WorldWideScience

Sample records for shisetsuyo koseinoka zairyo

  1. Fiscal 1997 project on the R and D of industrial scientific technology under consignment from NEDO. Report on the results of the R and D of technologies to invent original high-functional materials (technical development of materials to heighten efficiency of power generation facilities); 1997 nendo sangyo kagaku gijutsu kenkyu kaihatsu jigyo Shin Energy Sangyo Gijutsu Sogo Kaihatsu Kiko itaku. Dokusoteki kokino zairyo sosei gijutsu no kenkyu kaihatsu (hatsuden shisetsuyo koseinoka zairyo gijutsu kaihatsu) seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    The paper described the fiscal 1997 results of the study of the condensation base precise structure control conducted as a technical development of materials to heighten efficiency of power generation facilities. Condensation base polymer is an important material which occupies most of the engineering plastics. The study is aimed at developing basic technologies on the molecular weight and regularity by which a remarkable improvement can be expected in performance of condensation polymerization/ring-opening polymerization polymer materials, polymerization catalyst which arbitarily controls the primary structure such as branch and end group structures, and development of the precision polymerization process. In the synthesis of ordered polymer by direct polycondensation, synthesis of ordered polyamide from asymmetric monomers is studied. In the synthesis of chemically selective polyamide by direct polymerization, polyamide with functional group is synthesized by polymerizing without protecting functional group the monomer with such functional group as causes side reaction in polymerization. In the synthesis of polyamide having the limited distribution of molecular weight, the molecular weight/distribution of polyamide are controlled by connectedly conducting polycondensation which is itself to be done successively. 91 refs., 72 figs., 43 tabs.

  2. FY 1998 annual report on the study on development of corrosion-resistant ceramic materials for garbage incinerators; 1998 nendo gomi shori shisetsuyo taishoku ceramics zairyo no kaihatsu ni kansuru kenkyu chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Described herein are the FY 1988 results of development of corrosion-resistant ceramic materials for garbage incinerators. Residue released when porcelain stocks are collected is selected as the inexpensive stock for SiO{sub 2}-Al{sub 2}O{sub 3}-based refractory materials. It is incorporated with carbon black and reduced at 1,200 to 1,500 degrees C in a nitrogen atmosphere. Synthesis of the target Si-Al-C-N-O-based compound succeeds in the presence of a solid catalyst, but it is a fine powder, and hence that of the massive compound fails. The commercial ceramic materials and new refractory materials, made on a trial basis, are evaluated for their resistance to corrosion using fry ashes collected from a commercial incinerator. These ashes are higher in melting point, more viscous, holding a larger quantity of attached slag and more corrosive than synthetic ashes. These materials are corroded acceleratedly as temperature increases to 1,200 degrees C or higher, more noted with the ceramic materials than with the refractory materials. Oxidation and melting characteristics of the molten slag affect corrosion of some materials. Use of the graphite-based material shall be limited to a section below the slag surface, where graphite is oxidized to a smaller extent. The MgO-based material is promising. The Al{sub 2}O{sub 3}-Cr{sub 2}O{sub 3}-based material is more promising than any other material developed in this study. Their bending strength before and after the corrosion test is measured at normal temperature to 1,700 degrees C, to investigate their deterioration by high temperature and corrosion. (NEDO)

  3. Improved design of three-dimensional lens for low concentrator PV modules; Teishukogata taiyo denchiyo sanjigen lens no koseinoka ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Goma, S.; Yoshioka, K.; Saito, T. [Tokyo Univ. of Agriculture and Technology, Tokyo (Japan)

    1997-11-25

    Attention is paid to reduction in area required for solar cells by solar concentration as a means of solving cost limits of solar cells and unstable supply of Si materials. Low concentration solar cells are effective from the aspects of utilization of scattered light and unnecessary ray tracing. The optical concentration ratio was calculated of three-dimensional lens having design values of various north/south and east/west direction allowable incidence half angles. The three-dimensional lens are designed by cutting a rectangular parallelepiped by the two-dimensional composite elliptical plane designed by various allowable incidence half angles from two directions of north/south and east/west. Using Perez`s sky solar radiation models and meteorological data HASP, calculated were the annual accumulated global radiation ratio on an inclined surface and the optical efficiency. Calculated were the solar cell area ratio and solar concentration area ratio of the concentration type to obtain solar radiation the same as that of the planar type. From the optimization calculation, it was found that lens are optimal which have design values of north/south and east/west direction allowable incidence half angles of 30-70deg. The solar cell area ratio is 57% and the solar concentration area ratio is 1.2 times. It was found that by making the module area 1.2 times, more than 40% of the solar cells used can be saved. 5 refs., 8 figs.

  4. Development of new catalytic materials; Shinshokubai zairyo no kaihatsu doko

    Energy Technology Data Exchange (ETDEWEB)

    Tatsumi, Takashi [Yokohama National Univ., Kanagawa (Japan)

    1999-04-05

    The catalyst fulfils large role for the solution of environmental problem, resources problem, and energy problem. It is popular to carry out the research, which intends to realize the new process of which the environmental loading is low by the new catalyst. And, the development of catalyst material, which demonstrates the function under the ultimate condition like the environmental catalyst, is required. The interest has leaned in also using the solid catalyst for the synthesis of fine chemical such as intermediate and perfume of the medical supply synthesis. In this paper, the following are described as a new catalyst material: Zeolite and development trend of meso porous molecular sieve explosively studied recently. The application to the reaction is also simply touched. (NEDO)

  5. Window glasses for amenity life. Jukankyo ni yasashii garasu zairyo

    Energy Technology Data Exchange (ETDEWEB)

    Nakashima, H.; Morimoto, S. (Central Glass Co. Ltd., Tokyo (Japan). Technical Center)

    1993-04-01

    In regard to the glass materials kindly to environment or kindly to mankind, specially glasses for construction and flat glasses for cars, various types of functional glasses have been developed. The functions of these glasses are introciuced. Glasses with optical functions are introduced as following; highly functional colored glass, heat reflection glass which can decrease the cooler load in summer by reflecting the solar energy together with the creation of comfortable room atmosphere, optical glass which can make comfortable room atmosphere by adjusting the transmitted amount of light and heat, electrochromic glass (EC glass) which can freely control the transmission rate by changing the direction of the current. Besides, thermal insulation multilayer glass having thermal function, highly efficient insulation multilayered glass, sound proof glass with noise function and sound proof/insulation glass are introduced. Shielding glass with electromagnetic function, antistatic glass, and multiple strength glass having mechanical function, used for outer part of building are also described. 10 refs., 10 figs., 2 tabs.

  6. Database on organic composite materials for cryogenic use. Goku teion prime yo yuki fukugo zairyo (yuki zairyo) no database

    Energy Technology Data Exchange (ETDEWEB)

    Nishijima, S.; Okada, T. (Osaka Univ., Osaka (Japan). Institute of Scientific and Industrial Research)

    1990-10-25

    A description is given of a database (DB) on organic composite materials for cryogenic use, which has been set up at the Institute of Scientific and Industrial Research of Osaka University. Principal features of the DB are noted as follows: first, the DB holds only those data on physical properties of the materials that have been obtained by using the measuring apparatuses which the institute is provided with so that they should be free from limitations of qualities arising from the use of different kinds of measuring methods; second, the name of supplier and the trade name of each material are included in its data as subsidary information as to the material so that users of the DB can easily obtain it in case of need. Connected with the usage of the DB, there is a description of the arrangement of directories in the DB, meanings of some abbreviations and kinds of contents which each data file should hold. It is noted that the DB will be supplied in the form of a floppy disk in which the data are recorded with the aid of the software on the market. 3 refs., 6 figs., 4 tabs.

  7. Seismic resistant repair and reinforcement materials; Shiyo zairyo ni miru taishin hokyo to hoshu gijutsu

    Energy Technology Data Exchange (ETDEWEB)

    Sakai, E.; Daimon, M. [Tokyo Industral Univ. (Japan)

    1997-08-10

    Seismic resistant repair and reinforcement materials are outlined with emphasis on relation between main components and characteristics of cements, polymers and composite materials referring to recent domestic reports and guidelines. First, types and required performance of polymer and specialized cementitious repair and reinforcement materials are summarized. Among the polymer repair and reinforcement materials, grouting materials for cracks, adhesives and carbon fiber FRP are taken up, and the following items are specifically explained; use of injection property and adhesiveness; use of reinforcement effect. On the cementitious repair and reinforcement materials, the following items are explained; use of rapid adhesion and rapid hardening; use of injection and filling properties; use of low contraction; use of adhesion; use of densification and chemical resistance. Finally, the following future problems are shown; new material development based on the user demand on existing materials; performance improvement of cementitious composite materials as durable materials; warranty of construction and quality. 25 refs., 5 figs., 8 tabs.

  8. Investigation research on autonomous responsive materials; Jiritsu oto zairyo ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    A survey was made on autonomous responsive materials as a new material which reversibly change molecular structures and the aggregation state according to external stimuli. Autonomous responsive materials imitate environmental responsibility in the living organism system and have sensing, control and active functions for external stimuli. The materials are highly efficient and environmentally friendly. In biomimetic materials for soft actuators, drastic changes by temperature of elastic modulus of water-swollen hydrogel are used to the motion. In order to molecularly design stimulus-responsible polymer gel, studied are the relation between the micro structure and stimulus responsibility, dynamic correlation between the micro structure and the macro structure, etc. In the biomedical field, new cure and diagnosis using innovative materials are expected, and the application of autonomous responsive materials to the field is studied. For example, using hydrogel responding the temperature and the surface and controlling by temperature the interaction with components of the organism such as protein and cells, drug delivery in the organism is optimized. Also studied is the application of hydrophilic/hydrophobic changes by temperature to the chromatography. 215 refs., 47 figs., 11 tabs.

  9. Investigational research on the design of computational materials; Keisanki zairyo sekkei no chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    Computer chemistry was investigationally studied. The advance of theoretical chemistry is indispensable to the design of materials, and the theory and high speed computational method are expected which can simulate the real system with more accuracy. It is basic to simulate structures and physical properties of structural molecules and the aggregate, but the meso region, the intermedium region between structural molecules and the aggregate, has became regarded as important. Rough visualization models in high polymer materials and the progress of computational software/hardware of quantum chemistry/molecular dynamics such as catalyst become necessary. Seamless zooming is proposed as a concept of the software which simulates materials from micro/macro/meso viewpoints. Moreover, to make the most of computer chemistry, an integrated system is necessary which generally handles computational software, database, etc. For the development of software, indispensable is the demonstrative verification by a combination of experiments and researchers. Under a commission from NEDO, the investigational research was conducted as a leading study during fiscal 1996 and 1997 to view the course of the research. 17 refs., 37 figs., 5 tabs.

  10. Research study on harmonized molecular materials (HMM); Bunshi kyocho zairyo ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    As functional material to satisfy various needs for environmental harmonization and efficient conversion for information-oriented and aging societies, HMM were surveyed. Living bodies effectively carry out transmission/processing of information, and transport/conversion of substances, and these functions are based on harmonization between organic molecules, and between those and metal or inorganic ones. HMM is a key substance to artificially realize these bio-related functions. Its R & D aims at (1) Making a breakthrough in production process based on innovation of material separation/conversion technology, (2) Contribution to an information-oriented society by high-efficiency devices, and (3) Growth of a functional bio-material industry. HMM is classified into three categories: (1) Assembly materials such as organic ultra-thin films (LB film, self-organizing film), and organic/inorganic hybrid materials for optoelectronics, sensors and devices, (2) Mesophase materials such as functional separation membrane and photo-conductive material, and (3) Microporous materials such as synthetic catalyst using guest/host materials. 571 refs., 88 figs., 21 tabs.

  11. Research study on highly functional carbon related materials; Tansokei kokino zairyo no chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    The study results on highly functional carbon related materials are reported as a part of the leading research in fiscal 1996. Synthesis of these novel materials is outlined, and R & D results on the following materials are described: diamond, hetero-diamond, graphite, amorphous carbon, carbyne, fullerences, carbon nitride and chemically modified carbon materials. Their issues, future possibility and market in 2010 are also described. The markets are predicted of such electronic materials as electronic emitter, sensor, solid device and heat sink, such optical materials as X-ray lithography, and such chemical materials as electrode and catalyst. Promising characteristics of light-weight and high-hardness machine materials are presented, and some issues such as material synthesis, and intensive machining and application technologies are described. The future markets are predicted of their applications to tools, dies, information equipment, glass, automobiles, aircraft, spacecraft and industrial machines. Problems and their break through techniques of these novel materials are also presented. 220 refs., 68 figs., 16 tabs.

  12. Research on harmonized molecular materials; Bunshi kyocho zairyo ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    Harmonized molecular materials (HMM) were researched to create functional materials adaptable to needs such as environmental harmony and high-efficient conversion in post-industrial society and aging society. Superior mechanisms function efficiently in organisms for perception, transmission and processing of information, and transport and conversion of substances. These functions are caused by harmonization between organic molecules, or organic molecule and metal or inorganic substance. HMM is a key substance to realize these functions similar to those of organisms artificially. It is the purpose of this research to develop HMMs, reform production process by innovating separation and conversion technologies, and finally realize molecular chemical plants. This research also develops high-efficient devices to contribute to the information society, and progresses the industry of bio-functional materials such as high-sensitive bio-sensor. The functions, applications and creation technologies of three kinds of HMM such as assembly, mesophase and microporous materials were researched in fiscal 1995. 956 refs., 128 figs., 13 tabs.

  13. Manufacturing and properties of inorganic porous materials. Mukishitsu tako zairyo no seizo to seishitsu

    Energy Technology Data Exchange (ETDEWEB)

    Daimon, M.; Okada, K. (Tokyo Inst. of Technology, Tokyo (Japan). Faculty of Engineering)

    1992-09-01

    As for the manufacturing of the inorganic porous materials, synthesis of the materials like zeolyte which have pores with crystal structure, gel formation that have included the formation of gel by neutralizing inorganic aqueous solution and the hydrolysis of metallic alkoxide, formation of gel in cement concrete, porous glass from phase decomposition, sintered porous material, and the formation methods of honeycom and fibers, are described. In general their properties are divided into four types such as solid property, surface property, solid-gas composite property and the property of pore. Inorganic porous materials are used as filter material or composite materials having single component gas phase which have properties like thermal insulation, soundproof and control of electric resistance. They are also used in all important chemical processes like separation, purification and concentration. Chemical activity in the surface has been important, and the function of the catalyst is decided by the surface properties. The change in the properties of the material by increasing and fixing effective surface area of the supportive materials is explained. 27 refs., 11 figs.,1 tab.

  14. Palletizing system of packets containing confectionery materials; Kashi zairyo backet paretaizu system

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-02-29

    A palletizing system of packets containing confectionery materials was manufactured and delivered (Figure 11). The three-step loaded packets on which the confectionery materials carried out from the preceding process were put are positioned on the tip conveyor. These packets are then sequentially taken out from the upper packet and transferred to an empty pallet. The step-loaded packets are easy to shift from the position, so a special hand that allows the position shift was applied. For the step loading of packets, the special relief mechanism and push-in operation of a hook are used so that the clearance between packets does not occur. The packet dimensions are about 500 x 350 x 380 mm (W/H/D). The maximum weight is about 30 kg. A pallet is made of resin. Five packets in five steps are loaded on one pallet. The main configuration of this system is as follows: (1) Palletizer (VPR-800) x 1. (2) Controller (meirocs-G) x 1. (3) Packet catch-only hand x 1. (4) Tip conveyor x 1. (5) Safety fence. (translated by NEDO)

  15. Structural experiment of wind turbine blades; Fushayo blade no zairyo rikigakuteki jikken kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Seki, K.; Shimizu, Y.; Kuroyanagi, H. [Tokai University, Tokyo (Japan)

    1997-11-25

    Aluminum, GFRP and composite of aluminum coated with carbon as structural materials for wind turbine blades were bending-tested, to improve blade bending stiffness, understand stress conditions at each position, and clarify structural dynamic strength by the bending-failure test. It is possible to estimate stress conditions at each position from the test results of displacement and strain at each load. The test results with GFRP are well explained qualitatively by the boundary theory, known as a theory for composite materials. The test gives reasonable material strength data, useful for designing wind turbines of high functions and safety. The results of the blade bending-failure test are in good agreement with the calculated structural blade strength. It is also found that GFRP is a good material of high structural strength for wind turbines. 8 refs., 6 tabs.

  16. Survey and research on precision polymerization polymeric materials; Seimitsu jugo kobunshi zairyo ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    Survey and research on the precision control of primary structure of polymeric materials and the precision evaluation technology have been conducted to develop advanced polymeric materials. It is proposed that the three basic processes of polymer synthesis, i.e., addition, condensation, and biomimesis, in forming the precision polymerization skeleton are to be covered through a centralized joint research effort with participation of industry, academia, and the government institute and under the leadership of researchers from academic institutions as the team leaders. For the study of technology trends, international conferences held in UK, Germany, and Hawaii are introduced, and domestic meetings, i.e., Annual Polymer Congress and Polymer Conference, are summarized. In addition, Precision Polymerization Forum and International Workshop on Precision Polymerization were held. The basic studies include a quantum-chemical elucidation of the elementary process in polymerization reaction, time-resolved analysis of polymerization process and polymer properties, synthesis of polymers with controlled microstructures by coordination polymerization using metal complexes, synthesis of polymer with controlled microstructures by precision polycondensation, molecular recognition in catalyst-reaction site, and synthesis of imprinting polymers. 246 refs., 117 figs., 14 tabs.

  17. Recycling of plastic group composite materials. 3. ; Current situation in recycling of thermosetting resin composite materials in Japan, Europe and America. Plastic ki fukugo zairyo no recycle. 3. ; Netsukokasei jushi fukugo zairyo no recycle no Nichiobei no genjo

    Energy Technology Data Exchange (ETDEWEB)

    Iimori, H. (Mitsui Toatsu Chemicals, Inc., Tokyo (Japan))

    1993-07-15

    This paper describes the current situation in Japan, Europe and America on recycling of thermosetting resin composite materials, and material treatment and resource re-utilization with emphasis on FRP. Land reclamation would become impossible eventually as a result of difficulty in land procurement, soil contamination, and residents' objection. Pulverization consists of a flow comprising disassembling, cutting, crushing, pulverization, and classification. Pyrolysis heats materials in steam, oxygen-free or low-oxygen atmosphere to recover combustible gases, oils, and resin material solids. Incineration requires incinerator designs that take into account incinerator damages due to black smoke and molten glassfibers. Japan, Europe, and America which have common environmental and legislative regulation issues have begun researches simultaneously. Europe has advanced with pulverization systems in reaching practical use levels, and North America has been using the systems practically. The pyrolytic means are in a feasibility study phase. The issue of the car scrapping law in Germany is inevitable to become a common problem for the EC countries. The automobile industries in North America have been working on technical development under joint investments. Treatment technologies in Japan have nearly reached the levels in Europe and America. Responses to structural change requirements from consumption type to environmental protection type are required. 14 refs., 8 figs., 7 tabs.

