WorldWideScience

Sample records for singlet potential energy

  1. Oxathiiranes 8 On the OCS2 Singlet Potential Energy Surface

    DEFF Research Database (Denmark)

    Carlsen, Lars

    1982-01-01

    as the fragmentations of the possible intermediates 1–5 have been studied theoretically within the semiempirical cndo/B framework as conceivable ground-state reactions. On the basis of mo correlations and potential energy changes along the reaction paths, supplementary with previously reported experimental data...

  2. Prediction of Tetraoxygen Reaction Mechanism with Sulfur Atom on the Singlet Potential Energy Surface

    Directory of Open Access Journals (Sweden)

    Ashraf Khademzadeh

    2014-01-01

    Full Text Available The mechanism of S+O4 (D2h reaction has been investigated at the B3LYP/6-311+G(3df and CCSD levels on the singlet potential energy surface. One stable complex has been found for the S+O4 (D2h reaction, IN1, on the singlet potential energy surface. For the title reaction, we obtained four kinds of products at the B3LYP level, which have enough thermodynamic stability. The results reveal that the product P3 is spontaneous and exothermic with −188.042 and −179.147 kcal/mol in Gibbs free energy and enthalpy of reaction, respectively. Because P1 adduct is produced after passing two low energy level transition states, kinetically, it is the most favorable adduct in the 1S+1O4 (D2h atmospheric reactions.

  3. Global potential energy surface of ground state singlet spin O4

    Science.gov (United States)

    Mankodi, Tapan K.; Bhandarkar, Upendra V.; Puranik, Bhalchandra P.

    2018-02-01

    A new global potential energy for the singlet spin state O4 system is reported using CASPT2/aug-cc-pVTZ ab initio calculations. The geometries for the six-dimensional surface are constructed using a novel point generation scheme that employs randomly generated configurations based on the beta distribution. The advantage of this scheme is apparent in the reduction of the number of required geometries for a reasonably accurate potential energy surface (PES) and the consequent decrease in the overall computational effort. The reported surface matches well with the recently published singlet surface by Paukku et al. [J. Chem. Phys. 147, 034301 (2017)]. In addition to the O4 PES, the ground state N4 PES is also constructed using the point generation scheme and compared with the existing PES [Y. Paukku et al., J. Chem. Phys. 139, 044309 (2013)]. The singlet surface is constructed with the aim of studying high energy O2-O2 collisions and predicting collision induced dissociation cross section to be used in simulating non-equilibrium aerothermodynamic flows.

  4. Intramolecular Singlet Fission in Quinoidal Bi- and Tetrathiophenes: A Comparative Study of Low-Lying Excited Electronic States and Potential Energy Surfaces.

    Science.gov (United States)

    Momeni, Mohammad R

    2016-10-11

    Quinoidal bithiophene has recently been introduced ( Varnavski, O. et al. J. Phys. Chem. Lett. 2015 , 6 , 1375 - 1384 ) as a very promising isolated organic compound for intramolecular singlet fission (iSF) with an outstanding SF quantum yield of ≈180%. In contrast, another recent study ( Ren, L. et al. J. Am. Chem. Soc. 2015 , 137 , 11294 - 11302 ) revealed that quinoidal tetrathiophenes have no activity in the iSF process and are strong fluorophores instead, with measured fluorescent quantum yields up to 53.1%. Using DFT and TD-DFT methods, the authors of the second contribution attributed the marked differences between these compounds to faster reverse T 2 → S 1 intersystem crossing processes in the tetrathiophenes. To address this unprecedented discrepancy, quinoidal bithiophene and tetrathiophene compounds and their derivatives are carefully examined using the CASPT2 technique. Theoretical evidence is provided through detailed investigation of CASPT2 potential energy surfaces of different singlet and triplet states involved in the iSF process. Through comparison of the CASPT2 results with the CASSCF and RAS-2SF data, it is found that the dynamic electron correlation present in the CASPT2 method plays a crucial role for correct description of the multiexciton nature of the triplet pair 1 [TT] state in quinoidal bi- and tetrathiophenes. Effects of substitution and structural modification on iSF activity of these compounds are also examined using the CASPT2 method where the obtained results are in accordance with previous experimental predictions. These results contribute to a better understanding of the iSF mechanism in quinoidal systems which could be relevant for designing new iSF active compounds.

  5. Is π-Stacking Prone To Accelerate Singlet-Singlet Energy Transfers?

    Science.gov (United States)

    Gao, Di; Aly, Shawkat M; Karsenti, Paul-Ludovic; Harvey, Pierre D

    2018-03-23

    π-Stacking is the most common structural feature that dictates the optical and electronic properties of chromophores in the solid state. Herein, a unidirectional singlet-singlet energy-transfer dyad has been designed to test the effect of π-stacking of zinc(II) porphyrin, [Zn 2 ], as a slipped dimer acceptor using a BODIPY unit, [bod], as the donor, bridged by the linker C 6 H 4 C≡CC 6 H 4 . The rate of singlet energy transfer, k ET (S 1 ), at 298 K ( k ET (S 1 ) = 4.5 × 10 10 s -1 ) extracted through the change in fluorescence lifetime, τ F , of [bod] in the presence (27.1 ps) and the absence of [Zn 2 ] (4.61 ns) from Streak camera measurements, and the rise time of the acceptor signal in femtosecond transient absorption spectra (22.0 ps), is faster than most literature cases where no π-stacking effect exists (i.e., monoporphyrin units). At 77 K, the τ F of [bod] increases to 45.3 ps, indicating that k ET (S 1 ) decreases by 2-fold (2.2 × 10 10 s -1 ), a value similar to most values reported in the literature, thus suggesting that the higher value at 298 K is thermally promoted at a higher temperature.

  6. Color-singlet instantaneous potential in the coulomb gauge QCD

    International Nuclear Information System (INIS)

    Nakagawa, Yoshiyuki; Toki, Hiroshi; Nakamura, Atsushi; Saito, Takuya

    2007-01-01

    We study the Coulomb gauge confinement mechanism in the quenched lattice QCD simulations. It is found that the color-Coulomb instantaneous potential in the color-singlet channel between two quarks grows linearly at large distances; namely, the color-Coulomb interaction is a source of color confinement. However, the linearity of this potential remains even in the quark-gluon plasma phase. We discuss the relation between this thermal Coulomb-string tension and a magnetic scaling introduced as an infrared cutoff of the thermal QCD theory. (author)

  7. Reaction Dynamics of O((3)P) + Propyne: II. Primary Products, Branching Ratios, and Role of Intersystem Crossing from Ab Initio Coupled Triplet/Singlet Potential Energy Surfaces and Statistical Calculations.

    Science.gov (United States)

    Gimondi, Ilaria; Cavallotti, Carlo; Vanuzzo, Gianmarco; Balucani, Nadia; Casavecchia, Piergiorgio

    2016-07-14

    The mechanism of the O((3)P) + CH3CCH reaction was investigated using a combined experimental/theoretical approach. Experimentally the reaction dynamics was studied using crossed molecular beams (CMB) with mass-spectrometric detection and time-of-flight analysis at 9.2 kcal/mol collision energy. Theoretically master equation (ME) simulations were performed on a potential energy surface (PES) determined using high-level ab initio electronic structure calculations. In this paper (II) the theoretical results are described and compared with experiments, while in paper (I) are reported and discussed the results of the experimental study. The PES was investigated by determining structures and vibrational frequencies of wells and transition states at the CASPT2/aug-cc-pVTZ level using a minimal active space. Energies were then determined at the CASPT2 level increasing systematically the active space and at the CCSD(T) level extrapolating to the complete basis set limit. Two separate portions of the triplet PES were investigated, as O((3)P) can add either on the terminal or the central carbon of the unsaturated propyne bond. Minimum energy crossing points (MECPs) between the triplet and singlet PESs were searched at the CASPT2 level. The calculated spin-orbit coupling constants between the T1 and S0 electronic surfaces were ∼25 cm(-1) for both PESs. The portions of the singlet PES that can be accessed from the MECPs were investigated at the same level of theory. The system reactivity was predicted integrating stochastically the one-dimensional ME using Rice-Ramsperger-Kassel-Marcus theory to determine rate constants on the full T1/S0 PESs, accounting explicitly for intersystem crossing (ISC) using the Landau-Zener model. The computational results are compared both with the branching ratios (BRs) determined experimentally in the companion paper (I) and with those estimated in a recent kinetic study at 298 K. The ME results allow to interpret the main system reactivity: CH

  8. Predicting singlet-triplet energy splittings with projected Hartree-Fock methods.

    Science.gov (United States)

    Rivero, Pablo; Jiménez-Hoyos, Carlos A; Scuseria, Gustavo E

    2013-08-22

    Hartree-Fock (HF) and density functional theory (DFT) methods are known for having problems in predicting singlet-triplet energy splittings when the system displays significant diradical character. Multireference methods are traditionally advocated to deal with the spin-contamination problem inherent in broken-symmetry mean-field methods. In the present work, spin-contamination is rigorously eliminated by means of a symmetry projection approach, carried out in a variation-after-projection fashion, recently implemented in our research group. We here explore the performance of a variety of projected Hartree-Fock (PHF) approaches (SUHF, KSUHF, SGHF, and KSGHF) in predicting singlet-triplet energy gaps in a broad set of diradical systems: small diatomic molecules, carbenes and silenes, and a few larger molecules (trimethylenemethane and benzyne isomers). For most of these systems, accurate experimental data is available in the literature. Additionally, we assess the quality of the geometrical parameters obtained in SUHF-based optimizations for some of the systems considered. Our results indicate that PHF methods yield high-quality multireference wave functions, providing a good description of the ground state potential surface as well as an accurate singlet-triplet splitting gap, all within a modest mean-field computational cost.

  9. Preorganized Chromophores Facilitate Triplet Energy Migration, Annihilation and Upconverted Singlet Energy Collection.

    Science.gov (United States)

    Mahato, Prasenjit; Yanai, Nobuhiro; Sindoro, Melinda; Granick, Steve; Kimizuka, Nobuo

    2016-05-25

    Photon upconversion (UC) based on triplet-triplet annihilation (TTA) has the potential to enhance significantly photovoltaic and photocatalytic efficiencies by harnessing sub-bandgap photons, but the progress of this field is held back by the chemistry problem of how to preorganize multiple chromophores for efficient UC under weak solar irradiance. Recently, the first maximization of UC quantum yield at solar irradiance was achieved using fast triplet energy migration (TEM) in metal-organic frameworks (MOFs) with ordered acceptor arrays, but at the same time, a trade-off between fast TEM and high fluorescence efficiency was also found. Here, we provide a solution for this trade-off issue by developing a new strategy, triplet energy migration, annihilation and upconverted singlet energy collection (TEM-UPCON). The porous structure of acceptor-based MOF crystals allows triplet donor molecules to be accommodated without aggregation. The surface of donor-doped MOF nanocrystals is modified with highly fluorescent energy collectors through coordination bond formation. Thanks to the higher fluorescence quantum yield of surface-bound collectors than parent MOFs, the implementation of the energy collector greatly improves the total UC quantum yield. The UC quantum yield maximization behavior at ultralow excitation intensity was retained because the TTA events take place only in the MOF acceptors. The TEM-UPCON concept may be generalized to collectors with various functions and would lead to quantitative harvesting of upconverted energy, which is difficult to achieve in common molecular diffusion-based systems.

  10. Singlet oxygen mediated DNA degradation by copper nanoparticles: potential towards cytotoxic effect on cancer cells

    OpenAIRE

    Sengupta Tapas K; Mandal Swadhin K; Santra Subhankar; Jose Gregor P

    2011-01-01

    Abstract The DNA degradation potential and anti-cancer activities of copper nanoparticles of 4-5 nm size are reported. A dose dependent degradation of isolated DNA molecules by copper nanoparticles through generation of singlet oxygen was observed. Singlet oxygen scavengers such as sodium azide and Tris [hydroxyl methyl] amino methane were able to prevent the DNA degradation action of copper nanoparticles confirming the involvement of activated oxygen species in the degradation process. Addit...

  11. Efficient singlet-singlet energy transfer in a novel host-guest assembly composed of an organic cavitand, aromatic molecules, and a clay nanosheet.

    Science.gov (United States)

    Ishida, Yohei; Kulasekharan, Revathy; Shimada, Tetsuya; Takagi, Shinsuke; Ramamurthy, V

    2013-02-12

    A supramolecular host-guest assembly composed of a cationic organic cavitand (host), neutral aromatic molecules (guests), and an anionic clay nanosheet has been prepared and demonstrated that in this arrangement efficient singlet-singlet energy transfer could take place. The novelty of this system is the use of a cationic organic cavitand that enabled neutral organic molecules to be placed on an anionic saponite nanosheet. Efficient singlet-singlet energy transfer between neutral pyrene and 2-acetylanthracene enclosed within a cationic organic cavitand (octa amine) arranged on a saponite nanosheet was demonstrated through steady-state and time-resolved emission studies. The high efficiency was realized from the suppression of aggregation, segregation, and self-fluorescence quenching. We believe that the studies presented here using a novel supramolecular assembly have expanded the types of molecules that could serve as candidates for efficient energy-transfer systems, such as in an artificial light-harvesting system.

  12. Energy transfer within Zn-porphyrin dendrimers: Study of the singlet-singlet annihilation kinetics

    Czech Academy of Sciences Publication Activity Database

    Larsen, J.; Brüggemann, B.; Polívka, Tomáš; Sundström, V.; Akesson, E.; Sly, J.; Crossley, M.J.

    2005-01-01

    Roč. 109, č. 47 (2005), s. 10654-10662 ISSN 1089-5639 Institutional research plan: CEZ:AV0Z50510513 Keywords : Energy transfer * Zn-porphyrin Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 2.898, year: 2005

  13. The singlet-triplet energy gap in divalent three, five and seven ...

    African Journals Online (AJOL)

    The singlet-triplet energy gap in divalent three, five and seven-membered cyclic C2H2M, C4H4M and C6H6M (M = C, Si, Ge, Sn AND Pb) ... Nuclear independent chemical shifts (NICS) calculations were carried out for determination of aromatic character. The geometrical parameters are calculated and discussed.

  14. Singlet Fission

    Czech Academy of Sciences Publication Activity Database

    Smith, M. B.; Michl, Josef

    2010-01-01

    Roč. 110, č. 11 (2010), s. 6891-6936 ISSN 0009-2665 Grant - others:Department of Energy(US) DE- FG36 -08GO18017 Institutional research plan: CEZ:AV0Z40550506 Keywords : solar energy conversion * photovoltaics * singlet fission Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 33.033, year: 2010

  15. Search for Singlet Fission Chromophores

    Energy Technology Data Exchange (ETDEWEB)

    Havlas, Z.; Akdag, A.; Smith, M. B.; Dron, P.; Johnson, J. C.; Nozik, A. J.; Michl, J.

    2012-01-01

    Singlet fission, in which a singlet excited chromophore shares its energy with a ground-state neighbor and both end up in their triplet states, is of potential interest for solar cells. Only a handful of compounds, mostly alternant hydrocarbons, are known to perform efficiently. In view of the large number of conditions that a successful candidate for a practical cell has to meet, it appears desirable to extend the present list of high performers to additional classes of compounds. We have (i) identified design rules for new singlet fission chromophores and for their coupling to covalent dimers, (ii) synthesized them, and (iii) evaluated their performance as neat solids or covalent dimers.

  16. Singlet-triplet splittings from the virial theorem and single-particle excitation energies

    Science.gov (United States)

    Becke, Axel D.

    2018-01-01

    The zeroth-order (uncorrelated) singlet-triplet energy difference in single-particle excited configurations is 2Kif, where Kif is the Coulomb self-energy of the product of the transition orbitals. Here we present a non-empirical, virial-theorem argument that the correlated singlet-triplet energy difference should be half of this, namely, Kif. This incredibly simple result gives vertical HOMO-LUMO excitation energies in small-molecule benchmarks as good as the popular TD-B3LYP time-dependent approach to excited states. For linear acenes and nonlinear polycyclic aromatic hydrocarbons, the performance is significantly better than TD-B3LYP. In addition to the virial theorem, the derivation borrows intuitive pair-density concepts from density-functional theory.

  17. Singlet oxygen mediated DNA degradation by copper nanoparticles: potential towards cytotoxic effect on cancer cells

    Directory of Open Access Journals (Sweden)

    Sengupta Tapas K

    2011-03-01

    Full Text Available Abstract The DNA degradation potential and anti-cancer activities of copper nanoparticles of 4-5 nm size are reported. A dose dependent degradation of isolated DNA molecules by copper nanoparticles through generation of singlet oxygen was observed. Singlet oxygen scavengers such as sodium azide and Tris [hydroxyl methyl] amino methane were able to prevent the DNA degradation action of copper nanoparticles confirming the involvement of activated oxygen species in the degradation process. Additionally, it was observed that the copper nanoparticles are able to exert cytotoxic effect towards U937 and Hela cells of human histiocytic lymphoma and human cervical cancer origins, respectively by inducing apoptosis. The growth characteristics of U937 and Hela cells were studied applying various concentrations of the copper nanoparticles.

  18. Singlet oxygen mediated DNA degradation by copper nanoparticles: potential towards cytotoxic effect on cancer cells.

    Science.gov (United States)

    Jose, Gregor P; Santra, Subhankar; Mandal, Swadhin K; Sengupta, Tapas K

    2011-03-25

    The DNA degradation potential and anti-cancer activities of copper nanoparticles of 4-5 nm size are reported. A dose dependent degradation of isolated DNA molecules by copper nanoparticles through generation of singlet oxygen was observed. Singlet oxygen scavengers such as sodium azide and Tris [hydroxyl methyl] amino methane were able to prevent the DNA degradation action of copper nanoparticles confirming the involvement of activated oxygen species in the degradation process. Additionally, it was observed that the copper nanoparticles are able to exert cytotoxic effect towards U937 and Hela cells of human histiocytic lymphoma and human cervical cancer origins, respectively by inducing apoptosis. The growth characteristics of U937 and Hela cells were studied applying various concentrations of the copper nanoparticles.

  19. Effects of fermionic singlet neutrinos on high- and low-energy observables

    International Nuclear Information System (INIS)

    Weiland, C.

    2013-01-01

    In this doctoral thesis, we study both low- and high-energy observables related to massive neutrinos. Neutrino oscillations have provided indisputable evidence in favour of non-zero neutrino masses and mixings. However, the original formulation of the standard model cannot account for these observations, which calls for the introduction of new physics. Among many possibilities, we focus here on the inverse seesaw, a neutrino mass generation mechanism in which the standard model is extended with fermionic gauge singlets. This model offers an attractive alternative to the usual seesaw realisations since it can potentially have natural Yukawa couplings (O(1)) while keeping the new physics scale at energies within the reach of the LHC. Among the many possible effects, this scenario can lead to deviations from lepton flavour universality. We have investigated these signatures and found that the ratios R K and R π provide new, additional constraints on the inverse seesaw. We have also considered the embedding of the inverse seesaw in supersymmetric models. This leads to increased rates for various lepton flavour violating processes, due to enhanced contributions from penguin diagrams mediated by the Higgs and Z 0 bosons. Finally, we also found that the new invisible decay channels associated with the sterile neutrinos present in the super-symmetric inverse seesaw could significantly weaken the constraints on the mass and couplings of a light CP-odd Higgs boson. (author)

  20. Focal point analysis of the singlet-triplet energy gap of octacene and larger acenes.

    Science.gov (United States)

    Hajgató, Balázs; Huzak, Matija; Deleuze, Michael S

    2011-08-25

    A benchmark theoretical study of the electronic ground state and of the vertical and adiabatic singlet-triplet (ST) excitation energies of n-acenes (C(4n+2)H(2n+4)) ranging from octacene (n = 8) to undecacene (n = 11) is presented. The T1 diagnostics of coupled cluster theory and further energy-based criteria demonstrate that all investigated systems exhibit predominantly a (1)A(g) singlet closed-shell electronic ground state. Singlet-triplet (S(0)-T(1)) energy gaps can therefore be very accurately determined by applying the principle of a focal point analysis (FPA) onto the results of a series of single-point and symmetry-restricted calculations employing correlation consistent cc-pVXZ basis sets (X = D, T, Q, 5) and single-reference methods [HF, MP2, MP3, MP4SDQ, CCSD, and CCSD(T)] of improving quality. According to our best estimates, which amount to a dual extrapolation of energy differences to the level of coupled cluster theory including single, double, and perturbative estimates of connected triple excitations [CCSD(T)] in the limit of an asymptotically complete basis set (cc-pV∞Z), the S(0)-T(1) vertical (adiabatic) excitation energies of these compounds amount to 13.40 (8.21), 10.72 (6.05), 8.05 (3.67), and 7.10 (2.58) kcal/mol, respectively. In line with the absence of Peierls distortions (bond length alternations), extrapolations of results obtained at this level for benzene (n = 1) and all studied n-acenes so far (n = 2-11) indicate a vanishing S(0)-T(1) energy gap, in the limit of an infinitely large polyacene, within an uncertainty of 1.5 kcal/mol (0.06 eV). Lacking experimental values for the S(0)-T(1) energy gaps of n-acenes larger than hexacene, comparison is made with recent optical and electrochemical determinations of the HOMO-LUMO band gap. Further issues such as scalar relativistic, core correlation, and diagonal Born-Oppenheimer corrections (DBOCs) are tentatively examined. © 2011 American Chemical Society

  1. Singlet and triplet energy transfer dynamics in self-assembled axial porphyrin-anthracene complexes: towards supra-molecular structures for photon upconversion.

    Science.gov (United States)

    Gray, Victor; Küçüköz, Betül; Edhborg, Fredrik; Abrahamsson, Maria; Moth-Poulsen, Kasper; Albinsson, Bo

    2018-03-14

    Energy and electron transfer reactions are central to many different processes and research fields, from photosynthesis and solar energy harvesting to biological and medical applications. Herein we report a comprehensive study of the singlet and triplet energy transfer dynamics in porphyrin-anthracene coordination complexes. Seven newly synthesized pyridine functionalized anthracene ligands, five with various bridge lengths and two dendrimer structures containing three and seven anthracene units, were prepared. We found that triplet energy transfer from ruthenium octaethylporphyrin to an axially coordinated anthracene is possible, and is in some cases followed by back triplet energy transfer to the porphyrin. The triplet energy transfer follows an exponential distance dependence with an attenuation factor, β, of 0.64 Å -1 . Further, singlet energy transfer from anthracene to the ruthenium porphyrin appears to follow a R 6 Förster distance dependence. Porphyrin-anthracene complexes are also used as triplet sensitizers for triplet-triplet annihilation (TTA) based photon upconversion, demonstrating their potential for photophysical and photochemical applications. The triplet lifetime of the complex is extended by the anthracene ligands, resulting in a threefold increase in the upconversion efficiency, Φ UC to 4.5%, compared to the corresponding ruthenium porphyrin-pyridine complex. Based on the results herein we discuss the future design of supra-molecular structures for TTA upconversion.

  2. Low energy gamma ray excess confronting a singlet scalar extended inert doublet dark matter model

    Directory of Open Access Journals (Sweden)

    Amit Dutta Banik

    2015-04-01

    Full Text Available Recent study of gamma rays originating from the region of galactic centre has confirmed an anomalous γ-ray excess within the energy range 1–3 GeV. This can be explained as the consequence of pair annihilation of a 31–40 GeV dark matter into bb¯ with thermal annihilation cross-section σv∼1.4–2.0×10−26 cm3/s. In this work we revisit the Inert Doublet Model (IDM in order to explain this gamma ray excess. Taking the lightest inert particle (LIP as a stable DM candidate we show that a 31–40 GeV dark matter derived from IDM will fail to satisfy experimental limits on dark matter direct detection cross-section obtained from ongoing direct detection experiments and is also inconsistent with LHC findings. We show that a singlet extended inert doublet model can easily explain the reported γ-ray excess which is as well in agreement with Higgs search results at LHC and other observed results like DM relic density and direct detection constraints.

  3. Blinking fluorescence of single donor-acceptor pairs: important role of "dark'' states in resonance energy transfer via singlet levels.

    Science.gov (United States)

    Osad'ko, I S; Shchukina, A L

    2012-06-01

    The influence of triplet levels on Förster resonance energy transfer via singlet levels in donor-acceptor (D-A) pairs is studied. Four types of D-A pair are considered: (i) two-level donor and two-level acceptor, (ii) three-level donor and two-level acceptor, (iii) two-level donor and three-level acceptor, and (iv) three-level donor and three-level acceptor. If singlet-triplet transitions in a three-level acceptor molecule are ineffective, the energy transfer efficiency E=I_{A}/(I_{A}+I_{D}), where I_{D} and I_{A} are the average intensities of donor and acceptor fluorescence, can be described by the simple theoretical equation E(F)=FT_{D}/(1+FT_{D}). Here F is the rate of energy transfer, and T_{D} is the donor fluorescence lifetime. In accordance with the last equation, 100% of the donor electronic energy can be transferred to an acceptor molecule at FT_{D}≫1. However, if singlet-triplet transitions in a three-level acceptor molecule are effective, the energy transfer efficiency is described by another theoretical equation, E(F)=F[over ¯](F)T_{D}/[1+F[over ¯](F)T_{D}]. Here F[over ¯](F) is a function of F depending on singlet-triplet transitions in both donor and acceptor molecules. Expressions for the functions F[over ¯](F) are derived. In this case the energy transfer efficiency will be far from 100% even at FT_{D}≫1. The character of the intensity fluctuations of donor and acceptor fluorescence indicates which of the two equations for E(F) should be used to find the value of the rate F. Therefore, random time instants of photon emission in both donor and acceptor fluorescence are calculated by the Monte Carlo method for all four types of D-A pair. Theoretical expressions for start-stop correlators (waiting time distributions) in donor and acceptor fluorescence are derived. The probabilities w_{N}^{D}(t) and w_{N}^{A}(t) of finding N photons of donor and acceptor fluorescence in the time interval t are calculated for various values of the energy

  4. Roles of binding energy and diffusion length of singlet and triplet excitons in organic heterojunction solar cells

    International Nuclear Information System (INIS)

    Narayan, Monishka Rita; Singh, Jai

    2012-01-01

    The influence of binding energy and diffusion length on the dissociation of excitons in organic solids is studied. The binding energy and excitonic Bohr radius of singlet and triplet excitons are calculated and compared using the dissociation energy of 0.3 eV, which is provided by the lowest unoccupied molecular orbital offset in heterojunction organic solar cells. A relation between the diffusion coefficient and diffusion length of singlet and triplet excitons is derived using the Foerster and Dexter transfer processes and are plotted as a function of the donor-acceptor separation. The diffusion length reduces nearly to a zero if the distance between donor and acceptor is increased to more than 1.5 nm. It is found that the donor-acceptor separation needs to be ≤ 1.5 nm for easy dissociation on singlet excitons leading to better conversion efficiency in heterojunction organic solar cells. (copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  5. Roles of binding energy and diffusion length of singlet and triplet excitons in organic heterojunction solar cells

    Energy Technology Data Exchange (ETDEWEB)

    Narayan, Monishka Rita [Centre for Renewable Energy and Low Emission Technology, Charles Darwin University, Darwin, NT 0909 (Australia); Singh, Jai [School of Engineering and IT, Charles Darwin University, Darwin, NT 0909 (Australia)

    2012-12-15

    The influence of binding energy and diffusion length on the dissociation of excitons in organic solids is studied. The binding energy and excitonic Bohr radius of singlet and triplet excitons are calculated and compared using the dissociation energy of 0.3 eV, which is provided by the lowest unoccupied molecular orbital offset in heterojunction organic solar cells. A relation between the diffusion coefficient and diffusion length of singlet and triplet excitons is derived using the Foerster and Dexter transfer processes and are plotted as a function of the donor-acceptor separation. The diffusion length reduces nearly to a zero if the distance between donor and acceptor is increased to more than 1.5 nm. It is found that the donor-acceptor separation needs to be {<=} 1.5 nm for easy dissociation on singlet excitons leading to better conversion efficiency in heterojunction organic solar cells. (copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  6. Heavy quark free energies, potentials and the renormalized Polyakov loop

    International Nuclear Information System (INIS)

    Kaczmarek, O.; Karsch, F.; Petreczky, P.; Zantow, F.

    2004-01-01

    We discuss the renormalized free energy of a heavy quark anti-quark pair in the color singlet channel for quenched and full QCD at finite temperature. The temperature and mass dependence, as well as its short distance behavior is analyzed. Using the free energies we calculate the heavy quark potential and entropy in quenched QCD The asymptotic large distance behavior of the free energy is used to define the non-perturbatively renormalized Polyakov loop which is well behaved in the continuum limit. String breaking is studied in the color singlet channel in 2-flavor QCD

  7. Singlet Fission in Rubrene Derivatives: Impact of Molecular Packing

    KAUST Repository

    Sutton, Christopher

    2017-03-13

    We examine the properties of six recently synthesized rubrene derivatives (with substitutions on the side phenyl rings) that show vastly different crystal structures. In order to understand how packing in the solid state affects the excited states and couplings relevant for singlet fission, the lowest excited singlet (S), triplet (T), multiexciton (TT), and charge-transfer (CT) states of the rubrene derivatives are compared to known singlet fission materials [tetracene, pentacene, 5,12-diphenyltetracene (DPT), and rubrene itself]. While a small difference of less than 0.2 eV is calculated for the S and TT energies, a range of 0.50 to 1.2 eV in the CT energies and nearly 3 orders of magnitude in the electronic couplings are computed for the rubrene derivatives in their crystalline packings, which strongly affects the role of the CT state in facilitating SF. To rationalize experimental observations of singlet fission occurring in amorphous phases of rubrene, DPT, and tetracene, we use molecular dynamics (MD) simulations to assess the impact of molecular packing and orientations and to gain a better understanding of the parameters that control singlet fission in amorphous films compared to crystalline packings. The MD simulations point to a crystalline-like packing for thin films of tetracene; on the other hand, DPT, rubrene, and the rubrene derivatives all show various degrees of disorder with a number of sites that have larger electronic couplings than in the crystal, which can facilitate singlet fission in such thin films. Our analysis underlines the potential of these materials as promising candidates for singlet fission and helps understand how various structural motifs affect the critical parameters that control the ability of a system to undergo singlet fission.

  8. Anharmonic rovibrational calculations of singlet cyclic C{sub 4} using a new ab initio potential and a quartic force field

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Xiaohong; Bowman, Joel M., E-mail: jmbowma@emory.edu [Cherry L. Emerson Center for Scientific Computation and Department of Chemistry, Emory University, Atlanta, Georgia 30322 (United States); Huang, Xinchuan [SETI Institute, 189 Bernardo Ave, Suite 100, Mountain View, California 94043 (United States); Lee, Timothy J., E-mail: Timothy.J.Lee@nasa.gov [MS 245-1, NASA Ames Research Center, Mofffett Field, California 94035 (United States)

    2013-12-14

    We report a CCSD(T)/cc-pCV5Z quartic force field (QFF) and a semi-global CCSD(T)-F12b/aug-cc-pVTZ potential energy surface (PES) for singlet, cyclic C{sub 4}. Vibrational fundamentals, combinations, and overtones are obtained using vibrational second-order perturbation theory (VPT2) and the vibrational configuration-interaction (VCI) approach. Agreement is within 10 cm{sup −1} between the VCI calculated fundamentals on the QFF and PES using the MULTIMODE (MM) program, and VPT2 and VCI results agree for the fundamentals. The agreement between VPT2-QFF and MM-QFF results is also good for the C{sub 4} combinations and overtones. The J = 1 and J = 2 rovibrational energies are reported from both VCI (MM) on the PES and VPT2 on the QFF calculations. The spectroscopic constants of {sup 12}C{sub 4} and two C{sub 2v}-symmetry, single {sup 13}C-substituted isotopologues are presented, which may help identification of cyclic C{sub 4} in future experimental analyses or astronomical observations.

  9. Solar energy potential

    Science.gov (United States)

    1973-01-01

    The potential of solar energy as a national resource is discussed. Research and development programs for the development of eleven concepts are described to show the proposed funding for each year over a fifteen year period. The estimated energy contributions by period for each of the solar concepts are analyzed. The estimated impact of the solar concepts to the year 2020 are tabulated.

  10. Thiocyanate potentiates antimicrobial photodynamic therapy: In situ generation of the sulfur trioxide radical anion by singlet oxygen

    Science.gov (United States)

    St Denis, Tyler G.; Vecchio, Daniela; Zadlo, Andrzej; Rineh, Ardeshir; Sadasivam, Magesh; Avci, Pinar; Huang, Liyi; Kozinska, Anna; Chandran, Rakkiyappan; Sarna, Tadeusz; Hamblin, Michael R.

    2013-01-01

    Antimicrobial photodynamic therapy (PDT) is used for the eradication of pathogenic microbial cells and involves the light excitation of dyes in the presence of O2, yielding reactive oxygen species including the hydroxyl radical (•OH) and singlet oxygen (1O2). In order to chemically enhance PDT by the formation of longer-lived radical species, we asked whether thiocyanate (SCN−) could potentiate the methylene blue (MB) and light-mediated killing of the gram-positive Staphylococcus aureus and the gram-negative Escherichia coli. SCN− enhanced PDT (10 μM MB, 5J/cm2 660 nm hv) killing in a concentration-dependent manner of S. aureus by 2.5 log10 to a maximum of 4.2 log10 at 10 mM (P < 0.001) and increased killing of E. coli by 3.6 log10 to a maximum of 5.0 log10 at 10 mM (P < 0.01). We determined that SCN− rapidly depleted O2 from an irradiated MB system, reacting exclusively with 1O2, without quenching the MB excited triplet state. SCN− reacted with 1O2, producing a sulfur trioxide radical anion (a sulfur-centered radical demonstrated by EPR spin trapping). We found that MB-PDT of SCN− in solution produced both sulfite and cyanide anions, and that addition of each of these salts separately enhanced MB-PDT killing of bacteria. We were unable to detect EPR signals of •OH, which, together with kinetic data, strongly suggests that MB, known to produce •OH and 1O2, may, under the conditions used, preferentially form 1O2. PMID:23969112

  11. Benchmark theoretical study of the ionization energies, electron affinities and singlet-triplet energy gaps of azulene, phenanthrene, pyrene, chrysene and perylene

    Energy Technology Data Exchange (ETDEWEB)

    Huzak, M. [Theoretical Chemistry and Molecular Modelling, Hasselt University, Agoralaan, Gebouw D, B-3590 Diepenbeek (Belgium); Hajgato, B. [General Chemistry Division, Free University of Brussels (VUB), Pleinlaan 2, B-1050 Brussels (Belgium); Deleuze, M.S., E-mail: michael.deleuze@uhasselt.be [Theoretical Chemistry and Molecular Modelling, Hasselt University, Agoralaan, Gebouw D, B-3590 Diepenbeek (Belgium)

    2012-10-08

    Highlights: Black-Right-Pointing-Pointer Electronic properties of aromatic hydrocarbons are computed at benchmark levels. Black-Right-Pointing-Pointer Electron correlation has a very strong influence on the computed results. Black-Right-Pointing-Pointer The role of structural relaxation and zero-point vibrations is highlighted. Black-Right-Pointing-Pointer We approach chemical accuracy, using the principles of a focal point analysis. -- Abstract: The vertical and adiabatic singlet-triplet energy gaps, electron affinities and ionization energies of azulene, phenanthrene, pyrene, chrysene, and perylene are computed by applying the principles of a focal point analysis onto a series of single-point calculations at the level of Hartree-Fock theory, second-, third-, and fourth-order Moller-Plesset perturbation theory, as well as coupled cluster theory including single, double and perturbative triple excitations, in conjunction with correlation consistent basis sets of improving quality. Results are supplemented with an extrapolation to the limit of an asymptotically complete basis set. According to our best estimates, azulene, phenanthrene, pyrene, chrysene, and perylene exhibit adiabatic singlet-triplet energy gaps of 1.79, 2.92, 2.22, 2.79 and 1.71 eV, respectively. In the same order, the corresponding adiabatic electron affinities (EAs) amount to 0.71, -0.08, -0.40, 0.24, and 0.87 eV, whereas benchmark values equal to 7.43, 8.01, 7.48, 7.66 and 7.15 eV, are found for the adiabatic ionization energies.

  12. The effect of the silver nanoparticles on the dynamics of singlet-singlet energy transfer of luminophores in thin films of polyvinyl alcohol

    International Nuclear Information System (INIS)

    Bryukhanov, V.V.; Samusev, I.G.; Slezhkin, V.A.; Tsibul'nikova, A.V.

    2014-01-01

    The effect of ablated silver nanoparticles (ANP) on the dynamics of non-radiative inductance-resonance energy transfer and phosphorescence in the donor-acceptor pair of molecules of eosin and methylene blue (MB) luminophores embedded in thin films of polyvinyl alcohol have been investigated. Increased fluorescence intensity of donor (eosin) and acceptor (MB) molecules, as well as a growth of the dipole-dipole transfer efficiency have been obtained under the resonant excitation of the silver ANP surface plasmons in the absorption band of the donor energy. The luminescence quantum yields and the fluorescence lifetimes have been measured. The energy transfer constants, degree of polarization and fluorescence anisotropy have been determined. (authors)

  13. Zethrene biradicals: How pro-aromaticity is expressed in the ground electronic state and in the lowest energy singlet, triplet, and ionic states

    Science.gov (United States)

    Zafra, José Luis; González Cano, Rafael C.; Ruiz Delgado, M. Carmen; Sun, Zhe; Li, Yuan; López Navarrete, Juan T.; Wu, Jishan; Casado, Juan

    2014-02-01

    A analysis of the electronic and molecular structures of new molecular materials based on zethrene is presented with particular attention to those systems having a central benzo-quinoidal core able to generate Kekulé biradicals whose stability is provided by the aromaticity recovery in this central unit. These Kekulé biradicals display singlet ground electronic states thanks to double spin polarization and have low-energy lying triplet excited states also featured by the aromaticity gain. Pro-aromatization is also the driving force for the stabilization of the ionized species. Moreover, the low energy lying singlet excited states also display a profound biradical fingerprint allowing to singlet exciton fission. These properties are discussed in the context of the size of the zethrene core and of its substitution. The work encompasses all known long zethrenes and makes use of a variety of experimental techniques, such as Raman, UV-Vis-NIR absorption, transient absorption, in situ spectroelectrochemistry and quantum chemical calculations. This study reveals how the insertion of suitable molecular modules (i.e., quinoidal) opens the door to new intriguing molecular properties exploitable in organic electronics.

  14. High-efficiency fluorescent organic light-emitting devices using sensitizing hosts with a small singlet-triplet exchange energy.

    Science.gov (United States)

    Zhang, Dongdong; Duan, Lian; Li, Chen; Li, Yilang; Li, Haoyuan; Zhang, Deqiang; Qiu, Yong

    2014-08-06

    Materials with small singlet-triplet splits (ΔEST s) are introduced as sensitizing hosts to excite fluorescent dopants, breaking the trade-off between small ΔEST and high radiative decay rates. A highly efficient orange-fluorescent organic light-emitting diode (OLED) is prepared, showing a maximum external quantum efficiency of 12.2%. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  15. Probing color-singlet exchange at D0

    International Nuclear Information System (INIS)

    Abbott, B.; Abolins, M.; Acharya, B.S.

    1997-07-01

    We present latest preliminary results on hard color-singlet exchange in proton-antiproton collisions. The fraction of dijet events produced via color-singlet exchange is measured as a function of jet transverse energy, dijet pseudorapidity separation, and proton-antiproton center-of-mass energy. These results are qualitatively consistent with a color-singlet fraction that increases with increasing quark-initiated processes

  16. Stability of singlet and triplet trions in carbon nanotubes

    International Nuclear Information System (INIS)

    Ronnow, Troels F.; Pedersen, Thomas G.; Cornean, Horia D.

    2009-01-01

    We investigate singlet and triplet trion states in semiconducting carbon nanotubes using a one-dimensional model. It is concluded that singlet trion states in bind up to 13.6% stronger than exciton states, and that they lower the optical transition energy with up to 50% of the tight binding band gap energy.

  17. Confinement sensitivity in quantum dot singlet-triplet relaxation

    Science.gov (United States)

    Wesslén, C. J.; Lindroth, E.

    2017-11-01

    Spin-orbit mediated phonon relaxation in a two-dimensional quantum dot is investigated using different confining potentials. Elliptical harmonic oscillator and cylindrical well results are compared to each other in the case of a two-electron GaAs quantum dot subjected to a tilted magnetic field. The lowest energy set of two-body singlet and triplet states are calculated including spin-orbit and magnetic effects. These are used to calculate the phonon induced transition rate from the excited triplet to the ground state singlet for magnetic fields up to where the states cross. The roll of the cubic Dresselhaus effect, which is found to be much more important than previously assumed, and the positioning of ‘spin hot-spots’ are discussed and relaxation rates for a few different systems are exhibited.

  18. The potential of biogas energy

    International Nuclear Information System (INIS)

    Acaroglu, M.; Hepbasli, A.; Kocar, G.

    2005-01-01

    Biogas technology has been known about for a long time, but in recent years the interest in it has significantly increased, especially due to the higher costs and the rapid depletion of fossil fuels as well as their environmental considerations. The main objective of the present study is to investigate the potential of biogas energy in the 15 European Union (EU) countries and in Turkey, which is seeking admission to the EU and is trying to meet EU environmental standards. Biogas energy potential of the 15 EU countries is estimated to be about 800 PJ. Besides this, Turkey's annual animal waste potential is obtained to be about 11.81 million tons with a biogas energy equivalent of 53.6 PJ. It is expected that this study will be helpful in developing highly applicable and productive planning for energy policies towards the optimum utilization of biogas energy. (author)

  19. Nuclear energy: potentiality and implications

    International Nuclear Information System (INIS)

    Bahgat, Gawdat

    2008-01-01

    After a discussion about a broad definition of energy security and about the main challenges facing a potential nuclear renaissance, the article analyses how the European Union and the United States have addressed these challenges. There is no doubt that nuclear power will remain an important component of global energy mix, but it should not be seen as a panacea to the flows in the global energy markets [it

  20. Biowaste energy potential in Kenya

    International Nuclear Information System (INIS)

    Nzila, Charles; Dewulf, Jo; van Langenhove, Herman; Spanjers, Henri; Kiriamiti, Henry

    2010-01-01

    Energy affects all aspects of national development. Hence the current global energy crisis demands greater attention to new initiatives on alternative energy sources that are renewable, economically feasible and sustainable. The agriculture-dependent developing countries in Africa can mitigate the energy crisis through innovative use of the available but underutilised biowaste such as organic residues from maize, barley, cotton, tea and sugarcane. Biogas technology is assumed to have the capacity to economically and sustainably convert these vast amounts of biowaste into renewable energy, thereby replacing the unsustainable fossil energy sources, and reducing dependency on fossil fuels. However, the total energy potential of biogas production from crop residues available in Kenya has never been evaluated and quantified. To this end, we selected five different types of residues (maize, barley, cotton, tea and sugarcane) from Kenya and evaluated their energy potential through biomethane potential analysis at 30 C and a test time of 30 days. The specific methane yields for maize, barley, cotton, tea and sugarcane residues obtained under batch conditions were respectively 363, 271, 365, 67 and 177 m 3 per tonne volatile solids. In terms of energy potential, maize, cotton and barley residues were found to be better substrates for methane production than tea and sugarcane residues and could be considered as potential substrates or supplements for methane production without compromising food security in the country. The evaluated residues have a combined national annual maximum potential of about 1313 million cubic meters of methane which represent about 3916 Gigawatt hour (GWh) of electricity and 5887 GWh of thermal energy. The combined electrical potential is equivalent to 73% of the country's annual power production of 5307 GWh. Utilization of the residues that are readily available on a 'free on site' basis for energy production could substitute the fossil fuels that

  1. World potential of renewable energies

    Energy Technology Data Exchange (ETDEWEB)

    Dessus, B.; Devin, B.; Pharabod, F.

    1991-07-01

    A comprehensive analysis, region by region, of the actually accessible renewable energies at a given horizon, is presented. The same methodology as the one employed to derive ``proven fossil energy reserves`` from ``energy resources`` is adopted, in which resources are defined by quantitative information on physical potential, while reserves take into account technical and economical accessibility. As renewable resources are fluctuating with time and are diluted in space and not readily transportable or storeable, it is necessary to consider the presence of populations or activities near enough to be able to profit by these diluted and volatile energies.

  2. Stability of singlet and triplet trions in carbon nanotubes

    DEFF Research Database (Denmark)

    Rønnow, Troels Frimodt; Pedersen, Thomas Garm; Cornean, Horia

    2009-01-01

    We investigate singlet and triplet trion states in semiconducting carbon nanotubes using a one-dimensional model. It is concluded that singlet trion states in bind up to 13.5% stronger than exciton states, and that they lower the optical transition energy with up to 50% of the tight binding band...

  3. Renewable energy potential in Colombia

    Science.gov (United States)

    Correa Guzman, Jose Luis

    2008-12-01

    Renewable energy flows are very large in comparison with humankind's use of energy. In principle, all our energy needs, both now and into the future, can be met by energy from renewable sources. After many years trying to develop the alternative energy potential of Colombia, a major effort is principally being made since 2000 to explore and assess the renewable resources of the entire country. Until 2000, the availability of conventional energy sources in Colombia prevented renewable energy exploration from reaching a higher level. However, the extreme energy crisis of 1992 - 1993 alerted the authorities and the community to the necessity for exploring alternative energy sources. This energy study is a general approach to the current and future renewable energy scenario of Colombia. It was prepared in response to the increased interest around the world and in particular in Colombia to develop its non-fossil energy prospective. It, therefore, represents a working document giving an initial impression of the possible scale of the main renewables sources as a response to the concern about energy security and fossil fuel dependence problems. The assumptions made and calculations reported may therefore be subject to revision as more information becomes available. The aim of this dissertation is not only to improve the public understanding and discussion of renewable energy matters in Colombia but also to stimulate the development and application of renewable energy, wherever they have prospects of economic viability and environmental acceptability. To achieve such goal this paper reviews several renewable technologies, their availability, contribution and feasibility in Colombia.

  4. MR spectroscopy of intracranial tuberculomas: A singlet peak at 3.8 ppm as potential marker to differentiate them from malignant tumors.

    Science.gov (United States)

    Morales, Humberto; Alfaro, David; Martinot, Carlos; Fayed, Nicolas; Gaskill-Shipley, Mary

    2015-06-01

    The diagnosis of intracranial tuberculomas is often challenging. Our purpose is to describe the most common metabolic patterns of tuberculomas by MR spectroscopy (MRS) with emphasis on potential specific markers. Single-voxel MRS short echo time was performed in 13 cases of tuberculomas proven by histology and/or response to anti-mycobacterial therapy. For comparison MRS was also performed in 19 biopsy-proven malignant tumors (13 high-grade gliomas and six metastasis). Presence of metabolic peaks was assessed visually and categorical variables between groups were compared using chi-square. Metabolite ratios were compared using Mann-Whitney test and diagnostic accuracy of the metabolite ratios was compared using receiver-operating characteristic (ROC) curves analysis. Spectroscopic peaks representing lipids and glutamate/glutamine (Glx) as well as a peak at ∼3.8 ppm were well defined in 77% (10/13), 77% (10/13) and 69% (nine of 13) of tuberculomas, respectively. Lipid and Glx peaks were also present in most of the malignant lesions, 79% (15/19) and 74% (14/19) respectively. However, a peak at ∼3.8 ppm was present in only 10% (two of 19) of the tumor cases (p values between 1.7-1.9 for Cho/Cr and 0.8-0.9 for mI/Cr provided high specificity (91% for both metabolites) and adequate sensitivity (75% and 80%, respectively) for discrimination of malignant lesions. A singlet peak at ∼3.8 ppm is present in the majority of tuberculomas and absent in most malignant tumors, potentially a marker to differentiate these lesions. The assignment of the peak is difficult from our analysis; however, guanidinoacetate (Gua) is a possibility. Higher Cho/Cr and mI/Cr ratios should favor malignant lesions over tuberculomas. The presence of lipids and Glx is non-specific. © The Author(s) 2015.

  5. Energy intensities: Prospects and potential

    International Nuclear Information System (INIS)

    Anon.

    1992-01-01

    In the previous chapter, the author described how rising activity levels and structural change are pushing toward higher energy use in many sectors and regions, especially in the developing countries. The extent to which more activity leads to greater energy use will depend on the energy intensity of end-use activities. In this chapter, the author presents an overview of the potential for intensity reductions in each sector over the next 10-20 years. It is not the author's intent to describe in detail the various technologies that could be employed to improve energy efficiency, which has been done by others (see, for example, Lovins ampersand Lovins, 1991; Goldembert et al., 1987). Rather, he discusses the key factors that will shape future energy intensities in different parts of the world, and gives a sense for the changes that could be attained if greater attention were given to accelerate efficiency improvement. The prospects for energy intensities, and the potential for reduction, vary among sectors and parts of the world. In the majority of cases, intensities are tending to decline as new equipment and facilities come into use and improvements are made on existing stocks. The effect of stock turnover will be especially strong in the developing countries, where stocks are growing at a rapid pace, and the Former East Bloc, where much of the existing industrial plant will eventually be retired and replaced with more modern facilities. While reductions in energy intensity are likely in most areas, there is a large divergence between the technical and economic potential for reducing energy intensities and the direction in which present trends are moving. In the next chapter, the author presents scenarios that illustrate where trends are pointing, and what could be achieved if improving energy efficiency were a focus of public policies. 53 refs., 4 figs., 2 tabs

  6. Singlet and triplet instability theorems

    Energy Technology Data Exchange (ETDEWEB)

    Yamada, Tomonori; Hirata, So, E-mail: sohirata@illinois.edu [Department of Chemistry, University of Illinois at Urbana-Champaign, 600 South Mathews Avenue, Urbana, Illinois 61801 (United States); CREST, Japan Science and Technology Agency, 4-1-8 Honcho, Kawaguchi, Saitama 332-0012 (Japan)

    2015-09-21

    A useful definition of orbital degeneracy—form-degeneracy—is introduced, which is distinct from the usual energy-degeneracy: Two canonical spatial orbitals are form-degenerate when the energy expectation value in the restricted Hartree–Fock (RHF) wave function is unaltered upon a two-electron excitation from one of these orbitals to the other. Form-degenerate orbitals tend to have isomorphic electron densities and occur in the highest-occupied and lowest-unoccupied molecular orbitals (HOMOs and LUMOs) of strongly correlated systems. Here, we present a mathematical proof of the existence of a triplet instability in a real or complex RHF wave function of a finite system in the space of real or complex unrestricted Hartree–Fock wave functions when HOMO and LUMO are energy- or form-degenerate. We also show that a singlet instability always exists in a real RHF wave function of a finite system in the space of complex RHF wave functions, when HOMO and LUMO are form-degenerate, but have nonidentical electron densities, or are energy-degenerate. These theorems provide Hartree–Fock-theory-based explanations of Hund’s rule, a singlet instability in Jahn–Teller systems, biradicaloid electronic structures, and a triplet instability during some covalent bond breaking. They also suggest (but not guarantee) the spontaneous formation of a spin density wave (SDW) in a metallic solid. The stability theory underlying these theorems extended to a continuous orbital-energy spectrum proves the existence of an oscillating (nonspiral) SDW instability in one- and three-dimensional homogeneous electron gases, but only at low densities or for strong interactions.

  7. The potential of renewable energy

    Energy Technology Data Exchange (ETDEWEB)

    1990-03-01

    On June 27 and 28, 1989, the US Department of Energy (DOE) national laboratories were convened to discuss plans for the development of a National Energy Strategy (NES) and, in particular, the analytic needs in support of NES that could be addressed by the laboratories. As a result of that meeting, interlaboratory teams were formed to produce analytic white papers on key topics, and a lead laboratory was designated for each core laboratory team. The broad-ranging renewables assignment is summarized by the following issue statement from the Office of Policy, Planning and Analysis: to what extent can renewable energy technologies contribute to diversifying sources of energy supply What are the major barriers to greater renewable energy use and what is the potential timing of widespread commercialization for various categories of applications This report presents the results of the intensive activity initiated by the June 1989 meeting to produce a white paper on renewable energy. Scores of scientists, analysts, and engineers in the five core laboratories gave generously of their time over the past eight months to produce this document. Their generous, constructive efforts are hereby gratefully acknowledged. 126 refs., 44 figs., 32 tabs.

  8. MR spectroscopy of intracranial tuberculomas: A singlet peak at 3.8 ppm as potential marker to differentiate them from malignant tumors

    Science.gov (United States)

    Alfaro, David; Martinot, Carlos; Fayed, Nicolas; Gaskill-Shipley, Mary

    2015-01-01

    Purpose The diagnosis of intracranial tuberculomas is often challenging. Our purpose is to describe the most common metabolic patterns of tuberculomas by MR spectroscopy (MRS) with emphasis on potential specific markers. Methods Single-voxel MRS short echo time was performed in 13 cases of tuberculomas proven by histology and/or response to anti-mycobacterial therapy. For comparison MRS was also performed in 19 biopsy-proven malignant tumors (13 high-grade gliomas and six metastasis). Presence of metabolic peaks was assessed visually and categorical variables between groups were compared using chi-square. Metabolite ratios were compared using Mann-Whitney test and diagnostic accuracy of the metabolite ratios was compared using receiver-operating characteristic (ROC) curves analysis. Results Spectroscopic peaks representing lipids and glutamate/glutamine (Glx) as well as a peak at ∼3.8 ppm were well defined in 77% (10/13), 77% (10/13) and 69% (nine of 13) of tuberculomas, respectively. Lipid and Glx peaks were also present in most of the malignant lesions, 79% (15/19) and 74% (14/19) respectively. However, a peak at ∼3.8 ppm was present in only 10% (two of 19) of the tumor cases (p < 0.001). Higher Cho/Cr and mI/Cr ratios helped discriminate malignant lesions with an area under the ROC curve of 0.86 (SE: 0.078, p < 0.002, CI: 0.7–1) and 0.8 (SE: 0.1, p < 0.009, CI: 0.6–1), respectively. Threshold values between 1.7–1.9 for Cho/Cr and 0.8–0.9 for mI/Cr provided high specificity (91% for both metabolites) and adequate sensitivity (75% and 80%, respectively) for discrimination of malignant lesions. Conclusion A singlet peak at ∼3.8 ppm is present in the majority of tuberculomas and absent in most malignant tumors, potentially a marker to differentiate these lesions. The assignment of the peak is difficult from our analysis; however, guanidinoacetate (Gua) is a possibility. Higher Cho/Cr and mI/Cr ratios should favor malignant lesions

  9. Potential energy function of CN-

    Czech Academy of Sciences Publication Activity Database

    Špirko, Vladimír; Polák, Rudolf

    2008-01-01

    Roč. 248, č. 1 (2008), s. 77-80 ISSN 0022-2852 R&D Projects: GA MŠk LC512; GA AV ČR IAA400550511; GA AV ČR IAA400400504 Institutional research plan: CEZ:AV0Z40550506; CEZ:AV0Z40400503 Keywords : potential energy curve * fundamental transition * spectroscopic constants Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 1.636, year: 2008

  10. Wind energy potential in India

    International Nuclear Information System (INIS)

    Rangarajan, S.

    1995-01-01

    Though located in the tropics, India is endowed with substantial wind resources because of its unique geographical location which gets fully exposed to both the south-west and north-east monsoon winds. The westerly winds of the south-west monsoons provide bulk of the wind potential. Areas with mean annual wind speed exceeding 18 k mph and areas with mean annual power density greater than 140 W/m 2 have been identified using the wind data collected by the wind monitoring project funded by the Ministry of Non-conventional Energy Sources (MNES). Seasonal variations in wind speed at selected locations are discussed as also the frequency distribution of hourly wind speed. Annual capacity factors for 250 kW wind electric generators have been calculated for several typical locations. A good linear correlation has been found between mean annual wind speed and mean annual capacity factor. A method is described for assessing wind potential over an extended region where adequate data is available. It is shown that the combined wind energy potential over five selected areas of limited extent in Gujarat, Andhra Pradesh and Tamil Nadu alone amounts to 22,000 MW under the assumption of 20 per cent land availability for installing wind farms. For a higher percentage of land availability, the potential will be correspondingly higher. (author). 12 refs., 6 figs., 3 tabs

  11. Singlet Ground State Magnetism:

    DEFF Research Database (Denmark)

    Loidl, A.; Knorr, K.; Kjems, Jørgen

    1979-01-01

    The magneticGamma 1 –Gamma 4 exciton of the singlet ground state system TbP has been studied by inelastic neutron scattering above the antiferromagnetic ordering temperature. Considerable dispersion and a pronounced splitting was found in the [100] and [110] directions. Both the band width...... and the splitting increased rapidly as the transition temperature was approached in accordance with the predictions of the RPA-theory. The dispersion is analysed in terms of a phenomenological model using interactions up to the fourth nearest neighbour....

