IR Laser-Induced Thermolysis and UV Laser-Induced Photolysis of 1,3-Diethyldisiloxane: Chemical Vapour Deposition of Nanotextured Hydridoalkylsilicones

Czech Academy of Sciences Publication Activity Database

Urbanová, Markéta; Bastl, Zdeněk; Šubrt, Jan; Pola, Josef

2001-01-01

Roč. 11, č. 6 (2001), s. 1557-1562 ISSN 0959-9428 R&D Projects: GA AV ČR IAA4072806 Keywords : thermolysis * UV laser photolysis * composition Subject RIV: CH - Nuclear ; Quantum Chemistry Impact factor: 2.736, year: 2001

Gas-phase thermolysis reaction of formaldehyde diperoxide. Kinetic study and theoretical mechanisms

International Nuclear Information System (INIS)

Jorge, Nelly Lidia; Romero, Jorge Marcelo; Grand, André; Hernández-Laguna, Alfonso

2012-01-01

Highlights: ► Kinetic and mechanism of the gas-phase thermolysis of tetroxane were determined. ► Gas chromatography and computational potential energy surfaces were performed. ► A mechanism in steps looked like the most probable mechanism. ► A spin–orbit coupling appeared at the singlet and triple diradical open structures. ► A non-adiabatic crossing from the singlet to the triplet state occurred. - Abstract: Gas-phase thermolysis reaction of formaldehyde diperoxide (1,2,4,5-tetroxane) was performed in an injection chamber of a gas chromatograph at a range of 463–503 K. The average Arrhenius activation energy and pre-exponential factor were 29.3 ± 0.8 kcal/mol and 5.2 × 10 13 s −1 , respectively. Critical points and reaction paths of the ground singlet and first triplet potential energy surfaces (PES) were calculated, using DFT method at BHANDHLYP/6-311+G ∗∗ level of the theory. Also, G3 calculations were performed on the reactant and products. Reaction by the ground-singlet and first-triplet states turned out to be endothermic and exothermic, respectively. The mechanism in three steps seemed to be the most probable one. An electronically non-adiabatic process appeared, in which a crossing, at an open diradical structure, from the singlet to the triplet state PES occurred, due to a spin–orbit coupling, yielding an exothermic reaction. Theoretical kinetic constant coming from the non- adiabatic transition from the singlet to the triplet state agrees with the experimental values.

Gas-phase thermolysis reaction of formaldehyde diperoxide. Kinetic study and theoretical mechanisms

Energy Technology Data Exchange (ETDEWEB)

Jorge, Nelly Lidia [Instituto Andaluz de Ciencias de la Tierra, CSIC-Universidad de Granada, Av. Las Palmeras 4, 18100 Armilla, Granada (Spain); Area de Quimica Fisica Facultad de Ciencias Exactas y Naturales y Agrimensura, UNNE, Avda. Libertad 5460, 3400 Corrientes (Argentina); Romero, Jorge Marcelo [Area de Quimica Fisica Facultad de Ciencias Exactas y Naturales y Agrimensura, UNNE, Avda. Libertad 5460, 3400 Corrientes (Argentina); Grand, Andre [INAC, SCIB, Laboratoire ' Lesions des Acides Nucleiques' , UMR CEA-UJF E3, CEA-Grenoble, 17 Rue des Martyrs, 38054 Grenoble cedex 9 (France); Hernandez-Laguna, Alfonso, E-mail: ahlaguna@ugr.es [Instituto Andaluz de Ciencias de la Tierra, CSIC-Universidad de Granada, Av. Las Palmeras 4, 18100 Armilla, Granada (Spain)

2012-01-17

Highlights: Black-Right-Pointing-Pointer Kinetic and mechanism of the gas-phase thermolysis of tetroxane were determined. Black-Right-Pointing-Pointer Gas chromatography and computational potential energy surfaces were performed. Black-Right-Pointing-Pointer A mechanism in steps looked like the most probable mechanism. Black-Right-Pointing-Pointer A spin-orbit coupling appeared at the singlet and triple diradical open structures. Black-Right-Pointing-Pointer A non-adiabatic crossing from the singlet to the triplet state occurred. - Abstract: Gas-phase thermolysis reaction of formaldehyde diperoxide (1,2,4,5-tetroxane) was performed in an injection chamber of a gas chromatograph at a range of 463-503 K. The average Arrhenius activation energy and pre-exponential factor were 29.3 {+-} 0.8 kcal/mol and 5.2 Multiplication-Sign 10{sup 13} s{sup -1}, respectively. Critical points and reaction paths of the ground singlet and first triplet potential energy surfaces (PES) were calculated, using DFT method at BHANDHLYP/6-311+G{sup Asterisk-Operator Asterisk-Operator} level of the theory. Also, G3 calculations were performed on the reactant and products. Reaction by the ground-singlet and first-triplet states turned out to be endothermic and exothermic, respectively. The mechanism in three steps seemed to be the most probable one. An electronically non-adiabatic process appeared, in which a crossing, at an open diradical structure, from the singlet to the triplet state PES occurred, due to a spin-orbit coupling, yielding an exothermic reaction. Theoretical kinetic constant coming from the non- adiabatic transition from the singlet to the triplet state agrees with the experimental values.

Kinetic isotope effect in the thermolysis of methylenecyclobutane

International Nuclear Information System (INIS)

Chickos, J.S.

1979-01-01

The intramolecular kinetic isotope effect for the thermolysis of equilibrated methylenecyclobutane-d 2 was investigated at 515 0 C as a function of pressure. A high-pressure value of k/sub H/k/sub D/ (ethylene/ethylene-d 2 ) = 0.9 was obtained at 13 cm of N 2 pressure. This value decreased to 0.86 at 70 μm total pressure. No intermolecular kinetic isotope effect was measured for the formation of ethylene from labeled and unlabeled methylenecyclobutane. The pressure and temperature dependence of the intramolecular kinetic isotope effect was used as evidence in establishing the inverse nature of the effect. The isotope effect observed was explained in terms of competing equilibrium and kinetic isotope effects in which the equilibrium isotope effects dominate. It was concluded on the bases of these results that an acyclic intermediate is involved in the fragmentation of methylenecyclobutane to ethylene and allene. The results also support the notion that deuterium prefers to accumulate at the methylene group with the greatest p character in the carbon--hydrogen bond. 1 figure, 4 tables

Polyol-mediated thermolysis process for the synthesis of MgO nanoparticles and nanowires

Energy Technology Data Exchange (ETDEWEB)

Subramania, A; Kumar, G Vijaya; Priya, A R Sathiya; Vasudevan, T [Advanced Materials Research Lab, Department of Industrial Chemistry, Alagappa University, Karaikudi-630 003 (India)

2007-06-06

The main aim of this work is to prepare MgO nanoparticles and nanowires by a novel polyol-mediated thermolysis (PMT) process. The influence of different mole concentration of magnesium acetate, polyvinyl pyrrolidone (PVP; capping agent) and ethylene glycol (EG; solvent as well as reducing agent) on the formation of nanoparticles and nanowires and the effect of calcination on the crystalline size of the samples were also examined. The resultant oxide structure, thermal behaviour, size and shape have been studied using x-ray diffraction (XRD) studies, thermal (TG/DTA) analysis and scanning electron microscopy (SEM)/transmission electron microscopy (TEM) respectively.

Polyol-mediated thermolysis process for the synthesis of MgO nanoparticles and nanowires

Science.gov (United States)

Subramania, A.; Vijaya Kumar, G.; Sathiya Priya, A. R.; Vasudevan, T.

2007-06-01

The main aim of this work is to prepare MgO nanoparticles and nanowires by a novel polyol-mediated thermolysis (PMT) process. The influence of different mole concentration of magnesium acetate, polyvinyl pyrrolidone (PVP; capping agent) and ethylene glycol (EG; solvent as well as reducing agent) on the formation of nanoparticles and nanowires and the effect of calcination on the crystalline size of the samples were also examined. The resultant oxide structure, thermal behaviour, size and shape have been studied using x-ray diffraction (XRD) studies, thermal (TG/DTA) analysis and scanning electron microscopy (SEM)/transmission electron microscopy (TEM) respectively.

Polyol-mediated thermolysis process for the synthesis of MgO nanoparticles and nanowires

International Nuclear Information System (INIS)

Subramania, A; Kumar, G Vijaya; Priya, A R Sathiya; Vasudevan, T

2007-01-01

The main aim of this work is to prepare MgO nanoparticles and nanowires by a novel polyol-mediated thermolysis (PMT) process. The influence of different mole concentration of magnesium acetate, polyvinyl pyrrolidone (PVP; capping agent) and ethylene glycol (EG; solvent as well as reducing agent) on the formation of nanoparticles and nanowires and the effect of calcination on the crystalline size of the samples were also examined. The resultant oxide structure, thermal behaviour, size and shape have been studied using x-ray diffraction (XRD) studies, thermal (TG/DTA) analysis and scanning electron microscopy (SEM)/transmission electron microscopy (TEM) respectively

Catalytic thermal treatment (catalytic thermolysis) of a rice grain-based biodigester effluent of an alcohol distillery plant.

Science.gov (United States)

Prajapati, Abhinesh Kumar; Chaudhari, Parmesh Kumar; Mazumdar, Bidyut; Choudhary, Rumi

2015-01-01

The catalytic thermolysis (CT) process is an effective and novel approach to treat rice grain-based biodigester effluent (BDE) of the distillery plant. CT treatment of rice grain-based distillery wastewater was carried out in a 0.5 dm(3) thermolytic batch reactor using different catalysts such as CuO, copper sulphate and ferrous sulphate. With the CuO catalyst, a temperature of 95°C, catalyst loading of 4 g/dm(3) and pH 5 were found to be optimal, obtaining a maximum chemical oxygen demand (COD) and colour removal of 80.4% and 72%, respectively. The initial pH (pHi) was an important parameter to remove COD and colour from BDE. At higher pHi (pH 9.5), less COD and colour reduction were observed. The settling characteristics of CT-treated sludge were also analysed at different temperatures. It was noted that the treated slurry at a temperature of 80°C gave best settling characteristics. Characteristics of residues are also analysed at different pH.

Solution Focused Approach and Usage of Nursing

Directory of Open Access Journals (Sweden)

Nurcan AKGUL GUNDOGDU

2016-12-01

Full Text Available "Problem talk creates problems; solution talk creates solutions " Steve de Shazer In recent years, concern for solution-oriented approach has increased in nursing practice. In this review it is aimed to give information about nursing application of solution-oriented approach whose efficacy has been proved with many studies. In addition, solution-oriented approach is what how it turned out, the answer to the question of principle, and that is what the management strategy and what the nursing relationship will be sought. [JCBPR 2016; 5(3.000: 145-152

Phase transformations during HLnTiO{sub 4} (Ln=La, Nd) thermolysis and photocatalytic activity of obtained compounds

Energy Technology Data Exchange (ETDEWEB)

Silyukov, Oleg I., E-mail: olegsilyukov@yandex.ru; Abdulaeva, Liliia D.; Burovikhina, Alena A.; Rodionov, Ivan A.; Zvereva, Irina A.

2015-03-15

Layered HLnTiO{sub 4} (Ln=La, Nd) compounds belonging to Ruddlesden–Popper phases were found to form partially hydrated compounds Ln{sub 2}Ti{sub 2}O{sub 7}·xH{sub 2}O during thermal dehydration as well as defect oxides Ln{sub 2}□Ti{sub 2}O{sub 7} as final products. Further heating of metastable defect Ln{sub 2}□Ti{sub 2}O{sub 7} substances leads to the formation of pyrochlore-type oxides Ln{sub 2}Ti{sub 2}O{sub 7} {sub (p)}, with subsequent transformation under higher temperatures to stable layered 110-type perovskites Ln{sub 2}Ti{sub 2}O{sub 7}. The occurring structure transformations lead to an increase of photocatalytic activity in the order of HLnTiO{sub 4}solution. - Graphical abstract: Layered HLnTiO{sub 4} (Ln=La, Nd) compounds form partially hydrated Ln{sub 2}Ti{sub 2}O{sub 7}·xH{sub 2}O compounds during thermal dehydration, further heating results to the formation to defect oxides Ln{sub 2}□Ti{sub 2}O{sub 7}, pyrochlor-type oxides Ln{sub 2}Ti{sub 2}O{sub 7} {sub (p)}, with subsequent transformation to layered 110-type perovskites Ln{sub 2}Ti{sub 2}O{sub 7}. Structure transformations lead to an increase of photocatalytic activity in the order of HLnTiO{sub 4}thermolysis of HLnTiO{sub 4} (Ln=La, Nd) compounds. • XRD, STA and solid state IR studies were carried out. • A new series of metastable Ln{sub 2}Ti{sub 2}O{sub 7}·yH{sub 2}O compounds was obtained. • We examined the photocatalytic activity of all obtained compounds. The hydrogen evolution rate increased in the course of the structure changes during thermolysis.

Impacts of glycolate and formate radiolysis and thermolysis on hydrogen generation rate calculations for the Savannah River Site tank farm

Energy Technology Data Exchange (ETDEWEB)

Crawford, C. L. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); King, W. D. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

2017-08-14

Savannah River Remediation (SRR) personnel requested that the Savannah River National Laboratory (SRNL) evaluate available data and determine its applicability to defining the impact of planned glycolate anion additions to Savannah River Site (SRS) High Level Waste (HLW) on Tank Farm flammability (primarily with regard to H₂ production). Flammability evaluations of formate anion, which is already present in SRS waste, were also needed. This report describes the impacts of glycolate and formate radiolysis and thermolysis on Hydrogen Generation Rate (HGR) calculations for the SRS Tank Farm.

Preparation and characterization of CuO catalyst for the thermolysis treatment of distillery wastewater.

Science.gov (United States)

Sharma, Deepak; Prajapati, Abhinesh Kumar; Choudhary, Rumi; Kaushal, Rajesh Kumar; Pal, Dharm; Sawarkar, Ashish N

2017-08-16

CuO catalyst was prepared from copper sulfate by alkali precipitation method followed by drying and calcination. Characterization of CuO catalyst using X-ray diffraction, Brunauer-Emmett-Teller, and Barrett-Joyner-Halenda surface area analysis envisaged the effectiveness of CuO as a catalyst for the treatment of biodigester effluent (BDE) emanated from distilleries. The catalytic thermolysis is an efficient advance treatment method for distillery biodigester effluent (BDE). CT treatment of BDE was carried out in a 0.5 dm 3 thermolytic batch reactor using CuO as a catalyst at different pH (1-9), temperatures (80-110°C), and catalyst loadings (1-4 kg/m 3 ). With CuO catalyst, a temperature of 110°C, catalyst loading of 4 kg/m 3 , and pH of 2 was found to be optimal, providing a maximum reduction in chemical oxygen demand of 65%. The settling characteristics at different temperatures of CT-treated sludge were also presented.

Thermolysis of (1R,2R)-1,2-dideuteriocyclobutane. An application of vibrational circular dichroism to kinetic analysis

International Nuclear Information System (INIS)

Chickos, J.S.; Annamalai, A.; Keiderling, T.A.

1986-01-01

The relative rates of geometric isomerization to racemization have been studied for the title compound by using a combination of infrared (IR) and vibrational circular dichroism (VCD) spectroscopies, respectively. The results are interpreted with a kinetic and mechanistic scheme which parallels that used by Berson, Pedersen, and Carpenter on a similar study of chiral cyclopropane-d 2 thermolysis. Relative rates of isomerization to stereomutation of 1.5 +/- 0.4 were obtained which can be interpreted to be consistent with a mechanism best described by random methylene rotation in tetramethylene-d 2 . This is the first application of VCD to kinetic analysis, and the advantages of IR techniques over the more usually employed UV spectroscopies to this type of basic mechanistic problem are illustrated

Large-scale preparation of CdS quantum dots by direct thermolysis of a single-source precursor

Energy Technology Data Exchange (ETDEWEB)

Li Zhiguo; Cai Wei; Sui Jiehe [School of Material Science and Engineering, Harbin Institute of Technology, Harbin, Heilongjiang 150001 (China)

2008-01-23

CdS quantum dots (QDs) have been synthesized on a large scale, based on the direct thermolysis of one single-source precursor (Me{sub 4}N){sub 4}[S{sub 4}Cd{sub 10}(SPh){sub 16}], in hexadecylamine (HDA). Transmission electron microscopy (TEM) observations show that the CdS QDs are well-defined, nearly spherical particles. The clear lattice fringes in high-resolution TEM (HRTEM) images confirm the crystalline nature of the QDs. The broad diffraction in the x-ray diffraction (XRD) pattern and diffuse diffraction rings of the selected-area electron diffraction (SAED) pattern are typical of nanomeric-size particles and indicative of the hexagonal phase of CdS QDs. The absorption spectra confirm quantum confinement of CdS QDs. The synthesis process for CdS QDs was investigated by ultraviolet-visible (UV-vis) absorption spectroscopy. The results demonstrate that the nucleation and growth stages were separated automatically in a homogeneous system.

Chemical vapor deposition growth of boron-carbon-nitrogen layers from methylamine borane thermolysis products

Science.gov (United States)

Leardini, Fabrice; Flores, Eduardo; Galvis E, Andrés R.; Ferrer, Isabel J.; Ramón Ares, José; Sánchez, Carlos; Molina, Pablo; van der Meulen, Herko P.; Gómez Navarro, Cristina; López Polin, Guillermo; Urbanos, Fernando J.; Granados, Daniel; García-García, F. Javier; Demirci, Umit B.; Yot, Pascal G.; Mastrangelo, Filippo; Grazia Betti, Maria; Mariani, Carlo

2018-01-01

This work investigates the growth of B-C-N layers by chemical vapor deposition using methylamine borane (MeAB) as the single-source precursor. MeAB has been synthesized and characterized, paying particular attention to the analysis of its thermolysis products, which are the gaseous precursors for B-C-N growth. Samples have been grown on Cu foils and transferred onto different substrates for their morphological, structural, chemical, electronic and optical characterizations. The results of these characterizations indicate a segregation of h-BN and graphene-like (Gr) domains. However, there is an important presence of B and N interactions with C at the Gr borders, and of C interacting at the h-BN-edges, respectively, in the obtained nano-layers. In particular, there is a significant presence of C-N bonds, at Gr/h-BN borders and in the form of N doping of Gr domains. The overall B:C:N contents in the layers is close to 1:3:1.5. A careful analysis of the optical bandgap determination of the obtained B-C-N layers is presented, discussed and compared with previous seminal works with samples of similar composition.

Knudsen thermogravimetry approach to the thermodynamics of aqueous solutions

International Nuclear Information System (INIS)

Schiraldi, Alberto; Signorelli, Marco; Fessas, Dimitrios

2013-01-01

Highlights: ► Knudsen cells were designed to replace standard TG pans for desorption experiments. ► The Knudsen effusion data allow determination of water activity of aqueous solutions. ► This methods can replace the traditional isopiestic approach for aqueous solutions. ► The Gibbs–Duhem relationship was used to fit the experimental data. -- Abstract: The use of isothermal TGA with Knudsen-like cells allows determination of the thermodynamic activity of water, a W . The typical experiment implies a slow dehydration of the aqueous solution at constant temperature in dynamic vacuum conditions. The method is alternative to the classical isopiestic approach and offers the advantage of a continuous record on increasing the solute concentration. These data can be directly treated according to the classical thermodynamic relationships drawn from the Gibbs–Duhem expression to evaluate the activity and osmotic coefficient of the aqueous solutions of electrolytes and non-electrolytes, and, in the case of electrolytes, allow determination of solubility of the solute. Discrepancies with respect to the literature data are observed when the viscosity of the systems becomes too high, as in the case of sugars with a very large solubility. Such a mismatch may however be accounted for either slowing the dehydration rate with use of a narrower Knudsen orifice, or correcting the experimental a W with a calibration curve. The same approach can be applied to non-aqueous solutions

Silverlight 2 Recipes A Problem-solution Approach

CERN Document Server

Ghosh, Cameron

2010-01-01

Microsoft .NET Architect Evangelist, Jit Ghosh, presents a practical companion guide to developing rich, interactive web applications with Silverlight 2. Common problems, issues, and every--day scenarios are tackled with a detailed discussion of the solution and ready--made code recipes that will save you hours of coding time. The recipes included in Silverlight 2 Recipes: A Problem-Solution Approach have been carefully selected and tested with the professional developer in mind. You'll find clearly and succinctly stated problems, well--architected solutions, and ample discussion of the code a

Spring Recipes A Problem-solution Approach

CERN Document Server

Long, Josh; Mak, Gary

2010-01-01

With over 3 Million users/developers, Spring Framework is the leading "out of the box" Java framework. Spring addresses and offers simple solutions for most aspects of your Java/Java EE application development, and guides you to use industry best practices to design and implement your applications. The release of Spring Framework 3 has ushered in many improvements and new features. Spring Recipes: A Problem-Solution Approach, Second Edition continues upon the bestselling success of the previous edition but focuses on the latest Spring 3 features for building enterprise Java applications.

Organisational Change: A Solution-Focused Approach

Science.gov (United States)

Morgan, Gavin

2016-01-01

This study investigates the effectiveness of a solution-focused approach to organisational change. Planning Alternative Tomorrows with Hope (PATH) is an intervention more commonly applied to individuals. In this study the intervention is used with groups of people working in educational organisations to help manage the change process. The approach…

One-Step Thermolysis Synthesis of Divalent Transition Metal Ions Monodoped and Tridoped CdS and ZnS Luminescent Nanomaterials

Directory of Open Access Journals (Sweden)

S. E. Saeed

2014-01-01

Full Text Available Mn2+, Co2+, or Ni2+ monodoped CdS (or ZnS and Mn2+-Co2+-Ni2+ tridoped CdS (or ZnS have been successfully synthesized by novel one-step thermolysis method using thiourea as a sulphur source. The synthesized nanomaterials were characterized by X-ray diffraction (XRD, transmission electron microscopy (TEM, and scanning electron microscopy (SEM. It is found that the average diameter and morphology of the synthesized samples varied with the nature of dopant ion. The successful doping of Mn2+-Co2+-Ni2+ tridoped ions into the host CdS (or ZnS was proved by the EDX spectra. The luminescence of CdS is only enhanced when monodoped with Mn2+ whereas it is enhanced when ZnS is either monodoped with Mn2+, Co2+, or Ni2+ or tridoped with Mn2+-Co2+-Ni2+. The synthesized samples could therefore offer opportunities for further fundamental research and technological applications.

Java EE 7 recipes a problem-solution approach

CERN Document Server

Juneau, Josh

2013-01-01

Java EE 7 Recipes takes an example-based approach in showing how to program Enterprise Java applications in many different scenarios. Be it a small-business web application, or an enterprise database application, Java EE 7 Recipes provides effective and proven solutions to accomplish just about any task that you may encounter. You can feel confident using the reliable solutions that are demonstrated in this book in your personal or corporate environment. The solutions in Java EE 7 Recipes are built using the most current Java Enterprise specifications, including EJB 3.2, JSF 2.2, Expression La

Technological development report for fiscal 1993 on the woodwaste thermolysis/gasification technology and generated gas utilization technology; 1993 nendo mokushitsukei haikibutsu no netsubunkai gas ka gijutsu to seisei gas no riyo gijutsu kaihatsu hokokusho

Energy Technology Data Exchange (ETDEWEB)

NONE

1994-03-01

The project is a joint effort of Japan and the Philippines to develop a thermolysis/gasification system, in which woodwaste now remaining unexploited in the Philippines is subjected to thermolysis/gasification and the resulting gas is used in a gas engine for the generation of electric power, in a 5-year period beginning in fiscal 1990. In this fiscal year, element technology verification tests are conducted, components of a demonstration plant are manufactured, and procurement is made as required, which completes all the tasks allotted to this fiscal year. All the constituents of the said demonstration plant fabricated or procured since fiscal 1991 are packed up and forwarded to Industrial Technology Development Institute (ITDI) of the Philippines, and engineering guidance is extended and test operations are carried out at the site of plant installation. In line with the said endeavors, on-site investigations are performed and researches are conducted together with ITDI scientists concerning the construction work and element technology confirmation. On the other hand, the Philippine side performs the second phase of civil engineering and construction carried over from the first phase. The demonstration plant is completed, adjustment and test operations are carried out, which means that the project is in progress as initially scheduled. (NEDO)

Thermolysis synthesis of pure phase NiO from novel sonochemical synthesized Ni(II) nano metal-organic supramolecular architecture.

Science.gov (United States)

Hanifehpour, Younes; Morsali, Ali; Mirtamizdoust, Babak; Joo, Sang Woo; Soltani, Behzad

2017-07-01

Nano-structures of a new supramolecular coordination compound of divalent nickel with the pyrazol (pzH) containing the terminal azide anions, [Ni(pzH) 2 (N 3 ) 2 ] (1), with discrete molecular architecture (DMA) in solid state was synthesized via sonochemical method. The new nanostructure was characterized by scanning electron microscopy, X-ray powder diffraction, IR, and elemental analysis. Compound 1 was structurally characterized by single crystal X-ray diffraction and the single-crystal X-ray data shows that the coordination number of Ni (II) ions is six, (NiN 6 ), with four N-donor atoms from neutral "pzH" ligands and two N-donors from two terminal azide anions. The supramolecular features in these complexes are guided and controlled by weak directional intermolecular interactions. The structure of the title complex was optimized by density functional theory calculations. Calculated structural parameters and IR spectra for the title complex are consistent with the crystal structure. The NiO nanoparticles were obtained by thermolysis of 1 at 180°C with oleic acid as a surfactant. Copyright © 2017 Elsevier B.V. All rights reserved.

TOXIC LEADERSHIP: A SYSTEMIC APPROACH TO SHIFT FROM REACTIVE TO PROACTIVE SOLUTIONS

Science.gov (United States)

2017-03-01

AIR COMMAND AND STAFF COLLEGE AIR UNIVERSITY TOXIC LEADERSHIP: A SYSTEMIC APPROACH TO SHIFT FROM REACTIVE TO PROACTIVE SOLUTIONS...DISTRIBUTION A. Approved for public release: distribution unlimited. Toxic Leadership: A Systemic Approach to Shift From Reactive to Proactive Solutions 1...US military loses valuable personnel when it is too late to implement corrective action and after those toxic Toxic Leadership: A Systemic Approach

Toward Analytic Solution of Nonlinear Differential Difference Equations via Extended Sensitivity Approach

International Nuclear Information System (INIS)

Darmani, G.; Setayeshi, S.; Ramezanpour, H.

2012-01-01

In this paper an efficient computational method based on extending the sensitivity approach (SA) is proposed to find an analytic exact solution of nonlinear differential difference equations. In this manner we avoid solving the nonlinear problem directly. By extension of sensitivity approach for differential difference equations (DDEs), the nonlinear original problem is transformed into infinite linear differential difference equations, which should be solved in a recursive manner. Then the exact solution is determined in the form of infinite terms series and by intercepting series an approximate solution is obtained. Numerical examples are employed to show the effectiveness of the proposed approach. (general)

Melting Behavior and Thermolysis of NaBH4−Mg(BH42 and NaBH4−Ca(BH42 Composites

Directory of Open Access Journals (Sweden)

Morten B. Ley

2015-04-01

Full Text Available The physical properties and the hydrogen release of NaBH4–Mg(BH42 and NaBH4−Ca(BH42 composites are investigated using in situ synchrotron radiation powder X-ray diffraction, thermal analysis and temperature programmed photographic analysis. The composite, xNaBH4–(1 − xMg(BH42, x = 0.4 to 0.5, shows melting/frothing between 205 and 220 °C. However, the sample does not become a transparent molten phase. This behavior is similar to other alkali-alkaline earth metal borohydride composites. In the xNaBH4–(1 − xCa(BH42 system, eutectic melting is not observed. Interestingly, eutectic melting in metal borohydrides systems leads to partial thermolysis and hydrogen release at lower temperatures and the control of sample melting may open new routes for obtaining high-capacity hydrogen storage materials.

Tricyanomethane and Its Ketenimine Tautomer: Generation from Different Precursors and Analysis in Solution, Argon Matrix, and as a Single Crystal.

Science.gov (United States)

Banert, Klaus; Chityala, Madhu; Hagedorn, Manfred; Beckers, Helmut; Stüker, Tony; Riedel, Sebastian; Rüffer, Tobias; Lang, Heinrich

2017-08-01

Solutions of azidomethylidenemalononitrile were photolyzed at low temperatures to produce the corresponding 2H-azirine and tricyanomethane, which were analyzed by low-temperature NMR spectroscopy. The latter product was also observed after short thermolysis of the azide precursor in solution whereas irradiation of the azide isolated in an argon matrix did not lead to tricyanomethane, but to unequivocal detection of the tautomeric ketenimine by IR spectroscopy for the first time. When the long-known "aquoethereal" greenish phase generated from potassium tricyanomethanide, dilute sulfuric acid, and diethyl ether was rapidly evaporated and sublimed, a mixture of hydronium tricyanomethanide and tricyanomethane was formed instead of the previously claimed ketenimine tautomer. Under special conditions of sublimation, single crystals of tricyanomethane could be isolated, which enabled the analysis of the molecular structure by X-ray diffraction. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Zinc oxide microcapsules obtained via a bio-inspired approach

International Nuclear Information System (INIS)

Lipowsky, Peter; Hirscher, Michael; Hoffmann, Rudolf C; Bill, Joachim; Aldinger, Fritz

2007-01-01

Hollow zinc oxide microcapsules have been synthesized by a sacrificial template route involving the chemical bath deposition of nanostructured zinc oxide thin films on sulfonate-modified polystyrene microspheres and subsequent removal of the polymer core by dissolution in a solvent or by thermolysis. Scanning electron micrographs show that uniform coating of the templates is achieved when ZnO is deposited from a solution containing zinc acetate, the polymer polyvinylpyrrolidone, and a base in methanol, and that the ZnO shells remain intact after removal of the cores. A focused ion beam is used to cut slices from the spheres and demonstrate their inner morphology and hollowness. X-ray diffraction yields evidence that the shells consist of nanocrystalline ZnO with the zincite structure

ASP.NET MVC 4 recipes a problem-solution approach

CERN Document Server

Ciliberti, John

2013-01-01

ASP.NET MVC 4 Recipes is a practical guide for developers creating modern web applications, cutting through the complexities of ASP.NET, jQuery, Knockout.js and HTML 5 to provide straightforward solutions to common web development problems using proven methods based on best practices. The problem-solution approach gets you in, out, and back to work quickly while deepening your understanding of the underlying platform and how to develop with it. Author John Ciliberti guides you through the framework and development tools, presenting typical challenges, along with code solutions and clear, conci

A Generic Solution Approach to Nurse Rostering

DEFF Research Database (Denmark)

Hansen, Anders Dohn; Mason, Andrew; Ryan, David

In this report, we present a solution approach to the nurse rostering problem. The problem is defined by a generic model that is able to capture close to all of the problem characteristics that we have seen in the literature and in the realistic problems at hand. The model is used directly in the...

Improved harmonic balance approach to periodic solutions of non-linear jerk equations

International Nuclear Information System (INIS)

Wu, B.S.; Lim, C.W.; Sun, W.P.

2006-01-01

An analytical approximate approach for determining periodic solutions of non-linear jerk equations involving third-order time-derivative is presented. This approach incorporates salient features of both Newton's method and the method of harmonic balance. By appropriately imposing the method of harmonic balance to the linearized equation, the approach requires only one or two iterations to predict very accurate analytical approximate solutions for a large range of initial velocity amplitude. One typical example is used to verify and illustrate the usefulness and effectiveness of the proposed approach

Performance of metal compound on thermolysis and electrolysis on sugar industries waste water treatment: COD and color removal with sludge analysis (batch-experiment)

Science.gov (United States)

Sahu, Omprakash

2017-10-01

The sugar cane industry is one of the most water demanding industries. Sugar industries consume and generate excess amount of water. The generated water contains organic compounds, which would cause pollution. The aim of this research work is to study the effectiveness of metal compound for treatment of sugar industry waste water by thermolysis and electrolysis process. The result shows ferrous metal catalyst shows 80 and 85 % chemical oxygen demand and color removal at pH 6, optimum mass loading 4 kg/m3, treatment temperature 85 °C and treatment time 9 h. When ferrous material was used as electrode, maximum 81 % chemical oxygen demand and 84 % color removal at pH 6, current density 156 Am-2, treatment time 120 min and anode consumption 0.7 g for 1.5 L wastewater were obtained.

Electrolyte solutions at curved electrodes. II. Microscopic approach.

Science.gov (United States)

Reindl, Andreas; Bier, Markus; Dietrich, S

2017-04-21

Density functional theory is used to describe electrolyte solutions in contact with electrodes of planar or spherical shape. For the electrolyte solutions, we consider the so-called civilized model, in which all species present are treated on equal footing. This allows us to discuss the features of the electric double layer in terms of the differential capacitance. The model provides insight into the microscopic structure of the electric double layer, which goes beyond the mesoscopic approach studied in Paper I. This enables us to judge the relevance of microscopic details, such as the radii of the particles forming the electrolyte solutions or the dipolar character of the solvent particles, and to compare the predictions of various models. Similar to Paper I, a general behavior is observed for small radii of the electrode in that in this limit the results become independent of the surface charge density and of the particle radii. However, for large electrode radii, non-trivial behaviors are observed. Especially the particle radii and the surface charge density strongly influence the capacitance. From the comparison with the Poisson-Boltzmann approach, it becomes apparent that the shape of the electrode determines whether the microscopic details of the full civilized model have to be taken into account or whether already simpler models yield acceptable predictions.

A new modeling and solution approach for the number partitioning problem

Directory of Open Access Journals (Sweden)

Bahram Alidaee

2005-01-01

Full Text Available The number partitioning problem has proven to be a challenging problem for both exact and heuristic solution methods. We present a new modeling and solution approach that consists of recasting the problem as an unconstrained quadratic binary program that can be solved by efficient metaheuristic methods. Our approach readily accommodates both the common two-subset partition case as well as the more general case of multiple subsets. Preliminary computational experience is presented illustrating the attractiveness of the method.

Inter-Governmental E-Government Processes:Comparison of Different Solution Approaches- Based on Examples from Switzerland / Europe

Directory of Open Access Journals (Sweden)

Frank Zimmermann

2006-12-01

Full Text Available The main objective of this article is to describe different solution approaches for e-Government processes across different institutions at different levels of public administrations: a phased approach for specific e-Government solutions and a platform approach for cross-organisational public services. We discuss selection criteria for the different approaches considering several examples and indicate a relationship between the expected return-on-investment and the complexity of the solution.

Android Recipes A Problem-Solution Approach

CERN Document Server

Friesen, Jeff

2011-01-01

Android continues to be one of the leading mobile OS and development platforms driving today's mobile innovations and the apps ecosystem. Android appears complex, but offers a variety of organized development kits to those coming into Android with differing programming language skill sets. Android Recipes: A Problem-Solution Approach guides you step-by-step through a wide range of useful topics using complete and real-world working code examples. In this book, you'll start off with a recap of Android architecture and app fundamentals, and then get down to business and build an app with Google'

Exact Travelling Solutions of Discrete sine-Gordon Equation via Extended Tanh-Function Approach

International Nuclear Information System (INIS)

Dai Chaoqing; Zhang Jiefang

2006-01-01

In this paper, we generalize the extended tanh-function approach, which was used to find new exact travelling wave solutions of nonlinear partial differential equations or coupled nonlinear partial differential equations, to nonlinear differential-difference equations. As illustration, two series of exact travelling wave solutions of the discrete sine-Gordon equation are obtained by means of the extended tanh-function approach.

Definition and use of Solution-focused Sustainability Assessment: A novel approach to generate, explore and decide on sustainable solutions for wicked problems.

Science.gov (United States)

Zijp, Michiel C; Posthuma, Leo; Wintersen, Arjen; Devilee, Jeroen; Swartjes, Frank A

2016-05-01

This paper introduces Solution-focused Sustainability Assessment (SfSA), provides practical guidance formatted as a versatile process framework, and illustrates its utility for solving a wicked environmental management problem. Society faces complex and increasingly wicked environmental problems for which sustainable solutions are sought. Wicked problems are multi-faceted, and deriving of a management solution requires an approach that is participative, iterative, innovative, and transparent in its definition of sustainability and translation to sustainability metrics. We suggest to add the use of a solution-focused approach. The SfSA framework is collated from elements from risk assessment, risk governance, adaptive management and sustainability assessment frameworks, expanded with the 'solution-focused' paradigm as recently proposed in the context of risk assessment. The main innovation of this approach is the broad exploration of solutions upfront in assessment projects. The case study concerns the sustainable management of slightly contaminated sediments continuously formed in ditches in rural, agricultural areas. This problem is wicked, as disposal of contaminated sediment on adjacent land is potentially hazardous to humans, ecosystems and agricultural products. Non-removal would however reduce drainage capacity followed by increased risks of flooding, while contaminated sediment removal followed by offsite treatment implies high budget costs and soil subsidence. Application of the steps in the SfSA-framework served in solving this problem. Important elements were early exploration of a wide 'solution-space', stakeholder involvement from the onset of the assessment, clear agreements on the risk and sustainability metrics of the problem and on the interpretation and decision procedures, and adaptive management. Application of the key elements of the SfSA approach eventually resulted in adoption of a novel sediment management policy. The stakeholder

Chemical evolution studies: the radiolysis and thermal decomposition of malonic acid

International Nuclear Information System (INIS)

Cruz-Castaneda, J.; Negron-Mendoza, A.; Heredia, A.; Ramos-Bernal, S.; Villafane-Barajas, S.; Frias, D.; Colin-Garcia, M.

2015-01-01

In the context of chemical evolution a simulation of a hydrothermal vent was performed. The thermolysis and radiolysis of malonic acid in aqueous solution were studied. The thermolysis was done by heating the samples (95 deg C) and radiolysis using gamma radiation. Products were identified by gas chromatography and gas chromatography-mass spectrometry. The thermal treatment produced acetic acid and CO 2 . The radiolysis experiments yield carbon dioxide, acetic acid, and di- and tricarboxylic acids. A theoretical model of the chemical process occurring under irradiation was developed; this was able to reproduce formation of products and the consumption of malonic acid. (author)

Entity Framework 4.0 Recipes A Problem-solution Approach

CERN Document Server

Tenny, L

2010-01-01

Entity Framework 4.0 Recipes provides an exhaustive collection of ready-to-use code solutions for Microsoft's Entity Framework, Microsoft's vision for the future of data access. Entity Framework is a model-centric data access platform with an ocean of new concepts and patterns for developers to learn. With this book, you will learn the core concepts of Entity Framework through a broad range of clear and concise solutions to everyday data access tasks. Armed with this experience, you will be ready to dive deep into Entity Framework, experiment with new approaches, and develop ways to solve even

New approaches and solutions of the nonlinear force-free field

International Nuclear Information System (INIS)

Xie Baisong; Yin Xintao; Luo Xia

2006-01-01

New approaches to nonlinear force-free field equations are presented and new exact solutions are found analytically. Examples are given and some implications of the results to astrophysical solar plasmas as well as tokamak plasmas are discussed

Numerical solution of the full potential equation using a chimera grid approach

Science.gov (United States)

Holst, Terry L.

1995-01-01

A numerical scheme utilizing a chimera zonal grid approach for solving the full potential equation in two spatial dimensions is described. Within each grid zone a fully-implicit approximate factorization scheme is used to advance the solution one interaction. This is followed by the explicit advance of all common zonal grid boundaries using a bilinear interpolation of the velocity potential. The presentation is highlighted with numerical results simulating the flow about a two-dimensional, nonlifting, circular cylinder. For this problem, the flow domain is divided into two parts: an inner portion covered by a polar grid and an outer portion covered by a Cartesian grid. Both incompressible and compressible (transonic) flow solutions are included. Comparisons made with an analytic solution as well as single grid results indicate that the chimera zonal grid approach is a viable technique for solving the full potential equation.

Scientific Approach and Inquiry Learning Model in the Topic of Buffer Solution: A Content Analysis

Science.gov (United States)

Kusumaningrum, I. A.; Ashadi, A.; Indriyanti, N. Y.

2017-09-01

Many concepts in buffer solution cause student’s misconception. Understanding science concepts should apply the scientific approach. One of learning models which is suitable with this approach is inquiry. Content analysis was used to determine textbook compatibility with scientific approach and inquiry learning model in the concept of buffer solution. By using scientific indicator tools (SIT) and Inquiry indicator tools (IIT), we analyzed three chemistry textbooks grade 11 of senior high school labeled as P, Q, and R. We described how textbook compatibility with scientific approach and inquiry learning model in the concept of buffer solution. The results show that textbook P and Q were very poor and book R was sufficient because the textbook still in procedural level. Chemistry textbooks used at school are needed to be improved in term of scientific approach and inquiry learning model. The result of these analyses might be of interest in order to write future potential textbooks.

SOA enabled ELTA: approach in designing business intelligence solutions in Era of Big Data

Directory of Open Access Journals (Sweden)

Viktor Dmitriyev

2015-01-01

Full Text Available The current work presents a new approach for designing business intelligence solutions. In the Era of Big Data, former and robust analytical concepts and utilities need to adapt themselves to the changed market circumstances. The main focus of this work is to address the acceleration of building process of a “data-centric” Business Intelligence (BI solution besides preparing BI solutions for Big Data utilization. This research addresses the following goals: reducing the time spent during business intelligence solution’s design phase; achieving flexibility of BI solution by adding new data sources; and preparing BI solution for utilizing Big Data concepts. This research proposes an extension of the existing Extract, Load and Transform (ELT approach to the new one Extract, Load, Transform and Analyze (ELTA supported by service-orientation concept. Additionally, the proposed model incorporates Service-Oriented Architecture concept as a mediator for the transformation phase. On one side, such incorporation brings flexibility to the BI solution and on the other side; it reduces the complexity of the whole system by moving some responsibilities to external authorities.

On one approach to an earthquakes forecasting problems solution

International Nuclear Information System (INIS)

Khugaev, A.V.; Koblik, Yu.N.; Rakhmanov, T.T.

2007-01-01

The problem of earthquake forecasting is practically important one but it is extremely complex and so it does not solved yet. In the report the problem of data analysis obtained in measurements of radioactive gases emission (for example, radon, thoron, action) from the earth surface, data in magnetic fields anomalies measurement and their correlation in accordance of seismic activity is considered. In a general case the problem has an unlikely total solution in an analytic meaning due to it nonlinearity, multi-parametration and influence of random factors. It is suggested that useful solution could be found only at reasonable combination of empiric knowledge got at a long observations, its generalization and numerical simulation. In the base of the offered calculation method the correlation analysis between seismic activity and , for example, radioactive gases emission variations of earthquake signs one can present in form of two components, one of which is regular component, and the second one is irregular one. The key interest presents the analysis of irregular component reasoned by random factors. At problem solution of irregular component of the Earth magnetic fields determination which with high precise could measured with help of magnetic sensors is determined. At that time in the base of mathematical apparatus for analysis the approach for irregular component determination applied at determination of irregular component of galactic magnet field. Hear values of irregular component and field size in which they play considerable role are obtained. Besides, the work the approach allowing solving problem about complex surface oscillation with necessary precision for practical requirements is discussed

Cerium(III) pivalate [Ce(Piv)3(HPiv)3]2: synthesis, crystal structure, and thermal stability

International Nuclear Information System (INIS)

Khudyakov, M.Yu.; Kuz'mina, N.P.; Pisarevskij, A.P.; Martynenko, L.I.

2002-01-01

Complex [Ce(Piv) 3 (HPiv) 3 ] 2 was prepared by precipitation of cerium(III) nitrate aqueous solution with salt NH 4 (Piv) (HPiv = pivalic acid) and subsequent recrystallization from 5% HPiv solution in hexane. According to data of X-ray diffraction analysis and IR spectroscopy crystal structure of the complex is built of centrally symmetric dimers, in which cerium atoms are bound by four bridge pivalate ligands. Thermal analysis suggests that heating of the complex in nitrogen atmosphere results first in splitting off six HPiv molecules in the range of 90-190 deg C and then in thermolysis of Ce(Piv) 3 formed at 290-450 deg C. Sublimation of Ce(Piv) 3 occurs in the range of 290-350 deg C along with thermolysis during heating in vacuum (0.01 mm Hg), which permits preparing CeO 2 films by the method of chemical precipitation from gaseous phase [ru

Synthesis and derivatographic investigation of potassium octacyanotungstate (4)

International Nuclear Information System (INIS)

Kovbashin, V.I.; Dovgej, V.V.; Chernyak, B.I.

1983-01-01

The interaction between the rated quantities of potassium cyanide and WO(OH) 3 hydroxide resulted in preparation of potassium dioxytetracyanotungstate (4), K 4 [WO 2 (CN) 4 ]X6H 2 O. The latter, while interacting with a saturated potassium cyanide solution in a carbon dioxide flow transforms to potassium octacyanotungstate (4). The process of K 4 [W(CH) 8 ]x2H 2 O compound thermolysis in argon atmosphere is studied. It is found that, after dehydration of the complex, there occurs thermal transformation of K 4 [W(CN) 8 ] to K 3 [W(CN) 7 ] and then to K 3 [W(CN) 6 ]. The thermolysis final product is tungsten carbide WC

Neuro-genetic hybrid approach for the solution of non-convex economic dispatch problem

International Nuclear Information System (INIS)

Malik, T.N.; Asar, A.U.

2009-01-01

ED (Economic Dispatch) is non-convex constrained optimization problem, and is used for both on line and offline studies in power system operation. Conventionally, it is solved as convex problem using optimization techniques by approximating generator input/output characteristic. Curves of monotonically increasing nature thus resulting in an inaccurate dispatch. The GA (Genetic Algorithm) has been used for the solution of this problem owing to its inherent ability to address the convex and non-convex problems equally. This approach brings the solution to the global minimum region of search space in a short time and then takes longer time to converge to near optimal results. GA based hybrid approaches are used to fine tune the near optimal results produced by GA. This paper proposes NGH (Neuro Genetic Hybrid) approach to solve the economic dispatch with valve point effect. The proposed approach combines the GA with the ANN (Artificial Neural Network) using SI (Swarm Intelligence) learning rule. The GA acts as a global optimizer and the neural network fine tunes the GA results to the desired targets. Three machines standard test system has been tested for validation of the approach. Comparing the results with GA and NGH model based on back-propagation learning, the proposed approach gives contrast improvements showing the promise of the approach. (author)

Variational Approaches for the Existence of Multiple Periodic Solutions of Differential Delay Equations

Directory of Open Access Journals (Sweden)

Rong Cheng

2010-01-01

Full Text Available The existence of multiple periodic solutions of the following differential delay equation (=−((− is established by applying variational approaches directly, where ∈ℝ, ∈(ℝ,ℝ and >0 is a given constant. This means that we do not need to use Kaplan and Yorke's reduction technique to reduce the existence problem of the above equation to an existence problem for a related coupled system. Such a reduction method introduced first by Kaplan and Yorke in (1974 is often employed in previous papers to study the existence of periodic solutions for the above equation and its similar ones by variational approaches.

Theoretical approach to the destruction or sterilization of drugs in aqueous solution

International Nuclear Information System (INIS)

Slegers, Catherine; Tilquin, Bernard

2005-01-01

Two novel applications in the radiation processing of aqueous solutions of drugs are the sterilization of injectable drugs and the decontamination of hospital wastewaters by ionizing radiation. The parameters influencing the destruction of the drug in aqueous solutions are studied with a computer simulation program. This theoretical approach has revealed that the dose rate is the most important parameter that can be easily varied in order to optimize the destruction or the protection of the drug

THE DECEPTIVELY SIMPLE THERMOLYSIS OF TRIVALENT PERMETHYLTITANOCENE DERIVATIVES (ETA-5-C5ME5)2TIR - FORMATION OF A TETRAMETHYLFULVENE TITANIUM COMPOUND (ETA-6-C5ME4CH2)(ETA-5-C5ME5)TI AND RH, CATALYZED BY PERMETHYLTITANOCENE HYDRIDE, (ETA-5-C5ME5)2TIH

NARCIS (Netherlands)

LUINSTRA, GA; TEUBEN, JH

1992-01-01

The complexes Cp*2TiR (Cp* = eta-5-C5Me5; R = Me, Et, n-Pr, C2H3, CH2CMe3, Ph) undergo thermolysis to yield the fulvene complex Cp*FvTi (Fv = eta-6-C5Me4CH2) and RH. Kinetic measurements and deuterium labeling studies show that the decomposition is catalyzed by Cp*2TiH, which is formed either by

Fabrication of γ-Fe2O3 Nanoparticles by Solid-State Thermolysis of a Metal-Organic Framework, MIL-100(Fe, for Heavy Metal Ions Removal

Directory of Open Access Journals (Sweden)

Shengtao Hei

2014-01-01

Full Text Available Porous γ-Fe2O3 nanoparticles were prepared via a solid-state conversion process of a mesoporous iron(III carboxylate crystal, MIL-100(Fe. First, the MIL-100(Fe crystal that served as the template of the metal oxide was synthesized by a low-temperature (<100°C synthesis route. Subsequently, the porous γ-Fe2O3 nanoparticles were fabricated by facile thermolysis of the MIL-100(Fe powders via a two-step calcination treatment. The obtained γ-Fe2O3 was characterized by X-ray diffraction (XRD, N2 adsorption, X-ray photoelectron spectroscopy (XPS, and scanning electron microscopy (SEM techniques, and then used as an adsorbent for heavy metal ions removal in water treatment. This study illustrates that the metal-organic frameworks may be suitable precursors for the fabrication of metal oxides nanomaterials with large specific surface area, and the prepared porous γ-Fe2O3 exhibits a superior adsorption performance for As(V and As(III ions removal in water treatment.

TALENT MANAGEMENT: A NOVEL APPROACH FOR DEVELOPING INNOVATIVE SOLUTIONS TOWARDS HERITAGE COMMUNITIES DEVELOPMENT

Directory of Open Access Journals (Sweden)

Mohamed Hesham Madbouly Hussein Khalil

2017-11-01

Full Text Available Heritage communities in Egypt have continuously developed to sustain a history of millenniums. Developments have been focused on sustaining the physical heritage such as buildings and cities, yet ignoring the intangible heritage such as stories, memories and traditions of people. The results are deterioration of the developed physical heritage as a natural response of ignorance. Architectural Design Firms (ADFs are responsible for developing innovative solutions that translate intangible heritage into sustainable projects. Such solutions require talented architects who are in need of being treated in a talented manner. Therefore, this paper aims to investigate the role of Talent Management (TM as a novel approach for developing innovative solutions for Egyptian heritage communities’ development. In order to achieve this aim, a qualitative approach based on (1 literature review is used to investigate heritage development, creative industries, ADFs, motivation and TM and (2 a case study is collected and analysed to study the relationship between TM and intangible heritage preservation.

A facile route to shape controlled CdTe nanoparticles

Energy Technology Data Exchange (ETDEWEB)

Mntungwa, Nhlakanipho; Rajasekhar, Pullabhotla V.S.R. [Department of Chemistry, University of Zululand, Private Bag X1001, KwaDlangezwa 3886, Empangeni, KZN (South Africa); Revaprasadu, Neerish, E-mail: nrevapra@pan.uzulu.ac.za [Department of Chemistry, University of Zululand, Private Bag X1001, KwaDlangezwa 3886, Empangeni, KZN (South Africa)

2011-04-15

Research highlights: {yields} A facile hybrid solution based/thermolysis route has been used for the synthesis of hexadecylamine capped CdTe nanoparticles. {yields} This method involves the reaction by the addition of an aqueous suspension of a cadmium salt to a freshly prepared NaHTe solution. {yields} The cadmium salt plays an important role in the growth mechanism of the particles and hence its final morphology. - Abstract: Hexadecylamine (HDA) capped CdTe nanoparticles have been synthesized using a facile hybrid solution based/thermolysis route. This method involves the reaction by the addition of an aqueous suspension or solution of a cadmium salt (chloride, acetate, nitrate or carbonate) to a freshly prepared NaHTe solution. The isolated CdTe was then dispersed in tri-octylphosphine (TOP) and injected into pre-heated HDA at temperatures of 190, 230 and 270 deg. C for 2 h. The particle growth and size distribution of the CdTe particles synthesized using cadmium chloride as the cadmium source were monitored using absorption and photoluminescence spectroscopy. The final morphology of the CdTe nanoparticles synthesized from the various cadmium sources was studied by transmission electron microscopy (TEM) and high resolution TEM. The cadmium source has an influence on the final morphology of the particles.

A facile route to shape controlled CdTe nanoparticles

International Nuclear Information System (INIS)

Mntungwa, Nhlakanipho; Rajasekhar, Pullabhotla V.S.R.; Revaprasadu, Neerish

2011-01-01

Research highlights: → A facile hybrid solution based/thermolysis route has been used for the synthesis of hexadecylamine capped CdTe nanoparticles. → This method involves the reaction by the addition of an aqueous suspension of a cadmium salt to a freshly prepared NaHTe solution. → The cadmium salt plays an important role in the growth mechanism of the particles and hence its final morphology. - Abstract: Hexadecylamine (HDA) capped CdTe nanoparticles have been synthesized using a facile hybrid solution based/thermolysis route. This method involves the reaction by the addition of an aqueous suspension or solution of a cadmium salt (chloride, acetate, nitrate or carbonate) to a freshly prepared NaHTe solution. The isolated CdTe was then dispersed in tri-octylphosphine (TOP) and injected into pre-heated HDA at temperatures of 190, 230 and 270 deg. C for 2 h. The particle growth and size distribution of the CdTe particles synthesized using cadmium chloride as the cadmium source were monitored using absorption and photoluminescence spectroscopy. The final morphology of the CdTe nanoparticles synthesized from the various cadmium sources was studied by transmission electron microscopy (TEM) and high resolution TEM. The cadmium source has an influence on the final morphology of the particles.