  18. Fiscal 1997 technological survey report. R and D on micromachine technology (Development of high functional maintenance technology for power station equipment); 1997 nendo micromachine gijutsu no kenkyu kaihatsu seika hokokusho. Hatsuden shisetsuyo kokino maintenance gijutsu kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    Activities were conducted in search of micromachine technology for a high functional maintenance system that inspects and repairs abnormal conditions such as cracks in a heat exchanger or a piping system without disassembling it in a power generating station such as a thermal or nuclear power plant. The activities were proceeded in four areas of (1) experimental manufacturing of the system (an inline self-running environment recognizing system, an external inspection system for fine tube group, and a system capable of light internal operation such as welding), (2) R and D on sophistication technology for functional devices, (3) R and D on common basic technologies, and (4) comprehensive investigation and research. In (1), examination of detailed basic specifications was carried out, as were examination of element technologies, experimental manufacturing and operation test of element devices, and performance evaluation. Further, a part of element devices was made on an experimental basis, with the basic functions demonstrated. In the comprehensive investigation and research, a trend in the future maintenance technology in power generating equipment was obtained and pigeonholed. (NEDO)

  19. FY 1994 Report on the technical results. Research and development of micromachine technologies (Development of highly functional maintenance technologies for power plants); 1994 nendo micromachine gijutsu no kenkyu kaihatsu seika hokokusho. Hatsuden shisetsuyo kokino maintenance gijutsu kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-09-01

    This research and development project is aimed at development of the technologies for the micromachines provided with maintenance functions, e.g., for examination and maintenance of abnormal conditions in heat exchangers, piping systems or the like. The initial target is set at establishment of basic technologies for the micromachines, in consideration of the available technologies. The R and D activities are directed to (1) microcapsules for, e.g., micro power generators, (2) mother machines having controlling and instructing functions, (3) non-cabled examination modules, (4) cabled examination modules, and (5) total systems. The item (1) involves the micro power generators, and mechanisms of signal transmission, flaw finding and driving/suspension; the item (2) mechanisms of micro-optics and connection, group controlling, microbatteries, action type controlling, and artificial muscles; the item (3) expansion/contraction type transfer mechanisms, light energy supply, micro visual sensation, function connection, and concerted controlling; the item (4) tubular manipulators, and mechanisms of light-aided power generation and voltage elevation; and the item (5) maintenance and micromachine systems. (NEDO)

  20. Achievement report for fiscal 1996 on the research and development of micromachine technology. Development of advanced-function maintenance technology for power generation facilities; 1996 nendo micromachine gijutsu no kenkyu kaihatsu seika hokokusho. Hatsuden shisetsuyo kokino maintenance gijutsu kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    Technologies for integrating functions are studied for a self-propelled surroundings recognition system that travels in a small-diameter tube at power generation facilities. Parameters are analyzed, and piezoelectric locomotion devices are reduced in size. A disk shape microantenna is experimentally built and evaluated, which is for realizing energy supply and communication by means of microwaves. Studies are conducted to improve the performance of optical energy transmission devices and to realize their systematization. Basic specifications are established for the embodiment of CCD (charge coupled device) microcameras to be installed. A high-efficiency, high-reliability micromachine system is constructed, in which multiple machines coordinate with each other for the exterior inspection of groups of small-diameter tubes. Devices which are capable of driving, deceleration, and propulsion prove to be feasible. Basic specifications are established for microconnectors to connect, separate, and combine multiple machines as occasion calls. Also discussed is the development of a micromachine for tube interior check and repair which operates making use of the inspection hole enabling tube interior check and repair without the need of disassembling the equipment to be repaired.

  1. Investigation on development of advanced materials by solvothermal technique; Sorubo thermal hanno riyo senshin zairyo kaihatsu ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    Solvothermal reaction is reaction under high temperature and high pressure, which is expected to fabricate new functional materials. In this study, the materials are classified into two fields, i.e., inorganic materials, metals and their composites and organic materials and their composites. The current status of R and D of production and processing technology in each field is surveyed and the prospect of it is discussed. For the inorganic materials, metals and their composites, it is explained that very fine metal oxide particles, complex oxides, single crystals, whiskers, compounds with layer structure, metastable compounds, ion conductors and catalysts with high ability could be produced only by controlling the solvothermal reactions in atomic order. For the organic materials and their composites, surveyed results of the solvothermal technique using non-aqueous solutions are mainly provided. The necessity of a national project for researches on the solvothermal reactions is proposed from the viewpoint of resource, environment and energy. 777 refs., 38 figs., 26 tabs.

  2. Recent surface modification based on advanced energy processes; Ko energy process ni yoru zairyo no hyomen kaishitsu no genjo

    Energy Technology Data Exchange (ETDEWEB)

    Makino, Y. [Osaka University, Osaka (Japan). Joining and Welding Research Institute

    1997-08-20

    This paper introduces nitrides with metastable phase created by advanced energy processes using ion and plasma as new surface modification methods of materials. Since carbon nitride is a highly hard material harder than diamond which was suggested by Cohen, synthesis of {beta}-C3N4 crystal has been tried by means of the magnetron spattering, plasma CVD, ion beam assisted deposition, and laser abrasion processes. Obtained CN film with high hardness should be based on the sp{sup 3} hybrid bonding. However, the whole atomic configuration has not been clarified yet. Synthesis of cubic system BN (c-BN) is being succeeded for these non-equilibrium metastable phases. The c-BN has a high temperature and high pressure equilibrium phase, and provides properties equivalent to diamond. For the AlN metastable phase, creation of abrasion resistance films superior to haploid TiN has been tried through the synthesis of quasi-2D nitrides by adding AlN to TiN. 24 refs., 4 figs., 1 tab.

  3. Investigational research on highly functional carbon and related materials (HF-CRMs); Tansokei kokino zairyo no chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    The paper arranged a fiscal 1997 guiding study of highly functional carbon and related materials (HF-CRMs). In the material invention field, described were the composition by interatomic control technology and the characteristics of pure carbon nanotubes, carbynes, graphite, fullerene polymer, porous carbon, etc. Heteroelement substituted materials were also described. The paper also reported the application of HF-CRMs to the electric/chemical field, and arranged the basement technology and applicability of diamond in particular. The subjects are enhancement of composition technology and reduction of the price of processing technology. Especially, the control of impurities and defects is a must for the electric use. The application of HF-CRMs to the mechanical field was reported. Superlubricant, wear resistant and high temperature corrosion resistant materials were taken up, and were surveyed in terms of their use mostly to refuse incineration power generation boilers, and thermal power generation use turbines. In the development of mechanical materials, technologies were surveyed especially for large area/complex shape film formation to form films for various parts, functionally gradient film formation for relaxation of thermal stress and residual stress in the film, and high speed film formation for quantity production. 363 refs., 88 figs., 10 tabs.

  4. Polymer-based matrix composites in general industries. Ippan sangyo bun'ya ni okeru kobunshiki fukugo zairyo

    Energy Technology Data Exchange (ETDEWEB)

    Kenmochi, K. (National Institute of Materials and Chemical Research, Tsukuba (Japan))

    1994-02-15

    This paper summarizes the course of development of polymer-based matrix composites (PMC) begun in the 1950's, their future problems, and prospects. Because of PMC being a petroleum product, the changing period before and after the first and second oil crises (1974-1983) has seen even a negative growth from the declined product price out of increased material cost. However, the materials have been continuing expansion in such applications year after year for two decades since then as plant, marine vessel, and housing materials. The course of their development to date has included such proliferation impeding factors as unproved reliability, high production cost, and legal regulations because of being new materials. However, the ardent technical development efforts having produced a number of products including hybrid FRP, particularly the fundamental technology development studies sponsored by the Ministry of International Trade and Industry, have improved properties and reliability and contributed largely to expanding practical applications. Sought in different functions expected in PMC in the future would be application of bionic designs, transfer from functional quality to sensitive quality, and development of material recycling techniques. 8 refs., 11 figs., 1 tab.

  5. Study on the advanced orientation control technology of biopolymers; Seitai kobunshi zairyo no kodo haiko hairetsu seigyo gijutsu no kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    Creation of new functional organic materials for the medical application has been investigated under the microgravity. Facilities of the Japan Microgravity Center were used for this study. For the high-speed synthesis of uniform polymer particles under the microgravity condition for ten seconds, appropriately good results were obtained in the oxidation polymerization of pyrroles. For the synthesis of organic conductive thin films by the electrolytic polymerization, the resistance of electrolyte became larger in the microgravity field. It was required to set conditions so as to enhance the effects of microgravity environment. For the orientation control and thin film formation of proteins, the bacteriorhodopsin was examined. It was found that the microgravity improved the quality of electrocoatings. When the surface tension and viscosity of coating liquid were appropriately controlled under the microgravity, thin films were able to be prepared by utilizing a change from 1g to {mu}g. When the high viscosity fluid is placed in the artificial two-dimensional space composing of two parallel plates, and the low viscosity fluid, such as air, is injected into the above, the interface grows in the finger shaped pattern, namely, viscous fingering. The influence of gravity on this phenomenon was also investigated. 11 refs., 45 figs., 5 tabs.

  6. FY1995 basic research for neuroactive materials; 1995 nendo shinkei kino zairyo kaihatsu ni kansuru kiban kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    Development of nenroactive materials to improve neuronal defects is one of the most important subjects in Japan that will soon become a aging society. In this project, basic research for neuroactive molecule was performed to develop technology for neuronal regeneration, regulation of synaptic activity and interface between artificial surface and living neurons. A novel neurite promoting factor was discovered and its cDNA was cloned. Mutagenesis in vitro showed that a functional region of this factor located in a polypeptide of less than 50 aminoacids. Using neuronal culture, synapse formation was found to depend on two modes of activities and long-lasting synaptic potentiation was demonstrated to depend on a macromolecules released from pre- or postsynaptic neurons. To regulate nervous activities, photoactivated caged-peptide was developed and confirmed to change in affinity to its receptor. Neurons were cultured on substrates paterned by microlithography. (NEDO)

  7. Development of the hardness-gradient blade material by aluminum cladding; Arumikuraddo ni yoru keisha kodo hamono zairyo no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Imai, J.; Hamada, T.; Yamada, S.; Takegawa, Y. [Matsushita Electric Industrial Co. Ltd., Kadoma, Osaka (Japan)] Yamada, H. [Daido Steel Co. Ltd., Nagoya (Japan)

    1998-06-20

    Both high speed drive of a blade and sharpening of the edge of the blade are important for improving the cutting performance of a shaver. An elongation percentage of 20% or greater is requisite for processing the blade and a high surface hardness after heat treatment is necessary for sharpening the edge of the blade. Therefore, an object of this research is to develop a blade material wherein the base material hardness is similar to that of quenched steel of Hv=5GP or greater and the surface hardness is Hv=10GPa or greater. The surface and base material-hardened blade material is obtained by performing heat treatment after the processing of a material with Al applied as cladding to both sides of F3-13CR-2Mo martensite stainless steel. In this material, Al diffuses from the surface to the inside of the material, FeAl-based intermetallic compound is formed in the surface, thus the hardness decreases gradiently toward the inside of the material. When the above-described material is applied to a shaver, the edge of the blade can be sharpened to have a curve radius of or smaller than 1{mu}m, and therefore a blade material with excellent cutting performance is accomplished. 4 refs., 7 figs.

  8. Reinstatement of material research in the 21st century; 21 seiki ni okeru zairyo kenkyu no fukken

    Energy Technology Data Exchange (ETDEWEB)

    Shinbara, K. [Osaka Univercity, Osaka (Japan). Institute of Scientific and Industrial Research

    2000-03-10

    Just before the 21st century, Japan is demanded most importantly of reforming the industrial structures, breeding new industries, and working on global environment and energy problems. To solve these problems, emergence of material technologies based on original ideas is indispensable. However, Japan lacks a temperament to value original ideas and support them in positive manners. Structuring unique ideas and concepts with high originality is one of the most important intellectual production activities for human being. Understanding that these activities require incessant challenging spirit and accumulation of exhaustive efforts, a system should be structured to give the highest honor to researchers and groups who have made successes in this respect. It should be understood that development of the material technologies requires huge amount of fund, human resources and time, and national strategies should be established as required. Habitat segregation is to be moved forward in research and development, and a system will be built that links effectively the seed oriented research by universities and national research institutes with the need oriented research by business enterprises. The 21st century will be an age that many people can dream of their own success. (NEDO)

  9. 1998 report on results of R and D project for industrial science and technology (R and D for technologies of producing innovative high performance material) (development of technologies for structural control material). R and D for high stimuli-responsive material; 1998 nendo dokusoteki kokino zairyo sosei gijutsu no kenkyu kaihatsu (kozo seigyo zairyo gijutsu kaihatsu) kodo shigeki oto zairyo no kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    A report was made on the results of 1998 R and D concerning high stimuli-responsive materials. This R and D was intended to develop technologies for producing, by copying organism, innovative new stocks and new materials which repeatedly provide functions such as separating, transmitting and moving in response to stimuli. In the R and D of polymeric high stimuli-responsive materials, studies were conducted on multi-stimuli-responsive separation materials, molecular recognition controlled separation materials, and cell adhesion/separation materials with molecular recognition function. In the R and D of composite high stimuli-responsive materials, release controlled function materials and materials for actuator were studied. The investigation and research of common basic technologies were carried out on such subjects as synthesis and functional development of multi-signal responded polymer gels, development of temperature-responsive chromatography, synthesis and characterization of novel stimuli-sensitive materials, studies on structural characterization of intelligent gels, novel thermosensitive polymers, polyelectrolytic model networks, etc. (NEDO)

  10. Achievement report for fiscal 1990 on research and development of electrically conductive polymeric materials; 1990 nendo dodensei kobunshi zairyo no kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1991-03-01

    It is intended to realize new electrically conductive materials characterized by light weight, corrosion resistance and easy-to-process performance, and electrical and electronic materials having functions different from those of metallic conduction mechanism. Therefore, activities were performed to seek technologies for polymeric materials having conductivity greater than 10{sup 5} S/cm and being stable and easy to process. Activities were taken in the following six fields: (1) new hydrocarbon conjugate polymers, (2) excipient conjugate conductive materials, (3) technologies to form thin films of graphite synthesized at low temperatures, (4) conductive polymers of hetero aromatic system, (5) research and development of conductive materials of the hetero containing system and the {pi} conjugate system, and (6) comprehensive investigative research. In (1), thin films of polyacetylene and polyacene systems were formed, in (2), excipient hydrocarbon conjugate polymers and excipient graphite materials were developed, in (3), a high-accuracy process controlled graphite thin film forming technology was developed, in (4), the conductivity was enhanced by using high-order structural control and molecular design, and stability of the conductive polymers of complex annular conjugate system was enhanced, and in (5), conductive polymers of the hetero containing system and the {pi} conjugate system, and flexible graphite fibers were developed. (NEDO)

  11. Final report of `research on advanced uses of cast materials`; Chusho kigyo taisaku gijutsu tokubetsu kenkyu `chuzo zairyo no kodo riyo gijutsu ni kansuru kenkyu` shuryo hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    Tada, S.; Takahashi, T.; Abe, T. [Tohoku National Industrial Research Institute, Sendai (Japan)

    1997-03-31

    For the advanced utilization of casting iron, temperature differential austempering and partial austempering with the gradient mechanical properties of ADI (austempered ductile iron) by local electric method were experimentally investigated. For the former, gradient mechanical properties are obtained by giving temperature difference to the material in the process of austempering of casting iron, to add the strength and toughness. For the latter, mechanical properties are controlled by repeating partial austempering with changing the isothermal transformation condition by means of local electric method, to obtain the strength characteristics with appropriate balance. As a result of the former experiment, function gradient materials could be obtained with continuously changing internal mechanical properties. The fabricated material provided different properties depending on the direction of load. Radial crushing strength constant of the ring material depended on the treatment temperature of inside surface of the specimen. Fatigue and yield strengths can be simultaneously improved. As a result of the latter experiment, it was found that the mechanical properties can be improved at arbitrary part by the partial austempering. 13 refs., 25 figs., 4 tabs.

  12. Development of high field magnets at the National Research Institute for Metals. Kinzoku zairyo gijutsu kenkyusho ni okeru kojikai magnet gun no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Kiyoshi, T.; Inoue, K.; Maeda, H. (National Research Inst. for Metals, Tsukuba (Japan))

    1993-06-20

    Sinece 1988, the Scince and Technology Agency has initiated the superconductor multicore project, which has a purpose of the versatile study on the high temperature superconducting materials of the oxide series. The National Research Institute for Metals is in charge of 5 cores out of them, and in the performance evaluation core which is one of them, the development of each kind of the high field magnets is being advanced for evaluating the characteristics under the high magnetic field. As the magnets, including the 40T class hybrid magnet which generates the steady state magnetic field of 40T, the superconducting magnet of 20T with a large diameter which generates the magnetic field over 20T with a superconductor, the condenser bank system for the pulse magnet to generate the pulse magnetic field up to 80T, and the ultra-precise magnet system which generates the magnetic field with a high uniformity will be consolidated. Keeping pace with a removal of the National Research Institute for Metals to Tsukuba, the construction of the strong magnetic field station is being advanced in the Sakura area. These several kinds of magnets are scheduled to be used in turn for the international joint study. 33 refs., 5 figs., 4 tabs.

  13. FY 1998 annual report on the research and development of non-linear, opto-electronic materials; 1998 nendo hisenkei hikari denshi zairyo no kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    The final assessment of researches on non-linear, opto-electronic materials was conducted in FY 1988. These researches are evaluated as the world-level basic researches, high in potential of giving ripple effects on various areas. The R and D themes are organic, low-molecular-weight materials; technology for orientation-controlled crystal growth; conjugated polymer films; microcrystallite-doped glasses using vapor deposition and stuffing method; glass composite materials using sol-gel method and ultra-low melting point glass; nanoparticle-dispersed glasses using super-cooling technology; materials dispersed in organic compounds; organic superlattice formation; three-dimensionally superstructured materials; and comprehensive surveys and researches. The researches and surveys on the common basic techniques were recommissioned to Universities of Tokyo, Keio Gijuku, Nagoya, Tohoku and Hokkaido. These themes are analytical methods for non-linear optical characteristics; morphology-controlled crystal growth of nonlinear-optical organic materials and fundamental studies on all-optical devices; large enhancement of optical nonlinearity and its mechanism in nanocrystals embedded in matrices; improvement of organic materials for high performance; and ultrafast nonlinear optical processes and their application for controlling ultrafast optical pulses. (NEDO)

  14. FY 1991 Report on the results of the researches on nonlinear photoelectronic materials; 1991 nendo hisenkei hikari denshi zairyo no kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1992-03-01

    The nonlinear optics with light-light conversion and electro-optical effects are expected to be the optical materials of the next generation for their functions of, e.g., conversion of the infrared laser beams into visual light, and optical switching. The efforts are directed to development of the procedures for exploring and designing various raw materials, and technologies for synthesizing the raw materials and for producing and evaluating the materials, in order to develop highly nonlinear, high-speed responding materials. Three areas are studied; for the organic materials, the chiral nonlinear effects are demonstrated and the new procedure for determining electrical susceptibility ({gamma}) is developed; for the dispersed materials, highly nonlinear susceptibility of glass dispersed with fine particles of semiconductors, e.g., CuCl, is realized, and possibility of controlled dispersion of fine semiconductor particles in an organic polymer is established; and for development of the superlattice-based materials, the layered structures of thin organic superlattice films are studied, the thin semiconductor films of high purity and little defects are prepared, and development of the three-dimensional structures is started. The individual researches are conducted, 3 for the organic materials, 4 for the dispersed materials, and 2 for the superlattice-based materials. The targets of susceptibility and response are 10{sup -8}esu or more and 10ps or less, respectively. (NEDO)

  15. Investigational study of optical function materials for two-dimensional data processing; Nijigen joho shoriyo hikari kino zairyo ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    The paper investigated/studied `space light modulation materials,` `dynamic hologram/memory materials,` `optical waveguide path materials,` etc. which become key materials in the high speed two dimensional processing. As to electrooptical materials proposed in this investigational study, the external electric field and the electric charges generated make quality of molecules themselves directly change to memory strong/weak signals of light. Therefore, the response velocity becomes less than a millionth of that of the liquid crystal display, and high speed which is needed for realtime moving image processing is anticipated. Hologram includes the phase information in addition to information on light strength. Therefore, it is a large capacity record medium and at the same time a record medium which can read/write two dimensional information as it is. With optical fiber, images cannot be transmitted as they are. Light waveguide path materials are those that accumulate roles of mirror and lens in a sheet of the material and construct a system which is strong in vibration, as optical parts connecting among materials for two dimensional data processing. 273 refs., 107 figs., 17 tabs.

  16. Research on giving antibacteria activity of tailored dental materials; Gin ion ni yoru shikayo zairyo no kokinsei fuyo ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    The secondary dental caries easily occur by breeding of bacteria in cavities between living body and composite resin, false tooth or root of tailored tooth as tooth repairing materials. The antibacteria activity of tailored dental materials was thus studied by implanting Ag ion. The antibacteria effect with time after culture of caries bacteria was studied by implanting Ag ion into SiO2 powder, PMMA samples and Ti alloy samples at 20 and 200keV in energy of ion. In addition, the antibacteria activity of SiO2 powder as composite material was found at 25keV which was previously effective for the antibacteria activity. This SiO2 filler (Ag{sup +} filler) showed the antibacteria activity on every bacteria sample after 2h, and in particular, could kill all of 3 kinds of bacteria obtained from a composite resin surface after 12h. The number of living S. salivarius was reduced by half after 12h. The application of the composite resin filler implanted with Ag{sup +} is significant to prevent recurrence of caries. 5 refs., 27 figs., 7 tabs.

