Tank characterization report for single-shell tank 241-S-111

International Nuclear Information System (INIS)

Conner, J.M.

1997-01-01

One of the major functions of the Tank Waste Remediation System (TWRS) is to characterize wastes in support of waste management and disposal activities at the Hanford Site. Analytical data from sampling and analysis, along with other available information about a tank, are compiled and maintained in a tank characterization report (TCR). This report and its appendices serve as the TCR for single-shell tank 241-S-111. The objectives of this report are: (1) to use characterization data to address technical issues associated with tank 241-S-111 waste; and (2) to provide a standard characterization of this waste in terms of a best-basis inventory estimate. The response to technical issues is summarized in Section 2.0, and the best-basis inventory estimate is presented in Section 3.0. Recommendations regarding safety status and additional sampling needs are provided in Section 4.0. Supporting data and information are contained in the appendices. This report also supports the requirements of Hanford Federal Facility Agreement and Consent Order (Ecology et al. 1996) milestone M-44-10

Tank characterization report for single-shell tank 241-S-111

Energy Technology Data Exchange (ETDEWEB)

Conner, J.M.

1997-04-28

One of the major functions of the Tank Waste Remediation System (TWRS) is to characterize wastes in support of waste management and disposal activities at the Hanford Site. Analytical data from sampling and analysis, along with other available information about a tank, are compiled and maintained in a tank characterization report (TCR). This report and its appendices serve as the TCR for single-shell tank 241-S-111. The objectives of this report are: (1) to use characterization data to address technical issues associated with tank 241-S-111 waste; and (2) to provide a standard characterization of this waste in terms of a best-basis inventory estimate. The response to technical issues is summarized in Section 2.0, and the best-basis inventory estimate is presented in Section 3.0. Recommendations regarding safety status and additional sampling needs are provided in Section 4.0. Supporting data and information are contained in the appendices. This report also supports the requirements of Hanford Federal Facility Agreement and Consent Order (Ecology et al. 1996) milestone M-44-10.

Tank characterization report for single-shell tank 241-U-103

Energy Technology Data Exchange (ETDEWEB)

SASAKI, L.M.

1999-02-24

A major function of the Tank Waste Remediation System (TWRS) is to characterize waste in support of waste management and disposal activities at the Hanford Site. Analytical data from sampling and analysis and other available information about a tank are compiled and maintained in a tank characterization report. This report and its appendices serve as the tank characterization report for single-shell tank 241-U-103. The objectives of this report are (1) to use characterization data in response to technical issues associated with tank 241-U-103 waste and (2) to provide a standard characterization of this waste in terms of a best-basis inventory estimate. Section 2.0 summarizes the response to technical issues, Section 3.0 shows the best-basis inventory estimate, Section 4.0 makes recommendations about the safety status of the tank and additional sampling needs. The appendices contain supporting data and information. This report supports the requirements of the Hanford Federal Facility Agreement and Consent Order (Ecology et al. 1997), Milestone M-44-15b, change request M-44-97-03 to ''issue characterization deliverables consistent with Waste Information Requirements Documents developed for 1998.''

Hanford Single-Shell Tank Leak Causes and Locations - 241-C Farm

Energy Technology Data Exchange (ETDEWEB)

Girardot, Crystal L.; Harlow, Donald G.

2013-07-30

This document identifies 241-C Tank Farm (C Farm) leak causes and locations for the 100 series leaking tanks (241-C-101 and 241-C-105) identified in RPP-RPT-33418, Rev. 2, Hanford C-Farm Leak Inventory Assessments Report. This document satisfies the C Farm portion of the target (T04) in the Hanford Federal Facility Agreement and Consent Order milestone M-045-91F.

Tank characterization report for single-shell tank 241-T-105

International Nuclear Information System (INIS)

Field, J.G.

1998-01-01

A major function of the Tank Waste Remediation System (TWRS) is to characterize waste in support of waste management and disposal activities at the Hanford Site. Analytical data from sampling and analysis and other available information about a tank are compiled and maintained in a tank characterization report (TCR). This report and its appendices serve as the TCR for single-shell tank 241-T-105. The objectives of this report are (1) to use characterization data in response to technical issues associated with tank 241-T-105 waste and (2) to provide a standard characterization of this waste in terms of a best-basis inventory estimate. Section 2.0 summarizes the response to technical issues, Section 3.0 shows the best-basis inventory estimate, Section 4.0 makes recommendations about the safety status of the tank and additional sampling needs. The appendices contain supporting data and information. This report supports the requirements of the Hanford Federal Facility Agreement and Consent Order (Ecology et al. 1997), Milestone M-44-15b, change request M-44-97-03, to ''issue characterization deliverables consistent with the waste information requirements documents developed for 1998''

Tank characterization report for single-shell tank 241-U-112

International Nuclear Information System (INIS)

Field, J.G.

1998-01-01

A major function of the Tank Waste Remediation System (TWRS) is to characterize waste in support of waste management and disposal activities at the Hanford Site. Analytical data from sampling and analysis and other available information about a tank are compiled and maintained in a tank characterization report (TCR). This report and its appendixes serve as the TCR for single-shell tank 241-U-112. The objectives of this report are (1) to use characterization data in response to technical issues associated with tank 241-U-112 waste, and (2) to provide a standard characterization of this waste in terms of a best-basis inventory estimate. Section 2.0 summarizes the response to technical issues, Section 3.0 shows the best-basis inventory estimate, Section 4.0 makes recommendations about the safety status of the tank and additional sampling needs. The appendixes contain supporting data and information. This report supports the requirements of the Hanford Federal Facility Agreement and Consent Order (Ecology et al. 1997), Milestone M-44-15b, change request M-44-97-03 to issue characterization deliverables consistent with the Waste Information Requirements Document developed for 1998

Tank characterization report for single-shell tank 241-T-112

International Nuclear Information System (INIS)

McCain, D.J.

1998-01-01

A major function of the Tank Waste Remediation System (TWRS) is to characterize waste in support of waste management and disposal activities at the Hanford Site. Analytical data from sampling and analysis and other available information about a tank are compiled and maintained in a tank characterization report (TCR). This report and its appendices serve as the TCR for single-shell tank 241-T-112. The objectives of this report are (1) to use characterization data in response to technical issues associated with tank 241-T-112 waste and (2) to provide a standard characterization of this waste in terms of a best-basis inventory estimate. Section 2.0 summarizes the response to technical issues, Section 3.0 shows the best-basis inventory estimate, Section 4.0 makes recommendations about the safety status of the tank and additional sampling needs. The appendices contain supporting data and information. This report supports the requirements of the Hanford Federal Facility Agreement and Consent Order (Ecology et al. 1997), Milestone M-44-15b, change request M-44-97-03, to ''issue characterization deliverables consistent with the Waste Information Requirements Documents developed for 1998.''

Tank characterization report for single-shell tank 241-T-105

Energy Technology Data Exchange (ETDEWEB)

Field, J.G.

1998-06-18

A major function of the Tank Waste Remediation System (TWRS) is to characterize waste in support of waste management and disposal activities at the Hanford Site. Analytical data from sampling and analysis and other available information about a tank are compiled and maintained in a tank characterization report (TCR). This report and its appendices serve as the TCR for single-shell tank 241-T-105. The objectives of this report are (1) to use characterization data in response to technical issues associated with tank 241-T-105 waste and (2) to provide a standard characterization of this waste in terms of a best-basis inventory estimate. Section 2.0 summarizes the response to technical issues, Section 3.0 shows the best-basis inventory estimate, Section 4.0 makes recommendations about the safety status of the tank and additional sampling needs. The appendices contain supporting data and information. This report supports the requirements of the Hanford Federal Facility Agreement and Consent Order (Ecology et al. 1997), Milestone M-44-15b, change request M-44-97-03, to ``issue characterization deliverables consistent with the waste information requirements documents developed for 1998``.

Tank characterization report for single-shell tank 241-S-104

International Nuclear Information System (INIS)

Jo, J.

1997-01-01

One of the major functions of the Tank Waste Remediation System (TWRS) is to characterize wastes in support of waste management and disposal activities at the Hanford Site. Analytical data from sampling and analysis, along with other available information about a tank, are compiled and maintained in a tank characterization report (TCR). This report and its appendixes serve as the TCR for single-shell tank 241-S-104. The objectives of this report are: (1) to use characterization data in response to technical issues associated with 241-S- 104 waste; and (2) to provide a standard characterization of this waste in terms of a best-basis inventory estimate. The response to technical issues is summarized in Section 2.0, and the best-basis inventory estimate is presented in Section 3.0. Recommendations regarding safety status and additional sampling needs are provided in Section 4.0. Supporting data and information are contained in the appendixes. This report also supports the requirements of the Hanford Federal Facility Agreement and Consent Order (Ecology et al. 1996) milestone M-44-05

Tank characterization report for single-shell tanks 241-T-201, 241-T-202, 241-T-203, and 241-T-204

International Nuclear Information System (INIS)

Simpson, B.C.

1998-01-01

A major function of the Tank Waste Remediation System (TWRS) is to characterize waste in support of waste management and disposal activities at the Hanford Site. Analytical data from sampling and analysis, in addition to other available information about a tank are compiled and maintained in a tank characterization report (TCR). This report and its appendices serve as the TCR for the single-shell tank series consisting of 241-T-201, -T-202, -T-203, and -T-204. The objectives of this report are: (1) to use characterization data in response to technical issues associated with T-200 series tank waste and (2) to provide a standard characterization of this waste in terms of a best-basis inventory estimate. Section 2.0 summarizes the response to technical issues, Section 3.0 shows the best-basis inventory estimate, Section 4.0 makes recommendations about the safety status of the tank and additional sampling needs. The appendices contain supporting data and information. Appendix A contains historical information for 241-T-201 to T-204, including surveillance information, records pertaining to waste transfers and tank operations, and expected tank contents derived from a process knowledge-based computer program. Appendix B summarizes sampling events, sample data obtained before 1989, and the most current sampling results. Appendix C reports the statistical analysis and numerical manipulation of data used in issue resolution. Appendix D contains the evaluation to establish the best-basis for the inventory estimate and the statistical analysis performed for this evaluation. Appendix E is a bibliography that resulted from an in-depth literature search of all known information sources applicable to tanks 241-T-201, -T-202, -T-203, and -T-204. The reports listed in Appendix E are available in the Tank Characterization and Safety Resource Center

Tank characterization report for single-shell tank 241-C-204

International Nuclear Information System (INIS)

Conner, J.M.

1996-01-01

This document summarizes the information on the historical uses, present status, and the sampling and analysis results of waste stored in Tank 241-C-204. This report supports the requirements of Tri Party Agreement Milestone M 44 09

Tank characterization report for single-shell tank 241-T-102

International Nuclear Information System (INIS)

Baldwin, J.H.

1997-01-01

A major function of the Tank Waste Remediation System (TWRS) is to characterize wastes in support of waste management and disposal activities at the Hanford Site. Analytical data from sampling and analysis, along with other available information about a tank, are compiled and maintained in a tank characterization report (TCR). This report and its appendixes serve as the TCR for single-shell tank 241-T-102. The objectives of this report are to use characterization data in response to technical issues associated with tank 241-T-102 waste; and to provide a standard characterization of this waste in terms of a best-basis inventory estimate. The response to technical issues is summarized in Section 2.0, and the best-basis inventory estimate is presented in Section 3.0. Recommendations regarding safety status and additional sampling needs are provided in Section 4.0. Supporting data and information are contained in the appendixes. This report supports the requirements of the Hanford Federal Facility Agreement and Consent Order milestone M-44-05. Characterization information presented in this report originated from sample analyses and known historical sources. The most recent core sampling of tank 241-T-102 (March 1993) predated the existence of data quality objectives (DQOs). An assessment of the technical issues from the currently applicable DQOs was made using data from the 1993 push mode core sampling event, a July 1994 grab sampling event, and a May 1996 vapor flammability measurement. Historical information for tank 241-T-102, provided in Appendix A, includes surveillance information, records pertaining to waste transfers and tank operations, and expected tank contents derived from a process knowledge model. Appendix B contains further sampling and analysis data from the March 1993 push mode core sampling event and data from the grab sampling event in August 1994 and May 1996 vapor flammability measurement. Of the two push mode cores taken in March of 1993, cores 55

Tank characterization report for single-shell tank 241-T-102

Energy Technology Data Exchange (ETDEWEB)

Baldwin, J.H.

1997-06-24

A major function of the Tank Waste Remediation System (TWRS) is to characterize wastes in support of waste management and disposal activities at the Hanford Site. Analytical data from sampling and analysis, along with other available information about a tank, are compiled and maintained in a tank characterization report (TCR). This report and its appendixes serve as the TCR for single-shell tank 241-T-102. The objectives of this report are to use characterization data in response to technical issues associated with tank 241-T-102 waste; and to provide a standard characterization of this waste in terms of a best-basis inventory estimate. The response to technical issues is summarized in Section 2.0, and the best-basis inventory estimate is presented in Section 3.0. Recommendations regarding safety status and additional sampling needs are provided in Section 4.0. Supporting data and information are contained in the appendixes. This report supports the requirements of the Hanford Federal Facility Agreement and Consent Order milestone M-44-05. Characterization information presented in this report originated from sample analyses and known historical sources. The most recent core sampling of tank 241-T-102 (March 1993) predated the existence of data quality objectives (DQOs). An assessment of the technical issues from the currently applicable DQOs was made using data from the 1993 push mode core sampling event, a July 1994 grab sampling event, and a May 1996 vapor flammability measurement. Historical information for tank 241-T-102, provided in Appendix A, includes surveillance information, records pertaining to waste transfers and tank operations, and expected tank contents derived from a process knowledge model. Appendix B contains further sampling and analysis data from the March 1993 push mode core sampling event and data from the grab sampling event in August 1994 and May 1996 vapor flammability measurement. Of the two push mode cores taken in March of 1993, cores 55

Hanford Single-Shell Tank Leak Causes and Locations - 241-SX Farm

International Nuclear Information System (INIS)

Girardot, Crystal L.; Harlow, Donald G.

2014-01-01

This document identifies 241-SX Tank Farm (SX Farm) leak causes and locations for the 100 series leaking tanks (241-SX-107, 241-SX-108, 241-SX-109, 241-SX-111, 241-SX-112, 241-SX-113, 241-SX-114, and 241-SX-115) identified in RPP-ENV-39658, Rev. 0, Hanford SX-Farm Leak Assessments Report. This document satisfies the SX Farm portion of the target (T04) in the Hanford Federal Facility Agreement and Consent Order milestone M-045-91F

Hanford Single-Shell Tank Leak Causes and Locations - 241-SX Farm

Energy Technology Data Exchange (ETDEWEB)

Girardot, Crystal L. [Washington River Protection Solutions (United States); Harlow, Donald G. [Washington River Protection Solutions (United States)

2014-01-08

This document identifies 241-SX Tank Farm (SX Farm) leak causes and locations for the 100 series leaking tanks (241-SX-107, 241-SX-108, 241-SX-109, 241-SX-111, 241-SX-112, 241-SX-113, 241-SX-114, and 241-SX-115) identified in RPP-ENV-39658, Rev. 0, Hanford SX-Farm Leak Assessments Report. This document satisfies the SX Farm portion of the target (T04) in the Hanford Federal Facility Agreement and Consent Order milestone M-045-91F.

Preliminary tank characterization report for single-shell tank 241-TX-101: best-basis inventory

International Nuclear Information System (INIS)

Kupfer, M.J.

1997-01-01

This document is a preliminary Tank Characterization Report (TCR). It only contains the current best-basis inventory (Appendix D) for single-shell tank 241-TX-101. No TCRs have been previously issued for this tank, and current core sample analyses are not available. The best-basis inventory, therefore, is based on an engineering assessment of waste type, process flowsheet data, early sample data, and/or other available information. The Standard Inventories of Chemicals and Radionuclides in Hanford Site Tank Wastes describes standard methodology used to derive the tank-by-tank best-basis inventories. This preliminary TCR will be updated using this same methodology when additional data on tank contents become available

Preliminary tank characterization report for single-shell tank 241-TY-102: best-basis inventory

International Nuclear Information System (INIS)

Place, D.E.

1997-01-01

This document is a preliminary Tank Characterization Report (TCR). It only contains the current best-basis inventory (Appendix D) for single-shell tank 241-TY-102. No TCRs have been previously issued for this tank, and current core sample analyses are not available. The best-basis inventory, therefore, is based on an engineering assessment of waste type, process flowsheet data, early sample data, and/or other available information. The Standard Inventories of Chemicals and Radionuclides in Hanford Site Tank Wastes describes standard methodology used to derive the tank-by-tank best-basis inventories. This preliminary TCR will be updated using this same methodology when additional data on tank contents become available

Preliminary tank characterization report for single-shell tank 241-TX-113: best-basis inventory

International Nuclear Information System (INIS)

Place, D.E.

1997-01-01

This document is a preliminary Tank Characterization Report (TCR). It only contains the current best-basis inventory (Appendix D) for single-shell tank 241-TX-113. No TCRs have been previously issued for this tank, and current core sample analyses are not available. The best-basis inventory, therefore, is based on an engineering assessment of waste type, process flowsheet data, early sample data, and/or other available information. The Standard Inventories of Chemicals and Radionuclides in Hanford Site Tank Wastes describes standard methodology used to derive the tank-by-tank best-basis inventories. This preliminary TCR will be updated using this same methodology when additional data on tank contents become available

Single-Shell Tank (SST) Retrieval Project Plan for Tank 241-C-104 Retrieval

International Nuclear Information System (INIS)

DEFIGH PRICE, C.

2000-01-01

In support of the SST Interim Closure Project, Project W-523 ''Tank 241-C-104 Waste Retrieval System'' will provide systems for retrieval and transfer of radioactive waste from tank 241-C-104 (C-104) to the DST staging tank 241-AY-101 (AY-101). At the conclusion of Project W-523, a retrieval system will have been designed and tested to meet the requirements for Acceptance of Beneficial Use and been turned over to operations. Completion of construction and operations of the C-104 retrieval system will meet the recently proposed near-term Tri-Party Agreement milestone, M-45-03F (Proposed Tri-Party Agreement change request M-45-00-01A, August, 30 2000) for demonstrating limits of retrieval technologies on sludge and hard heels in SSTs, reduce near-term storage risks associated with aging SSTs, and provide feed for the tank waste treatment plant. This Project Plan documents the methodology for managing Project W-523; formalizes responsibilities; identifies key interfaces required to complete the retrieval action; establishes the technical, cost, and schedule baselines; and identifies project organizational requirements pertaining to the engineering process such as environmental, safety, quality assurance, change control, design verification, testing, and operational turnover

Ventilation system consequence calculations to support salt well pumping single-shell tank 241-A-101

Energy Technology Data Exchange (ETDEWEB)

Ryan, G.W.

1997-05-07

This document presents the radiological dose and toxicological exposure calculations for an accident scenario involved with the ventilation system used to support salt well pumping single-shell tank 241-A-101. This tank has been listed on the Hydrogen Watch List.

Ventilation system consequence calculations to support salt well pumping single-shell tank 241-A-101

International Nuclear Information System (INIS)

Ryan, G.W.

1997-01-01

This document presents the radiological dose and toxicological exposure calculations for an accident scenario involved with the ventilation system used to support salt well pumping single-shell tank 241-A-101. This tank has been listed on the Hydrogen Watch List

Tank characterization report for Single-Shell Tank 241-BX-107

International Nuclear Information System (INIS)

Raphael, G.F.

1994-09-01

This study examined and assessed the status, safety issues, composition, and distribution of the wastes contained in the tank 241-BX-107. Historical and most recent information, ranging from engineering structural assessment experiments, process history, monitoring and remediation activities, to analytical core sample data, were compiled and interpreted in an effort to develop a realistic, contemporary profile for the tank BX-107 contents. The results of this is study revealed that tank BX-107, a 2,006,050 L (530,000 gal) cylindrical single-shell, dished-bottom carbon-steel tank in the 200 East Area of the Hanford Site, was classified as sound. It has been interim stabilized and thus contains less than 189,250 L (50,000 gal) of interstitial liquid, and less than 18,925 L (5,000 gal) of supernatant. It has also been partially interim isolated, whereby all inlets to the tank are sealed to prevent inadvertent addition of liquid. At a residual waste level of ∼3.07 m (120.7 ± 2 in. from sidewall bottom or ∼132.9 in. from center bottom), it is estimated that the tank BX-107 contents are equivalent to 1,305,825 L (345,000 gal). The vapor space pressure is at atmospheric. The latest temperature readings, which were taken in July 1994, show a moderate temperature value of 19 degrees C (66 degrees F). Two supernatant samples were collected in 1974 and 1990, prior to interim stabilization. Sludge core samples were obtained in 1979 and 1992

Preliminary tank characterization report for single-shell tank 241-BY-101: best-basis inventory

International Nuclear Information System (INIS)

Kupfer, M.J.

1997-01-01

An effort is underway to provide waste inventory estimates that will serve as standard characterization source terms for the various waste management activities. As part of this effort, an evaluation of available information for single-shell tank 241-BY-101 was performed, and a best-basis inventory was established. This work follows the methodology that was established by the standard inventory task

Preliminary tank characterization report for single-shell tank 241-U-103: best-basis inventory

International Nuclear Information System (INIS)

Kupfer, M.J.; Stout, R.E.; Winward, R.T.

1997-01-01

An effort is underway to provide waste inventory estimates that will serve as standard characterization source terms for the various waste management activities. As part of this effort, an evaluation of available information for single-shell tank 241-U-103 was performed, and a best-basis inventory was established. This work follows the methodology that was established by the standard inventory task

Preliminary tank characterization report for single-shell tank 241-TX-116: best-basis inventory

International Nuclear Information System (INIS)

Place, D.E.

1997-01-01

An effort is underway to provide waste inventory estimates that will serve as standard characterization source terms for the various waste management activities. As part of this effort, an evaluation of available information for single-shell tank 241-TX-116 was performed, and a bost-basis inventory was established. This work follows the methodology that was established by the standard inventory task

Preliminary tank characterization report for single-shell tank 241-TX-110: Best-basis inventory

International Nuclear Information System (INIS)

Place, D.E.

1997-01-01

An effort is underway to provide waste inventory estimates that will serve as standard characterization source terms for the various waste management activities. As part of this effort, an evaluation of available information for single-shell tank 241-TX-110 was performed, and a best-basis inventory was established. This work follows the methodology that was established by the standard inventory task

Preliminary tank characterization report for single-shell tank 241-BX-102: best-basis inventory

International Nuclear Information System (INIS)

Kupfer, M.J.

1997-01-01

An effort is underway to provide waste inventory estimates that will serve as standard characterization source terms for the various waste management activities. As part of this effort, an evaluation of available information for single-shell tank 241-BX-102 was performed, and a best-basis inventory was established. This work follows the methodology that was established by the standard inventory task

Preliminary tank characterization report for single-shell tank 241-TY-101: best-basis inventory

International Nuclear Information System (INIS)

Lambert, S.L.

1997-01-01

An effort is underway to provide waste inventory estimates that will serve as standard characterization source terms for the various waste management activities. As part of this effort, an evaluation of available information for single-shell tank 241-TY-101 was performed, and a best-basis inventory was established. This work follows the methodology that was established by the standard inventory task

Prelimainary tank characterization report for single-shell tank 241-TY-103 : Best-Basis inventory

International Nuclear Information System (INIS)

Hendrickson, D.W.

1997-01-01

An effort is underway to provide waste inventory estimates that will serve as standard characterization source terms for the various waste management activities. As part of this effort, an evaluation of available information for single-shell tank 241'-TY-103 was performed, and a best-basis inventory was established. This work follows the methodology that was established by the standard inventory task

Preliminary tank characterization report for single-shell tank 241-SX-111: Best-basis inventory

International Nuclear Information System (INIS)

Kupfer, M.J.; Schulz, W.W.; Winward, R.T.

1997-01-01

An effort is underway to provide waste inventory estimates that will serve as standard characterization source terms for the various waste management activities. As part of this effort,.an evaluation of available information for single-shell tank 241-SX-111 was performed, and a best-basis inventory was established. This work follows the methodology that was established by the standard inventory task

Preliminary tank characterization report for single-shell tank 241-SX-112: Best-basis inventory

International Nuclear Information System (INIS)

Kupfer, M.J.; Schulz, W.W.; Winward, R.T.

1997-01-01

An effort is underway to provide waste inventory estimates that will serve as standard characterization source terms for the various waste management activities. As part of this effort, an evaluation of available information for single-shell tank 241-SX-112 was performed, and a best-basis, inventory was established. This work follows the methodology that was established by the standard inventory task

Preliminary tank characterization report for single-shell tank 241-SX-107: Best-basis inventory

International Nuclear Information System (INIS)

Kupfer, M.J.; Schulz, W.W.; Jones, T.E.

1997-01-01

An effort is underway to provide waste inventory estimates that will serve as standard characterization source terms for the various waste management activities. As part of this effort, an evaluation of available information for single-shell tank 241-SX-107 was performed, and a best-basis inventory was established. This work follows the methodology that was established by the standard inventory task

Preliminary tank characterization report for single-shell tank 241-BX-111: best-basis inventory

International Nuclear Information System (INIS)

Kupfer, M.J.

1997-01-01

An effort is underway to provide waste inventory estimates that will serve as standard characterization source terms for the various waste management activities. As part of this effort, an evaluation of available information for single-shell tank 241-BX-111 was performed, and a best-basis inventory was established. This work follows the methodology that was established by the standard inventory task

Tank characterization report for double-shell tank 241-AN-102

International Nuclear Information System (INIS)

Jo, J.

1996-01-01

This characterization report summarizes the available information on the historical uses, current status, and sampling and analysis results of waste stored in double-shell underground storage tank 241- AN-102. This report supports the requirements of the Hanford Federal Facility Agreement and Consent Order, Milestone M-44-09 (Ecology et al. 1996). Tank 241-AN-102 is one of seven double-shell tanks located in the AN Tank Farm in the Hanford Site 200 East Area. The tank was hydrotested in 1981, and when the water was removed, a 6-inch heel was left. Tank 241-AN-102 began receiving waste from tank 241-SY-102 beginning in 1982. The tank was nearly emptied in the third quarter of 1983, leaving only 125 kL (33 kgal) of waste. Between the fourth quarter of 1983 and the first quarter of 1984, tank 241-AN-102 received waste from tanks 241-AY-102, 241-SY-102, 241-AW-105, and 241- AN-101. The tank was nearly emptied in the second quarter of 1984, leaving a heel of 129 kL (34 kgal). During the second and third quarters of 1984, the tank was filled with concentrated complexant waste from tank 241-AW-101. Since that time, only minor amounts of Plutonium-Uranium Extraction (PUREX) Plant miscellaneous waste and water have been received; there have been no waste transfer to or from the tank since 1992. Therefore, the waste currently in the tank is considered to be concentrated complexant waste. Tank 241-AN-102 is sound and is not included on any of the Watch Lists

Preliminary tank characterization report for single-shell tank 241-TX-111: Best-basis inventory

International Nuclear Information System (INIS)

Place, D.E.

1997-01-01

An effort is underway to provide waste inventory estimates that will serve as standard characterization source terms for the various waste management activities. As part of this effort, an evaluation of available information for single-shell tank 241-TX-111 was performed, and a best-basis inventory was established. This work follows the methodology that was established by the standard inventory task. The best-basis inventory is based on an engineering assessment of waste type, process flowsheet data, early sample data, and/or other available information. The Standard Inventories of Chemicals and Radionuclides in Hanford Site Tank Wastes (Kupfer et al. 1997) describes standard methodology used to derive the tank-by-tank best-basis inventories. This preliminary TCR will be updated using this same methodology when additional data on tank contents become available

Preliminary tank characterization report for single-shell tank 241-TX-103: Best-basis inventory

International Nuclear Information System (INIS)

Hendrickson, D.W.

1997-01-01

An effort is underway to provide waste inventory estimates that will serve as standard characterization source terms for the various waste management activities. As part of this effort, an evaluation of available information for single-shell tank 241-TX-103 was performed, and a best-basis inventory was established. This work follows the methodology that was established by the standard inventory task. The best-basis inventory is based on an engineering assessment of waste type, process flowsheet data, early sample data, and/or other available information. The Standard Inventories of Chemicals and Radionuclides in Hanford Site Tank Wastes (Kupfer et al. 1997) describes standard methodology used to derive the tank-by-tank best-basis inventories. This preliminary TCR will be updated using this same methodology when additional data on tank contents become available

Tank 241-C-107 tank characterization plan

International Nuclear Information System (INIS)

Schreiber, R.D.

1995-01-01

The Defense Nuclear Facilities Safety Board (DNFSB) has advised the US Department of Energy (DOE) to concentrate the near-term sampling and analysis activities on identification and resolution of safety issues. The data quality objective (DQO) process was chosen as a tool to be used to identify sampling and analytical needs for the resolution of safety issues. As a result, a revision in the Federal Facility Agreement and Consent Order (Tri-Party Agreement or TPA) milestone M-44-00 has been made, which states that ''A Tank Characterization Plan (TCP) will also be developed for each double-shell tank (DST) and single-shell tank (SST) using the DQO process... Development of TCPs by the DQO process is intended to allow users (e.g., Hanford Facility user groups, regulators) to ensure their needs will be met and that resources are devoted to gaining only necessary information.'' This document satisfies that requirement for the Tank 241-C-107 (C-107) sampling activities. Currently tank C-107 is categorized as a sound, low-heat load tank with partial isolation completed in December 1982. The tank is awaiting stabilization. Tank C-107 is expected to contain three primary layers of waste. The bottom layer should contain a mixture of the following wastes: ion exchange, concentrated phosphate waste from N-Reactor, Hanford Lab Operations, strontium semi-works, Battelle Northwest, 1C, TBP waste, cladding waste, and the hot semi-works. The middle layer should contain strontium recovery supernate. The upper layer should consist of non-complexed waste

Solid Phase Characterization of Tank 241-C-105 Grab Samples

International Nuclear Information System (INIS)

Ely, T. M.; LaMothe, M. E.; Lachut, J. S.

2016-01-01

The solid phase characterization (SPC) of three grab samples from single-shell Tank 241-C-105 (C-105) that were received at the laboratory the week of October 26, 2015, has been completed. The three samples were received and broken down in the 11A hot cells.

Composition and quantities of retained gas measured in Hanford waste tanks 241-U-103, S-106, BY-101, and BY-109

Energy Technology Data Exchange (ETDEWEB)

Mahoney, L.A.; Antoniak, Z.I.; Bates, J.M.

1997-12-01

This report provides the results obtained for the single-shell tanks (SSTs) sampled with the Retained Gas Sampler (RGS) during 1997: Tanks 241-U-103, 241-S-106, 241-BY-101, and 241-BY-109. The RGS is a modified version of the core sampler used at Hanford. It is designed specifically to be used in concert with the gas extraction equipment in the hot cell to capture and extrude a gas-containing waste sample in a hermetically sealed system. The four tanks represent several different types of flammable gas SSTs. Tank U-103 is on the Flammable Gas Watch List (FGWL) and is one of the highest-priority group of SSTs that show evidence of significant gas retention. Tank S-106, though not a FGWL tank, has a uniquely high barometric pressure response and continuing rapid surface level rise, indicating a large and increasing volume of retained gas. Tanks BY-101 and BY-109 are not on the FGWL but were chosen to test the effect of recent salt-well pumping on gas retention. Section 2 of this report provides an overview of the process by which retained gases in the Hanford tanks are sampled and analyzed. A detailed description of the procedure used to reduce and analyze the data is provided in Section 3. Tank-by-tank results are covered in Section 4 (with the data presented in the order in which the tanks were sampled), and an RGS system performance overview is given in Section 5. Section 6 presents conclusions from these analyses and recommendations for further research. The cited references are listed in Section 7. Appendix A describes the procedures used to extract gas and ammonia from the samples, Appendix B contains detailed laboratory data from each of the tanks, and Appendix C gives field sampling data.

Composition and quantities of retained gas measured in Hanford waste tanks 241-U-103, S-106, BY-101, and BY-109

International Nuclear Information System (INIS)

Mahoney, L.A.; Antoniak, Z.I.; Bates, J.M.

1997-12-01

This report provides the results obtained for the single-shell tanks (SSTs) sampled with the Retained Gas Sampler (RGS) during 1997: Tanks 241-U-103, 241-S-106, 241-BY-101, and 241-BY-109. The RGS is a modified version of the core sampler used at Hanford. It is designed specifically to be used in concert with the gas extraction equipment in the hot cell to capture and extrude a gas-containing waste sample in a hermetically sealed system. The four tanks represent several different types of flammable gas SSTs. Tank U-103 is on the Flammable Gas Watch List (FGWL) and is one of the highest-priority group of SSTs that show evidence of significant gas retention. Tank S-106, though not a FGWL tank, has a uniquely high barometric pressure response and continuing rapid surface level rise, indicating a large and increasing volume of retained gas. Tanks BY-101 and BY-109 are not on the FGWL but were chosen to test the effect of recent salt-well pumping on gas retention. Section 2 of this report provides an overview of the process by which retained gases in the Hanford tanks are sampled and analyzed. A detailed description of the procedure used to reduce and analyze the data is provided in Section 3. Tank-by-tank results are covered in Section 4 (with the data presented in the order in which the tanks were sampled), and an RGS system performance overview is given in Section 5. Section 6 presents conclusions from these analyses and recommendations for further research. The cited references are listed in Section 7. Appendix A describes the procedures used to extract gas and ammonia from the samples, Appendix B contains detailed laboratory data from each of the tanks, and Appendix C gives field sampling data

Final report for tank 241-BX-109, push mode cores 84 and 85

International Nuclear Information System (INIS)

Schreiber, R.D.

1996-01-01

This document summarizes the sampling activities for tank 241-BX-109. This report contains tables of the analytical results on total organic compounds and total inorganic compounds in the radioactive wastes. Tank 241-BX-109 has not been on a Watch List

Tank characterization report for double-shell tank 241-AP-105

International Nuclear Information System (INIS)

DeLorenzo, D.S.; Simpson, B.C.

1994-01-01

Double-Shell Tank 241-AP-105 is a radioactive waste tank most recently sampled in March of 1993. Sampling and characterization of the waste in Tank 241-AP-105 contributes toward the fulfillment of Milestone M-44-05 of the Hanford Federal Facility Agreement and Consent Order (Ecology, EPA, and DOE, 1993). Characterization is also needed tot evaluate the waste's fitness for safe processing through an evaporator as part of an overall waste volume reduction program. Tank 241-AP-105, located in the 200 East Area AP Tank Farm, was constructed and went into service in 1986 as a dilute waste receiver tank; Tank 241AP-1 05 was considered as a candidate tank for the Grout Treatment Facility. With the cancellation of the Grout Program, the final disposal of the waste in will be as high- and low-level glass fractions. The tank has an operational capacity of 1,140,000 gallons, and currently contains 821,000 gallons of double-shell slurry feed. The waste is heterogeneous, although distinct layers do not exist. Waste has been removed periodically for processing and concentration through the 242-A Evaporator. The tank is not classified as a Watch List tank and is considered to be sound. There are no Unreviewed Safety Questions associated with Tank 241-AP-105 at this time. The waste in Tank 241-AP-105 exists as an aqueous solution of metallic salts and radionuclides, with limited amounts of organic complexants. The most prevalent soluble analytes include aluminum, potassium, sodium, hydroxide, carbonate, nitrate, and nitrite. The calculated pH is greater than the Resource Conservation and Recovery Act established limit of 12.5 for corrosivity. In addition, cadmium, chromium, and lead concentrations were found at levels greater than their regulatory thresholds. The major radionuclide constituent is 137 Cs, while the few organic complexants present include glycolate and oxalate. Approximately 60% of the waste by weight is water

Tank characterization report for double-shell Tank 241-AP-107

International Nuclear Information System (INIS)

DeLorenzo, D.S.; Simpson, B.C.

1994-01-01

The purpose of this tank characterization report is to describe and characterize the waste in Double-Shell Tank 241-AP-107 based on information gathered from various sources. This report summarizes the available information regarding the waste in Tank 241-AP-107, and arranges it in a useful format for making management and technical decisions concerning this particular waste tank. In addition, conclusion and recommendations based on safety and further characterization needs are given. Specific objectives reached by the sampling and characterization of the waste in Tank 241-AP-107 are: Contribute toward the fulfillment of the Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement) Milestone M-44-05 concerning the characterization of Hanford Site high-level radioactive waste tanks; Complete safety screening of the contents of Tank 241-AP-107 to meet the characterization requirements of the Defense Nuclear Facilities Safety board (DNFSB) Recommendation 93-5; and Provide tank waste characterization to the Tank Waste Remediation System (TWRS) Program Elements in accordance with the TWRS Tank Waste Analysis Plan

Hanford Tank 241-C-106: Residual Waste Contaminant Release Model and Supporting Data

International Nuclear Information System (INIS)

Deutsch, William J.; Krupka, Kenneth M.; Lindberg, Michael J.; Cantrell, Kirk J.; Brown, Christopher F.; Schaef, Herbert T.