Heuristic Solution Approaches to the Double TSP with Multiple Stacks

DEFF Research Database (Denmark)

Petersen, Hanne Løhmann

This paper introduces the Double Travelling Salesman Problem with Multiple Stacks and presents a three different metaheuristic approaches to its solution. The Double Travelling Salesman Problem with Multiple Stacks is concerned with finding the shortest route performing pickups and deliveries in ...... are developed for the problem and used with each of the heuristics. Finally some computational results are given along with lower bounds on the objective value....

Heuristic Solution Approaches to the Double TSP with Multiple Stacks

DEFF Research Database (Denmark)

Petersen, Hanne Løhmann

2006-01-01

This paper introduces the Double Travelling Salesman Problem with Multiple Stacks and presents a three different metaheuristic approaches to its solution. The Double Travelling Salesman Problem with Multiple Stacks is concerned with finding the shortest route performing pickups and deliveries in ...... are developed for the problem and used with each of the heuristics. Finally some computational results are given along with lower bounds on the objective value....

A hybrid solution approach for a multi-objective closed-loop logistics network under uncertainty

Science.gov (United States)

Mehrbod, Mehrdad; Tu, Nan; Miao, Lixin

2015-06-01

The design of closed-loop logistics (forward and reverse logistics) has attracted growing attention with the stringent pressures of customer expectations, environmental concerns and economic factors. This paper considers a multi-product, multi-period and multi-objective closed-loop logistics network model with regard to facility expansion as a facility location-allocation problem, which more closely approximates real-world conditions. A multi-objective mixed integer nonlinear programming formulation is linearized by defining new variables and adding new constraints to the model. By considering the aforementioned model under uncertainty, this paper develops a hybrid solution approach by combining an interactive fuzzy goal programming approach and robust counterpart optimization based on three well-known robust counterpart optimization formulations. Finally, this paper compares the results of the three formulations using different test scenarios and parameter-sensitive analysis in terms of the quality of the final solution, CPU time, the level of conservatism, the degree of closeness to the ideal solution, the degree of balance involved in developing a compromise solution, and satisfaction degree.

A biomechanical triphasic approach to the transport of nondilute solutions in articular cartilage.

Science.gov (United States)

Abazari, Alireza; Elliott, Janet A W; Law, Garson K; McGann, Locksley E; Jomha, Nadr M

2009-12-16

Biomechanical models for biological tissues such as articular cartilage generally contain an ideal, dilute solution assumption. In this article, a biomechanical triphasic model of cartilage is described that includes nondilute treatment of concentrated solutions such as those applied in vitrification of biological tissues. The chemical potential equations of the triphasic model are modified and the transport equations are adjusted for the volume fraction and frictional coefficients of the solutes that are not negligible in such solutions. Four transport parameters, i.e., water permeability, solute permeability, diffusion coefficient of solute in solvent within the cartilage, and the cartilage stiffness modulus, are defined as four degrees of freedom for the model. Water and solute transport in cartilage were simulated using the model and predictions of average concentration increase and cartilage weight were fit to experimental data to obtain the values of the four transport parameters. As far as we know, this is the first study to formulate the solvent and solute transport equations of nondilute solutions in the cartilage matrix. It is shown that the values obtained for the transport parameters are within the ranges reported in the available literature, which confirms the proposed model approach.

The Deceptively Simple Thermolysis of Trivalent Permethyltitanocene Derivatives (η5-C5Me5)2TiR. Formation of a Tetramethylfulvene Titanium Compound (η6-C5Me4CH2)(η5-C5Me5)Ti and RH, Catalyzed by Permethyltitanocene Hydride, (η5-C5Me5)2TiH

NARCIS (Netherlands)

Luinstra, Gerrit A.; Teuben, Jan H.

1992-01-01

The complexes Cp*2TiR (Cp* = η5-C5Me5; R = Me, Et, n-Pr, C2H3, CH2CMe3, Ph) undergo thermolysis to yield the fulvene complex Cp*FvTi (Fv = η6-C5Me4CH2) and RH. Kinetic measurements and deuterium labeling studies show that the decomposition is catalyzed by Cp*2TiH, which is formed either by

Solution preparation

International Nuclear Information System (INIS)

Seitz, M.G.

1982-01-01

Reviewed in this statement are methods of preparing solutions to be used in laboratory experiments to examine technical issues related to the safe disposal of nuclear waste from power generation. Each approach currently used to prepare solutions has advantages and any one approach may be preferred over the others in particular situations, depending upon the goals of the experimental program. These advantages are highlighted herein for three approaches to solution preparation that are currently used most in studies of nuclear waste disposal. Discussion of the disadvantages of each approach is presented to help a user select a preparation method for his particular studies. Also presented in this statement are general observations regarding solution preparation. These observations are used as examples of the types of concerns that need to be addressed regarding solution preparation. As shown by these examples, prior to experimentation or chemical analyses, laboratory techniques based on scientific knowledge of solutions can be applied to solutions, often resulting in great improvement in the usefulness of results

The simulation of solute transport: An approach free of numerical dispersion

International Nuclear Information System (INIS)

Carrera, J.; Melloni, G.

1987-01-01

The applicability of most algorithms for simulation of solute transport is limited either by instability or by numerical dispersion, as seen by a review of existing methods. A new approach is proposed that is free of these two problems. The method is based on the mixed Eulerian-Lagrangian formulation of the mass-transport problem, thus ensuring stability. Advection is simulated by a variation of reverse-particle tracking that avoids the accumulation of interpolation errors, thus preventing numerical dispersion. The algorithm has been implemented in a one-dimensional code. Excellent results are obtained, in comparison with an analytical solution. 36 refs., 14 figs., 1 tab

Producing Satisfactory Solutions to Scheduling Problems: An Iterative Constraint Relaxation Approach

Science.gov (United States)

Chien, S.; Gratch, J.

1994-01-01

One drawback to using constraint-propagation in planning and scheduling systems is that when a problem has an unsatisfiable set of constraints such algorithms typically only show that no solution exists. While, technically correct, in practical situations, it is desirable in these cases to produce a satisficing solution that satisfies the most important constraints (typically defined in terms of maximizing a utility function). This paper describes an iterative constraint relaxation approach in which the scheduler uses heuristics to progressively relax problem constraints until the problem becomes satisfiable. We present empirical results of applying these techniques to the problem of scheduling spacecraft communications for JPL/NASA antenna resources.

Multiscale Multilevel Approach to Solution of Nanotechnology Problems

Directory of Open Access Journals (Sweden)

Polyakov Sergey

2018-01-01

Full Text Available The paper is devoted to a multiscale multilevel approach for the solution of nanotechnology problems on supercomputer systems. The approach uses the combination of continuum mechanics models and the Newton dynamics for individual particles. This combination includes three scale levels: macroscopic, mesoscopic and microscopic. For gas–metal technical systems the following models are used. The quasihydrodynamic system of equations is used as a mathematical model at the macrolevel for gas and solid states. The system of Newton equations is used as a mathematical model at the mesoand microlevels; it is written for nanoparticles of the medium and larger particles moving in the medium. The numerical implementation of the approach is based on the method of splitting into physical processes. The quasihydrodynamic equations are solved by the finite volume method on grids of different types. The Newton equations of motion are solved by Verlet integration in each cell of the grid independently or in groups of connected cells. In the framework of the general methodology, four classes of algorithms and methods of their parallelization are provided. The parallelization uses the principles of geometric parallelism and the efficient partitioning of the computational domain. A special dynamic algorithm is used for load balancing the solvers. The testing of the developed approach was made by the example of the nitrogen outflow from a balloon with high pressure to a vacuum chamber through a micronozzle and a microchannel. The obtained results confirm the high efficiency of the developed methodology.

Multiscale Multilevel Approach to Solution of Nanotechnology Problems

Science.gov (United States)

Polyakov, Sergey; Podryga, Viktoriia

2018-02-01

The paper is devoted to a multiscale multilevel approach for the solution of nanotechnology problems on supercomputer systems. The approach uses the combination of continuum mechanics models and the Newton dynamics for individual particles. This combination includes three scale levels: macroscopic, mesoscopic and microscopic. For gas-metal technical systems the following models are used. The quasihydrodynamic system of equations is used as a mathematical model at the macrolevel for gas and solid states. The system of Newton equations is used as a mathematical model at the mesoand microlevels; it is written for nanoparticles of the medium and larger particles moving in the medium. The numerical implementation of the approach is based on the method of splitting into physical processes. The quasihydrodynamic equations are solved by the finite volume method on grids of different types. The Newton equations of motion are solved by Verlet integration in each cell of the grid independently or in groups of connected cells. In the framework of the general methodology, four classes of algorithms and methods of their parallelization are provided. The parallelization uses the principles of geometric parallelism and the efficient partitioning of the computational domain. A special dynamic algorithm is used for load balancing the solvers. The testing of the developed approach was made by the example of the nitrogen outflow from a balloon with high pressure to a vacuum chamber through a micronozzle and a microchannel. The obtained results confirm the high efficiency of the developed methodology.

Noether symmetries of a modified model in teleparallel gravity and a new approach for exact solutions

Energy Technology Data Exchange (ETDEWEB)

Tajahmad, Behzad [University of Tabriz, Faculty of Physics, Tabriz (Iran, Islamic Republic of)

2017-04-15

In this paper, we present the Noether symmetries of flat FRW spacetime in the context of a new action in teleparallel gravity which we construct based on the f(R) version. This modified action contains a coupling between the scalar field potential and magnetism. Also, we introduce an innovative approach, the beyond Noether symmetry (B.N.S.) approach, for exact solutions which carry more conserved currents than the Noether approach. By data analysis of the exact solutions, obtained from the Noether approach, late-time acceleration and phase crossing are realized, and some deep connections with observational data such as the age of the universe, the present value of the scale factor as well as the state and deceleration parameters are observed. In the B.N.S. approach, we consider the dark energy dominated era. (orig.)

Noether symmetries of a modified model in teleparallel gravity and a new approach for exact solutions

International Nuclear Information System (INIS)

Tajahmad, Behzad

2017-01-01

In this paper, we present the Noether symmetries of flat FRW spacetime in the context of a new action in teleparallel gravity which we construct based on the f(R) version. This modified action contains a coupling between the scalar field potential and magnetism. Also, we introduce an innovative approach, the beyond Noether symmetry (B.N.S.) approach, for exact solutions which carry more conserved currents than the Noether approach. By data analysis of the exact solutions, obtained from the Noether approach, late-time acceleration and phase crossing are realized, and some deep connections with observational data such as the age of the universe, the present value of the scale factor as well as the state and deceleration parameters are observed. In the B.N.S. approach, we consider the dark energy dominated era. (orig.)

Mathematical solution of multilevel fractional programming problem with fuzzy goal programming approach

Science.gov (United States)

Lachhwani, Kailash; Poonia, Mahaveer Prasad

2012-08-01

In this paper, we show a procedure for solving multilevel fractional programming problems in a large hierarchical decentralized organization using fuzzy goal programming approach. In the proposed method, the tolerance membership functions for the fuzzily described numerator and denominator part of the objective functions of all levels as well as the control vectors of the higher level decision makers are respectively defined by determining individual optimal solutions of each of the level decision makers. A possible relaxation of the higher level decision is considered for avoiding decision deadlock due to the conflicting nature of objective functions. Then, fuzzy goal programming approach is used for achieving the highest degree of each of the membership goal by minimizing negative deviational variables. We also provide sensitivity analysis with variation of tolerance values on decision vectors to show how the solution is sensitive to the change of tolerance values with the help of a numerical example.

Analyzing Interpersonal Problem Solving in Terms of Solution Focused Approach and Humor Styles of University Student

Science.gov (United States)

Koc, Hayri; Arslan, Coskun

2017-01-01

In this study university students interpersonal problem solving approaches were investigated in terms of solution focused approach and humor styles. The participants were 773 (542 female and 231 male, between 17-33 years old) university students. To determine the university students' problem solving approaches "Interpersonal Problem Solving…

The double travelling salesman problem with multiple stacks - Formulation and heuristic solution approaches

DEFF Research Database (Denmark)

Petersen, Hanne Løhmann; Madsen, Oli B.G.

2009-01-01

This paper introduces the double travelling salesman problem with multiple stacks and presents four different metaheuristic approaches to its solution. The double TSP with multiple stacks is concerned with determining the shortest route performing pickups and deliveries in two separated networks...

Periodic oscillatory solution in delayed competitive-cooperative neural networks: A decomposition approach

International Nuclear Information System (INIS)

Yuan Kun; Cao Jinde

2006-01-01

In this paper, the problems of exponential convergence and the exponential stability of the periodic solution for a general class of non-autonomous competitive-cooperative neural networks are analyzed via the decomposition approach. The idea is to divide the connection weights into inhibitory or excitatory types and thereby to embed a competitive-cooperative delayed neural network into an augmented cooperative delay system through a symmetric transformation. Some simple necessary and sufficient conditions are derived to ensure the componentwise exponential convergence and the exponential stability of the periodic solution of the considered neural networks. These results generalize and improve the previous works, and they are easy to check and apply in practice

Comparative environmental and human health evaluations of thermolysis and solvolysis recycling technologies of carbon fiber reinforced polymer waste.

Science.gov (United States)

Khalil, Y F

2018-06-01

This quantitative research aims to compare environmental and human health impacts associated with two recycling technologies of CFRP waste. The 'baseline' recycling technology is the conventional thermolysis process via pyrolysis and the 'alternative' recycling technology is an emerging chemical treatment via solvolysis using supercritical water (SCW) to digest the thermoset matrix. Two Gate-to-Gate recycling models are developed using GaBi LCA platform. The selected functional unit (FU) is 1 kg CFRP waste and the geographical boundary of this comparative LCIA is defined to be within the U.S. The results of this comparative assessment brought to light new insights about the environmental and human health impacts of CFRP waste recycling via solvolysis using SCW and, therefore, helped close a gap in the current state of knowledge about sustainability of SCW-based solvolysis as compared to pyrolysis. Two research questions are posed to identify whether solvolysis recycling offers more environmental and human health gains relative to the conventional pyrolysis recycling. These research questions lay the basis for formulating two null hypotheses (H 0,1 and H 0,2 ) and their associated research hypotheses (H 1,1 and H 1,2 ). LCIA results interpretation included 'base case' scenarios, 'sensitivity studies,' and 'scenarios analysis.' The results revealed that: (a) recycling via solvolysis using SCW exhibits no gains in environmental and human health impacts relative to those impacts associated with recycling via pyrolysis and (b) use of natural gas in lieu of electricity for pyrolyzer's heating reduces the environmental and human health impacts by 37% (lowest) and up to 95.7% (highest). It is recommended that on-going experimental efforts that focus only on identifying the best solvent for solvolysis-based recycling should also consider quantification of the energy intensity as well as environmental and human health impacts of the proposed solvents. Copyright © 2018

A coupled PFEM-Eulerian approach for the solution of porous FSI problems

Science.gov (United States)

Larese, A.; Rossi, R.; Oñate, E.; Idelsohn, S. R.

2012-12-01

This paper aims to present a coupled solution strategy for the problem of seepage through a rockfill dam taking into account the free-surface flow within the solid as well as in its vicinity. A combination of a Lagrangian model for the structural behavior and an Eulerian approach for the fluid is used. The particle finite element method is adopted for the evaluation of the structural response, whereas an Eulerian fixed-mesh approach is employed for the fluid. The free surface is tracked by the use of a level set technique. The numerical results are validated with experiments on scale models rockfill dams.

[Pd(NH{sub 3}){sub 4}]MoO{sub 4} as a precursor for Pd–Mo-containing catalysts: Thermal behavior, X-ray analysis of the thermolysis products and related catalytic studies

Energy Technology Data Exchange (ETDEWEB)

Gubanov, Alexander I., E-mail: gubanov@niic.nsc.su [Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Akad. Lavrentiev Prospekt 3, 630090 Novosibirsk (Russian Federation); Novosibirsk State University, Pirogova str. 2, 630090 Novosibirsk (Russian Federation); Filatov, Eugeny Yu.; Semitut, Eugeny Yu.; Smolentsev, Anton I. [Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Akad. Lavrentiev Prospekt 3, 630090 Novosibirsk (Russian Federation); Novosibirsk State University, Pirogova str. 2, 630090 Novosibirsk (Russian Federation); Snytnikov, Pavel V.; Potemkin, Dmitry I. [Novosibirsk State University, Pirogova str. 2, 630090 Novosibirsk (Russian Federation); Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Akad. Lavrentiev Prospekt 5, 630090 Novosibirsk (Russian Federation); Korenev, Sergey V. [Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Akad. Lavrentiev Prospekt 3, 630090 Novosibirsk (Russian Federation); Novosibirsk State University, Pirogova str. 2, 630090 Novosibirsk (Russian Federation)

2013-08-20

Highlights: • [Pd(NH{sub 3}){sub 4}]MoO{sub 4} as a precursor for Pd–Mo-containing catalysts. • Different products are formed depending on atmosphere of thermal decomposition. • Thermolysis in He atmosphere affords finely mixed two-phase nanosized system Pd–MoO{sub 2}. • Pd–MoO{sub 2} system can be a promising catalyst both in pure and supported form. - Abstract: Compound [Pd(NH{sub 3}){sub 4}]MoO{sub 4} (1) has been synthesized and characterized by IR spectroscopy, analytical data, powder and single-crystal X-ray crystallography. Thermal properties of 1 have been examined by thermogravimetry. Powder X-ray diffraction has been applied to investigate the nanosized products of thermal decomposition of the precursor in hydrogen (Pd–Mo) and helium (Pd–MoO{sub 2}) atmospheres. Pd–Mo catalysts supported with γ-Al{sub 2}O{sub 3} have been tested in oxidation of CO and H{sub 2} mixtures.

A General Approach to Access Morphologies of Polyoxometalates in Solution by Using SAXS: An Ab Initio Modeling Protocol.

Science.gov (United States)

Li, Mu; Wang, Weiyu; Yin, Panchao

2018-05-02

Herein, we reported a general protocol for an ab initio modeling approach to deduce structure information of polyoxometalates (POMs) in solutions from scattering data collected by the small-angle X-ray scattering (SAXS) technique. To validate the protocol, the morphologies of a serious of known POMs in either aqueous or organic solvents were analyzed. The obtained particle morphologies were compared and confirmed with previous reported crystal structures. To extend the feasibility of the protocol to an unknown system of aqueous solutions of Na 2 MoO 4 with the pH ranging from -1 to 8.35, the formation of {Mo 36 } clusters was probed, identified, and confirmed by SAXS. The approach was further optimized with a multi-processing capability to achieve fast analysis of experimental data, thereby, facilitating in situ studies of formations of POMs in solutions. The advantage of this approach is to generate intuitive 3D models of POMs in solutions without confining information such as symmetries and possible sizes. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Theoretical aspects of pressure and solute denaturation of proteins: A Kirkwood-buff-theory approach

Science.gov (United States)

Ben-Naim, Arieh

2012-12-01

A new approach to the problem of pressure-denaturation (PD) and solute-denaturation (SD) of proteins is presented. The problem is formulated in terms of Le Chatelier principle, and a solution is sought in terms of the Kirkwood-Buff theory of solutions. It is found that both problems have one factor in common; the excluded volumes of the folded and the unfolded forms with respect to the solvent molecules. It is shown that solvent-induced effects operating on hydrophilic groups along the protein are probably the main reason for PD. On the other hand, the SD depends on the preferential solvation of the folded and the unfolded forms with respect to solvent and co-solvent molecules.

A new approach to study cadmium complexes with oxalic acid in soil solution.

Science.gov (United States)

Dytrtová, Jana Jaklová; Jakl, Michal; Sestáková, Ivana; Zins, Emilie-Laure; Schröder, Detlef; Navrátil, Tomáš

2011-05-05

This study presents a new analytical approach for the determination of heavy metals complexed to low-molecular-weight-organic acids in soil solutions, which combines the sensitivity of differential pulse anodic stripping voltammetry (DPASV) with the molecular insight gained by electrospray ionization mass spectrometry (ESI-MS). The combination of these analytical methods allows the investigation of such complexes in complex matrixes. On the voltammograms of the soil solutions, in addition to the expected complexes of oxalic acid with cadmium and lead, respectively, also peaks belonging to mixed complexes of cadmium, lead, and oxalic acid (OAH(2)) were observed. In order to verify the possible formation of complexes with OAH(2), aqueous solutions of OAH(2) with traces of Cd(II) were investigated as model systems. Signals corresponding to several distinct molecular complexes between cadmium and oxalic acid were detected in the model solutions using negative-ion ESI-MS, which follow the general formula [Cd(n)(X,Y)((2n+1))](-), where n is the number of cadmium atoms, X=Cl(-), and Y=OAH(-). Some of these complexes were also identified in the ESI mass spectra taken from the soil solutions. Copyright © 2011 Elsevier B.V. All rights reserved.

A new approach to study cadmium complexes with oxalic acid in soil solution

International Nuclear Information System (INIS)

Jaklova Dytrtova, Jana; Jakl, Michal; Sestakova, Ivana; Zins, Emilie-Laure; Schroeder, Detlef; Navratil, Tomas

2011-01-01

This study presents a new analytical approach for the determination of heavy metals complexed to low-molecular-weight-organic acids in soil solutions, which combines the sensitivity of differential pulse anodic stripping voltammetry (DPASV) with the molecular insight gained by electrospray ionization mass spectrometry (ESI-MS). The combination of these analytical methods allows the investigation of such complexes in complex matrixes. On the voltammograms of the soil solutions, in addition to the expected complexes of oxalic acid with cadmium and lead, respectively, also peaks belonging to mixed complexes of cadmium, lead, and oxalic acid (OAH 2 ) were observed. In order to verify the possible formation of complexes with OAH 2 , aqueous solutions of OAH 2 with traces of Cd(II) were investigated as model systems. Signals corresponding to several distinct molecular complexes between cadmium and oxalic acid were detected in the model solutions using negative-ion ESI-MS, which follow the general formula [Cd n (X,Y) (2n+1) ] - , where n is the number of cadmium atoms, X = Cl - , and Y = OAH - . Some of these complexes were also identified in the ESI mass spectra taken from the soil solutions.

A new approach to study cadmium complexes with oxalic acid in soil solution

Energy Technology Data Exchange (ETDEWEB)

Jaklova Dytrtova, Jana, E-mail: dytrtova@uochb.cas.cz [Institute of Organic Chemistry and Biochemistry of the AS CR, v.v.i., Flemingovo namesti 2, 16610 Prague 6 (Czech Republic); Jakl, Michal [Department of Agro-Environmental Chemistry and Plant Nutrition, Faculty of Agrobiology, Food and Natural Resources, Czech University of Life Sciences, Kamycka 129, 16521 Prague - Suchdol (Czech Republic); Sestakova, Ivana [J. Heyrovsky Institute of Physical Chemistry of the AS CR, v.v.i., Dolejskova 3, 182 23 Prague 8 (Czech Republic); Zins, Emilie-Laure; Schroeder, Detlef [Institute of Organic Chemistry and Biochemistry of the AS CR, v.v.i., Flemingovo namesti 2, 16610 Prague 6 (Czech Republic); Navratil, Tomas [J. Heyrovsky Institute of Physical Chemistry of the AS CR, v.v.i., Dolejskova 3, 182 23 Prague 8 (Czech Republic)

2011-05-05

This study presents a new analytical approach for the determination of heavy metals complexed to low-molecular-weight-organic acids in soil solutions, which combines the sensitivity of differential pulse anodic stripping voltammetry (DPASV) with the molecular insight gained by electrospray ionization mass spectrometry (ESI-MS). The combination of these analytical methods allows the investigation of such complexes in complex matrixes. On the voltammograms of the soil solutions, in addition to the expected complexes of oxalic acid with cadmium and lead, respectively, also peaks belonging to mixed complexes of cadmium, lead, and oxalic acid (OAH{sub 2}) were observed. In order to verify the possible formation of complexes with OAH{sub 2}, aqueous solutions of OAH{sub 2} with traces of Cd(II) were investigated as model systems. Signals corresponding to several distinct molecular complexes between cadmium and oxalic acid were detected in the model solutions using negative-ion ESI-MS, which follow the general formula [Cd{sub n}(X,Y){sub (2n+1)}]{sup -}, where n is the number of cadmium atoms, X = Cl{sup -}, and Y = OAH{sup -}. Some of these complexes were also identified in the ESI mass spectra taken from the soil solutions.

Exact traveling wave solutions of the KP-BBM equation by using the new approach of generalized (G'/G)-expansion method.

Science.gov (United States)

Alam, Md Nur; Akbar, M Ali

2013-01-01

The new approach of the generalized (G'/G)-expansion method is an effective and powerful mathematical tool in finding exact traveling wave solutions of nonlinear evolution equations (NLEEs) in science, engineering and mathematical physics. In this article, the new approach of the generalized (G'/G)-expansion method is applied to construct traveling wave solutions of the Kadomtsev-Petviashvili-Benjamin-Bona-Mahony (KP-BBM) equation. The solutions are expressed in terms of the hyperbolic functions, the trigonometric functions and the rational functions. By means of this scheme, we found some new traveling wave solutions of the above mentioned equation.

Solution of the neutron point kinetics equations with temperature feedback effects applying the polynomial approach method

International Nuclear Information System (INIS)

Tumelero, Fernanda; Petersen, Claudio Z.; Goncalves, Glenio A.; Lazzari, Luana

2015-01-01

In this work, we present a solution of the Neutron Point Kinetics Equations with temperature feedback effects applying the Polynomial Approach Method. For the solution, we consider one and six groups of delayed neutrons precursors with temperature feedback effects and constant reactivity. The main idea is to expand the neutron density, delayed neutron precursors and temperature as a power series considering the reactivity as an arbitrary function of the time in a relatively short time interval around an ordinary point. In the first interval one applies the initial conditions of the problem and the analytical continuation is used to determine the solutions of the next intervals. With the application of the Polynomial Approximation Method it is possible to overcome the stiffness problem of the equations. In such a way, one varies the time step size of the Polynomial Approach Method and performs an analysis about the precision and computational time. Moreover, we compare the method with different types of approaches (linear, quadratic and cubic) of the power series. The answer of neutron density and temperature obtained by numerical simulations with linear approximation are compared with results in the literature. (author)

Solution of the neutron point kinetics equations with temperature feedback effects applying the polynomial approach method

Energy Technology Data Exchange (ETDEWEB)

Tumelero, Fernanda, E-mail: fernanda.tumelero@yahoo.com.br [Universidade Federal do Rio Grande do Sul (UFRGS), Porto Alegre, RS (Brazil). Programa de Pos-Graduacao em Engenharia Mecanica; Petersen, Claudio Z.; Goncalves, Glenio A.; Lazzari, Luana, E-mail: claudiopeteren@yahoo.com.br, E-mail: gleniogoncalves@yahoo.com.br, E-mail: luana-lazzari@hotmail.com [Universidade Federal de Pelotas (DME/UFPEL), Capao do Leao, RS (Brazil). Instituto de Fisica e Matematica

2015-07-01

In this work, we present a solution of the Neutron Point Kinetics Equations with temperature feedback effects applying the Polynomial Approach Method. For the solution, we consider one and six groups of delayed neutrons precursors with temperature feedback effects and constant reactivity. The main idea is to expand the neutron density, delayed neutron precursors and temperature as a power series considering the reactivity as an arbitrary function of the time in a relatively short time interval around an ordinary point. In the first interval one applies the initial conditions of the problem and the analytical continuation is used to determine the solutions of the next intervals. With the application of the Polynomial Approximation Method it is possible to overcome the stiffness problem of the equations. In such a way, one varies the time step size of the Polynomial Approach Method and performs an analysis about the precision and computational time. Moreover, we compare the method with different types of approaches (linear, quadratic and cubic) of the power series. The answer of neutron density and temperature obtained by numerical simulations with linear approximation are compared with results in the literature. (author)

Designing e-learning solutions with a client centred approach

DEFF Research Database (Denmark)

Ørngreen, Rikke; Nielsen, Janni; Levinsen, Karin

2008-01-01

  This paper claims that the strategies applied in designing e-learning solutions tend to focus on how to proceed after the precondition, e.g., learners requirements, pedagogical choice, etc., have been decided upon. Investigating the HCI research field, we find that the methodological approaches...... as the organisation that has initiated the e-learning project and needs to manage the e-learning system after its development. Through the Client Centred Design and in close collaboration with the client, three strategic issues are uncovered and strategic models are presented for each. These models are complementary...... perspectives in a Client Centred framework that is useable as the starting point for others in developing large scale e-learning projects....

A hybrid computational-experimental approach for automated crystal structure solution

Science.gov (United States)

Meredig, Bryce; Wolverton, C.

2013-02-01

Crystal structure solution from diffraction experiments is one of the most fundamental tasks in materials science, chemistry, physics and geology. Unfortunately, numerous factors render this process labour intensive and error prone. Experimental conditions, such as high pressure or structural metastability, often complicate characterization. Furthermore, many materials of great modern interest, such as batteries and hydrogen storage media, contain light elements such as Li and H that only weakly scatter X-rays. Finally, structural refinements generally require significant human input and intuition, as they rely on good initial guesses for the target structure. To address these many challenges, we demonstrate a new hybrid approach, first-principles-assisted structure solution (FPASS), which combines experimental diffraction data, statistical symmetry information and first-principles-based algorithmic optimization to automatically solve crystal structures. We demonstrate the broad utility of FPASS to clarify four important crystal structure debates: the hydrogen storage candidates MgNH and NH3BH3; Li2O2, relevant to Li-air batteries; and high-pressure silane, SiH4.

Siemens IT solutions for power sector. PROFIT solutions

International Nuclear Information System (INIS)

Lunter, P.

2004-01-01

The cost reduction, flexibility and revenue increase, potential exploitation, productivity increase, and business opportunities exploitation - that is all what can be required in the races for the promonent positioning on the electricity power market. These requirements can be realized by the sophisticated IT solutions hand-tailored to the special requirements of the electric power producers and tradesmen. This approach makes it possible to achieve greater profit. Our solutions 'PROFIT Solutions', that are symbiosis of the most progressive information technologies and the power plant techniques of the company Siemens, satisfy submitted specifications in substantial measure. The system solutions 'PROFIT Solutions' comprise three solution groups: process, operation a business. The solutions of the group 'IT Process Solutions' increase flexibility and manoeuvrability of equipment, improve the efficiency and contribute to more economical operation of the power generation. Solutions 'IT Process Solutions' simplify and shorten the period of power cycles and conduce to higher labour productivity. Solutions group 'IT Process Solutions' approaches equipment to the market - supports the profit strategies, helps quickly and expertly to determine and predict hazards. The extension PROFIT Cockpit means the nuance to the solutions world 'PROFIT Solutions'. The survey about the whole installation is within reach at the simple touch of a button. It is possible to compile the total system part by part from single solutions 'PROFIT Solutions'. As a matter of fact all single parts can be interconnected with already existing solutions. Routines 'PROFIT Solutions' cooperate with all modern control systems. (author)

Adjusted permutation method for multiple attribute decision making with meta-heuristic solution approaches

Directory of Open Access Journals (Sweden)

Hossein Karimi

2011-04-01

Full Text Available The permutation method of multiple attribute decision making has two significant deficiencies: high computational time and wrong priority output in some problem instances. In this paper, a novel permutation method called adjusted permutation method (APM is proposed to compensate deficiencies of conventional permutation method. We propose Tabu search (TS and particle swarm optimization (PSO to find suitable solutions at a reasonable computational time for large problem instances. The proposed method is examined using some numerical examples to evaluate the performance of the proposed method. The preliminary results show that both approaches provide competent solutions in relatively reasonable amounts of time while TS performs better to solve APM.

Efficient and Safe Chemical Gas Generators with Nanocomposite Reactive Materials

Science.gov (United States)

2015-11-30

thermolysis and hydrolysis . This reaction also releases hydrogen from water, thus increasing the total hydrogen yield. The investigation of iodine...for AB thermolysis and hydrolysis . This reaction also releases hydrogen from water, thus increasing the total hydrogen yield. Experiments have... hydrogen yield. The isotopic tests have shown that AB participates in two parallel processes − thermolysis and hydrolysis . Because of this, as much as 88

Effectiveness of solution focus brief counseling approach (SFBC in developing student career adaptability

Directory of Open Access Journals (Sweden)

Mulawarman Mulawarman

2016-12-01

Full Text Available Career adaptability is the preparedness role in work and adjustman to changes in working situation in the future. The purpose of this study was to examine Solution Focused Brief Counseling (SFBC approach in developing career adaptability of students.The method used in this study was a mix method . Subjects selected through a purposive sampling method that is focused on graduate students at the beginning of the semester with a major in Guidance and Counseling Faculty of Education, Semarang State University. Career adaptability in this study consists of four dimensions, concern, control, curiosity and confidence. Stages of Solution Focused Brief Counseling (SFBC implemented include establishing relationships, Identifying a solvable complaint, Establishing goals, Designing and Implementing Intervention, and termination, evaluation, and follow-up. The results of this study showed Solution Focused Brief Counseling (SFBC is effective in improving the adaptability of student career both qualitatively and quantitatively.

New approach development for solution of cloning results detection problem in lossy saved digital image

Directory of Open Access Journals (Sweden)

A.A. Kobozeva

2016-09-01

Full Text Available The problem of detection of the digital image falsification results performed by cloning is considered – one of the most often used program tools implemented in all modern graphic editors. Aim: The aim of the work is further development of approach to the solution of a cloning detection problem having the cloned image saved in a lossy format, offered by authors earlier. Materials and Methods: Further development of a new approach to the solution of a problem of cloning results detection in the digital image is presented. Approach is based on the accounting of small changes of cylindrical body volume with the generatrix, that is parallel to the OZ axis, bounded above by the interpolating function plot for a matrix of brightness of the analyzed image, and bounded below by the XOY plane, during the compression process. Results: Adaptation of the offered approach to conditions of the cloned image compression with the arbitrary factor of compression quality is carried out (compression ratio. The approach solvency in the conditions of the cloned image compression according to the algorithms different from the JPEG standard is shown: JPEG2000, compression with use of low-rank approximations of the image matrix (matrix blocks. The results of computational experiment are given. It is shown that the developed approach can be used to detect the results of cloning in digital video in the conditions of lossy compression after cloning process.

Evaluating Emergency Response Solutions for Sustainable Community Development by Using Fuzzy Multi-Criteria Group Decision Making Approaches: IVDHF-TOPSIS and IVDHF-VIKOR

Directory of Open Access Journals (Sweden)

Junling Zhang

2016-03-01

Full Text Available Emergency management is vital in implementing sustainable community development, for which community planning must include emergency response solutions to potential natural and manmade hazards. To help maintain such solution repository, we investigate effective fuzzy multi-criteria group decision making (FMCGDM approaches for the complex problems of evaluating alternative emergency response solutions, where weights for decision makers and criteria are unknown due to problem complexity. We employ interval-valued dual hesitant fuzzy (IVDHF set to address decision hesitancy more effectively. Based on IVDHF assessments, we develop a deviation maximizing model to compute criteria weights and another compatibility maximizing model to calculate weights for decision makers. Then, two ideal-solution-based FMCGDM approaches are proposed: (i by introducing a synthesized IVDHF group decision matrix into TOPSIS, we develop an IVDHF-TOPSIS approach for fuzzy group settings; (ii when emphasizing both maximum group utility and minimum individual regret, we extend VIKOR to develop an IVDHF-VIKOR approach, where the derived decision makers’ weights are utilized to obtain group decision matrix and the determined criteria weights are integrated to reflect the relative importance of distances from the compromised ideal solution. Compared with aggregation-operators-based approach, IVDHF-TOPSIS and IVDHF-VIKOR can alleviate information loss and computational complexity. Numerical examples have validated the effectiveness of the proposed approaches.

The simple solutions concept: a useful approach to estimate deviation from ideality in solvent extraction

International Nuclear Information System (INIS)

Sorel, C.; Pacary, V.

2010-01-01

The solvent extraction systems devoted to uranium purification from crude ore to spent fuel involve concentrated solutions in which deviation from ideality can not be neglected. The Simple Solution Concept based on the behaviour of isopiestic solutions has been applied to quantify the activity coefficients of metals and acids in the aqueous phase in equilibrium with the organic phase. This approach has been validated on various solvent extraction systems such as trialkylphosphates, malonamides or acidic extracting agents both on batch experiments and counter-current tests. Moreover, this concept has been successfully used to estimate the aqueous density which is useful to quantify the variation of volume and to assess critical parameters such as the number density of nuclides. (author)

Computational Approach for Studying Optical Properties of DNA Systems in Solution

DEFF Research Database (Denmark)

Nørby, Morten Steen; Svendsen, Casper Steinmann; Olsen, Jógvan Magnus Haugaard

2016-01-01

In this paper we present a study of the methodological aspects regarding calculations of optical properties for DNA systems in solution. Our computational approach will be built upon a fully polarizable QM/MM/Continuum model within a damped linear response theory framework. In this approach...... the environment is given a highly advanced description in terms of the electrostatic potential through the polarizable embedding model. Furthermore, bulk solvent effects are included in an efficient manner through a conductor-like screening model. With the aim of reducing the computational cost we develop a set...... of averaged partial charges and distributed isotropic dipole-dipole polarizabilities for DNA suitable for describing the classical region in ground-state and excited-state calculations. Calculations of the UV-spectrum of the 2-aminopurine optical probe embedded in a DNA double helical structure are presented...

Differentiation of the molecular structure of nitro compounds as the basis for simulation of their thermal destruction processes

Energy Technology Data Exchange (ETDEWEB)

Korolev, V L; Pivina, Tatyana S; Sheremetev, Aleksei B [N.D.Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow (Russian Federation); Porollo, A A [University of Cincinnati, Cincinnati (United States); Petukhova, T V; Ivshin, Viktor P [Mari State University, Yoshkar-Ola (Russian Federation)

2009-10-31

Data on the experimental and theoretical studies of thermal decomposition of C- and N-nitro compounds of aliphatic, alicyclic, aromatic and heteroaromatic compounds, which formed the grounds for the development of ab initio approach to the prediction of the mechanisms of thermolysis of energetic compounds, are described systematically. The relationships between the structures and thermolysis mechanisms of compounds based on differentiation of the structural fragments depending on the functional surrounding of nitro groups are identified. Using the RRN (Recombination Reaction Network) strategy and original CASB (Computer Assisted Structure Building) software, full reaction mechanisms for the thermal destruction of nitro compounds at different thermal decomposition levels (including extensive ones) are simulated. The full set of possible mechanisms of thermal decomposition of 38 chemically different nitro compounds is presented

Traveling wave solutions of the Boussinesq equation via the new approach of generalized (G'/G)-expansion method.

Science.gov (United States)

Alam, Md Nur; Akbar, M Ali; Roshid, Harun-Or-

2014-01-01

Exact solutions of nonlinear evolution equations (NLEEs) play a vital role to reveal the internal mechanism of complex physical phenomena. In this work, the exact traveling wave solutions of the Boussinesq equation is studied by using the new generalized (G'/G)-expansion method. Abundant traveling wave solutions with arbitrary parameters are successfully obtained by this method and the wave solutions are expressed in terms of the hyperbolic, trigonometric, and rational functions. It is shown that the new approach of generalized (G'/G)-expansion method is a powerful and concise mathematical tool for solving nonlinear partial differential equations in mathematical physics and engineering. 05.45.Yv, 02.30.Jr, 02.30.Ik.

Evaluation of near-wall solution approaches for large-eddy simulations of flow in a centrifugal pump impeller

Directory of Open Access Journals (Sweden)

Zhi-Feng Yao

2016-01-01

Full Text Available The turbulent flow in a centrifugal pump impeller is bounded by complex surfaces, including blades, a hub and a shroud. The primary challenge of the flow simulation arises from the generation of a boundary layer between the surface of the impeller and the moving fluid. The principal objective is to evaluate the near-wall solution approaches that are typically used to deal with the flow in the boundary layer for the large-eddy simulation (LES of a centrifugal pump impeller. Three near-wall solution approaches –the wall-function approach, the wall-resolved approach and the hybrid Reynolds averaged Navier–Stoke (RANS and LES approach – are tested. The simulation results are compared with experimental results conducted through particle imaging velocimetry (PIV and laser Doppler velocimetry (LDV. It is found that the wall-function approach is more sparing of computational resources, while the other two approaches have the important advantage of providing highly accurate boundary layer flow prediction. The hybrid RANS/LES approach is suitable for predicting steady-flow features, such as time-averaged velocities and hydraulic losses. Despite the fact that the wall-resolved approach is expensive in terms of computing resources, it exhibits a strong ability to capture a small-scale vortex and predict instantaneous velocity in the near-wall region in the impeller. The wall-resolved approach is thus recommended for the transient simulation of flows in centrifugal pump impellers.

A Simple Approach to Derive a Novel N-Soliton Solution for a (3+1)-Dimensional Nonlinear Evolution Equation

International Nuclear Information System (INIS)

Wu Jianping

2010-01-01

Based on the Hirota bilinear form, a simple approach without employing the standard perturbation technique, is presented for constructing a novel N-soliton solution for a (3+1)-dimensional nonlinear evolution equation. Moreover, the novel N-soliton solution is shown to have resonant behavior with the aid of Mathematica. (general)

On symmetries and exact solutions of the Einstein–Maxwell field equations via the symmetry approach

International Nuclear Information System (INIS)

Kaur, Lakhveer; Gupta, R K

2013-01-01

Using the Lie symmetry approach, we have examined herein the system of partial differential equations corresponding to the Einstein–Maxwell equations for a static axially symmetric spacetime. The method used reduces the system of partial differential equations to a system of ordinary differential equations according to the Lie symmetry admitted. In particular, we found the relevant system of ordinary differential equations is all optimal subgroups. The system of ordinary differential equations is further solved in general to obtain exact solutions. Several new physically important families of exact solutions are derived. (paper)

Hibernate Recipes A Problem-Solution Approach

CERN Document Server

Mak, Gary

2010-01-01

Hibernate continues to be the most popular out-of-the-box framework solution for Java Persistence and data/database accessibility techniques and patterns. It is used for e-commerce-based web applications as well as heavy-duty transactional systems for the enterprise. Gary Mak, the author of the best-selling Spring Recipes, now brings you Hibernate Recipes. This book contains a collection of code recipes and templates for learning and building Hibernate solutions for you and your clients. This book is your pragmatic day-to-day reference and guide for doing all things involving Hibernate. There

A spatially adaptive grid-refinement approach for the finite element solution of the even-parity Boltzmann transport equation

International Nuclear Information System (INIS)

Mirza, Anwar M.; Iqbal, Shaukat; Rahman, Faizur

2007-01-01

A spatially adaptive grid-refinement approach has been investigated to solve the even-parity Boltzmann transport equation. A residual based a posteriori error estimation scheme has been utilized for checking the approximate solutions for various finite element grids. The local particle balance has been considered as an error assessment criterion. To implement the adaptive approach, a computer program ADAFENT (adaptive finite elements for neutron transport) has been developed to solve the second order even-parity Boltzmann transport equation using K + variational principle for slab geometry. The program has a core K + module which employs Lagrange polynomials as spatial basis functions for the finite element formulation and Legendre polynomials for the directional dependence of the solution. The core module is called in by the adaptive grid generator to determine local gradients and residuals to explore the possibility of grid refinements in appropriate regions of the problem. The a posteriori error estimation scheme has been implemented in the outer grid refining iteration module. Numerical experiments indicate that local errors are large in regions where the flux gradients are large. A comparison of the spatially adaptive grid-refinement approach with that of uniform meshing approach for various benchmark cases confirms its superiority in greatly enhancing the accuracy of the solution without increasing the number of unknown coefficients. A reduction in the local errors of the order of 10 2 has been achieved using the new approach in some cases

A spatially adaptive grid-refinement approach for the finite element solution of the even-parity Boltzmann transport equation

Energy Technology Data Exchange (ETDEWEB)

Mirza, Anwar M. [Department of Computer Science, National University of Computer and Emerging Sciences, NUCES-FAST, A.K. Brohi Road, H-11, Islamabad (Pakistan)], E-mail: anwar.m.mirza@gmail.com; Iqbal, Shaukat [Faculty of Computer Science and Engineering, Ghulam Ishaq Khan (GIK) Institute of Engineering Science and Technology, Topi-23460, Swabi (Pakistan)], E-mail: shaukat@giki.edu.pk; Rahman, Faizur [Department of Physics, Allama Iqbal Open University, H-8 Islamabad (Pakistan)

2007-07-15

A spatially adaptive grid-refinement approach has been investigated to solve the even-parity Boltzmann transport equation. A residual based a posteriori error estimation scheme has been utilized for checking the approximate solutions for various finite element grids. The local particle balance has been considered as an error assessment criterion. To implement the adaptive approach, a computer program ADAFENT (adaptive finite elements for neutron transport) has been developed to solve the second order even-parity Boltzmann transport equation using K{sup +} variational principle for slab geometry. The program has a core K{sup +} module which employs Lagrange polynomials as spatial basis functions for the finite element formulation and Legendre polynomials for the directional dependence of the solution. The core module is called in by the adaptive grid generator to determine local gradients and residuals to explore the possibility of grid refinements in appropriate regions of the problem. The a posteriori error estimation scheme has been implemented in the outer grid refining iteration module. Numerical experiments indicate that local errors are large in regions where the flux gradients are large. A comparison of the spatially adaptive grid-refinement approach with that of uniform meshing approach for various benchmark cases confirms its superiority in greatly enhancing the accuracy of the solution without increasing the number of unknown coefficients. A reduction in the local errors of the order of 10{sup 2} has been achieved using the new approach in some cases.

Choosing the Right Solution Approach: The Crucial Role of Situational Knowledge in Electricity and Magnetism

Science.gov (United States)

Savelsbergh, Elwin R.; de Jong, Ton; Ferguson-Hessler, Monica G. M.

2011-01-01

Novice problem solvers are rather sensitive to surface problem features, and they often resort to trial and error formula matching rather than identifying an appropriate solution approach. These observations have been interpreted to imply that novices structure their knowledge according to surface features rather than according to problem type…

A Solution-Based Approach for Mo-99 Production: Considerations for Nitrate versus Sulfate Media

Directory of Open Access Journals (Sweden)

Amanda J. Youker

2013-01-01

Full Text Available Molybdenum-99 is the parent of Technetium-99m, which is used in nearly 80% of all nuclear medicine procedures. The medical community has been plagued by Mo-99 shortages due to aging reactors, such as the NRU (National Research Universal reactor in Canada. There are currently no US producers of Mo-99, and NRU is scheduled for shutdown in 2016, which means that another Mo-99 shortage is imminent unless a potential domestic Mo-99 producer fills the void. Argonne National Laboratory is assisting two potential domestic suppliers of Mo-99 by examining the effects of a uranyl nitrate versus a uranyl sulfate target solution configuration on Mo-99 production. Uranyl nitrate solutions are easier to prepare and do not generate detectable amounts of peroxide upon irradiation, but a high radiation field can lead to a large increase in pH, which can lead to the precipitation of fission products and uranyl hydroxides. Uranyl sulfate solutions are more difficult to prepare, and enough peroxide is generated during irradiation to cause precipitation of uranyl peroxide, but this can be prevented by adding a catalyst to the solution. A titania sorbent can be used to recover Mo-99 from a highly concentrated uranyl nitrate or uranyl sulfate solution; however, different approaches must be taken to prevent precipitation during Mo-99 production.

Calcium ferrite formation from the thermolysis of calcium tris (maleato)

Indian Academy of Sciences (India)

For preparing calcium ferrite, calcium tris (maleato) ferrate(III) precursor was prepared by mixing aqueous solutions of iron(III) maleate, calcium maleate and maleic acid. Various physico-chemical techniques i.e. TG, DTG, DTA, Mössbauer, XRD, IR etc have been used to study the decomposition behaviour from ambient to ...

Stochastic level-set variational implicit-solvent approach to solute-solvent interfacial fluctuations

Energy Technology Data Exchange (ETDEWEB)

Zhou, Shenggao, E-mail: sgzhou@suda.edu.cn, E-mail: bli@math.ucsd.edu [Department of Mathematics and Mathematical Center for Interdiscipline Research, Soochow University, 1 Shizi Street, Jiangsu, Suzhou 215006 (China); Sun, Hui; Cheng, Li-Tien [Department of Mathematics, University of California, San Diego, La Jolla, California 92093-0112 (United States); Dzubiella, Joachim [Soft Matter and Functional Materials, Helmholtz-Zentrum Berlin, 14109 Berlin, Germany and Institut für Physik, Humboldt-Universität zu Berlin, 12489 Berlin (Germany); Li, Bo, E-mail: sgzhou@suda.edu.cn, E-mail: bli@math.ucsd.edu [Department of Mathematics and Quantitative Biology Graduate Program, University of California, San Diego, La Jolla, California 92093-0112 (United States); McCammon, J. Andrew [Department of Chemistry and Biochemistry, Department of Pharmacology, Howard Hughes Medical Institute, University of California, San Diego, La Jolla, California 92093-0365 (United States)

2016-08-07

Recent years have seen the initial success of a variational implicit-solvent model (VISM), implemented with a robust level-set method, in capturing efficiently different hydration states and providing quantitatively good estimation of solvation free energies of biomolecules. The level-set minimization of the VISM solvation free-energy functional of all possible solute-solvent interfaces or dielectric boundaries predicts an equilibrium biomolecular conformation that is often close to an initial guess. In this work, we develop a theory in the form of Langevin geometrical flow to incorporate solute-solvent interfacial fluctuations into the VISM. Such fluctuations are crucial to biomolecular conformational changes and binding process. We also develop a stochastic level-set method to numerically implement such a theory. We describe the interfacial fluctuation through the “normal velocity” that is the solute-solvent interfacial force, derive the corresponding stochastic level-set equation in the sense of Stratonovich so that the surface representation is independent of the choice of implicit function, and develop numerical techniques for solving such an equation and processing the numerical data. We apply our computational method to study the dewetting transition in the system of two hydrophobic plates and a hydrophobic cavity of a synthetic host molecule cucurbit[7]uril. Numerical simulations demonstrate that our approach can describe an underlying system jumping out of a local minimum of the free-energy functional and can capture dewetting transitions of hydrophobic systems. In the case of two hydrophobic plates, we find that the wavelength of interfacial fluctuations has a strong influence to the dewetting transition. In addition, we find that the estimated energy barrier of the dewetting transition scales quadratically with the inter-plate distance, agreeing well with existing studies of molecular dynamics simulations. Our work is a first step toward the

Analytical Solution of Multicompartment Solute Kinetics for Hemodialysis

Directory of Open Access Journals (Sweden)

Przemysław Korohoda

2013-01-01

Full Text Available Objective. To provide an exact solution for variable-volume multicompartment kinetic models with linear volume change, and to apply this solution to a 4-compartment diffusion-adjusted regional blood flow model for both urea and creatinine kinetics in hemodialysis. Methods. A matrix-based approach applicable to linear models encompassing any number of compartments is presented. The procedure requires the inversion of a square matrix and the computation of its eigenvalues λ, assuming they are all distinct. This novel approach bypasses the evaluation of the definite integral to solve the inhomogeneous ordinary differential equation. Results. For urea two out of four eigenvalues describing the changes of concentrations in time are about 105 times larger than the other eigenvalues indicating that the 4-compartment model essentially reduces to the 2-compartment regional blood flow model. In case of creatinine, however, the distribution of eigenvalues is more balanced (a factor of 102 between the largest and the smallest eigenvalue indicating that all four compartments contribute to creatinine kinetics in hemodialysis. Interpretation. Apart from providing an exact analytic solution for practical applications such as the identification of relevant model and treatment parameters, the matrix-based approach reveals characteristic details on model symmetry and complexity for different solutes.

Analytic hierarchy process-based approach for selecting a Pareto-optimal solution of a multi-objective, multi-site supply-chain planning problem

Science.gov (United States)

Ayadi, Omar; Felfel, Houssem; Masmoudi, Faouzi

2017-07-01

The current manufacturing environment has changed from traditional single-plant to multi-site supply chain where multiple plants are serving customer demands. In this article, a tactical multi-objective, multi-period, multi-product, multi-site supply-chain planning problem is proposed. A corresponding optimization model aiming to simultaneously minimize the total cost, maximize product quality and maximize the customer satisfaction demand level is developed. The proposed solution approach yields to a front of Pareto-optimal solutions that represents the trade-offs among the different objectives. Subsequently, the analytic hierarchy process method is applied to select the best Pareto-optimal solution according to the preferences of the decision maker. The robustness of the solutions and the proposed approach are discussed based on a sensitivity analysis and an application to a real case from the textile and apparel industry.

Directional approach to spatial structure of solutions to the Navier–Stokes equations in the plane

International Nuclear Information System (INIS)

Konieczny, P; Mucha, P B

2011-01-01

We investigate a steady flow of incompressible fluid in the plane. The motion is governed by the Navier–Stokes equations with prescribed velocity u ∞ at infinity. The main result shows the existence of unique solutions for arbitrary force, provided sufficient largeness of u ∞ . Furthermore a spatial structure of the solution is obtained in comparison with the Oseen flow. A key element of our new approach is based on a setting which treats the direction of the flow as the time direction. The analysis is done in the framework of the Fourier transform taken in one (perpendicular) direction and a special choice of function spaces which take into account the inhomogeneous character of the symbol of the Oseen system. From that point of view our technique can be used as an effective tool in examining spatial asymptotics of solutions to other systems modelled by elliptic equations

Nano-particle drag prediction at low Reynolds number using a direct Boltzmann-BGK solution approach

Science.gov (United States)

Evans, B.