  17. Development of new engine bearings with overlay consisting of solid lubricants; Kotai junkatsu overlay tsuki engine yo suberi jikuuke zairyo no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Kanayama, H.; Kawakami, S.; Gohara, C. [Taiho Kogyo Co. Ltd., Aichi (Japan); Fuwa, Y.; Michioka, H. [Toyota Motor Corp., Aichi (Japan)

    1997-10-01

    Recently, modern engines have a tendency for higher output and longer periods. As a result , higher bearing performance is required. For this reason, we have developed the new conceptual overlay consisting of solid lubricants and thermosetting plastics. This paper describes the performance of engine bearings with the new overlay. 5 refs., 13 figs., 5 tabs.

  18. FY 1985-1992 summarized report on the R and D of photoreactive materials; 1985 nendo kara 1992 nendo hikari hanno zairyo kenkyu kaihatsu sokatsu hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1993-12-01

    For the purpose of establishing the basement technology relating to photoreactive materials which make remarkably higher density and larger capacity of the information recording possible, the following were made for photochromic materials and PHB materials: elucidation of the photoreaction mechanism, development of materials, development of material processing/structure technology and development of evaluation technology. The target is to establish the technology of the multiplex recording which is applicable to the super-high density recording in relation to PHB materials/organic photochromic materials which have potentiality of photon-mode recording. PHB materials were developed which have potentiality of 600 wavelength multiple recording and 5 electric field multiple recording in 4.2K and 9 wavelength multiple recording in 77K. Photochromic materials were developed which have high sensitivity and preservation stability and have potentiality of 10 wavelength multiple recording at room temperature. A new photo-recording method was found out by which the orientation of liquid crystal is photo-controlled and potentiality of the multiple polarization was shown. Moreover, the fabrication was successfully made of PHB materials and photochromic materials which make non-destructive readout operation of more than 10{sup 4} times possible. (NEDO)

  19. Preprint of the 40th material study joint lecture of Science Council of Japan; Dai 40 kai Nippon gakujutsu kaigi zairyo kenkyu rengo koenkai maezurishu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-09-19

    The paper stated mostly topics from special lectures. Composite materials have a lot of potentialities, and there are larger expectations in flexible and high-strength soft composites rather than the conventional high rigidity ones. As to micro-machines, the problems are on mechanical property of the element, environment/friction/fracture/life, etc. and the evaluation method of the characteristics was studied. Concerning the research and development of the intellectual structure system, the introductive study has entered the second year. Ultimately, structures have functions similar to those of the living organism had, and conduct self-diagnosis, self-repair and autonomous-response. Railroad structures receive regular inspections according to the rule, and a half of the objects for the inspection are cracks, unbonding and weathering of concrete. With the Hanshin Awaji great earthquake especially, the anti-earthquake reinforcement has been expedited. In various kinds of materials, the finer the crystal particle becomes, the greater the high temperature deforming ability becomes. When the particle size is below the critical particle size, it shows superplasticity. The study is advancing. As to high density secondary batteries, introduced especially were Ni-hydrogen batteries and Li batteries.

  20. FY 1991 Report on the results of the research and development of photo-reactive materials; 1991 nendo hikari hanno zairyo no kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1992-03-01

    This project is aimed at establishment of the basic technologies for photo-reactive materials capable of, e.g., superhigh-density, superhigh-resolution display using photo-functions to control structures and associated conditions of the molecules. More concretely, the efforts are directed to realization of the technologies for multiplexing, sensitivity-response and material stability, applicable to superhigh-density recording by photochromic and photo-chemical burning (PHB) materials. For the photochromic materials, the long-chain alkyl derivatives of photochromic compounds, e.g., spiropyran and fulgide, are formed into thin films by the LB method, in order to develop organic, superhigh-density recording devices by controlling their associated conditions, and controlling of the photochromism reactions in the films is studied. Those studied for the PHB materials include improvement of heat resistance of the materials, development of quinone-based materials and improvement of their degree of multiplexing, and development of porphyrin-based materials and of technologies for structuring them. The comprehensive survey/research activities include extraction of the problems involved in the themes mainly related to the committee activities, and related technologies. (NEDO)

  1. Oxadiazole derivatives for emmitter and carrier transport materials in organic electroluminescent devices. Yuki electroluminescence zairyo toshite no oxadiazole yudotai no hyoka

    Energy Technology Data Exchange (ETDEWEB)

    Hamada, Y. (Sanyo Electric Co. Ltd., Osaka (Japan)); Adachi, C.; Tsutsui, T.; Saito, S. (Kyushu Univ., Fukuoka (Japan). Graduate School of Engineering Sciences)

    1991-11-10

    This paper describes the result of evaluation made on oxidiazole derivatives, which have been used as materials for electrophotography and scintillators, as a new organic electroluminescence (EL) material. The evaluation made on 10 kinds of newly synthesized oxadiazole derivatives gives the following results. When various substituents having different electronic properties are introduced into three types of oxadiazole derivatives, A, B, and C, strong fluorescence from 374 nm to 527 nm in wavelength occurs. Regarding the wavelength difference between the photoluminescence (PL) and EL, those having substituents of alkyl, ethoxyl, and phenyl groups have larger wavelength differences and those having substituents of dimethylamino base have smaller wavelength differences. As a result of investigation on luminance characteristics made by device structures, it becomes clear that the groups having larger wavelength differences between EL and PL are substances having only electron transporting property and groups having smaller wavelength differences are substances having both electron and hole transporting properties. 9 refs., 12 figs., 1 tab.

  2. Achievement report for fiscal 1990 on research and development of highly crystalline polymeric materials; 1990 nendo kokesshosei kobunshi zairyo no kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1991-03-01

    Activities were performed to seek polymeric materials having mechanical strength comparable to metallic materials as a result of giving contrivance on the composition and processing method, and bending strength of 100 GPa or more. The activities were taken in the following five fields: (1) a one-dimensional system material, (2) special melting and forming of a multi-dimensional system, (3) compound forming of multi-dimensional molecules, (4) hybrid cross-linking of cross-linking systems, and (5) high-density cross linking of cross-linking systems. In Item (1), researches were made on optimization of the structures, and elongation and fluid processing of thermotropic liquid crystal polyacrylate, wherein the objective was achieved. In Item (2), the objective was achieved on poly (imide-benzobisthiazole) by monoaxial drawing and lamination thereof. Discussions were given on the liquid crystal polymer as to its correlation between the structure and the magnetic field orientation. In Item (3) discussions were given on the composition and processing method for molecule compounded materials reinforced by aromatic polyamide matrix-polyphenylenebenzothiazole. In Item (4), ionomers were discussed. In Item (5), discussions were given on multi-functional diacetylene system and diacetylene group containing polyimide. (NEDO)

  3. Simulation on breakage of heterogeneous materials caused by detonative loading; Bakugo shogeki ni yoru fukinshitsu zairyo no hakai gensho no simulation

    Energy Technology Data Exchange (ETDEWEB)

    Sassa, K.; Watanabe, T.; Ashida, Y. [Kyoto University, Kyoto (Japan). Faculty of Engineering

    1996-05-01

    Investigations were conducted by simulation of breakage of inhomogeneous materials (rock) attributable to detonative loading, which simulation used the Days-2 Code. During the simulation, one-free-face blastings were used for testing a homogeneous structure, horizontal 2-layer structure, and horizontal 3-layer structure. Property values were assigned to the rocks on the assumption that they were sedimentary rocks such as sandstone or mudstone or hard rocks such as granite. As the result, it was found that a detonative loading resulted in shear failure in a sphere near the focus that was followed by radially developed cracks due to tension breakage, that more area is damaged in a soft rock than in a hard rock, that cracks due to breakage are produced by the overlapping of waves directly from the focus and those reflected from the free face in case of one-free-face blastings, that such cracks propagated along the soft rock layer in case there is a soft rock layer in a hard rock, but that breakage does not extend beyond the soft rock layer. 6 refs., 6 figs., 1 tab.

  4. Development of symmetric composition-gradient materials including hard particles in its surface layer; Hyosobu ni koshitsu ryushi wo fukumu taishogata sosei keisha zairyo no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    Development of new materials with both thermal resistance and thermal shock resistance was studied on the basis of symmetric ceramics/metal/ceramics gradient composition. Al2O3/TiC/Ni/TiC/Al2O3 was used as material model of basic composition, and the system was selected where WC-Co system alloy hard particles were dispersed into the Al2O3 ceramic surface layer. The layered material was sintered in N2 gas atmosphere by SHS/HIP method using exothermic caused by nitriding reaction. Since cracks were generated in some specimens of 5-layer structure, improved specimens of 7-layer structure were prepared. To examine the effect of a particle size on toughness, WC-Co system alloy specimens with different particle sizes were also prepared. As a result, no cracks were found, and residual stress and fracture toughness were affected by particle size. In addition, the following were studied: technique of mass production, observation of fine structures, analysis of thermal stress, thermal shock resistance, and friction and abrasion characteristics. 13 refs., 65 figs., 15 tabs.

  5. Report on investigations and studies on development of materials for hydrogen absorbing alloys; Suiso kyuzo gokin no zairyo no kaihatsu ni kansuru chosa kenkyu hokokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1984-03-01

    This paper describes investigations and studies on hydrogen absorbing alloy materials and the technologies to utilize them. In the investigations and studies, literatures were collected and put into order, questionnaire surveys were performed and analyzed, lecture meetings and panel discussions were held, and the discussion results were summarized. In the present status of developing hydrogen absorbing alloys, the current status of and problems in developing such hydrogen absorbing alloys as Ti-based, Mg-based, and rare earth-based alloys were put into order. Discussions were given on prospects of possibilities of developing new alloys, making them amorphous, and putting them into mass production. In the current status of developing the utilizing technologies, such technologies as hydrogen storage systems and heat pumps were put into order and discussed. With regard to problems in hydrogen absorbing alloys, discussions were given on alloy weight, pulverization, activation, heat conductivity, and alloy costs. In discussing the safety, discussions were given on the safety and compliance with related laws and regulations relative to hydrogen transportation using a great amount of hydrogen absorbing alloys, their storage, and heat storage systems. In addition, questionnaire surveys were carried out with an objective to identify the status of developing hydrogen absorbing alloys and needs from the industries. (NEDO)

  6. On the improvement of mechanical properties of monolithic silica aerogels (for transparent insulating material); Silica aerogel (tomei dannetsu zairyo) kyodo no kaizen ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Tajiri, K.; Igarashi, K.; Tanemura, S. [National Industrial Research Institute of Nagoya, Nagoya (Japan)

    1997-11-25

    Study was made on improvement of the strength of silica aerogel as transparent insulating material. Silica aerogel is a low-density porous material with high heat insulation and transparency. To develop a insulating material with high transparency, monolithic silica aerogel was studied. For direct use of it for windows, its strength improvement was attempted. The aerogel was prepared by supercritical drying (alcohol or CO2) of silica wet gel obtained by hydrolysis and condensation of silicon alkoxide solution. To prepare the aerogel bonded on plate glass for strength improvement, the aerogel was bonded to alkoxide by exposing active silanol radical through F-etching of plate glass surface. However, to obtain the practical large-area bonded aerogel, shrinkage control of the aerogel in supercritical drying was necessary. Addition of Laponite into a silica network for strength improvement by polymer increased the bending strength by 50%. Although some reduction of its transparency was observed because of clouding, its heat insulation was stable. Further strength improvement is necessary for its practical use. 5 figs., 1 tab.

  7. Development of new type of nonlinear optical materials with a function of ultrafast optical modulation; Chokosoku hikari reiki hencho kino wo motsu atarashii hisenkei kogaku zairyo no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Sakaguchi, H. [Shizuoka University, Shizuoka (Japan). Research Institute of Electronics

    1995-12-15

    Ultrafast modulation of second harmonies from a Langmuir-Blodgett film consisting of a ruthenium complex was demonstrated for the first time. The mechanism of the modulator of SHG intensity on laser irradiation was ascribed to the change of molecular hyperpolarizability of the ruthenium complex on going from the ground state to the excited state. 9 refs., 12 figs.

  8. Effects of mechanical stimulating treatment on self-organization phenomena of materials; Kikaiteki reiki shori. Zairyo no jiko soshikia gensho ni oyobosu sono koka

    Energy Technology Data Exchange (ETDEWEB)

    Hida, M. [Okayama University, Okayama (Japan). Faculty of Mechanical Engineering

    1999-03-31

    The atoms and atom clusters around dislocation cores in crystals or surface layer deformed by mechanical energy are locally excited so as to give rise some chemical reactions and to self-organize their products into a kind of Spatial-Temporal Pattern Formation as a dissipative structure. A famous coupling phenomenon between mechanical and chemical process in solid materials must have been mechanical alloing. This report explains that various mechano-chemical treatments are powerfull method for entraining the solid system into non-equilibrium states and interesting phenomena stimulated by the mechanical self-catalysis reaction causing self-organization. (author)

  9. Achievement report on research and development in fiscal 1989. Research and development of non-linear photoelectron materials; 1989 nendo hisenkei hikari denshi zairyo no kenkyu kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1990-03-01

    With an objective to realize the communication and information processing utilizing the high velocity and parallelism of light, search for materials having non-linear susceptibility and high-speed responsiveness, and research and development of the material using technology have begun. This paper reports the achievements in fiscal 1989. In developing organic materials, investigations and preliminary experiments were performed on three-dimensional non-linear photoelectron materials of organic low molecular systems, such as chiral non-linear photoelectron material. Fundamental studies were made on growth of orientation controlled crystals. Researches were carried out on polymeric films of organic and conjugate systems. In developing the dispersed system materials, researches were executed on a technology to deposit CuCl particulates using the air phase method and porous glass impregnation method, and on evaluation of non-linear photoelectron properties of CuCl particulate dispersed glass. In addition, glass dispersed system materials were studied by using the sol-gel method, the ultra-low melting point glass method, and the ultra quenching method. Furthermore, for the organic dispersed system materials, synthesizing conditions were discussed on CdS/polymer dispersing element films, and ultra-particulate synthesizing experiments were performed. In developing the ultra-grid system materials, researches were performed on the organic ultra grid making technology and the three-dimensional ultra-structuring technology. (NEDO)

  10. FY 1996 R/D project of industrial and scientific technologies contracted with NEDO. Report on R/D of organosilicon polymers; 1996 nendo sangyo kagaku gijutsu kenkyu kaihatsu jigyo Shin energy Sangyo Gijutsu Sogo Kaihatsu Kiko itaku. Keisokei kobunshi zairyo no kenkyu kaihatsu (Keisokei kobunshi zairyo no kenkyu kaihatsu) seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-12-01

    Organosilicon polymers are highly innovative materials having high performance and novel functions, and they can be widely applied. The purpose of this study is to establish fundamental techniques for molecular design, synthesis, material processing and evaluation of organosilicon polymers having excellent electro- and photo-functions, and advanced heat-proof, fire-proof and mechanical properties. This R/D includes (1) R/D of electrical conducting materials by organosilicon polymers, (2) R/D of novel organosilicon polymers applicable to direct lithography, (3) R/D of new silicon-based polymer materials with electro-luminous function, and (4) R/D of silicon-based polymers for new photoconductive materials. In (1), synthesis of highly conjugated polymers is investigated. In (2), novel organosilicon polymeric materials have been developed, which would be applicable to direct lithography of electronic circuits, and which could contribute to simplification of the circuit formation process. In (3), the research aims at development of new silicon-based polymer materials with luminescent function which can be applied to the large size electro-luminescent display devices. In (4), new materials with visible light absorption have been synthesized through the molecular design and synthesis. The photo-carrier generation was observed. 107 refs., 86 figs., 23 tabs.

  11. FY 1997 R/D project of industrial and scientific technologies contracted with NEDO. Report on R/D of organosilicon polymers; 1997 nendo sangyo kagaku gijutsu kenkyu kaihatsu jigyo Shin energy Sangyo Gijutsu Sogo Kaihatsu Kiko itaku. Keisokei kobunshi zairyo no kenkyu kaihatsu (keisokei kobunshi zairyo no kenkyu kaihatsu) seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    The purpose of this study is to establish fundamental techniques for molecular design, synthesis, material processing and evaluation of organosilicon polymers having excellent electro- and photo-functions, and advanced heat-proof, fire-proof and mechanical properties. This R/D includes (1) R/D of electrical conducting materials by organosilicon polymers, (2) R/D of novel organosilicon polymers applicable to direct lithography, (3) R/D of new silicon-based polymer materials with electro-luminous function, and (4) R/D of silicon-based polymers for new photoconductive materials. In (1), synthesis method of regular polymers with a 3-D structure was developed. Non-volatile dopants were developed, and structures of polymer-dopant composites could be controlled. In (2), precise control of conductivity was examined. Material processing and evaluation techniques were also examined through stabilization of polysilane thin films, optimization of pattern forming conditions, and precision of patterns. In (3), new silicon-based polymers have been synthesized. In (4), two kinds of polymers have been synthesized for development of materials with high photo-carrier generation efficiency and high mobility. 72 refs., 71 figs., 22 tabs.

  12. FY 1991 Research and development project for large-scale industrial technologies. Report on results of R and D of superhigh technological machining systems (Development of advanced machining devices for power-generating members); 1991 nendo chosentan kako system no kenkyu kaihatsu seika hokokusho. Hatsuden shisetsuyo buzai kodo kako sochi kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1992-03-01

    Described herein are the FY 1991 results of the R and D project aimed at establishment of superprecision machining technologies for developing machining technologies and nano-technologies aided by excited beams. For increasing the excimer laser output, the discharge-exciting technologies necessary for designing the 2kW laser as the final target are established. The service life tests are started to demonstrate the member service life of 10{sup 9} shots or more. For development of the technologies for large-current composite ion beams, the plant is constructed to attain the final targets (100keV, 2A, width: 500mm or more). The currents reaching the substrate are developed to have 2.8mA with the Ar ion and 2.9mA with the Ca ion by, e.g., developing the ion sources and improving functions of the ion beam controlling systems. Researches on the surface modification technologies for producing the superhigh-quality metallic surfaces involve composite ion implantation and providing the modified layer of Ti-B-based hard compound. Corrosion rate of the modified titanium surface in a boiling sulfuric acid solution is reduced from 300mm/year to around 0.13mm/year. (NEDO)

  13. Fiscal 1997 report under consignment from NEDO on photon measuring/processing technology (development of power generation facility use high-function maintenance technology); 1997 nendo Shin energy Sangyo Gijutsu Sogo Kaihatsu Kiko itaku photon keisoku kako gijutsu (hatsuden shisetsuyo kokino maintenance gijutsu kaihatsu) seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    A research/development was conducted on technologies of photon applied measuring/photon applied processing/photon generation which are usable for heightening of reliability and maintenance efficiency of power generation facilities. In fiscal 1997, high melting-point metal particles were manufactured by high energy density laser for formation of high temperature and stabilized fine functional circuit. Further, a wavelength changeable ultra red laser light source was studied which can make in-situ measurement of gas concentration and components. A study was also made to examine the surface composition by measuring fluorescent X-rays emitted by radiating high intensity laser beam on the surface of material. A rod type and a slab type as a high-output complete-solidified laser are under development. There is also a development aiming at high speed/high quality photon processing such as high speed/high precision welding/cutting and laser joining. Besides, a study is being made of high energy pulse/high quality beam complete-solidified laser. The paper made a comprehensive survey of the trend of the photon measuring/monitoring technology, and made a systematical arrangement of the developmental subjects extracted. 142 refs., 357 figs., 62 tabs.

