Decision 99-16: Canadian 88 Energy Corp. application to drill a level 4 critical sour gas well, Lochend Field

International Nuclear Information System (INIS)

1999-07-01

Canadian 88 Energy Corp. applied, pursuant to section 2.020 of the Oil and Gas Conservation Regulations, for a licence to drill a level 4 critical sour gas well to be located at Legal Subdivision 10 of Section 35, Township 26, Range 3, West of the fifth Meridian. The level 4 designation is used to determine the minimum separation distance between the well and land-use surface developments during the suspended or producing stage. This 10-35 well would require a minimum separation distance of 100 m from any individual dwelling development up to eight dwellings per quarter section, 500 m from an unrestricted county development, and 1500 m from an urban centre or public facility. The application and interventions were considered at a hearing in Calgary, Alberta commencing on 4 May 1998. The issues respecting the application were: the need for the well, the proposed well location, the potential hydrogen sulfide release rate, the drilling and completion considerations, the public safety risk assessment, emergency preparedness, the land use impacts, and public consultation. The Board believes that the public safety risks associated with the proposed well are representative of normal industrial risks accepted by society and that the well can be safely drilled. Also, the Board believes that these risks are similar to existing facilities and are acceptable if managed through strict adherence to the risk control measures required in the existing regulations. Given this, and having considered all the evidence, the Board is prepared to issue the well licence after Canadian 88 has undertaken, committed to, and submitted a number of requirements for review

The effects of the lodgepole sour gas well blowout on coniferous tree growth

International Nuclear Information System (INIS)

Baker, K.A.

1991-01-01

A dendrochronological study was used to evaluate growth impacts on White Spruce (Picea glauca (Moench) resulting from the 1982 Lodgepole sour gas well blowout. Stem analysis was evaluated from four ecologically similar monitoring sites located on a 10 kilometre downwind gradient and compared to a control site. Incremental volume was calculated, standardized using running mean filters and analyzed using one-way ANOVA. Pre and post-blowout growth trends were analyzed between sites and were also evaluated over a height profile in order to assess growth impact variability within individual trees. Growth reductions at the two sites closest the wellhead were statistically significant for five post-blowout years. Growth at these condensate impacted sites was reduced to 9.8% and 38.1% in 1983. Differences in growth reductions reflect a gradient of effects and a dose-response relationship. Recovery of surviving trees has been rapid but is leveling off at approximately 80% of pre-blowout growth. growth reductions were greater and recovery rates slower than those previously predicted by other authors. Statistically significant differences in height profile growth responses were limited to the upper portions of the trees. Growth rates over a tree height profile ranged from 10% less to 50% more than growth rates observed at a 1.3 metres. Analytical methodologies detected and described growth differences over a height profile but a larger sample size was desirable. As is always the case in catastrophic events, obtaining pre-event baseline data is often difficult. Dendrochronological methods described in this paper offer techniques for determining pre-blowout growth and monitoring impacts and recovery in forested areas

Cross-Linkable Polyimide Membranes for Improved Plasticization Resistance and Permselectivity in Sour Gas Separations

KAUST Repository

Kraftschik, Brian

2013-09-10

A series of cross-linkable membrane materials based on the 6FDA-DAM:DABA (3:2) polyimide backbone were synthesized for improved sour gas separation performance, in terms of both membrane stability and permselectivity. Short-chain poly(ethylene glycol) (PEG) molecules were used as cross-linking agents in an esterification-based cross-linking reaction. Pure and mixed gas permeation and pure gas sorption experiments were performed on dense films of these materials. Compared to unmodified 6FDA-DAM:DABA (3:2), higher sour gas permselectivity and membrane stability were achieved under aggressive feed conditions. H2S-induced plasticization was not evident until pure H2S feed pressures greater than approximately 6-8 bar. Pure CO 2-induced plasticization only occurred at feed pressures greater than about 25 bar. Under mixed gas feed conditions with 20% H2S, 20% CO2, and 60% CH4 at 35 C, attractive selectivities above 22 and 27 for H2S/CH4 and CO2/CH4, respectively, were observed for a feed pressure of 62 bar with both triethylene glycol and tetraethylene glycol cross-linking agents. © 2013 American Chemical Society.

Cross-Linkable Polyimide Membranes for Improved Plasticization Resistance and Permselectivity in Sour Gas Separations

KAUST Repository

Kraftschik, Brian; Koros, William J.

2013-01-01

A series of cross-linkable membrane materials based on the 6FDA-DAM:DABA (3:2) polyimide backbone were synthesized for improved sour gas separation performance, in terms of both membrane stability and permselectivity. Short-chain poly(ethylene glycol) (PEG) molecules were used as cross-linking agents in an esterification-based cross-linking reaction. Pure and mixed gas permeation and pure gas sorption experiments were performed on dense films of these materials. Compared to unmodified 6FDA-DAM:DABA (3:2), higher sour gas permselectivity and membrane stability were achieved under aggressive feed conditions. H2S-induced plasticization was not evident until pure H2S feed pressures greater than approximately 6-8 bar. Pure CO 2-induced plasticization only occurred at feed pressures greater than about 25 bar. Under mixed gas feed conditions with 20% H2S, 20% CO2, and 60% CH4 at 35 C, attractive selectivities above 22 and 27 for H2S/CH4 and CO2/CH4, respectively, were observed for a feed pressure of 62 bar with both triethylene glycol and tetraethylene glycol cross-linking agents. © 2013 American Chemical Society.

Formation and Control of Sulfur Oxides in Sour Gas Oxy-Combustion: Prediction Using a Reactor Network Model

KAUST Repository

Bongartz, Dominik; Shanbhogue, Santosh J.; Ghoniem, Ahmed F.

2015-01-01

© 2015 American Chemical Society. Sour natural gas currently requires expensive gas cleanup before it can be used in power generation because it contains large amounts of hydrogen sulfide (H2S) and carbon dioxide (CO2) that entail a low heating

A Numerical Study of the Sour Gas Reforming in a Dielectric Barrier Discharge Reactor

Directory of Open Access Journals (Sweden)

Sajedeh Shahsavari

2016-10-01

Full Text Available In this paper, using a one-dimensional simulation model, the reforming process of sour gas, i.e. CH4, CO2, and H2S, to the various charged particles and syngas in a dielectric barrier discharge (DBD reactor is studied. An electric field is applied across the reactor radius, and thus a non-thermal plasma discharge is formed within the reactor. Based on the space-time coupled finite element method, the governing equations are solved, and the temporal and spatial profiles of different formed charged species from sour gas inside the plasma reactor are verified. It is observed that the electric field increases radially towards the cathode electrode. Moreover, the electron density growth rate at the radial positions closer to the cathode surface is smaller than the one in the anode electrode region. Furthermore, as time progresses, the positive ions density near the anode electrode is higher. In addition, the produced syngas density is mainly concentrated in the proximity of anode dielectric electrode.

Domino effect of pollution from sour gas fields : failing legume nodulation and the honey industry

International Nuclear Information System (INIS)

Pirker, H.J.

1998-01-01

The sustainability of the honey industry in Alberta's Peace Country has been threatened by pollution from sour gas fields. The region has suffered crop reductions and chlorosis in grains, grasses, and legumes. Severe die-back and die-off of aspens and poplars has also been observed. Crops per colony were reduced by as much as 75 per cent, and winter losses more than tripled. Nectar flow patterns shifted from main flow in early summer to late flows in August or September from second growth alfalfa. A sampling of 27 fields found nitrogen fixation in alfalfa and red clovers lacking in areas downwind from major oil and sour gas flaring facilities. The reduction of the early season nectar flow appears to be caused by the synergistic interaction of ozone and sulphur compounds when ozone levels are at their highest. Reduced ozone levels in the fall permit a late, but uncertain flow from alfalfa plants

Domino effect of pollution from sour gas fields : failing legume nodulation and the honey industry

Energy Technology Data Exchange (ETDEWEB)

Pirker, H.J. [Peace Country Agricultural Protection Association, AB (Canada)

1998-10-01

The sustainability of the honey industry in Alberta`s Peace Country has been threatened by pollution from sour gas fields. The region has suffered crop reductions and chlorosis in grains, grasses, and legumes. Severe die-back and die-off of aspens and poplars has also been observed. Crops per colony were reduced by as much as 75 per cent, and winter losses more than tripled. Nectar flow patterns shifted from main flow in early summer to late flows in August or September from second growth alfalfa. A sampling of 27 fields found nitrogen fixation in alfalfa and red clovers lacking in areas downwind from major oil and sour gas flaring facilities. The reduction of the early season nectar flow appears to be caused by the synergistic interaction of ozone and sulphur compounds when ozone levels are at their highest. Reduced ozone levels in the fall permit a late, but uncertain flow from alfalfa plants.

Reservoir souring: it is all about risk mitigation

Energy Technology Data Exchange (ETDEWEB)

Kuijvenhoven, Cor [Shell (Canada)

2011-07-01

The presence of H2S in produced fluid can be due to various sources, among which are heat/rock interaction and leaks from other reservoirs. This paper discusses the reasons, risk assessment and tools for mitigating reservoir souring. Uncontrolled microorganism activity can cause a sweet reservoir (without H2S) to become sour (production of H2S). The development of bacteria is one of the main causes of reservoir souring in unconventional gas fields. It is difficult to predict souring in seawater due to produced water re-injection (PWRI). Risk assessment and modeling techniques for reservoir souring are discussed. Some of the factors controlling H2S production include injection location, presence of scavenging minerals and biogenic souring. Mitigation methods such as biocide treatment of injection water, sulphate removal from seawater, microbial monitoring techniques such as the molecular microbiology method (MMM), and enumeration by serial dilution are explained. In summary, it can be concluded that reservoir souring is a long-term problem and should be assessed at the beginning of operations.

Evaluation and improvement of sour property packages in UniSim design

Energy Technology Data Exchange (ETDEWEB)

Yang, J.; Zhao, E.; Wang, L.; Saha, S. [Honeywell, Calgary, AB (Canada)

2010-07-01

This presentation described specialty fluid packages for modeling oil and gas process systems involving sour gases in contact with aqueous phase. UniSim Design is a popular process simulation tool in the oil and gas industry. The sour Peng-Robinson (PR) and sour Soave-Redlich-Kwong (SRK) models are commonly used for handling sour system where hydrogen sulphide (H{sub 2}S), carbon dioxide (CO{sub 2}) or ammonia (NH{sub 3}) are in contact with an aqueous phase. These sour options combine the PR/SRK equation of state and Wilson's API-sour model where the equation of state is used to determine the fugacities of the vapor and liquid hydrocarbon phases, plus the enthalpy for all 3 phases. The Wilson's API-sour method is used for the aqueous phase calculations, which accounts for the ionization of H{sub 2}S, CO{sub 2} and NH{sub 3} in the aqueous phase. The efficiency of these 2 thermodynamic property packages were evaluated in this study by comparing industrial and experimental data and the results from other similar models. The purpose of this study was to improve these property packages for more accurate and reliable modeling of sour systems. tabs., figs.

Corrosion behaviour of steels and CRA in sour gas environments

Energy Technology Data Exchange (ETDEWEB)

Lara, M. Alvarez de; Lancha, A.M.; Hernandez, F.; Gomez-Briceno, D. [CIEMAT, Avenida Complutense 22, 28040 Madrid (Spain); Coca, P. [ELCOGAS, S.A., C.T. GICC Puertollano, Carretera de Calzada de Calatrava a Puertollano, km 27, 13500 Puertollano, Ciudad Real (Spain)

2004-07-01

The ELCOGAS power plant in Puertollano (Spain), with 335 MWe (ISO conditions), is an Integrated Gasification Combined Cycle (IGCC) plant built to demonstrate both the technical and economic feasibility of this alternative for clean generation of electricity from coal. IGCC technology is based on a coal gasification process, namely the conversion of coal into combustible gas, which is then subjected to an exhaustive cleaning process. The result is a synthetic gas, virtually free of pollutants that can be burned with a high efficiency in a combined cycle electricity-generating unit. Basically, the ELCOGAS plant consists of three islands jointly designed and integrated into the process: gasification island, air separation island and combined cycle island. In the gasification island, the gas from the gasifier is cleaned (de-dusted and washed) and desulfurized before being sent to the combined cycle island. The washing system consists of a Venturi scrubber with a separator where halogens and alkalis (NH{sub 3}, HCl, HF) are removed from the previously de-dusted gas by means of the wash water. The halogens and alkalis removed are then stripped from the wash water as stripped gas, which is a sour gas. The coal-gas coming from the separator proceeds to sulphur removal in a MDEA system and then, the clean gas (mainly CO, H{sub 2}) is sent to the combined cycle plant. As COS is a significant part of the sulphur containing gases in the coal gas, hydrolysis of the COS to H{sub 2}S takes place before the desulfurization stage, since MDEA is a selective amine for H{sub 2}S. There are many important areas related to materials corrosion within the gas cleaning system. In the ELCOGAS plant carbon steels, austenitic stainless steels and nickel based alloys, such as AISI 316Ti, AISI 904L and Hastelloy C276, are used in the Venturi, the water separator and the strippers. AISI 316Ti is used for the gas piping from the separator to the COS hydrolysis system. Laboratory tests to evaluate

Decision 99-28: Mobil Oil Canada, Ltd., and Mobil Resources Ltd., - application for a well licence to drill a critical sour gas well LSD 4-36-27-28 W4, Crossfield Field, application No. 1037560

International Nuclear Information System (INIS)

1999-01-01

On 12 February 1999, Mobil submitted Application No. 1037560 to the Alberta Energy and Utilities (EUB) Board on a routine basis, pursuant to Section 2.020 of the Oil and Gas Conservation Regulations, for a well licence to drill a critical sour gas well. The well would be drilled from a surface location in Legal Subdivision (LSD) 4 of Section 36, Township 27, Range 28, West of the 4th Meridian to a bottomhole location in LDS 7-36-27-28 W4M, with an 1100 m horizontal section. The aim of the 4-36 well was to obtain gas production from the Crossfield member. On 17 February 1999, the EUB issued Well Licence No. 221575 on the understanding that there were no outstanding objections to the 4-36 well. Mobil spudded the 4-36 well on 3 March 1999, drilled to 363 m and set surface casing. The EUB subsequently received objections to the application from area residents near the proposed well location. Accordingly, pursuant to Section 43 of the Energy Resources Conservation Act, the EUB directed that a public hearing be held to consider the application. The Board assessed in detail the effects that would likely result and the mitigative measures that would have to be taken to reduce any negative effects considering: the proposed well location, impacts of the proposed well, safety of the well, and public notification and consultation. Having carefully considered all the evidence, the EUB Board determined that Application No. 1037560 met all the EUB's regulatory requirements and was satisfied that appropriate measures were taken to ensure that public safety risks and impacts were minimized

a Real-Time GIS Platform for High Sour Gas Leakage Simulation, Evaluation and Visualization

Science.gov (United States)

Li, M.; Liu, H.; Yang, C.

2015-07-01

The development of high-sulfur gas fields, also known as sour gas field, is faced with a series of safety control and emergency management problems. The GIS-based emergency response system is placed high expectations under the consideration of high pressure, high content, complex terrain and highly density population in Sichuan Basin, southwest China. The most researches on high hydrogen sulphide gas dispersion simulation and evaluation are used for environmental impact assessment (EIA) or emergency preparedness planning. This paper introduces a real-time GIS platform for high-sulfur gas emergency response. Combining with real-time data from the leak detection systems and the meteorological monitoring stations, GIS platform provides the functions of simulating, evaluating and displaying of the different spatial-temporal toxic gas distribution patterns and evaluation results. This paper firstly proposes the architecture of Emergency Response/Management System, secondly explains EPA's Gaussian dispersion model CALPUFF simulation workflow under high complex terrain and real-time data, thirdly explains the emergency workflow and spatial analysis functions of computing the accident influencing areas, population and the optimal evacuation routes. Finally, a well blow scenarios is used for verify the system. The study shows that GIS platform which integrates the real-time data and CALPUFF models will be one of the essential operational platforms for high-sulfur gas fields emergency management.

Sour pressure swing adsorption process

Science.gov (United States)

Bhadra, Shubhra Jyoti; Wright, Andrew David; Hufton, Jeffrey Raymond; Kloosterman, Jeffrey William; Amy, Fabrice; Weist, Jr., Edward Landis

2017-11-07

Methods and apparatuses for separating CO.sub.2 and sulfur-containing compounds from a synthesis gas obtained from gasification of a carbonaceous feedstock. The primary separating steps are performed using a sour pressure swing adsorption (SPSA) system, followed by an acid gas enrichment system and a sulfur removal unit. The SPSA system includes multiple pressure equalization steps and a rinse step using a rinse gas that is supplied from a source other than directly from one of the adsorber beds of the SPSA system.

Community inflamed: Passionate opposition mounted to sour-gas drilling plan upwind of Canada's energy capital

International Nuclear Information System (INIS)

Lorenz, A.

1998-01-01

Residents of Bearspaw and Glendale, two small communities near Calgary are up in arms in opposition to the plans of Canadian 88 Energy Company to drill a 'level four' sour gas well in the area. The target gas contains 33.9 per cent hydrogen sulfide, a substance rated as lethal in much lower doses. Since the well is slated to be drilled on high ground upwind of Calgary, an accident causing a leak could expose community residents and thousands of Calgarians within half hour distance from the well to hydrogen sulfide concentrations several times higher than the Alberta Energy Board considers safe. Seepage into the water system poses yet another danger. For reasons that are not too well understood the Alberta Energy Board relaxed the size of the area for which the company must provide an emergency response plan from a radius of 18 km to a radius of 4 km, considered by experts to be totally unacceptable in a populated area. The Board granted the relaxation of the area covered by the emergency response plan on the assurances of the Company that it would substantially increase the criteria needed to make the plan manageable. However, the community is not convinced that the emergency response plan comes near to addressing the problem, and is prepared to oppose drilling of the well by all available means

Applications of UT results to confirm defects findings by utilization of relevant metallurgical investigations techniques on gas/condensate pipeline working in wet sour gas environment

Science.gov (United States)

El-Azhari, O. A.; Gajam, S. Y.

2015-03-01

The gas/condensate pipe line under investigation is a 12 inch diameter, 48 km ASTM, A106 steel pipeline, carrying hydrocarbons containing wet CO2 and H2S.The pipe line had exploded in a region 100m distance from its terminal; after 24 years of service. Hydrogen induced cracking (HIC) and sour gas corrosion were expected due to the presence of wet H2S in the gas analysis. In other areas of pipe line ultrasonic testing was performed to determine whether the pipeline can be re-operated. The results have shown presence of internal planner defects, this was attributed to the existence of either laminations, type II inclusions or some service defects such as HIC and step wise cracking (SWC).Metallurgical investigations were conducted on fractured samples as per NACE standard (TM-0284-84). The obtained results had shown macroscopic cracks in the form of SWC, microstructure of steel had MnS inclusions. Crack sensitivity analyses were calculated and the microhardness testing was conducted. These results had confirmed that the line material was suffering from sour gas deteriorations. This paper correlates the field UT inspection findings with those methods investigated in the laboratory. Based on the results obtained a new HIC resistance material pipeline needs to be selected.

High-efficiency low LCOE combined cycles for sour gas oxy-combustion with CO[subscript 2] capture

OpenAIRE

Chakroun, Nadim Walid; Ghoniem, Ahmed F

2015-01-01

The growing concerns over global warming and carbon dioxide emissions have driven extensive research into novel ways of capturing carbon dioxide in power generation plants. In this regard, oxy-fuel combustion has been considered as a promising technology. One unconventional fuel that is considered is sour gas, which is a mixture of methane, hydrogen sulfide and carbon dioxide. In this paper, carbon dioxide is used as the dilution medium in the combustor and different combined cycle configurat...

ERCB investigation report : Daylight Energy Amalgamation Co Ltd. sour gas release surface location 06-23-047-10W5M December 16, 2009

Energy Technology Data Exchange (ETDEWEB)

Temple, B.; Schlager, J.; Wilkes, J.; Saulnier, P.; Mayall, J.; Duben, A.; Ravensdale, C.

2010-07-21

This report discussed a sour gas release that occurred at a well located near the town of Lodgepole. The well had a hydrogen sulfide (H{sub 2}S) concentration of 29.19 per cent, with an emergency planning zone (EPZ) of 570 m. The owner of the well contacted stakeholders in the region, and road blocks were set up north of the well. Three mobile air monitoring units were dispatched to the site, and service contractors were hired to kill the well. The road blocks were removed after a review of the air monitoring data. Prior to the release, a heat tape assembly had been installed in the well as a result of ongoing hydrate formation problems. An investigation of the well after the release showed damage to the connectors in the heat tape assembly. A failure analysis showed that the damage was caused by excessive temperatures created by a short circuit in the wires located in each connector. The heat allowed downhole gas pressure to push the wire to the surface. Gas was released from the damaged assembly seal. An outline of all steps taken to address the emergency was provided. 4 figs.

The chemistry of sour taste and the strategy to reduce the sour taste of beer.

Science.gov (United States)

Li, Hong; Liu, Fang

2015-10-15

The contributions of free hydrogen ions, undissociated hydrogen ions in protonated acid species, and anionic acid species to sour taste were studied through sensory experiments. According to tasting results, it can be inferred that the basic substance producing a sour taste is the hydrogen ion, including free hydrogen ions and undissociated hydrogen ions. The intensity of a sour taste is determined by the total concentration of free hydrogen ions and undissociated hydrogen ions. The anionic acid species (without hydrogen ions) does not produce a sour taste but can intensify or weaken the intensity of a sour taste. It seems that hydroxyl or conjugated groups in anionic acid species can intensify the sour taste produced by hydrogen ions. The following strategy to reduce the sensory sourness is advanced: not only reduce free hydrogen ions, namely elevate pH value, but also reduce the undissociated hydrogen ions contained in protonated acid species. Copyright © 2015 Elsevier Ltd. All rights reserved.

Increasing of the processing capacity of an alkanoamine in aqueous solution mixed sour gas treatment unit; Incremento de la capacidad de procesamiento de una planta de tratamiento de gas amargo con mezclas de alcanolaminas en solucion acuosa

Energy Technology Data Exchange (ETDEWEB)

Bernal, J. Manuel; Valtierra, Victor H.; Cabrales, Alberto [Instituto Mexicano del Petroleo, Mexico City (Mexico)

1998-07-01

The necessity of increasing the process capacity of the existing sour gas treating units, has been a factor that has driven the investigation centers to develop new solvent formulations that could been capable of removing the sour gases without majors changes in the equipment that conforms those units. In this sense, the Instituto Mexicano del Petroleo has carried out the study in order to increase the processing capacity of a sour gas treatment plant of Petroleos Mexicanos. In this work, the use of solvents or alternative formulations, based on the use of methyl-diethanolamine (MDEA), as single solvent, or in mixture with others are considered. Our experimental data indicates that the use of MDEA in a formulation, in mixture with another amines, carry out to combination of attributes such as high absorption capacity and a high speed of absorption of the preferred acid gas (H{sub 2}S), besides it reduces the degradation index of the solvent and minimizes the equipment corrosion situation that is transformed in considerable improvement in the processing capacity and/or in the energy process savings, finally the operative problems are minimized. (author)

Primary souring: A novel bacteria-free method for sour beer production.

Science.gov (United States)

Osburn, Kara; Amaral, Justin; Metcalf, Sara R; Nickens, David M; Rogers, Cody M; Sausen, Christopher; Caputo, Robert; Miller, Justin; Li, Hongde; Tennessen, Jason M; Bochman, Matthew L

2018-04-01

In the beverage fermentation industry, especially at the craft or micro level, there is a movement to incorporate as many local ingredients as possible to both capture terroir and stimulate local economies. In the case of craft beer, this has traditionally only encompassed locally sourced barley, hops, and other agricultural adjuncts. The identification and use of novel yeasts in brewing lags behind. We sought to bridge this gap by bio-prospecting for wild yeasts, with a focus on the American Midwest. We isolated 284 different strains from 54 species of yeast and have begun to determine their fermentation characteristics. During this work, we found several isolates of five species that produce lactic acid and ethanol during wort fermentation: Hanseniaspora vineae, Lachancea fermentati, Lachancea thermotolerans, Schizosaccharomyces japonicus, and Wickerhamomyces anomalus. Tested representatives of these species yielded excellent attenuation, lactic acid production, and sensory characteristics, positioning them as viable alternatives to lactic acid bacteria (LAB) for the production of sour beers. Indeed, we suggest a new LAB-free paradigm for sour beer production that we term "primary souring" because the lactic acid production and resultant pH decrease occurs during primary fermentation, as opposed to kettle souring or souring via mixed culture fermentation. Copyright © 2017 Elsevier Ltd. All rights reserved.

Sour ageusia in two individuals implicates ion channels of the ASIC and PKD families in human sour taste perception at the anterior tongue.

Directory of Open Access Journals (Sweden)

Taufiqul Huque

2009-10-01

Full Text Available The perception of sour taste in humans is incompletely understood at the receptor cell level. We report here on two patients with an acquired sour ageusia. Each patient was unresponsive to sour stimuli, but both showed normal responses to bitter, sweet, and salty stimuli.Lingual fungiform papillae, containing taste cells, were obtained by biopsy from the two patients, and from three sour-normal individuals, and analyzed by RT-PCR. The following transcripts were undetectable in the patients, even after 50 cycles of amplification, but readily detectable in the sour-normal subjects: acid sensing ion channels (ASICs 1a, 1beta, 2a, 2b, and 3; and polycystic kidney disease (PKD channels PKD1L3 and PKD2L1. Patients and sour-normals expressed the taste-related phospholipase C-beta2, the delta-subunit of epithelial sodium channel (ENaC and the bitter receptor T2R14, as well as beta-actin. Genomic analysis of one patient, using buccal tissue, did not show absence of the genes for ASIC1a and PKD2L1. Immunohistochemistry of fungiform papillae from sour-normal subjects revealed labeling of taste bud cells by antibodies to ASICs 1a and 1beta, PKD2L1, phospholipase C-beta2, and delta-ENaC. An antibody to PKD1L3 labeled tissue outside taste bud cells.These data suggest a role for ASICs and PKDs in human sour perception. This is the first report of sour ageusia in humans, and the very existence of such individuals ("natural knockouts" suggests a cell lineage for sour that is independent of the other taste modalities.

Developing remediation criteria on the basis of health and ecological risks at a former sour gas plant site

International Nuclear Information System (INIS)

Brown, G. L.; Wilson, R. M.; Clyde, G. A.; Chollak, D. F.

1997-01-01

A human health and ecological risk assessment was completed for the Okotoks sour gas processing gas plant, based on the existing environmental sampling and toxicity testing that has been collected at the site since 1987. For the human health risk assessment, two potential scenarios were considered, including industrial use and parkland use. The ecological risk assessment involved synthesis of existing sampling and toxicity testing results as well as the assessment of potential risk to ecological receptors such as the meadow vole, red-tailed hawk and cattle. The assessment included chemical screening, receptor and exposure pathway selection, toxicity assessment of chemicals of concern, estimation of exposures, risk characterization and generation of soil and groundwater remediation criteria. Results of the assessments to date indicate that limited subsurface remediation is required for the protection of human health under industrial/parkland use. In contrast, ecological considerations will require remediation or reclamation of surface soil and the imposition of certain risk management controls, such as e. g. encumbrances on land title. 2 figs

Analytical and sensorial characterization of the aroma of wines produced with sour rotten grapes using GC-O and GC-MS: identification of key aroma compounds.

Science.gov (United States)

Barata, André; Campo, Eva; Malfeito-Ferreira, Manuel; Loureiro, Virgílio; Cacho, Juan; Ferreira, Vicente

2011-03-23

In the present work, the aroma profiles of wines elaborated from sound and sour rot-infected grapes as raw material have been studied by sensory analysis, gas chromatography-olfactometry (GC-O), and gas chromatography-mass spectrometry (GC-MS), with the aim of determining the odor volatiles most likely associated with this disease. The effect of sour rot was tested in monovarietal wines produced with the Portuguese red grape variety Trincadeira and in blends of Cabernet Sauvignon and sour rotten Trincadeira grapes. Wines produced from damaged berries exhibited clear honey-like notes not evoked by healthy samples. Ethyl phenylacetate (EPhA) and phenylacetic acid (PAA), both exhibiting sweet honey-like aromas, emerged as key aroma compounds of sour rotten wines. Their levels were 1 order of magnitude above those found in controls and reached 304 and 1668 μg L(-1) of EPhA and PAA, respectively, well above the corresponding odor thresholds. Levels of γ-nonalactone also increased by a factor 3 in sour rot samples. Results also suggest that sour rot exerts a great effect on the secondary metabolism of yeast, decreasing the levels of volatiles related to fatty acids and amino acid synthesis. The highest levels of γ-decalactone of up to 405 μg L(-1) were also found in all of the samples, suggesting that this could be a relevant aroma compound in Trincadeira wine aroma.

Precipitation hardened nickel-base alloys for sour gas environments

International Nuclear Information System (INIS)

Igarashi, M.; Mukai, S.; Kudo, T.; Okada, Y.; Ikeda, A.

1987-01-01

SCC (Stress Corrosion Cracking) in sour gas environments of γ'(gamma prime: Ni/sub 3/(Ti and/or Al)) and γ''(gamma double prime: Ni/sub 3/Nb) precipitation hardened nickel-base alloys has been studied using the SSRT (Slow Strain Rate Tensile) test, anodic polarization measurement and transmission electron microscopy (TEM). The γ'-type alloy containing Ti was more susceptible to SCC in the SSRT tests up to 350 0 F(450 K) than the γ''-type alloy containing Nb. The susceptibility to SCC was related to their deformation structures in terms of stress localization and sensitivity to pitting corrosion in H/sub 2/S solutions. TEM observation showed the γ'-type alloy deformed by the superlattice dislocations in coplanar structures. This mode of deformation induced the stress localization to some boundaries such as grain boundary and as a result the susceptibility to SCC of the γ'-type alloy was increased. On the other hand, the γ''-type alloy deformed by the massive dislocation not in coplanar structures so that it was less susceptible to SCC in terms of the stress localization. The anodic polarization measurement suggested the γ'-type alloy was more susceptible to pitting corrosion compared with the γ''-type alloy

Corrosion inhibitor development for slightly sour environments with oxygen intrusion

Energy Technology Data Exchange (ETDEWEB)

Wylde, J.; Wang, H.; Li, J. [Clariant Oil Services North America, Calgary, AB (Canada)

2009-07-01

This presentation reported on a study that examined the effect of oxygen on the inhibition of carbon steel in slightly sour corrosion, and the initiation and propagation of localized attack. Oxygen can enter sour water injection systems through the vapor space in storage tanks and process system. Oxygen aggravates the corrosion attack by participating in the cathodic reaction under full or partial diffusion control. Laboratory testing results were reported in this presentation along with the development of corrosion inhibitors for such a slightly sour system. Bubble testing cells were used with continuous H{sub 2}/CO{sub 2} mixture gas sparging and occasional oxygen intrusion of 2 to 4 hours during a week long test. Linear polarization resistance (LPR) measurements and weight loss corrosion coupons were used to quantify the corrosion attack. The findings were presented in terms of the magnitude of localized attacks at different oxygen concentrations and intrusion periods, with and without the presence of corrosion inhibitors. tabs., figs.

Decision 99-13: Crestar Energy Inc. applications to construct and operate sour gas batteries and pipelines, Vulcan Field

International Nuclear Information System (INIS)

1999-06-01

On 1 December 1998, the applicant applied pursuant to Part 4 of the Pipeline Act and Section 7.001 of the Oil and Gas Conservation Regulations for approval to construct and operate a sour gas pipeline and various surface facilities to tie in three wells. These are located at Legal Subdivision 12 of Section 36, Township 16, Range 24, West of the fourth Meridian (12-36 facility), Lsd 10-35-16-24 WM4 (10-35 facility), and Lsd 7-26-16-24 WM4 (7-26 facility), to an existing pipeline and proposed surface facility at Lsd 16-16-16-24 WM4. The 10-35, 7-26 and 16-16 facilities would each have a separator, a flare knockout drum, and a flare stack. The 12-36 facility would have two separators, one for each of the two producing zones at the 12-36 facility, a flare knockout drum, and flare stack. A compressor would be installed at the 16-16 facility. All fluids would be measured and re-injected into the pipeline for removal at the 16-16 facility. All proposed flare stacks would consists of a continuously burning sweet gas pilot and would be used for emergencies, routine well servicing, and pigging operations only. The pipeline would be designated as a Level 1 facility, and would transport up to 18 moles of hydrogen sulfide per kilomole of natural gas. Although the Board approved Application No. 1037084 after carefully considering the evidence, subject to meeting all the regulatory requirements and conditions set out in Attachment 1, it rejected Application No. 1033453

Natural Gas

OpenAIRE

Bakar, Wan Azelee Wan Abu; Ali, Rusmidah

2010-01-01

Natural gas fuel is a green fuel and becoming very demanding because it is environmental safe and clean. Furthermore, this fuel emits lower levels of potentially harmful by-products into the atmosphere. Most of the explored crude natural gas is of sour gas and yet, very viable and cost effective technology is still need to be developed. Above all, methanation technology is considered a future potential treatment method for converting the sour natural gas to sweet natural gas.

Air emissions from sour-gas processing plants and dairy-cattle reproduction in Alberta, Canada.

Science.gov (United States)

Scott, H M; Soskolne, C L; Martin, S W; Shoukri, M M; Lissemore, K D; Coppock, R W; Guidotti, T L

2003-02-15

The dispersion of air pollutants from all 231 licensed sour-gas processing plants in Alberta, Canada, was modeled on a monthly basis over a 10-year period (1985-1994). Exposure estimates for sulfur dioxide (SO(2)-used as a surrogate for exposure to combusted emissions) then were assigned to 1382 provincial dairy farms using a geographical-information system. Individual average and peak exposure for periods prior to each of 15 months of age and conception (four exposure-averaging periods for each of two dispersion models) were estimated for 163,988 primiparous female dairy-cattle between 1986 and 1994. Monthly or annual average farm-site exposure estimates likewise were assigned to associated herd-level data sets for the biologically relevant period of interest for each of three additional reproductive outcomes: monthly herd-average calving interval, stillbirth risk, and twinning risk. In one of the main-effects models, the maximum (i.e., peak) monthly sour-gas exposure experienced by individual-animals from birth to conception was associated with an increased time to first-calving in the very-highest exposure category (hazard ratio=0.86, 95% CI=0.80, 0.92). This equates to a decreased hazard (lambda) of calving (in each month subsequent to 22 months of age) for the highest-exposure animals (lambda=0.170) versus the zero-exposure animals (lambda=0.198) in a model with referent values for agro-ecological region and season of birth. The dose-response was not consistent across the full range of exposure categories. There was significant (P=0.003) interaction of emissions with agro-ecological region. After accounting for the interaction, a more-consistent dose-response was evident for some (but not all) agro-ecological regions. This suggests that any effect of emissions on dairy-heifer reproduction is subject to modification by features of soil type, vegetative cover, and/or climate. The increase in monthly herd-average calving interval on farms exposed to the very

A Multistage Fluidized Bed for the Deep Removal of Sour Gases : Proof of Concept and Tray Efficiencies

NARCIS (Netherlands)

Driessen, Rick T.; Bos, Martin J.; Brilman, Derk W. F.

2018-01-01

Currently there are significant amounts of natural gas that cannot be produced and treated to meet pipeline specifications, because that would not be economically viable. This work investigates a bench scale multistage fluidized bed (MSFB) with shallow beds for sour gas removal from natural gas

New progress in wastewater treatment technology for standard-reaching discharge in sour gas fields

Directory of Open Access Journals (Sweden)

Jie Yang

2018-02-01

Full Text Available Gas field water is generally characterized by complex contaminant components and high salinity. Its proper treatment has always been the great concern in the field of environmental protection of oil & gas fields. In this paper, the wastewater from a gas field in the Sichuan Basin with high salinity and more contaminants (e.g. sulfides was treated as a case study for the standard-reaching discharge. Lab experiments were carried out to analyze the adaptability and effectiveness of coagulation–desulfurization composite treatment technology, chemical oxidation based ammonia nitrogen removal technology and cryogenic multi-efficacy distillation technology in the treatment of wastewater in this field. The results show that the removal rate of sulfides and oils is over 90% if polymeric ferric sulfate (PFS is taken as the coagulant combined with TS-1 desulfurization agent. Besides, the removal rate of ammonia nitrogen is over 96% if CA-1 is taken as the oxidant. Finally, after the gas field water is treated by means of cryogenic three-efficacy distillation technology, chloride concentration of distilled water is below 150 mg/L and CODcr concentration is less than 60 mg/L. It is concluded that after the whole process treatment, the main contaminant indicators of wastewater in this case study can satisfy the grade one standard specified in the Integrated Wastewater Discharge Standard (GB 8978–1996 and the chloride concentration can meet the requirement of the Standards for Irrigation Water Quality (GB 5084–2005. To sum up, the above mentioned composite technologies are efficient to the wastewater treatment in sour gas fields. Keywords: Sulfide-bearing gas field water, Coagulation, Desulfurization, Chemical oxidation, Standard discharge, Ammonia nitrogen, Chloride, Cryogenic multi-efficacy distillation, Sichuan Basin

Stimulation of deep gas wells using HCl/formic acid system : lab studies and field application

Energy Technology Data Exchange (ETDEWEB)

Nasr-El-Din, H.A.; Al-Mutairi, S.; Al-Malki, B. [Saudi Aramco (Saudi Arabia); Metcalf, S.; Walters, W. [BJ Services Co USA, Houston, TX (United States)

2002-06-01

Well stimulation in the deep carbonate Khuff reservoirs in eastern Saudi Arabia is needed to remove drilling mud filter cakes and to enhance reservoir permeability. A non associated gas is being produced from the reservoirs. This gas is associated with the hydrogen sulfide content that varies from 0 to 10-mol per cent. The average reservoir temperature is 275 degrees F and initial reservoir pressure is 7,000 psi. A special system is needed to stimulate the carbonate reservoir because of this high bottomhole temperature and the corrosive nature of hydrochloric acid (HCl) at high temperature. A rotating disk method was used to determine the reaction rate of an HCl/formic acid system with reservoir rocks. Results from coreflood tests showed that the acid system creates deep wormholes in tight reservoir cores. Corrosion tests showed that the well tubulars could tolerate the acid system. A gelled 15-wt per cent HCl/9-wt per cent formic acid system successfully fractured 3 vertical wells in deep sour gas reservoirs without any operational problems. The treatment resulted in significant increases in gas production and flowing wellhead pressures. In addition, overflush of the treatment successfully eliminated the return of live acid after the treatment. 37 refs., 10 tabs., 17 figs.

SOUR MILK FORMULAS IN NUTRITION OF INFANTS

Directory of Open Access Journals (Sweden)

E.F. Lukushkina

2010-01-01

Full Text Available Health-giving properties of fermented food are related to the fact, that acid medium improves assimilation of protein and fat, increases absorption of iron and zinc, improves digestion. But the kefir and other sour milk food based on the whole milk can’t be used in nutrition of infants as human milk substitute because of high content of protein, high osmolarity, deficiency of vitamins and microelements. The article describes the results of clinical approbation of new modern sour milk formula «NAN sour milk», containing proper amount of high-quality protein (OptiPro, enriched with lactalbumin and all sufficient vitamins and microelements. This mixture contains also probiotics (B. lactis, providing high functionality of this food. Key words: infants, sour milk formula, nutrition.(Voprosy sovremennoi pediatrii — Current Pediatrics. 2010;9(1:136-141

Bortezomib alters sour taste sensitivity in mice

Directory of Open Access Journals (Sweden)

Akihiro Ohishi

Full Text Available Chemotherapy-induced taste disorder is one of the critical issues in cancer therapy. Bortezomib, a proteasome inhibitor, is a key agent in multiple myeloma therapy, but it induces a taste disorder. In this study, we investigated the characteristics of bortezomib-induced taste disorder and the underlying mechanism in mice. Among the five basic tastes, the sour taste sensitivity of mice was significantly increased by bortezomib administration. In bortezomib-administered mice, protein expression of PKD2L1 was increased. The increased sour taste sensitivity induced by bortezomib returned to the control level on cessation of its administration. These results suggest that an increase in protein expression of PKD2L1 enhances the sour taste sensitivity in bortezomib-administered mice, and this alteration is reversed on cessation of its administration. Keywords: Taste disorder, Bortezomib, Sour taste, Chemotherapy, Adverse effect

SOUR MILK FOODSTUFF IN INFANTS DIET

Directory of Open Access Journals (Sweden)

T. E. Borovik

2014-01-01

Full Text Available Products of sour milk are widely used in nutrition of infants. They are an important source of digestible proteins, vitamins and potassium. Regular intake of sour milk foodstuff has favorable influence on intestinal microbiocenosis, functioning of the immune system, improves secretory and motor functions of the gastrointestinal tract, stimulates appetites and increases bioavailability of micronutrients. Modern line in functional diet is enrichment of sour milk foodstuff with probiotics. Strains of microorganisms used in manufacture of products with probiotic action are proven to be safe and effective in prophylaxis and treatment of various diseases. Modern data which confirm prophylactic and medicinal properties of probiotic-containing foodstuff, especially bioyoghurts for children, are shown in this article.

Hydrogen sulfide (H{sub 2}S) and sour gas effects on the eye. A historical perspective

Energy Technology Data Exchange (ETDEWEB)

Lambert, Timothy William [Environmental Health, Calgary Health Region, 1509 Centre St SW, Calgary Alberta, T2G 2E6 (Canada)]. E-mail: tim.lambert@calgaryheathregion.ca; Goodwin, Verona Marie [VM Goodwin Research and Consulting Ltd. (Canada); Stefani, Dennis [Environmental Health, Calgary Health Region, 1509 Centre St SW, Calgary Alberta, T2G 2E6 (Canada); Strosher, Lisa [Environmental Health, Calgary Health Region, 1509 Centre St SW, Calgary Alberta, T2G 2E6 (Canada)

2006-08-15

The toxicology of hydrogen sulfide (H{sub 2}S) and sour gas on the eye has a long history beginning at least with Ramazzini's observations [Ramazzini B. Diseases of Workers-De Morbis Artificum Diatriba-1713. Wright WC (trans). New York, C. Hafner Publishing Co Inc.; 1964. 98-99 pp.]. In contrast, a recent review by Alberta Health and Wellness (AHW Report) concluded that there is little evidence of eye irritation following short-term exposures to H{sub 2}S at concentrations up to 100 ppm and that the H{sub 2}S literature on the eye is a series of unsubstantiated claims reproduced in review articles dating back to the 1930s [Alberta Health and Wellness (AHW report). Health effects associated with short-term exposure to low levels of hydrogen sulfide: a technical review, Alberta Health and Wellness, October 2002, 81pp.]. In this paper, we evaluated this claim through a historical review of the toxicology of the eye. Ramazzini noted the effects of sewer gas on the eye [Ramazzini B. Diseases of Workers-De Morbis Artificum Diatriba-1713. Wright WC (trans). New York, C. Hafner Publishing Co Inc. 1964. 98-99 pp.]. Lehmann experimentally showed eye effects in men at 70-90 ppm H{sub 2}S and also in animals [Lehmann K. Experimentalle Studien uber den Einfluss technisch und hygienisch wichtiger Gase und Dampfe auf den Organismus. Arch Hyg 1892;14:135-189]. In 1923, Sayers, Mitchell and Yant reported eye effects in animals and men at 50 ppm H{sub 2}S. Barthelemy showed eye effects in animals and men at 20 ppm H{sub 2}S [Barthelemy HL. Ten years' experience with industrial hygiene in connection with the manufacture of viscose rayon. J Ind Hyg Toxicol 1939;21:141-51]. Masure experimentally showed that H{sub 2}S is the causative agent of eye impacts in animals and men [Masure R. La Keratoconjunctivite des filatures de viscose; etude clinique and experiementale. Rev Belge Pathol 1950;20:297-341]. Michal upon microscopic examination of the rat's cornea, found nuclear

Shell Canada Limited application for increased throughput sour gas plant - Caroline Field : decision 97-5

International Nuclear Information System (INIS)

1998-06-01

The Alberta Energy and Utilities Board considered an application by Shell Canada Limited to amend its existing Caroline Gas plant approval. Shell desires to add additional cooling equipment to enhance gas processing during the warmer months. Interveners raised several concerns, including the impact of the existing operation on the environment, and the health and safety of the community. Shell stated that the proposed increased throughput of sour gas would result in a 21 per cent increase in sulphur inlet, but that the emissions of SO 2 would still remain below the currently-approved daily maximum level of 45 t/d. Shell also stated that the proposed project would have no impact on flaring duration or frequency. The Board reviewed the evidence filed, and considered the comments of the participants made at a pre-hearing on June 11, 1996. The Board's assessment was that a public hearing was necessary to address Shell's application. The Board also expressed the belief that the scope of the public hearing should be limited to the possible impacts that may occur from the processing of incremental raw inlet gas and sulphur. A hearing date of July 22, 1996 was set. Having regard to the evidence which the Board received and considered, the Board declared itself satisfied that the technical changes to the plant were satisfactory and that the applied-for plant modifications would meet regulatory standards. The Board also believed that the approval of the application to increase throughput at the plant would be in the public interest. Accordingly, the Board declared its readiness to approve the application provided that Shell agreed to meet certain specified conditions. tab., 1 fig

Fifty per cent reduction in solution gas flaring : a report to the Saddle Hills Awareness Committee

International Nuclear Information System (INIS)

1999-01-01

Information by the Alberta Energy Company to the Saddle Hills Awareness Committee (SHAC) regarding company operations in the West Peace River Arch of the western Canadian Sedimentary Basin in northwest Alberta is presented, the purpose being to bring the Committee up-to-date, and respond to concerns about the health effects of sour gas emissions. The SHAC represents citizens who are concerned about issues relating to sour gas emissions. AEC West, a business unit of Alberta Energy Company, operates two sour gas processing plants, one sweet gas plant and three sour oil batteries in the Grande Prairie area. AEC's gas plants are connected by pipelines and process petroleum and natural gas products from approximately 200 oil and gas wells. The H 2 S content of the natural gas being processed by AEC's various plants ranges from trace amounts to 11 per cent. Activities at AEC's Hythe plant and at the Sexsmith plant, and the company's gas storage project are briefly reviewed. An analysis is included of the role that flaring plays in the petroleum and natural gas industry, emphasizing AEC West's efforts during 1997 to reduce solution gas flaring volumes from single well oil batteries by 50 per cent. Other AEC West environmental protection initiatives include the preliminary regional airshed study sponsored by the company which resulted in part from SHAC feedback and in part from the innovative approach of AEC employees. AEC West established the industry's first Ombudsman to provide a problem resolution focus on landowner complaints and introduced a policy of making available solution gas that would eventually be flared to industrial colleagues, free of charge

Changes in taste sensation of sour, salty, sweet, bitter, umami, and spicy, as well as levels of malondialdehyde serum in radiographers

Directory of Open Access Journals (Sweden)

Agniz Nur Aulia

2016-06-01

on the effects of radiation on cancer patients show that radiation can cause an increase in bitterness and metal taste [in cancer patients] leading to discomfort in the oral cavity. In body, free radicals then can cause lipid peroxidation process. Lipid peroxidation is an oxidative destruction of polyunsaturated fatty acid producing malondialdehyde (MDA. Purpose: This study aimed to determine the effects of radiation on changes in the taste sensation of sour, salty, sweet, bitter, umami, and spicy as well as the levels of MDA serum in radiographers. Method: This study was an observational laboratory research using post- test control design. Samples were selected using simple random sampling technique. The samples were seven radiographers who have been working for five years in the laboratory and radiographic units in Surabaya. Result: Based on the results of statistical tests, it showed that there were no differences in the sensitivity of all tastes between the groups tested. Moreover, the results also depicted considerable value for the sour taste was 0.550, the saltiness was 0.775, the sweetness was 0.294, the bitter taste was 0.065, the umami taste was 0.705, and the spicy taste was 0.319 (p>0.05. However, the dramatic increase was higlighted in levels of MDA serum with a significant value of 0.065 (p>0.005. Conclusion. There were no changes in the sensitivity of sour, salty, sweet, bitter, umami, and spicy tastes, but there was a significant increased in level of MDA serum in the radiographers compared to the control group.

Case studies of the application of enhanced steel alloys for bottom hole assembly components for sour service conditions

Energy Technology Data Exchange (ETDEWEB)

Chan, Alvaro [Nov Grant Prideco, Navasota (United States); Moura, Carlos [ASPEN Assesoria Tecnica e Comercial, Cascavel, PR (Brazil); Johnson, Charles; Landriault, Alain [Weatherford Canda Partnership, Calgary, AB (Canada)

2008-07-01

The new more modern drilling programs require the drill string to travel across sour formations in order to reach the hydrocarbon reservoirs. Traditional materials have been employed in the manufacture of HWDP components along with basic heat treatment processes. Standard HWDP tools have started to show their operational as well as environmental limitations when subjected to sour service applications. The advanced, more complex drilling programs require for the HWDP tools to be put in service under different configurations. Either at the bottom of the drill string near the drill bit for vertical well configurations or on top of the drill string for weight application on horizontal or extended reach applications. An operator in northwestern Canada has replaced standard HWDP with enhanced sour service HWDP in order to complete the programmed wells. These enhanced tools offer higher tensile and torque capabilities and improved toughness than standard HWDP tools and in addition, provide protection against sour service conditions. The use of second-generation double shoulder connections (2nd-Gen. DSC) has also provided added torque and tensile capacities to these versatile HWDP tools. For over a year more than a dozen wells have been drilled employing these enhanced BHA tools and have helped the operator reach its targets through sour service formations and produce wells in a safe and cost effective manner. (author)

Polyphenols and Volatiles in Fruits of Two Sour Cherry Cultivars, Some Berry Fruits and Their Jams

Directory of Open Access Journals (Sweden)

Branka Levaj

2010-01-01

Full Text Available This paper reports about the content of polyphenols and volatiles in fresh fruits of two sour cherry cultivars (Marasca and Oblačinska, some berry fruits (strawberry Maya, raspberry Willamette and wild blueberry and the corresponding low sugar jams. Phenolic compounds (hydroxybenzoic and hydroxycinnamic acids, flavan 3-ols and flavonols were determined by high-performance liquid chromatography (HPLC. Those found in the fruits were also found in the jams. Jams contained lower amounts of polyphenols than fresh fuits, but their overall retention in jams was relatively high. Among fruits, sour cherry Marasca had the highest level of polyphenols, while sour cherry Marasca jam and raspberry Willamette jam had the highest level of polyphenols among jams. The major flavonoid in all investigated fruits, except in sour cherry Oblačinska, was (–-epicatechin. Sour cherry Marasca had the highest level of (–-epicatechin (95.75 mg/kg, and it also contained very high amounts of flavonols, derivatives of quercetin and kaempferol. Hydroxybenzoic acids (HBAs were not found in sour cherries Marasca and Oblačinska, but were found in berry fruits and jams. Phenolic compound (+-gallocatechin was found only in Marasca fruit and jam. Ellagic acid was found in the highest concentration in raspberry Willamette fruit and jam. Hydroxycinnamic acids (HCAs were found in all the investigated fruits, with the exception of a derivative of ferulic acid, which was not found in strawberry. Derivatives of caffeic, p-coumaric and chlorogenic acids were found in all the investigated fruits, with chlorogenic acid being the most abundant, especially in sour cherry Marasca. Volatiles were determined by gas chromatography (GC and expressed as the peak area of the identified compounds. All investigated volatiles of fresh fruit were also determined in the related jams with relatively high retention. Sour cherries Marasca and Oblačinska contained the same volatile compounds, but

De novo transcriptome assembly of a sour cherry cultivar, Schattenmorelle

Directory of Open Access Journals (Sweden)

Yeonhwa Jo

2015-12-01

Full Text Available Sour cherry (Prunus cerasus in the genus Prunus in the family Rosaceae is one of the most popular stone fruit trees worldwide. Of known sour cherry cultivars, the Schattenmorelle is a famous old sour cherry with a high amount of fruit production. The Schattenmorelle was selected before 1650 and described in the 1800s. This cultivar was named after gardens of the Chateau de Moreille in which the cultivar was initially found. In order to identify new genes and to develop genetic markers for sour cherry, we performed a transcriptome analysis of a sour cherry. We selected the cultivar Schattenmorelle, which is among commercially important cultivars in Europe and North America. We obtained 2.05 GB raw data from the Schattenmorelle (NCBI accession number: SRX1187170. De novo transcriptome assembly using Trinity identified 61,053 transcripts in which N50 was 611 bp. Next, we identified 25,585 protein coding sequences using TransDecoder. The identified proteins were blasted against NCBI's non-redundant database for annotation. Based on blast search, we taxonomically classified the obtained sequences. As a result, we provide the transcriptome of sour cherry cultivar Schattenmorelle using next generation sequencing.

Microbially-Enhanced Redox Solution Reoxidation for Sour Natural Gas Sweetening

Energy Technology Data Exchange (ETDEWEB)

Kenneth Brezinsky

2008-01-15

The specific objective of this project are to advance the technology and improve the economics of the commercial iron-based chelate processes such as LO-CAT II and SulFerox process utilizing biologically enhanced reoxidation of the redox solutions used in these processes. The project is based on the use of chelated ferric iron as the catalyst for the production of elemental sulfur, and then oxidizing bacteria, such as Thiobacillus Ferrooxidans (ATCC 23270) as an oxidizer. The regeneration of Fe{sup 3+} - chelate is accomplished by the use of these same microbes under mild conditions at 25-30 C and at atmospheric pressure to minimize the chelate degradation process. The pH of the redox solution was observed to be a key process parameter. Other parameters such as temperature, total iron concentration, gas to liquid ratio and bacterial cell densities also influence the overall process. The second part of this project includes experimental data and a kinetic model of microbial H{sub 2}S removal from sour natural gas using thiobacillus species. In the experimental part, a series of experiments were conducted with a commercial chelated iron catalyst at pH ranges from 8.7 to 9.2 using a total iron concentration range from 925 ppm to 1050 ppm in the solution. Regeneration of the solution was carried out by passing air through the solution. Iron oxidizing bacteria were used at cell densities of 2.3 x 10{sup 7}cells/ml for optimum effective performance. In the modeling part, oxidation of Fe{sup 2+} ions by the iron oxidizing bacteria - Thiobacillus Ferrooxidans was studied for application to a continuous stirred tank reactor (CSTR). The factors that can directly affect the oxidation rate such as dilution rate, temperature, and pH were analyzed. The growth of the microorganism was assumed to follow Monod type of growth kinetics. Dilution rate had influence on the rate of oxidation of ferrous iron. Higher dilution rates caused washout of the biomass. The oxidation rate was

Organic constituents in sour condensates from shale-oil and petroleum-crude runs at Sohio's Toledo refinery: identification and wastewater-control-technology considerations

Energy Technology Data Exchange (ETDEWEB)

Wingender, R J; Harrison, W; Raphaelian, L A

1981-02-01

Samples of sour condensate generated from the continuous processing of both crude shale oil and petroleum crude were collected and extracted with methylene chloride. The extracts were analyzed using capillary-column gas chromatography/mass spectrometry at Argonne National Laboratory and Radian Corporation. Qualitatively, the predominant types of organic compounds present in the shale-oil sour condensate were pyridines and anilines; semiquantitatively, these compounds were present at a concentration of 5.7 ppM, or about 78% of the total concentration of components detected. In contrast, straight-chain alkanes were the predominant types of compounds found in the sour condensate produced during isocracking of conventional crude oil. The approximate concentration of straight-chain alkanes, 8.3 ppM, and of other branched and/or unsaturated hydrocarbons, 6.8 ppM, amounted to 88% of the total concentration of components detected in the sour condensate from the petroleum-crude run. Nitrogen compounds in the shale-oil sour condensate may necessitate alterations of the sour water and refinery wastewater-treatment facilities to provide for organics degradation and to accommodate the potentially greater ammonia loadings. This would include use of larger amounts of caustic to enhance ammonia removal by steam stripping. Possible problems associated with biological removal of organic-nitrogen compounds should be investigated in future experimental shale-oil refining runs.

HPLC and MS/MS study of polar contaminants in a wetland adjoining a sour-gas plant

International Nuclear Information System (INIS)

Dickson, L.C.; Headley, J.V.; Peru, K.; Spiegel, K.; Gandrass, J.

1995-01-01

An analytical methodology was developed for target analyses and broad spectrum characterization of polar contaminants such as nitrogenous and organosulfur compounds in wetlands using the complementary techniques of HPLC with electrochemical (EC) detection and tandem MS with probe and electrospray ionization. Tandem MS was well suited for the identification and quantification of mixtures of polar compounds in water samples and soil extracts, while HPLC-EC provided sensitive detection of compounds transparent to MS detection and conventional methods. The usefulness of the methodology is demonstrated by studying the removal of polar contaminants from a wetland in western Canada affected by releases of hydrocarbon-rich condensate and free product from an adjoining sour-gas plant. The concern is that the mobile water-soluble polar contaminants may not be as efficiently attenuated by volatilization or adsorption processes as the more hydrophobic hydrocarbons and that some of the polar toxic compounds may break through to contaminate groundwater and surface waters. Samples of groundwater, surface water, and aqueous soil extracts were analyzed to quantify levels of polar contaminants in the presence of high concentrations of hydrocarbons. The use of water extracts reduced the background interference from hydrocarbons and other non-polar compounds that were present in the soil samples. HPLC-EC was used to quantify the target compounds that included monoethanolamine, diethanolamine and methyldiethanolamine and sulfolane-derived compounds while tandem MS was used to identify related compounds and degradation products. Influent concentrations were in the ppm range and discharge concentrations were in the ppb range

Using random event simulation to evaluate the effectiveness of indoor sheltering during a sour gas release

International Nuclear Information System (INIS)

Wilson, D.

