WorldWideScience

Sample records for solid analyses imperative

  1. Translational Research in Pediatrics IV: Solid Tissue Collection and Processing.

    Science.gov (United States)

    Gillio-Meina, Carolina; Zielke, H Ronald; Fraser, Douglas D

    2016-01-01

    Solid tissues are critical for child-health research. Specimens are commonly obtained at the time of biopsy/surgery or postmortem. Research tissues can also be obtained at the time of organ retrieval for donation or from tissue that would otherwise have been discarded. Navigating the ethics of solid tissue collection from children is challenging, and optimal handling practices are imperative to maximize tissue quality. Fresh biopsy/surgical specimens can be affected by a variety of factors, including age, gender, BMI, relative humidity, freeze/thaw steps, and tissue fixation solutions. Postmortem tissues are also vulnerable to agonal factors, body storage temperature, and postmortem intervals. Nonoptimal tissue handling practices result in nucleotide degradation, decreased protein stability, artificial posttranslational protein modifications, and altered lipid concentrations. Tissue pH and tryptophan levels are 2 methods to judge the quality of solid tissue collected for research purposes; however, the RNA integrity number, together with analyses of housekeeping genes, is the new standard. A comprehensive clinical data set accompanying all tissue samples is imperative. In this review, we examined: the ethical standards relating to solid tissue procurement from children; potential sources of solid tissues; optimal practices for solid tissue processing, handling, and storage; and reliable markers of solid tissue quality. Copyright © 2016 by the American Academy of Pediatrics.

  2. The Imperative in Chinese.

    Science.gov (United States)

    Hashimoto, Anne Yue

    A preliminary study of the syntactic characteristics of the imperative construction in modern Chinese is presented. The term "imperative" is used to refer to the type of syntactic construction which is marked by an implicit or explicit second person subject, and which expresses a direct command. Indirect or implied commands expressed by a…

  3. Ethnic Conflict: Imperatives for US Military Strategy

    National Research Council Canada - National Science Library

    Lohide, Kurtis D

    1999-01-01

    .... Recent fighting in Bosnia, Central Africa, and Kosovo seems to provide this context. Such outbreaks of internecine fighting present compelling evidence that ethnic warfare will be a major source of conflict in the new millennium. Therefore, if 21st century American military thinkers are to craft a successful strategy, they must address the imperatives of ethnic conflict. This paper discusses the theoretical imperatives, doctrinal imperatives, and force structure imperatives of ethnic warfare.

  4. Gospel and constitutional imperatives: the right to life

    Directory of Open Access Journals (Sweden)

    S.P. Giles

    2011-06-01

    Full Text Available Gospel and constitutional imperatives: the right to life In the Republic of South Africa, Christians are called to live out gospel imperatives within the legal framework of the Constitution. Ethical issues about the right to life are considered from the perspectives of selected gospel and constitutional imperatives. Gospel imperatives impose themselves as a consequence of Christian discipleship. These are many and diverse, both explicit and implicit. Christian vocation, discipleship, witness and perseverance, are foundational and integral to the praxis of Christian daily living. These facets of Christian life are illustrated by the selected gospel imperatives, “Follow me” (Matt. 4:19 and synoptic parallels, “Love God, and your neighbour as yourself” (Matt. 22:34-40 and synoptic parallels, and “Take up your cross” (Matt. 10:38 and synoptic parallels. The central theoretical argument of this article is driven from a reformed ethical perspective. Gospel imperatives have priority over constitutional imperatives since gospel imperatives are of divine origin and constitutional imperatives of human origin. Acknowledgement of these priorities informs the Christian ethical perspective on the right to life and on abortion.

  5. A Possible Ethical Imperative Based on the Entropy Law

    Directory of Open Access Journals (Sweden)

    Mehrdad Massoudi

    2016-11-01

    Full Text Available Lindsay in an article titled, “Entropy consumption and values in physical science,” (Am. Sci. 1959, 47, 678–696 proposed a Thermodynamic Imperative similar to Kant’s Ethical Categorical Imperative. In this paper, after describing the concept of ethical imperative as elaborated by Kant, we provide a brief discussion of the role of science and its relationship to the classical thermodynamics and the physical implications of the first and the second laws of thermodynamics. We finally attempt to extend and supplement Lindsay’s Thermodynamic Imperative (TI, by another Imperative suggesting simplicity, conservation, and harmony.

  6. How is a categorical imperative possible? : Kant’s deduction of the categorical imperative (GMS, III,4)

    OpenAIRE

    Schönecker, Dieter

    2016-01-01

    Kant’s deduction of the categorical imperative is the answer to the following question: “How is a categorical imperative possible?” The answer is given in subsection 4 (Sec. 4) of chapter three of the Groundwork. It is impossible to understand this answer, and hence impossible to understand Kant’s deduction of the moral law, without taking into account the overall context of Groundwork III (GMS III). However, here I can only sketch the overall structure of GMS III, and there...

  7. Coastal Innovation Imperative

    Directory of Open Access Journals (Sweden)

    Bruce C. Glavovic

    2013-03-01

    Full Text Available This is the second of two articles that explores the coastal innovation paradox and imperative. Paradoxically, innovation is necessary to escape the vulnerability trap created by past innovations that have degraded coastal ecosystems and imperil coastal livelihoods. The innovation imperative is to reframe and underpin business and technology with coherent governance innovations that lead to social transformation for coastal sustainability. How might coastal management help to facilitate this transition? It is argued that coastal management needs to be reconceptualised as a transformative practice of deliberative coastal governance. A foundation comprising four deliberative or process outcomes is posited. The point of departure is to build human and social capital through issue learning and improved democratic attitudes and skills. Attention then shifts to facilitating community-oriented action and improving institutional capacity and decision-making. Together, these endeavours enable improved community problem-solving. The ultimate process goal is to build more collaborative communities. Instituting transformative deliberative coastal governance will help to stimulate innovations that chart new sustainability pathways and help to resolve the coastal problems. This framework could be adapted and applied in other geographical settings.

  8. Search and imperative programming

    NARCIS (Netherlands)

    K.R. Apt (Krzysztof); A. Schaerf

    1996-01-01

    textabstractWe augment the expressive power of imperative programming in order to make it a more attractive vehicle for problems that involve search.The proposed additions are limited yet powerful and are inspired by the logic programming paradigm.We illustrate their use by presenting solutions to a

  9. Mothers of Obese Children Use More Direct Imperatives to Restrict Eating.

    Science.gov (United States)

    Pesch, Megan H; Miller, Alison L; Appugliese, Danielle P; Rosenblum, Katherine L; Lumeng, Julie C

    2018-04-01

    To examine the association of mother and child characteristics with use of direct imperatives to restrict eating. A total of 237 mother-child dyads (mean child age, 70.9 months) participated in a video-recorded, laboratory-standardized eating protocol with 2 large portions of cupcakes. Videos were reliably coded for counts of maternal direct imperatives to restrict children's eating. Anthropometrics were measured. Regression models tested the association of participant characteristics with counts of direct imperatives. Child obese weight status and maternal white non-Hispanic race/ethnicity were associated with greater levels of direct imperatives to restrict eating (p = .0001 and .0004, respectively). Mothers of obese children may be using more direct imperatives to restrict eating so as to achieve behavioral compliance to decrease their child's food intake. Future work should consider the effects direct imperatives have on children's short- and long-term eating behaviors and weight gain trajectories. Copyright © 2017 Society for Nutrition Education and Behavior. Published by Elsevier Inc. All rights reserved.

  10. Validating carbonation parameters of alkaline solid wastes via integrated thermal analyses: Principles and applications

    International Nuclear Information System (INIS)

    Pan, Shu-Yuan; Chang, E.-E.; Kim, Hyunook; Chen, Yi-Hung; Chiang, Pen-Chi

    2016-01-01

    Highlights: • Key carbonation parameters of wastes are determined by integrated thermal analyses. • A modified TG-DTG interpretation is proposed, and validated by the DSC technique. • The modified TG-DTG interpretation is further verified by DTA, TG-MS and TG-FTIR. • Kinetics and thermodynamics of CaCO 3 decomposition in solid wastes are determined. • Implication to maximum carbonation conversion of various solid wastes is described. - Abstract: Accelerated carbonation of alkaline solid wastes is an attractive method for CO 2 capture and utilization. However, the evaluation criteria of CaCO 3 content in solid wastes and the way to interpret thermal analysis profiles were found to be quite different among the literature. In this investigation, an integrated thermal analyses for determining carbonation parameters in basic oxygen furnace slag (BOFS) were proposed based on thermogravimetric (TG), derivative thermogravimetric (DTG), and differential scanning calorimetry (DSC) analyses. A modified method of TG-DTG interpretation was proposed by considering the consecutive weight loss of sample with 200–900 °C because the decomposition of various hydrated compounds caused variances in estimates by using conventional methods of TG interpretation. Different quantities of reference CaCO 3 standards, carbonated BOFS samples and synthetic CaCO 3 /BOFS mixtures were prepared for evaluating the data quality of the modified TG-DTG interpretation, in terms of precision and accuracy. The quantitative results of the modified TG-DTG method were also validated by DSC analysis. In addition, to confirm the TG-DTG results, the evolved gas analysis was performed by mass spectrometer and Fourier transform infrared spectroscopy for detection of the gaseous compounds released during heating. Furthermore, the decomposition kinetics and thermodynamics of CaCO 3 in BOFS was evaluated using Arrhenius equation and Kissinger equation. The proposed integrated thermal analyses for

  11. Validating carbonation parameters of alkaline solid wastes via integrated thermal analyses: Principles and applications

    Energy Technology Data Exchange (ETDEWEB)

    Pan, Shu-Yuan [Graduate Institute of Environmental Engineering, National Taiwan University, Taipei 10673, Taiwan (China); Chang, E.-E. [Department of Biochemistry, Taipei Medical University, Taipei 110, Taiwan (China); Kim, Hyunook [Department of Environmental Engineering, University of Seoul, Seoul 130-743 (Korea, Republic of); Chen, Yi-Hung [Department of Chemical Engineering and Biotechnology, National Taipei University of Technology, Taipei 10608, Taiwan (China); Chiang, Pen-Chi, E-mail: pcchiang@ntu.edu.tw [Graduate Institute of Environmental Engineering, National Taiwan University, Taipei 10673, Taiwan (China)

    2016-04-15

    Highlights: • Key carbonation parameters of wastes are determined by integrated thermal analyses. • A modified TG-DTG interpretation is proposed, and validated by the DSC technique. • The modified TG-DTG interpretation is further verified by DTA, TG-MS and TG-FTIR. • Kinetics and thermodynamics of CaCO{sub 3} decomposition in solid wastes are determined. • Implication to maximum carbonation conversion of various solid wastes is described. - Abstract: Accelerated carbonation of alkaline solid wastes is an attractive method for CO{sub 2} capture and utilization. However, the evaluation criteria of CaCO{sub 3} content in solid wastes and the way to interpret thermal analysis profiles were found to be quite different among the literature. In this investigation, an integrated thermal analyses for determining carbonation parameters in basic oxygen furnace slag (BOFS) were proposed based on thermogravimetric (TG), derivative thermogravimetric (DTG), and differential scanning calorimetry (DSC) analyses. A modified method of TG-DTG interpretation was proposed by considering the consecutive weight loss of sample with 200–900 °C because the decomposition of various hydrated compounds caused variances in estimates by using conventional methods of TG interpretation. Different quantities of reference CaCO{sub 3} standards, carbonated BOFS samples and synthetic CaCO{sub 3}/BOFS mixtures were prepared for evaluating the data quality of the modified TG-DTG interpretation, in terms of precision and accuracy. The quantitative results of the modified TG-DTG method were also validated by DSC analysis. In addition, to confirm the TG-DTG results, the evolved gas analysis was performed by mass spectrometer and Fourier transform infrared spectroscopy for detection of the gaseous compounds released during heating. Furthermore, the decomposition kinetics and thermodynamics of CaCO{sub 3} in BOFS was evaluated using Arrhenius equation and Kissinger equation. The proposed

  12. An MDE Approach for Modular Program Analyses

    NARCIS (Netherlands)

    Yildiz, Bugra Mehmet; Bockisch, Christoph; Aksit, Mehmet; Rensink, Arend

    Program analyses are an important tool to check if a system fulfills its specification. A typical implementation strategy for program analyses is to use an imperative, general-purpose language like Java, and access the program to be analyzed through libraries that offer an API for reading, writing

  13. A global public health imperative

    African Journals Online (AJOL)

    MESKE

    Actions towards closing the health equity gap: A global public health imperative. Tewabech ... global health development. With only two ... of himself and of his family; including food, clothing .... impact on health equity and in the end issued the.

  14. From a Managerial Imperative to a Learning Imperative: Experiences of Urban, Public School Principals

    Science.gov (United States)

    Terosky, Aimee LaPointe

    2014-01-01

    Purpose: This article examines the experiences of urban, public school principals noted for their instructional leadership and highlights a leadership approach grounded in a learning imperative. Framework: This article explores the concept of instructional leadership, defined as attending to instructional matters, as embedded in an urban public…

  15. Three imperative action formats in Danish talk-in-interaction

    DEFF Research Database (Denmark)

    Steensig, Jakob; Heinemann, Trine

    2017-01-01

    be translated into ‘just’ in English, but they are not synonymous in Danish. The investigated actions formats are: (1) imperative+lige, which is used to perform a bilateral request, that is a request for an action that is portrayed as being part of a common project, (2) imperative+bare, which is used to grant...... permission, and (3) bare+imperative, which is used to advise the recipient to carry out a specific action as a solution to a problem. The action formats are designed to show consideration of the recipients’ benefits of the proposed actions in specific ways and they make differential claims of entitlement...

  16. Consider This: The Role of Imperatives in Scholarly Writing.

    Science.gov (United States)

    Swales, John M.; Ahmad, Ummul K.; Change, Yu-Ying; Chavez, Daniel; Dressen, Dacia F.; Seymour, Ruth

    1998-01-01

    Analyzes the use of imperatives in five scholarly journal articles (main text and notes) in each of ten disciplines, and follow-up interviews with authors using imperatives within main text indicate specific patterns and purposes of usage and field-specific expectations and conventions. Discusses implications for instruction of non-native-speaking…

  17. A Java Bytecode Metamodel for Composable Program Analyses

    NARCIS (Netherlands)

    Yildiz, Bugra Mehmet; Bockisch, Christoph; Rensink, Arend; Aksit, Mehmet; Seidl, Martina; Zschaler, Steffen

    Program analyses are an important tool to check if a system fulfills its specification. A typical implementation strategy for program analyses is to use an imperative, general-purpose language like Java; and access the program to be analyzed through libraries for manipulating intermediate code, such

  18. The Methodological Imperatives of Feminist Ethnography

    Directory of Open Access Journals (Sweden)

    Richelle D. Schrock

    2013-12-01

    Full Text Available Feminist ethnography does not have a single, coherent definition and is caught between struggles over the definition and goals of feminism and the multiple practices known collectively as ethnography. Towards the end of the 1980s, debates emerged that problematized feminist ethnography as a productive methodology and these debates still haunt feminist ethnographers today. In this article, I provide a concise historiography of feminist ethnography that summarizes both its promises and its vulnerabilities. I address the three major challenges I argue feminist ethnographers currently face, which include responding productively to feminist critiques of representing "others," accounting for feminisms' commitment to social change while grappling with poststructuralist critiques of knowledge production, and confronting the historical and ongoing lack of recognition for significant contributions by feminist ethnographers. Despite these challenges, I argue that feminist ethnography is a productive methodology and I conclude by delineating its methodological imperatives. These imperatives include producing knowledge about women's lives in specific cultural contexts, recognizing the potential detriments and benefits of representation, exploring women's experiences of oppression along with the agency they exercise in their own lives, and feeling an ethical responsibility towards the communities in which the researchers work. I argue that this set of imperatives enables feminist ethnographers to successfully navigate the challenges they face.

  19. A Hybrid Imperative and Functional Molecular Mechanics Application

    Directory of Open Access Journals (Sweden)

    Thomas Deboni

    1996-01-01

    Full Text Available Molecular mechanics applications model the interactions among large ensembles of discrete particles. They are used where probabilistic methods are inadequate, such as drug chemistry. This methodology is difficult to parallelize with good performance, due to its poor locality, uneven partitions, and dynamic behavior. Imperative programs have been written that attempt this on shared and distributed memory machines. Given such a program, the computational kernel can be rewritten in Sisal, a functional programming language, and integrated with the rest of the imperative program under the Sisal Foreign Language Interface. This allows minimal effort and maximal return from parallelization work, and leaves the work appropriate to imperative implementation in its original form. We describe such an effort, focusing on the parts of the application that are appropriate for Sisal implementation, the specifics of mixed-language programming, and the complex performance behavior of the resulting hybrid code.

  20. From the categorical imperative to the moral law

    OpenAIRE

    Vahl, Marianne

    2008-01-01

    This thesis is a critical survey of Christine Korsgaard’s arguments regarding the rational basis for moral obligations. I focus on her arguments taking us from the categorical imperative to the Moral Law. She makes a distinction that Kant does not; claiming that the categorical imperative is not the Moral Law. In order to equate rational agency with moral agency Korsgaard therefore needs some additional arguments. These arguments, I argue, are not convincing. My claim is that they do not succ...

  1. The Imperative Paradigm of Korowai, a language of West Papua

    NARCIS (Netherlands)

    de Vries, Lourens; Aikhenvald, Alexandra; Dixon, R.M.W

    2017-01-01

    The imperative paradigm of Korowai, a Papuan language of West Papua, is the richest independent verb paradigm of Korowai: it makes more tense, aspect, mood, person and number distinctions than all other verb paradigms. This formal richness is matched by functional richness: imperatives are used in a

  2. Experimental investigation on the hydrodynamics of a gas–liquid–solid fluidized bed using vibration signature and pressure fluctuation analyses

    International Nuclear Information System (INIS)

    Sheikhi, Amir; Sotudeh-Gharebagh, Rahmat; Mostoufi, Navid; Zarghami, Reza

    2013-01-01

    Highlights: • Bed shell vibration fluctuation is introduced as a novel non-invasive monitoring method in three-phase fluidized beds. • Analyses of vibration signatures and pressure fluctuations were performed to characterize gas–liquid–solid fluidized beds. • These enabled further investigation on the dual effect of solid particles on the local and global bed hydrodynamics. -- Abstract: Simultaneous analyses of vibration signatures and pressure fluctuations were performed to investigate the hydrodynamics of a conventional three-phase gas–liquid–solid fluidized bed over a wide range of operating conditions. Non-intrusive vibration signature and pressure fluctuation signals were acquired by means of accelerometers and a piezoresistive pressure transducer, respectively. Comprehensive study on the standard deviation of pressure fluctuations was conducted simultaneously with two new statistical analyses on the pressure fluctuations, namely signal energy and average cycle frequency, which presented a new method of determining minimum liquid-fluidization velocity. This enabled further investigation on the dual effect of solid particles on the local hydrodynamics in the three-phase beds. The vibration analysis of the bed was introduced as a novel and non-invasive tool, which proved to be a robust representative of the global governing regimes suggesting a new approach on the dual effect of solid particles on the bed global hydrodynamics. These methods can pave the way towards the non-invasive hydrodynamic characterization of industrial three-phase reactors

  3. Search and imperative programming

    OpenAIRE

    Apt, Krzysztof; Schaerf, A.

    1996-01-01

    textabstractWe augment the expressive power of imperative programming in order to make it a more attractive vehicle for problems that involve search.The proposed additions are limited yet powerful and are inspired by the logic programming paradigm.We illustrate their use by presenting solutions to a number of classical problems, including the straight search problem, the knapsack problem, and the 8 queens problem. These solutions are substantially simpler than their counterparts written in th...

  4. Do green building assessment criteria meet sustainability imperatives: a critical analysis

    CSIR Research Space (South Africa)

    Van Wyk, Llewellyn V

    2008-07-01

    Full Text Available The purpose of this paper is to determine whether green building assessment criteria meet the imperatives of sustainable development. The paper finds that green building assessment criteria fail to meet the sustainable development imperatives...

  5. Relating Maxwell’s demon and quantitative analysis of information leakage for practical imperative programs

    International Nuclear Information System (INIS)

    Anjaria, Kushal; Mishra, Arun

    2017-01-01

    Shannon observed the relation between information entropy and Maxwell demon experiment to come up with information entropy formula. After that, Shannon’s entropy formula is widely used to measure information leakage in imperative programs. But in the present work, our aim is to go in a reverse direction and try to find possible Maxwell’s demon experimental setup for contemporary practical imperative programs in which variations of Shannon’s entropy formula has been applied to measure the information leakage. To establish the relation between the second principle of thermodynamics and quantitative analysis of information leakage, present work models contemporary variations of imperative programs in terms of Maxwell’s demon experimental setup. In the present work five contemporary variations of imperative program related to information quantification are identified. They are: (i) information leakage in imperative program, (ii) imperative multithreaded program, (iii) point to point leakage in the imperative program, (iv) imperative program with infinite observation, and (v) imperative program in the SOA-based environment. For these variations, minimal work required by an attacker to gain the secret is also calculated using historical Maxwell’s demon experiment. To model the experimental setup of Maxwell’s demon, non-interference security policy is used. In the present work, imperative programs with one-bit secret information have been considered to avoid the complexity. The findings of the present work from the history of physics can be utilized in many areas related to information flow of physical computing, nano-computing, quantum computing, biological computing, energy dissipation in computing, and computing power analysis. (paper)

  6. The Agility Imperative

    DEFF Research Database (Denmark)

    Mitchell, Dr. William

    that the number of tanks or warships you have matters less than your ability to think network rather than linearly is comforting. But gone is also the physical certainty of winning or losing decisive battles and formal surrenders of state actors. The security environment is driven by an unparalleled explosion...... in information transfer that has affected how humans fundamentally organise and develop ideas. The military cannot avoid the impact of these developments and the challenges they present. By the end of 2013 the agility imperative will likely stand out as one of the defining characteristics necessary for military...

  7. The Imperative Sentence Pattern “Vp+tsau” in the Mengjin Dialect

    Directory of Open Access Journals (Sweden)

    Peng Lanyu

    2017-10-01

    Full Text Available In the Mengjin dialect, the imperative sentence “Vp+ʦau (‘go’” is a common sentence pattern, which has six major structural forms. The basic structure is “tɕhy412(‘go’+(Np+Vp+ʦau (‘go’”, and “ʦau” in this form is a marginalized directional verb. Containing the stronger power factor, the imperative sentence “Vp+ʦau” is often used in the relationship between the superior and the subordinate, which has a high degree of colloquialism. Nevertheless, the power factor can be ignored on condition that the relationship between the two parties of the communication is very close. Due to the division of the ancient Chinese political jurisdictions and the influence of population migration, the imperative “Vp+ʦau” is widely distributed. Two different imperative sentences being merged and weakened, this sentence pattern comes into being.

  8. Cognitive Style and Achievement in Imperative and Functional Programming Language Courses.

    Science.gov (United States)

    Myers, J. Paul, Jr.; Munsinger, Brita

    This paper investigates the relationship between learning style and programming achievement in two paradigms: imperative and functional. An imperative language achieves its effect by changing the value of variables by means of assignment statements while functional languages rely on evaluation of expressions rather than side-effects. Learning…

  9. Imperatives in informal organizational resource exchange in Central Europe

    Directory of Open Access Journals (Sweden)

    David Jancsics

    2015-01-01

    Full Text Available This paper challenges the mainstream social scientific approach that emphasizes “moral inferiority” in corruption and bribery in Central and Eastern Europe. We argue that in many cases, people participate in informal organizational resource exchanges not because of immorality or greed but rather because of powerful external forces. By using the case of contemporary Hungary to support this argument, this paper provides a systematic analysis of such imperatives. The findings of 50 in-depth qualitative interviews suggest that two main imperatives can be distinguished; macro-level social and meso-level organizational forces. Macro-level forces may be linked to historical paths, Hungary's socialist and pre-socialist social conditions, and its post-socialist welfare state development. Meso-level organizational forces are more general phenomena and can be found in many other countries in the world. Moreover, there are numerous categories within each theme. Some of them represent normative imperatives, while others are more material structural forces.

  10. The strategic entrepreneurial thinking imperative

    OpenAIRE

    S. Dhliwayo; J. J. Van Vuuren

    2007-01-01

    Purpose: The aim of this paper is to demonstrate that strategic entrepreneurial thinking is a unitary concept which should be viewed as a standalone construct. Design/Methodology/Approach: The concept strategic entrepreneurial thinking is modelled from an analysis of strategic thinking and entrepreneurial thinking from available literature. The strategic entrepreneurial mindset imperative is then emphasised and confirmed. Findings: This paper's finding is that there is no diff...

  11. Global analyses of historical masonry buildings: Equivalent frame vs. 3D solid models

    Science.gov (United States)

    Clementi, Francesco; Mezzapelle, Pardo Antonio; Cocchi, Gianmichele; Lenci, Stefano

    2017-07-01

    The paper analyses the seismic vulnerability of two different masonry buildings. It provides both an advanced 3D modelling with solid elements and an equivalent frame modelling. The global structural behaviour and the dynamic properties of the compound have been evaluated using the Finite Element Modelling (FEM) technique, where the nonlinear behaviour of masonry has been taken into account by proper constitutive assumptions. A sensitivity analysis is done to evaluate the effect of the choice of the structural models.

  12. The Categorical Imperative Analyzing Immanuel Kant’s Grounding for A Metaphysics of Morals

    OpenAIRE

    Bordum, Anders

    2002-01-01

    In this article I first argue that Immanuel Kant’s conception of the categorical imperative is important to his philosophy. I systematically, though indirectly, interconnect the cognitive and moral aspects of his thinking. Second, I present an interpretation of the Kantian ethics, taking as my point of departure, the concept of the categorical imperative. Finally, I show how the categorical imperative is given a dialogical interpretation by Jürgen Habermas in his approach, usually referred to...

  13. Academic boycott - political strategy or moral imperative?

    African Journals Online (AJOL)

    academic boycott is a morally imperative component of a broader sanctions .... The issue on which I should like to focus is the assertion that academic boycott can ..... Business Bookrnan, 1957. 3. Tingsten H. The ... Shaw WH. Boyeotting South ...

  14. The Education of the Categorical Imperative

    Science.gov (United States)

    Johnston, James Scott

    2006-01-01

    In this article, I examine anew the moral philosophy of Immanuel Kant and its contributions to educational theory. I make four claims. First, that Kant should be read as having the Categorical Imperative develop out of subjective maxims. Second, that moral self-perfection is the aim of moral education. Third, that moral self-perfection develops by…

  15. Validating carbonation parameters of alkaline solid wastes via integrated thermal analyses: Principles and applications.

    Science.gov (United States)

    Pan, Shu-Yuan; Chang, E-E; Kim, Hyunook; Chen, Yi-Hung; Chiang, Pen-Chi

    2016-04-15

    Accelerated carbonation of alkaline solid wastes is an attractive method for CO2 capture and utilization. However, the evaluation criteria of CaCO3 content in solid wastes and the way to interpret thermal analysis profiles were found to be quite different among the literature. In this investigation, an integrated thermal analyses for determining carbonation parameters in basic oxygen furnace slag (BOFS) were proposed based on thermogravimetric (TG), derivative thermogravimetric (DTG), and differential scanning calorimetry (DSC) analyses. A modified method of TG-DTG interpretation was proposed by considering the consecutive weight loss of sample with 200-900°C because the decomposition of various hydrated compounds caused variances in estimates by using conventional methods of TG interpretation. Different quantities of reference CaCO3 standards, carbonated BOFS samples and synthetic CaCO3/BOFS mixtures were prepared for evaluating the data quality of the modified TG-DTG interpretation, in terms of precision and accuracy. The quantitative results of the modified TG-DTG method were also validated by DSC analysis. In addition, to confirm the TG-DTG results, the evolved gas analysis was performed by mass spectrometer and Fourier transform infrared spectroscopy for detection of the gaseous compounds released during heating. Furthermore, the decomposition kinetics and thermodynamics of CaCO3 in BOFS was evaluated using Arrhenius equation and Kissinger equation. The proposed integrated thermal analyses for determining CaCO3 content in alkaline wastes was precise and accurate, thereby enabling to effectively assess the CO2 capture capacity of alkaline wastes for mineral carbonation. Copyright © 2015 Elsevier B.V. All rights reserved.

  16. Report: Searching for a way to sustainability: technical and policy analyses of solid waste issues in Kathmandu.

    Science.gov (United States)

    Dangi, Mohan B; Cohen, Ronald R H; Urynowicz, Michael A; Poudyal, Khem N

    2009-05-01

    Kathmandu Metropolitan City has attempted to reorganize its solid waste management a number of times. The German Technical and Financial Aid Organization led early efforts that were followed by a number of more recent experiments that left the city with an unsustainable solid waste management system following the termination of foreign aid. To examine this failure, the research team evaluated household surveys, field observations, interviews, and other primary and secondary information within the context of technical, social, and institutional analyses. The survey results show that the solid waste collection rates are far below the 90% claimed by the metropolis and street sweeping consumes approximately 51% of its solid waste budget. As a result of the relatively low collection rates the city residents are encouraged to dump waste into public lands. Consequently, too much of the city's resources are focused on sweeping rather than collection. Kathmandu needs to recognize informal waste picking, privatize, use local techniques, build capacity, promote bottom-up and participatory styles of management, and regulate policies to maintain solid waste management.

  17. Computational and experimental analyses of the wave propagation through a bar structure including liquid-solid interface

    Energy Technology Data Exchange (ETDEWEB)

    Park, Sang Jin [UST Graduate School, Daejeon (Korea, Republic of); Rhee, Hui Nam [Division of Mechanical and Aerospace Engineering, Sunchon National University, Sunchon (Korea, Republic of); Yoon, Doo Byung; Park, Jin Ho [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2015-08-15

    In this research, we study the propagation of longitudinal and transverse waves through a metal rod including a liquid layer using computational and experimental analyses. The propagation characteristics of longitudinal and transverse waves obtained by the computational and experimental analyses were consistent with the wave propagation theory for both cases, that is, the homogeneous metal rod and the metal rod including a liquid layer. The fluid-structure interaction modeling technique developed for the computational wave propagation analysis in this research can be applied to the more complex structures including solid-liquid interfaces.

  18. Tuneable diode laser gas analyser for methane measurements on a large scale solid oxide fuel cell

    Science.gov (United States)

    Lengden, Michael; Cunningham, Robert; Johnstone, Walter

    2011-10-01

    A new in-line, real time gas analyser is described that uses tuneable diode laser spectroscopy (TDLS) for the measurement of methane in solid oxide fuel cells. The sensor has been tested on an operating solid oxide fuel cell (SOFC) in order to prove the fast response and accuracy of the technology as compared to a gas chromatograph. The advantages of using a TDLS system for process control in a large-scale, distributed power SOFC unit are described. In future work, the addition of new laser sources and wavelength modulation will allow the simultaneous measurement of methane, water vapour, carbon-dioxide and carbon-monoxide concentrations.

  19. Production and Comprehension of Prosodic Markers in Sign Language Imperatives

    Directory of Open Access Journals (Sweden)

    Diane Brentari

    2018-05-01

    Full Text Available In signed and spoken language sentences, imperative mood and the corresponding speech acts such as for instance, command, permission or advice, can be distinguished by morphosyntactic structures, but also solely by prosodic cues, which are the focus of this paper. These cues can express paralinguistic mental states or grammatical meaning, and we show that in American Sign Language (ASL, they also exhibit the function, scope, and alignment of prosodic, linguistic elements of sign languages. The production and comprehension of prosodic facial expressions and temporal patterns therefore can shed light on how cues are grammaticalized in sign languages. They can also be informative about the formal semantic and pragmatic properties of imperative types not only in ASL, but also more broadly. This paper includes three studies: one of production (Study 1 and two of comprehension (Studies 2 and 3. In Study 1, six prosodic cues are analyzed in production: temporal cues of sign and hold duration, and non-manual cues including tilts of the head, head nods, widening of the eyes, and presence of mouthings. Results of Study 1 show that neutral sentences and commands are well distinguished from each other and from other imperative speech acts via these prosodic cues alone; there is more limited differentiation among explanation, permission, and advice. The comprehension of these five speech acts is investigated in Deaf ASL signers in Study 2, and in three additional groups in Study 3: Deaf signers of German Sign Language (DGS, hearing non-signers from the United States, and hearing non-signers from Germany. Results of Studies 2 and 3 show that the ASL group performs significantly better than the other 3 groups and that all groups perform above chance for all meaning types in comprehension. Language-specific knowledge, therefore, has a significant effect on identifying imperatives based on targeted cues. Command has the most cues associated with it and is the

  20. Clean translation of an imperative reversible programming language

    DEFF Research Database (Denmark)

    Axelsen, Holger Bock

    2011-01-01

    We describe the translation techniques used for the code generation in a compiler from the high-level reversible imperative programming language Janus to the low-level reversible assembly language PISA. Our translation is both semantics preserving (correct), in that target programs compute exactly...... the same functions as their source programs (cleanly, with no extraneous garbage output), and efficient, in that target programs conserve the complexities of source programs. In particular, target programs only require a constant amount of temporary garbage space. The given translation methods are generic......, and should be applicable to any (imperative) reversible source language described with reversible flowcharts and reversible updates. To our knowledge, this is the first compiler between reversible languages where the source and target languages were independently developed; the first exhibiting both...

  1. A software framework for analysing solid-state MAS NMR data

    International Nuclear Information System (INIS)

    Stevens, Tim J.; Fogh, Rasmus H.; Boucher, Wayne; Higman, Victoria A.; Eisenmenger, Frank; Bardiaux, Benjamin; Rossum, Barth-Jan van; Oschkinat, Hartmut; Laue, Ernest D.

    2011-01-01

    Solid-state magic-angle-spinning (MAS) NMR of proteins has undergone many rapid methodological developments in recent years, enabling detailed studies of protein structure, function and dynamics. Software development, however, has not kept pace with these advances and data analysis is mostly performed using tools developed for solution NMR which do not directly address solid-state specific issues. Here we present additions to the CcpNmr Analysis software package which enable easier identification of spinning side bands, straightforward analysis of double quantum spectra, automatic consideration of non-uniform labelling schemes, as well as extension of other existing features to the needs of solid-state MAS data. To underpin this, we have updated and extended the CCPN data model and experiment descriptions to include transfer types and nomenclature appropriate for solid-state NMR experiments, as well as a set of experiment prototypes covering the experiments commonly employed by solid-sate MAS protein NMR spectroscopists. This work not only improves solid-state MAS NMR data analysis but provides a platform for anyone who uses the CCPN data model for programming, data transfer, or data archival involving solid-state MAS NMR data.

  2. TECHNOLOGICAL IMPERATIVE IMPACT OF GLOBALIZATION ON INTERNATIONAL AGRICULTURAL ECONOMY

    Directory of Open Access Journals (Sweden)

    А. Кozlova

    2014-09-01

    Full Text Available The article highlights the factors influencing agricultural production towards global market. The study consists basic fundamental imperatives of globalization on the agricultural sector in international economic relations. The article analyzes the strategic priorities of the international agricultural sector, which includes financial and credit support, legal aspects, processes and integration of organizational structures. Technological imperatives require a large structural and institutional turn in the Ukrainian economy on the basis of current trends in the global economy, scientific and technical potential. There is a growing importance of organizing and conducting international level in the field of technological forecasting. This type of prediction is considered as backbone component in strategic forecasting and economic development programming.

  3. Transforming Cobol Legacy Software to a Generic Imperative Model

    National Research Council Canada - National Science Library

    Moraes, DinaL

    1999-01-01

    .... This research develops a transformation system to convert COBOL code into a generic imperative model, recapturing the initial design and deciphering the requirements implemented by the legacy code...

  4. The Attachment Imperative

    DEFF Research Database (Denmark)

    Navne, Laura Emdal; Svendsen, Mette Nordahl; Gammeltoft, Tine

    2017-01-01

    on social relations and point to the productive aspects of practices of distance and detachment. We show that while the NICU upholds an imperative of attachment independently of the infant's chances of survival, for parents, attachment is contingent on certain hesitations in relation to their infant. We...... argue that there are nuances in practices of relationmaking in need of more attention (i.e., the nexus of attachment and detachment). Refraining from touching, holding, and feeding their infants during critical periods, the parents enact detachment as integral to their practices of attachment....... Such “cuts” in parent–infant relations become steps on the way to securing the infant's survival and making kin(ship). We conclude that although infants may be articulated as “maybe‐lives” by staff, in the NICU as well as in Danish society, the ideal of attachment appears to leave little room for “maybe‐parents.”...

  5. Discourse, the Moral Imperative and Faraday's Candle

    Science.gov (United States)

    Melville, Wayne

    2013-01-01

    This commentary considers two lines of inquiry into the work of Ideland and Malmberg: the role of discourse in shaping teachers' responses to Roberts' (2011) Visions of Science and the moral imperatives that will accompany any shifts between Vision I and II. Vision I of science has accreted to itself great power and prestige, both of which shape…

  6. Municipal solid waste composition: Sampling methodology, statistical analyses, and case study evaluation

    International Nuclear Information System (INIS)

    Edjabou, Maklawe Essonanawe; Jensen, Morten Bang; Götze, Ramona; Pivnenko, Kostyantyn; Petersen, Claus; Scheutz, Charlotte; Astrup, Thomas Fruergaard

    2015-01-01

    Highlights: • Tiered approach to waste sorting ensures flexibility and facilitates comparison of solid waste composition data. • Food and miscellaneous wastes are the main fractions contributing to the residual household waste. • Separation of food packaging from food leftovers during sorting is not critical for determination of the solid waste composition. - Abstract: Sound waste management and optimisation of resource recovery require reliable data on solid waste generation and composition. In the absence of standardised and commonly accepted waste characterisation methodologies, various approaches have been reported in literature. This limits both comparability and applicability of the results. In this study, a waste sampling and sorting methodology for efficient and statistically robust characterisation of solid waste was introduced. The methodology was applied to residual waste collected from 1442 households distributed among 10 individual sub-areas in three Danish municipalities (both single and multi-family house areas). In total 17 tonnes of waste were sorted into 10–50 waste fractions, organised according to a three-level (tiered approach) facilitating comparison of the waste data between individual sub-areas with different fractionation (waste from one municipality was sorted at “Level III”, e.g. detailed, while the two others were sorted only at “Level I”). The results showed that residual household waste mainly contained food waste (42 ± 5%, mass per wet basis) and miscellaneous combustibles (18 ± 3%, mass per wet basis). The residual household waste generation rate in the study areas was 3–4 kg per person per week. Statistical analyses revealed that the waste composition was independent of variations in the waste generation rate. Both, waste composition and waste generation rates were statistically similar for each of the three municipalities. While the waste generation rates were similar for each of the two housing types (single

  7. Municipal solid waste composition: Sampling methodology, statistical analyses, and case study evaluation

    Energy Technology Data Exchange (ETDEWEB)

    Edjabou, Maklawe Essonanawe, E-mail: vine@env.dtu.dk [Department of Environmental Engineering, Technical University of Denmark, 2800 Kgs. Lyngby (Denmark); Jensen, Morten Bang; Götze, Ramona; Pivnenko, Kostyantyn [Department of Environmental Engineering, Technical University of Denmark, 2800 Kgs. Lyngby (Denmark); Petersen, Claus [Econet AS, Omøgade 8, 2.sal, 2100 Copenhagen (Denmark); Scheutz, Charlotte; Astrup, Thomas Fruergaard [Department of Environmental Engineering, Technical University of Denmark, 2800 Kgs. Lyngby (Denmark)

    2015-02-15

    Highlights: • Tiered approach to waste sorting ensures flexibility and facilitates comparison of solid waste composition data. • Food and miscellaneous wastes are the main fractions contributing to the residual household waste. • Separation of food packaging from food leftovers during sorting is not critical for determination of the solid waste composition. - Abstract: Sound waste management and optimisation of resource recovery require reliable data on solid waste generation and composition. In the absence of standardised and commonly accepted waste characterisation methodologies, various approaches have been reported in literature. This limits both comparability and applicability of the results. In this study, a waste sampling and sorting methodology for efficient and statistically robust characterisation of solid waste was introduced. The methodology was applied to residual waste collected from 1442 households distributed among 10 individual sub-areas in three Danish municipalities (both single and multi-family house areas). In total 17 tonnes of waste were sorted into 10–50 waste fractions, organised according to a three-level (tiered approach) facilitating comparison of the waste data between individual sub-areas with different fractionation (waste from one municipality was sorted at “Level III”, e.g. detailed, while the two others were sorted only at “Level I”). The results showed that residual household waste mainly contained food waste (42 ± 5%, mass per wet basis) and miscellaneous combustibles (18 ± 3%, mass per wet basis). The residual household waste generation rate in the study areas was 3–4 kg per person per week. Statistical analyses revealed that the waste composition was independent of variations in the waste generation rate. Both, waste composition and waste generation rates were statistically similar for each of the three municipalities. While the waste generation rates were similar for each of the two housing types (single

  8. Employee Work-Life Balance as an HR Imperative | Igbinomwanhia ...

    African Journals Online (AJOL)

    Employee Work-Life Balance as an HR Imperative. ... With the growing diversity of family structures represented in today‟s workforce, ... of managing an employee's work-life balance have increased markedly over the past 20 years.

  9. Clarifying the Imperative of Integration Research for Sustainable Environmental Management

    Directory of Open Access Journals (Sweden)

    Stephen Dovers

    2005-01-01

    Full Text Available This paper discusses why integration is important in doing research for developing policy and practice of sustainable environmental management. The imperative of integration includes environmental, social, economic, and other disciplinary considerations, as well as stakeholder interests. However, what is meant by integration is not always clear. While the imperative is being increasingly enunciated, the challenges it presents are difficult and indicate a long term pursuit. This paper clarifies the different dimensions of integration, as an important preliminary step toward advancing mutual understanding and the development of approaches. The paper identifies the driving forces for integration, discusses when integration is required, categorises forms of integration, and proposes principles to inform research programs and projects.

  10. Anti-m antibody in solid tumors-two case reports.

    Science.gov (United States)

    Soni, Shiv Kumar; Goyal, Hari; Sood, S K; Setia, Rasika

    2014-09-01

    Anti-M antibodies are usually of IgM, appear as cold agglutinins and are clinically insignificant. We are reporting two cases of anti-M in cases of solid tumors where the anti-M caused discrepancy in blood grouping, reacted in coombs phase of crossmatching. Anti-M in first case showed dosage effect. These antibodies can be clinical significant when detected in coombs phase, making M antigen negative coombs compatible unit transfusion imperative.

  11. Radwastes and public ethics: issues and imperatives

    International Nuclear Information System (INIS)

    Maxey, M.M.

    1978-01-01

    This paper, which was presented at the Health Physics Society annual meeting at Atlanta, conclude that the problem of radioactive waste management is neither unique and unprecedented, nor has it been properly formulated from an ethical perspective, and that to recover and maintain a balanced perspective on this particular biohazard and to introduce some corrective perception in the public mind becomes an ethical imperative. (author)

  12. Academic boycott - political strategy or moral imperative? Selective ...

    African Journals Online (AJOL)

    Academic boycott has been justified as an appropriate political strategy in the struggle against the oppression of apartheid. Moral outrage against racist policies has led to the claim that academic boycott is a morally imperative component of a broader sanctions policy. This claim has neither been substantiated by a ...

  13. Women as a business imperative.

    Science.gov (United States)

    Schwartz, F N

    1992-01-01

    In 1989, Felice N. Schwartz's HBR article "Management Women and the New Facts of Life" generated a huge debate over the rules established by corporations in their handling of women executives. Now in "Women as a Business Imperative," Schwartz follows up with practical insights about the costs companies incur in passing over qualified businesswomen. In the form of a memo to a fictional CEO, Schwartz describes how the atmosphere within most companies is corrosive to women and must change. Preconceptions harbored by male senior managers about women are so deeply ingrained that many men are not even aware of them. Yet senior managers must help women advance. Those companies that accept their responsibility to make radical change--both in women's treatment and in family support--can improve their bottom lines enormously. Treating women as a business imperative is the equivalent of creating a unique R&D product for which there is great demand. Most companies ignore child care and other family concerns. Many companies hire women to ensure mere adequacy and avoid litigation. Women's ambitions and energies are stifled by such businesses at the same time that women have demonstrated their competence and potential in the best business schools. High turnover results. However, the restraints that now hold women back can be loosened easily. CEOs and other senior managers must support their female employees by (1) acknowledging the fundamental difference between women and men--the biological fact of maternity; (2) allowing flexibility for women and men who need it; (3) providing training that takes advantage of women's leadership potential; and (4) eliminating the corrosive atmosphere and the barriers that exist for women in the workplace.

  14. Moral imperatives for academic medicine.

    Science.gov (United States)

    Thompson, J N

    1997-12-01

    As the health care system becomes dominated by managed care, academic medicine must do more than simply learn how to continue to offer the same level of care with ever-tightening resources and in new practice environments. Three moral imperatives must guide how medicine is practiced and taught: (1) patients' health and well-being must always be foremost, centered in quality of care and respect for life; (2) the emotional and spiritual needs of patients must be considered, not just the physical needs; (3) academic medicine must instill in its trainees discipline, passion, and skills to meet their obligation to be lifelong learners. These imperatives make it more important than ever for medical educators to tackle two crucial questions: What kind of person makes the best possible physician? And what constitutes the best possible training for that person? Taking these questions seriously in the new era of health care may mean that medical educators need to rethink the teaching of medicine. One example of how this might be done is the Curriculum for 2002 Committee recently formed at the Wake Forest University School of Medicine. It is becoming clear that medical educators can do a better and more comprehensive job of helping future physicians uncover and strengthen their own morality and, in the face of managed care's pressures, renew their loyalty to medicine as a service rather than a business. Morally sensitized physicians can better deal with the hard issues of medicine, such as euthanasia and abortion, and can help their students examine these issues. Most important, they can show their students that physicians are members of a moral community dedicated to something other than its own self-interest.

  15. Authoritative knowledge, the technological imperative and women's responses to prenatal diagnostic technologies.

    Science.gov (United States)

    McCoyd, Judith L M

    2010-12-01

    Theories about authoritative knowledge (AK) and the technological imperative have received varying levels of interest in anthropological, feminist and science and technology studies. Although the anthropological literature abounds with empirical considerations of authoritative knowledge, few have considered both theories through an empirical, inductive lens. Data extracted from an earlier study of 30 women's responses to termination for fetal anomaly are reanalyzed to consider the women's views of, and responses to, prenatal diagnostic technologies (PNDTs). Findings indicate that a small minority embrace the societal portrayal of technology as univalently positive, while the majority have nuanced and ambivalent responses to the use of PNDTs. Further, the interface of authoritative knowledge and the technological imperative suggests that AK derives not only from medical provider status and technology use, but also from the adequacy and trustworthiness of the information. The issue of timing and uncertainty of the information also are interrogated for their impact on women's lives and what that can illuminate about the theories of AK and the technological imperative.

  16. Alma-0: an imperative language that supports declarative programming

    NARCIS (Netherlands)

    K.R. Apt (Krzysztof); J. Brunekreef; V. Partinton; A. Schaerf

    1997-01-01

    textabstractWe describe here an implemented small programming language, called Alma, that augments the expressive power of imperative programming by a limited number of features inspired by the logic programming paradigm. These additions encourage declarative programming and make it a more

  17. Validity as a social imperative for assessment in health professions education: a concept analysis.

    Science.gov (United States)

    Marceau, Mélanie; Gallagher, Frances; Young, Meredith; St-Onge, Christina

    2018-06-01

    Assessment can have far-reaching consequences for future health care professionals and for society. Thus, it is essential to establish the quality of assessment. Few modern approaches to validity are well situated to ensure the quality of complex assessment approaches, such as authentic and programmatic assessments. Here, we explore and delineate the concept of validity as a social imperative in the context of assessment in health professions education (HPE) as a potential framework for examining the quality of complex and programmatic assessment approaches. We conducted a concept analysis using Rodgers' evolutionary method to describe the concept of validity as a social imperative in the context of assessment in HPE. Supported by an academic librarian, we developed and executed a search strategy across several databases for literature published between 1995 and 2016. From a total of 321 citations, we identified 67 articles that met our inclusion criteria. Two team members analysed the texts using a specified approach to qualitative data analysis. Consensus was achieved through full team discussions. Attributes that characterise the concept were: (i) demonstration of the use of evidence considered credible by society to document the quality of assessment; (ii) validation embedded through the assessment process and score interpretation; (iii) documented validity evidence supporting the interpretation of the combination of assessment findings, and (iv) demonstration of a justified use of a variety of evidence (quantitative and qualitative) to document the quality of assessment strategies. The emerging concept of validity as a social imperative highlights some areas of focus in traditional validation frameworks, whereas some characteristics appear unique to HPE and move beyond traditional frameworks. The study reflects the importance of embedding consideration for society and societal concerns throughout the assessment and validation process, and may represent a

  18. National Security Imperatives and the Neorealist State: Iran and Realpolitik

    National Research Council Canada - National Science Library

    Grogan, Michael

    2000-01-01

    .... Iran's imperative has been-and still is-focused on the pragmatic national security interests of the nation-state model vice the ideological potential for spreading its brand of Islamic revolution abroad...

  19. Big data governance an emerging imperative

    CERN Document Server

    Soares, Sunil

    2012-01-01

    Written by a leading expert in the field, this guide focuses on the convergence of two major trends in information management-big data and information governance-by taking a strategic approach oriented around business cases and industry imperatives. With the advent of new technologies, enterprises are expanding and handling very large volumes of data; this book, nontechnical in nature and geared toward business audiences, encourages the practice of establishing appropriate governance over big data initiatives and addresses how to manage and govern big data, highlighting the relevant processes,

  20. Verification of Imperative Programs by Constraint Logic Program Transformation

    Directory of Open Access Journals (Sweden)

    Emanuele De Angelis

    2013-09-01

    Full Text Available We present a method for verifying partial correctness properties of imperative programs that manipulate integers and arrays by using techniques based on the transformation of constraint logic programs (CLP. We use CLP as a metalanguage for representing imperative programs, their executions, and their properties. First, we encode the correctness of an imperative program, say prog, as the negation of a predicate 'incorrect' defined by a CLP program T. By construction, 'incorrect' holds in the least model of T if and only if the execution of prog from an initial configuration eventually halts in an error configuration. Then, we apply to program T a sequence of transformations that preserve its least model semantics. These transformations are based on well-known transformation rules, such as unfolding and folding, guided by suitable transformation strategies, such as specialization and generalization. The objective of the transformations is to derive a new CLP program TransfT where the predicate 'incorrect' is defined either by (i the fact 'incorrect.' (and in this case prog is not correct, or by (ii the empty set of clauses (and in this case prog is correct. In the case where we derive a CLP program such that neither (i nor (ii holds, we iterate the transformation. Since the problem is undecidable, this process may not terminate. We show through examples that our method can be applied in a rather systematic way, and is amenable to automation by transferring to the field of program verification many techniques developed in the field of program transformation.

  1. Intercultural Education as an Imperative of Social Development

    Science.gov (United States)

    Baça, Ferit

    2015-01-01

    The imperative need of a social coexistence among different groups of people is the implementation of the intercultural education. In these circumstances, school is the most important place and factor for pupils and students as future citizens to take the first knowledge-based on society, life and coexistence in a given country. On the other hand,…

  2. Inclusive development as an imperative to realizing the human right ...

    African Journals Online (AJOL)

    Inclusive development as an imperative to realizing the human right to water and sanitation. ... PROMOTING ACCESS TO AFRICAN RESEARCH ... where the latter aims at ensuring that the structural causes of inequality are also addressed.

  3. Evidence for Bulk Ripplocations in Layered Solids

    Science.gov (United States)

    Gruber, Jacob; Lang, Andrew C.; Griggs, Justin; Taheri, Mitra L.; Tucker, Garritt J.; Barsoum, Michel W.

    2016-09-01

    Plastically anisotropic/layered solids are ubiquitous in nature and understanding how they deform is crucial in geology, nuclear engineering, microelectronics, among other fields. Recently, a new defect termed a ripplocation-best described as an atomic scale ripple-was proposed to explain deformation in two-dimensional solids. Herein, we leverage atomistic simulations of graphite to extend the ripplocation idea to bulk layered solids, and confirm that it is essentially a buckling phenomenon. In contrast to dislocations, bulk ripplocations have no Burgers vector and no polarity. In graphite, ripplocations are attracted to other ripplocations, both within the same, and on adjacent layers, the latter resulting in kink boundaries. Furthermore, we present transmission electron microscopy evidence consistent with the existence of bulk ripplocations in Ti3SiC2. Ripplocations are a topological imperative, as they allow atomic layers to glide relative to each other without breaking the in-plane bonds. A more complete understanding of their mechanics and behavior is critically important, and could profoundly influence our current understanding of how graphite, layered silicates, the MAX phases, and many other plastically anisotropic/layered solids, deform and accommodate strain.

  4. Curbing Corruption in Nigeria: The Imperatives of Good Leadership ...

    African Journals Online (AJOL)

    The work generally examined the past and present government leaderships' efforts at curbing corruption in Nigeria and the imperatives of good leadership. The study, specifically, analyzed the relationship between effectively fighting and curbing corruption and the leadership style in Nigeria. The basic finding is that ...

  5. Analysis of solids by spark-source mass spectrometry; Analyse des solides au spectrometre de masse a etincelles

    Energy Technology Data Exchange (ETDEWEB)

    Stefani, R; Desjardins, M; Brun, J C; Cornu, A; Bourguillot, R [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1965-07-01

    Spark source mass spectrometer MS7 has been designed to determine traces of impurities in solids without standards. An atlas of 12 000 lines, assembled in the Grenoble laboratory, allows a quick investigation of mass spectra, notwithstanding their complexity due to multiply charged and polyatomic darkening. Photometric measurements increase accuracy calibration curve is known for each photo-plate. Further, reproducibility is better, if random fluctuations of matrix line darkening are corrected. So far, in a concentration range of 0,01 to 1 000 ppm (atomic), reproducibility is approximately 20 per cent, but absolute value of results depends on 'sensitivity coefficients'. (authors) [French] Le spectrometre de masse a etincelles, de type MS7, est destine a l'analyse chimique de traces dans les solides, sans echantillons etalons. L'emploi de catalogues de 12 000 raies, elabores au laboratoire, permet un depouillement rapide des spectres, malgre leur complexite due aux ionisations multiples et aux associations d'atomes. Le niveau d'apparition d'une impurete donne une estimation de sa teneur, mais la valeur du renseignement depend de la preparation des electrodes et de la connaissance plus ou moins approfondie des processus d'ionisation dans l'etincelle et de noircissement des emulsions photographiques. Les mesures photometriques augmentent la precision des resultats, si l'on determine systematiquement la courbe de noircissement de chaque plaque. De meme la reproductibilite est amelioree si l'on tient compte des fluctuations statistiques du noircissement de l'emulsion par les ions de la matrice. Actuellement, les concentrations mesurees dans le domaine de 0,01 a 1000 ppm atomiques sont reproductibles a 20 pour cent pres, mais leur valeur absolue n'est assuree qu'a un coefficient 3 pres. Des etudes sont en cours pour calibrer l'appareil en valeur absolue, par une determination des coefficients de sensibilite a partir d'echantillons etalons. (auteurs)

  6. Organizational Culture and the Imperatives for Implementing Joint Vision 2010

    National Research Council Canada - National Science Library

    Casmus, David

    1997-01-01

    .... Second, it identifies the notion of culture as it applies to the Armed Forces. Third, it identifies the cultural imperatives of Joint Vision 2010 and applies some tools from Edgar Schein's models for influencing organizational culture changes...

  7. Communication: Dynamical and structural analyses of solid hydrogen under vapor pressure

    Energy Technology Data Exchange (ETDEWEB)

    Hyeon-Deuk, Kim, E-mail: kim@kuchem.kyoto-u.ac.jp [Department of Chemistry, Kyoto University, Kyoto 606-8502 (Japan); Japan Science and Technology Agency, PRESTO, 4-1-8 Honcho, Kawaguchi, Saitama 332-0012 (Japan); Ando, Koji [Department of Chemistry, Kyoto University, Kyoto 606-8502 (Japan)

    2015-11-07

    Nuclear quantum effects play a dominant role in determining the phase diagram of H{sub 2}. With a recently developed quantum molecular dynamics simulation method, we examine dynamical and structural characters of solid H{sub 2} under vapor pressure, demonstrating the difference from liquid and high-pressure solid H{sub 2}. While stable hexagonal close-packed lattice structures are reproduced with reasonable lattice phonon frequencies, the most stable adjacent configuration exhibits a zigzag structure, in contrast with the T-shape liquid configuration. The periodic angular distributions of H{sub 2} molecules indicate that molecules are not a completely free rotor in the vapor-pressure solid reflecting asymmetric potentials from surrounding molecules on adjacent lattice sites. Discrete jumps of librational and H–H vibrational frequencies as well as H–H bond length caused by structural rearrangements under vapor pressure effectively discriminate the liquid and solid phases. The obtained dynamical and structural information of the vapor-pressure H{sub 2} solid will be useful in monitoring thermodynamic states of condensed hydrogens.

  8. VARIANTS IMPERATIVE FORMS OF SECOND PERSON IN CENTURIES XIX AND XX: SOCIAL EXPRESSION

    Directory of Open Access Journals (Sweden)

    Márcia Cristina de Brito Rumeu

    2016-12-01

    Full Text Available In this text, looking to trace the synchronic reality of Brazilian Portuguese on the variable imperative grammatical expression of the second person singular ((“fala você” vs. (“Agora seja tu o laso de união...”,1919. Based on the analysis of 19th and 20th century personal letters,written by educated Brazilians, members of a same Brazilian family (the Pedreira Ferraz-Magalhaes family, whose sociolinguistic profiles have beenidentified (CONDE SILVEST RE, 2007; ROMAINE, 2010; HERNÀNDEX-CAMPOY; CONDE SILVESTRE, 2014, the results expound the representativeness of Gender and Age group as significant social categories for research on the variable imperative grammatical expression of the second person singular. Following the orientation of Labov’s methodological quantitative sociolinguistic analysis (LABOV, 1994,2001, is confirmed the hypothesis that the abrasileirado imperative, in terms of Scherre (2007, tends become established in Brazilian Portugueseas young people seemed be heading in the historic direction of change inprogress.

  9. The environmental imperative for renewable energy

    International Nuclear Information System (INIS)

    Serchuk, Adam

    2000-01-01

    This article assesses the report by the Renewable Energy Policy Project entitled 'The Environmental Imperative: A Driving Force in the Development and Deployment of Renewable Energy Technologies', and focuses on the environmental impacts of the generation of electricity including air pollution, climate change, land and water pollution, the threat to wildlife, and the risk of radiation from commercial nuclear power plants. A table is presented illustrating the air pollution, climate change, land use and degradation, water use and quality, wildlife and radiation effects from the use of coal, oil, natural gas, biomass, wind, photovoltaic, geothermal, hydroelectric and nuclear power

  10. Beyond School Boundaries: New Health Imperatives, Families and Schools

    Science.gov (United States)

    Rich, Emma

    2012-01-01

    This article draws upon research examining the impact of new health imperatives on schools in the United Kingdom. Specifically, it examines features of emerging surveillant relations, which not only speak to the changing nature of health-related practices in schools but have particular currency for broader understandings of theorisations of…

  11. Are Kant's categorical imperative and instrumental rationality incompatible? The case for the prisoner's dilemma

    OpenAIRE

    Brinca, Pedro

    2005-01-01

    Why is good good and bad bad? Kant's categorical imperative (KCI) and instrumental rationality are analyzed under the game-theoretical framework of the folk theorem. Prescribing different courses of action under the one-shot game, Kant's categorical imperative emerges as instrumentally rational provided that the conditions of the folk theorem are observed and the norms and values underlying KCI are presented as selective advantages of the group of reference in which the individual belongs. No...

  12. Sleep: A Health Imperative

    Science.gov (United States)

    Luyster, Faith S.; Strollo, Patrick J.; Zee, Phyllis C.; Walsh, James K.

    2012-01-01

    Chronic sleep deficiency, defined as a state of inadequate or mistimed sleep, is a growing and underappreciated determinant of health status. Sleep deprivation contributes to a number of molecular, immune, and neural changes that play a role in disease development, independent of primary sleep disorders. These changes in biological processes in response to chronic sleep deficiency may serve as etiological factors for the development and exacerbation of cardiovascular and metabolic diseases and, ultimately, a shortened lifespan. Sleep deprivation also results in significant impairments in cognitive and motor performance which increase the risk of motor vehicle crashes and work-related injuries and fatal accidents. The American Academy of Sleep Medicine and the Sleep Research Society have developed this statement to communicate to national health stakeholders the current knowledge which ties sufficient sleep and circadian alignment in adults to health. Citation: Luyster FS; Strollo PJ; Zee PC; Walsh JK. Sleep: a health imperative. SLEEP 2012;35(6):727-734. PMID:22654183

  13. Declarative versus imperative process modeling languages : the issue of maintainability

    NARCIS (Netherlands)

    Fahland, D.; Mendling, J.; Reijers, H.A.; Weber, B.; Weidlich, M.; Zugal, S.; Rinderle-Ma, S.; Sadiq, S.; Leymann, F.

    2010-01-01

    The rise of interest in declarative languages for process modeling both justifies and demands empirical investigations into their presumed advantages over more traditional, imperative alternatives. Our concern in this paper is with the ease of maintaining business process models, for example due to

  14. Feminism and the Moral Imperative for Contraception.

    Science.gov (United States)

    Espey, Eve

    2015-08-01

    This commentary is adapted from the Irvin M. Cushner Memorial Lecture, "Feminism and the Moral Imperative for Contraception," given at 2014 Annual Clinical Meeting of the American College of Obstetricians and Gynecologists in Chicago. It provides a brief and simplified historical review of the feminist movement, primarily in the United States, focusing on feminism's association with contraception. This commentary reflects the perspective and opinions of the author. Contraception is fundamental to a woman's ability to achieve equality and realize her full social, economic, and intellectual potential.

  15. A Call for Strategic Planning: The Two-Year College Imperative.

    Science.gov (United States)

    Masoner, David J.; Essex, Nathan, L.

    1987-01-01

    Addresses the imperative for strategic and tactical planning to support the viability of the two-year college. Describes a process for approaching strategic planning, comprising the following steps: self-identification, self-analysis, analysis of service area, informed decision making, and the development of a marketing plan. (CBC)

  16. What girls won't do for love: human immunodeficiency virus/sexually transmitted infections risk among young African-American women driven by a relationship imperative.