  14. FY 1992 Report on the results of the research and development of micromachine technologies. R and D of highly functional maintenance technologies for power generating systems; 1992 nendo micromachine gijutsu no kenkyu kaihatsu seika hokokusho. Hatsuden shisetsuyo kokino maintenance gijutsu kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1993-03-01

    Described herein are the FY 1992 results of the R and D project aimed at development of microcapsules, mother machines, examination modules without retrieval and working modules with retrieval, and their application to total systems for development of the highly functional maintenance technologies for power generating systems. Researches on the microgenerators involve studies and extraction of technical problems for structures, thin-film magnet production methods, coil winding methods, high-speed microbearings and microaccelerators. Researches on the mother machines involve development of the basic elements, on a trial basis, of the electrostatic actuators for the mechanisms of driving the main bodies, and evaluation of their characteristics by a minute torque analyzer. Researches on the examination modules without retrieval involve basic studies on, e.g., expansion driving, supersonic and microwave energy conversion devices for the expansion transfer mechanisms, development of these devices on a trial basis, evaluation of their functions, and extraction of the problems. Researches on the working modules with retrieval involve studies on shape memory alloy materials for tubular manipulators and actuator mechanisms. (NEDO)

  15. Research and development project in fiscal 1990 for large industrial technologies. Achievement report on research and development of ultra-advanced processing systems (Development of high-level processing devices for electric power generation facility members); 1990 nendo chosentan kako system no kenkyu kaihatsu seika hokokusho. Hatsuden shisetsuyo buzai kodo kako sochi kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1991-03-01

    Research and development has been performed with an objective to establish the processing technology using excitation beam required for the advanced technology industries, and the ultra-precision machining technology to realize the nano-technology. This paper summarizes the achievements in fiscal 1990. In the research on the large output and long life technology for excimer laser, an average output of 500 W or more was demonstrated achieving the intermediate target by developing and improving the technologies for low electric power gas circulation, high efficiency discharge and excitation, and large output oscillation control. In the research on intensity resistant optical element technology, a prototype device was fabricated to create and process axially symmetrical aspherical shapes, whereas SiC aspherical shape creation and processing were demonstrated at the shape accuracy of three microns or better, and surface roughness of 20 nanometers or less, having achieved the intermediate target. Regarding the large current ion beam, a demonstration device was completed based on improvements and test results on the sheet plasma generator. In the research and development of the high-level processing technology, low-temperature forming technology was developed for oxide ceramic thin films by using the excimer laser abrasion method. (NEDO)

  16. Fiscal 1998 research report on application technology of molecular assemblies for a functional protein system (Development of advanced maintenance technology for power plants); 1998 nendo kinosei tanpakushitsu shugotai oyo gijutsu no kenkyu kaihatsu. Hatsuden shisetsuyo kokino mentenansu gijutsu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Basic research was made on engineering reappearance and industrial use of the complex function of molecular assemblies for a functional protein system of organisms. In research on a light controllable reaction system by physicochemical technique, construction of a light controllable bioreactor is in promotion. In research on a light controllable reaction system by biochemical technique, researches are in promotion on structure and correlation analysis of photosynthetic protein complex, stabilization of an activity, and conversion of light energy to membrane transport energy using cyanobacteria as material. In research on a molecular recognition controllable reaction system in a fine membrane region, correlation analysis of the structure and function of glutamine receptor channels is in promotion. In addition, researches were made on reconstitution of endocytic micromachinery, a multi-enzyme system for synthesis of glycosphingolipids, a complex redox system by genetic engineering technique, and application technology of molecular assemblies for a functional protein system. (NEDO)

  17. Fiscal 1997 project on the R and D of industrial scientific technology under consignment form NEDO. Report on the results of the R and D of technologies to invent original high-functional materials (technical development of structure control materials / R and D of molecular harmonized materials); 1997 nendo sangyo kagaku gijutsu kenkyu kaihatsu jigyo Shin Energy Sangyo Gijutsu Sogo Kaihatsu Kiko itaku. Dokusoteki kokino zairyo sosei gijutsu no kenkyu kaihatsu (kozo seigyo zairyo gijutsu kaihatsu) bunshi kyocho zairyo no kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    By establishing microtechnology using molecular-level bottoming-up (molecular harmonization) by imitating the system of living organism, the paper described the R and D of molecular harmonized materials aiming at developing high-functional/high-performance materials such as high-performance catalyst, photo-information functional materials and sensing materials. Under consignment from NEDO, Japan Chemical innovation Institute started the 5-year plan in fiscal 1997. Self-assembled molecular films, in which organic molecules are orderly arranged by self-assembly, aim at developing new memory/optical/sensing materials. Mesophase materials which are such materials as liquid crystal showing the intermediate state between solid and liquid, develop optical/photoconductive materials using precise molecular orientation controllability. Macroporous materials are such substances as zeolite having molecular size micro pores. The paper aims at establishment of synthesis techniques of them and development of high-performance catalyst, etc. using them. In the comprehensive investigational research, conducted was a survey of the trend overseas in addition to a study of subjects in question. Further, the supporting basic study was reconsigned to universities, etc. 57 refs., 62 figs., 17 tabs.

  18. Fiscal 1997 project on the R and D of industrial scientific technology under consignment from NEDO. Report on the results of the R and D of technologies to invent original high-functional materials (technical development of structure control materials / R and D of multi-stimuli-responsive materials); 1997 nendo sangyo kagaku gijutsu kenkyu kaihatsu jigyo Shin Energy Sangyo Gijutsu Sogo Kaihatsu Kiko itaku. Dokusoteki kokino zairyo sosei gijutsu no kenkyu kaihatsu (kozo seigyo zairyo gijutsu kaihatsu) kodo shigeki oto zairyo no kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    The paper described multi-stimuli-responsive materials out of the technology developments for creating original high-functional materials under the system of R and D of industrial scientific technologies. These are materials which repeatedly reproduce functions such as separation, penetration and movement in response to stimuli by imitating living organisms. In relation to polymer multi-stimuli-responsive materials, various copolymers were synthesized using N-acetyl (meta) acrylamide, of which the synthesis method was established in the previous fiscal year, as a main component, and thermal responsive polymer with upper critical solution temperature which becomes a base of separation functional materials was searched for. By immobilizing it with molecular recognition ligand, measured was thermal dependence of affinity of the immobilized matter to albumin. Also studied were molecular recognition cell adhesion/separation functional materials. Concerning composite multi-stimuli-responsive materials, with the use of silica microcapsule surface-immobilized with silane coupling agent, studied were the optimum conditions for immobilizing thermo-responsive polymer to the surface of the capsule. Using motion functional materials by ion exchange resin, obtained was motion functionality which is satisfactory at the state of practical use. 94 refs., 82 figs., 16 tabs.

  19. FY 1997 report on the modification of dental materials with Ag for improvement of antibacterial activity; 1997 nendo chosa hokokusho (gin ion ni yoru shikayo zairyo no kokinsei fuyo ni kansuru kenkyu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    Improvement of an antibacterial activity is one of the issues in modification of artificial teeth for an aged society. Study was made on improvement technique of an antibacterial activity with Ag ion as secondary corrosion measures. Partial gaps of dental materials themselves and gaps between materials and peripheral tissues causes bad breath or bad teeth through propagation of disease germs. Ag ion is harmless and has an antibacterial activity for bio-tissues from a macro-viewpoint, however, only corrosion germ causing bad teeth in mouths should be sterilized by controlling an elution rate of Ag properly. The antibacterial activity was controlled by controlling Ag ion implantation depth and rate, and Ag elution rate for dental materials. Experiment was made on an IMZ twinplus specimen implanted with Ag ion and an Ag thin film-coated specimen using beagle dog in comparison with an unmodified specimen. As a result, the very favorable antibacterial activity was obtained. Ag ion is effective for prevention of endogenous infectious disease due to mouth germs in dental surgery. 3 refs., 47 figs., 10 tabs.

  20. Achievement report for fiscal 1998 on the research and development of a technology to create original high-function materials; 1998 nendo dokusoteki kokino zairyo sosei gijutsu no kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    In order to promote effectively the research and development of a technology to create original high-function materials, the Japan Chemical Innovation Institute (JCII) has performed as comprehensive surveys and studies the surveys on the state of progress in research and development, as well as extraction, analysis and discussions on the status of the research and development. The Institute has also executed technological trend surveys on technological currents in Japan and other countries, the latest technologies, technological seeds and technological markets. The comprehensive survey and study committee has held at the end of a fiscal year a meeting of the comprehensive survey and study committee for the technology to create original high-function materials collectively on the following five themes: high-level stimulation responsive materials, molecule coordinating materials, precision catalyst polymerization, condensation system precision structural control, and multi-dimensional spatial polymers. The committee reported and discussed the status of progress in each centralized joint research for this fiscal year and the research plans for the next fiscal year. In the development of the chlorine-based primer substituting high-performance polymers, development is being carried out on the technology to provide reactivity groups to both ends of a polymer utilizing living polymerization of propylene by using a vanadium-based Ziegler type catalyst. Development of new catalysts has also been begun with an aim of further improving the performance of the catalysts. (NEDO)

  1. Fiscal 1993 achievement report on next-generation industrial structure technology (Advanced materials for extreme environments - Development of methane fueled aeroengine); 1993 nendo chotaikankyosei senshin zairyo no kenkyu kaihatsu seika hokokusho. Methane nenryo kokukiyo engine no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-03-01

    Efforts were exerted to develop advanced materials for use under extreme environments, which were intermetallic compounds and fiber reinforced intermetallic compound composite materials excellent in heat resistance, specific strength, oxidation resistance, or the like. For the development of intermetallic compounds, efforts were made to develop Ti-Al-X (X=metal) high specific strength intermetallic compounds and Nb-Al-X (X=metal) high melting point intermetallic compounds. Ternary phase diagrams were prepared and the effect of added elements on basic characteristics was investigated. Basics of element technologies (texture control, melting, casting, and isothermal rolling) for manufacturing panel materials were studied and, in the case of Ti-Al-X systems, Ti-Al thin panels were fabricated. In the case of Nb-Al-X systems, items were experimentally fabricated by casting in an effort to study precision casting technology optimization. For the development of composite materials, efforts were made to develop SiC based and SiMC (M=metal) based fibers, and studies were carried out to complex them with Ti-Al based matrices. (NEDO)

  2. Thermal shock resistance of SiC/C functionally gradient material prepared by chemical vapor deposition. CVD ho ni yori sakuseishita SiC/C keisha kino zairyo no tainetsu shogekisei

    Energy Technology Data Exchange (ETDEWEB)

    Sasaki, M.; Hirai, T. (Tohoku Univ., Sendai (Japan). The Research Inst. for Iron, Steel and Other Metals); Hashida, T.; Takahashi, H. (Tohoku Univ., Sendai (Japan). Faculty of Engineering)

    1990-09-25

    The authors fabricated functionally gradient materials (FGM) having a composition distribution from C to SiC on a graphite substrate by chemical vapor deposition (CVD), and researched the thermal shock resistance under local heating. The thicknesses of the SiC/C FGM are 0.8 mm and 1.8 mm. Under local heating by carbon dioxide laser, SiC non FGM (NFGM) suffered cracking at heat flux density 5.8 MW/m {sup 2}, and SiC/C FGM suffered cracking at heat flux density 7.4 MW/m {sup 2}. As the thickness of FGM film increased from 0.8 mm to 1.8 mm, temperature difference in the film increased from 390K to 560K. From these experiments, it was clarified that the improvement of thermal shock resistance under local heating was achieved by SiC/CFGM coating. 7 refs., 6 figs.

  3. Research and development of basic technologies for next-generation industry. Ultimate evaluation report on research and development of highly efficient polymeric separation membrane material; Jisedai sangyo kiban gijutsu kenkyu kaihatsu. Kokoritsu kobunshi bunrimaku zairyo saishu kenkyu kaihatsu hyoka

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1991-05-01

    For the enhancement of separation process efficiency and energy efficiency in the chemical industry, etc., basic technologies are developed involving high-performance separation membrane materials which are excellent in durability and usable in the field where separation by membranes has been impractical. The liquid mixtures subjected to separation are a neutral organic compound/water system, an acidic organic compound/water system, and a polar organic compound/water system; the gas mixtures subjected to separation are an oxygen/nitrogen system and a carbon monoxide/nitrogen system. After a 10-year/3-phase development endeavors, the initially intended goals are sufficiently achieved. Among those that have to be mentioned is the development of a nonaqueous separation membrane, a supported liquid membrane with amino acid optically active high performance separation capability, a high-precision evaluation unit for gas separation membrane characteristics, a selective permeation membrane with high-level oxygen and carbon monoxide carriers and reactivation technology, a high-performance ethanol separation membrane, a water/polar organic compound separation membrane, and a water/acetic acid separation membrane and stability providing technology. In particular, the water selective permeation membrane for a mixture of water and alcohol has already arrived at the stage of bench plant demonstration. (NEDO)

  4. FY 1991 Report on the results of the research and development of silicon-based high-molecular-weight materials; 1991 nendo keisokei kobunshi zairyo no kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1992-03-01

    The research and development project has been started to establish the basic technologies for molecular designs, synthesis, material production and evaluation of silicon-based high-molecular-weight materials expected to exhibit excellent characteristics, e.g., electro-optical functions, resistance to heat, flame retardance and mechanical properties. The efforts in FY 1991, the first year for the 10-year project, are mainly directed to the surveys on the R and D trends, both domestic and foreign, to clarify the relationship between the structures and functions/properties. The R and D projects followed include the technologies for synthesizing (1) electroconductive silicon-based high-molecular-weight materials, (2) novel silicon-based high-molecular-weight materials capable of drawing circuits, (3) novel, light-emitting silicon-based high-molecular-weight materials and (4) silicon-based opto-electric conversion materials for the electro-optical functional high-molecular-weight materials; and (1) synthesis of high-molecular-weight structural materials of sea island structure, (2) technologies for forming inter-penetrating type structures (IPN), (3) development of composite structural materials of organometallic complex and silicon-based high-molecular-weight material, and (4) development of silicon-based high-molecular-weight materials of ring structure for the high-molecular-weight structural materials. (NEDO)

  5. Study of super high temperature ceramics-based and Mo-based materials for the heat exchanger of coal combustion gas; Sekitan nensho gas netsu kokankiyo no ceramic kei oyobi molybdenum kei chokoon zairyo ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    Materials for the heat exchanger were studied which can bear the high temperature corrosion environment represented by the high efficiency coal-fired power generation system. From the literature search, were selected the Cr2O3-based ceramics with relatively high corrosion resistance, and the Mo-based materials of which corrosion resistance would be improved by the MoSi2 coating among the metals. For the Cr2O3-based ceramics, materials were fabricated by the hot press process, and their corrosion resistance against the molten coal ash was examined. As a result, the simple Cr2O3 showed remarkably poor degree of sintering, but significantly dense test specimens were obtained from the Cr2O3-Al2O3-based materials. It was provided that a part of these has excellent corrosion resistance. However, further investigation would be still required to determine the optimum composition and the fabrication process. For the Mo-based metal materials, Mo(Al-Si)2 coatings with excellent corrosion resistance were fabricated by dipping them in the Al-Si melting solution, which is called the dip coating method. It was found that the amorphous SiO2, which has excellent resistance to oxidation, became very stable by the presence of aluminum. 18 refs., 73 figs., 21 tabs.

  6. Achievement report for fiscal 1998. Research and development of super-functional environment-resistant materials by controlling trace metal ion implantation; 1998 nendo seika hokokusho. Gokubiryo kinzoku ion chunyu seigyo ni yoru chokino taikankyo zairyo no kenkyu kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    The aim was to develop reliable materials high in resistance to hostile environments, greatly improved in their resistance to oxidation, abrasion, and corrosion at high temperatures. To achieve the goal, trace quantities of high melting point metals were implanted into the compound formed on the substrate surface or deep into the substrate material. This year's research and development is outlined below. Important technologies in the ion process involved materials which at high temperatures were very resistant to oxidation, abrasion, and corrosion. The high-temperature oxidation resistant material was studied for use with the automobile supercharger rotor. The study on the high-temperature abrasion resistant material involved Ti-N thin coatings: the optimization of coating conditions, slidability at room temperature, and slidability in a high-temperature atmosphere. As for the high-temperature corrosion resistant material, studies were made to use it for refuse-fueled power generation. The TiAl material was also studied: the effect of ion implantation on the improvement of its high-temperature oxidation resisting capability, analysis into oxidized alloy surface properties, ion implantation into complicatedly shaped items and the optimum material for them, and the surface treatment by ion beams for improving resistance to high-temperature corrosion. (NEDO)

  7. FY 1993 Report on the industrial science and technology research and development project results. Research and development of non-linear photoelectronic materials; 1993 nendo hisenkei hikari denshi zairyo no kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-11-01

    Described herein are the results of the industrial science and technology research and development project for nonlinear optoelectronic materials. The more functional chiral and pi-conjugated compounds are investigated as the organic, low-molecular-weight materials. The technologies for the orientation-controlled crystal growth are continuously investigated. Polyacetylene is investigated as the conjugated pi-electron system. The glass-dispersed systems, prepared by the sol-gel, superlow-melting glass and super-cooling methods, are investigated. In order to elucidate the relationship between the organic superlattice and properties (e.g., photoelectronic properties), the intramolecular interactions under the superlattice conditions are estimated by the theoretical chemical calculations, and the optimum structures deduced from the measured properties are proposed. The thin, composite films of fine metallic particles and glass are prepared by the multi-dimensional sputtering, to explore the constituent materials suitable for the three-dimensional superstructures, and their properties are analyzed. The thin semiconductor films of superlattices are prepared by the molecular beam epitaxy method, to investigate the optimization of the structures and compositions. The basic aspects of the three-dimensional superstructures, prepared by the superfine machining, are investigated. The results of the comprehensive investigations and researches are also described. (NEDO)

  8. Fiscal 1998 international research cooperation project. Research report on development of ultra-solid lubricant with cluster diamond; 1998 nendo kokusai kenkyu kyoroku jigyo seika hokokusho. Kurasuta diamond wo riyoshita kotai junkatsu fukugo zairyo no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Study was made on cluster diamond-dispersed composite materials to develop advanced ultra-solid lubricant. As for processing technology of such composite materials, study was made on the uniform mixing condition of cluster diamond and Cu or Cu-Sn alloy by mechanical milling. The fabricated composite powder was caked by vacuum hot compressive formation technique. The production process of composite materials composed of cluster diamond and TiO{sub 2} was also developed by using sol-gel technique. As for formation of a functional layer and development of micro- formation technology, the prototype forming equipment using radial extrusion process and the mould were designed and prepared. In the preliminary experiment only for matrix, study was made on working limit, material flow, fine recrystallization and working condition during working. The friction test result showed the antifrictional property of the cluster diamond-dispersed composite materials using Cu, Cu-Sn, Al, Al-Si as matrix. (NEDO)

  9. Report for fiscal 1998 on results of research and development of silicon-based polymeric material. Material research for the liquid methane fueled aircraft engine; 1998 nendo keisokei kobunshi zairyo no kenkyu kaihatsu seika hokokusho. Methane nenryo kokukiyo engine kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Research was conducted for the purpose of establishing basic technology concerning molecular design, synthesis, material formation, and evaluation of silicon-based polymers which are expected to provide superior electronic/optical functions, high heat/combustion resistance and dynamic properties. The research subjects were such as following: research and development of silicon-based polymeric materials with sea-island microstructures; research and development of silicon-based polymeric materials with sea-island microstructures; research and development on IPN formation with silicon-based polymers; research and development of hybrid silicon polymers with organometallic compounds; research and development of silicon containing polymer materials with ring structures; general committee for investigation and research; the optimized low-temperature Wurtz synthesis and modification of polysilanes; study of unsaturated and hypercoordinate organosilicon compounds; basic studies on the synthesis and properties of silicon-based high polymers; studies of new monomer-synthesis and their polymerization reaction; studies on new method of preparation and functionalization of polysilanes; novel applications of silicon-based polymers in imaging devices for information display, memory, and recordings; and molecular design of silicon-containing {pi}-conjugated and {sigma}-conjugated compounds. (NEDO)

  10. Design of environment-friendly and next generation-type conversion system for unused carbon resources by developing highly functional materials; Kokino zairyo kaihatsu ni yoru kankyo chowagata jisedai miriyo tanso shigen tenkan system no kochiku

    Energy Technology Data Exchange (ETDEWEB)

    Wakabayashi, K.; Morooka, S.; Arai, Y. [Kyushu University, Fukuoka (Japan). Faculty of Engineering; Sakanishi, K. [Kyushu University, Fukuoka (Japan). Institute of Advanced Material Study

    1997-02-01

    Studies are conducted for the development of now-unused kinds of fossil carbon resources, such as low rank coal and heavy gravity crude oil, into higher-value liquid fuel. In the preliminary treatment process, the fossil carbon resources are dried by use of supercritical carbon dioxide, when it is found that the resources are disintegrated and water is desorbed. In a low rank coal liquefaction process using the NiMo/KB (Kefjen Black) catalyst, more than 60% is converted into oil, which rate is improved by use of the dual-temperature liquefaction process. This catalyst may be recovered by separation utilizing specific gravity difference. As a low temperature gasification catalyst, the alkaline carbonate-carried carbon catalyst is very quick at the initial stage of reaction. The perovskite-carried alkaline carbonate catalyst is high in carbon oxidizing/activating efficiency at low temperatures. The silica film deposited on an alumina-coated support tube is excellent in selectivity and speed as a hydrogen separating film, and a carbonized polyimide film as a carbon dioxide separating film. For the supercritical phase adsorption/separation of chemicals not to be distilled easily, the NaY-type zeolite functions effectively. Pd/ZrO2 serving as a carbon monoxide conversion catalyst enables the recovery of more MeOH when Pd grains are smaller in diameter.

