WorldWideScience

Sample records for sandy soils degradation

  1. Enhancing crude oil degradation in a sandy soil: Effects of addition ...

    African Journals Online (AJOL)

    This study investigated the effects of the addition of poultry manure alone and in combination with surfactant (Goldcrew or Corexit) and/or alternate carbon substrate (glucose or starch) on crude oil degradation in a sandy soil. With poultry manure alone, optimal crude oil degradation was obtained at a concentration of 4.0% ...

  2. Fate of CL-20 in sandy soils: Degradation products as potential markers of natural attenuation

    International Nuclear Information System (INIS)

    Monteil-Rivera, Fanny; Halasz, Annamaria; Manno, Dominic; Kuperman, Roman G.; Thiboutot, Sonia; Ampleman, Guy; Hawari, Jalal

    2009-01-01

    Hexanitrohexaazaisowurtzitane (CL-20) is an emerging explosive that may replace the currently used explosives such as RDX and HMX, but little is known about its fate in soil. The present study was conducted to determine degradation products of CL-20 in two sandy soils under abiotic and biotic anaerobic conditions. Biotic degradation was prevalent in the slightly acidic VT soil, which contained a greater organic C content, while the slightly alkaline SAC soil favored hydrolysis. CL-20 degradation was accompanied by the formation of formate, glyoxal, nitrite, ammonium, and nitrous oxide. Biotic degradation of CL-20 occurred through the formation of its denitrohydrogenated derivative (m/z 393 Da) while hydrolysis occurred through the formation of a ring cleavage product (m/z 156 Da) that was tentatively identified as CH 2 =N-C(=N-NO 2 )-CH=N-CHO or its isomer N(NO 2 )=CH-CH=N-CO-CH=NH. Due to their chemical specificity, these two intermediates may be considered as markers of in situ attenuation of CL-20 in soil. - Two key intermediates of CL-20 degradation are potential markers of its natural attenuation in soil

  3. Study of aliphatic-aromatic copolyester degradation in sandy soil and its ecotoxicological impact.

    Science.gov (United States)

    Rychter, Piotr; Kawalec, Michał; Sobota, Michał; Kurcok, Piotr; Kowalczuk, Marek

    2010-04-12

    Degradation of poly[(1,4-butylene terephthalate)-co-(1,4-butylene adipate)] (Ecoflex, BTA) monofilaments (rods) in standardized sandy soil was investigated. Changes in the microstructure and chemical composition distribution of the degraded BTA samples were evaluated and changes in the pH and salinity of postdegradation soil, as well as the soil phytotoxicity impact of the degradation products, are reported. A macroscopic and microscopic evaluation of the surface of BTA rod samples after specified periods of incubation in standardized soil indicated erosion of the surface of BTA rods starting from the fourth month of their incubation, with almost total disintegration of the incubated BTA material observed after 22 months. However, the weight loss after this period of time was about 50% and only a minor change in the M(w) of the investigated BTA samples was observed, along with a slight increase in the dispersity (from an initial 2.75 up to 4.00 after 22 months of sample incubation). The multidetector SEC and ESI-MS analysis indicated retention of aromatic chain fragments in the low molar mass fraction of the incubated sample. Phytotoxicity studies revealed no visible damage, such as necrosis and chlorosis, or other inhibitory effects, in the following plants: radish, cres, and monocotyledonous oat, indicating that the degradation products of the investigated BTA copolyester are harmless to the tested plants.

  4. Degradation kinetics of ptaquiloside in soil and soil solution

    DEFF Research Database (Denmark)

    Ovesen, Rikke Gleerup; Rasmussen, Lars Holm; Hansen, Hans Christian Bruun

    2008-01-01

    and soil solutions in sandy and clayey soils subjected to high natural PTA loads from bracken stands. Degradation kinetics in moist soil could be fitted with the sum of a fast and a slow first-order reaction; the fast reaction contributed 20 to 50% of the total degradation of PTA. The fast reaction...... was similar in all horizons, with the rate constant k1F ranging between 0.23 and 1.5/h. The slow degradation, with the rate constant k1S ranging between 0.00067 and 0.029/h, was more than twice as fast in topsoils compared to subsoils, which is attributable to higher microbial activity in topsoils....... Experiments with sterile controls confirmed that nonmicrobial degradation processes constituted more than 90% of the fast degradation and 50% of the slow degradation. The lower nonmicrobial degradation rate observed in the clayey compared with the sandy soil is attributed to a stabilizing effect of PTA...

  5. Biofuel components change the ecology of bacterial volatile petroleum hydrocarbon degradation in aerobic sandy soil

    International Nuclear Information System (INIS)

    Elazhari-Ali, Abdulmagid; Singh, Arvind K.; Davenport, Russell J.; Head, Ian M.; Werner, David

    2013-01-01

    We tested the hypothesis that the biodegradation of volatile petroleum hydrocarbons (VPHs) in aerobic sandy soil is affected by the blending with 10 percent ethanol (E10) or 20 percent biodiesel (B20). When inorganic nutrients were scarce, competition between biofuel and VPH degraders temporarily slowed monoaromatic hydrocarbon degradation. Ethanol had a bigger impact than biodiesel, reflecting the relative ease of ethanol compared to methyl ester biodegradation. Denaturing gradient gel electrophoresis (DGGE) of bacterial 16S rRNA genes revealed that each fuel mixture selected for a distinct bacterial community, each dominated by Pseudomonas spp. Despite lasting impacts on soil bacterial ecology, the overall effects on VHP biodegradation were minor, and average biomass yields were comparable between fuel types, ranging from 0.40 ± 0.16 to 0.51 ± 0.22 g of biomass carbon per gram of fuel carbon degraded. Inorganic nutrient availability had a greater impact on petroleum hydrocarbon biodegradation than fuel composition. Highlights: ► The effect of 10% ethanol or 20% biodiesel on the biodegradability of volatile petroleum hydrocarbons in soil was investigated. ► Competition for scarce inorganic nutrients between biofuel and VPH degraders slowed monoaromatic hydrocarbon degradation. ► Biofuel effects were transitional. ► Each fuel selected for a distinct predominant bacterial community. ► All bacterial communities were dominated by Pseudomonas spp. - Blending of petroleum with ethanol or biodiesel changes the fuel degrading soil bacterial community structure, but the long-term effects on fuel biodegradability are minor.

  6. Amelioration of sandy soils in drought stricken areas through use of ...

    African Journals Online (AJOL)

    ACSS

    improving N, P, Ca and Mg content in sandy soils, and consequently support crop growth and yield. ... stress, soil moisture conservation, soil fertility management ... water many times its own weight. ... improves the productivity of degraded,.

  7. Degradation kinetics of ptaquiloside in soil and soil solution.

    Science.gov (United States)

    Ovesen, Rikke Gleerup; Rasmussen, Lars Holm; Hansen, Hans Christian Bruun

    2008-02-01

    Ptaquiloside (PTA) is a carcinogenic norsesquiterpene glycoside produced in bracken (Pteridium aquilinum (L.) Kuhn), a widespread, aggressive weed. Transfer of PTA to soil and soil solution eventually may contaminate groundwater and surface water. Degradation rates of PTA were quantified in soil and soil solutions in sandy and clayey soils subjected to high natural PTA loads from bracken stands. Degradation kinetics in moist soil could be fitted with the sum of a fast and a slow first-order reaction; the fast reaction contributed 20 to 50% of the total degradation of PTA. The fast reaction was similar in all horizons, with the rate constant k(1F) ranging between 0.23 and 1.5/h. The slow degradation, with the rate constant k(1S) ranging between 0.00067 and 0.029/ h, was more than twice as fast in topsoils compared to subsoils, which is attributable to higher microbial activity in topsoils. Experiments with sterile controls confirmed that nonmicrobial degradation processes constituted more than 90% of the fast degradation and 50% of the slow degradation. The lower nonmicrobial degradation rate observed in the clayey compared with the sandy soil is attributed to a stabilizing effect of PTA by clay silicates. Ptaquiloside appeared to be stable in all soil solutions, in which no degradation was observed within a period of 28 d, in strong contrast to previous studies of hydrolysis rates in artificial aqueous electrolytes. The present study predicts that the risk of PTA leaching is controlled mainly by the residence time of pore water in soil, soil microbial activity, and content of organic matter and clay silicates.

  8. Degradation and persistence of cotton pesticides in sandy loam soils from Punjab, Pakistan.

    Science.gov (United States)

    Tariq, Muhammad Ilyas; Afzal, Shahzad; Hussain, Ishtiaq

    2006-02-01

    The present study evaluated the influence of temperature, moisture, and microbial activity on the degradation and persistence of commonly used cotton pesticides, i.e., carbosulfan, carbofuran, lambda-cyhalothrin, endosulfan, and monocrotophos, with the help of laboratory incubation and lysimeter studies on sandy loam soil (Typic Ustocurepts) in Pakistan. Drainage from the lysimeters was sampled on days 49, 52, 59, 73, 100, 113, and 119 against the pesticide application on days 37, 63, 82, 108, and 137 after the sowing of cotton. Carbofuran, monocrotophos, and nitrate were detected in the drainage samples, with an average value, respectively, of 2.34, 2.6 microg/L, and 15.6 mg/L for no-tillage and 2.16, 2.3 microg/L, and 13.4 mg/L for tillage. In the laboratory, pesticide disappearance kinetics were measured with sterile and nonsterile soils from 0 to 10 cm in depth at 15, 25, and 35 degrees C and 50% and 90% field water capacities. Monocrotophos and carbosulfan dissipation followed first-order kinetics while others followed second-order kinetics. The results of incubation studies showed that temperature and moisture contents significantly reduced the t(1/2) (half-life) values of pesticides in sterile and nonsterile soil, but the effect of microbial activity was nearly significant that might be due to less organic carbon (0.3%). The presence of carbofuran and monocrotophos in the soil profile (0-10, 10-30, 30-60, 60-90, 90-150 cm) and the higher concentrations of endosulfan and lambda-cyhalothrin in the top layer (0-10 cm) showed the persistence of the pesticides. The detection of endosulfan and lambda-cyhalothrin in the 10-30 cm soil layer might be due to preferential flow. The data generated from this study could be helpful for risk assessment studies of pesticides and for validating pesticide transport models for sandy loam soils in cotton-growing areas of Pakistan.

  9. Reclamation status of a degraded pasture based on soil health indicators.

    OpenAIRE

    SANTOS, C. A. dos; KRAWULSKI, C. C.; BINI, D.; GOULART FILHO, T.; KNOB, A.; MEDINA, C. C.; ANDRADE FILHO, G.; NOGUEIRA, M. A.

    2015-01-01

    Pasture degradation is a concern, especially in susceptible sandy soils for which strategies to recover them must be developed. Microbiological and biochemical soil health indicators are useful in the guindace of soil management practices and sustainable soil use. We assessed the success of threePanicum maximum Jacq. cultivars in the reclamation of a pasture in a sandy Typic Acrudox in the northwest of the state of Paraná, Brazil, based on soil health indicators. On a formerly degraded p...

  10. Degradation of zearalenone and ochratoxin A in three Danish agricultural soils

    DEFF Research Database (Denmark)

    Mortensen, G.K.; Strobel, B.W.; Hansen, H.C.B.

    2006-01-01

    Degradation of two mycotoxins: zearalenone (ZON) produced by species of Fusarium and ochratoxin A (OTA) produced by species of Penicillium were followed in pot experiments using agricultural topsoils from Danish experimental farms: a sandy soil, a sandy clay soil and a gyttja soil with a high...... content of silt. Experiments with unplanted soil and pots planted with barley were included. Soil samples were withdrawn during a period of 225 days and analysed for the content of OTA and ZON. The degradation of both toxins consisted of an initial fast degradation followed by a slower transformation step......, whereas the half-lives for OTA were about 0.2-1 day. The slowest degradation was measured in soil rich in clay. After 225 days, neither OTA nor ZON was detected in any of the soil types. Generally, the degradation of ZON and OTA was faster in planted soil than in unplanted soil, probably due to higher...

  11. Effects of soil amendment on soil characteristics and maize yield in Horqin Sandy Land

    Science.gov (United States)

    Zhou, L.; Liu, J. H.; Zhao, B. P.; Xue, A.; Hao, G. C.

    2016-08-01

    A 4-year experiment was conducted to investigate the inter-annual effects of sandy soil amendment on maize yield, soil water storage and soil enzymatic activities in sandy soil in Northeast China in 2010 to 2014. We applied the sandy soil amendment in different year, and investigated the different effects of sandy soil amendment in 2014. There were six treatments including: (1) no sandy soil amendment application (CK); (2) one year after applying sandy soil amendment (T1); (3) two years after applying sandy soil amendment(T2); (4) three years after applying sandy soil amendment(T3); (5)four years after applying sandy soil amendment(T4); (6) five years after applying sandy soil amendment (T5). T refers to treatment, and the number refers to the year after application of the sandy soil amendment. Comparing with CK, sandy soil amendments improved the soil water storage, soil urease, invertase, and catalase activity in different growth stages and soil layers, the order of soil water storage in all treatments roughly performed: T3 > T5 > T4 > T2 > T1 > CK. the order of soil urease, invertase, and catalase activity in all treatments roughly performed: T5 > T3 > T4 > T2 > T1 > CK. Soil application of sandy soil amendment significantly (p≤⃒0.05) increased the grain yield and biomass yield by 22.75%-41.42% and 29.92%-45.45% respectively, and maize yield gradually increased with the years go by in the following five years. Sandy soil amendment used in poor sandy soil had a positive effect on soil water storage, soil enzymatic activities and maize yield, after five years applied sandy soil amendment (T5) showed the best effects among all the treatments, and deserves further research.

  12. Degradation of aldrin im samples of 'cerrado' Brazilian soils

    International Nuclear Information System (INIS)

    Musumeci, M.R.; Ruegg, E.F.

    1981-01-01

    14 C-aldrin degradation was studied in the laboratory, in samples of 'cerrado' Brazilian soils, during a period of 240 days. Recovery of radiocarbon decreased with time, although radiocarbon was not incorporated to the soil organic matter as show by soil combustion. In both soils 14 C-aldrin degraded to dieldrin and another compound that showed caracteristics of a hydrosoluble derivative of aldrin 14 C-aldrin was more persistent in sandy soil but amendment of this soil with nutrients or fertilizers did not enhanced aldrin degradation in this soil. (Author) [pt

  13. Strength Characteristics of Reinforced Sandy Soil

    OpenAIRE

    S. N. Bannikov; Mahamed Al Fayez

    2005-01-01

    Laboratory tests on determination of reinforced sandy soil strength characteristics (angle of internal friction, specific cohesive force) have been carried out with the help of a specially designed instrument and proposed methodology. Analysis of the obtained results has revealed that cohesive forces are brought about in reinforced sandy soil and an angle of internal soil friction becomes larger in comparison with non-reinforced soil.

  14. Biodegradation and bioremediation potential of diazinon-degrading Serratia marcescens to remove other organophosphorus pesticides from soils.

    Science.gov (United States)

    Cycoń, Mariusz; Żmijowska, Agnieszka; Wójcik, Marcin; Piotrowska-Seget, Zofia

    2013-03-15

    The ability of diazinon-degrading Serratia marcescens to remove organophosphorus pesticides (OPPs), i.e. chlorpyrifos (CP), fenitrothion (FT), and parathion (PT) was studied in a mineral salt medium (MSM) and in three soils of different characteristics. This strain was capable of using all insecticides at concentration of 50 mg/l as the only carbon source when grown in MSM, and 58.9%, 70.5%, and 82.5% of the initial dosage of CP, FT, and PT, respectively was degraded within 14 days. The biodegradation experiment showed that autochthonous microflora in all soils was characterized by a degradation potential of all tested OPPs; however, the initial lag phases for degradation of CP and FT, especially in sandy soil, were observed. During the 42-day experiment, 45.3%, 61.4% and 72.5% of the initial dose of CP, FT, and PT, respectively, was removed in sandy soil whereas the degradation of CP, FT, and PT in the same period, in sandy loam and silty soils reached 61.4%, 79.7% and 64.2%, and 68.9%, 81.0% and 63.6%, respectively. S. marcescens introduced into sterile soils showed a higher degradation potential (5-13%) for OPPs removal than those observed in non-sterile soil with naturally occurring attenuation. Inoculation of non-sterile soils with S. marcescens enhanced the disappearance rates of all insecticides, and DT50 for CP, FT, and PT was reduced by 20.7, 11.3 and 13.0 days, and 11.9, 7.0 and 8.1 days, and 9.7, 14.5 and 12.6 days in sandy, sandy loam, and silty soils, respectively, in comparison with non-sterile soils with only indigenous microflora. This ability of S. marcescens makes it a suitable strain for bioremediation of soils contaminated with OPPs. Copyright © 2013 Elsevier Ltd. All rights reserved.

  15. Respirable dust and quartz exposure from three South African farms with sandy, sandy loam, and clay soils.

    Science.gov (United States)

    Swanepoel, Andrew J; Kromhout, Hans; Jinnah, Zubair A; Portengen, Lützen; Renton, Kevin; Gardiner, Kerry; Rees, David

    2011-07-01

    To quantify personal time-weighted average respirable dust and quartz exposure on a sandy, a sandy loam, and a clay soil farm in the Free State and North West provinces of South Africa and to ascertain whether soil type is a determinant of exposure to respirable quartz. Three farms, located in the Free State and North West provinces of South Africa, had their soil type confirmed as sandy, sandy loam, and clay; and, from these, a total of 298 respirable dust and respirable quartz measurements were collected between July 2006-November 2009 during periods of major farming operations. Values below the limit of detection (LOD) (22 μg · m(-3)) were estimated using multiple 'imputation'. Non-parametric tests were used to compare quartz exposure from the three different soil types. Exposure to respirable quartz occurred on all three farms with the highest individual concentration measured on the sandy soil farm (626 μg · m(-3)). Fifty-seven, 59, and 81% of the measurements on the sandy soil, sandy loam soil, and clay soil farm, respectively, exceeded the American Conference of Governmental Industrial Hygienists (ACGIH) threshold limit value (TLV) of 25 μg · m(-3). Twelve and 13% of respirable quartz concentrations exceeded 100 μg · m(-3) on the sandy soil and sandy loam soil farms, respectively, but none exceeded this level on the clay soil farm. The proportions of measurements >100 μg · m(-3) were not significantly different between the sandy and sandy loam soil farms ('prop.test'; P = 0.65), but both were significantly larger than for the clay soil farm ('prop.test'; P = 0.0001). The percentage of quartz in respirable dust was determined for all three farms using measurements > the limit of detection. Percentages ranged from 0.5 to 94.4% with no significant difference in the median quartz percentages across the three farms (Kruskal-Wallis test; P = 0.91). This study demonstrates that there is significant potential for over-exposure to respirable quartz in

  16. Responses of soil fungal community to the sandy grassland restoration in Horqin Sandy Land, northern China.

    Science.gov (United States)

    Wang, Shao-Kun; Zuo, Xiao-An; Zhao, Xue-Yong; Li, Yu-Qiang; Zhou, Xin; Lv, Peng; Luo, Yong-Qing; Yun, Jian-Ying

    2016-01-01

    Sandy grassland restoration is a vital process including re-structure of soils, restoration of vegetation, and soil functioning in arid and semi-arid regions. Soil fungal community is a complex and critical component of soil functioning and ecological balance due to its roles in organic matter decomposition and nutrient cycling following sandy grassland restoration. In this study, soil fungal community and its relationship with environmental factors were examined along a habitat gradient of sandy grassland restoration: mobile dunes (MD), semi-fixed dunes (SFD), fixed dunes (FD), and grassland (G). It was found that species abundance, richness, and diversity of fungal community increased along with the sandy grassland restoration. The sequences analysis suggested that most of the fungal species (68.4 %) belonged to the phylum of Ascomycota. The three predominant fungal species were Pleospora herbarum, Wickerhamomyces anomalus, and Deconica Montana, accounting for more than one fourth of all the 38 species. Geranomyces variabilis was the subdominant species in MD, Pseudogymnoascus destructans and Mortierella alpine were the subdominant species in SFD, and P. destructans and Fungi incertae sedis were the dominant species in FD and G. The result from redundancy analysis (RDA) and stepwise regression analysis indicated that the vegetation characteristics and soil properties explain a significant proportion of the variation in the fungal community, and aboveground biomass and C:N ratio are the key factors to determine soil fungal community composition during sandy grassland restoration. It was suggested that the restoration of sandy grassland combined with vegetation and soil properties improved the soil fungal diversity. Also, the dominant species was found to be alternative following the restoration of sandy grassland ecosystems.

  17. EFFECTS OF ALKALINE SANDY LOAM ON SULFURIC SOIL ACIDITY AND SULFIDIC SOIL OXIDATION

    Directory of Open Access Journals (Sweden)

    Patrick S. Michael

    2015-08-01

    Full Text Available  In poor soils, addition of alkaline sandy loam containing an adequate proportion of sand, silt and clay would add value by improving the texture, structure and organic matter (OM for general use of the soils. In acid sulfate soils (ASS, addition of alkaline sandy would improve the texture and leach out salts as well as add a sufficient proportion of OM for vegetation establishment. In this study, addition of alkaline sandy loam into sulfuric soil effectively increased the pH, lowered the redox and reduced the sulfate content, the magnitude of the effects dependent on moisture content. Addition of alkaline sandy loam in combination with OM was highly effective than the effects of the lone alkaline sandy loam. When alkaline sandy was added alone or in combination with OM into sulfidic soil, the effects on pH and the redox were similar as in the sulfuric soil but the effect on sulfate content was variable. The effects under aerobic conditions were higher than under anaerobic conditions. The findings of this study have important implications for the general management of ASS where lime availability is a concern and its application is limited.International Journal of Environment Volume-4, Issue-3, June-August 2015Page: 42-54

  18. Controlled release fertilizer increased phytoremediation of petroleum-contaminated sandy soil.

    Science.gov (United States)

    Cartmill, Andrew D; Cartmill, Donita L; Alarcón, Alejandro

    2014-01-01

    A greenhouse experiment was conducted to determine the effect of the application of controlled release fertilizer [(CRF) 0, 4,6, or 8 kg m(-3)] on Lolium multiflorum Lam. survival and potential biodegradation of petroleum hydrocarbons (0, 3000, 6000, or 15000 mg kg(-1)) in sandy soil. Plant adaptation, growth, photosynthesis, total chlorophyll, and proline content as well as rhizosphere microbial population (culturable heterotrophic fungal and bacterial populations) and total petroleum hydrocarbon (TPH)-degradation were determined. Petroleum induced-toxicity resulted in reduced plant growth, photosynthesis, and nutrient status. Plant adaptation, growth, photosynthesis, and chlorophyll content were enhanced by the application of CRF in contaminated soil. Proline content showed limited use as a physiological indicator of petroleum induced-stress in plants. Bacterial and filamentous fungi populations were stimulated by the petroleum concentrations. Bacterial populations were stimulated by CRF application. At low petroleum contamination, CRF did not enhance TPH-degradation. However, petroleum degradation in the rhizosphere was enhanced by the application of medium rates of CRF, especially when plants were exposed to intermediate and high petroleum contamination. Application of CRF allowed plants to overcome the growth impairment induced by the presence of petroleum hydrocarbons in soils.

  19. Incorporated Woodchips as a Novel Intervention to Support Plant Growth through Increased Water Holding Capacity and Nutrient Retention in Sandy Degraded Soils

    Science.gov (United States)

    Menzies, E.; Schneider, R.; Walter, T.

    2017-12-01

    According to the World Wildlife Federation's most recent Plow Print report 53 million acres of temperate, water limited, grasslands across the Great Plains have been converted to agriculture since 2009. This conversion very often begins the process of soil degradation which can lead to desertification and the necessity to convert more land to agriculture. The most common solution to this problem is improved crop efficiency to reduce conversion of grasslands to agriculture while still producing enough food for us all. We suggest that while that may be the beginning of the solution, degraded soils need to be rehabilitated and brought back into production to adequately provide food crops for the increasing population of the globe. Incorporated woodchips can be used to improve the soils' water holding capacity and nutrient (N and P) retention. In a previous study we observed an increase in the gravimetric water content and a decrease in soluble N and P losses when fertilizers were applied in liquid form in soil columns with incorporated woodchips (see attached figure). In this study we examine the availability of the retained water and nutrients to grasses to determine the extent to which this intervention might be used to reestablish plant growth in degraded sandy soils. We also begin examining the quantity of woodchips necessary to retain sufficient water and nutrients to sustain the growth of grasses over the course of a growing season. A laboratory soil column study is currently underway to examine these questions; the results of this study will be presented at the Fall Meeting.

  20. Reducing Nutrient Losses with Directed Fertilization of Degraded Soils

    Science.gov (United States)

    Menzies, E.; Walter, M. T.; Schneider, R.

    2016-12-01

    Degraded soils around the world are stunting agricultural productivity in places where people need it the most. In China, hundreds of years of agriculture and human activity have turned large swaths of productive grasslands into expanses of sandy soils where nothing can grow. Returning soils such as these to healthy productive landscapes is crucial to the livelihoods of rural families and to feeding the expanding population of China and the world at large. Buried wood chips can be used to improve the soils' water holding capacity but additional nutrient inputs are crucial to support plant growth and completely restore degraded soils in China and elsewhere. Improperly applied fertilizer can cause large fluxes of soluble nutrients such as nitrogen (N) and phosphorus (P) to pollute groundwater, and reach surface water bodies causing harmful algal blooms or eutrophication. Similarly, fertilization can create increases in nutrient losses in the form of greenhouse gases (GHGs). It is imperative that nutrient additions to this system be done in a way that fosters restoration and a return to productivity, but minimizes nutrient losses to adjacent surface water bodies and the atmosphere. The primary objective of this study is to characterize soluble and gaseous N and P losses from degraded sandy soils with wood chip and fertilizer amendments in order to identify optimal fertilization methods, frequencies, and quantities for soil restoration. A laboratory soil column study is currently underway to begin examining these questions results of this study will be presented at the Fall Meeting.

  1. Reclamation status of a degraded pasture based on soil health indicators

    Directory of Open Access Journals (Sweden)

    Cristiane Alcantara dos Santos

    2015-06-01

    Full Text Available Pasture degradation is a concern, especially in susceptible sandy soils for which strategies to recover them must be developed. Microbiological and biochemical soil health indicators are useful in the guindace of soil management practices and sustainable soil use. We assessed the success of threePanicum maximum Jacq. cultivars in the reclamation of a pasture in a sandy Typic Acrudox in the northwest of the state of Paraná, Brazil, based on soil health indicators. On a formerly degraded pasture withUrochloa brizantha (Hochst. ex A. Rich. R.D. Webster, a trial with threeP. maximum (cv. Massai, Tanzânia, or Mombaça was conducted. Lime and phosphate were applied at set-up, and mineral N and K as topdressing. A remnant of degraded pasture adjacent to the trial was used as control. Twenty-three chemical, physical, microbiological and biochemical attributes were assessed for the 0-10 cm topsoil. The procedures for reclamation improved most of the indicators of soil health in relation to the degraded pasture, such as soil P, mineral N, microbial biomass C, ammonification rate, dehydrogenase activity and acid phosphatase. CO2 evolution decreased, whereas microbial biomass C increased in the pasture under reclamation, resulting in a lower metabolic quotient (qCO2 that points to a decrease in metabolic stress of the microbial community. The reclamation of the pasture withP. maximum, especially cv. Mombaça, were evidenced by improvements in the microbiological and biochemical soil health indicators, showing a recovery of processes related to C, N and P cycling in the soil.

  2. Radon emanation coefficients in sandy soils

    International Nuclear Information System (INIS)

    Holy, K.; Polaskova, A.; Baranova, A.; Sykora, I.; Hola, O.

    1998-01-01

    In this contribution the results of the study of an influence of the water content on the emanation coefficient for two sandy soil samples are reported. These samples were chosen on the because of the long-term continual monitoring of the 222 Rn concentration just in such types of soils and this radon concentration showed the significant variations during a year. These variations are chiefly given in connection with the soil moisture. Therefore, the determination of the dependence of the emanation coefficient of radon on the water content can help to evaluate the influence of the soil moisture variations of radon concentrations in the soil air. The presented results show that the emanation coefficient reaches the constant value in the wide interval of the water content for both sandy soil samples. Therefore, in the common range of the soil moisture (5 - 20 %) it is impossible to expect the variations of the radon concentration in the soil air due to the change of the emanation coefficient. The expressive changes of the radon concentration in the soil air can be observed in case of the significant decrease of the emanation coefficient during the soil drying when the water content decreases under 5 % or during the complete filling of the soil pores by the water. (authors)

  3. Effects of bioremediation agents on oil degradation in mineral and sandy salt marsh sediments

    International Nuclear Information System (INIS)

    Lin, Q.; Mendelssohn, I.A.; Henry, C.B. Jr.; Roberts, P.O.; Walsh, M.M.; Overton, E.B.; Portier, R.J.

    1999-01-01

    Although bioremediation for oil spill cleanup has received considerable attention in recent years, its satisfactory use in the cleanup of oil spills in the wetland environment is still generally untested. A study of the often most used bioremediation agents, fertiliser, microbial product and soil oxidation, as a means of enhancing oil biodegradation in coastal mineral and sandy marsh substrates was conducted in controlled greenhouse conditions. Artificially weathered south Louisiana crude oil was applied to sods of marsh (soil and intact vegetation) at the rate of 2 l m -2 . Fertiliser application enhanced marsh plant growth, soil microbial populations, and oil biodegradation rate. The live aboveground biomass of Spartina alterniflora with fertiliser application was higher than that without fertiliser. The application of fertiliser significantly increased soil microbial respiration rates, indicating the potential for enhancing oil biodegradation. Bioremediation with fertiliser application significantly reduced the total targeted normal hydrocarbons (TTNH) and total targeted aromatic hydrocarbons (TTAH) remaining in the soil, by 81% and 17%, respectively, compared to those of the oil controls. TTNH/hopane and TTAAH/hopane ratios showed a more consistent reduction, further suggesting an enhancement of oil biodegradation by fertilisation. Furthermore, soil type affected oil bioremediation; the extent of fertiliser-enhanced oil biodegradation was greater for sandy (13% TTNH remaining in the treatments with fertiliser compared to the control) than for mineral soils (26% of the control), suggesting that fertiliser application was more effective in enhancing TTNH degradation in the former. Application of microbial product and soil oxidant had no positive effects on the variables mentioned above under the present experimental conditions, suggesting that microbial degraders are not limiting biodegradation in this soil. Thus, the high cost of microbial amendments during

  4. Bacterial polyextremotolerant bioemulsifiers from arid soils improve water retention capacity and humidity uptake in sandy soil

    KAUST Repository

    Raddadi, Noura

    2018-05-31

    Water stress is a critical issue for plant growth in arid sandy soils. Here, we aimed to select bacteria producing polyextremotolerant surface-active compounds capable of improving water retention and humidity uptake in sandy soils.From Tunisian desert and saline systems, we selected eleven isolates able to highly emulsify different organic solvents. The bioemulsifying activities were stable with 30% NaCl, at 4 and 120 °C and in a pH range 4-12. Applications to a sandy soil of the partially purified surface-active compounds improved soil water retention up to 314.3% compared to untreated soil. Similarly, after 36 h of incubation, the humidity uptake rate of treated sandy soil was up to 607.7% higher than untreated controls.Overall, results revealed that polyextremotolerant bioemulsifiers of bacteria from arid and desert soils represent potential sources to develop new natural soil-wetting agents for improving water retention in arid soils.

  5. Bacterial polyextremotolerant bioemulsifiers from arid soils improve water retention capacity and humidity uptake in sandy soil

    KAUST Repository

    Raddadi, Noura; Giacomucci, Lucia; Marasco, Ramona; Daffonchio, Daniele; Cherif, Ameur; Fava, Fabio

    2018-01-01

    Water stress is a critical issue for plant growth in arid sandy soils. Here, we aimed to select bacteria producing polyextremotolerant surface-active compounds capable of improving water retention and humidity uptake in sandy soils.From Tunisian desert and saline systems, we selected eleven isolates able to highly emulsify different organic solvents. The bioemulsifying activities were stable with 30% NaCl, at 4 and 120 °C and in a pH range 4-12. Applications to a sandy soil of the partially purified surface-active compounds improved soil water retention up to 314.3% compared to untreated soil. Similarly, after 36 h of incubation, the humidity uptake rate of treated sandy soil was up to 607.7% higher than untreated controls.Overall, results revealed that polyextremotolerant bioemulsifiers of bacteria from arid and desert soils represent potential sources to develop new natural soil-wetting agents for improving water retention in arid soils.

  6. Bacterial polyextremotolerant bioemulsifiers from arid soils improve water retention capacity and humidity uptake in sandy soil.

    Science.gov (United States)

    Raddadi, Noura; Giacomucci, Lucia; Marasco, Ramona; Daffonchio, Daniele; Cherif, Ameur; Fava, Fabio

    2018-05-31

    Water stress is a critical issue for plant growth in arid sandy soils. Here, we aimed to select bacteria producing polyextremotolerant surface-active compounds capable of improving water retention and humidity uptake in sandy soils. From Tunisian desert and saline systems, we selected eleven isolates able to highly emulsify different organic solvents. The bioemulsifying activities were stable with 30% NaCl, at 4 and 120 °C and in a pH range 4-12. Applications to a sandy soil of the partially purified surface-active compounds improved soil water retention up to 314.3% compared to untreated soil. Similarly, after 36 h of incubation, the humidity uptake rate of treated sandy soil was up to 607.7% higher than untreated controls. Overall, results revealed that polyextremotolerant bioemulsifiers of bacteria from arid and desert soils represent potential sources to develop new natural soil-wetting agents for improving water retention in arid soils.

  7. Preparation of Sandy Soil Stabilizer for Roads Based on Radiation Modified Polymer Composite

    International Nuclear Information System (INIS)

    Elnahas, H.H.

    2016-01-01

    Radiation modified polymer composite (RMPC) was studied to build an extremely durable sandy road, construct a trail or bath, or control dust and erosion. A dilute solution of composite binds sandy soil fines through a coagulation bonding process. The result is a dense soil structure that has superior resistance to cracks and water penetration and can also solve erosion control problems. In erosion control applications, diluted composite is merely sprayed into sandy soil without compaction, effectively sealing the surface to prevent air-born dust or deterioration from erosion. The prepared composite has an elastic and melt-able film formation that imparts thermal compacting to the stabilized sandy soil after full dryness for sandy road leveling, repairing and restoration processes. The prepared composite is environmentally economical when compared with traditional sandy soil stabilizing (SSS) or sealing methods.

  8. EFFECT OF IRRIGATION INTERVAL AND SOIL AMENDMENTS ON SOIL ORGANIC C, NITROGEN AND POTASSIUM OF SANDY SOIL AND GROWTH OF Jatropha curcas L.

    Directory of Open Access Journals (Sweden)

    Djajadi

    2013-06-01

    Full Text Available Inherently, sandy soil is the unfertile soil with low in all aspects of soil fertility and has a low capacity to retain water applied nutrients. To improve the fertility of sandy soil as media growth of Jatropha curcas, clay and organic matter may have important role when they are incorporated to the sandy soil. This study investigated the effect of irrigation interval and incorporation of clay together with organic matter to sandy soil on soil organic C, N, and K and growth of J. curcas. The rates of clay and organic matter incorporated to top sandy soil were 5% clay + 0.8% organic matter and 10% clay + 1.6% organic matter. Two irrigation intervals tested were 10 day and 20 day. The results found that incorporation of 10% clay + 1.6% organic matter to sandy soil increased soil C organic, N total and exchangeable K which in turn increased number of leaves and number of lateral branches of J curcas. Irrigation intervals had no effect on all parameters observed.

  9. Migration characteristics of cobalt-60 through sandy soil in high pH solution

    International Nuclear Information System (INIS)

    Ohnuki, Toshihiko

    1992-01-01

    Migration characteristics of 60 Co through sandy soil in high pH solution has been investigated by both column and batch techniques. The association of 60 Co with the sandy soil and its components were studied by sequential extraction techniques. The concentration profile of 60 Co in the sandy soil column was composed of two exponential curves showing that 60 Co would consist of immobile and mobile fractions. The immobile 60 Co was retained by the sandy soil and was distributed near the top. Though the mobile 60 Co was little sorbed by soil and migrated through the soil column, maximum concentration of 60 Co in the effluents decreased slightly with increasing path length of the soil column. The sequential extraction of 60 Co from the sandy soil and from its components showed that 60 Co was sorbed by both manganese oxide and clay minerals. And manganese oxide is one of the responsible soil components for the observed decrease in the maximum concentration of 60 Co in the effluents. Although the content of manganese oxide in the sandy soil was 0.13%, manganese oxide is the important component to prevent from the migration of 60 Co in the high pH solution. (author)

  10. Effects of Pisha sandstone content on solute transport in a sandy soil.

    Science.gov (United States)

    Zhen, Qing; Zheng, Jiyong; He, Honghua; Han, Fengpeng; Zhang, Xingchang

    2016-02-01

    In sandy soil, water, nutrients and even pollutants are easily leaching to deeper layers. The objective of this study was to assess the effects of Pisha sandstone on soil solute transport in a sandy soil. The miscible displacement technique was used to obtain breakthrough curves (BTCs) of Br(-) as an inert non-adsorbed tracer and Na(+) as an adsorbed tracer. The incorporation of Pisha sandstone into sandy soil was able to prevent the early breakthrough of both tracers by decreasing the saturated hydraulic conductivity compared to the controlled sandy soil column, and the impeding effects increased with Pisha sandstone content. The BTCs of Br(-) were accurately described by both the convection-dispersion equation (CDE) and the two-region model (T-R), and the T-R model fitted the experimental data slightly better than the CDE. The two-site nonequilibrium model (T-S) accurately fit the Na(+) transport data. Pisha sandstone impeded the breakthrough of Na(+) not only by decreasing the saturated hydraulic conductivity but also by increasing the adsorption capacity of the soil. The measured CEC values of Pisha sandstone were up to 11 times larger than those of the sandy soil. The retardation factors (R) determined by the T-S model increased with increasing Pisha sandstone content, and the partition coefficient (K(d)) showed a similar trend to R. According to the results of this study, Pisha sandstone can successfully impede solute transport in a sandy soil column. Copyright © 2015 Elsevier Ltd. All rights reserved.

  11. Physical Properties of Sandy Soil Affected by Soil Conditioner Under Wetting and Drying cycles

    Directory of Open Access Journals (Sweden)

    M.I. Choudhary

    1998-06-01

    Full Text Available Information on the effectiveness of soil conditioners over a prolonged period is scarce. A laboratory experiment was undertaken to evaluate the effectiveness of a polyacrylamide (Broadleaf P4 soil conditioner on the physical properties of sandy soil subjected to wetting and drying cycles. Four concentrations of Broadleaf P4 0, 0.2, 0.4, and 0.6% on dry weight basis were uniformly mixed with a calcareous sandy soil. Addition of Broadleaf P4 to sandy soil increased the water holding capacity, decreased the bulk density, and increased the porosity and void ratio at 0 and 16 wetting and drying cycles. The coefficient of linear extensibility increased considerably with increasing concentrations of the polymer. The addition of polymer at 0 and 16 cycles increased considerably the retention and availability of water in sandy soil. Saturated hydraulic conductivity decreased with increasing concentrations of Broadleaf P4 whereas unsaturated hydraulic conductivity at 0 and 16 cycles showed an increase with increasing soil moisture contents. After I6 wetting and drying cycles, the capacity of the soil to hold water was lost on average by 15.8% when compared to the 0 wetting and drying cycle. The effectiveness of the soil conditioner on bulk density, coefficient of linear extensibility, available water and saturated hydraulic conductivity was reduced on average by 14.1, 24.5, 21.l and 53.7% respectively. The significant changes in soil properties between 0 and 16 cycles suggested that the effectiveness of the conditioner decreased with the application of wetting and drying cycles. However, its effect was still considerable when compared to untreated soil under laboratory conditions.

  12. Assessment of grass root effects on soil piping in sandy soils using the pinhole test

    Science.gov (United States)

    Bernatek-Jakiel, Anita; Vannoppen, Wouter; Poesen, Jean

    2017-10-01

    Soil piping is an important land degradation process that occurs in a wide range of environments. Despite an increasing number of studies on this type of subsurface erosion, the impact of vegetation on piping erosion is still unclear. It can be hypothesized that vegetation, and in particular plant roots, may reduce piping susceptibility of soils because roots of vegetation also control concentrated flow erosion rates or shallow mass movements. Therefore, this paper aims to assess the impact of grass roots on piping erosion susceptibility of a sandy soil. The pinhole test was used as it provides quantitative data on pipeflow discharge, sediment concentration and sediment discharge. Tests were conducted at different hydraulic heads (i.e., 50 mm, 180 mm, 380 mm and 1020 mm). Results showed that the hydraulic head was positively correlated with pipeflow discharge, sediment concentration and sediment discharge, while the presence of grass roots (expressed as root density) was negatively correlated with these pipeflow characteristics. Smaller sediment concentrations and sediment discharges were observed in root-permeated samples compared to root-free samples. When root density exceeds 0.5 kg m- 3, piping erosion rates decreased by 50% compared to root-free soil samples. Moreover, if grass roots are present, the positive correlation between hydraulic head and both sediment discharge and sediment concentration is less pronounced, demonstrating that grass roots become more effective in reducing piping erosion rates at larger hydraulic heads. Overall, this study demonstrates that grass roots are quite efficient in reducing piping erosion rates in sandy soils, even at high hydraulic head (> 1 m). As such, grass roots may therefore be used to efficiently control piping erosion rates in topsoils.

  13. Effects of plant cover on soil N mineralization during the growing season in a sandy soil

    Science.gov (United States)

    Yao, Y.; Shao, M.; Wei, X.; Fu, X.

    2017-12-01

    Soil nitrogen (N) mineralization and its availability plays a vital role in regulating ecosystem productivity and C cycling, particularly in semiarid and desertified ecosystems. To determine the effect of plant cover on N turnover in a sandy soil ecosystem, we measured soil N mineralization and inorganic N pools in soil solution during growing season in a sandy soil covered with various plant species (Artemisia desertorum, Salix psammophila, and Caragana korshinskii). A bare sandy soil without any plant was selected as control. Inorganic N pools and N mineralization rates decreased overtime during the growing season, and were not affected by soil depth in bare land soils, but were significantly higher at the 0-10 cm layer than those at the 10-20 cm soil layer under any plant species. Soil inorganic N pool was dominated by ammonium, and N mineralization was dominated by nitrification regardless of soil depth and plant cover. Soils under C. korshinskii have significant higher inorganic N pools and N mineralization rate than soils under bare land and A. desertorum and S. psammophila, and the effects of plant cover were greater at the 0-10 cm soil layer than at the 10-20 cm layer. The effects of C. korshinskii on soil inorganic N pools and mineralization rate varied with the stage of growing season, with greater effects on N pools in the middle growing season, and greater effects on mineralization rate at the last half of the growing season. The results from this study indicate that introduction of C. korshinskii has the potential to increase soil N turnover and availability in sandy soils, and thus to decrease N limitation. Caragana korshinskii is therefore recommend for the remediation of the desertified land.

  14. Compost amendment of sandy soil affects soil properties and greenhouse tomato productivity

    DEFF Research Database (Denmark)

    Arthur, Emmanuel; Cornelis, W.; Razzaghi, Fatemeh

    2012-01-01

    Sandy soils, with low productivity, could be improved by compost application to sustain crop production. This study aimed to examine the effect of three compost types (vegetable, fruit and yard waste compost, garden waste compost, and spent mushroom compost) on basic properties of a loamy sand...... compost had greater effect in improving tomato productivity. A decade-long application of composts on loamy sand improved basic chemical and physical properties which were reflected in increased fruit yield in tomato. Since no negative effect of compost was observed, we suggest that sandy soils may serve...... and greenhouse tomato productivity. Disturbed and intact soil samples were taken from a decade-long compost field experiment on loamy sand with three compost types at application rate of 30 m3 ha-1 yr-1 (7.5 ton ha-1 yr-1). The soils were characterized for chemical and physical properties. Tomato was planted...

  15. Migration of cesium-137 through sandy soil layer effect of fine silt on migration

    International Nuclear Information System (INIS)

    Ohnuki, Toshihiko; Wadachi, Yoshiki

    1983-01-01

    The migration of 137 Cs through sandy soil layer was studied with consideration of the migration of fine silt by column method. It was found that a portion of fine silt migrated through the soil layer accompanying with 137 Cs. The mathematical migration model of 137 Cs involved the migration of fine silt through such soil layer was presented. This model gave a good accordance between calculated concentration distribution curve in sandy soil layer and effluent curve and observed those. So, this model seems to be advanced one for evaluating migration of 137 Cs in sandy soil layer with silt. (author)

  16. The fate of fresh and stored 15N-labelled sheep urine and urea applied to a sandy and a sandy loam soil using different application strategies

    DEFF Research Database (Denmark)

    Sørensen, P.; Jensen, E.S.

    1996-01-01

    The fate of nitrogen from N-15-labelled sheep urine and urea applied to two soils was studied under field conditions. Labelled and stored urine equivalent to 204 kg N ha(-1) was either incorporated in soil or applied to the soil surface prior to sowing of Italian ryegrass (Lolium multiflorum L...... and soil was not significantly different for incorporated urine and urea. Almost all the supplied labelled N was accounted for in soil and herbage in the sandy loam soil, whereas 33-34% of the labelled N was unaccounted for in the sandy soil. When the stored urine was applied to the soil surface, 20...... was applied to growing ryegrass at the sandy loam soil, the immobilization of urine-derived N was significantly reduced compared to application prior to sowing. The results indicated that the net mineralization of urine N was similar to that of urea in the sandy soil, but only about 75% of the urine N was net...

  17. Light Gray Surface-Gleyed Loamy Sandy Soils of the Northern Part of Tambov Plain: Agroecology, Properties, and Diagnostics

    Science.gov (United States)

    Zaidel'man, F. R.; Stepantsova, L. V.; Nikiforova, A. S.; Krasin, V. N.; Dautokov, I. M.; Krasina, T. V.

    2018-04-01

    Light gray soils of Tambov oblast mainly develop from sandy and loamy sandy parent materials; these are the least studied soils in this region. Despite their coarse texture, these soils are subjected to surface waterlogging. They are stronger affected by the agrogenic degradation in comparison with chernozems and dark gray soils. Morphology, major elements of water regime, physical properties, and productivity of loamy sandy light gray soils with different degrees of gleyzation have been studied in the northern part of Tambov Plain in order to substantiate the appropriate methods of their management. The texture of these soils changes at the depth of 70-100 cm. The upper part is enriched in silt particles (16-30%); in the lower part, the sand content reaches 80-85%. In the nongleyed variants, middle-profile horizons contain thin iron-cemented lamellae (pseudofibers); in surface-gleyed variants, iron nodules are present in the humus horizon. The removal of clay from the humus horizon and its accumulation at the lithological contact and in pseudofibers promote surface subsidence and formation of microlows in the years with moderate and intense winter precipitation. The low range of active moisture favors desiccation of the upper horizons to the wilting point in dry years. The yield of cereal crops reaches 3.5-4.5 t/ha in the years with high and moderate summer precipitation on nongleyed and slightly gleyed light gray soils and decreases by 20-50% on strongly gleyed light gray soils. On light gray soils without irrigation, crop yields are unstable, and productivity of pastures is low. High yields of cereals and vegetables can be obtained on irrigated soils. In this case, local drainage measures should be applied to microlows; liming can be recommended to improve soil productivity.

  18. Fine-scale spatial distribution of plants and resources on a sandy soil in the Sahel

    NARCIS (Netherlands)

    Rietkerk, M.G.; Ouedraogo, T.; Kumar, L.; Sanou, S.; Langevelde, F. van; Kiema, A.; Koppel, J. van de; Andel, J. van; Hearne, J.; Skidmore, A.K.; Ridder, N. de; Stroosnijder, L.; Prins, H.H.T.

    2002-01-01

    We studied fine-scale spatial plant distribution in relation to the spatial distribution of erodible soil particles, organic matter, nutrients and soil water on a sandy to sandy loam soil in the Sahel. We hypothesized that the distribution of annual plants would be highly spatially autocorrelated

  19. Evaluation of Diuron Tolerance and Biotransformation by Fungi from a Sugar Cane Plantation Sandy-Loam Soil.

    Science.gov (United States)

    Perissini-Lopes, Bruna; Egea, Tássia Chiachio; Monteiro, Diego Alves; Vici, Ana Cláudia; Da Silva, Danilo Grünig Humberto; Lisboa, Daniela Correa de Oliveira; de Almeida, Eduardo Alves; Parsons, John Robert; Da Silva, Roberto; Gomes, Eleni

    2016-12-14

    Microorganisms capable of degrading herbicides are essential to minimize the amount of chemical compounds that may leach into other environments. This work aimed to study the potential of sandy-loam soil fungi to tolerate the herbicide Herburon (50% diuron) and to degrade the active ingredient diuron. Verticillium sp. F04, Trichoderma virens F28, and Cunninghamella elegans B06 showed the highest growth in the presence of the herbicide. The evaluation of biotransformation showed that Aspergillus brasiliensis G08, Aspergillus sp. G25, and Cunninghamella elegans B06 had the greatest potential to degrade diuron. Statistical analysis demonstrated that glucose positively influences the potential of the microorganism to degrade diuron, indicating a cometabolic process. Due to metabolites founded by diuron biotransformation, it is indicated that the fungi are relevant in reducing the herbicide concentration in runoff, minimizing the environmental impact on surrounding ecosystems.

  20. Degradation of hydrocarbons in soil samples analyzed within accepted analytical holding times

    International Nuclear Information System (INIS)

    Jackson, J.; Thomey, N.; Dietlein, L.F.

    1992-01-01

    Samples which are collected in conjunction with subsurface investigations at leaking petroleum storage tank sites and petroleum refineries are routinely analyzed for benzene, toluene, ethylbenzene, xylenes (BTEX), and total petroleum hydrocarbons (TPH). Water samples are preserved by the addition of hydrochloric acid and maintained at four degrees centigrade prior to analysis. This is done to prevent bacterial degradation of hydrocarbons. Chemical preservation is not presently performed on soil samples. Instead, the samples are cooled and maintained at four degrees centigrade. This study was done to measure the degree of degradation of hydrocarbons in soil samples which are analyzed within accepted holding times. Soil samples were collected and representative subsamples were prepared from the initial sample. Subsamples were analyzed in triplicate for BTEX and TPH throughout the length of the approved holding times to measure the extent of sample constituent degradation prior to analysis. Findings imply that for sandy soils, BTEX and TPH concentrations can be highly dependent upon the length of time which elapses between sample collection and analysis

  1. Organic Carbon and Physical Properties in Sandy Soil after Conversion from Degraded Pasture to Eucalyptus in the Brazilian Cerrado

    Directory of Open Access Journals (Sweden)

    Karla Nascimento Sena

    Full Text Available ABSTRACT Soil is currently seen as the most relevant carbon sink and the most effective carbon stabilizer. In contrast, agriculture is the second largest C emitter, after burning of fossil fuels. This organic carbon (OC introduced into the soil, mainly via organic matter (OM, is essential for several soil properties and plays an extremely important role in sandy soils. The objective of this study was to describe the changes in the amounts and pools of OC and the influence thereof on some physical soil properties in areas converted from pasture to eucalyptus. The following areas were analyzed: a degraded pasture (PAST, two areas of pasture-eucalyptus conversion after 2 and 15 years (EU02 and EU15, respectively and a preserved Cerrado area (CER in the east of the state of Mato Grosso do Sul. Soil samples were taken from the 0.00-0.05, 0.05-0.10, and 0.10-0.30 m layers. The OC was measured and analyzed, the carbon pool (CP calculated, aggregate stability, bulk density (BD, and macro- and microporosity determined, and total porosity (TP calculated to analyze the influence of land use on soil properties. The experimental design was completely randomized, and four clusters per area were established, with nine subsampling points, for a total of 36 subsamples per area, organized in 20 × 20 m grids, The soil under natural vegetation (preserved Cerrado was used as a control. The change from CER to commercial cultivation accelerates the process of OC loss (reductions of 25-35 % and reductions in soil physical quality. In the PAST area, OC was reduced by 30 % in the 0.00-0.05 m layer. Cumulative OC and CP were highest in the 0.00-0.05 m layer and decreased in the deeper layers in all land use treatments. Organic C in the 0.10-0.30 m layer was not influenced by land use, indicating the possibility of OC persistence in the soil for longer periods. Macroporosity and total porosity may be considered appropriate in CER and EU15, whereas the conditions for plant

  2. Use of dolomite phosphate rock (DPR) fertilizers to reduce phosphorus leaching from sandy soil

    International Nuclear Information System (INIS)

    Chen, G.C.; He, Z.L.; Stoffella, P.J.; Yang, X.E.; Yu, S.; Calvert, D.