    Science.gov (United States)

    Raiford, Jerris L; Seth, Puja; DiClemente, Ralph J

    2013-05-01

    Rates of Human immunodeficiency virus (HIV) and other sexually transmitted infections (STIs) continue to increase among African-American youth. Adolescents who have a stronger identity in relation to others (relational identity) rather than to themselves (self-identity) may view intimate relationships as imperative to a positive self-concept, which may lead to risky sexual behavior and abuse. Therefore, the present study assessed the associations among a relationship imperative and HIV/STI-related risk factors and behaviors. Participants were 715 African-American adolescent females, aged 15 to 21 years. They completed measures that assessed how important a relationship was to them and HIV-related risk factors and behaviors. Participants also provided vaginal swab specimens for STI testing. Multivariate logistic regression analyses, controlling for covariates, were conducted. Females who endorsed a relationship imperative (29%), compared to those who did not, were more likely to report: unprotected sex, less power in their relationships, perceived inability to refuse sex, anal sex, sex while their partner was high on alcohol/drugs, and partner abuse. Furthermore, participants with less power, recent partner abuse, and a perceived ability to refuse sex were more likely to test STI positive. These results indicate that if African-American adolescent females believe a relationship is imperative, they are more likely to engage in riskier sexual behaviors. Additionally, less perceived power and partner abuse increases their risk for STIs. HIV/STI prevention programs should target males and females and address healthy relationships, sense of self-worth, self-esteem and the gender power imbalance that may persist in the community along with HIV/STI risk. Published by Elsevier Inc.

  17. On the Contradiction in Conception Test of the Categorical Imperative

    African Journals Online (AJOL)

    The author argues against Christine Korsgaard\\'s influential interpretation of. Kant\\'s contradiction in conception test of the categorical imperative. Korsgaard\\'s rejection of the 'teleological' interpretation is shown to be based on a misunderstanding of the role that teleology plays for Kant in ruling out immoral maxims, and her ...

  18. Cultural Identity Forum: Enacting the Self-Awareness Imperative in Intercultural Communication

    Science.gov (United States)

    Anderson-Lain, Karen

    2017-01-01

    Courses: Intercultural Communication; any course with an intercultural communication unit. Objectives: Students will demonstrate the self-awareness imperative in intercultural communication, explore their own cultural identities, and reflect on others cultural identities in order to build their intercultural communication competence.

  19. Religious and sacred imperatives in human conflict.

    Science.gov (United States)

    Atran, Scott; Ginges, Jeremy

    2012-05-18

    Religion, in promoting outlandish beliefs and costly rituals, increases ingroup trust but also may increase mistrust and conflict with outgroups. Moralizing gods emerged over the last few millennia, enabling large-scale cooperation, and sociopolitical conquest even without war. Whether for cooperation or conflict, sacred values, like devotion to God or a collective cause, signal group identity and operate as moral imperatives that inspire nonrational exertions independent of likely outcomes. In conflict situations, otherwise mundane sociopolitical preferences may become sacred values, acquiring immunity to material incentives. Sacred values sustain intractable conflicts that defy "business-like" negotiation, but also provide surprising opportunities for resolution.

  20. Stability of pharmaceutical salts in solid oral dosage forms.

    Science.gov (United States)

    Nie, Haichen; Byrn, Stephen R; Zhou, Qi Tony

    2017-08-01

    Using pharmaceutical salts in solid dosage forms can raise stability concerns, especially salt dissociation which can adversely affect the product performance. Therefore, a thorough understanding of the salt instability encountered in solid-state formulations is imperative to ensure the product quality. The present article uses the fundamental theory of acid base, ionic equilibrium, relationship of pH and solubility as a starting point to illustrate and interpret the salt formation and salt disproportionation in pharmaceutical systems. The criteria of selecting the optimal salt form and the underlying theory of salt formation and disproportionation are reviewed in detail. Factors influencing salt stability in solid dosage forms are scrutinized and discussed with the case studies. In addition, both commonly used and innovative strategies for preventing salt dissociations in formulation, on storage and during manufacturing will be suggested herein. This article will provide formulation scientists and manufacturing engineers an insight into the mechanisms of salt disproportionation and salt formation, which can help them to avoid and solve the instability issues of pharmaceutical salts in the product design.

  1. Imperatives of Socio-Religious Measures in Solving the Crisis in ...

    African Journals Online (AJOL)

    This study therefore, seeks to explore the imperative for socio-religious measures in solving the violence, conflicts and war (ISRMSCW) in the country. It looks at the causative factors of crisis and conflict and the implications of the incessant conflicts in Nigeria. In terms of methodology, the data used includes both primary and ...

  2. Determination of plutonium isotopes in waters and environmental solids: A review

    DEFF Research Database (Denmark)

    Qiao, Jixin; Hou, Xiaolin; Miró, Manuel

    2009-01-01

    A number of analytical methods have been developed in the past few years for environmental monitoring of plutonium (Pu) isotopes around nuclear facilities within protocols for emergency preparedness as well as for risk assessment of contaminated areas resulting from nuclear weapon tests, nuclear...... accidents, and the discharge of nuclear waste. This article summarizes and critically compares recently reported methods for determination of Pu isotopes in waters and environmental solid substrates, in which sample pre-treatment is imperative for separation of the target species from matrix ingredients and...

  3. Food security in the MENA region: the imperative rehabilitation of ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    21 حزيران (يونيو) 2013 ... Food security in the MENA region: the imperative rehabilitation of agriculture ... Overcoming the food security challenge necessarily requires sustainably ... Local climate change data is securing food and livelihoods in southern Africa ... Copyright · Open access policy · Privacy policy · Research ethics ...

  4. Avian and pandemic human influenza policy in South-East Asia: the interface between economic and public health imperatives.

    Science.gov (United States)

    Pongcharoensuk, Petcharat; Adisasmito, Wiku; Sat, Le Minh; Silkavute, Pornpit; Muchlisoh, Lilis; Cong Hoat, Pham; Coker, Richard

    2012-08-01

    The aim of this study was to analyse the contemporary policies regarding avian and human pandemic influenza control in three South-East Asia countries: Thailand, Indonesia and Vietnam. An analysis of poultry vaccination policy was used to explore the broader policy of influenza A H5N1 control in the region. The policy of antiviral stockpiling with oseltamivir, a scarce regional resource, was used to explore human pandemic influenza preparedness policy. Several policy analysis theories were applied to analyse the debate on the use of vaccination for poultry and stockpiling of antiviral drugs in each country case study. We conducted a comparative analysis across emergent themes. The study found that whilst Indonesia and Vietnam introduced poultry vaccination programmes, Thailand rejected this policy approach. By contrast, all three countries adopted similar strategic policies for antiviral stockpiling in preparation. In relation to highly pathogenic avian influenza, economic imperatives are of critical importance. Whilst Thailand's poultry industry is large and principally an export economy, Vietnam's and Indonesia's are for domestic consumption. The introduction of a poultry vaccination policy in Thailand would have threatened its potential to trade and had a major impact on its economy. Powerful domestic stakeholders in Vietnam and Indonesia, by contrast, were concerned less about international trade and more about maintaining a healthy domestic poultry population. Evidence on vaccination was drawn upon differently depending upon strategic economic positioning either to support or oppose the policy. With influenza A H5N1 endemic in some countries of the region, these policy differences raise questions around regional coherence of policies and the pursuit of an agreed overarching goal, be that eradication or mitigation. Moreover, whilst economic imperatives have been critically important in guiding policy formulation in the agriculture sector, questions arise

  5. Greenhouse gas emission and exergy analyses of an integrated trigeneration system driven by a solid oxide fuel cell

    International Nuclear Information System (INIS)

    Chitsaz, Ata; Mahmoudi, S. Mohammad S.; Rosen, Marc A.

    2015-01-01

    Exergy and greenhouse gas emission analyses are performed for a novel trigeneration system driven by a solid oxide fuel cell (SOFC). The trigeneration system also consists of a generator-absorber heat exchanger (GAX) absorption refrigeration system and a heat exchanger to produce electrical energy, cooling and heating, respectively. Four operating cases are considered: electrical power generation, electrical power and cooling cogeneration, electrical power and heating cogeneration, and trigeneration. Attention is paid to numerous system and environmental performance parameters, namely, exergy efficiency, exergy destruction rate, and greenhouse gas emissions. A maximum enhancement of 46% is achieved in the exergy efficiency when the SOFC is used as the primary mover for the trigeneration system compared to the case when the SOFC is used as a standalone unit. The main sources of irreversibility are observed to be the air heat exchanger, the SOFC and the afterburner. The unit CO 2 emission (in kg/MWh) is considerably higher for the case in which only electrical power is generated. This parameter is reduced by half when the system is operates in a trigeneration mode. - Highlights: • A novel trigeneration system driven by a solid oxide fuel cell is analyzed. • Exergy and greenhouse gas emission analyses are performed. • Four special cases are considered. • An enhancement of up to 46% is achieved in exergy efficiency. • The CO 2 emission drops to a relatively low value for the tri-generation case

  6. Automated headspace solid-phase dynamic extraction to analyse the volatile fraction of food matrices.

    Science.gov (United States)

    Bicchi, Carlo; Cordero, Chiara; Liberto, Erica; Rubiolo, Patrizia; Sgorbini, Barbara

    2004-01-23

    High concentration capacity headspace techniques (headspace solid-phase microextraction (HS-SPME) and headspace sorptive extraction (HSSE)) are a bridge between static and dynamic headspace, since they give high concentration factors as does dynamic headspace (D-HS), and are as easy to apply and as reproducible as static headspace (S-HS). In 2000, Chromtech (Idstein, Germany) introduced an inside-needle technique for vapour and liquid sampling, solid-phase dynamic extraction (SPDE), also known as "the magic needle". In SPDE, analytes are concentrated on a 50 microm film of polydimethylsiloxane (PDMS) and activated carbon (10%) coated onto the inside wall of the stainless steel needle (5 cm) of a 2.5 ml gas tight syringe. When SPDE is used for headspace sampling (HS-SPDE), a fixed volume of the headspace of the sample under investigation is sucked up an appropriate number of times with the gas tight syringe and an analyte amount suitable for a reliable GC or GC-MS analysis accumulates in the polymer coating the needle wall. This article describes the preliminary results of both a study on the optimisation of sampling parameters conditioning HS-SPDE recovery, through the analysis of a standard mixture of highly volatile compounds (beta-pinene, isoamyl acetate and linalool) and of the HS-SPDE-GC-MS analyses of aromatic plants and food matrices. This study shows that HS-SPDE is a successful technique for HS-sampling with high concentration capability, good repeatability and intermediate precision, also when it is compared to HS-SPME.

  7. STRATEGIC IMPERATIVES OF THE DEVELOPMENT OF THE SCIENTIFIC LIBRARY OF THE RESEARCH UNIVERSITY

    Directory of Open Access Journals (Sweden)

    M. Sitnitskiy

    2017-09-01

    Full Text Available The article presents strategic imperatives that influence the development of scientific libraries and systematizes the criteria that the scientific library of the research university must meet in order to ensure effective development in accordance with modern trends in science and technology. Strategic imperatives for the development of the library of the research university consist in providing: modern technologies of codification and transfer of information containing knowledge; Compliance with international standards of existing information and technical infrastructure of scientific libraries; Equal access to world-class advanced science-computer databases; Timely updating of library funds; Proactive visitor system and automate the processing of relevance of their queries; The fastest and most accurate search and access to information; availability of an effective information security system contained in the cloud of scientific library; Development of adjacent commercial services, which allow to receive a "package" of information generalized by professional specialists; Creation of creative space for a comfortable visit to the library by interested persons for obtaining existing knowledge and creating new ones. The only way for Ukraine to slow down the outflow of skilled scientific and pedagogical staff and students with high intellectual potential is to preserve and balance the system of research universities and to develop within their walls powerful scientific libraries that will be able to meet the above-mentioned development imperatives.

  8. Modular 3-D solid finite element model for fatigue analyses of a PWR coolant system

    International Nuclear Information System (INIS)

    Garrido, Oriol Costa; Cizelj, Leon; Simonovski, Igor

    2012-01-01

    Highlights: ► A 3-D model of a reactor coolant system for fatigue usage assessment. ► The performed simulations are a heat transfer and stress analyses. ► The main results are the expected ranges of fatigue loadings. - Abstract: The extension of operational licenses of second generation pressurized water reactor (PWR) nuclear power plants depends to a large extent on the analyses of fatigue usage of the reactor coolant pressure boundary. The reliable estimation of the fatigue usage requires detailed thermal and stress analyses of the affected components. Analyses, based upon the in-service transient loads should be compared to the loads analyzed at the design stage. The thermal and stress transients can be efficiently analyzed using the finite element method. This requires that a 3-D solid model of a given system is discretized with finite elements (FE). The FE mesh density is crucial for both the accuracy and the cost of the analysis. The main goal of the paper is to propose a set of computational tools which assist a user in a deployment of modular spatial FE model of main components of a typical reactor coolant system, e.g., pipes, pressure vessels and pumps. The modularity ensures that the components can be analyzed individually or in a system. Also, individual components can be meshed with different mesh densities, as required by the specifics of the particular transient studied. For optimal accuracy, all components are meshed with hexahedral elements with quadratic interpolation. The performance of the model is demonstrated with simulations performed with a complete two-loop PWR coolant system (RCS). Heat transfer analysis and stress analysis for a complete loading and unloading cycle of the RCS are performed. The main results include expected ranges of fatigue loading for the pipe lines and coolant pump components under the given conditions.

  9. "Notice the Similarities between the Two Sets …": Imperative Usage in a Corpus of Upper-Level Student Papers

    Science.gov (United States)

    Neiderhiser, Justine A.; Kelley, Patrick; Kennedy, Kohlee M.; Swales, John M.; Vergaro, Carla

    2016-01-01

    The sparse literature on the use of imperatives in research papers suggests that they are relatively common in a small number of disciplines, but rare, if used at all, in others. The present study addresses the use of imperatives in a corpus of upper-level A-graded student papers from 16 disciplines. A total of 822 papers collected within the past…

  10. New Mandates and Imperatives in the Revised "ACA Code of Ethics"

    Science.gov (United States)

    Kaplan, David M.; Kocet, Michael M.; Cottone, R. Rocco; Glosoff, Harriet L.; Miranti, Judith G.; Moll, E. Christine; Bloom, John W.; Bringaze, Tammy B.; Herlihy, Barbara; Lee, Courtland C.; Tarvydas, Vilia M.

    2009-01-01

    The first major revision of the "ACA Code of Ethics" in a decade occurred in late 2005, with the updated edition containing important new mandates and imperatives. This article provides interviews with members of the Ethics Revision Task Force that flesh out seminal changes in the revised "ACA Code of Ethics" in the areas of confidentiality,…

  11. Solar Energy Gain and Space-Heating Energy Supply Analyses for Solid-Wall Dwelling Retrofitted with the Experimentally Achievable U-value of Novel Triple Vacuum Glazing

    Directory of Open Access Journals (Sweden)

    Saim Memon

    2017-06-01

    Full Text Available A considerable effort is devoted to devising retrofit solutions for reducing space-heating energy in the domestic sector. Existing UK solid-wall dwellings, which have both heritage values and historic fabric, are being improved but they tend to have meagre thermal performance, partly, due to the heat-loss through glazings. This paper takes comparative analyses approach to envisage space-heating supply required in order to maintain thermal comfort temperatures and attainable solar energy gains to households with the retrofit of an experimentally achievable thermal performance of the fabricated sample of triple vacuum glazing to a UK solid-wall dwelling. 3D dynamic thermal models (timely regimes of heating, occupancy, ventilation and internal heat gains of an externally-insulated solid-wall detached dwelling with a range of existing glazing types along with triple vacuum glazings are modelled. A dramatic decrease of space-heating load and moderate increase of solar gains are resulted with the dwelling of newly achievable triple vacuum glazings (having centre-of-pane U-value of 0.33 Wm-2K-1 compared to conventional glazing types. The space-heating annual cost of single glazed dwellings was minimised to 15.31% (≈USD 90.7 with the retrofit of triple-vacuum glazings. An influence of total heat-loss through the fabric of solid-wall dwelling was analysed with steady-state calculations which indicates a fall of 10.23 % with triple vacuum glazings compared to single glazings.

  12. Jacques Lacan’s “Kant with Sade”: renunciation to desire and sadism in the Kantian categorical imperative

    Directory of Open Access Journals (Sweden)

    Francisco Conde Soto

    2017-06-01

    Full Text Available The aim of this study is to evaluate the juxtaposition of Kant’s categorical imperative with Sade’s maxim exposed in several texts of the French psychoanalyst Jacques Lacan. According to Lacan Kant and Sade are two sides of the same coin in reference to their position with respect to desire and enjoyment. His thesis are: 1. Sade’s maxim that the libertine is entitled to vex his neighbor as he pleases essentially meets the requirements of Kant’s categorical imperative. 2. Both Sade and Kant’s theories are examples of only one sadism directed at other subjects the first and directed toward himself in the form of moral duty the second. Reading The Ethics of Psychoanalysis (1959-60 and especially the text “Kant with Sade” (1966 is exposed Lacan’s critique of the categorical imperative of Kant, taken as a paradigm of what it means to be moral.

  13. A knowledge acquisition process to analyse operational problems in solid waste management facilities.

    Science.gov (United States)

    Dokas, Ioannis M; Panagiotakopoulos, Demetrios C

    2006-08-01

    The available expertise on managing and operating solid waste management (SWM) facilities varies among countries and among types of facilities. Few experts are willing to record their experience, while few researchers systematically investigate the chains of events that could trigger operational failures in a facility; expertise acquisition and dissemination, in SWM, is neither popular nor easy, despite the great need for it. This paper presents a knowledge acquisition process aimed at capturing, codifying and expanding reliable expertise and propagating it to non-experts. The knowledge engineer (KE), the person performing the acquisition, must identify the events (or causes) that could trigger a failure, determine whether a specific event could trigger more than one failure, and establish how various events are related among themselves and how they are linked to specific operational problems. The proposed process, which utilizes logic diagrams (fault trees) widely used in system safety and reliability analyses, was used for the analysis of 24 common landfill operational problems. The acquired knowledge led to the development of a web-based expert system (Landfill Operation Management Advisor, http://loma.civil.duth.gr), which estimates the occurrence possibility of operational problems, provides advice and suggests solutions.

  14. On the applicability of probabilistic analyses to assess the structural reliability of materials and components for solid-oxide fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Lara-Curzio, Edgar [ORNL; Radovic, Miladin [Texas A& M University; Luttrell, Claire R [ORNL

    2016-01-01

    The applicability of probabilistic analyses to assess the structural reliability of materials and components for solid-oxide fuel cells (SOFC) is investigated by measuring the failure rate of Ni-YSZ when subjected to a temperature gradient and comparing it with that predicted using the Ceramics Analysis and Reliability Evaluation of Structures (CARES) code. The use of a temperature gradient to induce stresses was chosen because temperature gradients resulting from gas flow patterns generate stresses during SOFC operation that are the likely to control the structural reliability of cell components The magnitude of the predicted failure rate was found to be comparable to that determined experimentally, which suggests that such probabilistic analyses are appropriate for predicting the structural reliability of materials and components for SOFCs. Considerations for performing more comprehensive studies are discussed.

  15. Analyse des solides déformables par la méthode des éléments finis

    CERN Document Server

    Bonnet, Marc

    2006-01-01

    Cet ouvrage propose une présentation structurée de la formulation et la mise en œuvre de la simulation numérique par éléments finis en mécanique des solides déformables. Il présente et développe les concepts et techniques permettant la transposition, en termes de codes de calcul de structures mécaniques industrielles, des notions fondamentales de mécanique des milieux continus solides, et ce dans le cadre d'analyses en régimes (a) statique linéaire, (b) quasistatique non-linéaire et (c) dynamique linéaire. L'exposé théorique est complété et illustré au moyen de programmes d'initiation écrits en Matlab (librement accessibles par Internet) mettant en œuvre les notions développées dans cet ouvrage et conçus comme support pratique à un enseignement. Le texte combine ainsi l'exposition des principes et des méthodes avec la présentation détaillée de ces programmes et d'exemples les mettant en œuvre. L'ouvrage est complété d'une annexe écrite par Andrei Constantinescu (directeur de...

  16. A Formalization of Kant's Second Formulation of the Categorical Imperative

    OpenAIRE

    Lindner, Felix; Bentzen, Martin Mose

    2018-01-01

    We present a formalization and computational implementation of the second formulation of Kant's categorical imperative. This ethical principle requires an agent to never treat someone merely as a means but always also as an end. Here we interpret this principle in terms of how persons are causally affected by actions. We introduce Kantian causal agency models in which moral patients, actions, goals, and causal influence are represented, and we show how to formalize several readings of Kant's ...

  17. Building an IDE for the Calculational Derivation of Imperative Programs

    Directory of Open Access Journals (Sweden)

    Dipak L. Chaudhari

    2015-08-01

    Full Text Available In this paper, we describe an IDE called CAPS (Calculational Assistant for Programming from Specifications for the interactive, calculational derivation of imperative programs. In building CAPS, our aim has been to make the IDE accessible to non-experts while retaining the overall flavor of the pen-and-paper calculational style. We discuss the overall architecture of the CAPS system, the main features of the IDE, the GUI design, and the trade-offs involved.

  18. Solid waste as an energy source

    International Nuclear Information System (INIS)

    Armenski, Slave

    2004-01-01

    The solid wastes as sources of heat and electrical energy were analysed. Typical structure of solid waste and organic products from: municipal solid wastes, industrial wastes and agricultural wastes for some developed countries are presented. Some dates of agricultural wastes for R. Macedonia are presented. The structure and percentage of organic products and energy content of solid wastes are estimated. The quantity of heat from solid wastes depending of the waste mass is presented. The heat quantity of some solid wastes component and the mixed municipal waste is presented. (Original)

  19. The Nuclear Imperative in Russia’s Security Strategy

    Directory of Open Access Journals (Sweden)

    J. Oscar Alvarez Calzada

    2005-10-01

    Full Text Available The process which culminated in the disappearance of the USSR was heavily influenced by that Soviet Union’s inability to maintain the level of technology reached by the US in the arms race. Under the circumstances of deteriorating Russian power which have been developing since 1991, and given the precariousness that affects its armed forces, nuclear weapons have become the core element of the Russian Federation’s national security strategy. This article explores the causes that have led to this nuclear imperative in Russia’s security strategy; and secondly, it presents the most relevant, and worrying, consequence that this dependence has generated, which is the lowering of the threshold necessary forthe use of nuclear weapons.

  20. Non-Blocking Concurrent Imperative Programming with Session Types

    Directory of Open Access Journals (Sweden)

    Miguel Silva

    2017-01-01

    Full Text Available Concurrent C0 is an imperative programming language in the C family with session-typed message-passing concurrency. The previously proposed semantics implements asynchronous (non-blocking output; we extend it here with non-blocking input. A key idea is to postpone message reception as much as possible by interpreting receive commands as a request for a message. We implemented our ideas as a translation from a blocking intermediate language to a non-blocking language. Finally, we evaluated our techniques with several benchmark programs and show the results obtained. While the abstract measure of span always decreases (or remains unchanged, only a few of the examples reap a practical benefit.

  1. An Imperative Type Hierarchy with Partial Products

    DEFF Research Database (Denmark)

    Schwartzbach, Michael Ignatieff; Schmidt, Erik Meineche

    1989-01-01

    notation for defining recursive types, that is superior to traditional type sums and products. We show how the ordering on types extends to an ordering on types with invariants. We allow the use of least upper bounds in type definitions and show how to compute upper bounds of invariants.......A type hierarchy for a programming language defines an ordering on the types such that any application for small types may be reused for all larger types. The imperative facet makes this non-trivial; the straight-forward definitions will yield an inconsistent system. We introduce a new type...... constructor, the partial product, and show how to define a consistent hierarchy in the context of fully recursive types. A simple polymorphism is derived by introducing a notion of placeholder types. By extending the partial product types to include structural invariants we obtain a particularly appropriate...

  2. Imperatives of Information and Communication Technology (ICT) for Second Language Learners and Teachers

    Science.gov (United States)

    Akinwamide, Timothy Kolade

    2012-01-01

    The introduction of information and communication technology (ICT) to education creates new learning paradigms. We are dwelling in a world which technology has reduced to a global village and the breakthrough in technology is underpinning pedagogical submissions. It may become imperative therefore to have a rethinking on how to ameliorate the…

  3. Predación por peces sobre Anax imperator asociada a la reproducción de éste (Odonata: Aeshnidae)

    OpenAIRE

    Torralba Burrial, Antonio; Ocharan Larrondo, Francisco Javier

    2003-01-01

    Se informa de observaciones sobre predación por parte del pez alóctono Micropterus salmoides sobre Anax imperator (Odonata: Aeshnidae). Los ataques observados están asociados a la actividad reproductiva de la libélula, y representan un coste asociado a dicha reproducción que afecta, por distintos motivos, a ambos sexos. Predation by fish associated with reproduction in Anax imperator (Odonata, Aeshnidae) Abstract: Instances of predation by the non-native fish Micropterus salmoides on Anax imp...

  4. The Ethical Imperative of Reason: How Anti-Intellectualism, Denialism, and Apathy Threaten National Security

    Science.gov (United States)

    2016-03-01

    imperative for “reason” and factual discussion to rule the policy process. 14. SUBJECT TERMS ethics, philosophy , reason, anti-intellectualism...opinion, public trust, science, scientific process, discurisive reasoning, morality , technology, futurology, Aristole, Sagan, Hofstader, Kant, Ross 15...9 D. CONCLUSION ........................................................................................10 III. PHILOSOPHY AND

  5. Economic Imperative of Global Community Establishment

    Directory of Open Access Journals (Sweden)

    Deyneka Tatyana

    2017-12-01

    Full Text Available Modern global society is becoming increasingly controversial. Under such conditions, the question of prospects for life of megasociety, which demands theoretical and methodological research from the economic science, as well as a thorough analysis of empiricists, becomes of special relevance. The publication presents the concept of systemic transformation of the global economy and global community. The following is defined: subsystems (spheres of transformed community system (economic, political, social, spiritual; objects of transformation, the change of which is essential for the acquisition of a new quality by the system; causes and determinants of system transformation. Based on this, it is proved that the system of world community harmonized in its internal composition is integrity, each of its subsystems corresponds to the imperative of humanism. If this equirement is fulfilled, the world community will be able to move to a higher level of civilization development. In the process of studying transformation of the global society, a methodology has been used to identify these changes in the mega-society and describe them with a model. Choosing the defining parameters of the model allowed to answer the following questions: what is the purpose of humanity, radically changing its life; what are the structural transformations; in what way will community evolve; how the relations in such a society will be institutionalized. On the basis of the applied theory and methodology, the following is substantiated: The purpose of social dynamics is the comprehensive development of man and the creation of a society based on the principles of noosphere; changes in the structure of social system occur simultaneously with changes in subsystems and are subject to the imperative of continuous enrichment of the potential of society development; innovation as a basis for social reproduction in all its spheres is a way of society evolving; the systematic

  6. The recovery imperative: a critical examination of mid-life women's recovery from depression.

    Science.gov (United States)

    O'Brien, Wendy

    2012-08-01

    Australia, like other countries in neo-liberal democracies, is grappling with the gendered health 'problem' of depression. More concerning is the issue of recovery and relapse, with depression being the third largest cause of disability-adjusted life years (DALY). In addition, advanced liberal discourses of health position recovery as an exercise of individual responsibility to return to a functioning and productive norm and prevent recurrence. This moral enterprise of health articulates a 'recovery imperative' which overlooks the gendered context which may have created the conditions for women's depression and may in turn impede their recovery. Drawing on insights from governmentality and feminist post-structuralism, the article critically examines the effects of normalized recovery discourses on women's subjectivities. Data for the study were collected between 2005 and 2007 through in-depth interviews with 31 mid-life Australian women. Three key themes; 'in' recovery, 'eight out of ten' recovered, and recovering the authentic self, illustrate how the 'recovery imperative' may be implicated in perpetuating the cycle of recovery and relapse. Copyright © 2012 Elsevier Ltd. All rights reserved.

  7. Thermodynamic analyses of municipal solid waste gasification plant integrated with solid oxide fuel cell and Stirling hybrid system

    DEFF Research Database (Denmark)

    Rokni, Masoud

    2015-01-01

    the plant efficiency in terms of operating conditions. Compared with modern waste incinerators with heat recovery, the gasification process integrated with SOFC and Stirling engine permits an increase in electricity output up of 50%, which means that the solid waste gasification process can compete......Municipal solid waste (MSW) can be considered a valid biomass to be used in a power plant. The major advantage is the reduction of pollutants and greenhouse gases emissions not only within large cities but also globally. Another advantage is that by their use it is possible to reduce the waste...... storage in landfills and devote these spaces to other human activities. It is also important to point out that this kind of renewable energy suffers significantly less availability which characterizes other type of renewable energy sources such as in wind and solar energy.In a gasification process, waste...

  8. Municipal solid waste composition: Sampling methodology, statistical analyses, and case study evaluation

    DEFF Research Database (Denmark)

    Edjabou, Vincent Maklawe Essonanawe; Jensen, Morten Bang; Götze, Ramona

    2015-01-01

    Sound waste management and optimisation of resource recovery require reliable data on solid waste generation and composition. In the absence of standardised and commonly accepted waste characterisation methodologies, various approaches have been reported in literature. This limits both...... comparability and applicability of the results. In this study, a waste sampling and sorting methodology for efficient and statistically robust characterisation of solid waste was introduced. The methodology was applied to residual waste collected from 1442 households distributed among 10 individual sub......-areas in three Danish municipalities (both single and multi-family house areas). In total 17 tonnes of waste were sorted into 10-50 waste fractions, organised according to a three-level (tiered approach) facilitating,comparison of the waste data between individual sub-areas with different fractionation (waste...

  9. Time-frequency analyses of fluid-solid interaction under sinusoidal translational shear deformation of the viscoelastic rat cerebrum

    Science.gov (United States)

    Leahy, Lauren N.; Haslach, Henry W.

    2018-02-01

    During normal extracellular fluid (ECF) flow in the brain glymphatic system or during pathological flow induced by trauma resulting from impacts and blast waves, ECF-solid matter interactions result from sinusoidal shear waves in the brain and cranial arterial tissue, both heterogeneous biological tissues with high fluid content. The flow in the glymphatic system is known to be forced by pulsations of the cranial arteries at about 1 Hz. The experimental shear stress response to sinusoidal translational shear deformation at 1 Hz and 25% strain amplitude and either 0% or 33% compression is compared for rat cerebrum and bovine aortic tissue. Time-frequency analyses aim to correlate the shear stress signal frequency components over time with the behavior of brain tissue constituents to identify the physical source of the shear nonlinear viscoelastic response. Discrete fast Fourier transformation analysis and the novel application to the shear stress signal of harmonic wavelet decomposition both show significant 1 Hz and 3 Hz components. The 3 Hz component in brain tissue, whose magnitude is much larger than in aortic tissue, may result from interstitial fluid induced drag forces. The harmonic wavelet decomposition locates 3 Hz harmonics whose magnitudes decrease on subsequent cycles perhaps because of bond breaking that results in easier fluid movement. Both tissues exhibit transient shear stress softening similar to the Mullins effect in rubber. The form of a new mathematical model for the drag force produced by ECF-solid matter interactions captures the third harmonic seen experimentally.

  10. A solid-on-solid invasion percolation model for self-affine interfaces

    International Nuclear Information System (INIS)

    Arizmendi, C.M.; Martin, H.O.; Sanchez, J.R.

    1993-08-01

    The scaling properties of the interface of a new growth model are studied. The model is based on the standard invasion percolation without trapping in which the solid-on-solid condition is imposed. The local correlation between points of the interface can be controlled through a parameter. The self-affine properties of the interface show strong dependence on the existence of the local correlation. The dependence of the relevant exponents of the interface with the correlation is analysed. (author). 8 refs, 4 figs

  11. Landfill mining: Resource potential of Austrian landfills--Evaluation and quality assessment of recovered municipal solid waste by chemical analyses.

    Science.gov (United States)

    Wolfsberger, Tanja; Aldrian, Alexia; Sarc, Renato; Hermann, Robert; Höllen, Daniel; Budischowsky, Andreas; Zöscher, Andreas; Ragoßnig, Arne; Pomberger, Roland

    2015-11-01

    Since the need for raw materials in countries undergoing industrialisation (like China) is rising, the availability of metal and fossil fuel energy resources (like ores or coal) has changed in recent years. Landfill sites can contain considerable amounts of recyclables and energy-recoverable materials, therefore, landfill mining is an option for exploiting dumped secondary raw materials, saving primary sources. For the purposes of this article, two sanitary landfill sites have been chosen for obtaining actual data to determine the resource potential of Austrian landfills. To evaluate how pretreating waste before disposal affects the resource potential of landfills, the first landfill site has been selected because it has received untreated waste, whereas mechanically-biologically treated waste was dumped in the second. The scope of this investigation comprised: (1) waste characterisation by sorting analyses of recovered waste; and (2) chemical analyses of specific waste fractions for quality assessment regarding potential energy recovery by using it as solid recovered fuels. The content of eight heavy metals and the net calorific values were determined for the chemical characterisation tests. © The Author(s) 2015.

  12. Noospheric ecological imperative in culture of technocratic society

    Science.gov (United States)

    Shantarin, V. D.; Bezzubtseva, N. A.; Zemenkov, Yu D.

    2018-05-01

    Technogenic, dynamic and mobile civilization has been in a state of systemic ecological and economic crisis for several decades. Numerous studies of its origins and causes show that the culture of a technocratic society associated with a quantitative increase in consumption has exhausted its capabilities and proved incapable of alleviating the sustainable future of humankind. Comprehension of this problem gives grounds to believe that its solvation is largely predetermined by the formation of a new culture, the core of which is the noospheric ecological imperative: only the thing that does not violate the natural balance is allowed. Life in the conditions of imposed restrictions is connected with the change of worldview attitudes of society, understanding the ideas of noospheregenesis and eco-centrism, the need for strict regulation, economy and conscious restriction of consumption.

  13. Frequent Statement and Dereference Elimination for Imperative and Object-Oriented Distributed Programs

    Science.gov (United States)

    El-Zawawy, Mohamed A.

    2014-01-01

    This paper introduces new approaches for the analysis of frequent statement and dereference elimination for imperative and object-oriented distributed programs running on parallel machines equipped with hierarchical memories. The paper uses languages whose address spaces are globally partitioned. Distributed programs allow defining data layout and threads writing to and reading from other thread memories. Three type systems (for imperative distributed programs) are the tools of the proposed techniques. The first type system defines for every program point a set of calculated (ready) statements and memory accesses. The second type system uses an enriched version of types of the first type system and determines which of the ready statements and memory accesses are used later in the program. The third type system uses the information gather so far to eliminate unnecessary statement computations and memory accesses (the analysis of frequent statement and dereference elimination). Extensions to these type systems are also presented to cover object-oriented distributed programs. Two advantages of our work over related work are the following. The hierarchical style of concurrent parallel computers is similar to the memory model used in this paper. In our approach, each analysis result is assigned a type derivation (serves as a correctness proof). PMID:24892098

  14. Medium-energy ion reflection from solids

    CERN Document Server

    Mashkova, ES

    1985-01-01

    ``Medium-Energy Ion Reflection from Solids'' analyses the results of experimental, theoretical and computer investigations on the process of scattering of ions by solid surfaces. Surface scattering is a relatively young and rapidly developing branch of the physics of atomic collisions and the literature on this subject has rapidly grown.As the first monograph devoted specifically to surface scattering of ions, this book is directed at scientists involved in ion-solid interaction studies.

  15. characterization and composition analysis of municipal solid waste

    African Journals Online (AJOL)

    userpc

    ABSTRACT. Municipal Solid Waste (MSW) is produced through human activities and in the last two ... Solid waste samples were collected and analysed from the four major dumpsites in ..... Technology, Ueberlandstrasse 133,. Switzerland.

  16. Overview of PAT process analysers applicable in monitoring of film coating unit operations for manufacturing of solid oral dosage forms.

    Science.gov (United States)

    Korasa, Klemen; Vrečer, Franc

    2018-01-01

    Over the last two decades, regulatory agencies have demanded better understanding of pharmaceutical products and processes by implementing new technological approaches, such as process analytical technology (PAT). Process analysers present a key PAT tool, which enables effective process monitoring, and thus improved process control of medicinal product manufacturing. Process analysers applicable in pharmaceutical coating unit operations are comprehensibly described in the present article. The review is focused on monitoring of solid oral dosage forms during film coating in two most commonly used coating systems, i.e. pan and fluid bed coaters. Brief theoretical background and critical overview of process analysers used for real-time or near real-time (in-, on-, at- line) monitoring of critical quality attributes of film coated dosage forms are presented. Besides well recognized spectroscopic methods (NIR and Raman spectroscopy), other techniques, which have made a significant breakthrough in recent years, are discussed (terahertz pulsed imaging (TPI), chord length distribution (CLD) analysis, and image analysis). Last part of the review is dedicated to novel techniques with high potential to become valuable PAT tools in the future (optical coherence tomography (OCT), acoustic emission (AE), microwave resonance (MR), and laser induced breakdown spectroscopy (LIBS)). Copyright © 2017 Elsevier B.V. All rights reserved.

  17. The Strategic Imperative for the Use of Social Media in Health Care.

    Science.gov (United States)

    Kotsenas, Amy L; Arce, Makala; Aase, Lee; Timimi, Farris K; Young, Colleen; Wald, John T

    2018-01-01

    Although health care lags behind many other industries in adopting social media as part of a business strategy, the Mayo Clinic recognized the importance of these applications more than a decade ago. In addition to typical media relations and marketing tactics, the Mayo Clinic has successfully used social media as part of an overall program to support the strategic imperatives of the institution. Copyright © 2017 American College of Radiology. Published by Elsevier Inc. All rights reserved.

  18. From Kantian to Habersmanian Ethics: Socio-Juridical Implications of the Discursive Reconfigurationof the Categorical Imperative

    Directory of Open Access Journals (Sweden)

    Marcio Renan Hamel

    2011-11-01

    Full Text Available This article analyzes the reconstruction of Kant’s categoric imperative by Habermas’ discourse ethics. Various scientific methodologies were combined including deductive, typological, analytical and hermeneutic-phenomenological approaches. The deductive approach begins from the general theory about the issue to seek conclusions about particular situations. The typology approach focuses on the study of an ideal type used to create a model in reality. The analytical approach focuses on conceptual analysis and strives for a rigorous use of concepts. In the hermeneutic-phenomenological approach the fundamental epistemological category is comprehension and the goal is an interpretation of the facts. The text first presents a formulation of the categorical imperative and its consequences for human action and derived formulas. It then presents the Habermasian proposal for a discourse ethics, the principle of universalization and the reduction of ethical action to monological action. Finally, it establishes a relation between the two theoretical-philosophical positions and the socio-juridical consequences of Habermasian ethics for a Theory of Society.

  19. Imperatives for using plutonium in commercial power reactors

    International Nuclear Information System (INIS)

    Sandquist, G.M.; Kunze, J.F.

    1995-01-01

    The use of reprocessed or newly produced plutonium as a fissile fuel in commercial nuclear reactors in the US has been actively suppressed by the current US Administration. Yet, many other advanced nations have already adopted mixed oxide fuels which are manufactured from a mixture of plutonium and natural uranium compounds. These nations have successfully proven the use of such nuclear fuel in their commercial power reactors for many years. The full consequence of the restrictive nuclear policy in the US will greatly limit the lifetime of the nuclear fuel resources in the US from a nominal potential of 100 centuries or more of potential energy supply to about 50 years or less at economical prices for uranium. This paper addresses both the imperatives and the potential and the perceived hazards of plutonium utilization and examines the consequences of government policy regarding utilization of nuclear power

  20. The Syntax of Imperatives in English and Germanic Word Order Variation in the Minimalist Framework

    NARCIS (Netherlands)

    Rupp, L.M.

    2002-01-01

    This book examines several aspects of the syntax of imperative clauses in English and in a variety of other Germanic languages in the context of the challenge that apparent optional movement poses for the Minimalist Program. At a more general level, the book engages in current debate on one of the

  1. Nonprescription analgesics and their use in solid-organ transplantation: a review.

    Science.gov (United States)

    Gabardi, Steven; Luu, Linh

    2004-09-01

    To review the pharmacology, adverse events, drug interactions, and use of the nonprescription analgesics in solid-organ transplant recipients. Studies evaluating nonprescription analgesics in solid-organ transplantation were considered for evaluation. English-language studies were selected for inclusion. Nonprescription analgesics (aspirin, choline salicylate, magnesium salicylate, sodium salicylate, ibuprofen, ketoprofen, naproxen sodium, and acetaminophen) are the most commonly purchased over-the-counter agents in the United States. These agents, although generally considered safe, have been associated with a number of toxicities. The salicylates and nonsteroidal anti-inflammatory drugs have been associated with gastrointestinal damage, hematologic changes, liver and kidney dysfunction, and breathing difficulties. Acetaminophen has been shown to induce hematologic changes and liver and renal dysfunction. A closer look at the nonprescription analgesics reveals their potential for harm when used by solid-organ transplant recipients. In this patient population, the salicylates and nonsteroidal anti-inflammatory drugs should generally be avoided if possible, because of their potential toxicities, especially renal dysfunction. Low-dose aspirin, for the prevention of cardiovascular and cardiocerebral events, appears to be safe, but patients must still be followed closely. Acetaminophen is generally considered the nonprescription analgesic and antipyretic of choice in transplant recipients because of its favorable toxicity profile. However, it is imperative that patients and transplant practitioners are aware that this agent is not without toxicities and proper monitoring is advised.

  2. Revising the economic imperative for US STEM education.

    Science.gov (United States)

    Donovan, Brian M; Moreno Mateos, David; Osborne, Jonathan F; Bisaccio, Daniel J

    2014-01-01

    Over the last decade macroeconomic studies have established a clear link between student achievement on science and math tests and per capita gross domestic product (GDP) growth, supporting the widely held belief that science, technology, engineering, and math(STEM) education are important factors in the production of economic prosperity. We critique studies that use science and math tests to predict GDP growth, arguing that estimates of the future economic value of STEM education involve substantial speculation because they ignore the impacts of economic growth on biodiversity and ecosystem functionality, which, in the long-term, limit the potential for future economic growth. Furthermore, we argue that such ecological impacts can be enabled by STEM education. Therefore, we contend that the real economic imperative for the STEM pipeline is not just raising standardized test scores, but also empowering students to assess, preserve, and restore ecosystems in order to reduce ecological degradation and increase economic welfare.

  3. Conservative and revolutionary readings of the categorical imperative: The logic of desire and the logic of drive in Kant’s practical philosophy

    Directory of Open Access Journals (Sweden)

    Selimbegović Ivan

    2011-01-01

    Full Text Available This paper will confront two possible conceptions of Imamanuel Kant’s practical philosophy based on two different possible understandings of categorical imperative. The first conception sees the categorical imperative as prescribing a form for the maxime under which a subject is to act if his actions are to be taken as moral. This conception is shown to be conservative as it preserves the existing moral norms of a society. This way of functioning of categorical imperative is shown to be homologuous to the logic of desiare as described by the french psychoanalyst Jacques Lacan and as incapable of providing a basis for ascribing responsibility to a subject for his acts. Another conception will be offered as an alternative: on that conception the categorical imeprative prescribes a manner of willing any maxime which is shown to be analoguous to the logic of the death drive. It’s ethical and revolutionary character are elucidated towards the end of the paper.

  4. Synthetic Biology and the Translational Imperative.

    Science.gov (United States)

    Heidari Feidt, Raheleh; Ienca, Marcello; Elger, Bernice Simone; Folcher, Marc

    2017-12-18

    Advances at the interface between the biological sciences and engineering are giving rise to emerging research fields such as synthetic biology. Harnessing the potential of synthetic biology requires timely and adequate translation into clinical practice. However, the translational research enterprise is currently facing fundamental obstacles that slow down the transition of scientific discoveries from the laboratory to the patient bedside. These obstacles including scarce financial resources and deficiency of organizational and logistic settings are widely discussed as primary impediments to translational research. In addition, a number of socio-ethical considerations inherent in translational research need to be addressed. As the translational capacity of synthetic biology is tightly linked to its social acceptance and ethical approval, ethical limitations may-together with financial and organizational problems-be co-determinants of suboptimal translation. Therefore, an early assessment of such limitations will contribute to proactively favor successful translation and prevent the promising potential of synthetic biology from remaining under-expressed. Through the discussion of two case-specific inventions in synthetic biology and their associated ethical implications, we illustrate the socio-ethical challenges ahead in the process of implementing synthetic biology into clinical practice. Since reducing the translational lag is essential for delivering the benefits of basic biomedical research to society at large and promoting global health, we advocate a moral obligation to accelerating translational research: the "translational imperative."

  5. An assessment of the impact of the pet trade on five CITES-Appendix II case studies - Boa constrictor imperator

    Science.gov (United States)

    Montgomery, Chad E.; Boback, Scott M.; Reed, Robert N.; Frazier, Julius A.

    2015-01-01

    Boa constrictor is a wide ranging snake species that is common in the pet trade and is currently listed in CITES Appendix II. Hog Island boas, or Cayos Cochinos boas, are a dwarf, insular race of Boa constrictor imperator endemic to the Cayos Cochinos Archipelago, Honduras. Cayos Cochinos boas are prized in the international pet trade for their light pink dorsal coloration, as well as for being much smaller and more docile than mainland boas (Porras, 1999; Russo, 2007). The boa population in the Cayos Cochinos was heavily exploited for the pet trade from 1979 to 1993, and researchers reported finding no boas on the islands during a five day herpetological survey trip in the early 1990s (Wilson and CruzDiaz, 1993), leading to the speculation that the population had been extirpated (e.g., Russo, 2007). The Cayos Cochinos Archipelago Natural Marine Monument has been managed by the Honduran Coral Reef Foundation since 1994 and prohibits removal of boas from the area. Poaching for the pet trade continues today, although at a lower level. Due to the endemic nature of this island morph of B. c. imperator it is imperative that we understand the dynamics of the populations and the ongoing threats that could negatively impact their long-term survival.

  6. Plasma dynamics from laser ablated solid lithium

    Indian Academy of Sciences (India)

    b; 52.25.-b; 52.70.-m. 1. Introduction. Pulsed laser ablation of a solid sample generates a dense plasma emission in the shape of ... The multichannel analyser plate of the ICCD was gated for as less as 4 ns using ... to explain the atomic collision processes [4]. .... Within duration of laser pulse, there occurs laser-solid interac-.

  7. Radiation, ecology and the invalid LNT model: the evolutionary imperative.

    Science.gov (United States)

    Parsons, Peter A

    2006-09-27

    Metabolic and energetic efficiency, and hence fitness of organisms to survive, should be maximal in their habitats. This tenet of evolutionary biology invalidates the linear-no threshold (LNT) model for the risk consequences of environmental agents. Hormesis in response to selection for maximum metabolic and energetic efficiency, or minimum metabolic imbalance, to adapt to a stressed world dominated by oxidative stress should therefore be universal. Radiation hormetic zones extending substantially beyond common background levels, can be explained by metabolic interactions among multiple abiotic stresses. Demographic and experimental data are mainly in accord with this expectation. Therefore, non-linearity becomes the primary model for assessing risks from low-dose ionizing radiation. This is the evolutionary imperative upon which risk assessment for radiation should be based.

  8. La Planificación Urbana: un imperativo ético. / Urban Planning: an ethical imperative.

    Directory of Open Access Journals (Sweden)

    Torres Jofré, Mario

    2001-07-01

    Full Text Available Se presenta un análisis de las estadísticas chilenas en materia de indicadores socioeconómicos; refiere los principios éticos de la planificación del territorio. Una tentativa de esclarecimiento del concepto de bien común, analizando los aspectos filosóficos que lo sustentan y lo establecido en la propia Constitución Política de la República de Chile. Se informa ejemplos de la incoherencia actual –entre discurso y obras–, y se ilustra cómo algunas instituciones encargadas de velar por el bien común tergiversan la interpretación de la ley a favor de sector empresarial. Se expone el imperativo ético de la planificación del territorio./Here is presented an analysis of the relevant statistics used in socioeconomic indicators in Chile, referring to the ethical principals of territorial planning. A tentative aclaration of the concept of 'common good' is attempted, analysing the underlying philosophical aspects and those which are established in the Political Constitution of the Republic of Chile. Examples are given of the current incoherence, between discourse and action, and it is shown how some institutions responsable for upholding the common good twist the interpretation of the law in favour of the private sector. The ethical imperative of territorial planning is highlighted.

  9. Pitch peak alignment in an outside focus realization : Frisian-Dutch bilingual speakers’ declarative and imperative intonation patterns

    NARCIS (Netherlands)

    Nota, Amber; Hilton, Nanna; Coler, Matthew

    2016-01-01

    This paper investigates intonational pitch variations and pitch peak alignment in declarative sentences and is part of a larger study of declarative, interrogative and imperative grammatical constructions in the Frisian-Dutch contact situation. Frisian is a minority language spoken in the province

  10. Determinants of Early Introduction of Solid, Semi-Solid or Soft Foods among Infants Aged 3–5 Months in Four Anglophone West African Countries

    Directory of Open Access Journals (Sweden)

    Abukari I. Issaka

    2014-07-01

    Full Text Available This study was conducted to explore and identify factors associated with the practice of early introduction of solid, semi-solid or soft foods among infants aged 3–5 months in four Anglophone West African countries. Data sources for the analyses were the latest Demographic and Health Survey datasets of the 4 countries, namely Ghana (GDHS, 2008, Liberia (LDHS, 2007, Nigeria (NDHS, 2013 and Sierra Leone (SLDHS, 2008. Multiple logistic regression methods were used to analyze the factors associated with early introduction of solid, semi-solid or soft foods among infants aged 3–5 months, using individual-, household- and community-level determinants. The sample consisted of 2447 infants aged 3–5 months from four Anglophone West African countries: 166 in Ghana, 263 in Liberia, 1658 in Nigeria and 360 in Sierra Leone. Multivariable analyses revealed the individual factors associated with early introduction of solid, semi-solid or soft foods in these countries. These included increased infant’s age, diarrhea, acute respiratory infection and newborns perceived to be small by their mothers. Other predictors of early introduction of solid, semi-solid or soft foods were: mothers with no schooling, young mothers and fathers who worked in an agricultural industry. Public health interventions to improve exclusive breastfeeding practices by discouraging early introduction of solid, semi-solid or soft foods are needed in all 4 countries, targeting especially mothers at risk of introducing solid foods to their infants early.

  11. Continuous mixing of solids

    NARCIS (Netherlands)

    Raouf, M.S.

    1963-01-01

    The most important literature on theoretical aspects of mixing solids was reviewed.

    Only when the mixed materials showed no segregation it was possible to analyse the mixing process quantitatively. In this case the mixture could be described by the 'χ' Square test. Longitudinal mixing could be

  12. Twitter weather warnings: Communicating risk in 140 characters-the impact of imperative and declarative message style on weather risk perception and behavioral intentions.

    Science.gov (United States)

    Rainear, Adam M; Lachlan, Kenneth A; Spence, Patric R

    Understanding how individuals utilize risk messages is important for protecting lives and gaining compliance toward safe behaviors. Recent advances in technology afford users with timeliness when needing to acquire information, and research investigating imperative and declarative message styles suggests utilizing both strategies is most effective. Similarly, the element of time can play a role when an individual engages in certain behaviors. This study employed an experimental design to better understand how imperative and declarative tweets, and time can contribute to risk perceptions and behavioral intentions. Results indicate the most negative affect is experienced after receiving an imperative-only tweet in a short-lead time condition, whereas a tweet utilizing both message styles in a long-lead time condition induces the most fear. Future research should investigate stylistic message elements on new media platforms to better understand how messages can be effectively sent and received by the intended audience within character-limited platforms.

  13. Imperative of preventive measures addressing the life-cycle.

    Science.gov (United States)

    Yajnik, Chittaranjan S

    2009-01-01

    The epidemiological characteristics of chronic non-communicable diseases (NCD) are fast changing. The prevalence has risen to unprecedented levels, and the young and the underprivileged are increasingly affected. The classic view of the etiology of NCD consists of a genetic susceptibility which is precipitated by aging and modern lifestyle. In a virtual absence of any methods to tackle genetic susceptibility, the preventive approach has so far been focused on the control of lifestyle factors in those at high risk (old, and those with positive family history and elevated risk factors). Such an approach might help high risk individuals, but is unlikely to curtail the burgeoning epidemic of obesity and diabetes. Recent research has suggested that susceptibility to NCD originates in early life through non-genetic mechanisms (fetal programming). Tackling these may offer an exciting opportunity to control the NCD epidemic by influencing the susceptibility in a more durable manner than only controlling the lifestyle factors in adult life. The imperative is to address the life cycle rather than concentrate on the end stages. Copyright (c) 2009 S. Karger AG, Basel.

  14. On the Drive Specificity of Freudian Drives for the Generation of SEEKING Activities: The Importance of the Underestimated Imperative Motor Factor

    Directory of Open Access Journals (Sweden)

    Michael Kirsch

    2018-05-01

    Full Text Available Doubters of Freud’s theory of drives frequently mentioned that his approach is outdated and therefore cannot be useful for solving current problems in patients with mental disorders. At present, many scientists believe that affects rather than drives are of utmost importance for the emotional life and the theoretical framework of affective neuroscience, developed by Panksepp, strongly underpinned this view. Panksepp evaluated seven so-called command systems and the SEEKING system is therein of central importance. Panksepp used Pankseppian drives as inputs for the SEEKING system but noted the missing explanation of drive-specific generation of SEEKING activities in his description. Drive specificity requires dual action of the drive: the activation of a drive-specific brain area and the release of the neurotransmitter dopamine. Noticeably, as Freud claimed drive specificity too, it was here analyzed whether a Freudian drive can evoke the generation of drive-specific SEEKING activities. Special importance was addressed to the imperative motor factor in Freud’s drive theory because Panksepp’s formulations focused on neural pathways without specifying underlying neurotransmitter/endocrine factors impelling motor activity. As Panksepp claimed sleep as a Pankseppian drive, we firstly had to classified sleep as a Freudian drive by using three evaluated criteria for a Freudian drive. After that it was possible to identify the imperative motor factors of hunger, thirst, sex, and sleep. Most importantly, all of these imperative motor factors can both activate a drive-specific brain area and release dopamine from dopaminergic neurons, i.e., they can achieve the so-called drive specificity. Surprisingly, an impaired Freudian drive can alter via endocrinological pathways the concentration of the imperative motor factor of a second Freudian drive, obviously in some independence to the level of the metabolic deficit, thereby offering the possibility to

  15. Solid forms for Savannah River Plant radioactive wastes

    International Nuclear Information System (INIS)

    Wallace, R.M.; Hale, W.H.; Bradley, R.F.; Hull, H.L.; Kelley, J.A.; Stone, J.A.; Thompson, G.H.

    1976-01-01

    Methods are being developed to immobilize Savannah River Plant wastes in solid forms such as cement, asphalt, or glass. 137 Cs and 90 Sr are the major biological hazards and heat producers in the alkaline wastes produced at SRP. In the conceptual process being studied, 137 Cs removed from alkaline supernates, together with insoluble sludges that contain 90 Sr, will be incorporated into solid forms of high integrity and low volume suitable for storage in a retrievable surface storage facility for about 100 years, and for eventual shipment to an off-site repository. Mineralization of 137 Cs, or its fixation on zeolite prior to incorporation into solid forms, is also being studied. Economic analyses to reduce costs and fault-tree analyses to minimize risks are being conducted. Methods are being studied for removal of sludge from (and final decontamination of) waste tanks

  16. Geometrical setting of solid mechanics

    International Nuclear Information System (INIS)

    Fiala, Zdenek

    2011-01-01

    Highlights: → Solid mechanics within the Riemannian symmetric manifold GL (3, R)/O (3, R). → Generalized logarithmic strain. → Consistent linearization. → Incremental principle of virtual power. → Time-discrete approximation. - Abstract: The starting point in the geometrical setting of solid mechanics is to represent deformation process of a solid body as a trajectory in a convenient space with Riemannian geometry, and then to use the corresponding tools for its analysis. Based on virtual power of internal stresses, we show that such a configuration space is the (globally) symmetric space of symmetric positive-definite real matrices. From this unifying point of view, we shall analyse the logarithmic strain, the stress rate, as well as linearization and intrinsic integration of corresponding evolution equation.

  17. Factors Associated with Early Introduction of Formula and/or Solid, Semi-Solid or Soft Foods in Seven Francophone West African Countries

    Directory of Open Access Journals (Sweden)

    Abukari I. Issaka

    2015-01-01

    Full Text Available The aim of this study was to identify factors associated with early introduction of formula and/or solid, semi-solid or soft foods to infants aged three to five months in seven Francophone West African countries. The sources of data for the analyses were the most recent Demographic and Health Survey datasets of the seven countries, namely Benin (BDHS, 2012, Burkina Faso (BFDHS, 2010, Cote d’Ivoire (CIDHS, 2011–2012, Guinea (GDHS, 2012, Mali (MDHS, 2012–2013, Niger (NDHS, 2012 and Senegal (SDHS, 2010. The study used multiple logistic regression methods to analyse the factors associated with early introduction of complementary feeding using individual-, household- and community-level determinants. The sample was composed of 4158 infants aged between three and five months with: 671 from Benin, 811 from Burkina Faso, 362 from Cote d’Ivoire, 398 from Guinea, 519 from Mali, 767 from Niger and 630 from Senegal. Multiple analyses indicated that in three of the seven countries (Benin, Guinea and Senegal, infants who suffered illnesses, such as diarrhoea and acute respiratory infection, were significantly more likely to be introduced to formula and/or solid, semi-solid or soft foods between the age of three and five months. Other significant factors included infants who: were born in second to fourth position (Benin, whose mothers did not attend any antenatal clinics (Burkina Faso and Niger, were male (Cote d’Ivoire and Senegal, lived in an urban areas (Senegal, or were delivered by traditional birth attendants (Guinea, Niger and Senegal. Programmes to discourage early introduction of formula and/or solid, semi-solid or soft foods in these countries should target the most vulnerable segments of the population in order to improve exclusive breastfeeding practices and reduce infant mortality.

  18. Lost in Translation: The Participatory Imperative and Local Water Governance in North Thailand and Southwest Germany

    Directory of Open Access Journals (Sweden)

    Andreas Neef

    2008-06-01

    Full Text Available Water management in Thailand and Germany has been marked by a command-and-control policy-style for decades, but has recently begun to move slowly towards more inclusive and participatory approaches. In Germany, the push for public participation stems from the recently promulgated European Union Water Framework Directive (EU WFD, while participatory and integrated river basin management in Thailand has been strongly promoted by major international donors. Drawing on case studies from two watersheds in North Thailand and Southwest Germany, this paper analyses how the participatory imperative in water governance is translated at the local level. Evidence suggests that in both countries public participation in water management is still in its infancy, with legislative and executive responsibilities being divided between a variety of state agencies and local authorities. Bureaucratic restructuring and technocratic attitudes, passive resistance on the part of administrative staff towards inclusive processes, and a trend towards the (recentralisation of responsibilities for water governance in both study regions undermines community-based and stakeholder-driven water governance institutions, thus calling into question the subsidiarity principle. State-driven participatory processes tend to remain episodic and ceremonial and have not (yet gone beyond the informative and consultative stage. Meaningful public participation, promised on paper and in speeches, gets lost in translation too often.

  19. Outcome Measurement in Nursing: Imperatives, Ideals, History, and Challenges

    Science.gov (United States)

    Jones, Terry L

    2016-05-31

    Nurses have a social responsibility to evaluate the effect of nursing practice on patient outcomes in the areas of health promotion; injury and illness prevention; and alleviation of suffering. Quality assessment initiatives are hindered by the paucity of available data related to nursing processes and patient outcomes across these three domains of practice. Direct care nurses are integral to self-regulation for the discipline as they are the best source of information about nursing practice and patient outcomes. Evidence supports the assumption that nurses do contribute to prevention of adverse events but there is insufficient evidence to explain how nurses contribute to these and/or other patient outcomes. The purposes of this article are to examine the imperatives, ideal conditions, history, and challenges related to effective outcome measurement in nursing. The article concludes with recommendations for action to move quality assessment forward, such as substantial investment to support adequate documentation of nursing practice and patient outcomes.

  20. Solid-phase extraction versus matrix solid-phase dispersion: Application to white grapes.

    Science.gov (United States)

    Dopico-García, M S; Valentão, P; Jagodziñska, A; Klepczyñska, J; Guerra, L; Andrade, P B; Seabra, R M

    2007-11-15

    The use of matrix solid-phase dispersion (MSPD) was tested to, separately, extract phenolic compounds and organic acids from white grapes. This method was compared with a more conventional analytical method previously developed that combines solid liquid extraction (SL) to simultaneously extract phenolic compounds and organic acids followed by a solid-phase extraction (SPE) to separate the two types of compounds. Although the results were qualitatively similar for both techniques, the levels of extracted compounds were in general quite lower on using MSPD, especially for organic acids. Therefore, SL-SPE method was preferred to analyse white "Vinho Verde" grapes. Twenty samples of 10 different varieties (Alvarinho, Avesso, Asal-Branco, Batoca, Douradinha, Esganoso de Castelo Paiva, Loureiro, Pedernã, Rabigato and Trajadura) from four different locations in Minho (Portugal) were analysed in order to study the effects of variety and origin on the profile of the above mentioned compounds. Principal component analysis (PCA) was applied separately to establish the main sources of variability present in the data sets for phenolic compounds, organic acids and for the global data. PCA of phenolic compounds accounted for the highest variability (77.9%) with two PCs, enabling characterization of the varieties of samples according to their higher content in flavonol derivatives or epicatechin. Additionally, a strong effect of sample origin was observed. Stepwise linear discriminant analysis (SLDA) was used for differentiation of grapes according to the origin and variety, resulting in a correct classification of 100 and 70%, respectively.

  1. Molecular Analyses Reveal Inflammatory Mediators in the Solid Component and Cyst Fluid of Human Adamantinomatous Craniopharyngioma.

