiro[indoline-3,4′-pyrano[3,2-c][2,1]benzothiazine]-3′-carbonitrile dimethylformamide monosolvate

    Directory of Open Access Journals (Sweden)

    Svitlana V. Shishkina

    2014-07-01

    Full Text Available The title solvate, C20H14N4O4S·C3H7NO, comprises a stereogenic centre but the centrosymmetric space group causes the presence of the racemate in the crystal. The spiro-joined fragments are almost orthogonal, with a dihedral angle of 86.8 (2° between the mean planes of the pyrane ring and the dihydroindolone ring system. The atoms of the indolinone bicycle are coplanar, with an r.m.s. deviation of 0.005 Å. In the crystal, pairs of N—H...O hydrogen bonds link the molecules into centrosymmetric dimers which are linked to the dimethylformamide solvent molecules by further N—H...O hydrogen bonds. N—H...N hydrogen bonds link neighbouring dimers into [010] chains.

  10. Crystal structure of di-bromo-meth-oxy-seselin (DBMS), a photobiologically active pyran-ocoumarin.

    Science.gov (United States)

    Bauri, A K; Foro, Sabine; Rahman, A F M M

    2017-05-01

    The title compound, C 15 H 14 Br 2 O 4 [systematic name: rac -(9 S ,10 R )-3,9-dibromo-10-methoxy-8,8-dimethyl-9,10-dihydropyrano[2,3- h ]chromen-2(8 H )-one], is a pyran-ocoumarin derivative formed by the bromination of seselin, which is a naturally occurring angular pyran-ocoumarin isolated from the Indian herb Trachyspermum stictocarpum . In the mol-ecule, the benzo-pyran ring system is essentially planar, with a maximum deviation of 0.044 (2) Å for the O atom. The di-hydro-pyran ring is in a half-chair conformation and the four essentially planar atoms of this ring form a dihedral angle of 4.6 (2)° with the benzo-pyran ring system. In the crystal, mol-ecules are linked by weak C-H⋯O hydrogen bonds, forming chains propagating along [010]. In addition, π-π stacking inter-actions, with centroid-centroid distances of 3.902 (2) and 3.908 (2) Å, link the hydrogen-bonded chains into layers parallel to (001).

  11. Simple synthesis of polyfunctionalized indoline-spiro fused pyran derivatives via an aqueous multicomponent reaction

    International Nuclear Information System (INIS)

    Dolati, H.; Habibi, A.; Ayatollahi, S.A.M.

    2016-01-01

    The one-pot multicomponent reaction of malononitrile/ethyl cyanoacetate, 1, 3-dicarbonyl compounds, and 1, 2-dicarbonyl moiety (ninhydrin/isatin or acenaphthenequinone) in water and in the attendance of DABCO (1, 4-diazabicyclo (2.2.2) octane) as catalyst to afford related spiropyran derivatives with excellent yields. This environmental friendliness reaction which can be carried out under mild conditions has easy work-up and covers a great range of spiropyran products. (author)

  12. Synthesis of Polyfunctionalized 4H-Pyrans

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    Manisha Bihani

    2013-01-01

    Full Text Available Amberlyst A21 catalyzed one-pot three-component coupling of aldehyde and malononitrile with active methylene compounds such as acetylacetone and ethyl acetoacetate for the synthesis of pharmaceutically important polyfunctionalized 4H-pyrans has been reported. Simple experimental procedure, no chromatographic purification, no hazardous organic solvents, easy recovery and reusability of the catalyst, and room temperature reaction conditions are some of the highlights of this protocol for the synthesis of pharmaceutically relevant focused libraries.

  13. (E-4-Hydroxy-6-methyl-3-[1-(2-phenylhydrazinylideneethyl]-2H-pyran-2-one

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    Samra Rahmouni

    2016-05-01

    Full Text Available The title compound, C14H14N2O3, crystallized with three crystallographically independent molecules (A, B and C in the asymmetric unit. The three molecules each have an E conformation about the C=N bond but differ in the orientation of the phenyl and pyran rings. The dihedral angles between the phenyl and pyran ring planes are 14.30 (1, 28.38 (1 and 25.58 (1° in molecules A, B and C, respectively. There is an intramolecular O—H...N hydrogen bond in each molecule with an S(6 ring motif. In the crystal, molecules are linked by N—H...O and C—H...O hydrogen bonds, forming layers parallel to (001, enclosing R22(8 and R33(21 ring motifs. The layers are linked via C—H...π interactions, forming bilayers, which are joined by a further C—H...π interaction, forming a three-dimensional structure.

  14. Synthesis of novel spiro-β-lactams

    Indian Academy of Sciences (India)

    Administrator

    the amyloid precursor protein responsible for the pathogenesis of Alzheimer's disease has also been shown to be coupled with cholesterol regulation. 4. Structure-activity studies have identified 3-spiro-β- lactams SCH 54016 A and SCH 58053 B as most potent cholesterol absorption inhibitors. 5. Several approaches for the ...

  15. Ethyl 2,2-dimethyl-4-oxo-6-phenyl-3,4-dihydro-2H-pyran-5-carboxylate

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    N. Sharmila

    2016-12-01

    Full Text Available The title compound, C16H18O4, is a derivative of 3,4-dihydro-2H-pyran-4-one. The plane of the pyranone ring system forms a dihedral angle of 42.76 (10° with that of the phenyl group. The crystal structure is stabilized by C—H...O interactions that enclose an R21(6 ring motif and link the molecules into chains along the c axis. A short intramolecular O...O contact [2.942 (3 Å] gives rise to an S(5 motif.

  16. Structure and stability of spiro-cyclic water clusters

    Indian Academy of Sciences (India)

    Administrator

    donates two protons, resulting in an overall stabili- zation of the spiro-cyclic structure. A close scrutiny. Figure 1. Optimized geometries of different spiro- cyclic water clusters obtained using HF/6-311++G** cal- culation. These clusters are found to be stable without any reorganization during energy minimization at DFT.

  17. Structure and stability of spiro-cyclic water clusters

    Indian Academy of Sciences (India)

    Administrator

    Abstract. The structure and stability of spiro-cyclic water clusters containing up to 32 water molecules have been investigated at different levels of theory. Although there exist minima lower in energy than these spiro-cyclic clusters, calculations at the Hartree–Fock level, density functional theory using B3LYP parametrization ...

  18. Synthesis of spiro [indolo-1, 5-benzodiazepines] from 3-acetyl ...

    Indian Academy of Sciences (India)

    3'-hydroxy-2'-oxo indolo) acetyl coumarins (3), which on dehydration afforded the corresponding ,-unsaturated ketones (4). Cyclocondensation of (4) with substituted -phenylene diamines resulted in novel 3-coumarinyl spiro[indolo-1 ...

  19. Ethyl 6-(4-chlorophenyl-2,2-dimethyl-4-oxo-3,4-dihydro-2H-pyran-5-carboxylate

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    N. Sharmila

    2017-01-01

    Full Text Available The title compound, C16H17ClO4, is a derivative of 3,4-dihydro-2H-pyran-4-one in which the root moiety forms a dihedral angle of 49.36 (5° with the pendent chlorobenzene ring. The crystal structure features weak methyl-C—H...O(ring carbonyl contacts, leading to an R22(12 ring motif, and benzene-C—H...O(ester interactions, leading to a supramolecular chain along the b axis, to form a three-dimensional network.

  20. Photochemical synthesis of benzoyl spiro[2.2]pentanes.

    Science.gov (United States)

    Muehling, Olaf; Wessig, Pablo

    2006-11-01

    In the present study, we describe the photochemical behaviour of 2-mesyloxy phenyl ketones 8 and 12 bearing a cyclopropane moiety in the side-chain. Irradiation of 8 and 12 leads to the corresponding benzoyl spiro[2.2]pentanes as a consequence of an initial gamma-H-shift, subsequent elimination of MsOH (accompanied by a spin-center shift) and cyclization of the resulting 1,3-diradicals. In contrast, a corresponding phenyl ketone without a mesyloxy group in the 2-position, and thus a potential reactant of the "classical" Norrish-Yang reaction, shows no photochemical reaction. By means of quantum chemical calculations we discovered that in the presence of a mesyloxy group the activation barrier for the photochemical gamma-H-shift is substantially decreased. Furthermore, a photoinduced skeletal rearrangement of benzoyl spiro[2.2]pentane to 2-cyclobutylidene-acetophenone could be observed. Compared to the common methods used to synthesize spiro[2.2]pentanes, the photochemical preparation of benzoyl spiro[2.2]pentane presented herein is the first example where a bond between the spiro atom and an adjacent atom is formed.

  1. Chemistry of Pyrones, Part 3: New Podands of 4H-Pyran-4-ones

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    Aziz Shahrisa

    2000-03-01

    Full Text Available New derivatives of 3,5-disubstituted 4H-Pyran-4-one podands (9-15 were prepared by transesterification reaction of dimethyl or diethyl 2,6-dimethyl-4H-pyran-4-one-3,5-dicarboxylate with some glycol, glycol ethers or by nucleophilic substitution of some phenols or glycol ethers with 3,5-bis (bromomethyl-2,6-diphenyl-4H-pyran-4-one.

  2. A 26-Membered Macrocycle Obtained by a Double Diels-Alder Cycloaddition Between Two 2H-Pyran-2-one Rings and Two 1,1'-(Hexane-1,6-diyl)bis (1H-pyrrole-2,5-dione)s.

    Science.gov (United States)

    Turek, Bor Lucijan; Kočevar, Marijan; Kranjc, Krištof; Perdih, Franc

    2017-12-01

    With the application of a double dienophile 1,1'-(hexane-1,6-diyl)bis(1H-pyrrole-2,5-dione) for a [4+2] cycloaddition with a substituted 2H-pyran-2-one a novel 26-membered tetraaza heteromacrocyclic system 3 was prepared via a direct method under solvent-free conditions with microwave irradiation. The macrocycle prepared is composed of two units of the dienophile and two of the diene. The structure of the macrocycle was characterized on the basis of IR, 1H and 13C NMR and mass spectroscopy, as well as by the elemental analysis and melting point determination. With X-ray diffraction of a single crystal of the macrocycle we have determined that the two acetyl groups (attached to the bridging double bond of the bicyclo[2.2.2]octene fragments) are oriented towards each other (and also towards the inside of the cavity of the macrocycle), therefore, mostly filling it completely.

  3. Fragrance material review on 1-spiro[4.5]dec-7-en-7-yl-4-pent-1-one.

    Science.gov (United States)

    Scognamiglio, J; Letizia, C S; Api, A M

    2013-12-01

    A toxicologic and dermatologic review of 1-spiro[4.5]dec-7-en-7-yl-4-pent-1-one when used as a fragrance ingredient is presented. 1-Spiro[4.5]dec-7-en-7-yl-4-pent-1-one is a member of the fragrance structural group Alkyl Cyclic Ketones. These fragrances can be described as being composed of an alkyl, R1, and various substituted and bicyclic saturated or unsaturated cyclic hydrocarbons, R2, in which one of the rings may include up to 12 carbons. Alternatively, R2 may be a carbon bridge of C2-C4 carbon chain length between the ketone and cyclic hydrocarbon. This review contains a detailed summary of all published and unpublished toxicology and dermatology papers that are related to this individual fragrance ingredient and is not intended as a stand-alone document. Available data for 1-spiro[4.5]dec-7-en-7-yl-4-pent-1-one were evaluated then summarized and includes acute toxicity, skin irritation, mucous membrane (eye) irritation, skin sensitization, phototoxicity, photoallergy, repeated dose, and genotoxicity data. A safety assessment of the entire Alkyl Cyclic Ketones will be published simultaneously with this document; please refer to Belsito et al. (2013) for an overall assessment of the safe use of this material and all Alkyl Cyclic Ketones in fragrances. Copyright © 2013 Elsevier Ltd. All rights reserved.

  4. Magnetic iron oxide/phenylsulfonic acid: A novel, efficient and recoverable nanocatalyst for green synthesis of tetrahydrobenzo[b]pyrans under ultrasonic conditions.

    Science.gov (United States)

    Elhamifar, Dawood; Ramazani, Zahra; Norouzi, Meysam; Mirbagheri, Reza

    2018-02-01

    A novel magnetic iron oxide supported phenylsulfonic acid (Fe 3 O 4 @Ph-SO 3 H) with core-shell structure is prepared, characterized and applied as efficient nanocatalyst for green synthesis of tetrahydrobenzo[b]pyrans. The Fe 3 O 4 @Ph-SO 3 H was prepared via modification of magnetic iron oxide cores with 1,4-bis(triethoxysilyl)benzene (BTEB) followed by sulfonation of aromatic rings. The Fe 3 O 4 @Ph-SO 3 H was characterized using FTIR, TGA, PXRD, SEM, TEM, VSM and EDX techniques. This was effectively applied for synthesis of tetrahydrobenzo[b]pyrans in water as green solvent at room temperature under ultrasonic conditions. The products were obtained in high to excellent yields at short times. The recoverability, reusability and durability of this nanocatalyst were studied under applied reaction conditions. Copyright © 2017 Elsevier Inc. All rights reserved.

  5. New Aliphatic Esters and Pyran Derivatives isolated from stem bark of Dalbergia Sissoo Roxb

    International Nuclear Information System (INIS)

    Trag, A. R.; Siddiqui, T. O.; Mahmooduzzafar; Iqbal, M.; Ali, M.

    2005-01-01

    Phytochemical investigation of the ethanolic extract of the stem bark of Dalbergia Sissoo led to the isolation of two new aliphatic esters and two new pyran derivatives and their structures have been elucidated as n-hexacosan-5-ol-1-yl propionate, n-tetracosan-5-ol-yl propionate, 7-hydroxy-8-methoxy-4-(2'-hydroxyphenyl1)-[4H]-benzopyran (dalbergyl pyran) and 10, 12, 13-trihydroxy-11-methoxyanthracenyl-15-18[2H]pyran(anthracenyl pyran) on the basis of spectral data analyses and chemical reactions. (author)

  6. Ethyl (E)-2-(2,7-dimethyl-5-oxo-4H,5H-pyrano[4,3-b]pyran-4-ylidene)acetate

    OpenAIRE

    Oulemda Bassou; Hakima Chicha; Latifa Bouissane; El Mostapha Rakib; Mohamed Saadi; Lahcen El Ammari

    2017-01-01

    In the title compound, C14H14O5, the two heterocyclic rings are coplanar (r.m.s. deviation = 0.008 Å), with the largest deviation from the mean plane being 0.012 (1) Å. The mean plane through the acetate group is inclined slightly with respect to the oxopyrano[4,3-b]pyran-4-yl system, as indicated by the dihedral angle of 1.70 (7)° between them. Two intramolecular hydrogen bonds, completing S(6) ring motifs, are observed in the molecule. In the crystal, molecules are linked by weak C—H...O hy...

  7. [Chemical and pharmacological research on pyran derivatives. VI. 2-Dialkylamino-4-oxo-4H-naphto/1,2-b/pyrans and derivatives].

    Science.gov (United States)

    Ermili, A; Balbi, A; Roma, G

    1976-09-01

    The 2-dialkylamino-4-oxo-4H-naphtho [1,2-b]pyrans are obtained by the reaction of N,N-dialkylethoxycarbonylacetamides with alpha-naphthol and with substituted alpha-naphthols. The products on treatment with formaldehyde and morpholine or piperidine or N-methylpiperazine are transformed into the 2-dialkylamino-3-dialkylaminomethyl-4-oxo-4H-naphtho [1,2-b]pyrans. Pharmacological investigation has shown that 2-dimethylamino (K 12164), 2-(N-ethyl, N-methyl)amino- (K 12087) and 2-diethylamino-4-oxox-4H-naphtho [1,2-b]pyran (K 12165) show clear neurotropic activity of the neuroleptic type whereas compounds of the isomeric series, 1H-naphtho-[2,1-b]pyrans, studied previously (1), show anticonvulsive and sedative activity. This difference in pharmacological activity has prompted a more complete comparative examination of the activity of the two series of compounds. Study of antagonism to the effects of reserpine by both 4H-naphtho [1,2-b]pyrans and 1H-naphtho [2,1-b]pyrans has shown that in the latter series the 1-oxo-3-dimethylamino- (K 8291), the 1-oxo-3-(N-ethyl, N-methyl)amino- (K 8409) and the 1-oxo-3-diethylamino-1H-naphtho [2,1-b]-pyran (K 8292) have marked neurotropic activity of the antidepressive type.

  8. Crystal structure of a photobiologically active brominated angular pyran-ocoumarin: bromo-hy-droxy-seselin.

    Science.gov (United States)

    Bauri, A K; Foro, Sabine; Rahman, A F M Mustafizur

    2017-03-01

    The title compound, C 14 H 13 BrO 3 [systematic name: rac -(9 S ,10 R )-9-bromo-10-hy-droxy-8,8-dimethyl-9,10-di-hydro-2 H ,8 H -pyrano[2,3- f ]chromen-2-one], is a substituted pyran-ocoumarin, obtained by bromination of seselin [8,8-dimethyl-2 H ,8 H -pyrano[2,3- f ]chromen-2-one], which was isolated from the Indian herb Trachyspermum stictocarpum (Aajmod). The pyrano ring has a distorted half-chair conformation and its mean plane is inclined to the coumarin mean plane by 1.6 (2)°. In the crystal, mol-ecules are linked by pairs of O-H⋯O hydrogen bonds, forming inversion dimers with an R 2 2 (16) ring motif. The dimers stack along the a -axis direction and are linked by offset π-π inter-actions, forming columns [inter-centroid distance = 3.514 (4) Å].

  9. New spiro (thio) barbiturates based on cyclohexanone and bicyclo ...

    African Journals Online (AJOL)

    diaryl-1'H-spiro[bicyclo[3.3.1]nonane-3,5'-pyrimidine]-2',4',6',9(3'H)-tetraone, respectively in good yield. Structure elucidation is carried out by 1H NMR, 13C NMR, FT-IR, UV-Visible, mass spectroscopy and X-ray crystallography techniques.

  10. new spiro (thio) barbiturates based on cyclohexanone and bicyclo

    African Journals Online (AJOL)

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    condensation can be operated with the aid of strong acids or bases [2, 13]. Several catalytic methods have been achieved for crossed-aldol condensation [4, 14-31]. Several spiro-(thio)barbituric acid derivatives in which the active methylene carbon of. (thio)barbituric acid is substituted by an unsubstituted cyclobutane or ...

  11. 5′-Methylsulfanyl-4′-oxo-7′-phenyl-3′,4′-dihydro-1′H-spiro[cyclohexane-1,2′-quinazoline]-8′-carbonitrile dimethylformamide monosolvate

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    Xuan Liu

    2011-08-01

    Full Text Available In the title compound, C21H21N3OS·C3H7NO, the carbonitrile molecule is built up of two fused six-membered rings and one six-membered ring linked through a spiro C atom. The 1,3-diaza ring adopts an envelope conformation and the cyclohexane ring adopts a chair conformation. The dihedral angle between the aromatic rings is 46.7 (3°. In the crystal, the components are linked by N—H...O hydrogen bonds.

  12. Ethyl (E-2-(2,7-dimethyl-5-oxo-4H,5H-pyrano[4,3-b]pyran-4-ylideneacetate

    Directory of Open Access Journals (Sweden)

    Oulemda Bassou

    2017-02-01

    Full Text Available In the title compound, C14H14O5, the two heterocyclic rings are coplanar (r.m.s. deviation = 0.008 Å, with the largest deviation from the mean plane being 0.012 (1 Å. The mean plane through the acetate group is inclined slightly with respect to the oxopyrano[4,3-b]pyran-4-yl system, as indicated by the dihedral angle of 1.70 (7° between them. Two intramolecular hydrogen bonds, completing S(6 ring motifs, are observed in the molecule. In the crystal, molecules are linked by weak C—H...O hydrogen bonds involving the same acceptor atom, forming chains propagating along the c-axis direction and enclosing R21(6 ring motifs. The chains are linked via offset π–π interactions [intercentroid distance = 3.622 (1 Å], involving inversion-related oxopyrano[4,3-b]pyran-4-yl ring systems, forming slabs parallel to the bc plane.

  13. The tert-Amino Effect in Heterocyclic Chemistry. Synthesis of Spiro Heterocycles

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    Y. Morzherin

    2005-09-01

    Full Text Available The tert-amino reaction effect was examined. A new method to synthesize spiro heterocycles is presented. It was shown that the “tert-amino effect” could be applied to the formation of spiro-fused heterocycles. The formation of spiro compounds proceeds in most cases in good yields in a one-pot reaction.

  14. Crystal structure of 3,4′-diphenyl-3′-p-tolyl-4′H-spiro[indan-2,5′-[1,2]oxazol]-1-one

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    Asmae Mahfoud

    2015-11-01

    Full Text Available In the title compound, C30H23NO2, the five-membered rings are both in envelope conformations with the same spiro C atom as the flap. The benzene ring and the two phenyl rings are inclined to the mean plane of the indene ring system by 83.98 (8, 81.46 (8 and 72.31 (7°. In the crystal, molecules are linked by pairs of C—H...O hydrogen bonds into inversion dimers. The dimers are further connected by C—H...N interactions, forming layers parallel to (10-1.

  15. Spiro K. Antiochos Receives 2013 John Adam Fleming Medal: Citation

    Science.gov (United States)

    Klimchuk, James A.

    2014-01-01

    The John Adam Fleming Medal is awarded for "original research and technical leadership in geomagnetism, atmospheric electricity, aeronomy, space physics, and related sciences." Originality and technical leadership are exactly the characteristics that distinguish the research of Spiro K. Antiochos. Spiro possesses a truly unique combination of physical insight, creativity, and mastery of the concepts and mathematical and numerical tools of space physics. These talents have allowed him to develop completely original theories for major observational problems and to test and refine those theories using sophisticated numerical simulation codes that he himself helped to develop. Spiro's physical insight is especially impressive. He has an uncanny ability to identify the fundamental aspects of complex problems and to see physical connections where others do not. This can sometimes involve ideas that may initially seem counterintuitive to those with less creativity. Many of Spiro's revolutionary advances have opened up whole new areas of study and shaped the course of space physics. Examples include the breakout model for coronal mass ejections (CMEs), the S-web model for the slow solar wind, and the thermal nonequilibrium model for solar prominences. The breakout model is of special significance to AGU as it strives to promote science for the betterment of humanity. CMEs are enormous explosions on the Sun that can have major "space weather" impacts here on Earth. They affect technologies ranging from communication and navigation systems to electrical power grids. Breakout is the leading theory for why CMEs occur and may one day be the foundation for more accurate space weather forecasting.

  16. Crystal structure of 2-amino-3-cyano-4-(4-methoxyphenyl-4H-1-benzothieno[3,2-b]pyran

    Directory of Open Access Journals (Sweden)

    Mohamed Bakhouch

    2015-12-01

    Full Text Available The three fused five- and six-membered rings in the title compound, C19H14N2O2S, are virtually coplanar, with the maximum deviation from the mean plane being 0.060 (1 Å. This benzothieno[3,2-b]pyran ring system is nearly perpendicular to the plane of the 4-methoxyphenyl ring, forming a dihedral angle of 83.65 (5°. In the crystal, molecules are linked by pairs of N—H...N hydrogen bonds into inversion dimers. The dimeric units are further connected by an N—H...O hydrogen bond into a tape running along the b axis. The tapes are linked together by C—H...N and π–π interactions [centroid–centroid distance = 3.7743 (8 Å], forming a three-dimensional network.

  17. Androgenic-anabolic activities of some new synthesized steroidal pyrane, pyridine and thiopyrimidine derivatives.

    Science.gov (United States)

    Abdalla, Mohamed M; Amr, Abd El-Galil E; Al-Omar, Mohamed A; Hussain, Azza A; Amer, Mohamed S

    2014-01-01

    In continuation of our previous work, fused steroidal derivatives with pyrane, pyridine, pyrimidine moieties were synthesized and evaluated as androgenic-anabolic agents. Some of the newly synthesized compounds are exhibited pronounced androgenic-anabolic activities.

  18. Ionic liquid-mediated three-component synthesis of fluorinated spiro ...

    Indian Academy of Sciences (India)

    Abstract. A simple, green and catalyst-free novel protocol is developed for the synthesis of medici- nally important spiro[indole-3,2 [1,3]-thiazine]-2,4 -dione and spiro[acenaphthylene-1,2 -[1,3]thiazine]dione libraries by the tandem reaction of readily available reagents in 1-butyl-3-methylimidazolium hexafluorophos-.

  19. New insights into canted spiro carbon interstitial in graphite

    Science.gov (United States)

    EL-Barbary, A. A.

    2017-12-01

    The self-interstitial carbon is the key to radiation damage in graphite moderator nuclear reactor, so an understanding of its behavior is essential for plant safety and maximized reactor lifetime. The density functional theory is applied on four different graphite unit cells, starting from of 64 carbon atoms up to 256 carbon atoms, using AIMPRO code to obtain the energetic, athermal and mechanical properties of carbon interstitial in graphite. This study presents first principles calculations of the energy of formation that prove its high barrier to athermal diffusion (1.1 eV) and the consequent large critical shear stress (39 eV-50 eV) necessary to shear graphite planes in its presence. Also, for the first time, the gamma surface of graphite in two dimensions is calculated and found to yield the critical shear stress for perfect graphite. Finally, in contrast to the extensive literature describing the interstitial of carbon in graphite as spiro interstitial, in this work the ground state of interstitial carbon is found to be canted spiro interstitial.

  20. Synthesis, characterization, photophysics and electroluminescence based on a series of pyran-containing emitters

    Energy Technology Data Exchange (ETDEWEB)

    Yang Lifen [State Key Laboratory of Rare Earth Materials Chemistry and Applications, Peking University, Beijing 100871 (China); Guan Min [State Key Laboratory of Rare Earth Materials Chemistry and Applications, Peking University, Beijing 100871 (China); Bian Zuqiang [State Key Laboratory of Rare Earth Materials Chemistry and Applications, Peking University, Beijing 100871 (China)]. E-mail: bianzq@pku.edu.cn; Xie Junqi [State Key Laboratory of Rare Earth Materials Chemistry and Applications, Peking University, Beijing 100871 (China); Chen Tianpeng [State Key Laboratory of Rare Earth Materials Chemistry and Applications, Peking University, Beijing 100871 (China); Huang Chunhui [State Key Laboratory of Rare Earth Materials Chemistry and Applications, Peking University, Beijing 100871 (China)]. E-mail: chhuang@pku.edu.cn

    2006-04-03

    Four unsymmetric as well as symmetric carbazole or oxadiazole modified pyran-containing compounds have been synthesized and characterized. These compounds are 4-(dicyanomethylene)-2-methyl-6-(4-(carbazolo-9-yl)phenyl)-4H-pyran (10), 4-(dicyanomethylene)-2,6-bis(4-(carbazolo-9-yl)phenyl)-4H-pyran (11), 4-(dicyanomethylene)-2-methyl-6-(4-tert-phenyl)-1,3,4-oxdiazole-4-phenyl)-4 H-pyran (12), and 4-(dicyanomethylene)-2,6-bis(4-tert-phenyl)-1,3, 4-oxdiazole-4-phenyl-4H-pyran (13). Photoluminescent measurements indicated that their maximal emissions can be tuned from 543 to 590 nm in acetone solution. Electroluminescent studies based on these compounds as dopants resulted in greenish yellow light emission. It was found that the device based on the bis-condensed symmetric compound (11) with the configuration of indium tin oxide / Copper (II) phthalocyanine (5 nm) / N,N'-bis-(1-naphthl)-diphenyl-1,1'-biphenyl-4,4'-diamine (40 nm) / compound (11) : tris-(8-quinolinolato)aluminium (Alq{sub 3}) (1%) (30 nm) / 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline (5 nm) / Alq{sub 3} (40 nm) / Mg : Ag (9 : 1) (200 nm) / Ag (80 nm) has achieved the highest luminance (6869 cd/m{sup 2}) and efficiency (1.32 lm/W and 2.52 cd/A) among the four emitters.

  1. Synthesis and properties of nitrogenous heterocycles containing a spiro-fused cyclopropane fragment

    International Nuclear Information System (INIS)

    Tomilov, Yury V; Nefedov, Oleg M; Kostyuchenko, Irina V

    2000-01-01

    The published data on the methods of synthesis and chemical transformations of nitrogenous heterocyclic compounds spiro-fused with a cyclopropane fragment are described systematically and generalised. The bibliography includes 146 references.

  2. Ionic liquid-mediated three-component synthesis of fluorinated spiro ...

    Indian Academy of Sciences (India)

    mediated three-component synthesis of fluorinated spiro-thiazine derivatives and their antimycobacterial and DNA cleavage activities. Anshu Dandia Ruby Singh Deepti Saini. Volume 125 Issue 5 September 2013 pp 1045-1053 ...

  3. Microwave mediated synthesis of spiro-(indoline-isoxazolidines): mechanistic study and biological activity evaluation

    DEFF Research Database (Denmark)

    Raunak, R.; Kumar, Vineet; Mukherjee, Shubhasish

    2005-01-01

    Regioisomeric spiro-(indoline-isoxazolidines) have been synthesized in moderate yields by the cycloaddition reaction between ethyl (3-indolylidene)acetate and various substituted α,N-diphenylnitrones, using environmentally benign microwave technology. A novel concerted reaction mechanism is descr......Regioisomeric spiro-(indoline-isoxazolidines) have been synthesized in moderate yields by the cycloaddition reaction between ethyl (3-indolylidene)acetate and various substituted α,N-diphenylnitrones, using environmentally benign microwave technology. A novel concerted reaction mechanism...

  4. Effective click construction of bridged- and spiro-multicyclic polymer topologies with tailored cyclic prepolymers (kyklo-telechelics).

    Science.gov (United States)

    Sugai, Naoto; Heguri, Hiroyuki; Ohta, Kengo; Meng, Qingyuan; Yamamoto, Takuya; Tezuka, Yasuyuki

    2010-10-27

    An alkyne-azide addition, i.e., click, reaction in conjunction with an electrostatic self-assembly and covalent fixation (ESA-CF) process has been demonstrated to effectively construct a variety of unprecedented multicyclic polymer topologies. A series of single cyclic poly(tetrahydrofuran), poly(THF), precursors having an alkyne group (Ia), an azide group (Ib), two alkyne groups at the opposite positions (Ic), and an alkyne group and an azide group at the opposite positions (Id) have been prepared by the ESA-CF process. Moreover, a bicyclic 8-shaped precursor having two alkyne groups at the opposite positions (Ie) was synthesized. The subsequent click reaction of Ia with linear (IIa) and three-armed star (IIb) telechelic precursors having azide groups has been performed to construct bridged-type two-way (IIIa) and three-way (IIIb) paddle-shaped polymer topologies, respectively. Likewise, spiro-type tandem tricyclic (IVa) and tetracyclic (IVb) topologies resulted from Ib/Ic and Ib/Ie, respectively. Furthermore, three types of multicyclic topologies that are composed of repeating ring (Va), alternating ring/linear (Vb), and alternating ring/star (Vc) units have been synthesized from Id, Ic/IIa, and Ic/IIb, respectively.

  5. Benzoyl Peroxide as an Efficient Dopant for Spiro-OMeTAD in Perovskite Solar Cells.

    Science.gov (United States)

    Liu, Qiuju; Fan, Lisheng; Zhang, Qin'e; Zhou, An'an; Wang, Baozeng; Bai, Hua; Tian, Qingyong; Fan, Bin; Zhang, Tongyi

    2017-08-10

    Although organic small molecule spiro-OMeTAD is widely used as a hole-transport material in perovskite solar cells, its limited electric conductivity poses a bottleneck in the efficiency improvement of perovskite solar cells. Here, a low-cost and easy-fabrication technique is developed to enhance the conductivity and hole-extraction ability of spiro-OMeTAD by doping it with commercially available benzoyl peroxide (BPO). The experimental results show that the conductivity increases several orders of magnitude, from 6.2×10 -6  S cm -1 for the pristine spiro-OMeTAD to 1.1×10 -3  S cm -1 at 5 % BPO doping and to 2.4×10 -2  S cm -1 at 15 % BPO doping, which considerably outperform the conductivity of 4.62×10 -4  S cm -1 for the currently used oxygen-doped spiro-OMeTAD. The fluorescence spectra suggest that the BPO-doped spiro-OMeTAD-OMeTAD layer is able to efficiently extract holes from CH 3 NH 3 PbI 3 and thus greatly enhances the charge transfer. The BPO-doped spiro-OMeTAD is used in the fabrication of perovskite solar cells, which exhibit enhancement in the power conversion efficiency. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  6. Introduction of axial chirality at a spiro carbon atom in the synthesis of pentaerythritol-imine macrocycles.

    Science.gov (United States)

    Grajewski, J; Piotrowska, K; Zgorzelak, M; Janiak, A; Biniek-Antosiak, K; Rychlewska, U; Gawronski, J

    2018-02-07

    Novel chiral macrocyclic polyimines with spiro carbon atoms are described. The key feature of the synthesis is the formation of an axially chiral quaternary carbon atom having four constitutionally identical substituents. This is possible either by the freezing of the labile conformation of a spiro-diboronate moiety or by the diastereomeric fitting of a conformationally stable spiro-acetal moiety into a chiral framework. A general model for the description of this type of axial chirality is proposed.

  7. 2-Acetyl-amino-1,3,4,6-tetra-O-(tri-methyl-silyl)-2-de-oxy-α-d-gluco-pyran-ose.

    Science.gov (United States)

    Cheng, Zhao-Dong; Cui, Yan-Li; Mao, Jian-Wei

    2013-06-01

    The title compound, C20H47NO6Si4, was synthesized by per-O-tri-methyl-silylation of N-acetyl-d-glucosa-mine using chloro-tri-methyl-silane in the presence of hexa-methyl-disiloxane. The tri-methyl-silyl group and acetamido group are located on the same side of the pyran ring, showing an α-configuration glycoside. One of the tri-methyl-silyl groups is disordered over two orientations, with site-occupancy factors of 0.625 (9) and 0.375 (9). In the crystal, N-H⋯O hydrogen bonds link the mol-ecules into supra-molecular chains along the a-axis direction.

  8. 3′,6′-Bis(diethylamino-3H-spiro[2-benzothiophene-1,9′-xanthene]-3-thione

    Directory of Open Access Journals (Sweden)

    Bing-Yuan Su

    2008-11-01

    Full Text Available The title compound, C28H30N2OS2, was obtained by thionation of 3′,6′-bis(diethylamino-3H-spiro[isobenzofuran-1,9′-xanthene]-3-one with 2,4-bis(p-methoxyphenyl-1,3-dithiadiphosphetane disulfide (Lawesson's reagent. The planes of the two benzene rings of the xanthene system are inclined at a dihedral angle of 17.4 (1°, and the plane of the dithiophthalide group and the planes through the two benzene rings of the xanthene system make dihedral angles of 80.2 (1 and 82.8 (1°, respectively.

  9. High performance spiro ammonium electrolyte for Electric Double Layer Capacitors

    Science.gov (United States)

    DeRosa, Donald; Higashiya, Seiichiro; Schulz, Adam; Rane-Fondacaro, Manisha; Haldar, Pradeep

    2017-08-01

    The smallest spiro ammonium salt reported to date, 1 M 4-Axoniaspiro[3,4]octane tetrafluoroborate (APBF4), was successfully synthesized and investigated as the electrolyte with acetonitrile (AN) in an Electric Double Layer Capacitor (EDLC) for the first time. The electrochemical characteristics of EDLC devices containing 1 M APBF4/AN paired with commercial activated carbon electrodes were compared to devices containing popular EDLC electrolytes, 1 M 5-Azoniaspiro[4.4]nonane tetrafluoroborate (SBPBF4/AN) and 1 M tetraethyl ammonium tetrafluoroborate (TEABF4/AN), using cyclic voltammetry (CV), galvanostatic charge discharge (GCD), and electrochemical impedance spectroscopy (EIS). The average gravimetric capacitance of the 1 M APBF4 device (124.7 F g-1) was found to be greater than the values measured for both the 1 M SBPBF4 device (108.6 F g-1) and the 1 M TEABF4 device (99.2 F g-1). The direct current equivalent series resistance (ESR) of the 1 M APBF4 device (383.4 mΩ cm-2) was found to be substantially lower than the values measured for both the 1 M SBPBF4 device (501.0 mΩ cm-2) and the 1 M TEABF4 device (710.8 mΩ cm-2). These results demonstrate that APBF4, when compared to current commercial electrolytes, significantly enhances the energy storage properties of EDLC devices.

  10. Optically active 6-acetyloxy-2H-pyran-3(6H)-one obtained by lipase catalyzed transesterification and esterification

    NARCIS (Netherlands)

    van den Heuvel, M.; Cuiper, A.D; van der Deen, H.; Kellogg, R.M; Feringa, B.L.

    1997-01-01

    Kinetic resolution of 6-acetyloxy-2H-pyran-3(6H)-one (1) is achieved by immobilized lipase PS on Hyflo Super Cell in organic solvents. Transesterification in hexane/n-butanol yields enantiomerically pure R-(-)-6-acetyloxy-2H-pyran-3(6H)-one, whereas esterification of 6-hydroxy-2H-pyran-3(6H)-one (2)

  11. Synthesis of Racemic β-Chamigrene, a Spiro[5.5]undecane Sequiterpene

    Directory of Open Access Journals (Sweden)

    Simen Antonsen

    2014-12-01

    Full Text Available The present paper describes a total synthesis of racemic β-chamigrene (1, a sesquiterpene with a spiro[5.5]undecane carbon framework. Compared with previously reported β-chamigrene syntheses, we were able to reduce the total number of reaction steps, which also resulted in a significant improvement of the overall yield. The commercially available ketone 6-methylhept-5-en-2-one was transformed by known simple procedures into 3,3-dimethyl-2-methylenecyclohexanone. This reacted with isoprene by a Diels-Alder reaction to give a spiro ketone. An olefination reaction on this compound gave the target molecule.

  12. Schemata, Cognitive Structure, and Advance Organizers: A Reply to Anderson, Spiro, and Anderson.

    Science.gov (United States)

    Ausubel, David P.

    1980-01-01

    Anderson, Spiro, and Anderson (EJ 189 658) assert that the author's assimilation theory of meaningful learning and retention is "hopelessly vague." Documented examination of these assertions indicates that they are unspecified, unsubstantiated, undocumented, and based on indisputable misrepresentation of published material and on logical…

  13. Spiro-OMeTAD single crystals: Remarkably enhanced charge-carrier transport via mesoscale ordering

    KAUST Repository

    Shi, Dong

    2016-04-15

    We report the crystal structure and hole-transport mechanism in spiro-OMeTAD [2,2′,7,7′-tetrakis(N,N-di-p-methoxyphenyl-amine)9,9′-spirobifluorene], the dominant hole-transporting material in perovskite and solid-state dye-sensitized solar cells. Despite spiro-OMeTAD’s paramount role in such devices, its crystal structure was unknown because of highly disordered solution-processed films; the hole-transport pathways remained ill-defined and the charge carrier mobilities were low, posing a major bottleneck for advancing cell efficiencies. We devised an antisolvent crystallization strategy to grow single crystals of spiro-OMeTAD, which allowed us to experimentally elucidate its molecular packing and transport properties. Electronic structure calculations enabled us to map spiro-OMeTAD’s intermolecular charge-hopping pathways. Promisingly, single-crystal mobilities were found to exceed their thin-film counterparts by three orders of magnitude. Our findings underscore mesoscale ordering as a key strategy to achieving breakthroughs in hole-transport material engineering of solar cells.

  14. Green synthesis of tetrahydrobenzo[b]Pyrans by microwave assisted multi-component one-pot reactions in PEG-400.

    Science.gov (United States)

    Feng, Chun; Wang, Qiuyan; Lu, Cuifen; Yang, Guichun; Chen, Zuxing

    2012-01-01

    Polyethylene glycol is found to be a nontoxic and recyclable reaction medium for the microwave-assisted, multi-component one-pot reactions of aromatic aldehydes with ethyl-2-cyanoacetate and 1,3-cyclohexanedione or 5,5- dimethyl-1,3-cyclohexanedione in the presence of piperidine. This environmentally friendly microwave protocol offers ease of operation and enables recyclability of reaction medium and synthesis of a variety of substituted tetrahydrobenzo[b]pyran derivatives. It is an efficient, promising, and green synthetic strategy to construct tetrahydrobenzo[b]pyran skeleton.

  15. An Environmentally Benign Protocol for Aqueous Synthesis of Tetrahydrobenzo[b]Pyrans Catalyzed by Cost-Effective Ionic Liquid

    Directory of Open Access Journals (Sweden)

    Huanan Hu

    2014-04-01

    Full Text Available A mild, efficient, and environmentally benign protocol for the synthesis of tetrahydrobenzo[b]pyran derivatives in the presence of readily accessible, biodegradable, and choline hydroxide based ionic liquid as catalyst has been established. The key features of the reported methodology include good to excellent yields of desired products, simple work-up procedure and good recyclability of catalysts, which may be a practical alternative to the existing conventional processes for the preparation of 4-H pyrans to cater to the requirements of academia as well as industry.

  16. Spiro-linked hyperbranched architecture in electrophosphorescent conjugated polymers for tailoring triplet energy back transfer.

    Science.gov (United States)

    Shao, Shiyang; Ma, Zhihua; Ding, Junqiao; Wang, Lixiang; Jing, Xiabin; Wang, Fosong

    2012-04-17

    A spiro-linked hyperbranched architecture has been incorporated into electrophosphorescent conjugated polymers for the first time, aiming at simultaneously tailoring the intra- and intermolecular triplet energy back transfer from the phosphorescent guest to the conjugated polymer host. Based on a prototype with this unique structure, slower decay of triplet excitons, and 5-8 fold enhancement of device efficiencies are obtained compared with the conventional blending counterpart. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  17. 6′-Methyl-1′,2′,3′,4′-tetra­hydro­spiro­cyclo­hexane-2′-quinazolin-4′-one

    Science.gov (United States)

    Ling, Zhang; Shi, Daxin; Yanqiu, Fan; Wei, Xia; Li, Jiarong

    2009-01-01

    The title compound, C14H18N2O, was synthesized by the reaction of cyclo­hexa­none and 2-amino-5-methyl­benzonitrile. In the mol­ecule, the cyclo­hexane ring displays a chair conformation, whereas the 1,3-diaza­cyclo­hexane moiety of the bicyclic system has a sofa conformation with the spiro C atom displaced by 0.603 (2) Å from the rest of the atoms of the 1,3-diaza­cyclo­hexane ring [planar within 0.052 (2) Å]. Mol­ecules are linked into centrosymmetric dimers via N—H⋯O hydrogen bonds. PMID:21583911

  18. 2-Acetyl­amino-1,3,4,6-tetra-O-(tri­methyl­silyl)-2-de­oxy-α-d-gluco­pyran­ose

    Science.gov (United States)

    Cheng, Zhao-Dong; Cui, Yan-Li; Mao, Jian-Wei

    2013-01-01

    The title compound, C20H47NO6Si4, was synthesized by per-O-tri­methyl­silylation of N-acetyl-d-glucosa­mine using chloro­tri­methyl­silane in the presence of hexa­methyl­disiloxane. The tri­methyl­silyl group and acetamido group are located on the same side of the pyran ring, showing an α-configuration glycoside. One of the tri­methyl­silyl groups is disordered over two orientations, with site-occupancy factors of 0.625 (9) and 0.375 (9). In the crystal, N—H⋯O hydrogen bonds link the mol­ecules into supra­molecular chains along the a-axis direction. PMID:23795087

  19. (2-Methyl-4-oxo-4H-pyran-3-olato-κ2O3,O4bis(triphenylphosphane-κPcopper(I–triphenylphosphane–methanol (1/1/1

    Directory of Open Access Journals (Sweden)

    Fabian M. A. Muller

    2011-05-01

    Full Text Available In the title compound, [Cu(C6H5O3(C18H15P2]·C18H15P·CH3OH, the pyran-4-one ring is appromimately planar (r.m.s deviation = 0.0138 Å, with the CuI atom 0.451 (5 Å out of the plane. The CuI atom has a distorted tetrahedral coordination. The O—Cu—O angle is 80.07 (8° and the P—Cu—P angle is 123.49 (3°. The crystal packing is stablized by intramolecular C—H...O interactions and intermolecular C—H...O and O—H...O interactions.

  20. Caffeine Catalyzed Synthesis of Tetrahydrobenzo[b]pyran Derivatives: Synthesis and Insight into Kinetics and Mechanism.

    Science.gov (United States)

    Habibi-Khorassani, Sayyed Mostafa; Shahraki, Mehdi; Mollashahi, Ebrahim; Pourpanah, Sayyedeh Shadfar; Majdabadi, Shabnam Keshavarz

    2016-01-01

    Tetrahydrobenzo[b]pyran derivatives are considered as a special class in drug research because of their various biological and pharmacological benefiting usages. In the current work, we developed new synthetic methods for the preperation of tetrahydrobenzo[b]pyran derivatives using arylaldehydes 1, malononitrile 2 and dimedonein 3 in the presence of caffeine as catalyst as a cheap, easily accessible, biodegradable and green catalyst. Moreover, for the first time, we have described kinetic results together along with detailed mechanistic studies of the synthetic reaction of a derivative of 4Htetrahydrobenzo[ b]pyran based on a global kinetic analysis methodology using UVvis spectrophotometry apparatus. Products were characterized by comparison of physical data with authentic samples and spectroscopic data (IR and NMR). Infrared (IR) spectra were recorded on a JASCO FT IR 460 plus spectrometer. 1H nuclear magnetic resonance (NMR) spectra were obtained with a Bruker DRX 400 Advance spectrometer and using deuterated dimethylsulfoxide (DMSO) and acetone as solvents. Thin layer chromatography (TLC) was performed on Silica-gel polygram SILG/UV 254 plates. Rate constants are presented as an average of several kinetic runs (at least 6-10) and are reproducible within ± 3%. The overall rate of reaction is followed by monitoring the absorbance changes of the products versus time on a Varian (Model Cary Bio-300) UV-vis spectrophotometer with a 10 mm light-path cell. For optimization, the reaction of benzaldehyde (1 mmol), malonitrile (1 mmol) and dimedone (1 mmol) was investigated. The desired results were obtained at 70 °C in the presence of (20 mol %) caffeine in H2O: EtOH (2:1). Moreover, the overall order of reaction for the formation of a 4Htetrahydrobenzo[ b]pyran derivative in the presence of caffeine followed second-order kinetics and the partial orders with regard to 4-nitrobenzaldehyde 1, malononitrile 2 and dimedone 3 were one, one and zero, respectively. It was

  1. Multicomponent synthesis, biological evaluation and molecular docking of new spiro-oxindole derivatives

    Directory of Open Access Journals (Sweden)

    M. Sapnakumari

    2017-11-01

    Full Text Available A new series of spiro-oxindoles that were identified based upon their ability to inhibit methionine tRNA synthase (PDB ID: 1PFV and glucosamine-6-phosphate synthase (PDB ID: 1JXA enzymes in virtual screening was synthesized by a three-component 1,3-dipolar cycloaddition method. The reaction proceeds through the formation of azomethine ylides generated in situ by the decarboxylative condensation of isatin and amino acids with dipolarophile chalcones. These compounds are active against Staphylococcus aureus, Escherichia coli, Aspergillus niger and Aspergillus flavus, supporting the in silico screening. In addition, their antitubercular activity was assessed using the MABA method. The compounds 3′-[(4-fluorophenylcarbonyl]-4′-phenylspiro[indole-3,2′-pyrrolidin]-2(1H-one 3a, 4′-(4-bromophenyl-3′-[(4-fluorophenylcarbonyl]-5′-(hydroxymethyl spiro[indole-3,2′-pyrrolidin]-2(1H-one 3e and 4′-(4-chlorophenyl-3′-[(4-fluorophenylcarbonyl]-5′-(2-methylpropylspiro[indole-3,2′-pyrrolidin]-2(1H-one 3g are potent molecules with MIC of 0.8 μg/mL. In the DPPH radical scavenging assay, compounds 4′-(4-chlorophenyl-3′-[(4-fluorophenylcarbonyl]spiro[indole-3,2′-pyrrolidin]-2(1H-one 3b, 4′-(4-chlorophenyl-3′-[(4-fluorophenylcarbonyl]-5′-(hydroxymethylspiro[indole-3,2′-pyrrolidin]-2(1H-one 3d and 4′-(4-bromophenyl-3′-[(4-fluorophenylcarbonyl]-5′-(hydroxymethylspiro[indole-3,2′-pyrrolidin]-2(1H-one 3e exhibited significant radical scavenging capacity. Keywords: Chalcone, Spiro-oxindole, Azomethine ylide, Antimicrobial activity, Molecular docking

  2. Shelly Spiro: a pharmacy technology guru ASCP president 2009-2010.

    Science.gov (United States)

    Bloom, Marlene Z

    2009-10-01

    Rachelle "Shelly" Spiro, RPh, FASCP, incoming president of the American Society of Consultant Pharmacists (ASCP), believes sharing information electronically will greatly benefit pharmacy practice. In recent years she has been an expert in health care technology, helping establish standards for reporting health care data on outcomes, reimbursement, and electronic medical records--all areas that affect consultant pharmacists. One of her goals as president is to help mentor potential leaders by having a grassroots campaign to reach out to students in schools of pharmacy. In addition, she wants ASCP's leadership to move to a more regional structure and get members more involved locally at state levels.

  3. Synthesis of spiro[indolo-1,5-benzodiazepines] from 3-acetyl ...

    Indian Academy of Sciences (India)

    Unknown

    Synthesis of spiro[indolo-1,5-benzodiazepines] from 3-acetyl coumarins. 267. Table 2. IR and PMR spectral data of compounds 4(a–f). IR (cm–1). Compd. R. νC=O (lactone). νC=O (keto). νC=O (amide). νN–H. PMR δ (ppm). 4a. H. 1721. 1610. 1662. 3188. 7⋅93 (s, 1H, =CH), 8⋅70 (s, 1H, C4-H), 10⋅46. (s, 1H, NH, D2O ...

  4. Nanostructured TiO2/CH3NH3PbI3 heterojunction solar cells employing spiro-OMeTAD/Co-complex as hole-transporting material

    KAUST Repository

    Noh, Jun Hong

    2013-01-01

    For using 2,2′,7,7′-tetrakis(N,N′-di-p- methoxyphenylamine)-9,9′-spirobifluorene (spiro-OMeTAD) as a hole conductor in solar cells, it is necessary to improve its charge-transport properties through electrochemical doping. With the aim of fabricating efficient mesoscopic TiO2/CH3NH3PbI3 heterojunction solar cells, we used tris[2-(1H-pyrazol-1-yl)-4-tert- butylpyridine)cobalt(iii) tris(bis(trifluoromethylsulfonyl) imide)] (FK209) as a p-dopant for spiro-OMeTAD. The mixture of spiro-OMeTAD, FK209, lithium bis(trifluoromethylsulfonyl)imide (Li-TFSI), and 4-tert-butylpyridine (TBP) exhibited significantly higher performance than mixtures of pristine spiro-OMeTAD, spiro-OMeTAD, and FK209, and spiro-OMeTAD, Li-TFSI, and TBP. Such a synergistic effect between the Co-complex and Li-TFSI in conjunction with spiro-OMeTAD effectively improved the power conversion efficiency (PCE) of the fabricated solar cells. As a result, we achieved PCE of 10.4%, measured under standard solar conditions (AM 1.5G, 100 mW cm-2). © 2013 The Royal Society of Chemistry.