    2006-01-01

    There is increasing concern over P leaching from sandy soils applied with water-soluble P fertilizers. Laboratory column leaching experiments were conducted to evaluate P leaching from a typical acidic sandy soil in Florida amended with DPR fertilizers developed from dolomite phosphate rock (DPR) and N-Viro soil. Ten leaching events were carried out at an interval of 7 days, with a total leaching volume of 1183 mm equivalent to the mean annual rainfall of this region during the period of 2001-2003. Leachates were collected and analyzed for total P and inorganic P. Phosphorus in the leachate was dominantly reactive, accounting for 67.7-99.9% of total P leached. Phosphorus leaching loss mainly occurred in the first three leaching events, accounting for 62.0-98.8% of the total P leached over the whole period. The percentage of P leached (in the total P added) from the soil amended with water-soluble P fertilizer was higher than those receiving the DPR fertilizers. The former was up to 96.6%, whereas the latter ranged from 0.3% to 3.8%. These results indicate that the use of N-Viro-based DPR fertilizers can reduce P leaching from sandy soils. - Fertilizers developed from dolomite phosphate rock (DPR) reduce phosphorus leaching from sandy soil

  3. Effect of Particle Size and Soil Compaction on Gas Transport Parameters in Variably Saturated, Sandy Soils

    DEFF Research Database (Denmark)

    Hamamoto, Shoichiro; Møldrup, Per; Kawamoto, Ken

    2009-01-01

    The soil gas diffusion coefficient (Dp) and air permeability (ka) and their dependency on soil air content ( ) control gas diffusion and advection in soils. This study investigated the effects of average particle size (D50) and dry bulk density ( b) on Dp and ka for six sandy soils under variably...

  4. Microbial degradation of street dust polycyclic aromatic hydrocarbons in microcosms simulating diffuse pollution of urban soil

    DEFF Research Database (Denmark)

    Johnsen, Anders R; de Lipthay, Julia R; Sørensen, Søren J

    2006-01-01

    Diffuse pollution with polycyclic aromatic hydrocarbons (PAHs) of topsoil in urban regions has caused increasing concerns in recent years. We simulated diffuse pollution of soil in microcosms by spiking sandy topsoil (A-horizon) and coarse, mineral subsoil (C-horizon) with street dust (PM63...... for the persistence and low bioaccessibility of 5- and 6-ring PAHs in diffusely polluted soil.......) isolated from municipal street sweepings from central Copenhagen. The microbial communities adapted to PAH degradation in microcosms spiked with street dust in both A-horizon and C-horizon soils, in spite of low PAH-concentrations. The increased potential for PAH degradation was demonstrated on several...

  5. Soil Seed Bank and Plant Community Development in Passive Restoration of Degraded Sandy Grasslands

    Directory of Open Access Journals (Sweden)

    Renhui Miao

    2016-06-01

    Full Text Available To evaluate the efficacy of passive restoration on soil seed bank and vegetation recovery, we measured the species composition and density of the soil seed bank, as well as the species composition, density, coverage, and height of the extant vegetation in sites passively restored for 0, 4, 7, and 12 years (S0, S4, S7, and S12 in a degraded grassland in desert land. Compared with S0, three more species in the soil seed bank at depths of 0–30 cm and one more plant species in the community was detected in S12. Seed density within the topsoil (0–5 cm was five times higher in S12 than that in S0. Plant densities in S7 and S12 were triple and quadruple than that in S0. Plant coverage was increased by 1.5 times (S4, double (S7, and triple (S12 compared with S0. Sørensen’s index of similarity in species composition between the soil seed bank and the plant community were high (0.43–0.63, but it was lower in short-term restoration sites (S4 and S7 than that in no and long-term restoration sites (S0 and S12. The soil seed bank recovered more slowly than the plant community under passive restoration. Passive restoration is a useful method to recover the soil seed bank and vegetation in degraded grasslands.

  6. CONTRIBUTIONS TO IMPROVING CULTURE TEHNOLOGIES OF PEACHES GROWN ON SANDY SOILS THE SOUTH OF OLTENIA

    Directory of Open Access Journals (Sweden)

    Anica Durau

    2013-12-01

    Full Text Available Technological factors with major implications in obtaining high yields and quality in peaches grown on sandy soils are planting row distance and shape of the crown, soil maintenance system, chemical, organic and foliar fertilzation. A smal size combined with the flatening of the crowns of the tres alows a dense planting, also ensure proper mechanization of work and easy penetration of light to the leaves and fruits. Crown form vertical belt proved to be suitable for al planting distances studied, easily made and maintained, having fruit production ranged betwen 15.9 t / ha at a distance of 2 m, 10.3 t / ha at a distance of 2.5 m and 7.9 t / ha at a distance of 3 m. The state of soil nutrient supply influence sucesful peach crop on sandy soils. The fertilzer dose of technology to N10 P80 K10 kg s.a / ha production was 34.9 t / ha. Organic fertilzation also contributes to obtaining high yields of peach. In sandy soil conditions most fruit production of 9.6 t / ha was obtained by fertilzation with organic manure 60t/ha. Besides fertilzation, soil maintenance system is one important link in the technology peach crop on sandy soils. The results found that the biggest peach fruit production was obtained from field maintenance system black-8,2t/ha. Using technology in foliar peaches culture on sandy soils, is an important means of providing nutrients that lead to improved proceses of growth and fructification. The best way is with foliar fertilzation Folibor in dose 5l/ha, the production obtained was 12.4 t /ha.

  7. Soil water retention, air flow and pore structure characteristics after corn cob biochar application to a tropical sandy loam

    DEFF Research Database (Denmark)

    Amoakwah, Emmanuel; Frimpong, Kwame Agyei; Okae-Anti, D

    2017-01-01

    Soil structure is a key soil physical property that affects soil water balance, gas transport, plant growth and development, and ultimately plant yield. Biochar has received global recognition as a soil amendment with the potential to ameliorate the structure of degraded soils. We investigated how...... corn cob biochar contributed to changes in soil water retention, air flow by convection and diffusion, and derived soil structure indices in a tropical sandy loam. Intact soil cores were taken from a field experiment that had plots without biochar (CT), and plots each with 10 t ha− 1 (BC-10), 20 t ha...... to significant increase in soil water retention compared to the CT and BC-10 as a result of increased microporosity (pores biochar had minimal impact. No significant influence of biochar was observed for ka and Dp/D0 for the BC treatments compared to the CT despite...

  8. Effect of Irrigation Water Type on Infiltration Rates of Sandy Soil

    International Nuclear Information System (INIS)

    Al-Omran, A.M.; Al-Matrood, S.M.; Choudhary, M.I.

    2004-01-01

    A laboratory experiment was conducted to test the effect of three water types (tap water, well water and sewage water) on the infiltration rate of three soils varying in texture (sand. loamy sand and sandy loam). A stationary rainfall simulator dispensing water at a rate of 45 mm h-1, connected to the different sources of water, was used to measure the infiltration rates. A total of 5 runs were carried out using each water quality. The volume of runoff against the time was recorded at each 5 minute interval. The infiltration rate was calculated as the difference between the water applied and the excesses water measured as surface runoff. Infiltration rate at first run were rapid in all the three soils and then progressively declined as the number of runs increased. The same trend was observed for each water quality tested. The reduction in infiltration rate with increasing number of runs for prewetted surface than for the initial dry surface was attributed to break down and settling of fine particles that took place earlier during prewetting. The infiltration curves for all the three soils when irrigared with different qualities of water was not distinguishable. The relationship between infiltration rate as function of time for the treatments applied were tested using Kostiakov equation I=bt-n. The infiltration data gave a coefficient of determination R2 >0.90 for all the treatments. The infiltration parameters B, and n varied strongly with respect to soil texture. Values of B decreased with changing soil textures, being highest for the sandy soil, and lowest for the sandy loamy soil, whereas n values showed the opposite trend. It was concluded that effect of soil texture on the infiltration rate was very pronounced while water qualities showed a little effect. (author)

  9. An Experimental Study of Portland Cement and Superfine Cement Slurry Grouting in Loose Sand and Sandy Soil

    Directory of Open Access Journals (Sweden)

    Weijing Yao

    2018-04-01

    Full Text Available Grouting technology is widely applied in the fields of geotechnical engineering in infrastructure. Loose sand and sandy soil are common poor soils in tunnel and foundation treatments. It is necessary to use superfine cement slurry grouting in the micro-cracks of soil. The different effectiveness of Portland cement slurry and superfine cement slurry in sandy soil by the laboratory grouting experiment method were presented in this paper. The grouting situations of superfine cement slurry injected into sand and sandy soil were explored. The investigated parameters were the dry density, wet density, moisture content, internal friction angle, and cohesion force. The results show that the consolidation effect of superfine cement is better than that of Portland cement due to the small size of superfine cement particles. The superfine cement can diffuse into the sand by infiltration, extrusion, and splitting. When the water–cement ratio of superfine cement slurry is less than 2:1 grouting into loose sand, the dry and wet density decrease with the increase in the water–cement ratio, while the moisture content and cohesive force gradually increase. When the water–cement ratio of superfine cement slurry is 1:1 grouting into loose sand and sandy soil, the dry density, wet density, and cohesive force of loose sand are larger than those of sandy soil. The results of the experiment may be relevant for engineering applications.

  10. ACHIEVEMENTS AND PERSPECTIVES ON STONE FRUIT GROWING ON SANDY SOILS

    Directory of Open Access Journals (Sweden)

    Anica Durău

    2012-01-01

    Full Text Available Climatic conditions in the sandy soils of southern Oltenia encourage cultivation of tree species in terms of applying specific technologies. Possibility of poor sandy soils fertile capitalization, earliness in 7- 10 days of fruit ripening , high yields and quality are the main factors supporting the development of fruit growing in the sandy soils of southern Oltenia. The main objectives of the research were to CCDCPN Dăbuleni. Establish and improve stone fruit species assortment, adapted to the stress of the sandy soils, establishment and evaluation of the influence of stress on trees and their influence on the size and quality of production, development of technological links (planting distances, forms management, fertilization, getting high and consistent annual production of high quality, containing low as pesticide residues, to establish a integrated health control program of the trees with emphasis on biotechnical. Research has shown good stone species behavior, and their recommended proportion is 75% of all fruit trees (peach 36%, 14% apricot, plum15%, sweet and sour cherry fruit growing 10% of the total area. Results on peach varieties revealed: ’Redhaven’, ’Suncrest’, ’Loring’ with yields ranging from (24.8 t / ha to 29.0 t/ha with maturation period from July to August, and varieties ’NJ 244’, ’Fayette’, ’Flacara’ with productions ranging from (19.7 t / ha to 23.0 t/ha with maturation period from August to September. The sweet cherry varieties ’Van’, ’Rainier’, ’Stella’, with yields ranging from 17. 2 to 24.4 t / ha. In the range studied sour cherry were found ’Oblacinska’ varieties of 11.0 t / ha, ’Cernokaia’ with 10.5 t / ha, ’Schatten Morelle’ with 9.1 t / ha. Optimum planting density and shape of the peach crown found that the highest yields of fruit are produced in the form of vertical cordon crown, with values ranging from 15.9 t / ha at a distance of 2 m, 10.3 t / ha at a distance

  11. Amelioration of sandy soils in drought stricken areas through use of ...

    African Journals Online (AJOL)

    Soil moisture shortage is a major limiting factor to agricultural production in eastern Africa, in view of increased drought incidences and seasonal rainfall variability. This study evaluated the potential for Ca-bentonite (a 2:1 clay mineral) as a possible amendment for increased moisture retention by sandy soils in drought ...

  12. Effect of Biochar Amendment and Ageing on Adsorption and Degradation of Two Herbicides.

    Science.gov (United States)

    Zhelezova, Alena; Cederlund, Harald; Stenström, John

    2017-01-01

    Biochar amendment can alter soil properties, for instance, the ability to adsorb and degrade different chemicals. However, ageing of the biochar, due to processes occurring in the soil over time, can influence such biochar-mediated effects. This study examined how biochar affected adsorption and degradation of two herbicides, glyphosate (N-(phosphonomethyl)-glycine) and diuron (3-(3,4-dichlorophenyl)-1,1-dimethylurea) in soil and how these effects were modulated by ageing of the biochar. One sandy and one clayey soil that had been freshly amended with a wood-based biochar (0, 1, 10, 20 and 30% w / w ) were studied. An ageing experiment, in which the soil-biochar mixtures were aged for 3.5 months in the laboratory, was also performed. Adsorption and degradation were studied in these soil and soil-biochar mixtures, and compared to results from a soil historically enriched with charcoal. Biochar amendment increased the pH in both soils and increased the water-holding capacity of the sandy soil. Adsorption of diuron was enhanced by biochar amendment in both soils, while glyphosate adsorption was decreased in the sandy soil. Ageing of soil-biochar mixtures decreased adsorption of both herbicides in comparison with freshly biochar-amended soil. Herbicide degradation rates were not consistently affected by biochar amendment or ageing in any of the soils. However, glyphosate half-lives correlated with the Freundlich Kf values in the clayey soil, indicating that degradation was limited by availability there.

  13. Lasting effects of soil health improvements with management changes in cotton-based cropping systems in a sandy soil

    Science.gov (United States)

    The soil microbial component is essential for sustainable agricultural systems and soil health. This study evaluated the lasting impacts of 5 years of soil health improvements from alternative cropping systems compared to intensively tilled continuous cotton (Cont. Ctn) in a low organic matter sandy...

  14. Remediation of Diesel Fuel Contaminated Sandy Soil using Ultrasonic Waves

    Directory of Open Access Journals (Sweden)

    Wulandari P.S.

    2010-01-01

    Full Text Available Ultrasonic cleaning has been used in industry for some time, but the application of ultrasonic cleaning in contaminated soil is just recently received considerable attention, it is a very new technique, especially in Indonesia. An ultrasonic cleaner works mostly by energy released from the collapse of millions of microscopic cavitations near the dirty surface. This paper investigates the use of ultrasonic wave to enhance remediation of diesel fuel contaminated sandy soil considering the ultrasonic power, soil particle size, soil density, water flow rate, and duration of ultrasonic waves application.

  15. Different Behavior of Enteric Bacteria and Viruses in Clay and Sandy Soils after Biofertilization with Swine Digestate

    Science.gov (United States)

    Fongaro, Gislaine; García-González, María C.; Hernández, Marta; Kunz, Airton; Barardi, Célia R. M.; Rodríguez-Lázaro, David

    2017-01-01

    Enteric pathogens from biofertilizer can accumulate in the soil, subsequently contaminating water and crops. We evaluated the survival, percolation and leaching of model enteric pathogens in clay and sandy soils after biofertilization with swine digestate: PhiX-174, mengovirus (vMC0), Salmonella enterica Typhimurium and Escherichia coli O157:H7 were used as biomarkers. The survival of vMC0 and PhiX-174 in clay soil was significantly lower than in sandy soil (iT90 values of 10.520 ± 0.600 vs. 21.270 ± 1.100 and 12.040 ± 0.010 vs. 43.470 ± 1.300, respectively) and PhiX-174 showed faster percolation and leaching in sandy soil than clay soil (iT90 values of 0.46 and 2.43, respectively). S. enterica Typhimurium was percolated and inactivated more slowly than E. coli O157:H7 (iT90 values of 9.340 ± 0.200 vs. 6.620 ± 0.500 and 11.900 ± 0.900 vs. 10.750 ± 0.900 in clay and sandy soils, respectively), such that E. coli O157:H7 was transferred more quickly to the deeper layers of both soils evaluated (percolation). Our findings suggest that E. coli O157:H7 may serve as a useful microbial biomarker of depth contamination and leaching in clay and sandy soil and that bacteriophage could be used as an indicator of enteric pathogen persistence. Our study contributes to development of predictive models for enteric pathogen behavior in soils, and for potential water and food contamination associated with biofertilization, useful for risk management and mitigation in swine digestate recycling. PMID:28197137

  16. Effects of sodium polyacrylate on water retention and infiltration capacity of a sandy soil.

    Science.gov (United States)

    Zhuang, Wenhua; Li, Longguo; Liu, Chao

    2013-01-01

    Based on the laboratory study, the effects of sodium polyacrylate (SP) was investigated at 5 rates of 0, 0.08, 0.2, 0.5, and 1%, on water retention, saturated hydraulic conductivity(Ks), infiltration characteristic and water distribution profiles of a sandy soil. The results showed that water retention and available water capacity effectively increased with increasing SP rate. The Ks and the rate of wetting front advance and infiltration under certain pond infiltration was significantly reduced by increasing SP rate, which effectively reduced water in a sandy soil leaking to a deeper layer under the plough layer. The effect of SP on water distribution was obviously to the up layer and very little to the following deeper layers. Considering both the effects on water retention and infiltration capacity, it is suggested that SP be used to the sandy soil at concentrations ranging from 0.2 to 0.5%.

  17. An Experimental Study of Portland Cement and Superfine Cement Slurry Grouting in Loose Sand and Sandy Soil

    OpenAIRE

    Weijing Yao; Jianyong Pang; Yushan Liu

    2018-01-01

    Grouting technology is widely applied in the fields of geotechnical engineering in infrastructure. Loose sand and sandy soil are common poor soils in tunnel and foundation treatments. It is necessary to use superfine cement slurry grouting in the micro-cracks of soil. The different effectiveness of Portland cement slurry and superfine cement slurry in sandy soil by the laboratory grouting experiment method were presented in this paper. The grouting situations of superfine cement slurry inject...

  18. Assessment of structural stability of a degraded sandy clay loam soil ...

    African Journals Online (AJOL)

    The effects of bare, two legumes and four grasses cover treatments on the structural stability of a sandy clay loam Ultisol were studied within a two year period. The experiment was of a randomised complete block design with seven treatments. The legume treatments were Centrosema pubescens (Ce) and Pueraria ...

  19. Effect of soil pH on sorption of salinomycin in clay and sandy soils

    African Journals Online (AJOL)

    use

    The sorption of salinomycin to the sandy soil marginally increased as the pH decreased, while the sorption to the two .... plastic containers at room temperature for further analysis. ... The pH was adjusted eight times over 20 days to stabilize at.

  20. [Monitoring of water and salt transport in silt and sandy soil during the leaching process].

    Science.gov (United States)

    Fu, Teng-Fei; Jia, Yong-Gang; Guo, Lei; Liu, Xiao-Lei

    2012-11-01

    Water and salt transport in soil and its mechanism is the key point of the saline soil research. The dynamic rule of water and transport in soil during the leaching process is the theoretical basis of formation, flush, drainage and improvement of saline soil. In this study, a vertical infiltration experiment was conducted to monitor the variation in the resistivity of silt and sandy soil during the leaching process by the self-designed automatic monitoring device. The experimental results showed that the peaks in the resistivity of the two soils went down and faded away in the course of leaching. It took about 30 minutes for sandy soil to reach the water-salt balance, whereas the silt took about 70 minutes. With the increasing leaching times, the desalination depth remained basically the same, being 35 cm for sandy soil and 10 cm for the silt from the top to bottom of soil column. Therefore, 3 and 7 leaching processes were required respectively for the complete desalination of the soil column. The temporal and spatial resolution of this monitoring device can be adjusted according to the practical demand. This device can not only achieve the remote, in situ and dynamic monitoring data of water and salt transport, but also provide an effective method in monitoring, assessment and early warning of salinization.

  1. Expanded uncertainty estimation methodology in determining the sandy soils filtration coefficient

    Science.gov (United States)

    Rusanova, A. D.; Malaja, L. D.; Ivanov, R. N.; Gruzin, A. V.; Shalaj, V. V.

    2018-04-01

    The combined standard uncertainty estimation methodology in determining the sandy soils filtration coefficient has been developed. The laboratory researches were carried out which resulted in filtration coefficient determination and combined uncertainty estimation obtaining.

  2. Study of sandy soil grain-size distribution on its deformation properties

    Science.gov (United States)

    Antropova, L. B.; Gruzin, A. V.; Gildebrandt, M. I.; Malaya, L. D.; Nikulina, V. B.

    2018-04-01

    As a rule, new oil and gas fields' development faces the challenges of providing construction objects with material and mineral resources, for example, medium sand soil for buildings and facilities footings of the technological infrastructure under construction. This problem solution seems to lie in a rational usage of the existing environmental resources, soils included. The study was made of a medium sand soil grain-size distribution impact on its deformation properties. Based on the performed investigations, a technique for controlling sandy soil deformation properties was developed.

  3. Soil organic matter degradation and enzymatic profiles of intertidal and subaqueous soils

    Science.gov (United States)

    Ferronato, Chiara; Marinari, Sara; Bello, Diana; Vianello, Gilmo; Trasar-Cepeda, Carmen; Vittori Antisari, Livia

    2017-04-01

    of epipedons, reflect the influence of the type of annual biomass depositions on ITSs (i.e. Salicornia europaea), but also the important role of the tide oscillation that promotes the continuous alternation of red-ox exchanges and thus fasten the organic matter turnover in ITSs. On these pedons, invertase was the most effective enzymes (11.6 μmol glucose g-1h-1). Moreover, in SASs and ITSs, most of the activities linked to the degradation of exoskeletons and fungi (e.g. chitinase) increase along the soil profile, probably due to the disrupting effect of water on the soil and to the type of SOM in saltmarshes soils. By considering the specific activity (enzymatic activity/TOC content), data showed how SASs, ITSs and TESs had different oxidoreductases and hydrolases trends, suggesting a different path and effectiveness of SOM degradation, which probably depends both on the soil hydric regime, and on the different type of organic compounds. A particular increase of catalase and invertase specific activities along the soil profiles, suggests the presence of microaerophilic environment in some saturated AC and C sandy horizons but generally, it was observed a gradual decrease of biochemical alteration of the SOM by enzymatic activities along the soil profile due to the progressive restriction of the edaphic conditions.

  4. Toluene removal from sandy soils via in situ technologies with an emphasis on factors influencing soil vapor extraction.

    Science.gov (United States)

    Amin, Mohammad Mehdi; Hatamipour, Mohammad Sadegh; Momenbeik, Fariborz; Nourmoradi, Heshmatollah; Farhadkhani, Marzieh; Mohammadi-Moghadam, Fazel

    2014-01-01

    The integration of bioventing (BV) and soil vapor extraction (SVE) appears to be an effective combination method for soil decontamination. This paper serves two main purposes: it evaluates the effects of soil water content (SWC) and air flow rate on SVE and it investigates the transition regime between BV and SVE for toluene removal from sandy soils. 96 hours after air injection, more than 97% removal efficiency was achieved in all five experiments (carried out for SVE) including 5, 10, and 15% for SWC and 250 and 500 mL/min for air flow rate on SVE. The highest removal efficiency (>99.5%) of toluene was obtained by the combination of BV and SVE (AIBV: Air Injection Bioventing) after 96 h of air injection at a constant flow rate of 250 mL/min. It was found that AIBV has the highest efficiency for toluene removal from sandy soils and can remediate the vadose zone effectively to meet the soil guideline values for protection of groundwater.

  5. Toluene Removal from Sandy Soils via In Situ Technologies with an Emphasis on Factors Influencing Soil Vapor Extraction

    Directory of Open Access Journals (Sweden)

    Mohammad Mehdi Amin

    2014-01-01

    Full Text Available The integration of bioventing (BV and soil vapor extraction (SVE appears to be an effective combination method for soil decontamination. This paper serves two main purposes: it evaluates the effects of soil water content (SWC and air flow rate on SVE and it investigates the transition regime between BV and SVE for toluene removal from sandy soils. 96 hours after air injection, more than 97% removal efficiency was achieved in all five experiments (carried out for SVE including 5, 10, and 15% for SWC and 250 and 500 mL/min for air flow rate on SVE. The highest removal efficiency (>99.5% of toluene was obtained by the combination of BV and SVE (AIBV: Air Injection Bioventing after 96 h of air injection at a constant flow rate of 250 mL/min. It was found that AIBV has the highest efficiency for toluene removal from sandy soils and can remediate the vadose zone effectively to meet the soil guideline values for protection of groundwater.

  6. effect of tractor forward speed on sandy loam soil physical ...

    African Journals Online (AJOL)

    Dr Obe

    Ilorin on a sandy loam soil to evaluate the effect of the imposition of different .... of the blade is 10.5cm. ... arranged in an inverted cone shape with ... replicates were taken for each speed run. The ..... Thakur, T. C; A. Yadav; B. P. Varshney and.

  7. Sorption and Migration Mechanisms of 237 Np through Sandy Soil

    International Nuclear Information System (INIS)

    Chantaraprachoom, Nanthavan; Tanaka, Tadao

    2003-06-01

    In order to evaluate migration behavior of radioactive nuclides in the disposal of low-level radioactive waste into a shallow land burial, the sorption characteristic and migration behavior of 237 Np through sandy soil was studied. Two experimental methods were performed by using batch and column systems. The distribution coefficients (K d ) obtained from the adsorption and desorption process are rather small about 16 and 21 cm 3 /g respectively. Size distribution of 237 Np species in the influent solution was measured by ultra-filtration technique. Migration mechanism of 237 Np was studied by column experiments. The experimental condition was the influence of volume of eluting solution; 100, 300, 500, 1000 and 2000 ml respectively. The result from five column experiments confirm that the sorption characteristics of 237 Np are mainly controlled by a reversible ion-exchange reaction and the migration of 237 Np in the sandy soil can be estimated by using the K d concept

  8. Reorganization of vegetation, hydrology and soil carbon after permafrost degradation across heterogeneous boreal landscapes

    International Nuclear Information System (INIS)

    Torre Jorgenson, M; Harden, Jennifer; Manies, Kristen; Kanevskiy, Mikhail; Shur, Yuri; O’Donnell, Jonathan; Wickland, Kim; Striegl, Robert; Ewing, Stephanie; Zhuang Qianlai; Koch, Josh

    2013-01-01

    The diversity of ecosystems across boreal landscapes, successional changes after disturbance and complicated permafrost histories, present enormous challenges for assessing how vegetation, water and soil carbon may respond to climate change in boreal regions. To address this complexity, we used a chronosequence approach to assess changes in vegetation composition, water storage and soil organic carbon (SOC) stocks along successional gradients within four landscapes: (1) rocky uplands on ice-poor hillside colluvium, (2) silty uplands on extremely ice-rich loess, (3) gravelly–sandy lowlands on ice-poor eolian sand and (4) peaty–silty lowlands on thick ice-rich peat deposits over reworked lowland loess. In rocky uplands, after fire permafrost thawed rapidly due to low ice contents, soils became well drained and SOC stocks decreased slightly. In silty uplands, after fire permafrost persisted, soils remained saturated and SOC decreased slightly. In gravelly–sandy lowlands where permafrost persisted in drier forest soils, loss of deeper permafrost around lakes has allowed recent widespread drainage of lakes that has exposed limnic material with high SOC to aerobic decomposition. In peaty–silty lowlands, 2–4 m of thaw settlement led to fragmented drainage patterns in isolated thermokarst bogs and flooding of soils, and surface soils accumulated new bog peat. We were not able to detect SOC changes in deeper soils, however, due to high variability. Complicated soil stratigraphy revealed that permafrost has repeatedly aggraded and degraded in all landscapes during the Holocene, although in silty uplands only the upper permafrost was affected. Overall, permafrost thaw has led to the reorganization of vegetation, water storage and flow paths, and patterns of SOC accumulation. However, changes have occurred over different timescales among landscapes: over decades in rocky uplands and gravelly–sandy lowlands in response to fire and lake drainage, over decades to

  9. Validation of regression models for nitrate concentrations in the upper groundwater in sandy soils

    International Nuclear Information System (INIS)

    Sonneveld, M.P.W.; Brus, D.J.; Roelsma, J.

    2010-01-01

    For Dutch sandy regions, linear regression models have been developed that predict nitrate concentrations in the upper groundwater on the basis of residual nitrate contents in the soil in autumn. The objective of our study was to validate these regression models for one particular sandy region dominated by dairy farming. No data from this area were used for calibrating the regression models. The model was validated by additional probability sampling. This sample was used to estimate errors in 1) the predicted areal fractions where the EU standard of 50 mg l -1 is exceeded for farms with low N surpluses (ALT) and farms with higher N surpluses (REF); 2) predicted cumulative frequency distributions of nitrate concentration for both groups of farms. Both the errors in the predicted areal fractions as well as the errors in the predicted cumulative frequency distributions indicate that the regression models are invalid for the sandy soils of this study area. - This study indicates that linear regression models that predict nitrate concentrations in the upper groundwater using residual soil N contents should be applied with care.

  10. Phosphorus distribution in sandy soil profile under drip irrigation system

    International Nuclear Information System (INIS)

    El-Gendy, R.W.; Rizk, M.A.; Abd El Moniem, M.; Abdel-Aziz, H.A.; Fahmi, A.E.

    2009-01-01

    This work aims at to studying the impact of irrigation water applied using drip irrigation system in sandy soil with snap bean on phosphorus distribution. This experiment was carried out in soils and water research department farm, nuclear research center, atomic energy authority, cairo, Egypt. Snap bean was cultivated in sandy soil and irrigated with 50,37.5 and 25 cm water in three water treatments represented 100, 75 and 50% ETc. Phosphorus distribution and direction of soil water movement had been detected in three sites on the dripper line (S1,S2 and S3 at 0,12.5 and 25 cm distance from dripper). Phosphorus fertilizer (super phosphate, 15.5% P 2 O 5 in rate 300 kg/fed)was added before cultivation. Neutron probe was used to detect the water distribution and movement at the three site along soil profile. Soil samples were collected before p-addition, at end developing, mid, and late growth stages to determine residual available phosphorus. The obtained data showed that using 50 cm water for irrigation caused an increase in P-concentration till 75 cm depth in the three sites of 100% etc treatment, and covered P-requirements of snap bean for all growth stages. As for 37.5 and 25 cm irrigation water cannot cover all growth stages for P-requirements of snap bean. It could be concluded that applied irrigation water could drive the residual P-levels till 75 cm depth in the three sites. Yield of the crop had been taken as an indicator as an indicator profile. Yield showed good response according to water quantities and P-transportation within the soil profile

  11. Improvement of Water Movement in an Undulating Sandy Soil Prone to Water Repellency

    NARCIS (Netherlands)

    Oostindie, K.; Dekker, L.W.; Wesseling, J.G.; Ritsema, C.J.

    2011-01-01

    The temporal dynamics of water repellency in soils strongly influence water flow. We investigated the variability of soil water content in a slight slope on a sandy fairway exhibiting water-repellent behavior. A time domain reflectometry (TDR) array of 60 probes measured water contents at 3-h

  12. Factors affecting N immobilisation/mineralisation kinetics for cellulose-, glucose- and straw-amended sandy soils

    NARCIS (Netherlands)

    Vinten, A.J.A.; Whitmore, A.P.; Bloem, J.; Howard, R.; Wright, F.

    2002-01-01

    The kinetics of nitrogen immobilization/mineralization for cellulose-, glucose- and straw-amended sandy soils were investigated in a series of laboratory incubations. Three Scottish soils expected to exhibit a range of biological activity were used: aloamy sand, intensively cropped horticultural

  13. Influence of drainage status on soil and water chemistry, litter decomposition and soil respiration in central Amazonian forests on sandy soils

    Directory of Open Access Journals (Sweden)

    Antônio Ocimar Manzi

    2011-04-01

    Full Text Available Central Amazonian rainforest landscape supports a mosaic of tall terra firme rainforest and ecotone campinarana, riparian and campina forests, reflecting topography-induced variations in soil, nutrient and drainage conditions. Spatial and temporal variations in litter decomposition, soil and groundwater chemistry and soil CO2 respiration were studied in forests on sandy soils, whereas drought sensitivity of poorly-drained valley soils was investigated in an artificial drainage experiment. Slightly changes in litter decomposition or water chemistry were observed as a consequence of artificial drainage. Riparian plots did experience higher litter decomposition rates than campina forest. In response to a permanent lowering of the groundwater level from 0.1 m to 0.3 m depth in the drainage plot, topsoil carbon and nitrogen contents decreased substantially. Soil CO2 respiration decreased from 3.7±0.6 µmol m-2 s-1 before drainage to 2.5±0.2 and 0.8±0.1 µmol m-2 s-1 eight and 11 months after drainage, respectively. Soil respiration in the control plot remained constant at 3.7±0.6 µmol m-2 s-1. The above suggests that more frequent droughts may affect topsoil carbon and nitrogen content and soil respiration rates in the riparian ecosystem, and may induce a transition to less diverse campinarana or short-statured campina forest that covers areas with strongly-leached sandy soil.

  14. Remediation of sandy soils contaminated with hydrocarbons and halogenated hydrocarbons by soil vapour extraction.

    Science.gov (United States)

    Albergaria, José Tomás; Alvim-Ferraz, Maria da Conceição M; Delerue-Matos, Cristina

    2012-08-15

    This paper presents the study of the remediation of sandy soils containing six of the most common contaminants (benzene, toluene, ethylbenzene, xylene, trichloroethylene and perchloroethylene) using soil vapour extraction (SVE). The influence of soil water content on the process efficiency was evaluated considering the soil type and the contaminant. For artificially contaminated soils with negligible clay contents and natural organic matter it was concluded that: (i) all the remediation processes presented efficiencies above 92%; (ii) an increase of the soil water content led to a more time-consuming remediation; (iii) longer remediation periods were observed for contaminants with lower vapour pressures and lower water solubilities due to mass transfer limitations. Based on these results an easy and relatively fast procedure was developed for the prediction of the remediation times of real soils; 83% of the remediation times were predicted with relative deviations below 14%. Copyright © 2012 Elsevier Ltd. All rights reserved.

  15. Restoring Soil Quality to Mitigate Soil Degradation

    Directory of Open Access Journals (Sweden)

    Rattan Lal

    2015-05-01

    Full Text Available Feeding the world population, 7.3 billion in 2015 and projected to increase to 9.5 billion by 2050, necessitates an increase in agricultural production of ~70% between 2005 and 2050. Soil degradation, characterized by decline in quality and decrease in ecosystem goods and services, is a major constraint to achieving the required increase in agricultural production. Soil is a non-renewable resource on human time scales with its vulnerability to degradation depending on complex interactions between processes, factors and causes occurring at a range of spatial and temporal scales. Among the major soil degradation processes are accelerated erosion, depletion of the soil organic carbon (SOC pool and loss in biodiversity, loss of soil fertility and elemental imbalance, acidification and salinization. Soil degradation trends can be reversed by conversion to a restorative land use and adoption of recommended management practices. The strategy is to minimize soil erosion, create positive SOC and N budgets, enhance activity and species diversity of soil biota (micro, meso, and macro, and improve structural stability and pore geometry. Improving soil quality (i.e., increasing SOC pool, improving soil structure, enhancing soil fertility can reduce risks of soil degradation (physical, chemical, biological and ecological while improving the environment. Increasing the SOC pool to above the critical level (10 to 15 g/kg is essential to set-in-motion the restorative trends. Site-specific techniques of restoring soil quality include conservation agriculture, integrated nutrient management, continuous vegetative cover such as residue mulch and cover cropping, and controlled grazing at appropriate stocking rates. The strategy is to produce “more from less” by reducing losses and increasing soil, water, and nutrient use efficiency.

  16. Influence of salinity on bioremediation of oil in soil

    International Nuclear Information System (INIS)

    Rhykerd, R.L.; Weaver, R.W.; McInnes, K.J.

    1995-01-01

    Spills from oil production and processing result in soils being contaminated with oil and salt. The effect of NaCl on degradation of oil in a sandy-clay loam and a clay loam soil was determined. Soils were treated with 50 g kg -1 non-detergent motor oil (30 SAE). Salt treatments included NaCl amendments to adjust the soil solution electrical conductivities to 40, 120, and 200 dS m -1 . Soils were amended with nutrients and incubated at 25 o C. Oil degradation was estimated from the quantities of CO 2 evolved and from gravimetric determinations of remaining oil. Salt concentrations of 200 dS m -1 in oil amended soils resulted in a decrease in oil mineralized by 44% for a clay loam and 20% for a sandy-clay loam soil. A salt concentration of 40 dS m -1 reduced oil mineralization by about 10% in both soils. Oil mineralized in the oil amended clay-loam soil was 2-3 times greater than for comparable treatments of the sandy-clay loam soil. Amending the sandy-clay loam soil with 5% by weight of the clay-loam soil enhanced oil mineralization by 40%. Removal of salts from oil and salt contaminated soils before undertaking bioremediation may reduce the time required for bioremediation. (author)

  17. 15N Isotopic Study on Decomposition of Organic Residues Incorporated into Alluvial and Sandy Saline Soils

    International Nuclear Information System (INIS)

    El-Kholi, A. F.; Galal, Y. G. M.

    2004-01-01

    Incubation experiment was conducted to study the effect of the nitrogenous fertilizer on the decomposition and mineralization of organic residues (soybean powdered forage) as well as the release of the soil inorganic nitrogen. This technique was carried out using two types of soils, one is alluvial and the other is saline sandy soil collected from Fayoum governorate. Soybean forage has an organic carbon 23.1%, total N 1.6% and C/N ratio 14.4. Regarding the effect of incubation period on the two soil samples, the evolved NH 4 -N was generally reached its highest peak after 30-45 days, in the presence of either the added 15 No3-fertilizer solely or in combination with soybean forage. Reversible trend was occurred with regard to the evolved No3-N. The highest peak of evolved No3-N recorded in unfertilized control, as compared to 15 No3-N treatment, at 30 day incubation period indicated that the addition of labeled mineral fertilizer had appreciably enhanced the immobilization process. Net nitrification revealed that it was the highest in unfertilized control soil where it was significantly decreased in the treated two soil samples. Gross mineralization as affected by the addition of soybean forage in combination with labeled mineral fertilizer had been promoted by 75% in the alluvial soil and by 18% in the sandy saline soil, as compared with the soil samples received 15 No3-fertilizer only. Gross immobilization, in soil samples received 15 No3-fertilizer plus soybean forage had surpassed those received 15 No3-fertilizer only by 16% in the alluvial soil and by 25% in the sandy saline soil. (Authors)

  18. Nitrogen and Carbon Leaching in Repacked Sandy Soil with Added Fine Particulate Biochar

    DEFF Research Database (Denmark)

    Bruun, Esben W.; Petersen, Carsten; Strobel, Bjarne W.

    2012-01-01

    Biochar amendment to soil may affect N turnover and retention, and may cause translocation of dissolved and particulate C. We investigated effects of three fine particulate biochars made of wheat (Triticum aestivum L.) straw (one by slow pyrolysis and two by fast pyrolysis) on N and C leaching from...... repacked sandy soil columns (length: 51 cm). Biochar (2 wt%), ammonium fertilizer (NH4+, amount corresponding to 300 kg N ha-1) and an inert tracer (bromide) were added to a 3-cm top layer of sandy loam, and the columns were then irrigated with constant rate (36 mm d-1) for 15 d. The total amount...... of leachate came to about 3.0 water filled pore volumes (WFPVs). Our study revealed a high mobility of labile C components originating from the fine particulate fast pyrolysis biochar. This finding highlights a potential risk of C leaching coupled with the use of fast pyrolysis biochars for soil amendment...

  19. Soil-ecological risks for soil degradation estimation

    Science.gov (United States)

    Trifonova, Tatiana; Shirkin, Leonid; Kust, German; Andreeva, Olga

    2016-04-01

    Soil degradation includes the processes of soil properties and quality worsening, primarily from the point of view of their productivity and decrease of ecosystem services quality. Complete soil cover destruction and/or functioning termination of soil forms of organic life are considered as extreme stages of soil degradation, and for the fragile ecosystems they are normally considered in the network of their desertification, land degradation and droughts /DLDD/ concept. Block-model of ecotoxic effects, generating soil and ecosystem degradation, has been developed as a result of the long-term field and laboratory research of sod-podzol soils, contaminated with waste, containing heavy metals. The model highlights soil degradation mechanisms, caused by direct and indirect impact of ecotoxicants on "phytocenosis- soil" system and their combination, frequently causing synergistic effect. The sequence of occurring changes here can be formalized as a theory of change (succession of interrelated events). Several stages are distinguished here - from heavy metals leaching (releasing) in waste and their migration downward the soil profile to phytoproductivity decrease and certain phytocenosis composition changes. Phytoproductivity decrease leads to the reduction of cellulose content introduced into the soil. The described feedback mechanism acts as a factor of sod-podzolic soil self-purification and stability. It has been shown, that using phytomass productivity index, integrally reflecting the worsening of soil properties complex, it is possible to solve the problems dealing with the dose-reflecting reactions creation and determination of critical levels of load for phytocenosis and corresponding soil-ecological risks. Soil-ecological risk in "phytocenosis- soil" system means probable negative changes and the loss of some ecosystem functions during the transformation process of dead organic substance energy for the new biomass composition. Soil-ecological risks estimation is

  20. Physical fertility of degraded acid sands in South-eastern Nigeria ...

    African Journals Online (AJOL)

    We evaluated the physical fertility of degraded and undegraded acid sands in Akwa Ibom State, South-eastern Nigeria. The soils were similar in texture, being predominantly sandy, averaging 90.1% in degraded and 89.9% in undegraded soil. Bulk density averaged 1.50g/cm3 and 1.45g/cm3, while macropores averaged ...

  1. Fit-for-purpose phosphorus management: do riparian buffers qualify in catchments with sandy soils?

    Science.gov (United States)

    Weaver, David; Summers, Robert

    2014-05-01

    Hillslope runoff and leaching studies, catchment-scale water quality measurements and P retention and release characteristics of stream bank and catchment soils were used to better understand reasons behind the reported ineffectiveness of riparian buffers for phosphorus (P) management in catchments with sandy soils from south-west Western Australia (WA). Catchment-scale water quality measurements of 60 % particulate P (PP) suggest that riparian buffers should improve water quality; however, runoff and leaching studies show 20 times more water and 2 to 3 orders of magnitude more P are transported through leaching than runoff processes. The ratio of filterable reactive P (FRP) to total P (TP) in surface runoff from the plots was 60 %, and when combined with leachate, 96 to 99 % of P lost from hillslopes was FRP, in contrast with 40 % measured as FRP at the large catchment scale. Measurements of the P retention and release characteristics of catchment soils (bank soil (bank soils suggest that catchment soils contain more P, are more P saturated and are significantly more likely to deliver FRP and TP in excess of water quality targets than stream bank soils. Stream bank soils are much more likely to retain P than contribute P to streams, and the in-stream mixing of FRP from the landscape with particulates from stream banks or stream beds is a potential mechanism to explain the change in P form from hillslopes (96 to 99 % FRP) to large catchments (40 % FRP). When considered in the context of previous work reporting that riparian buffers were ineffective for P management in this environment, these studies reinforce the notion that (1) riparian buffers are unlikely to provide fit-for-purpose P management in catchments with sandy soils, (2) most P delivered to streams in sandy soil catchments is FRP and travels via subsurface and leaching pathways and (3) large catchment-scale water quality measurements are not good indicators of hillslope P mobilisation and transport

  2. Evaluation of the 137Cs technique for estimating wind erosion losses for some sandy Western Australian soils

    International Nuclear Information System (INIS)

    Harper, R.J.; Gilkes, R.J.

    1994-01-01

    The utility of the caesium-137 technique, for estimating the effects of wind erosion, was evaluated on the soils of a semi-arid agricultural area near Jerramungup, Western Australia. The past incidence of wind erosion was estimated from field observations of soil profile morphology and an existing remote sensing study. Erosion was limited to sandy surfaced soils (0-4% clay), with a highly significant difference (P 137 Cs values between eroded and non-eroded sandy soils, with mean values of 243±17 and 386±13 Bq m -2 respectively. Non-eroded soils, with larger clay contents, had a mean 137 Cs content of 421±26 Bq m -2 , however, due to considerable variation between replicate samples, this value was not significantly different from that of the non-eroded sands. Hence, although the technique discriminates between eroded and non-eroded areas, the large variation in 137 Cs values means that from 27 to 96 replicate samples are required to provide statistically valid estimates of 137 Cs loss. The occurrence of around 18% of the total 137 Cs between 10 and 20 cm depth in these soils, despite cultivation being confined to the surface 9 cm, suggests that leaching of 137 Cs occurs in the sandy soils, although there was no relationship between clay content and 137 Cs value for either eroded or non-eroded soils. In a multiple linear regression, organic carbon content and the mean grain size of the eroded soils explained 35% of the variation in 137 Cs content. This relationship suggests that both organic carbon and 137 Cs are removed by erosion, with erosion being more prevalent on soils with a finer sand fraction. Clay and silt contents do not vary with depth in the near-surface horizons of the eroded sandy soils, hence it is likely that wind erosion strips the entire surface horizon with its 137 Cs content, rather than selectively winnowing fine material. 71 refs., 6 tabs., 2 fig

  3. Transport of water and solutes in wettable and water repellent sandy soils

    NARCIS (Netherlands)

    Ritsema, C.J.; Dekker, L.W.

    1996-01-01

    The research yielded the following conclusions and results: preferential flow can be expected in recently deposited, loosely packed, wettable dune sands; preferential flow is common in most water-repellent sandy soils; distribution flow in topsoils isa process of major importance, resulting in a

  4. Improvement of Shear Strength of Sandy Soil by Cement Grout with Fly Ash

    Directory of Open Access Journals (Sweden)

    Haifaa Abdulrasool Ali

    2018-12-01

    Full Text Available The effects of the permeation cement grout with fly ash on the sandy soil skeleton were studied in the present work in two phase; first phase the shear strength parameters, and the second phase effect of these grouted materials on volume grouted zone by injection (51 cm³ of slurry in sandy soil placed in steel cylinder model with dimension 15 cm in diameter and 30 cm in height. The soil sample was obtained from Karbala city and it is classified as poorly graded sand (SP according to USCS. The soil samples were improved by cement grout with three percentages weight of water cement ratio (w:c; (0.1w:0.9c, 0.8w:0.2c, and 0.7w:0.3c, while the soil samples were dehydrated for one day curing time. Fly ash class (F was used with cement grout as filler material; it was added to the mixture as a replacement material for cement in weight percentages; 10%, 25% and 40%. According to the results of tests, both shear strength and approximate volume of the effective grouted zone for treated samples soil with cement grout was increased when the water cement ratio decreased. Fly ash with cement grout needs to increase the water demand for the grout mixing to give best results in both shear strength and filling the soil voids.

  5. Effect of pore-size distribution on the collapse behaviour of anthropogenic sandy soil deposits

    Directory of Open Access Journals (Sweden)

    Baille Wiebke

    2016-01-01

    Full Text Available In the former open-pit mines of the Lusatian region in Germany, several liquefaction events have occurred during the recent years in the anthropogenic deposits made of very loose sandy soils. These events are related to the rising ground water table after the stop of controlled ground water lowering. The very loose state is due to the formation of sand aggregates (pseudo-grains during the deposition process. The pseudo-grains enclose larger voids of dimension greater than the single sand grain. Wetting induced collapse of the pseudo-grains is presumed to be one of the possible mechanisms triggering liquefaction. In the present study, the effect of larger voids on the wetting induced deformation behaviour of sandy soils is experimentally investigated by laboratory box tests. The deformation field in the sample during wetting was measured using Digital Image Correlation (DIC technique. The results show that the observed deformations are affected by the pore size distribution, thus the amount of voids between the pseudo-grains (macro-void ratio and the voids inside the pseudo-grains (matrix void ratio. The global void ratio of a sandy soil is not sufficient as single state parameter, but the pore size distribution has to be taken into account, experimentally as well as in modelling.

  6. Degradation of thiram in soil

    International Nuclear Information System (INIS)

    Raghu, K.; Murthy, N.B.K.; Kumarsamy, R.

    1975-01-01

    Determination of the residual 35 S labelled tetramethylthiuram disulfide showed that the fungicide persisted longer in sterilized than in unsterilized soil, while the chloroform extractable radioactivity decreased, the water extractable radioactivity increased with increase in time. However, in sterilized soil the water extractable radioactivity remained more or less constant. Degradation of the fungicide was further demonstrated by the release of C 35 S 2 from soil treated with labelled thiram. Dimethylamine was found to be one of the degradation products. A bacterium isolated from thiram-enriched soil could degrade the fungicide in shake culture. The degradation pathways of thiram in sterilized and unsterilized soils are discussed. (author)

  7. Monitor Soil Degradation or Triage for Soil Security? An Australian Challenge

    Directory of Open Access Journals (Sweden)

    Andrea Koch

    2015-04-01

    Full Text Available The Australian National Soil Research, Development and Extension Strategy identifies soil security as a foundation for the current and future productivity and profitability of Australian agriculture. Current agricultural production is attenuated by soil degradation. Future production is highly dependent on the condition of Australian soils. Soil degradation in Australia is dominated in its areal extent by soil erosion. We reiterate the use of soil erosion as a reliable indicator of soil condition/quality and a practical measure of soil degradation. We describe three key phases of soil degradation since European settlement, and show a clear link between inappropriate agricultural practices and the resultant soil degradation. We demonstrate that modern agricultural practices have had a marked effect on reducing erosion. Current advances in agricultural soil management could lead to further stabilization and slowing of soil degradation in addition to improving productivity. However, policy complacency towards soil degradation, combined with future climate projections of increased rainfall intensity but decreased volumes, warmer temperatures and increased time in drought may once again accelerate soil degradation and susceptibility to erosion and thus limit the ability of agriculture to advance without further improving soil management practices. Monitoring soil degradation may indicate land degradation, but we contend that monitoring will not lead to soil security. We propose the adoption of a triaging approach to soil degradation using the soil security framework, to prioritise treatment plans that engage science and agriculture to develop practices that simultaneously increase productivity and improve soil condition. This will provide a public policy platform for efficient allocation of public and private resources to secure Australia’s soil resource.

  8. Irrigation initiation timing in soybean grown on sandy soils in Northeast Arkansas

    Science.gov (United States)

    Irrigation initiation timing was evaluated in furrow-irrigated soybean field with sandy soils in Mississippi County, AR. A major objective of this 2015 study was to validate and expand irrigation timing recommendations that pair plant growth measures with weather cues including use of local weather ...

  9. Distribution of transformed organic matter in structural units of loamy sandy soddy-podzolic soil

    Science.gov (United States)

    Kogut, B. M.; Yashin, M. A.; Semenov, V. M.; Avdeeva, T. N.; Markina, L. G.; Lukin, S. M.; Tarasov, S. I.

    2016-01-01

    The effect of land use types and fertilizing systems on the structural and aggregate composition of loamy sandy soddy-podzolic soil and the quantitative parameters of soil organic matter has been studied. The contribution of soil aggregates 2-1 mm in size to the total Corg reserve in the humus horizon is higher than the contributions of other aggregates by 1.3-4.2 times. Reliable correlations have been revealed between the contents of total (Corg), labile (Clab), and active (C0) organic matter in the soil. The proportion of C0 is 44-70% of Clab extractable by neutral sodium pyrophosphate solution. The contributions of each of the 2-1, 0.5-0.25, and fractions to the total C0 reserve are 14-21%; the contributions of each of the other fractions are 4-12%. The chemically labile and biologically active components of humic substances reflect the quality changes of soil organic matter under agrogenic impacts. A conceptual scheme has been proposed for the subdivision of soil organic matter into the active, slow (intermediate), and passive pools. In the humus horizon of loamy sandy soddy-podzolic soil, the active, slow, and passive pools contain 6-11, 34-65, and 26-94% of the total Corg, respectively.

  10. [Soil moisture dynamics of artificial Caragana microphylla shrubs at different topographical sites in Horqin sandy land].

    Science.gov (United States)

    Huang, Gang; Zhao, Xue-yong; Huang, Ying-xin; Su, Yan-gui

    2009-03-01

    Based on the investigation data of vegetation and soil moisture regime of Caragana microphylla shrubs widely distributed in Horqin sandy land, the spatiotemporal variations of soil moisture regime and soil water storage of artificial sand-fixing C. microphylla shrubs at different topographical sites in the sandy land were studied, and the evapotranspiration was measured by water balance method. The results showed that the soil moisture content of the shrubs was the highest in the lowland of dunes, followed by in the middle, and in the crest of the dunes, and increased with increasing depth. No water stress occurred during the growth season of the shrubs. Soil moisture content of the shrubs was highly related to precipitation event, and the relationship of soil moisture content with precipitation was higher in deep soil layer (50-180 cm) than in shallow soil layer (0-50 cm). The variation coefficient of soil moisture content was also higher in deep layer than in shallow layer. Soil water storage was increasing in the whole growth season of the shrubs, which meant that the accumulation of soil water occurred in this area. The evapotranspiriation of the shrubs occupied above 64% of the precipitation.