2018-01-01

This paper outlines a novel approach for solution of the Boltzmann-BGK equation describing molecular gas dynamics applied to the challenging problem of drag prediction of a 2D circular nano-particle at transitional Knudsen number (0.0214) and low Reynolds number (0.25-2.0). The numerical scheme utilises a discontinuous-Galerkin finite element discretisation for the physical space representing the problem particle geometry and a high order discretisation for molecular velocity space describing the molecular distribution function. The paper shows that this method produces drag predictions that are aligned well with the range of drag predictions for this problem generated from the alternative numerical approaches of molecular dynamics codes and a modified continuum scheme. It also demonstrates the sensitivity of flow-field solutions and therefore drag predictions to the wall absorption parameter used to construct the solid wall boundary condition used in the solver algorithm. The results from this work has applications in fields ranging from diagnostics and therapeutics in medicine to the fields of semiconductors and xerographics.

Toward enhanced hydrogen generation from water using oxygen permeating LCF membranes

KAUST Repository

Wu, Xiao-Yu; Chang, Le; Uddi, Mruthunjaya; Kirchen, Patrick; Ghoniem, Ahmed F.

2015-01-01

and flow rates on the feed and sweep sides on the water thermolysis rate and oxygen flux. A single step reaction mechanism is proposed for surface reactions, and three-resistance permeation models are derived. Results show that water thermolysis

A SUPPORT VECTOR MACHINE APPROACH FOR DEVELOPING TELEMEDICINE SOLUTIONS: MEDICAL DIAGNOSIS

Directory of Open Access Journals (Sweden)

Mihaela GHEORGHE

2015-06-01

Full Text Available Support vector machine represents an important tool for artificial neural networks techniques including classification and prediction. It offers a solution for a wide range of different issues in which cases the traditional optimization algorithms and methods cannot be applied directly due to different constraints, including memory restrictions, hidden relationships between variables, very high volume of computations that needs to be handled. One of these issues relates to medical diagnosis, a subset of the medical field. In this paper, the SVM learning algorithm is tested on a diabetes dataset and the results obtained for training with different kernel functions are presented and analyzed in order to determine a good approach from a telemedicine perspective.

WOWW: A Solution Orientated Approach to Enhance Classroom Relationships and Behaviour within a Primary Three Class

Science.gov (United States)

Fernie, Lynne; Cubeddu, Daniela

2016-01-01

A Working on What Works (WOWW) approach was utilised over six sessions in a mainstream Scottish primary class to enhance classroom relationships and behaviours. The aim of the intervention was to manage everyday classroom problems within a natural classroom environment. WOWW incorporates positive psychology and implements a solution-focused…

A potential approach to solutions for set games

NARCIS (Netherlands)

Driessen, T.S.H.; Sun, H.

2001-01-01

Concerning the solution theory for set games, the paper introduces a new solution by allocating, to any player, the items (taken from an universe) that are attainable for the player, but can not be blocked (by any coalition not containing the player). The resulting value turns out to be an utmost

Modified solution calorimetry approach for determination of vaporization and sublimation enthalpies of branched-chain aliphatic and alkyl aromatic compounds at T = 298.15 K

International Nuclear Information System (INIS)

Varfolomeev, Mikhail A.; Novikov, Vladimir B.; Nagrimanov, Ruslan N.; Solomonov, Boris N.

2015-01-01

Highlights: • Solution enthalpies of 18 branching-chain alkyl aromatic and aliphatic compounds in cyclohexane were measured. • Group contributions to the enthalpy of solvation due to branching and substitution in carbon chain were evaluated. • Modified solution calorimetry based approach for determination of vaporization/sublimation enthalpies was proposed. • This approach provides vaporization/sublimation enthalpies directly at T = 298.15 K. • Vaporization/sublimation enthalpies of 35 branched-chain alkyl aromatic and aliphatic compounds were determined. - Abstract: The enthalpies of solution, solvation and vaporization/sublimation are interrelated values combined in the simplest thermodynamic circle. Hence, experimental determination of vaporization/sublimation enthalpy can be substituted by experimentally simpler determination of solution enthalpy when solvation enthalpy is known. Previously it was found that solvation enthalpies of a wide range of unbranched aliphatic and aromatic solutes in saturated hydrocarbons are in good linear correlation with their molar refraction values. This allows to estimate the vaporization/sublimation enthalpy of any unbranched organic compound from its solution enthalpy in saturated hydrocarbon and molar refraction. In the present work this approach was modified for determination of vaporization/sublimation enthalpy of branched-chain alkyl aromatic and aliphatic compounds. Group contributions to the enthalpy of solvation due to the branching of carbon chain were evaluated. Enthalpies of solution at infinite dilution of 18 branched-chain aliphatic and alkyl aromatic compounds were measured at T = 298.15 K. Vaporization/sublimation enthalpies for 35 branched aliphatic and alkyl aromatic compounds were determined by using modified solution calorimetry approach. These values are in good agreement with available literature data on vaporization/sublimation enthalpies obtained by conventional methods.

Development of Hydrogen Storage Tank Systems Based on Complex Metal Hydrides

Directory of Open Access Journals (Sweden)

Morten B. Ley

2015-09-01

Full Text Available This review describes recent research in the development of tank systems based on complex metal hydrides for thermolysis and hydrolysis. Commercial applications using complex metal hydrides are limited, especially for thermolysis-based systems where so far only demonstration projects have been performed. Hydrolysis-based systems find their way in space, naval, military and defense applications due to their compatibility with proton exchange membrane (PEM fuel cells. Tank design, modeling, and development for thermolysis and hydrolysis systems as well as commercial applications of hydrolysis systems are described in more detail in this review. For thermolysis, mostly sodium aluminum hydride containing tanks were developed, and only a few examples with nitrides, ammonia borane and alane. For hydrolysis, sodium borohydride was the preferred material whereas ammonia borane found less popularity. Recycling of the sodium borohydride spent fuel remains an important part for their commercial viability.

Development of Hydrogen Storage Tank Systems Based on Complex Metal Hydrides

Science.gov (United States)

Ley, Morten B.; Meggouh, Mariem; Moury, Romain; Peinecke, Kateryna; Felderhoff, Michael

2015-01-01

This review describes recent research in the development of tank systems based on complex metal hydrides for thermolysis and hydrolysis. Commercial applications using complex metal hydrides are limited, especially for thermolysis-based systems where so far only demonstration projects have been performed. Hydrolysis-based systems find their way in space, naval, military and defense applications due to their compatibility with proton exchange membrane (PEM) fuel cells. Tank design, modeling, and development for thermolysis and hydrolysis systems as well as commercial applications of hydrolysis systems are described in more detail in this review. For thermolysis, mostly sodium aluminum hydride containing tanks were developed, and only a few examples with nitrides, ammonia borane and alane. For hydrolysis, sodium borohydride was the preferred material whereas ammonia borane found less popularity. Recycling of the sodium borohydride spent fuel remains an important part for their commercial viability. PMID:28793541

Secondary α-deuterium isotope effects as a probe to the relationship between structure and mechanism of pyrolysis of secondary azoalkanes

International Nuclear Information System (INIS)

Grizzle, P.L.

1975-01-01

This study was carried out to investigate the mechanism of azoalkane thermolysis and the effect of molecular structure on the potential-energy hypersurface for pyrolysis utilizing secondary α-deuterium isotope effects. Since the magnitude of the α-effect for 1,1'-diphenylazoethane is of singular importance in the interpretation of those for related compounds, it has been redetermined. To investigate the effect of molecular structure on the potential-energy hypersurface for thermolysis, α-effects have been determined for 2,2,2',2'-tetramethyl-1,1'-diphenylazoethane and (2,2-dimethyl-1-phenylpropyl)azomethane; the inability to prepare these compounds by conventional methods necessitated the development of a new method for synthesis of secondary azoalkanes. A convenient synthesis of secondary azo compounds is reported. Secondary α-deuterium isotope effects were obtained for the thermal decomposition of 1,1'-diphenylazoethane (III) and 1,1'-diphenylazoethane-1,1'-d 2 (III-d 2 ). The isotope effect is entirely consistent with a simultaneous one-step thermolysis mechanism. Secondary α-deuterium isotope effects and activation parameters were obtained in the thermolysis of 2,2,2',2'-tetramethyl-1,1'-diphenylazopropane (VIII) and (2,2-dimethyl-1-phenylpropyl)azomethane (IX). The data for VIII is considered in terms of both a one- and two-step thermolysis mechanism. The α-effect and activation energy for VIII are not obviously reconcilable with a one-step mechanism. The α-effects, activation energies, and rates of thermolysis for VIII, IX, and (1-phenylethyl)azomethane are most easily rationalized by a two-step mechanism

Multi-Period Natural Gas Market Modeling. Applications, Stochastic Extensions and Solution Approaches

International Nuclear Information System (INIS)

Egging, R.G.

2010-11-01

This dissertation develops deterministic and stochastic multi-period mixed complementarity problems (MCP) for the global natural gas market, as well as solution approaches for large-scale stochastic MCP. The deterministic model is unique in the combination of the level of detail of the actors in the natural gas markets and the transport options, the detailed regional and global coverage, the multi-period approach with endogenous capacity expansions for transportation and storage infrastructure, the seasonal variation in demand and the representation of market power according to Nash-Cournot theory. The model is applied to several scenarios for the natural gas market that cover the formation of a cartel by the members of the Gas Exporting Countries Forum, a low availability of unconventional gas in the United States, and cost reductions in long-distance gas transportation. The results provide insights in how different regions are affected by various developments, in terms of production, consumption, traded volumes, prices and profits of market participants. The stochastic MCP is developed and applied to a global natural gas market problem with four scenarios for a time horizon until 2050 with nineteen regions and containing 78,768 variables. The scenarios vary in the possibility of a gas market cartel formation and varying depletion rates of gas reserves in the major gas importing regions. Outcomes for hedging decisions of market participants show some significant shifts in the timing and location of infrastructure investments, thereby affecting local market situations. A first application of Benders decomposition (BD) is presented to solve a large-scale stochastic MCP for the global gas market with many hundreds of first-stage capacity expansion variables and market players exerting various levels of market power. The largest problem solved successfully using BD contained 47,373 variables of which 763 first-stage variables, however using BD did not result in

Fault Estimation for Fuzzy Delay Systems: A Minimum Norm Least Squares Solution Approach.

Science.gov (United States)

Huang, Sheng-Juan; Yang, Guang-Hong

2017-09-01

This paper mainly focuses on the problem of fault estimation for a class of Takagi-Sugeno fuzzy systems with state delays. A minimum norm least squares solution (MNLSS) approach is first introduced to establish a fault estimation compensator, which is able to optimize the fault estimator. Compared with most of the existing fault estimation methods, the MNLSS-based fault estimation method can effectively decrease the effect of state errors on the accuracy of fault estimation. Finally, three examples are given to illustrate the effectiveness and merits of the proposed method.

[Zn(NH3)4][PtCl6] and [Cd(NH3)4][PtCl6] as precursors for intermetallic compounds PtZn and PtCd

International Nuclear Information System (INIS)

Zadesenets, A.V.; Venediktov, A.B.; Shubin, Yu.V.; Korenev, S.V.

2007-01-01

Double complex salts (tetraamminezinc and tetraamminecadmium hexachloroplatinates) have been synthesized. Their thermal properties have been studied, as well as the products of their degradation in hydrogen and helium atmospheres. Optimal thermolysis schedules have been determined. Thermolysis under hydrogen yields intermetallic compounds PtZn and PtCd [ru

Rational Solutions to the ABS List: Transformation Approach

Science.gov (United States)

Zhang, Danda; Zhang, Da-Jun

2017-10-01

In the paper we derive rational solutions for the lattice potential modified Korteweg-de Vries equation, and Q2, Q1(δ), H3(δ), H2 and H1 in the Adler-Bobenko-Suris list. Bäcklund transformations between these lattice equations are used. All these rational solutions are related to a unified τ function in Casoratian form which obeys a bilinear superposition formula.

Quality assessment of Isfahan Medical Faculty web site electronic services and prioritizing solutions using analytic hierarchy process approach.

Science.gov (United States)

Hajrahimi, Nafiseh; Dehaghani, Sayed Mehdi Hejazi; Hajrahimi, Nargess; Sarmadi, Sima

2014-01-01

Implementing information technology in the best possible way can bring many advantages such as applying electronic services and facilitating tasks. Therefore, assessment of service providing systems is a way to improve the quality and elevate these systems including e-commerce, e-government, e-banking, and e-learning. This study was aimed to evaluate the electronic services in the website of Isfahan University of Medical Sciences in order to propose solutions to improve them. Furthermore, we aim to rank the solutions based on the factors that enhance the quality of electronic services by using analytic hierarchy process (AHP) method. Non-parametric test was used to assess the quality of electronic services. The assessment of propositions was based on Aqual model and they were prioritized using AHP approach. The AHP approach was used because it directly applies experts' deductions in the model, and lead to more objective results in the analysis and prioritizing the risks. After evaluating the quality of the electronic services, a multi-criteria decision making frame-work was used to prioritize the proposed solutions. Non-parametric tests and AHP approach using Expert Choice software. The results showed that students were satisfied in most of the indicators. Only a few indicators received low satisfaction from students including, design attractiveness, the amount of explanation and details of information, honesty and responsiveness of authorities, and the role of e-services in the user's relationship with university. After interviewing with Information and Communications Technology (ICT) experts at the university, measurement criteria, and solutions to improve the quality were collected. The best solutions were selected by EC software. According to the results, the solution "controlling and improving the process in handling users complaints" is of the utmost importance and authorities have to have it on the website and place great importance on updating this process

Statistically optimal estimation of Greenland Ice Sheet mass variations from GRACE monthly solutions using an improved mascon approach

NARCIS (Netherlands)

Ran, J.; Ditmar, P.G.; Klees, R.; Farahani, H.

2017-01-01

We present an improved mascon approach to transform monthly spherical harmonic solutions based on GRACE satellite data into mass anomaly estimates in Greenland. The GRACE-based spherical harmonic coefficients are used to synthesize gravity anomalies at satellite altitude, which are then inverted

Multi-period natural gas market modeling Applications, stochastic extensions and solution approaches

Science.gov (United States)

Egging, Rudolf Gerardus

This dissertation develops deterministic and stochastic multi-period mixed complementarity problems (MCP) for the global natural gas market, as well as solution approaches for large-scale stochastic MCP. The deterministic model is unique in the combination of the level of detail of the actors in the natural gas markets and the transport options, the detailed regional and global coverage, the multi-period approach with endogenous capacity expansions for transportation and storage infrastructure, the seasonal variation in demand and the representation of market power according to Nash-Cournot theory. The model is applied to several scenarios for the natural gas market that cover the formation of a cartel by the members of the Gas Exporting Countries Forum, a low availability of unconventional gas in the United States, and cost reductions in long-distance gas transportation. 1 The results provide insights in how different regions are affected by various developments, in terms of production, consumption, traded volumes, prices and profits of market participants. The stochastic MCP is developed and applied to a global natural gas market problem with four scenarios for a time horizon until 2050 with nineteen regions and containing 78,768 variables. The scenarios vary in the possibility of a gas market cartel formation and varying depletion rates of gas reserves in the major gas importing regions. Outcomes for hedging decisions of market participants show some significant shifts in the timing and location of infrastructure investments, thereby affecting local market situations. A first application of Benders decomposition (BD) is presented to solve a large-scale stochastic MCP for the global gas market with many hundreds of first-stage capacity expansion variables and market players exerting various levels of market power. The largest problem solved successfully using BD contained 47,373 variables of which 763 first-stage variables, however using BD did not result in

A topological approach to the existence of solutions for nonlinear differential equations with piecewise constant argument

International Nuclear Information System (INIS)

Huang Zhenkun; Wang Xinghua; Xia Yonghui

2009-01-01

In this paper, we investigate qualitative behavior of nonlinear differential equations with piecewise constant argument (PCA). A topological approach of Wazewski-type which gives sufficient conditions to guarantee that the graph of at least one solution stays in a given domain is formulated. Moreover, our results are also suitable for a class of general system of discrete equations. By using a regular polyfacial set, we apply our developed topological approach to cellular neural networks (CNNs) with PCA. Some new results are attained to reveal dynamic behavior of CNNs with PCA and discrete-time CNNs. Finally, an illustrative example of CNNs with PCA shows usefulness and effectiveness of our results.

Online Learning Integrity Approaches: Current Practices and Future Solutions

Science.gov (United States)

Lee-Post, Anita; Hapke, Holly

2017-01-01

The primary objective of this paper is to help institutions respond to the stipulation of the Higher Education Opportunity Act of 2008 by adopting cost-effective academic integrity solutions without compromising the convenience and flexibility of online learning. Current user authentication solutions such as user ID and password, security…

Modern Urban Naming Practices: Strategic Approaches and Practical Solutions

Directory of Open Access Journals (Sweden)

Marina V. Golomidova

2017-11-01

Full Text Available The article looks at the problems of the naming of municipal facilities. The author analyzes the existing policy in assigning new names and renaming urban sites, describes the current strategic approaches to urban naming and proposes a new strategy based on congruity with the holistic image of the city. The current approaches to urban naming mark the predominating interest in the historical and cultural heritage of cities as a valuable source for the toponymic nomination shared both by native and foreign experts. However, this commitment to the past may run counter to the modern arrangement and perception of the urban space, as well as impede the city development prospects. From the standpoint of modern area marketing, names of urban sites are regarded as an information and communication resource highly relevant to the city image formation and promotion. In the author’s view, the benefits of adopting a new strategy may also resonate with the concept of “urbanonymic construction,” which is understood as sustainable and streamlined management policy aimed at the progressive implementation of long-term programs for individual urban site names consistency. The urbanonymic construction involves a normative, regulatory aspect; formation of the holistic city image that builds on its resource base, the symbolic capital, and the development strategy; definition of key characteristics of the city image which are most relevant to its positioning; identification of principal nominative themes for verbal representation of the city image; use of naming technologies to ensure the relevance of the name’s implications; testing and expert evaluation of new names. Drawing on domestic and foreign expertise in the same study field, a number of practical solutions for the creation of new urbanonyms are described.

Dynamic Approaches for Multichoice Solutions

Directory of Open Access Journals (Sweden)

Yu-Hsien Liao

2011-01-01

Full Text Available Based on alternative reduced games, several dynamic approaches are proposed to show how the three extended Shapley values can be reached dynamically from arbitrary efficient payoff vectors on multichoice games.

Quality assessment of Isfahan Medical Faculty web site electronic services and prioritizing solutions using analytic hierarchy process approach

Science.gov (United States)

Hajrahimi, Nafiseh; Dehaghani, Sayed Mehdi Hejazi; Hajrahimi, Nargess; Sarmadi, Sima

2014-01-01

Context: Implementing information technology in the best possible way can bring many advantages such as applying electronic services and facilitating tasks. Therefore, assessment of service providing systems is a way to improve the quality and elevate these systems including e-commerce, e-government, e-banking, and e-learning. Aims: This study was aimed to evaluate the electronic services in the website of Isfahan University of Medical Sciences in order to propose solutions to improve them. Furthermore, we aim to rank the solutions based on the factors that enhance the quality of electronic services by using analytic hierarchy process (AHP) method. Materials and Methods: Non-parametric test was used to assess the quality of electronic services. The assessment of propositions was based on Aqual model and they were prioritized using AHP approach. The AHP approach was used because it directly applies experts’ deductions in the model, and lead to more objective results in the analysis and prioritizing the risks. After evaluating the quality of the electronic services, a multi-criteria decision making frame-work was used to prioritize the proposed solutions. Statistical Analysis Used: Non-parametric tests and AHP approach using Expert Choice software. Results: The results showed that students were satisfied in most of the indicators. Only a few indicators received low satisfaction from students including, design attractiveness, the amount of explanation and details of information, honesty and responsiveness of authorities, and the role of e-services in the user's relationship with university. After interviewing with Information and Communications Technology (ICT) experts at the university, measurement criteria, and solutions to improve the quality were collected. The best solutions were selected by EC software. According to the results, the solution “controlling and improving the process in handling users complaints” is of the utmost importance and authorities

The effect of the solution-focused approach on nutrition-exercise attitudes and behaviours of overweight and obese adolescents: Randomised controlled trial.

Science.gov (United States)

Akgul Gundogdu, Nurcan; Sevig, Emine Umit; Guler, Nuran

2018-04-01

To assess the effect of the solution-focused approach interview technique on overweight/obese adolescents' nutrition-exercise attitudes and behaviours. Obesity is a serious health problem for all age groups, particularly adolescents; therefore, it is important for adolescents to develop healthy nutrition habits and acquire exercise behaviours. Unless healthy nutrition-exercise behaviours are acquired, obesity can develop in adolescence, continue in adulthood. Focusing on solutions can be effective for overweight/obese adolescents to develop healthy nutrition-exercise behaviours. A pretest-post-test randomised controlled trial design was used. The study included 32 overweight/obese adolescents (16 for intervention group, 16 for control group) aged 12-13 years who attended a health centre and met the inclusion criteria. The solution-focused Approach interview technique was applied to the intervention group. Eight solution-focused interviews were conducted with each adolescent at 2-week intervals (interview length 30-45 min). For each group, anthropometric, metabolic measurement follow-ups were conducted in the first and sixth months. The data were evaluated using independent samples t test, Mann-Whitney U, Wilcoxon test, respectively, for normally, non-normally distributed variables. The categorical variables were compared using chi-square test. The value p exercise attitude and behaviour scale scores were higher in the sixth month follow-up; difference between the follow-ups was significant (p exercise attitude and behaviour scores. Eight interviews during 6 months were adequate for positive development of their nutrition-exercise attitudes and behaviours; significant decrease in their weight, BMI percentile, BMI-SDS values; and normal metabolic values. The solution-focused approach interview technique enabled overweight/obese adolescents' weight and blood glucose to be controlled against obesity. It helped them acquire healthy nutrition-exercise behaviours

State of the art concerning optimum location of capacitors and studying the exhaustive search approach for optimising a given solution

Directory of Open Access Journals (Sweden)

Sergio Raúl Rivera Rodríguez

2004-09-01

Full Text Available The present article reviews the state of the art of optimum capacitor location in distribution systems, provideing guidelines for planners engaged in optimising tension profiles and controlling reagents in distribution networks.Optimising a given solution by exhastive search is studied here; the dimensions of a given problem are determined by evaluating the different possibilities for resolving it and the solution algorithm's computational times and requierements are visualised. An example system (9 node, IEEE is used for illustrating the exhaustive search approach, where it was found that methods used in the literature regarding this topic do not always lead to the optimum solution.

Toward enhanced hydrogen generation from water using oxygen permeating LCF membranes

KAUST Repository

Wu, Xiao-Yu

2015-01-01

© the Owner Societies. Hydrogen production from water thermolysis can be enhanced by the use of perovskite-type mixed ionic and electronic conducting (MIEC) membranes, through which oxygen permeation is driven by a chemical potential gradient. In this work, water thermolysis experiments were performed using 0.9 mm thick La0.9Ca0.1FeO3-δ (LCF-91) perovskite membranes at 990 °C in a lab-scale button-cell reactor. We examined the effects of the operating conditions such as the gas species concentrations and flow rates on the feed and sweep sides on the water thermolysis rate and oxygen flux. A single step reaction mechanism is proposed for surface reactions, and three-resistance permeation models are derived. Results show that water thermolysis is facilitated by the LCF-91 membrane especially when a fuel is added to the sweep gas. Increasing the gas flow rate and water concentration on the feed side or the hydrogen concentration on the sweep side enhances the hydrogen production rate. In this work, hydrogen is used as the fuel by construction, so that a single-step surface reaction mechanism can be developed and water thermolysis rate parameters can be derived. Both surface reaction rate parameters for oxygen incorporation/dissociation and hydrogen-oxygen reactions are fitted at 990 °C. We compare the oxygen fluxes in water thermolysis and air separation experiments, and identify different limiting steps in the processes involving various oxygen sources and sweep gases for this 0.9 mm thick LCF-91 membrane. In the air feed-inert sweep case, the bulk diffusion and sweep side surface reaction are the two limiting steps. In the water feed-inert sweep case, surface reaction on the feed side dominates the oxygen permeation process. Yet in the water feed-fuel sweep case, surface reactions on both the feed and sweep sides are rate determining when hydrogen concentration in the sweep side is in the range of 1-5 vol%. Furthermore, long term studies show that the surface

Gas-Phase Thermolysis

DEFF Research Database (Denmark)

Carlsen, Lars; Egsgaard, Helge; Schaumann, Ernst

1980-01-01

The unimolecular gas-phase thermolytic decomposition of three silylated thionocarboxylic acid derivatives (2b), (3), and (8) have been studied by the flash vacuum thermolysis–field ionization mass spectrometry technique in the temperature range from 783 to 1 404 K in order to elucidate its possible...... applicability as a route to thioketens. Only very minor amounts of the expected thioketens were found, whereas the corresponding ketens were obtained as the major products. A possible mechanism for keten formation is discussed....

Premises and solutions regarding a global approach of gaseous pollutants emissions from the fossil fuel power plants in Romania

International Nuclear Information System (INIS)

Tutuianu, O.; Fulger, E.D.; Vieru, A.; Feher, M.

1996-01-01

This paper deals with the present state of RENEL (Romanian Electricity Authority) - controlled thermal power plants from the point of view of technical aspects, utilized fuels and pollutant emissions. National and international regulations are also analyzed as well as their implications concerning the management of pollutant atmospheric emissions of the plants of RENEL. Starting from these premises the paper points out the advantage of global approach of pollution problems and offers solutions already implemented by RENEL. This global approach will result in an optimization of costs implied in pollutant emission limitations as the most efficient solution were found and applied. Having in view this treatment of the pollution problems, RENEL has submitted to the Ministry of the Industries and to the Ministry of Waters, Forests and Environmental Protection a 'Convention on the limitation of CO 2 , SO 2 and NO x emissions produced in the thermal power plants of RENEL'. (author)

Lie symmetry analysis and reduction for exact solution of (2+1)-dimensional Bogoyavlensky-Konopelchenko equation by geometric approach

Science.gov (United States)

Ray, S. Saha

2018-04-01

In this paper, the symmetry analysis and similarity reduction of the (2+1)-dimensional Bogoyavlensky-Konopelchenko (B-K) equation are investigated by means of the geometric approach of an invariance group, which is equivalent to the classical Lie symmetry method. Using the extended Harrison and Estabrook’s differential forms approach, the infinitesimal generators for (2+1)-dimensional B-K equation are obtained. Firstly, the vector field associated with the Lie group of transformation is derived. Then the symmetry reduction and the corresponding explicit exact solution of (2+1)-dimensional B-K equation is obtained.

Economic planning for electric energy systems: a multi objective linearized approach for solution

International Nuclear Information System (INIS)

Mata Medeiros Branco, T. da.

1986-01-01

The economic planning problem associated to the expansion and operation of electrical power systems is considered in this study, represented for a vectorial objective function in which the minimization of resources involved and maximization of attended demand constitute goals to be satisfied. Supposing all the variables involved with linear characteristic and considering the conflict existing among the objectives to be achieved, in order to find a solution, a multi objective linearized approach is proposed. This approximation utilizes the compromise programming technique and linear programming methods. Generation and transmission are simultaneously considered into the optimization process in which associated losses and the capacity of each line are included. Illustrated examples are also presented with results discussed. (author)

Comprehensive approach to energy and environment in the Eco Care Program for design, engineering and operation of Siemens Industry Solutions

Energy Technology Data Exchange (ETDEWEB)

Wegener, D. (Siemens AG, Erlangen (Germany)); Finkbeiner, M. (Technische Univ. Berlin (TUB), Systemumwelttechnik (SUT), Berlin (Germany)); Geiger, D. (Siemens AG, Munich (Germany)); Olsen, S.I. (Danish Technical Univ. (DTU), Management Engineering, Lyngby (Denmark)); Walachowicz, F. (Siemens AG, Berlin (Germany))

2009-09-15

This paper intends to describe the outline of the Eco Care Program (ECP) at the Siemens-Division Industry Solutions and its implementation. ECP aims to embrace and to coordinate main activities within the product lifecycle management (PLM) process considering both economic targets in terms of overall lifecycle costs as well as energy efficiency and other important environmental issues in the innovation management for industrial solutions. ECP consists of adapted methods for assessing the environmental and financial impacts of industrial solutions (plants, processes, single technologies or even services) and tools which helps to derive reliable assessment results. Life Cycle Assessment (LCA) is a suitable method for assessing environmental impacts of products and solutions over their entire lifecycle focusing on those lifecycle phases which may contribute significantly to environmental burdens or benefits. To meet these requirements the main challenge is to simplify the assessment methodology as far as reliability and accuracy of results is preserved. To present results in both dimensions of economical performance and environmental impact the paper introduces the concept of the 'eco care matrix' (ECM). Environmental sound industrial solutions have advantages in both 'eco' dimensions (eco-nomical + eco-logical). The analytical approach presented is further on implemented in two complementary and independent industrial application fields: in order to exemplify usability of the approach in quite complex process technology different hot metal producing technologies (blast furnace route vs. smelting reduction routes COREX / FINEX). The second pilot application is targeted on the assessment of infrastructure solutions especially focusing on the comparison of environmental and financial effects of different technologies and payment schemes of electronic city tolling systems for London and Copenhagen. Experienced results derived from these two pilot

Dissolution of carbon dioxide in aqueous electrolyte solutions, in the context of geological storage: A thermodynamic approach

International Nuclear Information System (INIS)

Liborio, Barbara

2017-01-01

This thesis studies the enthalpy of solution of carbon dioxide in electrolyte aqueous solutions. To develop theoretical models describing the systems (CO 2 -water-salt) under the geological storage conditions of carbon dioxide, it is necessary to have experimental data, namely solubility and enthalpy. In this study, a customized flow mixing unit was adapted to a SETARAM C-80 calorimeter to measure the enthalpy of CO 2 solution in aqueous electrolyte solutions (NaCl, CaCl 2 and Na 2 SO 4 ) at the ionic strengths between 2 and 6 and at temperatures between 323.1 K and 372.9 K and pressures ranging from 2 to 16 MPa. Data from the literature were used to adjust the thermodynamic phase equilibrium model in the Y-φ approach. The thermodynamic model reproduces the experimental enthalpies to plus or minus 10%. The calculation of the enthalpy in the rigorous model is strongly dependent on the data of the literature. An experimental device has been set up for the determination of the molar volume of CO 2 at infinite dilution, which is necessary for thermodynamic modeling. The carbon dioxide to be stored may contain impurities such as annexes (O 2 , N 2 , SO x , H 2 S, N y O x , H 2 , CO and Ar). Under the objective of studying the influence of these impurities, an experimental apparatus has been set up for the measurement of enthalpies of solution of SO 2 in water and aqueous solutions of NaCl and the first results are promising. (author)

A New Approach to Look at the Electrical Conductivity of Streamflow: Decomposing a Bulk Signal to Recover Individual Solute Concentrations at High-Frequency

Science.gov (United States)

Benettin, P.; Van Breukelen, B. M.

2017-12-01

The ability to evaluate stream hydrochemistry is often constrained by the capacity to sample streamwater at an adequate frequency. While technology is no longer a limiting factor, economic and management efforts can still be a barrier to high-resolution water quality instrumentation. We propose a new framework to investigate the electrical conductivity (EC) of streamwater, which can be measured continuously through inexpensive sensors. We show that EC embeds information on ion content which can be isolated to retrieve solute concentrations at high resolution. The approach can already be applied to a number of datasets worldwide where water quality campaigns are conducted, provided continuous EC measurements can be collected. The essence of the approach is the decomposition of the EC signal into its "harmonics", i.e. the specific contributions of the major ions which conduct current in water. The ion contribution is used to explore water quality patterns and to develop algorithms that reconstruct solute concentrations during periods where solute measurements are not available. The approach is validated on a hydrochemical dataset from Plynlimon, Wales. Results show that the decomposition of EC is feasible and for at least two major elements the methodology provided improved estimates of high-frequency solute dynamics. Our results support the installation of EC probes to complement water quality campaigns and suggest that the potential of EC measurements in rivers is currently far from being fully exploited.

A Practical Solution Using A New Approach To Robot Vision

Science.gov (United States)

Hudson, David L.

1984-01-01

Up to now, robot vision systems have been designed to serve both application development and operational needs in inspection, assembly and material handling. This universal approach to robot vision is too costly for many practical applications. A new industrial vision system separates the function of application program development from on-line operation. A Vision Development System (VDS) is equipped with facilities designed to simplify and accelerate the application program development process. A complimentary but lower cost Target Application System (TASK) runs the application program developed with the VDS. This concept is presented in the context of an actual robot vision application that improves inspection and assembly for a manufacturer of electronic terminal keyboards. Applications developed with a VDS experience lower development cost when compared with conventional vision systems. Since the TASK processor is not burdened with development tools, it can be installed at a lower cost than comparable "universal" vision systems that are intended to be used for both development and on-line operation. The VDS/TASK approach opens more industrial applications to robot vision that previously were not practical because of the high cost of vision systems. Although robot vision is a new technology, it has been applied successfully to a variety of industrial needs in inspection, manufacturing, and material handling. New developments in robot vision technology are creating practical, cost effective solutions for a variety of industrial needs. A year or two ago, researchers and robot manufacturers interested in implementing a robot vision application could take one of two approaches. The first approach was to purchase all the necessary vision components from various sources. That meant buying an image processor from one company, a camera from another and lens and light sources from yet others. The user then had to assemble the pieces, and in most instances he had to write

Siemens IT solutions for power sector

International Nuclear Information System (INIS)

Lunter, P.

2004-01-01

The cost reduction, flexibility and revenue increase, potential exploitation, productivity increase, and business opportunities exploitation - that is all what can be required in the races for the promonent positioning on the electricity power market. These requirements can be realized by the sophisticated IT solutions hand-tailored to the special requirements of the electric power producers and tradesmen. This approach makes it possible to achieve greater profit. Our solutions 'PROFIT Solutions', that are symbiosis of the most progressive information technologies and the power plant techniques of the company Siemens, satisfy submitted specifications in substantial measure. The system solutions 'PROFIT Solutions' comprise three solution groups: process, operation a business. The solutions of the group 'IT Process Solutions' increase flexibility and manoeuvrability of equipment, improve the efficiency and contribute to more economical operation of the power generation. Solutions 'IT Process Solutions' simplify and shorten the period of power cycles and conduce to higher labour productivity. Solutions group 'IT Process Solutions' approaches equipment to the market - supports the profit strategies, helps quickly and expertly to determine and predict hazards. The extension PROFIT Cockpit means the nuance to the solutions world 'PROFIT Solutions'. The survey about the whole installation is within reach at the simple touch of a button. It is possible to compile the total system part by part from single solutions 'PROFIT Solutions'. As a matter of fact all single parts can be interconnected with already existing solutions. Routines 'PROFIT Solutions' cooperate with all modern control systems. (author)

Stochastic uncertainty analysis for solute transport in randomly heterogeneous media using a Karhunen‐Loève‐based moment equation approach

Science.gov (United States)

Liu, Gaisheng; Lu, Zhiming; Zhang, Dongxiao

2007-01-01

A new approach has been developed for solving solute transport problems in randomly heterogeneous media using the Karhunen‐Loève‐based moment equation (KLME) technique proposed by Zhang and Lu (2004). The KLME approach combines the Karhunen‐Loève decomposition of the underlying random conductivity field and the perturbative and polynomial expansions of dependent variables including the hydraulic head, flow velocity, dispersion coefficient, and solute concentration. The equations obtained in this approach are sequential, and their structure is formulated in the same form as the original governing equations such that any existing simulator, such as Modular Three‐Dimensional Multispecies Transport Model for Simulation of Advection, Dispersion, and Chemical Reactions of Contaminants in Groundwater Systems (MT3DMS), can be directly applied as the solver. Through a series of two‐dimensional examples, the validity of the KLME approach is evaluated against the classical Monte Carlo simulations. Results indicate that under the flow and transport conditions examined in this work, the KLME approach provides an accurate representation of the mean concentration. For the concentration variance, the accuracy of the KLME approach is good when the conductivity variance is 0.5. As the conductivity variance increases up to 1.0, the mismatch on the concentration variance becomes large, although the mean concentration can still be accurately reproduced by the KLME approach. Our results also indicate that when the conductivity variance is relatively large, neglecting the effects of the cross terms between velocity fluctuations and local dispersivities, as done in some previous studies, can produce noticeable errors, and a rigorous treatment of the dispersion terms becomes more appropriate.

eSIP: A Novel Solution-Based Sectioned Image Property Approach for Microscope Calibration.

Directory of Open Access Journals (Sweden)

Malte Butzlaff

Full Text Available Fluorescence confocal microscopy represents one of the central tools in modern sciences. Correspondingly, a growing amount of research relies on the development of novel microscopic methods. During the last decade numerous microscopic approaches were developed for the investigation of various scientific questions. Thereby, the former qualitative imaging methods became replaced by advanced quantitative methods to gain more and more information from a given sample. However, modern microscope systems being as complex as they are, require very precise and appropriate calibration routines, in particular when quantitative measurements should be compared over longer time scales or between different setups. Multispectral beads with sub-resolution size are often used to describe the point spread function and thus the optical properties of the microscope. More recently, a fluorescent layer was utilized to describe the axial profile for each pixel, which allows a spatially resolved characterization. However, fabrication of a thin fluorescent layer with matching refractive index is technically not solved yet. Therefore, we propose a novel type of calibration concept for sectioned image property (SIP measurements which is based on fluorescent solution and makes the calibration concept available for a broader number of users. Compared to the previous approach, additional information can be obtained by application of this extended SIP chart approach, including penetration depth, detected number of photons, and illumination profile shape. Furthermore, due to the fit of the complete profile, our method is less susceptible to noise. Generally, the extended SIP approach represents a simple and highly reproducible method, allowing setup independent calibration and alignment procedures, which is mandatory for advanced quantitative microscopy.

The use of potassium hydroxide (KOH) solution as a suitable approach to isolate plastics ingested by marine organisms.

Science.gov (United States)

Kühn, Susanne; van Werven, Bernike; van Oyen, Albert; Meijboom, André; Bravo Rebolledo, Elisa L; van Franeker, Jan A

2017-02-15

In studies of plastic ingestion by marine wildlife, visual separation of plastic particles from gastrointestinal tracts or their dietary content can be challenging. Earlier studies have used solutions to dissolve organic materials leaving synthetic particles unaffected. However, insufficient tests have been conducted to ensure that different categories of consumer products partly degraded in the environment and/or in gastrointestinal tracts were not affected. In this study 63 synthetic materials and 11 other dietary items and non-plastic marine debris were tested. Irrespective of shape or preceding environmental history, most polymers resisted potassium hydroxide (KOH) solution, with the exceptions of cellulose acetate from cigarette filters, some biodegradable plastics and a single polyethylene sheet. Exposure of hard diet components and other marine debris showed variable results. In conclusion, the results confirm that usage of KOH solutions can be a useful approach in general quantitative studies of plastic ingestion by marine wildlife. Copyright © 2016 The Authors. Published by Elsevier Ltd.. All rights reserved.

A New Heuristic Providing an Effective Initial Solution for a Simulated Annealing approach to Energy Resource Scheduling in Smart Grids

DEFF Research Database (Denmark)

Sousa, Tiago M; Morais, Hugo; Castro, R.

2014-01-01

scheduling problem. Therefore, the use of metaheuristics is required to obtain good solutions in a reasonable amount of time. This paper proposes two new heuristics, called naive electric vehicles charge and discharge allocation and generation tournament based on cost, developed to obtain an initial solution...... to be used in the energy resource scheduling methodology based on simulated annealing previously developed by the authors. The case study considers two scenarios with 1000 and 2000 electric vehicles connected in a distribution network. The proposed heuristics are compared with a deterministic approach...

Sythesis of metal sulfide nanomaerials via thermal decomposition of single-source percursors

Energy Technology Data Exchange (ETDEWEB)

Jen-La Plante, Ilan; Zeid, Tahani W.; Yang, Peidong; Mokari, Taleb

2010-06-03

In this report, we present a synthetic method for the formation of cuprous sulfide (Cu2S) and lead sulfide (PbS) nanomaterials directly on substrates from the thermolysis of single-source precursors. We find that the final morphology and arrangement of the nanomaterials may be controlled through the concentration of the dissolved precursors and choice of solvent. One-dimensional (1-D) morphologies may also be grown onto substrates with the addition of a metal catalyst layer through solution-liquid-solid (SLS) growth. These synthetic techniques may be expanded to other metal sulfide materials.

A new analytical approach for limit cycles and quasi-periodic solutions of nonlinear oscillators: the example of the forced Van der Pol Duffing oscillator

International Nuclear Information System (INIS)

Shukla, Anant Kant; Ramamohan, T R; Srinivas, S

2014-01-01

In this paper we propose a technique to obtain limit cycles and quasi-periodic solutions of forced nonlinear oscillators. We apply this technique to the forced Van der Pol oscillator and the forced Van der Pol Duffing oscillator and obtain for the first time their limit cycles (periodic) and quasi-periodic solutions analytically. We introduce a modification of the homotopy analysis method to obtain these solutions. We minimize the square residual error to obtain accurate approximations to these solutions. The obtained analytical solutions are convergent and agree well with numerical solutions even at large times. Time trajectories of the solution, its first derivative and phase plots are presented to confirm the validity of the proposed approach. We also provide rough criteria for the determination of parameter regimes which lead to limit cycle or quasi-periodic behaviour. (papers)

Passive House Solutions

Energy Technology Data Exchange (ETDEWEB)

Strom, I.; Joosten, L.; Boonstra, C. [DHV Sustainability Consultants, Eindhoiven (Netherlands)

2006-05-15

PEP stands for 'Promotion of European Passive Houses' and is a consortium of European partners, supported by the European Commission, Directorate General for Energy and Transport. In this working paper an overview is given of Passive House solutions. An inventory has been made of Passive House solutions for new build residences applied in each country. Based on this, the most common basic solutions have been identified and described in further detail, including the extent to which solutions are applied in common and best practice and expected barriers for the implementation in each country. An inventory per country is included in the appendix. The analysis of Passive House solutions in partner countries shows high priority with regard to the performance of the thermal envelope, such as high insulation of walls, roofs, floors and windows/ doors, thermal bridge-free construction and air tightness. Due to the required air tightness, special attention must be paid to indoor air quality through proper ventilation. Finally, efficient ((semi-)solar) heating systems for combined space and DHW heating still require a significant amount of attention in most partner countries. Other basic Passive House solutions show a smaller discrepancy with common practice and fewer barriers have been encountered in partner countries. In the next section, the general barriers in partner countries have been inventoried. For each type of barrier a suggested approach has been given. Most frequently encountered barriers in partner countries are: limited know-how; limited contractor skills; and acceptation of Passive Houses in the market. Based on the suggested approaches to overcoming barriers, this means that a great deal of attention must be paid to providing practical information and solutions to building professionals, providing practical training to installers and contractors and communication about the Passive House concept to the market.

Solution properties and taste behavior of lactose monohydrate in aqueous ascorbic acid solutions at different temperatures: Volumetric and rheological approach.

Science.gov (United States)

Sarkar, Abhijit; Sinha, Biswajit

2016-11-15

The densities and viscosities of lactose monohydrate in aqueous ascorbic acid solutions with several molal concentrations m=(0.00-0.08)molkg(-1) of ascorbic acid were determined at T=(298.15-318.15)K and pressure p=101kPa. Using experimental data apparent molar volume (ϕV), standard partial molar volume (ϕV(0)), the slope (SV(∗)), apparent specific volumes (ϕVsp), standard isobaric partial molar expansibility (ϕE(0)) and its temperature dependence [Formula: see text] the viscosity B-coefficient and solvation number (Sn) were determined. Viscosity B-coefficients were further employed to obtain the free energies of activation of viscous flow per mole of the solvents (Δμ1(0≠)) and of the solute (Δμ2(0≠)). Effects of molality, solute structure and temperature and taste behavior were analyzed in terms of solute-solute and solute-solvent interactions; results revealed that the solutions are characterized predominantly by solute-solvent interactions and lactose monohydrate behaves as a long-range structure maker. Copyright © 2016 Elsevier Ltd. All rights reserved.

Cultural dissonance among generations: a solution-focused approach with East Asian elders and their families.

Science.gov (United States)

Lee, Mo Yee; Mjelde-Mossey, LeeAnn

2004-10-01

In traditional East Asian cultures, high value is assigned to family harmony and filial piety coupled with the expectation that elders will be honored and obeyed. A lifetime of such expectations shapes how elders perceive their role and status in the family. Problems can arise when younger, less traditional, generations do not share these expectations. This article describes a solution-focused approach that facilitates the family in creating a beneficial harmony in situations of cultural dissonance. Family members are empowered to draw on personal strengths in which multiple worldviews and values of individual members are recognized, incorporated, and negotiated.

Solution approach for a large scale personnel transport system for a large company in Latin America

Energy Technology Data Exchange (ETDEWEB)

Garzón-Garnica, Eduardo-Arturo; Caballero-Morales, Santiago-Omar; Martínez-Flores, José-Luis

2017-07-01

The present paper focuses on the modelling and solution of a large-scale personnel transportation system in Mexico where many routes and vehicles are currently used to service 525 points. The routing system proposed can be applied to many cities in the Latin-American region. Design/methodology/approach: This system was modelled as a VRP model considering the use of real-world transit times, and the fact that routes start at the farthest point from the destination center. Experiments were performed on different sized sets of service points. As the size of the instances was increased, the performance of the heuristic method was assessed in comparison with the results of an exact algorithm, the results remaining very close between both. When the size of the instance was full-scale and the exact algorithm took too much time to solve the problem, then the heuristic algorithm provided a feasible solution. Supported by the validation with smaller scale instances, where the difference between both solutions was close to a 6%, the full –scale solution obtained with the heuristic algorithm was considered to be within that same range. Findings: The proposed modelling and solving method provided a solution that would produce significant savings in the daily operation of the routes. Originality/value: The urban distribution of the cities in Latin America is unique to other regions in the world. The general layout of the large cities in this region includes a small town center, usually antique, and a somewhat disordered outer region. The lack of a vehicle-centered urban planning poses distinct challenges for vehicle routing problems in the region. The use of a heuristic VRP combined with the results of an exact VRP, allowed the obtention of an improved routing plan specific to the requirements of the region.

Solution approach for a large scale personnel transport system for a large company in Latin America

International Nuclear Information System (INIS)

Garzón-Garnica, Eduardo-Arturo; Caballero-Morales, Santiago-Omar; Martínez-Flores, José-Luis

2017-01-01

The present paper focuses on the modelling and solution of a large-scale personnel transportation system in Mexico where many routes and vehicles are currently used to service 525 points. The routing system proposed can be applied to many cities in the Latin-American region. Design/methodology/approach: This system was modelled as a VRP model considering the use of real-world transit times, and the fact that routes start at the farthest point from the destination center. Experiments were performed on different sized sets of service points. As the size of the instances was increased, the performance of the heuristic method was assessed in comparison with the results of an exact algorithm, the results remaining very close between both. When the size of the instance was full-scale and the exact algorithm took too much time to solve the problem, then the heuristic algorithm provided a feasible solution. Supported by the validation with smaller scale instances, where the difference between both solutions was close to a 6%, the full –scale solution obtained with the heuristic algorithm was considered to be within that same range. Findings: The proposed modelling and solving method provided a solution that would produce significant savings in the daily operation of the routes. Originality/value: The urban distribution of the cities in Latin America is unique to other regions in the world. The general layout of the large cities in this region includes a small town center, usually antique, and a somewhat disordered outer region. The lack of a vehicle-centered urban planning poses distinct challenges for vehicle routing problems in the region. The use of a heuristic VRP combined with the results of an exact VRP, allowed the obtention of an improved routing plan specific to the requirements of the region.

Solution approach for a large scale personnel transport system for a large company in Latin America

Directory of Open Access Journals (Sweden)

Eduardo-Arturo Garzón-Garnica

2017-10-01

Full Text Available Purpose: The present paper focuses on the modelling and solution of a large-scale personnel transportation system in Mexico where many routes and vehicles are currently used to service 525 points. The routing system proposed can be applied to many cities in the Latin-American region. Design/methodology/approach: This system was modelled as a VRP model considering the use of real-world transit times, and the fact that routes start at the farthest point from the destination center. Experiments were performed on different sized sets of service points. As the size of the instances was increased, the performance of the heuristic method was assessed in comparison with the results of an exact algorithm, the results remaining very close between both.  When the size of the instance was full-scale and the exact algorithm took too much time to solve the problem, then the heuristic algorithm provided a feasible solution. Supported by the validation with smaller scale instances, where the difference between both solutions was close to a 6%, the full –scale solution obtained with the heuristic algorithm was considered to be within that same range. Findings: The proposed modelling and solving method provided a solution that would produce significant savings in the daily operation of the routes. Originality/value: The urban distribution of the cities in Latin America is unique to other regions in the world. The general layout of the large cities in this region includes a small town center, usually antique, and a somewhat disordered outer region. The lack of a vehicle-centered urban planning poses distinct challenges for vehicle routing problems in the region. The use of a heuristic VRP combined with the results of an exact VRP, allowed the obtention of an improved routing plan specific to the requirements of the region.

Deproteinization: an integrated-solution approach to increase efficiency in β-galactosidase production using cheese whey powder (CWP solution

Directory of Open Access Journals (Sweden)

Leandro Freire dos Santos

2017-08-01

Full Text Available Whey is the liquid that results from the coagulation of milk during cheese manufacture. Cheese whey is also an important environmental pollution source. The present experiment sought to compare β-galactosidase (EC 3.2.1.23 production by Aspergillus oryzae from deproteinized and un-deproteinized CWP solutions. β-galactosidase was produced by submerged fermentation in deproteinized or un-deproteinized CWP solutions. To determine the activity of the enzyme, a reaction mixture containing cell-free extract and ortho Nitrophenyl β galactoside (ONPG was used. The results indicated that β-galactosidase induction was greater when using deproteinized CWP solution compared to the un deproteinized CWP solution. These results may enable an alternative management of cheese whey, thereby decreasing its impact on the environment and producing value-added biomacromolecules.

Compositional Solution Space Quantification for Probabilistic Software Analysis

Science.gov (United States)

Borges, Mateus; Pasareanu, Corina S.; Filieri, Antonio; d'Amorim, Marcelo; Visser, Willem

2014-01-01

Probabilistic software analysis aims at quantifying how likely a target event is to occur during program execution. Current approaches rely on symbolic execution to identify the conditions to reach the target event and try to quantify the fraction of the input domain satisfying these conditions. Precise quantification is usually limited to linear constraints, while only approximate solutions can be provided in general through statistical approaches. However, statistical approaches may fail to converge to an acceptable accuracy within a reasonable time. We present a compositional statistical approach for the efficient quantification of solution spaces for arbitrarily complex constraints over bounded floating-point domains. The approach leverages interval constraint propagation to improve the accuracy of the estimation by focusing the sampling on the regions of the input domain containing the sought solutions. Preliminary experiments show significant improvement on previous approaches both in results accuracy and analysis time.

Thermal processing of Khoot coal and characterization of obtained solid and liquid products

Directory of Open Access Journals (Sweden)

S Batbileg

2014-12-01

Full Text Available On 21st January 2015, the abstract of this paper was replaced with the correct abstract.The coal of Khoot deposit have been investigated and determined the technical characteristics, elemental and petrographical maceral compositions. On the basis of proximate, ultimate, petrographic and IR analysis results have been confirmed that the Khoot coal is a sub-bituminous coal. The hard residue after pyrolysis have been activated by heated water steam and determined the iodine and methylene blue adsorption of initial coal and activated carbon samples from pyrolysis hard residue. The porosity structure of initial coal, activated carbon of pyrolysis hard residue and hard residue after thermolysis (thermal dissolution have been determined by SEM analysis. The liquid tar product of thermolysis of Khoot coal was investigated by FTIR, 13C and 1H NMR spectrometric analysis. The results of thermolysis of Khoot coal in tetralin with constant mass ratio between coal and tetralin (1:1.8 at 450°C show that 60.8% of liquid product can be obtained after thermolysis of the coal organic mass.DOI: http://doi.dx.org/10.5564/mjc.v15i0.326 Mongolian Journal of Chemistry 15 (41, 2014, p66-72

Accounting for model error in Bayesian solutions to hydrogeophysical inverse problems using a local basis approach

Science.gov (United States)

Irving, J.; Koepke, C.; Elsheikh, A. H.

2017-12-01

Bayesian solutions to geophysical and hydrological inverse problems are dependent upon a forward process model linking subsurface parameters to measured data, which is typically assumed to be known perfectly in the inversion procedure. However, in order to make the stochastic solution of the inverse problem computationally tractable using, for example, Markov-chain-Monte-Carlo (MCMC) methods, fast approximations of the forward model are commonly employed. This introduces model error into the problem, which has the potential to significantly bias posterior statistics and hamper data integration efforts if not properly accounted for. Here, we present a new methodology for addressing the issue of model error in Bayesian solutions to hydrogeophysical inverse problems that is geared towards the common case where these errors cannot be effectively characterized globally through some parametric statistical distribution or locally based on interpolation between a small number of computed realizations. Rather than focusing on the construction of a global or local error model, we instead work towards identification of the model-error component of the residual through a projection-based approach. In this regard, pairs of approximate and detailed model runs are stored in a dictionary that grows at a specified rate during the MCMC inversion procedure. At each iteration, a local model-error basis is constructed for the current test set of model parameters using the K-nearest neighbour entries in the dictionary, which is then used to separate the model error from the other error sources before computing the likelihood of the proposed set of model parameters. We demonstrate the performance of our technique on the inversion of synthetic crosshole ground-penetrating radar traveltime data for three different subsurface parameterizations of varying complexity. The synthetic data are generated using the eikonal equation, whereas a straight-ray forward model is assumed in the inversion

Mean-field learning for satisfactory solutions

KAUST Repository

Tembine, Hamidou; Tempone, Raul; Vilanova, Pedro

2013-01-01

One of the fundamental challenges in distributed interactive systems is to design efficient, accurate, and fair solutions. In such systems, a satisfactory solution is an innovative approach that aims to provide all players with a satisfactory payoff

Thick brane solutions

International Nuclear Information System (INIS)

Dzhunushaliev, Vladimir; Minamitsuji, Masato; Folomeev, Vladimir

2010-01-01

This paper gives a comprehensive review on thick brane solutions and related topics. Such models have attracted much attention from many aspects since the birth of the brane world scenario. In many works, it has been usually assumed that a brane is an infinitely thin object; however, in more general situations, one can no longer assume this. It is also widely considered that more fundamental theories such as string theory would have a minimal length scale. Many multidimensional field theories coupled to gravitation have exact solutions of gravitating topological defects, which can represent our brane world. The inclusion of brane thickness can realize a variety of possible brane world models. Given our understanding, the known solutions can be classified into topologically non-trivial solutions and trivial ones. The former class contains solutions of a single scalar (domain walls), multi-scalar, gauge-Higgs (vortices), Weyl gravity and so on. As an example of the latter class, we consider solutions of two interacting scalar fields. Approaches to obtain cosmological equations in the thick brane world are reviewed. Solutions with spatially extended branes (S-branes) and those with an extra time-like direction are also discussed.