  5. Synthesis and pharmacological evaluation of novel N-aryl-3,4-dihydro-1'H-spiro[chromene-2,4'-piperidine]-1'-carboxamides as TRPM8 antagonists.

    Science.gov (United States)

    Chaudhari, Sachin S; Kadam, Ashok B; Khairatkar-Joshi, Neelima; Mukhopadhyay, Indranil; Karnik, Pallavi V; Raghuram, Anupindi; Rao, Shobha S; Vaiyapuri, Thamil Selvan; Wale, Dinesh P; Bhosale, Vikram M; Gudi, Girish S; Sangana, Ramchandra R; Thomas, Abraham

    2013-11-01

    A novel series of N-aryl-3,4-dihydro-1'H-spiro[chromene-2,4'-piperidine]-1'-carboxamides was identified as transient receptor potential melastatin 8 (TRPM8) channel blockers through analogue-based rational design, synthesis and screening. Details of the synthesis, effect of aryl groups and their substituents on in-vitro potency were studied. The effects of selected functional groups on the 4-position of the chromene ring were also studied, which showed interesting results. The 4-hydroxy derivatives showed excellent potency and selectivity. Optical resolution and screening of alcohols revealed that (R)-(-)-isomers were in general more potent than the corresponding (S)-(+)-isomers. The isomer (R)-(-)-10e (IC50: 8.9nM) showed a good pharmacokinetic profile upon oral dosing at 10mg/kg in Sprague-Dawley (SD) rats. The compound (R)-(-)-10e also showed excellent efficacy in relevant rodent models of neuropathic pain. Copyright © 2013 Elsevier Ltd. All rights reserved.

  6. The oxidation of 2,2,5-three methyl-6-spiro cyclo hexane di hydro pyranol-5(X CI)

    International Nuclear Information System (INIS)

    Nikitin, V.I.

    1961-01-01

    In this chapter of book author as a result of oxidation of 2,2,5-three methyl-6-spiro cyclo hexane di hydro pyranol-5 evolved acetone, cyclopentanone, formic acid, acetic acid, oxalic acid, α-oxi isobutyric acid and adipinic acids

  7. Vortex rings

    CERN Document Server

    Akhmetov, D G

    2009-01-01

    This text on vortex rings covers their theoretical foundation, systematic investigations, and practical applications such as the extinction of fires at gushing oil wells. It pays special attention to the formation and motion of turbulent vortex rings.

  8. Synthesis, stereochemistry and cytotoxic activity of novel steroidal 16-spiro-1,3,2-dioxaphosphorinanes

    Science.gov (United States)

    Wölfling, János; Kovács-Pénzes, Piroska; Zupkó, István; Schneider, Gyula; Frank, Éva

    2012-04-01

    The epimeric pairs a and b of novel steroidal 16-spiro-dioxaphosphorinanes 4-8 were synthetized via the phosphorylation of 16,16-bis(hydroxymethyl)androst-4-ene-3,17-dione (2) and their stereostructures were investigated by NMR methods. The dioxaphosphorinane moiety exists mainly as one of the possible chair conformers or as a chair-twist equilibrium in solution as a consequence of the rigidity of the sterane framework. The contributions of the conformers depend strongly on the configuration of the P atom and the stereoelectronic properties of the substituents on it. The antiproliferative activities of the structurally related products were determined in vitro with the MTT assay on three malignant human cell lines (HeLa, MCF7 and A431).

  9. Shelf life stability comparison in air for solution processed pristine PDPP3T polymer and doped spiro-OMeTAD as hole transport layer for perovskite solar cell

    Directory of Open Access Journals (Sweden)

    Ashish Dubey

    2016-06-01

    Full Text Available This data in brief includes forward and reverse scanned current density–voltage (J–V characteristics of perovskite solar cells with PDPP3T and spiro-OMeTAD as HTL, stability testing conditions of perovskite solar cell shelf life in air for both PDPP3T and spiro-OMeTAD as HTL as per the description in Ref. [1], and individual J–V performance parameters acquired with increasing time exposed in ambient air are shown for both type of devices using PDPP3T and spiro-OMeTAD as HTL. The data collected in this study compares the device stability with time for both PDPP3T and spiro-OMeTAD based perovskite solar cells and is directly related to our research article “solution processed pristine PDPP3T polymer as hole transport layer for efficient perovskite solar cells with slower degradation” [2].

  10. Planetary Rings

    Science.gov (United States)

    Tiscareno, Matthew S.

    Planetary rings are the only nearby astrophysical disks and the only disks that have been investigated by spacecraft (especially the Cassini spacecraft orbiting Saturn). Although there are significant differences between rings and other disks, chiefly the large planet/ring mass ratio that greatly enhances the flatness of rings (aspect ratios as small as 10- 7), understanding of disks in general can be enhanced by understanding the dynamical processes observed at close range and in real time in planetary rings.We review the known ring systems of the four giant planets, as well as the prospects for ring systems yet to be discovered. We then review planetary rings by type. The A, B, and C rings of Saturn, plus the Cassini Division, comprise our solar system's only dense broad disk and host many phenomena of general application to disks including spiral waves, gap formation, self-gravity wakes, viscous overstability and normal modes, impact clouds, and orbital evolution of embedded moons. Dense narrow rings are found both at Uranus (where they comprise the main rings entirely) and at Saturn (where they are embedded in the broad disk) and are the primary natural laboratory for understanding shepherding and self-stability. Narrow dusty rings, likely generated by embedded source bodies, are surprisingly found to sport azimuthally confined arcs at Neptune, Saturn, and Jupiter. Finally, every known ring system includes a substantial component of diffuse dusty rings.Planetary rings have shown themselves to be useful as detectors of planetary processes around them, including the planetary magnetic field and interplanetary impactors as well as the gravity of nearby perturbing moons. Experimental rings science has made great progress in recent decades, especially numerical simulations of self-gravity wakes and other processes but also laboratory investigations of coefficient of restitution and spectroscopic ground truth. The age of self-sustained ring systems is a matter of

  11. Storage rings

    Energy Technology Data Exchange (ETDEWEB)

    O' Neill, Gerald K.

    1963-04-15

    The development of storage rings is discussed. Advantages of such devices are pointed out as well as their limits, requirements, and design and fabrication problems. Information gained by the operation of small electron storage rings is included, and three experiments are proposed for colliding-beam facilities. (D.C.W.)

  12. Synthesis and biological activities of some new spiro 1,2,4-triazole derivatives having sulfonamide moiety

    Directory of Open Access Journals (Sweden)

    Hany M. Dalloul

    2017-10-01

    Full Text Available A new series of spiro 1,2,4-triazoles 5-9a-j were prepared by the reaction of appropriate amidrazones 4 with cyclic ketones in catalytic amount of p-toluene sulfonic acid. The structures of the titled compounds have been elucidated by the elemental analysis and spectroscopic data (IR, 1H NMR, 13C NMR and MS. The biological activities of the prepared compounds were investigated using well-established methods from the literature.

  13. Genotoxicity evaluation of two kinds of smoke-water and 3,7-dimethyl-2H-furo[2,3-c]pyran-2-one

    Czech Academy of Sciences Publication Activity Database

    Trinh, C.; Gevaert, L.; Kohout, Ladislav; van Staden, J.; Verschaeve, L.

    2010-01-01

    Roč. 30, č. 6 (2010), s. 596-602 ISSN 0260-437X Institutional research plan: CEZ:AV0Z40550506 Keywords : butenolide * smoke -water * 3,7-dimethyl-2H-furo[2,3-c]pyran-2-one * assay * seed germination Subject RIV: CC - Organic Chemistry Impact factor: 2.322, year: 2010

  14. One-pot synthesis of 2H-pyrans by indium(III) chloride-catalyzed reactions. efficient synthesis of pyranocoumarins, pyranophenalenones, and pyranoquinolinones

    International Nuclear Information System (INIS)

    Lee, Yong Rok; Kim, Do Hoon; Shim, Jae Jin; Kim, Seog K.; Park, Jung Hag; Cha, Jin Soon; Lee, Chong Soon

    2002-01-01

    An efficient synthesis of 2H-pyrans is achieved by indium (III) chloride-catalyzed reactions of 1,3-dicarbonyl compounds with a variety of α.β-unsaturated aldehydes in moderates yields. This method has been applied to the synthesis of pyranocoumarins, pyranophenaleneones, and pyranoquinolinone alkaloids

  15. A one-step synthesis of 2,3-dihydro-4H-pyran-4-ones from 3-ethoxy alpha,beta-unsaturated lactones.

    Science.gov (United States)

    Winkler, Jeffrey D; Oh, Kyungsoo

    2005-06-09

    [reaction: see text] Addition of diverse nucleophiles to the unsaturated lactone 2 that results from hetero Diels-Alder reaction of Brassard's diene 1 with aldehydes leads to an efficient and general approach to the synthesis of 2,3-dihydro-4H-pyran-4-ones 3.

  16. Determinantal rings

    CERN Document Server

    Bruns, Winfried

    1988-01-01

    Determinantal rings and varieties have been a central topic of commutative algebra and algebraic geometry. Their study has attracted many prominent researchers and has motivated the creation of theories which may now be considered part of general commutative ring theory. The book gives a first coherent treatment of the structure of determinantal rings. The main approach is via the theory of algebras with straightening law. This approach suggest (and is simplified by) the simultaneous treatment of the Schubert subvarieties of Grassmannian. Other methods have not been neglected, however. Principal radical systems are discussed in detail, and one section is devoted to each of invariant and representation theory. While the book is primarily a research monograph, it serves also as a reference source and the reader requires only the basics of commutative algebra together with some supplementary material found in the appendix. The text may be useful for seminars following a course in commutative ring theory since a ...

  17. ring system

    African Journals Online (AJOL)

    1,3,2-DIAZABORACYCLOALKANE. RING SYSTEM. Negussie Retta" and Robert H. Neilson. 'Department of Chemistry, Addis Ababa University, P.O. Box 1176, Addis Ababa, Ethiopia. Department of Chemistry, Texas Christian University.

  18. Vascular ring

    Science.gov (United States)

    ... trachea) and esophagus can lead to breathing and digestive problems. The more the ring presses down, the more severe the symptoms will be. Breathing problems may include: ... Digestive symptoms are rare, but may include: Choking Difficulty ...

  19. Synthesis and Crystal Structure of a New Hydrated Benzimidazolium Salt Containing Spiro Structure

    Directory of Open Access Journals (Sweden)

    Wulan Zeng

    2017-10-01

    Full Text Available A new hydrated benzimidazolium salt containing spiro structure was obtained when benzimidazole is added to ethyl alcohol of 1,5-dioxaspiro[5.5]undecane-2,4-dione and trimethoxymethane. The title compound (C19H21O8 (C7H7N2 (0.5H2O was characterized by elemental analysis, IR, UV-Vis, and single-crystal X-ray diffraction. The result shows that it belongs to the triclinic system, space group P-1, with a = 11.017(2 Å, b = 11.424(2 Å, c = 11.650(2 Å, α = 70.60(3°, β = 71.00(3°, γ = 67.64(3°, Mr = 505.51, V = 1245.2(5 Å, Z = 2, Dc = 1.348 g/cm3, F(000 = 534, μ(MoKa = 0.102 mm−1. There exist two types of hydrogen bonds in the crystal. (C19H21O8− anions and (C7H7N2+ cations are linked by N–H···O hydrogen bonds, while (C19H21O8− anions and free water are linked by O–H···O hydrogen bonds. All of the above hydrogen bonds form a one-dimensional (1D-chained structure. The 1D chains further links the molecule into a three-dimensional (3D-layered structure.

  20. Synthesis, Molecular Structure and Spectroscopic Investigations of Novel Fluorinated Spiro Heterocycles

    Directory of Open Access Journals (Sweden)

    Mohammad Shahidul Islam

    2015-05-01

    Full Text Available This paper describes an efficient and regioselective method for the synthesis of novel fluorinated spiro-heterocycles in excellent yield by cascade [5+1] double Michael addition reactions. The compounds 7,11-bis(4-fluorophenyl-2,4-dimethyl- 2,4-diazaspiro[5.5] undecane-1,3,5,9-tetraone (3a and 2,4-dimethyl-7,11-bis (4-(trifluoromethylphenyl-2,4-diazaspiro[5.5]undecane-1,3,5,9-tetraone (3b were characterized by single-crystal X-ray diffraction, FT-IR and NMR techniques. The optimized geometrical parameters, infrared vibrational frequencies and NMR chemical shifts of the studied compounds have also been calculated using the density functional theory (DFT method, using Becke-3-Lee-Yang-Parr functional and the 6-311G(d,p basis set. There is good agreement between the experimentally determined structural parameters, vibrational frequencies and NMR chemical shifts of the studied compounds and those predicted theoretically. The calculated natural atomic charges using NBO method showed higher polarity of 3a compared to 3b.The calculated electronic spectra are also discussed based on the TD-DFT calculations.

  1. Synthesis and Characterization of a Novel Nanosilica Supported Bipyridinium Chloride Nanocomposite and its Application as a Basic Catalyst in the One-pot Preparation of Tetrahydrobenzo[b]pyran, Dihydropyrano[3,2-c]chromene and Dihydropyrano[4,3-b]pyran Derivatives

    Directory of Open Access Journals (Sweden)

    Ali Reza Kiasat

    2016-07-01

    Full Text Available A novel rice-husk-silica supported n-propyl bipyridinium chloride (RHPrBPCl has been prepared. Due to the basicity of RHPrBPCl, it was decided to evaluate its catalytic activity in the one-pot preparation of tetrahydrobenzo[b]pyran, dihydropyrano[3,2-c]chromene and dihydropyrano[4,3-b]pyran derivatives. The catalyst was characterized by FT-IR, SEM and TGA analyses. This methodology offers several advantages including easy work-up procedure, high yields of the products, short reaction times, recyclable catalyst and green reaction medium.

  2. Synthesis of 6-Substituted 2-Pyrones Starting from Renewable Resources: Total Synthesis of Sibirinone, (E)-6-(Pent-1-en-1-yl)-2H-pyran-2-one, and (E)-6-(Hept-1-en-1-yl)-2H-pyran-2-one.

    Science.gov (United States)

    Dobler, Daniel; Reiser, Oliver

    2016-11-04

    An atom-economic reaction sequence to 6-substituted 2-pyrones was developed starting from furfuryl alcohol, a renewable resource made from bran or bagasse, and aldehydes, utilizing a thermal rearrangement of cyclopentadienone epoxides as key step. Derivatives bearing a hydroxyalkyl side chain could be enzymatically resolved, providing access to enantiomerically pure 2-pyrones, or converted to alkenyl-substituted 2-pyrones such as naturally occurring sibirinone, (E)-6-(pent-1-en-1-yl)-2H-pyran-2-one, and (E)-6-(hept-1-en-1-yl)-2H-pyran-2-one.

  3. Fluorescence and amplified spontaneous emission of glass forming compounds containing styryl-4H-pyran-4-ylidene fragment

    Energy Technology Data Exchange (ETDEWEB)

    Vembris, Aivars, E-mail: aivars.vembris@cfi.lu.lv [Institute of Solid State Physics, University of Latvia, 8 Kengaraga Street, Riga LV-1063 (Latvia); Muzikante, Inta [Institute of Solid State Physics, University of Latvia, 8 Kengaraga Street, Riga LV-1063 (Latvia); Karpicz, Renata; Sliauzys, Gytis [Institute of Physics, Center for Physical Sciences and Technology, A. Gostauto 11, LT-01108 Vilnius (Lithuania); Miasojedovas, Arunas; Jursenas, Saulius [Institute of Applied Research, Vilnius University, Sauletekio 9-III, LT-10222 Vilnius (Lithuania); Gulbinas, Vidmantas [Institute of Physics, Center for Physical Sciences and Technology, A. Gostauto 11, LT-01108 Vilnius (Lithuania)

    2012-09-15

    Potential of glassy films of newly synthesised low molecular weight organic molecules for light amplification and lasing applications has been investigated by analysing fluorescence, transient differential absorption and amplified spontaneous emission properties. These non-symmetric and symmetric molecules contain styryl-4H-pyran-4-ylidene fragment with three different electron acceptor groups: dicyanomethylene, barbituric acid, indene-1,3-dione. Fluorescence quantum yields of the investigated compounds in solutions are between 0.32 and 0.54, while they drop down by an order of magnitude in thin solid films. Incorporation of bulky side groups reduced excitonic interactions enabling manifestation of amplified spontaneous emission in the neat films of the investigated derivatives. - Highlights: Black-Right-Pointing-Pointer Bulky substituents attached to DCM dye enable formation of neat glassy films. Black-Right-Pointing-Pointer Investigated dyes show amplified spontaneous emission in neat films. Black-Right-Pointing-Pointer Two electron donor groups negatively influence light amplification.

  4. Aggregation and permeation of 4-(dicyanomethylene)-2-methyl-6-(p- dimethylaminostyryl)-4H-pyran molecules in Alq

    Science.gov (United States)

    Zhong, G. Y.; Xu, Z.; He, J.; Zhang, S. T.; Zhan, Y. Q.; Wang, X. J.; Xiong, Z. H.; Shi, H. Z.; Ding, X. M.; Huang, W.; Hou, X. Y.

    2002-08-01

    The morphologic and luminescent behaviors of various 4-(dicyanomethylene)-2methyl-6-(p-dimethylaminostyryl)-4H-pyran (DCM) containing films have been investigated. This involves pure DCM layers deposited on top of a tris-(8-hydroxyquinoline) aluminum (Alq) layer or positioned between two Alq layer, DCM-doped Alq films, and periodically arranged Alq/DCM multilayer structures. The occurrence over a period of time of aggregation and permeation of DCM molecules at room temperature and at temperatures as low as approx260 K is found in all the cases studied. Such a phenomenon will result in degradation of related organic light-emitting devices and is closely related to the electric polarity of the DCM molecule.

  5. Diethyl 3H-naphtho[2,1-b]pyran-2,3-dicarboxylate

    Directory of Open Access Journals (Sweden)

    Abdullah Mohamed Asiri

    2009-04-01

    Full Text Available The sp3-hybridized methine C atom in the title compound, C19H18O5, lies out of the mean plane of the remaining 13 atoms of the naphthopyran fused-ring system by 0.571 (1 Å, and its H atom occupies a pseudo-equatorial site.

  6. Ring accelerators

    International Nuclear Information System (INIS)

    Gisler, G.; Faehl, R.

    1983-01-01

    We present two-dimensional simulations in (r-z) and r-theta) cylinderical geometries of imploding-liner-driven accelerators of rings of charged particles. We address issues of azimuthal and longitudinal stability of the rings. We discuss self-trapping designs in which beam injection and extraction is aided by means of external cusp fields. Our simulations are done with the 2-1/2-D particle-in-cell plasma simulation code CLINER, which combines collisionless, electromagnetic PIC capabilities with a quasi-MHD finite element package

  7. Topological rings

    CERN Document Server

    Warner, S

    1993-01-01

    This text brings the reader to the frontiers of current research in topological rings. The exercises illustrate many results and theorems while a comprehensive bibliography is also included. The book is aimed at those readers acquainted with some very basic point-set topology and algebra, as normally presented in semester courses at the beginning graduate level or even at the advanced undergraduate level. Familiarity with Hausdorff, metric, compact and locally compact spaces and basic properties of continuous functions, also with groups, rings, fields, vector spaces and modules, and with Zorn''s Lemma, is also expected.

  8. Ring interferometry

    CERN Document Server

    Malykin, Grigorii B; Zhurov, Alexei

    2013-01-01

    This monograph is devoted to the creation of a comprehensive formalism for quantitative description of polarized modes' linear interaction in modern single-mode optic fibers. The theory of random connections between polarized modes, developed in the monograph, allows calculations of the zero shift deviations for a fiber ring interferometer. The monograph addresses also the

  9. Synthesis and Crystal Structures of Two Novel O, N-Containing Spiro Compounds

    Directory of Open Access Journals (Sweden)

    Wulan Zeng

    2016-06-01

    Full Text Available Two novel O, N-containing spiro compounds, C16H16ClNO4 (1 and C16H16N2O6 (2, were prepared by reactions of monosubstituted benzenamine (substituent = –NO2, –Cl and 1,5-dioxaspiro[5.5]undecane-2,4-dione in ethanol solution of trimethoxymethane. Their structures were characterized by elemental analysis, IR, UV-Vis and single-crystal X-ray diffraction. Compound 1 is triclinic with space group P-1 and cell constants: a = 5.9448(12, b = 9.782(2, c = 13.480(3 Å, α = 100.28(3°, β = 100.66(3°, γ = 97.83(3°, Mr = 321.75, V = 746.3(3 Å3, Z = 2, Dc = 1.432 g/cm3, F(000 = 336, μ(MoKa = 0.274 mm−1, the final R = 0.0544 and wR = 0.1538. Compound 2 is monoclinic with space group P21/c and cell constants: a = 12.472(3, b = 11.856(2, c = 10.643(2 Å, β = 99.83(3°, Mr = 332.31, V = 1550.7(5 Å3, Z = 4, Dc = 1.423 g/cm3, F(000 = 696, μ(MoKa = 0.110 mm−1, the final R = 0.0444 and wR = 0.1187. In 1, there exist some intra- and inter-molecular hydrogen bonds and C–H···π supramolecular interactions, while there are still π···π stacking interactions except for some intra- and intermolecular hydrogen bonds in 2. Two compounds both form a three-dimensional network structure via above intermolecular interactions.

  10. Click construction of spiro- and bridged-quatrefoil polymer topologies with kyklo-telechelics having an azide group.

    Science.gov (United States)

    Ko, Yee Song; Yamamoto, Takuya; Tezuka, Yasuyuki

    2014-02-01

    Unprecedented tetracyclic polymer topologies with spiro- and a bridged-type quatrefoil forms are effectively constructed through an alkyne-azide, click-linking reaction by employing a kyklo-telechelic poly(tetrahydrofuran), poly(THF), precursor having an azide group, obtained through an electrostatic self-assembly and covalent fixation (ESA-CF) process, and complementary tetrafunctional alkyne reagents of either a pentaerythritol derivative or a four-armed star telechelic polymer precursor. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  11. Pyran-Squaraine as Photosensitizers for Dye-Sensitized Solar Cells: DFT/TDDFT Study of the Electronic Structures and Absorption Properties

    Directory of Open Access Journals (Sweden)

    Reda M. El-Shishtawy

    2014-01-01

    Full Text Available In an effort to provide, assess, and evaluate a theoretical approach which enables designing efficient donor-acceptor dye systems, the electronic structure and optical properties of pyran-squaraine as donor-acceptor dyes used in dye-sensitized solar cells were investigated. Ground state properties have been computed at the B3LYP/6-31+G** level of theory. The long-range corrected density functionals CAM-B3LYP, PBEPBE, PBE1PBE (PBE0, and TPSSH with 6-311++G** were employed to examine absorption properties of the studied dyes. In an extensive comparison between experimental results and ab initio benchmark calculations, the TPSSH functional with 6-311++G** basis set was found to be the most appropriate in describing the electronic properties for the studied pyran and squaraine dyes. Natural transition orbitals (NTO, frontier molecular orbitals (FMO, LUMO, HOMO, and energy gaps, of these dyes, have been analyzed to show their effect on the process of electron injection and dye regeneration. Interaction between HOMO and LUMO of pyran and squaraine dyes was investigated to understand the recombination process and charge-transfer process involving these dyes. Additionally, we performed natural bond orbital (NBO analysis to investigate the role of charge delocalization and hyperconjugative interactions in the stability of the molecule.

  12. Oleaceran: a novel spiro[isobenzofuran-1,2'-naptho[1,8-bc]furan] isolated from a terrestrial Streptomyces sp.

    Science.gov (United States)

    Raju, Ritesh; Gromyko, Oleksandr; Fedorenko, Viktor; Luzhetskyy, Andriy; Müller, Rolf

    2013-07-19

    Chemical analysis of a terrestrial-derived Streptomyces sp. Lv20-195 cultivated from the root zone of Olea europea yielded oleaceran, 1, possessing a novel spiro[isobenzofuran-1,2'-naptho[1,8-b,c]furan] carbon skeleton. The structure of 1 was determined by detailed spectroscopic analysis.

  13. New iridium complex as additive to the spiro-OMeTAD in perovskite solar cells with enhanced stability

    Directory of Open Access Journals (Sweden)

    Laura Badia

    2014-08-01

    Full Text Available A new iridium complex, IrCp*Cl(PyPyz[TFSI], has been synthesized and used as additive for the hole transporter material, spiro-OMeTAD, in perovskite solar cells. The cells prepared with this Ir additive present higher efficiency than reference cells, and similar to cells prepared with Co additive. We have determined that the presence of metal complexes as additives decreases the recombination rate, as it has been observed by impedance spectroscopy. Very interestingly, while the efficiency after 3 months decreases by 22% and 70% for reference cell and cell with Co additive, respectively, the efficiency of devices containing the Ir additive is only decreased by a 4%.

  14. Ringing phenomenon of the fiber ring resonator.

    Science.gov (United States)

    Ying, Diqing; Ma, Huilian; Jin, Zhonghe

    2007-08-01

    A resonator fiber-optic gyro (R-FOG) is a high-accuracy inertial rotation sensor based on the Sagnac effect. A fiber ring resonator is the core sensing element in the R-FOG. When the frequency of the fiber ring resonator input laser is swept linearly with time, ringing of the output resonance curve is observed. The output field of the fiber ring resonator is derived from the superposition of the light transmitted through the directional coupler directly and the multiple light components circulated in the fiber ring resonator when the frequency of the laser is swept. The amplitude and phase of the output field are analyzed, and it is found that the difference in time for different light components in the fiber ring resonator to reach a point of destructive interference causes the ringing phenomenon. Finally the ringing phenomenon is observed in experiments, and the experimental results agree with the theoretical analysis well.

  15. ASSOCIATIVE RINGS SOLVED AS LIE RINGS

    Directory of Open Access Journals (Sweden)

    M. B. Smirnov

    2011-01-01

    Full Text Available The paper has proved that an associative ring which is solvable of a n- class as a Lie ring has a nilpotent ideal of the nilpotent class not more than 3×10n–2  and a corresponding quotient ring satisfies an identity [[x1, x2, [x3, x4

  16. Radical theory of rings

    CERN Document Server

    Gardner, JW

    2003-01-01

    Radical Theory of Rings distills the most noteworthy present-day theoretical topics, gives a unified account of the classical structure theorems for rings, and deepens understanding of key aspects of ring theory via ring and radical constructions. Assimilating radical theory's evolution in the decades since the last major work on rings and radicals was published, the authors deal with some distinctive features of the radical theory of nonassociative rings, associative rings with involution, and near-rings. Written in clear algebraic terms by globally acknowledged authorities, the presentation

  17. Michel Spiro is appointed director of the IN2P3 and the Department of Nuclear and Particle Physics of the CNRS

    CERN Multimedia

    2003-01-01

    "Michel Spiro was appointed director of the IN2P3, by order of the Minister of Youth, National Education and Research and the Minister of Research and New Technologies on February 17, 2003. He was also appointed director of the Department of Nuclear and Particle Physics of the CNRS by decision of the CNRS Director General on February 21, 2003" (1/2 page).

  18. New spiro (thio barbiturates based on cyclohexanone and bicyclo [3.1.1]heptan-6-one by nonconcerted [1+5] cycloaddition reaction and their conformational structures

    Directory of Open Access Journals (Sweden)

    N. N. Pesyan

    2014-09-01

    Full Text Available Crossed-aldol condensation reaction of aromatic aldehydes with ketones such as; acetone and cyclohexanone leads to the efficient formation of cross conjugated α,β-unsaturated ketones in excellent yield. The intermolecular and then intramolecular Michael addition reaction of α,β-unsaturated ketones derived from acetone and cyclohexanone with (thiobarbituric acids lead to synthesis new type of 7,11-diaryl-2,4-diazaspiro[5.5]undecane-1,3,5,9-tetraone and 2,4-diaryl-1'H-spiro[bicyclo[3.3.1]nonane-3,5'-pyrimidine]-2',4',6',9(3'H-tetraone, respectively in good yield. Structure elucidation is carried out by 1H NMR, 13C NMR, FT-IR, UV-Visible, mass spectroscopy and X-ray crystallography techniques. A possible mechanism of the formation is discussed. The structural conformation also demonstrated by coupling constants derived from dihedral angles between vicinal and geminal protons. The 1H NMR spectra of NH protons of spiro compounds derived from barbituric acid show a broad singlet peak instead, these protons in the spiro compounds derived from thiobarbituric acid show two distinct peaks. DOI: http://dx.doi.org/10.4314/bcse.v28i3.12

  19. Characterization of pore-filling of spiro-MeOTAD in solid-state dye-sensitized solar cells and its consequence in device performance

    KAUST Repository

    Ding, I-Kang

    2009-08-27

    In this paper, the pore filling of spiro-MeOTAD (2,2\\',7,7\\'-tetrakis-(N,N-di-p-methoxyphenylamine)9, 9\\'-spirobifluorene) in mesoporous TiO2 films is quantified for the first time using XPS depth profiling and UVVis absorption spectroscopy. We show that spiro-OMeTAD can penetrate the entire depth of the film, and its concentration is constant throughout the film. We determine that in a 2.5-•m-thick film, the volume of the pores is 60-65% filled. The pores become less filled when thicker films are used. Such filling fraction is much higher than the solution concentration because the excess solution on top of the film can act as a reservoir during the spin coating process. Lastly, we demonstrate that by using a lower spin coating speed and higher spiro-OMeTAD solution concentration, we can increase the filling fraction and consequently the efficiency of the device

  20. Pore-Filling of Spiro-OMeTAD in Solid-State Dye Sensitized Solar Cells: Quantification, Mechanism, and Consequences for Device Performance

    KAUST Repository

    Ding, I-Kang

    2009-08-10

    In this paper, the pore filling of spiro-OMeTAD (2,2′,7,7′- tetrakis-(N,N-di-p-methoxyphenylamine)9,9′-spirobtfIuorene) in mesoporous TiO2 films is quantified for the first time using XPS depth profiling and UV-Vis absorption spectroscopy. It is shown that spiro-OMeTAD can penetrate the entire depth of the film, and its concentration is constant throughout the film. We determine that in a 2.5-μm-thick film, the volume of the pores is 60-65% filled. The pores become less filled when thicker films are used. Such filling fraction is much higher than the solution concentration because the excess solution on top of the film can act as a reservoir during the spin coating process. Lastly, we demonstrate that by using a lower spin coating speed and higher spiro-OMeTAD solution concentration, we can increase the filling fraction and consequently the efficiency of the device. © 2009 WILEY-VCH Verlag GmbH & Co. KGaA.

  1. A facile, efficient, and sustainable chitosan/CaHAp catalyst and one-pot synthesis of novel 2,6-diamino-pyran-3,5-dicarbonitriles.

    Science.gov (United States)

    Maddila, Suresh; Gangu, Kranthi Kumar; Maddila, Surya Narayana; Jonnalagadda, Sreekantha B

    2017-02-01

    A simple and versatile one-pot three-component synthetic protocol is devised for heterocycles, viz. 2,6-diamino-4-substituted-4H-pyran-3,5-dicarbonitrile derivatives, in short reaction times ([Formula: see text]30 min) at room temperature using ethanol as a solvent. This method involves the three-component reaction of malononitrile, substituted aldehydes, and cyanoacetamide catalyzed by chitosan-doped calcium hydroxyapatites (CS/CaHAps) giving good to excellent yields (86-96%). Twelve new pyran derivatives (4a-l) were synthesized and their structures were established and confirmed by different spectroscopic methods ([Formula: see text]H NMR, [Formula: see text]C NMR, [Formula: see text]N NMR, and HRMS). The heterogeneous catalyst, CS/CaHAp, was characterized by various instrumental techniques including XRD, TEM, SEM, and FT-IR and TGA spectroscopies. The catalyst was easily separable and reusable for up to six runs without any apparent loss of activity. The reported protocol has many benefits, such as ease of preparation, use of a green solvent, reduced reaction times, excellent product yields, and operational simplicity.

  2. Structural reassignment, absolute configuration, and conformation of hypurticin, a highly flexible polyacyloxy-6-heptenyl-5,6-dihydro-2H-pyran-2-one.

    Science.gov (United States)

    Mendoza-Espinoza, José Alberto; López-Vallejo, Fabian; Fragoso-Serrano, Mabel; Pereda-Miranda, Rogelio; Cerda-García-Rojas, Carlos M

    2009-04-01

    The structural reassignment, absolute configuration, and conformational behavior of the highly flexible natural product hypurticin (pectinolide E), 6S-[3'S,5'R,6'S-triacetoxy-1Z-heptenyl]-5S-acetoxy-5,6-dihydro-2H-pyran-2-one (1), were ascertained by a molecular modeling protocol, which includes extensive conformational searching, geometry optimization by DFT B3LYP/DGDZVP calculations, and comparison between the theoretical (DFT) and experimental (1)H-(1)H NMR coupling constants. Hyptolide (2), a related cytotoxic 5,6-dihydro-2H-pyran-2-one that increased the S phase of the HeLa cell cycle, was employed as a reference substance to validate the theoretical protocol designed to characterize the 3D properties of compound 1. The related synthetic derivative, tri-O-acetyl-3,6-dideoxy-d-glucose diphenyldithioacetal (14), was prepared by a six-step reaction sequence starting from d-glucose and served as an enantiopure building block to reinforce the structural and configurational assignment of 1. This protocol proved to be an important tool for the structural characterization of highly flexible bioactive polyoxygenated natural products.

  3. 3+ and [Sb13Se16Br2] 5+ - Double and quadruple spiro cubanes from ionic liquids

    KAUST Repository

    Ahmed, Ejaz

    2014-01-08

    The reaction of antimony and selenium in the bromine-rich Lewis acidic ionic liquid [BMIm]Br·4.7AlBr3 (BMIm: 1-butyl-3- methylimidazolium) in the presence of a small amount of NbCl5 at 160 °C yielded dark-red crystals of [Sb7Se8Br 2][AlX4]3. For X = Cl0.15(1)Br 0.85(1), the compound is isostructural to [Sb7S 8Br2][AlCl4]3 [P212 121, a = 12.5132(5) Å, b = 17.7394(6) Å, c = 18.3013(6) Å]. For a higher chlorine content, X = Cl 0.58(1)Br0.42(1), a slightly disordered variant with a bisected unit cell is found [P21212, a = 12.3757(3) Å, b = 17.4116(5) Å, c = 9.0420(2) Å]. The [Sb 7Se8Br2]3+ heteropolycation (C 2 symmetry) is a spiro double-cubane with an antimony atom on the shared corner. From this distorted octahedrally coordinated central atom, tricoordinate selenium and antimony atoms alternate in the bonding sequence. The terminal antimony atoms each bind to a bromine atom. Quantum chemical calculations confirm polar covalent Sb-Se bonding within the cubes and indicate three-center, four-electron bonds for the six-coordinate spiro atoms. The calculated charge distribution reflects the electron-donor role of the antimony atoms. The use of a chlorine-rich ionic liquid resulted in the formation of triclinic [Sb13Se16Br2][AlX4] 5 with X = Cl0.80(1)Br0.20(1) [P$\\\\bar {1}$, a = 9.0842(5) Å, b = 19.607(1) Å, c = 21.511(1) Å, α = 64.116(6), β = 79.768(7), γ = 88.499(7)]. The cationic cluster [Sb13Se16Br2]5+ is a bromine-terminated spiro quadruple-cubane. This 31 atom concatenation of four cubes is assumed to be the largest known discrete main group polycation. A similar reaction in a chloride-free system yielded [Sb7Se 8Br2][Sb13Se16Br2] [AlBr4]8. In its monoclinic structure [P2/c, a = 27.214(5) Å, b = 9.383(2) Å, c = 22.917(4) Å, β = 101.68(1)], the two types of polycations alternate in layers along the a axis. In the series [Sb4+3nSe4+4nBr2](2+n)+, these cations are the members with n = 1 and 3. Copyright © 2014 WILEY-VCH Verlag GmbH & Co. KGa

  4. Stirling engine piston ring

    Science.gov (United States)

    Howarth, Roy B.

    1983-01-01

    A piston ring design for a Stirling engine wherein the contact pressure between the piston and the cylinder is maintained at a uniform level, independent of engine conditions through a balancing of the pressure exerted upon the ring's surface and thereby allowing the contact pressure on the ring to be predetermined through the use of a preloaded expander ring.

  5. Alternative loop rings

    CERN Document Server

    Goodaire, EG; Polcino Milies, C

    1996-01-01

    For the past ten years, alternative loop rings have intrigued mathematicians from a wide cross-section of modern algebra. As a consequence, the theory of alternative loop rings has grown tremendously. One of the main developments is the complete characterization of loops which have an alternative but not associative, loop ring. Furthermore, there is a very close relationship between the algebraic structures of loop rings and of group rings over 2-groups. Another major topic of research is the study of the unit loop of the integral loop ring. Here the interaction between loop rings and group ri

  6. A comprehensive evaluation of potential lung function associated genes in the SpiroMeta general population sample.

    Directory of Open Access Journals (Sweden)

    Ma'en Obeidat

    Full Text Available Lung function measures are heritable traits that predict population morbidity and mortality and are essential for the diagnosis of chronic obstructive pulmonary disease (COPD. Variations in many genes have been reported to affect these traits, but attempts at replication have provided conflicting results. Recently, we undertook a meta-analysis of Genome Wide Association Study (GWAS results for lung function measures in 20,288 individuals from the general population (the SpiroMeta consortium.To comprehensively analyse previously reported genetic associations with lung function measures, and to investigate whether single nucleotide polymorphisms (SNPs in these genomic regions are associated with lung function in a large population sample.We analysed association for SNPs tagging 130 genes and 48 intergenic regions (+/-10 kb, after conducting a systematic review of the literature in the PubMed database for genetic association studies reporting lung function associations.The analysis included 16,936 genotyped and imputed SNPs. No loci showed overall significant association for FEV(1 or FEV(1/FVC traits using a carefully defined significance threshold of 1.3×10(-5. The most significant loci associated with FEV(1 include SNPs tagging MACROD2 (P = 6.81×10(-5, CNTN5 (P = 4.37×10(-4, and TRPV4 (P = 1.58×10(-3. Among ever-smokers, SERPINA1 showed the most significant association with FEV(1 (P = 8.41×10(-5, followed by PDE4D (P = 1.22×10(-4. The strongest association with FEV(1/FVC ratio was observed with ABCC1 (P = 4.38×10(-4, and ESR1 (P = 5.42×10(-4 among ever-smokers.Polymorphisms spanning previously associated lung function genes did not show strong evidence for association with lung function measures in the SpiroMeta consortium population. Common SERPINA1 polymorphisms may affect FEV(1 among smokers in the general population.

  7. Real Closed Rings and Real Closed * Rings

    OpenAIRE

    Capco, Jose

    2007-01-01

    Here we try to distinguish and compare different notions of real closedness mainly one developed by N. Schwartz in his Habilitationschrift and the other developed by A. Sankaranand K. Varadarajan which we shall call real closed *. We stick to the definition of real closed rings as defined and characterized N. Schwartz and we try to determine and characterize real closed rings that are real closed *. The main result is that real closed rings have unique real closure * and that real closure of ...

  8. Synthesis of novel 2-(2-(6-chloro-9H-purin-9-ylethoxy-6-isobutoxy-tetrahydro-2H-pyran-3-ol as a potential antiviral agent

    Directory of Open Access Journals (Sweden)

    A. A. Jarrahpour

    2006-06-01

    Full Text Available In this paper we propose the synthesis of 2-(2-(6-chloro-9H-purin-9-ylethoxy-6-isobutoxy-tetrahydro-2H-pyran-3-ol as a new potential antiviral agent Its structure has been confirmed by IR, 1H-NMR, 13C-NMR, UV and Mass spectroscopic data.

  9. Studies of Grafted and Sulfonated Spiro Poly(isatin-ethersulfone Membranes by Super Acid-Catalyzed Reaction

    Directory of Open Access Journals (Sweden)

    Lei Jin

    2016-03-01

    Full Text Available Spiro poly(isatin-ethersulfone polymers were prepared from isatin and bis-2,6-dimethylphenoxyphenylsulfone by super acid catalyzed polyhydroxyalkylation reactions. We designed and synthesized bis-2,6-dimethylphenoxyphenylsulfone, which is structured at the meta position steric hindrance by two methyl groups, because this structure minimized crosslinking reaction during super acid catalyzed polymerization. In addition, sulfonic acid groups were structured in both side chains and main chains to form better polymer chain morphology and improve proton conductivity. The sulfonation reactions were performed in two steps which are: in 3-bromo-1-propanesulfonic acid potassium salt and in con. sulfuric acid. The membrane morphology was studied by tapping mode atomic force microscope (AFM. The phase difference between the hydrophobic polymer main chain and hydrophilic sulfonated units of the polymer was shown to be the reasonable result of the well phase separated structure. The correlations of proton conductivity, ion exchange capacity (IEC and single cell performance were clearly described with the membrane morphology.

  10. (4S)-4-(3,4-Dichloro?phen?yl)-1?-methyl-4?-phenyl-3,4-dihydronaphthalene-2-spiro-3?-pyrrolidine-2?-spiro-1??-acenaphthyl?ene-1,2??(2H,1??H)-dione

    OpenAIRE

    Murugan, R.; Gunasekaran, B.; Narayanan, S. Sriman; Manivannan, V.

    2008-01-01

    In the title compound, C37H27Cl2NO2, the 3,4-dichloro?phenyl ring makes a dihedral angle of 46.66?(6)? with the phenyl ring. The mol?ecular structure is stabilized by weak intra?molecular C?H?O inter?actions and the crystal structure is stabilized by weak inter?molecular C?H?O inter?actions. The C?C?C?C?C five-membered ring is planar, while the C?C?C?C?N five-membered ring adopts a half-chair conformation.

  11. Groups, rings, modules

    CERN Document Server

    Auslander, Maurice

    2014-01-01

    This classic monograph is geared toward advanced undergraduates and graduate students. The treatment presupposes some familiarity with sets, groups, rings, and vector spaces. The four-part approach begins with examinations of sets and maps, monoids and groups, categories, and rings. The second part explores unique factorization domains, general module theory, semisimple rings and modules, and Artinian rings. Part three's topics include localization and tensor products, principal ideal domains, and applications of fundamental theorem. The fourth and final part covers algebraic field extensions

  12. Synthesis, characterization, and crystal structure of 2-amino-7-methyl-5-oxo-4-phenyl-4,5-dihydropyrano[3,2-c] pyran-3-carbonitrile

    Energy Technology Data Exchange (ETDEWEB)

    Sharma, S. [University of Jammu, X-ray Crystallography Laboratory, Post-Graduate Department of Physics and Electronics (India); Banerjee, B.; Brahmachari, G. [Visva-Bharati (a Central University), Laboratory of Natural Products & Organic Synthesis, Department of Chemistry (India); Kant, Rajni; Gupta, V. K., E-mail: vivek-gupta2k2@hotmail.com [University of Jammu, X-ray Crystallography Laboratory, Post-Graduate Department of Physics and Electronics (India)

    2015-12-15

    2-Amino-7-methyl-5-oxo-4-phenyl-4,5-dihydropyrano[3,2-c] pyran-3-carbonitrile, C{sub 16}H{sub 12}N{sub 2}O{sub 3} is synthesized via one-pot multi-component reaction at room temperature using commercially available urea as inexpensive and environmentally benign organo-catalyst. Its structure is determined by single-crystal X-ray diffraction technique The crystals are monoclinic, a = 10.7357(12), b = 8.7774(8), c = 15.0759(16) Å, β = 103.575(11)°, Z = 4, sp. gr. P2{sub 1}/n, R = 0.0551 for 1696 observed reflections. The crystal structure is stabilized by N–H···N, C–H···O, and C–H···π interactions.

  13. 1,3,5-Trihydroxy-13,13-dimethyl-2H-pyran [7,6-b] xanthone directly targets heat shock protein 27 in hepatocellular carcinoma.

    Science.gov (United States)

    Fu, Wei-Ming; Wang, Wei-Mao; Wang, Hua; Zhu, Xiao; Liang, Yan; Kung, Hsiang-Fu; Zhang, Jin-Fang

    2014-02-01

    We previously showed that the small molecule 1,3,5-trihydroxy-13,13-dimethyl-2H-pyran [7,6-b] xanthone (TDP) induces apoptosis in hepatocellular carcinoma (HCC) by suppressing Hsp27 expression, although the mechanism is not fully understood. To investigate the functional association between TDP and Hsp27 protein in HCC, recombinant Hsp27 protein was incubated with TDP at room temperature, and assayed by mass spectrum (MS) and natural electrophoresis. TDP effectively stimulated Hsp27 to form aggregates ex vitro, leading to suppression of its chaperone activity. The aggregates were degraded by the ubiquitin-proteasome (UPS) pathway. TDP directly interacted with Asp17 and Phe55 in chain C of Hsp27 on the basis of bioinformatic prediction. In conclusion, Hsp27 is a direct target of TDP in its anti-cancer activity, which provides strong support for a clinical application. © 2013 International Federation for Cell Biology.

  14. Birth Control Ring

    Science.gov (United States)

    ... Staying Safe Videos for Educators Search English Español Birth Control Ring KidsHealth / For Teens / Birth Control Ring What's in this article? What Is ... español Anillo vaginal anticonceptivo What Is It? The birth control ring is a soft, flexible, doughnut-shaped ...

  15. Physics of quantum rings

    CERN Document Server

    Fomin, Vladimir M

    2013-01-01

    This book deals with a new class of materials, quantum rings. Innovative recent advances in experimental and theoretical physics of quantum rings are based on the most advanced state-of-the-art fabrication and characterization techniques as well as theoretical methods. The experimental efforts allow to obtain a new class of semiconductor quantum rings formed by capping self-organized quantum dots grown by molecular beam epitaxy. Novel optical and magnetic properties of quantum rings are associated with non-trivial topologies at the nanoscale. An adequate characterization of quantum rings is po

  16. Pure- and mixed-gas propylene/propane permeation properties of spiro- and triptycene-based microporous polyimides

    KAUST Repository

    Swaidan, Ramy Jawdat

    2015-06-03

    Solution-processable polyimides of intrinsic microporosity (PIM-PIs) comprising relatively inflexible and contorted backbones have demonstrated outstanding molecular-sieving behavior in membrane-based separation of gas/gas pairs. In this work, the effects of systematically increasing intra-chain rigidity on the propylene/propane separation properties were compared for PIM-PIs made from 2,3,5,6-tetramethyl-1,4-phenylene diamine (TMPD) and (i) spiro-centered dianhyride (SPDA-TMPD or PIM-PI-1) and (ii) 9,10-diisopropyltriptycene-based dianhydride (TPDA-TMPD or KAUST PI-1). Pure-gas experiments at 2 bar and 35 oC showed significant increases in C3H6 permeability and C3H6/C3H8 selectivity by transitioning from PIM-PI-1 (P(C3H6)=393 Barrer, α(C3H6/C3H8)=6) to KAUST-PI-1 (P(C3H6)=817 Barrer, α(C3H6/C3H8)=16), positioning KAUST-PI-1 considerably above the experimentally observed pure-gas C3H6/C3H8 polymer upper bound. However, 50:50 C3H6/C3H8 mixed-gas feeds induced significant losses in C3H6 permeability and C3H6/C3H8 selectivity relative to the 2 bar pure-gas data for PIM-PI-1 and KAUST-PI-1 as the C3H6/C3H8 selectivity dropped from 6 to 3 and 16 to 5, respectively, at 2 bar C3H6 partial pressure due to plasticization and competitive sorption.

  17. Stereoselective Construction of Spiro-Fused Tricyclic Frameworks by Sequential Reaction of Enynes, Imines, and Diazoalkenes with Rh(I) and Rh(II) Catalysts.

    Science.gov (United States)

    Hato, Yoshio; Oonishi, Yoshihiro; Yamamoto, Yasunori; Nakajima, Kiyohiko; Sato, Yoshihiro

    2016-09-02

    Stereoselective construction of spiro-fused tricyclic compounds from enynes having a tethered imine with diazoalkenes was achieved by Rh(I)- and Rh(II)-catalyzed sequential reactions. This method consists of three reactions, i.e., Rh(I)-catalyzed cyclization of enynes with a tethered imine, Rh(II)-catalyzed cyclopropanation with diazoalkenes, and Cope rearrangement. Notably, the sequential reactions can be operated in one pot, in which Rh(I) and Rh(II) catalysts work in relay without any serious catalyst deactivation to afford the spirocycles in a stereoselective manner.

  18. Microwave-assisted reductive cyclization: An easy entry to the indoloquinolines and spiro[2H-indole-2,30-oxindole].

    Digital Repository Service at National Institute of Oceanography (India)

    Parvatkar, P.T.; Majik, M.S.

    ., vol.4; 2014; 22481-22486 Microwave-assisted reductive cyclization: An easy entry to the indoloquinolines and spiro[2H-indole-2,3’-oxindole] Prakash T. Parvatkar* and Mahesh S. Majik Bio-organic Chemistry Laboratory, CSIR-National Institute... of this cyclization step under MW assisted condition delivered similar results indicating the reproducibility of this methodology. In case of entry 4 (Table 1), low yields of the two products (19 and 15) and no formation of compound 20 may be due to the temperature...

  19. Synthesis of spiro[isoindole-1,5’-isoxazolidin]-3(2H-ones as potential inhibitors of the MDM2-p53 interaction

    Directory of Open Access Journals (Sweden)

    Salvatore V. Giofrè

    2016-12-01

    Full Text Available A series of spiro[isoindole-1,5-isoxazolidin]-3(2H-ones has been synthesized by 1,3-dipolar cycloaddition of N-benzylnitrone with isoindolin-3-methylene-1-ones. The regio- and stereoselectivity of the process have been rationalized by computational methods. The obtained compounds show cytotoxic properties and antiproliferative activity in the range of 9–22 μM. Biological tests suggest that the antitumor activity could be linked to the inhibition of the protein–protein p53-MDM2 interaction. Docking measurements support the biological data.

  20. A Yellow-Emitting Homoleptic Iridium(III) Complex Constructed from a Multifunctional Spiro Ligand for Highly Efficient Phosphorescent Organic Light-Emitting Diodes.