2005-01-01

CH2M HILL is producing risk/performance assessments to support the closure of single-shell tanks at the DOE's Hanford Site. As part of this effort, staff at PNNL were asked to develop release models for contaminants of concern that are present in residual sludge remaining in tank 241-C-106 (C-106) after final retrieval of waste from the tank. This report provides the information developed by PNNL

Nonradioactive air emissions notice of construction, Project W-320, 241-C-106 tank sluicing

International Nuclear Information System (INIS)

Hays, C.B.

1998-01-01

This document serves as a Notice of Construction for the Phase 2 activities of Project W-320, 241-C-106 Tank Sluicing, pursuant to the requirements of Washington Administrative Codes (WAC) 173-400 and 173-460. Phased permitting for Project W-320 was discussed with the Washington State Department of Ecology (Ecology) on November 2, 1993. In April 1994, it was deemed unnecessary because the Phase 1 activities did not constitute a new source of emissions and therefore did not require approval from Ecology. The 241-C-106 tank is a 2-million liter capacity, single-shell tank (SST) used for radioactive waste storage since 1947. Between mid-1963 and mid-1969, 241-C-106 tank received high-heat waste, PUREX (plutonium-uranium extraction) Facility high-level waste, and strontium-bearing solids from the strontium and cesium recovery activities. In 1971, temperatures exceeding 99 C were observed in the tank, and therefore, a ventilation system was installed to cool the tank. In addition, approximately 22,712 liters of cooling water are added to the tank each month to prevent the sludge from drying out and overheating. Excessive drying of the sludge could result in possible structural damage. The current radiolytic heat generation rate has been calculated at 32 kilowatts (kW) plus or minus 6 kW. The 241-C-106 tank was withdrawn from service in 1979 and currently is categorized as not leaking. The heat generation in 241-C-106 tank has been identified as a key safety issue on the Hanford Site. The evaporative cooling provided by the added water during operation and/or sluicing maintains the 241-C-106 tank within its specified operating temperature limits. Project W-320, 241-C-106 Tank Sluicing, will mobilize and remove the heat-generating sludge, allowing the water additions to cease. Following sludge removal, the 241-C-106 tank could be placed in a safe, interim stabilized condition. Tank-to-tank sluicing, an existing, proven technology, will provide the earliest possible

Nonradioactive air emissions notice of construction, Project W-320, 241-C-106 tank sluicing

Energy Technology Data Exchange (ETDEWEB)

Hays, C.B.

1998-01-28

This document serves as a Notice of Construction for the Phase 2 activities of Project W-320, 241-C-106 Tank Sluicing, pursuant to the requirements of Washington Administrative Codes (WAC) 173-400 and 173-460. Phased permitting for Project W-320 was discussed with the Washington State Department of Ecology (Ecology) on November 2, 1993. In April 1994, it was deemed unnecessary because the Phase 1 activities did not constitute a new source of emissions and therefore did not require approval from Ecology. The 241-C-106 tank is a 2-million liter capacity, single-shell tank (SST) used for radioactive waste storage since 1947. Between mid-1963 and mid-1969, 241-C-106 tank received high-heat waste, PUREX (plutonium-uranium extraction) Facility high-level waste, and strontium-bearing solids from the strontium and cesium recovery activities. In 1971, temperatures exceeding 99 C were observed in the tank, and therefore, a ventilation system was installed to cool the tank. In addition, approximately 22,712 liters of cooling water are added to the tank each month to prevent the sludge from drying out and overheating. Excessive drying of the sludge could result in possible structural damage. The current radiolytic heat generation rate has been calculated at 32 kilowatts (kW) plus or minus 6 kW. The 241-C-106 tank was withdrawn from service in 1979 and currently is categorized as not leaking. The heat generation in 241-C-106 tank has been identified as a key safety issue on the Hanford Site. The evaporative cooling provided by the added water during operation and/or sluicing maintains the 241-C-106 tank within its specified operating temperature limits. Project W-320, 241-C-106 Tank Sluicing, will mobilize and remove the heat-generating sludge, allowing the water additions to cease. Following sludge removal, the 241-C-106 tank could be placed in a safe, interim stabilized condition. Tank-to-tank sluicing, an existing, proven technology, will provide the earliest possible

Analysis and characterization of double shell tank 241-AP-108

International Nuclear Information System (INIS)

Miller, G.L.

1994-01-01

This document is the first part of a three-part report describing the analysis and characterization of double shell tank 241-AP-108 which is located at the Hanford Reservation.This document is the analytical laboratory data package entitled 'Analysis and Characterization of Double Shell Tank 241-AP-108' which contains a case sampling history, the sampling protocols, the analytical procedures, sampling and analysis quality assurance and quality control measures, and chemical analysis results for samples obtained from the tank

Vapor and gas sampling of single-shell tank 241-BX-110 using the in situ vapor sampling system

International Nuclear Information System (INIS)

Lockrem, L.L.

1997-01-01

The Vapor Issue Resolution Program tasked the Vapor Team (the team) to collect representative headspace samples from Hanford Site single-shell tank (SST) 241-BX-110. This document presents sampling data resulting from the April 30, 1996 sampling of SST 241-BX-110. Analytical results will be presented in a separate report issued by Pacific Northwest National Laboratory (PNNL), which supplied and analyzed the sampling media

Tank characterization report for double-shell Tank 241-AW-105

International Nuclear Information System (INIS)

DiCenso, A.T.; Amato, L.C.; Franklin, J.D.; Lambie, R.W.; Stephens, R.H.; Simpson, B.C.

1994-01-01

In May 1990, double-shell Tank 241-AW-105 was sampled to determine proper handling of the waste, to address corrosivity and compatibility issues, and to comply with requirements of the Washington Administrative Code. This Tank Characterization Report presents an overview of that tank sampling and analysis effort, and contains observations regarding waste characteristics. It also addresses expected concentration and bulk inventory data for the waste contents based on this latest sampling data and background tank information. This report summarizes the available information regarding the waste in Tank 241-AW-105, and using the historical information to place the analytical data in context, arranges this information in a useful format for making management and technical decisions concerning this waste tank. In addition, conclusions and recommendations are given based on safety issues and further characterization needs

Vapor and gas sampling of single-shell tank 241-U-104 using the in situ vapor sampling system

International Nuclear Information System (INIS)

Lockrem, L.L.

1997-01-01

The Vapor Issue.Resolution Program tasked the Vapor Team (VT) to collect representative headspace samples from Hanford Site single-shell tank (SST) 241-U-104. This document presents In Situ Vapor Sampling System (ISVS) data resulting from the July 16, 1996 sampling of SST 241-U-104. Analytical results will be presented in separate reports issued by the Pacific Northwest National Laboratory (PNNL) which supplied and analyzed the sample media

Vapor and gas sampling of single-shell tank 241-S-103 using the in situ vapor sampling system

International Nuclear Information System (INIS)

Lockrem, L.L.

1997-01-01

The Vapor Issue Resolution Program tasked the Vapor Team (VT) to collect representative headspace samples from Hanford Site single-shell tank (SST) 241-S-103. This document presents In Situ Vapor Sampling System (ISVS) data resulting from the June 12, 1996 sampling of SST 241-S-103. Analytical results will be presented in separate reports issued by the Pacific Northwest National Laboratory (PNNL) which supplied and analyzed the sample media

Vapor and gas sampling of single-shell tank 241-S-106 using the in situ vapor sampling system

International Nuclear Information System (INIS)

Lockrem, L.L.

1997-01-01

The Vapor Issue Resolution Program tasked the Vapor Team (VT) to collect representative headspace samples from Hanford Site single-shell tank (SST) 241-S-106. This document presents In Situ vapor Sampling System (ISVS) data resulting from the June 13, 1996 sampling of SST 241-S-106. Analytical results will be presented in separate reports issued by the Pacific Northwest National Laboratory (PNNL) which'supplied and analyzed the sample media

Tank characterization report for double-shell tank 241-AP-102

International Nuclear Information System (INIS)

LAMBERT, S.L.

1999-01-01

In April 1993, Double-Shell Tank 241-AP-102 was sampled to determine waste feed characteristics for the Hanford Grout Disposal Program. This Tank Characterization Report presents an overview of that tank sampling and analysis effort, and contains observations regarding waste characteristics, expected bulk inventory, and concentration data for the waste contents based on this latest sampling data and information on the history of the tank. Finally, this report makes recommendations and conclusions regarding tank operational safety issues

Tank 241-U-203: Tank Characterization Plan

International Nuclear Information System (INIS)

Sathyanarayana, P.

1995-01-01

The revised Federal Facility Agreement and Consent Order states that a tank characterization plan will be developed for each double-shell tank and single-shell tank using the data quality objective process. The plans are intended to allow users and regulators to ensure their needs will be met and resources are devoted to gaining only necessary information. This document satisfies that requirement for Tank 241-U-203 sampling activities

Preliminary tank characterization report for single-shell tank 241-B-105: best-basis inventory

International Nuclear Information System (INIS)

Higley, B.A.

1997-01-01

An effort is underway to provide waste inventory estimates that will serve as standard characterization source terms for the at sign various waste management activities. As part of this effort, an evaluation of available information for singlb-shell tank 241-B-105 was performed, and a best-basis inventory was established. This work follows the methodology that was established by the standard inventory task

Project management plan for Project W-320, Tank 241-C-106 sluicing. Revision 2

Energy Technology Data Exchange (ETDEWEB)

Phillips, D.R.

1994-07-01

A major mission of the US Department of Energy (DOE) is the permanent disposal of Hanford Site defense wastes by utilizing safe, environmentally acceptable, and cost-effective disposal methods that meet applicable regulations. The Tank Waste Remediation System (TWRS) Program was established at the Hanford Site to manage and control activities specific to the remediation of safety watch list tanks, including high-heat-producing tanks, and for the ultimate characterization, retrieval, pretreatment, and disposal of the low- and high-level fractions of the tank waste. Project W-320, Tank 241-C-106 Sluicing, provides the methodology, equipment, utilities, and facilities necessary for retrieving the high-heat waste from single-shell tank (SST) 24-C-106. Project W-320 is a fiscal year (FY) 1993 expense-funded major project, and has a design life of 2 years. Retrieval of the waste in tank 241-C-106 will be accomplished through mobilization of the sludge into a pumpable slurry using past-practice sluicing. The waste is then transferred directly to a double-shell tank for interim storage, subsequent pretreatment, and eventual disposal. A detailed description of the management organization and responsibilities of all participants is presented in this document.

Project management plan for Project W-320, Tank 241-C-106 sluicing. Revision 2

International Nuclear Information System (INIS)

Phillips, D.R.

1994-07-01

A major mission of the US Department of Energy (DOE) is the permanent disposal of Hanford Site defense wastes by utilizing safe, environmentally acceptable, and cost-effective disposal methods that meet applicable regulations. The Tank Waste Remediation System (TWRS) Program was established at the Hanford Site to manage and control activities specific to the remediation of safety watch list tanks, including high-heat-producing tanks, and for the ultimate characterization, retrieval, pretreatment, and disposal of the low- and high-level fractions of the tank waste. Project W-320, Tank 241-C-106 Sluicing, provides the methodology, equipment, utilities, and facilities necessary for retrieving the high-heat waste from single-shell tank (SST) 24-C-106. Project W-320 is a fiscal year (FY) 1993 expense-funded major project, and has a design life of 2 years. Retrieval of the waste in tank 241-C-106 will be accomplished through mobilization of the sludge into a pumpable slurry using past-practice sluicing. The waste is then transferred directly to a double-shell tank for interim storage, subsequent pretreatment, and eventual disposal. A detailed description of the management organization and responsibilities of all participants is presented in this document

Hanford Single-Shell Tank Leak Causes and Locations - 241-BY and 241-TY Farm

Energy Technology Data Exchange (ETDEWEB)

Girardot, Crystal L.; Harlow, Donald G.

2014-09-04

This document identifies 241-BY Tank Farm (BY Farm) and 241-TY Tank Farm (TY Farm) lead causes and locations for the 100 series leaking tanks (241-BY-103, 241-TY-103, 241-TY-104, 241-TY-105 and 241-TY-106) identified in RPP-RPT-43704, Hanford BY Farm Leak Assessments Report, and in RPP-RPT-42296, Hanford TY Farm Leak Assessments Report. This document satisfies the BY and TY Farm portion of the target (T04) in the Hanford Federal Facility Agreement and Consent Order milestone M-045-91F.

Chemical compatibility of tank wastes in tanks 241-C-106, 241-AY-101, and 241-AY-102

International Nuclear Information System (INIS)

Sederburg, J.P.

1994-01-01

This report documents the chemical compatibility of waste types within tanks 241-C-106, 241-AY-101, and 241-AY-102. This information was compiled to facilitate the transfer of tank 241-C-106 waste to tank 241-AY-102 utilizing supernatant from tank 241-AY-101 as the sluicing medium. This document justifies that no chemical compatibility safety issues currently understood, or theorized from thermodynamic modeling, will result from the intended sluice transfer operation

Tank characterization report for single-shell tank 241-BY-112

International Nuclear Information System (INIS)

Baldwin, J.H.

1997-01-01

This document summarizes the information on the historical uses, present status, and the sampling and analysis results of waste stored in Tank 241-BY-112. This report supports the requirements of the Tri-Party Agreement Milestone M-44-10. (This tank has been designated a Ferrocyanide Watch List tank.)

Final results of double-shell tank 241-AN-105 ultrasonic inspection

International Nuclear Information System (INIS)

JENSEN, C.E.

1999-01-01

This document presents the results and documentation of the nondestructive ultrasonic examination of tank 241-AN-105. A tank inspection supplier was retained to provide and use an ultrasonic examination system (equipment, procedures, and inspectors) to scan a limited area of double-shell tank 241-AN-105 primary tank wall primary knuckle, and secondary tank bottom. The inspection found some indication of general and local wall thinning with no cracks detected

Tank characterization data report: Tank 241-C-112

Energy Technology Data Exchange (ETDEWEB)

Simpson, B.C.; Borsheim, G.L.; Jensen, L.

1993-09-01

Tank 241-C-112 is a Hanford Site Ferrocyanide Watch List tank that was most recently sampled in March 1992. Analyses of materials obtained from tank 241-C-112 were conducted to support the resolution of the Ferrocyanide Unreviewed Safety Question (USQ) and to support Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement) Milestone M-10-00. Analysis of core samples obtained from tank 241-C-112 strongly indicates that the fuel concentration in the tank waste will not support a propagating exothermic reaction. Analysis of the process history of the tank as well as studies of simulants provided valuable information about the physical and chemical condition of the waste. This information, in combination with the analysis of the tank waste, sup ports the conclusion that an exothermic reaction in tank 241-C-112 is not plausible. Therefore, the contents of tank 241-C-112 present no imminent threat to the workers at the Hanford Site, the public, or the environment from its forrocyanide inventory. Because an exothermic reaction is not credible, the consequences of this accident scenario, as promulgated by the General Accounting Office, are not applicable.

Tank characterization data report: Tank 241-C-112

International Nuclear Information System (INIS)

Simpson, B.C.; Borsheim, G.L.; Jensen, L.

1993-09-01

Tank 241-C-112 is a Hanford Site Ferrocyanide Watch List tank that was most recently sampled in March 1992. Analyses of materials obtained from tank 241-C-112 were conducted to support the resolution of the Ferrocyanide Unreviewed Safety Question (USQ) and to support Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement) Milestone M-10-00. Analysis of core samples obtained from tank 241-C-112 strongly indicates that the fuel concentration in the tank waste will not support a propagating exothermic reaction. Analysis of the process history of the tank as well as studies of simulants provided valuable information about the physical and chemical condition of the waste. This information, in combination with the analysis of the tank waste, sup ports the conclusion that an exothermic reaction in tank 241-C-112 is not plausible. Therefore, the contents of tank 241-C-112 present no imminent threat to the workers at the Hanford Site, the public, or the environment from its forrocyanide inventory. Because an exothermic reaction is not credible, the consequences of this accident scenario, as promulgated by the General Accounting Office, are not applicable

Final results of double-shell tank 241-AZ-101 ultrasonic inspection

International Nuclear Information System (INIS)

JENSEN, C.E.

1999-01-01

This document presents the results and documentation of the nondestructive ultrasonic examination of tank 241-AZ-101. A tank inspection supplier was retained to provide and use an ultrasonic examination system (equipment, procedures, and inspectors) to scan a limited area of double-shell tank 241-AZ-101 primary tank wall and welds. The inspection found one reportable indication of thinning and no reportable pitting, corrosion, or cracking

Tank characterization report for double-shell tank 241-AP-101. Revision 1

International Nuclear Information System (INIS)

Conner, J.M.

1997-01-01

One major function of the Tank Waste Remediation System (TWRS) is to characterize wastes m support of waste management and disposal activities at the Hanford Site. Analytical data from sampling and analysis and other available information about a tank are compiled and maintained in a tank characterization report (TCR). This report and its appendixes serve as the TCR for double-shell tank 241-AP-101. The objectives of this report are to use characterization data in response to technical issues associated with tank 241-AP-101 waste; and to provide a standard characterization of this waste in terms of a best-basis inventory estimate. Section 2.0 summarizes the response to technical issues, Section 3.0 provides the best-basis inventory estimate, and Section 4.0 makes recommendations about safety status and additional sampling needs. The appendixes contain supporting data and information. This report supported the requirements of the Hanford Federal Facility Agreement and Consent Order, Milestone M-44-05. The characterization information in this report originated from sample analyses and known historical sources. Appendix A provides historical information for tank 241-AP-101 including surveillance, information, records pertaining to waste transfers and tank operations, and expected tank contents derived from a model based upon process knowledge. Appendix B summarizes recent sampling events and historical sampling information. Tank 241-AP-101 was grab sampled in November 1995, when the tank contained 2,790 kL (737 kgal) of waste. An addition1034al 1,438 kL (380 kgal) of waste was received from tank 241-AW-106 in transfers on March 1996 and January 1997. This waste was the product of the 242-A Evaporator Campaign 95-1. Characterization information for the additional 1,438 kL (380 kgal) was obtained using grab sampling data from tank 241-AW-106 and a slurry sample from the evaporator. Appendix C reports on the statistical analysis and numerical manipulation of data used in

Vapor space characterization of waste Tank 241-C-109 (in situ): Results from samples collected on 6/23/94

International Nuclear Information System (INIS)

Clauss, T.W.; Ligotke, M.W.; Pool, K.H.; Lucke, R.B.; McVeety, B.D.; Sharma, A.K.; McCulloch, M.; Fruchter, J.S.; Goheen, S.C.

1995-10-01

This report describes organic analyses results from in situ samples obtained from the headspace of the Hanford waste storage Tank 241-C-109 (referred to as Tank C-109). The results described here were obtained to support safety and toxicological evaluations. Organic compounds were quantitatively determined. Thirteen organic tentatively identified compounds (TICs) were observed above the detection limit of (ca.) 10 ppbv, but standards for most of these were not available at the time of analysis, and the reported concentrations are semiquantitative estimates. In addition, the authors looked for the 40 standard TO-14 analytes. Of these, only one was observed above the 2-ppbv calibrated instrumental detection limit. However, it is believed, even though the values for dichlorodifluoromethane and trichlorofluoromethane are below the instrumental detection limit, they are accurate at these low concentrations. The six analytes account for approximately 100% of the total organic components in Tank C-109. These six organic analytes with the highest estimated concentrations are listed in Summary Table 1. Detailed descriptions of the results appear in the text

Final results of double-shell tank 241-AY-102 ultrasonic inspection

International Nuclear Information System (INIS)

JENSEN, C.E.

1999-01-01

This document presents the results and documentation of the nondestructive ultrasonic examination of tank 241-AY-102. A tank inspection supplier was retained to provide and use an ultrasonic examination system (equipment, procedures, and inspectors) to scan a limited area of double-shell tank 241-AY-102 primary tank wall and welds. The inspection found some indication of insignificant general and local wall thinning with no cracks detected

Preliminary analysis of tank 241-C-106 dryout due to large postulated leak and vaporization

Energy Technology Data Exchange (ETDEWEB)

Piepho, M.G.

1995-03-01

At the Hanford site in SE Washington, there are 149 single-shell tanks containing radionuclide wastes in the form of liquids, sludges and salt cakes. One of the tanks, tank 241-C-106, is heated to the boiling point due to radionuclide decay (primarily Sr-90). Water is added to the tank, which is ventilated, in order to cool the tank. This analysis assumes that there is a hypothetical large leak at the bottom of Tank 241-C-106 which initiates the dryout of the tank. The time required for a tank to dryout after a leak is of interest for safety reasons. As a tank dries outs, its temperature is expected to greatly increase, which could affect the structural integrity of the concrete tank dome. Hence, it is of interest to know how fast the temperature in a leaky tank increases, so that mitigation procedures can be planned and implemented in a timely manner. The objective of the study was to determine how long it would take for tank 241-C-106 to reach 350 degrees Fahrenheit (about 177 degrees Centigrade) after a postulated large leak develops at the bottom center of the tank.

Vapor and gas sampling of single-shell tank 241-B-102 using the in situ vapor sampling system

International Nuclear Information System (INIS)

Lockrem, L.L.

1997-01-01

The Vapor Issue Resolution Program tasked the Vapor Team (the team) to collect representative headspace samples from Hanford Site single-shell tank (SST) 241-B-102. This document presents sampling data resulting from the April 18, 1996 sampling of SST 241-B-102. Analytical results will be presented in a separate report issued by Pacific Northwest National Laboratory (PNNL), which supplied and analyzed the sampling media. The team, consisting of Sampling and Mobile Laboratories (SML) and Special Analytical Studies (SAS) personnel, used the vapor sampling system (VSS) to collect representative samples of the air, gases, and vapors from the headspace of SST 241-B-102 with sorbent traps and SUMMA canisters

Tank characterization report for single-shell tank 241-A-101

International Nuclear Information System (INIS)

Field, J.M.

1997-01-01

This document summarizes the information on the historical uses, present status, and the sampling and analysis results of waste stored in Tank 241-A-101. This tank has been listed on the Hydrogen Watch List. This report supports the requirements of the Tri-Party Agreement Milestone M-44-10

Tank 241-C-106 sampling data requirements developed through the data quality objectives (DQO) process

International Nuclear Information System (INIS)

Wang, O.S.; Bell, K.E.; Anderson, C.M.; Peffers, M.S.; Pulsipher, B.A.; Scott, J.L.

1994-01-01

The rate of heat generation for tank 241-C-106 at the Hanford Site is estimated at more then 100,000 Btu/h. The heat is generated primarily from the radioactive decay of 90 Sr waste that was inadvertently transferred into the tank in the late 1960s. If proper tank cooling is not maintained for this tank, heat-induced structural damage to the tank's concrete shell could result in the release of nuclear waste to the environment. Because of high-heat concerns in January 1991, tank 241-C-106 was designated as a Watch List tank and deemed as a Priority 1 safety issue. Waste Tank Safety Program (WTSP) is responsible for the resolution of this safety issue. Although forced cooling is effective for short term, the long-term resolution for tank cooling is waste retrieval. Single-shell Tank Retrieval Project (Retrieval) is responsible for the safe retrieval and transfer of radioactive waste from tank 241-C-106 to a selected double-shell tank. This data quality objective (DQO) study is an effort to determine engineering and design data needs for WTSP and assist Retrieval in designing contingency action retrieval systems. The 7-step DQO process is a tool developed by the Environmental Protection Agency with a goal of identifying needs and reducing costs. This report discusses the results of two DQO efforts for WTSP and Retrieval. The key data needs to support WTSP are thermal conductivity, permeability, and heat load profile. For the Retrieval support, there are nine and three data needs identified, respectively, for retrieval engineering system design and HVAC system design. The updated schedule to drill two core samples using rotary mode is set for March 1994. The analysis of the sample is expected to be completed by September 1994

Tank characterization report for single-shell tank 241-U-110

International Nuclear Information System (INIS)

Brown, T.M.; Jensen, L.

1993-09-01

Tank 241-U-110 (U-110) is a Hanford Site waste tank that was;most recently sampled in November and December 1989. Analysis of the samples obtained from tank U-110 was conducted to support the characterization of the contents of this tank and to support Hanford Federal Facility Agreement and Consent Order milestone M-10-00 (Ecology, et al. 1992). Because of incomplete recovery of the waste during sampling, there may be bias in the results of this characterization report

Tank characterization report for double-shell tank 241-AN-105

International Nuclear Information System (INIS)

Jo, J.

1997-01-01

A major function of the Tank Waste Remediation System (TWRS) is to characterize wastes in support of waste management and disposal activities at the Hanford Site. Analytical data from sampling and analysis, along with other available information about a tank, are compiled and maintained in a tank characterization report (TCR). This report and its appendixes serve as the TCR for double-shell tank 241-AN-105. The objectives of this report are: (1) to use characterization data in response to technical issues associated with tank 241-AN-105 waste; and (2) to provide a standard characterization of this waste in terms of a best-basis inventory estimate. The response to technical issues is summarized in Section 2.0, and the best-basis inventory estimate is presented in Section 3.0. Recommendations regarding safety status and additional sampling needs are provided in Section 4.0. Supporting data and information are contained in the appendices. This report also supports the requirements of the Hanford Federal Facility Agreement and Consent Order (Ecology et al. 1996) milestone M-44-10

Riser configuration, Tank 241-A-105, light duty utility arm

International Nuclear Information System (INIS)

Boucher, T.D.

1994-01-01

The light-duty utility arm (LDUA) is a seven-joint stainless steel robotic arm with a payload capacity of 75 lb. The robotic arm is deployed vertically with a maximum vertical reach of 63 ft. and a maximum horizontal reach of 13.5 ft. The functional requirements of the LDUA system are mapping and characterization of waste in Hanford single-shell tanks (SST) before and during waste retrieval. The LDUA system consists of a mobile deployment system (MDS), a vertical positioning mast (VPM), a tank riser interface confinement (TRIC), the LDUA, and a controller subsystem or support trailer. Currently, the system is in design and is subject to change; however, the LDUA or robotic arm will be deployed through a 12-in. riser above the tank dome. Field trips were performed to gather specifics for future deployment of the LDUA in Tank 241-A-105. The purpose of this report is to support two previous reports for the investigation of SSTs for deployment of the LDUA system. The first report identified the availability of risers while the second report identified the availability of Tanks 241-A-105, 241-A-S-109, 241-A-T-101, and 241-A-T-109 for deployment of the LDUA system. The second report also identified those 4- and 12-in. risers that could be used for deployment of the LDUA and camera system. This report addresses accessibility to the 241-A Tank Farm and the usability of the Tank 241-A-105 risers. The following information for assisting in the design and deployment of the LDUA will be discussed in this report: radiation survey; flange identification; high resolution video; computer simulated model; and field survey

Updated Drainable Interstitial Liquid Volume Estimates for 119 Single Shell Tanks (SST) Declared Stabilized

International Nuclear Information System (INIS)

FIELD, J.G.

2000-01-01

This document assesses the volume of drainable interstitial liquid (DIL) and pumpable liquid remaining in 119 single-shell tanks (SSTs) that were previously stabilized. Based on the methodology and assumptions presented, the DIL exceeded the stabilization criterion of less than 50,000 gal in two of the 119 SSTs. Tank 241-C-102 had an estimated DIL of 62,000 gal, and the estimated DIL for tank 241-BY-103 was 58,000 gal. In addition, tanks 241-BX-103, 241-T-102, and 241-T-112 appear to exceed the stabilization criterion of 5,000 gal supernatant. An assessment of the source of the supernatant in these tanks is beyond the scope of this document. The actual DIL and pumpable liquid remaining volumes for each tank may vary significantly from estimated volumes as a result of specific tank waste characteristics that are not currently measured or defined. Further refinement to the pumpable liquid and DIL volume estimates may be needed as additional tank waste information is obtained

Safety evaluation for packaging transportation of equipment for tank 241-C-106 waste sluicing system

International Nuclear Information System (INIS)

Calmus, D.B.

1994-01-01

A Waste Sluicing System (WSS) is scheduled for installation in nd waste storage tank 241-C-106 (106-C). The WSS will transfer high rating sludge from single shell tank 106-C to double shell waste tank 241-AY-102 (102-AY). Prior to installation of the WSS, a heel pump and a transfer pump will be removed from tank 106-C and an agitator pump will be removed from tank 102-AY. Special flexible receivers will be used to contain the pumps during removal from the tanks. After equipment removal, the flexible receivers will be placed in separate containers (packagings). The packaging and contents (packages) will be transferred from the Tank Farms to the Central Waste Complex (CWC) for interim storage and then to T Plant for evaluation and processing for final disposition. Two sizes of packagings will be provided for transferring the equipment from the Tank Farms to the interim storage facility. The packagings will be designated as the WSSP-1 and WSSP-2 packagings throughout the remainder of this Safety Evaluation for Packaging (SEP). The WSSP-1 packagings will transport the heel and transfer pumps from 106-C and the WSSP-2 packaging will transport the agitator pump from 102-AY. The WSSP-1 and WSSP-2 packagings are similar except for the length

Tank characterization report for double-shell tank 241-AW-105

International Nuclear Information System (INIS)

Sasaki, L.M.

1997-01-01

One of the major functions of the Tank Waste Remediation System (TWRS) is to characterize wastes in support of waste management and disposal activities at the Hanford Site. Analytical data from sampling and analysis, along with other available information about a tank, are compiled and maintained in a tank characterization report (TCR). This report and its appendices serve as the TCR for double-shell tank 241-AW-105. The objectives of this report are to use characterization data in response to technical issues associated with tank 241-AW-105 waste; and to provide a standard characterization of this waste in terms of a best-basis inventory estimate. The response to technical issues is summarized in Section 2.0, and the best-basis inventory estimate is presented in Section 3.0. Recommendations regarding safety status and additional sampling needs are provided in Section 4.0. Supporting data and information are contained in the appendices. This report supports the requirements of the Hanford Federal Facility Agreement and Consent Order milestone Characterization. information presented in this report originated from sample analyses and known historical sources. While only the results of a recent sampling event will be used to fulfill the requirements of the data quality objectives (DQOs), other information can be used to support or question conclusions derived from these results. Historical information for tank 241-AW-105 is provided in Appendix A, including surveillance information, records pertaining to waste transfers and tank operations, and expected tank contents derived from a process knowledge model. The recent sampling event listed, as well as pertinent sample data obtained before 1996, are summarized in Appendix B along with the sampling results. The results of the 1996 grab sampling event satisfied the data requirements specified in the sampling and analysis plan (SAP) for this tank. In addition, the tank headspace flammability was measured, which addresses

Tank 241-C-103 headspace flammability

International Nuclear Information System (INIS)

Huckaby, J.L.

1994-01-01

Information regarding flammable vapors, gases, and aerosols is presented for the purpose of resolving the tank 241-C-103 headspace flammability issue. Analyses of recent vapor and liquid samples, as well as visual inspections of the tank headspace, are discussed in the context of tank dynamics. This document is restricted to issues regarding the flammability of gases, vapors, and an aerosol that may exist in the headspace of tank 241-C-103. While discussing certain information about the organic liquid present in tank 241-C-103, this document addresses neither the potential for, nor consequences of, a pool fire involving this organic liquid; they will be discussed in a separate report

Tank 241-C-103 headspace flammability

Energy Technology Data Exchange (ETDEWEB)

Huckaby, J.L.

1994-01-01

Information regarding flammable vapors, gases, and aerosols is presented for the purpose of resolving the tank 241-C-103 headspace flammability issue. Analyses of recent vapor and liquid samples, as well as visual inspections of the tank headspace, are discussed in the context of tank dynamics. This document is restricted to issues regarding the flammability of gases, vapors, and an aerosol that may exist in the headspace of tank 241-C-103. While discussing certain information about the organic liquid present in tank 241-C-103, this document addresses neither the potential for, nor consequences of, a pool fire involving this organic liquid; they will be discussed in a separate report.

Tank characterization report for single-shell tank 241-BX-107

International Nuclear Information System (INIS)

Raphael, G.F.

1996-01-01

This study examined and assessed the status, safety issues, composition, and distribution of the wastes contained in the tank 241-BX-107. Historical and most recent information, ranging from engineering structural assessment experiments, process history, monitoring and remediation activities, to analytical core sample data, were compiled and interpreted in an effort to develop a realistic, contemporary profile for the tank BX-107 contents

Hanford Single Shell Tank Leak Causes and Locations - 241-TX Farm

Energy Technology Data Exchange (ETDEWEB)

Girardot, C. L.; Harlow, D> G.

2014-07-22

This document identifies 241-TX Tank Farm (TX Farm) leak causes and locations for the 100 series leaking tanks (241-TX-107 and 241-TX-114) identified in RPP-RPT-50870, Rev. 0, Hanford 241-TX Farm Leak Inventory Assessment Report. This document satisfies the TX Farm portion of the target (T04) in the Hanford Federal Facility Agreement and Consent Order milestone M-045-91F.

241-AY Double Shell Tanks (DST) Integrity Assessment Report

Energy Technology Data Exchange (ETDEWEB)

JENSEN, C.E.

1999-09-21

This report presents the results of the integrity assessment of the 241-AY double-shell tank farm facility located in the 200 East Area of the Hanford Site. The assessment included the design evaluation and integrity examinations of the tanks and concluded that the facility is adequately designed, is compatible with the waste, and is fit for use. Recommendations including subsequent examinations. are made to ensure the continued safe operation of the tanks.

241-AN Double Shell Tanks (DST) Integrity Assessment Report

International Nuclear Information System (INIS)

JENSEN, C.E.

1999-01-01

This report presents the results of the integrity assessment of the 241-AN double-shell tank farm facility located in the 200 East Area of the Hanford Site. The assessment included the design evaluation and integrity examinations of the tanks and concluded that the facility is adequately designed, is compatible with the waste, and is fit for use. Recommendations including subsequent examinations, are made to ensure the continued safe operation of the tanks

241-AY Double Shell Tanks (DST) Integrity Assessment Report

International Nuclear Information System (INIS)

JENSEN, C.E.

1999-01-01

This report presents the results of the integrity assessment of the 241-AY double-shell tank farm facility located in the 200 East Area of the Hanford Site. The assessment included the design evaluation and integrity examinations of the tanks and concluded that the facility is adequately designed, is compatible with the waste, and is fit for use. Recommendations including subsequent examinations, are made to ensure the continued safe operation of the tanks

241-SY Double Shell Tanks (DST) Integrity Assessment Report

International Nuclear Information System (INIS)

JENSEN, C.E.

1999-01-01

This report presents the results of the integrity assessment of the 241-SY double-shell tank farm facility located in the 200 West Area of the Hanford Site. The assessment included the design evaluation and integrity examinations of the tanks and concluded that the facility is adequately designed, is compatible with the waste, and is fit for use. Recommendations including subsequent examinations, are made to ensure the continued safe operation of the tanks

241-AZ Double-Shell Tanks (DST) Integrity Assessment Report

International Nuclear Information System (INIS)

JENSEN, C.E.

1999-01-01

This report presents the results of the integrity assessment of the 241-A2 double-shell tank farm facility located in the 200 East Area of the Hanford Site. The assessment included the design evaluation and integrity examinations of the tanks and concluded that the facility is adequately designed, is compatible with the waste, and is fit for use. Recommendations including subsequent examinations, are made to ensure the continued safe operation of the tanks

241-AW Double Shell Tanks (DST) Integrity Assessment Report

International Nuclear Information System (INIS)

JENSEN, C.E.

1999-01-01

This report presents the results of the integrity assessment of the 241-AW double-shell tank farm facility located in the 200 East Area of the Hanford Site. The assessment included the design evaluation and integrity examinations of the tanks and concluded that the facility is adequately designed, is compatible with the waste, and is fit for use. Recommendations including subsequent examinations, are made to ensure the continued safe operation of the tanks

Double-Shell Tank Visual Inspection Changes Resulting from the Tank 241-AY-102 Primary Tank Leak

International Nuclear Information System (INIS)

Girardot, Crystal L.; Washenfelder, Dennis J.; Johnson, Jeremy M.; Engeman, Jason K.