  12. Singlets of fermionic gauge symmetries

    NARCIS (Netherlands)

    Bergshoeff, E.A.; Kallosh, R.E.; Rahmanov, M.A.

    1989-01-01

    We investigate under which conditions singlets of fermionic gauge symmetries which are "square roots of gravity" can exist. Their existence is non-trivial because there are no fields neutral in gravity. We tabulate several examples of singlets of global and local supersymmetry and κ-symmetry and

  13. Energy Foundations - Potential for Ireland

    OpenAIRE

    Hemmingway, Phil; Long, Michael (Michael M.)

    2011-01-01

    With one of the highest energy dependencies in the European Union, Ireland must adapt quickly to renewable energy technologies or risk paying the penalty in the form of high energy prices in years to come. Escalating energy costs have led to a renewed interest in alternative energy technologies and ground source energy is one such resource which is being increasingly considered. This paper presents some of the practical considerations of energy foundations, evidenced from the i...

  14. The electroweak phase transition in models with gauge singlets

    International Nuclear Information System (INIS)

    Ahriche, A.

    2007-01-01

    A strong first order phase transition is needed for generating the baryon asymmetry; and also to save it during the electroweak phase transition (EWPT). However this condition is not fulfilled within the Standard Model (SM), but in its extensions. It is widely believed that the existence of singlet scalars in some Standard Model extensions can easily make the EWPT strongly first order. In this work, we will examine the strength of the EWPT in the simplest extension of the SM with a real gauge singlet using the sphaleron energy at the critical temperature. We find that the phase transition is stronger by adding a singlet; and also that the criterion for a strong phase transition Ω(T c )/T c >or similar 1, where Ω = (v 2 + (x - x 0 ) 2 ) ( 1)/(2) and x(x 0 ) is the singlet vacuum expectation value in the broken (symmetric) phase, is not valid for models containing singlets, even though often used in the literature. The usual condition v c /T c >or similar 1 is more meaningful, and it is satisfied for the major part of the parameter space for physically allowed Higgs masses. Then it is convenient to study the EWPT in models with singlets that couple only to the Higgs doublets, by replacing the singlets by their vevs. (orig.)

  15. The electroweak phase transition in models with gauge singlets

    Energy Technology Data Exchange (ETDEWEB)

    Ahriche, A.

    2007-04-18

    A strong first order phase transition is needed for generating the baryon asymmetry; and also to save it during the electroweak phase transition (EWPT). However this condition is not fulfilled within the Standard Model (SM), but in its extensions. It is widely believed that the existence of singlet scalars in some Standard Model extensions can easily make the EWPT strongly first order. In this work, we will examine the strength of the EWPT in the simplest extension of the SM with a real gauge singlet using the sphaleron energy at the critical temperature. We find that the phase transition is stronger by adding a singlet; and also that the criterion for a strong phase transition {omega}(T{sub c})/T{sub c} >or similar 1, where {omega} = (v{sup 2} + (x - x{sub 0}){sup 2}){sup (}1)/(2) and x(x{sub 0}) is the singlet vacuum expectation value in the broken (symmetric) phase, is not valid for models containing singlets, even though often used in the literature. The usual condition v{sub c}/T{sub c} >or similar 1 is more meaningful, and it is satisfied for the major part of the parameter space for physically allowed Higgs masses. Then it is convenient to study the EWPT in models with singlets that couple only to the Higgs doublets, by replacing the singlets by their vevs. (orig.)

  16. Gaugino Mass without Singlets

    CERN Document Server

    Giudice, Gian Francesco; Murayama, H; Rattazzi, Riccardo; Giudice, Gian F.; Luty, Markus A.; Murayama, Hitoshi; Rattazzi, Riccardo

    1998-01-01

    In models with dynamical supersymmetry breaking in the hidden sector, the gaugino masses in the observable sector have been believed to be extremely suppressed (below 1 keV), unless there is a gauge singlet in the hidden sector with specific couplings to the observable sector gauge multiplets. We point out that there is a pure supergravity contribution to gaugino masses at the quantum level arising from the superconformal anomaly. Our results are valid to all orders in perturbation theory and are related to the `exact' beta functions for soft terms. There is also an anomaly contribution to the A terms proportional to the beta function of the corresponding Yukawa coupling. The gaugino masses are proportional to the corresponding gauge beta functions, and so do not satisfy the usual GUT relations.

  17. Photovoltaic energy potential of Quebec

    International Nuclear Information System (INIS)

    Royer, J.; Thomas, R.

    1993-01-01

    Results are presented from a study concerning the potential of photovoltaic (PV) energy in Quebec to the year 2010. The different PV applications which are or will be economically viable in Quebec for the study period are identified and evaluated in comparison with the conventional energy sources used for these applications. Two penetration scenarios are proposed. One considers little change at the level of policies established for commercialization of PV sources, and the other considers certain measures which accelerate the implementation of PV technology in certain niches. While the off-grid market is already motivated to adopt PV technology for economic reasons, it is forecast that all encouragement from lowering costs would accelerate PV sales, offering a larger purchasing power to all interested parties. Above all, lowered PV costs would open up the network market. Photovoltaics would have access to a much larger market, which will accelerate changes in the very nature of the industry and bring with it new reductions in the costs of producing PV systems. 5 refs., 1 fig., 7 tabs

  18. Residential Energy Efficiency Potential: Washington

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-27

    Energy used by Washington single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  19. Residential Energy Efficiency Potential: Colorado

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-16

    Energy used by Colorado single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  20. Residential Energy Efficiency Potential: Delaware

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-16

    Energy used by Delaware single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  1. Residential Energy Efficiency Potential: Kentucky

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-02

    Energy used by Kentucky single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  2. Residential Energy Efficiency Potential: Minnesota

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-22

    Energy used by Minnesota single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  3. Residential Energy Efficiency Potential: Nebraska

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-22

    Energy used by Nebraska single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  4. Residential Energy Efficiency Potential: Illinois

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-02

    Energy used by Illinois single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  5. Residential Energy Efficiency Potential: Iowa

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-02

    Energy used by Iowa single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  6. Residential Energy Efficiency Potential: Wisconsin

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-27

    Energy used by Wisconsin single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  7. Residential Energy Efficiency Potential: Wyoming

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-27

    Energy used by Wyoming single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  8. Residential Energy Efficiency Potential: Oregon

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-02

    Energy used by Oregon single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  9. Residential Energy Efficiency Potential: Georgia

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-17

    Energy used by Georgia single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  10. Residential Energy Efficiency Potential: Ohio

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-02

    Energy used by Ohio single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  11. Residential Energy Efficiency Potential: Arkansas

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-16

    Energy used by Arkansas single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  12. Residential Energy Efficiency Potential: Indiana

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-02

    Energy used by Indiana single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  13. Residential Energy Efficiency Potential: Vermont

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-22

    Energy used by Vermont single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  14. Residential Energy Efficiency Potential: Missouri

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-22

    Energy used by Missouri single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  15. Residential Energy Efficiency Potential: Alabama

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-15

    Energy used by Alabama single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  16. Residential Energy Efficiency Potential: Nevada

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-16

    Energy used by Nevada single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  17. Residential Energy Efficiency Potential: California

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-16

    Energy used by California single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  18. Residential Energy Efficiency Potential: Tennessee

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-02

    Energy used by Tennessee single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  19. Residential Energy Efficiency Potential: Maine

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-02

    Energy used by Maine single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  20. Residential Energy Efficiency Potential: Florida

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-16

    Energy used by Florida single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  1. Residential Energy Efficiency Potential: Pennsylvania

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-02

    Energy used by Pennsylvania single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  2. Residential Energy Efficiency Potential: Virginia

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-27

    Energy used by Virginia single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  3. Residential Energy Efficiency Potential: Oklahoma

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-02

    Energy used by Oklahoma single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  4. Residential Energy Efficiency Potential: Idaho

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-02

    Energy used by Idaho single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  5. Residential Energy Efficiency Potential: Michigan

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-22

    Energy used by Michigan single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  6. Residential Energy Efficiency Potential: Arizona

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-16

    Energy used by Arizona single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  7. Residential Energy Efficiency Potential: Texas

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-02

    Energy used by Texas single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  8. Residential Energy Efficiency Potential: Kansas

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-02

    Energy used by Kansas single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  9. Residential Energy Efficiency Potential: Massachusetts

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-21

    Energy used by Massachusetts single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  10. Residential Energy Efficiency Potential: Mississippi

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-22

    Energy used by Mississippi single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  11. Residential Energy Efficiency Potential: Connecticut

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-16

    Energy used by Connecticut single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  12. Residential Energy Efficiency Potential: Montana

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-22

    Energy used by Montana single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  13. Residential Energy Efficiency Potential: Maryland

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-16

    Energy used by Maryland single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  14. Residential Energy Efficiency Potential: Utah

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-22

    Energy used by Utah single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  15. Residential Energy Efficiency Potential: Louisiana

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-02

    Energy used by Louisiana single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  16. Geothermal Energy: Tapping the Potential

    Science.gov (United States)

    Johnson, Bill

    2008-01-01

    Ground source geothermal energy enables one to tap into the earth's stored renewable energy for heating and cooling facilities. Proper application of ground-source geothermal technology can have a dramatic impact on the efficiency and financial performance of building energy utilization (30%+). At the same time, using this alternative energy…

  17. Biowaste energy potential in Kenya

    NARCIS (Netherlands)

    Nzila, C.; DeWulf, J.; Spanjers, H.; Kiriamiti, H.; Langenhove, H.

    2010-01-01

    Energy affects all aspects of national development. Hence the current global energy crisis demands greater attention to new initiatives on alternative energy sources that are renewable, economically feasible and sustainable. The agriculture-dependent developing countries in Africa can mitigate the

  18. Renewable energy costs, potentials, barriers: Conceptual issues

    International Nuclear Information System (INIS)

    Verbruggen, Aviel; Fischedick, Manfred; Moomaw, William; Weir, Tony; Nadai, Alain; Nilsson, Lars J.; Nyboer, John; Sathaye, Jayant

    2010-01-01

    Renewable energy can become the major energy supply option in low-carbon energy economies. Disruptive transformations in all energy systems are necessary for tapping widely available renewable energy resources. Organizing the energy transition from non-sustainable to renewable energy is often described as the major challenge of the first half of the 21st century. Technological innovation, the economy (costs and prices) and policies have to be aligned to achieve full renewable energy potentials, and barriers impeding that growth need to be removed. These issues are also covered by IPCC's special report on renewable energy and climate change to be completed in 2010. This article focuses on the interrelations among the drivers. It clarifies definitions of costs and prices, and of barriers. After reviewing how the third and fourth assessment reports of IPCC cover mitigation potentials and commenting on definitions of renewable energy potentials in the literature, we propose a consistent set of potentials of renewable energy supplies.

  19. Energy restriction and potential energy restriction mimetics.

    Science.gov (United States)

    Nikolai, Sibylle; Pallauf, Kathrin; Huebbe, Patricia; Rimbach, Gerald

    2015-12-01

    Energy restriction (ER; also known as caloric restriction) is the only nutritional intervention that has repeatedly been shown to increase lifespan in model organisms and may delay ageing in humans. In the present review we discuss current scientific literature on ER and its molecular, metabolic and hormonal effects. Moreover, criteria for the classification of substances that might induce positive ER-like changes without having to reduce energy intake are summarised. Additionally, the putative ER mimetics (ERM) 2-deoxy-d-glucose, metformin, rapamycin, resveratrol, spermidine and lipoic acid and their suggested molecular targets are discussed. While there are reports on these ERM candidates that describe lifespan extension in model organisms, data on longevity-inducing effects in higher organisms such as mice remain controversial or are missing. Furthermore, some of these candidates produce detrimental side effects such as immunosuppression or lactic acidosis, or have not been tested for safety in long-term studies. Up to now, there are no known ERM that could be recommended without limitations for use in humans.

  20. Potential of renewable and alternative energy sources

    Science.gov (United States)

    Konovalov, V.; Pogharnitskaya, O.; Rostovshchikova, A.; Matveenko, I.

    2015-11-01

    The article deals with application potential of clean alternative renewable energy sources. By means of system analysis the forecast for consumption of electrical energy in Tomsk Oblast as well as main energy sources of existing energy system have been studied up to 2018. Engineering potential of renewable and alternative energy sources is evaluated. Besides, ranking in the order of their efficiency descending is performed. It is concluded that Tomsk Oblast has high potential of alternative and renewable energy sources, among which the most promising development perspective is implementation of gasification stations to save fuel consumed by diesel power stations as well as building wind-power plants.

  1. Singlet Fission of Non-polycyclic Aromatic Molecules in Organic Photovoltaics.

    Science.gov (United States)

    Kawata, So; Pu, Yong-Jin; Saito, Ayaka; Kurashige, Yuki; Beppu, Teruo; Katagiri, Hiroshi; Hada, Masaki; Kido, Junji

    2016-02-24

    Singlet fission of thienoquinoid compounds in organic photovoltaics is demonstrated. The escalation of the thienoquinoid length of the compounds realizes a suitable packing structure and energy levels for singlet fission. The magnetic-field dependence of the photocurrent and the external quantum efficiency of the devices reveal singlet fission of the compounds and dissociation of triplet excitons into charges. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  2. Energy potential of Finnish peatlands

    Energy Technology Data Exchange (ETDEWEB)

    Virtanen, K. (Geological Survey of Finland, Kuopio (Finland)); Valpola, S. (Geological Survey of Finland, Kokkola (Finland)), e-mail: kimmo.virtanen@gtk.fi, e-mail: samu.valpola@gtk.fi

    2011-07-01

    One-third of the Finnish land area is covered by mires and peat. GTK has investigated 2.0 million ha of the 9.3 million ha area covered by mires in Finland. According to the EU Commission, the broadly-based Finnish energy economy, with various energy sources, is the best in the EU. As a fuel, peat fulfils the goals of the EU energy policy in Finland well: it is local, its availability is good and the price is stable. The use of peat also enhances national security. At present, peat is used in around one hundred larger applications that co-generate electricity and heat. In Finland, the development of mires has led to several mire complex types and three main types: raised bogs in Southern Finland, aapa mires in Ostrobothnia and Lapland, and palsa mires in Northern Lapland. Peat layers are deepest in southern Finland and partly in the southern Finnish Lake area, the Region of North Karelia and in the area of central Lapland. The mean depth of geological mires is 1.41 m and the thickest drilled peat is 12.3 m. According to peat investigations, the national peat reserve totals 69.3 billion m3 in situ (peatlands larger than 20 hectares). The dry solids of peat are estimated at 6.3 billion tones. Sphagnum peat accounts for 54% and Carex peat for 45% of feasible peat reserves. Peatlands that are technically suitable for the peat industry cover a total area of 1.2 million ha and contain 29.6 billion m3 of peat in situ. Slightly humified peat suitable for horticultural and environmental use totals 5.9 billion m3 in situ. The energy peat reserve is 23.7 billion m3 in situ and its energy content is 12 800 TWh. (orig.)

  3. Energy sector and wind energy potential in Turkey

    International Nuclear Information System (INIS)

    Ogulata, R.T.

    2003-01-01

    Turkey has very limited indigenous energy resources and has to import around 65% of primary energy to meet her needs. It is a large importer of primary energy despite having ample renewable energy sources. Turkey's vibrant economy has led to increased energy demand in recent years. This situation is expected to continue in the near future because its economy is dependent mainly on imported oil, natural gas and electricity. This paper presents the prevailing and the expected energy situation and energy demand. Wind energy potential in Turkey is also discussed. (author)

  4. Energy potential of agricultural crops in Kosovo

    International Nuclear Information System (INIS)

    Sahiti, Naser; Sfishta, Avni; Gramatikov, Plamen

    2015-01-01

    Primary energy mix in Kosovo with 98 % consisting of lignite and only 2 % of water is far from portfolio of primary energy sources which could contribute to a sustainable and environmental friendly energy supply of the country. In order to improve the situation, government is supporting activities in favor of upgrading of electricity production capacities based on Renewable Energy Sources. Corresponding action plans and feed in tariffs are already in place. However, prior to any investment, one needs specific results on available potential. Current study provides results of the analysis of Kosovo potential for energy production by using of agricultural crops. Study is based on national statistics on available agricultural crops in Kosovo and provides results on biomass potential of crops, corresponding energy potential and an assessment of financial cost of energy produced.

  5. Unlocking potential for energy reduction.

    Science.gov (United States)

    O'Leary, John

    2013-05-01

    In the latest of our series of articles designed to provide healthcare engineers with sound technical guidance on equipment or technology-related topics, John O'Leary, key account manager at Trend Controls (who in April's HEJ discussed the benefits of natural ventilation in healthcare settings), explains the functions of a building energy management system (BEMS), and the vital that role such equipment can play in helping healthcare estates teams reduce carbon emissions and save money, as well as ensuring the most comfortable environment for patients, staff, and visitors.

  6. Singlet-triplet interaction in linear triatomic molecules

    Science.gov (United States)

    Osherov, V. I.; Osherov, M. V.; Poluyanov, L. V.

    2018-01-01

    We present here two-electronic model, which describes singlet-triplet interaction 1 π -3Σ+ in linear triatomic molecules. The analysis takes into account spin-orbital coupling terms in electronic Hamiltonian, as well as its symmetry properties. We give the symmetry operators of electronic Hamiltonian including space operators (acting on electronic coordinates) and matrix operators (acting on electronic spin). We consider only deformation π -modes and our resulting 5 × 5 vibronic matrix describes actual relativistic pseudo-Renner effect (1 π -3 Σ) × π . The eigenvalues of vibronic matrix (i.e. potential energy surfaces) have axial symmetry and represented by analytical expressions, include five electrostatic and three spin-orbital parameters.

  7. Potential energy surfaces for chemical reactions

    International Nuclear Information System (INIS)

    Schaefer, H.F. III.

    1976-01-01

    Research into potential energy surfaces for chemical reactions at Lawrence Berkeley Laboratory during 1976 is described. Topics covered include: the fuzzy interface between surface chemistry catalysis and organometallic chemistry; potential energy surfaces for elementary fluorine hydrogen reactions; structure, energetics, and reactivity of carbenes; and the theory of self-consistent electron pairs

  8. Storing unsteady energy, like photovoltaically generated electric energy, as potential energy

    OpenAIRE

    Kutz, Nadja

    2012-01-01

    A proposal to store unsteady energy in potential energy via lifting masses with a rough quantitative overview. Some applications and methods to harvest the potential energy are also given. A focus is put on photovoltaically generated energy.

  9. Geothermal Energy Potential in Western United States

    Science.gov (United States)

    Pryde, Philip R.

    1977-01-01

    Reviews types of geothermal energy sources in the western states, including hot brine systems and dry steam systems. Conversion to electrical energy is a major potential use of geothermal energy, although it creates environmental disruptions such as noise, corrosion, and scaling of equipment. (AV)

  10. Energy potential mapping for energy-producing neighborhoods

    NARCIS (Netherlands)

    Dobbelsteen, van den A.; Broersma, S.; Stremke, S.

    2011-01-01

    Over the past five years, the method of energy potential mapping (EPM) has evolved from a cartoonish charting of climatic features with energy consequences to a detailed methodology for the development of spatial plans based on energy-effective foundations. By means of EPM the rudimentary features

  11. Conservation energy - potential and practice in Canada

    Energy Technology Data Exchange (ETDEWEB)

    Armstong, G.T.

    1980-06-24

    As energy prices increase and as more is learned about the technology and overall costs and benefits of substituting conservation (and renewable) energy for conventional energy, what may be termed conservation energy will become more widely used in Canada. As a result, conservation energy sources will significantly increase their share of the energy services market through the 1980s. This paper concentrates on the sources of this energy services input, after reviewing the pattern of Canadian energy demands and some major aspects of conservation energy. From the review it is evident that there is great potential in Canada for the use of conservation energy that does not entail cutting-back and that is competitive with conventional energy. Attempts have been made to quantify the costs of conservation energy and some results of this work are presented. Success in capitalizing on conservation energy opportunities will improve economic performance by efficiently reducing the proportion of expenditure outlays on conventional energy. There are also opportunities to improve Canadian capabilities in what may be termed the energy conservation industries. In developing these industries, there is a great need to design conservation and renewable energy technologies that operate efficiently in Canadian climatic conditions. 2 refs., 4 figs., 21 tabs.

  12. Guidance for Mutual Disposition of Chromophores for Singlet Fission

    Czech Academy of Sciences Publication Activity Database

    Havlas, Zdeněk; Michl, Josef

    2016-01-01

    Roč. 56, č. 1 (2016), s. 96-106 ISSN 0021-2148 R&D Projects: GA ČR GA15-19143S Institutional support: RVO:61388963 Keywords : chromophores * energy transfer * photophysics * singlet fission * theory Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 2.455, year: 2016

  13. 1,3-Diphenylisobenzofuran: a Model Chromophore for Singlet Fission

    Czech Academy of Sciences Publication Activity Database

    Johnson, J. C.; Michl, Josef

    2017-01-01

    Roč. 375, č. 5 (2017), č. článku 80. ISSN 2365-0869 R&D Projects: GA ČR GA15-19143S Institutional support: RVO:61388963 Keywords : 1,3-diphenylisobenzofuran * photophysics * solar energy * singlet fission * covalent dimers Subject RIV: CF - Physical ; Theoretical Chemistry OBOR OECD: Physical chemistry Impact factor: 4.033, year: 2016

  14. Energy audit: potential of energy - conservation in Jordanian ceramic industry

    International Nuclear Information System (INIS)

    Adas, H.; Taher, A.

    2005-01-01

    This paper represents the findings of the preliminary energy-audits performed by the Rational Use of Energy Division at the National Energy Research Center (NERC), as well as the findings of a detailed energy-audit carried out in the largest Ceramic plant in Jordan (Jordan Ceramic industries).These studies were preceded by a survey of the ceramic factories in Jordan. The survey was carried out in 1997. The performed preliminary energy-audits showed that an average saving-potential in most of theses plants is about 25 % of the total energy-bills in these plants, which constitutes a considerable portion of the total production-cost. This fact was verified through the detailed energy-audit performed by NERC team for the largest Ceramic Plant in Jordan in June 2003, which showed an energy-saving potential of about 30 %. This saving can be achieved by some no-cost or low-cost measures, in addition to some measures that need reasonable investments with an average pay-back period of about two years. This detailed energy-audit covered electrical systems, refrigeration systems, compressed-air systems, and kilns. The results of the detailed energy-audit can be disseminated to other Ceramic plant, because of the similarity in the production process between these plants and the plant where the detailed energy-audit was carried out. (author)

  15. Energy development potential: An analysis of Brazil

    International Nuclear Information System (INIS)

    Perobelli, Fernando Salgueiro; Oliveira, Caio Cézar Calheiros de

    2013-01-01

    This paper develops an indicator for the energy development potential (EDP) of 27 Brazilian states. This indicator uses data on a state's infrastructure and its supply of and demand for energy. The indicator measures the data for three periods: the first part of the 1990s, which is a period of low economic growth; the first part of the 2000s, which is a period of high economic growth but with a historical crisis in the Brazilian energy sector; and 2009–2011, which is a period of economic growth after the energy crisis. Using a factor analysis, we are able to identify three factors for EDP. They are the demand for energy, the supply of renewable energy, and the supply of nonrenewable energy. We use these factors to classify the Brazilian states according to their EDP and to perform an exploratory spatial data analysis (ESDA) by using the Moran indicators and the local indicators of spatial association (LISA). - Highlights: • This paper deals with the spatial dimension of the Brazilian energy sector. • We construct an index of the energy development potential for Brazilian states. • Energy issues are defined over time and space, thus have spatial dimensions. • The spatial results show that there are two well-defined spatial patterns

  16. Centrifugal potential energy : an astounding renewable energy concept

    Energy Technology Data Exchange (ETDEWEB)

    Oduniyi, I.A. [Aled Conglomerate Nigeria Ltd., Lagos (Nigeria)

    2010-07-01

    A new energy concept known as centrifugal potential energy was discussed. This new energy concept is capable of increasing the pressure, temperature and enthalpy of a fluid, without having to apply work or heat transfer to the fluid. It occurs through a change in the centrifugal potential energy of the flowing fluid in a rotating frame of reference or a centrifugal force field, where work is performed internally by the centrifugal weight of the fluid. This energy concept has resulted in new energy equations, such as the Rotational Frame Bernoulli's Equation for liquids and the Rotational Frame Steady-Flow Energy Equation for gases. Applications of these equations have been incorporated into the design of centrifugal field pumps and compressors. Rather than compressing a fluid with a physical load transfer, these devices can compress a fluid via the effect of centrifugal force applied to the object. A large amount of energy is therefore produced when this high pressure compressed working fluid expands in a turbine. When water is used as the working fluid, it could reach renewable energy densities in the range of 25-100 kJ/kg of water. When atmospheric air is used, it could reach energy densities in the range of 500-1,500 kJ/kg of air.

  17. Photo-excitation of carotenoids causes cytotoxicity via singlet oxygen production

    International Nuclear Information System (INIS)

    Yoshii, Hiroshi; Yoshii, Yukie; Asai, Tatsuya; Furukawa, Takako; Takaichi, Shinichi; Fujibayashi, Yasuhisa

    2012-01-01

    Highlights: ► Some photo-excited carotenoids have photosensitizing ability. ► They are able to produce ROS. ► Photo-excited fucoxanthin can produce singlet oxygen through energy transfer. -- Abstract: Carotenoids, natural pigments widely distributed in algae and plants, have a conjugated double bond system. Their excitation energies are correlated with conjugation length. We hypothesized that carotenoids whose energy states are above the singlet excited state of oxygen (singlet oxygen) would possess photosensitizing properties. Here, we demonstrated that human skin melanoma (A375) cells are damaged through the photo-excitation of several carotenoids (neoxanthin, fucoxanthin and siphonaxanthin). In contrast, photo-excitation of carotenoids that possess energy states below that of singlet oxygen, such as β-carotene, lutein, loroxanthin and violaxanthin, did not enhance cell death. Production of reactive oxygen species (ROS) by photo-excited fucoxanthin or neoxanthin was confirmed using a reporter assay for ROS production with HeLa Hyper cells, which express a fluorescent indicator protein for intracellular ROS. Fucoxanthin and neoxanthin also showed high cellular penetration and retention. Electron spin resonance spectra using 2,2,6,6-tetramethil-4-piperidone as a singlet oxygen trapping agent demonstrated that singlet oxygen was produced via energy transfer from photo-excited fucoxanthin to oxygen molecules. These results suggest that carotenoids such as fucoxanthin, which are capable of singlet oxygen production through photo-excitation and show good penetration and retention in target cells, are useful as photosensitizers in photodynamic therapy for skin disease.

  18. Glow discharge in singlet oxygen

    International Nuclear Information System (INIS)

    Vagin, N.P.; Ionin, A.A.; Klimachev, Yu.M.; Sinitsyn, D.V.; Yuryshev, N.N.; Kochetov, I.V.; Napartovich, A.P.

    2003-01-01

    Currently, there is no experimental data on the plasma balance in gas mixtures with a high content of singlet delta oxygen O 2 ( 1 Δ g ). These data can be obtained by studying the parameters of an electric discharge in singlet oxygen produced by a chemical generator. The O 2 ( 1 Δ g ) molecules significantly change the kinetics of electrons and negative ions in plasma. Hence, the discharge conditions at low and high O 2 ( 1 Δ g ) concentrations are very different. Here, the parameters of the positive column of a glow discharge in a gas flow from a chemical singlet-oxygen generator are studied. It is experimentally shown that, at an O 2 ( 1 Δ g ) concentration of 50% and at pressures of 1.5 and 2 torr, the electric field required to sustain the discharge is considerably lower than in the case when all of the oxygen molecules are in the ground state. A theoretical model of the glow discharge is proposed whose predictions are in good agreement with the experimental data

  19. Biomass energy potential in Brazil. Country study

    International Nuclear Information System (INIS)

    Moreira, J.

    1995-01-01

    The present paper was prepared as a country study about the biomass potential for energy production in Brazil. Information and analysis of the most relevant biomass energy sources and their potential are presented in six chapters. Ethanol fuel, sugar-cane bagasse, charcoal, vegetable oil, firewood and other biomass-derived fuels are the objects of a historical review, in addition to the presentation of state-of-the-art technologies, economic analysis and discussion of relevant social and environmental issues related to their production and use. Wherever possible, an evaluation, from the available sources of information and based on the author's knowledge, is performed to access future perspectives of each biomass energy source. Brazil is a country where more than half of the energy consumed is provided from renewable sources of energy, and biomass provides 28% of the primary energy consumption. Its large extension, almost all located in the tropical and rainy region, provides an excellent site for large-scale biomass production, which is a necessity if biomass is to be used to supply a significant part of future energy demand. Even so, deforestation has occurred and is occurring in the country, and the issue is discussed and explained as mainly the result of non-energy causes or the use of old and outdated technologies for energy production. (author)

  20. Energy dependence of nonlocal optical potentials

    Science.gov (United States)

    Lovell, A. E.; Bacq, P.-L.; Capel, P.; Nunes, F. M.; Titus, L. J.

    2017-11-01

    Recently, a variety of studies have shown the importance of including nonlocality in the description of reactions. The goal of this work is to revisit the phenomenological approach to determining nonlocal optical potentials from elastic scattering. We perform a χ2 analysis of neutron elastic scattering data off 40Ca, 90Zr, and 208Pb at energies E ≈5 -40 MeV, assuming a Perey and Buck [Nucl. Phys. 32, 353 (1962), 10.1016/0029-5582(62)90345-0] or Tian et al. [Int. J. Mod. Phys. E 24, 1550006 (2015), 10.1142/S0218301315500068] nonlocal form for the optical potential. We introduce energy and asymmetry dependencies in the imaginary part of the potential and refit the data to obtain a global parametrization. Independently of the starting point in the minimization procedure, an energy dependence in the imaginary depth is required for a good description of the data across the included energy range. We present two parametrizations, both of which represent an improvement over the original potentials for the fitted nuclei as well as for other nuclei not included in our fit. Our results show that, even when including the standard Gaussian nonlocality in optical potentials, a significant energy dependence is required to describe elastic-scattering data.

  1. Singlet oxygen in the low-temperature plasma of an electron-beam-sustained discharge

    International Nuclear Information System (INIS)

    Vagin, N. P.; Ionin, A. A.; Klimachev, Yu. M.; Kotkov, A. A.; Kochetov, I. V.; Napartovich, A. P.; Podmar'kov, Yu. P.; Rulev, O. A.; Seleznev, L. V.; Sinitsyn, D. V.; Frolov, M. P.; Yuryshev, N. N.

    2006-01-01

    Results are presented from experimental and theoretical studies of the production of singlet delta oxygen in a pulsed electron-beam-sustained discharge ignited in a large (∼18-1) volume at a total gas mixture pressure of up to 210 Torr. The measured yield of singlet oxygen reaches 10.5%. It is found that varying the reduced electric field from ∼2 to ∼11 kV/(cm atm) slightly affects singlet oxygen production. It is shown experimentally that an increase in the gas mixture pressure or the specific input energy reduces the duration of singlet oxygen luminescence. The calculated time evolution of the singlet oxygen concentration is compared with experimental results

  2. Spatial mapping of renewable energy potential

    Energy Technology Data Exchange (ETDEWEB)

    Ramachandra, T.V. [Centre for Sustainable Technologies, Indian Institute of Science, Bangalore (India); Energy Research Group, CES RNO 215, Centre for Ecological Sciences, Indian Institute of Science, Bangalore 560 012 (India); Shruthi, B.V. [Energy Research Group, CES RNO 215, Centre for Ecological Sciences, Indian Institute of Science, Bangalore 560 012 (India)

    2007-09-15

    An energy resource that is renewed by nature and whose supply is not affected by the rate of consumption is often termed as renewable energy. The need to search for renewable, alternate and non-polluting sources of energy assumes top priority for self-reliance in the regional energy supply. This demands an estimation of available energy resources spatially to evolve better management strategies for ensuring sustainability of resources. The spatial mapping of availability and demand of energy resources would help in the integrated regional energy planning through an appropriate energy supply-demand matching. This paper discusses the application of Geographical Information System (GIS) to map the renewable energy potential talukwise in Karnataka State, India. Taluk is an administrative division in the federal set-up in India to implement developmental programmes like dissemination of biogas, improved stoves, etc. Hence, this paper focuses talukwise mapping of renewable energy (solar, wind, bioenergy and small hydroenergy) potential for Karnataka using GIS. GIS helps in spatial and temporal analyses of the resources and demand and also aids as Decision Support System while implementing location-specific renewable energy technologies. Regions suitable for tapping solar energy are mapped based on global solar radiation data, which provides a picture of the potential. Coastal taluks in Uttara Kannada have higher global solar radiation during summer (6.31 kWh/m{sup 2}), monsoon (4.16 kWh/m{sup 2}) and winter (5.48 kWh/m{sup 2}). Mapping of regions suitable for tapping wind energy has been done based on wind velocity data, and it shows that Chikkodi taluk, Belgaum district, has higher potential during summer (6.06 m/s), monsoon (8.27 m/s) and winter (5.19 m/s). Mysore district has the maximum number of small hydropower plants with a capacity of 36 MW. Talukwise computation of bioenergy availability from agricultural residue, forest, horticulture, plantation and livestock

  3. Natural gas decompression energy recovery: Energy savings potential in Italy

    International Nuclear Information System (INIS)

    Piatti, A.; Piemonte, C.; Rampini, E.; Vatrano, F.; Techint SpA, Milan; ENEA, Rome

    1992-01-01

    This paper surveyed the natural gas distribution systems employed in the Italian civil, industrial and thermoelectric sectors to identify those installations which can make use of gas decompression energy recovery systems (consisting of turbo-expanders or alternative expanders) to economically generate electric power. Estimates were then made of the total amount of potential energy savings. The study considered as eligible for energy savings interventions only those plants with a greater than 5,000 standard cubic meter per hour plant capacity. It was evaluated that, with suitable decompression equipment installed at 50 key installations (33 civil, 15 industrial), about 200 GWh of power could be produced annually, representing potential savings of about 22,000 petroleum equivalent tonnes of energy. A comparative analysis was done on three investment alternatives involving inputs of varying amounts of Government financial assistance

  4. Vibration Energy Harvesting Potential for Turbomachinery Applications

    Directory of Open Access Journals (Sweden)

    Adrian STOICESCU

    2018-03-01

    Full Text Available The vibration energy harvesting process represents one of the research directions for increasing power efficiency of electric systems, increasing instrumentation nodes autonomy in hard to reach locations and decreasing total system mass by eliminating cables and higher-power adapters. Research based on the possibility of converting vibration energy into useful electric energy is used to evaluate the potential of its use on turbomachinery applications. Aspects such as the structure and characteristics of piezoelectric generators, harvesting networks, their setup and optimization, are considered. Finally, performance test results are shown using piezoelectric systems on a turbine engine.

  5. Complex singlet extension of the standard model

    International Nuclear Information System (INIS)

    Barger, V.; Langacker, P.; McCaskey, M.; Ramsey-Musolf, M.; Shaughnessy, G.

    2009-01-01

    We analyze a simple extension of the standard model (SM) obtained by adding a complex singlet to the scalar sector (cxSM). We show that the cxSM can contain one or two viable cold dark matter candidates and analyze the conditions on the parameters of the scalar potential that yield the observed relic density. When the cxSM potential contains a global U(1) symmetry that is both softly and spontaneously broken, it contains both a viable dark matter candidate and the ingredients necessary for a strong first order electroweak phase transition as needed for electroweak baryogenesis. We also study the implications of the model for discovery of a Higgs boson at the Large Hadron Collider

  6. Energy efficiency potential study for New Brunswick

    International Nuclear Information System (INIS)

    1992-05-01

    The economic and environmental impacts associated with economically attractive energy savings identified in each of four sectors in New Brunswick are analyzed. The results are derived through a comparison of two potential future scenarios. The frozen efficiency scenario projects what future energy expenditures would be if no new energy efficiency initiatives are introduced. The economic potential scenario projects what those expenditures would be if all economically attractive energy efficiency improvements were gradually implemented over the next 20 years. Energy related emissions are estimated under scenarios with and without fuel switching. The results show, for example, that New Brunswick's energy related CO 2 emissions would be reduced by ca 5 million tonnes in the year 2000 under the economic potential scenario. If fuel switching is adopted, an additional 1 million tonnes of CO 2 emissions could be saved in the year 2000 and 1.6 million tonnes in 2010. The economic impact analysis is restricted to efficiency options only and does not consider fuel switching. Results show the effect of the economic potential scenario on employment, government revenues, and intra-industry distribution of employment gains and losses. The employment impact is estimated as the equivalent of the creation of 2,424 jobs annually over 1991-2010. Government revenues would increase by ca $24 million annually. The industries benefitting most from energy efficiency improvements would be those related to construction, retail trade, finance, real estate, and food/beverages. Industries adversely affected would be the electric power, oil, and coal sectors. 2 figs., 37 tabs

  7. Potential Energy Curve of N2 Revisited

    Czech Academy of Sciences Publication Activity Database

    Špirko, Vladimír; Xiangzhu, L.; Paldus, J.

    2011-01-01

    Roč. 76, č. 4 (2011), s. 327-341 ISSN 0010-0765 R&D Projects: GA MŠk LC512; GA ČR GAP208/11/0436 Institutional research plan: CEZ:AV0Z40550506 Keywords : reduced multireference coupled-cluster method * reduced potential curve method * nitrogen molecule potential energy curves Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 1.283, year: 2011

  8. Correlation energy generating potentials for molecular hydrogen

    International Nuclear Information System (INIS)

    Sharma, B.S.; Thakkar, A.J.

    1985-01-01

    A variety of local correlation energy functionals are currently in use. All of them depend, to some extent, on modeling the correlation energy of a homogeneous electron fluid. Since atomic and molecular charge densities are neither uniform nor slowly varying, it is important to attempt to use known high accuracy wave functions to learn about correlation energy functionals appropriate to such systems. We have extended the definition of the correlation energy generating potentials V/sub c/ introduced by Ros. A charge density response to correlation has been allowed for by inclusion of an electron--nuclear component V/sup e/n/sub c/ in addition to the electron--electron component V/sup e/e/sub c/. Two different definitions of V/sup e/n/sub c/ are given. We present the first calculations of V/sub c/ for a molecular system: H 2 . The results show that V/sup e/n/sub c/, in either definition, is by no means negligible. Moreover, V/sup e/e/sub c/ and both forms of V/sup e/n/sub c/ show significant nonlocal dependence on the charge density. Calculations with ten different model correlation energy functionals show that none of them is particularly sensitive to the charge density. However, they are quite sensitive to the parametrization of the electron fluid correlation energy. The schemes which include self-interaction corrections (SIC) are found to be superior to those of Kohn--Sham type. The correlation energy generating potentials implied by the SIC type and empirical correlation energy functionals are found to correspond roughly to averages of one of the accurate potentials

  9. Energy from streaming current and potential

    NARCIS (Netherlands)

    Olthuis, Wouter; Schippers, Bob; Eijkel, Jan C.T.; van den Berg, Albert

    2005-01-01

    It is investigated how much energy can be delivered by a streaming current source. A streaming current and subsequent streaming potential originate when double layer charge is transported by hydrodynamic flow. Theory and a network model of such a source is presented and initial experimental results

  10. Potential energy surface of alanine polypeptide chains

    DEFF Research Database (Denmark)

    Solov'yov, Ilia; Yakubovich, Alexander V.; Solov'yov, Andrey V.

    2006-01-01

    The multidimensional potential energy surfaces of the peptide chains consisting of three and six alanine (Ala) residues have been studied with respect to the degrees of freedom related to the twist of these molecules relative to the peptide backbone (these degrees of freedom are responsible...

  11. Timing of potential and metabolic brain energy

    NARCIS (Netherlands)

    Korf, Jakob; Gramsbergen, Jan Bert

    2007-01-01

    The temporal relationship between cerebral electro-physiological activities, higher brain functions and brain energy metabolism is reviewed. The duration of action potentials and transmission through glutamate and GABA are most often less than 5 ms. Subjects may perform complex psycho-physiological

  12. Energy transfer in scattering by rotating potentials

    Indian Academy of Sciences (India)

    Quantum mechanical scattering theory is studied for time-dependent Schrödinger operators, in particular for particles in a rotating potential. Under various assumptions about the decay rate at infinity we show uniform boundedness in time for the kinetic energy of scattering states, existence and completeness of wave ...

  13. Energy Transfer in Scattering by Rotating Potentials

    Indian Academy of Sciences (India)

    Quantum mechanical scattering theory is studied for time-dependent Schrödinger operators, in particular for particles in a rotating potential. Under various assumptions about the decay rate at infinity we show uniform boundedness in time for the kinetic energy of scattering states, existence and completeness of wave ...

  14. Energy transfer in scattering by rotating potentials

    Indian Academy of Sciences (India)

    R. Narasimhan (Krishtel eMaging) 1461 1996 Oct 15 13:05:22

    Abstract. Quantum mechanical scattering theory is studied for time-dependent. Schrödinger operators, in particular for particles in a rotating potential. Under various assumptions about the decay rate at infinity we show uniform boundedness in time for the kinetic energy of scattering states, existence and completeness of ...

  15. Energy potential of the Estonian rivers

    International Nuclear Information System (INIS)

    Reihan, Alvina; Kovalenko, Olga

    2002-01-01

    In the current study the river runoff, its long-term distribution and river slope were considered as factors in the evaluation of the hydro energy potential of the Estonian rivers. The analyses of the long-term runoff hydrographs showed the increase of the maximum discharges and the decrease of the minimum discharges, at the same time mean annual discharges were almost unchanged. It indicated that seasonal variability of the runoff decreased. The evaluation of the hydro energy potential of rivers showed, that the Narva and Paernu rivers are the most suitable for hydro energy production, then in decreasing order - the Kasari, Pedja, Piusa, Halliste, Vohandu, Jaegala rivers etc. The analyses of the Rannapungerja river runoff showed, that the activity of the restored Tudulinna hydropower plant had an influence on runoff in 2001: the minimum discharge was less than permitted by the legislative acts. Thus, the environmental aspects should have a high priority in hydropower plants reconstruction(author)

  16. Offshore wind energy potential in China

    DEFF Research Database (Denmark)

    Hong, Lixuan; Möller, Bernd

    2011-01-01

    This paper investigates available offshore wind energy resources in China’s exclusive economic zone (EEZ) with the aid of a Geographical Information System (GIS), which allows the influence of technical, spatial and economic constraints on offshore wind resources being reflected in a continuous...... of each spatial constraint as well as various scenarios of spatial constraints on marginal production costs of offshore wind energy. Furthermore, the impacts of differing Feed-in-tariff (FIT) standards on the economic potential are calculated. It confirms that economic potential of offshore wind energy...... and economic costs. However, the influence of tropical cyclone risks on these regions and detailed assessments at regional or local scale are worth of further discussions. Nevertheless, the models and results provide a foundation for a more comprehensive regional planning framework that would address...

  17. Renewable energy in India: Status and potential

    Energy Technology Data Exchange (ETDEWEB)

    Pillai, Indu R.; Banerjee, Rangan [Department of Energy Science and Engineering, Indian Institute of Technology Bombay, Powai, Mumbai 400076 (India)

    2009-08-15

    A majority of the Indian population does not have access to convenient energy services (LPG, electricity). Though India has made significant progress in renewable energy, the share of modern renewables in the energy mix is marginal. This paper reviews the status and potential of different renewables (except biomass) in India. This paper documents the trends in the growth of renewables in India and establishes diffusion model as a basis for setting targets. The diffusion model is fitted tot the past trends for wind, small hydro and solar water heating and is used to establish future targets. The economic viability and green house gas (GHG) saving potential is estimated for each option. Several renewables have high growth rates, for example wind, Photovoltaic (PV) module manufacture and solar water heaters. New technologies like Tidal, OTEC, Solar thermal power plants and geothermal power plants are at the demonstration stage and future dissemination will depend on the experience of these projects. (author)

  18. Timing of potential and metabolic brain energy

    DEFF Research Database (Denmark)

    Korf, Jakob; Gramsbergen, Jan Bert

    2007-01-01

    -physiological tasks within 50 to 200 ms, and perception of conscious experience requires 0.5 to 2 s. Activation of cerebral oxygen consumption starts after at least 100 ms and increases of local blood flow become maximal after about 1 s. Current imaging technologies are unable to detect rapid physiological brain......The temporal relationship between cerebral electro-physiological activities, higher brain functions and brain energy metabolism is reviewed. The duration of action potentials and transmission through glutamate and GABA are most often less than 5 ms. Subjects may perform complex psycho...... functions. We introduce the concepts of potential and metabolic brain energy to distinguish trans-membrane gradients of ions or neurotransmitters and the capacity to generate energy from intra- or extra-cerebral substrates, respectively. Higher brain functions, such as memory retrieval, speaking...

  19. Supersymmetric singlet majorons and cosmology

    International Nuclear Information System (INIS)

    Chun, E.J.; Kim, H.B.; Lukas, A.

    1994-02-01

    We examine cosmological constraints on the lepton number breaking scale in super-symmetric singlet majoron models. Special attention is drawn to the model dependence arising from the particular choice of a certain majoron extension and a cosmological scenario. We find that the bounds on the symmetry breaking scale can vary substantially. Large values of this scale can be allowed if the decoupling temperature of majoron and majorino exceeds the reheating temperature of inflation. In the opposite case an upper bound depending on the majoron model can be obtained which, however, is unlikely to be much larger than 10 10 GeV. (author). 13 refs, 2 figs

  20. Effects of Intermolecular Coupling on Excimer Formation and Singlet Fission

    Science.gov (United States)

    Mauck, Catherine McKay

    The development of organic photovoltaic devices benefits from understanding the fundamental processes underlying charge generation in thin films of organic semiconductors. This dissertation exploits model systems of pi-stacked chromophores such as perylene-3,4:9,10-bis(dicarboximide) (PDI) and 3,6-bis(aryl)diketopyrrolopyrrole (DPP) to study these processes using ultrafast electronic and vibrational spectroscopy. In particular, the characterization of covalent molecular dimers, thin films, and solution aggregates can reveal how supramolecular order affects photophysical properties. PDI and DPP are organic semiconductors that have been widely studied in organic photovoltaics, due to their strong visible absorption and excellent chemical stability. As solution-phase monomers, they are highly fluorescent, but in the thin film environment of photovoltaic devices these planar aromatic molecules couple to one another, stacking largely through pi-pi interactions. In self-assembled stacks of PDI, strong interchromophore coupling may disrupt charge separation through the formation of excimer states, preventing the generation of free carriers. By studying molecular dimers of PDI with different pi-stacked geometry, femtosecond visible pump mid-infrared probe spectroscopy allows direct observation of the structural dynamics associated with excimer state relaxation, showing that this low-energy state is primarily coupled to the core modes that shift as planarization and rotation lead to the most stable excimer geometry. PDI is also able to undergo singlet fission in thin films and aggregates. Singlet fission is the process in which a singlet excited state is downconverted into two triplet excitons, when the energy of its first singlet excited state is at least twice the energy of the lowest triplet state in an appropriately coupled molecular system. This spin-allowed, ultrafast process enables a theoretical yield of two charge carriers per incident photon, making it a

  1. In Search of the Wind Energy Potential

    DEFF Research Database (Denmark)

    Lundtang Petersen, Erik

    2017-01-01

    The worldwide advancement of wind energy is putting high demands on a number of underlying technologies such as wind turbine aerodynamics, structural dynamics, gearbox design, electrical grid connections, and so on. As wind is the only fuel for wind power plants, naturally, wind......-meteorology and wind-climatology are essential for any utilization of wind energy. This is what we are concerned about here with a view on what has happened in wind energy potential assessments in the last 25 years where the utilization of wind turbines in national power supply has accelerated and what......., The New Worldwide Microscale Wind Resource Assessment Data on IRENA's Global Atlas (The EUDP Global Wind Atlas, 2015)], and finally, the perspective for the current work with the New European Wind Atlas [E. L. Petersen et al., Energy Bull. 17, 34–39 (2014); Environ. Res. Lett. 8(1), 011005 (2013...

  2. Energy independent optical potentials: construction and limitations

    International Nuclear Information System (INIS)

    Hussein, M.S.; Moniz, E.J.

    1983-11-01

    Properties of the energy-independent potential U sup(-) which is wave-function-equivalent to the usual optical potential U(E) are constructed and examined. A simple procedure is presented for constructing U sup(-) in the uniform medium, and physical examples are discussed. The general result for finite systems, a recursive expansion in powers of U(E), is used to investigate the multiple scattering expansion of U sup(-); the energy-independent potential is found to have serious short-comings for direct microscopic construction or phenomenological parametrization. The microscopic theory, as exemplified here by the multiple scattering approach, does not lead to a reliable approximation scheme. Phenomenological approaches to U sup(-) are unattractive because the physics does not guide the parametrization effectively: the structure of the nonlocality is not tied directly to the dynamics; Im U sup(-) changes sign; different elements of the physics, separate in U(E), are completely entangled in U sup(-). (Author) [pt

  3. Energy potential of the modified excess sludge

    Science.gov (United States)

    Zawieja, Iwona

    2017-11-01

    On the basis of the SCOD value of excess sludge it is possible to estimate an amount of energy potentially obtained during the methane fermentation process. Based on a literature review, it has been estimated that from 1 kg of SCOD it is possible to obtain 3.48 kWh of energy. Taking into account the above methane and energy ratio (i.e. 10 kWh/1Nm3 CH4), it is possible to determine the volume of methane obtained from the tested sludge. Determination of potential energy of sludge is necessary for the use of biogas as a source of power generators as cogeneration and ensure the stability of this type of system. Therefore, the aim of the study was to determine the energy potential of excess sludge subjected to the thermal and chemical disintegration. In the case of thermal disintegration, test was conducted in the low temperature 80°C. The reagent used for the chemical modification was a peracetic acid, which in an aqueous medium having strong oxidizing properties. The time of chemical modification was 6 hours. Applied dose of the reagent was 1.0 ml CH3COOOH/L of sludge. By subjecting the sludge disintegration by the test methods achieved an increase in the SCOD value of modified sludge, indicating the improvement of biodegradability along with a concomitant increase in their energy potential. The obtained experimental production of biogas from disintegrated sludge confirmed that it is possible to estimate potential intensity of its production. The SCOD value of 2576 mg O2/L, in the case of chemical disintegration, was obtained for a dose of 1.0 ml CH3COOH/L. For this dose the pH value was equal 6.85. In the case of thermal disintegration maximum SCOD value was 2246 mg O2/L obtained at 80°C and the time of preparation 6 h. It was estimated that in case of thermal disintegration as well as for the chemical disintegration for selected parameters, the potential energy for model digester of active volume of 5L was, respectively, 0.193 and 0,118 kWh.

  4. Energy potential of the modified excess sludge

    Directory of Open Access Journals (Sweden)

    Zawieja Iwona

    2017-01-01

    Full Text Available On the basis of the SCOD value of excess sludge it is possible to estimate an amount of energy potentially obtained during the methane fermentation process. Based on a literature review, it has been estimated that from 1 kg of SCOD it is possible to obtain 3.48 kWh of energy. Taking into account the above methane and energy ratio (i.e. 10 kWh/1Nm3 CH4, it is possible to determine the volume of methane obtained from the tested sludge. Determination of potential energy of sludge is necessary for the use of biogas as a source of power generators as cogeneration and ensure the stability of this type of system. Therefore, the aim of the study was to determine the energy potential of excess sludge subjected to the thermal and chemical disintegration. In the case of thermal disintegration, test was conducted in the low temperature 80°C. The reagent used for the chemical modification was a peracetic acid, which in an aqueous medium having strong oxidizing properties. The time of chemical modification was 6 hours. Applied dose of the reagent was 1.0 ml CH3COOOH/L of sludge. By subjecting the sludge disintegration by the test methods achieved an increase in the SCOD value of modified sludge, indicating the improvement of biodegradability along with a concomitant increase in their energy potential. The obtained experimental production of biogas from disintegrated sludge confirmed that it is possible to estimate potential intensity of its production. The SCOD value of 2576 mg O2/L, in the case of chemical disintegration, was obtained for a dose of 1.0 ml CH3COOH/L. For this dose the pH value was equal 6.85. In the case of thermal disintegration maximum SCOD value was 2246 mg O2/L obtained at 80°C and the time of preparation 6 h. It was estimated that in case of thermal disintegration as well as for the chemical disintegration for selected parameters, the potential energy for model digester of active volume of 5L was, respectively, 0.193 and 0,118 kWh.

  5. Status of the scalar singlet dark matter model

    Science.gov (United States)

    Athron, Peter; Balázs, Csaba; Bringmann, Torsten; Buckley, Andy; Chrząszcz, Marcin; Conrad, Jan; Cornell, Jonathan M.; Dal, Lars A.; Edsjö, Joakim; Farmer, Ben; Jackson, Paul; Kahlhoefer, Felix; Krislock, Abram; Kvellestad, Anders; McKay, James; Mahmoudi, Farvah; Martinez, Gregory D.; Putze, Antje; Raklev, Are; Rogan, Christopher; Saavedra, Aldo; Savage, Christopher; Scott, Pat; Serra, Nicola; Weniger, Christoph; White, Martin

    2017-08-01

    One of the simplest viable models for dark matter is an additional neutral scalar, stabilised by a Z_2 symmetry. Using the GAMBIT package and combining results from four independent samplers, we present Bayesian and frequentist global fits of this model. We vary the singlet mass and coupling along with 13 nuisance parameters, including nuclear uncertainties relevant for direct detection, the local dark matter density, and selected quark masses and couplings. We include the dark matter relic density measured by Planck, direct searches with LUX, PandaX, SuperCDMS and XENON100, limits on invisible Higgs decays from the Large Hadron Collider, searches for high-energy neutrinos from dark matter annihilation in the Sun with IceCube, and searches for gamma rays from annihilation in dwarf galaxies with the Fermi-LAT. Viable solutions remain at couplings of order unity, for singlet masses between the Higgs mass and about 300 GeV, and at masses above ˜ 1 TeV. Only in the latter case can the scalar singlet constitute all of dark matter. Frequentist analysis shows that the low-mass resonance region, where the singlet is about half the mass of the Higgs, can also account for all of dark matter, and remains viable. However, Bayesian considerations show this region to be rather fine-tuned.