Finite element approach to solution of multidimensional quasi ...

African Journals Online (AJOL)

problems whose function can be expressed as derivatives and integrated functional or on solution of quasi-harmonic functions whose physical behaviors are governed by a general quasi-harmonic differential equation that can be treated as a quadratic functional that can be minimized over a region. The functional of a ...

Computational Approaches to Modeling Artificial Emotion -– An overview of the Proposed Solutions

Directory of Open Access Journals (Sweden)

Zdzislaw eKOWALCZUK

2016-04-01

Full Text Available Cybernetic approach to modeling artificial emotion through the use of different theories of psychology is considered in this paper, presenting a review of twelve proposed solutions: ActAffAct, FLAME, EMA, ParleE, FearNot!, FAtiMA, WASABI, Cathexis, KARO, MAMID, FCM, and xEmotion. The main motivation for this study is founded on the hypothesis that emotions can play a definite utility role of scheduling variables in the construction of intelligent autonomous systems, agents and mobile robots. In this review we also include an innovative and panoptical, comprehensive system, referred to as the Intelligent System of Decision-making (ISD, which has been employed in practical applications of various autonomous units, and which applies as its part the xEmotion, taking into consideration the personal aspects of emotions, affects (short term emotions and mood (principally, long term emotions.

A New Approach for the Approximations of Solutions to a Common Fixed Point Problem in Metric Fixed Point Theory

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Ishak Altun

2016-01-01

Full Text Available We provide sufficient conditions for the existence of a unique common fixed point for a pair of mappings T,S:X→X, where X is a nonempty set endowed with a certain metric. Moreover, a numerical algorithm is presented in order to approximate such solution. Our approach is different to the usual used methods in the literature.

α-Bromodiazoacetamides – a new class of diazo compounds for catalyst-free, ambient temperature intramolecular C–H insertion reactions

Directory of Open Access Journals (Sweden)

Åsmund Kaupang

2013-07-01

Full Text Available In this work, we introduce a new class of halodiazocarbonyl compounds, α-halodiazoacetamides, which through a metal-free, ambient-temperature thermolysis perform intramolecular C–H insertions to produce α-halo-β-lactams. When carried out with α-bromodiazoacetamides bearing cyclic side chains, the thermolysis reaction affords bicyclic α-halo-β-lactams, in some cases in excellent yields, depending on the ring size and substitution pattern of the cyclic amide side chains.

Sharing solutions - The users' group approach

International Nuclear Information System (INIS)

Kania, G.; Winter, K.

1991-01-01

Regulatory compliance, operating efficiency, and plant-life extension are common goals shared by all nuclear power plants. To achieve these goals, nuclear utilities must be proactive and responsive to the regulatory agencies, work together with each other in the sharing of operating experiences and solution to problems, and develop long-term working relationships with an even smaller number of quality suppliers. Users' and owners' groups are one of the most effective means of accomplishing these objectives. Users' groups facilitate communication between nuclear power plants and provide an interactive vendor interface. Both the utilities and suppliers benefit through shared information and improved customer feedback. This paper describes the evolution and experiences of the Sorrento Electronics (SE) Radiation Monitoring System (RMS) Users' Group. The authors highlight the group's past successes and plans for the future

A new approach to the solution of the vacuum magnetic problem in fusion machines

International Nuclear Information System (INIS)

Zabeo, L.; Artaserse, G.; Cenedese, A.; Piccolo, F.; Sartori, F.

2007-01-01

The magnetic vacuum topology reconstruction using magnetic measurements is essential in controlling and understanding plasmas produced in magnetic confinement fusion devices. In a wide range of cases, the instruments used to approach the problem have been designed for a specific machine and to solve a specific plasma model. Recently, a new approach has been used for developing new magnetic software called FELIX. The adopted solution in the design allows the use of the software not only at JET but also at other machines. In order to reduce the analysis and debugging time the software has been designed with modularity and platform independence in mind. This results in a large portability and in particular it allows using the same code both offline and in real-time. One of the main aspects of the tool is its capability to solve different plasma models of current distribution. Thanks to this feature, in order to improve the plasma magnetic reconstruction in real-time, a set of different models has been run using FELIX. FELIX is presently running at JET in different real-time analysis and control systems that need vacuum magnetic topology

Thermochemical stability of Soviet macroporous sulfonated cation-exchangers

Energy Technology Data Exchange (ETDEWEB)

Rukhlyada, N.N.; Plotnikova, V.P.; Roginskaya, B.S.; Znamenskii, Yu.P.; Zavodovskaya, A.S.; Dobrova, E.I.

1988-10-20

The purpose of this work was to study the influence of macroporosity on the thermochemical stability of sulfonated cation-exchangers. The investigations were carried out on commercial macroporous sulfonated cation-exchangers based on styrene-divinylbenzene copolymers. Study of the thermochemical stability of macroporous sulfonated cation-exchangers in dilute hydrogen peroxide solutions showed that the type of macroporosity has virtually no influence on their stability. The determining factor in thermal stability of macroporous cation-exchangers, as of the gel type, is the degree of cross-linking of the polymer matrix. The capacity loss of macroporous cation-exchangers during oxidative thermolysis is caused by destruction of the macromolecular skeleton and elution of fragments of polar chains containing sulfo groups into the solution.

Solution of the nonrelativistic wave equation using the tridiagonal representation approach

Science.gov (United States)

Alhaidari, A. D.

2017-07-01

We choose a complete set of square integrable functions as a basis for the expansion of the wavefunction in configuration space such that the matrix representation of the nonrelativistic time-independent linear wave operator is tridiagonal and symmetric. Consequently, the matrix wave equation becomes a symmetric three-term recursion relation for the expansion coefficients of the wavefunction. The recursion relation is then solved exactly in terms of orthogonal polynomials in the energy. Some of these polynomials are not found in the mathematics literature. The asymptotics of these polynomials give the phase shift for the continuous energy scattering states and the spectrum for the discrete energy bound states. Depending on the space and boundary conditions, the basis functions are written in terms of either the Laguerre or Jacobi polynomials. The tridiagonal requirement limits the number of potential functions that yield exact solutions of the wave equation. Nonetheless, the class of exactly solvable problems in this approach is larger than the conventional class (see, for example, Table XII in the text). We also give very accurate results for cases where the wave operator matrix is not tridiagonal but its elements could be evaluated either exactly or numerically with high precision.

Simulation of macromolecule self-assembly in solution: A multiscale approach

Energy Technology Data Exchange (ETDEWEB)

Lavino, Alessio D., E-mail: alessiodomenico.lavino@studenti.polito.it; Barresi, Antonello A., E-mail: antonello.barresi@polito.it; Marchisio, Daniele L., E-mail: daniele.marchisio@polito.it [Dipartimento di Scienza Applicata e Tecnologia, Istituto di Ingegneria Chimica, Politecnico di Torino, C.so Duca degli Abruzzi 24, 10129 Torino (Italy); Pasquale, Nicodemo di, E-mail: nicodemo.dipasquale@manchester.ac.uk [School of Chemistry, The University of Manchester, Oxford Road, Manchester M13 9PL, UnitedKingdom (United Kingdom); Carbone, Paola, E-mail: paola.carbone@manchester.ac.uk [School of Chemical Engineering and Analytical Science, The University of Manchester, Oxford Road, Manchester M13 9PL, UnitedKingdom (United Kingdom)

2015-12-17

One of the most common processes to produce polymer nanoparticles is to induce self-assembly by using the solvent-displacement method, in which the polymer is dissolved in a “good” solvent and the solution is then mixed with an “anti-solvent”. The polymer ability to self-assemble in solution is therefore determined by its structural and transport properties in solutions of the pure solvents and at the intermediate compositions. In this work, we focus on poly-ε-caprolactone (PCL) which is a biocompatible polymer that finds widespread application in the pharmaceutical and biomedical fields, performing simulation at three different scales using three different computational tools: full atomistic molecular dynamics (MD), population balance modeling (PBM) and computational fluid dynamics (CFD). Simulations consider PCL chains of different molecular weight in solution of pure acetone (good solvent), of pure water (anti-solvent) and their mixtures, and mixing at different rates and initial concentrations in a confined impinging jets mixer (CIJM). Our MD simulations reveal that the nano-structuring of one of the solvents in the mixture leads to an unexpected identical polymer structure irrespectively of the concentration of the two solvents. In particular, although in pure solvents the behavior of the polymer is, as expected, very different, at intermediate compositions, the PCL chain shows properties very similar to those found in pure acetone as a result of the clustering of the acetone molecules in the vicinity of the polymer chain. We derive an analytical expression to predict the polymer structural properties in solution at different solvent compositions and use it to formulate an aggregation kernel to describe the self-assembly in the CIJM via PBM and CFD. Simulations are eventually validated against experiments.

A Feminist Critique of Solution-Focused Therapy.

Science.gov (United States)

Dermer, Shannon B.; Hemesath, Crystal Wilhite; Russell, Candyce S.

1998-01-01

Applying the feminist critique to solution-focused therapy highlights the strengths and weaknesses of this model from a feminist perspective. Although solution-focused therapy and feminist approaches share an emphasis on competence and strengths, solution-focused theory tends to overlook gender and power differences. In general, the model falls…

A solution approach for non-linear analysis of concrete members

International Nuclear Information System (INIS)

Hadi, N. M.; Das, S.

1999-01-01

Non-linear solution of reinforced concrete structural members, at and beyond its maximum strength poses complex numerical problems. This is due to the fact that concrete exhibits strain softening behaviour once it reaches its maximum strength. This paper introduces an improved non-linear solution capable to overcome the numerical problems efficiently. The paper also presents a new concept of modeling discrete cracks in concrete members by using gap elements. Gap elements are placed in between two adjacent concrete elements in tensile zone. The magnitude of elongation of gap elements, which represents the width of the crack in concrete, increases edith the increase of tensile stress in those elements. As a result, transfer of local from one concrete element to adjacent elements reduces. Results of non-linear finite element analysis of three concrete beams using this new solution strategy are compared with those obtained by other researchers, and a good agreement is achieved. (authors). 13 refs. 9 figs.,

Flow-Solution-Liquid-Solid Growth of Semiconductor Nanowires: A Novel Approach for Controlled Synthesis

Energy Technology Data Exchange (ETDEWEB)

Hollingsworth, Jennifer A. [Los Alamos National Laboratory; Palaniappan, Kumaranand [Los Alamos National Laboratory; Laocharoensuk, Rawiwan [National Science and Technology Center, Thailand; Smith, Nickolaus A. [Los Alamos National Laboratory; Dickerson, Robert M. [Los Alamos National Laboratory; Casson, Joanna L. [Los Alamos National Laboratory; Baldwin, Jon K. [Los Alamos National Laboratory

2012-06-07

Semiconductor nanowires (SC-NWs) have potential applications in diverse technologies from nanoelectronics and photonics to energy harvesting and storage due to their quantum-confined opto-electronic properties coupled with their highly anisotropic shape. Here, we explore new approaches to an important solution-based growth method known as solution-liquid-solid (SLS) growth. In SLS, molecular precursors are reacted in the presence of low-melting metal nanoparticles that serve as molten fluxes to catalyze the growth of the SC-NWs. The mechanism of growth is assumed to be similar to that of vapor-liquid-solid (VLS) growth, with the clear distinctions of being conducted in solution in the presence of coordinating ligands and at relatively lower temperatures (<300 C). The resultant SC-NWs are soluble in common organic solvents and solution processable, offering advantages such as simplified processing, scale-up, ultra-small diameters for quantum-confinement effects, and flexible choice of materials from group III-V to groups II-VI, IV-VI, as well as truly ternary I-III-VI semiconductors as we recently demonstrates. Despite these advantages of SLS growth, VLS offers several clear opportunities not allowed by conventional SLS. Namely, VLS allows sequential addition of precursors for facile synthesis of complex axial heterostructures. In addition, growth proceeds relatively slowly compared to SLS, allowing clear assessments of growth kinetics. In order to retain the materials and processing flexibility afforded by SLS, but add the elements of controlled growth afforded by VLS, we transformed SLS into a flow based method by adapting it to synthesis in a microfluidic system. By this new method - so-called 'flow-SLS' (FSLS) - we have now demonstrated unprecedented fabrication of multi-segmented SC-NWs, e.g., 8-segmented CdSe/ZnSe defined by either compositionally abrupt or alloyed interfaces as a function of growth conditions. In addition, we have studied growth

New traveling wave solutions to AKNS and SKdV equations

International Nuclear Information System (INIS)

Ozer, Teoman

2009-01-01

We analyze the traveling wave solutions of Ablowitz-Kaup-Newell-Segur (AKNS) and Schwarz-Korteweg-de Vries (SKdV) equations. As the solution method for differential equations we consider the improved tanh approach. This approach provides to transform the partial differential equation into the ordinary differential equation and then obtain the new families of exact solutions based on the solutions of the Riccati equation. The different values of the coefficients of the Riccati equation allow us to obtain new type of traveling wave solutions to AKNS and SKdV equations.

On a direct approach to quasideterminant solutions of a noncommutative modified KP equation

International Nuclear Information System (INIS)

Gilson, C R; Nimmo, J J C; Sooman, C M

2008-01-01

A noncommutative version of the modified KP equation and a family of its solutions expressed as quasideterminants are discussed. The origin of these solutions is explained by means of Darboux transformations and the solutions are verified directly. We also verify directly an explicit connection between quasideterminant solutions of the noncommutative mKP equation and the noncommutative KP equation arising from the Miura transformation

Matched pairs approach to set theoretic solutions of the Yang-Baxter equation

International Nuclear Information System (INIS)

Gateva-Ivanova, T.; Majid, S.

2005-08-01

We study set-theoretic solutions (X,r) of the Yang-Baxter equations on a set X in terms of the induced left and right actions of X on itself. We give a characterization of involutive square-free solutions in terms of cyclicity conditions. We characterise general solutions in terms of an induced matched pair of unital semigroups S(X,r) and construct (S,r S ) from the matched pair. Finally, we study extensions of solutions in terms of matched pairs of their associated semigroups. We also prove several general results about matched pairs of unital semigroups of the required type, including iterated products S bowtie S bowtie S underlying the proof that r S is a solution, and extensions (S bowtie T, r Sb owtie T ). Examples include a general 'double' construction (S bowtie S,r Sb owtie S ) and some concrete extensions, their actions and graphs based on small sets. (author)

Forming of protective nanostructure coatings on metals and glasses and their properties investigation

International Nuclear Information System (INIS)

Deshkovskaya, A.; Lynkov, L.; Nagibarov, A.; Glybin, V.; Richter, E.; Pham, M.

2013-01-01

Transparent heat-resistant coatings of 10-30 nm thickness described by (ZrO 2 ) x •(Y 2 O 3 ) y composition are formed on the surface of metals and glasses by thermolysis technique. Produced coatings possess high adhesive strength, high corrosive and abrasive resistance. Nanocrystalline formations are revealed on samples surface, with quantity of these formations depending on basic solution concentration, formed layers number and thermal treatment mode. Ion-beam modification of obtained coatings under mixing mode enables said properties enhancing owing to zirconium oxiboride formation at substrate-coating interface as a result of ion-beam synthesis. (authors)

Solution immersed silicon (SIS)-based biosensors: a new approach in biosensing.

Science.gov (United States)

Diware, M S; Cho, H M; Chegal, W; Cho, Y J; Jo, J H; O, S W; Paek, S H; Yoon, Y H; Kim, D

2015-02-07

A novel, solution immersed silicon (SIS)-based sensor has been developed which employs the non-reflecting condition (NRC) for a p-polarized wave. The SIS sensor's response is almost independent of change in the refractive index (RI) of a buffer solution (BS) which makes it capable of measuring low-concentration and/or low-molecular-weight compounds.

Theoretical multi-physics approaches to solid-solution strengthening of Al

Energy Technology Data Exchange (ETDEWEB)

Ma, Duancheng; Friak, Martin; Raabe, Dierk; Neugebauer, Joerg [Max-Planck-Institut fuer Eisenforschung GmbH, Duesseldorf (Germany)

2009-07-01

The strengthening of soft metallic materials has a long tradition and is an important metallurgical topic since the time when ancient smiths forged the first swords. Intense materials research revealed a combination of three mechanisms as decisive for solid-solution strengthening phenomena: (i) the size mismatch of components (Mott and Nabarro's parelastic concept), (ii) the elastic modulus mismatch of atoms (Fleischer's dielastic contribution), and (iii) the concentration of solutes (statistical concept of Friedel and Labusch). Combining density functional theory calculations and linear-elasticity theory, the key parameters that are essential for the classical strengthening theories are determined in order to test them and identify their possible validity limits. The strengthening of fcc aluminium is chosen as an example and a series of binary systems Al-X (with X=Ca,Sr,Ir,Li,Mg,Cu) was considered. Comparing our results with those obtained by applying classical theories we find clear deviations. These deviations originate from non-classical lattice distortions due to the size mismatch of solute atoms in their first coordination shells.

Anisotropic solutions by gravitational decoupling

Science.gov (United States)

Ovalle, J.; Casadio, R.; da Rocha, R.; Sotomayor, A.

2018-02-01

We investigate the extension of isotropic interior solutions for static self-gravitating systems to include the effects of anisotropic spherically symmetric gravitational sources by means of the gravitational decoupling realised via the minimal geometric deformation approach. In particular, the matching conditions at the surface of the star with the outer Schwarzschild space-time are studied in great detail, and we describe how to generate, from a single physically acceptable isotropic solution, new families of anisotropic solutions whose physical acceptability is also inherited from their isotropic parent.

Anisotropic solutions by gravitational decoupling

Energy Technology Data Exchange (ETDEWEB)

Ovalle, J. [Silesian University in Opava, Institute of Physics and Research Centre of Theoretical Physics and Astrophysics, Faculty of Philosophy and Science, Opava (Czech Republic); Universidad Simon Bolivar, Departamento de Fisica, Caracas (Venezuela, Bolivarian Republic of); Casadio, R. [Alma Mater Universita di Bologna, Dipartimento di Fisica e Astronomia, Bologna (Italy); Istituto Nazionale di Fisica Nucleare, Bologna (Italy); Rocha, R. da [Universidade Federal do ABC (UFABC), Centro de Matematica, Computacao e Cognicao, Santo Andre, SP (Brazil); Sotomayor, A. [Universidad de Antofagasta, Departamento de Matematicas, Antofagasta (Chile)

2018-02-15

We investigate the extension of isotropic interior solutions for static self-gravitating systems to include the effects of anisotropic spherically symmetric gravitational sources by means of the gravitational decoupling realised via the minimal geometric deformation approach. In particular, the matching conditions at the surface of the star with the outer Schwarzschild space-time are studied in great detail, and we describe how to generate, from a single physically acceptable isotropic solution, new families of anisotropic solutions whose physical acceptability is also inherited from their isotropic parent. (orig.)

Sn approach applied to the solution of transport equation

International Nuclear Information System (INIS)

Lopes, J.P.

1973-09-01

In this work the origin of the Transport Theory is considered and the Transport Equation for the movement of the neutron in a system is established in its more general form, using the laws of nuclear physics. This equation is used as the starting point for development, under adequate assumptions, of simpler models that render the problem suitable for numerical solution. Representation of this model in different geometries is presented. The different processes of nuclear physics are introduced briefly and discussed. In addition, the boundary conditions for the different cases and a general procedure for the application of the Conservation Law are stated. The last chapter deals specifically with the S n method, its development, definitions and generalities. Computational schemes for obtaining the S n solution in spherical and cylindrical geometry, and convergence acceleration methods are also developed. (author)

Pure soliton solutions of some nonlinear partial differential equations

International Nuclear Information System (INIS)

Fuchssteiner, B.

1977-01-01

A general approach is given to obtain the system of ordinary differential equations which determines the pure soliton solutions for the class of generalized Korteweg-de Vries equations. This approach also leads to a system of ordinary differential equations for the pure soliton solutions of the sine-Gordon equation. (orig.) [de

Analytical approaches for the approximate solution of a nonlinear fractional ordinary differential equation

International Nuclear Information System (INIS)

Basak, K C; Ray, P C; Bera, R K

2009-01-01

The aim of the present analysis is to apply the Adomian decomposition method and He's variational method for the approximate analytical solution of a nonlinear ordinary fractional differential equation. The solutions obtained by the above two methods have been numerically evaluated and presented in the form of tables and also compared with the exact solution. It was found that the results obtained by the above two methods are in excellent agreement with the exact solution. Finally, a surface plot of the approximate solutions of the fractional differential equation by the above two methods is drawn for 0≤t≤2 and 1<α≤2.

Modelling solid solutions with cluster expansion, special quasirandom structures, and thermodynamic approaches

Science.gov (United States)

Saltas, V.; Horlait, D.; Sgourou, E. N.; Vallianatos, F.; Chroneos, A.

2017-12-01

Modelling solid solutions is fundamental in understanding the properties of numerous materials which are important for a range of applications in various fields including nanoelectronics and energy materials such as fuel cells, nuclear materials, and batteries, as the systematic understanding throughout the composition range of solid solutions for a range of conditions can be challenging from an experimental viewpoint. The main motivation of this review is to contribute to the discussion in the community of the applicability of methods that constitute the investigation of solid solutions computationally tractable. This is important as computational modelling is required to calculate numerous defect properties and to act synergistically with experiment to understand these materials. This review will examine in detail two examples: silicon germanium alloys and MAX phase solid solutions. Silicon germanium alloys are technologically important in nanoelectronic devices and are also relevant considering the recent advances in ternary and quaternary groups IV and III-V semiconductor alloys. MAX phase solid solutions display a palette of ceramic and metallic properties and it is anticipated that via their tuning they can have applications ranging from nuclear to aerospace industries as well as being precursors for particular MXenes. In the final part, a brief summary assesses the limitations and possibilities of the methodologies discussed, whereas there is discussion on the future directions and examples of solid solution systems that should prove fruitful to consider.

Towards demand-side solutions for mitigating climate change

Science.gov (United States)

Creutzig, Felix; Roy, Joyashree; Lamb, William F.; Azevedo, Inês M. L.; Bruine de Bruin, Wändi; Dalkmann, Holger; Edelenbosch, Oreane Y.; Geels, Frank W.; Grubler, Arnulf; Hepburn, Cameron; Hertwich, Edgar G.; Khosla, Radhika; Mattauch, Linus; Minx, Jan C.; Ramakrishnan, Anjali; Rao, Narasimha D.; Steinberger, Julia K.; Tavoni, Massimo; Ürge-Vorsatz, Diana; Weber, Elke U.

2018-04-01

Research on climate change mitigation tends to focus on supply-side technology solutions. A better understanding of demand-side solutions is missing. We propose a transdisciplinary approach to identify demand-side climate solutions, investigate their mitigation potential, detail policy measures and assess their implications for well-being.

Semi-mechanistic partial buffer approach to modeling pH, the buffer properties, and the distribution of ionic species in complex solutions.

Science.gov (United States)

Dougherty, Daniel P; Da Conceicao Neta, Edith Ramos; McFeeters, Roger F; Lubkin, Sharon R; Breidt, Frederick

2006-08-09

In many biological science and food processing applications, it is very important to control or modify pH. However, the complex, unknown composition of biological media and foods often limits the utility of purely theoretical approaches to modeling pH and calculating the distributions of ionizable species. This paper provides general formulas and efficient algorithms for predicting the pH, titration, ionic species concentrations, buffer capacity, and ionic strength of buffer solutions containing both defined and undefined components. A flexible, semi-mechanistic, partial buffering (SMPB) approach is presented that uses local polynomial regression to model the buffering influence of complex or undefined components in a solution, while identified components of known concentration are modeled using expressions based on extensions of the standard acid-base theory. The SMPB method is implemented in a freeware package, (pH)Tools, for use with Matlab. We validated the predictive accuracy of these methods by using strong acid titrations of cucumber slurries to predict the amount of a weak acid required to adjust pH to selected target values.

Doubly periodic solutions of the modified Kawahara equation

International Nuclear Information System (INIS)

Zhang Dan

2005-01-01

Some doubly periodic (Jacobi elliptic function) solutions of the modified Kawahara equation are presented in closed form. Our approach is to introduce a new auxiliary ordinary differential equation and use its Jacobi elliptic function solutions to construct doubly periodic solutions of the modified Kawahara equation. When the module m → 1, these solutions degenerate to the exact solitary wave solutions of the equation. Then we reveal the relation of some exact solutions for the modified Kawahara equation obtained by other authors

Photoelectrochemical water splitting with mesoporous hematite prepared by a solution-based colloidal approach.

Science.gov (United States)

Sivula, Kevin; Zboril, Radek; Le Formal, Florian; Robert, Rosa; Weidenkaff, Anke; Tucek, Jiri; Frydrych, Jiri; Grätzel, Michael

2010-06-02

Sustainable hydrogen production through photoelectrochemical water splitting using hematite (alpha-Fe(2)O(3)) is a promising approach for the chemical storage of solar energy, but is complicated by the material's nonoptimal optoelectronic properties. Nanostructuring approaches have been shown to increase the performance of hematite, but the ideal nanostructure giving high efficiencies for all absorbed light wavelengths remains elusive. Here, we report for the first time mesoporous hematite photoelectodes prepared by a solution-based colloidal method which yield water-splitting photocurrents of 0.56 mA cm(-2) under standard conditions (AM 1.5G 100 mW cm(-2), 1.23 V vs reversible hydrogen electrode, RHE) and over 1.0 mA cm(-2) before the dark current onset (1.55 V vs RHE). The sintering temperature is found to increase the average particle size, and have a drastic effect on the photoactivity. X-ray photoelectron spectroscopy and magnetic measurements using a SQUID magnetometer link this effect to the diffusion and incorporation of dopant atoms from the transparent conducting substrate. In addition, examining the optical properties of the films reveals a considerable change in the absorption coefficient and onset properties, critical aspects for hematite as a solar energy converter, as a function of the sintering temperature. A detailed investigation into hematite's crystal structure using powder X-ray diffraction with Rietveld refinement to account for these effects correlates an increase in a C(3v)-type crystal lattice distortion to the improved optical properties.

A New Solution Assessment Approach and Its Application to Space Geodesy Data Analysis

Science.gov (United States)

Hu, X.; Huang, C.; Liao, X.

2001-12-01

The statistics of the residuals are used in this paper to perform a quality assessment of the solutions from space geodesy data analysis. With the stochastic estimation and the relatively arbitrary empirical parameters being employed to absorb unmodelled errors, it has long been noticed that different estimate combinations or analysis strategies may achieve the same level of fitting yet result in significantly different solutions. Based on the postulate that no conceivable signals should remain in the residuals, solutions of the same level of root mean square error (RMS) and variance-covariance may be differentiated in the sense that for reasonable solutions, the residuals are virtually identical with noise. While it is possible to develop complex noise models, the Gaussian white noise model simplifies the solution interpretation and implies the unmodelled errors have been smoothed out. Statistical moments of the residuals as well as the Pearson chi-square are computed in this paper to measure the discrepancies between the residuals and Gaussian white noise. Applying to both satellite laser ranging (SLR) and global positioning system (GPS) data analysis, we evaluate different parameter estimate combinations and/or different strategies that would be hardly discriminated by the level of fitting. Unlike most solution assessment methods broadly termed as external comparison, no information independent of the data analyzed is required. This makes the immediate solution assessment possible and easy to carry out. While the external comparison is the best and most convincing quality assessment of the solution, the statistics of the residuals provide important information on the solutions and, in some cases as discussed in this paper, can be supported with external comparison.

Determination of the activity of a molecular solute in saturated solution

International Nuclear Information System (INIS)

Nordstroem, Fredrik L.; Rasmuson, Ake C.

2008-01-01

Prediction of the solubility of a solid molecular compound in a solvent, as well as, estimation of the solution activity coefficient from experimental solubility data both require estimation of the activity of the solute in the saturated solution. The activity of the solute in the saturated solution is often defined using the pure melt at the same temperature as the thermodynamic reference. In chemical engineering literature also the activity of the solid is usually defined on the same reference state. However, far below the melting temperature, the properties of this reference state cannot be determined experimentally, and different simplifications and approximations are normally adopted. In the present work, a novel method is presented to determine the activity of the solute in the saturated solution (=ideal solubility) and the heat capacity difference between the pure supercooled melt and solid. The approach is based on rigorous thermodynamics, using standard experimental thermodynamic data at the melting temperature of the pure compound and solubility measurements in different solvents at various temperatures. The method is illustrated using data for ortho-, meta-, and para-hydroxybenzoic acid, salicylamide and paracetamol. The results show that complete neglect of the heat capacity terms may lead to estimations of the activity that are incorrect by a factor of 12. Other commonly used simplifications may lead to estimations that are only one-third of the correct value

Determination of the activity of a molecular solute in saturated solution

Energy Technology Data Exchange (ETDEWEB)

Nordstroem, Fredrik L. [Department of Chemical Engineering and Technology, Royal Institute of Technology, 100 44 Stockholm (Sweden); Rasmuson, Ake C. [Department of Chemical Engineering and Technology, Royal Institute of Technology, 100 44 Stockholm (Sweden)], E-mail: rasmuson@ket.kth.se

2008-12-15

Prediction of the solubility of a solid molecular compound in a solvent, as well as, estimation of the solution activity coefficient from experimental solubility data both require estimation of the activity of the solute in the saturated solution. The activity of the solute in the saturated solution is often defined using the pure melt at the same temperature as the thermodynamic reference. In chemical engineering literature also the activity of the solid is usually defined on the same reference state. However, far below the melting temperature, the properties of this reference state cannot be determined experimentally, and different simplifications and approximations are normally adopted. In the present work, a novel method is presented to determine the activity of the solute in the saturated solution (=ideal solubility) and the heat capacity difference between the pure supercooled melt and solid. The approach is based on rigorous thermodynamics, using standard experimental thermodynamic data at the melting temperature of the pure compound and solubility measurements in different solvents at various temperatures. The method is illustrated using data for ortho-, meta-, and para-hydroxybenzoic acid, salicylamide and paracetamol. The results show that complete neglect of the heat capacity terms may lead to estimations of the activity that are incorrect by a factor of 12. Other commonly used simplifications may lead to estimations that are only one-third of the correct value.

Nitrile imines and nitrile ylides: rearrangements of benzonitrile N-methylimine and benzonitrile dimethylmethylide to azabutadienes, carbodiimides, and ketenimines. Chemical activation in thermolysis of azirenes, tetrazoles, oxazolones, isoxazolones, and oxadiazolones.

Science.gov (United States)

Bégué, Didier; Dargelos, Alain; Berstermann, Hans M; Netsch, Klaus P; Bednarek, Pawel; Wentrup, Curt

2014-02-07

Flash vacuum thermolysis (FVT) of 1-methyl-5-phenyltetrazole (5b), 2-methyl-5-phenyltetrazole (1b), and 3-methyl-5-phenyl-1,3,4-oxadiazol-2(3H)-one (3b) affords the nitrile imine (2b), which rearranges in part to N-methyl-N'-phenylcarbodiimide (7b). Another part of 2b undergoes a 1,4-H shift to the diazabutadiene (13). 13 undergoes two chemically activated decompositions, to benzonitrile and CH2═NH and to styrene and N2. FVT of 2,2-dimethyl-4-phenyl-oxazol-5(2H)-one (16) at 400 °C yields 3-methyl-1-phenyl-2-azabutadiene (18) in high yield. In contrast, FVT of 3,3-dimethyl-2-phenyl-1-azirene (21) at 600 °C or 4,4-dimethyl-3-phenyl-isoxazolone (20) at 600 °C affords only a low yield of azabutadiene (18) due to chemically activated decomposition of 18 to styrene and acetonitrile. There are two reaction paths from azirene (21): one (path a) leading to nitrile ylide (17) and the major products styrene and acetonitrile and the other (path b) leading to the vinylnitrene (22) and ketenimine (23). The nitrile ylide PhC(-)═N(+)═C(CH3)2 (17) is implicated as the immediate precursor of azabutadiene (18). FVT of either 3-phenylisoxazol-5(4H)one (25) or 2-phenylazirene (26) at 600 °C affords N-phenylketenimine (28). The nitrile ylide PhC(-)═N(+)═CH2 (30) is postulated as a reversibly formed intermediate. N-Phenylketenimine (28) undergoes chemically activated free radical rearrangement to benzyl cyanide. The mechanistic interpretations are supported by calculations of the energies of key intermediates and transition states.

Exact cosmological solutions for MOG

International Nuclear Information System (INIS)

Roshan, Mahmood

2015-01-01

We find some new exact cosmological solutions for the covariant scalar-tensor-vector gravity theory, the so-called modified gravity (MOG). The exact solution of the vacuum field equations has been derived. Also, for non-vacuum cases we have found some exact solutions with the aid of the Noether symmetry approach. More specifically, the symmetry vector and also the Noether conserved quantity associated to the point-like Lagrangian of the theory have been found. Also we find the exact form of the generic vector field potential of this theory by considering the behavior of the relevant point-like Lagrangian under the infinitesimal generator of the Noether symmetry. Finally, we discuss the cosmological implications of the solutions. (orig.)

Reactive solute transport in streams: A surface complexation approach for trace metal sorption

Science.gov (United States)

Runkel, Robert L.; Kimball, Briant A.; McKnight, Diane M.; Bencala, Kenneth E.

1999-01-01

A model for trace metals that considers in-stream transport, metal oxide precipitation-dissolution, and pH-dependent sorption is presented. Linkage between a surface complexation submodel and the stream transport equations provides a framework for modeling sorption onto static and/or dynamic surfaces. A static surface (e.g., an iron- oxide-coated streambed) is defined as a surface with a temporally constant solid concentration. Limited contact between solutes in the water column and the static surface is considered using a pseudokinetic approach. A dynamic surface (e.g., freshly precipitated metal oxides) has a temporally variable solid concentration and is in equilibrium with the water column. Transport and deposition of solute mass sorbed to the dynamic surface is represented in the stream transport equations that include precipitate settling. The model is applied to a pH-modification experiment in an acid mine drainage stream. Dissolved copper concentrations were depressed for a 3 hour period in response to the experimentally elevated pH. After passage of the pH front, copper was desorbed, and dissolved concentrations returned to ambient levels. Copper sorption is modeled by considering sorption to aged hydrous ferric oxide (HFO) on the streambed (static surface) and freshly precipitated HFO in the water column (dynamic surface). Comparison of parameter estimates with reported values suggests that naturally formed iron oxides may be more effective in removing trace metals than synthetic oxides used in laboratory studies. The model's ability to simulate pH, metal oxide precipitation-dissolution, and pH-dependent sorption provides a means of evaluating the complex interactions between trace metal chemistry and hydrologic transport at the field scale.

Category Theory Approach to Solution Searching Based on Photoexcitation Transfer Dynamics

Directory of Open Access Journals (Sweden)

Makoto Naruse

2017-07-01

Full Text Available Solution searching that accompanies combinatorial explosion is one of the most important issues in the age of artificial intelligence. Natural intelligence, which exploits natural processes for intelligent functions, is expected to help resolve or alleviate the difficulties of conventional computing paradigms and technologies. In fact, we have shown that a single-celled organism such as an amoeba can solve constraint satisfaction problems and related optimization problems as well as demonstrate experimental systems based on non-organic systems such as optical energy transfer involving near-field interactions. However, the fundamental mechanisms and limitations behind solution searching based on natural processes have not yet been understood. Herein, we present a theoretical background of solution searching based on optical excitation transfer from a category-theoretic standpoint. One important indication inspired by the category theory is that the satisfaction of short exact sequences is critical for an adequate computational operation that determines the flow of time for the system and is termed as “short-exact-sequence-based time.” In addition, the octahedral and braid structures known in triangulated categories provide a clear understanding of the underlying mechanisms, including a quantitative indication of the difficulties of obtaining solutions based on homology dimension. This study contributes to providing a fundamental background of natural intelligence.

A thermodynamic approach to assess organic solute adsorption onto activated carbon in water

KAUST Repository

De Ridder, David J.; Verliefde, Arne R. D.; Heijman, Bas G J; Gelin, Simon; Pereira, Manuel Fernando Ribeiro; Rocha, Raquel P.; Figueiredo, José Luí s M; Amy, Gary L.; Van Dijk, Hans C.

2012-01-01

In this paper, the hydrophobicity of 13 activated carbons is determined by various methods; water vapour adsorption, immersion calorimetry, and contact angle measurements. The quantity and type of oxygen-containing groups on the activated carbon were measured and related to the methods used to measure hydrophobicity. It was found that the water-activated carbon adsorption strength (based on immersion calorimetry, contact angles) depended on both type and quantity of oxygen-containing groups, while water vapour adsorption depended only on their quantity. Activated carbon hydrophobicity measurements alone could not be related to 1-hexanol and 1,3-dichloropropene adsorption. However, a relationship was found between work of adhesion and adsorption of these solutes. The work of adhesion depends not only on activated carbon-water interaction (carbon hydrophobicity), but also on solute-water (solute hydrophobicity) and activated carbon-solute interactions. Our research shows that the work of adhesion can explain solute adsorption and includes the effect of hydrogen bond formation between solute and activated carbon. © 2012 Elsevier Ltd. All rights reserved.

A thermodynamic approach to assess organic solute adsorption onto activated carbon in water

KAUST Repository

De Ridder, David J.

2012-08-01

In this paper, the hydrophobicity of 13 activated carbons is determined by various methods; water vapour adsorption, immersion calorimetry, and contact angle measurements. The quantity and type of oxygen-containing groups on the activated carbon were measured and related to the methods used to measure hydrophobicity. It was found that the water-activated carbon adsorption strength (based on immersion calorimetry, contact angles) depended on both type and quantity of oxygen-containing groups, while water vapour adsorption depended only on their quantity. Activated carbon hydrophobicity measurements alone could not be related to 1-hexanol and 1,3-dichloropropene adsorption. However, a relationship was found between work of adhesion and adsorption of these solutes. The work of adhesion depends not only on activated carbon-water interaction (carbon hydrophobicity), but also on solute-water (solute hydrophobicity) and activated carbon-solute interactions. Our research shows that the work of adhesion can explain solute adsorption and includes the effect of hydrogen bond formation between solute and activated carbon. © 2012 Elsevier Ltd. All rights reserved.

Recovering Process from Child Sexual Abuse During Adulthood from an Integrative Approach to Solution-Focused Therapy: A Case Study.

Science.gov (United States)

Gonzalez, Carolina

2017-10-01

In recent times, strengths-based recovery approaches that focus on the present and build strategies that look toward the future have become popular. However, some cases require the consideration of experiences from previous stages of the clients' development. This single-case study explores the psychotherapeutic process of a middle-aged woman who presented with a history of child sexual abuse (incest) and a long-term adult diagnosis of depression that was treated in public health services. This psychotherapy involved an integrative approach to solution-focused therapy; specifically, the approach proposed by Yvonne Dolan to work with adult survivors of sexual abuse, in conjunction with techniques and strategies from the transtheoretical model. Measures incorporating therapeutic working alliance and outcomes were administered over sessions. Results showed positive outcomes from this therapeutic intervention, which remained at 3-month and 12-month follow-ups. Implications for practitioners' specialist practice in health services are discussed, given the complexity of comorbid mental health conditions with a history of child sexual abuse.

Investigations to explore interactions in (polyhydroxy solute + L-ascorbic acid + H2O) solutions at different temperatures: Calorimetric and viscometric approach

International Nuclear Information System (INIS)

Banipal, Parampaul K.; Sharma, Mousmee; Aggarwal, Neha; Banipal, Tarlok S.

2016-01-01

Highlights: • The hydrophilic-hydrophilic interactions predominate at low temperatures. • Enthalpy change for polyol is less exothermic than its parent saccharide. • Δ dil C o p,2,m values suggest structural increase in presence of L-ascorbic acid. • Solutes act as kosmotropes in L-ascorbic acid (aq) solutions as indicated by dB/dT. - Abstract: Isothermal titration micro-calorimeter has been used to measure the enthalpy change (q) of polyhydroxy solutes [(+)-D-xylose, xylitol, (+)-D-glucose, 2-deoxy-D-glucose, (+)-methyl-α-D-glucopyranoside, and (+)-maltose monohydrate] in water and in (0.05, 0.15, and 0.25) mol·kg −1 L-ascorbic acid (aq) solutions at (288.15, 298.15, 308.15, and 318.15) K. Limiting enthalpies of dilution (Δ dil H°) of these solutes were calculated from heat evolved/absorbed during calorimetric experiments. Further thermodynamic quantities such as limiting enthalpies of dilution of transfer (Δ tr Δ dil H°), change in heat capacity (Δ dil C o p,2,m ), and pair (h AB ) and triplet (h ABB ) enthalpic interaction coefficients were also calculated and used to explore the nature of interactions of solutes with cosolute (L-ascorbic acid). The Jones-Dole viscosity B-coefficients for (+)-D-xylose, xylitol, (+)-D-galactose, galactitol, (+)-D-glucose, 2-deoxy-D-glucose, (+)-methyl-α-D-glucopyranoside, and (+)-maltose monohydrate in water and in (0.05, 0.15, 0.25, and 0.35) mol·kg −1 L-ascorbic acid (aq) solutions have been determined from viscosity (η) data measured over temperature range (288.15–318.15) K and at pressure, P = 101.3 kPa. The temperature dependence of B-coefficients (dB/dT), and viscosity B-coefficients of transfer (Δ tr B) of solutes from water to cosolute have also been estimated. These parameters have been discussed in terms of structure-making (kosmotropic) or -breaking (chaotropic) behavior of solutes.

Cellular solutions for the Poisson equation in extended systems

International Nuclear Information System (INIS)

Zhang, X.; Butler, W.H.; MacLaren, J.M.; van Ek, J.

1994-01-01

The Poisson equation for the electrostatic potential in a solid is solved using three different cellular techniques. The relative merits of these different approaches are discussed for two test charge densities for which an analytic solution to the Poisson equation is known. The first approach uses full-cell multiple-scattering theory and results in the famililar structure constant and multipole moment expansion. This solution is shown to be valid everywhere inside the cell, although for points outside the muffin-tin sphere but inside the cell the sums must be performed in the correct order to yield meaningful results. A modification of the multiple-scattering-theory approach yields a second method, a Green-function cellular method, which only requires the solution of a nearest-neighbor linear system of equations. A third approach, a related variational cellular method, is also derived. The variational cellular approach is shown to be the most accurate and reliable, and to have the best convergence in angular momentum of the three methods. Coulomb energies accurate to within 10 -6 hartree are easily achieved with the variational cellular approach, demonstrating the practicality of the approach in electronic structure calculations

A new approach to the solution of the vacuum magnetic problem in fusion machines

International Nuclear Information System (INIS)

Zabeo, L.; Piccolo, F.; Sartori, F.; Albanese, R.; Cenedese, A.

2006-01-01

The magnetic vacuum topology reconstruction using the magnetic measurements is essential in controlling and understanding plasmas produced by fusion machines. In a wide range of the cases, the instruments to approach the problem have been designed for a specific machine and to solve a specific plasma model. Recently a new approach has been used by developing new magnetic software called Felix. The adopted solution in the design allows the use of the software not only at JET but also at different machines by simply changing a configuration file. A database describing the tokamak in the magnetic point of view is used to provide different vacuum magnetic models (polynomial, moments, filamentary) that can be solved by Felix without any recompiling or testing. In order to reduce the analysis and debugging time the software has been designed with modularity and platform independence in mind. That results in a large portability and in particular it allows use of the same code both offline and in real-time. One of the main aspects of the tool is its capability to solve different plasma models of current distribution by changing its configuration file. In order to improve the plasma magnetic reconstruction in real time a set of models has been run using Felix. An improved polynomial based model compared with the one presently used and two models using current filaments have been tested and compared. The new system has also been improved the calculation of plasma magnetic parameters. Double null configurations smooth transitions, more accurate gap and strike-point calculations, detailed boundary reconstruction are now systematically available. Felix is presently running at JET in different real-time analysis and control systems that need vacuum magnetic topology such as control of the plasma shape, the wall protection system [F.Piccolo et al.'Upgrade of the protection system for the first wall at JET in the ITER Be and W tiles prespective' this conference], the magnetic

Calculation of deformation rate of interstitial solid solutions under irradiation with usage of the object-oriented approach

International Nuclear Information System (INIS)

Lopuga, A.D.; Pyatiletov, Yu.S.

2000-01-01

The creep rate is determined by streams of self point defects and mobile complexes impurity - free point defect on the dislocation. These streams are by the numerical method, if the stationary distributions of point defects in a neighbourhood of sinks are known. For solution of this composite system of the nonlinear differential equations the object-oriented approach utilized, which one represents series iterative process consisting of four stages: the analysis, designing, evolution and modification. On the basis of the object-oriented approach, the program application DefRate.exe for research of radiation creep rate is created. The application works in an operating system Windows. As all parameters are set interactive, the designed program can be easily utilized for research of the broad set of materials. The introduced object-oriented method is applicable for research of the broad set of processes controlled by the diffusion, such as the swelling and radiation creep of construction materials, the hydrogen permeability etc

Consequences of energy conservation violation: late time solutions of Λ(T)CDM subclass of f(R,T) gravity using dynamical system approach

Energy Technology Data Exchange (ETDEWEB)

Shabani, Hamid [University of Sistan and Baluchestan, Physics Department, Faculty of Sciences, Zahedan (Iran, Islamic Republic of); Ziaie, Amir Hadi [Islamic Azad University, Department of Physics, Kahnooj Branch, Kerman (Iran, Islamic Republic of)

2017-05-15

Very recently, Josset and Perez (Phys. Rev. Lett. 118:021102, 2017) have shown that a violation of the energy-momentum tensor (EMT) could result in an accelerated expansion state via the appearance of an effective cosmological constant, in the context of unimodular gravity. Inspired by this outcome, in this paper we investigate cosmological consequences of a violation of the EMT conservation in a particular class of f(R,T) gravity when only the pressure-less fluid is present. In this respect, we focus on the late time solutions of models of the type f(R,T) = R + βΛ(-T). As the first task, we study the solutions when the conservation of EMT is respected, and then we proceed with those in which violation occurs. We have found, provided that the EMT conservation is violated, that there generally exist two accelerated expansion solutions of which the stability properties depend on the underlying model. More exactly, we obtain a dark energy solution for which the effective equation of state depends on the model parameters and a de Sitter solution. We present a method to parametrize the Λ(-T) function, which is useful in a dynamical system approach and has been employed in the model. Also, we discuss the cosmological solutions for models with Λ(-T) = 8πG(-T){sup α} in the presence of ultra-relativistic matter. (orig.)

Exact and heuristic solutions to the Double TSP with Multiple Stacks

DEFF Research Database (Denmark)

Petersen, Hanne Løhmann; Archetti, Claudia; Madsen, Oli B.G.

-pallet, which can be loaded in 3 stacks in a standard 40 foot container. Different exact and heuristic solution approaches to the DTSPMS have been implemented and tested. The exact approaches are based on different mathematical formulations of the problem which are solved using branch-and-cut. One formulation...... instances. The implemented heuristics include tabu search, simulated annealing and large neighbourhood search. Particularly the LNS approach shows promising results. It finds the known optimal solution of smaller instances (15 orders) within 10 seconds in most cases, and in 3 minutes it finds solutions...

Citropin 1.1 Trifluoroacetate to Chloride Counter-Ion Exchange in HCl-Saturated Organic Solutions: An Alternative Approach.

Science.gov (United States)

Sikora, Karol; Neubauer, Damian; Jaśkiewicz, Maciej; Kamysz, Wojciech

2018-01-01

In view of the increasing interest in peptides in various market sectors, a stronger emphasis on topics related to their production has been seen. Fmoc-based solid phase peptide synthesis, although being fast and efficient, provides final products with significant amounts of trifluoroacetate ions in the form of either a counter-ion or an unbound impurity. Because of the proven toxicity towards cells and peptide activity inhibition, ion exchange to more biocompatible one is purposeful. Additionally, as most of the currently used counter-ion exchange techniques are time-consuming and burdened by peptide yield reduction risk, development of a new approach is still a sensible solution. In this study, we examined the potential of peptide counter-ion exchange using non-aqueous organic solvents saturated with HCl. Counter-ion exchange of a model peptide, citropin 1.1 (GLFDVIKKVASVIGGL-NH 2 ), for each solvent was conducted through incubation with subsequent evaporation under reduced pressure, dissolution in water and lyophilization. Each exchange was performed four times and compared to a reference method-lyophilization of the peptide from an 0.1 M HCl solution. The results showed superior counter-ion exchange efficiency for most of the organic solutions in relation to the reference method. Moreover, HCl-saturated acetonitrile and tert -butanol provided a satisfying exchange level after just one repetition. Thus, those two organic solvents can be potentially introduced into routine peptide counter-ion exchange.

SU-F-R-10: Selecting the Optimal Solution for Multi-Objective Radiomics Model

International Nuclear Information System (INIS)

Zhou, Z; Folkert, M; Wang, J

2016-01-01

Purpose: To develop an evidential reasoning approach for selecting the optimal solution from a Pareto solution set obtained by a multi-objective radiomics model for predicting distant failure in lung SBRT. Methods: In the multi-objective radiomics model, both sensitivity and specificity are considered as the objective functions simultaneously. A Pareto solution set with many feasible solutions will be resulted from the multi-objective optimization. In this work, an optimal solution Selection methodology for Multi-Objective radiomics Learning model using the Evidential Reasoning approach (SMOLER) was proposed to select the optimal solution from the Pareto solution set. The proposed SMOLER method used the evidential reasoning approach to calculate the utility of each solution based on pre-set optimal solution selection rules. The solution with the highest utility was chosen as the optimal solution. In SMOLER, an optimal learning model coupled with clonal selection algorithm was used to optimize model parameters. In this study, PET, CT image features and clinical parameters were utilized for predicting distant failure in lung SBRT. Results: Total 126 solution sets were generated by adjusting predictive model parameters. Each Pareto set contains 100 feasible solutions. The solution selected by SMOLER within each Pareto set was compared to the manually selected optimal solution. Five-cross-validation was used to evaluate the optimal solution selection accuracy of SMOLER. The selection accuracies for five folds were 80.00%, 69.23%, 84.00%, 84.00%, 80.00%, respectively. Conclusion: An optimal solution selection methodology for multi-objective radiomics learning model using the evidential reasoning approach (SMOLER) was proposed. Experimental results show that the optimal solution can be found in approximately 80% cases.

SU-F-R-10: Selecting the Optimal Solution for Multi-Objective Radiomics Model

Energy Technology Data Exchange (ETDEWEB)

Zhou, Z; Folkert, M; Wang, J [UT Southwestern Medical Center, Dallas, TX (United States)

2016-06-15

Purpose: To develop an evidential reasoning approach for selecting the optimal solution from a Pareto solution set obtained by a multi-objective radiomics model for predicting distant failure in lung SBRT. Methods: In the multi-objective radiomics model, both sensitivity and specificity are considered as the objective functions simultaneously. A Pareto solution set with many feasible solutions will be resulted from the multi-objective optimization. In this work, an optimal solution Selection methodology for Multi-Objective radiomics Learning model using the Evidential Reasoning approach (SMOLER) was proposed to select the optimal solution from the Pareto solution set. The proposed SMOLER method used the evidential reasoning approach to calculate the utility of each solution based on pre-set optimal solution selection rules. The solution with the highest utility was chosen as the optimal solution. In SMOLER, an optimal learning model coupled with clonal selection algorithm was used to optimize model parameters. In this study, PET, CT image features and clinical parameters were utilized for predicting distant failure in lung SBRT. Results: Total 126 solution sets were generated by adjusting predictive model parameters. Each Pareto set contains 100 feasible solutions. The solution selected by SMOLER within each Pareto set was compared to the manually selected optimal solution. Five-cross-validation was used to evaluate the optimal solution selection accuracy of SMOLER. The selection accuracies for five folds were 80.00%, 69.23%, 84.00%, 84.00%, 80.00%, respectively. Conclusion: An optimal solution selection methodology for multi-objective radiomics learning model using the evidential reasoning approach (SMOLER) was proposed. Experimental results show that the optimal solution can be found in approximately 80% cases.

Comparison of groundwater transit velocity estimates from flux theory and water table recession based approaches for solute transport.