2013-01-01

As part of the Double-Shell Tank (DST) Integrity Program, remote visual inspections are utilized to perform qualitative in-service inspections of the DSTs in order to provide a general overview of the condition of the tanks. During routine visual inspections of tank 241-AY-102 (AY-102) in August 2012, anomalies were identified on the annulus floor which resulted in further evaluations. In October 2012, Washington River Protection Solutions, LLC determined that the primary tank of AY-102 was leaking. Following identification of the tank AY-102 probable leak cause, evaluations considered the adequacy of the existing annulus inspection frequency with respect to the circumstances of the tank AY-102 1eak and the advancing age of the DST structures. The evaluations concluded that the interval between annulus inspections should be shortened for all DSTs, and each annulus inspection should cover > 95 percent of annulus floor area, and the portion of the primary tank (i.e., dome, sidewall, lower knuckle, and insulating refractory) that is visible from the annulus inspection risers. In March 2013, enhanced visual inspections were performed for the six oldest tanks: 241-AY-101, 241-AZ-101,241-AZ-102, 241-SY-101, 241-SY-102, and 241-SY-103, and no evidence of leakage from the primary tank were observed. Prior to October 2012, the approach for conducting visual examinations of DSTs was to perform a video examination of each tank's interior and annulus regions approximately every five years (not to exceed seven years between inspections). Also, the annulus inspection only covered about 42 percent of the annulus floor

Evaluation of Hanford Single-Shell Waste Tanks Suspected of Water Intrusion

International Nuclear Information System (INIS)

Feero, Amie J.; Washenfelder, Dennis J.; Johnson, Jeremy M.; Schofield, John S.

2013-01-01

Intrusions evaluations for twelve single-shell tanks were completed in 2013. The evaluations consisted of remote visual inspections, data analysis, and calculations of estimated intrusion rates. The observation of an intrusion or the preponderance of evidence confirmed that six of the twelve tanks evaluated had intrusions. These tanks were tanks 241-A-103, BX-101, BX-103, BX-110, BY-102, and SX-106

Tank characterization report for single shell tank 241-SX-108

Energy Technology Data Exchange (ETDEWEB)

Eggers, R.F., Westinghouse Hanford

1996-07-11

This document summarizes the information on the historical uses, present status, and the sampling and analysis results of waste stored in tank 241-SX-108. This report supports the requirements of Tri-Party Agreement Milestone M-44-09.

Tank characterization report for single-shell tank 241-B-101

International Nuclear Information System (INIS)

Schreiber, R.D.

1996-01-01

This document summarizes the information on the historical uses, present status, and the sampling and analysis results of waste stored in tank 241-B-101. This report supports the requirements of Tri-Party Agreement Milestone M-44-09

Tank characterization report for single-shell tank 241-T-108

International Nuclear Information System (INIS)

Baldwin, J.H.

1996-01-01

This document summarizes the information on the historical uses, present status, and the sampling and analysis results of waste stored in Tank 241-T-108. This report supports the requirements of Tri-Party Agreement Milestone M-44-09

Tank characterization report for single-shell tank 241-T-106

International Nuclear Information System (INIS)

Jo, J.

1996-03-01

This document summarizes the information on the historical uses, present status, and the sampling and analysis results of waste stored in Tank 241-T-106. This report supports the requirements of Tri-Party Agreement Milestone M-44-09

Tank characterization report for single-shell tank 241-B-107

International Nuclear Information System (INIS)

Conner, J.M.

1998-01-01

This document summarizes the information on the historical uses, present status, and the sampling and analysis results of waste stored in Tank 241-B-107. This report supports the requirements of the Tri-Party Agreement Milestone M-44-ISB

Tank characterization report for single-shell tank 241-BX-111

International Nuclear Information System (INIS)

Anantatmula, R.P.

1998-01-01

This document summarizes the information on the historical uses, present status, and the sampling and analysis results of waste, stored in Tank 241-BX-111. This report supports the requirements of the Tri-Party Agreement Milestone M-44-ISB

Tank characterization report for single-shell tank 241-B-108

International Nuclear Information System (INIS)

Schreiber, R.D.

1997-01-01

This document summarizes the information on the historical uses, present status, and the sampling and analysis results of waste stored in Tank 241-B-108. This report supports the requirements of the Tri-Party Agreement Milestone M-44-05

Tank characterization report for single-shell tank 241-b-110

International Nuclear Information System (INIS)

Field, J.G.

1997-01-01

This document summarizes the information on the historical uses, present status, and the sampling and analysis results of waste stored in Tank 241-B-110. This report supports the requirements of the Tri-Party Agreement Milestone M-44-05

Tank Characterization Report for Single-Shell Tank 241-U-103

International Nuclear Information System (INIS)

ADAMS, M.R.

2000-01-01

This document summarizes the information on the historical uses, present status, and the sampling and analysis results of waste stored in Tank 241-U-103. This report supports the requirements of the Tri-Party Agreement Milestone M-44-15B

Hanford Single-Shell Tank Leak Causes and Locations - 241-A Farm

Energy Technology Data Exchange (ETDEWEB)

Girardot, Crystal L.; Harlow, Donald G.

2013-09-10

This document identifies 241-A Tank Farm (A Farm) leak causes and locations for the 100 series leaking tanks (241-A-104 and 241-A-105) identified in RPP-ENV-37956, Hanford A and AX Farm Leak Assessment Report. This document satisfies the A Farm portion of the target (T04) in the Hanford Federal Facility Agreement and Consent Order milestone M-045-91F.

Statistical characterization report for Single-Shell Tank 241-T-104

International Nuclear Information System (INIS)

Cromar, R.D.; Wilmarth, S.R.; Jensen, L.

1994-01-01

This report contains the results of the statistical analysis of data from two core samples obtained from single-shell tank 241-T-104 (T-104). Section 2.0 contains a description of the core samples and the chemical analyses performed on the core samples. Section 3.0 contains mean concentration estimates and associated 95% confidence intervals (CIs) on the mean for each of the analytes found in the core composite samples. Section 4.0 contains estimates of the spatial variability (variability between cores) and estimates of the analytical variability from the core composite data. Two types of analytical variability were estimated from the core composite data: (1) sample composite variability (variability between composite samples within the same core) and (2) analytical measurement variability (variability between the primary and duplicate analyses within each core composite sample). Estimates of the analytical measurement variability were used as the reference value to test the significance of the spatial and sample composite variability. Spatial variability was significantly different from zero for 32 out of 80 analytes. The sample composite variance was significantly different from zero for 18 out of the 80 analytes

Statistical characterization report for single-shell tank 241-T-111

International Nuclear Information System (INIS)

Cromar, R.D.; Wilmarth, S.R.

1994-01-01

This report contains the results of the statistical analysis of data from two core samples obtained from single-shell tank 241-T-111 (T-111). Section 2.0 contains a description of the core samples and the chemical analyses performed on the core samples. Section 3.0 contains mean concentration estimates and associated 95% confidence intervals (CIs) on the mean for each of the analytes found in the core samples from T-111. Section 4.0 contains estimates of the spatial variability (variability between cores) and estimates of the analytical variability from the core composite data. Two types of analytical variability were estimated from the core composite data: (1) sample composite variability (variability between composite samples within the same core) and (2) analytical measurement variability (variability between the primary and duplicate analyses within each core composite sample). Estimates of the analytical measurement variability were used as the reference value to test the significance of the spatial and sample composite variability. Spatial variability was significantly different from zero for 39 out of 85 analytes. The sample composite variance was significantly different from zero for (a different) 39 out of the 85 analytes

Tank 241-BY-110 tank characterization plan. Revision 1

International Nuclear Information System (INIS)

Homi, C.S.

1995-01-01

This document is a plan that identifies the information needed to address relevant issues concerning short-term and long-term safe storage and long-term management of Single-Shell Tank (SST) 241-BY-110

Tank 241-AN-102 tank characterization plan. Revision 1

International Nuclear Information System (INIS)

Homi, C.S.

1995-01-01

This document is a plan that identifies the information needed to address relevant issues concerning short-term and long-term safe storage and long-term management of Single-Shell Tank (SST) 241-AN-102

Tank 241-U-111 tank characterization plan. Revision 1

International Nuclear Information System (INIS)

Homi, C.S.

1995-01-01

This document is a plan that identifies the information needed to address relevant issues concerning short-term and long-term safe storage and long-term management of Single-Shell Tank (SST) 241-U-111

Tank 241-S-107 tank characterization plan. Revision 1

International Nuclear Information System (INIS)

Homi, C.S.

1995-01-01

This document is a plan that identifies the information needed to address relevant issues concerning short-term and long-term safe storage and long-term management of Single-Shell Tank (SST) 241-S-107

Tank 241-B-106 tank characterization plan. Revision 1

International Nuclear Information System (INIS)

Homi, C.S.

1995-01-01

This document is a plan that identifies the information needed to address relevant issues concerning short-term and long-term safe storage and long-term management of Single-Shell Tank (SST) 241-B-106

Tank 241-SY-103 tank characterization plan. Revision 1

International Nuclear Information System (INIS)

Homi, C.S.

1995-01-01

This document is a plan that identifies the information needed to address relevant issues concerning short-term and long-term safe storage and long-term management of Single-Shell Tank (SST) 241-SY-103

Preliminary safety equipment list for Tank 241-C-106 Manipulator Retrieval System, Project W-340

International Nuclear Information System (INIS)

Guthrie, R.L.

1994-01-01

This document identifies the anticipated safety classification of the estimated major subsystems, based on the projected major functions, that will be used as guidance for the development of the conceptual design of the Manipulator Retrieval System for Tank 241-C-106. This document is intended to be updated as the design of the Manipulator Retrieval System evolves through the conceptual and definitive design phases. The Manipulator Retrieval System is to be capable of removing the hardened sludge heel at the bottom of single shell Tank 241-C-106 and to perform an overall clean out of the tank that leaves a maximum of 360 ft 3 (TPA milestone M-45-00). The thickness of the heel prior to initiation of waste retrieval with the Manipulator Retrieval System is estimated to be 1- to 2-ft. The Manipulator Retrieval System is currently in the pre-conceptual phase with no definitive systems or subsystems. The anticipated retrieval functions for the Manipulator Retrieval System is based on Table 6-2 of WHC-SD-W340-ES-001, Rev. 1. Projected equipment to accomplish these functions were based on the following systems and equipment: Rotary Mode Core Sampling Equipment (WHC-SD-WM-SEL-032); Light Duty Utility Arm System Equipment (WHC-SD-WM-SEL-034); Single Shell Tanks Equipment (WHC-SD-WM-SEL-020)

Gravity settling of Hanford single-shell tank sludges

International Nuclear Information System (INIS)

Brooks, K.P.; Rector, D.R.; Smith, P.A.

1999-01-01

The US Department of Energy plans to use gravity settling in million-gallon storage tanks while pretreating sludge on the Hanford site. To be considered viable in these large tanks, the supernatant must become clear, and the sludge must be concentrated in an acceptable time. These separations must occur over the wide range of conditions associated with sludge pretreatment. In the work reported here, gravity settling was studied with liter quantities of actual single-shell tank sludge from hanford Tank 241-C-107. Because of limited sludge availability, an approach was developed using the results of these liter-scale tests to predict full-scale operation. Samples were centrifuged at various g-forces to simulate compaction with higher layers of sludge. A semi-empirical settling model was then developed incorporating both the liter-scale settling data and the centrifuge compression results to describe the sludge behavior in a million-gallon tank. The settling model predicted that the compacted sludge solids would exceed 20 wt% in less than 30 days of settling in a 10-m-tall tank for all pretreatment steps

Tank 241-BY-109, cores 201 and 203, analytical results for the final report

International Nuclear Information System (INIS)

Esch, R.A.

1997-01-01

This document is the final laboratory report for tank 241-BY-109 push mode core segments collected between June 6, 1997 and June 17, 1997. The segments were subsampled and analyzed in accordance with the Tank Push Mode Core Sampling and Analysis Plan (Bell, 1997), the Tank Safety Screening Data Quality Objective (Dukelow, et al, 1995). The analytical results are included

Tank characterization report for single-shell tank 241-U-110. Revision 1

Energy Technology Data Exchange (ETDEWEB)

Brown, T.M.; Jensen, L.

1993-09-01

Tank 241-U-110 (U-110) is a Hanford Site waste tank that was ;most recently sampled in November and December 1989. Analysis of the samples obtained from tank U-110 was conducted to support the characterization of the contents of this tank and to support Hanford Federal Facility Agreement and Consent Order milestone M-10-00 (Ecology, et al. 1992). Because of incomplete recovery of the waste during sampling, there may be bias in the results of this characterization report.

Hanford Single-Shell Tank Leak Causes and Locations - 241-B Farm

International Nuclear Information System (INIS)

Girardot, Crystal L.; Harlow, Donald G.

2013-01-01

This document identifies 241-B Tank Farm (B Farm) leak cause and locations for the 100 series leaking tank (241-B-107) identified in RPP-RPT-49089, Hanford B-Farm Leak Inventory Assessments Report. This document satisfies the B Farm portion of the target (T04) in the Hanford Federal Facility Agreement and Consent Order milestone M-045-91F

Tank 241-C-106 past-practice sluicing waste retrieval, Hanford Site, Richland, Washington. Environmental Assessment

International Nuclear Information System (INIS)

1995-02-01

The US Department of Energy (DOE) needs to take action to eliminate safety concerns with storage of the high-heat waste in Tank 241-C-106 (Tank C-106), and demonstrate a tank waste retrieval technology. This Environmental Assessment (EA) was prepared to analyze the potential impacts associated with the proposed action, past-practice sluicing of Tank C-106, an underground single-shell tank (SST). Past-practice sluicing is defined as the mode of waste retrieval used extensively in the past at the Hanford Site on the large underground waste tanks, and involves introducing a high-volume, low-pressure stream of liquid to mobilize sludge waste prior to pumping. It is proposed to retrieve the waste from Tank C-106 because this waste is classified not only as transuranic and high-level, but also as high-heat, which is caused by the radioactive decay of strontium. This waste characteristic has led DOE to place Tank C-106 on the safety ''Watchlist.''

Systems engineering study: tank 241-C-103 organic skimming,storage, treatment and disposal options

Energy Technology Data Exchange (ETDEWEB)

Klem, M.J.

1996-10-23

This report evaluates alternatives for pumping, storing, treating and disposing of the separable phase organic layer in Hanford Site Tank 241-C-103. The report provides safety and technology based preferences and recommendations. Two major options and several varations of these options were identified. The major options were: 1) transfer both the organic and pumpable aqueous layers to a double-shell tank as part of interim stabilization using existing salt well pumping equipment or 2) skim the organic to an above ground before interim stabilization of Tank 241-C-103. Other options to remove the organic were considered but rejected following preliminary evaluation.

Tank 241-C-103 tank characterization plan

International Nuclear Information System (INIS)

Schreiber, R.D.

1994-01-01

The data quality objective (DQO) process was chosen as a tool to be used to identify the sampling analytical needs for the resolution of safety issues. A Tank Characterization Plant (TCP) will be developed for each double shell tank (DST) and single-shell tank (SST) using the DQO process. There are four Watch list tank classifications (ferrocyanide, organic salts, hydrogen/flammable gas, and high heat load). These classifications cover the six safety issues related to public and worker health that have been associated with the Hanford Site underground storage tanks. These safety issues are as follows: ferrocyanide, flammable gas, organic, criticality, high heat, and vapor safety issues. Tank C-103 is one of the twenty tanks currently on the Organic Salts Watch List. This TCP will identify characterization objectives pertaining to sample collection, hot cell sample isolation, and laboratory analytical evaluation and reporting requirements in accordance with the appropriate DQO documents. In addition, the current contents and status of the tank are projected from historical information. The relevant safety issues that are of concern for tanks on the Organic Salts Watch List are: the potential for an exothermic reaction occurring from the flammable mixture of organic materials and nitrate/nitrite salts that could result in a release of radioactive material and the possibility that other safety issues may exist for the tank

Tank 241-C-108 vapor sampling and analysis tank characterization report

International Nuclear Information System (INIS)

Huckaby, J.L.

1995-01-01

Tank 241-C-108 headspace gas and vapor samples were collected and analyzed to help determine the potential risks to tank farm workers due to fugitive emissions from the tank. The drivers and objectives of waste tank headspace sampling and analysis are discussed in Program Plan for the Resolution of Tank Vapor Issues (Osborne and Huckaby 1994). Tank 241-C-108 was vapor sampled in accordance with Data Quality Objectives for Generic In-Tank Health and Safety Issue Resolution (Osborne et al., 1994)

Tank 241-C-104 vapor sampling and analysis tank characterization report

International Nuclear Information System (INIS)

Huckaby, J.L.

1995-01-01

Tank 241-C-104 headspace gas and vapor samples were collected and analyzed to help determine the potential risks to tank farm workers due to fugitive emissions from the tank. The drivers and objectives of waste tank headspace sampling and analysis are discussed in open-quotes Program Plan for the Resolution of Tank Vapor Issues.close quotes Tank 241-C-104 was vapor sampled in accordance with open-quotes Data Quality Objectives for Generic In-Tank Health and Safety Issue Resolution.close quotes

Engineering study of tank leaks related to hydraulic retrieval of sludge from tank 241-C-106

International Nuclear Information System (INIS)

Lowe, S.S.; Carlos, W.C.; Irwin, J.J.; Khaleel, R.; Kline, N.W.; Ludowise, J.D.; Marusich, R.M.; Rittman, P.D.

1993-01-01

This study evaluates hydraulic retrieval (sluicing) of the waste in single-shell tank 241-C-106 with respect to the likelihood of tank leaks, gross volumes of potential leaks, and their consequences. A description of hydraulic retrieval is developed to establish a baseline for the study. Leak models are developed based on postulated leak mechanisms to estimate the amount of waste that could potentially leak while sluicing. Transport models describe the movement of the waste constituents in the surrounding soil and groundwater after a leak occurs. Environmental impact and risk associated with tank leaks are evaluated. Transport of leaked material to the groundwater is found to be dependent on the rate of recharge of moisture in the soil for moderate-sized leaks. Providing a cover over the tank and surrounding area would eliminate the recharge. The bulk of any leaked material would remain in the vicinity of the tank for remedial action

Soil structure interaction analysis for the Hanford Site 241-SY-101 double-shell waste storage tanks

International Nuclear Information System (INIS)

Giller, R.A.; Weiner, E.O.

1991-09-01

The 241-SY-101 tank is a double-shell waste storage tank buried in the 241-SY tank farm in the 200 West Area of the Hanford Site. This analysis addresses the effects of seismic soil-structure interaction on the tank structure and includes a parametric soil-structure interaction study addressing three configurations: two-dimensional soil structure, a two-dimensional structure-soil-structure, and a three-dimensional soil-structure interaction. This study was designed to determine an optimal method for addressing seismic-soil effects on underground storage tanks. The computer programs calculate seismic-soil pressures on the double-shell tank walls and and seismic acceleration response spectra in the tank. The results of this soil-structure interaction parametric study as produced by the computer programs are given in terms of seismic soil pressures and response spectra. The conclusions of this soil-structure interaction evaluation are that dynamically calculated soil pressures in the 241-SY-101 tank are significantly reduce from those using standard hand calculation methods and that seismic evaluation of underground double-shell waste storage tanks must consider soil-structure interaction effects in order to predict conservative structural response. Appendixes supporting this study are available in Volume 2 of this report

Tank 241-C-106 in-tank imaging system operational test report

International Nuclear Information System (INIS)

Pedersen, L.T.

1998-01-01

This document presents the results of operational testing of the 241-C-106 In-Tank Video Camera Imaging System. This imaging system was installed as a component of Project W-320 to monitor sluicing and waste retrieval activities in Tank 241-C-106

Tank Characterization Report for Single-Shell Tank 241-C-104

International Nuclear Information System (INIS)

ADAMS, M.R.

2000-01-01

Interprets information about the tank answering a series of six questions covering areas such as information drivers, tank history, tank comparisons, disposal implications, data quality and quantity, and unique aspects of the tank

Chemical compatibility of tank wastes in 241-C-106, 241-AY-101, and 241-AY-102

International Nuclear Information System (INIS)

Sederburg, J.P.

1994-01-01

This report documents the chemical compatibility of waste types within tanks 241-C-106, 241-AY-101, and 241-AY-102. This information was compiled to facilitate the transfer of tank C-106 waste to tank AY-102 utilizing supernatant from AY-101 as the sluicing medium. This document justifies that no chemical compatibility safety issues currently understood, or theorized from thermodynamic modeling, will result from the intended sluice transfer operation

FLAMMABLE GAS DIFFUSION THROUGH SINGLE SHELL TANK (SST) DOMES

Energy Technology Data Exchange (ETDEWEB)

MEACHAM, J.E.

2003-11-10

This report quantified potential hydrogen diffusion through Hanford Site Single-Shell tank (SST) domes if the SSTs were hypothetically sealed airtight. Results showed that diffusion would keep headspace flammable gas concentrations below the lower flammability limit in the 241-AX and 241-SX SST. The purpose of this document is to quantify the amount of hydrogen that could diffuse through the domes of the SSTs if they were hypothetically sealed airtight. Diffusion is assumed to be the only mechanism available to reduce flammable gas concentrations. The scope of this report is limited to the 149 SSTs.

Sample preparation of tank 241-C-106 grab samples and testing For compatibility with tank 241-AY-102 supernate

International Nuclear Information System (INIS)

Crawford, B.A.

1996-01-01

This test plan describes a sample separation method which will be used to obtain physical measurements and separated 241-C-106 solids and supernate fractions. In addition compatibility of tank 241-C-106 sludge with tank 241-AY-102 supernate will be determined

Test procedures and instructions for single shell tank saltcake cesium removal with crystalline silicotitanate

Energy Technology Data Exchange (ETDEWEB)

Duncan, J.B.

1997-01-07

This document provides specific test procedures and instructions to implement the test plan for the preparation and conduct of a cesium removal test, using Hanford Single Shell Tank Saltcake from tanks 24 t -BY- I 10, 24 1 -U- 108, 24 1 -U- 109, 24 1 -A- I 0 1, and 24 t - S-102, in a bench-scale column. The cesium sorbent to be tested is crystalline siticotitanate. The test plan for which this provides instructions is WHC-SD-RE-TP-024, Hanford Single Shell Tank Saltcake Cesium Removal Test Plan.

241-AY-101 Tank Construction Extent of Condition Review for Tank Integrity

Energy Technology Data Exchange (ETDEWEB)

Barnes, Travis J.; Gunter, Jason R.

2013-08-26

This report provides the results of an extent of condition construction history review for tank 241-AY-101. The construction history of tank 241-AY-101 has been reviewed to identify issues similar to those experienced during tank AY-102 construction. Those issues and others impacting integrity are discussed based on information found in available construction records, using tank AY-102 as the comparison benchmark. In tank 241-AY-101, the second double-shell tank constructed, similar issues as those with tank 241-AY-102 construction reoccurred. The overall extent of similary and affect on tank 241-AY-101 integrity is described herein.

Characterization of Solids in Residual Wastes from Single-Shell Tanks at the Hanford Site, Washington, USA - 9277

International Nuclear Information System (INIS)

Krupka, Kenneth M.; Cantrell, Kirk J.; Schaef, Herbert T.; Arey, Bruce W.; Heald, Steve M.; Deutsch, William J.; Lindberg, Michael J.

2009-01-01

Solid-phase characterization methods have been used in an ongoing study of residual wastes (i.e., waste remaining after final retrieval operations) from the underground single-shell storage tanks 241-C-103, 241-C-106, 241-C-202, 241-C-203, and 241-S-112 at the U.S. Department of Energy's Hanford Site in Washington State. The results of studies completed to date show significant variability in the compositions of those residual wastes and the compositions, morphologies, and crystallinities of the individual phases that make up these wastes. These differences undoubtedly result from the various waste types stored and transferred in and out each tank and the sluicing and retrieval operations used for waste retrieval. Our studies indicate that these residual wastes are chemically-complex assemblages of crystalline and amorphous solids that contain contaminants as discrete phases and/or co-precipitated within oxide phases. Depending on the specific tank, various solids (e.g., gibbsite; boehmite; dawsonite; cancrinite; Fe oxides such as hematite, goethite, and maghemite; rhodochrosite; lindbergite; whewellite; nitratine; and numerous amorphous or poorly crystalline phases) have been identified by X-ray diffraction and scanning electron microscopy/energy dispersive X-ray spectroscopy in residual wastes studied to date. Our studies also show that contact of residual wastes with Ca(OH)2- and CaCO3-saturated aqueous solutions, which were used as surrogates for the compositions of pore-fluid leachants derived from young and aged cements respectively, may alter the compositions of solid phases present in the contacted wastes. Fe oxides/hydroxides have been identified in all residual wastes studied to date. They occur in these wastes as discrete particles, particles intergrown within a matrix of other phases, and surface coatings on other particles or particle aggregates. These Fe oxides/hydroxides typically contain trace concentrations of other transition metals, such Cr, Mn

Tank 241-C-108 vapor sampling and analysis tank characterization report. Revision 1

International Nuclear Information System (INIS)

Huckaby, J.L.

1995-01-01

Tank 241-C-108 headspace gas and vapor samples were collected and analyzed to help determine the potential risks to tank farm workers due to fugitive emissions from the tank. The drivers and objectives of waste tank headspace sampling and analysis are discussed in open-quotes Program Plan for the Resolution of Tank Vapor Issues.close quotes Tank 241-C-108 was vapor sampled in accordance with open-quotes Data Quality Objectives for Generic In-Tank Health and Safety Issue Resolution.close quotes

Contaminant Release from Residual Waste in Single Shell Tanks at the Hanford Site, Washington, USA - 9276

International Nuclear Information System (INIS)

Cantrell, Kirk J.; Krupka, Kenneth M.; Deutsch, William J.; Lindberg, Michael J.

2009-01-01

Determinations of elemental and solid-phase compositions, and contaminant release studies have been applied in an ongoing study of residual tank wastes (i.e., waste remaining after final retrieval operations) from five of 149 underground single-shell storage tanks (241-C-103, 241-C-106, 241-C-202, 241-C-203, and 241-S-112) at the U.S. Department of Energy's Hanford Site in Washington State. This work is being conducted to support performance assessments that will be required to evaluate long-term health and safety risks associated with tank site closure. The results of studies completed to date show significant variability in the compositions, solid phase properties, and contaminant release characteristics from these residual tank wastes. This variability is the result of differences in waste chemistry/composition of wastes produced from several different spent fuel reprocessing schemes, subsequent waste reprocessing to remove certain target constituents, tank farm operations that concentrated wastes and mixed wastes between tanks, and differences in retrieval processes used to remove the wastes from the tanks. Release models were developed based upon results of chemical characterization of the bulk residual waste, solid-phase characterization (see companion paper 9277 by Krupka et al.), leaching and extraction experiments, and geochemical modeling. In most cases empirical release models were required to describe contaminant release from these wastes. Release of contaminants from residual waste was frequently found to be controlled by the solubility of phases that could not be identified and/or for which thermodynamic data and/or dissolution rates have not been measured. For example, significant fractions of Tc-99, I-129, and Cr appear to be coprecipitated at trace concentrations in metal oxide phases that could not be identified unambiguously. In the case of U release from tank 241-C-103 residual waste, geochemical calculations indicated that leachate

241-AW Tank Farm Construction Extent of Condition Review for Tank Integrity

Energy Technology Data Exchange (ETDEWEB)

Barnes, Travis J.; Gunter, Jason R.; Reeploeg, Gretchen E.

2013-11-19

This report provides the results of an extent of condition construction history review for the 241-AW tank farm. The construction history of the 241-AW tank farm has been reviewed to identify issues similar to those experienced during tank AY-102 construction. Those issues and others impacting integrity are discussed based on information found in available construction records, using tank AY-102 as the comparison benchmark. In the 241-AW tank farm, the fourth double-shell tank farm constructed, similar issues as those with tank 241-AY-102 construction occured. The overall extent of similary and affect on 241-AW tank farm integrity is described herein.

Hanford Tank 241-C-106: Impact of Cement Reactions on Release of Contaminants from Residual Waste

International Nuclear Information System (INIS)

Deutsch, William J.; Krupka, Kenneth M.; Lindberg, Michael J.; Cantrell, Kirk J.; Brown, Christopher F.; Schaef, Herbert T.

2006-01-01

The CH2M HILL Hanford Group, Inc. (CH2M HILL) is producing risk/performance assessments to support the closure of single-shell tanks at the U.S. Department of Energy's Hanford Site. As part of this effort, staff at Pacific Northwest National Laboratory were asked to develop release models for contaminants of concern that are present in residual sludge remaining in tank 241-C-106 (C-106) after final retrieval of waste from the tank. Initial work to produce release models was conducted on residual tank sludge using pure water as the leaching agent. The results were reported in an earlier report. The decision has now been made to close the tanks after waste retrieval with a cementitious grout to minimize infiltration and maintain the physical integrity of the tanks. This report describes testing of the residual waste with a leaching solution that simulates the composition of water passing through the grout and contacting the residual waste at the bottom of the tank.

Engineering evaluation of alternatives: Managing the assumed leak from single-shell Tank 241-T-101

International Nuclear Information System (INIS)

Brevick, C.H.; Jenkins, C.

1996-02-01

At mid-year 1992, the liquid level gage for Tank 241-T-101 indicated that 6,000 to 9,000 gal had leaked. Because of the liquid level anomaly, Tank 241-T-101 was declared an assumed leaker on October 4, 1992. SSTs liquid level gages have been historically unreliable. False readings can occur because of instrument failures, floating salt cake, and salt encrustation. Gages frequently self-correct and tanks show no indication of leak. Tank levels cannot be visually inspected and verified because of high radiation fields. The gage in Tank 241-T-101 has largely corrected itself since the mid-year 1992 reading. Therefore, doubt exists that a leak has occurred, or that the magnitude of the leak poses any immediate environmental threat. While reluctance exists to use valuable DST space unnecessarily, there is a large safety and economic incentive to prevent or mitigate release of tank liquid waste into the surrounding environment. During the assessment of the significance of the Tank 241-T-101 liquid level gage readings, Washington State Department of Ecology determined that Westinghouse Hanford Company was not in compliance with regulatory requirements, and directed transfer of the Tank 241-T-101 liquid contents into a DST. Meanwhile, DOE directed WHC to examine reasonable alternatives/options for safe interim management of Tank 241-T-101 wastes before taking action. The five alternatives that could be used to manage waste from a leaking SST are: (1) No-Action, (2) In-Tank Stabilization, (3) External Tank Stabilization, (4) Liquid Retrieval, and (5) Total Retrieval. The findings of these examinations are reported in this study

Seismic evaluation of Tank 241C106 in support of retrieval activities

International Nuclear Information System (INIS)

Wallace, D.A.

1994-01-01

Tank 241C106 (C106) is a domed, single-shell high-level waste storage tank that has been in service in the 200 East Area of the Hanford Site since 1947. Tank C106 is one of twelve tanks in a 4 x 3 array with a 100-ft center-to-center spacing. Each of the tanks is approximately 75 ft in diameter, 24-ft high at the haunch, and 33-ft high at the dome apex. The level of waste in C106 and the associated thermal environment have varied throughout the life of the tanks with the peak temperature in the concrete reaching approximately 300 F at the base of the tank in the mid-1970's (Bander 1992). The calculated peak temperature in the concrete has decreased since that time to approximately 200 F. The peak temperature occurs at the inside bottom of the tank; concrete temperatures in the wall and dome are less than 130 F. The waste inside the tank is primarily solid matter approximately 7- to 8-ft deep. The tank is completely buried in dry, sandy soil to a depth of approximately 6 ft at the dome apex. The in situ evaluation of C106 documented in July 1994 includes only the effects of gravity and thermal loads. A preliminary seismic evaluation of C106 considering only horizontal excitation demonstrated the finite-element program SASSI (A System for Analysis of Soil-Structure Interaction) and provided an estimate of seismic effects including soil-to-structure interaction. This final seismic evaluation expands on the preliminary seismic evaluation to include further verification and refinement of analysis parameters, quantification to tank-to-tank and waste-to-tank interaction, and examination of the effects of vertical seismic excitation. The concrete structure of tank C106 is classified as a Safety Class 1 non-reactor structure

Initial Single-Shell Tank Retrieval System mission analysis report

International Nuclear Information System (INIS)

Hertzel, J.S.

1996-03-01

This document provides the mission analysis for the Initial Single-Shell Tank Retrieval System task, which supports the Single-Shell Tank Waste Retrieval Program in its commitment to remove waste from single-shell tanks for treatment and final closure

SINGLE-SHELL TANKS LEAK INTEGRITY ELEMENTS/SX FARM LEAK CAUSES AND LOCATIONS - 12127

Energy Technology Data Exchange (ETDEWEB)

VENETZ TJ; WASHENFELDER D; JOHNSON J; GIRARDOT C

2012-01-25

Washington River Protection Solutions, LLC (WRPS) developed an enhanced single-shell tank (SST) integrity project in 2009. An expert panel on SST integrity was created to provide recommendations supporting the development of the project. One primary recommendation was to expand the leak assessment reports (substitute report or LD-1) to include leak causes and locations. The recommendation has been included in the M-045-9IF Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement) as one of four targets relating to SST leak integrity. The 241-SX Farm (SX Farm) tanks with leak losses were addressed on an individual tank basis as part of LD-1. Currently, 8 out of 23 SSTs that have been reported to having a liner leak are located in SX Farm. This percentage was the highest compared to other tank farms which is why SX Farm was analyzed first. The SX Farm is comprised of fifteen SSTs built 1953-1954. The tanks are arranged in rows of three tanks each, forming a cascade. Each of the SX Farm tanks has a nominal I-million-gal storage capacity. Of the fifteen tanks in SX Farm, an assessment reported leak losses for the following tanks: 241-SX-107, 241-SX-108, 241-SX-109, 241-SX-111, 241-SX-112, 241-SX-113, 241-SX-114 and 241-SX-115. The method used to identify leak location consisted of reviewing in-tank and ex-tank leak detection information. This provided the basic data identifying where and when the first leaks were detected. In-tank leak detection consisted of liquid level measurement that can be augmented with photographs which can provide an indication of the vertical leak location on the sidewall. Ex-tank leak detection for the leaking tanks consisted of soil radiation data from laterals and drywells near the tank. The in-tank and ex-tank leak detection can provide an indication of the possible leak location radially around and under the tank. Potential leak causes were determined using in-tank and ex-tank information that is not directly related to

Single-Shell Tanks Leak Integrity Elements/ SX Farm Leak Causes and Locations - 12127

Energy Technology Data Exchange (ETDEWEB)

Girardot, Crystal [URS- Safety Management Solutions, Richland, Washington 99352 (United States); Harlow, Don [ELR Consulting Richland, Washington 99352 (United States); Venetz, Theodore; Washenfelder, Dennis [Washington River Protection Solutions, LLC Richland, Washington 99352 (United States); Johnson, Jeremy [U.S. Department of Energy, Office of River Protection Richland, Washington 99352 (United States)

2012-07-01

Washington River Protection Solutions, LLC (WRPS) developed an enhanced single-shell tank (SST) integrity project in 2009. An expert panel on SST integrity was created to provide recommendations supporting the development of the project. One primary recommendation was to expand the leak assessment reports (substitute report or LD-1) to include leak causes and locations. The recommendation has been included in the M-045-91F Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement) as one of four targets relating to SST leak integrity. The 241-SX Farm (SX Farm) tanks with leak losses were addressed on an individual tank basis as part of LD-1. Currently, 8 out of 23 SSTs that have been reported to having a liner leak are located in SX Farm. This percentage was the highest compared to other tank farms which is why SX Farm was analyzed first. The SX Farm is comprised of fifteen SSTs built 1953-1954. The tanks are arranged in rows of three tanks each, forming a cascade. Each of the SX Farm tanks has a nominal 1-million-gal storage capacity. Of the fifteen tanks in SX Farm, an assessment reported leak losses for the following tanks: 241-SX-107, 241-SX-108, 241-SX-109, 241-SX- 111, 241-SX-112, 241-SX-113, 241-SX-114 and 241-SX-115. The method used to identify leak location consisted of reviewing in-tank and ex-tank leak detection information. This provided the basic data identifying where and when the first leaks were detected. In-tank leak detection consisted of liquid level measurement that can be augmented with photographs which can provide an indication of the vertical leak location on the sidewall. Ex-tank leak detection for the leaking tanks consisted of soil radiation data from laterals and dry-wells near the tank. The in-tank and ex-tank leak detection can provide an indication of the possible leak location radially around and under the tank. Potential leak causes were determined using in-tank and ex-tank information that is not directly related to

Project W-340 tank 241-C-106 manipulator system closeout summary

International Nuclear Information System (INIS)

McDaniel, L.B.