2003-01-01

In the event of sour gas releases to the atmosphere, there is a strong bias toward evacuation rather than sheltering-in-place. This paper described the critical factors in decision-making for shelter-in-place versus evacuation. These include: delay time expected before release begins; size of potential release, explosion or fire; expected duration; direction to safety for evacuation; the air tightness of the building; and, the number of people in the emergency response zone. A shelter-in-place decision chart developed by the Canadian Association of Fire Chiefs was presented. It shows the usual bias toward evacuation as the default position. It also shows the greatest drawbacks of sheltering-in-place. The main factor in maintaining the effectiveness of the building shelter is the rate of air infiltration into the building. Other issues to consider include: reactive versus passive chemicals in the release; light versus heavy gas releases; building type (houses, high-rise apartments, office buildings, or warehouses); tightness of building construction; whether to turn the house heating and air conditioning on or off during shelter; daytime versus nighttime conditions; and, cost factors. Equations for calculating indoor and outdoor toxic exposure to decide on shelter versus evacuation were also presented. It was concluded that the absence of peak concentrations dramatically reduce the risk of fatality to people sheltering indoors. Keeping people indoors is the best way to assure their safety for the first hour following a toxic release. 8 refs., 6 figs

Increasing the capacity of the NEAG natural gas processing plants; Kapazitaetssteigerung der Erdgasaufbereitungsanlagen der NEAG

Energy Technology Data Exchange (ETDEWEB)

Rest, W.; Weiss, A. [Mobil Erdgas-Erdoel GmbH, Celle (Germany)

1998-12-31

The fact that new deposits of sour natural gas were found in the concessions at Scholen/Wesergebirgsvorland and that a sour gas pipeline was built from the BEB-operated field in South-Oldenburg increased the sour gas volume handled by the North German Natural Gas Processing Company (NEAG) so much, that capacities had to be stepped up. This paper describes the measures taken to increase capacities. Various interesting process engineering methods employed to remove bottlenecks in the parts of the plant are described in detail. These refer to the modification of the baffle plates in the high-pressure absorber of the Purisolwashers NEAG I, as well as in the expansion tank and the purified gas waher of the NEAG III washing plant as well as comprehensive modifications of the MODOP-flue gas scrubber NEAG III (orig.) [Deutsch] Neue Sauergasfunde in den Konzessionen Scholen/Wiehengebirgsvorland sowie der Bau der Sauergasverbindungsleitung aus dem von BEB operierten Feldesbereich Sued-Oldenburg haben die der Norddeutschen Erdgas-Aufbereitungsgesellschaft (NEAG) in Voigtei angebotenen Sauergasmengen soweit erhoeht, dass eine Kapazitaetserhoehung notwendig wurde. Im Rahmen des Vortrages werden die Massnahmen zur Kapazitaetssteigerung vorgestellt. Einige verfahrenstechnisch besonders interessante Loesungen zur Beseitigung von Engpaessen in Anlagenteilen werden detailliert beschrieben. Es handelt sich hierbei um die Modifikation der Einbauten im Hochdruckabsorber der Purisolwaesche NEAG I, im Entspannungsbehaelter und Reingaswaescher der Waesche NEAG III sowie umfangreiche Aenderungen im Bereich der MODOP-Abgasreinigungsanlage NEAG III. (orig.)

Sulfide stress corrosion study of a super martensitic stainless steel in H2S sour environments: Metallic sulfides formation and hydrogen embrittlement

Science.gov (United States)

Monnot, Martin; Nogueira, Ricardo P.; Roche, Virginie; Berthomé, Grégory; Chauveau, Eric; Estevez, Rafael; Mantel, Marc

2017-02-01

Thanks to their high corrosion resistance, super martensitic stainless steels are commonly used in the oil and gas industry, particularly in sour environments. Some grades are however susceptible to undergo hydrogen and mechanically-assisted corrosion processes in the presence of H2S, depending on the pH. The martensitic stainless steel EN 1.4418 grade exhibits a clear protective passive behavior with no sulfide stress corrosion cracking when exposed to sour environments of pH ≥ 4, but undergoes a steep decrease in its corrosion resistance at lower pH conditions. The present paper investigated this abrupt loss of corrosion resistance with electrochemical measurements as well as different physicochemical characterization techniques. Results indicated that below pH 4.0 the metal surface is covered by a thick (ca 40 μm) porous and defect-full sulfide-rich corrosion products layer shown to be straightforwardly related to the onset of hydrogen and sulfide mechanically-assisted corrosion phenomena.

Modelling souring in a high salinity reservoir

Energy Technology Data Exchange (ETDEWEB)

Adams, Michael; Crossland, Alan; Stott, Jim

2006-03-15

CAPCIS Ltd (Capcis) have developed a souring model for use in highly saline reservoirs where salinity limits the growth of sulphate reducing bacteria (SRB). Capcis have successfully applied the model to a field in North Africa. The conceptual basis of the model considers the course of the H2S from generation in the reservoir including dilution, sulphide retardation and scavenging and H2S fluid phase partitioning. At each stage mathematical equations governing the behaviour of the H2S were produced. In order to estimate the potential for H2S generation, it is required to know the chemistry of the injection and formation waters, as well as the properties of the indigenous SRB, i.e. the maximum salinity for their growth. This is determined by bottle testing of H2S generation by SRB at a range of injection/formation water ratios. The maximum salinity for SRB growth then determines the mixing ratios at which H2S generation takes place. Sulphide retardation due to adsorption at immobile interfaces was empirically modeled from reservoir data. Sulphide scavenging due to reaction with iron generated from corrosion was also modelled. Reservoir mineral scavenging was not modelled but could be incorporated in an extension to the model. Finally, in order to compute the gas-phase concentration of generated H2S, the H2S in the well stream is partitioned between the gas, oil and water phases. Capcis has carried out detailed computations of H2S solubility in crude oil and formation waters and the derivation of distribution ratios based on the respective partition coefficients using Gerard's line method, a modification of Henry's Law. (author) (tk)

New challenges in gas

Energy Technology Data Exchange (ETDEWEB)

Mandil, C. [Institut Francais du Petrole (IFP), 92 - Rueil-Malmaison (France); Chabrelie, M.F. [Cedigaz, 92 - Rueil Malmaison (France); Streicher, C. [Prosernat, 92 - Paris la Defense (France)] [and others

2003-07-01

New developments in the area of gas treatment will be to a large extent driven by the need to find appropriate solutions to the fundamental need of sustainable development. New gas treatment processes are developed with the aim to minimise contaminant emissions and meet most stringent environmental specifications. A new major challenge for the industry will be to implement new cost effective technologies for reducing CO{sub 2} emissions. Industry has also to minimise its costs, and therefore, in order to ensure at the same time a better protection of the environment and a better safety, it is necessary to innovate. The purpose of this seminar is precisely to identify better the innovations which are required in the area of gas treatment. These proceedings comprise 8 papers and a summary of the contributions to a round-table discussion dealing with the options for CO{sub 2} capture and sequestration. The presentations treat of: the future prospects for the gas industry (M.F. Chabrelie, Cedigaz); the solutions for offshore gas treatment (C. Streicher, Prosernat); gas treatment with membranes (H. Meyer, GTI); the Axens Multibed{sub TM} technology for natural gas treatment (G. Jochem, Axens); the potentials and applications for the Propure co-current contactors (F.P. Nilsen, ProPure); the production of very-sour and super-sour large gas reserves: the new challenges (F. Lallemand, TotalFinaElf); Hybrisol, a new gas treatment process for sour natural gases (F. Lecomte, IFP); and the conception and building of large acid-gas removal units (J. Castel, Technip-Coflexip). (J.S.)

Sour Taste preferences of children relate to preference of novel and intense stimuli

NARCIS (Netherlands)

Liem, D.G.; Westerbeek, A.; Wolterink, S.; Kok, F.J.; Graaf, de C.

2004-01-01

Previous research has suggested that some children have a preference for sour tastes. The origin of this preference remains unclear. We investigated whether preference for sour tastes is related to a difference in rated sour intensity due to physiological properties of saliva, or to an overall

Field demonstration of ex situ biological treatability of contaminated groundwater at the Strachan gas plant

International Nuclear Information System (INIS)

Kurz, M.D.; Stepan, D.J.

1997-03-01

A multi-phase study was conducted to deal with the issues of groundwater and soil contamination by sour gas processing plants in Alberta. Phase One consisted of a review of all soil and groundwater monitoring data submitted to Alberta Environment by sour gas plants in accordance with the Canadian Clean Water Act. The current phase involves the development, evaluation and demonstration of selected remediation technologies to address subsurface contamination of sediments and groundwater at sour gas treatment plants with special attention to the presence of natural gas condensate in the subsurface. Results are presented from a pilot-scale biological treatability test that was performed at the Gulf Strachan Natural Gas Processing Plant in Rocky Mountain House, Alberta, where contaminated groundwater from the plant was being pumped to the surface through many recovery wells to control contaminant migration. The recovered groundwater was directed to a pump-and-treat system that consisted of oil-water separation, iron removal, hardness removal, and air stripping, before being reinjected. The pilot-scale biological treatability testing was conducted to evaluate process stability in treating groundwater without pretreatment for iron and hardness reduction and to evaluate the removal of organic contaminants. Results of a groundwater characterization analysis are discussed. Chemical characteristics of the groundwater at the Strachan Gas Plant showed that an ex situ remediation technology would address the dissolved volatile and semi-volatile organic contamination from natural gas condensates, as well as the nitrogenous compounds resulting from the use of amine-based process chemicals. 4 refs., 5 tabs., 4 figs

Application of natural antimicrobial compounds for reservoir souring and MIC prevention in offshore oil and gas production systems

DEFF Research Database (Denmark)

Thomsen, Mette Hedegaard; Skovhus, Torben Lund; Mashietti, Marco

Offshore oil production facilities are subjectable to internal corrosion, potentially leading to human and environmental risk and significant economic losses. Microbiologically influenced corrosion (MIC) and reservoir souring - sulphide production by sulfate reducing microorganisms in the reservo...

Industrial processing effects on phenolic compounds in sour cherry (Prunus cerasus L.) fruit

NARCIS (Netherlands)

Toydemir, G.; Capanoglu, E.; Gomez-Roldan, M.V.; Vos, de R.C.H.; Boyacioglu, D.; Hall, R.D.; Beekwilder, M.J.

2013-01-01

The processed juice (or nectar) of the sour cherry, Prunus cerasus L., is widely consumed in the Balkan region and Turkey. Sour cherry is known to be rich in polyphenolic compounds, such as anthocyanins and procyanidins. In this work, the effects of processing of sour cherry fruit to nectar on

Surface Studies of Ultra Strength Drilling Steel after Corrosion Fatigue in Simulated Sour Environment

Energy Technology Data Exchange (ETDEWEB)

M. Ziomek-Moroz; J.A. Hawk; R. Thodla; F. Gui

2012-05-06

The Unites States predicted 60% growth in energy demand by 2030 makes oil and natural gas primary target fuels for energy generation. The fact that the peak of oil production from shallow wells (< 5000 m) is about to be reached, thereby pushing the oil and natural gas industry into deeper wells. However, drilling to depths greater than 5000 m requires increasing the strength-to weight ratio of the drill pipe materials. Grade UD-165 is one of the ultra- high yield strength carbon steels developed for ultra deep drilling (UDD) activities. Drilling UDD wells exposes the drill pipes to Cl{sup -}, HCO{sub 3}{sup -}/CO{sub 3}{sup 2-}, and H{sub 2}S-containig corrosive environments (i.e., sour environments) at higher pressures and temperatures compared to those found in conventional wells. Because of the lack of synergism within the service environment, operational stresses can result in catastrophic brittle failures characteristic for environmentally assisted cracking (EAC). Approximately 75% of all drill string failures are caused by fatigue or corrosion fatigue. Since there is no literature data on the corrosion fatigue performance of UD-165 in sour environments, research was initiated to better clarify the fatigue crack growth (FCGR) behavior of this alloy in UDD environments. The FCGR behavior of ultra-strength carbon steel, grade UD-165, was investigated by monitoring crack growth rate in deaerated 5%NaCl solution buffered with NaHCO{sub 3}/Na{sub 2}CO{sub 3} and in contact with H{sub 2}S. The partial pressure of H{sub 2}S (p{sub H2S}) was 0.83 kPa and pH of the solution was adjusted by NaOH to 12. The fatigue experiments were performed at 20 and 85 C in an autoclave with surface investigations augmented by scanning electron microscopy (SEM) and energy dispersive x-ray (EDX) spectroscopy. In this study, research focused on surface analyses supported by the fatigue crack growth rate measurements. Fig. 1 shows an SEM micrograph of the crack that propagated from the

The effect of produced water reinjection on reservoir souring in the Statfjord field

Energy Technology Data Exchange (ETDEWEB)

Bjoernestad, Eva Oe.; Sunde, Egil; Dinning, Anthony J.

2006-03-15

A produced water reinjection (PWRI) pilot test was performed in one well in the Statfjord field in the period 2000-2001. In order to establish the souring parameters and influence of PWRI in the near well area, the well was back flowed prior to PWRI, and at the end of the PWRI test period. Tracer was used for mass balance evaluations. After the PWRI pilot test was finished, the PWRI plant was upgraded at the Statfjord C platform and since 2003; two wells have been re injecting produced water. Nitrate has substituted biocides for corrosion control in the water injection system at the Statfjord B and Statfjord C platforms. Based on experience from other Statoil operated fields, nitrate will improve the corrosion control and in addition reduce the reservoir souring and hence the H2S production. In 2004, three wells were backflowed; a PWRI- injector, a seawater injector and a sea water injector with addition of nitrate. Results from the PWRI pilot test, showed that the sulphide production increased 17 times after PWRI in comparison with seawater injection. In the backflowing studies in 2004, water from the PWRI injector showed considerable higher H2S content (approximately 300 mg/l) than the well injecting only seawater (approximately 3-4 mg/l). The well injecting nitrate showed the lowest sulphide concentration in the backflowed fluids in comparison with the other wells (below 1 mg/l). This illustrates a significant increase in microbiological activity within the near injection area as a result of increased nutrient availability due to PWRI. The impact of PWRI in the lifetime of the Statfjord field has been evaluated and the PWRI strategy may be altered due to increases in souring. (Author)

27 CFR 25.192 - Removal of sour or damaged beer.

Science.gov (United States)

2010-04-01

... beer. 25.192 Section 25.192 Alcohol, Tobacco Products and Firearms ALCOHOL AND TOBACCO TAX AND TRADE BUREAU, DEPARTMENT OF THE TREASURY LIQUORS BEER Removals Without Payment of Tax Removal of Beer Unfit for Beverage Use § 25.192 Removal of sour or damaged beer. (a) Containers. The brewer shall remove sour or...

Antihyperlipidemic Effects of Sour Cherries Characterized by Different In Vitro Antioxidant Power and Polyphenolic Composition.

Science.gov (United States)

Papp, Nóra; Blázovics, Anna; Fébel, Hedvig; Salido, Sofía; Altarejos, Joaquín; Fehér, Erzsébet; Kocsis, Ibolya; Szentmihályi, Klára; Abrankó, László; Hegedűs, Attila; Stefanovits-Bányai, Éva

2015-12-01

The aims of the present study were to clarify in vivo effects of three sour cherry cultivars characterized by different polyphenolic composition in hyperlipidemic animals in a short term experiment. The three different sour cherry cultivars were chosen based on their total in vitro antioxidant capacity, total polyphenolic, monomeric anthocyanin and flavonoid content. Male Wistar rats were divided randomly into eight groups: rats kept on normal diet (control) and normal diet supplied with sour cherry powder of one of the three cultivars; others were kept on fat-rich diet and fat-rich diet supplied with sour cherry powder prepared from one of the three cultivars. The treatment lasted 10 days. Lyophilized sour cherry administered in the diet decreased both total cholesterol and LDL cholesterol levels, and increased the HDL cholesterol concentration in sera of hyperlipidemic animals. Significant differences were found in the efficacy of different sour cherry cultivars in case of hyperlipidemia. Sour cherries characterized by higher polyphenol content seem to have a more pronounced effect on serum cholesterol levels. Our results suggest that besides anthocyanins, colourless polyphenols also have lipid lowering effect.

Effect of adding sour yoghurt and dough as bacterial inoculant on ...

African Journals Online (AJOL)

Inoculation of whole-crop corn with sourdough and sour yoghurt significantly decreased pH, ash content and ammonia nitrogen, while dry matter determined using toloen distillation (DMT), Flieg point, crude protein (CP), and total nitrogen increased (P<0.05). Key words: Silage, sour yoghurt, sourdough, corn forage.

Advanced technologies for manufacturing high strength sour grade UOE line pipe

Energy Technology Data Exchange (ETDEWEB)

Kobayashi, Kenji; Omura, Tomohiko; Takahashi, Nobuaki; Minato, Izuru; Yamamoto, Akio [Sumitomo Metal Industries, Ltd., Kashima, (Japan)

2010-07-01

A new kind of high strength pipeline has been manufactured for sour service in offshore pipelines. This paper first presents a review of developments in manufacturing technology to improve sour resistance. This was particularly the case with Grade UOE line pipe. The improvement was achieved by optimizing the continuous casting process, monitoring the shape of inclusions (such as MnS, CaS, Al2O3, CaO-Al2O3) and decreasing coarse precipitates (Nb(C,N), TiN). The study then used the HIC evaluation method to determine hydrogen induced cracking (HIC) resistance of the material and HAZ test for sulfide stress cracking (SSC) resistance. The evaluation of the NACE TM0284 solution A showed that these pipelines are able to resist severe sour conditions because of good HIC and SSC resistance. Optimizing others components like alloying elements and the ACC process would improve sour resistance in future applications.

Unstable well behaviour in gas well liquid loading

NARCIS (Netherlands)

Belfroid, S.P.C.; Wijhe, A. van

2017-01-01

Liquid loading is the mechanism that is associated with increased liquid hold-up and liquid back flow at lower gas flow rates in gas production wells. In laboratory, most liquid loading experiments are performed at fixed gas and liquid rates (mass flow controlled). In the field, the well behavior is

The Researches on Reasonable Well Spacing of Gas Wells in Deep and low Permeability Gas Reservoirs

Science.gov (United States)

Bei, Yu Bei; Hui, Li; Lin, Li Dong

2018-06-01

This Gs64 gas reservoir is a condensate gas reservoir which is relatively integrated with low porosity and low permeability found in Dagang Oilfield in recent years. The condensate content is as high as 610g/m3. At present, there are few reports about the well spacing of similar gas reservoirs at home and abroad. Therefore, determining the reasonable well spacing of the gas reservoir is important for ensuring the optimal development effect and economic benefit of the gas field development. This paper discusses the reasonable well spacing of the deep and low permeability gas reservoir from the aspects of percolation mechanics, gas reservoir engineering and numerical simulation. considering there exist the start-up pressure gradient in percolation process of low permeability gas reservoir, this paper combined with productivity equation under starting pressure gradient, established the formula of gas well spacing with the formation pressure and start-up pressure gradient. The calculation formula of starting pressure gradient and well spacing of gas wells. Adopting various methods to calculate values of gas reservoir spacing are close to well testing' radius, so the calculation method is reliable, which is very important for the determination of reasonable well spacing in low permeability gas reservoirs.

Some effects of winter grazing of Dohne sour veld | PF | African ...

African Journals Online (AJOL)

The utilisation of spared sour veld poses practical problems. As a result of the development of high level protein or nitrogen supplements it has however become possible to efficiently graze spared veld. Results of experiments during three winters where spared sour veld was grazed off either by sheep or by cattle are given.

Efficacy of gaseous ozone to counteract postharvest table grape sour rot.

Science.gov (United States)

Pinto, L; Caputo, L; Quintieri, L; de Candia, S; Baruzzi, F

2017-09-01

This work aims at studying the efficacy of low doses of gaseous ozone in postharvest control of the table grape sour rot, a disease generally attributed to a consortium of non-Saccharomyces yeasts (NSY) and acetic acid bacteria (AAB). Sour rot incidence of wounded berries, inoculated with 8 NSYstrains, or 7 AAB, or 56 yeast-bacterium associations, was monitored at 25 °C up to six days. Sour rot incidence in wounded berries inoculated with yeast-bacterium associations resulted higher than in berries inoculated with one single NSY or AAB strain. Among all NSY-AAB associations, the yeast-bacterium association composed of Candida zemplinina CBS 9494 (Cz) and Acetobacter syzygii LMG 21419 (As) showed the highest prevalence of sour rot; thus, after preliminary in vitro assays, this simplified As-Cz microbial consortium was inoculated in wounded berries that were stored at 4 °C for ten days under ozone (2.14 mg m -3 ) or in air. At the end of cold storage, no berries showed sour-rot symptoms although ozonation mainly affected As viable cell count. After additional 12 days at 25 °C, the sour rot index of inoculated As-Cz berries previously cold-stored under ozone or in air accounted for 22.6 ± 3.7% and 66.7 ± 4.5%, respectively. Molecular analyses of dominant AAB and NSY populations of both sound and rotten berries during post-refrigeration period revealed the appearance of new strains mainly belonging to Gluconobacter albidus and Hanseniaspora uvarum species, respectively. Cold ozonation resulted an effective approach to extend the shelf-life of table grapes also after cold storage. Copyright © 2017 Elsevier Ltd. All rights reserved.

Gas in your water well

International Nuclear Information System (INIS)

2011-03-01

In Alberta, the presence of carbon dioxide, methane or hydrogen sulphide in water wells is common. The aim of this paper is to provide information to private owners of water wells. It is stated in this document that spurting taps or a gurgling noise indicate that there is gas in your water well; you can determine which gas it is by collecting a sample and having it analyzed. In order to address the risks associated with the presence of gas in the water well, the well pit or well pump should be properly vented to avoid any oxygen deficiency in the atmosphere. It is also possible to get rid of the gas by lowering the pump intake. It is also mentioned that the development of coalbed methane in Alberta should not contaminate private wells since regulations aimed at avoiding this have been implemented. This paper provided useful information to help private owners manage the presence of gas in their water wells.

Measurement of fugitive emissions from gas processing plants in Alberta

Energy Technology Data Exchange (ETDEWEB)

Chambers, A. [Alberta Research Council, Edmonton, AB (Canada)

2004-07-01

This paper presents a new gas visualization camera created to detect leaks. An outline of the device's projected entry into the oil and gas industry was provided, and included: a demonstration of Differential Absorption Light Detection and Ranging (DIAL) and leak cameras to measure and reduce fugitive emissions; a comparison of DIAL measured emissions with estimated emissions; and a review of methods to measure particulate emissions. In addition, a background of gas leak visualisation technology was presented along with an an overview of DIAL and its results from sour gas plants. The results of a survey conducted in 2003 were presented, including leaks identified and repaired as well as a follow up leak survey. An analysis of pre and post-repair hydrocarbon emissions from the Deepcut area revealed a 60 per cent reduction with savings of $140,000 as well as additional savings from reduced carbon emissions. A similar survey conducted in another plant measured emissions from condensate tanks before and after cooler installation as well as from surrounding well sites, quantifying an 80 per cent reduction in methane emissions. Tasks identified for future research concerned particulate emissions and the development of Lidar methods which can currently identify particulates, but are not yet able to quantify them. Other tasks included a complete DIAL data workup and reporting; the quantification of both methane and carbon emissions reduction at a sour gas plant; a comparison of measured emissions with methods that estimate fugitives; and a complete review of particulate measurements. tabs, figs.

New highly divergent Plum pox virus isolates infecting sour cherry in Russia.

Science.gov (United States)

Chirkov, Sergei; Ivanov, Peter; Sheveleva, Anna; Zakubanskiy, Alexander; Osipov, Gennady

2017-02-01

Unusual Plum pox virus (PPV) isolates (named Tat isolates) were discovered on sour cherry (Prunus cerasus) in Russia. They failed to be recognized by RT-PCR using commonly employed primers specific to the strains C or CR (the only ones that proved able to infect sour cherry) as well as to the strains M and W. Some of them can be detected by RT-PCR using the PPV-D-specific primers P1/PD or by TAS-ELISA with the PPV-C-specific monoclonal antibody AC. Phylogenetic analysis of the 3'-terminal genomic region assigned the Tat isolates into the cluster of cherry-adapted strains. However, they grouped separately from the C and CR strains and from each other as well. The sequence divergence of the Tat isolates is comparable to the differences between the known PPV strains. They may represent new group(s) of cherry-adapted isolates which do not seem to belong to any known strain of the virus. Copyright © 2016. Published by Elsevier Inc.

5-HT3A -driven green fluorescent protein delineates gustatory fibers innervating sour-responsive taste cells: A labeled line for sour taste?

Science.gov (United States)

Stratford, J M; Larson, E D; Yang, R; Salcedo, E; Finger, T E

2017-07-01

Taste buds contain multiple cell types with each type expressing receptors and transduction components for a subset of taste qualities. The sour sensing cells, Type III cells, release serotonin (5-HT) in response to the presence of sour (acidic) tastants and this released 5-HT activates 5-HT 3 receptors on the gustatory nerves. We show here, using 5-HT 3A GFP mice, that 5-HT 3 -expressing nerve fibers preferentially contact and receive synaptic contact from Type III taste cells. Further, these 5-HT 3 -expressing nerve fibers terminate in a restricted central-lateral portion of the nucleus of the solitary tract (nTS)-the same area that shows increased c-Fos expression upon presentation of a sour tastant (30 mM citric acid). This acid stimulation also evokes c-Fos in the laterally adjacent mediodorsal spinal trigeminal nucleus (DMSp5), but this trigeminal activation is not associated with the presence of 5-HT 3 -expressing nerve fibers as it is in the nTS. Rather, the neuronal activation in the trigeminal complex likely is attributable to direct depolarization of acid-sensitive trigeminal nerve fibers, for example, polymodal nociceptors, rather than through taste buds. Taken together, these findings suggest that transmission of sour taste information involves communication between Type III taste cells and 5-HT 3 -expressing afferent nerve fibers that project to a restricted portion of the nTS consistent with a crude mapping of taste quality information in the primary gustatory nucleus. © 2017 Wiley Periodicals, Inc.

Gas, oil, and environmental biotechnology IV

Energy Technology Data Exchange (ETDEWEB)

Akin, C; Markuszewski, R; Smith, J [eds.; Institute of Gas Technology, Chicago, IL (United States)

1992-01-01

Contains 32 papers presented at the 4th international IGT symposium on gas, oil and environmental biotechnology. Topics covered were: hydrocarbon bioremediation; groundwater, soil and explosives bioremediation; gas and oil reservoir souring; and biodesulfurization. 2 papers have been abstracted separately.

Characteristic Value Method of Well Test Analysis for Horizontal Gas Well

Directory of Open Access Journals (Sweden)

Xiao-Ping Li

2014-01-01

Full Text Available This paper presents a study of characteristic value method of well test analysis for horizontal gas well. Owing to the complicated seepage flow mechanism in horizontal gas well and the difficulty in the analysis of transient pressure test data, this paper establishes the mathematical models of well test analysis for horizontal gas well with different inner and outer boundary conditions. On the basis of obtaining the solutions of the mathematical models, several type curves are plotted with Stehfest inversion algorithm. For gas reservoir with closed outer boundary in vertical direction and infinite outer boundary in horizontal direction, while considering the effect of wellbore storage and skin effect, the pseudopressure behavior of the horizontal gas well can manifest four characteristic periods: pure wellbore storage period, early vertical radial flow period, early linear flow period, and late horizontal pseudoradial flow period. For gas reservoir with closed outer boundary both in vertical and horizontal directions, the pseudopressure behavior of the horizontal gas well adds the pseudosteady state flow period which appears after the boundary response. For gas reservoir with closed outer boundary in vertical direction and constant pressure outer boundary in horizontal direction, the pseudopressure behavior of the horizontal gas well adds the steady state flow period which appears after the boundary response. According to the characteristic lines which are manifested by pseudopressure derivative curve of each flow period, formulas are developed to obtain horizontal permeability, vertical permeability, skin factor, reservoir pressure, and pore volume of the gas reservoir, and thus the characteristic value method of well test analysis for horizontal gas well is established. Finally, the example study verifies that the new method is reliable. Characteristic value method of well test analysis for horizontal gas well makes the well test analysis

Decision 99-27 application 1029022 - Petro-Canada Oil and Gas application to install compressors at the Wilson Creek gas plant and at LSD 3-19-43-4 W5M, Wilson Creek Field

International Nuclear Information System (INIS)

1999-11-01

Petro-Canada Oil and Gas applied to the Alberta Energy and Utilities Board (EUB) for approval to add two new compressors at the existing Wilson Creek sour gas processing facility, and to construct and operate a new sour gas compressor station in Alberta. The application was made pursuant to Section 26 (1)(b) of the Oil and Gas Conservation Act and Sections 7.001, 9.020, and 15.050 of the Oil and Gas Conservation Regulations. The applications and interventions were considered at a hearing at the Last West Hall, Rimbley, Alberta, commencing 7 April 1999. The issues concerning the applications were: the need for and location of the compressors, plant life, emissions, sulphur recovery, and noise. Petro-Canada will proceed with its commitment to local landowners to install and commission a sulphur recovery unit within 16 months of the date of this report. The sulphur recovery capability of the facility will meet guidelines defined in IL 88-13 for new sour gas plants based on either the current or an acceptable maximum daily inlet sulphur rate. Continuous-vent gas streams, including glycol regenerator, produced-water tank, and hydrocarbon condensate tank vents, at both the 3-29 compressor and at the Wilson Creek plant site will be burned in a flare or incinerator. Flare stacks at the 3-19 compressor site will be equipped with a suitable pilot and automatic igniter. The Wilson Creek plant flare system will be equipped with a suitable pilot, as well as automatic igniter and/or flame failure detection system. Petro-Canada will implement local ambient air quality monitoring and sound level monitoring consistent with its commitments to local landowners and regulatory requirements

Influence of ph on corrosion control of carbon steel by peroxide injection in sour water

Energy Technology Data Exchange (ETDEWEB)

Vieira, Martins Magda; Baptista, Walmar; Joia, Carlos Jose Bandeira de Mello [PROTEMP - PETROBRAS/CENPES, Cidade Universitaria, Quadra 7, Rio de Janeiro, CEP 21949-900 (Brazil); Ponciano, Gomes Jose Antonio da Cunha [Departamento de Engenharia Metalurgica e de Materiais-COPPE/UFRJ, Cidade Universitaria, Rio de Janeiro (Brazil)

2004-07-01

Sour hydrogen damage is considered the most important corrosive process in the light-ends recovery section of Fluid Catalytic Cracking Units (FCCU). Corrosion in this condition is due to heavy gas oil that originates great amount of contaminants, such as H{sub 2}S, NH{sub 3} and HCN. Hydrogen absorption is promoted by the presence of free cyanides in the environment. The attenuation of this process requires the use of some inhibitors, such as oxygen, hydrogen peroxide (H{sub 2}O{sub 2}) or commercial polysulfides. The effect of these compounds is to neutralize free cyanides (CN{sup -}) into thio-sulfides (SCN{sup -}). When peroxide injection is selected, cyanide concentration in sour water has been used as key parameter to start the peroxide introduction. However, the importance of pH in this system has been pointed out by many authors. The aim of this work is to investigate the influence of pH when peroxide injection is carried out in less alkaline conditions of sour water. Electrochemical techniques - like anodic polarization and hydrogen permeation tests - and weight loss measurements were used to evaluate the effectiveness of corrosion control of carbon steel. It was concluded that at pH 7.5 peroxide injection can drive to an increment of the corrosion rate. Besides that, it was concluded that hydrogen permeation into the metal is promoted. Both detrimental effects were due to elemental sulfur generation in this pH range. The adoption of pH as a key parameter for peroxide injection is then suggested. (authors)

21 CFR 131.160 - Sour cream.

Science.gov (United States)

2010-04-01

... CONSUMPTION MILK AND CREAM Requirements for Specific Standardized Milk and Cream § 131.160 Sour cream. (a... of analysis. Referenced methods in paragraph (c) (1) and (2) of this section are from “Official Methods of Analysis of the Association of Official Analytical Chemists,” 13th Ed. (1980), which is...

Great gas plants : these five natural gas processing facilities demonstrate decades of top-flight technology

Energy Technology Data Exchange (ETDEWEB)

Byfield, M.

2010-07-15

The natural gas purification and pipeline sector is a major economic driver in Canada. Gas processing facilities are growing in number, and several large gas projects are being planned for future construction in the western provinces. This article outlined 5 gas plants in order to illustrate the sector's history and breadth in Canada. The Shell Jumping Pound gas complex was constructed in 1951 after a sulfur-rich gas discovery near Calgary in 1944. The Empress Straddle plant was built in 1971 in southeastern Alberta and is one of the largest single industrial consumers of electrical power in the province. The Fort Nelson gas processing plant is North America's largest sour gas processing facility. The Shell Caroline complex was built 1993. The Sable offshore energy project is located on the coast of Nova Scotia to handle gas produced from the Thebaud wells. A consortium is now considering the development of new gas fields in the Sable area. 5 figs.

Acid Gas Removal from Natural Gas with Alkanolamines

DEFF Research Database (Denmark)

Sadegh, Negar

commercially for the removal of acid gas impurities from natural gas. Alkanolamines, simple combinations of alcohols and ammonia, are the most commonly used category of chemical solvents for acid gas capture. This Ph.D. project is aboutthermodynamics of natural gas cleaning process with alkanolamines......Some 40 % of the world’s remaining gas reserves are sour or acid, containing large quantities of CO2 and H2S and other sulfur compounds. Many large oil and gas fields have more than 10 mole % CO2 and H2S content. In the gas processing industry absorption with chemical solvents has been used...... pressure on acid gas solubility was also quantitatively investigated through both experimental and modeling approaches....

Organic acid profile of commercial sour cassava starch

Directory of Open Access Journals (Sweden)

DEMIATE I.M.

1999-01-01

Full Text Available Organic acids are present in sour cassava starch ("polvilho azedo" and contribute with organoleptic and physical characteristics like aroma, flavor and the exclusive baking property, that differentiate this product from the native cassava starch. Samples of commercial sour cassava starch collected in South and Southeast Brazil were prepared for high performance liquid chromatography (HPLC analysis. The HPLC equipment had a Biorad Aminex HPX-87H column for organic acid analysis and a refractometric detector. Analysis was carried out with 0.005M sulfuric acid as mobile phase, 0.6ml/min flow rate and column temperature of 60° C. The acids quantified were lactic (0.036 to 0.813 g/100g, acetic (0 to 0.068 g/100g, propionic (0 to 0.013 g/100g and butyric (0 to 0.057 g/100g, that are produced during the natural fermentation of cassava starch. Results showed large variation among samples, even within the same region. Some samples exhibited high acid levels, mainly lactic acid, but in these neither propionic nor butyric acids were detected. Absence of butyric acid was not expected because this is an important component of the sour cassava starch aroma, and the lack of this acid may suggest that such samples were produced without the natural fermentation step.

Effective pollination period in "Oblačinska" sour cherry clones

Directory of Open Access Journals (Sweden)

Fotirić-Akšić Milica

2014-01-01

Full Text Available To obtain high yields there should be high flower density and fruit set in sour cherry (Prunus cerasus L. production. Furthermore, in order to ensure successful fertilization, there should be satisfactory stigma receptivity, rapid pollen tube growth along the style, as well as adequate ovule longevity. This manuscript presents the study of the effective pollination period (EPP of four ‘Oblačinska’ sour cherry clones (II/2, III/9, XI/3 and XIII/1 that differs in pollen germination, fruit set and yields. In order to estimate EPP, pollination was conducted in six different stages of flower development: balloon stage, 2 d before anthesis (-2, at anthesis (0, and 2, 4, 6 and 8 d after anthеsis (DAA. The initial (IFS and final fruit set (FFS were recorded under the field conditions. Alongside with this, the rate of pollen tubes growth in the style was observed with fluorescent microscopy. The experimental design was completely randomized, a two-factorial analysis of variance was carried out and individual testing was performed using LSD test (p ≤ 0.05; p ≤ 0.01. The experiment was set in triplicates. Regarding FFS, clones II/2 and III/9 showed the best results (p ≤ 0.01 in 4 and 6 DAA. The number of pollen tubes in the style of the pistil decreased with subsequent terms of pollination, while its number in the ovule increased up to sixth day after pollination, followed by a decline. Clones II/2 and III/9 showed EPP which lasted from 6 to 8 d, while EPP found in clone XI/3, lasted only 2 d. It is concluded that only clone having long EPP should be used as parents for creating new sour cherry cultivars. [Projekat Ministarstva nauke Republike Srbije, br. TR 31063 and FP7 Project AREA 316004

Effects of a sour bolus on the intramuscular electromyographic (EMG) activity of muscles in the submental region.

Science.gov (United States)

Palmer, Phyllis M; McCulloch, Timothy M; Jaffe, Debra; Neel, Amy T

2005-01-01

A sour bolus has been used as a modality in the treatment of oropharyngeal dysphagia based on the hypothesis that this stimulus provides an effective preswallow sensory input that lowers the threshold required to trigger a pharyngeal swallow. The result is a more immediate swallow onset time. Additionally, the sour bolus may invigorate the oral muscles resulting in stronger contractions during the swallow. The purpose of this investigation was to compare the intramuscular electromyographic activity of the mylohyoid, geniohyoid, and anterior belly of the digastric muscles during sour and water boluses with regard to duration, strength, and timing of muscle activation. Muscle duration, swallow onset time, and pattern of muscle activation did not differ for the two bolus types. Muscle activation time was more tightly approximated across the onsets of the three muscles when a sour bolus was used. A sour bolus also resulted in a stronger muscle contraction as evidenced by greater electromyographic activity. These data support the use of a sour bolus as part of a treatment paradigm.

Genetic and molecular characterization of three novel S-haplotypes in sour cherry (Prunus cerasus L.).

Science.gov (United States)

Tsukamoto, Tatsuya; Potter, Daniel; Tao, Ryutaro; Vieira, Cristina P; Vieira, Jorge; Iezzoni, Amy F

2008-01-01

Tetraploid sour cherry (Prunus cerasus L.) exhibits gametophytic self-incompatibility (GSI) whereby the specificity of self-pollen rejection is controlled by alleles of the stylar and pollen specificity genes, S-RNase and SFB (S haplotype-specific F-box protein gene), respectively. As sour cherry selections can be either self-compatible (SC) or self-incompatible (SI), polyploidy per se does not result in SC. Instead the genotype-dependent loss of SI in sour cherry is due to the accumulation of non-functional S-haplotypes. The presence of two or more non-functional S-haplotypes within sour cherry 2x pollen renders that pollen SC. Two new S-haplotypes from sour cherry, S(33) and S(34), that are presumed to be contributed by the P. fruticosa species parent, the complete S-RNase and SFB sequences of a third S-haplotype, S(35), plus the presence of two previously identified sweet cherry S-haplotypes, S(14) and S(16) are described here. Genetic segregation data demonstrated that the S(16)-, S(33)-, S(34)-, and S(35)-haplotypes present in sour cherry are fully functional. This result is consistent with our previous finding that 'hetero-allelic' pollen is incompatible in sour cherry. Phylogenetic analyses of the SFB and S-RNase sequences from available Prunus species reveal that the relationships among S-haplotypes show no correspondence to known organismal relationships at any taxonomic level within Prunus, indicating that polymorphisms at the S-locus have been maintained throughout the evolution of the genus. Furthermore, the phylogenetic relationships among SFB sequences are generally incongruent with those among S-RNase sequences for the same S-haplotypes. Hypotheses compatible with these results are discussed.

Identification of crude-oil components and microorganisms that cause souring under anaerobic conditions.

Science.gov (United States)

Hasegawa, R; Toyama, K; Miyanaga, K; Tanji, Y

2014-02-01

Oil souring has important implications with respect to energy resources. Understanding the physiology of the microorganisms that play a role and the biological mechanisms are both important for the maintenance of infrastructure and mitigation of corrosion processes. The objective of this study was to identify crude-oil components and microorganisms in oil-field water that contribute to crude-oil souring. To identify the crude-oil components and microorganisms that are responsible for anaerobic souring in oil reservoirs, biological conversion of crude-oil components under anaerobic conditions was investigated. Microorganisms in oil field water in Akita, Japan degraded alkanes and aromatics to volatile fatty acids (VFAs) under anaerobic conditions, and fermenting bacteria such as Fusibacter sp. were involved in VFA production. Aromatics such as toluene and ethylbenzene were degraded by sulfate-reducing bacteria (Desulfotignum sp.) via the fumarate-addition pathway and not only degradation of VFA but also degradation of aromatics by sulfate-reducing bacteria was the cause of souring. Naphthenic acid and 2,4-xylenol were not converted.

A large increase of sour taste receptor cells in Skn-1-deficient mice does not alter the number of their sour taste signal-transmitting gustatory neurons.

Science.gov (United States)

Maeda, Naohiro; Narukawa, Masataka; Ishimaru, Yoshiro; Yamamoto, Kurumi; Misaka, Takumi; Abe, Keiko

2017-05-01

The connections between taste receptor cells (TRCs) and innervating gustatory neurons are formed in a mutually dependent manner during development. To investigate whether a change in the ratio of cell types that compose taste buds influences the number of innervating gustatory neurons, we analyzed the proportion of gustatory neurons that transmit sour taste signals in adult Skn-1a -/- mice in which the number of sour TRCs is greatly increased. We generated polycystic kidney disease 1 like 3-wheat germ agglutinin (pkd1l3-WGA)/Skn-1a +/+ and pkd1l3-WGA/Skn-1a -/- mice by crossing Skn-1a -/- mice and pkd1l3-WGA transgenic mice, in which neural pathways of sour taste signals can be visualized. The number of WGA-positive cells in the circumvallate papillae is 3-fold higher in taste buds of pkd1l3-WGA/Skn-1a -/- mice relative to pkd1l3-WGA/Skn-1a +/+ mice. Intriguingly, the ratio of WGA-positive neurons to P2X 2 -expressing gustatory neurons in nodose/petrosal ganglia was similar between pkd1l3-WGA/Skn-1a +/+ and pkd1l3-WGA/Skn-1a -/- mice. In conclusion, an alteration in the ratio of cell types that compose taste buds does not influence the number of gustatory neurons that transmit sour taste signals. Copyright © 2017. Published by Elsevier B.V.

Sweet and sour taste preferences of children

NARCIS (Netherlands)

Liem, D.G.

2004-01-01

In the industrialized countries children have many foods to choose from, both healthy and unhealthy products, these choices mainly depend on children's taste preferences. The present thesis focused on preferences for sweet and sour taste of young children (4- to 12-years of age) living in the US and

Advanced Acid Gas Separation Technology for Clean Power and Syngas Applications

Energy Technology Data Exchange (ETDEWEB)

Amy, Fabrice [Air Products and Chemicals Inc., Allentown, PA (United States); Hufton, Jeffrey [Air Products and Chemicals Inc., Allentown, PA (United States); Bhadra, Shubhra [Air Products and Chemicals Inc., Allentown, PA (United States); Weist, Edward [Air Products and Chemicals Inc., Allentown, PA (United States); Lau, Garret [Air Products and Chemicals Inc., Allentown, PA (United States); Jonas, Gordon [Air Products and Chemicals Inc., Allentown, PA (United States)

2015-06-30

Air Products has developed an acid gas removal technology based on adsorption (Sour PSA) that favorably compares with incumbent AGR technologies. During this DOE-sponsored study, Air Products has been able to increase the Sour PSA technology readiness level by successfully operating a two-bed test system on coal-derived sour syngas at the NCCC, validating the lifetime and performance of the adsorbent material. Both proprietary simulation and data obtained during the testing at NCCC were used to further refine the estimate of the performance of the Sour PSA technology when expanded to a commercial scale. In-house experiments on sweet syngas combined with simulation work allowed Air Products to develop new PSA cycles that allowed for further reduction in capital expenditure. Finally our techno economic analysis of the use the Sour PSA technology for both IGCC and coal-to-methanol applications suggests significant improvement of the unit cost of electricity and methanol compared to incumbent AGR technologies.

Using Thermodynamics to Predict the Outcomes of Nitrate-Based Oil Reservoir Souring Control Interventions

Directory of Open Access Journals (Sweden)

Jan Dolfing

2017-12-01

Full Text Available Souring is the undesirable production of hydrogen sulfide (H2S in oil reservoirs by sulfate-reducing bacteria (SRB. Souring is a common problem during secondary oil recovery via water flooding, especially when seawater with its high sulfate concentration is introduced. Nitrate injection into these oil reservoirs can prevent and remediate souring by stimulating nitrate-reducing bacteria (NRB. Two conceptually different mechanisms for NRB-facilitated souring control have been proposed: nitrate-sulfate competition for electron donors (oil-derived organics or H2 and nitrate driven sulfide oxidation. Thermodynamics can facilitate predictions about which nitrate-driven mechanism is most likely to occur in different scenarios. From a thermodynamic perspective the question “Which reaction yields more energy, nitrate driven oxidation of sulfide or nitrate driven oxidation of organic compounds?” can be rephrased as: “Is acetate driven sulfate reduction to sulfide exergonic or endergonic?” Our analysis indicates that under conditions encountered in oil fields, sulfate driven oxidation of acetate (or other SRB organic electron donors is always more favorable than sulfide oxidation to sulfate. That predicts that organotrophic NRB that oxidize acetate would outcompete lithotrophic NRB that oxidize sulfide. However, sulfide oxidation to elemental sulfur is different. At low acetate HS− oxidation is more favorable than acetate oxidation. Incomplete oxidation of sulfide to S0 is likely to occur when nitrate levels are low, and is favored by low temperatures; conditions that can be encountered at oil field above-ground facilities where intermediate sulfur compounds like S0 may cause corrosion. These findings have implications for reservoir management strategies and for assessing the success and progress of nitrate-based souring control strategies and the attendant risks of corrosion associated with souring and nitrate injection.

Bioactivity of sour cherry cultivars grown in Denmark

DEFF Research Database (Denmark)

Khoo, Gaik Ming; Clausen, Morten Rahr; Pedersen, Bjarne Hjelmsted

2012-01-01

Thirty four varieties of sour cherries (Prunus cerasus) were investigated for their total antioxidant activity, Caco-2 cancer cell proliferation inhibitory activity and effect on prostaglandin E2 (PGE2) production. Total phenolic content, oxygen radical absorbance capacity (ORAC) and cancer cell ...

Reservoir Souring - Latest developments for application and mitigation

DEFF Research Database (Denmark)

Johnson, Richard J; Folwell, Benjamin D; Wirekoh, Alexander

2017-01-01

Sulphate-reducing prokaryotes (SRP) have been identified in oil field fluids since the 1920s. SRP reduce sulphate to sulphide, a toxic and corrosive species that impacts on operational safety, metallurgy and both capital and operational cost. Differences in water cut, temperature, pressure...... and fluid chemistry can impact on the observed H2S concentration, meaning that an increase in H2S concentration does not always correlate with activity of SRP. However it wasn't until the 1990s that SRP activity was accepted as the leading cause of reservoir souring (i.e. an increase in H2S concentrations...... to reservoir souring. This has led to some recent advances in microbial control and detection, however, despite this, many of the methods used routinely for microbial control and detection are over a century old. We therefore look towards emerging and novel mitigation technologies that may be used...

CO{sub 2} storage in the geological ground: Integrity of drilling acceptable for CSEGR (Carbon Sequestration with Enhanced Gas Recovery); CO{sub 2} Lagerung im Geogrund: Bohrungsintegritaet akzeptabel fuer CSEGR (Carbon Sequestration with Enhanced Gas Recovery)

Energy Technology Data Exchange (ETDEWEB)

Reinicke, K.M.; Franz, O. [Technische Univ. Clausthal (Germany). Inst. fuer Erdoel- und Erdgastechnik

2008-10-23

With respect to the handling of carbon dioxide, there exist long-standing experiences in the industry (a) for the injection of carbon dioxide in petroleum deposits in the context of EOR measures (EOR = Enhanced Oil Recovery); (b) for the production of high pressure sour gas from petroleum deposits and (c) for the injection of hydrogen sulfide and carbon dioxide from the production of sour gas. Extensive information about arising failure processes and consequences was compiled and used for the development of the sour gas technology. With employment of this technology, no fundamental problems are to be expected in order to guarantee a safe injection and production during the operation phase. The authors of the contribution under consideration report on the state of the art so far it is relevant for the guarantee of the drilling integrity under influence of carbon dioxide. Recommendations for the guarantee and the proof are given to the mechanical integrity for new drillings, old drillings, filled drillings and monitoring.

Music to Make Your Mouth Water? Assessing the Potential Influence of Sour Music on Salivation

Science.gov (United States)

Wang, Qian J.; Knoeferle, Klemens; Spence, Charles

2017-01-01

People robustly associate various sound attributes with specific smells/tastes, and soundtracks that are associated with specific tastes can influence people’s evaluation of the taste of food and drink. However, it is currently unknown whether such soundtracks directly impact the eating experience via physiological changes (an embodiment account), or whether they act at a higher cognitive level, or both. The present research assessed a version of the embodiment account, where a soundtrack associated with sourness is hypothesized to induce a physiological response in the listener by increasing salivary flow. Salivation was measured while participants were exposed to three different experimental conditions – a sour soundtrack, a muted lemon video showing a man eating a lemon, and a silent baseline condition. The results revealed that salivation during the lemon video condition was significantly greater than in the sour soundtrack and baseline conditions. However, contrary to our hypothesis, there was no significant difference between salivation levels in the sour soundtrack compared to the baseline condition. These results are discussed in terms of potential mechanisms underlying the auditory modulation of taste perception/evaluation. PMID:28491044

Condensed Rotational Separation to upgrade sour gas

NARCIS (Netherlands)

Brouwers, J.J.H.; Kemenade, van H.P.

2010-01-01

A steadily increasing amount of newly located natural gas fields is severely contaminated with CO2 and/or H2S. Percentages of 30 % CO2/H2S or even larger are not uncommon. Fields with such high degrees of contaminant can not be economically exploited by conventional techniques based on amine

Beef herd health and productivity and exposure to the petroleum industry in west-central Alberta

Energy Technology Data Exchange (ETDEWEB)

Waldner, C. L.

1999-07-01

Health and productivity of cow-calf herds surrounding a new sour gas processing plant have been monitored from the fall of 1991 through to the calfing season in 1997. No significant change in the risk of non-pregnancy, abortion, stillbirth, calf mortality, median calfing date or crude weaning date have been found. There was measurable improvement in average age-adjusted weight for both male and female calves. Exposure to hydrogen sulfide and the complex mixture of compounds found in emissions from sour gas processing plants did not appear to have affected productivity parameters across the cow-calf production cycles examined, although there have been five examples of positive association between increasing exposure to total sulfation and decreased productivity. Increased risk of non-pregnancy was occasionally observed to be associated with one or more of sour flaring battery facilities, all battery flaring sites, active gas wells, and larger field facilities, however, these associations were not consistent among years . Risk of abortions did not increase with proximity of facilities or flaring. Examples of positive correlation were observed between volume of sour gas flared from battery sites and increased risk of stillbirth, sour gas and increased calf mortality, and exposure to oil well or all well sites and increased productivity.

Well log characterization of natural gas-hydrates

Science.gov (United States)

Collett, Timothy S.; Lee, Myung W.

2012-01-01

In the last 25 years there have been significant advancements in the use of well-logging tools to acquire detailed information on the occurrence of gas hydrates in nature: whereas wireline electrical resistivity and acoustic logs were formerly used to identify gas-hydrate occurrences in wells drilled in Arctic permafrost environments, more advanced wireline and logging-while-drilling (LWD) tools are now routinely used to examine the petrophysical nature of gas-hydrate reservoirs and the distribution and concentration of gas hydrates within various complex reservoir systems. Resistivity- and acoustic-logging tools are the most widely used for estimating the gas-hydrate content (i.e., reservoir saturations) in various sediment types and geologic settings. Recent integrated sediment coring and well-log studies have confirmed that electrical-resistivity and acoustic-velocity data can yield accurate gas-hydrate saturations in sediment grain-supported (isotropic) systems such as sand reservoirs, but more advanced log-analysis models are required to characterize gas hydrate in fractured (anisotropic) reservoir systems. New well-logging tools designed to make directionally oriented acoustic and propagation-resistivity log measurements provide the data needed to analyze the acoustic and electrical anisotropic properties of both highly interbedded and fracture-dominated gas-hydrate reservoirs. Advancements in nuclear magnetic resonance (NMR) logging and wireline formation testing (WFT) also allow for the characterization of gas hydrate at the pore scale. Integrated NMR and formation testing studies from northern Canada and Alaska have yielded valuable insight into how gas hydrates are physically distributed in sediments and the occurrence and nature of pore fluids(i.e., free water along with clay- and capillary-bound water) in gas-hydrate-bearing reservoirs. Information on the distribution of gas hydrate at the pore scale has provided invaluable insight on the mechanisms

Music to Make Your Mouth Water? Assessing the Potential Influence of Sour Music on Salivation

Directory of Open Access Journals (Sweden)

Qian J. Wang

2017-04-01

Full Text Available People robustly associate various sound attributes with specific smells/tastes, and soundtracks that are associated with specific tastes can influence people’s evaluation of the taste of food and drink. However, it is currently unknown whether such soundtracks directly impact the eating experience via physiological changes (an embodiment account, or whether they act at a higher cognitive level, or both. The present research assessed a version of the embodiment account, where a soundtrack associated with sourness is hypothesized to induce a physiological response in the listener by increasing salivary flow. Salivation was measured while participants were exposed to three different experimental conditions – a sour soundtrack, a muted lemon video showing a man eating a lemon, and a silent baseline condition. The results revealed that salivation during the lemon video condition was significantly greater than in the sour soundtrack and baseline conditions. However, contrary to our hypothesis, there was no significant difference between salivation levels in the sour soundtrack compared to the baseline condition. These results are discussed in terms of potential mechanisms underlying the auditory modulation of taste perception/evaluation.

Meet the biologists: Sour gas treatment uses biology rather than chemistry to clean things up

Energy Technology Data Exchange (ETDEWEB)

Budd, G.

2003-03-01

Basic elements of the new bio-desulfurization technology are described. The new process uses the commonly occurring bacterium, Thiobacillus, rather than chemical means to remove hydrogen sulfide from natural gas. Development of the process began some ten years ago in the Netherlands as a means to clean sewage water and purify water for beer. The application of removing hydrogen sulfide from natural gas evolved upon discovery that the process was able to convert hydrogen sulfide to sulfur. Key to the bio-desulfurization process is the Thiobacillus bacterium, which unlike other plant forms, relies on chemosynthesis (instead of photosynthesis) of hydrogen sulfide, oxygen and carbon dioxide for its energy requirements. The technology has applications in refineries as well as in gas processing plants. It is well suited for use in Canada where operations tend to be on the small scale (less than 50 tonnes per day). The portable unit can be moved to another location when production at a given well drops off.

In Vivo Fast Induction of Homogeneous Autopolyploids via Callus in Sour Jujube (Ziziphus acidojujuba Cheng et Liu

Directory of Open Access Journals (Sweden)

Qinghua Shi

2016-05-01

Full Text Available Polyploidization has been demonstrated as a very effective approach in fruit tree improvement. Sour jujube (Ziziphus acidojujuba Cheng et Liu is a promising diploid wild, traditional fruit species (2n = 2x = 24 that is rich in vitamin C, which is the main rootstock of Chinese jujube (Z. jujuba Mill.. The novel method we developed for rapid in vivo induction of homogeneous autopolyploids (IVIHA via callus in Chinese jujube was first applied and further optimized in sour jujube. Under optimized conditions, an average of one pure autotetraploid shoot could be regenerated from one treated branch, thereby indicating a relatively high efficiency rate. A total of 9 pure autotetraploid genotypes were created, and one of these was released as a new cultivar named ‘Zhuguang’ in 2015. Moreover, unexpected octoploids and hexaploids were also simultaneously created and detected. The leaves of tetraploids were thicker, broader, and darker in color than those of the original diploids, whereas the leaf sizes of octoploids were much smaller compared to that of diploids. However, stoma size increased with the occurrence of ploidy, mainly from diploid to octoploid. The well grown ploidies of jujube included diploids, triploids, and tetraploids. Anatomical observation indicated that adventitious buds/shoots emerged from the callus that formed on the cut, which was then followed by the development of connective vascular tissues between the adventitious bud and the stock plant tissue. This study demonstrates the universality of the IVIHA method that was initially developed in Chinese jujube, as well as provides a foundation for high-efficiency pure polyploid induction in sour jujube.

Removing well bore liquid blockage by gas injection

International Nuclear Information System (INIS)

Ahmed, Tarek

2000-01-01

Gas condensate reservoirs have long presented production problems when the pressure around the well bore drops below the dew point pressure. The formation of the condensate around the well bore can be thought of as an additional 'skin' that causes a reduction in the gas flow rates. Many processes have been used successfully to prevent or reduce the formation of liquids within the entire reservoir, such as pressure maintenance schemes and gas cycling processes. The pressure maintenance scheme is designed to keep the reservoir pressure at or above the dew point pressure while the gas cycling process is intended to reduce the liquid dropout by vaporization.Often times the pressure in the near-well bore region of the reservoir falls below the dew point pressure, while the pressure in the reservoir remains higher than the dew point pressure. As the near-well bore pressure drops below the dew point pressure, retrograde condensation occurs leading to the formation and then the mobilization of the condensate phase towards the producing wells. The liquid phase accumulates in the near Well bore region, forming a ring, which progressively reduces the gas deliverability. This study is designed to provide an insight into the mechanism of gas injection process in reducing gas-well productivity losses due to condensate blocking in the near well bore region. The study also evaluates the effectiveness of lean gas, N 2 , and CO 2 Huff 'n' Puff injection technique in removing the liquid dropout accumulation in and around the well bore. Results of the study show the importance of selecting the optimum injection volume and pressure. (author)

Mulher, cura e pajelança em Soure (Ilha do Marajó-PA).