    Science.gov (United States)

    Donson, Andrew M; Apps, John; Griesinger, Andrea M; Amani, Vladimir; Witt, Davis A; Anderson, Richard C E; Niazi, Toba N; Grant, Gerald; Souweidane, Mark; Johnston, James M; Jackson, Eric M; Kleinschmidt-DeMasters, Bette K; Handler, Michael H; Tan, Aik-Choon; Gore, Lia; Virasami, Alex; Gonzalez-Meljem, Jose Mario; Jacques, Thomas S; Martinez-Barbera, Juan Pedro; Foreman, Nicholas K; Hankinson, Todd C

    2017-09-01

    Pediatric adamantinomatous craniopharyngioma (ACP) is a highly solid and cystic tumor, often causing substantial damage to critical neuroendocrine structures such as the hypothalamus, pituitary gland, and optic apparatus. Paracrine signaling mechanisms driving tumor behavior have been hypothesized, with IL-6R overexpression identified as a potential therapeutic target. To identify potential novel therapies, we characterized inflammatory and immunomodulatory factors in ACP cyst fluid and solid tumor components. Cytometric bead analysis revealed a highly pro-inflammatory cytokine pattern in fluid from ACP compared to fluids from another cystic pediatric brain tumor, pilocytic astrocytoma. Cytokines and chemokines with particularly elevated concentrations in ACPs were IL-6, CXCL1 (GRO), CXCL8 (IL-8) and the immunosuppressive cytokine IL-10. These data were concordant with solid tumor compartment transcriptomic data from a larger cohort of ACPs, other pediatric brain tumors and normal brain. The majority of receptors for these cytokines and chemokines were also over-expressed in ACPs. In addition to IL-10, the established immunosuppressive factor IDO-1 was overexpressed by ACPs at the mRNA and protein levels. These data indicate that ACP cyst fluids and solid tumor components are characterized by an inflammatory cytokine and chemokine expression pattern. Further study regarding selective cytokine blockade may inform novel therapeutic interventions. © 2017 American Association of Neuropathologists, Inc. All rights reserved.

  2. Storing and evacuation of solid radioactive waste (1960); Stockage et evacuation des dechets radioactifs solides (1960)

    Energy Technology Data Exchange (ETDEWEB)

    Pomarola, J [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1960-07-01

    The object of this paper is to present the plans under consideration for the final destination of solid radioactive wastes. 1) It is first of all necessary to provide in each centre an organised temporary storage dump. Several types of temporary dumps are suitable and can coexist in the same area; on the ground, in buildings; in basements. 2) Definitive storage. To accomplish a definitive storage arrangement it is necessary, as a function of the activity and the conditioning of the wastes, to define: - the site and the means of transport considered both inside and outside nuclear centres. The solution adopted depends on the above imperatives, and plans for definitive storage on the ground, under ground and in the sea are examined successively. Economic considerations play a large part in the decision reached. (author) [French] La presente communication a pour objet les solutions envisagees pour une destination finale des dechets radioactifs solide. 1) Il est tout d'abord necessaire de prevoir, dans chaque centre, un stockage provisoire organise. Plusieurs types de stockage previsoire peuvent convenir et coexister sur une meme aire; stockage sur le sol; stockage en batiment; stockage en sous-sol. 2) Stockage definitif. La realisation d'un stockage definitif rend necessaire, en fonction de l'activite et du conditionnement des dechets, la definition: - du site et des modes de transports envisages a l'interieur et a l'exterieur des Centres Nucleaires. Le choix des solutions decoule des imperatifs ci-dessus et on examine successivement le stockage definitif, - sur le sol; dans le sous-sol; en mer. Les considerations d'ordre economique constituent un facteur important dans le choix de la solution. (auteur)

  3. Analyse économique de la gestion des déchets solides et du ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    La plupart des villes à croissance rapide en Asie du Sud sont confrontées à une augmentation de l'engorgement et de la contamination de l'eau en raison de la mauvaise gestion des déchets solides. Il est attendu que des événements climatiques extrêmes comme les inondations et la sécheresse compliqueront davantage ...

  4. On Decidable Growth-Rate Properties of Imperative Programs

    Directory of Open Access Journals (Sweden)

    Amir M. Ben-Amram

    2010-05-01

    Full Text Available In 2008, Ben-Amram, Jones and Kristiansen showed that for a simple "core" programming language - an imperative language with bounded loops, and arithmetics limited to addition and multiplication - it was possible to decide precisely whether a program had certain growth-rate properties, namely polynomial (or linear bounds on computed values, or on the running time. This work emphasized the role of the core language in mitigating the notorious undecidability of program properties, so that one deals with decidable problems. A natural and intriguing problem was whether more elements can be added to the core language, improving its utility, while keeping the growth-rate properties decidable. In particular, the method presented could not handle a command that resets a variable to zero. This paper shows how to handle resets. The analysis is given in a logical style (proof rules, and its complexity is shown to be PSPACE-complete (in contrast, without resets, the problem was PTIME. The analysis algorithm evolved from the previous solution in an interesting way: focus was shifted from proving a bound to disproving it, and the algorithm works top-down rather than bottom-up.

  5. Solid phase carrier for radioimmuno analyses, as well as its manufacture and use

    International Nuclear Information System (INIS)

    Meriadec, B.; Roubertie, P.

    1979-01-01

    The solid phase carrier is in the form of a tablet containing freeze-dried protein-bonded gel, dicalcium phosphate and magnesium stearate. It is able to absorb 0.400 microlitre of an a solution containing antigen-antibody. When contacted with the solution, the tablet swells up and adapts to the shape of the column. The carrier is suitable for the TSH RIA test. (DG) [de

  6. Solid-state 29Si NMR and FTIR analyses of lignin-silica coprecipitates

    DEFF Research Database (Denmark)

    Cabrera Orozco, Yohanna; Cabrera, Andrés; Larsen, Flemming Hofmann

    2016-01-01

    When agricultural residues are processed to ethanol, lignin and silica are some of the main byproducts. Separation of these two products is difficult and the chemical interactions between lignin and silica are not well described. In the present study, the effect of lignin-silica complexing has been...... investigated by characterizing lignin and silica coprecipitates by FTIR and solid state NMR. Silica particles were coprecipitated with three different lignins, three lignin model compounds, and two silanes representing silica-in-lignin model compounds. Comparison of 29Si SP/MAS NMR spectra revealed differences...

  7. ???????????? SolidWorks/SolidWorks Flow Simulation/SolidWorks Simulation ??? ?????????? ???????? ?? ????????????? ???

    OpenAIRE

    ????????????, ?. ?.; ????????, ?. ?.; ?????, ?. ?.

    2012-01-01

    ? ?????? ???????? ??????? ??????? ???????? ?? ???????????? ??????????? ????????? SolidWorks/SolidWorks Flow Simulation (COSMOSFloWorks)/SolidWorks Simulation ??? ?????????? ???????? ?? ????????????? ???. ??? ???????? ????????? ???????? ?????????? ?? ?????? ???????? ??????? ? ????????????? ?????? ? ????????????? ????????????? ?????????? ???????????? SolidWorks Flow Simulation (COSMOSFloWorks). ??? ???????????? ??????????? ????????????? ?????? ?? ????????? ??????????? ??????? ?? ??????????? ...

  8. Educational-Methodical Projects for Students' Intellectual Competences Formation: The Imperative Goal of the Educational Process of the University

    Science.gov (United States)

    Kutuev, Ruslan A.; Kudyasheva, Albina N.; Buldakova, Natalya V.; Aleksandrova, Natalia S.; Vasilenko, Alexandra S.

    2016-01-01

    The research urgency is caused by the tendencies of the modern information society which produces and consumes intelligence, knowledge and competences as the main educational product of labor market. These trends fundamentally alter the methodological basis of the educational process of the University, subjecting it to imperative goals: the…

  9. Generic Skills for Graduate Accountants: The Bigger Picture, a Social and Economic Imperative in the New Knowledge Economy

    Science.gov (United States)

    Bunney, Diane; Sharplin, Elaine; Howitt, Christine

    2015-01-01

    The case for integrating generic skills in university accounting programmes is well documented in the literature, but the implementation of strategies designed to teach generic skills in the context of accounting courses has posed ongoing challenges for academics and course administrators. The imperative for generic skills in accounting programmes…

  10. All-Solid-State Sodium-Selective Electrode with a Solid Contact of Chitosan/Prussian Blue Nanocomposite

    Directory of Open Access Journals (Sweden)

    Tanushree Ghosh

    2017-11-01

    Full Text Available Conventional ion-selective electrodes with a liquid junction have the disadvantage of potential drift. All-solid-state ion-selective electrodes with solid contact in between the metal electrode and the ion-selective membrane offer high capacitance or conductance to enhance potential stability. Solution-casted chitosan/Prussian blue nanocomposite (ChPBN was employed as the solid contact layer for an all-solid-state sodium ion-selective electrode in a potentiometric sodium ion sensor. Morphological and chemical analyses confirmed that the ChPBN is a macroporous network of chitosan that contains abundant Prussian blue nanoparticles. Situated between a screen-printed carbon electrode and a sodium-ionophore-filled polyvinylchloride ion-selective membrane, the ChPBN layer exhibited high redox capacitance and fast charge transfer capability, which significantly enhanced the performance of the sodium ion-selective electrode. A good Nernstian response with a slope of 52.4 mV/decade in the linear range from 10−4–1 M of NaCl was observed. The stability of the electrical potential of the new solid contact was tested by chronopotentiometry, and the capacitance of the electrode was 154 ± 4 µF. The response stability in terms of potential drift was excellent (1.3 µV/h for 20 h of continuous measurement. The ChPBN proved to be an efficient solid contact to enhance the potential stability of the all-solid-state ion-selective electrode.

  11. Airflow Obstruction and Use of Solid Fuels for Cooking or Heating: BOLD Results.

    Science.gov (United States)

    Amaral, André F S; Patel, Jaymini; Kato, Bernet S; Obaseki, Daniel O; Lawin, Hervé; Tan, Wan C; Juvekar, Sanjay K; Harrabi, Imed; Studnicka, Michael; Wouters, Emiel F M; Loh, Li-Cher; Bateman, Eric D; Mortimer, Kevin; Buist, A Sonia; Burney, Peter G J

    2017-09-12

    Evidence supporting the association of COPD or airflow obstruction with use of solid fuels is conflicting and inconsistent. To assess the association of airflow obstruction with self-reported use of solid fuels for cooking or heating. We analysed 18,554 adults from the BOLD study, who had provided acceptable post-bronchodilator spirometry measurements and information on use of solid fuels. The association of airflow obstruction with use of solid fuels for cooking or heating was assessed by sex, within each site, using regression analysis. Estimates were stratified by national income and meta-analysed. We carried out similar analyses for spirometric restriction, chronic cough and chronic phlegm. We found no association between airflow obstruction and use of solid fuels for cooking or heating (ORmen=1.20, 95%CI 0.94-1.53; ORwomen=0.88, 95%CI 0.67-1.15). This was true for low/middle and high income sites. Among never smokers there was also no evidence of an association of airflow obstruction with use of solid fuels (ORmen=1.00, 95%CI 0.57-1.76; ORwomen=1.00, 95%CI 0.76-1.32). Overall, we found no association of spirometric restriction, chronic cough or chronic phlegm with the use of solid fuels. However, we found that chronic phlegm was more likely to be reported among female never smokers and those who had been exposed for ≥20 years. Airflow obstruction assessed from post-bronchodilator spirometry was not associated with use of solid fuels for cooking or heating.

  12. MFT homogeneity study at TNX: Final report on the low weight percent solids concentration

    International Nuclear Information System (INIS)

    Jenkins, W.J.

    1993-01-01

    A statistical design and analysis of both elemental analyses and weight percent solids analyses data was utilized to evaluate the MFT homogeneity at low heel levels and low agitator speed at both high and low solids feed concentrations. The homogeneity was also evaluated at both low and high agitator speed at the 6000+ gallons static level. The dynamic level portion of the test simulated feeding the Melter from the MFT to evaluate the uniformity of the solids slurry composition (Frit-PHA-Sludge) entering the melter from the MFT. This final report provides the results and conclusions from the second half of the study, the low weight percent solids concentration portion, as well as a comparison with the results from the first half of the study, the high weight percent solids portion

  13. Solid State Bonding Mechanics In Extrusion And FSW: Experimental Tests And Numerical Analyses

    International Nuclear Information System (INIS)

    Buffa, G.; Fratini, L.; Donati, L.; Tomesani, L.

    2007-01-01

    In the paper the authors compare the different solid state bonding mechanics for both the processes of hollow profiles extrusion and Friction Stir Welding (FSW), through the results obtained from a wide experimental campaign on AA6082-T6 aluminum alloys. Microstructure evaluation, tensile tests and micro-hardness measurements realized on specimens extracted by samples of the two processes are discussed also by means of the results obtained from coupled FEM simulation of the processes

  14. Five Strategic Imperatives for Interdisciplinary Study in Mass Communications/Media Studies in the U.S. and U.K.

    Science.gov (United States)

    Petrausch, Robert J.

    2005-01-01

    Interdisciplinary study can allow students to share ideas with scholars in allied fields and broaden their knowledge of global issues. Mass communication/media studies programs in the U.S. and U.K. can serve as models to lead students into successful learning through interdisciplinary study. This paper outlines five strategic imperatives for the…

  15. The Criticality of Norms to the Functional Imperatives of the Social Action System of College and University Work

    Science.gov (United States)

    Braxton, John M.

    2010-01-01

    In this article, I assert that the work of colleges and universities forms a social action system. I array the critical positions represented in this issue according to the four functional imperatives of social action systems: adaptation, goal attainment, integration, and pattern maintenance. I discuss the role of normative structures for these…

  16. Characterization and morphology of solids suspended in rain water

    International Nuclear Information System (INIS)

    Iturbe G, J.L.; Lopez M, B.E.; Torre O, J. De la

    2000-01-01

    This work presents the results obtained from the analysis of rain water in Mexico. The study treats over the characterization and morphology of the solids suspended in form of particles in the atmosphere. The solids suspended were obtained of the pluvial precipitations after these have been centrifuged. Subsequently of the separation, the particulate matter was analysed by Sem and X-ray dispersive energy

  17. IMPERATIVES OF THE INTERNATIONAL POLITICAL AND LEGAL ORDER

    Directory of Open Access Journals (Sweden)

    Elena IFTIME

    2016-08-01

    Full Text Available In this paper, we intend to discuss a topic of particular importance, given that it addresses the imperatives of international political and legal order, as they appear in the light of current international law. It is an issue of great complexity, of very wide current interest because the international law that establishes and maintains an international legal order is a real energetic factor of organization of international community life. So viewed, the rules of international nature respond to the current acute need of founding the relations in this field and of meeting the common needs of the members of international society. We considered that by comparison with the internal legal order reflecting the health inscribed in this order, the international legal order is influenced by the structuring and training of the mondial community. Therefore we shall insist on the principal model of organizing international life – the state – to be viewed and analyzed in a double perspective: as an internal sovereign authority and as an actor on the scene of international life. In both instances, the state provides the foundation of legal order (domestic or international for that law has always been the expression of the state wish.

  18. (suspended solids and metals) removal efficiencies

    African Journals Online (AJOL)

    ABSTRACT. Presented in this paper are the results of correlational analyses and logistic regression between metal substances (Cd, Cu,. Pb, Zn), as well as suspended solids removal, and physical pond parameters of 19 stormwater retention pond case studies obtained from the International Stormwater BMP database.

  19. Climate Change Dynamics and Imperatives for Food Security in Nigeria

    Directory of Open Access Journals (Sweden)

    Olumide D. Onafeso

    2016-02-01

    Full Text Available Decadal variability in African rainfall is projected from General Circulation Models (GCMs to continue under elevated greenhouse gas scenarios. Effects on rain intensity, spatio-temporal variability of growing seasons, flooding, drought, and land-use change impose feedbacks at regional-local scales. Yet, empirical knowledge of associated impacts on crop yield is limited; thus, we examined the imperatives for food security in Nigeria. Bivariate correlation and multiple regression suggests impending drought in the northern region where livestock farming is predominant. Relative contributions of climate independent variables in determining crop yield by backward selection procedures with stepwise approach indexed the impacts of annual climate variability by a parameter computed as annual yield minus mean annual yield divided by the standard deviation. Results show Z-distribution approximately 5 to + 5, when 3 indicate impacts significant at 95% confidence levels. In conclusion, we established the interwoven relationship between climatic change and food security.

  20. A Comparison of Functional and Imperative Programming Techniques for Mathematical Software Development

    Directory of Open Access Journals (Sweden)

    Scott Frame

    2014-04-01

    Full Text Available Functional programming has traditionally been considered elegant and powerful, but also somewhat impractical for ordinary computing. Proponents of functional programming claim that the evolution of functional languages makes their use feasible in many domains. In this work, a popular imperative language (C++ and the leading functional language (Haskell are compared in a math-intensive, real-world application using a variety of criteria: ease of implementation, efficiency, and readability. The programming tasks that were used as benchmarks involved mathematical transformations between local and global coordinate systems. Details regarding the application area and how language features of both languages were used to solve critical problems are described. The paper closes with some conclusions regarding applicability of functional programming for mathematical applications.

  1. Teacher Education in Post-Apartheid South Africa: Navigating a Way through Competing State and Global Imperatives for Change

    Science.gov (United States)

    Schafer, Marc; Wilmot, Di

    2012-01-01

    This article focuses on teacher education in post-apartheid South Africa. It argues that the restructuring and reorganization of teacher education is at the nexus of the axes of tension created by national and global imperatives for change. Along with the dismantling of apartheid and the transition to a free and democratic state in 1994 came the…

  2. Towards sustainable solid waste management: Investigating household participation in solid waste management

    Science.gov (United States)

    Akil, A. M.; Ho, C. S.

    2014-02-01

    The aim of this paper is to assess the readiness of Iskandar Malaysia community to accept solid waste recycling. The research is based on quantitative research design and descriptive survey of the households at Iskandar Malaysia using the stratified sampling method for a sample of 670. The survey was conducted using a structured questionnaire that covered two basic principles; a) recycling knowledge; b) willingness to recycle. Data was analysed using the SPSS to carry out statistical analysis. The finding shows households' knowledge towards the solid waste recycling is good and positive. However, finding also shows that respondents have incomprehensive knowledge on the method of disposal as more than 50% of householders only recycle papers and textiles. Most of the households agreed to participate in the activities of the separation of waste if the facility will be made available at their kerbside. Therefore, it is recommended that government should provide more in-depth knowledge by intensifying the awareness of the households in the recycling programs. In term of urban planning and management, the location of recycling facility can be analysing by using GIS. This is important to understand the catchment area of each neighbourhood or precinct to ensure effective household participation.

  3. Possibilities of municipal solid waste incinerator fly ash utilisation.

    Science.gov (United States)

    Hartmann, Silvie; Koval, Lukáš; Škrobánková, Hana; Matýsek, Dalibor; Winter, Franz; Purgar, Amon

    2015-08-01

    Properties of the waste treatment residual fly ash generated from municipal solid waste incinerator fly ash were investigated in this study. Six different mortar blends with the addition of the municipal solid waste incinerator fly ash were evaluated. The Portland cement replacement levels of the municipal solid waste incinerator fly ash used were 25%, 30% and 50%. Both, raw and washed municipal solid waste incinerator fly ash samples were examined. According to the mineralogical composition measurements, a 22.6% increase in the pozzolanic/hydraulic properties was observed for the washed municipal solid waste incinerator fly ash sample. The maximum replacement level of 25% for the washed municipal solid waste incinerator fly ash in mortar blends was established in order to preserve the compressive strength properties. Moreover, the leaching characteristics of the crushed mortar blend was analysed in order to examine the immobilisation of its hazardous contents. © The Author(s) 2015.

  4. From dark to bright: novel daylighting applications in solid state lighting

    Science.gov (United States)

    Adler, Helmar G.

    2011-10-01

    The term "daylighting" is used in various ways, on one hand in a more architectural sense, i.e. using existing daylight to illuminate spaces, and on the other, more recently, for using light sources to replicate daylight. The emergence of solid state lighting (SSL) opens up a large number of new avenues for daylighting. SSL allows innovative controllability of intensity and color for artificial light sources that can be advantageously applied to daylighting. With the assistance of these new technologies the combination of natural and artificial lighting could lead to improvements in energy savings and comfort of living beings. Thus it is imperative to revisit or even improve daylighting research so that building networks of the future with their sensor, energy (e.g. HVAC) and lighting requirements can benefit from the emerging capabilities. This paper will briefly review existing daylighting concepts and technology and discuss new ideas. An example of a tunable multi-color SSL system will be shown.

  5. Fabrication and Application of (1-x) NaCl+xKCl Solid Solution

    International Nuclear Information System (INIS)

    Kyi Kyi Lwin

    2011-12-01

    (1-X)NaCl+xKCl solid solution are prepared by the starting materials NaCl (0.9, 0.95) in equal molar ratio. The solid solutions are heat-treated at various temperature and XRD analyses are carried out for the solid solutions to examine the crystalline phase, crystallographic orientation and lattice parameters. The electrical properties of the solutions are determined by using the conductometer. The solid solutions are utilized as crystal oscillator and outcoming frequencies, capacitances and dielectric constants are also investigated.

  6. Economic evaluation of radiation processing in urban solid wastes treatment

    Science.gov (United States)

    Carassiti, F.; Lacquaniti, L.; Liuzzo, G.

    During the last few years, quite a number of studies have been done, or are still in course, on disinfection of urban liquid wastes by means of ionizing radiations. The experience gained by SANDIA pilot plant of irradiation on dried sewage sludge, together with the recently presented conceptual design of another plant handling granular solids, characterized by high efficiency and simple running, have shown the possibility of extending this process to the treatment of urban solid wastes. As a matter of fact, the problems connected to the pathogenic aspects of sludge handling are often similar to those met during the disposal of urban solid wastes. This is even more so in the case of their reuse in agriculture and zootechny. The present paper introduces the results of an analysis carried out in order to evaluate the economical advantage of inserting irradiation treatment in some process scheme for management of urban solid wastes. Taking as an example a comprehensive pattern of urban solid wastes management which has been analysed and estimated economically in previous works, we first evaluated the extra capital and operational costs due to the irradiation and then analysed economical justification, taking into account the increasing commercial value of the by-products.

  7. Trends in the Development of International Tourism and Imperatives of Modernizing the Tourism Industry

    Directory of Open Access Journals (Sweden)

    Zeyneb Adamanova

    2015-01-01

    Full Text Available This article provides a rationale for the significance and explores the characteristics of international tourism. The author establishes that this sector of the global economy has been developing in quite a sustainable fashion, without being affected by substantial differences between various regions around the world. The author discusses groups of stimulating factors and major trends in the development of international tourism at the current stage, including major changes in the tourism product and the operation of the global market of tourism services. The article defines the imperatives of modernizing the tourism industry at the national level.

  8. Putting Foucault to work: an approach to the practical application of Foucault's methodological imperatives

    Directory of Open Access Journals (Sweden)

    DAVID A. NICHOLLS

    2009-01-01

    Full Text Available This paper presents an overview of the methodological approach taken in a recently completed Foucauldian discourse analysis of physiotherapy practice. In keeping with other approaches common to postmodern research this paper resists the temptation to define a proper or ‘correct’ interpretation of Foucault’s methodological oeuvre; preferring instead to apply a range of Foucauldian propositions to examples drawn directly from the thesis. In the paper I elucidate on the blended archaeological and genealogical approach I took and unpack some of the key imperatives, principles and rules I grappled with in completing the thesis.

  9. Categorical model of structural operational semantics for imperative language

    Directory of Open Access Journals (Sweden)

    William Steingartner

    2016-12-01

    Full Text Available Definition of programming languages consists of the formal definition of syntax and semantics. One of the most popular semantic methods used in various stages of software engineering is structural operational semantics. It describes program behavior in the form of state changes after execution of elementary steps of program. This feature makes structural operational semantics useful for implementation of programming languages and also for verification purposes. In our paper we present a new approach to structural operational semantics. We model behavior of programs in category of states, where objects are states, an abstraction of computer memory and morphisms model state changes, execution of a program in elementary steps. The advantage of using categorical model is its exact mathematical structure with many useful proved properties and its graphical illustration of program behavior as a path, i.e. a composition of morphisms. Our approach is able to accentuate dynamics of structural operational semantics. For simplicity, we assume that data are intuitively typed. Visualization and facility of our model is  not only  a  new model of structural operational semantics of imperative programming languages but it can also serve for education purposes.

  10. Introduction of solid food to young infants.

    Science.gov (United States)

    Kuo, Alice A; Inkelas, Moira; Slusser, Wendelin M; Maidenberg, Molly; Halfon, Neal

    2011-11-01

    Timing of the first introduction of solid food during infancy may have potential effects on life-long health. To understand the characteristics that are associated with the timing of infants' initial exposure to solid foods. The 2000 National Survey of Early Childhood Health (NSECH) was a nationally representative telephone survey of 2,068 parents of children aged 4-35 months, which profiled content and quality of health care for young children. African-American and Latino families were over-sampled. Analyses in this report include bivariate tests and logistic regressions. 62% of parents reported introducing solids to their child between 4-6 months of age. African-American mothers (OR=0.5 [0.3, 0.9]), English-speaking Latino mothers (OR=0.4 [0.2, 0.7]), White mothers with more than high school education (OR=0.5 [0.2, 1.0]), and mothers who breastfed for 4 months or longer (OR=0.4 [0.3, 0.7]) were less likely to introduce solids early. Most parents (92%) of children 4-9 months of age reported that their pediatric provider had discussed introduction of solids with them since the child's birth, and provider discussion of feeding was not associated with the timing of introduction of solids. Although most parents recall discussing the introduction of solid foods with their child's physician, several subgroups of mothers introduce solid foods earlier than the AAP recommendation of 4-6 months. More effective discussion of solid food introduction linked to counseling and support of breastfeeding by the primary health care provider may reduce early introduction of solids.

  11. The legal imperative to protect critical energy infrastructure

    Energy Technology Data Exchange (ETDEWEB)

    Shore, J.J.M.

    2008-03-15

    Canada's critical infrastructure is comprised of energy facilities, communications centres, finance, health care, food, government and transportation sectors. All sectors face a range of physical or cyber threats from terrorism and natural phenomenon. Failures or disruptions in the sectors can cascade through other systems and disrupt essential services. The power outage in 2003 demonstrated gaps in North America's emergency preparedness. In 2006, al-Qaida called for terrorist attacks on North American oil fields and pipelines, specifically targeting Canada. Studies have confirmed that Canada is vulnerable to attacks on energy infrastructure. Government agencies and the private sector must work ensure the safety of Canada's energy infrastructure, as the primary responsibility of government is the protection of its citizenry. The fulfilment of the government's commitment to national security cannot be achieved without protecting Canada's critical energy infrastructure. However, Canada has not yet provided a framework linking federal government with critical infrastructures, despite the fact that a draft strategy has been under development for several years. It was concluded that governments and the private sector should work together to reduce risks, protect the public, and secure the economy. National security litigation against the government and legal imperatives for energy facility owners and operators were also reviewed. 98 refs., 20 figs.

  12. Hate Won, but Love Will Have the Final Word: Critical Pedagogy, Liberation Theology, and the Moral Imperative of Resistance

    Science.gov (United States)

    Kirylo, James D

    2017-01-01

    In the context of the recent presidential election in the United States, this article examines the place of critical pedagogy and liberation theology and its positionality in impacting the moral imperative of resisting a climate of hate and intolerance. Particularly drawing from the work of Peter McLaren, Gustavo Gutiérrez, Paulo Freire and…

  13. Methane potential of sterilized solid slaughterhouse wastes.

    Science.gov (United States)

    Pitk, Peep; Kaparaju, Prasad; Vilu, Raivo

    2012-07-01

    The aim of the current study was to determine chemical composition and methane potential of Category 2 and 3 solid slaughterhouse wastes rendering products (SSHWRP) viz. melt, decanter sludge, meat and bone meal (MBM), technical fat and flotation sludge from wastewater treatment. Chemical analyses showed that SSHWRP were high in protein and lipids with total solids (TS) content of 96-99%. Methane yields of the SSHWRP were between 390 and 978 m(3) CH(4)/t volatile solids (VS)(added). Based on batch experiments, anaerobic digestion of SSHWRP from the dry rendering process could recover 4.6 times more primary energy than the energy required for the rendering process. Estonia has technological capacity to sterilize all the produced Category 2 and 3 solid slaughterhouse wastes (SSHW) and if separated from Category 1 animal by-products (ABP), it could be further utilized as energy rich input material for anaerobic digestion. Copyright © 2012 Elsevier Ltd. All rights reserved.

  14. Simulation as an ethical imperative and epistemic responsibility for the implementation of medical guidelines in health care.

    Science.gov (United States)

    Garbayo, Luciana; Stahl, James

    2017-03-01

    Guidelines orient best practices in medicine, yet, in health care, many real world constraints limit their optimal realization. Since guideline implementation problems are not systematically anticipated, they will be discovered only post facto, in a learning curve period, while the already implemented guideline is tweaked, debugged and adapted. This learning process comes with costs to human health and quality of life. Despite such predictable hazard, the study and modeling of medical guideline implementation is still seldom pursued. In this article we argue that to systematically identify, predict and prevent medical guideline implementation errors is both an epistemic responsibility and an ethical imperative in health care, in order to properly provide beneficence, minimize or avoid harm, show respect for persons, and administer justice. Furthermore, we suggest that implementation knowledge is best achieved technically by providing simulation modeling studies to anticipate the realization of medical guidelines, in multiple contexts, with system and scenario analysis, in its alignment with the emerging field of implementation science and in recognition of learning health systems. It follows from both claims that it is an ethical imperative and an epistemic responsibility to simulate medical guidelines in context to minimize (avoidable) harm in health care, before guideline implementation.

  15. Code development and analyses within the area of transmutation and safety

    International Nuclear Information System (INIS)

    Maschek, W.

    2002-01-01

    A strong code development is going on to meet various demands resulting from the development of dedicated reactors for transmutation and incineration. Code development is concerned with safety codes and general codes needed for assessing scenarios and transmutation strategies. Analyses concentrate on various ADS systems with solid and liquid molten salt fuels. Analyses deal with ADS Demo Plant (5th FP EU) and transmuters with advanced fuels

  16. Municipal Solid Waste Characterization according to Different Income Levels: A Case Study

    Directory of Open Access Journals (Sweden)

    Huseyin Kurtulus Ozcan

    2016-10-01

    Full Text Available Solid waste generation and characterization are some of the most important parameters which affect environmental sustainability. Municipal solid waste (MSW characterization depends on social structure and income levels. This study aims to determine the variations in waste components within MSW mass by income levels and seasonal conditions following the analysis conducted on the characterization of solid wastes produced in the Kartal district of the province of Istanbul, which is the research area of this study. To this end, 1.9 tons of solid waste samples were collected to represent four different lifestyles (high, medium, and low income levels, and downtown in the winter and summer periods, and characterization was made on these samples. In order to support waste characterization, humidity content and calorific value analyses were also conducted and various suggestions were brought towards waste management in line with the obtained findings. According to the results obtained in the study, organic waste had the highest rate of waste mass by 57.69%. Additionally, significant differences were found in municipal solid waste components (MSWC based on income level. Average moisture content (MC of solid waste samples was 71.1% in moisture analyses. The average of calorific (heating value (HHV was calculated as 2518.5 kcal·kg−1.

  17. Characteristics of soils and saprolite in Solid Waste Storage Area 6

    International Nuclear Information System (INIS)

    Ammons, J.T.; Phillips, D.H.; Timpson, M.E.

    1987-01-01

    Solid Waste Storage Area 6 (SWSA-6) is one of the disposal sites for solid low-level radioactive waste at Oak Ridge National Laboratory. Soils and saprolites from the site were characterized to provide base line information to initiate assessment for remedial actions and closure plans. Physical, chemical, mineralogical, and engineering analyses were conducted on soil and saprolite samples

  18. Solid-waste leach characteristics and contaminant-sediment interactions

    International Nuclear Information System (INIS)

    Serne, R.J.; LeGore, V.L.; Cantrell, K.J.; Lindenmeier, C.W.; Campbell, J.A.; Amonette, J.E.; Conca, J.L.; Wood, M.I.

    1993-10-01

    The objectives of this report and subsequent volumes include describing progress on (1) development of conceptual-release models for Hanford Site defense solid-waste forms; (2) optimization of experimental methods to quantify the release from contaminants from solid wastes and their subsequent interactions with unsaturated sediments; and (3) creation of empirical data for use as provisional source term and retardation factors that become input parameters for performance assessment analyses for future Hanford disposal units and baseline risk assessments for inactive and existing disposal units

  19. How dentists account for social responsibility: economic imperatives and professional obligations.

    Science.gov (United States)

    Dharamsi, Shafik; Pratt, Daniel D; MacEntee, Michael I

    2007-12-01

    This study explores how dentists explain the concept of social responsibility and its relationship to issues affecting access to oral health care by vulnerable segments of the population. Analysis of open-ended interviews with thirty-four dentists, including dental educators, and administrators and officials of dental public health programs in Canada and the United States revealed that four main themes-economics, professionalism, individual choice, and politics-influenced the respondents' sense of social responsibility in dentistry. There was a belief that social responsibility in dentistry is dominated by economic imperatives that impact negatively on the policies and practices directing access to care. Yet, despite the highly critical stance on dentistry as a business, there was practical recognition of the economic realities of dental practice. Nevertheless, those who focused on social responsibility as a professional obligation highlighted the privileges of self-governance along with the accompanying duty to serve the welfare of everyone and not just those who are socioeconomically advantaged.

  20. Older age impacts on survival outcome in patients receiving curative surgery for solid cancer

    Directory of Open Access Journals (Sweden)

    Chang-Hsien Lu

    2018-07-01

    Full Text Available Summary: Background: Given the global increase in aging populations and cancer incidence, understanding the influence of age on postoperative outcome after cancer surgery is imperative. This study aimed to evaluate the impact of age on survival outcome in solid cancer patients receiving curative surgery. Methods: A total of 37,288 patients receiving curative surgeries for solid cancers between 2007 and 2012 at four affiliated Chang Gung Memorial Hospital were included in the study. All patients were categorized into age groups by decades for survival analysis. Results: The percentages of patient populations aged <40 years, 40–49 years, 50–59 years, 60–69 years, 70–79 years, and ≥80 years were 9.7%, 17.7%, 27.8%, 22.1%, 16.9%, and 5.7%, respectively. The median follow-up period was 38.9 months (range, 22.8–60.4 months and the overall, cancer-specific, and noncancer-specific mortality rates were 26.0%, 17.6%, and 8.5%, respectively. The overall mortality rate of patients in different age groups were 18.5%, 21.1%, 22.0%, 25.3%, 35.3%, and 49.0%, respectively. Compared to patients aged <40 years, more significant decrease in long-term survival were observed in aging patients. Multivariate analysis showed higher postoperative short-term mortality rates in patients older than 70 years, and the adjusted odds ratio of mortality risk ranged from 1.47 to 1.74 and 2.26 to 3.03 in patients aged 70–79 years and ≥80 years, respectively, compared to those aged <40 years. Conclusion: Aging was a negative prognostic factor of survival outcome in solid cancer patients receiving curative surgery. After adjustment of other clinicopathologic factors, the influence of age on survival outcome was less apparent in the elderly. Keywords: Age, Solid cancer, Surgical resection, Prognosis

  1. The Primary Solid Waste Storage Gaps Experienced By Nairobi ...

    African Journals Online (AJOL)

    `123456789jkl''''#

    This study identifies and analyses the solid waste management service gaps and situations in these different socio-economic ... identifying gaps existing at primary (household) SW ... internal structure is based on land uses and income levels.

  2. Good governance in national solid waste management policy (NSWMP) implementation: A case study of Malaysia

    Science.gov (United States)

    Wee, Seow Ta; Abas, Muhamad Azahar; Mohamed, Sulzakimin; Chen, Goh Kai; Zainal, Rozlin

    2017-10-01

    The National Solid Waste Management Policy (NSWMP) was introduced in 2007 under the Act 672. The execution of NSWMP involves stakeholders from various government agencies and a collaboration with the private sectors. Despite the initiatives taken by the stakeholders, the objectives of NSWMP failed to materialise. One of the major constraints is weak governance among stakeholders with regards to the NSWMP implementation. This paper will explore the good governance practices implemented by the stakeholders. Identifying the current good governance practices implemented by the stakeholders is crucial as it will serve as a guideline to improve good governance practice in the future. An exploratory research approach is applied in this study through in-depth interviews with several government agencies and concessionaires involved in the NSWMP implementation. A total of six respondents took part in this study. The findings of this study show that there are several good governance practices implemented in policy promotion, participation of stakeholders, and capacity enhancement programme for the staff. This study also proposed some points on good governance practices in the context of policy promotion and staff development. A paradigm shift by the stakeholders is imperative so as to enhance the good governance practice in NSWMP implementation towards an efficient solid waste management in Malaysia.

  3. Solid angle subtended by two circular discs

    International Nuclear Information System (INIS)

    Gilly, Louis.

    1978-09-01

    Methods of calculation of solid angles, subtended by two circular discs are analysed. Calculus are methodically classified as follow: series development Legendre polynomes, defined integral, elliptic integrals, Bessel integrals, multiple integrals, Monte Carlo method, electrostatic analogy. Applications in Nuclear Physics are added as examples. List of numeric tables completes bibliography [fr

  4. Stress transmission in planar disordered solid foams

    International Nuclear Information System (INIS)

    Blumenfeld, Raphael

    2003-01-01

    Stress transmission in planar open-cell cellular solids is analysed using a recent theory developed for marginally rigid granular assemblies. This is made possible by constructing a one-to-one mapping between the two systems. General trivalent networks are mapped onto assemblies of rough grains, while networks where Plateau rules are observed, are mapped onto assemblies of smooth grains. The constitutive part of the stress transmission equations couples the stress directly to the local rotational disorder of the cellular structure via a new fabric tensor. An intriguing consequence of the analysis is that the stress field can be determined in terms of the microstructure alone independent of stress-strain information. This redefines the problem of structure-property relationship in these materials and poses questions on the relations between this formalism and elasticity theory. The deviation of the stress transmission equations from those of conventional solids has been interpreted in the context of granular assemblies as a new state of solid matter and the relevance of this interpretation to the state of matter of cellular solids is discussed

  5. Investigation of Tank 241-AN-101 Floating Solids

    Energy Technology Data Exchange (ETDEWEB)

    Kraft, Douglas P. [Washington River Protection Solutions, LLC, Richland, VA (United States); Meznarich, H. K. [Washington River Protection Solutions, LLC, Richland, VA (United States)

    2017-10-30

    Tank 241-AN-101 is the receiver tank for retrieval of several C-Farms waste tanks, including Tanks 241-C-102 and 241-C-111. Tank 241 C 111 received first-cycle decontamination waste from the bismuth phosphate process and Plutonium and Uranium Extraction cladding waste, as well as hydraulic fluid. Three grab samples, 1AN-16-01, 1AN-16-01A, and 1AN-16-01B, were collected at the surface of Tank 241-AN-101 on April 25, 2016, after Tank 241-C-111 retrieval was completed. Floating solids were observed in the three grab samples in the 11A hot cell after the samples were received at the 222-S Laboratory. Routine chemical analyses, solid phase characterization on the floating and settled solids, semivolatile organic analysis mainly on the aqueous phase for identification of degradation products of hydraulic fluids were performed. Investigation of the floating solids is reported.

  6. Analysis of solid-state transformations of pharmaceutical compounds using vibrational spectroscopy

    DEFF Research Database (Denmark)

    Heinz, Andrea; Strachan, Clare J; Gordon, Keith C

    2009-01-01

    OBJECTIVES: Solid-state transformations may occur during any stage of pharmaceutical processing and upon storage of a solid dosage form. Early detection and quantification of these transformations during the manufacture of solid dosage forms is important since the physical form of an active...... pharmaceutical ingredient can significantly influence its processing behaviour, including powder flow and compressibility, and biopharmaceutical properties such as solubility, dissolution rate and bioavailability. KEY FINDINGS: Vibrational spectroscopic techniques such as infrared, near-infrared, Raman and, most...... multivariate approaches where even overlapping spectral bands can be analysed. SUMMARY: This review discusses the applications of different vibrational spectroscopic techniques to detect and monitor solid-state transformations possible for crystalline polymorphs, hydrates and amorphous forms of pharmaceutical...

  7. Nuclear Hybrid Energy Systems: Imperatives, Prospects, and Challenges

    International Nuclear Information System (INIS)

    Aumeier, Steven E.

    2010-01-01

    As global population reaches an expected 8 billion people by 2030, primary energy consumption is expected to increase by almost 40% from approximately 520 exajoules consumed today to almost 740 exajoules. Much of this increase is expected to come from non-Organization for Economic Cooperation and Development (OECD) nations, and Asia specifically. In these economies, energy used for transportation is expected to grow substantially, as is industrial, commercial and to a lesser degree residential energy use, creating considerable pressure on global and local energy markets. The magnitude and timing of growth in energy consumption likely will create a global imperative to deploy energy production technologies that balance the three pillars of energy security: (1) economic stability - related to the affordability of energy products, stability and predictability in their price, and the efficient and effective deployment of global capital resources in their development; (2) environmental sustainability - related to minimizing the negative impacts of energy production to air, land, and water systems and advancing the long-term viability of using a particular resource in a way that does not limit future generations ability to prosper; (3) resource security - related to the ability to access energy resources and products where and when necessary, in an affordable and predictable manner. One approach to meeting these objectives is hybrid energy systems (HES). Broadly described, HES are energy product production plants that take two or more energy resource inputs (typically includes both carbon and non-carbon based sources) and produce two or more energy products (e.g. electricity, liquid transportation fuels, industrial chemicals) in an integrated plant. Nuclear energy integration into HES offers intriguing potential, particularly if smaller (<300 MWe) reactors are available. Although the concept of using nuclear energy in a variety of non-electrical process applications is

  8. Sierra/Solid Mechanics 4.48 User's Guide.

    Energy Technology Data Exchange (ETDEWEB)

    Merewether, Mark Thomas; Crane, Nathan K; de Frias, Gabriel Jose; Le, San; Littlewood, David John; Mosby, Matthew David; Pierson, Kendall H.; Porter, Vicki L.; Shelton, Timothy; Thomas, Jesse David; Tupek, Michael R.; Veilleux, Michael; Gampert, Scott; Xavier, Patrick G.; Plews, Julia A.

    2018-03-01

    Sierra/SolidMechanics (Sierra/SM) is a Lagrangian, three-dimensional code for finite element analysis of solids and structures. It provides capabilities for explicit dynamic, implicit quasistatic and dynamic analyses. The explicit dynamics capabilities allow for the efficient and robust solution of models with extensive contact subjected to large, suddenly applied loads. For implicit problems, Sierra/SM uses a multi-level iterative solver, which enables it to effectively solve problems with large deformations, nonlinear material behavior, and contact. Sierra/SM has a versatile library of continuum and structural elements, and a large library of material models. The code is written for parallel computing environments enabling scalable solutions of extremely large problems for both implicit and explicit analyses. It is built on the SIERRA Framework, which facilitates coupling with other SIERRA mechanics codes. This document describes the functionality and input syntax for Sierra/SM.

  9. SOME PROBLEMS ON JUMP CONDITIONS OF SHOCK WAVES IN 3-DIMENSIONAL SOLIDS

    Institute of Scientific and Technical Information of China (English)

    LI Yong-chi; YAO Lei; HU Xiu-zhang; CAO Jie-dong; DONG Jie

    2006-01-01

    Based on the general conservation laws in continuum mechanics, the Eulerian and Lagrangian descriptions of the jump conditions of shock waves in 3-dimensional solids were presented respectively. The implication of the jump conditions and their relations between each other, particularly the relation between the mass conservation and the displacement continuity, were discussed. Meanwhile the shock wave response curves in 3-dimensional solids, i.e. the Hugoniot curves were analysed, which provide the foundation for studying the coupling effects of shock waves in 3-dimensional solids.

  10. An Elusive Policy Imperative: Data and Methodological Challenges When Using Growth in Student Achievement to Evaluate Teacher Education Programs' "Value-Added"

    Science.gov (United States)

    Amrein-Beardsley, Audrey; Lawton, Kerry; Ronan, Katherine

    2017-01-01

    In this study researchers examined the effectiveness of one of the largest teacher education programs located within the largest research-intensive universities within the US. They did this using a value-added model as per current federal educational policy imperatives to assess the measurable effects of teacher education programs on their teacher…

  11. Synthesis of solid and hollow ATO spheres by carbothermal reduction of ATO nanoparticles

    International Nuclear Information System (INIS)

    Chai Chunfang; Huang Zaiyin; Liao Dankui; Tan Xuecai; Wu Jian; Yuan Aiqun

    2007-01-01

    Solid and hollow ATO spheres were fabricated by heating ATO nanoparticles and graphite mixture in a tube furnace. The as-synthesized samples were characterized by EDS, XRD, FE-SEM, TEM and HRTEM. The size of the solid spheres could be controlled by adjusting the rate of Ar flow and deposition positions. The hollow spheres were synthesized in an alumina tube system under conditions of a relatively high oxygen concentration. The growth mechanism of solid and hollow spheres was analysed

  12. Solid propellant impact tests

    International Nuclear Information System (INIS)

    Snow, E.C.

    1976-03-01

    Future space missions, as in the past, call for the continued use of radioisotopes as heat sources for thermoelectric power generators. In an effort to minimize the risk of radioactive contamination of the environment, a complete safety analysis of each such system is necessary. As a part of these analyses, the effects on such a system of a solid propellant fire environment resulting from a catastrophic launch pad abort must be considered. Several impact tests were conducted in which either a simulant MHW-FSA or a steel ball was dropped on the cold, unignited or the hot, burning surface of a block of UTP-3001 solid propellant. The rebound velocities were measured for both surface conditions of the propellant. The resulting coefficient of restitution, determined as the ratio of the components of the impact and rebound velocities perpendicular to the impact surface of the propellant, were not very dependent on whether the surface was cold or hot at the time of impact

  13. The Imperative for Research to Promote Health Equity in Indigenous Communities.

    Science.gov (United States)

    Stanley, Linda R; Swaim, Randall C; Kaholokula, Joseph Keawe'aimoku; Kelly, Kathleen J; Belcourt, Annie; Allen, James

    2017-11-06

    Health disparities exact a devastating toll upon Indigenous people in the USA. However, there has been scant research investment to develop strategies to address these inequities in Indigenous health. We present a case for increased health promotion, prevention, and treatment research with Indigenous populations, providing context to the recent NIH investment in the Intervention Research to Improve Native American Health (IRINAH) network. We discuss the disproportionate costs and consequences of disparities borne by Indigenous groups, the limited evidence base on effective intervention for this population, how population uniqueness often makes transfer of existing intervention models difficult, and additional challenges in creating interventions for Indigenous settings. Given the history of colonial disruption that has included genocide, forced removal from lands, damaging federal, state and local policies and practices, environmental contamination, and most recently, climate change, we conclude research that moves beyond minor transformations of existing majority population focused interventions, but instead truly respects Indigenous wisdom, knowledge, traditions, and aspirations is needed, and that investment in intervention science to address Indigenous health disparities represent a moral imperative.

  14. Freedom and imperative: mutual care between older spouses with physical disabilities.

    Science.gov (United States)

    Torgé, Cristina Joy

    2014-05-01

    This article explores mutual caregiving between older spouses aging with physical disabilities. Nine older couples, where both partners had lived long lives with physical disabilities, were interviewed as dyads about mutual caregiving. The couples not only had access to different kinds and degrees of formal support but also provided mutual care to each other in a variety of ways. Interview coding using grounded theory led to two overarching categories from which motivation for mutual caregiving could be understood. These categories were Mutual care as freedom and Mutual care as imperative. The results extend understanding about how older couples with disabilities attached meaning to their mutual caregiving, and why mutual care was sometimes preferable, despite the availability of other sources of help and despite practical difficulties of providing this help. These findings suggest that health care professionals need to be sensitive to the dynamics of the couple relationship and carefully explore the couple's preferences for how formal support can best be provided in ways that honor and sustain the integrity of the couple relationship.

  15. Emission control with route optimization in solid waste collection ...

    Indian Academy of Sciences (India)

    system is used, route distance and route time will be decreased by 24·6% and. 44·3% as ... Keywords. Exhaust emission; route optimization; solid waste collection; GIS, .... Catchment areas for a sales campaign can be analysed. Customers ...

  16. Phase I study of TP300 in patients with advanced solid tumors with pharmacokinetic, pharmacogenetic and pharmacodynamic analyses

    International Nuclear Information System (INIS)

    Anthoney, D Alan; Miwa, Masanori; Twelves, Christopher; Evans, TRJ; Naik, Jay; MacPherson, Iain RJ; Crawford, Donna; Hartley, John M; Hartley, Janet A; Saito, Tomohisa; Abe, Masaichi; Jones, Keith

    2012-01-01

    A Phase I dose escalation first in man study assessed maximum tolerated dose (MTD), dose-limiting toxicity (DLT) and recommended Phase II dose of TP300, a water soluble prodrug of the Topo-1 inhibitor TP3076, and active metabolite, TP3011. Eligible patients with refractory advanced solid tumors, adequate performance status, haematologic, renal, and hepatic function. TP300 was given as a 1-hour i.v. infusion 3-weekly and pharmacokinetic (PK) profiles of TP300, TP3076 and TP3011 were analysed. Polymorphisms in CYP2D6, AOX1 and UGT1A1 were studied and DNA strand-breaks measured in peripheral blood mononuclear cells (PBMCs). 32 patients received TP300 at 1, 2, 4, 6, 8, 10, 12 mg/m 2 . MTD was 10 mg/m 2 ; DLTs at 12 (2/4 patients) and 10 mg/m 2 (3/12) included thrombocytopenia and febrile neutropenia; diarrhoea was uncommon. Six patients (five had received irinotecan), had stable disease for 1.5-5 months. TP3076 showed dose proportionality in AUC and C max from 1–10 mg/m 2 . Genetic polymorphisms had no apparent influence on exposure. DNA strand-breaks were detected after TP300 infusion. TP300 had predictable hematologic toxicity, and diarrhoea was uncommon. AUC at MTD is substantially greater than for SN38. TP3076 and TP3011 are equi-potent with SN38, suggesting a PK advantage. EU-CTR2006-001345-33

  17. Sandis irradiator for dried sewage solids. Final safety analysis report

    International Nuclear Information System (INIS)

    Morris, M.

    1980-07-01

    Analyses of the hazards associated with the operation of the Sandia irradiator for dried sewage solids, as well as methods and design considerations to minimize these hazards, are presented in accordance with DOE directives

  18. Some aspects of the solid - liquid transition; Quelques aspects de la transition solide-liquide

    Energy Technology Data Exchange (ETDEWEB)

    Hicter, P [Ecole Nationale Superieure d' Electrochimie et d' Electrometallurgie, 38 - Grenoble (France); Malmejac, Y [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1965-05-01

    Current theories of fusion are analysed and grouped by analogies using a unified symbolism to facilitate comparisons. Theories are presented based on solid state vibrational models nucleation models, order-disorder models, vacancies and dislocations. For each model the authors have separated out the hypotheses underlying the theoretical analysis and defined the essential parts of the theoretical development. Principal results are compared with experimental data.(authors) [French] Les theories de la fusion les plus courantes sont analysees et groupees par analogies; la symbolique a ete unifiee pour faciliter les comparaisons. Sont presentes les modeles derivant des theories harmoniques de l'etat solide, des theories communautaires, de la theorie de l'ordre-desordre ainsi que des modeles en lacunes et en dislocations. Les auteurs ont pour chaque modele, degage les hypotheses, limite a l'essentiel les developpements theoriques, et presente les resultats principaux, confrontes avec les valeurs experimentales. (auteurs)

  19. Gaming industry employees' responses to responsible gambling training: a public health imperative.

    Science.gov (United States)

    LaPlante, Debi A; Gray, Heather M; LaBrie, Richard A; Kleschinsky, John H; Shaffer, Howard J

    2012-06-01

    Gaming industry employees work in settings that create personal health risks. They also have direct contact with customers who might engage in multiple risky activities (e.g., drinking, smoking, and gambling) and might need to facilitate help-seeking by patrons or co-workers who experience problems. Consequently, the empirical examination of the processes and procedures designed to prepare employees for such complex situations is a public health imperative. In the current study we describe an evaluation of the Casino, Inc. Play Responsibly responsible gaming program. We surveyed 217 employees prior to and 1 month after (n = 116) they completed a multimedia driven responsible gambling training program. We observed that employees improved their knowledge of responsible gambling concepts from baseline to follow-up. The Play Responsibly program was more successful in providing new knowledge than it was in correcting mistaken beliefs that existed prior to training. We conclude, generally, that Play Responsibly is associated with increases in employees' responsible gambling knowledge.

  20. COMPILATION OF DISPOSABLE SOLID WASTE CASK EVALUATIONS

    International Nuclear Information System (INIS)

    THIELGES, J.R.; CHASTAIN, S.A.

    2007-01-01

    The Disposable Solid Waste Cask (DSWC) is a shielded cask capable of transporting, storing, and disposing of six non-fuel core components or approximately 27 cubic feet of radioactive solid waste. Five existing DSWCs are candidates for use in storing and disposing of non-fuel core components and radioactive solid waste from the Interim Examination and Maintenance Cell, ultimately shipping them to the 200 West Area disposal site for burial. A series of inspections, studies, analyses, and modifications were performed to ensure that these casks can be used to safely ship solid waste. These inspections, studies, analyses, and modifications are summarized and attached in this report. Visual inspection of the casks interiors provided information with respect to condition of the casks inner liners. Because water was allowed to enter the casks for varying lengths of time, condition of the cask liner pipe to bottom plate weld was of concern. Based on the visual inspection and a corrosion study, it was concluded that four of the five casks can be used from a corrosion standpoint. Only DSWC S/N-004 would need additional inspection and analysis to determine its usefulness. The five remaining DSWCs underwent some modification to prepare them for use. The existing cask lifting inserts were found to be corroded and deemed unusable. New lifting anchor bolts were installed to replace the existing anchors. Alternate lift lugs were fabricated for use with the new lifting anchor bolts. The cask tiedown frame was modified to facilitate adjustment of the cask tiedowns. As a result of the above mentioned inspections, studies, analysis, and modifications, four of the five existing casks can be used to store and transport waste from the Interim Examination and Maintenance Cell to the disposal site for burial. The fifth cask, DSWC S/N-004, would require further inspections before it could be used

  1. COMPILATION OF DISPOSABLE SOLID WASTE CASK EVALUATIONS

    Energy Technology Data Exchange (ETDEWEB)

    THIELGES, J.R.; CHASTAIN, S.A.

    2007-06-21

    The Disposable Solid Waste Cask (DSWC) is a shielded cask capable of transporting, storing, and disposing of six non-fuel core components or approximately 27 cubic feet of radioactive solid waste. Five existing DSWCs are candidates for use in storing and disposing of non-fuel core components and radioactive solid waste from the Interim Examination and Maintenance Cell, ultimately shipping them to the 200 West Area disposal site for burial. A series of inspections, studies, analyses, and modifications were performed to ensure that these casks can be used to safely ship solid waste. These inspections, studies, analyses, and modifications are summarized and attached in this report. Visual inspection of the casks interiors provided information with respect to condition of the casks inner liners. Because water was allowed to enter the casks for varying lengths of time, condition of the cask liner pipe to bottom plate weld was of concern. Based on the visual inspection and a corrosion study, it was concluded that four of the five casks can be used from a corrosion standpoint. Only DSWC S/N-004 would need additional inspection and analysis to determine its usefulness. The five remaining DSWCs underwent some modification to prepare them for use. The existing cask lifting inserts were found to be corroded and deemed unusable. New lifting anchor bolts were installed to replace the existing anchors. Alternate lift lugs were fabricated for use with the new lifting anchor bolts. The cask tiedown frame was modified to facilitate adjustment of the cask tiedowns. As a result of the above mentioned inspections, studies, analysis, and modifications, four of the five existing casks can be used to store and transport waste from the Interim Examination and Maintenance Cell to the disposal site for burial. The fifth cask, DSWC S/N-004, would require further inspections before it could be used.

  2. Sierra/solid mechanics 4.22 user's guide.

    Energy Technology Data Exchange (ETDEWEB)

    Thomas, Jesse David

    2011-10-01

    Sierra/SolidMechanics (Sierra/SM) is a Lagrangian, three-dimensional code for the analysis of solids and structures. It provides capabilities for explicit dynamic and implicit quasistatic and dynamic analyses. The explicit dynamics capabilities allow for the efficient and robust solution of models subjected to large, suddenly applied loads. For implicit problems, Sierra/SM uses a multi-level iterative solver, which enables it to effectively solve problems with large deformations, nonlinear material behavior, and contact. Sierra/SM has a versatile library of continuum and structural elements, and an extensive library of material models. The code is written for parallel computing environments, and it allows for scalable solutions of very large problems for both implicit and explicit analyses. It is built on the SIERRA Framework, which allows for coupling with other SIERRA mechanics codes. This document describes the functionality and input structure for Sierra/SM.

  3. Solid Organic Deposition During Gas Injection Studies

    DEFF Research Database (Denmark)

    Dandekar, Abhijit Y.; Andersen, Simon Ivar; Stenby, Erling Halfdan

    2000-01-01

    Recently a series of first contact miscibility (swelling) experiments have been performed on undersaturated light and heavy oils using LPG rich and methane rich injection gases, in which solid organic deposition was observed. A compositional gradient in the oils during the gas injection process....... The asphaltene content of the different oil samples were determined by the TP 143 method. The standard asphaltenes and the solid organic deposit recovered from the swelling tests were analyzed using FTIR, HPLC-SEC and H-1 NMR. The aim of these analyses is to reveal the molecular nature of the deposits formed...... during the gas injection process in comparison with the standard asphaltenes in order to understand the mechanisms involved in asphaltene deposition....

  4. Nuclear and thermal analyses of supercritical-water-cooled solid breeder blanket for fusion DEMO reactor

    Energy Technology Data Exchange (ETDEWEB)

    Yanagi, Yoshihiko; Sato, Satoshi; Enoeda, Mikio; Hatano, Toshihisa; Kikuchi, Shigeto; Kuroda, Toshimasa; Kosaku, Yasuo; Ohara, Yoshihiro [Japan Atomic Energy Research Inst., Naka, Ibaraki (Japan). Naka Fusion Research Establishment

    2001-11-01

    Within a design study of a fusion DEMO reactor aiming at demonstrating technologies of fusion power plant, supercritical water is applied as a coolant of solid breeder blanket to attain high thermal efficiency. The blanket has multi-layer composed of solid breeder pebbles (Li{sub 2}O) and neutron multiplier pebbles (Be) which are radially separated by cooling panels. The first wall and the breeding region are cooled by supercritical water below and above the pseudo-critical temperature, respectively. Temperature distribution and tritium breeding ratio (TBR) have been estimated by one-dimensional nuclear and thermal calculations. The local TBR as high as 1.47 has been obtained after optimization of temperature distribution in the breeder region under the following conditions: neutron wall loading of 5 MW/m{sup 2}, {sup 6}Li enrichment of 30% and coolant temperature at inlet of breeder region of 380degC. In the case of the higher coolant temperature 430degC of the breeder region the local TBR was reduced to be 1.40. This means that the net TBR higher than 1.0 could be expected with the supercritical-water-cooled blanket, whose temperature distribution in the breeder region would be optimized by following the coolant temperature, and where a coverage of the breeder region is assumed to be 70%. (author)

  5. Gross alpha/beta analyses in water by liquid scintillation counting

    International Nuclear Information System (INIS)

    Wong, C.T.; Lawrence Livermore National Laboratory, CA; Soliman, V.M.; Perera, S.K.

    2005-01-01

    The standard procedure for analyzing gross alpha and gross beta in water is evaporation of the sample and radioactivity determination of the resultant solids by proportional counting. This technique lacks precision, and lacks sensitivity for samples with high total dissolved solids. Additionally, the analytical results are dependent on the choice of radionuclide calibration standard and the sample matrix. Direct analysis by liquid scintillation counting has the advantages of high counting efficiencies and minimal sample preparation time. However, due to the small sample aliquants used for analysis, long count times are necessary to reach required detection limits. The procedure proposed consists of evaporating a sample aliquant to dryness, dissolving the resultant solids in a small volume of dilute acid, followed by liquid scintillation counting to determine radioactivity. This procedure can handle sample aliquants containing up to 500 mg of dissolved solids. Various acids, scintillation cocktail mixtures, instrument discriminator settings, and regions of interest (ROI) were evaluated to determine optimum counting conditions. Precision is improved and matrix effects are reduced as compared to proportional counting. Tests indicate that this is a viable alternative to proportional counting for gross alpha and gross beta analyses of water samples. (author)

  6. Parametric study on vapor-solid-solid growth mechanism of multiwalled carbon nanotubes

    Energy Technology Data Exchange (ETDEWEB)

    Shukrullah, S., E-mail: zshukrullah@gmail.com [Center of Innovative Nanostructures and Nanodevices, Universiti Teknologi PETRONAS, 32610, Bandar Seri Iskandar, Perak (Malaysia); Mohamed, N.M. [Center of Innovative Nanostructures and Nanodevices, Universiti Teknologi PETRONAS, 32610, Bandar Seri Iskandar, Perak (Malaysia); Shaharun, M.S. [Department of Fundamental and Applied Sciences, Universiti Teknologi PETRONAS, 32610, Bandar Seri Iskandar, Perak (Malaysia); Naz, M.Y. [Department of Mechanical Engineering, Universiti Teknologi PETRONAS, 32610, Bandar Seri Iskandar, Perak (Malaysia)

    2016-06-15

    This study aimed at investigating the effect of the fluidized bed chemical vapor deposition (FBCVD) process parameters on growth mechanism, morphology and purity of the multiwalled carbon nanotubes (MWCNTs). Nanotubes were produced in a vertical FBCVD reactor by catalytic decomposition of ethylene over Al{sub 2}O{sub 3} supported nano-iron catalyst buds at different flow rates. FESEM, TEM, Raman spectroscopy and TGA thermograms were used to elaborate the growth parameters of the as grown MWCNTs. As the growth process was driven by the process temperatures well below the iron-carbon eutectic temperature (1147 °C), the appearance of graphite platelets from the crystallographic faces of the catalyst particles suggested a solid form of the catalyst during CNT nucleation. A vapor-solid-solid (VSS) growth mechanism was predicted for nucleation of MWCNTs with very low activation energy. The nanotubes grown at optimized temperature and ethylene flow rate posed high graphitic symmetry, purity, narrow diameter distribution and shorter inter-layer spacing. In Raman and TGA analyses, small I{sub D}/I{sub G} ratio and residual mass revealed negligible ratios of structural defects and amorphous carbon in the product. However, several structural defects and impurity elements were spotted in the nanotubes grown under unoptimized process parameters. - Graphical abstract: Arrhenius plot of relatively pure MWCNTs grown over Al2O3 supported nano-iron buds. - Highlights: • Vapor–solid–solid growth mechanism of MWCNTs was studied in a vertical FBCVD reactor. • MWCNTs were grown over Al2O3 supported nano-iron buds at very low activation energy. • FBCVD reactor was operated at temperatures well below the iron-carbon eutectic point. • Ideally graphitized structures were obtained at a process temperature of 800 °C. • Tube diameter revealed a narrow distribution of 20–25 nm at the optimum temperature.

  7. Parametric study on vapor-solid-solid growth mechanism of multiwalled carbon nanotubes

    International Nuclear Information System (INIS)

    Shukrullah, S.; Mohamed, N.M.; Shaharun, M.S.; Naz, M.Y.