  6. Status of the scalar singlet dark matter model

    Energy Technology Data Exchange (ETDEWEB)

    Athron, Peter; Balazs, Csaba [Monash University, School of Physics and Astronomy, Melbourne, VIC (Australia); Australian Research Council Centre of Excellence for Particle Physics at the Tera-scale (Australia); Bringmann, Torsten; Dal, Lars A.; Krislock, Abram; Raklev, Are [University of Oslo, Department of Physics, Oslo (Norway); Buckley, Andy [University of Glasgow, SUPA, School of Physics and Astronomy, Glasgow (United Kingdom); Chrzaszcz, Marcin [Universitaet Zuerich, Physik-Institut, Zurich (Switzerland); Polish Academy of Sciences, H. Niewodniczanski Institute of Nuclear Physics, Krakow (Poland); Conrad, Jan; Edsjoe, Joakim; Farmer, Ben [AlbaNova University Centre, Oskar Klein Centre for Cosmoparticle Physics, Stockholm (Sweden); Stockholm University, Department of Physics, Stockholm (Sweden); Cornell, Jonathan M. [McGill University, Department of Physics, Montreal, QC (Canada); Jackson, Paul; White, Martin [Australian Research Council Centre of Excellence for Particle Physics at the Tera-scale (Australia); University of Adelaide, Department of Physics, Adelaide, SA (Australia); Kahlhoefer, Felix [DESY, Hamburg (Germany); Kvellestad, Anders; Savage, Christopher [NORDITA, Stockholm (Sweden); McKay, James; Scott, Pat [Imperial College London, Department of Physics, Blackett Laboratory, London (United Kingdom); Mahmoudi, Farvah [Univ. Lyon, Univ. Lyon 1, ENS de Lyon, CNRS, Centre de Recherche Astrophysique de Lyon UMR5574, Saint-Genis-Laval (France); CERN, Theoretical Physics Department, Geneva (Switzerland); Martinez, Gregory D. [University of California, Physics and Astronomy Department, Los Angeles, CA (United States); Putze, Antje [LAPTh, Universite de Savoie, CNRS, Annecy-le-Vieux (France); Rogan, Christopher [Harvard University, Department of Physics, Cambridge, MA (United States); Saavedra, Aldo [Australian Research Council Centre of Excellence for Particle Physics at the Tera-scale (Australia); The University of Sydney, Centre for Translational Data Science, Faculty of Engineering and Information Technologies, School of Physics, Sydney, NSW (Australia); Serra, Nicola [Universitaet Zuerich, Physik-Institut, Zurich (Switzerland); Weniger, Christoph [University of Amsterdam, GRAPPA, Institute of Physics, Amsterdam (Netherlands); Collaboration: The GAMBIT Collaboration

    2017-08-15

    One of the simplest viable models for dark matter is an additional neutral scalar, stabilised by a Z{sub 2} symmetry. Using the GAMBIT package and combining results from four independent samplers, we present Bayesian and frequentist global fits of this model. We vary the singlet mass and coupling along with 13 nuisance parameters, including nuclear uncertainties relevant for direct detection, the local dark matter density, and selected quark masses and couplings. We include the dark matter relic density measured by Planck, direct searches with LUX, PandaX, SuperCDMS and XENON100, limits on invisible Higgs decays from the Large Hadron Collider, searches for high-energy neutrinos from dark matter annihilation in the Sun with IceCube, and searches for gamma rays from annihilation in dwarf galaxies with the Fermi-LAT. Viable solutions remain at couplings of order unity, for singlet masses between the Higgs mass and about 300 GeV, and at masses above ∝ 1 TeV. Only in the latter case can the scalar singlet constitute all of dark matter. Frequentist analysis shows that the low-mass resonance region, where the singlet is about half the mass of the Higgs, can also account for all of dark matter, and remains viable. However, Bayesian considerations show this region to be rather fine-tuned. (orig.)

  7. Status of the scalar singlet dark matter model

    International Nuclear Information System (INIS)

    Athron, Peter; Balazs, Csaba; Bringmann, Torsten; Dal, Lars A.; Krislock, Abram; Raklev, Are; Buckley, Andy; Chrzaszcz, Marcin; Conrad, Jan; Edsjoe, Joakim; Farmer, Ben; Cornell, Jonathan M.; Jackson, Paul; White, Martin; Kahlhoefer, Felix; Kvellestad, Anders; Savage, Christopher; McKay, James; Scott, Pat; Mahmoudi, Farvah; Martinez, Gregory D.; Putze, Antje; Rogan, Christopher; Saavedra, Aldo; Serra, Nicola; Weniger, Christoph

    2017-01-01

    One of the simplest viable models for dark matter is an additional neutral scalar, stabilised by a Z 2 symmetry. Using the GAMBIT package and combining results from four independent samplers, we present Bayesian and frequentist global fits of this model. We vary the singlet mass and coupling along with 13 nuisance parameters, including nuclear uncertainties relevant for direct detection, the local dark matter density, and selected quark masses and couplings. We include the dark matter relic density measured by Planck, direct searches with LUX, PandaX, SuperCDMS and XENON100, limits on invisible Higgs decays from the Large Hadron Collider, searches for high-energy neutrinos from dark matter annihilation in the Sun with IceCube, and searches for gamma rays from annihilation in dwarf galaxies with the Fermi-LAT. Viable solutions remain at couplings of order unity, for singlet masses between the Higgs mass and about 300 GeV, and at masses above ∝ 1 TeV. Only in the latter case can the scalar singlet constitute all of dark matter. Frequentist analysis shows that the low-mass resonance region, where the singlet is about half the mass of the Higgs, can also account for all of dark matter, and remains viable. However, Bayesian considerations show this region to be rather fine-tuned. (orig.)

  8. Microscopic optical potential at medium energies

    International Nuclear Information System (INIS)

    Malecki, A.

    1979-01-01

    The problems concerning a microscopic optical model for the elastic nuclear collisions at medium energies are discussed. We describe the method for constructing the optical potential which makes use of the particular properties of quantum scattering in the eikonal limit. The resulting potential is expressed in terms of the nuclear wave functions and the nucleon-nucleon scattering amplitudes. This potential has a dynamic character since by including the effects of multiple scattering it allows for the possibility of intermediate excitations of the projectile and target nuclei. The use of the potential in the exact wave equation accounts for the most important mechanisms present in the collisions between composite particles. The microscopic optical model was successfully applied in the analysis of elastic scattering of protons and α-particles on atomic nuclei in the energy range of 300-1000 MeV/nucleon. The dynamic optical potential in this case represents a considerable improvement over the eikonal Glauber model and the static optical potential of Watson. The possibilities to extend the microscopic description of the proton-nucleus interaction by considering the spin dependence of the elementary amplitude and the Majorana exchange effects were investigated. (author)

  9. Potential Energy Cost Savings from Increased Commercial Energy Code Compliance

    Energy Technology Data Exchange (ETDEWEB)

    Rosenberg, Michael I.; Hart, Philip R.; Athalye, Rahul A.; Zhang, Jian; Cohan, David F.

    2016-08-22

    An important question for commercial energy code compliance is: “How much energy cost savings can better compliance achieve?” This question is in sharp contrast to prior efforts that used a checklist of code requirements, each of which was graded pass or fail. Percent compliance for any given building was simply the percent of individual requirements that passed. A field investigation method is being developed that goes beyond the binary approach to determine how much energy cost savings is not realized. Prototype building simulations were used to estimate the energy cost impact of varying levels of non-compliance for newly constructed office buildings in climate zone 4C. Field data collected from actual buildings on specific conditions relative to code requirements was then applied to the simulation results to find the potential lost energy savings for a single building or for a sample of buildings. This new methodology was tested on nine office buildings in climate zone 4C. The amount of additional energy cost savings they could have achieved had they complied fully with the 2012 International Energy Conservation Code is determined. This paper will present the results of the test, lessons learned, describe follow-on research that is needed to verify that the methodology is both accurate and practical, and discuss the benefits that might accrue if the method were widely adopted.

  10. Wave energy potential in Galicia (NW Spain)

    DEFF Research Database (Denmark)

    Iglesias, Gregorio; López, Mario; Carballo, Rodrigo

    2009-01-01

    harsh wave climate; in this work its potential for energy production is assessed based on three-hourly data from a third generation ocean wave model (WAM) covering the period 1996 - 2005. Taking into account the results of this assessment along with other relevant considerations such as the location...... of ports, navigation routes, and fishing and aquaculture zones, an area is selected for wave energy exploitation. The transformation of the offshore wave field as it propagates into this area is computed by means of a nearshore wave model (SWAN) in order to select the optimum locations for a wave farm. Two...

  11. Computed potential energy surfaces for chemical reactions

    Science.gov (United States)

    Walch, Stephen P.

    1994-01-01

    Quantum mechanical methods have been used to compute potential energy surfaces for chemical reactions. The reactions studied were among those believed to be important to the NASP and HSR programs and included the recombination of two H atoms with several different third bodies; the reactions in the thermal Zeldovich mechanism; the reactions of H atom with O2, N2, and NO; reactions involved in the thermal De-NO(x) process; and the reaction of CH(squared Pi) with N2 (leading to 'prompt NO'). These potential energy surfaces have been used to compute reaction rate constants and rates of unimolecular decomposition. An additional application was the calculation of transport properties of gases using a semiclassical approximation (and in the case of interactions involving hydrogen inclusion of quantum mechanical effects).

  12. Potential energy surface of triplet O4.

    Science.gov (United States)

    Paukku, Yuliya; Varga, Zoltan; Truhlar, Donald G

    2018-03-28

    We present a global ground-state potential energy surface (PES) for the triplet spin state of O 4 that is suitable for treating high-energy vibrational-rotational energy transfer and collision-induced dissociation in electronically adiabatic spin-conserving O 2 -O 2 collisions. The surface is based on MS-CASPT2/maug-cc-pVTZ electronic structure calculations with scaled external correlation; the active space has 16 electrons in 12 orbitals. The global ground-state potential energy surface was fitted by a many-body approach with an accurate O-O pairwise interaction and a fit of the many-body interaction potential to 10 180 electronic structure data points. The many-body fit is based on permutationally invariant polynomials in terms of bond-order functions of the six interatomic distances; the bond-order functions are mixed exponential-Gaussian functions. The geometries calculated and used for the fit include geometry scans corresponding to dissociative and vibrationally excited diatom-diatom collisions of O 2 , scans corresponding to O 3 interacting with O, additional geometries identified by running trajectories, and geometries along linear synchronous transit paths connecting randomly selected points. The global O 4 PES includes subsurfaces describing the interaction of diatomic molecules with other diatomic molecules or interactions of triatomic molecules and an atom. The interaction of ozone with a ground-state oxygen atom occurs on the triplet O 4 surface, and our surface includes high-energy points with O 3 -O geometries as well as O 2 -O 2 geometries and O 2 -O-O geometries.

  13. The Wind Energy Potential of Iceland

    Science.gov (United States)

    Nawri, Nikolai; Nína Petersen, Guðrún; Bjornsson, Halldór; Hahmann, Andrea N.; Jónasson, Kristján; Bay Hasager, Charlotte; Clausen, Niels-Erik

    2014-05-01

    While Iceland has an abundant wind energy resource, its use for electrical power production has so far been limited. Electricity in Iceland is generated primarily from hydro- and geothermal sources, and adding wind energy has so far not been considered practical or even necessary. However, wind energy is becoming a more viable option, as opportunities for new hydro- or geothermal power installations become limited. In order to obtain an estimate of the wind energy potential of Iceland, a wind atlas has been developed as part of the joint Nordic project 'Improved Forecast of Wind, Waves and Icing' (IceWind). Downscaling simulations performed with the Weather Research and Forecasting (WRF) model were used to determine the large-scale wind energy potential of Iceland. Local wind speed distributions are represented by Weibull statistics. The shape parameter across Iceland varies between 1.2 and 3.6, with the lowest values indicative of near-exponential distributions at sheltered locations, and the highest values indicative of normal distributions at exposed locations in winter. Compared with summer, average power density in winter is increased throughout Iceland by a factor of 2.0 - 5.5. In any season, there are also considerable spatial differences in average wind power density. Relative to the average value within 10 km of the coast, power density across Iceland varies between 50 - 250%, excluding glaciers, or between 300 - 1500 W m-2 at 50 m above ground level in winter. At intermediate elevations of 500 - 1000 m above mean sea level, power density is independent of the distance to the coast. In addition to seasonal and spatial variability, differences in average wind speed and power density also exist for different wind directions. Along the coast in winter, power density of onshore winds is higher by 100 - 700 W m-2 than that of offshore winds. The regions with the highest average wind speeds are impractical for wind farms, due to the distances from road

  14. Energy Savings Potential of Radiative Cooling Technologies

    Energy Technology Data Exchange (ETDEWEB)

    Fernandez, Nicholas [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Wang, Weimin [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Alvine, Kyle J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Katipamula, Srinivas [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2015-11-30

    Pacific Northwest National Laboratory (PNNL), with funding from the U.S. Department of Energy’s (DOE’s) Building Technologies Program (BTP), conducted a study to estimate, through simulation, the potential cooling energy savings that could be achieved through novel approaches to capturing free radiative cooling in buildings, particularly photonic ‘selective emittance’ materials. This report documents the results of that study.

  15. Endogenous Generation of Singlet Oxygen and Ozone in Human and Animal Tissues: Mechanisms, Biological Significance, and Influence of Dietary Components

    Directory of Open Access Journals (Sweden)

    Arnold N. Onyango

    2016-01-01

    Full Text Available Recent studies have shown that exposing antibodies or amino acids to singlet oxygen results in the formation of ozone (or an ozone-like oxidant and hydrogen peroxide and that human neutrophils produce both singlet oxygen and ozone during bacterial killing. There is also mounting evidence that endogenous singlet oxygen production may be a common occurrence in cells through various mechanisms. Thus, the ozone-producing combination of singlet oxygen and amino acids might be a common cellular occurrence. This paper reviews the potential pathways of formation of singlet oxygen and ozone in vivo and also proposes some new pathways for singlet oxygen formation. Physiological consequences of the endogenous formation of these oxidants in human tissues are discussed, as well as examples of how dietary factors may promote or inhibit their generation and activity.

  16. The wind energy potential in Argentina

    International Nuclear Information System (INIS)

    Alvarez, P

    2005-01-01

    The wind energy are increasing its contribution to large scale electricity generation in many countries.The high technical maturity reached by modern wind turbines returns it viable and competitive in many regions, specially in those where a suitable legal framework stimulates the generation from renewable sources of energy.As this regard, the objective of this report is to demonstrate that, far from being limited to provide energy to remote, dispersed or geographically isolated sites not served by conventional networks, the wind energy has fully potential to supply a pretty relevant part of the electrical consumption of the great urban centers located in those zones of the country favored with this resource.For it, two preliminary estimations has done: the total 'windy' surface area in geographic proximity of the high voltage lines and electrical substations of the Argentine System of Interconnection (SADI) able 'to be seeded' with wind turbines, and the total electrical energy feasible of being generated from them.The paper supposes the exclusion of important non apt areas by virtue of strictly geographic, economic or environmental considerations.Even so, the result of the final calculation is extraordinarily high and promissory: if only 4% of the total surface of the contiguous land areas (in a maximum radius of 62 km) to the high voltage transmission system (in which the annual mean wind speed surpasses the 5.55 m/s) would be filled with power wind turbines, the annual average energy produced by them would be equivalent to 89% of the estimated national electrical consumption for year 2013.The usable wind potential in favorable technical conditions for commercial generation rounds this way around 40,000 MW, that would report an annual average energy of 100,000 GWh, occupying an area near 5000 km 2 .The total wind energy potential is (of course) considerably greater. Anyway, given the random nature of the wind and the consequent characteristics of not firm power

  17. Energy saving potential in existing industrial compressors

    International Nuclear Information System (INIS)

    Vittorini, Diego; Cipollone, Roberto

    2016-01-01

    The Compressed Air Sector accounts for a mean 10% worldwide electricity consumption, which ensures about its importance, when energy saving and CO 2 emissions reduction are in question. Since the compressors alone account for 15% overall industry electricity consumption, it appears vital to pay attention to machine performances. The paper presents an overview of present compressor technology and focuses on saving directions for screw and sliding vanes machines, according to data provided by the Compressed Air and Gas Institute and PNEUROP. Data were processed to obtain consistency with fixed reference pressures and organized as a function of main operating parameters. Each sub-term, contributing to the overall efficiency (adiabatic, volumetric, mechanical, electric, organic), was considered separately: the analysis showed that the thermodynamic improvement during compression achievable by splitting the compression in two stages, with a lower compression ratio, opens the way to significantly reduce the energy specific consumption. - Highlights: • Compressors technology overview in industrial compressed air systems. • Market compressors efficiency baseline definition. • Energy breakdown and evaluation of main efficiency terms. • Assessment of air cooling-related energy saving potential. • Energy specific consumption reduction through dual stage compression.

  18. Geothermal energy in Yugoslavia, potentials and applications

    International Nuclear Information System (INIS)

    Boreli, F.; Paradjanin, Lj.; Stankovic, Srb.

    2002-01-01

    This paper promotes the use of Geothermal energy (GTE) in Serbia, and argues that while GTE is both a viable and environmentally friendly energy source, as demonstrated elsewhere in the world, there is also a multitude of opportunities in this region, and the local knowledge and capabilities required for implementing the GTE plants. First, a general introduction to GTE in is given. The basis of GTE is the thermal energy accumulated in fluids and rocks masses in the Earth's Crust. The main GTE advantage compared to the traditional energy sources like thermo-electric plants is the absence of environmental deterioration, however GTE also has advantages compared to other NARES, as the GT sources are permanently available and independent of weather conditions. Worldwide energy potential of GTE is huge, as the reduction of Earth Crust temperature for just 0.1 deg. C would give enough Energy to produce Electrical Energy, at the present dissipation level, for the next 15,000 years. An overview of the regions in Yugoslavia which have a high GTE potential is given. There are two distinct regions with higher GTE values in Serbia: the first is a part of the South Panonian basin including Vojvodina, with Macva and Yu-part along Danube and Morava rivers. This is a sedimental part of the Tercier's Panonic Sea 'Parathetis', with partial depression and Backa subsupression, and is well investigated due to oil and gas holeboring. The second region includes Central and Southern part of Serbia, south from the Panonia basin, with pretercier's and tercier's magmatic volcanic intrusions, which produce a very high and stable thermal flux. This Region is rich in GT-warm water springs with stable yields, and includes 217 locations with 970 natural springs with temperature above 20 deg. C. These compare very favorably with international locations where GTE is exploited. GTE can be used for Electric Energy production using corresponding heat pump systems, for house heating and warm water

  19. Colour singlets in perturbative QCD

    International Nuclear Information System (INIS)

    Bassetto, A.

    1979-01-01

    In the axial gauge and at the leading log level, a definite and consistent picture seems to emerge of a parton decay into states in which many partons are found just before confinement should take place. They are grouped into colourless clusters in a number sufficient to exhaust the ''final'' state, still possessing a finite average mass. This result is peculiar of QCD, in particular of its non-abelian nature. Large transverse momenta or more generally average invariant quantities of partons are mainly due to the multiplicities involved in the branching processes. If eventually confinement would convert these clusters into hadrons (and this is of course the main issue which has still to be proven) without a large rearrangement of the colour lines, the picture we have found for colour singlets could apply to the real hadronic world. (author)

  20. Mixing of Singlet and Triplet Pairing for Surface Superconductivity

    Science.gov (United States)

    Gor'kov, L. P.; Rashba, E. I.

    2002-07-01

    We consider structure of the Cooper wave function for superconductivity in a surface layer. Broken space inversion at the surface results in lifted spin degeneracy and in two branches of the gapped energy spectrum as caused by the spin-orbit interaction. The pair wave function consists of a mixture of both singlet and triplet components. Anisotropy of the Knight shift measurable in the NMR experiments is calculated in the whole temperature regime. Implications for a few known experimental situations is briefly discussed.

  1. Development potential of wind energy in Turkey

    Directory of Open Access Journals (Sweden)

    İsmet Akova

    2011-07-01

    energy potential, as part of the renewable energy sources of Turkey, are highly important and each of these two sources has the technical potential to cover the electric production in 2008. The recent increase in the number of wind energy power stations can be related to the preparation of Turkish Wind Atlas, the preparation of legal arrangements to support private sector entrepreneurs and the rise in oil prices. Wind energy power stations are active in Marmara, Aegean region and the Mediterreanean region witnessing more constant and strong winds and are anticipated to be founded in other geographical regions as well in the future.

  2. Theoretical studies of potential energy surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Harding, L.B. [Argonne National Laboratory, IL (United States)

    1993-12-01

    The goal of this program is to calculate accurate potential energy surfaces (PES) for both reactive and nonreactive systems. To do this the electronic Schrodinger equation must be solved. Our approach to this problem starts with multiconfiguration self-consistent field (MCSCF) reference wavefunctions. These reference wavefunctions are designed to be sufficiently flexible to accurately describe changes in electronic structure over a broad range of geometries. Electron correlation effects are included via multireference, singles and doubles configuration interaction (MRSDCI) calculations. With this approach, the authors are able to provide useful predictions of the energetics for a broad range of systems.

  3. Computed potential energy surfaces for chemical reactions

    Science.gov (United States)

    Walch, Stephen P.; Levin, Eugene

    1993-01-01

    A new global potential energy surface (PES) is being generated for O(P-3) + H2 yields OH + H. This surface is being fit using the rotated Morse oscillator method, which was used to fit the previous POL-CI surface. The new surface is expected to be more accurate and also includes a much more complete sampling of bent geometries. A new study has been undertaken of the reaction N + O2 yields NO + O. The new studies have focused on the region of the surface near a possible minimum corresponding to the peroxy form of NOO. A large portion of the PES for this second reaction has been mapped out. Since state to state cross sections for the reaction are important in the chemistry of high temperature air, these studies will probably be extended to permit generation of a new global potential for reaction.

  4. Induced Seismicity Potential of Energy Technologies

    Science.gov (United States)

    Hitzman, Murray

    2013-03-01

    Earthquakes attributable to human activities-``induced seismic events''-have received heightened public attention in the United States over the past several years. Upon request from the U.S. Congress and the Department of Energy, the National Research Council was asked to assemble a committee of experts to examine the scale, scope, and consequences of seismicity induced during fluid injection and withdrawal associated with geothermal energy development, oil and gas development, and carbon capture and storage (CCS). The committee's report, publicly released in June 2012, indicates that induced seismicity associated with fluid injection or withdrawal is caused in most cases by change in pore fluid pressure and/or change in stress in the subsurface in the presence of faults with specific properties and orientations and a critical state of stress in the rocks. The factor that appears to have the most direct consequence in regard to induced seismicity is the net fluid balance (total balance of fluid introduced into or removed from the subsurface). Energy technology projects that are designed to maintain a balance between the amount of fluid being injected and withdrawn, such as most oil and gas development projects, appear to produce fewer seismic events than projects that do not maintain fluid balance. Major findings from the study include: (1) as presently implemented, the process of hydraulic fracturing for shale gas recovery does not pose a high risk for inducing felt seismic events; (2) injection for disposal of waste water derived from energy technologies does pose some risk for induced seismicity, but very few events have been documented over the past several decades relative to the large number of disposal wells in operation; and (3) CCS, due to the large net volumes of injected fluids suggested for future large-scale carbon storage projects, may have potential for inducing larger seismic events.

  5. Holographic monitoring of spatial distributions of singlet oxygen in water

    Science.gov (United States)

    Belashov, A. V.; Bel'tyukova, D. M.; Vasyutinskii, O. S.; Petrov, N. V.; Semenova, I. V.; Chupov, A. S.

    2014-12-01

    A method for monitoring spatial distributions of singlet oxygen in biological media has been developed. Singlet oxygen was generated using Radachlorin® photosensitizer, while thermal disturbances caused by nonradiative deactivation of singlet oxygen were detected by the holographic interferometry technique. Processing of interferograms yields temperature maps that characterize the deactivation process and show the distribution of singlet oxygen species.

  6. The Wind Energy Potential of Kurdistan, Iran.

    Science.gov (United States)

    Arefi, Farzad; Moshtagh, Jamal; Moradi, Mohammad

    2014-01-01

    In the current work by using statistical methods and available software, the wind energy assessment of prone regions for installation of wind turbines in, Qorveh, has been investigated. Information was obtained from weather stations of Baneh, Bijar, Zarina, Saqez, Sanandaj, Qorveh, and Marivan. The monthly average and maximum of wind speed were investigated between the years 2000-2010 and the related curves were drawn. The Golobad curve (direction and percentage of dominant wind and calm wind as monthly rate) between the years 1997-2000 was analyzed and drawn with plot software. The ten-minute speed (at 10, 30, and 60 m height) and direction (at 37.5 and 10 m height) wind data were collected from weather stations of Iranian new energy organization. The wind speed distribution during one year was evaluated by using Weibull probability density function (two-parametrical), and the Weibull curve histograms were drawn by MATLAB software. According to the average wind speed of stations and technical specifications of the types of turbines, the suitable wind turbine for the station was selected. Finally, the Divandareh and Qorveh sites with favorable potential were considered for installation of wind turbines and construction of wind farms.

  7. The Wind Energy Potential of Kurdistan, Iran

    Science.gov (United States)

    Arefi, Farzad; Moshtagh, Jamal; Moradi, Mohammad

    2014-01-01

    In the current work by using statistical methods and available software, the wind energy assessment of prone regions for installation of wind turbines in, Qorveh, has been investigated. Information was obtained from weather stations of Baneh, Bijar, Zarina, Saqez, Sanandaj, Qorveh, and Marivan. The monthly average and maximum of wind speed were investigated between the years 2000–2010 and the related curves were drawn. The Golobad curve (direction and percentage of dominant wind and calm wind as monthly rate) between the years 1997–2000 was analyzed and drawn with plot software. The ten-minute speed (at 10, 30, and 60 m height) and direction (at 37.5 and 10 m height) wind data were collected from weather stations of Iranian new energy organization. The wind speed distribution during one year was evaluated by using Weibull probability density function (two-parametrical), and the Weibull curve histograms were drawn by MATLAB software. According to the average wind speed of stations and technical specifications of the types of turbines, the suitable wind turbine for the station was selected. Finally, the Divandareh and Qorveh sites with favorable potential were considered for installation of wind turbines and construction of wind farms. PMID:27355042

  8. Computed potential energy surfaces for chemical reactions

    Science.gov (United States)

    Walch, Stephen P.

    1988-01-01

    The minimum energy path for the addition of a hydrogen atom to N2 is characterized in CASSCF/CCI calculations using the (4s3p2d1f/3s2p1d) basis set, with additional single point calculations at the stationary points of the potential energy surface using the (5s4p3d2f/4s3p2d) basis set. These calculations represent the most extensive set of ab initio calculations completed to date, yielding a zero point corrected barrier for HN2 dissociation of approx. 8.5 kcal mol/1. The lifetime of the HN2 species is estimated from the calculated geometries and energetics using both conventional Transition State Theory and a method which utilizes an Eckart barrier to compute one dimensional quantum mechanical tunneling effects. It is concluded that the lifetime of the HN2 species is very short, greatly limiting its role in both termolecular recombination reactions and combustion processes.

  9. Photo-excitation of carotenoids causes cytotoxicity via singlet oxygen production

    Energy Technology Data Exchange (ETDEWEB)

    Yoshii, Hiroshi, E-mail: yoshii@nirs.go.jp [Research Center for Radiation Emergency Medicine, National Institute of Radiological Science, Chiba 263-8555 (Japan); Faculty of Medical Sciences, University of Fukui, Eiheiji, Fukui 910-1193 (Japan); Yoshii, Yukie, E-mail: yukiey@nirs.go.jp [Molecular Imaging Center, National Institute of Radiological Science, Chiba 263-8555 (Japan); Biomedical Imaging Research Center, University of Fukui, Eiheiji, Fukui 910-1193 (Japan); Asai, Tatsuya [Biomedical Imaging Research Center, University of Fukui, Eiheiji, Fukui 910-1193 (Japan); Faculty of Engineering, University of Fukui, Fukui 910-8507 (Japan); Furukawa, Takako [Molecular Imaging Center, National Institute of Radiological Science, Chiba 263-8555 (Japan); Biomedical Imaging Research Center, University of Fukui, Eiheiji, Fukui 910-1193 (Japan); Takaichi, Shinichi [Department of Biology, Nippon Medical School, Kawasaki, Kanagawa 211-0063 (Japan); Fujibayashi, Yasuhisa [Molecular Imaging Center, National Institute of Radiological Science, Chiba 263-8555 (Japan); Biomedical Imaging Research Center, University of Fukui, Eiheiji, Fukui 910-1193 (Japan)

    2012-01-06

    Highlights: Black-Right-Pointing-Pointer Some photo-excited carotenoids have photosensitizing ability. Black-Right-Pointing-Pointer They are able to produce ROS. Black-Right-Pointing-Pointer Photo-excited fucoxanthin can produce singlet oxygen through energy transfer. -- Abstract: Carotenoids, natural pigments widely distributed in algae and plants, have a conjugated double bond system. Their excitation energies are correlated with conjugation length. We hypothesized that carotenoids whose energy states are above the singlet excited state of oxygen (singlet oxygen) would possess photosensitizing properties. Here, we demonstrated that human skin melanoma (A375) cells are damaged through the photo-excitation of several carotenoids (neoxanthin, fucoxanthin and siphonaxanthin). In contrast, photo-excitation of carotenoids that possess energy states below that of singlet oxygen, such as {beta}-carotene, lutein, loroxanthin and violaxanthin, did not enhance cell death. Production of reactive oxygen species (ROS) by photo-excited fucoxanthin or neoxanthin was confirmed using a reporter assay for ROS production with HeLa Hyper cells, which express a fluorescent indicator protein for intracellular ROS. Fucoxanthin and neoxanthin also showed high cellular penetration and retention. Electron spin resonance spectra using 2,2,6,6-tetramethil-4-piperidone as a singlet oxygen trapping agent demonstrated that singlet oxygen was produced via energy transfer from photo-excited fucoxanthin to oxygen molecules. These results suggest that carotenoids such as fucoxanthin, which are capable of singlet oxygen production through photo-excitation and show good penetration and retention in target cells, are useful as photosensitizers in photodynamic therapy for skin disease.

  10. Electroweak baryogenesis and dark matter from a singlet Higgs

    Energy Technology Data Exchange (ETDEWEB)

    Cline, James M. [Department of Physics, McGill University, 3600 Rue University, Montréal, Québec, H3A 2T8 Canada (Canada); Kainulainen, Kimmo, E-mail: jcline@physics.mcgill.ca, E-mail: kimmo.kainulainen@jyu.fi [Department of Physics, University of Jyväskylä, P.O. Box 35 (YFL), FI-40014 Jyväskylä (Finland)

    2013-01-01

    If the Higgs boson H couples to a singlet scalar S via λ{sub m}|H|{sup 2}S{sup 2}, a strong electroweak phase transition can be induced through a large potential barrier that exists already at zero temperature. In this case properties of the phase transition can be computed analytically. We show that electroweak baryogenesis can be achieved using CP violation from a dimension-6 operator that couples S to the top-quark mass, suppressed by a new physics scale that can be well above 1 TeV. Moreover the singlet is a dark matter candidate whose relic density is ∼<3% of the total dark matter density, but which nevertheless interacts strongly enough with nuclei (through Higgs exchange) to be just below the current XENON100 limits. The DM mass is predicted to be in the range 80–160 GeV.

  11. IDMS: inert dark matter model with a complex singlet

    Science.gov (United States)

    Bonilla, Cesar; Sokolowska, Dorota; Darvishi, Neda; Diaz-Cruz, J. Lorenzo; Krawczyk, Maria

    2016-06-01

    We study an extension of the inert doublet model (IDM) that includes an extra complex singlet of the scalars fields, which we call the IDMS. In this model there are three Higgs particles, among them a SM-like Higgs particle, and the lightest neutral scalar, from the inert sector, remains a viable dark matter (DM) candidate. We assume a non-zero complex vacuum expectation value for the singlet, so that the visible sector can introduce extra sources of CP violation. We construct the scalar potential of IDMS, assuming an exact Z 2 symmetry, with the new singlet being Z 2-even, as well as a softly broken U(1) symmetry, which allows a reduced number of free parameters in the potential. In this paper we explore the foundations of the model, in particular the masses and interactions of scalar particles for a few benchmark scenarios. Constraints from collider physics, in particular from the Higgs signal observed at the Large Hadron Collider with {M}h≈ 125 {{GeV}}, as well as constraints from the DM experiments, such as relic density measurements and direct detection limits, are included in the analysis. We observe significant differences with respect to the IDM in relic density values from additional annihilation channels, interference and resonance effects due to the extended Higgs sector.

  12. Energy resource potential of natural gas hydrates

    Science.gov (United States)

    Collett, T.S.

    2002-01-01

    The discovery of large gas hydrate accumulations in terrestrial permafrost regions of the Arctic and beneath the sea along the outer continental margins of the world's oceans has heightened interest in gas hydrates as a possible energy resource. However, significant to potentially insurmountable technical issues must be resolved before gas hydrates can be considered a viable option for affordable supplies of natural gas. The combined information from Arctic gas hydrate studies shows that, in permafrost regions, gas hydrates may exist at subsurface depths ranging from about 130 to 2000 m. The presence of gas hydrates in offshore continental margins has been inferred mainly from anomalous seismic reflectors, known as bottom-simulating reflectors, that have been mapped at depths below the sea floor ranging from about 100 to 1100 m. Current estimates of the amount of gas in the world's marine and permafrost gas hydrate accumulations are in rough accord at about 20,000 trillion m3. Disagreements over fundamental issues such as the volume of gas stored within delineated gas hydrate accumulations and the concentration of gas hydrates within hydrate-bearing strata have demonstrated that we know little about gas hydrates. Recently, however, several countries, including Japan, India, and the United States, have launched ambitious national projects to further examine the resource potential of gas hydrates. These projects may help answer key questions dealing with the properties of gas hydrate reservoirs, the design of production systems, and, most important, the costs and economics of gas hydrate production.

  13. Singlet-paired coupled cluster theory for open shells

    International Nuclear Information System (INIS)

    Gomez, John A.; Henderson, Thomas M.; Scuseria, Gustavo E.

    2016-01-01

    Restricted single-reference coupled cluster theory truncated to single and double excitations accurately describes weakly correlated systems, but often breaks down in the presence of static or strong correlation. Good coupled cluster energies in the presence of degeneracies can be obtained by using a symmetry-broken reference, such as unrestricted Hartree-Fock, but at the cost of good quantum numbers. A large body of work has shown that modifying the coupled cluster ansatz allows for the treatment of strong correlation within a single-reference, symmetry-adapted framework. The recently introduced singlet-paired coupled cluster doubles (CCD0) method is one such model, which recovers correct behavior for strong correlation without requiring symmetry breaking in the reference. Here, we extend singlet-paired coupled cluster for application to open shells via restricted open-shell singlet-paired coupled cluster singles and doubles (ROCCSD0). The ROCCSD0 approach retains the benefits of standard coupled cluster theory and recovers correct behavior for strongly correlated, open-shell systems using a spin-preserving ROHF reference.

  14. Role and potential of renewable energy and energy efficiency for global energy supply

    Energy Technology Data Exchange (ETDEWEB)

    Krewitt, Wolfram; Nienhaus, Kristina [German Aerospace Center e.V. (DLR), Stuttgart (Germany); Klessmann, Corinna; Capone, Carolin; Stricker, Eva [Ecofys Germany GmbH, Berlin (Germany); Graus, Wina; Hoogwijk, Monique [Ecofys Netherlands BV, Utrecht (Netherlands); Supersberger, Nikolaus; Winterfeld, Uta von; Samadi, Sascha [Wuppertal Institute for Climate, Environment and Energy GmbH, Wuppertal (Germany)

    2009-12-15

    The analysis of different global energy scenarios in part I of the report confirms that the exploitation of energy efficiency potentials and the use of renewable energies play a key role in reaching global CO2 reduction targets. An assessment on the basis of a broad literature research in part II shows that the technical potentials of renewable energy technologies are a multiple of today's global final energy consumption. The analysis of cost estimates for renewable electricity generation technologies and even long term cost projections across the key studies in part III demonstrates that assumptions are in reasonable agreement. In part IV it is shown that by implementing technical potentials for energy efficiency improvements in demand and supply sectors by 2050 can be limited to 48% of primary energy supply in IEA's ''Energy Technology Perspectives'' baseline scenario. It was found that a large potential for cost-effective measures exists, equivalent to around 55-60% of energy savings of all included efficiency measures (part V). The results of the analysis on behavioural changes in part VI show that behavioural dimensions are not sufficiently included in energy scenarios. Accordingly major research challenges are revealed. (orig.)

  15. Interplay between singlet and triplet excited states in a conformationally locked donor–acceptor dyad

    KAUST Repository

    Filatov, Mikhail A.

    2015-10-13

    The synthesis and photophysical characterization of a palladium(II) porphyrin – anthracene dyad bridged via short and conformationally rigid bicyclo[2.2.2]octadiene spacer were achieved. A spectroscopic investigation of the prepared molecule in solution has been undertaken to study electronic energy transfer in excited singlet and triplet states between the anthracene and porphyrin units. By using steady-state and time-resolved photoluminescence spectroscopy it was shown that excitation of the singlet excited state of the anthracene leads to energy transfer to the lower-lying singlet state of porphyrin. Alternatively, excitation of the porphyrin followed by intersystem crossing to the triplet state leads to very fast energy transfer to the triplet state of anthracene. The rate of this energy transfer has been determined by transient absorption spectroscopy. Comparative studies of the dynamics of triplet excited states of the dyad and reference palladium octaethylporphyrin (PdOEP) have been performed.

  16. Potential of renewable energy systems in China

    International Nuclear Information System (INIS)

    Liu, Wen; Lund, Henrik; Mathiesen, Brian Vad; Zhang, Xiliang

    2011-01-01

    Along with high-speed economic development and increasing energy consumption, the Chinese Government faces a growing pressure to maintain the balance between energy supply and demand. In 2009, China has become both the largest energy consumer and CO 2 emitting country in the world. In this case, the inappropriate energy consumption structure should be changed. As an alternative, a suitable infrastructure for the implementation of renewable energy may serve as a long-term sustainable solution. The perspective of a 100% renewable energy system has been analyzed and discussed in some countries previously. In this process, assessment of domestic renewable energy sources is the first step. Then appropriate methodologies are needed to perform energy system analyses involving the integration of more sustainable strategies. Denmark may serve as an example of how sustainable strategies can be implemented. The Danish system has demonstrated the possibility of converting into a 100% renewable energy system. This paper discusses the perspective of renewable energy in China firstly, and then analyses whether it is suitable to adopt similar methodologies applied in other countries as China approaches a renewable energy system. The conclusion is that China's domestic renewable energy sources are abundant and show the possibility to cover future energy demand; the methodologies used to analyse a 100% renewable energy system are applicable in China. Therefore, proposing an analysis of a 100% renewable energy system in China is not unreasonable. (author)

  17. Interaction of plasmalogens and their diacyl analogs with singlet oxygen in selected model systems

    Science.gov (United States)

    Broniec, Agnieszka; Klosinski, Radoslaw; Pawlak, Anna; Wrona-Krol, Marta; Thompson, David; Sarna, Tadeusz

    2011-01-01

    Plasmalogens (Plg) are phospholipids containing vinyl ether linkage at the sn-1 position of the glycerophospholipid backbone. In spite of being quite abundant in humans, the biological role of plasmalogens remains speculative. It has been postulated that plasmalogens are physiological antioxidants with the vinyl ether functionality serving as sacrificial trap for free radicals and singlet oxygen. However, no quantitative data on the efficiency of plasmalogens to scavenge these reactive species are available. In this study, rate constants of quenching of singlet oxygen, generated by photosensitized energy transfer, by several plasmalogens and, for comparison, by their diacyl analogs, were determined by time-resolved detection of phosphorescence at 1270 nm. Relative rates of the interaction of singlet oxygen, with plasmalogens and other lipids in solution and liposomal membranes were measured by electron paramagnetic resonance oximetry and product analysis, employing HPLC-EC detection of cholesterol hydroperoxides and iodometric assay of lipid hydroperoxides. Results show that singlet oxygen interacts with plasmalogens significantly faster than with the other lipids, with he corresponding rate constants being by one-two orders of magnitude greater. The quenching of singlet oxygen by plasmalogens is mostly reactive in nature and results from its preferential interaction with the vinyl ether bond. The data suggest that plasmalogens could protect unsaturated membrane lipids against oxidation induced by singlet oxygen, providing that the oxidation products are not excessively cytotoxic. PMID:21236336

  18. Alaska's renewable energy potential.

    Energy Technology Data Exchange (ETDEWEB)

    2009-02-01

    This paper delivers a brief survey of renewable energy technologies applicable to Alaska's climate, latitude, geography, and geology. We first identify Alaska's natural renewable energy resources and which renewable energy technologies would be most productive. e survey the current state of renewable energy technologies and research efforts within the U.S. and, where appropriate, internationally. We also present information on the current state of Alaska's renewable energy assets, incentives, and commercial enterprises. Finally, we escribe places where research efforts at Sandia National Laboratories could assist the state of Alaska with its renewable energy technology investment efforts.

  19. Solar-energy potential in Turkey

    Energy Technology Data Exchange (ETDEWEB)

    Soezen, Adnan; Arcaklioglu, Erol; Oezalp, Mehmet; Kanit, E. Galip

    2005-04-01

    In this study, a new formula based on meteorological and geographical data was developed to determine the solar-energy potential in Turkey using artificial neural-networks (ANNs). Scaled conjugate gradient (SCG) and Levenberg-Marquardt (LM) learning algorithms and a logistic sigmoid transfer function were used in the network. Meteorological data for the last four years (2000 {yields} 2003) from 18 cities (Bilecik, Kirsehir, Akhisar, Bingoel, Batman, Bodrum, Uzunkoeprue, Sile, Bartin, Yalova, Horasan, Polatli, Malazgirt, Koeycegiz, Manavgat, Doertyol, Karatas and Birecik) spread over Turkey were used as data in order to train the neural network. Meteorological and geographical data (latitude, longitude, altitude, month, mean sunshine duration, and mean temperature) were used in the input layer of the network. Solar radiation is the output layer. One-month test data for each city was used, and these months data were not used for training. The results show that the maximum mean absolute percentage error (MAPE) was found to be 3.448% and the R{sup 2} value 0.9987 for Polatli. The best approach was found for Kirsehir (MAPE=1.2257, R{sup 2}=0.9998). The MAPE and R{sup 2} for the testing data were 3.3477 and 0.998534, respectively. The ANN models show greater accuracy for evaluating solar-resource possibilities in regions where a network of monitoring stations has not been established in Turkey. This study confirms the ability of the ANN to predict solar-radiation values precisely.

  20. Solar-energy potential in Turkey

    Energy Technology Data Exchange (ETDEWEB)

    Sozen, Adnan; Ozalp, Mehmet [Gazi Univ., Mechanical Education Dept., Ankara (Turkey); Arcaklioglu, Erol [Kirikkale Univ., Mechanical Engineering Dept., Kirikkale (Turkey); Kanit, E. Galip [Turkish State Meteorological Office, Ankara (Turkey)

    2005-04-01

    In this study, a new formula based on meteorological and geographical data was developed to determine the solar-energy potential in Turkey using artificial neural-networks (ANNs). Scaled conjugate gradient (SCG) and Levenberg-Marquardt (LM) learning algorithms and a logistic sigmoid transfer function were used in the network. Meteorological data for the last four years (2000-2003) from 18 cities (Bilecik, Kirsehir, Akhisar, Bingol, Batman, Bodrum, Uzunkopru, Sile, Bartin, Yalova, Horasan, Polatli, Malazgirt, Koycegiz, Manavgat, Dortyol, Karatas and Birecik) spread over Turkey were used as data in order to train the neural network. Meteorological and geographical data (latitude, longitude, altitude, month, mean sunshine duration, and mean temperature) were used in the input layer of the network. Solar radiation is the output layer. One-month test data for each city was used, and these months data were not used for training. The results show that the maximum mean absolute percentage error (MAPE) was found to be 3.448% and the R{sup 2} value 0.9987 for Polatli. The best approach was found for Kirsehir (MAPE=1.2257, R{sup 2}=0.9998). The MAPE and R{sup 2} for the testing data were 3.3477 and 0.998534, respectively. The ANN models show greater accuracy for evaluating solar-resource possibilities in regions where a network of monitoring stations has not been established in Turkey. This study confirms the ability of the ANN to predict solar-radiation values precisely (Author)

  1. Solar-energy potential in Turkey

    International Nuclear Information System (INIS)

    Soezen, Adnan; Arcaklioglu, Erol; Oezalp, Mehmet; Kanit, E. Galip

    2005-01-01

    In this study, a new formula based on meteorological and geographical data was developed to determine the solar-energy potential in Turkey using artificial neural-networks (ANNs). Scaled conjugate gradient (SCG) and Levenberg-Marquardt (LM) learning algorithms and a logistic sigmoid transfer function were used in the network. Meteorological data for the last four years (2000 → 2003) from 18 cities (Bilecik, Kirsehir, Akhisar, Bingoel, Batman, Bodrum, Uzunkoeprue, Sile, Bartin, Yalova, Horasan, Polatli, Malazgirt, Koeycegiz, Manavgat, Doertyol, Karatas and Birecik) spread over Turkey were used as data in order to train the neural network. Meteorological and geographical data (latitude, longitude, altitude, month, mean sunshine duration, and mean temperature) were used in the input layer of the network. Solar radiation is the output layer. One-month test data for each city was used, and these months data were not used for training. The results show that the maximum mean absolute percentage error (MAPE) was found to be 3.448% and the R 2 value 0.9987 for Polatli. The best approach was found for Kirsehir (MAPE=1.2257, R 2 =0.9998). The MAPE and R 2 for the testing data were 3.3477 and 0.998534, respectively. The ANN models show greater accuracy for evaluating solar-resource possibilities in regions where a network of monitoring stations has not been established in Turkey. This study confirms the ability of the ANN to predict solar-radiation values precisely

  2. Renewable Energy Potential for New Mexico

    Science.gov (United States)

    RE-Powering America's Land: Renewable Energy on Contaminated Land and Mining Sites was presented by Penelope McDaniel, during the 2008 Brown to Green: Make the Connection to Renewable Energy workshop.

  3. Potential of renewable energy systems in China

    DEFF Research Database (Denmark)

    Liu, Wen; Lund, Henrik; Mathiesen, Brian Vad

    2011-01-01

    , the inappropriate energy consumption structure should be changed. As an alternative, a suitable infrastructure for the implementation of renewable energy may serve as a long-term sustainable solution. The perspective of a 100% renewable energy system has been analyzed and discussed in some countries previously....... In this process, assessment of domestic renewable energy sources is the first step. Then appropriate methodologies are needed to perform energy system analyses involving the integration of more sustainable strategies. Denmark may serve as an example of how sustainable strategies can be implemented. The Danish...... system has demonstrated the possibility of converting into a 100% renewable energy system. This paper discusses the perspective of renewable energy in China firstly, and then analyses whether it is suitable to adopt similar methodologies applied in other countries as China approaches a renewable energy...

  4. The energy dependence of the nucleon-nucleus potential

    International Nuclear Information System (INIS)

    Mackintosh, R.S.; Cooper, S.G.

    1997-01-01

    By way of evaluating a new procedure for energy-dependent inversion we have compared the energy dependence of the local potential phase equivalent to the Perey-Buck non-local potential with the energy dependence of local potentials derived from RGM and phenomenology. (author)

  5. Potential energy savings and thermal comfort

    DEFF Research Database (Denmark)

    Jensen, Karsten Ingerslev; Rudbeck, Claus Christian; Schultz, Jørgen Munthe

    1996-01-01

    Results of simulations carried out on four different buildings with common windows, commercial low-energy windows and xerogel windows are presented. The results are the annual energy consumption for space heating and the indoor air temperature level.......Results of simulations carried out on four different buildings with common windows, commercial low-energy windows and xerogel windows are presented. The results are the annual energy consumption for space heating and the indoor air temperature level....

  6. Residential Energy Efficiency Potential: New York

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-02

    Energy used by New York single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  7. Residential Energy Efficiency Potential: South Carolina

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-02

    Energy used by South Carolina single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  8. Residential Energy Efficiency Potential: New Hampshire

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-16

    Energy used by New Hampshire single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  9. Residential Energy Efficiency Potential: New Jersey

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-16

    Energy used by New Jersey single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  10. Residential Energy Efficiency Potential: North Carolina

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-02

    Energy used by North Carolina single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  11. Residential Energy Efficiency Potential: New Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-02

    Energy used by New Mexico single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  12. Residential Energy Efficiency Potential: North Dakota

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-02

    Energy used by North Dakota single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  13. Residential Energy Efficiency Potential: West Virginia

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-27

    Energy used by West Virginia single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  14. Residential Energy Efficiency Potential: Rhode Island

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-02

    Energy used by Rhode Island single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  15. Residential Energy Efficiency Potential: South Dakota

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-11-02

    Energy used by South Dakota single-family homes that can be saved through cost-effective improvements. Prepared by Eric Wilson and Noel Merket, NREL, and Erin Boyd, U.S. Department of Energy Office of Energy Policy and Systems Analysis.

  16. Renewable energy - its potential and limitations

    International Nuclear Information System (INIS)

    Read, W.R.

    1990-01-01

    Several renewable energy options are discussed, namely solar energy, passive solar systems, photovoltaics, wind energy and biomass. Although technical feasibility has been shown for various systems, there has been slow growth in their implementation. Some aspects of this slow growth are in the domains of economic viability, long term reliability, the training of operators and installers, public perception and education and govenmental attitudes. It is estimated that the increased use of renewable energy depends on several factors which include government policies, funding, energy conservation, pricing policies, reliable commercial products, public education and adequate training. 11 refs

  17. Potential energy efficiency improvements in Swedish energy intensive industries using an Energy Efficiency Obligation Scheme

    OpenAIRE

    Xylia, Maria; Silveira, Semida

    2014-01-01

    Energy Efficiency Obligation Schemes (EEOS) as suggested in the Energy Efficiency Directive (EED) could help remove barriers to energy efficiency. However, despite the fact that such schemes have been successfully implemented and proven cost-effective in several Member States, not all countries are convinced of their potential benefits. In this paper, we investigate the policy instruments that Sweden has introduced or is planning to introduce for achieving increased industrial efficiency unde...

  18. User behaviour impact on energy savings potential

    DEFF Research Database (Denmark)

    Rose, Jørgen

    2014-01-01

    When buildings are to undergo energy upgrading in Denmark, the national compliance checker, Be10, is often used to calculate expected energy savings for different energy-saving measures. The Be10 calculation is, however, very dependent on a variety of standard assumptions concerning the building...... and the residents' behaviour and if these defaults do not reflect actual circumstances, it can result in non-realisation of expected energy savings. Furthermore, a risk also exists that residents' behaviour change after the energy upgrading, e.g. to obtain improved comfort than what was possible before...... the upgrading and this could lead to further discrepancies between the calculated and the actual energy savings. This paper presents an analysis on how residents’ behaviour and the use of standard assumptions may influence expected energy savings. The analysis is performed on two typical single-family houses...

  19. Renewable energy potential in Southern Africa: conference proceedings

    International Nuclear Information System (INIS)

    1986-01-01

    This conference, held in Cape Town from 8-10 September 1986, consist of many papers discussing the renewalble energy potential in Southern Africa. The papers delivered at the conference include topics such as wind energy, ocean energy, hydroelectric resources, solar resources, wave energy, agroforestry, fuelwood, hydrogen energy and the production of energy from biomass. Several papers were delivered on solar water heating and one on nuclear vs renewable energy

  20. Singlet Exciton Fission and Photochemical Upconversion

    NARCIS (Netherlands)

    Aulin, Y.V.

    2016-01-01

    The Sun is the main source of renewable energy on Earth. Our planet receives about 174 PW of solar power. At the same time, global energy consumption from all energy sources is orders of magnitude lower and is equal to approximately 16 TW. Clearly, solar energy has a tremendous potential, as well as

  1. User behaviour impact on energy savings potential

    DEFF Research Database (Denmark)

    Rose, Jørgen

    2014-01-01

    and the residents' behaviour and if these defaults do not reflect actual circumstances, it can result in non-realisation of expected energy savings. Furthermore, a risk also exists that residents' behaviour change after the energy upgrading, e.g. to obtain improved comfort than what was possible before...... the upgrading and this could lead to further discrepancies between the calculated and the actual energy savings. This paper presents an analysis on how residents’ behaviour and the use of standard assumptions may influence expected energy savings. The analysis is performed on two typical single-family houses......, 3) Domestic hot water consumption and 4) Air change rate. Based on the analysis, a methodology is established that can be used to make more realistic and accurate predictions of expected energy savings associated with energy upgrading taking into account user behaviour....

  2. Renewable Energy in Reunion: Potentials and Outlook

    International Nuclear Information System (INIS)

    Baddour, Julien; Percebois, Jacques

    2011-01-01

    Renewable, environmentally friendly and evenly distributed across the globe, renewable energy (RES for Renewable Energy Resources) is an excellent means of taking up the global energy challenge, i.e. enabling developing countries in the south to make progress without harming the environment. Since it is particularly well suited to an island territory's character and local needs, RE is also an excellent tool that could enable France's overseas Departments and Territories to reduce their energy dependence, preserve their environment and ensure their sustainable development. In Reunion, RES benefit from marked political support and from a very favourable financial and institutional environment, which has allowed the Reunion region to become a national pioneer in the realm of thermal energy and photovoltaics. Nonetheless, RES are not a panacea as they are subject to a number of flaws. It is currently expensive and uncompetitive, intermittent and insufficiently powerful, and not always available to keep up with demand. This explains why RES cannot aspire to be a complete substitute for fossil fuels. The two energy systems complement one another to meet the region's total energy needs. This article also highlights the negative consequences of the support measures for RES (inflated costs and negative prices on the electricity markets) and underscores the need for a complementary energy policy in pricing electricity, as well as effecting energy savings, which must remain our priority. (authors)

  3. Novel foamy origin for singlet fermion masses

    Science.gov (United States)

    Ellis, John; Mavromatos, Nick E.; Nanopoulos, Dimitri V.

    2017-10-01

    We show how masses for singlet fermions can be generated by interactions with a D-particle model of space-time foam inspired by brane theory. It has been shown previously by one of the authors (N. E. M.) that such interactions may generate dynamically small masses for charged fermions via the recoils of D-particle defects interacting with photons. In this work we consider the direct interactions of D-particle with uncharged singlet fermions such as right-handed neutrinos. Quantum fluctuations of the lattice of D-particles have massless vector (spin-one) excitations that are analogues of phonons. These mediate forces with the singlet fermions, generating large dynamical masses that may be communicated to light neutrinos via the seesaw mechanism.

  4. Transport and noise properties of a normal metal-superconductor-normal metal junction with mixed singlet and chiral triplet pairings

    Science.gov (United States)

    Paul, Ganesh C.; Dutta, Paramita; Saha, Arijit

    2017-01-01

    We study transport and zero frequency shot noise properties of a normal metal-superconductor-normal metal (NSN) junction, with the superconductor having mixed singlet and chiral triplet pairings. We show that in the subgapped regime when the chiral triplet pairing amplitude dominates over that of the singlet, a resonance phenomena emerges out at zero energy where all the quantum mechanical scattering probabilities acquire a value of 0.25. At the resonance, crossed Andreev reflection mediating through such junction, acquires a zero energy peak. This reflects as a zero energy peak in the conductance as well depending on the doping concentration. We also investigate shot noise for this system and show that shot noise cross-correlation is negative in the subgapped regime when the triplet pairing dominates over the singlet one. The latter is in sharp contrast to the positive shot noise obtained when the singlet pairing is the dominating one.

  5. Potential for Geothermal Energy in Myanmar

    International Nuclear Information System (INIS)

    Khin Soe Moe

    2010-12-01

    Geothermal energy is energy obtained by tapping the heat of the earth itself from kilometers deep into the earth's crust in some places of world. It is power extracted from heat stored in the earth. It is a renewable energy source because the heat is continuously produced inside the earth. Geothermal energy originates from the heat retained within the Earth's core since the orginal formation of the planet, from radioactive decay of minerals, and from solar energy absorbed at the surface. Most high temperature geothermal heat is harvested in regions close to tectonic plate boundaries where volcanic activity rises up to the surface of the Earth. It is one of the best renewable sources of energy and is capable of maintaining its temperature. The heating cost is very low. It uses less electricity and 75 per cent more efficient than the oil furnace and 48 per cent more efficient than the gas furnace. The energy is not only used for heating a place but also for cooling down the site. It generates uniform energy and creates no sound pollution. Maintenance cost is very cheap. The life of the underground piping is more than 50 year.

  6. Energy conservation potential of surface modification technologies

    Energy Technology Data Exchange (ETDEWEB)

    Le, H.K.; Horne, D.M.; Silberglitt, R.S.

    1985-09-01

    This report assesses the energy conservation impact of surface modification technologies on the metalworking industries. The energy conservation impact of surface modification technologies on the metalworking industries is assessed by estimating their friction and wear tribological sinks and the subsequent reduction in these sinks when surface modified tools are used. Ion implantation, coatings, and laser and electron beam surface modifications are considered.

  7. Energy saving potential of energy services - experimentation on the life cycle of energy conversion equipment

    International Nuclear Information System (INIS)

    Dupont, M.