OpenAIRE

Mayra Cristina Silva Faro; UEPA

2012-01-01

Neste trabalho pretendo apresentar alguns resultados de uma pesquisa que vem sendo realizada desde 2009 sobre a pajelança cabocla e as mulheres pajés na cidade de Soure, Ilha do Marajó/PA. Este estudo tem como objetivos analisar práticas e saberes de cura em Soure, e observar o papel da mulher no contexto religioso e simbólico da pajelança. Compreende-se pajelança cabocla como um conjunto de crenças e práticas de cura bastante difundida na Amazônia, em que encontram-se mesclados em graus vari...

Quality of sour cherry juice of different clones and cultivars (Prunus cerasus L.) determined by a combined sensory and NMR spectroscopic approach

DEFF Research Database (Denmark)

Clausen, Morten Rahr; Pedersen, Bjarne Hjelmsted; Bertram, Hanne Christine S.

2011-01-01

Juice was manufactured from seven different sour cherry clones/cultivars and evaluated by quantitative descriptive sensory analysis and 1H NMR spectroscopy. The sensory evaluation showed a large variation in several sensory attributes between the sour cherry clones/cultivars, which could be divided...... into two groups on the basis of both the sensory data and the NMR spectroscopic data. These groups were closely related to the genetic background of the clones. Kelleris clones were distinctly different from Stevnsberry and Fanal clones. Hence, 1H NMR spectroscopic data seem to correlate with sensory...... quality of different sour cherry clones. In addition, malic acid was the most important metabolite for modeling the two highly correlated sensory attributes sweetness and sourness, whereas the glucose content had a slight effect and the fructose content had no impact on sweetness/sourness. Other...

Decision 99-18: Range Petroleum Corporation application for a well licence, Sturgeon Lake Area

International Nuclear Information System (INIS)

1999-07-01

Range Petroleum Corporation (Range) applied to the Alberta Energy and Utilities Board (EUB) pursuant to Section 2.020 of the Oil and Gas Conservation Regulations for a well licence to drill a sour oil well from a surface location in Legal Subdivision 4, Section 34, West of the fifth Meridian, directionally to a bottom-hole location under Sturgeon Lake. The purpose of the proposed well would be to obtain sour oil production from the Leduc Formation. The well would be a Level 1 well because it would have a potential maximum hydrogen sulphide release rate of 0.0412 cubic m/s. The EUB received objections to the application from landowners, cattle ranchers, farmers, residents, and cottage owners in the area of the proposed well. The application and intervention were considered at a public hearing on 26 January 1999 in Grande Prairie, Alberta, and the Board viewed the proposed surface location, the previous Lds 3-2 surface location, and the surrounding area prior to the hearing. Having carefully considered the evidence, the Board believed that it would be possible to drill the proposed well safely and with minimal risk, subject to attached conditions. But in light of the unique setting of the area, including the residences and the road and lake configurations, and the difficulty that would exist preparing an effective environmental review process (ERP), the Board deferred its decision on the well licence application until an approved ERP is in place

Certain possible causes of between shaft gas seepage in gas wells

Energy Technology Data Exchange (ETDEWEB)

Shikhmamedov, N.S.

1981-01-01

Investigations for casing wells are carried out at the Turkmen branch of VNIIgaz (All Union petroleum and Gas Research Institute). The presence of high bottom hole pressure that affects further development of wells was established. Thus, for example, at the Shatlyk formation bottom hole pressures reach 138/sup 0/, and the temperature of the gas at the well head - 106/sup 0/C. Because of the heating process, the casing tubes lengthen, and as a result the euqipment at the well head is raised. Thus, at wells 42 and 312 the height of equipment's rise reaches 12 and 15 cm. respectively. Due to high bottom hole pressure temperatures grouting cement is necessary, one composed of 85% cement and 15% clay powder with a water-cement factor of up to 0.9, and density 1.57-1.60 g/cm/sup 3/. The necessity to create prelimnary casing tube tension was noted. The heated casing tubes must not be cooled during well damping. Wells with high gas temperature and presence of packer at bottom hole should have temperature elongation compensators.

Evaluation of maize-soybean flour blends for sour maize bread ...

African Journals Online (AJOL)

Properties examined included amylose content, bulk density, dispersibility, swelling power, water absorption capacity and viscoelastic properties. The effect of the different flour/meal samples on the properties of sour maize bread were evaluated by baking bread samples with the different flours/meals using a mixed starter ...

Reação da laranjeira azêda à tristeza Reaction of the sour orange plant to tristeza

Directory of Open Access Journals (Sweden)

A. S. Costa

1954-01-01

plantas sadias se desenvolvem mais ou menos satisfatòriamente quando sôbre-enxertadas em galhos de laranjeira doce sobre laranjeira azêda, já em avançado estado de declínio. Uma copa mista de laranjeiras azêda e doce sôbre cavalo de azêda pode causar alguns benefícios à planta afetada pela tristeza sob determinadas condições, mas êsse benefício não é duradouro e o método não oferece possibilidades práticas. A laranjeira azêda em viveiro tem sido utilizada com vantagem na determinação da presença do vírus da tristeza em borbulhas de vários tipos de Citrus, pela observação do crescimento feito a partir dessas borbulhas em comparação com aquêle de borbulhas da mesma variedade garantidamente sadias. Para a determinação da presença de estirpes fracas do vírus o método é mais demorado. Interenxertos de laranjeira azêda entre copas e raízes de laranjeira doce são suficientes para que haja manifestação de sintomas da moléstia. Há aparentemente alguma translocação através do interenxêrto, pois o desenvolvimento do cavalo abaixo e acima dele é aproximadamente igual.Young sour orange seedlings are more easily infected with the tristeza virus by approach-grafts than by means of the aphid vector. Under natural conditions adult plants in the field are highly resistant to infection by the aphid vector. Recovery of the tristeza virus from infected sour orange plants is also more easily accomplished by tissue union than by means of the aphid vector. Sour orange seedlings show yellowing of young leaves followed by stunting and shedding of leaves when infected with the ordinary strain of the tristeza virus in Brazil. These symptoms do not differ from those described for seedling yellows. The symptoms of leaf yellowing are less evident in plants infected with mild strains of the tristeza virus and there is subsequent recovery. New flushes of young leaves may show occasional vein dashes. Sour orange tissues below the bud union of the sweet

Source-Sink Relations in Fruits VII. Effects of Pruning in Sour Cherry and Plum

DEFF Research Database (Denmark)

Toldam-Andersen, Torben Bo; Hansen, P.

1993-01-01

Sour cherries cv. 'Stevnsbær' and plums cv. 'Victoria' were heavily pruned in 1987. Fruit samples were collected during the growing season and concentrations of different quality components were determined. Pruning resulted in a small increase in fruit size, the effect being greater on the older...... trees (sour cherries) or at the lower crop load (plum). Additionally, pruning decreased the con­centrations of total and soluble dry matter and of anthocya­nins ('Stevnsbær'), while titratable acids showed an increas­ing tendency. The effects of pruning are discussed based on influences on root...

Direct photothermal techniques for quantification of anthocyanins in sour cherry cultivars

NARCIS (Netherlands)

Doka, O.; Ficzek, G.; Bicanic, D.D.; Spruijt, R.B.; Luterotti, S.; Toth, M.; Buijnsters, J.G.; György Végvári, G.

2011-01-01

The analytical performance of the newly proposed laser-based photoacoustic spectroscopy (PAS) and of optothermal window (OW) method for quantification of total anthocyanin concentration (TAC) in five sour cherry varieties is compared to that of the spectrophotometry (SP). High performance liquid

A field demonstration of the microbial treatment of sour produced water

Energy Technology Data Exchange (ETDEWEB)

Sublette, K.L. [Univ. of Tulsa, OK (United States); Morse, D.; Raterman, K. [Amoco Production Co., Tulsa, OK (United States)

1995-12-31

The potential for detoxification and deodorization of sulfide-laden water (sour water) by microbial treatment was evaluated at a petroleum production site under field conditions. A sulfide-tolerant strain of the chemautotroph and facultative anaerobe, Thiobacillus denitrificans, was introduced into an oil-skimming pit of the Amoco Production Company LACT 10 Unit of the Salt Creek Field, Wyoming. Field-produced water enters this pit from the oil/water separation treatment train at an average flowrate of 5,000 bbl/D (795 m{sup 3}/D) with a potential maximum of 98,000 bbl/D (15,580 m{sup 3}/D). Water conditions at the pit inlet are 4,800 mg/l TDS, 100 mg/l sulfide, pH 7.8, and 107{degrees}F. To this water an aqueous solution of ammonium nitrate and diphosphorous pentoxide was added to provide required nutrients for the bacteria. The first 20% of the pit was aerated to a maximum depth of 5 ft (1.5 m) to facilitate the aerobic oxidation of sulfide. No provisions for pH control or biomass recovery and recycle were made. Pilot operations were initiated in October 1992 with the inoculation of the 19,000 bbl (3,020 m{sup 3}) pit with 40 lb (18.1 kg) of dry weight biomass. After a brief acclimation period, a nearly constant mass flux of 175 lb/D (80 kg/D) sulfide was established to the pit. Bio-oxidation of sulfide to elemental sulfur and sulfate was immediate and complete. Subsequent pilot operations focused upon process optimization and process sensitivity to system upsets. The process appeared most sensitive to large variations in sulfide loading due to maximum water discharge events. However, recoveries from such events could be accomplished within hours. This paper details all pertinent aspects of pilot operation, performance, and economics. Based on this body of evidence, it is suggested that the oxidation of inorganic sulfides by T denitrificans represents a viable concept for the treatment of sour water coproduced with oil and gas.

Shale-gas wells as virtual storage for supporting intermittent renewables

International Nuclear Information System (INIS)

Knudsen, Brage Rugstad; Foss, Bjarne

2017-01-01

Mature shale-gas wells possess a property that enables cyclic production and shut-in without incurring revenue losses. Based on this property, we suggest that fields with mature shale-gas wells may act as virtual gas storage for supplying fast-ramping gas power plants which balance intermittent renewable generation. By enabling gas supply to power plants to circumvent intermediate third-party storage, we argue that the proposed integration facilitates demand-driven gas production, and discuss how the scheme may support utilization of renewables and reduce supply-related greenhouse-gas emissions in electricity generation. - Highlights: • A novel integration strategy of shale gas and renewable electricity generation. • Mature shale-gas wells enable shut-ins without incurring revenue losses. • This property enables the use mature shale-gas wells as virtual gas storage. • Proposed scheme facilitates demand-driven gas production. • Omitting intermediate gas storage reduces GHG emissions from producer to end-user.

Detailed evaluation of gas hydrate reservoir properties using JAPEX/JNOC/GSC Mallik 2L-38 gas hydrate research well downhole well-log displays

Science.gov (United States)

Collett, T.S.

1999-01-01

The JAPEX/JNOC/GSC Mallik 2L-38 gas hydrate research well project was designed to investigate the occurrence of in situ natural gas hydrate in the Mallik area of the Mackenzie Delta of Canada. Because gas hydrate is unstable at surface pressure and temperature conditions, a major emphasis was placed on the downhole logging program to determine the in situ physical properties of the gas-hydrate-bearing sediments. Downhole logging tool strings deployed in the Mallik 2L-38 well included the Schlumberger Platform Express with a high resolution laterolog, Array Induction Imager Tool, Dipole Shear Sonic Imager, and a Fullbore Formation Microlmager. The downhole log data obtained from the log- and core-inferred gas-hydrate-bearing sedimentary interval (897.25-1109.5 m log depth) in the Mallik 2L-38 well is depicted in a series of well displays. Also shown are numerous reservoir parameters, including gas hydrate saturation and sediment porosity log traces, calculated from available downhole well-log and core data. The gas hydrate accumulation delineated by the Mallik 2L-38 well has been determined to contain as much as 4.15109 m3 of gas in the 1 km2 area surrounding the drill site.

SUBSTANTIATION OF STORAGE PARAMETERS OF THE SOUR-MILK INFANT DRINK «BIOLAKT»

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N. Tkachenko

2017-10-01

Full Text Available Changes in the quality indicators of sour-milk infant drink «Biolakt» characterized by high probiotic and immunomodulatory properties and low allergic effect that were made according to the improved technology and stored in sealed-off containers at temperature (4±2 ºС during 28 days have been studied: organoleptic properties of taste and odour, consistency and appearance; physical and chemical properties – titrated acidity, ºТ; active acidity, pH units; moisture retention property, %; microbiological properties – number of living cells of mixed cultures B. bifidum 1 + B. longum Я3 + B. infantis 512, CFU/cm3; the most probable number of living cells of monocultures L. acidophilus La-5, CFU/cm3; presence of coli form bacteria in 0.3 cm3; presence of  Salmonella in 50 cm3; biochemical properties – antioxidant activity, activity units; and maximum possible content of malondialdehyde at complete oxidation of the product ingredients, mg/100 g. It is proved that under indicated conditions in the course of 24 days the studied samples of target products possess high organoleptic and standardized for sour-milk infant drinks physical, chemical, biochemical and microbiological indicators and are, also, characterized by high content of probiotics: (0.43…8.60∙109 and (0.25…1.10∙109 CFU/cm3 of living cells of bifidus bacteria and lactobacilli, accordingly.It has been established that the limit storage period of sour-milk infant drink «Biolakt» produced according to the improved technology and stored at temperature (4±2 ºС should not exceed 12 days with due account of the safety margin for sour-milk infant drinks (provided they are kept in sealed-off containers.It has been proved that the target product formulas should include lactulose, polyunsaturated fatty acids omega-3 FT EU of «Fortitech» company (Denmark, vitamin complex FT 041081EU of «Fortitech» company (Denmark and/or complex of mineral substances FT 042836EU of �

Tail gas treatment of sour-SEWGS CO2 product. Public version

Energy Technology Data Exchange (ETDEWEB)

Van Dijk, H.A.J. [ECN Biomass and Energy Efficiency, Petten (Netherlands)

2012-06-15

This literature review covers the technologies suitable for the CO2-H2S separation within the context of CO2 purification of a pre-combustion captured stream intended for storage or reuse. The technologies considered cover existing industrially applied processes, emerging processes as well as processes in development. Several technologies capable of achieving the desired CO2-H2S separation were identified. Among them are liquid scrubbing processes Thiopaq and CrystaSulf producing elemental sulphur, selective oxidation to elemental sulphur such as MODOP or based on novel catalysts and sorbent-based (reactive) separations using low-, medium- or high-temperature (reactive) sorbents. SEWGS stands for Sorption Enhanced Water Gas Shift process.

Increased stray gas abundance in a subset of drinking water wells near Marcellus shale gas extraction.

Science.gov (United States)

Jackson, Robert B; Vengosh, Avner; Darrah, Thomas H; Warner, Nathaniel R; Down, Adrian; Poreda, Robert J; Osborn, Stephen G; Zhao, Kaiguang; Karr, Jonathan D

2013-07-09

Horizontal drilling and hydraulic fracturing are transforming energy production, but their potential environmental effects remain controversial. We analyzed 141 drinking water wells across the Appalachian Plateaus physiographic province of northeastern Pennsylvania, examining natural gas concentrations and isotopic signatures with proximity to shale gas wells. Methane was detected in 82% of drinking water samples, with average concentrations six times higher for homes gas wells (P = 0.0006). Ethane was 23 times higher in homes gas wells (P = 0.0013); propane was detected in 10 water wells, all within approximately 1 km distance (P = 0.01). Of three factors previously proposed to influence gas concentrations in shallow groundwater (distances to gas wells, valley bottoms, and the Appalachian Structural Front, a proxy for tectonic deformation), distance to gas wells was highly significant for methane concentrations (P = 0.007; multiple regression), whereas distances to valley bottoms and the Appalachian Structural Front were not significant (P = 0.27 and P = 0.11, respectively). Distance to gas wells was also the most significant factor for Pearson and Spearman correlation analyses (P gas wells was the only statistically significant factor (P gas (4)He to CH4 in groundwater were characteristic of a thermally postmature Marcellus-like source in some cases. Overall, our data suggest that some homeowners living gas wells have drinking water contaminated with stray gases.

Evaluation of the glycoside hydrolase activity of a Brettanomyces strain on glycosides from sour cherry (Prunus cerasus L.) used in the production of special fruit beers.

Science.gov (United States)

Daenen, Luk; Sterckx, Femke; Delvaux, Freddy R; Verachtert, Hubert; Derdelinckx, Guy

2008-11-01

The glycoside hydrolase activity of Saccharomyces cerevisiae and Brettanomyces custersii was examined on sour cherry (Prunus cerasus L.) glycosides with bound volatile compounds. Refermentations by the beta-glucosidase-negative S. cerevisiae strains LD25 and LD40 of sour cherry juice-supplemented beer demonstrated only a moderate increase of volatiles. In contrast, the beta-glucosidase-positive B. custersii strain LD72 showed a more pronounced activity towards glycosides with aliphatic alcohols, aromatic compounds and terpenoid alcohols. Important contributors to sour cherry aroma such as benzaldehyde, linalool and eugenol were released during refermentation as shown by analytical tools. A gradually increasing release was observed during refermentations by B. custersii when whole sour cherries, sour cherry pulp or juice were supplemented in the beer. Refermentations with whole sour cherries and with sour cherry stones demonstrated an increased formation of benzyl compounds. Thus, amygdalin was partially hydrolysed, and a large part of the benzaldehyde formed was mainly reduced to benzyl alcohol and some further esterified to benzyl acetate. These findings demonstrate the importance and interesting role of certain Brettanomyces species in the production of fruit lambic beers such as 'Kriek'.

Oil and gas products and energy equipment

International Nuclear Information System (INIS)

1996-01-01

The planned activities of the Canadian oil and gas products and energy equipment industry for 1996-1997, were presented. The sector is made up of approximately 1500 small and medium sized enterprises. The Canadian oil field manufacturing and servicing industry holds only a small 2.5% share of the world export market, but it is recognized internationally as one of the leading suppliers of advanced petroleum equipment. Their exports include specialized equipment for extracting oil sands, gathering and treatment facilities for sour gas, underbalanced drilling technologies, equipment for wells experiencing declining production rates, top motor drives, winter drilling rigs, and horizontal drilling technologies. They also offer petroleum industry software products. Most exploration and production equipment sold abroad by Canadian firms is manufactured in Canada, but there is an increasing trend toward manufacturing in the country of operation. 2 tabs

Effects of nitrate injection on microbial enhanced oil recovery and oilfield reservoir souring.

Science.gov (United States)

da Silva, Marcio Luis Busi; Soares, Hugo Moreira; Furigo, Agenor; Schmidell, Willibaldo; Corseuil, Henry Xavier

2014-11-01

Column experiments were utilized to investigate the effects of nitrate injection on sulfate-reducing bacteria (SRB) inhibition and microbial enhanced oil recovery (MEOR). An indigenous microbial consortium collected from the produced water of a Brazilian offshore field was used as inoculum. The presence of 150 mg/L volatile fatty acids (VFA´s) in the injection water contributed to a high biological electron acceptors demand and the establishment of anaerobic sulfate-reducing conditions. Continuous injection of nitrate (up to 25 mg/L) for 90 days did not inhibit souring. Contrariwise, in nitrogen-limiting conditions, the addition of nitrate stimulated the proliferation of δ-Proteobacteria (including SRB) and the associated sulfide concentration. Denitrification-specific nirK or nirS genes were not detected. A sharp decrease in water interfacial tension (from 20.8 to 14.5 mN/m) observed concomitantly with nitrate consumption and increased oil recovery (4.3 % v/v) demonstrated the benefits of nitrate injection on MEOR. Overall, the results support the notion that the addition of nitrate, at this particular oil reservoir, can benefit MEOR by stimulating the proliferation of fortuitous biosurfactant-producing bacteria. Higher nitrate concentrations exceeding the stoichiometric volatile fatty acid (VFA) biodegradation demands and/or the use of alternative biogenic souring control strategies may be necessary to warrant effective SRB inhibition down gradient from the injection wells.

The impact of past waste management practices on future tourist development. Turner Valley gas plant: A case study

International Nuclear Information System (INIS)

Hill, D.

1992-12-01

The reclamation of older sour gas plants in western Canada poses a number of problems as past production and waste management practices were not well documented, leading to a concern about possible soil and groundwater contamination. The Turner Valley Gas Plant, the oldest sour gas plant in Alberta, was examined as a site for an industrial museum. Production methods and waste disposal techniques were researched and documented, areas of environmental contamination were located and sampling regimes were established, and a site redevelopment concept was developed that would be sensitive to tourism needs, environmental concerns and reclamation requirements. Data were derived from government and company archives, airphotos, site visits, and interviews with former employees. A number of specific areas on the site requiring reclamation were identified, including areas where likely soil contamination with sulfur, hydrocarbons, mercury, polychlorinated biphenyls, or chromate exists. Methods that can be used to remediate soils and groundwater at the site at low cost are presented. The viability of an industrial museum is supported, with recommendations that the existing buildings be reused, the site be revegetated to reduce heat and dust, that underground hazards such as pits and tanks be buried, and visitor interest be encouraged. 49 refs., 32 figs., 2 tabs

Gas coning control for smart wells using a dynamic coupled well-reservoir simulator

NARCIS (Netherlands)

Leemhuis, A.P.; Nennie, E.D.; Belfroid, S.P.C.; Alberts, G.J.N.; Peters, E.; Joosten, G.J.P.

2008-01-01

A strong increase in gas inflow due to gas coning and the resulting bean-back because of Gas to Oil Ratio (GOR) constraints can severely limit oil production and reservoir drive energy. In this paper we will use a coupled reservoir-well model to demonstrate that oil production can be increased by

H2S and mercaptans in the air in the Molve gas field

International Nuclear Information System (INIS)

Vadjic, V.; Tomic, M.

1995-01-01

During the processing and refining of natural gas the working areas and ambient air can be polluted by emission of specific pollutants. The natural gas from gas and gas-condensate fields Molve, Stari Gradac and Kalinovac near Bjelovar in northern Croatia contains high levels of hydrogen sulphide and mercaptans. At the central gas station located in the gas field Molve the sour gas from all fields is collected and cleaned by absorption of sulphur compounds in K 2 CO 3 solution before emission to the atmosphere

A comparative study of the effect of green tea and sour tea on blood pressure and lipid profile in healthy adult men

Directory of Open Access Journals (Sweden)

Marzieh Kafeshani

2017-06-01

Full Text Available BACKGROUND: Cardiovascular diseases (CVD are a set of metabolic disorders affecting heart and blood vessels. Green tea and sour tea (Hibiscus sabdariffa L. have attracted significant attention recently due to their high popularity, nutrient profile and therapeutic effects. The aim of the present study was to compare the effects of green tea and sour tea supplementation on blood pressure and lipid profile in healthy adult men. METHODS: This randomized, double-blind, placebo-controlled trial included 54 healthy adult men. The participants were randomly assigned to two intervention groups receiving 450 mg green tea or sour tea and one placebo group which consumed 450 mg placebo (maltodextrin for 6 weeks. Blood pressure, lipid profile, dietary intake and physical activity were measured pre- and post-intervention and compared. RESULTS: After 6 weeks of intervention, sour tea supplementation led to a significant decrease in systolic blood pressure (SBP compared with the placebo group. However, we faild to find any significant difference in SBP between green tea and control groups. Also, no significant changes were observed in diastolic blood pressure (DBP and lipid profile between the three groups. In comparison with baseline, there was a significant increase in the mean level of serum high-density lipoprotein cholesterol (HDL-C in green tea and sour tea groups. Also, the interventions resulted in significant decrease in the mean levels of serum total cholesterol (TC and low-density lipoprotein cholesterol (LDL-C and DBP in the sour tea group compared with the pre-intervention value. CONCLUSION: On the basis of our findings, sour tea supplementation led to decreased SBP in healthy men compared with the placebo, but there was no significant difference between their effects on DBP and lipid profile. 

Degradation of Anthocyanin Content in Sour Cherry Juice During Heat Treatment

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Lilla Szalóki-Dorkó

2015-01-01

Full Text Available Sour cherry juices made from two sour cherry cultivars (Érdi bőtermő and Kántorjánosi 3, were investigated to determine their total anthocyanin content and half-life of anthocyanins during heat treatment at different temperatures (70, 80 and 90 °C for 4 h. Before the heat treatment, Érdi bőtermő juice had higher anthocyanin concentration (812 mg/L than Kántorjánosi 3 juice (513 mg/L. The greatest heat sensitivity of anthocyanins was measured at 90 °C, while the treatments at 80 and 70 °C caused lower thermal degradation. The loss of anthocyanins in Érdi bőtermő juice after treatment was 38, 29 and 18 %, respectively, while in Kántorjánosi 3 juice losses of 46, 29 and 19 % were observed, respectively. At 90 °C sour cherry Érdi bőtermő juice had higher half-life (t1/2 of anthocyanins, while the Kántorjánosi 3 juice had higher t1/2 values at 70 °C. Cyanidin-3-glucosyl-rutinoside was present in higher concentrations in both cultivars (Érdi bőtermő: 348 and Kántorjánosi 3: 200 mg/L than cyanidin-3-rutinoside (177 and 121 mg/L before treatment. However, during the experiment, cyanidin-3-rutinoside was proved to be more resistant to heat. Comparing the two varieties, both investigated pigment compounds were more stable in Kántorjánosi 3 than in Érdi bőtermő. Degradation rate of anthocyanins was cultivar-dependent characteristic, which should be taken into account in the food production.

Development of a novel processing system for efficient sour water stripping

International Nuclear Information System (INIS)

Kazemi, Abolghasem; Mehrabani-Zeinabad, Arjomand; Beheshti, Masoud

2017-01-01

Application of vapor recompression systems can result in enhanced energy efficiency and reduced energy requirements of distillation systems. In vapor recompression systems, temperature and dew point temperature of the top product of the column are increased through compression. By transferring heat from top to bottoms product, required boil up and reflux streams for the column are provided. In this paper, a new system is proposed for efficient stripping of sour water based on vapor recompression. Ammonia and H 2 S are the contaminants of sour water. Initially, based on a certain specifications of products, a sour water stripping system is implemented. A novel processing system is then developed and simulated to reduce utility requirements. The two processing systems are economically evaluated by Aspen Economic Evaluation software. There are 89.0% and 83.7% reduction of hot and cold utility requirements for the proposed system in comparison to the base processing system. However, the new processing system requires new equipment such as compressor and corresponding mechanical work that increases its capital and operating costs in comparison to the base case. However, the results indicate that the proposed system results in reduction of 11.4% of total annual costs and 14.9% of operating costs. - Highlights: • A novel system was developed for enhancement of performance of a distillation system based on vapor recompression. • In this system, utility streams are used for providing thermal energy. • A parametric study is carried out on the proposed processing system. • Applying the proposed system resulted in reduction of energy and utility requirements and costs of the separation process. • Environmental performance of the model was investigated.

Optimization of Sour Cherry Juice Spray Drying as
Affected by Carrier Material and Temperature

Science.gov (United States)

Zorić, Zoran; Pedisić, Sandra; Dragović-Uzelac, Verica

2016-01-01

Summary Response surface methodology was applied for optimization of the sour cherry Marasca juice spray drying process with 20, 30 and 40% of carriers maltodextrin with dextrose equivalent (DE) value of 4–7 and 13–17 and gum arabic, at three drying temperatures: 150, 175 and 200 °C. Increase in carrier mass per volume ratio resulted in lower moisture content and powder hygroscopicity, higher bulk density, solubility and product yield. Higher temperatures decreased the moisture content and bulk density of powders. Temperature of 200 °C and 27% of maltodextrin with 4–7 DE were found to be the most suitable for production of sour cherry Marasca powder. PMID:28115901

Volume fracturing of deep shale gas horizontal wells

Directory of Open Access Journals (Sweden)

Tingxue Jiang

2017-03-01

Full Text Available Deep shale gas reservoirs buried underground with depth being more than 3500 m are characterized by high in-situ stress, large horizontal stress difference, complex distribution of bedding and natural cracks, and strong rock plasticity. Thus, during hydraulic fracturing, these reservoirs often reveal difficult fracture extension, low fracture complexity, low stimulated reservoir volume (SRV, low conductivity and fast decline, which hinder greatly the economic and effective development of deep shale gas. In this paper, a specific and feasible technique of volume fracturing of deep shale gas horizontal wells is presented. In addition to planar perforation, multi-scale fracturing, full-scale fracture filling, and control over extension of high-angle natural fractures, some supporting techniques are proposed, including multi-stage alternate injection (of acid fluid, slick water and gel and the mixed- and small-grained proppant to be injected with variable viscosity and displacement. These techniques help to increase the effective stimulated reservoir volume (ESRV for deep gas production. Some of the techniques have been successfully used in the fracturing of deep shale gas horizontal wells in Yongchuan, Weiyuan and southern Jiaoshiba blocks in the Sichuan Basin. As a result, Wells YY1HF and WY1HF yielded initially 14.1 × 104 m3/d and 17.5 × 104 m3/d after fracturing. The volume fracturing of deep shale gas horizontal well is meaningful in achieving the productivity of 50 × 108 m3 gas from the interval of 3500–4000 m in Phase II development of Fuling and also in commercial production of huge shale gas resources at a vertical depth of less than 6000 m.

Sour and duke cherry viruses in South-West Europe

Directory of Open Access Journals (Sweden)

Rodrigo PÉREZ-SÁNCHEZ

2017-05-01

Full Text Available This study investigated the phytosanitary status of sour and duke cherry genetic resources in the Iberian Peninsula, and the incidence and leaf symptoms induced by the Prunus necrotic ringspot virus (PNRSV, Prune dwarf virus (PDV and Apple chlorotic leaf spot virus (ACLSV. Young leaf samples were taken from 204 sour and duke cherry trees belonging to ten cultivars, and were assayed by DAS-ELISA. Samples positive for any of the three viruses were also tested by RT-PCR. To associate the leaf symptoms with virus presence, 50 mature leaves from each infected tree were visually inspected during the summer. The ELISA and RT-PCR results indicated that 63% of the cherry trees were infected by at least one of these viruses. PNRSV occurred in all cultivars sampled and presented the highest infection rate (46%, followed by PDV (31% and ACLSV (6%. Many trees, (60 to 100%, were asymptomatic while harbouring single and mixed virus infections. The leaf symptoms associated with the viruses included chlorotic and dark brown necrotic ringspots on secondary veins and interveinal regions, for PNRSV, generalized chlorosis around the midveins, for PDV, chlorotic and reddish necrotic ringspots, for ACLSV, and generalized interveinal chlorosis, for mixed PNRSV and PDVinfections.

Metabolic Capability of a Predominant Halanaerobium sp. in Hydraulically Fractured Gas Wells and Its Implication in Pipeline Corrosion

Science.gov (United States)

Liang, Renxing; Davidova, Irene A.; Marks, Christopher R.; Stamps, Blake W.; Harriman, Brian H.; Stevenson, Bradley S.; Duncan, Kathleen E.; Suflita, Joseph M.

2016-01-01

Microbial activity associated with produced water from hydraulic fracturing operations can lead to gas souring and corrosion of carbon-steel equipment. We examined the microbial ecology of produced water and the prospective role of the prevalent microorganisms in corrosion in a gas production field in the Barnett Shale. The microbial community was mainly composed of halophilic, sulfidogenic bacteria within the order Halanaerobiales, which reflected the geochemical conditions of highly saline water containing sulfur species (S2O32-, SO42-, and HS-). A predominant, halophilic bacterium (strain DL-01) was subsequently isolated and identified as belonging to the genus Halanaerobium. The isolate could degrade guar gum, a polysaccharide polymer used in fracture fluids, to produce acetate and sulfide in a 10% NaCl medium at 37°C when thiosulfate was available. To mitigate potential deleterious effects of sulfide and acetate, a quaternary ammonium compound was found to be an efficient biocide in inhibiting the growth and metabolic activity of strain DL-01 relative to glutaraldehyde and tetrakis (hydroxymethyl) phosphonium sulfate. Collectively, our findings suggest that predominant halophiles associated with unconventional shale gas extraction could proliferate and produce sulfide and acetate from the metabolism of polysaccharides used in hydraulic fracturing fluids. These metabolic products might be returned to the surface and transported in pipelines to cause pitting corrosion in downstream infrastructure. PMID:27446028

Radical scavenging activities of Rio Red grapefruits and Sour orange fruit extracts in different in vitro model systems.

Science.gov (United States)

Jayaprakasha, G K; Girennavar, Basavaraj; Patil, Bhimanagouda S

2008-07-01

Antioxidant fractions from two different citrus species such as Rio Red (Citrus paradise Macf.) and Sour orange (Citrus aurantium L.) were extracted with five different polar solvents using Soxhlet type extractor. The total phenolic content of the extracts was determined by Folin-Ciocalteu method. Ethyl acetate extract of Rio Red and Sour orange was found to contain maximum phenolics. The dried fractions were screened for their antioxidant activity potential using in vitro model systems such as 1,1-diphenyl-2-picryl hydrazyl (DPPH), phosphomolybdenum method and nitroblue tetrazolium (NBT) reduction at different concentrations. The methanol:water (80:20) fraction of Rio Red showed the highest radical scavenging activity 42.5%, 77.8% and 92.1% at 250, 500 and 1000 ppm, respectively, while methanol:water (80:20) fraction of Sour orange showed the lowest radical scavenging activity at all the tested concentrations. All citrus fractions showed good antioxidant capacity by the formation of phosphomolybdenum complex at 200 ppm. In addition, superoxide radical scavenging activity was assayed using non-enzymatic (NADH/phenaxine methosulfate) superoxide generating system. All the extracts showed variable superoxide radical scavenging activity. Moreover, methanol:water (80:20) extract of Rio Red and methanol extract of Sour orange exhibited marked reducing power in potassium ferricyanide reduction method. The data obtained using above in vitro models clearly establish the antioxidant potential of citrus fruit extracts. However, comprehensive studies need to be conducted to ascertain the in vivo bioavailability, safety and efficacy of such extracts in experimental animals. To the best of our knowledge, this is the first report on antioxidant activity of different polar extracts from Rio Red and Sour oranges.

In-situ gas hydrate hydrate saturation estimated from various well logs at the Mount Elbert Gas Hydrate Stratigraphic Test Well, Alaska North Slope

Science.gov (United States)

Lee, M.W.; Collett, T.S.

2011-01-01

In 2006, the U.S. Geological Survey (USGS) completed detailed analysis and interpretation of available 2-D and 3-D seismic data and proposed a viable method for identifying sub-permafrost gas hydrate prospects within the gas hydrate stability zone in the Milne Point area of northern Alaska. To validate the predictions of the USGS and to acquire critical reservoir data needed to develop a long-term production testing program, a well was drilled at the Mount Elbert prospect in February, 2007. Numerous well log data and cores were acquired to estimate in-situ gas hydrate saturations and reservoir properties.Gas hydrate saturations were estimated from various well logs such as nuclear magnetic resonance (NMR), P- and S-wave velocity, and electrical resistivity logs along with pore-water salinity. Gas hydrate saturations from the NMR log agree well with those estimated from P- and S-wave velocity data. Because of the low salinity of the connate water and the low formation temperature, the resistivity of connate water is comparable to that of shale. Therefore, the effect of clay should be accounted for to accurately estimate gas hydrate saturations from the resistivity data. Two highly gas hydrate-saturated intervals are identified - an upper ???43 ft zone with an average gas hydrate saturation of 54% and a lower ???53 ft zone with an average gas hydrate saturation of 50%; both zones reach a maximum of about 75% saturation. ?? 2009.

Fruit and snack consumption related to sweet, sour and salty taste preferences

NARCIS (Netherlands)

Sijtsema, S.J.; Reinders, M.J.; Hiller, S.; Guardia, D.

2012-01-01

Purpose – To better understand fruit consumption and its determinants this paper aims to explore the relationship between the consumption of different types of fruit and other snacks and consumer taste preferences for sweet, salty and sour is explored. Design/methodology/approach – Respondents

Nuclear Well Log Properties of Natural Gas Hydrate Reservoirs

Science.gov (United States)

Burchwell, A.; Cook, A.

2015-12-01

Characterizing gas hydrate in a reservoir typically involves a full suite of geophysical well logs. The most common method involves using resistivity measurements to quantify the decrease in electrically conductive water when replaced with gas hydrate. Compressional velocity measurements are also used because the gas hydrate significantly strengthens the moduli of the sediment. At many gas hydrate sites, nuclear well logs, which include the photoelectric effect, formation sigma, carbon/oxygen ratio and neutron porosity, are also collected but often not used. In fact, the nuclear response of a gas hydrate reservoir is not known. In this research we will focus on the nuclear log response in gas hydrate reservoirs at the Mallik Field at the Mackenzie Delta, Northwest Territories, Canada, and the Gas Hydrate Joint Industry Project Leg 2 sites in the northern Gulf of Mexico. Nuclear logs may add increased robustness to the investigation into the properties of gas hydrates and some types of logs may offer an opportunity to distinguish between gas hydrate and permafrost. For example, a true formation sigma log measures the thermal neutron capture cross section of a formation and pore constituents; it is especially sensitive to hydrogen and chlorine in the pore space. Chlorine has a high absorption potential, and is used to determine the amount of saline water within pore spaces. Gas hydrate offers a difference in elemental composition compared to water-saturated intervals. Thus, in permafrost areas, the carbon/oxygen ratio may vary between gas hydrate and permafrost, due to the increase of carbon in gas hydrate accumulations. At the Mallik site, we observe a hydrate-bearing sand (1085-1107 m) above a water-bearing sand (1107-1140 m), which was confirmed through core samples and mud gas analysis. We observe a decrease in the photoelectric absorption of ~0.5 barnes/e-, as well as an increase in the formation sigma readings of ~5 capture units in the water-bearing sand as

SOUR CHERRY (Prunus cerasus L. GENETIC VARIABILITY AND PHOTOSYNTHETIC EFFICIENCY DURING DROUGHT

Directory of Open Access Journals (Sweden)

Marija Viljevac

2012-12-01

Full Text Available Sour cherry is an important fruit in Croatian orchards. Cultivar Oblačinska is predominant in existing orchards with noted intracultivar phenotypic heterogeneity. In this study, the genetic variability of 22 genotypes of cvs. Oblačinska, Maraska and Cigančica, as well as standard cvs. Kelleris 14, Kelleris 16, Kereška, Rexelle and Heimann conserved were investigated. Two types of molecular markers were used: microsatellite markers (SSR in order to identify intercultivar, and AFLP in order to identify intracultivar variabilities. A set of 12 SSR markers revealed small genetic distance between cvs. Maraska and Oblačinska while cv. Cigančica is affined to cv. Oblačinska. Furthermore, cvs. Oblačinska, Cigančica and Maraska were characterized compared to standard ones. AFLP markers didn`t confirm significant intracultivar variability of cv. Oblačinska although the variability has been approved at the morphological, chemical and pomological level. Significant corelation between SSR and AFLP markers was found. Identification of sour cherry cultivars tolerant to drought will enable the sustainability of fruit production with respect to the climate change in the future. For this purpose, the tolerance of seven sour cherry genotypes (cvs. Kelleris 16, Maraska, Cigančica and Oblačinska represented by 4 genotypes: OS, 18, D6 and BOR to drought conditions was tested in order to isolate genotypes with the desired properties. In the greenhouse experiment, cherry plants were exposed to drought stress. The leaf relative water content, OJIP test parameters which specify efficiency of the photosynthetic system based on measurements of chlorophyll a fluorescence, and concentrations of photo-synthetic pigments during the experiment were measured as markers of drought tolerance. Photosynthetic performance index (PIABS comprises three key events in the reaction centre of photosystem II affecting the photosynthetic activity: the absorption of energy

Sour gas injection for use with in situ heat treatment

Science.gov (United States)

Fowler, Thomas David [Houston, TX

2009-11-03

Systems, methods, and heaters for treating a subsurface formation are described herein. At least one method for providing acidic gas to a subsurface formation is described herein. The method may include providing heat from one or more heaters to a portion of a subsurface formation; producing fluids that include one or more acidic gases from the formation using a heat treatment process. At least a portion of one of the acidic gases may be introduced into the formation, or into another formation, through one or more wellbores at a pressure below a lithostatic pressure of the formation in which the acidic gas is introduced.

Decline curve based models for predicting natural gas well performance

Directory of Open Access Journals (Sweden)

Arash Kamari

2017-06-01

Full Text Available The productivity of a gas well declines over its production life as cannot cover economic policies. To overcome such problems, the production performance of gas wells should be predicted by applying reliable methods to analyse the decline trend. Therefore, reliable models are developed in this study on the basis of powerful artificial intelligence techniques viz. the artificial neural network (ANN modelling strategy, least square support vector machine (LSSVM approach, adaptive neuro-fuzzy inference system (ANFIS, and decision tree (DT method for the prediction of cumulative gas production as well as initial decline rate multiplied by time as a function of the Arps' decline curve exponent and ratio of initial gas flow rate over total gas flow rate. It was concluded that the results obtained based on the models developed in current study are in satisfactory agreement with the actual gas well production data. Furthermore, the results of comparative study performed demonstrates that the LSSVM strategy is superior to the other models investigated for the prediction of both cumulative gas production, and initial decline rate multiplied by time.

Investigations of corrosion films formed on API-X52 pipeline steel in acid sour media

Energy Technology Data Exchange (ETDEWEB)

Hernandez-Espejel, A. [Instituto Politecnico Nacional, Departamento de Ingenieria Metalurgica, IPN-ESIQIE, UPALM Ed. 7, Zacatenco 07738, Mexico, D.F. (Mexico); Dominguez-Crespo, M.A. [Instituto Politecnico Nacional, CICATA-Unidad Altamira-Tamaulipas, km 14.5, Carretera Tampico-Puerto Industrial Altamira, 89600 Altamira, Tamps (Mexico); Cabrera-Sierra, R. [Instituto Politecnico Nacional, Departamento de Ingenieria Quimica Industrial, IPN-ESIQIE, UPALM Ed. 7, Zacatenco 07738, Mexico, D.F. (Mexico); Rodriguez-Meneses, C. [Instituto Politecnico Nacional, Departamento de Ingenieria Metalurgica, IPN-ESIQIE, UPALM Ed. 7, Zacatenco 07738, Mexico, D.F. (Mexico); Arce-Estrada, E.M., E-mail: earce@ipn.m [Instituto Politecnico Nacional, Departamento de Ingenieria Metalurgica, IPN-ESIQIE, UPALM Ed. 7, Zacatenco 07738, Mexico, D.F. (Mexico)

2010-07-15

Corrosion films formed by voltammetry using different switching potentials and by immersion on API-X52 pipeline steel in simulated acid sour media (NACE ID182) have been characterized using Scanning Electron Microscopy (SEM), X-ray Diffraction (XRD), Linear Polarization and Electrochemical Impedance Spectroscopy (EIS) techniques. XRD and EDS analysis showed that the films are mainly composed of sulphide compounds (mackinawite, troilite, marcasite and pyrite) as well as iron oxides, as steel damage increases. Across SEM micrographs the corrosion films formed by potentiodynamic and immersion tests are very similar, covering most of the steel. Polarization and EIS results corroborate poor behavior against corrosion.

Investigations of corrosion films formed on API-X52 pipeline steel in acid sour media

International Nuclear Information System (INIS)

Hernandez-Espejel, A.; Dominguez-Crespo, M.A.; Cabrera-Sierra, R.; Rodriguez-Meneses, C.; Arce-Estrada, E.M.

2010-01-01

Corrosion films formed by voltammetry using different switching potentials and by immersion on API-X52 pipeline steel in simulated acid sour media (NACE ID182) have been characterized using Scanning Electron Microscopy (SEM), X-ray Diffraction (XRD), Linear Polarization and Electrochemical Impedance Spectroscopy (EIS) techniques. XRD and EDS analysis showed that the films are mainly composed of sulphide compounds (mackinawite, troilite, marcasite and pyrite) as well as iron oxides, as steel damage increases. Across SEM micrographs the corrosion films formed by potentiodynamic and immersion tests are very similar, covering most of the steel. Polarization and EIS results corroborate poor behavior against corrosion.

Genetic Diversity Assessment and Identification of New Sour Cherry Genotypes Using Intersimple Sequence Repeat Markers

Directory of Open Access Journals (Sweden)

Roghayeh Najafzadeh

2014-01-01

Full Text Available Iran is one of the chief origins of subgenus Cerasus germplasm. In this study, the genetic variation of new Iranian sour cherries (which had such superior growth characteristics and fruit quality as to be considered for the introduction of new cultivars was investigated and identified using 23 intersimple sequence repeat (ISSR markers. Results indicated a high level of polymorphism of the genotypes based on these markers. According to these results, primers tested in this study specially ISSR-4, ISSR-6, ISSR-13, ISSR-14, ISSR-16, and ISSR-19 produced good and various levels of amplifications which can be effectively used in genetic studies of the sour cherry. The genetic similarity among genotypes showed a high diversity among the genotypes. Cluster analysis separated improved cultivars from promising Iranian genotypes, and the PCoA supported the cluster analysis results. Since the Iranian genotypes were superior to the improved cultivars and were separated from them in most groups, these genotypes can be considered as distinct genotypes for further evaluations in the framework of breeding programs and new cultivar identification in cherries. Results also confirmed that ISSR is a reliable DNA marker that can be used for exact genetic studies and in sour cherry breeding programs.

Oil, Gas, and Injection Wells in Louisiana, Geographic NAD83, LDNR (2007) [oil_gas_wells_LDNR_2007

Data.gov (United States)

Louisiana Geographic Information Center — This is a point dataset containing the location of over 230,000 oil and gas and injection wells in the state of Louisiana. It was developed from the DNR Office of...

Wellhead gas compression extends life of beam-pumped wells

International Nuclear Information System (INIS)

Sherry, M.J.; Fairchild, P.W.

1992-01-01

This paper reports that operators of marginal oil and gas wells often can avoid having to shut them in by compressing gas from the back side of the casing at the well head and delivering it into the flowline. This process can reduce the back pressure at the face of the producing formation, which allows additional oil and gas to be produced and extends the economical reserves. Small, low-horsepower stationary compressors or a walking beam compressor (WBC) may be used for this purpose. A portable compressor test unit recently has been employed to evaluate wells that are possible candidates for wellhead compression as another cost cutting measure

[Health effects of sour cherries with unique polyphenolic composition in their fruits].

Science.gov (United States)

Hegedűs, Attila; Papp, Nóra; Blázovics, Anna; Stefanovitsné Bányai, Éva

2018-05-01

Health effects of fruit consumption are confirmed by many studies. Such effects are attributed to the polyphenolic compounds accumulating in fruit skin and mesocarp tissues. They contribute to the regulation on transcriptional, post-transcriptional and epigenetic levels. Since people consume much less fruits than the recommended quantities, a new approach includes the promotion of super fruits that are extremely rich sources of specific health compounds. A comparative analysis of Hungarian stone fruit cultivars detected a huge variability in fruit in vitro antioxidant capacity and total polyphenolic content. Two outstanding sour cherry cultivars ('Pipacs 1' and 'Fanal') were identified to accumulate elevated levels of polyphenolic compounds in their fruits. Sour cherries with different polyphenolic compositions were tested against alimentary induced hyperlipidemia using male Wistar rat model. Consumption of cherry fruit had different consequences for different cultivars: consumption of 'Pipacs 1' and 'Fanal' fruits resulted in 30% lower total cholesterol levels in the sera of hyperlipidemic animals after only 10 days of treatment. However, the consumption of 'Újfehértói fürtös' fruit has not induced significant alterations in the same parameter. Other lipid parameters also reflected the short-term beneficial effects of 'Pipacs 1' and 'Fanal' fruits. We suggest that not only some tropical and berry fruits might be considered as super fruits but certain genotypes of stone fruits as well. These have indeed marked physiological effects. Since 'Pipacs 1' and 'Fanal' are rich sources of colourless polyphenolics (e.g., phenolic acids and isoflavonoids) and anthocyanins, respectively, the protective effects associated with their consumption can be attributed to different polyphenolic compounds. Orv Hetil. 2018; 159(18): 720-725.

Method of determining the depth of gas entry into the lifter of a gas lift well

Energy Technology Data Exchange (ETDEWEB)

Mishalov, N F; Popov, V A

1981-01-01

A method is proposed for determining the depth of gas entry into the lifter of a gas lift well, based on the data for measuring downhole and effective pressures. The method is used when analyzing and selecting operating conditions for gas lift wells at the Pravdinsk field.

New oil and gas incentives in Saskatchewan

International Nuclear Information System (INIS)

Patel, B.

2003-01-01

Saskatchewan is Canada's second largest producer of crude oil and the third largest producer of natural gas with nearly 400 oil and gas companies operating in the province. The oil ranges from heavy sour to light sweet crude oil. Nearly half of the production is heavy oil, 30 per cent is medium oil and 20 per cent is light oil. In 2002, the Province announced changes to the oil and gas Royalty and Tax Regime in an effort to encourage new oil and gas exploration and development activities in Saskatchewan and to help the industry compete with other jurisdictions around the world. This paper examined the pre-October 2002 Saskatchewan Crown Royalty and freehold production tax structure and compared them to the new structure. The paper also briefly outlined the corporation capital tax, resource surcharge, and flow-through share tax credit initiatives announced in 2001 and 2002. With reductions in the Crown Royalty, freehold production tax and corporation capital taxes, the Province expects that more than 9000 oil and gas wells will be drilled in the next decade, representing new investment of about $4.3 billion and 40,000 new jobs. The flow-through share credit may not attract significant investment because it only benefits those who pay taxes in Saskatchewan. 40 refs

Methane in groundwater from a leaking gas well, Piceance Basin, Colorado, USA

Science.gov (United States)

McMahon, Peter B.; Thomas, Judith C.; Crawford, John T.; Dornblaser, Mark M.; Hunt, Andrew G.

2018-01-01

Site-specific and regional analysis of time-series hydrologic and geochemical data collected from 15 monitoring wells in the Piceance Basin indicated that a leaking gas well contaminated shallow groundwater with thermogenic methane. The gas well was drilled in 1956 and plugged and abandoned in 1990. Chemical and isotopic data showed the thermogenic methane was not from mixing of gas-rich formation water with shallow groundwater or natural migration of a free-gas phase. Water-level and methane-isotopic data, and video logs from a deep monitoring well, indicated that a shale confining layer ~125 m below the zone of contamination was an effective barrier to upward migration of water and gas. The gas well, located 27 m from the contaminated monitoring well, had ~1000 m of uncemented annular space behind production casing that was the likely pathway through which deep gas migrated into the shallow aquifer. Measurements of soil gas near the gas well showed no evidence of methane emissions from the soil to the atmosphere even though methane concentrations in shallow groundwater (16 to 20 mg/L) were above air-saturation levels. Methane degassing from the water table was likely oxidized in the relatively thick unsaturated zone (~18 m), thus rendering the leak undetectable at land surface. Drilling and plugging records for oil and gas wells in Colorado and proxies for depth to groundwater indicated thousands of oil and gas wells were drilled and plugged in the same timeframe as the implicated gas well, and the majority of those wells were in areas with relatively large depths to groundwater. This study represents one of the few detailed subsurface investigations of methane leakage from a plugged and abandoned gas well. As such, it could provide a useful template for prioritizing and assessing potentially leaking wells, particularly in cases where the leakage does not manifest itself at land surface.

Estimating pore-space gas hydrate saturations from well log acoustic data

Science.gov (United States)

Lee, Myung W.; Waite, William F.

2008-07-01

Relating pore-space gas hydrate saturation to sonic velocity data is important for remotely estimating gas hydrate concentration in sediment. In the present study, sonic velocities of gas hydrate-bearing sands are modeled using a three-phase Biot-type theory in which sand, gas hydrate, and pore fluid form three homogeneous, interwoven frameworks. This theory is developed using well log compressional and shear wave velocity data from the Mallik 5L-38 permafrost gas hydrate research well in Canada and applied to well log data from hydrate-bearing sands in the Alaskan permafrost, Gulf of Mexico, and northern Cascadia margin. Velocity-based gas hydrate saturation estimates are in good agreement with Nuclear Magneto Resonance and resistivity log estimates over the complete range of observed gas hydrate saturations.

Geospatial Analysis of Oil and Gas Wells in California

Science.gov (United States)

Riqueros, N. S.; Kang, M.; Jackson, R. B.

2015-12-01

California currently ranks third in oil production by U.S. state and more than 200,000 wells have been drilled in the state. Oil and gas wells provide a potential pathway for subsurface migration, leading to groundwater contamination and emissions of methane and other fluids to the atmosphere. Here we compile available public databases on oil and gas wells from the California Department of Conservation's Division of Oil, Gas, and Geothermal Resources, the U.S. Geological Survey, and other state and federal sources. We perform geospatial analysis at the county and field levels to characterize depths, producing formations, spud/completion/abandonment dates, land cover, population, and land ownership of active, idle, buried, abandoned, and plugged wells in California. The compiled database is designed to serve as a quantitative platform for developing field-based groundwater and air emission monitoring plans.

A prospective field study examining the association between environmental emissions from the petroleum industry and the productivity of commercial beef cows

Energy Technology Data Exchange (ETDEWEB)

Waldner, C.L.; Ribble, C.S.; Janzen, E.D.; Campbell, J.R. [Western College of Veterinary Medicine, AB (Canada). Dept. of Herd Medicine and Theriogenology

2000-07-01

The health and productivity of seven cow-calf herds located near a new sour gas processing plant was measured using newly developed intensive biological accounting methods. Production records from more than 7000 bull contacts were examined from 1991 to 1997. Detailed information was collected on other risk factors which could influence beef herd productivity. Published reports were in good agreement with the collected data on the median risks for non-pregnancy, abortion, late calving, stillbirth, calf mortality, calving date or weaning weight. Herd age-adjusted weight for both male and female calves improved significantly. Exposure assessments made on individual animals indicated that there is no consistent association between the total sulfation and H{sub 2}S deposition which was used as markers for the compounds found in emissions from sour gas processing plants and flares. However, five examples of association were found to exist between increasing exposure to total sulfation and decreased productivity. Finally, the association between cow-calf productivity and cumulative animal proximity to petroleum field facilities and sour gas flares from battery sites was examined. It was determined that an increased risk of non-pregnancy was sometimes associated with exposure to sour flaring, battery facilities, active gas wells and larger field facilities, but the association was not consistent from from year to year. Flaring was not found to be associated with increased abortion risk, but volume of flared sour gas from battery sites was associated with an increased risk of stillbirth. In the 1992-1993 calf crop, sour flaring was found to be associated with an increased risk in calf mortality.

Well Integrity for Natural Gas Storage in Depleted Reservoirs and Aquifers

Energy Technology Data Exchange (ETDEWEB)

Freifeld, Barry [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Oldenburg, Curtis [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Jordan, Preston [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Pan, Lehua [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Perfect, Scott [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Morris, Joseph [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); White, Joshua [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Bauer, Stephen [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Blankenship, Douglas [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Roberts, Barry [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Bromhal, Grant [National Energy Technology Lab. (NETL), Morgantown, WV (United States); Glosser, Deborah [National Energy Technology Lab. (NETL), Morgantown, WV (United States); Wyatt, Douglas [National Energy Technology Lab. (NETL), Morgantown, WV (United States); Rose, Kelly [National Energy Technology Lab. (NETL), Morgantown, WV (United States)

2016-09-01

The 2015-2016 Aliso Canyon/Porter Ranch natural gas well blowout emitted approximately 100,000 tonnes of natural gas (mostly methane, CH₄) over four months. The blowout impacted thousands of nearby residents, who were displaced from their homes. The high visibility of the event has led to increased scrutiny of the safety of natural gas storage at the Aliso Canyon facility, as well as broader concern for natural gas storage integrity throughout the country. This report presents the findings of the DOE National Laboratories Well Integrity Work Group efforts in the four tasks. In addition to documenting the work of the Work Group, this report presents high priority recommendations to improve well integrity and reduce the likelihood and consequences of subsurface natural gas leaks.

Heptyl vicianoside and methyl caramboside from sour star fruit.

Science.gov (United States)

Yang, Dan; Jia, Xuchao; Xie, Haihui

2018-04-23

Two new alkyl glycosides, heptyl vicianoside (1) and methyl 2-O-β-d-fucopyranosyl-α-l-arabinofuranoside (methyl caramboside, 4), were isolated from the sour fruit of Averrhoa carambola L. (Oxalidaceae), along with octyl vicianoside (2), cis-3-hexenyl rutinoside (3), and methyl α-d-fructofuranoside (5). Their structures were determined by spectroscopic and chemical methods. Compounds 2, 3, and 5 were obtained from the genus Averrhoa for the first time. All the compounds were evaluated for in vitro α-glucosidase, pancreatic lipase, and acetylcholinesterase inhibitory activities, but none of them were potent.

Problems Caused by Microbes and Treatment Strategies Monitoring and Preventing Reservoir Souring Using Molecular Microbiological Methods (MMM)

Science.gov (United States)

Gittel, Antje

The injection of seawater during the process of secondary oil recovery in offshore oilfields supplies huge amounts of sulphate to the prokaryotic reservoir communities. Together with the presence of oil organics and their degradation products as electron donors, this facilitates the enrichment and growth of sulphate-reducing prokaryotes (SRP) in the reservoir, as well as in pipings and top-side installations (Sunde and Torsvik, 2005; Vance and Thrasher, 2005). The activity of SRP causes severe economic problems due to the reactivity and toxicity of the produced hydrogen sulphide (H2S), one of the major problems being reservoir souring. Besides the use of broad-spectrum biocides or inhibitors for sulphate reduction, the addition of nitrate effectively decreased the net production of H2S in model column studies (Myhr et al., 2002; Hubert et al., 2005; Dunsmore et al., 2006) and field trials (Telang et al., 1997; Bødtker et al., 2008). The mechanisms by which nitrate addition might affect souring control are (i) the stimulation of heterotrophic nitrate-reducing bacteria (hNRB) that outcompete SRP for electron donors, (ii) the activity of nitrate-reducing, sulphide-oxidising bacteria (NR-SOB), and (iii) the inhibition of SRP by the production of nitrite and nitrous oxides (Sunde and Torsvik, 2005; Hubert and Voordouw, 2007).