    2016-01-01

    This study aimed at investigating the effect of the fluidized bed chemical vapor deposition (FBCVD) process parameters on growth mechanism, morphology and purity of the multiwalled carbon nanotubes (MWCNTs). Nanotubes were produced in a vertical FBCVD reactor by catalytic decomposition of ethylene over Al_2O_3 supported nano-iron catalyst buds at different flow rates. FESEM, TEM, Raman spectroscopy and TGA thermograms were used to elaborate the growth parameters of the as grown MWCNTs. As the growth process was driven by the process temperatures well below the iron-carbon eutectic temperature (1147 °C), the appearance of graphite platelets from the crystallographic faces of the catalyst particles suggested a solid form of the catalyst during CNT nucleation. A vapor-solid-solid (VSS) growth mechanism was predicted for nucleation of MWCNTs with very low activation energy. The nanotubes grown at optimized temperature and ethylene flow rate posed high graphitic symmetry, purity, narrow diameter distribution and shorter inter-layer spacing. In Raman and TGA analyses, small I_D/I_G ratio and residual mass revealed negligible ratios of structural defects and amorphous carbon in the product. However, several structural defects and impurity elements were spotted in the nanotubes grown under unoptimized process parameters. - Graphical abstract: Arrhenius plot of relatively pure MWCNTs grown over Al2O3 supported nano-iron buds. - Highlights: • Vapor–solid–solid growth mechanism of MWCNTs was studied in a vertical FBCVD reactor. • MWCNTs were grown over Al2O3 supported nano-iron buds at very low activation energy. • FBCVD reactor was operated at temperatures well below the iron-carbon eutectic point. • Ideally graphitized structures were obtained at a process temperature of 800 °C. • Tube diameter revealed a narrow distribution of 20–25 nm at the optimum temperature.

  8. Discovery of Microorganisms and Enzymes Involved in High-Solids Decomposition of Rice Straw Using Metagenomic Analyses

    Science.gov (United States)

    D’haeseleer, Patrik; Khudyakov, Jane; Burd, Helcio; Hadi, Masood; Simmons, Blake A.; Singer, Steven W.; Thelen, Michael P.; VanderGheynst, Jean S.

    2013-01-01

    High-solids incubations were performed to enrich for microbial communities and enzymes that decompose rice straw under mesophilic (35°C) and thermophilic (55°C) conditions. Thermophilic enrichments yielded a community that was 7.5 times more metabolically active on rice straw than mesophilic enrichments. Extracted xylanase and endoglucanse activities were also 2.6 and 13.4 times greater, respectively, for thermophilic enrichments. Metagenome sequencing was performed on enriched communities to determine community composition and mine for genes encoding lignocellulolytic enzymes. Proteobacteria were found to dominate the mesophilic community while Actinobacteria were most abundant in the thermophilic community. Analysis of protein family representation in each metagenome indicated that cellobiohydrolases containing carbohydrate binding module 2 (CBM2) were significantly overrepresented in the thermophilic community. Micromonospora, a member of Actinobacteria, primarily housed these genes in the thermophilic community. In light of these findings, Micromonospora and other closely related Actinobacteria genera appear to be promising sources of thermophilic lignocellulolytic enzymes for rice straw deconstruction under high-solids conditions. Furthermore, these discoveries warrant future research to determine if exoglucanases with CBM2 represent thermostable enzymes tolerant to the process conditions expected to be encountered during industrial biofuel production. PMID:24205054

  9. Discovery of microorganisms and enzymes involved in high-solids decomposition of rice straw using metagenomic analyses.

    Directory of Open Access Journals (Sweden)

    Amitha P Reddy

    Full Text Available High-solids incubations were performed to enrich for microbial communities and enzymes that decompose rice straw under mesophilic (35°C and thermophilic (55°C conditions. Thermophilic enrichments yielded a community that was 7.5 times more metabolically active on rice straw than mesophilic enrichments. Extracted xylanase and endoglucanse activities were also 2.6 and 13.4 times greater, respectively, for thermophilic enrichments. Metagenome sequencing was performed on enriched communities to determine community composition and mine for genes encoding lignocellulolytic enzymes. Proteobacteria were found to dominate the mesophilic community while Actinobacteria were most abundant in the thermophilic community. Analysis of protein family representation in each metagenome indicated that cellobiohydrolases containing carbohydrate binding module 2 (CBM2 were significantly overrepresented in the thermophilic community. Micromonospora, a member of Actinobacteria, primarily housed these genes in the thermophilic community. In light of these findings, Micromonospora and other closely related Actinobacteria genera appear to be promising sources of thermophilic lignocellulolytic enzymes for rice straw deconstruction under high-solids conditions. Furthermore, these discoveries warrant future research to determine if exoglucanases with CBM2 represent thermostable enzymes tolerant to the process conditions expected to be encountered during industrial biofuel production.

  10. Encapsulation of solid dispersion in solid lipid particles for dissolution enhancement of poorly water-soluble drug.

    Science.gov (United States)

    Tran, Khanh Thi My; Vo, Toi Van; Tran, Phuong Ha-Lien; Lee, Beom-Jin; Duan, Wei; Tran, Thao Truong-Dinh

    2017-06-05

    The aim of this research was to engineer solid dispersion lipid particles (SD-SLs) in which a solid dispersion (SD) was encapsulated to form the core of solid lipid particles (SLs), thereby achieving an efficient enhancement in the dissolution of a poorly water-soluble drug. Ultrasonication was introduced into the process to obtain micro/nanoscale SLs. The mechanism of dissolution enhancement was investigated by analysing the crystalline structure, molecular interactions, and particle size of the formulations. The drug release from the SD-SLs was significantly greater than that from the SD or SLs alone. This enhancement in drug release was dependent on the preparation method and the drug-to-polymer ratio of the SD. With an appropriate amount of polymer in the SD, the solidification method had the potential to alter the drug crystallinity to an amorphous state, resulting in particle uniformity and molecular interactions in the SD-SLs. The proposed system provides a new strategy for enhancing the dissolution rate of poorly water-soluble drugs and further improving their bioavailability. Copyright© Bentham Science Publishers; For any queries, please email at epub@benthamscience.org.

  11. Culture shift: an imperative for future survival.

    Science.gov (United States)

    Muroff, Lawrence R

    2013-02-01

    Radiologists have experienced unprecedented prosperity for the past 3 decades. Technology has continually evolved, providing exciting opportunities for earlier diagnoses and improved patient care. The financial rewards enjoyed by radiologists have been impressive, and the quality of life has been difficult to beat. Circumstances change, and in the past few years, radiologists have been confronted with a variety of new challenges. These trends include declining reimbursement, an "image problem" at both the local and the national levels, more demanding hospital administrations, nontraditional competition from national entrepreneurial radiology entities for radiology hospital contracts, and alternative payment systems. The author outlines the genesis of these trends, describes strategies for meeting these challenges, and discusses the roles of both radiology practices and the ACR in preparing radiologists for the threats and the opportunities that lie ahead. Although it will be important for radiologists to "get to the table" to participate fully in the new health care environment, it will be imperative for radiologists to know what to do once they are at the table. This is not "business as usual," and for radiologists, there will be winners and losers in the coming years. It will take work to succeed, and the apathy, denial, and sense of entitlement that have characterized our practitioners must be replaced by service, visibility, health policy data, and "value-added" information for referring physicians and their patients. The future for radiology is bright; the future for radiologists is far less certain. Strategic planning, scenario planning, practice building, and the efficient provision of high-quality patient care are the keys for radiologists to succeed. Radiologists must integrate themselves into the medical, social, and political fabrics of their hospitals and their communities, and they will need to get the in-depth leadership training and the important

  12. Laser generation of nanostructures on the surface and in the bulk of solids

    International Nuclear Information System (INIS)

    Bityurin, N M

    2010-01-01

    This paper considers nanostructuring of solid surfaces by nano-optical techniques, primarily by laser particle nanolithography. Threshold processes are examined that can be used for laser structuring of solid surfaces, with particular attention to laser swelling of materials. Fundamental spatial resolution issues in three-dimensional (3D) laser nanostructuring are analysed with application to laser nanopolymerisation and 3D optical information recording. The formation of nanostructures in the bulk of solids due to their structural instability under irradiation is exemplified by photoinduced formation of nanocomposites. (photonics and nanotechnology)

  13. Science and the common good: indefinite, non-reviewable mandatory detention of asylum seekers and the research imperative.

    Science.gov (United States)

    Steel, Zachary; Silove, Derrick

    2004-10-01

    Despite a strong historical record of resettling and providing care for refugee populations, the Australian Federal Government has increasingly implemented harsh and restrictive policies regarding the treatment and management of asylum seekers. Most controversial of these has been the mandatory detention of asylum seekers, a policy applied indiscriminately and without discretion where individual cases have not been subject to judicial review or time constraints. From the outset health professionals have raised concerns about the possible adverse mental health impacts of prolonged detention. In contrast, government representatives have characterized conditions in detention as benign and comfortable, and have consistently contested criticism of detention, often citing a lack of scientific evidence as tacit support for the continuation of the policy. Nevertheless, requests for access to the detention centres to undertake rigorous scientific investigations have gone unheeded. In this context we argue that the Australian Government has failed to uphold its commitment to good governance by allowing transparency, openness and a willingness to have the impact of its policies scrutinized by scientists. The manifest conflict of interest in the government position leads to a breach in the normal social contract between mental health researchers and those responsible for the policy of detention. There is, we argue, a legitimate moral imperative in such situations for clinical researchers to breach the walls of enforced silence and give a voice to those who are afflicted. This imperative, however, must be carefully balanced against the risks that may face detainees agreeing to participate in such research.

  14. Physician Training in Cancer Prevention and Control: A Population Health Imperative.

    Science.gov (United States)

    Moore, Miranda A; Goodman, Richard A

    2018-03-01

    Cancer is the second leading cause of morbidity and mortality in the U.S. Although reducing the number of new cancer cases is a national health goal, the continuing growth of the older adult population ensures that the burden of cancer will increase. Despite documentation of the shortage of oncologists to meet the growing need, relatively limited attention has been focused on increasing the physician workforce trained in the prevention and control of cancer. The existing physician workforce with such specialized training in cancer prevention and control is small, aging, increasing at a low rate, and likely to decrease because of an imbalance between retiring physicians and new entrants. This commentary addresses the imperative for increasing the number of physicians trained in preventive medicine with a specialization in cancer prevention and control by first providing a brief overview of U.S. cancer morbidity and mortality, then describing the status of, and trends in, physician training in cancer prevention and control, and concluding by suggesting opportunities for bolstering physician training in cancer prevention and control. Copyright © 2018 American Journal of Preventive Medicine. Published by Elsevier Inc. All rights reserved.

  15. Sample Results from MCU Solids Outage

    Energy Technology Data Exchange (ETDEWEB)

    Peters, T.; Washington, A.; Oji, L.; Coleman, C.; Poirier, M.

    2014-09-22

    additional details are provided below as recommendations. From this point on, IC-Anions analyses of the DSSHT should be part of the monthly routine analysis in order to spot negative trends in the oxalate leaving the MCU system. Care must be taken to monitor the oxalate content to watch for sudden precipitation of oxalate salts in the system; Conduct a study to optimize the cleaning strategy at ARP-MCU through decreasing the concentration or entirely eliminating the oxalic acid; The contents of the SSFT should remain unagitated. Routine visual observation should be maintained to ensure there is not a large buildup of solids. As water with agitation provided sufficient removal of the solids in the feed tank, it should be considered as a good means for dissolving oxalate solids if they are found in the future; Conduct a study to improve prediction of oxalate solubility in salt batch feed materials. As titanium and mercury have been found in various solids in this report, evaluate if either element plays a role in oxalate solubility during processing; Salt batch characterization focuses primarily on characterization and testing of unaltered Tank 21H material; however, non-typical feeds are developed through cleaning, washing, and/or sump transfers. As these solutions are processed through MCU, they may precipitate solids or reduce performance. Salt batch characterization and testing should be expanded to encompass a broader range of feeds that may be processed through ARPMCU.

  16. Comparative analysis of solid waste management in 20 cities

    NARCIS (Netherlands)

    Wilson, D.C.; Rodic-Wiersma, L.; Scheinberg, A.; Velis, C.A.; Alabaster, G.

    2012-01-01

    This paper uses the ‘lens’ of integrated and sustainable waste management (ISWM) to analyse the new data set compiled on 20 cities in six continents for the UN-Habitat flagship publication Solid Waste Management in the World’s Cities. The comparative analysis looks first at waste generation rates

  17. Experimental characterization of solid particle transport by slug flow using Particle Image Velocimetry

    International Nuclear Information System (INIS)

    Goharzadeh, A; Rodgers, P

    2009-01-01

    This paper presents an experimental study of gas-liquid slug flow on solid particle transport inside a horizontal pipe with two types of experiments conducted. The influence of slug length on solid particle transportation is characterized using high speed photography. Using combined Particle Image Velocimetry (PIV) with Refractive Index Matching (RIM) and fluorescent tracers (two-phase oil-air loop) the velocity distribution inside the slug body is measured. Combining these experimental analyses, an insight is provided into the physical mechanism of solid particle transportation due to slug flow. It was observed that the slug body significantly influences solid particle mobility. The physical mechanism of solid particle transportation was found to be discontinuous. The inactive region (in terms of solid particle transport) upstream of the slug nose was quantified as a function of gas-liquid composition and solid particle size. Measured velocity distributions showed a significant drop in velocity magnitude immediately upstream of the slug nose and therefore the critical velocity for solid particle lifting is reached further upstream.

  18. Automated, Ultra-Sterile Solid Sample Handling and Analysis on a Chip

    Science.gov (United States)

    Mora, Maria F.; Stockton, Amanda M.; Willis, Peter A.

    2013-01-01

    There are no existing ultra-sterile lab-on-a-chip systems that can accept solid samples and perform complete chemical analyses without human intervention. The proposed solution is to demonstrate completely automated lab-on-a-chip manipulation of powdered solid samples, followed by on-chip liquid extraction and chemical analysis. This technology utilizes a newly invented glass micro-device for solid manipulation, which mates with existing lab-on-a-chip instrumentation. Devices are fabricated in a Class 10 cleanroom at the JPL MicroDevices Lab, and are plasma-cleaned before and after assembly. Solid samples enter the device through a drilled hole in the top. Existing micro-pumping technology is used to transfer milligrams of powdered sample into an extraction chamber where it is mixed with liquids to extract organic material. Subsequent chemical analysis is performed using portable microchip capillary electrophoresis systems (CE). These instruments have been used for ultra-highly sensitive (parts-per-trillion, pptr) analysis of organic compounds including amines, amino acids, aldehydes, ketones, carboxylic acids, and thiols. Fully autonomous amino acid analyses in liquids were demonstrated; however, to date there have been no reports of completely automated analysis of solid samples on chip. This approach utilizes an existing portable instrument that houses optics, high-voltage power supplies, and solenoids for fully autonomous microfluidic sample processing and CE analysis with laser-induced fluorescence (LIF) detection. Furthermore, the entire system can be sterilized and placed in a cleanroom environment for analyzing samples returned from extraterrestrial targets, if desired. This is an entirely new capability never demonstrated before. The ability to manipulate solid samples, coupled with lab-on-a-chip analysis technology, will enable ultraclean and ultrasensitive end-to-end analysis of samples that is orders of magnitude more sensitive than the ppb goal given

  19. Municipal Solid Waste management

    OpenAIRE

    Mirakovski, Dejan; Hadzi-Nikolova, Marija; Doneva, Nikolinka

    2010-01-01

    Waste management covers newly generated waste or waste from an onging process. When steps to reduce or even eliminate waste are to be considered, it is imperative that considerations should include total oversight, technical and management services of the total process.From raw material to the final product this includes technical project management expertise, technical project review and pollution prevention technical support and advocacy.Waste management also includes handling of waste, in...

  20. Sustainability: A new imperative in contaminated land remediation

    International Nuclear Information System (INIS)

    Hou, Deyi; Al-Tabbaa, Abir

    2014-01-01

    . The paper concludes that “sustainability” is becoming a new imperative in the environmental remediation field, with important implications for regulators, liability owners, consultants, contractors, and technology vendors

  1. Deciphering the imperative: translating public health quality improvement into organizational performance management gains.

    Science.gov (United States)

    Beitsch, Leslie M; Yeager, Valerie A; Moran, John

    2015-03-18

    With the launching of the national public health accreditation program under the auspices of the Public Health Accreditation Board (PHAB), health department momentum around quality improvement adoption has accelerated. Domain 9 of the PHAB standards (one of 12 domains) focuses on evaluation and improvement of performance and is acting as a strong driver for quality improvement and performance management implementation within health departments. Widespread adoption of quality improvement activities in public health trails that in other US sectors. Several performance management models have received broad acceptance, including models among government and nonprofits. A model specifically for public health has been developed and is presented herein. All models in current use reinforce customer focus; streamlined, value-added processes; and strategic alignment. All are structured to steer quality improvement efforts toward organizational priorities, ensuring that quality improvement complements performance management. High-performing health departments harness the synergy of quality improvement and performance management, providing powerful tools to achieve public health strategic imperatives.

  2. Solid municipal waste processing plants: Cost benefit analysis

    International Nuclear Information System (INIS)

    Gerardi, V.

    1992-01-01

    This paper performs cost benefit analyses on three solid municipal waste processing alternatives with plants of diverse daily outputs. The different processing schemes include: selected wastes incineration with the production of refuse derived fuels; selected wastes incineration with the production of refuse derived fuels and compost; pyrolysis with energy recovery in the form of electric power. The plant daily outputs range from 100 to 300 tonnes for the refuse derived fuel alternatives, and from 200 to 800 tonnes for the pyrolysis/power generation scheme. The cost analyses consider investment periods of fifteen years in duration and interest rates of 5%

  3. Imperatives for an agricultural green economy in South Africa

    Directory of Open Access Journals (Sweden)

    Constansia Musvoto

    2015-01-01

    Full Text Available Globally, there are social, economic and environmental challenges related to sustainable development; these challenges include climate change, the need to feed a rapidly increasing population, high rates of poverty and environmental degradation. These challenges have forced us to rethink the way in which development takes place, resulting in the emergence of the concept of a �green economy�. A green economy results in improved human well-being and social equity, while significantly reducing risks to the environment. It is based on principles which integrate social, economic and environmental considerations. South Africa has adopted the principle of green economic growth, and agriculture is one of the sectors that will drive this growth. Agriculture could address some of the sustainable development problems, but there are challenges related to resource availability, environmental impacts of agriculture and climate change. For agriculture to support a green economy it has to be productive, contribute to economic growth and not undermine the environment, social and cultural systems. The information base and policies required to support a green economy in general, and/or an agriculture-supported green economy have not yet been developed, as the green economy is an emerging concept in South Africa as well as globally. The generation of such information requires analysis and synthesis of green economy principles and agricultural imperatives into generic principles and practices for facilitating agriculture�s contribution to the green economy. In this paper, we conduct this analysis and synthesis and highlight the defining aspects of an agricultural green economy.

  4. Solid waste containing method and solid waste container

    International Nuclear Information System (INIS)

    Sawai, Takeshi.

    1997-01-01

    Solid wastes are filled in a sealed vessel, and support spacers are inserted to the gap between the inner wall of a vessel main body and the solid wastes. The solid wastes comprise shorn pieces (crushed pieces) of spent fuel rod cladding tubes, radioactively contaminated metal pieces and miscellaneous solids pressed into a disk-like shape. The sealed vessel comprises, for example, a stainless steel. The solid wastes are filled while being stacked in a plurality of stages. A solidifying filler is filled into the gap between the inner wall and the solid wastes in the vessel main body by way of an upper opening, and the upper opening is closed by a closing lid to provide an entirely sealed state. Alumina particles having high heat conductivity and excellent heat durability are used for the solid filler. It is preferable to fill an inert gas such as a dried nitrogen gas in the sealed vessel. (I.N.)

  5. Solid and liquid radioactive wastes

    International Nuclear Information System (INIS)

    Cluchet, J.; Desroches, J.

    1977-01-01

    The problems raised by the solid and liquid radioactive wastes from the CEA nuclear centres are briefly exposed. The processing methods developed at the Saclay centre are described together with the methods for the wastes from nuclear power plants and reprocessing plants. The different storage techniques used at the La Hague centre are presented. The production of radioactive wastes by laboratories, hospitals and private industry is studied for the sealed sources and the various radioactive substances used in these plants. The cost of the radioactive wastes is analysed: processing, transport, long term storage [fr

  6. The evolution of hot-stage microscopy to aid solid-state characterizations of pharmaceutical solids

    International Nuclear Information System (INIS)

    Vitez, I.M.; Davidovich, M.; Newman, A.W.; Kiesnowski, C.

    1998-01-01

    A variety of techniques can be used to characterize the physical properties of pharmaceutical solids, including thermal analysis, hot-stage microscopy, X-ray powder diffraction, spectroscopic and micromeritic analysis. Comprehensive characterizations of the physical properties of pharmaceutical solids require a multi-disciplinary approach, since no single technique is capable of characterizing the materials completely.The combination of traditional hot-stage microscopy with new technologies such as high-resolution micrography, image capture, storage manipulation, and presentation, have permitted more comprehensive physical property characterizations to be conducted. As a result of these technological advances, it is possible to present the results of these microscopic analyses, as they were initially collected by the microscopist, outside of the laboratory.An evolutionary trail detailing the use of hot-stage microscopy in the Materials Science Group, from a simple melting point apparatus to the current hot-stage DSC microscopy instrument, will be presented. Examples of materials characterized using the hot-stage microscopy system will also be presented. (Copyright (c) 1998 Elsevier Science B.V., Amsterdam. All rights reserved.)

  7. An Interactive Learning Environment for Teaching the Imperative and Object-Oriented Programming Techniques in Various Learning Contexts

    Science.gov (United States)

    Xinogalos, Stelios

    The acquisition of problem-solving and programming skills in the era of knowledge society seems to be particularly important. Due to the intrinsic difficulty of acquiring such skills various educational tools have been developed. Unfortunately, most of these tools are not utilized. In this paper we present the programming microworlds Karel and objectKarel that support the procedural-imperative and Object-Oriented Programming (OOP) techniques and can be used for supporting the teaching and learning of programming in various learning contexts and audiences. The paper focuses on presenting the pedagogical features that are common to both environments and mainly on presenting the potential uses of these environments.

  8. IS THE ETHICS OF ECONOMIES ADAPTED OR NOT TO THE IMPERATIVE OF BIOETHICS

    Directory of Open Access Journals (Sweden)

    Dejan Donev

    2012-09-01

    Full Text Available The ethics in economy is not only a corrector, but also must be initiator if we want to achieve essence of our existence - the human being as “Homo ethicus”, as well as, which is more important for mankind - to achieve a human being as “Homo homine ethica ethicus est”. This remark points on two things. First: we came to the stage where we become aware about the fact that our economies are dehumanized. The second: that’s the reason why we must return to ethics and pull out from it that universal values which will make the managers of natural recourses more ethically awarded, so they will be able to start managing production without endangering bio potentials anymore. Previous remark lead us to conclusion that, no matter if the idiom “business ethics” is oxymoron or not, the present ethics is more a list of rules of conduction or, more precisely, etiquette. This clearly points that this kind of ethics of economy and in economy is not adoptive to the imperative of Bioethics: Don’t misuse recourses if you want to feed yourself and those for which you create the existence! This is so because always when we talk about ethics and ethicizing of those which managing the base of existence, de facto, are discussions about choosing the appropriate model of capitalism. The problem of these “discussions” is that we almost always forget to explain: is the chosen model of capitalization of society applicable considering the local specifics and needs of community? Therefore, the imperative of Bioethics, in this context, is to teach the ethics how to think about bio resource and bio heritage, even if we stop talk of some kinds of ethics and ethicizing of economies and of those which managing with it, because if we reconsider the reactions of the population, it is clear that they are seek of talking about it. But also, it’s recognizable the fact that they who talks just show that the essential thinking about Bioethics is absent and that the

  9. Theorizing the lesbian hashtag: Identity, community, and the technological imperative to name the sexual self.

    Science.gov (United States)

    Herrera, Andrea P

    2017-11-27

    This analysis integrates poststructuralist and symbolic interactionist approaches to the self by incorporating the insights of science and technology studies regarding categorization processes. While the advent of the Internet has freed many individuals from geographical constraints on community formation, the architectures of online platforms produce a technological imperative to name aspects of the self with words. Using sexual identity hashtags on Instagram (e.g., #lesbian) thus performs paradoxical functions: the hashtag both enables the construction of a sexual identity within an affirming community and also reinforces the power relations that compel individuals to name and account for their sexual selves. By illustrating one way sexual identities function in the online lives of young women, this research complicates other scholars' findings that the salience of sexual identity categories is decreasing.

  10. Screening for substance abuse in women's health: a public health imperative.

    Science.gov (United States)

    Goodman, Daisy J; Wolff, Kristina B

    2013-01-01

    Alcohol and drug use is a significant public health problem with particular implications for the health and safety of women. Women who abuse these substances are more likely to have untreated depression and anxiety and are at higher risk for intimate partner violence, homelessness, incarceration, infectious disease, and unplanned pregnancy. Substance abuse during pregnancy places both mother and fetus at risk for adverse perinatal outcomes. Data regarding the prevalence of substance abuse in women are conflicting and difficult to interpret. On the clinical level, strong arguments exist against routine urine drug testing and in favor of the use of validated instruments to screen women for drug and alcohol use both in primary women's health care and during pregnancy. A number of sex-specific screening tools are available for clinicians, some of which have also been validated for use during pregnancy. Given the risks associated with untreated substance abuse and dependence in women, the integration of drug and alcohol screening into daily clinical practice is imperative. This article reviews screening tools available to providers in both the prenatal and primary women's health care settings and addresses some of the challenges raised when women screen positive for drug and alcohol abuse. © 2013 by the American College of Nurse-Midwives.

  11. Greenhouse gas emissions from solid waste in Beijing: The rising trend and the mitigation effects by management improvements.

    Science.gov (United States)

    Yu, Yongqiang; Zhang, Wen

    2016-04-01

    Disposal of solid waste poses great challenges to city managements. Changes in solid waste composition and disposal methods, along with urbanisation, can certainly affect greenhouse gas emissions from municipal solid waste. In this study, we analysed the changes in the generation, composition and management of municipal solid waste in Beijing. The changes of greenhouse gas emissions from municipal solid waste management were thereafter calculated. The impacts of municipal solid waste management improvements on greenhouse gas emissions and the mitigation effects of treatment techniques of greenhouse gas were also analysed. Municipal solid waste generation in Beijing has increased, and food waste has constituted the most substantial component of municipal solid waste over the past decade. Since the first half of 1950s, greenhouse gas emission has increased from 6 CO2-eq Gg y(-1)to approximately 200 CO2-eq Gg y(-1)in the early 1990s and 2145 CO2-eq Gg y(-1)in 2013. Landfill gas flaring, landfill gas utilisation and energy recovery in incineration are three techniques of the after-emission treatments in municipal solid waste management. The scenario analysis showed that three techniques might reduce greenhouse gas emissions by 22.7%, 4.5% and 9.8%, respectively. In the future, if waste disposal can achieve a ratio of 4:3:3 by landfill, composting and incineration with the proposed after-emission treatments, as stipulated by the Beijing Municipal Waste Management Act, greenhouse gas emissions from municipal solid waste will decrease by 41%. © The Author(s) 2016.

  12. Waves in microstructured solids and negative group velocity

    Science.gov (United States)

    Peets, T.; Kartofelev, D.; Tamm, K.; Engelbrecht, J.

    2013-07-01

    Waves with negative group velocity (NGV) were discovered in optics by Sommerfeld and Brillouin, and experimentally verified in many cases, for example in left-handed media. For waves in solids, such an effect is described mostly in layered media. In this paper, it is demonstrated that in microstructured solids, waves with NGV may also exist leading to backwards pulse propagation. Two physical cases are analysed: a Mindlin-type hierarchical (a scale within a scale) material and a felt-type (made of fibres) material. For both cases, the dispersion analysis of one-dimensional waves shows that there exists certain ranges of physical parameters which lead to NGV. The results can be used in dispersion engineering for designing materials with certain properties.

  13. Fully coupled heat conduction and deformation analyses of visco-elastic solids

    KAUST Repository

    Khan, Kamran

    2012-04-21

    Visco-elastic materials are known for their capability of dissipating energy. This energy is converted into heat and thus changes the temperature of the materials. In addition to the dissipation effect, an external thermal stimulus can also alter the temperature in a viscoelastic body. The rate of stress relaxation (or the rate of creep) and the mechanical and physical properties of visco-elastic materials, such as polymers, vary with temperature. This study aims at understanding the effect of coupling between the thermal and mechanical response that is attributed to the dissipation of energy, heat conduction, and temperature-dependent material parameters on the overall response of visco-elastic solids. The non-linearly viscoelastic constitutive model proposed by Schapery (Further development of a thermodynamic constitutive theory: stress formulation, 1969,Mech. Time-Depend. Mater. 1:209-240, 1997) is used and modified to incorporate temperature- and stress-dependent material properties. This study also formulates a non-linear energy equation along with a dissipation function based on the Gibbs potential of Schapery (Mech. Time-Depend. Mater. 1:209-240, 1997). A numerical algorithm is formulated for analyzing a fully coupled thermo-visco-elastic response and implemented it in a general finite-element (FE) code. The non-linear stress- and temperature-dependent material parameters are found to have significant effects on the coupled thermo-visco-elastic response of polymers considered in this study. In order to obtain a realistic temperature field within the polymer visco-elastic bodies undergoing a non-uniform heat generation, the role of heat conduction cannot be ignored. © Springer Science+Business Media, B. V. 2012.

  14. Enhanced performance of solid oxide electrolysis cells by integration with a partial oxidation reactor: Energy and exergy analyses

    International Nuclear Information System (INIS)

    Visitdumrongkul, Nuttawut; Tippawan, Phanicha; Authayanun, Suthida; Assabumrungrat, Suttichai; Arpornwichanop, Amornchai

    2016-01-01

    Highlights: • Process design of solid oxide electrolyzer integrated with a partial oxidation reactor is studied. • Effect of key operating parameters of partial oxidation reactor on the electrolyzer performance is presented. • Exergy analysis of the electrolyzer process is performed. • Partial oxidation reactor can enhance the solid oxide electrolyzer performance. • Partial oxidation reactor in the process is the highest exergy destruction unit. - Abstract: Hydrogen production without carbon dioxide emission has received a large amount of attention recently. A solid oxide electrolysis cell (SOEC) can produce pure hydrogen and oxygen via a steam electrolysis reaction that does not emit greenhouse gases. Due to the high operating temperature of SOEC, an external heat source is required for operation, which also helps to improve SOEC performance and reduce operating electricity. The non-catalytic partial oxidation reaction (POX), which is a highly exothermic reaction, can be used as an external heat source and can be integrated with SOEC. Therefore, the aim of this work is to study the effect of operating parameters of non-catalytic POX (i.e., the oxygen to carbon ratio, operating temperature and pressure) on SOEC performance, including exergy analysis of the process. The study indicates that non-catalytic partial oxidation can enhance the hydrogen production rate and efficiency of the system. In terms of exergy analysis, the non-catalytic partial oxidation reactor is demonstrated to be the highest exergy destruction unit due to irreversible chemical reactions taking place, whereas SOEC is a low exergy destruction unit. This result indicates that the partial oxidation reactor should be improved and optimally designed to obtain a high energy and exergy system efficiency.

  15. Molecular Dynamics Analyses on Microscopic Contact Angle - Effect of Wall Atom Configuration

    International Nuclear Information System (INIS)

    Takahiro Ito; Yosuke Hirata; Yutaka Kukita

    2006-01-01

    Boiling or condensing phenomena of liquid on the solid surface is greatly affected by the wetting condition of the liquid to the solid. Although the contact angle is one of the most important parameter to represent the wetting condition, the behavior of the contact angle is not understood well, especially in the dynamic condition. In this study we made molecular dynamics simulations to investigate the microscopic contact angle behavior under several conditions on the numerical density of the wall atoms. In the analyses, when the number density of the wall is lower, the changing rate of the dynamics contact angles for the variation of ΔV was higher than those for the case where the wall density is higher. This is mainly due to the crystallization of the fluid near the wall and subsequent decrease in the slip between the fluid and the wall. The analyses also show that the static contact angle decreases with increase in the number density of the wall. This was mainly induced by the increase in the number density of the wall itself. (authors)

  16. Strategic review on management and disposal of low- and intermediate-level solid radwastes

    International Nuclear Information System (INIS)

    Li Xuequn

    1993-01-01

    An overview on the actual status of solid low- and intermediate-level wastes (L/ILW) management in China is described. Some of the main problems at present are analysed. The strategies on management and disposal of the wastes are discussed in light of systematology. A large amount of solid L/ILW and distilled residual solution to be solidified have been accumulated during the past 30 years development of nuclear industry in China. These wastes, containing fission products, activated products, and uranium and transuranium elements respectively, mainly come from nuclear reactors, spent fuel reprocessing plants, and nuclear fuel fabrication plants. In the century, solid L/ILW and solidified wastes are produced mainly by nuclear industry; but in the next century, solid wastes will be steadily produced mainly from nuclear power plants

  17. Concept and performance study of turbocharged solid propellant ramjet

    Science.gov (United States)

    Li, Jiang; Liu, Kai; Liu, Yang; Liu, Shichang

    2018-06-01

    This study proposes a turbocharged solid propellant ramjet (TSPR) propulsion system that integrates a turbocharged system consisting of a solid propellant (SP) air turbo rocket (ATR) and the fuel-rich gas generator of a solid propellant ramjet (SPR). First, a suitable propellant scheme was determined for the TSPR. A solid hydrocarbon propellant is used to generate gas for driving the turbine, and a boron-based fuel-rich propellant is used to provide fuel-rich gas to the afterburner. An appropriate TSPR structure was also determined. The TSPR's thermodynamic cycle was analysed to prove its theoretical feasibility. The results showed that the TSPR's specific cycle power was larger than those of SP-ATR and SPR and thermal efficiency was slightly less than that of SP-ATR. Overall, TSPR showed optimal performance in a wide flight envelope. The specific impulses and specific thrusts of TSPR, SP-ATR, and SPR in the flight envelope were calculated and compared. TSPR's flight envelope roughly overlapped that of SP-ATR, its specific impulse was larger than that of SP-ATR, and its specific thrust was larger than those of SP-ATR and SPR. Attempts to improve the TSPR off-design performance prompted our proposal of a control plan for off-design codes in which both the turbocharger corrected speed and combustor excess gas coefficient are kept constant. An off-design performance model was established by analysing the TSPR working process. We concluded that TSPR with a constant corrected speed had wider flight envelope, higher thrust, and higher specific impulse than TSPR with a constant physical speed determined by calculating the performance of off-design TSPR codes under different control plans. The results of this study can provide a reference for further studies on TSPRs.

  18. Comparison based on energy and exergy analyses of the potential cogeneration efficiencies for fuel cells and other electricity generation devices

    Energy Technology Data Exchange (ETDEWEB)

    Rosen, M A [Ryerson Polytechnical Inst., Toronto, (CA). Dept. of Mechanical Engineering

    1990-01-01

    Comparisons of the potential cogeneration efficiencies are made, based on energy and exergy analyses, for several devices for electricity generation. The investigation considers several types of fuel cell system (Phosphoric Acid, Alkaline, Solid Polymer Electrolyte, Molten Carbonate and Solid Oxide), and several fossil-fuel and nuclear cogeneration systems based on steam power plants. In the analysis, each system is modelled as a device for which fuel and air enter, and electrical- and thermal-energy products and material and thermal-energy wastes exit. The results for all systems considered indicate that exergy analyses should be used when analysing the cogeneration potential of systems for electricity generation, because they weigh the usefulnesses of heat and electricity on equivalent bases. Energy analyses tend to present overly optimistic views of performance. These findings are particularly significant when large fractions of the heat output from a system are utilized for cogeneration. (author).

  19. Sorption analyses in materials science: selected oxides

    International Nuclear Information System (INIS)

    Fuller, E.L. Jr.; Condon, J.B.; Eager, M.H.; Jones, L.L.

    1981-01-01

    Physical adsorption studies have been shown to be extremely valuable in studying the chemistry and structure of dispersed materials. Many processes rely on the access to the large amount of surface made available by the high degree of dispersion. Conversely, there are many applications where consolidation of the dispersed solids is required. Several systems (silica gel, alumina catalysts, mineralogic alumino-silicates, and yttrium oxide plasters) have been studied to show the type and amount of chemical and structural information that can be obtained. Some review of current theories is given and additional concepts are developed based on statistical and thermodynamic arguments. The results are applied to sorption data to show that detailed sorption analyses are extremely useful and can provide valuable information that is difficult to obtain by any other means. Considerable emphasis has been placed on data analyses and interpretation of a nonclassical nature to show the potential of such studies that is often not recognized nor utilized

  20. One-dimensional Seismic Analysis of a Solid-Waste Landfill

    International Nuclear Information System (INIS)

    Castelli, Francesco; Lentini, Valentina; Maugeri, Michele

    2008-01-01

    Analysis of the seismic performance of solid waste landfill follows generally the same procedures for the design of embankment dams, even if the methods and safety requirements should be different. The characterization of waste properties for seismic design is difficult due the heterogeneity of the material, requiring the procurement of large samples. The dynamic characteristics of solid waste materials play an important role on the seismic response of landfill, and it also is important to assess the dynamic shear strengths of liner materials due the effect of inertial forces in the refuse mass. In the paper the numerical results of a dynamic analysis are reported and analysed to determine the reliability of the common practice of using 1D analysis to evaluate the seismic response of a municipal solid-waste landfill. Numerical results indicate that the seismic response of a landfill can vary significantly due to reasonable variations of waste properties, fill heights, site conditions, and design rock motions

  1. Combustion Characteristics of Chlorine-Free Solid Fuel Produced from Municipal Solid Waste by Hydrothermal Processing

    Directory of Open Access Journals (Sweden)

    Kunio Yoshikawa

    2012-11-01

    Full Text Available An experimental study on converting municipal solid waste (MSW into chlorine-free solid fuel using a combination of hydrothermal processing and water-washing has been performed. After the product was extracted from the reactor, water-washing experiments were then conducted to obtain chlorine-free products with less than 3000 ppm total chlorine content. A series of combustion experiments were then performed for the products before and after the washing process to determine the chlorine content in the exhaust gas and those left in the ash after the combustion process at a certain temperature. A series of thermogravimetric analyses were also conducted to compare the combustion characteristics of the products before and after the washing process. Due to the loss of ash and some volatile matter after washing process, there were increases in the fixed carbon content and the heating value of the product. Considering the possible chlorine emission, the washing process after the hydrothermal treatment should be necessary only if the furnace temperature is more than 800 °C.

  2. Nanocrystalline solids

    International Nuclear Information System (INIS)

    Gleiter, H.

    1991-01-01

    Nanocrystalline solids are polycrystals, the crystal size of which is a few (typically 1 to 10) nanometres so that 50% or more of the solid consists of incoherent interfaces between crystals of different orientations. Solids consisting primarily of internal interfaces represent a separate class of atomic structures because the atomic arrangement formed in the core of an interface is known to be an arrangement of minimum energy in the potential field of the two adjacent crystal lattices with different crystallographic orientations on either side of the boundary core. These boundary conditions result in atomic structures in the interfacial cores which cannot be formed elsewhere (e.g. in glasses or perfect crystals). Nanocrystalline solids are of interest for the following four reasons: (1) Nanocrystalline solids exhibit an atomic structure which differs from that of the two known solid states: the crystalline (with long-range order) and the glassy (with short-range order). (2) The properties of nanocrystalline solids differ (in some cases by several orders of magnitude) from those of glasses and/or crystals with the same chemical composition, which suggests that they may be utilized technologically in the future. (3) Nanocrystalline solids seem to permit the alloying of conventionally immiscible components. (4) If small (1 to 10 nm diameter) solid droplets with a glassy structure are consolidated (instead of small crystals), a new type of glass, called nanoglass, is obtained. Such glasses seem to differ structurally from conventional glasses. (orig.)

  3. Chemical composition shape form and size of suspended solids in the atmosphere carried by rain water

    International Nuclear Information System (INIS)

    Iturbe G, J.L.; Lopez M, B.E.; Torre O, J. De la

    2001-01-01

    The interest of this work is to know about shape form, size and chemical composition of the suspended solids in the atmosphere of Toluca city and which are carried by the rains. The harvest of the samples was carried out during january to november 1999. The separation of the particulate matter from the rain water was realized through centrifugation. The solids were analysed by Scanning Electron Microscopy to know the shape form and size and the chemical composition was determined by X-ray dispersive energy in general form and of some particles individually analysed. The p H was measured to the solutions and the quantification of some dissolved ions by the Icp technique was realized. The results of the solids showed C, O, Na, Mg, Al, Si, S, P, K, Ca, Ti and Fe. Moreover they present sizes which varying from a ten of nanometers until some tens of microns. (Author)

  4. Procedures for field chemical analyses of water samples

    International Nuclear Information System (INIS)

    Korte, N.; Ealey, D.

    1983-12-01

    A successful water-quality monitoring program requires a clear understanding of appropriate measurement procedures in order to obtain reliable field data. It is imperative that the responsible personnel have a thorough knowledge of the limitations of the techniques being used. Unfortunately, there is a belief that field analyses are simple and straightforward. Yet, significant controversy as well as misuse of common measurement techniques abounds. This document describes procedures for field measurements of pH, carbonate and bicarbonate, specific conductance, dissolved oxygen, nitrate, Eh, and uranium. Each procedure section includes an extensive discussion regarding the limitations of the method as well as brief discussions of calibration procedures and available equipment. A key feature of these procedures is the consideration given to the ultimate use of the data. For example, if the data are to be used for geochemical modeling, more precautions are needed. In contrast, routine monitoring conducted merely to recognize gross changes can be accomplished with less effort. Finally, quality assurance documentation for each measurement is addressed in detail. Particular attention is given to recording sufficient information such that decisions concerning the quality of the data can be easily made. Application of the procedures and recommendations presented in this document should result in a uniform and credible water-quality monitoring program. 22 references, 4 figures, 3 tables

  5. Solid-soluted content of cerium in solid solution of sphene

    International Nuclear Information System (INIS)

    Zhao Wei; Teng Yuancheng; Li Yuxiang; Ren Xuetan; Huang Junjun

    2010-01-01

    The sphene solid solution was synthesized by solid-state method,with calcium carbonate, silica, titanium dioxide, cerium oxalate and alumina as raw materials. The solid-soluted content of cerium in sphene was researched by means of X-ray diffraction (XRD), backscattering scanning electron microscopy (BSE), energy dispersive spectroscopy (EDS) and so on. The influence of A l3+ ion introduction to sphene on the solid-soluted content of cerium in sphene solid solution was studied. The results indicate that when introducing Al 3+ to sphene as electrovalence compensation, Ce 4+ could be well solidified to Ca 1-x Ce x Ti 1-2x A l2x SiO 5 , and the solid-soluted content is approximately 12.61%. With no electrovalence compensation, Ce 4+ could be solidified to Ca 1-2x Ce x TiSiO 5 , and the solid-soluted content is approximately 10.98%. The appropriate synthesis temperature of sphene solid solution is 1 260 degree C.(authors)

  6. Characterisation of vibration equipment used for the immobilisation of solid items in cement grout

    International Nuclear Information System (INIS)

    Dalton, M.J.

    1984-12-01

    Processes are being developed at AEE Winfrith for the immobilisation of solid radioactive waste in cement grouts. The flow of grout during the infilling stage is assisted by vibration of the waste container. A high resolution signal analyser has been used to measure the operating frequency and amplitude characteristics of vibrating equipment used in the solid immobilisation process. In this report the commissioning of the instrument and results obtained on the equipment are described. (author)

  7. Classification of sources of municipal solid wastes in developing countries

    Energy Technology Data Exchange (ETDEWEB)

    Buenrostro, O. [Instituto de Investigaciones sobre los Recursos Naturales, Universidad Michoacana de San Nicolas de Hidalgo, Apartado Postal 2-105, 58400, Michoacan, Morelia (Mexico); Bocco, G. [Departamento de Ecologia de los Recursos Naturales, Instituto de Ecologia, Universidad Nacional Autonoma de Mexico, Campus Morelia, Apartado Postal 27-3 Xangari, 58089, Michoacan, Morelia (Mexico); Cram, S. [Departamento de Geografia Fisica, Instituto de Geografia, Universidad Nacional Autonoma de Mexico, Circuito Exterior, C.P. 04510 Ciudad Universitaria, Mexico City (Mexico)

    2001-05-01

    The existence of different classifications of municipal solid waste (MSW) creates confusion and makes it difficult to interpret and compare the results of generation analyses. In this paper, MSW is conceptualized as the solid waste generated within the territorial limits of a municipality, independently of its source of generation. Grounded on this assumption, and based on the economic activity that generates a solid waste with determinate physical and chemical characteristics, a hierarchical source classification of MSW is suggested. Thus, a connection between the source and the type of waste is established. The classification categorizes the sources into three divisions and seven classes of sources: residential, commercial, institutional, construction/demolition, agricultural-animal husbandry, industrial, and special. When applied at different geographical scales, this classification enables the assessment of the volume of MSW generated, and provides an overview of the types of residues expected to be generated in a municipality, region or state.

  8. Dogs (Canis familiaris, but not chimpanzees (Pan troglodytes, understand imperative pointing.

    Directory of Open Access Journals (Sweden)

    Katharina C Kirchhofer

    Full Text Available Chimpanzees routinely follow the gaze of humans to outside targets. However, in most studies using object choice they fail to use communicative gestures (e.g. pointing to find hidden food. Chimpanzees' failure to do this may be due to several difficulties with this paradigm. They may, for example, misinterpret the gesture as referring to the opaque cup instead of the hidden food. Or perhaps they do not understand informative communicative intentions. In contrast, dogs seem to be skilful in using human communicative cues in the context of finding food, but as of yet there is not much data showing whether they also use pointing in the context of finding non-food objects. Here we directly compare chimpanzees' (N = 20 and dogs' (N = 32 skills in using a communicative gesture directed at a visible object out of reach of the human but within reach of the subject. Pairs of objects were placed in view of and behind the subjects. The task was to retrieve the object the experimenter wanted. To indicate which one she desired, the experimenter pointed imperatively to it and directly rewarded the subject for handing over the correct one. While dogs performed well on this task, chimpanzees failed to identify the referent. Implications for great apes' and dogs' understanding of human communicative intentions are discussed.

  9. Leaching from municipal solid waste incineration residues

    Energy Technology Data Exchange (ETDEWEB)

    Hyks, J.

    2008-02-15

    Leaching of pollutants from Municipal Solid Waste Incineration (MSWI) residues has been investigated combining a range of laboratory leaching experiments with geochemical modeling. Special attention was paid to assessing the applicability of laboratory data for subsequent modeling with respect to presumed full-scale conditions; both sample pretreatment and actual influence of leaching conditions on the results of laboratory experiments were considered. It was shown that sample pretreatment may have large impact on leaching test data. In particular, a significant fraction of Pb was shown mobile during the washing of residues with water. In addition, drying of residues (i.e. slow oxidation) prior to leaching experiments increased the leaching of Cr significantly. Significant differences regarding the leaching behavior of individual elements with respect to (non)equilibrium conditions in column percolation experiments were observed in the study. As a result, three groups of elements were identified based on the predominant leaching control and the influence of (non)equilibrium on the results of the laboratory column experiments: I. Predominantly availability-controlled elements (e.g. Na, K, Cl) II. Solubility-controlled elements (e.g. Ca, S, Si, Al, Ba, and Zn) III. Complexation-controlled elements (e.g. Cu and Ni) With respect to the above groups it was suggested that results of laboratory column experiments can, with consideration, be used to estimate full-scale leaching of elements from Group I and II. However, in order to avoid large underestimations in the assessment of leaching from Group III, it is imperative to describe the time-dependent transport of dissolved organic carbon (DOC) in the tested system or to minimize the physical non-equilibrium during laboratory experiments (e.g. bigger column, slower flow velocity). Forward geochemical modeling was applied to simulate long-term release of elements from a MSWI air-pollution-control residue. Leaching of a

  10. When the "twilight of justice" meets the "dawn of nanotechnology": A critique of transhumanism and the technological imperative in the light of George Grant's moral philosophy

    Science.gov (United States)

    Rosales, Janna Metcalfe

    This dissertation examines how contemporary Western ethical perspectives frame moral judgements about technologies intended to expand or enhance human abilities. Of particular interest are technological advances that involve nanotechnology, a realm of technoscience that seeks the precise control of matter through deliberately designing structures, devices, and processes with novel and useful properties at the molecular scale. In this thesis I analyze trends in the emerging dialogue about the social and ethical implications of nanotechnology. There is growing awareness that technological "progress" should not outpace critical reflection over the means and ends of those advances, but I argue that there is a tension between the role of ethics and the practice of technoscience. By ethics I mean ongoing public discussion that contemplates what it means to live a "good life" and that maintains limits to human actions. By contrast, the practice of technoscience appears to be guided by the "technological imperative" which holds that we can only know what is good by first figuring out what is possible. Despite concerted interdisciplinary efforts to address the broad range of ethical issues posed by nanotechnology's proposed goals, the prevailing tone of the current discussion tends to reveal what I call a "technoprogressive" bias, or the belief that technological development is a primary way to improve the human estate and that it leads inevitably to cumulative progress. However, because technoprogressive commentary on nanotechnology focuses on concerns that are framed mainly in terms of risk assessment, cost-benefit analyses, and utilitarian principles, technoprogressive ethics overlooks crucial ethical questions of a different nature, questions that deal with the limits of human action, the nature of justice, and the meaning of being human. To analyze the implications of technoprogressive ethics, I employ the moral philosophy of Canadian thinker George Grant because he

  11. Solid Matter

    CERN Document Server

    Angelo, Joseph A

    2011-01-01

    Supported by a generous quantity of full-color illustrations and interesting sidebars, Solid Matter introduces the basic characteristics and properties of solid matter. It briefly describes the cosmic connection of the elements, leading readers through several key events in human pre-history that resulted in more advanced uses of matter in the solid state. Chapters include:. -Solid Matter: An Initial Perspective. -Physical Behavior of Matter. -The Gravity of Matter. -Fundamentals of Materials Science. -Rocks and Minerals. -Metals. -Building Materials. -Carbon Earth's Most Versatile Element. -S

  12. Preparation and impedance characterization of all-solid-state thin film battery systems

    OpenAIRE

    Schichtel, Patrick

    2018-01-01

    In this thesis the behavior and properties of solid-state batteries based on multiple electrodes are analysed. For this purpose thin film systems of the relevant materials are prepared to achieve model system for more detailed analysis of the material specific properties. The characterisation of the systems is carried out with typical physical and electrochemical methods and especially using impedance spectroscopy. The first material analysed in this thesis is Li4Ti5O12 which was recognize...

  13. Solid Lithium Ion Conductors (SLIC) for Lithium Solid State Batteries

    Data.gov (United States)

    National Aeronautics and Space Administration — To identify the most lithium-ion conducting solid electrolytes for lithium solid state batteries from the emerging types of solid electrolytes, based on a...

  14. Solid state physics

    CERN Document Server

    Burns, Gerald

    2013-01-01

    Solid State Physics, International Edition covers the fundamentals and the advanced concepts of solid state physics. The book is comprised of 18 chapters that tackle a specific aspect of solid state physics. Chapters 1 to 3 discuss the symmetry aspects of crystalline solids, while Chapter 4 covers the application of X-rays in solid state science. Chapter 5 deals with the anisotropic character of crystals. Chapters 6 to 8 talk about the five common types of bonding in solids, while Chapters 9 and 10 cover the free electron theory and band theory. Chapters 11 and 12 discuss the effects of moveme

  15. Urban solid waste generation and disposal in Mexico: a case study.

    Science.gov (United States)

    Buenrostro, O; Bocco, G; Bernache, G

    2001-04-01

    The adequate management of municipal solid waste in developing countries is difficult because of the scarcity of studies about their composition. This paper analyses the composition of urban solid waste (USW) in the city of Morelia, Michoacán, Mexico. Residential and non-residential waste sources were sampled, and a structured interview was made to evaluate the socioeconomic characteristics of the studied area. Also, to determine the seasonal patterns of solid waste generation and the efficiency level of the collection service, quantification of solid waste deposited in the dumping ground was measured. Our results show that the recorded amount of SW deposited in the municipal dumping-ground is less than the estimated amount of SW generated; for this reason, the former amount is not recommended as an unbiased indicator for planning public waste collection services. It is essential that dumping-grounds are permanently monitored and that the incoming waste be weighed in order to have a more efficient record of USW deposited in the dumping-ground per day; these data are fundamental for developing adequate managing strategies.

  16. Solid waste management

    OpenAIRE

    Srebrenkoska, Vineta; Golomeova, Saska; Zhezhova, Silvana

    2013-01-01

    Waste is unwanted or useless materials from households, industry, agriculture, hospitals. Waste materials in solid state are classified as solid waste. Increasing of the amount of solid waste and the pressure what it has on the environment, impose the need to introduce sustainable solid waste management. Advanced sustainable solid waste management involves several activities at a higher level of final disposal of the waste management hierarchy. Minimal use of material and energy resources ...

  17. Solid phase radioimmunoassays

    International Nuclear Information System (INIS)

    Wide, L.

    1977-01-01

    Solid phase coupled antibodies were introduced to facilitate the separation of bound and free labelled ligand in the competitive inhibition radioimmunoassay. Originally, the solid matrix used was in the form of small particles and since then a number of different matrices have been used such as very fine powder particles, gels, paper and plastic discs, magnetic particles and the inside surface of plastic tubes. The coupling of antibodies may be that of a covalent chemical binding, a strong physical adsorbtion, or an immunological binding to a solid phase coupled antigen. New principles of radioimmunoassay such as the solid phase sandwich techniques and the immunoradiometric assay were developped from the use of solid phase coupled antigens and antibodies. The solid phase sandwich techniques are reagent excess methods with a very wide applicability. Several of the different variants of solid phase techniques are suitable for automation. Advantages and disadvantages of solid phase radioimmunoassays when compared with those using soluble reagents are discussed. (orig.) [de

  18. Multielemental analyses of tree rings by inductively coupled plasma mass spectrometry

    International Nuclear Information System (INIS)

    Hall, G.S.

    1990-01-01

    Inductively coupled plasma mass spectrometry (ICP-MS) was evaluated for major, minor, trace, and ultra-trace elemental analyses of individual tree rings. The samples were obtained from an old-growth Douglas fir growing near Mount St. Helens volcano, and from trees at various other North American sites. Eightly percent of elements from Li to U had detection limits in the solid (wood) below 8.0 ng g -1 . Two anomalous peaks occur in Mount St. Helens samples at A.D. 1478 and 1490 that closely correlate with past eruptions of the volcano. These results show that ICP-MS is a rapid and sensitive analytical method for multielemental analyses of individual tree rings. (author) 16 refs.; 2 figs.; 2 tabs

  19. Solid - solid and solid - liquid phase transitions of iron and iron alloys under laser shock compression

    Science.gov (United States)

    Harmand, M.; Krygier, A.; Appel, K.; Galtier, E.; Hartley, N.; Konopkova, Z.; Lee, H. J.; McBride, E. E.; Miyanishi, K.; Nagler, B.; Nemausat, R.; Vinci, T.; Zhu, D.; Ozaki, N.; Fiquet, G.

    2017-12-01

    An accurate knowledge of the properties of iron and iron alloys at high pressures and temperatures is crucial for understanding and modelling planetary interiors. While Earth-size and Super-Earth Exoplanets are being discovered in increasingly large numbers, access to detailed information on liquid properties, melting curves and even solid phases of iron and iron at the pressures and temperatures of their interiors is still strongly limited. In this context, XFEL sources coupled with high-energy lasers afford unique opportunities to measure microscopic structural properties at far extreme conditions. Also the achievable time resolution allows the shock history and phase transition mechanisms to be followed during laser compression, improving our understanding of the high pressure and high strain experiments. Here we present recent studies devoted to investigate the solid-solid and solid-liquid transition in laser-shocked iron and iron alloys (Fe-Si, Fe-C and Fe-O alloys) using X-ray diffraction and X-ray diffuse scattering. Experiment were performed at the MEC end-station of the LCLS facility at SLAC (USA). Detection of the diffuse scattering allowed the identification of the first liquid peak position along the Hugoniot, up to 4 Mbar. The time resolution shows ultrafast (between several tens and several hundreds of picoseconds) solid-solid and solid-liquid phase transitions. Future developments at XFEL facilities will enable detailed studies of the solid and liquid structures of iron and iron alloys as well as out-of-Hugoniot studies.

  20. International trends in solid-state lighting : analyses of the article and patent literature.

    Energy Technology Data Exchange (ETDEWEB)

    Tsao, Jeffrey Yeenien; Huey, Mark C. (Strategic Perspectives, Incorporated, McLean, VA); Boyack, Kevin W.; Miksovic, Ann E. (Strategic Perspectives, Incorporated, McLean, VA)

    2008-07-01

    We present an analysis of the literature of solid-state lighting, based on a comprehensive dataset of 35,851 English-language articles and 12,420 U.S. patents published or issued during the years 1977-2004 in the foundational knowledge domain of electroluminescent materials and phenomena. The dataset was created using a complex, iteratively developed search string. The records in the dataset were then partitioned according to: whether they are articles or patents, their publication or issue date, their national or continental origin, whether the active electroluminescent material was inorganic or organic, and which of a number of emergent knowledge sub-domains they aggregate into on the basis of bibliographic coupling. From these partitionings, we performed a number of analyses, including: identification of knowledge sub-domains of historical and recent importance, and trends over time of the contributions of various nations and continents to the knowledge domain and its sub-domains. Among the key results: (1) The knowledge domain as a whole has been growing quickly: the average growth rates of the inorganic and organic knowledge sub-domains have been 8%/yr and 25%/yr, respectively, compared to average growth rates less than 5%/yr for English-language articles and U.S. patents in other knowledge domains. The growth rate of the organic knowledge sub-domain is so high that its historical dominance by the inorganic knowledge sub-domain will, at current trajectories, be reversed in the coming decade. (2) Amongst nations, the U.S. is the largest contributor to the overall knowledge domain, but Japan is on a trajectory to become the largest contributor within the coming half-decade. Amongst continents, Asia became the largest contributor during the past half-decade, overwhelmingly so for the organic knowledge sub-domain. (3) The relative contributions to the article and patent datasets differ for the major continents: North America contributing relatively more patents

  1. Just Learning: The Imperative to Transform Juvenile Justice Systems into Effective Educational Systems. A Study of Juvenile Justice Schools in the South and the Nation. Special Summary

    Science.gov (United States)

    Southern Education Foundation, 2014

    2014-01-01

    This brief summarizes the findings of the larger study, "Just Learning: The Imperative to Transform Juvenile Justice Systems into Effective Educational Systems. A Study of Juvenile Justice Schools in the South and the Nation." With awareness growing that schools are disciplining and suspending minority students at alarming rates, the…

  2. Kinetics of solid-phase in ion exchange on tin hydrogen phosphate

    International Nuclear Information System (INIS)

    Kislitsyn, M.N.; Ketsko, V.A.; Yaroslavtsev, A.B.

    2004-01-01

    Solid state reactions in mixture of tin hydrogen phosphate and alkali metal (M=Na, K, Cs) chlorides have been studied both in the mode of polythermal heating and at a fixed temperature, using data of X-ray phase and thermogravimetric analyses. In the range 400-750 Deg C solid state ion exchange reactions occur in the systems studied and yield mono-- and dialkali phosphates MHSn(PO 4 ) 2 and M 2 Sn(PO 4 ) 2 . Counter diffusion coefficients for alkali metal cations and protons in the matrices of compositions MHSn(PO 4 ) 2 and M 2 Sn(PO 4 ) 2 have been determined [ru

  3. SOLID WASTE FOR HEALTH: ENVIRONMENTAL IMPACT HEALTH AND FEEDBACK IN CASE-DISEASE

    Directory of Open Access Journals (Sweden)

    Vanessa Cruz Santos

    2008-05-01

    Full Text Available Considering the reality of the city of Vitoria da Conquista, with regard to the handling and final provisions of solid waste, health, it becomes imperative to raise so reflective, environmental impact Resíduos sólidos de saúde: impacto ambiental... and harm to health caused by them. This aims to describe research on the environmental impacts generated by Solid Wastes of Health (RSS and its implicativos in the health-disease; reflect on the ethical point of view focusing on professional negligence on the part of these, identifying the responsibilities of each involved in context; propose suggestions for improvements to creation of specific areas and handling appropriate to their final destination, to promote a balance of the environment and a healthy life. Through bibliographic methods, descriptive and exploratory with empirical basis, it was emphasized the conduct of that employed the landfill council, whose information based on photographic images of the site, showing thus the breach of the rules of the National Environmental Council ( CONAMA, the resolution 5 / 93 establishing standards of environmental quality in ralação to RSS1. Among other bodies engaged in monitoring the performance of health standards, is also SURVEILLANCE OF DIRECTORS AND CONTROL HEALTH, ENVIRONMENT (DIVISAM 2. The situation, if not circumvented quickly, tends to increase the rates of infections caused by such waste and degradation of the environment due to the exorbitant amount of them, that the landfill receives daily from various establishments of health. To this apparatus pejorativo, perceives itself as a city seen as a model in health, and this concept is linked directly with the environment, once you see an unconnected with reality and nature, and this source and stage of human life and well divides his words as a form of protest or a coincidence "Natu Reza".

  4. Solid waste for health: environmental impact health and feedback in case-disease

    Directory of Open Access Journals (Sweden)

    Karla Ferraz dos Anjos

    2008-01-01

    Full Text Available Considering the reality of the city of Vitoria da Conquista, with regard to the handling and final provisions of solid waste, health, it becomes imperative to raise so reflective, environmental impact and harm to health caused by them. This aims to describe research on the environmental impacts generated by Solid Wastes of Health (RSS and its implicativos in the health-disease; reflect on the ethical point of view focusing on professional negligence on the part of these, identifying the responsibilities of each involved in context; propose suggestions for improvements to creation of specific areas and handling appropriate to their final destination, to promote a balance of the environment and a healthy life. Through bibliographic methods, descriptive and exploratory with empirical basis, it was emphasized the conduct of that employed the landfill council, whose information based on photographic images of the site, showing thus the breach of the rules of the National Environmental Council ( CONAMA, the resolution 5 / 93 establishing standards of environmental quality in ralação to RSS1. Among other bodies engaged in monitoring the performance of health standards, is also SURVEILLANCE OF DIRECTORS AND CONTROL HEALTH, ENVIRONMENT (DIVISAM 2. The situation, if not circumvented quickly, tends to increase the rates of infections caused by such waste and degradation of the environment due to the exorbitant amount of them, that the landfill receives daily from various establishments of health. To this apparatus pejorativo, perceives itself as a city seen as a model in health, and this concept is linked directly with the environment, once you see an unconnected with reality and nature, and this source and stage of human life and well divides his words as a form of protest or a coincidence "Natu Reza"

  5. Tritium dynamics in fusion reactor solid breeder

    International Nuclear Information System (INIS)

    Violante, V.