    2006-12-01

    Energy efficiency services are growing in Europe but their role is still limited. In order to evaluate the potential, we focused first of all on policy, economical and environmental mechanisms that support their development. European natural gas and electricity markets, that are now almost wholly de-regulated, are analysed and compared to their historical structure. By introducing uncertainty on energy prices, this new deal translates better the real energy costs. Energy performance contracts (EPC) limit the impact of these uncertainties on the customer energy bills by guaranteeing a financial result. As a result of the modelling of these contracts, namely operation and maintenance ones, we prove that they transfer technical and financial risks from building owners to energy service companies (ESCO) making energy saving measures easier and less expensive at the same time. These contracts are relatively widespread for heating or compressed-air processes but remain marginal for air-conditioning systems. So new methods were needed to guarantee on the long terms the efficiency of air-conditioning systems demand (1) to master the process and its performances and (2) to be able to determine precisely the energy saving potential and its realisation costs. A detailed energy audit is thus necessary for which we propose a guidance. Conclusions of audits carried out prove that energy saving potential is mainly located in equipment management and control. These optimizations are not always carried out because of a lack of contractual incentive and due to the weaknesses of audit methods. Through the involvement of an independent expert, the mandatory and regular inspection of air-conditioning systems may allow to verify and guide such practices. A three-step analysis procedure has been developed in order to maximize the inspection potential and to get higher benefits from service contracts. (author)

  8. Potential Advantages of Reusing Potentially Contaminated Land for Renewable Energy Fact Sheet

    Science.gov (United States)

    EPA promotes the reuse of potentially contaminated lands and landfills for renewable energy. This strategy creates new markets for potentially contaminated lands, while providing a sustainable land development strategy for renewable energy.

  9. Energy performance contracting - energy saving potential of selected energy conservation measures (ECM)

    Energy Technology Data Exchange (ETDEWEB)

    Johansson, M. (Dansk Energi Analyse A/S, Frederiksberg (Denmark)); Langkilde, G.; Olesen, Bjarne W. (Technical Univ. of Denmark, ICIEE, Kgs. Lyngby (Denmark)); Moerck, O. (Cenergia Energy Consultants, Herlev (Denmark)); Sundman, O. (DONG Energy, Copenhagen (Denmark)); Engelund Thomsen, K. (Aalborg Univ., SBi, Hoersholm (Denmark))

    2008-09-15

    This report has been developed under the research project 'Etablering af grundlag for energitjenester i Danmark' (project number: ENS-33031-0185) under the Danish research programme - EFP. The objective of this project has been to contribute to the utilisation of the large potential for energy conservations in the building sector within the public, industry and service sectors through the development of a better basis for decision making for both the Energy Service Companies (ESCOes) and the building owners. The EU directive on Energy Service Contracting points at the buildings as the area where the biggest potential market for energy services and energy efficiency improvements are. The EFP-project has two parts: (1) A Danish part and (2) participation in the international cooperation project 'Holistic Assesment Tool-Kit on Energy Efficient Retrofit Measures for Government Buildings (EnERGo)', Annex 46 under the IEA R and D program 'Energy Conservation In Buildings And Community Systems' (ECBCS). This report describes the Danish contributions to the IEA projects subtask B, which has a primary objective to develop a database of energy conservation measures (ECM) with descriptions and performance characteristics of these. (au)

  10. Non-diagonal processes of singlet and ordinary quark production

    International Nuclear Information System (INIS)

    Bejlin, V.A.; Vereshkov, G.M.; Kuksa, V.I.

    1995-01-01

    Non-diagonal processes of singlet and ordinary quark production are analyzed in the model where the down singlet quark mixes with the ordinary ones. The possibility of experimental selection of h-quark effects is demonstrated

  11. Potential for energy recovery from humid air streams.

    Science.gov (United States)

    Howard H. Rosen

    1979-01-01

    The potential for energy recovery from the vent stream of dryers is examined by assuming the vent stream transfers its energy in a regenerative heat exchanger. Tables present energy recovery over a range of conditions. Example problems demonstrate the use of the energy recovery tables.

  12. Energy potential in the food industry; Store energipotensialer i naeringsmiddelindustrien

    Energy Technology Data Exchange (ETDEWEB)

    Rosenberg, E; Risberg, T M; Mydske, H J; Helgerud, H E

    2007-07-01

    The food industry is one of the most power consuming industries (excluding the heavy industry) and has large potential for reducing the energy consumption. This report explains the most energy efficient measures and if the injunctions are followed

  13. Singlet oxygen-mediated protein oxidation

    DEFF Research Database (Denmark)

    Wright, Adam; Bubb, William A; Hawkins, Clare Louise

    2002-01-01

    Singlet oxygen (1O2) is generated by a number of enzymes as well as by UV or visible light in the presence of a sensitizer and has been proposed as a damaging agent in a number of pathologies including cataract, sunburn, and skin cancers. Proteins, and Cys, Met, Trp, Tyr and His side chains in pa...

  14. Recycling and imaging of nuclear singlet hyperpolarization

    DEFF Research Database (Denmark)

    Pileio, Giuseppe; Bowen, Sean; Laustsen, Christoffer

    2013-01-01

    observation of the same batch of polarized nuclei over a period of 30 min and more. We report a recycling protocol in which the enhanced nuclear polarization achieved by dissolution-DNP is observed with full intensity and then returned to singlet order. MRI experiments may be run on a portion of the available...

  15. Energy transfer in scattering by rotating potentials

    Indian Academy of Sciences (India)

    R. Narasimhan (Krishtel eMaging) 1461 1996 Oct 15 13:05:22

    In this section we study bounds of the kinetic energy on incoming and outgoing scattering states. These bounds follow from ... Let H(t) = H0 + Vt be a self-adjoint family of operators which satisfies (2.1), (2.2) and generates a unitary propagator U(t,s) ...... Math. Soc. Transl. of Math. Monographs (RI: Providence) (1992) vol. 105.

  16. Assessment of algorithms for computing moist available potential energy

    OpenAIRE

    Harris, Bethan L.; Tailleux, Remi

    2017-01-01

    Atmospheric moist available potential energy (MAPE) has been traditionally defined as the potential energy of a moist atmosphere relative to that of the adiabatically sorted reference state defining a global potential energy minimum. Finding such a reference state was recently shown to be a linear assignment problem, and therefore exactly solvable. However, this is computationally extremely expensive, so there has been much interest in developing heuristic methods for computing MAPE in practi...

  17. Comparing energy levels in isotropic and anisotropic potentials

    International Nuclear Information System (INIS)

    Pikovski, Alexander

    2015-01-01

    Qualitative information about the quantized energy levels of a system can be of great value. We study the relationship between the bound-state energies of an anisotropic potential and those of its spherical average. It is shown that the two ground-state energies satisfy an inequality, and there is a similar inequality for the first excited states. - Highlights: • Quantized energy levels in an arbitrary non-central potential are studied. • We derive inequalities between energies in a potential and its spherical average. • The results hold in three and two dimensions for any ground state and, with additional symmetry requirements for the first excited state.

  18. Free energy via thermostatted dynamic potential-energy changes

    International Nuclear Information System (INIS)

    Holian, B.L.; Posch, H.A.; Hoover, W.G.

    1993-01-01

    Three dynamical methods for computing canonical-ensemble Helmholtz free energies are discussed and compared for a thermostatted six-body harmonic chain. We use a Martyna-Klein-Tuckerman thermostat [J. Chem. Phys. 97, 2635 (1992)] with six time-reversible friction coefficients to study both single-trajectory and ensemble-averaged free-energy changes. Though all three dynamic methods produce identical long-time averages, the one based on Kirkwood's coupling-parameter theory [J. Chem. Phys. 3, 300 (1935)] converges much more rapidly than do the two based on time-integrated heat transfer

  19. Energy Savings Potential and Research & Development Opportunities for Commercial Refrigeration

    Energy Technology Data Exchange (ETDEWEB)

    none,

    2009-09-01

    This study documents the energy consumption of commercial refrigeration equipment (CRE) in the U.S. and evaluated the energy savings potential of various technologies and energy efficiency measures that could be applied to such equipment. The study provided an overview of CRE applications, assessed the energy-savings potential of CRE in the U.S., outline key barriers to adoption of energy-savings technologies, and recommended opportunities for advanced energy saving technology research. The study was modeled after an earlier 1996 report by Arthur D. Little, Inc., and updated key information, examined more equipment types, and outlined long-term research and development opportunities.

  20. Bandwidth Study on Energy Use and Potential Energy Saving Opportunities in U.S. Chemical Manufacturing

    Energy Technology Data Exchange (ETDEWEB)

    Sabine Brueske, Caroline Kramer, Aaron Fisher

    2015-06-01

    Energy bandwidth studies of U.S. manufacturing sectors can serve as foundational references in framing the range (or bandwidth) of potential energy savings opportunities. This bandwidth study examines energy consumption and potential energy savings opportunities in U.S. chemical manufacturing. The study relies on multiple sources to estimate the energy used in the production of 74 individual chemicals, representing 57% of sector-wide energy consumption. Energy savings opportunities for individual chemicals and for 15 subsectors of chemicals manufacturing are based on technologies currently in use or under development; these potential savings are then extrapolated to estimate sector-wide energy savings opportunity.

  1. Bandwidth Study on Energy Use and Potential Energy Savings Opportunities in U.S. Petroleum Refining

    Energy Technology Data Exchange (ETDEWEB)

    Sabine Brueske, Caroline Kramer, Aaron Fisher

    2015-06-01

    Energy bandwidth studies of U.S. manufacturing sectors can serve as foundational references in framing the range (or bandwidth) of potential energy savings opportunities. This bandwidth study examines energy consumption and potential energy savings opportunities in U.S. petroleum refining. The study relies on multiple sources to estimate the energy used in nine individual process areas, representing 68% of sector-wide energy consumption. Energy savings opportunities for individual processes are based on technologies currently in use or under development; these potential savings are then extrapolated to estimate sector-wide energy savings opportunity.

  2. World status of geothermal energy use: past and potential

    International Nuclear Information System (INIS)

    Lund, John

    2000-01-01

    The past and potential development of geothermal energy is reviewed, and the use of geothermal energy for power generation and direct heat utilisation is examined. The energy savings that geothermal energy provides in terms of fuel oil and carbon savings are discussed. Worldwide development of geothermal electric power (1940-2000) and direct heat utilisation (1960 to 2000), regional geothermal use in 2000, the national geothermal contributions of geothermal energy, and the installed geothermal electric generating capacities in 2000 are tabulated

  3. Renewable energy resources in Pakistan: status, potential and information systems

    International Nuclear Information System (INIS)

    Khan, A.M.

    1991-01-01

    This paper provides some details regarding the characteristic properties, potential and assessment of renewable energy compared with other forms of energy sources. It gives status of renewable energy sources in Pakistan. It also lights about the agencies providing technical information regarding renewable energy in Pakistan as well as suggestions and recommendations for the development of these resources, and over view the present status of renewable energy sources. (author)

  4. The Wind Energy Potential of Kurdistan, Iran

    OpenAIRE

    Arefi, Farzad; Moshtagh, Jamal; Moradi, Mohammad

    2014-01-01

    In the current work by using statistical methods and available software, the wind energy assessment of prone regions for installation of wind turbines in, Qorveh, has been investigated. Information was obtained from weather stations of Baneh, Bijar, Zarina, Saqez, Sanandaj, Qorveh, and Marivan. The monthly average and maximum of wind speed were investigated between the years 2000?2010 and the related curves were drawn. The Golobad curve (direction and percentage of dominant wind and calm wind...

  5. Wood Energy Potential in Northwestern South Carolina

    Science.gov (United States)

    James W. McMinn

    1986-01-01

    The quantity of unused wood in an Ill-county area in northwestern South Carolina was projected to be more than 16 million tons annually. Wood that is unsuitable for products other than fuel amounts to nearly 9 million tons annually.The most likely energy demand by industrial plants that are good candidates for wood fuel systems is 1.5 million tons annually.Maximum...

  6. Realizing the potential of nuclear energy

    International Nuclear Information System (INIS)

    Walske, C.

    1982-01-01

    The future of nuclear power, just as the future of America, can be viewed with optimism. There is hope in America's record of overcoming obstacles, but growth is essential for that hope to be realized. Despite the downturn in energy demand made possible by conservation, we will need a 35% growth in total energy for new workers and production. Electricity generated by nuclear or coal can make US production more cost-competitive, and it can power mass-transit systems, electric heat pumps, and communications and information systems. Changes in electricity and gross national product (GNP) have been more closely in step since 1973 than have total energy and GNP. The nuclear power units now under construction will add 80,000 megawatts to the 56,000 now on line. It is important to note that, while utilities are cancelling plans for nuclear plants, they aren't ordering new coal plants, which shows the impact of the high cost of money. Interest rates must come down and public-relations efforts to sell electricity must improve to change the situation. Although capital shortages are real, waste disposal is a problem of perception that was politically induced because the government failed to provide a demonstration of safety as the French are doing. Streamlined regulatory and insurance procedures can help to justify optimism in the nuclear option. 4 figures

  7. Photophysical characterization and time-resolved spectroscopy of a anthradithiophene dimer: exploring the role of conformation in singlet fission

    KAUST Repository

    Dean, Jacob C.

    2017-08-18

    Quantitative singlet fission has been observed for a variety of acene derivatives such as tetracene and pentacene, and efforts to extend the library of singlet fission compounds is of current interest. Preliminary calculations suggest anthradithiophenes exhibit significant exothermicity between the first optically-allowed singlet state, S1, and 2 × T1 with an energy difference of >5000 cm−1. Given the fulfillment of this ingredient for singlet fission, here we investigate the singlet fission capability of a difluorinated anthradithiophene dimer (2ADT) covalently linked by a (dimethylsilyl)ethane bridge and derivatized by triisobutylsilylethynyl (TIBS) groups. Photophysical characterization of 2ADT and the single functionalized ADT monomer were carried out in toluene and acetone solution via absorption and fluorescence spectroscopy, and their photo-initiated dynamics were investigated with time-resolved fluorescence (TRF) and transient absorption (TA) spectroscopy. In accordance with computational predictions, two conformers of 2ADT were observed via fluorescence spectroscopy and were assigned to structures with the ADT cores trans or cis to one another about the covalent bridge. The two conformers exhibited markedly different excited state deactivation mechanisms, with the minor trans population being representative of the ADT monomer showing primarily radiative decay, while the dominant cis population underwent relaxation into an excimer geometry before internally converting to the ground state. The excimer formation kinetics were found to be solvent dependent, yielding time constants of ∼1.75 ns in toluene, and ∼600 ps in acetone. While the difference in rates elicits a role for the solvent in stabilizing the excimer structure, the rate is still decidedly long compared to most singlet fission rates of analogous dimers, suggesting that the excimer is neither a kinetic nor a thermodynamic trap, yet singlet fission was still not observed. The result

  8. Zeta-function approach to Casimir energy with singular potentials

    International Nuclear Information System (INIS)

    Khusnutdinov, Nail R.

    2006-01-01

    In the framework of zeta-function approach the Casimir energy for three simple model system: single delta potential, step function potential and three delta potentials are analyzed. It is shown that the energy contains contributions which are peculiar to the potentials. It is suggested to renormalize the energy using the condition that the energy of infinitely separated potentials is zero which corresponds to subtraction all terms of asymptotic expansion of zeta-function. The energy obtained in this way obeys all physically reasonable conditions. It is finite in the Dirichlet limit, and it may be attractive or repulsive depending on the strength of potential. The effective action is calculated, and it is shown that the surface contribution appears. The renormalization of the effective action is discussed

  9. On colour non-singlet representations of the quark-gluon system at finite temperature

    International Nuclear Information System (INIS)

    Abbas, A.; Paria, L.

    2000-01-01

    We use a group theoretical technique to project out the partition function for a system of quarks, antiquarks and gluons onto a particular representation of the internal symmetry group SU(3): the colour singlet, colour octet and colour 27-plet, at finite temperature. We do this to calculate the thermodynamic quantities for those representations. We also calculate the change in free energy of the plasma droplet formed from the hot hadronic gas. We find that the size of the droplet in the colour-octet representation is smaller than that in the colour-singlet representations at different temperatures in the vicinity of the critical temperatures of the phase transitions. (orig.)

  10. The potential of new renewable energy sources in Switzerland

    International Nuclear Information System (INIS)

    Dietrich, P.; Kaiser, T.; Wokaun, A.

    2010-01-01

    This article presents and discusses the results of an evaluation made by the so-called 'Swiss Energy Trialogue' ETS on the potential offered by new renewable energy sources in Switzerland. The evaluation forecasts an important contribution to Swiss energy supply by renewable energy sources by the year 2050. The authors are of the opinion that, in spite of a considerable increase in the offers of renewable energy and the full use of energy saving potential, a discrepancy will exist between estimates of energy needs and the actual energy available from renewable resources if large-scale power generation facilities are not built. Activities proposed by the Swiss government are discussed and analysed. In particular, possible contributions to be made by renewable energy sources are examined. Suggestions made by ETS concerning possible courses of action are discussed

  11. Singlet-to-triplet intermediates and triplet exciton dynamics in pentacene thinfilms

    Science.gov (United States)

    Thorsmolle, Verner; Korber, Michael; Obergfell, Emanuel; Kuhlman, Thomas; Campbell, Ian; Crone, Brian; Taylor, Antoinette; Averitt, Richard; Demsar, Jure

    Singlet-to-triplet fission in organic semiconductors is a spin-conserving multiexciton process in which one spin-zero singlet excitation is converted into two spin-one triplet excitations on an ultrafast timescale. Current scientific interest into this carrier multiplication process is largely driven by prospects of enhancing the efficiency in photovoltaic applications by generating two long-lived triplet excitons by one photon. The fission process is known to involve intermediate states, known as correlated triplet pairs, with an overall singlet character, before being interchanged into uncorrelated triplets. Here we use broadband femtosecond real-time spectroscopy to study the excited state dynamics in pentacene thin films, elucidating the fission process and the role of intermediate triplet states. VKT and AJT acknowledge support by the LDRD program at Los Alamos National Laboratory and the Department of Energy, Grant No. DE-FG02-04ER118. MK, MO and JD acknowledge support by the Alexander von Humboldt Foundation.

  12. On the hypothetical utilization of atmospheric potential energy

    Directory of Open Access Journals (Sweden)

    Thomas Frisius

    2014-09-01

    Full Text Available Atmospheric potential energy is typically divided into an available and a nonavailable part. In this article a hypothetical utilization of a fraction of the nonavailable potential energy is described. This part stems from the water vapor that can be converted into the liquid phase. An energy gain results when the potential energy of the condensate relative to a reference height exceeds the energy necessary to condensate the water vapor. It is shown that this can be the case in a saturated atmosphere without convective available potential energy. Finally, simulations with the numerical cloud model HURMOD are performed to estimate the usability of the device in practice. Indeed, a positive energy output results in a simulation with immediate gathering of the condensate. On the contrary, potential energy gained falls significantly short of the necessary energy for forming the condensate when a realistic cloud microphysical scheme allowing re-evaporation of condensate is applied. Taken together it can be concluded that, a utilization of atmospheric potential energy is hypothetically possible but the practical realization is probably not feasible.

  13. An assessement of global energy resource economic potentials

    International Nuclear Information System (INIS)

    Mercure, Jean-François; Salas, Pablo

    2012-01-01

    This paper presents an assessment of global economic energy potentials for all major natural energy resources. This work is based on both an extensive literature review and calculations using natural resource assessment data. Economic potentials are presented in the form of cost-supply curves, in terms of energy flows for renewable energy sources, or fixed amounts for fossil and nuclear resources, with strong emphasis on uncertainty, using a consistent methodology that allow direct comparisons to be made. In order to interpolate through available resource assessment data and associated uncertainty, a theoretical framework and a computational methodology are given based on statistical properties of different types of resources, justified empirically by the data, and used throughout. This work aims to provide a global database for natural energy resources ready to integrate into models of energy systems, enabling to introduce at the same time uncertainty over natural resource assessments. The supplementary material provides theoretical details and tables of data and parameters that enable this extensive database to be adapted to a variety of energy systems modelling frameworks. -- Highlights: ► Global energy potentials for all major energy resources are reported. ► Theory and methodology for calculating economic energy potentials is given. ► An uncertainty analysis for all energy economic potentials is carried out.

  14. Geothermal energy potential in the San Luis Valley, Colorado

    Energy Technology Data Exchange (ETDEWEB)

    Coe, B.A.

    1980-01-01

    The background of the area itself is investigated considering the geography, population, economy, attitudes of residents, and energy demands of the area. The requirements for geothermal energy development are considered, including socio-economic, institutional, and environmental conditions as well as some technical aspects. The current, proposed, and potential geothermal energy developments are described. The summary, conclusions, and methodology are included. (MHR)

  15. Achieving wood energy potentials: evidence in northeastern Minnesota.

    Science.gov (United States)

    Dennis P. Bradley; David C. Lothner

    1987-01-01

    A study of wood energy potential in northeastern Minnesota concludes that (1) the forests of the region could support a much larger wood energy harvest without significant cost increases for other forest products; (2) existing stands are predominantly overmature and cutting more now will enhance future wood supplies for all users; (3) converting to wood energy could...

  16. The potential for microfluidics in electrochemical energy systems

    NARCIS (Netherlands)

    Modestino, Miquel A.; Fernandez Rivas, David; Hashemi, Seyyed Mohammad Hosseini; Gardeniers, Johannes G.E.; Psaltis, Demetri

    2016-01-01

    Flow based electrochemical energy conversion devices have the potential to become a prominent energy storage technology in a world driven by renewable energy sources. The optimal design of these devices depends strongly on the tradeoffs between the losses associated with multiple transport

  17. Energy saving potential of emerging technologies in milk powder production

    NARCIS (Netherlands)

    Moejes, S.N.; Boxtel, van A.J.B.

    2017-01-01

    Background: The food industry has a large potential for energy reduction which, with an eye on the future, has to be exploited. Milk powder production consists of many thermal processes and is responsible for 15% of the total energy use in the dairy industry. A reduction in energy consumption can be

  18. Physico-chemical properties and energy potential of wood wastes ...

    African Journals Online (AJOL)

    Physico-chemical properties and energy potential of wood wastes from sawmills in Benin metropolis, Nigeria. ... The results are indications that the wood wastes are suitable as feedstock for renewable energy generation with little or no threat to the environment. Keywords: Benin Metropolis; Bio-energy; Calorific value; ...

  19. Research on potential user identification model for electric energy substitution

    Science.gov (United States)

    Xia, Huaijian; Chen, Meiling; Lin, Haiying; Yang, Shuo; Miao, Bo; Zhu, Xinzhi

    2018-01-01

    The implementation of energy substitution plays an important role in promoting the development of energy conservation and emission reduction in china. Energy service management platform of alternative energy users based on the data in the enterprise production value, product output, coal and other energy consumption as a potential evaluation index, using principal component analysis model to simplify the formation of characteristic index, comprehensive index contains the original variables, and using fuzzy clustering model for the same industry user’s flexible classification. The comprehensive index number and user clustering classification based on constructed particle optimization neural network classification model based on the user, user can replace electric potential prediction. The results of an example show that the model can effectively predict the potential of users’ energy potential.

  20. Vector performance of a potential energy functional representation

    International Nuclear Information System (INIS)

    Lagana, A.; Ciccarelli, L.; Garcia, E.

    1987-01-01

    In computer codes based on classical mechanics treatments of the molecular dynamics the bottleneck to vectorization is the evaluation of the potential energy and of its derivatives. These calculations are usually confined inside ad hoc routines. Quite often these routines have a complex structure motivated by the complex form of the functional adopted for representing the molecular interaction. Typical examples of potential energy routines difficult to restructure for taking advantage of vector architectures are those concerned with interactions obtained by assembling different functional forms individually designed for describing accurately particular regions of the potential energy surface. A more favourable case are global representations of the potential energy. The authors' suggestion is to follow a multi-body expansion of the interaction. This representation of the potential energy of a triatomic system is not only quite accurate, but it is also easy to vectorize. Several ways of vectorizing related codes and their performances are discussed. Applications to chemical reactions are made

  1. Estimating the energy saving potential of telecom operators in China

    International Nuclear Information System (INIS)

    Yang, Tian-Jian; Zhang, Yue-Jun; Huang, Jin; Peng, Ruo-Hong

    2013-01-01

    A set of models are employed to estimate the potential of total energy saved of productions and segmented energy saving for telecom operators in China. During the estimation, the total energy saving is divided into that by technology and management, which are derived from technical reform and progress, and management control measures and even marketing respectively, and the estimating methodologies for energy saving potential of each segment are elaborated. Empirical results from China Mobile indicate that, first, the technical advance in communications technology accounts for the largest proportion (70%–80%) of the total energy saved of productions in telecom sector of China. Second, technical reform brings about 20%–30% of the total energy saving. Third, the proportions of energy saving brought by marketing and control measures appear relatively smaller, just less than 3%. Therefore, China's telecom operators should seize the opportunity of the revolution of communications network techniques in recent years to create an advanced network with lower energy consumption

  2. The radial shapes of intermediate energy microscopic optical potentials

    International Nuclear Information System (INIS)

    Shen Qingbiao; Wang Chang; Tian Ye; Zhuo Yizhong

    1984-01-01

    The radial shapes of intermediate energy proton microscopic optical potentials of 40 Ca are calculated with nuclear matter approach by Skyrme interactions. The calculated results show that the real central potential in central region of nucleus changes from attractive to repulsive when the energy of incident nucleon is above 150 MeV and appears apparently a 'wine-bottle-bottom' shape in the transition energy region (from 150 MeV to 300 MeV). This tendency is consistent with empirical optical potential obtained through fitting experiments and microscopic optical potential calculated with relativistic mean field theory as well as with the BHF theory. The calculated imaginary part of the microscopic optical potential changes from the dominant surface absorption into the volume absorption and its absolute value become larger as energy increases. The effects of Skyrme force parameters to the radial shape of the calculated microscopic optical potential are analysed in detail

  3. Innovative Basis of Research of Energy-Efficient Potential and Effectiveness of Renewable Energy Sources

    OpenAIRE

    Hasanov Seymur Latif oglu; Hasanov Elnur Latif oglu

    2018-01-01

    In recent years, countries of the world have been trying to attract new energy sources (wind, sun, biogas, waves, drainage, non-conventional energy sources such as hydroelectric power of small rivers) in their fuel-energy balance. Azerbaijan has renewable natural resources, favorable for its energy-efficient potential, according to the amount of sunny and windy days. In this article was given total information about renewable energy potential of Azerbaijan Republic. In this article we use inf...

  4. The off-shell nucleon-nucleon interaction in the singlet s-state

    International Nuclear Information System (INIS)

    Groot, H. de

    1975-01-01

    This thesis studies the off-shell behaviour of the neutron-proton interaction in the singlet state. To generate phase-shift-equivalent potentials a particular type of inversion problem is solved. It requires the potential to contain a non-local, separable part which is supposed to describe part of the short-range interaction. A special solution of the general inversion problem that produces potentials consisting of two separable terms is studied. Criteria to accept or reject particular inversion solutions are discussed. Neutron-proton potentials in the 1 S 0 partial wave which form part of the input for the general inversion procedure are defined. Different local potential tails are chosen, as well as varying short-range interactions, both local and non-local. The input phase shifts are discussed including three extrapolations of the phase shifts at high energy. The half-shell transition matrix for the potentials defined is studied. Some problems introduced by the additional electromagnetic interaction in the proton-proton system is investigated. (Auth.)

  5. Ukraine’s renewable energy potential as promising investment area

    OpenAIRE

    Sivitska, Svitlana

    2013-01-01

    In this research types of enewable energy have been considered, the necessity of investing has been substantiated and the main factors for alternative energy development in Ukraine have been identified.The most promising regions for investment in alternative energy on the basis of a comparison of its development potential in each regions of Ukraine have been identified and also the territorial aspect of each renewable energy sources type development has been analyzed.

  6. Future bio-energy potential under various natural constraints

    International Nuclear Information System (INIS)

    Vuuren, Detlef P. van; Vliet, Jasper van; Stehfest, Elke

    2009-01-01

    Potentials for bio-energy have been estimated earlier on the basis of estimates of potentially available land, excluding certain types of land use or land cover (land required for food production and forests). In this paper, we explore how such estimates may be influenced by other factors such as land degradation, water scarcity and biodiversity concerns. Our analysis indicates that of the original bio-energy potential estimate of 150, 80 EJ occurs in areas classified as from mild to severe land degradation, water stress, or with high biodiversity value. Yield estimates were also found to have a significant impact on potential estimates. A further 12.5% increase in global yields would lead to an increase in bio-energy potential of about 50%. Changes in bio-energy potential are shown to have a direct impact on bio-energy use in the energy model TIMER, although the relevant factor is the bio-energy potential at different cost levels and not the overall potential.

  7. Singlet Glueballs In Klebanov-Strassler Theory

    Science.gov (United States)

    Gordeli, Ivan

    In this thesis we complete the singlet glueball sector analysis of the N = 1 super-symmetric Klebanov-Strassler gauge theory. Employing the string theory holographic approach we come up with a prediction of the spectrum of lightest glueballs in SU(N) N = 1 supersymmetric Yang-Mills theory at large N. Interestingly the spectrum of some of the glueballs is consistent with the lattice results for QCD glueballs.

  8. Magnetic properties of singlet ground state systems

    International Nuclear Information System (INIS)

    Diederix, K.M.

    1979-01-01

    Experiments are described determining the properties of a magnetic system consisting of a singlet ground state. Cu(NO 3 ) 2 .2 1/2H 2 O has been studied which is a system of S = 1/2 alternating antiferromagnetic Heisenberg chains. The static properties, spin lattice relaxation time and field-induced antiferromagnetically ordered state measurements are presented. Susceptibility and magnetic cooling measurements of other compounds are summarised. (Auth.)

  9. Singlet - oxygen therapy. 'MIT-S' apparatus

    International Nuclear Information System (INIS)

    Samosyuk, I.Z.; Chukhraev, N.V.; Pisanko, O.I.

    2003-01-01

    The described method is based on using singlet-oxygen mixture with antioxiding properties. This mixture is produced by photochemical sensibilization of air or water vapour in MIT-S apparatus. Technical parameters of MIT-S are presented. The method is used for therapy of different organs, for prophylactics, treatment and rehabilitation of a series of diseases (bronchial asthma, cardio-vascular, neurologic, sugar diabet, immune diseases)

  10. High-power generator of singlet oxygen

    Czech Academy of Sciences Publication Activity Database

    Jirásek, Vít; Čenský, Miroslav; Špalek, Otomar; Kodymová, Jarmila

    2013-01-01

    Roč. 36, č. 10 (2013), s. 1755-1763 ISSN 0930-7516 Grant - others:Laser Science and Technology Centre(IN) LASTEC/FE/RKT/54/10-11 Institutional research plan: CEZ:AV0Z10100523 Keywords : high-pressure singlet oxygen generator * spray generator * centrifugal separation Subject RIV: BH - Optics, Masers, Lasers Impact factor: 2.175, year: 2013

  11. NVU dynamics. III. Simulating molecules at constant potential energy

    DEFF Research Database (Denmark)

    Ingebrigtsen, Trond; Dyre, J. C.

    2012-01-01

    This is the final paper in a series that introduces geodesic molecular dynamics at constant potential energy. This dynamics is entitled NVU dynamics in analogy to standard energy-conserving Newtonian NVE dynamics. In the first two papers [T. S. Ingebrigtsen, S. Toxvaerd, O. J. Heilmann, T. B....... In this paper, the NVU algorithm for atomic systems is extended to be able to simulate the geodesic motion of molecules at constant potential energy. We derive an algorithm for simulating rigid bonds and test this algorithm on three different systems: an asymmetric dumbbell model, Lewis-Wahnström o......-terphenyl (OTP) and rigid SPC/E water. The rigid bonds introduce additional constraints beyond that of constant potential energy for atomic systems. The rigid-bond NVU algorithm conserves potential energy, bond lengths, and step length for indefinitely long runs. The quantities probed in simulations give results...

  12. Assessing the Potential for Renewable Energy on Public Lands

    Energy Technology Data Exchange (ETDEWEB)

    2003-02-01

    This report represents an initial activity of the Bureau of Land Managements (BLM) proposed National Energy Policy Implementation Plan: identify and evaluate renewable energy resources on federal lands and any limitations on accessing them. Ultimately, BLM will prioritize land-use planning activities to increase industrys development of renewable energy resources. These resources include solar, biomass, geothermal, water, and wind energy. To accomplish this, BLM and the Department of Energys National Renewable Energy Laboratory (NREL) established a partnership to conduct an assessment of renewable energy resources on BLM lands in the western United States. The objective of this collaboration was to identify BLM planning units in the western states with the highest potential for private-sector development of renewable resources. The assessment resulted in the following findings: (1) 63 BLM planning units in nine western states have high potential for one or more renewable energy technologies; and (2) 20 BLM planning units in seven western states have high potential for power production from three or more renewable energy sources. This assessment report provides BLM with information needed to prioritize land-use planning activities on the basis of potential for the development of energy from renewable resources.

  13. A snapshot of geothermal energy potential and utilization in Turkey

    International Nuclear Information System (INIS)

    Erdogdu, Erkan

    2009-01-01

    Turkey is one of the countries with significant potential in geothermal energy. It is estimated that if Turkey utilizes all of her geothermal potential, she can meet 14% of her total energy need (heat and electricity) from geothermal sources. Therefore, today geothermal energy is an attractive option in Turkey to replace fossil fuels. Besides, increase in negative effects of fossil fuels on the environment has forced many countries, including Turkey, to use renewable energy sources. Also, Turkey is an energy importing country; more than two-thirds of her energy requirement is supplied by imports. In this context, geothermal energy appears to be one of the most efficient and effective solutions for sustainable energy development and environmental pollution prevention in Turkey. Since geothermal energy will be used more and more in the future, its current potential, usage, and assessment in Turkey is the focus of the present study. The paper not only presents a review of the potential and utilization of the geothermal energy in Turkey but also provides some guidelines for policy makers. (author)

  14. Higher-order semiclassical energy expansions for potentials with ...

    Indian Academy of Sciences (India)

    we obtain an explicit asymptotic energy expansion of symmetric odd power potentials x 2 j·1 (j- positive integer). We then show how to develop approximate semiclassical expansions for potentials x α when α is any positive real number. Keywords. Eigenenergies; asymptotic; WKB; polynomial potentials. PACS Nos 03.65.

  15. San Jose, California: Evaluating Local Solar Energy Generation Potential (City Energy: From Data to Decisions)

    Energy Technology Data Exchange (ETDEWEB)

    Office of Strategic Programs, Strategic Priorities and Impact Analysis Team

    2017-09-29

    This fact sheet "San Jose, California: Evaluating Local Solar Energy Generation Potential" explains how the City of San Jose used data from the U.S. Department of Energy's Cities Leading through Energy Analysis and Planning (Cities-LEAP) and the State and Local Energy Data (SLED) programs to inform its city energy planning. It is one of ten fact sheets in the "City Energy: From Data to Decisions" series.

  16. Singlet oxygen quenching by oxygen in tetraphenyl-porphyrin solutions

    International Nuclear Information System (INIS)

    Dedic, Roman; Korinek, Miloslav; Molnar, Alexander; Svoboda, Antonin; Hala, Jan

    2006-01-01

    Time-resolved measurement of singlet oxygen infrared phosphorescence is a powerful tool for determination of quantum yields and kinetics of its photosensitization. This technique was employed to investigate in detail the previously observed effect of singlet oxygen quenching by oxygen. The question whether the singlet oxygen is quenched by oxygen in ground or in excited state was addressed by study of two complementary dependencies of singlet oxygen lifetimes: on dissolved oxygen concentration and on excitation intensity. Oxygen concentration dependence study of meso-tetra(4-sulphonato)phenylporphyrin (TPPS 4 ) phosphorescence kinetics showed linearity of the dependence of TPPS 4 triplet state rate-constant. Corresponding bimolecular quenching constant of (1.5±0.1)x10 9 l/mol s was obtained. On the other hand, rate constants of singlet oxygen depopulation exhibit nonlinear dependence on oxygen concentration. Comparison of zero oxygen concentration-extrapolated value of singlet oxygen lifetime of (6.5±0.4) μs to (3.7±0.1) μs observed under air-saturated conditions indicates importance of the effect of quenching of singlet oxygen by oxygen. Upward-sloping dependencies of singlet oxygen depopulation rate-constant on excitation intensity evidence that singlet oxygen is predominantly quenched by oxygen in excited singlet state

  17. The Contribution of Singlet Oxygen to Insulin Resistance

    Directory of Open Access Journals (Sweden)

    Arnold N. Onyango

    2017-01-01

    Full Text Available Insulin resistance contributes to the development of diabetes and cardiovascular dysfunctions. Recent studies showed that elevated singlet oxygen-mediated lipid peroxidation precedes and predicts diet-induced insulin resistance (IR, and neutrophils were suggested to be responsible for such singlet oxygen production. This review highlights literature suggesting that insulin-responsive cells such as endothelial cells, hepatocytes, adipocytes, and myocytes also produce singlet oxygen, which contributes to insulin resistance, for example, by generating bioactive aldehydes, inducing endoplasmic reticulum (ER stress, and modifying mitochondrial DNA. In these cells, nutrient overload leads to the activation of Toll-like receptor 4 and other receptors, leading to the production of both peroxynitrite and hydrogen peroxide, which react to produce singlet oxygen. Cytochrome P450 2E1 and cytochrome c also contribute to singlet oxygen formation in the ER and mitochondria, respectively. Endothelial cell-derived singlet oxygen is suggested to mediate the formation of oxidized low-density lipoprotein which perpetuates IR, partly through neutrophil recruitment to adipose tissue. New singlet oxygen-involving pathways for the formation of IR-inducing bioactive aldehydes such as 4-hydroperoxy-(or hydroxy or oxo-2-nonenal, malondialdehyde, and cholesterol secosterol A are proposed. Strategies against IR should target the singlet oxygen-producing pathways, singlet oxygen quenching, and singlet oxygen-induced cellular responses.

  18. Intermolecular potential energy surface for CS2 dimer.

    Science.gov (United States)

    Farrokhpour, Hossein; Mombeini, Zainab; Namazian, Mansoor; Coote, Michelle L

    2011-04-15

    A new four-dimensional intermolecular potential energy surface for CS(2) dimer is obtained by ab initio calculation of the interaction energies for a range of configurations and center-of-mass separation distances for the first time. The calculations were performed using the supermolecular approach at the Møller-Plesset second-order perturbation (MP2) level of theory with the augmented correlation consistent basis sets (aug-cc-pVxZ, x = D, T) and corrected for the basis-set superposition error using the full counterpoise correction method. A two-point extrapolation method was used to extrapolate the calculated energy points to the complete basis set limit. The effect of using the higher levels of theory, quadratic configuration interaction containing single, double, and perturbative triple excitations QCISD(T) and coupled cluster singles, doubles and perturbative triples excitations CCSD(T), on the shape of potential energy surface was investigated. It is shown that the MP2 level of theory apparently performs extremely poorly for describing the intermolecular potential energy surface, overestimating the total energy by a factor of nearly 1.73 in comparison with the QCISD(T) and CCSD(T) values. The value of isotropic dipole-dipole dispersion coefficient (C(6) ) of CS(2) fluid was obtained from the extrapolated MP2 potential energy surface. The MP2 extrapolated energy points were fitted to well-known analytical potential functions using two different methods to represent the potential energy surface analytically. The most stable configuration of the dimer was determined at R = 6.23 au, α = 90°, β = 90°, and γ = 90°, with a well depth of 3.980 kcal mol(-1) at the MP2 level of theory. Finally, the calculated second virial coefficients were compared with experimental values to test the quality of the presented potential energy surface. Copyright © 2010 Wiley Periodicals, Inc.

  19. Potential of Tidal Plants and Offshore Energy Storage in India

    International Nuclear Information System (INIS)

    Lemperiere, F.

    2008-01-01

    After a discussion of the future needs of electric power in India, the author discusses the perspectives offered by different possible sources of electric energy in this country: coal, hydro, nuclear, wind, solar. These two last ones seem very promising. In order to solve the intermittency problem raised by wind and solar energy, the author discusses and assesses the needs, potentials and costs of energy storage. Then, he evokes the opportunities and possible sites for the development of tidal energy, proposes a schedule of investments for energy

  20. Potential contribution of biomass to the sustainable energy development

    International Nuclear Information System (INIS)

    Demirbas, M. Fatih; Balat, Mustafa; Balat, Havva

    2009-01-01

    Biomass is a renewable energy source and its importance will increase as national energy policy and strategy focuses more heavily on renewable sources and conservation. Biomass is considered the renewable energy source with the highest potential to contribute to the energy needs of modern society for both the industrialized and developing countries worldwide. The most important biomass energy sources are wood and wood wastes, agricultural crops and their waste byproducts, municipal solid waste, animal wastes, waste from food processing, and aquatic plants and algae. Biomass is one potential source of renewable energy and the conversion of plant material into a suitable form of energy, usually electricity or as a fuel for an internal combustion engine, can be achieved using a number of different routes, each with specific pros and cons. Currently, much research has been focused on sustainable and environmental friendly energy from biomass to replace conventional fossil fuels. The main objective of the present study is to investigate global potential and use of biomass energy and its contribution to the sustainable energy development by presenting its historical development.

  1. Renewable energy development strategy and market potential in China

    International Nuclear Information System (INIS)

    Liu Hongpeng

    2000-01-01

    Renewable energy development in China is at a critical crossroads. With large increases in energy demand a certainty over the long term, development of large-scale renewable energy supply is strategically important for local, regional and global environmental sustainability. Chinese government has paid great attention to renewable energy development and formulated a series policy to promote renewable energy utilization. This paper will provide an overview of China's efforts to adopt and implement a more market-oriented renewable energy development strategy. Furthermore, along with its economic growth and sustainable development, China's development program for promising renewable energy technologies, and specific priority areas create opportunities for investment and cooperation. This paper will also explain the present situation of ongoing market penetration projects and analyse the market potential of renewable energy technologies in the future. (author)

  2. Singlet Exciton Lifetimes in Conjugated Polymer Films for Organic Solar Cells

    KAUST Repository

    Dimitrov, Stoichko

    2016-01-13

    The lifetime of singlet excitons in conjugated polymer films is a key factor taken into account during organic solar cell device optimization. It determines the singlet exciton diffusion lengths in polymer films and has a direct impact on the photocurrent generation by organic solar cell devices. However, very little is known about the material properties controlling the lifetimes of singlet excitons, with most of our knowledge originating from studies of small organic molecules. Herein, we provide a brief summary of the nature of the excited states in conjugated polymer films and then present an analysis of the singlet exciton lifetimes of 16 semiconducting polymers. The exciton lifetimes of seven of the studied polymers were measured using ultrafast transient absorption spectroscopy and compared to the lifetimes of seven of the most common photoactive polymers found in the literature. A plot of the logarithm of the rate of exciton decay vs. the polymer optical bandgap reveals a medium correlation between lifetime and bandgap, thus suggesting that the Energy Gap Law may be valid for these systems. This therefore suggests that small bandgap polymers can suffer from short exciton lifetimes, which may limit their performance in organic solar cell devices. In addition, the impact of film crystallinity on the exciton lifetime was assessed for a small bandgap diketopyrrolopyrrole co-polymer. It is observed that the increase of polymer film crystallinity leads to reduction in exciton lifetime and optical bandgap again in agreement with the Energy Gap Law.

  3. Potential environmental effects of the leading edge hydrokinetic energy technology.

    Science.gov (United States)

    2017-05-01

    The Volpe Center evaluated potential environmental challenges and benefits of the ARPA-E funded research project, Marine Hydrokinetic Energy Harvesting Using Cyber-Physical Systems, led by Brown University. The Leading Edge research team develo...

  4. Ab initio Potential Energy Surface for H-H2

    Science.gov (United States)

    Partridge, Harry; Bauschlicher, Charles W., Jr.; Stallcop, James R.; Levin, Eugene

    1993-01-01

    Ab initio calculations employing large basis sets are performed to determine an accurate potential energy surface for H-H2 interactions for a broad range of separation distances. At large distances, the spherically averaged potential determined from the calculated energies agrees well with the corresponding results determined from dispersion coefficients; the van der Waals well depth is predicted to be 75 +/- (mu)E(sub h). Large basis sets have also been applied to reexamine the accuracy of theoretical repulsive potential energy surfaces. Multipolar expansions of the computed H-H2 potential energy surface are reported for four internuclear separation distances (1.2, 1.401, 1.449, and 1.7a(sub 0) of the hydrogen molecule. The differential elastic scattering cross section calculated from the present results is compared with the measurements from a crossed beam experiment.

  5. Representing Global Reactive Potential Energy Surfaces Using Gaussian Processes.

    Science.gov (United States)

    Kolb, Brian; Marshall, Paul; Zhao, Bin; Jiang, Bin; Guo, Hua

    2017-04-06

    Representation of multidimensional global potential energy surfaces suitable for spectral and dynamical calculations from high-level ab initio calculations remains a challenge. Here, we present a detailed study on constructing potential energy surfaces using a machine learning method, namely, Gaussian process regression. Tests for the 3 A″ state of SH 2 , which facilitates the SH + H ↔ S( 3 P) + H 2 abstraction reaction and the SH + H' ↔ SH' + H exchange reaction, suggest that the Gaussian process is capable of providing a reasonable potential energy surface with a small number (∼1 × 10 2 ) of ab initio points, but it needs substantially more points (∼1 × 10 3 ) to converge reaction probabilities. The implications of these observations for construction of potential energy surfaces are discussed.

  6. Potential energy curves for neutral and multiply charged carbon ...

    Indian Academy of Sciences (India)

    Abstract. Potential energy curves of various electronic states of CO+ (0 ≤ ≤ 6) are generated at MRCI/CASSCF level using cc-pvQZ basis set and the results are compared with available experimental and theoretical data.

  7. Ab initio adiabatic and quasidiabatic potential energy surfaces of H ...

    Indian Academy of Sciences (India)

    s12039-015-1022-8. Ab initio adiabatic and quasidiabatic potential energy surfaces of H. ++. CN system. BHARGAVA ANUSURI and SANJAY KUMAR. ∗. Department of Chemistry, Indian Institute of Technology Madras, Chennai 600 036, India.

  8. Ab initio potential energy and dipole moment surfaces for CS2: determination of molecular vibrational energies.

    Science.gov (United States)

    Pradhan, Ekadashi; Carreón-Macedo, José-Luis; Cuervo, Javier E; Schröder, Markus; Brown, Alex

    2013-08-15

    The ground state potential energy and dipole moment surfaces for CS2 have been determined at the CASPT2/C:cc-pVTZ,S:aug-cc-pV(T+d)Z level of theory. The potential energy surface has been fit to a sum-of-products form using the neural network method with exponential neurons. A generic interface between neural network potential energy surface fitting and the Heidelberg MCTDH software package is demonstrated. The potential energy surface has also been fit using the potfit procedure in MCTDH. For fits to the low-energy regions of the potential, the neural network method requires fewer parameters than potfit to achieve high accuracy; global fits are comparable between the two methods. Using these potential energy surfaces, the vibrational energies have been computed for the four most abundant CS2 isotopomers. These results are compared to experimental and previous theoretical data. The current potential energy surfaces are shown to accurately reproduce the low-lying vibrational energies within a few wavenumbers. Hence, the potential energy and dipole moments surfaces will be useful for future study on the control of quantum dynamics in CS2.

  9. The development of efficient two-photon singlet oxygen sensitizers

    DEFF Research Database (Denmark)

    Nielsen, Christian Benedikt

    the singlet oxygen yield and the two-photon absorption cross section, where it was revealed that a careful balancing of the amount of charge transfer present in theexcited state of the sensitizer is necessary to obtain both a high singlet oxygen quantum yield and a high two-photon cross section. An increasing...... amount of charge-transfer is beneficial for high two-photon absorption cross sections but iscounter-productive for singlet oxygen generation. The design principles obtained from the studies in lipophilic solvents were applied to synthesize water-soluble twophoton singlet oxygen sensitizers......The development of efficient two-photon singlet oxygen sensitizers is addressed focusing on organic synthesis. Photophysical measurements were carried out on new lipophilic molecules, where two-photon absorption cross sections and singlet oxygen quantumyields were measured. Design principles...

  10. Fermi energy anomaly in the nucleon-nucleus potential

    International Nuclear Information System (INIS)

    Finlay, R.W.

    1988-01-01

    Careful comparisons of the parameters of the nucleon-nucleus optical potential at energy (E 20 MeV) have revealed discrepancies. Commonly used ''global optical models'' tend to fail in one energy region or the other. Improved agreement with the data can be restored in phenomenological models in which certain geometrical parameters of the model are allowed to depend explicitly on neutron energy. The origin of this effect in the n+ 208 Pb system has been explained in terms of the dispersion correction to the real part of the standard local optical potential. In dispersion theory, the magnitude of this correction is obtained from the energy dependence of the phenomenological imaginary potential. The phenomenological parameters for n and p on 208 Pb are re-examined. The dispersion theory explanation of the low energy behaviour of the neutron potential is supported by the present analysis, but no similar analyses suggest that the Fermi energy anomaly for the p+ 208 Pb potential is located at energies well below the Coulomb barrier

  11. Energy Generation Potential of West African Ocean Current ...

    African Journals Online (AJOL)

    A review of the West African ocean current energy generating potential is carried out. The peculiarity of the West African ocean characteristic is discussed and the challenges noted. Based on this review, it is found that ocean current represents an alternative source of renewable energy in West Africa in a streamed regular ...

  12. 7Li breakup polarization potential at near barrier energies

    International Nuclear Information System (INIS)

    Lubian, J. . E-mail lubian@if.uff.br; Correa, T.; Paes, B.; Figueira, J.M.; Abriola, D.; Fernandez Niello, J.O.; Arazi, A.; Capurro, O.A.; de Barbara, E.; Marti, G.V.; Martinez Heinmann, D.; Negri, A.E.; Pacheco, A.J.; Padron, I.; Gomes, P.R.S.

    2007-01-01

    Inelastic and one neutron transfer cross sections at energies around the Coulomb barrier were used to derive dynamic polarization potential (DPP) for the 7 Li + 27 Al system. The DPP due to breakup, obtained in a simple way, indicates that its real part is repulsive at near barrier energies

  13. Li breakup polarization potential at near barrier energies

    International Nuclear Information System (INIS)

    Lubian, F. J.; Correa, T.; Gomes, P.R.S.; Paes, B; Figueira, J. M.; Abriola, D.; Fernandez, J. O.; Capurro, O. A.; Marti, G.V.; Martinez, D.; Heimann; Negri, A.; Pacheco, A. J.; Padron, I.

    2007-01-01

    Inelastic and one neutron transfer cross sections at energies around the Coulomb barrier were used to derive dynamic polarization potential (DPP) for the 7 Li + 27 Al system. The DPP due to breakup, obtained in a simple way, indicates that its real part is repulsive at nearbarrier energies. (Author)

  14. Energy use reduction potential of passenger transport in Europe

    NARCIS (Netherlands)

    Bouwman, ME; Moll, HC

    2000-01-01

    To contribute to a sustainable society, considerable reduction in energy use and CO2 emissions should be achieved. This paper presents the results of calculations exploring the energy use reduction potential of passenger transport for Western Europe (OECD Europe minus Turkey). For these

  15. Geospatial Analysis of Renewable Energy Technical Potential on Tribal Lands

    Energy Technology Data Exchange (ETDEWEB)

    Doris, E.; Lopez, A.; Beckley, D.

    2013-02-01

    This technical report uses an established geospatial methodology to estimate the technical potential for renewable energy on tribal lands for the purpose of allowing Tribes to prioritize the development of renewable energy resources either for community scale on-tribal land use or for revenue generating electricity sales.

  16. Voltage-sensitive styryl dyes as singlet oxygen targets on the surface of bilayer lipid membrane.

    Science.gov (United States)

    Sokolov, V S; Gavrilchik, A N; Kulagina, A O; Meshkov, I N; Pohl, P; Gorbunova, Yu G

    2016-08-01

    Photosensitizers are widely used as photodynamic therapeutic agents killing cancer cells by photooxidation of their components. Development of new effective photosensitive molecules requires profound knowledge of possible targets for reactive oxygen species, especially for its singlet form. Here we studied photooxidation of voltage-sensitive styryl dyes (di-4-ANEPPS, di-8-ANEPPS, RH-421 and RH-237) by singlet oxygen on the surface of bilayer lipid membranes commonly used as cell membrane models. Oxidation was induced by irradiation of a photosensitizer (aluminum phthalocyanine tetrasulfonate) and monitored by the change of dipole potential on the surface of the membrane. We studied the drop of the dipole potential both in the case when the dye molecules were adsorbed on the same side of the lipid bilayer as the photosensitizer (cis-configuration) and in the case when they were adsorbed on the opposite side (trans-configuration). Based on a simple model, we determined the rate of oxidation of the dyes from the kinetics of change of the potential during and after irradiation. This rate is proportional to steady-state concentration of singlet oxygen in the membrane under irradiation. Comparison of the oxidation rates of various dyes reveals that compounds of ANEPPS series are more sensitive to singlet oxygen than RH type dyes, indicating that naphthalene group is primarily responsible for their oxidation. Copyright © 2016 Elsevier B.V. All rights reserved.

  17. Analyses of relativistic optical potential for medium energy proton

    International Nuclear Information System (INIS)

    Feng Dachun; Liu Wenqin; Ma Zhongyu

    1993-01-01

    The influence of the parameters of the relativistic optical potential on the nucleon scattering properties, such as cross sections, angular distributions and spin observables etc., is studied based on a set of global Dirac phenomenological optical potentials. It is show that, in contrast with the case at low energies, the total scattering cross sections vary slowly as the energy and weakly depend on the potentials at E p <200 MeV. The differential cross sections and spin observables depend not only on the volume integrals of the optical potentials, but also on their strengths and shapes. The applicability of the relativistic microscopic optical potential based on Walecka model in the medium energy region is also discussed

  18. Energy independent optical potential and inverse scattering from non-local potential

    International Nuclear Information System (INIS)

    Tam, K.C.

    1982-01-01

    An energy-independent optical potential for nucleon-nucleus scattering is formally derived. A simple relation between energy-dependent and energy-independent potentials is established, showing that the latter has the same thresholds as the former. A generalized dispersion relation for energy-independent potentials is found and compared with the conventional dispersion relations of the generalized energy-dependent optical potentials. An inverse scattering method for non-local potential is developed to obtain this energy-independent optical potential anti U. Unlike the case of local potential, in addition to the bound-state information, the knowledge of the off-shell effect in the continuum is required for a unique construction of this non-local potential. A numerical method, known as the interpolation method, is proposed for the calculation of anti U. It is shown that a unique construction of anti U can be attained with the elastic scattering wave function and all bound-state energies and functions. Another method, known as the perturbative method, is also proposed and applied to calculations of anti U for elastic (n, 40 Ca) scatterings from empirical energy-dependent optical model potentials U(E) of the Woods-Saxon type. The perturbative method is found to converge satisfactorily when the energy dependence of the underlying U(e) potential is weak, as in the case of the empirical optical model potentials. The anti U from both the inverse scattering method and the perturbative one has the same elastic scattering wave function as for U(E)

  19. Strong Electroweak Phase Transitions in the Standard Model with a Singlet

    CERN Document Server

    Espinosa, Jose R; Riva, Francesco

    2012-01-01

    It is well known that the electroweak phase transition (EWPhT) in extensions of the Standard Model with one real scalar singlet can be first-order for realistic values of the Higgs mass. We revisit this scenario with the most general renormalizable scalar potential systematically identifying all regions in parameter space that develop, due to tree-level dynamics, a potential barrier at the critical temperature that is strong enough to avoid sphaleron wash-out of the baryon asymmetry. Such strong EWPhTs allow for a simple mean-field approximation and an analytic treatment of the free-energy that leads to very good theoretical control and understanding of the different mechanisms that can make the transition strong. We identify a new realization of such mechanism, based on a flat direction developing at the critical temperature, which could operate in other models. Finally, we discuss in detail some special cases of the model performing a numerical calculation of the one-loop free-energy that improves over the ...

  20. Scenarios of energy demand and efficiency potential for Bulgaria

    Energy Technology Data Exchange (ETDEWEB)

    Tzvetanov, P.; Ruicheva, M.; Denisiev, M.