Effect of ultrasound on some chemical and microbiological properties of sour cherry juice by response surface methodology.

Science.gov (United States)

Türken, Tuğba; Erge, Hande S

2017-09-01

In this study, it is aimed to determine effect of ultrasonication on some chemical and microbiological properties of sour cherry juice by response surface methodology, since ultrasound is known as an alternative method for thermal food processing. Sour cherry juice was sonicated at varying amplitude levels (50, 75, 100%); moderate temperatures (20, 30, 40 ℃); and treatment times of 2, 6, 10 min at a constant frequency of 20 kHz. Different ultrasonication amplitudes, temperatures, and times had no significant effect on pH,°Bx, and titratable acidity. A significant increase in total monomeric anthocyanins was observed as the amplitude level and temperature increased (p < 0.01). An increase in the total phenolics was also obtained as the temperature increased (p < 0.05). The effect of amplitude level on antioxidant capacity of sour cherry juice was also found significant (p < 0.05). Color parameters (L*, a*, b*, C, h) generally increased by increasing temperature, amplitude level, and treatment time. It was determined that Escherichia coli O157:H7 significantly affected by temperature and treatment time (p < 0.05).

Advanced Acid Gas Separation Technology for the Utilization of Low Rank Coals

Energy Technology Data Exchange (ETDEWEB)

Kloosterman, Jeff

2012-12-31

Air Products has developed a potentially ground-breaking technology – Sour Pressure Swing Adsorption (PSA) – to replace the solvent-based acid gas removal (AGR) systems currently employed to separate sulfur containing species, along with CO{sub 2} and other impurities, from gasifier syngas streams. The Sour PSA technology is based on adsorption processes that utilize pressure swing or temperature swing regeneration methods. Sour PSA technology has already been shown with higher rank coals to provide a significant reduction in the cost of CO{sub 2} capture for power generation, which should translate to a reduction in cost of electricity (COE), compared to baseline CO{sub 2} capture plant design. The objective of this project is to test the performance and capability of the adsorbents in handling tar and other impurities using a gaseous mixture generated from the gasification of lower rank, lignite coal. The results of this testing are used to generate a high-level pilot process design, and to prepare a techno-economic assessment evaluating the applicability of the technology to plants utilizing these coals.

Flue gas wells to minimize dust and acidic components in small-scale burning of field fuel, further development; Roekgasbrunn foer minimering av stoft och sura komponenter vid smaaskalig foerbraenning av aakerbraenslen, vidareutveckling

Energy Technology Data Exchange (ETDEWEB)

Yngvesson, Johan; Roennbaeck, Marie; Arkeloev, Olof

2011-01-15

Agricultural derived solid fuels are more problematic to combust in small-scale heating plants than conventional wood fuels. Their high content of ash, chlorine and sulphur leads to increased emissions of dust, sulphur dioxide and hydrogen chloride in the flue gases. By transporting the flue gases to a flue gas well where it condenses, and separates dust and sour components, enables a cost effective flue gas purification for small-scale heating plants (50 kW - 10 MW) of agricultural derived solid fuels. This project have studied two heating plants using flue gas wells with the aim to add to the knowledge about how a flue gas wells may look like and to quantify how much emissions of dust, chlorine and sulphur in the flue gases are reduced. The project also aimed to summon regulations and laws regarding the handling of the condensate that develop in the flue gas well. In the project measures were conducted on two different heating plants with mounted flue gas wells: a 60 kW biofuels boiler combusting grains and red canary grass and a 1 MW batch fired boiler combusting wheat straw. Measurements on flue gases were conducted with and without water injection in the flue gases. The flue gas wells reduced dust emissions of up to 80 %. The best reduction was achieved at the 60 kW heating plant when firing red canary grass. Firing grains in the same plant lead to 7 % reduction of the dust emissions. In the 1 MW heating plant firing wheat straw the flue gas well accomplished 40 % reduction of dust emissions. The boiler ability to achieve complete combustion, hence minimize the content of volatile and semi-volatile components in the flue gas, is largely affecting the flue gas well ability to reduce dust emissions. This did not, however, affect the reduction of dust in the flue. Chlorine emissions was reduced by up to 88 % by a flue gas well. Water injection made a big difference on reduction of chlorine emission from grain combustion. Sulphur emissions was reduced by 50

Effects of aqueous extracts of dried calyx of sour tea (Hibiscus sabdariffa L. on polygenic dyslipidemia: A randomized clinical trial

Directory of Open Access Journals (Sweden)

Majid Hajifaraji

2017-12-01

Full Text Available Objective: Dyslipidemia has been considered as a major risk factor for coronary heart disease. Alternative medicine has a significant role in treatment of dyslipidemia. There are controversial findings regarding the effects of sour tea on dyslipidemia. The aim of this study was to evaluate the impact of aqueous extract of dried calyx of sour tea on polygenic dyslipidemia. Materials and Methods: This clinical trial was done on 43 adults (30-60 years old with polygenic dyslipidemia that were randomly assigned to the intervention and control groups. The control group was trained in lifestyle modifications at baseline. The intervention group was trained for lifestyle modifications at baseline and received two cups of sour tea daily, and both groups were followed up for 12 weeks. Lipid profile was evaluated at baseline, and six and 12 weeks following the intervention. In addition, dietary and physical activity assessed at baseline for twelve weeks. Results: Mean concentration of total cholesterol, HDL-C and LDL-C significantly decreased by up to 9.46%, 8.33%, and 9.80%, respectively, after 12 weeks in the intervention group in comparison to their baseline values. However, LDL-C/HDL-C ratio significantly increased  by up to 3.15%, following 12 weeks in the control group in comparison to their baseline values. This study showed no difference in lipid profiles between the two groups, except for HDL-C concentrations. Conclusion: sour tea may have significant positive effects on lipid profile of polygenic dyslipidemia subjects and these effect might be attributed to its anthocyanins and inflation factor content. Therefore, sour tea intake with recommended dietary patterns and physical activity can be useful in regulation of lipid profile in patients with polygenic dyslipidemia.

Possible techniques for decontamination of natural gas from gas wells stimulated by a nuclear explosion

Energy Technology Data Exchange (ETDEWEB)

Wethington, Jr, John A [Lawrence Radiation Laboratory, University of California, Livermore, CA (United States)

1970-05-15

Decontamination of the products from gas wells stimulated by nuclear explosions requires the removal of T, present as HT, CH{sub 3}T, C{sub 2}H{sub 5}T, etc., and {sup 85}Kr from the production stream. Flaring of large volumes of gas from the Gasbuggy well led to the replacement of radioactive cavity gas with inactive formation gas, but this would not be a satisfactory production procedure because it releases T and {sup 85}Kr into the atmosphere and wastes large amounts of product gas. Exchange reactions appear to offer promise for removing the tritium. For example, water or steam flowing countercurrent to tritiated gas in the presence of a suitable catalyst can participate in the exchange reactions CH{sub 3}T + H{sub 2}O {r_reversible} CH{sub 4} + HTO, HT + H{sub 2}O {r_reversible} H{sub 2} + HTO, resulting in the transfer of T from gas into water. Other possibilities for utilizing exchange reactions include exchange of the gas with ethylene glycol used in the gas dryer, with silicate rocks introduced into the gas stream, or with a countercurrent stream of NH{sub 3} or H{sub 2}S. As another approach, use of the contaminated gas for the manufacture of ammonia synthesis gas has potential for removal of both T and {sup 85}Kr. (author)

Phytoplasmas in apricot, peach and sour cherry orchards in East Bohemia, Czech Republic

Czech Academy of Sciences Publication Activity Database

Ludvíková, H.; Fránová, Jana; Suchá, J.

2011-01-01

Roč. 64, Suppl. (2011), s. 67-68 ISSN 1721-8861 R&D Projects: GA MŠk OC09021 Institutional research plan: CEZ:AV0Z50510513 Keywords : Candidatus Phytoplasma prunorum * PCR/RFLP * apricot, peach and sour cherry orchards Subject RIV: EE - Microbiology, Virology Impact factor: 0.592, year: 2011

Variability of oil and gas well productivities for continuous (unconventional) petroleum accumulations

Science.gov (United States)

Charpentier, Ronald R.; Cook, Troy A.

2013-01-01

Over the last decade, oil and gas well productivities were estimated using decline-curve analysis for thousands of wells as part of U.S. Geological Survey (USGS) studies of continuous (unconventional) oil and gas resources in the United States. The estimated ultimate recoveries (EURs) of these wells show great variability that was analyzed at three scales: within an assessment unit (AU), among AUs of similar reservoir type, and among groups of AUs with different reservoir types. Within a particular oil or gas AU (such as the Barnett Shale), EURs vary by about two orders of magnitude between the most productive wells and the least productive ones (excluding those that are dry and abandoned). The distributions of EURs are highly skewed, with most of the wells in the lower part of the range. Continuous AUs were divided into four categories based on reservoir type and major commodity (oil or gas): coalbed gas, shale gas, other low-permeability gas AUs (such as tight sands), and low-permeability oil AUs. Within each of these categories, there is great variability from AU to AU, as shown by plots of multiple EUR distributions. Comparing the means of each distribution within a category shows that the means themselves have a skewed distribution, with a range of approximately one to two orders of magnitude. A comparison of the three gas categories (coalbed gas, shale gas, and other low-permeability gas AUs) shows large overlap in the ranges of EUR distributions. Generally, coalbed gas AUs have lower EUR distributions, shale gas AUs have intermediate sizes, and the other low-permeability gas AUs have higher EUR distributions. The plot of EUR distributions for each category shows the range of variation among developed AUs in an appropriate context for viewing the historical development within a particular AU. The Barnett Shale is used as an example to demonstrate that dividing wells into groups by time allows one to see the changes in EUR distribution. Subdivision into groups

Consortium for Petroleum & Natural Gas Stripper Wells

Energy Technology Data Exchange (ETDEWEB)

Morrison, Joel [Pennsylvania State Univ., University Park, PA (United States)

2011-12-01

The United States has more oil and gas wells than any other country. As of December 31, 2004, there were more than half a million producing oil wells in the United States. That is more than three times the combined total for the next three leaders: China, Canada, and Russia. The Stripper Well Consortium (SWC) is a partnership that includes domestic oil and gas producers, service and supply companies, trade associations, academia, the Department of Energy’s Strategic Center for Natural Gas and Oil (SCNGO) at the National Energy Technology Laboratory (NETL), and the New York State Energy Research and Development Authority (NYSERDA). The Consortium was established in 2000. This report serves as a final technical report for the SWC activities conducted over the May 1, 2004 to December 1, 2011 timeframe. During this timeframe, the SWC worked with 173 members in 29 states and three international countries, to focus on the development of new technologies to benefit the U.S. stripper well industry. SWC worked with NETL to develop a nationwide request-for-proposal (RFP) process to solicit proposals from the U.S. stripper well industry to develop and/or deploy new technologies that would assist small producers in improving the production performance of their stripper well operations. SWC conducted eight rounds of funding. A total of 132 proposals were received. The proposals were compiled and distributed to an industry-driven SWC executive council and program sponsors for review. Applicants were required to make a formal technical presentation to the SWC membership, executive council, and program sponsors. After reviewing the proposals and listening to the presentations, the executive council made their funding recommendations to program sponsors. A total of 64 projects were selected for funding, of which 59 were fully completed. Penn State then worked with grant awardees to issue a subcontract for their approved work. SWC organized and hosted a total of 14 meetings

Terminal acidic shock inhibits sour beer bottle conditioning by Saccharomyces cerevisiae.

Science.gov (United States)

Rogers, Cody M; Veatch, Devon; Covey, Adam; Staton, Caleb; Bochman, Matthew L

2016-08-01

During beer fermentation, the brewer's yeast Saccharomyces cerevisiae experiences a variety of shifting growth conditions, culminating in a low-oxygen, low-nutrient, high-ethanol, acidic environment. In beers that are bottle conditioned (i.e., carbonated in the bottle by supplying yeast with a small amount of sugar to metabolize into CO2), the S. cerevisiae cells must overcome these stressors to perform the ultimate act in beer production. However, medium shock caused by any of these variables can slow, stall, or even kill the yeast, resulting in production delays and economic losses. Here, we describe a medium shock caused by high lactic acid levels in an American sour beer, which we refer to as "terminal acidic shock". Yeast exposed to this shock failed to bottle condition the beer, though they remained viable. The effects of low pH/high [lactic acid] conditions on the growth of six different brewing strains of S. cerevisiae were characterized, and we developed a method to adapt the yeast to growth in acidic beer, enabling proper bottle conditioning. Our findings will aid in the production of sour-style beers, a trending category in the American craft beer scene. Copyright © 2016 Elsevier Ltd. All rights reserved.

Potential for offshore geothermal developments using deep gas wells

Energy Technology Data Exchange (ETDEWEB)

Teodoriu, C.; Falcone, G. [Technische Univ. Clausthal, Clausthal-Zellerfeld (Germany). ITE

2013-08-01

The development of geothermal resources is steadily increasing as operators meet the challenge of maximising the temperature difference between production and injection wells, while minimising the wellhead temperature of the latter. At present, the minimum working wellhead temperature reported for the heat-to-electricity conversion cycles is limited to about 80 C. The cycle efficiency can be improved by reducing the injection temperature, which is the temperature at which the fluid exits the process. This paper evaluates the potential for generating electricity with a subsea geothermal plant using the difference between downhole reservoir temperature and that of the cold seawater at the mud line. The temperature in the world's oceans is relatively constant, ranging from 0 to 4 C at around 400 meters water depth. The use of these lower offshore water temperatures may help boost geothermal energy development. Deep gas resources are considered to be held within reservoirs below 4600 meters (15000 feet) and are relatively undeveloped as the risks and costs involved in drilling and producing such resources are extremely high. These deep resources have high reservoir temperatures, which offer an opportunity for geothermal exploitation if a new development concept can be formulated. In particular, the well design and reservoir development plan should consider reutilising existing well stock, including dry and plugged and abandoned wells for geothermal application once the gas field has been depleted. The major risks considered in this study include alternative uses of wells in no flow or rapid depletion situations. Reutilisation of the wells of depleted gas reservoirs will invariably lead to lower geothermal development costs compared with starting a geothermal campaign by drilling new wells. In particular, the well design and reservoir development plan should consider reutilising existing well stock, including dry and plugged and abandoned wells for geothermal

The voice of Canada's oil and natural gas industry : oil and natural gas

International Nuclear Information System (INIS)

2001-04-01

The Canadian Association of Petroleum Producers (CAPP) represents 150 members of the oil and gas industry, which together are responsible for approximately 95 per cent of the oil and natural gas produced in Canada. The upstream sector comprises companies that explore for, develop and produce petroleum resources, while the downstream sector involves companies that refine and market the resources. CAPP works closely with governments of 11 of Canada's 13 provinces and territories and with public groups to represent upstream producers active across the country. The enhancement of the economic well-being and sustainability of the upstream petroleum industry is the mission of the CAPP. The main priorities of the CAPP are: Environment, Health and Safety Stewardship, reasonable and timely access to resources, competitiveness of the Canadian industry on a global basis, the secure and efficient access to markets, and open and constructive public, government and media affairs. Some of the issues dealt with by the CAPP are sour gas, flaring, venting and industry-landowner relations, improved safety performance, federal issues such as corporate taxes and environmental issues, Aboriginal and First Nations issues, transportation costs for natural gas on major pipelines, and oil and sands bitumen issues, to name a few. The board of the CAPP is made up of 32 members. The work is carried out by hundreds of volunteers from member companies who provide their time and expertise for various committees and working groups, as well as a staff of approximately 40 people to assist them. The members provide the entire funding for CAPP, which is located in Calgary, Alberta. The document concluded with a few facts concerning the petroleum industry in general. 12 figs

High-resolution well-log derived dielectric properties of gas-hydrate-bearing sediments, Mount Elbert Gas Hydrate Stratigraphic Test Well, Alaska North Slope

Science.gov (United States)

Sun, Y.; Goldberg, D.; Collett, T.; Hunter, R.

2011-01-01

A dielectric logging tool, electromagnetic propagation tool (EPT), was deployed in 2007 in the BPXA-DOE-USGS Mount Elbert Gas Hydrate Stratigraphic Test Well (Mount Elbert Well), North Slope, Alaska. The measured dielectric properties in the Mount Elbert well, combined with density log measurements, result in a vertical high-resolution (cm-scale) estimate of gas hydrate saturation. Two hydrate-bearing sand reservoirs about 20 m thick were identified using the EPT log and exhibited gas-hydrate saturation estimates ranging from 45% to 85%. In hydrate-bearing zones where variation of hole size and oil-based mud invasion are minimal, EPT-based gas hydrate saturation estimates on average agree well with lower vertical resolution estimates from the nuclear magnetic resonance logs; however, saturation and porosity estimates based on EPT logs are not reliable in intervals with substantial variations in borehole diameter and oil-based invasion.EPT log interpretation reveals many thin-bedded layers at various depths, both above and below the thick continuous hydrate occurrences, which range from 30-cm to about 1-m thick. Such thin layers are not indicated in other well logs, or from the visual observation of core, with the exception of the image log recorded by the oil-base microimager. We also observe that EPT dielectric measurements can be used to accurately detect fine-scale changes in lithology and pore fluid properties of hydrate-bearing sediments where variation of hole size is minimal. EPT measurements may thus provide high-resolution in-situ hydrate saturation estimates for comparison and calibration with laboratory analysis. ?? 2010 Elsevier Ltd.

Inhibitory effect of sour pomegranate sauces on some green vegetables and kisir.

Science.gov (United States)

Karabiyikli, Seniz; Kisla, Duygu

2012-04-16

In this study, the antimicrobial effects of both traditional and commercial pomegranate sour sauce samples on some green vegetables and also on "kısır" which is a popular and traditional appetizer in Turkey were investigated. The inhibitory effect of the pomegranate products on the naturally existing bacterial microflora of lettuce, spring onion, parsley and kısır were analyzed. Also, all these food samples were inoculated with Staphylococcus aureus (ATCC-25923) and Escherichia coli O157:H7 (ATCC-43895) and antimicrobial effect of the pomegranate products on the inoculated microflora was detected. All the food samples were treated with pomegranate products for different time periods and the effect of treatment time was investigated. pH and titratable acidity values of the traditional and commercial pomegranate sour sauce samples were detected. The results showed that although the pomegranate products had an antimicrobial effect on the natural bacterial microflora of the food samples, the effect on inoculated food samples was more prominent and additionally the application time was found to be a crucial parameter for both cases. Copyright © 2012 Elsevier B.V. All rights reserved.

Presynaptic (Type III) cells in mouse taste buds sense sour (acid) taste.

Science.gov (United States)

Huang, Yijen A; Maruyama, Yutaka; Stimac, Robert; Roper, Stephen D

2008-06-15

Taste buds contain two types of cells that directly participate in taste transduction - receptor (Type II) cells and presynaptic (Type III) cells. Receptor cells respond to sweet, bitter and umami taste stimulation but until recently the identity of cells that respond directly to sour (acid) tastants has only been inferred from recordings in situ, from behavioural studies, and from immunostaining for putative sour transduction molecules. Using calcium imaging on single isolated taste cells and with biosensor cells to identify neurotransmitter release, we show that presynaptic (Type III) cells specifically respond to acid taste stimulation and release serotonin. By recording responses in cells isolated from taste buds and in taste cells in lingual slices to acetic acid titrated to different acid levels (pH), we also show that the active stimulus for acid taste is the membrane-permeant, uncharged acetic acid moiety (CH(3)COOH), not free protons (H(+)). That observation is consistent with the proximate stimulus for acid taste being intracellular acidification, not extracellular protons per se. These findings may also have implications for other sensory receptors that respond to acids, such as nociceptors.

Problems of Gas Pressure Build-up in Casing String of UGS and Gas Wells

Directory of Open Access Journals (Sweden)

Peter Sovius

2006-10-01

Full Text Available This paper consists of three basic parts. The opening part is a brief description of problems associated with the secondary untightness of UGS wells (Underground Gas Storages and gas wells generally.The main part of the paper is composed of some cases that we have met in our company. Solution proposals of various cases are also supplied in this part. Separate problem situations are described in terms of finding out an untight point and also a testing result and consequential removing of untightness.The conclusion includes knowledge summary that were taken by solution of complicatedsituations connected with well non-hermeticity.

Optimizing production gas wells by using a dual completion

International Nuclear Information System (INIS)

Boussa, M.; Hebbal, H.

2006-01-01

Dual completion has frequently been used in producing oil wells that are perforated on several zones. This paper presented the results of a study investigating the use of dual completion techniques on producing gas wells with 2 and 3 layers in Hassi-R'mel gas field in Algeria. The aim of the study was to improve production in the upper zones of the wells. The advantages and disadvantages of dual completion were discussed. Capital costs and profit ratios after completion were also examined. Hassi R'mel is one of the largest wet gas reservoirs in the world, and has 3 distinct reservoir horizons. Zone A is comprised of fine-grained clay-rich sandstone with anhydritic cementing in places. Zones B and C have permeabilities ranging 300 to 1200 mD. The lower zones contribute to the majority of the gas production. Water influx from Zone C generates an increase in the flow of some wells in Zone A. Three wells were selected that shared the following characteristics: (1) cross-flow; (2) water influx; and (3) low flow from the higher zone. Two computer simulations were prepared to compare the use of well smart completion techniques and dual completion. Hagedorne and Brown correlations were used. Results of the simulation indicated that smart well completion gave the best results when compared with dual completion, and was more cost-effective due to the fact that the completion technique did not need to be altered, and flow at the bottom could be controlled from the surface by valves. The technique prevented cross flow between zones and optimized production from various zones. 7 refs., 3 tabs., 40 figs

Review of Well Operator Files for Hydraulically Fractured Oil and Gas Production Wells: Well Design and Construction Fact Sheet

Science.gov (United States)

EPA reviewed a statistically representative sample of oil and gas production wells reported by nine service companies to help understand the role of well design and construction practices preventing pathways for subsurface fluid movement.

The influence of sour taste and cold temperature in pharyngeal transit duration in patients with stroke

Directory of Open Access Journals (Sweden)

Paula Cristina Cola

2010-03-01

Full Text Available CONTEXT: The effect of sour taste and food temperature variations in dysphagic patients has not been entirely clarified. OBJECTIVE: To determine the effect of sour and cold food in the pharyngeal transit times of patients with stroke. METHODS: Patients participating in this study were 30 right-handed adults, 16 of which were male and 14 were female, aged 41 to 88 (average age 62.3 years with ictus varying from 1 to 30 days (median of 6 days. To analyze the pharyngeal transit time a videofluoroscopy swallow test was performed. Each patient was observed during swallow of a 5 mL paste bolus given by spoon, totaling four different stimuli (natural, cold, sour and cold sour, one at a time, room temperature (22ºC and cold (8ºC were used. Later, the tests were analyzed using specific software to measure bolus transit time during the pharyngeal phase. RESULTS: The results showed that the pharyngeal transit time was significantly shorter during swallow of cold sour bolus when compared with other stimuli. Conclusion - Sour taste stimuli associated to cold temperature cause significant change in swallowing patterns, by shortening the pharyngeal transit time, which may lead to positive effects in patients with oropharyngeal dysphagia.CONTEXTO: O efeito do sabor azedo e as variações da temperatura dos alimentos em indivíduos disfágicos, ainda não foi totalmente esclarecidos. OBJETIVO: Verificar o efeito do sabor azedo e da temperatura fria no tempo de trânsito faríngeo da deglutição em indivíduos após acidente vascular encefálico hemisférico isquêmico. MÉTODOS: Participaram deste estudo 30 indivíduos adultos, sendo 16 do gênero masculino e 14 do feminino, destros, com faixa etária variando de 41 a 88 anos (média de 62,3 anos e ictus que variou de 1 a 30 dias (mediana de 6 dias. Para analisar o tempo de trânsito faríngeo da deglutição foi realizado o exame de videofluoroscopia da deglutição. Cada indivíduo foi observado durante a

Spatial and Temporal Characteristics of Historical Oil and Gas Wells in Pennsylvania: Implications for New Shale Gas Resources.

Science.gov (United States)

Dilmore, Robert M; Sams, James I; Glosser, Deborah; Carter, Kristin M; Bain, Daniel J

2015-10-20

Recent large-scale development of oil and gas from low-permeability unconventional formations (e.g., shales, tight sands, and coal seams) has raised concern about potential environmental impacts. If left improperly sealed, legacy oil and gas wells colocated with that new development represent a potential pathway for unwanted migration of fluids (brine, drilling and stimulation fluids, oil, and gas). Uncertainty in the number, location, and abandonment state of legacy wells hinders environmental assessment of exploration and production activity. The objective of this study is to apply publicly available information on Pennsylvania oil and gas wells to better understand their potential to serve as pathways for unwanted fluid migration. This study presents a synthesis of historical reports and digital well records to provide insights into spatial and temporal trends in oil and gas development. Areas with a higher density of wells abandoned prior to the mid-20th century, when more modern well-sealing requirements took effect in Pennsylvania, and areas where conventional oil and gas production penetrated to or through intervals that may be affected by new Marcellus shale development are identified. This information may help to address questions of environmental risk related to new extraction activities.

Noninteracting Fermi gas in a square-well potential.

Science.gov (United States)

Nash, C. E.

1971-01-01

The problem of a noninteracting Fermi gas in a finite square-well potential is solved analytically in the limit that the well becomes infinitely wide. The errors of previous authors using this model as a first approximation to the problem of a simple metal with surfaces are pointed out.

Evaluation of thiosulfate as a substitute for hydrogen sulfide in sour corrosion fatigue studies

Science.gov (United States)

Kappes, Mariano Alberto

This work evaluates the possibility of replacing hydrogen sulfide (H 2S) with thiosulfate anion (S2O32- ) in sour corrosion fatigue studies. H2S increases the corrosion fatigue crack growth rate (FCGR) and can be present in carbon steel risers and flowlines used in off-shore oil production. Corrosion tests with gaseous H2S require special facilities with safety features, because H2S is a toxic and flammable gas. The possibility of replacing H2S with S2O32-, a non-toxic anion, for studying stress corrosion cracking of stainless and carbon steels in H2S solutions was first proposed by Tsujikawa et al. ( Tsujikawa et al., Corrosion, 1993. 49(5): p. 409-419). In this dissertation, Tsujikawa work will be extended to sour corrosion fatigue of carbon steels. H2S testing is often conducted in deareated condition to avoid oxygen reaction with sulfide that yields sulfur and to mimic oil production conditions. Nitrogen deareation was also adopted in S2O3 2- testing, and gas exiting the cell was forced through a sodium hydroxide trap. Measurements of the sulfide content of this trap were used to estimate the partial pressure of H2S in nitrogen, and Henry's law was used to estimate the content of H2S in the solution in the cell. H2S was produced by a redox reaction of S2O 32-, which required electrons from carbon steel corrosion. This reaction is spontaneous at the open circuit potential of steel. Therefore, H2S concentration was expected to be maximum at the steel surface, and this concentration was estimated by a mass balance analysis. Carbon steel specimens exposed to S2O32- containing solutions developed a film on their surface, composed by iron sulfide and cementite. The film was not passivating and a good conductor of electrons. Hydrogen permeation experiments proved that this film controls the rate of hydrogen absorption of steels exposed to thiosulfate containing solutions. The absorption of hydrogen in S2O3 2- solutions was compared with the absorption of hydrogen in

Advanced ultrasonic technology for natural gas measurement

Energy Technology Data Exchange (ETDEWEB)

NONE

2011-11-15

In recent years, due to rising environmental and safety concerns, increasing commodity prices, and operational inefficiencies, a paradigm shift has been taking place with respect to gas measurement. The price of natural gas depends on the location, time of the year, and type of consumer. There is wide uncertainty associated with an orifice meter. This paper presents the use of advanced ultrasonic technology for the measurement of natural gas. For many years, multi-path ultrasonic meters with intelligent sensor technology have been used for gas measurement. This paper gives the various applications of ultrasonic technology along with their advantages and a draws a comparison with orifice meters. From the study it can be concluded that extensive advances in the use of ultrasonic technology for gas measurement have widened the areas of application and that varying frequencies combined with sealed transducer designs make it possible to measure atmospheric and sour gas in custody transfer process control and flaring accurately.

Clearing the air : with 87 recommendations now implemented for reducing sulphur emissions from conventional facilities, clean air strategists in Alberta are setting their sights on the oilsands

Energy Technology Data Exchange (ETDEWEB)

Collison, M.

2008-11-15

Clean air strategists in Alberta are now preparing to implement recommendations for reducing sulfur emissions in oil sands facilities. The oil and gas industry in Alberta has made significant reductions in emissions over the last few decades. Sulfur emissions at acid gas flaring plants have decreased by 73 per cent, and emissions from sulfur recovery plants have decreased by 40 per cent. Complaints about emissions have also dropped as industry regulations and practices have been refined and improved. The impacts of sour gas on human and animal health have not been proven despite the fact that many Alberta residents claim that the emissions have harmed their health. An independent public safety sour gas advisory committee was formed in the province in 1999 in order to identify and communicate with major stakeholder groups in the province. Recommendations made by the committee after consultation with public stakeholders included more direct involvement with disputes over sour gas. In 2007, the Alberta Energy and Utilities Board (EUB) toughened sour gas regulations and assisted in researching the health effects of sour gas exposure. Regulations for the inspection and testing of sour gas pipelines were also implemented. It was concluded that maintaining and improving air quality in Alberta will require comprehensive strategies that involve governments, industry, and individual stakeholders. 2 figs.

Lactic acid bacteria and yeasts associated with spontaneous fermentations during the production of sour cassava starch in Brazil.

Science.gov (United States)

Lacerda, Inayara C A; Miranda, Rose L; Borelli, Beatriz M; Nunes, Alvaro C; Nardi, Regina M D; Lachance, Marc-André; Rosa, Carlos A

2005-11-25

Sour cassava starch is a traditional fermented food used in the preparation of fried foods and baked goods such as traditional cheese breads in Brazil. Thirty samples of sour cassava starch were collected from two factories in the state of Minas Gerais. The samples were examined for the presence of lactic acid bacteria, yeasts, mesophilic microorganisms, Bacillus cereus and faecal coliforms. Lactic acid bacteria and yeasts isolates were identified by biochemical tests, and the identities were confirmed by molecular methods. Lactobacillus plantarum and Lactobacillus fermentum were the prevalent lactic acid bacteria in product from both factories, at numbers between 6.0 and 9.0 log cfu g(-)(1). Lactobacillus perolans and Lactobacillus brevis were minor fractions of the population. Galactomyces geothricum and Issatchenkia sp. were the prevalent yeasts at numbers of 5.0 log cfu g(-)(1). A species similar to Candida ethanolica was frequently isolated from one factory. Mesophilic bacteria and amylolytic microorganisms were recovered in high numbers at all stages of the fermentation. B. cereus was found at low numbers in product at both factories. The spontaneous fermentations associated with the production of sour cassava starch involve a few species of lactic acid bacteria at high numbers and a variety of yeasts at relatively low numbers.

State-of-the-art review of liquid loading in gas wells

Energy Technology Data Exchange (ETDEWEB)

Falcone, G. [Technische Univ. Clausthal, Clausthal-Zellerfeld (Germany). ITE; Barbosa, J.R. Jr. [Universidade Federal de Santa Catarina, Florianopolis, SC (Brazil). Dept. of Mechanical Engineering

2013-08-01

Gas wells suffering from liquid loading are incapable of removing the liquid associated with produced gas from the wellbore. This phenomenon is initiated when the upward gas velocity in the well falls below a critical value at which point the liquid that was initially flowing upwards, begins to fall back. This liquid accumulates downhole, where it increases the hydrostatic back-pressure on the reservoir, destabilises the multiphase flow in the well (following flow regime changes), decreases production rate and, in severe cases, kills the well. The typical liquid loading sequence begins with a gas flow rate that is high enough to transport all liquids to surface and there is no liquid fall-back in the well. However, as the gas velocity slows or the liquid content in the well rises, there is insufficient energy in the well to carry all liquids to surface and some begins to flow backwards. As the hydrostatic head downhole increases, the liquid column that has accumulated in the well can re-enter the near-wellbore region of the reservoir. This results in the well becoming 'unloaded' so that it can flow once more, with the gas carrying all liquids to surface. However, the reinjection of liquids into the reservoir may cause formation damage, which will impair the well productivity. This cycle continues, providing the typical intermittent response of liquid-loaded gas wells, until the reservoir potential starts to fall or the liquid yield rises. Diagnosing liquid loading is often difficult as the affected well(s) may continue production without any substantial performance impairment for a long period of time. Typical symptoms of liquid loading include sharp drops in the cumulative production decline curve, the onset of liquid slugs in the surface facilities, abrupt changes in the flowing pressure gradient, low temperature spikes at the wellhead and declining water production or condensate-gas-ratio. Many remedial lifting options have been developed for use in

Oil and Natural Gas Wells, US, 2010, Platts

Data.gov (United States)

U.S. Environmental Protection Agency — The Oil and Natural Gas Well geospatial dataset contains point features representing permitted locations, most of which have been drilled and completed, or drilled...

Constant rate natural gas production from a well in a hydrate reservoir

International Nuclear Information System (INIS)

Ji Chuang; Ahmadi, Goodarz; Smith, Duane H.

2003-01-01

Using a computational model, production of natural gas at a constant rate from a well that is drilled into a confined methane hydrate reservoir is studied. It is assumed that the pores in the reservoir are partially saturated with hydrate. A linearized model for an axisymmetric condition with a fixed well output is used in the analysis. For different reservoir temperatures and various well outputs, time evolutions of temperature and pressure profiles, as well as the gas flow rate in the hydrate zone and the gas region, are evaluated. The distance of the decomposition front from the well as a function of time is also computed. It is shown that to maintain a constant natural gas production rate, the well pressure must be decreased with time. A constant low production rate can be sustained for a long duration of time, but a high production rate demands unrealistically low pressure at the well after a relatively short production time. The simulation results show that the process of natural gas production in a hydrate reservoir is a sensitive function of reservoir temperature and hydrate zone permeability

Decline Curve Based Models for Predicting Natural Gas Well Performance

OpenAIRE

Kamari, Arash; Mohammadi, Amir H.; Lee, Moonyong; Mahmood, Tariq; Bahadori, Alireza

2016-01-01

The productivity of a gas well declines over its production life as cannot cover economic policies. To overcome such problems, the production performance of gas wells should be predicted by applying reliable methods to analyse the decline trend. Therefore, reliable models are developed in this study on the basis of powerful artificial intelligence techniques viz. the artificial neural network (ANN) modelling strategy, least square support vector machine (LSSVM) approach, adaptive neuro-fuzzy ...

Gas composition and isotopic geochemistry of cuttings, core, and gas hydrate from the JAPEX/JNOC/GSC Mallik 2L-38 gas hydrate research well

Science.gov (United States)

Lorenson, T.D.

1999-01-01

Molecular and isotopic composition of gases from the JAPEX/JNOC/GSC Mallik 2L-38 gas hydrate research well demonstrate that the in situ gases can be divided into three zones composed of mixtures of microbial and thermogenic gases. Sediments penetrated by the well are thermally immature; thus the sediments are probably not a source of thermogenic gas. Thermogenic gas likely migrated from depths below 5000 m. Higher concentrations of gas within and beneath the gas hydrate zone suggest that gas hydrate is a partial barrier to gas migration. Gas hydrate accumulations occur wholly within zone 3, below the base of permafrost. The gas in gas hydrate resembles, in part, the thermogenic gas in surrounding sediments and gas desorbed from lignite. Gas hydrate composition implies that the primary gas hydrate form is Structure I. However, Structure II stabilizing gases are more concentrated and isotopically partitioned in gas hydrate relative to the sediment hosting the gas hydrate, implying that Structure II gas hydrate may be present in small quantities.

Inhibitory effect of cyanide on wastewater nitrification determined using SOUR and RNA-based gene-specific assays

Science.gov (United States)

The effect of CN- (CN-) on nitrification was examined with samples from nitrifying wastewater enrichments using two different approaches: by measuring substrate (ammonia) specific oxygen uptake rates (SOUR), and by using RT-qPCR to quantify the transcripts of functional genes inv...

Records of wells drilled for oil and gas in New Mexico

Science.gov (United States)

Dixon, G.H.; Baltz, D.H.; Stipp, T.F.; Bieberman, R.A.

1954-01-01

Data concerning nearly 3,000 of the more than 13,000 wells drilled in New Mexico, before September 1, 1953, including unsuccessful wildcat and field extension wells and most of the discovery wells, have been compiled and are published in this circular. Although the search for oil and gas has extended to all parts of the State, most of the wells and all the oil and natural gas fields are located in the northwest and southeast quadrants of the State.

Study on fracture and stress corrosion cracking behavior of casing sour service materials

International Nuclear Information System (INIS)

Sequera, C.; Gordon, H.

2003-01-01

Present work describes sulphide stress corrosion cracking and fracture toughness tests performed to high strength sour service materials of T-95, C-100 and C-110 oil well tubular grades. P-110 was considered as a reference case, since it is one of the high strength materials included in specification 5CT of American Petroleum Institute, API. Sulphide stress corrosion cracking, impact and fracture toughness values obtained in the tests show that there is a correspondence among them. A decreasing classification order was established, namely C-100, T-95, C-110 and P-110. Special grades steels studied demonstrated a better behavior in the evaluated properties than the reference case material grade: P-110. Results obtained indicate that a higher sulphide stress corrosion cracking resistance is related to a higher toughness. The fracture toughness results evidence the hydrogen influence on reducing the toughness values. (author)

Effects of Ultrasound Assistance on Dehydration Processes and Bioactive Component Retention of Osmo-Dried Sour Cherries.

Science.gov (United States)

Siucińska, Karolina; Mieszczakowska-Frąc, Monika; Połubok, Aleksandra; Konopacka, Dorota

2016-07-01

Despite having numerous health benefits, dried sour cherries have proven to be more acceptable to consumers when infused with sugar or other sweeteners to enhance their flavor, which, in turn, leads to serious anthocyanin losses. For this reason, a consideration was made for the application of ultrasound to accelerate solid gain and shorten drying time, thus favoring bioactive component retention. To determine the usefulness of ultrasound as a tool for sour cherry osmotic infusion enhancement, the effect of sonication time on dehydration effectiveness, as well as the stability of bioactive components during osmotic treatment and consecutive convective drying, was investigated. Fruits were osmo-dehydrated using a 60% sucrose solution for 120 min (40 °C), during which, ultrasound of 25 kHz (0.4 W/cm(2) ), was applied for 0, 30, 60, 90, and 120 min, after which, the fruits were convectively dried. In the range of the applied ultrasound energy no significant effect of sonication on mass transfer intensification was observed; moreover, longer acoustic treatment seemed to retard moisture removal during subsequent convective drying, which can be related to the breakdown of the parenchyma cell walls caused by the prolonged ultrasound (US) action. It was concluded that although US assistance could be considered neutral for bioactive component retention, excessive sonication time can lead to some anthocyanin deterioration. According to high-performance liquid chromatography analysis, the particular anthocyanin alterations, both during dehydration and final drying, occurred in a similar way. Sonication time prolongation caused approximately 10% more bioactive compound deterioration, than earlier, shorter trials. © 2016 Institute of Food Technologists®

Design of small diameter HT/HP sour service reeled rigid pipelines

Energy Technology Data Exchange (ETDEWEB)

Carneiro, Daniel; Gouveia, Joao; Tardelli, Luciano [Tecnitas, Rio de Janeiro, RJ (Brazil)], e-mail: daniel.carneiro@br.bureauveritas.com; Parrilha, Rafael [Bureau Veritas Group, London (United Kingdom); Oazen, Eduardo; Cardoso, Carlos [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil)

2009-12-19

The paper presents an overview of the challenges overcome in the engineering design of two 219 mm diameter, 6 km length oil production pipelines, to be installed by reeling at Espirito Santo Basin, offshore Brazilian coast in 1500 m water depth. The high temperature and high pressure (HT/HP) operating conditions and sour content associated with the small diameter required to single well oil production would usually lead to flexible flow line solution in Brazilian fields. The decision of employing small diameter thick-walled rigid C-Mn steel pipelines with thick thermal insulation made necessary extensive engineering work to achieve a safe and robust thermal expansion control arrangement, including the design of walking mitigation and buckle initiation apparatus; a feasible weld acceptance criterion covering both high cycle fatigue due to pipe lay and vortex induced vibration (VIV) at free spans, and high strain low cycle fatigue and fracture growth induced by reeling installation and in-service lateral buckling. Several studies were performed using highly non-linear three-dimensional finite element models considering: pipe-soil interaction with full 3D seabed bathymetry; load history maintained from pipe lay to operational cycles, including temperature transient effects; high plastic strains (including steel properties de-rating due to high temperature) and section ovalization; mechanical contact between pipe and appurtenances during both installation and operational phases. Pipe-soil interaction comprised embedment considering dynamic effects of pipe lay and full non-linear lateral and axial response curves including break-out and residual resistance. Strain concentration factors due to field joints were evaluated using detailed solid models considering non-linear response of both steel and insulation materials. Susceptibility to VIV at free spans was assessed considering post loaded deformed span natural frequencies, including multi-span interaction effects and

Changes in sour cherry (Prunus cerasus L.) antioxidants during nectar processing and in vitro gastrointestinal digestion.

NARCIS (Netherlands)

Toydemir, G.; Capanoglu, E.; Kamiloglu, S.; Boyacioglu, D.; Vos, de C.H.; Hall, R.D.; Beekwilder, M.J.

2013-01-01

Sour cherry (Prunus cerasus L.) is rich in polyphenols, and like its processed products, is especially rich in anthocyanins. We have applied HPLC, spectrophotometric and on-line antioxidant detection methods to follow the fate of cherry antioxidants during an entire multi-step industrial-scale

H2S cracking resistance of type 420 stainless steel tubulars

International Nuclear Information System (INIS)

Klein, L.J.

1984-01-01

Type 420 stainless steel (13Cr) production tubing is being used successfully in deep sour gas wells in the Tuscaloosa Trend. Despite their reputation for poor H 2 S cracking resistance in laboratory tests, 12-13% Cr steels continue to perform well in sour environments. NACE Tensile Test and Shell bent beam test results indicate Type 420 is more resistant to H 2 S cracking than Type 410, but is not as resistant as carbon steel, at to 586-690 MPa (85-100 ksi) yield strength level. In addition to evaluating Type 420 stainless steel in the standard NACE Tensile and Shell bent beam tests, the effects on cracking tendency of chloride concentration, pH, and H 2 S gas concentration in the NACE Test solution were also examined. Type 420 appears to be more resistant to H 2 S cracking than is indicated by standard laboratory tests, at least in low H 2 S level sour environments

Broadband Seismic Studies at the Mallik Gas Hydrate Research Well

Science.gov (United States)

Sun, L. F.; Huang, J.; Lyons-Thomas, P.; Qian, W.; Milkereit, B.; Schmitt, D. R.

2005-12-01

The JAPEX/JNOC/GSC et al. Mallik 3L-38, 4L-38 and 5L-38 scientific wells were drilled in the MacKenzie Delta, NWT, Canada in early 2002 primarily for carrying out initial tests of the feasibility of producing methane gas from the large gas hydrate deposits there [1]. As part of this study, high resolution seismic profiles, a pseudo-3D single fold seismic volume and broadband (8~180Hz) multi-offset vertical seismic profiles (VSP) were acquired at the Mallik site. Here, we provide details on the acquisition program, present the results of the 2D field profile, and discuss the potential implications of these observations for the structure of the permafrost and gas hydrate zones. These zones have long been problematic in seismic imaging due to the lateral heterogeneities. Conventional seismic data processing usually assume a stratified, weak-contrast elastic earth model. However, in permafrost and gas hydrate zones this approximation often becomes invalid. This leads to seismic wave scattering caused by multi-scale perturbation of elastic properties. A 3D viscoelastic finite difference modeling algorithm was employed to simulate wave propagation in a medium with strong contrast. Parameters in this modeling analysis are based on the borehole geophysical log data. In addition, an uncorrelated Vibroseis VSP data set was studied to investigate frequency-dependent absorption and velocity dispersion. Our results indicate that scattering and velocity dispersion are important for a better understanding of attenuation mechanisms in heterogeneous permafrost and gas hydrate zones. [1] Dallimore, S.R., Collett, T.S., Uchida, T., and Weber, M., 2005, Overview of the science program for the Mallik 2002 Gas Hydrate Production Research Well Program; in Scientific Results from Mallik 2002 Gas Hydrate production Research Well Program, MacKenzie Delta, Northwest Territories, Canada, (ed.) S.R. Dallimore and T.S. Collett; Geological Survey of Canada, Bulletin 585, in press.

ADVANCED TECHNOLOGIES FOR STRIPPER GAS WELL ENHANCEMENT

International Nuclear Information System (INIS)

Charles M. Boyer II; Ronald J. MacDonald P.G.

2001-01-01

As part of Task 1 in Advanced Technologies for Stripper Gas Well Enhancement, Schlumberger-Holditch Reservoir Technologies (H-RT) has joined with two Appalachian Basin producers, Great Lakes Energy Partners, LLC, and Belden and Blake Corporation to develop methodologies for identification and enhancement of stripper wells with economic upside potential. These industry partners have provided us with data for more than 700 wells in northwestern Pennsylvania. Phase 1 goals of this project are to develop and validate methodologies that can quickly and cost-effectively identify wells with enhancement potential. We are currently in the final stages of developing and testing our new Microsoft(trademark) Access/Excel based software. We will be processing this well data and identifying potential candidate wells that can be used in Phase 2 to validate these methodologies. Preparation of the final technical report is underway

Cuttings-carried theory and erosion rule in gas drilling horizontal well

Directory of Open Access Journals (Sweden)

Wei Na

2014-01-01

Full Text Available In gas horizontal drilling, the gas with cuttings will go through the annulus at high speed which will lead strong erosion to the drill tools. This paper proposes a cuttings-carried theory and modified the critical cuttings-carried model for the gas-solid flow. Meanwhile, the erosive energy is obtained through simulating the gas-solid mixture in different conditions. The study result has positive significance on the determination of reasonable injection volume by optimizing construction parameters of horizontal well in gas drilling.

Papers of the PTAC air issues forum and poster session for the upstream oil and gas industry

Energy Technology Data Exchange (ETDEWEB)

NONE

2004-07-01

This forum focused on air issues from the perspective of the oil and gas industry. The impacts of the national pollutant release inventory and the new regional air quality network and the Albertan oil sands region were discussed as well as some of the varied impacts of environmental assessment procedures. The impact of sour gas emissions on southern Alberta was also examined. New methods and technologies for measuring emissions were presented, including: tools for the measurement of fugitive emissions; improved flare tip design; optical emissions detection technology; investigation of the sooting propensity of flares; and the measurement of fugitive emissions at gas processing facilities. Energy efficiency in practice was also discussed with a case study comparison of an emergency planning zone (EPZ) determination using existing and new models of the Energy Utilities Board (EUB). Seventeen papers were presented at this forum, three of which have been catalogued separately for inclusion in this database. tabs, figs.

ADVANCED TECHNOLOGIES FOR STRIPPER GAS WELL ENHANCEMENT

International Nuclear Information System (INIS)

Charles M. Boyer II; Ronald J. MacDonald P.G.

2001-01-01

As part of Task 1 in Advanced Technologies for Stripper Gas Well Enhancement, Schlumberger-Holditch Reservoir Technologies (H-RT) has joined with two Appalachian Basin producers, Great Lakes Energy Partners, LLC, and Belden and Blake Corporation to develop methodologies for identification and enhancement of stripper wells with economic upside potential. These industry partners have provided us with data for more than 700 wells in northwestern Pennsylvania. Phase 1 goals of this project are to develop and validate methodologies that can quickly and cost-effectively identify wells with enhancement potential. We have continued to enhance and streamline our software, and we are testing the final stages of our new Microsoft(trademark) Access/Excel based software. We are continuing to process this well data and are identifying potential candidate wells that can be used in Phase 2 to validate the new methodologies. In addition, preparation of the final technical report is underway

Applying probabilistic well-performance parameters to assessments of shale-gas resources

Science.gov (United States)

Charpentier, Ronald R.; Cook, Troy

2010-01-01

In assessing continuous oil and gas resources, such as shale gas, it is important to describe not only the ultimately producible volumes, but also the expected well performance. This description is critical to any cost analysis or production scheduling. A probabilistic approach facilitates (1) the inclusion of variability in well performance within a continuous accumulation, and (2) the use of data from developed accumulations as analogs for the assessment of undeveloped accumulations. In assessing continuous oil and gas resources of the United States, the U.S. Geological Survey analyzed production data from many shale-gas accumulations. Analyses of four of these accumulations (the Barnett, Woodford, Fayetteville, and Haynesville shales) are presented here as examples of the variability of well performance. For example, the distribution of initial monthly production rates for Barnett vertical wells shows a noticeable change with time, first increasing because of improved completion practices, then decreasing from a combination of decreased reservoir pressure (in infill wells) and drilling in less productive areas. Within a partially developed accumulation, historical production data from that accumulation can be used to estimate production characteristics of undrilled areas. An understanding of the probabilistic relations between variables, such as between initial production and decline rates, can improve estimates of ultimate production. Time trends or spatial trends in production data can be clarified by plots and maps. The data can also be divided into subsets depending on well-drilling or well-completion techniques, such as vertical in relation to horizontal wells. For hypothetical or lightly developed accumulations, one can either make comparisons to a specific well-developed accumulation or to the entire range of available developed accumulations. Comparison of the distributions of initial monthly production rates of the four shale-gas accumulations that were

Deep learning and data assimilation for real-time production prediction in natural gas wells

NARCIS (Netherlands)

Loh, K.K.L.; Shoeibi Omrani, P.S.; Linden, R.J.P. van der

2018-01-01

The prediction of the gas production from mature gas wells, due to their complex end-of-life behavior, is challenging and crucial for operational decision making. In this paper, we apply a modified deep LSTM model for prediction of the gas flow rates in mature gas wells, including the uncertainties

Periodical gas flow around a well in porous media

International Nuclear Information System (INIS)

Shnaid, I.; Olek, S.

1996-01-01

Analytical solutions of the linearized governing equation are presented for periodic gas flow around a well in porous media. Two cases are considered: a fully penetrating well and a partially penetrating well. For the first case, a closed form solution is obtained, whereas for the second case the solution is in the form of eigenfunctions expansions. The results have practical application in compressed air energy storage. (authors)

Production of natural gas from methane hydrate by a constant downhole pressure well

International Nuclear Information System (INIS)

Ahmadi, Goodarz; Ji, Chuang; Smith, Duane H.

2007-01-01

Natural gas production from the dissociation of methane hydrate in a confined reservoir by a depressurizing downhole well was studied. The case that the well pressure was kept constant was treated, and two different linearization schemes in an axisymmetric configuration were used in the analysis. For different fixed well pressures and reservoir temperatures, approximate self similar solutions were obtained. Distributions of temperature, pressure and gas velocity field across the reservoir were evaluated. The distance of the decomposition front from the well and the natural gas production rate as functions of time were also computed. Time evolutions of the resulting profiles were presented in graphical forms, and their differences with the constant well output results were studied. It was shown that the gas production rate was a sensitive function of well pressure and reservoir temperature. The sensitivity of the results to the linearization scheme used was also studied

Abnormal liquid loading in gas wells of the Samandepe Gasfield in Turkmenistan and countermeasures

Directory of Open Access Journals (Sweden)

Peijun Zhang

2015-10-01

Full Text Available With complicated formation mechanisms, liquid loading in gas wells during gasfield development may significantly affect the productivity of gas wells and the ultimate recovery rate. Dynamic monitoring data of the Samandepe Gasfield in Turkmenistan shows that liquid loading can be found extensively in gas wells. Their formation mechanisms and negative impacts on gasfield development severely restrict the productivity enhancement of this gasfield. With their origins taken into consideration, liquid loads in gas wells were classified into three types: formation water, condensed liquid, and external liquid. By using the hydrostatic pressure gradient method and through PLT monitoring, properties of liquid loads in the Samandepe Gasfield were determined. In addition, formation mechanisms related to liquid loading in gas wells were obtained through analyses of critical fluid-carrying capacities and by using gas-reservoir production data. The following findings were obtained. Liquid loading was commonly found in this gas well with majority of reservoir formations in lower well intervals flooded. However, the formation mechanisms for these liquid loads are different from those of other gasfields. Due to long-term shut-down of gas wells, killing fluids precipitated and pores in lower reservoir formations were plugged. As a result, natural gas had no access to boreholes, killing fluids were impossibly carried out of the borehole. Instead, the killing fluid was detained at the bottomhole to generate liquid load and eliminate the possibility of formation water coning. Moreover, since the gasfield was dominated by block reservoirs with favorable physical properties and connectivity, impacts of liquid load on gasfield development were insignificant. Thus, to enhance the recovery rate of the Samandepe Gasfield significantly, it is necessary to expand the gasfield development scale and strengthen the development of marginal gas reservoirs.

A prediction method of natural gas hydrate formation in deepwater gas well and its application

Directory of Open Access Journals (Sweden)

Yanli Guo

2016-09-01

Full Text Available To prevent the deposition of natural gas hydrate in deepwater gas well, the hydrate formation area in wellbore must be predicted. Herein, by comparing four prediction methods of temperature in pipe with field data and comparing five prediction methods of hydrate formation with experiment data, a method based on OLGA & PVTsim for predicting the hydrate formation area in wellbore was proposed. Meanwhile, The hydrate formation under the conditions of steady production, throttling and shut-in was predicted by using this method based on a well data in the South China Sea. The results indicate that the hydrate formation area decreases with the increase of gas production, inhibitor concentrations and the thickness of insulation materials and increases with the increase of thermal conductivity of insulation materials and shutdown time. Throttling effect causes a plunge in temperature and pressure in wellbore, thus leading to an increase of hydrate formation area.

Effect of the improved fermentation on physicochemical properties and sensorial acceptability of sour cassava starch

Directory of Open Access Journals (Sweden)

Maria Janete Angeloni Marcon

2007-11-01

Full Text Available The aim of this work was to study the effect of improved fermentation on sour cassava starch, aiming to reduce its fermentation time and to enhance its expansion capacity as well as its viscoamylographic properties and its sensorial acceptability. Results showed that the improved process of cassava starch production did not harm starch expansion, physicochemical properties or sensorial acceptability; it also produced starches with different viscoamylographic properties, which compared favourably to those of the sour cassava starch produced through current industrial methods.O Polvilho azedo é caracterizado pelas suas propriedades físicas, químicas e reológicas, as quais são diferentes do amido nativo do qual se originou. A propriedade de expansão é uma das mais importantes características do produto, sendo um parâmetro fundamental de avaliação do polvilho azedo. O resultado do perfil viscoamilográfico também é uma importante maneira de avaliação uma vez que cada amido tem um padrão viscoamilográfico definido de acordo com sua organização granular. Este trabalho determinou o efeito da fermentação melhorada pela adição de glicose, sobre o polvilho azedo, apontando para uma redução no tempo de fermentação e avaliando sua capacidade de expansão, suas propriedades viscoamilográficas e aceitabilidade sensorial. O processo de produção de polvilho azedo melhorado não prejudicou a expansão do amido, suas propriedades físico-químicas e sensoriais, mas sim resultou em amidos com diferentes propriedades viscoamilográficas melhores comparativamente ao polvilho azedo produzido pelo processo industrial atual.

Well Integrity for Natural Gas Storage in Depleted Reservoirs and Aquifers

Energy Technology Data Exchange (ETDEWEB)

Freifeld, Barry M. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Oldenburg, Curtis M. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Jordan, Preston [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Pan, Lehua [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Perfect, Scott [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Morris, Joseph [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); White, Joshua [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Bauer, Stephen [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Blankenship, Douglas [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Roberts, Barry [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Bromhal, Grant [National Energy Technology Lab. (NETL), Morgantown, WV (United States); Glosser, Deborah [National Energy Technology Lab. (NETL), Morgantown, WV (United States); Wyatt, Douglas [National Energy Technology Lab. (NETL), Morgantown, WV (United States); Rose, Kelly [National Energy Technology Lab. (NETL), Morgantown, WV (United States)

2016-09-02

Introduction Motivation The 2015-2016 Aliso Canyon/Porter Ranch natural gas well blowout emitted approximately 100,000 tonnes of natural gas (mostly methane, CH₄) over four months. The blowout impacted thousands of nearby residents, who were displaced from their homes. The high visibility of the event has led to increased scrutiny of the safety of natural gas storage at the Aliso Canyon facility, as well as broader concern for natural gas storage integrity throughout the country. Federal Review of Well Integrity In April of 2016, the U.S. Department of Energy (DOE), in conjunction with the U.S. Department of Transportation (DOT) through the Pipeline and Hazardous Materials Safety Administration (PHMSA), announced the formation of a new Interagency Task Force on Natural Gas Storage Safety. The Task Force enlisted a group of scientists and engineers at the DOE National Laboratories to review the state of well integrity in natural gas storage in the U.S. The overarching objective of the review is to gather, analyze, catalogue, and disseminate information and findings that can lead to improved natural gas storage safety and security and thus reduce the risk of future events. The “Protecting our Infrastructure of Pipelines and Enhancing Safety Act of 2016’’ or the ‘‘PIPES Act of 2016,’’which was signed into law on June 22, 2016, created an Aliso Canyon Natural Gas Leak Task Force led by the Secretary of Energy and consisting of representatives from the DOT, Environmental Protection Agency (EPA), Department of Health and Human Services, Federal Energy Regulatory Commission (FERC), Department of Commerce and the Department of Interior. The Task Force was asked to perform an analysis of the Aliso Canyon event and make recommendations on preventing similar incidents in the future. The PIPES Act also required that DOT/PHMSA promulgate minimum safety standards for underground storage that would take effect within two years. Background on the DOE

Effectiveness of managed populations of wild and honey bees as supplemental pollinators of sour cherry (Prunus cerasus L.) under different climatic conditions

DEFF Research Database (Denmark)

Hansted, Lise; Grout, Brian William Wilson; Toldam-Andersen, Torben Bo

2015-01-01

Managed populations of Apis mellifera, Bombus terrestris and Osmia have been investigated rufa as sour cherry pollinators in two flowering seasons with different weather patterns. Flight activity of the three bee species during the pollination-receptive period of the cultivar ‘Stevnsbaer’ was rec......Managed populations of Apis mellifera, Bombus terrestris and Osmia have been investigated rufa as sour cherry pollinators in two flowering seasons with different weather patterns. Flight activity of the three bee species during the pollination-receptive period of the cultivar ‘Stevnsbaer...