    Science.gov (United States)

    Ren, Bao-Yi; Guo, Run-Da; Zhong, Dao-Kun; Ou, Chang-Jin; Xiong, Gang; Zhao, Xiang-Hua; Sun, Ya-Guang; Jurow, Matthew; Kang, Jun; Zhao, Yi; Li, Sheng-Biao; You, Li-Xin; Wang, Lin-Wang; Liu, Yi; Huang, Wei

    2017-07-17

    To suppress concentration quenching and to improve charge-carrier injection/transport in the emission layer (EML) of phosphorescent organic light-emitting diodes (PhOLEDs), a facial homoleptic iridium(III) complex emitter with amorphous characteristics was designed and prepared in one step from a multifunctional spiro ligand containing spiro[fluorene-9,9'-xanthene] (SFX) unit. Single-crystal X-ray analysis of the resulting fac-Ir(SFXpy) 3 complex revealed an enlarged Ir···Ir distance and negligible intermolecular π-π interactions between the spiro ligands. The emitter exhibits yellow emission and almost equal energy levels compared to the commercial phosphor iridium(III) bis(4-phenylthieno[3,2-c]pyridinato-N,C 2 ')acetylacetonate (PO-01). Dry-processed devices using a common host, 4,4'-bis(N-carbazolyl)-1,1'-biphenyl, and the fac-Ir(SFXpy) 3 emitter at a doping concentration of 15 wt % exhibited a peak performance of 46.2 cd A -1 , 36.3 lm W -1 , and 12.1% for the current efficiency (CE), power efficiency (PE), and external quantum efficiency (EQE), respectively. Compared to control devices using PO-01 as the dopant, the fac-Ir(SFXpy) 3 -based devices remained superior in the doping range between 8 and 15 wt %. The current densities went up with increasing doping concentration at the same driving voltage, while the roll-offs remain relatively low even at high doping levels. The superior performance of the new emitter-based devices was ascribed to key roles of the spiro ligand for suppressing aggregation and assisting charge-carrier injection/transport. Benefiting from the amorphous stability of the emitter, the wet-processed device also exhibited respectful CE, PE, and EQE of 32.2 cd A -1 , 22.1 lm W -1 , and 11.3%, respectively, while the EQE roll-off was as low as 1.7% at the luminance of 1000 cd m -2 . The three-dimensional geometry and binary-conjugation features render SFX the ideal multifunctional module for suppressing concentration quenching

  1. A spiro-bifluorene based 3D electron acceptor with dicyanovinylene substitution for solution-processed non-fullerene organic solar cells

    KAUST Repository

    Xia, Debin

    2015-04-20

    A novel electron acceptor, namely 2,2′-(12H,12′H-10,10′-spirobi[indeno[2,1-b]fluorene]-12,12′-diylidene)dimalononitrile (4CN-spiro), exhibiting a three-dimensional molecular structure was synthesized and its thermal, photophysical, electrochemical, crystal, and photovoltaic properties were investigated. The novel acceptor exhibits excellent thermal stability with a decomposition temperature of 460 °C, an absorption extending to 600 nm, and a LUMO level of −3.63 eV. Solution processed bulk-heterojunction (BHJ) organic solar cells were fabricated using 4CN-spiro as an acceptor and polythieno[3,4-b]-thiophene-co-benzodithiophene (PTB7) as a donor polymer. The effect of the donor-to-acceptor ratio and processing conditions on the device performance was investigated. A device processed from tetrachloroethane with a donor to acceptor weight ratio of 1 : 1 yielded a power conversion efficiency (PCE) of 0.80%.

  2. CERN Library | Sandrine Saison-Marsollier, Corinne Pralavorio and Michel Spiro present "Si tu devais me dessiner l’Univers…" | 10 December

    CERN Multimedia

    CERN Library

    2015-01-01

    Sandrine Saison-Marsollier, Corinne Pralavorio and Michel Spiro present Si tu devais me dessiner l’Univers… Thursday, 10 December 2015 at 3.30 p.m. at the Library, Building 52-1-052 Tea and coffee will be served at 3 p.m. In 2014, CERN launched an art competition for local primary schools. Children were asked to come up with questions about the universe, matter and working as a researcher. The initiative was so successful that it has been turned into a book that teachers can explore with their pupils, discussing the questions and discovering the answers together. The book is laid out in double-page spreads, with the child’s illustration on one page and the question and its answer opposite. The answers take the form of a short text written by Michel Spiro, the competition’s scientific advisor, together with a cultural quotation whose purpose is to highlight the close association between science, literature and philosophy. The questions include: What was there...

  3. Brane world black rings

    International Nuclear Information System (INIS)

    Sahay, Anurag; Sengupta, Gautam

    2007-01-01

    Five dimensional neutral rotating black rings are described from a Randall-Sundrum brane world perspective in the bulk black string framework. To this end we consider a rotating black string extension of a five dimensional black ring into the bulk of a six dimensional Randall-Sundrum brane world with a single four brane. The bulk solution intercepts the four brane in a five dimensional black ring with the usual curvature singularity on the brane. The bulk geodesics restricted to the plane of rotation of the black ring are constructed and their projections on the four brane match with the usual black ring geodesics restricted to the same plane. The asymptotic nature of the bulk geodesics are elucidated with reference to a bulk singularity at the AdS horizon. We further discuss the description of a brane world black ring as a limit of a boosted bulk black 2 brane with periodic identification

  4. Token Ring Project

    Directory of Open Access Journals (Sweden)

    Adela Ionescu

    2007-01-01

    Full Text Available Ring topology is a simple configuration used to connect processes that communicate among themselves. A number of network standards such as token ring, token bus, and FDDI are based on the ring connectivity. This article will develop an implementation of a ring of processes that communicate among themselves via pipe links. The processes are nodes in the ring. Each process reads from its standard input and writes in its standard output. N-1 process redirects the its standard output to a standard input of the process through a pipe. When the ring-structure is designed, the project can be extended to simulate networks or to implement algorithms for mutual exclusion

  5. Token ring technology report

    CERN Document Server

    2013-01-01

    Please note this is a Short Discount publication. This report provides an overview of the IBM Token-Ring technology and products built by IBM and compatible vendors. It consists of two sections: 1. A summary of the design trade-offs for the IBM Token-Ring. 2. A summary of the products of the major token-ring compatible vendors broken down by adapters and components, wiring systems, testing, and new chip technology.

  6. Spannungsgesteuerter Ring-Oszillator

    OpenAIRE

    Wang, Z.; Thiede, A.

    1999-01-01

    The oscillator (1) of integrated monolithic design has several analogue amplifier units (2) connected in a ring. The individual amplifiers are frequency selective in regard to a resonance frequency. The phase displacements of the amplifiers are chosen so that the total phase displacement over the ring at the resonance frequencies of the amplifiers amounts to 3600 or a whole number multiple of that. The number of amplifiers selected corresponds to the overall quality factor for the ring oscill...

  7. Radioactive gold ring dermatitis

    Energy Technology Data Exchange (ETDEWEB)

    Miller, R.A.; Aldrich, J.E. (Dalhousie Univ., Halifax, Nova Scotia (Canada))

    1990-08-01

    A superficial squamous cell carcinoma developed in a woman who wore a radioactive gold ring for more than 30 years. Only part of the ring was radioactive. Radiation dose measurements indicated that the dose to basal skin layer was 2.4 Gy (240 rad) per week. If it is assumed that the woman continually wore her wedding ring for 37 years since purchase, she would have received a maximum dose of approximately 4600 Gy.

  8. Vortex and source rings

    DEFF Research Database (Denmark)

    Branlard, Emmanuel Simon Pierre

    2017-01-01

    The velocity field, vector potential and velocity gradient of a vortex ring is derived in this chapter. The Biot-Savart law for the vector potential and velocity is expressed in a first section. Then, the flow is derived at specific locations: on the axis, near the axis and in the far field where...... is dedicated to vortex rings. Source rings are only briefly mentioned....

  9. Radioactive gold ring dermatitis

    International Nuclear Information System (INIS)

    Miller, R.A.; Aldrich, J.E.

    1990-01-01

    A superficial squamous cell carcinoma developed in a woman who wore a radioactive gold ring for more than 30 years. Only part of the ring was radioactive. Radiation dose measurements indicated that the dose to basal skin layer was 2.4 Gy (240 rad) per week. If it is assumed that the woman continually wore her wedding ring for 37 years since purchase, she would have received a maximum dose of approximately 4600 Gy

  10. The ring laser gyro

    Science.gov (United States)

    Chow, W. W.; Gea-Banacloche, J.; Pedrotti, L. M.; Sanders, V. E.; Schleich, W.; Scully, M. O.

    1985-01-01

    This paper presents a review of both active and passive ring laser devices. The operating principles of the ring laser are developed and discussed, with special emphasis given to the problems associated with the achievement of greater sensitivity and stability. First-principle treatments of the nature of quantum noise in the ring laser gyro and various methods designed to avoid low-rotation-rate lock-in are presented. Descriptions of state-of-the-art devices and current and proposed applications (including a proposed test of metric theories of gravity using a passive cavity ring laser) are given.

  11. Reappraising the structures and distribution of metabolites from black aspergilli containing uncommon 2-benzyl-4H-pyran-4-one and 2-benzylpyridin-4(1H)-one systems.

    Science.gov (United States)

    Henrikson, Jon C; Ellis, Trevor K; King, Jarrod B; Cichewicz, Robert H

    2011-09-23

    To date, natural products containing 2-benzyl-4H-pyran-4-one and 2-benzylpyridin-4(1H)-one substructures have been encountered in relatively few fungi outside of the black aspergilli clade. While exploring the occurrence of these compounds among Aspergillus spp., it was determined that the structures of the unusual furopyrrols tensidols A and B (5 and 6) and JBIR-86 and JBIR-87 (9 and 10) were incorrect and should be reassigned as 2-benzyl-4H-pyran-4-ones (7, 8, 11e, and 12, respectively). The origin of the unique N-phenyl groups in the 2-benzylpyridin-4(1H)-ones nygerones A and B (1 and 2) were also examined, and it was established that N-phenylamides added to the culture medium were suitable substrates for generating these metabolites; however, this phenomenon remained limited to a single fungus in our collection (Aspergillus niger ATCC 1015). A variety of 2-benzyl-4H-pyran-4-ones and 2-benzylpyridin-4(1H)-ones were detected among the black aspergilli, but only pestalamide B (13) was found in all 11 of the tested strains. These metabolites, as well as a group of synthetic analogues, demonstrated weak antifungal activity against several Candida strains, Aspergillus flavus, and Aspergillus fumigatus.

  12. Reaction of 1-substituted 3-aminoquinoline-2,4-diones with isothiocyanates. An easy pathway to generate novel 2-thioxo-1′H-spiro[imidazoline-5,3′-indole]-2,2′-diones

    Czech Academy of Sciences Publication Activity Database

    Klásek, A.; Mrkvička, V.; Lyčka, A.; Mikšík, Ivan; Růžička, A.

    2009-01-01

    Roč. 65, č. 25 (2009), s. 4908-4916 ISSN 0040-4020 Grant - others:GA ČR(CZ) GA203/07/0320 Institutional research plan: CEZ:AV0Z50110509 Keywords : enamides * thiourea derivatives * spiro-heterocycles Subject RIV: CC - Organic Chemistry Impact factor: 3.219, year: 2009

  13. EBT ring physics

    International Nuclear Information System (INIS)

    Uckan, N.A.

    1980-04-01

    This workshop attempted to evaluate the status of the current experimental and theoretical understanding of hot electron ring properties. The dominant physical processes that influence ring formation, scaling, and their optimal behavior are also studied. Separate abstracts were prepared for each of the 27 included papers

  14. Children of Sex Rings.

    Science.gov (United States)

    Hunt, Patricia; Baird, Margaret

    1990-01-01

    Outlines three major differentiating categories of children who were sexually abused by sex rings: level of fear, ability to trust, and disclosure confusion. Addresses denial and resistance regarding child sexual exploitation by a ring among practitioners in the child welfare system. (Author/BB)

  15. Illustration of Saturn's Rings

    Science.gov (United States)

    2001-01-01

    This illustration shows a close-up of Saturn's rings. These rings are thought to have formed from material that was unable to form into a Moon because of tidal forces from Saturn, or from a Moon that was broken up by Saturn's tidal forces.

  16. Relativistic ring models

    Energy Technology Data Exchange (ETDEWEB)

    Ujevic, Maximiliano [Universidade Federal do ABC (UFABC), Santo Andre, SP (Brazil). Centro de Ciencias Naturais e Humanas; Letelier, Patricio S.; Vogt, Daniel [Universidade Estadual de Campinas (UNICAMP), SP (Brazil). Inst. de Matematica, Estatistica e Computacao Cientifica. Dept. de Matematica Aplicada

    2011-07-01

    Full text: Relativistic thick ring models are constructed using previously found analytical Newtonian potential-density pairs for flat rings and toroidal structures obtained from Kuzmin-Toomre family of discs. This was achieved by inflating previously constructed Newtonian ring potentials using the transformation |z|{yields}{radical}z{sup 2} + b{sup 2}, and then finding their relativistic analog. The models presented have infinite extension but the physical quantities decays very fast with the distance, and in principle, one could make a cut-off radius to consider it finite. In particular, we present systems with one ring, two rings and a disc with a ring. Also, the circular velocity of a test particle and its stability when performing circular orbits are presented in all these models. Using the Rayleigh criterion of stability of a fluid at rest in a gravitational field, we find that the different systems studied present a region of non-stability that appears in the intersection of the disc and the ring, and between the rings when they become thinner. (author)

  17. Imaging rings in ring imaging Cherenkov counters

    Energy Technology Data Exchange (ETDEWEB)

    Ratcliff, Blair N

    2002-11-25

    The general concepts used to form images in Ring Imaging Cherenkov (RICH) counters are described and their performance properties compared. Particular attention is paid to issues associated with imaging in the time dimension, especially in Detectors of Internally Reflected Cherenkov light (DIRCs).

  18. Rings and their modules

    CERN Document Server

    Bland, Paul E

    2011-01-01

    This book is an introduction to the theory of rings and modules that goes beyond what one normally obtains in a graduate course in abstract algebra. In addition to the presentation of standard topics in ring and module theory, it also covers category theory, homological algebra and even more specialized topics like injective envelopes and projective covers, reflexive modules and quasi-Frobenius rings, and graded rings and modules. The book is a self-contained volume written in a very systematic style: allproofs are clear and easy for the reader to understand and allarguments are based onmaterials contained in the book. A problem sets follow each section. It is suitable for graduate and PhD students who have chosen ring theory for their research subject.

  19. Ring chromosome 13

    DEFF Research Database (Denmark)

    Brandt, C A; Hertz, Jens Michael; Petersen, M B

    1992-01-01

    A stillborn male child with anencephaly and multiple malformations was found to have the karyotype 46,XY,r(13) (p11q21.1). The breakpoint at 13q21.1, determined by high resolution banding, is the most proximal breakpoint ever reported in patients with ring chromosome 13. In situ hybridisation...... with the probe L1.26 confirmed the derivation from chromosome 13 and DNA polymorphism analysis showed maternal origin of the ring chromosome. Our results, together with a review of previous reports of cases with ring chromosome 13 with identified breakpoints, could neither support the theory of distinct clinical...

  20. Faithfully quadratic rings

    CERN Document Server

    Dickmann, M

    2015-01-01

    In this monograph the authors extend the classical algebraic theory of quadratic forms over fields to diagonal quadratic forms with invertible entries over broad classes of commutative, unitary rings where -1 is not a sum of squares and 2 is invertible. They accomplish this by: (1) Extending the classical notion of matrix isometry of forms to a suitable notion of T-isometry, where T is a preorder of the given ring, A, or T = A^2. (2) Introducing in this context three axioms expressing simple properties of (value) representation of elements of the ring by quadratic forms, well-known to hold in

  1. Synthesis and crystal structure of a spiro amine: 3,9,12-triaza-6-azoniaspiro[5,8]tetradecane chloride trihydrochloride dihydrates

    DEFF Research Database (Denmark)

    Springborg, Johan; Kofod, Pauli; Olsen, Carl Erik

    1995-01-01

    A spiro amine, 3,9,12-triaza-6-azoniaspiro[5.8]tetradecane chloride trihydrochloride dihydrate, was synthesized from 1-(toluenesulfonyl)-1,3,7-triazacyclononane and N,O,O'-tris(p-toluenesulfonyl)bis(2-hydroxyethyl)amine. The structure of 3,9,12-triaza-6-azoniaspiro[5.8]tetradecane chloride trihyd....... consts. have been detd. potentiometrically, and the following values were obtained: pKa1 = 0.55(6), pKa2 = 5.23(3), pKa3 = 7.11(5) (1 M NaCl, 25 DegC). The 13C NMR spectrum is in agreement with a time-averaged C2v symmetry in soln....

  2. The g-2 ring

    CERN Multimedia

    1974-01-01

    The precise measurement of "g-2", the anomalous magnetic moment of the muon, required a special muon storage ring with electrostatic focussing and very accurate knowledge of the magnetic bending field. For more details see under photo 7405430.

  3. Saturn's dynamic D ring

    Science.gov (United States)

    Hedman, M.M.; Burns, J.A.; Showalter, M.R.; Porco, C.C.; Nicholson, P.D.; Bosh, A.S.; Tiscareno, M.S.; Brown, R.H.; Buratti, B.J.; Baines, K.H.; Clark, R.

    2007-01-01

    The Cassini spacecraft has provided the first clear images of the D ring since the Voyager missions. These observations show that the structure of the D ring has undergone significant changes over the last 25 years. The brightest of the three ringlets seen in the Voyager images (named D72), has transformed from a narrow, <40-km wide ringlet to a much broader and more diffuse 250-km wide feature. In addition, its center of light has shifted inwards by over 200 km relative to other features in the D ring. Cassini also finds that the locations of other narrow features in the D ring and the structure of the diffuse material in the D ring differ from those measured by Voyager. Furthermore, Cassini has detected additional ringlets and structures in the D ring that were not observed by Voyager. These include a sheet of material just interior to the inner edge of the C ring that is only observable at phase angles below about 60??. New photometric and spectroscopic data from the ISS (Imaging Science Subsystem) and VIMS (Visual and Infrared Mapping Spectrometer) instruments onboard Cassini show the D ring contains a variety of different particle populations with typical particle sizes ranging from 1 to 100 microns. High-resolution images reveal fine-scale structures in the D ring that appear to be variable in time and/or longitude. Particularly interesting is a remarkably regular, periodic structure with a wavelength of ??? 30 ?? km extending between orbital radii of 73,200 and 74,000 km. A similar structure was previously observed in 1995 during the occultation of the star GSC5249-01240, at which time it had a wavelength of ??? 60 ?? km. We interpret this structure as a periodic vertical corrugation in the D ring produced by differential nodal regression of an initially inclined ring. We speculate that this structure may have formed in response to an impact with a comet or meteoroid in early 1984. ?? 2006 Elsevier Inc. All rights reserved.

  4. Child sex rings.

    OpenAIRE

    Wild, N J; Wynne, J M

    1986-01-01

    Details of 11 child sex rings identified in one working class community were obtained by interviewing investigating police officers and examining health and social services records. The rings contained 14 adult male perpetrators and 175 children aged 6-15 years. Most perpetrators used child ringleaders to recruit victims; others became a "family friend" or obtained a position of authority over children. Secrecy was encouraged and bribery, threats, and peer pressure used to induce participatio...

  5. Storage ring group summary

    International Nuclear Information System (INIS)

    King, N.M.

    1980-01-01

    The Storage Ring Group set out to identify and pursue salient problems in accelerator physics for heavy ion fusion, divorced from any particular reference design concept. However, it became apparent that some basic parameter framework was required to correlate the different study topics. As the Workshop progressed, ring parameters were modified and updated. Consequently, the accompanying papers on individual topics will be found to refer to slightly varied parameters, according to the stage at which the different problems were tackled

  6. Matrimonial ring structures

    OpenAIRE

    Hamberger, Klaus; Houseman, Michael; Daillant, Isabelle; White, Douglas R.; Barry, Laurent

    2006-01-01

    The paper deals with matrimonial rings, a particular kind of cycles in kinship networks which result when spouses are linked to each other by ties of consanguinity or affinity. By taking a network-analytic perspective, the paper endeavours to put this classical issue of structural kinship theory on a general basis, such as to allow conclusions which go beyond isolated discussions of particular ring types (like "cross-cousin marriage", "sister exchange", and so forth). The paper provides a def...

  7. Design, synthesis and biological studies of a library of NK1-Receptor Ligands Based on a 5-arylthiosubstituted 2-amino-4,6-diaryl-3-cyano-4H-pyran core: Switch from antagonist to agonist effect by chemical modification.

    Science.gov (United States)

    Recio, Rocío; Vengut-Climent, Empar; Mouillac, Bernard; Orcel, Hélène; López-Lázaro, Miguel; Calderón-Montaño, José Manuel; Álvarez, Eleuterio; Khiar, Noureddine; Fernández, Inmaculada

    2017-09-29

    A library of 5-arylthiosubstituted 2-amino-4,6-diaryl-3-cyano-4H-pyrans has been synthesized as a new family of non-peptide NK1 receptor ligands by a one-pot cascade process. Their biological effects via interaction with the NK1 receptor were experimentally determined as percentage of inhibition (for antagonists) and percentage of activation (for agonists), compared to the substance P (SP) effect, in IPone assay. A set of these amino compounds was found to inhibit the action of SP, and therefore can be considered as a new family of SP-antagonists. Interestingly, the acylation of the 2-amino position causes a switch from antagonist to agonist activity. The 5-phenylsulfonyl-2-amino derivative 17 showed the highest antagonist activity, while the 5-p-tolylsulfenyl-2-trifluoroacetamide derivative 20R showed the highest agonist effect. As expected, in the case of the 5-sulfinylderivatives, there was an enantiomeric discrimination in favor of one of the two enantiomers, specifically those with (S S ,R C ) configuration. The anticancer activity studies assessed by using human A-549 lung cancer cells and MRC-5 non-malignant lung fibroblasts, revealed a statistically significant selective cytotoxic effect of some of these 2-amino-4H-pyran derivatives toward the lung cancer cells. These studies demonstrated that the newly synthesized 4H-pyran derivatives can be used as a starting point for the synthesis of novel SP-antagonists with higher anticancer activity in the future. Copyright © 2017 Elsevier Masson SAS. All rights reserved.

  8. BERKELEY: ALS ring

    International Nuclear Information System (INIS)

    Anon.

    1993-01-01

    Everybody at Lawrence Berkeley Laboratory's Center for Beam Physics is pleased with the rapid progress in commissioning LBL's Advanced Light Source (ALS) electron storage ring, the foundation for this third-generation synchrotron radiation facility. Designed for a maximum current of 400 mA, the ALS storage ring reached 407 mA just 24 days after storing the first beam on 16 March. ALS construction as a US Department of Energy (DOE) national user facility to provide high-brightness vacuum ultra-violet and soft x-ray radiation began in October 1987. One technical requirement marking project completion was to accumulate a 50-mA current in the storage ring. The ALS passed this milestone on 24 March, a week ahead of the official deadline. Once injected, the electron beam decays quasi-exponentially primarily because of interactions with residual gas molecules in the storage-ring vacuum chamber. Eventually, when the pressure in the vacuum chamber with beam decreases toward the expected operating level of 1 nano Torr, it will only be necessary to refill the storage ring at intervals of four to eight hours. At present the vacuum is improving rapidly as surfaces are irradiated (scrubbed) by the synchrotron radiation itself. At 100 mA, beam lifetime was about one hour (9 April)

  9. Ultrasound promoted one-pot synthesis of 2-amino-4,8-dihydropyrano[3,2-b]pyran-3-carbonitrile scaffolds in aqueous media: a complementary 'green chemistry' tool to organic synthesis.

    Science.gov (United States)

    Banitaba, Sayed Hossein; Safari, Javad; Khalili, Shiva Dehghan

    2013-01-01

    A green and simple approach to assembling of 2-amino-4,8-dihydropyrano[3,2-b]pyran-3-carbonitrile scaffolds via three-component reaction of kojic acid, malononitrile, and aromatic aldehydes in aqueous media under ultrasound irradiation is described. The combinatorial synthesis was achieved for this methodology with applying ultrasound irradiation while making use of water as green solvent. In comparison to conventional methods, experimental simplicity, good functional group tolerance, excellent yields, short routine, and selectivity without the need for a transition metal or base catalyst are prominent features of this green procedure. Copyright © 2012 Elsevier B.V. All rights reserved.

  10. A Facile Synthesis of New 2-Amino-4H-pyran-3-carbonitriles by a One-Pot Reaction of ,′-Bis(arylidene Cycloalkanones and Malononitrile in the Presence of KCO

    Directory of Open Access Journals (Sweden)

    Zahed Karimi-Jaberi

    2012-01-01

    Full Text Available A rapid and environmentally friendly method is developed for the synthesis of a series of new substituted 2-amino-4H-pyran-3-carbonitriles through a one-pot condensation of malononitrile and ,-bis(arylidene cycloalkanones in ethanol by using K2CO3 as a catalyst. Short experimental reaction times, excellent yields, no need to use cumbersome apparatus for purification of the products, and inexpensiveness and commercially availability of the catalyst are the advantages of this method.

  11. Almost ring theory

    CERN Document Server

    2003-01-01

    This book develops thorough and complete foundations for the method of almost etale extensions, which is at the basis of Faltings' approach to p-adic Hodge theory. The central notion is that of an "almost ring". Almost rings are the commutative unitary monoids in a tensor category obtained as a quotient V-Mod/S of the category V-Mod of modules over a fixed ring V; the subcategory S consists of all modules annihilated by a fixed ideal m of V, satisfying certain natural conditions. The reader is assumed to be familiar with general categorical notions, some basic commutative algebra and some advanced homological algebra (derived categories, simplicial methods). Apart from these general prerequisites, the text is as self-contained as possible. One novel feature of the book - compared with Faltings' earlier treatment - is the systematic exploitation of the cotangent complex, especially for the study of deformations of almost algebras.

  12. Decay ring design

    CERN Document Server

    Chancé, A; Bouquerel, E; Hancock, S; Jensen, E

    The study of the neutrino oscillation between its different flavours needs pureand very intense fluxes of high energy, well collimated neutrinos with a welldetermined energy spectrum. A dedicated machine seems to be necessarynowadays to reach the required flux. A new concept based on the β-decayof radioactive ions which were accelerated in an accelerator chain was thenproposed. After ion production, stripping, bunching and acceleration, the unstableions are then stored in a racetrack-shaped superconducting decay ring.Finally, the ions are accumulated in the decay ring until being lost. The incomingbeam is merged to the stored beam by using a specific RF system, whichwill be presented here.We propose here to study some aspects of the decay ring, such as its opticalproperties, its RF system or the management of the losses which occur in thering (mainly by decay or by collimation).

  13. Peniciadametizine A, a Dithiodiketopiperazine with a Unique Spiro[furan-2,7'-pyrazino[1,2-b][1,2]oxazine] Skeleton, and a Related Analogue, Peniciadametizine B, from the Marine Sponge-Derived Fungus Penicillium adametzioides.

    Science.gov (United States)

    Liu, Yang; Mándi, Attila; Li, Xiao-Ming; Meng, Ling-Hong; Kurtán, Tibor; Wang, Bin-Gui

    2015-06-05

    Peniciadametizine A (1); a new dithiodiketopiperazine derivative possessing a unique spiro[furan-2,7'-pyrazino[1,2-b][1,2]oxazine] skeleton, together with a highly oxygenated new analogue, peniciadametizine B (2); as well as two known compounds, brasiliamide A (3); and viridicatumtoxin (4), were isolated and identified from Penicillium adametzioides AS-53, a fungus obtained from an unidentified marine sponge. The unambiguous assignment of the relative and absolute configuration for the spiro center C-2 of compound 1 was solved by the combination of NMR and ECD measurements with Density-Functional Theory (DFT) conformational analysis and Time-Dependent Density-Functional Theory-Electronic Circular Dichroism (TDDFT-ECD) calculations. The spiro[furan-2,7'-pyrazino[1,2-b][1,2]oxazine] skeleton of 1 has not been reported yet among natural products and the biosynthetic pathway for 1 and 2 was discussed. Compounds 1 and 2 showed inhibitory activity against the pathogenic fungus Alternaria brassicae.

  14. Fusion rings and fusion ideals

    DEFF Research Database (Denmark)

    Andersen, Troels Bak

    This dissertation investigates fusion rings, which are Grothendieck groups of rigid, monoidal, semisimple, abelian categories. Special interest is in rational fusion rings, i.e., fusion rings which admit a finite basis, for as commutative rings they may be presented as quotients of polynomial rings...... by the so-called fusion ideals. The fusion rings of Wess-Zumino-Witten models have been widely studied and are well understood in terms of precise combinatorial descriptions and explicit generating sets of the fusion ideals. They also appear in another, more general, setting via tilting modules for quantum...

  15. Fusion Rings for Quantum Groups

    DEFF Research Database (Denmark)

    Andersen, Henning Haahr; Stroppel, Catharina

    2012-01-01

    We study the fusion rings of tilting modules for a quantum group at a root of unity modulo the tensor ideal of negligible tilting modules. We identify them in type A with the combinatorial rings from [12] and give a similar description of the sp2n-fusion ring in terms of noncommutative symmetric...... functions. Moreover we give a presentation of all fusion rings in classical types as quotients of polynomial rings. Finally we also compute the fu- sion rings for type G2....

  16. Lattices for antiproton rings

    International Nuclear Information System (INIS)

    Autin, B.

    1984-01-01

    After a description of the constraints imposed by the cooling of Antiprotons on the lattice of the rings, the reasons which motivate the shape and the structure of these machines are surveyed. Linear and non-linear beam optics properties are treated with a special amplification to the Antiproton Accumulator. (orig.)

  17. Flushing Ring for EDM

    Science.gov (United States)

    Earwood, L.

    1985-01-01

    Removing debris more quickly lowers cutting time. Operation, cutting oil and pressurized air supplied to ring placed around workpiece. Air forces oil through small holes and agitates oil as it flows over workpiece. High flow rate and agitation dislodge and remove debris. Electrical discharge removes material from workpiece faster.

  18. SXLS storage ring design

    International Nuclear Information System (INIS)

    Anon.

    1991-01-01

    X-ray lithography has emerged as a strong candidate to meet the demands of ever finer linewidths on integrated circuits, particularly for linewidths less than .25 microns. Proximity printing X-ray lithography makes use of soft X-rays to shadow print an image of a mask onto a semiconductor wafer to produce integrated circuits. To generate the required X-rays in sufficient quantities to make commercial production viable, electron storage rings have been proposed as the soft X-ray sources. Existing storage rings have been used to do the initial development work and the success of these efforts has led the lithographers to request that new rings be constructed that are dedicated to X-ray lithography. As a result of a series of workshops held at BNL [10.3] which were attended by both semiconductor and accelerator scientists, the following set of zeroth order specifications' on the light and electron beam of a storage ring for X-ray lithography were developed: critical wavelength of light: λ c = 6 to 10 angstroms, white light power: P = 0.25 to 2.5 watts/mrad, horizontal collection angle per port: θ = 10 to 50 mrad, electron beam sizes: σ x ∼ σ y y ' < 1 mrad

  19. Ring Bubbles of Dolphins

    Science.gov (United States)

    Shariff, Karim; Marten, Ken; Psarakos, Suchi; White, Don J.; Merriam, Marshal (Technical Monitor)

    1996-01-01

    The article discusses how dolphins create and play with three types of air-filled vortices. The underlying physics is discussed. Photographs and sketches illustrating the dolphin's actions and physics are presented. The dolphins engage in this behavior on their own initiative without food reward. These behaviors are done repeatedly and with singleminded effort. The first type is the ejection of bubbles which, after some practice on the part of the dolphin, turn into toroidal vortex ring bubbles by the mechanism of baroclinic torque. These bubbles grow in radius and become thinner as they rise vertically to the surface. One dolphin would blow two in succession and guide them to fuse into one. Physicists call this a vortex reconnection. In the second type, the dolphins first create an invisible vortex ring in the water by swimming on their side and waving their tail fin (also called flukes) vigorously. This vortex ring travels horizontally in the water. The dolphin then turns around, finds the vortex and injects a stream of air into it from its blowhole. The air "fills-out" the core of the vortex ring. Often, the dolphin would knock-off a smaller ring bubble from the larger ring (this also involves vortex reconnection) and steer the smaller ring around the tank. One other dolphin employed a few other techniques for planting air into the fluke vortex. One technique included standing vertically in the water with tail-up, head-down and tail piercing the free surface. As the fluke is waved to create the vortex ring, air is entrained from above the surface. Another technique was gulping air in the mouth, diving down, releasing air bubbles from the mouth and curling them into a ring when they rose to the level of the fluke. In the third type, demonstrated by only one dolphin, the longitudinal vortex created by the dorsal fin on the back is used to produce 10-15 foot long helical bubbles. In one technique she swims in a curved path. This creates a dorsal fin vortex since

  20. FUZZY RINGS AND ITS PROPERTIES

    Directory of Open Access Journals (Sweden)

    Karyati Karyati

    2017-01-01

      One of algebraic structure that involves a binary operation is a group that is defined  an un empty set (classical with an associative binary operation, it has identity elements and each element has an inverse. In the structure of the group known as the term subgroup, normal subgroup, subgroup and factor group homomorphism and its properties. Classical algebraic structure is developed to algebraic structure fuzzy by the researchers as an example semi group fuzzy and fuzzy group after fuzzy sets is introduced by L. A. Zadeh at 1965. It is inspired of writing about semi group fuzzy and group of fuzzy, a research on the algebraic structure of the ring is held with reviewing ring fuzzy, ideal ring fuzzy, homomorphism ring fuzzy and quotient ring fuzzy with its properties. The results of this study are obtained fuzzy properties of the ring, ring ideal properties fuzzy, properties of fuzzy ring homomorphism and properties of fuzzy quotient ring by utilizing a subset of a subset level  and strong level  as well as image and pre-image homomorphism fuzzy ring.   Keywords: fuzzy ring, subset level, homomorphism fuzzy ring, fuzzy quotient ring

  1. Inorganic glass ceramic slip rings

    Science.gov (United States)

    Glossbrenner, E. W.; Cole, S. R.

    1972-01-01

    Prototypes of slip rings have been fabricated from ceramic glass, a material which is highly resistant to deterioration due to high temperature. Slip ring assemblies were not structurally damaged by mechanical tests and performed statisfactorily for 200 hours.

  2. e-læring

    DEFF Research Database (Denmark)

    Helms, Niels Henrik

    e-læring kan defineres på ganske mange måder. Ordet e-læring består jo tydeligt nok af to elementer. E + læring ligesom e-handel eller e-banking, og umiddelbart vil de fleste nok sige, at det så handler om læring vha. internettet. I bidraget advokeres for en læringsmæssig frem for normativ tilgang....

  3. Design of low energy ring(s)

    CERN Document Server

    Lachaize, Antoine

    During the last two years, several upgrades of the initial baseline scenario were studied with the aim of increasing the average intensity of ion beams in the accelerator chain of the Beta Beam complex. This is the reason why the Rapid Cycling Synchrotron (RCS) specifications were reconsidered many times [1], [2], [3].General considerations on the optical design were presented at the Beta Beam Task Meetings held at CERN and at Saclay in 2005 [4]. More detailed beam optics studies were performed during the next months. Lattices, RF system parameters, multi-turn injection scheme, fast extraction, closed orbit correction and chromaticity correction systems were proposed for different versions of the RCS [5], [6], [7].Finally, the RCS specifications have stabilized in November 2006 after the fourth Beta Beam Task Meeting when it was decided to fix the maximum magnetic rigidity of ion beams to 14.47 T.m (3.5 GeV equivalent proton energy) and to adopt a ring physical radius of 40 m in order to facilitate injectio...

  4. Clean elements in abelian rings

    Indian Academy of Sciences (India)

    equivalent to being clean for an abelian ring is 'topologically boolean'. In line with [1] we say that a ring R (not necessarily commutative) is right (resp. left) topologically boolean, or a right (resp. left) tb-ring for short, if for every pair of distinct maximal right (resp. left) ideals of R there is an idempotent in exactly one of them.

  5. 3′-(4-Chlorophenyl-4′-phenyl-3H,4′H-spiro[benzo[b]thiophene-2,5′-isoxazol]-3-one

    Directory of Open Access Journals (Sweden)

    Mohamed Bakhouch

    2017-05-01

    Full Text Available The molecule of the title compound, C22H14ClNO2S, is built up from an isoxazole ring linked to a benzothiophene ring system with additional phenyl and 4-chlorophenyl substituents. The benzothiophene system is virtually planar with the largest deviation from the mean plane being 0.041 (2 Å, while the isoxazole ring adopts an envelope conformation. The plane of the benzothiophene ring system is almost perpendicular to those of the phenyl and the 4-chlorophenyl rings, with dihedral angles of 64.76 (10 and 82.81 (10°, respectively, between them. The phenyl ring is inclined by 85.76 (12° to the plane of the 4-chlorophenyl ring, which in turn lies close to the plane of the isoxazole ring. In the crystal, molecules are linked by weak C—H...O hydrogen bonds and offset π–π interactions between the aromatic rings of adjacent benzothiophene ring systems. These combine to form a three-dimensional network structure.

  6. Ring Confidential Transactions

    Directory of Open Access Journals (Sweden)

    Shen Noether

    2016-12-01

    Full Text Available This article introduces a method of hiding transaction amounts in the strongly decentralized anonymous cryptocurrency Monero. Similar to Bitcoin, Monero is a cryptocurrency which is distributed through a proof-of-work “mining” process having no central party or trusted setup. The original Monero protocol was based on CryptoNote, which uses ring signatures and one-time keys to hide the destination and origin of transactions. Recently the technique of using a commitment scheme to hide the amount of a transaction has been discussed and implemented by Bitcoin Core developer Gregory Maxwell. In this article, a new type of ring signature, A Multilayered Linkable Spontaneous Anonymous Group signature is described which allows one to include a Pedersen Commitment in a ring signature. This construction results in a digital currency with hidden amounts, origins and destinations of transactions with reasonable efficiency and verifiable, trustless coin generation. The author would like to note that early drafts of this were publicized in the Monero Community and on the #bitcoin-wizards IRC channel. Blockchain hashed drafts are available showing that this work was started in Summer 2015, and completed in early October 2015. An eprint is also available at http://eprint.iacr.org/2015/1098.

  7. SOR-ring failure

    International Nuclear Information System (INIS)

    Kitamura, Hideo

    1981-01-01

    It was in the autumn of 1976 that the SOR-ring (synchrotron radiation storage ring) has commenced the regular operation. Since then, the period when the operation was interrupted due to the failures of SOR-ring itself is in total about 8 weeks. Failures and accidents have occurred most in the vacuum system. Those failure experiences are described on the vacuum, electromagnet, radio-frequency acceleration and beam transport systems with their interrupted periods. The eleven failures in the vacuum system have been reported, such as bellows breakage in a heating-evacuating period, leakage from the bellows of straight-through valves (made in U.S.A. and Japan), and leakage from the joint flange of the vacuum system. The longest interruption was 5 weeks due to the failure of a domestically manufactured straight-through valve. The failures of the electromagnet system involve the breakage in a cooling water system, short circuit of a winding in the Q magnet power transformer, blow of a fuse protecting the deflection magnet power source by the current less than the rating, and others. The failures of the RF acceleration system include the breakage of an output electronic tube the breakage of a cavity ceramic, RF voltage fluctuation due to the contact deterioration at a cavity electrode, and the failure of grid bias power source. It is necessary to select the highly reliable components for the vacuum system because the vacuum system failures require longer time for recovery, and very likely to induce secondary and tertiary failures. (Wakatsuki, Y.)

  8. Femtoslicing in Storage Rings

    CERN Document Server

    Khan, Shaukat

    2005-01-01

    The generation of ultrashort synchrotron radiation pulses by laser-induced energy modulation of electrons and their subsequent transverse displacement, now dubbed "femtoslicing," was demonstrated at the Advanced Light Source in Berkeley. More recently, a femtoslicing user facility was commissioned at the BESSY storage ring in Berlin, and another project is in progress at the Swiss Light Source. The paper reviews the principle of femtoslicing, its merits and shortcomings, as well as the variations of its technical implementation. Various diagnostics techniques to detect successful laser-electron interaction are discussed and experimental results are presented.

  9. Proton storage rings

    International Nuclear Information System (INIS)

    Rau, R.R.

    1978-04-01

    A discussion is given of proton storage ring beam dynamic characteristics. Topics considered include: (1) beam energy; (2) beam luminosity; (3) limits on beam current; (4) beam site; (5) crossing angle; (6) beam--beam interaction; (7) longitudinal instability; (8) effects of scattering processes; (9) beam production; and (10) high magnetic fields. Much of the discussion is related to the design parameters of ISABELLE, a 400 x 400 GeV proton---proton intersecting storage accelerator to be built at Brookhaven National Laboratory

  10. Fusion Rings for Quantum Groups

    DEFF Research Database (Denmark)

    Andersen, Henning Haahr; Stroppel, Catharina

    2014-01-01

    We study the fusion rings of tilting modules for a quantum group at a root of unity modulo the tensor ideal of negligible tilting modules. We identify them in type A with the combinatorial rings from Korff, C., Stroppel, C.: The sl(ˆn)k-WZNW fusion ring: a combinato-rial construction and a realis......We study the fusion rings of tilting modules for a quantum group at a root of unity modulo the tensor ideal of negligible tilting modules. We identify them in type A with the combinatorial rings from Korff, C., Stroppel, C.: The sl(ˆn)k-WZNW fusion ring: a combinato-rial construction...... and a realisation as quotient of quantum cohomology. Adv. Math. 225(1), 200–268, (2010) and give a similar description of the sp2n-fusion ring in terms of non-commutative symmetric functions. Moreover we give a presentation of all fusion rings in classical types as quotients of polynomial rings. Finally we also...... compute the fusion rings for type G2....

  11. Viscosity of ring polymer melts

    KAUST Repository

    Pasquino, Rossana

    2013-10-15

    We have measured the linear rheology of critically purified ring polyisoprenes, polystyrenes, and polyethyleneoxides of different molar masses. The ratio of the zero-shear viscosities of linear polymer melts η0,linear to their ring counterparts η0,ring at isofrictional conditions is discussed as a function of the number of entanglements Z. In the unentangled regime η0,linear/η 0,ring is virtually constant, consistent with the earlier data, atomistic simulations, and the theoretical expectation η0,linear/ η0,ring = 2. In the entanglement regime, the Z-dependence of ring viscosity is much weaker than that of linear polymers, in qualitative agreement with predictions from scaling theory and simulations. The power-law extracted from the available experimental data in the rather limited range 1 < Z < 20, η0,linear/η0,ring ∼ Z 1.2±0.3, is weaker than the scaling prediction (η0,linear/η0,ring ∼ Z 1.6±0.3) and the simulations (η0,linear/ η0,ring ∼ Z2.0±0.3). Nevertheless, the present collection of state-of-the-art experimental data unambiguously demonstrates that rings exhibit a universal trend clearly departing from that of their linear counterparts, and hence it represents a major step toward resolving a 30-year-old problem. © 2013 American Chemical Society.

  12. Saturn ring temperature variations with approaching ring equinox

    Science.gov (United States)

    Spilker, L.; Leyrat, C.; Flandes, A.; Altobelli, N.; Pilorz, S.; Ferrari, C.; Edgington, S.

    2009-04-01

    Cassini's Composite Infrared Spectrometer (CIRS) has acquired a wide-ranging set of thermal measurements of Saturn's main rings (A, B, C and Cassini Division) at solar elevations ranging from less than one degree to 24 degrees. At Saturn equinox in August the solar elevation angle will reach zero as the sun traverses from the south to north side of the rings. For the data acquired to date, temperatures were retrieved for the lit and unlit rings over a variety of ring geometries that include solar elevation, as well as spacecraft elevation, phase angle and local hour angle. To first order, the largest temperature changes on the lit face of the rings are driven by variations in phase angle while differences in temperature with changing spacecraft elevation and local time are a secondary effect. Decreasing ring temperature with decreasing solar elevation are observed for both the lit and unlit faces of the rings after phase angle and local time effects are taken into account. As the solar elevation continues to decrease, the ring temperatures are decreasing in a non-linear fashion. The difference in temperature between the lit and unlit sides of the rings is decreasing also with decreasing solar elevation. Using ring thermal models developed by Leyrat we extrapolate to the expected minimum ring temperatures at equinox for our planned CIRS ring observations. This research was carried out at the Jet Propulsion Laboratory, California Institute of Technology, under contract with NASA and at CEA Saclay supported by the "Programme National de Planetologie". Copyright 2009 California Institute of Technology. Government sponsorship acknowledged.

  13. Ring Image Analyzer

    Science.gov (United States)

    Strekalov, Dmitry V.

    2012-01-01

    Ring Image Analyzer software analyzes images to recognize elliptical patterns. It determines the ellipse parameters (axes ratio, centroid coordinate, tilt angle). The program attempts to recognize elliptical fringes (e.g., Newton Rings) on a photograph and determine their centroid position, the short-to-long-axis ratio, and the angle of rotation of the long axis relative to the horizontal direction on the photograph. These capabilities are important in interferometric imaging and control of surfaces. In particular, this program has been developed and applied for determining the rim shape of precision-machined optical whispering gallery mode resonators. The program relies on a unique image recognition algorithm aimed at recognizing elliptical shapes, but can be easily adapted to other geometric shapes. It is robust against non-elliptical details of the image and against noise. Interferometric analysis of precision-machined surfaces remains an important technological instrument in hardware development and quality analysis. This software automates and increases the accuracy of this technique. The software has been developed for the needs of an R&TD-funded project and has become an important asset for the future research proposal to NASA as well as other agencies.

  14. Flexible ring seal

    International Nuclear Information System (INIS)

    Abbes, Claude; Gournier, Andre; Rouaud, Christian; Villepoix, Raymond de.

    1976-01-01

    The invention concerns a flexible metal ring seal, able to ensure a perfect seal between two bearings due to the crushing and elastic deformation properties akin to similar properties in elastomers. Various designs of seal of this kind are already known, particularly a seal made of a core formed by a helical wire spring with close-wound turns and with high axial compression ratio, closed on itself and having the shape of an annulus. This wire ring is surrounded by at least one envelope having at rest the shape of a toroidal surface of which the generating circle does not close on itself. In a particular design mode, the seal in question can include, around the internal spring, two envelopes of which one in contact with the spring is composed of a low ductility elastic metal, such as mild steel or stainless steel and the other is, on the contrary, made of a malleable metal, such as copper or nickel. The first envelope evenly distributes the partial crushing of the spring, when the seal is tightened, on the second envelope which closely fits the two surfaces between which the seal operates. The stress-crushing curve characteristic of the seal comprises two separate parts, the first with a relatively sharp slope corresponds to the start of the seal compression phase, enabling at least some of these curves to reach the requisite seal threshold very quickly, then, beyond this, a second part, practically flat, where the stress is appreciably constant for a wide operating bracket [fr

  15. NRL ion ring program

    International Nuclear Information System (INIS)

    Kapetanakos, C.A.; Golden, J.; Drobot, A.; Mahaffey, R.A.; Marsh, S.J.; Pasour, J.A.

    1977-01-01

    An experiment is under way to form a storng proton ring using the 200 ka, 1.2 MeV, 50 nsec hollow proton beam recently generated at NRL. The 5 m long magnetic field configuration consists of a magnetic cusp, a compressing magnetic field, a gate field and a magnetic mirror. The midplane value of the magnetic mirror is such that the major radius of the ring will be about 10 cm. The degree of field reversal that will be achieved with 5 x 10 16 protons per pulse from the existing beam depends upon the field reversal is possible with the 600 kA proton beam that would be generated from the low inductance coaxial triode coupled to the upgraded Gamble II generator. The propagation and trapping of an intense proton beam in the experimental magnetic field configuration is investigated numerically. The results show that the self magnetic has a very pronounced effect on the dynamics of the gyrating protons

  16. On thickness of Saturn rings

    International Nuclear Information System (INIS)

    Brahic, Andre; Laques, Pierre; Lecacheux, Jean; Servan, Bernard; Despiau, Raymond; Michet, Daniel; Renard, Leopold

    1980-01-01

    Electronographic plates of Saturn were taken during the transit of the Earth through the ring plane. Observing conditions were more favorable than those prevailing in 1966. Thanks to the quality of the detectors and the telescopes, it has been possible to make a more precise photometric determination of the brightness of the ring seen edge on and to measure the brightness variation with respect to the distance to the center of the planet. Extrapolating to the case where the elevation of the Earth above the ring plane is strictly zero, we deduce an apparent photometric ring thickness equal to 1.5+-0.3 km. For an homogeneous layer of small particles colliding inelastically, theory predicts a thickness of the order of a few particles radii, i.e. a few tens of meters. The observed brightness could be explained by the E ring, the brightness of large chunks, condensations and warping of the ring [fr

  17. Saturn's Rings and Associated Ring Plasma Cavity: Evidence for Slow Ring Erosion

    Science.gov (United States)

    Farrell, W. M.; Kurth, W. S.; Gurnett, D. A.; Persoon, A. M.; MacDowall, R. J.

    2017-01-01

    We re-examine the radio and plasma wave observations obtained during the Cassini Saturn orbit insertion period, as the spacecraft flew over the northern ring surface into a radial distance of 1.3 Rs (over the C-ring). Voyager era studies suggest the rings are a source of micro-meteoroid generated plasma and dust, with theorized peak impact-created plasma outflows over the densest portion of the rings (central B-ring). In sharp contrast, the Cassini Radio and Plasma Wave System (RPWS) observations identify the presence of a ring-plasma cavity located in the central portion of the B-ring, with little evidence of impact-related plasma. While previous Voyager era studies have predicted unstable ion orbits over the C- ring, leading to field-aligned plasma transport to Saturns ionosphere, the Cassini RPWS observations do not reveal evidence for such instability-created plasma fountains. Given the passive ring loss processes observed by Cassini, we find that the ring lifetimes should extend >10(exp 9) years, and that there is limited evidence for prompt destruction (loss in <100 Myrs).

  18. A facile one-pot green synthesis and antibacterial activity of 2-amino-4H-pyrans and 2-amino-5-oxo-5,6,7,8-tetrahydro-4H-chromenes.

    Science.gov (United States)

    Kumar, Dalip; Reddy, V Buchi; Sharad, Shashwat; Dube, Urvashi; Kapur, Suman

    2009-09-01

    A facile one-pot expeditious synthesis of 2-amino-4H-pyrans and 2-amino-5-oxo-5,6,7,8-tetrahydro-4H-chromenes has been described under solvent-free conditions using magnesium oxide as a catalyst in very good yields. The reaction catalyst, magnesium oxide was reused and recycled without any loss of activity and product yield. All the synthesized compounds were screened for in vitro antibacterial activity, and compounds 3a, 3b, 3f, 4b, 4c, 4d, 4e and 4g showed complete inhibition of bacterial growth at 128 microg/mL or less and the rest of the compounds exhibited incomplete inhibition.

  19. Caustic rings of dark matter

    International Nuclear Information System (INIS)

    Sikivie, P.