Science.gov (United States)

Rasiah, Velu; Armour, John David

2013-02-15

Reliable information in transit time (TT) derived from transit velocity (TV) for rain or irrigation water to mix with groundwater (GW) and the subsequent discharge to surface water bodies (SWB) is essential to address the issues associated with the transport of nutrients, particularly nitrate, from GW to SWB. The objectives of this study are to (i) compare the TV estimates obtained using flux theory-based (FT) approach with the water table rise/recession (WT) rate approach and (ii) explore the impact of the differences on solute transport from GW to SWB. The results from a study conducted during two rainy seasons in the northeast humid tropics of Queensland, Australia, showed the TV varied in space and over time and the variations depended on the estimation procedures. The lateral TV computed using the WT approach ranged from 1.00 × 10(-3) to 2.82 × 10(-1) m/d with a mean of 6.18 × 10(-2) m/d compared with 2.90 × 10(-4) to 5.15 × 10(-2) m/d for FT with a mean of 2.63 × 10(-2) m/d. The vertical TV ranged from 2.00 × 10(-3) to 6.02 × 10(-1) m/d with a mean of 1.28 × 10(-1) m/d for the WT compared with 6.76 × 10(-3)-1.78 m/d for the FT with a mean of 2.73 × 10(-1) m/d. These differences are attributed to the role played by different flow pathways. The bypass flow pathway played a role only in WT but not in FT. Approximately 86-95% of the variability in lateral solute transport was accounted for by the lateral TV and the total recession between two consecutive major rainfall events. A comparison of TT from FT and WT approaches indicated the laterally transported nitrate from the GW to the nearby creek was relatively 'new', implying the opportunity for accumulation and to undergo biochemical reactions in GW was low. The results indicated the WT approach produced more reliable TT estimates than FT in the presence of bypass flow pathways. Copyright © 2012 Elsevier Ltd. All rights reserved.

Sparse Solutions for Single Class SVMs: A Bi-Criterion Approach

Data.gov (United States)

National Aeronautics and Space Administration — In this paper we propose an innovative learning algorithm - a variation of One-class Support Vector Machines (SVMs) learning algorithm to produce sparser solutions...

Operator approach to solutions of the constrained BKP hierarchy

International Nuclear Information System (INIS)

Shen, Hsin-Fu; Lee, Niann-Chern; Tu, Ming-Hsien

2011-01-01

The operator formalism to the vector k-constrained BKP hierarchy is presented. We solve the Hirota bilinear equations of the vector k-constrained BKP hierarchy via the method of neutral free fermion. In particular, by choosing suitable group element of O(∞), we construct rational and soliton solutions of the vector k-constrained BKP hierarchy.

Solution approaches of social adaptation of orphan children

OpenAIRE

Olga Vahrameeva

2013-01-01

The actual problem of social-cultural activity of boarding schools directed on process of social adaptation of orphan children and children who have remained without guardianship of parents is considered in the article. Author offers use of an individual approach during the work with orphan children. This approach includes carrying out a complex of the interconnected programs of social and pedagogical work with the use of technologies of the social-cultural activity, which main objective is a...

Thermal decomposition of rhenium (5) complexes with 1,2,4-triazole

International Nuclear Information System (INIS)

Amindzhanov, A.A.; Gagieva, S.Ch.; Kotegov, K.V.

1991-01-01

Processes of thermal decomposition of rhenium (5) complexes with 1,2,4-triazole were studied. Thermolysis products were identified on the basis of data of the element analysis, IR spectra, conductometry and other methods. It is ascertained that at the first stage of thermolysis of hydroxyl-containing monomer complexes removal of water molecules occurs, and at the second one - dimerization process with formation of Re-O-Re group. It is shown that the nature of halide ion practically does not affect the temperature of the start of intensive thermal decomposition of the complexes

Thermal decomposition of rhenium (5) complexes with 1,2,4-triazole. Termicheskoe razlozhenie kompleksov reniya (5) s 1,2,4-triazolom

Energy Technology Data Exchange (ETDEWEB)

Amindzhanov, A A; Gagieva, S Ch; Kotegov, K V [Tadzhikskij Gosudarstvennyj Univ., Dushanbe (Tajikistan)

1991-01-01

Processes of thermal decomposition of rhenium (5) complexes with 1,2,4-triazole were studied. Thermolysis products were identified on the basis of data of the element analysis, IR spectra, conductometry and other methods. It is ascertained that at the first stage of thermolysis of hydroxyl-containing monomer complexes removal of water molecules occurs, and at the second one - dimerization process with formation of Re-O-Re group. It is shown that the nature of halide ion practically does not affect the temperature of the start of intensive thermal decomposition of the complexes.

A Photoelectron Spectroscopic Study of Di-t-butylphosphazene

DEFF Research Database (Denmark)

Elbel, S.; Ellis, A.; Niecke, E.

1985-01-01

Gaseous trans-ButPNBut, generated by mild gas-phase thermolysis of its more stable [2 + 1] cyclodimer, has been characterized by field-ionization mass spectrometry and U.V. photoelectron spectroscopy. The photoelectron spectrum has been assigned based on SCC-Xα model calculations for representat......Gaseous trans-ButPNBut, generated by mild gas-phase thermolysis of its more stable [2 + 1] cyclodimer, has been characterized by field-ionization mass spectrometry and U.V. photoelectron spectroscopy. The photoelectron spectrum has been assigned based on SCC-Xα model calculations...

Solution of underdetermined systems of equations with gridded a priori constraints.

Science.gov (United States)

Stiros, Stathis C; Saltogianni, Vasso

2014-01-01

The TOPINV, Topological Inversion algorithm (or TGS, Topological Grid Search) initially developed for the inversion of highly non-linear redundant systems of equations, can solve a wide range of underdetermined systems of non-linear equations. This approach is a generalization of a previous conclusion that this algorithm can be used for the solution of certain integer ambiguity problems in Geodesy. The overall approach is based on additional (a priori) information for the unknown variables. In the past, such information was used either to linearize equations around approximate solutions, or to expand systems of observation equations solved on the basis of generalized inverses. In the proposed algorithm, the a priori additional information is used in a third way, as topological constraints to the unknown n variables, leading to an R(n) grid containing an approximation of the real solution. The TOPINV algorithm does not focus on point-solutions, but exploits the structural and topological constraints in each system of underdetermined equations in order to identify an optimal closed space in the R(n) containing the real solution. The centre of gravity of the grid points defining this space corresponds to global, minimum-norm solutions. The rationale and validity of the overall approach are demonstrated on the basis of examples and case studies, including fault modelling, in comparison with SVD solutions and true (reference) values, in an accuracy-oriented approach.

Mass transfer simulation of nanofiltration membranes for electrolyte solutions through generalized Maxwell-Stefan approach

International Nuclear Information System (INIS)

Hoshyargar, Vahid; Fadaei, Farzad; Ashrafizadeh, Seyed Nezameddin

2015-01-01

A comprehensive mathematical model is developed for simulation of ion transport through nanofiltration membranes. The model is based on the Maxwell-Stefan approach and takes into account steric, Donnan, and dielectric effects in the transport of mono and divalent ions. Theoretical ion rejection for multi-electrolyte mixtures was obtained by numerically solving the 'hindered transport' based on the generalized Maxwell-Stefan equation for the flux of ions. A computer simulation has been developed to predict the transport in the range of nanofiltration, a numerical procedure developed linearization and discretization form of the governing equations, and the finite volume method was employed for the numerical solution of equations. The developed numerical method is capable of solving equations for multicomponent systems of n species no matter to what extent the system shows stiffness. The model findings were compared and verified with the experimental data from literature for two systems of Na 2 SO 4 +NaCl and MgCl 2 +NaCl. Comparison showed great agreement for different concentrations. As such, the model is capable of predicting the rejection of different ions at various concentrations. The advantage of such a model is saving costs as a result of minimizing the number of required experiments, while it is closer to a realistic situation since the adsorption of ions has been taken into account. Using this model, the flux of permeates and rejections of multi-component liquid feeds can be calculated as a function of membrane properties. This simulation tool attempts to fill in the gap in methods used for predicting nanofiltration and optimization of the performance of charged nanofilters through generalized Maxwell-Stefan (GMS) approach. The application of the current model may weaken the latter gap, which has arisen due to the complexity of the fundamentals of ion transport processes via this approach, and may further facilitate the industrial development of

Soliton solutions for ABS lattice equations: I. Cauchy matrix approach

Science.gov (United States)

Nijhoff, Frank; Atkinson, James; Hietarinta, Jarmo

2009-10-01

In recent years there have been new insights into the integrability of quadrilateral lattice equations, i.e. partial difference equations which are the natural discrete analogues of integrable partial differential equations in 1+1 dimensions. In the scalar (i.e. single-field) case, there now exist classification results by Adler, Bobenko and Suris (ABS) leading to some new examples in addition to the lattice equations 'of KdV type' that were known since the late 1970s and early 1980s. In this paper, we review the construction of soliton solutions for the KdV-type lattice equations and use those results to construct N-soliton solutions for all lattice equations in the ABS list except for the elliptic case of Q4, which is left to a separate treatment.

Acquisition and Analysis of Data from High Concentration Solutions

KAUST Repository

Besong, Tabot M.D.

2016-05-13

The problems associated with ultracentrifugal analysis of macromolecular solutions at high (>10 mg/ml) are reviewed. Especially for the case of solutes which are non-monodisperse, meaningful results are not readily achievable using sedimentation velocity approaches. It is shown however by both simulation and analysis of practical data that using a modified form of an algorithm (INVEQ) published in other contexts, sedimentation equilibrium (SE) profiles can be analysed successfully, enabling topics such as oligomer presence or formation to be defined.To achieve this, it is necessary to employ an approach in which the solution density, which in an SE profile is radius-dependent, is taken into consideration. Simulation suggests that any reasonable level of solute concentration can be analysed.

Acquisition and Analysis of Data from High Concentration Solutions

KAUST Repository

Besong, Tabot M.D.; Rowe, Arthur J.

2016-01-01

The problems associated with ultracentrifugal analysis of macromolecular solutions at high (>10 mg/ml) are reviewed. Especially for the case of solutes which are non-monodisperse, meaningful results are not readily achievable using sedimentation velocity approaches. It is shown however by both simulation and analysis of practical data that using a modified form of an algorithm (INVEQ) published in other contexts, sedimentation equilibrium (SE) profiles can be analysed successfully, enabling topics such as oligomer presence or formation to be defined.To achieve this, it is necessary to employ an approach in which the solution density, which in an SE profile is radius-dependent, is taken into consideration. Simulation suggests that any reasonable level of solute concentration can be analysed.

Finding ergonomic solutions--participatory approaches.

Science.gov (United States)

Hignett, Sue; Wilson, John R; Morris, Wendy

2005-05-01

This paper gives an overview of the theory of participatory ergonomics interventions and summary examples from a range of industries, including health care, military, manufacturing, production and processing, services, construction and transport. The definition of participatory approaches includes interventions at macro (organizational, systems) levels as well as micro (individual), where workers are given the opportunity and power to use their knowledge to address ergonomic problems relating to their own working activities. Examples are given where a cost-effective benefit has been measured using musculoskeletal sickness absence and compensation costs. Other examples, using different outcome measures, also showed improvements, for example, an increase in productivity, improved communication between staff and management, reduction in risk factors, the development of new processes and new designs for work environments and activities. Three cases are described from Canada and Japan where the participatory project was led by occupational health teams, suggesting that occupational health practitioners can have an important role to play in participatory ergonomics projects.

dispersion equation parameters of solute transport in agricultural

African Journals Online (AJOL)

Jane

2011-08-31

Aug 31, 2011 ... fields for predicting soil quality property. Key words: ... The classical approach of modeling solute transport in porous media uses the deterministic ... concentration of the solution in the liquid phase, u0 is the mean velocity and ...

Roentgenographic and derivatographic investigation of gallium and indium complexes with azo compounds on the base of pyrogallol

International Nuclear Information System (INIS)

Gambarov, D.G.; Rzaev, R.Z.; Musaev, F.N.; Musaeva, A.N.; Chyragov, F.M.

1985-01-01

Seven complexes of gallium and indium with N-donor ligands obtained on the base of pyrogallol are synthesized. Their chemical composition is established. Nitrogen-containing ligands and their complexes are investigated by the methods of roentgenographic and thermogravimetric analyses. It is shown that gallium and indium complexes are amorphous compounds. An assumption is made on the thermolysis character that complexes have a similar structure: structural complex nucleus constitutes a six-term chelate ring. Para-substitutors in the ligand do not participate in complexing, possibly they participate in H-bonds formation. It is established by spectrophotometric methods that in solutions stoichiometric ratio metal: ligand is the same as in the solid phase

Roentgenographic and derivatographic investigation of gallium and indium complexes with azo compounds on the base of pyrogallol

Energy Technology Data Exchange (ETDEWEB)

Gambarov, D G; Rzaev, R Z; Musaev, F N; Musaeva, A N; Chyragov, F M

1985-01-01

Seven complexes of gallium and indium with N-donor ligands obtained on the base of pyrogallol are synthesized. Their chemical composition is established. Nitrogen-containing ligands and their complexes are investigated by the methods of roentgenographic and thermogravimetric analyses. It is shown that gallium and indium complexes are amorphous compounds. An assumption is made on the thermolysis character that complexes have a similar structure: structural complex nucleus constitutes a six-term chelate ring. Para-substitutors in the ligand do not participate in complexing, possibly they participate in H-bonds formation. It is established by spectrophotometric methods that in solutions stoichiometric ratio metal: ligand is the same as in the solid phase.

Processes leading to yttrium-barium cuprates formation in synthesis using nitrates

International Nuclear Information System (INIS)

Kulakov, A.B.; Tesker, A.M.; Zalishchanskij, M.E.; Tret'yakov, Yu.D.; Gipius, A.A.

1989-01-01

An attempt to determine sequence and conditions for transformations occuring at heating both of mechanical mixture of copper, yttrium and barium nitrates and salt product of sublimated dehydration of quick frozen solution of nitrates in question of correlation which corresponds to YBa 2 Cu 3 O 7-σ final compounds is made. It is shown that unlike individual nitrates their thermolysis in the mixture occurs at lower temperatures with mechanism variation of decomposition separate stages. Specimens of superconducting ceramics with 4.3 g/cm 3 density phase composition and oxygen content which correspond to YBa 2 Cu 3 O 6.85±0.05 formula are obtaied

A comprehensive analytical solution of the nonlinear pendulum

International Nuclear Information System (INIS)

Ochs, Karlheinz

2011-01-01

In this paper, an analytical solution for the differential equation of the simple but nonlinear pendulum is derived. This solution is valid for any time and is not limited to any special initial instance or initial values. Moreover, this solution holds if the pendulum swings over or not. The method of approach is based on Jacobi elliptic functions and starts with the solution of a pendulum that swings over. Due to a meticulous sign correction term, this solution is also valid if the pendulum does not swing over.

Combinatorial solutions to integrable hierarchies

Science.gov (United States)

Kazarian, M. E.; Lando, S. K.

2015-06-01

This paper reviews modern approaches to the construction of formal solutions to integrable hierarchies of mathematical physics whose coefficients are answers to various enumerative problems. The relationship between these approaches and the combinatorics of symmetric groups and their representations is explained. Applications of the results to the construction of efficient computations in problems related to models of quantum field theories are described. Bibliography: 34 titles.

Exact and heuristic solution approaches for the Integrated Job Scheduling and Constrained Network Routing Problem

DEFF Research Database (Denmark)

Gamst, M.

2014-01-01

problem. The methods are computationally evaluated on test instances arising from telecommunications with up to 500 jobs and 500 machines. Results show that solving the integrated job scheduling and constrained network routing problem to optimality is very difficult. The exact solution approach performs......This paper examines the problem of scheduling a number of jobs on a finite set of machines such that the overall profit of executed jobs is maximized. Each job has a certain demand, which must be sent to the executing machine via constrained paths. A job cannot start before all its demands have...... arrived at the machine. Furthermore, two resource demand transmissions cannot use the same edge in the same time period. The problem has application in grid computing, where a number of geographically distributed machines work together for solving large problems. The machines are connected through...

Exact solutions for the (2+1)-dimensional Boiti-Leon-Pempielli system

International Nuclear Information System (INIS)

Hu, Y H; Zheng, C L

2008-01-01

The object reduction approach is applied to the (2+1)-dimensional Boiti-Leon-Pempielli system using a special conditional similarity reduction. Abundant exact solutions of this system, including the hyperboloid function solutions, the trigonometric function solutions and a rational function solution, are obtained

An Algorithm for the Numerical Solution of the Pseudo Compressible Navier-stokes Equations Based on the Experimenting Fields Approach

KAUST Repository

Salama, Amgad; Sun, Shuyu; Amin, Mohamed F. El

2015-01-01

In this work, the experimenting fields approach is applied to the numerical solution of the Navier-Stokes equation for incompressible viscous flow. In this work, the solution is sought for both the pressure and velocity fields in the same time. Apparently, the correct velocity and pressure fields satisfy the governing equations and the boundary conditions. In this technique a set of predefined fields are introduced to the governing equations and the residues are calculated. The flow according to these fields will not satisfy the governing equations and the boundary conditions. However, the residues are used to construct the matrix of coefficients. Although, in this setup it seems trivial constructing the global matrix of coefficients, in other setups it can be quite involved. This technique separates the solver routine from the physics routines and therefore makes easy the coding and debugging procedures. We compare with few examples that demonstrate the capability of this technique.

An Algorithm for the Numerical Solution of the Pseudo Compressible Navier-stokes Equations Based on the Experimenting Fields Approach

KAUST Repository

Salama, Amgad

2015-06-01

In this work, the experimenting fields approach is applied to the numerical solution of the Navier-Stokes equation for incompressible viscous flow. In this work, the solution is sought for both the pressure and velocity fields in the same time. Apparently, the correct velocity and pressure fields satisfy the governing equations and the boundary conditions. In this technique a set of predefined fields are introduced to the governing equations and the residues are calculated. The flow according to these fields will not satisfy the governing equations and the boundary conditions. However, the residues are used to construct the matrix of coefficients. Although, in this setup it seems trivial constructing the global matrix of coefficients, in other setups it can be quite involved. This technique separates the solver routine from the physics routines and therefore makes easy the coding and debugging procedures. We compare with few examples that demonstrate the capability of this technique.

Solution combustion synthesis of strontium aluminate, SrAl2O4, powders: single-fuel versus fuel-mixture approach.

Science.gov (United States)

Ianoş, Robert; Istratie, Roxana; Păcurariu, Cornelia; Lazău, Radu

2016-01-14

The solution combustion synthesis of strontium aluminate, SrAl2O4, via the classic single-fuel approach and the modern fuel-mixture approach was investigated in relation to the synthesis conditions, powder properties and thermodynamic aspects. The single-fuel approach (urea or glycine) did not yield SrAl2O4 directly from the combustion reaction. The absence of SrAl2O4 was explained by the low amount of energy released during the combustion process, in spite of the highly negative values of the standard enthalpy of reaction and standard Gibbs free energy. In the case of single-fuel recipes, the maximum combustion temperatures measured by thermal imaging (482 °C - urea, 941 °C - glycine) were much lower than the calculated adiabatic temperatures (1864 °C - urea, 2147 °C - glycine). The fuel-mixture approach (urea and glycine) clearly represented a better option, since (α,β)-SrAl2O4 resulted directly from the combustion reaction. The maximum combustion temperature measured in the case of a urea and glycine fuel mixture was the highest one (1559 °C), which was relatively close to the calculated adiabatic temperature (1930 °C). The addition of a small amount of flux, such as H3BO3, enabled the formation of pure α-SrAl2O4 directly from the combustion reaction.

Distinct solutions of infinite U Hubbard model through nested Bethe ansatz and Gutzwiller projection operator approach

International Nuclear Information System (INIS)

Mishra, A.K.; Kishore, R.

2009-01-01

The exact nested Bethe ansatz solution for the one dimensional (1-D) U infinity Hubbard model show that the state vectors are a product of spin-less fermion and spin wavefunctions, or an appropriate superposition of such factorized wavefunctions. The spin-less fermion component of the wavefunctions ensures no double occupancy at any site. It had been demonstrated that the nested Bethe ansatz wavefunctions in the U infinity limit obey orthofermi statistics. Gutzwiller projection operator formalism is the another well known technique employed to handle U infinity Hubbard model. In general, this approach does not lead to spin-less fermion wavefunctions. Therefore, the nested Bethe ansatz and Gutzwiller projection operator approach give rise to different kinds of the wavefunctions for the U infinity limit of 1-D Hubbard Hamiltonian. To compare the consequences of this dissimilarity in the wavefunctions, we have obtained the ground state energy of a finite system consisting of three particles on a four site closed chain. It is shown that in the nested Bethe ansatz implemented through orthofermion algebra, all the permissible 2 3 spin configurations are degenerate in the ground state. This eight fold degeneracy of the ground state is absent in the Gutzwiller projection operator approach. This finding becomes relevant in the context of known exact U infinity results, which require that all the energy levels are 2 N -fold degenerate for an N particle system.

Scaling solutions for dilaton quantum gravity

Energy Technology Data Exchange (ETDEWEB)

Henz, T.; Pawlowski, J.M., E-mail: j.pawlowski@thphys.uni-heidelberg.de; Wetterich, C.

2017-06-10

Scaling solutions for the effective action in dilaton quantum gravity are investigated within the functional renormalization group approach. We find numerical solutions that connect ultraviolet and infrared fixed points as the ratio between scalar field and renormalization scale k is varied. In the Einstein frame the quantum effective action corresponding to the scaling solutions becomes independent of k. The field equations derived from this effective action can be used directly for cosmology. Scale symmetry is spontaneously broken by a non-vanishing cosmological value of the scalar field. For the cosmology corresponding to our scaling solutions, inflation arises naturally. The effective cosmological constant becomes dynamical and vanishes asymptotically as time goes to infinity.

A simple method of genomic DNA extraction suitable for analysis of bulk fungal strains.

Science.gov (United States)

Zhang, Y J; Zhang, S; Liu, X Z; Wen, H A; Wang, M

2010-07-01

A simple and rapid method (designated thermolysis) for extracting genomic DNA from bulk fungal strains was described. In the thermolysis method, a few mycelia or yeast cells were first rinsed with pure water to remove potential PCR inhibitors and then incubated in a lysis buffer at 85 degrees C to break down cell walls and membranes. This method was used to extract genomic DNA from large numbers of fungal strains (more than 92 species, 35 genera of three phyla) isolated from different sections of natural Ophiocordyceps sinensis specimens. Regions of interest from high as well as single-copy number genes were successfully amplified from the extracted DNA samples. The DNA samples obtained by this method can be stored at -20 degrees C for over 1 year. The method was effective, easy and fast and allowed batch DNA extraction from multiple fungal isolates. Use of the thermolysis method will allow researchers to obtain DNA from fungi quickly for use in molecular assays. This method requires only minute quantities of starting material and is suitable for diverse fungal species.

High-accuracy alignment based on atmospherical dispersion - technological approaches and solutions for the dual-wavelength transmitter

International Nuclear Information System (INIS)

Burkhard, Boeckem

1999-01-01

In the course of the progressive developments of sophisticated geodetic systems utilizing electromagnetic waves in the visible or near IR-range a more detailed knowledge of the propagation medium and coevally solutions of atmospherically induced limitations will become important. An alignment system based on atmospherical dispersion, called a dispersometer, is a metrological solution to the atmospherically induced limitations, in optical alignment and direction observations of high accuracy. In the dispersometer we are using the dual-wavelength method for dispersive air to obtain refraction compensated angle measurements, the detrimental impact of atmospheric turbulence notwithstanding. The principle of the dual-wavelength method utilizes atmospherical dispersion, i.e. the wavelength dependence of the refractive index. The difference angle between two light beams of different wavelengths, which is called the dispersion angle Δβ, is to first approximation proportional to the refraction angle: β IR ν(β blue - β IR ) = ν Δβ, this equation implies that the dispersion angle has to be measured at least 42 times more accurate than the desired accuracy of the refraction angle for the wavelengths used in the present dispersometer. This required accuracy constitutes one major difficulty for the instrumental performance in applying the dispersion effect. However, the dual-wavelength method can only be successfully used in an optimized transmitter-receiver combination. Beyond the above mentioned resolution requirement for the detector, major difficulties in instrumental realization arise in the availability of a suitable dual-wavelength laser light source, laser light modulation with a very high extinction ratio and coaxial emittance of mono-mode radiation at both wavelengths. Therefore, this paper focuses on the solutions of the dual-wavelength transmitter introducing a new hardware approach and a complete re-design of the in [1] proposed conception of the dual

Determination of acid ionization constants for weak acids by osmometry and the instrumental analysis self-evaluation feedback approach to student preparation of solutions

Science.gov (United States)

Kakolesha, Nyanguila

One focus of this work was to develop of an alternative method to conductivity for determining the acid ionization constants. Computer-controlled osmometry is one of the emerging analytical tools in industrial research and clinical laboratories. It is slowly finding its way into chemistry laboratories. The instrument's microprocessor control ensures shortened data collection time, repeatability, accuracy, and automatic calibration. The equilibrium constants of acetic acid, chloroacetic acid, bromoacetic acid, cyanoacetic acid, and iodoacetic acid have been measured using osmometry and their values compared with the existing literature values obtained, usually, from conductometric measurements. Ionization constant determined by osmometry for the moderately strong weak acids were in reasonably good agreement with literature values. The results showed that two factors, the ionic strength and the osmotic coefficient, exert opposite effects in solutions of such weak acids. Another focus of the work was analytical chemistry students solution preparation skills. The prevailing teacher-structured experiments leave little room for students' ingenuity in quantitative volumetric analysis. The purpose of this part of the study was to improve students' skills in making solutions using instrument feedback in a constructivist-learning model. After making some solutions by weighing and dissolving solutes or by serial dilution, students used the spectrophotometer and the osmometer to compare their solutions with standard solutions. Students perceived the instrument feedback as a nonthreatening approach to monitoring the development of their skill levels and liked to clarify their understanding through interacting with an instructor-observer. An assessment of the instrument feedback and the constructivist model indicated that students would assume responsibility for their own learning if given the opportunity. This study involved 167 students enrolled in Quantitative Chemical

Solution Prototype

DEFF Research Database (Denmark)

Efeoglu, Arkin; Møller, Charles; Serie, Michel

2013-01-01

This paper outlines an artifact building and evaluation proposal. Design Science Research (DSR) studies usually consider encapsulated artifact that have relationships with other artifacts. The solution prototype as a composed artifact demands for a more comprehensive consideration in its systematic...... environment. The solution prototype that is composed from blending product and service prototype has particular impacts on the dualism of DSR’s “Build” and “Evaluate”. Since the mix between product and service prototyping can be varied, there is a demand for a more agile and iterative framework. Van de Ven......’s research framework seems to fit this purpose. Van de Ven allows for an iterative research approach to problem solving with flexible starting point. The research activity is the result between the iteration of two dimensions. This framework focuses on the natural evaluation, particularly on ex...

Development of solute transport models in YMPYRÄ framework to simulate solute migration in military shooting and training areas

Science.gov (United States)

Warsta, L.; Karvonen, T.

2017-12-01

There are currently 25 shooting and training areas in Finland managed by The Finnish Defence Forces (FDF), where military activities can cause contamination of open waters and groundwater reservoirs. In the YMPYRÄ project, a computer software framework is being developed that combines existing open environmental data and proprietary information collected by FDF with computational models to investigate current and prevent future environmental problems. A data centric philosophy is followed in the development of the system, i.e. the models are updated and extended to handle available data from different areas. The results generated by the models are summarized as easily understandable flow and risk maps that can be opened in GIS programs and used in environmental assessments by experts. Substances investigated with the system include explosives and metals such as lead, and both surface and groundwater dominated areas can be simulated. The YMPYRÄ framework is composed of a three dimensional soil and groundwater flow model, several solute transport models and an uncertainty assessment system. Solute transport models in the framework include particle based, stream tube and finite volume based approaches. The models can be used to simulate solute dissolution from source area, transport in the unsaturated layers to groundwater and finally migration in groundwater to water extraction wells and springs. The models can be used to simulate advection, dispersion, equilibrium adsorption on soil particles, solubility and dissolution from solute phase and dendritic solute decay chains. Correct numerical solutions were confirmed by comparing results to analytical 1D and 2D solutions and by comparing the numerical solutions to each other. The particle based and stream tube type solute transport models were useful as they could complement the traditional finite volume based approach which in certain circumstances produced numerical dispersion due to piecewise solution of the

Solute-solute interactions in intermetallic compounds

Energy Technology Data Exchange (ETDEWEB)

Banerjee, Debashis; Murray, Ryan; Collins, Gary S., E-mail: collins@wsu.edu [Washington State University, Department of Physics and Astronomy (United States); Zacate, Matthew O. [Northern Kentucky University, Department of Physics and Geology (United States)

2017-11-15

Experiments were carried out on highly ordered GdAl{sub 2} samples containing extremely dilute mole fractions of{sup 111}In/Cd probe-atom solutes (about 10{sup −11}), intrinsic antisite atoms Al{sub Gd} having mole fractions of order 0-10{sup −2}, and doped with Ag solutes at mole fractions of order 10{sup −2}. Three types of defect interactions were investigated. (1) Quadrupole interactions caused by Ag-solute atoms neighboring{sup 111}In/Cd solute probe atoms were detected using the method of perturbed angular correlation of gamma rays (PAC). Three complexes of pairs of In-probes and Ag-solutes occupying neighboring positions on Gd- and Al-sublattices were identified by comparing site fractions in Gd-poor and Gd-rich GdAl{sub 2}(Ag) samples and from the symmetry of the quadrupole interactions. Interaction enthalpies between solute-atom pairs were determined from temperature dependences of observed site fractions. Repulsive interactions were observed for close-neighbor complexes In{sub Gd}+Ag{sub Gd} and In{sub Gd}+Ag{sub Al} pairs, whereas a slightly attractive interaction was observed for In{sub Al}+Ag{sub Al}. Interaction enthalpies were all small, in the range ±0.15 eV. (2) Quadrupole interactions caused by intrinsic antisite atoms Al{sub Gd} neighboring In{sub Gd} probes were also detected and site fractions measured as a function of temperature, as in previous work on samples not doped with Ag-solutes [Temperature- and composition-driven changes in site occupation of solutes in Gd{sub 1+3x}Al{sub 2−3x}, Zacate and Collins (Phys. Rev. B69, 174202 (1))]. However, the effective binding enthalpy between In{sub Gd} probe and Al{sub Gd} antisite was found to change sign from -0.12 eV (attractive interaction) in undoped samples to + 0.24 eV (repulsive) in Ag-doped samples. This may be attributed to an attractive interaction between Al{sub Gd} antisite atoms and Ag-dopants that competes with the attractive interaction between In{sub Gd} and Al{sub Gd

Developing e-learning solutions in the automotive industry

Directory of Open Access Journals (Sweden)

Razvan Virgil Bogdan

2016-07-01

Full Text Available In the rapid developing market of automotive industry, cutting-edge technologies are being introduced. One such example is the AUTOSAR standard. Companies are investing a large amount of finances for the training of their employees into the intricacies of such technologies. In order to face such an increase of the training costs, automotive corporation have started lately switching their approach to e-Learning systems. This paper presents an e-Learning approach developed in the automotive industry in order to address the demands of teaching AUTOSAR standard. The developed e-Learning project is called Academy. In order to develop the e-Learning solution we focused on the Software Development part of automotive industry. Therefore we had to gather the ideas from different trainers, come with a common approach and use specific techniques so that the trainee should get a real feeling of the material. It is presented the design, implementation and evaluation of this e-Learning solution, but more than that faced issues and learned lessons. Developing this solution has offered different insights into how to approach such a task which are useful for the further expansion of the project, but also for future researchers who might encounter such a challenge of developing e-Learning solutions for the automotive industry. These are all grouped in a set of guidelines related to following a model of implementation, getting track of participants, user interaction with the AUTOSAR standard, test and production development and so on.

Monitoring Approach to Evaluate the Performances of a New Deposition Nozzle Solution for DED Systems

Directory of Open Access Journals (Sweden)

Federico Mazzucato

2017-05-01

Full Text Available Abstract: In order to improve the process efficiency of a direct energy deposition (DED system, closed loop control systems can be considered for monitoring the deposition and melting processes and adjusting the process parameters in real-time. In this paper, the monitoring of a new deposition nozzle solution for DED systems is approached through a simulation-experimental comparison. The shape of the powder flow at the exit of the nozzle outlet and the spread of the powder particles on the deposition plane are analyzed through 2D images of the powder flow obtained by monitoring the powder depositions with a high-speed camera. These experimental results are then compared with data obtained through a Computational Fluid Dynamics model. Preliminary tests are carried out by varying powder, carrier, and shielding mass flow, demonstrating that the last parameter has a significant influence on the powder distribution and powder flow geometry.

Automated structure solution, density modification and model building.

Science.gov (United States)

Terwilliger, Thomas C

2002-11-01

The approaches that form the basis of automated structure solution in SOLVE and RESOLVE are described. The use of a scoring scheme to convert decision making in macromolecular structure solution to an optimization problem has proven very useful and in many cases a single clear heavy-atom solution can be obtained and used for phasing. Statistical density modification is well suited to an automated approach to structure solution because the method is relatively insensitive to choices of numbers of cycles and solvent content. The detection of non-crystallographic symmetry (NCS) in heavy-atom sites and checking of potential NCS operations against the electron-density map has proven to be a reliable method for identification of NCS in most cases. Automated model building beginning with an FFT-based search for helices and sheets has been successful in automated model building for maps with resolutions as low as 3 A. The entire process can be carried out in a fully automatic fashion in many cases.

Classification of exact solutions to the generalized Kadomtsev-Petviashvili equation

International Nuclear Information System (INIS)

Pandir, Yusuf; Gurefe, Yusuf; Misirli, Emine

2013-01-01

In this paper, we study the Kadomtsev-Petviashvili equation with generalized evolution and derive some new results using the approach called the trial equation method. The obtained results can be expressed by the soliton solutions, rational function solutions, elliptic function solutions and Jacobi elliptic function solutions. In the discussion, we give a new version of the trial equation method for nonlinear differential equations.

Review of Modelling Approaches for Developing Virtual Natural Lighting Solutions

NARCIS (Netherlands)

Mangkuto, R.A.; Ochoa Morales, C.E.; Aries, M.B.C.; Loenen, van E.J.; Hensen, J.L.M.

2011-01-01

Several studies have shown that natural light is preferred over electrical lighting in built environments. It has positive effects on user satisfaction, health, and energy saving. However, natural light is limited by time and space. A possible solution is to apply the new concept of virtual natural

Application of solution-mineral equilibrium chemistry to solution mining of uranium ores

International Nuclear Information System (INIS)

Riese, A.C.; Propp, C.J.

1980-01-01

Modern methods of uranium solution mining are typically accompanied by gains and losses of mass through reagent consumption by rock-forming minerals, with subsequent formation of clay minerals, gypsum, carbonates, and iron oxyhydroxides. A systematic approach to alleviate such problems involves the application of leach solutions that are in equilibrium with the host-rock minerals but in disequilibrium with the ore-forming minerals. This partial equilibrium can be approximated by solution-composition adjustments within the systems K 2 O-Al 2 O 3 SiO 2 -H 2 O and Na 2 O 3 -Al 2 O 3 SiO 2 -H 2 O. Uranium ore containing 0.15 percent U 3 O 8 from the Gulf Mineral Resources Corporation's Mariano Lake mine, the Smith Lake district of the Grants mineral belt, was collected for investigation. Presented are a theoretical evaluation of leachate data and an experimental treatment of the ore, which contained mainly K-feldspar, plagioclase feldspar, and quartz (with lesser amounts of micas, clay minerals, and organic carbonaceous material). Small-scale (less than or equal to 1 kg) column-leaching experiments were conducted to model the results of conventional leaching operations and to provide leachate solutions that could be compared with solutions calculated to be in equilibrium with the matrix minerals. Leach solutions employed include: 1) sulfuric acid, 2) sodium bicarbonate, and 3) sulfuric acid with 1.0 molal potassium chloride. The uranium concentrations in the sodium-bicarbonate leach solution and the acid-leach solution were about a gram per liter at the termination of the tests. However, the permeability of the ore in the acid leach was greatly reduced, owing to the formation of clay minerals. Uranium solubility in the leach column stabilized with the potassium-chloride solution was calculated from leachate compositions to be limited by the solubility of carnotite

Bridging Flows: Microfluidic End‐User Solutions

DEFF Research Database (Denmark)

Sabourin, David

Microfluidic applications hold promise for many different end‐users both within and outside, and across many different research communities. Despite the benefits of microfluidic approaches, adoption and implementation thereof is often hindered by practical issues. Microfluidic components which......‐integrated interconnection and miniaturized peristaltic pump solutions were then combined into modular microfluidic systems. One system provides high interconnection numbers/density and allows many possible configurations. Additionally, and apart from many other accounts of modular microfluidic solutions, methods...... for control and actuation of microfluidic networks built from the modular components is described. Prototypes of the microfluidic system have begun to be distributed to external collaborators and researcher parties. These end‐users will assist in the validation of the approach and ultimately fulfil the key...

New exact solutions of the generalized Zakharov–Kuznetsov ...

Indian Academy of Sciences (India)

In this paper, new exact solutions, including soliton, rational and elliptic integral function solutions, for the generalized Zakharov–Kuznetsov modified equal-width equation are obtained using a new approach called the extended trial equation method. In this discussion, a new version of the trial equation method for the ...

New approach to crystal nucleation from solution on active centers

Czech Academy of Sciences Publication Activity Database

Kožíšek, Zdeněk; Demo, Pavel; Sveshnikov, Alexey

2013-01-01

Roč. 5, č. 6 (2013), s. 548-552 ISSN 2164-6627 R&D Projects: GA ČR GAP108/12/0891 Institutional support: RVO:68378271 Keywords : phase transition * nucleation * solution Subject RIV: BM - Solid Matter Physics ; Magnetism http://www.aspbs.com/asem.html#v5n6

The fractional coupled KdV equations: Exact solutions and white noise functional approach

International Nuclear Information System (INIS)

Ghany, Hossam A.; El Bab, A. S. Okb; Zabel, A. M.; Hyder, Abd-Allah

2013-01-01

Variable coefficients and Wick-type stochastic fractional coupled KdV equations are investigated. By using the modified fractional sub-equation method, Hermite transform, and white noise theory the exact travelling wave solutions and white noise functional solutions are obtained, including the generalized exponential, hyperbolic, and trigonometric types. (general)

Solutions in radiology services management: a literature review.

Science.gov (United States)

Pereira, Aline Garcia; Vergara, Lizandra Garcia Lupi; Merino, Eugenio Andrés Díaz; Wagner, Adriano

2015-01-01

The present study was aimed at reviewing the literature to identify solutions for problems observed in radiology services. Basic, qualitative, exploratory literature review at Scopus and SciELO databases, utilizing the Mendeley and Illustrator CC Adobe softwares. In the databases, 565 papers - 120 out of them, pdf free - were identified. Problems observed in the radiology sector are related to procedures scheduling, humanization, lack of training, poor knowledge and use of management techniques, and interaction with users. The design management provides the services with interesting solutions such as Benchmarking, CRM, Lean Approach, ServiceBlueprinting, continued education, among others. Literature review is an important tool to identify problems and respective solutions. However, considering the small number of studies approaching management of radiology services, this is a great field of research for the development of deeper studies.

The Fermi-Pasta-Ulam Model Periodic Solutions

CERN Document Server

Arioli, G; Terracini, S

2003-01-01

We introduce two novel methods for studying periodic solutions of the FPU beta-model, both numerically and rigorously. One is a variational approach, based on the dual formulation of the problem, and the other involves computer-assisted proofs. These methods are used e.g. to construct a new type of solutions, whose energy is spread among several modes, associated with closely spaced resonances.

Rogue waves and rational solutions of a (3+1)-dimensional nonlinear evolution equation

International Nuclear Information System (INIS)

Zhaqilao,

2013-01-01

A simple symbolic computation approach for finding the rogue waves and rational solutions to the nonlinear evolution equation is proposed. It turns out that many rational solutions with real and complex forms of a (3+1)-dimensional nonlinear evolution equation are obtained. Some features of rogue waves and rational solutions are graphically discussed. -- Highlights: •A simple symbolic computation approach for finding the rational solutions to the NEE is proposed. •Some rogue waves and rational solutions with real and complex forms of a (3+1)-D NEE are obtained. •Some features of rogue waves are graphically discussed

Rogue waves and rational solutions of a (3+1)-dimensional nonlinear evolution equation

Energy Technology Data Exchange (ETDEWEB)

Zhaqilao,, E-mail: zhaqilao@imnu.edu.cn

2013-12-06

A simple symbolic computation approach for finding the rogue waves and rational solutions to the nonlinear evolution equation is proposed. It turns out that many rational solutions with real and complex forms of a (3+1)-dimensional nonlinear evolution equation are obtained. Some features of rogue waves and rational solutions are graphically discussed. -- Highlights: •A simple symbolic computation approach for finding the rational solutions to the NEE is proposed. •Some rogue waves and rational solutions with real and complex forms of a (3+1)-D NEE are obtained. •Some features of rogue waves are graphically discussed.

Equilibrium and nonequilibrium solvation and solute electronic structure

International Nuclear Information System (INIS)

Kim, H.J.; Hynes, J.T.

1990-01-01

When a molecular solute is immersed in a polar and polarizable solvent, the electronic wave function of the solute system is altered compared to its vacuum value; the solute electronic structure is thus solvent-dependent. Further, the wave function will be altered depending upon whether the polarization of the solvent is or is not in equilibrium with the solute charge distribution. More precisely, while the solvent electronic polarization should be in equilibrium with the solute electronic wave function, the much more sluggish solvent orientational polarization need not be. We call this last situation non-equilibrium solvation. We outline a nonlinear Schroedinger equation approach to these issues

Negative Saturation Approach for Non-Isothermal Compositional Two-Phase Flow Simulations

NARCIS (Netherlands)

Salimi, H.; Wolf, K.H.; Bruining, J.

2011-01-01

This article deals with developing a solution approach, called the non-isothermal negative saturation (NegSat) solution approach. The NegSat solution approach solves efficiently any non-isothermal compositional flow problem that involves phase disappearance, phase appearance, and phase transition.

Cepstrum analysis and applications to computational fluid dynamic solutions

Science.gov (United States)

Meadows, Kristine R.

1990-04-01

A novel approach to the problem of spurious reflections introduced by artificial boundary conditions in computational fluid dynamic (CFD) solutions is proposed. Instead of attempting to derive non-reflecting boundary conditions, the approach is to accept the fact that spurious reflections occur, but to remove these reflections with cepstrum analysis, a signal processing technique which has been successfully used to remove echoes from experimental data. First, the theory of the cepstrum method is presented. This includes presentation of two types of cepstra: The Power Cepstrum and the Complex Cepstrum. The definitions of the cepstrum methods are applied theoretically and numerically to the analytical solution of sinusoidal plane wave propagation in a duct. One-D and 3-D time dependent solutions to the Euler equations are computed, and hard-wall conditions are prescribed at the numerical boundaries. The cepstrum method is applied, and the reflections from the boundaries are removed from the solutions. One-D and 3-D solutions are computed with so called nonreflecting boundary conditions, and these solutions are compared to those obtained by prescribing hard wall conditions and processing with the cepstrum.

On Direct Transformation Approach to Asymptotical Analytical Solutions of Perturbed Partial Differential Equation

International Nuclear Information System (INIS)

Liu Hongzhun; Pan Zuliang; Li Peng

2006-01-01

In this article, we will derive an equality, where the Taylor series expansion around ε = 0 for any asymptotical analytical solution of the perturbed partial differential equation (PDE) with perturbing parameter ε must be admitted. By making use of the equality, we may obtain a transformation, which directly map the analytical solutions of a given unperturbed PDE to the asymptotical analytical solutions of the corresponding perturbed one. The notion of Lie-Baecklund symmetries is introduced in order to obtain more transformations. Hence, we can directly create more transformations in virtue of known Lie-Baecklund symmetries and recursion operators of corresponding unperturbed equation. The perturbed Burgers equation and the perturbed Korteweg-de Vries (KdV) equation are used as examples.

Intuitive Understanding of Solutions of Partially Differential Equations

Science.gov (United States)

Kobayashi, Y.

2008-01-01

This article uses diagrams that help the observer see how solutions of the wave equation and heat conduction equation are obtained. The analytical approach cannot necessarily show the mechanisms of the key to the solution without transforming the differential equation into a more convenient form by separation of variables. The visual clues based…

Implementing SaaS Solution for CRM

OpenAIRE

Adriana LIMBÄ‚ÅžAN; Lucia RUSU

2011-01-01

Greatest innovations in virtualization and distributed computing have accelerated interest in cloud computing (IaaS, PaaS, SaaS, aso). This paper presents the SaaS prototype for Customer Relationship Management of a real estate company. Starting from several approaches of e-marketing and SaaS features and architectures, we adopted a model for a CRM solution using SaaS Level 2 architecture and distributed database. Based on the system objective, functionality, we developed a modular solution f...

Parallelised Krylov subspace method for reactor kinetics by IQS approach

International Nuclear Information System (INIS)

Gupta, Anurag; Modak, R.S.; Gupta, H.P.; Kumar, Vinod; Bhatt, K.

2005-01-01

Nuclear reactor kinetics involves numerical solution of space-time-dependent multi-group neutron diffusion equation. Two distinct approaches exist for this purpose: the direct (implicit time differencing) approach and the improved quasi-static (IQS) approach. Both the approaches need solution of static space-energy-dependent diffusion equations at successive time-steps; the step being relatively smaller for the direct approach. These solutions are usually obtained by Gauss-Seidel type iterative methods. For a faster solution, the Krylov sub-space methods have been tried and also parallelised by many investigators. However, these studies seem to have been done only for the direct approach. In the present paper, parallelised Krylov methods are applied to the IQS approach in addition to the direct approach. It is shown that the speed-up obtained for IQS is higher than that for the direct approach. The reasons for this are also discussed. Thus, the use of IQS approach along with parallelised Krylov solvers seems to be a promising scheme

Exact solutions, numerical relativity and gravitational radiation

International Nuclear Information System (INIS)

Winicour, J.

1986-01-01

In recent years, there has emerged a new use for exact solutions to Einstein's equation as checks on the accuracy of numerical relativity codes. Much has already been written about codes based upon the space-like Cauchy problem. In the case of two Killing vectors, a numerical characteristic initial value formulation based upon two intersecting families of null hypersurfaces has successfully evolved the Schwarzschild and the colliding plane wave vacuum solutions. Here the author discusses, in the context of exact solutions, numerical studies of gravitational radiation based upon the null cone initial value problem. Every stage of progress in the null cone approach has been associated with exact solutions in some sense. He begins by briefly recapping this history. Then he presents two new examples illustrating how exact solutions can be useful

Numerical solution of the radionuclide transport equation

International Nuclear Information System (INIS)

Hadermann, J.; Roesel, F.

1983-11-01

A numerical solution of the one-dimensional geospheric radionuclide chain transport equation based on the pseudospectral method is developed. The advantages of this approach are flexibility in incorporating space and time dependent migration parameters, arbitrary boundary conditions and solute rock interactions as well as efficiency and reliability. As an application the authors investigate the impact of non-linear sorption isotherms on migration in crystalline rock. It is shown that non-linear sorption, in the present case a Freundlich isotherm, may reduce concentration at the geosphere outlet by orders of magnitude provided the migration time is comparable or larger than the half-life of the nuclide in question. The importance of fixing dispersivity within the continuum approach is stressed. (Auth.)

Lump solutions to the Kadomtsev–Petviashvili equation

Energy Technology Data Exchange (ETDEWEB)

Ma, Wen-Xiu, E-mail: mawx@cas.usf.edu

2015-09-25

Through symbolic computation with Maple, a class of lump solutions, rationally localized in all directions in the space, to the (2 + 1)-dimensional Kadomtsev–Petviashvili (KP) equation is presented, making use of its Hirota bilinear form. The resulting lump solutions contain six free parameters, two of which are due to the translation invariance of the KP equation and the other four of which satisfy a non-zero determinant condition guaranteeing analyticity and rational localization of the solutions. Three contour plots with different determinant values are sequentially made to show that the corresponding lump solution tends to zero when the determinant approaches zero. Two particular lump solutions with specific values of the involved parameters are plotted, as illustrative examples. - Highlights: • Positive quadratic function solutions. • Solitons rationally-localized in all directions in the space. • Solving systems of nonlinear algebraic equations by symbolic computation with Maple.

Benchmarking whole-building energy performance with multi-criteria technique for order preference by similarity to ideal solution using a selective objective-weighting approach

International Nuclear Information System (INIS)

Wang, Endong

2015-01-01

Highlights: • A TOPSIS based multi-criteria whole-building energy benchmarking is developed. • A selective objective-weighting procedure is used for a cost-accuracy tradeoff. • Results from a real case validated the benefits of the presented approach. - Abstract: This paper develops a robust multi-criteria Technique for Order Preference by Similarity to Ideal Solution (TOPSIS) based building energy efficiency benchmarking approach. The approach is explicitly selective to address multicollinearity trap due to the subjectivity in selecting energy variables by considering cost-accuracy trade-off. It objectively weights the relative importance of individual pertinent efficiency measuring criteria using either multiple linear regression or principal component analysis contingent on meta data quality. Through this approach, building energy performance is comprehensively evaluated and optimized. Simultaneously, the significant challenges associated with conventional single-criterion benchmarking models can be avoided. Together with a clustering algorithm on a three-year panel dataset, the benchmarking case of 324 single-family dwellings demonstrated an improved robustness of the presented multi-criteria benchmarking approach over the conventional single-criterion ones

Improved Pedagogy for Linear Differential Equations by Reconsidering How We Measure the Size of Solutions

Science.gov (United States)

Tisdell, Christopher C.

2017-01-01

For over 50 years, the learning of teaching of "a priori" bounds on solutions to linear differential equations has involved a Euclidean approach to measuring the size of a solution. While the Euclidean approach to "a priori" bounds on solutions is somewhat manageable in the learning and teaching of the proofs involving…

A Posteriori Approach for Community Detection

Institute of Scientific and Technical Information of China (English)

Chuan Shi; Zhen-Yu Yan; Xin Pan; Ya-Nan Cai; Bin Wu

2011-01-01

Conventional community detection approaches in complex network are based on the optimization of a priori decision,i.e.,a single quality function designed beforehand.This paper proposes a posteriori decision approach for community detection.The approach includes two phases:in the search phase,a special multi-objective evolutionary algorithm is designed to search for a set of tradeoff partitions that reveal the community structure at different scales in one run; in the decision phase,three model selection criteria and the Possibility Matrix method are proposed to aid decision makers to select the preferable solutions through differentiating the set of optimal solutions according to their qualities.The experiments in five synthetic and real social networks illustrate that,in one run,our method is able to obtain many candidate solutions,which effectively avoids the resolution limit existing in priori decision approaches.In addition,our method can discover more authentic and comprehensive community structures than those priori decision approaches.

A Regionalization Approach to select the final watershed parameter set among the Pareto solutions

Science.gov (United States)

Park, G. H.; Micheletty, P. D.; Carney, S.; Quebbeman, J.; Day, G. N.

2017-12-01

The calibration of hydrological models often results in model parameters that are inconsistent with those from neighboring basins. Considering that physical similarity exists within neighboring basins some of the physically related parameters should be consistent among them. Traditional manual calibration techniques require an iterative process to make the parameters consistent, which takes additional effort in model calibration. We developed a multi-objective optimization procedure to calibrate the National Weather Service (NWS) Research Distributed Hydrological Model (RDHM), using the Nondominant Sorting Genetic Algorithm (NSGA-II) with expert knowledge of the model parameter interrelationships one objective function. The multi-objective algorithm enables us to obtain diverse parameter sets that are equally acceptable with respect to the objective functions and to choose one from the pool of the parameter sets during a subsequent regionalization step. Although all Pareto solutions are non-inferior, we exclude some of the parameter sets that show extremely values for any of the objective functions to expedite the selection process. We use an apriori model parameter set derived from the physical properties of the watershed (Koren et al., 2000) to assess the similarity for a given parameter across basins. Each parameter is assigned a weight based on its assumed similarity, such that parameters that are similar across basins are given higher weights. The parameter weights are useful to compute a closeness measure between Pareto sets of nearby basins. The regionalization approach chooses the Pareto parameter sets that minimize the closeness measure of the basin being regionalized. The presentation will describe the results of applying the regionalization approach to a set of pilot basins in the Upper Colorado basin as part of a NASA-funded project.

Spurious Solutions Of Nonlinear Differential Equations

Science.gov (United States)

Yee, H. C.; Sweby, P. K.; Griffiths, D. F.

1992-01-01

Report utilizes nonlinear-dynamics approach to investigate possible sources of errors and slow convergence and non-convergence of steady-state numerical solutions when using time-dependent approach for problems containing nonlinear source terms. Emphasizes implications for development of algorithms in CFD and computational sciences in general. Main fundamental conclusion of study is that qualitative features of nonlinear differential equations cannot be adequately represented by finite-difference method and vice versa.

Combining metadynamics simulation and experiments to characterize dendrimers in solution

NARCIS (Netherlands)

Pavan, G.M.; Barducci, A.; Albertazzi, L.; Parrinello, M.

2013-01-01

We report a combined theoretical-experimental approach to characterize dendrimers and Polyethylene Glycol (PEG)-dendrimer hybrids in solution. Well-tempered metadynamics simulation allows for an exhaustive sampling of the conformational fluctuations in solution. In contrast to classical molecular

Mean-field learning for satisfactory solutions

KAUST Repository

Tembine, Hamidou

2013-12-01

One of the fundamental challenges in distributed interactive systems is to design efficient, accurate, and fair solutions. In such systems, a satisfactory solution is an innovative approach that aims to provide all players with a satisfactory payoff anytime and anywhere. In this paper we study fully distributed learning schemes for satisfactory solutions in games with continuous action space. Considering games where the payoff function depends only on own-action and an aggregate term, we show that the complexity of learning systems can be significantly reduced, leading to the so-called mean-field learning. We provide sufficient conditions for convergence to a satisfactory solution and we give explicit convergence time bounds. Then, several acceleration techniques are used in order to improve the convergence rate. We illustrate numerically the proposed mean-field learning schemes for quality-of-service management in communication networks. © 2013 IEEE.