Fruit Set of Several Sour Cherry Cultivars in Latvia Influenced by Weather Conditions Before and During Flowering

Directory of Open Access Journals (Sweden)

Feldmane Daina

2017-06-01

Full Text Available Fruit set is a crucial stage in the process of yield formation, which is influenced by environmental factors, growing technologies and peculiarities of genotype. The aim of the study was to evaluate the quality of pollen (viability and germination capacity and the effect of weather before and during flowering on fruit set in sour cherry cultivars ‘Latvijas Zemais’, ‘Zentenes’, ‘Bulatnikovskaya’, and ‘Orlica’. The research was carried out in Institute of Horticulture (Latvia University of Agriculture in 2009-2016. Good pollen viability and germination was found for cultivars ‘Latvijas Zemais’ and ‘Bulatnikovskaya’. Negative effects of increasing air temperature (in the range of 7.7 to 17.5 °C and relative humidity (in the range of 51.4 to 88.5% was observed for all cultivars during flowering. The effects of diurnal temperature fluctuations, wind and the amount of days with precipitation differed depending on sour cherry cultivar.

Well-to-wheel analysis of direct and indirect use of natural gas in passenger vehicles

International Nuclear Information System (INIS)

Curran, Scott J.; Wagner, Robert M.; Graves, Ronald L.; Keller, Martin; Green, Johney B.

2014-01-01

The abundance of natural gas in the United States because of the number of existing natural gas reserves and the recent advances in extracting unconventional reserves has been one of the main drivers for low natural gas prices. A question arises of what is the optimal use of natural gas as a transportation fuel. Is it more efficient to use natural gas in a stationary power application to generate electricity to charge electric vehicles, compress natural gas for onboard combustion in vehicles, or re-form natural gas into a denser transportation fuel? This study investigates the well-to-wheels energy use and greenhouse gas emissions from various natural gas to transportation fuel pathways and compares the results to conventional gasoline vehicles and electric vehicles using the US electrical generation mix. Specifically, natural gas vehicles running on compressed natural gas are compared against electric vehicles charged with electricity produced solely from natural gas combustion in stationary power plants. The results of the study show that the dependency on the combustion efficiency of natural gas in stationary power can outweigh the inherent efficiency of electric vehicles, thus highlighting the importance of examining energy use on a well-to-wheels basis. - Highlights: • Well-to-wheels analysis shows differences in use of natural gas for transportation. • Well-to-wheels approach needed to evaluate total energy use and greenhouse gas emissions. • Well-to-wheels energy and GHG (greenhouse gas) emissions depend on efficiency of the prime mover. • Efficiency of power generation critical for low GHG emissions with electric vehicles. • Fuel economy critical for low GHG emissions with compressed natural gas vehicles

Natural gas in 1951: Petroleum in 1951: Logs of wells for 1951. Annual publication

Energy Technology Data Exchange (ETDEWEB)

NONE

1954-12-31

The first part of this report summarises natural gas exploration activity, well drilling, infrastructure changes and improvements, production, distribution, consumption, and leakage during transmission or distribution of natural gas in Ontario. Includes lists of operators licensed to lease, prospect, drill or bore for, produce, and distribute natural gas in the province. The second part summarises oil industry activities, oil production, well drilling, petroleum and refined products imports, and petroleum refining operations. Relevant statistics are provided throughout both parts of the report. Also includes drillers` logs for oil and gas wells completed during the year.

Technologies applied to wells producing gas in Bolivia; Tecnologias aplicadas aos pocos produtores de gas em Bolivia

Energy Technology Data Exchange (ETDEWEB)

Nobrega, Fernando R.B. [Petroleo Brasileiro S.A. (PETROBRAS), Rio de Janeiro, RJ (Brazil); Carrillo, Marco A.; Barrerro, Dennys A. [PETROBRAS Bolivia S.A., La Paz (Bolivia)

2012-07-01

The This paper seeks to highlight the engineering, lessons learned and topics for improvement of the technologies used in gas wells drilled between November 2008 and October 2011 in an environment of Bolivian' subandino. Among technologies employed and commented hereunder has the drilling gas reservoirs in near balance using a dual phase fluid, with nitrogen; carrying out multilateral wells equipped with intelligent completion in such environment; as well as other technologies presented herein. This document was prepared on drilling operations performed in SAL-15, SAL-17, SBLSBL- 7 and SBL-8, comprising the period from November 2008 to October 2011. (author)

Antimicrobial effect of sour pomegranate sauce on Escherichia coli O157:H7 and Staphylococcus aureus.

Science.gov (United States)

Kışla, Duygu; Karabıyıklı, Şeniz

2013-05-01

Pomegranate sauce is one of the most popular pomegranate products produced in Turkey. This study was conducted to determine the minimum inhibitory concentrations (MICs) of both traditional and commercial sour pomegranate sauce samples on Staphylococcus aureus (ATCC 25923) and Escherichia coli O157:H7 (ATCC 43895). The initial microflora of the pomegranate sauce samples was determined by performing the enumerations of total aerobic mesophilic bacteria, yeast and mold, S. aureus, E. coli, and the determination of Salmonella spp. MIC tests were applied to the neutralized and the original (unneutralized) sour pomegranate sauce samples in order to put forth the inhibition effect depending on low pH value. It was found that inhibitory effect of the traditional and the commercial samples, except one sample, on pathogens was not only due to the acidity of the products. The results of MIC tests indicated that although both traditional and commercial samples showed a considerable inhibitory effect on test microorganisms, the traditional pomegranate sauce samples were more effective than the commercial ones. © 2013 Institute of Food Technologists®

Influence of the date of cut of rootstocks to the stub on growth of maider sour cherry trees cv. 'Łutówka'

Directory of Open Access Journals (Sweden)

Stanisław Wociór

2013-12-01

Full Text Available Over a three-year period (1997-1999 investigations were conducted on the effect of 6 date of cut to the stub on tree trunk diameter, height and branching of sour cherry maidens in the nursery.On the Prunus mahaleb seedling rootstock were found no significant influen ce of the date between January, 15 - March, 30 of cut to the stub on growth of sour cherry maidens cv. ´Łutówka' (tree trunk diameter and branching and efficiency of nursery. The date of cutting in 15 April decreased trunk diameter and percent of the first quality trees.

Numerical solution of fractured horizontal wells in shale gas reservoirs considering multiple transport mechanisms

Science.gov (United States)

Zhao, Yu-long; Tang, Xu-chuan; Zhang, Lie-hui; Tang, Hong-ming; Tao, Zheng-Wu

2018-06-01

The multiscale pore size and specific gas storage mechanism in organic-rich shale gas reservoirs make gas transport in such reservoirs complicated. Therefore, a model that fully incorporates all transport mechanisms and employs an accurate numerical method is urgently needed to simulate the gas production process. In this paper, a unified model of apparent permeability was first developed, which took into account multiple influential factors including slip flow, Knudsen diffusion (KD), surface diffusion, effects of the adsorbed layer, permeability stress sensitivity, and ad-/desorption phenomena. Subsequently, a comprehensive mathematical model, which included the model of apparent permeability, was derived to describe gas production behaviors. Thereafter, on the basis of unstructured perpendicular bisection grids and finite volume method, a fully implicit numerical simulator was developed using Matlab software. The validation and application of the new model were confirmed using a field case reported in the literature. Finally, the impacts of related influencing factors on gas production were analyzed. The results showed that KD resulted in a negligible impact on gas production in the proposed model. The smaller the pore size was, the more obvious the effects of the adsorbed layer on the well production rate would be. Permeability stress sensitivity had a slight effect on well cumulative production in shale gas reservoirs. Adsorbed gas made a major contribution to the later flow period of the well; the greater the adsorbed gas content, the greater the well production rate would be. This paper can improve the understanding of gas production in shale gas reservoirs for petroleum engineers.

Leakage detection of Marcellus Shale natural gas at an Upper Devonian gas monitoring well: a 3-d numerical modeling approach.

Science.gov (United States)

Zhang, Liwei; Anderson, Nicole; Dilmore, Robert; Soeder, Daniel J; Bromhal, Grant

2014-09-16

Potential natural gas leakage into shallow, overlying formations and aquifers from Marcellus Shale gas drilling operations is a public concern. However, before natural gas could reach underground sources of drinking water (USDW), it must pass through several geologic formations. Tracer and pressure monitoring in formations overlying the Marcellus could help detect natural gas leakage at hydraulic fracturing sites before it reaches USDW. In this study, a numerical simulation code (TOUGH 2) was used to investigate the potential for detecting leaking natural gas in such an overlying geologic formation. The modeled zone was based on a gas field in Greene County, Pennsylvania, undergoing production activities. The model assumed, hypothetically, that methane (CH4), the primary component of natural gas, with some tracer, was leaking around an existing well between the Marcellus Shale and the shallower and lower-pressure Bradford Formation. The leaky well was located 170 m away from a monitoring well, in the Bradford Formation. A simulation study was performed to determine how quickly the tracer monitoring could detect a leak of a known size. Using some typical parameters for the Bradford Formation, model results showed that a detectable tracer volume fraction of 2.0 × 10(-15) would be noted at the monitoring well in 9.8 years. The most rapid detection of tracer for the leak rates simulated was 81 days, but this scenario required that the leakage release point was at the same depth as the perforation zone of the monitoring well and the zones above and below the perforation zone had low permeability, which created a preferred tracer migration pathway along the perforation zone. Sensitivity analysis indicated that the time needed to detect CH4 leakage at the monitoring well was very sensitive to changes in the thickness of the high-permeability zone, CH4 leaking rate, and production rate of the monitoring well.

Natural gas in 1950: Petroleum in 1950: Logs of wells in 1950. Annual publication

Energy Technology Data Exchange (ETDEWEB)

NONE

1953-12-31

Part III of this annual report consists of three separate reports on natural gas; petroleum; and logs of wells. The natural gas report discusses production and distribution, changes and improvements; consumption and rates; and gas wells and their production. The petroleum report presents information on production and drilling by township; expansion; and petroleum importation and refining operations. The logs of wells are presented alphabetically by counties, townships, and owners, respectively.

Natural gas in 1952: Petroleum in 1952: Logs of wells for 1952. Annual publication

Energy Technology Data Exchange (ETDEWEB)

NONE

1955-12-31

Part III of this annual report consists of three separate reports on natural gas; petroleum; and logs of wells. The natural gas report discusses production and distribution, changes and improvements; consumption and rates; and gas wells and their production. The petroleum report presents information on production and drilling by township; expansion; and petroleum importation and refining operations. The logs of wells are presented alphabetically by counties, townships, and owners, respectively.

An unconventional rate decline approach for tight and fracture-dominated gas wells

Energy Technology Data Exchange (ETDEWEB)

Duong, A.N. [ConocoPhillips Canada Resources Corp., Calgary, AB (Canada)

2010-07-01

In both Canada and the United States, unconventional gas reservoirs, especially wet shale gas are being aggressively pursued for new development. Forecasting production and estimating reserves accurately for these resource plays has become increasingly important and necessary. This paper introduced an empirically derived decline model based on a long-term linear flow in a large number of wells in tight and shale gas reservoirs. A new methodology was developed for production analysis and forecasting of unconventional reservoirs based on this model. In order to represent any uncertainty in reserve estimation, this method also utilized probability distributions of reserves in forecasting resource plays. The paper discussed the methodology development including long-term linear flow and their associated equations, as well as several field examples including a gas retrograde case and individual well analysis. Result comparisons and a discussion of the results were also presented. It was concluded that pressure initialization used in numerical modeling based on fluid gradients may have been incorrect. Results from such numerical modeling may not be representative of the shale gas flow characteristics. 24 refs., 2 tabs., 15 figs., 1 appendix.

Increasing gas producer profitability with virtual well visibility via an end-to-end, wireless Internet gas monitoring system

Energy Technology Data Exchange (ETDEWEB)

McDougall, M.; Coleman, K.; Beck, R.; Lyon, R.; Potts, R. [Northrock Resources Ltd., Calgary, AB (Canada); Benterud, K. [Zed.i solutions, Calgary, AB (Canada)

2003-07-01

Most gas producing companies still use 100-year old technology to measure gas volumes because of the prohibitive costs of implementing corporate wide electronic information systems to replace circular mechanical chart technology. This paper describes how Northrock Resources Ltd. increased profitability using Smart-Alek{sup TM} while avoiding high implementation costs. Smart-Alek is a new type of fully integrated end-to-end electronic gas flow measurement (GFM) system based on Field Intelligence Network and End User Interference (FINE). Smart-Alek can analyze gas production through public wireless communications and a web-browser delivery system. The system has enabled Northrock to increase gas volumes with more accurate measurement and reduced downtime. In addition, operating costs were also decreased because the frequency of well visits was reduced and the administrative procedures of data collection was more efficient. The real-time well visibility of the tool has proven to be very effective in optimizing business profitability. 9 refs., 1 tab., 9 figs.

Control of degreening in postharvest green sour citrus fruit by electrostatic atomized water particles.

Science.gov (United States)

Yamauchi, Naoki; Takamura, Kohtaro; Shigyo, Masayoshi; Migita, Catharina Taiko; Masuda, Yukihiro; Maekawa, Tetsuya

2014-08-01

The effect of electrostatic atomized water particles (EAWP) on degreening of green sour citrus fruit during storage was determined. Superoxide anion and hydroxyl radicals included in EAWP were present on the surface of the fruit peel after the treatment. Hydrogen peroxide was formed from EAWP in an aqueous solution, which could indicate that a hydroxyl radical of EAWP turns to hydrogen peroxide in the fruit flavedo as well as in the aqueous solution. EAWP treatment effectively suppressed the degreening of green yuzu and Nagato-yuzukichi fruits during storage at 20°C. The enhancement in K+ ion leakage of both EAWP-treated fruits reduced in comparison with the control. In spite of EAWP treatment, total peroxide level in both fruits showed almost no changes during storage, suggesting that hydrogen peroxide formed by EAWP treatment could stimulate the activation of hydrogen peroxide scavenging system and control degreening of these fruits during storage. Copyright © 2014 Elsevier Ltd. All rights reserved.

High-yield well modes and production practices in the Longwangmiao Fm gas reservoirs, Anyue Gas Field, central Sichuan Basin

Directory of Open Access Journals (Sweden)

Zhongren Yu

2016-12-01

Full Text Available The lithologic Longwangmiao Fm gas reservoirs are situated in the Moxi Block of the Anyue Gas Field, central Sichuan Basin. Due to their great heterogeneity affected by the differential roles of lithologic facies and karstification, huge differences exist in the single-well gas yield tests. To improve the development efficiency of gas reservoirs and achieve the goal of “high yield but with few wells to be drilled”, it is especially important to establish a high-yield gas well mode by use of cores, logging, seismic data, etc., and through analysis of reservoir properties, high-yield controlling factors, and seismic response features of quality reservoirs and so on. The following findings were achieved. (1 The positive relationship between yield and the thickness of dissolved vug reservoirs is obvious. (2 The dissolved vug reservoirs are reflected as the type of honeycomb dark patches from the image logging and the conventional logging is featured generally by “Three Lows and Two Highs (i.e., low GR, low RT and low DEN but high AC and high CNL”. (3 From the seismic profile, the highlighted spots (strong peaks correspond to the bottom boundary of the Longwangmiao Fm reservoirs. The trough waves in larger amplitude represents that there are more well-developed karsts in the reservoirs. On this basis, high-quality 3D seismic data was used for tracking and fine interpretation of those highlighted spots and trough waves on the strong peaks to describe the plane distribution of high-yield dissolved vug reservoirs in this study area. This study is of great significance to the good planning of development wells and well trajectory planning and adjustment. As a result, high-thickness dissolved vug reservoirs have been targeted in this study area with the tested gas yield of 28 wells reaching up to 100 × 104 m3/d among the completed and tested 30 wells in total.

Operation of flooded wells by the gas-lift method

Energy Technology Data Exchange (ETDEWEB)

Li, G S; Kabirov, M M; Nigay, Yu V

1983-01-01

A study is made of the factors which influence the effectiveness of operation of the gas-lift lifter during progressive flooding of a well. The law governing the change in its efficiency under the given conditions is also examined.

Compact type mutants in apple and sour cherries

International Nuclear Information System (INIS)

Zagaja, S.W.; Przybyla, A.

1976-01-01

Induction of mutations in deciduous fruits is considered complementary to the conventional breeding methods. Several promissing mutants, particularly in apples, were described and some of them were introduced to commercial orchards. Studies described herein are aimed at developing compact type mutants in apple cultivars, apple rootstocks and in sour cherry cultivars. Data obtained so far confirm the results of the other authors, who developed compact type mutants in apples and sweet cherries. Physiological studies have shown that the leaves of spontaneous apple mutants of compact type are more efficient in photosynthesis than the leaves of respective standards. In spite of this, using branch ringing techniques, it was found that the leaves of compacts and those of standards do not differ in their productivity. There seem to be several advantages in employing tissue culture technique in mutation breeding. That is why a project was started to work out a method of growing apple shoots from adventitious buds developed on sections of roots. (author)

ADVANCED TECHNOLOGIES FOR STRIPPER GAS WELL ENHANCEMENT

International Nuclear Information System (INIS)

Charles M. Boyer II; Ronald J. MacDonald P.G.

2002-01-01

As part of Task 1 in Advanced Technologies for Stripper Gas Well Enhancement, Schlumberger-Holditch Reservoir Technologies (H-RT) has joined with two Appalachian Basin producers, Great Lakes Energy Partners, LLC, and Belden and Blake Corporation to develop methodologies for identification and enhancement of stripper wells with economic upside potential. These industry partners have provided us with data for more than 700 wells in northwestern Pennsylvania. Phase 1 goals of this project are to develop and validate methodologies that can quickly and cost-effectively identify wells with enhancement potential. We have continued to enhance and streamline our software, and we are testing the final stages of our new Microsoft(trademark) Access/Excel based software. We are continuing to process the information and are identifying potential candidate wells that can be used in Phase 2 to validate the new methodologies. In addition, preparation of the final technical report is underway. During this quarter, we have presented our project and discussed the software to numerous Petroleum Technology Transfer Council (PTTC) workshops located in various regions of the United States

Analysis of the structural steels corrosion resistance in sour water from petroleum refineries; Analise da resistencia a corrosao de acos estruturais em aguas acidas de refinarias de petroleo

Energy Technology Data Exchange (ETDEWEB)

Proenca, Marcos B.; Freire, Celia M. de A. [Universidade Estadual de Campinas, SP (Brazil). Faculdade de Engenharia Mecanica; Santos, Margatita B. [Universidade Estadual de Campinas, SP (Brazil). Inst. de Fisica. Dept. de Fisica Aplicada

1994-07-01

The presence of H{sub 2} S in refineries FCC sour water provokes the formation of a passive Fe S scale. The cyanides present on sour water remove this scale, raising the corrosion rate in pipping and vessels. In this work it was measured the corrosion rate of structural steels in this water by electrochemical methods. Anodic polarization curves were plotted and the corrosion rates of the steels were determined. (author)

Problems in the wellbore integrity of a shale gas horizontal well and corresponding countermeasures

Directory of Open Access Journals (Sweden)

Zhonglan Tian

2015-12-01

Full Text Available In the Changning–Weiyuan national shale gas demonstration area, SW Sichuan Basin, the wellbore integrity damage occurs in some shale gas wells and has direct effect on the gas production rate of single shale gas horizontal well. After statistics analysis was performed on the problems related with wellbore integrity, such as casing damage, casing running difficulty and cement sheath blow-by, the multi-factor coupling casing stress calculation and evaluation mode laws established. Then study was conducted on the influential mechanism of multi-factor coupling (temperature effect, casing bending and axial pressure on casing damage. The shale slip mechanism and its relationship with casing sheared formation were analyzed by using the Mohr–Coulomb criterion. Inversion analysis was performed on the main controlling factors of casing friction by using the developed casing hook load prediction and friction analysis software. And finally, based on the characteristics of shale gas horizontal wells, wellbore integrity control measures were proposed in terms of design and construction process, so as to improve the drilling quality (DQ. More specifically, shale gas well casing design calculation method and check standard were modified, well structure and full bore hole trajectory design were optimized, drilling quality was improved, cement properties were optimized and cement sealing integrity during fracturing process was checked. These research findings are significant in the design and management of future shale gas borehole integrity.

New methodology for aquifer influx status classification for single wells in a gas reservoir with aquifer support

Directory of Open Access Journals (Sweden)

Yong Li

2016-10-01

Full Text Available For gas reservoirs with strong bottom or edge aquifer support, the most important thing is avoiding aquifer breakthrough in a gas well. Water production in gas wells does not only result in processing problems in surface facilities, but it also explicitly reduces well productivity and reservoir recovery. There are a lot of studies on the prediction of water breakthrough time, but they are not completely practicable due to reservoir heterogeneity. This paper provides a new method together with three diagnostic curves to identify aquifer influx status for single gas wells; the aforementioned curves are based on well production and pressure data. The whole production period of a gas well can be classified into three periods based on the diagnostic curves: no aquifer influx period, early aquifer influx period, and middle-late aquifer influx period. This new method has been used for actual gas well analysis to accurately identify gas well aquifer influx status and the water breakthrough sequence of all wells in the same gas field. Additionally, the evaluation results are significantly beneficial for well production rate optimization and development of an effective gas field.

Flaring versus thermal incineration of waste gases in the oil and gas industry

International Nuclear Information System (INIS)

Smolarski, G.M.

1999-01-01

The efficient combustion of waste gases at oil processing plants, battery or well sites is discussed. Several problem situations are examined, field test results are reviewed, and custom design systems are explained including modifications to systems to conserve fuel. It is shown that combustion of waste gases in fuel efficient thermal incinerators is a practical means of disposal, particularly for sour or toxic gas of low heating value. These gases contain noxious compounds that may cause odours or adverse health effects. Results of a field tests of a portable in-situ incinerator show that compared to flaring (to oxide waste gas), incineration is a more efficient form of waste management. Emission tests also prove the superior performance of incineration. The feasibility of incinerating oil storage tank vapours was also demonstrated. Tests were also conducted with a fuel-efficient Glycol Still Off-Gas Incinerator which was developed to control toxic waste emissions. Glycol dehydration removes water vapour from natural gas. The key compounds that are removed by glycol are aromatic hydrocarbons or BTEX compounds (benzene, toluene, ethylbenzene and xylene), and sulphur compounds. The main design considerations for any incinerator are temperature, turbulence and residence time. An incinerator exit temperature of 760 degrees C is generally needed to reduce sulphur compounds. 2 refs., 8 tabs., 7 figs

The Effect of Green Tea versus Sour Tea on Insulin Resistance, Lipids Profiles and Oxidative Stress in Patients with Type 2 Diabetes Mellitus: A Randomized Clinical Trial

Directory of Open Access Journals (Sweden)

Hassan Mozaffari-Khosravi

2014-09-01

Full Text Available Background: By decreasing oxidative stress and whereby decreasing insulin resistance, it may be possible to decrease complications of Diabetes Mellitus (DM. Green tea and sour tea contain phytochemicals which have anti-oxidative function. The aim of this study is to compare the effect of sour and green tea consumption on insulin resistance and oxidative stress in DM. Methods: This study is a randomized clinical trial in which 100 type 2 diabetes patients were randomly assigned into sour tea group (ST and green tea group (GT. The patients were instructed to drink 150ml sour tea and green tea infusion, respectively, three times a day for 4 weeks. Fasting blood sugar (FBS, fructosamine, lipid profiles, fasting blood insulin (FBI, homeostasis model assessment of insulin resistance (HOMA-IR; beta cell function (b%, insulin sensitivity (S% and malondialdehyde (MDA were monitored. Results: HDL-c significantly increased in both groups. The median of FBI in GT showed significant decrease (8.5 to 6.6 μIU/mL unlike the ST which showed significant increase (8.2 to 16.3 μIU/mL. The median of HOMA-IR after the intervention in GT showed lower levels than the ST (1.1 vs. 1.6, P=0.004. The median of b% only in ST showed significant increase from 38.2% at the baseline to 47.7% after the intervention. The mean of S% only in ST showed significant decrease after the intervention. Conclusion: This study shows that the use of 150 ml infusion of green tea or sour tea, three times a day for four weeks, has positive effect on insulin resistance and certain lipoproteins in type 2 DM. Trial Registration Number: IRCT201107317161N1

Life cycle water consumption and wastewater generation impacts of a Marcellus shale gas well.

Science.gov (United States)

Jiang, Mohan; Hendrickson, Chris T; VanBriesen, Jeanne M

2014-01-01

This study estimates the life cycle water consumption and wastewater generation impacts of a Marcellus shale gas well from its construction to end of life. Direct water consumption at the well site was assessed by analysis of data from approximately 500 individual well completion reports collected in 2010 by the Pennsylvania Department of Conservation and Natural Resources. Indirect water consumption for supply chain production at each life cycle stage of the well was estimated using the economic input-output life cycle assessment (EIO-LCA) method. Life cycle direct and indirect water quality pollution impacts were assessed and compared using the tool for the reduction and assessment of chemical and other environmental impacts (TRACI). Wastewater treatment cost was proposed as an additional indicator for water quality pollution impacts from shale gas well wastewater. Four water management scenarios for Marcellus shale well wastewater were assessed: current conditions in Pennsylvania; complete discharge; direct reuse and desalination; and complete desalination. The results show that under the current conditions, an average Marcellus shale gas well consumes 20,000 m(3) (with a range from 6700 to 33,000 m(3)) of freshwater per well over its life cycle excluding final gas utilization, with 65% direct water consumption at the well site and 35% indirect water consumption across the supply chain production. If all flowback and produced water is released into the environment without treatment, direct wastewater from a Marcellus shale gas well is estimated to have 300-3000 kg N-eq eutrophication potential, 900-23,000 kg 2,4D-eq freshwater ecotoxicity potential, 0-370 kg benzene-eq carcinogenic potential, and 2800-71,000 MT toluene-eq noncarcinogenic potential. The potential toxicity of the chemicals in the wastewater from the well site exceeds those associated with supply chain production, except for carcinogenic effects. If all the Marcellus shale well wastewater is

Assessment of Uinta Basin Oil and Natural Gas Well Pad Pneumatic Controller Emissions

Science.gov (United States)

In the fall of 2016, a field study was conducted in the Uinta Basin Utah to improve information on oil and natural gas well pad pneumatic controllers (PCs) and emission measurement methods. A total of 80 PC systems at five oil sites (supporting six wells) and three gas sites (sup...

Numerical Modeling of Methane Leakage from a Faulty Natural Gas Well into Fractured Tight Formations.

Science.gov (United States)

Moortgat, Joachim; Schwartz, Franklin W; Darrah, Thomas H

2018-03-01

Horizontal drilling and hydraulic fracturing have enabled hydrocarbon recovery from unconventional reservoirs, but led to natural gas contamination of shallow groundwaters. We describe and apply numerical models of gas-phase migration associated with leaking natural gas wells. Three leakage scenarios are simulated: (1) high-pressure natural gas pulse released into a fractured aquifer; (2) continuous slow leakage into a tilted fractured formation; and (3) continuous slow leakage into an unfractured aquifer with fluvial channels, to facilitate a generalized evaluation of natural gas transport from faulty natural gas wells. High-pressure pulses of gas leakage into sparsely fractured media are needed to produce the extensive and rapid lateral spreading of free gas previously observed in field studies. Transport in fractures explains how methane can travel vastly different distances and directions laterally away from a leaking well, which leads to variable levels of methane contamination in nearby groundwater wells. Lower rates of methane leakage (≤1 Mcf/day) produce shorter length scales of gas transport than determined by the high-pressure scenario or field studies, unless aquifers have low vertical permeabilities (≤1 millidarcy) and fractures and bedding planes have sufficient tilt (∼10°) to allow a lateral buoyancy component. Similarly, in fractured rock aquifers or where permeability is controlled by channelized fluvial deposits, lateral flow is not sufficiently developed to explain fast-developing gas contamination (0-3 months) or large length scales (∼1 km) documented in field studies. Thus, current efforts to evaluate the frequency, mechanism, and impacts of natural gas leakage from faulty natural gas wells likely underestimate contributions from small-volume, low-pressure leakage events. © 2018, National Ground Water Association.

Sulphur sales should bear processing cost

Energy Technology Data Exchange (ETDEWEB)

Jones, W

1969-01-20

In this analysis, all the pertinent costs of processing sulfur from sour gas are allocated to one item, the sulfur produced from the sour gas. Therefore, in the graphical representations, the sour gas fed to the amine unit was considered to be dry sour gas containing no carbon dioxide. Cases were considered for increasing percentages of hydrogen sulfide. Costs of amine units and sulfur units were estimated and updated from the literature both for capital investment and operating costs for plants sized to produce sulfur at rates ranging from 20 to 500 long tons per day. The figures shown on the graph for unit costs confirm that the sulfur industry in W. Canada has been selling its sulfur below cost until recently. The conditioning of the natural gas bore the cost of producing sulfur, a sign of unhealthy sulfur markets. Producers would be wise to replenish their sulfur stockpiles to obtain stable marketing conditions at good prices.

Reservoir souring: Problems, uncertainties and modelling. Part I: Problems and uncertainty involved in prediction. Part II: Preliminary investigations of a computational model

International Nuclear Information System (INIS)

Paulsen, J.E.; Read, P.A.; Thompson, C.P.; Jelley, C.; Lezeau, P.

1996-01-01

The paper relates to improved oil recovery (IOR) techniques by mathematical modelling. The uncertainty involved in modelling of reservoir souring is discussed. IOR processes are speculated to influence a souring process in a positive direction. Most models do not take into account pH in reservoir fluids, and thus do not account for partitioning behaviour of sulfide. Also, sulfide is antagonistic to bacterial metabolism and impedes to bacterial metabolism and impedes the sulfate reduction rate, this may be an important factor in modelling. Biofilms are thought to play a crucial role in a reservoir souring process. Biofilm in a reservoir matrix is different from biofilm in open systems. This has major impact on microbial impact on microbial transport and behaviour. Studies on microbial activity in reservoir matrices must be carried out with model cores, in order to mimic a realistic situation. Sufficient data do not exist today. The main conclusion is that a model does not reflect a true situation before the nature of these elements is understood. A simplified version of an Norwegian developed biofilm model is discussed. The model incorporates all the important physical phenomena studied in the above references such as bacteria growth limited by nutrients and/or energy sources and hydrogen sulfide adsorption. 18 refs., 8 figs., 1 tab

Reservoir souring: Problems, uncertainties and modelling. Part I: Problems and uncertainty involved in prediction. Part II: Preliminary investigations of a computational model

Energy Technology Data Exchange (ETDEWEB)

Paulsen, J.E. [Rogalandsforskning, Stavanger (Norway); Read, P.A.; Thompson, C.P.; Jelley, C.; Lezeau, P.

1996-12-31

The paper relates to improved oil recovery (IOR) techniques by mathematical modelling. The uncertainty involved in modelling of reservoir souring is discussed. IOR processes are speculated to influence a souring process in a positive direction. Most models do not take into account pH in reservoir fluids, and thus do not account for partitioning behaviour of sulfide. Also, sulfide is antagonistic to bacterial metabolism and impedes to bacterial metabolism and impedes the sulfate reduction rate, this may be an important factor in modelling. Biofilms are thought to play a crucial role in a reservoir souring process. Biofilm in a reservoir matrix is different from biofilm in open systems. This has major impact on microbial impact on microbial transport and behaviour. Studies on microbial activity in reservoir matrices must be carried out with model cores, in order to mimic a realistic situation. Sufficient data do not exist today. The main conclusion is that a model does not reflect a true situation before the nature of these elements is understood. A simplified version of an Norwegian developed biofilm model is discussed. The model incorporates all the important physical phenomena studied in the above references such as bacteria growth limited by nutrients and/or energy sources and hydrogen sulfide adsorption. 18 refs., 8 figs., 1 tab.

SemGroup acquisition of central Alberta midstream : case study

International Nuclear Information System (INIS)

Purcell, T.

2005-01-01

A case study of SemGroup's acquisition of Central Alberta Midstream was presented. SemCAMS specializes in providing more efficient supply, storage, and distribution assets and services. Seminole Canada Gas is a leading independent natural gas marketing and energy asset management company that currently markets 369 MMbtu per day. The company purchases natural gas in western Canada for fee-based marketing services while also managing firm transportation contracts and providing gas storage for third party customers. SemCAMS owns the largest sour gas processor in Alberta as well as 3 sour gas processing plants, 600 miles of gathering pipeline, and a sweet gas processing plant. the company is also planning increased drilling and production activities and is now pursuing aggressive land acquisition policies. Over 25,000 square miles of land have been acquired. It was concluded that midstream companies should be customer-focused, provide reliability and guarantees, infrastructure investment and optimization. tabs., figs

New perspective on gas-well liquid loading and unloading

NARCIS (Netherlands)

Veeken, C.A.M.; Belfroid, S.P.C.

2010-01-01

This paper discusses the multiphase flow mechanism responsible for gas-well liquid loading. It shows that the conventional idea of droplet flow reversal (Turner et al. (1969)) does not capture reality and that actual observations are better described by film flow reversal. This paper subsequently

Characterization of Sugar and Polyphenolic Diversity in Floral Nectar of Different 'Oblačinska' Sour Cherry Clones.

Science.gov (United States)

Guffa, Basem; Nedić, Nebojša M; Dabić Zagorac, Dragana Č; Tosti, Tomislav B; Gašić, Uroš M; Natić, Maja M; Fotirić Akšić, Milica M

2017-09-01

'Oblačinska' sour cherry, an autochthonous cultivar, is the most planted cultivar in Serbian orchards. Since fruit trees in temperate zone reward insects by producing nectar which 'quality' affects the efficiency of insect pollination, the aim of this study was analyzing of sugars and polyphenolics in floral nectar of 16 'Oblačinska' sour cherry clones with different yielding potential. The contents of sugars and sugar alcohols were analyzed by ion chromatography, while polyphenolic profile was established using liquid chromatography/mass spectrometry technique. Fourteen sugars and six sugar alcohols were detected in nectar samples and the most abundant were fructose, glucose, and sucrose. Eleven polyphenols were quantified using available standards, while another 17 were identified according to their exact masses and characteristic fragmentations. Among quantified polyphenols, rutin, naringenin, and chrysin were the most abundant in nectar. Principal component analysis showed that some polyphenol components (naringin, naringenin, and rutin) together with sugars had high impact of spatial distribution of nectar samples on score plot. © 2017 Wiley-VHCA AG, Zurich, Switzerland.

Strategic conservation of orchard germplasm based on indigenous knowledge and genetic diversity: a case study of sour orange populations in China.

Science.gov (United States)

Ming, Feng; Liu, Qi-Kun; Shi, Jin-Lei; Wang, Wei; Lu, Bao-Rong

2009-01-01

To effectively conserve sour orange (Citrus aurantium L.) germplasm on two islands at the estuary of the Yangtze River in China, we estimated genetic variation and relationships of the known parental trees and their proposed descendents (young trees) using the fingerprints of random amplified polymorphic DNA (RAPD). Results based on RAPD analyses showed considerable genetic diversity in the parental populations (H(e)=0.202). The overall populations including the parental and young trees showed slightly higher genetic diversity (H(e)=0.298) than the parents, with about 10% variation between populations. An unweighted pair group method with arithmetic mean analysis dendrogram based on cluster analysis of the Jaccard similarity among individuals demonstrated a more complicated relationship of the parental and young trees from the two islands, although the young trees showed a clear association with parental trees. This indicates a significant contribution of parental trees in establishing the sour orange populations on the two islands. According to farmers' knowledge, conservation of only one or two parental trees would be sufficient because they believed that the whole populations were generated from a single mother tree. However, this study suggests that preserving most parental trees and some selected young trees with distant genetic relationships should be an effective conservation strategy for sour orange germplasm on the two islands.

Gas lift for annular flow in San Andres well No. 24

Energy Technology Data Exchange (ETDEWEB)

Zenteno, E B

1968-10-01

Gas lift is a method of artificial lift which utilizes the expansive energy of compressed gas to lift fluid from the formation up to the surface separation installation. A wide range of operations exists for gas lifting. For making a decision regarding the use of such a method, the following steps are recommended: (1) establish the well fluid characteristics, the productivity index, the oil/water relationship, the fluid properties, the diameter of the tubing and similar data; (2) for the range of production desired, calculate a pressure gradient curve for the fluid below the point of gas injection; (3) supposing there is a difference in the relationship of injected gas to oil, calculate a pressure gradient curve of the fluid above the point of gas injection (this assumes a constant surface discharge pressure); and (4) simultaneously solve (2) and (3), which will permit determination of the variation according to depth of the point of gas injection, together with the pressure of the injected gas, and also the relation between the injected gas and the oil. Finally, calculate the theoretical potential necessary for the desired compression of the gas to such surface pressure that it will discharge at an injection pressure that will produce optimized conditions for development of the desired production.

Chemical contamination of groundwater at gas processing plants - the past, the present and the future

International Nuclear Information System (INIS)

Wrubleski, R.M.; Drury, C.R.

1997-01-01

The chemicals used to remove the sour gas components (primarily H 2 S) from raw gas in the sour gas sweetening processes were discussed. The chemicals, mainly amines and physical absorbents, have been found as contaminants in soil and groundwater at several sites. Studies have been conducted to evaluate the behaviour of some of these chemicals. In particular, the contamination by sulfolane and diisopropanolamine (DIPA) which originate from the Sulfinol R sweetening process, was discussed. Prior to the mid 1970s wastes from these processes were disposed of on site in landfills that were not engineered for groundwater protection. By the mid 1970s the landfills were closed by capping. Many of the gas plant sites were located on elevated terrain where hydraulic gradient was available for downward movement of groundwater and any chemicals contained within. Contaminant movement in fractured bedrock has also affected drinking water. Ground water monitoring began in the mid 1980s to address environmental concerns, focusing on monitoring for potability, metals and organics. It was discovered that most of the plants using the Sulfinol process had groundwater contaminated with sulfolane levels ranging from 1 ppm to over 800 ppm. A research project was developed to determine the soil interaction parameters and biodegradation behaviour of pure sulfolane and DIPA to provide data in order to predict plume migration. Ecotoxicity tests were also performed to verify toxicity effects of sulfolane, DIPA, reclaimer bottoms and observed biodegradation metabolites to bio-organisms and aquatic life in aquatic receptors. 3 refs., 1 tab., 1 fig

Chemical contamination of groundwater at gas processing plants - the past, the present and the future

Energy Technology Data Exchange (ETDEWEB)

Wrubleski, R.M.; Drury, C.R. [Shell Canada Ltd., Calgary, AB (Canada). Calgary Research Centre; Sevigny, J.H. [Komex Consultants Ltd., Calgary, AB (Canada)

1997-12-31

The chemicals used to remove the sour gas components (primarily H{sub 2}S) from raw gas in the sour gas sweetening processes were discussed. The chemicals, mainly amines and physical absorbents, have been found as contaminants in soil and groundwater at several sites. Studies have been conducted to evaluate the behaviour of some of these chemicals. In particular, the contamination by sulfolane and diisopropanolamine (DIPA) which originate from the Sulfinol{sup R} sweetening process, was discussed. Prior to the mid 1970s wastes from these processes were disposed of on site in landfills that were not engineered for groundwater protection. By the mid 1970s the landfills were closed by capping. Many of the gas plant sites were located on elevated terrain where hydraulic gradient was available for downward movement of groundwater and any chemicals contained within. Contaminant movement in fractured bedrock has also affected drinking water. Ground water monitoring began in the mid 1980s to address environmental concerns, focusing on monitoring for potability, metals and organics. It was discovered that most of the plants using the Sulfinol process had groundwater contaminated with sulfolane levels ranging from 1 ppm to over 800 ppm. A research project was developed to determine the soil interaction parameters and biodegradation behaviour of pure sulfolane and DIPA to provide data in order to predict plume migration. Ecotoxicity tests were also performed to verify toxicity effects of sulfolane, DIPA, reclaimer bottoms and observed biodegradation metabolites to bio-organisms and aquatic life in aquatic receptors. 3 refs., 1 tab., 1 fig.

Direct measurements of methane emissions from abandoned oil and gas wells in Pennsylvania.

Science.gov (United States)

Kang, Mary; Kanno, Cynthia M; Reid, Matthew C; Zhang, Xin; Mauzerall, Denise L; Celia, Michael A; Chen, Yuheng; Onstott, Tullis C

2014-12-23

Abandoned oil and gas wells provide a potential pathway for subsurface migration and emissions of methane and other fluids to the atmosphere. Little is known about methane fluxes from the millions of abandoned wells that exist in the United States. Here, we report direct measurements of methane fluxes from abandoned oil and gas wells in Pennsylvania, using static flux chambers. A total of 42 and 52 direct measurements were made at wells and at locations near the wells ("controls") in forested, wetland, grassland, and river areas in July, August, October 2013 and January 2014, respectively. The mean methane flow rates at these well locations were 0.27 kg/d/well, and the mean methane flow rate at the control locations was 4.5 × 10(-6) kg/d/location. Three out of the 19 measured wells were high emitters that had methane flow rates that were three orders of magnitude larger than the median flow rate of 1.3 × 10(-3) kg/d/well. Assuming the mean flow rate found here is representative of all abandoned wells in Pennsylvania, we scaled the methane emissions to be 4-7% of estimated total anthropogenic methane emissions in Pennsylvania. The presence of ethane, propane, and n-butane, along with the methane isotopic composition, indicate that the emitted methane is predominantly of thermogenic origin. These measurements show that methane emissions from abandoned oil and gas wells can be significant. The research required to quantify these emissions nationally should be undertaken so they can be accurately described and included in greenhouse gas emissions inventories.

Increasing gas producer profitability with virtual well visibility via an end-to-end wireless Internet gas monitoring system

Energy Technology Data Exchange (ETDEWEB)

McDougall, M. [Northrock Resources Ltd., Calgary, AB (Canada); Benterud, K. [Zed.i solutions, Calgary, AB (Canada)

2003-07-01

This PowerPoint presentation describes how Northrock Resources Ltd. increased profitability using Smart-Alek{sup TM} while avoiding high implementation costs. Smart-Alek is a new type of fully integrated end-to-end electronic gas flow measurement (GFM) system based on Field Intelligence Network and End User Interference (FINE). Smart-Alek can analyze gas production through public wireless communications and a web-browser delivery system. The system has enabled Northrock to increase gas volumes with more accurate measurement and reduced downtime. In addition, operating costs have decreased because the frequency of well visits has been reduced and the administrative procedures of data collection is more efficient. The real-time well visibility of the tool has proven to be very effective in optimizing business profitability. 7 figs.

An Investigation on Gas Lift Performance Curve in an Oil-Producing Well

Directory of Open Access Journals (Sweden)

Deni Saepudin

2007-01-01

Full Text Available The main objective in oil production system using gas lift technique is to obtain the optimum gas injection rate which yields the maximum oil production rate. Relationship between gas injection rate and oil production rate is described by a continuous gas lift performance curve (GLPC. Obtaining the optimum gas injection rate is important because excessive gas injection will reduce production rate, and also increase the operation cost. In this paper, we discuss a mathematical model for gas lift technique and the characteristics of the GLPC for a production well, for which one phase (liquid is flowing in the reservoir, and two phases (liquid and gas in the tubing. It is shown that in certain physical condition the GLPC exists and is unique. Numerical computations indicate unimodal properties of the GLPC. It is also constructed here a numerical scheme based on genetic algorithm to compute the optimum oil production.

Gas release during salt well pumping: model predictions and comparisons to laboratory experiments

International Nuclear Information System (INIS)

Peurrung, L.M.; Caley, S.M.; Bian, E.Y.; Gauglitz, P.A.

1996-09-01

The Hanford Site has 149 single-shell tanks (SSTs) containing radioactive wastes that are complex mixes of radioactive and chemical products. Some of these wastes are known to generate mixtures of flammable gases, including hydrogen, nitrous oxide, and ammonia. Nineteen of these SSTs have been placed on the Flammable Gas Watch List (FGWL) because they are known or suspected, in all but one case, to retain these flammable gases. Salt well pumping to remove the interstitial liquid from SSTs is expected to cause the release of much of the retained gas, posing a number of safety concerns. Research at the Pacific Northwest National Laboratory (PNNL) has sought to quantify the release of flammable gases during salt well pumping operations. This study is being conducted for Westinghouse Hanford Company as part of the PNNL Flammable Gas Project. Understanding and quantifying the physical mechanisms and waste properties that govern gas release during salt well pumping will help to resolve the associated safety issues

Potential effect of natural gas wells on alluvial groundwater contamination at the Kansas City Plant

Energy Technology Data Exchange (ETDEWEB)

Pickering, D.A.; Laase, A.D. [Oak Ridge National Lab., TN (United States); Locke, D.A. [Oak Ridge Inst. for Science and Education, TN (United States)

1993-05-01

This report is the result of a request for further information about several abandoned natural gas wells at the US Department of Energy`s Kansas City Plant (KCP). The request was prompted by an old map showing several, possibly eight, natural gas wells located under or near what is now the southeast corner of the Main Manufacturing Building at KCP. Volatile organic compound contamination in the alluvial aquifer surrounding the gas wells might possibly contaminate the bedrock aquifer if the gas wells still exist as conduits. Several circumstances exist that make it doubtful that contamination is entering the bedrock aquifers: (1) because regional groundwater flow in the bedrock beneath the KCP is expected to be vertically upward, contaminants found in the alluvial aquifer should not migrate down the old wells; (2) because of the low hydraulic conductivity of the bedrock units, contaminant transport would be extremely slow if the contaminants were migrating down the wells; and (3) casing, apparently set through the alluvium in all of the wells, would have deteriorated and may have collapsed; if the casing collapsed, the silty clays in the alluvium would also collapse and seal the well. No definitive information has been discovered about the exact location of the wells. No further search for or consideration of the old gas wells is recommended.

Potential effect of natural gas wells on alluvial groundwater contamination at the Kansas City Plant

Energy Technology Data Exchange (ETDEWEB)

Pickering, D.A.; Laase, A.D. (Oak Ridge National Lab., TN (United States)); Locke, D.A. (Oak Ridge Inst. for Science and Education, TN (United States))

1993-05-01

This report is the result of a request for further information about several abandoned natural gas wells at the US Department of Energy's Kansas City Plant (KCP). The request was prompted by an old map showing several, possibly eight, natural gas wells located under or near what is now the southeast corner of the Main Manufacturing Building at KCP. Volatile organic compound contamination in the alluvial aquifer surrounding the gas wells might possibly contaminate the bedrock aquifer if the gas wells still exist as conduits. Several circumstances exist that make it doubtful that contamination is entering the bedrock aquifers: (1) because regional groundwater flow in the bedrock beneath the KCP is expected to be vertically upward, contaminants found in the alluvial aquifer should not migrate down the old wells; (2) because of the low hydraulic conductivity of the bedrock units, contaminant transport would be extremely slow if the contaminants were migrating down the wells; and (3) casing, apparently set through the alluvium in all of the wells, would have deteriorated and may have collapsed; if the casing collapsed, the silty clays in the alluvium would also collapse and seal the well. No definitive information has been discovered about the exact location of the wells. No further search for or consideration of the old gas wells is recommended.

Potential effect of natural gas wells on alluvial groundwater contamination at the Kansas City Plant

International Nuclear Information System (INIS)

Pickering, D.A.; Laase, A.D.; Locke, D.A.

1993-05-01

This report is the result of a request for further information about several abandoned natural gas wells at the US Department of Energy's Kansas City Plant (KCP). The request was prompted by an old map showing several, possibly eight, natural gas wells located under or near what is now the southeast corner of the Main Manufacturing Building at KCP. Volatile organic compound contamination in the alluvial aquifer surrounding the gas wells might possibly contaminate the bedrock aquifer if the gas wells still exist as conduits. Several circumstances exist that make it doubtful that contamination is entering the bedrock aquifers: (1) because regional groundwater flow in the bedrock beneath the KCP is expected to be vertically upward, contaminants found in the alluvial aquifer should not migrate down the old wells; (2) because of the low hydraulic conductivity of the bedrock units, contaminant transport would be extremely slow if the contaminants were migrating down the wells; and (3) casing, apparently set through the alluvium in all of the wells, would have deteriorated and may have collapsed; if the casing collapsed, the silty clays in the alluvium would also collapse and seal the well. No definitive information has been discovered about the exact location of the wells. No further search for or consideration of the old gas wells is recommended

Microsatellite marker development by partial sequencing of the sour passion fruit genome (Passiflora edulis Sims).

Science.gov (United States)

Araya, Susan; Martins, Alexandre M; Junqueira, Nilton T V; Costa, Ana Maria; Faleiro, Fábio G; Ferreira, Márcio E

2017-07-21

The Passiflora genus comprises hundreds of wild and cultivated species of passion fruit used for food, industrial, ornamental and medicinal purposes. Efforts to develop genomic tools for genetic analysis of P. edulis, the most important commercial Passiflora species, are still incipient. In spite of many recognized applications of microsatellite markers in genetics and breeding, their availability for passion fruit research remains restricted. Microsatellite markers in P. edulis are usually limited in number, show reduced polymorphism, and are mostly based on compound or imperfect repeats. Furthermore, they are confined to only a few Passiflora species. We describe the use of NGS technology to partially assemble the P. edulis genome in order to develop hundreds of new microsatellite markers. A total of 14.11 Gbp of Illumina paired-end sequence reads were analyzed to detect simple sequence repeat sites in the sour passion fruit genome. A sample of 1300 contigs containing perfect repeat microsatellite sequences was selected for PCR primer development. Panels of di- and tri-nucleotide repeat markers were then tested in P. edulis germplasm accessions for validation. DNA polymorphism was detected in 74% of the markers (PIC = 0.16 to 0.77; number of alleles/locus = 2 to 7). A core panel of highly polymorphic markers (PIC = 0.46 to 0.77) was used to cross-amplify PCR products in 79 species of Passiflora (including P. edulis), belonging to four subgenera (Astrophea, Decaloba, Distephana and Passiflora). Approximately 71% of the marker/species combinations resulted in positive amplicons in all species tested. DNA polymorphism was detected in germplasm accessions of six closely related Passiflora species (P. edulis, P. alata, P. maliformis, P. nitida, P. quadrangularis and P. setacea) and the data used for accession discrimination and species assignment. A database of P. edulis DNA sequences obtained by NGS technology was examined to identify microsatellite repeats in

The impact of oil and natural gas facilities on rural residential property values

International Nuclear Information System (INIS)

Boxall, P.C.

2005-01-01

This PowerPoint presentation examined challenges in the economic valuation of environmental changes within the context of formal real estate markets. It was proposed that some values that are expressed in markets can be affected by environmental changes and should be used in resource development land assessments. Details of indirect market valuation and revealed preference methods were reviewed. An outline of hedonic pricing was presented. It was noted that hedonic pricing can be used with other market values and prices such as tourism, art prices and hotel prices, where multivariate regression techniques are used and regression coefficients reveal information on the implicit prices of certain characteristics. Property value examples in the environmental economics literature were reviewed. A case study using data from eco-terrorism costs was presented. Issues concerning sour gas facilities were discussed with reference to public anxiety over hydrogen sulfide (H 2 S) toxicity and flares. Concerns over health risks and negative amenity impacts were discussed. The impacts of sour gas facilities on property values of residential acreages in and around Calgary were considered, and a map of the study area was presented. An outline of emergency plan response zones was provided. Price effects of industry facilities were presented, including marginal and cumulative impacts on price. It was concluded that oil and gas activities have significant impacts on rural residential property prices, but that industry members currently report that there is little to no effect. It was suggested that the research presented in this paper could be used to assess levels of compensation. tabs., figs

The Effect of Green Tea and Sour Tea (Hibiscus sabdariffa L.) Supplementation on Oxidative Stress and Muscle Damage in Athletes.

Science.gov (United States)

Hadi, Amir; Pourmasoumi, Makan; Kafeshani, Marzieh; Karimian, Jahangir; Maracy, Mohammad Reza; Entezari, Mohammad Hasan

2017-05-04

Additional oxygen consumption during intense exercises may lead to oxidative stress and contribute to muscular fatigue. Green tea and sour tea (Hibiscus sabdariffa L.), which contain various flavonoids and polyphenols, have many healthful properties such as anticarcinogenic, anti-inflammatory, and heart protecting effects. The aim of the present study was to assess the effects of green tea and sour tea supplementation on oxidative stress and muscle damage in soccer athletes. This randomized, double-blind control trial was conducted on 54 male soccer players. Participants were randomly assigned to three groups to receive: 450 mg/d green tea extract (GTE) in the first group (n = 18), 450 mg/d sour tea extract (STE) in the second group (n = 18) and 450 mg/d maltodextrin in the control group (n = 18). Fasting whole blood samples were taken under resting conditions at the beginning and the end of the study to quantify the serum levels of muscle damage indices, aspartate aminotransferase (AST), creatine kinase (CK), lactate dehydrogenase (LDH), and oxidative stress biomarkers, malondialdehyde (MDA), and total antioxidant capacity (TAC). After six weeks intervention, athletes who received GTE and STE supplements compared with the placebo had a significantly decreased MDA level (P = 0.008). Furthermore, STE supplementation resulted in a significant increase in TAC level compared with GTE and placebo groups (P = 0.01). However, supplementation with GTE and STE had no significant effects on muscle damage indices. GTE and STE supplementation have beneficial effects on oxidative stress status in male athletes. However, both kinds of tea extract did not affect muscle damage status.

Alternate method for gas measurement to offshore wells producing by plunger lift

Energy Technology Data Exchange (ETDEWEB)

Silva, Sergio Jose Goncalves e [PETROBRAS, Rio de Janeiro, RJ (Brazil). Exploracao e Producao; Mota, Francisco das Chagas [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil)

2008-07-01

The purpose of this paper is to describe an alternate method for gas measurement to wells producing by conventional plunger lift to a two phase separator in offshore production systems. The principle of the plunger lift is basically the use of a free piston acting as a mechanical interface between the formation gas and the produced liquids, greatly increasing the well's lifting efficiency. However, when the piston reaches the surface a liquid slug is produced through the flowline and it propagates into the separator where the phases are measured. Usually, orifice meter is widely used in separators to measure steady-state gas flow rate, but when intermittent flow is present, the gas causes the signal saturation of the differential pressure element ({delta}P), resulting in measurement distortion. The solution proposed in this work to estimate the gas flow rate during the liquid slug it was obtained through the mathematical modeling of the separator and with the use of System Identification Theory. Applying the ARX model it was possible to get the best fit to the collected data. So, with this model and its recursive variant (RARX) it was possible to prove that, with reasonable forecast degree, the signal of the gas flow rate can be recovered by starting from the signal of the pressure control valve of the separator. (author)

Production optimization of remotely operated gas wells

Energy Technology Data Exchange (ETDEWEB)

Juell, Aleksander

2012-07-01

From the introduction: The Remote Operations in Oklahoma Intended for Education (ROOKIE) project is a remote field laboratory constructed as a part of this research project. ROOKIE was initiated to provide data in research on production optimization of low productivity gas wells. In addition to this, ROOKIE is used as a teaching tool. Much of the remote operations technology used in the ROOKIE project has been used by the industry for several decades. The first use of remote data acquisition in Oklahoma was in 1989, as described by Luppens [7]. Even though this, for the most part, is old technology, the ROOKIE project is the first remote operations project set up with research and teaching as the main focus. This chapter will discuss the process of establishing the remote field laboratory and the data storage facilities. Results from the project will also be discussed. All testing, instrumentation installation, and modifications to the wells discussed in this chapter was performed by the author. The communication system between the well and NTNU, and the storage database was installed and configured by the author.(Author)

Optimization of the key geological target parameters of shale-gas horizontal wells in the Changning Block, Sichuan Basin

Directory of Open Access Journals (Sweden)

Hongzhi Yang

2016-12-01

Full Text Available In recent years, great progress has been made in geologic evaluation, engineering test and development optimization of the Lower Cambrian Wufeng Fm–Lower Silurian Longmaxi Fm shale gas in the Sichuan Basin, and the main shale gas exploitation technologies have been understood preliminarily. In addition, scale productivity construction has been completed in Jiaoshiba, Changning and Weiyuan blocks. In this paper, the Wufeng Fm–Longmaxi Fm shale gas wells in Changning Block were taken as the study object to provide technical reference for the development design of similar shale-gas horizontal wells. The technology combining geology with engineering, dynamic with static, and statistical analysis with simulation prediction was applied to quantify the main factors controlling shale-gas well productivity, develop the shale-gas well production prediction model, and optimize the key technical parameters of geologic target of shale-gas horizontal wells in the block (e.g. roadway orientation, location and spacing, horizontal section length and gas well production index. In order to realize high productivity of shale gas wells, it is necessary to maximize the included angle between the horizontal section orientation and the maximum major stress and fracture development direction, deploy horizontal-well roadway in top-quality shale layers, and drill the horizontal section in type I reservoirs over 1000 m long. It is concluded that high productivity of shale gas wells is guaranteed by the horizontal-well wellbore integrity and the optimized low-viscosity slickwater and ceramsite fracturing technology for complex fracture creation. Based on the research results, the technical policies for shale gas development of Changning Block are prepared and a guidance and reference are provided for the shale gas development and productivity construction in the block and the development design of similar shale-gas horizontal wells.