    1997-01-01

    It is shown that the infall of collisionless dark matter onto isolated galaxies produce a series of caustic rings in the halo dark matter distribution. The properties of these caustics are investigated. It is found in particular that the density profile of the caustic behaves as the inverse distance to the ring. Bumps in the rotation curve of NGC 3198 are interpreted as due to caustic rings of dark matter

  20. Version para el português del texto "One enters through one door and leaves then through another" de annette spiro

    Directory of Open Access Journals (Sweden)

    Catherine Otondo

    2009-06-01

    Full Text Available No ano de 2002 a arquiteta suíça Annette Spiro lança, pela Editora Niggli, um livro primoroso sobre a obra de Paulo Mendes, com 37 projetos publicados, fotos novas criadas pela autora e um ensaio crítico de sua autoria sobre o conjunto de projetos publicados, além de uma entrevista com o arquiteto e um simpático prefácio escrito pelo arquiteto Luigi Snozzi. O texto de Annette surpreende pela maneira inédita pela qual analisa as obras do arquiteto, por sua compreensão da cultura brasileira, o que acaba por ampliar o alcance dessa abordagem. O caminho escolhido para efetuar sua análise é a partir dos componentes constitutivos da obra arquitetônica: terreno, cobertura, balanços, pilotis, e constrói um raciocínio sobre a articulação desses elementos no espaço. E assim - apoiada, sobretudo, nos textos do autor inglês Colin Rowe - analisa os projetos sob a ótica da tradição clássica e sua ordenação espacial. Contudo, a autora não se restringe aos aspectos formais ou materiais dos edifícios: concreto aparente, rigor estrutural, apreço pela técnica, características que levariam a uma associação imediata, e talvez superficial, com estilos tais como brutalista, minimalista ou abstracionista. E, sim, explora a relação entre componentes fundamentais de cada projeto: planos horizontais e verticais, a relação com o terreno, a oposição entre cheios e vazios e a luz como elemento constitutivo do espaço.

  1. A facile one-pot ultrasound assisted for an efficient synthesis of 1H-spiro[furo[3,4-b]pyridine-4,3'-indoline]-3-carbonitriles.

    Science.gov (United States)

    Ghahremanzadeh, Ramin; Rashid, Zahra; Zarnani, Amir-Hassan; Naeimi, Hossein

    2014-07-01

    A convenient one-pot protocol was developed for the synthesis of 1H-spiro[furo[3,4-b]pyridine-4,3'-indoline]-3-carbonitrile derivatives. This reaction was carried out through a three component condensation reaction of isatins, malononitrile, and anilinolactones in the presence of a catalytic amount of Et3N as an inexpensive and available basic catalyst in THF under ultrasound irradiation. The products were obtained in high yields and short reaction times. The main advantage of this synthetic method is that the obtained products in ultrasonic irradiations are different from classical heating. Copyright © 2014 Elsevier B.V. All rights reserved.

  2. Acceleration of magnetized plasma rings

    International Nuclear Information System (INIS)

    Hartman, D.; Eddleman, J.; Hammer, J.H.

    1982-01-01

    One scheme is considered, acceleration of a ring between coaxial electrodes by a B/sub theta/ field as in a coaxial rail-gun. If the electrodes are conical, a ring accelerated towards the apex of the cone undergoes self-similar compression (focussing) during acceleration. Because the allowable acceleration force F/sub a/ = kappa U/sub m//R (kappa - 2 , the accelerating distance for conical electrodes is considerably shortened over that required for coaxial electrodes. In either case however, since the accelerating flux can expand as the ring moves, most of the accelerating field energy can be converted into kinetic energy of the ring leading to high efficiency

  3. Saturn's Rings Edge-on

    Science.gov (United States)

    1995-01-01

    In one of nature's most dramatic examples of 'now-you see-them, now-you-don't', NASA's Hubble Space Telescope captured Saturn on May 22, 1995 as the planet's magnificent ring system turned edge-on. This ring-plane crossing occurs approximately every 15 years when the Earth passes through Saturn's ring plane.For comparison, the top picture was taken by Hubble on December 1, 1994 and shows the rings in a more familiar configuration for Earth observers.The bottom picture was taken shortly before the ring plane crossing. The rings do not disappear completely because the edge of the rings reflects sunlight. The dark band across the middle of Saturn is the shadow of the rings cast on the planet (the Sun is almost 3 degrees above the ring plane.) The bright stripe directly above the ring shadow is caused by sunlight reflected off the rings onto Saturn's atmosphere. Two of Saturn's icy moons are visible as tiny starlike objects in or near the ring plane. They are, from left to right, Tethys (slightly above the ring plane) and Dione.This observation will be used to determine the time of ring-plane crossing and the thickness of the main rings and to search for as yet undiscovered satellites. Knowledge of the exact time of ring-plane crossing will lead to an improved determination of the rate at which Saturn 'wobbles' about its axis (polar precession).Both pictures were taken with Hubble's Wide Field Planetary Camera 2. The top image was taken in visible light. Saturn's disk appears different in the bottom image because a narrowband filter (which only lets through light that is not absorbed by methane gas in Saturn's atmosphere) was used to reduce the bright glare of the planet. Though Saturn is approximately 900 million miles away, Hubble can see details as small as 450 miles across.The Wide Field/Planetary Camera 2 was developed by the Jet Propulsion Laboratory and managed by the Goddard Spaced Flight Center for NASA's Office of Space Science.This image and other images and

  4. Integrated Ring Resonators The Compendium

    CERN Document Server

    Rabus, Dominik G

    2007-01-01

    The optical filter, which has emerged in the last few years in integrated optics, is resonator based. Ring-resonator filters do not require facets or gratings for optical feedback and are thus particularly suited for monolithic integration with other components. Ring resonators find applications not only in optical networks, but also as sensors. The required passband shape of ring resonator-filters can be custom designed by the use of configurations of various ring coupled resonators. This book describes the current state-of-the-art on these devices with respect to design, fabrication and application.

  5. ring og refleksion

    DEFF Research Database (Denmark)

    Wahlgren, B.; Rattleff, Pernille; Høyrup, S.

    State of the art inden for forskning om læring på arbejdspladsen samt gennemgang af læringsteori og refleksionsbegrebet hos Dewey, Dreyfus, Schön, Argyris, Kolb, Jarvis, Mezirow og Brookfield. Afsluttes med diskussion af syntetiseret model for læring på arbejdspladsen.......State of the art inden for forskning om læring på arbejdspladsen samt gennemgang af læringsteori og refleksionsbegrebet hos Dewey, Dreyfus, Schön, Argyris, Kolb, Jarvis, Mezirow og Brookfield. Afsluttes med diskussion af syntetiseret model for læring på arbejdspladsen....

  6. Conformational analysis of benzoannulated nine-membered rings. Part 2. X-ray analysis and force-field calculations of 1,4,5,7-tetrahydro-3 H-2,6-benzodithionin and its derivatives

    Science.gov (United States)

    Rys, Barbara; Szneler, Edward; Grochowski, Jacek; Serda, Paweł; Duddeck, Helmut

    1992-09-01

    The conformations of 1,4,5,7-tetrahydro-3 H-2,6-benzodithionin-4-spiro-(1'-cyclobutane), -(3'-oxacylobutane) and -(cyclopentane) have been determined by X-ray analysis and are compared with previous low-temperature NMR results and with MM2 calculations. Significant changes in bond lengths and torsion angles of the nine-membered ring may be due to differences in intramolecular strain and molecular packing. X-ray data revealed conformational similarities in spite of different substituents. MM2 calculations have shown that the solid-state conformation is close to the most stable of the twelve minimum-energy conformations found for the parent compound without substituents.

  7. Coiffured black rings

    Science.gov (United States)

    Bena, Iosif; Ross, Simon F.; Warner, Nicholas P.

    2014-08-01

    We describe a new type of hair on supersymmetric black string and black ring solutions, which produces the largest known violation of black hole uniqueness, parameterized by an arbitrary function and hence an infinite number of continuous parameters. The new solutions can have non-trivial density profiles for the electric fields along the horizon, and yet have a geometry that is regular, although generically not infinitely differentiable, at the horizon. Both neutral and charged probes can cross the horizon without experiencing divergent forces. We also find restricted examples, parameterized by a few arbitrary continuous parameters, where the charge densities fluctuate but the metric does not and hence is completely differentiable. Our new class of solutions owes its existence to a mechanism reminiscent of the Q-ball: in the simplest examples the metric has more symmetry than the matter that supports it.

  8. Ring-constrained Join

    DEFF Research Database (Denmark)

    Yiu, Man Lung; Karras, Panagiotis; Mamoulis, Nikos

    2008-01-01

    We introduce a novel spatial join operator, the ring-constrained join (RCJ). Given two sets P and Q of spatial points, the result of RCJ consists of pairs (p, q) (where p ε P, q ε Q) satisfying an intuitive geometric constraint: the smallest circle enclosing p and q contains no other points in P, Q....... This new operation has important applications in decision support, e.g., placing recycling stations at fair locations between restaurants and residential complexes. Clearly, RCJ is defined based on a geometric constraint but not on distances between points. Thus, our operation is fundamentally different...... from the conventional distance joins and closest pairs problems. We are not aware of efficient processing algorithms for RCJ in the literature. A brute-force solution requires computational cost quadratic to input size and it does not scale well for large datasets. In view of this, we develop efficient...

  9. On separable extensions of group rings and quaternion rings

    Directory of Open Access Journals (Sweden)

    George Szeto

    1978-01-01

    Full Text Available The purposes of the present paper are (1 to give a necessary and sufficient condition for the uniqueness of the separable idempotent for a separable group ring extension RG(R may be a non-commutative ring, and (2 to give a full description of the set of separable idempotents for a quaternion ring extension RQ over a ring R, where Q are the usual quaternions i,j,k and multiplication and addition are defined as quaternion algebras over a field. We shall show that RG has a unique separable idempotent if and only if G is abelian, that there are more than one separable idempotents for a separable quaternion ring RQ, and that RQ is separable if and only if 2 is invertible in R.

  10. rac-(rel-1R,2R,4S-Spiro[bicyclo[2.2.1]heptane-2,3′-indol]-2′-amine

    Directory of Open Access Journals (Sweden)

    Andreas Lemmerer

    2011-02-01

    Full Text Available In the racemic title compound, C14H16N2, the aromatic ring component of the aminoindoline system occupies the endo cavity of the norbornane component. The aromatic ring lies at an angle of 74.12 (5° to the plane defined by the four C atoms that comprises the rigid part of the boat-shaped six-membered ring of the norbornane unit. Pairs of molecules assemble in the crystal structure, forming centrosymmetric hydrogen-bonded dimers via pairs of N—H...N hydrogen bonds through the syn H atom of the amine group.

  11. DELPHI's Ring Imaging Cherenkov Chamber

    CERN Multimedia

    1989-01-01

    The hundreds of mirrors around this Ring Imaging Cherenkov Chamber reflect cones of light created by fast moving particles to a detector. The velocity of a particle can be measured by the size of the ring produced on the detector. DELPHI, which ran from 1989 to 2000 on the LEP accelerator, was primarily concerned with particle identification.

  12. Caustic rings of dark matter

    OpenAIRE

    Sikivie, Pierre

    1997-01-01

    It is shown that the infall of collisionless dark matter onto isolated galaxies produces a series of caustic rings in the halo dark matter distribution. The properties of these caustics are investigated. The density profile of the caustic is derived for a specific case. Bumps in the rotation curve of NGC 3198 are interpreted as due to caustic rings of dark matter.

  13. Pyrimidine-pyridine ring interconversion

    NARCIS (Netherlands)

    Plas, van der H.C.

    2003-01-01

    This chapter discusses the pyrimidine-to-pyridine ring transformation and pyridine-to-pyrimidine ring transformation. In nucleophile-induced pyrimidine-to-pyridine rearrangements, two types of reactions can be distinguished depending on the structure of the nucleophile: (1) reactions in which the

  14. Binomial Rings: Axiomatisation, Transfer and Classification

    OpenAIRE

    Xantcha, Qimh Richey

    2011-01-01

    Hall's binomial rings, rings with binomial coefficients, are given an axiomatisation and proved identical to the numerical rings studied by Ekedahl. The Binomial Transfer Principle is established, enabling combinatorial proofs of algebraical identities. The finitely generated binomial rings are completely classified. An application to modules over binomial rings is given.

  15. Burnside Rings of Fusion Systems

    DEFF Research Database (Denmark)

    Reeh, Sune Precht

    In this thesis we study the interactions between saturated fusion systems and group actions of the underlying p-groups. For a saturated fusion system F on a finite p-group S we construct the Burnside ring of F in terms of the finite S-sets whose actions respect the structure of the fusion system...... of Burnside rings given by multiplication with the characteristic idempotent, and we show that this map is the transfer map previously constructed. Applying these results, we show that for every saturated fusion system the ring generated by all (non-idempotent) characteristic elements in the p-local double...... Burnside ring is isomorphic to the p-local Burnside ring of the fusion system, and we disprove a conjecture by Park-Ragnarsson-Stancu on the composition product of fusion systems....

  16. Ionization cooling ring for muons

    Directory of Open Access Journals (Sweden)

    R. Palmer

    2005-06-01

    Full Text Available Practical ionization cooling rings could lead to lower cost or improved performance in neutrino factory or muon collider designs. The ring modeled here uses realistic three-dimensional fields. The performance of the ring compares favorably with the linear cooling channel used in the second U.S. Neutrino Factory Study. The normalized 6D emittance of an ideal ring is decreased by a factor of approximately 240, compared with a factor of only 15 for the linear channel. We also examine such real-world effects as windows on the absorbers and rf cavities and leaving empty lattice cells for injection and extraction. For realistic conditions the ring decreases the normalized 6D emittance by a factor of 49.

  17. Evaluation of ring impedance of the Photon Factory storage ring

    International Nuclear Information System (INIS)

    Kiuchi, T.; Izawa, M.; Tokumoto, S.; Hori, Y.; Sakanaka, S.; Kobayashi, M.; Kobayakawa, H.

    1992-05-01

    The loss parameters of the ducts in the Photon Factory (PF) storage ring were evaluated using the wire method and the code TBCI. Both the measurement and the calculation were done for a different bunch length (σ) ranging from 23 to 80 ps. The PF ring impedance was estimated to be |Z/n|=3.2 Ω using the broadband impedance model. The major contribution to the impedance comes from the bellows and the gate valve sections. Improvements of these components will lower the ring impedance by half. (author)

  18. Decay ring status / studies

    CERN Document Server

    Chance, A

    2008-01-01

    The aim of "beta-beams" is to produce highly energetic pure electron neutrino and anti-neutrino beams coming from β-decay of radioactive ions. In CERN baseline, after accelerating, the ions 6He2+ and 18Ne10+ are stored in a racetrack-shaped-decay ring until they are lost [1]. Consequently, the injection compensates the losses which occurred between two cycles. Two main loss sources were identified: the β decay and the injection scheme. After giving the optics, we will see how to protect the magnetic elements from the decay products. The injections scheme will be then detailed with its implications. We will see that the injection process makes a collimation section in energy necessary. Since the magnetic elements are not perfect, we will take into account the magnet misalignment and the multipole defects in the dipoles. We will talk then about the closed orbit distortion due to misalignment defects and about the long-term transverse stability with the dynamic aperture.

  19. JAERI storage ring JSR

    International Nuclear Information System (INIS)

    Yokomizo, H.; Harada, S.; Yanagida, K.; Yokoyama, M.; Nagai, T.; Suzuki, Y.; Mashiko, K.; Ishizaki, N.; Tayama, H.

    1990-01-01

    A design study for a next generation 8 GeV synchrotron radiation facility is in progress in Japan, and the Japan Atomic Energy Research Institute (JAERI) and Institute of Physical and Chemical Research (RIKEN) have join forces in this project. A compact electron storage ring JSR has been under construction in the linac building in the Tokai Research Establishment of JAERI to serve for studies of various kind of accelerator technologies, examination of insertion devices and beam monitors, and training of young researchers. This paper describes the lattice design, injection system, magnets, vacuum system, RF system, control system and beam monitors and presents some operation results regarding the electron beam injection and storage. The JSR is presently in good condition concerning it's fundamental functions such as injection, storage at around 150 MeV and 300 MeV, and acceleration from 150 MeV and 300 MeV. Photon induced gas desorption is still large because the vacuum chamber has not been aged heavily by synchrotron radiation. (N.K.)

  20. Is the bell ringing?

    CERN Multimedia

    Francesco Poppi

    2010-01-01

    During the Nobel prize-winning UA1 experiment, scientists in the control room used to ring a bell if a particularly interesting event had occurred. Today, the “CMS Exotica hotline” routine produces a daily report that lists the exotic events that were recorded the day before.   Display of an event selected by the Exotica routine. Take just a very small fraction of the available data (max. 5%); define the events that you want to keep and set the parameters accordingly; run the Exotica routine and only look at the very few images that the system has selected for you. This is the recipe that a small team of CMS researchers has developed to identify the signals coming from possible new physics processes. “This approach does not replace the accurate data analysis on the whole set of data. However, it is a very fast and effective way to focus on just a few events that are potentially very interesting”, explains Maurizio Pierini (CERN), who developed the...

  1. Particle properties and processes in Uranus' rings

    Science.gov (United States)

    Esposito, L. W.; Brahic, A.; Burns, J. A.; Marouf, Essam A.

    1991-01-01

    The particle properties and processes in the Uranian rings are analyzed from Voyager observations and ground-based data. Occultation observations of the epsilon ring are interpreted to yield an effective size of the ring particles that exceeds 70 cm, a surface mass density that exceeds 80 g/sq cm, and a ring vertical thickness greater than tens of meters for solid ice particles. The particles forming the classic rings are dark and gray, with albedo of 0.014 +/-0.004. It is argued that the small amount of dust that exists in the classical rings and between the rings in bands is created by erosion of ring particles and unseen satellites resulting from collisions and micrometeoroid bombardment. As proposed for regions of the other known ring systems, new ring material can be continually created by the destruction of small moons near the rings, which may explain the youthful appearance of the Uranian rings.

  2. Ion Rings for Magnetic Fusion

    Energy Technology Data Exchange (ETDEWEB)

    Greenly, John, B.

    2005-07-31

    This Final Technical Report presents the results of the program, Ion Rings for Magnetic Fusion, which was carried out under Department of Energy funding during the period August, 1993 to January, 2005. The central objective of the program was to study the properties of field-reversed configurations formed by ion rings. In order to reach this objective, our experimental program, called the Field-reversed Ion Ring Experiment, FIREX, undertook to develop an efficient, economical technology for the production of field-reversed ion rings. A field-reversed configuration (FRC) in which the azimuthal (field-reversing) current is carried by ions with gyro-radius comparable to the magnetic separatrix radius is called a field-reversed ion ring. A background plasma is required for charge neutralization of the ring, and this plasma will be confined within the ring's closed magnetic flux. Ion rings have long been of interest as the basis of compact magnetic fusion reactors, as the basis for a high-power accelerator for an inertial fusion driver, and for other applications of high power ion beams or plasmas of high energy density. Specifically, the FIREX program was intended to address the longstanding question of the contribution of large-orbit ions to the observed stability of experimental FRCs to the MHD tilt mode. Typical experimental FRCs with s {approx} 2-4, where s is the ratio of separatrix radius to ion gyro-radius, have been stable to tilting, but desired values for a fusion reactor, s > 20, should be unstable. The FIREX ring would consist of a plasma with large s for the background ions, but with s {approx} 1 for the ring ions. By varying the proportions of these two populations, the minimum proportion of large-orbit ions necessary for stability could be determined. The incorporation of large-orbit ions, perhaps by neutral-beam injection, into an FRC has been advanced for the purpose of stabilizing, heating, controlling angular momentum, and aiding the formation

  3. Treatment of Unstable Pelvic Ring Injuries.

    Science.gov (United States)

    Kim, Weon-Yoo

    2014-06-01

    Pelvic fractures are classified according to the stability of the pelvic ring. Unlike stable pelvic fractures, which heal without complications, unstable fractures may lead to pelvic ring deformities, which cause severe complications. An orthopedic surgeon must determine the stability of the pelvic ring by radiography and physical examination of the patient in order to ensure early, prompt treatment. This article includes anatomy of the pelvic ring, classification of pelvic ring injuries, its treatment algorithm, and corresponding cases involving unstable pelvic ring injury.

  4. Distributively generated matrix near rings

    International Nuclear Information System (INIS)

    Abbasi, S.J.

    1993-04-01

    It is known that if R is a near ring with identity then (I,+) is abelian if (I + ,+) is abelian and (I,+) is abelian if (I*,+) is abelian [S.J. Abbasi, J.D.P. Meldrum, 1991]. This paper extends these results. We show that if R is a distributively generated near ring with identity then (I,+) is included in Z(R), the center of R, if (I + ,+) is included in Z(M n (R)), the center of matrix near ring M n (R). Furthermore (I,+) is included in Z(R) if (I*,+) is included in Z(M n (R)). (author). 5 refs

  5. Researches on the Piston Ring

    Science.gov (United States)

    Ehihara, Keikiti

    1944-01-01

    In internal combustion engines, steam engines, air compressors, and so forth, the piston ring plays an important role. Especially, the recent development of Diesel engines which require a high compression pressure for their working, makes, nowadays, the packing action of the piston ring far more important than ever. Though a number of papers have been published in regard to researches on the problem of the piston ring, none has yet dealt with an exact measurement of pressure exerted on the cylinder wall at any given point of the ring. The only paper that can be traced on this subject so far is Mr. Nakagawa's report on the determination of the relative distribution of pressure on the cylinder wall, but the measuring method adopted therein appears to need further consideration. No exact idea has yet been obtained as to how the obturation of gas between the piston and cylinder, the frictional resistance of the piston, and the wear of the cylinder wall are affected by the intensity and the distribution of the radial pressure of the piston ring. Consequently, the author has endeavored, by employing an apparatus of his own invention, to get an exact determination of the pressure distribution of the piston ring. By means of a newly devised ring tester, to which piezoelectricity of quartz was applied, the distribution of the radial pressure of many sample rings on the market was accurately determined. Since many famous piston rings show very irregular pressure distribution, the author investigated and achieved a manufacturing process of the piston ring which will exert uniform pressure on the cylinder wall. Temperature effects on the configuration and on the mean spring power have also been studied. Further, the tests were performed to ascertain how the gas tightness of the piston ring may be affected by the number or spring power. The researches as to the frictional resistance between the piston ring and the cylinder wall were carried out, too. The procedure of study, and

  6. SMARANDACHE NON-ASSOCIATIVE RINGS

    OpenAIRE

    Vasantha, Kandasamy

    2002-01-01

    An associative ring is just realized or built using reals or complex; finite or infinite by defining two binary operations on it. But on the contrary when we want to define or study or even introduce a non-associative ring we need two separate algebraic structures say a commutative ring with 1 (or a field) together with a loop or a groupoid or a vector space or a linear algebra. The two non-associative well-known algebras viz. Lie algebras and Jordan algebras are mainly built using a vecto...

  7. Deceleration of electron rings by ions

    International Nuclear Information System (INIS)

    Schumacher, U.; Hofmann, I.; Merkel, P.; Reiser, M.

    1976-02-01

    The deceleration of intense relativistic electron rings by ions created by impact ionization in the electron rings is calculated analytically and numerically. It turns out that the stopping of rings with initial axial velocities of about β 0 = 0.1 is possible under conditions that easily can be realized experimentally in the Maryland ERA. The stopping length of the electron rings, however, depends sensitively on the initial axial ring velocities β 0 (as β 0 3 ). If the method of ring deceleration by ions is used, the reproducibility of the initial ring parameters (especially that of β 0 ) should be very good to get reliable electron ring loading and acceleration. (orig.) [de

  8. (1′S-4-(3,4-Dichlorophenyl-1′-(3,5-dimethoxyphenyl-1,2,3,4-tetrahydronaphthalene-2-spiro-2′-pyrrolizidine-3′-spiro-3′′-indoline-1,2′′-dione

    Directory of Open Access Journals (Sweden)

    S. Sriman Narayanan

    2008-10-01

    Full Text Available In the title compound C37H32Cl2N2O4, the unsubstituted pyrrolidine ring shows a twist conformation whereas the substituted pyrrolidine ring shows an envelope conformation. The dimethoxy benzene ring is perpendicular to the tetralone ring, making a dihedral angle of 89.94 (5°. Molecules are linked into centrosymmetric dimers by N—H...O hydrogen bonds and the crystal structure is stabilized by C—H...π interactions and C—H...O hydrogen bonds. One methoxy group is disordered over two positions with the site occupancy factors of 0.84 (2 and 0.16 (2.

  9. Minimal Gromov-Witten rings

    International Nuclear Information System (INIS)

    Przyjalkowski, V V

    2008-01-01

    We construct an abstract theory of Gromov-Witten invariants of genus 0 for quantum minimal Fano varieties (a minimal class of varieties which is natural from the quantum cohomological viewpoint). Namely, we consider the minimal Gromov-Witten ring: a commutative algebra whose generators and relations are of the form used in the Gromov-Witten theory of Fano varieties (of unspecified dimension). The Gromov-Witten theory of any quantum minimal variety is a homomorphism from this ring to C. We prove an abstract reconstruction theorem which says that this ring is isomorphic to the free commutative ring generated by 'prime two-pointed invariants'. We also find solutions of the differential equation of type DN for a Fano variety of dimension N in terms of the generating series of one-pointed Gromov-Witten invariants

  10. Autumn study on storage rings

    CERN Multimedia

    1974-01-01

    The first two weeks of October have seen storage ring people from accelerator Laboratories throughout the world at CERN to study the fundamental problems of very high energy protonproton colliding beam machines.

  11. Quasi-isochronous storage rings

    International Nuclear Information System (INIS)

    Robin, D.; Forest, E.; Pellegrini, C.; Amiry, A.

    1993-01-01

    A study is made of the single-particle dynamics of an electron-positron storage ring where the phase-slip factor is made small in order to make the ring nearly isochronous and reduce the bunch length. What is found is that a quasi-isochronous ring makes it possible to obtain a bunch length in the millimeter range, about one order of magnitude shorter than present values. In this study we have extended the work of others on isochronous storage rings by quantitatively including higher-order terms in the longitudinal equations of motion. Scaling laws are then derived relating the linear term with the next-highest-order term. These scaling laws, which are derived from a two-dimensional Hamiltonian (one dimension of position and one of momentum), establish criteria for stability. These scaling laws are then checked with full six-dimensional tracking on one particular lattice

  12. ring i familien

    DEFF Research Database (Denmark)

    Kryger, Niels

    2015-01-01

    Artiklen diskutere de senere års eksplosionsagtig interesse for børns læring i familien, og sætter et kritisk lys på den snævre investeringslogik (læring skal give afkast i form af økonomisk produktivitet), der har ledsaget mange af de programmer, der er sat i gang for at fremme denne ”familielær......Artiklen diskutere de senere års eksplosionsagtig interesse for børns læring i familien, og sætter et kritisk lys på den snævre investeringslogik (læring skal give afkast i form af økonomisk produktivitet), der har ledsaget mange af de programmer, der er sat i gang for at fremme denne...

  13. Ring lasers - a brief history

    Science.gov (United States)

    Klein, Tony

    2017-10-01

    Used these days in inertial navigation, ring lasers are also used in recording the tiniest variations in the Earth's spin, as well in detecting earthquakes and even the drift of continents. How did it all begin?

  14. Prototype moving-ring reactor

    International Nuclear Information System (INIS)

    Smith, A.C. Jr.; Ashworth, C.P.; Abreu, K.E.

    1982-01-01

    We have completed a design of the Prototype Moving-Ring Reactor. The fusion fuel is confined in current-carrying rings of magnetically-field-reversed plasma (Compact Toroids). The plasma rings, formed by a coaxial plasma gun, undergo adiabatic magnetic compression to ignition temperature while they are being injected into the reactor's burner section. The cylindrical burner chamber is divided into three burn stations. Separator coils and a slight axial guide field gradient are used to shuttle the ignited toroids rapidly from one burn station to the next, pausing for 1/3 of the total burn time at each station. D-T- 3 He ice pellets refuel the rings at a rate which maintains constant radiated power

  15. The Composition of Saturn's Rings

    Science.gov (United States)

    Clark, R. N.; Cuzzi, J.; Filacchione, G.; Cruikshank, D. P.; Curchin, J. M.; Hoefen, T. M.; Nicholson, P. D.; Hedman, M.; Brown, R. H.; Buratti, B. J.; Baines, K. H.; Nelson, R. M.

    2008-12-01

    The Cassini spacecraft has obtained a unique collection of data about Saturn's rings, as it has observed the rings from 0 to 180 degrees in phase angle, and on both lit and unlit sides. Identification of trace contaminants, especially organic compounds, requires that spectra of the rings be uncontaminated by light from Saturn. The Cassini Visual and Infrared Mapping Spectrometer (VIMS) has acquired 0.35 to 5.1 micron, high spatial resolution spectroscopic data near the shadow of Saturn on the rings where scattered light is at a minimum. At low phase angles, the ring spectra show classic crystalline-ice spectral features except for a contaminant causing a UV absorption. VIMS spectra at 180-degree phase angle are generally flat, with only a weak positive feature at 2.86 microns in spectra of the F-ring. The general transmission decrease is due to large ring particles completely blocking light. The 2.86-micron feature indicates the presence of fine ice dust, where the ice's index of refraction is near 1.0, and light is not refracted or diffracted. There are no indications of interparticle scattering in the VIMS data at any phase angle. The lack of interparticle scattering indicates that the dense A and B rings must be very thin, approaching a monolayer, but rigorous constraints have yet to be modeled. Previous studies used tholins and amorphous carbon for the contaminant causing the UV absorption, but these models display additional absorptions and spectral structure in the near infrared not seen in VIMS data. Clark et al. (Icarus, v193, p372, 2008) modeled the changing blue peak and UV absorber observed on Phoebe, Iapetus, Hyperion, and Dione with amorphous carbon and nano-sized hematite. Nanohematite has muted spectral features compared to larger grained hematite, due to crystal field effects at the surfaces of small grains. Nanohematite has a strong UV absorber that matches the steep UV slope observed in spectra of Saturn's rings and has no strong IR absorptions

  16. Collector ring project at FAIR

    International Nuclear Information System (INIS)

    Dolinskii, A; Blell, U; Dimopoulou, C; Gorda, O; Leibrock, H; Litvinov, S; Laier, U; Schurig, I; Weinrich, U; Berkaev, D; Koop, I; Starostenko, A; Shatunov, P

    2015-01-01

    The collector ring is a dedicated ring for fast cooling of ions coming from separators at the FAIR project. To accommodate optimal technical solutions, a structure of a magnet lattice was recently reviewed and modified. Consequently, more appropriate technical solutions for the main magnets could be adopted. A general layout and design of the present machine is shown. The demanding extraction schemes have been detailed and open design issues were completed. (paper)

  17. Synlig læring

    DEFF Research Database (Denmark)

    Brandsen, Mads

    2017-01-01

    Introduktionen af John Hatties synlig læring i den danske skoleverden møder stadig meget kritik. Mange lærere og pædagoger oplever synlig læring som en tornado, der vil opsuge og ødelægge deres særlige danske udgave af den kontinentale dannelsestænkning, didaktik og pædagogik. Spørgsmålet er om...

  18. MUON STORAGE RINGS - NEUTRINO FACTORIES

    International Nuclear Information System (INIS)

    PARSA, Z.

    2000-01-01

    The concept of a muon storage ring based Neutrino Source (Neutrino Factory) has sparked considerable interest in the High Energy Physics community. Besides providing a first phase of a muon collider facility, it would generate more intense and well collimated neutrino beams than currently available. The BNL-AGS or some other proton driver would provide an intense proton beam that hits a target, produces pions that decay into muons. The muons must be cooled, accelerated and injected into a storage ring with a long straight section where they decay. The decays occurring in the straight sections of the ring would generate neutrino beams that could be directed to detectors located thousands of kilometers away, allowing studies of neutrino oscillations with precisions not currently accessible. For example, with the neutrino source at BNL, detectors at Soudan, Minnesota (1,715 km), and Gran Sasso, Italy (6,527 km) become very interesting possibilities. The feasibility of constructing and operating such a muon-storage-ring based Neutrino-Factory, including geotechnical questions related to building non-planar storage rings (e.g. at 8degree angle for BNL-Soudan, and 3degree angle for BNL-Gran Sasso) along with the design of the muon capture, cooling, acceleration, and storage ring for such a facility is being explored by the growing Neutrino Factory and Muon Collider Collaboration (NFMCC). The authors present overview of Neutrino Factory concept based on a muon storage ring, its components, physics opportunities, possible upgrade to a full muon collider, latest simulations of front-end, and a new bowtie-muon storage ring design

  19. Optofluidic ring resonator dye lasers

    Science.gov (United States)

    Sun, Yuze; Suter, Jonathan D.; Fan, Xudong

    2010-02-01

    We overview the recent progress on optofluidic ring resonator (OFRR) dye lasers developed in our research group. The fluidics and laser cavity design can be divided into three categories: capillary optofluidic ring resonator (COFRR), integrated cylindrical optofluidic ring resonator (ICOFRR), and coupled optofluidic ring resonator (CpOFRR). The COFRR dye laser is based on a micro-sized glass capillary with a wall thickness of a few micrometers. The capillary circular cross-section forms the ring resonator and supports the whispering gallery modes (WGMs) that interact evanescently with the gain medium in the core. The laser cavity structure is versatile to adapt to the gain medium of any refractive index. Owing to the high Q-factor (>109), the lasing threshold of 25 nJ/mm2 is achieved. Besides directly pump the dye molecules, lasing through fluorescence resonance energy transfer (FRET) between the donor and acceptor dye molecules is also studied in COFRR laser. The energy transfer process can be further controlled by designed DNA scaffold labeled with donor/acceptor molecules. The ICOFRR dye laser is based on a cylindrical ring resonator fused onto the inner surface of a thick walled glass capillary. The structure has robust mechanical strength to sustain rapid gain medium circulation. The CpOFRR utilizes a cylindrical ring resonator fused on the inner surface of the COFRR capillary. Since the capillary wall is thin, the individual WGMs of the cylindrical ring resonator and the COFRR couples strongly and forms Vernier effect, which provides a way to generate a single mode dye laser.

  20. Resonance capture and Saturn's rings

    International Nuclear Information System (INIS)

    Patterson, C.W.

    1986-05-01

    We have assigned the resonances apparently responsible for the stabilization of the Saturn's shepherd satellites and for the substructure seen in the F-ring and the ringlets in the C-ring. We show that Saturn's narrow ringlets have a substructure determined by three-body resonances with Saturn's ringmoons and the sun. We believe such resonances have important implications to satellite formation. 17 refs., 1 fig., 1 tab

  1. Ring insertions as light sources

    International Nuclear Information System (INIS)

    Green, G.K.

    1975-01-01

    Bending magnets can be inserted in the long straight sections of electron storage rings to produce synchrotron radiation. If the design is carefully proportioned, the bending magnets create only a small perturbation of the properties of the ring. The resulting spectra have favorable optical properties as sources for spectroscopy and diffraction studies. The characteristics of the source are discussed, and the geometrical requirements of the magnets are presented

  2. Commuting Π-regular rings

    Directory of Open Access Journals (Sweden)

    Shervin Sahebi

    2014-05-01

    Full Text Available ‎$R$ is called commuting regular ring (resp‎. ‎semigroupif‎ for each $x,y\\in R$ there exists $a\\in R$‎ such that$xy=yxayx$‎. ‎In this paper‎, ‎we introduce the concept of‎‎commuting $\\pi$-regular rings (resp‎. ‎semigroups and‎‎study various properties of them.

  3. The Circular RFQ Storage Ring

    International Nuclear Information System (INIS)

    Ruggiero, A. G.

    1999-01-01

    This paper presents a novel idea of storage ring for the accumulation of intense beams of light and heavy ions at low energy. The new concept is a natural development of the combined features of conventional storage rings and ion traps, and is basically a linear RFQ bent on itself. The advantages are: smaller beam dimensions, higher beam intensity, and a more compact storage device

  4. Standard Fibre Optic Ring LANs

    Science.gov (United States)

    Beale, N. C. L.

    1985-08-01

    The paper begins with a reminder of the particular need for standards in LANs. We then describe the requirements of High Integrity LANs. Current developments in LAN standards are then outlined. It is argued that the requirements of industrial LANs lead ideally to reconfiguring fibre optic rings, for which there are two major emerging standards. These two (IEEE 802.5 and ANSI FDDI) and the Cambridge Ring are discussed and compared. One implementation - the HILAN is discussed.

  5. Of Rings and Volcanoes

    Science.gov (United States)

    2002-01-01

    Office National d'Etudes et de Recherches Aérospatiales (ONERA) , Laboratoire d'Astrophysique de Grenoble (LAOG) and the DESPA and DASGAL laboratories of the Observatoire de Paris in France, in collaboration with ESO. The CONICA infra-red camera was built, under an ESO contract, by the Max-Planck-Institut für Astronomie (MPIA) (Heidelberg) and the Max-Planck Institut für Extraterrestrische Physik (MPE) (Garching) in Germany, in collaboration with ESO. Saturn - Lord of the rings ESO PR Photo 04a/02 ESO PR Photo 04a/02 [Preview - JPEG: 460 x 400 pix - 54k] [Normal - JPEG: 1034 x 800 pix - 200k] Caption : PR Photo 04a/02 shows the giant planet Saturn, as observed with the VLT NAOS-CONICA Adaptive Optics instrument on December 8, 2001; the distance was 1209 million km. It is a composite of exposures in two near-infrared wavebands (H and K) and displays well the intricate, banded structure of the planetary atmosphere and the rings. Note also the dark spot at the south pole at the bottom of the image. One of the moons, Tethys, is visible as a small point of light below the planet. It was used to guide the telescope and to perform the adaptive optics "refocussing" for this observation. More details in the text. Technical information about this photo is available below. This NAOS/CONICA image of Saturn ( PR Photo 04a/02 ), the second-largest planet in the solar system, was obtained at a time when Saturn was close to summer solstice in the southern hemisphere. At this moment, the tilt of the rings was about as large as it can be, allowing the best possible view of the planet's South Pole. That area was on Saturn's night side in 1982 and could therefore not be photographed during the Voyager encounter. The dark spot close to the South Pole is a remarkable structure that measures approximately 300 km across. It was only recently observed in visible light from the ground with a telescope at the Pic du Midi Observatory in the Pyrenees (France) - this is the first infrared image to

  6. Rhythmic ring-ring stacking drives the circadian oscillator clockwise.

    Science.gov (United States)

    Chang, Yong-Gang; Tseng, Roger; Kuo, Nai-Wei; LiWang, Andy

    2012-10-16

    The oscillator of the circadian clock of cyanobacteria is composed of three proteins, KaiA, KaiB, and KaiC, which together generate a self-sustained ∼24-h rhythm of phosphorylation of KaiC. The mechanism propelling this oscillator has remained elusive, however. We show that stacking interactions between the CI and CII rings of KaiC drive the transition from the phosphorylation-specific KaiC-KaiA interaction to the dephosphorylation-specific KaiC-KaiB interaction. We have identified the KaiB-binding site, which is on the CI domain. This site is hidden when CI domains are associated as a hexameric ring. However, stacking of the CI and CII rings exposes the KaiB-binding site. Because the clock output protein SasA also binds to CI and competes with KaiB for binding, ring stacking likely regulates clock output. We demonstrate that ADP can expose the KaiB-binding site in the absence of ring stacking, providing an explanation for how it can reset the clock.

  7. Accretion in Saturn's F Ring

    Science.gov (United States)

    Meinke, B. K.; Esposito, L. W.; Stewart, G.

    2012-12-01

    Saturn's F ring is the solar system's principal natural laboratory for direct observation of accretion and disruption processes. The ring resides in the Roche zone, where tidal disruption competes with self-gravity, which allows us to observe the lifecycle of moonlets. Just as nearby moons create structure at the B ring edge (Esposito et al. 2012) and the Keeler gap (Murray 2007), the F ring "shepherding" moons Prometheus and Pandora stir up ring material and create observably changing structures on timescales of days to decades. In fact, Beurle et al (2010) show that Prometheus makes it possible for "distended, yet gravitationally coherent clumps" to form in the F ring, and Barbara and Esposito (2002) predicted a population of ~1 km bodies in the ring. In addition to the observations over the last three decades, the Cassini Ultraviolet Imaging Spectrograph (UVIS) has detected 27 statistically significant features in 101 occultations by Saturn's F ring since July 2004. Seventeen of those 27 features are associated with clumps of ring material. Two features are opaque in occultation, which makes them candidates for solid objects, which we refer to as Moonlets. The 15 other features partially block stellar signal for 22 m to just over 3.7 km along the radial expanse of the occultation. Upon visual inspection of the occultation profile, these features resemble Icicles, thus we will refer to them as such here. The density enhancements responsible for such signal attenuations are likely due to transient clumping of material, evidence that aggregations of material are ubiquitous in the F ring. Our lengthy observing campaign reveals that Icicles are likely transient clumps, while Moonlets are possible solid objects. Optical depth is an indicator of clumping because more-densely aggregated material blocks more light; therefore, it is natural to imagine moonlets as later evolutionary stage of icicle, when looser clumps of material compact to form a feature that appears

  8. Double acting stirling engine piston ring

    Science.gov (United States)

    Howarth, Roy B.

    1986-01-01

    A piston ring design for a Stirling engine wherein the contact pressure between the piston and the cylinder is maintained at a uniform level, independent of engine conditions through a balancing of the pressure exerted upon the ring's surface and thereby allowing the contact pressure on the ring to be predetermined through the use of a preloaded expander ring.

  9. Manipulation of vortex rings for flow control

    International Nuclear Information System (INIS)

    Toyoda, Kuniaki; Hiramoto, Riho

    2009-01-01

    This paper reviews the dynamics of vortex rings and the control of flow by the manipulation of vortex rings. Vortex rings play key roles in many flows; hence, the understanding of the dynamics of vortex rings is crucial for scientists and engineers dealing with flow phenomena. We describe the structures and motions of vortex rings in circular and noncircular jets, which are typical examples of flows evolving into vortex rings. For circular jets the mechanism of evolving, merging and breakdown of vortex rings is described, and for noncircular jets the dynamics of three-dimensional deformation and interaction of noncircular vortex rings under the effect of self- and mutual induction is discussed. The application of vortex-ring manipulation to the control of various flows is reviewed with successful examples, based on the relationship between the vortex ring dynamics and the flow properties. (invited paper)

  10. Structure and dynamics of ringed galaxies

    International Nuclear Information System (INIS)

    Buta, R.J.

    1984-01-01

    In many spiral and SO galaxies, single or multiple ring structures are visible in the disk. These inner rings (r), outer rings (R), and nuclear rings (nr) were investigated by means of morphology, photometry, and spectroscopy in order to provide basic data on a long neglected phenomenon. The metric properties of each ring are investigated and found to correlate with the structure of the parent galaxy. When properly calibrated, inner rings in barred (SB) systems can be used as geometric extragalactic distance indicators to distances in excess of 100 Mpc. Other statistics are presented that confirm previous indications that the rings have preferred shapes, relative sizes, and orientations with respect to bars. A survey is made of the less homogeneous non-barred (SA) ringed systems, and the causes of the inhomogeneity are isolated. It is shown that rings can be identified in multiple-ring SA systems that are exactly analogous to those in barred spirals

  11. Treatment of Unstable Pelvic Ring Injuries

    OpenAIRE

    Kim, Weon-Yoo

    2014-01-01

    Pelvic fractures are classified according to the stability of the pelvic ring. Unlike stable pelvic fractures, which heal without complications, unstable fractures may lead to pelvic ring deformities, which cause severe complications. An orthopedic surgeon must determine the stability of the pelvic ring by radiography and physical examination of the patient in order to ensure early, prompt treatment. This article includes anatomy of the pelvic ring, classification of pelvic ring injuries, its...

  12. Ring wormholes via duality rotations

    Directory of Open Access Journals (Sweden)

    Gary W. Gibbons

    2016-09-01

    Full Text Available We apply duality rotations and complex transformations to the Schwarzschild metric to obtain wormhole geometries with two asymptotically flat regions connected by a throat. In the simplest case these are the well-known wormholes supported by phantom scalar field. Further duality rotations remove the scalar field to yield less well known vacuum metrics of the oblate Zipoy–Voorhees–Weyl class, which describe ring wormholes. The ring encircles the wormhole throat and can have any radius, whereas its tension is always negative and should be less than −c4/4G. If the tension reaches the maximal value, the geometry becomes exactly flat, but the topology remains non-trivial and corresponds to two copies of Minkowski space glued together along the disk encircled by the ring. The geodesics are straight lines, and those which traverse the ring get to the other universe. The ring therefore literally produces a hole in space. Such wormholes could perhaps be created by negative energies concentrated in toroidal volumes, for example by vacuum fluctuations.

  13. Dream of Isochronous Ring Again

    CERN Document Server

    Hama, H

    2005-01-01

    More than 20 years ago, D.A.G. Deacon proposed an isochronous storage ring for FEL to avoid bunch heating and decreasing instantaneous gain [1]. Some of low momentum compaction (alpha) operations have been carried out, and recently coherent infrared radiation are observed on a 3rd generation light source. Because the 3rd generation rings are optimized to obtain very low emittance beam, the dispersion function in the arc sections are much reduced by introducing large bending radius, so that those are very big machines. Meanwhile N.A. Vinokurov et al. recently proposed a ring type SASE FEL based on a complete isochronous bending transport [2]. At least, experimental and theoretical study of the isochronous ring so far suggests nonlinear effects resulted from higher order dispersion and chromaticity declines the "complete" isochronous system. On the other hand, in a wavelength region of THz, tolerance of the path length along a turn of the ring seems to be within our reach. A concept to preserve of a form factor...

  14. Preparation of (2' R)- 5' -(2 - 125I-lodo-3-Furanyl)Spiro[1-Azabicyclo [2.2.2] Octane]- 3,2' (3' H) - Furo [2,3-b] Pyridine: A Nicotinic Cholinergic Receptor Tracer

    International Nuclear Information System (INIS)

    Farouk, N.; Talaat, H.M.

    2012-01-01

    The radiochemical synthesis of (2R)-5-(2- 125 l iodo-3-Furanyl) spiro [1- azabicyclo(2,2,2) Octane [-3,2-(311-furo(2,3-b]pyridine was accomplished by radioiodination using iodogen and lactoperoxidase as oxidizing agents. An average radiochemical yields was 95% 88 % and the reactions proceed well within 15-30 min and 45-60 min at 70 degree C using the two oxidizing agents, respectively. Different chromatographic analysis techniques (TLC and HPLC) were used to evaluate the radiochemical yields during the process as well as the purity of the final product with radiochemical purity over 99.9 % and a specific activity of 74 KBq / μg substrate

  15. Novel synthesis of a series of spiro 1,3-indanedione-fused dihydropyridines through the condensation of a tetrone with N-aryl/alkylenamines in presence of solid support silica sulfuric acid.

    Science.gov (United States)

    Kundu, Ashis; Pramanik, Animesh

    2015-08-01

    A convenient protocol for the library synthesis of biologically important 1-aryl-2',6-spiro(1',3'-indanedione)-1H-indeno[1,2-b]quinoline-5,7-diones has been developed. In this one-pot reaction protocol a tetrone is condensed with various N-aryl/alkylenamines of 1,3-cyclohexadiones on the surface of a solid-supported acid catalyst silica sulfuric acid under solvent-free condition. The significant advantages of this methodology are the use of solvent-free reaction conditions, operational simplicity of the reaction, good yield of the products with high atom economy, and employment of a recyclable catalyst. All these favorable factors make the present method convenient, economic, and 'benign by design'.

  16. Primitivity and weak distributivity in near rings and matrix near rings

    International Nuclear Information System (INIS)

    Abbasi, S.J.

    1993-08-01

    This paper shows the structure of matrix near ring constructed over a weakly distributive and primative near ring. It is proved that a weakly distributive primitive near ring is a ring and the matrix near rings constructed over it is also a bag. (author). 14 refs

  17. Heat shock protein 27 mediates the effect of 1,3,5-trihydroxy-13,13-dimethyl-2H-pyran [7,6-b] xanthone on mitochondrial apoptosis in hepatocellular carcinoma.

    Science.gov (United States)

    Fu, Wei-ming; Zhang, Jin-fang; Wang, Hua; Xi, Zhi-chao; Wang, Wei-mao; Zhuang, Peng; Zhu, Xiao; Chen, Shih-chi; Chan, Tak-ming; Leung, Kwong-Sak; Lu, Gang; Xu, Hong-Xi; Kung, Hsiang-fu

    2012-08-03

    Hepatocellular carcinoma (HCC) is a global public health problem which causes approximately 500,000 deaths annually. Considering that the limited therapeutic options for HCC, novel therapeutic targets and drugs are urgently needed. In this study, we discovered that 1,3,5-trihydroxy-13,13-dimethyl-2H-pyran [7,6-b] xanthone (TDP), isolated from the traditional Chinese medicinal herb, Garcinia oblongifolia, effectively inhibited cell growth and induced the caspase-dependent mitochondrial apoptosis in HCC. A two-dimensional gel electrophoresis and mass spectrometry-based comparative proteomics were performed to find the molecular targets of TDP in HCC cells. Eighteen proteins were identified as differently expressed, with Hsp27 protein being one of the most significantly down-regulated proteins induced by TDP. In addition, the following gain- and loss-of-function studies indicated that Hsp27 mediates mitochondrial apoptosis induced by TDP. Furthermore, a nude mice model also demonstrated the suppressive effect of TDP on HCC. Our study suggests that TDP plays apoptosis-inducing roles by strongly suppressing the Hsp27 expression that is specifically associated with the mitochondrial death of the caspase-dependent pathway. In conclusion, TDP may be a potential anti-cancer drug candidate, especially to cancers with an abnormally high expression of Hsp27. Copyright © 2012 Elsevier B.V. All rights reserved.

  18. SBA-15/hydrotalcite nanocomposite as an efficient support for the immobilization of heteropolyacid: A triply-hybrid catalyst for the synthesis of 2-amino-4H-pyrans in water

    Science.gov (United States)

    Sadjadi, Samahe; Heravi, Majid M.; Zadsirjan, Vahideh; Farzaneh, Vahid

    2017-12-01

    To circumvent the high solubility and low surface area of heteropolyacid and in attempt to develop a bi-functional heterogeneous catalyst for promoting organic transformations, heteropolyacid was embedded in functionalized SBA-15 and subsequently hybridized with layered double hydroxide. The catalyst could be considered as a bi-functional catalyst with both acidic and basic properties. The acidic properties emerged from the SBA-15 and heteropolyacid component while layered double hydroxide render the catalyst basic. The catalyst was characterized by using SEM/EDX, FT-IR, XRD, ICP-AES, BET and elemental mapping analysis. The catalytic activity of the catalyst was studied for promoting one-pot three-component condensation of aromatic aldehydes, malononitrile or ethyl cyanoacetate and C-H activated acidic molecules in aqueous media for the synthesis of 2-amino-4H-pyran derivatives. The catalyst exhibited high catalytic activity, which was superior to the previously reported ones. Moreover, the reusability of the catalyst was excellent and the leaching of heteropolyacid was dramatically suppressed. High yields, short reaction times, eco-friendly conditions, simplicity of the procedure, reusability of the catalyst and broad substrate scope are the merits of this protocol.