    1986-01-01

    In the field of the NET research progrm, the chemical and diffusive processes involved in solid ceramic breeder materials have been analysed. A mathematical model describing the phenomena has been developed to obtain a quantitative evaluation for a first design approach. The data obtained by means of the above mentioned model are in good agreement with the data obtained by other research groups working in Europe and in United States. The computer codes BLANKET2, MC2, FWBC, have been developed to simulate the phenomena

  6. Self-care as a professional imperative: physician burnout, depression, and suicide.

    Science.gov (United States)

    Kuhn, Catherine M; Flanagan, Ellen M

    2017-02-01

    Burnout has been identified in approximately half of all practicing physicians, including anesthesiologists. In this narrative review, the relationship between burnout, depression, and suicide is explored, with particular attention to the anesthesiologist. Throughout this review, we highlight our professional imperative regarding this epidemic. The authors searched the existing English language literature via PubMed from 1986 until present using the search terms physician burnout, depression, and suicide, with particular attention to studies regarding anesthesiologists and strategies to address these problems. Burnout and depression have increased among physicians, while the rate of suicide has remained relatively the same. There are many factors associated with burnout and depression as well as many causes. Certain individual factors include sex, amount of social support, and mental health history. Systems factors that play a role in burnout and depression include work compression, demands of electronic health records, production pressure, and lack of control over one's professional life. Medical license applications include questions that reinforce the stigma of psychological stresses and discourage physicians from seeking appropriate care. The concept of physician well-being is multidimensional and includes factors related to each physician as an individual as well as to the working environment. Anesthesiologists must actively engage in self-care. Anesthesiology practices and healthcare organizations should evaluate the balance between demands they place on physicians and the resources provided to sustain an engaged, productive, and satisfied physician workforce. National efforts must be rallied to support physicians seeking help for physical and psychological health problems.

  7. Experimental validation of solid rocket motor damping models

    Science.gov (United States)

    Riso, Cristina; Fransen, Sebastiaan; Mastroddi, Franco; Coppotelli, Giuliano; Trequattrini, Francesco; De Vivo, Alessio

    2017-12-01

    In design and certification of spacecraft, payload/launcher coupled load analyses are performed to simulate the satellite dynamic environment. To obtain accurate predictions, the system damping properties must be properly taken into account in the finite element model used for coupled load analysis. This is typically done using a structural damping characterization in the frequency domain, which is not applicable in the time domain. Therefore, the structural damping matrix of the system must be converted into an equivalent viscous damping matrix when a transient coupled load analysis is performed. This paper focuses on the validation of equivalent viscous damping methods for dynamically condensed finite element models via correlation with experimental data for a realistic structure representative of a slender launch vehicle with solid rocket motors. A second scope of the paper is to investigate how to conveniently choose a single combination of Young's modulus and structural damping coefficient—complex Young's modulus—to approximate the viscoelastic behavior of a solid propellant material in the frequency band of interest for coupled load analysis. A scaled-down test article inspired to the Z9-ignition Vega launcher configuration is designed, manufactured, and experimentally tested to obtain data for validation of the equivalent viscous damping methods. The Z9-like component of the test article is filled with a viscoelastic material representative of the Z9 solid propellant that is also preliminarily tested to investigate the dependency of the complex Young's modulus on the excitation frequency and provide data for the test article finite element model. Experimental results from seismic and shock tests performed on the test configuration are correlated with numerical results from frequency and time domain analyses carried out on its dynamically condensed finite element model to assess the applicability of different equivalent viscous damping methods to describe

  8. Experimental validation of solid rocket motor damping models

    Science.gov (United States)

    Riso, Cristina; Fransen, Sebastiaan; Mastroddi, Franco; Coppotelli, Giuliano; Trequattrini, Francesco; De Vivo, Alessio

    2018-06-01

    In design and certification of spacecraft, payload/launcher coupled load analyses are performed to simulate the satellite dynamic environment. To obtain accurate predictions, the system damping properties must be properly taken into account in the finite element model used for coupled load analysis. This is typically done using a structural damping characterization in the frequency domain, which is not applicable in the time domain. Therefore, the structural damping matrix of the system must be converted into an equivalent viscous damping matrix when a transient coupled load analysis is performed. This paper focuses on the validation of equivalent viscous damping methods for dynamically condensed finite element models via correlation with experimental data for a realistic structure representative of a slender launch vehicle with solid rocket motors. A second scope of the paper is to investigate how to conveniently choose a single combination of Young's modulus and structural damping coefficient—complex Young's modulus—to approximate the viscoelastic behavior of a solid propellant material in the frequency band of interest for coupled load analysis. A scaled-down test article inspired to the Z9-ignition Vega launcher configuration is designed, manufactured, and experimentally tested to obtain data for validation of the equivalent viscous damping methods. The Z9-like component of the test article is filled with a viscoelastic material representative of the Z9 solid propellant that is also preliminarily tested to investigate the dependency of the complex Young's modulus on the excitation frequency and provide data for the test article finite element model. Experimental results from seismic and shock tests performed on the test configuration are correlated with numerical results from frequency and time domain analyses carried out on its dynamically condensed finite element model to assess the applicability of different equivalent viscous damping methods to describe

  9. A radiochemical analyses of metastudtite and leachates from spent fuel

    International Nuclear Information System (INIS)

    McNamara, Bruce K.; Hanson, Brady D.; Buck, Edgar C.; Soderquist, Chuck Z.

    2004-01-01

    Immersion of commercial spent nuclear fuel (CSNF) in deionized water produced two novel corrosion products after a two-year contact period. Another unexpected result was that suspensions of aggregates were observed to form at the air-water interface for each of five samples. These solids were characterized, by SEM and XRD to be nearly pure metastudtite (UO4-2H2O); while the corrosion present on the surface of the fuel itself was determined to be studtite (UO4-2H2O). The occurrence of the floating phase prompted a radiochemical analysis of these solids. This chemical analysis was a unique opportunity to study the relatively pure corrosion phase for incorporation of radionuclides. The analysis indicated that high concentration of 90Sr, 137Cs, 99Tc, and that lower concentrations 237Np, 238, 239Pu and 243, 244Cm had partitioned with the air-water interface aggregates. The concentrations of 241Am were two orders of magnitude lower than the expected inventory in the suspended solids. The radiochemical analyses of the several leachate samples provide preliminary solubility data for the hydrogen peroxide leaching of CSNF and these data are compared to leaching of the same fuel in J-13 and deionized waters. The extent of fuel dissolution in these media are discussed

  10. Solid Base Catalysis

    CERN Document Server

    Ono, Yoshio

    2011-01-01

    The importance of solid base catalysts has come to be recognized for their environmentally benign qualities, and much significant progress has been made over the past two decades in catalytic materials and solid base-catalyzed reactions. The book is focused on the solid base. Because of the advantages over liquid bases, the use of solid base catalysts in organic synthesis is expanding. Solid bases are easier to dispose than liquid bases, separation and recovery of products, catalysts and solvents are less difficult, and they are non-corrosive. Furthermore, base-catalyzed reactions can be performed without using solvents and even in the gas phase, opening up more possibilities for discovering novel reaction systems. Using numerous examples, the present volume describes the remarkable role solid base catalysis can play, given the ever increasing worldwide importance of "green" chemistry. The reader will obtain an overall view of solid base catalysis and gain insight into the versatility of the reactions to whic...

  11. Solid waste

    International Nuclear Information System (INIS)

    1995-01-01

    The article drawn up within the framework of 'the assessment of the state of the environment in Lebanon' provides an overview of solid waste management, and assesses future wastes volume and waste disposal issues.In particular it addresses the following concerns: - Long term projections of solid waste arisings (i.e. domestic, industrial, such commercial wastes, vehicle types, construction waste, waste oils, hazardous toxic wastes and finally hospital and clinical wastes) are described. - Appropriate disposal routes, and strategies for reducing volumes for final disposal - Balance between municipal and industrial solid waste generation and disposal/treatment and - environmental impacts (aesthetics, human health, natural environment )of existing dumps, and the potential impact of government plans for construction of solid waste facilities). Possible policies for institutional reform within the waste management sector are proposed. Tables provides estimations of generation rates and distribution of wastes in different regions of Lebanon. Laws related to solid waste management are summarized

  12. O "Programa Alfabetização Solidária": terceirização no contexto da reforma do Estado "Programa Alfabetização Solidária" literacy program and State reform in Brazil

    Directory of Open Access Journals (Sweden)

    Gladys Beatriz Barreyro

    2010-12-01

    Full Text Available O presente trabalho busca analisar o Programa Alfabetização Solidária a partir de um modelo de Estado proposto pelo governo do presidente Fernando Henrique Cardoso (1997-2002. Considera-se que a proposta de Reforma do Estado ali desenvolvida, a partir do conceito de publicização, teve sua derivação na área social-assistencial do governo na Comunidade Solidária, um ensaio de terceirização na área das políticas sociais. O Alfabetização Solidária, subprograma deste, foi a versão para a área de educação. De modo que algumas características desse Programa específico devem ser discutidas e contextualizadas à luz de um marco mais amplo, analisando conceitos como terceirização, filantropia, empregabilidade temporária, participação social e direito à educação.This article analyses the "Programa de Afabetização Solidária" Literacy Program as a product of the model of State proposed during the two presidential terms of Fernando Henrique Cardoso (1997-2002, in Brazil. I analysed the proposal of State Reform based on publicization and its counterpart in the social-assistance area of the government: the creation of the Solidarity Community ("Comunidade Solidária". This was a test of outsourcing in the social policy area and the "Programa de Afabetização Solidária"Solidarity in Literacy Program, which arose as a subproject of that one, was a laboratory that developed that State model in the educational area. For this reason, some characteristics of this Program are discussed within that frame and concepts like outsourcing, philanthropy, use of cheap and temporary labor force, participation and right to education are analyzed.

  13. Solid lubricants and surfaces

    CERN Document Server

    Braithwaite, E R

    1964-01-01

    Solid Lubricants and Surfaces deals with the theory and use of solid lubricants, particularly in colloidal form. Portions of this book are devoted to graphite and molybdenum disulfides, which are widely used solid lubricants in colloidal form. An extensive literature on the laboratory examination of hundreds of solids as potential lubricants is also provided in this text. Other topics discussed include the metals and solid lubricants; techniques for examining surfaces; other solid lubricants; metal shaping; and industrial uses of solid-lubricant dispersions. This publication is beneficial to e

  14. A systematic meta-review of evaluations of youth violence prevention programs: Common and divergent findings from 25 years of meta-analyses and systematic reviews☆

    Science.gov (United States)

    Matjasko, Jennifer L.; Vivolo-Kantor, Alana M.; Massetti, Greta M.; Holland, Kristin M.; Holt, Melissa K.; Cruz, Jason Dela

    2018-01-01

    Violence among youth is a pervasive public health problem. In order to make progress in reducing the burden of injury and mortality that result from youth violence, it is imperative to identify evidence-based programs and strategies that have a significant impact on violence. There have been many rigorous evaluations of youth violence prevention programs. However, the literature is large, and it is difficult to draw conclusions about what works across evaluations from different disciplines, contexts, and types of programs. The current study reviews the meta-analyses and systematic reviews published prior to 2009 that synthesize evaluations of youth violence prevention programs. This meta-review reports the findings from 37 meta-analyses and 15 systematic reviews; the included reviews were coded on measures of the social ecology, prevention approach, program type, and study design. A majority of the meta-analyses and systematic reviews were found to demonstrate moderate program effects. Meta-analyses yielded marginally smaller effect sizes compared to systematic reviews, and those that included programs targeting family factors showed marginally larger effects than those that did not. In addition, there are a wide range of individual/family, program, and study moderators of program effect sizes. Implications of these findings and suggestions for future research are discussed. PMID:29503594

  15. Plasmas produced by incident laser in solids

    International Nuclear Information System (INIS)

    Oliveira Campos, D. de; Boeckelmann, H.K.

    1984-01-01

    The experimental arrangement for plasma production by incident laser in solids and a system of diagnostics are presented. The system of diagnostics allows: verify the plasma generation and expansion through the ultrahigh-speed photography; obtain measurements of temperature and density by spectroscopy (using an optical analyser of multichannels) and obtain measurements of kinetic energy of ions through his fly time, using a 'Faraday cup'. A vacuum system with an adsorption pump for pre-vacuum and ionic pump was used to reduce pressure and avoid mechanical vibrations and system contaminations. (M.C.K.) [pt

  16. Solid solution in Al-4.5 wt% Cu produced by mechanical alloying

    International Nuclear Information System (INIS)

    Fogagnolo, J.B.; Amador, D.; Ruiz-Navas, E.M.; Torralba, J.M.

    2006-01-01

    Mechanical alloying has been used to produce oxide dispersion strengthened alloys, intermetallic compounds, aluminium alloys and to obtain nanostructured and amorphous materials, as well as to extend the solid solution limit. In this work, Al and Cu elemental powders were subjected to high-energy milling to produce Al-4.5 wt% Cu powder alloy. The powders obtained were characterized by scanning electron microscopy, X-ray diffraction (XRD) and differential scanning calorimetry (DSC), aiming to explore if the copper is present in solid solution or as small particles after high-energy milling. Related to the formation of a supersaturated solid solution, the results of scanning electron microscopy and X-ray diffraction are non-conclusive: the copper could be dispersed with a very small size, undetectable to both techniques. The Al 2 Cu precipitation at temperatures between 160 and 230 deg. C, verified by DSC and XRD analyses, substantiated that mechanical alloying had produced a supersaturated solid solution of copper in aluminium. The crystallite size as a function of milling time and annealing temperature was also determined by X-ray techniques

  17. Pharmacoeconomics of bisphosphonates for skeletal-related event prevention in metastatic non-breast solid tumours.

    Science.gov (United States)

    Carter, John A; Joshi, Avani D; Kaura, Satyin; Botteman, Marc F

    2012-05-01

    Bisphosphonates reduce the risk of skeletal-related events (SREs; i.e. spinal cord compression, pathological fracture, radiation or surgery to the bone, and hypercalcaemia) in patients with metastatic cancer. A number of analyses have been conducted to assess the cost effectiveness of bisphosphonates in patients with bone metastases secondary to breast cancer, but few in other solid tumours. This is a review of cost-effectiveness analyses in patients with non-breast solid tumours and bone metastases. A literature search was conducted to identify cost-effectiveness analyses reporting the cost per QALY gained of bisphosphonates in patients with metastatic bone disease secondary to non-breast solid tumours. Four analyses met inclusion criteria. These included two in prostate cancer (one of which used a global perspective but expressed results in $US, and the other reported from a multiple country perspective: France, Germany, Portugal and the Netherlands). The remaining analyses were in lung cancer (in the UK, France, Germany, Portugal and the Netherlands), and renal cell carcinoma (in the UK, France and Germany). In each analysis, the cost effectiveness of zoledronic acid versus placebo was analysed. Zoledronic acid was found to be cost effective in all European countries across all three indications but not in the sole global prostate cancer analysis. Across countries and indications, assumptions regarding patient survival, drug cost and baseline utility (i.e. patient utility with metastatic disease but without an SRE) were the most robust drivers of modelled estimates. Assumptions of SRE-related costs were most often the second strongest cost driver. Further review indicated that particular attention should be paid to the inclusion or exclusion of nonsignificant survival benefits, whether health state utilities were elicited from community or patient samples or author assumptions, delineation between symptomatic and asymptomatic SREs, and the methods with which SRE

  18. History of Solid Rockets

    Science.gov (United States)

    Green, Rebecca

    2017-01-01

    Solid rockets are of interest to the space program because they are commonly used as boosters that provide the additional thrust needed for the space launch vehicle to escape the gravitational pull of the Earth. Larger, more advanced solid rockets allow for space launch vehicles with larger payload capacities, enabling mankind to reach new depths of space. This presentation will discuss, in detail, the history of solid rockets. The history begins with the invention and origin of the solid rocket, and then goes into the early uses and design of the solid rocket. The evolution of solid rockets is depicted by a description of how solid rockets changed and improved and how they were used throughout the 16th, 17th, 18th, and 19th centuries. Modern uses of the solid rocket include the Solid Rocket Boosters (SRBs) on the Space Shuttle and the solid rockets used on current space launch vehicles. The functions and design of the SRB and the advancements in solid rocket technology since the use of the SRB are discussed as well. Common failure modes and design difficulties are discussed as well.

  19. Solid wastes management in petroleum refineries; Gerenciamento de residuos solidos em refinarias de petroleo

    Energy Technology Data Exchange (ETDEWEB)

    Araujo, Lizabela Souza de [Universidade Federal, Rio de Janeiro, RJ (Brazil). Escola de Quimica]|[Agencia Nacional de Petroleo, Brasilia, DF (Brazil)]. E-mail: lizabela@eq.ufrj.br; Nicolaiewsky, Elioni [Universidade Federal, Rio de Janeiro, RJ (Brazil). Escola de Quimica. Dept. de Engenharia Quimica]. E-mail: elioni@eq.ufrj.br; Freire, Denize Dias de Carvalho [Universidade Federal, Rio de Janeiro, RJ (Brazil). Escola de Quimica. Dept. de Engenharia Bioquimica]. E-mail: denize@eq.ufrj.br

    2002-07-01

    This work performs a survey on the solid wastes generated from petroleum refining activities. The possible environmental impacts are analysed and procedures for disposal and treatment are suggested. The treatment techniques are detached: minimization, incineration, co-processing, bioremediation and industrial embankments.

  20. 36. INVESTING IN RECOVERY – AN ECONOMIC AS WELL AS MORAL IMPERATIVE

    Science.gov (United States)

    McDaid, David

    2018-01-01

    Abstract Overall Abstract: ‘Recovery’ is a key concept in mental health policy around the globe. The World Health Organization has called for ‘a recovery-based approach that puts the emphasis on supporting individuals with mental disorders and psychosocial disabilities to achieve their own aspirations and goals’. Investing in evidence-based actions to help foster recovery should therefore be core to any system of support for anyone experiencing schizophrenia or other severe mental health problems. While there is clearly a moral imperative to maximise opportunities for recovery, the economic case for action can also be compelling and complementary. However, the opportunity to make an economic argument to support investment in recovery is not always taken, and even when made it is often too narrow in ambition and scope to have a major influence policy and practice. This presentation will highlight examples of the economic potential of recovery-focused services in health, employment, education and housing services. It will look at strengths and weaknesses in the way in which economic evidence is presented to policy makers, including the extent to which implementation challenges have been considered. It will argue that in making the economic case for recovery it is just as vital to look at the role of the messenger as well as the message that is being communicated.

  1. Solid-phase microextraction for bioconcentration studies according to OECD TG 305

    Energy Technology Data Exchange (ETDEWEB)

    Duering, Rolf-Alexander; Boehm, Leonard [Land Use and Nutrition (IFZ) Justus Liebig University Giessen, Institute of Soil Science and Soil Conservation, Research Centre for BioSystems, Giessen (Germany); Schlechtriem, Christian [Fraunhofer Institute for Molecular Biology and Applied Ecology (IME), Schmallenberg (Germany)

    2012-12-15

    An important aim of the European Community Regulation on chemicals and their safe use is the identification of (very) persistent, (very) bioaccumulative, and toxic substances. In other regulatory chemical safety assessments (pharmaceuticals, biocides, pesticides), the identification of such (very) persistent, (very) bioaccumulative, and toxic substances is of increasing importance. Solid-phase microextraction is especially capable of extracting total water concentrations as well as the freely dissolved fraction of analytes in the water phase, which is available for bioconcentration in fish. However, although already well established in environmental analyses to determine and quantify analytes mainly in aqueous matrices, solid-phase microextraction is still a rather unusual method in regulatory ecotoxicological research. Here, the potential benefits and drawbacks of solid-phase microextraction are discussed as an analytical routine approach for aquatic bioconcentration studies according to OECD TG 305, with a special focus on the testing of hydrophobic organic compounds characterized by log K{sub OW}> 5. (orig.)

  2. Design and Characterisation of Solid Electrolytes for All-Solid-State Lithium Batteries

    DEFF Research Database (Denmark)

    Sveinbjörnsson, Dadi Þorsteinn

    The development of all-solid-state lithium batteries, in which the currently used liquid electrolytes are substituted for solid electrolyte materials, could lead to safer batteries offering higher energy densities and longer cycle lifetimes. Designing suitable solid electrolytes with sufficient...... chemical and electrochemical stability, high lithium ion conduction and negligible electronic conduction remains a challenge. The highly lithium ion conducting LiBH4-LiI solid solution is a promising solid electrolyte material. Solid solutions with a LiI content of 6.25%-50% were synthesised by planetary......-rich microstructures during ball milling is found to significantly influence the conductivity of the samples. The long-range diffusion of lithium ions was measured using quasi-elastic neutron scattering. The solid solutions are found to exhibit two-dimensional conduction in the hexagonal plane of the crystal structure...

  3. Lithiated and sulphonated poly(ether ether ketone) solid state electrolyte films for supercapacitors

    Energy Technology Data Exchange (ETDEWEB)

    Chiu, K.-F.; Su, S.-H., E-mail: minimono42@gmail.com

    2013-10-01

    Poly(ether ether ketone) (PEEK) films have been synthesised and used as solid-state electrolytes for supercapacitors. In order to increase their ion conductivity, the PEEK films were sulphonated by sulphuric acid, and various amounts of LiClO{sub 4} were added. The solid-state electrolyte films were characterised by Fourier transform infrared spectroscopy, scanning electron microscopy, energy-dispersive X-ray spectroscopy, and thermogravimetric analysis. The ionic conductivities of the electrolyte films were analysed by performing electrochemical impedance spectroscopy. The obtained electrolyte films can be sandwiched or directly coated on activated carbon electrodes to form solid-state supercapacitors. The electrochemical characteristics of these supercapacitors were investigated by performing cyclic voltammetry and charge–discharge tests. Under an optimal content of LiClO{sub 4}, the supercapacitor can provide a capacitance as high as 190 F/g. After 1000 cycles, the supercapacitors show almost no capacitance fading, indicating high stability of the solid-state electrolyte films. - Highlights: • Poly(ether ether ketone) (PEEK) films have been used as solid-state electrolytes. • LiClO4 addition can efficiently improve the ionic conductivity. • Supercapacitors using PEEK electrolyte films deliver high capacitance.

  4. Lithiated and sulphonated poly(ether ether ketone) solid state electrolyte films for supercapacitors

    International Nuclear Information System (INIS)

    Chiu, K.-F.; Su, S.-H.

    2013-01-01

    Poly(ether ether ketone) (PEEK) films have been synthesised and used as solid-state electrolytes for supercapacitors. In order to increase their ion conductivity, the PEEK films were sulphonated by sulphuric acid, and various amounts of LiClO 4 were added. The solid-state electrolyte films were characterised by Fourier transform infrared spectroscopy, scanning electron microscopy, energy-dispersive X-ray spectroscopy, and thermogravimetric analysis. The ionic conductivities of the electrolyte films were analysed by performing electrochemical impedance spectroscopy. The obtained electrolyte films can be sandwiched or directly coated on activated carbon electrodes to form solid-state supercapacitors. The electrochemical characteristics of these supercapacitors were investigated by performing cyclic voltammetry and charge–discharge tests. Under an optimal content of LiClO 4 , the supercapacitor can provide a capacitance as high as 190 F/g. After 1000 cycles, the supercapacitors show almost no capacitance fading, indicating high stability of the solid-state electrolyte films. - Highlights: • Poly(ether ether ketone) (PEEK) films have been used as solid-state electrolytes. • LiClO4 addition can efficiently improve the ionic conductivity. • Supercapacitors using PEEK electrolyte films deliver high capacitance

  5. EVALUATION OF A BUFFERED SOLID PHASE DISPERSION PROCEDURE ADAPTED FOR PESTICIDE ANALYSES IN THE SOIL MATRIX

    Directory of Open Access Journals (Sweden)

    Ana María Domínguez

    2015-08-01

    Full Text Available An evaluation of the pesticides extracted from the soil matrix was conducted using a citrate-buffered solid phase dispersion sample preparation method (QuEChERS. The identification and quantitation of pesticide compounds was performed using gas chromatography-mass spectrometry. Because of the occurrence of the matrix effect in 87% of the analyzed pesticides, the quantification was performed using matrix-matched calibration. The method's quantification limits were between 0.01 and 0.5 mg kg-1. Repeatability and intermediate precision, expressed as a relative standard deviation percentage, were less than 20%. The recoveries in general ranged between 62% and 99%, with a relative standard deviation < 20%. All the responses were linear, with a correlation coefficient (r ≥0.99.

  6. Design and technology development of solid breeder blanket cooled by supercritical water in Japan

    Science.gov (United States)

    Enoeda, M.; Kosaku, Y.; Hatano, T.; Kuroda, T.; Miki, N.; Honma, T.; Akiba, M.; Konishi, S.; Nakamura, H.; Kawamura, Y.; Sato, S.; Furuya, K.; Asaoka, Y.; Okano, K.

    2003-12-01

    This paper presents results of conceptual design activities and associated R&D of a solid breeder blanket system for demonstration of power generation fusion reactors (DEMO blanket) cooled by supercritical water. The Fusion Council of Japan developed the long-term research and development programme of the blanket in 1999. To make the fusion DEMO reactor more attractive, a higher thermal efficiency of more than 40% was strongly recommended. To meet this requirement, the design of the DEMO fusion reactor was carried out. In conjunction with the reactor design, a new concept of a solid breeder blanket cooled by supercritical water was proposed and design and technology development of a solid breeder blanket cooled by supercritical water was performed. By thermo-mechanical analyses of the first wall, the tresca stress was evaluated to be 428 MPa, which clears the 3Sm value of F82H. By thermal and nuclear analyses of the breeder layers, it was shown that a net TBR of more than 1.05 can be achieved. By thermal analysis of the supercritical water power plant, it was shown that a thermal efficiency of more than 41% is achievable. The design work included design of the coolant flow pattern for blanket modules, module structure design, thermo-mechanical analysis and neutronics analysis of the blanket module, and analyses of the tritium inventory and permeation. Preliminary integration of the design of a solid breeder blanket cooled by supercritical water was achieved in this study. In parallel with the design activities, engineering R&D was conducted covering all necessary issues, such as development of structural materials, tritium breeding materials, and neutron multiplier materials; neutronics experiments and analyses; and development of the blanket module fabrication technology. Upon developing the fabrication technology for the first wall and box structure, a hot isostatic pressing bonded F82H first wall mock-up with embedded rectangular cooling channels was

  7. Interim report on the state-of-the-art of solid-state motor controllers. Part 4. Failure-rate and failure-mode data

    International Nuclear Information System (INIS)

    Jaross, R.A.

    1983-09-01

    An assessment of the reliability of solid-state motor controllers for nuclear power plants is made. Available data on failure-rate and failure-mode data for solid-state motor controllers based on industrial operating experience is meager; the data are augmented by data on other solid-state power electronic devices that are shown to have components similar to those found in solid-state motor controllers. In addition to large nonnuclear solid-state adjustable-speed motor drives, the reliability of nuclear plant inverter systems and high-voltage solid-state dc transmission-line converters is assessed. Licensee Event Report analyses from several sources, the open literature, and personal communications are used to determine the realiability of solid-state devices typical of those expected to be used in nuclear power plants in terms of failures per hour

  8. STUDY OF PAEDIATRIC SOLID TUMOURS FOR A PERIOD OF 5 YEARS

    Directory of Open Access Journals (Sweden)

    Basumitra Das

    2017-12-01

    Full Text Available BACKGROUND Paediatric Solid Neoplasms (PSN are a global problem. There is significant variation of incidence of paediatric solid neoplasms in various regions of the world. Benign tumours are more common than cancer. In an effort to better understand the prevalence of paediatric solid tumours in our region, a retrospective review of the tumours diagnosed histopathologically was carried out. MATERIALS AND METHODS This is a retrospective study undertaken in a tertiary care hospital for a period of five years. All the benign and malignant paediatric solid tumours of children below 14 years from January 2012 to December 2016 were retrieved and analysed according to age, sex and histopathological diagnosis. Leukaemias were excluded from our study. All tumours were diagnosed on conventional haematoxylin and eosin-stained sections. RESULTS A total of 109 cases of solid paediatric tumours were received during this period. Of these, maximum of 30 tumours were of soft tissue tumours followed by Central Nervous System (CNS and bone tumours with 24 and 23 cases, respectively. 7 cases of blastomas were also observed. CONCLUSION This study showed benign and malignant tumours to be of near-equal prevalence. Soft tissue tumours were the most common. Ratio of benign tumours to malignant were almost equal below 4 years. Malignant tumours were higher in 5-9 years group.

  9. Municipal solid waste management in Tehran: Changes during the last 5 years.

    Science.gov (United States)

    Malmir, Tahereh; Tojo, Yasumasa

    2016-05-01

    The situation of waste management in Tehran was a typical example of it in developing countries. The amount of municipal solid waste has been increasing and the city has depended on landfill for municipal solid waste management. However, in recent years, various measures have been taken by the city, such as collecting recyclables at the source and increasing the capacity of waste-processing facilities. As a result, significant changes in the waste stream are starting to occur. This study investigated the nature of, and reasons for, the marked changes in the waste stream from 2008 to 2012 by analysing the municipal solid waste statistics published by the Tehran Waste Management Organization in 2013 and survey data on the physical composition of the municipal solid waste. The following trends were identified: Although the generation of municipal solid waste increased by 10% during the 5-year period, the amount of waste directly disposed of to landfill halved and resource recovery almost doubled. An increase in the capacity of a waste-processing facility contributed significantly to these changes. The biodegradable fraction going to landfill was estimated by using the quantity and the composition of each input to the landfill. The estimated result in 2012 decreased to 49% of its value in 2008. © The Author(s) 2016.

  10. 3D analyses of cavitation instabilities accounting for plastic anisotropy

    DEFF Research Database (Denmark)

    Legarth, Brian Nyvang; Tvergaard, Viggo

    2010-01-01

    Full three dimensional cell model analyses are carried out for a solid containing a single small void, in order to determine the critical stress levels for the occurrence of cavitation instabilities. The material models applied are elastic‐viscoplastic, with a small rate‐hardening exponent...... that the quasi‐static solution is well approximated. A special procedure is used to strongly reduce the loading rate a little before the instability occurs. It is found that plastic anisotropy has a significant effect on the level of the critical stress for cavitation instabilities....

  11. Theoretical solid state physics

    CERN Document Server

    Haug, Albert

    2013-01-01

    Theoretical Solid State Physics, Volume 1 focuses on the study of solid state physics. The volume first takes a look at the basic concepts and structures of solid state physics, including potential energies of solids, concept and classification of solids, and crystal structure. The book then explains single-electron approximation wherein the methods for calculating energy bands; electron in the field of crystal atoms; laws of motion of the electrons in solids; and electron statistics are discussed. The text describes general forms of solutions and relationships, including collective electron i

  12. Isostructural solid-solid transition of (colloidal) simple fluids

    International Nuclear Information System (INIS)

    Tejero, C.F.; Daanoun, A.; Lakkerkerker, H.N.W.; Baus, M.

    1995-01-01

    A variational approach based on the Gibbs-Bogoliubov inequality is used in order to evaluate the free energy of simple fluids described by a double-Yukawa pair potential. A hard-sphere reference fluid is used to describe the fluid phases, and an Einstein reference crystal to describe the solid phases. Apart from the usual type of phase diagram, typical of atomic simple fluids with long-ranged attractions, we find two types of phase diagrams, specific to colloidal systems with intermediate and short-ranged attractions. One of the latter phase diagrams exhibits an isostructural solid-solid transition, which has not yet been observed experimentally

  13. Characterization and morphology of solids suspended in rain water; Caracterizacion y morfologia de solidos suspendidos en agua de lluvia

    Energy Technology Data Exchange (ETDEWEB)

    Iturbe G, J.L.; Lopez M, B.E.; Torre O, J. De la [Instituto Nacional de Investigaciones Nucleares, A.P. 18-1027, Mexico D.F. (Mexico)

    2000-07-01

    This work presents the results obtained from the analysis of rain water in Mexico. The study treats over the characterization and morphology of the solids suspended in form of particles in the atmosphere. The solids suspended were obtained of the pluvial precipitations after these have been centrifuged. Subsequently of the separation, the particulate matter was analysed by Sem and X-ray dispersive energy.

  14. Application of Acoustic and Optic Methods for Estimating Suspended-Solids Concentrations in the St. Lucie River Estuary, Florida

    Science.gov (United States)

    Patino, Eduardo; Byrne, Michael J.

    2004-01-01

    Acoustic and optic methods were applied to estimate suspended-solids concentrations in the St. Lucie River Estuary, southeastern Florida. Acoustic Doppler velocity meters were installed at the North Fork, Speedy Point, and Steele Point sites within the estuary. These sites provide varying flow, salinity, water-quality, and channel cross-sectional characteristics. The monitoring site at Steele Point was not used in the analyses because repeated instrument relocations (due to bridge construction) prevented a sufficient number of samples from being collected at the various locations. Acoustic and optic instruments were installed to collect water velocity, acoustic backscatter strength (ABS), and turbidity data that were used to assess the feasibility of estimating suspended-solids concentrations in the estuary. Other data collected at the monitoring sites include tidal stage, salinity, temperature, and periodic discharge measurements. Regression analyses were used to determine the relations of suspended-solids concentration to ABS and suspended-solids concentration to turbidity at the North Fork and Speedy Point sites. For samples used in regression analyses, measured suspended-solids concentrations at the North Fork and Speedy Point sites ranged from 3 to 37 milligrams per liter, and organic content ranged from 50 to 83 percent. Corresponding salinity for these samples ranged from 0.12 to 22.7 parts per thousand, and corresponding temperature ranged from 19.4 to 31.8 ?C. Relations determined using this technique are site specific and only describe suspended-solids concentrations at locations where data were collected. The suspended-solids concentration to ABS relation resulted in correlation coefficients of 0.78 and 0.63 at the North Fork and Speedy Point sites, respectively. The suspended-solids concentration to turbidity relation resulted in correlation coefficients of 0.73 and 0.89 at the North Fork and Speedy Point sites, respectively. The adequacy of the

  15. Initial clinical experience with dedicated ultra fast solid state cardiac gamma camera

    International Nuclear Information System (INIS)

    Aland, Nusrat; Lele, V.

    2010-01-01

    Full text: To analyze the imaging and diagnostic performance of new dedicated ultra fast solid state detector gamma camera and compare it with standard dual detector gamma camera in myocardial perfusion imaging. Material and Methods: In total 900 patients underwent myocardial perfusion imaging between 1st February 2010 and 29th August 2010 either stress/rest or rest/stress protocol. There was no age or gender bias (there were 630 males and 270 females). 5 and 15 mCi of 99m Tc - Tetrofosmin/MIBI was injected for 1st and 2nd part of the study respectively. Waiting period after injection was 20 min for regular stress and 40 min for pharmacological stress and 40 min after rest injection. Acquisition was performed on solid state detector gamma camera for a duration of 5 min and 3 min for 1st and 2nd part respectively. Interpretation of myocardial perfusion was done and QGS/QPS protocol was used for EF analysis. Out of these, 20 random patients underwent back to back myocardial perfusion SPECT imaging on standard dual detector gamma camera on same day. There was no age or gender bias (there were 9 males, 11 females). Acquisition time was 20 min for each part of the study. Interpretation was done using Autocard and EF analyses with 4 DM SPECT. Images obtained were then compared with those of solid state detector gamma camera. Result: Good quality and high count myocardial perfusion images were obtained with lesser amount of tracer activity on solid state detector gamma camera. Obese patients also showed good quality images with less tracer activity. As compared to conventional dual detector gamma camera images were brighter and showed better contrast with solid state gamma camera. Right ventricular imaging was better seen. Analyses of diastolic dysfunction was possible with 16 frame gated studies with solid state gamma camera. Shorter acquisition time with comfortable position reduced possibility of patient motion. All cardiac views were obtained with no movement of the

  16. Meeting the imperative to improve physician well-being: assessment of an innovative program.

    Science.gov (United States)

    Dunn, Patrick M; Arnetz, Bengt B; Christensen, John F; Homer, Louis

    2007-11-01

    Improving physician health and performance is critical to successfully meet the challenges facing health systems that increasingly emphasize productivity. Assessing long-term efficacy and sustainability of programs aimed at enhancing physician and organizational well-being is imperative. To determine whether data-guided interventions and a systematic improvement process to enhance physician work-life balance and organizational efficacy can improve physician and organizational well-being. From 2000 to 2005, 22-32 physicians regularly completed 3 questionnaires coded for privacy. Results were anonymously reported to physicians and the organization. Data-guided interventions to enhance physician and organizational well-being were built on physician control over the work environment, order in the clinical setting, and clinical meaning. Questionnaires included an ACP/ASIM survey on physician satisfaction, the Maslach Burnout Inventory (MBI), and the Quality Work Competence (QWC) survey. Emotional and work-related exhaustion decreased significantly over the study period (MBI, p = 0.002; QWC, p = 0.035). QWC measures of organizational health significantly improved initially and remained acceptable and stable during the rest of the study. A data-guided program on physician well-being, using validated instruments and process improvement methods, enhanced physician and organizational well-being. Given the increases in physician burnout, organizations are encouraged to urgently create individual and systems approaches to lessen burnout risk.

  17. Innovative Pathways for Effective E-Governance in Africa: The Imperative of Authentic Leadership

    Directory of Open Access Journals (Sweden)

    Godwyns Agbude

    2015-12-01

    Full Text Available The evolving concept of e-governance has become one of the leading praxis of the 21st Century. This again reinforces, not just the importance of governance in human societies, but the need to redefine, reappraise, reinvent and redirect the path of governance towards effective and efficient service delivery. The paradigm of Science and Technology therefore presents the leading edge in our contemporary world thereby validating the viability of Information and Communication Technology (ICT in governance at diverse levels of operations. This paper, employs secondary data and presents the position that in the light of the fact that e-governance covers areas such as government, citizens and businesses/interest groups, the central place of leadership that will authenticate trust and confidence in the effective delivery of the e-governance protocols therefore becomes an imperative. In the gamut of literature on leadership, this paper identifies authentic leadership as a necessary condition that will facilitate effectiveness and efficiency of e-governance. This paper concludes that since there is a human dimension to the process of e-governance, creating innovative pathways for its effectiveness in Africa calls for authentic leadership which emphasizes constructive and developmental interactions between leaders and followers.

  18. Solid electroytes for CNT-based actuators

    Science.gov (United States)

    Riemenschneider, Johannes; Geier, Sebastian; Mahrholz, Thorsten; Mosch, Jürgen; Monner, Hans Peter; Sinapius, Michael

    2009-03-01

    Actuators based on carbon nanotubes (CNT) have the potential to generate high forces at very low voltages. The density of the raw material is just 1330 kg/m3, which makes them well applicable for lightweight applications. Moreover, active strains of up to 1% can be achieved - due to the CNTs dimensional changes on charge injection. Therefore the nanotubes have to be arranged and electrically wired like electrodes of a capacitor. In previous works the system's response of the Nanotubes comprising a liquid electrolyte was studied in detail. The major challenge is to repeat such experiments with solid electrolytes, which is a prerequisite for structural integration. In this paper a method is proposed which makes sure the expansion is not based on thermal expansion. This is done by analysing the electrical system response. As thermal expansion is dominated by ohmic resistance the CNT based actuators show a strong capacitive behavior. This behavior is referable to the constitution of the electrochemical double layer around the nanotubes, which causes the tubes to expand. Also a novel test setup is described, which guarantees that the displacement which is measured will not be caused by bending of a bimorph but due to expansion of a single layer of nanotubes. This paper also presents experimental results demonstrating both, the method of electrical characterization of CNT based actuators with implemented solid electrolytes and the novel test setup which is used to measure the needed data. The actuators which were characterized are hybrids of CNT and the solid electrolyte NAFION which is supplying the ions needed to constitute the electrochemical double layer. The manufacturing, processing of these actuators and also some first experimental results are shown. Unfortunately, the results are not as clear as those for liquid electrolytes, which depend on the hybrid character of the analyzed devices. In the liquid electrolyte based case the CNTs are the only source of

  19. Solid State Division

    International Nuclear Information System (INIS)

    Green, P.H.; Watson, D.M.

    1989-08-01

    This report contains brief discussions on work done in the Solid State Division of Oak Ridge National Laboratory. The topics covered are: Theoretical Solid State Physics; Neutron scattering; Physical properties of materials; The synthesis and characterization of materials; Ion beam and laser processing; and Structure of solids and surfaces

  20. Hanford solid waste management system simulation

    International Nuclear Information System (INIS)

    Shaver, S.R.; Armacost, L.L.; Konynenbelt, H.S.; Wehrman, R.R.

    1994-12-01

    This paper describes systems analysis and simulation model development for a proposed solid waste management system at a U.S. Department of Energy Site. The proposed system will include a central storage facility, four treatment facilities, and three disposal sites. The material managed by this system will include radioactive, hazardous, and mixed radioactive and hazardous wastes. The objective of the modeling effort is to provide a means of evaluating throughput and capacity requirements for the proposed treatment, storage, and disposal facilities. The model is used to evaluate alternative system configurations and the effect on the alternatives of changing waste stream characteristics and receipt schedules. An iterative modeling and analysis approach is used that provides macro-level models early in the project and establishes credibility with the customer. The results from the analyses based on the macro models influence system design decisions and provide information that helps focus subsequent model development. Modeling and simulation of alternative system configurations and operating strategies yield a better understanding of the solid waste system requirements. The model effectively integrates information obtained through systems analysis and waste characterization to provide a consistent basis for system and facility planning

  1. A mass spectrographic investigation of the methods for obtaining quantitative analyses for the mass balance of P and B through a submerged arc silicon smelter

    International Nuclear Information System (INIS)

    Rogers, D.E.C.; Jones, D.S.; Wegman, J.W.; Brain, L.; Van Wamelen, J.

    1983-11-01

    Mass spectrographic analyses of silica, silicon and silica reducing agents have been made using an arc discharge mass spectrograph. Analyses of certified standards and standard mixtures are given. An evaluation of doping techniques shows that the solid doping technique is satisfactory and that the liquid doping technique leads to significant errors. The amount of liquid dopant absorbed onto the substrate matrix varied from one compound to another and from one matrix to another. Comparison of analyses of solid-doped and undoped certified standards shows that all of the solid dopant is taken up by the sample. Analysis of silica reducing agents used in the arc reduction furnace shows that the major source of contamination by B and P is likely to be the coal and wood. Silica contains 0.4 ppm of B and 4 ppm of P and is a minor source of contamination. The levels in silicon are about 10 ppm for B and 20 ppm for P. A mass balance on P cannot be made and the missing amount is larger than the inaccuracy of the analysis. For analyses of feedstocks where the smelter outlet fumes are not sampled an accuracy of analysis to a factor of two is sufficient for the analysis of the coal and wood chips

  2. Developing a common framework for integrated solid waste management advances in Managua, Nicaragua.

    Science.gov (United States)

    Olley, Jane E; IJgosse, Jeroen; Rudin, Victoria; Alabaster, Graham

    2014-09-01

    This article describes the municipal solid waste management system in Managua, Nicaragua. It updates an initial profile developed by the authors for the 2010 UN-HABITAT publication Solid Waste Management in the World's Cities and applies the methodology developed in that publication. In recent years, the municipality of Managua has been the beneficiary of a range of international cooperation projects aimed at improving municipal solid waste management in the city. The article describes how these technical assistance and infrastructure investments have changed the municipal solid waste management panorama in the city and analyses the sustainability of these changes. The article concludes that by working closely with the municipal government, the UN-HABITAT project Strengthening Capacities for Solid Waste Management in Managua was able to unite these separate efforts and situate them within a strategic framework to guide the evolution of the municipal solid waste management system in the forthcoming years. The creation of this multi-stakeholder platform allowed for the implementation of joint activities and ensured coherence in the products generated by the different projects. This approach could be replicated in other cities and in other sectors with similar effect. Developing a long term vision was essential for the advancement of municipal solid waste management in the city. Nevertheless, plan implementation may still be undermined by the pressures of the short term municipal administrative government, which emphasize operational over strategic investment. © The Author(s) 2014.

  3. Solid State Division

    Energy Technology Data Exchange (ETDEWEB)

    Green, P.H.; Watson, D.M. (eds.)

    1989-08-01

    This report contains brief discussions on work done in the Solid State Division of Oak Ridge National Laboratory. The topics covered are: Theoretical Solid State Physics; Neutron scattering; Physical properties of materials; The synthesis and characterization of materials; Ion beam and laser processing; and Structure of solids and surfaces. (LSP)

  4. Application of process tomography in gas-solid fluidised beds in different scales and structures

    Science.gov (United States)

    Wang, H. G.; Che, H. Q.; Ye, J. M.; Tu, Q. Y.; Wu, Z. P.; Yang, W. Q.; Ocone, R.

    2018-04-01

    Gas-solid fluidised beds are commonly used in particle-related processes, e.g. for coal combustion and gasification in the power industry, and the coating and granulation process in the pharmaceutical industry. Because the operation efficiency depends on the gas-solid flow characteristics, it is necessary to investigate the flow behaviour. This paper is about the application of process tomography, including electrical capacitance tomography (ECT) and microwave tomography (MWT), in multi-scale gas-solid fluidisation processes in the pharmaceutical and power industries. This is the first time that both ECT and MWT have been applied for this purpose in multi-scale and complex structure. To evaluate the sensor design and image reconstruction and to investigate the effects of sensor structure and dimension on the image quality, a normalised sensitivity coefficient is introduced. In the meantime, computational fluid dynamic (CFD) analysis based on a computational particle fluid dynamic (CPFD) model and a two-phase fluid model (TFM) is used. Part of the CPFD-TFM simulation results are compared and validated by experimental results from ECT and/or MWT. By both simulation and experiment, the complex flow hydrodynamic behaviour in different scales is analysed. Time-series capacitance data are analysed both in time and frequency domains to reveal the flow characteristics.

  5. Solid phase microextraction.

    Science.gov (United States)

    Pawliszyn, J

    2001-01-01

    Solid Phase Microextraction (SPME) uses a small volume of sorbent dispersed typically on the surface of small fibres, to isolate and concentrate analytes from sample matrix. After contact with sample, analytes are absorbed or adsorbed by the fibre phase (depending on the nature of the coating) until an equilibrium is reached in the system. The amount of an analyte extracted by the coating at equilibrium is determined by the magnitude of the partition coefficient of the analyte between the sample matrix and the coating material. After the extraction step, the fibres are transferred, with the help of a syringe-like handling device, to analytical instrument, for separation and quantitation of target analytes. This technique integrates sampling, extraction and sample introduction and is a simple way of facilitating on-site monitoring. Applications of this technique include environmental monitoring, industrial hygiene, process monitoring, clinical, forensic, food, flavour, fragrance and drug analyses, in laboratory and on-site analysis.

  6. Structural analysis of nickel doped cerium oxide catalysts for fuel reforming in solid oxide fuel cells

    Science.gov (United States)

    Cavendish, Rio

    As world energy demands increase, research into more efficient energy production methods has become imperative. Heterogeneous catalysis and nanoscience are used to promote chemical transformations important for energy production. These concepts are important in solid oxide fuel cells (SOFCs) which have attracted attention because of their potential to provide an efficient and environmentally favorable power generation system. The SOFC is also fuel-flexible with the ability to run directly on many fuels other than hydrogen. Internal fuel reforming directly in the anode of the SOFC would greatly reduce the cost and complexity of the device. Methane is the simplest hydrocarbon and a main component in natural gas, making it useful when testing catalysts on the laboratory scale. Nickel (Ni) and gadolinium (Gd) doped ceria (CeO 2) catalysts for potential use in the SOFC anode were synthesized with a spray drying method and tested for catalytic performance using partial oxidation of methane and steam reforming. The relationships between catalytic performance and structure were then investigated using X-ray diffraction, transmission electron microscopy, and environmental transmission electron microscopy. The possibility of solid solutions, segregated phases, and surface layers of Ni were explored. Results for a 10 at.% Ni in CeO2 catalyst reveal a poor catalytic behavior while a 20 at.% Ni in CeO2 catalyst is shown to have superior activity. The inclusion of both 10 at.% Gd and 10 at.% Ni in CeO2 enhances the catalytic performance. Analysis of the presence of Ni in all 3 samples reveals Ni heterogeneity and little evidence for extensive solid solution doping. Ni is found in small domains throughout CeO2 particles. In the 20 at.% Ni sample a segregated, catalytically active NiO phase is observed. Overall, it is found that significant interaction between Ni and CeO2 occurs that could affect the synthesis and functionality of the SOFC anode.

  7. SolidWorks Administration Bible

    CERN Document Server

    Lombard, Matt

    2009-01-01

    What you need to prepare, install, and maintain SolidWorks. It's not enough to know how to use SolidWorks, if your job also requires you to install or maintain it, train new users, and implement standards. This in-depth guide was written for those of you who have to actually manage your company's SolidWorks system. From hardware selection to helping users to licensing and more, this is the everyday, bread-and-butter SolidWorks administration resource that IT and CAD managers have been seeking.:; SolidWorks is a powerful 3D solid modeling system that is popular with CAD users everywhere, but of

  8. Gravitational sedimentation of cloud of solid spherical particles at small Reynolds numbers

    Directory of Open Access Journals (Sweden)

    Arkhipov Vladimir

    2015-01-01

    Full Text Available The experimental results of study of gravitational sedimentation of highly-concentrated systems of solid spherical particles at small Reynolds numbers Re<1 are presented. Empirical equation for drag coefficient of the particle assembly has been obtained. The influence of initial particle concentration in the cloud on its dynamics and velocity has been analysed.

  9. Determination of correction coefficients for quantitative analysis by mass spectrometry. Application to uranium impurities analysis; Recherche des coefficients de correction permettant l'analyse quantitative par spectrometrie de masse. Application a l'analyse d'impuretes dans l'uranium

    Energy Technology Data Exchange (ETDEWEB)

    Billon, J P [Commissariat a l' Energie Atomique, Bruyeres-le-Chatel (France). Centre d' Etudes

    1970-07-01

    Some of basic principles in spark source mass spectrometry are recalled. It is shown how this method can lead to quantitative analysis when attention is paid to some theoretical aspects. A time constant relation being assumed between the analysed solid sample and the ionic beam it gives we determined experimental relative sensitivity factors for impurities in uranium matrix. Results being in fairly good agreement with: an unelaborate theory on ionization yield in spark-source use of theoretically obtained relative sensitivity factors in uranium matrix has been developed. (author) [French] Apres avoir rappele quelques principes fondamentaux regissant la spectrometrie de masse a etincelles, nous avons montre que moyennant un certain nombre de precautions, il etait possible d'utiliser cette methode en analyse quantitative. Ayant admis qu'il existait une relation constante dans le temps entre l'echantillon solide analyse et le faisceau ionique qui en est issu, nous avons d'abord entrepris de determiner des coefficients de correction experimentaux pour des matrices d'uranium. Les premiers resultats pratiques semblant en accord avec une theorie simple relative au rendement d'ionisation dans la source a etincelles, nous avons etudie la possibilite d'appliquer directement les coefficients theoriques ainsi definis, l'application etant toujours faite sur des matrices d'uranium. (auteur)

  10. Child mortality from solid-fuel use in India: a nationally-representative case-control study

    Directory of Open Access Journals (Sweden)

    Bassani Diego G

    2010-08-01

    Full Text Available Abstract Background Most households in low and middle income countries, including in India, use solid fuels (coal/coke/lignite, firewood, dung, and crop residue for cooking and heating. Such fuels increase child mortality, chiefly from acute respiratory infection. There are, however, few direct estimates of the impact of solid fuel on child mortality in India. Methods We compared household solid fuel use in 1998 between 6790 child deaths, from all causes, in the previous year and 609 601 living children living in 1.1 million nationally-representative homes in India. Analyses were stratified by child's gender, age (neonatal, post-neonatal, 1-4 years and colder versus warmer states. We also examined the association of solid fuel to non-fatal pneumonias. Results Solid fuel use was very common (87% in households with child deaths and 77% in households with living children. After adjustment for demographic factors and living conditions, solid-fuel use significantly increase child deaths at ages 1-4 (prevalence ratio (PR boys: 1.30, 95%CI 1.08-1.56; girls: 1.33, 95%CI 1.12-1.58. More girls than boys died from exposure to solid fuels. Solid fuel use was also associated with non-fatal pneumonia (boys: PR 1.54 95%CI 1.01-2.35; girls: PR 1.94 95%CI 1.13-3.33. Conclusions Child mortality risks, from all causes, due to solid fuel exposure were lower than previously, but as exposure was common solid, fuel caused 6% of all deaths at ages 0-4, 20% of deaths at ages 1-4 or 128 000 child deaths in India in 2004. Solid fuel use has declined only modestly in the last decade. Aside from reducing exposure, complementary strategies such as immunization and treatment could also reduce child mortality from acute respiratory infections.

  11. Solid-State NMR Study of New Copolymers as Solid Polymer Electrolytes

    Directory of Open Access Journals (Sweden)

    Jean-Christophe Daigle

    2018-01-01

    Full Text Available We report the analysis of comb-like polymers by solid-state NMR. The polymers were previously evaluated as solid-polymer-electrolytes (SPE for lithium-polymer-metal batteries that have suitable ionic conductivity at 60 °C. We propose to develop a correlation between 13C solid-state NMR measurements and phase segregation. 13C solid-state NMR is a perfect tool for differentiating polymer phases with fast or slow motions. 7Li was used to monitor the motion of lithium ions in the polymer, and activation energies were calculated.

  12. Concepts in solids lectures on the theory of solids

    CERN Document Server

    Anderson, Philip Warren

    1964-01-01

    These lecture notes constitute a course on a number of central concepts of solid state physics - classification of solids, band theory, the developments in one-electron band theory in the presence of perturbation, effective Hamiltonian theory, elementary excitations and the various types of collective elementary excitation (excitons, spin waves and phonons), the Fermi liquid, ferromagnetic spin waves, antiferromagnetic spin waves and the theory of broken symmetry. The book can be used in conjunction with a survey course in solid state physics, or as the basis of a first graduate-level course.

  13. A novel kind of solid rocket propellant

    Energy Technology Data Exchange (ETDEWEB)

    Lo, R.E. [Berlin University of Technology (Germany). Rocket Technology at the Aerospace Institute (ILR)

    1998-09-01

    Cryogenic Solid Propellants (CSPs) combine the simplicity of conventional solid propulsion with the high performance of liquid propulsion. By introducing materials that require cooling for remaining solid, CSPs offer an almost unlimited choice of propellant constituents that mights be selected with respect to specific impulse, density or environmental protection. The prize to be paid for these advantages is the necessity of constant cooling and the requirement of special design features that provide combustion control by moving from deflagration to hybrid like boundary layer combustion. This is achieved by building the solid propellant grains out of macroscopic elements rather than using the quasi homogeneous mixture of conventional composites. The elements may be coated, providing protection and support. Different elements may be designed for individual tasks and serve as modules for ignition, sustained combustion, gas generation, combustion efficiency enhancement, etc. Modular dissected grains offer many new ways of interaction inside the combustion chamber and new degrees of freedom for the designer of such `multiple internal hybrid grains`. At a preliminary level, a study finished in Germany 1997 demonstrated large payload gains when the US space Shuttle and the ARIANE 5 boosters were replaced by CSP-boosters. A very preliminary cost analysis resulted in development costs in the usual magnitude (but not in higher ones). Costs of operation were identified as crucial, but not established. Some experimental work in Germany is scheduled to begin in 1998, almost all details in this article (and many more that were not mentioned - most prominent cost analyses of CSP development and operations) wait for deeper analysis and verification. Actually, a whole new world new of world of chemical propulsion awaits exploration. The topic can be looked up and discussed at the web site of the Advanced Propulsion Workshop of the International Academy of Astronautics. The author

  14. Results of initial analyses of the salt (macro) batch 11 Tank 21H qualification samples

    Energy Technology Data Exchange (ETDEWEB)

    Peters, T. B. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2017-10-23

    Savannah River National Laboratory (SRNL) analyzed samples from Tank 21H in support of qualification of Interim Salt Disposition Project (ISDP) Salt (Macro) Batch 11 for processing through the Actinide Removal Process (ARP) and the Modular Caustic-Side Solvent Extraction Unit (MCU). This document reports the initial results of the analyses of samples of Tank 21H. Analysis of the Tank 21H Salt (Macro) Batch 11 composite sample indicates that the material does not display any unusual characteristics or observations, such as floating solids, the presence of large amounts of solids, or unusual colors. Further sample results will be reported in a future document. This memo satisfies part of Deliverable 3 of the Technical Task Request (TTR).

  15. An unsteady point vortex method for coupled fluid-solid problems

    Energy Technology Data Exchange (ETDEWEB)

    Michelin, Sebastien [Jacobs School of Engineering, UCSD, Department of Mechanical and Aerospace Engineering, La Jolla, CA (United States); Ecole Nationale Superieure des Mines de Paris, Paris (France); Llewellyn Smith, Stefan G. [Jacobs School of Engineering, UCSD, Department of Mechanical and Aerospace Engineering, La Jolla, CA (United States)

    2009-06-15

    A method is proposed for the study of the two-dimensional coupled motion of a general sharp-edged solid body and a surrounding inviscid flow. The formation of vorticity at the body's edges is accounted for by the shedding at each corner of point vortices whose intensity is adjusted at each time step to satisfy the regularity condition on the flow at the generating corner. The irreversible nature of vortex shedding is included in the model by requiring the vortices' intensity to vary monotonically in time. A conservation of linear momentum argument is provided for the equation of motion of these point vortices (Brown-Michael equation). The forces and torques applied on the solid body are computed as explicit functions of the solid body velocity and the vortices' position and intensity, thereby providing an explicit formulation of the vortex-solid coupled problem as a set of non-linear ordinary differential equations. The example of a falling card in a fluid initially at rest is then studied using this method. The stability of broadside-on fall is analysed and the shedding of vorticity from both plate edges is shown to destabilize this position, consistent with experimental studies and numerical simulations of this problem. The reduced-order representation of the fluid motion in terms of point vortices is used to understand the physical origin of this destabilization. (orig.)

  16. Effect on Cs removal of solid-phase metal oxidation in metal ferrocyanides

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Keun-Young; Kim, Jimin; Oh, Maengkyo; Lee, Eil-Hee; Kim, Kwang-Wook; Chung, Dong-Yong; Moon, Jei-Kwon [Korea Atomic Energy Research Institute (KAERI), Daejeon (Korea, Republic of).

    2017-07-01

    Metal ferrocyanides (MFCs) have been studied for many years and are regarded as efficient adsorbents for the selective removal of radioactive cesium (Cs) from contaminated aqueous solutions. Although their efficiency has been demonstrated, various investigations on the physicochemical, thermal, and radiological stability of the solids of MFCs are required to enhance the applicability of MFCs in the treatment process. We observed that the Cs adsorption efficiencies of cobalt and nickel ferrocyanides decreased as their aging period increased, while the Cs adsorption efficiencies of copper and zinc ferrocyanides did not decrease. The tendencies of these ferrocyanides were accelerated by exposure of the solids at a higher temperature for a longer time. Our comprehensive analyses demonstrated that only the oxidizable metals in the MFCs can be oxidized by aging time and increasing temperature; also, this affects the Cs removal efficiency by decreasing the exchangeable sites in the solids. The chemical stability of MFCs is very important for the optimization of the synthesis and storage conditions.

  17. Energy Harvesting, Electrode Processes and the Partitioning and Speciation of Solid Phase Iron and Sulfur in Marine Sediments

    National Research Council Canada - National Science Library

    Reimers, Clare

    2003-01-01

    .... Sediment, pore water and electrode surface analyses indicated that electricity product ion is coupled to the oxidation of dissolved and solid-phase forms of reduced sulfur supplied from the sediments...

  18. Diversity in C-Xanes Spectra Obtained from Carbonaceous Solid Inclusions from Monahans Halite

    Science.gov (United States)

    Kebukawa, Y.; Zolensky, M. E.; Fries, M.; Kilcoyne, A. L. D.; Rahman, Z.; Cody, G. D.

    2014-01-01

    Monahans meteorite (H5) contains fluid inclusion- bearing halite (NaCl) crystals [1]. Microthermometry and Raman spectroscopy showed that the fluid in the inclusions is an aqueous brine and they were trapped near 25degC [1]. Their continued presence in the halite grains requires that their incorporation into the H chondrite asteroid was post metamorphism [2]. Abundant solid inclusions are also present in the halites. The solid inclusions include abundant and widely variable organics [2]. Analyses by Raman microprobe, SEM/EDX, synchrotron X-ray diffraction and TEM reveal that these grains include macromolecular carbon similar in structure to CV3 chondrite matrix carbon, aliphatic carbon compounds, olivine (Fo99-59), high- and low-Ca pyroxene, feldspars, magnetite, sulfides, lepidocrocite, carbonates, diamond, apatite and possibly the zeolite phillipsite [3]. Here we report organic analyses of these carbonaceous residues in Monahans halite using C-, N-, and O- X-ray absorption near edge structure (XANES). Samples and Methods: Approximately 100 nm-thick sections were extracted with a focused ion beam (FIB) at JSC from solid inclusions from Monahans halite. The sections were analyzed using the scanning transmission X-ray microscope (STXM) on beamline 5.3.2.2 at the Advanced Light Source, Lawrence Berkeley National Laboratory for XANES spectroscopy. Results and Discussion: C-XANES spectra of the solid inclusions show micrometer-scale heterogeneity, indicating that the macromolecular carbon in the inclusions have complex chemical variations. C-XANES features include 284.7 eV assigned to aromatic C=C, 288.4-288.8 eV assigned to carboxyl, and 290.6 eV assigned to carbonate. The carbonyl features obtained by CXANES might have been caused by the FIB used in sample preparation. No specific N-XANES features are observed. The CXANES spectra obtained from several areas in the FIB sections include type 1&2 chondritic IOM like, type 3 chondritic IOM like, and none of the above

  19. Longitudinal acoustic instabilities in slender solid propellant rockets : linear analysis

    OpenAIRE

    García Schafer, Juan Esteban; Liñán Martínez, Amable

    2001-01-01

    To describe the acoustic instabilities in the combustion chambers of laterally burning solid propellant rockets the interaction of the mean flow with the acoustic waves is analysed, using multiple scale techniques, for realistic cases in which the combustion chamber is slender and the nozzle area is small compared with the cross-sectional area of the chamber. Associated with the longitudinal acoustic oscillations we find vorticity and entropy waves, with a wavelength typically small compared ...