    1996-12-31

    The paper presents aggregated results on macroeconomic and final energy demand scenarios developed within the Bulgarian Country Study on Greenhouse Gas Emissions Mitigation, supported by US Country Studies Program. The studies in this area cover 5 main stages: (1) {open_quotes}Baseline{close_quotes} and {open_quotes}Energy Efficiency{close_quotes} socioeconomic and energy policy philosophy; (2) Modeling of macroeconomic and sectoral development till 2020; (3) Expert assessments on the technological options for energy efficiency increase and GHG mitigation in the Production, Transport and Households and Services Sectors; (4) Bottom-up modeling of final energy demand; and (5) Sectoral and overall energy efficiency potential and policy. Within the Bulgarian Country Study, the presented results have served as a basis for the final integration stage {open_quotes}Assessment of the Mitigation Policy and Measures in the Energy System of Bulgaria{close_quotes}.

  1. Savings potential of ENERGY STAR (registered trademark) voluntary labeling programs

    International Nuclear Information System (INIS)

    Webber, Carrie A.; Brown, Richard E.

    1998-01-01

    In 1993 the U.S. Environmental Protection Agency (EPA) introduced ENERGY STAR (registered trademark), a voluntary labeling program designed to identify and promote energy-efficient products. Since then EPA, now in partnership with the U.S. Department of Energy (DOE), has introduced programs for more than twenty products, spanning office equipment, residential heating and cooling equipment, new homes, commercial and residential lighting, home electronics, and major appliances. We present potential energy, dollar and carbon savings forecasts for these programs for the period 1998 to 2010. Our target market penetration case represents our best estimate of future ENERGY STAR savings. It is based on realistic market penetration goals for each of the products. We also provide results under the assumption of 100% market penetration; that is, we assume that all purchasers buy ENERGY STAR-compliant products instead of standard efficiency products throughout the analysis period. Finally, we assess the sensitivity of our target penetration case forecasts to greater or lesser marketing success by EPA and DOE, lower-than-expected future energy prices, and higher or lower rates of carbon emission by electricity generators. The potential savings of ENERGY STAR are substantial. If all purchasers chose Energy Star-compliant products instead of standard efficiency products over the next 15 years, they would save more than$100 billion on their energy bills during those 15 years. (Bill savings are in 1995 dollars, discounted at a 4% real discount rate.)

  2. High Triplet Yield from Singlet Fission in a Thin Film of 1,3-Diphenylisobenzofuran

    Czech Academy of Sciences Publication Activity Database

    Johnson, J. C.; Nozik, A. J.; Michl, Josef

    2010-01-01

    Roč. 132, č. 46 (2010), s. 16302-16303 ISSN 0002-7863 Grant - others:Department of Energy(US) XAT-5-33636-01; Department of Energy(US) DE- FG36 -08GO18017 Institutional research plan: CEZ:AV0Z40550506 Keywords : singlet fission * thin solid films * heterocycles Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 9.019, year: 2010

  3. Metallic bionanocatalysts: potential applications as green catalysts and energy materials.

    Science.gov (United States)

    Macaskie, Lynne E; Mikheenko, Iryna P; Omajai, Jacob B; Stephen, Alan J; Wood, Joseph

    2017-09-01

    Microbially generated or supported nanocatalysts have potential applications in green chemistry and environmental application. However, precious (and base) metals biorefined from wastes may be useful for making cheap, low-grade catalysts for clean energy production. The concept of bionanomaterials for energy applications is reviewed with respect to potential fuel cell applications, bio-catalytic upgrading of oils and manufacturing 'drop-in fuel' precursors. Cheap, effective biomaterials would facilitate progress towards dual development goals of sustainable consumption and production patterns and help to ensure access to affordable, reliable, sustainable and modern energy. © 2017 The Authors. Microbial Biotechnology published by John Wiley & Sons Ltd and Society for Applied Microbiology.

  4. Potential reduction of energy consumption in public university library

    Science.gov (United States)

    Noranai, Z.; Azman, ADF

    2017-09-01

    Efficient electrical energy usage has been recognized as one of the important factor to reduce cost of electrical energy consumption. Various parties have been emphasized about the importance of using electrical energy efficiently. Inefficient usage of electrical energy usage lead to biggest factor increasing of administration cost in Universiti Tun Hussein Onn Malaysia. With this in view, a project the investigate potential reduction electrical energy consumption in Universiti Tun Hussein Onn Malaysia was carried out. In this project, a case study involving electrical energy consumption of Perpustakaan Tunku Tun Aminah was conducted. The scopes of this project are to identify energy consumption in selected building and to find the factors that contributing to wastage of electrical energy. The MS1525:2001, Malaysian Standard - Code of practice on energy efficiency and use of renewable energy for non-residential buildings was used as reference. From the result, 4 saving measure had been proposed which is change type of the lamp, install sensor, decrease the number of lamp and improve shading coefficient on glass. This saving measure is suggested to improve the efficiency of electrical energy consumption. Improve of human behaviour toward saving energy measure can reduce 10% from the total of saving cost while on building technical measure can reduce 90% from total saving cost.

  5. Investigating Energy-Saving Potentials in the Cloud

    Science.gov (United States)

    Lee, Da-Sheng

    2014-01-01

    Collecting webpage messages can serve as a sensor for investigating the energy-saving potential of buildings. Focusing on stores, a cloud sensor system is developed to collect data and determine their energy-saving potential. The owner of a store under investigation must register online, report the store address, area, and the customer ID number on the electric meter. The cloud sensor system automatically surveys the energy usage records by connecting to the power company website and calculating the energy use index (EUI) of the store. Other data includes the chain store check, company capital, location price, and the influence of weather conditions on the store; even the exposure frequency of store under investigation may impact the energy usage collected online. After collecting data from numerous stores, a multi-dimensional data array is constructed to determine energy-saving potential by identifying stores with similarity conditions. Similarity conditions refer to analyzed results that indicate that two stores have similar capital, business scale, weather conditions, and exposure frequency on web. Calculating the EUI difference or pure technical efficiency of stores, the energy-saving potential is determined. In this study, a real case study is performed. An 8-dimensional (8D) data array is constructed by surveying web data related to 67 stores. Then, this study investigated the savings potential of the 33 stores, using a site visit, and employed the cloud sensor system to determine the saving potential. The case study results show good agreement between the data obtained by the site visit and the cloud investigation, with errors within 4.17%. Among 33 the samples, eight stores have low saving potentials of less than 5%. The developed sensor on the cloud successfully identifies them as having low saving potential and avoids wasting money on the site visit. PMID:24561405

  6. Investigating energy-saving potentials in the cloud.

    Science.gov (United States)

    Lee, Da-Sheng

    2014-02-20

    Collecting webpage messages can serve as a sensor for investigating the energy-saving potential of buildings. Focusing on stores, a cloud sensor system is developed to collect data and determine their energy-saving potential. The owner of a store under investigation must register online, report the store address, area, and the customer ID number on the electric meter. The cloud sensor system automatically surveys the energy usage records by connecting to the power company website and calculating the energy use index (EUI) of the store. Other data includes the chain store check, company capital, location price, and the influence of weather conditions on the store; even the exposure frequency of store under investigation may impact the energy usage collected online. After collecting data from numerous stores, a multi-dimensional data array is constructed to determine energy-saving potential by identifying stores with similarity conditions. Similarity conditions refer to analyzed results that indicate that two stores have similar capital, business scale, weather conditions, and exposure frequency on web. Calculating the EUI difference or pure technical efficiency of stores, the energy-saving potential is determined. In this study, a real case study is performed. An 8-dimensional (8D) data array is constructed by surveying web data related to 67 stores. Then, this study investigated the savings potential of the 33 stores, using a site visit, and employed the cloud sensor system to determine the saving potential. The case study results show good agreement between the data obtained by the site visit and the cloud investigation, with errors within 4.17%. Among 33 the samples, eight stores have low saving potentials of less than 5%. The developed sensor on the cloud successfully identifies them as having low saving potential and avoids wasting money on the site visit.

  7. Study of the potential of wave energy in Malaysia

    Science.gov (United States)

    Tan, Wan Ching; Chan, Keng Wai; Ooi, Heivin

    2017-07-01

    Renewable energy is generally defined as energy harnessed from resources which are naturally replenished. It is an alternative to the current conventional energy sources such as natural gas, oil and coal, which are nonrenewable. Besides being nonrenewable, the harnessing of these resources generally produce by-products which could be potentially harmful to the environment. On the contrary, the generation from renewable energy does not pose environmental degradation. Some examples of renewable energy sources are sunlight, wind, tides, waves and geothermal heat. Wave energy is considered as one of the most promising marine renewable resources and is becoming commercially viable quicker than other renewable technologies at an astonishing growth rate. This paper illustrates the working principle of wave energy converter (WEC) and the availability of wave energy in Malaysia oceans. A good understanding of the behaviour of ocean waves is important for designing an efficient WEC as the characteristics of the waves in shallow and deep water are different. Consequently, wave energy converters are categorized into three categories on shore, near shore and offshore. Therefore, the objectives of this study is ought to be carried out by focusing on the formation of waves and wave characteristics in shallow as well as in deep water. The potential sites for implementation of wave energy harvesting technology in Malaysia and the wave energy available in the respective area were analysed. The potential of wave energy in Malaysia were tabulated and presented with theoretical data. The interaction between motion of waves and heave buoys for optimum phase condition by using the mass and diameter as the variables were investigated.

  8. Morphing ab initio potential energy curve of beryllium monohydride

    Czech Academy of Sciences Publication Activity Database

    Špirko, Vladimír

    2016-01-01

    Roč. 330, Dec (2016), s. 89-95 ISSN 0022-2852 Institutional support: RVO:61388963 Keywords : beryllium monohydride * potential energy function * reduced potential * homotopic morphing Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 1.618, year: 2016

  9. Analytical potential energy function for the Br + H2 system

    International Nuclear Information System (INIS)

    Kurosaki, Yuzuru

    2001-01-01

    Analytical functions with a many-body expansion for the ground and first-excited-state potential energy surfaces for the Br+H 2 system are newly presented in this work. These functions describe the abstraction and exchange reactions qualitatively well, although it has been found that the function for the ground-state potential surface is still quantitatively unsatisfactory. (author)

  10. Potential geothermal energy applications for Idaho Elks Rehabilitation Hospital

    Energy Technology Data Exchange (ETDEWEB)

    Austin, J.C.

    1981-11-01

    Several potential applications of geothermal energy for the Idaho Elks Rehabilitation Hospital are outlined. A brief background on the resource and distribution system, is provided; which hospital heating systems should be considered for potential geothermal retrofit is discussed; and technical and economic feasibility are addressed.

  11. Calculation of molecular free energies in classical potentials

    International Nuclear Information System (INIS)

    Farhi, Asaf; Singh, Bipin

    2016-01-01

    Free energies of molecules can be calculated by quantum chemistry computations or by normal mode classical calculations. However, the first can be computationally impractical for large molecules and the second is based on the assumption of harmonic dynamics. We present a novel, accurate and complete calculation of molecular free energies in standard classical potentials. In this method we transform the molecule by relaxing potential terms which depend on the coordinates of a group of atoms in that molecule and calculate the free energy difference associated with the transformation. Then, since the transformed molecule can be treated as non-interacting systems, the free energy associated with these atoms is analytically or numerically calculated. This two-step calculation can be applied to calculate free energies of molecules or free energy difference between (possibly large) molecules in a general environment. We demonstrate the method in free energy calculations for methanethiol and butane molecules in vacuum and solvent. We suggest the potential application of free energy calculation of chemical reactions in classical molecular simulations. (paper)

  12. Exploring the potential of wind energy for a coastal state

    International Nuclear Information System (INIS)

    Yue, C.-D.; Yang, M.-H.

    2009-01-01

    Adequate recognition of the wind energy potential of coastal states may have far-reaching effects on the development of the energy systems of these countries. This study evaluates wind energy resources in Taiwan with the aid of a geographic information system (GIS), which allows local potentials and restrictions such as climate conditions, land uses, and ecological environments to be considered. The findings unveiled in this study suggest a significant role for offshore wind energy resources, which may constitute between 94% and 98% of overall wind resources in Taiwan. Total power yield from wind energy could reach between 150 and 165 TWh, which would have, respectively, accounted for between 62% and 68% of Taiwan's total power generation of 243 TWh in 2007. Based on the Taiwan's current emission factor of electricity, wind energy has the potential to reduce CO 2 emissions by between 94 and 102 million ton per year in Taiwan, which is, respectively, equivalent to 28% and 31% of the national net equivalent CO 2 emissions released in 2002. However, the challenge of managing the variability of wind power has to be addressed before the considerable contribution of wind energy to domestic energy supply and CO 2 reduction can be realized.

  13. Potentials of interaction between medium energy particles and nuclei

    International Nuclear Information System (INIS)

    Berezhnoj, Yu.A.; Molev, A.S.

    1986-01-01

    The potential of interaction between mean-energy particles and atomic nuclei is determined as a solution of an integral equation relating it to the scattering matrix. Potentials involving the central and spin-orbital or isospin parts are reconstructed on the basis of the scattering matrix of the diffraction model. Approximated expressions for central and spin-orbital potentials in the case of weak refraction are obtained. The effect of nuclear parameters on the shape of central potential of interaction between 156 MeV protons and the 208 Pb nuclei is considered. The calculated and phenomenological central and spin-orbital potentials of interaction between 185 MeV protons and the 90 Zr, 208 Pb nuclei are in good agreement only in the surface region of nuclei. The central and isospin potentials of interaction between the 3 He nuclei with 217 MeV energy and the 9 Be nuclei are studied

  14. Photocurrent enhanced by singlet fission in a dye-sensitized solar cell.

    Science.gov (United States)

    Schrauben, Joel N; Zhao, Yixin; Mercado, Candy; Dron, Paul I; Ryerson, Joseph L; Michl, Josef; Zhu, Kai; Johnson, Justin C

    2015-02-04

    Investigations of singlet fission have accelerated recently because of its potential utility in solar photoconversion, although only a few reports definitively identify the role of singlet fission in a complete solar cell. Evidence of the influence of singlet fission in a dye-sensitized solar cell using 1,3-diphenylisobenzofuran (DPIBF, 1) as the sensitizer is reported here. Self-assembly of the blue-absorbing 1 with co-adsorbed oxidation products on mesoporous TiO2 yields a cell with a peak internal quantum efficiency of ∼70% and a power conversion efficiency of ∼1.1%. Introducing a ZrO2 spacer layer of thickness varying from 2 to 20 Å modulates the short-circuit photocurrent such that it is initially reduced as thickness increases but 1 with 10-15 Å of added ZrO2. This rise can be explained as being due to a reduced rate of injection of electrons from the S1 state of 1 such that singlet fission, known to occur with a 30 ps time constant in polycrystalline films, has the opportunity to proceed efficiently and produce two T1 states per absorbed photon that can subsequently inject electrons into TiO2. Transient spectroscopy and kinetic simulations confirm this novel mode of dye-sensitized solar cell operation and its potential utility for enhanced solar photoconversion.

  15. Synergy potential for oil and geothermal energy exploitation

    DEFF Research Database (Denmark)

    Ziabakhsh-Ganji, Zaman; Nick, Hamidreza M.; Donselaar, Marinus E.

    2018-01-01

    and feasibility analyses of the synergy potential of thermally-enhanced oil recovery and geothermal energy production are performed. A series of simulations are carried out to examine the effects of reservoir properties on energy consumption and oil recovery for different injection rates and injection temperature......A new solution for harvesting energy simultaneously from two different sources of energy by combining geothermal energy production and thermal enhanced heavy oil recovery is introduced. Numerical simulations are employed to evaluate the feasibility of generating energy from geothermal resources......, both for thermally enhanced oil recovery from a heavy oil reservoir and for direct heating purposes. A single phase non-isothermal fluid flow modeling for geothermal doublet system and a two-phase non-isothermal fluid flow modelling for water flooding in an oil reservoir are utilised. Sensitivity...

  16. Synergy potential for oil and geothermal energy exploitation

    DEFF Research Database (Denmark)

    Ziabakhsh-Ganji, Zaman; Nick, Hamidreza M.; Donselaar, Marinus E.

    2018-01-01

    A new solution for harvesting energy simultaneously from two different sources of energy by combining geothermal energy production and thermal enhanced heavy oil recovery is introduced. Numerical simulations are employed to evaluate the feasibility of generating energy from geothermal resources......, both for thermally enhanced oil recovery from a heavy oil reservoir and for direct heating purposes. A single phase non-isothermal fluid flow modeling for geothermal doublet system and a two-phase non-isothermal fluid flow modelling for water flooding in an oil reservoir are utilised. Sensitivity...... and feasibility analyses of the synergy potential of thermally-enhanced oil recovery and geothermal energy production are performed. A series of simulations are carried out to examine the effects of reservoir properties on energy consumption and oil recovery for different injection rates and injection temperature...

  17. Energy Planning in Selected European Regions - Methods for Evaluating the Potential of Renewable Energy Sources

    OpenAIRE

    Sliz-Szkliniarz, Beata

    2013-01-01

    Given their potentially positive impact on climate protection and the preservation of fossil resources, alternative energy sources have become increasingly important for the energy supply over the past years. However, the questions arises what economic and ecological impacts and potential conflicts over land use resources are associated with the promotion of renewable energy production. Using the examples of three selected European Regions in Poland, France and German, the dissertation discus...

  18. Warm Body Temperature Facilitates Energy Efficient Cortical Action Potentials

    Science.gov (United States)

    Yu, Yuguo; Hill, Adam P.; McCormick, David A.

    2012-01-01

    The energy efficiency of neural signal transmission is important not only as a limiting factor in brain architecture, but it also influences the interpretation of functional brain imaging signals. Action potential generation in mammalian, versus invertebrate, axons is remarkably energy efficient. Here we demonstrate that this increase in energy efficiency is due largely to a warmer body temperature. Increases in temperature result in an exponential increase in energy efficiency for single action potentials by increasing the rate of Na+ channel inactivation, resulting in a marked reduction in overlap of the inward Na+, and outward K+, currents and a shortening of action potential duration. This increase in single spike efficiency is, however, counterbalanced by a temperature-dependent decrease in the amplitude and duration of the spike afterhyperpolarization, resulting in a nonlinear increase in the spike firing rate, particularly at temperatures above approximately 35°C. Interestingly, the total energy cost, as measured by the multiplication of total Na+ entry per spike and average firing rate in response to a constant input, reaches a global minimum between 37–42°C. Our results indicate that increases in temperature result in an unexpected increase in energy efficiency, especially near normal body temperature, thus allowing the brain to utilize an energy efficient neural code. PMID:22511855

  19. Potential for natural evaporation as a reliable renewable energy resource.

    Science.gov (United States)

    Cavusoglu, Ahmet-Hamdi; Chen, Xi; Gentine, Pierre; Sahin, Ozgur

    2017-09-26

    About 50% of the solar energy absorbed at the Earth's surface drives evaporation, fueling the water cycle that affects various renewable energy resources, such as wind and hydropower. Recent advances demonstrate our nascent ability to convert evaporation energy into work, yet there is little understanding about the potential of this resource. Here we study the energy available from natural evaporation to predict the potential of this ubiquitous resource. We find that natural evaporation from open water surfaces could provide power densities comparable to current wind and solar technologies while cutting evaporative water losses by nearly half. We estimate up to 325 GW of power is potentially available in the United States. Strikingly, water's large heat capacity is sufficient to control power output by storing excess energy when demand is low, thus reducing intermittency and improving reliability. Our findings motivate the improvement of materials and devices that convert energy from evaporation.The evaporation of water represents an alternative source of renewable energy. Building on previous models of evaporation, Cavusoglu et al. show that the power available from this natural resource is comparable to wind and solar power, yet it does not suffer as much from varying weather conditions.

  20. Split kinetic energy method for quantum systems with competing potentials

    International Nuclear Information System (INIS)

    Mineo, H.; Chao, Sheng D.

    2012-01-01

    For quantum systems with competing potentials, the conventional perturbation theory often yields an asymptotic series and the subsequent numerical outcome becomes uncertain. To tackle such a kind of problems, we develop a general solution scheme based on a new energy dissection idea. Instead of dividing the potential energy into “unperturbed” and “perturbed” terms, a partition of the kinetic energy is performed. By distributing the kinetic energy term in part into each individual potential, the Hamiltonian can be expressed as the sum of the subsystem Hamiltonians with respective competing potentials. The total wavefunction is expanded by using a linear combination of the basis sets of respective subsystem Hamiltonians. We first illustrate the solution procedure using a simple system consisting of a particle under the action of double δ-function potentials. Next, this method is applied to the prototype systems of a charged harmonic oscillator in strong magnetic field and the hydrogen molecule ion. Compared with the usual perturbation approach, this new scheme converges much faster to the exact solutions for both eigenvalues and eigenfunctions. When properly extended, this new solution scheme can be very useful for dealing with strongly coupling quantum systems. - Highlights: ► A new basis set expansion method is proposed. ► Split kinetic energy method is proposed to solve quantum eigenvalue problems. ► Significant improvement has been obtained in converging to exact results. ► Extension of such methods is promising and discussed.

  1. External quantum efficiency exceeding 100% in a singlet-exciton-fission-based solar cell

    Science.gov (United States)

    Baldo, Marc

    2013-03-01

    Singlet exciton fission can be used to split a molecular excited state in two. In solar cells, it promises to double the photocurrent from high energy photons, thereby breaking the single junction efficiency limit. We demonstrate organic solar cells that exploit singlet exciton fission in pentacene to generate more than one electron per incident photon in the visible spectrum. Using a fullerene acceptor, a poly(3-hexylthiophene) exciton confinement layer, and a conventional optical trapping scheme, the peak external quantum efficiency is (109 +/-1)% at λ = 670 nm for a 15-nm-thick pentacene film. The corresponding internal quantum efficiency is (160 +/-10)%. Independent confirmation of the high internal efficiency is obtained by analysis of the magnetic field effect on photocurrent, which determines that the triplet yield approaches 200% for pentacene films thicker than 5 nm. To our knowledge, this is the first solar cell to generate quantum efficiencies above 100% in the visible spectrum. Alternative multiple exciton generation approaches have been demonstrated previously in the ultraviolet, where there is relatively little sunlight. Singlet exciton fission differs from these other mechanisms because spin conservation disallows the usual dominant loss process: a thermal relaxation of the high-energy exciton into a single low-energy exciton. Consequently, pentacene is efficient in the visible spectrum at λ = 670 nm because only the collapse of the singlet exciton into twotriplets is spin-allowed. Supported as part of the Center for Excitonics, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under Award Number DE-SC0001088.

  2. Saturation wind power potential and its implications for wind energy.

    Science.gov (United States)

    Jacobson, Mark Z; Archer, Cristina L

    2012-09-25

    Wind turbines convert kinetic to electrical energy, which returns to the atmosphere as heat to regenerate some potential and kinetic energy. As the number of wind turbines increases over large geographic regions, power extraction first increases linearly, but then converges to a saturation potential not identified previously from physical principles or turbine properties. These saturation potentials are >250 terawatts (TW) at 100 m globally, approximately 80 TW at 100 m over land plus coastal ocean outside Antarctica, and approximately 380 TW at 10 km in the jet streams. Thus, there is no fundamental barrier to obtaining half (approximately 5.75 TW) or several times the world's all-purpose power from wind in a 2030 clean-energy economy.

  3. Potential energy savings by using direct current for residential applications

    DEFF Research Database (Denmark)

    Diaz, Enrique Rodriguez; Quintero, Juan Carlos Vasquez; Guerrero, Josep M.

    2017-01-01

    This paper presents a study of the potential energy savings by implementing dc distribution systems for residential applications. In general, it is commonly accepted that the use of dc voltage improves the efficiency of the distribution, due to a decrease in the conduction losses and an efficiency...... improvement in the power converter units. However, for residential applications, the efficiency is not always improved. A grid connected residential microgrid, with renewable energy sources (RES), energy storage systems (ESS) and local loads, is presented in this work. The microgrid has been modelled...... loads. However, for isolated microgrids, the use of dc voltage has the potential to bring a significant efficiency improvement. Nevertheless the potential for cost reduction in all scenarios is very promising....

  4. Collisionless Plasma Modeling in an Arbitrary Potential Energy Distribution

    Science.gov (United States)

    Liemohn, M. W.; Khazanov, G. V.

    1997-01-01

    A new technique for calculating a collisionless plasma along a field line is presented. The primary feature of the new model is that it can handle an arbitrary (including nonmonotonic) potential energy distribution. This was one of the limiting constraints on the existing models in this class, and these constraints are generalized for an arbitrary potential energy composition. The formulation for relating current density to the field-aligned potential as well as formulas for density, temperature and energy flux calculations are presented for several distribution functions, ranging from a bi-Lorentzian with a loss cone to an isotropic Maxwellian. A comparison of these results with previous models shows that the formulation reduces.to the earlier models under similar assumptions.

  5. Potential benefits of selling by auction the CIP 6 energy

    International Nuclear Information System (INIS)

    Campidoglio, C.

    2000-01-01

    This paper analyses the potential benefits of selling by auction the CIP 6 energy. This would both reduce the supply shortage and the prices on the eligible market, increase competition on the contract-for-difference market, indicate a clear price to which regulated energy charges could be indexed, thus extending the auction benefits to the franchise market to avoid the reintroduction of cross-subsidies [it

  6. Potential structural material problems in a hydrogen energy system

    Science.gov (United States)

    Gray, H. R.; Nelson, H. G.; Johnson, R. E.; Mcpherson, W. B.; Howard, F. S.; Swisher, J. H.

    1976-01-01

    Potential structural material problems that may be encountered in the three components of a hydrogen energy system - production, transmission/storage, and utilization - have been identified. Hydrogen embrittlement, corrosion, oxidation, and erosion may occur during the production of hydrogen. Hydrogen embrittlement is of major concern during both transmission and utilization of hydrogen. Specific materials research and development programs necessary to support a hydrogen energy system are described. An awareness of probable shortages of strategic materials has been maintained in these suggested programs.

  7. Optical detection of singlet oxygen from single cells

    DEFF Research Database (Denmark)

    Snyder, John; Skovsen, Esben; Lambert, John D. C.

    2006-01-01

    The lowest excited electronic state of molecular oxygen, singlet molecular oxygen, O2(a 1g), is a reactive species involved in many chemical and biological processes. To better understand the roles played by singlet oxygen in biological systems, particularly at the sub-cellular level, optical tools...

  8. Mapping Thermal Energy Resource Potentials from Wastewater Treatment Plants

    Directory of Open Access Journals (Sweden)

    Georg Neugebauer

    2015-09-01

    Full Text Available Wastewater heat recovery via heat exchangers and heat pumps constitutes an environmentally friendly, approved and economically competitive, but often underestimated technology. By introducing the spatial dimension in feasibility studies, the results of calculations change considerably. This paper presents a methodology to estimate thermal energy resource potentials of wastewater treatment plants taking spatial contexts into account. In close proximity to settlement areas, wastewater energy can ideally be applied for heating in mixed-function areas, which very likely have a continuous heat demand and allow for an increased amount of full-load hours compared to most single-use areas. For the Austrian case, it is demonstrated that the proposed methodology leads to feasible results and that the suggested technology might reduce up to 17% of the Austrian global warming potential of room heating. The method is transferrable to other countries as the input data and calculation formula are made available. A broad application of wastewater energy with regard to spatial structures and spatial development potentials can lead to (1 increasing energy efficiency by using a maximum of waste heat and (2 a significant reduction of (fossil energy consumption which results in a considerable reduction of the global warming potential of the heat supply (GWP if electricity from renewables is used for the operation of heat pumps.

  9. Map of decentralised energy potential based on renewable energy sources in Croatia

    International Nuclear Information System (INIS)

    Schneider, D. R.; Ban, M.; Duic, N.; Bogdan, Z.

    2005-01-01

    Although the Republic of Croatia is almost completely electrified there are still regions where electricity network is not in place or network capacity is insufficient. These regions usually include areas of special state care (underdeveloped, war-affected or depopulated areas), islands, and mountainous areas. However, they often have good renewable energy potential. Decentralised energy generation based on renewable energy sources (wind power, hydropower, solar energy, biomass) has potential to ensure energy supply to users in remote and often isolated rural areas (off-grid applications). Such applications will primarily be related to tourism business in mountainous, rural and island/coastal regions. Also, agriculture, wood-processing and food-processing industries will potentially be interested in application of decentralised energy generation systems, most likely those using biomass as fuel (for example cogeneration facilities, connected on-grid).(author)

  10. Renewable, ethical? Assessing the energy justice potential of renewable electricity

    Directory of Open Access Journals (Sweden)

    Aparajita Banerjee

    2017-08-01

    Full Text Available Energy justice is increasingly being used as a framework to conceptualize the impacts of energy decision making in more holistic ways and to consider the social implications in terms of existing ethical values. Similarly, renewable energy technologies are increasingly being promoted for their environmental and social benefits. However, little work has been done to systematically examine the extent to which, in what ways and in what contexts, renewable energy technologies can contribute to achieving energy justice. This paper assesses the potential of renewable electricity technologies to address energy justice in various global contexts via a systematic review of existing studies analyzed in terms of the principles and dimensions of energy justice. Based on publications including peer reviewed academic literature, books, and in some cases reports by government or international organizations, we assess renewable electricity technologies in both grid integrated and off-grid use contexts. We conduct our investigation through the rubric of the affirmative and prohibitive principles of energy justice and in terms of its temporal, geographic, socio-political, economic, and technological dimensions. Renewable electricity technology development has and continue to have different impacts in different social contexts, and by considering the different impacts explicitly across global contexts, including differences between rural and urban contexts, this paper contributes to identifying and understanding how, in what ways, and in what particular conditions and circumstances renewable electricity technologies may correspond with or work to promote energy justice.

  11. He-, Ne-, and Ar-phosgene intermolecular potential energy surfaces

    DEFF Research Database (Denmark)

    Munteanu, Cristian R.; Henriksen, Christian; Felker, Peter M.

    2013-01-01

    Using the CCSD(T) model, we evaluated the intermolecular potential energy surfaces of the He-, Ne-, and Ar-phosgene complexes. We considered a representative number of intermolecular geometries for which we calculated the corresponding interaction energies with the augmented (He complex) and double......-phosgene surfaces were found to have absolute minima of -72.1, -140.4, and -326.6 cm -1 at distances between the rare-gas atom and the phosgene center of mass of 3.184, 3.254, and 3.516 Å, respectively. The potentials were further used in the evaluation of rovibrational states and the rotational constants...

  12. An adaptive interpolation scheme for molecular potential energy surfaces

    Science.gov (United States)

    Kowalewski, Markus; Larsson, Elisabeth; Heryudono, Alfa

    2016-08-01

    The calculation of potential energy surfaces for quantum dynamics can be a time consuming task—especially when a high level of theory for the electronic structure calculation is required. We propose an adaptive interpolation algorithm based on polyharmonic splines combined with a partition of unity approach. The adaptive node refinement allows to greatly reduce the number of sample points by employing a local error estimate. The algorithm and its scaling behavior are evaluated for a model function in 2, 3, and 4 dimensions. The developed algorithm allows for a more rapid and reliable interpolation of a potential energy surface within a given accuracy compared to the non-adaptive version.

  13. Defining The Energy Saving Potential of Architectural Design

    DEFF Research Database (Denmark)

    Naboni, Emanuele; Malcangi, Antonio; Zhang, Yi

    2015-01-01

    Designers, in response to codes or voluntary " green building " programs, are increasingly concerned with building energy demand reduction, but they are not fully aware of the energy saving potential of architectural design. According to literature, building form, construction and material choices...... million different buildings constitute the optimization search space, and the most energy efficient design solutions were explored for 8 different climate zones. The building designs are varied by shape, orientation, window to wall ratio, component and construction types, materials, and different occupant...... results from building energy simulations made with limited computational resources available at the time. The research presented in this paper uses a genetic algorithms based approach for the optimization of heating, cooling and lighting energy demands of different building designs. In total, over 25...

  14. Predicting the potential of energy from agricultural wastes in Malaysia

    International Nuclear Information System (INIS)

    Arifah Bahar; Ahmad Mahir Razali; Kamaruzzaman Sopian

    2000-01-01

    This paper presents the prediction of the potential of energy supply from agricultural wastes in Malaysia until the year 2005. The exponential smoothing method is used to predict the supply of energy from these resources. The prediction is based on four scenarios namely (a) business as usual, (b) increase in the plantation area by 1 % (c) increase in productivity by 1 % with no increase in plantation area and (d) decrease in plantation area of 1%. The agricultural wastes considered are from rubber, oil palm ,cocoa, paddy, coconut and pineapple resources. In Peninsular Malaysia, these resources include groundnut, sugar cane, and tapioca. Assuming an energy conversion of 30%, only three agricultural wastes can contribute as an energy supply i.e. oil palm, paddy and sugar cane wastes. The contribution of these resources to the demand of energy for Malaysia is 21% in the year 2000 and 17% in the year 2005. (Author)

  15. Biohydrogen production as a potential energy fuel in South Africa

    Directory of Open Access Journals (Sweden)

    P.T. Sekoai

    2015-06-01

    Full Text Available Biohydrogen production has captured increasing global attention due to it social, economic and environmental benefits. Over the past few years, energy demands have been growing significantly in South Africa due to rapid economic and population growth. The South African parastatal power supplier i.e. Electricity Supply Commission (ESKOM has been unable to meet the country’s escalating energy needs. As a result, there have been widespread and persistent power cuts throughout the country. This prompts an urgent need for exploration and implementation of clean and sustainable energy fuels like biohydrogen production in order to address this crisis. Therefore, this paper discusses the current global energy challenges in relation to South Africa’s problems. It then examines the feasibility of using biohydrogen production as a potential energy fuel in South Africa. Finally, it reviews the hydrogen-infrastructure development plans in the country.

  16. Study of heavy quarkonium with energy dependent potential

    International Nuclear Information System (INIS)

    Gupta, Pramila; Mehrotra, I

    2009-01-01

    It is well known that charmonium and bottonium states can be calculated by using a nonrelativistic Schrodinger equation. The basic reasons are: 1) the mass of charm and bottom quarks is much larger than QCD scale, which makes this system free of strong normalization effects and 2) the binding energy is small compared to the mass energy ψ and γ states in terms of nonrelativistic qq system governed by more or less phenomenological potentials. In the present work we have studied mass spectra of charmonium and bottonium using the following energy dependent model in the framework of nonrelativistic Schrodinger equation

  17. On the potential energy landscape of supercooled liquids and glasses

    DEFF Research Database (Denmark)

    Rodney, D.; Schrøder, Thomas

    2011-01-01

    The activation-relaxation technique (ART), a saddle-point search method, is applied to determine the potential energy landscape around supercooled and glassy configurations of a three-dimensional binary Lennard-Jones system. We show a strong relation between the distribution of activation energies...... of transitions undergone by the same supercooled liquid during a time trajectory simulated by molecular dynamics. We find that ART is biased towards more heterogeneous transitions with higher activation energies and more broken bonds than the MD simulation....

  18. Potentials and policy implications of energy and material efficiency improvement

    Energy Technology Data Exchange (ETDEWEB)

    Worrell, Ernst; Levine, Mark; Price, Lynn; Martin, Nathan; van den Broek, Richard; Block, Kornelis

    1997-01-01

    There is a growing awareness of the serious problems associated with the provision of sufficient energy to meet human needs and to fuel economic growth world-wide. This has pointed to the need for energy and material efficiency, which would reduce air, water and thermal pollution, as well as waste production. Increasing energy and material efficiency also have the benefits of increased employment, improved balance of imports and exports, increased security of energy supply, and adopting environmentally advantageous energy supply. A large potential exists for energy savings through energy and material efficiency improvements. Technologies are not now, nor will they be, in the foreseeable future, the limiting factors with regard to continuing energy efficiency improvements. There are serious barriers to energy efficiency improvement, including unwillingness to invest, lack of available and accessible information, economic disincentives and organizational barriers. A wide range of policy instruments, as well as innovative approaches have been tried in some countries in order to achieve the desired energy efficiency approaches. These include: regulation and guidelines; economic instruments and incentives; voluntary agreements and actions, information, education and training; and research, development and demonstration. An area that requires particular attention is that of improved international co-operation to develop policy instruments and technologies to meet the needs of developing countries. Material efficiency has not received the attention that it deserves. Consequently, there is a dearth of data on the qualities and quantities for final consumption, thus, making it difficult to formulate policies. Available data, however, suggest that there is a large potential for improved use of many materials in industrialized countries.

  19. Impact of Weather and Occupancy on Energy Flexibility Potential of a Low-energy Building

    DEFF Research Database (Denmark)

    Zilio, Emanuele; Foteinaki, Kyriaki; Gianniou, Panagiota

    The introduction of renewable energy sources in the energy market leads to instability of the energy system itself; therefore, new solutions to increase its flexibility will become more common in the coming years. In this context the implementation of energy flexibility in buildings is evaluated...... solar radiation and the outdoor temperature appeared to have the larger impact on the thermal flexibility of the building. Specifically, the energy flexibility potential of the examined apartment can ensure its thermal autonomy up to 200 h in a typical sunny winter day......., using heat storage in the building mass. This study focuses on the influence of weather conditions and internal gains on the energy flexibility potential of a nearly-zero-energy building in Denmark. A specific six hours heating program is used to reach the scope. The main findings showed that the direct...

  20. The potential biomass for energy production in the Czech Republic

    International Nuclear Information System (INIS)

    Lewandowski, I.; van Hooijdonk, A.; van Dam, J.; Faaij, A.; Weger, J.; Havlickova, K.

    2006-01-01

    Biomass production is a promising alternative for the Czech Republic's (CZ) agricultural sector. Biomass could cover the domestic bio-energy demand of 250PJa -1 (predicted for 2030), and could be exported as bio-fuels to other EU countries. This study assesses the CZ's biomass production potential on a regional level and provides cost-supply curves for biomass from energy crops and agricultural and forestry residues. Agricultural productivity and the amount of land available for energy crop production are key variables in determining biomass potentials. Six scenarios for 2030 with different crop-yield levels, feed conversion efficiencies and land allocation procedures were built. The demand for food and fodder production was derived from FAO predictions for 2030. Biomass potential in the CZ is mainly determined by the development of food and fodder crop yields because the amount of land available for energy crop production increases with increasing productivity of food and fodder crops. In most scenarios the NUTS-3 regions CZ020, 31 and 32 provided the most land for energy-crop production and the highest biomass potentials. About 110PJa -1 , mostly from agricultural and forestry residues, can be provided from biomass when the present Czech agricultural productivity is maintained. About 195PJa -1 (105PJ from energy crops) can be provided when production systems are optimised with regard to fertilizer regimes and 365PJa -1 (290PJ from energy crops) when the yield level of Dutch agriculture is reached. Costs for woody biomass decrease with increasing plantation yield and range between 2.58 and 4.76 GJ -1 . It was concluded that Czech agriculture could provide enough biomass for domestic demand and for export if agricultural productivity is increased. (author)

  1. Morse potential, symmetric Morse potential and bracketed bound-state energies

    Czech Academy of Sciences Publication Activity Database

    Znojil, Miloslav

    2016-01-01

    Roč. 31, č. 14 (2016), s. 1650088 ISSN 0217-7323 R&D Projects: GA ČR GA16-22945S Institutional support: RVO:61389005 Keywords : quantum bound states * special functions * Morse potential * symmetrized Morse potential * upper and lower energy estimates * computer-assisted symbolic manipulations Subject RIV: BE - Theoretical Physics Impact factor: 1.165, year: 2016

  2. Global Potential of Energy Efficiency Standards and Labeling Programs

    Energy Technology Data Exchange (ETDEWEB)

    McNeil, Michael A; McNeil, Michael A.; Letschert, Virginie; de la Rue du Can, Stephane

    2008-06-15

    This report estimates the global potential reductions in greenhouse gas emissions by 2030 for energy efficiency improvements associated with equipment (appliances, lighting, and HVAC) in buildings by means of energy efficiency standards and labels (EES&L). A consensus has emerged among the world's scientists and many corporate and political leaders regarding the need to address the threat of climate change through emissions mitigation and adaptation. A further consensus has emerged that a central component of these strategies must be focused around energy, which is the primary generator of greenhouse gas emissions. Two important questions result from this consensus: 'what kinds of policies encourage the appropriate transformation to energy efficiency' and 'how much impact can these policies have'? This report aims to contribute to the dialogue surrounding these issues by considering the potential impacts of a single policy type, applied on a global scale. The policy addressed in this report is Energy Efficient Standards and Labeling (EES&L) for energy-consuming equipment, which has now been implemented in over 60 countries. Mandatory energy performance standards are important because they contribute positively to a nation's economy and provide relative certainty about the outcome (both timing and magnitudes). Labels also contribute positively to a nation's economy and importantly increase the awareness of the energy-consuming public. Other policies not analyzed here (utility incentives, tax credits) are complimentary to standards and labels and also contribute in significant ways to reducing greenhouse gas emissions. We believe the analysis reported here to be the first systematic attempt to evaluate the potential of savings from EES&L for all countries and for such a large set of products. The goal of the analysis is to provide an assessment that is sufficiently well-quantified and accurate to allow comparison and integration

  3. Nature of the singlet and triplet excitations mediating thermally activated delayed fluorescence

    Science.gov (United States)

    Olivier, Y.; Yurash, B.; Muccioli, L.; D'Avino, G.; Mikhnenko, O.; Sancho-García, J. C.; Adachi, C.; Nguyen, T.-Q.; Beljonne, D.

    2017-12-01

    Despite significant efforts, a complete mechanistic understanding of thermally activated delayed fluorescence (TADF) materials has not yet been fully uncovered. Part of the complexity arises from the apparent dichotomy between the need for close energy resonance and for a significant spin-orbit coupling between alike charge-transfer singlet and triplet excitations. Here we show, in the case of reference carbazole derivatives, that this dichotomy can be resolved in a fully atomistic model accounting for thermal fluctuations of the molecular conformations and microscopic electronic polarization effects in amorphous films. These effects yield electronic excitations with a dynamically mixed charge-transfer and localized character, resulting in thermally averaged singlet-triplet energy differences and interconversion rates in excellent agreement with careful spectroscopic studies.

  4. Non-self-sustained electric discharge in oxygen gas mixtures: singlet delta oxygen production

    CERN Document Server

    Ionin, A A; Kotkov, A A; Kochetov, I V; Napartovich, A P; Seleznev, L V; Sinitsyn, D V; Hager, G D

    2003-01-01

    The possibility of obtaining a high specific input energy in an electron-beam sustained discharge ignited in oxygen gas mixtures O sub 2 : Ar : CO (or H sub 2) at the total gas pressures of 10-100 Torr was experimentally demonstrated. The specific input energy per molecular component exceeded approx 6 kJ l sup - sup 1 atm sup - sup 1 (150 kJ mol sup - sup 1) as a small amount of carbon monoxide was added into a gas mixture of oxygen and argon. It was theoretically demonstrated that one might expect to obtain a singlet delta oxygen yield of 25% exceeding its threshold value needed for an oxygen-iodine laser operation at room temperature, when maintaining a non-self-sustained discharge in oxygen gas mixtures with molecular additives CO, H sub 2 or D sub 2. The efficiency of singlet delta oxygen production can be as high as 40%.

  5. Potential energy consumption reduction of automotive climate control systems

    International Nuclear Information System (INIS)

    Nielsen, Filip; Uddheim, Åsa; Dalenbäck, Jan-Olof

    2016-01-01

    Highlights: • Twenty-on energy saving measures for vehicle interior climate were evaluated. • Few single energy saving measures could reduce the energy use significantly. • The operation of the system in intermediate conditions determines the energy use. • Required heating/cooling of passenger compartment had small effect on energy use. - Abstract: In recent years fuel consumption of passenger vehicles has received increased attention by customers, the automotive industry, regulatory agencies and academia. One area which affect the fuel consumption is climate control systems. Twenty-one energy saving measures were evaluated regarding the total energy use for vehicle interior climate using simulation. Evaluated properties were heat flow into the passenger compartment, electrical and mechanical work. The simulation model included sub models of the passenger compartment, air-handling unit, Air Conditioning (AC) system, engine and engine cooling system. A real-world representative test cycle, which included tests in cold, intermediate and warm conditions, was used for evaluation. In general, few single energy saving measures could reduce the energy use significantly. The measures with most potential were increased blower efficiency with a reduction of 46% of the electrical work and increased AC-system disengage temperature with a reduction of 27% of the mechanical work. These results show that the operation of the climate control system had a large effect on the energy use, especially compared to the required heating and cooling of the passenger compartment. As a result energy saving measures need to address how heating and cooling is generated before reducing the heat flow into the passenger compartment.

  6. Potential of Using Solar Energy for Drinking Water Treatment Plant

    Science.gov (United States)

    Bukhary, S. S.; Batista, J.; Ahmad, S.

    2016-12-01

    Where water is essential to energy generation, energy usage is integral to life cycle processes of water extraction, treatment, distribution and disposal. Increasing population, climate change and greenhouse gas production challenges the water industry for energy conservation of the various water-related operations as well as limiting the associated carbon emissions. One of the ways to accomplish this is by incorporating renewable energy into the water sector. Treatment of drinking water, an important part of water life cycle processes, is vital for the health of any community. This study explores the feasibility of using solar energy for a drinking water treatment plant (DWTP) with the long-term goal of energy independence and sustainability. A 10 MGD groundwater DWTP in southwestern US was selected, using the treatment processes of coagulation, filtration and chlorination. Energy consumption in units of kWh/day and kWh/MG for each unit process was separately determined using industry accepted design criteria. Associated carbon emissions were evaluated in units of CO2 eq/MG. Based on the energy consumption and the existing real estate holdings, the DWTP was sized for distributed solar. Results showed that overall the motors used to operate the pumps including the groundwater intake pumps were the largest consumers of energy. Enough land was available around DWTP to deploy distributed solar. Results also showed that solar photovoltaics could potentially be used to meet the energy demands of the selected DWTP, but warrant the use of a large storage capacity, and thus increased costs. Carbon emissions related to solar based design were negligible compared to the original case. For future, this study can be used to analyze unit processes of other DWTP based on energy consumption, as well as for incorporating sustainability into the DWTP design.

  7. Potential energy surface for ? dissociation including spin-orbit effects

    Science.gov (United States)

    Siebert, Matthew R.; Aquino, Adelia J. A.; de Jong, Wibe A.; Granucci, Giovanni; Hase, William L.

    2012-10-01

    Previous experiments [J. Phys. Chem. A 116, 2833 (2012)] have studied the dissociation of 1,2-diiodoethane radical cation ( ? ) and found a one-dimensional distribution of translational energy, an odd finding considering most product relative translational energy distributions are two-dimensional. The goal of this study is to obtain an accurate understanding of the potential energy surface (PES) topology for the unimolecular decomposition reaction ? → C2H4I+ + I•. This is done through comparison of many single-reference electronic structure methods, coupled-cluster single-point (energy) calculations, and multi-reference energy calculations used to quantify spin-orbit (SO) coupling effects. We find that the structure of the ? reactant has a substantial effect on the role of the SO coupling on the reaction energy. Both the BHandH and MP2 theories with an ECP/6-31++G** basis set, and without SO coupling corrections, provide accurate models for the reaction energetics. MP2 theory gives an unsymmetric structure with different C-I bond lengths, resulting in a SO energy for ? similar to that for the product I-atom and a negligible SO correction to the reaction energy. In contrast, DFT gives a symmetric structure for ? , similar to that of the neutral C2H4I2 parent, resulting in a substantial SO correction and increasing the reaction energy by 6.0-6.5 kcalmol-1. Also, we find that, for this system, coupled-cluster single-point energy calculations are inaccurate, since a small change in geometry can lead to a large change in energy.

  8. Magnetism of singlet - singlet ions interacting with an electron gas: application to PrAl2

    International Nuclear Information System (INIS)

    Palermo, L.

    1986-01-01

    Various magnetic quantities are investigated for a system consisting of singlet-singlet ions interacting with an electron gas. In obtaining the magnetic state equations, the molecular field approximation is used. At T=0, an onset magnetic order condition in function of crystal field and exchange parameters and eletronic density of states at Fermi level is derived. A parametric study of the model is performed numerically. Main results are shown on diagrams. From the experimental data existent in the literature for magnetisation, susceptibility and magnetic specific heat of the PrAl 2 , a fitting with the model predictions is obtained using the following parameters: exchange interaction: 611meV; crystal field parameters: 2,5 meV; band with: 10 eV (of a rectangular density of states with 0,8 el/atom). (author) [pt

  9. Reliable Prediction with Tuned Range-Separated Functionals of the Singlet-Triplet Gap in Organic Emitters for Thermally Activated Delayed Fluorescence (TADF)

    KAUST Repository

    Sun, Haitao

    2015-07-09

    The thermally activated delayed fluorescence (TADF) mechanism has recently attracted much interest in the field of organic light-emitting diodes (OLEDs). TADF relies on the presence of a very small energy gap between the lowest singlet and triplet excited states. Here, we demonstrate that time-dependent density functional theory (TD-DFT) in the Tamm-Dancoff Approximation can be very successful in the calculations of the lowest singlet and triplet excitation energies and the corresponding singlet-triplet gap when using nonempirically tuned range-separated functionals. Such functionals provide very good estimates in a series of 17 molecules used in TADF-based OLED devices, with mean absolute deviations of 0.15 eV for the vertical singlet excitation energies and 0.09 eV [0.07 eV] for the adiabatic [vertical] singlet-triplet energy gaps as well as low relative errors and high correlation coefficients compared to the corresponding experimental values. They significantly outperform conventional functionals, a feature which is rationalized on the basis of the amount of exact-exchange included and the delocalization error. The present work provides a reliable theoretical tool for the prediction and development of novel TADF-based materials with low singlet-triplet energetic splittings.

  10. Energy aspects and potential energy savings of the new DASI process for milk sterilization

    Energy Technology Data Exchange (ETDEWEB)

    Frey, B.C. (Univ. of Maryland, College Park); Stewart, L.E.; Chandarana, D.; Wolfson, R.P.

    1981-01-01

    An experimental study was conducted to determine the difference in total processing energy required by the DASI ultra-high temperature (UHT) system and a conventional high temperature short time (HTST) fluid milk system. Data available in the literature were used to develop an energy use profile for the current US fluid milk system from processor to consumer. The energy data measured and the profile developed were used to estimate the potential energy savings resulting from the introduction of sterile milk in the US fluid milk market. Savings of energy resulting from the introduction of sterile milk were estimated to be 12 million barrels of oil annually.

  11. Polymer-enhanced energy harvesting from streaming potential

    NARCIS (Netherlands)

    Nguyen, Trieu; Xie, Yanbo; de Vreede, Lennart; van den Berg, Albert; Eijkel, Jan C.T.; Fujii, T.; Hibara, A.; Takeuchi, S.; Fukuba, T.

    2012-01-01

    In this contribution, we present the experimental results of energy conversion from the streaming potential when a polymer, polyacrylic acid (PAA) with concentration from 200 ppm to 4000 ppm in background electrolyte KCl solution was used as the working fluid. The results show that when PAA was

  12. Determination of wave energy potential of black sea

    NARCIS (Netherlands)

    Bingölbali, Bilal; Akpınar, Adem; van Vledder, G.P.; Lynett, P.

    2016-01-01

    This study aims to assess wave energy potential and its long-term spatial and temporal characteristics in the Black Sea within the TUBITAK research project (Akpınar et al., 2015). With this purpose, a wave model (SWAN model version 41.01 driven by the CFSR winds) over the entire Black Sea was

  13. Potential for sustainable energy with biogas from sewage purification

    International Nuclear Information System (INIS)

    Coenen, J.; Van Gastel, M.; De Jong, K.

    2005-04-01

    Insight is given into the possibility to produce biogas from sewage purification plants in the Netherlands. Attention is paid to the estimated potential of sustainable energy from biogas, the economic effectiveness of several scenarios, the critical success factors and bottlenecks [nl

  14. On intermediate energy heavy ion optical model potential

    International Nuclear Information System (INIS)

    Rihan, T.H.; Awin, A.M.

    1992-08-01

    We derive in this paper an approximate analytical expression for the heavy ion optical potential by solving the inversion problem based on the McIntyre parametrization of the S-matrix. The quasi-classical limit of high energy approximation is modified in our approach so as to account for the Coulomb distortion of the trajectory. (author). 5 refs, 2 figs

  15. Density-scaling exponents and virial potential-energy correlation ...

    Indian Academy of Sciences (India)

    This paper investigates the relation between the density-scaling exponent γ and the virial potential energy correlation coefficient R at several thermodynamic state points in three dimensions for the generalized (2n, n) Lennard-Jones (LJ) system for n = 4, 9, 12, 18, as well as for the standard n = 6 LJ system in two,three, and ...

  16. Assessing the potential for biomass energy development in South Carolina

    Science.gov (United States)

    Roger C. Conner; Tim O. Adams; Tony G. Johnson

    2009-01-01

    An assessment of the potential for developing a sustainable biomass energy industry in South Carolina was conducted. Biomass as defined by Forest Inventory and Analysis is the aboveground dry weight of wood in the bole and limbs of live trees ≥1-inch diameter at breast height, and excludes tree foliage, seedlings, and understory...

  17. Scattering at zero energy for attractive homogeneous potentials

    DEFF Research Database (Denmark)

    Derezinski, Jan; Skibsted, Erik

    2009-01-01

    We compute up to a compact term the zero-energy scattering matrix for a class of potentials asymptotically behaving as −γ|x|−μ with 0 < μ < 2 and γ > 0. It turns out to be the propagator for the wave equation on the sphere at time ....

  18. RUSTEC: Greening Europe's energy supply by developing Russia's renewable energy potential

    International Nuclear Information System (INIS)

    Boute, Anatole; Willems, Patrick

    2012-01-01

    The North-West of Russia is characterized by a large renewable energy resource base in geographic proximity to the EU. At the same time, EU Member States are bound by mandatory renewable energy targets which could prove to be costly to achieve in the current budgetary context and which often face strong local opposition. Directive 2009/28/EC on Renewable Energy makes it possible for Member States to achieve their targets by importing electricity produced from renewable energy sources from non-EU countries. So far, most attention has been on the Mediterranean Solar Plan or Desertec. An EU–Russia Renewable Energy Plan or RUSTEC – being based on onshore wind/biomass/hydro energy and on-land interconnection, rather than solar power and subsea lines – could present a cost-efficient and short-term complement to Desertec. This article examines the political, geopolitical, economic, social and legal challenges and opportunities of exporting “green” energy from Russia to the EU. It argues that EU–Russian cooperation in the renewable energy field would present a win-win situation: Member States could achieve their targets on the basis of Russia's renewable energy potential, while Russia could begin to develop a national renewable energy industry without risking potential price increases for domestic consumers—a concern of great political sensitivity in Russia. - Highlights: ► Russia has a huge renewable energy potential in geographic proximity to the EU. ► This potential could help the EU decarbonize its electricity supply at least cost.► EU–Russia green energy export is a win-win situation but lacks political attention.► RUSTEC could be a short-term and cost-efficient complement to Desertec. ► RUSTEC would diversify EU energy imports/Russian exports and stimulate innovation.

  19. Pseudospectral Gaussian quantum dynamics: Efficient sampling of potential energy surfaces.

    Science.gov (United States)

    Heaps, Charles W; Mazziotti, David A

    2016-04-28

    Trajectory-based Gaussian basis sets have been tremendously successful in describing high-dimensional quantum molecular dynamics. In this paper, we introduce a pseudospectral Gaussian-based method that achieves accurate quantum dynamics using efficient, real-space sampling of the time-dependent basis set. As in other Gaussian basis methods, we begin with a basis set expansion using time-dependent Gaussian basis functions guided by classical mechanics. Unlike other Gaussian methods but characteristic of the pseudospectral and collocation methods, the basis set is tested with N Dirac delta functions, where N is the number of basis functions, rather than using the basis function as test functions. As a result, the integration for matrix elements is reduced to function evaluation. Pseudospectral Gaussian dynamics only requires O(N) potential energy calculations, in contrast to O(N(2)) evaluations in a variational calculation. The classical trajectories allow small basis sets to sample high-dimensional potentials. Applications are made to diatomic oscillations in a Morse potential and a generalized version of the Henon-Heiles potential in two, four, and six dimensions. Comparisons are drawn to full analytical evaluation of potential energy integrals (variational) and the bra-ket averaged Taylor (BAT) expansion, an O(N) approximation used in Gaussian-based dynamics. In all cases, the pseudospectral Gaussian method is competitive with full variational calculations that require a global, analytical, and integrable potential energy surface. Additionally, the BAT breaks down when quantum mechanical coherence is particularly strong (i.e., barrier reflection in the Morse oscillator). The ability to obtain variational accuracy using only the potential energy at discrete points makes the pseudospectral Gaussian method a promising avenue for on-the-fly dynamics, where electronic structure calculations become computationally significant.