  19. Proton storage ring summer workshop

    International Nuclear Information System (INIS)

    Lawrence, G.P.; Cooper, R.K.

    1977-10-01

    During the week of August 16, 1976 a Workshop was held at the Los Alamos Scientific Laboratory (LASL) on the Proton Storage Ring (PSR) for the Weapons Neutron Research Facility (WNRF). Written contributions were solicited from each of the participants in the Workshop, and the contributions that were received are presented. The papers do not represent polished or necessarily complete work, but rather represent ''first cuts'' at their respective areas. Topics covered include: (1) background information on the storage ring; (2) WNRF design; (3) rf transient during filling; (4) rf capture; (5) beam bunch compression; (6) transverse space charge limits; (7) transverse resistive instability in the PSR; (8) longitudinal resistive instability; (9) synchrotron frequency splitting; (10) E Quintus Unum--off resonance; (11) first harmonic bunching in the storage ring; (12) kicker considerations; (13) beam extraction; (14) ferrite kicker magnets; and (15) E Quintus Unum: a possible ejection scheme

  20. Adiabatic compression of ion rings

    International Nuclear Information System (INIS)

    Larrabee, D.A.; Lovelace, R.V.

    1982-01-01

    A study has been made of the compression of collisionless ion rings in an increasing external magnetic field, B/sub e/ = zB/sub e/(t), by numerically implementing a previously developed kinetic theory of ring compression. The theory is general in that there is no limitation on the ring geometry or the compression ratio, lambdaequivalentB/sub e/ (final)/B/sub e/ (initial)> or =1. However, the motion of a single particle in an equilibrium is assumed to be completely characterized by its energy H and canonical angular momentum P/sub theta/ with the absence of a third constant of the motion. The present computational work assumes that plasma currents are negligible, as is appropriate for a low-temperature collisional plasma. For a variety of initial ring geometries and initial distribution functions (having a single value of P/sub theta/), it is found that the parameters for ''fat'', small aspect ratio rings follow general scaling laws over a large range of compression ratios, 1 3 : The ring radius varies as lambda/sup -1/2/; the average single particle energy as lambda/sup 0.72/; the root mean square energy spread as lambda/sup 1.1/; and the total current as lambda/sup 0.79/. The field reversal parameter is found to saturate at values typically between 2 and 3. For large compression ratios the current density is found to ''hollow out''. This hollowing tends to improve the interchange stability of an embedded low β plasma. The implications of these scaling laws for fusion reactor systems are discussed

  1. Tree rings and radiocarbon calibration

    International Nuclear Information System (INIS)

    Barbetti, M.

    1999-01-01

    Only a few kinds of trees in Australia and Southeast Asia are known to have growth rings that are both distinct and annual. Those that do are therefore extremely important to climatic and isotope studies. In western Tasmania, extensive work with Huon pine (Lagarostrobos franklinii) has shown that many living trees are more than 1,000 years old, and that their ring widths are sensitive to temperature, rainfall and cloud cover (Buckley et al. 1997). At the Stanley River there is a forest of living (and recently felled) trees which we have sampled and measured. There are also thousands of subfossil Huon pine logs, buried at depths less than 5 metres in an area of floodplain extending over a distance of more than a kilometre with a width of tens of metres. Some of these logs have been buried for 50,000 years or more, but most of them belong to the period between 15,000 years and the present. In previous expeditions in the 1980s and 1990s, we excavated and sampled about 350 logs (Barbetti et al. 1995; Nanson et al. 1995). By measuring the ring-width patterns, and matching them between logs and living trees, we have constructed a tree-ring dated chronology from 571 BC to AD 1992. We have also built a 4254-ring floating chronology (placed by radiocarbon at ca. 3580 to 7830 years ago), and an earlier 1268-ring chronology (ca. 7,580 to 8,850 years ago). There are many individuals, or pairs of logs which match and together span several centuries, at 9,000 years ago and beyond

  2. Superconducting proton ring for PETRA

    International Nuclear Information System (INIS)

    Baynham, E.

    1979-01-01

    A powerful new facility for colliding beam physics could be provided by adding a proton storage ring in the range of several hundred GeV to the electron-positron storage ring PETRA at DESY. This can be achieved in an economic way utilizing the PETRA tunnel and taking advantage of the higher magnetic fields of superconducting magnets which would be placed above or below the PETRA magnets. A central field of 4 Tesla in the bending magnets corresponds to a proton energy of 225 GeV. (orig.)

  3. INVITED TALK: Dynamics Of Planetary Rings

    Science.gov (United States)

    Tiscareno, Matthew S.

    2011-04-01

    Planetary rings are the only nearby astrophysical disks, and the only disks that have been investigated by spacecraft (especially the Cassini spacecraft orbiting Saturn). Although there are significant differences between rings and other disks, chiefly the large planet/ring mass ratio that greatly enhances the flatness of rings (aspect ratios as small as 1e-7), understanding of disks in general can be enhanced by understanding the dynamical processes observed at close-range and in real-time in planetary rings. We will review the known ring systems of the four giant planets, as well as the prospects for ring systems yet to be discovered. We will then review planetary rings by type. The A, B, and C rings of Saturn, plus the Cassini Division, comprise our solar system's only dense broad disk and host many phenomena of general application to disks including spiral waves, gap formation, self-gravity wakes, viscous overstability and normal modes, impact clouds, and orbital evolution of embedded moons. Dense narrow rings are found both at Uranus (where they comprise the main rings entirely) and at Saturn (where they are embedded in the broad disk), and are the primary natural laboratory for understanding shepherding and self-stability. Narrow dusty rings, likely generated by embedded source bodies, are surprisingly found to sport azimuthally-confined arcs both at Saturn, Jupiter, and Neptune. Finally, every known ring system includes a substantial component of diffuse dusty rings.

  4. Soft Neutrosophic Ring and Soft Neutrosophic Field

    Directory of Open Access Journals (Sweden)

    Mumtaz Ali

    2014-04-01

    Full Text Available In this paper we extend the theory of neutrosophic rings and neutrosophic fields to soft sets and construct soft neutrosophic rings and soft neutrosophic fields. We also extend neutrosophic ideal theory to form soft neutrosophic ideal over a neutrosophic ring and soft neutrosophic ideal of a soft neutrosophic ring. We have given many examples to illustrate the theory of soft neutrosophic rings and soft neutrosophic fields and display many properties of these. At the end of this paper we gave soft neutrosophic ring homomorphism.

  5. Thomson's Jumping Ring Over a Long Coil

    Science.gov (United States)

    Jeffery, Rondo N.; Amiri, Farhang

    2018-03-01

    The classic jumping ring apparatus consists of a coil with an iron core that extends out of the coil. A copper or aluminum ring placed over the iron core jumps upward when AC power is applied to the coil. In this paper we will examine a modified design of the jumping ring apparatus, called the "long-coil design." It allows the ring to jump upward or downward, depending on the starting position of the ring. These features shed significant light on the study of the force that causes the ring to jump.

  6. E-læring

    DEFF Research Database (Denmark)

    Heilesen, Simon

    2001-01-01

    E-læring er et modeord og et mantra. Undervisning bliver ikke automatisk bedre af, at der sættes et ”e-” foran. Forbedring og fornyelse af undervisningen er betinget af, at vi forstår computermediets muligheder og skaber forandring ved at tilpasse det til de undervisningsformer, vi ønsker....

  7. ring og it

    DEFF Research Database (Denmark)

      Antologien er et bidrag til didaktiske diskussioner om brug af f.eks. programpakker til sprogundervisning, præsentationsprogrammel og konferencesystemer på de videregående uddannelser. Antologien diskuterer ideen om, at multimediale medier og internettet kan understøtte læring, undervisning og ...

  8. Ring laser frequency biasing mechanism

    International Nuclear Information System (INIS)

    McClure, R.E.

    1975-01-01

    A ring laser cavity including a magnetically saturable member for differentially phase shifting the contradirectional waves propagating in the laser cavity, the phase shift being produced by the magneto-optic interaction occurring between the light waves and the magnetization in the cavity forming component as the light waves are reflected therefrom is described

  9. Counting problems for number rings

    NARCIS (Netherlands)

    Brakenhoff, Johannes Franciscus

    2009-01-01

    In this thesis we look at three counting problems connected to orders in number fields. First we study the probability that for a random polynomial f in Z[X] the ring Z[X]/f is the maximal order in Q[X]/f. Connected to this is the probability that a random polynomial has a squarefree

  10. Wands of the Black Ring

    Czech Academy of Sciences Publication Activity Database

    Pravda, Vojtěch; Pravdová, Alena

    2005-01-01

    Roč. 37, č. 7 (2005), s. 1277-1287 ISSN 0001-7701 R&D Projects: GA ČR GP202/03/P017; GA AV ČR KJB1019403 Institutional research plan: CEZ:AV0Z10190503 Keywords : algebraic classification * Petrov classification * black ring Subject RIV: BA - General Mathematics Impact factor: 1.550, year: 2005

  11. On commutativity theorems for rings

    Directory of Open Access Journals (Sweden)

    H. A. S. Abujabal

    1990-01-01

    Full Text Available Let R be an associative ring with unity. It is proved that if R satisfies the polynomial identity [xny−ymxn,x]=0(m>1,n≥1, then R is commutative. Two or more related results are also obtained.

  12. International Tree Ring Data Bank (ITRDB)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Tree ring data from the International Tree Ring Data Bank and World Data Center for Paleoclimatology archives. Data include raw treering measurements (most are...

  13. Planetary science: Shepherds of Saturn's ring

    Science.gov (United States)

    Crida, Aurélien

    2015-09-01

    Saturn's F ring is chaperoned on both sides by the tiny moons Prometheus and Pandora. Numerical simulations show that this celestial ballet can result from the collision of two aggregates that evolved out of Saturn's main rings.

  14. Planetary ring systems properties, structures, and evolution

    CERN Document Server

    Murray, Carl D

    2018-01-01

    Planetary rings are among the most intriguing structures of our solar system and have fascinated generations of astronomers. Collating emerging knowledge in the field, this volume reviews our current understanding of ring systems with reference to the rings of Saturn, Uranus, Neptune, and more. Written by leading experts, the history of ring research and the basics of ring–particle orbits is followed by a review of the known planetary ring systems. All aspects of ring system science are described in detail, including specific dynamical processes, types of structures, thermal properties and their origins, and investigations using computer simulations and laboratory experiments. The concluding chapters discuss the prospects of future missions to planetary rings, the ways in which ring science informs and is informed by the study of other astrophysical disks, and a perspective on the field's future. Researchers of all levels will benefit from this thorough and engaging presentation.

  15. Nonlinear analysis of ring oscillator circuits

    KAUST Repository

    Ge, Xiaoqing

    2010-06-01

    Using nonlinear systems techniques, we analyze the stability properties and synchronization conditions for ring oscillator circuits, which are essential building blocks in digital systems. By making use of its cyclic structure, we investigate local and global stability properties of an n-stage ring oscillator. We present a sufficient condition for global asymptotic stability of the origin and obtain necessity if the ring oscillator consists of identical inverter elements. We then give a synchronization condition for identical interconnected ring oscillators.

  16. On P-coherent endomorphism rings

    Indian Academy of Sciences (India)

    A ring is called right -coherent if every principal right ideal is finitely presented. Let M R be a right -module. We study the -coherence of the endomorphism ring of M R . It is shown that is a right -coherent ring if and only if every endomorphism of M R has a pseudokernel in add M R ; S is a left -coherent ring if and ...

  17. Tree-ring anomalies in Toona ciliata

    OpenAIRE

    Heinrich, Ingo; Banks, John Charles Gripper

    2006-01-01

    New increment core samples of Toona ciliata collected in the Australian tropics and subtropics compared to already existing material from the Upper Kangaroo Valley, near Sydney exhibit distinct differences in tree-ring structures. This necessitated a closer examination of the wood anatomy, possible false rings and the species’ crossdating capacity in northeast Australia. During tree-ring analysis two growth anomalies (extensive zones of narrow and indistinct rings) and three types of false ri...

  18. The Hi-Ring DCN Architecture

    DEFF Research Database (Denmark)

    Galili, Michael; Kamchevska, Valerija; Ding, Yunhong

    2016-01-01

    We will review recent work on the proposed hierarchical ring-based architecture (HiRing) proposed for data center networks. We will discuss the architecture and initial demonstrations of optical switching performance and time-domain synchronization......We will review recent work on the proposed hierarchical ring-based architecture (HiRing) proposed for data center networks. We will discuss the architecture and initial demonstrations of optical switching performance and time-domain synchronization...

  19. Random Implantation of Asymmetric Intracorneal Rings

    Directory of Open Access Journals (Sweden)

    Cristina Peris-Martínez

    2014-01-01

    Full Text Available Intracorneal ring employment for treating ectasia is widespread. Although the mechanism of action of intracorneal rings in the regularization of the corneal surface after its implantation is well known in most cases, there are still many doubts. We present a case of implanted intracorneal rings, where, despite the peculiar position of the rings, the patient gains lines of visual acuity and keratoconus remains stable.

  20. Edge-on View of Saturn's Rings

    Science.gov (United States)

    1996-01-01

    TOP - This is a NASA Hubble Space Telescope snapshot of Saturn with its rings barely visible. Normally, astronomers see Saturn with its rings tilted. Earth was almost in the plane of Saturn's rings, thus the rings appear edge-on.In this view, Saturn's largest moon, Titan, is casting a shadow on Saturn. Titan's atmosphere is a dark brown haze. The other moons appear white because of their bright, icy surfaces. Four moons - from left to right, Mimas, Tethys, Janus, and Enceladus - are clustered around the edge of Saturn's rings on the right. Two other moons appear in front of the ring plane. Prometheus is on the right edge; Pandora, on the left. The rings also are casting a shadow on Saturn because the Sun was above the ring plane.BOTTOM - This photograph shows Saturn with its rings slightly tilted. The moon called Dione, on the lower right, is casting a long, thin shadow across the whole ring system due to the setting Sun on the ring plane. The moon on the upper left of Saturn is Tethys.Astronomers also are studying the unusual appearance of Saturn's rings. The bottom image displays a faint, narrow ring, the F-ring just outside the main ring, which normally is invisible from Earth. Close to the edge of Saturn's disk, the front section of rings seem brighter and more yellow than the back due to the additional lumination by yellowish Saturn.The color images were assembled from separate exposures taken August 6 (top) and November 17 (bottom), 1995 with the Wide Field Planetary Camera-2.The Wide Field/Planetary Camera 2 was developed by the Jet Propulsion Laboratory and managed by the Goddard Spaced Flight Center for NASA's Office of Space Science.This image and other images and data received from the Hubble Space Telescope are posted on the World Wide Web on the Space Telescope Science Institute home page at URL http://oposite.stsci.edu/pubinfo/

  1. Optical fiber having wave-guiding rings

    Science.gov (United States)

    Messerly, Michael J [Danville, CA; Dawson, Jay W [Livermore, CA; Beach, Raymond J [Livermore, CA; Barty, Christopher P. J. [Hayward, CA

    2011-03-15

    A waveguide includes a cladding region that has a refractive index that is substantially uniform and surrounds a wave-guiding region that has an average index that is close to the index of the cladding. The wave-guiding region also contains a thin ring or series of rings that have an index or indices that differ significantly from the index of the cladding. The ring or rings enable the structure to guide light.

  2. Familial transmission of a ring chromosome 21

    DEFF Research Database (Denmark)

    Hertz, Jens Michael

    1987-01-01

    A ring chromosome 21 was found in a phenotypically normal mother and her son. The clinical findings in the son were bilateral retention of the testes and a slightly delayed puberty onset. Consequences of a ring formation of a chromosome 21 in phenotypically normal patients are presented...... and discussed, and the previously reported cases of familially transmitted G-group ring chromosomes are reviewed....

  3. Self-gravitation in Saturn's rings

    International Nuclear Information System (INIS)

    Salo, H.; Lukkari, J.

    1982-01-01

    In a ring-shaped collisional system self-gravitation reduces the equilibrium values of the geometric and optical thickness. In Saturn's rings both effects are appreciable. The previously found discrepancy between the calculated profile and the observed profile of the rings is chiefly caused by the omission of self-gravitation. (Auth.)

  4. Anomalous dark growth rings in black cherry

    Science.gov (United States)

    Robert P. Long; David W. Trimpey; Michael C. Wiemann; Susan L. Stout

    2012-01-01

    Anomalous dark growth rings have been observed in black cherry (Prunus serotina) sawlogs from northwestern Pennsylvania making the logs unsuitable for veneer products. Thirty-six cross sections with dark rings, each traceable to one of ten stands, were obtained from a local mill and sections were dated and annual ring widths were measured. One or...

  5. A Ring Construction Using Finite Directed Graphs

    Science.gov (United States)

    Bardzell, Michael

    2012-01-01

    In this paper we discuss an interesting class of noncommutative rings which can be constructed using finite directed graphs. This construction also creates a vector space. These structures provide undergraduate students connections between ring theory and graph theory and, among other things, allow them to see a ring unity element that looks quite…

  6. Laser driven structured quantum rings

    Science.gov (United States)

    Castiglia, Giuseppe; Corso, Pietro Paolo; De Giovannini, Umberto; Fiordilino, Emilio; Frusteri, Biagio

    2015-06-01

    In this work we study harmonic emission from structured quantum rings (SQRs). In SQRs, electrons trapped in two-dimensional structures are further confined by an external potential composed of N scattering centers arranged on a circle. We build a suitable one-dimensional model Hamiltonian describing this class of systems and analytically solve the associated Schödinger equation. We find that the solution can be expressed in terms of Mathieu functions and focus on the specific case of N = 6. By exactly solving the time-dependent Schödinger equation, we then show how the harmonic response to linearly polarized lasers strongly depends on the ring physical parameters. The results illustrate how the additional degrees of freedom introduced by these parameters provide important handles to control the emitted spectrum that in some cases extends into the XUV region.

  7. Fiber Ring Optical Gyroscope (FROG)

    Science.gov (United States)

    1979-01-01

    The design, construction, and testing of a one meter diameter fiber ring optical gyro, using 1.57 kilometers of single mode fiber, are described. The various noise components: electronic, thermal, mechanical, and optical, were evaluated. Both dc and ac methods were used. An attempt was made to measure the Earth rotation rate; however, the results were questionable because of the optical and electronic noise present. It was concluded that fiber ring optical gyroscopes using all discrete components have many serious problems that can only be overcome by discarding the discrete approach and adapting an all integrated optic technique that has the laser source, modulator, detector, beamsplitters, and bias element on a single chip.

  8. Behavioral Mapless Navigation Using Rings

    Science.gov (United States)

    Monroe, Randall P.; Miller, Samuel A.; Bradley, Arthur T.

    2012-01-01

    This paper presents work on the development and implementation of a novel approach to robotic navigation. In this system, map-building and localization for obstacle avoidance are discarded in favor of moment-by-moment behavioral processing of the sonar sensor data. To accomplish this, we developed a network of behaviors that communicate through the passing of rings, data structures that are similar in form to the sonar data itself and express the decisions of each behavior. Through the use of these rings, behaviors can moderate each other, conflicting impulses can be mediated, and designers can easily connect modules to create complex emergent navigational techniques. We discuss the development of a number of these modules and their successful use as a navigation system in the Trinity omnidirectional robot.

  9. Livslang læring

    DEFF Research Database (Denmark)

    Larson, Anne

    2016-01-01

    Pædagogisk sociologi beskæftiger sig blandt andet med de politiske rammebetingelser for opdragelse, undervisning, socialisering og uddannelse. I dette kapitel præsenteres en komparativ undersøgelse af EU’s politik med hensyn til livslang læring på den ene side, og den danske politik og lovgivning...... tilgang kaldet ‘What is the problem represented to be?’...

  10. ring og vejledning

    DEFF Research Database (Denmark)

    Ambjørn, Lone

    Formålet med kompendiet om forskellige aspekter omkring sproglig læring er at ruste de studerende til studiet på en højere læreranstalt; at højne effektiviteten i deres sproglige læringsproces; at lære de studerende at arbejde uafhængigt af underviseren; at give de studerende de nødvendige redska...

  11. Two superconducting storage rings: ISABELLE

    International Nuclear Information System (INIS)

    Sanford, J.R.

    1978-01-01

    The general features of the design and the status of the ISABELLE storage ring project at the present time are reported. It brings up to date the results reported at the National Particle Accelerator Conference in March 1977. The most significant change since that time has been an upgrading of the energy of the overall facility, and acceptance of the project by the Department of Energy

  12. ring mellem elever

    DEFF Research Database (Denmark)

    Georgsen, Marianne; Davidsen, Jacob

    2010-01-01

    I denne rapport præsenteres resultater fra følgeforskningen til projektet Læring gennem Bevægelse, som er gennemført på Søndervangskolen i Hammel i perioden august 2009 - maj 2010. Projektet er gennemført i samspil mellem lærere, it-vejleder, elever og skolens ledelse. Projektets overordnede formål...

  13. ring mellem elever

    DEFF Research Database (Denmark)

    Davidsen, Jacob; Georgsen, Marianne

    I denne rapport tilbyder vi et indblik i det gennemførte projekt, og forfatterne har valgt nogle forhold ud, som belyses og diskuteres, mens andre ikke berøres eller diskuteres nævneværdigt i denne rapport. Det skyldes blandt andet projektets mange facetter, som dækker både læring, teknologi, pæd...

  14. Progressiv læring

    DEFF Research Database (Denmark)

    Wahlgren, Bjarne

    2017-01-01

    undervisningen. • At der afsættes tid til implementeringen, og at det gøres tydeligt, at implementering tager tid. • At organiseringen af undervisningen på skolerne tilpasses, så det letter anvendelsen af principperne i Progressiv Læring. • At lærernes kompetenceudvikling er forankret på skolen både emnemæssigt...

  15. (S-6-{[(S-2,2-Dimethyl-1,3-dioxolan-4-yl]methyl}-5,5-difluoro-5,6-dihydro-2H-pyran-2-one

    Directory of Open Access Journals (Sweden)

    Zengsheng Yin

    2009-08-01

    Full Text Available The title compound, C11H14F2O4, is a γ,γ-gem-difluorinated α,β-unsaturated δ-lactone. The dioxolane five-membered ring and the lactone ring adopt half-chair conformations. There are two intermolecular C—H...O interactions involving the carbonyl group as an acceptor which stabilize the crystal structure.

  16. One-Pot Eco-Safe Saccharin-Catalyzed Procedure for Expedient and Convenient Synthesis of Dihydropyrano[2,3-c]pyrazole, Tetrahydrobenzo[b]pyran and Pyrano[2,3-d]pyrimidinone Scaffolds as a Green and Versatile Catalyst

    Directory of Open Access Journals (Sweden)

    Farzaneh Mohamadpour

    2018-02-01

    Full Text Available A green and facile saccharin-catalyzed procedure is developed for the one-pot convenient synthesis of dihydropyrano[2,3-c]pyrazole, tetrahydrobenzo[b]pyran and pyrano[2,3-d]pyrimidinone scaffolds via multi-component tandem Knoevenagel cyclocondensation reaction. This procedure has the chief advantages of green, inexpensive and readily available catalyst, high atom-economy, high to quantitative yields and the reaction procedure is mild and involves facile workup procedure to obtain the desired products in short reaction times.

  17. Multi-wavelength studies of Saturn's rings to constrain ring particle properties and ring structure

    Science.gov (United States)

    Spilker, L.; Deau, E.; Morishima, R.; Filacchione, G.; Hedman, M.; Nicholson, P.; Colwell, J.; Bradley, T.

    2012-04-01

    A great deal can be learned about the nature of Saturn's ring particles and their regoliths by modeling the changes in brightness, color and temperature with changing viewing geometry over a wide range of wavelengths, from ultraviolet through the thermal infrared. Data from Cassini's Composite Infrared Spectrometer (CIRS), Visual and Infrared Mapping Spectrometer (VIMS), Imaging Science Subsystem (ISS) and Ultraviolet Imaging Spectrograph (UVIS) are jointly being studied using scans of the lit and unlit main rings (A, B, C and Cassini Division) at multiple geometries and solar elevations. Using multi-wavelength data sets allow us to test different thermal models by combining the effects of particle albedo, regolith grain size and surface roughness with thermal emissivity and inertia, particle spin rate and spin axis orientation. With the high spatial resolution of the Cassini data it is now possible to analyze these effects at smaller spatial scales and characterize regions such as the C ring plateaus and ringlets, where albedo differences may be present. In the CIRS data, over a range of solar elevations from -23 degrees to -8 degrees, the bulk of the temperature variations are confined primarily to phase angle. Only small temperature differences are observed with changing spacecraft elevation. Similar behavior is seen in the ISS color data. Color and temperature dependence with changing solar elevation angle are also observed. VIMS observations show that the IR ice absorption band depths are (almost) independent of phase angle, out to ~140 deg phase, suggesting that interparticle light scattering is relatively unimportant except at very high phase angles. These results imply that the individual properties of the ring particles may play a larger role than the collective properties of the rings, in particular at visible wavelengths. The temperature and color variation with phase angle may be a result of scattering within the regolith and on possibly rough surfaces

  18. Polyurethane Foams with Pyrimidine Rings

    Directory of Open Access Journals (Sweden)

    Kania Ewelina

    2014-09-01

    Full Text Available Oligoetherols based on pyrimidine ring were obtained upon reaction of barbituric acid with glycidol and alkylene carbonates. These oligoetherols were then used to obtain polyurethane foams in the reaction of oligoetherols with isocyanates and water. The protocol of foam synthesis was optimized by the choice of proper kind of oligoetherol and synthetic composition. The thermal resistance was studied by dynamic and static methods with concomitant monitoring of compressive strength. The polyurethane foams have similar physical properties as the classic ones except their enhanced thermal resistance. They stand long-time heating even at 200°C. Moreover thermal exposition of foams results generally in increase of their compressive strength.

  19. Ring with changeable radiation dosimeter

    International Nuclear Information System (INIS)

    Collica, C.; Epifano, L.; Farella, R.

    1976-01-01

    A ring for housing a disc of radiation measuring material is described comprising a band having a circular shape and a housing integral with the band. The housing comprises a hollow cylindrical section substantially normal to the band surface and terminating in an inwardly disposed annular flange which defines a substantially circular aperture. In a preferred embodiment of the invention a retaining protrusion formed on the inside of the cylindrical section and spaced from the annular flange is provided to retain a plurality of discs mounted in the housing in layered fashion

  20. Storage ring proton EDM experiment

    CERN Multimedia

    CERN. Geneva

    2015-01-01

    sensitivity of 10^-29 e-cm.  The strength of the method originates from the fact that there are high intensity polarized proton beams available and the fact that the so-called geometric phase systematic error background cancels with clock-wise and counter-clock-wise storage possible in electric rings. The ultimate sensitivity of the method is 10^-30 e-cm. At this level it will either detect a non-zero EDM or it will eliminate electro-weak baryogenesis.

  1. Longitudinal dynamics in storage rings

    International Nuclear Information System (INIS)

    Colton, E.P.

    1986-01-01

    The single-particle equations of motion are derived for charged particles in a storage ring. Longitudinal space charge is included in the potential assuming an infinitely conducting circular beam pipe with a distributed inductance. The framework uses Hamilton's equations with the canonical variables phi and W. The Twiss parameters for longitudinal motion are also defined for the small amplitude synchrotron oscillations. The space-charge Hamiltonian is calculated for both parabolic bunches and ''matched'' bunches. A brief analysis including second-harmonic rf contributions is also given. The final sections supply calculations of dynamical quantities and particle simulations with the space-charge effects neglected

  2. Interface-læring

    DEFF Research Database (Denmark)

    Thorhauge, Sally

    2015-01-01

    Interface-læring er den læringsoplevelse, der kan opstå i grænsefladen mellem to væsensforskellige læringsmiljøer, når de mødes og griber ind i hinanden. Et gymnasium og et museum er eksempler på to sådanne læringsmiljøer. Artiklen præsenterer nogle af de væsentligste resultater fra min ph.d. afh...

  3. SpiroZin1: a reversible and pH-Insensitive, reaction-based, red-fluorescent probe for imaging biological mobile zinc.

    Science.gov (United States)

    Rivera-Fuentes, Pablo; Lippard, Stephen J

    2014-06-01

    A reversible, reaction-based sensor for biological mobile zinc was designed, prepared, and characterized. The sensing mechanism of this probe is based on the zinc-induced, ring-opening reaction of spirobenzopyran to give a cyanine fluorophore that emits in the deep-red region of the electromagnetic spectrum. This probe is not activated by protons and operates efficiently in aqueous solution at pH 7 and high ionic strength. The mechanism of this reaction was studied by using a combination of kinetics experiments and DFT calculations. The biocompatibility of the probe was demonstrated in live HeLa cells. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  4. Boom and Bust Cycles in Saturn's Rings

    Science.gov (United States)

    Esposito, L. W.; Meinke, B. K.; Sremcevic, M.; Albers, N.

    2010-12-01

    Cassini UVIS occultation data show clumping in Saturn’s F ring and at the B ring outer edge, indicating aggregation and disaggregation at these locations perturbed by Mimas and Prometheus. Timescales range from hours to months. The maximum clumping lags the moon by roughly π in the forcing frame. This indicates a direct relation between the moon and the ring clumping. We propose that the collective behavior of the ring particles resembles a predator-prey system: the aggregate mean size is the prey, which feeds the velocity dispersion; conversely, increasing dispersion breaks up the aggregates. For realistic values of the parameters this creates a limit cycle behavior, as for the ecology of foxes and hares or the boom-bust economic cycle. Solving for the long-term behavior of this forced system gives a periodic response at the perturbing frequency, with a phase lag roughly consistent with the UVIS occultation measurements. We conclude that the agitation by the moons at both these locations in the F ring and at the B ring outer edge drives aggregation and disaggregation in the forcing frame. This agitation of the ring material allows fortuitous formation of solid objects from the temporary clumps, via stochastic processes like compaction, adhesion, sintering or reorganization that drives the denser parts of the aggregate to the center or ejects the lighter elements. These more persistent objects would then orbit at the Kepler rate. Such processes can create the equinox objects seen at the B ring edge and in the F ring, explain the ragged nature of those ring regions and allow for rare events to aggregate ring particles into solid objects, recycling the ring material and extending the ring lifetime.

  5. The cryogenic storage ring CSR

    Science.gov (United States)

    von Hahn, R.; Becker, A.; Berg, F.; Blaum, K.; Breitenfeldt, C.; Fadil, H.; Fellenberger, F.; Froese, M.; George, S.; Göck, J.; Grieser, M.; Grussie, F.; Guerin, E. A.; Heber, O.; Herwig, P.; Karthein, J.; Krantz, C.; Kreckel, H.; Lange, M.; Laux, F.; Lohmann, S.; Menk, S.; Meyer, C.; Mishra, P. M.; Novotný, O.; O'Connor, A. P.; Orlov, D. A.; Rappaport, M. L.; Repnow, R.; Saurabh, S.; Schippers, S.; Schröter, C. D.; Schwalm, D.; Schweikhard, L.; Sieber, T.; Shornikov, A.; Spruck, K.; Sunil Kumar, S.; Ullrich, J.; Urbain, X.; Vogel, S.; Wilhelm, P.; Wolf, A.; Zajfman, D.

    2016-06-01

    An electrostatic cryogenic storage ring, CSR, for beams of anions and cations with up to 300 keV kinetic energy per unit charge has been designed, constructed, and put into operation. With a circumference of 35 m, the ion-beam vacuum chambers and all beam optics are in a cryostat and cooled by a closed-cycle liquid helium system. At temperatures as low as (5.5 ± 1) K inside the ring, storage time constants of several minutes up to almost an hour were observed for atomic and molecular, anion and cation beams at an energy of 60 keV. The ion-beam intensity, energy-dependent closed-orbit shifts (dispersion), and the focusing properties of the machine were studied by a system of capacitive pickups. The Schottky-noise spectrum of the stored ions revealed a broadening of the momentum distribution on a time scale of 1000 s. Photodetachment of stored anions was used in the beam lifetime measurements. The detachment rate by anion collisions with residual-gas molecules was found to be extremely low. A residual-gas density below 140 cm-3 is derived, equivalent to a room-temperature pressure below 10-14 mbar. Fast atomic, molecular, and cluster ion beams stored for long periods of time in a cryogenic environment will allow experiments on collision- and radiation-induced fragmentation processes of ions in known internal quantum states with merged and crossed photon and particle beams.

  6. Replantation of ring avulsion amputations

    Directory of Open Access Journals (Sweden)

    Sabapathy R

    2003-01-01

    Full Text Available Replantation of ring avulsion injuries is a challenge because of the long segment damage to the vessels and intrinsic damage caused to soft tissues at the proximal edge of the amputation. Eight patients with total ring avulsion amputations underwent microsurgical replantation in the period 1994 to 2002. Arterial repair was done by direct vessel suture in three patients, interposition vein grafts in two and cross anastomosis of the digital arteries in three patients. Venous anastomosis was carried out by mobilization and direct suture in seven patients and vessel transfer from the adjacent finger in one patient. Seven of the eight replantations were successful, while one patient had a partial failure. At a minimum follow-up of one year, these patients showed good functional and cosmetic recovery. All successful patients were happy with the outcome and none have requested for amputation, even those whose results were not functionally adequate. However, in addition to technical factors, it is important to evaluate the patient's motivation to undergo not only the long surgery, but also multiple secondary procedures and regular supervised physiotherapy. We also describe a simple method which prevents the soft tissues inside the degloved digit from becoming wrapped around the K wire during bony fixation, thus making one step of this technically challenging procedure a little easier.

  7. New diols with imidazoquinazoline ring

    Science.gov (United States)

    Szyszkowska, Agnieszka; Klasek, Antonin; Pawlędzio, Sylwia; Trzybiński, Damian; Woźniak, Krzysztof; Zarzyka, Iwona

    2018-02-01

    The objective of these studies was to synthesize and characterize new diols with an imidazoquinazoline ring. New diols were obtained in reactions of 2,6-bis-(ethoxycarbonylmethyl)-1-phenylimidazo[1,5-c]quinazoline-3,5-dione with excess of ethylene glycol or in reaction of 1-phenyl-2H,6H-imidazo[1,5-c]quinazoline-3,5-dione with 2-M excess of ethylene oxide. The products were isolated at high yield and characterized by instrumental methods (IR, 1H- and 13C-NMR, MS-ESI, UV, TGA). The structure of 2,6-bis(2-hydroxyethyl)-1-phenylimidazo[1,5-c]quinazoline-3,5-dione (BEFIQ) was also investigated by single-crystal X-ray diffraction. BEFIQ crystallizes in the monoclinic P21/n space group with two molecules in the asymmetric unit of the crystal lattice. The nature of the packing of molecules in the crystal lattice of BEFIQ was investigated by Hirshfeld surface analysis. The described methods enable the synthesis of new diols with an imidazoquinazoline ring. The new diols are quite soluble in typical organic solvents. Therefore, they can be used as raw materials for the synthesis of thermally stable polymers, and they can also have biological activity.

  8. Methyl 5,7-dihydroxy-2,2,9-trimethyl-6,11-dioxo-6,11-dihydro-2H-anthra[2,3-b]pyran-8-carboxylate

    Directory of Open Access Journals (Sweden)

    Annelise Lobstein

    2008-12-01

    Full Text Available The title compound, C22H18O7, also known as laurentiquinone B, is a new anthraquinone which was isolated from Vismia laurentii, a Cameroonian medicinal plant. The asymmetric unit contains two independent molecules. Each of them contains four fused rings, three of which are coplanar and typical of anthracene, while the heterocyclic rings adopt envelope conformations. Intramolecular O—H...O hydrogen bonds result in the formation of two planar rings, which are also almost coplanar with the adjacent rings. In the crystal structure, intermolecular O—H...O and C—H...O hydrogen bonds link the molecules and a π–π contact is also present [centroid-centroid distance = 3.967 (3 Å].

  9. A first course in noncommutative rings

    CERN Document Server

    Lam, T Y

    2001-01-01

    A First Course in Noncommutative Rings, an outgrowth of the author's lectures at the University of California at Berkeley, is intended as a textbook for a one-semester course in basic ring theory. The material covered includes the Wedderburn-Artin theory of semisimple rings, Jacobson's theory of the radical, representation theory of groups and algebras, prime and semiprime rings, local and semilocal rings, perfect and semiperfect rings, etc. By aiming the level of writing at the novice rather than the connoisseur and by stressing th the role of examples and motivation, the author has produced a text that is suitable not only for use in a graduate course, but also for self- study in the subject by interested graduate students. More than 400 exercises testing the understanding of the general theory in the text are included in this new edition.

  10. Foundations of commutative rings and their modules

    CERN Document Server

    Wang, Fanggui

    2016-01-01

    This book provides an introduction to the basics and recent developments of commutative algebra. A glance at the contents of the first five chapters shows that the topics covered are ones that usually are included in any commutative algebra text. However, the contents of this book differ significantly from most commutative algebra texts: namely, its treatment of the Dedekind–Mertens formula, the (small) finitistic dimension of a ring, Gorenstein rings, valuation overrings and the valuative dimension, and Nagata rings. Going further, Chapter 6 presents w-modules over commutative rings as they can be most commonly used by torsion theory and multiplicative ideal theory. Chapter 7 deals with multiplicative ideal theory over integral domains. Chapter 8 collects various results of the pullbacks, especially Milnor squares and D+M constructions, which are probably the most important example-generating machines. In Chapter 9, coherent rings with finite weak global dimensions are probed, and the local ring of weak gl...

  11. Report of the eRHIC Ring-Ring Working Group

    Energy Technology Data Exchange (ETDEWEB)

    Aschenauer, E. C. [Brookhaven National Lab. (BNL), Upton, NY (United States); Berg, S. [Brookhaven National Lab. (BNL), Upton, NY (United States); Blaskiewicz, M. [Brookhaven National Lab. (BNL), Upton, NY (United States); Brennan, M. [Brookhaven National Lab. (BNL), Upton, NY (United States); Fedotov, A. [Brookhaven National Lab. (BNL), Upton, NY (United States); Fischer, W. [Brookhaven National Lab. (BNL), Upton, NY (United States); Litvinenko, V. [Brookhaven National Lab. (BNL), Upton, NY (United States); Montag, C. [Brookhaven National Lab. (BNL), Upton, NY (United States); Palmer, R. [Brookhaven National Lab. (BNL), Upton, NY (United States); Parker, B. [Brookhaven National Lab. (BNL), Upton, NY (United States); Peggs, S. [Brookhaven National Lab. (BNL), Upton, NY (United States); Ptitsyn, V. [Brookhaven National Lab. (BNL), Upton, NY (United States); Ranjbar, V. [Brookhaven National Lab. (BNL), Upton, NY (United States); Tepikian, S. [Brookhaven National Lab. (BNL), Upton, NY (United States); Trbojevic, D. [Brookhaven National Lab. (BNL), Upton, NY (United States); Willeke, F. [Brookhaven National Lab. (BNL), Upton, NY (United States)

    2015-10-13

    This report evaluates the ring-ring option for eRHIC as a lower risk alternative to the linac-ring option. The reduced risk goes along with a reduced initial luminosity performance. However, a luminosity upgrade path is kept open. This upgrade path consists of two branches, with the ultimate upgrade being either a ring-ring or a linac-ring scheme. The linac-ring upgrade could be almost identical to the proposed linac-ring scheme, which is based on an ERL in the RHIC tunnel. This linac-ring version has been studied in great detail over the past ten years, and its significant risks are known. On the other hand, no detailed work on an ultimate performance ring-ring scenario has been performed yet, other than the development of a consistent parameter set. Pursuing the ring-ring upgrade path introduces high risks and requires significant design work that is beyond the scope of this report.

  12. ring og den kulturhistoriske skole

    DEFF Research Database (Denmark)

    Broström, Stig

    2007-01-01

    -forskere uddrager den grundlæggende forståelse af forholdet mellem læring og udvikling. Nemlig at læring og udvikling indgår i en dialektisk enhed og virker gensidigt ind på hinanden - dog således at læring kommer ført, den trækker udviklingen med sig og så at sige leder udviklingen. Vygotskys tese vedrørende...

  13. On the potential of large ring lasers

    Science.gov (United States)

    Stedman, G. E.; Hurst, R. B.; Schreiber, K. U.

    2007-11-01

    We describe a new ring laser with area A = 833 m 2 and update performance statistics for several such machines. Chaio and Anandan [R.Y. Chaio, J. Anandan, Gen. Relat. Gravit. 14 (1982) 515-521] judged ring lasers inferior to matter interferometers as possible detectors of gravitational waves. However, we note that geophysically interesting results have been obtained from large ring lasers and that there is still a lot of room for improvements.

  14. Arkitektur krop og læring

    DEFF Research Database (Denmark)

    Gulløv, E.; Coninck-Smith, N. D.; Pedersen, S. H.

    Når vi taler om læring, tænker vi sædvanligvis på resultatet af bevidst tilrettelagt undervisningsforløb. Megen læring sker imidlertid ubevidst via den påvirkning, omgivelserne øver på vores kroppe og vores sanser. I arkitektur, krop og læring gives en teoretisk og analytisk fremstilling af forsk......, Gebauer, Wulf, Lorentzer, Merleau-Ponty, Barth, Ehn....

  15. RRF rings which are not LRF

    Indian Academy of Sciences (India)

    All the rings we consider will be associative rings with an identity element 1 TИ 0 and all the modules considered will be unital modules. In what follows A denotes a ring, mod-A. (respectively A-mod) will denote the category of right (respectively left) A-modules. Recall (Definition 2.1 in [9]) that an A-module M is said to be ...

  16. Relatively Orthocomplemented Skew Nearlattices in Rickart Rings

    Directory of Open Access Journals (Sweden)

    Cīırulis Jānis

    2015-12-01

    Full Text Available A class of (right Rickart rings, called strong, is isolated. In particular, every Rickart *-ring is strong. It is shown in the paper that every strong Rickart ring R admits a binary operation which turns R into a right normal band having an upper bound property with respect to its natural order ≤; such bands are known as right normal skew nearlattices. The poset (R, ≤ is relatively orthocomplemented; in particular, every initial segment in it is orthomodular.

  17. Saturn’s ring temperatures at equinox

    Science.gov (United States)

    Spilker, Linda J.; Ferrari, C.; Morishima, R.

    2013-10-01

    Modeling the thermal emission of Saturn's rings is challenging due to the numerous heating sources as well as the structural properties of the disk and of the particles that are closely related. At equinox, however, the main rings are externally heated by Saturn alone and the problem is somewhat simplified. We test the abilities of our current models to reproduce the temperatures observed with the Cassini CIRS instrument around equinox in August 2009. A simple semi-analytic model which includes mutual shadowing effects can mostly explain the radial profile of the equinox ring temperatures, except the model predicts lower temperatures than those observed for the A ring. The temperature variation at a given saturnocentric radius is primarily caused by observational geometry variations relative to Saturn. The observed temperature increases with decreasing Saturn-ring-observer angle. In addition, we found evidence that the leading hemispheres of particles are warmer than the trailing hemispheres at least for the C ring and probably for the A and B rings as well. This is explained if some fraction of particles has spin rates lower than the synchronous rotation rate as predicted by N-body simulations. The spin model for a monolayer ring (Ferrari, C., Leyrat, C., 2006, Astron. Astrophys. 447, 745-760) can fit the temperature variations with spacecraft longitude observed in the C ring with currently known thermal properties and a mixing of slow and fast rotators. The multilayer model (Morishima, R., Salo, H., Ohtsuki, K., 2009, Icarus 201, 634-654) can reproduce the temperatures of the B and C rings but gives A ring temperatures that are significantly lower than those observed as does the simple semi-analytic model. More advanced models which take into account self-gravity wakes may explain the A ring temperature behavior.

  18. Parameter Scan for the CLIC Damping Rings

    CERN Document Server

    Papaphilippou, Y; Korostelev, M

    2008-01-01

    Triggered by the RF frequency reduction of the CLIC main linac cavities, the damping ring parameters had to be reevaluated and the rings performance adapted to the new luminosity requirements. In view of a staged approach for reaching the ultimate energy of the collider, the dependence of the rings output emittances under the influence of Intrabeam Scattering is evaluated with respect to different beam characteristics such as bunch population, beam energy, coupling and longitudinal beam characteristics.

  19. Design of Piston Ring Friction Tester Apparatus

    DEFF Research Database (Denmark)

    Klit, Peder

    2006-01-01

    One of the major prerequisites for calculating piston ring friction is a good description of the tribological situation. Piston rings operate in three different lubrication regimes and the theoretical models should be capable to describe this. A very important condition for describing the frictio......One of the major prerequisites for calculating piston ring friction is a good description of the tribological situation. Piston rings operate in three different lubrication regimes and the theoretical models should be capable to describe this. A very important condition for describing...... the frictional behavior of a piston ring correctly is knowledge about the amount of lubricant present. For piston rings the external load may be established by measuring the pressure distribution, i.e. the pressure drop in the piston ring package. Speed and temperature may also be established. The amount...... available is reflected in the friction absorbed in the bearing. The following properties will be measured: Oil fillm thickness - along liner (axial variation), oil film thickness - along piston ring (circumferential variation), piston tilt, temperature of piston rings and liner, pressure at piston lands...

  20. Forandringslæring med autismediagnoser?

    DEFF Research Database (Denmark)

    Gustafson, Kari Ingrid; Mørck, Line Lerche

    2013-01-01

    Rasmus’ ændringer i læring, selvforståelse og tilhørsforhold perspektiveres med andre ASF-diagnostiseredes læring udforsket bl.a. gennem gruppeinterviews i regi af Asperger-foreningen. Artiklen byder således på et alternativ i form af at forstå forandringslæring som overskridende læring, med langt større...... hvor fx Asperger-foreningen, lærere og skolebørns- og unges-fællesskaber, samt forældrene er vigtige aktører i overskridelsen af marginalisering....

  1. Corneal iron ring after hyperopic photorefractive keratectomy.

    Science.gov (United States)

    Bilgihan, K; Akata, F; Gürelik, G; Adigüzel, U; Akpinar, M; Hasanreisoğlu, B

    1999-05-01

    To report the incidence and course of corneal iron deposition after hyperopic photorefractive keratectomy (PRK). Gazi University, Medical School, Department of Ophthalmology, Ankara, Turkey. Between January 1995 and December 1997, 62 eyes had PRK to correct hyperopia. Nine eyes developed corneal iron ring 5 to 8 months (mean 6.25 months +/- 1.3 [SD]) after PRK for hyperopia. The rings persisted during the mean follow-up of 19 +/- 11.09 months. The ring-shaped iron deposition after PRK for hyperopia must be differentiated from the Fleischer ring. Our results suggest that the slitlamp findings of peripheral corneal iron deposition in hyperopic PRK patients correlate with achieved correction.

  2. Multiplication modules over non-commutative rings

    International Nuclear Information System (INIS)

    Tuganbaev, A A

    2003-01-01

    It is proved that each submodule of a multiplication module over a regular ring is a multiplicative module. If A is a ring with commutative multiplication of right ideals, then each projective right ideal is a multiplicative module, and a finitely generated A-module M is a multiplicative module if and only if all its localizations with respect to maximal right ideals of A are cyclic modules over the corresponding localizations of A. In addition, several known results on multiplication modules over commutative rings are extended to modules over not necessarily commutative rings

  3. Status of the SLC damping rings

    International Nuclear Information System (INIS)

    Hutton, A.M.; Davies-White, W.A.; Delahaye, J.P.

    1985-06-01

    Electron beams of full design energy 1.21 GeV and nearly full design intensity 4 x 10 10 particles/pulse (design 5 x 10 10 ) have been extracted from the Stanford Linac and successfully stored in the electron damping ring. Beams of less intensity have been extracted from the ring and reinjected into the Linac. The present intensity limits are not thought to be fundamental. The operating experience with the electron ring and the status of the construction of the positron ring will be discussed. 11 refs., 1 fig., 2 tabs

  4. The Conversion of Wiswesser Line Notations to Ring Codes. I. The Conversion of Ring Systems

    Science.gov (United States)

    Granito, Charles E.; And Others

    1972-01-01

    The computerized conversion of Wiswesser Line Notations to Ring Codes, using a two-part approach, and the set of computer programs generated for the conversion of ring systems are described. (9 references) (Author)

  5. Mechanical support of a ceramic gas turbine vane ring

    Science.gov (United States)

    Shi, Jun; Green, Kevin E.; Mosher, Daniel A.; Holowczak, John E.; Reinhardt, Gregory E.

    2010-07-27

    An assembly for mounting a ceramic turbine vane ring onto a turbine support casing comprises a first metal clamping ring and a second metal clamping ring. The first metal clamping ring is configured to engage with a first side of a tab member of the ceramic turbine vane ring. The second metal clamping ring is configured to engage with a second side of the tab member such that the tab member is disposed between the first and second metal clamping rings.

  6. Ring opening metathesis polymerization catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Grubbs, R.H.; Johnson, L.K.; Novak, B.M.; Hillmyer, M.; Benedicto, A.; France, M.; Nguyen, S.T. [California Institute of Technology, Pasadena, CA (United States)

    1993-12-31

    Over the past eight years, a number of new catalysts for the ring opening metathesis polymerization of cyclic olefins have been developed. These catalysts are simple organometallic complexes containing metal carbon multiple bonds that in most cases polymerize olefins by a living process. These catalysts have been used to prepare a family of near monodispersed and structurally homogeneous polymers, a series of telechelic polymers with controlled molecular weight and functionality and triblock polymers with segments with potentially interesting electronic properties. A series of new group VIII catalysts are being developed that allow a wide range of functionality to be incorporated into the polymer side chains. The same catalysts can also be used in the synthesis of fine chemicals.

  7. Main ring transition crossing simulations

    International Nuclear Information System (INIS)

    Kourbanis, I.; Ng, King-Yuen.

    1990-10-01

    We used ESME to simulate transition crossing in the Main Ring (MR). For the simulations, we followed the MR 29 cycle used currently for bar p production with a flat top of 120 GeV. In Sect. II, some inputs are discussed. In Sect. III, we present simulations with space charge turned off so that the effect of nonlinearity can be studied independently. When space charge is turned on in Sect. IV, we are faced with the problem of statistical errors due to binning, an analysis of which is given in the Appendices. Finally in Sects. V and VI, the results of simulations with space charge are presented and compared with the experimental measurements. 7 refs., 6 figs

  8. Low-emittance Storage Rings

    CERN Document Server

    Wolski, Andrzej

    2014-01-01

    The effects of synchrotron radiation on particle motion in storage rings are discussed. In the absence of radiation, particle motion is symplectic, and the beam emittances are conserved. The inclusion of radiation effects in a classical approximation leads to emittance damping: expressions for the damping times are derived. Then, it is shown that quantum radiation effects lead to excitation of the beam emittances. General expressions for the equilibrium longitudinal and horizontal (natural) emittances are derived. The impact of lattice design on the natural emittance is discussed, with particular attention to the special cases of FODO-, achromat- and theoretical-minimum-emittance-style lattices. Finally, the effects of betatron coupling and vertical dispersion (generated by magnet alignment and lattice tuning errors) on the vertical emittance are considered.