  11. THE PROBLEMATIC OF SANDY LANDS IN PARANAVAI MUNICIPALITY –PR

    Directory of Open Access Journals (Sweden)

    Marcelo Eduardo Freres Stipp

    2005-05-01

    Full Text Available The sandy lands are a process of scouring with sand forming a sandy area, which correspondsto a reworking of the sands due its constant mobility, involving the transformation of notsolids deposits is sandy areas. This work tried to establish the characterization of thisphenomenon of scouring with sand in a local level, occurring in arenaceous areas in theNortheast of the state of Paraná, specifically in the urban site of Paranavaí. It was also madean evaluation of the environmental degradation as well as different causes for what provokedthese sandy areas. Being an area with a high level of soil decomposition with the highwaysroutes crossing it, it was necessary, besides bibliographic data that allowed a theoretical basis,a research applied in order to supply subsides for future planning related to the spaceorganization. The evolution of the use and soil occupation in this area has been processedwithin an urban planning which considered by no account neither soil characteristic, thevegetation nor the predominant climate in that region. The mechanisms of region atmospherecirculation were analyzed, the alterations or attributes of the climate as well, aiming toidentify the genesis of the erosion sandy and possible time and space distribution. Initially, themain characteristics of the region were collected, components e processes working on the landmodel. It was observed how it worked and the use and occupation of the soil in past times andcurrently. During 2004, using the Environmental Fragility Letter, the areas of erosion wereidentified, ravines and strong erosion that compounds the first stages of the focused problem.The sandy land is a process that involves erosion, transport, e accumulation, meaning most oftimes the loosing of Biosphere productivity. For monitoring these risk areas some measuringcanes were made to measure the soil loss, which were used in several spots of erosion in theurban area in Paranavaí. The measurement happened in

  12. Groundwater chemistry of Al under Dutch sandy soils: Effects of land use and depth

    NARCIS (Netherlands)

    Fest, E.P.M.J.; Temminghoff, E.J.M.; Griffioen, J.; Grift, B. van der; Riemsdijk, W.H. van

    2007-01-01

    Aluminium has received great attention in the second half of the 20th century, mainly in the context of the acid rain problem mostly in forest soils. In this research the effect of land use and depth of the groundwater on Al, pH and DOC concentration in groundwater under Dutch sandy soils has been

  13. Estimating water retention curves and strength properties of unsaturated sandy soils from basic soil gradation parameters

    Science.gov (United States)

    Wang, Ji-Peng; Hu, Nian; François, Bertrand; Lambert, Pierre

    2017-07-01

    This study proposed two pedotransfer functions (PTFs) to estimate sandy soil water retention curves. It is based on the van Genuchten's water retention model and from a semiphysical and semistatistical approach. Basic gradation parameters of d60 as particle size at 60% passing and the coefficient of uniformity Cu are employed in the PTFs with two idealized conditions, the monosized scenario and the extremely polydisperse condition, satisfied. Water retention tests are carried out on eight granular materials with narrow particle size distributions as supplementary data of the UNSODA database. The air entry value is expressed as inversely proportional to d60 and the parameter n, which is related to slope of water retention curve, is a function of Cu. The proposed PTFs, although have fewer parameters, have better fitness than previous PTFs for sandy soils. Furthermore, by incorporating with the suction stress definition, the proposed pedotransfer functions are imbedded in shear strength equations which provide a way to estimate capillary induced tensile strength or cohesion at a certain suction or degree of saturation from basic soil gradation parameters. The estimation shows quantitative agreement with experimental data in literature, and it also explains that the capillary-induced cohesion is generally higher for materials with finer mean particle size or higher polydispersity.

  14. Garlic mustard and its effects on soil microbial communities in a sandy pine forest in central Illinois

    Science.gov (United States)

    Alexander B. Faulkner; Brittany E. Pham; Truc-Quynh D. Nguyen; Kenneth E. Kitchell; Daniel S. O' Keefe; Kelly D. McConnaughay; Sherri J. Morris

    2014-01-01

    This study evaluated the impacts of garlic mustard (Alliaria petiolata), an invasive species, on soil microbial community dynamics in a pine plantation on sandy soils in central Illinois. In situ soil carbon dioxide efflux was significantly greater in invaded sites. Similarly, in vitro carbon mineralization was significantly greater for soils...

  15. [Soil sandy desertification and salinization and their interrelationships in Yanghuang irrigated area of Hongsipu, Ningxia of northwest China].

    Science.gov (United States)

    Yang, Xin-guo; Song, Nai-ping

    2011-09-01

    By the methods of controlled and typical sampling, this paper analyzed the texture, salinization characteristics, cation exchange capacity (CEC), and their correlations in the 0-40 cm soil profiles of corn land, medlar land, and non-utilized land in Yanghuang irrigated area of Hongsipu, Northwest China. Under controlled sampling, the salt content in the soil profiles was 0.69-1.30 g x kg(-1) (except in non-utilized land where the 0-10 cm soil salt content was up to 1.74 g x kg(-1)), with no obvious salinization. The sodium adsorption ratio and exchangeable sodium percentage in the 20-40 cm soil layer of medlar land were 12.18 and 14.1%, respectively, and the total content of clay and silt in the 0-40 cm soil profile of medlar land was up to 37.3% whereas that in the 0-20 cm soil layer of corn land was only 13.5%. In the 20-40 cm soil layer of corn land, the indices of sandy desertification and salinization had significant correlations under controlled sampling but no correlations under typical sampling, while the CEC and the sandy desertification and salinization indices had significant correlations under typical sampling. In different land use types in the study area, soil sandy desertification and salinization had complicated interrelationships, and CEC could be used as the indicator for the changes in soil environmental quality.

  16. Biochar Application in Malaysian Sandy and Acid Sulfate Soils: Soil Amelioration Effects and Improved Crop Production over Two Cropping Seasons

    Directory of Open Access Journals (Sweden)

    Theeba Manickam

    2015-12-01

    Full Text Available The use of biochar as an agricultural soil improvement was tested in acid sulfate and sandy soils from Malaysia, cropped with rice and corn. Malaysia has an abundance of waste rice husks that could be used to produce biochar. Rice husk biochar was produced in a gasifier at a local mill in Kelantan as well as in the laboratory using a controlled, specially designed, top lift up draft system (Belonio unit. Rice husk biochar was applied once to both soils at two doses (2% and 5%, in a pot set up that was carried out for two cropping seasons. Positive and significant crop yield effects were observed for both soils, biochars and crops. The yield effects varied with biochar type and dosage, with soil type and over the cropping seasons. The yield increases observed for the sandy soil were tentatively attributed to significant increases in plant-available water contents (from 4%–5% to 7%–8%. The yield effects in the acid sulfate soil were likely a consequence of a combination of (i alleviation of plant root stress by aluminum (Ca/Al molar ratios significantly increased, from around 1 to 3–5 and (ii increases in CEC. The agricultural benefits of rice husk biochar application to Malaysian soils holds promise for its future use.

  17. EXPERIMENTAL DETERMINATION OF VARIABILITY IN PERMEABILITY OF SANDY SILT SOIL MIXED WITH FLY ASH IN PROPORTIONATE

    OpenAIRE

    Rasna Sharma*, Dr. M.K. Trivedi

    2016-01-01

    This paper presents the experimental determination of variability in permeability of sandy silt soil by blending with fly ash. The grain size, porosity, structure of the soil, specific gravity of the soil, viscosity and temperature are important factors in varying the permeability of the soil. Permeability is the flow conduction property of the soil. The void ratio with in the soil plays a vital role in varying the permeability. By blending with finer grains like fly ash in the soil with sand...

  18. Soil degradation effect on biological activity in Mediterranean calcareous soils

    Science.gov (United States)

    Roca-Pérez, L.; Alcover-Sáez, S.; Mormeneo, S.; Boluda, R.

    2009-04-01

    Soil degradation processes include erosion, organic matter decline, compaction, salinization, landslides, contamination, sealing and biodiversity decline. In the Mediterranean region the climatological and lithological conditions, together with relief on the landscape and anthropological activity are responsible for increasing desertification process. It is therefore considered to be extreme importance to be able to measure soil degradation quantitatively. We studied soil characteristics, microbiological and biochemical parameters in different calcareous soil sequences from Valencia Community (Easter Spain), in an attempt to assess the suitability of the parameters measured to reflect the state of soil degradation and the possibility of using the parameters to assess microbiological decline and soil quality. For this purpose, forest, scrubland and agricultural soil in three soil sequences were sampled in different areas. Several sensors of the soil biochemistry and microbiology related with total organic carbon, microbial biomass carbon, soil respiration, microorganism number and enzyme activities were determined. The results show that, except microorganism number, these parameters are good indicators of a soil biological activity and soil quality. The best enzymatic activities to use like indicators were phosphatases, esterases, amino-peptidases. Thus, the enzymes test can be used as indicators of soil degradation when this degradation is related with organic matter losses. There was a statistically significant difference in cumulative O2 uptake and extracellular enzymes among the soils with different degree of degradation. We would like to thank Spanish government-MICINN for funding and support (MICINN, project CGL2006-09776).

  19. Estimating water retention curves for sandy soils at the Doñana National Park, SW Spain

    Science.gov (United States)

    The determination of soil water retention curves (SWRC) in the laboratory is a slow and tedious task, which is especially challenging for sandy soils due to their low water retention capacity and large water content changes for small pressure head differences. Due to spatial variability within larg...

  20. Use of neutron scattering meter to detect soil moisture distribution under trickle irrigation system in sandy soil of inshas, Egypt

    International Nuclear Information System (INIS)

    Abd El-moniem, M.; El-gendy, R.W.; Gadalla, A.M.; Hamdy, A.; Zeedan, A.

    2006-01-01

    This study aims to investigate the soil moisture distribution under different quantities of irrigation water in cultivated sandy soil with squash, using drip irrigation system. This study was carried out in Inshas sandy soil at the farm of Soil and Water Research Department, Nuclear Research Centre, Atomic Energy Authority, Egypt. Three rates of applied irrigation water (100, 75 and 50 % ETc) were used. Three sites (0, 12.5 and 25 cm distances from the emitter between drippers and laterals lines) were chosen to measure soil moisture contents (horizontal and vertical directions within the soil depths). The obtained data pointed out that the maximum width, in onion shape of water distribution under drip irrigation system, was at 45 cm depth at 0 site. From the study of soil moisture distribution, the overlapping between each two neighbor drippers played a good role in increasing soil moisture content at the 25 site rather than the rest sites. Water distribution was affected with plant location within the wet area as well as the used irrigation water quantities. Water distribution between drippers and laterals did not differ much approximately. The highest soil moisture depletion was at 12.5 site (between drippers) for 100 and 75 % ETc rather than the rest treatments. 100 % ETc treatment introduced the highest soil moisture depletion in the first stage of plant growth season for the three sites (between drippers and laterals). In the last stage of plant growth season, water re-distribution phenomena resulted from the changeable total hydraulic potential, which played important role for interpretation of results

  1. Effect of Nano-Carbon on Water Holding Capacity in a Sandy Soil of the Loess Plateau

    Directory of Open Access Journals (Sweden)

    Beibei Zhou

    2017-10-01

    Full Text Available The poor water retention capacity of sandy soils commonly aggregate soil erosion and ecological environment on the Chinese Loess Plateau. Due to its strong capacity for absorption and large specific surface area, the use of nanocarbon made of coconut shell as a soil amendment that could improve water retention was investigated. Soil column experiments were conducted in which a layer of nanocarbon mixed well with the soil was formed at a depth of 20 cm below the soil surface. Four different nanocarbon contents by weight (0%, 0.1%, 0.5%, and 1% and five thicknesses of the nanocarbon- soil mixture layer ranging from 1 to 5 cm were considered. Cumulative infiltration and soil water content distributions were determined when water was added to soil columns. Soil Water Characteristic Curves (SWCC were obtained using the centrifuge method. The principal results showed that the infiltration rate and cumulative infiltration increased with the increases of nanocarbon contents, to the thicknesses of the nano carbon-soil mixture layer. Soil water contents that below the soil-nano carbon layer decreased sharply. Both the Brooks-Corey and van Genuchten models could describe well the SWCC of the disturbed sandy soil with various nano carbon contents. Both the saturated water content (θs, residual water content (θr and empirical parameter (α increased with increasing nano carbon content, while the pore-size distribution parameter (n decreased. The available soil water contents were efficiently increased with the increase in nanocarbon contents.

  2. Earthworms (Eisenia fetida) demonstrate potential for use in soil bioremediation by increasing the degradation rates of heavy crude oil hydrocarbons.

    Science.gov (United States)

    Martinkosky, Luke; Barkley, Jaimie; Sabadell, Gabriel; Gough, Heidi; Davidson, Seana

    2017-02-15

    Crude oil contamination widely impacts soil as a result of release during oil and gas exploration and production activities. The success of bioremediation methods to meet remediation goals often depends on the composition of the crude oil, the soil, and microbial community. Earthworms may enhance bioremediation by mixing and aerating the soil, and exposing soil microorganisms to conditions in the earthworm gut that lead to increased activity. In this study, the common composting earthworm Eisenia fetida was tested for utility to improve remediation of oil-impacted soil. E. fetida survival in soil contaminated with two distinct crude oils was tested in an artificial (lab-mixed) sandy loam soil, and survival compared to that in the clean soil. Crude oil with a high fraction of light-weight hydrocarbons was more toxic to earthworms than the crude oil with a high proportion of heavy polyaromatic and aliphatic hydrocarbons. The heavier crude oil was added to soil to create a 30,000mg/kg crude oil impacted soil, and degradation in the presence of added earthworms and feed, feed alone, or no additions was monitored over time and compared. Earthworm feed was spread on top to test effectiveness of no mixing. TPH degradation rate for the earthworm treatments was ~90mg/day slowing by 200days to ~20mg/day, producing two phases of degradation. With feed alone, the rate was ~40mg/day, with signs of slowing after 500days. Both treatments reached the same end point concentrations, and exhibited faster degradation of aliphatic hydrocarbons C21, decreased. During these experiments, soils were moderately toxic during the first three months, then earthworms survived well, were active and reproduced with petroleum hydrocarbons present. This study demonstrated that earthworms accelerate bioremediation of crude oil in soils, including the degradation of the heaviest polyaromatic fractions. Copyright © 2016 Elsevier B.V. All rights reserved.

  3. Biological soil crust formation under artificial vegetation effect and its properties in the Mugetan sandy land, northeastern Qinghai-Tibet Plateau

    Science.gov (United States)

    Li, Y. F.; Li, Z. W.; Jia, Y. H.; Zhang, K.

    2016-08-01

    Mugetan sandy land is an inland desertification area of about 2,065 km2 in the northeastern Qinghai-Tibet Plateau. In the ecological restoration region of the Mugetan sandy land, different crusts have formed under the action of vegetation in three types of sandy soil (i.e. semi-fixed sand dune, fixed sand dune and ancient fixed aeolian sandy soil). The surface sand particle distribution, mineral component and vegetation composition of moving sand dunes and three types of sandy soil were studied in 2010-2014 to analyze the biological crust formation properties in the Mugetan sandy land and the effects of artificial vegetation. Results from this study revealed that artificial vegetation increases the clay content and encourages the development of biological curst. The fine particles (i.e. clay and humus) of the surface layer of the sand dunes increased more than 15% ten years after the artificial vegetation planting, and further increased up to 20% after one hundred years. The interaction of clay, humus, and other fine particles formed the soil aggregate structure. Meanwhile, under the vegetation effect from the microbes, algae, and moss, the sand particles stuck together and a biological crust formed. The interconnection of the partial crusts caused the sand dunes to gradually be fixed as a whole. Maintaining the integrity of the biological crust plays a vital role in fixing the sand under the crust. The precipitation and temperature conditions in the Mugetan sandy land could satisfy the demand of biological crust formation and development. If rational vegetation measures are adopted in the region with moving sand dunes, the lichen-moss-algae biological curst will form after ten years, but it still takes more time for the sand dunes to reach the nutrient enrichment state. If the biological curst is partly broken due to human activities, reasonable closure and restoration measures can shorten the restoration time of the biological crust.

  4. Aggregate stability and soil degradation in the tropics

    International Nuclear Information System (INIS)

    Mbagwu, J.S.C.

    2004-01-01

    Aggregate stability is a measure of the structural stability of soils. Factors that influence aggregate stability are important in evaluating the ease with which soils erode by water and/or wind, the potential of soils to crust and/or seal, soil permeability, quasi-steady state infiltration rates and seedling emergence and in predicting the capacity of soils to sustain long-term crop production. Aggregate stability of soils can be measured by the wet-sieving or raindrop techniques. A reduction in soil aggregate stability implies an increase in soil degradation. Hence aggregate stability and soil degradation are interwoven. The measures used can either be preventive or remedial. Preventive practices minimize the chances of soil degradation occurring or the magnitude or severity of the damage when the degradation manifests. These include in Nigeria, (i) manuring and mulching, (ii) planted fallows and cover crops, (iii) sustainable farming systems, (iv) adequate rotations, (v) home gardens or compound farms, (vi) alley cropping and related agro forestry systems, and (vii) chemical fertilizers which are mainly remedial measures. Because of alterations in soil properties that affect particular land uses, soils may degrade for one crop (maize rather sorghum). As long as some land use is possible soil degradation is not always an absolute concept. Decline in agricultural productivity should be evaluated in terms of inputs such as fertilizer use, water management and tillage methods. We can alleviate some types of soil degradation by use of micronutrients, inorganic fertilizers and organic residues. Soil that responds to management practices cannot be said to be degraded. Since crop growth depends on weather, degraded soils may be more sensitive to harsh weather (e.g. drought, temperature) than undegraded soils. A soil is degraded if its productivity falls below the economic threshold even under favourable weather conditions or with judicious inputs. All human

  5. Biochar reduces copper toxicity in Chenopodium quinoa Willd. In a sandy soil.

    Science.gov (United States)

    Buss, Wolfram; Kammann, Claudia; Koyro, Hans-Werner

    2012-01-01

    Mining, smelting, land applications of sewage sludge, the use of fungicides containing copper (Cu), and other human activities have led to widespread soil enrichment and contamination with Cu and potentially toxic conditions. Biochar (BC) can adsorb several substances, ranging from herbicides to plant-inhibiting allelochemicals. However, the range of potential beneficial effects on early-stage plant growth with regard to heavy metal toxicity is largely unexplored. We investigated the ameliorating properties of a forestry-residue BC under Cu toxicity conditions on early plant growth. Young quinoa plants () were grown in the greenhouse in the presence of 0, 2, and 4% BC application (w/w) added to a sandy soil with 0, 50, or 200 μg g Cu supplied. The plants without BC showed severe stress symptoms and reduced growth shortly after Cu application of 50 μg g and died at 200 μg Cu g. Increasing BC concentrations in the growth medium significantly increased the plant performance without Cu toxicity or under Cu stress. At the 4% BC application rate, the plants with 200 μg g Cu almost reached the same biomass as in the control treatment. In the presence of BC, less Cu entered the plant tissues, which had reduced Cu concentrations in the order roots, shoots, leaves. The amelioration effect also was reflected in the plant-soil system CO gas exchange, which showed clear signs of improvement with BC presence. The most likely ameliorating mechanisms were adsorption of Cu to negatively charged BC surfaces and an improvement of the water supply. Overall, BC seems to be a beneficial amendment with the potential to ameliorate Cu toxicity in sandy soils. Further research with a broad spectrum of different soil types, BCs, and crop plants is required. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

  6. Aggregation of surface mine soil by interaction between VAM fungi and lignin degradation products of lespedeza

    Energy Technology Data Exchange (ETDEWEB)

    Rothwell, F.M. (USDA Forest Service, Berea, KY (USA). Northeastern Forest Experiment Station, Forestry Sciences Laboratory)

    1984-01-01

    The external mycelium of a vesicular-arbuscular mycorrhizal (VAM) fungus was effective in aggregating a sandy loam minesoil. The polysaccharide nature of the soil binding agent on hyphal surfaces and on the surfaces of sand particles in contact with the hyphae within the aggregate was demonstrated with the periodic acid-Schiff reagent staining reaction. A possible stabilizing mechanism for macroaggregates was proposed that involves a coupling reaction between glucosamines in the hyphal walls of the fungus with phenolic compounds released during lignin degradation of sericea lespedeza root tissue. 28 refs.

  7. Effects of leachate on geotechnical characteristics of sandy clay soil

    Science.gov (United States)

    Harun, N. S.; Ali, Z. Rahman; Rahim, A. S.; Lihan, T.; Idris, R. M. W.

    2013-11-01

    Leachate is a hazardous liquid that poses negative impacts if leaks out into environments such as soil and ground water systems. The impact of leachate on the downgraded quality in terms of chemical characteristic is more concern rather than the physical or mechanical aspect. The effect of leachate on mechanical behaviour of contaminated soil is not well established and should be investigated. This paper presents the preliminary results of the effects of leachate on the Atterberg limit, compaction and shear strength of leachate-contaminated soil. The contaminated soil samples were prepared by mixing the leachate at ratiosbetween 0% and 20% leachate contents with soil samples. Base soil used was residual soil originated from granitic rock and classified as sandy clay soil (CS). Its specific gravity ranged between 2.5 and 2.64 with clay minerals of kaolinite, muscovite and quartz. The field strength of the studied soil ranged between 156 and 207 kN/m2. The effects of leachate on the Atterberg limit clearly indicated by the decrease in liquid and plastic limit values with the increase in the leachate content. Compaction tests on leachate-contaminated soil caused the dropped in maximum dry density, ρdry and increased in optimum moisture content, wopt when the amount of leachate was increased between 0% and 20%. The results suggested that leachate contamination capable to modify some geotechnical properties of the studied residual soils.

  8. Comparative effects of application of coated and non-coated urea in clayey and sandy paddy soil microcosms examined by the 15N tracer technique. 2. Effects on soil microbial biomass N and microbial 15N immobilization

    International Nuclear Information System (INIS)

    Acquaye, Solomon; Inubushi, Kazuyuki

    2004-01-01

    Nitrogen fertilizer and soil types exert an impact on plant and soil microbial biomass (SMB). A 15 N tracer experiment was conducted to compare the effects of the application of controlled-release coated urea (CRCU) and urea on SMB in gley (clayey) and sandy paddy soils. The fertilizers were applied at the rate of 8 g N m -2 for CRCU as deep-side placement and 10 g N m -2 for urea mixed into soil or applied into floodwater. The soil type and soil layer (surface: few millimeter depth of surface soil to include benthic algae; subsurface: 1 to 20 cm depth), but not the fertilizer type, affected the amount of microbial biomass N (B N ). On an area basis, subsurface soil layers contained about 2-3 times the amount of B N in the surface layers. The seasonal average B N amount i.e. at 1 to 20 cm depth, in the gley soil was 1.67 g N m -2 , compared to 1.20 g N m -2 for the sandy soil. The proportion of B N in total soil N was significantly influenced by the soil type and soil layer, and was higher for the surface layers of both soils and subsurface layer of the sandy soil than for the subsurface layer of gley soil. Soil type, soil layer, and fertilizer type significantly influenced the amount of microbial biomass 15 N (B 15N ). Unlike B N , the amount of B 15N was significantly higher in the surface (11.9-177.3 mg N m -2 ) than in the subsurface soil layers (4.8-83.6 mg N m -2 ), especially with urea application between 60 and 120 DAT (days after transplanting). At 30 DAT, the subsurface layer of the sandy soil showed a higher B 15N (218 mg N m -2 ) amount than the surface layer (133.4 mg N m -2 ). Sandy soil (4.8-218 mg N m -2 ) and urea (6.2-218 mg N m -2 ) induced a larger increase of the amount of B 15 N than the gley soil (6.2-83.6 mg N m -2 ) and CRCU (4.8-40 mg Nm -2 ). Again, the sandy soil, surface soil layers, and urea induced a higher proportion (%) of B 15N in B N than the gley soil, subsurface soil layers, and CRCU, respectively. The soil type affected B N

  9. Irradiated Sewage Sludge for Production of Fennel Plants in Sandy Soil

    International Nuclear Information System (INIS)

    El-Motaium, R. A.; Abo El-Seoud, M. A.

    2004-01-01

    Irradiated sewage sludge (SS) has proved to be a useful organic fertilizer particularly for sandy soil. The objective of this study is to compare the response of fennel (Foeniculum vulgare L.) plants growing in sandy soil to different fertilizer regimes, organic vs. mineral. In a field experiment four levels (20, 40, 60, 80 t/ha) of irradiated and non-irradiated sewage sludge were incorporated into sandy soil, in addition to the control treatment (mineral fertilizer). Samples analysis included the biomass production at the vegetative and flowering stages, chlorophyll content, total and reducing sugars and heavy metals content of the shoots. The data indicate that the biomass production has dramatically increased as the sludge application rate increased in both irradiated and non-irradiated plots. However, the increase was significantly higher under all irradiated treatments than the corresponding rates of non-irradiated treatments at both the vegetative and flowering stages. Also, the biomass production at all levels of application was higher than the control, receiving mineral fertilizer. At the vegetative stage, the biomass values ranged from 3.1 g/plant for the control to 10.2 and 34.1 g/plant at 80 t/ha for non-irradiated and irradiated sewage sludge, respectively. Whereas, at the flowering stage the values ranged from 9.8 g/plant for the control to 23.9 and 65.1 g/plant at 80 t/ha for non-irradiated and irradiated sewage sludge, respectively. Total sugars, reducing sugar, non-reducing sugar, and chlorophyll content has increased as the sludge application rate increased. At 80t/ha application rate of irradiated sludge, the reducing sugars content was 29.39 mg/g DW at the vegetative stage and 37.85 mg/g DW at the flowering stage. Reducing sugars recorded lower values in the control plants, 14.54 mg/g DW at the vegetative stage and 18.78 mg/g DW at the flowering stage. Heavy metals (Zn, Fe, Pb, Cd) of the shoots was also determined. Sewage sludge was a good

  10. Soil physical properties affecting soil erosion in tropical soils

    International Nuclear Information System (INIS)

    Lobo Lujan, D.

    2004-01-01

    The total vegetated land area of the earth is about 11,500 hectare. Of this, about 12% is in South America. Of this, about 14% is degraded area. Water erosion, chemical degradation, wind erosion, and physical degradation have been reported as main types of degradation. In South America water erosion is a major process for soil degradation. Nevertheless, water erosion can be a consequence of degradation of the soil structure, especially the functional attributes of soil pores to transmit and retain water, and to facilitate root growth. Climate, soil and topographic characteristics determine runoff and erosion potential from agricultural lands. The main factors causing soil erosion can be divided into three groups: Energy factors: rainfall erosivity, runoff volume, wind strength, relief, slope angle, slope length; Protection factors: population density, plant cover, amenity value (pressure for use) and land management; and resistance factors: soil erodibility, infiltration capacity and soil management. The degree of soil erosion in a particular climatic zone, with particular soils, land use and socioeconomic conditions, will always result from a combination of the above mentioned factors. It is not easy to isolate a single factor. However, the soil physical properties that determine the soil erosion process, because the deterioration of soil physical properties is manifested through interrelated problems of surface sealing, crusting, soil compaction, poor drainage, impeded root growth, excessive runoff and accelerated erosion. When an unprotected soil surface is exposed to the direct impact of raindrops it can produce different responses: Production of smaller aggregates, dispersed particles, particles in suspension and translocation and deposition of particles. When this has occurred, the material is reorganized at the location into a surface seal. Aggregate breakdown under rainfall depends on soil strength and a certain threshold kinetic energy is needed to start

  11. Vegetation impact on the hydrology of an aeolian sandy soil in a continental climate

    Czech Academy of Sciences Publication Activity Database

    Lichner, Ľ.; Hallett, P. D.; Orfánus, T.; Czachor, H.; Rajkai, K.; Šír, Miloslav; Tesař, Miroslav

    2010-01-01

    Roč. 3, č. 4 (2010), s. 413-420 ISSN 1936-0584 R&D Projects: GA MŠk MEB0808114 Institutional research plan: CEZ:AV0Z20600510 Keywords : sandy soil * water repellency * plant cover * sorptivity * hydraulic conductivity Subject RIV: DA - Hydrology ; Limnology Impact factor: 1.835, year: 2010

  12. Effects of nano-sized zero-valent iron (nZVI) on DDT degradation in soil and its toxicity to collembola and ostracods.

    Science.gov (United States)

    El-Temsah, Yehia S; Joner, Erik J

    2013-06-01

    Nano-sized zero valent iron (nZVI) has been studied for in situ remediation of contaminated soil and ground water. However, little is known about its effects on organisms in soil and aquatic ecosystems. In this study, the effect of nZVI on degradation of DDT and its ecotoxicological effects on collembola (Folsomia candida) and ostracods (Heterocypris incongruens) were investigated. Two soils were used in suspension incubation experiments lasting for 7 and 30 d; a spiked (20 mg DDT kg(-1)) sandy soil and an aged (>50 years) DDT-polluted soil (24 mg DDT kg(-1)). These were incubated with 1 or 10 g nZVI kg(-1), and residual toxicity in soil and the aqueous phase tested using ecotoxicological tests with collembola or ostracods. Generally, addition of either concentration of nZVI to soil led to about 50% degradation of DDT in spiked soil at the end of 7 and 30 d incubation, while the degradation of DDT was less in aged DDT-polluted soil (24%). Severe negative effects of nZVI were observed on both test organisms after 7 d incubation, but prolonged incubation led to oxidation of nZVI which reduced its toxic effects on the tested organisms. On the other hand, DDT had significant negative effects on collembolan reproduction and ostracod development. We conclude that 1 g nZVI kg(-1) was efficient for significant DDT degradation in spiked soil, while a higher concentration was necessary for treating aged pollutants in soil. The adverse effects of nZVI on tested organisms seem temporary and reduced after oxidation. Copyright © 2013 Elsevier Ltd. All rights reserved.

  13. Characterization of biomass residues and their amendment effects on water sorption and nutrient leaching in sandy soil.

    Science.gov (United States)

    Wang, Letian; Tong, Zhaohui; Liu, Guodong; Li, Yuncong

    2014-07-01

    In this study, we evaluated the efficiency of two types of biomass residues (fermentation residues from a bioethanol process, FB; brown mill residues from a papermaking process, BM) as amendments for a sandy soil. The characteristics of these residues including specific surface areas, morphologies and nutrient sorption capacity were measured. The effects of biorefinery residues on water and nutrient retention were investigated in terms of different particle sizes and loadings. The results indicated that bio-based wastes FB and BM were able to significantly improve water and nutrient retention of sandy soil. The residues with larger surface areas had better water and nutrient retention capability. Specifically, in the addition of 10% loading, FB and BM was able to improve water retention by approximately 150% and 300%, while reduce 99% of ammonium and phosphate concentration in the leachate compare to the soil control, respectively. Copyright © 2014 Elsevier Ltd. All rights reserved.

  14. Water management in sandy soil using neutron scattering method

    International Nuclear Information System (INIS)

    Mohamed, K.M.

    2011-01-01

    This study was carried out during 2008/2009 at the Experimental Field of Soil and Water Research Department, Nuclear Research Center, Atomic Energy Authority, Inshas in a newly reclaimed sandy soil. The aims of this work are,- determine soil moisture tension within the active root zone and - detecting the behavior of soil moisture within the active root zoon by defines the total hydraulic potential within the soil profile to predict both of actual evapotranspiration and rate of moisture depletion This work also is aimed to study soil water distribution under drip irrigation system.- reducing water deep percolation under the active root depth.This study included two factors, the first one is the irrigation intervals, and the second one is the application rate of organic manure. Irrigation intervals were 5, 10 and 15 days, besides three application rates of organic manure (0 m 3 /fed, 20 m 3 /fed. and 30 m 3 /fed.) in -three replicates under drip irrigation system, Onion was used as an indicator plant. Obtained data show, generally, that neutron scattering technique and soil moisture retention curve model helps more to study the water behavior in the soil profile.Application of organic manure and irrigation to field capacity is a good way to minimize evapotranspiration and deep percolation, which was zero mm/day in the treated treatments.The best irrigation interval for onion plant, in the studied soil, was 5 days with 30m 3 /fad. an application rate of organic manure.Parameter α of van Genuchent's 1980 model was affected by the additions of organic manure, which was decreased by addition of organic manure decreased it. Data also showed that n parameter was decreased by addition of organic manure Using surfer program is a good tool to describe the water distribution in two directions (vertical and horizontal) through soil profile.

  15. [Soil moisture dynamics and water balance of Salix psammophila shrubs in south edge of Mu Us Sandy Land].

    Science.gov (United States)

    An, Hui; An, Yu

    2011-09-01

    Taking the artificial sand-fixing Salix psammophila shrubs with different plant density (0.2, 0.6, and 0.8 plants x m(-2)) in Mu Us Sandy Land as test objects, this paper studied the soil moisture dynamics and evapotranspiration during growth season. There existed obvious differences in the soil moisture dynamics and evapotranspiration among the shrubs. The soil moisture content changed in single-hump-shape with the increase of plant density, and in "S" shape during growth season, being closely correlated with precipitation. The evapotranspiration was the highest (114.5 mm) in the shrubs with a density 0.8 plants x m(-1), accounting for 90.8% of the total precipitation during growth season, and the lowest (109.7 mm) in the shrubs with a density 0.6 plants x m(-2) Based on the soil moisture dynamics and water balance characteristics, the appropriate planting density of S. psammophila shrubs in Mu Us Sandy Land could be 0.6 plants x m(-2).

  16. Spatial variation in the degradation rate of the pesticides isoproturon, azoxystrobin and diflufenican in soil and its relationship with chemical and microbial properties

    International Nuclear Information System (INIS)

    Bending, Gary D.; Lincoln, Suzanne D.; Edmondson, Rodney N.

    2006-01-01

    The extent of within field variability in the degradation rate of the pesticides isoproturon, azoxystrobin and diflufenican, and the role of intrinsic soil factors and technical errors in contributing to the variability, was investigated in sites on sandy-loam and clay-loam. At each site, 40 topsoil samples were taken from a 160x60 m area, and pesticides applied in the laboratory. Time to 25% dissipation (DT25) ranged between 13 and 61 weeks for diflufenican, 5.6 and 17.2 weeks for azoxystrobin, and 0.3 and 12.5 weeks for isoproturon. Variability in DT25 was higher in the sandy-loam in which there was also greatest variability in soil chemical and microbial properties. Technical error associated with pesticide extraction, analysis and lack of model fit during derivation of DT25 accounted for between 5.3 and 25.8% of the variability for isoproturon and azoxystrobin, but could account for almost all the variability for diflufenican. Azoxystrobin DT25, sorption and pH were significantly correlated. - Spatial variation determines risk assessment for pesticides in soil

  17. Spatial variation in the degradation rate of the pesticides isoproturon, azoxystrobin and diflufenican in soil and its relationship with chemical and microbial properties

    Energy Technology Data Exchange (ETDEWEB)

    Bending, Gary D. [Warwick HRI, University of Warwick, Wellesbourne, Warwick CV35 9EF (United Kingdom)]. E-mail: gary.bending@warwick.ac.uk; Lincoln, Suzanne D. [Warwick HRI, University of Warwick, Wellesbourne, Warwick CV35 9EF (United Kingdom); Edmondson, Rodney N. [Warwick HRI, University of Warwick, Wellesbourne, Warwick CV35 9EF (United Kingdom)

    2006-01-15

    The extent of within field variability in the degradation rate of the pesticides isoproturon, azoxystrobin and diflufenican, and the role of intrinsic soil factors and technical errors in contributing to the variability, was investigated in sites on sandy-loam and clay-loam. At each site, 40 topsoil samples were taken from a 160x60 m area, and pesticides applied in the laboratory. Time to 25% dissipation (DT25) ranged between 13 and 61 weeks for diflufenican, 5.6 and 17.2 weeks for azoxystrobin, and 0.3 and 12.5 weeks for isoproturon. Variability in DT25 was higher in the sandy-loam in which there was also greatest variability in soil chemical and microbial properties. Technical error associated with pesticide extraction, analysis and lack of model fit during derivation of DT25 accounted for between 5.3 and 25.8% of the variability for isoproturon and azoxystrobin, but could account for almost all the variability for diflufenican. Azoxystrobin DT25, sorption and pH were significantly correlated. - Spatial variation determines risk assessment for pesticides in soil.

  18. Response of sesame to population densities and nitrogen fertilization on newly reclaimed sandy soils

    International Nuclear Information System (INIS)

    Noorka, I.R.; Hafiz, S.I.

    2011-01-01

    Two field experiments were conducted at the Experimental Farm of Faculty of Agriculture, Suez Canal University at Ismailia during 2008 and 2009 seasons to study the effect of nitrogen fertilization and planting density on growth , yield, its attributes as well as seed quality of new sesame variety (Taka 2 cv.). On newly reclaimed sandy soils of Ismailia Governorate, Egypt, experimental design in split plots form with four replications was used. Four levels of nitrogen fertilization 55, 105, 155 and 205 Kg/ha were arranged randomly in the main plots and three planting distances between hills (10, 15 and 20 cm, respectively) were distributed at random in the sub plots. Increasing N fertilizer level up to 205 Kg/ha significantly increased plant height, fruiting zone length, height of the first fruiting branch, number of branches and capsules/plant, 1000-seed weight, seed weight/plant, seed oil content (%) and seed and oil yields /ha. Decreasing planting distance from 20 to 15 and 10 cm consistently and significantly increased plant height, height of the first fruiting branch and seed and oil yields /ha. The reverse was true regarding the yield components. These results were expected, since experiment soil was newly reclaimed sandy soil and very poor in the nutrients and organic matter. (author)

  19. Background levels of some trace elements in sandy soil of Abou-Zabal, and its variation with soil depth determines by neutron activation analysis. Vol. 4

    International Nuclear Information System (INIS)

    Abdel-Sabour, M.F.; Sanad, W.; Flex, H.; Abdel-Haleem, A.S.; Zohny, E.

    1996-01-01

    The variation in soil total heavy metal contents (horizontally and vertically) in small land area (about one acre) was investigated using neutron activities analysis technique. The background levels found in the sandy soil of Abou-Zabal are also discussed in relation to the findings of other workers. 5 tabs

  20. Background levels of some trace elements in sandy soil of Abou-Zabal, and its variation with soil depth determines by neutron activation analysis. Vol. 4.

    Energy Technology Data Exchange (ETDEWEB)

    Abdel-Sabour, M F [Soil Pollution Unit, Soil and Water Department. Nuclear Research Center, Atomic energy Authority, Cairo, (Egypt); Sanad, W; Flex, H; Abdel-Haleem, A S [Hot Lab. Center, Atomic Energy Authority, Cairo (Egypt); Zohny, E [Physics Department, Faculty of Science, Cairo Univ., Beni-Sweif Branch, Cairo, (Egypt)

    1996-03-01

    The variation in soil total heavy metal contents (horizontally and vertically) in small land area (about one acre) was investigated using neutron activities analysis technique. The background levels found in the sandy soil of Abou-Zabal are also discussed in relation to the findings of other workers. 5 tabs.

  1. Enantioselective degradation and enantiomerization of indoxacarb in soil.

    Science.gov (United States)

    Sun, Dali; Pang, Junxiao; Qiu, Jing; Li, Li; Liu, Chenglan; Jiao, Bining

    2013-11-27

    In this study, the enantioselective degradation and enantiomerizaton of indoxacarb were investigated in two soils under nonsterilized and sterilized conditions using a chiral OD-RH column on a reversed-phase HPLC. Under nonsterilized conditions, the degradation of indoxacarb in two soils was enantioselective. In acidic soil, the half-lives of R-(-)- and S-(+)-indoxacarb were 10.43 and 14.00 days, respectively. Acidic soil was preferential to the degradation of R-(-)-indoxacarb. In alkaline soil, the half-lives of R-(-)- and S-(+)-indoxacarb were 12.14 and 4.88 days, respectively. S-(+)-Indoxacarb was preferentially degraded. Under sterilized conditions, approximately 5-10% of the initial concentration degraded after 75 days of incubation in acidic soil, whereas in alkaline soil, approximately half of the initial concentration degraded due to chemical hydrolysis under alkaline conditions. Enantiomerization was also discovered in acidic and alkaline soils. The results showed that mutual transformation existed between two enantiomers and that S-(+)-indoxacarb had a significantly higher inversion rate to R-(-)-indoxacarb than its antipode.

  2. Acidification of sandy grasslands - consequences for plant diversity

    DEFF Research Database (Denmark)

    Olsson, Pål Axel; Mårtensson, Linda-Maria; Bruun, Hans Henrik

    2009-01-01

    soil; a number of nationally red-listed species showed a similar pattern. Plant species diversity and number of red-listed species increased with slope. Where the topsoil had been acidified, limestone was rarely present above a depth of 30 cm. The presence of limestone restricts the availability......Questions: (1) Does soil acidification in calcareous sandy grasslands lead to loss of plant diversity? (2) What is the relationship between the soil content of lime and the plant availability of mineral nitrogen (N) and phosphorus (P) in sandy grasslands? Location: Sandy glaciofluvial deposits......). Environmental variables were recorded at each plot, and soil samples were analysed for exchangeable P and N, as well as limestone content and pH. Data were analysed with regression analysis and canonical correspondence analysis. Results: Plant species richness was highest on weakly acid to slightly alkaline...

  3. The soil structure investigation for the interpreting radiocaesium behaviour in upper horizons of Chernobyl contaminated sandy soils

    International Nuclear Information System (INIS)

    Vazhinskij, A.G.

    2002-01-01

    The soil-composing particles in natural environment form aggregates of different stability. For soils (topsoil) of contrasting type from Chernobyl NPP area the particle size and microaggregate analyses have been performed and the distribution of Cs 137 in the obtained fractions has been studied. Results of long-term investigation of Cs 137 vertical migration in sandy soils of 50-km zone around Chernobyl NPP have been compared with data on radiocaesium distribution among water-stable aggregates and particles of various size in studied soils. On the basis of particle size analysis and aggregate soil composition the size of soil components with vertical migration potential, and the amount of Cs 137 potentially tending to migrate with the soil components along soil profile have been assessed. Based on findings showing Cs 137 partitioning among water-stable soil aggregates of diverse size and pattern of the radionuclide vertical distribution in top 0-10 cm soil layer, it was assumed that neither shift of peak radiocaesium level from upper soil layer downwards nor the so-called slow constituent of Cs 137 vertical migration (in terms of quasi diffusion description of Cs 137 profile in soil) could not be explained by self-motion of soil aggregates and particles with associated radiocaesium. Hypothesis of root intermixing as principal mechanism responsible for Cs 137 vertical transport in top 0-10 cm soil layer was postulated

  4. North American Soil Degradation: Processes, Practices, and Mitigating Strategies

    Directory of Open Access Journals (Sweden)

    R. L. Baumhardt

    2015-03-01

    Full Text Available Soil can be degraded by several natural or human-mediated processes, including wind, water, or tillage erosion, and formation of undesirable physical, chemical, or biological properties due to industrialization or use of inappropriate farming practices. Soil degradation occurs whenever these processes supersede natural soil regeneration and, generally, reflects unsustainable resource management that is global in scope and compromises world food security. In North America, soil degradation preceded the catastrophic wind erosion associated with the dust bowl during the 1930s, but that event provided the impetus to improve management of soils degraded by both wind and water erosion. Chemical degradation due to site specific industrial processing and mine spoil contamination began to be addressed during the latter half of the 20th century primarily through point-source water quality concerns, but soil chemical degradation and contamination of surface and subsurface water due to on-farm non-point pesticide and nutrient management practices generally remains unresolved. Remediation or prevention of soil degradation requires integrated management solutions that, for agricultural soils, include using cover crops or crop residue management to reduce raindrop impact, maintain higher infiltration rates, increase soil water storage, and ultimately increase crop production. By increasing plant biomass, and potentially soil organic carbon (SOC concentrations, soil degradation can be mitigated by stabilizing soil aggregates, improving soil structure, enhancing air and water exchange, increasing nutrient cycling, and promoting greater soil biological activity.

  5. Geotechnical response of pipelines shallowly embedded in clayey and sandy soils

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, Jose Renato M.S. [Military Institute of Engineering (IME), Rio de Janeiro, RJ (Brazil); Borges, Ricardo G. [Centro de Pesquisa Leopoldo A. Miguez de Melo (CENPES/PETROBRAS), Rio de Janeiro, RJ (Brazil); Feitoza, Jaquelline; Almeida, Maria C.F.; Almeida, Marcio S.S. [Universidade Federal do Rio de Janeiro (COPPE/UFRJ), Rio de Janeiro, RJ (Brazil). Coordenacao dos Programas de Pos-graduacao de Engenharia

    2009-07-01

    Offshore and onshore pipelines used for oil and gas transportation are often buried to avoid eventual damages and also to provide movement constraint. The soil cover supply resistance against upward and lateral displacements of the pipe caused by thermally-induced axial loading, which can lead to structural buckling. The clear understanding of this behavior is critical for the development of new analysis tools and new design criteria which could minimize future accidents. In this way, research on pipe-soil interaction behavior has been undertaken using both clayey and sandy soils through physical and numerical simulations. This paper is part of a research effort to provide a pipe-soil interaction guideline suitable for application in pipeline design along the Brazilian coast. This work presents a comprehensive set of lateral buckling simulation tests using the COPPE-UFRJ geotechnical centrifuge. The chosen soils are typical of the Brazilian coast and therefore very representative of tropical regions. Physical and numerical results are compared and other research works are considered in order to assess the overall uplift resistance. In flight T-bar and cone penetration tests were undertaken to provide a soil resistance profile which was used to trace dimensionless curves that could be adopted in similar design situations. (author)

  6. Aggregate-associated carbon and nitrogen in reclaimed sandy loam soils

    Energy Technology Data Exchange (ETDEWEB)

    Wick, A.F.; Stahl, P.D.; Ingram, L.J. [Virginia Polytechnic Institute & State University, Blacksburg, VA (United States)

    2009-11-15

    Minimal research has been conducted on aggregate, C, and N in coarse-textured soils used to reclaim surface coal mine lands. Furthermore, little is known about the contribution different plant communities make to the recovery of aggregation in these soils. Two chronosequences of semiarid reclaimed sites with sandy loam soils were sampled under shrub- and grass-dominated communities. Aggregation, aggregate fractions, and associated C and N were measured. No definitive trends of increasing macroaggregates between sites were observed undershrubs; however, macro- and microaggregation was greater in the 16-yr-old (0.20 and 0.23 kg aggregate kg{sup -1} soil, respectively) than in the 5-yr-old soils (0.02 and 0.08 kg aggregate kg{sup -1} soil, respectively) under grasses. Although C and N concentrations were drastically reduced (50-75%) with mining activity between the <1-yr-old and native soils, aggregate C and N concentrations tinder shrubs and grasses were similar to each other and to the native soils in the 5-yr-old site. Sods under grass in the 16-yr-old site had lower available and aggregate-occluded C and N concentrations than the 5-yr-old site, while C and N concentrations did not change between 5- and 16-yr-old soils under shrubs. Conversely, aggregate C and N pool sizes under shrubs and grasses both increased with site age to conditions similar to those observed in the native soil. Reclaimed shrub site soils had consistently higher C concentrations in the older reclaimed sites (10 and 16 yr old) than the soils under grasses, indicating greater accumulation and retention of C and N in organic material under shrub than grass communities in semiarid reclaimed sites.

  7. Hydrocarbon degradation potential in reference soils and soils contaminated with jet fuel

    International Nuclear Information System (INIS)

    Lee, R.F.; Hoeppel, R.

    1991-01-01

    Petroleum degradation in surface and subsurface soils is affected by such factors as moisture content, pH, soil type, soil organics, temperature, and oxygen concentrations. In this paper, the authors determine the degradation rates of 14 C-labeled hydrocarbons added to soils collected from a contaminated surface site, contaminated subsurface sites, and a clean reference site. The radiolabeled hydrocarbons used include benzene, toluene, naphthalene, 1-methynaphthalene, phenanthrene, fluorene, anthracene, chrysene, and hexadecane. Microbial degradation rates were based on determination of mineralization rates (production of 14 CO 2 ) of hydrocarbons that were added to soil samples. Since water was added and oxygen was not limiting, the hydrocarbon rates determined are likely to be higher than those occurring in situ. Using radiolabeled hydrocarbons, information can be provided on differences in the degradation rates of various petroleum compounds in different types of soils at a site, on possible production of petroleum metabolites in the soil, and on the importance of anaerobic petroleum degradation and the effects of nutrient, water, and surfactant addition on biodegradation rates

  8. Experimental Investigation of Phenanthrene Pollutant Removal Efficiency for Contaminated Sandy Soil by Enhanced Soil Washing

    Directory of Open Access Journals (Sweden)

    Saif salah Alquzweeni

    2016-12-01

    Full Text Available Polycyclic aromatic hydrocarbons (PAHs are environmental concerns that must be removed to acceptable level. This research assesses two agents (Na2EDTA and SDS to remediate contaminated sandy soil, spiked with 500mg/kg phenanthrene. Five sets of experiments (batch are applied to investigate the optimal of five influencing factors on soil remediation: Na2EDTA-SDS concentration, liquid/Solid ratio, stirring speed, pH value of flushing solution and mixing time. The results of batch experiments showed that SDS has high phenanthrene removal efficiency (90%, while Na2EDTA shows no phenanthrene removal. pH has no effect on phenanthrene removal. To study the influence of flow rates on the removal efficiency of contaminants, two column tests with hydraulic gradient of 0.2 and 1.2 conducted by SDS solution. The results illustrate that high phenanthrene removal from soil obtained by 1.2 hydraulic gradient condition. The SDS flushing solution removed approximately 69% and 81% of phenanthrene from soil under low and high hydraulic gradients, respectively. It was concluded that phenanthrene removal depend on surfactant micelles formation. Overall, the study showed that soil flushing removal efficiency for contaminants depends on the flushing agents selectivity and affinity to the contaminants and the condition of hydraulic gradient.

  9. Seasonal variations measured by TDR and GPR on an anthropogenic sandy soil and the implications for utility detection

    Science.gov (United States)

    Curioni, Giulio; Chapman, David N.; Metje, Nicole

    2017-06-01

    The electromagnetic (EM) soil properties are dynamic variables that can change considerably over time, and they fundamentally affect the performance of Ground Penetrating Radar (GPR). However, long-term field studies are remarkably rare and records of the EM soil properties and their seasonal variation are largely absent from the literature. This research explores the extent of the seasonal variation of the apparent permittivity (Ka) and bulk electrical conductivity (BEC) measured by Time Domain Reflectometry (TDR) and their impact on GPR results, with a particularly important application to utility detection. A bespoke TDR field monitoring station was specifically developed and installed in an anthropogenic sandy soil in the UK for 22 months. The relationship between the temporal variation of the EM soil properties and GPR performance has been qualitatively assessed, highlighting notably degradation of the GPR images during wet periods and a few days after significant rainfall events following dry periods. Significantly, it was shown that by assuming arbitrary average values (i.e. not extreme values) of Ka and BEC which do not often reflect the typical conditions of the soil, it can lead to significant inaccuracies in the estimation of the depth of buried targets, with errors potentially up to approximately 30% even over a depth of 0.50 m (where GPR is expected to be most accurate). It is therefore recommended to measure or assess the soil conditions during GPR surveys, and if this is not possible to use typical wet and dry Ka values reported in the literature for the soil expected at the site, to improve confidence in estimations of target depths.

  10. Seed Burial Depth and Soil Water Content Affect Seedling Emergence and Growth of Ulmus pumila var. sabulosa in the Horqin Sandy Land

    Directory of Open Access Journals (Sweden)

    Jiao Tang

    2016-01-01

    Full Text Available We investigated the effects of seed burial depth and soil water content on seedling emergence and growth of Ulmus pumila var. sabulosa (sandy elm, an important native tree species distributed over the European-Asian steppe. Experimental sand burial depths in the soil were 0.5, 1.0, 1.5, 2.0 and 2.5 cm, and soil water contents were 4%, 8%, 12% and 16% of field capacity. All two-way ANOVA (five sand burial depths and four soil water contents results showed that seed burial depths, soil water content and their interactions significantly affected all the studied plant variables. Most of the times, seedling emergence conditions were greater at the lower sand burial depths (less than 1.0 cm than at the higher (more than 1.0 cm seed burial depths, and at the lower water content (less than 12% than at the higher soil water content. However, high seed burial depths (more than 1.5 cm or low soil water content (less than 12% reduced seedling growth or change in the root/shoot biomass ratios. In conclusion, the most suitable range of sand burial was from 0.5 to 1.0 cm soil depth and soil water content was about 12%, respectively, for the processes of seedling emergence and growth. These findings indicate that seeds of the sandy elm should be kept at rather shallow soil depths, and water should be added up to 12% of soil capacity when conducting elm planting and management. Our findings could help to create a more appropriate sandy elm cultivation and understand sparse elm woodland recruitment failures in arid and semi-arid regions.