  11. Improvement of low temperature oxidation resistance in MoSi{sub 2}-oxides composites; Sankabutsu no fukugoka ni yoru MoSi{sub 2} zairyo no teion sanka tokusei no kaizen

    Energy Technology Data Exchange (ETDEWEB)

    Jiang, W.; Uchiyama, T. [Riken Corp., Saitama (Japan)

    1999-11-15

    MoSi{sub 2}-oxides composites using fine aluminosilicate powder (< 0.2{mu}m) have demonstrated excellent low temperature oxidation resistance and thermal shock resistance. These properties strongly depend on microstructural morphology and are obtained in composites that network-structures of both phases of MoSi{sub 2} and oxides are developed, i.e., in composites with oxides of 20 {approx} 40 vol. %. When one phase is independently dispersed in the other phase, on the other hand, problems of low temperature oxidation and thermal shock occur. The low temperature oxidation problem occurs in the composites with oxides less than 15 vol. % and the thermal shock problem occurs in the composites with oxides more than 50 vol. %. These results will contribute to material design approaches for high temperature structural applications of MoSi{sub 2}. (author)

  12. Fiscal 1992 R and D project for next generation infrastructure technology. Report on results of R and D on silicon-based polymeric material; 1992 nendo keisokei kobunshi zairyo no kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1993-03-01

    R and D was conducted with the purpose of establishing fundamental technologies for molecular design, synthesis, material formation and evaluation method concerning silicon-based polymer. with the fiscal 1992 results summarized. In the studies on synthesis technology of electrically conductive silicon-based polymeric materials, silicon-based compounds were synthesized including in particular -Si-Si- bond and carbon multiple bond like -C-C-, with acquisition/analysis of material data started. In the studies on new silicon-based polymeric materials capable of circuit plotting, syntheses were performed for network polysilanes through the disproportionation reaction of alkoxydisilanes. In the studies on new silicon-based polymeric materials having a light emitting function, evaluation of oxidation-reduction potential and search for synthesizing conditions were performed for halosilanes and hydrosilanes. In the studies on silicon-based photoelectric conversion materials, molecular design progressed using a crystal orbital method. Furthermore, researches were implemented on such subjects as silicon-based polymeric materials having a sea-island structure, interpenetrating polymer network forming technologies, and composite structural materials composed of organic metallic complex and silicon-based polymers. (NEDO)

  13. Fiscal 1993 R and D project for industrial science and technology. Report on results of R and D on silicon-based high polymer material; 1993 nendo keisokei kobunshi zairyo no kenkyu kaihtsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-03-01

    R and D was conducted on the silicon-based high polymer that are hoped for superior electronic/optical functions and heat/flame-resistant dynamical properties, for the purpose of establishing fundamental technologies such as molecular design, synthesis, material forming and evaluation method, with the fiscal 1993 results summarized. In the synthesis of electrically conductive silicon-based polymeric materials, a concept of indirect doping was presented, revealing that workability and electrically conductive properties were enhanced by additives. In the synthesis of new silicon-based polymeric materials capable of circuit plotting, studies were made on Si-Si bond forming reaction of alkoxydisilanes as well as on the correlation between polysilane skeleton structure and its property. In the synthesis of new silicon-based polymeric materials having for example a light-emitting function, evaluation was made on synthesis and light emitting property concerning the compound that controlled the silicon skeleton structure. In addition, R and D was conducted on the precision synthesis technology of compounds, on which manifestation of photoelectric conversion function was expected. Further, research was done on unsaturated and high coordination organosilicic compound, functionality of silicon-based high polymer, and synthesis/polymerization of silicon monomer. (NEDO)

  14. Research and development project in fiscal 1989 for fundamental technologies for next generation industries. Achievement report on research and development on high-efficiency polymer separating film materials; 1989 nendo kokoritsu kobunshi bunrimaku zairyo no kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1990-03-01

    With an objective to improve efficiency and energy conservation in separation processes used in the chemical industry, researches have been performed on high-efficiency liquid separating film and air separating film materials. This paper summarizes the achievements in fiscal 1989. With regard to molecule recognizing films, researches were made on oxygen and carbon monoxide carriers, and on the elementary technology for fabricating the carrier films. In the research of metal complex fixing thin films, discussions were given on causes for deactivation in complex films. In the research of high-functional complex films, discussions were given on the structure of polymer ligand/carrier complex system solid films, and on oxygen adsorption and desorption properties. Solid film structures were selected that suit the oxygen separating films. In the research of alcohol condensation films, discussions were given on polydimethylsiloxane constituent that shows ethanol selectivity and permeability, and a multi-phase system polymeric film composed of one other constituent. In the research of water-acetic acid separating films, the basic performance of polyurea film was discussed, and evaluation was given by means of a durability test. In the research of particle separation method utilizing liquid films, a prototype continuous particle separating device was fabricated. (NEDO)

  15. FY 1990 Report on the results of the research and development project for the industrial base technologies of the next generation. Research and development of nonlinear optoelectronic materials; 1990 nendo hisenkei hikari denshi zairyo no kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1991-03-01

    Described herein are the FY 1990 results of the research and development project for the optoelectronic materials, implemented to cope with the highly information-oriented societies. The FY 1990 is the second year for the phase-I project of the basic plan, and the R and D efforts are directed to elucidation of the mechanisms involved in the nonlinear phenomena, exploration and designs of various materials, and investigations of the technologies for, e.g., the material synthesis and evaluation. The themes to be investigated by the long-term project include exploration and preparation of the superfine particles and base materials for the organic materials; and crystal growth, dispersion of the fine particles and development of the superlattices for development of the materials. The comprehensive investigation and research program investigates the trends of the related technologies, both domestic and foreign. A total of 9 research themes are recommissioned to 9 enterprises. They include organic, low-molecular-weight materials, growth of orientation-controlled crystals, films of high-molecular-weight organic conjugated compounds, glass-dispersed materials (prepared by the vapor-phase, impregnation of porous glass, sol-gel, superlow-melting glass and super-cooling methods), organic dispersed materials, development of the organic superlattices, and development of the three-dimensional superstructures. (NEDO)

  16. FY 1997 report on the study on development of corrosion-resistant ceramics for refuse incinerators; 1997 nendo chosa hokokusho (gomi shokyakuroyo taishoku ceramics zairyo no kaihatsu ni kansuru kenkyu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    This paper describes development of structural materials for municipal refuse incinerators, in particular, high- temperature corrosion-resistant ceramics for inner walls. Unlike boiler tubes of which inner walls are cooled by water or water vapor, refractory for inner walls is subjected to high-temperature flame over 1000degC, corrosive gases such as HCl and SO2. and low-melting point corrosive dust such as chloride, sulfate and oxide under strong corrosive environment. Experiment was made on 14 kinds of ceramics including commercially available oxide system, non-oxide system and refractory system ceramics. Except graphite system ones, every ceramics, in particular, Al2O3, ZrO2, B4C-doped SiC and CVD-SiO showed superior properties. Commercially available ceramics, in particular, non-oxide system ones are very expensive. Since inner wall materials for refuse incinerators are heat-/corrosion-resistant consumption articles, it is suggested that improvement of reasonable oxide system ceramics or conventional SiC system ones is better. 73 refs., 89 figs., 39 tabs.

  17. Development of a readily recyclable sound insulation material made of polyester fibers. Application of the PET fibers from plastic bottles; Recycle kanona jidoshayo polyester sei kyuon zairyo no kaihatsu. Shiyozumi pet bottle zai no insulator zai eno tekiyo

    Energy Technology Data Exchange (ETDEWEB)

    Nemoto, K.; Watanabe, K.; Sugawara, H.; Minemura, Y. [Nissan Motor Co. Ltd., Tokyo (Japan)

    1997-10-01

    We have developed new polyester sound-absorbing materials made of fine and modified-cross-section polyester fabric. They provide noticeably higher sound-absorbing performance than traditional materials. Another feature of the new materials is their excellent recyclability since they are made of polyester. Application of the new materials to the dash silencer and the floor carpeting produced a great improvement in sound-insulation performance with less weight. 2 refs., 7 figs.

  18. Ultimate evaluation report on research and development of basic technologies for next-generation industry. Conductive polymeric materials; Jisedai sangyo kiban gijutsu kenkyu kaihatsu saishu kenkyu kaihatsu hyoka. Dodensei kobunshi zairyo

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1991-05-01

    Basic technologies are established that equip polymeric materials (insulators in general) with conductivity similar to that of metals for the realization of novel conducting materials characterized by light weight, high resistance to corrosion, and ease of machining, and for the manufacture of novel electrical/electronic materials having new functions different from those of conventionally used metals. The aims are to realize a conductivity of 10{sup 5}S/cm or more, to manufacture materials sufficiently stable when left in the ordinary or inert atmosphere, and to manufacture materials which may be machined into proper shapes as required in the industry. The results of the 10-year-long development endeavor greatly contribute to the creation of high-level materials, the systematization of technologies, and the elucidation of the conducting mechanism. In relation to polymeric materials, in particular, a new technology is developed that equips, with high reproducibility, polymeric materials with conductivity similar to that of silver or copper; a graphitic material is created for the first time provided with conductivity superior to that of metals; and conducting polymeric materials are equipped with an easy-to-machine feature. A great contribution is accomplished to the production of superconductivity in organic charge-transfer complex crystals and to the elucidation of the conducting mechanism. (NEDO)

  19. Development of a high temperature electric resistance measuring apparatus and the applications to measurements for carbon materials. Koon denki teiko sokutei sochi no shisaku to tansokei zairyo eno oyo

    Energy Technology Data Exchange (ETDEWEB)

    Sato, S.; Kurumada, A.; Kawamata, K. (Ibaraki University, Ibaraki (Japan). Faculty of Engineering); Sasaki, T.; Shibano, M. (Ibaraki University, Ibaraki (Japan))

    1990-12-20

    A trial fabrication was done to build a vertical type high temperature electric resistance measuring apparatus utilizing an ultra high temperature electric furnace using graphite as a heater for the purpose of studying application of carbon materials under ultra high temperatures. Electric specific resistance was measured on carbon materials to a temperature of up to 2,400 {degree}C. The test pieces are of composite material composed of fine grain isotropic graphite, electrode graphite for steel furnace made by Arc, and C/C. The electric resistance was obtained using a voltage drop method at a reference current of 100 mA, and the specific resistance was calculated using the test piece diameter and the distance between electrodes. The temperature was raised at a rate of 550-600 {degree}C/h. All the graphite materials have their own individual values of electric specific resistance at the room temperature. As the temperature is raised, the specific resistance decreases, shows a minimum value, and then increases gradually showing a nearly constant increase rate until the temperature approaches the graphitization temperature of 3000 {degree}C. At low temperatures, the current carrier mobility is constant, but at higher than the normal temperature, mobility reducing speed becomes dominant because of heat excitation scattering, which is believed to increase the electric specific resistance. 5 refs., 12 figs., 5 tabs.

  20. Mixture of industrial waste oxidized titanium and reduced slag from electric furnace used as hydraulic material. Denkiro kangen slug to sanka titan kogyo haikibutsu no kongobutsu no suinan zairyo to shiteno riyo

    Energy Technology Data Exchange (ETDEWEB)

    Honda, A. (Osaka City University, Osaka (Japan). Faculty of Engineering); Kuwayama, T. (Daido Institute of Technology, Nagoya (Japan)); Yamada, M.; Ikezaki, H. (Osaka City University, Osaka (Japan). Faculty of Engineering)

    1990-10-29

    Slag released from an electric furnace consists mainly of waste steel. There are two types of slag, namely, oxidized slag and reduced slag. Reduced slag, which is generally in the form of powder, is difficult to recycle as compared with oxidized slag. However, with a hydraulicity, some reduced slag is expected to be useful as hydraulic material. Test results obtained here show that the hydraulic properties of reduced slag powder can be improved by mixing it with gypsum and that the resultant mixture can serve to improve the prooperties of soft clay. Another study is made to determine the potential, as hydraulic material, of mixtures of reduced slag powder and waste gypsum material with a high gypsum content released from an oxidized titanium production process. The hydraulicity is found to develop as a result of the formation of a hydrate of calcium aluminate which is contained in the slag. Addition of water to the hydrate and gypsum cause the formation of ettringite, leading to an increased uniaxial compressive strength. These findings indicate that the above-mentioned mixture can be useful to improve the hydraulic properties of coal ash to be disposed of at landfill sites. 5 refs., 5 figs., 1 tab.

  1. FY 1992 Report on the results of the research and development project for the industrial base technologies of the next generation. Research and development of nonlinear optoelectronic materials; 1992 nendo hisenkei hikari denshi zairyo no kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1993-03-01

    Described herein are the FY 1992 results of the research and development project for the optoelectronic materials. The FY 1992 is the last year for the phase-I project of the basic plan, and the results are evaluated mainly viewed from extent of attainment of the interim targets. For the organic materials, the highly unique chiral nonlinear compounds are further developed, and direction for the investigations of the conjugated low-molecular-weight compounds is established. The excellent high-molecular-weight films are developed. For the dispersed materials, those developed include CuCl-dispersed glass, CdTe laminated glass developed by the laser evaporation method, glass dispersed with semiconductors at high concentrations, and dispersed materials with high-molecular-weight materials as the matrices. For the material development, those technologies investigated are orientation controlling of the crystals for thin organic films, and development of superlattices. A total of 9 research themes are recommissioned to 9 enterprises. They include organic, low-molecular-weight materials, growth of orientation-controlled crystals, films of high-molecular-weight organic conjugated compounds, glass-dispersed materials (prepared by the vapor-phase, impregnation of porous glass, sol-gel, superlow-melting glass and super-cooling methods), organic dispersed materials, development of the organic superlattices, and development of the three-dimensional superstructures. (NEDO)

  2. Research and development of photovoltaic power system. Study on structural defects in silicon-based amorphous materials; Taiyoko hatsuden system no kenkyu kaihatsu. Amorphous silicon kei zairyo no kozo kekkan ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Shimizu, T. [Kanazawa University, Ishikawa (Japan). Faculty of Engineering

    1994-12-01

    Described herein are the results of the FY1994 research program for structural defects of silicon-based amorphous materials for solar cells. The study on light generation defects of the a-Si:H system and rejuvenation process by annealing establishes the effects of light irradiation time on changed neutral dangling bond density as a result of light irradiation at varying temperature of 77K, room temperature and 393K. The study on annealing to rejuvenate light generation defects of various types of a-Si-H systems establishes the activation energy distribution with respect to annealing to remove light-induced defects, showing that hydrogen affects the distribution of light-induced defects. The study on decaying process of light-induced ESR for undoped and N-doped a-Si:H systems observes the decaying process of light-induced ESR, after light is cut off, extending for a period of several seconds to several hours at 77K for the a-Si-H systems containing N in a range from 0 to 12at%. The other results presented are space distribution of neutral defects of light-irradiated a-Si-H systems, and rejuvenation process of light-induced spin for the a-Si(1-x)N(x):H composition. 6 figs.

  3. Achievement report on research and development of the industrial basic technologies of the next generation in fiscal 1981. Research and development of composite materials; 1981 nendo jisedai sangyo kiban gijutsu itaku kenkyu kaihatsu seika hokokusho. Fukugo zairyo no kenkyu kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1982-03-01

    Described herein are the results of the FY 1981 research and development for composite materials, established by the R and D system for the basic technologies of the next generation. The R and D project for resin-based composite materials involves basic researches on the matrix resins, and surface modification of the reinforcing fibers. The investigations and basic tests are conducted for monolithic molding, other types of molding, and cutting and boring by, e.g., laser beams and water jet. The other related efforts include researches on analysis theories for optimization of strength and rigidity of the composite structures, and development of the optimization programs. For the R and D project for the metal-based composite materials, the efforts are directed to understanding wettability and reactivity of the reinforcing fibers with metals, and development of the techniques for producing various types of preforms and compositing methods. The basic researches are conducted for hot pressing/rolling molding, extrusion/withdrawal, powder molding and melt molding of the composite materials with aluminum alloys as the matrices. The other R and D items include investigations on methods for evaluating qualities for the steps form the stock preparation to production of the final products. (NEDO)

  4. Cryogenic mode 2 interlaminar fracture toughness of glass-cloth/epoxy; Tanmen kikaki mage shiken ni yoru orimono garasu-epokishi sekiso zairyo no goku teion modo 2 sokan hakai jinsei

    Energy Technology Data Exchange (ETDEWEB)

    Shindo, Y.; Kudo, H.; Horiguchi, K. [Tohoku University, Miyagi (Japan)

    1999-11-10

    With the extension of superconductive application and application to the space science and technology, the fiber reinforced plastics laminated material would be used under the severe environment of the very low temperature. And, the laminated material, since the intercalation strength is low, it is important to evaluate characteristics of generation and progress of the delamination crack, and it is an urgent problem. Using the end face notch test piece for bend test of SL-E, this study carried out the mode 2 interlaminar fracture toughness test at room temperature, 77K and 4K, and it clarified the effect of specimen configuration and test temperature in search of initial mode 2 interlaminar fracture toughness peeling crack growth. (NEDO)

  5. Proceedings of the Spring Meeting of the Society of Naval Architects of Japan (1996). Part 2. Structure, materials, welding, construction, and design; Nihon zosen gakkai (1996 nen) shunki koen ronbun maezuri. 2. Kozo, zairyo, yosetsu, kosaku, sekkei

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-12-31

    This is a proceedings of the Spring Meeting of the Society of Naval Architects of Japan made public on May 15 and 16, 1996. In the basic research, the following are included: Basic studies on computer aided concurrent engineering for hull structure design and piping design; Fundamental study on the new method to estimate vibration level on a ship; Flat plate approximation in the three-dimensional slamming; Development of new finite element by source method, etc. As to fracture and cracks, Equivalent CTOD concept based on the local approach and its application to fracture performance evaluation of welded joints; Fracture mechanical modeling of brittle crack propagation and arrest of steel; An evaluation method for ductile crack propagation in pre-strained plates; Multiple fatigue cracks propagating in a stiffened panel, etc. Relating to fatigue strength, Fatigue life estimation of welded joints of an aluminum alloy under superimposed random load waves; Study on unified fatigue strength assessment method for welded structure, etc.

  6. Proceedings of the papers read in the 47th Science Lecture Meeting of the Society of Materials Science, Japan; Nippon Zairyo Gakkai dai 47 ki gakujutsu koenkai koen ronbunshu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-05-21

    As to the evaluation and analysis of organs and strength at high temperature, papers were reported on high temperature reformation behavior, damage models and analysis/evaluation, long-time creep fatigue, fatigue strength, fatigue crack development, microstructures of super alloys/composite materials, high temperature characteristics of ductile materials, etc. Relating to the materials database related to phase transformation and its application to simulation, reported were quenching, phase transformation behavior and structural formulas, concrete, polycrystal reformation, timber and dynamics, analysis of composite materials, etc. Concerning strength characteristics and evaluation of surface reforming materials, papers on abrasion, thin films, monocrystal, grain boundary, corrosion, etc. About the design/evaluation of ceramic materials, the sintering process, reformation/fracture behaviors and their simulation, strength characteristics of composite ceramics, fatigue, evaluation of superconduction characteristics, etc. The paper also described composite materials/organism use materials, polymer, magnetic materials, etc. As the impact behavior of materials/structures, reported were impact pressure welding, impact loads, fatigue/fracture of composite materials, thermal analysis, etc. From time to time, measuring methods were also reported

  7. Fiscal 1992 R and D project for next generation infrastructure technology. Report on results of R and D on photo-reactive material; 1992 nendo hikari hanno zairyo no kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1993-03-01

    R and D was conducted with the purpose of establishing fundamental technologies concerning photo-reactive materials, which control molecular structures or polymerization through light beam behavior and which can be used for ultra-high density optical recording, high resolution display, optical switch, etc., with the fiscal 1992 results summarized. In the studies on photochromic materials, investigation was carried out on the possibility of 10 multiple recording and the fundamental features of aggregate forming photochromic compounds. In the studies on high temperature of photochemical hole burning (PHB) materials, a material was synthesized using ionic porphyrin derivatives as guest material and deuterated polyvinyl alcohol (PVA) and the like as host, with the evaluation made on the performance of multiple hole formation and storage. In addition, comparisons were made for example on the thermal properties of the PHB materials among the participating enterprises mutually. In the development of chinone PHB materials and research on the improvement of the multiplicity, as this being the final year, researches were done on such subjects as integration of element technologies, material evaluation technology and PHB-related studies, correlatively as the work of the final year. Research results were also reported on the development and systematizing technology of porphyrin-based PHB materials. (NEDO)

  8. Application of resin lining system for countermeasures for preventing leakage from openings in low temperature materials storage; Teion busshitsu chozoji no ekimore oyobi reiki more taisaku toshite no kobunshikei zairyo no tekiyosei

    Energy Technology Data Exchange (ETDEWEB)

    Inada, Y. [Ehime Univ., Ehime (Japan). Faculty of Engineering; Seki, S.