1995-02-01

This document summarizes the work that was ongoing when Project W-340 was put on hold. Project W-340: Tank 241-C-106 Manipulator Retrieval System, was a candidate FY98 Major System Acquisition. The project was to develop, procure and deploy a Long Reach Manipulator (LRM) waste retrieval system to provide an alternate method to completing the in-tank demonstration of Single Shell Tank waste retrieval technology. The need for enhanced capabilities derives from (1) the inability of the baseline technology to retrieve certain hard waste forms; (2) uncertainty in the quantity of leakage which will be allowed. Numerous studies over the years have identified an arm architecture as a promising retrieval technology to overcome these concerns. The W340 project was intended to further develop and demonstrate this alternative, as part of selecting the best approach for all tanks. Prior to completing the effort, it was determined that an LRM system was too architecture specific and was envisioned to be too expensive for a one time demonstration of retrieval technology. At the time the work was stopped, an effort was underway to broaden the project scope to allow alternatives to an arm-based system

Thermal modeling of tanks 241-AW-101 and 241-AN-104 with the TEMPEST code

International Nuclear Information System (INIS)

Antoniak, Z.I.; Recknagle, K.P.

1995-07-01

The TEMPEST code was exercised in a preliminary study of double-shell Tanks 241 -AW-101 and 241-AN-104 thermal behavior. The two-dimensional model used is derived from our earlier studies on heat transfer from Tank 241-SY-101. Several changes were made to the model to simulate the waste and conditions in 241-AW-101 and 241-AN-104. The nonconvective waste layer was assumed to be 254 cm (100 in.) thick for Tank 241-AW-101, and 381 cm (150 in.) in Tank 241-AN-104. The remaining waste was assumed, for each tank, to consist of a convective layer with a 7.6-cm (3-inch) crust on top. The waste heat loads for 241-AW-101 and 241-AN-104 were taken to be 10 kW (3.4E4 Btu/hr) and 12 kW (4.0E4 Btu/hr), respectively. Present model predictions of maximum and convecting waste temperatures are within 1.7 degrees C (3 degrees F) of those measured in Tanks 241-AW-101 and 241-AN-104. The difference between the predicted and measured temperature is comparable to the uncertainty of the measurement equipment. These models, therefore, are suitable for estimating the temperatures within the tanks in the event of changing air flows, waste levels, and/or waste configurations

Tank 241-C-101 tank characterization plan

International Nuclear Information System (INIS)

Schreiber, R.D.

1994-01-01

This document is a plan which serves as the contractual agreement between the Characterization Program, Sampling Operations, WHC 222-S Laboratory, and PNL 325 Analytical Chemistry Laboratory. The scope of this plan is to provide guidance for the sampling and analysis of samples from tank 241-C-101

Tank 241-C-105 tank characterization plan

International Nuclear Information System (INIS)

Schreiber, R.D.

1994-01-01

This document is a plan which serves as the contractual agreement between the Characterization Program, Sampling Operations, WHC 222-S Laboratory, and PNL 325 Analytical Chemistry Laboratory. The scope of this plan is to provide guidance for the sampling and analysis of samples from tank 241-C-105

Single-shell tank interim stabilization project plan

Energy Technology Data Exchange (ETDEWEB)

Ross, W.E.

1998-03-27

Solid and liquid radioactive waste continues to be stored in 149 single-shell tanks at the Hanford Site. To date, 119 tanks have had most of the pumpable liquid removed by interim stabilization. Thirty tanks remain to be stabilized. One of these tanks (C-106) will be stabilized by retrieval of the tank contents. The remaining 29 tanks will be interim stabilized by saltwell pumping. In the summer of 1997, the US Department of Energy (DOE) placed a moratorium on the startup of additional saltwell pumping systems because of funding constraints and proposed modifications to the Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement) milestones to the Washington State Department of Ecology (Ecology). In a letter dated February 10, 1998, Final Determination Pursuant to Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement) in the Matter of the Disapproval of the DOE`s Change Control Form M-41-97-01 (Fitzsimmons 1998), Ecology disapproved the DOE Change Control Form M-41-97-01. In response, Fluor Daniel Hanford, Inc. (FDH) directed Lockheed Martin Hanford Corporation (LNMC) to initiate development of a project plan in a letter dated February 25, 1998, Direction for Development of an Aggressive Single-Shell Tank (SST) Interim Stabilization Completion Project Plan in Support of Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement). In a letter dated March 2, 1998, Request for an Aggressive Single-Shell Tank (SST) Interim Stabilization Completion Project Plan, the DOE reaffirmed the need for an aggressive SST interim stabilization completion project plan to support a finalized Tri-Party Agreement Milestone M-41 recovery plan. This project plan establishes the management framework for conduct of the TWRS Single-Shell Tank Interim Stabilization completion program. Specifically, this plan defines the mission needs and requirements; technical objectives and approach; organizational structure, roles, responsibilities

Single-shell tank interim stabilization project plan

International Nuclear Information System (INIS)

Ross, W.E.

1998-01-01

Solid and liquid radioactive waste continues to be stored in 149 single-shell tanks at the Hanford Site. To date, 119 tanks have had most of the pumpable liquid removed by interim stabilization. Thirty tanks remain to be stabilized. One of these tanks (C-106) will be stabilized by retrieval of the tank contents. The remaining 29 tanks will be interim stabilized by saltwell pumping. In the summer of 1997, the US Department of Energy (DOE) placed a moratorium on the startup of additional saltwell pumping systems because of funding constraints and proposed modifications to the Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement) milestones to the Washington State Department of Ecology (Ecology). In a letter dated February 10, 1998, Final Determination Pursuant to Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement) in the Matter of the Disapproval of the DOE's Change Control Form M-41-97-01 (Fitzsimmons 1998), Ecology disapproved the DOE Change Control Form M-41-97-01. In response, Fluor Daniel Hanford, Inc. (FDH) directed Lockheed Martin Hanford Corporation (LNMC) to initiate development of a project plan in a letter dated February 25, 1998, Direction for Development of an Aggressive Single-Shell Tank (SST) Interim Stabilization Completion Project Plan in Support of Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement). In a letter dated March 2, 1998, Request for an Aggressive Single-Shell Tank (SST) Interim Stabilization Completion Project Plan, the DOE reaffirmed the need for an aggressive SST interim stabilization completion project plan to support a finalized Tri-Party Agreement Milestone M-41 recovery plan. This project plan establishes the management framework for conduct of the TWRS Single-Shell Tank Interim Stabilization completion program. Specifically, this plan defines the mission needs and requirements; technical objectives and approach; organizational structure, roles, responsibilities

Acceptance test report for the Tank 241-C-106 in-tank imaging system

International Nuclear Information System (INIS)

Pedersen, L.T.

1998-01-01

This document presents the results of Acceptance Testing of the 241-C-106 in-tank video camera imaging system. The purpose of this imaging system is to monitor the Project W-320 sluicing of Tank 241-C-106. The objective of acceptance testing of the 241-C-106 video camera system was to verify that all equipment and components function in accordance with procurement specification requirements and original equipment manufacturer's (OEM) specifications. This document reports the results of the testing

Discovery of the First Leaking Double-Shell Tank - Hanford Tank 241-AY-102

International Nuclear Information System (INIS)

Harrington, Stephanie J.; Sams, Terry L.

2013-01-01

A routine video inspection of the annulus space between the primary tank and secondary liner of double-shell tank 241-AY-102 was performed in August 2012. During the inspection, unexpected material was discovered. A subsequent video inspection revealed additional unexpected material on the opposite side of the tank, none of which had been observed during inspections performed in December 2006 and January 2007. A formal leak assessment team was established to review the tank's construction and operating histories, and preparations for sampling and analysis began to determine the material's origin. A new sampling device was required to collect material from locations that were inaccessible to the available sampler. Following its design and fabrication, a mock-up test was performed for the new sampling tool to ensure its functionality and capability of performing the required tasks. Within three months of the discovery of the unexpected material, sampling tools were deployed, material was collected, and analyses were performed. Results indicated that some of the unknown material was indicative of soil, whereas the remainder was consistent with tank waste. This, along with the analyses performed by the leak assessment team on the tank's construction history, lead to the conclusion that the primary tank was leaking into the annulus. Several issues were encountered during the deployment of the samplers into the annulus. As this was the first time samples had been required from the annulus of a double-shell tank, a formal lessons learned was created concerning designing equipment for unique purposes under time constraints

Hanford double shell tank corrosion monitoring instrument tree prototype

International Nuclear Information System (INIS)

Nelson, J.L.; Edgemon, G.L.; Ohl, P.C.

1995-11-01

High-level nuclear wastes at the Hanford site are stored underground in carbon steel double-shell and single-shell tanks (DSTs and SSTs). The installation of a prototype corrosion monitoring instrument tree into DST 241-A-101 was completed in December 1995. The instrument tree has the ability to detect and discriminate between uniform corrosion, pitting, and stress corrosion cracking (SCC) through the use of electrochemical noise measurements and a unique stressed element, three-electrode probe. The tree itself is constructed of AISI 304L stainless steel (UNS S30403), with probes in the vapor space, vapor/liquid interface and liquid. Successful development of these trees will allow their application to single shell tanks and the transfer of technology to other US Department of Energy (DOE) sites. Keywords: Hanford, radioactive waste, high-level waste tanks, electrochemical noise, probes, double-shell tanks, single-shell tanks, corrosion

Tank 241-AP-104 tank characterization plan

International Nuclear Information System (INIS)

Homi, C.S.

1995-11-01

This document is a plan that identifies the information needed to address relevant issues concerning short-term and long-term safe storage and long-term management of Double-Shell Tank (DST) 241-AP-104

Tank 241-AZ-101 tank characterization plan

International Nuclear Information System (INIS)

Schreiber, R.D.

1995-01-01

The Defense Nuclear Facilities Safety Board has advised the DOE to concentrate the near-term sampling and analysis activities on identification and resolution of safety issues. The Data Quality Objective (DQO) process was chosen as a tool to be used in the resolution of safety issues. As a result, A revision in the Federal Facilities Agreement and Consent Order (Tri-Party Agreement) milestone M-44 has been made, which states that ''A Tank Characterization Plan (TCP) will also be developed for each double-shell tank (DST) and single-shell tank (SST) using the DQO process. Development of TCPs by the DQO process is intended to allow users to ensure their needs will be met and that resources are devoted to gaining only necessary information''. This document satisfies that requirement for Tank 241-AZ-101 (AZ-101) sampling activities. Tank AZ-101 is currently a non-Watch List tank, so the only DQOs applicable to this tank are the safety screening DQO and the compatibility DQO, as described below. The contents of Tank AZ-101, as of October 31, 1994, consisted of 3,630 kL (960 kgal) of dilute non-complexed waste and aging waste from PUREX (NCAW, neutralized current acid waste). Tank AZ-101 is expected to have two primary layers. The bottom layer is composed of 132 kL of sludge, and the top layer is composed of 3,500 kL of supernatant, with a total tank waste depth of approximately 8.87 meters

Tank 241-B-103 tank characterization plan

International Nuclear Information System (INIS)

Carpenter, B.C.

1995-01-01

The Defense Nuclear Facilities Safety Board (DNFSB) has advised the US Department of Energy (DOE) to concentrate the near-term sampling and analysis activities on identification and resolution of safety issues. The data quality objective (DQO) process was chosen as a tool to be used to identify sampling and analytical needs for the resolution of safety issues. As a result, a revision in the Federal Facility Agreement and Consent Order (Tri-Party Agreement or TPA) milestone M-44-00 has been made, which states that ''A Tank Characterization Plan (TCP) will also be developed for each double-shell tank (DST) and single-shell tank (SST) using the DQO process... Development of TCPs by the DQO process is intended to allow users (e.g., Hanford Facility user groups, regulators) to ensure their needs will be met and that resources are devoted to gaining only necessary information.'' This document satisfies that requirement for Tank 241-B-103 (B-103) sampling activities. Tank B-103 was placed on the Organic Watch List in January 1991 due to review of TRAC data that predicts a TOC content of 3.3 dry weight percent. The tank was classified as an assumed leaker of approximately 30,280 liters (8,000 gallons) in 1978 and declared inactive. Tank B-103 is passively ventilated with interim stabilization and intrusion prevention measures completed in 1985

Statistical characterization report for Single-Shell Tank 241-T-107

International Nuclear Information System (INIS)

Cromar, R.D.; Wilmarth, S.R.; Jensen, L.

1994-01-01

This report contains the results of the statistical analysis of data from three core samples obtained from single-shell tank 241-T-107 (T-107). Four specific topics are addressed. They are summarized below. Section 3.0 contains mean concentration estimates of analytes found in T-107. The estimates of open-quotes errorclose quotes associated with the concentration estimates are given as 95% confidence intervals (CI) on the mean. The results given are based on three types of samples: core composite samples, core segment samples, and drainable liquid samples. Section 4.0 contains estimates of the spatial variability (variability between cores and between segments) and the analytical variability (variability between the primary and the duplicate analysis). Statistical tests were performed to test the hypothesis that the between cores and the between segments spatial variability is zero. The results of the tests are as follows. Based on the core composite data, the between cores variance is significantly different from zero for 35 out of 74 analytes; i.e., for 53% of the analytes there is no statistically significant difference between the concentration means for two cores. Based on core segment data, the between segments variance is significantly different from zero for 22 out of 24 analytes and the between cores variance is significantly different from zero for 4 out of 24 analytes; i.e., for 8% of the analytes there is no statistically significant difference between segment means and for 83% of the analytes there is no difference between the means from the three cores. Section 5.0 contains the results of the application of multiple comparison methods to the core composite data, the core segment data, and the drainable liquid data. Section 6.0 contains the results of a statistical test conducted to determine the 222-S Analytical Laboratory's ability to homogenize solid core segments

Headspace vapor characterization of Hanford Waste Tank 241-SX-109: Results from samples collected on August 1, 1995. Tank Vapor Characterization Project

International Nuclear Information System (INIS)

Pool, K.H.; Clauss, T.W.; Evans, J.C.

1996-05-01

This report describes the results of vapor samples taken from the headspace of waste storage tank 241-SX-109 (Tank SX-109) at the Hanford Site in Washington State. Pacific Northwest National Laboratory (PNNL) contracted with Westinghouse Hanford Company (WHC) to provide sampling devices and analyze samples for inorganic and organic analytes collected from the tank headspace and ambient air near the tank. The analytical work was performed by the PNNL Vapor Analytical Laboratory (VAL) by the Tank Vapor Characterization Project. Work performed was based on a sample and analysis plan (SAP) prepared by WHC. The SAP provided job-specific instructions for samples, analyses, and reporting. The SAP for this sample job was open-quotes Vapor Sampling and Analysis Planclose quotes, and the sample job was designated S5048. Samples were collected by WHC on August 1, 1995, using the Vapor Sampling System (VSS), a truck-based sampling method using a heated probe inserted into the tank headspace

Tank 241-AZ-102 tank characterization plan

International Nuclear Information System (INIS)

Schreiber, R.D.

1995-01-01

The Defense Nuclear Facilities Safety Board has advised the DOE to concentrate the near-term sampling and analysis activities on identification and resolution of safety issues. The Data Quality Objective (DQO) process was chosen as a tool to be used in the resolution of safety issues. As a result, a revision in the Federal Facilities Agreement and Consent Order (Tri-Party Agreement) milestone M-44 has been made, which states that ''A Tank Characterization Plan (TCP) will also be developed for each double-shell tank (DST) and single-shell tank (SST) using the DQO process ... Development of TCPs by the DQO process is intended to allow users to ensure their needs will be met and that resources are devoted to gaining only necessary information''. This document satisfies that requirement for tank 241-AZ-102 (AZ-102) sampling activities. Tank AZ-102 is currently a non-Watch List tank, so the only DQOs applicable to this tank are the safety screening DQO and the compatibility DQO, as described below. The current contents of Tank AZ-102, as of October 31, 1994, consisted of 3,600 kL (950 kgal) of dilute non-complexed waste and aging waste from PUREX (NCAW, neutralized current acid waste). Tank AZ-102 is expected to have two primary layers. The bottom layer is composed of 360 kL of sludge, and the top layer is composed of 3,240 kL of supernatant, with a total tank waste depth of approximately 8.9 meters

Overview of Hanford Single Shell Tank (SST) Structural Integrity

Energy Technology Data Exchange (ETDEWEB)

Rast, Richard S.; Washenfelder, Dennis J.; Johnson, Jeremy M.

2013-11-14

To improve the understanding of the single-shell tanks (SSTs) integrity, Washington River Protection Solutions, LLC (WRPS), the USDOE Hanford Site tank contractor, developed an enhanced Single-Shell Tank Integrity Project (SSTIP) in 2009. An expert panel on SST integrity, consisting of various subject matters experts in industry and academia, was created to provide recommendations supporting the development of the project. This panel developed 33 recommendations in four main areas of interest: structural integrity, liner degradation, leak integrity and prevention, and mitigation of contamination migration, Seventeen of these recommendations were used to develop the basis for the M-45-10-1 Change Package for the Hanford Federal Agreement and Compliance Order, which is also known as the Tri-Party Agreement. The structural integrity of the tanks is a key element in completing the cleanup mission at the Hanford Site. There are eight primary recommendations related to the structural integrity of Hanford Single-Shell Tanks. Six recommendations are being implemented through current and planned activities. The structural integrity of the Hanford is being evaluated through analysis, monitoring, inspection, materials testing, and construction document review. Structural evaluation in the form of analysis is performed using modern finite element models generated in ANSYS. The analyses consider in-situ, thermal, operating loads and natural phenomena such as earthquakes. Structural analysis of 108 of 149 Hanford Single-Shell Tanks has concluded that the tanks are structurally sound and meet current industry standards. Analysis of the remaining Hanford Single-Shell Tanks is scheduled for FY2014. Hanford Single-Shell Tanks are monitored through a dome deflection program. The program looks for deflections of the tank dome greater than 1/4 inch. No such deflections have been recorded. The tanks are also subjected to visual inspection. Digital cameras record the interior surface of

Overview of Hanford Single Shell Tank (SST) Structural Integrity

International Nuclear Information System (INIS)

Rast, Richard S.; Washenfelder, Dennis J.; Johnson, Jeremy M.

2013-01-01

To improve the understanding of the single-shell tanks (SSTs) integrity, Washington River Protection Solutions, LLC (WRPS), the USDOE Hanford Site tank contractor, developed an enhanced Single-Shell Tank Integrity Project (SSTIP) in 2009. An expert panel on SST integrity, consisting of various subject matters experts in industry and academia, was created to provide recommendations supporting the development of the project. This panel developed 33 recommendations in four main areas of interest: structural integrity, liner degradation, leak integrity and prevention, and mitigation of contamination migration, Seventeen of these recommendations were used to develop the basis for the M-45-10-1 Change Package for the Hanford Federal Agreement and Compliance Order, which is also known as the Tri-Party Agreement. The structural integrity of the tanks is a key element in completing the cleanup mission at the Hanford Site. There are eight primary recommendations related to the structural integrity of Hanford Single-Shell Tanks. Six recommendations are being implemented through current and planned activities. The structural integrity of the Hanford is being evaluated through analysis, monitoring, inspection, materials testing, and construction document review. Structural evaluation in the form of analysis is performed using modern finite element models generated in ANSYS. The analyses consider in-situ, thermal, operating loads and natural phenomena such as earthquakes. Structural analysis of 108 of 149 Hanford Single-Shell Tanks has concluded that the tanks are structurally sound and meet current industry standards. Analysis of the remaining Hanford Single-Shell Tanks is scheduled for FY2014. Hanford Single-Shell Tanks are monitored through a dome deflection program. The program looks for deflections of the tank dome greater than 1/4 inch. No such deflections have been recorded. The tanks are also subjected to visual inspection. Digital cameras record the interior surface of

Tank 241-C-107 vapor sampling and analysis tank characterization report

International Nuclear Information System (INIS)

Huckaby, J.L.

1995-01-01

This report presents the details of the Hanford waste tank characterization study for tank 241-C-107. The drivers and objectives of the headspace vapor sampling and analysis were in accordance with procedures that were presented in other reports. The vapor and headspace gas samples were collected and analyzed to determine the potential risks to tank farm workers due to fugitive emissions from the tank

Tank 241-C-102 vapor sampling and analysis tank characterization report

International Nuclear Information System (INIS)

Huckaby, J.L.

1995-01-01

This report presents the details of the Hanford waste tank characterization study for tank 241-C-102. The drivers and objectives of the headspace vapor sampling and analysis were in accordance with procedures that were presented in other reports. The vapor and headspace gas samples were collected and analyzed to determine the potential risks to tank farm workers due to fugitive emissions from the tank

Radiological and toxicological analyses of tank 241-AY-102 and tank 241-C-106 ventilation systems

International Nuclear Information System (INIS)

Himes, D.A.

1998-01-01

The high heat content solids contained in Tank 241-C-106 are to be removed and transferred to Tank 241-AY-102 by sluicing operations, to be authorized under project W320. While sluicing operations are underway, the state of these tanks will be transformed from unagitated to agitated. This means that the partition fraction which describes the aerosol content of the head space will increase from IE-10 to IE-8 (see WHC-SD-WM-CN062, Rev. 2 for discussion of partition fractions). The head spare will become much more loaded with suspended material. Furthermore, the nature of this suspended material can change significantly: sluicing could bring up radioactive solids which normally would lay under many meters of liquid supernate. It is assumed that the headspace and filter aerosols in Tank 241-AY-102 are a 90/10 liquid/solid split. It is further assumed that the sluicing line, the headspace in Tank 241-C-106, and the filters on Tank 241-C-106 contain aerosols which are a 67/33 liquid/solid split. The bases of these assumptions are discussed in Section 3.0. These waste compositions (referred to as mitigated compositions) were used in Attachments 1 through 4 to calculate survey meter exposure rates per liter of inventory in the various system components. Three accident scenarios are evaluated: a high temperature event which melts or burns the HEPA filters and causes releases from other system components; an overpressure event which crushes and blows out the HEPA filters and causes releases from other system components; and an unfiltered release of tank headspace air. The initiating event for the high temperature release is a fire caused by a heater malfunction inside the exhaust dust or a fire outside the duct. The initiating event for the overpressure event could be a steam bump which over pressurizes the tank and leads to a blowout of the HEPA filters in the ventilation system. The catastrophic destruction of the HEPA filters would release a fraction of the accumulated

Radiological and toxicological analyses of tank 241-AY-102 and tank 241-C-106 ventilation systems

Energy Technology Data Exchange (ETDEWEB)

Himes, D.A.

1998-08-11

The high heat content solids contained in Tank 241-C-106 are to be removed and transferred to Tank 241-AY-102 by sluicing operations, to be authorized under project W320. While sluicing operations are underway, the state of these tanks will be transformed from unagitated to agitated. This means that the partition fraction which describes the aerosol content of the head space will increase from IE-10 to IE-8 (see WHC-SD-WM-CN062, Rev. 2 for discussion of partition fractions). The head spare will become much more loaded with suspended material. Furthermore, the nature of this suspended material can change significantly: sluicing could bring up radioactive solids which normally would lay under many meters of liquid supernate. It is assumed that the headspace and filter aerosols in Tank 241-AY-102 are a 90/10 liquid/solid split. It is further assumed that the sluicing line, the headspace in Tank 241-C-106, and the filters on Tank 241-C-106 contain aerosols which are a 67/33 liquid/solid split. The bases of these assumptions are discussed in Section 3.0. These waste compositions (referred to as mitigated compositions) were used in Attachments 1 through 4 to calculate survey meter exposure rates per liter of inventory in the various system components. Three accident scenarios are evaluated: a high temperature event which melts or burns the HEPA filters and causes releases from other system components; an overpressure event which crushes and blows out the HEPA filters and causes releases from other system components; and an unfiltered release of tank headspace air. The initiating event for the high temperature release is a fire caused by a heater malfunction inside the exhaust dust or a fire outside the duct. The initiating event for the overpressure event could be a steam bump which over pressurizes the tank and leads to a blowout of the HEPA filters in the ventilation system. The catastrophic destruction of the HEPA filters would release a fraction of the accumulated

Safety evaluation for the interim stabilization of Tank 241-C-103

Energy Technology Data Exchange (ETDEWEB)

Geschke, G.R.

1995-03-01

This document provides the basis for interim stabilization of tank 241-C-103. The document covers the removal of the organic liquid layer and the aqueous supernatant from tank 241-C-103. Hazards are identified, consequences are calculated and controls to mitigate or prevent potential accidents are developed.

Safety evaluation for the interim stabilization of Tank 241-C-103

International Nuclear Information System (INIS)

Geschke, G.R.

1995-03-01

This document provides the basis for interim stabilization of tank 241-C-103. The document covers the removal of the organic liquid layer and the aqueous supernatant from tank 241-C-103. Hazards are identified, consequences are calculated and controls to mitigate or prevent potential accidents are developed

Results of Characterization and Retrieval Testing on Tank 241-C-109 Heel Solids

Energy Technology Data Exchange (ETDEWEB)

Callaway, William S.

2013-09-26

Eight samples of heel solids from tank 241-C-109 were delivered to the 222-S Laboratory for characterization and dissolution testing. After being drained thoroughly, one-half to two-thirds of the solids were off-white to tan solids that, visually, were fairly evenly graded in size from coarse silt (30-60 μm) to medium pebbles (8-16 mm). The remaining solids were mostly strongly cemented aggregates ranging from coarse pebbles (16-32 mm) to fine cobbles (6-15 cm) in size. Solid phase characterization and chemical analysis indicated that the air-dry heel solids contained ≈58 wt% gibbsite [Al(OH){sub 3}] and ≈37 wt% natrophosphate [Na{sub 7}F(PO{sub 4}){sub 2}·19H{sub 2}O]. The strongly cemented aggregates were mostly fine-grained gibbsite cemented with additional gibbsite. Dissolution testing was performed on two test samples. One set of tests was performed on large pieces of aggregate solids removed from the heel solids samples. The other set of dissolution tests was performed on a composite sample prepared from well-drained, air-dry heel solids that were crushed to pass a 1/4-in. sieve. The bulk density of the composite sample was 2.04 g/mL. The dissolution tests included water dissolution followed by caustic dissolution testing. In each step of the three-step water dissolution tests, a volume of water approximately equal to 3 times the initial volume of the test solids was added. In each step, the test samples were gently but thoroughly mixed for approximately 2 days at an average ambient temperature of 25 °C. The caustic dissolution tests began with the addition of sufficient 49.6 wt% NaOH to the water dissolution residues to provide ≈3.1 moles of OH for each mole of Al estimated to have been present in the starting composite sample and ≈2.6 moles of OH for each mole of Al potentially present in the starting aggregate sample. Metathesis of gibbsite to sodium aluminate was then allowed to proceed over 10 days of gentle mixing of the

Tank characterization report for Single-Shell Tank B-111

International Nuclear Information System (INIS)

Remund, K.M.; Tingey, J.M.; Heasler, P.G.; Toth, J.J.; Ryan, F.M.; Hartley, S.A.; Simpson, D.B.; Simpson, B.C.

1994-09-01

Tank 241-B-111 (hereafter referred to as B-111) is a 2,006,300 liter (530,000 gallon) single-shell waste tank located in the 200 East B tank farm at Hanford. Two cores were taken from this tank in 1991 and analysis of the cores was conducted by Battelle's 325-A Laboratory in 1993. Characterization of the waste in this tank is being done to support Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement) Milestone M-44-05. Tank B-111 was constructed in 1943 and put into service in 1945; it is the second tank in a cascade system with Tanks B-110 and B-112. During its process history, B-111 received mostly second-decontamination-cycle waste and fission products waste via the cascade from Tank B-110. This tank was retired from service in 1976, and in 1978 the tank was assumed to have leaked 30,300 liters (8,000 gallons). The tank was interim stabilized and interim isolated in 1985. The tank presently contains approximately 893,400 liters (236,000 gallons) of sludge-like waste and approximately 3,800 liters (1,000 gallons) of supernate. Historically, there are no unreviewed safety issues associated with this tank and none were revealed after reviewing the data from the latest core sampling event in 1991. An extensive set of analytical measurements was performed on the core composites. The major constituents (> 0.5 wt%) measured in the waste are water, sodium, nitrate, phosphate, nitrite, bismuth, iron, sulfate and silicon, ordered from largest concentration to the smallest. The concentrations and inventories of these and other constituents are given. Since Tanks B-110 and B-111 have similar process histories, their sampling results were compared. The results of the chemical analyses have been compared to the dangerous waste codes in the Washington Dangerous Waste Regulations (WAC 173-303). This assessment was conducted by comparing tank analyses against dangerous waste characteristics 'D' waste codes; and against state waste codes

Hanford Tanks 241-C-203 and 241-C-204: Residual Waste Contaminant Release Model and Supporting Data

Energy Technology Data Exchange (ETDEWEB)

Deutsch, William J.; Krupka, Kenneth M.; Lindberg, Michael J.; Cantrell, Kirk J.; Brown, Christopher F.; Schaef, Herbert T.

2004-10-28

This report describes the development of release models for key contaminants that are present in residual sludge remaining after closure of Hanford Tanks 241-C-203 (C-203) and 241-C-204 (C-204). The release models were developed from data generated by laboratory characterization and testing of samples from these two tanks. Key results from this work are (1) future releases from the tanks of the primary contaminants of concern (99Tc and 238U) can be represented by relatively simple solubility relationships between infiltrating water and solid phases containing the contaminants; and (2) high percentages of technetium-99 in the sludges (20 wt% in C-203 and 75 wt% in C-204) are not readily water leachable, and, in fact, are very recalcitrant. This is similar to results found in related studies of sludges from Tank AY-102. These release models are being developed to support the tank closure risk assessments performed by CH2M HILL Hanford Group, Inc., for the U.S. Department of Energy.

Hanford Tanks 241-C-203 and 241-C-204: Residual Waste Contaminant Release Model and Supporting Data

International Nuclear Information System (INIS)

Deutsch, William J.; Krupka, Kenneth M.; Lindberg, Michael J.; Cantrell, Kirk J.; Brown, Christopher F.; Schaef, Herbert T.

2004-01-01

This report describes the development of release models for key contaminants that are present in residual sludge remaining after closure of Hanford Tanks 241-C-203 (C-203) and 241-C-204 (C-204). The release models were developed from data generated by laboratory characterization and testing of samples from these two tanks. Key results from this work are (1) future releases from the tanks of the primary contaminants of concern (99Tc and 238U) can be represented by relatively simple solubility relationships between infiltrating water and solid phases containing the contaminants; and (2) high percentages of technetium-99 in the sludges (20 wt% in C-203 and 75 wt% in C-204) are not readily water leachable, and, in fact, are very recalcitrant. This is similar to results found in related studies of sludges from Tank AY-102. These release models are being developed to support the tank closure risk assessments performed by CH2M HILL Hanford Group, Inc., for the U.S. Department of Energy

Construction Method Study For Installation Of A Large Riser In A Single-Shell Tank

International Nuclear Information System (INIS)

Adkisson, D.A.

2010-01-01

This study evaluates and identifies a construction method for cutting a hole in a single-shell tank dome. This study also identifies and evaluates vendors for performing the cut. Single-shell tanks (SST) in the 241-C tank farm are currently being retrieved using various retrieval technologies (e.g., modified sluicing). The Hanford Federal Facility Agreement and Consent Order require that the SSTs be retrieved to less than 360 cubic feet of radioactive waste. The current technologies identified and deployed for tank retrieval have not been able to retrieve waste in accordance with the Hanford Federal Facility Agreement and Consent Order. As such, alternative retrieval systems have been proposed and are currently under construction that will have the ability to retrieve waste to this defined level. The proposed retrieval systems will not fit down existing risers. New risers will need to be installed to provide the retrieval systems access to the inside of the SSTs. The purpose of this study is two-fold. The first objective is to identify multiple concrete cutting technologies and perform an initial pre-screening, evaluate the technologies identified for more in-depth analysis, and recommend a technology/methodology for cutting a hole in the tank dome. The identified/pre-screened methods will be evaluated based on the following criteria: (1) Maturity/complexity; (2) Waste generation; (3) Safety; (4) Cost; and (5) Schedule. Once the preferred method is identified to cut the hole in the tank dome, the second objective is to identify, evaluate, and recommend a vendor for the technology selected that will perform the cutting process.

Tank 241-C-103 tank characterization plan. Revision 1

International Nuclear Information System (INIS)

Schreiber, R.D.

1995-01-01

This document is a plan which serves as the contractual agreement between the Characterization Program, Sampling Operations, WHC 222-S Laboratory, and PNL 325 Analytical Chemistry Laboratory. The scope of this plan is to provide guidance for the sampling and analysis of samples from tank 241-C-103

Ultrasonic Examination of Double-Shell Tank 241-AY-101 Examination Completed August 2003

International Nuclear Information System (INIS)

Pardini, Allan F.; Posakony, Gerald J.

2003-01-01

COGEMA Engineering Corporation (COGEMA), under a contract from CH2M Hill Hanford Group (CH2M Hill), has performed an ultrasonic nondestructive examination of selected portions of Double-Shell Tank 241-AY-101. The purpose of this examination was to provide information that could be used to evaluate the integrity of the wall of the secondary tank. The requirements for the ultrasonic examination of Tank 241-AY-101 were to detect, characterize (identify, size, and locate), and record measurements made of any wall thinning or pitting that might be present in the wall of the secondary tank. Any measurements that exceed the requirements set forth in the Engineering Task Plan (ETP), RPP--11832 (Jensen 2002) and summarized on page 1 of this document, are reported to CH2M Hill and the Pacific Northwest National Laboratory (PNNL) for further evaluation. Under the contract with CH2M Hill, all data is to be recorded on disk and paper copies of all measurements are provided to PNNL for third-party evaluation. PNNL is responsible for preparing a report that describes the results of the COGEMA ultrasonic examinations

Ultrasonic Examination of Double-Shell Tank 241-AP-104. Examination Completed August 2004

International Nuclear Information System (INIS)

Pardini, Allan F.; Posakony, Gerald J.

2004-01-01

COGEMA Engineering Corporation (COGEMA), under a contract from CH2M Hill Hanford Group (CH2M Hill), has performed an ultrasonic nondestructive examination of selected portions of Double-Shell Tank 241-AP-104. The purpose of this examination was to provide information that could be used to evaluate the integrity of the wall of the primary tank. The requirements for the ultrasonic examination of Tank 241-AP-104 were to detect, characterize (identify, size, and locate), and record measurements made of any wall thinning, pitting, or cracks that might be present in the wall of the primary tank. Any measurements that exceed the requirements set forth in the Engineering Task Plan (ETP), RPP-17750 (Jensen 2003) and summarized on page 1 of this document, are reported to CH2M Hill and the Pacific Northwest National Laboratory (PNNL) for further evaluation. Under the contract with CH2M Hill, all data is to be recorded on disk and paper copies of all measurements are provided to PNNL for third-party evaluation. PNNL is responsible for preparing a report that describes the results of the COGEMA ultrasonic examinations

Ultrasonic Examination of Double-Shell Tank 241-SY-103. Examination completed February 2004

International Nuclear Information System (INIS)

Pardini, Allan F.; Posakony, Gerald J.

2004-01-01

COGEMA Engineering Corporation (COGEMA), under a contract from CH2M Hill Hanford Group (CH2M Hill), has performed an ultrasonic nondestructive examination of selected portions of Double-Shell Tank 241-SY-103. The purpose of this examination was to provide information that could be used to evaluate the integrity of the wall of the primary tank. The requirements for the ultrasonic examination of Tank 241-SY-103 were to detect, characterize (identify, size, and locate), and record measurements made of any wall thinning, pitting, or cracks that might be present in the wall of the primary tank. Any measurements that exceed the requirements set forth in the Engineering Task Plan (ETP), RPP-17750 (Jensen 2003) and summarized on page 1 of this document, are reported to CH2M Hill and the Pacific Northwest National Laboratory (PNNL) for further evaluation. Under the contract with CH2M Hill, all data is to be recorded on disk and paper copies of all measurements are provided to PNNL for third-party evaluation. PNNL is responsible for preparing a report that describes the results of the COGEMA ultrasonic examinations

Ultrasonic Examination of Double-Shell Tank 241-AZ-102 Examination Completed August 2003

International Nuclear Information System (INIS)

Pardini, Allan F.; Posakony, Gerald J.