Effect of different levels of sugar on qualitative characteristics of lassi prepared from sour dahi

Directory of Open Access Journals (Sweden)

Muhammad Shah Moazzem

2018-08-01

Full Text Available An investigation was carried out to develop lassi from sour dahi using different levels of sugar (10, 15, 20 and 25% and 15% water. Lassi quality was assayed through the study of physical, chemical and microbiological parameters. Results revealed that significant difference existed in overall physical score of lassi samples and the highest score was found in 15% sugar lassi whereas, the lowest score was found in 25% sugar lassi. Total solids, carbohydrate, fat, protein and ash contents differed significantly among various levels of sugar added lassi. From chemical test, it appears that, 15% sugar added lassi possess the highest fat and protein values whereas, the highest total solids and carbohydrate values posses in 25% sugar added lassi. No significant difference (p>0.05 revealed in terms of pH value and acidity percentage among lassi types. Lassi made from 10% sugar was most inferior than other levels of sugar added lassi in respect of microbiological quality- total viable count (×104 cfu/mL content was 95.67±2.08 and coliform (×10 cfu/mL content was 1.00±0.00. Considering above mentioned quality aspects, it might be resolved that lassi could be prepared successfully from sour dahi with 15% sugar keeping water level constant at 15%. [Fundam Appl Agric 2018; 3(2.000: 434-439

Simulation of temperature-pressure profiles and wax deposition in gas-lift wells

Directory of Open Access Journals (Sweden)

Sevic Snezana

2017-01-01

Full Text Available Gas-lift is an artificial lift method in which gas is injected down the tubing- -casing annulus and enters the production tubing through the gas-lift valves to reduce the hydrostatic pressure of the formation fluid column. The gas changes pressure, temperature and fluid composition profiles throughout the production tubing string. Temperature and pressure drop along with the fluid composition changes throughout the tubing string can lead to wax, asphaltenes and inorganic salts deposition, increased emulsion stability and hydrate formation. This paper presents a new model that can sucesfully simulate temperature and pressure profiles and fluid composition changes in oil well that operates by means of gas-lift. This new model includes a pipe-in-pipe segment (production tubing inside production casing, countercurrent flow of gas-lift gas and producing fluid, heat exchange between gas-lift gas and the surrounding ambient – ground; and gas-lift gas with the fluid in the tubing. The model enables a better understanding of the multiphase fluid flow up the production tubing. Model was used to get insight into severity and locations of wax deposition. The obtained information on wax deposition can be used to plan the frequency and depth of wax removing operations. Model was developed using Aspen HYSYS software.

A New Method for Fracturing Wells Reservoir Evaluation in Fractured Gas Reservoir

Directory of Open Access Journals (Sweden)

Jianchun Guo

2014-01-01

Full Text Available Natural fracture is a geological phenomenon widely distributed in tight formation, and fractured gas reservoir stimulation effect mainly depends on the communication of natural fractures. Therefore it is necessary to carry out the evaluation of this reservoir and to find out the optimal natural fractures development wells. By analyzing the interactions and nonlinear relationships of the parameters, it establishes three-level index system of reservoir evaluation and proposes a new method for gas well reservoir evaluation model in fractured gas reservoir on the basis of fuzzy logic theory and multilevel gray correlation. For this method, the Gaussian membership functions to quantify the degree of every factor in the decision-making system and the multilevel gray relation to determine the weight of each parameter on stimulation effect. Finally through fuzzy arithmetic operator between multilevel weights and fuzzy evaluation matrix, score, rank, the reservoir quality, and predicted production will be gotten. Result of this new method shows that the evaluation of the production coincidence rate reaches 80%, which provides a new way for fractured gas reservoir evaluation.

Reasons for the appearance of pulsations in gas-lift wells and methods of eliminating them

Energy Technology Data Exchange (ETDEWEB)

Sibirev, A P; Grekhov, V V; Leonov, V A; Shigapov, R R

1985-01-01

It is shown that the main reason for pulsation in the gas-lift well output is lack of coordinated operation between the bed and the gas-lift lifter. A plan is suggested for making decisions to conduct work to detect and eliminate pulsations in the gas-lift well output which permit elimination of the pulsation in the shortest time and with the least outlays.

Combination gas producing and waste-water disposal well

Science.gov (United States)

Malinchak, Raymond M.

1984-01-01

The present invention is directed to a waste-water disposal system for use in a gas recovery well penetrating a subterranean water-containing and methane gas-bearing coal formation. A cased bore hole penetrates the coal formation and extends downwardly therefrom into a further earth formation which has sufficient permeability to absorb the waste water entering the borehole from the coal formation. Pump means are disposed in the casing below the coal formation for pumping the water through a main conduit towards the water-absorbing earth formation. A barrier or water plug is disposed about the main conduit to prevent water flow through the casing except for through the main conduit. Bypass conduits disposed above the barrier communicate with the main conduit to provide an unpumped flow of water to the water-absorbing earth formation. One-way valves are in the main conduit and in the bypass conduits to provide flow of water therethrough only in the direction towards the water-absorbing earth formation.

Control of waste well casing vent gas from a thermal enhanced oil recovery operation

International Nuclear Information System (INIS)

Peavy, M.A.; Braun, J.E.

1991-01-01

This paper presents an overview of a waste gas treatment system designed to control emissions from thermally enhanced oil recovery wells. This case study discusses the need, design, installation and operations of the system. Oryx Energy Company (Oryx) operates approximately 940 wells in the Midway-Sunset (MWSS) field under casing vapor recovery systems. The emissions collected from well casing vent gas cotaining hydrocarbons and hydrogen sulfide that are collected and processed through casing vapor recovery skids. These skids are composed of condensers, compressors, and pumps that separate fluids from the waste gas stream. The non-condensible gas is then disposed of in incinerators that reduce the hydrocarbon and sulfur emissions into the atmosphere. Approximately 91,000 lbs/day of hydrocarbon and 10,116 lbs/day of sulfur dioxide are removed from the atmosphere from wells contained within these systems operated by Oryx. These hydrocarbons yield approximately 550 barrels of oil per day (BOPD). The system helps manage the pressure differential from the reservoir into each wellbore and contributes to improved ambient air quality in Kern County, California

Producer observations of the long term effects of acid forming emissions in livestock

International Nuclear Information System (INIS)

McGlynn, D.

1992-01-01

A series of interviews with livestock producers is presented to illustrate the environmental problems caused by sour gas plants in the Pincher Creek area of Alberta. Farmers located in the emission plume from the Shell Waterton plant and Gulf sour gas plants were interviewed and provided anecdotal evidence of adverse impacts of sour gas plant emissions on livestock. Common problems that are noticed in livestock include eye irritation, increased respiratory infections, mineral deficiencies, eye cancer, waterhole water quality deterioration, low calf birth weights, decreased cattle weight gain, and birth defects. Crop losses, lowered grass production, machinery corrosion, and water pollution also occur. 1 fig

LOW COST METHODOLOGIES TO ANALYZE AND CORRECT ABNORMAL PRODUCTION DECLINE IN STRIPPER GAS WELLS

International Nuclear Information System (INIS)

Jerry James; Gene Huck; Tim Knobloch

2001-01-01

A study group of 376 Clinton Sand wells in Ohio provided data to determine the historic frequency of the problem of abnormal production declines in stripper gas wells and the causes of the abnormal production decline. Analysis of the historic frequency of the problem indicates over 70% of the wells experienced abnormal production decline. The most frequently occurring causes of abnormal production declines were determined to be fluid accumulation (46%), gas gathering restrictions (24%), and mechanical failures (23%). Data collection forms and decision trees were developed to cost-effectively diagnose the abnormal production declines and suggest corrective action. The decision trees and data collection sheets were incorporated into a procedure guide to provide stripper gas well operators with a methodology to analyze and correct abnormal production declines. The systematic methodologies and techniques developed should increase the efficiency of problem well assessment and implementation of solutions for stripper gas wells. This eight quarterly technical progress report provides a summary of the deliverables completed to date, including the results of the remediations, the procedure guide, and the technology transfer. Due to the successful results of the study to date and the efficiency of the methodology development, two to three additional wells will be selected for remediation for inclusion into the study. The results of the additional remediations will be included in the final report

A Comparison of Thermal Models for Temperature Profiles in Gas-Lift Wells

Directory of Open Access Journals (Sweden)

Langfeng Mu

2018-02-01

Full Text Available Gas lift is a simple, reliable artificial lift method which is frequently used in offshore oil field developments. In order to enhance the efficiency of production by gas lift, it is vital to exactly predict the distribution of temperature-field for fluid within the wellbore. A new mechanistic model is developed for computing flowing fluid temperature profiles in both conduits simultaneously for a continuous-flow gas-lift operation. This model assumes steady heat transfer in the formation, as well as steady heat transfer in the conduits. A micro-units discrete from the wellbore, whose heat transfer process is analyzed and whose heat transfer equation is set up according to the law of conservation of energy. A simplified algebraic solution to our model is conducted to analyze the temperature profile. Sensitivity analysis was conducted with the new model. The results indicate that mass flow rate of oil and the tubing overall heat transfer coefficient are the main factors that influence the temperature distribution inside the tubing and that the mass flow rate of oil is the main factor affecting temperature distribution in the annulus. Finally, the new model was tested in three various wells and compared with other models. The results showed that the new model is more accurate and provides significant references for temperature prediction in gas lift well.

A case study to optimum selection of deliquification method for gas condensate well design: South Pars gas field

Directory of Open Access Journals (Sweden)

Ehsan Khamehchi

2016-06-01

Today, the most effective liquid-removal devices are pumping, the combination of liquid-diverter with gas lift and velocity string. Considering mentioned complexities, the most efficient method of liquid removal is different from one well to the others. This paper discusses a multi-criteria decision making (MCDM strategy for ranking these methods based on ELECTRE and TOPSIS techniques in a gas condensate reservoir. The most efficient model in this case, regarding its high efficiency and level of reliability is continuous gas lift. These procedures can be extended to other cases easily by changing the comparison matrix and user defined weights.

Oil & Natural Gas Technology A new approach to understanding the occurrence and volume of natural gas hydrate in the northern Gulf of Mexico using petroleum industry well logs

Energy Technology Data Exchange (ETDEWEB)

Cook, Ann [The Ohio State Univ., Columbus, OH (United States); Majumdar, Urmi [The Ohio State Univ., Columbus, OH (United States)

2016-03-31

The northern Gulf of Mexico has been the target for the petroleum industry for exploration of conventional energy resource for decades. We have used the rich existing petroleum industry well logs to find the occurrences of natural gas hydrate in the northern Gulf of Mexico. We have identified 798 wells with well log data within the gas hydrate stability zone. Out of those 798 wells, we have found evidence of gas hydrate in well logs in 124 wells (15% of wells). We have built a dataset of gas hydrate providing information such as location, interval of hydrate occurrence (if any) and the overall quality of probable gas hydrate. Our dataset provides a wide, new perspective on the overall distribution of gas hydrate in the northern Gulf of Mexico and will be the key to future gas hydrate research and prospecting in the area.

Design of ultrasonic probe and evaluation of ultrasonic waves on E.coli in Sour Cherry Juice

Directory of Open Access Journals (Sweden)

B Hosseinzadeh Samani

2015-09-01

Full Text Available Introduction: The common method used for juice pasteurization is the thermal method since thermal methods contribute highly to inactivating microbes. However, applying high temperatures would lead to inefficient effects on nutrition and food value. Such effects may include vitamin loss, nutritional flavor loss, non-enzyme browning, and protein reshaping (Kuldiloke, 2002. In order to decrease the adverse effects of the thermal pasteurization method, other methods capable of inactivation of microorganisms can be applied. In doing so, non-thermal methods including pasteurization using high hydrostatic pressure processing (HPP, electrical fields, and ultrasound waves are of interest (Chen and Tseng, 1996. The reason for diminishing microbial count in the presence of ultrasonic waves could be due to the burst of very tiny bubbles developed by ultrasounds which expand quickly and burst in a short time. Due to this burst, special temperature and pressure conditions are developed which could initiate or intensify several physical and/or chemical reactions. The aim of this study is to evaluate the non-thermal ultrasonic method and its effective factors on the E.coli bacteria of sour cherry. Materials and methods: In order to supply uniform ultrasonic waves, a 1000 W electric generator (Model MPI, Switzerland working at 20±1 kHz frequency was used. The aim of this study is to evaluate the non-thermal ultrasonic method and its effective factors on the E.coli bacteria of sour cherry. For this purpose, a certain amount of sour cherry fruit was purchased from local markets. First, the fruits were washed, cleaned and cored. The prepared fruits were then dewatered using an electric juicer. In order to separate pulp suspensions and tissue components, the extracted juice was poured into a centrifuge with the speed of 6000 rpm for 20 min. For complete separation of the remaining suspended particles, the transparent portion of the extract was passed through a

The toxicity of sulfolane and DIPA from sour gas plants to aquatic species

International Nuclear Information System (INIS)

Lintott, D.R.; Goudey, J.S.; Wilson, J.; Swanson, S.; Drury, C.

1997-01-01

The ecological effects of sulfolane and diisopropanolamine (DIPA), which are used to remove sulfur compounds from natural gas, were studied to establish risk-based cleanup criteria and to evaluate effective remedial measures. Toxicity tests were conducted on both the parent compounds and the thermal and biological degradation products. Toxicity testing focused on aquatic species because surface outlets, such as creeks, were found to be the major pathways for the water soluble DIPA and sulfolane chemicals. Sulfolane proved to be relatively non-toxic to aquatic species, with the exception of bacteria. DIPA was relatively toxic to algae at pH found in ground and surface waters. Aqueous and methanol reclaimer bottom extracts from five different gas plant sites were also tested using modified acute toxicity screening tests with different species. The reclaimer bottoms were found to be highly toxic to all species tested. DIPA and sulfolane did not entirely account for the toxicity of the reclaimer bottoms. Inorganic salts and metals present in reclaimer bottoms were found not to contribute to toxicity directly. The same was true for DIPA and sulfolane degradation products. 3 refs., 7 tabs., 8 figs

The toxicity of sulfolane and DIPA from sour gas plants to aquatic species

Energy Technology Data Exchange (ETDEWEB)

Lintott, D.R.; Goudey, J.S. [HydroQual Consultants, Inc., Calgary, AB (Canada); Wilson, J.; Swanson, S. [Golder Associates, Calgary, AB (Canada); Drury, C. [Shell Canada Ltd., Calgary, AB (Canada). Calgary Research Centre

1997-12-31

The ecological effects of sulfolane and diisopropanolamine (DIPA), which are used to remove sulfur compounds from natural gas, were studied to establish risk-based cleanup criteria and to evaluate effective remedial measures. Toxicity tests were conducted on both the parent compounds and the thermal and biological degradation products. Toxicity testing focused on aquatic species because surface outlets, such as creeks, were found to be the major pathways for the water soluble DIPA and sulfolane chemicals. Sulfolane proved to be relatively non-toxic to aquatic species, with the exception of bacteria. DIPA was relatively toxic to algae at pH found in ground and surface waters. Aqueous and methanol reclaimer bottom extracts from five different gas plant sites were also tested using modified acute toxicity screening tests with different species. The reclaimer bottoms were found to be highly toxic to all species tested. DIPA and sulfolane did not entirely account for the toxicity of the reclaimer bottoms. Inorganic salts and metals present in reclaimer bottoms were found not to contribute to toxicity directly. The same was true for DIPA and sulfolane degradation products. 3 refs., 7 tabs., 8 figs.

Shell's Caroline gas project on track in southwest Alberta

International Nuclear Information System (INIS)

Anon.

1992-01-01

This paper reports that western Canada's biggest sour natural gas, sulfur, and natural gas liquids development project in 2 decades is on target to start up late this year. Shell Canada Ltd.'s $950 million (Canadian) Caroline project will produce 2 tcf of gas and associated products from the Swan Hills member of the middle Devonian Beaverhill Lake group. The price tag will reach about $1 billion, including some start-up costs. The project is designed to process an average 300 MMcfd of gas. It will produce 17,500 b/d of pentanes plus, 4,100 metric tons/day of sulfur, 90 MMcfd of sales gas, and 28,000 b/d of NGL-ethane, propane, and butane. A labor force that is peaking at about 2,400 workers is completing a network of processing plants, about 143 miles of pipeline, three field compressors, and other facilities covering an area of 161 sq miles. Dilcon Constructors Ltd., an arm of Delta Catalytic Corp., Calgary, is the main contractor for the project. About 85% of the services and equipment for Caroline are coming from Alberta suppliers, 7% from suppliers elsewhere in Canada, and only 8% from non-Canadian Sources

A Model To Estimate Carbon Dioxide Injectivity and Storage Capacity for Geological Sequestration in Shale Gas Wells.

Science.gov (United States)

Edwards, Ryan W J; Celia, Michael A; Bandilla, Karl W; Doster, Florian; Kanno, Cynthia M

2015-08-04

Recent studies suggest the possibility of CO2 sequestration in depleted shale gas formations, motivated by large storage capacity estimates in these formations. Questions remain regarding the dynamic response and practicality of injection of large amounts of CO2 into shale gas wells. A two-component (CO2 and CH4) model of gas flow in a shale gas formation including adsorption effects provides the basis to investigate the dynamics of CO2 injection. History-matching of gas production data allows for formation parameter estimation. Application to three shale gas-producing regions shows that CO2 can only be injected at low rates into individual wells and that individual well capacity is relatively small, despite significant capacity variation between shale plays. The estimated total capacity of an average Marcellus Shale well in Pennsylvania is 0.5 million metric tonnes (Mt) of CO2, compared with 0.15 Mt in an average Barnett Shale well. Applying the individual well estimates to the total number of existing and permitted planned wells (as of March, 2015) in each play yields a current estimated capacity of 7200-9600 Mt in the Marcellus Shale in Pennsylvania and 2100-3100 Mt in the Barnett Shale.

A Computation Fluid Dynamic Model for Gas Lift Process Simulation in a Vertical Oil Well

Directory of Open Access Journals (Sweden)

Kadivar Arash

2017-03-01

Full Text Available Continuous gas-lift in a typical oil well was simulated using computational fluid dynamic (CFD technique. A multi fluid model based on the momentum transfer between liquid and gas bubbles was employed to simulate two-phase flow in a vertical pipe. The accuracy of the model was investigated through comparison of numerical predictions with experimental data. The model then was used to study the dynamic behaviour of the two-phase flow around injection point in details. The predictions by the model were compared with other empirical correlations, as well. To obtain an optimum condition of gas-lift, the influence of the effective parameters including the quantity of injected gas, tubing diameter and bubble size distribution were investigated. The results revealed that increasing tubing diameter, the injected gas rate and decreasing bubble diameter improve gas-lift performance.

A high-performance hydroxyl-functionalized polymer of intrinsic microporosity for an environmentally attractive membrane-based approach to decontamination of sour natural gas

KAUST Repository

Yi, Shouliang

2015-09-24

Acid gases carbon dioxide (CO2) and hydrogen sulfide (H2S) are important and highly undesirable contaminants in natural gas, and membrane-based removal of these contaminants is environmentally attractive. Although removal of CO2 from natural gas using membranes is well established in industry, there is limited research on H2S removal, mainly due to its toxic nature. In actual field operations, wellhead pressures can exceed 50 bar with H2S concentrations up to 20%. Membrane plasticization and competitive mixed-gas sorption, which can both lead to a loss of separation efficiency, are likely to occur under these aggressive feed conditions, and this is almost always accompanied by a significant decrease in membrane selectivity. In this paper, permeation and separation properties of a hydroxyl-functionalized polymer with intrinsic microporosity (PIM-6FDA-OH) are reported for mixed-gas feeds containing CO2, H2S or the combined pair with CH4. The pure-gas permeation results show no H2S-induced plasticization of the PIM-6FDA-OH film in a pure H2S feed at 35 °C up to 4.5 bar, and revealed only a slight plasticization up to 8 bar of pure H2S. The hydroxyl-functionalized PIM membrane exhibited a significant pure-gas CO2 plasticization resistance up to 28 bar feed pressure. Mixed-gas (15% H2S/15% CO2/70% CH4) permeation results showed that the hydroxyl-functionalized PIM membrane maintained excellent separation performance even under exceedingly challenging feed conditions. The CO2 and H2S permeability isotherms indicated minimal CO2-induced plasticization; however, H2S-induced plasticization effects were evident at the highest mixed gas feed pressure of 48 bar. Under this extremely aggressive mixed gas feed, the binary CO2/CH4 and H2S/CH4 permselectivities, and the combined CO2 and H2S acid gas selectivity were 25, 30 and 55, respectively. Our results indicate that OH-functionalized PIM materials are very promising candidate membrane materials for simultaneous removal of CO2

Summary of tank information relating salt well pumping to flammable gas safety issues

International Nuclear Information System (INIS)

Caley, S.M.; Mahoney, L.A.; Gauglitz, P.A.

1996-09-01

The Hanford Site has 149 single-shell tanks (SSTs) containing radioactive wastes that are complex mixes of radioactive and chemical products. Active use of these SSTs was phased out completely by November 1980, and the first step toward final disposal of the waste in the SSTs is interim stabilization, which involves removing essentially all of the drainable liquid from the tank. Stabilization can be achieved administratively, by jet pumping to remove drainable interstitial liquid, or by supernatant pumping. To date, 116 tanks have been declared interim stabilized; 44 SSTs have had drainable liquid removed by salt well jet pumping. Of the 149 SSTs, 19 are on the Flammable Gas Watch List (FGWL) because the waste in these tanks is known or suspected, in all but one case, to generate and retain mixtures of flammable gases, including; hydrogen, nitrous oxide, and ammonia. Salt well pumping to remove the drainable interstitial liquid from these SSTs is expected to cause the release of much of the retained gas, posing a number of safety concerns. The scope of this work is to collect and summarize information, primarily tank data and observations, that relate salt well pumping to flammable gas safety issues. While the waste within FGWL SSTs is suspected offering flammable gases, the effect of salt well pumping on the waste behavior is not well understood. This study is being conducted for the Westinghouse Hanford Company as part of the Flammable Gas Project at the Pacific Northwest National Laboratory (PNNL). Understanding the historical tank behavior during and following salt well pumping will help to resolve the associated safety issues

Consortium for Petroleum & Natural Gas Stripper Wells PART 2 OF 3

Energy Technology Data Exchange (ETDEWEB)

Morrison, Joel [Pennsylvania State Univ., University Park, PA (United States)

2011-12-01

The United States has more oil and gas wells than any other country. As of December 31, 2004, there were more than half a million producing oil wells in the United States. That is more than three times the combined total for the next three leaders: China, Canada, and Russia. The Stripper Well Consortium (SWC) is a partnership that includes domestic oil and gas producers, service and supply companies, trade associations, academia, the Department of Energy’s Strategic Center for Natural Gas and Oil (SCNGO) at the National Energy Technology Laboratory (NETL), and the New York State Energy Research and Development Authority (NYSERDA). The Consortium was established in 2000. This report serves as a final technical report for the SWC activities conducted over the May 1, 2004 to December 1, 2011 timeframe. During this timeframe, the SWC worked with 173 members in 29 states and three international countries, to focus on the development of new technologies to benefit the U.S. stripper well industry. SWC worked with NETL to develop a nationwide request-for-proposal (RFP) process to solicit proposals from the U.S. stripper well industry to develop and/or deploy new technologies that would assist small producers in improving the production performance of their stripper well operations. SWC conducted eight rounds of funding. A total of 132 proposals were received. The proposals were compiled and distributed to an industrydriven SWC executive council and program sponsors for review. Applicants were required to make a formal technical presentation to the SWC membership, executive council, and program sponsors. After reviewing the proposals and listening to the presentations, the executive council made their funding recommendations to program sponsors. A total of 64 projects were selected for funding, of which 59 were fully completed. Penn State then worked with grant awardees to issue a subcontract for their approved work. SWC organized and hosted a total of 14 meetings

Consortium for Petroleum & Natural Gas Stripper Wells PART 3 OF 3

Energy Technology Data Exchange (ETDEWEB)

Morrison, Joel [Pennsylvania State Univ., University Park, PA (United States)

2011-12-01

The United States has more oil and gas wells than any other country. As of December 31, 2004, there were more than half a million producing oil wells in the United States. That is more than three times the combined total for the next three leaders: China, Canada, and Russia. The Stripper Well Consortium (SWC) is a partnership that includes domestic oil and gas producers, service and supply companies, trade associations, academia, the Department of Energy’s Strategic Center for Natural Gas and Oil (SCNGO) at the National Energy Technology Laboratory (NETL), and the New York State Energy Research and Development Authority (NYSERDA). The Consortium was established in 2000. This report serves as a final technical report for the SWC activities conducted over the May 1, 2004 to December 1, 2011 timeframe. During this timeframe, the SWC worked with 173 members in 29 states and three international countries, to focus on the development of new technologies to benefit the U.S. stripper well industry. SWC worked with NETL to develop a nationwide request-for-proposal (RFP) process to solicit proposals from the U.S. stripper well industry to develop and/or deploy new technologies that would assist small producers in improving the production performance of their stripper well operations. SWC conducted eight rounds of funding. A total of 132 proposals were received. The proposals were compiled and distributed to an industrydriven SWC executive council and program sponsors for review. Applicants were required to make a formal technical presentation to the SWC membership, executive council, and program sponsors. After reviewing the proposals and listening to the presentations, the executive council made their funding recommendations to program sponsors. A total of 64 projects were selected for funding, of which 59 were fully completed. Penn State then worked with grant awardees to issue a subcontract for their approved work. SWC organized and hosted a total of 14 meetings

Fabrication of a gas sensor array with micro-wells for VOCs gas sensing based on polymer/carbon nanotube thin films

Science.gov (United States)

Xie, Guangzhong; Xie, Tao; Zhu, Tao; Jiang, Yadong; Tai, Huiling

2014-08-01

In this paper, gas sensor array with micro-well was designed and prepared by Micro Electro-Mechanical Systems (MEMS) technology. The micro-well and interdigital electrodes of sensor array were prepared using photolithography process, reactive ion etching (RIE) process, wet etching and conventional vacuum evaporation. In the manufacture process of the gas sensor array, KOH wet etching process was mainly discussed. The optimum etching processing parameters were as follows: 30 wt% KOH solution at 80 °C, a cooling back-flow device and a magnetic stirrer. The multi-walled carbon nanotubes (MWCNTs)-polyethyleneoxide (PEO) and MWNTs-Polyvinylpyrrolidone (PVP) composite films were utilized as sensitive layers to test gas-sensing properties. Response performances of MWCNTs- PEO and MWNTs-PVP composite films to toluene vapor and methanol vapor at room temperature were investigated. The results revealed that the sensor array showed a larger sensitivity to toluene vapor than to methanol vapor. In addition, the sensing mechanisms were studied as well.

Brownfield management opportunities to reduce the back pressure effects on the gas wells

Directory of Open Access Journals (Sweden)

Stefanescu Dan-Paul

2017-01-01

Full Text Available Gas mature fields are associated with challenges to optimize the hydrocarbon flow from reservoir to the sales point in a cost effective manner due to declining well productivity. Laslau Mare field is a mature gas field in Transylvanian basin (Mures County developed in 1970s and is producing∼99% methane with low water-gas ratio. As any brown field, the state of depleted reservoir will generate several constraints for gas flow from formation to surface facilities and further to delivery point. During the exploitation has been observed that the operation conditions are facing with unstable pressure in the system due to low demand. Therefore, the back pressure effect will affect the wells in terms of inability to unload the bottomhole accumulated liquids and the reservoir will suffer a higher pressure drawdown. The best fit-for-purpose solution to overcome the above challenges is represented by installation of group compressor. Laslau Mare field has 3 group compressors running and shows positive results, especially when external pressure fluctuates continuously. This paper explain the challenges seen in 2016 in Laslau Mare field with back pressure effects and how the compression overcome them, and also other solutions that should be considered to optimize the well production.

H2-rich and Hydrocarbon Gas Recovered in a Deep Precambrian Well in Northeastern Kansas

International Nuclear Information System (INIS)

Newell, K. David; Doveton, John H.; Merriam, Daniel F.; Lollar, Barbara Sherwood; Waggoner, William M.; Magnuson, L. Michael

2007-01-01

In late 2005 and early 2006, the WTW Operating, LLC (W.T.W. Oil Co., Inc.) no. 1 Wilson well (T.D. = 5772 ft; 1759.3 m) was drilled for 1826 ft (556.6 m) into Precambrian basement underlying the Forest City Basin in northeastern Kansas. Approximately 4500 of the 380,000 wells drilled in Kansas penetrate Precambrian basement. Except for two previous wells drilled into the arkoses and basalts of the 1.1-Ga Midcontinent Rift and another well drilled in 1929 in basement on the Nemaha Uplift east of the Midcontinent Rift, this well represents the deepest penetration into basement rocks in the state to date. Granite is the typical lithology observed in wells that penetrate the Precambrian in the northern Midcontinent. Although no cores were taken to definitively identify lithologies, well cuttings and petrophysical logs indicate that this well encountered basement metamorphic rocks consisting of schist, gneiss, and amphibolitic gneiss, all cut by aplite dikes.The well was cased and perforated in the Precambrian, and then acidized. After several days of swabbing operations, the well produced shows of low-Btu gas, dominated by the non-flammable component gases of nitrogen (20%), carbon dioxide (43%), and helium (1%). Combustible components include methane (26%), hydrogen (10%), and higher molecular-weight hydrocarbons (1%). Although Coveney and others [Am. Assoc. Petroleum Geologists Bull., v. 71, no, 1, p. 39-48, 1987] identified H 2 -rich gas in two wells located close to the Midcontinent Rift in eastern Kansas, this study indicates that high levels of H 2 may be a more widespread phenomenon than previously thought. Unlike previous results, the gases in this study have a significant component of hydrocarbon gas, as well as H 2 , N 2 , and CO 2 . Although redox reactions between iron-bearing minerals and groundwater are a possible source of H 2 in the Precambrian basement rocks, the hydrocarbon gas does not exhibit the characteristics typically associated with proposed

Fast Lemons and Sour Boulders: Testing Crossmodal Correspondences Using an Internet-Based Testing Methodology

Directory of Open Access Journals (Sweden)

Andy T. Woods

2013-09-01

Full Text Available According to a popular family of hypotheses, crossmodal matches between distinct features hold because they correspond to the same polarity on several conceptual dimensions (such as active–passive, good–bad, etc. that can be identified using the semantic differential technique. The main problem here resides in turning this hypothesis into testable empirical predictions. In the present study, we outline a series of plausible consequences of the hypothesis and test a variety of well-established and previously untested crossmodal correspondences by means of a novel internet-based testing methodology. The results highlight that the semantic hypothesis cannot easily explain differences in the prevalence of crossmodal associations built on the same semantic pattern (fast lemons, slow prunes, sour boulders, heavy red; furthermore, the semantic hypothesis only minimally predicts what happens when the semantic dimensions and polarities that are supposed to drive such crossmodal associations are made more salient (e.g., by adding emotional cues that ought to make the good/bad dimension more salient; finally, the semantic hypothesis does not explain why reliable matches are no longer observed once intramodal dimensions with congruent connotations are presented (e.g., visually presented shapes and colour do not appear to correspond.

Staged fracturing of horizontal shale gas wells with temporary plugging by sand filling

Directory of Open Access Journals (Sweden)

Xing Liang

2017-03-01

Full Text Available Due to downhole complexities, shale-gas horizontal well fracturing in the Sichuan Basin suffered from casing deformation and failure to apply the technique of cable-conveyed perforation bridge plug. In view of these problems, a new technique of staged volume fracturing with temporary plugging by sand filling is employed. Based on theoretical analyses and field tests, a design of optimized parameters of coiled tubing-conveyed multi-cluster sand-blasting perforation and temporary plugging by sand filling was proposed. It was applied in the horizontal Well ZJ-1 in which casing deformation occurred. The following results are achieved in field operations. First, this technique enables selective staged fracturing in horizontal sections. Second, this technique can realize massive staged fracturing credibly without mechanical plugging, with the operating efficiency equivalent to the conventional bridge plug staged fracturing. Third, full-hole is preserved after fracturing, thus it is possible to directly conduct an open flow test without time consumption of a wiper trip. The staged volume fracturing with temporary plugging by sand filling facilitated the 14-stage fracturing in Well ZJ-1, with similar SRV to that achieved by conventional bridge plug staged fracturing and higher gas yield than neighboring wells on the same well pad. Thus, a new and effective technique is presented in multi-cluster staged volume fracturing of shale gas horizontal wells.

Biogeochemical interactions between of coal mine water and gas well cement

Science.gov (United States)

Gulliver, D. M.; Gardiner, J. B.; Kutchko, B. G.; Hakala, A.; Spaulding, R.; Tkach, M. K.; Ross, D.

2017-12-01

Unconventional natural gas wells drilled in Northern Appalachia often pass through abandoned coal mines before reaching the Marcellus or Utica formations. Biogeochemical interactions between coal mine waters and gas well cements have the potential to alter the cement and compromise its sealing integrity. This study investigates the mineralogical, geochemical, and microbial changes of cement cores exposed to natural coal mine waters. Static reactors with Class H Portland cement cores and water samples from an abandoned bituminous Pittsburgh coal mine simulated the cement-fluid interactions at relevant temperature for time periods of 1, 2, 4, and 6 weeks. Fluids were analyzed for cation and anion concentrations and extracted DNA was analyzed by 16S rRNA gene sequencing and shotgun sequencing. Cement core material was evaluated via scanning electron microscope. Results suggest that the sampled coal mine water altered the permeability and matrix mineralogy of the cement cores. Scanning electron microscope images display an increase in mineral precipitates inside the cement matrix over the course of the experiment. Chemistry results from the reaction vessels' effluent waters display decreases in dissolved calcium, iron, silica, chloride, and sulfate. The microbial community decreased in diversity over the 6-week experiment, with Hydrogenophaga emerging as dominant. These results provide insight in the complex microbial-fluid-mineral interactions of these environments. This study begins to characterize the rarely documented biogeochemical impacts that coal waters may have on unconventional gas well integrity.

The unique field experiments on the assessment of accident consequences at industrial enterprises of gas-chemical complexes

International Nuclear Information System (INIS)

Belov, N.S.; Trebin, I.S.; Sorokovikova, O.

1998-01-01

Sour natural gas fields are the unique raw material base for setting up such large enterprises as gas chemical complexes. The presence of high toxic H 2 S in natural gas results in widening a range of dangerous and harmful factors for biosphere. Emission of such gases into atmosphere during accidents at gas wells and gas pipelines is of especial danger for environment and first of all for people. Development of mathematical forecast models for assessment of accidents progression and consequences is one of the main elements of works on safety analysis and risk assessment. The critical step in development of such models is their validation using the experimental material. Full-scale experiments have been conducted by the All-Union Scientific-Research institute of Natural Gases and Gas Technology (VNIIGAZ) for grounding of sizes of hazard zones in case of the severe accidents with the gas pipelines. The source of emergency gas release was the working gas pipelines with 100 mm dia. And 110 km length. This pipeline was used for transportation of natural gas with significant amount of hydrogen sulphide. During these experiments significant quantities of the gas including H 2 S were released into the atmosphere and then concentrations of gas and H 2 S were measured in the accident region. The results of these experiments are used for validation of atmospheric dispersion models including the new Lagrangian trace stochastic model that takes into account a wide range of meteorological factors. This model was developed as a part of computer system for decision-making support in case of accident release of toxic gases into atmosphere at the enterprises of Russian gas industry. (authors)

Volatile organic compound emissions from the oil and natural gas industry in the Uintah Basin, Utah: oil and gas well pad emissions compared to ambient air composition

Science.gov (United States)

Warneke, C.; Geiger, F.; Edwards, P. M.; Dube, W.; Pétron, G.; Kofler, J.; Zahn, A.; Brown, S. S.; Graus, M.; Gilman, J. B.; Lerner, B. M.; Peischl, J.; Ryerson, T. B.; de Gouw, J. A.; Roberts, J. M.

2014-10-01

Emissions of volatile organic compounds (VOCs) associated with oil and natural gas production in the Uintah Basin, Utah were measured at a ground site in Horse Pool and from a NOAA mobile laboratory with PTR-MS instruments. The VOC compositions in the vicinity of individual gas and oil wells and other point sources such as evaporation ponds, compressor stations and injection wells are compared to the measurements at Horse Pool. High mixing ratios of aromatics, alkanes, cycloalkanes and methanol were observed for extended periods of time and for short-term spikes caused by local point sources. The mixing ratios during the time the mobile laboratory spent on the well pads were averaged. High mixing ratios were found close to all point sources, but gas well pads with collection and dehydration on the well pad were clearly associated with higher mixing ratios than other wells. The comparison of the VOC composition of the emissions from the oil and natural gas well pads showed that gas well pads without dehydration on the well pad compared well with the majority of the data at Horse Pool, and that oil well pads compared well with the rest of the ground site data. Oil well pads on average emit heavier compounds than gas well pads. The mobile laboratory measurements confirm the results from an emissions inventory: the main VOC source categories from individual point sources are dehydrators, oil and condensate tank flashing and pneumatic devices and pumps. Raw natural gas is emitted from the pneumatic devices and pumps and heavier VOC mixes from the tank flashings.

Understanding gas production mechanism and effectiveness of well stimulation in the Haynesville shale through reservoir simulation

Energy Technology Data Exchange (ETDEWEB)

Fan, L.; Thompson, J.W.; Robinson, J.R. [Schlumberger, Houston, TX (United States)

2010-07-01

The Haynesville Shale Basin is one of the large and most active shale gas plays in the United States, with 185 horizontal rigs currently in place. The Haynesville Shale is a very tight source rock and resource play. The gas resources are being converted into gas reserves with horizontal wells and hydraulic fracture treatments. A complex fracture network created during well stimulation is the main factor in generating superior early well performance in the area. The key to making better wells in all the gas shale plays is to understand how to create more surface area during hydraulic stimulation jobs and preserve the surface area for as long as possible. This paper presented a unique workflow and methodology that has enabled analysis of production data using reservoir simulation to explain the shale gas production mechanism and the effectiveness of stimulation treatments along laterals. Since 2008, this methodology has been used to analyze production data from more than 30 horizontal wells in the Haynesville Shale. Factors and parameters relating to short and long term well performance were investigated, including pore pressure, rock matrix quality, natural fractures, hydraulic fractures, and complex fracture networks. Operators can use the simulation results to determine where and how to spend resources to produce better wells and to reduce the uncertainties of developing these properties. 19 refs., 1 tab., 17 figs.

Field data provide estimates of effective permeability, fracture spacing, well drainage area and incremental production in gas shales

KAUST Repository

Eftekhari, Behzad

2018-05-23

About half of US natural gas comes from gas shales. It is valuable to study field production well by well. We present a field data-driven solution for long-term shale gas production from a horizontal, hydrofractured well far from other wells and reservoir boundaries. Our approach is a hybrid between an unstructured big-data approach and physics-based models. We extend a previous two-parameter scaling theory of shale gas production by adding a third parameter that incorporates gas inflow from the external unstimulated reservoir. This allows us to estimate for the first time the effective permeability of the unstimulated shale and the spacing of fractures in the stimulated region. From an analysis of wells in the Barnett shale, we find that on average stimulation fractures are spaced every 20 m, and the effective permeability of the unstimulated region is 100 nanodarcy. We estimate that over 30 years on production the Barnett wells will produce on average about 20% more gas because of inflow from the outside of the stimulated volume. There is a clear tradeoff between production rate and ultimate recovery in shale gas development. In particular, our work has strong implications for well spacing in infill drilling programs.

Proximity to natural gas wells and reported health status: results of a household survey in Washington County, Pennsylvania.

Science.gov (United States)

Rabinowitz, Peter M; Slizovskiy, Ilya B; Lamers, Vanessa; Trufan, Sally J; Holford, Theodore R; Dziura, James D; Peduzzi, Peter N; Kane, Michael J; Reif, John S; Weiss, Theresa R; Stowe, Meredith H

2015-01-01

Little is known about the environmental and public health impact of unconventional natural gas extraction activities, including hydraulic fracturing, that occur near residential areas. Our aim was to assess the relationship between household proximity to natural gas wells and reported health symptoms. We conducted a hypothesis-generating health symptom survey of 492 persons in 180 randomly selected households with ground-fed wells in an area of active natural gas drilling. Gas well proximity for each household was compared with the prevalence and frequency of reported dermal, respiratory, gastrointestinal, cardiovascular, and neurological symptoms. The number of reported health symptoms per person was higher among residents living 2 km from the nearest gas well (mean ± SD, 1.60 ± 2.14; p = 0.0002). In a model that adjusted for age, sex, household education, smoking, awareness of environmental risk, work type, and animals in house, reported skin conditions were more common in households 2 km from the nearest gas well (odds ratio = 4.1; 95% CI: 1.4, 12.3; p = 0.01). Upper respiratory symptoms were also more frequently reported in persons living in households gas wells (39%) compared with households 1-2 km or > 2 km from the nearest well (31 and 18%, respectively) (p = 0.004). No equivalent correlation was found between well proximity and other reported groups of respiratory, neurological, cardiovascular, or gastrointestinal conditions. Although these results should be viewed as hypothesis generating, and the population studied was limited to households with a ground-fed water supply, proximity of natural gas wells may be associated with the prevalence of health symptoms including dermal and respiratory conditions in residents living near natural gas extraction activities. Further study of these associations, including the role of specific air and water exposures, is warranted.

Microbial Life in an Underground Gas Storage Reservoir

Science.gov (United States)

Bombach, Petra; van Almsick, Tobias; Richnow, Hans H.; Zenner, Matthias; Krüger, Martin

2015-04-01

While underground gas storage is technically well established for decades, the presence and activity of microorganisms in underground gas reservoirs have still hardly been explored today. Microbial life in underground gas reservoirs is controlled by moderate to high temperatures, elevated pressures, the availability of essential inorganic nutrients, and the availability of appropriate chemical energy sources. Microbial activity may affect the geochemical conditions and the gas composition in an underground reservoir by selective removal of anorganic and organic components from the stored gas and the formation water as well as by generation of metabolic products. From an economic point of view, microbial activities can lead to a loss of stored gas accompanied by a pressure decline in the reservoir, damage of technical equipment by biocorrosion, clogging processes through precipitates and biomass accumulation, and reservoir souring due to a deterioration of the gas quality. We present here results from molecular and cultivation-based methods to characterize microbial communities inhabiting a porous rock gas storage reservoir located in Southern Germany. Four reservoir water samples were obtained from three different geological horizons characterized by an ambient reservoir temperature of about 45 °C and an ambient reservoir pressure of about 92 bar at the time of sampling. A complementary water sample was taken at a water production well completed in a respective horizon but located outside the gas storage reservoir. Microbial community analysis by Illumina Sequencing of bacterial and archaeal 16S rRNA genes indicated the presence of phylogenetically diverse microbial communities of high compositional heterogeneity. In three out of four samples originating from the reservoir, the majority of bacterial sequences affiliated with members of the genera Eubacterium, Acetobacterium and Sporobacterium within Clostridiales, known for their fermenting capabilities. In

Vertical seismic profile data from well Mallik 2L-38 for gas hydrate studies

Energy Technology Data Exchange (ETDEWEB)

Mi, Y [Calgary Univ., AB (Canada); Walia, R [Victoria Univ., BC (Canada); Hyndman, R D; Sakai, A

1999-01-01

A gas hydrate research well was drilled in the Canadian Arctic to determine gas hydrates in a permafrost setting in a collaborative research project between the Japan National Oil Corp., and the Geological Survey of Canada with the participation of other agencies. The multidisciplinary study included an electromagnetic survey, permafrost and gas hydrate coring, and comprehensive downhole geophysical logging and measurement. Laboratory studies on recovered cores and cuttings included sedimentology, physical properties, geochemistry, and reservoir characteristics of the Mallik gas accumulation. As part of the field program, a vertical seismic profiling survey was conducted at zero and offset source positions with 3 component receiver tools and horizontal and vertical vibration sources. A special effort was made to record shear wave data, and results from this work were combined with down hole logs and regional surface seismic data. The data will be used also to determine the effect of gas hydrates on formation velocities and to measure gas hydrate concentrations as a function of depth in the formation penetrated by the well. Certain conclusions followed from the initial VSP analysis. 1) Zero offset vertical vibration Z component and horizontal X component data give reliable velocity estimation within the gas hydrate formation zone, and P wave velocities from offset data indicate excellent consistency with that from zero offset data and with the sonic log. 2) The VSP data permitted reliable identification of gas hydrate bearing zones. 4 refs.

Piston-like plugging of fuzzy-ball workover fluids for controlling and killing lost circulation of gas wells

Directory of Open Access Journals (Sweden)

Jinfeng Wang

2016-01-01

Full Text Available During well-killing operations for the workover of low-pressure gas wells, formation pressure should be balanced so as to guarantee well control safety by preventing natural gas overflow. In this paper, a laboratory evaluation was conducted with fuzzy-ball fluids as killing fluids. The results show that, the fuzzy-ball fluid, with a density of 0.5–1.5 g/cm3 and a viscosity up to 78,50,000 mPa·s at a low shear rate, realizes controllable performance and forms piston-like plugging slugs of solid-free high structural strength on natural gas wellbore after bonding. During well workover, multiple fluid column pressures were set up by injecting fuzzy-ball fluids with different densities at various rates. Owing to high structural strength of the fluids at a low shear rate, natural gas breaks through only inside the piston-like slug and cannot flow upwards to the ground, so the pathways of natural gas in the wellbore are isolated from the ground surface. Moreover, the fluid can wholly move up and down like a piston-like plug, with the change of formation pressures or the tripping of pipe strings. Like the conventional operations, the production can be restored after the workover, so long as the fluid in wellbore is cleaned by means of gas lift. In a natural gas field in NW China, where the formation pressure coefficient dropped to 0.60–0.82, three wells were fully filled with fuzzy-ball workover fluids for 7 days and another three wells were treated with the piston-like plugs of fuzzy-ball workover fluids for only 3 days. They all presented better technical results. The technology provides a new way for low-pressure gas well workover.

Field investigation finding of long term effects in Alberta livestock exposed to acid forming emissions: Survey following the Lodgepole blowout

International Nuclear Information System (INIS)

Harris, B.

1992-01-01

The effects of the Amoco Dome Brazeau River (Lodgepole) sour gas well blowout of October 1982 on livestock are reviewed. For 26 days the well was not on fire, with condensate falling on the area immediately surrounding the well site, while during the 41 days the well was burning, sour gas and condensate underwent combustion in the intense fire. Many local residents noted problems with their farm animals during the blowout period. A study was undertaken to evaluate opinions and attitudes of livestock producers about the long-term effects of the Lodgepole blowout. Contact was made with producers in the area of concern, and a worksheet was developed to aid in the collection of data. Information gathered was based on producer records, auction sale tickets, sales receipts and memory. Twenty livestock producers were interviewed, representing 1,700 head of beef cows, 40 dairy cows and 21 sows. Concerns expressed by producers included birth weight, birth defects or stillbirth, scours and problem calves, poor growth, open or dry cows, abortions, late calves, poor growth in replacement heifers, abnormal hair, and abnormal breeding. 1 tab

Antifungal modes of action of Saccharomyces and other biocontrol yeasts against fungi isolated from sour and grey rots.

Science.gov (United States)

Nally, M C; Pesce, V M; Maturano, Y P; Rodriguez Assaf, L A; Toro, M E; Castellanos de Figueroa, L I; Vazquez, F

2015-07-02

The aim of this study was to determine the putative modes of action of 59 viticultural yeasts (31 Saccharomyces and 28 non-Saccharomyces) that inhibited fungi isolated from sour and grey rot in grapes. Inhibition of fungal mycelial growth by metabolites, enzyme activities (laminarinases, chitinases), antifungal volatiles, competition for nutrients (siderophores, Niche Overlap Index (NOI)), inhibition of fungal spore germination and decreased germinal tube length and induction of resistance were assayed. Biofungicide yeasts were classified into "antifungal patterns", according to their mechanisms of action. Thirty isolates presented at least two of the mechanisms assayed. We propose that inhibition of fungal mycelial growth by metabolites, laminarinases, competition for nutrients, inhibition of fungal spore germination and decreased germinal tube length, and antifungal volatiles by Saccharomyces and non-Saccharomyces viticultural yeasts is used as putative biocontrol mechanisms against phytopathogenic fungi. Twenty-four different antifungal patterns were identified. Siderophore production (N)and a combination of siderophore production and NOI>0.92 (M)were the most frequent antifungal patterns observed in the biofungicide yeasts assayed. Elucidation of these mechanisms could be useful for optimization of an inoculum formulation, resulting in a more consistent control of grey and sour rot with Saccharomyces and non-Saccharomyces biocontrol yeasts. Copyright © 2015 Elsevier B.V. All rights reserved.

EUB Decision 2007-061 : West Energy Ltd., applications for well licences, Pembina Field

Energy Technology Data Exchange (ETDEWEB)

NONE

2007-08-08

West Energy Ltd. applied to the Alberta Energy and Utilities Board for licences to drill two level-2 sour crude oil wells to obtain crude oil from the Nisku Formation, about 3 km east of the Hamlet of Rocky Rapids, Alberta. Both wells are expected to contain 160 moles per kilomole hydrogen sulfide (H{sub 2}S). The expected cumulative H{sub 2}S release rate for the drilling and completion phases of the wells is 2.5 m{sup 3}/s, while for suspended and producing phases it is 0.44 m{sup 3}/s. Objections were received from 124 intervening parties who expressed concerns regarding health and safety, flaring, air quality, proliferation, emergency response planning, contamination of land and animals, and compensation. A public hearing was held in March 2007 to hear the views of the Board, the interested parties and the interveners. The Board considered various issues, including communication and participant involvement; need and timing of the wells; location of the wells; safety; human and livestock health; property values; and, environmental impacts. Having reviewed the evidence, the Board granted conditional approval for West Energy Ltd. to drill 2 sour crude oil wells near Rocky Rapids. The EUB imposed 10 conditions on West Energy Ltd. that will address public concerns raised during the 11-day hearing. With the conditions, the Board considers these wells to represent a low level of risk when failure probability, mitigating measures and enhanced emergency response plans are taken into account. 2 tabs., 1 fig., 4 appendices.

EUB Decision 2007-061 : West Energy Ltd., applications for well licences, Pembina Field

International Nuclear Information System (INIS)

2007-01-01

West Energy Ltd. applied to the Alberta Energy and Utilities Board for licences to drill two level-2 sour crude oil wells to obtain crude oil from the Nisku Formation, about 3 km east of the Hamlet of Rocky Rapids, Alberta. Both wells are expected to contain 160 moles per kilomole hydrogen sulfide (H 2 S). The expected cumulative H 2 S release rate for the drilling and completion phases of the wells is 2.5 m 3 /s, while for suspended and producing phases it is 0.44 m 3 /s. Objections were received from 124 intervening parties who expressed concerns regarding health and safety, flaring, air quality, proliferation, emergency response planning, contamination of land and animals, and compensation. A public hearing was held in March 2007 to hear the views of the Board, the interested parties and the interveners. The Board considered various issues, including communication and participant involvement; need and timing of the wells; location of the wells; safety; human and livestock health; property values; and, environmental impacts. Having reviewed the evidence, the Board granted conditional approval for West Energy Ltd. to drill 2 sour crude oil wells near Rocky Rapids. The EUB imposed 10 conditions on West Energy Ltd. that will address public concerns raised during the 11-day hearing. With the conditions, the Board considers these wells to represent a low level of risk when failure probability, mitigating measures and enhanced emergency response plans are taken into account. 2 tabs., 1 fig., 4 appendices

Shallow Gas Migration along Hydrocarbon Wells-An Unconsidered, Anthropogenic Source of Biogenic Methane in the North Sea.

Science.gov (United States)

Vielstädte, Lisa; Haeckel, Matthias; Karstens, Jens; Linke, Peter; Schmidt, Mark; Steinle, Lea; Wallmann, Klaus

2017-09-05

Shallow gas migration along hydrocarbon wells constitutes a potential methane emission pathway that currently is not recognized in any regulatory framework or greenhouse gas inventory. Recently, the first methane emission measurements at three abandoned offshore wells in the Central North Sea (CNS) were conducted showing that considerable amounts of biogenic methane originating from shallow gas accumulations in the overburden of deep reservoirs were released by the boreholes. Here, we identify numerous wells poking through shallow gas pockets in 3-D seismic data of the CNS indicating that about one-third of the wells may leak, potentially releasing a total of 3-17 kt of methane per year into the North Sea. This poses a significant contribution to the North Sea methane budget. A large fraction of this gas (∼42%) may reach the atmosphere via direct bubble transport (0-2 kt yr -1 ) and via diffusive exchange of methane dissolving in the surface mixed layer (1-5 kt yr -1 ), as indicated by numerical modeling. In the North Sea and in other hydrocarbon-prolific provinces of the world shallow gas pockets are frequently observed in the sedimentary overburden and aggregate leakages along the numerous wells drilled in those areas may be significant.

Development of a Non-Intrusive Diagnosis Technique for Gas Lifted Oil Wells

International Nuclear Information System (INIS)

Abidi, Tawfik; Guellouz, Mohamed Sadok; Harbaoui, Mohamed; Ellejmi, Mohamed

2009-01-01

In the present study a numerical model, representative of a real gas-lifted oil well, is used to perform flow simulations under different states of the oil reservoir. The simulations results helped to establish correlations between the well state and the measurable parameters at the well head. The uniqueness of these correlations, allows the reliable diagnosis of the state of the well by inferring the anomalies affecting it based on easily measurable parameters with no need to stop the oil production

A Theoretical Investigation of Radial Lateral Wells with Shockwave Completion in Shale Gas Reservoirs

Science.gov (United States)

Shan, Jia

As its role in satisfying the energy demand of the U.S. and as a clean fuel has become more significant than ever, the shale gas production in the U.S. has gained increasing momentum over recent years. Thus, effective and environmentally friendly methods to extract shale gas are critical. Hydraulic fracturing has been proven to be efficient in the production of shale gas. However, environmental issues such as underground water contamination and high usage of water make this technology controversial. A potential technology to eliminate the environmental issues concerning water usage and contamination is to use blast fracturing, which uses explosives to create fractures. It can be further aided by HEGF and multi-pulse pressure loading technology, which causes less crushing effect near the wellbore and induces longer fractures. Radial drilling is another relatively new technology that can bypass damage zones due to drilling and create a larger drainage area through drilling horizontal wellbores. Blast fracturing and radial drilling both have the advantage of cost saving. The successful combination of blast fracturing and radial drilling has a great potential for improving U.S. shale gas production. An analytical productivity model was built in this study, considering linear flow from the reservoir rock to the fracture face, to analyze factors affecting shale gas production from radial lateral wells with shockwave completion. Based on the model analyses, the number of fractures per lateral is concluded to be the most effective factor controlling the productivity index of blast-fractured radial lateral wells. This model can be used for feasibility studies of replacing hydraulic fracturing by blast fracturing in shale gas well completions. Prediction of fracture geometry is recommended for future studies.

Well-Being Analysis of Power Systems Considering Increasing Deployment of Gas Turbines

Directory of Open Access Journals (Sweden)

Bomiao Liang

2017-07-01

Full Text Available With the significant decrease in natural gas prices in many parts of the world, the employment of gas turbine (GT units has increased steadily in recent years. The ever-increasing deployment of GT units is strengthening the interconnections between electric power and natural gas systems, which could provide a higher level of operational flexibility and reliability. As a result, the planning and operation issues in the interconnected electric power and natural gas systems have aroused concern. In these circumstances, the impacts of increasing deployment of GT units in power system operation are studied and evaluated through well-being analysis (WBA. The fast responsive characteristics of GT units are analyzed first, and the definition and adaption of WBA in a power system with increasing deployment of GT units are addressed. Then the equivalent reserve capacity of GT units is estimated, taking demand fluctuations, commitment plans, and operational risks of GT units into account. The WBA of a power system with increasing deployment of GT units is conducted considering the uncertainties of system operation states and renewable energy sources. Finally, the proposed methods are validated through an integrated version of the IEEE 118-bus power system and a 10-bus natural gas system, and the impacts of GT units on power system security under various penetration levels are examined. Simulation results demonstrate that the role of a GT unit as a low-cost electricity producer may conflict with its role as a reserve provider, but through maintaining a proper proportion of idle GT capacities for reserve, the well-being performance of the power system concerned can be significantly improved.

Mount Elbert Gas Hydrate Stratigraphic Test Well, Alaska North Slope: Overview of scientific and technical program

Science.gov (United States)

Hunter, R.B.; Collett, T.S.; Boswell, R.; Anderson, B.J.; Digert, S.A.; Pospisil, G.; Baker, R.; Weeks, M.