    1996-12-21

    Recently, many of the low temperature materials such as LNG and LPG used as an energy substitution for petroleum were stored in the reclaimed land of the sea side district, however, it is necessary for those storage methods to enlarge sites. Therefore, it was considered to directly store the low temperature materials in openings excavated in the rock mountains. However, countermeasures for leakage of liquid and cold gas from cracks in openings would be an important subject. In this study, as a countermeasure for leakage of liquid and cold gas in the case in which low temperature materials were stored in openings in the rock mountains, the lining of resin materials on the surface of openings was proposed. Characteristics of strength and deformation and values of the thermal physical properties for the resin materials at the low temperature were obtained by experiments. This material was compared with granite supposed as a parent rock, and the thermal property of the resin materials was understood. Next, an analysis was conducted in the case of using the resin materials as a lining, the behavior of the surrounding rocks of the openings and the stability of the lining were investigated. 17 refs., 25 figs., 2 tabs.

  9. Research and development project in fiscal 1989 for fundamental technologies for next generation industries. Achievement report on research and development on electrically conductive polymeric materials; 1989 nendo dodensei kobunshi zairyo no kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1990-03-01

    With an objective to develop electric and electronic materials characterized by light weight, high corrosion resistance, and easy-to-process performance, and by having functions different from electricity conduction mechanism of metals, researches have been performed on fundamental technologies for electrically conductive polymeric materials. This paper summarizes the achievements in fiscal 1989. In new hydrocarbon conjugate polymers, researches were performed for the purpose of fabricating the conjugate system polymer and dopant complex system conductive thin films, and polyacene system polymer thin films. In developing the vehicular conjugate conductive materials, discussions were given on enhancing the molecular weight dependence and the conductivity by cross-linking the conjugate system, with regard to hydrocarbon system polymers that go through vehicular polymeric intermediates. In the research of vehicular graphite materials, it was discovered that mono-axial mono-plane PPV films and PTV films are graphitized. In developing the hetero aromatic system polymers, researches were advanced on the correlation among the gegen ions, high-order structures, and electric conductivity, mainly on polypyrrole. (NEDO)

  10. Fiscal 1997 project on the R and D of industrial scientific technology under consignment from NEDO. Report on the results of the R and D of technologies to invent original high-functional materials (development of precise structure control materials for enhancement of oil refining); 1997 nendo sangyo kagaku gijutsu kenkyu kaihatsu jigyo Shin Energy Sangyo Gijutsu Sogo Kaihatsu Kiko itaku. Dokusoteki kokino zairyo sosei gijutsu no kenkyu kaihatsu (sekiyu seisei kodoka seimitsu kozo seigyo zairyo kaihatsu) seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    The paper described the R and D of technologies for creating original high-functional materials under the R and D system of industrial scientific technology. Japan chemical Innovation Institute (JCII) is conducting intensive joint researches under consignment from NEDO with private companies, universities and national research institutes. Among those, the paper reported the fiscal 1997 results of the following two researches conducted as development of precise structure control materials for enhancement of oil refining: precision catalytic polymerization and multi-dimensional space polymer. As to the precision catalytic polymerization, the paper is aimed at developing base technologies for the molecular weight and stereoregularity by which remarkable improvement in performance of addition polymerization type polymer can be expected, and on the development of a polymerization catalyst which arbitarily controls the primary structure such as end group structure and of a precision addition polymerization process. Subthemes are addition polymerization with limit and oriented catalytic polymerization. In relation to multi-dimensional space polymer, the paper is aimed at developing highly selective polymerization technology of aromatic compounds using enzyme related catalysts and synthesis technology of regular structure polymer, and synthesis technology of new polymer group having a new chain pattern except covalent bond/new polymer group having characteristics in three-dimensional space geometric structure. 244 refs,, 160 figs., 94 tabs.

  11. Fiscal 1997 R and D project on industrial science and technology under a consignment from NEDO. R and D of the application technology of functional protein complex (R and D of the high-functional maintenance technology for power plants); 1997 nendo sangyo kagaku gijutsu kenkyu kaihatsu jigyo Shin energy Sangyo gijutsu Sogo Kaihatsu Kiko itaku. Kinosei tanpakushitsu shugotai oyo gijutsu no kenkyu kaihatsu (hatsuden shisetsuyo kokino maintenance gijutsu kaihatsu) seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    In order to develop advanced maintenance technology for power generation facilities, application technology of functional protein complexes is under investigation. On a light controllable enzymatic reaction system, construction of a light controllable bio-reactor by physico-chemical and bio- chemical techniques, and structure and functions of a photosynthetic protein complex using thermophilic cyanobacteria as material are under investigation. On a molecular mechanism for recognition and reaction of receptor proteins, structure analysis and engineering application of glutamate receptor channels of a synaptic transmission system, and basic study and material proteins for artificial structures using endocytic micromachinery, and a multi-enzyme system for synthesis of glycosphingolipids are under investigation. On a complex oxidation/reduction system by genetic engineering technique, construction of a high- efficiency stable system with functionally arranged oxidoreductase and electron transmission systems in biomembranes is in promotion. Research work was also made on molecular assemblies for a functional protein system. 166 refs., 91 figs., 9 tabs.

  12. Achievement report for fiscal 1997. Technological development for practical application of a solar energy power generation system /development of technology to manufacture solar cells/development of technology to manufacture thin film solar cells (development of technology to manufacture materials and substrates (development of technology to manufacture silicon crystal based high-quality materials and substrates)); 1997 nendo taiyoko hatsuden system jitsuyoka gijutsu kaihatsu seika hokokusho. Taiyo denchi seizo gijutsu kaihatsu, usumaku taiyo denchi seizo gijutsu kaihatsu, zairyo kiban seizo gijutsu kaihatsu (silicon kesshokei kohinshitsu zairyo kiban no seizo gujutsu kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    It is intended to develop thin film solar cells capable of mass production with high photo-stability and at low cost. Thus, the objective of the present research is to analyze the growth process of micro crystal silicon based thin films, the crystal being a high quality silicon crystal based material, and develop technology to manufacture high-quality micro crystal silicon thin films based on the findings therefrom. It was found that, when silicon source is available in cathode, pure hydrogen plasma forms micro crystal silicon films by using the plasma as a result of the chemical transportation effect from the silicon source. It was revealed that the crystal formation due to hydrogen plasma exposure is performed substantially by the crystals forming the films due to the chemical transportation effect, rather than crystallization in the vicinity of the surface. The crystal formation under this experiment was concluded that the formation takes place during film growth accompanied by diffusion of film forming precursors on the surface on which the film grows. According to the result obtained so far, the most important issue in the future is particularly the control of crystal growing azimuth by reducing the initially formed amorphous layer by controlling the stress in the initial phase for film formation, and by controlling the film forming precursors. (NEDO)

  13. Fiscal 2000 research achievement report on the development of super-advanced liquid crystal technology for energy use rationalization. Development promotion project for super-advanced electronic technology - Design, control, analysis, etc., of electronic materials having novel functions; 2000 nendo energy shiyo gorika chosentan ekisho gijutsu kaihatsu seika hokokusho. Chosentan denshi gijutsu kaihatsu sokushin jigyo (shinkino denshi zairyo sekkei seigyo bunseki nado gijutsu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-04-01

    Efforts are focused on the verification of target devices under the respective subjects, and activities are conducted with the development system reinforced. Three newly proposed reflection type liquid crystal devices achieve the target specifications of a reflection factor of 60% or higher and a contrast ratio of 15:1 or higher. Studies are conducted involving the five fields of (1) multilayer reflection devices, (2) memory retention liquid crystal devices, (3) single pixel color devices, (4) directional reflection devices, and (5) joint research. Research and development in field (1) covers ultra-anisotropic optical materials, ultrahigh reliability host liquid crystal materials for guest-host liquid crystals - mixed system, low voltage driven/high load holding liquid crystal compound systems, and new liquid crystal molecule orientation control technology; in field (2), low temperature fabrication of ferroelectric thin film, and ultrahigh purity high reliability liquid crystal compounds; in field (3), materials capable of controlling optical interference and higher order light scattering, photoregulation devices, highly birefringent liquid crystal materials - mixed system, and ultrahigh efficiency light scattering liquid crystal compounds; and, in field (4), multi-dimensional anisotropic structure fabrication technology and ultra-anisotropic optical materials. (NEDO)

  14. Research and development of basic technologies for the next generation industries, 'light-reactive materials'. Evaluation on the first term research and development; Jisedai sangyo kiban gijutsu kenkyu kaihatsu 'hikari hanno zairyo'. Daiikki kenkyu kaihatsu hyoka

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1989-03-01

    Research, development and evaluation were performed with an objective of establishing the basic technology related to light-reactive materials that control the structures and status of aggregation of molecules by using actions of light, and can be used for ultra-high density recording, high resolution indication and light switches. In elucidating the mechanism of light deterioration reaction of photochromic molecules, it was disclosed that 6-nitrospirobenzopyran has the light deterioration caused from the excitation triplet state. This disclosure presents a possibility of preventing the light deterioration. New derivatives that show photochromism were synthesized, and thin films were produced by using the LB process. This indicates a possibility of producing the photochromic materials as the high multiplex recording material. With regard to PHB materials, an evaluation technology having spectrum resolution of the world's highest level was established and measurements were performed. Hole formation was verified for the first time in the world at the temperature higher than the liquid nitrogen temperature by using a PHB material of ionic porphin/polyvinyl alcohol systems. This verification indicates a feasibility of practically usable PHB materials. (NEDO)

  15. Fabrication of a Ti-Al2O3 functionally graded material by dry-jet spraying of ultrafine particles and subsequent temperature-gradient sintering; Chobiryushi funsha sekisoho oyobi ondo keisha fuka shoketsuho ni yoru Ti-Al2O3 keisha kino zairyo no shisaku

    Energy Technology Data Exchange (ETDEWEB)

    Otsuka, A.; Tanizaki, H.; Iwasaki, K. [Nisshin Steel Co. Ltd., Tokyo (Japan)

    1997-04-15

    Investigations are conducted and efforts are exerted for the prevention of some problems from arising in the process of sintering of films formed by dry jet spraying of ultrafine particles. Such problems involve the exfoliation of films from the substrate, emergence of voids in the functionally graded material (FGM) when the composition of the material is altered, and initiation of cracks. A Ti-Al2O3-base stepped cylinder shape FGM is tentatively fabricated by the lamination-forming ultrafine particle dry-jet spraying method and temperature-gradient sintering method. The occurrence of defects during the sintering process may be avoided by the following steps. Addition of ultrafine hydride particles to the powder which is to be compacted into a base substrate makes the shrinkage rate of this substrate slightly higher than that of the FGM layer, and this prevents cracks due to difference in shrinkage rate. The size of pores in the FGM can be reduced if the high shrinkage rate range r=1 through r=0.5 (r=Ti/(Ti+Al2O3)) is skipped in the laminate deposition process. When the compacting pressure is appropriately chosen after lamination, cracks are prevented from occurring in parts of extraordinary shape of the substrate before it is subjected to sintering. 7 refs., 10 figs.

  16. Research and development of basic technologies for next generation industries, 'high-efficiency polymeric separation membrane material'. Evaluation on first term final research and development; Jisedai sangyo kiban gijutsu kenkyu kaihatsu. Kokoritsu kobunshi bunrimaku zairyo (daiikki kenkyu kaihatsu hyoka)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1985-03-30

    The first term has performed research and development placing emphasis on that 'the basic study on membrane separation is to be performed systematically to elucidate governing factors in membrane separation'. With respect to water/ethanol separation by using the penetration gasifying method, it was indicated that excellent separation performance can be exhibited by using natural polymers having sugar chain skeleton as a raw material, and by controlling the membrane structure by means of membrane manufacturing methods. For enhancement of performance in water selective permeation type separation membrane, it was shown experimentally that it is important to select a membrane suitable for the object of separation and a separation method that uses the selected membrane. Regarding the water/ethanol separation, it was shown theoretically that the penetration gasifying method can save more energy than the conventional distillation method, where the development target was presented. It was recognized that impregnation type liquid membrane using crown ether can separate amino acid optical isomers. High separation performance was obtained in carbon monoxide/nitrogen separation by using fluid carrier that uses cuprous iodine/1-methyl imidazole. (NEDO)

  17. Study on high quality spectral materials for emitted soft X-ray. Special study on inorganic materials between FY 1991 and FY 1995; Hoshako nan X sen`yo bunko zairyo no kohinshitsuka ni kansuru kenkyu. 1991 nendo - 1995 nendo muki zaishitsu tokubetsu kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-11-28

    This is No.93 report of National Institute for Research in Inorganic Materials. Single crystal growth of YB66 was investigated to develop the single crystal of YB66 as a spectral material for synchrotron emitted soft X-ray. The emitted light is white light including from visible radiation to hard X-ray. Usually, it is used as homogeneous light through spectra. There are K-absorption edges of Mg and Si in the region ranging from 1 to 2 keV, which is significant for material science. There has been no proper spectral elemental device for application of the emitted spectra. The YB66 is the most suitable for this purpose. For the single crystal growth of high crystalline YB66, high frequency indirect heating floating method has been developed. For the growth furnace, a mechanism has been developed, by which pressurized gas atmosphere can be sealed with magnetic fluid. At the same time, the growth axis can be driven in high accuracy. From evaluation of the elemental device, energy resolution of 0.5{times}10{sup -3} was obtained as expected. By using this spectral device, accurate measurements of XAFS and EXAFS can be conducted with excellent operability for K-absorption edges of Mg and Si. 15 refs., 54 figs., 1 tab.

  18. Dynamic mechanical properties and interaction at the interface in poly (p-Phenylene terephthalamide) fiber reinforced poly (methyl methacrylate) composite; Sen'ijo pori (p-fuenirenterefutaruamido) wo kyokazai to suru porimetakuriru san mechiru tono fukugo zairyo no dorikigakuteki seishitsu to sozaikan sogo sayo

    Energy Technology Data Exchange (ETDEWEB)

    Goto, K. [JSR Corporation, Tsukuba (Japan). Tsukuba Research Lab.

    2000-01-15

    The dynamic mechanical properties of the composites of poly (p-phenylene terephthalamide) (PPTA) fibers (rigid molecules) and poly (methyl methacrylate) (PMMA) matrix (flexible molecules), were investigated as a function of the surface area of the fiber and temperature. These composites showed reinforcing effect indicated by the storage modulus (E') over the whole temperature range. At the temperature region of glassy state, E' was influenced by both the elastic modulus and the surface area of reinforcing fiber. However, at the temperature region of rubbery state, E' depended mainly on the surface area. Disappearance of {beta}-relaxation, that is attributed to rotation mode of the side-chain, and the shift of the higher temperature side of {alpha}-relaxation of main-chain of PMMA were observed in the PPTA composite with larger surface area. These results are attributed to an interaction at the PPTA/PMMA interface. Furthermore retardation of thermal decomposition of PMMA was observed in the presence of PPTA. It can be shown that the higher activation energy for the thermal decomposition of PMMA is equivalent to higher interaction energy in the PPTA composites. The shift of -NH, >C=O IR absorption band of benzanilide, a model compound of PPTA, with change in the PMMA composition proved that the interaction is chemically originated from the formation of hydrogen bond between PPTA and PMMA. (author)

  19. Research on the preparation of highly functional ceramics aiming at fusing together with living cells. Pt. 1. Application for biomaterial; Seitai saibo tono yugo ka wo mezashitaa kokinosei ceramics sosei gijutsu ni kansuru kenkyu. 1. Seibutesugakuteki shuho wo mochiita zairyo kaihatsu wo mezashit

    Energy Technology Data Exchange (ETDEWEB)

    Inagaki, H.; Maeda, S.; Kato, K.; Saito, T. [National Industrial Research Institute of Nagoya, Nagoya (Japan)

    2000-03-06

    We isolated the gene of Bone Morphogenic Proteins-1 (BMP-1) by RT-PCR (Reverse Transcriptase Polymerase Chain Reaction), and produced BMP-1 protein for the industrial application. We clarified theroles of BMP-2 and BMP-4, which are other members of BMPs, in cardiovascular formation at an early stage of embryo. In addition, we isolated a novel gene from bone mRNA and termed it rDLG-6. From the sequence comparisons by the BLASTX program, we found that rDLG 6 is a member of MAGUK (Membrane Associated Guanylate Kinase) family. (author)

  20. Fiscal 1999 phase 2 R and D report of WE-NET (International Clean Energy Network Using Hydrogen Conversion). Task 10. Development of low-temperature materials; 1999 nendo suiso riyo kokusai clean energy gijutsu (WE-NET) dainiki kenkyu kaihatsu. Task 10. Teion zairyo no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    This report summarizes the fiscal 1999 research result on material property test under liquid hydrogen environment, and development of optimum welding material and welding technique for the WE-NET plan. In the study on material properties in a liquid hydrogen temperature range, fatigue strength tests of base metals and weld metals were conducted under liquid hydrogen environment continuously, and further fatigue data were collected. As a result, it was clarified that both SUS304L and SUS316L have extremely high fatigue strength. To improve the tenacity of candidate weld metals under liquid hydrogen environment, material tests of welds were conducted on the laser-welded stainless steel joint and friction stir- welded Al alloy joint prepared by TWI (The Welding Institute) in the U.K. The laser-welded stainless steel joint showed higher low-temperature tenacity and lower ductility than TIG- welded joints. The friction stir-welded Al alloy joint showed extremely improved tensile strength and tenacity in a liquid hydrogen temperature range. For the low-temperature material database, both addition of new data and improvement of software were promoted. (NEDO)

  1. Achievement report on research and development of the industrial basic technologies of the next generation in fiscal 1985. Research and development of composite materials (Separate edition (1)); 1985 nendo jisedai sangyo kiban gijutsu itaku kenkyu seika hokokusho. Fukugo zairyo no kenkyu kaihatsu (bessatsu 1)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1986-03-01

    Described herein are the results of the research and development project for developing composite materials as the basic technologies of the next generation, for patent/utility application situations, know-how techniques, processing procedures, computer code lists, and database/file lists. A total of 81 inventions are applied for patents and 3 inventions for utilities, of which 8 inventions are applied to the foreign countries. The know-how techniques developed by the project include basic testers for continuous molding of closed sections, systems for continuously withdrawing the molded articles, hot rolling molding processes which use no rolling jigs, and HIP processes for aluminum-based powders. A total of 10 processing procedures are drawn, including those for monolithic molding of panel structures, monolithic molding of planar and angled PGI/CF, production of carbon fiber/aluminum-based wire reforms, pressing, rolling, HIP molding, and melt/extrusion molding. The computer code lists include strength/rigidity/vibration optimization programs, buckling optimization programs, and impact analysis/two-dimensional of the composite materials. (NEDO)

  2. FY 1998 annual summary report on International Clean Energy Network Using Hydrogen Conversion (WE-NET) system technology. Subtask 8. Development of hydrogen combustion turbine and ultrahigh-temperature materials; 1998 nendo seika hokokusho. Suiso riyo kokusai clean energy system gijutsu (WE-NET) subtask 8 (suiro nensho turbine no kaihatsu/chokoon zairyo no kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Summarized herein are the materials designs/production and tests/evaluation results of heat-resistant materials, i.e., alloys, ceramic composites and carbon-based composites, which are expected to be applicable to the hydrogen combustion turbines. These have been studied since 1993, and this paper summarizes the overall evaluation results of the phase I program. The intermetallic compound as one of the candidate materials has a high-temperature strength in a range from 1200 to 1400 degrees C by optimizing elements added. However, no prospect is obtained for heat resistance at 1700 degrees C or more for the material not coated or cooled moderately. Each of the other candidate materials tested shows a bright prospect of applicability at the base material and specimen levels. The single-crystal superalloy for hybrid cooling structures has novelty in that it is free of Cr but incorporated with Si and Hf, showing approximately 10 degrees C higher heat-resistant temperature than CMSX-4. CMC and C/C are inherently excellent heat-resistant materials, and are attractive advanced composites, because they are expected to realize no-cooled blades at 1700 degrees C. (NEDO)

  3. Preparation and oxidation resistance of carbon/ceramic composites prepared from phenolic resin, B(OH)3 and Si(OC2H5)4; Phenol jushi, B(OH){sub 3} oyobi Si(OC{sub 2}H{sub 5}){sub 4} wo mochiiru tanso/ceramics fukugo zairyo no chosei taisankasei

    Energy Technology Data Exchange (ETDEWEB)

    Ueno, S. [Industrial Tech. Center of Okayama Prefecture, Okayama (Japan); Kameda, K. [Nakamura Refactories Co. Ltd., Okayama (Japan); Yu, J.; Hiragushi, K. [Okayama Ceramics Research Foundation, Okayama (Japan); Miura, Y. [Okayama Univ. (Japan)

    1998-07-01

    For a binding agent of the carbon containing refractories, phenolic resin and pitch are widely used. Carbon forming by heat treatment of these binding agents has different crystallization and oxidation resistance due to kinds and additives of raw materials. In general, carbon obtained by thermal decomposition of phenolic resin has inferior crystallization and worse oxidation resistance to that from pitch. Conventionally, in order to provide oxidation resistance to carbon material, for example, a method to increase crystallization of the carbon material by adding B4C, a method of coating the carbon material with oxide system coating film and so on are investigated. In this study, for raw materials of carbon materials and coating film forming materials phenolic rein and B(OH)3 and Si(OC2H5)4 were used respectively to make organic/inorganic composites, to conduct their heat treatments at 1300-1900degC and to prepare carbon/ceramic composites. As a result of investigation on oxidation resistance and so forth of these composites, the composite was thought to be more effective than a method to graphitize carbon. 9 refs., 8 figs.