  11. Estimation of Nitrogen Pools in Irrigated Potato Production on Sandy Soil Using the Model SUBSTOR

    Science.gov (United States)

    Prasad, Rishi; Hochmuth, George J.; Boote, Kenneth J.

    2015-01-01

    Recent increases in nitrate concentrations in the Suwannee River and associated springs in northern Florida have raised concerns over the contributions of non-point sources. The Middle Suwannee River Basin (MSRB) is of special concern because of prevalent karst topography, unconfined aquifers and sandy soils which increase vulnerability of the ground water contamination from agricultural operations- a billion dollar industry in this region. Potato (Solanum tuberosum L.) production poses a challenge in the area due to the shallow root system of potato plants, and low water and nutrient holding capacity of the sandy soils. A four-year monitoring study for potato production on sandy soil was conducted on a commercial farm located in the MSRB to identify major nitrogen (N) loss pathways and determine their contribution to the total environmental N load, using a partial N budget approach and the potato model SUBSTOR. Model simulated environmental N loading rates were found to lie within one standard deviation of the observed values and identified leaching loss of N as the major sink representing 25 to 38% (or 85 to 138 kg ha-1 N) of the total input N (310 to 349 kg ha-1 N). The crop residues left in the field after tuber harvest represented a significant amount of N (64 to 110 kg ha-1N) and posed potential for indirect leaching loss of N upon their mineralization and the absence of subsequent cover crops. Typically, two months of fallow period exits between harvest of tubers and planting of the fall row crop (silage corn). The fallow period is characterized by summer rains which pose a threat to N released from rapidly mineralizing potato vines. Strategies to reduce N loading into the groundwater from potato production must focus on development and adoption of best management practices aimed on reducing direct as well as indirect N leaching losses. PMID:25635904

  12. Transformation of the herbicide [14C]glufosinate in soils

    International Nuclear Information System (INIS)

    Smith, A.E.

    1989-01-01

    The degradation of 2 μg/g [ 14 C]glufosinate (DL-homoalan-4-ylmethylphosphinic acid) was studied in clay, clay loam, and sandy loam soils at 85% field capacity and at 20 degree C. Over a 4-week period the soils were extracted and analyzed for transformation products by radiochemical and gas chromatographic techniques. In all soils there was release of [ 14 C]carbon dioxide and formation of [ 14 C]-3-(hydroxymethylphosphinyl)propionic acid (MPPA) as major degradation products. Within 21 days, about 55% of the applied 14 C herbicide had been transformed to MPPA in the sandy loam and 19% to [ 14 C]carbon dioxide. After 28 days, approximately 45% of the 14 C herbicide had been transformed to MPPA in the clay and clay loam and 10% released as [ 14 C]carbon dioxide. At all samplings, other 14 C transformation products appeared to be insignificant

  13. Degradation of chlorpyrifos in tropical rice soils.

    Science.gov (United States)

    Das, Subhasis; Adhya, Tapan K

    2015-04-01

    Chlorpyrifos [O,O-diethyl O-(3,5,6-trichloro-2-pyridinol) phosphorothioate] is used worldwide as an agricultural insecticide against a broad spectrum of insect pests of economically important crops including rice, and soil application to control termites. The insecticide mostly undergoes hydrolysis to diethyl thiophosphoric acid (DETP) and 3,5,6-trichloro-2-pyridinol (TCP), and negligible amounts of other intermediate products. In a laboratory-cum-greenhouse study, chlorpyrifos, applied at a rate of 10 mg kg(-1) soil to five tropical rice soils of wide physico-chemical variability, degraded with a half-life ranging from 27.07 to 3.82 days. TCP was the major metabolite under both non-flooded and flooded conditions. Chlorpyrifos degradation had significant negative relationship with electrical conductivity (EC), cation exchange capacity (CEC), clay and sand contents of the soils under non-flooded conditions. Results indicate that degradation of chlorpyrifos was accelerated with increase in its application frequency, across the representative rice soils. Management regimes including moisture content and presence or absence of rice plants also influenced the process. Biotic factors also play an important role in the degradation of chlorpyrifos as demonstrated by its convincing degradation in mineral salts medium inoculated with non-sterile soil suspension. Copyright © 2015 Elsevier Ltd. All rights reserved.

  14. Partitioning of organic matter and heavy metals in a sandy soil: Effects of extracting solution, solid to liquid ratio and pH

    NARCIS (Netherlands)

    Fest, P.M.J.; Temminghoff, E.J.M.; Comans, R.N.J.; Riemsdijk, van W.H.

    2008-01-01

    In sandy soils the behavior of heavy metals is largely controlled by soil organic matter (solid and dissolved organic matter; SOC and DOC). Therefore, knowledge of the partitioning of organic matter between the solid phase and soil solution is essential for adequate predictions of the total

  15. Petroleum degradation by endophytic Streptomyces spp. isolated from plants grown in contaminated soil of southern Algeria.

    Science.gov (United States)

    Baoune, Hafida; Ould El Hadj-Khelil, Aminata; Pucci, Graciela; Sineli, Pedro; Loucif, Lotfi; Polti, Marta Alejandra

    2018-01-01

    Petroleum hydrocarbons are well known by their high toxicity and recalcitrant properties. Their increasing utilization around worldwide led to environmental contamination. Phytoremediation using plant-associated microbe is an interesting approach for petroleum degradation and actinobacteria have a great potential for that. For this purpose, our study aimed to isolate, characterize, and assess the ability of endophytic actinobacteria to degrade crude petroleum, as well as to produce plant growth promoting traits. Seventeen endophytic actinobacteria were isolated from roots of plants grown naturally in sandy contaminated soil. Among them, six isolates were selected on the basis of their tolerance to petroleum on solid minimal medium and characterized by 16S rDNA gene sequencing. All petroleum-tolerant isolates belonged to the Streptomyces genus. Determination by crude oil degradation by gas chromatorgraph-flame ionization detector revealed that five strains could use petroleum as sole carbon and energy source and the petroleum removal achieved up to 98% after 7 days of incubation. These isolates displayed an important role in the degradation of the n-alkanes (C 6 -C 30 ), aromatic and polycyclic aromatic hydrocarbons. All strains showed a wide range of plant growth promoting features such as siderophores, phosphate solubilization, 1-aminocyclopropane-1-carboxylate deaminase, nitrogen fixation and indole-3-acetic acid production as well as biosurfactant production. This is the first study highlighting the petroleum degradation ability and plant growth promoting attributes of endophytic Streptomyces. The finding suggests that the endophytic actinobacteria isolated are promising candidates for improving phytoremediation efficiency of petroleum contaminated soil. Copyright © 2017 Elsevier Inc. All rights reserved.

  16. Monitoring of Gasoline-ethanol Degradation In Undisturbed Soil

    Science.gov (United States)

    Österreicher-Cunha, P.; Nunes, C. M. F.; Vargas, E. A.; Guimarães, J. R. D.; Costa, A.

    Environmental contamination problems are greatly emphasised nowadays because of the direct threat they represent for human health. Traditional remediation methods fre- quently present low efficiency and high costs; therefore, biological treatment is being considered as an accessible and efficient alternative for soil and water remediation. Bioventing, commonly used to remediate petroleum hydrocarbon spills, stimulates the degradation capacity of indigenous microorganisms by providing better subsur- face oxygenation. In Brazil, gasoline and ethanol are mixed (78:22 v/v); some authors indicate that despite gasoline high degradability, its degradation in subsurface is hin- dered by the presence of much more rapidly degrading ethanol. Contaminant distribu- tion and degradation in the subsurface can be monitored by several physical, chemical and microbiological methodologies. This study aims to evaluate and follow the degra- dation of a gasoline-ethanol mixture in a residual undisturbed tropical soil from Rio de Janeiro. Bioventing was used to enhance microbial degradation. Shifts in bacte- rial culturable populations due to contamination and treatment effects were followed by conventional microbiology methods. Ground Penetrating Radar (GPR) measure- ments, which consist of the emission of electro-magnetic waves into the soil, yield a visualisation of contaminant degradation because of changes in soil conductivity due to microbial action on the pollutants. Chemical analyses will measure contaminant residue in soil. Our results disclosed contamination impact as well as bioventing stim- ulation on soil culturable heterotrophic bacterial populations. This multidisciplinary approach allows for a wider evaluation of processes occurring in soil.

  17. Calibration Curve of Neutron Moisture Meter for Sandy Soil under Drip Irrigation System

    International Nuclear Information System (INIS)

    Mohammad, Abd El- Moniem M.; Gendy, R. W.; Bedaiwy, M. N.

    2004-01-01

    The aim of this work is to construct a neutron calibration curve in order to be able to use the neutron probe in sandy soils under drip irrigation systems. The experimental work was conducted at the Soil and Water Department of the Nuclear Research Center, Atomic Energy Authority. Three replicates were used along the lateral lines of the drip irrigation system. For each dripper, ten neutron access tubes were installed to 100-cm depth at distances of 5, 15 and 25 cm from the dripper location around the drippers on the lateral line, as well as between lateral lines. The neutron calibrations were determined at 30, 45, and 60-cm depths. Determining coefficients as well as t-test in pairs were employed to detect the accuracy of the calibrations. Results indicated that in order for the neutron calibration curve to express the whole wet area around the emitter; three-access tubes must be installed at distances of 5, 15, and 25 cm from the emitter. This calibration curve will be correlating the average count ratio (CR) at the studied soil depth of the three locations (5, 15, and 25-cm distances from the emitter) to the average moisture content (θ) for this soil depth of the entire wetted area. This procedure should be repeated at different times in order to obtain different θ and C.R values, so that the regression equation of calibration curve at this soil depth can be obtained. To determine the soil moisture content, the average CR of the three locations must be taken and substituted into the regression equation representing the neutron calibration curve. Results taken from access tubes placed at distances of 15 cm from the emitter, showed good agreement with the average calibration curve both for the 45- and the 60-cm depths, suggesting that the 15-cm distance may provide a suitable substitute for the simultaneous use of the three different distances of 5, 15 and 25 cm. However, the obtained results show also that the neutron calibration curves of the 30-cm depth for

  18. Adsorption behavior of endosulfan on alluvial soil

    International Nuclear Information System (INIS)

    Ashraf, M.; Sherazi, S.T.H.; Nizamani, S.M.; Bhanger, M.I.

    2012-01-01

    The present study was carried out to assess the behavior of endosulfan pesticide in alluvial soil under laboratory conditions. Sandy loam soil was studied to evaluate the fate of applied endosulfan with respect to soil properties. Known amount of endosulfan was added on alluvial soil in PVC column and eluted with 1000 ml of water. Eluents were collected in 10 parts, each of 100 ml. The soil in the column was divided in to three equal parts, each of 10 cm. Each part of the soil and eluents were analyzed for the determination of Endosulfan level using GC- mu ECD and GC-MS techniques. The kinetic and equilibrium adsorption characteristics of endosulfan on sandy loam soil was also studied and found that it follows Ho's pseudo second order and Freundlich isotherm. The present study revealed that a-and beta-Endosulfan was determined efficiently with their degraded products in alluvial soil under laboratory conditions with above mentioned instruments. (author)

  19. A Constitutive Relationship for Gravelly Soil Considering Fine Particle Suffusion.

    Science.gov (United States)

    Zhang, Yuning; Chen, Yulong

    2017-10-23

    Suffusion erosion may occur in sandy gravel dam foundations that use suspended cutoff walls. This erosion causes a loss of fine particles, degrades the soil strength and deformation moduli, and adversely impacts the cutoff walls of the dam foundation, as well as the overlying dam body. A comprehensive evaluation of these effects requires models that quantitatively describe the effects of fine particle losses on the stress-strain relationships of sandy gravels. In this work, we propose an experimental scheme for studying these types of models, and then perform triaxial and confined compression tests to determine the effects of particle losses on the stress-strain relationships. Considering the Duncan-Chang E-B model, quantitative expressions describing the relationship between the parameters of the model and the particle losses were derived. The results show that particle losses did not alter the qualitative stress-strain characteristics of the soils; however, the soil strength and deformation moduli were degraded. By establishing the relationship between the parameters of the model and the losses, the same model can then be used to describe the relationship between sandy gravels and erosion levels that vary in both time and space.

  20. A Constitutive Relationship for Gravelly Soil Considering Fine Particle Suffusion

    Directory of Open Access Journals (Sweden)

    Yuning Zhang

    2017-10-01

    Full Text Available Suffusion erosion may occur in sandy gravel dam foundations that use suspended cutoff walls. This erosion causes a loss of fine particles, degrades the soil strength and deformation moduli, and adversely impacts the cutoff walls of the dam foundation, as well as the overlying dam body. A comprehensive evaluation of these effects requires models that quantitatively describe the effects of fine particle losses on the stress-strain relationships of sandy gravels. In this work, we propose an experimental scheme for studying these types of models, and then perform triaxial and confined compression tests to determine the effects of particle losses on the stress-strain relationships. Considering the Duncan-Chang E-B model, quantitative expressions describing the relationship between the parameters of the model and the particle losses were derived. The results show that particle losses did not alter the qualitative stress-strain characteristics of the soils; however, the soil strength and deformation moduli were degraded. By establishing the relationship between the parameters of the model and the losses, the same model can then be used to describe the relationship between sandy gravels and erosion levels that vary in both time and space.

  1. Agrogenic degradation of soils in Krasnoyarsk forest-steppe

    Science.gov (United States)

    Shpedt, A. A.; Trubnikov, Yu. N.; Zharinova, N. Yu.

    2017-10-01

    Agrogenic degradation of soils in Krasnoyarsk forest-steppe was investigated. Paleocryogenic microtopography of microlows and microhighs in this area predetermined the formation of paragenetic soil series and variegated soil cover. Specific paleogeographic conditions, thin humus horizons and soil profiles, and long-term agricultural use of the land resulted in the formation of soils unstable to degradation processes and subjected to active wind and water erosion. Intensive mechanical soil disturbances during tillage and long-term incorporation of the underlying Late Pleistocene (Sartan) calcareous silty and clay loams into the upper soil horizons during tillage adversely affected the soil properties. We determined the contents of total and labile humus and easily decomposable organic matter and evaluated the degree of soil exhaustion. It was concluded that in the case of ignorance of the norms of land use and soil conservation practices, intense soil degradation would continue leading to complete destruction of the soil cover within large areas.

  2. The Use of Ionizing Radiation to Prepare Polymeric Agro-waste Composite for Sandy Soil Application

    International Nuclear Information System (INIS)

    Elhady, M.A.; Elnahas, H.H.; Meligi, G.A.; Ammar, A.H.

    2015-01-01

    Super absorbent hydrogel composite (SHC) by radiation induced crosslinking of polyacrylamide (PAAM)/ rice straw (RS) composite and hydrophilic membrane system based on polyvinyl alcohol (PVA) for possible applications in agricultural field of sandy soil was studied. The factors affecting the quick and capacity for retaining irrigated water of swelling behaviour of prepared hydrogel composite through hydrophilic membrane system and increasing foaming/ porosity of the SHC were studied. The mechanism for this is most likely a prevention of irrigated water to pass through sandy particles for a time ranged from 20 to 40 min for the fluid uptake capacity and swelling of the SHC to take and swelling place without almost any loss of irrigated water. Effect of acid/ alkalinity (PH) and salt concentration were investigation.

  3. Regional analysis of groundwater phosphate concentrations under acidic sandy soils: Edaphic factors and water table strongly mediate the soil P-groundwater P relation.

    Science.gov (United States)

    Mabilde, Lisa; De Neve, Stefaan; Sleutel, Steven

    2017-12-01

    Historic long-term P application to sandy soils in NW-Europe has resulted in abundant sorption, saturation and eventually leaching of P from soil to the groundwater. Although many studies recognize the control of site-specific factors like soil texture and phosphate saturation degree (PSD), the regional-scaled relevance of effects exerted by single factors controlling P leaching is unclear. Very large observational datasets of soil and groundwater P content are furthermore required to reveal indirect controls of soil traits through mediating soil variables. We explored co-variation of phreatic groundwater orthophosphate (o-P) concentration and soil factors in sandy soils in Flanders, Belgium. Correlation analyses were complemented with an exploratory model derived using 'path analysis'. Data of oxalate-extractable Al, Fe, P and pH KCl , phosphate sorption capacity (PSC) and PSD in three depth layers (0-30, 30-60, 60-90 cm), topsoil SOC, % clay and groundwater depth (fluctuation) were interpolated to predict soil properties on exact locations of a very extensive net of groundwater monitoring wells. The mean PSD was only poorly correlated to groundwater o-P concentration, indicating the overriding control of other factors in the transport of P to the groundwater. A significant (P soil pH and groundwater table depth than by PSD indicates the likely oversimplification of the latter index to measure the long-term potential risk of P leaching. Accounting for controls on leaching not included in PSD via an alternative index, however, seems problematic as in Flanders for example groundwater o-P turned out to be higher in finer textured soils or soils with higher pedogenic Fe content, probably because of their lower pedogenic Al content and higher soil pH. Path analysis of extensive soil and groundwater datasets seems a viable way to identify prime local determinants of soil P leaching and could be further on used for 'ground-truthing' more complex P-migration simulation

  4. Differences in nitrogen cycling and soil mineralisation between a eucalypt plantation and a mixed eucalypt and #Acacia mangium# plantation on a sandy tropical soil

    OpenAIRE

    Tchichelle, Sogni Viviane; Epron, Daniel; Mialoundama, Fidèle; Koutika, Lydie-Stella; Harmand, Jean-Michel; Bouillet, Jean-Pierre; Mareschal, Louis

    2017-01-01

    Sustainable wood production requires appropriate management of commercial forest plantations. Establishment of industrial eucalypt plantations on poor sandy soils leads to a high loss of nutrients including nitrogen (N) after wood harvesting. An ecological intensification of eucalypt plantations was tested with the replacement of half of the Eucalyptus urophylla × E. grandis by Acacia mangium in the eucalypt monoculture to sustain soil fertility through enhancement of the N biological cycle. ...

  5. Hydrological Components of a Young Loblolly Pine Plantation on a Sandy Soil with Estimates of Water Use and Loss

    Science.gov (United States)

    Deborah A. Abrahamson; Phillip M. Dougherty; Stanley J. Zarnoch

    1998-01-01

    Fertilizer and irrigation treatments were applied in a 7- to l0-year-old loblolly pine (Pinus taeda L.) plantation on a sandy soil near Laurinburg, North Carolina. Rainfall, throughfall, stemflow, and soil water content were measured throughout the study period. Monthly interception losses ranged from 4 to 15% of rainfall. Stemflow ranged from 0.2...

  6. Bioremediation of endosulfan contaminated soil and water-Optimization of operating conditions in laboratory scale reactors

    International Nuclear Information System (INIS)

    Kumar, Mathava; Philip, Ligy

    2006-01-01

    A mixed bacterial culture consisted of Staphylococcus sp., Bacillus circulans-I and -II has been enriched from contaminated soil collected from the vicinity of an endosulfan processing industry. The degradation of endosulfan by mixed bacterial culture was studied in aerobic and facultative anaerobic conditions via batch experiments with an initial endosulfan concentration of 50 mg/L. After 3 weeks of incubation, mixed bacterial culture was able to degrade 71.58 ± 0.2% and 75.88 ± 0.2% of endosulfan in aerobic and facultative anaerobic conditions, respectively. The addition of external carbon (dextrose) increased the endosulfan degradation in both the conditions. The optimal dextrose concentration and inoculum size was estimated as 1 g/L and 75 mg/L, respectively. The pH of the system has significant effect on endosulfan degradation. The degradation of alpha endosulfan was more compared to beta endosulfan in all the experiments. Endosulfan biodegradation in soil was evaluated by miniature and bench scale soil reactors. The soils used for the biodegradation experiments were identified as clayey soil (CL, lean clay with sand), red soil (GM, silty gravel with sand), sandy soil (SM, silty sand with gravel) and composted soil (PT, peat) as per ASTM (American society for testing and materials) standards. Endosulfan degradation efficiency in miniature soil reactors were in the order of sandy soil followed by red soil, composted soil and clayey soil in both aerobic and anaerobic conditions. In bench scale soil reactors, endosulfan degradation was observed more in the bottom layers. After 4 weeks, maximum endosulfan degradation efficiency of 95.48 ± 0.17% was observed in red soil reactor where as in composted soil-I (moisture 38 ± 1%) and composted soil-II (moisture 45 ± 1%) it was 96.03 ± 0.23% and 94.84 ± 0.19%, respectively. The high moisture content in compost soil reactor-II increased the endosulfan concentration in the leachate. Known intermediate metabolites of

  7. Global Assessment of Human-induced Soil Degradation (GLASOD)

    NARCIS (Netherlands)

    Oldeman, L.R.; Hakkeling, R.T.A.; Sombroek, W.G.; Batjes, N.H.

    2014-01-01

    The GLASOD project (1987-1990) has produced a world map of human-induced soil degradation. Data were complied in cooperation with a large number of soil scientists throughout the world, using uniform Guidelines and international correlation. The status of soil degradation was mapped within loosely

  8. Spatial variation in the degradation rate of the pesticides isoproturon, azoxystrobin and diflufenican in soil and its relationship with chemical and microbial properties.

    Science.gov (United States)

    Bending, Gary D; Lincoln, Suzanne D; Edmondson, Rodney N

    2006-01-01

    The extent of within field variability in the degradation rate of the pesticides isoproturon, azoxystrobin and diflufenican, and the role of intrinsic soil factors and technical errors in contributing to the variability, was investigated in sites on sandy-loam and clay-loam. At each site, 40 topsoil samples were taken from a 160 x 60 m area, and pesticides applied in the laboratory. Time to 25% dissipation (DT25) ranged between 13 and 61 weeks for diflufenican, 5.6 and 17.2 weeks for azoxystrobin, and 0.3 and 12.5 weeks for isoproturon. Variability in DT25 was higher in the sandy-loam in which there was also greatest variability in soil chemical and microbial properties. Technical error associated with pesticide extraction, analysis and lack of model fit during derivation of DT25 accounted for between 5.3 and 25.8% of the variability for isoproturon and azoxystrobin, but could account for almost all the variability for diflufenican. Azoxystrobin DT25, sorption and pH were significantly correlated.

  9. Transport Modeling of Modified Magnetite Nanoparticles with Sodium Dodecyl Sulfate in a Saturated Sandy Soil

    Directory of Open Access Journals (Sweden)

    Ahmad Farrokhian Firouzi

    2017-02-01

    . The response curve was followed by analyzing the concentration history of Cl-1 in the effluent. Then, the influent was switched back to the background solution to thoroughly elute the tracer. Following the tracer test, a modified magnetite nanoparticles with sodium dodecyl sulfate was introduced into the column and the nanoparticle breakthrough curves were obtained by measuring the concentration history of total Fe in the effluent. Total iron concentration was analyzed with a flame atomic-absorption spectrophotometer. One site and two site kinetic attachment-detachment models in HYDRUS-1D software were used to predict the nanoparticles transport. Also parameters of model efficiency coefficient (E, root mean square error (RMSE, geometric mean error ratio (GMER, and geometric standard deviation of error ratio (GSDER were used to determine the accuracy of the models. Results and Discussion: SEM measurements demonstrated that the particle size of nanoparticles was about 40-60 nm. The hydrodynamic dispersion coefficient (D for each medium was obtained by fitting the classic 1-D convection–dispersion equation (CDE to the experimental breakthrough data using the CXTFIT code (STANMOD software, USDA. The relative concentration of nanoparticles in comparison with chloride in the collected effluent from soil columns were much lower indicating a strong retention of nanoparticles in studied porous media, thereby attachment, deposition and possibly straining of nanoparticles. Modeling results showed that in all sites of both models (one site and two-site kinetic attachment-detachment models, attachment was rapid and detachment was slow. These attachment kinetic sites may be because of consistent charges of minerals with attachment. Therefore, considering to same attachment-detachment behavior in two sites of two-site kinetic model, it is concluded that the one site kinetic model had eligible estimation of nanoparticles breakthrough curve in the studied sandy soil columns lonely

  10. Degradation of tetraethyllead during the degradation of leaded gasoline hydrocarbons in soil

    International Nuclear Information System (INIS)

    Mulroy, P.T.; Ou, L.T.

    1998-01-01

    For over 50 years, leaded gasoline was the only fuel for automobiles, and tetraethyllead (TEL) was the major octane number enhancer used in leaded gasoline. Ample information is available on the fate and remediation of gasoline hydrocarbons in contaminated subsoils and groundwater. However, little is known regarding the fate of TEL in leaded gasoline-contaminated subsoils and groundwater. In soil not contaminated with gasoline, TEL was rapidly degraded and completely disappeared in 14 d. In gasoline-contaminated soil, TEL degradation was slower; after 77 d, 4 to 17% of the applied TEL still remained in the contaminated soil. Disappearance of total petroleum hydrocarbons (TPH) was initially rapid but slowed appreciably after 7 to 14 d. As a result, after 77 d, 33 to 51% of the applied gasoline still remained in soil. The retardation of TEL degradation in leaded gasoline-contaminated soil is due to the presence of gasoline hydrocarbons. As long as gasoline hydrocarbons remain in soil, TEL may also remain in soil, most likely in the gasoline hydrocarbon phase

  11. Degradation and toxicity of phenyltin compounds in soil

    International Nuclear Information System (INIS)

    Paton, G.I.; Cheewasedtham, W.; Marr, I.L.; Dawson, J.J.C.

    2006-01-01

    Although the fate of organotins has been widely studied in the marine environment, fewer studies have considered their impact in terrestrial systems. The degradation and toxicity of triphenyltin in autoclaved, autoclaved-reinoculated and non-sterilised soil was studied in a 231 day incubation experiment following a single application. Degradation and toxicity of phenyltin compounds in soil was monitored using both chemical and microbial (lux-based bacterial biosensors) methods. Degradation was significantly slower in the sterile soil when compared to non-sterilised soils. In the non-sterilised treatment, the half-life of triphenyltin was 27 and 33 days at amendments of 10 and 20 mg Sn kg -1 , respectively. As initial triphenyltin degradation occurred, there was a commensurate increase in toxicity, reflecting the fact that metabolites produced may be both more bioavailable and toxic to the target receptor. Over time, the toxicity reduced as degradation proceeded. The toxicity impact on non-target receptors for these compounds may be significant. - Triphenyltin degradative metabolites cause toxic responses to biosensors

  12. [Community structure and diversity of soil arthropods in naturally restored sandy grasslands after grazing].

    Science.gov (United States)

    Liu, Ren-tao; Zhao, Ha-lin; Zhao, Xue-yong

    2010-11-01

    Taking the Naiman Desertification Research Station under Chinese Academy of Sciences as a base, an investigation was conducted on the community structure of soil arthropods in the naturally restored sandy grasslands after different intensity grazing disturbance, with the effects of vegetation and soil on this community structure approached. In the non-grazing grassland, soil arthropods were rich in species and more in individuals, and had the highest diversity. In the restored grassland after light grazing, soil arthropods had the lowest evenness and diversity. In the restored grassland after moderate grazing, the individuals of soil arthropods were lesser but the major groups were more, and the evenness and diversity were higher. In the restored grassland after heavy grazing, the individuals of soil arthropods were more but the major groups were lesser, and the diversity was higher. Plant individuals' number, vegetation height and coverage, and soil alkalinity were the main factors affecting the soil arthropod community in naturally restored grasslands after different intensity grazing disturbance. It was implied that after 12-year exclosure of grassland, soil arthropod community could be recovered to some degree, while grazing disturbance had long-term negative effects on the arthropod community.

  13. Volatilization of tri-allate, ethoprophos and parathion measured with four methods after spraying on a sandy soil

    NARCIS (Netherlands)

    Bor, G.; Berg, van den F.; Smelt, J.H.; Smidt, R.A.; Peppel-Groen, van de A.E.; Leistra, M.

    1995-01-01

    At about eleven times after application of tri-allate, ethoprophos and parathion to a sandy soil, their rates of volatilization were determined by the aerodynamic method (AD), the Bowen-ratio method (BR), the theoretical-profile method (TP) and the Box method. The volatilization was highest for

  14. Toxicity of iron oxide nanoparticles to grass litter decomposition in a sandy soil

    Science.gov (United States)

    Rashid, Muhammad Imtiaz; Shahzad, Tanvir; Shahid, Muhammad; Imran, Muhammad; Dhavamani, Jeyakumar; Ismail, Iqbal M. I.; Basahi, Jalal M.; Almeelbi, Talal

    2017-02-01

    We examined time-dependent effect of iron oxide nanoparticles (IONPs) at a rate of 2000 mg kg-1 soil on Cynodon dactylon litter (3 g kg-1) decomposition in an arid sandy soil. Overall, heterotrophic cultivable bacterial and fungal colonies, and microbial biomass carbon were significantly decreased in litter-amended soil by the application of nanoparticles after 90 and 180 days of incubation. Time dependent effect of nanoparticles was significant for microbial biomass in litter-amended soil where nanoparticles decreased this variable from 27% after 90 days to 49% after 180 days. IONPs decreased CO2 emission by 28 and 30% from litter-amended soil after 90 and 180 days, respectively. These observations indicated that time-dependent effect was not significant on grass-litter carbon mineralization efficiency. Alternatively, nanoparticles application significantly reduced mineral nitrogen content in litter-amended soil in both time intervals. Therefore, nitrogen mineralization efficiency was decreased to 60% after 180 days compared to that after 90 days in nanoparticles grass-litter amended soil. These effects can be explained by the presence of labile Fe in microbial biomass after 180 days in nanoparticles amendment. Hence, our results suggest that toxicity of IONPs to soil functioning should consider before recommending their use in agro-ecosystems.

  15. Decomposition of 14C - malathion in three Brazilian soil samples

    International Nuclear Information System (INIS)

    Helene, C.G.; Ruegg, E.F.

    1982-01-01

    The degradation of 14 C-malathion in soil was examined using gas chromatography and radiotracer techniques. About half of the malathion added was degraded within a day in soil from three regions of Brazil. Almost all the radiolabelled material extracted from the Red Latosol (Londrina, PR) was malathion, but metabolites were extracted from the 'Sandy' cerrado soil (Planaltina, DF) and Dark-Red Latosol (Passo Fundo, RS). The proportion of metabolites in the extracts increased until most of the malathion was degraded, after four days. Radiocarbon dioxide was liberated from all three soils at similar rates. When about half of the label had been recovered as carbon dioxide after eight weeks, the rate of evolution diminished. (Author) [pt

  16. Phosphorus fractions in sandy soils of vineyards in southern Brazil

    Directory of Open Access Journals (Sweden)

    Djalma Eugênio Schmitt

    2013-04-01

    Full Text Available Phosphorus (P applications to vineyards can cause P accumulation in the soil and maximize pollution risks. This study was carried out to quantify the accumulation of P fractions in sandy soils of vineyards in southern Brazil. Soil samples (layers 0-5, 6-10 and 11-20 cm were collected from a native grassland area and two vineyards, after 14 years (vineyard 1 and 30 years (vineyard 2 of cultivation, in Santana do Livramento, southern Brazil, and subjected to chemical fractionation of P. Phosphorus application, especially to the 30-year-old vineyard 2, increased the inorganic P content down to a depth of 20 cm, mainly in the labile fractions extracted by anion-exchange resin and NaHCO3, in the moderately labile fraction extracted by 0.1 and 0.5 mol L-1 NaOH, and in the non-labile fraction extracted by 1 mol L-1 HCl, indicating the possibility of water eutrophication. Phosphorus application and grapevine cultivation time increased the P content in the organic fraction extracted by NaHCO3 from the 0-5 cm layer, and especially in the moderately labile fraction extracted by 0.1 mol L-1 NaOH, down to a depth of 20 cm.

  17. Sorption, degradation and mobility of ptaquiloside, a carcinogenic Bracken (Pteridium sp.) constituent, in the soil environment

    DEFF Research Database (Denmark)

    Rasmussen, Lars Holm; Lauren, Denis; Hansen, Hans Christian Bruun

    2005-01-01

    Ptaquiloside (PTA) is a carcinogenic norsesquiterpene glucoside produced by Bracken in amounts up to at least 13 500 mg m2. The toxin is transferred from Bracken to the underlying soil from where it may leach to surface and groundwaters impairing the quality of drinking water. The objectives of t...... where PTA and a non-sorbing tracer showed almost coincident break-through. Leaching of PTA to the aqueous environment will be most extensive on sandy soils, having pH >4 and poor in organic matter which are exposed to high precipitation rates during cold seasons.......Ptaquiloside (PTA) is a carcinogenic norsesquiterpene glucoside produced by Bracken in amounts up to at least 13 500 mg m2. The toxin is transferred from Bracken to the underlying soil from where it may leach to surface and groundwaters impairing the quality of drinking water. The objectives...... of the present study were to characterize the solubility, degradation and retention of PTA in soils in order to evaluate the risk for groundwater contamination. PTA was isolated from Bracken. The logarithmic octanol–water and ethyl acetate–water partitioning coefficients for PTA were 0.63 and 0.88, respectively...

  18. Soil Degradation in India: Challenges and Potential Solutions

    Directory of Open Access Journals (Sweden)

    Ranjan Bhattacharyya

    2015-03-01

    Full Text Available Soil degradation in India is estimated to be occurring on 147 million hectares (Mha of land, including 94 Mha from water erosion, 16 Mha from acidification, 14 Mha from flooding, 9 Mha from wind erosion, 6 Mha from salinity, and 7 Mha from a combination of factors. This is extremely serious because India supports 18% of the world’s human population and 15% of the world’s livestock population, but has only 2.4% of the world’s land area. Despite its low proportional land area, India ranks second worldwide in farm output. Agriculture, forestry, and fisheries account for 17% of the gross domestic product and employs about 50% of the total workforce of the country. Causes of soil degradation are both natural and human-induced. Natural causes include earthquakes, tsunamis, droughts, avalanches, landslides, volcanic eruptions, floods, tornadoes, and wildfires. Human-induced soil degradation results from land clearing and deforestation, inappropriate agricultural practices, improper management of industrial effluents and wastes, over-grazing, careless management of forests, surface mining, urban sprawl, and commercial/industrial development. Inappropriate agricultural practices include excessive tillage and use of heavy machinery, excessive and unbalanced use of inorganic fertilizers, poor irrigation and water management techniques, pesticide overuse, inadequate crop residue and/or organic carbon inputs, and poor crop cycle planning. Some underlying social causes of soil degradation in India are land shortage, decline in per capita land availability, economic pressure on land, land tenancy, poverty, and population increase. In this review of land degradation in India, we summarize (1 the main causes of soil degradation in different agro-climatic regions; (2 research results documenting both soil degradation and soil health improvement in various agricultural systems; and (3 potential solutions to improve soil health in different regions using a

  19. Effect of Simulated Weathering and Aging of TNT in Amended Sandy Loam Soil on Toxicity to the Enchytraeid Worm, Enchytreaeus Crypticus

    Science.gov (United States)

    2006-05-01

    high bioavailability of organic compounds. However, amended SSL soil was analyzed for presence of metabolic transformation products from nitroaromatic...Phillips, C.; Checkai, R. 1999. Comparison of malathion toxicity using enchytraeid reproduction test and earthworm toxicity test in different soil ...OF TNT IN AMENDED SANDY LOAM SOIL ON TOXICITY TO THE ENCHYTRAEID WORM, ENCHYTRAEUS CRYPTICUS Roman G. Kuperman Ronald T. Checkai Michael Simini

  20. Nanoscale zerovalent iron-mediated degradation of DDT in soil.

    Science.gov (United States)

    Han, Yuling; Shi, Nan; Wang, Huifang; Pan, Xiong; Fang, Hua; Yu, Yunlong

    2016-04-01

    Nanoscale zerovalent iron (nZVI)-mediated degradation of 1,1,1-trichloro-2,2-bis(p-chlorophenyl)ethane (DDT) was investigated in a spiked soil under different conditions (iron sources, iron dosage, soil moisture, temperature, and soil types) and DDT-contaminated field. The degradation efficiency of p,p'-DDT by nZVI and nZVI coated with sodium oleate (SO-nZVI) was much higher than that by nZVI coated with polyimide (PI-nZVI). The rapid degradation of p,p'-DDT by nZVI only occurred in flooded soil. The degradation half-life of p,p'-DDT decreased significantly from 58.3 to 27.6 h with nZVI dosage from 0.5 to 2.0% and from 46.5 to 32.0 h with temperature from 15 to 35 °C. The degradation efficiency of p,p'-DDT by nZVI differed in Jinhua (JH), Jiaxing (JX), Xiaoshan (XS), Huajiachi (HJC), and Heilongjiang (HLJ) soils. A good correlation was found between the degradation half-life of p,p'-DDT and multiple soil properties. The probable nZVI-mediated degradation pathway of p,p'-DDT in soil was proposed as DDT → DDD/DDE → DDNS → DDOH based on the metabolites identified by GC-MS. The in situ degradation efficiency of residual DDTs in a contaminated field was profoundly enhanced by the addition of nZVI as compared to the control. It is concluded that nZVI might be an efficient agent for the remediation of DDT-contaminated soil under anaerobic environment.

  1. Effect of biosurfactant[0] on the sorption of phenanthrene onto original and H2O2-treated soils

    Institute of Scientific and Technical Information of China (English)

    PEI Xiaohong; ZHAN Xinhua; ZHOU Lixiang

    2009-01-01

    The objective of this study was to examine the effect of biosurfactant on sorption of phenanthrene (PHE) onto the original or H2O2-treated black loamy soil (typic isohumisols) and red sandy soil (typic ferralisols). The sorption isotherms were performed with the original and "soft" carbon-removed soils in the presence and absence of biosurfactant (200 mg/L). The sorption and degradation of biosurfactant were investigated. The result showed that organic matter played an important role in PHE sorption onto the black loamy and red sandy soils, and the PHE sorption isotherms on the "soft" carbon-removed soils exhibited more nonlinearity than those on the original soils. The values of partition coefficient (Kd) on the original black loamy soil with or without 200 mg/L biosurfactant were 181.6 and 494.5 mL/g, respectively. Correspondingly, in the red sandy soil, Kd was 246.4 and 212.8 mL/g in the presence or absence of biosurfactant, respectively. The changes of Kd suggested that biosurfactant inhibited PHE sorption onto the black loamy soil, but facilitated PHE sorption onto the red sandy soil. The nonlinearity of PHE sorption isotherm was decreased in the presence of biosurfactant. Site specific sorption might occur during PHE sorption onto both the original and the "soft" carbon-removed soils in the presence of biosurfactant. It was noted that biosurfactant could also be sorbed onto soils. The maximal sorption capacity of the red sandy soil for biosurfactant was (76.9 ± 0.007) μg/g, which was 1.31 times that of black loamy soil. Biosurfactant was degraded quickly in the two selected soils, and 92% of biosurfactant were mineralized throughout the incubation experiment for 7 d. It implied that biosurfactant should be added frequently when the remediation of polycyclic aromatic hydrocarbon (PAH)-contaminated soils was conducted through PAH desorption approach facilitated by biosurfactant.

  2. Fate of diuron and terbuthylazine in soils amended with two-phase olive oil mill waste.

    Science.gov (United States)

    Cabrera, A; Cox, Lucia; Velarde, P; Koskinen, William C; Cornejo, Juan

    2007-06-13

    The addition of organic amendments to soil increases soil organic matter content and stimulates soil microbial activity. Thus, processes affecting herbicide fate in the soil should be affected. The objective of this work was to investigate the effect of olive oil production industry organic waste (alperujo) on soil sorption-desorption, degradation, and leaching of diuron [3-(3,4-dichlorophenyl)-1,1-dimethylurea] and terbuthylazine [N2-tert-butyl-6-chloro-N4-ethyl-1,3,5-triazine-2,4-diamine], two herbicides widely used in olive crops. The soils used in this study were a sandy soil and a silty clay soil from two different olive groves. The sandy soil was amended in the laboratory with fresh (uncomposted) alperujo at the rate of 10% w/w, and the silty clay soil was amended in the field with fresh alperujo at the rate of 256 kg per tree during 4 years and in the laboratory with fresh or composted alperujo. Sorption of both herbicides increased in laboratory-amended soils as compared to unamended or field-amended soils, and this process was less reversible in laboratory-amended soils, except for diuron in amended sandy soil. Addition of alperujo to soils increased half-lives of the herbicides in most of the soils. Diuron and terbuthylazine leached through unamended sandy soil, but no herbicide was detected in laboratory-amended soil. Diuron did not leach through amended or unamended silty clay soil, whereas small amounts of terbuthylazine were detected in leachates from unamended soil. Despite their higher sorption capacity, greater amounts of terbuthylazine were found in the leachates from amended silty clay soils. The amounts of dissolved organic matter from alperujo and the degree of humification can affect sorption, degradation, and leaching of these two classes of herbicides in soils. It appears that adding alperujo to soil would not have adverse impacts on the behavior of herbicides in olive production.

  3. Crop uptake and leaching losses of 15N labelled fertilizer nitrogen in relation to waterlogging of clay and sandy loam soils

    International Nuclear Information System (INIS)

    Webster, C.P.; Belford, R.K.; Cannell, R.Q.

    1986-01-01

    Ammonium nitrate fertilizer, labelled with 15 N, was applied in spring to winter wheat growing in undisturbed monoliths of clay and sandy loam soil in lysimeters; the rates of application were respectively 95 and 102 kg N ha -1 in the spring of 1976 and 1975. Crops of winter wheat, oilseed rape, peas and barley grown in the following 5 or 6 years were treated with unlabelled nitrogen fertilizer at rates recommended for maximum yields. During each year of the experiments the lysimeters were divided into treatments which were either freely drained or subjected to periods of waterlogging. Another labelled nitrogen application was made in 1980 to a separate group of lysimeters with a clay soil and a winter wheat crop to study further the uptake of nitrogen fertilizer in relation to waterlogging. In the first growing season, shoots of the winter wheater at harvest contained 46 and 58% of the fertilizer nitrogen applied to the clay and sandy loam soils respectively. In the following year the crops contained a further 1-2% of the labelled fertilizer, and after 5 and 6 years the total recoveries of labelled fertilizer in the crops were 49 and 62% on the clay and sandy loam soils respectively. In the first winter after the labelled fertilizer was applied, less than 1% of the fertilizer was lost in the drainage water, and only about 2% of the total nitrogen (mainly nitrate) in the drainage water from both soils was derived from the fertilizer

  4. Soil Degradation Processes; Procesos de Degradacion del Suelo

    Energy Technology Data Exchange (ETDEWEB)

    Nunez Crespi, S; Perez Martinez, M; Cuesta Santianes, M J; Cabrera Jimenez, J A

    2007-12-28

    In the European communication entitled Towards a Thematic Strategy for Soil Protection, eight main threats to soil were identified: contamination, erosion, loss of organic matter, compaction, salinization; hydro-geological risks, soil sealing, and decline in biodiversity. The main purpose of this report is to provide the current state of knowledge of the soil degradation processes both, in the European Community scale and, particularly, in the Spanish territory. Furthermore, the main research project information related to soil degradation processes is also included, identifying the main actors involved in soil scientific research and development. (Author) 66 refs.

  5. Uncertainty of Deardorff’s soil moisture model based on continuous TDR measurements for sandy loam soil

    Directory of Open Access Journals (Sweden)

    Brandyk Andrzej

    2016-03-01

    Full Text Available Knowledge on soil moisture is indispensable for a range of hydrological models, since it exerts a considerable influence on runoff conditions. Proper tools are nowadays applied in order to gain in-sight into soil moisture status, especially of uppermost soil layers, which are prone to weather changes and land use practices. In order to establish relationships between meteorological conditions and topsoil moisture, a simple model would be required, characterized by low computational effort, simple structure and low number of identified and calibrated parameters. We demonstrated, that existing model for shallow soils, considering mass exchange between two layers (the upper and the lower, as well as with the atmosphere and subsoil, worked well for sandy loam with deep ground water table in Warsaw conurbation. GLUE (Generalized Likelihood Uncertainty Estimation linked with GSA (Global Sensitivity Analysis provided for final determination of parameter values and model confidence ranges. Including the uncertainty in a model structure, caused that the median soil moisture solution of the GLUE was shifted from the one optimal in deterministic sense. From the point of view of practical model application, the main shortcoming were the underestimated water exchange rates between the lower soil layer (ranging from the depth of 0.1 to 0.2 m below ground level and subsoil. General model quality was found to be satisfactory and promising for its utilization for establishing measures to regain retention in urbanized conditions.

  6. Soil physical land degradation processes

    Science.gov (United States)

    Horn, Rainer

    2017-04-01

    According to the European Soil Framework Directive (2006) soil compaction is besides water and wind erosion one of the main physical reasons and threats of soil degradation. It is estimated, that 32% of the subsoils in Europe are highly degraded and 18% moderately vulnerable to compaction. The problem is not limited to crop land or forest areas (especially because of non-site adjusted harvesting machines) but is also prevalent in rangelands and grassland, and even in so called natural non-disturbed systems. The main reasons for an intense increase in compacted agricultural or forested regions are the still increasing masses of the machines as well the increased frequency of wheeling under non favorable site conditions. Shear and vibration induced soil deformation enhances the deterioration of soil properties especially if the soil water content is very high and the internal soil strength very low. The same is true for animal trampling in combination with overgrazing of moist to wet pastures which subsequently causes a denser (i.e. reduced proportion of coarse pores with smaller continuity) but still structured soil horizons and will finally end in a compacted platy structure. In combination with high water content and shearing due to trampling therefore results in a complete muddy homogeneous soil with no structure at all. (Krümmelbein et al. 2013) Site managements of arable, forestry or horticulture soils requires a sufficiently rigid pore system which guarantees water, gas and heat exchange, nutrient transport and adsorption as well as an optimal rootability in order to avoid subsoil compaction. Such pore system also guarantees a sufficient microbial activity and composition in order to also decompose the plant etc. debris. It is therefore essential that well structured horizons dominate in soils with at best subangular blocky structure or in the top A- horizons a crumbly structure due to biological activity. In contrast defines the formation of a platy

  7. Cyanobacteria Inoculation Improves Soil Stability and Fertility on Different Textured Soils: Gaining Insights for Applicability in Soil Restoration

    Directory of Open Access Journals (Sweden)

    Sonia Chamizo

    2018-06-01

    Full Text Available Cyanobacteria are ubiquitous components of biocrust communities and the first colonizers of terrestrial ecosystems. They play multiple roles in the soil by fixing C and N and synthesizing exopolysaccharides, which increase soil fertility and water retention and improve soil structure and stability. Application of cyanobacteria as inoculants to promote biocrust development has been proposed as a novel biotechnological technique for restoring barren degraded areas and combating desertification processes in arid lands. However, previous to their widespread application under field conditions, research is needed to ensure the selection of the most suitable species. In this study, we inoculated two cyanobacterial species, Phormidium ambiguum (non N-fixing and Scytonema javanicum (N-fixing, on different textured soils (from silt loam to sandy, and analyzed cyanobacteria biocrust development and evolution of physicochemical soil properties for 3 months under laboratory conditions. Cyanobacteria inoculation led to biocrust formation in all soil types. Scanning electron microscope (SEM images showed contrasting structure of the biocrust induced by the two cyanobacteria. The one from P. ambiguum was characterized by thin filaments that enveloped soil particles and created a dense, entangled network, while the one from S. javanicum consisted of thicker filaments that grouped as bunches in between soil particles. Biocrust development, assessed by chlorophyll a content and crust spectral properties, was higher in S. javanicum-inoculated soils compared to P. ambiguum-inoculated soils. Either cyanobacteria inoculation did not increase soil hydrophobicity. S. javanicum promoted a higher increase in total organic C and total N content, while P. ambiguum was more effective in increasing total exopolysaccharide (EPS content and soil penetration resistance. The effects of cyanobacteria inoculation also differed among soil types and the highest improvement in soil

  8. Biocide Runoff from Building Facades: Degradation Kinetics in Soil.

    Science.gov (United States)

    Bollmann, Ulla E; Fernández-Calviño, David; Brandt, Kristian K; Storgaard, Morten S; Sanderson, Hans; Bester, Kai

    2017-04-04

    Biocides are common additives in building materials. In-can and film preservatives in polymer-resin render and paint, as well as wood preservatives are used to protect facade materials from microbial spoilage. Biocides leach from the facade material with driving rain, leading to highly polluted runoff water (up to several mg L -1 biocides) being infiltrated into the soil surrounding houses. In the present study the degradation rates in soil of 11 biocides used for the protection of building materials were determined in laboratory microcosms. The results show that some biocides are degraded rapidly in soil (e.g., isothiazolinones: T 1/2 soils; thus, rainfall events control how often new input to the soil occurs. Time intervals between rainfall events in Northern Europe are shorter than degradation half-lives even for many rapidly degraded biocides. Consequently, residues of some biocides are likely to be continuously present due to repeated input and most biocides can be considered as "pseudo-persistent"-contaminants in this context. This was verified by (sub)urban soil screening, where concentrations of up to 0.1 μg g -1 were detected for parent compounds as well as terbutryn degradation products in soils below biocide treated facades.

  9. Effects of sodium polyacrylate on water retention and infiltration capacity of a sandy soil

    OpenAIRE

    Zhuang, Wenhua; Li, Longguo; Liu, Chao

    2013-01-01

    Based on the laboratory study, the effects of sodium polyacrylate (SP) was investigated at 5 rates of 0, 0.08, 0.2, 0.5, and 1%, on water retention, saturated hydraulic conductivity(Ks), infiltration characteristic and water distribution profiles of a sandy soil. The results showed that water retention and available water capacity effectively increased with increasing SP rate. The Ks and the rate of wetting front advance and infiltration under certain pond infiltration was significantly reduc...

  10. Effect of biochar on aerobic processes, enzyme activity, and crop yields in two sandy loam soils

    DEFF Research Database (Denmark)

    Sun, Zhencai; Bruun, Esben; Arthur, Emmanuel

    2014-01-01

    Biochar added to agricultural soils may sequester carbon and improve physico-chemical conditions for crop growth, due to effects such as increased water and nutrient retention in the root zone. The effects of biochar on soil microbiological properties are less certain. We addressed the effects...... of wood-based biochar on soil respiration, water contents, potential ammonia oxidation (PAO), arylsulfatase activity (ASA), and crop yields at two temperate sandy loam soils under realistic field conditions. In situ soil respiration, PAO, and ASA were not significantly different in quadruplicate field...... plots with or without biochar (20 Mg ha−1); however, in the same plots, volumetric water contents increased by 7.5 % due to biochar (P = 0.007). Crop yields (oat) were not significantly different in the first year after biochar application, but in the second year, total yields of spring barley increased...

  11. Geophysical Monitoring of Hydrocarbon-Contaminated Soils Remediated with a Bioelectrochemical System.

    Science.gov (United States)

    Mao, Deqiang; Lu, Lu; Revil, André; Zuo, Yi; Hinton, John; Ren, Zhiyong Jason

    2016-08-02

    Efficient noninvasive techniques are desired for monitoring the remediation process of contaminated soils. We applied the direct current resistivity technique to image conductivity changes in sandbox experiments where two sandy and clayey soils were initially contaminated with diesel hydrocarbon. The experiments were conducted over a 230 day period. The removal of hydrocarbon was enhanced by a bioelectrochemical system (BES) and the electrical potentials of the BES reactors were also monitored during the course of the experiment. We found that the variation in electrical conductivity shown in the tomograms correlate well with diesel removal from the sandy soil, but this is not the case with the clayey soil. The clayey soil is characterized by a larger specific surface area and therefore a larger surface conductivity. In sandy soil, the removal of the diesel and products from degradation leads to an increase in electrical conductivity during the first 69 days. This is expected since diesel is electrically insulating. For both soils, the activity of BES reactors is moderately imaged by the inverted conductivity tomogram of the reactor. An increase in current production by electrochemically active bacteria activity corresponds to an increase in conductivity of the reactor.