2011-01-01

The Mount Elbert Gas Hydrate Stratigraphic Test Well was drilled within the Alaska North Slope (ANS) Milne Point Unit (MPU) from February 3 to 19, 2007. The well was conducted as part of a Cooperative Research Agreement (CRA) project co-sponsored since 2001 by BP Exploration (Alaska), Inc. (BPXA) and the U.S. Department of Energy (DOE) in collaboration with the U.S. Geological Survey (USGS) to help determine whether ANS gas hydrate can become a technically and commercially viable gas resource. Early in the effort, regional reservoir characterization and reservoir simulation modeling studies indicated that up to 0.34 trillion cubic meters (tcm; 12 trillion cubic feet, tcf) gas may be technically recoverable from 0.92 tcm (33 tcf) gas-in-place within the Eileen gas hydrate accumulation near industry infrastructure within ANS MPU, Prudhoe Bay Unit (PBU), and Kuparuk River Unit (KRU) areas. To further constrain these estimates and to enable the selection of a test site for further data acquisition, the USGS reprocessed and interpreted MPU 3D seismic data provided by BPXA to delineate 14 prospects containing significant highly-saturated gas hydrate-bearing sand reservoirs. The "Mount Elbert" site was selected to drill a stratigraphic test well to acquire a full suite of wireline log, core, and formation pressure test data. Drilling results and data interpretation confirmed pre-drill predictions and thus increased confidence in both the prospect interpretation methods and in the wider ANS gas hydrate resource estimates. The interpreted data from the Mount Elbert well provide insight into and reduce uncertainty of key gas hydrate-bearing reservoir properties, enable further refinement and validation of the numerical simulation of the production potential of both MPU and broader ANS gas hydrate resources, and help determine viability of potential field sites for future extended term production testing. Drilling and data acquisition operations demonstrated that gas hydrate

Quantum particle-number fluctuations in a two-component Bose gas in a double-well potential

International Nuclear Information System (INIS)

Zin, Pawel; Oles, Bartlomiej; Sacha, Krzysztof

2011-01-01

A two-component Bose gas in a double-well potential with repulsive interactions may undergo a phase separation transition if the interspecies interactions outweigh the intraspecies ones. We analyze the transition in the strong interaction limit within the two-mode approximation. Numbers of particles in each potential well are equal and constant. However, at the transition point, the ground state of the system reveals huge fluctuations of numbers of particles belonging to the different gas components; that is, the probability for observation of any mixture of particles in each potential well becomes uniform.

Drilling of gas and condensed gas wells

Energy Technology Data Exchange (ETDEWEB)

Geranin, M P; Chao, P L; Lomonosov, V V

1981-01-01

Cementing of boreholes drilled into underground gas fields and the requirements imposed on the grouting mortar are reviewed. Results are set forth from a study of the insulation capacity of cementing mortar used to increase the quality of reinforcements of boreholes at PKhG. Data are presented on the properties of different grouting mortars for boreholes at PKhG, including those that may be used at low temperatures. Information is also provided on the use of light mortar containing a CaCl/sub 2/ additive, grouting mortar with furfuryl alcohol added, and expanding grouting mortars.

Behavior and dynamics of bubble breakup in gas pipeline leaks and accidental subsea oil well blowouts.

Science.gov (United States)

Wang, Binbin; Socolofsky, Scott A; Lai, Chris C K; Adams, E Eric; Boufadel, Michel C

2018-06-01

Subsea oil well blowouts and pipeline leaks release oil and gas to the environment through vigorous jets. Predicting the breakup of the released fluids in oil droplets and gas bubbles is critical to predict the fate of petroleum compounds in the marine water column. To predict the gas bubble size in oil well blowouts and pipeline leaks, we observed and quantified the flow behavior and breakup process of gas for a wide range of orifice diameters and flow rates. Flow behavior at the orifice transitions from pulsing flow to continuous discharge as the jet crosses the sonic point. Breakup dynamics transition from laminar to turbulent at a critical value of the Weber number. Very strong pure gas jets and most gas/liquid co-flowing jets exhibit atomization breakup. Bubble sizes in the atomization regime scale with the jet-to-plume transition length scale and follow -3/5 power-law scaling for a mixture Weber number. Copyright © 2018 Elsevier Ltd. All rights reserved.

In situ thermal conductivity of gas-hydrate-bearing sediments of the Mallik 5L-38 well

Science.gov (United States)

Henninges, J.; Huenges, E.; Burkhardt, H.

2005-11-01

Detailed knowledge about thermal properties of rocks containing gas hydrate is required in order to quantify processes involving gas hydrate formation and decomposition in nature. In the framework of the Mallik 2002 program, three wells penetrating a continental gas hydrate occurrence under permafrost were successfully equipped with permanent fiber-optic distributed temperature sensing cables. Temperature data were collected over a 21-month period after completing the wells. Thermal conductivity profiles were calculated from the geothermal data as well as from a petrophysical model derived from the available logging data and application of mixing law models. Results indicate that thermal conductivity variations are mainly lithologically controlled with a minor influence from hydrate saturation. Average thermal conductivity values of the hydrate-bearing sediments range between 2.35 and 2.77 W m-1 K-1. Maximum gas hydrate saturations can reach up to about 90% at an average porosity of 0.3.

Effects of shallow natural gas well structures and associated roads on grassland songbird reproductive success in Alberta, Canada.

Directory of Open Access Journals (Sweden)

Jenny Yoo

Full Text Available Grassland songbird populations across North America have experienced dramatic population declines due to habitat loss and degradation. In Canada, energy development continues to fragment and disturb prairie habitat, but effects of oil and gas development on reproductive success of songbirds in North American mixed-grass prairies remains largely unknown. From 2010-2012, in southeastern Alberta, Canada, we monitored 257 nests of two ground-nesting grassland songbird species, Savannah sparrow (Passerculus sandwichensis and chestnut-collared longspur (Calcarius ornatus. Nest locations varied with proximity to and density of conventional shallow gas well structures and associated roads in forty-two 258-ha mixed-grass prairie sites. We estimated the probabilities of nest success and clutch size relative to gas well structures and roads. There was little effect of distance to or density of gas well structure on nest success; however, Savannah sparrow experienced lower nest success near roads. Clutch sizes were lower near gas well structures and cattle water sources. Minimizing habitat disturbance surrounding gas well structures, and reducing abundance of roads and trails, would help minimize impacts on reproductive success for some grassland songbirds.

Digital representation of oil and natural gas well pad scars in southwest Wyoming: 2012 update

Science.gov (United States)

Garman, Steven L.; McBeth, Jamie L.

2015-01-01

The recent proliferation of oil and natural gas energy development in the Greater Green River Basin of southwest Wyoming has accentuated the need to understand wildlife responses to this development. The location and extent of surface disturbance that is created by oil and natural gas well pad scars are key pieces of information used to assess the effects of energy infrastructure on wildlife populations and habitat. A digital database of oil and natural gas pad scars had previously been generated from 1-meter (m) National Agriculture Imagery Program imagery (NAIP) acquired in 2009 for a 7.7-million hectare (ha) (19,026,700 acres) region of southwest Wyoming. Scars included the pad area where wellheads, pumps, and storage facilities reside and the surrounding area that was scraped and denuded of vegetation during the establishment of the pad. Scars containing tanks, compressors, the storage of oil and gas related equipment, and produced-water ponds were also collected on occasion. This report updates the digital database for the five counties of southwest Wyoming (Carbon, Lincoln, Sublette, Sweetwater, Uinta) within the Wyoming Landscape Conservation Initiative (WLCI) study area and for a limited portion of Fremont, Natrona, and Albany Counties using 2012 1-m NAIP imagery and 2012 oil and natural gas well permit information. This report adds pad scars created since 2009, and updates attributes of all pad scars using the 2012 well permit information. These attributes include the origination year of the pad scar, the number of active and inactive wells on or near each pad scar in 2012, and the overall status of the pad scar (active or inactive). The new 2012 database contains 17,404 pad scars of which 15,532 are attributed as oil and natural gas well pads. Digital data are stored as shapefiles projected to the Universal Transverse Mercator (zones 12 and 13) coordinate system. These data are available from the U.S. Geological Survey (USGS) at http://dx.doi.org/10

Knowing thy enemy : detailed study of coiled tubing's breaking point in sour conditions is leading to failure avoidance

Energy Technology Data Exchange (ETDEWEB)

Smith, M.

2007-03-15

Well failures arising from coiled tubing (CT) in sour oil and gas environments can result in the loss of millions of dollars. This article examined some of the causes of CT well failures in Alberta, and provided details of joint industry projects (JIPs) headed by BJ Services Company currently investigating the chemical reactions related to the degradation of CT materials. Degradation of CT tools can be caused hydrogen-induced cracking (HIC); sulphide stress cracking; step-wise cracking; stress-oriented HIC; and blistering. CT is repeatedly wound off and onto a reel when cycled in and out of wells, and can accumulate both low-cycle fatigue and surface damage over time, either of which can lead to failures. Exposure to hydrogen sulphide (H{sub 2}S) significantly reduces the lifespan of CT. When H{sub 2}S is in an aqueous environment or solution and comes into contact with steel, chemical reactions take place on the surface of the steel that generate atomic hydrogen, which causes the steel to become brittle. Cracking can also occur as a result of the hydrogen atoms within the steel matrix recombining to form hydrogen molecules, or as the result of applying a stress above threshold limits. Tests are now being conducted at a Shell laboratory to expose CT specimens to H{sub 2}S. After immersion, the steel specimens are then maintained in a -78.5 degrees C environment so that the H{sub 2}S is locked into the steel. Acoustic emission sensors are wired to a monitoring system to determine both when cracks occur and under what conditions of load or severity of environment. A bend fatigue machine is also used to cycle CT through a bend and straighten sequence. Samples also undergo constant load testing, hydrogen diffusion cell testing and external mechanical damage assessments. The effect of H{sub 2}S on bias and butt welds is also studied. Efforts are also being made to improve the CT steel manufacturing process. Results of the JIP have led researchers to conclude that

Assessment of Gas Production Potential from Hydrate Reservoir in Qilian Mountain Permafrost Using Five-Spot Horizontal Well System

Directory of Open Access Journals (Sweden)

Yun-Pei Liang

2015-09-01

Full Text Available The main purpose of this study is to investigate the production behaviors of gas hydrate at site DK-2 in the Qilian Mountain permafrost using the novel five-spot well (5S system by means of numerical simulation. The whole system is composed of several identical units, and each single unit consists of one injection well and four production wells. All the wells are placed horizontally in the hydrate deposit. The combination method of depressurization and thermal stimulation is employed for hydrate dissociation in the system. Simulation results show that favorable gas production and hydrate dissociation rates, gas-to-water ratio, and energy ratio can be acquired using this kind of multi-well system under suitable heat injection and depressurization driving forces, and the water production rate is manageable in the entire production process under current technology. In addition, another two kinds of two-spot well (2S systems have also been employed for comparison. It is found that the 5S system will be more commercially profitable than the 2S configurations for gas production under the same operation conditions. Sensitivity analysis indicates that the gas production performance is dependent on the heat injection rate and the well spacing of the 5S system.

Concentration of saline produced water from coalbed methane gas wells in multiple-effect evaporator using waste heat from the gas compressor and compressor drive engine

International Nuclear Information System (INIS)

Sadler, L.Y.; George, O.

1995-01-01

The use of heat of compression from the gas compressor and waste heat from the diesel compressor drive engine in a triple-effect feed forward evaporator was studied as a means of concentrating saline produced water to facilitate its disposal. The saline water, trapped in deeply buried coal seams, must be continuously pumped from coalbed natural gas wells so that the gas can desorb from the coal and make its way to the wellbore. Unlike conventional natural gas which is associated with petroleum and usually reaches the wellhead at high pressure, coalbed natural gas reaches the wellhead at low pressure, usually around 101 kPa (1 atm), and must be compressed near the well site for injection into gas transmission pipelines. The water concentration process was simulated for a typical 3.93 m 3 /s (500 MCF/h), at standard conditions (101 kPa, 289K), at the gas production field in the Warrior Coal Basin of Alabama, but has application to the coalbed gas fields being brought into production throughout the world. It was demonstrated that this process can be considered for concentrating saline water produced with natural gas in cases where the gas must be compressed near the wellhead for transportation to market. 9 refs., 1 fig., 2 tabs

Ensuring full-capacity production in case of liquid loading in gas wells; Aufrechterhalten der Produktion aus verwaessernden Erdgasbohrungen

Energy Technology Data Exchange (ETDEWEB)

Reinicke, K.M. [Technische Univ. Clausthal (Germany). Inst. fuer Erdoel- und Erdgastechnik; Albrecht, I. [Schlumberger Holding GmbH, Hannover (Germany); Thurow, M. [ILF Consulting Engineers, Muenchen (Germany)

2007-09-13

In the late production stages, water production from natural gas wells may become a problem that may require abandoning the well, thus losing valuable productive assets. In a joint project of organisations of the Deutsche Wissenschaftliche Gesellschaft fuer Erdoel, Erdgas und Kohle, a status report was made in 2005, and best practice methods for dewatering natural gas wells were identified. This contribution presents some of the results: common methods for improved liquid unloading from natural gas wells, preconditions for their application, experience of the industries in this field, elements of the selection and planning process, and an outlook. (orig.)

Acid stimulation (sour taste elicits GABA and serotonin release from mouse taste cells.

Directory of Open Access Journals (Sweden)

Yijen A Huang

Full Text Available Several transmitter candidates including serotonin (5-HT, ATP, and norepinephrine (NE have been identified in taste buds. Recently, γ-aminobutyric acid (GABA as well as the associated synthetic enzymes and receptors have also been identified in taste cells. GABA reduces taste-evoked ATP secretion from Receptor cells and is considered to be an inhibitory transmitter in taste buds. However, to date, the identity of GABAergic taste cells and the specific stimulus for GABA release are not well understood. In the present study, we used genetically-engineered Chinese hamster ovary (CHO cells stably co-expressing GABA(B receptors and Gαqo5 proteins to measure GABA release from isolated taste buds. We recorded robust responses from GABA biosensors when they were positioned against taste buds isolated from mouse circumvallate papillae and the buds were depolarized with KCl or a stimulated with an acid (sour taste. In contrast, a mixture of sweet and bitter taste stimuli did not trigger GABA release. KCl- or acid-evoked GABA secretion from taste buds was Ca(2+-dependent; removing Ca(2+ from the bathing medium eliminated GABA secretion. Finally, we isolated individual taste cells to identify the origin of GABA secretion. GABA was released only from Presynaptic (Type III cells and not from Receptor (Type II cells. Previously, we reported that 5-HT released from Presynaptic cells inhibits taste-evoked ATP secretion. Combined with the recent findings that GABA depresses taste-evoked ATP secretion, the present results indicate that GABA and 5-HT are inhibitory transmitters in mouse taste buds and both likely play an important role in modulating taste responses.

A sequential approach to control gas for the extraction of multi-gassy coal seams from traditional gas well drainage to mining-induced stress relief

International Nuclear Information System (INIS)

Kong, Shengli; Cheng, Yuanping; Ren, Ting; Liu, Hongyong

2014-01-01

Highlights: • The gas reservoirs characteristics are measured and analyzed. • A sequential approach to control gas of multi-gassy coal seams is proposed. • The design of gas drainage wells has been improved. • The utilization ways of different concentrations of gas production are shown. - Abstract: As coal resources become exhausted in shallow mines, mining operations will inevitably progress from shallow depth to deep and gassy seams due to increased demands for more coal products. However, during the extraction process of deeper and gassier coal seams, new challenges to current gas control methods have emerged, these include the conflict between the coal mine safety and the economic benefits, the difficulties in reservoirs improvement, as well as the imbalance between pre-gas drainage, roadway development and coal mining. To solve these problems, a sequential approach is introduced in this paper. Three fundamental principles are proposed: the mining-induced stress relief effect of the first-mined coalbed should be sufficient to improve the permeability of the others; the coal resource of the first-mined seams must be abundant to guarantee the economic benefits; the arrangement of the vertical wells must fit the underground mining panel. Tunlan coal mine is taken as a typical example to demonstrate the effectiveness of this approach. The approach of integrating surface coalbed methane (CBM) exploitation with underground gas control technologies brings three major benefits: the improvement of underground coal mining safety, the implementation of CBM extraction, and the reduction of greenhouse gas emissions. This practice could be used as a valuable example for other coal mines having similar geological conditions

SELECTION AND TREATMENT OF STRIPPER GAS WELLS FOR PRODUCTION ENHANCEMENT, MOCANE-LAVERNE FIELD, OKLAHOMA

Energy Technology Data Exchange (ETDEWEB)

Scott Reeves; Buckley Walsh

2003-08-01

In 1996, Advanced Resources International (ARI) began performing R&D targeted at enhancing production and reserves from natural gas fields. The impetus for the effort was a series of field R&D projects in the early-to-mid 1990's, in eastern coalbed methane and gas shales plays, where well remediation and production enhancement had been successfully demonstrated. As a first step in the R&D effort, an assessment was made of the potential for restimulation to provide meaningful reserve additions to the U.S. gas resource base, and what technologies were needed to do so. That work concluded that: (1) A significant resource base did exist via restimulation (multiples of Tcf). (2) The greatest opportunities existed in non-conventional plays where completion practices were (relatively) complex and technology advancement was rapid. (3) Accurate candidate selection is the greatest single factor that contributes to a successful restimulation program. With these findings, a field-oriented program targeted at tight sand formations was initiated to develop and demonstrate successful candidate recognition technology. In that program, which concluded in 2001, nine wells were restimulated in the Green River, Piceance and East Texas basins, which in total added 2.9 Bcf of reserves at an average cost of $0.26/Mcf. In addition, it was found that in complex and heterogeneous reservoirs (such as tight sand formations), candidate selection procedures should involve a combination of fundamental engineering and advanced pattern recognition approaches, and that simple statistical methods for identifying candidate wells are not effective. In mid-2000, the U.S. Department of Energy (DOE) awarded ARI an R&D contract to determine if the methods employed in that project could also be applied to stripper gas wells. In addition, the ability of those approaches to identify more general production enhancement opportunities (beyond only restimulation), such as via artificial lift and compression

Effects of acid conditions on element distribution beneath a sulphur basepad

International Nuclear Information System (INIS)

Sevigny, J.H.; Fennell, J.W.; Sharma, A.

1997-04-01

A reconnaissance-scale study was conducted to determine the extent of acid conditions beneath a sulphur basepad at Canadian Occidental's Balzac sour gas plant and to examine the effects of acid conditions on element distribution in the subsurface. Sulphur which is extracted from sour natural gas is stored in large blocks directly on the ground. The elemental sulphur will oxidize to H 2 SO 4 under aerobic conditions and with the proper microorganisms can result in possible removal of metals from the soil and transportation in the groundwater. The basepad at the sour gas plant is 36 years old and is covered by about 1 metre of elemental sulphur. EM31 terrain conductivity and electrical resistivity tomography geophysical surveys were conducted to determine aerial and subsurface bulk electrical conductivity. The objective was to locate the indurated layer using the geophysical techniques and soil boring. The extent of acid conditions beneath the sulphur block was determined. Migration rates for the site were also estimated. Results suggested that minimal soil and groundwater impact can be expected from sulphur blocks overlying properly buffered soils, and that synthetic liners beneath sulphur blocks may not be a necessary measure at sour gas plants in Alberta. 19 refs., 6 tabs., 6 figs., 5 appendices

A breakthrough in flue gas cleanup, CO2 mitigation and H2S removal

Energy Technology Data Exchange (ETDEWEB)

Koch, Wolf; Wasas, James; Stenger, Raymond; Howell, Evan

2010-09-15

SWAPSOL Corp. is developing commercial processes around a newly discovered reaction that reduces H2S below detectable levels while reacting with CO2 to form water, sulfur and carsuls, a carbon-sulfur polymer. The Stenger-Wasas Process (SWAP) stands to simplify sulfur removal technology as it consumes CO2 in an exothermic reaction. The SWAP has applications in landfill, sour, flue and Claus tail gas cleanup and may replace Claus technology. Destruction of waste hydrocarbons provides a source of H2S. The primary reactions and variants have been independently verified and the chemical kinetics determined by a third party laboratory.

Properties of samples containing natural gas hydrate from the JAPEX/JNOC/GSC Mallik 2L-38 gas hydrate research well, determined using Gas Hydrate And Sediment Test Laboratory Instrument (GHASTLI)

Science.gov (United States)

Winters, W.J.

1999-01-01

As part of an ongoing laboratory study, preliminary acoustic, strength, and hydraulic conductivity results are presented from a suite of tests conducted on four natural-gas-hydrate-containing samples from the Mackenzie Delta JAPEX/JNOC/GSC Mallik 2L-38 gas hydrate research well. The gas hydrate samples were preserved in pressure vessels during transport from the Northwest Territories to Woods Hole, Massachusetts, where multistep tests were performed using GHASTLI (Gas Hydrate And Sediment Test Laboratory Instrument), which recreates pressure and temperature conditions that are stable for gas hydrate. Properties and changes in sediment behaviour were measured before, during, and after controlled gas hydrate dissociation. Significant amounts of gas hydrate occupied the sample pores and substantially increased acoustic velocity and shear strength.

The tidal influence on oil and gas emissions from an abandoned oil well: Nearshore Summerland, California

International Nuclear Information System (INIS)

Leifer, Ira; Wilson, Ken

2007-01-01

Oil and gas emissions were quantified for natural and human sources in nearshore waters off Summerland, California through deployment of custom designed collection tents. Seepage was measured at a repeatedly abandoned well, on the seabed from a caisson located along the historical location of the Treadwell Wharf, where the world's first off-shore oil wells were drilled at the end of the 19th century. Seepage rates at the capped T-10 Well, located in ∼5 m water, showed high correlation to tides. Site emissions were 2.4 and 38.7 L day -1 oil and gas, respectively. Emissions were measured from two areas of seepage at the T-10 Well Site. Oil and gas ratios were inversely correlated between the two seepage areas, demonstrating connectivity. Data were interpreted in terms of an electronic circuit model of seepage with respect to the time lag between local low tide and peak oil emissions

A New Approach for Accurate Prediction of Liquid Loading of Directional Gas Wells in Transition Flow or Turbulent Flow

Directory of Open Access Journals (Sweden)

Ruiqing Ming

2017-01-01

Full Text Available Current common models for calculating continuous liquid-carrying critical gas velocity are established based on vertical wells and laminar flow without considering the influence of deviation angle and Reynolds number on liquid-carrying. With the increase of the directional well in transition flow or turbulent flow, the current common models cannot accurately predict the critical gas velocity of these wells. So we built a new model to predict continuous liquid-carrying critical gas velocity for directional well in transition flow or turbulent flow. It is shown from sensitivity analysis that the correction coefficient is mainly influenced by Reynolds number and deviation angle. With the increase of Reynolds number, the critical liquid-carrying gas velocity increases first and then decreases. And with the increase of deviation angle, the critical liquid-carrying gas velocity gradually decreases. It is indicated from the case calculation analysis that the calculation error of this new model is less than 10%, where accuracy is much higher than those of current common models. It is demonstrated that the continuous liquid-carrying critical gas velocity of directional well in transition flow or turbulent flow can be predicted accurately by using this new model.

Hydrocarbon and Carbon Dioxide Fluxes from Natural Gas Well Pad Soils and Surrounding Soils in Eastern Utah.

Science.gov (United States)

Lyman, Seth N; Watkins, Cody; Jones, Colleen P; Mansfield, Marc L; McKinley, Michael; Kenney, Donna; Evans, Jordan

2017-10-17

We measured fluxes of methane, nonmethane hydrocarbons, and carbon dioxide from natural gas well pad soils and from nearby undisturbed soils in eastern Utah. Methane fluxes varied from less than zero to more than 38 g m -2 h -1 . Fluxes from well pad soils were almost always greater than from undisturbed soils. Fluxes were greater from locations with higher concentrations of total combustible gas in soil and were inversely correlated with distance from well heads. Several lines of evidence show that the majority of emission fluxes (about 70%) were primarily due to subsurface sources of raw gas that migrated to the atmosphere, with the remainder likely caused primarily by re-emission of spilled liquid hydrocarbons. Total hydrocarbon fluxes during summer were only 39 (16, 97)% as high as during winter, likely because soil bacteria consumed the majority of hydrocarbons during summer months. We estimate that natural gas well pad soils account for 4.6 × 10 -4 (1.6 × 10 -4 , 1.6 × 10 -3 )% of total emissions of hydrocarbons from the oil and gas industry in Utah's Uinta Basin. Our undisturbed soil flux measurements were not adequate to quantify rates of natural hydrocarbon seepage in the Uinta Basin.

An evaluation of water quality in private drinking water wells near natural gas extraction sites in the Barnett Shale formation.

Science.gov (United States)

Fontenot, Brian E; Hunt, Laura R; Hildenbrand, Zacariah L; Carlton, Doug D; Oka, Hyppolite; Walton, Jayme L; Hopkins, Dan; Osorio, Alexandra; Bjorndal, Bryan; Hu, Qinhong H; Schug, Kevin A

2013-09-03

Natural gas has become a leading source of alternative energy with the advent of techniques to economically extract gas reserves from deep shale formations. Here, we present an assessment of private well water quality in aquifers overlying the Barnett Shale formation of North Texas. We evaluated samples from 100 private drinking water wells using analytical chemistry techniques. Analyses revealed that arsenic, selenium, strontium and total dissolved solids (TDS) exceeded the Environmental Protection Agency's Drinking Water Maximum Contaminant Limit (MCL) in some samples from private water wells located within 3 km of active natural gas wells. Lower levels of arsenic, selenium, strontium, and barium were detected at reference sites outside the Barnett Shale region as well as sites within the Barnett Shale region located more than 3 km from active natural gas wells. Methanol and ethanol were also detected in 29% of samples. Samples exceeding MCL levels were randomly distributed within areas of active natural gas extraction, and the spatial patterns in our data suggest that elevated constituent levels could be due to a variety of factors including mobilization of natural constituents, hydrogeochemical changes from lowering of the water table, or industrial accidents such as faulty gas well casings.

Underbalance well completion - a modern approach for mature gas fields

Directory of Open Access Journals (Sweden)

Tătaru Argentina

2017-01-01

Full Text Available The exploitation of natural gas fields from Transylvanian Basin started a century ago. The majority of these fields were discovered and developed in the last century, from 1950 to 1970. So, these reservoirs have over 50 years of production historical. These are mature fields with a very low reservoir pressure. Now, for some of these reservoirs the pressure is 10 – 20 % of initial values. The biggest challenge for a production company is to make completions and recompletions in depleted reservoirs wells. At the beginning was not a problem to do a workover in these wells because the completion fluids were lost in the reservoir and the pressure helped the wells to clean up. Now, because the reservoir pressure is very low, it takes time for well to be cleaned. From time to time, some net pays have to be bypassed because the fluid can be lost in the reservoir. So the best method to do recompletion works in these wells is to work underbalance or even with the well under pressure. This paper presents some of the technologies used by Romgaz to accomplish this goal.

Vertical seismic profile data from well Mallik 2L-38 for gas hydrate studies

Energy Technology Data Exchange (ETDEWEB)

Mi, Y [Calgary Univ., AB (Canada). Dept. of Geology and Geophysics; Walia, R [Victoria Univ., BC (Canada) School of Earth and Ocean Sciences; Hyndman, R [Geological Survey of Canada, Sidney, BC (Canada) Pacific Geoscience Centre

1999-07-01

A gas hydrate research well was drilled in the Canadian Arctic to study gas hydrates in a permafrost setting in a collaborative research project between the Japan National Oil Corp., the Geological Survey of Canada and other agencies. The multidisciplinary study included an electromagnetic survey, permafrost and gas hydrate coring, comprehensive downhole geophysical logging and measurement. Laboratory studies concerned studies on recovered cuttings and core including sedimentology, physical properties, geochemistry, and reservoir characteristics of the Mallik gas accumulation. As part of the Mallik 2L-38 field program, a vertical seismic profiling survey was conducted at zero and other offset source positions with three component receiver tools and horizontal and vertical vibration sources. A special effort was made to record shear wave data, which will be used to estimate the effect of gas hydrate on formation velocities and to determine gas hydrate concentration as a function of the Mallik gas accumulation. From the initial VSP analysis, certain conclusions follow: 1) zero offset vertical vibration component Z and horizontal X component data give reliable velocity determination within the gas hydrate formation zone. P wave velocities from offset VSP data show an excellent consistency with that from offset data and with the sonic log. And 2) the VSP data permit reliable identification of gas hydrate bearing zones. Abstract only included.

Subjective Well-Being Approach to Environmental Valuation: Evidence for Greenhouse Gas Emissions

Science.gov (United States)

Beja, Edsel L., Jr.

2012-01-01

The subjective well-being approach to environmental valuation is applied to analyze the valuation of greenhouse gas emissions with a fairness-adjustment in the valuation exercise. Results indicate that industrialized countries have high willingness-to-pay to reduce emissions. Developing countries differ in their valuations. Results indicate that…

A Mathematical Pressure Transient Analysis Model for Multiple Fractured Horizontal Wells in Shale Gas Reservoirs

Directory of Open Access Journals (Sweden)

Yan Zeng

2018-01-01

Full Text Available Multistage fractured horizontal wells (MFHWs have become the main technology for shale gas exploration. However, the existing models have neglected the percolation mechanism in nanopores of organic matter and failed to consider the differences among the reservoir properties in different areas. On that account, in this study, a modified apparent permeability model was proposed describing gas flow in shale gas reservoirs by integrating bulk gas flow in nanopores and gas desorption from nanopores. The apparent permeability was introduced into the macroseepage model to establish a dynamic pressure analysis model for MFHWs dual-porosity formations. The Laplace transformation and the regular perturbation method were used to obtain an analytical solution. The influences of fracture half-length, fracture permeability, Langmuir volume, matrix radius, matrix permeability, and induced fracture permeability on pressure and production were discussed. Results show that fracture half-length, fracture permeability, and induced fracture permeability exert a significant influence on production. A larger Langmuir volume results in a smaller pressure and pressure derivative. An increase in matrix permeability increases the production rate. Besides, this model fits the actual field data relatively well. It has a reliable theoretical foundation and can preferably describe the dynamic changes of pressure in the exploration process.

MODELING OF FLOW AND TRANSPORT INDUCED BY PRODUCTION OF HYDROFRACTURE-STIMULATED GAS WELLS NEAR THE RULISON NUCLEAR TEST

Energy Technology Data Exchange (ETDEWEB)

Hodges, Rex A. [Navarro Research and Engineering; Cooper, Clay [Desert Research Inst. (DRI), Reno, NV (United States); Falta, Ronald [Clemson Univ., SC (United States)

2012-09-17

The Piceance Basin in western Colorado contains significant reserves of natural gas in poorly connected, low-permeability (tight) sandstone lenses of the Mesaverde Group. The ability to enhance the production of natural gas in this area has long been a goal of the oil and gas industry. The U.S. Atomic Energy Commission, a predecessor agency to the U.S. Department of Energy (DOE) and the U.S. Nuclear Regulatory Commission, participated in three tests using nuclear detonations to fracture tight formations in an effort to enhance gas production. The tests were conducted under Project Plowshare, a program designed to identify peaceful, beneficial uses for nuclear devices. The first, Project Gasbuggy, was conducted in 1967 in the San Juan Basin of New Mexico. The two subsequent tests, Project Rulison in 1969 and Project Rio Blanco in 1973, were in the Piceance Basin. The ability to enhance natural gas production from tight sands has become practical through advances in hydraulic fracturing technology (hydrofracturing). This technology has led to an increase in drilling activity near the Rulison site, raising concerns that contamination currently contained in the subsurface could be released through a gas well drilled too close to the site. As wells are drilled nearer the site, the DOE Office of Legacy Management has taken the approach outlined in the June 2010 Rulison Path Forward document (DOE 2010), which recommends a conservative, staged approach to gas development. Drillers are encouraged to drill wells in areas with a low likelihood of encountering contamination (both distance and direction from the detonation zone are factors) and to collect data from these wells prior to drilling nearer the site’s 40 acre institutional control boundary (Lot 11). Previous modeling results indicate that contamination has been contained within Lot 11 (Figure 1). The Path Forward document couples the model predictions with the monitoring of gas and produced water from the gas wells

A numerical study of under-deposit pitting corrosion in sour petroleum pipelines

Energy Technology Data Exchange (ETDEWEB)

Zhu, Z.; Sand, K.W.; Teevens, P.J. [Broadsword Corrosion Engineering Ltd., Calgary, AB (Canada)

2010-07-01

Insufficient fluid velocity in petroleum pipelines can lead to the deposit of sand, corrosion products, and non-corrosion products on the pipe's metal surface, which in turn can lead to pitting corrosion. There is currently no reliable means of detecting and preventing the pitting process. This paper presented a computerized simulation tool that used the finite element method to model mass transfer-governed internal pitting corrosion under solids deposition in sour petroleum pipelines. The computational domain consisted of a hemispherical pit and a thin stagnant solution film under a surface deposit. The moving mesh method was used to track pitting growth. A Poisson equation was used to determine aqueous path migration of ions. Pitting corrosion rates were estimated using the Nernst-Planck equation. The model was used to predict the effects of different operating parameters on pitting corrosion rates. The model can be used to develop pigging and in-line-inspection (ILI) procedures. 35 refs., 2 tabs., 16 figs.

Broadening benefits from natural resource extraction: Housing values and taxation of natural gas wells as property

OpenAIRE

Weber, Jeremy G.; Burnett, J.Wesley; Xiarchos, Irene M.

2016-01-01

We study the effects of the property tax base shock caused by natural gas drilling in the Barnett Shale in Texas–a state that taxes oil and gas wells as property. Over the boom and bust in drilling, housing appreciation closely followed the oil and gas property tax base, which expanded the total tax base by 23 percent at its height. The expansion led to a decline in property tax rates while maintaining or increasing revenues to schools. Overall, each $1 per student increase in the oil and gas...

A Novel Acoustic Liquid Level Determination Method for Coal Seam Gas Wells Based on Autocorrelation Analysis

Directory of Open Access Journals (Sweden)

Ximing Zhang

2017-11-01

Full Text Available In coal seam gas (CSG wells, water is periodically removed from the wellbore in order to keep the bottom-hole flowing pressure at low levels, facilitating the desorption of methane gas from the coal bed. In order to calculate gas flow rate and further optimize well performance, it is necessary to accurately monitor the liquid level in real-time. This paper presents a novel method based on autocorrelation function (ACF analysis for determining the liquid level in CSG wells under intense noise conditions. The method involves the calculation of the acoustic travel time in the annulus and processing the autocorrelation signal in order to extract the weak echo under high background noise. In contrast to previous works, the non-linear dependence of the acoustic velocity on temperature and pressure is taken into account. To locate the liquid level of a coal seam gas well the travel time is computed iteratively with the non-linear velocity model. Afterwards, the proposed method is validated using experimental laboratory investigations that have been developed for liquid level detection under two scenarios, representing the combination of low pressure, weak signal, and intense noise generated by gas flowing and leakage. By adopting an evaluation indicator called Crest Factor, the results have shown the superiority of the ACF-based method compared to Fourier filtering (FFT. In the two scenarios, the maximal measurement error from the proposed method was 0.34% and 0.50%, respectively. The latent periodic characteristic of the reflected signal can be extracted by the ACF-based method even when the noise is larger than 1.42 Pa, which is impossible for FFT-based de-noising. A case study focused on a specific CSG well is presented to illustrate the feasibility of the proposed approach, and also to demonstrate that signal processing with autocorrelation analysis can improve the sensitivity of the detection system.

Transient Flow Dynamics in Optical Micro Well Involving Gas Bubbles

Science.gov (United States)

Johnson, B.; Chen, C. P.; Jenkins, A.; Spearing, S.; Monaco, L. A.; Steele, A.; Flores, G.

2006-01-01

The Lab-On-a-Chip Application Development (LOCAD) team at NASA s Marshall Space Flight Center is utilizing Lab-On-a-Chip to support technology development specifically for Space Exploration. In this paper, we investigate the transient two-phase flow patterns in an optic well configuration with an entrapped bubble through numerical simulation. Specifically, the filling processes of a liquid inside an expanded chamber that has bubbles entrapped. Due to the back flow created by channel expansion, the entrapped bubbles tend to stay stationary at the immediate downstream of the expansion. Due to the huge difference between the gas and liquid densities, mass conservation issues associated with numerical diffusion need to be specially addressed. The results are presented in terms of the movement of the bubble through the optic well. Bubble removal strategies are developed that involve only pressure gradients across the optic well. Results show that for the bubble to be moved through the well, pressure pulsations must be utilized in order to create pressure gradients across the bubble itself.

Collective Behavior of a Spin-Aligned Gas of Interwell Excitons in Double Quantum Wells

DEFF Research Database (Denmark)

Larionov, A. V.; Bayer, M.; Hvam, Jørn Märcher

2005-01-01

The kinetics of a spin-aligned gas of interwell excitons in GaAs/AlGaAs double quantum wells (n–i–n heterostructure) is studied. The temperature dependence of the spin relaxation time for excitons, in which a photoexcited electron and hole are spatially separated between two adjacent quantum wells...

75 FR 75995 - Request for Comments on Helium-3 Use in the Oil and Natural Gas Well Logging Industry

Science.gov (United States)

2010-12-07

... manufacture neutron detectors used by the well logging industry or wireline or Logging-While-Drilling tools... DEPARTMENT OF ENERGY Request for Comments on Helium-3 Use in the Oil and Natural Gas Well Logging... of Helium-3 by the oil and gas well logging industry. DATES: Written comments and information are...

Determining the hydraulic and fracture properties of the Coal Seam Gas well by numerical modelling and GLUE analysis

Science.gov (United States)

Askarimarnani, Sara; Willgoose, Garry; Fityus, Stephen

2017-04-01

Coal seam gas (CSG) is a form of natural gas that occurs in some coal seams. Coal seams have natural fractures with dual-porosity systems and low permeability. In the CSG industry, hydraulic fracturing is applied to increase the permeability and extract the gas more efficiently from the coal seam. The industry claims that it can design fracking patterns. Whether this is true or not, the public (and regulators) requires assurance that once a well has been fracked that the fracking has occurred according to plan and that the fracked well is safe. Thus defensible post-fracking testing methodologies for gas generating wells are required. In 2009 a fracked well HB02, owned by AGL, near Broke, NSW, Australia was subjected to "traditional" water pump-testing as part of this assurance process. Interpretation with well Type Curves and simple single phase (i.e. only water, no gas) highlighted deficiencies in traditional water well approaches with a systemic deviation from the qualitative characteristic of well drawdown curves (e.g. concavity versus convexity of drawdown with time). Accordingly a multiphase (i.e. water and methane) model of the well was developed and compared with the observed data. This paper will discuss the results of this multiphase testing using the TOUGH2 model and its EOS7C constitutive model. A key objective was to test a methodology, based on GLUE monte-carlo calibration technique, to calibrate the characteristics of the frack using the well test drawdown curve. GLUE involves a sensitivity analysis of how changes in the fracture properties change the well hydraulics through and analysis of the drawdown curve and changes in the cone of depression. This was undertaken by changing the native coal, fracture, and gas parameters to see how changing those parameters changed the match between simulations and the observed well drawdown. Results from the GLUE analysis show how much information is contained in the well drawdown curve for estimating field scale

Technique of optimum extraction of pectin from sour orange peels and its chemical evaluation

International Nuclear Information System (INIS)

Abid, H.; Hussain, A.; Ali, J.

2009-01-01

The extraction of pectin from sour orange peels and effect of pH, temperature, extraction time on the yield and quality of pectin was studied. The extracting reagent was 0.1 N sulphuric acid and variables were pH (1.5, 2.5 and 3.5), extraction time (30, 60 and 120 minutes) and temperature (70 degree C, 80 degree C arid 90 degree C). These variables were significantly affected the extraction of pectin. The best yield (16.10 %) was obtained on soaking the finely ground peels in the sulphuric acid solution of pH, 25 at 80 degree C for 120 minutes. Anhydrogalacturonic acid, methoxyl content were 7310 % and 9.93 %, respectively, while equivalent weight value 945 was obtained by using pH, 2.5 at 80 degree C for 120 minutes. (author)

IPR CURVE CALCULATING FOR A WELL PRODUCING BY INTERMITTENT GAS-LIFT METHOD

Directory of Open Access Journals (Sweden)

Zoran Mršić

2009-12-01

Full Text Available Master degree thesis (Mršić Z., 2009 shows the detailed procedure of calculating inflow performance curve for intermittent gas lift, based entirely on the data measured at surface. This article explains the detailed approach of the mentioned research and the essence of the results and observations acquired during the study. To evaluate the proposed method of calculating the average bottom hole flowing pressure (BHFP as the key parameter of inflow performance calculation, downhole pressure surveys have been conducted in three producing wells at Šandrovac and Bilogora oil fields: Šandrovac-75α, Bilogora-52 and Šandrovac-34. Absolute difference between measured and calculated values of average BHFP for first two wells was Δp=0,64 bar and Δp=0,06 bar while calculated relative error was εr=0,072 and εr=0,0038 respectively. Due to gas-lift valve malfunction in well Šandrovac-34, noticed during downhole pressure survey, value of calculated BHFP cannot be considered correct to compare with measured value. Based on the measured data the information have been revealed about actual values of a certain intermittent gas lift parameters that are usually assumed based on experience gained values or are calculated using empirical equations given in literature. The significant difference has been noticed for a parameter t2. The length of a minimum pressure period for which the measured values were in range of 10,74 min up to 16 min, while empirical equation gives values in the range of 1,23 min up to 1,75 min. Based on measured values of above mentioned parameter a new empirical equation has been established (the paper is published in Croatian.

Standard for baseline water-well testing for coalbed methane/natural gas in coal operations

International Nuclear Information System (INIS)

2006-04-01

Interest in developing coalbed methane (CBM) is increasing with the decline of conventional natural gas reserves. In Alberta, where CBM is in the early stages of development, the drilling, production and operational rules for CBM are the same as those that apply to natural gas. The government of Alberta is presently examining the rules and regulations that apply to CBM to determine if they are appropriate for responsible development and balanced with environmental protection. CBM development has the potential to affect water aquifers and water supply. As such, a new standard has been developed by Alberta Environment in collaboration with the Alberta Energy and Utilities Board which requires that companies involved in the development of shallow CBM must offer to test rural Albertan's water wells prior to drilling. The companies will submit baseline groundwater data to both Alberta Environment and the landowner. The broader application of groundwater testing will also support Alberta Environment's objective of mapping all groundwater resources in the province. This new standard will help achieve continued protection of provincial groundwater resources and Albertan's groundwater supplies. It will also facilitate responsible CBM development and the government's Water for Life strategy. This document explained the protocols for testing, sampling and analyzing groundwater. The standard provides scientific information to support achievement of the outcomes as well as a regulatory basis for water well testing and baseline data collection prior to CBM development. If a landowner registers a complaint regarding a perceived change in well water quantity and quality after CBM development, then the developers must retest the water well to address the landowner's concerns. The tests evaluate water well capacity, water quality, routine potability and analysis for water quality parameters, including major ionic constituents, bacteriological analysis and presence or absence of gas

Geochemical evaluation of flowback brine from Marcellus gas wells in Pennsylvania, USA

International Nuclear Information System (INIS)

Haluszczak, Lara O.; Rose, Arthur W.; Kump, Lee R.

2013-01-01

Large quantities of highly saline brine flow from gas wells in the Marcellus Formation after hydraulic stimulation (“fracking”). This study assesses the composition of these flowback waters from the Marcellus shale in Pennsylvania, USA. Concentrations of most inorganic components of flowback water (Cl, Br, Na, K, Ca, Mg, Sr, Ba, Ra, Fe, Mn, total dissolved solids, and others) increase with time from a well after hydraulic stimulation. Based on results in several datasets reported here, the greatest concentration of Cl − in flowback water is 151,000 mg/L. For total Ra (combined 226 Ra and 228 Ra) in flowback, the highest level reported is 6540 pCi/L. Flowback waters from hydraulic fracturing of Marcellus wells resemble brines produced from conventional gas wells that tap into other Paleozoic formations in the region. The Br/Cl ratio and other parameters indicate that both types of brine formed by the evaporation of seawater followed by dolomitization, sulfate reduction and subsurface mixing with seawater and/or freshwater. Trends and relationships in brine composition indicate that (1) increased salt concentration in flowback is not mainly caused by dissolution of salt or other minerals in rock units, (2) the flowback waters represent a mixture of injection waters with highly concentrated in situ brines similar to those in the other formations, and (3) these waters contain concentrations of Ra and Ba that are commonly hundreds of times the US drinking water standards.

Breckinridge Project, initial effort

Energy Technology Data Exchange (ETDEWEB)

None

1982-01-01

Report IV, Volume 5, provides descriptions, data, and drawings pertaining to Cryogenic Hydrogen Purification (Plant 8), Sour Water Treating (Plant 9), and the Sulfur Plant (Plant 10). Cryogenic Hydrogen Purification (Plant 8) purifies the purge gas stream from the Gas Plant (Plant 7, described in Report IV, Volume 4) to a 93% purity hydrogen product. Sour Water Treating (Plant 9) removes free ammonia and acid gases from sour water and separates them to recover a high quality anhydrous ammonia product. The Sulfur Plant (Plant 10) recovers, as a saleable liquid product, approximately 95% of the sulfur in feed streams from the Gas Plant (Plant 7, described in Report IV, Volume 4), Sour Water Treating (Plant 9), Gasification and Purification (Plant 12, described in Report IV, Volume 6), and Stack Gas Scrubbing (Plant 35, described in Report V, Volume 3). The following information is included for each of the three plants described in this volume: a description of the plant's process design, including the utility balance, catalysts and chemicals usage, and a process flow diagram; an equipment list, including item numbers and descriptions; data sheets and sketches for major plant components; and pertinent engineering drawings. An appendix contains: an overall site plan showing the locations of all plants; and the symbols and legend for the piping and instrument diagrams included in this volume.

PRODUCTION SYSTEM MODELING OF THE GAS LIFTED WELL BY MEANS OF THE PROGRAM PROSPER

Directory of Open Access Journals (Sweden)

Sonja Koščak Kolin

2009-12-01

Full Text Available A production system analysis was made for the well Šandrovac-136 equipped with a continuous gas lift. The analysis was based on the test data which served as the foundation for creating a production well model in computer program ‘PROSPER’ (Version 10.3, License 2681. The importance of the measured data in well modeling is accuracy and reliability in predicting future developments of the production system. The model design can be divided in six steps among which the most important are: calculation of the IPR curve, calculation of the gas lift system and matching of VLP and IPR curves based on the well testing. The aim of the VLP/IPR matching is to choose an appropriate method for calculating the pressure drop gradient by applying the nonlinear regression method, which results in the system working point adjusted to the measured data. This model was applied in sensitivity analysis of the well, in which three key variables are selected to predict their effect on future system changes, primarily on changes of the production and bottom dynamic pressure (the paper is published in Croatian.

A new method in predicting productivity of multi-stage fractured horizontal well in tight gas reservoirs

Directory of Open Access Journals (Sweden)

Yunsheng Wei

2016-10-01

Full Text Available The generally accomplished technique for horizontal wells in tight gas reservoirs is by multi-stage hydraulic fracturing, not to mention, the flow characteristics of a horizontal well with multiple transverse fractures are very intricate. Conventional methods, well as an evaluation unit, are difficult to accurately predict production capacity of each fracture and productivity differences between wells with a different number of fractures. Thus, a single fracture sets the minimum evaluation unit, matrix, fractures, and lateral wellbore model that are then combined integrally to approximate horizontal well with multiple transverse hydraulic fractures in tight gas reservoirs. This paper presents a new semi-analytical methodology for predicting the production capacity of a horizontal well with multiple transverse hydraulic fractures in tight gas reservoirs. Firstly, a mathematical flow model used as a medium, which is disturbed by finite conductivity vertical fractures and rectangular shaped boundaries, is established and explained by the Fourier integral transform. Then the idea of a single stage fracture analysis is incorporated to establish linear flow model within a single fracture with a variable rate. The Fredholm integral numerical solution is applicable for the fracture conductivity function. Finally, the pipe flow model along the lateral wellbore is adapted to couple multi-stages fracture mathematical models, and the equation group of predicting productivity of a multi-stage fractured horizontal well. The whole flow process from the matrix to bottom-hole and production interference between adjacent fractures is also established. Meanwhile, the corresponding iterative algorithm of the equations is given. In this case analysis, the productions of each well and fracture are calculated under the different bottom-hole flowing pressure, and this method also contributes to obtaining the distribution of pressure drop and production for every

Multi-zone coupling productivity of horizontal well fracturing with complex fracture networks in shale gas reservoirs

Directory of Open Access Journals (Sweden)

Weiyao Zhu

2018-02-01

Full Text Available In this paper, a series of specific studies were carried out to investigate the complex form of fracture networks and figure out the multi-scale flowing laws of nano/micro pores–complex fracture networks–wellbore during the development of shale reservoirs by means of horizontal well fracturing. First, hydraulic fractures were induced by means of Brazilian splitting tests. Second, the forms of the hydraulic fractures inside the rock samples were observed by means of X-ray CT scanning to measure the opening of hydraulic fractures. Third, based on the multi-scale unified flowing model, morphological description of fractures and gas flowing mechanism in the matrix–complex fracture network–wellbore, the productivity equation of single-stage horizontal well fracturing which includes diffusion, slipping and desorption was established. And fourthly, a productivity prediction model of horizontal well multi-stage fracturing in the shale reservoir was established considering the interference between the multi-stage fracturing zones and the pressure drop in the horizontal wellbore. The following results were obtained. First, hydraulic fractures are in the form of a complex network. Second, the measured opening of hydraulic fractures is in the range of 4.25–453 μm, averaging 112 μm. Third, shale gas flowing in different shapes of fracture networks follows different nonlinear flowing laws. Forth, as the fracture density in the strongly stimulated zones rises and the distribution range of the hydraulic fractures in strongly/weakly stimulated zones enlarges, gas production increases gradually. As the interference occurs in the flowing zones of fracture networks between fractured sections, the increasing amplitude of gas production rates decreases. Fifth, when the length of a simulated horizontal well is 1500 m and the half length of a fracture network in the strongly stimulated zone is 100 m, the productivity effect of stage 10 fracturing is the

Seismic Characterization and Continuity Analysis of Gas Hydrate Horizons Near the Mallik Research Wells, Mackenzie Delta, Canada

Science.gov (United States)

Bellefleur, G.; Riedel, M.; Brent, T.

2005-12-01

Gas hydrate deposits in arctic environment generally lack the BSR signature diagnostic of their presence in marine seismic data. The absence of the BSR signature complicates the estimation of the resources within or below the permafrost and the determination of their potential impact on future energy supplies, geohazard and climate change. We present results from a detailed seismic characterization of three gas hydrate horizons (A, B and C) intersected below the permafrost in five wells of the Mallik gas hydrate field located in the Mackenzie delta (Northwest Territories, Canada). The detailed seismic characterization included attribute analyses, synthetic modeling and acoustic impedance inversion and allowed estimation of the lateral continuity of the three horizons in the vicinity of the wells. Vertical Seismic Profiling (VSP) data, 3D and 2D industry seismic data and the 5L/2L-38 geophysical logs (density, P-wave sonic velocity) were used for this study. Synthetic modeling using the sonic and density logs reveals that the base of the lower gas hydrate horizons B and C can be identified on the industry 3D and 2D seismic sections as prominent isolated reflections. The uppermost gas hydrate occurrence (horizon A) and potentially other additional smaller-scale layers are identified only on the higher-resolution VSP data. The 3D industry seismic data set processed to preserve the relative true-amplitudes was used for attribute calculations and acoustic impedance inversion. The attribute maps defined areas of continuous reflectivity for horizons B and C and structural features disrupting them. Results from impedance inversion indicate that such continuous reflectivity around the wells is most likely attributable to gas hydrates. The middle gas hydrate occurrence (horizon B) covers an area of approximately 25 000m2. Horizon C, which marks the base of gas hydrate occurrence zone, extends over a larger area of approximately 120 000m2.

Construction of Shale Gas Well

Science.gov (United States)

Sapińska-Śliwa, Aneta; Wiśniowski, Rafał; Skrzypaszek, Krzysztof

2018-03-01

The paper describes shale gas borehole axes trajectories (vertical, horizontal, multilateral). The methodology of trajectory design in a two-and three-dimensional space has been developed. The selection of the profile type of the trajectory axes of the directional borehole depends on the technical and technological possibilities of its implementation and the results of a comprehensive economic analysis of the availability and development of the field. The work assumes the possibility of a multivariate design of trajectories depending on the accepted (available or imposed) input data.

Temperature control of thermal-gas-dynamical installation in cleaning oil-well tubes

Science.gov (United States)

Penner, V. A.; Martemyanov, D. B.; Pshenichnikova, V. V.

2017-08-01

The article provides the study results of cleaning oil-well tubes, the oil-well tube failure reasons for service by their types have been considered. The chemical method of cleaning oil-well tubes as the least expensive has been reviewed when acid solution moves to the interptube space mixing up with oil and liquidates paraffin and pitches deposits on the internal pipe surface. Except the chemical method of pipes cleaning the mechanical one was considered as well. Also the disadvantages -such as the low productivity of cleaning and design complexity- of this deposits removal method on the internal oil-well tube surface have been considered. An effective method for cleaning oil-well tubing from paraffin and pitches by the thermodynamic plant based on the aircraft engine has been introduced for the first time. The temperature distribution graph in the gas stream at the engine output has been given.

Arrangement for improving the strength of the bottom zones of gas wells

Energy Technology Data Exchange (ETDEWEB)

Tsaiger, M.A.; Ogneva, N.E.; Kogan, N.N.

1965-04-19

An arrangement for strengthening the incompetent zones of gas wells is based on phenol-formaldehyde resin and a catalyst (benzo-sulfo-acid). For increasing the stability of the formation without lowering its permeability, a preparation is injected into the formation which consists of 70-80% of resin and 20-30% of a water solution of benzo-sulfo-acid of 40-50% concentration.

Amount of gas hydrate estimated from compressional- and shear-wave velocities at the JAPEX/JNOC/GSC Mallik 2L-38 gas hydrate research well

Science.gov (United States)

Lee, M.W.

1999-01-01

The amount of in situ gas hydrate concentrated in the sediment pore space at the JAPEX/JNOC/GSC Mallik 2L-38 gas hydrate research well was estimated by using compressional-wave (P-wave) and shear-wave (S-wave) downhole log measurements. A weighted equation developed for relating the amount of gas hydrate concentrated in the pore space of unconsolidated sediments to the increase of seismic velocities was applied to the acoustic logs with porosities derived from the formation density log. A weight of 1.56 (W=1.56) and the exponent of 1 (n=1) provided consistent estimates of gas hydrate concentration from the S-wave and the P-wave logs. Gas hydrate concentration is as much as 80% in the pore spaces, and the average gas hydrate concentration within the gas-hydrate-bearing section from 897 m to 1110 m (excluding zones where there is no gas hydrate) was calculated at 39.0% when using P-wave data and 37.8% when using S-wave data.

Application of zipper-fracturing of horizontal cluster wells in the Changning shale gas pilot zone, Sichuan Basin

Directory of Open Access Journals (Sweden)

Bin Qian

2015-03-01

Full Text Available After several years of exploration practices in the Changning-Weiyuan national shale gas pilot zone, the industrial production has been achieved in a number of vertical and horizontal wells completed by SRV fracturing, and a series of independent shale gas reservoir stimulation technologies have come into being. Next, it is necessary to consider how to enhance the efficiency of fracturing by a factory-mode operation. This paper presents the deployment of Changning Well Pad A, the first cluster horizontal shale gas well group, and proposes the optimal design for the factory operation mode of this Pad according to the requirements of wellpad fracturing stimulation technologies and the mountainous landform in the Sichuan Basin. Accordingly, a zipper-fracturing mode was firstly adopted in the factory fracturing on wellpad. With the application of standardized field process, zipper operation, assembly line work, staggered placement of downhole fractures, and microseismic monitoring in real time, the speed of fracturing reached 3.16 stages a day on average, and the stimulated reservoir volume was maximized, which has fully revealed how the factory operation mode contributes to the large-scale SRV fracturing of horizontal shale gas cluster wells on wellpads in the aspect of speed and efficiency. Moreover, the fracturing process, operation mode, surface facilities and post-fracturing preliminary evaluation of the zipper-fracturing in the well group were examined comprehensively. It is concluded from the practice that the zipper-fracturing in the two wells enhanced the efficiency by 78% and stimulated reservoir volume by 50% compared with the single-well fracturing at the preliminary stage in this area.

Combination gas-producing and waste-water disposal well. [DOE patent application

Science.gov (United States)

Malinchak, R.M.

1981-09-03

The present invention is directed to a waste-water disposal system for use in a gas recovery well penetrating a subterranean water-containing and methane gas-bearing coal formation. A cased bore hole penetrates the coal formation and extends downwardly therefrom into a further earth formation which has sufficient permeability to absorb the waste water entering the borehole from the coal formation. Pump means are disposed in the casing below the coal formation for pumping the water through a main conduit towards the water-absorbing earth formation. A barrier or water plug is disposed about the main conduit to prevent water flow through the casing except for through the main conduit. Bypass conduits disposed above the barrier communicate with the main conduit to provide an unpumped flow of water to the water-absorbing earth formation. One-way valves are in the main conduit and in the bypass conduits to provide flow of water therethrough only in the direction towards the water-absorbing earth formation.

Prediction of critical transport velocity for preventing sand deposition in gas-oil multiphase production and well systems

Energy Technology Data Exchange (ETDEWEB)

Bello, O.O.; Reinicke, K.M. [Technische Univ. Clausthal, Clausthal-Zellerfeld (Germany). Inst. of Petroleum Engineering; Teodoriu, C. [Texas A and M Univ., College Station, TX (United States). Dept. of Petroleum Engineering

2008-10-23

The critical transport velocity is one of the key parameters for gas-oil-sand multiphase production and well system design and safe operation. Existing American Petroleum Institute Recommended Practice 14E (API RP 14E) for the sizing of multiphase flow systems suggests an equation to calculate threshold transport velocity. This equation only considers mixture density and does not account for factors such as fluid properties, gas-liquid flow patterns, sand loading, sand particle size, size distributions, shape factor and density. This work presents an improved computational methodology, which can be applied to estimate the critical transport velocity required to ensure efficient performance of gas-oil-sand multiphase production and well systems. The improved method is based on the modelling of three-phase gas-oil-sand pipe flow physics from first principle. Computations of the critical transport velocities show reasonable agreement with values calculated from mechanistic model (Danielson, 2007) for a relatively wide range of design and operating conditions. Compared with the mechanistic model (Danielson, 2007), the present method has no imposed limitations to the range of applicability. It is also takes into adequate account the effects of operating pressure, flow geometry, sand particle size, size distribution and shape factor, which have considerable influence on the critical transport velocity in gas-oil-sand multiphase production and well systems. (orig.)