  9. What confines the rings of Saturn?

    Science.gov (United States)

    Tajeddine, Radwan; Nicholson, Philip D.; El Moutamid, Maryame; Longaretti, Pierre-Yves; Burns, Joseph A.

    2017-10-01

    The viscous spreading of planetary rings is believed to be counteracted by satellite torques, either through an individual resonance or through overlapping resonances (when the satellite is close to the ring edge). For the A ring of Saturn, it has been commonly believed that the satellite Janus alone can prevent the ring from spreading via its 7:6 Lindblad resonance. We discuss this common misconception and show that, in reality, the A ring is confined by the contributions from the group of satellites Pan, Atlas, Prometheus, Pandora, Janus, Epimetheus, and Mimas, whose resonances gradually decrease the angular momentum flux transported outward through the ring via density and bending waves. We further argue that this decrease in angular momentum flux occurs through the mechanism of ‘flux reversal’.We find that the Janus 7:6 torque is relatively feeble, as is the comparable torque of the nearby small satellite Atlas, each amounting to less than one-tenth of the angular momentum transport carried by the A ring. But the cumulative torques of the many other satellite resonances in the A ring sufficiently reduce the angular momentum flux through the rings so that the torques due to Janus and Atlas are effective in confining the outer edge of the ring.Furthermore, we use the magnitude of the satellites’ resonance torques to estimate the effective viscosity profile across the A ring, showing that it decreases from ~50 cm2 s-1 at the inner edge to less than ~11 cm2 s-1 at the outer edge. The gradual estimated decrease of the angular momentum flux and effective viscosity are roughly consistent with results obtained by balancing the shepherding torques from Pan and Daphnis with the viscous torque at the edges of the Encke and Keeler gaps, as well as the edge of the A ring.On the other hand, the Mimas 2:1 Lindblad resonance alone seems to be capable of confining the edge of the B ring, and contrary to the situation in the A ring, we show that the effective viscosity

  10. VUV optical ring resonator for Duke storage ring free electron laser

    Energy Technology Data Exchange (ETDEWEB)

    Park, S.H.; Litvinenko, V.N.; Madey, J.M.J. [Duke Univ., Durham, NC (United States)] [and others

    1995-12-31

    The conceptual design of the multifaceted-mirror ring resonator for Duke storage ring VUV FEL is presented. The expected performance of the OK-4 FEL with ring resonator is described. We discuss in this paper our plans to study reflectivity of VUV mirrors and their resistivity to soft X-ray spontaneous radiation from OK-4 undulator.

  11. Electron beam cooling at a magnetic storage ring, TARN II, and an electrostatic storage ring

    International Nuclear Information System (INIS)

    Tanabe, Tetsumi

    2006-01-01

    At the High Energy Accelerator Research Organization (KEK), a magnetic storage ring, TARN II, with an electron cooler was operated from 1989 to 1999, while an electrostatic storage ring with a small electron cooler has been operational since 2000. In this paper, the electron cooling at TARN II and the electrostatic storage ring is described. (author)

  12. Two cases of halo scalp ring.

    Science.gov (United States)

    Douri, Thaer Hasan

    2016-11-15

    Halo scalp ring (HSR) is a rare form of non-scarring annular alopecia that is attributed to caput succedaneum. It arises perinatally because of prolonged pressure on the scalp by the cervix during or before the delivery. We report two new cases of halo scalp ring in full term pregnancy - newborns.

  13. Two cases of halo scalp ring

    OpenAIRE

    Douri, Thaer Hasan

    2016-01-01

    Halo scalp ring (HSR) is a rare form of non-scarring annular alopecia that is attributed to caput succedaneum. It arises perinatally because of prolonged pressure on the scalp by the cervix during or before the delivery. We report two new cases of halo scalp ring in full term pregnancy - newborns.

  14. Local duality for 2-dimensional local ring

    Indian Academy of Sciences (India)

    We prove a local duality for some schemes associated to a 2-dimensional complete local ring whose residue field is an -dimensional local field in the sense of Kato–Parshin. Our results generalize the Saito works in the case =0 and are applied to study the Bloch–Ogus complex for such rings in various cases.

  15. Hawking radiation of black rings from anomalies

    International Nuclear Information System (INIS)

    Chen Bin; He Wei

    2008-01-01

    We derive Hawking radiation of five-dimensional black rings from gauge and gravitational anomalies using the method proposed by Robinson and Wilczek. We find, as in the black hole case, that the problem could reduce to a (1+1)-dimensional field theory and the anomalies result in correct Hawking temperature for neutral, dipole and charged black rings

  16. Local duality for 2-dimensional local ring

    Indian Academy of Sciences (India)

    dimensional complete local ring whose residue field is an n-dimensional local field in the sense of. Kato–Parshin. Our results generalize the Saito works in the case n = 0 and are applied to study the Bloch–Ogus complex for such rings in various cases.

  17. Counteracting ring formation in rotary kilns

    NARCIS (Netherlands)

    Pisaroni, M.; Sadi, R.; Lahaye, D.

    Avoiding the formation of rings in rotary kilns is an issue of primary concern to the cement production industry. We developed a numerical combustion model that revealed that in our case study rings are typically formed in zones of maximal radiative heat transfer. This local overheating causes the

  18. The King's Ring: A Matter of Trust

    DEFF Research Database (Denmark)

    Sterrett, Joseph William

    2018-01-01

    This essay examines the material and social effects of an exchange of trust between a king, Henry VIII, and his counsellor, Thomas Cranmer in Shakespeare and Fletcher’s All is True. The ring that the King gives Cranmer is both nothing and everything: nothing in that it could be anything, any ring...

  19. Familial transmission of a ring chromosome 21

    DEFF Research Database (Denmark)

    Hertz, Jens Michael

    1987-01-01

    A ring chromosome 21 was found in a phenotypically normal mother and her son. The clinical findings in the son were bilateral retention of the testes and a slightly delayed puberty onset. Consequences of a ring formation of a chromosome 21 in phenotypically normal patients are presented...

  20. Coefficient rings of formal group laws

    International Nuclear Information System (INIS)

    Buchstaber, V M; Ustinov, A V

    2015-01-01

    We describe the coefficient rings of universal formal group laws which arise in algebraic geometry, algebraic topology and their application to mathematical physics. We also describe the homomorphisms of these coefficient rings coming from reductions of one formal group law to another. The proofs are based on the number-theoretic properties of binomial coefficients. Bibliography: 37 titles

  1. Ring chromosome 13 and ambiguous genitalia.

    Science.gov (United States)

    Ozsu, Elif; Yeşiltepe Mutlu, Gül; Ipekçi, Belkıs

    2014-01-01

    Ambiguous genitalia, known to be associated with sex chromosome disorders, may also be seen with autosomal chromosome anomalies. Herein, we report a case with ambiguous genitalia and ring chromosome 13. Ring chromosome 13 is a rare genetic anomaly in which the loss of genetic material determines the clinical spectrum.

  2. Ring Chromosome 13 and Ambiguous Genitalia

    OpenAIRE

    Özsu, Elif; Yeşiltepe Mutlu, Gül; İpekçi, Belkıs

    2014-01-01

    Ambiguous genitalia, known to be associated with sex chromosome disorders, may also be seen with autosomal chromosome anomalies. Herein, we report a case with ambiguous genitalia and ring chromosome 13. Ring chromosome 13 is a rare genetic anomaly in which the loss of genetic material determines the clinical spectrum.

  3. On P-coherent endomorphism rings

    Indian Academy of Sciences (India)

    A ring is called right -coherent if every principal right ideal is finitely presented. Let M R be a right -module. We study the -coherence of the endomorphism ring of M R . It is shown ... Author Affiliations. Li-Xin Mao1. Institute of Mathematics, Nanjing Institute of Technology, Nanjing 211167, People's Republic of China ...

  4. The Fine Structure of Herman Rings

    DEFF Research Database (Denmark)

    Fagella, Nuria; Henriksen, Christian

    2017-01-01

    We study the geometric structure of the boundary of Herman rings in a model family of Blaschke products of degree 3 (up to quasiconformal deformation). Shishikura’s quasiconformal surgery relates the Herman ring to the Siegel disk of a quadratic polynomial. By studying the regularity properties...

  5. On the nonlinear modeling of ring oscillators

    KAUST Repository

    Elwakil, Ahmed S.

    2009-06-01

    We develop higher-order nonlinear models of three-stage and five-stage ring oscillators based on a novel inverter model. The oscillation condition and oscillation frequency are derived and compared to classical linear model analysis. Two important special cases for five-stage ring oscillators are also studied. Numerical simulations are shown. © 2009 World Scientific Publishing Company.

  6. Piecewise catenarian and going between rings.

    OpenAIRE

    Brodmann, M.

    1980-01-01

    The main purpose of this paper is to prove the following theorem. Let R be a noetherian ring and n a nonnegative integer. Then R[X1, ••• ,Xn] is a going-between ring (=GB) iff R is GB and is (n+l)-piecewise catenarian.

  7. The decay of confined vortex rings

    Science.gov (United States)

    Stewart, K. C.; Niebel, C. L.; Jung, S.; Vlachos, P. P.

    2012-07-01

    Vortex rings are produced during the ejection of fluid through a nozzle or orifice, which occurs in a wide range of biological conditions such as blood flow through the valves of the heart or through arterial constrictions. Confined vortex ring dynamics, such as these, have not been previously studied despite their occurrence within the biological flow conditions mentioned. In this work, we investigate laminar vortex rings using particle image velocimetry and develop a new semi-empirical model for the evolution of vortex ring circulation subject to confinement. Here we introduce a decay parameter β which exponentially grows with increasing vortex ring confinement ratio, the ratio of the vortex ring diameter ( D VR) to the confinement diameter ( D), with the relationship β=4.38 exp(9.5D_VR/D), resulting in a corresponding increase in the rate of vortex ring circulation decay. This work enables the prediction of circulation decay rate based on confinement, which is important to understanding naturally occurring confined vortex ring dynamics.

  8. Cooling rings for TeV colliders

    International Nuclear Information System (INIS)

    Palmer, R.B.

    1985-02-01

    Consideration is given to quantum fluctuations, intra beam scattering, cooling rates, and ring acceptance in order to see if one can obtain a normalized emittance of 10 -8 in any plausible cooling ring. It is concluded that only a small gain is obtained by varying the partition functions, but a very significant gain is made by using higher bending fields. The ring is found to get bigger if the magnet apertures are increased. The ring diameter is found to increase if the momentum spread of the beam is reduced. It is shown that the power can be reduced by allowing a high beamstrahlung energy loss resulting in higher current in the cooling ring. Parameters are also given for a 10 -7 m radian emittance case

  9. Monlithic nonplanar ring oscillator and method

    Science.gov (United States)

    Nilsson, Alan C. (Inventor); Byer, Robert L. (Inventor)

    1991-01-01

    A monolithic nonplanar ring oscillator having an optically isotropic solid-state laser body for propagating laser radiation about a nonplanar ring path internal to the laser body is disclosed. The monolithic laser body is configured to produce a 2N reflection nonplanar ring light path, where N is an integer greater than or equal to 2, comprising 2N-1 total internal reflections and one reflection at a coupler in a single round trip. Undirectional traveling wave oscillation of the laser is induced by the geometry of the nonplanar ring path together with the effect of an applied magnetic field and partial polarizer characteristics of the oblique reflection from the coupler. The 6-reflection nonplanar ring oscillator makes possible otpimal unidirectional oscillation (low loss for the oscillating direction of propagation and, simultaneously high loss for the nonoscillating direction of propagation) in monolithic NPROs using materials with index of refraction smaller than the square root of 3, for example, laser glass.

  10. Observation of "fairy rings" in the lowlands

    Directory of Open Access Journals (Sweden)

    Barbara Sadowska

    2014-11-01

    Full Text Available Investigations on the formation of fairy rings by Agaricales were performed in the year·s 1971-1974 in forest meadows and reserves in Dziekanów Leśny and on agricultural mowed ones in Kazuń near Warsaw. During 240 observations 378 maps were made. In forest meadows 15 species formed rings and on agricultural mowed meadows 22 species. Many species formed rings considerably affecting the growth of vascular plants. This caused the formation of distinct zone.s parallel to the lines of fructifications. Many more species formed rings without affecting the growth and species composition of vascular plants. The appearance of fairy rings and the analysis of the reasons for their occurrence may facilitate in a certain sense the investigation of the speed and way of growth of mycelium in the soil.

  11. Vaginal rings for delivery of HIV microbicides

    Directory of Open Access Journals (Sweden)

    McCoy CF

    2012-11-01

    Full Text Available R Karl Malcolm, Susan M Fetherston, Clare F McCoy, Peter Boyd, Ian MajorSchool of Pharmacy, Queen's University Belfast, Belfast, UKAbstract: Following the successful development of long-acting steroid-releasing vaginal ring devices for the treatment of menopausal symptoms and contraception, there is now considerable interest in applying similar devices to the controlled release of microbicides against HIV. In this review article, the vaginal ring concept is first considered within the wider context of the early advances in controlled-release technology, before describing the various types of ring device available today. The remainder of the article highlights the key developments in HIV microbicide-releasing vaginal rings, with a particular focus on the dapivirine ring that is presently in late-stage clinical testing.Keywords: controlled release, sustained release, antiretroviral, dapivirine, SILCS diaphragm, silicone elastomer, thermoplastic

  12. An evolving view of Saturn's dynamic rings.

    Science.gov (United States)

    Cuzzi, J N; Burns, J A; Charnoz, S; Clark, R N; Colwell, J E; Dones, L; Esposito, L W; Filacchione, G; French, R G; Hedman, M M; Kempf, S; Marouf, E A; Murray, C D; Nicholson, P D; Porco, C C; Schmidt, J; Showalter, M R; Spilker, L J; Spitale, J N; Srama, R; Sremcević, M; Tiscareno, M S; Weiss, J

    2010-03-19

    We review our understanding of Saturn's rings after nearly 6 years of observations by the Cassini spacecraft. Saturn's rings are composed mostly of water ice but also contain an undetermined reddish contaminant. The rings exhibit a range of structure across many spatial scales; some of this involves the interplay of the fluid nature and the self-gravity of innumerable orbiting centimeter- to meter-sized particles, and the effects of several peripheral and embedded moonlets, but much remains unexplained. A few aspects of ring structure change on time scales as short as days. It remains unclear whether the vigorous evolutionary processes to which the rings are subject imply a much younger age than that of the solar system. Processes on view at Saturn have parallels in circumstellar disks.

  13. Semi-algebraic function rings and reflectors of partially ordered rings

    CERN Document Server

    Schwartz, Niels

    1999-01-01

    The book lays algebraic foundations for real geometry through a systematic investigation of partially ordered rings of semi-algebraic functions. Real spectra serve as primary geometric objects, the maps between them are determined by rings of functions associated with the spectra. The many different possible choices for these rings of functions are studied via reflections of partially ordered rings. Readers should feel comfortable using basic algebraic and categorical concepts. As motivational background some familiarity with real geometry will be helpful. The book aims at researchers and graduate students with an interest in real algebra and geometry, ordered algebraic structures, topology and rings of continuous functions.

  14. Electro-optical hybrid slip ring

    Science.gov (United States)

    Hong, En

    2005-11-01

    The slip ring is a rotary electrical interface, collector, swivel or rotary joint. It is a physical system that can perform continuous data transfer and data exchange between a stationary and a rotating structure. A slip ring is generally used to transfer data or power from an unrestrained, continuously rotating electro-mechanical system in real-time, thereby simplifying operations and eliminating damage-prone wires dangling from moving joints. Slip rings are widely used for testing, evaluating, developing and improving various technical equipment and facilities with rotating parts. They are widely used in industry, especially in manufacturing industries employing turbo machinery, as in aviation, shipbuilding, aerospace, defense, and in precise facilities having rotating parts such as medical Computerized Tomography (CT) and MRI scanners and so forth. Therefore, any improvement in slip ring technology can impact large markets. Research and development in this field will have broad prospects long into the future. The goal in developing the current slip ring technology is to improve and increase the reliability, stability, anti-interference, and high data fidelity between rotating and stationary structures. Up to now, there have been numerous approaches used for signal and data transfer utilizing a slip ring such as metal contacts, wires, radio transmission, and even liquid media. However, all suffer from drawbacks such as data transfer speed limitations, reliability, stability, electro-magnetic interference and durability. The purpose of the current research is to break through these basic limitations using an optical solution, thereby improving performance in current slip ring applications. This dissertation introduces a novel Electro-Optical Hybrid Slip Ring technology, which makes "through the air" digital-optical communication between stationary and rotating systems a reality with high data transfer speed, better reliability and low interference susceptibility

  15. Galactic rings revisited - I. CVRHS classifications of 3962 ringed galaxies from the Galaxy Zoo 2 Database

    Science.gov (United States)

    Buta, Ronald J.

    2017-11-01

    Rings are important and characteristic features of disc-shaped galaxies. This paper is the first in a series that re-visits galactic rings with the goals of further understanding the nature of the features and for examining their role in the secular evolution of galaxy structure. The series begins with a new sample of 3962 galaxies drawn from the Galaxy Zoo 2 citizen science data base, selected because zoo volunteers recognized a ring-shaped pattern in the morphology as seen in Sloan Digital Sky Survey colour images. The galaxies are classified within the framework of the Comprehensive de Vaucouleurs revised Hubble-Sandage system. It is found that zoo volunteers cued on the same kinds of ring-like features that were recognized in the 1995 Catalogue of Southern Ringed Galaxies. This paper presents the full catalogue of morphological classifications, comparisons with other sources of classifications and some histograms designed mainly to highlight the content of the catalogue. The advantages of the sample are its large size and the generally good quality of the images; the main disadvantage is the low physical resolution that limits the detectability of linearly small rings such as nuclear rings. The catalogue includes mainly inner and outer disc rings and lenses. Cataclysmic (`encounter-driven') rings (such as ring and polar ring galaxies) are recognized in less than 1 per cent of the sample.

  16. Wear Analysis of Top Piston Ring to Reduce Top Ring Reversal Bore Wear

    Directory of Open Access Journals (Sweden)

    P. Ilanthirayan

    2017-12-01

    Full Text Available The piston rings are the most important part in engine which controls the lubricating oil consumption and blowby of the gases. The lubricating film of oil is provided to seal of gases towards crankcase and also to give smooth friction free translatory motion between rings and liner. Of the three rings present top ring is more crucial as it does the main work of restricting gases downwards the crankcase. Boundary lubrication is present at the Top dead centre (TDC and Bottom dead centre (BDC of the liner surface. In addition to this, top ring is exposed to high temperature gases which makes the oil present near the top ring to get evaporated and decreasing its viscosity, making metal-metal contact most of the time. Due to this at TDC, excess wear happens on the liner which is termed as Top ring reversal bore wear. The wear rate depends upon many parameters such as lubrication condition, viscosity index, contact type, normal forces acting on ring, geometry of ring face, surface roughness, material property. The present work explores the wear depth for different geometries of barrel ring using Finite Element model with the help of Archard wear law and the same is validated through experimentation. The study reveals that Asymmetric barrel rings have less contact pressure which in turn reduces the wear at Top dead centre.

  17. Highly Simplified Reddish Orange Phosphorescent Organic Light-Emitting Diodes Incorporating a Novel Carrier- and Exciton-Confining Spiro-Exciplex-Forming Host for Reduced Efficiency Roll-off.

    Science.gov (United States)

    Xu, Ting; Zhang, Ye-Xin; Wang, Bo; Huang, Chen-Chao; Murtaza, Imran; Meng, Hong; Liao, Liang-Sheng

    2017-01-25

    A novel exciplex-forming host is applied so as to design highly simplified reddish orange light-emitting diodes (OLEDs) with low driving voltage, high efficiency, and an extraordinarily low efficiency roll-off, by combining N,N-10-triphenyl-10H-spiro [acridine-9,9'-fluoren]-3'-amine (SAFDPA) with 4,7-diphenyl-1,10-phenanthroline (Bphen) doped with trivalent iridium complex bis(2-methyldibenzo[f,h]quinoxaline) (acetylacetonate)iridium(III) (Ir(MDQ) 2 (acac)). The reddish orange OLEDs achieve a strikingly high power efficiency (PE) of 31.80 lm/W with an ultralow threshold voltage of 2.24 V which is almost equal to the triplet energy level of the phosphorescent reddish orange emitting dopant. The power efficiency of the device with the exciplex-forming host is enhanced, achieving 36.2% mainly owing to the lower operating voltage by the novel exciplex forming cohost, compared with the reference device (23.54 lm/W). Moreover, the OLEDs show extraordinarily low current efficiency (CE) roll-off to 1.41% at the brightness from 500 to 5000 cd/m 2 with a maximal CE of 32.87 cd/A (EQE max = 11.01%). The devices display a good reddish orange color (CIE of (0.628, 0.372) at 500 cd/m 2 ) nearly without color shift with increasing brightness. Co-host architecture phosphorescent OLEDs show a simpler device structure, lower working voltage, and a better efficiency and stability than those of the reference devices without the cohost architecture, which helps to simplify the OLED structure, lower the cost, and popularize OLED technology.

  18. Synthesis and antiviral activity of cyclopropyl-spirocarbocyclic adenosine, (4R,5S,6R,7R)-4-(6-amino-9H-purin-9-yl)-7-(hydroxymethyl)spiro[2.4]heptane-5,6-diol against hepatitis C virus.

    Science.gov (United States)

    Gadthula, Srinivas; Rawal, Ravindra K; Sharon, Ashoke; Wu, Dong; Korba, Brent; Chu, Chung K

    2011-07-01

    An efficient method was developed for the synthesis of 6-exocyclic methylene carbocyclic intermediate 4. The Simmons-Smith cyclopropanation protocol was applied on the 6-exocyclic methylene of intermediate 4 and demonstrated its utility for the synthesis of novel class of a spiro-carbocyclic nucleoside analog 8. The titled compound 8 demonstrated a significant antiviral activity against HCV with EC(50) values of 0.273 and 0.368 μM in genotypes 1A and 1B, respectively. Copyright © 2011 Elsevier Ltd. All rights reserved.

  19. Hyperautofluorescent ring in eyes with macular holes

    Directory of Open Access Journals (Sweden)

    Sato T

    2013-08-01

    Full Text Available Tatsuhiko Sato, Kazuyuki Emi, Yui Osawa, Hajime Bando Osaka Rosai Hospital Clinical Research Center for Occupational Sensory Organ Disability, Sakai, Japan Background: Fundus autofluorescence studies in eyes with macular holes (MHs have shown a hyperautofluorescent spot corresponding to the hole and a hypoautofluorescent ring corresponding to the fluid cuff surrounding the hole. The purpose of this report is to present three cases of MH with a different fundus autofluorescence pattern. Case reports: Case 1 was a 62-year-old woman who did not know the duration of the MH in her left eye. Her decimal best-corrected visual acuity (BCVA was 0.08. The left eye had a one-half disc diameter MH with a depigmented ring surrounding the area of the fluid cuff. Fundus autofluorescence showed a hyperautofluorescent ring corresponding to the depigmented ring. After vitrectomy, fundus autofluorescence showed the same size hyperautofluorescent ring despite the decreased size of the opened MH. Case 2 was a 69-year-old woman who had been diagnosed with MH in the right eye 13 years earlier. Her decimal BCVA was 0.1. The right eye had a one-half disc diameter MH with a depigmented ring surrounding the area of the fluid cuff. Fundus autofluorescence showed a hyperautofluorescent ring corresponding to the depigmented ring. Postoperative fundus autofluorescence showed the same size hyperautofluorescent ring despite the hole being closed. The decimal BCVA was 0.2 in her right eye 6 months after vitrectomy. Case 3 was a 71-year-old woman who had been diagnosed with MH in the right eye 15 years earlier. Her decimal BCVA was 0.1. The right eye had a one-half disc diameter MH with a depigmented ring which corresponded with a hyperautofluorescent ring. Postoperative fundus autofluorescence showed the same size hyperautofluorescent ring despite the hole being closed. The decimal BCVA was 0.2 in her right eye 6 months after vitrectomy. Conclusion: Our findings suggest that a

  20. Wedding ring shaped excitation coil

    Science.gov (United States)

    MacLennan, Donald A.; Tsai, Peter

    2001-01-01

    A high frequency inductively coupled electrodeless lamp includes an excitation coil with an effective electrical length which is less than one half wavelength of a driving frequency applied thereto, preferably much less. The driving frequency may be greater than 100 MHz and is preferably as high as 915 MHz. Preferably, the excitation coil is configured as a non-helical, semi-cylindrical conductive surface having less than one turn, in the general shape of a wedding ring. At high frequencies, the current in the coil forms two loops which are spaced apart and parallel to each other. Configured appropriately, the coil approximates a Helmholtz configuration. The lamp preferably utilizes an bulb encased in a reflective ceramic cup with a pre-formed aperture defined therethrough. The ceramic cup may include structural features to aid in alignment and/or a flanged face to aid in thermal management. The lamp head is preferably an integrated lamp head comprising a metal matrix composite surrounding an insulating ceramic with the excitation integrally formed on the ceramic. A novel solid-state oscillator preferably provides RF power to the lamp. The oscillator is a single active element device capable of providing over 70 watts of power at over 70% efficiency.

  1. Common pass decentered annular ring resonator

    Energy Technology Data Exchange (ETDEWEB)

    Holmes, D. A.; Waite, T. R.

    1985-04-30

    An optical resonator having an annular cylindrical gain region for use in a chemical laser or the like in which two ring-shaped mirrors having substantially conical reflecting surfaces are spaced apart along a common axis of revolution of the respective conical surfaces. A central conical mirror reflects incident light directed along said axis radially outwardly to the reflecting surface of a first one of the ring-shaped mirrors. The radial light rays are reflected by the first ring mirror to the second ring mirror within an annular cylindrical volume concentric with said common axis and forming a gain region. Light rays impinging on the second ring mirror are reflected to diametrically opposite points on the same conical mirror surfaces and back to the first ring mirror through the same annular cylindrical volume. The return rays are then reflected by the conical mirror surface of the first ring mirror back to the central conical mirror. The mirror surfaces are angled such that the return rays are reflected back along the common axis by the central mirror in a concentric annular cylindrical volume. A scraper mirror having a central opening centered on said axis and an offset opening reflects all but the rays passing through the two openings in an output beam. The rays passing through the second opening are reflected back through the first opening to provide feedback.

  2. Nilradicals of skew Hurwitz series of rings

    Directory of Open Access Journals (Sweden)

    Morteza Ahmadi

    2015-05-01

    Full Text Available ‎For a ring endomorphism α of a ring R, ‎Krempa called α a rigid endomorphism if aα(a=0 implies a = 0 for a in R. ‎A ring R is called rigid if there exists a rigid endomorphism of R. ‎In this paper‎, ‎we extend the α-rigid property of a ring R to the upper nilradical N_r(R of R. ‎For an endomorphism α and the upper nilradical N_r(R of a ring R, ‎we introduce the condition (*: ‎N_r(R is a α-ideal of R and aα(a in N_r(R implies a in N_r(R for a in R. ‎We study characterizations of a ring R with an endomorphism α satisfying the condition (*, ‎and we investigate their related properties‎. ‎The connections between the upper nilradical of R and the upper nilradical of the skew Hurwitz series ring (HR,α of R are also investigated‎.

  3. Ring enhancement in contrast enhancement computed tomography

    International Nuclear Information System (INIS)

    Inatsuki, Shinichi; Hayashi, Kuniaki; Miyake, Hidetoshi

    1979-01-01

    Ring enhancement was examined in 11 lesions, 61 patients, we experienced. The frequency of ring enhancement observed in cerebral abscesses and tumors and the characteristics and the differential points of each disease were obtained. The frequency of ring enhancement was 54% in metastatic cerebral tumor, 56% in glioblastoma and astrocytoma (grade III) and 100% in cerebral abscess. Glioblastoma and astrocytoma (grade III) differed from other diseases in having distorted rings with poor uniform thickness. Although there was a great similarity between the computed tomographic picture of metastatic cerebral tumor and that of cerebral abscess, the ring in cerebral abscess was clearer, thin and uniform, and the peripheral edema in cerebral abscess was weak in general. In cerebral infarct, peripheral edema and mass effect of the ring were not observed or slightly observed, if any. Considering only the characteristics of the rings, there are differences between each diseases, and differentiation seems to be possibly performed. In practice, however, it is not necessarily easy to make a differential diagnosis. Clinical results should be carefully managed. (Kumagai, M.)

  4. Dynamics of the Uranian Gamma Ring

    Science.gov (United States)

    Hamilton, Douglas P.; Rimlinger, Thomas; Hahn, Joseph M.

    2017-10-01

    The planet Uranus is surrounded by a unique ring system consisting of ten narrow ringlets as well as several broad sheets of dust. The brightest of these rings is bracketed by a pair of satellites, Cordelia and Ophelia, that may serve to help confine the ring radially. Searches for smaller satellites near the other narrow rings, however, have been unsuccessful. Hamilton et. al. 2016 and Rimlinger et al. 2016 have argued that the eccentric and/or inclined uranian ringlets self confine radially by a combination of ringlet gravity and viscous forces. Importantly, no shepherd satellites are required in this model.We apply these ideas to the uranian gamma ring, a particularly strange ringlet which has, in addition to the standard elliptical shape, a superposed m=0 breathing mode (French et. al. 1988). In a pure m=0 mode, the particles in an elliptical ring all reach pericenter at the same times giving the ring a circular appearance. The particles remain synced in phase and all move outward reaching apocenter simultaneously. Thus the ring appears circular at any given time, but the radius of the circle seems to increase and decrease - it breathes. We investigate first the dynamics of the pure m=0 mode and show that the equilibrium is stable against small perturbations. We are currently moving toward a more sophisticated stability analysis for the real gamma ring with its unusual combination of normal modes. We will detail our results to date and will report on our progress toward an origin scenario for this obscure but interesting ringlet.

  5. Migration of Star Clusters and Nuclear Rings

    OpenAIRE

    van de Ven, Glenn; Chang, Philip

    2008-01-01

    Star clusters that form in nuclear rings appear to be at slightly larger radii than the gas. We argue that the star clusters move out from the gas in which they are formed because of satellite-disk tidal interactions. In calculating the dynamics of this star cluster and gas ring system, we include the effects of dynamical friction of the background stars in the host galaxy on the star cluster, and inflowing gas along the bar onto the nuclear ring at the two contact points. We show that the fi...

  6. Beam dynamics in Compton ring gamma sources

    Directory of Open Access Journals (Sweden)

    Eugene Bulyak

    2006-09-01

    Full Text Available Electron storage rings of GeV energy with laser pulse stacking cavities are promising intense sources of polarized hard photons which, via pair production, can be used to generate polarized positron beams. In this paper, the dynamics of electron bunches circulating in a storage ring and interacting with high-power laser pulses is studied both analytically and by simulation. Both the common features and the differences in the behavior of bunches interacting with an extremely high power laser pulse and with a moderate pulse are discussed. Also considerations on particular lattice designs for Compton gamma rings are presented.

  7. Wind turbine ring/shroud drive system

    Science.gov (United States)

    Blakemore, Ralph W.

    2005-10-04

    A wind turbine capable of driving multiple electric generators having a ring or shroud structure for reducing blade root bending moments, hub loads, blade fastener loads and pitch bearing loads. The shroud may further incorporate a ring gear for driving an electric generator. In one embodiment, the electric generator may be cantilevered from the nacelle such that the gear on the generator drive shaft is contacted by the ring gear of the shroud. The shroud also provides protection for the gearing and aids in preventing gear lubricant contamination.

  8. Injection envelope matching in storage rings

    International Nuclear Information System (INIS)

    Minty, M.G.; Spence, W.L.

    1995-05-01

    The shape and size of the transverse phase space injected into a storage ring can be deduced from turn-by-turn measurements of the transient behavior of the beam envelope in the ring. Envelope oscillations at 2 x the β-tron frequency indicate the presence of a β-mismatch, while envelope oscillations at the β-tron frequency are the signature of a dispersion function mismatch. Experiments in injection optimization using synchrotron radiation imaging of the beam and a fast-gated camera at the SLC damping rings are reported

  9. Nitrile O-ring Cracking: A Case of Vacuum Flange O-ring Failures

    Energy Technology Data Exchange (ETDEWEB)

    Dees, Craig

    2016-07-01

    A review of recent nitrile O-ring failures in ISO-KF vacuum flange connections in glovebox applications is presented. An investigation of a single “isolated” o-ring failure leads to the discovery of cracked nitrile o-rings in a glovebox atmospheric control unit. The initial cause of the o-ring failure is attributed to ozone degradation. However, additional investigation reveals nitrile o-ring cracking on multiple gloveboxes and general purpose piping, roughly 85% of the nitrile o-rings removed for inspection show evidence of visible cracking after being in service for 18 months or less. The results of material testing and ambient air testing is presented, elevated ozone levels are not found. The contributing factors of o-ring failure, including nitrile air sensitivity, inadequate storage practices, and poor installation techniques, are discussed. A discussion of nitrile o-ring material properties, the benefits and limitations, and alternate materials are discussed. Considerations for o-ring material selection, purchasing, storage, and installation are presented in the context of lessons learned from the nitrile o-ring cracking investigation. This paper can be presented in 20 minutes and does not require special accommodations or special audio visual devices.

  10. Dark matter axions and caustic rings

    International Nuclear Information System (INIS)

    Sikivie, P.

    1997-01-01

    This report contains discussions on the following topics: the strong CP problem; dark matter axions; the cavity detector of galactic halo axions; and caustic rings in the density distribution of cold dark matter halos

  11. Proton storage ring: man/machine interface

    International Nuclear Information System (INIS)

    Lander, R.F.; Clout, P.N.

    1985-01-01

    The human interface of the Proton Storage Ring Control System at Los Alamos is described in some detail, together with the software environment in which operator interaction programs are written. Some examples of operator interaction programs are given

  12. Sapphire Ring Resonator For Microwave Oscillator

    Science.gov (United States)

    Dick, G. John; Saunders, Jon

    1991-01-01

    Sapphire dielectric ring resonator operating in "whispering-gallery" mode helps to stabilize frequency and phase of microwave oscillator. Reduces phase noise appreciably at room temperature and promises unprecedented stability of phase at cryogenic temperatures.

  13. Polarized gas targets for storage rings

    International Nuclear Information System (INIS)

    Holt, R.J.

    1990-01-01

    It is widely recognized that polarized gas targets in electron storage rings represent a new opportunity for precision nuclear physics studies. New developments in polarized target technology specific to internal applications will be discussed. In particular, polarized gas targets have been used in the VEPP-3 electron ring in Novosibirsk. A simple storage cell was used to increase the total target thickness by a factor of 15 over the simple gas jet target from an atomic beam source. Results from the initial phase of this project will be reported. In addition, the plans for increasing the luminosity by an additional order or magnitude will be presented. The application of this work to polarized hydrogen and deuterium targets for the HERA ring will be noted. The influence of beam-induced depolarization, a phenomena encountered in short-pulse electron storage rings, will be discussed. Finally, the performance tests of laser-driven sources will be presented. 8 refs., 12 figs., 1 tab

  14. A non-Abelian black ring

    Directory of Open Access Journals (Sweden)

    Tomás Ortín

    2016-09-01

    Full Text Available We construct a supersymmetric black ring solution of SU(2 N=1, d=5 Super-Einstein–Yang–Mills (SEYM theory by adding a distorted BPST instanton to an Abelian black ring solution of the same theory. The change cannot be observed from spatial infinity: neither the mass, nor the angular momenta or the values of the scalars at infinity differ from those of the Abelian ring. The entropy is, however, sensitive to the presence of the non-Abelian instanton, and it is smaller than that of the Abelian ring, in analogy to what happens in the supersymmetric colored black holes recently constructed in the same theory and in N=2, d=4 SEYM. By taking the limit in which the two angular momenta become equal we derive a non-Abelian generalization of the BMPV rotating black-hole solution.

  15. National synchrotron light source VUV storage ring

    International Nuclear Information System (INIS)

    Blumberg, L.; Bittner, J.; Galayda, J.; Heese, R.; Krinsky, S.; Schuchman, J.; van Steenbergen, A.

    1979-01-01

    A 700 MeV electron storage ring designed for synchrotron radiation applications is described. Lattice and stability calculations are presented and the vacuum, correction and injection systems are discussed

  16. Collins' bypass for the main ring

    International Nuclear Information System (INIS)

    Ohnuma, S.

    1982-01-01

    Design of the bypass for the main ring at Fermilab is discussed. Specific design features discussed include space, path length, geometric closure, matching of betatron functions, and external dispersion. Bypass parameters are given

  17. On Learning Ring-Sum-Expansions

    DEFF Research Database (Denmark)

    Fischer, Paul; Simon, H. -U.

    1992-01-01

    The problem of learning ring-sum-expansions from examples is studied. Ring-sum-expansions (RSE) are representations of Boolean functions over the base {#123;small infinum, (+), 1}#125;, which reflect arithmetic operations in GF(2). k-RSE is the class of ring-sum-expansions containing only monomials...... of length at most k:. term-RSE is the class of ring-sum-expansions having at most I: monomials. It is shown that k-RSE, k>or=1, is learnable while k-term-RSE, k>2, is not learnable if RPnot=NP. Without using a complexity-theoretical hypothesis, it is proven that k-RSE, k>or=1, and k-term-RSE, k>or=2 cannot...

  18. Ethinyl Estradiol and Etonogestrel Vaginal Ring

    Science.gov (United States)

    ... or stand with one leg up on a chair, step, or other object. Choose the position that ... contraceptive ring.if you are having surgery, including dental surgery, tell the doctor or dentist that you ...

  19. A dynamic, rotating ring current around Saturn.

    Science.gov (United States)

    Krimigis, S M; Sergis, N; Mitchell, D G; Hamilton, D C; Krupp, N

    2007-12-13

    The concept of an electrical current encircling the Earth at high altitudes was first proposed in 1917 to explain the depression of the horizontal component of the Earth's magnetic field during geomagnetic storms. In situ measurements of the extent and composition of this current were made some 50 years later and an image was obtained in 2001 (ref. 6). Ring currents of a different nature were observed at Jupiter and their presence inferred at Saturn. Here we report images of the ring current at Saturn, together with a day-night pressure asymmetry and tilt of the planet's plasma sheet, based on measurements using the magnetospheric imaging instrument (MIMI) on board Cassini. The ring current can be highly variable with strong longitudinal asymmetries that corotate nearly rigidly with the planet. This contrasts with the Earth's ring current, where there is no rotational modulation and initial asymmetries are organized by local time effects.

  20. From coffee ring to spherulites ring of poly(ethylene oxide) film from drying droplet

    Science.gov (United States)

    Hu, Yinchun; Zhang, Xuerong; Qiu, Maibo; Wei, Yan; Zhou, Qiong; Huang, Di

    2018-03-01

    We discuss how the "spherulites ring" morphology and "coffee ring" profile of PEO film formed by the drying droplet at glass substrate with different heating rate. Upon increasing the heating rate of substrate, it is found that deposited PEO film from drying droplet shows the unusually observed "coffee ring" profile and "spherulites ring" morphology. The main mechanism for this phenomenon is proposed to be an enhanced Marangoni convection which is induced by the increased solute concentration gradient and reduced viscous force above 70 °C. A simple formation mechanism of the unusually observed "coffee ring" profile and "spherulites ring" morphology is proposed. These findings can be exploited to trace the center of Marangoni convection, with potential applications in designing the spherulite patterns of crystalline polymer films in ink-jet printing and self-assembly fields.

  1. Vaginal rings for menopausal symptom relief.

    Science.gov (United States)

    Ballagh, Susan A

    2004-01-01

    The vagina is an alternative delivery site of sex steroids for menopausal women. New ring technology provides continuous and consistent delivery of steroids for up to 3 months. Rings rest on the pelvic floor muscles in a nearly horizontal position and are usually imperceptible. Steroid is delivered directly into the systemic circulation which may result in less alteration of coagulation/fibrinolysis pathways as seen with transdermal hormone therapy. Fewer adverse effects are noted when progesterone is applied vaginally, possibly due to lower serum levels of metabolites such as alloprenanolone. Women often switch to a ring for the longer dosing interval but also appreciate the reduced messiness. Over 5700 healthy US women who evaluated an unmedicated ring as a drug delivery platform found it very acceptable independent of age or prior use of barrier contraceptives. Marketed rings in the US include: (i) a ring for systemic and vaginal menopausal therapy that provides average serum estradiol levels of 40.6 pg/mL for the 0.05 mg and 76 pg/mL for the 0.1 mg dose; (ii) a ring for urogenital menopausal symptoms only that minimally elevates serum estradiol, usually within the menopausal range, treating atrophic vaginitis and urethritis; and (iii) a ring labelled for contraception that provides ethinyl estradiol 15 microg and etonogestrel 120 microg appropriate for nonsmoking perimenopausal women. A ring for combination hormone therapy and another releasing progesterone for contraception in lactating women have been reported in the literature, but are not yet available commercially. These may offer future options for hormone therapy. Women with a uterus receiving estrogen, even in low doses, should be given progestogen to prevent endometrial hyperplasia or carcinoma. Even women who have had an endometrial ablation are likely to have some endometrial tissue remaining since long-term amenorrhoea is uncommon. Since no marketed combination ring product is available, other forms

  2. Nonexistence of extremal de Sitter black rings

    Science.gov (United States)

    Khuri, Marcus; Woolgar, Eric

    2017-11-01

    We show that near-horizon geometries in the presence of a positive cosmological constant cannot exist with ring topology. In particular, de Sitter black rings with vanishing surface gravity do not exist. Our result relies on a known mathematical theorem which is a straightforward consequence of a type of energy condition for a modified Ricci tensor, similar to the curvature-dimension conditions for the m-Bakry-Émery-Ricci tensor.

  3. A Review of Piston Compression Ring Tribology

    Directory of Open Access Journals (Sweden)

    P.C. Mishra

    2014-09-01

    Full Text Available This paper presents studies related to piston compression ring tribology and the theoretical and experimental works developed to analyze ring-liner contact friction. The literatures revealed that the simulation and experimental work are more independently investigated. The correlation of modeling output with experimental output is presented in limited number of research works. The experimental work to capture data from a running engine is also in basic level.

  4. Prometheus Induced Vorticity in Saturn's F Ring

    Science.gov (United States)

    Sutton, Phil J.; Kusmartsev, Feo V.

    2016-11-01

    Saturn's rings are known to show remarkable real time variability in their structure. Many of which can be associated to interactions with nearby moons and moonlets. Possibly the most interesting and dynamic place in the rings, probably in the whole Solar System, is the F ring. A highly disrupted ring with large asymmetries both radially and azimuthally. Numerically non-zero components to the curl of the velocity vector field (vorticity) in the perturbed area of the F ring post encounter are witnessed, significantly above the background vorticity. Within the perturbed area rich distributions of local rotations is seen located in and around the channel edges. The gravitational scattering of ring particles during the encounter causes a significant elevated curl of the vector field above the background F ring vorticity for the first 1-3 orbital periods post encounter. After 3 orbital periods vorticity reverts quite quickly to near background levels. This new found dynamical vortex life of the ring will be of great interest to planet and planetesimals in proto-planetary disks where vortices and turbulence are suspected of having a significant role in their formation and migrations. Additionally, it is found that the immediate channel edges created by the close passage of Prometheus actually show high radial dispersions in the order 20-50 cm/s, up to a maximum of 1 m/s. This is much greater than the value required by Toomre for a disk to be unstable to the growth of axisymmetric oscillations. However, an area a few hundred km away from the edge shows a more promising location for the growth of coherent objects.

  5. Ring oscillator switching noise under NBTI wearout

    OpenAIRE

    Fernández García, Raúl; Gil Galí, Ignacio; Ruiz, José María; Morata Cariñena, Marta

    2011-01-01

    In this paper the switching noise of a CMOS ring oscillator has been analysed when their pFETs are subjected to negative bias temperature instability (NBTI). The impact of pFET under NBTI has been experimentally quantified whereas CMOS ring oscillator frequency and the switching noise has been analysed by means of electrical full-model simulation. The results show that the impact on the electromagnetic compatibility behaviour increases with NBTI wearout. Peer Reviewed

  6. Collective Effects in the CLIC Damping Rings

    CERN Document Server

    Zimmermann, Frank; Korostelev, Maxim S; Schulte, Daniel; Yokoya, Kaoru

    2005-01-01

    The small emittance, short bunch length, and high current in the CLIC damping ring could give rise to collective effects which degrade the quality of the extracted beam. In this paper, we survey a number of possible instabilities and estimate their impact on the ring performance. The effects considered include fast beam-ion instability, coherent synchrotron radiation, Touschek scattering, intrabeam scattering, resistive-wall wake fields, and electron cloud.

  7. Eelgrass fairy rings: sulfide as inhibiting agent

    DEFF Research Database (Denmark)

    Borum, Jens; Raun, Ane-Marie Løvendahl; Hasler-Sheetal, Harald

    2014-01-01

    specifically, for the apparent die- off of eelgrass shoots on the inner side of the rings. The fairy rings were up to 15 m in diameter consisting of 0.3- to 1-m-wide zones of sea grass shoots at densities of up to 1,200 shoots m−2 and rooted in an up to 10-cm-thick sediment layer. On the outer side, shoots...

  8. Power cocentralizing generalized derivations on prime rings

    Indian Academy of Sciences (India)

    ring it follows that [R,R] ⊆ L. This follows from pp. 4–5 in [6], Lemma 2 and Proposition 1 in [4] and Theorem 4 in [8]. 2. The case of inner generalized derivations on prime rings. We dedicate this section to prove the theorem in case both the generalized derivations. H and G are inner, that is there exist b, c, p, q ∈ U such that ...

  9. Integral Ring Carbon-Carbon Piston

    Science.gov (United States)

    Northam, G. Burton (Inventor)

    1999-01-01

    An improved structure for a reciprocating internal combustion engine or compressor piston fabricate from carbon-carbon composite materials is disclosed. An integral ring carbon-carbon composite piston, disclosed herein, reduces the need for piston rings and for small clearances by providing a small flexible, integral component around the piston that allows for variation in clearance due to manufacturing tolerances, distortion due to pressure and thermal loads, and variations in thermal expansion differences between the piston and cylinder liner.

  10. Characteristics of an Integrated Optics Ring Resonator.

    Science.gov (United States)

    1983-08-01

    water before polishing. A 3/4 inch pitch polishing lap is prepared using 50% soft optical pitch. The pitch is melted and poured onto a flat metal lap. To...working on the devel- Typical lae powers for laser writing range from 8 pW to OPawnt Of a ring interferometer in glass, consisting Of a ring 0.5 mW

  11. Computerspil og læring

    DEFF Research Database (Denmark)

    Larsen, Lasse Juel

    2015-01-01

    Game-based learning og gamification er ord, der ofte optræder i forbindelse med computerspil og læring. Denne artikel vil analytisk undersøge, hvordan computerspil og læring går i forbindelse med hinanden. Artikel tager afsæt i Gregory Batesons læringsteori og læser denne igennem det kommercielle...

  12. Inelastic neutron scattering from superconducting rings

    International Nuclear Information System (INIS)

    Agafonov, A.I.

    2010-01-01

    For the first time the differential cross section for the inelastic magnetic neutron scattering by superconducting rings is derived taking account of the interaction of the neutron magnetic moment with the magnetic field generated by the superconducting current. Calculations of the scattering cross section are carried out for cold neutrons and thin film rings from type-II superconductors with the magnetic fields not exceeding the first critical field.

  13. Latest on polarization in electron storage rings

    International Nuclear Information System (INIS)

    Chao, A.W.

    1983-01-01

    The field of beam polarization in electron storage rings is making rapid progress in recent several years. This report is an attempt to summarize some of these developments concerning how to produce and maintain a high level of beam polarization. Emphasized will be the ideas and current thoughts people have on what should and could be done on electron rings being designed at present such as HERA, LEP and TRISTAN. 23 references

  14. Tannakian duality over Dedekind rings and applications

    OpenAIRE

    Duong, Nguyen Dai; Hai, Phùng Hô

    2013-01-01

    We establish a duality between flat affine group schemes and rigid tensor categories equipped with a neutral fiber functor (called Tannakian lattice), both defined over a Dedekind ring. We use this duality and the known Tannakian duality due to Saavedra to study morphisms between flat affine group schemes. Next, we apply our new duality to the category of stratified sheaves on a smooth scheme over a Dedekind ring R to define the relative differential fundamental group scheme of the given sche...

  15. Ring Avulsion Injuries: A Systematic Review.

    Science.gov (United States)

    Bamba, Ravinder; Malhotra, Gautam; Bueno, Reuben A; Thayer, Wesley P; Shack, R Bruce

    2018-01-01

    Ring avulsion injuries can range from soft tissue injury to complete amputation. Grading systems have been developed to guide treatment, but there is controversy with high-grade injuries. Traditionally, advanced ring injuries have been treated with completion amputation, but there is evidence that severe ring injuries can be salvaged. The purpose of this systematic review was to pool the current published data on ring injuries. A systematic review of the English literature published from 1980 to 2015 in PubMed and MEDLINE databases was conducted to identify patients who underwent treatment for ring avulsion injuries. Twenty studies of ring avulsion injuries met the inclusion criteria. There were a total of 572 patients reported with ring avulsion injuries. The Urbaniak class breakdown was class I (54 patients), class II (204 patients), and class III (314 patients). The average total arc of motion (TAM) for patients with a class I injury was 201.25 (n = 40). The average 2-point discrimination was 5.6 (n = 10). The average TAM for patients with a class II injury undergoing microsurgical revascularization was 187.0 (n = 114), and the average 2-point discrimination was 8.3 (n = 40). The average TAM for patients with a class III injury undergoing microsurgical revascularization was 168.2 (n = 170), and the average 2-point discrimination was 10.5 (n = 97). Ring avulsion injuries are commonly classified with the Urbaniak class system. Outcomes are superior for class I and II injuries, and there are select class III injuries that can be treated with replantation. Shared decision making with patients is imperative to determine whether replantation is appropriate.

  16. SNS RING STUDY AT THE AGS BOOSTER

    International Nuclear Information System (INIS)

    ZHANG, S.Y.; AHRENS, L.; BEEBE-WANG, J.; BLASKIEWICZ, M.; FEDOTOV, A.; GARDNER, C.; LEE, Y.Y.; LUCCIO, A.; MALITSKY, N.; ROSER, T.; WENG, W.T.; WEI, J.; ZENO, K.; REECE, K.; WANG, J.G.