Solid solution hardening in face centered binary alloys: Gliding statistics of a dislocation in random solid solution by atomistic simulation

International Nuclear Information System (INIS)

Patinet, S.

2009-12-01

The glide of edge and screw dislocation in solid solution is modeled through atomistic simulations in two model alloys of Ni(Al) and Al(Mg) described within the embedded atom method. Our approach is based on the study of the elementary interaction between dislocations and solutes to derive solid solution hardening of face centered cubic binary alloys. We identify the physical origins of the intensity and range of the interaction between a dislocation and a solute atom. The thermally activated crossing of a solute atom by a dislocation is studied at the atomistic scale. We show that hardening of edge and screw segments are similar. We develop a line tension model that reproduces quantitatively the atomistic calculations of the flow stress. We identify the universality class to which the dislocation depinning transition in solid solution belongs. (author)

Retention of silica nanoparticles on calcium carbonate sands immersed in electrolyte solutions

KAUST Repository

Li, Yan Vivian; Cathles, Lawrence M.

2014-01-01

solution. AFM measurements on calcite immersed in NaCl solutions show the initial repulsion of a silica colloidal probe as the surface is approached is reduced as the solution ionic strength increases, and that at high ionic strengths it disappears entirely

McVittie solution in f(T) gravity

Energy Technology Data Exchange (ETDEWEB)

Bejarano, Cecilia; Jose Guzman, Maria [Instituto de Astronomia y Fisica del Espacio (IAFE, CONICET-UBA), Buenos Aires (Argentina); Ferraro, Rafael [Instituto de Astronomia y Fisica del Espacio (IAFE, CONICET-UBA), Buenos Aires (Argentina); Universidad de Buenos Aires, Departamento de Fisica, Facultad de Ciencias Exactas y Naturales, Buenos Aires (Argentina)

2017-12-15

We show that McVittie geometry, which describes a black hole embedded in a FLRW universe, not only solves the Einstein equations but also remains as a non-deformable solution of f(T) gravity. This search for GR solutions that survive in f(T) gravity is facilitated by a null tetrad approach. We also show that flat FLRW geometry is a consistent solution of f(T) dynamical equations not only for T = -6H{sup 2} but also for T = 0, which could be a manifestation of the additional degrees of freedom involved in f(T) theories. (orig.)

McVittie solution in f(T) gravity

International Nuclear Information System (INIS)

Bejarano, Cecilia; Jose Guzman, Maria; Ferraro, Rafael

2017-01-01

We show that McVittie geometry, which describes a black hole embedded in a FLRW universe, not only solves the Einstein equations but also remains as a non-deformable solution of f(T) gravity. This search for GR solutions that survive in f(T) gravity is facilitated by a null tetrad approach. We also show that flat FLRW geometry is a consistent solution of f(T) dynamical equations not only for T = -6H 2 but also for T = 0, which could be a manifestation of the additional degrees of freedom involved in f(T) theories. (orig.)

Finite Time Merton Strategy under Drawdown Constraint: A Viscosity Solution Approach

International Nuclear Information System (INIS)

Elie, R.

2008-01-01

We consider the optimal consumption-investment problem under the drawdown constraint, i.e. the wealth process never falls below a fixed fraction of its running maximum. We assume that the risky asset is driven by the constant coefficients Black and Scholes model and we consider a general class of utility functions. On an infinite time horizon, Elie and Touzi (Preprint, [2006]) provided the value function as well as the optimal consumption and investment strategy in explicit form. In a more realistic setting, we consider here an agent optimizing its consumption-investment strategy on a finite time horizon. The value function interprets as the unique discontinuous viscosity solution of its corresponding Hamilton-Jacobi-Bellman equation. This leads to a numerical approximation of the value function and allows for a comparison with the explicit solution in infinite horizon

Influence of thermocleavable functionality on organic field-effect transistor performance of small molecules

Science.gov (United States)

Mahale, Rajashree Y.; Dharmapurikar, Satej S.; Chini, Mrinmoy Kumar; Venugopalan, Vijay

2017-06-01

Diketopyrrolopyrrole based donor-acceptor-donor conjugated small molecules using ethylene dioxythiophene as a donor was synthesized. Electron deficient diketopyrrolopyrrole unit was substituted with thermocleavable (tert-butyl acetate) side chains. The thermal treatment of the molecules at 160 °C eliminated the tert-butyl ester group results in the formation of corresponding acid. Optical and theoretical studies revealed that the molecules adopted a change in molecular arrangement after thermolysis. The conjugated small molecules possessed p-channel charge transport characteristics in organic field effect transistors. The charge carrier mobility was increased after thermolysis of tert-butyl ester group to 5.07 × 10-5 cm2/V s.

Negotiating transfer pricing using the Nash bargaining solution

Directory of Open Access Journals (Sweden)

Clempner Julio B.

2017-12-01

Full Text Available This paper analyzes and proposes a solution to the transfer pricing problem from the point of view of the Nash bargaining game theory approach. We consider a firm consisting of several divisions with sequential transfers, in which central management provides a transfer price decision that enables maximization of operating profits. Price transferring between divisions is negotiable throughout the bargaining approach. Initially, we consider a disagreement point (status quo between the divisions of the firm, which plays the role of a deterrent. We propose a framework and a method based on the Nash equilibrium approach for computing the disagreement point. Then, we introduce a bargaining solution, which is a single-valued function that selects an outcome from the feasible pay-offs for each bargaining problem that is a result of cooperation of the divisions of the firm involved in the transfer pricing problem. The agreement reached by the divisions in the game is the most preferred alternative within the set of feasible outcomes, which produces a profit-maximizing allocation of the transfer price between divisions. For computing the bargaining solution, we propose an optimization method. An example illustrating the usefulness of the method is presented.

On the Solutions of Two-Extended Principal Conformal Toda Theory

Science.gov (United States)

Chao, L.; Hou, B. Y.

1994-02-01

The solutions of the two-extended principal conformal Toda theory (2-EPCT theory, also called bosonic superconformal Toda theory) are constructed in two different ways: (1) Leznov-Saveliev algebraic analysis and (2) the associated chiral embedding surface. The first approach gives rise to the general solution in terms of appropriate matrix elements in different fundamental representations of the underlying Lie algebra, whilst the second one leads to a special solution in the form of Wronski determinants and their co-minors, and it gives an explicit geometrical interpretation of the WZNW → 2-EPCT reduction. The key points of both approaches are the chiral vectors derived recently by the authors, which constitute a closed exchange algebra of the theory.

Solutions in radiology services management: a literature review

Directory of Open Access Journals (Sweden)

Aline Garcia Pereira

2015-10-01

Full Text Available AbstractObjective:The present study was aimed at reviewing the literature to identify solutions for problems observed in radiology services.Materials and Methods:Basic, qualitative, exploratory literature review at Scopus and SciELO databases, utilizing the Mendeley and Illustrator CC Adobe softwares.Results:In the databases, 565 papers – 120 out of them, pdf free – were identified. Problems observed in the radiology sector are related to procedures scheduling, humanization, lack of training, poor knowledge and use of management techniques, and interaction with users. The design management provides the services with interesting solutions such as Benchmarking, CRM, Lean Approach, ServiceBlueprinting, continued education, among others.Conclusion:Literature review is an important tool to identify problems and respective solutions. However, considering the small number of studies approaching management of radiology services, this is a great field of research for the development of deeper studies.

Solutions in radiology services management: a literature review*

Science.gov (United States)

Pereira, Aline Garcia; Vergara, Lizandra Garcia Lupi; Merino, Eugenio Andrés Díaz; Wagner, Adriano

2015-01-01

Objective The present study was aimed at reviewing the literature to identify solutions for problems observed in radiology services. Materials and Methods Basic, qualitative, exploratory literature review at Scopus and SciELO databases, utilizing the Mendeley and Illustrator CC Adobe softwares. Results In the databases, 565 papers – 120 out of them, pdf free – were identified. Problems observed in the radiology sector are related to procedures scheduling, humanization, lack of training, poor knowledge and use of management techniques, and interaction with users. The design management provides the services with interesting solutions such as Benchmarking, CRM, Lean Approach, ServiceBlueprinting, continued education, among others. Conclusion Literature review is an important tool to identify problems and respective solutions. However, considering the small number of studies approaching management of radiology services, this is a great field of research for the development of deeper studies. PMID:26543281

Proposing New Heuristic Approaches for Preventive Maintenance Scheduling

Directory of Open Access Journals (Sweden)

majid Esmailian

2013-08-01

Full Text Available The purpose of preventive maintenance management is to perform a series of tasks that prevent or minimize production breakdowns and improve reliability of production facilities. An important objective of preventive maintenance management is to minimize downtime of production facilities. In order to accomplish this objective, personnel should efficiently allocate resources and determine an effective maintenance schedule. Gopalakrishnan (1997 developed a mathematical model and four heuristic approaches to solve the preventive maintenance scheduling problem of assigning skilled personnel to work with tasks that require a set of corresponding skills. However, there are several limitations in the prior work in this area of research. The craft combination problem has not been solved because the craft combination is assumed as given. The craft combination problem concerns the computation of all combinations of assigning multi skilled workers to accomplishment of a particular task. In fact, determining craft combinations is difficult because of the exponential number of craft combinations that are possible. This research provides a heuristic approach for determining the craft combination and four new heuristic approach solution for the preventive maintenance scheduling problem with multi skilled workforce constraints. In order to examine the new heuristic approach and to compare the new heuristic approach with heuristic approach of Gopalakrishnan (1997, 81 standard problems have been generated based on the criterion suggested by from Gopalakrishnan (1997. The average solution quality (SQ of the new heuristic approaches is 1.86% and in old heuristic approaches is 8.32%. The solution time of new heuristic approaches are shorter than old heuristic approaches. The solution time of new heuristic approaches is 0.78 second and old heuristic approaches is 6.43 second, but the solution time of mathematical model provided by Gopalakrishnan (1997 is 152 second. �

Solution of linear ill-posed problems using overcomplete dictionaries

OpenAIRE

Pensky, Marianna

2016-01-01

In the present paper we consider application of overcomplete dictionaries to solution of general ill-posed linear inverse problems. Construction of an adaptive optimal solution for such problems usually relies either on a singular value decomposition or representation of the solution via an orthonormal basis. The shortcoming of both approaches lies in the fact that, in many situations, neither the eigenbasis of the linear operator nor a standard orthonormal basis constitutes an appropriate co...

Technical Solution for Improved Safeguards/State Cooperation

International Nuclear Information System (INIS)

Miller, S.

2015-01-01

This paper will discuss an information technology solution to allow the IAEA Safeguards Department to improve cooperation with States. The solution will be a portal or hub to integrate the information, processes, and people between Safeguards and States. It will allow for two-way communication and collaboration between Safeguards staff and State representatives. This paper discusses the information security challenges inherent in building such a system. It proposes technical architectures that might allow the existing integration approach (e.g., encrypted email exchange) to be kept, while expanding it to include modern integration technologies (e.g., web services), as well explorer new collaborative web technologies. It looks at current Safeguards processes and approaches to cooperation and discusses efficiencies that could be achieved through the adoption of this technology solution. Example process areas for improvement include: a) Safeguards Agreements: States are obligated to submit data on their nuclear programme to the IAEA on a periodic basis. Declarations are received through two separate systems using encrypted email. The proposed solution would allow for enhanced exchange of declaration where States can submit any type of declaration using one system. When declarations are received and validated, an acknowledgement would automatically be sent to the State. The solution would provide the Safeguards Department the ability to ask for clarification as well as collaborate on the submitted declarations. Both the question and the response would be recorded in the system. The solution could also integrate tools allowing declarations to be added directly and validated before submission. b) Other areas that could benefit from this solution include declarations from States with small quantities protocol, facility declarations, as well as systems that support extra-budgetary funding (e.g., SPRICS). (author)

An improved conjugate gradient scheme to the solution of least squares SVM.

Science.gov (United States)

Chu, Wei; Ong, Chong Jin; Keerthi, S Sathiya

2005-03-01

The least square support vector machines (LS-SVM) formulation corresponds to the solution of a linear system of equations. Several approaches to its numerical solutions have been proposed in the literature. In this letter, we propose an improved method to the numerical solution of LS-SVM and show that the problem can be solved using one reduced system of linear equations. Compared with the existing algorithm for LS-SVM, the approach used in this letter is about twice as efficient. Numerical results using the proposed method are provided for comparisons with other existing algorithms.

New approach to the exact solution of viscous flow due to stretching (shrinking and porous sheet

Directory of Open Access Journals (Sweden)

Azhar Ali

Full Text Available Exact analytical solutions for the generalized stretching (shrinking of a porous surface, for the variable suction (injection velocity, is presented in this paper. The solution is generalized in the sense that the existing solutions that correspond to various stretching velocities are recovered as a special case of this study. A suitable similarity transformation is introduced to find self-similar solution of the non-linear governing equations. The flow is characterized by a few non-dimensional parameters signifying the problem completely. These parameters are such that the whole range of stretching (shrinking problems discussed earlier can be recovered by assigning appropriate values to these parameters. A key point of the whole narrative is that a number of earlier works can be abridged into one generalized problem through the introduction of a new similarity transformation and finding its exact solution encompassing all the earlier solutions. Keywords: Exact solutions, New similarities, Permeable and moving sheet

Applied Integer Programming Modeling and Solution

CERN Document Server

Chen, Der-San; Dang, Yu

2011-01-01

An accessible treatment of the modeling and solution of integer programming problems, featuring modern applications and software In order to fully comprehend the algorithms associated with integer programming, it is important to understand not only how algorithms work, but also why they work. Applied Integer Programming features a unique emphasis on this point, focusing on problem modeling and solution using commercial software. Taking an application-oriented approach, this book addresses the art and science of mathematical modeling related to the mixed integer programming (MIP) framework and

Spinning solutions in general relativity with infinite central density

Science.gov (United States)

Flammer, P. D.

2018-05-01

This paper presents general relativistic numerical simulations of uniformly rotating polytropes. Equations are developed using MSQI coordinates, but taking a logarithm of the radial coordinate. The result is relatively simple elliptical differential equations. Due to the logarithmic scale, we can resolve solutions with near-singular mass distributions near their center, while the solution domain extends many orders of magnitude larger than the radius of the distribution (to connect with flat space-time). Rotating solutions are found with very high central energy densities for a range of adiabatic exponents. Analytically, assuming the pressure is proportional to the energy density (which is true for polytropes in the limit of large energy density), we determine the small radius behavior of the metric potentials and energy density. This small radius behavior agrees well with the small radius behavior of large central density numerical results, lending confidence to our numerical approach. We compare results with rotating solutions available in the literature, which show good agreement. We study the stability of spherical solutions: instability sets in at the first maximum in mass versus central energy density; this is also consistent with results in the literature, and further lends confidence to the numerical approach.

The Role of Green Infrastructure Solutions in Urban Flood Risk Management

OpenAIRE

Soz, Salman Anees; Kryspin-Watson, Jolanta; Stanton-Geddes, Zuzana

2016-01-01

This Knowledge Note explores the role of green infrastructure solutions in urban flood risk management. Green infrastructure solutions represent an approach that focuses on using natural processes for managing wet weather impacts while delivering environmental, social, and economic benefits. Green infrastructure solutions, such as wetlands, bioshields, buffer zones, green roofing, street s...

Higher-order differencing method with a multigrid approach for the solution of the incompressible flow equations at high Reynolds numbers

International Nuclear Information System (INIS)

Tzanos, C.P.

1992-01-01

A higher-order differencing method was recently proposed for the convection-diffusion equation, which even with a coarse mesh gives oscillation-free solutions that are far more accurate than those of the upwind scheme. In this paper, the performance of this method is investigated in conjunction with the performance of different iterative solvers for the solution of the Navier-Stokes equations in the vorticity-streamfunction formulation for incompressible flow at high Reynolds numbers. Flow in a square cavity with a moving lid was chosen as a model problem. Solvers that performed well at low Re numbers either failed to converge or had a computationally prohibitive convergence rate at high Re numbers. The additive correction method of Settari and Aziz and an iterative incomplete lower and upper (ILU) solver were used in a multigrid approach that performed well in the whole range of Re numbers considered (from 1000 to 10,000) and for uniform as well as nonuniform grids. At high Re numbers, point or line Gauss-Seidel solvers converged with uniform grids, but failed to converge with nonuniform grids

A Polymer "Pollution Solution" Classroom Activity.

Science.gov (United States)

Helser, Terry L.

1996-01-01

Explains an approach to presenting polymer chemistry to nonmajors that employs polystyrene foam, foam peanuts made from water soluble starch, and water soluble plastic bags. Students are presented with a pollution scenario and are guided to the discovery of solutions. (DDR)

Travelling wave solutions to the Kuramoto-Sivashinsky equation

International Nuclear Information System (INIS)

Nickel, J.

2007-01-01

Combining the approaches given by Baldwin [Baldwin D et al. Symbolic computation of exact solutions expressible in hyperbolic and elliptic functions for nonlinear PDEs. J Symbol Comput 2004;37:669-705], Peng [Peng YZ. A polynomial expansion method and new general solitary wave solutions to KS equation. Comm Theor Phys 2003;39:641-2] and by Schuermann [Schuermann HW, Serov VS. Weierstrass' solutions to certain nonlinear wave and evolution equations. Proc progress electromagnetics research symposium, 28-31 March 2004, Pisa. p. 651-4; Schuermann HW. Traveling-wave solutions to the cubic-quintic nonlinear Schroedinger equation. Phys Rev E 1996;54:4312-20] leads to a method for finding exact travelling wave solutions of nonlinear wave and evolution equations (NLWEE). The first idea is to generalize ansaetze given by Baldwin and Peng to find elliptic solutions of NLWEEs. Secondly, conditions used by Schuermann to find physical (real and bounded) solutions and to discriminate between periodic and solitary wave solutions are used. The method is shown in detail by evaluating new solutions of the Kuramoto-Sivashinsky equation

Topological inversion for solution of geodesy-constrained geophysical problems

Science.gov (United States)

Saltogianni, Vasso; Stiros, Stathis

2015-04-01

Geodetic data, mostly GPS observations, permit to measure displacements of selected points around activated faults and volcanoes, and on the basis of geophysical models, to model the underlying physical processes. This requires inversion of redundant systems of highly non-linear equations with >3 unknowns; a situation analogous to the adjustment of geodetic networks. However, in geophysical problems inversion cannot be based on conventional least-squares techniques, and is based on numerical inversion techniques (a priori fixing of some variables, optimization in steps with values of two variables each time to be regarded fixed, random search in the vicinity of approximate solutions). Still these techniques lead to solutions trapped in local minima, to correlated estimates and to solutions with poor error control (usually sampling-based approaches). To overcome these problems, a numerical-topological, grid-search based technique in the RN space is proposed (N the number of unknown variables). This technique is in fact a generalization and refinement of techniques used in lighthouse positioning and in some cases of low-accuracy 2-D positioning using Wi-Fi etc. The basic concept is to assume discrete possible ranges of each variable, and from these ranges to define a grid G in the RN space, with some of the gridpoints to approximate the true solutions of the system. Each point of hyper-grid G is then tested whether it satisfies the observations, given their uncertainty level, and successful grid points define a sub-space of G containing the true solutions. The optimal (minimal) space containing one or more solutions is obtained using a trial-and-error approach, and a single optimization factor. From this essentially deterministic identification of the set of gridpoints satisfying the system of equations, at a following step, a stochastic optimal solution is computed corresponding to the center of gravity of this set of gridpoints. This solution corresponds to a

Legendre Wavelet Operational Matrix Method for Solution of Riccati Differential Equation

Directory of Open Access Journals (Sweden)

S. Balaji

2014-01-01

Full Text Available A Legendre wavelet operational matrix method (LWM is presented for the solution of nonlinear fractional-order Riccati differential equations, having variety of applications in quantum chemistry and quantum mechanics. The fractional-order Riccati differential equations converted into a system of algebraic equations using Legendre wavelet operational matrix. Solutions given by the proposed scheme are more accurate and reliable and they are compared with recently developed numerical, analytical, and stochastic approaches. Comparison shows that the proposed LWM approach has a greater performance and less computational effort for getting accurate solutions. Further existence and uniqueness of the proposed problem are given and moreover the condition of convergence is verified.

Enhanced Multistage Homotopy Perturbation Method: Approximate Solutions of Nonlinear Dynamic Systems

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Daniel Olvera

2014-01-01

Full Text Available We introduce a new approach called the enhanced multistage homotopy perturbation method (EMHPM that is based on the homotopy perturbation method (HPM and the usage of time subintervals to find the approximate solution of differential equations with strong nonlinearities. We also study the convergence of our proposed EMHPM approach based on the value of the control parameter h by following the homotopy analysis method (HAM. At the end of the paper, we compare the derived EMHPM approximate solutions of some nonlinear physical systems with their corresponding numerical integration solutions obtained by using the classical fourth order Runge-Kutta method via the amplitude-time response curves.

Hierarchical Solution of the Traveling Salesman Problem with Random Dyadic Tilings

Science.gov (United States)

Kalmár-Nagy, Tamás; Bak, Bendegúz Dezső

We propose a hierarchical heuristic approach for solving the Traveling Salesman Problem (TSP) in the unit square. The points are partitioned with a random dyadic tiling and clusters are formed by the points located in the same tile. Each cluster is represented by its geometrical barycenter and a “coarse” TSP solution is calculated for these barycenters. Midpoints are placed at the middle of each edge in the coarse solution. Near-optimal (or optimal) minimum tours are computed for each cluster. The tours are concatenated using the midpoints yielding a solution for the original TSP. The method is tested on random TSPs (independent, identically distributed points in the unit square) up to 10,000 points as well as on a popular benchmark problem (att532 — coordinates of 532 American cities). Our solutions are 8-13% longer than the optimal ones. We also present an optimization algorithm for the partitioning to improve our solutions. This algorithm further reduces the solution errors (by several percent using 1000 iteration steps). The numerical experiments demonstrate the viability of the approach.

Molecular thermodynamics using fluctuation solution theory

DEFF Research Database (Denmark)

Ellegaard, Martin Dela

. The framework relates thermodynamic variables to molecular pair correlation functions of liquid mixtures. In this thesis, application of the framework is illustrated using two approaches: 1. Solubilities of solid solutes in mixed solvent systems are determined from fluctuation solution theory application......Properties of chemicals and their mutual phase equilibria are critical variables in process design. Reliable estimates of relevant equilibrium properties, from thermodynamic models, can form the basis of good decision making in the development phase of a process design, especially when access...... to relevant experimental data is limited. This thesis addresses the issue of generating and using simple thermodynamic models within a rigorous statistical mechanical framework, the so-called fluctuation solution theory, from which relations connecting properties and phase equilibria can be obtained...

Semiclassical approach to the quantization of the periodic solutions of the sine-Gordon equation

International Nuclear Information System (INIS)

Ghika, G.; Visinescu, M.

1978-01-01

The periodic solutions of the sine-Gordon equation are proved to be singular. For the semiclassical quantization of the periodic solutions we calculate the fluctuations around them and we use the path integrals in the Gaussian approximation in order to obtain the bound states of the sine-Gordon field equation. (author)

Test particle propagation in magnetostatic turbulence. 3: the approach to equilibrium

International Nuclear Information System (INIS)

Klimas, A.J.; Sandri, G.; Scudder, J.D.; Howell, D.R.

1977-05-01

The asymptotic behavior, for large time, of the quasi-linear diabatic solutions and their local approximations is considered. A time averaging procedure is introduced which yields the averages of these solutions over time intervals which contain only large time values. A discussion of the quasi-linear diabatic solutions which is limited to those solutions that are bounded from below as functions of time is given. It is shown that as the upper limit of the time averaging interval is allowed to approach infinity the time averaged quasi-linear diabatic solutions must approach isotropy (mu-independence). The first derivative with respect to mu of these solutions is also considered. This discussion is limited to first derivatives which are bounded functions of time. It is shown that as the upper limit of the time averaging interval is allowed to approach infinity, the time averaged first derivative must approach zero everywhere in mu except at mu = 0 where it must approach a large value which is calculated. The impact of this large derivative on the quasi-linear expansion scheme is discussed. An H-theorem for the first local approximation to the quasi-linear diabatic solutions is constructed. Without time averaging, the H-theorem is used to determine sufficient conditions for the first local approximate solutions to asymptote, with increasing time, to exactly the same final state which the time averaged quasi-linear diabatic solutions must approach as discussed above

Solution-Focused Brief Therapy: Impacts on Academic and Emotional Difficulties

Science.gov (United States)

Daki, Julia; Savage, Robert S.

2010-01-01

This randomized control trial study evaluated the effectiveness of the solution-focused approach in addressing academic, motivational, and socioemotional needs of 14 children with reading difficulties. The intervention group received five 40-min solution-focused sessions. The control group received academic homework support. Results showed…

Recoil halogen reactions in liquid and frozen aqueous solutions of biomolecules

International Nuclear Information System (INIS)

Arsenault, L.J.; Blotcky, A.J.; Firouzbakht, M.L.; Rack, E.P.; Nebraska Univ., Omaha

1982-01-01

Reactions of recoil 38 Cl, 80 Br and 128 I have been studied in crystalline systems of 5-halouracil, 5-halo-2'-deoxyuridine and 5-halouridine as well as liquid and frozen aqueous solutions of these halogenated biomolecules. In all systems expect crystalline 5-iuodouracil the major product was the radio-labelled halide ion. There was no evidence for other halogen inorganic species. The major labelled organic product was the parent molecule. A recoil atom tracer technique was developed to acquire site information of the biomolecule solutes in the liquid and frozen aqueous systems. For all liquid and frozen aqueous systems, the halogenated biomolecules tended to aggregate. For liquid systems, the tendency for aggregation diminished as the solute concentration approached zero, where the probable state of the solute approached a monomolecular dispersion. Unlike the liquid state, the frozen ice lattice demonstated a ''caging effect'' for the solute aggregates which resulted in constant product yields over the whole concentration range. (orig.)

Predicting adsorptive removal of chlorophenol from aqueous solution using artificial intelligence based modeling approaches.

Science.gov (United States)

Singh, Kunwar P; Gupta, Shikha; Ojha, Priyanka; Rai, Premanjali

2013-04-01

The research aims to develop artificial intelligence (AI)-based model to predict the adsorptive removal of 2-chlorophenol (CP) in aqueous solution by coconut shell carbon (CSC) using four operational variables (pH of solution, adsorbate concentration, temperature, and contact time), and to investigate their effects on the adsorption process. Accordingly, based on a factorial design, 640 batch experiments were conducted. Nonlinearities in experimental data were checked using Brock-Dechert-Scheimkman (BDS) statistics. Five nonlinear models were constructed to predict the adsorptive removal of CP in aqueous solution by CSC using four variables as input. Performances of the constructed models were evaluated and compared using statistical criteria. BDS statistics revealed strong nonlinearity in experimental data. Performance of all the models constructed here was satisfactory. Radial basis function network (RBFN) and multilayer perceptron network (MLPN) models performed better than generalized regression neural network, support vector machines, and gene expression programming models. Sensitivity analysis revealed that the contact time had highest effect on adsorption followed by the solution pH, temperature, and CP concentration. The study concluded that all the models constructed here were capable of capturing the nonlinearity in data. A better generalization and predictive performance of RBFN and MLPN models suggested that these can be used to predict the adsorption of CP in aqueous solution using CSC.

Implementing SaaS Solution for CRM

Directory of Open Access Journals (Sweden)

Adriana LIMBASAN

2011-01-01

Full Text Available Greatest innovations in virtualization and distributed computing have accelerated interest in cloud computing (IaaS, PaaS, SaaS, aso. This paper presents the SaaS prototype for Customer Relationship Management of a real estate company. Starting from several approaches of e-marketing and SaaS features and architectures, we adopted a model for a CRM solution using SaaS Level 2 architecture and distributed database. Based on the system objective, functionality, we developed a modular solution for solve CRM and e-marketing targets in real estate companies.

Inverse Kinematics With Closed Form Solution For Denso Robot Manipulator

Directory of Open Access Journals (Sweden)

Ikhsan Eka Prasetia

2015-03-01

Full Text Available In this paper, the forward kinematics and inverse kinematics used on the Denso robot manipulator which has a 6-DOF. The forward kinematics will result in the desired position by end-effector, while inverse kinematics produce angel on each joint. Inverse kinematics problem are very difficult, therefor to obtain the solution of inverse kinematics using closed form solution with geometry approach. The simulation result obtained from forward kinematics and inverse kinematics is determining desired position by Denso robot manipulator. Forward kinematics produce the desired position by the end-effector. Inverse kinematics produce joint angle, where the inverse kinematics produce eight conditions obtained from closed form solution with geometry approach to reach the desired position by the end-effector.

Problem Solution Processes of Musicians and Engineers: What do Their Approaches Look Like

Directory of Open Access Journals (Sweden)

Säde-Pirkko Nissilä

2015-06-01

Full Text Available PBL is learning through becoming conscious of practical and abstract problems and finding ways how to solve them. It can be a pattern which doesn’t follow traditional divisions of disciplines. In this article the material was collected from two, in the first sight, very different groups. One was music students (N = 62 who had to learn to solve various practical and theoretical problems in preparing a program for a series of concerts as collective and individual action. The method used was the 7-step method which divides learning into seven phases proceeding from creating the social frame of reference and mental models (steps 1–4 through actual work (steps 5–6 to the evaluation of the outcomes (step 7. Another group consisted of international, multicultural business leaders in engineering (N = 6. In using earlier the 7-step method, the approaches resembled those of the music students: deepening their professional competences. To engage their ability to use imagination and connect reality with brainstorming and mental flexibility, the creative PBL method 635 was used. Three practical problems were solved so that the solutions included new viewpoints which would be applied to meet the real needs in the near future. The results show that not only were the learning targets of both groups reached but, with reflection included, the processes widened the professional competences of the participants.

Dielectric constant of ionic solutions: a field-theory approach.

Science.gov (United States)

Levy, Amir; Andelman, David; Orland, Henri

2012-06-01

We study the variation of the dielectric response of a dielectric liquid (e.g. water) when a salt is added to the solution. Employing field-theoretical methods, we expand the Gibbs free energy to first order in a loop expansion and calculate self-consistently the dielectric constant. We predict analytically the dielectric decrement which depends on the ionic strength in a complex way. Furthermore, a qualitative description of the hydration shell is found and is characterized by a single length scale. Our prediction fits rather well a large range of concentrations for different salts using only one fit parameter related to the size of ions and dipoles.

Designing Integrated Product- Service System Solutions in Manufacturing Industries

DEFF Research Database (Denmark)

Costa, Nina; Patrício, Lia; Morelli, Nicola

2015-01-01

Manufacturing firms are increasingly evolving towards the design of integrated product-service solutions but servitization literature does not provide specific guidance on how to design these integrated solutions. Building upon ProductService System (PSS) and Service Design (SD) approaches...... how it brings new insights to manufacturing companies moving to a service, value cocreation perspective....

Electrodriven selective transport of Cs+ using chlorinated cobalt dicarbollide in polymer inclusion membrane: a novel approach for cesium removal from simulated nuclear waste solution.

Science.gov (United States)

Chaudhury, Sanhita; Bhattacharyya, Arunasis; Goswami, Asok

2014-11-04

The work describes a novel and cleaner approach of electrodriven selective transport of Cs from simulated nuclear waste solutions through cellulose tri acetate (CTA)/poly vinyl chloride (PVC) based polymer inclusion membrane. The electrodriven cation transport together with the use of highly Cs+ selective hexachlorinated derivative of cobalt bis dicarbollide, allows to achieve selective separation of Cs+ from high concentration of Na+ and other fission products in nuclear waste solutions. The transport selectivity has been studied using radiotracer technique as well as atomic emission spectroscopic technique. Transport studies using CTA based membrane have been carried out from neutral solution as well as 0.4 M HNO3, while that with PVC based membrane has been carried out from 3 M HNO3. High decontamination factor for Cs+ over Na+ has been obtained in all the cases. Experiment with simulated high level waste solution shows selective transport of Cs+ from most of other fission products also. Significantly fast Cs+ transport rate along with high selectivity is an interesting feature observed in this membrane. The current efficiency for Cs+ transport has been found to be ∼100%. The promising results show the possibility of using this kind of electrodriven membrane transport methods for nuclear waste treatment.

General solution of string inspired nonlinear equations

International Nuclear Information System (INIS)

Bandos, I.A.; Ivanov, E.; Kapustnikov, A.A.; Ulanov, S.A.

1998-07-01

We present the general solution of the system of coupled nonlinear equations describing dynamics of D-dimensional bosonic string in the geometric (or embedding) approach. The solution is parametrized in terms of two sets of the left- and right-moving Lorentz harmonic variables providing a special coset space realization of the product of two (D-2) dimensional spheres S D-2 = SO(1,D-1)/SO(1,1)xSO(D-2) contained in K D-2 . (author)

Radiotherapy problem under fuzzy theoretic approach

International Nuclear Information System (INIS)

Ammar, E.E.; Hussein, M.L.

2003-01-01

A fuzzy set theoretic approach is used for radiotherapy problem. The problem is faced with two goals: the first is to maximize the fraction of surviving normal cells and the second is to minimize the fraction of surviving tumor cells. The theory of fuzzy sets has been employed to formulate and solve the problem. A linguistic variable approach is used for treating the first goal. The solutions obtained by the modified approach are always efficient and best compromise. A sensitivity analysis of the solutions to the differential weights is given

Polygons of differential equations for finding exact solutions

International Nuclear Information System (INIS)

Kudryashov, Nikolai A.; Demina, Maria V.

2007-01-01

A method for finding exact solutions of nonlinear differential equations is presented. Our method is based on the application of polygons corresponding to nonlinear differential equations. It allows one to express exact solutions of the equation studied through solutions of another equation using properties of the basic equation itself. The ideas of power geometry are used and developed. Our approach has a pictorial interpretation, which is illustrative and effective. The method can be also applied for finding transformations between solutions of differential equations. To demonstrate the method application exact solutions of several equations are found. These equations are: the Korteveg-de Vries-Burgers equation, the generalized Kuramoto-Sivashinsky equation, the fourth-order nonlinear evolution equation, the fifth-order Korteveg-de Vries equation, the fifth-order modified Korteveg-de Vries equation and the sixth-order nonlinear evolution equation describing turbulent processes. Some new exact solutions of nonlinear evolution equations are given

A minimum wage solution to halving world poverty by 2015: A stakeholder approach

Directory of Open Access Journals (Sweden)

Arvind Ashta

2013-03-01

Full Text Available The UNDP has set Millennium Goals which include the halving of world poverty by 2015. This was translated into reducing by half the number of people living in abject poverty. We examine some existing poverty reduction solutions which are being experimented with, including aid (with central planning with participatory development, property rights, education, microfinance, bottom of the pyramid inclusion, and public sector employment, and find that these have been inadequate to the task, even conjointly. We add a minimum wage based solution.

Adaptive Multi-path Telecommunications Solutions for ITS

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Tomas Zelinka

2011-02-01

Full Text Available Intelligent Transport Services (ITS applications require availability of the wireless seamless secure communications solutions with selectable services quality and wide-area coverage. There are available both public as well as private wireless data services, however, dominantly in case of public services no guaranteed data service quality is offered. Principal improvement of the service quality can be reached by dynamical selection of the best possible alternative from the available portfolio of relevant services. Efficient decision processes must be implemented in the appropriate flexible seamless routing/switching structures. Generally recommended solution has been described in series of documents generated by ISO/CEN known as CALM family of standards. In accordance to our understanding CALM architecture represents very complex attitude, however, it is demanding solution for less ambitious implementations. On the other hand CALM decision processes are limited to approach based on the Policy-based Management (PBM principles with limited functionality and adaptability. Authors present L3 alternative solution with adaptive classifications processes applied instead of PBM ones. Such approach can be efficiently implemented specifically if there is available deep understanding of applied technologies. Requirements on the representative system performance indicators and their tolerance range should be so carefully identified. Paper includes results of authors’ laboratory study of three most widely spread data services which can be understood as basis for the “CALM ideas” based system implementations.

Complex structure of Kerr geometry and rotating 'photon rocket' solutions

International Nuclear Information System (INIS)

Burinskii, Alexander

2003-01-01

In the frame of the Kerr-Schild approach, we obtain a generalization of the Kerr solution to a nonstationary case corresponding to a rotating source moving with arbitrary acceleration. Similar to the Kerr solution, the solutions obtained have geodesic and shearfree principal null congruence. The current parameters of the solutions are determined by a complex retarded-time construction via a given complex worldline of source. The real part of the complex worldline defines the values of the boost and acceleration while the imaginary part controls the rotation. The acceleration of the source is accompanied by lightlike radiation along the principal null congruence. The solutions obtained generalize to the rotating case the known Kinnersley class of the 'photon rocket' solutions

Exactly Solvable Quantum Mechanical Potentials: An Alternative Approach.

Science.gov (United States)

Pronchik, Jeremy N.; Williams, Brian W.

2003-01-01

Describes an alternative approach to finding exactly solvable, one-dimensional quantum mechanical potentials. Differs from the usual approach in that instead of starting with a particular potential and seeking solutions to the related Schrodinger equations, it begins with known solutions to second-order ordinary differential equations and seeks to…

On the Solution of the Rational Matrix Equation

Directory of Open Access Journals (Sweden)

Faßbender Heike

2007-01-01

Full Text Available We study numerical methods for finding the maximal symmetric positive definite solution of the nonlinear matrix equation , where is symmetric positive definite and is nonsingular. Such equations arise for instance in the analysis of stationary Gaussian reciprocal processes over a finite interval. Its unique largest positive definite solution coincides with the unique positive definite solution of a related discrete-time algebraic Riccati equation (DARE. We discuss how to use the butterfly algorithm to solve the DARE. This approach is compared to several fixed-point and doubling-type iterative methods suggested in the literature.

Numerical Modeling Tools for the Prediction of Solution Migration Applicable to Mining Site

International Nuclear Information System (INIS)

Martell, M.; Vaughn, P.

1999-01-01

Mining has always had an important influence on cultures and traditions of communities around the globe and throughout history. Today, because mining legislation places heavy emphasis on environmental protection, there is great interest in having a comprehensive understanding of ancient mining and mining sites. Multi-disciplinary approaches (i.e., Pb isotopes as tracers) are being used to explore the distribution of metals in natural environments. Another successful approach is to model solution migration numerically. A proven method to simulate solution migration in natural rock salt has been applied to project through time for 10,000 years the system performance and solution concentrations surrounding a proposed nuclear waste repository. This capability is readily adaptable to simulate solution migration around mining

On Solutions for Linear and Nonlinear Schrödinger Equations with Variable Coefficients: A Computational Approach

Directory of Open Access Journals (Sweden)

Gabriel Amador

2016-05-01

Full Text Available In this work, after reviewing two different ways to solve Riccati systems, we are able to present an extensive list of families of integrable nonlinear Schrödinger (NLS equations with variable coefficients. Using Riccati equations and similarity transformations, we are able to reduce them to the standard NLS models. Consequently, we can construct bright-, dark- and Peregrine-type soliton solutions for NLS with variable coefficients. As an important application of solutions for the Riccati equation with parameters, by means of computer algebra systems, it is shown that the parameters change the dynamics of the solutions. Finally, we test numerical approximations for the inhomogeneous paraxial wave equation by the Crank-Nicolson scheme with analytical solutions found using Riccati systems. These solutions include oscillating laser beams and Laguerre and Gaussian beams.

Solute–Solute Interaction In α IRON: The Status QUO

Directory of Open Access Journals (Sweden)

Numakura H.

2015-09-01

Full Text Available An overview is presented on the interaction of substitutional solutes with carbon and nitrogen in α iron, which is an important factor in controlling the properties of steels. Starting from a simple model of trapping of the interstitial solute atoms by substitutional solute atoms, the principles of experimental methods for quantitative studies are described, focussing on the Snoek relaxation and solubility measurements, and the knowledge acquired by such experiments is reviewed. An account of recent theoretical approaches to the interaction is also given.

Impact of vacancy-solute clusters on the aging of α-Fe solid solutions

International Nuclear Information System (INIS)

Schuler, Thomas

2015-01-01

Understanding and monitoring the aging of steels under vacancy supersaturation is a challenge of great practical interest for many industrial groups, and most of all for those related to nuclear energy. These steels always contain interstitial solutes, either as alloying elements or as impurities, and vacancies (V) that are equilibrium structural defects of materials. We have chosen the Fe-V -X system (X = C, N or O) as a model system for ferritic steels. Vacancy-solute clusters are likely to form in such systems because, despite the very low concentrations of their components, these cluster show very high attractive bonding. First of all, we have been working on the computation of intrinsic equilibrium properties of individual clusters, both thermodynamic (free binding energies) and kinetic (mobilities, dissociation coefficients, and their relationship with continuum diffusion) properties. Thanks to this atomic-scale characterization procedure, we have been able to highlight various effects of these clusters on a macroscopic system containing different cluster types: increase of solute solubility limits and total vacancy concentrations, flux couplings between interstitial solutes and vacancies, acceleration of solute precipitation kinetics and precipitate dissolution by solid solution stabilization due to vacancies. These results would not have been obtained without the development and/or extension of analytical methods in statistical physics which are able to describe cluster's components and their interactions at the atomic scale. Finally, we have also been working on cavities in α-iron, the study of which requires a different approach. Our study highlights the impact of the atomic discrete lattice on the equilibrium shape of cavities, and describes various kinetic mechanisms of these objects at the atomic scale. (author) [fr

Integrated solution for field operations

Energy Technology Data Exchange (ETDEWEB)

Aubin, Renaud; Dionis, Francois [EDF, Chatou (France)

2014-08-15

This document presents our approach to design and to implement mobile applications for field operations. Internal on-field studies yield to the fact that the value added by mobile solutions is correlated with the easiness of their integration with each other and with the underlying information systems. Moreover, the fast-growing mobile market brings new concepts to the mass and industrial applications design can benefit from these. As a consequence, a simple components-based approach has been applied to design and develop mobile applications for field operations and on-site experiments of the resulting applications have been conducted.

Integrated solution for field operations

International Nuclear Information System (INIS)

Aubin, Renaud; Dionis, Francois

2014-01-01

This document presents our approach to design and to implement mobile applications for field operations. Internal on-field studies yield to the fact that the value added by mobile solutions is correlated with the easiness of their integration with each other and with the underlying information systems. Moreover, the fast-growing mobile market brings new concepts to the mass and industrial applications design can benefit from these. As a consequence, a simple components-based approach has been applied to design and develop mobile applications for field operations and on-site experiments of the resulting applications have been conducted

Integrated solution for field operations

International Nuclear Information System (INIS)

Aubin, Renaud; Dionis, Francois

2014-01-01

This paper presents the authors' approach to design and to implement mobile applications for field operations. Internal on-field studies can yield the fact that the value-added by mobile solutions is correlated with the easiness of their integration with each other and with the underlying information systems. Moreover, the fast-growing mobile market brings new concepts to the mass and industrial applications design can benefit from these. As a consequence, a simple components-based approach has been applied to design and develop mobile applications for field operations and on-site experiments of the resulting applications have been conducted. (author)

Exact Solutions to a Combined sinh-cosh-Gordon Equation

International Nuclear Information System (INIS)

Wei Long

2010-01-01

Based on a transformed Painleve property and the variable separated ODE method, a function transformation method is proposed to search for exact solutions of some partial differential equations (PDEs) with hyperbolic or exponential functions. This approach provides a more systematical and convenient handling of the solution process of this kind of nonlinear equations. Its key point is to eradicate the hyperbolic or exponential terms by a transformed Painleve property and reduce the given PDEs to a variable-coefficient ordinary differential equations, then we seek for solutions to the resulting equations by some methods. As an application, exact solutions for the combined sinh-cosh-Gordon equation are formally derived. (general)

Comments on lump solutions in SFT

International Nuclear Information System (INIS)

Bonora, Loriano; Tolla, Driba D.

2016-01-01

We analyze a recently proposed scheme to construct analytic lump solutions in open SFT. We argue that in order for the scheme to be operative and to guarantee background independence it must be implemented in the same 2D conformal field theory in which SFT is formulated. We outline and discuss two different possible approaches. Next we reconsider an older proposal for analytic lump solutions and implement a few improvements. In the course of the analysis we formulate a distinction between regular and singular gauge transformations and advocate the necessity of defining a topology in the space of string fields. (orig.)

Comments on lump solutions in SFT

Energy Technology Data Exchange (ETDEWEB)

Bonora, Loriano; Tolla, Driba D. [International School for Advanced Studies (SISSA), Trieste (Italy); INFN, Sezione di Trieste, Trieste (Italy)

2016-04-15

We analyze a recently proposed scheme to construct analytic lump solutions in open SFT. We argue that in order for the scheme to be operative and to guarantee background independence it must be implemented in the same 2D conformal field theory in which SFT is formulated. We outline and discuss two different possible approaches. Next we reconsider an older proposal for analytic lump solutions and implement a few improvements. In the course of the analysis we formulate a distinction between regular and singular gauge transformations and advocate the necessity of defining a topology in the space of string fields. (orig.)

New solitary wave solutions to the modified Kawahara equation

International Nuclear Information System (INIS)

Wazwaz, Abdul-Majid

2007-01-01

In this work we use the sine-cosine method, the tanh method, the extended tanh method, and ansatze of hyperbolic functions for analytic treatment for the modified Kawahara equation. New solitons solutions and periodic solutions are formally derived. The change of the parameters, that will drastically change the characteristics of the equation, is examined. The employed approaches are reliable and manageable

Fabrication and applications of copper sulfide (CuS) nanostructures

Energy Technology Data Exchange (ETDEWEB)

Shamraiz, Umair, E-mail: umairshamraiz@gmail.com; Hussain, Raja Azadar, E-mail: hussainazadar@gamil.com; Badshah, Amin, E-mail: aminbadshah@yahoo.com

2016-06-15

This review article presents different fabrication procedures (under the headlines of solvothermal routes, aerosol methods, solution methods and thermolysis), and applications (photocatalytic degradation, ablation of cancer cells, electrode material in lithium ion batteries and in gas sensing, organic solar cells, field emission properties, super capacitor applications, photoelectrochemical performance of QDSCs, photocatalytic reduction of organic pollutants, electrochemical bio sensing, enhanced PEC characteristics of pre-annealed CuS film electrodes) of copper sulfide (Covellite). - Highlights: • This review article presents the synthesis and applications of copper sulfide. • CuS has been used over the years for different applications in nanoscience. • Different synthetic protocols are followed for their preparation which help in the possible modifications in the morphology of CuS.

Alternative solution algorithm for coupled thermal-hydraulic problems

International Nuclear Information System (INIS)

Farnsworth, D.A.; Rice, J.G.

1986-01-01

A thermal-hydraulic system involves flow of a fluid for which a combined solution of the continuity, momentum, and energy equations is required. When the solutions of the energy and momentum fields are dependent on each other, the system is said to be thermally coupled. A common problem encountered in the numerical solution of strongly coupled thermal-hydraulic problems is a very slow rate of convergence or a complete lack of convergence. Many times this degradation in convergence is due to the lack of true coupling between the energy and momentum fields during the iteration process. In the most widely used solution algorithms - such as the SIMPLE algorithm and its many variants - a sequential solution technique is required. That is, the solution process alternates between the flow and energy fields until a converged solution is obtained. This approach allows only implicit energy-momentum coupling. To improve the convergence rate for strongly coupled problems, a practical solution algorithm that can accommodate true energy-momentum coupling terms was developed. A complete simultaneous (versus sequential) solution of the governing conservation equations utilizing a line-by-line solution was developed and direct coupling terms between the momentum and energy fields were added utilizing a modified Newton-Raphson technique

The elastic solid solution model for minerals at high pressures and temperatures

Science.gov (United States)

Myhill, R.

2018-02-01

Non-ideality in mineral solid solutions affects their elastic and thermodynamic properties, their thermobaric stability, and the equilibrium phase relations in multiphase assemblages. At a given composition and state of order, non-ideality in minerals is typically modelled via excesses in Gibbs free energy which are either constant or linear with respect to pressure and temperature. This approach has been extremely successful when modelling near-ideal solutions. However, when the lattice parameters of the solution endmembers differ significantly, extrapolations of thermodynamic properties to high pressures using these models may result in significant errors. In this paper, I investigate the effect of parameterising solution models in terms of the Helmholtz free energy, treating volume (or lattice parameters) rather than pressure as an independent variable. This approach has been previously applied to models of order-disorder, but the implications for the thermodynamics and elasticity of solid solutions have not been fully explored. Solid solution models based on the Helmholtz free energy are intuitive at a microscopic level, as they automatically include the energetic contribution from elastic deformation of the endmember lattices. A chemical contribution must also be included in such models, which arises from atomic exchange within the solution. Derivations are provided for the thermodynamic properties of n-endmember solutions. Examples of the use of the elastic model are presented for the alkali halides, pyroxene, garnet, and bridgmanite solid solutions. Elastic theory provides insights into the microscopic origins of non-ideality in a range of solutions, and can make accurate predictions of excess enthalpies, entropies, and volumes as a function of volume and temperature. In solutions where experimental data are sparse or contradictory, the Helmholtz free energy approach can be used to assess the magnitude of excess properties and their variation as a function

Solitary wave solutions to nonlinear evolution equations in ...

Indian Academy of Sciences (India)

1Computer Engineering Technique Department, Al-Rafidain University College, Baghdad, ... applied to extract solutions are tan–cot method and functional variable approaches. ... Consider the nonlinear partial differential equation in the form.

Effective Approach for Increasing the Heteroatom Doping Levels of Porous Carbons for Superior CO2 Capture and Separation Performance.

Science.gov (United States)

Abdelmoaty, Yomna H; Tessema, Tsemre-Dingel; Norouzi, Nazgol; El-Kadri, Oussama M; Turner, Joseph B McGee; El-Kaderi, Hani M

2017-10-18

Development of efficient sorbents for carbon dioxide (CO 2 ) capture from flue gas or its removal from natural gas and landfill gas is very important for environmental protection. A new series of heteroatom-doped porous carbon was synthesized directly from pyrazole/KOH by thermolysis. The resulting pyrazole-derived carbons (PYDCs) are highly doped with nitrogen (14.9-15.5 wt %) as a result of the high nitrogen-to-carbon ratio in pyrazole (43 wt %) and also have a high oxygen content (16.4-18.4 wt %). PYDCs have a high surface area (SA BET = 1266-2013 m 2 g -1 ), high CO 2 Q st (33.2-37.1 kJ mol -1 ), and a combination of mesoporous and microporous pores. PYDCs exhibit significantly high CO 2 uptakes that reach 2.15 and 6.06 mmol g -1 at 0.15 and 1 bar, respectively, at 298 K. At 273 K, the CO 2 uptake improves to 3.7 and 8.59 mmol g -1 at 0.15 and 1 bar, respectively. The reported porous carbons also show significantly high adsorption selectivity for CO 2 /N 2 (128) and CO 2 /CH 4 (13.4) according to ideal adsorbed solution theory calculations at 298 K. Gas breakthrough studies of CO 2 /N 2 (10:90) at 298 K showed that PYDCs display excellent separation properties. The ability to tailor the physical properties of PYDCs as well as their chemical composition provides an effective strategy for designing efficient CO 2 sorbents.

The precise time-dependent solution of the Fokker–Planck equation with anomalous diffusion

International Nuclear Information System (INIS)

Guo, Ran; Du, Jiulin

2015-01-01

We study the time behavior of the Fokker–Planck equation in Zwanzig’s rule (the backward-Ito’s rule) based on the Langevin equation of Brownian motion with an anomalous diffusion in a complex medium. The diffusion coefficient is a function in momentum space and follows a generalized fluctuation–dissipation relation. We obtain the precise time-dependent analytical solution of the Fokker–Planck equation and at long time the solution approaches to a stationary power-law distribution in nonextensive statistics. As a test, numerically we have demonstrated the accuracy and validity of the time-dependent solution. - Highlights: • The precise time-dependent solution of the Fokker–Planck equation with anomalous diffusion is found. • The anomalous diffusion satisfies a generalized fluctuation–dissipation relation. • At long time the time-dependent solution approaches to a power-law distribution in nonextensive statistics. • Numerically we have demonstrated the accuracy and validity of the time-dependent solution

The precise time-dependent solution of the Fokker–Planck equation with anomalous diffusion

Energy Technology Data Exchange (ETDEWEB)

Guo, Ran; Du, Jiulin, E-mail: jiulindu@aliyun.com

2015-08-15

We study the time behavior of the Fokker–Planck equation in Zwanzig’s rule (the backward-Ito’s rule) based on the Langevin equation of Brownian motion with an anomalous diffusion in a complex medium. The diffusion coefficient is a function in momentum space and follows a generalized fluctuation–dissipation relation. We obtain the precise time-dependent analytical solution of the Fokker–Planck equation and at long time the solution approaches to a stationary power-law distribution in nonextensive statistics. As a test, numerically we have demonstrated the accuracy and validity of the time-dependent solution. - Highlights: • The precise time-dependent solution of the Fokker–Planck equation with anomalous diffusion is found. • The anomalous diffusion satisfies a generalized fluctuation–dissipation relation. • At long time the time-dependent solution approaches to a power-law distribution in nonextensive statistics. • Numerically we have demonstrated the accuracy and validity of the time-dependent solution.

On the numerical solution of the Gross–Pitaevskii equation | Laoye ...

African Journals Online (AJOL)

The Gross–Pitaevskii equation is solved using an approach developed for the solution of the Bogoliubov–de Gennes equations for type II superconductivity. The solution is compared with others in the literature and is shown to be easily adapted to the study of an isolated vortex recently discovered in Bose-Einstein ...

Focus stacking: Comparing commercial top-end set-ups with a semi-automatic low budget approach. A possible solution for mass digitization of type specimens.