2003-01-01

COGEMA Engineering Corporation (COGEMA), under a contract from CH2M Hill Hanford Group (CH2M Hill), has performed an ultrasonic nondestructive examination of selected portions of Double-Shell Tank 241-AZ-102. The purpose of this examination was to provide information that could be used to evaluate the integrity of the wall of the primary tank. The requirements for the ultrasonic examination of Tank 241-AZ-102 were to detect, characterize (identify, size, and locate), and record measurements made of any wall thinning, pitting, or cracks that might be present in the wall of the primary tank. Any measurements that exceed the requirements set forth in the Engineering Task Plat (ETP), RPP-11832 (Jensen 2002) and summarized on page 1 of this document, are reported to CH2M Hill and the Pacific Northwest National Laboratory (PNNL) for further evaluation. Under the contract with CH2M Hill, all data is to be recorded on disk and paper copies of all measurements are provided to PNNL for third-party evaluation. PNNL is responsible for preparing a report that describes the results of the COGEMA ultrasonic examinations

Ultrasonic Examination of Double-Shell Tank 241-SY-102. Examination Completed June 2004

International Nuclear Information System (INIS)

Pardini, Allan F.; Posakony, Gerald J.

2004-01-01

COGEMA Engineering Corporation (COGEMA), under a contract from CH2M Hill Hanford Group (CH2M Hill), has performed an ultrasonic nondestructive examination of selected portions of Double-Shell Tank 241-SY-102. The purpose of this examination was to provide information that could be used to evaluate the integrity of the wall of the primary tank. The requirements for the ultrasonic examination of Tank 241-SY-102 were to detect, characterize (identify, size, and locate), and record measurements made of any wall thinning, pitting, or cracks that might be present in the wall of the primary tank. Any measurements that exceed the requirements set forth in the Engineering Task Plan (ETP), RPP-17750 (Jensen 2003) and/SUMmarized on page 1 of this document, are reported to CH2M Hill and the Pacific Northwest National Laboratory (PNNL) for further evaluation. Under the contract with CH2M Hill, all data is to be recorded on disk and paper copies of all measurements are provided to PNNL for third-party evaluation. PNNL is responsible for preparing a report that describes the results of the COGEMA

Single-shell tank interim stabilization risk analysis

International Nuclear Information System (INIS)

Basche, A.D.

1998-01-01

The purpose of the Single-Shell Tank (SST) Interim Stabilization Risk Analysis is to provide a cost and schedule risk analysis of HNF-2358, Rev. 1, Single-Shell Tank Interim Stabilization Project Plan (Project Plan) (Ross et al. 1998). The analysis compares the required cost profile by fiscal year (Section 4.2) and revised schedule completion date (Section 4.5) to the Project Plan. The analysis also evaluates the executability of the Project Plan and recommends a path forward for risk mitigation

Test plan for tank 241-C-104 retrieval testing

International Nuclear Information System (INIS)

HERTING, D.L.

1999-01-01

Tank 241-C-104 has been identified as one of the first tanks to be retrieved for high-level waste pretreatment and immobilization. Retrieval of the tank waste will require dilution. Laboratory tests are needed to determine the amount of dilution required for safe retrieval and transfer of feed. The proposed laboratory tests are described in this document

Test Plan for Tank 241-C-104 Retrieval Testing

International Nuclear Information System (INIS)

HERTING, D.L.

1999-01-01

Tank 241-C-104 has been identified as one of the first tanks to be retrieved for high-level waste pretreatment and immobilization. Retrieval of the tank waste will require dilution. Laboratory tests are needed to determine the amount of dilution required for safe retrieval and transfer of feed. The proposed laboratory tests are described in this document

Hanford Tanks 241-C-202 and 241-C-203 Residual Waste Contaminant Release Models and Supporting Data

Energy Technology Data Exchange (ETDEWEB)

Deutsch, William J.; Krupka, Kenneth M.; Lindberg, Michael J.; Cantrell, Kirk J.; Brown, Christopher F.; Mattigod, Shas V.; Schaef, Herbert T.; Arey, Bruce W.

2007-09-13

As directed by Congress, the U. S. Department of Energy (DOE) established the Office of River Protection in 1998 to manage DOE's largest, most complex environmental cleanup project – retrieval of radioactive waste from Hanford tanks for treatment and eventual disposal. Sixty percent by volume of the nation's high-level radioactive waste is stored at Hanford in aging deteriorating tanks. If not cleaned up, this waste is a threat to the Columbia River and the Pacific Northwest. CH2M Hill Hanford Group, Inc., is the Office of River Protection's prime contractor responsible for the storage, retrieval, and disposal of Hanford's tank waste. As part of this effort, CH2M HILL Hanford Group, Inc. contracted with Pacific Northwest National Laboratory (PNNL) to develop release models for key contaminants that are present in residual sludge remaining after closure of Hanford Tanks 241-C-203 (C-203) and 241-C-204 (C-204). The release models were developed from data generated by laboratory characterization and testing of samples from these two tanks. These release models are being developed to support the tank closure risk assessments performed by CH2M HILL Hanford Group, Inc., for DOE.

Tank 241-C-111 vapor sampling and analysis tank characterization report. Revision 1

International Nuclear Information System (INIS)

Huckaby, J.L.

1995-01-01

This report presents the details of the Hanford waste tank characterization study for tank 241-C-111. The drivers and objectives of the headspace vapor sampling and analysis were in accordance with procedures that were presented in other reports. The vapor and headspace gas samples were collected and analyzed to determine the potential risks to tank farm workers due to fugitive emissions from the tank

Hanford Double-Shell Tank Extent-of-Condition Construction Review

International Nuclear Information System (INIS)

Venetz, Theodore J.; Johnson, Jeremy M.; Gunter, Jason R.; Barnes, Travis J.; Washenfelder, Dennis J.; Boomer, Kayle D.

2013-01-01

During routine visual inspections of Hanford double-shell waste tank 241-AY-102 (AY-102), anomalies were identified on the annulus floor which resulted in further evaluations. Following a formal leak assessment in October 2012, Washington River Protection Solutions, LLC (WRPS) determined that the primary tank of AY-102 was leaking. The formal leak assessment, documented in RPP-ASMT-53793,Tank 241-AY-102 Leak Assessment Report, identified first-of-a-kind construction difficulties and trial-and-error repairs as major contributing factors to tank failure. To determine if improvements in double-shell tank (DST) construction occurred after construction of tank AY-102, a detailed review and evaluation of historical construction records were performed for the first three DST tank farms constructed, which included tanks 241-AY-101, 241-AZ-101, 241-AZ-102, 241-SY-101, 241-SY-102, and 241-SY-103. The review for these six tanks involved research and review of dozens of boxes of historical project documentation. These reviews form a basis to better understand the current condition of the three oldest Hanford DST farms. They provide a basis for changes to the current tank inspection program and also provide valuable insight into future tank use decisions. If new tanks are constructed in the future, these reviews provide valuable 'lessons-learned' information about expected difficulties as well as construction practices and techniques that are likely to be successful

Static internal pressure capacity of Hanford Single-Shell Waste Tanks

Energy Technology Data Exchange (ETDEWEB)

Julyk, L.J.

1994-07-19

Underground single-shell waste storage tanks located at the Hanford Site in Richland, Washington, generate gaseous mixtures that could be ignited, challenging the structural integrity of the tanks. The structural capacity of the single-shell tanks to internal pressure is estimated through nonlinear finite-element structural analyses of the reinforced concrete tank. To determine their internal pressure capacity, designs for both the million-gallon and the half-million-gallon tank are evaluated on the basis of gross structural instability.

Static internal pressure capacity of Hanford Single-Shell Waste Tanks

International Nuclear Information System (INIS)

Julyk, L.J.

1994-01-01

Underground single-shell waste storage tanks located at the Hanford Site in Richland, Washington, generate gaseous mixtures that could be ignited, challenging the structural integrity of the tanks. The structural capacity of the single-shell tanks to internal pressure is estimated through nonlinear finite-element structural analyses of the reinforced concrete tank. To determine their internal pressure capacity, designs for both the million-gallon and the half-million-gallon tank are evaluated on the basis of gross structural instability

Investigation of Tank 241-AN-101 Floating Solids

Energy Technology Data Exchange (ETDEWEB)

Kraft, Douglas P. [Washington River Protection Solutions, LLC, Richland, VA (United States); Meznarich, H. K. [Washington River Protection Solutions, LLC, Richland, VA (United States)

2017-10-30

Tank 241-AN-101 is the receiver tank for retrieval of several C-Farms waste tanks, including Tanks 241-C-102 and 241-C-111. Tank 241 C 111 received first-cycle decontamination waste from the bismuth phosphate process and Plutonium and Uranium Extraction cladding waste, as well as hydraulic fluid. Three grab samples, 1AN-16-01, 1AN-16-01A, and 1AN-16-01B, were collected at the surface of Tank 241-AN-101 on April 25, 2016, after Tank 241-C-111 retrieval was completed. Floating solids were observed in the three grab samples in the 11A hot cell after the samples were received at the 222-S Laboratory. Routine chemical analyses, solid phase characterization on the floating and settled solids, semivolatile organic analysis mainly on the aqueous phase for identification of degradation products of hydraulic fluids were performed. Investigation of the floating solids is reported.

Vapor characterization of Tank 241-C-103

International Nuclear Information System (INIS)

Huckaby, J.L.; Story, M.S.

1994-06-01

The Westinghouse Hanford Company Tank Vapor Issue Resolution Program has developed, in cooperation with Northwest Instrument Systems, Inc., Oak Ridge National Laboratory, Oregon Graduate Institute of Science and Technology, Pacific Northwest Laboratory, and Sandia National Laboratory, the equipment and expertise to characterize gases and vapors in the high-level radioactive waste storage tanks at the Hanford Site in south central Washington State. This capability has been demonstrated by the characterization of the tank 241-C-103 headspace. This tank headspace is the first, and for many reasons is expected to be the most problematic, that will be characterized (Osborne 1992). Results from the most recent and comprehensive sampling event, sample job 7B, are presented for the purpose of providing scientific bases for resolution of vapor issues associated with tank 241-C-103. This report is based on the work of Clauss et al. 1994, Jenkins et al. 1994, Ligotke et al. 1994, Mahon et al. 1994, and Rasmussen and Einfeld 1994. No attempt has been made in this report to evaluate the implications of the data presented, such as the potential impact of headspace gases and vapors to tank farm workers health. That and other issues will be addressed elsewhere. Key to the resolution of worker health issues is the quantitation of compounds of toxicological concern. The Toxicology Review Panel, a panel of Pacific Northwest Laboratory experts in various areas, of toxicology, has chosen 19 previously identified compounds as being of potential toxicological concern. During sample job 7B, the sampling and analytical methodology was validated for this preliminary list of compounds of toxicological concern. Validation was performed according to guidance provided by the Tank Vapor Conference Committee, a group of analytical chemists from academic institutions and national laboratories assembled and commissioned by the Tank Vapor Issue Resolution Program

Vapor characterization of Tank 241-C-103

Energy Technology Data Exchange (ETDEWEB)

Huckaby, J.L. [Westinghouse Hanford Co., Richland, WA (United States); Story, M.S. [Northwest Instrument Systems, Inc. Richland, WA (United States)

1994-06-01

The Westinghouse Hanford Company Tank Vapor Issue Resolution Program has developed, in cooperation with Northwest Instrument Systems, Inc., Oak Ridge National Laboratory, Oregon Graduate Institute of Science and Technology, Pacific Northwest Laboratory, and Sandia National Laboratory, the equipment and expertise to characterize gases and vapors in the high-level radioactive waste storage tanks at the Hanford Site in south central Washington State. This capability has been demonstrated by the characterization of the tank 241-C-103 headspace. This tank headspace is the first, and for many reasons is expected to be the most problematic, that will be characterized (Osborne 1992). Results from the most recent and comprehensive sampling event, sample job 7B, are presented for the purpose of providing scientific bases for resolution of vapor issues associated with tank 241-C-103. This report is based on the work of Clauss et al. 1994, Jenkins et al. 1994, Ligotke et al. 1994, Mahon et al. 1994, and Rasmussen and Einfeld 1994. No attempt has been made in this report to evaluate the implications of the data presented, such as the potential impact of headspace gases and vapors to tank farm workers health. That and other issues will be addressed elsewhere. Key to the resolution of worker health issues is the quantitation of compounds of toxicological concern. The Toxicology Review Panel, a panel of Pacific Northwest Laboratory experts in various areas, of toxicology, has chosen 19 previously identified compounds as being of potential toxicological concern. During sample job 7B, the sampling and analytical methodology was validated for this preliminary list of compounds of toxicological concern. Validation was performed according to guidance provided by the Tank Vapor Conference Committee, a group of analytical chemists from academic institutions and national laboratories assembled and commissioned by the Tank Vapor Issue Resolution Program.

Headspace vapor characterization of Hanford waste tank 241-U-109: Results from samples collected on 8/10/95

International Nuclear Information System (INIS)

Evans, J.C.; Thomas, B.L.; Pool, K.H.; Olsen, K.B.; Fruchter, J.S.; Silvers, K.L.

1996-05-01

This report describes the analytical results of vapor samples taken from the headspace of the waste storage tank 241-U-109 (Tank U-109) At the Hanford Site in Washington State. The results described in this report were obtained to characterize the vapors present in the tank headspace and to support safety evaluations and tank farm operations. This tank is on the Hydrogen Waste List. The results include air concentrations of selected inorganic and organic analytes and grouped compounds from samples obtained by Westinghouse Hanford Company (WHC) and provided for analysis to Pacific Northwest National Laboratory (PNNL). Analyses were performed by the Vapor Analytical Laboratory (VAL) at PNNL. Analyte concentrations were based on analytical results and, where appropriate, sample volumes provided by WHC. A summary of the inorganic analytes, permanent gases and total non-methane hydrocarbons is listed in a table. The three highest concentration analytes detected in SUMMA trademark canister and triple sorbent trap samples is also listed in the table. Detailed descriptions of the analytical results appear in the text

Single-shell tank retrieval program mission analysis report

Energy Technology Data Exchange (ETDEWEB)

Stokes, W.J.

1998-08-11

This Mission Analysis Report was prepared to provide the foundation for the Single-Shell Tank (SST) Retrieval Program, a new program responsible for waste removal for the SSTS. The SST Retrieval Program is integrated with other Tank Waste Remediation System activities that provide the management, technical, and operations elements associated with planning and execution of SST and SST Farm retrieval and closure. This Mission Analysis Report provides the basis and strategy for developing a program plan for SST retrieval. This Mission Analysis Report responds to a US Department of Energy request for an alternative single-shell tank retrieval approach (Taylor 1997).

Single-shell tank retrieval program mission analysis report

International Nuclear Information System (INIS)

Stokes, W.J.

1998-01-01

This Mission Analysis Report was prepared to provide the foundation for the Single-Shell Tank (SST) Retrieval Program, a new program responsible for waste removal for the SSTS. The SST Retrieval Program is integrated with other Tank Waste Remediation System activities that provide the management, technical, and operations elements associated with planning and execution of SST and SST Farm retrieval and closure. This Mission Analysis Report provides the basis and strategy for developing a program plan for SST retrieval. This Mission Analysis Report responds to a US Department of Energy request for an alternative single-shell tank retrieval approach (Taylor 1997)

Removal of floating organic in Hanford Waste Tank 241-C-103 restart plan

International Nuclear Information System (INIS)

Wilson, T.R.; Hanson, C.

1994-01-01

The decision whether or not to remove the organic layer from Waste Tank 241-C-103 was deferred until May, 1995. The following restart plan was prepared for removal of the organic if the decision is to remove the organic from the waste tank 241-C-103

Removal of floating organic in Hanford Waste Tank 241-C-103 restart plan

Energy Technology Data Exchange (ETDEWEB)

Wilson, T.R.; Hanson, C.

1994-10-03

The decision whether or not to remove the organic layer from Waste Tank 241-C-103 was deferred until May, 1995. The following restart plan was prepared for removal of the organic if the decision is to remove the organic from the waste tank 241-C-103.

Safety equipment list for 241-C-106 waste retrieval, Project W-320: Revision 1

International Nuclear Information System (INIS)

Conner, J.C.

1994-01-01

The goals of the C-106 sluicing operation are: (1) to stabilize the tank by reducing the heat load in the tank to less than 42 MJ/hr (40,000 Btu/hour), and (2) to initiate demonstration of single-shell tank (SST) retrieval technology. The purpose of this supporting document (SD) is as follows: (1) to provide safety classifications for items (systems, structures, equipment, components, or parts) for the waste retrieval sluicing system (WRSS), and (2) to document and methodology used to develop safety classifications. Appropriate references are made with regard to use of existing systems, structures, equipments, components, and parts for C-106 single-shell transfer tank located in the C Tank Farm, and 241-AY-102 (AY-102) double shell receiver tanks (DST) located in the Aging Waste Facility (AWF). The Waste Retrieval Sluicing System consists of two transfer lines that would connect the two tanks, one to carry the sluiced waste slurry to AY-102, and the other to return the supernatant liquid to C-106. The supernatant, or alternate fluid, will be used to mobilize waste in C-106 for the sluicing process. The equipment necessary for the WRSS include pumps in each tank, sluicers to direct the supernatant stream in C-106, a slurry distributor in AY-102, HVAC for C-106, instrumentation and control devices, and other existing components as required

Hanford Tanks 241-C-203 and 241 C 204: Residual Waste Contaminant Release Model and Supporting Data

Energy Technology Data Exchange (ETDEWEB)

Deutsch, William J.; Krupka, Kenneth M.; Lindberg, Michael J.; Cantrell, Kirk J.; Brown, Christopher F.; Schaef, Herbert T.

2007-05-23

This report was revised in May 2007 to correct 90Sr values in Chapter 3. The changes were made on page 3.9, paragraph two and Table 3.10; page 3.16, last paragraph on the page; and Tables 3.21 and 3.31. The rest of the text remains unchanged from the original report issued in October 2004. This report describes the development of release models for key contaminants that are present in residual sludge remaining after closure of Hanford Tanks 241-C-203 (C-203) and 241-C-204 (C-204). The release models were developed from data generated by laboratory characterization and testing of samples from these two tanks. Key results from this work are (1) future releases from the tanks of the primary contaminants of concern (99Tc and 238U) can be represented by relatively simple solubility relationships between infiltrating water and solid phases containing the contaminants; and (2) high percentages of technetium-99 in the sludges (20 wt% in C-203 and 75 wt% in C-204) are not readily water leachable, and, in fact, are very recalcitrant. This is similar to results found in related studies of sludges from Tank AY-102. These release models are being developed to support the tank closure risk assessments performed by CH2M HILL Hanford Group, Inc., for the U.S. Department of Energy.

Tank characterization report for double-shell tank 241-SY-103

International Nuclear Information System (INIS)

Conner, J.M.

1996-01-01

This document summarizes the information on the historical uses, present status, and the sampling and analysis results of waste stored in tank 241-SY-103. This report supports the requirements of Tri-Party Agreement Milestone M-44 09

Tank characterization report for double-shell tank 241-AP-105

International Nuclear Information System (INIS)

Hu, T.A.

1997-01-01

This document summarizes the information on the historical uses, present status, and the sampling and analysis results of waste stored in Tank 241-AP-105. This report supports the requirements of the Tri-Party Agreement Milestone M 44-05

Tank characterization report for double-shell tank 241-SY-103

International Nuclear Information System (INIS)

Hansen, D.R.

1996-01-01

This document summarizes the information on the historical uses, present status, and the sampling and analysis results of waste stored in Tank 241-SY-103. This report supports the requirements of the Tri-Party Agreement Milestone M-44-09

Tank characterization report for double-shell tank 241-AW-102

International Nuclear Information System (INIS)

Bell, K.E.

1997-01-01

This document summarizes the information on the historical uses, present status, and the sampling and analysis results of waste stored in Tank 241-AW-102. This report supports the requirements of the Tri-Party Agreement Milestone M-44-05

Tank characterization report for double-shell tank 241-AW-102

Energy Technology Data Exchange (ETDEWEB)

Bell, K.E.

1997-05-29

This document summarizes the information on the historical uses, present status, and the sampling and analysis results of waste stored in Tank 241-AW-102. This report supports the requirements of the Tri-Party Agreement Milestone M-44-05.

Ultrasonic Examination of Double-Shell Tank 241-AY-101. Examination completed October 2007

International Nuclear Information System (INIS)

Pardini, Allan F.; Weier, Dennis R.

2008-01-01

AREVA NC Inc., under contract from CH2M Hill Hanford Group, has performed an ultrasonic examination of selected portions of Double-Shell Tank 241-AY-101. PNNL is responsible for preparing a report(s) that describes the results of the AREVA ultrasonic examinations. This report is Revision 1 - more data has been added to the original report. The purpose of this examination was to provide information that could be used to evaluate the integrity of the wall of the primary tank. The requirements for the ultrasonic examination of Tank 241-AY-101 were to detect, characterize (identify, size, and locate), and record measurements made of any wall thinning, pitting, or cracks that might be present in the wall of the primary tank. Any measurements that exceed the requirements set forth in the Engineering Task Plan, RPP-Plan-27202 (Jensen 2005) and summarized on page 1 of this document, are to be reported to CH2M Hill Hanford Group and the Pacific Northwest National Laboratory for further evaluation. Under the contract with CH2M Hill Hanford Group, all data is to be recorded on electronic media and paper copies of all measurements are provided to Pacific Northwest National Laboratory for third-party evaluation. Pacific Northwest National Laboratory is responsible for preparing a report(s) that describes the results of the AREVA NC Inc. ultrasonic examinations.

Regulatory compliance analysis for the closure of single-shell tanks

International Nuclear Information System (INIS)

Smith, E.H.; Boomer, K.D.; Letourneau, M.; Oakes, L.; Lorang, R.

1991-08-01

This document provides a regulatory compliance analysis of the baseline environmental protection requirements for the closure of single-shell tanks. In preparing this document, the Westinghouse Hanford Company has analyzed the regulatory pathways and decisions points that have been identified to data through systems engineering and related studies as they relate to environmental protection. This regulatory compliance analysis has resulted in several conclusions that will aid the US Department of Energy in managing the single-shell tank waste and in developing strategies for the closure of these tanks. These conclusions include likely outcomes of current strategies, regulatory rulings that are required for future actions, variances and exemptions to be pursued, where appropriate, and potential rulings that may affect systems engineering and other portions of the single-shell tank closure effort. The conclusions and recommendations presented here are based on analysis of current regulations, regulatory exemptions and variances, and federal facility agreements. Because the remediation of the single-shell tanks will span 30 years, regulations that have yet to be promulgated and future interpretations of existing laws and regulations may impact the recommendations and conclusions presented here. 50 refs., 22 figs

Gas retention and release behavior in Hanford single-shell waste tanks

International Nuclear Information System (INIS)

Stewart, C.W.; Brewster, M.E.; Gauglitz, P.A.; Mahoney, L.A.; Meyer, P.A.; Recknagle, K.P.; Reid, H.C.

1996-12-01

This report describes the current understanding of flammable gas retention and release in Hanford single-shell waste tanks based on theory, experimental results, and observations of tank behavior. The single-shell tanks likely to pose a flammable gas hazard are listed and described, and photographs of core extrusions and the waste surface are included. The credible mechanisms for significant flammable gas releases are described, and release volumes and rates are quantified as much as possible. The only mechanism demonstrably capable of producing large (∼100 m 3 ) spontaneous gas releases is the buoyant displacement, which occurs only in tanks with a relatively deep layer of supernatant liquid. Only the double-shell tanks currently satisfy this condition. All release mechanisms believed plausible in single-shell tanks have been investigated, and none have the potential for large spontaneous gas releases. Only small spontaneous gas releases of several cubic meters are likely by these mechanisms. The reasons several other postulated gas release mechanisms are implausible or incredible are also given

Single Shell Tank (SST) Program Plan

International Nuclear Information System (INIS)

HAASS, C.C.

2000-01-01

This document provides an initial program plan for retrieval of the single-shell tank waste. Requirements, technical approach, schedule, organization, management, and cost and funding are discussed. The program plan will be refined and updated in fiscal year 2000

Single Shell Tank (SST) Program Plan

Energy Technology Data Exchange (ETDEWEB)

HAASS, C.C.

2000-03-21

This document provides an initial program plan for retrieval of the single-shell tank waste. Requirements, technical approach, schedule, organization, management, and cost and funding are discussed. The program plan will be refined and updated in fiscal year 2000.

Data Observations on Double Shell Tank (DST) Flammable Gas Watch List Tank Behavior

Energy Technology Data Exchange (ETDEWEB)

HEDENGREN, D.C.

2000-09-28

This report provides the data from the retained gas sampler, void fraction instrument, ball rheometer, standard hydrogen monitoring system, and other tank data pertinent to gas retention and release behavior in the waste stored in double-shelled Flammable Gas Watch List tanks at Hanford. These include tanks 241-AN-103,241-AN-104, 241-AN-105, 241-AW-101, 241-SY-101, and 241-SY-103. The tanks and the waste they contain are described in terms of fill history and chemistry. The results of mixer pump operation and recent waste transfers and back-dilution in SY-101 are also described. In-situ measurement and monitoring systems are described and the data are summarized under the categories of thermal behavior, waste configuration and properties, gas generation and composition, gas retention and historical gas release behavior.

Process control plan for Single Shell Tank (SST) Saltcake Dissolution Proof of Concept

International Nuclear Information System (INIS)

ESTEY, S.D.

2001-01-01

This document describes the process controls for the tank 241-U-107 (U-107) saltcake dissolution proof-of-concept operations. Saltcake dissolution is defined as a method by which water-soluble salts will be retrieved from the Hanford Site radioactive waste tanks utilizing dissolution as the mobilizing mechanism. The proof-of-concept operations will monitor the retrieval process and transfer at least 100 kgal of fluid from tank U-107 to the double-shell tank (DST) system during the performance period. Tank U-107 has been identified as posing the highest long-term risk to the Columbia River of all single shell tanks (SSTs). This is because of the high content of mobile, long-lived radionuclides mostly in the saltcake waste in the tank. To meet current contractual and consent decree commitments, tank U-107 is being prepared for interim stabilization in August 2001. It is currently scheduled for saltcake retrieval in 2023, near the end of the SST retrieval campaign because of a lack of infrastructure in U-Farm. The proof-of-concept test will install a system to dissolve and retrieve a portion of the saltcake as part of, and operating in parallel with, the standard interim stabilization system to be installed on tank U-107. This proof-of-concept should provide key information on spray nozzle selection and effective spray patterns, leak detection, monitoring, and mitigation (LDMM) and in-tank saltcake solubility data that will help in the design of a full-tank retrieval demonstration system

Gas retention and release behavior in Hanford single-shell waste tanks

Energy Technology Data Exchange (ETDEWEB)

Stewart, C.W.; Brewster, M.E.; Gauglitz, P.A.; Mahoney, L.A.; Meyer, P.A.; Recknagle, K.P.; Reid, H.C.

1996-12-01

This report describes the current understanding of flammable gas retention and release in Hanford single-shell waste tanks based on theory, experimental results, and observations of tank behavior. The single-shell tanks likely to pose a flammable gas hazard are listed and described, and photographs of core extrusions and the waste surface are included. The credible mechanisms for significant flammable gas releases are described, and release volumes and rates are quantified as much as possible. The only mechanism demonstrably capable of producing large ({approximately}100 m{sup 3}) spontaneous gas releases is the buoyant displacement, which occurs only in tanks with a relatively deep layer of supernatant liquid. Only the double-shell tanks currently satisfy this condition. All release mechanisms believed plausible in single-shell tanks have been investigated, and none have the potential for large spontaneous gas releases. Only small spontaneous gas releases of several cubic meters are likely by these mechanisms. The reasons several other postulated gas release mechanisms are implausible or incredible are also given.

Removal of 137-Cs from Dissolved Hanford Tank Saltcake by Treatment with IE-911

International Nuclear Information System (INIS)

Rapko, Brian M.; Sinkov, Sergei I.; Levitskaia, Tatiana G.

2003-01-01

The U.S. Department of Energy's Richland Operations Office plans to accelerate the cleanup of the Hanford Site. Testing new technology for the accelerated cleanup will require dissolved saltcake from single-shell tanks. However, the 137Cs will need to be removed from the saltcake to alleviate radiation hazards. A saltcake composite constructed from archived samples from Hanford Site single-shell tanks 241-S-101, 241-S-109, 241-S-110, 241-S-111, 241-U-106, and 241-U-109 was dissolved in water, adjusted to 5 M Na, and transferred from the 222-S Laboratory to the Radiochemical Processing Laboratory (RPL). At the RPL, the approximately 5.5 liters of solution was passed through a 0.2-micron polyethersulfone filter, collected, and homogenized. The filtered solution then was passed through an ion exchange column containing approximately 150 mL IONSIV(reg s ign) IE-911, an engineered form of crystalline silicotitanate available from UOP, at approximately 200 mL/hour in a continuous operation until all of the feed solution had been run through the column. An analysis of the 137Cs concentrations in the initial feed solution and combined column effluent indicates that > 99.999 percent of the Cs in the feed solution was removed by this operation

Hanford tank initiative test facility site selection study

International Nuclear Information System (INIS)

Staehr, T.W.

1997-01-01

The Hanford Tanks Initiative (HTI) project is developing equipment for the removal of hard heel waste from the Hanford Site underground single-shell waste storage tanks. The HTI equipment will initially be installed in the 241-C-106 tank where its operation will be demonstrated. This study evaluates existing Hanford Site facilities and other sites for functional testing of the HTI equipment before it is installed into the 241-C-106 tank

Thermal and Radiolytic Gas Generation Tests on Material from Tanks 241-U-103, 241-AW-101, 241-S-106, and 241-S-102: Status Report

International Nuclear Information System (INIS)

King, C.M.; Bryan, S.A.

1999-01-01

This report summarizes progress in evaluating thermal and radiolytic flammable gas generation in actual Hanford single-shell tank wastes. The work described was conducted at Pacific Northwest National Laboratory (PNNL) for the Flammable Gas Safety Project, whose purpose is to develop information to support DE and S Hanford (DESH) and Project Management Hanford Contract (PHMC) subcontractors in their efforts to ensure the safe interim storage of wastes at the Hanford Site. This work is related to gas generation studies performed by Numatec Hanford Corporation (formerly Westinghouse Hanford Company). This report describes the results of laboratory tests of gas generation from actual convective layer wastes from Tank 241-U-103 under thermal and radiolytic conditions. Accurate measurements of gas generation rates from highly radioactive tank wastes are needed to assess the potential for producing and storing flammable gases within the tanks. The gas generation capacity of the waste in Tank 241-U-103 is a high priority for the Flammable Gas Safety Program due to its potential for accumulating gases above the flammability limit (Johnson et al, 1997). The objective of this work was to establish the composition of gaseous degradation products formed in actual tank wastes by thermal and radiolytic processes as a function of temperature. The gas generation tests on Tank 241-U-103 samples focused first on the effect of temperature on the composition and rate of gas generation Generation rates of nitrogen, nitrous oxide, methane, and hydrogen increased with temperature, and the composition of the product gas mixture varied with temperature

Engineering Task Plan for Tank 241-C-106 contingency chiller definitive design

International Nuclear Information System (INIS)

Rensink, G.E.; Kriskovich, J.R.

1995-01-01

This document identifies the scope, cost, schedule and responsible organizations for completing a design of a contingency ventilation inlet air cooling system for Tank 241-C-106. The air cooling system, described in Rensink (1995), consists of a chiller, cooling coils, and supporting equipment that, when installed will be capable of assuring that the waste temperatures in Tank 241-C-106 are maintained within acceptable limits for safe storage. The effort described herein is scheduled for completion by May 31, 1995 to support Performance Based Incentive (PBI) Milestone SI-2x

Tank vapor sampling and analysis data package for tank 241-C-106 waste retrieval sluicing system process test phase III

Energy Technology Data Exchange (ETDEWEB)

LOCKREM, L.L.

1999-08-13

This data package presents sampling data and analytical results from the March 28, 1999, vapor sampling of Hanford Site single-shell tank 241-C-106 during active sluicing. Samples were obtained from the 296-C-006 ventilation system stack and ambient air at several locations. Characterization Project Operations (CPO) was responsible for the collection of all SUMMATM canister samples. The Special Analytical Support (SAS) vapor team was responsible for the collection of all triple sorbent trap (TST), sorbent tube train (STT), polyurethane foam (PUF), and particulate filter samples collected at the 296-C-006 stack. The SAS vapor team used the non-electrical vapor sampling (NEVS) system to collect samples of the air, gases, and vapors from the 296-C-006 stack. The SAS vapor team collected and analyzed these samples for Lockheed Martin Hanford Corporation (LMHC) and Tank Waste Remediation System (TWRS) in accordance with the sampling and analytical requirements specified in the Waste Retrieval Sluicing System Vapor Sampling and Analysis Plan (SAP) for Evaluation of Organic Emissions, Process Test Phase III, HNF-4212, Rev. 0-A, (LMHC, 1999). All samples were stored in a secured Radioactive Materials Area (RMA) until the samples were radiologically released and received by SAS for analysis. The Waste Sampling and Characterization Facility (WSCF) performed the radiological analyses. The samples were received on April 5, 1999.

Tank characterization report for single-shell Tank B-201

International Nuclear Information System (INIS)

Heasler, P.G.; Remund, K.M.; Tingey, J.M.; Baird, D.B.; Ryan, F.M.

1994-09-01

The purpose of this report is to characterize the waste in single shell Tank B-201. Characterization includes the determination of the physical, chemical (e.g., concentrations of elements and organic species), and radiological properties of the waste. These determinations are made using analytical results from B-201 core samples as well as historical information about the tank. The main objective is to determine average waste properties: but in some cases, concentrations of analytes as a function of depth were also determined. This report also consolidates the available historical information regarding Tank B-201, arranges the analytical information from the recent core sampling in a useful format, and provides an interpretation of the data within the context of what is known about the tank

45-Day safety screening report for grab samples from Tank 241-AP-107

International Nuclear Information System (INIS)

Miller, G.L.

1995-01-01

Three samples; 107-AP-1C, 107-AP-2c and 107-AP-3C; were received at 222-S Laboratory for analysis of DSC, TGA and visual appearance. Four additional samples; 107-AP-1D, 107-AP-2D, 107-AP-3D and 107-AP-6; were received for visual appearance only. No results exceeded the safety screen notification criteria. This report compiles the analytical results. Tank 241-AP-107 is a double-shell tank which is not on any of the four Watch Lists

Tank characterization report for single-shell tank 241-U-110

International Nuclear Information System (INIS)

Brown, T.M.; Jensen, L.

1993-04-01

This report investigates the nature of the waste in tank U-110 using historical and current information. When characterizing tank waste, several important properties are considered. First, the physical characteristics of the waste are presented, including waste appearance, density, and size of waste particles. The existence of any exotherms in the tank that may present a safety concern is investigated. Finally, the radiological and chemical composition of the tank are presented

Vapor space characterization of waste tank 241-BY-109 (in situ): Results from samples collected on 9/22/94

International Nuclear Information System (INIS)

Pool, K.H.; Clauss, T.W.; Ligotke, M.W.

1995-06-01

This report describes inorganic and organic analyses results from in situ samples obtained from the headspace of the Hanford waste storage Tank 241-BY-109 (referred to as Tank BY-109). The results described here were obtained to support safety and toxicological evaluations. A summary of the results for inorganic and organic analytes is listed in Summary Table 1. Detailed descriptions of the results appear in the text. Quantitative results were obtained for the inorganic compounds ammonia (NH 3 ), nitrogen dioxide (NO 2 ), nitric oxide (NO), and water (H 2 O). Sampling for hydrogen cyanide (HCN) and sulfur oxides (SO x ) was not requested. Organic compounds were also quantitatively determined. Twenty-three organic tentatively identified compounds (TICs) were observed above the detection limit of (ca.) 10 ppbv, but standards for most of these were not available at the time of analysis, and the reported concentrations are semiquantitative estimates. In addition, we looked for the 40 standard TO-14 analytes. We observed 38. Of these, only a few were observed above the 2-ppbv calibrated instrument detection limit. The ten organic analytes with the highest estimated concentrations are listed in Summary Table 1. The ten analytes account for approximately 84% of the total organic components in Tank BY-109

Tank 241-C-103 organic vapor and liquid characterization and supporting activities, Hanford Site, Richland, Washington

International Nuclear Information System (INIS)

1993-01-01

The action proposed is to sample the vapor space and liquid waste and perform other supporting activities in Tank 241-C-103 located in the 241-C Tank Farm on the Hanford Site. Operations at Tank 241-C-103 are curtailed because of an unreviewed safety question (USQ) concerning flammability issues of the organic waste in the tank. This USQ must be resolved before normal operation and surveillance of the tank can resume. In addition to the USQ, Tank 241-C-103 is thought to be involved in several cases of exposure of individuals to noxious vapors. This safety issue requires the use of supplied air for workers in the vicinity of the tank. Because of the USQ, the US Department of Energy proposes to characterize the waste in the vapor space and the organic and aqueous layers, to determine the volume of the organic layer. This action is needed to: (1) assess potential risks to workers, the public, and the environment from continued routine tank operations and (2) provide information on the waste material in the tank to facilitate a comprehensive safety analysis of this USQ. The information would be used to determine if a flammable condition within the tank is credible. This information would be used to prevent or mitigate an accident during continued waste storage and future waste characterization. Alternatives to the proposed activities have been considered in this analysis

Test Results for Caustic Demand Measurements on Tank 241-AX-101 and Tank 241-AX-103 Archive Samples

International Nuclear Information System (INIS)

Doll, Stephanie R.; Bolling, Stacie D.