  20. 31P NMR imaging of solid bone with solid echoes combined with refocused gradients

    International Nuclear Information System (INIS)

    Li, L.; Utah Univ., Salt Lake City, UT; Kruger, R.A.

    1990-01-01

    This note on 31 p NMR imaging presents some observations of the solid echoes acquired from solid bone and how the proposed solid echo imaging method can be employed to obtain the 31 images of solid bone. (UK)

  1. Energy properties of solid fossil fuels and solid biofuels

    International Nuclear Information System (INIS)

    Holubcik, Michal; Jandacka, Jozef; Kolkova, Zuzana

    2016-01-01

    The paper deals about the problematic of energy properties of solid biofuels in comparison with solid fossil fuels. Biofuels are alternative to fossil fuels and their properties are very similar. During the experiments were done in detail experiments to obtain various properties of spruce wood pellets and wheat straw pellets like biofuels in comparison with brown coal and black coal like fossil fuels. There were tested moisture content, volatile content, fixed carbon content, ash content, elementary analysis (C, H, N, S content) and ash fusion temperatures. The results show that biofuels have some advantages and also disadvantages in comparison with solid fossil fuels.

  2. Energy properties of solid fossil fuels and solid biofuels

    Energy Technology Data Exchange (ETDEWEB)

    Holubcik, Michal, E-mail: michal.holubcik@fstroj.uniza.sk; Jandacka, Jozef, E-mail: jozef.jandacka@fstroj.uniza.sk [University of Žilina, Faculty of Mechanical Engineering, Department of Power Engineering, Univerzitná 8215/1, 010 26 Žilina (Slovakia); Kolkova, Zuzana, E-mail: zuzana.kolkova@rc.uniza.sk [Research centre, University of Žilina, Univerzitna 8215/1, 010 26 Žilina (Slovakia)

    2016-06-30

    The paper deals about the problematic of energy properties of solid biofuels in comparison with solid fossil fuels. Biofuels are alternative to fossil fuels and their properties are very similar. During the experiments were done in detail experiments to obtain various properties of spruce wood pellets and wheat straw pellets like biofuels in comparison with brown coal and black coal like fossil fuels. There were tested moisture content, volatile content, fixed carbon content, ash content, elementary analysis (C, H, N, S content) and ash fusion temperatures. The results show that biofuels have some advantages and also disadvantages in comparison with solid fossil fuels.

  3. Standardized Testing Program for Solid-State Hydrogen Storage Technologies

    Energy Technology Data Exchange (ETDEWEB)

    Miller, Michael A. [Southwest Research Institute; Page, Richard A. [Southwest Research Institute

    2012-07-30

    In the US and abroad, major research and development initiatives toward establishing a hydrogen-based transportation infrastructure have been undertaken, encompassing key technological challenges in hydrogen production and delivery, fuel cells, and hydrogen storage. However, the principal obstacle to the implementation of a safe, low-pressure hydrogen fueling system for fuel-cell powered vehicles remains storage under conditions of near-ambient temperature and moderate pressure. The choices for viable hydrogen storage systems at the present time are limited to compressed gas storage tanks, cryogenic liquid hydrogen storage tanks, chemical hydrogen storage, and hydrogen absorbed or adsorbed in a solid-state material (a.k.a. solid-state storage). Solid-state hydrogen storage may offer overriding benefits in terms of storage capacity, kinetics and, most importantly, safety.The fervor among the research community to develop novel storage materials had, in many instances, the unfortunate consequence of making erroneous, if not wild, claims on the reported storage capacities achievable in such materials, to the extent that the potential viability of emerging materials was difficult to assess. This problem led to a widespread need to establish a capability to accurately and independently assess the storage behavior of a wide array of different classes of solid-state storage materials, employing qualified methods, thus allowing development efforts to focus on those materials that showed the most promise. However, standard guidelines, dedicated facilities, or certification programs specifically aimed at testing and assessing the performance, safety, and life cycle of these emergent materials had not been established. To address the stated need, the Testing Laboratory for Solid-State Hydrogen Storage Technologies was commissioned as a national-level focal point for evaluating new materials emerging from the designated Materials Centers of Excellence (MCoE) according to

  4. Role of anisotropy in determining stability of electrodeposition at solid-solid interfaces

    Science.gov (United States)

    Ahmad, Zeeshan; Viswanathan, Venkatasubramanian

    2017-10-01

    We investigate the stability of electrodeposition at solid-solid interfaces for materials exhibiting an anisotropic mechanical response. The stability of electrodeposition or resistance to the formation of dendrites is studied within a linear stability analysis. The deformation and stress equations are solved using the Stroh formalism and faithfully recover the boundary conditions at the interface. The stability parameter is used to quantify the stability of different solid-solid interfaces incorporating the full anisotropy of the elastic tensor of the two materials. Results show a high degree of variability in the stability parameter depending on the crystallographic orientation of the solids in contact, and point to opportunities for exploiting this effect in developing Li metal anodes.

  5. Quality standards and requirements for solid recovered fuels: a review.

    Science.gov (United States)

    Flamme, Sabine; Geiping, Julia

    2012-04-01

    The utilization of solid recovered fuels (SRF) for energy recovery has been increasing steadily in recent years, and this development is set to continue. In order to use SRF efficiently, it is necessary to define quality standards and introduce targeted quality assurance measures. SRF can be used both in mono-incineration and in co-incineration systems, for instance in power generation and cement plants; but as quality requirements differ, it is necessary to unambiguously define the term 'solid recovered fuel'. The purpose of this article is to provide an overview of the origin, development and the current status of quality assurance for SRF. The basic principles of quality assurance for SRF are explained with reference to the development of the German RAL Quality Assurance System and in addition specifications that have emerged from European standardization work of CEN/TC 343 are analysed.

  6. Laser cooling of solids

    Energy Technology Data Exchange (ETDEWEB)

    Epstein, Richard I [Los Alamos National Laboratory; Sheik-bahae, Mansoor [UNM

    2008-01-01

    We present an overview of solid-state optical refrigeration also known as laser cooling in solids by fluorescence upconversion. The idea of cooling a solid-state optical material by simply shining a laser beam onto it may sound counter intuitive but is rapidly becoming a promising technology for future cryocooler. We chart the evolution of this science in rare-earth doped solids and semiconductors.

  7. Determination of multi-class herbicides in soil by liquid-solid extraction coupled with headspace solid phase microextraction method

    Directory of Open Access Journals (Sweden)

    Đurović-Pejčev Rada

    2016-01-01

    Full Text Available A method is described for simultaneous determination of five herbicides (metribuzin, acetochlor, clomazone, oxyfluorfen and dimethenamid belonging to different pesticides groups in soil samples. Developed headspace solid phase microextraction method (HS-SPME in combination with liquid-solid sample preparation (LS was optimized and applied in the analysis of some agricultural samples. Optimization of microextraction conditions, such as temperature, extraction time and sodium chloride (NaCl content was perfor-med using 100 μm polydimethyl-siloxane (PDMS fiber. The extraction effi-ciencies of methanol, methanol:acetone=1:1 and methanol:acetone:hexane= =2:2:1 and the optimum number of extraction steps during the sample prepa-ration, were tested, as well. Gas chromatography-mass spectrometry (GC-MS was used for detection and quantification, obtaining relative standard deviation (RSD below 13%, and recovery values higher than 83% for multiple analyses of soil samples fortified at 30 μg kg-1 of each herbicide. Limits of detection (LOD were less than 1.2 μg kg-1 for all the studied herbicides. [Projekat Ministarstva nauke Republike Srbije, br. TR31043 i br. III43005

  8. Solid electrolytes

    Science.gov (United States)

    Abraham, Kuzhikalail M.; Alamgir, Mohamed

    1993-06-15

    This invention pertains to Li ion (Li.sup.+) conductive solid polymer electrolytes composed of solvates of Li salts immobilized (encapsulated) in a solid organic polymer matrix. In particular, this invention relates to solid polymer electrolytes derived by immobilizing complexes (solvates) formed between a Li salt such as LiAsF.sub.6, LiCF.sub.3 SO.sub.3 or LiClO.sub.4 and a mixture of aprotic organic solvents having high dielectric constants such as ethylene carbonate (EC) (dielectric constant=89.6) and propylene carbonate (PC) (dielectric constant=64.4) in a polymer matrix such as polyacrylonitrile, poly(tetraethylene glycol diacrylate), or poly(vinyl pyrrolidinone).

  9. Spatially Resolved Quantification of the Surface Reactivity of Solid Catalysts.

    Science.gov (United States)

    Huang, Bing; Xiao, Li; Lu, Juntao; Zhuang, Lin

    2016-05-17

    A new property is reported that accurately quantifies and spatially describes the chemical reactivity of solid surfaces. The core idea is to create a reactivity weight function peaking at the Fermi level, thereby determining a weighted summation of the density of states of a solid surface. When such a weight function is defined as the derivative of the Fermi-Dirac distribution function at a certain non-zero temperature, the resulting property is the finite-temperature chemical softness, termed Fermi softness (SF ), which turns out to be an accurate descriptor of the surface reactivity. The spatial image of SF maps the reactive domain of a heterogeneous surface and even portrays morphological details of the reactive sites. SF analyses reveal that the reactive zones on a Pt3 Y(111) surface are the platinum sites rather than the seemingly active yttrium sites, and the reactivity of the S-dimer edge of MoS2 is spatially anisotropic. Our finding is of fundamental and technological significance to heterogeneous catalysis and industrial processes demanding rational design of solid catalysts. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  10. Meeting the Imperative to Improve Physician Well-being: Assessment of an Innovative Program

    Science.gov (United States)

    Arnetz, Bengt B.; Christensen, John F.; Homer, Louis

    2007-01-01

    BACKGROUND Improving physician health and performance is critical to successfully meet the challenges facing health systems that increasingly emphasize productivity. Assessing long-term efficacy and sustainability of programs aimed at enhancing physician and organizational well-being is imperative. OBJECTIVE To determine whether data-guided interventions and a systematic improvement process to enhance physician work-life balance and organizational efficacy can improve physician and organizational well-being. DESIGN AND PARTICIPANTS From 2000 to 2005, 22–32 physicians regularly completed 3 questionnaires coded for privacy. Results were anonymously reported to physicians and the organization. Data-guided interventions to enhance physician and organizational well-being were built on physician control over the work environment, order in the clinical setting, and clinical meaning. MEASUREMENTS Questionnaires included an ACP/ASIM survey on physician satisfaction, the Maslach Burnout Inventory (MBI), and the Quality Work Competence (QWC) survey. RESULTS Emotional and work-related exhaustion decreased significantly over the study period (MBI, p = 0.002; QWC, p = 0.035). QWC measures of organizational health significantly improved initially and remained acceptable and stable during the rest of the study. CONCLUSIONS A data-guided program on physician well-being, using validated instruments and process improvement methods, enhanced physician and organizational well-being. Given the increases in physician burnout, organizations are encouraged to urgently create individual and systems approaches to lessen burnout risk. PMID:17891503

  11. Review on solid electrolytes for all-solid-state lithium-ion batteries

    Science.gov (United States)

    Zheng, Feng; Kotobuki, Masashi; Song, Shufeng; Lai, Man On; Lu, Li

    2018-06-01

    All-solid-state (ASS) lithium-ion battery has attracted great attention due to its high safety and increased energy density. One of key components in the ASS battery (ASSB) is solid electrolyte that determines performance of the ASSB. Many types of solid electrolytes have been investigated in great detail in the past years, including NASICON-type, garnet-type, perovskite-type, LISICON-type, LiPON-type, Li3N-type, sulfide-type, argyrodite-type, anti-perovskite-type and many more. This paper aims to provide comprehensive reviews on some typical types of key solid electrolytes and some ASSBs, and on gaps that should be resolved.

  12. Developments in international solid biofuel trade - an analysis of volumes, policies and market factors

    NARCIS (Netherlands)

    Lamers, P.; Junginger, H.M.; Hamelinck, C.N.; Faaij, A.P.C.

    2012-01-01

    This paper presents and analyses international solid biofuel trade and concludes upon interactions with bioenergy policies and market factors. It shows that trade has grown from about 56 to 300 PJ between 2000 and 2010. Wood pellets grew strongest, i.e. from 8.5 to 120 PJ. Other relevant streams by

  13. Statics of deformable solids

    CERN Document Server

    Bisplinghoff, Raymond L; Pian, Theodore HH

    2014-01-01

    Profusely illustrated exposition of fundamentals of solid mechanics and principles of mechanics, statics, and simple statically indeterminate systems. Covers strain and stress in three-dimensional solids, elementary elasticity, energy principles in solid continuum, and more. 1965 edition.

  14. Solid-phase data from cores at the proposed Dewey Burdock uranium in-situ recovery mine, near Edgemont, South Dakota

    Science.gov (United States)

    Johnson, Raymond H.; Diehl, Sharon F.; Benzel, William M.

    2013-01-01

    This report releases solid-phase data from cores at the proposed Dewey Burdock uranium in-situ recovery site near Edgemont, South Dakota. These cores were collected by Powertech Uranium Corporation, and material not used for their analyses were given to the U.S. Geological Survey for additional sampling and analyses. These additional analyses included total carbon and sulfur, whole rock acid digestion for major and trace elements, 234U/238U activity ratios, X-ray diffraction, thin sections, scanning electron microscopy analyses, and cathodoluminescence. This report provides the methods and data results from these analyses along with a short summary of observations.

  15. Nanoscale hydrodynamics near solids

    Science.gov (United States)

    Camargo, Diego; de la Torre, J. A.; Duque-Zumajo, D.; Español, Pep; Delgado-Buscalioni, Rafael; Chejne, Farid

    2018-02-01

    Density Functional Theory (DFT) is a successful and well-established theory for the study of the structure of simple and complex fluids at equilibrium. The theory has been generalized to dynamical situations when the underlying dynamics is diffusive as in, for example, colloidal systems. However, there is no such a clear foundation for Dynamic DFT (DDFT) for the case of simple fluids in contact with solid walls. In this work, we derive DDFT for simple fluids by including not only the mass density field but also the momentum density field of the fluid. The standard projection operator method based on the Kawasaki-Gunton operator is used for deriving the equations for the average value of these fields. The solid is described as featureless under the assumption that all the internal degrees of freedom of the solid relax much faster than those of the fluid (solid elasticity is irrelevant). The fluid moves according to a set of non-local hydrodynamic equations that include explicitly the forces due to the solid. These forces are of two types, reversible forces emerging from the free energy density functional, and accounting for impenetrability of the solid, and irreversible forces that involve the velocity of both the fluid and the solid. These forces are localized in the vicinity of the solid surface. The resulting hydrodynamic equations should allow one to study dynamical regimes of simple fluids in contact with solid objects in isothermal situations.

  16. SolidWorks 2011 Assemblies Bible

    CERN Document Server

    Lombard, Matt

    2011-01-01

    A fan of the SolidWorks Bible, but want more detail on assemblies? Here you go. SolidWorks fans have long sought more detail on SolidWorks topics, and now you have it. We took our popular SolidWorks Bible, divided it into two books (SolidWorks 2011 Assemblies Bible and SolidWorks 2011 Parts Bible) and packed each new book with a host of items from your wish lists, such as more extensive coverage of the basics, additional tutorials, and expanded coverage of topics largely ignored by other books. This SolidWorks 2011 Assemblies Bible shows you how to organize parts data to create assemblies or s

  17. Preparation of environmental analyses for synfuel and unconventional gas technologies

    Energy Technology Data Exchange (ETDEWEB)

    Reed, R.M. (ed.)

    1982-09-01

    Government agencies that offer financial incentives to stimulate the commercialization of synfuel and unconventional gas technologies usually require an analysis of environmental impacts resulting from proposed projects. This report reviews potentially significant environmental issues associated with a selection of these technologies and presents guidance for developing information and preparing analyses to address these issues. The technologies considered are western oil shale, tar sand, coal liquefaction and gasification, peat, unconventional gas (western tight gas sands, eastern Devonian gas shales, methane from coal seams, and methane from geopressured aquifers), and fuel ethanol. Potentially significant issues are discussed under the general categories of land use, air quality, water use, water quality, biota, solid waste disposal, socioeconomics, and health and safety. The guidance provided in this report can be applied to preparation and/or review of proposals, environmental reports, environmental assessments, environmental impact statements, and other types of environmental analyses. The amount of detail required for any issue discussed must, by necessity, be determined on a case-by-case basis.

  18. Preparation and characterization of a novel polymeric based solid-solid phase change heat storage material

    International Nuclear Information System (INIS)

    Xi Peng; Gu Xiaohua; Cheng Bowen; Wang Yufei

    2009-01-01

    Here we reported a two-step procedure for preparing a novel polymeric based solid-solid phase change heat storage material. Firstly, a copolymer monomer containing a polyethylene glycol monomethyl ether (MPEG) phase change unit and a vinyl unit was synthesized via the modification of hydrogen group of MPEG. Secondly, by copolymerization of the copolymer monomer and phenyl ethylene, a novel polymeric based solid-solid phase change heat storage material was prepared. The composition, structure and properties of the novel polymeric based solid-solid phase change material were characterized by IR, 1 H NMR, DSC, WAXD, and POM, respectively. The results show that the novel polymeric based solid-solid phase change material possesses of excellent crystal properties and high phase change enthalpy.

  19. Combustibility of tetraphenylborate solids

    International Nuclear Information System (INIS)

    Walker, D.D.

    1989-01-01

    Liquid slurries expected under normal in-tank processing (ITP) operations are not ignitible because of their high water content. However, deposits of dry solids from the slurries are combustible and produce dense, black smoke when burned. The dry solids burn similarly to Styrofoam and more easily than sawdust. It is the opinion of fire hazard experts that a benzene vapor deflagration could ignite the dry solids. A tetraphenylborate solids fire will rapidly plug the waste tank HEPA ventilation filters due to the nature of the smoke produced. To prevent ignition and combustion of these solids, the waste tanks have been equipped with a nitrogen inerting system

  20. Stability of Electrodeposition at Solid-Solid Interfaces and Implications for Metal Anodes

    Science.gov (United States)

    Ahmad, Zeeshan; Viswanathan, Venkatasubramanian

    2017-08-01

    We generalize the conditions for stable electrodeposition at isotropic solid-solid interfaces using a kinetic model which incorporates the effects of stresses and surface tension at the interface. We develop a stability diagram that shows two regimes of stability: a previously known pressure-driven mechanism and a new density-driven stability mechanism that is governed by the relative density of metal in the two phases. We show that inorganic solids and solid polymers generally do not lead to stable electrodeposition, and provide design guidelines for achieving stable electrodeposition.

  1. An initial applications study of ceria-gadolinia solid oxide fuel cells: V. 1

    Energy Technology Data Exchange (ETDEWEB)

    Bauen, A.; Hart, D.; Mould, B.

    1998-11-01

    Fuel cells are categorised by their electrolytes, and the solid oxide fuel cell is so called because its electrolyte consists of a solid ceramic oxide. Commonly this has been a form of zirconia, though other materials are now being considered for their different electrical properties. One of these, ceria doped with gadolinia, shows promise for use in lower temperature regimes than zirconia, and may open up different areas of a future market for consideration. This report considers the opportunities for ceria-gadolinia solid oxide fuel cell systems by comparing them with the application requirements in markets where fuel cells may have potential. The advantages and disadvantages of the technology are analysed, together with the state of the art in research and development. The direction in which research effort needs to move to address some of the issues is assessed. The report then draws conclusions regarding the potential of ceria-gadolinia in solid oxide fuel cell systems and in the energy markets as a whole. It should be noted that while this report is an applications study, some technology assessment has been included. Much of this is found in Volume 2. (author)

  2. Pulmonary adenocarcinomas appearing as part-solid ground-glass nodules: Is measuring solid component size a better prognostic indicator?

    Energy Technology Data Exchange (ETDEWEB)

    Hwang, Eui Jin; Ryu, Youngjin; Lee, Sang Min [Seoul National University Medical Research Center, Department of Radiology, Seoul National University College of Medicine, and Institute of Radiation Medicine, 101, Daehangno, Jongno-gu, Seoul (Korea, Republic of); Park, Chang Min; Goo, Jin Mo [Seoul National University Medical Research Center, Department of Radiology, Seoul National University College of Medicine, and Institute of Radiation Medicine, 101, Daehangno, Jongno-gu, Seoul (Korea, Republic of); Seoul National University, Cancer Research Institute, Seoul (Korea, Republic of); Kim, Young Tae [Seoul National University, Cancer Research Institute, Seoul (Korea, Republic of); Seoul National University College of Medicine, Department of Thoracic and Cardiovascular Surgery, Seoul (Korea, Republic of); Kim, Young Whan [Seoul National University College of Medicine, Division of Pulmonary and Critical Care Medicine, Department of Internal Medicine and Lung Institute, Seoul (Korea, Republic of)

    2014-10-02

    To assess whether measuring the solid portion of adenocarcinomas appearing as part-solid ground-glass nodules (GGNs) can predict a patient's prognosis accurately and how the prognosis corresponds to that of solid nodules. 501 patients (solid nodule group, 304; part-solid GGN group, 197) underwent curative surgery for stage I adenocarcinomas. Maximal diameters of the whole lesion including ground-glass opacities (D{sub whole}) and solid components only (D{sub solid}) were measured on CT. Disease-free survival (DFS) and overall survival (OS) were calculated from the date of surgery. D{sub solid} was a significant prognostic factor in the part-solid GGN group, while D{sub whole} was not. Part-solid GGNs with D{sub solid} ≤2 cm showed significantly better DFS (P = 0.016) and OS (P = 0.004) than solid nodules; however, those with D{sub solid} >2 cm did not show a significant difference. Hazard ratio (HR) for increase in D{sub solid} was significantly greater in part-solid GGNs than in solid nodules (P = 0.009). For OS, HR for increase in D{sub solid} was greater in part-solid GGNs than in solid nodule, which was marginally not significant (P = 0.060). D{sub solid} was better than D{sub whole} for prognosis prediction of adenocarcinomas appearing as part-solid GGNs. In addition, the influence of D{sub solid} on prognosis in the part-solid GGN group was greater than in the solid nodule group. (orig.)

  3. Luminescence and the solid state

    CERN Document Server

    Ropp, Richard C

    2013-01-01

    Since the discovery of the transistor in 1948, the study of the solid state has been burgeoning. Recently, cold fusion and the ceramic superconductor have given cause for excitement. There are two approaches possible to this area of science, namely, that of solid state physics and solid state chemistry, although both overlap extensively. The former is more concerned with electronic states in solids (including electromagnetics) whereas the latter is more concerned with interactions of atoms in solids. The area of solid state physics is well documented, however, there are very few texts which de

  4. Municipal solid waste incineration in China and the issue of acidification: A review.

    Science.gov (United States)

    Ji, Longjie; Lu, Shengyong; Yang, Jie; Du, Cuicui; Chen, Zhiliang; Buekens, Alfons; Yan, Jianhua

    2016-04-01

    In China, incineration is essential for reducing the volume of municipal solid waste arising in its numerous megacities. The evolution of incinerator capacity has been huge, yet it creates strong opposition from a small, but vocal part of the population. The characteristics of Chinese municipal solid waste are analysed and data presented on its calorific value and composition. These are not so favourable for incineration, since the sustained use of auxiliary fuel is necessary for ensuring adequate combustion temperatures. Also, the emission standard for acid gases is more lenient in China than in the European Union, so special attention should be paid to the issue of acidification arising from flue gas. Next, the techniques used in flue gas cleaning in China are reviewed and the acidification potential by cleaned flue gas is estimated. Still, acidification induced by municipal solid waste incinerators remains marginal compared with the effects of coal-fired power plants. © The Author(s) 2016.

  5. Solid biomass barometer

    International Nuclear Information System (INIS)

    Anon.

    2007-01-01

    Primary energy production from solid biomass (wood, wood waste and other solid vegetal and animal materials) reached 62,4 million tons oil equivalent (Mtoe) in 2006, i-e 3,1 more than in 2005. The primary energy coming from the direct combustion of renewable origin solid urban waste in incineration unit scan also be added to this figure. In 2006 this represented a production of 5,3 Mtoe, i-e 0,1 Mtoe more than in 2005. (author)

  6. A continuum treatment of sliding in Eulerian simulations of solid-solid and solid-fluid interfaces

    Science.gov (United States)

    Subramaniam, Akshay; Ghaisas, Niranjan; Lele, Sanjiva

    2017-11-01

    A novel treatment of sliding is developed for use in an Eulerian framework for simulating elastic-plastic deformations of solids coupled with fluids. In this method, embedded interfacial boundary conditions for perfect sliding are imposed by enforcing the interface normal to be a principal direction of the Cauchy stress and appropriate consistency conditions ensure correct transmission and reflection of waves at the interface. This sliding treatment may be used either to simulate a solid-solid sliding interface or to incorporate an internal slip boundary condition at a solid-fluid interface. Sliding laws like the Coulomb friction law can also be incorporated with relative ease into this framework. Simulations of sliding interfaces are conducted using a 10th order compact finite difference scheme and a Localized Artificial Diffusivity (LAD) scheme for shock and interface capturing. 1D and 2D simulations are used to assess the accuracy of the sliding treatment. The Richmyer-Meshkov instability between copper and aluminum is simulated with this sliding treatment as a demonstration test case. Support for this work was provided through Grant B612155 from the Lawrence Livermore National Laboratory, US Department of Energy.

  7. The Attachment Imperative: Parental Experiences of Relation-making in a Danish Neonatal Intensive Care Unit.

    Science.gov (United States)

    Navne, Laura E; Svendsen, Mette N; Gammeltoft, Tine M

    2018-03-01

    In this article, we explore how parents establish relations with extremely premature infants whose lives and futures are uncertain. Drawing on ethnographic fieldwork in a Danish Neonatal Intensive Care Unit (NICU), we engage recent discussions of the limits of conventional anthropological thinking on social relations and point to the productive aspects of practices of distance and detachment. We show that while the NICU upholds an imperative of attachment independently of the infant's chances of survival, for parents, attachment is contingent on certain hesitations in relation to their infant. We argue that there are nuances in practices of relationmaking in need of more attention (i.e., the nexus of attachment and detachment). Refraining from touching, holding, and feeding their infants during critical periods, the parents enact detachment as integral to their practices of attachment. Such "cuts" in parent-infant relations become steps on the way to securing the infant's survival and making kin(ship). We conclude that although infants may be articulated as "maybe-lives" by staff, in the NICU as well as in Danish society, the ideal of attachment appears to leave little room for "maybe-parents." © 2017 by the American Anthropological Association.

  8. Laser cooling of solids

    CERN Document Server

    Petrushkin, S V

    2009-01-01

    Laser cooling is an important emerging technology in such areas as the cooling of semiconductors. The book examines and suggests solutions for a range of problems in the development of miniature solid-state laser refrigerators, self-cooling solid-state lasers and optical echo-processors. It begins by looking at the basic theory of laser cooling before considering such topics as self-cooling of active elements of solid-state lasers, laser cooling of solid-state information media of optical echo-processors, and problems of cooling solid-state quantum processors. Laser Cooling of Solids is an important contribution to the development of compact laser-powered cryogenic refrigerators, both for the academic community and those in the microelectronics and other industries. Provides a timely review of this promising field of research and discusses the fundamentals and theory of laser cooling Particular attention is given to the physics of cooling processes and the mathematical description of these processes Reviews p...

  9. Potential for a solids fire during an ITP waste tank deflagration and the impact on gas pressure

    International Nuclear Information System (INIS)

    Thomas, J.K.

    1993-07-01

    During the In-Tank Precipitation (ITP) process, solid deposits may form at the water-line on internal waste tank surfaces. These solids may be combustible due to the presence of tetraphenylborate compounds and hence there is a potential that a waste tank deflagration could ignite a solids fire. The work described in this report evaluates the potential for a waste tank deflagration to ignite a solids fire and the subsequent effect on gas pressure. Thermal analyses were performed using a one-dimensional conduction model, radiative heat flux values calculated with the Deflagration Pressure Analysis Code (DPAC), and effective deposit properties calculated from the component properties. It was shown that a solids fire could only be ignited by a waste tank deflagration for a limited range of cases. For the best-estimate mixtures, a solids fire could not be ignited prior to the time the peak gas pressure is reached and would not increase the peak pressure. For the upper-bound mixtures, the thickness of the solid layer which could be ignited is insufficient to increase the energy released by the deflagration by a significant amount. It was also shown that these conclusions are relatively insensitive to uncertainties related to deposit composition. Thus, the contribution from a solids fire to the gas pressure resulting from a waste tank deflagration may be neglected

  10. SACALCCYL, Calculates the average solid angle subtended by a volume; SACALC2B, Calculates the average solid angle for source-detector geometries

    International Nuclear Information System (INIS)

    Whitcher, Ralph

    2007-01-01

    1 - Description of program or function: SACALC2B calculates the average solid angle subtended by a rectangular or circular detector window to a coaxial or non-coaxial rectangular, circular or point source, including where the source and detector planes are not parallel. SACALC C YL calculates the average solid angle subtended by a cylinder to a rectangular or circular source, plane or thick, at any location and orientation. This is needed, for example, in calculating the intrinsic gamma efficiency of a detector such as a GM tube. The program also calculates the number of hits on the cylinder side and on each end, and the average path length through the detector volume (assuming no scattering or absorption). Point sources can be modelled by using a circular source of zero radius. NEA-1688/03: Documentation has been updated (January 2006). 2 - Methods: The program uses a Monte Carlo method to calculate average solid angle for source-detector geometries that are difficult to analyse by analytical methods. The values of solid angle are calculated to accuracies of typically better than 0.1%. The calculated values from the Monte Carlo method agree closely with those produced by polygon approximation and numerical integration by Gardner and Verghese, and others. 3 - Restrictions on the complexity of the problem: The program models a circular or rectangular detector in planes that are not necessarily coaxial, nor parallel. Point sources can be modelled by using a circular source of zero radius. The sources are assumed to be uniformly distributed. NEA-1688/04: In SACALC C YL, to avoid rounding errors, differences less than 1 E-12 are assumed to be zero

  11. Solid state radiation dosimetry

    International Nuclear Information System (INIS)

    Moran, P.R.

    1976-01-01

    Important recent developments provide accurate, sensitive, and reliable radiation measurements by using solid state radiation dosimetry methods. A review of the basic phenomena, devices, practical limitations, and categories of solid state methods is presented. The primary focus is upon the general physics underlying radiation measurements with solid state devices

  12. Solid discharge and landslide activity at basin scale

    Science.gov (United States)

    Ardizzone, F.; Guzzetti, F.; Iadanza, C.; Rossi, M.; Spizzichino, D.; Trigila, A.

    2012-04-01

    This work presents a preliminary analysis aimed at understanding the relationship between landslide sediment supply and sediment yield at basin scale in central and southern Italy. A database of solid discharge measurements regarding 116 gauging stations, located along the Apennines chain in Italy, has been compiled by investigating the catalogues, named Annali Idrologici, published by Servizio Idrografico e Mareografico Italiano in the period from 1917 to 1997. The database records several information about the 116 gauging stations, and especially reports the sediment yield monthly measurements (103 ton) and the catchments area (km2). These data have been used to calculate the average solid yield and the normalized solid yield for each station in the observation period. The Italian Landslide Inventory (Progetto IFFI) has been used to obtained the size of the landslides, in order to estimate the landslide mobilization rates. The IFFI Project funded by the Italian Government is realized by ISPRA (Italian National Institute for Environmental Protection and Research - Geological Survey of Italy) in partnership with the 21 Regions and Self Governing Provinces. 21 of the 116 gauging stations and the related catchments have been selected on the basis of the length of the solid discharge observation period and excluding the catchments with dams located upstream the stations. The landslides inside the selected catchments have been extracted from the IFFI inventory, calculating the planimetric area of each landslide. Considering both the shallow and deep landslides, the landslide volume has been estimated using an empirical power law relation (landslide area vs. volume). The total landslide volume in the study areas and the average sediment yield measured at the gauging stations have been compared, analysing the behaviour of the basins which drainage towards the Tyrrhenian sea and the basins which drainage towards the Adriatic sea.

  13. Solid radiation curable polyene compositions containing liquid polythiols and solid styrene-allyl copolymer based polyenes

    International Nuclear Information System (INIS)

    Morgan, C.R.

    1977-01-01

    Novel styrene-allyl alcohol copolymer based solid polyene compositions which when mixed with liquid polythiols can form solid curable polyene-polythiol systems are claimed. These solid polyenes, containing at least two reactive carbon-to-carbon unsaturated bonds, are urethane or ester derivatives of styrene-allyl alcohol copolymers. The solid polyenes are prepared by treating the hydroxyl groups of a styrene-allyl alcohol copolymer with a reactive unsaturated isocyanate, e.g., allyl isocyanate or a reactive unsaturated carboxylic acid, e.g., acrylic acid. Upon exposure to a free radical generator, e.g., actinic radiation, the solid polyene-polythiol compositions cure to solid, insoluble, chemically resistant, cross-linked polythioether products. Since the solid polyene-liquid polythiol composition can be cured in a solid state, such a curable system finds particular use in preparation of coatings, imaged surfaces such as photoresists, particularly solder-resistant photoresists, printing plates, etc

  14. Report: new guidelines for characterization of municipal solid waste: the Portuguese case.

    Science.gov (United States)

    da Graça Madeira Martinho, Maria; Silveira, Ana Isabel; Fernandes Duarte Branco, Elsa Maria

    2008-10-01

    This report proposes a new set of guidelines for the characterization of municipal solid waste. It is based on an analysis of reference methodologies, used internationally, and a case study of Valorsul (a company that handles recovery and treatment of solid waste in the North Lisbon Metropolitan Area). In particular, the suggested guidelines present a new definition of the waste to be analysed, change the sampling unit and establish statistical standards for the results obtained. In these new guidelines, the sampling level is the waste collection vehicle and contamination and moisture are taken into consideration. Finally, focus is on the quality of the resulting data, which is essential for comparability of data between countries. These new guidelines may also be applicable outside Portugal because the methodology includes, besides municipal mixed waste, separately collected fractions of municipal waste. They are a response to the need for information concerning Portugal (e.g. Eurostat or OECD inquiries) and follow European Union municipal solid waste management policies (e.g. packaging waste recovery and recycling targets and the reduction of biodegradable waste going to landfill).

  15. Solid-Solid Vacuum Regolith Heat-Exchanger for Oxygen Production, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — This SBIR Phase-1 project will demonstrate the feasibility of using a novel coaxial counterflow solid-solid heat exchanger to recover heat energy from spent regolith...

  16. Association between tumor-stroma ratio and prognosis in solid tumor patients: a systematic review and meta-analysis.

    Science.gov (United States)

    Wu, Jiayuan; Liang, Caixia; Chen, Manyu; Su, Wenmei

    2016-10-18

    Tumor-related stroma plays an active role in tumor invasion and metastasis. The tumor-stroma ratio (TSR) in the pathologic specimen has drawn increasing attention from the field of predicting tumor prognosis. However, the prognostic value of TSR in solid tumors necessitates further elucidation. We conducted a meta-analysis on 14 studies with 4238 patients through a comprehensive electronic search on databases updated on May 2016 to explore the relationship between TSR and prognosis of solid tumors. The overall hazard ratio showed that rich stroma in tumor tissue was associated with poor overall survival (OS) (14 studies, 4238 patients) and disease-free survival (DFS) (9 studies, 2235 patients) of patients with solid tumors. The effect of low TSR on poor OS was observed among various cancer types, but not in the early stage of cervical caner. A significant relationship between low TSR and poor OS was also observed in the subgroup analyses based on study region, blinding status, and Newcastle-Ottawa Scale (NOS) score. Subgroup analyses indicated that cancer type, clinical stage, study region, blinding status, and NOS score did not affect the prognostic value of TSR for DFS. Moreover, low TSR was significantly correlated with the serious clinical stage, advanced depth of invasion, and positive lymph node metastasis. These findings indicate that a high proportion of stroma in cancer tissue is associated with poor clinical outcomes in cancer patients, and TSR may serve as an independent prognostic factor for solid tumors.

  17. Renewable energy source from pyrolysis of solid wastes

    International Nuclear Information System (INIS)

    Md Kawser Jamil; Farid Nasir Ani

    2000-01-01

    Malaysia is blessed with a significant renewable energy resource base such as solar energy and biomass. To continue with its industrial development, Malaysia must manages energy supply its c prudently in order to avoid becoming an energy importer supply. Most significantly renewable energy from biomass such as rice husks, wood wastes, oil palm wastes, rubber wastes and other agricultural wastes. Beside rice and timber. Malaysia produces a huge amount of palm oil and natural rubber. These generate a significant amount of solid wastes in the forms of oil palm shell and rubber. These wastes are producing pollution and emission problems in Malaysia which is causing an environmental issue. Besides energy is not recovered efficiently from these waste resources. From the elemental composition and thermogravimetric studies of the wastes, it appeared that the wastes could be used as an alternative value-added source of energy. For this purpose a fast pyrolysis of 300 mi-n lone, and 50 mm diameter stainless-steel reactor was designed and fabricated. The grounded, sieved and dried solid feed particles underwent pyrolysis reactor at moderate temperature and were converted into pyrolytic oil, solid char and cas. Oil and char were collected while the cas was flared. The oil was characterised by GC-MS technique. Detailed analysis of the oil showed that there was no concentration of biologically active polycyclic aromatic species in the oil. The fuel properties of the derived oils were also analysed and compared to diesel fuel. (Author)

  18. When a relationship is imperative, will young women knowingly place their sexual health at risk? A sample of African American adolescent girls in the juvenile justice system.

    Science.gov (United States)

    Raiford, Jerris L; Seth, Puja; Fasula, Amy M; DiClemente, Ralph J

    2017-08-01

    HIV and other sexually transmissible infections (HIV/STIs) are significant contributors to adolescent girls' morbidity in the US. Risks for HIV/STIs are increased among adolescent girls involved in the juvenile justice system, and African American adolescent girls comprise nearly 50% of adolescent girls in detention centres. Although HIV prevention programs focus on HIV/STI knowledge, increased knowledge may not be sufficient to reduce sexual risk. The present study examined the interactive effects of HIV/STI knowledge and the importance of being in a relationship (a relationship imperative) on sexual risk behaviours in a sample of detained African American adolescent girls. In all, 188 African American adolescent girls, 13-17 years of age, were recruited from a short-term detention facility in Atlanta, Georgia, and completed assessments on sexual risk behaviours, relationship characteristics, HIV/STI knowledge and several psychosocial risk factors. When girls endorsed a relationship imperative, higher HIV/STI knowledge was associated with low partner communication self-efficacy, inconsistent condom use and unprotected sex, when controlling for demographics and self-esteem. Young girls with high HIV/STI knowledge may have placed themselves at risk for HIV/STIs given the importance and value they place on being in a relationship. Contextual factors should be considered when developing interventions.

  19. Management of solid waste

    Science.gov (United States)

    Thompson, W. T.; Stinton, L. H.

    1980-04-01

    Compliance with the latest regulatory requirements addressing disposal of radioactive, hazardous, and sanitary solid waste criteria in the selection, design, and operation of solid waste management facilities. Due to the state of flux of these regulatory requirements from EPA and NRC, several waste management options were of solid waste. The current regulatory constraints and the design and operational requirements for construction of both storage and disposal facilities for use in management of DOE-ORO solid waste are highlighted. Capital operational costs are included for both disposal and storage options.

  20. Management of solid wastes

    Energy Technology Data Exchange (ETDEWEB)

    Williams, D.J. [University of Queensland, St. Lucia, Qld. (Australia). Dept. of Civil Engineering

    1996-12-31

    This chapter introduces the range of solid waste materials produced in the mining and mineral processing industries, with particular reference to Australia. The waste materials are characterised and their important geotechnical engineering properties are discussed. Disposal management techniques for metalliferous, coal, heavy mineral sand, fly ash and bauxite solid wastes are described. Geo-technical techniques for the management of potential contaminants are presented. Minimisation and utilisation of solid wastes, and the economics of solid waste management, are discussed from the perspectives of policy, planning, costing and rehabilitation. 19 figs., 2 tabs.

  1. Analysis of the organic matter which are present in solid organic wastes from urban areas

    International Nuclear Information System (INIS)

    Canellas, Luciano Pasqualoto; Santos, Gabriel de Araujo; Amarai Sobrinho, Nelson Moura Brasil do; Mazur, Nelson; Moraes, Anselmo Alpande

    1997-01-01

    This study analyses the organic matter which are present in the solid wastes from the Rio de Janeiro city - Brazil. The humic acids were extracted and purified. After the purification, the humic acids were dried by lyophilization. Visible UV, infrared and NMR spectra were obtained for the humic acids extracted

  2. Some structural characteristics of gamma-irradiated pure and Li2O-doped NiO solids

    International Nuclear Information System (INIS)

    Ramadan, A.A.; Dessouki, A.M.

    1989-01-01

    The induced structural changes, due to Li 2 O-doping (2.5 mol%) and γ-irradiation (10-80 Mrad), of NiO were investigated by XRD analyses. The results obtained revealed that lithium-doping resulted in a significant increase in the internal strain and a decrease in lattice parameter. These changes were explained in terms of creation of Ni 3+ ions in the doped solids. γ-Irradiation of pure and doped solids effected a decrease in both crystallite size and microstrain upon subjecting to doses of 20 and 30 Mrad. Higher doses induced an increase in both parameters in the case of pure NiO and a further decrease in case of the doped solid. These results were attributed to splitting of the large strained crystallites and to an activated sintering of the small strained ones. γ-Irradiation effected also an increase in the lattice parameters of pure and doped solids due to removal of some excess oxygen with subsequent decrease in the concentration of Ni 3+ ions. (author)

  3. Solids Accumulation Scouting Studies

    Energy Technology Data Exchange (ETDEWEB)

    Duignan, M. R.; Steeper, T. J.; Steimke, J. L.

    2012-09-26

    The objective of Solids Accumulation activities was to perform scaled testing to understand the behavior of remaining solids in a Double Shell Tank (DST), specifically AW-105, at Hanford during multiple fill, mix, and transfer operations. It is important to know if fissionable materials can concentrate when waste is transferred from staging tanks prior to feeding waste treatment plants. Specifically, there is a concern that large, dense particles containing plutonium could accumulate in poorly mixed regions of a blend tank heel for tanks that employ mixing jet pumps. At the request of the DOE Hanford Tank Operations Contractor, Washington River Protection Solutions, the Engineering Development Laboratory of the Savannah River National Laboratory performed a scouting study in a 1/22-scale model of a waste staging tank to investigate this concern and to develop measurement techniques that could be applied in a more extensive study at a larger scale. Simulated waste tank solids: Gibbsite, Zirconia, Sand, and Stainless Steel, with stainless steel particles representing the heavier particles, e.g., plutonium, and supernatant were charged to the test tank and rotating liquid jets were used to mix most of the solids while the simulant was pumped out. Subsequently, the volume and shape of the mounds of residual solids and the spatial concentration profiles for the surrogate for heavier particles were measured. Several techniques were developed and equipment designed to accomplish the measurements needed and they included: 1. Magnetic particle separator to remove simulant stainless steel solids. A device was designed and built to capture these solids, which represent the heavier solids during a waste transfer from a staging tank. 2. Photographic equipment to determine the volume of the solids mounds. The mounds were photographed as they were exposed at different tank waste levels to develop a composite of topographical areas. 3. Laser rangefinders to determine the volume of

  4. Dynamic analysis of solid propellant grains subjected to ignition pressurization loading

    Science.gov (United States)

    Chyuan, Shiang-Woei

    2003-11-01

    Traditionally, the transient analysis of solid propellant grains subjected to ignition pressurization loading was not considered, and quasi-elastic-static analysis was widely adopted for structural integrity because the analytical task gets simplified. But it does not mean that the dynamic effect is not useful and could be neglected arbitrarily, and this effect usually plays a very important role for some critical design. In order to simulate the dynamic response for solid rocket motor, a transient finite element model, accompanied by concepts of time-temperature shift principle, reduced integration and thermorheologically simple material assumption, was used. For studying the dynamic response, diverse ignition pressurization loading cases were used and investigated in the present paper. Results show that the dynamic effect is important for structural integrity of solid propellant grains under ignition pressurization loading. Comparing the effective stress of transient analysis and of quasi-elastic-static analysis, one can see that there is an obvious difference between them because of the dynamic effect. From the work of quasi-elastic-static and transient analyses, the dynamic analysis highlighted several areas of interest and a more accurate and reasonable result could be obtained for the engineer.

  5. Heat-Assisted Multiferroic Solid-State Memory.

    Science.gov (United States)

    Lepadatu, Serban; Vopson, Melvin M

    2017-08-25

    A heat-assisted multiferroic solid-state memory design is proposed and analysed, based on a PbNbZrSnTiO₃ antiferroelectric layer and Ni 81 Fe 19 magnetic free layer. Information is stored as magnetisation direction in the free layer of a magnetic tunnel junction element. The bit writing process is contactless and relies on triggering thermally activated magnetisation switching of the free layer towards a strain-induced anisotropy easy axis. A stress is generated using the antiferroelectric layer by voltage-induced antiferroelectric to ferroelectric phase change, and this is transmitted to the magnetic free layer by strain-mediated coupling. The thermally activated strain-induced magnetisation switching is analysed here using a three-dimensional, temperature-dependent magnetisation dynamics model, based on simultaneous evaluation of the stochastic Landau-Lifshitz-Bloch equation and heat flow equation, together with stochastic thermal fields and magnetoelastic contributions. The magnetisation switching probability is calculated as a function of stress magnitude and maximum heat pulse temperature. An operating region is identified, where magnetisation switching always occurs, with stress values ranging from 80 to 180 MPa, and maximum temperatures normalised to the Curie temperature ranging from 0.65 to 0.99.

  6. Problem drug use the public health imperative: what some of the literature says.

    Science.gov (United States)

    Bevan, Gez

    2009-12-16

    With more than 200,000 problem drug users is contact with structured treatment services in England the public health imperative behind drug treatment is great. Problem drug use for many is a chronic and relapsing condition, where "cure" is often neither a reasonable or appropriate expectation and it can further be argued that in these circumstances problem drug use is no different from any number of chronic and enduring health conditions that are managed in the health care system and therefore should be conceptualised as such. A public health approach to drug treatment emphasises the need for drug users in or accessing treatment, to reduce their harmful drug use, reduce drug use related risks such as sepsis and overdose and stay alive for longer. However a public health perspective in relation to problem drug use isn't always either apparent or readily understood and to that end there is still a significant need to continue the arguments and debate that treatment and interventions for problem and dependent drug users need to extend beyond an individualistic approach. For the purposes of discussion in this article public and population health will be used interchangeably. A recognition and acceptance that a public and population health approach to the management of problem drug users is sound public health policy also then requires a long term commitment in terms of staffing and resources where service delivery mirrors that of chronic condition management.

  7. A critical compilation and review of default soil solid/liquid partition coefficients, Kd, for use in environmental assessments

    International Nuclear Information System (INIS)

    Thibault, D.H.; Sheppard, M.I.; Smith, P.A.

    1990-03-01

    Environmental assessments of the Canadian concept for disposal of nuclear fuel waste in plutonic rock formations require analyses of the migration of nuclides from the disposal vault to the biosphere. Analyses of nuclide migration via groundwater through the geosphere, unconsolidated overburden and soil use models requiring solid/liquid partition coefficients (K d ) to describe the interaction of the nuclides with the solid materials. This report presents element-specific soil solid/liquid partition coefficients based on a detailed survey of the literature. Values for clays, silt, sand and organic soils are summarized. Partition coefficients for the following elements are presented: americium, antimony, arsenic, barium, boron, cadmium, calcium, carbon, cerium, cesium, chromium, cobalt, copper, curium, europium, iodine, iron, lead, lithium, manganese, molybdenum, neptunium, nickel, niobium, palladium, phosphorus, plutonium, polonium, radium, ruthenium, samarium, selenium, silver, strontium, technetium, tellurium, terbium, thorium, tin, tritium, uranium, zinc, and zirconium. The values compiled in this study are compared with earlier K d value compendiums and are the values recommended for the use in the soil, deep sediment and overburden models for the Environmental Impact Statement on the concept for disposal of Canada's nuclear fuel waste

  8. Projecting future solid waste management requirements on the Hanford Site

    International Nuclear Information System (INIS)

    Shaver, S.R.; Stiles, D.L.; Holter, G.M.; Anderson, B.C.

    1990-09-01

    The problem of treating and disposing of hazardous transuranic (TRU), low-level radioactive, and mixed waste has become a major concern of the public and the government. At the US Department of Energy's Hanford Site in Washington state, the problem is compounded by the need to characterize, retrieve, and treat the solid waste that was generated and stored for retrieval during the past 20 years. This paper discusses the development and application of a Solid Waste Projection Model that uses forecast volumes and characteristics of existing and future solid waste to address the treatment, storage, and disposal requirements at Hanford. The model uses a data-driven, object-oriented approach to assess the storage and treatment throughout requirements for each operation for each of the distinct waste classes and the accompanying cost of the storage and treatment operations. By defining the elements of each alternative for the total waste management system, the same database can be used for numerous analyses performed at different levels of detail. This approach also helps a variety of users with widely varying information requirements to use the model and helps achieve the high degree of flexibility needed to cope with changing regulations and evolving treatment and disposal technologies. 2 figs

  9. Modal Survey of ETM-3, A 5-Segment Derivative of the Space Shuttle Solid Rocket Booster

    Science.gov (United States)

    Nielsen, D.; Townsend, J.; Kappus, K.; Driskill, T.; Torres, I.; Parks, R.

    2005-01-01

    The complex interactions between internal motor generated pressure oscillations and motor structural vibration modes associated with the static test configuration of a Reusable Solid Rocket Motor have potential to generate significant dynamic thrust loads in the 5-segment configuration (Engineering Test Motor 3). Finite element model load predictions for worst-case conditions were generated based on extrapolation of a previously correlated 4-segment motor model. A modal survey was performed on the largest rocket motor to date, Engineering Test Motor #3 (ETM-3), to provide data for finite element model correlation and validation of model generated design loads. The modal survey preparation included pretest analyses to determine an efficient analysis set selection using the Effective Independence Method and test simulations to assure critical test stand component loads did not exceed design limits. Historical Reusable Solid Rocket Motor modal testing, ETM-3 test analysis model development and pre-test loads analyses, as well as test execution, and a comparison of results to pre-test predictions are discussed.

  10. FORCED HAPPINESS AS A MODERN SOCIO AND CULTURAL IMPERATIVE

    Directory of Open Access Journals (Sweden)

    H. V. Khodus

    2015-12-01

    Full Text Available Purpose. In this article is an attempt to "read" cultural code of the phenomenon of happiness in actual social circumstances. The research was primarily focused on the specifics of the contemporary cultural situation, which determines the emotional infrastructure of individuals’ life. Methodology. The number of concepts that were proposed by M. Foucault, N. Elias, in particular – «configurationally balance of power», «culture of yourself», «take care of yourself», «practice of yourself», "the discourse of power/knowledge" are proposed as a heuristic resource that allows to comprehend the transit of value-semantic codes of the happiness phenomenon. Such analytical optics enable reading of contemporary social reality as a discursive space that permeated with visual aestheticization of various emotions, legitimized with knowledge/power. This disciplinary discourse not only codifies the "correct" expression of emotions, but also culturally encodes the hierarchy of these "correct" emotions. Scientific novelty. It is proved that a characteristic feature of current modernity (available in Ukrainian realities is the change in happiness status, its transformation into "normative" emotion that individuals should feel and show. In other words, the cult of happiness becomes dominant cultural imperative, a duty, acting as a moral duty. It is argued that "the forced happiness" is a social effect of the therapeutic culture, which streamlines the emotional life of the individual, interpersonal relationships, scenarios of success and happiness. The key role of cultural mediators, commercial narratives (Internet, media in the design and promotion of the ideology of "forced happiness" is justified. Conclusions. The proposed research approach allows deconstructing the emotional regime of modernity in the aspect of problematization the phenomenon of happiness. The idea is that the right to happiness, to private pleasure and self-care are the basic ideas

  11. Comparison of spray drying, electroblowing and electrospinning for preparation of Eudragit E and itraconazole solid dispersions.

    Science.gov (United States)

    Sóti, Péter Lajos; Bocz, Katalin; Pataki, Hajnalka; Eke, Zsuzsanna; Farkas, Attila; Verreck, Geert; Kiss, Éva; Fekete, Pál; Vigh, Tamás; Wagner, István; Nagy, Zsombor K; Marosi, György

    2015-10-15

    Three solvent based methods: spray drying (SD), electrospinning (ES) and air-assisted electrospinning (electroblowing; EB) were used to prepare solid dispersions of itraconazole and Eudragit E. Samples with the same API/polymer ratios were prepared in order to make the three technologies comparable. The structure and morphology of solid dispersions were identified by scanning electron microscopy and solid phase analytical methods such as, X-ray powder diffraction (XRPD), differential scanning calorimetry (DSC) and Raman chemical mapping. Moreover, the residual organic solvents of the solid products were determined by static headspace-gas chromatography/mass spectroscopy measurements and the wettability of samples was characterized by contact angle measurement. The pharmaceutical performance of the three dispersion type, evaluated by dissolution tests, proved to be very similar. According to XRPD and DSC analyses, made after the production, all the solid dispersions were free of any API crystal clusters but about 10 wt% drug crystallinity was observed after three months of storage in the case of the SD samples in contrast to the samples produced by ES and EB in which the polymer matrix preserved the API in amorphous state. Copyright © 2015 Elsevier B.V. All rights reserved.

  12. Vibrational properties of complex solids

    International Nuclear Information System (INIS)

    Fagas, G.

    1999-11-01

    Following a brief outline of the statistical analysis of spectra with respect to random matrix theory predictions and of numerical methods for calculating the elastic scattering matrix, statistical studies of vibrational spectra in disordered and complex solids, as well as studies of phonon transport across imperfect structures, are presented. The analysis of spectral statistics of lattice modes in a disordered crystal, confirmed GOE Wigner-Dyson statistical correlations of the eigenmode frequencies of a block of a disordered solid. Spectral correlations in the optic phonon spectrum of a solid with a polyatomic unit cell are also analysed using the Wigner-Dyson statistical approach. Despite the fact that all force constants are real, it is demonstrated that the statistics are predominantly of the GUE type depending on the location within the Brillouin zone of a crystal and the unit cell symmetry. Analytic and numerical results for the crossover from GOE to GUE statistics are presented. A method originally developed to probe electron transport on a mesoscopic scale is used to study generic properties of elastic phonon transport at a disordered interface. The results show that phonon transmittance is a strong function of frequency and the disorder correlation length. At low frequencies the transmittance at a given frequency increases as the correlation length decreases. This is also reflected by different power-laws for phonon conductance across correlated and uncorrelated disordered interfaces which are in approximate agreement with perturbation theory of an elastic continuum. Finally we present an analysis of acoustic-phonon propagation across long, free-standing, insulating wires with rough surfaces. We find that owing to a crossover from ballistic propagation of the lowest-frequency phonon mode at ω 1 πc/W to a diffusive (or even localized) behavior upon the increase of phonon frequency, followed by reentrance into the quasiballistic regime, the heat

  13. Solubility and dissolution performances of spray-dried solid dispersion of Efavirenz in Soluplus.

    Science.gov (United States)

    Lavra, Zênia Maria Maciel; Pereira de Santana, Davi; Ré, Maria Inês

    2017-01-01

    Efavirenz (EFV), a first-line anti-HIV drug largely used as part of antiretroviral therapies, is practically insoluble in water and belongs to BCS class II (low solubility/high permeability). The aim of this study was to improve the solubility and dissolution performances of EFV by formulating an amorphous solid dispersion of the drug in polyvinyl caprolactam-polyvinyl acetate-polyethylene glycol graft copolymer (Soluplus ® ) using spray-drying technique. To this purpose, spray-dried dispersions of EFV in Soluplus ® at different mass ratios (1:1.25, 1:7, 1:10) were prepared and characterized using particle size measurements, SEM, XRD, DSC, FTIR and Raman microscopy mapping. Solubility and dissolution were determined in different media. Stability was studied at accelerated conditions (40 °C/75% RH) and ambient conditions for 12 months. DSC and XRD analyses confirmed the EFV amorphous state. FTIR spectroscopy analyses revealed possible drug-polymer molecular interaction. Solubility and dissolution rate of EFV was enhanced remarkably in the developed spray-dried solid dispersions, as a function of the polymer concentration. Spray-drying was concluded to be a proper technique to formulate a physically stable dispersion of amorphous EFV in Soluplus ® , when protected from moisture.

  14. Numerical study of the influence of solid polarization on electrophoresis at finite Debye thickness.

    Science.gov (United States)

    Bhattacharyya, Somnath; De, Simanta

    2015-09-01

    The influence of solid polarization on the electrophoresis of a uniformly charged dielectric particle for finite values of the particle-to-fluid dielectric permittivity ratio is analyzed quantitatively without imposing the thin Debye length or weak-field assumption. Present analysis is based on the computation of the coupled Poisson-Nernst-Planck and Stokes equations in the fluid domain along with the Laplace equation within the solid. The electrophoretic velocity is determined through the balance of forces acting on the particle. The solid polarization of the charged particle produces a reduction on its electrophoretic velocity compared to a nonpolarizable particle of the same surface charge density. In accordance with the existing thin-layer analysis, our computed results for thin Debye layer shows that the solid polarization is important only when the applied electric field is strong. When the Debye length is in the order of the particle size, the electrophoretic velocity decreases with the rise of the particle permittivity and attains a saturation limit at large values of the permittivity. Our computed solution for electrophoretic velocity is in agreement with the existing asymptotic analyses based on a thin Debye layer for limiting cases.

  15. Solid-solid phase transitions in Fe nanowires induced by axial strain

    International Nuclear Information System (INIS)

    Sandoval, Luis; Urbassek, Herbert M

    2009-01-01

    By means of classical molecular-dynamics simulations we investigate the solid-solid phase transition from a bcc to a close-packed crystal structure in cylindrical iron nanowires, induced by axial strain. The interatomic potential employed has been shown to be capable of describing the martensite-austenite phase transition in iron. We study the stress versus strain curves for different temperatures and show that for a range of temperatures it is possible to induce a solid-solid phase transition by axial strain before the elasticity is lost; these transition temperatures are below the bulk transition temperature. The two phases have different (non-linear) elastic behavior: the bcc phase softens, while the close-packed phase stiffens with temperature. We also consider the reversibility of the transformation in the elastic regimes, and the role of the strain rate on the critical strain necessary for phase transition.

  16. Photoemission from solids: the transition from solid-state to atomic physics

    International Nuclear Information System (INIS)

    Shirley, D.A.

    1980-08-01

    As the photon energy is increased, photoemission from solids undergoes a slow transition from solid-state to atomic behavior. However, throughout the energy range hν = 10 to 1000 eV or higher both types of phenomena are present. Thus angle-resolved photoemission can only be understood quantitatively if each experimenter recognizes the presence of band-structure, photoelectron diffraction, and photoelectron asymmetry effects. The quest for this understanding will build some interesting bridges between solid-state and atomic physics and should also yield important new insights about the phenomena associated with photoemission

  17. Applied structural and solid mechanics section: 1983 review and 1984 programs

    International Nuclear Information System (INIS)

    Chadha, J.A.

    1984-01-01

    This report reviews briefly the applied research and problem solving work carried out by the Applied Structural and Solid Mechanics Section during 1983. In 1983 there was a strong demand for services in the areas of theroretical and experimental stress analysis, heat transfer analysis, nonlinear analysis, and general structural analyses related to nuclear and thermal power plant, and transmission line components. Development of capabilities in these areas progressed well. Proposed work programs for 1984 are outlined in this report

  18. A review of the features and analyses of the solid electrolyte interphase in Li-ion batteries

    International Nuclear Information System (INIS)

    Verma, Pallavi; Maire, Pascal; Novak, Petr

    2010-01-01

    The solid electrolyte interphase (SEI) is a protecting layer formed on the negative electrode of Li-ion batteries as a result of electrolyte decomposition, mainly during the first cycle. Battery performance, irreversible charge 'loss', rate capability, cyclability, exfoliation of graphite and safety are highly dependent on the quality of the SEI. Therefore, understanding the actual nature and composition of SEI is of prime interest. If the chemistry of the SEI formation and the manner in which each component affects battery performance are understood, SEI could be tuned to improve battery performance. In this paper key points related to the nature, formation, and features of the SEI formed on carbon negative electrodes are discussed. SEI has been analyzed by various analytical techniques amongst which FTIR and XPS are most widely used. FTIR and XPS data of SEI and its components as published by many research groups are compiled in tables for getting a global picture of what is known about the SEI. This article shall serve as a handy reference as well as a starting point for research related to SEI.

  19. Feasibility of using acoustic velocity meters for estimating highly organic suspended-solids concentrations in streams

    Science.gov (United States)

    Patino, Eduardo

    1996-01-01

    A field experiment was conducted at the Levee 4 canal site below control structure G-88 in the Everglades agricultural area in northwestern Broward County, Florida, to study the relation of acoustic attenuation to suspended-solids concentrations. Acoustic velocity meter and temperature data were obtained with concurrent water samples analyzed for suspended-solids concentrations. Two separate acoustic velocity meter frequencies were used, 200 and 500 kilohertz, to determine the sensitivity of acoustic attenuation to frequency for the measured suspended-solids concentration range. Suspended-solids concentrations for water samples collected at the Levee 4 canal site from July 1993 to September 1994 ranged from 22 to 1,058 milligrams per liter, and organic content ranged from about 30 to 93 percent. Regression analyses showed that attenuation data from the acoustic velocity meter (automatic gain control) and temperature data alone do not provide enough information to adequately describe the concentrations of suspended solids. However, if velocity is also included as one of the independent variables in the regression model, a satisfactory correlation can be obtained. Thus, it is feasible to use acoustic velocity meter instrumentation to estimate suspended-solids concentrations in streams, even when suspended solids are primarily composed of organic material. Using the most comprehensive data set available for the study (500 kiloherz data), the best fit regression model produces a standard error of 69.7 milligrams per liter, with actual errors ranging from 2 to 128 milligrams per liter. Both acoustic velocity meter transmission frequencies of 200 and 500 hilohertz produced similar results, suggesting that transducers of either frequency could be used to collect attenuation data at the study site. Results indicate that calibration will be required for each acoustic velocity meter system to the unique suspended-solids regime existing at each site. More robust solutions may

  20. On the intersection of phonetic detail and the organization of interaction: clinical connections.

    Science.gov (United States)

    Walker, Gareth; Local, John

    2013-01-01

    The analysis of language use in real-world contexts poses particular methodological challenges. We codify responses to these challenges as a series of methodological imperatives. To demonstrate the relevance of these imperatives to clinical investigation, we present analyses of single episodes of interaction where one participant has a speech and/or language impairment: atypical prosody, echolalia and dysarthria. We demonstrate there is considerable heuristic and analytic value in taking this approach to analysing the organization of interaction involving individuals with a speech and/or language impairment.