  20. Review of Potential Characterization Techniques in Approaching Energy and Sustainability

    Directory of Open Access Journals (Sweden)

    David J. LePoire

    2014-03-01

    Full Text Available Societal prosperity is linked to sustainable energy and a healthy environment. However, tough global challenges include increased demand for fossil fuels, while approaching peak oil production and uncertainty in the environmental impacts of energy generation. Recently, energy use was identified as a major component of economic productivity, along with capital and labor. Other environmental resources and impacts may be nearing environmental thresholds, as indicated by nine planetary environmental boundaries, many of which are linked to energy production and use. Foresight techniques could be applied to guide future actions which include emphasis on (1 energy efficiency to bridge the transition to a renewable energy economy; (2 continued research, development, and assessment of new technologies; (3 improved understanding of environment impacts including natural capital use and degradation; (4 exploration of GDP alternative measures that include both economic production and environmental impacts; and (5 international cooperation and awareness of longer-term opportunities and their associated potential scenarios. Examples from the U.S. and the international community illustrate challenges and potential.

  1. Recognising the potential for renewable energy heating and cooling

    International Nuclear Information System (INIS)

    Seyboth, Kristin; Beurskens, Luuk; Langniss, Ole; Sims, Ralph E.H.

    2008-01-01

    Heating and cooling in the industrial, commercial, and domestic sectors constitute around 40-50% of total global final energy demand. A wide range of renewable energy heating and cooling (REHC) technologies exists but they are presently only used to meet around 2-3% of total world demand (excluding from traditional biomass). Several of these technologies are mature, their markets are growing, and their costs relative to conventional heating and cooling systems continue to decline. However, in most countries, policies developed to encourage the wider deployment of renewable electricity generation, transport biofuels and energy efficiency have over-shadowed policies aimed at REHC technology deployment. This paper, based on the findings of the International Energy Agency publication Renewables for Heating and Cooling-Untapped Potential, outlines the present and future markets and compares the costs of providing heating and cooling services from solar, geothermal and biomass resources. It analyses current policies and experiences and makes recommendations to support enhanced market deployment of REHC technologies to provide greater energy supply security and climate change mitigation. If policies as successfully implemented by the leading countries were to be replicated elsewhere (possibly after modification to better suit local conditions), there would be good potential to significantly increase the share of renewable energy in providing heating and cooling services

  2. Energy storage: potential analysis is still on the way

    International Nuclear Information System (INIS)

    Signoret, Stephane; Dejeu, Mathieu; Deschaseaux, Christelle; De Santis, Audrey; Cygler, Clement; Petitot, Pauline

    2014-01-01

    A set of articles gives an overview of the status and current evolutions of the energy storage sector. The different technologies (flywheel, lithium-ion batteries, NaS or Zebra batteries, compressed air energy storage or CAES, 2. generation CAES, pump storage power plants or PSP) have different applications areas, and also different technological maturity levels. PSPs have probably the best potential nowadays, but investors must be supported. In an interview, a member of the CNRS evokes the main researches, the obstacles in the development of solar thermodynamic plants, technology transfers, and the potential of hydrogen for massive energy storage. An article outlines the need to develop the battery market. Several technological examples and experiments are then presented: Nice Grid (storage at the source level), FlyProd (energy storage by flywheel). An article then addresses the issue of heat storage, notably in a situation of energy co-generation. Researches and prototype development are then presented, the objective of which is to obtain an adiabatic CAES. The last articles address the development of hydrogen to store energy (technologies) and a first technological demonstrator

  3. Three-dimensional potential energy surface of Ar–CO

    Energy Technology Data Exchange (ETDEWEB)

    Sumiyoshi, Yoshihiro, E-mail: y-sumiyoshi@gunma-u.ac.jp [Division of Pure and Applied Science, Graduate School of Science and Technology, Gunma University, 4-2 Aramaki, Maebashi, Gunma 371-8510 (Japan); Endo, Yasuki [Department of Basic Science, Graduate School of Arts and Sciences, The University of Tokyo, Komaba, Meguro-ku, Tokyo 153-8902 (Japan)

    2015-01-14

    A three-dimensional intermolecular potential energy surface of the Ar–CO complex has been determined by fitting most of the previously reported spectroscopic data, where observed transition frequencies by microwave, millimeter-wave, submillimeter-wave, and infrared spectroscopy were reproduced simultaneously within their experimental accuracies. A free rotor model Hamiltonian considering all the freedom of motions for an atom-diatom system was applied to calculate vibration-rotation energies. A three-dimensional potential energy surface obtained by ab initio calculations at the CCSD(T)-F12b/aug-cc-pV5Z level of theory was parameterized by a model function consisting of 46 parameters. They were used as initial values for the least-squares analysis of the experimental data. A total of 20 parameters were optimized to reproduce all the spectroscopic data.

  4. Generalized Potential Energy Finite Elements for Modeling Molecular Nanostructures.

    Science.gov (United States)

    Chatzieleftheriou, Stavros; Adendorff, Matthew R; Lagaros, Nikos D

    2016-10-24

    The potential energy of molecules and nanostructures is commonly calculated in the molecular mechanics formalism by superimposing bonded and nonbonded atomic energy terms, i.e. bonds between two atoms, bond angles involving three atoms, dihedral angles involving four atoms, nonbonded terms expressing the Coulomb and Lennard-Jones interactions, etc. In this work a new, generalized numerical simulation is presented for studying the mechanical behavior of three-dimensional nanostructures at the atomic scale. The energy gradient and Hessian matrix of such assemblies are usually computed numerically; a potential energy finite element model is proposed herein where these two components are expressed analytically. In particular, generalized finite elements are developed that express the interactions among atoms in a manner equivalent to that invoked in simulations performed based on the molecular dynamics method. Thus, the global tangent stiffness matrix for any nanostructure is formed as an assembly of the generalized finite elements and is directly equivalent to the Hessian matrix of the potential energy. The advantages of the proposed model are identified in terms of both accuracy and computational efficiency. In the case of popular force fields (e.g., CHARMM), the computation of the Hessian matrix by implementing the proposed method is of the same order as that of the gradient. This analysis can be used to minimize the potential energy of molecular systems under nodal loads in order to derive constitutive laws for molecular systems where the entropy and solvent effects are neglected and can be approximated as solids, such as double stranded DNA nanostructures. In this context, the sequence dependent stretch modulus for some typical base pairs step is calculated.

  5. Energy efficiency potential study for New Brunswick: Commercial sector

    International Nuclear Information System (INIS)

    1992-02-01

    A study was conducted to quantify the energy savings in the New Brunswick commercial sector. A description is presented of the current New Brunswick commercial building stock, including typical insulation levels, lighting levels, light loads, heating/ventilation/air conditioning equipment and operating hours for each building segment selected, as well as estimation of existing floor space and segment-specific growth and demolition rates. Key energy data for the commercial sector are described, including end-use energy intensities for existing and new building stock and estimation of fuel shares for each building segment and end use. Potential energy savings were calculated under three scenarios: frozen-efficiency, in which no new energy efficiency improvements are incorporated into existing buildings; technical potential, in which the most efficient commercially available technologies are incorporated into the building stock; and economic potential, in which the only technologies implemented are those whose installed cost is equal to, or less than, the economic cost of new supply. Results show that in the year 2000, total potential economic secondary electricity savings related to efficiency improvements are estimated to be ca 2,460 TJ; savings at the primary level would be ca 7,625 TJ. If fuel switching options are included, total electricity demand in the year 2000 would be further reduced from the frozen efficiency level of 2,969 GWh to 1,834 GWh. By the year 2010, the total potential for electricity reduction, due exclusively to fuel switching, increases to 765 GWh; over 90% of this reduction is due to space heat conversions. 11 figs., 122 tabs

  6. Study of the renewable energy potential and development in Alsace

    International Nuclear Information System (INIS)

    2016-01-01

    This report is part of a study which aimed at assessing the possibility of a renewable energy production equal to or greater than Alsace energy production between 2020 and 2050. It comprised an analysis of potentials and deadlocks for the development of each renewable energy. After an overview of renewable energy production by the end of 2012, the report addresses the different sectors (solar, biomass fuel, geothermal, heat recovery, aero-thermal, wind, hydroelectricity, methanization, agricultural fuels, transports). For each of them, it proposes assessments for the different specific technical resources and processes. Then, after a synthesis of the obtained maximum theoretical resources, it reports the development of three scenarios (a trend-based one, a maximum one, and a proactive one) while addressing each resource within them

  7. Potential of forestry biomass for energy in economies in transition

    International Nuclear Information System (INIS)

    Apalovic, R.

    1995-01-01

    A rapid increase in the world's population, the gradual exhaustion of fossil fuels and serious ecological problems are making developed countries more attentive to the utilization of renewable energy sources, mainly biomass, which should form part of the global energy mix during the twenty-first century. The economies in transition have been experiencing a transformation of their political, economic and social systems and a modernization of their industry, including the energy industry. Energy supply in the transition economies is based on coal, oil, gas and nuclear power. Of the renewable sources, only hydroelectric power is utilized to any significant extent. The forest biomass resources of these economies are quantified in this paper. The economies in transition have a big potential for biomass from forestry and timber industry wastes and agricultural wastes that are not being utilized and could become a source of energy. So far, biomass is used as a source of energy in only small amounts in the wood and pulp industries and as fuelwood in forestry. The governments of some countries (the Czech Republic, Hungary and Slovakia) have energy plans through the year 2010 that aim to develop renewable energy sources. Economic, institutional, technical and other barriers to the development of renewable sources and their utilization are analysed in this paper and some remedies are proposed. In cooperation with countries such as Austria, Denmark, Sweden, Finland, the United States of America and others, which have achieved remarkable results in the utilization of biomass for energy, it would be possible for the transition economies to quickly develop the technological know-how needed to satisfy the demand for energy of approximately 350 million inhabitants. (author)

  8. Nuclear energy role and potential for global sustainable development

    International Nuclear Information System (INIS)

    Ujita, H.; Matsui, K.

    2006-01-01

    The long-term energy supply simulation that optimizes the energy system cost until 2100 for the world is being performed, by using the energy module of GRAPE model, where energy demand under the C02 emission constraint etc. is assumed. The model has been taken up for the trial calculation in I PCC the third report . Role and potential of nuclear energy system in the energy options is discussed here from the viewpoint of sustainable development with protecting from global warming. Taking the effort for energy conservation as major premise, carbon-sequestration for fossil fuel, renewable energy and nuclear energy should be altogether developed under the C02 constraint. Especially, fast breeder reactor will be attached importance to, as the 22nd century is approaching, due to its carbon free and resource limitless features when the nuclear generation cost is cheap as a current light water reactor level. It takes time around 30 years in order for breeding of Pu, a fast breeder reactor will begin to be introduced from around 2030. If the period for the technology establish of nuclear fuel cycle is assumed to be 30 years, it is necessary to start technical development right now. If the Kyoto Protocol, the emission constraint on only the developed countries, is extended in 21st century, it will promote the growth of nuclear power in the developed countries in the first half of the century. After 2050, the developing countries will face the shortage of uranium and plutonium. Carbon emission constraint should be covered all countries in the World not only for the developed countries but also for the developing countries. Therefore, it is important that the developing countries will use nuclear power effectively from the viewpoint of harmonization of energy growth and global environment. The policy that nuclear power is considered as Clean Development Mechanism would mitigate such global warming problems

  9. Rotational Energy Transfer of N2 Gas Determined Using a New Ab Initio Potential Energy Surface

    Science.gov (United States)

    Huo, Winifred M.; Stallcop, James R.; Partridge, Harry; Langhoff, Stephen R. (Technical Monitor)

    1997-01-01

    Rotational energy transfer between two N2 molecules is a fundamental process of some importance. Exchange is expected to play a role, but its importance is somewhat uncertain. Rotational energy transfer cross sections of N2 also have applications in many other fields including modeling of aerodynamic flows, laser operations, and linewidth analysis in nonintrusive laser diagnostics. A number of N2-N2 rigid rotor potential energy surface (PES) has been reported in the literature.

  10. Potentials for energy efficiency improvements and implementation of renewable energy sources in hotel industry in Macedonia

    OpenAIRE

    Cingoski, Vlatko

    2015-01-01

    In this presentation, potentials for energy efficiency improvements and implementation of renewable energy sources in hotel industry in Macedonia are discussed. This presentation was part of the research project entitled "Opportunities and Methods for Energy Substitution, Savings and Efficiency Improvements in the Hotel Industry" funded by the University "Goce Delcev", Stip, Macedonia. It was prsented at the joint workshop between University "Goce Delcev", Stip, Macedonia and the Bashkent Un...

  11. Contracting of energy services in Switzerland. Development, effects, market potentials

    International Nuclear Information System (INIS)

    Muggli, C.; Baumgartner, W.; Kohn, L.

    1999-06-01

    The authors of this detailed report first define the contracting of energy services, this new reality of the market place, and analyse its current status in Switzerland. Contracting is mainly to be understood as the delegation of certain energy-related services by a company. The total investment for the operated energy systems considered by the study is about 120 millions USD, with an installed power of 160 MW. This market is highly unhomogeneous and is the answer to various goals. Globally, it brings a more efficient use of energy, including a more frequent involvement of renewable energy sources, along with a lower risk and significant advantages for all contractors. That is the reason for the energy policy authority to recommend contracting. The report goes on with the analysis of the factors leading the chief executives to consider contracting of energy services, or on the contrary to exclude it. The authors estimate the realistic potential market for contracting in Switzerland to 650 millions USD for the period 1999-2004. They conclude by giving recommendations which should result in an acceleration of the contracting's development on the market place

  12. Performance-based potential for residential energy efficiency

    Energy Technology Data Exchange (ETDEWEB)

    Performance-based potential for residential energy efficiency

    2013-01-15

    Energy performance contracts (EPCs) have proven an effective mechanism for increasing energy efficiency in nearly all sectors of the economy since their introduction nearly 30 years ago. In the modern form, activities undertaken as part of an EPC are scoped and implemented by experts with specialized technical knowledge, financed by commercial lenders, and enable a facility owner to limit risk and investment of time and resources while receiving the rewards of improved energy performance. This report provides a review of the experiences of the US with EPCs and discusses the possibilities for the residential sector to utilize EPCs. Notably absent from the EPC market is the residential segment. Historically, research has shown that the residential sector varies in several key ways from markets segments where EPCs have proven successful, including: high degree of heterogeneity of energy use characteristics among and within households, comparatively small quantity of energy consumed per residence, limited access to information about energy consumption and savings potential, and market inefficiencies that constrain the value of efficiency measures. However, the combination of recent technological advances in automated metering infrastructure, flexible financing options, and the expansion of competitive wholesale electricity markets to include energy efficiency as a biddable supply-side resource present an opportunity for EPC-like efforts to successfully engage the residential sector, albeit following a different model than has been used in EPCs traditionally.(Author)

  13. Constructing ab initio and empirical potential energy surfaces for water

    International Nuclear Information System (INIS)

    Kain, Jacqueline Sophie

    2001-01-01

    The infrared spectrum of water is possibly one of the most well studied and yet portions of it are still poorly understood. Recently, significant advances have been made in assigning water spectra using variational nuclear calculations. The major factor determining the accuracy of ro-vibrational spectra of water is the accuracy of the underlying Potential Energy Surface. Even the most accurate ab initio Potential Energy Surface does not reproduce the Born-Oppenheimer surface to sufficient accuracy for spectroscopic studies. Furthermore, effects beyond this model such as the adiabatic correction, the relativistic correction and the non-adiabatic correction have to be considered. This thesis includes a discussion on how the relativistic correction was calculated, for the water molecule, from first-order perturbation theory. The relativistic correction improved vibrational stretching motion while making the prediction of the bending modes far worse. For rotational motion the relativistic effect had an increasing effect with increasing Ka. A further alteration to the ab initio calculations is introduced by adjusting the barrier to linearity in the water potential. This alteration to the barrier was considered in order to compensate for the lack of convergence of quantum chemical calculations of the Born-Oppenheimer surface. This barrier attempts to represent the change in the potential from linear to equilibrium. We show the improvements this has on the calculated energy levels by comparison with the HITRAN database. This then led the way to the improved spectroscopic potential presented here in this thesis. This new spectroscopic potential reduces the overall standard deviation significantly for vibrational and rotational energy levels. (author)

  14. Production of Singlet Oxygen in a Non-Self-Sustained Discharge

    International Nuclear Information System (INIS)

    Vasil'eva, A.N.; Klopovskii, K.S.; Kovalev, A.S.; Lopaev, D.V.; Mankelevich, Yu.A.; Popov, N.A.; Rakhimov, A.T.; Rakhimova, T.V.

    2005-01-01

    The production of O 2 (a 1 Δ g ) singlet oxygen in non-self-sustained discharges in pure oxygen and mixtures of oxygen with noble gases (Ar or He) was studied experimentally. It is shown that the energy efficiency of O 2 (a 1 Δ g ) production can be optimized with respect to the reduced electric field E/N. It is shown that the optimal E/N values correspond to electron temperatures of 1.2-1.4 eV. At these E/N values, a decrease in the oxygen percentage in the mixture leads to an increase in the excitation rate of singlet oxygen because of the increase in the specific energy deposition per O 2 molecule. The onset of discharge instabilities not only greatly reduces the energy efficiency of singlet oxygen production but also makes it impossible to achieve high energy deposition in a non-self-sustained discharge. A model of a non-self-sustained discharge in pure oxygen is developed. It is shown that good agreement between the experimental and computed results for a discharge in oxygen over a wide range of reduced electric fields can be achieved only by taking into account the ion component of the discharge current. The cross section for the electron-impact excitation of O 2 (a 1 Δ g ) and the kinetic scheme of the discharge processes with the participation of singlet oxygen are verified by comparing the experimental and computed data on the energy efficiency of the production of O 2 (a 1 Δ g ) and the dynamics of its concentration. It is shown that, in the dynamics of O 2 (a 1 Δ g ) molecules in the discharge afterglow, an important role is played by their deexcitation in a three-body reaction with the participation of O( 3 P) atoms. At high energy depositions in a non-self-sustained discharge, this reaction can reduce the maximal attainable concentration of singlet oxygen. The effect of a hydrogen additive to an Ar : O 2 mixture is analyzed based on the results obtained using the model developed. It is shown that, for actual electron beam current densities, a

  15. Theoretical rationalization of the singlet-triplet gap in OLEDs materials: impact of charge-transfer character.

    Science.gov (United States)

    Moral, M; Muccioli, L; Son, W-J; Olivier, Y; Sancho-García, J C

    2015-01-13

    New materials for OLED applications with low singlet-triplet energy splitting have been recently synthesized in order to allow for the conversion of triplet into singlet excitons (emitting light) via a Thermally Activated Delayed Fluorescence (TADF) process, which involves excited-states with a non-negligible amount of Charge-Transfer (CT). The accurate modeling of these states with Time-Dependent Density Functional Theory (TD-DFT), the most used method so far because of the favorable trade-off between accuracy and computational cost, is however particularly challenging. We carefully address this issue here by considering materials with small (high) singlet-triplet gap acting as emitter (host) in OLEDs and by comparing the accuracy of TD-DFT and the corresponding Tamm-Dancoff Approximation (TDA), which is found to greatly reduce error bars with respect to experiments thanks to better estimates for the lowest singlet-triplet transition. Finally, we quantitatively correlate the singlet-triplet splitting values with the extent of CT, using for it a simple metric extracted from calculations with double-hybrid functionals, that might be applied in further molecular engineering studies.

  16. A generalization of CAPE into potential-energy convertibility

    Science.gov (United States)

    Yano, Jun-Ichi; Chaboureau, Jean-Pierre; Guichard, Françoise

    2005-04-01

    The concept of the potential-energy convertibility (PEC) is proposed as a generalization of convective available potential energy (CAPE). It is defined as a vertical integral of buoyancy weighted by a non-dimensional normalized vertical momentum. This is a measure of convertibility of potential energy into kinetic energy in the sense that the actual conversion rate is recovered when PEC evaluated by the convective-scale local buoyancy and vertical momentum, as available from cloud-resolving model (CRM) simulations, is multiplied by the normalization factor for the vertical momentum. It reduces to CAPE, when the standard parcel-lifted buoyancy and a unit value for the normalized vertical momentum are used. It is equivalent to Arakawas-Schubert's cloud work function, when the buoyancy and the vertical momentum profile for an entraining plume are used. PEC evaluated from locally defined buoyancy and vertical momentum in CRM simulations correlates better with the convective precipitation than CAPE. The evaluation of PEC within a convective parametrization may be possible with an appropriate definition of the effective entrainment rate, for example, which is expected to improve CAPE-based convective parametrizations.

  17. The Dilemmas of Energy: Essential energy services and potentially fatal risks

    Science.gov (United States)

    Perkins, J. H.

    2018-01-01

    During their evolution, humans have made three energy transitions, each marked by the adoption of new ways of procuring energy with attendant changes in lifestyle. Modern civilization arose in the Third Energy Transition, and its major sources of energy come from coal, oil, gas, uranium, and hydropower. Unfortunately, despite its incalculable benefits, the Third Transition can’t provide sustainable energy services for the indefinite future. Climate change is the most serious problem. Criteria and standards for each of the currently available, nine primary energy sources indicate the potential feasibility of replacing most or all uses of coal, oil, gas, and uranium with hydropower, solar, wind, biomass, and geothermal. This is the Fourth Energy Transition, promotion of which is strongly supported by considerations of sustainability.

  18. No strings attached potential vs. interaction energy in QCD

    International Nuclear Information System (INIS)

    Goldman, T.

    1996-01-01

    In infrared-stable fixed-point field theories, the interaction energy of a test particle is proportional to the non-relativistic (heavy source) coordinate-space potential derived from the field strength produced by that source. This is no longer true in ultraviolet-stable fixed-point field theories (UVSFPFT) as they may not have a finite infrared fixed point. This leads to the possibility that UVSFPFTs may have quite conventional field strength distributions despite the unusual spatial dependence expected for the interaction energy

  19. Parallel unconstrained minimization of potential energy in LAMMPS

    Energy Technology Data Exchange (ETDEWEB)

    Plantenga, T.

    1997-10-13

    This report describes a new minimization capability added to LAMMPS V4.0. Minimization of potential energy is used to find molecular conformations that are close to structures found in nature. The new minimization algorithm uses LAMMPS subroutines for calculating energy and force vectors, and follows the LAMMPS partitioning scheme for distributing large data objects on multiprocessor machines. Since gradient-based algorithms cannot tolerate nonsmoothness, a new Coulomb style that smoothly cuts off to zero at a finite distance is provided. This report explains the minimization algorithm and its parallel implementation within LAMMPS. Guidelines are given for invoking the algorithm and interpreting results.

  20. The electric energy potential of landfill biogas in Brazil

    International Nuclear Information System (INIS)

    Mambeli Barros, Regina; Tiago Filho, Geraldo Lúcio; Silva, Tiago Rodrigo da

    2014-01-01

    The increases in a country's energy capacity are related to its gross domestic product (GDP). In Brazil, increases in income and the consumption of goods and services have led to an increase in the generation of solid waste (SW), which is sent to landfills as a method of treatment and final disposal. The purpose of this study was to facilitate an increase in energy generation from renewable resources, specifically from landfills via thermal biogas plants, and the research was divided into two phases. The first phase involved the assessment of the potential population size contributing to the landfill, which could result in the installation of a financially viable enterprise to generate electricity in Brazil. Next, an estimate of the costs associated with the generation and collection of solid waste in Brazil was predicted by GDP prognoses, the latter being in accordance with the National Energy Balance (Balanço Energético Nacional – BEN) plan created by the Mines and Energy Ministry of Brazil (Ministério de Minas e Energia do Brasil – MME). The net present value (NPV) and internal rate of return (IRR) of each enterprise scenario was used in the first stage to assess the plan's financial viability. In the second stage, estimation curves such as logistics, decreasing rate of growth, and logarithmic curves were used to establish relationships between the generation scenarios and the projected collection of SW and projected GDP. Thus, a range of possible landfill biogas/methane generation values and installed energy capacities were created, considering the extreme maximum and minimum values. These values were related to the energy sources from residual fuels reported by BEN. The results demonstrated that such values still represented a small percentage (0.00020% in 2010 and 0.44496–0.81042% in 2030) of the projected energy generation from residual fuels. Thus, an urgent need was identified to formulate policies that would encourage landfills as a

  1. TeV scale singlet dark matter

    International Nuclear Information System (INIS)

    Ponton, Eduardo; Randall, Lisa

    2009-01-01

    It is well known that stable weak scale particles are viable dark matter candidates since the annihilation cross section is naturally about the right magnitude to leave the correct thermal residual abundance. Many dark matter searches have focused on relatively light dark matter consistent with weak couplings to the Standard Model. However, in a strongly coupled theory, or even if the coupling is just a few times bigger than the Standard Model couplings, dark matter can have TeV-scale mass with the correct thermal relic abundance. Here we consider neutral TeV-mass scalar dark matter, its necessary interactions, and potential signals. We consider signals both with and without higher-dimension operators generated by strong coupling at the TeV scale, as might happen for example in an RS scenario. We find some potential for detection in high energy photons that depends on the dark matter distribution. Detection in positrons at lower energies, such as those PAMELA probes, would be difficult though a higher energy positron signal could in principle be detectable over background. However, a light dark matter particle with higher-dimensional interactions consistent with a TeV cutoff can in principle match PAMELA data.

  2. Fossil energy savings potential of sugar cane bio-energy systems

    Energy Technology Data Exchange (ETDEWEB)

    Nguyen, Thu Lan T. [Department of Agroecology, Aarhus University, Tjele (Denmark); The Joint Graduate School of Energy and Environment, King Mongkut' s University of Technology Thonburi, Bangkok (Thailand); Hermansen, John E. [Department of Agroecology, Aarhus University, Tjele (Denmark); Sagisaka, Masayuki [Institute of Science for Safety and Sustainability, National Institute of Advanced Industrial Science and Technology, Tsukuba (Japan)

    2009-11-15

    One important rationale for bio-energy systems is their potential to save fossil energy. Converting a conventional sugar mill into a bio-energy process plant would contribute to fossil energy savings via the extraction of renewable electricity and ethanol substituting for fossil electricity and gasoline, respectively. This paper takes a closer look at the Thai sugar industry and examines two practical approaches that will enhance fossil energy savings. The first one addresses an efficient extraction of energy in the form of electricity from the excess bagasse and cane trash. The second while proposing to convert molasses or sugar cane to ethanol stresses the use of bagasse as well as distillery spent wash to replace coal in meeting ethanol plants' energy needs. The savings potential achieved with extracting ethanol from surplus sugar versus current practice in sugar industry in Thailand amounts to 15 million barrels of oil a year. Whether the saving benefits could be fully realized, however, depends on how well the potential land use change resulting from an expansion of ethanol production is managed. The results presented serve as a useful guidance to formulate strategies that enable optimum utilization of biomass as an energy source. (author)

  3. Potential for energy technologies in residential and commercial buildings

    Energy Technology Data Exchange (ETDEWEB)

    Glesk, M.M.

    1979-11-01

    The residential-commercial energy technology model was developed as a planning tool for policy analysis in the residential and commercial building sectors. The model and its procedures represent a detailed approach to estimating the future acceptance of energy-using technologies both in new construction and for retrofit into existing buildings. The model organizes into an analytical framework all relevant information and data on building energy technology, building markets, and government policy, and it allows for easy identification of the relative importance of key assumptions. The outputs include estimates of the degree of penetration of the various building energy technologies, the levels of energy use savings associated with them, and their costs - both private and government. The model was designed to estimate the annual energy savings associated with new technologies compared with continued use of conventional technology at 1975 levels. The amount of energy used under 1975 technology conditions is referred to as the reference case energy use. For analytical purposes the technologies were consolidated into ten groupings: electric and gas heat pumps; conservation categories I, II, and III; solar thermal (hot water, heating, and cooling); photovoltaics, and wind systems. These groupings clearly do not allow an assessment of the potential for individual technologies, but they do allow a reasonable comparison of their roles in the R/C sector. Assumptions were made regarding the technical and economic performances of the technologies over the period of the analysis. In addition, the study assessed the non-financial characteristics of the technologies - aesthetics, maintenance complexity, reliability, etc. - that will also influence their market acceptability.

  4. Evaluation of global onshore wind energy potential and generation costs.

    Science.gov (United States)

    Zhou, Yuyu; Luckow, Patrick; Smith, Steven J; Clarke, Leon

    2012-07-17

    In this study, we develop an updated global estimate of onshore wind energy potential using reanalysis wind speed data, along with updated wind turbine technology performance, land suitability factors, cost assumptions, and explicit consideration of transmission distance in the calculation of transmission costs. We find that wind has the potential to supply a significant portion of the world energy needs, although this potential varies substantially by region and with assumptions such as on what types of land can be used to site wind farms. Total global economic wind potential under central assumptions, that is, intermediate between optimistic and pessimistic, is estimated to be approximately 119.5 petawatt hours per year (13.6 TW) at less than 9 cents/kWh. A sensitivity analysis of eight key parameters is presented. Wind potential is sensitive to a number of input parameters, particularly wind speed (varying by -70% to +450% at less than 9 cents/kWh), land suitability (by -55% to +25%), turbine density (by -60% to +80%), and cost and financing options (by -20% to +200%), many of which have important policy implications. As a result of sensitivities studied here we suggest that further research intended to inform wind supply curve development focus not purely on physical science, such as better resolved wind maps, but also on these less well-defined factors, such as land-suitability, that will also have an impact on the long-term role of wind power.

  5. Energy splitting in a finite periodic multiple-well potential

    Science.gov (United States)

    Song, Dae-Yup

    2017-09-01

    The low-lying states for a one-dimensional potential consisting of N identical wells are considered, assuming that the wells are parabolic around the minima. The N localized approximate eigenfunctions, each of which matches an eigenfunction of the simple harmonic oscillator in one of the wells, are constructed, relying on the WKB approximation. Diagonalizing the Hamiltonian in the subspace spanned by the approximate eigenfunctions, a formula for the energy eigenvalues is obtained. The present work will be useful for introducing Bloch wave functions in a periodic potential to undergraduate and graduate students. It is shown that the formula for the eigenvalues can reproduce a known rigorous expression on the Mathieu equation.

  6. Construction of molecular potential energy curves by an optimization method

    Science.gov (United States)

    Wang, J.; Blake, A. J.; McCoy, D. G.; Torop, L.

    1991-01-01

    A technique for determining the potential energy curves for diatomic molecules from measurements of diffused or continuum spectra is presented. It is based on a numerical procedure which minimizes the difference between the calculated spectra and the experimental measurements and can be used in cases where other techniques, such as the conventional RKR method, are not applicable. With the aid of suitable spectral data, the associated dipole electronic transition moments can be simultaneously obtained. The method is illustrated by modeling the "longest band" of molecular oxygen to extract the E 3Σ u- and B 3Σ u- potential curves in analytical form.

  7. Energy Perspectives In Switzerland: The Potential Of Nuclear Power

    International Nuclear Information System (INIS)

    Foskolos, K.; Hardegger, P.

    2005-01-01

    In 2004, discussions were started in Switzerland concerning future of energy supply, including domestic electricity generation. On behalf of the Federal Office of Energy, PSI undertook a study to evaluate the potential of future nuclear technologies, covering electricity demand, with a time horizon up to 2050. It has been shown that nuclear power plants (NPPs) of the Third Generation, similar to the ones currently under construction in several other countries, built on the existing nuclear sites in Switzerland, have the potential to replace, at competitive costs, the existing nuclear plants, and even to cover (postulated) increases in electricity demand. Because of their late maturity (expected at the earliest around 2030), NPPs of the Fourth Generation, which are currently under development, cannot play a major role in Switzerland, since, with the exception of the Leibstadt NPP, all decisions regarding replacement of the current Swiss NPPs have to be taken before 2030. (author)

  8. Energy Saving Potential by Utilizing Natural Ventilation under Warm Conditions

    DEFF Research Database (Denmark)

    Oropeza-Perez, Ivan; Østergaard, Poul Alberg

    2014-01-01

    –airflow simulations of 27 common cases of dwellings (considered as one thermal zone) based on the combination of specific features of the building design, occupancy and climate conditions. The energy saving potential is assessed then by the use of a new assessment method suitable for large-scale scenarios using......The objective of this article is to show the potential of natural ventilation as a passive cooling method within the residential sector of countries which are located in warm conditions using Mexico as a case study. The method is proposed as performing, with a simplified ventilation model, thermal...... the actual number of air-conditioned dwellings distributed among the 27 cases. Thereby, the energy saving is presented as the difference in the cooling demand of the dwelling during one year without and with natural ventilation, respectively. Results indicate that for hot-dry conditions, buildings with high...

  9. Energy from waste. Potentials and possibilities for usage; Energie aus Abfall. Potenziale und Nutzungsmoeglichkeiten

    Energy Technology Data Exchange (ETDEWEB)

    Wallmann, Rainer; Fritz, Thomas [Hochschule fuer Angewandte Wissenschaft und Kunst (HAWK), Goettingen (DE). Fachgebiet Nachhaltige Energie- und Umwelttechnik (NEUTec); Fricke, Klaus [Technische Univ. Braunschweig (Germany). Abt. Abfall- und Ressourcenwirtschaft

    2009-05-15

    In the present article the results of appraisal for the determination of the theoretical potential of energy and the current secondary energy supply of waste streams, which are relevant for the power production in Germany are represented. To sum up, the following conclusions arise from the balance: The theoretical primary energy supply potential of the examined waste streams amounts from 540 to 650 PJ/a and corresponds from 3.9 to 4.6% of the total primary energy consumption in Germany. In consideration of the system-dependent efficiencies and steering of flow patterns for materials altogether approx. 53 PJ electricity and 104 PJ (used) heat were produced as secondary energy within the regarded ranges in the year 2006 in Germany. This corresponds approx. to 1.7% of the final energy consumption in Germany. The outcome of the evaluated energy data for 2006 is a middle energy efficiency of approx. 26.5% (approx. 8.9% electrically and approx. 17.6% thermally). Under technically optimized conditions the power efficiency can be raised possibly on approx. 37%, whereby the share of the final energy consumption in Germany would increase to 2,3%. (orig.)

  10. Biomass energy in Jordan, and its potential contribution towards the total energy mix of the Kingdom

    International Nuclear Information System (INIS)

    Al-Dabbas, Moh'd A. F.

    1994-04-01

    An evaluation of Jordan's bio-energy status was carried out. Available sources and the viability of exploitation were studied in order to identify the size of contribution that bio-energy could provide to the total energy mix of the Kingdom. The advantages of biogas technology were discussed, and a general description of Jordan's experience in this field was presented. Data on Jordan' animal, municipal, and agricultural wastes that are available as a potential source of bio-energy was tabulated. The report ascertained the economic feasibility of biogas utilization in Jordan, and concluded that the annual energy production potential from biogas, with only animal wastes being utilized, would amount to 80,000 ton oil equivalent. This amount of energy is equivalent to 2% of Jordan's total energy consumption in 1992. The utilization of biogas from municipal wastes would produce an additional 2.5% of the total energy consumption of Jordan. The annual value of utilizing animal and municipal wastes would reach 23 million Jordanian Dinars (JD). This value would increase to 61.5 million JD with the utilization of human wastes. The investment required for the utilization of bio-energy sources in Amman and its suburbs on the scale of family unit fermenters was estimated to be in the order of a million JD. The size of investment for industrial scale utilization for power generation with an electricity feed to the national grid, would range from 3 to 4 million JD. (A.M.H.). 8 refs., 4 tabs

  11. Potential energy landscape of TIP4P/2005 water

    Science.gov (United States)

    Handle, Philip H.; Sciortino, Francesco

    2018-04-01

    We report a numerical study of the statistical properties of the potential energy landscape of TIP4P/2005, one of the most accurate rigid water models. We show that, in the region where equilibrated configurations can be generated, a Gaussian landscape description is able to properly describe the model properties. We also find that the volume dependence of the landscape properties is consistent with the existence of a locus of density maxima in the phase diagram. The landscape-based equation of state accurately reproduces the TIP4P/2005 pressure-vs-volume curves, providing a sound extrapolation of the free-energy at low T. A positive-pressure liquid-liquid critical point is predicted by the resulting free-energy.

  12. The Potential of Renewable Energy Sources in Latvia

    Science.gov (United States)

    Sakipova, S.; Jakovics, A.; Gendelis, S.

    2016-02-01

    The article discusses some aspects of the use of renewable energy sources in the climatic conditions prevailing in most of the territory of Latvia, with relatively low wind speeds and a small number of sunny days a year. The paper gives a brief description of the measurement equipment and technology to determine the parameters of the outer air; the results of the measurements are also analysed. On the basis of the data obtained during the last two years at the meteorological station at the Botanical Garden of the University of Latvia, the energy potential of solar radiation and wind was estimated. The values of the possible and the actual amount of produced energy were determined.

  13. Potential energy landscape of TIP4P/2005 water.

    Science.gov (United States)

    Handle, Philip H; Sciortino, Francesco

    2018-04-07

    We report a numerical study of the statistical properties of the potential energy landscape of TIP4P/2005, one of the most accurate rigid water models. We show that, in the region where equilibrated configurations can be generated, a Gaussian landscape description is able to properly describe the model properties. We also find that the volume dependence of the landscape properties is consistent with the existence of a locus of density maxima in the phase diagram. The landscape-based equation of state accurately reproduces the TIP4P/2005 pressure-vs-volume curves, providing a sound extrapolation of the free-energy at low T. A positive-pressure liquid-liquid critical point is predicted by the resulting free-energy.

  14. LHC Physics Potential vs. Energy: Considerations for the 2011 Run

    CERN Document Server

    Quigg, Chris

    2011-01-01

    Parton luminosities are convenient for estimating how the physics potential of Large Hadron Collider experiments depends on the energy of the proton beams. I quantify the advantage of increasing the beam energy from 3.5 TeV to 4 TeV. I present parton luminosities, ratios of parton luminosities, and contours of fixed parton luminosity for $gg$, $u\\bar{d}$, $qq$, and $gq$ interactions over the energy range relevant to the Large Hadron Collider, along with example analyses for specific processes. This note extends the analysis presented in arXiv:0908.3660. Full-size figures are available as pdf files at http://lutece.fnal.gov/PartonLum11/

  15. Covalent Dimers of 1,3-Diphenylisobenzofuran for Singlet Fission: Synthesis and Electrochemistry

    Czech Academy of Sciences Publication Activity Database

    Akdag, Akin; Wahab, Abdul; Beran, Pavel; Rulíšek, Lubomír; Dron, P. I.; Ludvík, Jiří; Michl, Josef

    2015-01-01

    Roč. 80, č. 1 (2015), s. 80-89 ISSN 0022-3263 R&D Projects: GA ČR GA13-21704S; GA ČR(CZ) GA14-31419S Institutional support: RVO:61388963 ; RVO:61388955 Keywords : singlet fission * reduction potentials * electrochemistry * theoretical calculations Subject RIV: CC - Organic Chemistry; CG - Electrochemistry (UFCH-W) Impact factor: 4.785, year: 2015

  16. CO dimer: new potential energy surface and rovibrational calculations.

    Science.gov (United States)

    Dawes, Richard; Wang, Xiao-Gang; Carrington, Tucker

    2013-08-15

    The spectrum of CO dimer was investigated by solving the rovibrational Schrödinger equation on a new potential energy surface constructed from coupled-cluster ab initio points. The Schrödinger equation was solved with a Lanczos algorithm. Several 4D (rigid monomer) global ab initio potential energy surfaces (PESs) were made using a previously reported interpolating moving least-squares (IMLS) fitting procedure specialized to describe the interaction of two linear fragments. The potential has two nonpolar minima giving rise to a complicated set of energy level stacks, which are very sensitive to the shapes and relative depths of the two wells. Although the CO dimer has defied previous attempts at an accurate purely ab initio description our best surface yields results in good agreement with experiment. Root-mean-square (rms) fitting errors of less than 0.1 cm(-1) were obtained for each of the fits using 2226 ab initio data at different levels. This allowed direct assessment of the quality of various levels of ab initio theory for prediction of spectra. Our tests indicate that standard CCSD(T) is slow to converge the interaction energy even when sextuple zeta bases as large as ACV6Z are used. The explicitly correlated CCSD(T)-F12b method was found to recover significantly more correlation energy (from singles and doubles) at the CBS limit. Correlation of the core-electrons was found to be important for this system. The best PES was obtained by extrapolation of calculations at the CCSD(T)(AE)-F12b/CVnZ-F12 (n = 3,4) levels. The calculated energy levels were compared to 105 J ≤ 10 levels from experiment. The rms error for 68 levels with J ≤ 6 is only 0.29 cm(-1). The calculated energy levels were assigned stack labels using several tools. New stacks were found. One of them, stack y1, has an energy lower than many previously known stacks and may be observable.

  17. The nature of singlet excitons in oligoacene molecular crystals

    KAUST Repository

    Yamagata, H.

    2011-01-01

    A theory for polarized absorption in crystalline oligoacenes is presented, which includes Frenkel exciton coupling, the coupling between Frenkel and charge-transfer (CT) excitons, and the coupling of all neutral and ionic excited states to the dominant ring-breathing vibrational mode. For tetracene, spectra calculated using all Frenkel couplings among the five lowest energy molecular singlet states predict a Davydov splitting (DS) of the lowest energy (0-0) vibronic band of only -32cm-1, far smaller than the measured value of 631cm-1 and of the wrong sign-a negative sign indicating that the polarizations of the lower and upper Davydov components are reversed from experiment. Inclusion of Frenkel-CT coupling dramatically improves the agreement with experiment, yielding a 0-0 DS of 601cm-1 and a nearly quantitative reproduction of the relative spectral intensities of the 0-n vibronic components. Our analysis also shows that CT mixing increases with the size of the oligoacenes. We discuss the implications of these results on exciton dissociation and transport. © 2011 American Institute of Physics.

  18. Singlet Fission and Excimer Formation in Disordered Solids of Alkyl-Substituted 1,3-Diphenylisobenzofurans.

    Science.gov (United States)

    Dron, Paul I; Michl, Josef; Johnson, Justin C

    2017-11-16

    We describe the preparation and excited state dynamics of three alkyl derivatives of 1,3-diphenylisobenzofuran (1) in both solutions and thin films. The substitutions are intended to disrupt the slip-stacked packing observed in crystals of 1 while maintaining the favorable energies of singlet and triplet for singlet fission (SF). All substitutions result in films that are largely amorphous as judged by the absence of strong X-ray diffraction peaks. The films of 1 carrying a methyl in the para position of one phenyl ring undergo SF relatively efficiently (≥75% triplet yield, Φ T ) but more slowly than thin films of 1. When the methyl is replaced with a t-butyl, kinetic competition in the excited state favors excimer formation rather than SF (Φ T = 55%). When t-Bu groups are placed in both meta positions of the phenyl substituent, SF is slowed further and Φ T = 35%.

  19. Potential energy and transition dipole moment functions of C2-

    Czech Academy of Sciences Publication Activity Database

    Šedivcová, Tereza; Špirko, Vladimír

    2006-01-01

    Roč. 104, 13/14 (2006), s. 1999-2005 ISSN 0026-8976 R&D Projects: GA AV ČR(CZ) IAA400550511; GA MŠk(CZ) LC512; GA ČR(CZ) GD203/05/H001 Institutional research plan: CEZ:AV0Z40550506 Keywords : ab initio calculation * transition moments * potential energy Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 1.690, year: 2006

  20. Electronic structure, molecular bonding and potential energy surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Ruedenberg, K. [Ames Laboratory, IA (United States)

    1993-12-01

    By virtue of the universal validity of the generalized Born-Oppenheimer separation, potential energy surfaces (PES`) represent the central conceptual as well as quantitative entities of chemical physics and provide the basis for the understanding of most physicochemical phenomena in many diverse fields. The research in this group deals with the elucidation of general properties of PES` as well as with the quantitative determination of PES` for concrete systems, in particular pertaining to reactions involving carbon, oxygen, nitrogen and hydrogen molecules.

  1. Study of the potential of energy storage - Investigation report - Synthesis

    International Nuclear Information System (INIS)

    Renaud, Arnaud; Fournie, Laurent; Girardeau, Pierre; Chammas, Maxime; Tarel, Guillaume; Chiche, Alice; De Freminville; Pierre; Lacroix, Olivier; Rakotojaona, Loic; Payen, Luc; Riu, Delphine; Kerouedan, Anne-Fleur

    2013-01-01

    The objective of this study is to assess, for France and its overseas territories, the potential of energy storage by 2030, and to identify the technological sectors which are the most economically relevant. A global surplus has been calculated, as well as the benefit from additional storage capacities. This benefit has been compared with cost predictions by 2030 for different storage technologies. Economically viable powers and types of energy storages are assessed with respect to different scenarios, and impacts in terms of associated jobs are assessed. The document reports and discusses the surplus assessment for the community, describes the various services provided by energy storage, presents the modelling scenarios and hypotheses, discusses the main results of valorisation for the community, presents the various energy storage technologies (gravity, thermodynamic, electrochemical, electrostatic, inertial, latent thermal, thermo-chemical, and power to gas), presents business models and deployment potential for different applications (mass storage of electricity in France, electricity storage in a non-connected area, decentralised electricity storage as a response to grid congestion, valorisation of an electricity storage, thermal storage on a heat network, cold storage, management of diffuse demand of hot water), and discusses implications regarding employment

  2. Bohm's quantum potential as an internal energy

    Energy Technology Data Exchange (ETDEWEB)

    Dennis, Glen, E-mail: gdennis502@gmail.com [TPRU, Birkbeck College, University of London, London, WC1E 7HX (United Kingdom); Gosson, Maurice A. de, E-mail: maurice.de.gosson@univie.ac.at [University of Vienna, Faculty of Mathematics, NuHAG, Oskar-Morgenstern-Platz 1, 1090 Vienna (Austria); Hiley, Basil J., E-mail: b.hiley@bbk.ac.uk [TPRU, Birkbeck College, University of London, London, WC1E 7HX (United Kingdom)

    2015-06-26

    Highlights: • The quantum potential is seen as internal energy associated with a phase space region. • Fermi's trick shows that Bohm's particle is an extended structure in phase space. • We associate Bohm's quantum potential with a context-dependent energy redistribution. • A physically motivated derivation of Schrodinger's equation is provided. • We show the Fermi set associated with a 3-D coherent state contains a quantum blob. - Abstract: We pursue our discussion of Fermi's surface initiated by Dennis, de Gosson and Hiley and show that Bohm's quantum potential can be viewed as an internal energy of a quantum system, giving further insight into its role in stationary states. This implies that the ‘particle’ referred to in Bohm's theory is not a classical point-like object but rather has an extended structure in phase space which can be linked to the notion of a symplectic capacity, a topological feature of the underlying symplectic geometry. This structure provides us with a new, physically motivated derivation of Schrödinger's equation provided we interpret Gleason's theorem as a derivation of the Born rule from fundamental assumptions about quantum probabilities.

  3. Electromagnetic potentials basis for energy density and power flux

    International Nuclear Information System (INIS)

    Puthoff, H E

    2016-01-01

    In rounding out the education of students in advanced courses in applied electromagnetics it is incumbent on us as mentors to raise issues that encourage appreciation of certain subtle aspects that are often overlooked during first exposure to the field. One of these has to do with the interplay between fields and potentials, with the latter often seen as just a convenient mathematical artifice useful in solving Maxwell’s equations. Nonetheless, to those practiced in application it is well understood that various alternatives in the use of fields and potentials are available within electromagnetic (EM) theory for the definitions of energy density, momentum transfer, EM stress–energy tensor, and so forth. Although the various options are all compatible with the basic equations of electrodynamics (e.g., Maxwell’s equations, Lorentz force law, gauge invariance), nonetheless certain alternative formulations lend themselves to being seen as preferable to others with regard to the transparency of their application to physical problems of interest. Here we argue for the transparency of an energy density/power flux option based on the EM potentials alone. (paper)

  4. Potential of Sugarcane in Modern Energy Development in Southern Africa

    International Nuclear Information System (INIS)

    Souza, Simone P.; Horta Nogueira, Luiz A.; Watson, Helen K.; Lynd, Lee Rybeck; Elmissiry, Mosad; Cortez, Luís A. B.

    2016-01-01

    For more than half of the Southern African population, human development is limited by a lack of access to electricity and modern energy for cooking. Modern bioenergy merits consideration as one means to address this situation in areas where sufficient arable land is available. While numerous studies have concluded that Africa has significant biomass potential, they do not indicate by how much it can effectively reduce the use of traditional biomass and provide more accessible energy, especially at a country level. Here, we evaluate the potential of sugarcane to replace traditional biomass and fossil fuel and enlarge the access to electricity in Southern Africa. By using its current molasses for ethanol production, Swaziland could increase electricity generation by 40% using bagasse and replace 60% of cooking fuel or 30% of liquid fossil fuel. Sugarcane expansion over 1% of the pasture land in Angola, Mozambique, and Zambia could replace greater than 70% of cooking fuel. Bioelectricity generation from modest sugarcane expansion could be increased by 10% in Malawi, Mozambique, and Zambia and by 20% in Angola. Our results support the potential of sugarcane as a modern energy alternative for Southern Africa.

  5. Potential of Sugarcane in Modern Energy Development in Southern Africa

    Energy Technology Data Exchange (ETDEWEB)

    Souza, Simone P., E-mail: sp.souza@yahoo.com.br; Horta Nogueira, Luiz A. [Interdisciplinary Center for Energy Planning, University of Campinas (UNICAMP), Campinas, SP (Brazil); Watson, Helen K. [School of Agricultural, Earth and Environmental Sciences, University of KwaZulu-Natal, Durban, KZN (South Africa); Lynd, Lee Rybeck [Dartmouth College, Thayer School of Engineering, Dartmouth, NH (United States); Elmissiry, Mosad [New Partnership for Africa’s Development (NEPAD), Johannesburg, GT (South Africa); Cortez, Luís A. B. [Faculty of Agricultural Engineering, University of Campinas (UNICAMP), Campinas, SP (Brazil)

    2016-12-26

    For more than half of the Southern African population, human development is limited by a lack of access to electricity and modern energy for cooking. Modern bioenergy merits consideration as one means to address this situation in areas where sufficient arable land is available. While numerous studies have concluded that Africa has significant biomass potential, they do not indicate by how much it can effectively reduce the use of traditional biomass and provide more accessible energy, especially at a country level. Here, we evaluate the potential of sugarcane to replace traditional biomass and fossil fuel and enlarge the access to electricity in Southern Africa. By using its current molasses for ethanol production, Swaziland could increase electricity generation by 40% using bagasse and replace 60% of cooking fuel or 30% of liquid fossil fuel. Sugarcane expansion over 1% of the pasture land in Angola, Mozambique, and Zambia could replace greater than 70% of cooking fuel. Bioelectricity generation from modest sugarcane expansion could be increased by 10% in Malawi, Mozambique, and Zambia and by 20% in Angola. Our results support the potential of sugarcane as a modern energy alternative for Southern Africa.

  6. Steam systems in industry: Energy use and energy efficiency improvement potentials

    International Nuclear Information System (INIS)

    Einstein, Dan; Worrell, Ernst; Khrushch, Marta

    2001-01-01

    Steam systems are a part of almost every major industrial process today. Thirty-seven percent of the fossil fuel burned in US industry is burned to produce steam. In this paper we will establish baseline energy consumption for steam systems. Based on a detailed analysis of boiler energy use we estimate current energy use in boilers in U.S. industry at 6.1 Quads (6.4 EJ), emitting almost 66 MtC in CO(sub 2) emissions. We will discuss fuels used and boiler size distribution. We also describe potential savings measures, and estimate the economic energy savings potential in U.S. industry (i.e. having payback period of 3 years or less). We estimate the nationwide economic potential, based on the evaluation of 16 individual measures in steam generation and distribution. The analysis excludes the efficient use of steam and increased heat recovery. Based on the analysis we estimate the economic potential at 18-20% of total boiler energy use, resulting in energy savings approximately 1120-1190 TBtu ( 1180-1260 PJ). This results in a reduction of CO(sub 2) emissions equivalent to 12-13 MtC

  7. Potential energy surface and rovibrational energy levels of the H2-CS van der Waals complex.

    Science.gov (United States)

    Denis-Alpizar, Otoniel; Stoecklin, Thierry; Halvick, Philippe; Dubernet, Marie-Lise; Marinakis, Sarantos

    2012-12-21

    Owing to its large dipole, astrophysicists use carbon monosulfide (CS) as a tracer of molecular gas in the interstellar medium, often in regions where H(2) is the most abundant collider. Predictions of the rovibrational energy levels of the weakly bound complex CS-H(2) (not yet observed) and also of rate coefficients for rotational transitions of CS in collision with H(2) should help to interpret the observed spectra. This paper deals with the first goal, i.e., the calculation of the rovibrational energy levels. A new four-dimensional intermolecular potential energy surface for the H(2)-CS complex is presented. Ab initio potential energy calculations were carried out at the coupled-cluster level with single and double excitations and a perturbative treatment of triple excitations, using a quadruple-zeta basis set and midbond functions. The potential energy surface was obtained by an analytic fit of the ab initio data. The equilibrium structure of the H(2)-CS complex is found to be linear with the carbon pointing toward H(2) at the intermolecular separation of 8.6 a(o). The corresponding well depth is -173 cm(-1). The potential was used to calculate the rovibrational energy levels of the para-H(2)-CS and ortho-H(2)-CS complexes. The present work provides the first theoretical predictions of these levels. The calculated dissociation energies are found to be 35.9 cm(-1) and 49.9 cm(-1), respectively, for the para and ortho complexes. The second virial coefficient for the H(2)-CS pair has also been calculated for a large range of temperature. These results could be used to assign future experimental spectra and to check the accuracy of the potential energy surface.

  8. Energy balance of chosen crops and their potential to saturate energy consumption in Slovakia

    Directory of Open Access Journals (Sweden)

    Katarína Hrčková

    2016-06-01

    Full Text Available The aim of the present work was to assess and compare energy inputs and outputs of various crop managements in 2011–2012. Two main crops on arable land and three permanent grasslands were investigated. Silage maize (Zea mays L. and winter wheat (Triticum aestivum L. were grown on lowland, whilst two semi-natural grasslands and grassland infested by tufted hair-grass (Deschampsia caespitose (L. P. Beauv were located in mountainous regions of Slovakia. In these crops and grasslands the dry matter yield was measured and subsequently the supplementary energy, energy gain and unifying energy value – tonne of oil equivalent (TOE – were calculated. Silage maize with 233.37 GJ*ha-1 has provided the highest energy gain. In the group of grasslands, grassland infested by tufted hair-grass has offered the highest energy gain (59.77 GJ*ha-1. And this grassland had the lowest requirement on the supplementary energy (3.66 GJ*ha-1, contrary to silage maize with highest one (12.37 GJ*ha-1. The total energy potential of the crop biomasses was confronted with energy consumption in Slovakia. Winter wheat has the biggest energy potential, but it could cover only 19.6% and 11.3% total consumption of electricity or natural gas, respectively. Large area of permanent grasslands and their spatial location make them an important energy reservoir for bioenergy production. But, it is not possible to replace all consumed fossil fuels by bioenergy from these tested renewable energy sources.

  9. Geophysical potential for wind energy over the open oceans.

    Science.gov (United States)

    Possner, Anna; Caldeira, Ken

    2017-10-24

    Wind turbines continuously remove kinetic energy from the lower troposphere, thereby reducing the wind speed near hub height. The rate of electricity generation in large wind farms containing multiple wind arrays is, therefore, constrained by the rate of kinetic energy replenishment from the atmosphere above. In recent years, a growing body of research argues that the rate of generated power is limited to around 1.5 W m -2 within large wind farms. However, in this study, we show that considerably higher power generation rates may be sustainable over some open ocean areas. In particular, the North Atlantic is identified as a region where the downward transport of kinetic energy may sustain extraction rates of 6 W m -2 and above over large areas in the annual mean. Furthermore, our results indicate that the surface heat flux from the oceans to the atmosphere may play an important role in creating regions where sustained high rates of downward transport of kinetic energy and thus, high rates of kinetic energy extraction may be geophysical possible. While no commercial-scale deep water wind farms yet exist, our results suggest that such technologies, if they became technically and economically feasible, could potentially provide civilization-scale power.