2016-01-01

Caustic demand testing is used to determine the necessary amount of caustic required to neutralize species present in the Hanford tank waste and obtain a target molarity of free hydroxide for tank corrosion control. The presence and quantity of hydroxide-consuming analytes are just as important in determining the caustic demand as is the amount of free hydroxide present. No single data point can accurately predict whether a satisfactory hydroxide level is being met, as it is dependent on multiple factors (e.g., free hydroxide, buffers, amphoteric metal hydroxides, bicarbonate, etc.). This enclosure contains the caustic demand, scanning electron microscopy (SEM), polarized light microscopy (PLM), and X-ray diffraction (XRD) analysis for the tank 241-AX-101 (AX-101) and 241-AX-103 (AX-103) samples. The work was completed to fulfill a customer request outlined in the test plan, WRPS-1505529, ''Test Plan and Procedure for Caustic Demand Testing on Tank 241-AX-101 and Tank 241-AX-103 Archive Samples.'' The work results will provide a baseline to support planned retrieval of AX-101 and AX-103.

Test Results for Caustic Demand Measurements on Tank 241-AX-101 and Tank 241-AX-103 Archive Samples

Energy Technology Data Exchange (ETDEWEB)

Doll, Stephanie R. [Washington River Protection Solutions, Richland, WA (United States); Bolling, Stacie D. [Washington River Protection Solutions, Richland, WA (United States)

2016-07-14

Caustic demand testing is used to determine the necessary amount of caustic required to neutralize species present in the Hanford tank waste and obtain a target molarity of free hydroxide for tank corrosion control. The presence and quantity of hydroxide-consuming analytes are just as important in determining the caustic demand as is the amount of free hydroxide present. No single data point can accurately predict whether a satisfactory hydroxide level is being met, as it is dependent on multiple factors (e.g., free hydroxide, buffers, amphoteric metal hydroxides, bicarbonate, etc.). This enclosure contains the caustic demand, scanning electron microscopy (SEM), polarized light microscopy (PLM), and X-ray diffraction (XRD) analysis for the tank 241-AX-101 (AX-101) and 241-AX-103 (AX-103) samples. The work was completed to fulfill a customer request outlined in the test plan, WRPS-1505529, “Test Plan and Procedure for Caustic Demand Testing on Tank 241-AX-101 and Tank 241-AX-103 Archive Samples.” The work results will provide a baseline to support planned retrieval of AX-101 and AX-103.

Toxicologic evaluation of analytes from Tank 241-C-103

International Nuclear Information System (INIS)

Mahlum, D.D.; Young, J.Y.; Weller, R.E.

1994-11-01

Westinghouse Hanford Company requested PNL to assemble a toxicology review panel (TRP) to evaluate analytical data compiled by WHC, and provide advice concerning potential health effects associated with exposure to tank-vapor constituents. The team's objectives would be to (1) review procedures used for sampling vapors from tanks, (2) identify constituents in tank-vapor samples that could be related to symptoms reported by workers, (3) evaluate the toxicological implications of those constituents by comparison to establish toxicological databases, (4) provide advice for additional analytical efforts, and (5) support other activities as requested by WHC. The TRP represents a wide range of expertise, including toxicology, industrial hygiene, and occupational medicine. The TRP prepared a list of target analytes that chemists at the Oregon Graduate Institute/Sandia (OGI), Oak Ridge National Laboratory (ORNL), and PNL used to establish validated methods for quantitative analysis of head-space vapors from Tank 241-C-103. this list was used by the analytical laboratories to develop appropriate analytical methods for samples from Tank 241-C-103. Target compounds on the list included acetone, acetonitrile, ammonia, benzene, 1, 3-butadiene, butanal, n-butanol, hexane, 2-hexanone, methylene chloride, nitric oxide, nitrogen dioxide, nitrous oxide, dodecane, tridecane, propane nitrile, sulfur oxide, tributyl phosphate, and vinylidene chloride. The TRP considered constituent concentrations, current exposure limits, reliability of data relative to toxicity, consistency of the analytical data, and whether the material was carcinogenic or teratogenic. A final consideration in the analyte selection process was to include representative chemicals for each class of compounds found

Engineering task plan for determining breathing rates in single shell tanks using tracer gas

International Nuclear Information System (INIS)

Andersen, J.A.

1997-01-01

The testing of single shell tanks to determine breathing rates. Inert tracer gases helium, and sulfur hexafluoride will be injected into the tanks AX-103, BY-105, C-107 and U-103. Periodic samples will be taken over a three month interval to determine actual headspace breathing rates

Single-shell tank interim stabilization project plan

Energy Technology Data Exchange (ETDEWEB)

Ross, W.E.

1998-05-11

This project plan establishes the management framework for conduct of the TWRS Single-Shell Tank Interim Stabilization completion program. Specifically, this plan defines the mission needs and requirements; technical objectives and approach; organizational structure, roles, responsibilities, and interfaces; and operational methods. This plan serves as the project executional baseline.

Assessment of single-shell tank residual-liquid issues at Hanford Site, Washington

International Nuclear Information System (INIS)

Murthy, K.S.; Stout, L.A.; Napier, B.A.; Reisenauer, A.E.; Landstrom, D.K.

1983-06-01

This report provides an assessment of the overall effectiveness and implications of jet pumping the interstitial liquids (IL) from single-shell tanks at Hanford. The jet-pumping program, currently in progress at Hanford, involves the planned removal of IL contained in 89 of the 149 single-shell tanks and its transfer to double-shell tanks after volume reduction by evaporation. The purpose of this report is to estimate the public and worker doses associated with (1) terminating pumping immediately, (2) pumping to a 100,000-gal limit per tank, (3) pumping to a 50,000-gal limit per tank, and (4) pumping to the maximum practical liquid removal level of 30,000 gal. Assessment of the cost-effectiveness of these various levels of pumping in minimizing any undue health and safety risks to the public or worker is also presented

Uncertainties in the measured quantities of water leaving waste Tank 241-C-106 via the ventilation system

Energy Technology Data Exchange (ETDEWEB)

Minteer, D.J.

1995-01-23

The purpose of this analysis is to estimate the uncertainty in the measured quantity of water which typically leaves Tank 241-C-106 via the ventilation system each month. Such measurements are essential for heat removal estimation and tank liquid level verification purposes. The uncertainty associated with the current, infrequent, manual method of measurement (involves various psychrometric and pressure measurements) is suspected to be unreasonably high. Thus, the possible reduction of this uncertainty using a continuous, automated method of measurement will also be estimated. There are three major conclusions as a result of this analysis: (1) the uncertainties associated with the current (infrequent, manual) method of measuring the water which typically leaves Tank 241-C-106 per month via the ventilation system are indeed quite high (80% to 120%); (2) given the current psychrometric and pressure measurement methods and any tank which loses considerable moisture through active ventilation, such as Tank 241-C-106, significant quantities of liquid can actually leak from the tank before a leak can be positively identified via liquid level measurement; (3) using improved (continuous, automated) methods of taking the psychrometric and pressure measurements, the uncertainty in the measured quantity of water leaving Tank 241-C-106 via the ventilation system can be reduced by approximately an order of magnitude.

Uncertainties in the measured quantities of water leaving waste Tank 241-C-106 via the ventilation system

International Nuclear Information System (INIS)

Minteer, D.J.

1995-01-01

The purpose of this analysis is to estimate the uncertainty in the measured quantity of water which typically leaves Tank 241-C-106 via the ventilation system each month. Such measurements are essential for heat removal estimation and tank liquid level verification purposes. The uncertainty associated with the current, infrequent, manual method of measurement (involves various psychrometric and pressure measurements) is suspected to be unreasonably high. Thus, the possible reduction of this uncertainty using a continuous, automated method of measurement will also be estimated. There are three major conclusions as a result of this analysis: (1) the uncertainties associated with the current (infrequent, manual) method of measuring the water which typically leaves Tank 241-C-106 per month via the ventilation system are indeed quite high (80% to 120%); (2) given the current psychrometric and pressure measurement methods and any tank which loses considerable moisture through active ventilation, such as Tank 241-C-106, significant quantities of liquid can actually leak from the tank before a leak can be positively identified via liquid level measurement; (3) using improved (continuous, automated) methods of taking the psychrometric and pressure measurements, the uncertainty in the measured quantity of water leaving Tank 241-C-106 via the ventilation system can be reduced by approximately an order of magnitude

Granulometric data 241-C Tank Farm monitoring well sediments

International Nuclear Information System (INIS)

Fecht, K.R.; Price, W.H.

1977-12-01

Approximately 500 sediment samples collected during the drilling of wells in the 241-C Tank Farm have been analyzed for grain size and calcium carbonate content. The grain size data were used to categorize the sediment samples into sediment classes. The granulometric data, the calcium carbonate data, and the sediment class of each of the 500 sediment samples are documented in this report

Progress toward resolution of vapor problems associated with tank 241-C-103

International Nuclear Information System (INIS)

Huckaby, J.L.; Babad, H.; Story, M.S.

1994-02-01

Noxious and flammable gases and vapors associated with high-level radioactive waste storage tank 241-C-103 at the Hanford Site are discussed. Focus is on the Westinghouse Hanford Company strategy to characterize the tank headspace. The sampling and analysis methodology is described. Sampling limitations, devices, and equipment are discussed. Results to date are given

Characterization of the corrosion behavior of the carbon steel liner in Hanford Site single-shell tanks

International Nuclear Information System (INIS)

Anantatmula, R.P.; Schwenk, E.B.; Danielson, M.J.

1994-06-01

Six safety initiatives have been identified for accelerating the resolution of waste tank safety issues and closure of unreviewed safety questions. Safety Initiative 5 is to reduce safety and environmental risk from tank leaks. Item d of Safety Initiative 5 is to complete corrosion studies of single-shell tanks to determine failure mechanisms and corrosion control options to minimize further degradation by June 1994. This report has been prepared to fulfill Safety Initiative 5, Item d. The corrosion mechanisms that apply to Hanford Site single-shell tanks are stress corrosion cracking, pitting/crevice corrosion, uniform corrosion, hydrogen embrittlement, and microbiologically influenced corrosion. The corrosion data relevant to the single-shell tanks dates back three decades, when results were obtained from in-situ corrosion coupons in a few single-shell tanks. Since that time there have been intertank transfers, evaporation, and chemical alterations of the waste. These activities have changed the character and the present composition of the waste is not well characterized. All conclusions and recommendations are made in the absence of relevant laboratory experimental data and tank inspection data. The report attempts to identify the failure mechanisms by a literature survey of carbon steel data in environments similar to the single-shell tank wastes, and by a review of the work performed at the Savannah River Site where similar wastes are stored in similar carbon steel tanks. Based on these surveys, and in the absence of data specific to Hanford single-shell tanks, it may be concluded that the single-shell tanks identified as leakers failed primarily by stress corrosion cracking due to the presence of high nitrate/low hydroxide wastes and residual stresses. In addition, some failures may be attributed to pitting under crevices in low hydroxide locations

Structural qualification of the multifunctional instrument tree for installation in double-shell and 100-series single-shell tanks

International Nuclear Information System (INIS)

Strohlow, J.P.

1995-12-01

This document provides the technical basis and methodology for qualifying the multifunctional instrument tree (MIT) structure for installation in double-shell and 100-series single-shell tanks. Structural qualification for MIT installations in specific tanks are also contained in this document

Single-Shell Tank (SST) Retrieval Sequence Fiscal Year 2000 Update

International Nuclear Information System (INIS)

GARFIELD, J.S.

2000-01-01

This document describes the baseline single-shell tank (SST) waste retrieval sequence for the River Protection Project (RPP) updated for Fiscal Year 2000. The SST retrieval sequence identifies the proposed retrieval order (sequence), the tank selection and prioritization rationale, and planned retrieval dates for Hanford SSTs. In addition, the tank selection criteria and reference retrieval method for this sequence are discussed

Identification of single-shell tank in-tank hardware obstructions to retrieval at Hanford Site Tank Farms

International Nuclear Information System (INIS)

Ballou, R.A.

1994-10-01

Two retrieval technologies, one of which uses robot-deployed end effectors, will be demonstrated on the first single-shell tank (SST) waste to be retrieved at the Hanford Site. A significant impediment to the success of this technology in completing the Hanford retrieval mission is the presence of unique tank contents called in-tank hardware (ITH). In-tank hardware includes installed and discarded equipment and various other materials introduced into the tank. This paper identifies those items of ITH that will most influence retrieval operations in the arm-based demonstration project and in follow-on tank operations within the SST farms

Single-shell tank riser resistance to ground test plan

International Nuclear Information System (INIS)

Kiewert, L.R.

1996-01-01

This Test Procedure provides the general directions for conducting Single-Shell Tank Riser to Earth Measurements which will be used by engineering as a step towards providing closure for the Lightning Hazard Issue

TANK 241-AN-102 MULTI-PROBE CORROSION MONITORING SYSTEM PROJECT LESSONS LEARNED

International Nuclear Information System (INIS)

TAYLOR T; HAGENSEN A; KIRCH NW

2008-01-01

During 2007 and 2008, a new Multi-Probe Corrosion Monitoring System (MPCMS) was designed and fabricated for use in double-shell tank 241-AN-102. The system was successfully installed in the tank on May 1, 2008. The 241-AN-102 MPCMS consists of one 'fixed' in-tank probe containing primary and secondary reference electrodes, tank material electrodes, Electrical Resistance (ER) sensors, and stressed and unstressed corrosion coupons. In addition to the fixed probe, the 241-AN-102 MPCMS also contains four standalone coupon racks, or 'removable' probes. Each rack contains stressed and unstressed coupons made of American Society of Testing and Materials A537 CL1 steel, heat-treated to closely match the chemical and mechanical characteristics of the 241-AN-102 tank wall. These coupon racks can be removed periodically to facilitate examination of the attached coupons for corrosion damage. Along the way to successful system deployment and operation, the system design, fabrication, and testing activities presented a number of challenges. This document discusses these challenges and lessons learned, which when applied to future efforts, should improve overall project efficiency

Tank vapor sampling and analysis data package for tank 241-C-106 waste retrieval sluicing system process test phase III, sampled March 28, 1999

International Nuclear Information System (INIS)

LOCKREM, L.L.

1999-01-01

This data package presents sampling data and analytical results from the March 28, 1999, vapor sampling of Hanford Site single-shell tank 241-C-106 during active sluicing. Samples were obtained from the 296-C-006 ventilation system stack and ambient air at several locations. Characterization Project Operations (CPO) was responsible for the collection of all SUMMATM canister samples. The Special Analytical Support (SAS) vapor team was responsible for the collection of all triple sorbent trap (TST), sorbent tube train (STT), polyurethane foam (PUF), and particulate filter samples collected at the 296-C-006 stack. The SAS vapor team used the non-electrical vapor sampling (NEVS) system to collect samples of the air, gases, and vapors from the 296-C-006 stack. The SAS vapor team collected and analyzed these samples for Lockheed Martin Hanford Corporation (LMHC) and Tank Waste Remediation System (TWRS) in accordance with the sampling and analytical requirements specified in the Waste Retrieval Sluicing System Vapor Sampling and Analysis Plan (SAP) for Evaluation of Organic Emissions, Process Test Phase III, HNF-4212, Rev. 0-A, (LMHC, 1999). All samples were stored in a secured Radioactive Materials Area (RMA) until the samples were radiologically released and received by SAS for analysis. The Waste Sampling and Characterization Facility (WSCF) performed the radiological analyses. The samples were received on April 5, 1999

Project W-211, initial tank retrieval systems, description of operations for 241-AP-102 and 241-AP-104

Energy Technology Data Exchange (ETDEWEB)

RIECK, C.A.

1999-02-25

The primary purpose of the Initial Tank Retrieval Systems (ITRS) is to provide systems for retrieval of radioactive wastes stored in underground double-shell tanks (DSTS) for transfer to alternate storage, evaporation, pretreatment or treatment, while concurrently reducing risks associated with safety watch list and other DSTs. This Description of Operations (DOO) defines the control philosophy for the waste retrieval system for tanks 241-AP-102 (AP-102) and 241-AP-104 (AP-104). This DOO will provide a basis for the detailed design of the Retrieval Control System (RCS) for AP-102 and AP-104 and establishes test criteria for the RCS. The test criteria will be used during qualification testing and acceptance testing to verify operability.

Project W-211, initial tank retrieval systems, description of operations for 241-AP-102 and 241-AP-104

International Nuclear Information System (INIS)

RIECK, C.A.

1999-01-01

The primary purpose of the Initial Tank Retrieval Systems (ITRS) is to provide systems for retrieval of radioactive wastes stored in underground double-shell tanks (DSTS) for transfer to alternate storage, evaporation, pretreatment or treatment, while concurrently reducing risks associated with safety watch list and other DSTs. This Description of Operations (DOO) defines the control philosophy for the waste retrieval system for tanks 241-AP-102 (AP-102) and 241-AP-104 (AP-104). This DOO will provide a basis for the detailed design of the Retrieval Control System (RCS) for AP-102 and AP-104 and establishes test criteria for the RCS. The test criteria will be used during qualification testing and acceptance testing to verify operability

Results of Phase I groundwater quality assessment for single-shell tank waste management Area S-SX at the Hanford Site

International Nuclear Information System (INIS)

Johnson, V.G.; Chou, C.J.

1998-01-01

Pacific Northwest National Laboratory (PNNL) conducted a Phase I, Resource Conservation and Recovery Act of 1976 (RCRA) groundwater quality assessment for the Richland Field Office of the U.S. Department of Energy (DOE-RL), in accordance with the Federal Facility Compliance Agreement. The purpose of the investigation was to determine if the Single-Shell Tank Waste Management Area (WMA) S-SX has impacted groundwater quality. The WMA is located in the southern portion of the 200 West Area of the Hanford Site and consists of the 241-S and 241-SX tank farms and ancillary waste systems. The unit is regulated under RCRA interim-status regulations (40 CFR 265, Subpart F) and was placed in assessment groundwater monitoring (40 CFR 265.93 [d]) in August 1996 because of elevated specific conductance and technetium-99, a non-RCRA co-contaminant, in downgradient monitoring wells. Major findings of the assessment are summarized below: (1) Distribution patterns for radionuclides and RCRA/dangerous waste constituents indicate WMA S-SX has contributed to groundwater contamination observed in downgradient monitoring wells. (2) Drinking water standards for nitrate and technetium-99 are currently exceeded in one RCRA-compliant well (299-W22-46) located at the southeastern comer of the SX tank farm. (3) Technetium-99, nitrate, and chromium concentrations in downgradient well 299-W22-46 (the well with the highest current concentrations) appear to be declining after reaching maximum concentrations in May 1997. (4) Cesium-137 and strontium-90, major constituents of concern in single-shell tank waste, were not detected in any of the RCRA-compliant wells in the WMA network, including the well with the highest current technetium-99 concentrations (299-W22-46). (5) Low but detectable strontium-90 and cesium-137 were found in one old well (2-W23-7), located inside and between the S and SX tank farms

Progress of the Enhanced Hanford Single Shell Tank (SST) Integrity Project

Energy Technology Data Exchange (ETDEWEB)

Venetz, Theodore J. [Washington River Protection Solutions, Richland, WA (United States); Washenfelder, Dennis J. [Washington River Protection Solutions, Richland, WA (United States); Boomer, Kayle D. [Washington River Protection Solutions, Richland, WA (United States); Johnson, Jeremy M. [USDOE Office of River Protection, Richland, WA (United States); Castleberry, Jim L. [Washington River Protection Solutions, Richland, WA (United States)

2015-01-07

To improve the understanding of the single-shell tanks (SSTs) integrity, Washington River Protection Solutions, LLC (WRPS), the USDOE Hanford Site tank contractor, developed an enhanced Single-Shell Tank Integrity Project (SSTIP) in 2009. An expert panel on SST integrity, consisting of various subject matters experts in industry and academia, was created to provide recommendations supporting the development of the project. This panel developed 33 recommendations in four main areas of interest: structural integrity, liner degradation, leak integrity and prevention, and mitigation of contamination migration. In late 2010, seventeen of these recommendations were used to develop the basis for the M-45-10-1 Change Package for the Hanford Federal Agreement and Compliance Order, which is also known as the Tri-Party Agreement.

241-SY Tank Farm Construction Extent of Condition Review for Tank Integrity

Energy Technology Data Exchange (ETDEWEB)

Barnes, Travis J.; Boomer, Kayle D.; Gunter, Jason R.; Venetz, Theodore J.

2013-07-25

This report provides the results of an extent of condition construction history review for tanks 241-SY-101, 241-SY-102, and 241-SY-103. The construction history of the 241-SY tank farm has been reviewed to identify issues similar to those experienced during tank 241-AY-102 construction. Those issues and others impacting integrity are discussed based on information found in available construction records, using tank 241-AY-102 as the comparison benchmark. In the 241-SY tank farm, the third DST farm constructed, refractory quality and stress relief were improved, while similar tank and liner fabrication issues remained.

Calculation note: project W-320 primary ventilation air flow requirements for mitigation of steady state flammable gas concentrations in the headspaces of tanks 241-C-106 and 241-AY-102

International Nuclear Information System (INIS)

Estey, S.D.

1997-01-01

This calculation note analyzes headspace concentrations of hydrogen dependent upon assumed ventilation flow rates provided for tanks 241-C-106 and 241-AY-102. The analyses are based on measured or estimated steady state hydrogen release rates. Tank 241-C-106 is analyzed prior to sluicing; tank 241-AY-102 is analyzed both prior to and after completion of sluicing. Specific analyses, using both best estimated and bounding hydrogen generation rates, include the minimum primary ventilation flow rates required in the tanks to ensure that the steady state hydrogen concentration in the respective tank headspace does not exceed 25% and 100% of the LFL. The headspace hydrogen concentration as a function of time as well as the time required to reach 25% and 100% of LFL upon complete loss of active ventilation, starting from the steady state hydrogen concentration based on a 200 CFM minimum flow rate in tank 241-C-106 and a 100 CFM minimum flow rate in tank241-AY-102. The headspace hydrogen concentration as a function of thee following partial loss of active ventilation (i.e., step changes to l60, l20, 80, and 40 CFM ventilation flow rates) in tank 241-C-106, staffing from a 200 CFM flow rate and the corresponding steady state hydrogen concentration based on the 200 CFM flow rate. The headspace hydrogen concentration as a function of the following partial loss of active ventilation i.e., step changes to 80, 60, 40, and 20 CFM ventilation flow rates) in tank 241-AY-102, starting from a 100 CFM flow rate and the corresponding steady state hydrogen concentration based on the 100 CFM flow rate

Single-Shell Tank (SST) Interim Stabilization Project Plan

International Nuclear Information System (INIS)

VLADIMIROFF, D.T.; BOYLES, V.C.

2000-01-01

This project plan establishes the management framework for the conduct of the CHG Single-Shell Tank Interim Stabilization completion program. Specifically, this plan defines the mission needs and requirements; technical objectives and approach; organization structure, roles, responsibilities, and interfaces; and operational methods. This plan serves as the project executional baseline

Tank 241-AZ-101 and tank 241-AZ-102, airlift circulator operation vapor sampling and analysis plan

International Nuclear Information System (INIS)

TEMPLETON, A.M.

1999-01-01

This sampling and analysis plan (SAP) identifies characterization objectives pertaining to sample collection, laboratory analytical evaluation, and reporting requirements for vapor samples obtained during the operation of the tank 241-AZ-101 and 241-AZ-102 airlift circulators (ALCs). The purpose of the ALC operation is to support portions of the operational test procedure (OTP) for Project W-030 (OTP-W030-001) and to perform functional test in support of Project W-151. Project W-030 is the 241-A-702 ventilation upgrade project (241-AZ-702) and Project W-151 is the 241-AZ-101 Mixer Pump Test. The functional tests will check the operability of the tank 241-AZ-101 ALCs. Process Memo's No.2E98-082 and No.2E99-001 (LMHC 1999a, LMHC 1999b) direct the operation of the ALCs and the Industrial Hygiene monitoring respectively. A series of tests will be conducted in which the ALCs in tanks 241-AZ-101 and 241-AZ-102 will be operated at different air flow rates. Vapor samples will be obtained to determine constituents that may be present in the tank headspace during ALC operation at tanks 241-AZ-101 and 241-AZ-102 as the waste is disturbed. During the testing, vapor samples will be obtained from the headspace of tanks 241-AZ-101 and 241-AZ-102 via the unused port on the standard hydrogen monitoring system (SHMS). Results will be used to provide the waste feed delivery program with environmental air permitting data for tank waste disturbing activities. Because of radiological concerns, the samples will be filtered for particulates. It is recognized that this may remove some organic compounds

Functions and Requirements for Automated Liquid Level Gauge Instruments in Single-Shell and Double-Shell Tank Farms

International Nuclear Information System (INIS)

CARPENTER, K.E.

1999-01-01

This functions and requirements document defines the baseline requirements and criteria for the design, purchase, fabrication, construction, installation, and operation of automated liquid level gauge instruments in the Tank Farms. This document is intended to become the technical baseline for current and future installation, operation and maintenance of automated liquid level gauges in single-shell and double-shell tank farms

EFFECTS OF CHEMISTRY AND OTHER VARIABLES ON CORROSION AND STRESS CORROSION CRACKING IN HANFORD DOUBLE SHELL TANKS

Energy Technology Data Exchange (ETDEWEB)

BROWN MH

2008-11-13

Laboratory testing was performed to develop a comprehensive understanding of the corrosivity of the tank wastes stored in Double-Shell Tanks using simulants primarily from Tanks 241-AP-105, 241-SY-103 and 241-AW-105. Additional tests were conducted using simulants of the waste stored in 241-AZ-102, 241-SY-101, 241-AN-107, and 241-AY-101. This test program placed particular emphasis on defining the range of tank waste chemistries that do not induce the onset of localized forms of corrosion, particularly pitting and stress corrosion cracking. This document summarizes the key findings of the research program.

EFFECTS OF CHEMISTRY AND OTHER VARIABLES ON CORROSION AND STRESS CORROSION CRACKING IN HANFORD DOUBLE-SHELL TANKS

International Nuclear Information System (INIS)

Brown, M.H.

2008-01-01

Laboratory testing was performed to develop a comprehensive understanding of the corrosivity of the tank wastes stored in Double-Shell Tanks using simulants primarily from Tanks 241-AP-105, 241-SY-103 and 241-AW-105. Additional tests were conducted using simulants of the waste stored in 241-AZ-102, 241-SY-101, 241-AN-107, and 241-AY-101. This test program placed particular emphasis on defining the range of tank waste chemistries that do not induce the onset of localized forms of corrosion, particularly pitting and stress corrosion cracking. This document summarizes the key findings of the research program

Organic carbon in Hanford single-shell tank waste

International Nuclear Information System (INIS)

Toth, J.J.; Willingham, C.E.; Heasler, P.G.; Whitney, P.D.

1994-04-01

Safety of Hanford single-shell tanks (SSTs) containing organic carbon is a concern because the carbon in the presence of oxidizers (NO 3 or NO 2 ) is combustible when sufficiently concentrated and exposed to elevated temperatures. A propagating chemical reaction could potentially occur at high temperature (above 200 C). The rapid increase in temperature and pressure within a tank might result in the release of radioactive waste constituents to the environment. The purpose of this study is to gather available laboratory information about the organic carbon waste inventories stored in the Hanford SSTs. Specifically, the major objectives of this investigation are: Review laboratory analytical data and measurements for SST composite core and supernatant samples for available organic data; Assess the correlation of organic carbon estimated utilizing the TRAC computer code compared to laboratory measurements; and From the laboratory analytical data, estimate the TOC content with confidence levels for each of the 149 SSTs

Fifth Single-Shell Tank Integrity Project Expert Panel Meeting August 28-29, 2014

Energy Technology Data Exchange (ETDEWEB)

Martin, Todd M. [Washington River Protection Solutions, LLC, Richland, WA (United States; Gunter, Jason R. [Washington River Protection Solutions, LLC, Richland, WA (United States); Boomer, Kayle D. [Washington River Protection Solutions, LLC, Richland, WA (United States)

2015-01-07

On August 28th and 29th, 2014 the Single-Shell Tank Integrity Project (SSTIP) Expert Panel (Panel) convened in Richland, Washington. This was the Panel’s first meeting since 2011 and, as a result, was focused primarily on updating the Panel on progress in response to the past recommendations (Single-Shell Tank Integrity Expert Panel Report, RPP-RPT-45921, Rev 0, May 2010). This letter documents the Panel’s discussions and feedback on Phase I activities and results.

Program plan for the resolution of tank vapor issues

International Nuclear Information System (INIS)

Osborne, J.W.

1992-09-01

The purpose of this document is to provide a detailed description of the priorities, logic, work breakdown structure (WBS), task descriptions, and program milestones required for the resolution of tank vapor issues associated with the single-shell tanks (SST) and double-shell tanks (DST). The primary objective of this plan is to determine whether a health (personnel exposure) and/or safety (flammability) hazard exists. This plan is focused upon one waste tank, 241-C-103, but contains all elements required to bring the vapor issues to resolution

Acceptance test procedure, 241-SY-101/241-C-106 shot loading system

International Nuclear Information System (INIS)

Ostrom, M.J.

1994-01-01

This Acceptance Test Procedure is for the 241-SY-101/241-C-106 Shot Loading System. The procedure will test the components of the Shot Loading System and its capability of adequately loading shot into the annular space of the Container. The loaded shot will provide shielding as required for transporting and storage of a contaminated pump after removal from the tank. This test serves as verification that the SLS is acceptable for use in the pump removal operations for Tanks 241-SY-101, 241-C-106 and 241-AY-102. The pump removal operation for these three tanks will be performed by two different organizations with different equipment, but the Shot Loading System will be compatible between the two operations

AX Tank Farm tank removal study

International Nuclear Information System (INIS)

SKELLY, W.A.

1998-01-01

This report considers the feasibility of exposing, demolishing, and removing underground storage tanks from the 241-AX Tank Farm at the Hanford Site. For the study, it was assumed that the tanks would each contain 360 ft 3 of residual waste (corresponding to the one percent residual Inventory target cited in the Tri-Party Agreement) at the time of demolition. The 241-AX Tank Farm is being employed as a ''strawman'' in engineering studies evaluating clean and landfill closure options for Hanford single-shell tank farms. The report is one of several reports being prepared for use by the Hanford Tanks Initiative Project to explore potential closure options and to develop retrieval performance evaluation criteria for tank farms

Results Of Physicochemical Characterization And Caustic Dissolution Tests On Tank 241-C-108 Heel Solids

International Nuclear Information System (INIS)

Callaway, W.S.; Huber, H.J.

2010-01-01

Based on an ENRAF waste surface measurement taken February 1, 2009, double-shell tank (DST) 241-AN-106 (AN-106) contained approximately 278.98 inches (793 kgal) of waste. A zip cord measurement from the tank on February 1, 2009, indicated a settled solids layer of 91.7 inches in height (280 kgal). The supernatant layer in February 2009, by difference, was approximately 187 inches deep (514 kgal). Laboratory results from AN-106 February 1, 2009 (see Table 2) grab samples indicated the supernatant was below the chemistry limit that applied at the time as identified in HNF-SD-WM-TSR-006, Tank Farms Technical Safety Requirements, Administrative Control (AC) 5.16, 'Corrosion Mitigation Controls.' (The limits have since been removed from the Technical Safety Requirements (TSR) and are captured in OSD-T-151-00007, Operating Specifications for the Double-Shell Storage Tanks.) Problem evaluation request WRPS-PER-2009-0218 was submitted February 9, 2009, to document the finding that the supernatant chemistry for grab samples taken from the middle and upper regions of the supernatant was noncompliant with the chemistry control limits. The lab results for the samples taken from the bottom region of the supernatant met AC 5.16 limits.

RESULTS OF PHYSICOCHEMICAL CHARACTERIZATION AND CAUSTIC DISSOLUTION TESTS ON TANK 241-C-108 HEEL SOLIDS

Energy Technology Data Exchange (ETDEWEB)

CALLAWAY WS; HUBER HJ

2010-07-01

Based on an ENRAF waste surface measurement taken February 1, 2009, double-shell tank (DST) 241-AN-106 (AN-106) contained approximately 278.98 inches (793 kgal) of waste. A zip cord measurement from the tank on February 1, 2009, indicated a settled solids layer of 91.7 inches in height (280 kgal). The supernatant layer in February 2009, by difference, was approximately 187 inches deep (514 kgal). Laboratory results from AN-106 February 1, 2009 (see Table 2) grab samples indicated the supernatant was below the chemistry limit that applied at the time as identified in HNF-SD-WM-TSR-006, Tank Farms Technical Safety Requirements, Administrative Control (AC) 5.16, 'Corrosion Mitigation Controls.' (The limits have since been removed from the Technical Safety Requirements (TSR) and are captured in OSD-T-151-00007, Operating Specifications for the Double-Shell Storage Tanks.) Problem evaluation request WRPS-PER-2009-0218 was submitted February 9, 2009, to document the finding that the supernatant chemistry for grab samples taken from the middle and upper regions of the supernatant was noncompliant with the chemistry control limits. The lab results for the samples taken from the bottom region of the supernatant met AC 5.16 limits.

Single shell tank sluicing history and failure frequency

International Nuclear Information System (INIS)

HERTZEL, J.S.

1998-01-01

This document assesses the potential for failure of the single-shell tanks (SSTs) that are presumably sound and helps to establish the retrieval priorities for these and the assumed leakers. Furthermore, this report examines probabilities of SST failure as a function of age and operational history, and provides a simple statistical summary of historical leak volumes, leak rates, and corrosion factor

241-AZ Tank Farm Construction Extent of Condition Review for Tank Integrity

Energy Technology Data Exchange (ETDEWEB)

Barnes, Travis J.; Boomer, Kayle D.; Gunter, Jason R.; Venetz, Theodore J.

2013-07-30

This report provides the results of an extent of condition construction history review for tanks 241-AZ-101 and 241-AZ-102. The construction history of the 241-AZ tank farm has been reviewed to identify issues similar to those experienced during tank AY-102 construction. Those issues and others impacting integrity are discussed based on information found in available construction records, using tank AY-102 as the comparison benchmark. In the 241-AZ tank farm, the second DST farm constructed, both refractory quality and tank and liner fabrication were improved.

Review of technologies for the pretreatment of retrieved single-shell tank waste at Hanford

International Nuclear Information System (INIS)

Gerber, M.A.

1992-08-01

The purpose of the study reported here was to identify and evaluate innovative processes that could be used to pretreat mixed waste retrieved from the 149 single-shell tanks (SSTs) on the US Department of Energy's (DOE) Hanford site. The information was collected as part of the Single Shell Tank Waste Treatment project at Pacific Northwest Laboratory (PNL). The project is being conducted for Westinghouse Hanford Company under their SST Disposal Program

Tank waste remediation system (TWRS) privatization contractor samples waste envelope D material 241-C-106

Energy Technology Data Exchange (ETDEWEB)

Esch, R.A.

1997-04-14

This report represents the Final Analytical Report on Tank Waste Remediation System (TWRS) Privatization Contractor Samples for Waste Envelope D. All work was conducted in accordance with ''Addendum 1 of the Letter of Instruction (LOI) for TWRS Privatization Contractor Samples Addressing Waste Envelope D Materials - Revision 0, Revision 1, and Revision 2.'' (Jones 1996, Wiemers 1996a, Wiemers 1996b) Tank 241-C-1 06 (C-106) was selected by TWRS Privatization for the Part 1A Envelope D high-level waste demonstration. Twenty bottles of Tank C-106 material were collected by Westinghouse Hanford Company using a grab sampling technique and transferred to the 325 building for processing by the Pacific Northwest National Laboratory (PNNL). At the 325 building, the contents of the twenty bottles were combined into a single Initial Composite Material. This composite was subsampled for the laboratory-scale screening test and characterization testing, and the remainder was transferred to the 324 building for bench-scale preparation of the Privatization Contractor samples.

Overview Of Enhanced Hanford Single-Shell Tank (SST) Integrity Project - 12128

International Nuclear Information System (INIS)

Venetz, T.J.; Boomer, K.D.; Washenfelder, D.J.; Johnson, J.B.