  12. Utilization of Sandy Soil as the Primary Raw Material in Production of Unfired Bricks

    Directory of Open Access Journals (Sweden)

    Guilan Tao

    2018-01-01

    Full Text Available In this study, attempts were made to use sandy soil as the main raw material in making unfired bricks. The sprayed-cured brick specimens were tested for compressive and flexural strength, rate of water absorption, percentage of voids, bulk density, freezing/thawing, and water immersion resistance. In addition, the microstructures of the specimens were also studied using scanning electron microscope (SEM and X-ray diffraction (XRD technique. The test results show that unfired brick specimens with the addition of ground-granulated blast-furnace slag (GGBS tend to achieve better mechanical properties when compared with the specimens that added cement alone, with GGBS correcting particle size distribution and contributing to the pozzolanic reactions and the pore-filling effects. The test specimens with the appropriate addition of cement, GGBS, quicklime, and gypsum are dense and show a low water absorption rate, a low percentage of voids, and an excellent freezing/thawing and water immersion resistance. The SEM observation and XRD analysis verify the formation of hydrate products C–S–H and ettringite, providing a better explanation of the mechanical and physical behavior and durability of the derived unfired bricks. The results obtained suggest that there is a technical approach for the high-efficient comprehensive utilization of sandy soil and provide increased economic and environmental benefits.

  13. Degradation of dimethyl disulphide in soil with or without biochar amendment.

    Science.gov (United States)

    Han, Dawei; Yan, Dongdong; Cao, Aocheng; Fang, Wensheng; Liu, Pengfei; Li, Yuan; Ouyang, Canbin; Wang, Qiuxia

    2017-09-01

    Dimethyl disulphide (DMDS) is a new and effective alternative to methyl bromide for soil fumigation. The effect of biochar on the fate of DMDS in soil is not fully understood. The objective of this study was to determine the degradation kinetics of DMDS in different soils and evaluate the effect of biochar amendment on DMDS degradation using incubation experiments. The degradation half-life of DMDS was between 1.05 and 6.66 days under non-sterile conditions, and 12.63 to 22.67 days under sterile conditions in five types of soil. Seven out of the eight tested biochar amendments (BC-2 to BC-8) delayed the degradation of DMDS in soil, increasing the half-life of DMDS in Fangshan soil from 1.05 to 1.16-5.87 days following amendment with 1% (w/w) biochar. The degradation rate of DMDS in Fangshan soil accelerated as the amendment rate of BC-1 increased, and decreased as the amendment rate of BC-7 increased. Biodegradation is an important degradation route for DMDS in soil, and DMDS degraded faster in alkaline soil. The effects of biochar amendments on DMDS degradation in soil are determined by complex multiple factors (such as surface area, pH and physicochemical composition), rather than by any single property of biochar. © 2017 Society of Chemical Industry. © 2017 Society of Chemical Industry.

  14. Tomato nitrogen accumulation and fertilizer use efficiency on a sandy soil, as affected by nitrogen rate and irrigation scheduling

    NARCIS (Netherlands)

    Zotarelli, L.; Dukes, M.D.; Scholberg, J.M.S.; Munoz-Carpena, R.; Icerman, J.

    2009-01-01

    Tomato production systems in Florida are typically intensively managed with high inputs of fertilizer and irrigation and on sandy soils with low inherent water and nutrient retention capacities; potential nutrient leaching losses undermine the sustainability of such systems. The objectives of this

  15. ELASTOPLASTICIDAD DE UN SUELO FRANCO ARENOSO DE SABANA I SANDY LOAM SAVANNA SOIL ELASTOPLASTICITY

    Directory of Open Access Journals (Sweden)

    Américo Hossne García

    2018-04-01

    Full Text Available The knowledge of elastoplastic properties is important for calculating soil elastic and plastic deformations experienced by static or dynamic loads generated, for example, by farm implements and root growth. The objective of this study was to determine the soil elastoplastic parameters: Young’s modulus (E, the shear modulus (G, bulk modulus (K and Poisson’s ratio (υ of a sandy-loam soil from a savanna in Monagas State, Venezuela. Triaxial tests and regression analyses were used to interpret the variance between them. The results show that E varied from 4693.39 to 36669.35 kPa; G from 700 to 5000 kPa; K from 500 to 2000 kPa and υ had a value of 0.50. It is concluded that these soils are incompressible under plastic conditions, i.e. easily deformable. The Poisson’s ratio varied significantly with soil water content. The Young modulus, bulk modulus and the shear modulus showed high variation with respect to water content. Both the Young’s modulus and Poisson’s ratio increased, at low soil water content, with the rise in chamber pressure .

  16. Degradation of tetraethyllead in leaded gasoline contaminated and uncontaminated soils

    International Nuclear Information System (INIS)

    Ou, L.; Jing, W.; Thomas, J.; Mulroy, P.

    1995-01-01

    For over 50 years, since its introduction in 1923 by General Motors, tetraethyllead (TEL) was the major antiknock agent used in leaded gasoline. Since the middle of 1970, use of leaded gasoline in automobiles was gradually phased out. The main objective of this study is to determine the degradation rates and metabolites of TEL in gasoline contaminated and uncontaminated soils. TEL in uncontaminated soils disappeared rapidly. Ionic triethyllead (TREL) was the major organolead metabolite in these soils, with ionic diethyllead (DEL) being the minor product. Nonsterile soils, but not autoclaved soils, had limited capacity to mineralize 14 C-TEL to 14 CO 2 , H 2 0, and Pb 2+ . Unlike TEL in uncontaminated soils, petroleum hydrocarbons protected TEL in leaded gasoline contaminated soils from being degraded. Both disappearance and mineralization rates of TEL in leaded gasoline contaminated soils decreased with the increase in gasoline concentration. It appears that TEL in leaded gasoline contaminated soils is relatively stable until the level of petroleum hydrocarbons falls below a critical value. TEL is then rapidly degraded. Hydrocarbon degrading microorganisms may be involved, to some extent, in the degradation of TEL

  17. Degradation of ¹³C-labeled pyrene in soil-compost mixtures and fertilized soil.

    Science.gov (United States)

    Adam, Iris K U; Miltner, Anja; Kästner, Matthias

    2015-11-01

    Polycyclic aromatic hydrocarbons (PAH) are toxic pollutants widely distributed in the environment due to natural and anthropogenic processes. In order to mitigate tar oil contaminations with PAH, research on improving bioremediation approaches, which are sometimes inefficient, is needed. However, the knowledge on the fate of PAH-derived carbon and the microbial degraders in particular in compost-supplemented soils is still limited. Here we show the PAH carbon turnover mass balance in microcosms with soil-compost mixtures or in farmyard fertilized soil using [(13)C6]-pyrene as a model PAH. Complete pyrene degradation of 100 mg/kg of soil was observed in all supplemented microcosms within 3 to 5 months, and the residual (13)C was mainly found as carbon converted to microbial biomass. Long-term fertilization of soil with farmyard manure resulted in pyrene removal efficiency similar to compost addition, although with a much longer lag phase, higher mineralization, and lower carbon incorporation into the biomass. Organic amendments either as long-term manure fertilization or as compost amendment thus play a key role in increasing the PAH-degrading potential of the soil microbial community. Phospholipid fatty acid stable isotope probing (PLFA-SIP) was used to trace the carbon within the microbial population and the amount of biomass formed from pyrene degradation. The results demonstrate that complex microbial degrader consortia rather than the expected single key players are responsible for PAH degradation in organic-amended soil.

  18. Plant species influence on soil C after afforestation of Mediterranean degraded soils

    Science.gov (United States)

    Dominguez, Maria T.; García-Vargas, Carlos; Madejón, Engracia; Marañón, Teodoro

    2015-04-01

    Increasing C sequestration in terrestrial ecosystems is one of the main current environmental challenges to mitigate climate change. Afforestation of degraded and contaminated lands is one of the key strategies to achieve an increase in C sequestration in ecosystems. Plant species differ in their mechanisms of C-fixation, C allocation into different plant organs, and interaction with soil microorganisms, all these factors influencing the dynamics of soil C following the afforestation of degraded soils. In this work we examine the influence of different woody plant species on soil C dynamics in degraded and afforested Mediterranean soils. The soils were former agricultural lands that were polluted by a mining accident and later afforested with different native plant species. We analysed the effect of four of these species (Olea europaea var. sylvestris Brot., Populus alba L., Pistacia lentiscus L. and Retama sphaerocarpa (L.) Boiss.) on different soil C fractions, soil nutrient availability, microbial activity (soil enzyme activities) and soil CO2 fluxes 15 years after the establishment of the plantations. Results suggest that the influence of the planted trees and shrubs is still limited, being more pronounced in the more acidic and nutrient-poor soils. Litter accumulation varied among species, with the highest C accumulated in the litter under the deciduous species (Populus alba L.). No differences were observed in the amount of total soil organic C among the studied species, or in the concentrations of phenols and sugars in the dissolved organic C (DOC), which might have indicated differences in the biodegradability of the DOC. Microbial biomass and activity was highly influenced by soil pH, and plant species had a significant influence on soil pH in the more acidic site. Soil CO2 fluxes were more influenced by the plant species than total soil C content. Our results suggest that changes in total soil C stocks after the afforestation of degraded Mediterranean

  19. Assessment of potential soil degradation on agricultural land in the czech republic.

    Science.gov (United States)

    Šarapatka, Bořivoj; Bednář, Marek

    2015-01-01

    Many attempts have been made worldwide to develop methods to identify the areas most threatened by soil degradation. Some soils in afflicted areas may be irreversibly degraded and thus have very little resilience (the ability to restore themselves). For the purpose of assessing the current state of soil degradation in the Czech Republic (CZ) we have developed an overall indicator of land vulnerability to the threat of soil degradation on the basis of individual factors that contribute to soil degradation and are monitored on a long-term basis in various research worksites in the CZ. Individual degradation factors were divided into two groups: chemical and physical degradation. On the basis of principal component analysis, individual degradation factors were assigned a specific weight of influence. With the use of a GIS, the input factors of degradation were combined to create maps of chemical and physical soil degradation, and consequently a map of overall degradation-threatened soils for the CZ, along with a map of areas differentiated according to the prevailing type of degradation. Results showed that, at present, the most important degradation factor in the CZ is water erosion, followed by loss of organic matter. Statistical analysis showed that approximately 51% of agricultural land is moderately threatened in the CZ. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

  20. Biochar effects on wet and dry regions of the soil water retention curve of a sandy loam

    DEFF Research Database (Denmark)

    Arthur, Emmanuel; Moldrup, Per; Sun, Zhencai

    2014-01-01

    Reported beneficial effects of biochar on soil physical properties and processes include decreased soil density, and increased soil water transport, water holding capacity and retention (mainly for the wet region). Research is limited on biochar effects on the full soil water retention curve (wet...... and dry regions) for a given soil and biochar amendment scenarios. This study evaluates how biochar applied to a sandy loam field at rates from 0 to 50 Mg ha−1 yr–1 in 2011, 2012, or both years (2011+2012) influences the full water retention curve. Inorganic fertilizer and pig slurry were added to all...... treatments. Six months after the last biochar application, intact and disturbed soil samples were collected for analyses. Soil water retention was measured from −1 kPa to −100 kPa using tension tables and ceramic plates and from −10 MPa to −480 MPa using a Vapor Sorption Analyzer. Soil specific area...

  1. [Effects of desertification on C and N storages in grassland ecosystem on Horqin sandy land].

    Science.gov (United States)

    Zhao, Ha-lin; Li, Yu-qiang; Zhou, Rui-lian

    2007-11-01

    Sandy grassland is widespread in northern China, where desertification is very common because of overgrazing and estrepement. However, little is known about the effects of desertification on grassland C and N storages in this region. A field survey was conducted on Horqin sandy grassland, and desertification gradients were established to evaluate the effects of desertification on C and N storages in soil, plant, and litter. The results showed that desertification had deep effects on the contents and storages of grassland C and N. The C and N contents and storages in the grassland decreased significantly with increasing desertification degree. Comparing with those in un-desertified grassland, the C and N contents in lightly, moderately, heavily, and severely desertified grasslands decreased by 56.06% and 48.72%, 78.43% and 74.36%, 88.95% and 84.62%, and 91.64% and 84.62% in 0-100 cm soil layer, and by 8.61% and 6.43%, 0.05% and 25.71%, 2.58% and 27.14%, and 8. 61% and 27. 86% in plant components, respectively. Relevantly, the C and N storages decreased by 50.95% and 43.38%, 75.19% and 71.04%, 86.76% and 81.48%, and 91.17% and 83.17% in plant underground components in 0-100 cm soil layer, and by 25.08% and 27.62%, 30.90% and 46.55%, 73.84% and 80.62%, and 90.89% and 87.31% in plant aboveground components, respectively. In 2000, the total area of desertified grassland in Horqin sandy land was 30152. 7 km2, and the C and N loss via desertification reached up to 107.53 and 9.97 Mt, respectively. Correlation analysis indicated that the decrease of soil C and N contents was mainly come from the decreased soil fine particles caused by wind erosion in the process of desertification, and the degradation of soil texture- and nutrient status led finally to the rapid decrease of C and N storages in plant biomass and litter.

  2. Field Performance of Nine Soil Water Content Sensors on a Sandy Loam Soil in New Brunswick, Maritime Region, Canada

    Directory of Open Access Journals (Sweden)

    Lionel Stevens

    2009-11-01

    Full Text Available An in situ field test on nine commonly-used soil water sensors was carried out in a sandy loam soil located in the Potato Research Center, Fredericton, NB (Canada using the gravimetric method as a reference. The results showed that among the tested sensors, regardless of installation depths and soil water regimes, CS615, Trase, and Troxler performed the best with the factory calibrations, with a relative root mean square error (RRMSE of 15.78, 16.93, and 17.65%, and a r2 of 0.75, 0.77, and 0.65, respectively. TRIME, Moisture Point (MP917, and Gopher performed slightly worse with the factory calibrations, with a RRMSE of 45.76, 26.57, and 20.41%, and a r2 of 0.65, 0.72, and 0.78, respectively, while the Gypsum, WaterMark, and Netafim showed a frequent need for calibration in the application in this region.

  3. Enhancing the biodegradation of oil in sandy sediments with choline: A naturally methylated nitrogen compound

    International Nuclear Information System (INIS)

    Mortazavi, Behzad; Horel, Agota; Anders, Jennifer S.; Mirjafari, Arsalan; Beazley, Melanie J.; Sobecky, Patricia A.

    2013-01-01

    We investigated how additions of choline, a naturally occurring methylated nitrogen-containing compound, accelerated hydrocarbon degradation in sandy sediments contaminated with moderately weathered crude oil (4000 mg kg −1 sediment). Addition of lauroylcholine chloride (LCC) and tricholine citrate (TCC) to oil contaminated sediments resulted in 1.6 times higher hydrocarbon degradation rates compared to treatments without added choline derivatives. However, the degradation rate constant for the oil contaminated sediments amended with LCC was similar to that in contaminated sediments amended with inorganic nitrogen, phosphorus, and glucose. Additions of LLC and TCC to sediments containing extensively weathered oil also resulted in enhanced mineralization rates. Cultivation-free 16S rRNA analysis revealed the presence of an extant microbial community with clones closely related to known hydrocarbon degraders from the Gammaproteobacteria, Alphaproteobacteria, and Firmicutes phyla. The results demonstrate that the addition of minimal amounts of organic compounds to oil contaminated sediments enhances the degradation of hydrocarbons. -- Highlights: •Aerobic degradation of weathered crude oil in sandy sediments was determined. •The effect of input of choline on degradation rates was determined. •16S rRNA clone library analyses were used to examine the microbial phylogeny. •The bacterial community was consisted of clones related to hydrocarbon degraders. •Hydrocarbon degradation in sandy sediments was accelerated by addition of choline. -- Choline, a naturally occurring methylated nitrogen-containing compound, accelerated hydrocarbon degradation in sandy sediments by an extant microbial community

  4. Bio stimulation for the Enhanced Degradation of Herbicides in Soil

    International Nuclear Information System (INIS)

    Kanissery, R.G; Sims, G.K

    2011-01-01

    Cleanup of herbicide-contaminated soils has been a dire environmental concern since the advent of industrial era. Although microorganisms are excellent degraders of herbicide compounds in the soil, some reparation may need to be brought about, in order to stimulate them to degrade the herbicide at a faster rate in a confined time frame. Bio stimulation through the appropriate utilization of organic amendments and nutrients can accelerate the degradation of herbicides in the soil. However, effective use of bio stimulants requires thorough comprehension of the global redox cycle during the microbial degradation of the herbicide molecules in the soil. In this paper, we present the prospects of using bio stimulation as a powerful remediation strategy for the rapid cleanup of herbicide-polluted soils.

  5. Eleven years' effect of conservation practices for temperate sandy loams: II. Soil pore characteristics

    DEFF Research Database (Denmark)

    Abdollahi, Lotfallah; Munkholm, Lars Juhl

    2017-01-01

    Conservation agriculture (CA) is regarded by many as a sustainable intensification strategy. Minimal soil disturbance in combination with residue retention are important CA components. This study examined the long-term effects of crop rotation, residue retention, and tillage on soil pore characte......Conservation agriculture (CA) is regarded by many as a sustainable intensification strategy. Minimal soil disturbance in combination with residue retention are important CA components. This study examined the long-term effects of crop rotation, residue retention, and tillage on soil pore...... characteristics of two Danish sandy loams. Rotation R2 is a rotation of winter crops (mainly cereals) with residues retained, rotation R3 a mix of winter and spring crops (mainly cereals) with residues removed, and rotation R4 the same mix of winter and spring crops, but with residues retained. Each rotation...... included the tillage treatments: moldboard plowing to 20-cm depth (MP), harrowing to 8- to 10-cm depth (H) and direct drilling (D). Soil cores were taken from the topsoil (4–8, 12–16, 18–27 cm) in mid-autumn 2013 and early spring 2014. Water retention, air permeability, and gas diffusivity was determined...

  6. Degradation of N-nitrosodimethylamine (NDMA) in landscape soils.

    Science.gov (United States)

    Yang, W C; Gan, J; Liu, W P; Green, R

    2005-01-01

    N-nitrosodimethylamine (NDMA), a potential carcinogen, was commonly found in treated wastewater as a by-product of chlorination. As treated water is increasingly used for landscape irrigation, there is an imperative need to understand the leaching risk for NDMA in landscape soils. In this study, adsorption and incubation experiments were conducted using landscape soils planted with turfgrass, ground cover, and trees. Adsorption of NDMA was negligibly weak (K(d) NDMA has a high potential for moving with percolating water in these soils. Degradation of NDMA occurred at different rates among these soils. At 21 degrees C, the half-life (t(1/2)) of NDMA was 4.1 d for the ground cover soil, 5.6 d for the turfgrass soil, and 22.5 d for the tree soil. The persistence was substantially prolonged after autoclaving or when incubated at 10 degrees C. The rate of degradation was not significantly affected by the initial NDMA concentration or addition of organic and inorganic nutrient sources. The relative persistence was inversely correlated with soil organic matter content, soil microbial biomass, and soil dehydrogenase activity, suggesting the importance of microorganisms in NDMA degradation in these soils. These results suggest that the behavior of NDMA depends closely on the vegetation cover in a landscape system, and prolonged persistence and increased leaching may be expected in soils with sparse vegetation due to low organic matter content and limited microbial activity.

  7. Soil Resources Degradation and Conservation Techniques Adopted ...

    African Journals Online (AJOL)

    Soil degradation is increasingly regarded as a major constraint to food production in the tropics. This problem is primarily caused by soil erosion, which particularly damages the soil surfaces. It is therefore the objectives of this paper to study the types of erosion in Gusau area as well as its effects on selected soil properties ...

  8. Soil bacterial diversity in degraded and restored lands of Northeast Brazil.

    Science.gov (United States)

    Araújo, Ademir Sérgio Ferreira; Borges, Clovis Daniel; Tsai, Siu Mui; Cesarz, Simone; Eisenhauer, Nico

    2014-11-01

    Land degradation deteriorates biological productivity and affects environmental, social, and economic sustainability, particularly so in the semi-arid region of Northeast Brazil. Although some studies exist reporting gross measures of soil microbial parameters and processes, limited information is available on how land degradation and restoration strategies influence the diversity and composition of soil microbial communities. In this study we compare the structure and diversity of bacterial communities in degraded and restored lands in Northeast Brazil and determine the soil biological and chemical properties influencing bacterial communities. We found that land degradation decreased the diversity of soil bacteria as indicated by both reduced operational taxonomic unit (OTU) richness and Shannon index. Soils under native vegetation and restoration had significantly higher bacterial richness and diversity than degraded soils. Redundancy analysis revealed that low soil bacterial diversity correlated with a high respiratory quotient, indicating stressed microbial communities. By contrast, soil bacterial communities in restored land positively correlated with high soil P levels. Importantly, however, we found significant differences in the soil bacterial community composition under native vegetation and in restored land, which may indicate differences in their functioning despite equal levels of bacterial diversity.

  9. Microbial degradation of sulfentrazone in a Brazilian rhodic hapludox soil

    Directory of Open Access Journals (Sweden)

    Camila O. Martinez

    2010-03-01

    Full Text Available Sulfentrazone is amongst the most widely used herbicides for treating the main crops in the State of São Paulo, Brazil, but few studies are available on the biotransformation of this compound in Brazilian soils. Soil samples of Rhodic Hapludox soil were supplemented with sulfentrazone (0.7 µg active ingredient (a.i. g-1 soil and maintained at 27ºC. The soil moisture content was corrected to 30, 70 or 100 % water holding capacity (WHC and maintained constant until the end of the experimental period. Herbicide-free soil samples were used as controls. Another experiment was carried out using soil samples maintained at a constant moisture content of 70% WHC, supplemented or otherwise with the herbicide, and submitted to different temperatures of 15, 30 and 40º C. In both experiments, aliquots were removed after various incubation periods for the quantitative analysis of sulfentrazone residues by gas chromatography. Herbicide-degrading microorganisms were isolated and identified. After 120 days a significant effect on herbicide degradation was observed for the factor of temperature, degradation being higher at 30 and 40º C. A half-life of 91.6 days was estimated at 27º C and 70 % WHC. The soil moisture content did not significantly affect sulfentrazone degradation and the microorganisms identified as potential sulfentrazone degraders were Nocardia brasiliensis and Penicillium sp. The present study enhanced the prospects for future studies on the bio-prospecting for microbial populations related to the degradation of sulfentrazone, and may also contribute to the development of strategies for the bioremediation of sulfentrazone-polluted soils.

  10. Strong Impact on the Polycyclic Aromatic Hydrocarbon (PAH)-Degrading Community of a PAH-Polluted Soil but Marginal Effect on PAH Degradation when Priming with Bioremediated Soil Dominated by Mycobacteria

    DEFF Research Database (Denmark)

    Johnsen, Anders R.; Schmidt, Stine; Hybholdt, Trine K.

    2007-01-01

    Bioaugmentation of soil polluted with polycyclic aromatic hydrocarbons (PAHs) is often disappointing because of the low survival rate and low activity of the introduced degrader bacteria. We therefore investigated the possibility of priming PAH degradation in soil by adding 2% of bioremediated soil...... with a high capacity for PAH degradation. The culturable PAH-degrading community of the bioremediated primer soil was dominated by Mycobacterium spp. A microcosm containing pristine soil artificially polluted with PAHs and primed with bioremediated soil showed a fast, 100- to 1,000-fold increase in numbers...... of culturable phenanthrene-, pyrene-, and fluoranthene degraders and a 160-fold increase in copy numbers of the mycobacterial PAH dioxygenase gene pdo1. A nonpolluted microcosm primed with bioremediated soil showed a high rate of survival of the introduced degrader community during the 112 days of incubation...

  11. Radiotracer studies on the degradation and dissipation of lindane under Malaysian environment. Part of a coordinated programme on the fate of persistent pesticides in the tropics, using radioisotopes

    International Nuclear Information System (INIS)

    Jamaluddin, M.D.

    1983-11-01

    A protocol was designed to provide information on rates of dissipation and degradation of lindane (γ-isomer of 1,2,3,4,5,6-hexachlorocyclohexane), a chemical used in Malaysia for pest control in rice paddies. The parameters studied included adsorption to three Malaysian soils, volatilization, degradation, dissipation through leaching and terminal residues in the grain. 14 C-labelled lindane was used after mixing with appropriate concentrations of the cold chemical. Standard nuclear techniques such as liquid scintillation counting and radiochromatography were applied. Adsorption of lindane to soil decreased in the order clay>sandy clay>loam>sandy loam. Volatilization of lindane was proportional to the chemical concentration and was more rapid in non-flooded and sterilized flooded soils. Under flooding conditions, microorganismal activities seem to play a dominant role in the disappearance, possibly degradation, of lindane. The half-life of lindane in non-sterilized flooded soil ranged from 10.5 to 34.5 days depending on the type of soil. The chemical residue in the grain was well below the maximum residue level. This is part of a project designed to provide data on the degradation and dissipation of lindane in the Malaysian environment in an attempt to pass a realistic judgement as to its persistence

  12. Adsorption, desorption and biodegradation in soil of CrylAb toxin protein from Bt transgenic rice

    International Nuclear Information System (INIS)

    Wang Haiyan; Ye Qingfu

    2004-01-01

    The equilibrium adsorption and binding of CrylAb toxin from Bt transgenic rice, to 7 different soils and the biodegradation of the bound toxin were studied. The adsorption rate of Bt in soils improved with decreasing of the added Bt purified protein concentration. Adsorption rate (125 and 780 nm/ml) in powdery-muddy paddy soil, Fluvio-marine yellow loamy and Coastal saline soil were 24.85% and 40.81%, 9.1% and 31.67%, 12.47% and 30.75%, respectively. Desorption rate in the soils dropped with content of soil-absorbed protein decreased. Its adsorption ratio in powdery-muddy paddy soil was 12.95% and 5.88%, respectively. The relationship between adsorption amount and concentration of Bt purified protein in different soils was notably positive correlation (P 0 e -λt ); Half life of Bt protein in soils was among 15.2-97.6 d; Degradation of pruified Bt protein was rapid at the initial incubation time (30 d), but slow at 150d incubation; The degradation of purified Bt protein in Intertidal sandy soil was the slowest with half-life of 97.6d. The protein in the soil amended with 1.25 μg/g could be still detectable after incubation of 345d; the degradation of purified Bt protein in Coastal saline soil and Aquic light saline sandy soil were faster. Their half-lives were 19.6 d and 15.2 d, respecitvely. The residue time of Bt purified protein in the soils was all more than 150 d. (authors)

  13. Carbazole degradation in the soil microcosm by tropical bacterial strains

    Directory of Open Access Journals (Sweden)

    Lateef B. Salam

    2015-01-01

    Full Text Available In a previous study, three bacterial strains isolated from tropical hydrocarbon-contaminated soils and phylogenetically identified as Achromobacter sp. strain SL1, Pseudomonassp. strain SL4 and Microbacterium esteraromaticum strain SL6 displayed angular dioxygenation and mineralization of carbazole in batch cultures. In this study, the ability of these isolates to survive and enhance carbazole degradation in soil were tested in field-moist microcosms. Strain SL4 had the highest survival rate (1.8 x 107 cfu/g after 30 days of incubation in sterilized soil, while there was a decrease in population density in native (unsterilized soil when compared with the initial population. Gas chromatographic analysis after 30 days of incubation showed that in sterilized soil amended with carbazole (100 mg/kg, 66.96, 82.15 and 68.54% were degraded by strains SL1, SL4 and SL6, respectively, with rates of degradation of 0.093, 0.114 and 0.095 mg kg−1 h−1. The combination of the three isolates as inoculum in sterilized soil degraded 87.13% carbazole at a rate of 0.121 mg kg−1 h−1. In native soil amended with carbazole (100 mg/kg, 91.64, 87.29 and 89.13% were degraded by strains SL1, SL4 and SL6 after 30 days of incubation, with rates of degradation of 0.127, 0.121 and 0.124 mg kg−1h−1, respectively. This study successfully established the survivability (> 106 cfu/g detected after 30 days and carbazole-degrading ability of these bacterial strains in soil, and highlights the potential of these isolates as seed for the bioremediation of carbazole-impacted environments.

  14. Relationships between physical-geographical factors and soil degradation on agricultural land.

    Science.gov (United States)

    Bednář, Marek; Šarapatka, Bořivoj

    2018-07-01

    It is a well-known fact that soil degradation is dramatically increasing and currently threatens agricultural soils all around the world. The objective of this study was to reveal the possible connection between soil degradation and seven physical-geographical factors - slope steepness, altitude, elevation differences, rainfall, temperature, soil texture and solar radiation - in the form of threshold values (if these exist), where soil degradation begins and ends. The analysis involved the whole area of the Czech Republic which consists of 13,027 cadasters (78,866 km 2 ). The greatest total degradation threat occurs in areas with slope steepness >7 degrees, average annual temperature 10.54, altitude >766 m a.s.l. Similarly, the results for water erosion, wind erosion, soil compaction, loss of organic matter, acidification and heavy metal contamination were processed. The results enable us to identify the relationships of different levels of threats which could consequently be used in various ways - for classification of threatened areas, for more effective implementation of anti-degradation measures, or purely for a better understanding of the role of physical geographical factors in soil degradation in the Czech Republic, and thus could increase the chances of reducing vulnerability to land degradation not only in the Czech Republic. Copyright © 2018 Elsevier Inc. All rights reserved.

  15. Response of corn silage (Zea mays L.) to zinc fertilization on a sandy soil under field and

    OpenAIRE

    Saad Drissi; Abdelhadi Aït Houssa; Ahmed Bamouh; Mohamed Benbella

    2017-01-01

    The purpose of the experiments was to evaluate zinc (Zn) fertilization effect on growth, yield and yield components of corn silage grown on a sandy soil under field and outdoor container conditions. Six rates of Zn supply (0 or control; 1.5; 3; 5; 10 and 50 mg kg−1) were tested. They were split at three different times during the growing season: (i) 50% immediately after sowing, (ii) 25% at 4–5 leaf stage and (iii) 25% at 8–9 leaf stage. These Zn rates were applied to the soil surface as a so...

  16. SUITABLE LOCATION OF SHEET PILE UNDER DAM RESTING ON SANDY SOIL WITH CAVITY

    Directory of Open Access Journals (Sweden)

    Laith J. Aziz

    2018-05-01

    Full Text Available This research describes the seepage characteristics of experimental model test of dam with cutoff located at different region (at dam heel, at mid floor of dam, and at dam toe. It is resting on sandy soil with cavity at different locations in X and Y directions (such as in Al-Najaf soil city. Thirty three model tests are performed in laboratory by using steel box to estimate the quantity of the seepage and flow lines direction. It was concluded that the best location of the cutoff wall is at the dam toe for model test with cavity ( Xc B = 0 and 0.5, but for model test with cavity ( Xc B ≥1, the best location of the sheet pile wall becomes at the dam heel. For negative location of the cavity, the best location of the sheet pile wall is at the middle of the floor dam.

  17. Chiral separation and enantioselective degradation of vinclozolin in soils.

    Science.gov (United States)

    Liu, Hui; Liu, Donghui; Shen, Zhigang; Sun, Mingjing; Zhou, Zhiqiang; Wang, Peng

    2014-03-01

    Vinclozolin is a chiral fungicide with potential environmental problems. The chiral separation of the enantiomers and enantioselective degradation in soil were investigated in this work. The enantiomers were separated by high-performance liquid chromatography (HPLC) on Chiralpak IA, IB, and AZ-H chiral columns under normal phase and the influence of the mobile phase composition on the separation was also studied. Complete resolutions were obtained on all three chiral columns under optimized conditions with the same elution order of (+)/(-). The residual analysis of the enantiomers in soil was conducted using accelerate solvent extraction followed by HPLC determination. The recoveries of the enantiomers ranged from 85.7-105.7% with relative standard deviation (SD) of 0.12-3.83%, and the limit of detection (LOD) of the method was 0.013 µg/g. The results showed that the degradations of vinclozolin enantiomers in the soils followed first-order kinetics. Preferential degradation of the (-)-enantiomer was observed only in one soil with the largest |ES| value of 0.047, and no obvious enantioselective degradation was observed in other soils. It was found that the persistence of vinclozolin in soil was related to pH values based on the half-lives. The two enantiomers disappeared about 8 times faster in basic soils than that in neutral or acidic soils. © 2014 Wiley Periodicals, Inc.

  18. CARBON FIXING CAPACITY OF AMAZONIAN SOILS IN RELATION TO ITS DEGRADATION CONDITIONS

    Directory of Open Access Journals (Sweden)

    Clara Patricia Peña Venegas

    2015-06-01

    Full Text Available Amazonian deforestation and transformation alert about their effects worldwide. One concern is the increase of the Carbon (C levels emitted. Previous works have estimated the fixed C in Amazon forests without including the C stored in soils. Within soil, the organic carbon molecules are highly sensitive to degradation, affecting the natural capacity of soils to fix and store C. The present study evaluates the impact of degradation in the natural capacity of Amazon soils to fix C. Thirty five farms with different typology were selected in Caquetá department which hold the highest deforestation and soil degradation rates in the Colombian Amazon. Soil samples were taken from natural forest relicts, cropping areas and introduced pastures of the farms, in locations with high, intermediate and low soil degradation. Aerial biomass was estimated in pastures with different level of soil degradation. Changes in the labile C stock were estimated from the soil organic carbon and the microbial biomass using substrate induced respiration. Results showed that the main C pool is in the natural forest relicts and the crops of the farms, independently from the size or type of farm sampled. The hills with higher intervention showed the lowest soil C fixation capacities. The soil C fixation capacity was related with changes in the soil microbial composition where conserved soils store preferentially C as fungal biomass while degraded soils store C as bacterial biomass. These estimations contribute to establish the cost of sustainability and soil degradation in the Colombian Amazon.

  19. Response characteristics of vegetation and soil environment to permafrost degradation in the upstream regions of the Shule River Basin

    International Nuclear Information System (INIS)

    Chen Shengyun; Liu Wenjie; Qin Xiang; Liu Yushuo; Ren Jiawen; Qin Dahe; Zhang Tongzuo; Hu Fengzu; Chen Kelong

    2012-01-01

    Permafrost degradation exhibits striking and profound influences on the alpine ecosystem, and response characteristics of vegetation and soil environment to such degradation inevitably differ during the entire degraded periods. However, up to now, the related research is lacking in the Qinghai–Tibetan Plateau (QTP). For this reason, twenty ecological plots in the different types of permafrost zones were selected in the upstream regions of the Shule River Basin on the northeastern margin of the QTP. Vegetation characteristics (species diversity, community coverage and biomass etc) and topsoil environment (temperature (ST), water content (SW), mechanical composition (SMC), culturable microorganism (SCM), organic carbon (SOC) and total nitrogen (TN) contents and so on), as well as active layer thickness (ALT) were investigated in late July 2009 and 2010. A spatial–temporal shifts method (the spatial pattern that is represented by different types of permafrost shifting to the temporal series that stands for different stages of permafrost degradation) has been used to discuss response characteristics of vegetation and topsoil environment throughout the entire permafrost degradation. The results showed that (1) ST of 0–40 cm depth and ALT gradually increased from highly stable and stable permafrost (H-SP) to unstable permafrost (UP). SW increased initially and then decreased, and SOC content and the quantities of SCM at a depth of 0–20 cm first decreased and then increased, whereas TN content and SMC showed obscure trends throughout the stages of permafrost degradation with a stability decline from H-SP to extremely unstable permafrost (EUP); (2) further, species diversity, community coverage and biomass first increased and then decreased in the stages from H-SP to EUP; (3) in the alpine meadow ecosystem, SOC and TN contents increased initially and then decreased, soil sandy fractions gradually increased with stages of permafrost degradation from substable (SSP

  20. Degradation of a chiral nonylphenol isomer in two agricultural soils

    International Nuclear Information System (INIS)

    Zhang Haifeng; Spiteller, Michael; Guenther, Klaus; Boehmler, Gabriele; Zuehlke, Sebastian

    2009-01-01

    The degradation of a chiral nonylphenol isomer, 4-(1-ethyl-1,4-dimethylpentyl)phenol (NP 112 ), in two agricultural soils from Monheim and Dortmund, Germany has been studied. The degradation of NP 112 and the formation of a nitro-nonylphenol metabolite were determined by means of GC-MS analysis. The degradation followed bi-exponential order kinetics, with half-life of less than 5 days in both soils. The nitro-metabolite was found at different concentration levels in the two soils. The nitro-metabolite of NP 112 was more persistent than its parent compound. After 150 days about 13% of the initially applied NP 112 remained in the Monheim soil as its nitro-metabolite. Results of the E-screen assay revealed that the nitro-NP 112 has oestrogenic potency of 85% of that of NP 112 . Furthermore, the results of chiral GC-MS analysis revealed that no chiral degradation of NP 112 occurred in this study. - The degradation of a chiral nonylphenol isomer in agricultural soils followed bi-exponential order kinetics resulting in a more persistent nitro-metabolite.

  1. Plant uptake and soil retention of phthalic acid applied to Norfolk sandy loam

    International Nuclear Information System (INIS)

    Dorney, J.R.; Weber, J.B.; Overcash, M.R.; Strek, H.J.

    1985-01-01

    Plant uptake and soil retention of 14 C carboxyl-labeled phthalic acid were studied at application rates of 0.6, 6.0, 60.0, and 600.0 ppm (soil dry weight) to Norfolk sandy loam (Typic Paleudult, fine loamy, kaolinitic, thermic). Height and dry weight of corn (Zea mays L. Pioneer 3368A) (21 day), tall fescue (Festuca arundinacea Schreb. Kentucky 31) (45 day) immature soybean (Glycine max (L.) Merr. Altoona) (21 day) plant, mature soybean plant, and mature wheat (Triticum aestivum L. Butte) straw were not affected by phthalic acid applied to soil. In addition, soybean seed and wheat seed dry weight were unaffected. Immature wheat (40 day) height decreased at the 600 ppm rate. Plant uptake of phthalic acid ranged from 0 to 23 ppm and was significantly above background for all plants and plant materials except soybean pods. Fescue and immature plants exhibited the highest concentration of phthalic acid while mature wheat plants and wheat seeds exhibited the least. Most of the phthalic acid volatilized or was decomposed from the soil by the end of the study; an average of only 5.7% of the originally applied chemical was recovered in both soil or plants. An average of 0.02% of the originally applied phthalic acid leached out of the treated zone. Considering the low toxicity of phthalic acid and its relatively rapid disappearance from soil, it is unlikely to become a health hazard from contaminated plants. However, plant uptake of other toxic organics could potentially become a hazard on soils treated with sludge containing significant quantities of these substances

  2. Effects of a novel poly (AA-co-AAm)/AlZnFe₂O₄/potassium humate superabsorbent hydrogel nanocomposite on water retention of sandy loam soil and wheat seedling growth.

    Science.gov (United States)

    Shahid, Shaukat Ali; Qidwai, Ansar Ahmad; Anwar, Farooq; Ullah, Inam; Rashid, Umer

    2012-10-25

    A novel poly(acrylic acid-co-acrylamide)AlZnFe₂O₄/potassium humate( )superabsorbent hydrogel nanocomposite (PHNC) was synthesized and its physical properties characterized using SEM, Energy Dispersive X-ray (EDX) and FTIR spectroscopic techniques. Air dried sandy loam soil was amended with 0.1 to 0.4 w/w% of PHNC to evaluate its soil moisture retention attributes. Effect of PHNC amendment on pH, electrical conductivity (EC), porosity, bulk density and hydraulic conductivity of sandy loam soil was also studied. The soil amendment with 0.1 to 0.4 w/w% of PHNC remarkably enhanced the moisture retention at field capacity as compared to the un-amended soils. Seed germination and seedling growth of wheat (Triticum aestivum L.) was considerably increased and a delay by 6-9 days in wilting of seedlings was observed in the soil amended with PHNC, resulting in improved wheat plant establishment and growth.

  3. Field sampling of residual aviation gasoline in sandy soil

    International Nuclear Information System (INIS)

    Ostendorf, D.W.; Hinlein, E.S.; Yuefeng, Xie; Leach, L.E.

    1991-01-01

    Two complementary field sampling methods for the determination of residual aviation gasoline content in the contaminated capillary fringe of a fine, uniform, sandy soil were investigated. The first method featured field extrusion of core barrels into pint-size Mason jars, while the second consisted of laboratory partitioning of intact stainless steel core sleeves. Soil samples removed from the Mason jars (in the field) and sleeve segments (in the laboratory) were subjected to methylene chloride extraction and gas chromatographic analysis to compare their aviation gasoline content. The barrel extrusion sampling method yielded a vertical profile with 0.10m resolution over an essentially continuous 5.0m interval from the ground surface to the water table. The sleeve segment alternative yielded a more resolved 0.03m vertical profile over a shorter 0.8m interval through the capillary fringe. The two methods delivered precise estimates of the vertically integrated mass of aviation gasoline at a given horizontal location, and a consistent view of the vertical profile as well. In the latter regard, a 0.2m thick lens of maximum contamination was found in the center of the capillary fringe, where moisture filled all voids smaller than the mean pore size. The maximum peak was resolved by the core sleeve data, but was partially obscured by the barrel extrusion observations, so that replicate barrels or a half-pint Mason jar size should be considered for data supporting vertical transport analyses in the absence of sleeve partitions

  4. Grape yield, and must compounds of 'Cabernet Sauvignon' grapevine in sandy soil with potassium contents increasing

    Directory of Open Access Journals (Sweden)

    Marlise Nara Ciotta

    2016-08-01

    Full Text Available ABSTRACT: Content of exchangeable potassium (K in t soil may influence on its content in grapevines leaves, grape yield, as well as, in must composition. The study aimed to assess the interference of exchangeable K content in the soil on its leaf content, production and must composition of 'Cabernet Sauvignon' cultivar. In September 2011, in Santana do Livramento (RS five vineyards with increasing levels of exchangeable K in the soil were selected. In the 2012/13 and 2013/14 harvests, the grape yield, yield components, total K content in the leaves in full bloom and berries veraison were evaluated. Values of total soluble sugar (TSS, pH, total titratable acidity (TTA, total polyphenols and anthocyanins were evaluated in the must. Exchangeable K content increase in soil with sandy surface texture increased its content in leaves collected during full flowering and in berries and must pH; however, it did not affect production of the 'Cabernet Sauvignon'.

  5. Study on degradation of dimefuron in soil by nuclear technique

    International Nuclear Information System (INIS)

    Pakkong, P.; Vadeilai, J.

    1996-01-01

    Study on degradation of herbicide dimefuron in soil by using bio meter flask experiment was conducted under laboratory condition, 14 C-dimefuron was applied to three conditions of sterile soil normal and bio fertilizer added soil. Every month 14 CO 2 was collected from 1 N KOH in bio meter flask with in eight months period. Carbon-14 activity was analyzed by liquid scintillation counter. The result of dimefuron degradation as 14 CO 2 in sterile normal and bio fertilizer added soil were 0.96 percent 6.31 percent and 9.36 percent. It can be concluded that increasing in dimefuron degradation rate was involved by micro-organism activity. After eight month extracted and bounded residue of dimefuron in soil were analysed. Radioassay show that extracted and bounded residue were 58.62 and 29.58 percent in sterile soil 45.73 and 41.91 percent in normal soil 45.28 and 36.3 percent in bio fertilizer added soil

  6. Long-term phytoavailability of soil-applied organo-borates

    International Nuclear Information System (INIS)

    Adriano, D.C.; Kaplan, D.I.; Burkman, W.G.; Mills, G.L.

    1988-01-01

    Sodium tetraphenylboron (NaTPB) is expected to be used in large quantities to separate radiocesium from high-level nuclear wastes. Greenhouse experiments were conducted to determine the long-term effects of NaTPB, diphenylboric acid (DPBA, a major degradation by-product of NaTPB) and boric acid (BA) on the extractability of soil B and plant B nutrition. Sorgrass (Sorghum vulgare sudanense Hitchc. Dub-L-Graze) was planted in sandy and loamy sandy soils in two separate 2-yr studies. Results indicate that initial differences between effects of the B sources on biomass, plant B concentration, plant B uptake and hot-water extractable B disappeared after the first harvest, while differences among these parameters due to soil type and application rate remained throughout the experiments. Extractable soil and plant B concentrations tended to decrease more gradually in the loamy sand than in the sandy soil. Plant toxicity from organic sources was noted only during the first harvest while BA had no adverse effects. Both NaTPB and DPBA reduced biomass, the former more than the latter. Initially, plant B concentrations were higher in NaTPB than BA treatments. The cumulative percentage of soil-applied B removal after 2 yr by sorgrass remained fairly similar, 20.0 +/- 1.7% (1SD) among B sources and application rates. This suggests that a large fraction of B applied to the soil was not taken up by the plant, presumably due to soil fixation. Biphenyl, another major breakdown product of NaTPB, had no effect on sorgrass growth, tissue B concentration, and soil B concentration

  7. Potassium efficiency of different crops grown on a sandy soil under controlled conditions

    International Nuclear Information System (INIS)

    El Dessougi, H. I.; Claassen, N.; Steingrobe, B.

    2010-01-01

    The objective of this work was to study K efficiency of different crops and determine the plant parameters affecting it. The study was carried out using 14 different crops and cultivars grown on a sandy soil rich in humus, with two potassium fertilisation levels under controlled conditions. The studied crops showed different K efficiency reflected in different dry matter yield production in unfertilised relative to fertilised treatments. All crops had , at low K supply, less than optimum K concentration in dry matter, indicating that the soil K concentration did not meet the K requirement of the plants, Thus, the ability to produce high dry matter yield indicated superior adaptability to K deficiency. The efficiency mechanisms employed by the different crops were low shoot growth rate and/or high root length-shoot weigh ratio and a high uptake rate per unit root, i.e. the influx, or low internal K requirement. Crops with high influx had higher calculated concentration gradients, since they caused further decrease of the concentration at the root surface. As such, they were able to create steeper concentration gradients between bulk soil solution and root surface. This resulted in higher diffusive flux to the roots.(Author)

  8. Degradation Capability of n-hexadecane Degrading Bacteria from Petroleum Contaminated Soils

    Directory of Open Access Journals (Sweden)

    PENG Huai-li

    2017-05-01

    Full Text Available Samplings were performed in the petroleum contaminated soils of Dongying, Shandong Province of China. Degrading bacteria was isolated through enrichment in a Bushnel-Hass medium, with n-hexadecane as the sole source of carbon and energy. Then the isolated strains were identified by amplification of 16S rDNA gene and sequencing. The strain TZSX2 was selected as the powerful bacteria with stronger degradation ability, which was then identified as Rhodococcus hoagii genera based on the constructing results of the phylogenetic tree. The optimum temperature that allowed both high growth and efficient degradation ratio was in the scope of 28~36 ℃, and gas chromatography results showed that approximately more than 30% of n-hexadecane could be degraded in one week of incubation within the temperature range. Moreover, the strain TZSX2 was able to grow in high concentrations of n-hexadecane. The degradation rate reached 79% when the initial n-hexadecane concentration was 2 mL·L-1,while it still achieved 12% with n-hexadecane concentration of 20 mL·L-1. The optimal pH was 9 that allowed the highest growth and the greatest degradation rate of 91%. Above all, the screened strain TZSX2 showed high capabilities of alkali tolerance with excellent degradation efficiency for even high concentration of n-hexadecane, and thus it would be quite suitable for the remediation of petroleum contaminated soils especially in the extreme environment.

  9. Evaluation of Bioaugmentation with Entrapped Degrading Cells as a Soil Remediation Technology

    DEFF Research Database (Denmark)

    Owsianiak, Mikolaj; Dechesne, Arnaud; Binning, Philip John

    2010-01-01

    Soil augmentation with microbial degraders immobilized on carriers is evaluated as a potential remediation technology using a mathematical model that includes degradation within spatially distributed carriers and diffusion or advectiondispersion as contaminant mass transfer mechanisms. The total...... degraders have low intrinsic degradation rates and that only limited carrier to soil volume ratios are practically feasible, bioaugmented soils are characterized by low effective degradation ratesandcanbeconsidered fully mixed. A simple exponential model is then sufficient to predict biodegradation...

  10. Measurement of earthquake-induced shear strain in sandy gravel

    International Nuclear Information System (INIS)

    Ohkawa, I.; Futaki, M.; Yamanouchi, H.

    1989-01-01

    The nuclear power reactor buildings have been constructed on the hard rock ground formed in or before the Tertiary in Japan. This is mainly because the nuclear reactor building is much heavier than the common buildings and requires a large bearing capacity of the underlying soil deposit, and additionally the excessive deformation in soil deposit might cause damage in reactor building and subsequently cause the malfunction of the internal important facilities. Another reason is that the Quaternary soil deposit is not fully known with respect to its dynamic property. The gravel, and the sandy gravel, the representative soils of the Quaternary, have been believed to be suitable soil deposits to support the foundation of a common building, although the soils have rarely been investigated so closely on their physical properties quantitatively. In this paper, the dynamic deformability, i.e., the shear stress-strain relationship of the Quaternary diluvial soil deposit is examined through the earthquake ground motion measurement using accelerometers, pore-pressure meters, the specific devices developed in this research work. The objective soil deposit in this research is the sandy gravel of the diluvial and the alluvial

  11. Degradation of 14C-glyphosate in compost amended soils.

    Science.gov (United States)

    Alexa, E; Bragea, M; Sumalan, R; Negrea, M; Lazureanu, A

    2009-01-01

    Glyphosate (N-phosphonomethyl-glycine), the active ingredient in several herbicide formulations, is a non-selective, post-emergent herbicide used in a variety of crop and non-crop situations. Glyphosate is a non-volatile herbicide that is relatively immobile in soil. Its degradation is due to microbiological processes and most laboratory studies have been conducted with 14C-glyphosate with the rate of 14CO2 evolution being used as an indication of herbicide breakdown. In this paper we have studied the glyphosate degradation in compost amendment soils using Scientilator Liquid TRIATHLER and Glyphosate-phosphonomethyl-14C-labeled with specific activity 2,2mCi/mmol. Four types of soils have been taken under study: Black Chernozem, Vertisol, Gleysol and Phaeozem with different characteristics. For the each type of soil have been realized four experimental variants (glyphosate blind sample with 1,5 ppm, concentration, autoclaved soil, soil with glyphosate and addition of compost in field concentration of 40 t/ha, respectively 60 t/ha. The mineralization curves of 14CO2 accumulated were compared during of 40 days. All the mineralization curves for the soils exhibited same patterns, with only two phases, the initial rapid phase of degradation, for about 20 days, attributed to microbial action on the free glyphosate and the second slow phase, when the curves attained plateaus. Compost applied with different concentrations to Vertisol and Black Chernozem did not appear to stimulate the microbial degradation of glyphosate. In Gleysol and Phaeozem with lower humus content, the mineralization curve of 14C indicate the increase degradation capacity, expressed as accumulated 14CO2 as % total 14C, with the increase of compost concentration.

  12. Soil degradation in Pakistan

    International Nuclear Information System (INIS)

    Khan, M.R.

    2005-01-01

    This paper diagnoses the issues involved behind the current state, usage, interactions and linkages in the soils in Pakistan. The condition of soils is deteriorating due to developmental and environmental factors such as soil degradation, water pollution, fauna degeneration etc. Issues, problems and constraints faced in the management and usage of soils are diagnosed at different levels in the ecosystems predominant in Pakistan. The research questions propose effective solutions, types of instruments, methods or processes to resolve the issues within the various areas or ecosystems in the most sustainable and effective manner [23]. Biological solutions and methods can be applied at the sub-system level by private individuals or communities at a lower cost, and at a more localized level than engineering methods. Engineering methods may be suited for interventions at a system level rather than at a sub-system level; but even at this level they will be complementary with biological methods. (author)

  13. Understanding and Enhancing Soil Biological Health: The Solution for Reversing Soil Degradation

    Directory of Open Access Journals (Sweden)

    R. Michael Lehman

    2015-01-01

    Full Text Available Our objective is to provide an optimistic strategy for reversing soil degradation by increasing public and private research efforts to understand the role of soil biology, particularly microbiology, on the health of our world’s soils. We begin by defining soil quality/soil health (which we consider to be interchangeable terms, characterizing healthy soil resources, and relating the significance of soil health to agroecosystems and their functions. We examine how soil biology influences soil health and how biological properties and processes contribute to sustainability of agriculture and ecosystem services. We continue by examining what can be done to manipulate soil biology to: (i increase nutrient availability for production of high yielding, high quality crops; (ii protect crops from pests, pathogens, weeds; and (iii manage other factors limiting production, provision of ecosystem services, and resilience to stresses like droughts. Next we look to the future by asking what needs to be known about soil biology that is not currently recognized or fully understood and how these needs could be addressed using emerging research tools. We conclude, based on our perceptions of how new knowledge regarding soil biology will help make agriculture more sustainable and productive, by recommending research emphases that should receive first priority through enhanced public and private research in order to reverse the trajectory toward global soil degradation.