  10. GIS Assessment of Wind Energy Potential in California and Florida

    Science.gov (United States)

    Snow, R. K.; Snow, M. M.

    2008-05-01

    Energy efficiency coupled with renewable energy technologies can provide most of the U.S. carbon emissions reductions needed to contain atmospheric carbon concentrations at 450-500 parts per million, considered by many to be a tipping point in mitigating climate change. Among the leaders in the alternative energy sector is wind power, which is now one of the largest sources of new power generation in the U.S. creating jobs and revenue for rural communities while powering our economy with an emissions-free source of energy. In 2006, wind turbines capable of generating more than 2,400 megawatts of electricity were installed in the U.S. and by 2007 this number had risen to 3,000 megawatts. The U.S. generated 31 billion kilowatt-hours of wind power in 2007, which is enough electricity to power the equivalent of nearly 3 million average homes. It is estimated that generating the same amount of electricity would require burning 16 million tons of coal or 50 million barrels of oil. This study examines the wind power potential of sites near populated areas in Florida and California to determine the practicability of installing wind turbines at these locations. A GIS was developed in order to conduct a spatial analysis of these sites based on mean annual wind speed measured in meters per second and wind power density ratings measured in watts per square meter. The analysis indicates that coastal areas of Cocoa Beach, Key West, Hollywood, and West Palm Beach, respectively, possess the greatest potential for wind energy in Florida with mean annual wind speeds of 4.9 m/s and average wind power density ratings of 171 w/m2 peaking at Cocoa Beach followed by wind speeds of 4.64 m/s and wind power ratings of 115 w/m2 at Key West. California wind energy potential is even greater than that of Florida with Fairfield exhibiting mean annual wind speeds of 5.9 m/s and average wind power density ratings of 327 w/m2 followed by the Mojave and Palmdale areas with mean annual wind speeds of

  11. SHORT COMMUNICATION SINGLET-TRIPLET GAP STUDIES ON ...

    African Journals Online (AJOL)

    Preferred Customer

    2009-02-10

    yahoo.com. SHORT COMMUNICATION. SINGLET-TRIPLET GAP STUDIES ON ARYL-CYCLOPENTADIENYLIDENES: INDIRECT ELECTRONIC EFFECTS. E. Vessally*. Payame Noor University (PNU), Zanjan, Iran. (Received February 10, 2009; ...

  12. Exploring the potential uptake of distributed energy generation

    International Nuclear Information System (INIS)

    Gardner, John; Ashworth, Peta; Carr-Cornish, Simone

    2007-01-01

    Full text: Global warming has been identified as an energy problem (Klare 2007). With a predicted increase in fossil fuel use for many years to come (IEA 2004) there is a need to find a future energy path that will meet our basic requirements for energy but also help to mitigate climate change (CSIRO 2006). Currently there are a range of technological solutions available, with each representing a different value proposition. Distributed Energy (DE) is one such technological solution, which involves the widespread use of small local power generators, located close to the end user. Such generators can be powered by a range of low emission and/or renewable sources. Until now, cheap electricity, existing infrastructure and reluctance for change both at a political and individual level has meant there has been little prospect for DE to be considered in Australia, except in some remote communities. However, with the majority of Australians now rating climate change as an issue of strategic importance to Australia (Ashworth, Pisarski and Littleboy 2006), it can be inferred that Australia's tolerance for generating greenhouse gas emissions has reduced, and that potential support for DE is increasing. It is therefore important to understand what factors might influence the potential adoption of DE. As part of a research project called the Intelligent Grid, CSIRO's Energy Transformed Flagship is aiming to identify the conditions under which Distributed Energy might be effectively implemented in Australia. One component of this project involves social research, which aims to understand the drivers and barriers to the uptake of DE technology by the community. This paper presents findings from two large-scale surveys (one of householders and one of businesses), designed to assess beliefs and knowledge about environmental issues, and about traditional and renewable energy sources. The surveys also assess current energy use, and identify preferences regarding DE technology. The

  13. Nuclear momentum distribution and potential energy surface in hexagonal ice

    Science.gov (United States)

    Lin, Lin; Morrone, Joseph; Car, Roberto; Parrinello, Michele

    2011-03-01

    The proton momentum distribution in ice Ih has been recently measured by deep inelastic neutron scattering and calculated from open path integral Car-Parrinello simulation. Here we report a detailed investigation of the relation between momentum distribution and potential energy surface based on both experiment and simulation results. The potential experienced by the proton is largely harmonic and characterized by 3 principal frequencies, which can be associated to weighted averages of phonon frequencies via lattice dynamics calculations. This approach also allows us to examine the importance of quantum effects on the dynamics of the oxygen nuclei close to the melting temperature. Finally we quantify the anharmonicity that is present in the potential acting on the protons. This work is supported by NSF and by DOE.

  14. Singlet oxygen-mediated protein oxidation

    DEFF Research Database (Denmark)

    Wright, Adam; Bubb, William A; Hawkins, Clare Louise

    2002-01-01

    Singlet oxygen (1O2) is generated by a number of enzymes as well as by UV or visible light in the presence of a sensitizer and has been proposed as a damaging agent in a number of pathologies including cataract, sunburn, and skin cancers. Proteins, and Cys, Met, Trp, Tyr and His side chains...... methods. The yield of these species is significantly enhanced in D2O and decreased by azide. Nuclear magnetic resonance and mass spectroscopic analysis of reaction mixtures, or materials separated by high-performance liquid chromatography, are consistent with the initial formation of an (undetected......-hydroxy-6-oxo-2,3,3a,6,7,7a-hexahydro-1H-indole-2-carboxylic acid. Hydroperoxides that lack a free alpha-amino group (e.g. those formed on 3-(4-hydroxyphenyl)propionic acid, N-Ac-Tyr and Tyr-containing peptides) are longer-lived, with half-lives of hours to days. These species undergo slow decay at low...

  15. Flavor-singlet hidden charm pentaquark

    Science.gov (United States)

    Irie, Yoya; Oka, Makoto; Yasui, Shigehiro

    2018-02-01

    One type of hidden charm pentaquark Pc s with quark content c c ¯u d s in light-flavor singlet state is studied in the quark model. This state is analogous to the Pc with c c ¯u u d in light-flavor octet, which was observed in LHC in 2015. Considering various combinations of color, spin, and light flavor as internal quantum numbers in Pc s, we investigate the mass ordering of the Pc s's by adopting both the one-gluon exchange interaction and the instanton-induced interaction in the quark model. The most stable configuration of Pc s is identified to be total spin 1 /2 in which the c c ¯ is combined to be color octet and spin 1, while the u d s cluster is in a color octet state. The other color octet configurations, the total spin 1 /2 state with the c c ¯ spin 0, and the state with total spin 3 /2 and c c ¯ spin 1, are found as excited states. We also discuss possible decay modes of these hidden charm pentaquarks.

  16. Singlet-oxygen therapy. Scientific and methodological materials

    OpenAIRE

    Chukhraiev, N.; Chukhraieva, E.; Gun'ko, M.; Kurik, L.; Lomeiko, S.; Marushko, Y.; Samosyuk, N.; Tkalina, A.; Vladimirov, A.; Unichenko, A.; Zavorotnaya, R.; Zukow, W.

    2018-01-01

    Radomska Szkoła Wyższa w Radomiu MEDICAL INNOVATIVE TECHNOLOGIES SINGLET-OXYGEN THERAPY Scientific and methodological materials 2018 This edition had extended and translated from ukrainian Edited by Chukhraiev N., Vladimirov A., Zukow W. Radom, Kyiv Radomska Szkoła Wyższa w Radomiu MEDICAL INNOVATIVE TECHNOLOGIES SINGLET-OXYGEN THERAPY Scientific and methodological materials 2018 This edition had extended and translated from ukrainian Edited by ...

  17. Multiple scattering of low energy ions in matter: Influence of energy loss and interaction potential

    Energy Technology Data Exchange (ETDEWEB)

    Mekhtiche, A. [Laboratoire SNIRM, Faculté de Physique, Université des Sciences et de la Technologie Houari Boumediene (USTHB), BP 32 El Alia, Bab Ezzouar, Algiers (Algeria); Faculté des Sciences et de la Technologie, Université Yahia Farès de Médéa (Algeria); Khalal-Kouache, K., E-mail: kkouache@yahoo.fr [Laboratoire SNIRM, Faculté de Physique, Université des Sciences et de la Technologie Houari Boumediene (USTHB), BP 32 El Alia, Bab Ezzouar, Algiers (Algeria)

    2015-07-01

    In this paper, the effect of inelastic energy loss and interaction potential on transmitted ions at low energy is studied. For this purpose, angular distributions of slow He{sup +} ions transmitted through thin Ag films are calculated using the theory of multiple scattering. Thin films (20–50 Å at 2 keV and 50–200 Å at 10 keV) are considered so that the total path length of transmitted ions can be approximated by the value of the target thickness in this calculation. The corresponding values of the relative energy loss ΔE/E are comprised between 0.04 and 0.17. We show that even if low values of the thickness are considered, the total energy loss of ions in the target should be included in the calculation. These calculated angular distributions are also influenced by the potential used to describe the interaction between the incident ion and the target atom.

  18. Onshore wind energy potential over Iberia: present and future projections

    Science.gov (United States)

    Rochinha, Carlos A.; Santos, João A.; Liberato, Margarida L. R.; Pinto, Joaquim G.

    2014-05-01

    Onshore grid-connected wind power generation has been explored for more than three decades in the Iberian Peninsula. Further, increasing attention has been devoted to renewable energy sources in a climate change context. While advantages of wind energy are widely recognized, its distribution is not spatially homogeneous and not uniform throughout the year. Hence, understanding these spatial-temporal distributions is critical in power system planning. The present study aims at assessing the potential power output estimated from 10 m wind components simulated by a regional climate model (CCLM), driven by ERA40 reanalysis. Datasets are available on a grid with a high spatial resolution (approximately 20 km) and over a 40-yr period (1961-2000). Furthermore, several target sites, located in areas with high installed wind generation capacity, are selected for local-to-regional scale assessments. The results show that potential wind power is higher over northern Iberia, mostly in Cantabria and Galicia, while Andalucía and Cataluña record the lowest values. With respect to the intra-annual variability, summer is by far the season with the lowest potential energy outputs. Furthermore, the inter-annual variability reveals an overall downward long-term trend over the 40-yr period, particularly in the winter time series. A CCLM transient experiment, forced by the SRES A1B emission scenario, is also discussed for a future period (2041-2070), after a model validation/calibration process (bias corrections). Significant changes in the wind power potential are projected for the future throughout Iberia, but their magnitude largely depends on the locations. This work was partially supported by FEDER (Fundo Europeu de Desenvolvimento Regional) funds through the COMPETE (Programa Operacional Factores de Competitividade) and by national funds through FCT (Fundação para a Ciência e a Tecnologia, Portugal) under project STORMEx FCOMP-01-0124-FEDER- 019524 (PTDC/AAC-CLI/121339/2010).

  19. Singlet oxygen: photosensitized generation, detection and reaction with organic molecules

    International Nuclear Information System (INIS)

    Barik, Atanu; Indira Priyadarsini, K.; Hari Mohan; Bajaj, P.N.; Sapre, A.V.; Mittal, J.P.; Mukherjee, T.

    2006-10-01

    Singlet molecular oxygen ( 1 O 2 ) is an excited state of molecular oxygen, having antiparallel spin in the same π antibonding orbital. The study of singlet oxygen production and reactivity has emerged as a rich and diverse area, with implication in diverse fields, such as synthetic chemistry, polymer chemistry, photodynamic therapy, etc. There are several known methods to produce singlet oxygen, and also various techniques employed to detect it. Out of these, photosensitization method is the most popular one. In this article, photosensitized production of singlet oxygen from triplet oxygen and photosensitizers in presence of light, and its detection by the infrared luminescence at 1270 nm have been presented. Further, some results using different types of photosensitizers, effect of solvent on singlet oxygen quantum yields and lifetime have been discussed. The quenching rate constants of singlet oxygen have been determined with different types of organic molecules such as derivatives of thiourea and its analogues, hydroxy indoles and antioxidants and the results have been presented. (author)

  20. Simulations of Cold Electroweak Baryogenesis: quench from portal coupling to new singlet field

    Science.gov (United States)

    Mou, Zong-Gang; Saffin, Paul M.; Tranberg, Anders

    2018-01-01

    We compute the baryon asymmetry generated from Cold Electroweak Baryogenesis, when a dynamical Beyond-the-Standard-Model scalar singlet field triggers the spinodal transition. Using a simple potential for this additional field, we match the speed of the quench to earlier simulations with a "by-hand" mass flip. We find that for the parameter subspace most similar to a by-hand transition, the final baryon asymmetry shows a similar dependence on quench time and is of the same magnitude. For more general parameter choices the Higgs-singlet dynamics can be very complicated, resulting in an enhancement of the final baryon asymmetry. Our results validate and generalise results of simulations in the literature and open up the Cold Electroweak Baryogenesis scenario to further model building.

  1. Intermolecular potential energy surface and thermophysical properties of ethylene oxide

    International Nuclear Information System (INIS)

    Crusius, Johann-Philipp; Hassel, Egon; Hellmann, Robert; Bich, Eckard

    2014-01-01

    A six-dimensional potential energy hypersurface (PES) for two interacting rigid ethylene oxide (C 2 H 4 O) molecules was determined from high-level quantum-chemical ab initio calculations. The counterpoise-corrected supermolecular approach at the MP2 and CCSD(T) levels of theory was utilized to determine interaction energies for 10178 configurations of two molecules. An analytical site-site potential function with 19 sites per ethylene oxide molecule was fitted to the interaction energies and fine tuned to agree with data for the second acoustic virial coefficient from accurate speed of sound measurements. The PES was validated by computing the second virial coefficient, shear viscosity, and thermal conductivity. The values of these properties are substantiated by the best experimental data as they tend to fall within the uncertainty intervals and also obey the experimental temperature functions, except for viscosity, where experimental data are insufficient. Due to the lack of reliable data, especially for the transport properties, our calculated values are currently the most accurate estimates for these properties of ethylene oxide

  2. Intermolecular potential energy surface and thermophysical properties of ethylene oxide

    Energy Technology Data Exchange (ETDEWEB)

    Crusius, Johann-Philipp, E-mail: johann-philipp.crusius@uni-rostock.de; Hassel, Egon [Lehrstuhl für Technische Thermodynamik, Universität Rostock, 18059 Rostock (Germany); Hellmann, Robert; Bich, Eckard [Institut für Chemie, Universität Rostock, 18059 Rostock (Germany)

    2014-10-28

    A six-dimensional potential energy hypersurface (PES) for two interacting rigid ethylene oxide (C{sub 2}H{sub 4}O) molecules was determined from high-level quantum-chemical ab initio calculations. The counterpoise-corrected supermolecular approach at the MP2 and CCSD(T) levels of theory was utilized to determine interaction energies for 10178 configurations of two molecules. An analytical site-site potential function with 19 sites per ethylene oxide molecule was fitted to the interaction energies and fine tuned to agree with data for the second acoustic virial coefficient from accurate speed of sound measurements. The PES was validated by computing the second virial coefficient, shear viscosity, and thermal conductivity. The values of these properties are substantiated by the best experimental data as they tend to fall within the uncertainty intervals and also obey the experimental temperature functions, except for viscosity, where experimental data are insufficient. Due to the lack of reliable data, especially for the transport properties, our calculated values are currently the most accurate estimates for these properties of ethylene oxide.

  3. Potential for energy conservation in the cement industry

    Energy Technology Data Exchange (ETDEWEB)

    Garrett-Price, B.A.

    1985-02-01

    This report assesses the potential for energy conservation in the cement industry. Energy consumption per ton of cement decreased 20% between 1972 and 1982. During this same period, the cement industry became heavily dependent on coal and coke as its primary fuel source. Although the energy consumed per ton of cement has declined markedly in the past ten years, the industry still uses more than three and a half times the fuel that is theoretically required to produce a ton of clinker. Improving kiln thermal efficiency offers the greatest opportunity for saving fuel. Improving the efficiency of finish grinding offers the greatest potential for reducing electricity use. Technologies are currently available to the cement industry to reduce its average fuel consumption per ton by product by as much as 40% and its electricity consumption per ton by about 10%. The major impediment to adopting these technologies is the cement industry's lack of capital as a result of low or no profits in recent years.

  4. Economic aspects and potentials of renewable energy sources in Germany

    International Nuclear Information System (INIS)

    Mannsbart, W.; Reichert, J.

    1992-01-01

    While there is a high theoretical potential for renewable energy sources in Germany, assessing theoretical potentials is more or less like playing with numbers; severe technical shortcomings and economic factors prevent then from being fully achieved. Unsuitable azimuth and slope of roofs, shading, absence of central hot water systems limit the application of collectors. The present storage technology is not suitable for a solar share higher than 50%. Individual space heating is not feasible under local climatic conditions. The broad application of biomass fuels fails because of limited resources. Feeding high amounts of fluctuating electricity generated by wind and photovoltaic systems into utility grids causes stability and storage problems. Insufficient training of installation personnel, lack of incentives for multi-family housing owners and high investment costs hinder the market penetration of renewable energy sources. Drastic cost reductions can only be expected from mass production. Therefore, appropriate policy measures - raised energy prices, as well as, subsidies or tax reliefs are necessary for market breakthrough

  5. Understanding usage patterns of electric kettle and energy saving potential

    International Nuclear Information System (INIS)

    Murray, D.M.; Liao, J.; Stankovic, L.; Stankovic, V.

    2016-01-01

    Highlights: • Time-of-use analysis to motivate kettle usage and consumption prediction. • Identification of households whose kettle usage and consumption is outside the norm. • Mathematical model to estimate water volume from consumed power measurements only. • Quantification of energy savings if a household uses its kettle more efficiently. • Kettle usage and demand prediction using an Adaptive Neuro Fuzzy Inference System. - Abstract: The availability of smart metering and smart appliances enables detecting and characterising appliance use in a household, quantifying energy savings through efficient appliance use and predicting appliance-specific demand from load measurements is possible. With growing electric kettle ownership and usage, lack of any efficiency labelling guidelines for the kettle, slow technological progress in improving kettle efficiency relative to other domestic appliances, and current consumer attitudes, urgent investigation into consumer kettle usage patterns is warranted. From an efficiency point of view, little can be done about the kettle, which is more efficient than other methods of heating water such as the stove top kettle. However, since a majority households use the kettle inefficiently by overfilling, in order to meet energy targets, it is imperative to quantify inefficient usage and predict demand. For the purposes of scalability, we propose tools that depend only on load measurement data for quantifying and visualising kettle usage and energy consumption, assessing energy wastage through overfilling via our proposed electric kettle model, and predicting kettle-specific demand, from which we can estimate potential energy savings in a household and across a housing stock. This is demonstrated using data from a longitudinal study across a sample of 14 UK households for a two-year period.

  6. Fossil energy savings potential of sugar cane bio-energy systems

    DEFF Research Database (Denmark)

    Nguyen, Thu Lan T; Hermansen, John Erik; Sagisaka, Masayuki

    2009-01-01

    and gasoline, respectively. This paper takes a closer look at the Thai sugar industry and examines two practical approaches that will enhance fossil energy savings. The first one addresses an efficient extraction of energy in the form of electricity from the excess bagasse and cane trash. The second while...... proposing to convert molasses or sugar cane to ethanol stresses the use of bagasse as well as distillery spent wash to replace coal in meeting ethanol plants' energy needs. The savings potential achieved with extracting ethanol from surplus sugar versus current practice in sugar industry in Thailand amounts...

  7. Energy strategy and mitigation potential in energy sector of the Russian federation

    Energy Technology Data Exchange (ETDEWEB)

    Yakovlev, A.F.; Petrov, V.N.; Chupyatov, V.P.

    1996-12-31

    This paper describes the mitigation potential in the Russian energy sector and presents CO{sub 2} - emission scenarios. Based on the Russian energy strategy, energy conservation potential has been estimated and three groups of energy conservation measures have been pointed out. Taking into account the economic development scenarios and the scenarios of energy consumption and energy conservation, future CO{sub 2} emission scenarios for 2000 and 2010 have been prepared. Some important characteristics of these scenarios have been presented and discussed. For the period 2000-2010 annual growth rates for CO{sub 2} emission in the Russian energy sector will not exceed 0.9-1.3 %, and emission levels in 2000 make up - 75-78 %, and in 2010 - 81-88 % of the 1990 level. For the probable scenario the CO{sub 2} emission reducing will make up about 6% and 25% (for the optimistic scenario about 16% and 31%) of CO{sub 2} emission for reference scenario in 2000 and 2010 respectively. Additional CO{sub 2} emission reducing (3-5% of domestic CO{sub 2} emission) will result from increasing share of natural gas consumption.

  8. Assessment of Global Wind Energy Resource Utilization Potential

    Science.gov (United States)

    Ma, M.; He, B.; Guan, Y.; Zhang, H.; Song, S.

    2017-09-01

    Development of wind energy resource (WER) is a key to deal with climate change and energy structure adjustment. A crucial issue is to obtain the distribution and variability of WER, and mine the suitable location to exploit it. In this paper, a multicriteria evaluation (MCE) model is constructed by integrating resource richness and stability, utilization value and trend of resource, natural environment with weights. The global resource richness is assessed through wind power density (WPD) and multi-level wind speed. The utilizable value of resource is assessed by the frequency of effective wind. The resource stability is assessed by the coefficient of variation of WPD and the frequency of prevailing wind direction. Regression slope of long time series WPD is used to assess the trend of WER. All of the resource evaluation indicators are derived from the atmospheric reanalysis data ERA-Interim with spatial resolution 0.125°. The natural environment factors mainly refer to slope and land-use suitability, which are derived from multi-resolution terrain elevation data 2010 (GMTED 2010) and GlobalCover2009. Besides, the global WER utilization potential map is produced, which shows most high potential regions are located in north of Africa. Additionally, by verifying that 22.22 % and 48.8 9% operational wind farms fall on medium-high and high potential regions respectively, the result can provide a basis for the macroscopic siting of wind farm.

  9. Potential impacts of nanotechnology on energy transmission applications and needs.

    Energy Technology Data Exchange (ETDEWEB)

    Elcock, D.; Environmental Science Division

    2007-11-30

    The application of nanotechnologies to energy transmission has the potential to significantly impact both the deployed transmission technologies and the need for additional development. This could be a factor in assessing environmental impacts of right-of-way (ROW) development and use. For example, some nanotechnology applications may produce materials (e.g., cables) that are much stronger per unit volume than existing materials, enabling reduced footprints for construction and maintenance of electricity transmission lines. Other applications, such as more efficient lighting, lighter-weight materials for vehicle construction, and smaller batteries having greater storage capacities may reduce the need for long-distance transport of energy, and possibly reduce the need for extensive future ROW development and many attendant environmental impacts. This report introduces the field of nanotechnology, describes some of the ways in which processes and products developed with or incorporating nanomaterials differ from traditional processes and products, and identifies some examples of how nanotechnology may be used to reduce potential ROW impacts. Potential environmental, safety, and health impacts are also discussed.

  10. Potential environmental effects of energy conservation measures in northwest industries

    Energy Technology Data Exchange (ETDEWEB)

    Baechler, M C; Gygi, K F; Hendrickson, P L

    1992-01-01

    The Bonneville Power Administration (Bonneville) has identified 101 plants in the Pacific Northwest that account for 80% of the region's industrial electricity consumption. These plants offer a precise target for a conservation program. PNL determined that most of these 101 plants were represented by 11 major industries. We then reviewed 36 major conservation technologies used in these 11 industrial settings to determine their potential environmental impacts. Energy efficiency technologies designed for industrial use may result in direct or indirect environmental impacts. Effects may result from the production of the conservation measure technology, changes in the working environment due to different energy and material requirements, or changes to waste streams. Industry type, work-place conditions, worker training, and environmental conditions inside and outside the plant are all key variables that may affect environmental outcomes. To address these issues this report has three objectives: Describe potential conservation measures that Bonneville may employ in industrial programs and discuss potential primary impacts. Characterize industrial systems and processes where the measure may be employed and describe general environmental issues associated with each industry type. Review environmental permitting, licensing, and other regulatory actions required for industries and summarize the type of information available from these sources for further analysis.

  11. Theoretical studies of potential energy surfaces and computational methods

    Energy Technology Data Exchange (ETDEWEB)

    Shepard, R. [Argonne National Laboratory, IL (United States)

    1993-12-01

    This project involves the development, implementation, and application of theoretical methods for the calculation and characterization of potential energy surfaces involving molecular species that occur in hydrocarbon combustion. These potential energy surfaces require an accurate and balanced treatment of reactants, intermediates, and products. This difficult challenge is met with general multiconfiguration self-consistent-field (MCSCF) and multireference single- and double-excitation configuration interaction (MRSDCI) methods. In contrast to the more common single-reference electronic structure methods, this approach is capable of describing accurately molecular systems that are highly distorted away from their equilibrium geometries, including reactant, fragment, and transition-state geometries, and of describing regions of the potential surface that are associated with electronic wave functions of widely varying nature. The MCSCF reference wave functions are designed to be sufficiently flexible to describe qualitatively the changes in the electronic structure over the broad range of geometries of interest. The necessary mixing of ionic, covalent, and Rydberg contributions, along with the appropriate treatment of the different electron-spin components (e.g. closed shell, high-spin open-shell, low-spin open shell, radical, diradical, etc.) of the wave functions, are treated correctly at this level. Further treatment of electron correlation effects is included using large scale multireference CI wave functions, particularly including the single and double excitations relative to the MCSCF reference space. This leads to the most flexible and accurate large-scale MRSDCI wave functions that have been used to date in global PES studies.

  12. Stabilized quasi-Newton optimization of noisy potential energy surfaces

    International Nuclear Information System (INIS)

    Schaefer, Bastian; Goedecker, Stefan; Alireza Ghasemi, S.; Roy, Shantanu

    2015-01-01

    Optimizations of atomic positions belong to the most commonly performed tasks in electronic structure calculations. Many simulations like global minimum searches or characterizations of chemical reactions require performing hundreds or thousands of minimizations or saddle computations. To automatize these tasks, optimization algorithms must not only be efficient but also very reliable. Unfortunately, computational noise in forces and energies is inherent to electronic structure codes. This computational noise poses a severe problem to the stability of efficient optimization methods like the limited-memory Broyden–Fletcher–Goldfarb–Shanno algorithm. We here present a technique that allows obtaining significant curvature information of noisy potential energy surfaces. We use this technique to construct both, a stabilized quasi-Newton minimization method and a stabilized quasi-Newton saddle finding approach. We demonstrate with the help of benchmarks that both the minimizer and the saddle finding approach are superior to comparable existing methods

  13. Economic potential of renewable energy in Vietnam's power sector

    International Nuclear Information System (INIS)

    Nguyen, Nhan T.; Ha-Duong, Minh

    2009-01-01

    A bottom-up Integrated Resource Planning model is used to examine the economic potential of renewable energy in Vietnam's power sector. In a baseline scenario without renewables, coal provides 44% of electricity generated from 2010 to 2030. The use of renewables could reduce that figure to 39%, as well as decrease the sector's cumulative emission of CO 2 by 8%, SO 2 by 3%, and NO x by 4%. In addition, renewables could avoid installing 4.4 GW in fossil fuel generating capacity, conserve domestic coal, decrease coal and gases imports, improving energy independence and security. Wind could become cost-competitive assuming high but plausible on fossil fuel prices, if the cost of the technology falls to 900 US$/kW. (author)

  14. Energy expenditure estimates during school physical education: Potential vs. reality?

    Science.gov (United States)

    Kahan, David; McKenzie, Thomas L

    2017-02-01

    Schools are salient locations for addressing the high prevalence of overweight and obesity. Most US states require some physical education (PE) and the energy expended during PE has potential to positively affect energy balance. We previously used 2012 data to examine state policies for PE to calculate estimated student energy expenditure (EEE) under potential (i.e., recommendations followed) and existing conditions. Since then, data have been updated on both state policies and the conduct of PE. Based on updated data, we used PE frequency, duration, and intensity, student mass, and class size to calculate EEE for the delivery of PE under (a) national professional recommendations, (b) 2016 state policies, and (c) school-reported conditions. Although increased from four years ago, only 22 states currently have policies mandating specific PE minutes. EEE over 10years shows the enormous impact PE could have on energy balance. For the average recommended-size PE class, resultant annual EEE based on professional recommendations for min/week far exceeded those based on average state (n=22) policy for min/week by 44.5% for elementary, 62.7% for middle, and 59.5% for high schools. Since 2012 more states adopted policies for PE minutes than dropped them, however, EEE over 10years showed a net loss of 1200kcal/student. With no overall recent improvements in state PE policy and professional recommendations currently not being met, PE remains an underutilized public health resource for EEE. Strong policies, coupled with enhanced accountability of PE teachers and administrators, are needed to ensure PE exists in schools. Copyright © 2016 Elsevier Inc. All rights reserved.

  15. To the Problem of the Clay Particles Energy Potential Assessment

    Directory of Open Access Journals (Sweden)

    V. V. Seredin

    2017-12-01

    Full Text Available Clay is a natural material, which surface of the particles is energetically active. This clay property is widely used in the industry as sorbents. However, clay sorption activity is different for various pollutants, and work aimed to increase their sorption activity is still under way. This work objective was to study the pressure influences on the activity of the clay particles surface. The experiments showed that increase of pressure results in the decrease in the content of clay minerals, while other minerals change in different manner. It has been statistically proved that pressures P = 125 MPa and P = 750 MPa are bounding values that allows identifying the three classes. The first class is related to the pressures under 125 MPa, the second comprises the range from 125 MPa to 750 MPa, and the third class is for the pressures above 750 MPa. In each class, the intensity and direction of the proceeding of processes of mineral clay composition alteration have specific features. Based on theoretical and experimental studies it was established that the less the value of indicator Mk, the higher the energy potential of the particle surface. It achieves the maximum values (Mk = 14.7 in montmorillonite clay under pressure of 125 MPa, and, conversely, with an increase in pressure up to 2200 MPa the Mk value decreases (Mk = 17.7. A different behavior was observed in kaolinite clay. The energy potential on the particle surface increases with an increase in pressure from Mk = 26.3 to Mk = 18.8 (P = 2000 MPa. Mathematical models, which make it possible to predict energy potential on the surface of montmorillonite and kaolinite particles depending on the pressure, have been developed based on the found statistical relations

  16. Field-dependent molecular ionization and excitation energies: Implications for electrically insulating liquids

    Directory of Open Access Journals (Sweden)

    N. Davari

    2014-03-01

    Full Text Available The molecular ionization potential has a relatively strong electric-field dependence as compared to the excitation energies which has implications for electrical insulation since the excited states work as an energy sink emitting light in the UV/VIS region. At some threshold field, all the excited states of the molecule have vanished and the molecule is a two-state system with the ground state and the ionized state, which has been hypothesized as a possible origin of different streamer propagation modes. Constrained density-functional theory is used to calculate the field-dependent ionization potential of different types of molecules relevant for electrically insulating liquids. The low singlet-singlet excitation energies of each molecule have also been calculated using time-dependent density functional theory. It is shown that low-energy singlet-singlet excitation of the type n → π* (lone pair to unoccupied π* orbital has the ability to survive at higher fields. This type of excitation can for example be found in esters, diketones and many color dyes. For alkanes (as for example n-tridecane and cyclohexane on the other hand, all the excited states, in particular the σ → σ* excitations vanish in electric fields higher than 10 MV/cm. Further implications for the design of electrically insulating dielectric liquids based on the molecular ionization potential and excitation energies are discussed.

  17. TRIAD AND MODUS MODEL REALIZATION OF POTENTIAL ENERGY AND RESOURCE SAVINGS ON THE ENTERPRISES

    Directory of Open Access Journals (Sweden)

    Maryna Klimchuk

    2017-03-01

    Full Text Available The article studied categories of the resource, energy and potential energy savings that resulted in the development of triad and modus model of potential energy and resource savings enterprises based on the concept of “environmental economics”. To assess the level of energy efficiency in the company it is proposed to use a definition of “potential of energy and resource savings” which is interpreted as a synergistic approach to improve energy conservation reserves through intensification of production based on the rationalization of the use of all resources. Keywords: potential of energy savings, renewable energy, energy efficiency, environmental economics, energy resource.

  18. Bandwidth Study on Energy Use and Potential Energy Saving Opportunities in U.S. Iron and Steel Manufacturing

    Energy Technology Data Exchange (ETDEWEB)

    Keith Jamison, Caroline Kramer, Sabine Brueske, Aaron Fisher

    2015-06-01

    Energy bandwidth studies of U.S. manufacturing sectors can serve as foundational references in framing the range (or bandwidth) of potential energy savings opportunities. This bandwidth study examines energy consumption and potential energy savings opportunities in U.S. iron and steel manufacturing. The study relies on multiple sources to estimate the energy used in six individual process areas and select subareas, representing 82% of sector-wide energy consumption. Energy savings opportunities for individual processes and subareas are based on technologies currently in use or under development; the potential savings are then extrapolated to estimate sector-wide energy savings opportunity.

  19. Bandwidth Study on Energy Use and Potential Energy Saving Opportunities in U.S. Pulp and Paper Manufacturing

    Energy Technology Data Exchange (ETDEWEB)

    Sabine Brueske, Caroline Kramer, Aaron Fisher

    2015-06-01

    Energy bandwidth studies of U.S. manufacturing sectors can serve as foundational references in framing the range (or bandwidth) of potential energy savings opportunities. This bandwidth study examines energy consumption and potential energy savings opportunities in U.S. pulp and paper manufacturing. The study relies on multiple sources to estimate the energy used in six individual process areas, representing 52% of sector-wide energy consumption. Energy savings opportunities for individual processes are based on technologies currently in use or under development; the potential savings are then extrapolated to estimate sector-wide energy savings opportunity

  20. Singlet extensions of the standard model at LHC Run 2: benchmarks and comparison with the NMSSM

    Energy Technology Data Exchange (ETDEWEB)

    Costa, Raul [Centro de Física Teórica e Computacional, Faculdade de Ciências,Universidade de Lisboa, Campo Grande, Edifício C8 1749-016 Lisboa (Portugal); Departamento de Física da Universidade de Aveiro,Campus de Santiago, 3810-183 Aveiro (Portugal); Mühlleitner, Margarete [Institute for Theoretical Physics, Karlsruhe Institute of Technology,76128 Karlsruhe (Germany); Sampaio, Marco O.P. [Departamento de Física da Universidade de Aveiro,Campus de Santiago, 3810-183 Aveiro (Portugal); CIDMA - Center for Research Development in Mathematics and Applications,Campus de Santiago, 3810-183 Aveiro (Portugal); Santos, Rui [Centro de Física Teórica e Computacional, Faculdade de Ciências,Universidade de Lisboa, Campo Grande, Edifício C8 1749-016 Lisboa (Portugal); ISEL - Instituto Superior de Engenharia de Lisboa,Instituto Politécnico de Lisboa, 1959-007 Lisboa (Portugal)

    2016-06-07

    The Complex singlet extension of the Standard Model (CxSM) is the simplest extension that provides scenarios for Higgs pair production with different masses. The model has two interesting phases: the dark matter phase, with a Standard Model-like Higgs boson, a new scalar and a dark matter candidate; and the broken phase, with all three neutral scalars mixing. In the latter phase Higgs decays into a pair of two different Higgs bosons are possible. In this study we analyse Higgs-to-Higgs decays in the framework of singlet extensions of the Standard Model (SM), with focus on the CxSM. After demonstrating that scenarios with large rates for such chain decays are possible we perform a comparison between the NMSSM and the CxSM. We find that, based on Higgs-to-Higgs decays, the only possibility to distinguish the two models at the LHC run 2 is through final states with two different scalars. This conclusion builds a strong case for searches for final states with two different scalars at the LHC run 2. Finally, we propose a set of benchmark points for the real and complex singlet extensions to be tested at the LHC run 2. They have been chosen such that the discovery prospects of the involved scalars are maximised and they fulfil the dark matter constraints. Furthermore, for some of the points the theory is stable up to high energy scales. For the computation of the decay widths and branching ratios we developed the Fortran code sHDECAY, which is based on the implementation of the real and complex singlet extensions of the SM in HDECAY.

  1. Material and energy recovery in integrated waste management systems: the potential for energy recovery.

    Science.gov (United States)

    Consonni, Stefano; Viganò, Federico

    2011-01-01

    This article is part of a set of six coordinated papers reporting the main findings of a research project carried out by five Italian universities on "Material and energy recovery in Integrated Waste Management Systems (IWMS)". An overview of the project and a summary of the most relevant results can be found in the introductory article of the series. This paper describes the work related to the evaluation of mass and energy balances, which has consisted of three major efforts (i) development of a model for quantifying the energy content and the elemental compositions of the waste streams appearing in a IWMS; (ii) upgrade of an earlier model to predict the performances of Waste-to-Energy (WtE) plants; (iii) evaluation of mass and energy balances of all the scenarios and the recovery paths considered in the project. Results show that not only the amount of material available for energy recovery is significantly higher than the Unsorted Residual Waste (URW) left after Separate Collection (SC), because selection and recycling generate significant amounts of residues, but its heating value is higher than that of the original, gross waste. Therefore, the energy potential of what is left after recycling is always higher than the complement to 100% of the Source Separation Level (SSL). Also, increasing SSL has marginal effects on the potential for energy recovery: nearly doubling SSL (from 35% to 65%) reduces the energy potential only by one fourth. Consequently, even at high SSL energy recovery is a fundamental step of a sustainable waste management system. Variations of SSL do bring about variations of the composition, heating value and moisture content of the material fed to WtE plants, but these variations (i) are smaller than one can expect; (ii) have marginal effects on the performances of the WtE plant. These considerations suggest that the mere value of SSL is not a good indicator of the quality of the waste management system, nor of its energy and environmental

  2. Energy usage and technical potential for energy saving measures in the Swedish residential building stock

    International Nuclear Information System (INIS)

    Mata, Érika; Sasic Kalagasidis, Angela; Johnsson, Filip

    2013-01-01

    This paper provides an analysis of the current energy usage (net energy and final energy by fuels) and associated carbon dioxide (CO 2 ) emissions of the Swedish residential building stock, which includes single-family dwellings and multi-family dwellings. Twelve energy saving measures (ESMs) are assessed using a bottom–up modeling methodology, in which the Swedish residential stock is represented by a sample of 1400 buildings (based on data from the year 2005). Application of the ESMs studied gives a maximum technical reduction potential in energy demand of 53%, corresponding to a 63% reduction in CO 2 emissions. Although application of the investigated ESMs would reduce CO 2 emissions, the measures that reduce electricity consumption for lighting and appliances (LA) will increase CO 2 emissions, since the saved electricity production is less CO 2 -intensive than the fuel mix used for the increased space heating required to make up for the loss in indirect heating obtained from LA. - Highlights: ► Analysis of year 2005energy use and CO2 emissions of Swedish residential buildings. ► Includes all single-family dwellings and multi-family dwellings. ► Bottom–up modeling of building stock represented by 1400 buildings. ► Technical effects of 12 energy saving measures are assessed. ► Energy demand can be reduced by53% and associated CO 2 emissions by 63%

  3. Structures and potential energy functions of Pu3 molecule

    International Nuclear Information System (INIS)

    Meng Daqiao; Jiang Gang; Liu Xiaoya; Luo Deli; Zhu Zhenghe

    2001-01-01

    Density functional (B3LYP) method with relativistic effective core potential (RECP) has been used to optimize the structures of Pu 2 and Pu 3 molecules. The results show that the ground states of Pu 2 and Pu 3 molecules are of D ∞h and D 3h symmetry, and of 13 and 19 fold, respectively. The spectral constants of Pu 2 , ω e = 52.3845 cm -1 and ω e x e = 0.0201 cm -1 , and the harmonic frequencies of Pu 3 , ν 1 = 56.9007 cm -1 , ν 2 = 57.1816 cm - '1 and ν 3 = 64.0785 cm -1 , have also been obtained on the B3LYP/RECP level. The potential energy functions of Pu 2 and Pu 3 have been derived, for the first time so far as known, from normal equation fitting and the many-body expansion theory

  4. Assessing geothermal energy potential in upstate New York. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Hodge, D.S. [SUNY, Buffalo, NY (United States)

    1996-08-01

    The potential of geothermal energy for future electric power generation in New York State is evaluated using estimates of temperatures of geothermal reservoir rocks. Bottom hole temperatures from over 2000 oil and gas wells in the region were integrated into subsurface maps of the temperatures for specific geothermal reservoirs. The Theresa/Potsdam formation provides the best potential for extraction of high volumes of geothermal fluids. The evaluation of the Theresa/Potsdam geothermal reservoir in upstate New York suggests that an area 30 miles east of Elmira, New York has the highest temperatures in the reservoir rock. The Theresa/Potsdam reservoir rock should have temperatures about 136 {degrees}C and may have as much as 450 feet of porosity in excess of 8%. Estimates of the volumes of geothermal fluids that can be extracted are provided and environmental considerations for production from a geothermal well is discussed.

  5. Potential energy curves and collision integrals of air components

    Science.gov (United States)

    Partridge, Harry; Stallcop, James R.; Levin, Eugene; Langhoff, Stephen R. (Technical Monitor)

    1995-01-01

    Collision integrals are fundamental quantities required to determine the transport properties of the environment surrounding aerospace vehicles in the upper atmosphere. These collision integrals can be determined as a function of temperature from the potential energy curves describing the atomic and molecular collisions. Ab initio calculations provide a practical method of computing the required interaction potentials. In this work we will discuss recent advances with an emphasis on the accuracy that is obtainable. Results for interactions, e.g. N+N, N+O, O+O, and H+N2 will be reviewed and their application to the determination of transport properties, such as diffusion and viscosity coefficients, will be examined.

  6. Multipole expansion of the retarded interatomic potential energy: induction energy for degenerate ground-state atoms

    NARCIS (Netherlands)

    Michels, M.A.J.; Suttorp, L.G.

    1972-01-01

    The inductive contribution to the retarded interatomic potential energy of two atoms in degenerate ground states is calculated up to all multipole orders on the basis of quantum electrodynamics. The result, which is found to have nonretarded character, is written in such a way as to show the

  7. Wind and Solar Energy Potential Assessment for Development of Renewables Energies Applications in Bucaramanga, Colombia

    Science.gov (United States)

    Ordóñez, G.; Osma, G.; Vergara, P.; Rey, J.

    2014-06-01

    Currently, the trend of micro-grids and small-scale renewable generation systems implementation in urban environments requires to have historical and detailed information about the energy potential resource in site. In Colombia, this information is limited and do not favor the design of these applications; for this reason, must be made detailed studies of the energy potential in their cities. In this paper is presented the wind and solar energy resource assessment for the city of Bucaramanga, based on the monitoring on four strategic points during the years 2010, 2011 and 2012. According to the analysis, is evidenced a significant solar resource throughout the year ascending on average to 1 734 kWh/m2, equivalent to 4.8 kWh/m2/day. Also, from a wind statistical study based on the Weibull probability distribution and Wind Power Density (WPD) was established the wind potential as Class 1 according to the scale of the Department of Energy of the United States (DOE), since the average speed is near 1.4 m/s. Due this, it is technically unfeasible the using of micro-turbines in the city, even so their potential for natural ventilation of building was analyzed. Finally, is presented a methodology to analyze solar harvesting by sectors in the city, according to the solar motion and shadowing caused by existing structures.

  8. Wind and Solar Energy Potential Assessment for Development of Renewables Energies Applications in Bucaramanga, Colombia

    International Nuclear Information System (INIS)

    Ordóñez, G; Osma, G; Vergara, P; Rey, J

    2014-01-01

    Currently, the trend of micro-grids and small-scale renewable generation systems implementation in urban environments requires to have historical and detailed information about the energy potential resource in site. In Colombia, this information is limited and do not favor the design of these applications; for this reason, must be made detailed studies of the energy potential in their cities. In this paper is presented the wind and solar energy resource assessment for the city of Bucaramanga, based on the monitoring on four strategic points during the years 2010, 2011 and 2012. According to the analysis, is evidenced a significant solar resource throughout the year ascending on average to 1 734 kWh/m 2 , equivalent to 4.8 kWh/m 2 /day. Also, from a wind statistical study based on the Weibull probability distribution and Wind Power Density (WPD) was established the wind potential as Class 1 according to the scale of the Department of Energy of the United States (DOE), since the average speed is near 1.4 m/s. Due this, it is technically unfeasible the using of micro-turbines in the city, even so their potential for natural ventilation of building was analyzed. Finally, is presented a methodology to analyze solar harvesting by sectors in the city, according to the solar motion and shadowing caused by existing structures

  9. Assessment of market potential of compressed air energy storage systems

    Science.gov (United States)

    Boyd, D. W.; Buckley, O. E.; Clark, C. E., Jr.

    1983-12-01

    This report describes an assessment of potential roles that EPRI might take to facilitate the commercial acceptance of compressed air energy storage (CAES) systems. The assessment is based on (1) detailed analyses of the market potential of utility storage technologies, (2) interviews with representatives of key participants in the CAES market, and (3) a decision analysis synthesizing much of the information about market and technology status. The results indicate a large potential market for CAES systems if the overall business environment for utilities improves. In addition, it appears that EPRI can have a valuable incremental impact in ensuring that utilities realize the potential of CAES by (1) continuing an aggressive information dissemination and technology transfer program, (2) working to ensure the success of the first United States CAES installation at Soyland Power Cooperative, (3) developing planning methods to allow utilities to evaluate CAES and other storage options more effectively and more realistically, and (4) supporting R and D to resolve residual uncertainties in first-generation CAES cost and performance characteristics. Previously announced in STAR as N83-25121

  10. An Ab Initio Based Potential Energy Surface for Water

    Science.gov (United States)

    Partridge, Harry; Schwenke, David W.; Langhoff, Stephen R. (Technical Monitor)

    1996-01-01

    We report a new determination of the water potential energy surface. A high quality ab initio potential energy surface (PES) and dipole moment function of water have been computed. This PES is empirically adjusted to improve the agreement between the computed line positions and those from the HITRAN 92 data base. The adjustment is small, nonetheless including an estimate of core (oxygen 1s) electron correlation greatly improves the agreement with experiment. Of the 27,245 assigned transitions in the HITRAN 92 data base for H2(O-16), the overall root mean square (rms) deviation between the computed and observed line positions is 0.125/cm. However the deviations do not correspond to a normal distribution: 69% of the lines have errors less than 0.05/cm. Overall, the agreement between the line intensities computed in the present work and those contained in the data base is quite good, however there are a significant number of line strengths which differ greatly.

  11. Forces on nuclei moving on autoionizing molecular potential energy surfaces.

    Science.gov (United States)

    Moiseyev, Nimrod

    2017-01-14

    Autoionization of molecular systems occurs in diatomic molecules and in small biochemical systems. Quantum chemistry packages enable calculation of complex potential energy surfaces (CPESs). The imaginary part of the CPES is associated with the autoionization decay rate, which is a function of the molecular structure. Molecular dynamics simulations, within the framework of the Born-Oppenheimer approximation, require the definition of a force field. The ability to calculate the forces on the nuclei in bio-systems when autoionization takes place seems to rely on an understanding of radiative damages in RNA and DNA arising from the release of slow moving electrons which have long de Broglie wavelengths. This work addresses calculation of the real forces on the nuclei moving on the CPES. By using the transformation of the time-dependent Schrödinger equation, previously used by Madelung, we proved that the classical forces on nuclei moving on the CPES correlated with the gradient of the real part of the CPES. It was proved that the force on the nuclei of the metastable molecules is time independent although the probability to detect metastable molecules exponentially decays. The classical force is obtained from the transformed Schrödinger equation when ℏ=0 and the Schrödinger equation is reduced to the classical (Newtonian) equations of motion. The forces on the nuclei regardless on what potential energy surface they move (parent CPES or product real PESs) vary in time due to the autoionization process.

  12. Transportation Energy Futures Series. Potential for Energy Efficiency Improvement Beyond the Light-Duty-Vehicle Sector

    Energy Technology Data Exchange (ETDEWEB)

    Vyas, A. D. [Argonne National Lab. (ANL), Argonne, IL (United States); Patel, D. M. [Argonne National Lab. (ANL), Argonne, IL (United States); Bertram, K. M. [Argonne National Lab. (ANL), Argonne, IL (United States)

    2013-02-01

    Considerable research has focused on energy efficiency and fuel substitution options for light-duty vehicles, while much less attention has been given to medium- and heavy-duty trucks, buses, aircraft, marine vessels, trains, pipeline, and off-road equipment. This report brings together the salient findings from an extensive review of literature on future energy efficiency options for these non-light-duty modes. Projected activity increases to 2050 are combined with forecasts of overall fuel efficiency improvement potential to estimate the future total petroleum and greenhouse gas (GHG) emissions relative to current levels. This is one of a series of reports produced as a result of the Transportation Energy Futures (TEF) project, a Department of Energy-sponsored multi-agency project initiated to pinpoint underexplored strategies for abating GHGs and reducing petroleum dependence related to transportation.

  13. Transportation Energy Futures Series: Potential for Energy Efficiency Improvement Beyond the Light-Duty-Vehicle Sector

    Energy Technology Data Exchange (ETDEWEB)

    Vyas, A. D.; Patel, D. M.; Bertram, K. M.

    2013-03-01

    Considerable research has focused on energy efficiency and fuel substitution options for light-duty vehicles, while much less attention has been given to medium- and heavy-duty trucks, buses, aircraft, marine vessels, trains, pipeline, and off-road equipment. This report brings together the salient findings from an extensive review of literature on future energy efficiency options for these non-light-duty modes. Projected activity increases to 2050 are combined with forecasts of overall fuel efficiency improvement potential to estimate the future total petroleum and greenhouse gas (GHG) emissions relative to current levels. This is one of a series of reports produced as a result of the Transportation Energy Futures (TEF) project, a Department of Energy-sponsored multi-agency project initiated to pinpoint underexplored strategies for abating GHGs and reducing petroleum dependence related to transportation.

  14. Epicardial Application Of Laser Energy In Vivo: Acute Arrhythmogenic Potential

    Science.gov (United States)

    Cohen, Mark H.; Ben-Shachar, Giora; Beder, Stanley D.; Sivakoff, Mark; Riemenschneider, Thomas A.

    1986-01-01

    In order to assess the effect of laser energy on the heart's rhythm, 7 newborn pigs each had 3 two-second applications of laser energy directly to the left ventricular epicardial surface. A quartz fiberoptic delivery system was used. All piglets (in all 21 applications) had ventricular arrhythmia induced. This varied from single premature ventricular contractions to sustained(112 seconds) ventricular tachycardia (6/7 piglets). The sustained ventri-cular tachycardia exhibited electrophysiologic criteria of a "re-entrant" mechanism. Fifteen minutes following lasing, programmed ventricular stimulation, a technique that indicates whether a substrate may be present for spontaneous re-entrant arrhythmias, showed induced arrhythmia in only 2/7 pigs, neither sustained. We conclude that epicardial application of laser energy frequently results in significant ventricular arrhythmia. This arrhythmia appears to be re-entrant in nature. Fowever, shortly following lasing, sustained arrhythmia could not be induced. Therefore, we feel that more knowledge about the arrhythmogenic potential of laser lesions is needed prior to wide-spread clinical application.

  15. Market potential for non-electric applications of nuclear energy

    International Nuclear Information System (INIS)

    2002-01-01

    The objective of this report is to assess the market potential for the non-electric applications of nuclear energy in the near (before 2020) and long (2020-2050) terms. The main non-electric applications are defined here as district heating, desalination (of sea, brackish and waste water), industrial heat supply, ship propulsion and the energy supply for spacecraft. This report is principally devoted to these applications, although a less detailed assessment of some innovative applications (e.g. hydrogen production and coal gasification) is also provided. While the technical details of these applications are covered briefly, emphasis is placed on the economic and other factors that may promote or hinder the penetration of the nuclear option into the market for non-electric energy services. The report is intentionally targeted towards expected demands. It is for this reason that its sections are structured by demand categories and not according to possible reactor types. At the same time, the orientation on the demand side can result in overlaps at the supply side, because the same nuclear reactor can often serve more than one type of demand. Such cases are noted as appropriate. Each section characterizes a specific non-electric application in terms of its market size, its prospects for nuclear technologies and the economic competitiveness of the technologies

  16. Potential strategic consequences of the nuclear energy revival

    International Nuclear Information System (INIS)

    Ferguson, Ch.D.

    2010-01-01

    Many people have projected their hopes and fears onto nuclear power. Nuclear energy has both benefits and risks, and disagreement persists about whether this energy source is, on balance, more of an asset than a liability. This debate involves a complicated set of factors that are difficult to assess, let alone fully resolve because of the differing interests in various countries' use and pursuit of nuclear power. Renewed interest throughout the globe in harnessing this energy source has stoked this perennial debate and raised concern about security threats from states and non-state actors while holding out the promise of more electricity for more people. While the motivations for nuclear energy vary among states, the two primary public goods this energy source offers are countering human-induced climate change and providing for greater energy security. Although views on how to achieve energy security differ, the essential aspect for nuclear energy is that for several countries, especially those with scarce indigenous energy sources from fossil fuels, investing in nuclear power plants diversifies electricity production portfolios and helps reduce dependence on foreign sources of energy. The focus here is on assessing the potential security consequences of increased use of nuclear power in the existing nuclear power states and most importantly in many more states that have in recent years expressed interest in this power source. The risks of nuclear power include possible reactor accidents, release of radioactive waste to the environment, attacks on or sabotage of nuclear facilities, and misuse of peaceful nuclear technologies to make nuclear weapons. While safety of nuclear plants and disposal of radioactive waste are important issues, this paper analyzes the latter two issues. In addition, it addresses two under-examined risks: military attacks on nuclear facilities and the effects on security alliances and conventional arms buildups as more countries seek to

  17. Networks of triboelectric nanogenerators for harvesting water wave energy: a potential approach toward blue energy.

    Science.gov (United States)

    Chen, Jun; Yang, Jin; Li, Zhaoling; Fan, Xing; Zi, Yunlong; Jing, Qingshen; Guo, Hengyu; Wen, Zhen; Pradel, Ken C; Niu, Simiao; Wang, Zhong Lin

    2015-03-24

    With 70% of the earth's surface covered with water, wave energy is abundant and has the potential to be one of the most environmentally benign forms of electric energy. However, owing to lack of effective technology, water wave energy harvesting is almost unexplored as an energy source. Here, we report a network design made of triboelectric nanogenerators (TENGs) for large-scale harvesting of kinetic water energy. Relying on surface charging effect between the conventional polymers and very thin layer of metal as electrodes for each TENG, the TENG networks (TENG-NW) that naturally float on the water surface convert the slow, random, and high-force oscillatory wave energy into electricity. On the basis of the measured output of a single TENG, the TENG-NW is expected to give an average power output of 1.15 MW from 1 km(2) surface area. Given the compelling features, such as being lightweight, extremely cost-effective, environmentally friendly, easily implemented, and capable of floating on the water surface, the TENG-NW renders an innovative and effective approach toward large-scale blue energy harvesting from the ocean.

  18. ROMANIA'S ENERGY POTENTIAL OF RENEWABLE ENERGIES IN THE CONTEXT OF SUSTAINABLE DEVELOPMENT

    Directory of Open Access Journals (Sweden)

    Maghear Diana

    2011-12-01

    environmental pollution as well as the depletion of the conventional resources that are highly polluting, highlighting the energy potential that renewable energy resources Romania has. This issue will be extensively discussed in the thesis entitled 'The necessity and importance of sustainable development of Romania. Case study on the use of renewable energies for heating the population in the western part of Romania' which I intend to realize and support at The West University of Timisoara, Faculty of Economics and Business Administration, under the guidance of Professor Doctor Laura Cismas.