    2000-01-01

    During the g-2 run at the BNL AGS in early 2000, a 200 MeV storage-ring-like magnetic cycle has been set-up and tuned at the Booster in preparing for the Spallation Neutron Source (SNS) accumulator ring study. In this article, we report the progress of the machine set-up, tuning, some preliminary studies, and the future plan

  17. Control of ring lasers by means of coupled cavities

    DEFF Research Database (Denmark)

    Buchhave, Preben; Abitan, Haim; Tidemand-Lichtenberg, Peter

    2000-01-01

    Variable phase coupling to an external ring is used to control a unidirectional ring laser. The observed behavior of the coupled rings is explained theoretically. We have found experimentally that by quickly changing the phase of the feedback from the external ring it is possible to Q-switch the ......-switch the ring laser. Also, at certain values of the phase of the feedback in the external ring, instabilities in the total system occur and oscillations arise in the ring laser.......Variable phase coupling to an external ring is used to control a unidirectional ring laser. The observed behavior of the coupled rings is explained theoretically. We have found experimentally that by quickly changing the phase of the feedback from the external ring it is possible to Q...

  18. Achieving Translationally Invariant Trapped Ion Rings

    Science.gov (United States)

    Urban, Erik; Li, Hao-Kun; Noel, Crystal; Hemmerling, Boerge; Zhang, Xiang; Haeffner, Hartmut

    2017-04-01

    We present the design and implementation of a novel surface ion trap design in a ring configuration. By eliminating the need for wire bonds through the use of electrical vias and using a rotationally invariant electrode configuration, we have realized a trap that is able to trap up to 20 ions in a ring geometry 45um in diameter, 400um above the trap surface. This large trapping height to ring diameter ratio allows for global addressing of the ring with both lasers and electric fields in the chamber, thereby increasing our ability to control the ring as a whole. Applying compensating electric fields, we measure very low tangential trap frequencies (less than 20kHz) corresponding to rotational barriers down to 4mK. This measurement is currently limited by the temperature of the ions but extrapolation indicates the barrier can be reduced much further with more advanced cooling techniques. Finally, we show that we are able to reduce this energy barrier sufficiently such that the ions are able to overcome it either through thermal motion or rotational motion and delocalize over the full extent of the ring. This work was funded by the Keck Foundation and the NSF.

  19. INJECTION EFFICIENCY IN COMPTON RING NESTOR

    Directory of Open Access Journals (Sweden)

    P. I. Gladkikh

    2017-12-01

    Full Text Available NESTOR is the hard X-ray source that is under commissioning at NSC KIPT. NESTOR based on the Compton scattering of laser photons on relativistic electrons. The structure of the facility can be represented as the following components: a linear accelerator, a transport channel, a storage ring, and a laser-optical system. Electrons are stored in the storage ring for energy of 40-200 MeV. Inevitable alignment errors of magnetic elements are strongly effect on the beam dynamics in the storage ring. These errors lead to a shift of the equilibrium orbit relative to the ideal one. Significant shift of the equilibrium orbit could lead to loss of the beam on physical apertures. Transverse sizes of electron and laser beams are only few tens of microns at the interaction point. The shift of electron beam at the interaction point could greatly complicate the operation adjustment of storage ring without sufficient beam position diagnostic system. This article presents the simulation results of the efficiency of electron beam accumulation in the NESTOR storage ring. Also, this article is devoted to electron beam dynamics due to alignment errors of magnetic element in the ring.

  20. Hitchhikers’ guide to analysing bird ringing data

    Directory of Open Access Journals (Sweden)

    Harnos Andrea

    2015-12-01

    Full Text Available Bird ringing datasets constitute possibly the largest source of temporal and spatial information on vertebrate taxa available on the globe. Initially, the method was invented to understand avian migration patterns. However, data deriving from bird ringing has been used in an array of other disciplines including population monitoring, changes in demography, conservation management and to study the effects of climate change to name a few. Despite the widespread usage and importance, there are no guidelines available specifically describing the practice of data management, preparation and analyses of ringing datasets. Here, we present the first of a series of comprehensive tutorials that may help fill this gap. We describe in detail and through a real-life example the intricacies of data cleaning and how to create a data table ready for analyses from raw ringing data in the R software environment. Moreover, we created and present here the R package; ringR, designed to carry out various specific tasks and plots related to bird ringing data. Most methods described here can also be applied to a wide range of capture-recapture type data based on individual marking, regardless to taxa or research question.

  1. Rings of non-spherical, axisymmetric bodies

    Science.gov (United States)

    Gupta, Akash; Nadkarni-Ghosh, Sharvari; Sharma, Ishan

    2018-01-01

    We investigate the dynamical behavior of rings around bodies whose shapes depart considerably from that of a sphere. To this end, we have developed a new self-gravitating discrete element N-body code, and employed a local simulation method to simulate a patch of the ring. The central body is modeled as a symmetric (oblate or prolate) ellipsoid, or defined through the characteristic frequencies (circular, vertical, epicyclic) that represent its gravitational field. Through our simulations we explore how a ring's behavior - characterized by dynamical properties like impact frequency, granular temperature, number density, vertical thickness and radial width - varies with the changing gravitational potential of the central body. We also contrast properties of rings about large central bodies (e.g. Saturn) with those of smaller ones (e.g. Chariklo). Finally, we investigate how the characteristic frequencies of a central body, restricted to being a solid of revolution with an equatorial plane of symmetry, affect the ring dynamics. The latter process may be employed to qualitatively understand the dynamics of rings about any symmetric solid of revolution.

  2. Phase behaviour of polyethylene knotted ring chains

    International Nuclear Information System (INIS)

    Wen Xiao-Hui; Xia A-Gen; Chen Hong-Ping; Zhang Lin-Xi

    2011-01-01

    The phase behaviour of polyethylene knotted ring chains is investigated by using molecular dynamics simulations. In this paper, we focus on the collapse of the polyethylene knotted ring chain, and also present the results of linear and ring chains for comparison. At high temperatures, a fully extensive knot structure is observed. The mean-square radius of gyration per bond (S 2 )/(Nb 2 ) and the shape factor (δ*) depend on not only the chain length but also the knot type. With temperature decreasing, chain collapse is observed, and the collapse temperature decreases with the chain length increasing. The actual collapse transition can be determined by the specific heat capacity C v , and the knotted ring chain undergoes gas—liquid—solid-like transition directly. The phase transition of a knotted ring chain is only one-stage collapse, which is different from the polyethylene linear and ring chains. This investigation can provide some insights into the statistical properties of knotted polymer chains. (condensed matter: structural, mechanical, and thermal properties)

  3. Systematic Search for Rings around Kepler Planet Candidates: Constraints on Ring Size and Occurrence Rate

    Science.gov (United States)

    Aizawa, Masataka; Masuda, Kento; Kawahara, Hajime; Suto, Yasushi

    2018-05-01

    We perform a systematic search for rings around 168 Kepler planet candidates with sufficient signal-to-noise ratios that are selected from all of the short-cadence data. We fit ringed and ringless models to their light curves and compare the fitting results to search for the signatures of planetary rings. First, we identify 29 tentative systems, for which the ringed models exhibit statistically significant improvement over the ringless models. The light curves of those systems are individually examined, but we are not able to identify any candidate that indicates evidence for rings. In turn, we find several mechanisms of false positives that would produce ringlike signals, and the null detection enables us to place upper limits on the size of the rings. Furthermore, assuming the tidal alignment between axes of the planetary rings and orbits, we conclude that the occurrence rate of rings larger than twice the planetary radius is less than 15%. Even though the majority of our targets are short-period planets, our null detection provides statistical and quantitative constraints on largely uncertain theoretical models of the origin, formation, and evolution of planetary rings.

  4. Mechanical improvement of metal reinforcement rings for a finite ring-shaped superconducting bulk

    Science.gov (United States)

    Huang, Chen-Guang; Zhou, You-He

    2018-03-01

    As a key technique, reinforcement of type-II superconducting bulks with metal rings can efficiently improve their mechanical properties to enhance the maximum trapped field. In this paper, we study the magnetostrictive and fracture behaviors of a finite superconducting ring bulk reinforced by three typical reinforcing structures composed of metal rings during the magnetizing process by means of the minimization of magnetic energy and the finite element method. After a field-dependent critical current density is adopted, the magnetostriction, pinning-induced stress, and crack tip stress intensity factor are calculated considering the demagnetization effects. The results show that the mechanical properties of the ring bulk are strongly dependent on the reinforcing structure and the material and geometrical parameters of the metal rings. Introducing the metal ring can significantly reduce the hoop stress, and the reduction effect by internal reinforcement is much improved relative to external reinforcement. By comparison, bilateral reinforcement seems to be the best candidate structure. Only when the metal rings have particular Young's modulus and radial thickness will they contribute to improve the mechanical properties the most. In addition, if an edge crack is pre-existing in the ring bulk, the presence of metal rings can effectively avoid crack propagation since it reduces the crack tip stress intensity factor by nearly one order of magnitude.

  5. Surface roughness of Saturn's rings and ring particles inferred from thermal phase curves

    Science.gov (United States)

    Morishima, Ryuji; Turner, Neal; Spilker, Linda

    2017-10-01

    We analyze thermal phase curves of all the main rings of Saturn (the A, B, C rings, and the Cassini division) measured by both the far-IR and mid-IR detectors of the Cassini Composite InfraRed Spectrometer (CIRS). All the rings show temperature increases toward zero phase angle, known as an opposition effect or thermal beaming. For the C ring and Cassini division, which have low optical depths, intra-particle shadowing is considered the dominant mechanism causing the effect. On the other hand, the phase curves of the optically thick B and A rings steepen significantly with decreasing absolute solar elevation angle from 21° to 14°, suggesting inter-particle shadowing plays an important role in these rings. We employ an analytic roughness model to estimate the degrees of surface roughness of the rings or ring particles. For optically thin rings, an isolated particle covered by spherical segment craters is employed while for the thick rings we approximate a packed particle layer as a slab covered by craters. The particles in the thin rings are found to have generally rough surfaces, except in the middle C ring. Across the C ring, the optical depth correlates with the degree of surface roughness. This may indicate that surface roughness comes mainly from particle clumping, while individual particles have rather smooth surfaces. For the optically thick rings, the surface roughness of the particle layer is found to be moderate. The modeled phase curves of optically thick rings are shallow if the phase angle change is primarily due to change of observer azimuthal angle. On the other hand, the phase curves are steep if the phase angle change is due to change of observer elevation angle, as inter-particle shadows become visible at higher observer elevation. In addition, the area of shadowed facets increases with decreasing solar elevation angle. These combined effects explain the large seasonal change of the phase curve steepness observed for the thick rings. The degrees

  6. Mechanical improvement of metal reinforcement rings for a finite ring-shaped superconducting bulk

    Directory of Open Access Journals (Sweden)

    Chen-Guang Huang

    2018-03-01

    Full Text Available As a key technique, reinforcement of type-II superconducting bulks with metal rings can efficiently improve their mechanical properties to enhance the maximum trapped field. In this paper, we study the magnetostrictive and fracture behaviors of a finite superconducting ring bulk reinforced by three typical reinforcing structures composed of metal rings during the magnetizing process by means of the minimization of magnetic energy and the finite element method. After a field-dependent critical current density is adopted, the magnetostriction, pinning-induced stress, and crack tip stress intensity factor are calculated considering the demagnetization effects. The results show that the mechanical properties of the ring bulk are strongly dependent on the reinforcing structure and the material and geometrical parameters of the metal rings. Introducing the metal ring can significantly reduce the hoop stress, and the reduction effect by internal reinforcement is much improved relative to external reinforcement. By comparison, bilateral reinforcement seems to be the best candidate structure. Only when the metal rings have particular Young’s modulus and radial thickness will they contribute to improve the mechanical properties the most. In addition, if an edge crack is pre-existing in the ring bulk, the presence of metal rings can effectively avoid crack propagation since it reduces the crack tip stress intensity factor by nearly one order of magnitude.

  7. Novel manifestations of the Aharonov-Bohm effect in quantum rings and Moebius rings

    International Nuclear Information System (INIS)

    Fomin, Vladimir M.

    2013-01-01

    - An overview is given on the recent experimental and theoretical advancements in studies of novel manifestations of the Aharonov-Bohm quantum-interference effect for excitons confined to self assembled quantum rings and other semiconductor nanostructures with ring-like states of charge carriers as well as for electrons in Moebius rings at the micro- and nanoscale. The exciton Aharonov-Bohm effect can be effectively controlled by an out-of-plane magnetic field, a vertical electric field, a spin disorder. A 'delocalization-to-localization' transition for the electron ground state occurs in a Moebius ring as it is made more inhomogeneous. (authors)

  8. Particle sizes in Saturn's rings from UVIS stellar occultations 1. Variations with ring region

    Science.gov (United States)

    Colwell, J. E.; Esposito, L. W.; Cooney, J. H.

    2018-01-01

    The Cassini spacecraft's Ultraviolet Imaging Spectrograph (UVIS) includes a high speed photometer (HSP) that has observed stellar occultations by Saturn's rings with a radial resolution of ∼10 m. In the absence of intervening ring material, the time series of measurements by the HSP is described by Poisson statistics in which the variance equals the mean. The finite sizes of the ring particles occulting the star lead to a variance that is larger than the mean due to correlations in the blocking of photons due to finite particle size and due to random variations in the number of individual particles in each measurement area. This effect was first exploited by Showalter and Nicholson (1990) with the stellar occultation observed by Voyager 2. At a given optical depth, a larger excess variance corresponds to larger particles or clumps that results in greater variation of the signal from measurement to measurement. Here we present analysis of the excess variance in occultations observed by Cassini UVIS. We observe differences in the best-fitting particle size in different ring regions. The C ring plateaus show a distinctly smaller effective particle size, R, than the background C ring, while the background C ring itself shows a positive correlation between R and optical depth. The innermost 700 km of the B ring has a distribution of excess variance with optical depth that is consistent with the C ring ramp and C ring but not with the remainder of the B1 region. The Cassini Division, while similar to the C ring in spectral and structural properties, has different trends in effective particle size with optical depth. There are discrete jumps in R on either side of the Cassini Division ramp, while the C ring ramp shows a smooth transition in R from the C ring to the B ring. The A ring is dominated by self-gravity wakes whose shadow size depends on the occultation geometry. The spectral ;halo; regions around the strongest density waves in the A ring correspond to

  9. Stable CSR in Storage Rings: A Model

    International Nuclear Information System (INIS)

    Sannibale, F.

    2005-01-01

    A comprehensive historical view of the work done on coherent synchrotron radiation (CSR) in storage rings is given in reference [1]. Here we want just to point out that even if the issue of CSR in storage rings was already discussed over 50 years ago, it is only recently that a considerable number of observations have been reported. In fact, intense bursts of coherent synchrotron radiation with a stochastic character were measured in the terahertz frequency range, at several synchrotron light source storage rings [2-8]. It has been shown [8-11], that this bursting emission of CSR is associated with a single bunch instability, usually referred as microbunching instability (MBI), driven by the fields of the synchrotron radiation emitted by the bunch itself. Of remarkably different characteristics was the CSR emission observed at BESSY II in Berlin, when the storage ring was tuned into a special low momentum compaction mode [12, 13]. In fact, the emitted radiation was not the quasi-random bursting observed in the other machines, but a powerful and stable flux of broadband CSR in the terahertz range. This was an important result, because it experimentally demonstrated the concrete possibility of constructing a stable broadband source with extremely high power in the terahertz region. Since the publication of the first successful experiment using the ring as a CSR source [14], BESSY II has regular scheduled user's shifts dedicated to CSR experiments. At the present time, several other laboratories are investigating the possibility of a CSR mode of operation [15-17] and a design for a new ring optimized for CSR is at an advanced stage [18]. In what follows, we describe a model that first accounts for the BESSY II observations and then indicates that the special case of BESSY II is actually quite general and typical when relativistic electron storage rings are tuned for short bunches. The model provides a scheme for predicting and optimizing the performance of ring

  10. Stable CSR in storage rings: A model

    International Nuclear Information System (INIS)

    Sannibale, Fernando; Byrd, John M.; Loftsdottir, Agusta; Venturini, Marco; Abo-Bakr, Michael; Feikes, Jorge; Holldack, Karsten; Kuske, Peter; Wustefeld, Godehart; Hubers, Heinz-Willerm; Warnock, Robert

    2005-01-01

    A comprehensive historical view of the work done on coherent synchrotron radiation (CSR) in storage rings is given in reference [1]. Here we want just to point out that even if the issue of CSR in storage rings was already discussed over 50 years ago, it is only recently that a considerable number of observations have been reported. In fact, intense bursts of coherent synchrotron radiation with a stochastic character were measured in the terahertz frequency range, at several synchrotron light source storage rings [2-8]. It has been shown [8-11], that this bursting emission of CSR is associated with a single bunch instability, usually referred as microbunching instability (MBI), driven by the fields of the synchrotron radiation emitted by the bunch itself. Of remarkably different characteristics was the CSR emission observed at BESSY II in Berlin, when the storage ring was tuned into a special low momentum compaction mode [12, 13]. In fact, the emitted radiation was not the quasi-random bursting observed in the other machines, but a powerful and stable flux of broadband CSR in the terahertz range. This was an important result, because it experimentally demonstrated the concrete possibility of constructing a stable broadband source with extremely high power in the terahertz region. Since the publication of the first successful experiment using the ring as a CSR source [14], BESSY II has regular scheduled user s shifts dedicated to CSR experiments. At the present time, several other laboratories are investigating the possibility of a CSR mode of operation [15-17] and a design for a new ring optimized for CSR is at an advanced stage [18]. In what follows, we describe a model that first accounts for the BESSY II observations and then indicates that the special case of BESSY II is actually quite general and typical when relativistic electron storage rings are tuned for short bunches. The model provides a scheme for predicting and optimizing the performance of ring

  11. α-Skew π-McCoy Rings

    Directory of Open Access Journals (Sweden)

    Areej M. Abduldaim

    2013-01-01

    Full Text Available As a generalization of α-skew McCoy rings, we introduce the concept of α-skew π-McCoy rings, and we study the relationships with another two new generalizations, α-skew π1-McCoy rings and α-skew π2-McCoy rings, observing the relations with α-skew McCoy rings, π-McCoy rings, α-skew Armendariz rings, π-regular rings, and other kinds of rings. Also, we investigate conditions such that α-skew π1-McCoy rings imply α-skew π-McCoy rings and α-skew π2-McCoy rings. We show that in the case where R is a nonreduced ring, if R is 2-primal, then R is an α-skew π-McCoy ring. And, let R be a weak (α,δ-compatible ring; if R is an α-skew π1-McCoy ring, then R is α-skew π2-McCoy.

  12. On rings generating supernilpotent and special atoms | France ...

    African Journals Online (AJOL)

    We study prime rings which generate supernilpotent (respectively special) atoms, that is, atoms of the lattice of all supernilpotent (respectively special) radicals. A prime ring A is called a **-ring if the smallest special class containing A is closed under semiprime homomorphic images of A. A semiprime ring A whose every ...

  13. Rings Related to Special Atoms | France-Jackson | Quaestiones ...

    African Journals Online (AJOL)

    Abstract unavailable at this time... Mathematics Subject Classification (1991): 16A21, 16A12 Keywords: ring, special atoms, atoms, *k-ring, prime ring, *-ring, Jacobson, artinia, essential extension, homomorphic image, ideals. Quaestiones Mathematicae 24(1) 2001, 105–109 ...

  14. Temperature histories from tree rings and corals

    Energy Technology Data Exchange (ETDEWEB)

    Cook, E.R. [Tree-Ring Lab., Palisades, NY (United States)

    1995-05-01

    Recent temperature trends in long tree-ring and coral proxy temperature histories are evaluated and compared in an effort to objectively determine how anomalous twentieth century temperature changes have been. These histories mostly reflect regional variations in summer warmth from the tree rings and annual warmth from the corals. In the Northern Hemisphere. the North American tree-ring temperature histories and those from the north Polar Urals, covering the past 1000 or more years, indicate that the twentieth century has been anomalously warm relative to the past. In contrast, the tree-ring history from northern Fennoscandia indicates that summer temperatures during the {open_quote}Medieval Warm Period{close_quote} were probably warmer on average than those than during this century. In the Southern Hemisphere, the tree-ring temperature histories from South America show no indication of recent warming, which is in accordance with local instrumental records. In contrast, the tree-ring, records from Tasmania and New Zealand indicate that the twentieth century has been unusually warm particularly since 1960. The coral temperature histories from the Galapagos Islands and the Great Barrier Reef are in broad agreement with the tree-ring temperature histories in those sectors, with the former showing recent cooling and the latter showing recent warming that may be unprecedented. Overall, the regional temperature histories evaluated here broadly support the larger-scale evidence for anomalous twentieth century warming based on instrumental records. However, this warming cannot be confirmed as an unprecedented event in all regions. 38 refs., 3 figs., 2 tabs.

  15. A note on derivations in semiprime rings

    Directory of Open Access Journals (Sweden)

    Joso Vukman

    2005-01-01

    Full Text Available We prove in this note the following result. Let n>1 be an integer and let R be an n!-torsion-free semiprime ring with identity element. Suppose that there exists an additive mapping D:R→R such that D(xn=∑j=1nxn−jD(xxj−1 is fulfilled for all x∈R. In this case, D is a derivation. This research is motivated by the work of Bridges and Bergen (1984. Throughout, R will represent an associative ring with center Z(R. Given an integer n>1, a ring R is said to be n-torsion-free if for x∈R, nx=0 implies that x=0. Recall that a ring R is prime if for a,b∈R, aRb=(0 implies that either a=0 or b=0, and is semiprime in case aRa=(0 implies that a=0. An additive mapping D:R→R is called a derivation if D(xy=D(xy+xD(y holds for all pairs x,y∈R and is called a Jordan derivation in case D(x2=D(xx+xD(x is fulfilled for all x∈R. Every derivation is a Jordan derivation. The converse is in general not true. A classical result of Herstein (1957 asserts that any Jordan derivation on a prime ring with characteristic different from two is a derivation. A brief proof of Herstein's result can be found in 1988 by Brešar and Vukman. Cusack (1975 generalized Herstein's result to 2-torsion-free semiprime rings (see also Brešar (1988 for an alternative proof. For some other results concerning derivations on prime and semiprime rings, we refer to Brešar (1989, Vukman (2005, Vukman and Kosi-Ulbl (2005.

  16. Analysis list: RING1 [Chip-atlas[Archive

    Lifescience Database Archive (English)

    Full Text Available RING1 Breast,Epidermis,Prostate + hg19 http://dbarchive.biosciencedbc.jp/kyushu-u/h...g19/target/RING1.1.tsv http://dbarchive.biosciencedbc.jp/kyushu-u/hg19/target/RING1.5.tsv http://dbarchive.bioscience...dbc.jp/kyushu-u/hg19/target/RING1.10.tsv http://dbarchive.biosciencedbc.jp/kyushu-u/hg19/colo/RING1....Breast.tsv,http://dbarchive.biosciencedbc.jp/kyushu-u/hg19/colo/RING1.Epidermis....tsv,http://dbarchive.biosciencedbc.jp/kyushu-u/hg19/colo/RING1.Prostate.tsv http://dbarchive.biosciencedbc.j

  17. Quality Assurance Project Plan for Verification of Sediment Ecotoxicity Assessment Ring(SEA Ring)

    Science.gov (United States)

    The objective of the verification is to test the efficacy and ability of the Sediment Ecotoxicity Assessment Ring (SEA Ring) to evaluate the toxicity of contaminants in the sediment, at the sediment-water interface, and WC to organisms that live in those respective environments.

  18. The combined contraceptive ring NuvaRing and spermicide co-medication.

    Science.gov (United States)

    Haring, T; Mulders, T M T

    2003-04-01

    The effects of nonoxynol-9 on etonogestrel and ethinylestradiol release and absorption from NuvaRing were studied in 12 subjects for two cycles: one control and one interaction cycle (nonoxynol-9 was administered on day 8). Nonoxynol-9 had no effect on release or absorption and, consequently, serum levels. Therefore, nonoxynol-9 did not compromise the contraceptive efficacy of NuvaRing.

  19. Analytical model for double split ring resonators with arbitrary ring width

    DEFF Research Database (Denmark)

    Zhurbenko, Vitaliy; Jensen, Thomas; Krozer, Viktor

    2008-01-01

    For the first time, the analytical model for a double split ring resonator with unequal width rings is developed. The proposed models for the resonators with equal and unequal widths are based on an impedance matrix representation and provide the prediction of performance in a wide frequency range...

  20. Cassini UVIS Observations Show Active Saturn's Rings

    Science.gov (United States)

    Esposito, L.; Colwell, J. E.; UVIS Team

    2004-12-01

    The Cassini Ultraviolet Imaging Spectrograph (UVIS) is part of the remote sensing payload of the NASA/ESA Cassini spacecraft. This spectrograph includes channels for extreme UV and far UV spectroscopic imaging, high speed photometry of stellar occultations, solar EUV occultation, and a hydrogen/deuterium absorption cell. We report our initial results from UVIS observations of Saturn's rings. Dynamic interactions between neutrals, ions, rings, moons and meteoroids produce a highly structured and time variable Saturn system Oxygen in the Saturn system dominates the magnetosphere. Observed fluctuations indicate close interactions with plasma sources. Stochastic events in the E ring may be the ultimate source. The spectral signature of water ice is seen on Phoebe and in Saturn's rings. Water ice is mixed non-uniformly with darker constituents. The high structure of the UV ring reflectance argues that collisional transport dominates ballistic transport in darkening the rings. Our preliminary results support the idea that rings are recycled fragments of moons: the current processes are more important than history and initial conditions. The spectra along the UVIS SOI radial scan indicate varying amounts of water ice. In the A ring, the ice fraction increases outward to a maximum at the outer edge. This large-scale variation is consistent with initially pure ice that has suffered meteoritic bombardment over the age of the Solar system (Cuzzi and Estrada 1998). We also see variations over scales of 1000 - 3000 km, which cannot be explained by this mechanism. Ballistic transport of spectrally neutral extrinsic pollutants from meteoroids striking the rings has a typical throw distance of 6000 km (Durisen et al 1989), too long to explain this finer structure. We propose a class of smaller renewal events, in which a small moon residing within the rings is shattered by an external impactor (Colwell and Esposito 1993, Barbara and Esposito 2002, Esposito and Colwell 2003). The

  1. A Summary and Status of the SNS Ring Vacuum Systems

    CERN Document Server

    Mapes, Michael; Hseuh Hsiao Chaun; Ladd, Peter; Rank, Jim; Smart, Loralie; Todd, Robert J; Weiss, Daniel

    2005-01-01

    The Spallation Neutron Source (SNS) ring is designed to accumulate high intensity protons. The SNS ring vacuum system consists of the High Energy Beam Transport (HEBT) line, Accumulator Ring and the Ring to Target Beam Transport (RTBT) line. The Accumulator ring has a circumference of 248m with 4 arcs and 4 straight sections, while the RTBT and HEBT have a total length of 350m of beam transport line. Ultrahigh vacuum of 10-9

  2. Light-Ring Stability for Ultracompact Objects

    Science.gov (United States)

    Cunha, Pedro V. P.; Berti, Emanuele; Herdeiro, Carlos A. R.

    2017-12-01

    We prove the following theorem: axisymmetric, stationary solutions of the Einstein field equations formed from classical gravitational collapse of matter obeying the null energy condition, that are everywhere smooth and ultracompact (i.e., they have a light ring) must have at least two light rings, and one of them is stable. It has been argued that stable light rings generally lead to nonlinear spacetime instabilities. Our result implies that smooth, physically and dynamically reasonable ultracompact objects are not viable as observational alternatives to black holes whenever these instabilities occur on astrophysically short time scales. The proof of the theorem has two parts: (i) We show that light rings always come in pairs, one being a saddle point and the other a local extremum of an effective potential. This result follows from a topological argument based on the Brouwer degree of a continuous map, with no assumptions on the spacetime dynamics, and, hence, it is applicable to any metric gravity theory where photons follow null geodesics. (ii) Assuming Einstein's equations, we show that the extremum is a local minimum of the potential (i.e., a stable light ring) if the energy-momentum tensor satisfies the null energy condition.

  3. Report of the New Rings Study Group

    International Nuclear Information System (INIS)

    Holmes, S.D.; Dugan, G.; Marriner, J.

    1987-01-01

    We have taken the approach here of trying to understand both the feasibility and practicality of varied options for new rings at Fermilab, rather than trying to produce a single detailed design. In other words, this document is not a design report and should not be construed as such. Our perception of the potential needs for new rings (in order of priority) is as follows: Antiproton Storage and/or Recovery: A facility for storing up to 4 x 10 12 antiprotons is needed. Recovery of antiprotons from the collider becomes a viable option if the luminosity is indeed dominated by emittance dilution rather than beam loss. New or Post-Booster: The goal here would be to inject into the existing Main Ring above transition. Improved performance of the Main Ring would be anticipated. New Main Ring: Advantages would include better emittance preservation, a faster cycle time for antiproton production, and the removal of interference/backgrounds at the B0 and D0 detectors. We discuss in this paper various scenarios based on one or more combinations of the above possibilities. 14 figs., 10 tabs

  4. Report of the New Rings Study Group

    Energy Technology Data Exchange (ETDEWEB)

    Holmes, S.D.; Dugan, G.; Marriner, J.

    1987-10-19

    We have taken the approach here of trying to understand both the feasibility and practicality of varied options for new rings at Fermilab, rather than trying to produce a single detailed design. In other words, this document is not a design report and should not be construed as such. Our perception of the potential needs for new rings (in order of priority) is as follows: Antiproton Storage and/or Recovery: A facility for storing up to 4 x 10/sup 12/ antiprotons is needed. Recovery of antiprotons from the collider becomes a viable option if the luminosity is indeed dominated by emittance dilution rather than beam loss. New or Post-Booster: The goal here would be to inject into the existing Main Ring above transition. Improved performance of the Main Ring would be anticipated. New Main Ring: Advantages would include better emittance preservation, a faster cycle time for antiproton production, and the removal of interference/backgrounds at the B0 and D0 detectors. We discuss in this paper various scenarios based on one or more combinations of the above possibilities. 14 figs., 10 tabs.

  5. The Vibration Ring. Phase 1; [Seedling Fund

    Science.gov (United States)

    Asnani, Vivake M.; Krantz, Timothy L.; Delap, Damon C.; Stringer, David B.

    2014-01-01

    The vibration ring was conceived as a driveline damping device to prevent structure-borne noise in machines. It has the appearance of a metal ring, and can be installed between any two driveline components like an ordinary mechanical spacer. Damping is achieved using a ring-shaped piezoelectric stack that is poled in the axial direction and connected to an electrical shunt circuit. Surrounding the stack is a metal structure, called the compression cage, which squeezes the stack along its poled axis when excited by radial driveline forces. The stack in turn generates electrical energy, which is either dissipated or harvested using the shunt circuit. Removing energy from the system creates a net damping effect. The vibration ring is much stiffer than traditional damping devices, which allows it to be used in a driveline without disrupting normal operation. In phase 1 of this NASA Seedling Fund project, a combination of design and analysis was used to examine the feasibility of this concept. Several designs were evaluated using solid modeling, finite element analysis, and by creating prototype hardware. Then an analytical model representing the coupled electromechanical response was formulated in closed form. The model was exercised parametrically to examine the stiffness and loss factor spectra of the vibration ring, as well as simulate its damping effect in the context of a simplified driveline model. The results of this work showed that this is a viable mechanism for driveline damping, and provided several lessons for continued development.

  6. Adhesion rings surround invadopodia and promote maturation

    Directory of Open Access Journals (Sweden)

    Kevin M. Branch

    2012-06-01

    Invasion and metastasis are aggressive cancer phenotypes that are highly related to the ability of cancer cells to degrade extracellular matrix (ECM. At the cellular level, specialized actin-rich structures called invadopodia mediate focal matrix degradation by serving as exocytic sites for ECM-degrading proteinases. Adhesion signaling is likely to be a critical regulatory input to invadopodia, but the mechanism and location of such adhesion signaling events are poorly understood. Here, we report that adhesion rings surround invadopodia shortly after formation and correlate strongly with invadopodium activity on a cell-by-cell basis. By contrast, there was little correlation of focal adhesion number or size with cellular invadopodium activity. Prevention of adhesion ring formation by inhibition of RGD-binding integrins or knockdown (KD of integrin-linked kinase (ILK reduced the number of ECM-degrading invadopodia and reduced recruitment of IQGAP to invadopodium actin puncta. Furthermore, live cell imaging revealed that the rate of extracellular MT1-MMP accumulation at invadopodia was greatly reduced in both integrin-inhibited and ILK-KD cells. Conversely, KD of MT1-MMP reduced invadopodium activity and dynamics but not the number of adhesion-ringed invadopodia. These results suggest a model in which adhesion rings are recruited to invadopodia shortly after formation and promote invadopodium maturation by enhancing proteinase secretion. Since adhesion rings are a defining characteristic of podosomes, similar structures formed by normal cells, our data also suggest further similarities between invadopodia and podosomes.

  7. On Stellar Flash Echoes from Circular Rings

    Science.gov (United States)

    Nemiroff, Robert; Mukherjee, Oindabi

    2018-01-01

    A flash -- or any episode of variability -- that occurs in the vicinity of a circular ring might be seen several times later, simultaneously, as echoes on the ring. Effective images of the flash are created and annihilated in pairs, with as many as four flash images visible concurrently. Videos detailing sequences of image pair creation, tandem motion, and subsequent image annihilation are shown, given simple opacity and scattering assumptions. It is proven that, surprisingly, images from a second pair creation event always annihilate with images from the first. Caustic surfaces between flash locations yielding two and four images are computed. Although such ring echos surely occur, their practical detection might be difficult as it could require dedicated observing programs involving sensitive photometry of extended objects. Potential flash sources include planetary and interstellar gas and dust rings near and around variable stars, flare stars, novae, supernovae, and GRBs. Potentially recoverable information includes size, distance, temporal history, and angular isotropy of both the ring and flash.

  8. Sphagnum moss disperses spores with vortex rings.

    Science.gov (United States)

    Whitaker, Dwight L; Edwards, Joan

    2010-07-23

    Sphagnum spores, which have low terminal velocities, are carried by turbulent wind currents to establish colonies many kilometers away. However, spores that are easily kept aloft are also rapidly decelerated in still air; thus, dispersal range depends strongly on release height. Vascular plants grow tall to lift spores into sufficient wind currents for dispersal, but nonvascular plants such as Sphagnum cannot grow sufficiently high. High-speed videos show that exploding capsules of Sphagnum generate vortex rings to efficiently carry spores high enough to be dispersed by turbulent air currents. Spores launched ballistically at similar speeds through still air would travel a few millimeters and not easily reach turbulent air. Vortex rings are used by animals; here, we report vortex rings generated by plants.

  9. Algebraic coding theory over finite commutative rings

    CERN Document Server

    Dougherty, Steven T

    2017-01-01

    This book provides a self-contained introduction to algebraic coding theory over finite Frobenius rings. It is the first to offer a comprehensive account on the subject. Coding theory has its origins in the engineering problem of effective electronic communication where the alphabet is generally the binary field. Since its inception, it has grown as a branch of mathematics, and has since been expanded to consider any finite field, and later also Frobenius rings, as its alphabet. This book presents a broad view of the subject as a branch of pure mathematics and relates major results to other fields, including combinatorics, number theory and ring theory. Suitable for graduate students, the book will be of interest to anyone working in the field of coding theory, as well as algebraists and number theorists looking to apply coding theory to their own work.

  10. Numerical Simulation of Piston Ring Lubrication

    DEFF Research Database (Denmark)

    Felter, Christian Lotz

    2006-01-01

    and the angle between the normals of the solid and the free surface. The numerical model is compared with the results from an analytical solution of Reynolds equation for a fixed incline slider bearing. Then results from a more compli- cated simulation of piston ring lubrication is given and discussed.......This paper describes a numerical method that can be used to model the lubrication of piston rings. Classical lubrication theory is based on the Reynolds equation which is ap- plicable to confined geometries and open geometries where the flooding conditions are known. Lubrication of piston rings...... on solids and the equilibrium of stresses on the free surface. It is assumed that the surrounding gas phase has zero viscosity. Surface tension can be included in the model if necessary. The contact point where the three phases solid, liquid, and gas intersect is updated based on the velocity of the solid...

  11. Interferometric output coupling of ring optical oscillators.

    Science.gov (United States)

    Chaitanya Kumar, S; Esteban-Martin, A; Ebrahim-Zadeh, M

    2011-04-01

    We demonstrate the successful deployment of an antiresonant ring (ARR) interferometer within a ring optical resonator and its use for absolute optimization of output power. The integration of the ARR interferometer in a folded arm of the ring oscillator provides continuously variable output coupling over broad spectral range and under any operating conditions. We demonstrate the technique using a picosecond optical parametric oscillator (OPO), where we show continuously adjustable output coupling and optimization of the output power for different pump power conditions, from 3.5 W to 13.5 W. By operating the OPO under an optimized output coupling at 14 W of pump power, we obtain >5 W of extracted signal power, more than 2.6 times that with a ~5% conventional output coupler. We also show that the inclusion of the ARR interferometer has no detrimental effect on the spatial, temporal, and spectral characteristics of OPO output.

  12. Tree ring record chronicles major Mesoamerican droughts

    Science.gov (United States)

    Tretkoff, Ernie

    2011-05-01

    A new tree ring record chronicles major Mesoamerican droughts in the past millennium that may have contributed to the decline of some pre-Hispanic civilizations. Although there is other evidence of droughts during the past millennium, the paleoclimate record had gaps. Stahle et al. used core samples from Montezuma bald cypress trees found in Barranca de Amealco, Querétaro, Mexico, to develop a 1238-year tree ring chronology. They reconstructed the soil moisture record from the tree ring growth patterns. The new record provides the first dated, annually resolved climate record for Mexico and Central America spanning this time period.(Geophysical Research Letters, doi:10.1029/2010GL046472, 2011)

  13. Amplitude-modulated fiber-ring laser

    DEFF Research Database (Denmark)

    Caputo, J. G.; Clausen, Carl A. Balslev; Sørensen, Mads Peter

    2000-01-01

    Soliton pulses generated by a fiber-ring laser are investigated by numerical simulation and perturbation methods. The mathematical modeling is based on the nonlinear Schrödinger equation with perturbative terms. We show that active mode locking with an amplitude modulator leads to a self-starting......Soliton pulses generated by a fiber-ring laser are investigated by numerical simulation and perturbation methods. The mathematical modeling is based on the nonlinear Schrödinger equation with perturbative terms. We show that active mode locking with an amplitude modulator leads to a self......-starting of stable solitonic pulses from small random noise, provided the modulation depth is small. The perturbative analysis leads to a nonlinear coupled return map for the amplitude, phase, and position of the soliton pulses circulating in the fiber-ring laser. We established the validity of this approach...

  14. Antiproton chain of the FAIR storage rings

    International Nuclear Information System (INIS)

    Katayama, T; Kamerdzhiev, V; Lehrach, A; Maier, R; Prasuhn, D; Stassen, R; Stockhorst, H; Herfurth, F; Lestinsky, M; Litvinov, Yu A; Steck, M; Stöhlker, T

    2015-01-01

    In the Modularized Start Version of the Facility of Antiproton and Ion Research (FAIR) at Darmstadt Germany, the 3 GeV antiprotons are precooled in the collector ring and accumulated in the high energy storage ring (HESR). They are further accelerated to 14 GeV or decelerated to 1 GeV for the experiments with a high-density internal target. The powerful beam cooling devices, stochastic cooling and electron cooling will support the provision of a high-resolution antiproton beam. The other option of FAIR is to prepare the low energy, 300 keV antiproton beam connecting the existing storage rings ESR and CRYRING with HESR. Beam physics issues related with these concepts are described. (paper)

  15. Control System of the Small Isochronous ring

    Energy Technology Data Exchange (ETDEWEB)

    Felix Marti; Eduard Pozdeyev

    2004-07-01

    The purpose of this paper is to describe the control system of the Small Isochronous Ring (SIR) developed and built at the National Superconducting Cyclotron Laboratory (NSCL) at Michigan State University (MSU). SIR is a small-scale experiment that simulates the dynamics of intense beams in large accelerators. A 20 to 30 keV hydrogen or deuterium ion bunch is injected in the ring, extracted after a variable number of turns and its longitudinal profile is studied. Information about the electronics used and software written to control different injection line, ring and extraction line elements is included. Some of these elements are magnets, electrostatic quadrupoles, electric and magnetic correctors, scanning wires, emittance measurement system, chopper and a fast Faraday cup.

  16. Beam Diagnostics of the Small Isochronous Ring

    Energy Technology Data Exchange (ETDEWEB)

    Felix Marti; Eduard Pozdeyev

    2004-07-01

    The purpose of this paper is to describe the beam diagnostic systems in the Small Isochronous Ring (SIR) developed and built at the National Superconducting Cyclotron Laboratory (NSCL) at Michigan State University (MSU). SIR is a small-scale experiment that simulates the dynamics of intense beams in large accelerators. A 20 to 30 keV hydrogen or deuterium ion bunch is injected in the ring, extracted after a variable number of turns and its longitudinal profile is studied. Some of the diagnostic tools available in SIR include an emittance measurement system in the injection line, scanning wires in different sections of the ring, phosphor screens at the injection and extraction points and a fast Faraday cup in the extraction line. The design of these systems and the kind of beam information they provide are discussed in detail.

  17. Ion production and trapping in electron rings

    International Nuclear Information System (INIS)

    Gluckstern, R.C.; Ruggiero, A.G.

    1979-08-01

    The electron beam in the VUV and X-ray rings of NSLS will ionize residual gas by collisions. Positive ions will be produced with low velocity, and will be attracted by the electron beam to the beam axis. If they are trapped in stable (transverse) orbits, they may accumulate, thereby increasing the ν/sub x,z/ of the individual electrons. Since the accumulated ions are unlikely to be of uniform density, a spread in ν/sub x,z/ will also occur. Should these effects be serious, it may be necessary to introduce clearing electrodes, although this may increase Z/n in the rings, thereby adding to longitudinal instability problems. The seriousness of the above effect for the VUV and X-ray rings is estimated

  18. Nonlinear dynamics aspects of modern storage rings

    International Nuclear Information System (INIS)

    Helleman, R.H.G.; Kheifets, S.A.

    1986-01-01

    It is argued that the nonlinearity of storage rings becomes an essential problem as the design parameters of each new machine are pushed further and further. Yet the familiar methods of classical mechanics do not allow determination of single particle orbits over reasonable lengths of time. It is also argued that the single particle dynamics of a storage ring is possibly one of the cleanest and simplest nonlinear dynamical systems available with very few degrees of freedom. Hence, reasons are found for accelerator physicists to be interested in nonlinear dynamics and for researchers in nonlinear dynamics to be interested in modern storage rings. The more familiar methods of treating nonlinear systems routinely used in acclerator theory are discussed, pointing out some of their limitations and pitfalls. 39 refs., 1 fig

  19. PREFACE: Special section on vortex rings Special section on vortex rings

    Science.gov (United States)

    Fukumoto, Yasuhide

    2009-10-01

    This special section of Fluid Dynamics Research includes five articles on vortex rings in both classical and quantum fluids. The leading scientists of the field describe the trends in and the state-of-the-art development of experiments, theories and numerical simulations of vortex rings. The year 2008 was the 150th anniversary of 'vortex motion' since Hermann von Helmholtz opened up this field. In 1858, Helmholtz published a paper in Crelle's Journal which put forward the concept of 'vorticity' and made the first analysis of vortex motion. Fluid mechanics before that was limited to irrotational motion. In the absence of vorticity, the motion of an incompressible homogeneous fluid is virtually equivalent to a rigid-body motion in the sense that the fluid motion is determined once the boundary configuration is specified. Helmholtz proved, among other things, that, without viscosity, a vortex line is frozen into the fluid. This Helmholtz's law immediately implies the preservation of knots and links of vortex lines and its implication is enormous. One of the major trends of fluid mechanics since the latter half of the 20th century is to clarify the topological meaning of Helmholtz's law and to exploit it to develop theoretical and numerical methods to find the solutions of the Euler equations and to develop experimental techniques to gain an insight into fluid motion. Vortex rings are prominent coherent structures in a variety of fluid motions from the microscopic scale, through human and mesoscale to astrophysical scales, and have attracted people's interest. The late professor Philip G Saffman (1981) emphasized the significance of studies on vortex rings. One particular motion exemplifies the whole range of problems of vortex motion and is also a commonly known phenomenon, namely the vortex ring or smoke ring. Vortex rings are easily produced by dropping drops of one liquid into another, or by puffing fluid out of a hole, or by exhaling smoke if one has the skill

  20. The exotic exchange of smoke rings

    International Nuclear Information System (INIS)

    Niemi, Antti J.

    2006-01-01

    Smoke rings are fascinating, to humans and animals alike. Experienced cigarette smokers blow them for entertainment while dolphins play with air-filled underwater rings that know how to puff. Smoke ring machines can be bought from science gadget shops and Lord Kelvin explains in a paper [Lord Kelvin, Proceedings of the Royal Society of Edinburgh, Vol. VI (1867), p. 94; reprinted in Philos. Mag. Vol. XXXIV (1867), p. 15] how one can be constructed from a cardboard box. Even Mount Etna [http://news.bbc.co.uk/1/hi/sci/tech/696953.stm] and our Sun [http://spacescience.com/headlines/y2000/ast03feb 1 .htm] are known to be sources of huge smoke rings. But a smoke ring is not only fun to watch. It is also an organized structure with the ability to engage in complex acts, best exemplified by the leapfrogging motion of two smoke rings. Here we propose that the leapfrogging actually encodes very important Physics: It is a direct three dimensional generalization of the motion that in the two dimensional context is responsible for exotic exchange statistics which rules the properties of structures and materials such as quantum Hall systems and high-temperature superconductors. By employing very simple and universal concepts with roots in the hydrodynamical Euler equation, the universal law that describes the properties of fluids and gases, we argue that three dimensional exotic exchange statistics is commonplace. Our observations could have far reaching consequences in fluids and gases which are subject to the laws of quantum mechanics, from helium superfluids to Bose-Einstein condensed alkali gases and even metallic hydrogen in its liquid phases. (author)

  1. Dynamics of rings around elongated bodies

    Science.gov (United States)

    Sicardy, Bruno; Leiva, Rodrigo; Ortiz, Jose Luis; Santos Sanz, Pablo; Renner, Stefan; El Moutamid, Maryame; Berard, Diane; Desmars, Josselin; Meza, Erick; Rossi, Gustavo; Braga-Ribas, Felipe; Camargo, Julio; Vieira-Martins, Roberto; Morales, Nicolas; Duffard, Rene; Colas, Francois; Maquet, Lucie; Bouley, Sylvain; Bath, Karl-Ludwig; Beisker, Wolfgang; Dauverge, Jean-Luc; Kretlow, Mike; Chariklo Occultations Team; Haumea Occultation Team

    2017-10-01

    Dense and narrow rings are encountered around small bodies like the Centaur object Chariklo, and possibly Chiron. The rings and central bodies can be studied in great details thanks to stellar occultations, which accuracies at the km-level. Here we present new results from three high-quality occultations by Chariklo observed in 2017. They provide new insights on the ring geometry and Chariklo's shape. Data are currently being analyzed, but preliminary results are consistent with a triaxial model for Chariklo, with semi-axes a>b>c, where (a-b) may reach values as large as 10-15 km, depending on the model.Such large values induce a strong coupling between the body and an initial collisional debris disk from which the rings emerged. This coupling stems from Lindblad resonances between the ring particle mean motion and Chariklo's spin rate. We find that the resonances clear the corotation zone (estimated to lie at about 215 km from Chariklo's center) in very short time scales (centuries) and pushes the material well beyond the 3/2 resonance - that lies at an estimated radius of 280 km, thus consistent with the radius of Chariklo's main ring C1R, 390 km.Other cases will be examined in view of multi-chord stellar occultations by Trans-Neptunian Objects successfully observed in 2017, as they provide constraints for the presence of material around these bodies. Results and dynamical implications will be presented.Part of this work has received funding from the European Research Council under the European Community's H2020 2014-2020 ERC grant Agreement n°669416 "Lucky Star"

  2. Lateglacial environmental variability from Swiss tree rings

    DEFF Research Database (Denmark)

    Schaub, Matthias; Büntgen, Ulf; Kaiser, Klaus Felix

    2008-01-01

    Evidence of annually resolved environmental variations during the Allerød interstadial is presented using 81 fossil Scots pine tree-ring series from Gaenziloo and Landikon, near Zurich, Switzerland. The absolute age of the trees ranges between 11,920 and 10,610 14C BP, which was determined...... by wiggle-matching radiocarbon ages to the Cariaco 14C data set. From the two sites we created a composite floating Allerød chronology on the basis of their 632 years of overlap (r = 0.57), after individual spline detrending. Merging both data sets resulted in a Lateglacial tree-ring chronology covering...

  3. Prospect of polarized targets in electron rings

    International Nuclear Information System (INIS)

    Holt, R.J.

    1984-01-01

    The feasibility of performing electron scattering experiments with polarized targets in electron storage rings is discussed. Three examples of the physics which would be accessible with this novel method are given. It is noted that this new method is compatible with recent proposals for linac-stretcher-ring accelerator designs. A new method for producing a polarized hydrogen or deuterium target is proposed and some preliminary results are described. A brief summary of laser-driven polarized targets as well as conventionally-produced polarized atomic beams is included

  4. Ring vortex solitons in nonlocal nonlinear media

    DEFF Research Database (Denmark)

    Briedis, D.; Petersen, D.E.; Edmundson, D.

    2005-01-01

    We study the formation and propagation of two-dimensional vortex solitons, i.e. solitons with a phase singularity, in optical materials with a nonlocal focusing nonlinearity. We show that nonlocality stabilizes the dynamics of an otherwise unstable vortex beam. This occurs for either single...... or higher charge fundamental vortices as well as higher order (multiple ring) vortex solitons. Our results pave the way for experimental observation of stable vortex rings in other nonlocal nonlinear systems including Bose-Einstein condensates with pronounced long-range interparticle interaction....

  5. Polarization calculations for electron storage rings

    International Nuclear Information System (INIS)

    Mane, S.R.

    1988-05-01

    A computer program called SMILE has been developed to calculate the equilibrium polarization in a high-energy electron storage ring. It can calculate spin resonances to arbitrary orders, in principle. Results of polarization calculations are shown for a variety of storage ring models, to elucidate various aspects of the behaviour of the polarization, such as the effects of machine symmetry, beam energy spread, and transverse momentum recoils, etc. Reasonable agreement is obtained with some experimental data from measurements at SPEAR. 12 refs., 12 figs

  6. Socialt ansvarlig markedsføring

    DEFF Research Database (Denmark)

    Henschel, Rene Franz

    2008-01-01

    Samarbejde mellem juridiske froskere fra ASB, datalogiske forskere fra AAU samt den geostatiske virksomhed GEOMATIC skal sikre, at udviklingen af markedsføring til nye mobile teknologier sker på en etisk og socialt ansvarlig måde og ikke overskrider forbrugernes privatsfære.......Samarbejde mellem juridiske froskere fra ASB, datalogiske forskere fra AAU samt den geostatiske virksomhed GEOMATIC skal sikre, at udviklingen af markedsføring til nye mobile teknologier sker på en etisk og socialt ansvarlig måde og ikke overskrider forbrugernes privatsfære....