  14. Effect of intermediate soil cover on municipal solid waste decomposition.

    Science.gov (United States)

    Márquez-Benavides, L; Watson-Craik, I

    2003-01-01

    A complex series of chemical and microbiological reactions is initiated with the burial of refuse in a sanitary landfill. At the end of each labour day, the municipal solid wastes (MSW) are covered with native soil (or an alternative material). To investigate interaction between the intermediate cover and the MSW, five sets of columns were set up, one packed with refuse only, and four with a soil-refuse mixture (a clay loam, an organic-rich peaty soil, a well limed sandy soil and a chalky soil). The anaerobic degradation over 6 months was followed in terms of leachate volatile fatty acids, chemical oxygen demand, pH and ammoniacal-N performance. Results suggest that the organic-rich peaty soil may accelerate the end of the acidogenic phase. Clay appeared not to have a significant effect on the anaerobic degradation process.

  15. Influence of manganese fertilizer on efficiency of grapes on sandy soils of the Chechen Republic

    Directory of Open Access Journals (Sweden)

    Batukaev A.A.

    2014-01-01

    Full Text Available As a result of the studies, there has been obtained new information about the manganese influence on productivity of grape plantations, on sandy soils of the Chechen Republic. Manganese fertilizing of 4 kg active ingredient per 1 ha, against the background of nitrogen 90 kg, phosphorus 90 kg and potassium 90 kg/ha, made it into a phase of grape sap flow, which contributes to higher yields, increase of the sugar content of the berries and a significant decrease in juice acidity, in comparison with other options.

  16. influence of tillage practices on physical properties of a sandy loam

    African Journals Online (AJOL)

    DR. AMINU

    many regions of the world if the mechanics of tillage effects on soil physical properties is to be well understood. Thus, the ... tillage systems on water storage of a sandy loam soil after 22 years of ..... Soil infiltration ... and processes. Academy ...

  17. Development of a composite soil degradation assessment index for cocoa agroecosystems in southwestern Nigeria

    Science.gov (United States)

    Adenrele Adeniyi, Sunday; de Clercq, Willem Petrus; van Niekerk, Adriaan

    2017-08-01

    Cocoa agroecosystems are a major land-use type in the tropical rainforest belt of West Africa, reportedly associated with several ecological changes, including soil degradation. This study aims to develop a composite soil degradation assessment index (CSDI) for determining the degradation level of cocoa soils under smallholder agroecosystems of southwestern Nigeria. Plots where natural forests have been converted to cocoa agroecosystems of ages 1-10, 11-40, and 41-80 years, respectively representing young cocoa plantations (YCPs), mature cocoa plantations (MCPs), and senescent cocoa plantations (SCPs), were identified to represent the biological cycle of the cocoa tree. Soil samples were collected at a depth of 0 to 20 cm in each plot and analysed in terms of their physical, chemical, and biological properties. Factor analysis of soil data revealed four major interacting soil degradation processes: decline in soil nutrients, loss of soil organic matter, increase in soil acidity, and the breakdown of soil textural characteristics over time. These processes were represented by eight soil properties (extractable zinc, silt, soil organic matter (SOM), cation exchange capacity (CEC), available phosphorus, total porosity, pH, and clay content). These soil properties were subjected to forward stepwise discriminant analysis (STEPDA), and the result showed that four soil properties (extractable zinc, cation exchange capacity, SOM, and clay content) are the most useful in separating the studied soils into YCP, MCP, and SCP. In this way, we have sufficiently eliminated redundancy in the final selection of soil degradation indicators. Based on these four soil parameters, a CSDI was developed and used to classify selected cocoa soils into three different classes of degradation. The results revealed that 65 % of the selected cocoa farms are moderately degraded, while 18 % have a high degradation status. The numerical value of the CSDI as an objective index of soil degradation

  18. Active Distribute Temperature Sensing to Estimate Vertical Water Content Variations in a Loamy-Sandy Soil

    Science.gov (United States)

    Ciocca, F.; Van De Giesen, N.; Assouline, S.; Huwald, H.; Hopmans, J. W.; Lunati, I.; Parlange, M. B.

    2011-12-01

    Optical fibers in combination with Raman scattering measurements (Distributed Temperature Sensor: DTS) have recently become more standard for the measurement of soil temperature. A recently developed technique to measure soil moisture called Active DTS (ADTS) is investigated in this study. ADTS consists of an application of a heat pulse for a fixed duration and power along the metal sheath covering the optical fiber placed in the soil. Soil moisture can be inferred from the increased temperature measured during the heating phase and the subsequent temperature decrease during the cooling phase. We assess this technique for a loamy-sandy soil as part of a field campaign that took place during the 2011 summer at EPFL. The measurements were taken within a weighing lysimeter (2.5 m depth and 1.2 m diameter) using an optical fiber arranged in 15 loops for a total measurement length of 52 m in the top 80 cm of the soil profile. Local soil moistures were simultaneously measured using capacity-based probes. Thermocouples, wrapped around the fiber, are used to account for the effects of the insulating cover surrounding the cable. Heat pulses of various duration and power have been applied for a range of soil moistures. Measurements were taken during periods of drainage and evaporation. The accuracy of the technique for the EPFL 2011 field campaign and the experiment are discussed and the soil moisture measurements are presented.

  19. Zinc oxide nanoparticles affect carbon and nitrogen mineralization of Phoenix dactylifera leaf litter in a sandy soil.

    Science.gov (United States)

    Rashid, Muhammad Imtiaz; Shahzad, Tanvir; Shahid, Muhammad; Ismail, Iqbal M I; Shah, Ghulam Mustafa; Almeelbi, Talal

    2017-02-15

    We investigated the impact of zinc oxide nanoparticles (ZnO NPs; 1000mgkg -1 soil) on soil microbes and their associated soil functions such as date palm (Phoenix dactylifera) leaf litter (5gkg -1 soil) carbon and nitrogen mineralization in mesocosms containing sandy soil. Nanoparticles application in litter-amended soil significantly decreased the cultivable heterotrophic bacterial and fungal colony forming units (cfu) compared to only litter-amended soil. The decrease in cfu could be related to lower microbial biomass carbon in nanoparticles-litter amended soil. Likewise, ZnO NPs also reduced CO 2 emission by 10% in aforementioned treatment but this was higher than control (soil only). Labile Zn was only detected in the microbial biomass of nanoparticles-litter applied soil indicating that microorganisms consumed this element from freely available nutrients in the soil. In this treatment, dissolved organic carbon and mineral nitrogen were 25 and 34% lower respectively compared to litter-amended soil. Such toxic effects of nanoparticles on litter decomposition resulted in 130 and 122% lower carbon and nitrogen mineralization efficiency respectively. Hence, our results entail that ZnO NPs are toxic to soil microbes and affect their function i.e., carbon and nitrogen mineralization of applied litter thus confirming their toxicity to microbial associated soil functions. Copyright © 2016 Elsevier B.V. All rights reserved.

  20. Impact of hydrocarbon type, concentration and weathering on its biodegradability in soil.

    Science.gov (United States)

    Maletić, Snežana P; Dalmacija, Božo D; Rončević, Srđan D; Agbaba, Jasmina R; Perović, Svetlana D Ugarčina

    2011-01-01

    The objective of this research was to investigate the impact of the hydrocarbon type and concentration, as well as the total effect of the natural weathering process to hydrocarbon biodegradability in sandy soil and the environment. In this experiment, sandy soil was separately contaminated with 0.5%, 1.0%, 2.0% and 3.5% of diesel and crude oils. Oil contaminated soil was taken from the Oil Refinery dumping sites after 9 years of weathering, and its concentration was adjusted to the above-mentioned levels. The biodegradation process was monitored by measuring CO(2), evolution rate, hydrocarbon degradation rate and dehydrogenase activity. The favourable concentration ranges for the soil contaminated with diesel oil were 1.0%, with concentrations at about 2.0% causing slightly adverse effects to CO(2) production which was overcome after 2 weeks, and with 3.5% diesel oil causing significant toxicity. For soil contaminated with crude oil, 2.0% was found to be optimum for effective biodegradation, with 3.5% crude oil also causing adverse effects to CO(2) production, although less so than the same concentration of diesel oil. No adverse effect was obtained for any concentration of the weathered oil, as after the weathering process, the remaining contaminants in the soil were mostly poorly degradable constituents like asphaltenes, resins etc. It has been proposed that such residual material from oil degradation is analogous to, and can even be regarded as, humic material. Due to its inert characteristics, insolubility and similarity to humic materials it is unlikely to be environmentally hazardous.

  1. Evaluation of natural attenuation, bioventing, bioaugmentation and bioaugmentation-bioventing techniques, for the biodegradation of diesel in a sandy soil, through column experiments

    International Nuclear Information System (INIS)

    Muskus Morales, Angelica Maria; Santoyo Munoz, Claudia; Plata Quintero, Luijesmarth Silvia

    2013-01-01

    The present study was developed within an inter-institutional agreement between the Universidad Pontificia Bolivariana, UPB-BBGA and the Colombian Petroleum Institute-ICP, in order to provide a solution to an environmental problem that occurs in areas where hydrocarbons are handled and where sandy soils have been found to be contaminated with diesel fuel with concentrations up to 6% at a maximum depth of 80 cm. For this study, the soil samples were artificially contaminated with diesel fuel in order to evaluate Natural Attenuation, Bioventing, Bioaugmentation and Bioaugmentation-Bioventing soil remediation techniques through the use of column experiments. The design parameters, column dimensions, inflow, diesel concentration, dissolved oxygen, bacterial growth, and monitoring was defined. Bioaugmentation was performed inoculating a bacterial consortium produced by the ICP. The experimental setup was assembled in triplicate and was monitored through a period of four months. The experimental results showed that Bioventing technique was the most effective, reaching up to 97% diesel removal from the contaminated soil; with the Bioaugmentation - Bioventing, diesel fuel removal percentage was 75%, and the Natural Attenuation and Bioaugmentation techniques resulted in diesel fuel removal percentages not greater than 48%. This study showed that the microbial consortium evaluated and provided by the Colombian Petroleum Institute proved to be not efficient for potentializing bioremediation processes of sandy soils contaminated with diesel fuel.

  2. Mobility and degradation of 14C-trifluralin in soil

    International Nuclear Information System (INIS)

    Zheng Lin; Wang Fujun

    1993-01-01

    Under laboratory condition, the adsorption, mobility and degradation of 14 C-trifluralin in soil were studied by using radioactive isotopic tracer. The results show that the adsorption of trifluralin in soil is quite strong. The rates of adsorption in soil are 73.89 ∼ 90.66%. The adsorption is significantly affected by the organic matter content of soil. It leaches rather low in Grassy-marsh land black soil containing plentiful organic matter and higher clay content, but quite higher in sand, and is more easily to move down. Under anaerobic condition, degradation of trifluralin in soil is faster. It is derogated by 60.2 ∼ 60.4% in soil extractive state within 30 days, and by 90.0 ∼ 94.7% within 60 days. Its main metabolites are the compounds with R f 0.06, 0.15 and 0.42 respectively

  3. Effect of soil texture on phytoremediation of arsenic-contaminated soils

    Science.gov (United States)

    Pallud, C. E.; Matzen, S. L.; Olson, A.

    2015-12-01

    Soil arsenic (As) contamination is a global problem, resulting in part from anthropogenic activities, including the use of arsenical pesticides and treated wood, mining, and irrigated agriculture. Phytoextraction using the hyperaccumulating fern Pteris vittata is a promising new technology to remediate soils with shallow arsenic contamination with minimal site disturbance. However, many challenges still lie ahead for a global application of phytoremediation. For example, remediation times using P. vittata are on the order of decades. In addition, most research on As phytoextraction with P. vittata has examined As removal from sandy soils, where As is more available, with little research focusing on As removal from clayey soils, where As is less available. The objective of this study is to determine the effects of soil texture and soil fertilization on As extraction by P. vittata, to optimize remediation efficiency and decrease remediation time under complex field conditions. A field study was established 2.5 years ago in an abandoned railroad grade contaminated with As (average 85.5 mg kg-1) with texture varying from sandy loam to silty clay loam. Organic N, inorganic N, organic P, inorganic P, and compost were applied to separate sub-plots; control ferns were grown in untreated soil. In a parallel greenhouse experiment, ferns were grown in sandy loam soil extracted from the field (180 mg As kg-1), with similar treatments as those used at the field site, plus a high phosphate treatment and treatments with arbuscular mycorrhizal fungi. In the field study, fern mortality was 24% higher in clayey soil than in sandy soil due to waterlogging, while As was primarily associated with sandy soil. Results from the sandy loam soil indicate that soil treatments did not significantly increase As phytoextraction, which was lower in phosphate-treated ferns than in control ferns, both in the field and greenhouse study. Under greenhouse conditions, ferns treated with organic N were

  4. Enhanced degradation of metalaxyl in agricultural soils of São Paulo State, Brazil

    Directory of Open Access Journals (Sweden)

    Papini Solange

    2001-01-01

    Full Text Available This work investigated the effect of repeated applications on enhanced degradation of metalaxyl in two different agricultural soils used for cultivation of orange and lemon from Casa Branca and Itapetininga districts of São Paulo State, Brazil. Soil samples were collected from areas repeatedly treated with commercial ridomil 50GR for six successive years, and from other areas never exposed to this fungicide. At the laboratory, soil samples received a 14C-metalaxyl solution and its degradation was studied through radiometric techniques to measure biomineralization and recovery of extractable- and soil-bound products. Enhanced degradation was verified only in one soil, although partial degradation and mineralization of the fungicide were detected in both soils. The different rates and patterns of metalaxyl degradation in the soils were probably due to their different physical, chemical, and biological characteristics.

  5. Soil degradation level under particular annual rainfall at Jenawi District– Karanganyar, Indonesia

    Science.gov (United States)

    Herawati, A.; Suntoro; Widijanto, H.; Pusponegoro, I.; Sutopo, N. R.; Mujiyo

    2018-03-01

    The study of the climatic elements such as rainfall is vital for the sustainable development of agriculture at a region. The aims of the study were to evaluate the soil degradation based on the annual rainfall and to determine the key factors which responsible for the soil degradation at in Jenawi Sub-District. The mapping of soil degradation potency is an identification of initial soil condition to discover the potential of the land degradation. The mapping was done by overlaying the map of soil, slope, rainfall and land use with the standard procedures to obtain the value and status of Soil Degradation Potency (SDP). The result showed that SDP in Jenawi District categorized in very low (SDP I) 0.00 ha (0.00%); low (SDP II) 109.01 ha (2.57%); moderate (SDP III) 1,935.92 ha (45.63%); high (SDP IV) 1,959.54 ha (46.19%) and very high (SDP V) 238.08 ha (5.61%). The rainfall is the factor which has the strong correlation with the SDP (r = 0.65, P local soil-land characteristics.

  6. Methodical comparison of neutron depth probes and long-term soil moisture measurements on loess, sandy loess, and boulder clay

    International Nuclear Information System (INIS)

    Neue, H.U.

    1980-01-01

    Three measuring instruments were tested: 0.05 mCi Cf-252, 100 mCi Am-241/Be, 500 mCi Am-241/Be. The advantages - measurement in undisturbed soil profiles, large depths of measurement, reproducibility of measurements in the same place over several years - and the disadvantages - radiation protection, resolution, variations of measured volume in dependence of moisture, background influences etc. - have been critically checked by experiment. In addition, annual soil moisture curves have been measured over two years by parallel use of the free probes on a loess, sandy loess, and boulder clay site. The results were compared and discussed with a view to the soil water dynamics of these sites. (orig./HP) [de

  7. Effect of fertilizer and irradiation sterilization on the degradation of lindane in soil

    International Nuclear Information System (INIS)

    Bennaceur, M.; Ghezal, F.

    1992-10-01

    The effect of fertilizer and sterelization using irradiation were studied on the fate of lindane degradation in two soils under laboratory conditions. Degradation of lindane is higher in organic matter rich soil. Half life of product is respectively about one week and one month for both rich soil and poor soil. Fertilizer used decreases PH of soils and irradiation dose of 1 mrad seems to be insufficient to sterilize completely the soils. Ammonium nitrate stimulates slightly the degradations of lindane in soil (not sterilized) after two months

  8. Aeolian sediment mass fluxes on a sandy soil in Central Patagonia

    NARCIS (Netherlands)

    Sterk, G.; Parigiani, J.; Cittadini, E.; Peters, P.; Scholberg, J.; Peri, P.

    2012-01-01

    The climate of Patagonia is semi-arid and characterised by frequent strong winds. Wind erosion is potentially a serious soil degradation process that impacts long-term sustainability of local agricultural systems, but the conditions and the rates of wind erosion in this region have not been

  9. Distribution, typology and assessment of degraded soils Piedmont Plains Zhetysu Ridge, Kazakhstan

    Directory of Open Access Journals (Sweden)

    Maira Kussainova

    2017-04-01

    Full Text Available Identification of land degradation is essential to check the problem and to implement the remedial measures needed. The study area falls under parts of foothill plains Zhetysu Ridge, Kazakhstan, that is an arid region in climate. Recent data on the status of study area refer to the 80s of the last century, and the intensive use of them led to a significant anthropogenic transformation. This study was carried out in 2015-2016 as part of a project aimed to study features and causes of land degradation in foothill plains Zhetysu Ridge, Kazakhstan. Under the conditions of rainfed soil degradation manifests itself in the development of erosion processes, agro depletion of soils, reducing the productivity of agriculture. The use of land for irrigation often accompanied by secondary salinization. In this regard, at present there is need to assess current state of the soil, with the identification of changes in their properties as a result of the impact of various anthropogenic factors and creation of new electronic soil maps and applied the powerful capabilities of advanced remote sensing (RS and geographic information system (GIS techniques to identify the geomorphological units and degradation risk assessment. Satellite imagery in addition to the field and laboratory studies to identify salinity-induced soil degradation was adopted in this study. Morphological, chemical and physical characteristics of soils in degraded sites in foothill plains Zhetysu Ridge, Kazakhstan, were depicted. The main results of a thorough evaluation of soil degradation in foothill plains Zhetysu Ridge, Kazakhstan, are presented. The data revealed that extent of salinity-induced degradation was generally related to some physical properties of soil, uncontrolled livestock grazing and previous soil management practices. These results are useful as the basis for designing soil conservation and restoration programs, as a base line for evaluating the performance of conservation

  10. Organic contaminants in soil : desorption kinetics and microbial degradation

    NARCIS (Netherlands)

    Schlebaum, W.

    1999-01-01

    The availability of organic contaminants in soils or sediments for microbial degradation or removal by physical means (e.g.) soil washing or soil venting) depends on the desorption kinetics of these contaminants from the soil matrix. When the organic contaminants desorb very slow from the

  11. Wind Erosion Induced Soil Degradation in Northern China: Status, Measures and Perspective

    Directory of Open Access Journals (Sweden)

    Zhongling Guo

    2014-12-01

    Full Text Available Soil degradation is one of the most serious ecological problems in the world. In arid and semi-arid northern China, soil degradation predominantly arises from wind erosion. Trends in soil degradation caused by wind erosion in northern China frequently change with human activities and climatic change. To decrease soil loss by wind erosion and enhance local ecosystems, the Chinese government has been encouraging residents to reduce wind-induced soil degradation through a series of national policies and several ecological projects, such as the Natural Forest Protection Program, the National Action Program to Combat Desertification, the “Three Norths” Shelter Forest System, the Beijing-Tianjin Sand Source Control Engineering Project, and the Grain for Green Project. All these were implemented a number of decades ago, and have thus created many land management practices and control techniques across different landscapes. These measures include conservation tillage, windbreak networks, checkerboard barriers, the Non-Watering and Tube-Protecting Planting Technique, afforestation, grassland enclosures, etc. As a result, the aeolian degradation of land has been controlled in many regions of arid and semiarid northern China. However, the challenge of mitigating and further reversing soil degradation caused by wind erosion still remains.

  12. Sorption, desorption and mineralisation of the herbicides glyphosate and MCPA in samples from two Danish soil and subsurface profiles

    International Nuclear Information System (INIS)

    Sorensen, Sebastian R.; Schultz, Anne; Jacobsen, Ole S.; Aamand, Jens

    2006-01-01

    The vertical distribution of the sorption, desorption and mineralisation of glyphosate and MCPA was examined in samples from two contrasting soil and subsurface profiles, obtained from a sandy agricultural site and a non-agricultural clay rich site. The highest mineralisation of [ 14 C-methylen]glyphosate, with 9.3-14.7% degraded to 14 CO 2 within 3 months was found in the deepest sample from the clay site. In the deeper parts of the sandy profile high sorption and low desorption of glyphosate coincided with no or minor mineralisation indicating a limited glyphosate bioavailability. MCPA was readily mineralised except in the deepest samples from both sites. The highest MCPA mineralisation was detected just below the surface layers with 72% or 44% degraded to 14 CO 2 at the sandy or the clay sites, respectively. MCPA sorped to a minor extent in all samples and no indications of sorption-controlled mineralisation was revealed. None of the herbicides were mineralised under anoxic conditions. - Natural attenuation potential of the herbicides glyphosate and MCPA was assessed in soil and subsurface profiles

  13. Sorption, desorption and mineralisation of the herbicides glyphosate and MCPA in samples from two Danish soil and subsurface profiles

    Energy Technology Data Exchange (ETDEWEB)

    Sorensen, Sebastian R. [Department of Geochemistry, Geological Survey of Denmark and Greenland (GEUS), Oster Voldgade 10, DK-1350 Copenhagen K (Denmark)]. E-mail: srs@geus.dk; Schultz, Anne [Department of Geochemistry, Geological Survey of Denmark and Greenland (GEUS), Oster Voldgade 10, DK-1350 Copenhagen K (Denmark); Jacobsen, Ole S. [Department of Geochemistry, Geological Survey of Denmark and Greenland (GEUS), Oster Voldgade 10, DK-1350 Copenhagen K (Denmark); Aamand, Jens [Department of Geochemistry, Geological Survey of Denmark and Greenland (GEUS), Oster Voldgade 10, DK-1350 Copenhagen K (Denmark)

    2006-05-15

    The vertical distribution of the sorption, desorption and mineralisation of glyphosate and MCPA was examined in samples from two contrasting soil and subsurface profiles, obtained from a sandy agricultural site and a non-agricultural clay rich site. The highest mineralisation of [{sup 14}C-methylen]glyphosate, with 9.3-14.7% degraded to {sup 14}CO{sub 2} within 3 months was found in the deepest sample from the clay site. In the deeper parts of the sandy profile high sorption and low desorption of glyphosate coincided with no or minor mineralisation indicating a limited glyphosate bioavailability. MCPA was readily mineralised except in the deepest samples from both sites. The highest MCPA mineralisation was detected just below the surface layers with 72% or 44% degraded to {sup 14}CO{sub 2} at the sandy or the clay sites, respectively. MCPA sorped to a minor extent in all samples and no indications of sorption-controlled mineralisation was revealed. None of the herbicides were mineralised under anoxic conditions. - Natural attenuation potential of the herbicides glyphosate and MCPA was assessed in soil and subsurface profiles.

  14. Assessment of land degradation using time series trend analysis of vegetation indictors in Otindag Sandy land

    International Nuclear Information System (INIS)

    Wang, H Y; Li, Z Y; Gao, Z H; Wu, J J; Sun, B; Li, C L

    2014-01-01

    Land condition assessment is a basic prerequisite for finding the degradation of a territory, which might lead to desertification under climatic and human pressures. The temporal change in vegetation productivity is a key indicator of land degradation. In this paper, taking the Otindag Sandy Land as a case, the mean normalized difference vegetation index (NDVI a ), net primary production (NPP) and vegetation rain use efficiency (RUE) dynamic trends during 2001–2010 were analysed. The Mann-Kendall test and the Correlation Analysis method were used and their sensitivities to land degradation were evaluated. The results showed that the three vegetation indicators (NDVI a , NPP and RUE) showed a downward trend with the two methods in the past 10 years and the land was degraded. For the analysis of the three vegetation indicators (NDVI a , NPP and RUE), it indicated a decreasing trend in 62.57%, 74.16% and 88.56% of the study area according to the Mann-Kendall test and in 57.85%, 68.38% and 85.29% according to the correlation analysis method. However, the change trends were not significant, the significant trends at the 95% confidence level only accounted for a small proportion. Analysis of NDVI a , NPP and RUE series showed a significant decreasing trend in 9.21%, 4.81% and 6.51% with the Mann-Kendall test. The NPP change trends showed obvious positive link with the precipitation in the study area. While the effect of the inter-annual variation of the precipitation for RUE was small, the vegetation RUE can provide valuable insights into the status of land condition and had best sensitivity to land degradation

  15. Occurrence and distribution of polycyclic aromatic hydrocarbons in organo-mineral particles of alluvial sandy soil profiles at a petroleum-contaminated site

    International Nuclear Information System (INIS)

    Lu, Zhe; Zeng, Fangang; Xue, Nandong; Li, Fasheng

    2012-01-01

    The occurrence and the distribution of 16 USEPA priority pollutants polycyclic aromatic hydrocarbons (PAHs) were investigated in two alluvial sandy soil profiles and in their four sizes of organo-mineral particles ( 200 μm coarse sand) beside a typical oil sludge storage site in eastern China. PAHs were mainly enriched in the surface soil (0–20 cm) and the concentrations declined in deeper soils, from 3.68 to 0.128 μg/g in profile 1 and 10.8 to 0.143 μg/g in profile 2 (dry wt.). The PAHs in the upper soil layers of this study site mainly came from combustion pollution, whereas in the lower soil layers petroleum contamination became the major source of PAHs. The content of different sized organo-mineral particles of this alluvial sandy soil decreased in the following order: fine sand > coarse sand > silt > clay. X-ray diffraction (XRD) results showed that all the different sized soil fractions of this study site were dominated by quartz, calcite and feldspar. The particle surface became smoother with size increasing as shown by scanning electron microscope (SEM) images. PAH concentrations varied largely in different sized soil fractions. The highest PAH concentration was associated with clay and decreased in the order: clay > silt > coarse sand > fine sand. Soil organic matter (SOM) content, mineral composition and particle surface characteristics were suggested as three main factors affecting the distribution of PAHs in different sized organo-mineral particles. This study will help to understand the distribution and transport characteristics of PAHs in soil profiles at petroleum-contaminated sites. -- Highlights: ► PAH concentrations varied largely in different sized fractions. ► The highest PAH concentrations were associated with clay and decreased in the order: clay > silt > coarse sand > fine sand. ► Soil organic matter (SOM) is an important factor to dominate the distribution of PAHs in this study site.

  16. Occurrence and distribution of polycyclic aromatic hydrocarbons in organo-mineral particles of alluvial sandy soil profiles at a petroleum-contaminated site

    Energy Technology Data Exchange (ETDEWEB)

    Lu, Zhe [State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Anwai, Dayangfang 8, Beijing 100012 (China); Department of Chemistry, University of Manitoba, Winnipeg, Manitoba, Canada R3T 2N2 (Canada); School of Environment, Renmin University of China, Zhongguancun Street 59, Beijing 100872 (China); Zeng, Fangang [School of Environment, Renmin University of China, Zhongguancun Street 59, Beijing 100872 (China); Xue, Nandong [State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Anwai, Dayangfang 8, Beijing 100012 (China); Li, Fasheng, E-mail: ligulax@vip.sina.com [State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Anwai, Dayangfang 8, Beijing 100012 (China)

    2012-09-01

    The occurrence and the distribution of 16 USEPA priority pollutants polycyclic aromatic hydrocarbons (PAHs) were investigated in two alluvial sandy soil profiles and in their four sizes of organo-mineral particles (< 2 {mu}m clay, 2-20 {mu}m silt, 20-200 {mu}m fine sand, and > 200 {mu}m coarse sand) beside a typical oil sludge storage site in eastern China. PAHs were mainly enriched in the surface soil (0-20 cm) and the concentrations declined in deeper soils, from 3.68 to 0.128 {mu}g/g in profile 1 and 10.8 to 0.143 {mu}g/g in profile 2 (dry wt.). The PAHs in the upper soil layers of this study site mainly came from combustion pollution, whereas in the lower soil layers petroleum contamination became the major source of PAHs. The content of different sized organo-mineral particles of this alluvial sandy soil decreased in the following order: fine sand > coarse sand > silt > clay. X-ray diffraction (XRD) results showed that all the different sized soil fractions of this study site were dominated by quartz, calcite and feldspar. The particle surface became smoother with size increasing as shown by scanning electron microscope (SEM) images. PAH concentrations varied largely in different sized soil fractions. The highest PAH concentration was associated with clay and decreased in the order: clay > silt > coarse sand > fine sand. Soil organic matter (SOM) content, mineral composition and particle surface characteristics were suggested as three main factors affecting the distribution of PAHs in different sized organo-mineral particles. This study will help to understand the distribution and transport characteristics of PAHs in soil profiles at petroleum-contaminated sites. -- Highlights: Black-Right-Pointing-Pointer PAH concentrations varied largely in different sized fractions. Black-Right-Pointing-Pointer The highest PAH concentrations were associated with clay and decreased in the order: clay > silt > coarse sand > fine sand. Black-Right-Pointing-Pointer Soil organic

  17. Adsorption and degradation of five selected antibiotics in agricultural soil.

    Science.gov (United States)

    Pan, Min; Chu, L M

    2016-03-01

    Large quantities of antibiotics are being added to agricultural fields worldwide through the application of wastewater, manures and biosolids, resulting in antibiotic contamination and elevated environmental risks in terrestrial environments. Most studies on the environmental fate of antibiotics focus on aquatic environments or wastewater treatment plants. Little is known about the behavior of antibiotics at environmentally relevant concentrations in agricultural soil. In this study we evaluated the adsorption and degradation of five different antibiotics (tetracycline, sulfamethazine, norfloxacin, erythromycin, and chloramphenicol) in sterilized and non-sterilized agricultural soils under aerobic and anaerobic conditions. Adsorption was highest for tetracycline (Kd, 1093 L/kg), while that for sulfamethazine was negligible (Kd, 1.365 L/kg). All five antibiotics were susceptible to microbial degradation under aerobic conditions, with half-lives ranging from 2.9 to 43.3 d in non-sterilized soil and 40.8 to 86.6 d in sterilized soil. Degradation occurred at a higher rate under aerobic conditions but was relatively persistent under anaerobic conditions. For all the antibiotics, a higher initial concentration was found to slow down degradation and prolong persistence in soil. The degradation behavior of the antibiotics varied in relation to their physicochemical properties as well as the microbial activities and aeration of the recipient soil. The poor adsorption and relative persistence of sulfamethazine under both aerobic and anaerobic conditions suggest that it may pose a higher risk to groundwater quality. An equation was proposed to predict the fate of antibiotics in soil under different field conditions, and assess their risks to the environment. Copyright © 2015 Elsevier B.V. All rights reserved.

  18. A review of the impacts of degradation threats on soil properties in the UK.

    Science.gov (United States)

    Gregory, A S; Ritz, K; McGrath, S P; Quinton, J N; Goulding, K W T; Jones, R J A; Harris, J A; Bol, R; Wallace, P; Pilgrim, E S; Whitmore, A P

    2015-10-01

    National governments are becoming increasingly aware of the importance of their soil resources and are shaping strategies accordingly. Implicit in any such strategy is that degradation threats and their potential effect on important soil properties and functions are defined and understood. In this paper, we aimed to review the principal degradation threats on important soil properties in the UK, seeking quantitative data where possible. Soil erosion results in the removal of important topsoil and, with it, nutrients, C and porosity. A decline in soil organic matter principally affects soil biological and microbiological properties, but also impacts on soil physical properties because of the link with soil structure. Soil contamination affects soil chemical properties, affecting nutrient availability and degrading microbial properties, whilst soil compaction degrades the soil pore network. Soil sealing removes the link between the soil and most of the 'spheres', significantly affecting hydrological and microbial functions, and soils on re-developed brownfield sites are typically degraded in most soil properties. Having synthesized the literature on the impact on soil properties, we discuss potential subsequent impacts on the important soil functions, including food and fibre production, storage of water and C, support for biodiversity, and protection of cultural and archaeological heritage. Looking forward, we suggest a twin approach of field-based monitoring supported by controlled laboratory experimentation to improve our mechanistic understanding of soils. This would enable us to better predict future impacts of degradation processes, including climate change, on soil properties and functions so that we may manage soil resources sustainably.

  19. MAPPING OF SOIL DEGRADATION POTENCY IN PADDY FIELD WONOGIRI, INDONESIA

    Directory of Open Access Journals (Sweden)

    Mujiyo

    2016-06-01

    Full Text Available Sustainability of paddy field becomes the main concern as the media of biomass production, thus it is needed a datum and information about land characteristics to find out its degradation. Mapping of soil degradation potency in paddy field is an identification of initial soil condition to discover the land degradation potency. Mapping was done by overlaying map of soil, slope, rainfall and land use with standard procedures to obtain its value and status of soil degradation potency. Area mapping is an effective land for biomass production (natural forest, mixed farm, savanna, paddy field, shrub and dry field with approximately 43,291.00 hectares (ha in Sidoharjo, Girimarto, Jatipurno, Jatisrono, Jatiroto, Tirtomoyo, Nguntoronadi and Ngadirojo District. The result shows that soil degradation potency (SDP in Districts of Sidoharjo, Girimarto, Jatipurno, Jatisrono, Jatiroto, Tirtomoyo, Nguntoronadi and Ngadirojo are very low, low (DP II 20,702.47 ha (47.82%, moderate (DP III 15,823.80 ha (36,55% and high (DP IV 6,764.73 ha (15.63%. Paddy field covered 22,036.26 ha or about 50.90% of all area as effective biomass production, its SDP considers as low (DP II 16,021.04 ha (37.01% and moderate (DP III 6,015.22 ha (13,89%. Paddy field has a low SDP because it is commonly lies on flat area and conservation method by the farmer is maintaining the paddy bund and terrace. This study needs an advanced study to identify actual SDP through detail verification in the field, and also support by soil sample analysis in the laboratory.

  20. Evaluation of the potential of pentachlorophenol degradation in soil by pulsed corona discharge plasma from soil characteristics.

    Science.gov (United States)

    Wang, Tie Cheng; Lu, Na; Li, Jie; Wu, Yan

    2010-04-15

    Chlorinated organics are frequently found as harmful soil contaminants and persisted for extended periods of time. A novel approach, named pulsed corona discharge plasma (PCDP), was employed for the degradation of pentachlorophenol (PCP) in soil. Experimental results showed that 87% of PCP could be smoothly removed in 60 min. Increasing pulse voltage, enhancing soil pH, lowering humic acid (HA) in soil and reducing granular size of the soil were found to be favorable for PCP degradation efficiency. Oxidation and physical processes simultaneously contributed to PCP removal in soil and ozone was the main factor in PCDP treatment. C-Cl bonds in PCP were cleaved during PCDP treatment by Fourier transform infrared spectroscopy (FTIR) analysis. The mineralization of PCP was confirmed by total organic carbon (TOC) and dechlorination analyses. The main intermediate products such as tetrachlorocatechol, tetrachlorohydroquinone, acetic acid, formic acid, and oxalic acid were identified by HPLC/MS and ion chromatography. A possible pathway of PCP degradation in soil in such a system was proposed.

  1. Heavy metals in a degraded soil treated with sludge from water treatment plant

    Directory of Open Access Journals (Sweden)

    Teixeira Sandra Tereza

    2005-01-01

    Full Text Available The application of water treatment sludge (WTS to degraded soil is an alternative for both residue disposal and degraded soil reclaim. This study evaluated effects of the application of water treatment sludge to a Typic Hapludox soil degraded by tin mining in the National Forest of Jamari, State of Rondonia, Brazil, on the content of heavy metals. A completely randomized experimental design with five treatments was used: control (n = 4; chemical control, which received only liming (n = 4; and rates D100, D150 and D200, which corresponded to 100, 150 and 200 mg of N-sludge kg-1 soil (n = 20, respectively. Thirty days after liming, period in which soil moisture was kept at 70% of the retention capacity, soil samples were taken and analyzed for total and extractable Fe, Cu, Mn, Zn, Cd, Pb, Ni, and Cr. The application of WTS increased heavy-metal contents in the degraded soil. Although heavy metals were below their respective critical limits, sludge application onto degraded areas may cause hazardous environmental impact and thus must be monitored.

  2. Identification of soil bacteria able to degrade phenanthrene bound to a hydrophobic sorbent in situ

    Energy Technology Data Exchange (ETDEWEB)

    Regonne, Raïssa Kom [CEA, DSV/iRTSV, Chimie et Biologie des Métaux, 38054, Grenoble cedex 9 (France); Univ. Grenoble Alpes and CNRS, UMR 5249, 38042, Grenoble (France); Laboratoire de Substances Actives et Pollution, ENSAI, Université de Ngaoundéré, BP 455, Ngaoundéré (Cameroon); Martin, Florence [CEA, DSV/iRTSV, Chimie et Biologie des Métaux, 38054, Grenoble cedex 9 (France); Univ. Grenoble Alpes and CNRS, UMR 5249, 38042, Grenoble (France); Mbawala, Augustin [Laboratoire de Microbiologie, ENSAI, Université de Ngaoundéré, BP 455, Ngaoundéré (Cameroon); Ngassoum, Martin Benoît [Laboratoire de Substances Actives et Pollution, ENSAI, Université de Ngaoundéré, BP 455, Ngaoundéré (Cameroon); Jouanneau, Yves [CEA, DSV/iRTSV, Chimie et Biologie des Métaux, 38054, Grenoble cedex 9 (France); Univ. Grenoble Alpes and CNRS, UMR 5249, 38042, Grenoble (France)

    2013-09-15

    Efficient bioremediation of PAH-contaminated sites is limited by the hydrophobic character and poor bioavailability of pollutants. In this study, stable isotope probing (SIP) was implemented to track bacteria that can degrade PAHs adsorbed on hydrophobic sorbents. Temperate and tropical soils were incubated with {sup 13}C-labeled phenanthrene, supplied by spiking or coated onto membranes. Phenanthrene mineralization was faster in microcosms with PAH-coated membranes than in microcosms containing spiked soil. Upon incubation with temperate soil, phenanthrene degraders found in the biofilms that formed on coated membranes were mainly identified as Sphingomonadaceae and Actinobacteria. In the tropical soil, uncultured Rhodocyclaceae dominated degraders bound to membranes. Accordingly, ring-hydroxylating dioxygenase sequences recovered from this soil matched PAH-specific dioxygenase genes recently found in Rhodocyclaceae. Hence, our SIP approach allowed the detection of novel degraders, mostly uncultured, which differ from those detected after soil spiking, but might play a key role in the bioremediation of PAH-polluted soils. -- Highlights: •Soil bacteria with the ability to degrade sorbent-bound PAHs were investigated. •In soil, membrane-bound phenanthrene was readily mineralized. •PAH degraders found in biofilms were different in temperate and tropical soils. •Uncultured Rhodocyclaceae were dominant phenanthrene degraders in the tropical soil. •PAH-specific ring-hydroxylating dioxygenase sequences were identified in soil DNA. -- Bacteria able to degrade PAHs bound to a hydrophobic sorbent were mainly identified as uncultured Rhodocyclaceae and Sphingomonadaceae in polluted soils from tropical and temperate area, respectively.

  3. Identification of soil bacteria able to degrade phenanthrene bound to a hydrophobic sorbent in situ

    International Nuclear Information System (INIS)

    Regonne, Raïssa Kom; Martin, Florence; Mbawala, Augustin; Ngassoum, Martin Benoît; Jouanneau, Yves

    2013-01-01

    Efficient bioremediation of PAH-contaminated sites is limited by the hydrophobic character and poor bioavailability of pollutants. In this study, stable isotope probing (SIP) was implemented to track bacteria that can degrade PAHs adsorbed on hydrophobic sorbents. Temperate and tropical soils were incubated with 13 C-labeled phenanthrene, supplied by spiking or coated onto membranes. Phenanthrene mineralization was faster in microcosms with PAH-coated membranes than in microcosms containing spiked soil. Upon incubation with temperate soil, phenanthrene degraders found in the biofilms that formed on coated membranes were mainly identified as Sphingomonadaceae and Actinobacteria. In the tropical soil, uncultured Rhodocyclaceae dominated degraders bound to membranes. Accordingly, ring-hydroxylating dioxygenase sequences recovered from this soil matched PAH-specific dioxygenase genes recently found in Rhodocyclaceae. Hence, our SIP approach allowed the detection of novel degraders, mostly uncultured, which differ from those detected after soil spiking, but might play a key role in the bioremediation of PAH-polluted soils. -- Highlights: •Soil bacteria with the ability to degrade sorbent-bound PAHs were investigated. •In soil, membrane-bound phenanthrene was readily mineralized. •PAH degraders found in biofilms were different in temperate and tropical soils. •Uncultured Rhodocyclaceae were dominant phenanthrene degraders in the tropical soil. •PAH-specific ring-hydroxylating dioxygenase sequences were identified in soil DNA. -- Bacteria able to degrade PAHs bound to a hydrophobic sorbent were mainly identified as uncultured Rhodocyclaceae and Sphingomonadaceae in polluted soils from tropical and temperate area, respectively

  4. A study on the aseismic safety of the experimental VHTR on the dense sandy layer

    International Nuclear Information System (INIS)

    Fujita, Shigeki; Ito, Yoshio; Baba, Osamu; Suzuki, Hideyuki; Takewaki, Naonobu; Kondo, Tsukasa; Yoshimura, Takashi; Yamada, Hitoshi.

    1986-12-01

    A series of studies has been carried out in 1983 and 1985 for the purpose of confirming the aseismic safety of the Experimental VHTR on the dense sandy layer. In 1983, effect of some of soil properties on seismic responses of the reactor building was estimated by means of parametric survey, and soil properties were estimated by analyzing the obserbed earthquake record. In 1985, literature review, linear, nonlinear parametric analyses and nonlinear simulation analyses were carried to study and compare the analysis method. In addition, seismic response of proposed construction site was estimated with nonlinear analysis method. As a result of these studies, the seismic response of reactor building on the dense sandy layers and wave propagation characteristics of sandy layers are understood. Especially, by means of many parametric studies, the effect of input wave characteristics, soil stiffness, nonlinear characteristics of soil properties and nonlinear analysis method on the reactor building responses were evaluated. (author)

  5. Degradation and adsorption of tralkoxydim in Chinese soils and water-sediment environments.

    Science.gov (United States)

    Wu, Wen Zhu; Shan, Zheng Jun; Kong, De Yang; He, Jian

    2017-06-01

    Tralkoxydim is a cyclohexanedione herbicide primarily used for gramineous weed control in China. In this paper, we present results of a tralkoxydim laboratory environmental fate study characterizing its degradation, adsorption, and mobility behavior in three different soils and two water-sediment systems (river and lake) in China. Degradation half-life of tralkoxydim in soil under aerobic conditions was 5.1, 7.7, and 7.9 days in Jiangxi red soil, Taihu paddy soil, and Northeast China black soil, respectively. Under anaerobic and flooding conditions, half-life values were 6.2, 15.1, and 19.8 days for the same three soils, respectively. Soil pH was the major factor effecting tralkoxydim degradation. In the aerobic water-sediment experiments, tralkoxydim degraded faster in the river system (total system half-life 43.3 days) than the lake system (total system half-life 99.0 days). Correspondingly, its anaerobic degradation half-life values were 46.2 and 53.3 days for the river and lake systems, respectively. Tralkoxydim adsorption in the three soils was found to follow the empirical Freundlich isotherm. The adsorption coefficient (K d ) was 8.60, 1.00, and 1.57 for Jiangxi red soil, Taihu paddy soil, and Northeast China black soil, respectively. Soil pH was the major factor effecting tralkoxydim adsorption. Adsorption free energy change was less than 40 kJ mol -1 in all three soils, indicating a physical mechanism in the process. Thin-layer chromatography (TLC) tests showed that relative to the solvent transport to 11.5 cm, the travel distance of tralkoxydim was 8-10 cm in the three soils, corresponding Rf values at 0.05, 0.35, and 0.75 for Jiangxi red soil, Taihu paddy soil, and Northeast China black soil, respectively. Results of this work suggest that under alkaline conditions, tralkoxydim adsorption becomes smaller; thus, assessments on its mobility and potential groundwater impact should focus on these soil types.

  6. Depth distribution of preferential flow patterns in a sandy loam soil as affected by tillage

    Directory of Open Access Journals (Sweden)

    C. T. Petersen

    1997-01-01

    Full Text Available Dye-tracer studies using the anionic dye Brilliant Blue FCF were conducted on a structured sandy loam soil (Typic Agrudalf. 25 mm of dye solution was applied to the surface of 11 1.6 x 1.6 m field plots, some of which had been subjected to conventional seed bed preparation (harrowing while others had been rotovated to either 5 or 15 cm depth before sowing. The soil was excavated to about 160 cm depth one or two days after dye application. Flow patterns and structural features appearing on vertical or horizontal cross sections were examined and photographed. The flow patterns were digitized, and depth functions for the number of activated flow pathways and the degree of dye coverage were calculated. Dye was found below 100 cm depth on 26 out of 33 vertical cross sections made in conventionally tilled plots showing that preferential flow was a prevailing phenomenon. The depth-averaged number of stained flow pathways in the 25-100 cm layer was significantly smaller in a plot rotovated to 5 cm depth than in a conventionally tilled plot, both under relatively dry initial soil conditions and when the entire soil profiles were initially at field capacity. There were no examples of dye penetration below 25 cm depth one month after deep rotovation. Distinct horizontal structures in flow patterns appearing at 20-40 cm depth coupled with changes in flow domains indicated soil layering with abrupt changes in soil structure and hydraulic properties.

  7. HPLC Analysis to Determine the Half-life and Bioavailability of the Termiticides Bifenthrin and Fipronil in Soil.

    Science.gov (United States)

    Manzoor, F; Pervez, M

    2017-12-05

    The aim of this study was to test the bioavailability and degradation in soil of the termiticides bifenthrin and fipronil, which are used to treat subterranean termites (Heterotermes indicola, Wasmann). Soil collected from different areas of Lahore was categorized as sandy clay loam (SCL) or sandy loam (SL). Laboratory bioassays were conducted to determine the bioavailability ratio of bifenthrin and fipronil in each type of soil after different periods of time. LT50 values were determined posttreatment at different time intervals. Regarding soil type, both termiticides were more effective in SL soil, compared with SCL soil posttreatment. There were significant differences in termite mortality in treated compared with untreated control samples (P bifenthrin (maximum, 1,002 and 1,262 d in SCL soil and SL soil, respectively) indicated that it persisted in both soil types at all concentrations. The maximum calculated half-life values of fipronil were 270 and 555 d in SCL and SL soil, respectively. At lower concentrations and over longer periods of time, fipronil completely degraded in SL soil, while a negligible amount was detected in SCL soil. Termiticide concentration decreased over time, as did the termiticide recovery rate. Overall, bifenthrin was more persistent than fipronil under all treatment conditions tested. © The Author(s) 2017. Published by Oxford University Press on behalf of Entomological Society of America. All rights reserved. For permissions, please e-mail: journals.permissions@oup.com.

  8. BioDegradation of Refined Petroleum Hydrocarbons in Soil | Obire ...

    African Journals Online (AJOL)

    Carbon-dioxide production and hydrocarbon degradation of refined petroleum hydrocarbon in soils treated with 5% gasoline, kerosene and diesel oil were investigated. Soil for study was bulked from around a car park in Port Harcourt. Soil samples were collected at weekly intervals for four weeks and subsequently at ...

  9. A method to detect soil carbon degradation during soil erosion

    OpenAIRE

    F. Conen; M. Schaub; C. Alewell

    2009-01-01

    Soil erosion has been discussed intensively but controversial both as a significant source or a significant sink of atmospheric carbon possibly explaining the gap in the global carbon budget. One of the major points of discussion has been whether or not carbon is degraded and mineralized to CO2 during detachment, transport and deposition of soil material. By combining the caesium-137 (137Cs) approach (quantification of erosion rates) with stable c...

  10. Characterization of acetanilide herbicides degrading bacteria isolated from tea garden soil.

    Science.gov (United States)

    Wang, Yei-Shung; Liu, Jian-Chang; Chen, Wen-Ching; Yen, Jui-Hung

    2008-04-01

    Three different green manures were added to the tea garden soils separately and incubated for 40 days. After, incubation, acetanilide herbicides alachlor and metolachlor were spiked into the soils, separately, followed by the isolation of bacteria in each soil at designed intervals. Several bacterial strains were isolated from the soils and identified as Bacillus silvestris, B. niacini, B. pseudomycoides, B. cereus, B. thuringiensis, B. simplex, B. megaterium, and two other Bacillus sp. (Met1 and Met2). Three unique strains with different morphologies were chosen for further investigation. They were B. megaterium, B. niacini, and B. silvestris. The isolated herbicide-degrading bacteria showed optimal performance among three incubation temperatures of 30 degrees C and the best activity in the 10 to 50 microg/ml concentration of the herbicide. Each bacterial strain was able to degrade more than one kind of test herbicides. After incubation for 119 days, B. cereus showed the highest activity to degrade alachlor and propachlor, and B. thuringiensis to degrade metolachlor.

  11. Methane oxidation and degradation of organic compounds in landfill soil covers

    DEFF Research Database (Denmark)

    Scheutz, Charlotte; Kjeldsen, Peter

    2002-01-01

    High rates of methane oxidation and degradation of the lowed halogenated methanes (TCM and DCM) and HCFCs (HCFC-21 and HCFC-22) were found in an investigation of the oxidation of methane and halogenated organic compunds (HOCs) in landfill gas affected soil. The degradation followed zero-order kin......High rates of methane oxidation and degradation of the lowed halogenated methanes (TCM and DCM) and HCFCs (HCFC-21 and HCFC-22) were found in an investigation of the oxidation of methane and halogenated organic compunds (HOCs) in landfill gas affected soil. The degradation followed zero...

  12. Thermomechanical Behavior of Energy Pile Embedded in Sandy Soil

    Directory of Open Access Journals (Sweden)

    Xu Huang

    2018-01-01

    Full Text Available The traditional energy pile (solid energy pile has been implemented for decades. However, the design of different kinds of energy piles is still not well understood. In this study, a series of model tests were performed on an aluminum pipe energy pile (PEP in dry sandy soil to investigate the thermal effects on the mechanical behaviors of pipe energy pile. The thermal responses of the PEP were also analyzed. Steady temperatures of the PEP under different working conditions were also compared with that of the solid energy pile. Different loading tests were carried out on four pipe energy piles under three different temperatures of 5, 35, and 50°C, respectively. The bearing capacity change can be interpreted through the load-displacement curves. Experiment results were also compared with the solid energy pile to evaluate bearing capacities of the PEP and the solid energy pile under different temperature conditions. The mobilized shaft resistance was also calculated and compared with the solid energy pile data and the results show that the PEP has a similar load transfer mechanism with the solid energy pile. It could also be found that, for PEPs under working load, plastic displacement would appear after a whole heating cycle.

  13. Effect of molarity in geo polymer earth brick reinforced with fibrous coir wastes using sandy soil and quarry dust as fine aggregate. (Case study

    Directory of Open Access Journals (Sweden)

    P. Palanisamy

    2018-06-01

    Full Text Available The studies are mainly carried out on strength development for various grades of geo-polymer mortar with varying molarity (M for producing geo-polymer earth brick (GPEB. The studies are focused on use of more sandy soil sieved from the raw earth available at site and quarry dust on replaced with river sand for making the un-burnt brick. The brick is reinforced with fibrous coir waste to increase shear strength and further pressed by hand compaction. Geo-polymer mortar is based on an inorganic alumina silicate binder system and it has more advantages of quick strength gain, negligence of water curing, best mechanical properties, eco-friendly, sustainable and alternate to ordinary Portland cement (OPC based mortar. Fly Ash (FA, Ground Granulated Blast-furnace Slag (GGBS, sandy soil sieved from earth and Quarry Dust (QD are mixed with alkaline solution in different molarities 6 M, 8 M and 10 M to prepare specimens. Specimens are tested against workability, compressive strength, and water absorption test, rate of water absorption, abraded test and also fiber content of the brick. The research found that the brick is made by FA & GGBS as binders and soil & quarry dust as fine aggregate in ratio of 0.5:0.5:1.75:0.25 with fibrous coir waste 1% and alkaline solution 10 M for preparing mortar to produce, excellent compressive strength, low water absorption, low rate of absorption, good abrasive resistance etc., The new brick is placed an alternate to compressed stabilized earth block, cement block and traditional burnt brick. Keywords: Fiber reinforced geo-polymer earth brick, Geo-polymer mortar using sandy soil and quarry dust as fine-aggregate, Nature fibrous coir wastes, Un-burnt brick, Alternate to compressed stabilized earth block

  14. Carbon degradation in agricultural soils flooded with seawater after managed coastal realignment

    Science.gov (United States)

    Sjøgaard, Kamilla S.; Treusch, Alexander H.; Valdemarsen, Thomas B.