Shallow gas incident in 3-ELPS-15D-SPS well; Incidente com shallow gas no poco 3-ELPS-15D-SPS

Energy Technology Data Exchange (ETDEWEB)

Ribeiro, Rubens Fausto [Agencia Nacional do Petroleo, Gas Natural e Biocombustiveis (ANP), Rio de Janeiro, RJ (Brazil)

2004-07-01

One of the concerns during the planning phase of an exploratory offshore well drilling is the possibility of occurrence of a shallow gas accumulation. In spite of being a rare event, taking into account that an event like this can have disastrous consequences, the cares to work with that type of incident cannot be despised. As example, in 2003, during the operations in the extension well 3-ELPS-15D-SPS, it happened the uncontrolled influx of water and gas to the bottom of the sea: the annular space between the 30'' and 13 3/8'' casings was not filled out with cement, allowing the flow from a shallow permeable interval to the bottom of the sea through the wellhead's cement return orifices, generating the need of an corrective action to make the abandonment of the well in accordance with the Regulation of Abandonment of Wells existent in Brazil. This work presents the mechanical conditions of the interval close to the wet wellhead of the 3-ELPS-15D-SPS, enumerating the sequence of operations accomplished to solve the problem. (author)

Successful well test application of portable multi-phase flow meter for high gas-volume and high water-cut wells in east Kalimantan, Indonesia

Energy Technology Data Exchange (ETDEWEB)

Kaura, Jiten D.; Finley, D.B. [PT Halliburton Indonesia, Jakarta (Indonesia); Sudradjat, Wangsa; Riyanto, Latief [Tota E and P Indonesie, Jakarta (Indonesia); Halverson, Martin [FlowSys AS, Bergen (Norway)

2004-07-01

Recently, testing was needed on production wells in East Kalimantan. The wells were in a mature field, and productivity from the wells field featured high water cut (WC) and extremely high gas-volume fractions (GVF). The WC and GVF ranged from 80 to 100% and 90 to 100%, respectively. Moreover, most of the wells are low productivity so they are very sensitive to back-pressure. The high WC, high GVF and low-productivity from these wells in this area present an extreme challenge for accurate production measurement. Barges are commonly used to perform well services in the swamp area of this marginal field, and production allocations from wells in this difficult area were previously monitored and measured with conventional well-test equipment on-board a well testing barge. The well test equipment traditionally used requires a large footprint, and the associated flaring presents an environmental situation in this sensitive swamp area. Hence, the MPFM solution was chosen. To better meet the challenges presented by the testing conditions, a portable multiphase flow meter (MPFM) was chosen to perform the testing from the well-testing barge. For comparative purposes, the MPFM was installed on the barge immediately upstream of the well testing equipment. Initial measurements with the MPFM yielded results that were {+-} 30% of the test separator reading. A slight modification was introduced to the MPFM system in the form of a gas knock-out (GKO) vessel. Subsequent measurements with the modified MPFM system yielded readings that were {+-}10% of the test separator reading. (author)

Influence of heat exchange of reservoir with rocks on hot gas injection via a single well

Science.gov (United States)

Nikolaev, Vladimir E.; Ivanov, Gavril I.

2017-11-01

In the computational experiment the influence of heat exchange through top and bottom of the gas-bearing reservoir on the dynamics of temperature and pressure fields during hot gas injection via a single well is investigated. The experiment was carried out within the framework of modified mathematical model of non-isothermal real gas filtration, obtained from the energy and mass conservation laws and the Darcy law. The physical and caloric equations of state together with the Newton-Riemann law of heat exchange of gas reservoir with surrounding rocks, are used as closing relations. It is shown that the influence of the heat exchange with environment on temperature field of the gas-bearing reservoir is localized in a narrow zone near its top and bottom, though the size of this zone is increased with time.

Auxiliary units for refining of high nitrogen content oils: Premium II refinery case

Energy Technology Data Exchange (ETDEWEB)

Nicolato, Paolo Contim; Pinotti, Rafael [Petroleo Brasileiro S.A. (PETROBRAS), Rio de Janeiro, RJ (Brazil)

2012-07-01

PETROBRAS is constantly investing on its refining park in order to increase the production of clean and stable fuels and to be capable to process heavier oils with high contaminants content. Sulfur and nitrogen are the main heteroatoms present in petroleum. They are responsible for some undesirable fuels properties like corrosivity and instability, and also emit pollutants when burnt. Hydrotreating and hydrocracking processes are designed to remove these contaminants and adjust other fuel properties, generating, as byproduct, sour gases and sour water streams rich in H{sub 2}S and NH{sub 3}, which are usually sent to Sour Water Treatment Units and Sulfur Recovery Units. The regeneration of the amine used for the light streams treatment, as fuel gas and LPG, also generates sour gas streams that must be also sent to Sulfur Recovery Units. As the ammonia content in the sour streams increases, some design parameters must be adjusted to avoid increasing the Refinery emissions. Sulfur Recovery Units must provide proper NH3 destruction. Sour Water Treatment must have a proper segregation between H{sub 2}S and ammonia streams, whenever desirable. Amine Regeneration Systems must have an efficient procedure to avoid the ammonia concentration in the amine solution. This paper presents some solutions usually applied to the Petroleum Industry and analyses some aspects related to Premium II Refinery Project and how its design will help the Brazilian refining park to meet future environmental regulation and market demands. (author)

Research and field tests of staged fracturing technology for casing deformation sections in horizontal shale gas wells

Directory of Open Access Journals (Sweden)

Shimeng Liao

2018-02-01

Full Text Available Horizontal shale gas well fracturing is mostly carried out by pumping bridge plugs. In the case of casing deformation, the bridge plug can not be pumped down to the designated position, so the hole sections below the deformation could not be stimulated according to the design program. About 30% of horizontal shale gas wells in the Changning and Weiyuan Blocks, Sichuan Basin, suffer various casing deformation after fracturing. Previously, the hole sections which could not be stimulated due to casing deformation were generally abandoned. As a result, the resources controlled by shale gas wells weren't exploited effectively and the fracturing effect was impacted greatly. There are a lot of difficulties in investigating casing deformation, such as complex mechanisms, various influencing factors and unpredictable deformation time. Therefore, it is especially important to seek a staged fracturing technology suitable for the casing deformation sections. In this paper, the staged fracturing technology with sand plugs inside fractures and the staged fracturing technology with temporary plugging balls were tested in casing deformation wells. The staged fracturing technology with sand plugs inside fractures was carried out in the mode of single-stage perforation and single-stage fracturing. The staged fracturing technology with temporary plugging balls was conducted in the mode of single perforation, continuous fracturing and staged ball dropping. Then, two kinds of technologies were compared in terms of their advantages and disadvantages. Finally, they were tested on site. According to the pressure response, the pressure monitoring of the adjacent wells and the microseismic monitoring in the process of actual fracturing, both technologies are effective in the stimulation of the casing deformation sections, realizing well control reserves efficiently and guaranteeing fracturing effects. Keywords: Shale gas, Horizontal well, Casing deformation, Staged

Overview of the science activities for the 2002 Mallik gas hydrate production research well program, Mackenzie Delta, N.W.T., Canada

Science.gov (United States)

Dallimore, S. R.; Collett, T. S.; Uchida, T.; Weber, M.

2003-04-01

With the completion of scientific studies undertaken as part of the 1998 Mallik 2L-38 gas hydrate research well, an international research site was established for the study of Arctic natural gas hydrates in the Mackenzie Delta of northwestern Canada. Quantitative well log analysis and core studies reveal multiple gas hydrate layers from 890 m to 1106 m depth, exceeding 110 m in total thickness. High gas hydrate saturation values, which in some cases exceed 80% of the pore volume, establish the Mallik gas hydrate field as one of the most concentrated gas hydrate reservoirs in the world. Beginning in December 2001 and continuing to the middle of March 2002, two 1188 m deep science observation wells were drilled and instrumented and a 1166 m deep production research well program was carried out. The program participants include 8 partners; The Geological Survey of Canada (GSC), The Japan National Oil Corporation (JNOC), GeoForschungsZentrum Potsdam (GFZ), United States Geological Survey (USGS), United States Department of the Energy (USDOE), India Ministry of Petroleum and Natural Gas (MOPNG)/Gas Authority of India (GAIL) and the Chevron-BP-Burlington joint venture group. In addition the project has been accepted as part of the International Scientific Continental Drilling Program. The Geological Survey of Canada is coordinating the science program for the project and JAPEX Canada Ltd. acted as the designated operator for the fieldwork. Primary objectives of the research program are to advance fundamental geological, geophysical and geochemical studies of the Mallik gas hydrate field and to undertake advanced production testing of a concentrated gas hydrate reservoir. Full-scale field experiments in the production well monitored the physical behavior of the hydrate deposits in response to depressurization and thermal stimulation. The observation wells facilitated cross-hole tomography and vertical seismic profile experiments (before and after production) as well as

Cloning, Expression, and Characterization of Sorbitol Transporters from Developing Sour Cherry Fruit and Leaf Sink Tissues1

Science.gov (United States)

Gao, Zhifang; Maurousset, Laurence; Lemoine, Remi; Yoo, Sang-Dong; van Nocker, Steven; Loescher, Wayne

2003-01-01

The acyclic polyol sorbitol is a primary photosynthetic product and the principal photosynthetic transport substance in many economically important members of the family Rosaceace (e.g. almond [Prunus dulcis (P. Mill.) D.A. Webber], apple [Malus pumila P. Mill.], cherry [Prunus spp.], peach [Prunus persica L. Batsch], and pear [Pyrus communis]). To understand key steps in long-distance transport and particularly partitioning and accumulation of sorbitol in sink tissues, we have cloned two sorbitol transporter genes (PcSOT1 and PcSOT2) from sour cherry (Prunus cerasus) fruit tissues that accumulate large quantities of sorbitol. Sorbitol uptake activities and other characteristics were measured by heterologous expression of PcSOT1 and PcSOT2 in yeast (Saccharomyces cerevisiae). Both genes encode proton-dependent, sorbitol-specific transporters with similar affinities (Km sorbitol of 0.81 mm for PcSOT1 and 0.64 mm for PcSOT2). Analyses of gene expression of these transporters, however, suggest different roles during leaf and fruit development. PcSOT1 is expressed throughout fruit development, but especially when growth and sorbitol accumulation rates are highest. In leaves, PcSOT1 expression is highest in young, expanding tissues, but substantially less in mature leaves. In contrast, PcSOT2 is mainly expressed only early in fruit development and not in leaves. Compositional analyses suggest that transport mediated by PcSOT1 and PcSOT2 plays a major role in sorbitol and dry matter accumulation in sour cherry fruits. Presence of these transporters and the high fruit sorbitol concentrations suggest that there is an apoplastic step during phloem unloading and accumulation in these sink tissues. Expression of PcSOT1 in young leaves before completion of the transition from sink to source is further evidence for a role in determining sink activity. PMID:12692316

Mobil Oil Canada annual progress report to the Voluntary Challenge and Registry Program 1998

International Nuclear Information System (INIS)

1998-10-01

Mobil Oil Canada has prepared estimates of its emissions of major greenhouse gases for the years 1994, 1995, 1996 and 1997. While the Voluntary Challenge and Registry (VCR) encouraged an inventory of emissions for 1990 to the present, data are not present for earlier than 1994. An inventory summary is included that outlines the quantity of emissions due to the following sources for each facility: combustion of fuel gas for heaters, boilers and compressors, flaring and venting of natural gas, and consumption of coal generated electricity. For all Mobil operated facilities in 1997, GHG emissions existed in the following fractions: 43% due to fuel gas use, 42% due to gas flaring and venting, and 15% from electricity consumption. In 1996, emissions were more evenly distributed amongst the three major sources. A discussion is included of emissions produced and energy used by each process type with data shown in tables. This includes: heavy oil facilities, light oil facilities, sulfur recovery facilities, a sour gas facility, a sweet gas facility, and a thermal heavy oil facility. Various projects were undertaken at each Mobil operated facility to increase energy efficiency and reduce emissions. A summary of the fuel gas, electricity and emission savings for each facility is described, as well as the main actions responsible for each emission saving. These cover: light oil facilities, sulfur recovery facilities, a thermal heavy oil facility, a conventional heavy oil facility, a sweet gas facility, and a sour gas facility. 5 tabs., 9 figs

Real-time electronic monitoring of a pitted and leaking gas gathering pipeline

Energy Technology Data Exchange (ETDEWEB)

Asperger, R.G.; Hewitt, P.G.

1986-08-01

Hydrogen patch, flush electrical resistance, and flush linear polarization proves wre used with flush coupons to monitor corrosion rates in a pitted and leaking sour gas gathering line. Four inhibitors were evaluated in stopping the leaks. Inhibitor residuals and the amount and ratio of water and condensate in the lines were measured at five locations along the line. The best inhibitor reduced reduced the pit-leak frequency by over a factor of 10. Inhibitor usage rate was optimized using the hydrogen patch current as a measure of the instantaneous corrosion rate. Improper pigging was identified as a cause of corrosion transients. This problem is discussed in relation to the pigging of pipelines in stratified flow where moving fluids are the carriers for continuously injected corrosion inhibitors.

Engineering critical assessment of PETROBRAS Camarupim pipeline

Energy Technology Data Exchange (ETDEWEB)

Gordon, J.R. [Microalloying International, Houston, TX (United States); Gatlin, R.W. [Global Industries, Rio de Janeiro, RJ (Brazil); Zumpano Junior, P.; Kaspary, T. [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil)

2009-12-19

This paper presents details of an Engineering Critical Assessment (ECA) performed to develop girth weld flaw acceptance criteria for the PETROBRAS Camarupim Pipeline which was installed in Espirito Santo Basin, ES, offshore Brazil in May 2008 by Global Industries. The pipeline was constructed using 24-inch diameter API Grade X65 pipe with wall thicknesses of 0.875-inch (22.2 mm) and 1.00 inch (25.4 mm). Although the Camarupim pipeline will initially transport sweet gas there is the potential for mildly sour service operation in mid to late life. To assess the effect of sour service on the material toughness properties a series of slow strain rate fracture toughness tests were performed in a Project representative sour service environment. In addition the results of sour service fatigue crack growth tests were analyzed to develop a conservative sour service fatigue crack growth law for the ECA analysis. (author)

MODELLING AND ANALYSIS OF TOWER INTERVENTION EQUIPMENT OF OIL & GAS WELLS

Directory of Open Access Journals (Sweden)

César A. Chagoyén-Méndez

2015-04-01

Full Text Available In this paper, the modeling and analysis of one tower Workover Rig belonging to a maintenance facility for oil and gas wells is presented. When performing the maintenance of this tower, it is detected that one of the elements of the structure has some deformation. It was decided not to put it into operation and submit it to research. The modeling of invariants as well as ways of modeling soil structure interaction is discussed. It was necessary to determine the material properties with the performing of test of some samples taken on two components of the tower. The structural behavior of the tower to operating loads are then studied, proving that the effect of the deformed element in the structure is not significant for the stresses to which are subject.

A preliminary assessment of the radiological implications of commercial utilization of natural gas from a nuclearly stimulated well

Energy Technology Data Exchange (ETDEWEB)

Jacobs, D G; Struxness, E G [Health Physics Division, Oak Ridge National Laboratory, Oak Ridge, TN (United States); Bowman, C R [El Paso Natural Gas Company, El Paso, TX (United States)

1970-05-01

Widespread utilization of nuclear explosives, in conjunction with the natural gas industry, can result in radiation exposure of sizable population groups. It is prudent to make realistic assessments of such potential radiation exposures before they occur and, unless the expected exposures are clearly insignificant, to consider these exposures in evaluating the net benefit of this particular use of nuclear energy. All pertinent facts relating to such assessments should be made public and presented in such a way that those who are to assume the risks, if any, can make a reasonable judgment as to whether the risks are acceptable. Radioactivity in natural gas from the Gasbuggy cavity has been analyzed prior to and during flaring operations. None of this gas has entered the collection and distribution system, but a theoretical analysis has been made of the hypothetical impact on members of the public that would have occurred if the gas had been introduced into the commercial stream. Dose equivalents have been estimated for both workers and consumers. In this analysis, Gasbuggy gas has been traced through a real gas-collection system and processing plant, as represented by the present situation existing in the San Juan Production Division, El Paso Natural Gas Company. In addition, a number of considerations are presented which would apply to radiation exposure in metropolitan areas. Results of this analysis for the Gasbuggy well indicate hypothetical dose equivalents to various population groups to be well within the annual dose limits suggested by the International Commission on Radiological Protection. Projection to a steady-state situation involving extensive natural gas production from many producing wells also resulted in hypothetical dose equivalents within the annual dose limits. Simple extrapolation of the results from this analysis to potential exposures resulting from nuclear stimulation of other gas reservoirs cannot be made on a direct basis, but this method

A preliminary assessment of the radiological implications of commercial utilization of natural gas from a nuclearly stimulated well

International Nuclear Information System (INIS)

Jacobs, D.G.; Struxness, E.G.; Bowman, C.R.

1970-01-01

Widespread utilization of nuclear explosives, in conjunction with the natural gas industry, can result in radiation exposure of sizable population groups. It is prudent to make realistic assessments of such potential radiation exposures before they occur and, unless the expected exposures are clearly insignificant, to consider these exposures in evaluating the net benefit of this particular use of nuclear energy. All pertinent facts relating to such assessments should be made public and presented in such a way that those who are to assume the risks, if any, can make a reasonable judgment as to whether the risks are acceptable. Radioactivity in natural gas from the Gasbuggy cavity has been analyzed prior to and during flaring operations. None of this gas has entered the collection and distribution system, but a theoretical analysis has been made of the hypothetical impact on members of the public that would have occurred if the gas had been introduced into the commercial stream. Dose equivalents have been estimated for both workers and consumers. In this analysis, Gasbuggy gas has been traced through a real gas-collection system and processing plant, as represented by the present situation existing in the San Juan Production Division, El Paso Natural Gas Company. In addition, a number of considerations are presented which would apply to radiation exposure in metropolitan areas. Results of this analysis for the Gasbuggy well indicate hypothetical dose equivalents to various population groups to be well within the annual dose limits suggested by the International Commission on Radiological Protection. Projection to a steady-state situation involving extensive natural gas production from many producing wells also resulted in hypothetical dose equivalents within the annual dose limits. Simple extrapolation of the results from this analysis to potential exposures resulting from nuclear stimulation of other gas reservoirs cannot be made on a direct basis, but this method

Gas prices deregulation: how to play the game well?

International Nuclear Information System (INIS)

Petitot, Pauline

2014-01-01

At the instigation of the European Union and in a context of increasing deregulation, the end of regulated gas prices in France is coming soon. Suppliers and consumers concerned are actively preparing themselves to take the turn of gas market liberalization. This short paper reveals their strategies

Literature review of acid forming emissions in livestock

International Nuclear Information System (INIS)

Prior, M.G.; Lopez, A.

1992-01-01

A review is presented of the effects of acid forming emissions such as sulfur and nitrogen oxides in livestock. Topics discussed include uptake of airborne pollutants, types of acid-forming pollutants, sources of sulfur-containing emissions, sour gas, and farm animal toxicity caused by carbon disulfide, carbonyl sulfide, ethyl sulfide, methyl sulfide, hydrogen sulfide, methylmercaptan, ethylmercaptan, propylmercaptan, nitrogen oxides, ozone, sulfur, and sulfur dioxide. A review is presented of field data including effects of emissions from gas plants, gas well blowouts, animal nutrition in west central Alberta, and experimental studies on goats and cows. 96 refs., 10 tabs

Biocide and corrosion inhibition use in the oil and gas industry: Effectiveness and potential environmental impacts

International Nuclear Information System (INIS)

Brandon, D.M.; Fillo, J.P.; Morris, A.E.; Evans, J.M.

1995-01-01

Treatment chemicals are used in all facets of the natural gas industry (NGI) from well development through transmission and storage of natural gas. The multitude of chemicals used, combined with the dozens of chemical manufacturers and/or suppliers has lead to the availability of hundreds of possible chemical products. Because of the widespread use of chemical products and their numerous sources, the NGI needs access to consistent data regarding their effectiveness and potential environmental impacts. The objective of this work was to evaluate the effectiveness and potential environmental impacts of, chemical products used in the NGI. This assessment was initially focused on biocides and corrosion inhibitors and their use in the gas production, storage and transmission facilities, The overall approach was obtain the necessary data on chemical use and effectiveness directly from the oil and gas industry, supplemented with data/information obtained from the published literature. Five case histories of chemical use were documented and evaluated to assess the effectiveness of these chemicals. Potential environmental impacts were addressed by performing a screening environmental assessment on the use of glutaraldehyde, a widely used biocide. Prototype discharge scenarios were formulated and modeled to evaluate potential impacts to groundwater and surface water. The paper describes the basis for the study, provides an overview of chemical use with a focus on biocides and corrosion inhibitors, describes and assesses the specific uses of chemicals, and presents the results of the environmental assessment. It was found that various chemicals can be effective in treating microbiologically influenced corrosion and souring, but that the effectiveness of specific chemicals is dependent on the operational scenario and the site-specific conditions

Mount Elbert Gas Hydrate Stratigraphic Test Well, Alaska North Slope: Coring operations, core sedimentology, and lithostratigraphy

Science.gov (United States)

Rose, K.; Boswell, R.; Collett, T.

2011-01-01

In February 2007, BP Exploration (Alaska), the U.S. Department of Energy, and the U.S. Geological Survey completed the BPXA-DOE-USGS Mount Elbert Gas Hydrate Stratigraphic Test Well (Mount Elbert well) in the Milne Point Unit on the Alaska North Slope. The program achieved its primary goals of validating the pre-drill estimates of gas hydrate occurrence and thickness based on 3-D seismic interpretations and wireline log correlations and collecting a comprehensive suite of logging, coring, and pressure testing data. The upper section of the Mount Elbert well was drilled through the base of ice-bearing permafrost to a casing point of 594??m (1950??ft), approximately 15??m (50??ft) above the top of the targeted reservoir interval. The lower portion of the well was continuously cored from 606??m (1987??ft) to 760??m (2494??ft) and drilled to a total depth of 914??m. Ice-bearing permafrost extends to a depth of roughly 536??m and the base of gas hydrate stability is interpreted to extend to a depth of 870??m. Coring through the targeted gas hydrate bearing reservoirs was completed using a wireline-retrievable system. The coring program achieved 85% recovery of 7.6??cm (3??in) diameter core through 154??m (504??ft) of the hole. An onsite team processed the cores, collecting and preserving approximately 250 sub-samples for analyses of pore water geochemistry, microbiology, gas chemistry, petrophysical analysis, and thermal and physical properties. Eleven samples were immediately transferred to either methane-charged pressure vessels or liquid nitrogen for future study of the preserved gas hydrate. Additional offsite sampling, analyses, and detailed description of the cores were also conducted. Based on this work, one lithostratigraphic unit with eight subunits was identified across the cored interval. Subunits II and Va comprise the majority of the reservoir facies and are dominantly very fine to fine, moderately sorted, quartz, feldspar, and lithic fragment-bearing to

Un simulateur de production de puits exploité en gas-lift A Production Simulator for Gas-Lift Wells

Directory of Open Access Journals (Sweden)

Caralp L.

2006-11-01

Full Text Available Le procédé d'exploitation assisté de pétrole par gas-lift " est utilisé dans les applications off-shore. Sa dynamique lente nuit à la réalisation in situ d'études de conditions d'exploitation optimales. Si l'on veut apprendre à conduire ce type de procédé ou optimiser les conditions d'exploitation sur un ensemble de puits, disposer d'un logiciel de simulation est une nécessité. Réalisé à partir des modèles de connaissance : - d'écoulement diphasique incluant le taux de gaz dans les bouchons d'huile (régime poches-bouchons et les échanges de masse entre phases; - de gisement; - de l'injection de gaz; le simulateur, qui emploie les corrélations les plus fréquemment utilisées décrivant les mélanges huile-gaz, fournit des résultats physiquement acceptables qui sont présentés. Le processus est non linéaire et asymétrique. Help oil well process by gas-liftare use in off shore application. Slow dynamic is an handicap for a study of optimal exploitation conditions. To learn to drive this process and to optimize exploitation conditions on an oil field it is necessary to set of a simulator. It is realized from knowledge models :(a two-phases flows, (b oil pool,(c gaz injection, including gas rate in oil slug (slug regime and mass exchange into phases. The simulator work with the most commonly use oil-gas mixture correlations. This results are physically reasonable. Process is non linear and asymetrical.

Advanced oxidation processes for treatment of petroleum refinery sour waters; Processos oxidativos avancados para tratamento de aguas acidas de refinaria de petroleo

Energy Technology Data Exchange (ETDEWEB)

Castro, Antonio V.; Coelho, Alessandra D.; Sant' Anna Junior, Geraldo L.; Dezotti, Marcia [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Coordenacao dos Programas de Pos-graduacao de Engenharia (COPPE). Programa de Engenharia Quimica

2004-07-01

The characteristics of the waste water generated by the petroleum refineries are related to the type and amount of processed oil, to the nature and the efficiency of the refining operation. The effluents are composed basically of oily waters, originating from of the contact with the oil. Among them, the current of sour water is one of the most preoccupying due to its composition: sulfide, ammonia, mercaptans, phenol, dissolved oil, basic pH, dissolved organic carbon (DOC) and chemical oxygen demand (COD) high. The aim of this work was to evaluate the advanced oxidation processes to degrade sour water (UV radiation, H{sub 2}O{sub 2} and H{sub 2}O{sub 2}/UV, photocatalysis, Fenton and photo-Fenton). All process, except Fenton and photo-Fenton, did not supply satisfactory results, reducing 25% of initial DOC, which it is of 450 mg/L. The results using the Fenton process reached removal of 50% of the initial COD, and when photo- Fenton process obtaining removal of 90%. The processes Fenton and photo-Fenton were shown capable to degrade this kind of waste water, minimizing the environmental problems and corrosion, operating as a pre-treatment for the biological system, or acting alone to degrade the organic matter contained, seeking the water reuse. The effluent used in this work came from Duque de Caxias Refinery (Reduc)/PETROBRAS. (author)

Physical properties of sediments from the JAPEX/JNOC/GSC Mallik 2L-38 gas hydrate research well

Science.gov (United States)

Winters, W.J.

1999-01-01

A 1150 m deep gas hydrate research well was drilled in the Canadian Arctic in February and March 1998 to investigate the interaction between the presence of gas hydrate and the natural conditions presented by the host sediments. Profiles of the following measured and derived properties are presented from that investigation: water content, sediment wet bulk density, grain size, porosity, gas hydrate quantity, and salinity. These data indicate that the greatest concentration of gas hydrate is located within sand and gravel deposits between 897 m and 922 m. American Society for Testing and Materials 1997: Standard test method for specific gravity of soil solids by gas pycnometer D 5550-94; in American Society for Testing and Materials, Annual Book of ASTM Standards, v. 04.09, Soil and Rock, West Conshohocken, Pennsylvania, p. 380-383.

Water Well Locations - Conservation Wells

Data.gov (United States)

NSGIC Education | GIS Inventory — The conservation well layer identifies the permitted surface location of oil and gas conservation wells that have not been plugged. These include active, regulatory...

Natural gas seepage from a dug well in Gemerska Panica

International Nuclear Information System (INIS)

Milicka, J.; Pereszlenyi, M.; Masaryk, P.

1997-01-01

On July 20 1993, a seepage of inflammable natural gas was reported by workers of the Slovak Gas Industry enterprise (SPP) to the Oil and Gas Research and Prospecting (VVNP). Therefore, the locality was visited with the aim to evaluate the current situation, to take rock and water samples for for chemical analysis, to survey the vicinity of Gemerska Panica and to prepare a preliminary oil-geological evaluation of the area, with a suggestion of further prospecting. At the same time, the seepage of inflammable natural gas was reported to the District Mining Office in Spisska Nova Ves. (authors)

Development of compact mutants in apple and sour cherry

International Nuclear Information System (INIS)

Zagaja, S.W.; Przybyla, A.; Machnik, B.

1982-01-01

During the period 1973 - 79 studies were conducted with the aim of developing compact mutants in apple and cherry cultivars and in apple vegetative rootstocks. During the investigations the effect of the dose of gamma rays on frequency of the mutants was studied. Attempts were also made to evolve a micropropagation technique adapted to propagate P 2 and P 22 apple rootstocks, as an aid in mutation breeding. Several mutants were produced in all the material studied, but none of them have yet reached a sufficient developmental stage to enable their complete assessment. On the basis of the results obtained so far the following conclusions can be drawn: higher doses of irradiation resulted in higher frequency of mutants in most apple cultivars and apple rootstocks; in sour cherries the effect of dose depended on the cultivars. Among V 1 shoots developed from sleeping buds on irradiated scion wood, compact mutants were found; their frequency, however, was about 60% lower than among V 1 shoots developed directly from irradiated dormant buds. In apple rootstocks A 2 and M 26 several dwarfed mutants were found; some of these produced thorny plants and some had lower rooting ability; both these characteristics are inferior from the practical point of view. Multiplication and rooting media for in vitro propagation of apple rootstocks, worked out for M 26, were found unsuitable for the rootstocks P 2 and P 22; modifications made in the growth substance composition of the above media enabled satisfactory propagation to be obtained. (author)

Towards a Quantitative Framework for Evaluating Vulnerability of Drinking Water Wells to Contamination from Unconventional Oil & Gas Development

Science.gov (United States)

Soriano, M., Jr.; Deziel, N. C.; Saiers, J. E.

2017-12-01

The rapid expansion of unconventional oil and gas (UO&G) production, made possible by advances in hydraulic fracturing (fracking), has triggered concerns over risks this extraction poses to water resources and public health. Concerns are particularly acute within communities that host UO&G development and rely heavily on shallow aquifers as sources of drinking water. This research aims to develop a quantitative framework to evaluate the vulnerability of drinking water wells to contamination from UO&G activities. The concept of well vulnerability is explored through application of backwards travel time probability modeling to estimate the likelihood that capture zones of drinking water wells circumscribe source locations of UO&G contamination. Sources of UO&G contamination considered in this analysis include gas well pads and documented sites of UO&G wastewater and chemical spills. The modeling approach is illustrated for a portion of Susquehanna County, Pennsylvania, where more than one thousand shale gas wells have been completed since 2005. Data from a network of eight multi-level groundwater monitoring wells installed in the study site in 2015 are used to evaluate the model. The well vulnerability concept is proposed as a physically based quantitative tool for policy-makers dealing with the management of contamination risks of drinking water wells. In particular, the model can be used to identify adequate setback distances of UO&G activities from drinking water wells and other critical receptors.

Strengthening mechanisms and mechanical properties of high interstitial stainless steel for drill collar and its corrosion resistance

Science.gov (United States)

Lee, Eunkyung

Two types (CN66, CN71) of high interstitial stainless steels (HISSs) were investigated for down-hole application in sour gas well environments. Experiments were designed to identify factors that have a significant effect on mechanical properties. The three factors examined in the study were carbon + nitrogen content (0.66 or 0.71 mass %), cooling rate in quenching (air or water), and heat treatment time (2 or 4 hours). The results showed that the cooling rate, C+N content, and the two-factor interaction of these variables have a significant effect on the mechanical properties of HISSs. Based on the statistical analysis results on mechanical properties, extensive analyses were undertaken to understand the strengthening mechanisms of HISSs. Microstructure analysis revealed that a pearlite phase with a high carbide and/or nitride content is dissolved in the matrix by heat treatment at 1,200 ºC which is considered the dissolution to increase the concentration of interstitial elements in steels. The distribution of elements in HISSs was investigated by quantitative mapping using EPMA, which showed that the high carbon concentration (carbide/cementite) area was decreased by increases in both the cooling rate and C+N content. The ferrite volume fraction of each specimen is increased by an increase in cooling rate, because there is insufficient time to form austenite from retained ferrite. The lattice expansion of HISS was investigated by the calculation of lattice parameters under various conditions, and these investigations confirm the solid solution strengthening effect on HISSs. CN66 with heat treatment at fast cooling has the highest wear resistance; a finding that was consistent with hardening mechanisms that occur due to an increased ferrite volume fraction. In addition, precipitates on the surface and the chemical bonding of chromium were investigated. As the amount of CrN bonding increased, the wear resistance also increased. This study also assessed the

REPEATED MEASURES ANALYSIS OF CHANGES IN PHOTOSYNTHETIC EFFICIENCY IN SOUR CHERRY DURING WATER DEFICIT

Directory of Open Access Journals (Sweden)

Marija Viljevac

2012-06-01

Full Text Available The objective of this study was to investigate changes in photosynthetic efficiency applying repeated measures ANOVA using the photosynthetic performance index (PIABS of the JIP-test as a vitality parameter in seven genotypes of sour cherry (Prunus cerasus, L. during 10 days of continuous water deficit. Both univariate and multivariate ANOVA repeated measures revealed highly significant time effect (Days and its subsequent interactions with genotype and water deficit. However, the multivariate Pillai’s trace test detected the interaction Time × Genotype × Water deficit as not significant. According to the Tukey’s Studentized Range (HSD test, differences between the control and genotypes exposed to water stress became significant on the fourth day of the experiment, indicating that the plants on the average, began to lose their photosynthetic efficiency four days after being exposed to water shortage. It corroborates previous findings in other species that PIABS is very sensitive tool for detecting drought stress.

Stress corrosion cracking resistance of 22% Cr duplex stainless steel in simulated sour environments

International Nuclear Information System (INIS)

Kudo, T.; Tsuge, H.; Moroishi, T.

1989-01-01

This paper reports the effect of nickel and nitrogen contents on stress corrosion cracking (SCC) of 22%Cr - 3%Mo-base duplex stainless steel investigated in simulated sour environments with respect to both the base metal and the heat-affected zone (HAZ) of welding. The threshold stress and the critical chloride concentration for SCC were evaluated as a function of the ferrite content (α-content) in the alloy. The threshold stress is highest at the α-content of 40 to 45%, and is lowered with decreasing and increasing the α-content from its value. The alloy whose α-content exceeds 80% at the HAZ has also high susceptibilities to pitting corrosion and intergranular corrosion (ICG). The critical chloride concentration for cracking increases with the decrease in the α-content. Moreover, the contents of chromium, nickel and molybdenum in the α-phase are considered to be an important factor for determining the critical chloride concentration

Drilling and exploitation of petroleum and gas wells. Burenie i ekspluatatsiya neftyanykh i gazovykh skvazhin

Energy Technology Data Exchange (ETDEWEB)

Sidorov, N A

1982-01-01

An examination is made of the methods employed for well drilling, equipment, principal and auxiliary instrumentation. Considerable attention is given drilling systems, well flushing, separation, and exposure of productive seams. Also studied are the prevention and elimination of accidents and complications. A detailed description is given of methods employed for operating wells, including an examination of apparatus and instruments, methods of increasing well productivity, and supporting stratal energy. Considerable attention is given to the collection and transport of petroleum and gas, adn to automation and telemechanization. 16 references, 208 figures, 51 tables.

Calculational techniques for estimating population doses from radioactivity in natural gas from nuclearly stimulated wells

International Nuclear Information System (INIS)

Barton, C.J.; Moore, R.E.; Rohwer, P.S.; Kaye, S.V.

1975-01-01

Techniques for estimating radiation doses from exposure to combustion products of natural gas obtained from wells created by use of nuclear explosives were first developed in the Gasbuggy Project. These techniques were refined and extended by development of a number of computer codes in studies related to the Rulison Project, the second in the series of joint government-industry efforts to demonstrate the feasibility of increasing natural gas production from low-permeability rock formations by use of nuclear explosives. These techniques are described and dose estimates that illustrate their use are given. These dose estimation studies have been primarily theoretical, but we have tried to make our hypothetical exposure conditions correspond as closely as possible with conditions that could exist if nuclearly stimulated natural gas is used commercially. (author)

Upgrade Egyptian biogas to meet the natural gas network quality standard

Directory of Open Access Journals (Sweden)

Sameh Tawfik Abd Elfattah

2016-09-01

Full Text Available Biogas is one of the promising renewable energy sources in Egypt. The objective of this research was to treat the raw biogas in order to clean it from acidic gases CO2 and H2S to meet the standard of the natural gas network. The acidic gases treating plant of the biogas were built up and numerically simulated using Aspen HYSYS 8.6 and a proper design of the plant was performed. The main purpose of the simulation is to determine the optimum working pressure, which can achieve the methane purity of the Egyptian biogas comparable to natural gas quality. The biogas treating process was accomplished inside Pressure Swing Absorber (PSA where the feed sour gas enters the absorber at the CO2 contents of 0.25, H2S contents of 0.0004, a temperature of 30 °C, a pressure of 1.1 bars, a flow rate of 13 m3/h, Diethanolamine (DEA concentration of 0.3 and 20 stages PSA with a tray diameter of 1.7 m. it is found that a PSA working pressure of 5 bars is required to obtain a biogas with methane purity of 95%.

Aqueous extraction of pectin from sour orange peel and its preliminary physicochemical properties.

Science.gov (United States)

Hosseini, Seyed Saeid; Khodaiyan, Faramarz; Yarmand, Mohammad Saeid

2016-01-01

Sour orange peel, a by-product of the fruit juice industry, was used as a source of pectin. The effects of temperature (75-95°C), time (30-90 min), and liquid-solid ratio (20-40, v/w) were investigated on yield, methoxylation degree (DE), and galacturonic acid content using a Box-Behnken design and response surface methodology. The highest extraction yield (17.95 ± 0.3%) was obtained at temperature of 95°C, time of 90 min, and liquid-solid ratio of 25 (v/w). The DE values for the pectin ranged from 17% to 30.5%, indicating that the pectin was low in methoxyle. The emulsifying activity of pectin extracted under optimal conditions was 45%. The emulsions were 86.6% stable at 4°C and 71.4% at 23°C after 30 days of storage. The pectin exhibited Newtonian flow at low concentrations (≤ 1.0%, w/v); as the concentration increased, pseudoplastic flow became dominant. Copyright © 2015 Elsevier B.V. All rights reserved.

Well water contamination in a rural community in southwestern Pennsylvania near unconventional shale gas extraction.

Science.gov (United States)

Alawattegama, Shyama K; Kondratyuk, Tetiana; Krynock, Renee; Bricker, Matthew; Rutter, Jennifer K; Bain, Daniel J; Stolz, John F

2015-01-01

Reports of ground water contamination in a southwestern Pennsylvania community coincided with unconventional shale gas extraction activities that started late 2009. Residents participated in a survey and well water samples were collected and analyzed. Available pre-drill and post-drill water test results and legacy operations (e.g., gas and oil wells, coal mining) were reviewed. Fifty-six of the 143 respondents indicated changes in water quality or quantity while 63 respondents reported no issues. Color change (brown, black, or orange) was the most common (27 households). Well type, when known, was rotary or cable tool, and depths ranged from 19 to 274 m. Chloride, sulfate, nitrate, sodium, calcium, magnesium, iron, manganese and strontium were commonly found, with 25 households exceeding the secondary maximum contaminate level (SMCL) for manganese. Methane was detected in 14 of the 18 houses tested. The 26 wells tested for total coliforms (2 positives) and E. coli (1 positive) indicated that septic contamination was not a factor. Repeated sampling of two wells in close proximity (204 m) but drawing from different depths (32 m and 54 m), revealed temporal variability. Since 2009, 65 horizontal wells were drilled within a 4 km (2.5 mile) radius of the community, each well was stimulated on average with 3.5 million gal of fluids and 3.2 million lbs of proppant. PA DEP cited violations included an improperly plugged well and at least one failed well casing. This study underscores the need for thorough analyses of data, documentation of legacy activity, pre-drill testing, and long term monitoring.

Planning for Higher Oil Prices : Power Sector Impact in Latin America and the Caribbean

OpenAIRE

Yépez-García, Rigoberto Ariel; San Vicente Portes, Luis; García, Luis Enrique

2013-01-01

A scenario with higher oil prices has important implications for diverting from oil-based technologies to renewables, as well as gas, coal, and nuclear alternatives. By 2030, energy demand in Latin America and the Caribbean (LAC) is expected to double from 2008 levels. A key issue is deciding on the most appropriate mix of fuels for power generation, given the various prices of energy sour...

Ghrelin is produced in taste cells and ghrelin receptor null mice show reduced taste responsivity to salty (NaCl and sour (citric acid tastants.

Directory of Open Access Journals (Sweden)

Yu-Kyong Shin

2010-09-01

Full Text Available The gustatory system plays a critical role in determining food preferences, food intake and energy balance. The exact mechanisms that fine tune taste sensitivity are currently poorly defined, but it is clear that numerous factors such as efferent input and specific signal transduction cascades are involved.Using immunohistochemical analyses, we show that ghrelin, a hormone classically considered to be an appetite-regulating hormone, is present within the taste buds of the tongue. Prepro-ghrelin, prohormone convertase 1/3 (PC 1/3, ghrelin, its cognate receptor (GHSR, and ghrelin-O-acyltransferase (GOAT , the enzyme that activates ghrelin are expressed in Type I, II, III and IV taste cells of mouse taste buds. In addition, ghrelin and GHSR co-localize in the same taste cells, suggesting that ghrelin works in an autocrine manner in taste cells. To determine a role for ghrelin in modifying taste perception, we performed taste behavioral tests using GHSR null mice. GHSR null mice exhibited significantly reduced taste responsivity to sour (citric acid and salty (sodium chloride tastants.These findings suggest that ghrelin plays a local modulatory role in determining taste bud signaling and function and could be a novel mechanism for the modulation of salty and sour taste responsivity.

A Resource Assessment Of Geothermal Energy Resources For Converting Deep Gas Wells In Carbonate Strata Into Geothermal Extraction Wells: A Permian Basin Evaluation

Energy Technology Data Exchange (ETDEWEB)

Erdlac, Richard J., Jr.

2006-10-12

Previously conducted preliminary investigations within the deep Delaware and Val Verde sub-basins of the Permian Basin complex documented bottom hole temperatures from oil and gas wells that reach the 120-180C temperature range, and occasionally beyond. With large abundances of subsurface brine water, and known porosity and permeability, the deep carbonate strata of the region possess a good potential for future geothermal power development. This work was designed as a 3-year project to investigate a new, undeveloped geographic region for establishing geothermal energy production focused on electric power generation. Identifying optimum geologic and geographic sites for converting depleted deep gas wells and fields within a carbonate environment into geothermal energy extraction wells was part of the project goals. The importance of this work was to affect the three factors limiting the expansion of geothermal development: distribution, field size and accompanying resource availability, and cost. Historically, power production from geothermal energy has been relegated to shallow heat plumes near active volcanic or geyser activity, or in areas where volcanic rocks still retain heat from their formation. Thus geothermal development is spatially variable and site specific. Additionally, existing geothermal fields are only a few 10’s of square km in size, controlled by the extent of the heat plume and the availability of water for heat movement. This plume radiates heat both vertically as well as laterally into the enclosing country rock. Heat withdrawal at too rapid a rate eventually results in a decrease in electrical power generation as the thermal energy is “mined”. The depletion rate of subsurface heat directly controls the lifetime of geothermal energy production. Finally, the cost of developing deep (greater than 4 km) reservoirs of geothermal energy is perceived as being too costly to justify corporate investment. Thus further development opportunities

A national assessment of underground natural gas storage: identifying wells with designs likely vulnerable to a single-point-of-failure

Science.gov (United States)

Michanowicz, Drew R.; Buonocore, Jonathan J.; Rowland, Sebastian T.; Konschnik, Katherine E.; Goho, Shaun A.; Bernstein, Aaron S.

2017-05-01

The leak of processed natural gas (PNG) from October 2015 to February 2016 from the Aliso Canyon storage facility, near Los Angeles, California, was the largest single accidental release of greenhouse gases in US history. The Interagency Task Force on Natural Gas Storage Safety and California regulators recently recommended operators phase out single-point-of-failure (SPF) well designs. Here, we develop a national dataset of UGS well activity in the continental US to assess regulatory data availability and uncertainty, and to assess the prevalence of certain well design deficiencies including single-point-of-failure designs. We identified 14 138 active UGS wells associated with 317 active UGS facilities in 29 states using regulatory and company data. State-level wellbore datasets contained numerous reporting inconsistencies that limited data concatenation. We identified 2715 active UGS wells across 160 facilities that, like the failed well at Aliso Canyon, predated the storage facility, and therefore were not originally designed for gas storage. The majority (88%) of these repurposed wells are located in OH, MI, PA, NY, and WV. Repurposed wells have a median age of 74 years, and the 2694 repurposed wells constructed prior to 1979 are particularly likely to exhibit design-related deficiencies. An estimated 210 active repurposed wells were constructed before 1917—before cement zonal isolation methods were utilized. These wells are located in OH, PA, NY, and WV and represent the highest priority related to potential design deficiencies that could lead to containment loss. This national baseline assessment identifies regulatory data uncertainties, highlights a potentially widespread vulnerability of the natural gas supply chain, and can aid in prioritization and oversight for high-risk wells and facilities.

Carbon Nanomaterials for Detection, Assessment and Purification of Oil and Natural Gas

Science.gov (United States)

Hwang, Chih-Chau

polymer formation. Once returned to ambient conditions, the poly(CO2) depolymerizes during the pressure swing, leading to a sorbent that can be easily regenerated without the thermal energy input that is required for traditional liquid phase sorbents. The synergy between the nucleophilic centers and the high surface area porous carbon produces a sorbent with high CO2 capacity, selectivity, and volumetric efficiency, so that the materials have potential to be used for CO2 removal from natural gas streams. As energy demand continues to increase, it is desirable to produce as much oil as possible from existing oil wells. Tracers have long been used to map entry/exit well correlations in the oil-field, but they do not provide any information about the environment between the entry and exit locations. Hence, the third part of this thesis will show that nanoparticles possessing functionalized carbon black (fCB) cores and sulfated polyvinyl alcohol (sPVA) addends can be designed to transport hydrocarbon detection molecules through subsurface rock formations. The sPVA-fCBs are stable under high-temperature and salinity conditions and are transported through a variety of oilfield rock types. A non-radioactive probe molecule that is easily detectable by mass spectrometry, triheptylamine (THA), was adsorbed onto the sPVA-fCBs. The THA was selectively released when the nanoparticles were passed through a column of isooctane-containing crushed rock, providing a path to both entry and exit correlations and a measure of oil content. This study simulates detection and quantitative analysis of the hydrocarbon content in downhole rock formations, which is a critically needed assessment in older oilfields. Crude oil is classified as "sour" when it contains a total sulfur content greater than 0.5%. Among these sulfur species, H2S is the one of main impurities in sour crude. The sour crude is toxic and corrosive to the materials of construction in pipelines and other holding and

Isotropic, anisotropic, and borehole washout analyses in Gulf of Mexico Gas Hydrate Joint Industry Project Leg II, Alaminos Canyon well 21-A

Science.gov (United States)

Lee, Myung W.

2012-01-01

Through the use of three-dimensional seismic amplitude mapping, several gas hydrate prospects were identified in the Alaminos Canyon area of the Gulf of Mexico. Two of the prospects were drilled as part of the Gulf of Mexico Gas Hydrate Joint Industry Program Leg II in May 2009, and a suite of logging-while-drilling logs was acquired at each well site. Logging-while-drilling logs at the Alaminos Canyon 21–A site indicate that resistivities of approximately 2 ohm-meter and P-wave velocities of approximately 1.9 kilometers per second were measured in a possible gas-hydrate-bearing target sand interval between 540 and 632 feet below the sea floor. These values are slightly elevated relative to those measured in the hydrate-free sediment surrounding the sands. The initial well log analysis is inconclusive in determining the presence of gas hydrate in the logged sand interval, mainly because large washouts in the target interval degraded well log measurements. To assess gas-hydrate saturations, a method of compensating for the effect of washouts on the resistivity and acoustic velocities is required. To meet this need, a method is presented that models the washed-out portion of the borehole as a vertical layer filled with seawater (drilling fluid). Owing to the anisotropic nature of this geometry, the apparent anisotropic resistivities and velocities caused by the vertical layer are used to correct measured log values. By incorporating the conventional marine seismic data into the well log analysis of the washout-corrected well logs, the gas-hydrate saturation at well site AC21–A was estimated to be in the range of 13 percent. Because gas hydrates in the vertical fractures were observed, anisotropic rock physics models were also applied to estimate gas-hydrate saturations.

Numerical simulation study of fracturing wells for shale gas with gas–water two-phase flow system under desorption and diffusion conditions

Directory of Open Access Journals (Sweden)

Jinzhou Zhao

2016-06-01

Full Text Available Hydraulic fracturing is an essential technology in developing shale gas reservoirs, not to mention, accurate prediction of productivity in fractured shale gas wells is the foundation of an efficient development in shale gas reservoirs. This paper establishes a gas–water two-phase flow percolation mathematical model by a determined numerical simulation and calculation method under desorption and diffusion conditions. By means of simulating for a post-frac performance of the shale gas reservoir, this paper devotes to a quantitative analysis the impact of fracture parameters, physical parameters, and desorption–diffusion parameters. The outcome of this research indicates that hydraulic fracturing can improve single well production and it's an effective measure in the development of shale gas. The conductivity of hydraulic fractures and the permeability of natural fractures are the main influences on shale gas production. The higher these factors are, the higher the gas and water productions are. In comparison, the matrix permeability and diffusion coefficients have minimal influences on production.

Determining the explosion risk level and the explosion hazard area for a group of natural gas wells

Science.gov (United States)

Gligor, A.; Petrescu, V.; Deac, C.; Bibu, M.

2016-11-01

Starting from the fact that the natural gas engineering profession is generally associated with a high occupational risk, the current paper aims to help increase the safety of natural gas wells and reduce the risk of work-related accidents, as well as the occurrence of professional illnesses, by applying an assessment method that has proven its efficiency in other industrial areas in combination with a computer-aided design software. More specifically, the paper focuses on two main research directions: assessing the explosion risk for employees working at natural gas wells and indicating areas with a higher explosion hazard by using a modern software that allows their presentation in 3D. The appropriate zoning of industrial areas allows to group the various functional areas function of the probability of the occurrence of a dangerous element, such as an explosive atmosphere and subsequently it allows also to correctly select the electrical and mechanical equipment that will be used in that area, since electrical apparatuses that are otherwise found in normal work environments cannot generally be used in areas with explosion hazard, because of the risk that an electric spark, an electrostatic discharge etc. ignites the explosive atmosphere.

Preliminary assessment of the waveform inversion method for interpretation of cross-well seismic data from the thermal production test, JAPEX/JNOC/GSC et al. Mallik 5L-38 gas hydrate production research well

Energy Technology Data Exchange (ETDEWEB)

Watanabe, T. [Nagoya Univ., Nagoya (Japan). Research Center for Seismology and Volcanology; Shimizu, S. [Japan National Oil Co., Chiba (Japan); Asakawa, E. [JGI Inc., Tokyo (Japan); Kamei, R.; Matsuoka, T. [Kyoto Univ., Kyoto (Japan). Dept. of Civil and Earth Resources Engineering

2005-07-01

The JAPEX/JNOC/GSC et al. Mallik 3L-38 and 4L-38 test wells were subjected to repeated cross-well seismic surveys before and during the gas production test from the gas-hydrate-bearing layer at a depth of about 905 to 920 m. High-resolution velocity images in the gas-hydrate-bearing layer were obtained using the frequency-domain nonlinear waveform inversion method. An acoustic waveform inversion method was used along with the frequency-domain approach in order to detect the change in acoustic properties of the gas-hydrate-bearing layer resulting from gas production. The layered structures with small lateral heterogeneities were reconstructed by tomography analysis of preprocessed waveform data using a smaller number of source-receiver pairs. Preliminary results reveal high velocity and very high attenuation in the gas-hydrate-bearing layers. No obvious velocity decreases were noted. Information for further detailed processing was also gathered.

The three-zone composite productivity model for a multi-fractured horizontal shale gas well

Science.gov (United States)

Qi, Qian; Zhu, Weiyao

2018-02-01

Due to the nano-micro pore structures and the massive multi-stage multi-cluster hydraulic fracturing in shale gas reservoirs, the multi-scale seepage flows are much more complicated than in most other conventional reservoirs, and are crucial for the economic development of shale gas. In this study, a new multi-scale non-linear flow model was established and simplified, based on different diffusion and slip correction coefficients. Due to the fact that different flow laws existed between the fracture network and matrix zone, a three-zone composite model was proposed. Then, according to the conformal transformation combined with the law of equivalent percolation resistance, the productivity equation of a horizontal fractured well, with consideration given to diffusion, slip, desorption, and absorption, was built. Also, an analytic solution was derived, and the interference of the multi-cluster fractures was analyzed. The results indicated that the diffusion of the shale gas was mainly in the transition and Fick diffusion regions. The matrix permeability was found to be influenced by slippage and diffusion, which was determined by the pore pressure and diameter according to the Knudsen number. It was determined that, with the increased half-lengths of the fracture clusters, flow conductivity of the fractures, and permeability of the fracture network, the productivity of the fractured well also increased. Meanwhile, with the increased number of fractures, the distance between the fractures decreased, and the productivity slowly increased due to the mutual interfere of the fractures.

Well-to-Wheels analysis of landfill gas-based pathways and their addition to the GREET model.

Energy Technology Data Exchange (ETDEWEB)

Mintz, M.; Han, J.; Wang, M.; Saricks, C.; Energy Systems

2010-06-30

Today, approximately 300 million standard cubic ft/day (mmscfd) of natural gas and 1600 MW of electricity are produced from the decomposition of organic waste at 519 U.S. landfills (EPA 2010a). Since landfill gas (LFG) is a renewable resource, this energy is considered renewable. When used as a vehicle fuel, compressed natural gas (CNG) produced from LFG consumes up to 185,000 Btu of fossil fuel and generates from 1.5 to 18.4 kg of carbon dioxide-equivalent (CO{sub 2}e) emissions per million Btu of fuel on a 'well-to-wheel' (WTW) basis. This compares with approximately 1.1 million Btu and 78.2 kg of CO{sub 2}e per million Btu for CNG from fossil natural gas and 1.2 million Btu and 97.5 kg of CO{sub 2}e per million Btu for petroleum gasoline. Because of the additional energy required for liquefaction, LFG-based liquefied natural gas (LNG) requires more fossil fuel (222,000-227,000 Btu/million Btu WTW) and generates more GHG emissions (approximately 22 kg CO{sub 2}e /MM Btu WTW) if grid electricity is used for the liquefaction process. However, if some of the LFG is used to generate electricity for gas cleanup and liquefaction (or compression, in the case of CNG), vehicle fuel produced from LFG can have no fossil fuel input and only minimal GHG emissions (1.5-7.7 kg CO{sub 2}e /MM Btu) on a WTW basis. Thus, LFG-based natural gas can be one of the lowest GHG-emitting fuels for light- or heavy-duty vehicles. This report discusses the size and scope of biomethane resources from landfills and the pathways by which those resources can be turned into and utilized as vehicle fuel. It includes characterizations of the LFG stream and the processes used to convert low-Btu LFG into high-Btu renewable natural gas (RNG); documents the conversion efficiencies and losses of those processes, the choice of processes modeled in GREET, and other assumptions used to construct GREET pathways; and presents GREET results by pathway stage. GREET estimates of well-to-pump (WTP

78 FR 17835 - Approval and Promulgation of Federal Implementation Plan for Oil and Natural Gas Well Production...

Science.gov (United States)

2013-03-22

...: One commenter stated that the EPA needs to control air quality because hydraulic fracturing (``fracking'') is under-regulated. Response: The majority of oil and natural gas wells drilled today are hydraulically fractured. Hydraulic fracturing occurs when wells are being completed and recompleted. NSPS OOOO...

A gas production system from methane hydrate layers by hot water injection and BHP control with radial horizontal wells

Energy Technology Data Exchange (ETDEWEB)

Yamakawa, T.; Ono, S.; Iwamoto, A.; Sugai, Y.; Sasaki, K. [Kyushu Univ., Fukuoka, Fukuoka (Japan)

2010-07-01

Reservoir characterization of methane hydrate (MH) bearing turbidite channel in the eastern Nankai Trough, in Japan has been performed to develop a gas production strategy. This paper proposed a gas production system from methane hydrate (MH) sediment layers by combining the hot water injection method and bottom hole pressure control at the production well using radial horizontal wells. Numerical simulations of the cylindrical homogeneous MH layer model were performed in order to evaluate gas production characteristics by the depressurization method with bottom hole pressure control. In addition, the effects of numerical block modeling and averaging physical properties of MH layers were presented. According to numerical simulations, combining the existing production system with hot water injection and bottom hole pressure control results in an outward expansion of the hot water chamber from the center of the MH layer with continuous gas production. 10 refs., 15 figs.

Development of a biofiltration system to remove hydrogen sulphide from small oil and gas production facilities

International Nuclear Information System (INIS)

Dombroski, E.C.; Gaudet, I. D.; Coleman, R. N.

1997-01-01

Environmental regulations require sulphur separation in any processing operation that produces more than one tonne of sulphur per day. This leaves about 50 small operations in Alberta where the daily production of sulphur is less than one tonne. In these cases, the extracted acid gases are usually flared. Since flares are often inefficient and do not completely oxidize the hydrogen sulfide, an alternate, cost-effective technology that could replace flaring and eliminate atmospheric discharge would be of considerable interest. Biofiltration is known to be capable of oxidizing hydrogen sulfide in an air stream to non-volatile sulphate. The objective of this paper was to investigate the effectiveness of this technology in controlling H 2 S and SO 2 emissions from sour gas plants. Results of this laboratory-scale experiment were encouraging, justifying further studies on a demonstration-scale to determine if a full-scale biofilter could provide a practical, cost-effective technology for sulfur emission control from gas plants. 9 refs., 7 figs