Science.gov (United States)

Brecko, Jonathan; Mathys, Aurore; Dekoninck, Wouter; Leponce, Maurice; VandenSpiegel, Didier; Semal, Patrick

2014-01-01

In this manuscript we present a focus stacking system, composed of commercial photographic equipment. The system is inexpensive compared to high-end commercial focus stacking solutions. We tested this system and compared the results with several different software packages (CombineZP, Auto-Montage, Helicon Focus and Zerene Stacker). We tested our final stacked picture with a picture obtained from two high-end focus stacking solutions: a Leica MZ16A with DFC500 and a Leica Z6APO with DFC290. Zerene Stacker and Helicon Focus both provided satisfactory results. However, Zerene Stacker gives the user more possibilities in terms of control of the software, batch processing and retouching. The outcome of the test on high-end solutions demonstrates that our approach performs better in several ways. The resolution of the tested extended focus pictures is much higher than those from the Leica systems. The flash lighting inside the Ikea closet creates an evenly illuminated picture, without struggling with filters, diffusers, etc. The largest benefit is the price of the set-up which is approximately € 3,000, which is 8 and 10 times less than the LeicaZ6APO and LeicaMZ16A set-up respectively. Overall, this enables institutions to purchase multiple solutions or to start digitising the type collection on a large scale even with a small budget.

Focus stacking: Comparing commercial top-end set-ups with a semi-automatic low budget approach. A possible solution for mass digitization of type specimens

Directory of Open Access Journals (Sweden)

Jonathan Brecko

2014-12-01

Full Text Available In this manuscript we present a focus stacking system, composed of commercial photographic equipment. The system is inexpensive compared to high-end commercial focus stacking solutions. We tested this system and compared the results with several different software packages (CombineZP, Auto-Montage, Helicon Focus and Zerene Stacker. We tested our final stacked picture with a picture obtained from two high-end focus stacking solutions: a Leica MZ16A with DFC500 and a Leica Z6APO with DFC290. Zerene Stacker and Helicon Focus both provided satisfactory results. However, Zerene Stacker gives the user more possibilities in terms of control of the software, batch processing and retouching. The outcome of the test on high-end solutions demonstrates that our approach performs better in several ways. The resolution of the tested extended focus pictures is much higher than those from the Leica systems. The flash lighting inside the Ikea closet creates an evenly illuminated picture, without struggling with filters, diffusers, etc. The largest benefit is the price of the set-up which is approximately € 3,000, which is 8 and 10 times less than the LeicaZ6APO and LeicaMZ16A set-up respectively. Overall, this enables institutions to purchase multiple solutions or to start digitising the type collection on a large scale even with a small budget.

Genus two finite gap solutions to the vector nonlinear Schroedinger equation

International Nuclear Information System (INIS)

Woodcock, Thomas; Warren, Oliver H; Elgin, John N

2007-01-01

A recently published article presents a technique used to derive explicit formulae for odd genus solutions to the vector nonlinear Schroedinger equation. In another article solutions of genus two are derived using a different approach which assumes a separable ansatz. In this communication, the extension of the first technique to the even genus case is discussed, and this extension is carried out explicitly for genus two. Furthermore, a birational mapping is found between the spectral curves that arise in the two approaches. (fast track communication)

Exact Solutions to the Double Travelling Salesman Problem with Multiple Stacks

DEFF Research Database (Denmark)

Petersen, Hanne L.; Archetti, Claudia; Speranza, M. Grazia

2010-01-01

In this paper we present mathematical programming formulations and solution approaches for the optimal solution of the Double Travelling Salesman Problem with Multiple Stacks (DTSPMS). A set of orders is given, each one requiring transportation of one item from a customer in a pickup region...

Steel corrosion resistance in model solutions and reinforced mortar containing wastes

NARCIS (Netherlands)

Koleva, D.A.; Van Breugel, K.

2012-01-01

This work reports on the corrosion resistance of steel in alkaline model solutions and in cement-based materials (mortar). The model solutions and the mortar specimens were Ordinary Portland Cement (OPC) based. Further, hereby discussed is the implementation of an eco-friendly approach of waste

Genetic algorithm and neural network hybrid approach for job-shop scheduling

OpenAIRE

Zhao, Kai; Yang, Shengxiang; Wang, Dingwei

1998-01-01

Copyright @ 1998 ACTA Press This paper proposes a genetic algorithm (GA) and constraint satisfaction adaptive neural network (CSANN) hybrid approach for job-shop scheduling problems. In the hybrid approach, GA is used to iterate for searching optimal solutions, CSANN is used to obtain feasible solutions during the iteration of genetic algorithm. Simulations have shown the valid performance of the proposed hybrid approach for job-shop scheduling with respect to the quality of solutions and ...

A class of exact solutions to the Einstein field equations

International Nuclear Information System (INIS)

Goyal, Nisha; Gupta, R K

2012-01-01

The Einstein-Rosen metric is considered and a class of new exact solutions of the field equations for stationary axisymmetric Einstein-Maxwell fields is obtained. The Lie classical approach is applied to obtain exact solutions. By using the Lie classical method, we are able to derive symmetries that are used for reducing the coupled system of partial differential equations into ordinary differential equations. From reduced differential equations we have derived some new exact solutions of Einstein-Maxwell equations. (paper)

Fluctuations around classical solutions for gauge theories in Lagrangian and Hamiltonian approach

International Nuclear Information System (INIS)

Miskovic, Olivera; Pons, Josep M

2006-01-01

We analyse the dynamics of gauge theories and constrained systems in general under small perturbations around a classical solution in both Lagrangian and Hamiltonian formalisms. We prove that a fluctuations theory, described by a quadratic Lagrangian, has the same constraint structure and number of physical degrees of freedom as the original non-perturbed theory, assuming the non-degenerate solution has been chosen. We show that the number of Noether gauge symmetries is the same in both theories, but that the gauge algebra in the fluctuations theory becomes Abelianized. We also show that the fluctuations theory inherits all functionally independent rigid symmetries from the original theory and that these symmetries are generated by linear or quadratic generators according to whether the original symmetry is preserved by the background or is broken by it. We illustrate these results with examples

The unified approach to integrable relativistic equations: Soliton solutions over non-vanishing backgrounds - 1

International Nuclear Information System (INIS)

Barashenkov, I.V.; Getmanov, B.S.; Kovtun, V.E.

1992-01-01

The scheme for unified description of integrable relativistic massive systems provides an inverse scattering formalism that covers universally all (1+1)- dimensional systems of this kind. In this work we construct the N-soliton solution (over an arbitrary background) for some generic system which is associated with the sl(2,C) case of the scheme and whose reductions include the complex sine-Gordon equation, the massive Thirring model and other equations, both in the Euclidean and Minkowski spaces. Thus the N-soliton solutions for all these systems emerge in a unified form differing only in the type of constraints imposed on their parameters. In an earlier paper the case of the zero background was considered while here we concentrate on the case of the non-vanishing constant background i.e., on the N-kink solutions. (author). 18 refs

Alternate Solution to Generalized Bernoulli Equations via an Integrating Factor: An Exact Differential Equation Approach

Science.gov (United States)

Tisdell, C. C.

2017-01-01

Solution methods to exact differential equations via integrating factors have a rich history dating back to Euler (1740) and the ideas enjoy applications to thermodynamics and electromagnetism. Recently, Azevedo and Valentino presented an analysis of the generalized Bernoulli equation, constructing a general solution by linearizing the problem…

Quantifying uncertainties on the solution model of seismic tomography; Quelle confiance accorder au modele solution de la tomographie de reflexion 3D?

Energy Technology Data Exchange (ETDEWEB)

Duffet, C.

2004-12-01

Reflection tomography allows the determination of a velocity model that fits the travel time data associated with reflections of seismic waves propagating in the subsurface. A least-square formulation is used to compare the observed travel times and the travel times computed by the forward operator based on a ray tracing. This non-linear optimization problem is solved classically by a Gauss-Newton method based on successive linearization of the forward operator. The obtained solution is only one among many possible models. Indeed, the uncertainties on the observed travel times (resulting from an interpretative event picking on seismic records) and more generally the under-determination of the inverse problem lead to uncertainties on the solution. An a posteriori uncertainty analysis is then crucial to delimit the range of possible solutions that fit, with the expected accuracy, the data and the a priori information. A linearized a posteriori analysis is possible by an analysis of the a posteriori covariance matrix, inverse of the Gauss-Newton approximation of the matrix. The computation of this matrix is generally expensive (the matrix is huge for 3D problems) and the physical interpretation of the results is difficult. Then we propose a formalism which allows to compute uncertainties on relevant geological quantities for a reduced computational time. Nevertheless, this approach is only valid in the vicinity of the solution model (linearized framework) and complex cases may require a non-linear approach. An experimental approach consists in solving the inverse problem under constraints to test different geological scenarios. (author)

An approach using centrifugation for the extraction of the soil solution and its usefulness in studies of radionuclide speciation in soils - Approach using centrifugation for extraction of soil solution and its study for uranium speciation

Energy Technology Data Exchange (ETDEWEB)

Medeiros, Adriana S. [CAPES Foundation, Ministry of Education of Brazil, 70040-020, Brasilia, Brazil, Proc.BEX 1958/13-5 (Brazil); Lozano, J.C.; Prieto, C. [Universidad de Salamanca, 37008, Salamanca (Spain); Blanco Rodriguez, P.; Vera Tome, F. [Universidad de Extremadura, 06006, Badajoz (Spain)

2014-07-01

The centrifugation technique is tested as a methodology for extraction of soil solution, for further characterization, in order to elucidate its contribution to the speciation of radionuclides, particularly uranium, in radioactively contaminated soils, as well as the determination of its availability for vegetation. Centrifugation of a previously saturated soil core provides the soil solution with a specific origin inside the soil sample. In such way that the different soil solution origin, associate to the effective pressure applied to the soil core, will reflect different distribution coefficients which affect the radionuclide availability definition. Speciation of radionuclides in the soil solution can be also conditioned by this water origin. The development of this methodology relating to technical challenges faces materials suitable for the centrifugation process, both in terms of mechanical properties and chemical inertness. This paper reports the preparation of ceramic pellets of perlite produced with the intention of replacing glass pellets, used inserts in support to soils coupled with centrifuges. The characterization of porosity and the test of its chemical inertness and mechanical strength to the centrifugation process have been performed. Porosity characterization is required to control the saturation gradient, which conditions the flow of water from the soil. Its mechanical adequacy was tested by subjecting the pellets to the centrifugation process and assessing its integrity end. Chemical inertia was measured by placing the tablets in aqueous solutions of known composition and then evaluating the presence or absence of elements in this solution, after on time of contact between them. (authors)

Mobility needs and wireless solutions

DEFF Research Database (Denmark)

Saugstrup, Dan; Henten, Anders

The main purpose of this report is to spell out a methodological approach to the analysis of user needs with respect to mobility. Furthermore, this methodological approach is used in an exemplary analysis of the relationship between user needs and technology solutions offered by different wireless...... technologies. The report is based on a research approach, emphasizing important aspects in relation to developing more user oriented mobile services and applications in a heterogeneous network environment. As a staring point, Scandinavian research within the field of social science concerning mobility...... is described and discussed. Furthermore different wireless technologies are briefly described and discussed in relation to possible transmission capacities and coverage areas. In addition to this, a preliminary framework regarding the implications of mobility on the use and development of mobile services...

Existence and uniqueness of solution for a system of equations of ...

African Journals Online (AJOL)

The existence and uniqueness of solution for a system of equations of microwave heating of biologic issue is discussed. Using the Green function approach we establish the existence and uniqueness of solution. Journal of the Nigerian Association of Mathematical Physics Vol. 8 2004: pp. 177-180 ...

Soliton and periodic solutions for higher order wave equations of KdV type (I)

International Nuclear Information System (INIS)

Khuri, S.A.

2005-01-01

The aim of the paper is twofold. First, a new ansaetze is introduced for the construction of exact solutions for higher order wave equations of KdV type (I). We show the existence of a class of discontinuous soliton solutions with infinite spikes. Second, the projective Riccati technique is implemented as an alternate approach for obtaining new exact solutions, solitary solutions, and periodic wave solutions

Application of soft- and hard-modelling approaches to resolution of kinetics of electron donor-acceptor complex formation of 2,3-dichloro-5,6-dicyano-1,4-benzoquinone with imipramine in different solutions

International Nuclear Information System (INIS)

Hasani, Masoumeh; Shariati-Rad, Masoud; Abdollahi, Hamid

2009-01-01

Kinetics of electron donor-acceptor (EDA) complex formation of imipramine and 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) was investigated spectrophotometrically in acetonitrile, 1,2-dichloroethane, and chloroform solutions using soft- and hard-modelling approaches. From the results of exploratory analysis of kinetic data and the spectral changes by soft-modelling approaches, evolving factor analysis (EFA) and orthogonal projection approach (OPA), a consecutive two-steps reaction with two intermediates was proposed for the process in acetonitrile and 1,2-dichloroethane media and one with a single intermediate in chloroform solution. Secondly, by applying, multivariate nonlinear least squares hard-modelling approach on the collected experimental kinetic data matrix, the nonlinear parameters (rate constants) as well as the linear parameters (spectral profiles) were obtained by fitting the collected experimental kinetic data matrix to the proposed model. Small values of standard deviation in the resulting parameters and sum of squares of the residuals (ssq) obtained showed the proper selection of the model. Furthermore, the values of lack of fit and percent of explained variance confirmed the correct identified models. Identification of the model with the aid of soft-modelling approaches followed by application of the hard-modelling approaches decreases significantly the rotational ambiguity associated with the obtained concentration and spectral profiles. Variations in the kinetic constants were in complete agreement with the model proposed and the solvent polarities

Application of soft- and hard-modelling approaches to resolution of kinetics of electron donor-acceptor complex formation of 2,3-dichloro-5,6-dicyano-1,4-benzoquinone with imipramine in different solutions

Energy Technology Data Exchange (ETDEWEB)

Hasani, Masoumeh [Faculty of Chemistry, Bu-Ali Sina University, Mahdieh, Hamedan, 65174 (Iran, Islamic Republic of)], E-mail: hasani@basu.ac.ir; Shariati-Rad, Masoud [Faculty of Chemistry, Bu-Ali Sina University, Mahdieh, Hamedan, 65174 (Iran, Islamic Republic of); Abdollahi, Hamid [Department of Chemistry, Institute for Advanced Studies in Basic Sciences, Zanjan (Iran, Islamic Republic of)

2009-03-23

Kinetics of electron donor-acceptor (EDA) complex formation of imipramine and 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) was investigated spectrophotometrically in acetonitrile, 1,2-dichloroethane, and chloroform solutions using soft- and hard-modelling approaches. From the results of exploratory analysis of kinetic data and the spectral changes by soft-modelling approaches, evolving factor analysis (EFA) and orthogonal projection approach (OPA), a consecutive two-steps reaction with two intermediates was proposed for the process in acetonitrile and 1,2-dichloroethane media and one with a single intermediate in chloroform solution. Secondly, by applying, multivariate nonlinear least squares hard-modelling approach on the collected experimental kinetic data matrix, the nonlinear parameters (rate constants) as well as the linear parameters (spectral profiles) were obtained by fitting the collected experimental kinetic data matrix to the proposed model. Small values of standard deviation in the resulting parameters and sum of squares of the residuals (ssq) obtained showed the proper selection of the model. Furthermore, the values of lack of fit and percent of explained variance confirmed the correct identified models. Identification of the model with the aid of soft-modelling approaches followed by application of the hard-modelling approaches decreases significantly the rotational ambiguity associated with the obtained concentration and spectral profiles. Variations in the kinetic constants were in complete agreement with the model proposed and the solvent polarities.

Multiobjective optimization of urban water resources: Moving toward more practical solutions

Science.gov (United States)

Mortazavi, Mohammad; Kuczera, George; Cui, Lijie

2012-03-01

The issue of drought security is of paramount importance for cities located in regions subject to severe prolonged droughts. The prospect of "running out of water" for an extended period would threaten the very existence of the city. Managing drought security for an urban water supply is a complex task involving trade-offs between conflicting objectives. In this paper a multiobjective optimization approach for urban water resource planning and operation is developed to overcome practically significant shortcomings identified in previous work. A case study based on the headworks system for Sydney (Australia) demonstrates the approach and highlights the potentially serious shortcomings of Pareto optimal solutions conditioned on short climate records, incomplete decision spaces, and constraints to which system response is sensitive. Where high levels of drought security are required, optimal solutions conditioned on short climate records are flawed. Our approach addresses drought security explicitly by identifying approximate optimal solutions in which the system does not "run dry" in severe droughts with expected return periods up to a nominated (typically large) value. In addition, it is shown that failure to optimize the full mix of interacting operational and infrastructure decisions and to explore the trade-offs associated with sensitive constraints can lead to significantly more costly solutions.

Statistically optimal estimation of Greenland Ice Sheet mass variations from GRACE monthly solutions using an improved mascon approach

Science.gov (United States)

Ran, J.; Ditmar, P.; Klees, R.; Farahani, H. H.

2018-03-01

We present an improved mascon approach to transform monthly spherical harmonic solutions based on GRACE satellite data into mass anomaly estimates in Greenland. The GRACE-based spherical harmonic coefficients are used to synthesize gravity anomalies at satellite altitude, which are then inverted into mass anomalies per mascon. The limited spectral content of the gravity anomalies is properly accounted for by applying a low-pass filter as part of the inversion procedure to make the functional model spectrally consistent with the data. The full error covariance matrices of the monthly GRACE solutions are properly propagated using the law of covariance propagation. Using numerical experiments, we demonstrate the importance of a proper data weighting and of the spectral consistency between functional model and data. The developed methodology is applied to process real GRACE level-2 data (CSR RL05). The obtained mass anomaly estimates are integrated over five drainage systems, as well as over entire Greenland. We find that the statistically optimal data weighting reduces random noise by 35-69%, depending on the drainage system. The obtained mass anomaly time-series are de-trended to eliminate the contribution of ice discharge and are compared with de-trended surface mass balance (SMB) time-series computed with the Regional Atmospheric Climate Model (RACMO 2.3). We show that when using a statistically optimal data weighting in GRACE data processing, the discrepancies between GRACE-based estimates of SMB and modelled SMB are reduced by 24-47%.

Data management for the internet of things: design primitives and solution.

Science.gov (United States)

Abu-Elkheir, Mervat; Hayajneh, Mohammad; Ali, Najah Abu

2013-11-14

The Internet of Things (IoT) is a networking paradigm where interconnected, smart objects continuously generate data and transmit it over the Internet. Much of the IoT initiatives are geared towards manufacturing low-cost and energy-efficient hardware for these objects, as well as the communication technologies that provide objects interconnectivity. However, the solutions to manage and utilize the massive volume of data produced by these objects are yet to mature. Traditional database management solutions fall short in satisfying the sophisticated application needs of an IoT network that has a truly global-scale. Current solutions for IoT data management address partial aspects of the IoT environment with special focus on sensor networks. In this paper, we survey the data management solutions that are proposed for IoT or subsystems of the IoT. We highlight the distinctive design primitives that we believe should be addressed in an IoT data management solution, and discuss how they are approached by the proposed solutions. We finally propose a data management framework for IoT that takes into consideration the discussed design elements and acts as a seed to a comprehensive IoT data management solution. The framework we propose adapts a federated, data- and sources-centric approach to link the diverse Things with their abundance of data to the potential applications and services that are envisioned for IoT.

An Effective Approach to Teaching Electrochemistry.

Science.gov (United States)

Birss, Viola I.; Truax, D. Rodney

1990-01-01

An approach which may be useful for teaching electrochemistry in freshman college chemistry courses is presented. Discussed are the potential problems with teaching this subject and solutions provided by this approach. (CW)

Solution-Focused Therapy: Strength-Based Counseling for Children with Social Phobia

Science.gov (United States)

George, Cindy M.

2008-01-01

Solution-focused therapy is proposed as an effective strength-based model for children with social phobia. Social phobia is described along with the etiology and prevailing treatment approaches. A case illustration demonstrates the application of solution-focused therapy with a child who experienced social phobia. Implications for counseling and…

Adsorption of Pb(II) ions from aqueous solution using lignin from ...

African Journals Online (AJOL)

The adsorption of lead(II) ions from aqueous solution onto alkali lignin extracted from Hagenia abyssinica was investigated by electrochemical methods. The effect of solution pH, lignin dosage and contact time were investigated at room temperature in a batch system. Adsorption equilibrium was approached within 80 min.

Cloud security - An approach with modern cryptographic solutions

OpenAIRE

Kostadinovska, Ivana

2016-01-01

The term “cloud computing” has been in the spotlights of IT specialists due to its potential of transforming computer industry. Unfortunately, there are still some challenges to be resolved and the security aspects in the cloud based computing environment remain at the core of interest. The goal of our work is to identify the main security issues of cloud computing and to present approaches to secure clouds. Our research also focuses on data and storage security layers. As a result, we f...

A Predictor-Corrector Approach for the Numerical Solution of Fractional Differential Equations

Science.gov (United States)

Diethelm, Kai; Ford, Neville J.; Freed, Alan D.; Gray, Hugh R. (Technical Monitor)

2002-01-01

We discuss an Adams-type predictor-corrector method for the numerical solution of fractional differential equations. The method may be used both for linear and for nonlinear problems, and it may be extended to multi-term equations (involving more than one differential operator) too.

From analytical solutions of solute transport equations to multidimensional time-domain random walk (TDRW) algorithms

Science.gov (United States)

Bodin, Jacques

2015-03-01

In this study, new multi-dimensional time-domain random walk (TDRW) algorithms are derived from approximate one-dimensional (1-D), two-dimensional (2-D), and three-dimensional (3-D) analytical solutions of the advection-dispersion equation and from exact 1-D, 2-D, and 3-D analytical solutions of the pure-diffusion equation. These algorithms enable the calculation of both the time required for a particle to travel a specified distance in a homogeneous medium and the mass recovery at the observation point, which may be incomplete due to 2-D or 3-D transverse dispersion or diffusion. The method is extended to heterogeneous media, represented as a piecewise collection of homogeneous media. The particle motion is then decomposed along a series of intermediate checkpoints located on the medium interface boundaries. The accuracy of the multi-dimensional TDRW method is verified against (i) exact analytical solutions of solute transport in homogeneous media and (ii) finite-difference simulations in a synthetic 2-D heterogeneous medium of simple geometry. The results demonstrate that the method is ideally suited to purely diffusive transport and to advection-dispersion transport problems dominated by advection. Conversely, the method is not recommended for highly dispersive transport problems because the accuracy of the advection-dispersion TDRW algorithms degrades rapidly for a low Péclet number, consistent with the accuracy limit of the approximate analytical solutions. The proposed approach provides a unified methodology for deriving multi-dimensional time-domain particle equations and may be applicable to other mathematical transport models, provided that appropriate analytical solutions are available.

Encapsulating peritoneal sclerosis in the era of a multi-disciplinary approach based on biocompatible solutions: the NEXT-PD study.

Science.gov (United States)

Nakayama, Masaaki; Miyazaki, Masanobu; Honda, Kazuho; Kasai, Kenji; Tomo, Tadashi; Nakamoto, Hidetomo; Kawanishi, Hideki

2014-01-01

Encapsulating peritoneal sclerosis (EPS) is a serious complication of peritoneal dialysis (PD). Over the past decade in Japan, a multidisciplinary approach has been adopted to minimize the incidence and improve outcomes of EPS. This strategy includes planned PD discontinuation for high-risk patients and the introduction of biocompatible solutions. This study examined the current clinical status of EPS in representative PD centers in Japan. Patients (n = 1,338) from 55 PD centers in Japan who were using neutral-pH solutions from the initiation of therapy (mean age, 62 years; median PD duration, 32 months; concomitant use of icodextrin, 35.2%; PD and hemodialysis combination therapy, 12.2%) were assessed every 6 months to ascertain the reasons for PD discontinuation and the development of EPS development. Outcomes were also recorded. The study period was from November 2008 to March 2012. There were 727 patients who discontinued PD, including 163 deaths. Among all causes of PD withdrawal except for death, planned PD discontinuation to avoid EPS was utilized in 58 cases (7.1% in total). The strategy was increasingly utilized in proportion to the duration of PD: 0.5% for patients undergoing PD for 8 years. Fourteen patients developed EPS (three cases after PD), which corresponded with an overall incidence of 1.0%. The incidence according to the duration of PD was 0.3% for PD 8 years. In terms of therapy, 11 patients were treated with prednisolone (PSL), and surgical enterolysis was utilized in two cases. Complete remission of abdominal symptoms was achieved in twelve patients (85.7%), and three died due to EPS (mortality rate of 21.4%). Use of the multidisciplinary approach described above reduces the risk of the development of EPS according to PD duration. In cases of de novo EPS cases in Japan, this strategy can also attenuate the clinical course of the condition. Copyright © 2014 International Society for Peritoneal Dialysis.

Solution Focused Financial Therapy: A Brief Report of a Pilot Study

Directory of Open Access Journals (Sweden)

Kristy L. Archuleta

2015-07-01

Full Text Available The financial counseling, financial planning, and financial therapy fields are hampered by a conceptual and empirical paucity of clinical and experimental evidence-based research. In an attempt to decrease this gap in the literature, a pilot study was developed to test the implementation of a solution-focused financial therapy client intervention approach, in which solution-focused therapy techniques were applied in a financial counseling setting. This paper reports findings from a clinical intervention study of college students (N = 8 who presented a variety of financial issues related to budgeting, investing, and debt repayment problems. Data were gathered prior to the start of treatment, after treatment ended, and three months later. Participants’ psychological well-being and financial behaviors improved, while financial distress decreased. The solution-focused financial therapy approach used is discussed.

New numerical method for solving the solute transport equation

International Nuclear Information System (INIS)

Ross, B.; Koplik, C.M.

1978-01-01

The solute transport equation can be solved numerically by approximating the water flow field by a network of stream tubes and using a Green's function solution within each stream tube. Compared to previous methods, this approach permits greater computational efficiency and easier representation of small discontinuities, and the results are easier to interpret physically. The method has been used to study hypothetical sites for disposal of high-level radioactive waste

A transformed path integral approach for solution of the Fokker-Planck equation

Science.gov (United States)

Subramaniam, Gnana M.; Vedula, Prakash

2017-10-01

A novel path integral (PI) based method for solution of the Fokker-Planck equation is presented. The proposed method, termed the transformed path integral (TPI) method, utilizes a new formulation for the underlying short-time propagator to perform the evolution of the probability density function (PDF) in a transformed computational domain where a more accurate representation of the PDF can be ensured. The new formulation, based on a dynamic transformation of the original state space with the statistics of the PDF as parameters, preserves the non-negativity of the PDF and incorporates short-time properties of the underlying stochastic process. New update equations for the state PDF in a transformed space and the parameters of the transformation (including mean and covariance) that better accommodate nonlinearities in drift and non-Gaussian behavior in distributions are proposed (based on properties of the SDE). Owing to the choice of transformation considered, the proposed method maps a fixed grid in transformed space to a dynamically adaptive grid in the original state space. The TPI method, in contrast to conventional methods such as Monte Carlo simulations and fixed grid approaches, is able to better represent the distributions (especially the tail information) and better address challenges in processes with large diffusion, large drift and large concentration of PDF. Additionally, in the proposed TPI method, error bounds on the probability in the computational domain can be obtained using the Chebyshev's inequality. The benefits of the TPI method over conventional methods are illustrated through simulations of linear and nonlinear drift processes in one-dimensional and multidimensional state spaces. The effects of spatial and temporal grid resolutions as well as that of the diffusion coefficient on the error in the PDF are also characterized.

Crossing-symmetric solutions to low equations

International Nuclear Information System (INIS)

McLeod, R.J.; Ernst, D.J.

1985-01-01

Crossing symmetric models of the pion-nucleon interaction in which crossing symmetry is kept to lowest order in msub(π)/msub(N) are investigated. Two iterative techniques are developed to solve the crossing-symmetric Low equation. The techniques are used to solve the original Chew-Low equations and their generalizations to include the coupling to the pion-production channels. Small changes are found in comparison with earlier results which used an iterative technique proposed by Chew and Low and which did not produce crossing-symmetric results. The iterative technique of Chew and Low is shown to fail because of its inability to produce zeroes in the amplitude at complex energies while physical solutions to the model require such zeroes. We also prove that, within the class of solutions such that phase shifts approach zero for infinite energy, the solution to the Low equation is unique. (orig.)

Approximated solutions to Born-Infeld dynamics

International Nuclear Information System (INIS)

Ferraro, Rafael; Nigro, Mauro

2016-01-01

The Born-Infeld equation in the plane is usefully captured in complex language. The general exact solution can be written as a combination of holomorphic and anti-holomorphic functions. However, this solution only expresses the potential in an implicit way. We rework the formulation to obtain the complex potential in an explicit way, by means of a perturbative procedure. We take care of the secular behavior common to this kind of approach, by resorting to a symmetry the equation has at the considered order of approximation. We apply the method to build approximated solutions to Born-Infeld electrodynamics. We solve for BI electromagnetic waves traveling in opposite directions. We study the propagation at interfaces, with the aim of searching for effects susceptible to experimental detection. In particular, we show that a reflected wave is produced when a wave is incident on a semi-space containing a magnetostatic field.

Approximated solutions to Born-Infeld dynamics

Energy Technology Data Exchange (ETDEWEB)

Ferraro, Rafael [Instituto de Astronomía y Física del Espacio (IAFE, CONICET-UBA),Casilla de Correo 67, Sucursal 28, 1428 Buenos Aires (Argentina); Departamento de Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires,Ciudad Universitaria, Pabellón I, 1428 Buenos Aires (Argentina); Nigro, Mauro [Departamento de Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires,Ciudad Universitaria, Pabellón I, 1428 Buenos Aires (Argentina)

2016-02-01

The Born-Infeld equation in the plane is usefully captured in complex language. The general exact solution can be written as a combination of holomorphic and anti-holomorphic functions. However, this solution only expresses the potential in an implicit way. We rework the formulation to obtain the complex potential in an explicit way, by means of a perturbative procedure. We take care of the secular behavior common to this kind of approach, by resorting to a symmetry the equation has at the considered order of approximation. We apply the method to build approximated solutions to Born-Infeld electrodynamics. We solve for BI electromagnetic waves traveling in opposite directions. We study the propagation at interfaces, with the aim of searching for effects susceptible to experimental detection. In particular, we show that a reflected wave is produced when a wave is incident on a semi-space containing a magnetostatic field.

Chain segmentation for the Monte Carlo solution of particle transport problems

International Nuclear Information System (INIS)

Ragheb, M.M.H.

1984-01-01

A Monte Carlo approach is proposed where the random walk chains generated in particle transport simulations are segmented. Forward and adjoint-mode estimators are then used in conjunction with the firstevent source density on the segmented chains to obtain multiple estimates of the individual terms of the Neumann series solution at each collision point. The solution is then constructed by summation of the series. The approach is compared to the exact analytical and to the Monte Carlo nonabsorption weighting method results for two representative slowing down and deep penetration problems. Application of the proposed approach leads to unbiased estimates for limited numbers of particle simulations and is useful in suppressing an effective bias problem observed in some cases of deep penetration particle transport problems

Solution based approaches for the morphology control of BaTiO3 particulates

Directory of Open Access Journals (Sweden)

Florentina Maxim

2010-09-01

Full Text Available Within the action COST 539 - ELENA our contribution was aimed at studying solution based approaches for the morphology control of BaTiO3 particulates. Initially, our kinetic analysis and systematic structural and morphological studies, demonstrated that during hydrothermal synthesis from layered titanate nanotubes (TiNTS, BaTiO3 forms via two mechanisms depending on the temperature and time. At low temperatures (90°C, “wild” type BaTiO3 dendritic particles with cubic structure were formed through a phase boundary topotactic reaction. At higher temperatures and/or for longer times time, the reaction is controlled by a dissolution precipitation mechanism and “seaweed” type BaTiO3 dendrites are formed. Our results unambiguously elucidated why TiNTs do not routinely act as templates for the formation of 1D BaTiO3.In our subsequent investigations, the effect of additives on the aqueous and hydrothermal synthesis of BaTiO3 was assessed. We reported that although the tested additives influenced the growth of BaTiO3, their behaviour varied; poly(acrylic acid (PAA adsorbed on specific crystallographic faces changing the growth kinetics and inducing the oriented attachment of the particles; poly(vinyl pyrrolidone (PVP, sodium dodecylsulfate (SDS and hydroxypropylmethylcellulose (HPMC act as growth inhibitors rather than crystal habit modifiers; and DFructose appeared to increase the activation energy for nucleation, resulting in small crystals (26 nm. Our work clearly indicates that the synthesis of 1D nanostructures of complex oxides by chemical methods is non trivial.

Existence criterion of spurious solutions of Faddeev equations

International Nuclear Information System (INIS)

Pupyshev, V.V.

1995-01-01

The Faddeev differential equations for a system of three different particles interacting via central two-body potentials are investigated within the hyperharmonics approach. A simple method for classification and construction of these solutions is proposed. 25 refs

A Collaborative Neurodynamic Approach to Multiple-Objective Distributed Optimization.

Science.gov (United States)

Yang, Shaofu; Liu, Qingshan; Wang, Jun

2018-04-01

This paper is concerned with multiple-objective distributed optimization. Based on objective weighting and decision space decomposition, a collaborative neurodynamic approach to multiobjective distributed optimization is presented. In the approach, a system of collaborative neural networks is developed to search for Pareto optimal solutions, where each neural network is associated with one objective function and given constraints. Sufficient conditions are derived for ascertaining the convergence to a Pareto optimal solution of the collaborative neurodynamic system. In addition, it is proved that each connected subsystem can generate a Pareto optimal solution when the communication topology is disconnected. Then, a switching-topology-based method is proposed to compute multiple Pareto optimal solutions for discretized approximation of Pareto front. Finally, simulation results are discussed to substantiate the performance of the collaborative neurodynamic approach. A portfolio selection application is also given.

Solution of two-dimensional equations of neutron transport in 4P0-approximation of spherical harmonics method

International Nuclear Information System (INIS)

Polivanskij, V.P.

1989-01-01

The method to solve two-dimensional equations of neutron transport using 4P 0 -approximation is presented. Previously such approach was efficiently used for the solution of one-dimensional problems. New an attempt is made to apply the approach to solution of two-dimensional problems. Algorithm of the solution is given, as well as results of test neutron-physical calculations. A considerable as compared with diffusion approximation is shown. 11 refs

Symmetry-breaking solutions of the Hubbard model

International Nuclear Information System (INIS)

Kuzemsky, A.L.; )

1998-10-01

The problem of finding the ferromagnetic and antiferromagnetic ''broken symmetry'' solutions of the correlated lattice fermion models beyond the mean-field approximation has been investigated. The calculation of the quasiparticle excitation spectrum with damping for the single- and multi-orbital Hubbard model has been performed in the framework of the equation-of-motion method for two-time temperature Green's Functions within a non-perturbative approach. A unified scheme for the construction of Generalised Mean Fields (elastic scattering corrections) and self-energy (inelastic scattering) in terms of Dyson equation has been generalised in order to include the presence of the ''source fields''. The damping of quasiparticles, which reflects the interaction of the single-particle and collective degrees of freedom has been calculated. The ''broken symmetry'' dynamical solutions of the Hubbard model, which correspond to various types of itinerant antiferromagnetism have been discussed. This approach complements previous studies and clarifies the nature of the concepts of itinerant antiferromagnetism and ''spin-aligning field'' of correlated lattice fermions. (author)

Exact solutions of the Fokker-Planck equation from an nth order supersymmetric quantum mechanics approach

Energy Technology Data Exchange (ETDEWEB)

Schulze-Halberg, Axel [Escuela Superior de Fisica y Matematicas, IPN, Unidad Profesional Adolfo Lopez Mateos, Col. San Pedro Zacatenco, Edificio 9, 07738 Mexico D.F. (Mexico)], E-mail: xbataxel@gmail.com; Rivas, Jesus Morales [Universidad Autonoma Metropolitana - Azcapotzalco, CBI - Area de Fisica Atomica Molecular Aplicada, Av. San Pablo 180, Reynosa Azcapotzalco, 02200 Mexico D.F. (Mexico)], E-mail: jmr@correo.azc.uam.mx; Pena Gil, Jose Juan [Universidad Autonoma Metropolitana - Azcapotzalco, CBI - Area de Fisica Atomica Molecular Aplicada, Av. San Pablo 180, Reynosa Azcapotzalco, 02200 Mexico D.F. (Mexico)], E-mail: jjpg@correo.azc.uam.mx; Garcia-Ravelo, Jesus [Escuela Superior de Fisica y Matematicas, IPN, Unidad Profesional Adolfo Lopez Mateos, Col. San Pedro Zacatenco, Edificio 9, 07738 Mexico D.F. (Mexico)], E-mail: ravelo@esfm.ipn.mx; Roy, Pinaki [Physics and Applied Mathematics Unit, Indian Statistical Institute, Calcutta-700108 (India)], E-mail: pinaki@isical.ac.in

2009-04-20

We generalize the formalism of nth order Supersymmetric Quantum Mechanics (n-SUSY) to the Fokker-Planck equation for constant diffusion coefficient and stationary drift potential. The SUSY partner drift potentials and the corresponding solutions of the Fokker-Planck equation are given explicitly. As an application, we generate new solutions of the Fokker-Planck equation by means of our first- and second-order transformation.

Exact solutions of the Fokker-Planck equation from an nth order supersymmetric quantum mechanics approach

International Nuclear Information System (INIS)

Schulze-Halberg, Axel; Rivas, Jesus Morales; Pena Gil, Jose Juan; Garcia-Ravelo, Jesus; Roy, Pinaki

2009-01-01

We generalize the formalism of nth order Supersymmetric Quantum Mechanics (n-SUSY) to the Fokker-Planck equation for constant diffusion coefficient and stationary drift potential. The SUSY partner drift potentials and the corresponding solutions of the Fokker-Planck equation are given explicitly. As an application, we generate new solutions of the Fokker-Planck equation by means of our first- and second-order transformation.

Prefabricated solution to modular construction in Cape Verde

Science.gov (United States)

Vieira, Nuno; Amado, Miguel; Pinho, Fernando

2017-02-01

Nowadays, the lack of adequate housing in Cape Verde is a growing problem. The migration of the population living in the countryside to the major cities generates an increase of the diameter of the cities. With the lack of economic power, the migrating families tend to occupy the land with houses which don't present proper conditions to living. Praia is the capital of Cape Verde and so on the biggest city of the country. This fact leads Praia to being the city with major economic power and job offer in all country. Consequently, Praia has developed the biggest slum of the Cape Verde and it is urgent to approach this problem in order to create solutions that reveal capacity to start solving it. Cape Verde's unique dry subtropical climate turns indispensable a careful resolution of the housing, in order to ensure the comfort of the occupants. The modular construction is a solution with potential to approach this problem with a fast and economic response. In order to answer the situation, this article introduces a modular solution in order to reach the needing of thermal comfort to the specific case of Praia.

Almost Periodic Solution for Memristive Neural Networks with Time-Varying Delays

Directory of Open Access Journals (Sweden)

Huaiqin Wu

2013-01-01

Full Text Available This paper is concerned with the dynamical stability analysis for almost periodic solution of memristive neural networks with time-varying delays. Under the framework of Filippov solutions, by applying the inequality analysis techniques, the existence and asymptotically almost periodic behavior of solutions are discussed. Based on the differential inclusions theory and Lyapunov functional approach, the stability issues of almost periodic solution are investigated, and a sufficient condition for the existence, uniqueness, and global exponential stability of the almost periodic solution is established. Moreover, as a special case, the condition which ensures the global exponential stability of a unique periodic solution is also presented for the considered memristive neural networks. Two examples are given to illustrate the validity of the theoretical results.

Some problems on non-linear semigroups and the blow-up of integral solutions

International Nuclear Information System (INIS)

Pavel, N.H.

1983-07-01

After some introductory remarks, this highly mathematical document considers a unifying approach in the theory of non-linear semigroups. Then a brief survey is given on blow-up of mild solutions from the semilinear case. Finally, the global behavior of solutions to non-linear evolution equations is addressed; it is found that classical results on the behavior of the maximal solution u as t up-arrow tsub(max) hold also for integral solutions

BKR 27(1) pp. 33-38 (Egwim et al)

African Journals Online (AJOL)

Femi J. Olorunniji

2015-03-31

Mar 31, 2015 ... polymers via simple sugars to biofuels like ethanol, butanol, or biodiesel, or to chemicals ... such as pyrolysis (thermolysis), chemical oxidation, hydrogenolysis ..... Review of Thermochemical Methods.Chem Engin Technol ...

Variable separation solutions for the Nizhnik-Novikov-Veselov equation via the extended tanh-function method

International Nuclear Information System (INIS)

Zhang Jiefang; Dai Chaoqing; Zong Fengde

2007-01-01

In this paper, with the variable separation approach and based on the general reduction theory, we successfully generalize this extended tanh-function method to obtain new types of variable separation solutions for the following Nizhnik-Novikov-Veselov (NNV) equation. Among the solutions, two solutions are new types of variable separation solutions, while the last solution is similar to the solution given by Darboux transformation in Hu et al 2003 Chin. Phys. Lett. 20 1413

Exact Solutions to the Double TSP with Multiple Stacks

DEFF Research Database (Denmark)

Petersen, Hanne Løhmann; Archetti, Claudia; Madsen, Oli B.G.

In the Double Travelling Salesman Problem with Multiple Stacks (DTSPMS) a set of orders is given, each one requiring transportation of one item from a customer in a pickup region to a customer in a delivery region. The vehicle available for the transportation in each region carries a container....... We present different modelling approaches to solving the DTSPMS to optimality and use the solutions obtained to evaluate the quality of previously obtained heuristic solutions....

Towards the general solution of the Yang-Mills equations

International Nuclear Information System (INIS)

Helfer, A.D.

1985-01-01

The author presents a new non-perturbative technique for finding arbitrary self-dual solutions to the Yang-Mills equations, and of describing massless fields minimally coupled to them. The approach uses techniques of complex analysis in several variables, and is complementary to Ward's: it is expected that a combination of the two techniques will yield general, non-self-dual solutions to the Yang-Mills equations. This has been verified to first order in perturbation theory

Data Management for the Internet of Things: Design Primitives and Solution

Science.gov (United States)

Abu-Elkheir, Mervat; Hayajneh, Mohammad; Ali, Najah Abu

2013-01-01

The Internet of Things (IoT) is a networking paradigm where interconnected, smart objects continuously generate data and transmit it over the Internet. Much of the IoT initiatives are geared towards manufacturing low-cost and energy-efficient hardware for these objects, as well as the communication technologies that provide objects interconnectivity. However, the solutions to manage and utilize the massive volume of data produced by these objects are yet to mature. Traditional database management solutions fall short in satisfying the sophisticated application needs of an IoT network that has a truly global-scale. Current solutions for IoT data management address partial aspects of the IoT environment with special focus on sensor networks. In this paper, we survey the data management solutions that are proposed for IoT or subsystems of the IoT. We highlight the distinctive design primitives that we believe should be addressed in an IoT data management solution, and discuss how they are approached by the proposed solutions. We finally propose a data management framework for IoT that takes into consideration the discussed design elements and acts as a seed to a comprehensive IoT data management solution. The framework we propose adapts a federated, data- and sources-centric approach to link the diverse Things with their abundance of data to the potential applications and services that are envisioned for IoT. PMID:24240599

Efficient Output Solution for Nonlinear Stochastic Optimal Control Problem with Model-Reality Differences

Directory of Open Access Journals (Sweden)

Sie Long Kek

2015-01-01

Full Text Available A computational approach is proposed for solving the discrete time nonlinear stochastic optimal control problem. Our aim is to obtain the optimal output solution of the original optimal control problem through solving the simplified model-based optimal control problem iteratively. In our approach, the adjusted parameters are introduced into the model used such that the differences between the real system and the model used can be computed. Particularly, system optimization and parameter estimation are integrated interactively. On the other hand, the output is measured from the real plant and is fed back into the parameter estimation problem to establish a matching scheme. During the calculation procedure, the iterative solution is updated in order to approximate the true optimal solution of the original optimal control problem despite model-reality differences. For illustration, a wastewater treatment problem is studied and the results show the efficiency of the approach proposed.

The Multi-Wave Method for Exact Solutions of Nonlinear Partial Differential Equations

Directory of Open Access Journals (Sweden)

Yusuf Pandir

2018-02-01

Full Text Available In this research, we use the multi-wave method to obtain new exact solutions for generalized forms of 5th order KdV equation and fth order KdV (fKdV equation with power law nonlinearity. Computations are performed with the help of the mathematics software Mathematica. Then, periodic wave solutions, bright soliton solutions and rational function solutions with free parameters are obtained by this approach. It is shown that this method is very useful and effective.

Tacit Knowledge Barriers in Franchising: Practical Solutions

Science.gov (United States)

Cumberland, Denise; Githens, Rod

2012-01-01

Purpose: The purpose of this paper is to identify barriers that hinder tacit knowledge transfer in a franchise environment and offer a compendium of solutions that encourage franchisees and franchisors to leverage tacit knowledge as a resource for competitive advantage. Design/methodology/approach: Drawing from the research on franchise…

An Optimum Solution for Electric Power Theft

Directory of Open Access Journals (Sweden)

Aamir Hussain Memon

2013-07-01

Full Text Available Electric power theft is a problem that continues to plague power sector across the whole country. Every year, the electricity companies face the line losses at an average 20-30% and according to power ministry estimation WAPDA companies lose more than Rs. 125 billion. Significantly, it is enough to destroy the entire power sector of country. According to sources 20% losses means the masses would have to pay extra 20% in terms of electricity tariffs. In other words, the innocent consumers pay the bills of those who steal electricity. For all that, no any permanent solution for this major issue has ever been proposed. We propose an applicable and optimum solution for this impassable problem. In our research, we propose an Electric power theft solution based on three stages; Transmission stage, Distribution stage, and User stage. Without synchronization among all, the complete solution can not be achieved. The proposed solution is simulated on NI (National Instruments Circuit Design Suite Multisim v.10.0. Our research work is an implicit and a workable approach towards the Electric power theft, as for conditions in Pakistan, which is bearing the brunt of power crises already

An Optimum Solution for Electric-Power Theft

International Nuclear Information System (INIS)

Memon, A.H.; Memon, F.

2013-01-01

Electric power theft is a problem that continues to plague power sector across the whole country. Every year, the electricity companies face the line losses at an average 20-30% and according to power ministry estimation WAPDA companies lose more than Rs. 125 billion. Significantly, it is enough to destroy the entire power sector of country. According to sources 20% losses means the masses would have to pay extra 20% in terms of electricity tariffs. In other words, the innocent consumers pay the bills of those who steal electricity. For all that, no any permanent solution for this major issue has ever been proposed. We propose an applicable and optimum solution for this impassable problem. In our research, we propose an Electric power theft solution based on three stages; Transmission stage, Distribution stage, and User stage. Without synchronization among all, the complete solution can not be achieved. The proposed solution is simulated on NI (National Instruments) Circuit Design Suite Multisim v.10.0. Our research work is an implicit and a workable approach towards the Electric power theft, as for conditions in Pakistan, which is bearing the brunt of power crises already. (author)

Predicting accurate absolute binding energies in aqueous solution

DEFF Research Database (Denmark)

Jensen, Jan Halborg

2015-01-01

Recent predictions of absolute binding free energies of host-guest complexes in aqueous solution using electronic structure theory have been encouraging for some systems, while other systems remain problematic. In this paper I summarize some of the many factors that could easily contribute 1-3 kcal......-represented by continuum models. While I focus on binding free energies in aqueous solution the approach also applies (with minor adjustments) to any free energy difference such as conformational or reaction free energy differences or activation free energies in any solvent....

Existence of Three Solutions for $p$-biharmonic Equation

Directory of Open Access Journals (Sweden)

Lin Li

2011-10-01

Full Text Available In this paper, the existence of at least three solutions to a Navier boundary problem involving the $p$-biharmonic equation, will be established. The technical approach is mainly based on the three critical points theorem of B. Ricceri.

Novel method for solution of coupled radial Schrödinger equations

International Nuclear Information System (INIS)

Ershov, S. N.; Vaagen, J. S.; Zhukov, M. V.

2011-01-01

One of the major problems in numerical solution of coupled differential equations is the maintenance of linear independence for different sets of solution vectors. A novel method for solution of radial Schrödinger equations is suggested. It consists of rearrangement of coupled equations in a way that is appropriate to avoid usual numerical instabilities associated with components of the wave function in their classically forbidden regions. Applications of the new method for nuclear structure calculations within the hyperspherical harmonics approach are given.

Water Evaporation from Acoustically Levitated Aqueous Solution Droplets.

Science.gov (United States)

Combe, Nicole A; Donaldson, D James

2017-09-28

We present a systematic study of the effect of solutes on the evaporation rate of acoustically levitated aqueous solution droplets by suspending individual droplets in a zero-relative humidity environment and measuring their size as a function of time. The ratios of the early time evaporation rates of six simple salts (NaCl, NaBr, NaNO 3 , KCl, MgCl 2 , CaCl 2 ) and malonic acid to that of water are in excellent agreement with predictions made by modifying the Maxwell equation to include the time-dependent water activity of the evaporating aqueous salt solution droplets. However, the early time evaporation rates of three ammonium salt solutions (NH 4 Cl, NH 4 NO 3 , (NH 4 ) 2 SO 4 ) are not significantly different from the evaporation rate of pure water. This finding is in accord with a previous report that ammonium sulfate does not depress the evaporation rate of its solutions, despite reducing its water vapor pressure, perhaps due to specific surface effects. At longer evaporation times, as the droplets approach crystallization, all but one (MgCl 2 ) of the solution evaporation rates are well described by the modified Maxwell equation.

Small-scale engagement model with arrivals: analytical solutions

International Nuclear Information System (INIS)

Engi, D.

1977-04-01

This report presents an analytical model of small-scale battles. The specific impetus for this effort was provided by a need to characterize hypothetical battles between guards at a nuclear facility and their potential adversaries. The solution procedure can be used to find measures of a number of critical parameters; for example, the win probabilities and the expected duration of the battle. Numerical solutions are obtainable if the total number of individual combatants on the opposing sides is less than 10. For smaller force size battles, with one or two combatants on each side, symbolic solutions can be found. The symbolic solutions express the output parameters abstractly in terms of symbolic representations of the input parameters while the numerical solutions are expressed as numerical values. The input parameters are derived from the probability distributions of the attrition and arrival processes. The solution procedure reduces to solving sets of linear equations that have been constructed from the input parameters. The approach presented in this report does not address the problems associated with measuring the inputs. Rather, this report attempts to establish a relatively simple structure within which small-scale battles can be studied

Different physical structures of solutions for two related Zakharov-Kuznetsov equations

International Nuclear Information System (INIS)

Lai Shaoyong; Yin Jun; Wu Yonghong

2008-01-01

The auxiliary differential equation approach and the symbolic computation system Maple are employed to investigate two types of related Zakharov-Kuznetsov equations with variable coefficients. The exact solutions to the equations are constructed analytically under certain circumstances. It is shown that the variable coefficients of the derivative terms of the equations result in their semi-travelling wave solutions

The orientation study activity: diagnosis and approach to a possible solution

Directory of Open Access Journals (Sweden)

Sergio Luís Alea García

2010-06-01

Full Text Available The orientation toward the study activity is one of the most important didactic functions that most be completed in the direction to the teaching-learning process, depending on it the efficien cy to complete the others. Professors assume extreme positions responding to theoretical traditional models and it generally goes parallelly to the development, which marks negatively the process and the results. Some of the causes were identified that are impacting in this problem; a possible solution is proposed and based.

Study and Thermogravimetric analysis of Poly N-4 Aminostyrol

International Nuclear Information System (INIS)

Meghezzi, A.; Lakhdar, Y.; Saidi, M.; Dadamoussa, B.

2006-01-01

The polyaminostyrol samples (PAS) and their copolymers with the styrol differing in position and quantity of amino-group, were obtained by polymerization of monomers on cyclogexan solution. The observed thermal effects were analyzed by the differential thermal analysis combined with a thermogravimetric analysis. It was found that the introduction of amino-groups into the polystyrols increased the temperature of total degradation of polymer from 150 till 260C. The increase in thermostability may be explained by the cohesion of macromolecules with the participation of amino-groups, which results in ammonium evolution, as well as in the decrease of valence area band of -NH2 grouping the region 3370-34440 cm. It was showed that the degree of cohesion formation and thermolysis rate depended on amino-group and their position into the cycle of benzene. (author)

TLC scheme for numerical solution of the transport equation on equilateral triangular meshes

International Nuclear Information System (INIS)

Walters, W.F.

1983-01-01

A new triangular linear characteristic TLC scheme for numerically solving the transport equation on equilateral triangular meshes has been developed. This scheme uses the analytic solution of the transport equation in the triangle as its basis. The data on edges of the triangle are assumed linear as is the source representation. A characteristic approach or nodal approach is used to obtain the analytic solution. Test problems indicate that the new TLC is superior to the widely used DITRI scheme for accuracy

Bessel collocation approach for approximate solutions of Hantavirus infection model

Directory of Open Access Journals (Sweden)

Suayip Yuzbasi

2017-11-01

Full Text Available In this study, a collocation method is introduced to find the approximate solutions of Hantavirus infection model which is a system of nonlinear ordinary differential equations. The method is based on the Bessel functions of the first kind, matrix operations and collocation points. This method converts Hantavirus infection model into a matrix equation in terms of the Bessel functions of first kind, matrix operations and collocation points. The matrix equation corresponds to a system of nonlinear equations with the unknown Bessel coefficients. The reliability and efficiency of the suggested scheme are demonstrated by numerical applications and all numerical calculations have been done by using a program written in Maple.