    2017-09-01

    Permanent flooding of low-lying coastal areas is a growing threat due to climate change and related sea-level rise. An increasingly common solution to protect coastal areas lying below sea level is intentional flooding by "managed coastal realignment". However, the biogeochemical implications of flooding agricultural soils with seawater are still not well understood. We conducted a 1-year mesocosm experiment to investigate microbial carbon degradation processes in soils flooded with seawater. Agricultural soils were sampled on the northern coast of the island Fyn (Denmark) at Gyldensteen Strand, an area that was subsequently flooded in a coastal realignment project. We found rapid carbon degradation to TCO2 1 day after experimental flooding and onwards and microbial sulfate reduction established quickly as an important mineralization pathway. Nevertheless, no free sulfide was observed as it precipitated as Fe-S compounds with Fe acting as a natural buffer, preventing toxic effects of free sulfide in soils flooded with seawater. Organic carbon degradation decreased significantly after 6 months, indicating that most of the soil organic carbon was refractory towards microbial degradation under the anoxic conditions created in the soil after flooding. During the experiment only 6-7 % of the initial soil organic carbon pools were degraded. On this basis we suggest that most of the organic carbon present in coastal soils exposed to flooding through sea-level rise or managed coastal realignment will be permanently preserved.

  15. A laboratory examination of organic matter degradation in a B horizon soil from post-mining reconstructed prime farmland soil

    International Nuclear Information System (INIS)

    Felton, G.K.; Taraba, J.L.

    1994-01-01

    A laboratory study was conducted to assess the effect of reclamation treatment on the aerobic degradation rate of organic matter composed of horse faeces, urine, and straw bedding. It was hypothesized that different physical treatments of soil removed during the mining process would alter the rate of organic matter decomposition. The soils were from the B horizon of reclaimed prime farmland. The B horizon was reconstructed using one of two treatments: soil direct hauled from the mining site to the reconstruction site; soil hauled from a 6-month-old stockpile. The soil that was immediately replaced exhibited organic matter degradation rates similar to a control whereas the stockpiled soil organic matter degradation rates were depressed. This implies that stockpiling adversely affects the microbial population. Prescription limiting, typically done during reclamation, did have the desired effect on pH and did not interfere with organic matter degradation. 15 refs., 1 fig., 4 tabs

  16. Measurement of surface redistribution of rainfall and modelling its effect on water balance calculations for a millet field on sandy soil in Niger.

    NARCIS (Netherlands)

    Gaze, S.R.; Simmonds, L.P.; Brouwer, J.; Bouma, J.

    1997-01-01

    During rain there can be substantial redistribution of water at the surface of sandy soils in the Sudano-Sahelian zone, because of localised runoff and runon. This results in variable infiltration over a field. Measurements of spatial variability in infiltration and crop growth were made in a millet

  17. The nematicidal effect of some bacterial biofertilizers on Meloidogyne incognita in sandy soil

    Directory of Open Access Journals (Sweden)

    M.E El-Hadad

    2011-03-01

    Full Text Available In a greenhouse experiment, the nematicidal effect of some bacterial biofertilizers including the nitrogen fixing bacteria (NFB Paenibacillus polymyxa (four strains, the phosphate solubilizing bacteria (PSB Bacillus megaterium (three strains and the potassium solubilizing bacteria (KSB B. circulans (three strains were evaluated individually on tomato plants infested with the root-knot nematode Meloidogyne incognita in potted sandy soil. Comparing with the uninoculated nematode-infested control, the inoculation with P. polymyxa NFB7, B. megaterium PSB2 and B. circulans KSB2, increased the counts of total bacteria and total bacterial spores in plants potted soil from 1.2 to 2.6 folds estimated 60 days post-inoculation. Consequently, the inoculation with P. polymyxa NFB7 increased significantly the shoot length (cm, number of leaves / plant, shoot dry weight (g / plant and root dry weight (g / plant by 32.6 %, 30.8 %, 70.3 % and 14.2 %, respectively. Generally, the majority treatments significantly reduced the nematode multiplication which was more obvious after 60 days of inoculation. Among the applied strains, P. polymyxa NFB7, B. megaterium PSB2 and B. circulans KSB2 inoculations resulted in the highest reduction in nematode population comparing with the uninoculated nematode-infested control. They recorded the highest reduction in numbers of hatched juveniles/root by 95.8 %, females/root by 63.75 % and juveniles/1kg soil by 57.8 %. These results indicated that these bacterial biofertilizers are promising double purpose microorganisms for mobilizing of soil nutrients (nitrogen, phosphate and potassium and for the biological control of M. incognita.

  18. Microbial functional diversity plays an important role in the degradation of polyhydroxybutyrate (PHB) in soil.

    Science.gov (United States)

    Dey, Samrat; Tribedi, Prosun

    2018-03-01

    Towards bioremediation of recalcitrant materials like synthetic polymer, soil has been recognized as a traditional site for disposal and subsequent degradation as some microorganisms in soil can degrade the polymer in a non-toxic, cost-effective, and environment friendly way. Microbial functional diversity is a constituent of biodiversity that includes wide range of metabolic activities that can influence numerous aspects of ecosystem functioning like ecosystem stability, nutrient availability, ecosystem dynamics, etc. Thus, in the current study, we assumed that microbial functional diversity could play an important role in polymer degradation in soil. To verify this hypothesis, we isolated soil from five different sites of landfill and examined several microbiological parameters wherein we observed a significant variation in heterotrophic microbial count as well as microbial activities among the soil microcosms tested. Multivariate analysis (principle component analysis) based on the carbon sources utilization pattern revealed that soil microcosms showed different metabolic patterns suggesting the variable distribution of microorganisms among the soil microcosms tested. Since microbial functional diversity depends on both microbial richness and evenness, Shannon diversity index was determined to measure microbial richness and Gini coefficient was determined to measure microbial evenness. The tested soil microcosms exhibited variation in both microbial richness and evenness suggesting the considerable difference in microbial functional diversity among the tested microcosms. We then measured polyhydroxybutyrate (PHB) degradation in soil microcosms after desired period of incubation of PHB in soil wherein we found that soil microcosms having higher functional diversity showed enhanced PHB degradation and soil microcosms having lower functional diversity showed reduced PHB degradation. We also noticed that all the tested soil microcosms showed similar pattern in both

  19. Quasi 3D modelling of water flow in the sandy soil

    Science.gov (United States)

    Rezaei, Meisam; Seuntjens, Piet; Joris, Ingeborg; Boënne, Wesley; De Pue, Jan; Cornelis, Wim

    2016-04-01

    Monitoring and modeling tools may improve irrigation strategies in precision agriculture. Spatial interpolation is required for analyzing the effects of soil hydraulic parameters, soil layer thickness and groundwater level on irrigation management using hydrological models at field scale. We used non-invasive soil sensor, a crop growth (LINGRA-N) and a soil hydrological model (Hydrus-1D) to predict soil-water content fluctuations and crop yield in a heterogeneous sandy grassland soil under supplementary irrigation. In the first step, the sensitivity of the soil hydrological model to hydraulic parameters, water stress, crop yield and lower boundary conditions was assessed after integrating models at one soil column. Free drainage and incremental constant head conditions were implemented in a lower boundary sensitivity analysis. In the second step, to predict Ks over the whole field, the spatial distributions of Ks and its relationship between co-located soil ECa measured by a DUALEM-21S sensor were investigated. Measured groundwater levels and soil layer thickness were interpolated using ordinary point kriging (OK) to a 0.5 by 0.5 m in aim of digital elevation maps. In the third step, a quasi 3D modelling approach was conducted using interpolated data as input hydraulic parameter, geometric information and boundary conditions in the integrated model. In addition, three different irrigation scenarios namely current, no irrigation and optimized irrigations were carried out to find out the most efficient irrigation regime. In this approach, detailed field scale maps of soil water stress, water storage and crop yield were produced at each specific time interval to evaluate the best and most efficient distribution of water using standard gun sprinkler irrigation. The results show that the effect of the position of the groundwater level was dominant in soil-water content prediction and associated water stress. A time-dependent sensitivity analysis of the hydraulic

  20. Degradation of [14C]isofenphos in soil in the laboratory under different soil pH's, temperatures, and moistures

    International Nuclear Information System (INIS)

    Abou-Assaf, N.; Coats, J.R.

    1987-01-01

    The effects of three soil pH's, three soil temperatures, and three soil moistures on [ 14 C]isofenphos degradation were investigated. All three factors interacted strongly and significantly affected the persistence of isofenphos as well as the formation of the degradation products (p less than 1%). Isofenphos degradation was greatest at the higher temperatures 35 0 C greater than 25 0 C greater than 15 0 C (except under alkaline pH's), medium moisture 25% greater than 30% greater than 15%, and in both alkaline (pH = 8) and acidic soils (pH = 6) compared with neutral soil (pH = 7). Isofenphos oxon formation was greatest at higher temperatures 35 0 C compared with 25 0 C and 15 0 C, in acidic soil greater than neutral soil greater than alkaline soil, and under high moisture (30%) compared with the 15% and 22.5% moistures. The formation of soil-bound residues was greatest at higher temperatures 35 0 C greater than 25 0 C greater than 15 0 C, higher moisture 30% compared with 15% and 22.5%, and in alkaline soil compared with neutral and acidic soils

  1. Lead and cadmium interactions in Cynodon nlemfuensis and sandy soil subjected to treated wastewater application under greenhouse conditions

    Science.gov (United States)

    Madyiwa, Simon; Chimbari, Moses John; Schutte, Frederik

    Pb and Cd are known to influence each other’s uptake by some plants when the two metals exist in the soil in significant amounts. This influence may be beneficial if it reduces uptake of metal by plants but may be detrimental if it increases uptake of the metal. This study was carried out to investigate the interaction of Pb and Cd in sandy soils and Cynodon nlemfluensis (star grass). Star grass was grown under greenhouse conditions in 33 fertilized pots containing sandy soils. Three weeks after planting the grass the pots were randomly assigned to the following treatments replicated three times; (a) application of three varying concentrations of Pb or Cd in addition to effluent and sludge, (b) application of three varying concentrations of combined Pb and Cd in addition to effluent and sludge, (c) application of water and (d) application of only effluent and sludge. Analysis of grass samples was done 45 and 90 days after addition of Pb and Cd to pots and that of the soil was done 90 days after addition of Pb and Cd to pots. The log normal mean level (in mg/kg) of Pb detected in the soil was 1.75 and that of Cd was 0.057 in mixed treatments while for single treatments the levels were 1.67 for Pb and 0.03 for Cd. The presence of Cd in the soil had no effect on the bio-available level of Pb but Pb significantly ( p < 0.05) increased the bio-available concentration of Cd. The log normal mean levels of Pb in grass re-growth from mixed treatment was 1.68 and that of Cd was 0.57 while the values for single treatments were 1.47 for Pb and 0.31 for Cd. There was no significant change in the level of uptake of Pb between single treatments and mixed treatments. However, Pb significantly increased uptake of Cd in mixed treatments compared to single treatments ( p < 0.05). The results of this study indicate that co-presence of Pb and Cd may have the detrimental effect of increasing uptake of Cd in star grass.

  2. Comparative metagenomic analysis of PAH degradation in soil by a mixed microbial consortium.

    Science.gov (United States)

    Zafra, German; Taylor, Todd D; Absalón, Angel E; Cortés-Espinosa, Diana V

    2016-11-15

    In this study, we used a taxonomic and functional metagenomic approach to analyze some of the effects (e.g. displacement, permanence, disappearance) produced between native microbiota and a previously constructed Polycyclic Aromatic Hydrocarbon (PAH)-degrading microbial consortium during the bioremediation process of a soil polluted with PAHs. Bioaugmentation with a fungal-bacterial consortium and biostimulation of native microbiota using corn stover as texturizer produced appreciable changes in the microbial diversity of polluted soils, shifting native microbial communities in favor of degrading specific populations. Functional metagenomics showed changes in gene abundance suggesting a bias towards aromatic hydrocarbon and intermediary degradation pathways, which greatly favored PAH mineralization. In contrast, pathways favoring the formation of toxic intermediates such as cytochrome P450-mediated reactions were found to be significantly reduced in bioaugmented soils. PAH biodegradation in soil using the microbial consortium was faster and reached higher degradation values (84% after 30 d) as a result of an increased co-metabolic degradation when compared with other mixed microbial consortia. The main differences between inoculated and non-inoculated soils were observed in aromatic ring-hydroxylating dioxygenases, laccase, protocatechuate, salicylate and benzoate-degrading enzyme genes. Based on our results, we propose that several concurrent metabolic pathways are taking place in soils during PAH degradation. Copyright © 2016 Elsevier B.V. All rights reserved.

  3. Organic Matter Dynamics in Soils Regenerating from Degraded ...

    African Journals Online (AJOL)

    The area of secondary forest (SF) regenerating from degraded abandoned rubber (Hevea brasiliensis) plantation is increasing in the rainforest zone of south southern Nigeria; however, the build-up of soil organic matter following abandonment is not well understood. This study examined the build-up of soil organic matter in ...

  4. Effect of Polylactic Acid-Degradable Film Mulch on Soil Temperature and Cotton Yield

    Directory of Open Access Journals (Sweden)

    ZHANG Ni

    2016-03-01

    Full Text Available Concern on biodegradable plastic film is increasing because of pollution problems caused by the plastic films currently used. The objective of this field experiment is to evaluate the effect of two thicknesses of polyactic acid-degradable film on soil temperature and cotton yield. The results showed that small holes appeared in the polyactic acid-degradable film at 17~22 d after it was installed. Burst period appeared about 60 d after installation. Splits were observed in the polyactic acid-degradable film at 130 d after installation. Soil temperatures rose slowly under polyactic acid-degradable film during the cotton seedling stage. Daytime soil temperatures were 0.8℃ and 6.2℃ lower under 18μm and 15μm thick polyactic acid-degradable film than non-degradable plastic film(CK, respectively. Nighttime soil temperatures under the polyactic acid-degradable film were about 1℃ warmer than CK. There was no significant difference in cotton yields between the 18μm polyactic acid degradable film treatment and CK. In contrast, yields in the 15μm degradable plastic film treatment were 8.9% less than that in CK. This study indicated that 18μm polyactic acid degradable plastic film had good degradability and no negative effect on cotton growth. The 18μm polyactic acid degradable plastic film can replace ordinary plastic film in agricultural production.

  5. In-situ hydrodynamic characterization of a soil by means of an infiltration experiment. Application to a sandy soil in the central zone of Senegal

    International Nuclear Information System (INIS)

    Haverkamp, R.; Hamon, G.; Vauclin, M.; Vachaud, G.

    1979-01-01

    A new method is presented for predicting the hydraulic conductivity curve of an unsaturated soil from the relation between effective pressure and water content and the law of cumulative infiltration. With this method, which is based on the conceptual model proposed by Mualem (1976), it is possible to determine the parameter n as a function of the type of soil by fitting the cumulative infiltration law obtained numerically by solution of the Richards equation to that obtained experimentally. This approach is tested on experimental results obtained using the internal drainage method on sandy soil in the Central Zone of Senegal. It is shown that the moisture profiles calculated with the aid of the predicted hydraulic conductivity curve are in very good agreement with the measured profiles. This method seems well suited for studying the spatial variability of hydrodynamic characteristics since it is simple to set up and precise, and a large number of experiments can be performed in a short space of time. (author)

  6. Biodegradation of 4-chlorophenol by adsorptive immobilized Alcaligenes sp. A 7-2 in soil.

    Science.gov (United States)

    Balfanz, J; Rehm, H J

    1991-08-01

    Alcaligenes sp. A 7-2 immobilized on granular clay has been applied in a percolator to degrade 4-chlorophenol in sandy soil. Good adsorption rates on granular clay were achieved using cell suspensions with high titres and media at pH 8.0. The influence of various parameters such as aeration rate, pH, temperature, concentration of 4-chlorophenol and size of inoculum on the degradation rate were investigated. During fed-batch fermentations under optimal culture conditions, concentrations of 4-chlorophenol up to 160 mg.l-1 could be degraded. Semicontinuous culture experiments demonstrated that the degradation potential in soil could be well established and enhanced by the addition of immobilized bacteria. Continuous fermentation was performed with varying 4-chlorophenol concentrations in the feed and different input levels. The maximum degradation rate was 1.64 g.l-1.day-1.

  7. Enhanced degradation of 14C-HCB in two tropical clay soils using multiple anaerobic–aerobic cycles

    International Nuclear Information System (INIS)

    Orori Kengara, Fredrick; Doerfler, Ulrike; Welzl, Gerhard; Ruth, Bernhard; Munch, Jean Charles; Schroll, Reiner

    2013-01-01

    The aim of the study was to induce and enhance the degradation of hexachlorobenzene (HCB), a highly-chlorinated persistent organic pollutant, in two ecologically different tropical soils: a paddy soil (PS) and a non-paddy soil (FS). The degradation of HCB was enhanced using two anaerobic–aerobic cycles in model laboratory experiments. There was greater degradation of HCB in the PS (half-life of 224 days) relative to the FS (half-life of 286 days). It was further shown that soils amended with compost had higher metabolite concentrations relative to the non-amended soils. In the first cycle, there was little degradation of HCB in both soils. However, in the second cycle, there was enhanced mineralization in the PS under aerobic conditions, with the compost-treated samples showing higher mineralization. There was also extensive volatilization in both soils. The metabolite pattern revealed that the increased mineralization and volatilization was due to the formation of lower chlorinated benzenes. - Highlights: ► Two anaerobic–aerobic cycles enhanced the dissipation of HCB in two tropical soils – a paddy and non-paddy soil. ► The paddy soil was more effective in degrading HCB. ► The non-paddy soil adapted and degraded HCB in the second anaerobic–aerobic cycle. ► An additional carbon source enhanced degradation and mineralisation of HCB in both soils. - Two anaerobic–aerobic cycles enhance the degradation of HCB in two ecologically different tropical clay soils.

  8. Current State and Development of Land Degradation Processes Based on Soil Monitoring in Slovakia

    Directory of Open Access Journals (Sweden)

    Kobza Jozef

    2017-08-01

    Full Text Available Current state and development of land degradation processes based on soil monitoring system in Slovakia is evaluated in this contribution. Soil monitoring system in Slovakia is consistently running since 1993 year in 5-years repetitions. Soil monitoring network in Slovakia is constructed using ecological principle, taking into account all main soil types and subtypes, soil organic matter, climatic regions, emission regions, polluted and non-polluted regions as well as various land use. The result of soil monitoring network is 318 sites on agricultural land in Slovakia. Soil properties are evaluated according to the main threats to soil relating to European Commission recommendation for European soil monitoring performance as follows: soil erosion and compaction, soil acidification, decline in soil organic matter and soil contamination. The most significant change has been determined in physical degradation of soils. The physical degradation was especially manifested in compacted and the eroded soils. It was determined that about 39% of agricultural land is potentially affected by soil erosion in Slovakia. In addition, slight decline in soil organic matter indicates the serious facts on evaluation and extension of soil degradation processes during the last period in Slovakia. Soil contamination is without significant change for the time being. It means the soils contaminated before soil monitoring process this unfavourable state lasts also at present.

  9. CARBON FIXING CAPACITY OF AMAZONIAN SOILS IN RELATION TO ITS DEGRADATION CONDITIONS

    OpenAIRE

    Clara Patricia Peña Venegas; Edmundo Rafael Mendoza Olmos; Carlos Hernando Rodríguez León; Gladys Inés Cardona Vanegas; Bernardo Eusebio Betancurt Parra; Maolenmarx Tatiana Garzón Gómez

    2015-01-01

    Amazonian deforestation and transformation alert about their effects worldwide. One concern is the increase of the Carbon (C) levels emitted. Previous works have estimated the fixed C in Amazon forests without including the C stored in soils. Within soil, the organic carbon molecules are highly sensitive to degradation, affecting the natural capacity of soils to fix and store C. The present study evaluates the impact of degradation in the natural capacity of Amazon soils to fix C. Thirty five...

  10. Degradation of dibutyl phthalate in two contrasting agricultural soils and its long-term effects on soil microbial community.

    Science.gov (United States)

    Cheng, Jinjin; Liu, Yanai; Wan, Qun; Yuan, Li; Yu, Xiangyang

    2018-06-04

    Due to its widespread application and large-scale production, dibutyl phthalate (DBP) has become one of the most frequently identified phthalic acid esters (PAEs) in soils. The fate of DBP and its effects on microbial communities in soils with contrasting properties have seldom been studied. In this study, the degradation of DBP and its long-term effects on the soil microbial community were investigated in aquic cambisols and udic ferrosols. The half-lives of DBP in aquic cambisols and udic ferrosols were found to be 0.286-1.41 days and 0.870-20.4 days, respectively, indicating that DBP was degraded faster in aquic cambisols. In addition, the degradation of DBP in aquic cambisols was less vulnerable to adverse incubation conditions, including high DBP concentration, low temperature and low moisture. These results can be ascribed to the higher microbial abundance and activity in aquic cambisols than in udic ferrosols. During DBP degradation, the toxic metabolite monobutyl phthalate (MBP) was present only transiently and did not accumulate in the two soils. After 60 days of incubation, the degradation-resistant DBP residue concentrations were as high as 1.10 and 1.34 mg/kg, and the relative abundance of 8.51%-12.9% of bacterial genera and 5.59%-6.02% of fungal genera was significantly disturbed by DBP in both test soils. The results from this study highlight the need to comprehensively evaluate the environmental risks of degradation-resistant DBP residues and the impact of DBP contamination on soil microbial functions. Copyright © 2018. Published by Elsevier B.V.

  11. Factors mediating the restoration of structurally degraded soils

    DEFF Research Database (Denmark)

    Arthur, Emmanuel; Moldrup, Per; Schjønning, Per

    with the ability of soils to perform these functions. The present study examines the roles of clay mineralogy, native organic matter, and exogenous organic material on the restoration of structurally degraded soils. Totally seven soils from Denmark and Ghana - five soils dominated by illites, one kaolinitic soil...... the incubation period, structural stability estimated as the amount of water-dispersible clay decreased with prevailing moisture content, and native organic matter. Also, microbial activity significantly increased with addition of exogenous organic matter. At the end of incubation, there was significant...... macroaggregation, decreased bulk density, and increased equivalent pore diameter and tortuosity (derived from measurements of soil-gas diffusivity and soil-air permeability) for all soils. Although aggregate friability was not affected by clay type, aggregate workability was highest for the kaolinitic soil...

  12. Thermal properties of degraded lowland peat-moorsh soils

    Science.gov (United States)

    Gnatowski, Tomasz

    2016-04-01

    Soil thermal properties, i.e.: specific heat capacity (c), thermal conductivity (K), volumetric heat capacity (C) govern the thermal environment and heat transport through the soil. Hence the precise knowledge and accurate predictions of these properties for peaty soils with high amount of organic matter are especially important for the proper forecasting of soil temperature and thus it may lead to a better assessment of the greenhouse gas emissions created by microbiological activity of the peatlands. The objective of the study was to develop the predictive models of the selected thermal parameters of peat-moorsh soils in terms of their potential applicability for forecasting changes of soil temperature in degraded ecosystems of the Middle Biebrza River Valley area. Evaluation of the soil thermal properties was conducted for the parameters: specific heat capacity (c), volumetric heat capacities of the dry and saturated soil (Cdry, Csat) and thermal conductivities of the dry and saturated soil (Kdry, Ksat). The thermal parameters were measured using the dual-needle probe (KD2-Pro) on soil samples collected from seven peaty soils, representing total 24 horizons. The surface layers were characterized by different degrees of advancement of soil degradation dependent on intensiveness of the cultivation practises (peaty and humic moorsh). The underlying soil layers contain peat deposits of different botanical composition (peat-moss, sedge-reed, reed and alder) and varying degrees of decomposition of the organic matter, from H1 to H7 (von Post scale). Based on the research results it has been shown that the specific heat capacity of the soils differs depending on the type of soil (type of moorsh and type of peat). The range of changes varied from 1276 J.kg-1.K-1 in the humic moorsh soil to 1944 J.kg-1.K-1 in the low decomposed sedge-moss peat. It has also been stated that in degraded peat soils with the increasing of the ash content in the soil the value of specific heat

  13. Degradation of 2,4-DB in Argentinean agricultural soils with high humic matter content.

    Science.gov (United States)

    Cuadrado, Virginia; Merini, Luciano J; Flocco, Cecilia G; Giulietti, Ana M

    2008-01-01

    The dissipation of 4-(2,4-dichlorophenoxy) butyric acid (2,4-DB) in high-humic-matter-containing soils from agricultural fields of the Argentinean Humid Pampa region was studied, employing soil microcosms under different experimental conditions. The added herbicide was dissipated almost completely by soils with and without history of herbicide use by day 28. At 500 ppm, both soils showed the same degradation rates; but at 5-ppm concentration, the chronically exposed soil demonstrated a faster degradation of the herbicide. 2,4-DB addition produced increases in herbicide-degrading bacteria of three and 1.5 orders of magnitude in soils with and without history of herbicide use, respectively, in microcosms with 5 ppm. At 500-ppm concentration, the increase in 2,4-DB degraders was five orders of magnitude after 14 days, independent of the history of herbicide use. No differences were observed in either 2,4-DB degradation rates or in degrader bacteria numbers in the presence and absence of alfalfa plants, in spite of some differential characteristics in patterns of 2,4-DB metabolite accumulation. The main factor affecting 2,4-DB degradation rate would be the history of herbicide use, as a consequence of the adaptation of the indigenous microflora to the presence of herbicides in the field.

  14. Rate of atrazine mineralisation in New Zealand topsoils and subsoils depends on numbers of specialist atrazine-degrading microorganisms

    International Nuclear Information System (INIS)

    Sparling, G.; Fraser, R.; Aislabie, J.; Dragten, R.

    1998-01-01

    Full text: The herbicide atrazine (2-chloro-4-ethylamino-6-isopropylamino-1,3,5-s-triazine) is widely used in horticulture and arable farming in New Zealand and there is a trend towards increasing concentrations in aquifers and ground waters. Microbial degradation is considered a major route whereby atrazine is decomposed in soil. Microbial activity declines rapidly with depth of soil, so to predict the risks of atrazine reaching aquifers, we need to know the rates of mineralisation at different depths in the soil profile. We measured the rates of mineralisation of [U] 14 C-ring-labelled atrazine in topsoils and subsoils of two sandy loam soils and an allophanic soil under a range of temperature and moisture conditions. The numbers of atrazine-degrading organisms were measured using a most-probable number method based on the mineralisation of [U] 14 C-ring-labelled atrazine to 14 CO 2 . Numbers of atrazine-degraders and rates of mineralisation were generally very low in subsoils. However, one subsoil had unusually high numbers of atrazine-degrading microbes and showed equivalent rates of mineralisation rates to those in the surface soil. The rate of atrazine mineralisation could be predicted from the number of atrazine-degrading microbes and the cation exchange capacity of the soil (R 2 = 0.86). A large amount (54-77%) of 14 C remained in the soil as non-extractable residues after 263 days but only trace amounts of atrazine were detectable

  15. Pathogenic prion protein is degraded by a manganese oxide mineral found in soils

    Science.gov (United States)

    Russo, F.; Johnson, C.J.; McKenzie, D.; Aiken, Judd M.; Pedersen, J.A.

    2009-01-01

    Prions, the aetiological agents of transmissible spongiform encephalopathies, exhibit extreme resistance to degradation. Soil can retain prion infectivity in the environment for years. Reactive soil components may, however, contribute to the inactivation of prions in soil. Members of the birnessite family of manganese oxides (MnO2) rank among the strongest natural oxidants in soils. Here, we report the abiotic degradation of pathogenic prion protein (PrPTSE) by a synthetic analogue of naturally occurring birnessite minerals. Aqueous MnO2 suspensions degraded the PrPTSE as evidenced by decreased immunoreactivity and diminished ability to seed protein misfolding cyclic amplification reactions. Birnessite-mediated PrPTSE degradation increased as a solution's pH decreased, consistent with the pH-dependence of the redox potential of MnO2. Exposure to 5.6 mg MnO2 ml-1 (PrPTSE:MnO2=1 : 110) decreased PrPTSE levels by ???4 orders of magnitude. Manganese oxides may contribute to prion degradation in soil environments rich in these minerals. ?? 2009 SGM.

  16. Persistence of bifenthrin in sandy loam soil as affected by microbial community.

    Science.gov (United States)

    Sharma, Divya; Singh, Shashi Bala

    2012-06-01

    Soil was fortified with bifenthrin at the level of 10 μg g(-1) soil. Soil samples were drawn at regular intervals of 0, 10, 20, 30 and 40 days. For extraction of bifenthrin, soil was extracted with acetone. Clean up was done by liquid-liquid partitioning with dichloromethane after diluting with brine solution. Quantification of bifenthrin residues was done by GC using mega bore column and ECD detector. Recovery of bifenthrin in soil ranged between 92.6 % and 93.8 % at 0.5 and 1.0 μg g(-1). The instrumental limit of detection of bifenthrin was 0.005 μg mL(-1) and LOQ for soil by this method was found to be 0.05 μg g(-1). The calibration curve was found to be linear within range the range of 0.01 and 0.10 μg mL(-1) concentration. The DT(50) (disappearance time for 50 % loss) of bifenthrin at the level of 10 μg g(-1) in sterile and non sterile soil were found to be 330 and 147 days, respectively. A vast difference in the half life of sterile and non sterile soil indicated the presence of potential microbes for bifenthrin degradation.

  17. Bioavailability and chronic toxicity of bismuth citrate to earthworm Eisenia andrei exposed to natural sandy soil.

    Science.gov (United States)

    Omouri, Zohra; Hawari, Jalal; Fournier, Michel; Robidoux, Pierre Yves

    2018-01-01

    The present study describes bioavailability and chronic effects of bismuth to earthworms Eisenia andrei using OECD reproduction test. Adult earthworms were exposed to natural sandy soil contaminated artificially by bismuth citrate. Average total concentrations of bismuth in soil recovered by HNO 3 digestion ranged from 75 to 289mg/kg. Results indicate that bismuth decreased significantly all reproduction parameters of Eisenia andrei at concentrations ≥ 116mg/kg. However, number of hatched cocoons and number of juveniles seem to be more sensitive than total number of cocoons, as determined by IC 50 ; i.e., 182, 123 and > 289mg/kg, respectively. Bismuth did not affect Eisenia andrei growth and survival, and had little effect on phagocytic efficiency of coelomocytes. The low immunotoxicity effect might be explained by the involvement of other mechanisms i.e. bismuth sequestered by metal-binding compounds. After 28 days of exposure bismuth concentrations in earthworms tissue increased with increasing bismuth concentrations in soil reaching a stationary state of 21.37mg/kg dry tissue for 243mg Bi/kg dry soil total content. Data indicate also that after 56 days of incubation the average fractions of bismuth available extracted by KNO 3 aqueous solution in soil without earthworms varied from 0.0051 to 0.0229mg/kg, while in soil with earthworms bismuth concentration ranged between 0.310-1.347mg/kg dry soil. We presume that mucus and chelating agents produced by earthworms and by soil or/and earthworm gut microorganisms could explain this enhancement, as well as the role of dermal and ingestion routes of earthworms uptake to soil contaminant. Copyright © 2017 Elsevier Inc. All rights reserved.

  18. Effect of elevated CO2 on degradation of azoxystrobin and soil microbial activity in rice soil.

    Science.gov (United States)

    Manna, Suman; Singh, Neera; Singh, V P

    2013-04-01

    An experiment was conducted in open-top chambers (OTC) to study the effect of elevated CO2 (580 ± 20 μmol mol(-1)) on azoxystrobin degradation and soil microbial activities. Results indicated that elevated CO2 did not have any significant effect on the persistence of azoxystrobin in rice-planted soil. The half-life values for the azoxystrobin in rice soils were 20.3 days in control (rice grown at ambient CO2 outdoors), 19.3 days in rice grown under ambient CO2 atmosphere in OTC, and 17.5 days in rice grown under elevated CO2 atmosphere in OTC. Azoxystrobin acid was recovered as the only metabolite of azoxystrobin, but it did not accumulate in the soil/water and was further metabolized. Elevated CO2 enhanced soil microbial biomass (MBC) and alkaline phosphatase activity of soil. Compared with rice grown at ambient CO2 (both outdoors and in OTC), the soil MBC at elevated CO2 increased by twofold. Elevated CO2 did not affect dehydrogenase, fluorescein diacetate, and acid phosphatase activity. Azoxystrobin application to soils, both ambient and elevated CO2, inhibited alkaline phosphates activity, while no effect was observed on other enzymes. Slight increase (1.8-2 °C) in temperature inside OTC did not affect microbial parameters, as similar activities were recorded in rice grown outdoors and in OTC at ambient CO2. Higher MBC in soil at elevated CO2 could be attributed to increased carbon availability in the rhizosphere via plant metabolism and root secretion; however, it did not significantly increase azoxystrobin degradation, suggesting that pesticide degradation was not the result of soil MBC alone. Study suggested that increased CO2 levels following global warming might not adversely affect azoxystrobin degradation. However, global warming is a continuous and cumulative process, therefore, long-term studies are necessary to get more realistic assessment of global warming on fate of pesticide.

  19. Biodegradation of polyethylene glycol (PEG) in three tropical soils using radio labelled PEG

    Energy Technology Data Exchange (ETDEWEB)

    Abdalla, A.L. [Laboratory of Animal Nutrition, Centre for Nuclear Energy in Agriculture, University of Sao Paulo (CENA/USP), Piracicaba SP (Brazil)]. E-mail: abdalla@cena.usp.br; Regitano, J.B.; Tornisielo, V.L.; Marchese, L. [Laboratory of Ecotoxicology, Piracicaba SP (Brazil); Pecanha, M.R.S.R.; Vitti, D.M.S.S. [Laboratory of Animal Nutrition, Centre for Nuclear Energy in Agriculture, University of Sao Paulo (CENA/USP), Piracicaba SP (Brazil); Smith, T. [School of Agriculture, Policy and Development, University of Reading, Reading (United Kingdom)

    2005-08-19

    Polyethylene glycol (PEG) may be added to forage based diets rich in tannins for ruminant feeding because it binds to tannins and thus prevent the formation of potentially indigestible tannin-protein complexes. The objective of this work was to determine the in vitro biodegradation (mineralization, i.e., complete breakdown of PEG to CO{sub 2}) rate of PEG. {sup 14}C-Polyethylene glycol ({sup 14}C-PEG) was added to three different tropical soils (a sandy clay loam soil, SaCL; a sandy clay soil, SaC; and a sandy loam soil, SaL) and was incubated in Bartha flasks. Free PEG and PEG bound to tannins from a tannin rich local shrub were incubated under aerobic conditions for up to 70 days. The biodegradation assay monitored the {sup 14}CO{sub 2} evolved after degradation of the labelled PEG in the soils. After incubation, the amount of {sup 14}CO{sub 2} evolved from the {sup 14}C-PEG application was low. Higher PEG mineralization values were found for the soils with higher organic matter contents (20.1 and 18.6 g organic matter/kg for SaCL and SaC, respectively) than for the SaL soil (11.9 g organic matter/kg) (P < 0.05). The extent of mineralization of PEG after 70 days of incubation in the soil was significantly lower (P < 0.05) when it was added as bound to the browse tannin than in the free form (0.040 and 0.079, respectively). (author)

  20. Long-Term Observations of Dust Storms in Sandy Desert Environments

    Science.gov (United States)

    Yun, Hye-Won; Kim, Jung-Rack; Choi, Yun-Soo

    2015-04-01

    Mineral dust occupies the largest portion of atmospheric aerosol. Considering the numerous risks that dust poses for socioeconomic and anthropogenic activities, it is crucial to understand sandy desert environments, which frequently generate dust storms and act as a primary source of atmospheric aerosol. To identify mineral aerosol mechanisms, it is essential to monitor desert environmental factors involving dust storm generation in the long term. In this study, we focused on two major environmental factors: local surface roughness and soil moisture. Since installments of ground observation networks in sandy deserts are unfeasible, remote sensing techniques for mining desert environmental factors were employed. The test area was established within the Badain Jaran and Kubuqi Deserts in Inner Mongolia, China, where significant seasonal aeolian processes emit mineral dust that influences all of East Asia. To trace local surface roughness, we employed a multi-angle imaging spectroradiometer (MISR) image sequence to extract multi-angle viewing (MAV) topographic parameters such as normalized difference angular index, which represents characteristics of the target desert topography. The backscattering coefficient from various space-borne SAR and stereotopography were compared with MAV observations to determine calibrated local surface roughness. Soil moisture extraction techniques from InSAR-phase coherence stacks were developed and compiled with advanced scatterometer (ASCAT) soil moisture data. Combined with metrological information such as the European Centre for Medium-Range Weather Forecasts (ECMWF) ERA interim, correlations between intensity of sand dune activity as a proxy of aeolian processes in desert environments, surface wind conditions, and surface soil moisture were traced. Overall, we have confirmed that tracking sandy desert aeolian environments for long-term observations is feasible with space-borne, multi-sensor observations when combined with

  1. Microbial degradation of metalaxyl in soil

    Energy Technology Data Exchange (ETDEWEB)

    Musumeci, M.R.; Ruegg, E.F. (Instituto Biologico, Sao Paulo (Brazil). Centro de Radioisotopos)

    1984-10-01

    The behaviour of the fungicide metalaxyl in purple latosol soil was investigated using a ring - /sup 14/C labelled compound under laboratory conditions. In nonsterile soil samples under aerobic conditions, metalaxyl was degraded into two metabolites. After 60 days, 60% of the radiocarbon on TLC plates corresponded to the parent fungicide, 22% to its metabolite N-(2-methoxyacetyl)-N-(2,6-xylyl)-DL-alanine, and 2.7% to a second and unidentified metabolite. The U.V. absorbance value of metalaxyl decreased after seven days incubation with a soil microorganisms suspension. Incubation of /sup 14/C-metalaxyl for 50 days with a bacterium or a fungus isolated from that suspension resulted in metalaxyl gradual disappearance from the medium, but not metabolites were detected during this period.

  2. [Oil degradation by basidiomycetes in soil and peat at low temperatures].

    Science.gov (United States)

    Kulikova, N A; Klein, O I; Pivchenko, D V; Landesman, E O; Pozdnyakova, N N; Turkovskaya, O V; Zaichik, B Ts; Ruzhitskii, A O; Koroleva, O V

    2016-01-01

    A total of 17 basidiomycete strains causing white rot and growing on oil-contaminated substrates have been screened. Three strains with high (Steccherinum murashkinskyi), average (Trametes maxima), and low (Pleurotus ostreatus) capacities for the colonization of oil-contaminated substrates have been selected. The potential for degrading crude oil hydrocarbons has been assessed with the use of fungi grown on nonsterile soil and peat at low temperatures. Candida sp. and Rhodococcus sp. commercial strains have been used as reference organisms with oil-degrading ability. All microorganisms introduced in oil-contaminated soil have proved to be ineffective, whereas the inoculation of peat with basidiomycetes and oil-degrading microorganisms accelerated the destruction of oil hydrocarbons. The greatest degradation potential of oil-aliphatic hydrocarbons has been found in S. murashlinskyi. T. maxima turned out to be the most successful in degrading aromatic hydrocarbons. It has been suggested that aboriginal microflora contributes importantly to the effectiveness of oil-destructing microorganisms. T. maxima and S. murashkinskyi strains are promising for further study as oil-oxidizing agents during bioremediation of oil-contaminated peat soil under conditions of low temperatures.

  3. Effect of lead on the microbiological activity in soil

    Energy Technology Data Exchange (ETDEWEB)

    Mikkelsen, J P

    1974-01-01

    The production of CO/sub 2/ has been measured after addition of 0, 100, 1000 and 5000 ppm lead (as nitrate) to three Danish soils (two sandy soils and one clay soil). The microbiological activity was inhibited for 10-14 days in the two sandy soils at an addition of 5000 ppm lead, but not in the clay soil. Extraction experiments indicated that the sandy soil has the greatest amount of slight soluble lead, and the content of heavy adsorbed lead was greatest in the clay soil. Determinations (counts) of the effect of lead on the microbial population has shown reduction of the number of microorganisms at addition of 5000 ppm lead. The reduction was greatest in the sandy soil.

  4. Identification of anthraquinone-degrading bacteria in soil contaminated with polycyclic aromatic hydrocarbons.

    Science.gov (United States)

    Rodgers-Vieira, Elyse A; Zhang, Zhenfa; Adrion, Alden C; Gold, Avram; Aitken, Michael D

    2015-06-01

    Quinones and other oxygenated polycyclic aromatic hydrocarbons (oxy-PAHs) are toxic and/or genotoxic compounds observed to be cocontaminants at PAH-contaminated sites, but their formation and fate in contaminated environmental systems have not been well studied. Anthracene-9,10-dione (anthraquinone) has been found in most PAH-contaminated soils and sediments that have been analyzed for oxy-PAHs. However, little is known about the biodegradation of oxy-PAHs, and no bacterial isolates have been described that are capable of growing on or degrading anthraquinone. PAH-degrading Mycobacterium spp. are the only organisms that have been investigated to date for metabolism of a PAH quinone, 4,5-pyrenequinone. We utilized DNA-based stable-isotope probing (SIP) with [U-(13)C]anthraquinone to identify bacteria associated with anthraquinone degradation in PAH-contaminated soil from a former manufactured-gas plant site both before and after treatment in a laboratory-scale bioreactor. SIP with [U-(13)C]anthracene was also performed to assess whether bacteria capable of growing on anthracene are the same as those identified to grow on anthraquinone. Organisms closely related to Sphingomonas were the most predominant among the organisms associated with anthraquinone degradation in bioreactor-treated soil, while organisms in the genus Phenylobacterium comprised the majority of anthraquinone degraders in the untreated soil. Bacteria associated with anthracene degradation differed from those responsible for anthraquinone degradation. These results suggest that Sphingomonas and Phenylobacterium species are associated with anthraquinone degradation and that anthracene-degrading organisms may not possess mechanisms to grow on anthraquinone. Copyright © 2015, American Society for Microbiology. All Rights Reserved.

  5. A Perspective on Water Resources in China. Interactions between Climate Change and Soil Degradation

    Energy Technology Data Exchange (ETDEWEB)

    Tao, Fulu; Lin, Erda [Chinese Academy of Agricultural Sciences, Institute of Agricultural Environment and Sustainable Development, Beijing, 100081 (China); Yokozawa, M.; Hayashi, Y. [National Institute for Agro-Environmental Sciences, 3-1-3 Kannondai, Tsukuba, Ibaraki 305-8604 (Japan)

    2005-01-01

    Water is one of the most critical resources in China. Climate change and soil degradation will be two major, interrelated environmental challenges faced by managers of water resources in coming decades. In this study, we used a water-balance model and updated databases to assess the interacting impacts of climate change and soil degradation on China's future water resources. We plotted the spatial pattern of changes in actual and potential evapotranspiration, soil moisture deficits, and surface runoff across China in the 2020s using a resolution of 0.5{sup o} latitude and longitude under scenarios based on climate change, soil degradation, and a combination of the two. The results showed that climate change would affect the magnitude and spatial pattern of water resources on a national scale. Some regions in central, southwestern, and northeastern China would become more vulnerable to disastrous drought and floods as a result of soil degradation. Under the combined impacts of climate change and soil degradation, soil moisture deficits would increase most in central, western, and southwestern China; surface runoff would increase most in southeastern China. More detailed process-based models are needed to capture feedback mechanisms more effectively.

  6. Occurrence, fate, and persistence of gemfibrozil in water and soil.

    Science.gov (United States)

    Fang, Yu; Karnjanapiboonwong, Adcharee; Chase, Darcy A; Wang, Jiafan; Morse, Audra N; Anderson, Todd A

    2012-03-01

    Pharmaceuticals and personal care products (PPCPs) have emerged as a group of potential environmental contaminants of concern. The occurrence of gemfibrozil, a lipid-regulating drug, was studied in the influent and effluent at a wastewater treatment plant (WWTP) and groundwater below a land application site receiving treated effluent from the WWTP. In addition, the sorption of gemfibrozil in two loam soils and sand was assessed, and biological degradation rates in two soil types under aerobic conditions were also determined. Results showed that concentrations of gemfibrozil in wastewater influent, effluent, and groundwater were in the range of 3.47 to 63.8 µg/L, 0.08 to 19.4 µg/L, and undetectable to 6.86 µg/L, respectively. Data also indicated that gemfibrozil in the wastewater could reach groundwater following land application of the treated effluent. Soil-water distribution coefficients for gemfibrozil, determined by the batch equilibrium method, varied with organic carbon content in the soils. The sorption capacity was silt loam > sandy loam > sand. Under aerobic conditions, dissipation half-lives for gemfibrozil in sandy loam and silt loam soils were 17.8 and 20.6 days, respectively; 25.4 and 11.3% of gemfibrozil was lost through biodegradation from the two soils over 14 days. Copyright © 2011 SETAC.

  7. Target Soil Impact Verification: Experimental Testing and Kayenta Constitutive Modeling.

    Energy Technology Data Exchange (ETDEWEB)

    Broome, Scott Thomas [Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States); Flint, Gregory Mark [Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States); Dewers, Thomas [Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States); Newell, Pania [Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)

    2015-11-01

    This report details experimental testing and constitutive modeling of sandy soil deformation under quasi - static conditions. This is driven by the need to understand constitutive response of soil to target/component behavior upon impact . An experimental and constitutive modeling program was followed to determine elastic - plastic properties and a compressional failure envelope of dry soil . One hydrostatic, one unconfined compressive stress (UCS), nine axisymmetric compression (ACS) , and one uniaxial strain (US) test were conducted at room temperature . Elastic moduli, assuming isotropy, are determined from unload/reload loops and final unloading for all tests pre - failure and increase monotonically with mean stress. Very little modulus degradation was discernable from elastic results even when exposed to mean stresses above 200 MPa . The failure envelope and initial yield surface were determined from peak stresses and observed onset of plastic yielding from all test results. Soil elasto - plastic behavior is described using the Brannon et al. (2009) Kayenta constitutive model. As a validation exercise, the ACS - parameterized Kayenta model is used to predict response of the soil material under uniaxial strain loading. The resulting parameterized and validated Kayenta model is of high quality and suitable for modeling sandy soil deformation under a range of conditions, including that for impact prediction.

  8. [Dynamic changes of surface soil organic carbon and light-fraction organic carbon after mobile dune afforestation with Mongolian pine in Horqin Sandy Land].

    Science.gov (United States)

    Shang, Wen; Li, Yu-qiang; Wang, Shao-kun; Feng, Jing; Su, Na

    2011-08-01

    This paper studied the dynamic changes of surface (0-15 cm) soil organic carbon (SOC) and light-fraction organic carbon (LFOC) in 25- and 35-year-old sand-fixing Mongolian pine (Pinus sylvestris var. mongolica) plantations in Horqin Sandy Land, with a mobile dune as a comparison site. After the afforestation on mobile dune, the content of coarse sand in soil decreased, while that of fine sand and clay-silt increased significantly. The SOC and LFOC contents also increased significantly, but tended to decrease with increasing soil depth. Afforestation increased the storages of SOC and LFOC in surface soil, and the increment increased with plantation age. In the two plantations, the increment of surface soil LFOC storage was much higher than that of SOC storage, suggesting that mobile dune afforestation had a larger effect on surface soil LFOC than on SOC.

  9. Structural Stability and Hydraulic Conductivity Of Nkpologu Sandy ...

    African Journals Online (AJOL)

    Studies were conducted in the runoff plots at the University of Nigeria Nsukka Teaching and Resesarch Farm in 2010 and 2011 to monitor the changes in structural stability and saturated hydraulic conductivity (Ksat) of Nkpologu sandy loam soil under different cover management practices. The management practices were ...

  10. A Modified Soil Quality Index to Assess the Influence of Soil Degradation Processes on Desertification Risk: The Apulia Case

    Directory of Open Access Journals (Sweden)

    Valeria Ancona

    2010-10-01

    Full Text Available Apulia is one of the most prone Italian regions to soil alteration phenomena, due to geographical and climatic conditions and also to human activities’ impact. In this study, in order to investigate regional soil degradation processes, following the “European Directive for Soil Protection”, the ESA’s method has been adopted. It is based on the use of an indicator’s set to assess the desertification risk. This approach simplifies the diagnosis and monitoring of soil degradation processes, defining their status and trend. Special attention has been given to Soil Quality Index (SQI determined by six predisposing indicators (parent material, soil texture, rock fragment, soil depth, drainage and slope grade. The integration in the SQI calculation of two additional soil parameters (organic matter content and soil salinity has been considered particularly significant. In fact, through the evaluation of a so “modified SQI” and the Apulia land use too, it could be possible to assess the role of agriculture management on soil degradation processes, which predisposing regional area to desertification threat. Moreover this approach provides short, but accurate, information thanks to GIS integration, which defines phenomena in detail, offering helpful planning tools.

  11. [Characteristics of soil microbes and enzyme activities in different degraded alpine meadows].

    Science.gov (United States)

    Yin, Ya Li; Wang, Yu Qin; Bao, Gen Sheng; Wang, Hong Sheng; Li, Shi Xiong; Song, Mei Ling; Shao, Bao Lian; Wen, Yu Cun

    2017-12-01

    Soil microbial biomass C and N, microbial diversities and enzyme activity in 0-10 cm and 10-20 cm soil layers of different degraded grasslands (non-degradation, ND; light degradation, LD; moderate degradation, MD; sever degradation, SD; and black soil beach, ED) were measured by Biolog and other methods. The results showed that: 1) There were significant diffe-rences between 0-10 cm and 10-20 cm soil layers in soil microbial biomass, diversities and inver-tase activities in all grasslands. 2) The ratio of soil microbial biomass C to N decreased significantly with the grassland degradation. In the 0-10 cm soil layer, microbial biomass C and N in ND and LD were significantly higher than that in MD, SD and ED. Among the latter three kinds of grasslands, there was no difference for microbial biomass C, but microbial biomass N was lower in MD than in the other grasslands. The average color change rate (AWCD) and McIntosh Index (U) also decreased with grassland degradation, but only the reduction from ND to MD was significant. There were no differences among all grasslands for Shannon index (H) and Simpson Index (D). The urease activity was highest in MD and SD, and the activity of phosphatase and invertase was lowest in ED. In the 10-20 cm soil layer, microbial biomass C in ND and LD were significantly higher than that in the other grasslands. Microbial biomass N in LD and ED were significantly higher than that in the other grasslands. Carbon metabolism index in MD was significantly lower than that in LD and SD. AWCD and U index in ND and LD were significantly higher than that in ED. H index and D index showed no difference among different grasslands. The urease activity in ND and MD was significantly higher than that in the other grasslands. The phosphatase activity was highest in MD, and the invertase activity was lowest in MD. 3) The belowground biomass was significantly positively correlated with microbial biomass, carbon metabolic index and phosphatase activity

  12. Effect of potassium fertilizers on 137Cs transfer from sandy soddy-podzolic soil to plants

    International Nuclear Information System (INIS)

    Belova, N.V.; Sanzharova, N.I.; Shishulina, M.V.; Moiseenko, F.V.; Vorob'eva, L.A.

    2009-01-01

    The purpose of the work is to study the behavior of potassium in sandy soddy podzolic soil and its influence on the availability of 137 Cs to plants of winter rye and lupine when applying various doses of potassium fertilizers (PF) and turf-manure compost (TMC). A many-years stationary experiment was established in the Bryansk region in 1986-1988 on soddy podzolic soil contaminated by the accident at the Chernobyl Power Station. The influence of fertilizer was studied in 4-field crop rotation in an experimental plot: seeded fallow (lupine, bird's-foot) – winter rye – potato – spring grains. Potassium and mineral fertilizers were applied. It was shown that the application of potassium fertilizers (from 0 to 180 kg/ha) increased the content of exchangeable potassium in the soil by 1.7-2-7 times and its mobility by 2.5-4.0 times which resulted in a decrease of 137Cs transfer to plants by 5.8-14 times. The inverse proportional relationship was found between the potassium mobility and the content of its mobile form and the accumulation coefficient of 137Cs by lupine and wheat rye plants. A linear relationship was reveled between the accumulation coefficient of 137Cs and the content of exchangeable radionuclide

  13. Degradation kinetics and safety evaluation of buprofezin residues in grape (Vitis vinifera L.) and three different soils of India.