  19. Computed Potential Energy Surfaces and Minimum Energy Pathways for Chemical Reactions

    Science.gov (United States)

    Walch, Stephen P.; Langhoff, S. R. (Technical Monitor)

    1994-01-01

    Computed potential energy surfaces are often required for computation of such parameters as rate constants as a function of temperature, product branching ratios, and other detailed properties. For some dynamics methods, global potential energy surfaces are required. In this case, it is necessary to obtain the energy at a complete sampling of all the possible arrangements of the nuclei, which are energetically accessible, and then a fitting function must be obtained to interpolate between the computed points. In other cases, characterization of the stationary points and the reaction pathway connecting them is sufficient. These properties may be readily obtained using analytical derivative methods. We have found that computation of the stationary points/reaction pathways using CASSCF/derivative methods, followed by use of the internally contracted CI method to obtain accurate energetics, gives usefull results for a number of chemically important systems. The talk will focus on a number of applications including global potential energy surfaces, H + O2, H + N2, O(3p) + H2, and reaction pathways for complex reactions, including reactions leading to NO and soot formation in hydrocarbon combustion.

  20. Future World Energy Demand and Supply: China and India and the Potential Role of Fusion Energy

    International Nuclear Information System (INIS)

    Sheffield, John

    2005-01-01

    Massive increases in energy demand are projected for countries such as China and India over this century e.g., many 100s of megawatts of electricity (MWe) of additional electrical capacity by 2050, with more additions later, are being considered for each of them. All energy sources will be required to meet such a demand. Fortunately, while world energy demand will be increasing, the world is well endowed with a variety of energy resources. However, their distribution does not match the areas of demand and there are many environmental issues.Such geopolitical issues affect China and India and make it important for them to be able to deploy improved technologies. In this regard, South Korea is an interesting example of a country that has developed the capability to do advanced technologies - such as nuclear power plants. International collaborations in developing these technologies, such as the International Thermonuclear Reactor (ITER), may be important in all energy areas. Fusion energy is viewed as an interesting potential option in these three countries

  1. Biogas from poultry waste-production and energy potential.

    Science.gov (United States)

    Dornelas, Karoline Carvalho; Schneider, Roselene Maria; do Amaral, Adriana Garcia

    2017-08-01

    The objective of this study was to evaluate the effect of heat treatment on poultry litter with different levels of reutilisation for potential generation of biogas in experimental biodigesters. Chicken litter used was obtained from two small-scale poultry houses where 14 birds m -2 were housed for a period of 42 days per cycle. Litter from aviary 1 received no heat treatment while each batch of litter produced from aviary 2 underwent a fermentation process. For each batch taken, two biodigesters were set for each aviary, with hydraulic retention time of 35 days. The efficiency of the biodigestion process was evaluated by biogas production in relation to total solids (TS) added, as well as the potential for power generation. Quantified volumes ranged from 8.9 to 41.1 L of biogas for aviary 1, and 6.7 to 33.9 L of biogas for aviary 2, with the sixth bed reused from both aviaries registering the largest biogas potential. Average potential biogas in m 3  kg -1 of TS added were 0.022 to 0.034 for aviary 1 and 0.015 to 0.022 for aviary 2. Energy values ​​of biogas produced were calculated based on calorific value and ranged from 0.06 to 0.33 kWh for chicken litter without fermentation and from 0.05 to 0.27 kWh for chicken litter with fermentation. It was concluded that the re-use of poultry litter resulted in an increase in biogas production, and the use of fermentation in the microbiological treatment of poultry litter seems to have negatively influenced production of biogas.

  2. Exploring Multiple Potential Energy Surfaces: Photochemistry of Small Carbonyl Compounds

    Directory of Open Access Journals (Sweden)

    Satoshi Maeda

    2012-01-01

    Full Text Available In theoretical studies of chemical reactions involving multiple potential energy surfaces (PESs such as photochemical reactions, seams of intersection among the PESs often complicate the analysis. In this paper, we review our recipe for exploring multiple PESs by using an automated reaction path search method which has previously been applied to single PESs. Although any such methods for single PESs can be employed in the recipe, the global reaction route mapping (GRRM method was employed in this study. By combining GRRM with the proposed recipe, all critical regions, that is, transition states, conical intersections, intersection seams, and local minima, associated with multiple PESs, can be explored automatically. As illustrative examples, applications to photochemistry of formaldehyde and acetone are described. In these examples as well as in recent applications to other systems, the present approach led to discovery of many unexpected nonadiabatic pathways, by which some complicated experimental data have been explained very clearly.

  3. Potential alternative energy technologies on the Outer Continental Shelf.

    Energy Technology Data Exchange (ETDEWEB)

    Elcock, D.; Environmental Assessment

    2007-04-20

    This technical memorandum (TM) describes the technology requirements for three alternative energy technologies for which pilot and/or commercial projects on the U.S. Outer Continental Shelf (OCS) are likely to be proposed within the next five to seven years. For each of the alternative technologies--wind, wave, and ocean current--the TM first presents an overview. After each technology-specific overview, it describes the technology requirements for four development phases: site monitoring and testing, construction, operation, and decommissioning. For each phase, the report covers the following topics (where data are available): facility description, electricity generated, ocean area (surface and bottom) occupied, resource requirements, emissions and noise sources, hazardous materials stored or used, transportation requirements, and accident potential. Where appropriate, the TM distinguishes between pilot-scale (or demonstration-scale) facilities and commercial-scale facilities.

  4. Improved DFT Potential Energy Surfaces via Improved Densities.

    Science.gov (United States)

    Kim, Min-Cheol; Park, Hansol; Son, Suyeon; Sim, Eunji; Burke, Kieron

    2015-10-01

    Density-corrected DFT is a method that cures several failures of self-consistent semilocal DFT calculations by using a more accurate density instead. A novel procedure employs the Hartree-Fock density to bonds that are more severely stretched than ever before. This substantially increases the range of accurate potential energy surfaces obtainable from semilocal DFT for many heteronuclear molecules. We show that this works for both neutral and charged molecules. We explain why and explore more difficult cases, for example, CH(+), where density-corrected DFT results are even better than sophisticated methods like CCSD. We give a simple criterion for when DC-DFT should be more accurate than self-consistent DFT that can be applied for most cases.

  5. Potential of Biomass for Energy. Market Survey Portugal

    International Nuclear Information System (INIS)

    2007-03-01

    The objective of this market survey is to provide information about the biomass sector in Portugal, relevant to mainly small and medium-sized enterprises (SME) in the Netherlands that are interested to strengthen their position in that sector. Much knowledge could be gathered from conversations with the partners of Sunergy, the company responsible for this survey. Sunergy is producing bio-diesel, and considering further investments in the solid biomass sector, and therefore well familiar with the developments. Other interviews were held with representatives of the Government (DGGE), association of forestry owners (AFLOPS), a biomass trading SME (Sobioen), the leading environmental NGO (Quercus), and an association representing the paper- and pulp industry (CELPA). Chapter 1 is a general introduction on biomass. Chapter 2 gives the background of the Portuguese energy sector and the relative importance of renewable and biomass energies within this market. Some prospects for future developments of the different renewable sources are given. Portugal's energy sector is dominated by a small number of players, which are introduced. Also the current policies and incentives (subsidies) are presented. In Chapter 3 the focus is on the Portuguese biomass sector, presenting the current use of biomass in each of the subsectors: transport, electricity and heat, and an overview of the policy framework specifically for biomass. Chapter 4 is a literature review of the market for existing and potential biomass resources, including demand, supply and other characteristics. Chapter 5 synthesizes the previous chapters. Also an overview of key drivers and key constraints for growth of this sector is given, leading to conclusions regarding the opportunities for Dutch companies. Finally, further information on how to proceed once the interest for Portugal's biomass sector is vested is listed at the end of Chapter 5

  6. An Accurate Potential Energy Surface for H2O

    Science.gov (United States)

    Schwenke, David W.; Partridge, Harry; Langhoff, Stephen R. (Technical Monitor)

    1997-01-01

    We have carried out extensive high quality ab initio electronic structure calculations of the ground state potential energy surface (PES) and dipole moment function (DMF) for H2O. A small adjustment is made to the PES to improve the agreement of line positions from theory and experiment. The theoretical line positions are obtained from variational ro-vibrational calculations using the exact kinetic energy operator. For the lines being fitted, the root-mean-square error was reduced from 6.9 to 0.08 /cm. We were then able to match 30,092 of the 30,117 lines from the HITRAN 96 data base to theoretical lines, and 80% of the line positions differed less than 0.1 /cm. About 3% of the line positions in the experimental data base appear to be incorrect. Theory predicts the existence of many additional weak lines with intensities above the cutoff used in the data base. To obtain results of similar accuracy for HDO, a mass dependent correction to the PH is introduced and is parameterized by simultaneously fitting line positions for HDO and D2O. The mass dependent PH has good predictive value for T2O and HTO. Nonadiabatic effects are not explicitly included. Line strengths for vibrational bands summed over rotational levels usually agree well between theory and experiment, but individual line strengths can differ greatly. A high temperature line list containing about 380 million lines has been generated using the present PES and DMF

  7. Renewable energy technologies in the Maldives - Realizing the potential

    International Nuclear Information System (INIS)

    Alphen, Klaas van; Hekkert, Marko P.; Sark, Wilfried G.J.H.M. van

    2008-01-01

    Like in many Small Island Developing States, the techno-economic potential of renewable energy technologies (RETs) in the Maldives is substantial. However, it is not certain that these economically viable RETs will indeed be implemented and utilized, since this is greatly influenced by various social, institutional and political factors (i.e., the Innovation System). In order to steer away from activities that enhance the current fossil fuel based lock-in situation and create an environment that increases the chance of a successful transfer and diffusion of RETs, several projects have been set up in the Maldives. These projects have been initiated by the Global Environmental Facility, the United Nations Development Program, and the European Commission. In this article we evaluate these projects by analyzing whether or not they strengthen the local Renewable Energy Innovation System. This evaluation shows that these RE programs strengthen most of the key processes necessary in an Innovation System conducive to technology transfer. However, as not enough attention is being paid to local entrepreneurial activities and the creation of a domestic market for RETs, the process of RET transfer might run the risk of stagnation after completion of the RE programs. (author)

  8. Zethrenes, Extended p -Quinodimethanes, and Periacenes with a Singlet Biradical Ground State

    KAUST Repository

    Sun, Zhe

    2014-08-19

    ConspectusResearchers have studied polycyclic aromatic hydrocarbons (PAHs) for more than 100 years, and most PAHs in the neutral state reported so far have a closed-shell electronic configuration in the ground state. However, recent studies have revealed that specific types of polycyclic hydrocarbons (PHs) could have a singlet biradical ground state and exhibit unique electronic, optical, and magnetic activities. With the appropriate stabilization, these new compounds could prove useful as molecular materials for organic electronics, nonlinear optics, organic spintronics, organic photovoltaics, and energy storage devices. However, before researchers can use these materials to design new devices, they need better methods to synthesize these molecules and a better understanding of the fundamental relationship between the structure and biradical character of these compounds and their physical properties. Their biradical character makes these compounds difficult to synthesize. These compounds are also challenging to physically characterize and require the use of various experimental techniques and theoretic methods to comprehensively describe their unique properties.In this Account, we will discuss the chemistry and physics of three types of PHs with a significant singlet biradical character, primarily developed in our group. These structures are zethrenes, Z-shaped quinoidal hydrocarbons; hydrocarbons that include a proaromatic extended p-quinodimethane unit; and periacenes, acenes fused in a peri-Arrangement. We used a variety of synthetic methods to prepare these compounds and stabilized them using both thermodynamic and kinetic approaches. We probed their ground-state structures by electronic absorption, NMR, ESR, SQUID, Raman spectroscopy, and X-ray crystallography and also performed density functional theory calculations. We investigated the physical properties of these PHs using various experimental methods such as one-photon absorption, two-photon absorption

  9. Estimating Solar Energy Potential in Buildings on a Global Level

    DEFF Research Database (Denmark)

    Petrichenko, Ksenia

    2015-01-01

    This chapter contributes to the debate around net-zero energy concept from a global perspective. By means of comprehensive modelling, it analyses how much global building energy consumption could be reduced through utilisation of building-integrated solar energy technologies and energy......-efficiency improvements. Valuable insights on the locations and building types, in which it is feasible to achieve a net-zero level of energy performance through solar energy utilisation, are presented in world maps....

  10. Recoil detection of the lightest neutralino in MSSM singlet extensions

    International Nuclear Information System (INIS)

    Barger, Vernon; Lewis, Ian; McCaskey, Mat; Shaughnessy, Gabe; Yencho, Brian; Langacker, Paul

    2007-01-01

    We investigate the correlated predictions of singlet extended MSSM models for direct detection and the cosmological relic density of the lightest neutralino. To illustrate the general effects of the singlet, we take heavy sleptons and squarks. We apply CERN LEP (g-2) μ , and perturbativity constraints. We find that the WMAP upper bound on the cold dark matter density limits much of the parameter space to regions where the lightest neutralino can be discovered in recoil experiments. The results for the next-to-minimal supersymmetric standard model and U(1) ' -extended minimal supersymmetric standard model are typically similar to the MSSM since their light neutralinos have similar compositions and masses. In the nearly minimal supersymmetric standard model the neutralino is often very light and its recoil detection is within the reach of the CDMS II experiment. In general, most points in the parameter spaces of the singlet models we consider are accessible to the WARP experiment

  11. Impurities near an antiferromagnetic-singlet quantum critical point

    International Nuclear Information System (INIS)

    Mendes-Santos, T.; Costa, N. C.; Batrouni, G.

    2017-01-01

    Heavy-fermion systems and other strongly correlated electron materials often exhibit a competition between antiferromagnetic (AF) and singlet ground states. We examine the effect of impurities in the vicinity of such an AF-singlet quantum critical point (QCP), through an appropriately defined “impurity susceptibility” χimp, using exact quantum Monte Carlo simulations. Our key finding is a connection within a single calculational framework between AF domains induced on the singlet side of the transition and the behavior of the nuclear magnetic resonance (NMR) relaxation rate 1/T1. Furthermore, we show that local NMR measurements provide a diagnostic for the location of the QCP, which agrees remarkably well with the vanishing of the AF order parameter and large values of χimp.

  12. Gamma rays from the annihilation of singlet scalar dark matter

    Science.gov (United States)

    Yaguna, Carlos E.

    2009-03-01

    We consider an extension of the Standard Model by a singlet scalar that accounts for the dark matter of the Universe. Within this model we compute the expected gamma ray flux from the annihilation of dark matter particles in a consistent way. To do so, an updated analysis of the parameter space of the model is first presented. By enforcing the relic density constraint from the very beginning, the viable parameter space gets reduced to just two variables: the singlet mass and the higgs mass. Current direct detection constraints are then found to require a singlet mass larger than 50 GeV. Finally, we compute the gamma ray flux and annihilation cross section and show that a large fraction of the viable parameter space lies within the sensitivity of Fermi-GLAST.

  13. Gamma rays from the annihilation of singlet scalar dark matter

    International Nuclear Information System (INIS)

    Yaguna, Carlos E.

    2009-01-01

    We consider an extension of the Standard Model by a singlet scalar that accounts for the dark matter of the Universe. Within this model we compute the expected gamma ray flux from the annihilation of dark matter particles in a consistent way. To do so, an updated analysis of the parameter space of the model is first presented. By enforcing the relic density constraint from the very beginning, the viable parameter space gets reduced to just two variables: the singlet mass and the higgs mass. Current direct detection constraints are then found to require a singlet mass larger than 50 GeV. Finally, we compute the gamma ray flux and annihilation cross section and show that a large fraction of the viable parameter space lies within the sensitivity of Fermi-GLAST

  14. Singlet fission efficiency in tetracene-based organic solar cells

    International Nuclear Information System (INIS)

    Wu, Tony C.; Thompson, Nicholas J.; Congreve, Daniel N.; Hontz, Eric; Yost, Shane R.; Van Voorhis, Troy; Baldo, Marc A.

    2014-01-01

    Singlet exciton fission splits one singlet exciton into two triplet excitons. Using a joint analysis of photocurrent and fluorescence modulation under a magnetic field, we determine that the triplet yield within optimized tetracene organic photovoltaic devices is 153% ± 5% for a tetracene film thickness of 20 nm. The corresponding internal quantum efficiency is 127% ± 18%. These results are used to prove the effectiveness of a simplified triplet yield measurement that relies only on the magnetic field modulation of fluorescence. Despite its relatively slow rate of singlet fission, the measured triplet yields confirm that tetracene is presently the best candidate for use with silicon solar cells

  15. A Comparison of Singlet Oxygen Explicit Dosimetry (SOED and Singlet Oxygen Luminescence Dosimetry (SOLD for Photofrin-Mediated Photodynamic Therapy

    Directory of Open Access Journals (Sweden)

    Michele M. Kim

    2016-12-01

    Full Text Available Accurate photodynamic therapy (PDT dosimetry is critical for the use of PDT in the treatment of malignant and nonmalignant localized diseases. A singlet oxygen explicit dosimetry (SOED model has been developed for in vivo purposes. It involves the measurement of the key components in PDT—light fluence (rate, photosensitizer concentration, and ground-state oxygen concentration ([3O2]—to calculate the amount of reacted singlet oxygen ([1O2]rx, the main cytotoxic component in type II PDT. Experiments were performed in phantoms with the photosensitizer Photofrin and in solution using phosphorescence-based singlet oxygen luminescence dosimetry (SOLD to validate the SOED model. Oxygen concentration and photosensitizer photobleaching versus time were measured during PDT, along with direct SOLD measurements of singlet oxygen and triplet state lifetime (τΔ and τt, for various photosensitizer concentrations to determine necessary photophysical parameters. SOLD-determined cumulative [1O2]rx was compared to SOED-calculated [1O2]rx for various photosensitizer concentrations to show a clear correlation between the two methods. This illustrates that explicit dosimetry can be used when phosphorescence-based dosimetry is not feasible. Using SOED modeling, we have also shown evidence that SOLD-measured [1O2]rx using a 523 nm pulsed laser can be used to correlate to singlet oxygen generated by a 630 nm laser during a clinical malignant pleural mesothelioma (MPM PDT protocol by using a conversion formula.

  16. Fixed energy potentials through an auxiliary inverse eigenvalue problem

    International Nuclear Information System (INIS)

    Pálmai, Tamás; Apagyi, Barnabás

    2012-01-01

    An inverse scattering method based on an auxiliary inverse Sturm–Liouville problem recently proposed by Horváth and Apagyi (2008 Mod. Phys. Lett. B 22 2137) is examined in various aspects and developed further to (re)construct spherically symmetric fixed energy potentials of compact support realized in the three-dimensional Schrödinger equation. The method is generalized to obtain a family of inverse procedures characterized by two parameters originating, respectively, from the Liouville transformation and the solution of the inverse Sturm–Liouville problem. Both parameters affect the bound states arising in the auxiliary inverse spectral problem and one of them enables us to reduce their number which is assessed by a simple method. Various solution techniques of the underlying moment problem are proposed including the exact Cauchy matrix inversion method, usage of spurious bound state and assessment of the number of bound states. Examples include (re)productions of potentials from phase shifts known theoretically or derived from scattering experiments. (paper)

  17. Potential of Livestock Generated Biomass: Untapped Energy Source in India

    Directory of Open Access Journals (Sweden)

    Gagandeep Kaur

    2017-06-01

    Full Text Available Modern economies run on the backbone of electricity as one of major factors behind industrial development. India is endowed with plenty of natural resources and the majority of electricity within the country is generated from thermal and hydro-electric plants. A few nuclear plants assist in meeting the national requirements for electricity but still many rural areas remain uncovered. As India is primarily a rural agrarian economy, providing electricity to the remote, undeveloped regions of the country remains a top priority of the government. A vital, untapped source is livestock generated biomass which to some extent has been utilized to generate electricity in small scale biogas based plants under the government's thrust on rural development. This study is a preliminary attempt to correlate developments in this arena in the Asian region, as well as the developed world, to explore the possibilities of harnessing this resource in a better manner. The current potential of 2600 million tons of livestock dung generated per year, capable of yielding 263,702 million m3 of biogas is exploited. Our estimates suggest that if this resource is utilized judiciously, it possesses the potential of generating 477 TWh (Terawatt hour of electrical energy per annum.

  18. Brazil's energy potential: a governance challenge

    International Nuclear Information System (INIS)

    Sebille-Lopez, Philippe

    2015-07-01

    Except good quality anthracite, Brazil possesses all possible energy resources in large quantities: large natural gas and oil reserves, high hydroelectric capacities, but also high wind and solar capacities. Despite this potential, Brazil is often facing large electric power failures. After a first part which proposes an overview of characteristics of the hydrocarbon sector (overview of oil discoveries, evocation of the Petrobras monopoly, comments about shortfall in natural gas production, and about ethanol as adjustment variable in transports but insufficient to solve the external dependency of Brazil for oil-based products), the author tries to identify and understand the political management of this sector by the Workers Party since 2003 (law, local content and limits of oil at the service of the Brazilian economy, Petrobras as a state within the state, issues related to corruption). The author then focuses on electricity, tries to understand why, despite this high potential and constant investment in this sector, the country is still facing these power failures. In this respect, he notably comments the status and condition of electricity production, the reform of electricity pricing, and the lack of statistics on hydroelectricity, and outlines that improvements are long coming. He also highlights the role of politics in the management of this sector

  19. Absence of Intramolecular Singlet Fission in Pentacene-Perylenediimide Heterodimers: The Role of Charge Transfer State.

    Science.gov (United States)

    Wang, Long; Wu, Yishi; Chen, Jianwei; Wang, Lanfen; Liu, Yanping; Yu, Zhenyi; Yao, Jiannian; Fu, Hongbing

    2017-11-16

    A new class of donor-acceptor heterodimers based on two singlet fission (SF)-active chromophores, i.e., pentacene (Pc) and perylenediimide (PDI), was developed to investigate the role of charge transfer (CT) state on the excitonic dynamics. The CT state is efficiently generated upon photoexcitation. However, the resulting CT state decays to different energy states depending on the energy levels of the CT state. It undergoes extremely rapid deactivation to the ground state in polar CH 2 Cl 2 , whereas it undergoes transformation to a Pc triplet in nonpolar toluene. The efficient triplet generation in toluene is not due to SF but CT-mediated intersystem crossing. In light of the energy landscape, it is suggested that the deep energy level of the CT state relative to that of the triplet pair state makes the CT state actually serve as a trap state that cannot undergoes an intramolecular singlet fission process. These results provide guidance for the design of SF materials and highlight the requisite for more widely applicable design principles.

  20. Standard model extended by a heavy singlet: Linear vs. nonlinear EFT

    Energy Technology Data Exchange (ETDEWEB)

    Buchalla, G., E-mail: gerhard.buchalla@lmu.de; Catà, O.; Celis, A.; Krause, C.

    2017-04-15

    We consider the Standard Model extended by a heavy scalar singlet in different regions of parameter space and construct the appropriate low-energy effective field theories up to first nontrivial order. This top-down exercise in effective field theory is meant primarily to illustrate with a simple example the systematics of the linear and nonlinear electroweak effective Lagrangians and to clarify the relation between them. We discuss power-counting aspects and the transition between both effective theories on the basis of the model, confirming in all cases the rules and procedures derived in previous works from a bottom-up approach.

  1. Synergy potential for oil and geothermal energy exploitation

    NARCIS (Netherlands)

    Ziabakhshganji, Z.; Maghami Nick, Hamidreza M.; Donselaar, Rick; Bruhn, D.F.

    2018-01-01

    A new solution for harvesting energy simultaneously from two different sources of energy by combining geothermal energy production and thermal enhanced heavy oil recovery is introduced. Numerical simulations are employed to evaluate the feasibility of generating energy from geothermal resources,

  2. Potential Ambient Energy-Harvesting Sources and Techniques

    Science.gov (United States)

    Yildiz, Faruk

    2009-01-01

    Ambient energy harvesting is also known as energy scavenging or power harvesting, and it is the process where energy is obtained from the environment. A variety of techniques are available for energy scavenging, including solar and wind powers, ocean waves, piezoelectricity, thermoelectricity, and physical motions. For example, some systems…

  3. On the global and regional potential of renewable energy sources

    NARCIS (Netherlands)

    Hoogwijk, Monique Maria

    2004-01-01

    In this thesis, the central research question is: what can be the contribution of renewable energy sources to the present and future world and regional energy supply system. The focus is on wind, solar PV and biomass energy (energy crops) for electricity generation. For the assessment of the

  4. Assessment of the wind energy potential at Bausch + Lomb Waterford

    OpenAIRE

    Flynn, John

    2013-01-01

    In recent years, renewable energy has come to prominence due to worldwide concern over greenhouse gases, energy supply issues and increasing economic volatility, and this, coupled with the ever-increasing price of fossil fuels, has led to an increased emphasis being placed on alternative sources of energy. These energy issues are attributable to a number of factors, typically, dependence on fossil fuel reserves, increase in energy demand and the current economic climate. As a result of the fa...

  5. Reversible Photochemical Control of Singlet Oxygen Generation Using Diarylethene Photochromic Switches

    NARCIS (Netherlands)

    Hou, Lili; Zhang, Xiaoyan; Pijper, Thomas C.; Browne, Wesley R.; Feringa, Bernard

    2014-01-01

    Reversible noninvasive control over the generation of singlet oxygen is demonstrated in a bicomponent system comprising a diarylethene photochromic switch and a porphyrin photosensitizer by selective irradiation at distinct wavelengths. The efficient generation of singlet oxygen by the

  6. THE SINGLET-TRIPLET ENERGY GAP IN DIVALENT THREE, FIVE ...

    African Journals Online (AJOL)

    Preferred Customer

    12. Barrau, J.; Rima, G. Coord. Chem. Rev. 1998, 180, 593. 13. Davidson, P.J.; Harris, D.H.; Lappert, M.F. J. Chem. Soc. Dalton Trans. 1976, 2268. 14. Kano, N.; Shibata, K.; Tokitoh, N.; Okazaki, R. Organometallics 1999, 18, 2999. 15. Harrison, P.G. Comprehensive Organometallic Chemistry II , Vol. 2, Pergamon: New York;.

  7. Geothermal energy in Italy - its importance, potential and projects

    International Nuclear Information System (INIS)

    Berger, W.

    2005-01-01

    This article discusses the perspectives for the use of geothermal energy in Italy. Starting with an overview of the principles of the use of geothermal energy in general, the article goes on to review Italy's geothermal resources and their relevance to energy supply. Figures are given on the political situation in Italy concerning energy and the rapidly increasing demands made on electricity supply. Political support for renewable energy in Italy is looked at and models for financing projects are examined. Examples of geothermal energy projects are given and the perspectives for further developments in this industry are looked at

  8. Correlated Pair States Formed by Singlet Fission and Exciton-Exciton Annihilation.

    Science.gov (United States)

    Scholes, Gregory D

    2015-12-24

    Singlet fission to form a pair of triplet excitations on two neighboring molecules and the reverse process, triplet-triplet annihilation to upconvert excitation, have been extensively studied. Comparatively little work has sought to examine the properties of the intermediate state in both of these processes-the bimolecular pair state. Here, the eigenstates constituting the manifold of 16 bimolecular pair excitations and their relative energies in the weak-coupling regime are reported. The lowest-energy states obtained from the branching diagram method are the triplet pairs with overall singlet spin |X1⟩ ≈ (1)[TT] and quintet spin |Q⟩ ≈ (5)[TT]. It is shown that triplet pair states can be separated by a triplet-triplet energy-transfer mechanism to give a separated, yet entangled triplet pair (1)[T···T]. Independent triplets are produced by decoherence of the separated triplet pair. Recombination of independent triplets by exciton-exciton annihilation to form the correlated triplet pair (i.e., nongeminate recombination) happens with 1/3 of the rate of either triplet migration or recombination of the separated correlated triplet pair (geminate recombination).

  9. The Potential for Renewable Energy Development to Benefit Restoration of the Salton Sea. Analysis of Technical and Market Potential

    Energy Technology Data Exchange (ETDEWEB)

    Gagne, Douglas [National Renewable Energy Lab. (NREL), Golden, CO (United States); Haase, Scott [National Renewable Energy Lab. (NREL), Golden, CO (United States); Oakleaf, Brett [National Renewable Energy Lab. (NREL), Golden, CO (United States); Hurlbut, David [National Renewable Energy Lab. (NREL), Golden, CO (United States); Akar, Sertac [National Renewable Energy Lab. (NREL), Golden, CO (United States); Wall, Anna [National Renewable Energy Lab. (NREL), Golden, CO (United States); Turchi, Craig [National Renewable Energy Lab. (NREL), Golden, CO (United States); Pienkos, Philip [National Renewable Energy Lab. (NREL), Golden, CO (United States); Melius, Jennifer [National Renewable Energy Lab. (NREL), Golden, CO (United States); Melaina, Marc [National Renewable Energy Lab. (NREL), Golden, CO (United States)

    2015-11-01

    This report summarizes the potential for renewable energy development in the Salton Sea region, as well as the potential for revenues from this development to contribute financially to Salton Sea restoration costs. It considers solar, geothermal, biofuels or nutraceutical production from algae pond cultivation, desalination using renewable energy, and mineral recovery from geothermal fluids.


  10. Energy spectrum of oscillations in generalized Sagdeev potential

    Science.gov (United States)

    Akbari-Moghanjoughi, M.

    2017-07-01

    In this paper, the full energy spectrum of nonlinear oscillations, known as the cnoidal waves, is studied in the framework of small-amplitude Korteweg de Vries and modified Korteweg de Vries (mKdV) theories based on the pseudoparticle motion in Helmholtz and Duffing potentials by employing the newly introduced pseudoenergy concept. The pseudoenergy dependence of various cnoidal oscillation parameters is then studied, and it is shown that superposition of cnoidal waves leads to familiar beating and Lissajous profiles. One of the most important aspects of the nonlinear oscillation is found to be the frequency dependence of the oscillation amplitude which mainly characterizes the nature of oscillations. It is shown that the developed method can be used to study the spectrum of oscillations and shock waves in the fully nonlinear Sagdeev pseudopotential and to directly calculate many dynamic parameters of the given nonlinear system. Current research may be helpful in understanding of basic excitations and interaction of nonlinear oscillation in various hydrodynamic systems including plasmas. It is also shown that nonlinear excitations in a hydrodynamic fluid can be effectively investigated by close inspection of shock waves which contain the full nonlinear spectrum of dynamical systems.

  11. Rotational Energy Transfer of N2 Determined Using a New Ab Initio Potential Energy Surface

    Science.gov (United States)

    Huo, Winifred M.; Stallcop, James R.; Partridge, Harry; Langhoff, Stephen R. (Technical Monitor)

    1997-01-01

    A new N2-N2 rigid-rotor surface has been determined using extensive Ab Initio quantum chemistry calculations together with recent experimental data for the second virial coefficient. Rotational energy transfer is studied using the new potential energy surface (PES) employing the close coupling method below 200 cm(exp -1) and coupled state approximation above that. Comparing with a previous calculation based on the PES of van der Avoird et al.,3 it is found that the new PES generally gives larger cross sections for large (delta)J transitions, but for small (delta)J transitions the cross sections are either comparable or smaller. Correlation between the differences in the cross sections and the two PES will be attempted. The computed cross sections will also be compared with available experimental data.

  12. Ab initio potential energy surface and vibration-rotation energy levels of beryllium monohydroxide.

    Science.gov (United States)

    Koput, Jacek

    2017-01-05

    The accurate potential energy surface of beryllium monohydroxide, BeOH, in its ground electronic state X 2A' has been determined from ab initio calculations using the coupled-cluster approach in conjunction with the correlation-consistent core-valence basis sets up to septuple-zeta quality. The higher-order electron correlation, scalar relativistic, and adiabatic effects were taken into account. The BeOH molecule was confirmed to be bent at equilibrium, with the BeOH angle of 141.2° and the barrier to linearity of 129 cm -1 . The vibration-rotation energy levels of the BeOH and BeOD isotopologues were predicted using a variational approach and compared with recent experimental data. The results can be useful in a further analysis of high-resolution vibration-rotation spectra of these interesting species. © 2016 Wiley Periodicals, Inc. © 2016 Wiley Periodicals, Inc.

  13. Ab initio potential energy surface and vibration-rotation energy levels of sulfur dioxide.

    Science.gov (United States)

    Koput, Jacek

    2017-05-05

    An accurate potential energy surface of sulfur dioxide, SO 2 , in its ground electronic state X∼ 1A1 has been determined from ab initio calculations using the coupled-cluster approach in conjunction with the correlation-consistent basis sets up to septuple-zeta quality. The results obtained with the conventional and explicitly correlated coupled-cluster methods are compared. The role of the core-electron correlation, higher-order valence-electron correlation, scalar relativistic, and adiabatic effects in determining the structure and dynamics of the SO 2 molecule is discussed. The vibration-rotation energy levels of the 32 SO 2 and 34 SO 2 isotopologues were predicted using a variational approach. It was shown that the inclusion of the aforementioned effects was mandatory to attain the "spectroscopic" accuracy. © 2017 Wiley Periodicals, Inc. © 2017 Wiley Periodicals, Inc.

  14. The Potential of Renewable Energy Systems in China

    DEFF Research Database (Denmark)

    Liu, Wen; Lund, Henrik; Mathiesen, Brian Vad

    2009-01-01

    in China. The conclusion is such development is not impossible in the future in terms of technology and domestic resources. Due to the uncertainty of estimation and exploitation level of renewable energy sources, energy conservation and efficiency improvement are essential for China to achieving......This paper discusses the prospective of renewable energy in the process of sustainable development in China. Along with the high-speed economic development and increasing energy consumption, the Chinese Government faces a growing pressure to maintain the balance between energy supply and demand...... as well as reduce environmental pollution. To ensure energy security and mitigate climate changes the inappropriate energy consumption structure should be changed. As an alternative, a suitable infrastructure for the implementation of renewable energy may serve as a long-term sustainable possibility...

  15. Renewable energy: the potential opportunities and obligations of ...

    African Journals Online (AJOL)

    Renewable energy is generally recognised as a positive step on the pathway to sustainable development, but biomass-based renewable energy is becoming a controversial issue. In agriculture, the lure of first-generation biofuels is already distorting world food markets, energy crops such as sugar cane and oil palm ...

  16. Flavor-singlet spectrum in multi-flavor QCD

    Energy Technology Data Exchange (ETDEWEB)

    Aoki, Yasamichi; Rinaldi, Enrico

    2017-06-18

    Studying SU(3) gauge theories with increasing number of light fermions is relevant both for understanding the strong dynamics of QCD and for constructing strongly interacting extensions of the Standard Model (e.g. UV completions of composite Higgs models). In order to contrast these many-flavors strongly interacting theories with QCD, we study the flavor-singlet spectrum as an interesting probe. In fact, some composite Higgs models require the Higgs boson to be the lightest flavor-singlet scalar in the spectrum of a strongly interacting new sector with a well defined hierarchy with the rest of the states. Moreover, introducing many light flavors at fixed number of colors can influence the dynamics of the lightest flavor-singlet pseudoscalar. We present the on-going study of these flavor-singlet channels using multiple interpolating operators on high-statistics ensembles generated by the LatKMI collaboration and we compare results with available data obtained by the Lattice Strong Dynamics collaboration. For the theory with 8 flavors, the two collaborations have generated configurations that complement each others with the aim to tackle the massless limit using the largest possible volumes.

  17. Atmospheric and Solar Neutrinos with a Heavy Singlet

    CERN Document Server

    King, S F

    1998-01-01

    We follow a minimalistic approach to neutrino masses, by introducing a single heavy singlet $N$ into the standard model (or supersymmetric standard model) with a heavy Majorana mass $M$, which couples as a single right-handed neutrino in a Dirac fashion to leptons, and induces a single light see-saw mass $m_{\

  18. Bounds on neutrino mixing with exotic singlet neutrinos E

    Indian Academy of Sciences (India)

    This allows us to neglect the masses of light (known) neutrinos. In the SM the process occurs at tree level via light neutrino exchange in t- and u-channels. The neu- trino mixing in special cases (e.g. mixing of exotic and/or singlets), induces non-diagonal light–heavy neutrino neutral currents and additional contribution to the ...

  19. Singlet Oxygen Generation Mediated By Silicon Nanocrystal Assemblies

    Science.gov (United States)

    2011-01-01

    efficient red-orange emission under illumination by ultraviolet light appeared. Increase of the etching time results in significant increase of the...in the singlet oxygen-mediated oxidation of organic compounds K. Loponov, B. Goller, A. Moskalenko, D. Kovalev, A. Lapkin Journal of Photochemistry

  20. Real gauge singlet scalar extension of the Standard Model: A ...

    Indian Academy of Sciences (India)

    2013-03-05

    Mar 5, 2013 ... Abstract. The simplest extension of Standard Model (SM) is considered in which a real SM gauge singlet scalar with an additional discrete symmetry Z2 is introduced to SM. This additional scalar can be a viable candidate of cold dark matter (CDM) since the stability of S is achieved by the application of Z2 ...

  1. Explorative computational study of the singlet fission process

    NARCIS (Netherlands)

    Havenith, Remco W. A.; de Gier, Hilde D.; Broer, Ria

    2012-01-01

    Different ab initio methods, namely multi-reference and nonorthogonal configuration interaction techniques, are explored for their applicability in studying the singlet fission problem. It has been shown for 2-methyl-1,5-hexadiene that the (TT)-T-1 state can be identified using multi-reference

  2. Singlet oxygen reactions with flavonoids. A theoretical-experimental study.

    Directory of Open Access Journals (Sweden)

    Javier Morales

    Full Text Available Detection of singlet oxygen emission, λ(max = 1270 nm, following laser excitation and steady-state methods were employed to measure the total reaction rate constant, k(T, and the reactive reaction rate constant, k(r, for the reaction between singlet oxygen and several flavonoids. Values of k(T determined in deuterated water, ranging from 2.4×10(7 M(-1 s(-1 to 13.4×10(7 M(-1 s(-1, for rutin and morin, respectively, and the values measured for k(r, ranging from 2.8×10(5 M(-1 s(-1 to 65.7×10(5 M(-1 s(-1 for kaempferol and morin, respectively, being epicatechin and catechin chemically unreactive. These results indicate that all the studied flavonoids are good quenchers of singlet oxygen and could be valuable antioxidants in systems under oxidative stress, in particular if a flavonoid-rich diet was previously consumed. Analysis of the dependence of rate constant values with molecular structure in terms of global descriptors and condensed Fukui functions, resulting from electronic structure calculations, supports the formation of a charge transfer exciplex in all studied reactions. The fraction of exciplex giving reaction products evolves through a hydroperoxide and/or an endoperoxide intermediate produced by singlet oxygen attack on the double bond of the ring C of the flavonoid.

  3. Singlet oxygen reactions with flavonoids. A theoretical-experimental study.

    Science.gov (United States)

    Morales, Javier; Günther, Germán; Zanocco, Antonio L; Lemp, Else

    2012-01-01

    Detection of singlet oxygen emission, λ(max) = 1270 nm, following laser excitation and steady-state methods were employed to measure the total reaction rate constant, k(T), and the reactive reaction rate constant, k(r), for the reaction between singlet oxygen and several flavonoids. Values of k(T) determined in deuterated water, ranging from 2.4×10(7) M(-1) s(-1) to 13.4×10(7) M(-1) s(-1), for rutin and morin, respectively, and the values measured for k(r), ranging from 2.8×10(5) M(-1) s(-1) to 65.7×10(5) M(-1) s(-1) for kaempferol and morin, respectively, being epicatechin and catechin chemically unreactive. These results indicate that all the studied flavonoids are good quenchers of singlet oxygen and could be valuable antioxidants in systems under oxidative stress, in particular if a flavonoid-rich diet was previously consumed. Analysis of the dependence of rate constant values with molecular structure in terms of global descriptors and condensed Fukui functions, resulting from electronic structure calculations, supports the formation of a charge transfer exciplex in all studied reactions. The fraction of exciplex giving reaction products evolves through a hydroperoxide and/or an endoperoxide intermediate produced by singlet oxygen attack on the double bond of the ring C of the flavonoid.

  4. Flavor-singlet spectrum in multi-flavor QCD

    Science.gov (United States)

    Aoki, Yasumichi; Aoyama, Tatsumi; Bennett, Ed; Kurachi, Masafumi; Maskawa, Toshihide; Miura, Kohtaroh; Nagai, Kei-ichi; Ohki, Hiroshi; Rinaldi, Enrico; Shibata, Akihiro; Yamawaki, Koichi; Yamazaki, Takeshi

    2018-03-01

    Studying SU(3) gauge theories with increasing number of light fermions is relevant both for understanding the strong dynamics of QCD and for constructing strongly interacting extensions of the Standard Model (e.g. UV completions of composite Higgs models). In order to contrast these many-flavors strongly interacting theories with QCD, we study the flavor-singlet spectrum as an interesting probe. In fact, some composite Higgs models require the Higgs boson to be the lightest flavor-singlet scalar in the spectrum of a strongly interacting new sector with a well defined hierarchy with the rest of the states. Moreover, introducing many light flavors at fixed number of colors can influence the dynamics of the lightest flavor-singlet pseudoscalar. We present the on-going study of these flavor-singlet channels using multiple interpolating operators on high-statistics ensembles generated by the LatKMI collaboration and we compare results with available data obtained by the Lattice Strong Dynamics collaboration. For the theory with 8 flavors, the two collaborations have generated configurations that complement each others with the aim to tackle the massless limit using the largest possible volumes.

  5. Label-free electrochemical detection of singlet oxygen protein damage

    Czech Academy of Sciences Publication Activity Database

    Vargová, Veronika; Gimenez, R.E.; Černocká, Hana; Trujillo, D.C.; Tulli, F.; Zanini, V.I.P.; Paleček, Emil; Borsarelli, C.D.; Ostatná, Veronika

    2016-01-01

    Roč. 187, JAN 2016 (2016), s. 662-669 ISSN 0013-4686 R&D Projects: GA ČR GA13-00956S Institutional support: RVO:68081707 Keywords : singlet oxygen protein damage * surface-attached protein stability * mercury and carbon electrodes Subject RIV: BO - Biophysics Impact factor: 4.798, year: 2016

  6. Delayed fluorescence from upper excited singlet states of aromatic ketones

    International Nuclear Information System (INIS)

    Nickel, B.; Roden, G.

    1980-01-01

    With liquid solutions of the aromatic ketones anthraquinone and xanthone, a P-type delayed fluorescence from upper excited singlet states, resulting from triplet-triplet annihilation, has been observed. Some peculiarities of the triplet-triplet annihilation of aromatic ketones are discussed. (orig.)

  7. Computed Potential Energy Surfaces and Minimum Energy Pathway for Chemical Reactions

    Science.gov (United States)

    Walch, Stephen P.; Langhoff, S. R. (Technical Monitor)

    1994-01-01

    Computed potential energy surfaces are often required for computation of such observables as rate constants as a function of temperature, product branching ratios, and other detailed properties. We have found that computation of the stationary points/reaction pathways using CASSCF/derivative methods, followed by use of the internally contracted CI method with the Dunning correlation consistent basis sets to obtain accurate energetics, gives useful results for a number of chemically important systems. Applications to complex reactions leading to NO and soot formation in hydrocarbon combustion are discussed.

  8. Evaluation of Potential Locations for Siting Small Modular Reactors near Federal Energy Clusters to Support Federal Clean Energy Goals

    Energy Technology Data Exchange (ETDEWEB)

    Belles, Randy J. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Omitaomu, Olufemi A. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2014-09-01

    Geographic information systems (GIS) technology was applied to analyze federal energy demand across the contiguous US. Several federal energy clusters were previously identified, including Hampton Roads, Virginia, which was subsequently studied in detail. This study provides an analysis of three additional diverse federal energy clusters. The analysis shows that there are potential sites in various federal energy clusters that could be evaluated further for placement of an integral pressurized-water reactor (iPWR) to support meeting federal clean energy goals.

  9. Morphological Tuning of the Energetics in Singlet Fission Organic Solar Cells

    NARCIS (Netherlands)

    Lin, Yun Hui L; Fusella, Michael A.; Kozlov, Oleg V.; Lin, Xin; Kahn, Antoine; Pshenichnikov, Maxim S.; Rand, Barry P.

    2016-01-01

    Effective singlet fission solar cells require both fast and efficient singlet fission as well as favorable energetics for harvesting the resulting triplet excitons. Notable progress has been made to engineer materials with rapid and efficient singlet fission, but the ability to control the

  10. Sea quark matrix elements and flavor singlet spectroscopy on the lattice

    International Nuclear Information System (INIS)

    Lagae, J.F.

    1996-01-01

    I summarize the results of three recent lattice studies which use stochastic estimator techniques in order to investigate the flavor singlet dynamics in QCD. These include a measurement of the pion-nucleon σ-term, the computation of the flavor singlet axial coupling constant of the nucleon and a determination of flavor singlet meson screening lengths in finite temperature QCD

  11. Status and potential of nuclear energy in Pakistan

    International Nuclear Information System (INIS)

    Khan, A.M.; Jalal, A.I.

    1991-01-01

    Pakistan is an energy resource deficient country which is heavily dependent on imported energy, while its per capita energy consumption level is still very low. Energy and electricity needs have been growing rapidly and these trends are expected to continue. Pakistan needs to make use of nuclear power on a large scale. This paper discusses the limitations of indigenous energy resources in coping with the future requirements of electricity and compares the cost economics of nuclear power with that of electricity generation based on imported oil and coal. It then describes the efforts being made in the country to make use of nuclear power in a self-reliant manner. (author)

  12. Geothermal energy: potential applications to diversify the energy matrix of Uruguay

    International Nuclear Information System (INIS)

    Cernuschi, F.

    2014-01-01

    The Geothermal energy is a promising renewable energy source due to the low to null CO2 emissions and the stability of energy production. In Uruguay, high geothermal gradients related to magmatism are extinct since the Cretaceous, limiting its geothermal potential. However, a moderate geothermal gradient in northwest Uruguay is estimated at an average of ∼ 28.6 oC/km. Here, thermally insolating Cretaceous flood basalts confine aquifers in Carboniferous to Jurassic sedimentary rocks of the Parana basin. In this area geothermal applications are possible: 1) The over-pressurized, warm waters of the Guarani Aquifer System (∼45°, >1000 m), presently only used by the tourism industry, could be used for domestic or industrial heating (eg. greenhouses) to reduce the consumption of energy from other sources. 2) Waters from possibly deeper Carboniferous-Permian aquifers (≤75 °C, ∼2300 m), may allow the generation of electricity using binary power plants cooled by superficial cold water. If these or other sedimentary rocks extend deeper (≤150 °C, ∼4500 m), conventional binary plants could contribute to the national energy demand. 3) If viable, creating an enhanced geothermal systems in the granitic basement, below 5000 m depth, could also enable the generation of significant amounts of electricity with binary plants. To develop these scenarios, detailed research of the geothermal gradient and its variations at depths, the stratigraphy and structural geology of the Parana basin, the hydrogeology of its aquifers and the localization of granitic intrusions on the basement are needed. All the above, have yet to be systematically and comprehensively studied

  13. The potential energy conservation of the Dutch industrial, business and service sector

    International Nuclear Information System (INIS)

    Van der Werff, R.L.; Opschoor, J.B.

    1992-01-01

    The database ICARUS has been used as a starting point to estimate the economical potential for energy conservation in different sectors of the Dutch society. ICARUS is based on research on real energy consuming processes and applications in a number of sub-sectors of the Dutch economy. The present energy conservation potential in the Netherlands is based on energy conservation studies in the Netherlands and other countries. For this article the economical efficient energy conservation potentials in 1992 have been investigated for the Dutch sectors, which do not supply energy. The potentials are determined on the basis of the technical energy conservation potentials for the year 2000, according to the database ICARUS. Two methods were used to extract the economic potential from the technical potential: the method of the Net Market Value and the method of the payback period. From the ICARUS analysis it appears that the technical potential for energy conservation is 479 PJ, which is 28.8% of the primary energy consumption of 1664 PJ in 1985. The economic energy conservation potential is 262 PJ for a payback period of less than five years, which is 17% of the 1985 primary energy consumption. Next to the above-mentioned analysis policy-aimed simulations were carried out for three scenarios to determine economical energy conservation potentials. In one scenario doubled energy prices were used in comparison with the 1991 prices. Another scenario uses the Net Market Value method with a 5% discount rate, and the third scenario uses both parameters

  14. Precision of total energy and orbital energies with the expansion method for the optimized effective Kohn-Sham potential

    NARCIS (Netherlands)

    Rohr, D.; Gritsenko, O.V.; Baerends, E.J.

    2006-01-01

    For functionals that depend on the Kohn-Sham orbitals, the optimized effective potential method (OEP) of density functional theory (DFT) seeks a lowest energy solution by finding that particular local potential v

  15. Sustainable development - the potential contribution of nuclear energy

    International Nuclear Information System (INIS)

    Bourdier, Jean-Pierre; Barre, Bertrand; Durret, Louis-Francois

    1998-01-01

    Sustainable development combines development, durability and sustainability. Energy is crucial for development: it brings work, nutrition, health, security, community, etc. Electrical energy offers the most possibilities for the consumer, particularly as regards the problems of pollution on the site of consumption. Nuclear generation is one of the best ways of producing electricity. Midway between stock energies and flow energies, it has several advantages: low consumption of resources, safety, compactness and cleanliness. Waste is not a specifically nuclear problem: it should be considered in terms of a life cycle analysis; construction, dismantling and functioning have to be assessed. The size of certain energies' contribution to the greenhouse effect is therefore made clear. Reprocessing represents a saving of energy, without environmental or health damage. It contributes to energy control, and therefore to sustainable development

  16. Power from Perspective: Potential future United States energy portfolios

    Energy Technology Data Exchange (ETDEWEB)

    Tonn, Bruce [University of Tennessee, Knoxville 37831-6038 (United States)], E-mail: btonn@utk.edu; Healy, K.C. [Deloitte Touche (United States); Gibson, Amy [University of Tennessee, Knoxville 37831-6038 (United States); Ashish, Ashutosh [Independent Consultant (United States); Cody, Preston; Beres, Drew [Deloitte Touche (United States); Lulla, Sam; Mazur, Jim [Independent Consultant (United States); Ritter, A.J. [Deloitte Touche (United States)

    2009-04-15

    This paper presents United States energy portfolios for the year 2030, developed from seven different Perspectives. The Perspectives are characterized by different weights placed on fourteen defining values (e.g., cost, social acceptance). The portfolios were constructed to achieve three primary goals, energy independence, energy security, and greenhouse gas reductions. The portfolios are also evaluated over a comprehensive set of secondary criteria (e.g., economic growth, technical feasibility). It is found that very different portfolios based on very different defining values can achieve the three primary goals. Commonalities among the portfolios include reliance upon cellulosic ethanol, nuclear power, and energy efficiency to meet year 2030 energy demands. It is concluded that the US energy portfolio must be diverse and to achieve national energy goals will require an explicit statement of goals, a strong role for government, and coordinated action across society.

  17. Power from Perspective. Potential future United States energy portfolios

    Energy Technology Data Exchange (ETDEWEB)

    Tonn, Bruce; Gibson, Amy [University of Tennessee, Knoxville 37831-6038 (United States); Healy, K.C.; Cody, Preston; Beres, Drew; Ritter, A.J. [Deloitte Touche (United States); Ashish, Ashutosh; Lulla, Sam; Mazur, Jim [Independent Consultant (United States)

    2009-04-15

    This paper presents United States energy portfolios for the year 2030, developed from seven different Perspectives. The Perspectives are characterized by different weights placed on fourteen defining values (e.g., cost, social acceptance). The portfolios were constructed to achieve three primary goals, energy independence, energy security, and greenhouse gas reductions. The portfolios are also evaluated over a comprehensive set of secondary criteria (e.g., economic growth, technical feasibility). It is found that very different portfolios based on very different defining values can achieve the three primary goals. Commonalities among the portfolios include reliance upon cellulosic ethanol, nuclear power, and energy efficiency to meet year 2030 energy demands. It is concluded that the US energy portfolio must be diverse and to achieve national energy goals will require an explicit statement of goals, a strong role for government, and coordinated action across society. (author)

  18. French Brittany macroalgae screening: composition and methane potential for potential alternative sources of energy and products.

    Science.gov (United States)

    Jard, G; Marfaing, H; Carrère, H; Delgenes, J P; Steyer, J P; Dumas, C

    2013-09-01

    Macroalgae are biomass resources that represent a valuable feedstock to be used entirely for human consumption or for food additives after some extractions (mainly colloids) and/or for energy production. In order to better develop the algal sector, it is important to determine the capacity of macroalgae to produce these added-values molecules for food and/or for energy industries on the basis of their biochemical characteristics. In this study, ten macroalgae obtained from French Brittany coasts (France) were selected. The global biochemical composition (proteins, lipids, carbohydrates, fibers), the presence and characteristics of added-values molecules (alginates, polyphenols) and the biochemical methane potential of these algae were determined. Regarding its biochemical composition, Palmaria palmata is interesting for food (rich in nutrients) and for anaerobic digestion (0.279 LCH4/gVS). Saccharina latissima could be used for alginate extraction (242 g/kgTS, ratio between mannuronic and guluronic acid M/G=1.4) and Sargassum muticum for polyphenol extraction (19.8 g/kgTS). Copyright © 2013 Elsevier Ltd. All rights reserved.

  19. Singlet-triplet annihilation in single LHCII complexes.

    Science.gov (United States)

    Gruber, J Michael; Chmeliov, Jevgenij; Krüger, Tjaart P J; Valkunas, Leonas; van Grondelle, Rienk

    2015-08-14

    In light harvesting complex II (LHCII) of higher plants and green algae, carotenoids (Cars) have an important function to quench chlorophyll (Chl) triplet states and therefore avoid the production of harmful singlet oxygen. The resulting Car triplet states lead to a non-linear self-quenching mechanism called singlet-triplet (S-T) annihilation that strongly depends on the excitation density. In this work we investigated the fluorescence decay kinetics of single immobilized LHCIIs at room temperature and found a two-exponential decay with a slow (3.5 ns) and a fast (35 ps) component. The relative amplitude fraction of the fast component increases with increasing excitation intensity, and the resulting decrease in the fluorescence quantum yield suggests annihilation effects. Modulation of the excitation pattern by means of an acousto-optic modulator (AOM) furthermore allowed us to resolve the time-dependent accumulation and decay rate (∼7 μs) of the quenching species. Inspired by singlet-singlet (S-S) annihilation studies, we developed a stochastic model and then successfully applied it to describe and explain all the experimentally observed steady-state and time-dependent kinetics. That allowed us to distinctively identify the quenching mechanism as S-T annihilation. Quantitative fitting resulted in a conclusive set of parameters validating our interpretation of the experimental results. The obtained stochastic model can be generalized to describe S-T annihilation in small molecular aggregates where the equilibration time of excitations is much faster than the annihilation-free singlet excited state lifetime.

  20. The fractional virial potential energy in two-component systems

    Directory of Open Access Journals (Sweden)

    Caimmi R.

    2008-01-01

    Full Text Available Two-component systems are conceived as macrogases, and the related equation of state is expressed using the virial theorem for subsystems, under the restriction of homeoidally striated density profiles. Explicit calculations are performed for a useful reference case and a few cases of astrophysical interest, both with and without truncation radius. Shallower density profiles are found to yield an equation of state, φ = φ(y, m, characterized (for assigned values of the fractional mass, m = Mj /Mi by the occurrence of two extremum points, a minimum and a maximum, as found in an earlier attempt. Steeper density profiles produce a similar equation of state, which implies that a special value of m is related to a critical curve where the above mentioned extremum points reduce to a single horizontal inflexion point, and curves below the critical one show no extremum points. The similarity of the isofractional mass curves to van der Waals' isothermal curves, suggests the possibility of a phase transition in a bell-shaped region of the (Oyφ plane, where the fractional truncation radius along a selected direction is y = Rj /Ri , and the fractional virial potential energy is φ = (Eji vir /(Eij vir . Further investigation is devoted to mass distributions described by Hernquist (1990 density profiles, for which an additional relation can be used to represent a sample of N = 16 elliptical galaxies (EGs on the (Oyφ plane. Even if the evolution of elliptical galaxies and their hosting dark matter (DM haloes, in the light of the model, has been characterized by equal fractional mass, m, and equal scaled truncation radius, or concentration, Ξu = Ru /r† , u = i, j, still it cannot be considered as strictly homologous, due to different values of fractional truncation radii, y, or fractional scaling radii, y† = r† /r† , deduced from sample objects.