  1. Ceramic solid electrolytes

    Energy Technology Data Exchange (ETDEWEB)

    Goodenough, John B. [Center for Materials Science and Engineering, University of Texas at Austin, Austin, TX (United States)

    1997-02-15

    Strategies for the design of ceramic solid electrolytes are reviewed. Problems associated with stoichiometric and doped compounds are compared. In the illustration of design principles, emphasis is given to oxide-ion electrolytes for use in solid-oxide fuel cells, oxygen pumps, and oxygen sensors

  2. Time-dependent post-imperative negative variation indicates adaptation and problem solving in migraine patients.

    Science.gov (United States)

    Kropp, Peter; Brecht, Ines-Beatrice; Niederberger, Uwe; Kowalski, Jens; Schröder, Dietmar; Thome, Johannes; Meyer, Wolfgang; Wallasch, Thomas-Martin; Hilgendorf, Inken; Gerber, Wolf-Dieter

    2012-10-01

    According to the Seligman theory of learned helplessness, depression is caused by a repetitive experience of loss of control resulting in internal, stable and global attributional styles for negative events. In depressed patients and healthy controls experiencing such events, an increased amplitude of the post-imperative negative variation (PINV) has been described. The aim of the study was to investigate a possible correlation between migraine, depression, learned helplessness and PINV. 24 patients suffering from migraine without aura and 24 healthy controls were exposed to a situation of loss of control whilst the contingent negative variation (CNV) from C3, C4 and Cz were recorded. Before conducting the experiment, the subjects were asked to answer the Beck Depression Inventory (BDI) and the German attributional style questionnaire (GASQ). Amplitudes of total CNV, early and late component and PINV were calculated in eight blocks of four recordings each. The results confirm findings of a pronounced PINV in situations of loss of control, though high amplitudes were not correlated with low values in the GASQ and therefore with learned helplessness. High PINV in migraine patients correlated with high scores in the BDI and the list of the complaints questionnaire. However, this was not the case in healthy controls. In this experimental situation, PINV in migraine patients can be interpreted as an expectancy potential in order to avoid failure and helplessness.

  3. Radiological analyses of solids in the area of the old uranium mine of Rosglas (Morbihan)

    International Nuclear Information System (INIS)

    2008-07-01

    After a brief presentation of the different uranium sites previously exploited in Brittany, this document reports measurements performed on one of them, the old uranium mine of Rosglas. In situ radiation measurements and sampling (surface soil, rocks, and sediments) were performed. Samples were then analysed (gamma radiation measurements) in order to asses the contamination by Uranium 238 and 235. The authors outline that some radioactive wastes are still accessible and therefore expose public to health risks. They discuss how to take these risks into account and discuss the required restructuring works to be done

  4. Numerical research on the neutronic/thermal-hydraulic/mechanical coupling characteristics of the optimized helium cooled solid breeder blanket for CFETR

    International Nuclear Information System (INIS)

    Cui, Shijie; Zhang, Dalin; Cheng, Jie; Tian, Wenxi; Su, G.H.

    2017-01-01

    As one of the candidate tritium breeding blankets for Chinese Fusion Engineering Test Reactor (CFETR), a conceptual structure of the helium cooled solid breeder blanket has recently been proposed. The neutronic, thermal-hydraulic and mechanical characteristics of the blanket directly affect its tritium breeding and safety performance. Therefore, neutronic/thermal-hydraulic/mechanical coupling analyses are of vital importance for a reliable blanket design. In this work, first, three-dimensional neutronics analysis and optimization of the typical outboard equatorial blanket module (No. 12) were performed for the comprehensive optimal scheme. Then, thermal and fluid dynamic analyses of the scheme under both normal and critical conditions were performed and coupled with the previous neutronic calculation results. With thermal-hydraulic boundaries, thermo-mechanical analyses of the structure materials under normal, critical and blanket over-pressurization conditions were carried out. In addition, several parametric sensitivity studies were also conducted to investigate the influences of the main parameters on the blanket temperature distributions. In this paper, the coupled analyses verify the reasonability of the optimized conceptual design preliminarily and can provide an important reference for the further analysis and optimization design of the CFETR helium cooled solid breeder blanket.

  5. Numerical research on the neutronic/thermal-hydraulic/mechanical coupling characteristics of the optimized helium cooled solid breeder blanket for CFETR

    Energy Technology Data Exchange (ETDEWEB)

    Cui, Shijie; Zhang, Dalin, E-mail: dlzhang@mail.xjtu.edu.cn; Cheng, Jie; Tian, Wenxi; Su, G.H.

    2017-01-15

    As one of the candidate tritium breeding blankets for Chinese Fusion Engineering Test Reactor (CFETR), a conceptual structure of the helium cooled solid breeder blanket has recently been proposed. The neutronic, thermal-hydraulic and mechanical characteristics of the blanket directly affect its tritium breeding and safety performance. Therefore, neutronic/thermal-hydraulic/mechanical coupling analyses are of vital importance for a reliable blanket design. In this work, first, three-dimensional neutronics analysis and optimization of the typical outboard equatorial blanket module (No. 12) were performed for the comprehensive optimal scheme. Then, thermal and fluid dynamic analyses of the scheme under both normal and critical conditions were performed and coupled with the previous neutronic calculation results. With thermal-hydraulic boundaries, thermo-mechanical analyses of the structure materials under normal, critical and blanket over-pressurization conditions were carried out. In addition, several parametric sensitivity studies were also conducted to investigate the influences of the main parameters on the blanket temperature distributions. In this paper, the coupled analyses verify the reasonability of the optimized conceptual design preliminarily and can provide an important reference for the further analysis and optimization design of the CFETR helium cooled solid breeder blanket.

  6. Holistic Assessment and Ethical Disputation on a New Trend in Solid Biofuels.

    Science.gov (United States)

    Hašková, Simona

    2017-04-01

    A new trend in the production technology of solid biof uels has appeared. There is a wide consensus that most solid biofuels will be produced according to the new production methods within a few years. Numerous samples were manufactured from agro-residues according to conventional methods as well as new methods. Robust analyses that reviewed the hygienic, environmental, financial and ethical aspects were performed. The hygienic and environmental aspect was assessed by robust chemical and technical analyses. The financial aspect was assessed by energy cost breakdown. The ethical point of view was built on the above stated findings, the survey questionnaire and critical discussion with the literature. It is concluded that the new production methods are significantly favourable from both the hygienic and environmental points of view. Financial indicators do not allow the expressing of any preference. Regarding the ethical aspect, it is concluded that the new methods are beneficial in terms of environmental responsibility. However, it showed that most of the customers that took part in the survey are price oriented and therefore they tend to prefer the cheaper-conventional alternative. In the long term it can be assumed that expansion of the new technology and competition among manufacturers will reduce the costs.

  7. Effect of solid-meal caloric content on gastric emptying kinetics of solids and liquids.

    Science.gov (United States)

    Urbain, J L; Siegel, J A; Mortelmans, L; van Cutsem, E; van den Maegdenbergh, V; de Roo, M

    1989-08-01

    In this study, we have evaluated the effect of the caloric content of a physiological test meal on the gastric emptying kinetics of solids and liquids. 22 healthy male volunteers were studied in two groups matched for age. After an overnight fast, each volunteer underwent the same test procedure; in the first group (G I), 10 volunteers received a meal consisting of bread, 111In-DTPA water and 1 scrambled egg labeled with 99mTc-labelled sulphur colloid; in the second group (G II) 12 volunteers were given the same meal but with 2 labeled eggs in order to increase the caloric content of the solid phase meal. Simultaneous anterior and posterior images were recorded using a dual-headed gamma camera. Solid and liquid geometric mean data were analyzed to determine the lag phase, the emptying rate and the half-emptying time for both solids and liquids. Solid and liquid gastric half-emptying times were significantly prolonged in G II compared to G I volunteers. For the solid phased, the delay was accounted for by a longer lag phase and a decrease in the equilibrium emptying rate. The emptying rate of the liquid phase was significantly decreased in G II compared to G I. Within each group, no statistically significant difference was observed between solid and liquid emptying rates. We conclude that the caloric content of the solid portion of a meal not only alters the emptying of the solid phase but also affects the emptying of the liquid component of the meal.

  8. Effect of solid-meal caloric content on gastric emptying kinetics of solids and liquids

    International Nuclear Information System (INIS)

    Urbain, J.L.; Mortelmans, L.; Cutsem, E. van; Maegdenbergh, V. van den; Roo, M. de

    1989-01-01

    In this study, we have evaluated the effect of the caloric content of a physiological test meal on the gastric emptying kinetics of solids and liquids. 22 healthy male volunteers were studied in two groups matched for age. After an overnight fast, each volunteer underwent the same test procedure; in the first group (G I), 10 volunteers received a meal consisting of bread, 111 In-DTPA water and 1 scrambled egg labeled with 99m Tc-labelled sulphur colloid; in the second group (G II) 12 volunteers were given the same meal but with 2 labeled eggs in order to increase the caloric content of the solid phase meal. Simultaneous anterior and posterior images were recorded using a dual-headed gamma camera. Solid and liquid geometric mean data were analyzed to determine the lag phase, the emptying rate and the half-emptying time for both solids and liquids. Solid and liquid gastric half-emptying times were significantly prolonged in G II compared to G I volunteers. For the solid phased, the delay was accounted for by a longer lag phase and a decrease in the equilibrium emptying rate. The emptying rate of the liquid phase was significantly decreased in G II compared to G I. Within each group, no statistically significant difference was observed between solid and liquid emptying rates. We conclude that the caloric content of the solid portion of a meal not only alters the emptying of the solid phase but also affects the emptying of the liquid component of the meal. (orig.) [de

  9. Biodegradation of low-density polyethylene (LDPE) by isolated fungi in solid waste medium

    International Nuclear Information System (INIS)

    Zahra, Sahebnazar; Abbas, Shojaosadati Seyed; Mahsa, Mohammad-Taheri; Mohsen, Nosrati

    2010-01-01

    In this study, biodegradation of low-density polyethylene (LDPE) by isolated landfill-source fungi was evaluated in a controlled solid waste medium. The fungi, including Aspergillus fumigatus, Aspergillus terreus and Fusarium solani, were isolated from samples taken from an aerobic aged municipal landfill in Tehran. These fungi could degrade LDPE via the formation of a biofilm in a submerged medium. In the sterilized solid waste medium, LPDE films were buried for 100 days in a 1-L flask containing 400 g sterile solid waste raw materials at 28 deg. C. Each fungus was added to a separate flask. The moisture content and pH of the media were maintained at the optimal levels for each fungus. Photo-oxidation (25 days under UV-irradiation) was used as a pretreatment of the LDPE samples. The progress of the process was monitored by measurement of total organic carbon (TOC), pH, temperature and moisture. The results obtained from monitoring the process using isolated fungi under sterile conditions indicate that these fungi are able to grow in solid waste medium. The results of FT-IR and SEM analyses show that A. terreus and A. fumigatus, despite the availability of other organic carbon of materials, could utilize LDPE as carbon source. While there has been much research in the field of LDPE biodegradation under solid conditions, this is the first report of degradation of LDPE by A. fumigatus.

  10. Magnetically Enhanced Solid-Liquid Separation

    Science.gov (United States)

    Rey, C. M.; Keller, K.; Fuchs, B.

    2005-07-01

    DuPont is developing an entirely new method of solid-liquid filtration involving the use of magnetic fields and magnetic field gradients. The new hybrid process, entitled Magnetically Enhanced Solid-Liquid Separation (MESLS), is designed to improve the de-watering kinetics and reduce the residual moisture content of solid particulates mechanically separated from liquid slurries. Gravitation, pressure, temperature, centrifugation, and fluid dynamics have dictated traditional solid-liquid separation for the past 50 years. The introduction of an external field (i.e. the magnetic field) offers the promise to manipulate particle behavior in an entirely new manner, which leads to increased process efficiency. Traditional solid-liquid separation typically consists of two primary steps. The first is a mechanical step in which the solid particulate is separated from the liquid using e.g. gas pressure through a filter membrane, centrifugation, etc. The second step is a thermal drying process, which is required due to imperfect mechanical separation. The thermal drying process is over 100-200 times less energy efficient than the mechanical step. Since enormous volumes of materials are processed each year, more efficient mechanical solid-liquid separations can be leveraged into dramatic reductions in overall energy consumption by reducing downstream drying requirements have a tremendous impact on energy consumption. Using DuPont's MESLS process, initial test results showed four very important effects of the magnetic field on the solid-liquid filtration process: 1) reduction of the time to reach gas breakthrough, 2) less loss of solid into the filtrate, 3) reduction of the (solids) residual moisture content, and 4) acceleration of the de-watering kinetics. These test results and their potential impact on future commercial solid-liquid filtration is discussed. New applications can be found in mining, chemical and bioprocesses.

  11. Applied mechanics of solids

    CERN Document Server

    Bower, Allan F

    2009-01-01

    Modern computer simulations make stress analysis easy. As they continue to replace classical mathematical methods of analysis, these software programs require users to have a solid understanding of the fundamental principles on which they are based. Develop Intuitive Ability to Identify and Avoid Physically Meaningless Predictions Applied Mechanics of Solids is a powerful tool for understanding how to take advantage of these revolutionary computer advances in the field of solid mechanics. Beginning with a description of the physical and mathematical laws that govern deformation in solids, the text presents modern constitutive equations, as well as analytical and computational methods of stress analysis and fracture mechanics. It also addresses the nonlinear theory of deformable rods, membranes, plates, and shells, and solutions to important boundary and initial value problems in solid mechanics. The author uses the step-by-step manner of a blackboard lecture to explain problem solving methods, often providing...

  12. Multivalent ion conducting solids

    Energy Technology Data Exchange (ETDEWEB)

    Imanaka, N. [Osaka Univ., Suita, Osaka (Japan). Dept. of Applied Chemistry

    2008-07-01

    Solid electrolytes possess important characteristics for industrial applications. Only a single ionic species can macroscopically migrate in these solids. This paper described a the new NASICON (M-Zr-Nb-P-O) type system, exhibiting an exceptionally high level of trivalent M3+ ion conductivity on polycrystalline solids. The partial substitution of the smaller higher valent Nb5+ ion for Zr4+ stabilized the NASICON phase and realized the M3+ ion conduction in the NASICON structure. It was concluded that the conductivities of the series are comparable to those of the practically applied solid electrolytes of oxide anion conductors of YSZ and CSZ. 3 refs., 2 figs.

  13. Utilisation of solid waste

    Energy Technology Data Exchange (ETDEWEB)

    Balu, K

    1978-07-01

    The prime solution to the present energy crisis is the recovery of latent energy from waste materials, for solid waste contains recoverable energy and it merely needs to be released. The paper is concerned with classification of solid waste, energy content of waste, methods of solid waste disposal, and chemical processing of solid waste. Waste disposal must be performed in situ with energy recovery. Scarcity of available land, pollution problem, and unrecovered latent energy restrict the use of the land-filling method. Pyrolysis is an effective method for the energy recovery and disposal problems. Chemical processing is suitable for the separated cellulosic fraction of the waste material.

  14. Management of solid waste

    International Nuclear Information System (INIS)

    Thompson, W.T.; Stinton, L.H.

    1980-01-01

    Compliance with the latest regulatory requirements addressing disposal of radioactive, hazardous, and sanitary solid waste requires the application of numerous qualitative and quantitative criteria in the selection, design, and operation of solid waste management facilities. Due to the state of flux of these regulatory requirements from EPA and NRC, several waste management options were identified as being applicable to the management of the various types of solid waste. This paper highlights the current regulatory constraints and the design and operational requirements for construction of both storage and disposal facilities for use in management of DOE-ORO solid waste. Capital and operational costs are included for both disposal and storage options

  15. Management of solid waste

    International Nuclear Information System (INIS)

    Thompson, W.T.; Stinton, L.H.

    1980-01-01

    Compliance with the latest regulatory requirements addressing disposal of radioactive, hazardous, and sanitary solid waste requires the application of numerous qualitative and quantitative criteria in the selection, design, and operation of solid waste management facilities. Due to the state of flux of these regulatory requirements from EPA and NRC several waste management options were identified as being applicable to the management of the various types of solid waste. This paper highlights the current regulatory constraints and the design and operational requirements for construction of both storage and disposal facilities for use in management of DOE-ORO solid waste. Capital and operational costs are included for both disposal and storage options

  16. Understanding solid state physics

    CERN Document Server

    Holgate, Sharon Ann

    2009-01-01

    Where Sharon Ann Holgate has succeeded in this book is in packing it with examples of the application of solid state physics to technology. … All the basic elements of solid state physics are covered … . The range of materials is good, including as it does polymers and glasses as well as crystalline solids. In general, the style makes for easy reading. … Overall this book succeeds in showing the relevance of solid state physics to the modern world … .-Contemporary Physics, Vol. 52, No. 2, 2011I was indeed amused and inspired by the wonderful images throughout the book, carefully selected by th

  17. Electric conductivity of solid solutions of the Na3-2xMxPO4 (M=Cd, Pb) systems

    International Nuclear Information System (INIS)

    Shekhtman, G.Sh.; Burmakin, E.I.; Smirnov, N.B.; Esina, N.O.

    2002-01-01

    Electric conductivity, phase composition and conductivity character in the system Na 3-2x Cd x PO 4 in the temperature range of 300-750 deg C were studied by the methods of conductometry, X-ray phase and thermal analyses. It was ascertained that maximum values of electric conductivity (6.25x10 -3 S/cm at 300 deg C) are observed near upper concentration boundaries (x ≅ 0.4) of monophase regions in γ-solid solutions. Conductivity of the solid electrolytes studied is of cocationic character. The values of activation energies of Na + and Cd 2+ cation jumping over in solid electrolytes Na 2.7 Cd 0.15 PO 4 are 38.7 and 43.6 kJ/mol respectively according to the NMR data [ru

  18. Solid state multinuclear NMR. A versatile tool for studying the reactivity of solid systems

    Energy Technology Data Exchange (ETDEWEB)

    MacKenzie, Kenneth J.D. [MacDiarmid Institute for Advanced Materials and Nanotechnology, Victoria University of Wellington, P.O. Box 600, Wellington (New Zealand)

    2004-08-31

    Traditionally, X-ray powder diffraction has been a favoured method for studying chemical reactions in the solid state, but the increasing importance of energy-efficient synthesis methods for solids (e.g. sol-gel synthesis, mechanochemical synthesis) has led to the need for an analytical method not dependent on long-range structural periodicity. Multinuclear solid state nuclear magnetic resonance (NMR) represents a technique which is equally applicable to amorphous or crystalline solids, and is now used in increasing numbers of solid state studies.This paper briefly outlines the principles and practical details of this powerful technique and gives examples of its use in solid-state chemistry, particularly in very recent studies of mechanochemical synthesis of advanced sialon ceramics. The temperature at which these technically important silicon aluminium oxynitride compounds are formed can be significantly lowered by high-energy grinding of their components to produce X-ray amorphous precursors. Solid-state NMR has been used to provide detailed information which could not have been obtained by any other means about the chemical environment of the Si and Al atoms in these amorphous precursors, and the various atomic movements undergone as they crystallise to the final product.

  19. Solid state NMR study of cumbaru flour

    International Nuclear Information System (INIS)

    Nogueira, Jose S.; Bathista, Andre L.B.S.; Silva, Emerson O.; Priante Filho, Nicolau; Tavares, Maria I.B.

    2001-01-01

    The polysaccharide obtained by seed of Dipteryx alata Vog, has been characterised by 13 C solid state, using the basic routine techniques, like MAS and CPMAS and by the proton spin-lattice relaxation time in the rotating frame parameter (T 1 H ρ). Knowing that the chemical structure and molecular dynamic are extremely necessary route to obtain information on the polysaccharides, this work contributes to the classification of the seed containing in the cumbaru fruit to get response on its application. To obtain the initial responses for our purposes some solid state NMR techniques were chosen. The CPMAS 13 C NMR spectrum of the polysaccharide was investigated to know if it has some crystallinity. The MAS 13 C NMR spectrum showed the presence of domains with distinct molecular mobility, because these domains will differ basically in the distribution size and chain packing. The variable contact time experiment was used to analyse the distribution form of 13 C decays, which give us more information about sample heterogeneity. The T 1 H ρHr values were obtained from the variable contact time and by delayed contact time experiment, because these parameter indicate the order of polysaccharides. From the values of this parameter, we found that this polysaccharide is completely non-ordered. (author)

  20. Use of reference samples for more accurate RBS analyses

    International Nuclear Information System (INIS)

    Lanford, W.A.; Pelicon, P.; Zorko, B.; Budnar, M.

    2002-01-01

    While one of the primary assets of RBS analysis is that it is quantitative without use of reference samples, for certain types of analyses the precision of the method can be improved by measuring RBS spectra of unknowns relative to the RBS spectra of a similar known sample. The advantage of such an approach is that one can reduce (or eliminate) the uncertainties that arise from error in the detector solid angle, beam current integration efficiency, scattering cross-section, and stopping powers. We have used this approach extensively to determine the composition (x) of homogeneous thin films of TaN x using as reference samples films of pure Ta. Our approach is to measure R=(Ta count) unknown /(Ta count) standard and use RUMP to determine the function x(R). Once the function x(R) has been determined, this approach makes it easy to analyze many samples quickly. Other analyses for which this approach has proved useful are determination of the composition (x) of WN x , SiO x H y and SiN x H y , using W, SiO 2 and amorphous Si as reference samples, respectively

  1. Solid Modeling and Finite Element Analysis of an Overhead Crane Bridge

    Directory of Open Access Journals (Sweden)

    C. Alkin

    2005-01-01

    Full Text Available The design of an overhead crane bridge with a double box girder has been investigated and a case study of a crane with 35 ton capacity and 13 m span length has been conducted. In the initial phase of the case study, conventional design calculations proposed by F. E. M. Rules and DIN standards were performed to verify the stress and deflection levels. The crane design was modeled using both solids and surfaces. Finite element meshes with 4-node tetrahedral and 4-node quadrilateral shell elements were generated from the solid and shell models, respectively. After a comparison of the finite element analyses, the conventional calculations and performance of the existing crane, the analysis with quadratic shell elements was found to give the most realistic results. As a result of this study, a design optimization method for an overhead crane is proposed. 

  2. Categorical Imperative Immanuel Kant sebagai Landasan Filosofis Pelaksanaan Putusan Arbitrase

    Directory of Open Access Journals (Sweden)

    Djunyanto Thriyana

    2016-04-01

    application in practice for the settlement of a dispute. Moral norm is a norm which can be a guide. One philosophical concept that is based on moral comes from Immanuel Kant. Kant introduced the concept of 'categorical imperative' or obligations that should unconditionally be owned by humans as sentient in achieving harmony with other humans, under the law of freedom based on universal principles. This concept should be deemed as suitable to be the cornerstone for the philosophy in the settlement of disputes through arbitration.

  3. Implementation of Solid Waste Policies in Pernambuco: a study from the institutional theory and interorganizational networks

    Directory of Open Access Journals (Sweden)

    Maria Luciana de Almeida

    2015-09-01

    Full Text Available Solid waste is a problem in the Brazilian context, not only because it is growing in larger proportions than the population and leading to soil and water contamination, but also because it is a vector for diseases and causes economic losses, since much of what is discarded can be reused. After several years of intense debate, the Brazilian law applying to national solid waste policy was sanctioned; this law contains goals to be achieved and challenges to be overcome. Since this is a major issue, the purpose of this paper is to discuss the implementation of public policies on solid waste, emphasizing the initiatives carried out in the state of Pernambuco, from the perspectives of institutional theory and inter-organizational networks. By analysing the provisions of the law, we can observe a coercive tendency to bring the states and municipalities to establish networks in order to meet demands related to solid waste, since the pertinent legislation induces the involved entities to develop this kind of partnership in order to obtain resources

  4. Solid waste management in Malaysia

    International Nuclear Information System (INIS)

    Nadzri Yahaya

    2010-01-01

    All of the countries over the world have their own policies about how waste were managed. Malaysia as one of the developing country also faces this problems. So, the government was established Department of National Solid Waste Management under Ministry of Housing and Local Government to control and make sure all of these problem on waste will managed systematically. Guiding principle on these issues was mentioned in 3rd Outline Perspective Plan (2000 until 2010), National Policy on Solid Waste Management, National Strategic Plan on Solid Waste Management and also 10th Malaysian Plan. In 10th Malaysian Plan, the government will complete restructuring efforts in this Solid Waste Management sector with the federalization of solid waste management and public cleansing and full enforcement of the Solid Waste and Public Cleansing Management Act 2007. The key outcomes of these efforts will include providing support to local authorities, delivering comprehensive and sanitary services and ensuring that waste is managed in a sustainable manner. These presentations cover all aspect of solid waste management in Malaysia. What are guiding principle, paradigm shift, strategies approach, monitoring and enforcement and also mention about some issues and constraint that appear in Solid waste management in Malaysia.

  5. The Deductions of Freedom/Morality-as-Autonomy and the Categorical Imperative in Groundwork III and Their Problems

    Directory of Open Access Journals (Sweden)

    Fernando Rudy Hiller

    2015-12-01

    Full Text Available The first objective of this paper is to present an interpretation of Groundwork III which aims to establish two main points: first, that Kant offers there a theoretically-grounded deduction (in Kantian sense of freedom/morality-as-autonomy; second, that Kant also offers a separate deduction of the categorical imperative. Thus, contrary to what several commentators have claimed, Groundwork III contains a theoretically-grounded double deduction. The second objective of the paper is to examine and criticize in detail one crucial step in these deductions, namely, Kant’s inference from the speculative spontaneity of reason to the noumenal existence of the subject as a free will. I show that Kant himself came to reject this inference in the B edition of the Critique of Pure Reason, and argue that this explains Kant’s rejection, in the Critique of Practical Reason, of the deduction of the moral law he previously offered. Thus, contrary to the “reconciliationist” reading, there is indeed a great reversal in the latter work.

  6. Sewage Solids Irradiator Transportation System (SSITS) cask: preliminary design description

    International Nuclear Information System (INIS)

    Eakes, R.G.; Kempka, S.N.; Lamoreaux, G.H.; Sutherland, S.H.

    1983-02-01

    The preliminary design of the Sewage Solids Irradiator Transportation System (SSITS) Cask is presented in this document. The SSITS cask is to be used for the transport of radioactive cesium chloride and strontium fluoride capsules which are of use in irradiators or as heat sources. The SSITS cask is approximately 1.4 m in diameter, 1.3 m high, weighs roughly 9 t, provides 33 cm of steel shielding, and can dissipate up to 5.2 kW of decay heat. The cask design criteria are identified and a description of the cask design and operation is provided. Detailed analyses of the design were performed to demonstrate licensability of the cask by the Nuclear Regulatory Commission (NRC). Results of the analyses indicate that the preliminary design is in compliance with the pertinent regulatory requirements for licensing of a radioactive material transportation container

  7. Direct determination of enthalpies of solid phase reactions by immersion method; Determination directe des enthalpies de reaction en phase solide par une methode de plongee

    Energy Technology Data Exchange (ETDEWEB)

    Roux, A; Richard, M; Eyraud, L; Stevanovic, M; Elston, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1967-07-01

    It is not generally possible to measure the enthalpy change corresponding to solid phase reactions using the dynamic differential thermal analysis method because these reactions are usually too slow at the temperature of operation of present equipment. A ballistic differential thermal analysis apparatus has been developed which is based on an immersion-compensation method; it overcomes the difficulties previously encountered. This apparatus has been used after calibration for determining the enthalpies of formation of calcium and cadmium titanates. and also the Wigner energies of BeO, MgO and Al{sub 2}O{sub 3} samples irradiated at variable dose at a temperature of under 100 deg. C. (authors) [French] Il n'est generalement pas possible de mesurer la variation d'enthalpie correspondant aux reactions en phase solide par la methode d'analyse thermique differentielle dynamique. En effet, ces reactions sont le plus souvent trop lentes aux temperatures d'utilisation des dispositifs actuels. Un appareil d'analyse thermique differentielle balistique, base sur une methode de plongee avec compensation, a ete mis au point et permet de surmonter les difficultes precedentes. Apres etalonnages, cet appareil a ete utilise pour la determination des enthalpies de formation du titanate de calcium et du titanate de cadmium ainsi que pour celle des energies Wigner emmagasinees dans des echantillons de BeO, MgO et Al{sub 2}O{sub 3} irradies a une temperature inferieure a 100 deg. C et a differentes doses. (auteurs)

  8. Non-drainage scleral buckling with solid silicone elements

    Directory of Open Access Journals (Sweden)

    Pukhraj Rishi

    2014-01-01

    Full Text Available Background: With the increasing number of cataract surgeries, incidence of posterior segment complications including rhegmatogenous retinal detachment (RRD is likely to rise. Scleral buckling (SB surgery is an effective and less expensive option. The primary advantage of non-drainage procedure is avoidance of possible complications associated with trans-choroidal drainage. The aim of present study is to describe the clinical profile of subjects undergoing non-drainage SB surgery with solid silicone elements for RRD and analyze their treatment outcomes. Materials and Methods: This was a retrospective, non-randomized, interventional study at a tertiary care center. Three hundred and six eyes of 298 patients undergoing non-drainage SB surgery with solid silicone elements from year 2000 to 2006 were included. Inclusion criteria were primary RRD, peripheral depressible retinal break, media clarity affording peripheral retinal view and proliferative vitreo-retinopathy (PVR up to grade C2. Uni- and multivariate analyses was done to analyze factors affecting anatomical and visual outcomes. Statistical analysis was performed using SPSS Version 10. Results: Mean follow-up was 303 ± 393.33 days. Primary anatomical success was obtained in 279 (91.2% eyes; primary functional success in 286 (93.5% eyes. PVR (grade B or C, intraocular pressure <10 mm Hg and the inability to find a retinal break were significantly associated with final anatomical failure. Baseline vision ≤3/60 was significantly associated with poor visual recovery. Conclusions: SB surgery is reasonably safe and highly efficacious. Solid silicone elements are effective in non-drainage SB surgery. However, case selection is important.

  9. Data summary of municipal solid waste management alternatives

    Energy Technology Data Exchange (ETDEWEB)

    1992-10-01

    This appendix on Mass Burn Technologies is the first in a series designed to identify, describe and assess the suitability of several currently or potentially available generic technologies for the management of municipal solid waste (MSW). These appendices, which cover eight core thermoconversion, bioconversion and recycling technologies, reflect public domain information gathered from many sources. Representative sources include: professional journal articles, conference proceedings, selected municipality solid waste management plans and subscription technology data bases. The information presented is intended to serve as background information that will facilitate the preparation of the technoeconomic and life cycle mass, energy and environmental analyses that are being developed for each of the technologies. Mass burn has been and continues to be the predominant technology in Europe for the management of MSW. In the United States, the majority of the existing waste-to-energy projects utilize this technology and nearly 90 percent of all currently planned facilities have selected mass burn systems. Mass burning generally refers to the direct feeding and combustion of municipal solid waste in a furnace without any significant waste preprocessing. The only materials typically removed from the waste stream prior to combustion are large bulky objects and potentially hazardous or undesirable wastes. The technology has evolved over the last 100 or so years from simple incineration to the most highly developed and commercially proven process available for both reducing the volume of MSW and for recovering energy in the forms of steam and electricity. In general, mass burn plants are considered to operate reliably with high availability.

  10. Theoretical solid state physics

    International Nuclear Information System (INIS)

    Anon.

    1977-01-01

    Research activities at ORNL in theoretical solid state physics are described. Topics covered include: surface studies; particle-solid interactions; electronic and magnetic properties; and lattice dynamics

  11. Ion beam modification of solids ion-solid interaction and radiation damage

    CERN Document Server

    Wesch, Werner

    2016-01-01

    This book presents the method of ion beam modification of solids in realization, theory and applications in a comprehensive way. It provides a review of the physical basics of ion-solid interaction and on ion-beam induced structural modifications of solids. Ion beams are widely used to modify the physical properties of materials. A complete theory of ion stopping in matter and the calculation of the energy loss due to nuclear and electronic interactions are presented including the effect of ion channeling. To explain structural modifications due to high electronic excitations, different concepts are presented with special emphasis on the thermal spike model. Furthermore, general concepts of damage evolution as a function of ion mass, ion fluence, ion flux and temperature are described in detail and their limits and applicability are discussed. The effect of nuclear and electronic energy loss on structural modifications of solids such as damage formation, phase transitions and amorphization is reviewed for ins...

  12. Solid-solid phase change thermal storage application to space-suit battery pack

    Science.gov (United States)

    Son, Chang H.; Morehouse, Jeffrey H.

    1989-01-01

    High cell temperatures are seen as the primary safety problem in the Li-BCX space battery. The exothermic heat from the chemical reactions could raise the temperature of the lithium electrode above the melting temperature. Also, high temperature causes the cell efficiency to decrease. Solid-solid phase-change materials were used as a thermal storage medium to lower this battery cell temperature by utilizing their phase-change (latent heat storage) characteristics. Solid-solid phase-change materials focused on in this study are neopentyl glycol and pentaglycerine. Because of their favorable phase-change characteristics, these materials appear appropriate for space-suit battery pack use. The results of testing various materials are reported as thermophysical property values, and the space-suit battery operating temperature is discussed in terms of these property results.

  13. Solid waste management: an overview

    International Nuclear Information System (INIS)

    Ayoub, G.M.

    1995-01-01

    The source, effect and characterization of solid wastes are discussed. Constituents of municipal solid wastes and a comparative compositions of municipal solid waste with some data on Lebanon are given. Collection, transport and processing practices are next introduced. Finally treatment and disposal techniques are presented with emphasis on the solid waste as energy source and as material source. Methods of recycling are evaluated in respect with their environmental impact. 7 refs. 2 tabs

  14. A new compact solid-state neutral particle analyser at ASDEX Upgrade: Setup and physics modeling

    Energy Technology Data Exchange (ETDEWEB)

    Schneider, P. A.; Blank, H.; Geiger, B.; Mank, K.; Martinov, S.; Ryter, F.; Weiland, M.; Weller, A. [Max-Planck-Institut für Plasmaphysik, Garching (Germany)

    2015-07-15

    At ASDEX Upgrade (AUG), a new compact solid-state detector has been installed to measure the energy spectrum of fast neutrals based on the principle described by Shinohara et al. [Rev. Sci. Instrum. 75, 3640 (2004)]. The diagnostic relies on the usual charge exchange of supra-thermal fast-ions with neutrals in the plasma. Therefore, the measured energy spectra directly correspond to those of confined fast-ions with a pitch angle defined by the line of sight of the detector. Experiments in AUG showed the good signal to noise characteristics of the detector. It is energy calibrated and can measure energies of 40-200 keV with count rates of up to 140 kcps. The detector has an active view on one of the heating beams. The heating beam increases the neutral density locally; thereby, information about the central fast-ion velocity distribution is obtained. The measured fluxes are modeled with a newly developed module for the 3D Monte Carlo code F90FIDASIM [Geiger et al., Plasma Phys. Controlled Fusion 53, 65010 (2011)]. The modeling allows to distinguish between the active (beam) and passive contributions to the signal. Thereby, the birth profile of the measured fast neutrals can be reconstructed. This model reproduces the measured energy spectra with good accuracy when the passive contribution is taken into account.

  15. Results of Characterization and Retrieval Testing on Tank 241-C-110 Heel Solids

    Energy Technology Data Exchange (ETDEWEB)

    Callaway, William S.

    2013-09-30

    Nine samples of heel solids from tank 241-C-110 were delivered to the 222-S Laboratory for characterization and dissolution testing. After being drained thoroughly, the sample solids were primarily white to light-brown with minor dark-colored inclusions. The maximum dimension of the majority of the solids was <2 mm; however, numerous pieces of aggregate, microcrystalline, and crystalline solids with maximum dimensions ranging from 5-70 mm were observed. In general, the larger pieces of aggregate solids were strongly cemented. Natrophosphate [Na{sub 7}F(PO{sub 4}){sub 2}°19H{sub 2}O] was the dominant solid phase identified in the heel solids. Results of chemical analyses suggested that 85-87 wt% of the heel solids were the fluoridephosphate double salt. The average bulk density measured for the heel solids was 1.689 g/mL; the reference density of natrophosphate is 1.71 g/mL. Dissolution tests on composite samples indicate that 94 to 97 wt% of the tank 241-C-110 heel solids can be retrieved by dissolution in water. Dissolution and recovery of the soluble components in 1 kg (0.59 L) of the heel solids required the addition of ≈9.5 kg (9.5 L) of water at 15 °C and ≈4.4 kg (4.45 L) of water at 45 °C. Calculations performed using the Environmental Simulation Program indicate that dissolution of the ≈0.86 kg of natrophosphate in each kilogram of the tank 241-C-110 heel solids would require ≈9.45 kg of water at 15 °C and ≈4.25 kg of water at 45 °C. The slightly larger quantities of water determined to be required to retrieve the soluble components in 1 kg of the heel solids are consistent with that required for the dissolution of solids composed mainly of natrophosphate with a major portion of the balance consisting of highly soluble sodium salts. At least 98% of the structural water, soluble phosphate, sodium, fluoride, nitrate, carbonate, nitrite, sulfate, oxalate, and chloride in the test composites was dissolved and recovered in the

  16. Pacific Northwest Laboratory's Solid Waste Initiative

    International Nuclear Information System (INIS)

    Holter, G.M.

    1993-09-01

    In fiscal year 1992 (FY-92), a Solid Waste Initiative was undertaken within the Pacific Northwest Laboratory (PNL). This action was partly in response to a perceived increase in the frequency and severity of impacts associated with solid waste issues at all levels. It also recognized the limited attention of previous efforts in addressing the broader impacts resulting from solid waste and, thus, dealing with solid waste issues in a holistic fashion. This paper provides a description of the Solid Waste Initiative at PNL, including a historical perspective on PNL's involvement in solid waste issues, the goals and objectives of the Solid Waste Initiative, and a discussion of selected activities being conducted under the Initiative

  17. Analysis and evalution of selected future biofuel options on the basis of solid biomass; Analyse und Bewertung ausgewaehlter zukuenftiger Biokraftstoffoptionen auf der Basis fester Biomasse

    Energy Technology Data Exchange (ETDEWEB)

    Mueller-Langer, Franziska

    2011-12-13

    The aim of this work is starting from the investigation of the technical development prospects along the fuel delivery chain to develop a suitable reproducible tool for the analysis and evaluation of future biofuel policies and on selected fuel options from solid biomass (1. bioethanol by biochemical fermentation, 2. Fischer-Tropsch-Diesel by thermochemical gasification, and 3. Bio-Synthetic Natural Gas (Bio-SNG) by thermochemical gasification). For this it is necessary for these biofuels in accordance with the current technology state the essential perspectives for the practical implementation taking into account the short, medium and long term (e.g. time horizon for implementation in up to 5 years, in about 10 to 15 years, or about 20 to 25 years) to identify possible technical options. [German] Ziel dieser Arbeit ist es, ausgehend von der Untersuchung der technischen Entwicklungsperspektiven entlang der Kraftstoffbereitstellungskette ein geeignetes reproduzierbares Werkzeug fuer die Analyse und Bewertung zukuenftiger Biokraftstoffkonzepte zu entwickeln und auf ausgewaehlte Kraftstoffoptionen auf Basis fester Biomasse (hier Bioethanol ueber die biochemische Fermentation, Fischer-Tropsch-Diesel ueber die thermochemische Vergasung und Bio-Synthetic Natural Gas (Bio-SNG) ueber die thermochemische Vergasung) anzuwenden. Dazu gilt es fuer diese Biokraftstoffe unter Beachtung des aktuellen Technikstandes die wesentlichen Perspektiven fuer die praktische Umsetzung unter Beruecksichtigung der kurz-, mittel- bis langfristig (d.h. Zeithorizont fuer die Realisierung in bis zu 5 Jahren, in etwa 10 bis 15 Jahren bzw. in etwa 20 bis 25 Jahren) denkbaren technischen Moeglichkeiten zu identifizieren.

  18. Electron probe micro-analysis of gas bubbles in solids: a novel approach

    International Nuclear Information System (INIS)

    Verwerft, M.; Vos, B.

    1999-01-01

    The local analysis of retained noble gas in nuclear fuel is inherently difficult since the physical form under which it is stored varies from atomically dispersed to bubbles with a diameter of several hundreds of nanometers. One of the techniques that has been applied since pore than twenty years is EPMA. Although many important results have been obtained with this technique, its application to the analysis of highly inhomogeneous materials is limited. The EPMA technique is indeed difficult to apply to samples that are not homogeneous on the scale of the electron-solid interaction volume. The paper discusses the development of a method to analyse a system of as bubbles distributed in a solid matrix. This method has been based on a multiple voltage EPMA measurement combined with a scanning Electron Microscopic analysis of the bubble size distribution

  19. SEISMIC DISTRESS AND PROTECTION OF FLEXIBLE MEMBRANE LINERS OF SOLID WASTE LANDFILLS

    DEFF Research Database (Denmark)

    Zania, Varvara; Tsompanakis, Yiannis; Psarropoulos, Prodromos

    2011-01-01

    Seismic distress of solid waste landfills may result from any of the two consequences of a seismic event: (a) the transient ground deformation related to seismic wave propagation, (b) the permanent ground deformation caused by abrupt fault dislocation. Design provisions for solid waste landfills...... prohibit the construction of landfills in the vicinity of an active fault aiming to prevent the latter. Nonetheless, the impact of applied permanent deformation on the system components of landfills and on the waste mass has not been fully demonstrated yet. For this purpose, efficient finite......-element analyses were performed, taking also into account the potential slip displacement development along the interfaces formulated on each side of the flexible membrane liner (FML). It is shown that base fault dislocation causes significant plastic strains at each one of the components of the waste landfill...

  20. Density-functional theory for fluid-solid and solid-solid phase transitions.

    Science.gov (United States)

    Bharadwaj, Atul S; Singh, Yashwant

    2017-03-01

    We develop a theory to describe solid-solid phase transitions. The density functional formalism of classical statistical mechanics is used to find an exact expression for the difference in the grand thermodynamic potentials of the two coexisting phases. The expression involves both the symmetry conserving and the symmetry broken parts of the direct pair correlation function. The theory is used to calculate phase diagram of systems of soft spheres interacting via inverse power potentials u(r)=ε(σ/r)^{n}, where parameter n measures softness of the potential. We find that for 1/nfcc) structure while for 1/n≥0.154 the body-centred-cubic (bcc) structure is preferred. The bcc structure transforms into the fcc structure upon increasing the density. The calculated phase diagram is in good agreement with the one found from molecular simulations.

  1. On the use of semiempirical models of (solid + supercritical fluid) systems to determine solid sublimation properties

    International Nuclear Information System (INIS)

    Tabernero, Antonio; Martin del Valle, Eva M.; Galan, Miguel A.

    2011-01-01

    Research highlights: → We propose a method to determine sublimation properties of solids. → Low deviations were produced calculating sublimation enthalpies and pressures. → It is a required step to determine the vaporization enthalpy of the solid. → It is possible to determine solid properties using semiempirical models solid-SCF. - Abstract: Experimental solubility data of solid-supercritical fluids have significantly increased in the last few years, and semiempirical models are emerging as one of the best choices to fit this type of data. This work establishes a methodology to calculate sublimation pressures using this type of equations. It requires the use of Bartle's equation to model equilibria data solid-supercritical fluids with the aim of determining the vaporization enthalpy of the compound. Using this method, low deviations were obtained by calculating sublimation pressures and sublimation enthalpies. The values of the sublimation pressures were subsequently used to successfully model different multiphasic equilibria, as solid-supercritical fluids and solid-solvent-supercritical fluids with the Peng-Robinson equation of state (without considering the sublimation pressure as an adjustable parameter). On the other hand, the sublimation pressures were also used to calculate solid sublimation properties and acetaminophen solvation properties in some solvents. Also, solubility data solid-supercritical fluids from 62 pharmaceuticals were fitted with different semiempirical equations (Chrastil, Kumar-Johnston and Bartle models) in order to present the values of solvation enthalpies in sc-CO 2 and vaporization enthalpies for these compounds. All of these results highlight that semiempirical models can be used for any other purpose as well as modeling (solid + supercritical fluids) equilibria.

  2. Exploration of the Solar System's Ocean Worlds as a Scientific (and Societal) Imperative

    Science.gov (United States)

    Lunine, J. I.

    2017-12-01

    The extraordinary discoveries made by multiple planetary spacecraft in the past 20 years have changed planetary scientists' perception of various objects as potential abodes for life, in particular a newly-recognized class of solar system objects called ocean worlds: those bodies with globe-girdling liquids on their surfaces or in their interiors. A reasonably complete list would include 13 bodies, of which the Earth is one, with Mars and Ceres classified as bodies with evidence for past oceans. For three bodies on this list—Europa, Titan and Enceladus—there are multiple independent lines of evidence for subsurface salty liquid water oceans. Of these, Enceladus' ocean has been directly sampled through its persistent plume, and Titan possesses not only an internal ocean but surface seas and lakes of methane and other hydrocarbons. All three of these moons are candidates for hosting microbial life, although in the case of Titan much of the interest is in a putative biochemistry dramatically different from ours, that would work in liquid methane. The possibility that after a half century of planetary exploration we may finally know where to find alien life raises the issue of the priority of life detection missions. Do they supersede ambitious plans for Mars or for Cassini-like explorations of Uranus and Neptune? I consider three possible imperatives: the scientific (elimination of the N=1 problem from biology), the cultural (proper framing of our place in the cosmos) and the political (the value propositions for planetary exploration that we offer the taxpayers).

  3. Geological modeling of a stratified deposit with CAD-Based solid model automation

    Directory of Open Access Journals (Sweden)

    Ayten Eser

    Full Text Available Abstract The planning stages of mining activities require many comprehensive and detailed analyses. Determining the correct orebody model is the first stage and one of the most important. Three-dimensional solid modeling is one of the significant methods that can examine the position and shape of the ore deposit. Although there are many different types of mining software for determining a solid model, many users try to build geological models in the computer without knowing how these software packages work. As researchers on the subject, we wanted to answer the question "How would we do it". For this purpose, a system was developed for generating solid models using data obtained from boreholes. Obtaining this model in an AutoCAD environment will be important for geologists and engineers. Developed programs were first tested with virtual borehole data belonging to a virtual deposit. Then the real borehole data of a cement raw material site were successfully applied. This article allows readers not only to see a clear example of the programming approach to layered deposits but also to produce more complicated software in this context. Our study serves as a window to understanding the geological modeling process.

  4. Volume reduction technology development for solid wastes from the nuclear fuel cycle

    International Nuclear Information System (INIS)

    Oh, Won Zin; Lee, Kune Woo; Song, Kee Chan; Choi, Wang Kyu; Kim, Young Min

    1998-07-01

    A great deal of solid wastes, which have various physical, chemical, and radiological characteristics, are generated from the nuclear fuel cycle facility as well as radioactive gaseous and liquid wastes. The treatment of the large quantity of solid wastes from the nuclear fuel cycle have great technical, economical and social effects on the domestic policy decision on the nuclear fuel cycle, such as operation and maintenance of the facility, waste disposal, etc. Cement immobilization, super compaction, and electrochemical dissolution were selected as the volume reduction technologies for solid wastes, which will generated from the domestic nuclear fuel cycle facility in the future. And the assessment of annual arisings and the preliminary conceptual design of volume reduction processes were followed. Electrochemical decontamination of α-radionuclides from the spent fuel hulls were experimentally investigated, and showed the successful results. However, β/γ radioactivity did not reduce to the level below which hulls can be classified as the low-level radioactive waste and sent to the disposal site for the shallow land burial. The effects of the various process variables in the electrochemical decontamination were experimentally analysed on the process. (author). 32 refs., 32 tabs., 52 figs

  5. Solid state video cameras

    CERN Document Server

    Cristol, Y

    2013-01-01

    Solid State Video Cameras reviews the state of the art in the field of solid-state television cameras as compiled from patent literature. Organized into 10 chapters, the book begins with the basic array types of solid-state imagers and appropriate read-out circuits and methods. Documents relating to improvement of picture quality, such as spurious signal suppression, uniformity correction, or resolution enhancement, are also cited. The last part considerssolid-state color cameras.

  6. Agro-industrial waste to solid biofuel through hydrothermal carbonization.

    Science.gov (United States)

    Basso, Daniele; Patuzzi, Francesco; Castello, Daniele; Baratieri, Marco; Rada, Elena Cristina; Weiss-Hortala, Elsa; Fiori, Luca

    2016-01-01

    In this paper, the use of grape marc for energy purposes was investigated. Grape marc is a residual lignocellulosic by-product from the winery industry, which is present in every world region where vine-making is addressed. Among the others, hydrothermal carbonization was chosen as a promising alternative thermochemical process, suitable for the treatment of this high moisture substrate. Through a 50 mL experimental apparatus, hydrothermal carbonization tests were performed at several temperatures (namely: 180, 220 and 250 °C) and residence times (1, 3, 8 h). Analyses on both the solid and the gaseous phases obtained downstream of the process were performed. In particular, solid and gas yields versus the process operational conditions were studied and the obtained hydrochar was evaluated in terms of calorific value, elemental analysis, and thermal stability. Data testify that hydrochar form grape marc presents interesting values of HHV (in the range 19.8-24.1 MJ/kg) and physical-chemical characteristics which make hydrochar exploitable as a solid biofuel. In the meanwhile, the amount of gases produced is very small, if compared to other thermochemical processes. This represents an interesting result when considering environmental issues. Statistical analysis of data allows to affirm that, in the chosen range of operational conditions, the process is influenced more by temperature than residence time. These preliminary results support the option of upgrading grape marc toward its energetic valorisation through hydrothermal carbonization. Copyright © 2015 Elsevier Ltd. All rights reserved.

  7. Spectroscopic, thermogravimetric and structural characterization analyses for comparing Municipal Solid Waste composts and vermicomposts stability and maturity.

    Science.gov (United States)

    Soobhany, Nuhaa; Gunasee, Sanjana; Rago, Yogeshwari Pooja; Joyram, Hashita; Raghoo, Pravesh; Mohee, Romeela; Garg, Vinod Kumar

    2017-07-01

    This is the first-ever study of its kind for an extensive assessment and comparison of maturity indexes between compost and vermicompost that have been derived from Municipal Solid Waste (MSW). The spectroscopic (Fourier transform infrared spectroscopy: FT-IR), thermogravimetric analysis (TG), differential scanning calorimetry (DSC) and structural characterization (scanning electron microscope: SEM) were recorded. FT-IR spectra showed an increase in conversion of polysaccharides species and aliphatic methylene groups in vermicompost compared to compost as depicted from the variation of the intensity of the peaks. TG curves of final vermicompost showed a much lower mass loss when compared to compost, indicating higher stability in feedstock. SEM micrographs of the vermicompost reflected strong fragmentation of material than composts which revealed the extent of intra-structural degradation of MSW. These findings elucidate on a clear comparison between composts and vermicomposts in terms of maturity indexes for soil enhancement and in agriculture as organic fertilizer. Copyright © 2017 Elsevier Ltd. All rights reserved.

  8. Suspended solids in liquid effluents

    International Nuclear Information System (INIS)

    McGrath, J.J.

    1988-06-01

    An international literature review and telephone mail survey was conducted with respect to technical and regulatory aspects of suspended solids in radioactive liquid wastes from nuclear power stations. Results of the survey are summarized and show that suspended solids are an important component of some waste streams. The data available, while limited, show these solids to be associated largely with corrosion products. The solids are highly variable in quantity, size and composition. Filtration is commonly applied for their removal from liquid effluents and is effective. Complex interactions with receiving waters can result in physical/chemical changes of released radionuclides and these phenomena have been seen as reason for not applying regulatory controls based on suspended solids content. 340 refs

  9. Solid-state laser engineering

    CERN Document Server

    Koechner, Walter

    1999-01-01

    Solid-State Laser Engineering, written from an industrial perspective, discusses in detail the characteristics, design, construction, and performance of solid-state lasers. Emphasis is placed on engineering and practical considerations; phenomenological aspects using models are preferred to abstract mathematical derivations. This new edition has extensively been updated to account for recent developments in the areas of diode-laser pumping, laser materials, and nonlinear crystals. Walter Koechner received a doctorate in Electrical Engineering from the University of Technology in Vienna, Austria, in 1965. He has published numerous papers in the fields of solid-state physics, optics, and lasers. Dr. Koechner is founder and president of Fibertek, Inc., a research firm specializing in the design, development, and production of advanced solid-state lasers, optical radars, and remote-sensing systems.

  10. Determination of chiral pharmaceuticals and illicit drugs in wastewater and sludge using microwave assisted extraction, solid-phase extraction and chiral liquid chromatography coupled with tandem mass spectrometry.

    Science.gov (United States)

    Evans, Sian E; Davies, Paul; Lubben, Anneke; Kasprzyk-Hordern, Barbara

    2015-07-02

    This is the first study presenting a multi-residue method allowing for comprehensive analysis of several chiral pharmacologically active compounds (cPACs) including beta-blockers, antidepressants and amphetamines in wastewater and digested sludge at the enantiomeric level. Analysis of both the liquid and solid matrices within wastewater treatment is crucial to being able to carry out mass balance within these systems. The method developed comprises filtration, microwave assisted extraction and solid phase extraction followed by chiral liquid chromatography coupled with tandem mass spectrometry to analyse the enantiomers of 18 compounds within all three matrices. The method was successfully validated for 10 compounds within all three matrices (amphetamine, methamphetamine, MDMA, MDA, venlafaxine, desmethylvenlafaxine, citalopram, metoprolol, propranolol and sotalol), 7 compounds validated for the liquid matrices only (mirtazapine, salbutamol, fluoxetine, desmethylcitalopram, atenolol, ephedrine and pseudoephedrine) and 1 compound (alprenolol) passing the criteria for solid samples only. The method was then applied to wastewater samples; cPACs were found at concentration ranges in liquid matrices of: 1.7 ng L(-1) (metoprolol) - 1321 ng L(-1) (tramadol) in influent, solid matrix digested sludge: 0.4 ng g(-1) (metoprolol) - 275 ng g(-1) (citalopram). Enantiomeric profiling revealed that studied compounds were present in analysed samples in non-racemic composition. Furthermore, enantiomeric composition of studied analytes differed in liquid and solid matrices. This demonstrates that not analysing the solid fraction of wastewater may lead to over-estimation of the removal rates of cPACs as well as possible misrepresentation of the enantiomeric fraction of the compounds as they leave the wastewater treatment plant. Consequently risks from cPACs entering the environment might be higher than

  11. Physical characterization of biomass-based pyrolysis liquids. Application of standard fuel oil analyses

    Energy Technology Data Exchange (ETDEWEB)

    Oasmaa, A; Leppaemaeki, E; Koponen, P; Levander, J; Tapola, E [VTT Energy, Espoo (Finland). Energy Production Technologies

    1998-12-31

    The main purpose of the study was to test the applicability of standard fuel oil methods developed for petroleum-based fuels to pyrolysis liquids. In addition, research on sampling, homogeneity, stability, miscibility and corrosivity was carried out. The standard methods have been tested for several different pyrolysis liquids. Recommendations on sampling, sample size and small modifications of standard methods are presented. In general, most of the methods can be used as such but the accuracy of the analysis can be improved by minor modifications. Fuel oil analyses not suitable for pyrolysis liquids have been identified. Homogeneity of the liquids is the most critical factor in accurate analysis. The presence of air bubbles may disturb in several analyses. Sample preheating and prefiltration should be avoided when possible. The former may cause changes in the composition and structure of the pyrolysis liquid. The latter may remove part of organic material with particles. The size of the sample should be determined on the basis of the homogeneity and the water content of the liquid. The basic analyses of the Technical Research Centre of Finland (VTT) include water, pH, solids, ash, Conradson carbon residue, heating value, CHN, density, viscosity, pourpoint, flash point, and stability. Additional analyses are carried out when needed. (orig.) 53 refs.

  12. Integrated solid waste management in megacities

    Directory of Open Access Journals (Sweden)

    M.A. Abdoli

    2016-05-01

    Full Text Available Rapid urbanization and industrialization, population growth and economic growth in developing countries make management of municipal solid waste more complex comparing with developed countries. Furthermore, the conventional municipal solid waste management approach often is reductionists, not tailored to handle complexity. Therefore, the need to a comprehensive and multi-disciplinary approach regarding the municipal solid waste management problems is increasing. The concept of integrated solid waste management is accepted for this aim all over the world. This paper analyzes the current situation as well as opportunities and challenges regarding municipal solid waste management in Isfahan according to the integrated solid waste management framework in six aspects: environmental, political/legal, institutional, socio-cultural, financial/economic, technical and performance aspects. Based on the results obtained in this analysis, the main suggestions for future integrated solid waste management of Isfahan are as i promoting financial sustainability by taking the solid waste fee and reducing the expenses through the promoting source collection of recyclable materials, ii improving compost quality and also marketing the compost products simultaneously, iii promoting the private sector involvements throughout the municipal solid waste management system.

  13. Laser solid sampling for a solid-state-detector ICP emission spectrometer

    International Nuclear Information System (INIS)

    Noelte, J.; Moenke-Blankenburg, L.; Schumann, T.

    1994-01-01

    Solid sampling with laser vaporization has been coupled to an ICP emission spectrometer with an Echelle optical system and a solid-state-detector for the analysis of steel and soil samples. Pulsation of the vaporized material flow was compensated by real-time background correction and internal standardization, resulting in good accuracy and precision. (orig.)

  14. Radionuclide distribution in TMI-2 reactor building basement liquids and solids

    International Nuclear Information System (INIS)

    Horan, J.T.; McIsaac, C.V.; Keefer, D.G.

    1984-01-01

    As a result of the TMI-2 accident, approximately 2.46 x 10 6 L of contaminated water were released to the Reactor Building basement. The principal fission product release pathway from the damaged core was through the reactor coolant system (RCS) to the pressurizer, through the pressure-operated relief valve (PORV) on the pressurizer to the Reactor Coolant Drain Tank (RCDT), and then through the RCDT rupture disk to the Reactor Building basement. Since August 1979, a number of efforts have been made to determine the location, quantity, and composition of fission products released to the Reactor Building basement. These efforts have included sampling of the basement water and solids, the basement sump pump recirculation line, the RCDT, and visual surveys using a closed circuit television (CCTV) system. The analysis of basement samples has provided data on the physical and radioisotopic characteristics of the liquids and solids. This paper describes the sample collection techniques and discusses radiochemical analyses results

  15. Invasive fungal infections and antifungal therapies in solid organ transplant recipients.

    Science.gov (United States)

    Gabardi, Steven; Kubiak, David W; Chandraker, Anil K; Tullius, Stefan G

    2007-12-01

    This manuscript will review the risk factors, prevalence, clinical presentation, and management of invasive fungal infections (IFIs) in solid organ transplant (SOT) recipients. Primary literature was obtained via MEDLINE (1966-April 2007) and EMBASE. Abstracts were obtained from scientific meetings or pharmaceutical manufacturers and included in the analysis. All studies and abstracts evaluating IFIs and/or antifungal therapies, with a primary focus on solid organ transplantation, were considered for inclusion. English-language literature was selected for inclusion, but was limited to those consisting of human subjects. Infectious complications following SOT are common. IFIs are associated with high morbidity and mortality rates in this patient population. Determining the best course of therapy is difficult due to the limited availability of data in SOT recipients. Well-designed clinical studies are infrequent and much of the available information is often based on case-reports or retrospective analyses. Transplant practitioners must remain aware of their therapeutic options and the advantages and disadvantages associated with the available treatment alternatives.

  16. Management of Municipal Solid Waste in One of the Galapagos Islands

    Directory of Open Access Journals (Sweden)

    Marco Ragazzi

    2014-12-01

    Full Text Available This paper analyses some aspects of the management of municipal solid waste in one of the islands of the Galapagos archipelago. The aim is to point out a few aspects of an interesting experience that could help decision managers faced with the organization of the waste sector in similar realities. The relevance of this case study consists in the presence of a very famous National Park surrounding the inhabited area. The role of tourism in the generation of waste is analyzed too.

  17. Secondary electron emission from solid HD and a solid H2-D2 mixture

    DEFF Research Database (Denmark)

    Sørensen, H.; Børgesen, P.; Hao-Ming, Chen

    1983-01-01

    Secondary electron emission from solid HD and a solid 0.6 H2 + 0.4 D2 mixture has been studied for electron and hydrogen ion bombardment at primary energies from 0.5 to 3 keV and 2 to 10 keV/amu, respectively. The yield for solid HD is well explained by a simple stoichiometric model of the low...

  18. Acrylamide levels in Finnish foodstuffs analysed with liquid chromatography tandem mass spectrometry.

    Science.gov (United States)

    Eerola, Susanna; Hollebekkers, Koen; Hallikainen, Anja; Peltonen, Kimmo

    2007-02-01

    Sample clean-up and HPLC with tandem mass spectrometric detection (LC-MS/MS) was validated for the routine analysis of acrylamide in various foodstuffs. The method used proved to be reliable and the detection limit for routine monitoring was sensitive enough for foods and drinks (38 microg/kg for foods and 5 microg/L for drinks). The RSDs for repeatability and day-to-day variation were below 15% in all food matrices. Two hundred and one samples which included more than 30 different types of food and foods manufactured and prepared in various ways were analysed. The main types of food analysed were potato and cereal-based foods, processed foods (pizza, minced beef meat, meat balls, chicken nuggets, potato-ham casserole and fried bacon) and coffee. Acrylamide was detected at levels, ranging from nondetectable to 1480 microg/kg level in solid food, with crisp bread exhibiting the highest levels. In drinks, the highest value (29 microg/L) was found in regular coffee drinks.