2012-01-01

To improve the understanding of the single-shell tanks integrity, Washington River Protection Solutions, LLC, the USDOE Hanford Site tank contractor, developed an enhanced Single-Shell Tank (SST) Integrity Project in 2009. An expert panel on SST integrity, consisting of various subject matters experts in industry and academia, was created to provide recommendations supporting the development of the project. This panel developed 33 recommendations in four main areas of interest: structural integrity, liner degradation, leak integrity and prevention, and mitigation of contamination migration, Seventeen of these recommendations were used to develop the basis for the M-45-10-1 Change Package for the Hanford Federal Agreement and Compliance Order, which is also known as the Tri-Party Agreement. The change package identified two phases of work for SST integrity. The initial phase has been focused on efforts to envelope the integrity of the tanks. The initial phase was divided into two primary areas of investigation: structural integrity and leak integrity. If necessary based on the outcome from the initial work, a second phase would be focused on further definition of the integrity of the concrete and liners. Combined these two phases are designed to support the formal integrity assessment of the Hanford SSTs in 2018 by Independent Qualified Registered Engineer. The work to further define the DOE's understanding of the structural integrity SSTs involves preparing a modern Analysis of Record using a finite element analysis program. Structural analyses of the SSTs have been conducted since 1957, but these analyses used analog calculation, less rigorous models, or focused on individual structures. As such, an integrated understanding of all of the SSTs has not been developed to modern expectations. In support of this effort, other milestones will address the visual inspection of the tank concrete and the collection of concrete core samples from the tanks for analysis of

Discovery of the First Leaking Double-Shell Tank - Hanford Tank 241-AY-102

International Nuclear Information System (INIS)

Harrington, Stephanie J.; Sams, Terry L.

2013-01-01

Full text - Long Abstract. A routine video inspection of the annulus region of double-shell tank 241-A Y-102 in August of 2012 indicated the presence material in the annulus space between the primary and secondary liners. A comparison was made to previous inspections performed in 2006 and 2007. which indicated that a change had occurred. The material was observed at two locations on the floor of the annulus and one location at the top of the annulus region where the primary and secondary top knuckles meet (RPP-ASMT-53793). Subsequent inspections were performed. leading to additional material observed on the floor of the annulus space in a region that had not previously been inspected (WRPS-PER-2012-1363). The annulus Continuous Air Monitor (CAM) was still operational and was not indicating elevated radiation levels in the annulus region. When the camera from the inspections was recovered. it also did not indicate increased radiation above minimum contamination levels (WRPS-PER-2012-1363). A formal leak assessment team was established August 10, 2012 to review tank 241-AY-102 construction and operating histories and to determine whether the material observed in the annulus had resulted from a leak in the primary tank. The team consisted of individuals from Engineering. Base Operations and Environmental Protection. As this was a first-of-its-kind task. a method for obtaining a sample of the material in the annulus was needed. The consistency of the material was unknown.and the location of a majority of the material was not conducive to using the sampling devices that were currently available at Hanford. A subcontractor was tasked with the development fabrication.and testing of a sampling device that would be able to obtain multiple samples from the material on the annulus floor. as well as the material originating from a refractory air-slot near the floor of the annulus space. This sampler would need to be able to collect and dispense the material it collected into a

Tank 241-C-111 headspace gas and vapor sample results - August 1993 samples

International Nuclear Information System (INIS)

Huckaby, J.L.

1994-01-01

Tank 241-C-111 is on the ferrocyanide Watch List. Gas and vapor samples were collected to assure safe conditions before planned intrusive work was performed. Sample analyses showed that hydrogen is about ten times higher in the tank headspace than in ambient air. Nitrous oxide is about sixty times higher than ambient levels. The hydrogen cyanide concentration was below 0.04 ppbv, and the average NO x concentration was 8.6 ppmv

Summary of Group Development and Testing for Single Shell Tank Closure at Hanford

International Nuclear Information System (INIS)

Harbour, John R.

2005-01-01

This report is a summary of the bench-scale and large scale experimental studies performed by Savannah River National Laboratory for CH2M HILL to develop grout design mixes for possible use in producing fill materials as a part of Tank Closure of the Single-Shell Tanks at Hanford. The grout development data provided in this report demonstrates that these design mixes will produce fill materials that are ready for use in Hanford single shell tank closure. The purpose of this report is to assess the ability of the proposed grout specifications to meet the current requirements for successful single shell tank closure which will include the contracting of services for construction and operation of a grout batch plant. The research and field experience gained by SRNL in the closure of Tanks 17F and 20F at the Savannah River Site was leveraged into the grout development efforts for Hanford. It is concluded that the three Hanford grout design mixes provide fill materials that meet the current requirements for successful placement. This conclusion is based on the completion of recommended testing using Hanford area materials by the operators of the grout batch plant. This report summarizes the regulatory drivers and the requirements for grout mixes as tank fill material. It is these requirements for both fresh and cured grout properties that drove the development of the grout formulations for the stabilization, structural and capping layers

Monitoring gas retention and slurry transport during the transfer of waste from Tank 241-C-106 to Tank 241-AY-102

International Nuclear Information System (INIS)

Stewart, C.W.; Erian, F.F.; Meyer, P.A.

1997-07-01

The retained gas volume can be estimated by several methods. All of these methods have significant uncertainties, but together they form a preponderance of evidence that describes the gas retention behavior of the tank. The methods are (1) an increase in nonconvective layer thickness; (2) a waste surface level rise (surface level effect [SLE] model); (3) the barometric pressure effect (BPE model); (4) direct void measurement; and (5) the consequences of the transfer process. The nonconvective layer thickness can be determined with sufficient accuracy to describe the overall waste configuration by means of temperature profiles or densitometer indications. However, the presence of a nonconvective layer does not necessarily indicate significant gas retention, and small changes in layer thickness that could quantify gas retention cannot be detected reliably with the methods available. The primary value of this measurement is in establishing the actual open-quotes fluffing factorclose quotes for thermal calculations. Surface level rise is not a useful measure of gas retention in Tank 241-C-106 (C-106) since the waste level fluctuates with regular makeup water additions. In Tank 241-AY-102 (AY-102) with the existing ventilation system it should be possible to determine the gas retention rate within 30-60% uncertainty from the surface level rise, should a significant rise be observed. The planned ventilation system upgrades in AY- 102 will greatly reduce the exhaust flow and the headspace humidity, and the evaporation rate should be significantly lower when transfers begin. This could reduce the uncertainty in gas retention rate estimates to around ± 10%

Ferrocyanide safety program: Heat load and thermal characteristics determination for selected tanks

International Nuclear Information System (INIS)

McLaren, J.M.; Cash, R.J.

1993-11-01

An analysis was conducted to determine the heat loads, conductivities, and heat distributions of waste tanks 241-BY-105, -106, -108, -110, -111, and 241-C-109 at the Hanford Site. The heat distribution of tank 241-BY-111 was determined to be homogeneously distributed throughout the sludge contained in the tank. All of the other tanks, with the exception of 241-C-109, showed evidence of a heat-producing layer at the bottom of the tanks. No evidence of a heat-producing layer in a position above the bottom was found. The thermal conductivities were determined to be within the ranges found by previous laboratory and computer analysis. The heat loads of the tanks were found to be below 2.81 kW (9,600 Btu/hr)

AX Tank Farm tank removal study

Energy Technology Data Exchange (ETDEWEB)

SKELLY, W.A.

1999-02-24

This report examines the feasibility of remediating ancillary equipment associated with the 241-AX Tank Farm at the Hanford Site. Ancillary equipment includes surface structures and equipment, process waste piping, ventilation components, wells, and pits, boxes, sumps, and tanks used to make waste transfers to/from the AX tanks and adjoining tank farms. Two remedial alternatives are considered: (1) excavation and removal of all ancillary equipment items, and (2) in-situ stabilization by grout filling, the 241-AX Tank Farm is being employed as a strawman in engineering studies evaluating clean and landfill closure options for Hanford single-shell tanks. This is one of several reports being prepared for use by the Hanford Tanks Initiative Project to explore potential closure options and to develop retrieval performance evaluation criteria for tank farms.

Evaluation of 241-AZ tank farm supporting phase 1 privatization waste feed delivery

Energy Technology Data Exchange (ETDEWEB)

CARLSON, A.B.

1998-11-19

This evaluation is one in a series of evaluations determining the process needs and assessing the adequacy of existing and planned equipment in meeting those needs at various double-shell tank farms in support of Phase 1 privatization. A number of tank-to-tank transfers and waste preparation activities are needed to process and feed waste to the private contractor in support of Phase 1 privatization. The scope of this evaluation is limited to process needs associated with 241-AZ tank farm during the Phase 1 privatization.

Evaluation of 241-AZ tank farm supporting phase 1 privatization waste feed delivery

International Nuclear Information System (INIS)

CARLSON, A.B.

1998-01-01

This evaluation is one in a series of evaluations determining the process needs and assessing the adequacy of existing and planned equipment in meeting those needs at various double-shell tank farms in support of Phase 1 privatization. A number of tank-to-tank transfers and waste preparation activities are needed to process and feed waste to the private contractor in support of Phase 1 privatization. The scope of this evaluation is limited to process needs associated with 241-AZ tank farm during the Phase 1 privatization

OVERVIEW OF ENHANCED HANFORD SINGLE-SHELL TANK (SST) INTEGRITY PROJECT - 12128

Energy Technology Data Exchange (ETDEWEB)

VENETZ TJ; BOOMER KD; WASHENFELDER DJ; JOHNSON JB

2012-01-25

To improve the understanding of the single-shell tanks integrity, Washington River Protection Solutions, LLC, the USDOE Hanford Site tank contractor, developed an enhanced Single-Shell Tank (SST) Integrity Project in 2009. An expert panel on SST integrity, consisting of various subject matters experts in industry and academia, was created to provide recommendations supporting the development of the project. This panel developed 33 recommendations in four main areas of interest: structural integrity, liner degradation, leak integrity and prevention, and mitigation of contamination migration, Seventeen of these recommendations were used to develop the basis for the M-45-10-1 Change Package for the Hanford Federal Agreement and Compliance Order, which is also known as the Tri-Party Agreement. The change package identified two phases of work for SST integrity. The initial phase has been focused on efforts to envelope the integrity of the tanks. The initial phase was divided into two primary areas of investigation: structural integrity and leak integrity. If necessary based on the outcome from the initial work, a second phase would be focused on further definition of the integrity of the concrete and liners. Combined these two phases are designed to support the formal integrity assessment of the Hanford SSTs in 2018 by Independent Qualified Registered Engineer. The work to further define the DOE's understanding of the structural integrity SSTs involves preparing a modern Analysis of Record using a finite element analysis program. Structural analyses of the SSTs have been conducted since 1957, but these analyses used analog calculation, less rigorous models, or focused on individual structures. As such, an integrated understanding of all of the SSTs has not been developed to modern expectations. In support of this effort, other milestones will address the visual inspection of the tank concrete and the collection of concrete core samples from the tanks for analysis

Permitting plan for project W-320 tank 241-C-106 waste retrieval sluicing system (WRSS)

International Nuclear Information System (INIS)

Symons, G.A.

1997-01-01

This document describes the permitting plan for Project W-320, Tank 241-C-106 Waste Retrieval Sluicing System (WRSS). A comprehensive review of environmental regulations have indicated that several environmental reviews [e.g. National Environmental Policy Act (NEPA), State Environmental Policy Act (SEPA)], permits, and approvals are required prior to construction or operation of the facility. The environmental reviews, permits and approvals, as well the regulatory authority, potentially applicable to the Tank 241-C-106 WRSS include the following: for NEPA - U.S. Department of Energy-Headquarters: Action Description Memorandum, Environmental Assessment, Categorical Exclusion, and Environmental Impact Statement; and for SEPA - State of Washington Department of Ecology (Ecology) Determination of Nonsignificance, Mitigated Determination of Nonsignificance, Determination of Significance, and SEPA Environmental Checklist

Optimization of the Retrieval of Waste from Hanford Tank S-109 through Numerical Modeling

International Nuclear Information System (INIS)

Patel, R.; Tachiev, G.; Mulchandani, A.; Roelant, D.

2009-01-01

This report covers 10 different retrieval scenarios to support the U.S. Department of Energy's Office of River Protection in its mission to facilitate the retrieval and treatment of high-level radioactive waste stored in underground tanks at the Hanford site by investigating the transport properties of the salt-cake. Salt-cake consists of salts precipitated out of the brines during evaporation and storage. The main objective of this study is to gain a better understanding of the dissolution process that will occur in Tank 241-S-109 as it is retrieved to provide waste for Vitrification at the Demonstration Bulk Vitrification System Facility (DBVS). Double Shell Tank (DST) space is extremely limited and will continue to be until the Waste Treatment Plant becomes operational. Maximizing the utilization of DST space is the goal of the S-109 Partial Waste Retrieval Project that will provide waste feed to the Demonstration Bulk Vitrification System (DBVS). Florida International University, FIU has developed a 2-D axisymmetric numerical model which will assist the Department of Energy (DOE) and Savannah River Site (SRS) in evaluating the potential of selective salt-cake retrieval for schedule acceleration and significant cost savings by analyzing the performance of different retrieval scenarios with the prediction of Cs breakthrough curves in the resulting salt-cake brine and to determine the displacement patterns of Cs. This predictive information is critical for scheduling and operational purposes. Ten retrieval scenarios which include addition of flushing liquid at the entire surface of the tank or at a side peripheral channel were simulated. All retrieval scenarios were analyzed for incremental retrieval (saturation of the tank with flushing liquid followed by complete drainage at the central well) versus continuous retrieval (water is continuously added at the top and retrieved at a central well). Furthermore, the specifics of the tank hydrology were approximated

Computational analysis of coupled fluid, heat, and mass transport in ferrocyanide single-shell tanks: FY 1994 interim report. Ferrocyanide Tank Safety Project

International Nuclear Information System (INIS)

McGrail, B.P.

1994-11-01

A computer modeling study was conducted to determine whether natural convection processes in single-shell tanks containing ferrocyanide wastes could generate localized precipitation zones that significantly concentrate the major heat-generating radionuclide, 137 Cs. A computer code was developed that simulates coupled fluid, heat, and single-species mass transport on a regular, orthogonal finite-difference grid. The analysis showed that development of a ''hot spot'' is critically dependent on the temperature dependence for the solubility of Cs 2 NiFe(CN) 6 or CsNaNiFe(CN) 6 . For the normal case, where solubility increases with increasing temperature, the net effect of fluid flow, heat, and mass transport is to disperse any local zones of high heat generation rate. As a result, hot spots cannot physically develop for this case. However, assuming a retrograde solubility dependence, the simulations indicate the formation of localized deposition zones that concentrate the 137 Cs near the bottom center of the tank where the temperatures are highest. Recent experimental studies suggest that Cs 2 NiFe(CN) 6 (c) does not exhibit retrograde solubility over the temperature range 25 degree C to 90 degree C and NaOH concentrations to 5 M. Assuming these preliminary results are confirmed, no natural mass transport process exists for generating a hot spot in the ferrocyanide single-shell tanks

Interim safety equipment list for 241-C-106 waste retrieval, project W-320

International Nuclear Information System (INIS)

Conner, J.C.

1996-01-01

The purpose of this supporting document is to provide safety classifications for systems, structures, and components of the Tank 241-C-106 Waste Retrieval Sluicing System (WRSS) and to document the methodology used to develop these safety classifications. The WRSS requires two transfer lines, one to carry sluiced waste slurry to tank 241-AY-102 and the other to return supernatant to tank 241-C-106; pumps in each tank; sluicers to direct the supernatant stream inside tank 241-C-106; a slurry distributor in tank 241-AY-102; heating, ventilation, and air conditioning for tank 241-C-106; and instrumentation and control devices

Interim safety equipment list for 241-C-106 waste retrieval, project W-320

Energy Technology Data Exchange (ETDEWEB)

Conner, J.C.

1996-01-25

The purpose of this supporting document is to provide safety classifications for systems, structures, and components of the Tank 241-C-106 Waste Retrieval Sluicing System (WRSS) and to document the methodology used to develop these safety classifications. The WRSS requires two transfer lines, one to carry sluiced waste slurry to tank 241-AY-102 and the other to return supernatant to tank 241-C-106; pumps in each tank; sluicers to direct the supernatant stream inside tank 241-C-106; a slurry distributor in tank 241-AY-102; heating, ventilation, and air conditioning for tank 241-C-106; and instrumentation and control devices.

Tank 241-TX-105 vapor sampling and analysis tank characterization report

International Nuclear Information System (INIS)

Huckaby, J.L.

1995-01-01

Tank 241-TX-105 headspace gas and vapor samples were collected and analyzed to help determine the potential risks to tank farm workers due to fugitive emissions from the tank. The drivers and objectives of waste tank headspace sampling and analysis are discussed in open-quotes Program Plan for the Resolution of Tank Vapor Issues.close quotes Tank 241-TX-105 was vapor sampled in accordance with open-quotes Data Quality Objectives for Generic In-Tank Health and Safety Issue Resolution.close quotes

Tank 241-BY-107 vapor sampling and analysis tank characterization report

International Nuclear Information System (INIS)

Huckaby, J.L.

1995-01-01

Tank 241-BY-107 headspace gas and vapor samples were collected and analyzed to help determine the potential risks to tank farm workers due to fugitive emissions from the tank. The drivers and objectives of waste tank headspace sampling and analysis are discussed in open-quotes Program Plan for the Resolution of Tank Vapor Issuesclose quotes. Tank 241-BY-107 was vapor sampled in accordance with open-quotes Data Quality Objectives for Generic In-Tank Health and Safety Issue Resolutionclose quotes

Tank 241-BY-111 vapor sampling and analysis tank characterization report

International Nuclear Information System (INIS)

Huckaby, J.L.

1995-01-01

Tank 241-BY-111 headspace gas and vapor samples were collected and analyzed to help determine the potential risks to tank farm workers due to fugitive emissions from the tank. The drivers and objectives of waste tank headspace sampling and analysis are discussed in open-quotes Program Plan for the Resolution of Tank Vapor Issues.close quotes Tank 241-BY-111 was vapor sampled in accordance with open-quotes Data Quality Objectives for Generic In-Tank Health and Safety Issue Resolution.close quotes

Tank 241-TX-118 vapor sampling and analysis tank characterization report

International Nuclear Information System (INIS)

Huckaby, J.L.

1995-01-01

Tank 241-TX-118 headspace gas and vapor samples were collected and analyzed to help determine the potential risks to tank farm workers due to fugitive emissions from the tank. The drivers and objectives of waste tank headspace sampling and analysis are discussed in open-quotes Program Plan for the Resolution of Tank Vapor Issues.close quotes Tank 241-TX-118 was vapor sampled in accordance with open-quotes Data Quality Objectives for Generic In-Tank Health and Safety Issue Resolution.close quotes

Tank 241-BY-112 vapor sampling and analysis tank characterization report

International Nuclear Information System (INIS)

Huckaby, J.L.

1995-01-01

Tank 241-BY-112 headspace gas and vapor samples were collected and analyzed to help determine the potential risks to tank farm workers due to fugitive emissions from the tank. The drivers and objectives of waste tank headspace sampling and analysis are discussed in open-quotes Program Plan for the Resolution of Tank Vapor Issues.close quotes Tank 241-BY-112 was vapor sampled in accordance with open-quotes Data Quality Objectives for Generic In-Tank Health and Safety Issue Resolution.close quotes

Tank 241-BY-103 vapor sampling and analysis tank characterization report

International Nuclear Information System (INIS)

Huckaby, J.L.

1995-01-01

Tank 241-BY-103 headspace gas and vapor samples were collected and analyzed to help determine the potential risks to tank farm workers due to fugitive emissions from the tank. The drivers and objectives of waste tank headspace sampling and analysis are discussed in open-quotes Program Plan for the Resolution of Tank Vapor Issues.close quotes Tank 241-BY-103 was vapor sampled in accordance with open-quotes Data Quality Objectives for Generic In-Tank Health and Safety Issue Resolution.close quotes

Tank 241-U-107 vapor sampling and analysis tank characterization report

Energy Technology Data Exchange (ETDEWEB)

Huckaby, J.L.

1995-05-31

Tank 241-U-107 headspace gas and vapor samples were collected and analyzed to help determine the potential risks to tank farm workers due to fugitive emissions from the tank. The drivers and objectives of waste tank headspace sampling and analysis are discussed in {open_quotes}Program Plan for the Resolution of Tank Vapor Issues.{close_quotes} Tank 241-U-107 was vapor sampled in accordance with {open_quotes}Data Quality Objectives for Generic In-Tank Health and Safety Issue Resolution.{close_quotes}

Tank 241-Z-361 process and characterization history

International Nuclear Information System (INIS)

Jones, S.A.

1998-01-01

An Unreviewed Safety Question (Wagoner, 1997) was declared based on lack of adequate authorization basis for Tank 241-Z-361 in the 200W Area at Hanford. This document is a summary of the history of Tank 241-Z-361 through December 1997. Documents reviewed include engineering files, laboratory notebooks from characterization efforts, waste facility process procedures, supporting documents and interviews of people's recollections of over twenty years ago. Records of transfers into the tank, past characterization efforts, and speculation were used to estimate the current condition of Tank 241-Z-361 and its contents. Information about the overall waste system as related to the settling tank was included to help in understanding the numbering system and process relationships. The Plutonium Finishing Plant was built in 1948 and began processing plutonium in mid-1949. The Incinerator (232-Z) operated from December 1961 until May 1973. The Plutonium Reclamation Facility (PRF, 236-Z) began operation in May 1964. The Waste Treatment Facility (242-Z) operated from August 1964 until August 1976. Waste from some processes went through transfer lines to 241-Z sump tanks. High salt and organic waste under normal operation were sent to Z-9 or Z-18 cribs. Water from the retention basin may have also passed through this tank. The transfer lines to 241-Z were numbered D-4 to D-6. The 241-Z sump tanks were numbered D-4 through D-8. The D-4, 5, and 8 drains went to the D-6 sump tank. When D-6 tank was full it was transferred to D-7 tank. Prior to transfer to cribs, the D-7 tank contents was sampled. If the plutonium content was analyzed to be more than 10 g per batch, the material was (generally) reprocessed. Below the discard limit, caustic was added and the material was sent to the cribs via the 241-Z-361 settling tank where solids settled out and the liquid overflowed by gravity to the cribs. Waste liquids that passed through the 241-Z-361 settling tank flowed from PFP to ground in

Tank 241-BY-108 tank characterization plan

International Nuclear Information System (INIS)

Carpenter, B.C.

1994-01-01

The sampling and analytical needs associated with the 51 Hanford Site underground storage tanks classified on one or more of the four Watch Lists (ferrocyanide, organic, flammable gas, and high heat), and the safety screening of all 177 tanks have been identified through the Data Quality Objective (DQO) process. DQOs identity information needed by a program group in the Tank Waste Remediation System concerned with safety issues, regulatory requirements, or the transporting and processing of tank waste. This Tank Characterization Plan will identify characterization objectives for tank BY-108 pertaining to sample collection, sample preparation and analysis, and laboratory analytical evaluation and reporting requirements. In addition, an estimate of the current contents and status of the tank is given. Single-shell tank BY-108 is classified as a Ferrocyanide Watch List tank. The tank was declared an assumed leaker and removed from service in 1972; interim stabilized was completed in February 1985. Although not officially an Organic Watch List tank, restrictions have been placed on intrusive operations by Standing Order number-sign 94-16 (dated 09/08/94) since the tank is suspected to contain or to have contained a floating organic layer

Mission analysis report for single-shell tank leakage mitigation

International Nuclear Information System (INIS)

Cruse, J.M.

1994-01-01

This document provides an analysis of the leakage mitigation mission applicable to past and potential future leakage from the Hanford Site's 149 single-shell high-level waste tanks. This mission is a part of the overall missions of the Westinghouse Hanford Company Tank Waste Remediation System division to remediate the tank waste in a safe and acceptable manner. Systems engineers principles are being applied to this effort. Mission analysis supports early decision making by clearly defining program objectives. This documents identifies the initial conditions and acceptable final conditions, defines the programmatic and physical interfaces and constraints, estimates the resources to carry out the mission, and establishes measures of success. The results of the mission analysis provide a consistent basis for subsequent systems engineering work

Test plan for evaluation of primary exhaust ventilation flow meters for double shell hydrogen watch list tanks

International Nuclear Information System (INIS)

Willingham, W.E.

1996-01-01

This document is a plan for testing four different flow meters for use in the primary exhaust ventilation ducts of Double Shell Tanks on the hydrogen watch list that do not already have this capability. This currently includes tanks 241-AW-101, 241-AN-103, 241-AN-104, 241-AN-105, and 241-SY-103. The anticipated airflow velocity in these tanks range from 0.25 m/s(50 ft/min) to 1.78 m/s (350 ft/min). Past experiences at Hanford are forcing the evaluation and selection of instruments to be used at the low flow and relatively high humidity conditions found in these tanks. Based on the results of this test, a flow meter shall be chosen for installation in the primary exhaust ventilation ducts of the above mentioned waste tanks

Consequences of a radioactive surface pool resulting from waste transfer operations between tanks 214-C-106 and 241-AY-102

International Nuclear Information System (INIS)

Van Vleet, R.J.

1997-01-01

This document contains supporting calculations for quantifying the dose consequences from a pool formed from an underground leak or a-leak from an above grade structure for the Waste Retrieval Sluicing System (Project W-320), i.e., sluicing the contents of Tank 241-C-106 (high heat, SST) into Tank 241-AY-102 (aging waste, DST)

Consequences of a radioactive surface pool resulting from waste transfer operations between tanks 214-C-106 and 241-AY-102

Energy Technology Data Exchange (ETDEWEB)

Van Vleet, R.J.

1997-08-05

This document contains supporting calculations for quantifying the dose consequences from a pool formed from an underground leak or a-leak from an above grade structure for the Waste Retrieval Sluicing System (Project W-320), i.e., sluicing the contents of Tank 241-C-106 (high heat, SST) into Tank 241-AY-102 (aging waste, DST).

Contingency plan for deployment of the void fraction instrument in Tank 241-AY-102

International Nuclear Information System (INIS)

CONNER, J.M.

1999-01-01

High-heat producing sludge from tank 241-C-106 will be sluiced and transferred to tank 241-AY-102 beginning in October 1998. Safety analyses have postulated that after retrieval, the waste in 241-AY-102 may generate and retain unsafe levels of flammable gases (Noorani 1998, Pasamebmetoglu etal. 1997). Unsafe levels of retained gas are not expected, but cannot be ruled out because of the large uncertainty in the gas generation and retention rates. The Tank Waste Remediation System Basis for Interim Operation (Noorani 1998) identifies the need for a contingency plan to add void fraction monitoring to tank 241-AY-102 within 2 weeks of the identification of flammable gas buildup that would warrant monitoring. The Tank 241-C-106 Waste Retrieval Sluicing System Process Control Plan (Carothers et al. 1998) committed to providing a contingency plan for deployment of the void fraction instrument (VFI) in tank 241-AY-102. The VFI determines the local void fraction of the waste by compressing a waste sample captured in a gas-tight test chamber. The sample chamber is mounted on the end of a 76-cm (2.5-ft) arm that can be rotated from vertical to horizontal when the instrument is deployed. Once in the waste, the arm can be positioned horizontally and rotated to sample in different areas below the riser. The VFI is deployed using a crane. The VFI has been deployed previously in 241-AW, 241-AN, and 241-SY tank farms, most recently in tank 241-SY-101 in June and July 1998. An additional test in tank 241-SY-101 is planned in September 1998. Operating instructions for the VFI are included in the Void Fraction Instrument Operation and Maintenance Manual (Pearce 1994)

Engineering Task Plan for a vapor treatment system on Tank 241-C-103

International Nuclear Information System (INIS)

Conrad, R.B.

1995-01-01

This Engineering Task Plan describes tasks and responsibilities for the design, fabrication, test, and installation of a vapor treatment system (mixing system) on Tank 241-C-103. The mixing system is to be installed downstream of the breather filter and will use a mixing blower to reduce the chemical concentrations to below allowable levels

Performance evaluation of rotating pump jet mixing of radioactive wastes in Hanford Tanks 241-AP-102 and -104

International Nuclear Information System (INIS)

Onishi, Y.; Recknagle, K.P.

1998-07-01

The purpose of this study was to confirm the adequacy of a single mixer pump to fully mix the wastes that will be stored in Tanks 241-AP-102 and -104. These Hanford double-shell tanks (DSTs) will be used as staging tanks to receive low-activity wastes from other Hanford storage tanks and, in turn, will supply the wastes to private waste vitrification facilities for eventual solidification. The TEMPEST computer code was applied to Tanks AP-102 and -104 to simulate waste mixing generated by the 60-ft/s rotating jets and to determine the effectiveness of the single rotating pump to mix the waste. TEMPEST simulates flow and mass/heat transport and chemical reactions (equilibrium and kinetic reactions) coupled together. Section 2 describes the pump jet mixing conditions the authors evaluated, the modeling cases, and their parameters. Section 3 reports model applications and assessment results. The summary and conclusions are presented in Section 4, and cited references are listed in Section 5

Analysis of organic carbon and moisture in Hanford single-shell tank waste

Energy Technology Data Exchange (ETDEWEB)

Toth, J.J.; Heasler, P.G.; Lerchen, M.E.; Hill, J.G.; Whitney, P.D.

1995-05-01

This report documents a revised analysis performed by Pacific Northwest Laboratory involving the organic carbon laboratory measurement data for Hanford single-shell tanks (SSTs) obtained from a review of the laboratory analytical data. This activity has as its objective to provide a best-estimate, including confidence levels, of total organic carbon (TOC) and moisture in each of the 149 SSTs at Hanford. The TOC and moisture information presented in this report is useful as part of the criteria to identify SSTs for additional measurements, or monitoring for the Organic Safety Program. In April 1994, an initial study of the organic carbon in Hanford single-shell tanks was completed at PNL. That study reflected the estimates of TOC based on tank characterizations datasets that were available at the time. Also in that study, estimation of dry basis TOC was based on generalized assumptions pertaining to the moisture of the tank wastes. The new information pertaining to tank moisture and TOC data that has become available from the current study influences the best estimates of TOC in each of the SSTs. This investigation of tank TOC and moisture has resulted in improved estimates based on waste phase: saltcake, sludge, or liquid. This report details the assumptions and methodologies used to develop the estimates of TOC and moisture in each of the 149 SSTs at Hanford.

Analysis of organic carbon and moisture in Hanford single-shell tank waste

International Nuclear Information System (INIS)

Toth, J.J.; Heasler, P.G.; Lerchen, M.E.; Hill, J.G.; Whitney, P.D.

1995-05-01

This report documents a revised analysis performed by Pacific Northwest Laboratory involving the organic carbon laboratory measurement data for Hanford single-shell tanks (SSTs) obtained from a review of the laboratory analytical data. This activity has as its objective to provide a best-estimate, including confidence levels, of total organic carbon (TOC) and moisture in each of the 149 SSTs at Hanford. The TOC and moisture information presented in this report is useful as part of the criteria to identify SSTs for additional measurements, or monitoring for the Organic Safety Program. In April 1994, an initial study of the organic carbon in Hanford single-shell tanks was completed at PNL. That study reflected the estimates of TOC based on tank characterizations datasets that were available at the time. Also in that study, estimation of dry basis TOC was based on generalized assumptions pertaining to the moisture of the tank wastes. The new information pertaining to tank moisture and TOC data that has become available from the current study influences the best estimates of TOC in each of the SSTs. This investigation of tank TOC and moisture has resulted in improved estimates based on waste phase: saltcake, sludge, or liquid. This report details the assumptions and methodologies used to develop the estimates of TOC and moisture in each of the 149 SSTs at Hanford

Tank 241-U-111 tank characterization plan

International Nuclear Information System (INIS)

Carpenter, B.C.

1995-01-01

This document is a plan which serves as the contractual agreement between the Characterization Program, Sampling Operations, Oak Ridge National Laboratory, and PNL tank vapor program. The scope of this plan is to provide guidance for the sampling and analysis of vapor samples from tank 241-U-111

Tank 241-BX-104 tank characterization plan

International Nuclear Information System (INIS)

Carpenter, B.C.

1994-01-01

This document is a plan which serves as the contractual agreement between the Characterization Program, Sampling Operations, Oak Ridge National Laboratory, and PNL tank vapor program. The scope of this plan is to provide guidance for the sampling and analysis of vapor samples from tank 241-BX-104

Tank 241-U-103 tank characterization plan

International Nuclear Information System (INIS)

Carpenter, B.C.

1995-01-01

This document is a plan which serves as the contractual agreement between the Characterization Program, Sampling Operations, Oak Ridge National Laboratory and PNL tank vapor program. The scope of this plan is to provide guidance for the sampling and analysis of vapor samples from tank 241-U-103

Tank 241-TX-118 tank characterization plan

International Nuclear Information System (INIS)

Carpenter, B.C.

1994-01-01

This document is a plan which serves as the contractual agreement between the Characterization Program, Sampling Operations, Oak Ridge National Laboratory, and PNL tank vapor program. The scope of this plan is to provide guidance for the sampling and analysis of vapor samples from tank 241-TX-118

Tank 241-T-111 tank characterization plan

International Nuclear Information System (INIS)

Homi, C.S.

1995-01-01

This document is a plan which serves as the contractual agreement between the Characterization Program, Sampling Operations, Oak Ridge National Laboratory, and PNL tank vapor program. The scope of this plan is to provide guidance for the sampling and analysis of vapor samples from tank 241-T-111

Tank 241-TY-101 Tank Characterization Plan

International Nuclear Information System (INIS)

Homi, C.S.

1995-01-01

This document is a plan which serves as the contractual agreement between the Characterization Program, Sampling Operations, Oak Ridge National Laboratory, and PNL tank vapor program. The scope of this plan is to provide guidance for the sampling and analysis of vapor samples from tank 241-TY-101

Tank 241-T-107 tank characterization plan

International Nuclear Information System (INIS)

Homi, C.S.

1995-01-01

This document is a plan which serves as the contractual agreement between the Characterization Program, Sampling Operations, Oak Ridge National Laboratory, and PNL tank vapor program. The scope of this plan is to provide guidance for the sampling and analysis of vapor samples from tank 241-T-107

Tank 24-C-103 headspace flammability

International Nuclear Information System (INIS)

Huckaby, J.L.

1994-05-01

Information regarding flammable vapors, gases, and aerosols is presented and interpreted to help resolve the tank 241-C-103 headspace flammability issue. Analyses of recent vapor and liquid samples, as well as visual inspections of the tank headspace, are discussed in the context of tank dynamics. Concern that the headspace of tank 241-C-103 may contain a flammable mixture of organic vapors and an aerosol of combustible organic liquid droplets arises from the presence of a layer of organic liquid in the tank. This organic liquid is believed to have originated in the plutonium-uranium extraction (PUREX) process, having been stored initially in tank 241-C-102 and apparently transferred to tank 241-C-103 in 1975 (Carothers 1988). Analyses of samples of the organic liquid collected in 1991 and 1993 indicate that the primary constituents are tributyl phosphate (TBP) and several semivolatile hydrocarbons (Prentice 1991, Pool and Bean 1994). This is consistent with the premise that the organic waste came from the PUREX process, because the PUREX process used a solution of TBP in a diluent composed of the n-C 11 H 24 to n-C 15 H 32 normal paraffinic hydrocarbons (NPH)

Tank 241C106 structural evaluation in support of Project W320 retrieval

International Nuclear Information System (INIS)

Wallace, D.A.

1994-10-01

Tank 241C106 structural evaluation to support W320. It includes ACI code input and riser evaluations. This work uses the in situ conditions established by Julyk to develop a three-dimensional model of the tank. Non-axisymmetric loads associated with retrieval activities are applied to assess their influence on structural integrity of the tank. This study addresses loads associated with normal opertion and credible accident scenarios. The concrete structure of tank C106 is classified as a Safety Class I non-reactor structure in accordance with the definition given in SDC 4.1. The operating specifications document (OSD) limits applicable to tank C106 include a live load limit for the C Tank Farm of 100 tons. For the technical basis of this limit, the OSD references SD-RE-TI-012, which qualifies the 100 tons as that distributed over a 10-ft radius. However, there is no specification for a uniform live load that would accompany natural hazard phenomena such as snow or ash fall. There is no specific guidance on crane loads applied at the surface outside the tank radius. Further, there is no record of any seismic analysis of tanks in the C Tank Farm. The analysis documented in this report evaluates nonseismic conditions that include a concentrated live load, a uniform live load, and a crane load, in addition to the in situ loads. The model documented in this study also is used to provide the nonseismic stress contribution to the seismic load combination documented by Wallace

ELECTROCHEMICAL STUDIES OF CARBON STEEL CORROSION IN HANFORD DOUBLE SHELL TANK (DST) WASTE

Energy Technology Data Exchange (ETDEWEB)

DUNCAN, J.B.; WINDISCH, C.F.