  4. FY 1998 report on the results of the international cooperation project, 'the joint R and D of the industrial base technology.' Development of functionally gradient materials; 1998 nendo sangyo kiban gijutsu kyodo kenkyu kaihatsu seika hokokusho. Keisha kinosei zairyo no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    For the purpose of developing the thermal stress relaxation type heat resistant large size bulk functionally gradient materials (FGM/LB) which are adaptable to high efficiency engine members, experimental researches were conducted, and the FY 1998 results were reported. As to the development of heat resistant use FGM/LB manufacturing technology, examinational researches were carried out on the dimensional evaluation of a spark discharge sintering method associated with the enlargement of the sintering process, examination of shape effect, examination of microstructures of large size sintered body, and mechanical properties. As a result of the study, FGM/LB sintered body was manufactured of diameter of 150mm which is composed of the ceramic simple substance material, metal simple substance material, and 9 layers of the intermediate gradient layer of the mixed material (11 layers in total). Concerning the development of large size FGM/LB evaluation technology, test pieces were manufactured of FGM/LB with diameter of 100mm and 150mm of ZrO2(3Y)-stainless steel base. The structural observation by SEM, hardness distribution measurement, etc. were conducted to get the basic property data. Moreover, to examine the heat resistant impact property, a test on thermal cycles was conducted. The occurrence of cracks was caught by AE sensor, and the correlation with heating temperature was studied. (NEDO)

  5. Achievement report for fiscal 1998 on the development of super-metal technology. Development of technology of high corrosion-resistance iron base controlled microstructure materials; 1998 nendo super metal no gijutsu kaihatsu. Kotaishokusei tetsukei bisai kozo seigyo kinzoku zairyo gijutsu no kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    During ultrafine structure formation due to transformation from austenite to ferrite in an intense magnetic field, the transformation is accelerated by the thermodynamic stabilization of the ferrite phase which is ferromagnetic. The application of an intense magnetic field works effectively during the generation of nuclei. When a magnetic field is applied during reverse transformation, a honeycomb 2-phase structure is formed oriented toward the direction of the magnetic field and, when the structure is vertically compressed, the recrystallized structure is made ultrafine effectively. In pearlite transformation, hardening occurs when carbon atoms supersaturated in density are introduced in the presence of a magnetic field gradient, and curing further promotes precipitation hardening. In a ferrite complex phase system, wherein ultrafine globular cementite is uniformly distributed, plastic instability becomes explicit in a tensile test. There is a good possibility that an ultrafine structure recrystallization model may be built by calculation, into which the distribution of energy stored prior to recrystallizing nucleus formation is incorporated. The profile of a conceptual process of off-line or in-line integration of heavy-strain process and intense magnetic field application has become tangible. (NEDO)

  6. Report on the results of efforts for fiscal 1997. Development of technologies for creating high-quality crystal materials for low-loss power control devices; 1997 nendo seika hokokusho. Teisonshitsu denryoku seigyo soshiyo kohinshitsu kessho zairyo sosei gijutsu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    Basic technologies are developed for the manufacture of high-quality crystal materials large in diameter and homogeneous in property which will allow power control semiconductor devices to grow more sophisticated in function and to be lower in the loss they suffer. Physical properties of molten semiconductor and the like are measured accurately, which include surface tension, density, viscosity, electric conductivity, thermal conductivity, emissivity, diffusion coefficient, vapor pressure, heat capacity, contact angle, and solid solution equilibrium distribution coefficient. In computer-aided simulation, as in the previous year, simulation codes are developed for the analysis of flow, temperature distribution, and diffusion behavior in the gas phase; simulation codes are developed for the analysis of 3D unsteady thermal flows in the melt; and a main program is developed which governs experimental calculations. As for experiments in model Czochralski crucibles, small crucible are used in which experiments are conducted in the temperature range of normal to 200degC for the acquisition of experimental data for verification. Measured by use of the model crucibles are the temperature distribution in the bath, the surface flow speeds, and the flows inside the melt. 140 refs., 153 figs., 10 tabs.

  7. Fiscal 1997 report on the results of the technical development of super metal under consignment from NEDO. Technology to create ferrous mesoscopic structure control materials; Super metal no gijutsu kaihatsu (tetsukei mesoscopic soshiki seigyo zairyo sosei gijutsu) seika hokokusho (1997 nendo). Shin Energy Sangyo Gijutsu Sogo Kaihatsu Kiko (NEDO) itaku kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    The fiscal 1997 results were reported of the project on the technical development of super metal which draws out limit performance of ferrous metal and improves the recyclability. In the study of large-strain deformation, a study was carried out with the use of large-strain deformation of more than 50% per 1 pass (strain rate: 0.7 or more) and multi-phase structure. By the crystal microstructuring technology, a level was reached where approximately 1{mu}m crystal size can be obtained. In the study of high magnetic field utilization, the course of study of the structure control and microstructuring was chosen in the preliminary experiment using the existing 8 tesla magnet, and the design and fabrication of a new 12 tesla large-diameter magnet were conducted. In the study of material structure prediction, modeling of microstructuring by recrystallization and establishment of a material predicting method of micro/multi-phase/mixed-grain structures were made the subjects. In the analysis of the mesoscopic structure, the mesoscopic analysis was made of the 0.3C-9Ni steel microstructured by the large-strain deformation thermal processing, and it was shown that the reflective electronic image measured by varying accelerating voltage gives new structural information. 111 refs., 135 figs., 35 tabs.

  8. Fiscal 1980 Sunshine Project research report. Development of hydrothermal power plant. Development of binary cycle power plant (Research on heat cycle, heat medium, material and heat medium turbine); 1980 nendo nessui riyo hatsuden plant no kaihatsu seika hokokusho. Binary cycle hatsuden plant no kaihatsu (netsu cycle oyobi netsubaitai no kenkyu, zairyo no kenkyu narabini netsubaitai turbine no kenkyu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1981-03-01

    This report summarizes the fiscal 1980 research result on each element of the next 10MW class geothermal binary cycle power plant, following last year. In the research on heat cycle and heat medium, measurement was made on the liquid density, vapor density, liquid specific heat, vapor specific heat and thermal conductivity of 8 heat media to prepare the precise pressure enthalpy chart. The thermal stability of each medium was also measured under a flow condition. The heat cycle of each medium was calculated in a hydrothermal temperature range of 120-160 degrees C for evaluation of its output. In the research on material, field corrosion test and laboratory simulation were made on 3 kinds of heat exchanger martials for acidic hot water to study the corrosion behavior of welding members. In the research on heat medium turbine, study was made on sealing characteristics such as differential pressure, flow rate and friction of sealing oil for oil film seal and mechanical seal as shaft seal devices of heat medium turbines for the 10MW class geothermal plant. (NEDO)

  9. Research report of FY 1997 on the industrial science and technology development. Technology development of super-metal (technology development of nano-amorphous structural control materials); 1997 nendo sangyo kagaku gijutsu kenkyu kaihatsu Shin Energy Sangyo Gijutsu Sogo Kaihatsu Kiko itaku seika hokokusho. Super metal no gijutsu kaihatsu (nano-amorphous kozo seigyo zairyo no gijutsu kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    Research and development of the innovative metals have been conducted, by which the weight reduction of members can be done by drastically improving the strength compared with conventional metals. For the high-rate cluster deposition and super plastic forming technologies, research and development of aluminum-based light-weight materials have been conducted, which provides excellent strength, toughness, and super plastic formability at room temperature. For the high-density energy utilization and control technology (amorphous-A), super-metals have been investigated as high dew point and corrosion resistance materials used for waste incinerators operated under the very severe conditions. These are expected to be applied to the apparatuses and equipment due to their excellent properties. For the controlled cooling technology (amorphous-B), super-metals with excellent soft magnetic characteristics and degree of shape freedom have been investigated for high performance and high efficiency devices including electric/electronic/communication devices, power transmission devices, and various industrial devices and parts. These are expected to contribute to the creation of new markets and the improvement of international competitive force. 123 refs., 160 figs., 33 tabs.

  10. Fiscal 2000 report on results of project for R and D of industrial science and technology in cooperation with universities, and R and D of platform for designing high functional materials (development of energy use rationalization technology); 2000 nendo kokino zairyo sekkei platform no kenkyu kaihatsu seika hokokusho. Energy shiyo gorika gijutsu kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    R and D was conducted concerning sophistication and high speeding in designing materials by simulation technology utilizing a new calculation method, with fiscal 2000 results compiled. A group working on coarse-grained molecular dynamics have tackled three problems such as the development and application of a multi-purpose coarse-grained molecular dynamics engine called COGNAC. A group on dynamic average domain method added various functions to a new multi-purpose dynamic average domain simulator called SUSI, and also achieved a variety of results by simulations using this simulator. A group on dispersed structure simulation has been proceeding with the development and application study of a multi-phase dynamics simulator called MUFFIN. A verification research group carried out verification of predictability, with the accuracy intended by each program, on thermal properties, optical properties, formability, etc., using polyethylene as the verification material. A platform group prepared a new high-speed platform that used less memory. (NEDO)

  11. Achievement report for fiscal 2000 on the phase II research and development for hydrogen utilizing international clean energy system technology (WE-NET). Task 10. Development of low-temperature materials; 2000 nendo suiso riyo kokusai clean energy system gijutsu (WE-NET) dai 2 ki kenkyu kaihatsu. Task 10. Teion zairyo no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    This paper describes the achievements in fiscal 2000 from the development of candidate low-temperature materials for liquid hydrogen transportation and storage (including mother materials and welds) for WE-NET. Evaluation tests were performed on material properties (mechanical properties, low-temperature embrittlement, and hydrogen embrittlement sensitivity) under room temperature and low temperature regions including liquid hydrogen atmosphere. Low temperature toughness of welds was assessed particularly to identify characteristics of different welding methods developed newly for improvements. The stainless steels and the mother materials of aluminum alloy selected as the candidates have sufficient characteristics even under the liquid hydrogen atmosphere, but the welds have lower low-temperature toughness, requiring improvement. For the stainless steels, since the amount of {delta} ferrite in welds affects greatly the low-temperature toughness, adoption of complete austenite type welding metal is effective. The reduced pressure electron beam welding method can enhance drastically the low-temperature toughness of stainless steel. For the aluminum alloy, it can be one of the alternatives to use an alloy system with composition of high low-temperature toughness. The friction stir welding method for the aluminum alloy was found to provide extremely high low-temperature toughness, which can be evaluated as a new welding method. (NEDO)

  12. Report on the results of the fiscal 1997 international research cooperation project. `Joint R and D industrial base technology` (development of functionally graded materials); 1997 nendo kokusai kyoryoku jigyo. `Sangyo kiban gijutsu kyodo kenkyu kaihatsu` keisha kinosei zairyo no kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    For the purpose of developing functionally graded materials (FGM/LB) of thermal stress relaxation heat resistant large bulk state which are adoptable to high efficiency engine members, conducted in fiscal 1997 as intermediate target were the experiment for enlargement of the sintering process of FGM/LB with bore of up to 100mm, evaluation of physical properties, the basic development of the fabricating system facility for the commercialization. In the development of heat resistance use FGM/LB fabrication technology, to obtain ZrO2(3Y) stainless steel system FGM/LB, the following were fabricated in each bore size of 50-100mm by the research use large discharge plasma sintering machine: sintered bodies of ceramics/metal single substrate materials and mixed layer single substance materials, and FGM/LB sintered bodies without separation and crack which are composed of 9 intermediate graded layers. The survey was also made on the optimal composition and optimal sintering conditions toward the enlargement without unevenness. In the evaluation of physical properties, ZrO2(3Y)/stainless steel system was selected and test pieces were fabricated to obtain basic data on texture observation, distribution of hardness, fracture toughness, high temperature abrasion resistance, thermal expansion rates, etc. 27 refs., 108 figs., 43 tabs.

  13. Analysis and evaluation for practical application of photovoltaic power generation system. Analysis and evaluation for thin substrate polycrystalline solar cells (compound semiconductors and their fabrication technologies); Taiyoko hatsuden system jitsuyoka no tame no kaiseki hyoka. Usumaku taiyo denchi jitsuyoka no tame no kaiseki hyoka (kagobutsu taiyo denchi zairyo oyobi seisaku gijutsu no kaiseki hyoka)

    Energy Technology Data Exchange (ETDEWEB)

    Oyagi, H.; Okada, Y.; Yamaguchi, H.; Shiota, T.; Kuroda, S.; Igarashi, O.; Tanino, H.; Makita, Y.; Yamada, A.; Kimura, S.; Ohara, A.; Niki, S.; Shibata, H.; Fons, P. [Electrotechnical Laboratory, Tsukuba (Japan)

    1994-12-01

    Described herein are the results of the FY1994 research program for analysis and evaluation for thin-film compound semiconductor solar cells. The study on epitaxial growth and optical properties of the thin films of CuInSe2 and CuGaSe2 evaluates the thin epitaxial films grown under various conditions, showing morphology of the defects at the interface of heteroepitaxial growth. These results are used to set the growth conditions under which a thin film of high luminescence by exciter recombination is produced. The study also gives information of luminescence transition in the vicinity of the band ends and of energy level between the bands. The study on structural analysis of the epitaxially grown thin films of CuInSe2 investigates dependence of lattice constants of the MBE-grown CIS layer on film thickness by the X-ray diffractometry based on the bond method. The study on epitaxial growth by the Se(CH3)2-halogen transfer method tests epitaxial growth of the single-crystalline Mo on a substrate of single-crystalline sapphire. 5 figs.

  14. Research and development of system to utilize photovoltaic energy. Survey on the high-durability and low-cost materials for constructing the solar-cell module and its structure; Taiyoko hatsuden riyo system no kenkyu. Taiyo denchi module yo kotaikyusei tei cost zairyo, kozo ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    Tatsuta, M. [New Energy and Industrial Technology Development Organization, Tokyo (Japan)

    1994-12-01

    This paper reports the results obtained during fiscal 1994 on a survey on the high-durability and low-cost materials for constructing the solar-cell module and on its structure. With respect to forms and materials used in the present solar-cell modules, identification was made on the current status of products commercially available and developed inside and outside Japan. Main types of solar cells used for electric power are of crystal-based silicon. Amorphous silicon and CdS-CdTe are used for consumer applications of indoor and outdoor use. As regards transparent resin materials, fluorine resin, PET, acryl, and polyimide are used as surface materials, and EVA, silicon and PVB are often used as fillers. Developments inside and outside Japan are limited to systems of polycarbonate, methacryl, fluorine, polyurethane, acryl and polyester. Butyl rubber and polyurethane are used as sealing materials. Developments are being performed on silicon rubber, polychloroprene rubber and EPT rubber for shaped materials, and silicon systems, urethane systems and polysulfide systems for non-shaped materials. 3 figs., 8 tabs.

  15. Technological development for super-high efficiency solar cells. Technological development for crystalline compound solar cells (research and development of composite materials on solar cells under microgravity environment); Chokokoritsu taiyo denchi no gijutsu kaihatsu. Kessho kagobutsu taiyo denchi no gijutsu kaihatsu (bisho juryoku kankyo wo riyoshita taiyo denchiyo zairyo kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    Tatsuta, M. [New Energy and Industrial Technology Development Organization, Tokyo (Japan)

    1994-12-01

    This paper reports the study results on development of composite materials for solar cells under microgravity environment in fiscal 1994. (1) On a thin film capillary method, 26 experiments of GaSb thin film crystal growth were conducted using the especially prepared high-accuracy electric furnace under microgravity. The wettability of thin film crystals was improved by refining equipment. Rhombus crystal planes and large crystal grains were observed in GaSb thin film crystals prepared under microgravity. (2) On a liquid phase method, the effect of the gravity on crystal structure and grain morphology was studied for synthesis of CdS fine grains. (3) On technological development of composite materials, the solidification experiment of Cu-In-Se melt was conducted under short time microgravity of 10{sup -4}g for 10 sec. As a result, more uniform texture and more high crystallinity were obtained under microgravity, and In in melt was concentrated by surface tension effect. It was suggested that high-quality CIS thin films will be obtained by Se doping into Cu-In composite films under microgravity environment.

  16. Hydrogen utilization international clean energy system technology (WE-NET). Subtask 8. Research and development of hydrogen combustion turbines (development of ultra-high temperature materials); Suiso riyo kokusai clean energy system (WE-NET). Subtask 8. Suiso nensho turbine no kenkyu kaihatsu chokoon zairyo no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    The paper described the result of the fiscal 1996 development of ultra-high temperature materials for parts of hydrogen combustion turbines, as part of the hydrogen utilization technology, which have excellent environmental protectivity and remarkably high efficiency. By the optimized solution heat treatment of monocrystal alloy developed in the previous fiscal year, obtained was strength property the same as the existing super alloys. As to FRC, pore size and strength property of SiC organic hybrid were made clear. ODS alloy cooling blades and heat insulation coating were studied, and YSZ was found to be most excellent as coating material. Concerning intermetallic compounds, the applicability to ultra-high temperatures up to 1700degC was not obtained. For improvement of heat resistance and environment resistance, adopted were highly compacting SiC matrix and BN coatings. Al2O3 was excellent in long-time stability. In the 1600degC steam corrosion test on multiplex structural materials with Al2O3 as surface material, chemical stability was confirmed. Three-dimensional woven fiber reinforced composite materials of C/C{center_dot}CMC were trially produced by changing the fiber orientation, and improvement in ultra-high temperature thermal shock resistance was confirmed. A study was made of spot observation of the specimen surface by laser microscope, and development was conducted of a temperature measuring method with no influence of radiant heat. 44 refs., 250 figs., 40 tabs.