  19. Energy and solid/hazardous waste

    Energy Technology Data Exchange (ETDEWEB)

    None

    1981-12-01

    This report addresses the past and potential future solid and hazardous waste impacts from energy development, and summarizes the major environmental, legislation applicable to solid and hazardous waste generation and disposal. A glossary of terms and acronyms used to describe and measure solid waste impacts of energy development is included. (PSB)

  20. Energy and solid/hazardous waste

    International Nuclear Information System (INIS)

    1981-12-01

    This report addresses the past and potential future solid and hazardous waste impacts from energy development, and summarizes the major environmental, legislation applicable to solid and hazardous waste generation and disposal. A glossary of terms and acronyms used to describe and measure solid waste impacts of energy development is included

  1. PLANNING OF INTEGRATED/SUSTAINABLE SOLID WASTE MANAGEMENT (ISWM – MODEL OF INTEGRATED SOLID WASTE MANAGEMENT IN REPUBLIKA SRPSKA/B&H

    Directory of Open Access Journals (Sweden)

    Milan Topić

    2015-11-01

    Full Text Available Municipal solid waste management (MSWM has become an important issue for countries around the world. The challenges are particularly notable in developing and transitional countries reflected mainly in inappropriate management, underdeveloped technology, an unfavorable economic situation and the lack of environmental awareness, causing a tremendous environmental impact. Today, various models are applied to analyze solid waste management systems from the regional to the municipal levels. Understanding the mechanisms and factors that currently drive the development of waste management is a crucial step for moving forward and planning sustainable waste management systems. The main objective of this paper is to apply the ISWM model, which is based on the Life-Cycle approach and follows the analytical framework methodology, to the research region. The transdisciplinary research framework was empirically tested and subsequently applied in the region Republika Srpska. Using the benchmark methodology, based on environmental, institutional and economical sustainability, the waste management is summarized in assessment profile. The results of the conducted analyses and the application of the developed model can be used further as a basis for the proposal of further strategic, political and managerial changes and support decision makers and stakeholders to handle waste in a cost-efficient and environmentally sound way

  2. Kinetics of the (solid + solid) transformations for the piracetam trimorphic system: Incidence on the construction of the p–T equilibrium phase diagram

    International Nuclear Information System (INIS)

    Corvis, Yohann; Spasojević-de Biré, Anne; Alzina, Camille

    2016-01-01

    Highlights: • Thermal analyses and X-ray diffraction experiments are performed. • Scan-rate dependence of the transition points is highlighted. • A new phase diagram of piracetam is proposed. • The new hierarchy of polymorphs stability is now coherent with all published data. - Abstract: The three common polymorphs of piracetam have been characterized by associating thermal analysis, X-ray diffraction and densimetry. DSC experiments showed that the (solid + solid) transition temperature between Forms II and I and between Forms III and I is scan-rate dependent. The transition temperatures decrease when the DSC scan rate decreases and the thermodynamic temperatures were confirmed by isothermal X-ray diffraction. These new results in terms of temperature and enthalpy of transition allow us to propose a new equilibrium phase diagram establishing the relative thermodynamic stability of the three common polymorphs of piracetam as a function of the temperature and the pressure. The diagram suggests that Form II presents a small stability domain located just above the stability domain of Form I. As a consequence, Form I should transform into Form II, which itself can turn into Form III when placed under pressure.

  3. Solid-state laser engineering

    CERN Document Server

    Koechner, Walter

    1996-01-01

    Solid-State Laser Engineering, written from an industrial perspective, discusses in detail the characteristics, design, construction, and performance of solid-state lasers. Emphasis is placed on engineering and practical considerations; phenomenological aspects using models are preferred to abstract mathematical derivations. This new edition has extensively been updated to account for recent developments in the areas of diode-laser pumping, mode locking, ultrashort-pulse generation etc. Walter Koechner received a doctorate in Electrical Engineering from the University of Technology in Vienna, Austria, in 1965. He has published numerous papers in the fields of solid-state physics, optics, and lasers. Dr. Koechner is founder and president of Fibertek, Inc., a research firm specializing in the design, development, and production of advanced solid-state lasers, optical radars, and remote-sensing systems.

  4. Life cycle assessment of potential municipal solid waste management strategies for Mumbai, India.

    Science.gov (United States)

    Sharma, Bhupendra K; Chandel, Munish K

    2017-01-01

    Dumping of municipal solid waste into uncontrolled dumpsites is the most common method of waste disposal in most cities of India. These dumpsites are posing a serious challenge to environmental quality and sustainable development. Mumbai, which generates over 9000 t of municipal solid waste daily, also disposes of most of its waste in open dumps. It is important to analyse the impact of municipal solid waste disposal today and what would be the impact under integrated waste management schemes. In this study, life cycle assessment methodology was used to determine the impact of municipal solid waste management under different scenarios. Six different scenarios were developed as alternatives to the current practice of open dumping and partially bioreactor landfilling. The scenarios include landfill with biogas collection, incineration and different combinations of recycling, landfill, composting, anaerobic digestion and incineration. Global warming, acidification, eutrophication and human toxicity were assessed as environmental impact categories. The sensitivity analysis shows that if the recycling rate is increased from 10% to 90%, the environmental impacts as compared with present scenario would reduce from 998.43 kg CO 2 eq t -1 of municipal solid waste, 0.124 kg SO 2 eq t -1 , 0.46 kg PO 4 -3 eq t -1 , 0.44 kg 1,4-DB eq t -1 to 892.34 kg CO 2 eq t -1 , 0.121 kg SO 2 eq t -1 , 0.36 kg PO 4 -3 eq t -1 , 0.40 kg 1,4-DB eq t -1 , respectively. An integrated municipal solid waste management approach with a mix of recycling, composting, anaerobic digestion and landfill had the lowest overall environmental impact. The technologies, such as incineration, would reduce the global warming emission because of the highest avoided emissions, however, human toxicity would increase.

  5. A Fair Accord: Cradle to Cradle as a Design Theory Measured against John Rawls’ Theory of Justice and Immanuel Kant’s Categorical Imperative

    Directory of Open Access Journals (Sweden)

    Cyrille Gijbels

    2010-01-01

    Full Text Available This essay explores a specific aspect of the role of attitude in design. The design of the built environment requires us constantly to make aesthetic and ethical judgments; every design decision has to be satisfactorily justified. Surprisingly perhaps, this requires a clear concept of justice against which a design can be grounded. Aesthetic concerns about quality spill into ethical concerns about the rightness of a decision and vice versa. This essay discusses a simple but crucial question: if a designer is aware of Cradle to Cradle as a theory of design but fails to act according to its principles, is it then possible to justify the resultant design? In other words, is Cradle to Cradle as a design theory that most rare of transcendental notions: a Categorical Imperative? Why might it be useful to describe it as such? Does the fact that we do not yet know how to redesign most products and processes according to its principles disqualify the theory? Does a dismissal of the Cradle to Cradle theory inevitably lead to an unfair society? These are serious questions, with interesting answers and far reaching implications for the way we think about design. First we shall explain what Cradle to Cradle means and how it distinguishes itself from other theories of sustainability. Then we shall put that explanation in the context of two ethical theories, first of all John Rawls’ Theory of Justice and second Immanuel Kant’s concept of the Categorical Imperative. After that we shall note a few problems concerning Cradle to Cradle design theory and put those into perspective. This will lead to an important attitudinal conclusion, namely that Cradle to Cradle can legitimately be described as one of those extremely rare cases which deserves universal applicability. We will offer a two-pronged strategy as to how to proceed.

  6. The electronic structures of solids

    CERN Document Server

    Coles, B R

    2013-01-01

    The Electronic Structures of Solids aims to provide students of solid state physics with the essential concepts they will need in considering properties of solids that depend on their electronic structures and idea of the electronic character of particular materials and groups of materials. The book first discusses the electronic structure of atoms, including hydrogen atom and many-electron atom. The text also underscores bonding between atoms and electrons in metals. Discussions focus on bonding energies and structures in the solid elements, eigenstates of free-electron gas, and electrical co

  7. Solid state chemistry an introduction

    CERN Document Server

    Smart, Lesley E

    2012-01-01

    ""Smart and Moore are engaging writers, providing clear explanations for concepts in solid-state chemistry from the atomic/molecular perspective. The fourth edition is a welcome addition to my bookshelves. … What I like most about Solid State Chemistry is that it gives simple clear descriptions for a large number of interesting materials and correspondingly clear explanations of their applications. Solid State Chemistry could be used for a solid state textbook at the third or fourth year undergraduate level, especially for chemistry programs. It is also a useful resource for beginning graduate

  8. Solid polymer electrolytes

    Science.gov (United States)

    Abraham, Kuzhikalail M.; Alamgir, Mohamed; Choe, Hyoun S.

    1995-01-01

    This invention relates to Li ion (Li.sup.+) conductive solid polymer electrolytes composed of poly(vinyl sulfone) and lithium salts, and their use in all-solid-state rechargeable lithium ion batteries. The lithium salts comprise low lattice energy lithium salts such as LiN(CF.sub.3 SO.sub.2).sub.2, LiAsF.sub.6, and LiClO.sub.4.

  9. Stiffening solids with liquid inclusions

    Science.gov (United States)

    Style, Robert W.; Boltyanskiy, Rostislav; Allen, Benjamin; Jensen, Katharine E.; Foote, Henry P.; Wettlaufer, John S.; Dufresne, Eric R.

    2015-01-01

    From bone and wood to concrete and carbon fibre, composites are ubiquitous natural and synthetic materials. Eshelby’s inclusion theory describes how macroscopic stress fields couple to isolated microscopic inclusions, allowing prediction of a composite’s bulk mechanical properties from a knowledge of its microstructure. It has been extended to describe a wide variety of phenomena from solid fracture to cell adhesion. Here, we show experimentally and theoretically that Eshelby’s theory breaks down for small liquid inclusions in a soft solid. In this limit, an isolated droplet’s deformation is strongly size-dependent, with the smallest droplets mimicking the behaviour of solid inclusions. Furthermore, in opposition to the predictions of conventional composite theory, we find that finite concentrations of small liquid inclusions enhance the stiffness of soft solids. A straightforward extension of Eshelby’s theory, accounting for the surface tension of the solid-liquid interface, explains our experimental observations. The counterintuitive stiffening of solids by fluid inclusions is expected whenever inclusion radii are smaller than an elastocapillary length, given by the ratio of the surface tension to Young’s modulus of the solid matrix. These results suggest that surface tension can be a simple and effective mechanism to cloak the far-field elastic signature of inclusions.

  10. Solid biomass barometer

    International Nuclear Information System (INIS)

    Anon.

    2006-01-01

    The European (EU 25) wish to substitute solid biomass origin energy consumption (principally wood and wood waste, but also straw, crop harvest residues, vegetal and animal waste) for a part of that of fossil fuel origin (petrol, gas and coal) is beginning to pay off. 58,7 million tons oil equivalent (Mtoe) of solid biomass was produced in 2005, i.e. a 3.1 Mtoe increase with respect to 2004. Production of primary energy coming from direct combustion of renewable municipal solid waste in incineration plants should also be added on to this figure. The 0,2 Mtoe increase in this production with respect to 2004 brings valorization of this type of waste up to 5,3 Mtoe in 2005. (author)

  11. Applications in solid mechanics

    DEFF Research Database (Denmark)

    Ølgaard, Kristian Breum; Wells, Garth N.

    2012-01-01

    Problems in solid mechanics constitute perhaps the largest field of application of finite element methods. The vast majority of solid mechanics problems involve the standard momentum balance equation, posed in a Lagrangian setting, with different models distinguished by the choice of nonlinear...... or linearized kinematics, and the constitutive model for determining the stress. For some common models, the constitutive relationships are rather complex. This chapter addresses a number of canonical solid mechanics models in the context of automated modeling, and focuses on some pertinent issues that arise...

  12. Transport properties of silver telluride in the solid and liquid states; Etude des proprietes de transport dans le tellurure d'argent Ag{sub 2}Te aux hautes temperatures a l'etat solide et a l'etat liquide

    Energy Technology Data Exchange (ETDEWEB)

    Pham, N T [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1969-01-01

    Measurements of the electrical resistivity, Hall coefficient and thermoelectric power have been carried out for silver telluride over a large temperature range including both solid and liquid states. The analysis of the experimental data shows that in the solid state the transport properties are governed by an ambipolar process with an electron mobility much higher than the hole mobility ({mu}{sub n} = 10*{mu}{sub p}). It is found that the temperature dependence of the electron mobility can be represented by a T{sup -3} law. Deviations from the stoichiometric composition Ag{sub 2}Te have been studied. For all specimens, melting is accompanied by discontinuous variations in the transport properties. Above the melting point, the magnitude of the measured parameters and their temperature dependence show that liquid silver telluride behaves as a semiconductor. The contribution of Ag{sup +} ions to transport phenomena is suggested to account for the behaviour of the electrical properties. Experimental data have been analysed in terms of conventional theories. (author) [French] Les mesures de la resistivite electrique, du coefficient de Hall et du pouvoir thermoelectrique ont ete effectuees sur le tellurure d'argent dans un large domaine de temperature couvrant l'etat solide et l'etat liquide. L'analyse des resultats experimentaux obtenus a l'etat solide montre que les proprietes de transport sont gouvernees par le processus ambipolaire avec une mobilite des electrons beaucoup plus grande que celle des trous ({mu}{sub n} 10*{mu}{sub p}). On trouve que la mobilite des electrons varie avec la temperature suivant la loi T{sup -3}. Les ecarts de la composition stoechiometrique Ag{sub 2}Te ont ete etudies. Pour tous les echantillons, la fusion est caracterisee par des variations discontinues des proprietes de transport. Au dessus du point de fusion, la grandeur des parametres mesures ainsi que leur variation avec la temperature montrent que le tellurure d'argent liquide se

  13. Solid state chemistry and its applications

    CERN Document Server

    West, Anthony R

    2013-01-01

    Solid State Chemistry and its Applications, 2nd Edition: Student Edition is an extensive update and sequel to the bestselling textbook Basic Solid State Chemistry, the classic text for undergraduate teaching in solid state chemistry worldwide. Solid state chemistry lies at the heart of many significant scientific advances from recent decades, including the discovery of high-temperature superconductors, new forms of carbon and countless other developments in the synthesis, characterisation and applications of inorganic materials. Looking forward, solid state chemistry will be crucial for the

  14. Optimization of Casting Design Parameters on Fabrication of Reliable Semi-Solid Aluminum Suspension Control Arm

    Science.gov (United States)

    Ragab, Kh. A.; Bouaicha, A.; Bouazara, M.

    2017-09-01

    The semi-solid casting process has the advantage of providing reliable mechanical aluminum parts that work continuously in dynamic as control arm of the suspension system in automotive vehicles. The quality performance of dynamic control arm is related to casting mold and gating system designs that affect the fluidity of semi-solid metal during filling the mold. Therefore, this study focuses on improvement in mechanical performance, depending on material characterization, and casting design optimization, of suspension control arms made of A357 aluminum semi-solid alloys. Mechanical and design analyses, applied on the suspension arm, showed the occurrence of mechanical failures at unexpected weak points. Metallurgical analysis showed that the main reason lies in the difficult flow of semi-solid paste through the thin thicknesses of a complex geometry. A design modification procedure is applied to the geometry of the suspension arm to avoid this problem and to improve its quality performance. The design modification of parts was carried out by using SolidWorks design software, evaluation of constraints with ABAQUS, and simulation of flow with ProCast software. The proposed designs showed that the modified suspension arm, without ribs and with a central canvas designed as Z, is considered as a perfect casting design showing an increase in the structural strength of the component. In this case, maximum von Mises stress is 199 MPa that is below the yield strength of the material. The modified casting mold design shows a high uniformity and minim turbulence of molten metal flow during semi-solid casting process.

  15. Solid-State Physics Introduction to the Theory

    CERN Document Server

    Patterson, James

    2010-01-01

    Learning Solid State Physics involves a certain degree of maturity, since it involves tying together diverse concepts from many areas of physics. The objective is to understand, in a basic way, how solid materials behave. To do this one needs both a good physical and mathematical background. One definition of Solid State Physics is it is the study of the physical (e.g. the electrical, dielectric, magnetic, elastic, and thermal) properties of solids in terms of basic physical laws. In one sense, Solid State Physics is more like chemistry than some other branches of physics because it focuses on common properties of large classes of materials. It is typical that Solid State Physics emphasizes how physics properties link to electronic structure. We have retained the term Solid Modern solid state physics came of age in the late thirties and forties and is now is part of condensed matter physics which includes liquids, soft materials, and non-crystalline solids. This solid state/condensed matter physics book begin...

  16. Semi solid metal processing: The fraction solid dilemma

    International Nuclear Information System (INIS)

    Nafisi, S.; Emadi, D.; Ghomashchi, R.

    2009-01-01

    One of the most challenging aspects in semi solid metal (SSM) processing is to determine the actual volume fraction of the solid at the processing temperature. The fraction has great impact on the SSM slurry viscosity and the subsequent filling of the mold in the casting stage. Three methods, namely quantitative metallography, thermodynamic calculation, and thermal analysis are employed to investigate and clarify the contradictory open literature reports about the real value of the volume fraction of primary particles. It is reported that the discrepancies between the results obtained by different methods are caused mainly by variations in cooling rates and by coarsening of the primaries during the quenching process

  17. Semi solid metal processing: The fraction solid dilemma

    Energy Technology Data Exchange (ETDEWEB)

    Nafisi, S. [EVRAZ Inc. NA 100 Armour Road, Regina, SK, S4P 3C7 (Canada)], E-mail: Shahrooz.Nafisi@evrazincna.com; Emadi, D. [CEPG, CanmetENERGY, Natural Resources Canada, Ottawa, ON, K1A 1M1 (Canada); Ghomashchi, R. [Advanced Materials and Processing Research Institute, Suite 122, A7-1390 Major MacKenzie, ON, L4S 0A1 (Canada)

    2009-05-15

    One of the most challenging aspects in semi solid metal (SSM) processing is to determine the actual volume fraction of the solid at the processing temperature. The fraction has great impact on the SSM slurry viscosity and the subsequent filling of the mold in the casting stage. Three methods, namely quantitative metallography, thermodynamic calculation, and thermal analysis are employed to investigate and clarify the contradictory open literature reports about the real value of the volume fraction of primary particles. It is reported that the discrepancies between the results obtained by different methods are caused mainly by variations in cooling rates and by coarsening of the primaries during the quenching process.

  18. Single crystal structure analyses of scheelite-powellite CaW1-xMoxO4 solidsolutions and unique occurrence in Jisyakuyama skarn deposits

    Science.gov (United States)

    Yamashita, K.; Yoshiasa, A.; Miyazaki, H.; Tokuda, M.; Tobase, T.; Isobe, H.; Nishiyama, T.; Sugiyama, K.; Miyawaki, R.

    2017-12-01

    Jisyakuyama skarn deposit, Fukuchi, Fukuoka, Japan, shows a simple occurrenceformed by penetration of hot water into limestone cracks. A unique occurrence of scheelite-powellite CaW1-xMoxO4 minerals is observed in the skarn deposit. Many syntheticexperiments for scheelite-powellite solid solutions have been reported as research onfluorescent materials. In this system it is known that a complete continuous solid solution isformed even at room temperature. In this study, we have carried out the chemical analyses,crystal structural refinements and detail description of occurrence on scheelite-powelliteminerals. We have also attempted synthesis of single crystal of solid solution in a widecomposition range. The chemical compositions were determined by JEOL scanningelectron microscope and EDS, INCA system. We have performed the crystal structurerefinements of the scheelite-powellite CaW1-xMoxO4 solid solutions (x=0.0-1.0) byRIGAKU single-crystal structure analysis system RAPID. The R and S values are around0.0s and 1.03. As the result of structural refinements of natural products and many solidsolutions, we confirm that most large natural single crystals have compositions at bothendmembers, and large solid solution crystals are rare. The lattice constants, interatomicdistances and other crystallographic parameters for the solid solution change uniquely withcomposition and it was confirmed as a continuous solid solution. Single crystals of scheeliteendmember + powellite endmember + solid solution with various compositions form anaggregate in the deposit (Figure 1). Crystal shapes of powellite and scheelite arehypidiomorphic and allotriomorphic, respectively. Many solid solution crystals areaccompanied by scheelite endmember and a compositional gap is observed betweenpowellite and solid-solution crystals. The presence of several penetration solutions withsignificantly different W and Mo contents may be assumed. This research can be expectedto lead to giving restrictive

  19. A computer program for processing experimental Compton profile of solids and liquids

    International Nuclear Information System (INIS)

    Das, G.P.

    1984-01-01

    A computer program COMPRO has been developed for processing experimental Compton profile data of solids and liquids generated by inelastic gamma ray scattering using a solid state detector and a multichannel analyser. It also calculates the fourier transform of the profile yielding the one electron autocorrelation function in position space. The theory behind the method of calculation is outlined and the various data processing steps needed to be applied on the raw experimental data have been discussed in detail. A flow chart of the program is given and the various subroutines of the program, method of feeding the input data and the method of presenting the final result are briefly described. The procedure is illustrated by measurement on a polycrystalline sample of manganese. The actual listing of the program along with the test run input data and the test run output data is also given. (M.G.B.)

  20. Solid targetry for compact cyclotrons

    International Nuclear Information System (INIS)

    Comor, J.

    2004-01-01

    In this presentation authors present experimental results of solid targetry for compact cyclotrons. It is concluded: Solid targetry is not restricted to large accelerator centers anymore; Small and medium scale radioisotope production is feasible with compact cyclotrons; The availability of versatile solid target systems is expected to boost the radiochemistry of 'exotic' positron emitters

  1. Magnetic resonance studies of solid polymers; Etude des polymeres solides par resonance magnetique

    Energy Technology Data Exchange (ETDEWEB)

    Lenk, R [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1969-07-01

    This paper is a review of the application of nuclear magnetic resonance (NMR) to solid polymers. In the first, theoretical part, the elements of the theory of NMR, which are necessary for the study of the properties of solid polymers are discussed: the moments method, nuclear relaxation and the distribution of correlation times. In the second part the experimental results are presented. (author) [French] Cette etude est une recherche bibliographique sur l'application de la resonance magnetique nucleaire (RMN) aux polymeres solides. Dans la premiere partie theorique on discute les elements de la theorie de RMN, necessaires pour l'etude des proprietes des polymeres solides: la methode des moments, la relaxation nucleaire et la distribution des temps de correlation. La deuxieme partie presente les resultats des experiences. (auteur)

  2. Trends in Consumption of Solid Fats, Added Sugars, Sodium, Sugar-Sweetened Beverages, and Fruit from Fast Food Restaurants and by Fast Food Restaurant Type among US Children, 2003-2010.

    Science.gov (United States)

    Rehm, Colin D; Drewnowski, Adam

    2016-12-13

    Energy intakes from fast food restaurants (FFRs) have declined among US children. Less is known about the corresponding trends for FFR-sourced solid fats, added sugars, and sodium, and food groups of interest, such as fruit and sugar-sweetened beverages (SSBs). Using data from a single 24-h dietary recall among 12,378 children aged 4-19 years from four consecutive cycles of the nationally-representative National Health and Nutrition Examination Survey (NHANES), 2003-2010 a custom algorithm segmented FFRs into burger, pizza, sandwich, Mexican cuisine, chicken, Asian cuisine, fish restaurants, and coffee shops. There was a significant population-wide decline in FFR-sourced solid fats (-32 kcal/day, p -trend restaurants; added sugars, solid fats, and SSBs declined significantly from burger restaurants. Fruit did not change for fast food restaurants overall. Temporal analyses of fast food consumption trends by restaurant type allow for more precise monitoring of the quality of children's diets than can be obtained from analyses of menu offerings. Such analyses can inform public health interventions and policy measures.

  3. Children's schemes for anticipating the validity of nets for solids

    Science.gov (United States)

    Wright, Vince; Smith, Ken

    2017-09-01

    There is growing acknowledgement of the importance of spatial abilities to student achievement across a broad range of domains and disciplines. Nets are one way to connect three-dimensional shapes and their two-dimensional representations and are a common focus of geometry curricula. Thirty-four students at year 6 (upper primary school) were interviewed on two occasions about their anticipation of whether or not given nets for the cube- and square-based pyramid would fold to form the target solid. Vergnaud's ( Journal of Mathematical Behavior, 17(2), 167-181, 1998, Human Development, 52, 83-94, 2009) four characteristics of schemes were used as a theoretical lens to analyse the data. Successful schemes depended on the interaction of operational invariants, such as strategic choice of the base, rules for action, particularly rotation of shapes, and anticipations of composites of polygons in the net forming arrangements of faces in the solid. Inferences were rare. These data suggest that students need teacher support to make inferences, in order to create transferable schemes.

  4. Separation of oils from solids

    International Nuclear Information System (INIS)

    Van Slyke, D.C.

    1992-01-01

    This patent describes a method for cleaning oil-contaminated particulate solids. It comprises: contacting contaminated solids with a non-aqueous liquid composition comprising a carboxylic acid; then contacting the solids with an aqueous wash containing a reagent for converting the carboxylic acid to a water-soluble carboxylate salt; and removing an aqueous phase containing carboxylate salt and entrained oil

  5. The impact imperative: Laser ablation for deflecting asteroids, meteoroids, and comets from impacting the earth

    Energy Technology Data Exchange (ETDEWEB)

    Campbell, Jonathan W [Advanced Projects/FD02, National Space Science and Technology Center, NASA/MSFC, Huntsville, Alabama, 35812 (United States); Phipps, Claude [Photonics Associates 200A Ojo de la Vaca Road Santa Fe, NM 87505 (United States); Smalley, Larry [Department of Physics, University of Alabama, Huntsville (United States); Reilly, James [Northeast Science and Technology, East Sandwich, MA (United States); Boccio, Dona [Queensborough Community College of the City, University of New York, New York (United States)

    2003-05-14

    Impacting at hypervelocity, an asteroid struck the Earth approximately 65 million years ago in the Yucatan Peninsula area. This triggered the extinction of almost 70% of the species of life on Earth including the dinosaurs. Other impacts prior to this one have caused even greater extinctions. Preventing collisions with the Earth by hypervelocity asteroids, meteoroids, and comets is the most important immediate space challenge facing human civilization. This is the Impact Imperative. We now believe that while there are about 2000 earth orbit crossing rocks greater than 1 kilometer in diameter, there may be as many as 200,000 or more objects in the 100 m size range. Can anything be done about this fundamental existence question facing our civilization? The answer is a resounding yes{exclamation_point} By using an intelligent combination of Earth and space based sensors coupled with an infra-structure of high-energy laser stations and other secondary mitigation options, we can deflect inbound asteroids, meteoroids, and comets and prevent them from striking the Earth. This can be accomplished by irradiating the surface of an inbound rock with sufficiently intense pulses so that ablation occurs. This ablation acts as a small rocket incrementally changing the shape of the rock's orbit around the Sun. One-kilometer size rocks can be moved sufficiently in about a month while smaller rocks may be moved in a shorter time span.

  6. The impact imperative: Laser ablation for deflecting asteroids, meteoroids, and comets from impacting the earth

    International Nuclear Information System (INIS)

    Campbell, Jonathan W.; Phipps, Claude; Smalley, Larry; Reilly, James; Boccio, Dona

    2003-01-01

    Impacting at hypervelocity, an asteroid struck the Earth approximately 65 million years ago in the Yucatan Peninsula area. This triggered the extinction of almost 70% of the species of life on Earth including the dinosaurs. Other impacts prior to this one have caused even greater extinctions. Preventing collisions with the Earth by hypervelocity asteroids, meteoroids, and comets is the most important immediate space challenge facing human civilization. This is the Impact Imperative. We now believe that while there are about 2000 earth orbit crossing rocks greater than 1 kilometer in diameter, there may be as many as 200,000 or more objects in the 100 m size range. Can anything be done about this fundamental existence question facing our civilization? The answer is a resounding yes! By using an intelligent combination of Earth and space based sensors coupled with an infra-structure of high-energy laser stations and other secondary mitigation options, we can deflect inbound asteroids, meteoroids, and comets and prevent them from striking the Earth. This can be accomplished by irradiating the surface of an inbound rock with sufficiently intense pulses so that ablation occurs. This ablation acts as a small rocket incrementally changing the shape of the rock's orbit around the Sun. One-kilometer size rocks can be moved sufficiently in about a month while smaller rocks may be moved in a shorter time span

  7. The solid state maser

    CERN Document Server

    Orton, J W; Walling, J C; Ter Haar, D

    1970-01-01

    The Solid State Maser presents readings related to solid state maser amplifier from the first tentative theoretical proposals that appeared in the early 1950s to the successful realization of practical devices and their application to satellite communications and radio astronomy almost exactly 10 years later. The book discusses a historical account of the early developments (including that of the ammonia maser) of solid state maser; the properties of paramagnetic ions in crystals; the development of practical low noise amplifiers; and the characteristics of maser devices designed for communica

  8. Structural diversity of solid dispersions of acetylsalicylic acid as seen by solid-state NMR.

    Science.gov (United States)

    Policianova, Olivia; Brus, Jiri; Hruby, Martin; Urbanova, Martina; Zhigunov, Alexander; Kredatusova, Jana; Kobera, Libor

    2014-02-03

    Solid dispersions of active pharmaceutical ingredients are of increasing interest due to their versatile use. In the present study polyvinylpyrrolidone (PVP), poly[N-(2-hydroxypropyl)-metacrylamide] (pHPMA), poly(2-ethyl-2-oxazoline) (PEOx), and polyethylene glycol (PEG), each in three Mw, were used to demonstrate structural diversity of solid dispersions. Acetylsalicylic acid (ASA) was used as a model drug. Four distinct types of the solid dispersions of ASA were created using a freeze-drying method: (i) crystalline solid dispersions containing nanocrystalline ASA in a crystalline PEG matrix; (ii) amorphous glass suspensions with large ASA crystallites embedded in amorphous pHPMA; (iii) solid solutions with molecularly dispersed ASA in rigid amorphous PVP; and (iv) nanoheterogeneous solid solutions/suspensions containing nanosized ASA clusters dispersed in a semiflexible matrix of PEOx. The obtained structural data confirmed that the type of solid dispersion can be primarily controlled by the chemical constitutions of the applied polymers, while the molecular weight of the polymers had no detectable impact. The molecular structure of the prepared dispersions was characterized using solid-state NMR, wide-angle X-ray scattering (WAXS), and differential scanning calorimetry (DSC). By applying various (1)H-(13)C and (1)H-(1)H correlation experiments combined with T1((1)H) and T1ρ((1)H) relaxation data, the extent of the molecular mixing was determined over a wide range of distances, from intimate intermolecular contacts (0.1-0.5 nm) up to the phase-separated nanodomains reaching ca. 500 nm. Hydrogen-bond interactions between ASA and polymers were probed by the analysis of (13)C and (15)N CP/MAS NMR spectra combined with the measurements of (1)H-(15)N dipolar profiles. Overall potentialities and limitations of individual experimental techniques were thoroughly evaluated.

  9. Creep behaviour of porous metal supports for solid oxide fuel cells

    DEFF Research Database (Denmark)

    Boccaccini, Dino; Frandsen, Henrik Lund; Sudireddy, Bhaskar Reddy

    2014-01-01

    The creep behaviour of porous ironechromium alloy used as solid oxide fuel cell support was investigated, and the creep parameters are compared with those of dense strips of similar composition under different testing conditions. The creep parameters were determined using a thermo......-mechanical analyser with applied stresses in the range from 1 to 15 MPa and temperatures between 650 and 800 _C. The GibsoneAshby and Mueller models developed for uniaxial creep of open-cell foams were used to analyse the results. The influence of scale formation on creep behaviour was assessed by comparing the creep...... data for the samples tested in reducing and oxidising atmospheres. The influence of preoxidation on creep behaviour was also investigated. In-situ oxidation during creep experiments increases the strain rate while pre-oxidation of samples reduces it. Debonding of scales at high stress regime plays...

  10. Effect of fluidization number on the combustion of simulated municipal solid waste in a fluidized bed

    International Nuclear Information System (INIS)

    Anwar Johari; Mutahharah, M.M.; Abdul, A.; Salema, A.; Kalantarifard, A.; Rozainee, M.

    2010-01-01

    The effect of fluidization number on the combustion of simulated municipal solid was in a fluidized bed was investigated. Simulated municipal solid waste was used a sample and it was formulated from major waste composition found in Malaysia which comprised of food waste, paper, plastic and vegetable waste. Proximate and ultimate analyses of the simulated were conducted and results showed its composition was similar to the actual Malaysian municipal solid waste composition. Combustion study was carried out in a rectangular fluidized bed with sand of mean particle size of 0.34 mm as a fluidising medium. The range of fluidization numbers investigated was 3 to 11 U mf . The combustion was carried out at stoichiometric condition (Air Factor = 1). Results showed that the best fluidization number was in the range of 5 to 7 U mf with 5 U mf being the most optimum in which the bed temperature was sustained in a much longer period. (author)

  11. Evaluation and Analysis of Solid Waste at ISF Academy

    Science.gov (United States)

    Ma, D. W. J.

    2017-12-01

    Waste management is one of the biggest environmental problems in Hong Kong. According to a report from the HK government, in less than 3 years, which is 2020, all the local landfills will be filled with trash. Therefore, ISF Academy, a school in HK with 1800 students, is planning to reduce their solid waste on campus by evaluating and analysing all solid wastes, which can assist professionals to reform and innovate solutions for refuse disposal. Meanwhile, this project is designed for both raising students' awareness of the magnitude of waste and figuring out measures for waste reduction. For one thing, the project includes the promotion of Waste Audit to reach the former purpose by teaching students how to sort waste. In addition, the weight of each type of waste will be recorded as reference data for students to learn about varied degrees of quantities among different kinds of garbage and relate data to impacts brought by waste with diverse characteristics on the environment. For another, the researcher involved in this project will carry out solutions corresponding to various sorts of waste by applying scientific knowledge, carrying out surveys, organizing campaigns etc.

  12. Developments of solid materials for UF6 sampling

    Energy Technology Data Exchange (ETDEWEB)

    Smith, Nicholas [Argonne National Lab. (ANL), Argonne, IL (United States). Nuclear Engineering Division; Hebden, Andrew [Argonne National Lab. (ANL), Argonne, IL (United States). Nuclear Engineering Division; Savina, Joseph [Argonne National Lab. (ANL), Argonne, IL (United States). Nuclear Engineering Division

    2017-11-15

    This project demonstrated that a device using majority Commercial Off the Shelf (COTS) components could be used to collect uranium hexafluoride samples safely from gaseous or solid sources. The device was based on the successful Cristallini method developed by ABACC over the past 10 years. The system was designed to capture and store the UF6 as an inert fluoride salt to ease transportation regulations. In addition, the method was considerably faster than traditional cryogenic methods, collected enough material to perform analyses without undue waste, and could be used either inside a facility or in the storage yard.

  13. SOLIDS PRECIPITATION EVENT IN MCU CAUSAL ANALYSIS AND RECOMMENDATIONS FROM SOLIDS RECOVERY TEAM

    Energy Technology Data Exchange (ETDEWEB)

    Garrison, A.; Aponte, C.

    2014-08-15

    A process upset occurred in the Modular Caustic-Side Solvent Extraction Unit (MCU) facility on April 6th, 2014. During recovery efforts, a significant amount of solids were found in the Salt Solution Feed Tank (SSFT), Salt Solution Receipt Tanks (SSRTs), two extraction contactors, and scrub contactors. The solids were identified by Savannah River National Laboratory (SRNL) as primarily sodium oxalate and sodium alumina silicate (NAS) with the presence of some aluminum hydroxide. NAS solids have been present in the SSFT since simulant runs during cold chemical startup of MCU in 2007, and have not hindered operations since that time. During the process upset in April 2014, the oxalate solids partially blocked the aqueous outlet of the extraction contactors, causing salt solution to exit through the contactor organic outlet to the scrub contactors with the organic phase. This salt solution overwhelmed the scrub contactors and passed with the organic phase to the strip section of MCU. The partially reversed flow of salt solution resulted in a Strip Effluent (SE) stream that was high in Isopar™ L, pH and sodium. The primary cause of the excessive solids accumulation in the SSRTs and SSFT at MCU is attributed to an increase in the frequency of oxalic acid cleaning of the 512-S primary filter. Agitation in the SSRTs at MCU in response to cold weather likely provided the primary mechanism to transfer the solids to the contactors. Sources of the sodium oxalate solids are attributed to the oxalic acid cleaning solution used to clean the primary filter at the Actinide Removal Process (ARP) filtration at 512-S, as well as precipitation from the salt batch feed, which is at or near oxalate saturation. The Solids Recovery Team was formed to determine the cause of the solids formation and develop recommendations to prevent or mitigate this event in the future. A total of 53 recommendations were generated. These recommendations were organized into 4 focus areas: • Improve

  14. Preparation and characterization of celecoxib solid dispersions; comparison of poloxamer-188 and PVP-K30 as carriers

    Directory of Open Access Journals (Sweden)

    Alireza Homayouni

    2014-05-01

    Full Text Available Objective(s:Solid dispersion formulation is the most promising strategy to improve oral bioavailability of poorly water soluble drugs. The aim of this study was to compare the effect of polyvinylpyrrolidone K30 (PVP and poloxamer-188 (PLX as carrier in solid dispersion formulations of celecoxib (CLX. Materials and Methods: Solid dispersions of CLX:PVP or CLX:PLX were prepared at different ratios (2:1, 1:1, 1:2, 1:4, 1:6 by solvent evaporation and melting methods, respectively. The characterization of samples was performed using differential scanning calorimetery (DSC, X-Ray powder diffraction (XRPD and Fourier transform infrared spectroscopy (FT-IR. The Gordon-Taylor equation was used to estimate the Tg of solid dispersion systems and the possibility of the interaction between CLX and PVP. Also, the dissolution rate of all samples was determined. Results: DSC and XRPD analyses confirmed the presence of amorphous state of drug in solid dispersion systems. FT-IR studies showed CLX could participate in hydrogen bonding with PVP whilst no specific interaction between CLX and PLX was observed. Both PVP and PLX enhanced the dissolution rate of drug in solid dispersion samples. The dissolution rate was dependent on the ratio of drug: carrier. Interestingly, the solid dispersion samples of PLX at 2:1 and 1:1 drug: carrier showed slower dissolution rate than pure CLX, whilst these results were not observed for PVP. Conclusion: The effect of PVP on dissolution rate enhancement was more pronounced compared to the other carrier. Having a higher Tg and more effect on dissolution rate, PVP could be considered as a more suitable carrier compared to PLX in solid dispersion formulation of CLX.

  15. 36 CFR 13.1118 - Solid waste disposal.

    Science.gov (United States)

    2010-07-01

    ... 36 Parks, Forests, and Public Property 1 2010-07-01 2010-07-01 false Solid waste disposal. 13.1118... Provisions § 13.1118 Solid waste disposal. (a) A solid waste disposal site may accept non-National Park Service solid waste generated within the boundaries of the park area. (b) A solid waste disposal site may...

  16. 36 CFR 13.1008 - Solid waste disposal.

    Science.gov (United States)

    2010-07-01

    ... 36 Parks, Forests, and Public Property 1 2010-07-01 2010-07-01 false Solid waste disposal. 13.1008... § 13.1008 Solid waste disposal. (a) A solid waste disposal site may accept non-National Park Service solid waste generated within the boundaries of the park area. (b) A solid waste disposal site may be...

  17. 36 CFR 13.1912 - Solid waste disposal.

    Science.gov (United States)

    2010-07-01

    ... 36 Parks, Forests, and Public Property 1 2010-07-01 2010-07-01 false Solid waste disposal. 13.1912....1912 Solid waste disposal. (a) A solid waste disposal site may accept non-National Park Service solid waste generated within the boundaries of the park area. (b) A solid waste disposal site may be located...

  18. 36 CFR 13.1604 - Solid waste disposal.

    Science.gov (United States)

    2010-07-01

    ... 36 Parks, Forests, and Public Property 1 2010-07-01 2010-07-01 false Solid waste disposal. 13.1604... Solid waste disposal. (a) A solid waste disposal site may accept non-National Park Service solid waste generated within the boundaries of the park area. (b) A solid waste disposal site may be located within one...

  19. Towards a person-centered medical education: challenges and imperatives (I

    Directory of Open Access Journals (Sweden)

    Andrew Miles

    2015-01-01

    curriculum are necessary, as a first step, to achieving real progress in the integrity of modern undergraduate medical education. Without such innovations, we do not believe that suitable foundations for subsequent innovations in postgraduate training can be laid and, with them, a continuing professional education in PCH that spans entire medical careers. We first review the historical perspectives of relevance to our arguments and then advocate a radical re-think of what we believe to be the urgent imperatives for a modern medical undergraduate and postgraduate training.

  20. Development of a solid phase technic for radioimmunoassay of triiodothyronine (T3) in serum

    International Nuclear Information System (INIS)

    Hamada, M.M.; Mesquita, C.H.; Silva, C.P.G. da.

    1988-10-01

    We have developed a solid phase radioimmunoassay (RIA) system for triiodothyronine (T 3 ), by immobilizing triiodothyronine antibodies on the inner wall of reaction tubes. The antibody-coated tubes were made via reaction of antibody with glutaraldeyde residue pre coated on the inner wall of the tubes by alkaline self-polimerization. The quality of the coated tubes was tested through its performance in the RIA methodology, by analysing the following RIA parameters: minimum detectable dose (MDD), nonspecific binding (NSB), ''X 50% '', slope of the standard curve, intra and inter-assay precision, accuracy of the method and figure of merit. The serum levels of T 3 in hypothyroid and hyperthyroid patients and the normal values range were determined for the solid phase RIA system. The results are in agreement with found in the literature. (author) [pt

  1. Independent and combined effects of maternal smoking and solid fuel on infant and child mortality in sub-Saharan Africa.

    Science.gov (United States)

    Akinyemi, Joshua O; Adedini, Sunday A; Wandera, Stephen O; Odimegwu, Clifford O

    2016-12-01

    To estimate the independent and combined risks of infant and child mortality associated with maternal smoking and use of solid fuel in sub-Saharan Africa. Pooled weighted data on 143 602 under-five children in the most recent demographic and health surveys for 15 sub-Saharan African countries were analysed. The synthetic cohort life table technique and Cox proportional hazard models were employed to investigate the effect of maternal smoking and solid cooking fuel on infant (age 0-11 months) and child (age 12-59 months) mortality. Socio-economic and other confounding variables were included as controls. The distribution of the main explanatory variable in households was as follows: smoking + solid fuel - 4.6%; smoking + non-solid fuel - 0.22%; no smoking + solid fuel - 86.9%; and no smoking + non-solid fuel - 8.2%. The highest infant mortality rate was recorded among children exposed to maternal smoking + solid fuel (72 per 1000 live births); the child mortality rate was estimated to be 54 per 1000 for this group. In full multivariate models, the risk of infant death was 71% higher among those exposed to maternal smoking + solid fuel (HR = 1.71, CI: 1.29-2.28). For ages 12 to 59 months, the risk of death was 99% higher (HR = 1.99, CI: 1.28-3.08). Combined exposures to cigarette smoke and solid fuel increase the risks of infant and child mortality. Mothers of under-five children need to be educated about the danger of smoking while innovative approaches are needed to reduce the mortality risks associated with solid cooking fuel. © 2016 John Wiley & Sons Ltd.

  2. Comparing peracetic acid and hypochlorite for disinfection of combined sewer overflows: Effects of suspended-solids and pH.

    Science.gov (United States)

    McFadden, M; Loconsole, J; Schockling, A J; Nerenberg, R; Pavissich, J P

    2017-12-01

    Peracetic acid (PAA) is an alternative disinfectant that may be effective for combined sewer overflow (CSO) disinfection, but little is known about the effect of particle size on PAA disinfection efficiency. In this work, PAA and hypochlorite were compared as disinfectants, with a focus on the effect of wastewater particles. Inactivation experiments were conducted on suspended cultures of Escherichia coli and wastewater suspended solids. Tested size fractions included particle diameters disinfection efficiency decreased with increasing solids size. However, solids size had little effect on PAA disinfection. The PAA disinfection efficiency decreased at pH values above 7.5. Live/dead staining revealed that PAA disinfection leaves most cells in a viable but non-culturable condition. Fourier transform infrared spectroscopy (FTIR) analyses suggests that PAA and hypochlorite may inactivate E. coli bacteria by similar mechanisms. Copyright © 2017 Elsevier B.V. All rights reserved.

  3. Solid polymer electrolyte lithium batteries

    Science.gov (United States)

    Alamgir, Mohamed; Abraham, Kuzhikalail M.

    1993-01-01

    This invention pertains to Lithium batteries using Li ion (Li.sup.+) conductive solid polymer electrolytes composed of solvates of Li salts immobilized in a solid organic polymer matrix. In particular, this invention relates to Li batteries using solid polymer electrolytes derived by immobilizing solvates formed between a Li salt and an aprotic organic solvent (or mixture of such solvents) in poly(vinyl chloride).

  4. XRD and solid state 13C-NMR evaluation of the crystallinity enhancement of 13C-labeled bacterial cellulose biosynthesized by Komagataeibacter xylinus under different stimuli: A comparative strategy of analyses.

    Science.gov (United States)

    Meza-Contreras, Juan C; Manriquez-Gonzalez, Ricardo; Gutiérrez-Ortega, José A; Gonzalez-Garcia, Yolanda

    2018-05-22

    The production and crystallinity of 13 C bacterial cellulose (BC) was examined in static culture of Komagataeibacter xylinus with different chemical and physical stimuli: the addition of NaCl or cloramphenicol as well as exposure to a magnetic field or to UV light. Crystalline BC biosynthesized under each stimulus was studied by XRD and solid state 13 C NMR analyses. All treatments produced BC with enhanced crystallinity over 90% (XRD) and 80% (NMR) compared to the control (83 and 76%, respectively) or to Avicel (77 and 62%, respectively). The XRD data indicated that the crystallite size was 80-85 Å. Furthermore, changes on the allomorphs (I α and I β ) ratio tendency of BC samples addressed to the stimuli were estimated using the C4 signal from 13 C NMR data. These results showed a decrease of the allomorph I α (3%) when BC was biosynthesized with UV light and chloramphenicol compared to control (58.79%). In contrast, the BC obtained with NaCl increased up to 60.31% of the I α allomorph ratio. Copyright © 2018 Elsevier Ltd. All rights reserved.

  5. Annealing effects in solid-state track recorders

    International Nuclear Information System (INIS)

    Gold, R.; Roberts, J.H.; Ruddy, F.H.

    1981-01-01

    Current analyses of the annealing process in Solid State Track Recorders (SSTR) reveal fundamental misconceptions. The use of the Arrhenius equation to describe the decrease in track density resulting from annealing is shown to be incorrect. To overcome these deficiencies, generalized reaction rate theory is used to describe the annealing process in SSTR. Results of annealing experiments are used to guide this theoretical formulation. Within this framework, the concept of energy per etchable defect for SSTR is introduced. A general correlation between sensitivity and annealing susceptibility in SSTR is deduced. In terms of this general theory, the apparent correlation between fission track size and fission track density observed under annealing is readily explained. Based on this theoretical treatment of annealing phenomena, qualitative explanations are advanced for current enigmas in SSTR cosmic ray work

  6. A coupled theory for chemically active and deformable solids with mass diffusion and heat conduction

    Science.gov (United States)

    Zhang, Xiaolong; Zhong, Zheng

    2017-10-01

    To analyse the frequently encountered thermo-chemo-mechanical problems in chemically active material applications, we develop a thermodynamically-consistent continuum theory of coupled deformation, mass diffusion, heat conduction and chemical reaction. Basic balance equations of force, mass and energy are presented at first, and then fully coupled constitutive laws interpreting multi-field interactions and evolving equations governing irreversible fluxes are constructed according to the energy dissipation inequality and the chemical kinetics. To consider the essential distinction between mass diffusion and chemical reactions in affecting free energy and dissipations of a highly coupled system, we regard both the concentrations of diffusive species and the extent of reaction as independent state variables. This new formulation then distinguishes between the energy contribution from the diffusive species entering the solid and that from the subsequent chemical reactions occurring among these species and the host solid, which not only interact with stresses or strains in different manners and on different time scales, but also induce different variations of solid microstructures and material properties. Taking advantage of this new description, we further establish a specialized isothermal model to predict precisely the transient chemo-mechanical response of a swelling solid with a proposed volumetric constraint that accounts for material incompressibility. Coupled kinetics is incorporated to capture the volumetric swelling of the solid caused by imbibition of external species and the simultaneous dilation arised from chemical reactions between the diffusing species and the solid. The model is then exemplified with two numerical examples of transient swelling accompanied by chemical reaction. Various ratios of characteristic times of diffusion and chemical reaction are taken into account to shed light on the dependency on kinetic time scales of evolution patterns for

  7. System and process for dissolution of solids

    Science.gov (United States)

    Liezers, Martin; Farmer, III, Orville T.

    2017-10-10

    A system and process are disclosed for dissolution of solids and "difficult-to-dissolve" solids. A solid sample may be ablated in an ablation device to generate nanoscale particles. Nanoparticles may then swept into a coupled plasma device operating at atmospheric pressure where the solid nanoparticles are atomized. The plasma exhaust may be delivered directly into an aqueous fluid to form a solution containing the atomized and dissolved solids. The composition of the resulting solution reflects the composition of the original solid sample.

  8. Solid-solid and gas-solid interactions induced during high-energy milling to produce PbTe nanopowders

    Energy Technology Data Exchange (ETDEWEB)

    Rojas-Chavez, H., E-mail: rojas_hugo@ittlahuac2.edu.mx [Instituto Tecnologico de Tlahuac - II (Mexico); Reyes-Carmona, F. [Facultad de Quimica - UNAM (Mexico); Garibay-Febles, V. [Instituto Mexicano del Petroleo, Laboratorio de Microscopia Electronica de Ultra Alta Resolucion (Mexico); Jaramillo-Vigueras, D. [Centro de Investigacion e Innovacion Tecnologica - IPN (Mexico)

    2013-05-15

    Transformations from precursors to nanoparticles by high-energy milling are promoted by two major driving forces, namely physical and/or chemical. While the former has been difficult to trace since stress, strain and recovery may occur almost simultaneously during milling, the latter has been sequentially followed as an evolution from precursors to intermediate phases and thereof to high purity nanocrystals. The specific objective of this work is to discern how solid-solid and partially solid-gas reactions manifest themselves correspondingly as a short-range diffusion through an interface or how vapor species, as a subliming phenomenon, grows as a different phase on an active local surface. These series of changes were traced by sub-cooling the as-milled powders extracted during a milling cycle. Through this experimental technique, samples were electron microscopically analyzed and where it was required, selected area electron diffraction images were obtained. High-resolution transmission electron microscopy results, unambiguously, confirm that nanocrystals in the last stage show a cubic morphology which average size distributions are around 17 nm.

  9. Indigenous microbial capability in solid manure residues to start-up solid-phase anaerobic digesters.

    Science.gov (United States)

    Yap, S D; Astals, S; Jensen, P D; Batstone, D J; Tait, S

    2017-06-01

    Batch solid-phase anaerobic digestion is a technology for sustainable on-farm treatment of solid residues, but is an emerging technology that is yet to be optimised with respect to start-up and inoculation. In the present study, spent bedding from two piggeries (site A and B) were batch digested at total solids (TS) concentration of 5, 10 and 20% at mesophilic (37°C) and thermophilic (55°C) temperatures, without adding an external inoculum. The results showed that the indigenous microbial community present in spent bedding was able to recover the full methane potential of the bedding (140±5 and 227±6L CH 4 kgVS fed -1 for site A and B, respectively), but longer treatment times were required than for digestion with an added external inoculum. Nonetheless, at high solid loadings (i.e. TS level>10%), the digestion performance was affected by chemical inhibition due to ammonia and/or humic acid. Thermophilic temperatures did not influence digestion performance but did increase start-up failure risk. Further, inoculation of residues from the batch digestion to subsequent batch enhanced start-up and achieved full methane potential recovery of the bedding. Inoculation with liquid residue (leachate) was preferred over a solid residue, to preserve treatment capacity for fresh substrate. Overall, the study highlighted that indigenous microbial community in the solid manure residue was capable of recovering full methane potential and that solid-phase digestion was ultimately limited by chemical inhibition rather than lack of suitable microbial community. Copyright © 2017 Elsevier Ltd. All rights reserved.

  10. Solid biomass barometer 2011

    International Nuclear Information System (INIS)

    2012-01-01

    The winter of 2011 was exceptionally mild, even in Northern Europe, with unusually warm temperatures. As a result the demand for firewood and solid biomass fuel was low. The European Union's primary energy production from solid biomass contracted by 2.9% slipping to 78.8 Mtoe. The first 4 countries are Germany (11.690 Mtoe), France (9.223 Mtoe), Sweden (8.165 Mtoe) and Finland (7.476 Mtoe) and when the production is relative to the population the first 4 countries become: Finland (1.391 toe/inhab.), Sweden (0.867 toe/inhab.), Latvia (0.784 toe/inhab.) and Estonia (0.644 toe/inhab.). Solid biomass electricity production continued to grow, driven by the additional take-up of biomass co-firing, to reach 72.800 TWh at the end of 2011, it means +2.6% compared to 2010. The energy policy of various states concerning solid biomass is analyzed

  11. Effect of solid distribution on elastic properties of open-cell cellular solids using numerical and experimental methods.

    Science.gov (United States)

    Zargarian, A; Esfahanian, M; Kadkhodapour, J; Ziaei-Rad, S

    2014-09-01

    Effect of solid distribution between edges and vertices of three-dimensional cellular solid with an open-cell structure was investigated both numerically and experimentally. Finite element analysis (FEA) with continuum elements and appropriate periodic boundary condition was employed to calculate the elastic properties of cellular solids using tetrakaidecahedral (Kelvin) unit cell. Relative densities between 0.01 and 0.1 and various values of solid fractions were considered. In order to validate the numerical model, three scaffolds with the relative density of 0.08, but different amounts of solid in vertices, were fabricated via 3-D printing technique. Good agreement was observed between numerical simulation and experimental results. Results of numerical simulation showed that, at low relative densities (solid fraction in vertices. By fitting a curve to the data obtained from the numerical simulation and considering the relative density and solid fraction in vertices, empirical relations were derived for Young׳s modulus and Poisson׳s ratio. Copyright © 2014 Elsevier Ltd. All rights reserved.

  12. Solid State Physics Introduction to the Theory

    CERN Document Server

    Patterson, James D

    2007-01-01

    Learning Solid State Physics involves a certain degree of maturity, since it involves tying together diverse concepts from many areas of physics. The objective is to understand, in a basic way, how solid materials behave. To do this one needs both a good physical and mathematical background. One definition of Solid State Physics is it is the study of the physical (e.g. the electrical, dielectric, magnetic, elastic, and thermal) properties of solids in terms of basic physical laws. In one sense, Solid State Physics is more like chemistry than some other branches of physics because it focuses on common properties of large classes of materials. It is typical that Solid State Physics emphasizes how physics properties link to electronic structure. We have retained the term Solid State Physics, even though Condensed Matter Physics is more commonly used. Condensed Matter Physics includes liquids and non-crystalline solids such as glass, which we shall not discuss in detail. Modern Solid State Physics came of age in ...

  13. Engineering Analyses of NCSX Modular Coil and Its Supporting Structure for EM Loads

    International Nuclear Information System (INIS)

    Fan, H.M.; Williamson, D.

    2003-01-01

    NCSX modular coil is a major parts of the NCSX coil systems that surround the highly shaped plasma and vacuum vessel. The flexible copper cable conductors are used to form modular coil on both sides of the ''tee'' beam, which is cast inside the supporting shell structure. The Engineering analyses comprise sequentially coupled-field analyses that include an electromagnetic analysis to calculate the magnetic fields and EM forces, and a structural analysis to evaluate the structural responses. In the sequential EM-structural analysis, nodal forces obtained from the EM analysis were applied as ''nodal force'' loads in the subsequent stress analysis using the identical nodal points and elements. The shell model was imported directly from Pro/ENGINEER files in order to obtain an accurate structural representation. The Boolean operations provided by the ANSYS preprocessor were then applied to subdivide the solid model for more desirable finite element meshing. Material properties of the modular coil were based on test results. Analyses using the ANSYS program to evaluate structural responses of the complicated modular coil systems provided a clear understanding of the structural behaviors and the directions for improving the structural design

  14. Trends in Consumption of Solid Fats, Added Sugars, Sodium, Sugar-Sweetened Beverages, and Fruit from Fast Food Restaurants and by Fast Food Restaurant Type among US Children, 2003–2010

    Science.gov (United States)

    Rehm, Colin D.; Drewnowski, Adam

    2016-01-01

    Energy intakes from fast food restaurants (FFRs) have declined among US children. Less is known about the corresponding trends for FFR-sourced solid fats, added sugars, and sodium, and food groups of interest, such as fruit and sugar-sweetened beverages (SSBs). Using data from a single 24-h dietary recall among 12,378 children aged 4–19 years from four consecutive cycles of the nationally-representative National Health and Nutrition Examination Survey (NHANES), 2003–2010 a custom algorithm segmented FFRs into burger, pizza, sandwich, Mexican cuisine, chicken, Asian cuisine, fish restaurants, and coffee shops. There was a significant population-wide decline in FFR-sourced solid fats (−32 kcal/day, p-trend restaurants; added sugars, solid fats, and SSBs declined significantly from burger restaurants. Fruit did not change for fast food restaurants overall. Temporal analyses of fast food consumption trends by restaurant type allow for more precise monitoring of the quality of children’s diets than can be obtained from analyses of menu offerings. Such analyses can inform public health interventions and policy measures. PMID:27983573

  15. Cathode solid electrolyte interface’s function originated from salt type additives in lithium ion batteries

    International Nuclear Information System (INIS)

    Kaneko, Yu; Park, Juyeon; Yokotsuji, Hokuto; Odawara, Makoto; Takase, Hironari; Ue, Makoto; Lee, Maeng-Eun

    2016-01-01

    Highlights: • Our chemical analysis determines the important functional groups of cathode’s solid electrolyte interface originated from salt type additives. • Our quantum chemical calculation reveals the redox character of the additives and their candidate chemical components of the solid electrolyte interface. • Our molecular dynamics simulation reproduces the selective lithium ion translocation and protective layer formation as the solid electrolyte interface function. - Abstract: This is the study about the cathode’s solid electrolyte interface (SEI) formation mechanism of salt type additives (STAs) and its function. To address this issue, we performed several types of chemical analysis and computer simulation techniques. In order to reveal the redox nature and oxidative decomposition dynamics, the electrolyte (EL) solution dynamics by Quantum mechanics and Molecular mechanics (QM/MM) method was applied. The estimation of SEI chemical components agrees with our chemical analyses data and other group’s reports. The molecular dynamics simulation of sub micro second sampling indicates that the SEI phase induced from STAs functions as a lithium ion selective translocation media and protective coating layer against the degradation of the solvent molecules. The results give us an insight how to design additive’s chemical structure to improve longevity of the cell in the high voltage regime.

  16. Controls on Mississippi Valley-Type Zn-Pb mineralization in Behabad district, Central Iran: Constraints from spatial and numerical analyses

    Science.gov (United States)

    Parsa, Mohammad; Maghsoudi, Abbas

    2018-04-01

    The Behabad district, located in the central Iranian microcontinent, contains numerous epigenetic stratabound carbonate-hosted Zn-Pb ore bodies. The mineralizations formed as fault, fracture and karst fillings in the Permian-Triassic formations, especially in Middle Triassic dolostones, and comprise mainly non-sulfides zinc ores. These are all interpreted as Mississippi Valley-type (MVT) base metal deposits. From an economic geological point of view, it is imperative to recognize the processes that have plausibly controlled the emplacement of MVT Zn-Pb mineralization in the Behabad district. To address the foregoing issue, analyses of the spatial distribution of mineral deposits comprising fry and fractal techniques and analysis of the spatial association of mineral deposits with geological features using distance distribution analysis were applied to assess the regional-scale processes that could have operated in the distribution of MVT Zn-Pb deposits in the district. The obtained results based on these analytical techniques show the main trends of the occurrences are NW-SE and NE-SW, which are parallel or subparallel to the major northwest and northeast trending faults, supporting the idea that these particular faults could have acted as the main conduits for transport of mineral-bearing fluids. The results of these analyses also suggest that Permian-Triassic brittle carbonate sedimentary rocks have served as the lithological controls on MVT mineralization in the Behabad district as they are spatially and temporally associated with mineralization.

  17. SOLID STATE ENERGY CONVERSION ALLIANCE (SECA) SOLID OXIDE FUEL CELL PROGRAM

    Energy Technology Data Exchange (ETDEWEB)

    Unknown

    2003-06-01

    This report summarizes the progress made during the September 2001-March 2002 reporting period under Cooperative Agreement DE-FC26-01NT41245 for the U. S. Department of Energy, National Energy Technology Laboratory (DOE/NETL) entitled ''Solid State Energy Conversion Alliance (SECA) Solid Oxide Fuel Cell Program''. The program focuses on the development of a low-cost, high-performance 3-to-10-kW solid oxide fuel cell (SOFC) system suitable for a broad spectrum of power-generation applications. The overall objective of the program is to demonstrate a modular SOFC system that can be configured to create highly efficient, cost-competitive, and environmentally benign power plants tailored to specific markets. When fully developed, the system will meet the efficiency, performance, life, and cost goals for future commercial power plants.

  18. Uranium analysis by neutron induced fissionography method using solid state nuclear track detectors

    International Nuclear Information System (INIS)

    Akyuez, T.; Tretyakova, S. P.; Guezel, T.; Akyuz, S.

    1999-01-01

    In this study total twenty samples (eight reference materials and twelve sediment samples) were analysed for their uranium content which is in the range of 1-17 μg/g, by neutron induced fissionography (NIF) method using solid state nuclear track detectors (SSNTDs) in comparison with the results of neutron activation analysis (NAA), delayed neutron counting (DNC) technique or fluorometric method. It is found that NIF method using SSNTDs is very sensitive for analysis of uranium

  19. Uranium analysis by neutron induced fissionography method using solid state nuclear track detectors

    CERN Document Server

    Akyuez, T; Guezel, T; Akyuz, S

    1999-01-01

    In this study total twenty samples (eight reference materials and twelve sediment samples) were analysed for their uranium content which is in the range of 1-17 mu g/g, by neutron induced fissionography (NIF) method using solid state nuclear track detectors (SSNTDs) in comparison with the results of neutron activation analysis (NAA), delayed neutron counting (DNC) technique or fluorometric method. It is found that NIF method using SSNTDs is very sensitive for analysis of uranium.

  20. The SoLid experiment

    Science.gov (United States)

    Kalousis, L. N.; SoLid Collaboration

    2017-09-01

    The SoLid experiment is a short-baseline project, probing the disappearance of reactor antineutrinos using a novel detector design. Installed at a very short distance of ˜ 5.5 - 10 m from the BR2 research reactor at SCK·CEN in Mol (Belgium) it will be able to search for active-to-sterile neutrino oscillations, exploring most of the allowed parameter region. SoLid will make use of a highly segmented detector, built from 5 cm PVT cubes, interleaved with 6LiF:ZnS(Ag) screens, and read out by optical fibers and Silicon Photomultipliers (SiPMs). The detector granularity allows for the localization of the positron and neutron signals from antineutrino interactions and the robust neutron identification capabilities, offered by the 6LiF:ZnS(Ag) inorganic scintillator, provide background suppression to an unparalleled level. This paper reviews the experimental layout and current status of SoLid. Emphasis is put on the challenges one faces towards this measurement, focusing on the decisions and strategy adapted by the SoLid collaboration. The analysis scheme and the details of the oscillation framework are also presented, highlighting the sensitivity contour and physics potential of SoLid. Finally, other physics topics, such as, reactor monitoring or measurement of the 235U spectrum are also covered.