Practical solutions for multi-objective optimization: An application to system reliability design problems

International Nuclear Information System (INIS)

Taboada, Heidi A.; Baheranwala, Fatema; Coit, David W.; Wattanapongsakorn, Naruemon

2007-01-01

For multiple-objective optimization problems, a common solution methodology is to determine a Pareto optimal set. Unfortunately, these sets are often large and can become difficult to comprehend and consider. Two methods are presented as practical approaches to reduce the size of the Pareto optimal set for multiple-objective system reliability design problems. The first method is a pseudo-ranking scheme that helps the decision maker select solutions that reflect his/her objective function priorities. In the second approach, we used data mining clustering techniques to group the data by using the k-means algorithm to find clusters of similar solutions. This provides the decision maker with just k general solutions to choose from. With this second method, from the clustered Pareto optimal set, we attempted to find solutions which are likely to be more relevant to the decision maker. These are solutions where a small improvement in one objective would lead to a large deterioration in at least one other objective. To demonstrate how these methods work, the well-known redundancy allocation problem was solved as a multiple objective problem by using the NSGA genetic algorithm to initially find the Pareto optimal solutions, and then, the two proposed methods are applied to prune the Pareto set

Electronic Excitations in Solution: The Interplay between State Specific Approaches and a Time-Dependent Density Functional Theory Description.

Science.gov (United States)

Guido, Ciro A; Jacquemin, Denis; Adamo, Carlo; Mennucci, Benedetta

2015-12-08

We critically analyze the performances of continuum solvation models when coupled to time-dependent density functional theory (TD-DFT) to predict solvent effects on both absorption and emission energies of chromophores in solution. Different polarization schemes of the polarizable continuum model (PCM), such as linear response (LR) and three different state specific (SS) approaches, are considered and compared. We show the necessity of introducing a SS model in cases where large electron density rearrangements are involved in the excitations, such as charge-transfer transitions in both twisted and quadrupolar compounds, and underline the very delicate interplay between the selected polarization method and the chosen exchange-correlation functional. This interplay originates in the different descriptions of the transition and ground/excited state multipolar moments by the different functionals. As a result, the choice of both the DFT functional and the solvent polarization scheme has to be consistent with the nature of the studied electronic excitation.

On the solution of nonconvex cardinality Boolean quadratic programming problems: a computational study

KAUST Repository

Lima, Ricardo

2016-06-16

This paper addresses the solution of a cardinality Boolean quadratic programming problem using three different approaches. The first transforms the original problem into six mixed-integer linear programming (MILP) formulations. The second approach takes one of the MILP formulations and relies on the specific features of an MILP solver, namely using starting incumbents, polishing, and callbacks. The last involves the direct solution of the original problem by solvers that can accomodate the nonlinear combinatorial problem. Particular emphasis is placed on the definition of the MILP reformulations and their comparison with the other approaches. The results indicate that the data of the problem has a strong influence on the performance of the different approaches, and that there are clear-cut approaches that are better for some instances of the data. A detailed analysis of the results is made to identify the most effective approaches for specific instances of the data. © 2016 Springer Science+Business Media New York

On the solution of nonconvex cardinality Boolean quadratic programming problems: a computational study

KAUST Repository

Lima, Ricardo; Grossmann, Ignacio E.

2016-01-01

This paper addresses the solution of a cardinality Boolean quadratic programming problem using three different approaches. The first transforms the original problem into six mixed-integer linear programming (MILP) formulations. The second approach takes one of the MILP formulations and relies on the specific features of an MILP solver, namely using starting incumbents, polishing, and callbacks. The last involves the direct solution of the original problem by solvers that can accomodate the nonlinear combinatorial problem. Particular emphasis is placed on the definition of the MILP reformulations and their comparison with the other approaches. The results indicate that the data of the problem has a strong influence on the performance of the different approaches, and that there are clear-cut approaches that are better for some instances of the data. A detailed analysis of the results is made to identify the most effective approaches for specific instances of the data. © 2016 Springer Science+Business Media New York

Towards the description of the phase behavior of electrolyte solutions in slit-like pores. Density functional approach for the restricted primitive model

Directory of Open Access Journals (Sweden)

O.Pizio

2004-01-01

Full Text Available We develop a density functional approach for the phase behavior of the restricted primitive model for electrolyte solutions confined to slit-like pores. The theory permits to evaluate the effects of confinement on the ionic vapor - ionic liquid coexistence envelope. We have shown that due to confinement in pores with uncharged walls the critical temperature of the model decreases compared to the bulk. Also the coexistence envelope of the transition is narrower in comparison to the bulk model. The transition between dense and dilute phase represents capillary evaporation. We have analyzed changes of the density profiles of ions during transition. Possible extensions of this study are discussed.

Hyporheic less-mobile porosity and solute transport in porous media

Science.gov (United States)

MahmoodPoorDehkordy, F.; Briggs, M. A.; Day-Lewis, F. D.; Scruggs, C.; Singha, K.; Zarnetske, J. P.; Lane, J. W., Jr.; Bagtzoglou, A. C.

2017-12-01

Solute transport and reactive processes are strongly influenced by hydrodynamic exchange with the hyporheic zone. Contaminant transport and redox zonation in the hyporheic zone and near-stream aquifer can be impacted by the exchange between mobile and less-mobile porosity zones in heterogeneous porous media. Less-mobile porosity zones can be created by fine materials with tight pore throats (e.g. clay, organics) and in larger, well-connected pores down gradient of flow obstructions (e.g. sand behind cobbles). Whereas fluid sampling is primarily responsive to the more-mobile domain, tracking solute tracer dynamics by geoelectrical methods provides direct information about both more- and less-mobile zones. During tracer injection through porous media of varied pore connectivity, a lag between fluid and bulk electrical conductivity is observed, creating a hysteresis loop when plotted in conductivity space. Thus, the combination of simultaneous fluid and bulk electrical conductivity measurements enables a much improved quantification of less-mobile solute dynamics compared to traditional fluid-only sampling approaches. We have demonstrated the less-mobile porosity exchange in laboratory-scale column experiments verified by simulation models. The experimental approach has also been applied to streambed sediments in column and reach-scale field experiments and verified using numerical simulation. Properties of the resultant hysteresis loops can be used to estimate exchange parameters of less-mobile porosity. Our integrated approach combining field experiments, laboratory experiments, and numerical modeling provides new insights into the effect of less-mobile porosity on solute transport in the hyporheic zone.

Existence of periodic solutions for Rayleigh equations with state-dependent delay

Directory of Open Access Journals (Sweden)

Jehad O. Alzabut

2012-05-01

Full Text Available We establish sufficient conditions for the existence of periodic solutions for a Rayleigh-type equation with state-dependent delay. Our approach is based on the continuation theorem in degree theory, and some analysis techniques. An example illustrates that our approach to this problem is new.

Combination of graph heuristics in producing initial solution of curriculum based course timetabling problem

Science.gov (United States)

Wahid, Juliana; Hussin, Naimah Mohd

2016-08-01

The construction of population of initial solution is a crucial task in population-based metaheuristic approach for solving curriculum-based university course timetabling problem because it can affect the convergence speed and also the quality of the final solution. This paper presents an exploration on combination of graph heuristics in construction approach in curriculum based course timetabling problem to produce a population of initial solutions. The graph heuristics were set as single and combination of two heuristics. In addition, several ways of assigning courses into room and timeslot are implemented. All settings of heuristics are then tested on the same curriculum based course timetabling problem instances and are compared with each other in terms of number of population produced. The result shows that combination of saturation degree followed by largest degree heuristic produce the highest number of population of initial solutions. The results from this study can be used in the improvement phase of algorithm that uses population of initial solutions.

The relation among the hyperbolic-function-type exact solutions of nonlinear evolution equations

International Nuclear Information System (INIS)

Liu Chunping; Liu Xiaoping

2004-01-01

First, we investigate the solitary wave solutions of the Burgers equation and the KdV equation, which are obtained by using the hyperbolic function method. Then we present a theorem which will not only give us a clear relation among the hyperbolic-function-type exact solutions of nonlinear evolution equations, but also provide us an approach to construct new exact solutions in complex scalar field. Finally, we apply the theorem to the KdV-Burgers equation and obtain its new exact solutions

Numerical Solution of Nonlinear Fredholm Integro-Differential Equations Using Spectral Homotopy Analysis Method

Directory of Open Access Journals (Sweden)

Z. Pashazadeh Atabakan

2013-01-01

Full Text Available Spectral homotopy analysis method (SHAM as a modification of homotopy analysis method (HAM is applied to obtain solution of high-order nonlinear Fredholm integro-differential problems. The existence and uniqueness of the solution and convergence of the proposed method are proved. Some examples are given to approve the efficiency and the accuracy of the proposed method. The SHAM results show that the proposed approach is quite reasonable when compared to homotopy analysis method, Lagrange interpolation solutions, and exact solutions.

Comparison: Mediation Solutions of WSMOLX and WebML/WebRatio

Science.gov (United States)

Zaremba, Maciej; Zaharia, Raluca; Turati, Andrea; Brambilla, Marco; Vitvar, Tomas; Ceri, Stefano

In this chapter we compare the WSMO/WSML/WSMX andWebML/WebRatio approaches to the SWS-Challenge workshop mediation scenario in terms of the utilized underlying technologies and delivered solutions. In the mediation scenario one partner uses Roset-taNet to define its B2B protocol while the other one operates on a proprietary solution. Both teams shown how these partners could be semantically integrated.

Non-classical solutions of a continuum model for rock descriptions

Directory of Open Access Journals (Sweden)

Mikhail A. Guzev

2014-06-01

Full Text Available The strain-gradient and non-Euclidean continuum theories are employed for construction of non-classical solutions of continuum models. The linear approximation of both models' results in identical structures in terms of their kinematic and stress characteristics. The solutions obtained in this study exhibit a critical behaviour with respect to the external loading parameter. The conclusions are obtained based on an investigation of the solution for the scalar curvature in the non-Euclidean continuum theory. The proposed analysis enables us to use different theoretical approaches for description of rock critical behaviour under different loading conditions.

An Agent Based Modelling Approach for Multi-Stakeholder Analysis of City Logistics Solutions

NARCIS (Netherlands)

Anand, N.

2015-01-01

This thesis presents a comprehensive framework for multi-stakeholder analysis of city logistics solutions using agent based modeling. The framework describes different stages for the systematic development of an agent based model for the city logistics domain. The framework includes a

From Goods to Solutions

DEFF Research Database (Denmark)

Chakkol, Mehmet; Johnson, Mark; Raja, Jawwad

2014-01-01

Purpose – This paper aims to adopt service-dominant logic (SDL) to empirically explore network configurations resulting from the provision of goods, goods and services, and solutions. Design/methodology/approach – This paper uses a single, in-depth, exploratory case study in a truck manufacturer......: dyadic, triadic and tetradic. The extent to which different network actors contribute to value co-creation varies across the offerings. Research limitations/implications – This paper is based on a single, in-depth case study developed in one industrial context. Whilst this represents an appropriate...

Synthesis, thermolysis and pyrolysis of group IV metal pinacolates: The impact of a vicinal diol as a supporting ligand for molecular precursors

Science.gov (United States)

Zechmann, Cecilia A.

In an effort to investigate the suitability of an alternative ligand class for molecular precursors, the following studies were carried out: (1) New zirconium species were obtained by reaction of zirconium isopropoxide alcoholate, Zr2(OiPr)8(HOiPr) 2, with pinacol (HOCMe2CMe2OH). Control of reaction stoichiometries followed by azeotropic distillation of evolved isopropanol led to the successful preparation of a range of homo- and heteroleptic trinuclear species, Zr3(OCMe2CMe2O)2(O iPr)8(HOiPr)2, Zr3(OCMe 2CMe2O)4(OCMe2CMe2OH) 2(OiPr)2, and Zr3(OCMe2CMe 2O)4(OCMe2CMe2OH)4. Dinuclear products could be obtained by carrying out the reactions at room temperature or by addition of excess pinacol (in which case Zr2(OCMe2 CMe2O)2(OCMe2CMe2OH) 4 was the product). (2) Similar reactions between Ti(Oi Pr)4 and pinacol gave dinuclear products under all conditions. Both homo- (Ti2(OiPr)2(OCMe2CMe 2O)2(OCMe2CMe2OH)2) and heterometallic complexes (Ti2(OCMe2CMe2O) 2(OCMe2CMe2OH)4) were characterized. (3) Controlled addition of water to either of the isolated titanium pinacolates gave Ti3(mu3-O)(OCMe2CMe2O) 4(OCMe2CMe2OH)2. (4) Reaction of zirconium pinacolates with water led to the isolation of Zr4(mu 2-O)(OCMe2CMe2O)4(OCMe2CMe 2OH)6 and Zr6(mu3-O)4(H 2O)2(OCMe2CMe2O)5(OCMe 2CMe2OH)5. 17O NMR studies aided in the investigation of active equilibria and reversibility of hydrolysis. (5) The thermolysis of Zr2(OCMe2CMe2O) 2(OCMe2CMe2OH)4 gave ZrO2 in a mixture of crystalline phases. GC-MS and NMR analysis of the volatiles revealed 4 C6 products as well as two ligand coupled products. Isotope-labeling studies were carried out to probe the mechanisms by which the organic products were formed. (6) Reaction of Zr2(OCMe 2CMe2O)2(OCMe2CMe2OH) 4 with Ti(OiPr)4 gives (OiPr) 2TiZr2(OCMe2CMe2O)4(OCMe 2CMe2OH)2 which reacts with a second equivalent of Ti(OiPr)4 to give (OiPr) 4Ti2Zr2(OCMe2CMe2O) 6. (7) Reaction of Li{N(SiMe3)2}·Et 2O or Na{N(SiMe3)2}·x THF with Zr2(OCMe2CMe2O)2(OCMe 2CMe2OH)4

Covariant solutions of the Bethe-Salpeter equation

International Nuclear Information System (INIS)

Williams, A.G.; Kusaka, K.; Simpson, K.M.

1997-01-01

There is a need for covariant solutions of bound state equations in order to construct realistic QCD based models of mesons and baryons. Furthermore, we ideally need to know the structure of these bound states in all kinematical regimes, which makes a direct solution in Minkowski space (without any 3-dimensional reductions) desirable. The Bethe-Salpeter equation (BSE) for bound states in scalar theories is reformulated and solved for arbitrary scattering kernels in terms of a generalized spectral representation directly in Minkowski space. This differs from the conventional Euclidean approach, where the BSE can only be solved in ladder approximation after a Wick rotation. (author)

A simple approach to nonlinear oscillators

International Nuclear Information System (INIS)

Ren Zhongfu; He Jihuan

2009-01-01

A very simple and effective approach to nonlinear oscillators is suggested. Anyone with basic knowledge of advanced calculus can apply the method to finding approximately the amplitude-frequency relationship of a nonlinear oscillator. Some examples are given to illustrate its extremely simple solution procedure and an acceptable accuracy of the obtained solutions.

A compartmentalized solute transport model for redox zones in contaminated aquifers: 1. Theory and development

Science.gov (United States)

Abrams , Robert H.; Loague, Keith

2000-01-01

This paper, the first of two parts [see Abrams and Loague, this issue], takes the compartmentalized approach for the geochemical evolution of redox zones presented by Abrams et al. [1998] and embeds it within a solute transport framework. In this paper the compartmentalized approach is generalized to facilitate the description of its incorporation into a solute transport simulator. An equivalent formulation is developed which removes any discontinuities that may occur when switching compartments. Rate‐limited redox reactions are modeled with a modified Monod relationship that allows either the organic substrate or the electron acceptor to be the rate‐limiting reactant. Thermodynamic constraints are used to inhibit lower‐energy redox reactions from occurring under infeasible geochemical conditions without imposing equilibrium on the lower‐energy reactions. The procedure used allows any redox reaction to be simulated as being kinetically limited or thermodynamically limited, depending on local geochemical conditions. Empirical reaction inhibition methods are not needed. The sequential iteration approach (SIA), a technique which allows the number of solute transport equations to be reduced, is adopted to solve the coupled geochemical/solute transport problem. When the compartmentalized approach is embedded within the SIA, with the total analytical concentration of each component as the dependent variable in the transport equation, it is possible to reduce the number of transport equations even further than with the unmodified SIA. A one‐dimensional, coupled geochemical/solute transport simulation is presented in which redox zones evolve dynamically in time and space. The compartmentalized solute transport (COMPTRAN) model described in this paper enables the development of redox zones to be simulated under both kinetic and thermodynamic constraints. The modular design of COMPTRAN facilitates the use of many different, preexisting solute transport and

The risk-based approach to anti-money laundering: problems and solutions

DEFF Research Database (Denmark)

Simonova, Anna

2011-01-01

Purpose – The purpose of this paper, which is a part of a PhD thesis, is to detect problems associated with the risk-based approach to anti-money laundering (AML), as well as present ways to improve the risk-based approach. Design/methodology/approach – The method is law and economics. The Ph......D thesis itself is also based on a comparative analysis of the Danish and British AML regimes. Findings – The main findings are: failure to develop adequate risk-based AML systems, taking into account varying levels of money laundering risk, is not only to be considered in the context of legal risk...... but also and more importantly in the context of integrity risk; anti-money laundering (AML) has to be made part of financial and non-financial institutions' corporate social responsibility policies; the Risk Analysis Manual provided by the Central Bank of The Netherlands lists very specific...

New Exact Travelling Wave and Periodic Solutions of Discrete Nonlinear Schroedinger Equation

International Nuclear Information System (INIS)

Yang Qin; Dai Chaoqing; Zhang Jiefang

2005-01-01

Some new exact travelling wave and period solutions of discrete nonlinear Schroedinger equation are found by using a hyperbolic tangent function approach, which was usually presented to find exact travelling wave solutions of certain nonlinear partial differential models. Now we can further extend the new algorithm to other nonlinear differential-different models.

Recent Advances of Solution-Processed Metal Oxide Thin-Film Transistors.

Science.gov (United States)

Xu, Wangying; Li, Hao; Xu, Jian-Bin; Wang, Lei

2018-03-06

Solution-processed metal oxide thin-film transistors (TFTs) are considered as one of the most promising transistor technologies for future large-area flexible electronics. This review surveys the recent advances in solution-based oxide TFTs, including n-type oxide semiconductors, oxide dielectrics and p-type oxide semiconductors. Firstly, we provide an introduction on oxide TFTs and the TFT configurations and operating principles. Secondly, we present the recent progress in solution-processed n-type transistors, with a special focus on low-temperature and large-area solution processed approaches as well as novel non-display applications. Thirdly, we give a detailed analysis of the state-of-the-art solution-processed oxide dielectrics for low-voltage electronics. Fourthly, we discuss the recent progress in solution-based p-type oxide semiconductors, which will enable the highly desirable future low-cost large-area complementary circuits. Finally, we draw the conclusions and outline the perspectives over the research field.

Shock-jump conditions in a general medium: weak-solution approach

Science.gov (United States)

Forbes, L. K.; Krzysik, O. A.

2017-05-01

General conservation laws are considered, and the concept of a weak solution is extended to the case of an equation involving three space variables and time. Four-dimensional vector calculus is used to develop general jump conditions at a shock wave in the material. To illustrate the use of this result, jump conditions at a shock in unsteady three-dimensional compressible gas flow are presented. It is then proved rigorously that these reduce to the commonly assumed conditions in coordinates normal and tangential to the shock face. A similar calculation is also outlined for an unsteady three-dimensional shock in magnetohydrodynamics, and in a chemically reactive fluid. The technique is available for determining shock-jump conditions in quite general continuous media.

Recovery of Ionic Liquids from aqueous solution by Nanofiltration

OpenAIRE

Fernández Dámaso, José Francisco

2011-01-01

The T-SAR methodology was combined with membrane characterization methods. An application of the combined approach was demonstrated with two commercial nanofiltration membranes and it was possible to successfully predict their performance for the recovery of ionic liquids from aqueous solution. Using model solutions of Pyr16 (CF3SO2)2N, it could be evidenced the formation of a new phase of ionic liquid during the concentration process. In this case, 66% of the ionic liquid was separated and t...

Performance improvement for solution-processed high-mobility ZnO thin-film transistors

International Nuclear Information System (INIS)

Li Chensha; Loutfy, Rafik O; Li Yuning; Wu Yiliang; Ong, Beng S

2008-01-01

The fabrication technology of stable, non-toxic, transparent, high performance zinc oxide (ZnO) thin-film semiconductors via the solution process was investigated. Two methods, which were, respectively, annealing a spin-coated precursor solution and annealing a drop-coated precursor solution, were compared. The prepared ZnO thin-film semiconductor transistors have well-controlled, preferential crystal orientation and exhibit superior field-effect performance characteristics. But the ZnO thin-film transistor (TFT) fabricated by annealing a drop-coated precursor solution has a distinctly elevated linear mobility, which further approaches the saturated mobility, compared with that fabricated by annealing a spin-coated precursor solution. The performance of the solution-processed ZnO TFT was further improved when substituting the spin-coating process by the drop-coating process

Performance improvement for solution-processed high-mobility ZnO thin-film transistors

Energy Technology Data Exchange (ETDEWEB)

Li Chensha; Loutfy, Rafik O [Department of Chemical Engineering, McMaster University, 1280 Main Street West, Hamilton, Ontario L8S 4L7 (Canada); Li Yuning; Wu Yiliang; Ong, Beng S [Materials Design and Integration Laboratory, Xerox Research Centre of Canada, 2660 Speakman Drive, Mississauga, Ontario L5K 2L1 (Canada)], E-mail: lichnsa@163.com

2008-06-21

The fabrication technology of stable, non-toxic, transparent, high performance zinc oxide (ZnO) thin-film semiconductors via the solution process was investigated. Two methods, which were, respectively, annealing a spin-coated precursor solution and annealing a drop-coated precursor solution, were compared. The prepared ZnO thin-film semiconductor transistors have well-controlled, preferential crystal orientation and exhibit superior field-effect performance characteristics. But the ZnO thin-film transistor (TFT) fabricated by annealing a drop-coated precursor solution has a distinctly elevated linear mobility, which further approaches the saturated mobility, compared with that fabricated by annealing a spin-coated precursor solution. The performance of the solution-processed ZnO TFT was further improved when substituting the spin-coating process by the drop-coating process.

Leadership during Crisis: Threat Identifcation and Solution Proposal

Directory of Open Access Journals (Sweden)

Lukáš Mazánek

2016-01-01

Full Text Available Purpose of the article: In the current dynamic market environment, companies are vulnerable to many problems of different character, which could result into a real business crisis. The submitted study summarizes possible approaches to leading through crisis situation. Therefore proposal of solutions which tools leader could use during crisis was made. Purpose of this study is to create theoretical background for the future research, in the field of application right leadership concept during crisis. Methodology/methods: For the purpose of the illustration possible threats which can lead to a business crisis was chosen the Ishikawa diagram. Next up review of scientific publication focused on leadership during crisis was made. With emphasis especially on research studies published in last 10 years in the Leadership Quarterly Journal. These results was precisely analyzed and then the most useful informations synthesized into proposed solutions. Scientific aim: The aim of this study, is to identify possible threats which could be a source of corporate crises. Subsequently propose solutions within the competence of corporate leader, how to prevent those threats or lower the intensity of crisis which already occur Findings: Proposed solutions was found in the field of HR leadership, crisis communication, leader´s behavior connected with leadership style used during crisis and increasing effectivity of leading crisis team. The application of mentioned approaches, contribute to preparedness on the possible negative future development and reduce the intensity of crisis, which has already af-fected the corporation. Conclusions: The contribution of this study is creation of synoptic overview of corporate threats and proposal of corresponding solutions of those. The implication is to summarize results from previous empirical studies to create enough theoretic foundation for the future research.

Studies on the influence of metallurgical variables on the stress corrosion behavior of AISI 304 stainless steel in sodium chloride solution using the fracture mechanics approach

International Nuclear Information System (INIS)

Khatak, H.S.; Gnanamoorthy, J.B.; Rodriguez, P.

1996-01-01

Stress corrosion data on a nuclear grade AISI type 304 stainless steel in a boiling solution of 5M NaCl + 0.15M Na 2 SO 4 + 3 mL/L HCl (bp 381 K) for various metallurgical conditions of the steel are presented in this article. The metallurgical conditions used are solution annealing, sensitization, 10 pct cold work, 20 pct cold work, solution annealing + sensitization, 10 pct cold work + sensitization, and 20 pct cold work + sensitization. The fracture mechanics approach has been used to obtain quantitative data on the stress corrosion crack growth rates. The stress intensity factor, K I , and J integral, J I , have been used as evaluation parameters. The crack growth rates have been measured using compact tension type samples under both increasing and decreasing stress intensity factors. A crack growth rate of 5 x 10 -11 m/s was chosen for the determination of threshold parameters. Results of the optical microscopic and fractographic examinations are presented. Acoustic signals were recorded during crack growth. Data generated from acoustic emissions, activation energy measurements, and fractographic features indicate hydrogen embrittlement as the possible mechanism of cracking

Algebraic dynamics solutions and algebraic dynamics algorithm for nonlinear partial differential evolution equations of dynamical systems

Institute of Scientific and Technical Information of China (English)

2008-01-01

Using functional derivative technique in quantum field theory, the algebraic dy-namics approach for solution of ordinary differential evolution equations was gen-eralized to treat partial differential evolution equations. The partial differential evo-lution equations were lifted to the corresponding functional partial differential equations in functional space by introducing the time translation operator. The functional partial differential evolution equations were solved by algebraic dynam-ics. The algebraic dynamics solutions are analytical in Taylor series in terms of both initial functions and time. Based on the exact analytical solutions, a new nu-merical algorithm—algebraic dynamics algorithm was proposed for partial differ-ential evolution equations. The difficulty of and the way out for the algorithm were discussed. The application of the approach to and computer numerical experi-ments on the nonlinear Burgers equation and meteorological advection equation indicate that the algebraic dynamics approach and algebraic dynamics algorithm are effective to the solution of nonlinear partial differential evolution equations both analytically and numerically.

Pareto Efficient Solutions of Attack-Defence Trees

DEFF Research Database (Denmark)

Aslanyan, Zaruhi; Nielson, Flemming

2015-01-01

Attack-defence trees are a promising approach for representing threat scenarios and possible countermeasures in a concise and intuitive manner. An attack-defence tree describes the interaction between an attacker and a defender, and is evaluated by assigning parameters to the nodes, such as proba......Attack-defence trees are a promising approach for representing threat scenarios and possible countermeasures in a concise and intuitive manner. An attack-defence tree describes the interaction between an attacker and a defender, and is evaluated by assigning parameters to the nodes......, such as probability or cost of attacks and defences. In case of multiple parameters most analytical methods optimise one parameter at a time, e.g., minimise cost or maximise probability of an attack. Such methods may lead to sub-optimal solutions when optimising conflicting parameters, e.g., minimising cost while...... maximising probability. In order to tackle this challenge, we devise automated techniques that optimise all parameters at once. Moreover, in the case of conflicting parameters our techniques compute the set of all optimal solutions, defined in terms of Pareto efficiency. The developments are carried out...

Turbulence effects on volatilization rates of liquids and solutes.

Science.gov (United States)

Lee, Jiunn-Fwu; Chao, Huan-Ping; Chiou, Cary T; Manes, Milton

2004-08-15

Volatilization rates of neat liquids (benzene, toluene, fluorobenzene, bromobenzene, ethylbenzene, m-xylene, o-xylene, o-dichlorobenzene, and 1-methylnaphthalene) and of solutes (phenol, m-cresol, benzene, toluene, ethylbenzene, o-xylene, and ethylene dibromide) from dilute water solutions have been measured in the laboratory over a wide range of air speeds and water-stirring rates. The overall transfer coefficients (K(L)) for individual solutes are independent of whether they are in single- or multi-solute solutions. The gas-film transfer coefficients (kG) for solutes in the two-film model, which have hitherto been estimated by extrapolation from reference coefficients, can now be determined directly from the volatilization rates of neat liquids through a new algorithm. The associated liquid-film transfer coefficients (kL) can then be obtained from measured K(L) and kG values and solute Henry law constants (H). This approach provides a novel means for checking the precision of any kL and kG estimation methods for ultimate prediction of K(L). The improved kG estimation enables accurate K(L) predictions for low-volatility (i.e., low-H) solutes where K(L) and kGH are essentially equal. In addition, the prediction of K(L) values for high-volatility (i.e., high-H) solutes, where K(L) approximately equal to kL, is also improved by using appropriate reference kL values.

Turbulence effects on volatilization rates of liquids and solutes

Science.gov (United States)

Lee, J.-F.; Chao, H.-P.; Chiou, C.T.; Manes, M.

2004-01-01

Volatilization rates of neat liquids (benzene, toluene, fluorobenzene, bromobenzene, ethylbenzene, m-xylene, o-xylene, o-dichlorobenzene, and 1-methylnaphthalene) and of solutes (phenol, m-cresol, benzene, toluene, ethylbenzene, o-xylene, and ethylene dibromide) from dilute water solutions have been measured in the laboratory over a wide range of air speeds and water-stirring rates. The overall transfer coefficients (KL) for individual solutes are independent of whether they are in single- or multi-solute solutions. The gas-film transfer coefficients (kG) for solutes in the two-film model, which have hitherto been estimated by extrapolation from reference coefficients, can now be determined directly from the volatilization rates of neatliquids through anew algorithm. The associated liquid-film transfer coefficients (KL) can then be obtained from measured KL and kG values and solute Henry law constants (H). This approach provides a novel means for checking the precision of any kL and kG estimation methods for ultimate prediction of KL. The improved kG estimation enables accurate K L predictions for low-volatility (i.e., low-H) solutes where K L and kGH are essentially equal. In addition, the prediction of KL values for high-volatility (i.e., high-H) solutes, where KL ??? kL, is also improved by using appropriate reference kL values.

Patients' expectations and solutions for improving primary diabetes care.

Science.gov (United States)

Vachon, Brigitte; Huynh, Ai-Thuy; Breton, Mylaine; Quesnel, Louise; Camirand, Michel; Leblanc, Jeannette; Tardif, Sylvie

2017-07-10

Purpose The purpose of this paper is to document health care needs expressed by people living with diabetes, describe the solutions they envisaged for improving the quality of primary care (PC) services and empower them to make better use of PC services. Design/methodology/approach A participatory research approach was used. Six workshops were organised to provide diabetes patients with knowledge on available services and to engage them in sharing their experience. Group discussions were recorded. Data were analysed using the thematic analysis method. Findings In total, 79 persons living with diabetes for a mean of 13 years participated. Needs expressed were grouped under seven themes: assurance of satisfactory follow-up by a family physician, continuous access to services adapted to evolving needs, motivation to adopt and maintain healthy behaviours, maintenance of knowledge about diabetes, psychological support, financial constraints, and collaboration with secondary-level services. Patients proposed solutions for improving services that were grouped under five themes: facilitating access to services, disseminating information about available services, centralising diabetes information on the internet, offering personalised services and improving interprofessional collaboration. Practical implications Needs expressed by diabetic patients concern different aspects of care such as accessibility, organisation, coordination, and better dissemination and visibility of services. The solutions proposed by patients focussed on better access to information and interprofessional services. Originality/value The workshop format used in this study offers an original and interesting approach and tool for actively engaging patients in quality improvement of services.

Approximate Solution of Dam-break Flow of Low Viscosity Bingham Fluid

Science.gov (United States)

Puay, How Tion; Hosoda, Takashi

In this study, we investigate the characteristics of dam-break flow of low viscosity Bingham fluid by deriving an approximate solution for the time development of the front position and depth at the origin of the flow. The asymptotic solutions representing the characteristic of Bingham fluid in the limit of low plastic viscosity are verified with a depth-averaged numerical model. Numerical simulations showed that with the decrease of plastic viscosity, the time development of the front position and depth at the origin approach to the theoretical asymptotic solution.

An efficient finite element solution for gear dynamics

International Nuclear Information System (INIS)

Cooley, C G; Parker, R G; Vijayakar, S M

2010-01-01

A finite element formulation for the dynamic response of gear pairs is proposed. Following an established approach in lumped parameter gear dynamic models, the static solution is used as the excitation in a frequency domain solution of the finite element vibration model. The nonlinear finite element/contact mechanics formulation provides accurate calculation of the static solution and average mesh stiffness that are used in the dynamic simulation. The frequency domain finite element calculation of dynamic response compares well with numerically integrated (time domain) finite element dynamic results and previously published experimental results. Simulation time with the proposed formulation is two orders of magnitude lower than numerically integrated dynamic results. This formulation admits system level dynamic gearbox response, which may include multiple gear meshes, flexible shafts, rolling element bearings, housing structures, and other deformable components.

Claims and Identity: On-Premise and Cloud Solutions

Science.gov (United States)

Bertocci, Vittorio

Today's identity-management practices are often a patchwork of partial solutions, which somehow accommodate but never really integrate applications and entities separated by technology and organizational boundaries. The rise of Software as a Service (SaaS) and cloud computing, however, will force organizations to cross such boundaries so often that ad hoc solutions will simply be untenable. A new approach that tears down identity silos and supports a de-perimiterized IT by design is in order.This article will walk you through the principles of claims-based identity management, a model which addresses both traditional and cloud scenarios with the same efficacy. We will explore the most common token exchange patterns, highlighting the advantages and opportunities they offer when applied on cloud computing solutions and generic distributed systems.

Epitaxial solution deposition of YBa2Cu3O7-6 coated conductors.

Energy Technology Data Exchange (ETDEWEB)

Overmyer, Donald L.; Clem, Paul Gilbert; Siegal, Michael P.; Holesinger, Terry A. (Los Alamos National Laboratory, Los Alamos, NM); Voigt, James A.; Richardson, Jacob J.; Dawley, Jeffrey Todd

2004-11-01

A variety of solution deposition routes have been reported for processing complex perovskite-based materials such as ferroelectric oxides and conductive electrode oxides, due to ease of incorporating multiple elements, control of chemical stoichiometry, and feasibility for large area deposition. Here, we report an extension of these methods toward long length, epitaxial film solution deposition routes to enable biaxially oriented YBa{sub 2}Cu{sub 3}O{sub 7-{delta}} (YBCO)-coated conductors for superconducting transmission wires. Recent results are presented detailing an all-solution deposition approach to YBCO-coated conductors with critical current densities J{sub c} (77 K) > 1 MA/cm{sup 2} on rolling-assisted, biaxially textured, (200)-oriented Ni-W alloy tapes. Solution-deposition methods such as this approach and those of other research groups appear to have promise to compete with vapor phase methods for superconductor electrical properties, with potential advantages for large area deposition and low cost/kA {center_dot} m of wire.

Special function solutions of a spectral problem for a nonlinear quantum oscillator

International Nuclear Information System (INIS)

Schulze-Halberg, A; Morris, J R

2012-01-01

We construct exact solutions of a spectral problem involving the Schrödinger equation for a nonlinear, one-parameter oscillator potential. In contrast to a previous analysis of the problem (Carinena et al 2007 Ann. Phys. 322 434–59), where solutions were given through a Rodrigues-type formula, our approach leads to closed-form representations of the solutions in terms of special functions, not containing any derivative operators. We show normalizability and orthogonality of our solutions, as well as correct reduction of the problem to the harmonic oscillator model, if the parameter in the potential gets close to zero. (paper)

A Method for Generating Approximate Similarity Solutions of Nonlinear Partial Differential Equations

Directory of Open Access Journals (Sweden)

Mazhar Iqbal

2014-01-01

Full Text Available Standard application of similarity method to find solutions of PDEs mostly results in reduction to ODEs which are not easily integrable in terms of elementary or tabulated functions. Such situations usually demand solving reduced ODEs numerically. However, there are no systematic procedures available to utilize these numerical solutions of reduced ODE to obtain the solution of original PDE. A practical and tractable approach is proposed to deal with such situations and is applied to obtain approximate similarity solutions to different cases of an initial-boundary value problem of unsteady gas flow through a semi-infinite porous medium.

Meta-Heuristics for Dynamic Lot Sizing: a review and comparison of solution approaches

NARCIS (Netherlands)

R.F. Jans (Raf); Z. Degraeve (Zeger)

2004-01-01

textabstractProofs from complexity theory as well as computational experiments indicate that most lot sizing problems are hard to solve. Because these problems are so difficult, various solution techniques have been proposed to solve them. In the past decade, meta-heuristics such as tabu search,

Model-based dispersive wave processing: A recursive Bayesian solution

International Nuclear Information System (INIS)

Candy, J.V.; Chambers, D.H.

1999-01-01

Wave propagation through dispersive media represents a significant problem in many acoustic applications, especially in ocean acoustics, seismology, and nondestructive evaluation. In this paper we propose a propagation model that can easily represent many classes of dispersive waves and proceed to develop the model-based solution to the wave processing problem. It is shown that the underlying wave system is nonlinear and time-variable requiring a recursive processor. Thus the general solution to the model-based dispersive wave enhancement problem is developed using a Bayesian maximum a posteriori (MAP) approach and shown to lead to the recursive, nonlinear extended Kalman filter (EKF) processor. The problem of internal wave estimation is cast within this framework. The specific processor is developed and applied to data synthesized by a sophisticated simulator demonstrating the feasibility of this approach. copyright 1999 Acoustical Society of America.

Inverse Kinematics With Closed Form Solution For Denso Robot Manipulator

OpenAIRE

Ikhsan Eka Prasetia; Trihastuti Agustinah

2015-01-01

In this paper, the forward kinematics and inverse kinematics used on the Denso robot manipulator which has a 6-DOF. The forward kinematics will result in the desired position by end-effector, while inverse kinematics produce angel on each joint. Inverse kinematics problem are very difficult, therefor to obtain the solution of inverse kinematics using closed form solution with geometry approach. The simulation result obtained from forward kinematics and inverse kinematics is determining desire...

Severe service sealing solutions

International Nuclear Information System (INIS)

Metcalfe, R.; Wensel, R.

1994-09-01

Successful sealing usually requires much more than initial leak-tightness. Friction and wear must also be acceptable, requiring a good understanding of tribology at the sealing interface. This paper describes various sealing solutions for severe service conditions. The CAN2A and CAN8 rotary face seals use tungsten carbide against carbon-graphite to achieve low leakage and long lifetime in nuclear main coolant pumps. The smaller CAN6 seal successfully uses tungsten carbide against silicon carbide in reactor water cleanup pump service. Where friction in CANDU fuelling machine rams must be essentially zero, a hydrostatic seal using two silicon carbide faces is the solution. In the NRU reactor moderator pumps, where pressure is much lower, eccentric seals that prevent boiling at the seal faces are giving excellent service. All these rotary face seals rely on supplementary elastomer seals between their parts. An integrated engineering approach to high performance sealing with O-rings is described. This is epitomized in critical Space Shuttle applications, but is increasingly being applied in CANDU plants. It includes gland design, selection and qualification of material, quality assurance, detection of defects and the effects of lubrication, surface finish, squeeze, stretch and volume constraints. In conclusion, for the severe service applications described, customized solutions have more than paid for themselves by higher reliability, lower maintenance requirements and reduced outage time. (author)

IPTV inter-destination synchronization: A network-based approach

NARCIS (Netherlands)

Stokking, H.M.; Deventer, M.O. van; Niamut, O.A.; Walraven, F.A.; Mekuria, R.N.

2010-01-01

This paper introduces a novel network-based approach to inter-destination media synchronization. The approach meets the need for synchronization in advanced TV concepts like social TV and offers high scalability, unlike conventional end-point based approaches. The solution for interdestination media

Bogolyubov renormalization group and symmetry of solution in mathematical physics

International Nuclear Information System (INIS)

Shirkov, D.V.; Kovalev, V.F.

2000-01-01

Evolution of the concept known in the theoretical physics as the Renormalization Group (RG) is presented. The corresponding symmetry, that has been first introduced in QFT in mid-fifties, is a continuous symmetry of a solution with respect to transformation involving parameters (e.g., of boundary condition) specifying some particular solution. After short detour into Wilson's discrete semi-group, we follow the expansion of QFT RG and argue that the underlying transformation, being considered as a reparametrization one, is closely related to the self-similarity property. It can be treated as its generalization, the Functional Self-similarity (FS). Then, we review the essential progress during the last decade of the FS concept in application to boundary value problem formulated in terms of differential equations. A summary of a regular approach recently devised for discovering the RG = FS symmetries with the help of the modern Lie group analysis and some of its applications are given. As a main physical illustration, we give application of a new approach to solution for a problem of self-focusing laser beam in a nonlinear medium

Teaching Thermodynamics of Ideal Solutions: An Entropy-Based Approach to Help Students Better Understand and Appreciate the Subtleties of Solution Models

Science.gov (United States)

Tomba, J. Pablo

2015-01-01

The thermodynamic formalism of ideal solutions is developed in most of the textbooks postulating a form for the chemical potential of a generic component, which is adapted from the thermodynamics of ideal gas mixtures. From this basis, the rest of useful thermodynamic properties can be derived straightforwardly without further hypothesis. Although…

Analytic Solution to Shell Boundary – Value Problems

Directory of Open Access Journals (Sweden)

Yu. I. Vinogradov

2015-01-01

Full Text Available Object of research is to find analytical solution to the shell boundary – value problems, i.e. to consider the solution for a class of problems concerning the mechanics of hoop closed shells strain.The objective of work is to create an analytical method to define a stress – strain state of shells under non-axisymmetric loading. Thus, a main goal is to derive the formulas – solutions of the linear ordinary differential equations with variable continuous coefficients.The partial derivative differential equations of mechanics of shells strain by Fourier's method of variables division are reduced to the system of the differential equations with ordinary derivatives. The paper presents the obtained formulas to define solutions of the uniform differential equations and received on their basis formulas to define a particular solution depending on a type of the right parts of the differential equations.The analytical algorithm of the solution of a boundary task uses an approach to transfer the boundary conditions to the randomly chosen point of an interval of changing independent variable through the solution of the canonical matrix ordinary differential equation with the subsequent solution of system of algebraic equations for compatibility of boundary conditions at this point. Efficiency of algorithm is based on the fact that the solution of the ordinary differential equations is defined as the values of Cauchy – Krylova functions, which meet initial arbitrary conditions.The results of researches presented in work are useful to experts in the field of calculus mathematics, dealing with solution of systems of linear ordinary differential equations and creation of effective analytical computing methods to solve shell boundary – value problems.

Definition and use of Solution-focused Sustainability Assessment: A novel approach to generate, explore and decide on sustainable solutions for wicked problems

NARCIS (Netherlands)

Zijp, M.C.; Posthuma, L.; Wintersen, A.; Devilee, J.; Swartjes, F.A.

2016-01-01

This paper introduces Solution-focused Sustainability Assessment (SfSA), provides practical guidance formatted as a versatile process framework, and illustrates its utility for solving a wicked environmental management problem. Society faces complex and increasingly wicked environmental problems for

An approximate and an analytical solution to the carousel-pendulum problem

Energy Technology Data Exchange (ETDEWEB)

Vial, Alexandre [Pole Physique, Mecanique, Materiaux et Nanotechnologies, Universite de technologie de Troyes, 12, rue Marie Curie BP-2060, F-10010 Troyes Cedex (France)], E-mail: alexandre.vial@utt.fr

2009-09-15

We show that an improved solution to the carousel-pendulum problem can be easily obtained through a first-order Taylor expansion, and its accuracy is determined after the obtention of an unusable analytical exact solution, advantageously replaced by a numerical one. It is shown that the accuracy is unexpectedly high, even when the ratio length of the pendulum to carousel radius approaches unity. (letters and comments)

Non-autonomous equations with unpredictable solutions

Science.gov (United States)

Akhmet, Marat; Fen, Mehmet Onur

2018-06-01

To make research of chaos more amenable to investigating differential and discrete equations, we introduce the concepts of an unpredictable function and sequence. The topology of uniform convergence on compact sets is applied to define unpredictable functions [1,2]. The unpredictable sequence is defined as a specific unpredictable function on the set of integers. The definitions are convenient to be verified as solutions of differential and discrete equations. The topology is metrizable and easy for applications with integral operators. To demonstrate the effectiveness of the approach, the existence and uniqueness of the unpredictable solution for a delay differential equation are proved as well as for quasilinear discrete systems. As a corollary of the theorem, a similar assertion for a quasilinear ordinary differential equation is formulated. The results are demonstrated numerically, and an application to Hopfield neural networks is provided. In particular, Poincaré chaos near periodic orbits is observed. The completed research contributes to the theory of chaos as well as to the theory of differential and discrete equations, considering unpredictable solutions.

On the use of the Lie group technique for differential equations with a small parameter: Approximate solutions and integrable equations

International Nuclear Information System (INIS)

Burde, G.I.

2002-01-01

A new approach to the use of the Lie group technique for partial and ordinary differential equations dependent on a small parameter is developed. In addition to determining approximate solutions to the perturbed equation, the approach allows constructing integrable equations that have solutions with (partially) prescribed features. Examples of application of the approach to partial differential equations are given

KONSEP BIMBINGAN DAN KONSELING ISLAM SOLUTION FOCUSED BRIEF THERAPY (SFBT UNTUK MEMBANTU MENYEMBUHKAN PERILAKU PROKRASTINASI MAHASISWA

Directory of Open Access Journals (Sweden)

FRENDI FERNANDO

2016-07-01

Full Text Available This article describes about concept of Islamic guidance and counseling through SFBT (Solution Focused Brief Therapy approach to review helps cure procrastination student behavior. SFBT is a form of brief therapy that builds on the strengths of the counselee to help raise and construct a solution to the problem. The concept of guidance and counseling Islam through SFBT approach is a comprehensive approach so that more leverage in helping cure procrastination behavior. Procrastination is the tendency of delaying completion of a task or work related academic activities. Islamic SFBT its essence lies in the counseling phase focused on solutions rather than on problems so counselee more energy is used to find a solution. There are stages of intervention in the form of a question miracle (miracle question, the counselee is directed to find the magic solution that comes from Allah Swt. That with Allah, nothing is impossible if people want to try. Wisdom and the role of Allah Swt always "presented" to engage in the process of this therapy. Intervention practices covering Islamic SFBT; Changes in pre-session; Search exception; Search competence; Miracle questions; The use of scale (scaling; Reframing; and closure of the session.

Biorthogonal Systems Approximating the Solution of the Nonlinear Volterra Integro-Differential Equation

Directory of Open Access Journals (Sweden)

Berenguer MI

2010-01-01

Full Text Available This paper deals with obtaining a numerical method in order to approximate the solution of the nonlinear Volterra integro-differential equation. We define, following a fixed-point approach, a sequence of functions which approximate the solution of this type of equation, due to some properties of certain biorthogonal systems for the Banach spaces and .

Embedded class solutions compatible for physical compact stars in general relativity

Science.gov (United States)

Newton Singh, Ksh.; Pant, Neeraj; Tewari, Neeraj; Aria, Anil K.

2018-05-01

We have explored a family of new solutions satisfying Einstein's field equations and Karmarkar condition. We have assumed an anisotropic stress-tensor with no net electric charge. Interestingly, the new solutions yield zero values of all the physical quantities for all even integer n > 0. However, for all n >0 (n ≠ even numbers) they yield physically possible solutions. We have tuned the solution for neutron star Vela X-1 so that the solutions matches the observed mass and radius. For the same star we have extensively discussed the behavior of the solutions. The solutions yield a stiffer equation of state for larger values of n since the adiabatic index increases and speed of sound approaches the speed of light. It is also found that the solution is physically possible for Vela X-1 if 1.8 ≤ n < 7 (with n≠ 2,4,6). All the solutions for n ≥ 7 violates the causality condition and all the solutions with 0 < n < 1.8 lead to complex values of transverse sound speed vt. The range of well-behaved n depends on the mass and radius of compact stars.

Chemical solution deposition of YBCO thin film by different polymer additives

International Nuclear Information System (INIS)

Wang, W.T.; Li, G.; Pu, M.H.; Sun, R.P.; Zhou, H.M.; Zhang, Y.; Zhang, H.; Yang, Y.; Cheng, C.H.; Zhao, Y.

2008-01-01

A polymer-assisted chemical solution deposition approach has been proposed for the preparation of YBCO thin film. Different additives like PVB (polyvinyl butyral), PEG (polyethylene glycol) and PVP (polyvinylpyrrolidone) have been used to adjust the final viscosity of the precursor solution and thus the film formation. In this fluorine-free approach, YBCO has been deposited on single crystal substrates with metal acetates being starting materials. Biaxially textured YBCO thin films have been obtained. However, different additives lead to different microstructure. Dense, smooth and crack-free YBCO film prepared with PVB as additive yields sharp superconducting transition around T c = 90 K as well as high J c (0 T, 77 K) over 3 MA/cm 2

Remarks on the Taub-NUT solution in Chern–Simons modified gravity

Energy Technology Data Exchange (ETDEWEB)

Brihaye, Yves, E-mail: yves.brihaye@umons.ac.be [Physique-Mathématique, Universite de Mons-Hainaut, Mons (Belgium); Radu, Eugen [Departamento de Física da Universidade de Aveiro and CIDMA, Campus de Santiago, 3810-183 Aveiro (Portugal)

2017-01-10

We discuss the generalization of the NUT spacetime in General Relativity (GR) within the framework of the (dynamical) Einstein–Chern–Simons (ECS) theory with a massless scalar field. These configurations approach asymptotically the NUT spacetime and are characterized by the ‘electric’ and ‘magnetic’ mass parameters and a scalar ‘charge’. The solutions are found both analytically and numerically. The analytical approach is perturbative around the Einstein gravity background. Our results indicate that the ECS configurations share all basic properties of the NUT spacetime in GR. However, when considering the solutions inside the event horizon, we find that in contrast to the GR case, the spacetime curvature grows (apparently) without bound.

Chemical solution deposition of YBCO thin film by different polymer additives

Energy Technology Data Exchange (ETDEWEB)

Wang, W.T.; Li, G.; Pu, M.H.; Sun, R.P.; Zhou, H.M.; Zhang, Y. [Key Laboratory of Magnetic Levitation Technologies and Maglev Trains, Ministry of Education of China, Superconductivity R and D Center (SRDC), Mail Stop 165, Southwest Jiaotong University, Chengdu 610031 (China); Zhang, H. [Department of Physics, Peking University, Beijing 100871 (China); Yang, Y. [Key Laboratory of Magnetic Levitation Technologies and Maglev Trains, Ministry of Education of China, Superconductivity R and D Center (SRDC), Mail Stop 165, Southwest Jiaotong University, Chengdu 610031 (China); Cheng, C.H. [Key Laboratory of Magnetic Levitation Technologies and Maglev Trains, Ministry of Education of China, Superconductivity R and D Center (SRDC), Mail Stop 165, Southwest Jiaotong University, Chengdu 610031 (China); School of Materials Science and Engineering, University of New South Wale, Sydney, 2052 NSW (Australia); Zhao, Y. [Key Laboratory of Magnetic Levitation Technologies and Maglev Trains, Ministry of Education of China, Superconductivity R and D Center (SRDC), Mail Stop 165, Southwest Jiaotong University, Chengdu 610031 (China); School of Materials Science and Engineering, University of New South Wale, Sydney, 2052 NSW (Australia)], E-mail: yzhao@swjtu.edu.cn

2008-09-15

A polymer-assisted chemical solution deposition approach has been proposed for the preparation of YBCO thin film. Different additives like PVB (polyvinyl butyral), PEG (polyethylene glycol) and PVP (polyvinylpyrrolidone) have been used to adjust the final viscosity of the precursor solution and thus the film formation. In this fluorine-free approach, YBCO has been deposited on single crystal substrates with metal acetates being starting materials. Biaxially textured YBCO thin films have been obtained. However, different additives lead to different microstructure. Dense, smooth and crack-free YBCO film prepared with PVB as additive yields sharp superconducting transition around T{sub c} = 90 K as well as high J{sub c} (0 T, 77 K) over 3 MA/cm{sup 2}.

Improved pedagogy for linear differential equations by reconsidering how we measure the size of solutions

Science.gov (United States)

Tisdell, Christopher C.

2017-11-01

For over 50 years, the learning of teaching of a priori bounds on solutions to linear differential equations has involved a Euclidean approach to measuring the size of a solution. While the Euclidean approach to a priori bounds on solutions is somewhat manageable in the learning and teaching of the proofs involving second-order, linear problems with constant co-efficients, we believe it is not pedagogically optimal. Moreover, the Euclidean method becomes pedagogically unwieldy in the proofs involving higher-order cases. The purpose of this work is to propose a simpler pedagogical approach to establish a priori bounds on solutions by considering a different way of measuring the size of a solution to linear problems, which we refer to as the Uber size. The Uber form enables a simplification of pedagogy from the literature and the ideas are accessible to learners who have an understanding of the Fundamental Theorem of Calculus and the exponential function, both usually seen in a first course in calculus. We believe that this work will be of mathematical and pedagogical interest to those who are learning and teaching in the area of differential equations or in any of the numerous disciplines where linear differential equations are used.

Participatory development of a middleware for AAL solutions: requirements and approach – the case of SOPRANO

Directory of Open Access Journals (Sweden)

Schmidt, Andreas

2008-10-01

Full Text Available This paper describes the main features of a middleware for Ambient Assisted Living (AAL applications, exemplified along the SOPRANO research project. The contribution outlines main requirements towards the technical system and the elicitation methodology. The presented middleware allows for personalisation and flexible, extendible configuration of AAL solutions with low effort. Concerning the technical concept, the design approach as well as components, qualities and functionality of the AAL platform are depicted. Furthermore the methodology of requirements elicitation is discussed. It is explained how SOPRANO met the problem to elicit socio-technical system requirements in a user-centred manner, although the addressed target group is not expected to be able to express precise guidelines. SOPRANO („Service oriented programmable smart environments for older Europeans“, http://www.soprano-ip.org/ is a research project funded by the European Commission, which aims at the provision of a technical (AAL infrastructure to help elderly people to keep their independence and to stay in their familiar environment as long as possible. SOPRANO focuses on in-house support and emphasises well-being. It is a main goal to secure situation-aware assistance and help not only in case of emergencies but particularly as well in activities of daily living.