  17. Fiscal 1993 achievement report. International Clean Energy Network Using Hydrogen Conversion (WE-NET) technology (Subtask 8 - Research and development of hydrogen combustion turbine - Development of ultrahigh-temperature materials); 1993 nendo seika hokokusho. Suiso riyo kokusai clean energy system gijutsu (WE-NET). (Subtask 8. Suiso nensho tabin no kaihatsu - Cho koon zairyo no kaihatsu no kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-03-01

    Current technologies are surveyed and tasks to discharge are extracted relating to heat resistant alloys, intermetallic compounds, ceramic based composite materials, and carbon based composite materials, which are expected to be used for hydrogen combustion turbines. Concerning oxide dispersion strengthened alloys for cooled vanes, tasks to discharge are extracted, which relate to the designing, development, and selection of vane materials, bonding layer materials, and coating materials, and to thermal barrier coating techniques and machining techniques. Concerning porous fiber reinforced ceramic materials for ceramic shells, tasks involve the elucidation of corrosion behavior and manufacturing techniques. MoSi{sub 2}, which is a promising high-melting intermetallic compound, also presents some tasks to discharge for an increase in its high strength and high ductility in an ultrahigh-temperature steam/reducing atmosphere, and for improvement in manufacturing techniques. For the carbon/carbon composite material which is the sole material usable in the ultrahigh-temperature domain of 2,000 degrees C, an analysis and evaluation method taking its anisotropy into consideration needs to be developed, and an oxidation resistant coating has to be also developed. In addition to the designing and development of these materials, development is necessary of materials testing and evaluating techniques. (NEDO)

  18. Research and development of basic technologies for the next generation industries, 'light-reactive materials'. Evaluation on the second term research and development; Jisedai sangyo kiban gijutsu kenkyu kaihatsu 'hikari hanno zairyo'. Dainiki kenkyu kaihatsu hyoka

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1991-03-01

    Research and evaluation was performed with an objective of establishing the basic technology related to light-reactive materials that control the structures and status of aggregation of molecules by using actions of light, and can be used for ultra-high density recording, high resolution indication and light switches. In elucidating the basic characteristics of photochromic materials, a non-destructively readable recording system was proposed and demonstrated, highly durable and high-functional photochromic compounds were developed, and a number of material design guidelines were accumulated to realize characteristics required in light-beam recording. With regard to development of the photochromic materials, realization of photochromic thin films that can record wavelengths in multiplex manner has become more realistic. For elucidating basic characteristics of PHB materials, a method for evaluation from a number of directions including the time method for photon echo was established in addition to the conventional frequency recording characteristics. Regarding the elucidation of the PHB phenomenon, demonstration was carried out on intermediate zone structure control in diversified material systems including living organism substances, where a large number of findings were accumulated. (NEDO)

  19. FY 2000 report on the results of the R and D of 'frontier carbon technology.' R and D of a system to support production of undersea oil; 2000 nendo 'tansokei kokino zairyo gijutsu' no kenkyu kaihatsu seika hokokusho. Kaitei sekiyu seisan shien system kenkyu kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-05-01

    This report summarized the results of the FY 2000 R and D of frontier carbon technology (FCT). In Chapter 1, technology of original production of substances, new carbon-base substances such as hetero-diamond and carbon nitride with high-grade and various characteristics are synthesized. And, the following are also established: method to synthesize nanotubes, etc. in quantity, technology to control interatomic bonding, technology to control hetero-element replacement, etc. BCN films were obtained by film formation by changing the gas component ratio of diborane, methane and nitrogen by the electron beam excitation CVD method. The sp{sup 3} bonding control in carbon film was advanced. By reacting benzene with raw materials using nickel phthalocyanine as catalyst, carbon nanotube with a 60nm diameter was obtained. Using ECRCVD device, carbon fiber was synthesized on Si substrate. In Chapter 2, original production process technology of mechanical high function materials, subjects are as follows: composition gradient film forming technology, complicated morphology film formation/micro processing technology, technology to apply carbon-base materials to tribology. The application of the materials to the movable part of various industrial machines is considered by making use of characteristics such as low friction and low abrasion which are expected of amorphous carbon, diamond, carbon nitride, etc. (NEDO)

  20. Fiscal 2000 report on result of R and D of industrial science and technology that creates new industry. Development of supermetal technology (development of nano-amorphous structured material); 2000 nendo super metal no gijutsu kaihatsu seika hokokusho. Nano amorphous kozo seigyo zairyo no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    R and D was conducted for the purpose of manufacturing innovative iron-based alloy materials that excel in high temperature strength, toughness and superplastic forming, with fiscal 2000 results compiled. In the technological study on high-speed grain accumulation and superplastic forming, the researchers were engrossed in developing an aluminum bulk material of nano-crystals. This year, an Al-Fe two-element based alloy using Fe element was evaluated in the composition, thermal processing conditions and physical properties, with a bulk material obtained having a grain size of several tens in nm at 2at% Fe level, a strength of 750-850 MPa and a tenacity (Kc value) of 45-65 MPa(center dot)m{sup 1/2}. In the research of technologies for utilizing and controlling high density energy, design of materials was progressed for strong-acid resistant dew point corrosion materials, leading to the discovery of an alloy composition Ni-10Cr-5Nb-16P-4B whose subcooled liquid zone was wider than the Ta-added alloy of the previous year. Use of He gas as injection gas enabled a quality amorphous powder to be obtained in kg units. In the development of bulk amorphous producing technologies, this powder was thermostatically rolled to make a dense bulk amorphous plate of 2.8 mm thick and about 100 mm long. (NEDO)

  1. FY 1998 annual summary report on International Clean Energy Network Using Hydrogen Conversion (WE-NET) system technology. Subtask 6. Development of cryogenic temperature materials technologies; 1998 nendo seika hokokusho. Suiso riyo kokusai clean energy system gijutsu (WE-NET) subtask 6 (teion zairyo gijutsu no kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Summarized herein are the cryogenic temperature materials technologies for the International Clean Energy Network Using Hydrogen Conversion (WE-NET) project, developed in FY 1998. The R and D programs have been implemented continuously since 1994. For stainless steel, the base and TIG weld metals were evaluated for their material characteristics in liquid hydrogen. The items investigated included the influences of hydrogen charge, 20% of stretch working on the base metal, welding methods, and ?-ferrite content on the characteristics. Fatigue strength of the base metal was found to increases as temperature decreases, but remain unchanged in a range from 20 to 77K. No significant difference was observed between 304L and 316L. For aluminum alloy, mechanical characteristics, centered by fatigue characteristics, were investigated for the base and weld metals. The sample of higher tensile strength showed a higher fatigue strength, at room temperature, 77 and 4K. The other tested items investigated included embrittlement characteristics in a hydrogen atmosphere, phase transformation, hydrogen diffusion and fracture toughness, for establishing the databases of cryogenic temperature materials. (NEDO)

  2. Fiscal 1996 project on the R and D of industrial scientific technology under consignment from NEDO. Report on the results of the R and D of technologies to invent original high-functional materials; 1996 nendo sangyo kagaku gijutsu kenkyu kaihatsu jigyo Shin Energy Sangyo Gijutsu Kaihatsu Kiko itaku. Dokusoteki kokino zairyo sosei gijutsu no kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    Technologies were described of creating original high-functional materials. The paper presented the following two as fields of technology on which importance is to be placed for the future R and D from technological and socioeconomic points of view. In the field of new materials of living organism imitation type, remarkably high-performance/high-functional new materials are invented by imitating the precise function manifestation mechanism of the ultimate living organism in which a great variety of matters are in harmony with each other and manifest complicated and high-level functions. In the field of structural control/synthesis process technology, the paper is aimed at manifestation of newer and higher functions/performance and innovation of the synthesis process, and also at developing technology to precisely control structure and process of materials including surface and interface in correspondence with atomic/molecular to macro levels. Up to the present, conducted were an examination of autonomous response materials (the subtheme is a R and D of polymer/composite multi-stimuli-responsive materials) and a R and D of precise polymerization (control) polymer materials. 239 refs., 129 figs., 49 tabs.

  3. `Joint Research and Development of Industrial Technology,` an international research collaboration for fiscal 1997. Research and development for practical application of low-temperature sinterable, highly heat-radiating materials for ceramics; 1997 nendo kokusai kenkyu kyoryoku jigyo `sangyo kiban gijutsu kyodo kenkyu kaihatsu`. Teion shoketsu kohonetsusei ceramics kiban zairyo no jitsuyoka gijutsu no kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    A highly heat-conducting AlN ceramic substrate is developed for the cooling of semiconductor integrated circuit devices and power controlling semiconductor devices. In the development of a low-temperature sinterable ceramic texture, a sintering assistant is selected. In this process various assistants are tested for the effect of their presence on the occurrence of AlN oxidation and on the magnitude of standard energy for aluminate compound formation. The volatility at high temperatures of the components of the assistants are also examined. The sintering assistant developed for this project (mixture of Y2O3, CaO, LaB6, and WO3) is used in the sintering of an AlN material powder developed by The Dow Chemical Co., and then it is demonstrated that highly heat-conducting AlN substrates are mass-produced by continuous sintering at 1600degC in a nitrogen atmosphere, the product having a relative density of 100%, average heat conductivity of 154W/mK, bend resisting strength of 440MPa, and a fracture toughness value of 3.8MPam{sup 1/2}. 6 refs., 92 figs., 10 tabs.

  4. Research and development of basic technologies for next generation industries, 'high-efficiency polymeric separation membrane material'. Evaluation on second term final research and development (first report); Jisesdai sangyo kiban gijutsu kenkyu kaihatsu. Kokoritsu bunshi bunrimaku zairyo (dainiki kenkyu kaihatsu hyoka)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1988-03-01

    This study is intended to establish a basic technology for innovative high-efficiency separation membrane materials that can be used in areas in which application of membrane separation has been impossible. The water/ethanol separation membrane (for water selective permeation) and water/acetic acid separation membrane (for water selective permeation) achieved separation coefficient and permeation velocity of the world's highest level. The water/ethanol separation membrane (for ethanol selective permeation), although its separation coefficient is lower than the world's highest performance, has high permeation velocity, providing the performance of the worldwide level as seen from the comprehensive viewpoint. The carbon monoxide/nitrogen separation membrane achieved separation coefficient and permeation velocity of the world's highest level. The oxygen/nitrogen separation membrane requires further enhancement in the permeation velocity and stability. Establishment has been performed on separation technologies for membrane separation of non-water soluble aqueous solutions, optical division by using chiral crown ether, high-performance liquid separation by means of plasma surface treatment, and particle separation. Basic analysis has been advanced also on evaluation technologies for gaseous body separation membrane and liquid separation membrane, of which future progress is expected. (NEDO)

  5. Fiscal 1997 R and D project on industrial science technology under consignment from NEDO. Report on the R and D of nonlinear optoelectronic materials; 1997 nendo sangyo kagaku gijutsu kenkyu kaihatsu jigyo Shin energy Sangyo Gijutsu Sogo Kaihatsu Kiko itaku. Hisenkei hikari denshi zairyo no kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    As to the development of organic base materials, the paper is going ahead with an evaluation, higher performance and further use as materials of basic optical properties of quirale nonlinear materials and organic conjugate base materials which are promising among organic low molecular materials. As the development of orientation control crystal growth technology, grooves for orientation control were formed on the surface of the lead glass substrate, from which thin film single crystals were obtained. The nonlinear response was studied of the glass where semiconducting fine particles dispersed in matrix glass. Glass scattering base prototype materials were selected by the sol-gel method and ultra-low melting-point glass method. The glass dispersion base materials by the very fast cooling method was also studied. For the purpose of realizing a high speed switching characteristic, a processing technology was developed of ultra fine particle dispersing polymer light waveguide. As to the technology for super lattice, the optimum nonlinear performance materials were selected mainly with the optimum complex super lattice base. Moreover, the three-dimensional super structuring technology was constructed to improve nonlinear optical characteristics. The comprehensive investigational study was conducted for effective promotion of the research development. 177 refs., 260 figs., 27 tabs.

  6. Fiscal 1997 project on the R and D of industrial scientific technology under consignment from NEDO. Report on the results of the R and D of silicon-based polymeric materials (development of liquid methane fueled aircraft engine); 1997 nendo sangyo kagaku gijutsu kenkyu kaihatsu jigyo / Shin energy Sangyo gijutsu Sogo Kaihatsu Kiko itaku. Keisokei kobunshi zairyo no kenkyu kaihatsu (methane nenryo kokukiyo engine kaihatsu) seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    This R and D aims at establishing the basic technology on the molecular design, synthesis, use as materials, and evaluation of silicon-based polymers, of which excellent electronic/optical functions, high heat-resistance/combustion-resistance/dynamic characteristic are expected. The paper introduced the results of the fiscal 1997 R and D of them. The themes are as follows: technology of synthesis of silicon-based polymeric materials with sea-island microstructures, interstitial type structure forming technology, composite materials with organometallic complexes and silicon-based polymers, silicon-based polymer structural materials with ring structures, optimization of the Wurtz`s synthesis method of silicon-based polymers, unsaturated and hypercoordinate organosilicic compounds, function of silicon-based polymers, synthesis and polymerization of new silicon-based monomers, development of a new synthesis method of polysilane and the function, development of new application of silicon-based polymers in imaging devices for recording/memory/display of information, molecular design of {pi}-conjugate and {sigma}-conjugate compounds including silicon, and conformation and electronic state of silicon-based polymeric materials. 186 refs., 141 figs., 68 tabs.

  7. Fiscal 1998 intellectual infrastructure project utilizing civil sector functions. Research and development project on prompt-effect type intellectual infrastructure creation (Research and development concerning relations between sintered body textural structure and material characteristics in fine ceramics); 1998 nendo minkan no kino wo katsuyoshita chiteki kiban jigyo seika hokokusho. Sokkogata chiteki kiban sosei kenkyu kaihatsu jigyo (fine ceramics no shoketsutai soshiki kozo to zairyo tokusei tono kankei ni kansuru kenkyu kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    Research and development was carried out involving fine ceramic sintered body textural structure evaluation methods for the development of process technologies for achieving higher quality and lower cost. Studies centered about a method for evaluating coarse pores and coarse grains in sintered bodies, relations between sintered body fracture strength and textural structure, and the standardization of evaluation methods. As the result, an evaluation method for observing pore structures in a sintered body flake specimen under an optical microscope and another for observing coarse grains under a polarization microscope were proposed. As for the effect of coarse defects on the fracture strength of ceramics, it was demonstrated experimentally and theoretically that coarse defects several tens of micrometers in size greatly affected the fracture strength. In the study of methods for sintered body grain size evaluation, findings were obtained about the processing of the specimen surface. (NEDO)

  8. Fiscal 1997 R and D project on industrial science and technology under a consignment from NEDO. R and D of the superconducting material and device (technical development of the Josephson device hybrid system); 1997 nendo sangyo kagaku gijutsu kenkyu kaihatsu jigyo Shin energy Sangyo Gijutsu Sogo Kaihatsu Kiko itaku. Chodendo zairyo chodendo soshi no kenkyu kaihatsu (Josephson soshi hybrid system no gijutsu kaihatsu) seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    In order to establish basic technology for hybrid systems of superconducting and semiconducting devices, study was made on ultrahigh speed and low energy consumption properties of Josephson devices. As Josephson IC technology, a logical circuit, ring network, memory circuit, and oxide superconductor logical circuit were studied. As superconducting hybrid system technology, a Josephson device- semiconductor device interface, formation technology of signal transmission lines, and Josephson-MOS IC technology were developed. In fiscal 1997, as Josephson IC technology, switch motion of 4GHz in clock frequency was achieved by new high-density wiring process. Integration of some semiconducting processor elements, junction of surface- stabilized superconducting thin films, and motion of combination structure of some SQUIDs were also confirmed. On the hybrid system, voltage conversion operation of all interfaces was confirmed. Proper logical operation of the Josephson device hybrid circuit was also confirmed. 95 refs., 90 figs., 5 tabs.

  9. Fiscal 1997 report on the development of an energy use rationalization ultra-high tech liquid crystal technology. Project of development/promotion of ultra-high tech electronic technology / technology of design/control/analysis of new functional electronic materials; 1997 nendo kenkyu seika hokokusho energy shiyo gorika chosentan ekisho gijutsu kaihatsu. Chosentan denshi gijutsu kaihatsu sokushin jigyo / shinkino denshi zairyo sekkei seigyo bunseki gijutsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-05-01

    A research was conducted with the aim of developing an ultra-low power consuming type information display which supports the next next generation informatizing society. As to the function combined type fine structure formation technology, a formation technology of fine structure supporting multi-layer pixel by organic polymer materials was established to confirm a possibility of adopting it to high functional liquid crystal display. Concerning the high functional fine structure formation technology, a study was proceeded with on holographic PDLC which is an interference reflection coloring method. In relation to the low temperature film formation technology of ferroelectric thin films, a film formation device was introduced to obtain basic data, and at the same time a possibility was studied of improving film characteristics by laser annealing conducted after the film formation. Moreover, concerning the new functional material technology, studies were made of optical interference/high light-scattering control materials, light alignment elements, ultra-high purity/ultra-reliable optical materials, ultra-anisotropy optical materials, etc. About the light reflection characteristics control technology, studied were new liquid crystal molucular orientaion control technology, multi-dimensional anisotropy structure formation technology, etc. 100 refs., 273 figs., 58 tabs.

  10. Analysis and evaluation for practical application of photovoltaic power generation system. Analysis and evaluation for thin substrate polycrystalline solar cells (alloy-base amorphous materials, PIN layers, strains in the interface, and effects of impurities); Taiyoko hatsuden system jitsuyoka no tame no kaiseki hyoka. Usumaku taiyo denchi jitsuyoka no tame no kaiseki hyoka (gokinkei amorphous zairyo pin kakuso kaimen ni okeru yugami fujunbutsu nado no eikyo)

    Energy Technology Data Exchange (ETDEWEB)

    Matsuda, A.; Oeda, H.; Yamasaki, S.; Hata, N.; Kondo, M.; Toshima, Y.; Sakata, I.; Ganguly, G.; Suzuki, A.; Kamei, T.; Okushi, H.; Nonaka, H.; Oda, N.; Katagiri, H.; Ichimura, N.; Kokubu, K.; Nakamura, K.; Sekikawa, T.; Yamanaka, M. [Electrotechnical Laboratory, Tsukuba (Japan)

    1994-12-01

    Described herein are the results of the FY1994 research program for analysis and evaluation for thin film solar cells. The study on quantitative analysis of hydrogen atoms in a plasma determines quantity of hydrogen atoms in the plasma of monosilane diluted with hydrogen. It is found, contrary to expectation, that quantity of hydrogen atoms in the plasma decreases as it is more diluted with hydrogen. The study on light-induced degradation of the thin chlorine-base amorphous silicon films confirms that the plasma CVD method with 20% of dichlorosilane gas added to monosilane gas produces the thin amorphous silicon film 3 times faster than the conventional method. The thin film has essentially the same defect density as the one prepared by the conventional method, showing good photoelectric characteristics. The thin film of chlorinated amorphous silicon has a 1 digit lower defect density than the conventional one of amorphous silicon, as revealed by the accelerated degradation test with irradiated laser light and the constant current method to determine saturated defect density. 3 figs.

  11. FY 2000 report on the results of the regional consortium R and D project - Regional consortium energy field. First year report. Development of the process for creation of new functional materials using electron beam excited plasma; 2000 nendo chiiki consortium kenkyu kaihatsu jigyo - chiiki consortium energy bun'ya. Denshi beam reiki plasma wo mochiita shinkino zairyo sosei process no kaihatsu (dai 1 nendo) seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    The development of manufacturing technology was proceeded with for a high speed nitriding system using electron beam excited plasma device which realizes high dissociation for nitrogen molecules and controls the plasma state. By the device, the following are aimed at: high quality/high speed nitriding, formation of super-hard cubic system boron nitride (c-BN) and carbon nitride (CN) films on the surface of tools, and formation of TiO{sub 2} thin films with high infrared reflectance and environmental purification photocatalyst function. TiO{sub 2} thin films are assumed to be applied to window glass by making use of the high performance heat mirror function as well as the environmental purification function. Studies were made in the following 6 fields: 1)development of small electron beam excitation plasma source; 2) development of high speed nitrided container; 3) establishment of technology for real-time monitoring of radicals and ions; 4) design/trial manufacture of a device to form super-hard nitrided thin films; 5) development of heat mirror film formation device; 6) establishment of a method to evaluate effects of photocatalyst. (NEDO)