  7. Vortex rings and the solar granulation

    Science.gov (United States)

    Arendt, Steve

    1994-01-01

    Observations indicate that solar granules have the flow topology of updraft vortex loops. We interpret granule behavior in terms of the mutual and self-interactions of such loops. In particular, the expansion phase that granules commonly undergo is explained by the self-expansion of a vortex ring in a stratified fluid. For a range of granular parameters, we find that the expansion velocity of a vortex ring varies from 0.7 to 1.5 times the maximum surface flow velocity, in agreement with granule observations. We also present speculation on the nature of granule fragmentation.

  8. Computers in nonassociative rings and algebras

    CERN Document Server

    Beck, Robert E

    1977-01-01

    Computers in Nonassociative Rings and Algebras provides information pertinent to the computational aspects of nonassociative rings and algebras. This book describes the algorithmic approaches for solving problems using a computer.Organized into 10 chapters, this book begins with an overview of the concept of a symmetrized power of a group representation. This text then presents data structures and other computational methods that may be useful in the field of computational algebra. Other chapters consider several mathematical ideas, including identity processing in nonassociative algebras, str

  9. Asymmetric Laser Radiant Cooling in Storage Rings

    CERN Document Server

    Bulyak, E V; Zimmermann, F

    2011-01-01

    Laser pulses with small spatial and temporal dimensions can interact with a fraction of the electron bunches circulating in Compton storage rings. We studied synchrotron dynamics of such bunches when laser photons scatter off from the electrons with energy higher than the synchronous energy. In this case of ‘asymmetric cooling', as shown theoretically, the stationary energy spread is much smaller than under conditions of regular scattering; the oscillations are damped faster. Coherent oscillations of large amplitude may be damped in one synchrotron period, which makes this method feasible for injection the bunches into a ring in the longitudinal phase space. The theoretical results are validated with simulations.

  10. J-regular rings with injectivities

    OpenAIRE

    Shen, Liang

    2010-01-01

    A ring $R$ is called a J-regular ring if R/J(R) is von Neumann regular, where J(R) is the Jacobson radical of R. It is proved that if R is J-regular, then (i) R is right n-injective if and only if every homomorphism from an $n$-generated small right ideal of $R$ to $R_{R}$ can be extended to one from $R_{R}$ to $R_{R}$; (ii) R is right FP-injective if and only if R is right (J, R)-FP-injective. Some known results are improved.

  11. A new storage-ring light source

    Energy Technology Data Exchange (ETDEWEB)

    Chao, Alex [SLAC National Accelerator Lab., Menlo Park, CA (United States)

    2015-06-01

    A recently proposed technique in storage ring accelerators is applied to provide potential high-power sources of photon radiation. The technique is based on the steady-state microbunching (SSMB) mechanism. As examples of this application, one may consider a high-power DUV photon source for research in atomic and molecular physics or a high-power EUV radiation source for industrial lithography. A less challenging proof-of-principle test to produce IR radiation using an existing storage ring is also considered.

  12. Pure phase decoherence in a ring geometry

    International Nuclear Information System (INIS)

    Zhu, Z.; Aharony, A.; Entin-Wohlman, O.; Stamp, P. C. E.

    2010-01-01

    We study the dynamics of pure phase decoherence for a particle hopping around an N-site ring, coupled both to a spin bath and to an Aharonov-Bohm flux which threads the ring. Analytic results are found for the dynamics of the influence functional and of the reduced density matrix of the particle, both for initial single wave-packet states, and for states split initially into two separate wave packets moving at different velocities. We also give results for the dynamics of the current as a function of time.

  13. Cadmium Toxicity to Ringed Seals (Phoca hispida)

    DEFF Research Database (Denmark)

    Sonne, Christian; Dietz, R.; Riget, F. F.

    Cadmium concentrations in kidneys from ringed seals (Phoca hispida) from North West Greenland (Qaanaaq) are high. Concentrations range at level known to induce renal toxic effects (mainly tubulopathy) and demineralisation (osteopenia) of the skeletal system (Fanconi's Syndrome) in humans as well...... as laboratory mammals. We have studied possible cadmium induced histopathological changes in the kidneys as well as a demineralisation of the skeletal system (DXA-scanning of lumbal vertebraes). No obvious cadmium induced toxic changes were found. Food composition and physiological adaptations may explain...... the absence of toxic effects of cadmium in ringed seal...

  14. Rings Research in the Next Decade

    Science.gov (United States)

    Burns, J. A.; Tiscareno, M. S.

    2009-12-01

    The study of planetary ring systems forms a key component of planetary science for several reasons: 1) The evolution and current states of planets and their satellites are affected in many ways by rings, while 2) conversely, properties of planets and moons and other solar system populations are revealed by their effects on rings; 3) highly structured and apparently delicate ring systems may be bellwethers, constraining various theories of the origin and evolution of their entire planetary system; and finally, 4) planetary rings provide an easily observable analogue to other astrophysical disk systems, enabling real “ground truth” results applicable to disks much more remote in space and/or time, including proto-planetary disks, circum-stellar disks, and even galaxies. Significant advances have been made in rings science in the past decade. The highest-priority rings research recommendations of the last Planetary Science Decadal Survey were to operate and extend the Cassini orbiter mission at Saturn; this has been done with tremendous success, accounting for much of the progress made on key science questions, as we will describe. Important progress in understanding the rings of Saturn and other planets has also come from Earth-based observational and theoretical work, again as prioritized by the last Decadal Survey. However, much important work remains to be done. At Saturn, the Cassini Solstice Mission must be brought to a successful completion. Priority should also be placed on sending spacecraft to Neptune and/or Uranus, now unvisited for more than 20 years. At Jupiter and Pluto, opportunities afforded by visiting spacecraft capable of studying rings should be exploited. On Earth, the need for continued research and analysis remains strong, including in-depth analysis of rings data already obtained, numerical and theoretical modeling work, laboratory analysis of materials and processes analogous to those found in the outer solar system, and continued Earth

  15. Mitral annuloplasty ring suture forces: Impact of surgeon, ring, and use conditions.

    Science.gov (United States)

    Pierce, Eric L; Bloodworth, Charles H; Siefert, Andrew W; Easley, Thomas F; Takayama, Tetsushi; Kawamura, Tomonori; Gorman, Robert C; Gorman, Joseph H; Yoganathan, Ajit P

    2018-01-01

    The study objective was to quantify the effect of ring type, ring-annulus sizing, suture position, and surgeon on the forces required to tie down and constrain a mitral annuloplasty ring to a beating heart. Physio (Edwards Lifesciences, Irvine, Calif) or Profile 3D (Medtronic, Dublin, Ireland) annuloplasty rings were instrumented with suture force transducers and implanted in ovine subjects (N = 23). Tie-down forces and cyclic contractile forces were recorded and analyzed at 10 suture positions and at 3 levels of increasing peak left ventricular pressure. Across all conditions, tie-down force was 2.7 ± 1.4 N and cyclic contractile force was 2.0 ± 1.2 N. Tie-down force was not meaningfully affected by any factor except surgeon. Significant differences in overall and individual tie-down forces were observed between the 2 primary implanting surgeons. No other factors were observed to significantly affect tie-down force. Contractile suture forces were significantly reduced by ring-annulus true sizing. This was driven almost exclusively by Physio cases and by reduction along the anterior aspect, where dehiscence is less common clinically. Contractile suture forces did not differ significantly between ring types. However, when undersizing, Profile 3D forces were significantly more uniform around the annular circumference. A suture's tie-down force did not correlate to its eventual contractile force. Mitral annuloplasty suture loading is influenced by ring type, ring-annulus sizing, suture position, and surgeon, suggesting that reports of dehiscence may not be merely a series of isolated errors. When compared with forces known to cause suture dehiscence, these in vivo suture loading data aid in establishing potential targets for reducing the occurrence of ring dehiscence. Copyright © 2017 The American Association for Thoracic Surgery. Published by Elsevier Inc. All rights reserved.

  16. Basin-ring spacing on the Moon, Mercury, and Mars

    Science.gov (United States)

    Pike, R.J.; Spudis, P.D.

    1987-01-01

    Radial spacing between concentric rings of impact basins that lack central peaks is statistically similar and nonrandom on the Moon, Mercury, and Mars, both inside and outside the main ring. One spacing interval, (2.0 ?? 0.3)0.5D, or an integer multiple of it, dominates most basin rings. Three analytical approaches yield similar results from 296 remapped or newly mapped rings of 67 multi-ringed basins: least-squares of rank-grouped rings, least-squares of rank and ring diameter for each basin, and averaged ratios of adjacent rings. Analysis of 106 rings of 53 two-ring basins by the first and third methods yields an integer multiple (2 ??) of 2.00.5D. There are two exceptions: (1) Rings adjacent to the main ring of multi-ring basins are consistently spaced at a slightly, but significantly, larger interval, (2.1 ?? 0.3)0.5D; (2) The 88 rings of 44 protobasins (large peak-plus-inner-ring craters) are spaced at an entirely different interval (3.3 ?? 0.6)0.5D. The statistically constant and target-invariant spacing of so many rings suggests that this characteristic may constrain formational models of impact basins on the terrestrial planets. The key elements of such a constraint include: (1) ring positions may not have been located by the same process(es) that formed ring topography; (2) ring location and emplacement of ring topography need not be coeval; (3) ring location, but not necessarily the mode of ring emplacement, reflects one process that operated at the time of impact; and (4) the process yields similarly-disposed topographic features that are spatially discrete at 20.5D intervals, or some multiple, rather than continuous. These four elements suggest that some type of wave mechanism dominates the location, but not necessarily the formation, of basin rings. The waves may be standing, rather than travelling. The ring topography itself may be emplaced at impact by this and/or other mechanisms and may reflect additional, including post-impact, influences. ?? 1987

  17. Single patent vessel over an embedded ring: a case report.

    Science.gov (United States)

    Awan, Bassim; Samargandi, Osama A; Aljaaly, Hattan A; Makhdom, Asim M

    2013-01-01

    Embedded ring injury is rarely encountered in clinical practice, and most of the few reported cases share common features, including deliberate neglect, mental illness, poor social support, female gender, and adult age group. Ischemia has never been reported in such injuries. Here, we report the case of a 16-year-old girl who presented with a completely embedded ring in the right index finger and a partially embedded ring in the left ring finger. Revascularization after ring embedment probably explains the intact vessel that was observed on the outer aspect of the embedded ring during surgical exploration of the right index finger.

  18. Ring cavity for a Raman capillary waveguide amplifier

    Science.gov (United States)

    Kurnit, N.A.

    1981-01-27

    A regenerative ring amplifier and regenerative ring oscillator are described which function to feed back a portion of the Stokes signal to complete the ring cavity. The ring cavity configuration allows the CO/sub 2/ laser pump signal and Stokes signal to copropagate through the Raman capillary waveguide amplifier. A Raman capillary waveguide amplifier is also provided in the return leg of the ring cavity to increase gain without increasing the round trip time. Additionally, the ring cavity can be designed such that the amplified Stokes signal is synchronous with the mode-locked spikes of the incoming CO/sub 2/ laser pump signal.

  19. Ring cavity for a Raman capillary waveguide amplifir

    Science.gov (United States)

    Kurnit, N.A.

    1981-01-27

    A regenerative ring amplifier and regenerative ring oscillator are described which function to feed back a portion of the Stokes signal to complete the ring cavity. The ring cavity configuration allows the CO/sub 2/ laser pump signal and Stokes signal to copropagate through the Raman capillary waveguide amplifier. A Raman capillary waveguide amplifier is also provided in the return leg of the ring cavity to increase gain without increasing the round trip time. Additionally, the ring cavity can be designed such that the amplified Stokes signal is synchronous with the mode-locked spikes of the incoming CO/sub 2/ laser pump signal.

  20. Rings with finite Gorenstein injective dimension

    DEFF Research Database (Denmark)

    Holm, Henrik Granau

    2004-01-01

    In this paper we prove that for any associative ring R, and for any left R-module M with nite projective dimension, the Gorenstein injective dimension GidRM equals the usual injective dimension idRM. In particular, if GidRR is nite, then also idRR is nite, and thus R is Gorenstein (provided that ...

  1. Antiprotons in the CERN intersecting storage rings

    International Nuclear Information System (INIS)

    Bryant, P.J.

    1984-01-01

    High-sensitivity electronics for TTl and ring 2 had been developed and installed, the original experimental stochastic cooling systems in the ISR were rebuilt and considerably improved, the split-field magnet (SFM) vacuum chamber was modified, some steering dipoles were designed, made and installed, and finally innumerable interlocks and computer programs were revised for antiproton operation. (orig./HSI)

  2. Inauguration ceremony for the Intersecting Storage Rings

    CERN Multimedia

    CERN PhotoLab

    1971-01-01

    The inauguration ceremony for the Intersecting Storage Rings (ISR) was held on 16 October 1971. Kjell Johnsen is seen in the picture handing a symbolic key to the ISR to Edoardo Amaldi. From left to right on the podium: Victor Frederik Weisskopf, former Director-General; M Antonioz; Willibald Jentschke as Director-General of CERN, and on the other side Werner Heisenberg.

  3. Volumes and surface areas of pendular rings

    Science.gov (United States)

    Rose, W.

    1958-01-01

    A packing of spheres is taken as a suitable model of porous media. The packing may be regular and the sphere size may be uniform, but in general, both should be random. Approximations are developed to give the volumes and surface areas of pendular rings that exist at points of sphere contact. From these, the total free volume and interfacial specific surface area are derived as expressive of the textural character of the packing. It was found that the log-log plot of volumes and surface areas of pendular rings vary linearly with the angle made by the line joining the sphere centers and the line from the center of the largest sphere to the closest edge of the pendular ring. The relationship, moreover, was found not to be very sensitive to variation in the size ratio of the spheres in contact. It also was found that the addition of pendular ring material to various sphere packings results in an unexpected decrease in the surface area of the boundaries that confine the resulting pore space. ?? 1958 The American Institute of Physics.

  4. Miniaturized Planar Split-Ring Resonator Antenna

    DEFF Research Database (Denmark)

    Kim, Oleksiy S.; Breinbjerg, Olav

    2009-01-01

    A miniaturized planar antenna based on a broadside-coupled split ring resonator excited by an arc-shaped dipole is presented. The excitation dipole acts as a small tuning capacitor in series with a parallel RLC circuit represented by the SRR. The antenna resonance frequency and dimensions...

  5. DIE RING In diens van onderlinge sorg

    African Journals Online (AJOL)

    kerk (Spoelstra 1989:248). Wanneer gemeentes in kerkverband met mekaar tree, en as 'n eerste uitdrukking hiervan in ringsverband vergader (in hulle eie omgewing), is dit in gehoorsaamheid aan hulle God se opdrag. Die ring het dus opsig self reeds 'n getuienisfunksie en mag daarom nie opsioneel raak nie. 8. DIE WEG ...

  6. Kac's ring: The case of four colours

    Indian Academy of Sciences (India)

    2017-03-15

    Mar 15, 2017 ... Abstract. We present an instance from nonequilibrium statistical mechanics which combines increase in entropy and finite Poincaré recurrence time. The model we consider is a variation of the well-known Kac's ring where we consider balls of four colours. As is known, Kac introduced this model where balls ...

  7. Cherenkov ring imaging using a television digitizer

    International Nuclear Information System (INIS)

    Charpak, G.; Peisert, A.; Sauli, F.; Cavestro, A.; Vascon, M.; Zanella, G.

    1981-01-01

    A Cherenkov ring imaging device using as photon detector a multistep spark chamber coupled to a television digitizer is described. Results of a test run using triethylamine as photo-ionizing vapour are presented, as well as preliminary results obtained with a new vapour having an extremely low ionization potential. (orig.)

  8. Almagest, a new trackless ring finding algorithm

    International Nuclear Information System (INIS)

    Lamanna, G.

    2014-01-01

    A fast ring finding algorithm is a crucial point to allow the use of RICH in on-line trigger selection. The present algorithms are either too slow (with respect to the incoming data rate) or need the information coming from a tracking system. Digital image techniques, assuming limited computing power (as for example Hough transform), are not perfectly robust for what concerns the noise immunity. We present a novel technique based on Ptolemy's theorem for multi-ring pattern recognition. Starting from purely geometrical considerations, this algorithm (also known as “Almagest”) allows fast and trackless rings reconstruction, with spatial resolution comparable with other offline techniques. Almagest is particularly suitable for parallel implementation on multi-cores machines. Preliminary tests on GPUs (multi-cores video card processors) show that, thanks to an execution time smaller than 10 μs per event, this algorithm could be employed for on-line selection in trigger systems. The user case of the NA62 RICH trigger, based on GPU, will be discussed. - Highlights: • A new algorithm for fast multiple ring searching in RICH detectors is presented. • The Almagest algorithm exploits the computing power of Graphics processers (GPUs). • A preliminary implementation for on-line triggering in the NA62 experiment shows encouraging results

  9. Vibration of Elastic Functionally Graded Thick Rings

    Directory of Open Access Journals (Sweden)

    Guang-Hui Xu

    2017-01-01

    Full Text Available The free vibration behaviors of functionally graded rings were investigated theoretically. The material graded in the thickness direction according to the power law rule and the rings were assumed to be in plane stress and plane strain states. Based on the first-order shear deformation theory and the kinetic relation of von Kárman type, the frequency equation for free vibration of functionally graded ring was derived. The derived results were verified by those in literatures which reveals that the present theory can be appropriate to predict the free vibration characteristics for quite thick rings with the radius-to-thickness ratio from 60 down to 2.09. Comparison between the plane stress case and the plane strain case indicates a slight difference. Meanwhile, the effects of the structural dimensional parameters and the material inhomogeneous parameter are examined. It is interesting that the value of the logarithmic form of vibration frequency is inversely proportional to the logarithmic form of the radius-to-thickness ratio or the mean radius.

  10. The Fluxgate Ring-Core Internal Field

    DEFF Research Database (Denmark)

    Primdahl, Fritz; Brauer, Peter; Merayo, José M.G.

    2002-01-01

    A large number of measured demagnetizing factors for fluxgate ring cores of a wide range of cross section shapes have been compiled from the literature and plotted against the core cross-sectional area over the squared mean core diameter. The points group close to a straight line through the orig...

  11. Genetics Home Reference: ring chromosome 14 syndrome

    Science.gov (United States)

    ... learning problems. Development may be delayed, particularly the development of speech and of motor skills such as sitting, standing, and walking. Additional features of ring chromosome 14 syndrome can include slow growth and short stature, a small head ( microcephaly ), puffy hands and/or feet caused ...

  12. Krop, rum, læring

    DEFF Research Database (Denmark)

    Justiniano, Birgitte

    2009-01-01

    Ud fra afprøvning af forskellige somaæstetiske iscenesættelser i skolen beskæftiger artiklen sig med koblinger mellem kroppen, det fysiske rum, læring og sundhed. Jeg argumenterer for, at kombinationen af skolens kulturindhold, det faktuelle indhold i undervisningen samt det arkitektoniske og per...

  13. Kac's ring: The case of four colours

    Indian Academy of Sciences (India)

    We present an instance from nonequilibrium statistical mechanics which combines increase in entropy and finite Poincaré recurrence time. The model we consider is a variation of the well-known Kac's ring where we consider balls of four colours. As is known, Kac introduced this model where balls arranged between lattice ...

  14. Electron Storage Ring Development for ICS Sources

    Energy Technology Data Exchange (ETDEWEB)

    Loewen, Roderick [Lyncean Technologies, Inc., Palo Alto, CA (United States)

    2015-09-30

    There is an increasing world-wide interest in compact light sources based on Inverse Compton Scattering. Development of these types of light sources includes leveraging the investment in accelerator technology first developed at DOE National Laboratories. Although these types of light sources cannot replace the larger user-supported synchrotron facilities, they offer attractive alternatives for many x-ray science applications. Fundamental research at the SLAC National Laboratory in the 1990’s led to the idea of using laser-electron storage rings as a mechanism to generate x-rays with many properties of the larger synchrotron light facilities. This research led to a commercial spin-off of this technology. The SBIR project goal is to understand and improve the performance of the electron storage ring system of the commercially available Compact Light Source. The knowledge gained from studying a low-energy electron storage ring may also benefit other Inverse Compton Scattering (ICS) source development. Better electron storage ring performance is one of the key technologies necessary to extend the utility and breadth of applications of the CLS or related ICS sources. This grant includes a subcontract with SLAC for technical personnel and resources for modeling, feedback development, and related accelerator physics studies.

  15. Guide to the Main Ring DO overpass

    International Nuclear Information System (INIS)

    Turkot, F.

    1985-01-01

    The DO overpass is a modification of the beam orbit in Main Ring in order to better accommodate a Tevatron collider detector at DO. The orbit is moved up approx. 51 inches over most of the long straight section at DO, thus making the Main Ring the world's first non-planar proton synchrotron. A similar overpass, but with four times the displacement, is planned for the CDF detector at the BO straight section. The nominal separation between the beam orbit in the Main Ring and the orbit in the Tevatron is 25.5 inches. Early in the design study of a detector that would utilize the Tevatron is a anti pp collider, it was apparent that a larger separation at the detector was highly desirable. In 1981, Tom Collins proposed a specific lattice geometry in the Main Ring for achieving larger separation, called ''the screw beam''. His proposal has served as the basis for the design of both the BO and DO overpasses. The main purpose of this report is to describe in some detail the implementation of the DO overpass. Topics to be covered include: (a) geometry of the overpass orbit, (b) the new hardware in the tunnel, (c) the power supply system, (d) the control facility, (e) accelerator beam dynamics ramifications, and (f) commissioning experience. A secondary purpose is to provide a fairly complete ''bibliography'' to the sources of information on the overpass. 17 refs., 17 figs

  16. Aktionslæring, forskning og forandring

    DEFF Research Database (Denmark)

    Broström, Stig

    2018-01-01

    En kritisk kommentar til 'Laboratoriemodellen' udarbejdet af Claus Michelsen, Linda Ahrenkiel og Morten Rask Petersen, alle fra Laboratorium for Sammenhængende Uddannelse og Læring, Syddansk Universitet. Modellen er et værktøj til kompetenceudvikling af naturfagsundervisere – Laboratoriemodellen ...

  17. Projective Ring Line Encompassing Two-Qubits

    Czech Academy of Sciences Publication Activity Database

    Saniga, M.; Planat, M.; Pracna, Petr

    2008-01-01

    Roč. 155, č. 3 (2008), s. 905-913 ISSN 0040-5779 R&D Projects: GA AV ČR 1ET400400410 Institutional research plan: CEZ:AV0Z40400503 Keywords : two-qubits * projective ring line * generalized quadrangle of order two Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 0.721, year: 2008

  18. Revisiting stability of pickup ion rings

    Science.gov (United States)

    Florinski, V. A.; Niemiec, J.; Heerikhuisen, J.

    2015-12-01

    Do we really understand ring distribution stability in weakly turbulent plasmas? The first measurement of the interstellar magnetic fluctuation spectrum by Voyager 1 was consistent with interstellar Kolmogorov turbulence spectrum, ruling out any significant local wave sources, such as an instability. We show that both linear dispersion analysis and kinetic plasma computer simulations should be approached with much caution when drawing conclusions about the wave generation and resulting particle scattering in pitch angle, especially for very tenuous rings. Using hybrid-kinetic and PIC models we carefully examine the nonlinear phase of pickup ion (PUI) scattering on self-generated fluctuations to reveal a critical dependence on the number of pseudo-particles present in the simulation. It is shown that narrow rings modeled with very high number of particles (1 million per cell) could become stable in the nonlinear phase. The second part of this presentation deals with more realistic pickup rings derived from the distribution of primary energetic neutral atoms (ENAs) originating in the solar wind and the inner heliosheath. The width of these distributions allow them to remain stable on the timescales of at least a few months. These results lend additional support to the secondary PUI theory of the origin of the IBEX ribbon.

  19. Computerspil og læring

    Directory of Open Access Journals (Sweden)

    Lasse Juel Larsen

    2015-02-01

    Full Text Available Game-based learning og gamification er ord, der ofte optræder i forbindelse med computerspil og læring. Denne artikel vil analytisk undersøge, hvordan computerspil og læring går i forbindelse med hinanden. Artikel tager afsæt i Gregory Batesons læringsteori og læser denne igennem det kommercielle computerspil StarCraft 2 fra Blizzard Intertainment. Batesons læringsteori vil ikke alene blive gennemgået, men også udvidet og perspektiveret.  Formålet med denne indsats er at skabe et afsæt, der kan demonstrere, hvordan læring foregår i computerspil. Herefter vil afsættet blive anvendt til at destillere et læringsteoretisk udkast. Artiklen falder således i to dele, hvor den første analytisk adresserer, hvordan læring i computerspil foregår, mens den anden er teoriproducerende på baggrund af resultaterne fra første del.

  20. Maximally differential ideals in regular local rings

    Indian Academy of Sciences (India)

    may either be maximally differential under a set of derivations or a set of higher derivations,. i.e, Hasse–Schmidt derivations. We also extend our result (Theorem 4 of [7]) about the structure of a maximally differ- ential ideal in positive characteristic to unequal characteristic case. 2. Results. By a ring we mean a commutative ...

  1. Bosonic and fermionic dipoles on a ring

    DEFF Research Database (Denmark)

    Zöllner, Sascha; Pethick, C. J.; Bruun, Georg Morten

    2011-01-01

    We show that dipolar bosons and fermions confined in a quasi-one-dimensional ring trap exhibit a rich variety of states because their interaction is inhomogeneous. For purely repulsive interactions, with increasing strength of the dipolar coupling there is a crossover from a gaslike state...

  2. Heptaphyrins: Expanded porphyrins with seven heterocyclic rings

    Indian Academy of Sciences (India)

    Unknown

    ring inversion. 1. Introduction. The syntheses of expanded porphyrins continue to attract the attention of chemists because of their diverse biological applications such as: anion receptors, photosensitizing agents, MRI contrast agents1 etc. They are also of interest, theoretically, to study the fundamental property of aromaticity ...

  3. From accelerators to storage rings to

    International Nuclear Information System (INIS)

    Panofsky, W.K.H.

    1983-02-01

    This talk gives a general but highly subjective overview of the expectation for accelerators and colliders for high energy physics, but not extended developments of accelerators and storage rings for application to nuclear structure physics, synchrotron radiation, medical applications or industrial use

  4. DIE RING In diens van onderlinge sorg

    African Journals Online (AJOL)

    die kerk waarin die sogenaamde postmoderne Christen homself tuis sal voel, word gewys op die feit dat hulle 'n wars het aan enige vorm van hiërargie of dwang van bo (Niemandt 2008:140, 160). Verhoudings, netwerke en plat strukture is binne hierdie kerkbegrip die aangewese weg. In gereformeerde denke ís die ring ...

  5. Leg og læring

    DEFF Research Database (Denmark)

    Pedersen, Annette

    2008-01-01

    Leg synes at have et potentiale som metode til at fremme læring. Men hvordan? Legen har en vis grad af parallelitet med den virkelige verden i dens interaktive og relationelle strukturer. Det bliver muligt at finde nye meninger i interaktioner, som refererer til vante interaktionsformer, men...

  6. An intensive tree-ring experience

    NARCIS (Netherlands)

    Sánchez-Salguero, Raúl; Hevia, Andrea; Camarero, J.J.; Treydte, Kerstin; Frank, Dave; Crivellaro, Alan; Domínguez-Delmás, Marta; Hellman, Lena; Kaczka, Ryszard J.; Kaye, Margot; Akhmetzyanov, Linar; Ashiq, Muhammad Waseem; Bhuyan, Upasana; Bondarenko, Olesia; Camisón, Álvaro; Camps, Sien; García, Vicenta Constante; Vaz, Filipe Costa; Gavrila, Ionela G.; Gulbranson, Erik; Huhtamaa, Heli; Janecka, Karolina; Jeffers, Darren; Jochner, Matthias; Koutecký, Tomáš; Lamrani-Alaoui, Mostafa; Lebreton-Anberrée, Julie; Seijo, María Martín; Matulewski, Pawel; Metslaid, Sandra; Miron, Sergiu; Morrisey, Robert; Opdebeeck, Jorgen; Ovchinnikov, Svyatoslav; Peters, Richard; Petritan, Any M.; Popkova, Margarita; Rehorkova, Stepanka; Ariza, María O.R.; Sánchez-Miranda, Ángela; Linden, Van der Marjolein; Vannoppen, Astrid; Volařík, Daniel

    2017-01-01

    The European Dendroecologial Fieldweek (EDF) provides an intensive learning experience in tree-ring research that challenges any participant to explore new multidisciplinary dendro-sciences approaches within the context of field and laboratory settings. Here we present the 25th EDF, held in

  7. Synthesis of azaphenanthridines via anionic ring closure

    DEFF Research Database (Denmark)

    Hansen, Henriette Møller; Lysén, M.; Begtrup, M.

    2005-01-01

    A new and convergent synthesis of azaphenanthridines via an anionic ring closure is reported. Ortho-lithiation/in situ borylation of cyanopyridines produces the corresponding cyanopyridylboronic esters, which undergo a Suzuki-Miyaura cross-coupling to give the key intermediates. Addition of lithium...

  8. Elevers læring og udvikling

    DEFF Research Database (Denmark)

    Skibsted, Else Bengaard; Løw, Ole

    Bogen giver lærerstuderende og lærere psykologisk indsigt i læreruddannelsens kompetenceområder 'Elevens læring og udvikling' & 'Specialpædagogik'. Bogen er skrevet af forskere og undervisere, der alle har en forskningsbaseret og empirisk tilgang til studiet af lærerarbejdet...

  9. Almagest, a new trackless ring finding algorithm

    Energy Technology Data Exchange (ETDEWEB)

    Lamanna, G., E-mail: gianluca.lamanna@cern.ch

    2014-12-01

    A fast ring finding algorithm is a crucial point to allow the use of RICH in on-line trigger selection. The present algorithms are either too slow (with respect to the incoming data rate) or need the information coming from a tracking system. Digital image techniques, assuming limited computing power (as for example Hough transform), are not perfectly robust for what concerns the noise immunity. We present a novel technique based on Ptolemy's theorem for multi-ring pattern recognition. Starting from purely geometrical considerations, this algorithm (also known as “Almagest”) allows fast and trackless rings reconstruction, with spatial resolution comparable with other offline techniques. Almagest is particularly suitable for parallel implementation on multi-cores machines. Preliminary tests on GPUs (multi-cores video card processors) show that, thanks to an execution time smaller than 10 μs per event, this algorithm could be employed for on-line selection in trigger systems. The user case of the NA62 RICH trigger, based on GPU, will be discussed. - Highlights: • A new algorithm for fast multiple ring searching in RICH detectors is presented. • The Almagest algorithm exploits the computing power of Graphics processers (GPUs). • A preliminary implementation for on-line triggering in the NA62 experiment shows encouraging results.

  10. Ring Chromosome 7 in an Indian Woman

    Science.gov (United States)

    Kaur, Anupam; Dhillon, Sumit; Garg, P. D.; Singh, Jai Rup

    2008-01-01

    Background: Ring chromosome 7 [r(7)] is a rare cytogenetic aberration, with only 16 cases (including 3 females) reported in the literature to date. This is the first reported case of r(7) from India. Method: Clinical and cytogenetic investigations were carried out in an adult female with microcephaly and intellectual disability. Results: Ring…

  11. Experimental results from the small isochronous ring

    Energy Technology Data Exchange (ETDEWEB)

    Eduard Pozdeyev

    2005-05-01

    The Small Isochronous Ring (SIR) is a compact, low-energy storage ring designed to investigate the beam dynamics of high-intensity isochronous cyclotrons and synchrotrons at the transition energy. The ring was developed at Michigan State University (MSU) and has been operational since December 2003. It stores 20 keV hydrogen beams with a peak current of 10-20 microamps for up to 200 turns. The transverse and longitudinal profiles of extracted bunches are measured with an accuracy of approximately 1 mm. The high accuracy of the measurements makes the experimental data attractive for validation of multi-particle space charge codes. The results obtained in the ring show a fast growth of the energy spread induced by the space charge forces. The energy spread growth is accompanied by a breakup of the beam bunches into separated clusters that are involved in the vortex motion specific to the isochronous regime. The experimental results presented in the paper show a remarkable agreement with simulations performed with the code CYCO. In this paper, we discuss specifics of space charge effects in the isochronous regime, present results of experiments in SIR, and conduct a detailed comparison of the experimental data with results of simulations.

  12. Unraveling the strands of Saturn's F ring

    Science.gov (United States)

    Murray, C.D.; Gordon, M.K.; Giuliatti, Winter S.M.

    1997-01-01

    Several high-resolution Voyager 2 images of Saturn's F ring show that it is composed of at least four separate, non-intersecting strands extending ~45?? in longitude. Voyager 1 images show that the two brightest strands appear to intersect, giving rise to a "braided" morphology. From a study of all available Voyager images the detectable radial structure is cataloged and reviewed. Previous indications that there is fine material interior to the orbit of the F ring are confirmed. Evidence is presented that a model of four strands with comparable eccentricities and nearly aligned perichrones is consistent with all the Voyager observations. The observed perichrone offset of the two brightest strands suggests a minimum radial separation of ~20 km, which implies intersection of these strands when their finite radial widths are taken into account. The longitude range of such an intersection includes that observed in the Voyager 1 "braid" images. The proximity of these two strands at some longitudes may account for the apparent differences in the ring between the Voyager encounters, as well as provide a source for the short-lived features detected in the Hubble Space Telescope images of the F ring. There is no evidence that the locations of the individual strands are determined by resonant perturbations with known satellites. It is proposed that the radial structure is formed by the localized action of small satellites orbiting within the strand region. ?? 1997 Academic Press.

  13. Elastic ring deformation and pedestal contact status analysis of elastic ring squeeze film damper

    Science.gov (United States)

    Zhang, Wei; Ding, Qian

    2015-06-01

    This paper investigates the dynamic parametric characteristic of the elastic ring squeeze film damper (ERSFD). Firstly, the coupled oil film Reynolds equations and dynamic equations of an ERSFD supported rotor system are established. The finite differential method and numerical simulation are used to analyze the oil film pressure distribution, bearing capacity of ERSFD, oil film stiffness and damping characteristics during a vibration period. Then, based on the oil film pressure results, the deformation of elastic ring is revealed by the finite element method. Finally, pedestal contact status is analyzed according to the change of oil film thickness during a vibration period. The results reveal that the oil film pressure is sectionally continuous, the deformation of elastic ring is complex under the compression of inner and outer oil film, and different pedestal contacts occur in a vibration period. The level of nonlinearity of the bearing capacity, oil film stiffness and damping can be effectively lightened by application of the elastic ring.

  14. Seco-B-Ring Steroidal Dienynes with Aromatic D Ring: Design, Synthesis and Biological Evaluation

    Directory of Open Access Journals (Sweden)

    Marcin Szybinski

    2017-10-01

    Full Text Available Continuing our structure-activity studies on the vitamin D analogs with the altered intercyclic seco-B-ring fragment, we designed compounds possessing dienyne system conjugated with the benzene D ring. Analysis of the literature data and the docking experiments seemed to indicate that the target compounds could mimic the ligands with a good affinity to the vitamin D receptor (VDR. Multi-step synthesis of the C/D-ring building block of the tetralone structure was achieved and its enol triflate was coupled with the known A-ring fragments, possessing conjugated enyne moiety, using Sonogashira protocol. The structures of the final products were confirmed by NMR, UV and mass spectroscopy. Their binding affinities for the full-length human VDR were determined and it was established that compound substituted at C-2 with exomethylene group showed significant binding to the receptor. This analog was also able to induce monocytic differentiation of HL-60 cells.

  15. Synthesis of novel spiro-β-lactams

    Indian Academy of Sciences (India)

    Administrator

    Since β-lactam antibiotics are a group of drugs of unparallel importance in chemotherapy, consider- able efforts have been made in the development of novel and biologically more active compounds. The search for improved antibiotics also includes design- ing of new methodology for the total synthesis as well as the ...

  16. SBA-15 Immobilized Ruthenium Carbenes as Catalysts for Ring Closing Metathesis and Ring Opening Metathesis Polymerization

    Czech Academy of Sciences Publication Activity Database

    Bek, David; Žilková, Naděžda; Dědeček, Jiří; Sedláček, J.; Balcar, Hynek

    2010-01-01

    Roč. 53, 3-4 (2010), s. 200-209 ISSN 1022-5528 R&D Projects: GA AV ČR IAA400400805; GA AV ČR KAN100400701 Institutional research plan: CEZ:AV0Z40400503 Keywords : ring closing metathesis * ring opening metathesis polymerization * hybrid catalysts Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 2.359, year: 2010

  17. The contraceptive vaginal ring, NuvaRing(®), a decade after its introduction.

    Science.gov (United States)

    Roumen, Frans J M E; Mishell, Daniel R

    2012-12-01

    To review the clinical experience with the contraceptive vaginal ring (CVR, NuvaRing(®)) since its introduction over ten years ago. The literature was searched on efficacy, cycle control, safety, user preference and satisfaction of the CVR in comparison with combined oral contraceptives (COCs) and the patch, with special attention to recent developments. The ring has the same working mechanism and contraindications as COCs. Serum levels of steroids are steadier, whereas oestrogenic exposure is lower. Contraceptive efficacy is similar, as are metabolic changes. Cycle control is better, and compliance and continuation rates are equal or higher. Oestrogen-related adverse symptoms appear to be fewer, but reports on the incidence of venous thrombosis are conflicting. Expulsion of the ring is reported by 4% to 20% of women. Local adverse events are the main reason for discontinuation. Acceptability is as high as with COCs and, after structured counselling, the ring is preferred by many women to the pill or the patch. Efficacy of the CVR, and the metabolic changes and adverse events it elicits, are generally comparable to those of COCs, yet oestrogenic exposure is lower and cycle control superior. After counselling, the ring is preferred to the pill by many women.

  18. Applications of Soft Union Sets in the Ring Theory

    Directory of Open Access Journals (Sweden)

    Yongwei Yang

    2013-01-01

    through discussing quotient soft subsets, an approach for constructing quotient soft union rings is made. Finally, isomorphism theorems of λ,μ-soft union rings related to invariant soft sets are discussed.

  19. Optical vortex patterns in a unidirectional ring oscillator

    DEFF Research Database (Denmark)

    Mamaev, A.V.; Saffman, M.

    1996-01-01

    We describe observation and analysis of optical vortex patterns in a unidirectional ring oscillator with photorefractive nonlinearity. Including field rotation in the resonator leads to novel structures, including counterrotating rings of optical vortices with opposite helicity. A modal analysis...

  20. Saturn Ring Seismology: Interpreting the Seismogram

    Science.gov (United States)

    Marley, Mark Scott

    2013-01-01

    Marley (1990) and Marley and Porco (1993) proposed that f-mode oscillations of Saturn could excite resonant density and bending waves in the inner C-ring. They hypothesized that certain wave features discovered by Rosen et al. (1991) that were not associated with known satellite resonances could be the result of such resonant interactions with the planetary oscillation modes. They also predicted that if this was the case the waves would be found to be density (and not bending) waves by Cassini and predicted the azimuthal wave number of the C-ring waves m. Employing Cassini VIMS stellar occultation data Hedman and Nicholson (2013) have now confirmed the predictions and demonstrated that at least some of the C-ring features identified by Rosen et al. are indeed likely caused by resonant oscillation modes of Saturn. Given this context we have taken a fresh look at the Saturn ring seismology. First we propose that an apparent bending wave denoted 'j' by Rosen may be a second order outer vertical resonance with the l=3, m=2 f-mode of Saturn and discuss the locations of other plausible second order resonances in the rings. Since only a handful of ring resonances have been identified, measuring even one or two additional planetary mode frequencies would substantially assist the process of inverting mode frequencies to constrain Saturn interior's structure. Using the available mode frequencies, modern inversion technique employed in stellar seismology, and a recent set of Saturn interior models we provide an initial estimation of what available mode frequencies are telling us about the interior structure of the planet. Since the f-modes are confined relatively closely to the planetary surface, most of the observed modes probe only the outermost layers of the planet that are already comparatively well understood. However the l = 2 mode does probe relatively deeply into the planet and we will discuss the potential the measurement of this mode frequency has for placing new

  1. An Engel condition with an additive mapping in semiprime rings

    Indian Academy of Sciences (India)

    We denote by C, Q and RC ⊆ Q the extended centroid, the maximal right ring of quotients and a central closure of a semiprime ring R, respectively. For the explanation of C, Q and RC we refer the reader to [3]. We denote by char(R) the characteristic of a prime ring R. An additive mapping D of a ring R into itself is called a ...

  2. Hierarchical Ring Network Design Using Branch-and-Price

    DEFF Research Database (Denmark)

    Thomadsen, Tommy; Stidsen, Thomas K.

    2005-01-01

    link establishment costs and the link capacity costs into account. Hierarchical ring network design problems combines the following optimization problems: Clustering, hub selection, metro ring design, federal ring design and routing problems. In this paper a branch-and-price algorithm is presented...... for jointly solving the clustering problem, the metro ring design problem and the routing problem. Computational results are given for networks with up to 36 nodes....

  3. Formalized Linear Algebra over Elementary Divisor Rings in Coq

    OpenAIRE

    Cano , Guillaume; Cohen , Cyril; Dénès , Maxime; Mörtberg , Anders; Siles , Vincent

    2016-01-01

    International audience; This paper presents a Coq formalization of linear algebra over elementary divisor rings, that is, rings where every matrix is equivalent to a matrix in Smith normal form. The main results are the formalization that these rings support essential operations of linear algebra, the classification theorem of finitely pre-sented modules over such rings and the uniqueness of the Smith normal form up to multiplication by units. We present formally verified algorithms comput-in...

  4. On the cardinality of smallest spanning sets of rings | Boudi ...

    African Journals Online (AJOL)

    Let R = (R, +, ·) be a ring. Then Z ⊆ R is called spanning if the R-module generated by Z is equal to the ring R. A spanning set Z ⊆ R is called smallest if there is no spanning set of smaller cardinality than Z. It will be shown that the cardinality of a smallest spanning set of a ring R is not always decidable. In particular, a ring R ...

  5. Placement Of O-Rings In Solid Rocket Booster

    Science.gov (United States)

    Wood, Charles

    1991-01-01

    Brief report proposes to modify placement of O-ring seals in joints of Solid Rocket Booster of Space Shuttle. Modified joint and seal essentially "inside-out" version of old joint and seal. O-rings placed between outer side of tang and clevis. Joint rotation pushes tang harder against O-rings, thereby making even tighter seal. Proposal derived from analysis of Space Shuttle Challenger disaster, attributed to failure of these O-ring seals.

  6. Efficient ring perception for the Chemistry Development Kit

    OpenAIRE

    May, John W; Steinbeck, Christoph

    2014-01-01

    Background The Chemistry Development Kit (CDK) is an open source Java library for manipulating and processing chemical information. A key aspect in handling chemical structures is the determination of the chemical rings. The rings of a structure are used areas including descriptors, stereochemistry, similarity, screening and atom typing. The CDK includes multiple algorithms for determining the rings of a structure on demand. Non-unique descriptions of rings were often used due to the slower p...

  7. On (m, n)-absorbing ideals of commutative rings

    Indian Academy of Sciences (India)

    with respect to various ring theoretic constructions and study (m, n)-absorbing ideals in several commutative rings. For example, in a Bézout ring or a Boolean ring, an ideal is an (m, n)-absorbing ideal if and only if it is an n-absorbing ideal, and in an almost. Dedekind domain every (m, n)-absorbing ideal is a product of at ...

  8. Storage ring development at the National Synchrotron Light Source

    International Nuclear Information System (INIS)

    Krinsky, S.; Bittner, J.; Fauchet, A.M.; Johnson, E.D.; Keane, J.; Murphy, J.; Nawrocky, R.J.; Rogers, J.; Singh, O.V.; Yu, L.H.

    1991-09-01

    This report contains papers on the following topics: Transverse Beam Profile Monitor; Bunch Length Measurements in the VUV Storage Ring; Photoelectric Effect Photon Beam Position Monitors; RF Receivers for Processing Electron Beam Pick-up Electrode Signals; Real-Time Global Orbit Feedback Systems; Local Orbit Feedback; Active Interlock System for High Power Insertion Devices in the X-ray Ring; Bunch Lengthening Cavity for the VUV Ring; SXLS Storage Ring Design

  9. Strangulating Penile Ring: A Case Report | Orakwe | Afrimedic Journal

    African Journals Online (AJOL)

    ... a patient who presented at the Nnamdi Azikiwe University Teaching hospital, and relevant review of literature. Result: The ring was removed by the string method. Conclusion: The use of the string method as a starting point in cases of strangulating penile ring is recommended. Key words: strangulating penile ring Nigeria.

  10. Vanishing of cohomology over Cohen–Macaulay rings

    DEFF Research Database (Denmark)

    Christensen, Lars Winther; Holm, Henrik Granau

    2012-01-01

    , and it remains unknown if they form a class that is closed under typical constructions in ring theory. In this paper, we study transfer of the AC property along local homomorphisms of Cohen–Macaulay rings. In particular, we show that the AC property is preserved by standard procedures in local algebra. Our...... results also yield new examples of Cohen–Macaulay AC rings....

  11. Dynamical black rings with a positive cosmological constant

    International Nuclear Information System (INIS)

    Kimura, Masashi

    2009-01-01

    We construct dynamical black ring solutions in the five-dimensional Einstein-Maxwell system with a positive cosmological constant and investigate the geometrical structure. The solutions describe the physical process such that a thin black ring at early time shrinks and changes into a single black hole as time increases. We also discuss the multiblack rings and the coalescence of them.

  12. Ring opening of monocyclic dimethyl cyclopropene via metathesis ...

    Indian Academy of Sciences (India)

    ing metathesis (RO–RCM).12 Cyclic olefins react irre- versibly with a metal alkylidene to give a new ring opened alkylidene as a product. The ring opening metathesis proceeds through the well-accepted Chauvin mechanism,13 which involves a metallacyclobutane (MCB) as an intermediate. The mechanistic scheme of ring ...

  13. Binary GCD like Algorithms for Some Complex Quadratic Rings

    DEFF Research Database (Denmark)

    Agarwal, Saurabh; Frandsen, Gudmund Skovbjerg

    2004-01-01

    binary gcd like algorithms for the ring of integers in and , one now has binary gcd like algorithms for all complex quadratic Euclidean domains. The running time of our algorithms is O(n 2) in each ring. While there exists an O(n 2) algorithm for computing the gcd in quadratic number rings by Erich...

  14. Perfect state transfer in unitary Cayley graphs over local rings

    Directory of Open Access Journals (Sweden)

    Yotsanan Meemark

    2014-12-01

    Full Text Available In this work, using eigenvalues and eigenvectors of unitary Cayley graphs over finite local rings and elementary linear algebra, we characterize which local rings allowing PST occurring in its unitary Cayley graph. Moreover, we have some developments when $R$ is a product of local rings.

  15. Transport effects due to particle erosion mechanisms. [in planetary rings

    Science.gov (United States)

    Durisen, R. H.

    1984-01-01

    Various processes can erode the surfaces of planetary ring particles. Recent estimates for Saturn's rings suggest that a centimeter-thick surface layer could be eroded from an isolated ring particle in less than 1000 yr by meteoroid impacts alone. The atoms, molecules, and chips ejected from ring particles by erosion will arc across the rings along elliptical orbits. For moderate ring optical depths, ejecta will be absorbed or inelastically scattered upon reintersecting the ring plane. Continuous exchange of ejecta between different ring regions can lead to net radial transport of mass and angular momentum, to changes in particle sizes, and to the buildup of chip regoliths several centimeters deep on the surfaces of ring particles. Because most of the erosional ejecta are not lost but merely exchanged over short distances, the net erosion rate of the surfaces of these ring particles will be much less than that estimated for an isolated particle. Numerical solutions for time-dependent ballistic transport under various assumptions suggest pile-up and spillover effects especially near regions of preexisting high optical depth contrast, such as the inner edges of A and B rings. Global redistribution could be significant over billions of years. Other features in planetary ring systems may be influenced by ballistic transport.

  16. Experimental Investigation of Piston Rings for Internal Combustion Engines

    DEFF Research Database (Denmark)

    Christiansen, Jens; Klit, Peder; Vølund, Anders

    2007-01-01

    One of the major prerequisites for calculating piston ring friction is a good description of the tribological situation. A very important condition for describing the frictional behavior of a piston ring correctly is knowledge about the amount of lubricant present. For piston rings the external l...

  17. Experimental Investigation of Piston Rings for Internal Combustion Engines

    DEFF Research Database (Denmark)

    Klit, Peder; Vølund, Anders

    2008-01-01

    One of the major prerequisites for calculating piston ring friction is a good description of the tribological situation. A very important condition for describing the frictional behavior of a piston ring correctly is knowledge about the amount of lubricant present. For piston rings the external l...

  18. Rings, chains and planes: Variation of Tg with composition in ...

    Indian Academy of Sciences (India)

    Unknown

    tural changes, which happen as we add arsenic to sulphur. It is known that the sulphur-rich glasses consist of rings of sulphur, made of 8 atoms. Since the ring is effectively of 0 dimension, one would expect that the Van der Waals interaction binding a ring is proportional to 1/r3 (extra- polating from (7)). Hence Tg in this ...

  19. Beam properties of UVSOR storage ring

    International Nuclear Information System (INIS)

    Kasuga, T.; Hasumoto, M.; Kinoshita, T.; Yonehara, H.

    1985-01-01

    UVSOR constructed at the IMS (Institute for Molecular Science) is an electron storage ring dedicated to synchrotron radiation research in molecular science and its related fields. The first beam was stored on 10th Nov. in 1983. From that time on, efforts have been devoted to improvement of the performance of the ring. During the accelerator studies, some inconvenient phenomena were found. One of the big problems is ion trapping effect. Trapped ions change the operating point and enhance the coupling between horizontal and vertical oscillations. As a result, the beam height is enlarged considerably at high beam current. The beam is shaken slightly in the vertical plane and the electrostatic clearing field is applied to solve this problem. The bunch length is somewhat longer than the expected value. This effect is also a problem to be solved

  20. Free electron laser in storage rings

    International Nuclear Information System (INIS)

    Couprie, M.E.

    1989-05-01

    Investigations on the development of a free electron laser, carried out in ACO storage ring, are reported. The emission of synchrotron radiation is obtained from the interaction of relativistic charged particles with the magnetic field of the undulator. The synchrotron radiation is stored in a cavity, where interaction with electrons occurs. From the amplification of light waves, the laser radiation is then obtained. The changes in the electron wave packets induced by LEL experiment, carried out in ACO storage ring, are reported. A better understanding of the saturation mechanism, which dictates laser equilibrium, is obtained. Experiments in Super ACO were carried out and the following topics, on the construction of the laser, were investigated: the development of an optical klystron, gain optimization, the position of the mirrors (concerning the radiation from the undulator). This work allowed the construction of a 600 MeV free electron laser, at Super ACO. The development of a laser involving UV range radiation, is considered [fr