2006-10-13

This paper reports on the electrochemical scans for the supernatant of Hanford double-shell tank (DST) 241-SY-102 and the electrochemical scans for the bottom saltcake layer for Hanford DST 241-AZ-102. It further reports on the development of electrochemical test cells adapted to both sample volume and hot cell constraints.

CORROSION MONITORING IN HANFORD NUCLEAR WASTE STORAGE TANKS, DESIGN AND DATA FROM 241-AN-102 MULTI-PROBE CORROSION MONITORING SYSTEM

International Nuclear Information System (INIS)

ANDA, V.S.; EDGEMON, G.L.; HAGENSEN, A.R.; BOOMER, K.D.; CAROTHERS, K.G.

2009-01-01

In 2008, a new Multi-Probe Corrosion Monitoring System (MPCMS) was installed in double-shell tank 241-AN-102 on the U.S. Department of Energy's Hanford Site in Washington State. Developmental design work included laboratory testing in simulated tank 241-AN-102 waste to evaluate metal performance for installation on the MPCMS as secondary metal reference electrodes. The MPCMS design includes coupon arrays as well as a wired probe which facilitates measurement of tank potential as well as corrosion rate using electrical resistance (ER) sensors. This paper presents the MPCMS design, field data obtained following installation of the MPCMS in tank 241-AN-102, and a comparison between laboratory potential data obtained using simulated waste and tank potential data obtained following field installation

Independent Review of Tank 241-AY-101 Fitness for Service

International Nuclear Information System (INIS)

Stewart, Charles W.; Bush, Spencer H.; Delegard, Calvin H.; Elmore, Monte R.; Johnson, A Burton Jr.; Pardini, Allan F.; Posakony, Gerald J.; Simonen, Fredric A.; Terry, Michael T.; Zapp, Philip E.

2003-01-01

Video inspections in the annulus of Hanford double-shell waste storage tank 241-AY-101 in 2001 and earlier showed rust over large areas of the primary and secondary tank walls. These observations led to extensive on-destructive inspections and analyses to determine the extent and severity of the corrosion and correction of several operational deficiencies that contributed to the problem. PNNL has performed an independent review of the accumulated evidence from these efforts to determine whether unacceptable conditions were corrected and the current condition of the tank meets or exceeds technical and operational requirements. The findings of this review are the subject of this report. The conclusion is that AY-101 is fit for service without restriction subject to several recommendations for further inspections and analyses

Tank 241-TX-105 tank characterization plan

International Nuclear Information System (INIS)

Carpenter, B.C.

1995-01-01

This document is a plan which serves as the contractual agreement between the Characterization Program, Sampling Operations, WHC 222-S Laboratory, Oak Ridge National Laboratory, and PNL tank vapor program. The scope of this plan is to provide guidance for the sampling and analysis of vapor samples from tank 241-TX-105

Single Shell Tank Waste Characterization Project for Tank B-110, Core 9 - data package and PNL validation summary report

International Nuclear Information System (INIS)

Pool, K.N.; Jones, T.E.; McKinley, S.G.; Tingey, J.M.; Longaker, T.M.; Gibson, J.A.

1990-01-01

This Data Package contains results obtained by Pacific Northwest Laboratory (PNL) staff in the characterization and analyses of Core 9 segments taken from the Single-Shell Tank (SST) 110B. The characterization and analysis of Core 9 segments are outlined in the Waste Characterization Plan for Hanford Site Single-Shell Tanks and in the Pacific Northwest Laboratory (PNL) Single-Shell Tank Waste Characterization Support FY 89/90 Statement of Work (SOW), Rev. 1 dated March, 1990. Specific analyses for each sub-sample taken from a segment are delineated in Test Instructions prepared by the PNL Single-Shell Tank Waste Characterization Project Management Office (SST Project) in accordance with procedures contained in the SST Waste Characterization Procedure Compendium (PNL-MA-599). Analytical procedures used in the characterization activities are also included in PNL-MA-599. Core 9 included five segments although segment 1 did not have sufficient material for characterization. The five samplers were received from Westinghouse Hanford Company (WHC) on 11/21-22/89. Each segment was contained in a sampler and was enclosed in a shipping cask. The shipping cask was butted up to the 325-A hot cell and the sampler moved into the hot cell. The material in the sampler (i.e., the segment) was extruded from the sampler, limited physical characteristics assessed, and photographed. At this point samples were taken for particle size and volatile organic analyses. Each segment was then homogenized. Sub-samples were taken for required analyses as delineated in the appropriate Test Instruction. Table 1 includes sample numbers assigned to Core 9 segment materials being transferred from 325-A Hot Cell. Sample numbers 90-0298, 90-0299, 90-0302, and 90-0303 were included in Table 1 although no analyses were requested for these samples. Table 2 lists Core 9 sub-sample numbers per sample preparation method

Hazard evaluation for transfer of waste from tank 241-SY-101 to tank 241-SY-102

International Nuclear Information System (INIS)

Shultz, M.V.

1999-01-01

Tank 241-SY-101 waste level growth is an emergent, high priority issue. The purpose of this document is to record the hazards evaluation process and document potential hazardous conditions that could lead to the release of radiological and toxicological material from the proposed transfer of a limited quantity (approximately 100,000 gallons) of waste from Tank 241-SY-101 to Tank 241-SY-102. The results of the hazards evaluation were compared to the current Tank Waste Remediation System (TWRS) Basis for Interim Operation (HNF-SD-WM-BIO-001, 1998, Revision 1) to identify any hazardous conditions where Authorization Basis (AB) controls may not be sufficient or may not exist. Comparison to LA-UR-92-3196, A Safety Assessment for Proposed Pump Mixing Operations to Mitigate Episodic Gas Releases in Tank 241-SY-101, was also made in the case of transfer pump removal activities. Revision 1 of this document deletes hazardous conditions no longer applicable to the current waste transfer design and incorporates hazardous conditions related to the use of an above ground pump pit and overground transfer line. This document is not part of the AB and is not a vehicle for requesting authorization of the activity; it is only intended to provide information about the hazardous conditions associated with this activity. The AB Control Decision process will be used to determine the adequacy of controls and whether the proposed activity is within the AB. This hazard evaluation does not constitute an accident analysis

241-AY/AZ waste storage tanks: Supplemental gravity load analysis. Volume 1

International Nuclear Information System (INIS)

Baliga, R.

1994-01-01

An analysis of the 241SY tanks performed by ADVENT(1994b) to resolve dome overload issues indicated that the tank can sustain the dome loads resulting from additional soil overburden depth, increased soil density, and increased concentrated load. Similar issues exist for the 241AY/AZ tanks and therefore, an interim analysis of the 241AY/AZ tanks is presented herein. The scope of this effort is to review and compare all design drawings pertaining to the 241AY and 241AZ tanks with those pertaining to the 241SY tanks; to modify the axisymmetric model of the 241SY tanks to represent the 241AY/AZ tanks; and to evaluate the effect of additional dome load on the 241AY/AZ tanks by performing a structural analysis for gravity loads (dead load + live load). ADVENTS's additional scope of work is to perform a qualitative evaluation of the 241AY/AZ tanks for seismic and thermal loadings (Vollert 1982 and Blume 1971). This qualitative evaluation does not include any detailed finite element analysis of the tanks. The following design-based gravity loading conditions are used in this interim analysis of the 241AY/AZ tanks to determine a baseline for the tank stresses or section loads

Functions and requirements for single-shell tank leakage mitigation

International Nuclear Information System (INIS)

Cruse, J.M.

1994-01-01

This document provides the initial functions and requirements for the leakage mitigation mission applicable to past and potential future leakage from the Hanford Site's 149 single-shell high-level waste tanks. This mission is a part of the overall mission of the Westinghouse Hanford Company Tank Waste Remediation System division to remediate the tank waste in a safe and acceptable manner. Systems engineering principles are being applied to this effort. A Mission Analysis has been completed, this document reflects the next step in the systems engineering approach to decompose the mission into primary functions and requirements. The functions and requirements in this document apply to mitigative actions to be taken regarding below ground leaks from SST containment boundaries and the resulting soil contamination. Leakage mitigation is invoked in the TWRS Program in three fourth level functions: (1) Store Waste, (2) Retrieve Waste, and (3) Disposition Excess Facilities

An assessment of the dilution required to mitigate Hanford tank 241-SY-101

International Nuclear Information System (INIS)

Hudson, J.D.; Bredt, P.R.; Felmy, A.R.; Stewart, C.W.; Tingey, J.M.; Trent, D.S.; Barney, G.S.; Herting, D.L.; Larrick, A.P.; Reynolds, D.A.

1995-02-01

A group of experts from PNL and WHC convened November 2 and 3, 1994, to screen the current state of knowledge about dilution and reach a consensus on the minimum dilution ratio that will achieve passive mitigation of Tank 241-SY-101 wastes and the dilution ratio that would satisfy the given cross-site transfer criteria with reasonable assurance. The panel evaluated the effects of dilution on the parameters important in gas generation, retention, and release and reached the following conclusions, which are deduced from the existing body of data, experience, and analyses: (1) Dissolution of solids is the single most important aspect of mitigation by dilution. We are confident that diluting until nitrates, nitrites, and aluminum salts are dissolved will mitigate Hanford flammable gas tanks; (2) Sufficient solids dissolution can be achieved in Tank 241-SY-101 at a dilution ratio of 1:1, which will result in a average specific gravity of approximately 1.35. It is likely that a 0.5:1 dilution will also mitigate 241-SY-101, but the current uncertainty is too high to recommend this dilution ratio; (3) The recommended dilution requires a diluent with at least 2 molar free hydroxide, because aluminum probably precipitates at lower hydroxide concentrations. The transfer criteria for Tank 241-SY-101 waste were also evaluated. These criteria have been specified as solids content ≤30% (volume), viscosity ≤30% cP and density <1.5 g/mL. (1) Solids content is the limiting criterion if it is defined as volume fraction of settled solids. A 1:1 dilution will satisfy this criterion at nominal premixing conditions in Tank 241-SY-101; however, analysis of Window E core samples suggests that up to 1.5:1 might be required. If the solids content is interpreted simply as solids volume fraction no further dilution is necessary, because Tank 241-SY-101 waste (excluding the crust) is already below 30%; (2) Bulk density is the next limiting criterion and is met at 0.4:1 dilution

Composition and quantities of retained gas measured in Hanford waste tanks 241-AW-101 A-101, AN-105, AN-104, and AN-103

International Nuclear Information System (INIS)

Shekarriz, A.; Rector, D.R.; Mahoney, L.A.

1997-03-01

This report provides the results obtained for the first five tanks sampled with the Retained Gas Sampler (RGS): Tanks 241-AW-101, A-101, AN-105, AN-104, and AN-103. The RGS is a modified version of the core sampler used at Hanford. It is designed specifically, in concert with the gas extraction equipment in the hot cell, to capture and extrude a gas-containing waste sample in a hermetically sealed system. The retained gases are then extracted and stored in small gas canisters. The composition of the gases contained in the canisters was measured by mass spectroscopy. The total gas volume was obtained from analysis of the extraction process, as discussed in detail throughout this report. The following are the findings of this research: (1) The RGS is a viable approach for measuring retained gases in double- and single-shell waste tanks at Hanford. (2) Local measurements of void fraction with the RGS agree with the results obtained with the void fraction instrument (VFI) in most cases. (3) In the tanks sampled, more than 16% of the retained gas in the nonconvective layer was nitrogen (N 2 ). The fraction of nitrogen gas was approximately 60% in Tank 241-AW-101. This finding shows that not all the retained gas mixtures are flammable. (4) In the tanks sampled, the ratios of hydrogen to oxidizers were observed to be significantly higher than 1; i.e., these tanks are fuel-rich. Based on these observations, the RGS will be used to sample for retained gases in several single-shell tanks at Hanford. The remaining sections of this summary describe the RGS-findings for the first five tanks tested. The results are described in the order in which the tanks were sampled, to reflect the increasing experience on which RGS methods were based

Tank 241-BY-107 vapor sampling and analysis tank characterization report. Revision 1

International Nuclear Information System (INIS)

Huckaby, J.L.

1995-01-01

Tank 241-BY-107 headspace gas and vapor samples were collected and analyzed to help determine the potential risks to tank farm workers due to fugitive emissions from the tank. The drivers and objectives of waste tank headspace sampling and analysis are discussed in open-quotes Program Plan for the Resolution of Tank Vapor Issues.close quotes Tank 241-BY-107 was vapor sampled in accordance with open-quotes Data Quality Objectives for Generic In-Tank Health and Safety Issue Resolution.close quotes

Tank 241-BY-108 vapor sampling and analysis tank characterization report. Revision 1

International Nuclear Information System (INIS)

Huckaby, J.L.

1995-01-01

Tank 241-BY-108 headspace gas and vapor samples were collected and analyzed to help determine the potential risks to tank farm workers due to fugitive emissions from the tank. The drivers and objectives of waste tank headspace sampling and analysis are discussed in ''Program Plan for the Resolution of Tank Vapor Issues'' (Osborne and Huckaby 1994). Tank 241-BY-108 was vapor sampled in accordance with ''Data Quality Objectives for Generic In-Tank Health and Safety Issue Resolution (Osborne et al., 1994)

Tank 241-BY-106 vapor sampling and analysis tank characterization report. Revision 1

International Nuclear Information System (INIS)

Huckaby, J.L.

1995-01-01

Tank 241-BY-106 headspace gas and vapor samples were collected and analyzed to help determine the potential risks to tank farm workers due to fugitive emissions from the tank. The drivers and objectives of waste tank headspace sampling and analysis are discussed in open-quotes Program Plan for the Resolution of Tank Vapor Issues.close quotes Tank 241-BY-106 was vapor sampled in accordance with open-quotes Data Quality Objectives for Generic In-Tank Health and Safety Issue Resolution.close quotes

The potential for buoyant displacement gas release events in Tank 241-SY-102 after waste transfer from Tank 241-SY-101

International Nuclear Information System (INIS)

Wells, BE; Meyer, P.E.; Chen, G.

2000-01-01

Tank 241-SY-101 (SY-101) is a double-shell, radioactive waste storage tank with waste that, before the recent transfer and water back-dilution operations, was capable of retaining gas and producing buoyant displacement (BD) gas release events (GREs). Some BD GREs caused gas concentrations in the tank headspace to exceed the lower flammability limit (LFL). A BD GRE occurs when a portion of the nonconvective layer retains enough gas to become buoyant, rises to the waste surface, breaks up, and releases some of its stored gas. The installation of a mixer pump in 1993 successfully mitigated gas retention in the settled solids layer in SY-101 and has since prevented BD GREs. However, operation of the mixer pump over the years caused gas retention in the floating crust layer and a corresponding accelerated waste level growth. The accelerating crust growth trend observed in 1997--98 led to initiation of sequences of waste removal and water back-dilutions in December 1999. Waste is removed from the mixed slurry layer in Tank SY-101 and transferred into Tank 241-Sy-102 (SY-102). Water is then added back to dissolve soluble solids that retain gas. The initial transfer of 89,500 gallons of SY-101 waste, diluted in-line at 0.94:1 by volume with water, to SY-102 was conducted in December 1999. The second transfer of 230,000 gallons of original SY-101 waste, diluted approximately 0.9:1, was completed in January 2000, and the third transfer of 205,500 gallons of original SY-101 waste diluted at 0.9:1 was completed in March 2000

CESIUM REMOVAL FROM TANKS 241-AN-103 & 241-SX-105 & 241-AZ-101 & 241AZ-102 COMPOSITE FOR TESTING IN BENCH SCALE STEAM REFORMER

Energy Technology Data Exchange (ETDEWEB)

DUNCAN JB; HUBER HJ

2011-04-21

This report documents the preparation of three actual Hanford tank waste samples for shipment to the Savannah River National Laboratory (SRNL). Two of the samples were dissolved saltcakes from tank 241-AN-103 (hereafter AN-103) and tank 241-SX-105 (hereafter SX-105); one sample was a supernate composite from tanks 241-AZ-101 and 241-AZ-102 (hereafter AZ-101/102). The preparation of the samples was executed following the test plans LAB-PLAN-10-00006, Test Plan for the Preparation of Samples from Hanford Tanks 241-SX-105, 241-AN-103, 241-AN-107, and LAB-PLN-l0-00014, Test Plan for the Preparation of a Composite Sample from Hanford Tanks 241-AZ-101 and 241-AZ-102 for Steam Reformer Testing at the Savannah River National Laboratory. All procedural steps were recorded in laboratory notebook HNF-N-274 3. Sample breakdown diagrams for AN-103 and SX-105 are presented in Appendix A. The tank samples were prepared in support of a series of treatability studies of the Fluidized Bed Steam Reforming (FBSR) process using a Bench-Scale Reformer (BSR) at SRNL. Tests with simulants have shown that the FBSR mineralized waste form is comparable to low-activity waste glass with respect to environmental durability (WSRC-STI-2008-00268, Mineralization of Radioactive Wastes by Fluidized Bed Steam Reforming (FBSR): Comparisons to Vitreous Waste Forms and Pertinent Durability Testing). However, a rigorous assessment requires long-term performance data from FBSR product formed from actual Hanford tank waste. Washington River Protection Solutions, LLC (WRPS) has initiated a Waste Form Qualification Program (WP-5.2.1-2010-001, Fluidized Bed Steam Reformer Low-level Waste Form Qualification) to gather the data required to demonstrate that an adequate FBSR mineralized waste form can be produced. The documentation of the selection process of the three tank samples has been separately reported in RPP-48824, Sample Selection Process for Bench-Scale Steam Reforming Treatability Studies Using

Radioactive air emissions notice of construction for installation and operation of a waste retrieval system and tanks 241-AP-102 and 241-AP-104 project

Energy Technology Data Exchange (ETDEWEB)

DEXTER, M.L.

1999-11-15

This document serves as a notice of construction (NOC) pursuant to the requirements of Washington Administrative Code (WAC) 246 247-060, and as a request for approval to modify pursuant to 40 Code of Federal Regulations (CFR) 61 07 for the installation and operation of one waste retrieval system in the 24 1 AP-102 Tank and one waste retrieval system in the 241 AP 104 Tank Pursuant to 40 CFR 61 09 (a)( 1) this application is also intended to provide anticipated initial start up notification Its is requested that EPA approval of this application will also constitute EPA acceptance of the initial start up notification Project W 211 Initial Tank Retrieval Systems (ITRS) is scoped to install a waste retrieval system in the following double-shell tanks 241-AP 102-AP 104 AN 102, AN 103, AN-104, AN 105, AY 102 AZ 102 and SY-102 between now and the year 2011. Because of the extended installation schedules and unknowns about specific activities/designs at each tank, it was decided to submit NOCs as that information became available This NOC covers the installation and operation of a waste retrieval system in tanks 241 AP-102 and 241 AP 104 Generally this includes removal of existing equipment installation of new equipment and construction of new ancillary equipment and buildings Tanks 241 AP 102 and 241 AP 104 will provide waste feed for immobilization into a low activity waste (LAW) product (i.e. glass logs) The total effective dose equivalent (TEDE) to the offsite maximally exposed individual (MEI) from the construction activities is 0 045 millirem per year The unabated TEDE to the offsite ME1 from operation of the mixer pumps is 0 042 millirem per year.

Radioactive air emissions notice of construction for installation and operation of a waste retrieval system and tanks 241-AP-102 and 241-AP-104 project

International Nuclear Information System (INIS)

DEXTER, M.L.

1999-01-01

This document serves as a notice of construction (NOC) pursuant to the requirements of Washington Administrative Code (WAC) 246 247-060, and as a request for approval to modify pursuant to 40 Code of Federal Regulations (CFR) 61 07 for the installation and operation of one waste retrieval system in the 24 1 AP-102 Tank and one waste retrieval system in the 241 AP 104 Tank Pursuant to 40 CFR 61 09 (a)( 1) this application is also intended to provide anticipated initial start up notification Its is requested that EPA approval of this application will also constitute EPA acceptance of the initial start up notification Project W 211 Initial Tank Retrieval Systems (ITRS) is scoped to install a waste retrieval system in the following double-shell tanks 241-AP 102-AP 104 AN 102, AN 103, AN-104, AN 105, AY 102 AZ 102 and SY-102 between now and the year 2011. Because of the extended installation schedules and unknowns about specific activities/designs at each tank, it was decided to submit NOCs as that information became available This NOC covers the installation and operation of a waste retrieval system in tanks 241 AP-102 and 241 AP 104 Generally this includes removal of existing equipment installation of new equipment and construction of new ancillary equipment and buildings Tanks 241 AP 102 and 241 AP 104 will provide waste feed for immobilization into a low activity waste (LAW) product (i.e. glass logs) The total effective dose equivalent (TEDE) to the offsite maximally exposed individual (MEI) from the construction activities is 0 045 millirem per year The unabated TEDE to the offsite ME1 from operation of the mixer pumps is 0 042 millirem per year

Regulatory issues associated with closure of the Hanford AX Tank Farm ancillary equipment

International Nuclear Information System (INIS)

Becker, D.L.

1998-01-01

Liquid mixed, high-level radioactive waste has been stored in underground single-shell tanks at the US Department of Energy's (DOE's) Hanford Site. After retrieval of the waste from the single-shell tanks, the DOE will proceed with closure of the tank farm. The 241-AX Tank Farm includes four one-million gallon single-shell tanks in addition to sluice lines, transfer lines, ventilation headers, risers, pits, cribs, catch tanks, buildings, well and associated buried piping. This equipment is classified as ancillary equipment. This document addresses the requirements for regulatory close of the ancillary equipment in the Hanford Site 241-AX Tank Farm. The options identified for physical closure of the ancillary equipment include disposal in place, disposal in place after treatment, excavation and disposal on site in an empty single-shell tank, and excavation and disposal outside the AX Tank Farm. The document addresses the background of the Hanford Site and ancillary equipment in the AX Tank Farm, regulations for decontamination and decommissioning of radioactively contaminated equipment, requirements for the cleanup and disposal of radioactive wastes, cleanup and disposal requirements governing hazardous and mixed waste, and regulatory requirements and issues associated with each of the four physical closure options. This investigation was conducted by the Sandia National Laboratories, Albuquerque, New Mexico, during Fiscal Year 1998 for the Hanford Tanks Initiative Project

Tank 241-C-101 vapor sampling and analysis tank characterization report

International Nuclear Information System (INIS)

Huckaby, J.L.

1995-01-01

Tank C-101 headspace gas and vapor samples were collected and analyzed to help determine the potential risks of fugitive emissions to tank farm workers. Gas and vapor samples from the Tank C-101 headspace were collected on July 7, 1994 using the in situ sampling (ISS) method, and again on September 1, 1994 using the more robust vapor sampling system (VSS). Gas and vapor concentrations in Tank C-101 are influenced by its connections to other tanks and its ventilation pathways. At issue is whether the organic vapors in Tank C-101 are from the waste in that tank, or from Tanks C-102 or C-103. Tank C-103 is on the Organic Watch List; the other two are not. Air from the Tank C-101 headspace was withdrawn via a 7.9-m long heated sampling probe mounted in riser 8, and transferred via heated tubing to the VSS sampling manifold. The tank headspace temperature was determined to be 34.0 C, and all heated zones of the VSS were maintained at approximately 50 C. Sampling media were prepared and analyzed by WHC, Oak Ridge National Laboratories, Pacific Northwest Laboratories, and Oregon Graduate Institute of Science and Technology through a contract with Sandia National Laboratories. The 39 tank air samples and 2 ambient air control samples collected are listed in Table X-1 by analytical laboratory. Table X-1 also lists the 14 trip blanks and 2 field blanks provided by the laboratories

Toxic chemical considerations for tank farm releases

Energy Technology Data Exchange (ETDEWEB)

Van Keuren, J.C.; Davis, J.S., Westinghouse Hanford

1996-08-01

This topical report contains technical information used to determine the accident consequences of releases of toxic chemical and gases for the Tank Farm Final Safety Analysis report (FSAR).It does not provide results for specific accident scenarios but does provide information for use in those calculations including chemicals to be considered, chemical concentrations, chemical limits and a method of summing the fractional contributions of each chemical. Tank farm composites evaluated were liquids and solids for double shell tanks, single shell tanks, all solids,all liquids, headspace gases, and 241-C-106 solids. Emergency response planning guidelines (ERPGs) were used as the limits.Where ERPGs were not available for the chemicals of interest, surrogate ERPGs were developed. Revision 2 includes updated sample data, an executive summary, and some editorial revisions.

Overview Of Hanford Single Shell Tank (SST) Structural Integrity - 12123

International Nuclear Information System (INIS)

Rast, R.S.; Rinker, M.W.; Washenfelder, D.J.; Johnson, J.B.

2012-01-01

To improve the understanding of the single-shell tanks (SSTs) integrity, Washington River Protection Solutions, LLC (WRPS), the USDOE Hanford Site tank contractor, developed an enhanced Single-Shell Tank Integrity Project in 2009. An expert panel on SST integrity, consisting of various subject matters experts in industry and academia, was created to provide recommendations supporting the development of the project. This panel developed 33 recommendations in four main areas of interest: structural integrity, liner degradation, leak integrity and prevention, and mitigation of contamination migration. Seventeen of these recommendations were used to develop the basis for the M-45-10-1 Change Package for the Hanford Federal Agreement and Compliance Order, which is also known as the Tri-Party Agreement. The structural integrity of the tanks is a key element in completing the cleanup mission at the Hanford Site. There are eight primary recommendations related to the structural integrity of Hanford SSTs. Six recommendations are being implemented through current and planned activities. The structural integrity of the Hanford SSTs is being evaluated through analysis, monitoring, inspection, materials testing, and construction document review. Structural evaluation in the form of analysis is performed using modern finite element models generated in ANSYS(reg s ign) The analyses consider in-situ, thermal, operating loads and natural phenomena such as earthquakes. Structural analysis of 108 of 149 Hanford SSTs has concluded that the tanks are structurally sound and meet current industry standards. Analyses of the remaining Hanford SSTs are scheduled for FY2013. Hanford SSTs are monitored through a dome deflection program. The program looks for deflections of the tank dome greater than 1/4 inch. No such deflections have been recorded. The tanks are also subjected to visual inspection. Digital cameras record the interior surface of the concrete tank domes, looking for cracks and

OVERVIEW OF HANFORD SINGLE SHELL TANK (SST) STRUCTURAL INTEGRITY - 12123

Energy Technology Data Exchange (ETDEWEB)

RAST RS; RINKER MW; WASHENFELDER DJ; JOHNSON JB

2012-01-25

To improve the understanding of the single-shell tanks (SSTs) integrity, Washington River Protection Solutions, LLC (WRPS), the USDOE Hanford Site tank contractor, developed an enhanced Single-Shell Tank Integrity Project in 2009. An expert panel on SST integrity, consisting of various subject matters experts in industry and academia, was created to provide recommendations supporting the development of the project. This panel developed 33 recommendations in four main areas of interest: structural integrity, liner degradation, leak integrity and prevention, and mitigation of contamination migration. Seventeen of these recommendations were used to develop the basis for the M-45-10-1 Change Package for the Hanford Federal Agreement and Compliance Order, which is also known as the Tri-Party Agreement. The structural integrity of the tanks is a key element in completing the cleanup mission at the Hanford Site. There are eight primary recommendations related to the structural integrity of Hanford SSTs. Six recommendations are being implemented through current and planned activities. The structural integrity of the Hanford SSTs is being evaluated through analysis, monitoring, inspection, materials testing, and construction document review. Structural evaluation in the form of analysis is performed using modern finite element models generated in ANSYS{reg_sign} The analyses consider in-situ, thermal, operating loads and natural phenomena such as earthquakes. Structural analysis of 108 of 149 Hanford SSTs has concluded that the tanks are structurally sound and meet current industry standards. Analyses of the remaining Hanford SSTs are scheduled for FY2013. Hanford SSTs are monitored through a dome deflection program. The program looks for deflections of the tank dome greater than 1/4 inch. No such deflections have been recorded. The tanks are also subjected to visual inspection. Digital cameras record the interior surface of the concrete tank domes, looking for cracks and

Physical and Liquid Chemical Simulant Formulations for Transuranic Waste in Hanford Single-Shell Tanks

International Nuclear Information System (INIS)

Rassat, Scot D.; Bagaasen, Larry M.; Mahoney, Lenna A.; Russell, Renee L.; Caldwell, Dustin D.; Mendoza, Donaldo P.

2003-01-01

CH2M HILL Hanford Group, Inc. (CH2M HILL) is in the process of identifying and developing supplemental process technologies to accelerate the tank waste cleanup mission. A range of technologies is being evaluated to allow disposal of Hanford waste types, including transuranic (TRU) process wastes. Ten Hanford single-shell tanks (SSTs) have been identified whose contents may meet the criteria for designation as TRU waste: the B-200 series (241-B-201, -B-202, -B 203, and B 204), the T-200 series (241-T-201, T 202, -T-203, and -T-204), and Tanks 241-T-110 and -T-111. CH2M HILL has requested vendor proposals to develop a system to transfer and package the contact-handled TRU (CH-TRU) waste retrieved from the SSTs for subsequent disposal at the Waste Isolation Pilot Plant (WIPP). Current plans call for a modified ''dry'' retrieval process in which a liquid stream is used to help mobilize the waste for retrieval and transfer through lines and vessels. This retrieval approach requires that a significant portion of the liquid be removed from the mobilized waste sludge in a ''dewatering'' process such as centrifugation prior to transferring to waste packages in a form suitable for acceptance at WIPP. In support of CH2M HILL's effort to procure a TRU waste handling and packaging process, Pacific Northwest National Laboratory (PNNL) developed waste simulant formulations to be used in evaluating the vendor's system. For the SST CH-TRU wastes, the suite of simulants includes (1) nonradioactive chemical simulants of the liquid fraction of the waste, (2) physical simulants that reproduce the important dewatering properties of the waste, and (3) physical simulants that can be used to mimic important rheological properties of the waste at different points in the TRU waste handling and packaging process. To validate the simulant formulations, their measured properties were compared with the limited data for actual TRU waste samples. PNNL developed the final simulant formulations

Waste behavior analysis for tank 241-SY-103

International Nuclear Information System (INIS)

Wilkins, N.E.

1994-01-01

Tank 241-SY-103 is on the Flammable Gas Watch List. The waste in this tank behaves similarly to that in tank 241-Sy-101. Both show slurry growth and periodic surface level drops. However, the surface level drops are much smaller than those in tank 101-SY. A standard hydrogen monitoring system (SHMS) was recently installed in tank 103-SY, and waste auger samples were recently taken. This document covers the characterization results to date for the auger samples, and the behavior of the tank waste during both steady state periods and gas release events

Tank 241-A-104 tank characterization plan

International Nuclear Information System (INIS)

Schreiber, R.D.

1994-01-01

This document is a plan which serves as the contractual agreement between the Characterization Program, Sampling Operations, WHC 222-S Laboratory, and PNL 325 Analytical Chemistry Laboratory. The scope of this plan is to provide guidance for the sampling and analysis of auger samples from tank 241-A-104. This Tank Characterization Plan will identify characterization objectives pertaining to sample collection, hot cell sample isolation, and laboratory analytical evaluation and reporting requirements in addition to reporting the current contents and status of the tank as projected from historical information

Engineering evaluation of intrusion prevention strategies for single-shell tanks

International Nuclear Information System (INIS)

Jenkins, C.E.

1994-01-01

In this study, previously implemented actions to prevent liquid intrusion into out-of-service single-shell tanks (SSTs), i.e., interim isolation or partial interim isolation, are investigated and expanded to identify additional cost-effective intrusion prevention techniques that could be reasonably taken until SSTs are ready for waste retrieval. Possible precipitation, groundwater, and condensation pathways and internal tank connections that could provide possible pathways for liquids are examined. Techniques to block identified potential pathways are developed and costed to determine the potential benefit to costed trade-offs for implementing the techniques. (Note: Surveillance data show increased waste surface levels for several SSTs that indicate possible liquid intrusion despite interim isolation activities.)

Organic carbon in Hanford single-shell tank waste

International Nuclear Information System (INIS)

Toth, J.J.; Willingham, C.E.; Heasler, P.G.; Whitney, P.D.

1994-07-01

This report documents an analysis performed by Pacific Northwest Laboratory (PNL) involving the organic carbon laboratory measurement data for Hanford single-shell tanks (SSTS) obtained from a review of the laboratory analytical data. This activity was undertaken at the request of Westinghouse Hanford Company (WHC). The objective of this study is to provide a best estimate, including confidence levels, of total organic carbon (TOC) in each of the 149 SSTs at Hanford. The TOC analyte information presented in this report is useful as part of the criteria to identify SSTs for additional measurements or monitoring for the organic safety program. This report is a precursor to an investigation of TOC and moisture in Hanford SSTS, in order to provide best estimates for each together in one report. Measured laboratory data were obtained for 75 of the 149 SSTS. The data represent a thorough investigation of data from 224 tank characterization datasets, including core-sampling and process laboratory data. Liquid and solid phase TOC values were investigated by examining selected tanks with both reported TOC values in solid and liquid phases. Some relationships were noted, but there was no clustering of data or significance between the solid and liquid phases. A methodology was developed for estimating the distribution and levels of TOC in SSTs using a logarithmic scale and an analysis of variance (ANOVA) technique. The methodology grouped tanks according to waste type using the Sort On Radioactive Waste Type (SORWT) grouping method. The SORWT model categorizes Hanford SSTs into groups of tanks expected to exhibit similar characteristics based on major waste types and processing histories. The methodology makes use of laboratory data for the particular tank and information about the SORWT group of which the tank is a member. Recommendations for a simpler tank grouping strategy based on organic transfer records were made

Hanford Site Tank 241-C-108 Residual Waste Contaminant Release Models and Supporting Data

Energy Technology Data Exchange (ETDEWEB)

Cantrell, Kirk J.; Krupka, Kenneth M.; Geiszler, Keith N.; Arey, Bruce W.; Schaef, Herbert T.

2010-06-18

This report presents the results of laboratory characterization, testing, and analysis for a composite sample (designated 20578) of residual waste collected from single-shell tank C-108 during the waste retrieval process after modified sluicing. These studies were completed to characterize concentration and form of contaminant of interest in the residual waste; assess the leachability of contaminants from the solids; and develop release models for contaminants of interest. Because modified sluicing did not achieve 99% removal of the waste, it is expected that additional retrieval processing will take place. As a result, the sample analyzed here is not expected to represent final retrieval sample.

Decision Document for the Low Activity Waste Retrieval Strategy for Tanks 241-AN-103 and 241-AN-104 and 241-AN-105 and 241-AW-101

International Nuclear Information System (INIS)

RASMUSSEN, O.R.

2000-01-01

This report documents the preferred approach (retrieval strategy) to prepare and transfer waste from low-activity waste source tanks containing soluble solids (Tanks 241-AN-103, 241-AN-104, 241-AN-105 and 241-AW-101) to the vitrification plant. Several opportunities to further refine the selected retrieval strategy were identified; these were recommended for follow-on studies

Tank 241-Z-361 process and characterization history

International Nuclear Information System (INIS)

Jones, S.A.

1997-01-01

This document is a summary of the history of Tank 241-Z-361 through December 1997. Documents reviewed include engineering files, laboratory notebooks from characterization efforts, waste facility process procedures, supporting documents and interviews of people's recollections of 20 plus years ago. Records of transfers into the tank, past characterization efforts, and speculation will be used to estimate the current condition of Tank 241-Z-361 and its contents

Status of tank 241-SY-101 data analyses

International Nuclear Information System (INIS)

Anantatmula, R.P.

1992-09-01

The Waste Tank Flammable Gas Stabilization Program was established in 1990 to provide for resolution of a major safety issue identified for 23 of the high-level waste tanks at the Hanford Site. The safety issue involves the production, accumulation, and periodic release from these tanks of flammable gases in concentrations exceeding the lower flammability limits. This document deals primarily with tank 241-SY-101 from the SY Tank Farm. The flammable gas condition has existed for this tank since the tank was first filled in the time period from 1977 to 1980. During a general review of waste tank chemical stability in 1988--1989, this situation was re-examined and, in March 1990, the condition was declared to be an unreviewed safety question. Tank 241-SY-101 was placed under special operating restrictions, and a program of investigation was begun to evaluate the condition and determine appropriate courses of action. This report summarizes the data that have become available on tank 241-SY-101 since it was declared as an unreviewed safety question and updates the information reported in an earlier document (WHC-EP-0517). The report provides a technical basis for use in the evaluation of safety risks of the tank and subsequent resolution of the unreviewed safety question