    Science.gov (United States)

    Oulkar, Dasharath P; Banerjee, Kaushik; Patil, Sangram H; Upadhyay, Ajay K; Taware, Praveen B; Deshmukh, Madhukar B; Adsule, Pandurang G

    2009-02-01

    This work was undertaken to determine the preharvest interval (PHI) of buprofezin to minimize its residues in grapes and thereby ensure consumer safety and avoid possible non-compliance in terms of residue violations in export markets. Furthermore, the residue dynamics in three grapevine soils of India was explored to assess its environmental safety. Residues dissipated following non-linear two-compartment first + first-order kinetics. In grapes, the PHI was 31 days at both treatments (312.5 and 625 g a.i. ha(-1)), with the residues below the maximum permissible intake even 1 h after foliar spraying. Random sampling of 5 kg comprising small bunchlets (8-10 berries) collected from a 1 ha area gave satisfactory homogeneity and representation of the population. A survey on the samples harvested after the PHI from supervised vineyards that received treatment at the recommended dose showed residues below the maximum residue limit (MRL) of 0.02 mg kg(-1) applicable for the European Union. In soil, the degradation rate was fastest in clay soil, followed by sandy loam and silty clay, with a half-life within 16 days in all the soils. The recommendation of the PHI proved to be effective in minimizing buprofezin residues in grapes. Thus, this work is of high practical significance to the domestic and export grape industry of India to ensure safety compliance in respect of buprofezin residues, keeping in view the requirements of international trade.

  14. Atrazine and its metabolites degradation in mineral salts medium and soil using an enrichment culture.

    Science.gov (United States)

    Kumar, Anup; Singh, Neera

    2016-03-01

    An atrazine-degrading enrichment culture was used to study degradation of atrazine metabolites viz. hydroxyatrazine, deethylatrazine, and deisopropylatrazine in mineral salts medium. Results suggested that the enrichment culture was able to degrade only hydroxyatrazine, and it was used as the sole source of carbon and nitrogen. Hydroxyatrazine degradation slowed down when sucrose and/or ammonium hydrogen phosphate were supplemented as the additional sources of carbon and nitrogen, respectively. The enrichment culture could degrade high concentrations of atrazine (up to 110 μg/mL) in mineral salts medium, and neutral pH was optimum for atrazine degradation. Further, except in an acidic soil, enrichment culture was able to degrade atrazine in three soil types having different physico-chemical properties. Raising the pH of acidic soil to neutral or alkaline enabled the enrichment culture to degrade atrazine suggesting that acidic pH inhibited atrazine-degrading ability. The study suggested that the enrichment culture can be successfully utilized to achieve complete degradation of atrazine and its persistent metabolite hydroxyatrazine in the contaminated soil and water.

  15. Soil degradation in Sub-Saharan Africa

    NARCIS (Netherlands)

    Hartemink, A.E.; Keulen, van H.

    2005-01-01

    Soil degradation in Sub-Sahara Africa has been much debated in the past decades. Although there are many different views, at the extremes there are those who are of the opinion that the problem is very serious and the main cause for the poverty and food crises and those that are convinced that it is

  16. Proposal of new convenient extractant for assessing phytoavailability of heavy metals in contaminated sandy soil.

    Science.gov (United States)

    Korzeniowska, Jolanta; Stanislawska-Glubiak, Ewa

    2017-06-01

    The aim of the study was to compare the usefulness of 1 M HCl with aqua regia, EDTA, and CaCl 2 for the extraction of phytoavailable forms of Cu, Ni, and Zn on coarse-textured soils contaminated with these metals. Two microplot experiments were used for the studies. Reed canary grass (Phalaris arundinacea), maize (Zea mays), willow (Salix viminalis), spartina (Spartina pectinata), and miscanthus (Miscanthus × giganteus) were used as test plants. They were grown on soil artificially spiked with Cu, Ni, and Zn. The experimental design included a control and three increasing doses of metals. Microplots (1 m 2  × 1 m deep) were filled with sandy soil (clay-6%, pH 5.5, Corg-0.8%). Metals in the form of sulfates were dissolved in water and applied to the plot using a hand liquid sprayer. During the harvest, samples were collected from aboveground parts, roots, and the soil and then tested for their Cu, Zn, and Ni contents. The metal content of the soil was determined using four tested extractants. It was found that Cu and Ni were accumulated in roots in bigger amounts than Zn. The usefulness of the extractants was evaluated based on the correlation between the content of metals in the soil and the plant (n = 32). This study demonstrated that 1 M HCl, aqua regia, and EDTA were more efficient or equally useful for the assessment of the phytoavailability of Cu, Ni, and Zn as CaCl 2 . Due to the ease of performing determinations and their low cost, 1 M HCl can be recommended to assess the excess of Cu, Ni, and Zn in the coarse-textured soils.

  17. Study of the effect of the repeated incorporation of millet straw on the availability of nitrogen in a sandy tropical soil using 15N

    International Nuclear Information System (INIS)

    Guiraud, G.; Ganry, F.; Llimous, Gisele.

    1980-01-01

    In order to maintain the level of organic materials in the sandy soils of Senegal, compost was injected in these soils over a period of four consecutive years. The effects of this injection were studied by carrying out tests in pots with a nitrogen 15 labelled fertilizer. The use of compost significantly increased the amount of organic matter in the soil and led to higher yields. The nitrogen present is used by the culture, but appears to be insufficient. A proportion of this nitrogen is lost. Fertilizers still enable high yields to be maintained. The use of compost, however, enables an irreversible drop in the potential fertility of these soils over a longer term period to be avoided [fr

  18. Distribution of Anaerobic Hydrocarbon-Degrading Bacteria in Soils from King George Island, Maritime Antarctica.

    Science.gov (United States)

    Sampaio, Dayanna Souza; Almeida, Juliana Rodrigues Barboza; de Jesus, Hugo E; Rosado, Alexandre S; Seldin, Lucy; Jurelevicius, Diogo

    2017-11-01

    Anaerobic diesel fuel Arctic (DFA) degradation has already been demonstrated in Antarctic soils. However, studies comparing the distribution of anaerobic bacterial groups and of anaerobic hydrocarbon-degrading bacteria in Antarctic soils containing different concentrations of DFA are scarce. In this study, functional genes were used to study the diversity and distribution of anaerobic hydrocarbon-degrading bacteria (bamA, assA, and bssA) and of sulfate-reducing bacteria (SRB-apsR) in highly, intermediate, and non-DFA-contaminated soils collected during the summers of 2009, 2010, and 2011 from King George Island, Antarctica. Signatures of bamA genes were detected in all soils analyzed, whereas bssA and assA were found in only 4 of 10 soils. The concentration of DFA was the main factor influencing the distribution of bamA-containing bacteria and of SRB in the analyzed soils, as shown by PCR-DGGE results. bamA sequences related to genes previously described in Desulfuromonas, Lautropia, Magnetospirillum, Sulfuritalea, Rhodovolum, Rhodomicrobium, Azoarcus, Geobacter, Ramlibacter, and Gemmatimonas genera were dominant in King George Island soils. Although DFA modulated the distribution of bamA-hosting bacteria, DFA concentration was not related to bamA abundance in the soils studied here. This result suggests that King George Island soils show functional redundancy for aromatic hydrocarbon degradation. The results obtained in this study support the hypothesis that specialized anaerobic hydrocarbon-degrading bacteria have been selected by hydrocarbon concentrations present in King George Island soils.

  19. Effects of soil organic matter on the development of the microbial polycyclic aromatic hydrocarbons (PAHs) degradation potentials

    International Nuclear Information System (INIS)

    Yang, Y.; Zhang, N.; Xue, M.; Lu, S.T.; Tao, S.

    2011-01-01

    The microbial activity in soils was a critical factor governing the degradation of organic micro-pollutants. The present study was conducted to analyze the effects of soil organic matter on the development of degradation potentials for polycyclic aromatic hydrocarbons (PAHs). Most of the degradation kinetics for PAHs by the indigenous microorganisms developed in soils can be fitted with the Logistic growth models. The microbial activities were relatively lower in the soils with the lowest and highest organic matter content, which were likely due to the nutrition limit and PAH sequestration. The microbial activities developed in humic acid (HA) were much higher than those developed in humin, which was demonstrated to be able to sequester organic pollutants stronger. The results suggested that the nutrition support and sequestration were the two major mechanisms, that soil organic matter influenced the development of microbial PAHs degradation potentials. - Research highlights: → PAH degradation kinetics obey Logistic model. → Degradation potentials depend on soil organic carbon content. → Humin inhibits the development of PAH degradation activity. → Nutrition support and sequestration regulate microbial degradation capacity. - Soil organic matter regulated PAH degradation potentials through nutrition support and sequestration.

  20. Water Infiltration and Hydraulic Conductivity in Sandy Cambisols

    DEFF Research Database (Denmark)

    Bens, Oliver; Wahl, Niels Arne; Fischer, Holger

    2006-01-01

    from pure Scots pine stands towards pure European beech stands. The water infiltration capacity and hydraulic conductivity (K) of the investigated sandy-textured soils are low and very few macropores exist. Additionally these pores are marked by poor connectivity and therefore do not have any...... of the experimental soils. The results indicate clearly that soils play a crucial role for water retention and therefore, in overland flow prevention. There is a need to have more awareness on the intimate link between the land use and soil properties and their possible effects on flooding.......Soil hydrological properties like infiltration capacity and hydraulic conductivity have important consequences for hydrological properties of soils in river catchments and for flood risk prevention. They are dynamic properties due to varying land use management practices. The objective...

  1. Seasonal Dynamics of Water Use Strategy of Two Salix Shrubs in Alpine Sandy Land, Tibetan Plateau.

    Science.gov (United States)

    Zhu, Yajuan; Wang, Guojie; Li, Renqiang

    2016-01-01

    Water is a limiting factor for plant growth and vegetation dynamics in alpine sandy land of the Tibetan Plateau, especially with the increasing frequency of extreme precipitation events and drought caused by climate change. Therefore, a relatively stable water source from either deeper soil profiles or ground water is necessary for plant growth. Understanding the water use strategy of dominant species in the alpine sandy land ecosystem is important for vegetative rehabilitation and ecological restoration. The stable isotope methodology of δD, δ18O, and δ13C was used to determine main water source and long-term water use efficiency of Salix psammophila and S. cheilophila, two dominant shrubs on interdune of alpine sandy land in northeastern Tibetan Plateau. The root systems of two Salix shrubs were investigated to determine their distribution pattern. The results showed that S. psammophila and S. cheilophila absorbed soil water at different soil depths or ground water in different seasons, depending on water availability and water use strategy. Salix psammophila used ground water during the growing season and relied on shallow soil water recharged by rain in summer. Salix cheilophila used ground water in spring and summer, but relied on shallow soil water recharged by rain in spring and deep soil water recharged by ground water in fall. The two shrubs had dimorphic root systems, which is coincident with their water use strategy. Higher biomass of fine roots in S. psammophila and longer fine roots in S. cheilophila facilitated to absorb water in deeper soil layers. The long-term water use efficiency of two Salix shrubs increased during the dry season in spring. The long-term water use efficiency was higher in S. psammophila than in S. cheilophila, as the former species is better adapted to semiarid climate of alpine sandy land.

  2. Effects of acacia senegal (L.,Willd.) on sandy soils: A case study of El damokeya forest, Northern Kordofan State

    International Nuclear Information System (INIS)

    Ahmed, D. M; Nimer, A. M.

    2002-01-01

    Soil properties were studied in El Damokeya forest, located at 30 km east of Elobeid town, Northern Kordofan State, during the rainy season of 1998. The aim was to characterize the soils of the area and to examine the effects of Acacia senegal plantations on the soils physical and chemical properties. The results showed that the soils were sandy, weakly structured, yellowish-red, neutral and poor in nutrient content, and that Acacia senegal plantations had induced considerable changes in the soil morphological, physical and chemical properties. The soil became more differentiated, with a third layer clearly discernible. No change had occurred in the soil texture. But, it became well structured with stable aggregates. Its organic matter content had been augmented to about one and half times, deeply incorporated and stained the whole profile with darker hues. The soil reaction became slightly acidic (ph 6.3). The exchange capacity was improved qualitatively and quantitatively. Thus, cation exchange capacity values increased from 2.8 in the bare land to 4.0 meq/100g soil under the forest, and the soil was saturated to 98% with base cations. The major nutrient elements (N,P, K, Ca, Mg, Fe) had generally increased with various proportions ranging from 10% to more than 130%, but only Ca showed significant difference at P=0.05. Among the trace elements, Cu and Co had significantly decreased in the forest soil, but Zn and Mn had increased to about 100%.(Author)

  3. Soil Degradation, Land Scarcity and Food Security: Reviewing a Complex Challenge

    Directory of Open Access Journals (Sweden)

    Tiziano Gomiero

    2016-03-01

    Full Text Available Soil health, along with water supply, is the most valuable resource for humans, as human life depends on the soil’s generosity. Soil degradation, therefore, poses a threat to food security, as it reduces yield, forces farmers to use more inputs, and may eventually lead to soil abandonment. Unfortunately, the importance of preserving soil health appears to be overlooked by policy makers. In this paper, I first briefly introduce the present situation concerning agricultural production, natural resources, soil degradation, land use and the challenge ahead, to show how these issues are strictly interwoven. Then, I define soil degradation and present a review of its typologies and estimates at a global level. I discuss the importance of preserving soil capital, and its relationship to human civilization and food security. Trends concerning the availability of arable agricultural land, different scenarios, and their limitations, are analyzed and discussed. The possible relation between an increase in a country’s GNP, population and future availability of arable land is also analyzed, using the World Bank’s database. I argue that because of the many sources of uncertainty in the data, and the high risks at stake, a precautionary approach should be adopted when drawing scenarios. The paper ends with a discussion on the key role of preserving soil organic matter, and the need to adopt more sustainable agricultural practices. I also argue that both our relation with nature and natural resources and our lifestyle need to be reconsidered.

  4. Management-induced Soil Structure Degradation: Organic Matter Depletion and Tillage

    OpenAIRE

    Kay, B.D.; Munkholm, L.J.

    2004-01-01

    Soil structure is an important element of soil quality since changes in structural characteristics can cause changes in the ability of soil to fulfil different functions and services. Emphasis in this chapter is placed on the role of soil structure in biological productivity of agroecosystems. Combinations of management practices in which the extent of the degradation of soil structure caused by one practice is balanced or exceeded by the extent of regeneration by other practices will help su...

  5. Biogenic volatile organic compounds as a potential stimulator for organic contaminant degradation by soil microorganisms

    International Nuclear Information System (INIS)

    McLoughlin, Emma; Rhodes, Angela H.; Owen, Susan M.; Semple, Kirk T.

    2009-01-01

    The effects of monoterpenes on the degradation of 14 C-2,4-dichlorophenol (DCP) were investigated in soils collected from areas surrounding monoterpene and non-monoterpene-emitting vegetation. Indigenous microorganisms degraded 14 C-2,4-DCP to 14 CO 2 , after 1 d contact time. Degradation was enhanced by prior exposure of the soils to 2,4-DCP for 32 d, increasing extents of mineralisation up to 60%. Monoterpene amendments further enhanced 2,4-DCP degradation, but only following pre-exposure to both 2,4-DCP and monoterpene, with total 2,4-DCP mineralisation extents of up to 71%. Degradation was greatest at the higher monoterpene concentrations (≥1 μg kg -1 ). Total mineralisation extents were similar between concentrations, but higher than the control and the 0.1 μg kg -1 amendment, indicating that increases in monoterpene concentration has a diminishing enhancing effect. We suggest that monoterpenes can stimulate the biodegradation of 2,4-DCP by indigenous soil microorganisms and that monoterpene amendment in soils is an effective strategy for removing organic contaminants. - A amendment of soils with monoterpenes may induce organic contaminant degradation by indigenous soil microorganisms

  6. Real-Time Monitoring of Water Content in Sandy Soil Using Shear Mode Piezoceramic Transducers and Active Sensing—A Feasibility Study

    Directory of Open Access Journals (Sweden)

    Qingzhao Kong

    2017-10-01

    Full Text Available A quantitative understanding of soil water content or soil water status is of great importance to many applications, such as landslide monitoring, rockfill dam health monitoring, precision agriculture, etc. In this paper, a feasibility study was conducted to monitor the soil water content in real time using permanent embedded piezoceramic-based transducers called smart aggregates (SAs. An active sensing approach using a customized swept acoustic wave with a frequency range between 100 Hz and 300 kHz was used to study the wave attenuation in the soil in correlation to soil moisture levels. Two sandy soil specimens, each embedded with a pair of SAs, were made in the laboratory, and the water percentage of the soil specimens was incrementally decreased from 15% to 3% during the tests. Due to the change of the soil water status, the damping property of the soil correspondingly changes. The change of the damping property results in the variation of the acoustic wave attenuation ratios. A wavelet packet-based energy index was adopted to compute the energy of the signal captured by the SA sensor. Experimental results show a parabolic growth curve of the received signal energy vs. the water percentage of the soil. The feasibility, sensitivity, and reliability of the proposed method for in-situ monitoring of soil water status were discussed.

  7. The Influence of Cattle Wastes on Degraded Savanna Soils of ...

    African Journals Online (AJOL)

    This paper examines the effects of cattle wastes on degraded savanna soils of Kwara State, Nigeria. A total of 40 soil samples were systematically collected from five quadrats of 12m x 12m. In 4 identified cattle sheds and 1 in adjacent fallow land (control field) on the same soil, climatic type and ecological zone. Standard ...

  8. Combating land degradation: the potential of soil reconversion

    Science.gov (United States)

    Tobias, Silvia; Conen, Franz; Duss, Adrian; Wenzel, Leonore; Buser, Christine; Alewell, Christine

    2017-04-01

    Land degradation is usually not seen as a major problem in industrialised countries, although continuous soil sealing for human settlements and infrastructure entails the loss of agricultural land, landscape fragmentation and the loss of natural habitats. In many European countries, land-take on greenfields is unbowed, while, at the same time, there is a considerable number of unused brownfields, like abandoned rail yards and industrial or military sites. In addition, many new by-pass roads have been constructed to take up the volume of traffic and unburden the towns and villages from traffic emissions, but the old roads are rarely downgraded or reconverted and risk being used as shortcuts. Today the sealed area exceeds the requirements of the current generation and contributes to degraded land with heavily disturbed soil-borne ecosystem services. Soil reconversion, i.e. replacing a sealed surface with soil to restore ecosystem services, could mitigate this unsustainable trend that restricts the options of future generations. This contribution discusses the potential and challenges of soil reconversion to reduce net soil loss. The expanses of brownfield area vary between countries, whereas the rate of new soil sealing is still high in most countries and soil reconversion should be considered more. Our research revealed that the current techniques enable successful restoration of agricultural soils and pioneer habitats on site. However, reconverting single small areas can hardly mitigate landscape fragmentation at a regional scale. The same principle prevails as for soil sealing, but in the inverse way: the benefit of soil reconversion may appear small for single cases, but in the sum soil reconversion might be effective. Today, many brownfield areas stay sealed because of economic and political reasons, or because the potential benefit from restoring ecosystem services at these brownfield sites is not known. We developed a mapping approach to assess the potential

  9. Effect of different irrigation systems on root growth of maize and cowpea plants in sandy soil

    Directory of Open Access Journals (Sweden)

    Noha A. Mahgoub

    2017-10-01

    Full Text Available A field experiment was conducted at the Experimental Farm, Faculty of Agriculture, Suez Canal University to study the influence of different irrigation systems on root length density and specific root length of maize and cowpea plants cultivated in sandy soil. Three irrigation systems (Surface, drip and sprinkler irrigation were used in this study. The NPK fertilizers were applied as recommended doses for maize and cowpea. Root samples were collected from the soil profile below one plant (maize and cowpea which was irrigated by the three irrigation systems by using an iron box (30 cm× 20 cm which is divided into 24 small boxes each box is (5× 5 × 5 cm. At surface irrigation, root length density of cowpea reached to soil depth 30-40cm with lateral distances 5-10 cm and 15-20 cm. Vertical distribution of root length density of maize was increased with soil depth till 20-25 cm, and then it decreased till soil depth 35-40cm. Under drip irrigation, root length density of cowpea increased horizontally from 0-5cm to 10-15cm then it decreased till soil depth 25-30 cm and below this depth root length density disappeared. For the root length density and specific root length of maize under drip irrigation, the data showed that root length density and specific root length decreased with increasing in soil depth. The root length density of cowpea under sprinkler irrigation at 0-5cm disappeared from horizontal distance at 25-30 cm. The data showed that root length density of maize under sprinkler irrigation was higher at the soil top layers 0-5 cm and 5-10 cm than other layers from 10-40 cm.

  10. Soil color indicates carbon and wetlands: developing a color-proxy for soil organic carbon and wetland boundaries on sandy coastal plains in South Africa.

    Science.gov (United States)

    Pretorius, M L; Van Huyssteen, C W; Brown, L R

    2017-10-13

    A relationship between soil organic carbon and soil color is acknowledged-albeit not a direct one. Since heightened carbon contents can be an indicator of wetlands, a quantifiable relationship between color and carbon might assist in determining wetland boundaries by rapid, field-based appraisal. The overarching aim of this initial study was to determine the potential of top soil color to indicate soil organic carbon, and by extension wetland boundaries, on a sandy coastal plain in South Africa. Data were collected from four wetland types in northern KwaZulu-Natal in South Africa. Soil samples were taken to a depth of 300 mm in three transects in each wetland type and analyzed for soil organic carbon. The matrix color was described using a Munsell soil color chart. Various color indices were correlated with soil organic carbon. The relationship between color and carbon were further elucidated using segmented quantile regression. This showed that potentially maximal carbon contents will occur at values of low color indices, and predictably minimal carbon contents will occur at values of low or high color indices. Threshold values can thus be used to make deductions such as "when the sum of dry and wet Value and Chroma values is 9 or more, carbon content will be 4.79% and less." These threshold values can then be used to differentiate between wetland and non-wetland sites with a 70 to 100% certainty. This study successfully developed a quantifiable correlation between color and carbon and showed that wetland boundaries can be determined based thereon.

  11. Effect of charcoal amendment on adsorption, leaching and degradation of isoproturon in soils

    Science.gov (United States)

    Si, Youbin; Wang, Midao; Tian, Chao; Zhou, Jing; Zhou, Dongmei

    2011-04-01

    The effects of charcoal amendment on adsorption, leaching and degradation of the herbicide isoproturon in soils were studied under laboratory conditions. The adsorption data all fitted well with the Freundlich empirical equation. It was found that the adsorption of isoproturon in soils increased with the rate of charcoal amended (correlation coefficient r = 0.957 **, P isoproturon in leachate decreased with the increase of the amount of charcoal addition to soil column, while the retention of isoproturon in soils increased with an increase in the charcoal content of soil samples. Biodegradation was still the most significant mechanism for isoproturon dissipation from soil. Charcoal amendment greatly reduced the biodegradation of isoproturon in soils. The half-lives of isoproturon degradation ( DT50) in soils greatly extended when the rate of added charcoal inceased from 0 to 50 g kg - 1 (for Paddy soil, DT50 values increased from 54.6 to 71.4 days; for Alfisol, DT50 from 16.0 to 136 days; and for Vertisol, DT50 from 15.2 to 107 days). The degradation rate of isoproturon in soils was significantly negatively correlated with the amount of added charcoal. This research suggests that charcoal amendment may be an effective management practice for reducing pesticide leaching and enhancing its persistence in soils.

  12. Pore-size distribution and compressibility of coarse sandy subsoil with added biochar

    DEFF Research Database (Denmark)

    Petersen, C. T.; Hansen, E.; Larsen, H. H.

    2016-01-01

    Sustainable agricultural production on coarse sandy soil is constrained by the restricted growth of roots, and poor water and nutrient retention. Amending the soil with biochar can reduce these problems, but the processes involved are not known in detail. We investigated in the laboratory...... the effects of two fine-grained gasification biochars made of straw (LTST) and other materials (LTSN) and of one fast pyrolysis straw biochar (FPST) on pore-size distribution and soil compressibility when added to coarse sandy subsoil. Water retention and therefore pore-size distribution were affected...... systematically. All biochars converted drainable pore space with pore diameters in the range 60–300 µm into water-retaining pores of size 0.2–60 µm, which was taken as an estimate of available water capacity (AWC). Effects were linear over the whole range of biochar (0–4% by mass). The effect of LTST and LTSN...

  13. Dynamic changes in functional gene copy numbers and microbial communities during degradation of pyrene in soils

    International Nuclear Information System (INIS)

    Peng Jingjing; Cai Chao; Qiao Min; Li Hong; Zhu Yongguan

    2010-01-01

    This study investigates the dynamics of pyrene degradation rates, microbial communities, and functional gene copy numbers during the incubation of pyrene-spiked soils. Spiking pyrene to the soil was found to have negligible effects on the bacterial community present. Our results demonstrated that there was a significant difference in nidA gene copy numbers between sampling dates in QZ soil. Mycobacterium 16S rDNA clone libraries showed that more than 90% mycobacteria detected were closely related to fast-growing PAH-degrading Mycobacterium in pyrene-spiked soil, while other sequences related to slow-growing Mycobacterium were only detected in the control soil. It is suggested that nidA gene copy number and fast-growing PAH-degrading Mycobacterium could be used as indicators to predict pyrene contamination and its degradation activity in soils. - nidA gene and fast-growing PAH-degrading Mycobacterium can serve as indicators for pyrene contamination.

  14. Degradation of soil cyanide by single and mixed cultures of Pseudomonas stutzeri and Bacillus subtilis.

    Science.gov (United States)

    Nwokoro, Ogbonnaya; Dibua, Marie Esther Uju

    2014-03-01

    The aim of this investigation was to study whether certain bacteria could be used for cyanide degradation in soil. The bacteria Pseudomonas stutzeri and Bacillus subtilis were selected based on their good growth in a minimal medium containing 0.8 mg mL-1 potassium cyanide (KCN). In this study we tested their ability to reduce cyanide levels in a medium containing 1.5 mg mL-1 of KCN. Although both microorganisms reduced cyanide levels, Pseudomonas stutzeri was the more effective test organism. Later on, the selected cultures were grown, diluted and their various cell concentrations were used individually and in combination to test their ability of cyanide degradation in soil samples collected around a cassava processing mill. Bacillus subtilis caused degradation of soil cyanide from 0.218 mg g-1 soil immediately with an inoculum concentration of 0.1 (OD600nm) to 0.072 mg g-1 soil after 10 days with an inoculum concentration of 0.6 (OD600nm) implying a 66.9 % reduction. Pseudomonas stutzeri cell concentration of 0.1 (OD600nm) decreased soil cyanide from 0.218 mg g-1 soil initially to 0.061 mg g-1 soil after 10 days with an inoculum concentration of 0.6 (OD600nm) (72 % reduction). The mixed culture of the two bacteria produced the best degradation of soil cyanide from 0.218 mg g-1 soil sample with a combined inoculum concentration of 0.1 (OD600nm) initially to 0.025 mg g-1 soil with a combined inoculum concentration of 0.6 (OD600nm) after 10 days incubation resulting in an 88.5 % degradation of soil cyanide. The analysed bacteria displayed high cyanide degradation potential and may be useful for efficient decontamination of cyanide contaminated sites.

  15. Residues of Avermectin B1a in rotational crops and soils following soil treatment with [14C]Avermectin B1a

    International Nuclear Information System (INIS)

    Moye, H.A.; Malagodi, M.H.; Yoh, H.; Leibee, G.L.; Ku, C.C.; Wislocki, P.G.

    1987-01-01

    [ 14 C]Avermectin B 1 a was applied twelve times to muck and sandy loam soils and three times to sandy soil at 0.025-0.030 lb/acre per application. These applications simulated the intended use of avermectin B 1 a on celery, vegetables, and cotton, respectively. Following three aging periods in each soil type, sorghum, lettuce, and carrot or turnip seeds were planted and harvested at one-fourth, half, and full size. Analysis of these crops by oxidative combustion demonstrated that crops grown in muck, sandy loam, and sandy soils contained radiolabeled residues ranging from below the limit of quantitation (BLQ) to 7.4 μg/kg of avermectin B 1 a equivalents, BLQ to 11.6 μg/kg, and BLQ to 3.54 μg/kg, respectively. There was a general trend of decreasing residue concentrations with increasing preharvest intervals in crops grown in all soils. The radioactivity present in muck and sandy loam soils disappeared with half-lives ranging from 103 to 267 days and from 102 to 132 days, respectively

  16. Degradation of 2,4-D in soils by Fe₃O₄ nanoparticles combined with stimulating indigenous microbes.

    Science.gov (United States)

    Fang, Guodong; Si, Youbin; Tian, Chao; Zhang, Gangya; Zhou, Dongmei

    2012-03-01

    Degradation of 2,4-dichlorophenoxyacetic acid (2,4-D) in soils by Fe₃O₄ nanoparticles combined with soil indigenous microbes was investigated, and the effects of Fe₃O₄ nanoparticles on soil microbial populations and enzyme activities were also studied. The soils contaminated with 2,4-D were treated with Fe₃O₄ nanoparticles. The microbial populations and enzyme activities were analyzed by dilution plate method and chemical assay, respectively, and the concentration of 2,4-D in soil was determined by high-performance liquid chromatography (HPLC). The results indicated that Fe₃O₄ nanoparticles combined with soil indigenous microbes led to a higher degradation efficiency of 2,4-D than the treatments with Fe₃O₄ nanoparticles or indigenous microbes alone. The degradation of 2,4-D in soils followed the pseudo first-order kinetic. The half-lives of 2,4-D degradation (DT₅₀) of the combined treatments were 0.9, 1.9 and 3.1 days in a Red soil, Vertisol and Alfisol, respectively, which implied that the DT₅₀ of the combination treatments were significantly shorter than that of the treatments Fe₃O₄ nanoparticles or indigenous microbes alone. The effects of Fe₃O₄ nanoparticles on soil microbial populations and enzyme activities were also investigated and compared with the α-Fe₂O₃ nanoparticles. The results suggested that the α-Fe₂O₃ nanoparticles had only comparatively small effects on degradation of 2,4-D in soils, while the Fe₃O₄ nanoparticles not only degraded 2,4-D in soils but also increased the soil microbial populations and enzyme activities; the maximum increase in enzyme activities were 67.8% (amylase), 53.8% (acid phosphatase), 26.5% (catalase) and 38.0% (urease), compared with the untreated soil. Moreover, the introduction of Fe₃O₄ nanoparticles at the different dosage resulted in a variable degradation efficiency of 2,4-D in soil. The method of combining Fe₃O₄ nanoparticles with indigenous soil microbes may

  17. Changes in Flow and Transport Patterns in Fen Peat as a Result of Soil Degradation

    Science.gov (United States)

    Liu, Haojie; Janssen, Manon; Lennartz, Bernd

    2016-04-01

    The preferential movement of water and transport of substances play an important role in soils and are not yet fully understood especially in degraded peat soils. In this study, we aimed at deducing changes in flow and transport patterns in the course of soil degradation as resulting from peat drainage, using titanium dioxide (TiO2) as a dye tracer. The dye tracer experiments were conducted on columns of eight types of differently degraded peat soils from three sites taken both in vertical and horizontal directions. The titanium dioxide suspension (average particle size of 0.3 μm; 10 g l-1) was applied in a pulse of 40 mm to each soil core. Twenty-four hours after the application of the tracer, cross sections of the soil cores were prepared for photo documentation. In addition, the saturated hydraulic conductivity (Ks) was determined. Preferential flow occurred in all investigated peat types. From the stained soil structural elements, we concluded that undecomposed plant remains are the major preferential flow pathways in less degraded peat. For more strongly degraded peat, bio-pores, such as root and earthworm channels, operated as the major transport domain. Results show that Ks and the effective pore network in less degraded peat soils are anisotropic. With increasing peat degradation, the Ks and cross section of effective pore network decreased. The results also indicate a strong positive relationship between Ks and number of macropores as well as pore continuity. Hence, we conclude that changes in flow and transport pathways as well as Ks with an increasing peat degradation are due to the disintegration of the peat forming plant material and decrement of number and continuity of macropores after drainage.

  18. Occurrence of Hydrocarbon Degrading Genes in the Soils of the Republic of Tatarstan (Russia)

    Science.gov (United States)

    Biktasheva, L. R.; Shalyamova, R. P.; Guseva, U. A.; Galitskaya, P. Yu

    2018-01-01

    Oil pollution is one of the most serious environmental problems nowadays. The ability of soils for self-restoration is important, when choosing the strategy of pollution control. This ability depends on the pull of microbes able to decompose hydrocarbons that were present in the nonpolluted soil prior to pollution. In this study, the occurrence of alkane degrading genes in the soils of the Republic of Tatarstan being one of the oil processing regions in Russia, was investigated. It was found that alkane degrading genes belonging to group I were present in 20 of the 25 soil samples, and their abundances ranged between 0.01 and 0.07%. Alkane degrading genes belonging to group II were not detected in the samples investigated, and those belonging to group III were present in all the samples, and their abundances ranged between 0.06 and 7.25%. No correlation between the alkane degrading gene copy numbers and pH and organic carbon content in soils was revealed.

  19. Use of mycelia as paths for the isolation of contaminant‐degrading bacteria from soil

    Science.gov (United States)

    Furuno, Shoko; Remer, Rita; Chatzinotas, Antonis; Harms, Hauke; Wick, Lukas Y.

    2012-01-01

    Summary Mycelia of fungi and soil oomycetes have recently been found to act as effective paths boosting bacterial mobility and bioaccessibility of contaminants in vadose environments. In this study, we demonstrate that mycelia can be used for targeted separation and isolation of contaminant‐degrading bacteria from soil. In a ‘proof of concept’ study we developed a novel approach to isolate bacteria from contaminated soil using mycelia of the soil oomycete Pythium ultimum as translocation networks for bacteria and the polycyclic aromatic hydrocarbon naphthalene (NAPH) as selective carbon source. NAPH‐degrading bacterial isolates were affiliated with the genera Xanthomonas, Rhodococcus and Pseudomonas. Except for Rhodococcus the NAPH‐degrading isolates exhibited significant motility as observed in standard swarming and swimming motility assays. All steps of the isolation procedures were followed by cultivation‐independent terminal 16S rRNA gene terminal fragment length polymorphism (T‐RFLP) analysis. Interestingly, a high similarity (63%) between both the cultivable NAPH‐degrading migrant and the cultivable parent soil bacterial community profiles was observed. This suggests that mycelial networks generally confer mobility to native, contaminant‐degrading soil bacteria. Targeted, mycelia‐based dispersal hence may have high potential for the isolation of bacteria with biotechnologically useful properties. PMID:22014110

  20. Assessment of soil degradation and chemical compositions in Rwandan tea-growing areas

    Directory of Open Access Journals (Sweden)

    Jean de la Paix Mupenzi

    2011-10-01

    Full Text Available This study has focused on the processes of soil degradation and chemical element concentration in tea-growing regions of Rwanda, Africa. Soil degradation accelerated by erosion is caused not only by topography but also by human activities. This soil degradation involves both the physical loss and reduction in the amount of topsoil associated with nutrient decline. Soil samples were collected from eleven tropical zones in Rwanda and from variable depth within each collecting site. Of these, Samples from three locations in each zone were analyzed in the laboratory, with the result that the pH of all soil samples is shown to be less than 5 (pH<5 with a general average of 4.4. The elements such as iron (Fe, copper (Cu, manganese (Mn, and zinc (Zn are present in high concentration levels. In contrast calcium (Ca and sodium (Na are present at low-level concentrations and carbon (C was found in minimal concentrations. In addition, elements derived from fertilizers, such as nitrogen (N, phosphorous (P, and potassium (K which is also from minerals such as feldspar, are also present in low-level concentrations. The results indicate that the soil in certain Rwandan tea plantations is acidic and that this level of pH may help explain, in addition to natural factors, the deficiency of some elements such as Ca, Mg, P and N. The use of chemical fertilizers, land use system and the location of fields relative to household plots are also considered to help explain why tea plantation soils are typically degraded.

  1. Naphthalene and pyrene degradation in contaminated soil as a ...

    African Journals Online (AJOL)

    The effect of soil particle size distribution and percent organic matter on the degradation rate of naphthalene and pyrene in a water medium of 7.05 ml/min at 27 ± 2oC in a soil reactor was studied. Analysis of the pattern of disappearance of these polycyclic aromatic hydrocarbons (PAHs) using various particle sizes showed ...

  2. The effect of soil type on the bioremediation of petroleum contaminated soils.

    Science.gov (United States)

    Haghollahi, Ali; Fazaelipoor, Mohammad Hassan; Schaffie, Mahin

    2016-09-15

    In this research the bioremediation of four different types of contaminated soils was monitored as a function of time and moisture content. The soils were categorized as sandy soil containing 100% sand (type I), clay soil containing more than 95% clay (type II), coarse grained soil containing 68% gravel and 32% sand (type III), and coarse grained with high clay content containing 40% gravel, 20% sand, and 40% clay (type IV). The initially clean soils were contaminated with gasoil to the concentration of 100 g/kg, and left on the floor for the evaporation of light hydrocarbons. A full factorial experimental design with soil type (four levels), and moisture content (10 and 20%) as the factors was employed. The soils were inoculated with petroleum degrading microorganisms. Soil samples were taken on days 90, 180, and 270, and the residual total petroleum hydrocarbon (TPH) was extracted using soxhlet apparatus. The moisture content of the soils was kept almost constant during the process by intermittent addition of water. The results showed that the efficiency of bioremediation was affected significantly by the soil type (Pvalue soil with the initial TPH content of 69.62 g/kg, and the lowest for the clay soil (23.5%) with the initial TPH content of 69.70 g/kg. The effect of moisture content on bioremediation was not statistically significant for the investigated levels. The removal percentage in the clay soil was improved to 57% (within a month) in a separate experiment by more frequent mixing of the soil, indicating low availability of oxygen as a reason for low degradation of hydrocarbons in the clay soil. Copyright © 2016 Elsevier Ltd. All rights reserved.

  3. Insight in the PCB-degrading functional community in long-term contaminated soil under bioremediation

    Energy Technology Data Exchange (ETDEWEB)

    Petric, Ines; Hrsak, Dubravka; Udikovic-Kolic, Nikolina [Ruder Boskovic Inst., Division for Marine and Environmental Research, Zagreb (Croatia); Fingler, Sanja [Inst. for Medical Research and Occupational Health, Zagreb (Croatia); Bru, David; Martin-Laurent, Fabrice [INRA, Univ. der Bourgogne, Soil and Environmental Microbiology, Dijon (France)

    2011-02-15

    A small-scale bioremediation assay was developed in order to get insight into the functioning of a polychlorinated biphenyl (PCB) degrading community during the time course of bioremediation treatment of a contaminated soil. The study was conducted with the aim to better understand the key mechanisms involved in PCB-removal from soils. Materials and methods Two bioremediation strategies were applied in the assay: (a) biostimulation (addition of carvone as inducer of biphenyl pathway, soya lecithin for improving PCB bioavailability, and xylose as supplemental carbon source) and (b) bioaugmentation with selected seed cultures TSZ7 or Rhodococcus sp. Z6 originating from the transformer station soil and showing substantial PCB-degrading activity. Functional PCB-degrading community was investigated by using molecular-based approaches (sequencing, qPCR) targeting bphA and bphC genes, coding key enzymes of the upper biphenyl pathway, in soil DNA extracts. In addition, kinetics of PCBs removal during the bioremediation treatment was determined using gas chromatography mass spectrometry analyses. Results and discussion bphA-based phylogeny revealed that bioremediation affected the structure of the PCB-degrading community in soils, with Rhodococcus-like bacterial populations developing as dominant members. Tracking of this population further indicated that applied bioremediation treatments led to its enrichment within the PCB-degrading community. The abundance of the PCB-degrading community, estimated by quantifying the copy number of bphA and bphC genes, revealed that it represented up to 0.3% of the total bacterial community. All bioremediation treatments were shown to enhance PCB reduction in soils, with approximately 40% of total PCBs being removed during a 1-year period. The faster PCB reduction achieved in bioaugmented soils suggested an important role of the seed cultures in bioremediation processes. Conclusions The PCBs degrading community was modified in response to

  4. Bioremediation of hydrocarbon degradation in a petroleum-contaminated soil and microbial population and activity determination.

    Science.gov (United States)

    Wu, Manli; Li, Wei; Dick, Warren A; Ye, Xiqiong; Chen, Kaili; Kost, David; Chen, Liming

    2017-02-01

    Bioremediation of hydrocarbon degradation in petroleum-polluted soil is carried out by various microorganisms. However, little information is available for the relationships between hydrocarbon degradation rates in petroleum-contaminated soil and microbial population and activity in laboratory assay. In a microcosm study, degradation rate and efficiency of total petroleum hydrocarbons (TPH), alkanes, and polycyclic aromatic hydrocarbons (PAH) in a petroleum-contaminated soil were determined using an infrared photometer oil content analyzer and a gas chromatography mass spectrometry (GC-MS). Also, the populations of TPH, alkane, and PAH degraders were enumerated by a modified most probable number (MPN) procedure, and the hydrocarbon degrading activities of these degraders were determined by the Biolog (MT2) MicroPlates assay. Results showed linear correlations between the TPH and alkane degradation rates and the population and activity increases of TPH and alkane degraders, but no correlation was observed between the PAH degradation rates and the PAH population and activity increases. Petroleum hydrocarbon degrading microbial population measured by MPN was significantly correlated with metabolic activity in the Biolog assay. The results suggest that the MPN procedure and the Biolog assay are efficient methods for assessing the rates of TPH and alkane, but not PAH, bioremediation in oil-contaminated soil in laboratory. Copyright © 2016 Elsevier Ltd. All rights reserved.

  5. Sorption and degradation of wastewater-associated pharmaceuticals and personal care products in agricultural soils and sediment.

    Science.gov (United States)

    Zhang, Ting; Wu, Bo; Sun, Na; Ye, Yong; Chen, Huaixia

    2013-01-01

    Pharmaceuticals and personal care products (PPCPs) have drawn popular concerns recently as an emerging class of aquatic contaminants. In this study, adsorption and degradation of four selected PPCPs, metronidazole, tinidazole, caffeine and chloramphenicol, have been investigated in the laboratory using two agricultural soils in China and sediment from Changjiang River. Adsorption tests using a batch equilibrium method demonstrated that adsorption of all tested chemicals in soils could be well described with Freundlich equation, and their adsorption affinity on soil followed the order of chloramphenicol > caffeine > tinidazole > metronidazole. Generally, higher Kf value was associated with soils which had higher organic matter contents (except for caffeine acid in this study). Degradation of selected PPCPs in soils generally followed first-order exponential decay kinetics, and half-lives ranging from 0.97 to 10.21 d. Sterilization generally decreased the degradation rates, indicating that microbial activity played a significant role in the degradation in soils. The degradation rate constant decreased with increasing initial chemical concentrations in soil, implying that the microbial activity was inhibited with high chemical loading levels.

  6. Analytical tools for assessing land degradation and its impact on soil quality

    Science.gov (United States)

    Bindraban, P. S.; Mantel, S.; Bai, Z.; de Jong, R.

    2010-05-01

    Maintaining and enhancing the quality of land is of major importance to sustain future production capacity for food and other agriculture based products like fibers and wood, and for maintaining ecosystems services, including below and above ground biodiversity, provision of soil water and sequestration of carbon. Deterioration of this production base will be detrimental to the provision of the foreseen dramatic increase in human needs for goods and services. For this reason, land degradation, defined as a long-term loss in ecosystem function and productivity, has to be understood properly. Climate, soils, topography and socioeconomic activities are primary factors that can cause, by themselves or in combination, a number of temporary or permanent changes in the landscape, leading to degradation of vegetation and soils. For identifying intervention measures to prevent and revert trends of land deterioration, it is fundamental to know the extent of land degradation and to understand its impact on functional properties of land. To assess the global extent, (Bai et al. 2008) apply a remotely sensed vegetation index that describes the greenness of the vegetation cover as a proxy for biomass. Biomass production has been identified as a strong indicator for soil quality as it is an integral measure for soil, crop and environmental characteristics (Bindraban et al., 2000). Bai and colleagues observed that 24% of the global land has been degrading over the past 26 years - often in very productive areas. The relation with functional properties of land can be made through ecosystem models. Mantel et al. (1999; 2000) applied dynamic crop-soil models to calculate crop productivity at the national level. A baseline scenario that represents the current conditions and a scenario for 20 years of prolonged sheet erosion were modeled to calculate the productivity impact of topsoil erosion for wheat in Uruguay and for maize in Kenya. They concluded that topsoil erosion primarily

  7. Evidence for the microbial degradation of imidacloprid in soils of Cameron Highlands

    Directory of Open Access Journals (Sweden)

    Nasrin Sabourmoghaddam

    2015-06-01

    Full Text Available Imidacloprid (1-[(6-chloro-3-pyridinylmethyl]-N-nitro-2-imidazolidinimine, with a novel mode of action is a recent systemic and contact insecticide with high activity against a wide range of pests. Continuous dispersion of this pesticide in the environment and its stability in soil results in environmental pollution which demands remediation. The present research was attempted to isolate and characterize imidacloprid degrading bacteria from vegetable farms of Cameron Highlands in Malaysia. The degradation ability of the isolates was tested in minimal salt medium (MSM for a duration of 25 days and the selected strains were characterized based on their biochemical and molecular characteristics. Levels of imidacloprid in MSM medium were analyzed by high performance liquid chromatography (HPLC. Among 50 soil bacterial isolates Bacillus sp., Brevibacterium sp., Pseudomonas putida F1, Bacillus subtilis and Rhizobium sp. were able to degrade 25.36–45.48% of the initial amount of imidacloprid at the concentration of 25 mg L−1 in C limited media. Brevibacterium sp. was isolated from organic farms that had never been exposed to imidacloprid while the other farms had previously been exposed to different levels of imidacloprid. All bacteria introduced in this study were among the first reports of imidacloprid degrading isolates in C limited media from tropical soil. Therefore, the results of this study demonstrate the effectiveness of using soil bacteria for microbial degradation of imidacloprid. These findings suggest that these strains may be promising candidates for bioremediation of imidacloprid-contaminated soils.

  8. Degradation of polycyclic aromatic hydrocarbons by microbial consortia enriched from three soils using two different culture media

    International Nuclear Information System (INIS)

    Wu, Manli; Chen, Liming; Tian, Yongqiang; Ding, Yi; Dick, Warren A.

    2013-01-01

    A consortium composed of many different bacterial species is required to efficiently degrade polycyclic aromatic hydrocarbons (PAH) in oil-contaminated soil. We obtained six PAH-degrading microbial consortia from three oil-contaminated soils using two different isolation culture media. Denaturing gradient gel electrophoresis (DGGE) and sequence analyses of amplified 16s rRNA genes confirmed the bacterial community was greatly affected by both the culture medium and the soil from which the consortia were enriched. Three bacterial consortia enriched using malt yeast extract (MYE) medium showed higher degradation rates of PAHs than consortia enriched using Luria broth (LB) medium. Consortia obtained from a soil and then added back to that same soil was more effective in degrading PAHs than adding, to the same soil, consortia isolated from other, unrelated soils. This suggests that inoculum used for bioremediation should be from the same, or very similar nearby soils, as the soil that is actually being bioremediated. -- Highlights: •Six PAH-degrading microbial consortia were isolated from three oil-contaminated soils. •The bacterial community by 16s rRNA genes was affected by culture media and source soil. •Inoculum should be from the same or similar soil as the soil being bioremediated. -- Bioremediation of oil-contaminated soils was most effective when using inoculum of microbial consortia from the same or similar soil as the soil being bioremediated

  9. Assessing soil water repellency of a sandy field with visible near infrared spectroscopy

    DEFF Research Database (Denmark)

    Knadel, Maria; Masis Melendez, Federico; de Jonge, Lis Wollesen

    2016-01-01

    . A lower prediction error of the WR model for soils dried at 105°C (1.93 mN m–1) than at 60°C (2.52 mN m–1) can be explained by a lower range of WR values for the soils dried at 105°C. Moreover, a higher temperature reduced the number of absorption bands related to OM, indicating a degradation......Soil water repellency (WR) is a widespread phenomenon caused by aggregated organic matter (OM) and layers of hydrophobic organic substances coating the surface of soil particles. These substances have a very low surface free energy, reducing a soil’s water attraction. There is focus on WR due...... to its effects on germination, root growth, liquid–vapour dynamics, surface erosion and leaching of chemicals through fingered flow paths. However, common techniques for measuring WR are time-consuming and expensive. Meanwhile, it is well established that visible near infrared (vis-NIR) spectroscopy...

  10. Crude oil degradation potential of bacteria isolated from oil-polluted soil and animal wastes in soil amended with animal wastes

    Directory of Open Access Journals (Sweden)

    Voke O. Urhibo

    2017-03-01

    Full Text Available The influence of animal wastes on crude oil degradation potential of strains of Proteus vulgaris and Bacillus subtilis isolated from animal wastes (poultry and pig droppings and petroleum-polluted soil was compared in laboratory studies. Both bacterial strains were selected for high crude oil degradation ability after screening many isolates by the 2,6-dichlorophenol indophenol method. Analyses by gas chromatography (GC showed that degradation of crude oil was markedly enhanced (88.3–97.3% vs 72.1–78.8% in soil amended with animal wastes as indicated by the reduction of total petroleum hydrocarbon (TPH. TPH reduction by animal waste bacterial strains in animal waste-amended soil was more than the reduction by strains from soil contaminated with petroleum (P < 0.001. The greatest reduction of TPH (96.6–97.3% vs 80.4–95.9% was by poultry waste strains and it occurred in soil amended with poultry waste. GC analyses of n-alkanes showed that although shorter chains were preferentially degraded [32.0–78.5% (C8–23 vs 6.3–18.5% (C24–36] in normal soil, biodegradation of longer chains increased to 38.4–46.3% in animal waste-amended soil inoculated with the same animal wastes’ strains. The results indicate that these animal waste strains may be of potential application for bioremediation of oil-polluted soil in the presence of the wastes from where they were isolated.

  11. Indicators and degradation mechanisam of loess soil

    Directory of Open Access Journals (Sweden)

    Gajić Grozdana

    2016-01-01

    Full Text Available Studies that are presented in this paper were carried out to define the formation criteria of loess soil degradation. Erosion stability analysis of this soil type will be carried out on the basis of its physical and mechanical characteristics. To describe the established relationships between the individual parameters of loess soil, the study uses mathematical model, that is based on experimentally obtained results of soils’ physical and mechanical characteristics, From the presented results of geotechnical tests, mathematical models and functional relations between water regime and loess soils’ resistant characteristics; indicators of internal erosion were defined as well as the mechanism of this process. Effects of the practical application of found results are also analyzed in this paper.

  12. Bioremediation of soil contaminated by dichlorodiphenyltrichloroethane with the use of aerobic strain Rhodococcus wratislaviensis Ch628

    Science.gov (United States)

    Egorova, D. O.; Farafonova, V. V.; Shestakova, E. A.; Andreyev, D. N.; Maksimov, A. S.; Vasyanin, A. N.; Buzmakov, S. A.; Plotnikova, E. G.

    2017-10-01

    The concentration of dichlorodiphenyltrichloroethane (DDT) was determined in a sandy soil of specially Protected Natural Area Osinskaya Lesnaya Dacha (Perm region) 45 years after the last application of the insecticide in this area. The concentration of DDT in the soil exceeded the maximum permissible concentration by 250 times and reached 25.05 mg/kg of soil. Under the conditions of model experiment, efficient decontamination of the soil was recorded in the system with the introduced strain Rhodococcus wratislaviensis Ch628; the DDT concentration decreased by 99.7% and equaled 0.07 mg/kg. The process of DDT degradation proceeded slower in the model soil system with autochthonous microbial complex. In this case, 58.2% DDT degraded in 70 days, and the final concentration was 10.47 mg/kg. The soil lost its toxicity for animal and plant test objects by the end of the experiment only in the model system containing the R. wratislaviensis Ch628 strain.

  13. Effect of sunlight irradiation on photocatalytic pyrene degradation in contaminated soils by micro-nano size TiO2

    International Nuclear Information System (INIS)

    Chang Chien, S.W.; Chang, C.H.; Chen, S.H.; Wang, M.C.; Madhava Rao, M.; Satya Veni, S.

    2011-01-01

    The enhanced catalytic pyrene degradation in quartz sand and alluvial and red soils by micro-nano size TiO 2 in the presence and absence of sunlight was investigated. The results showed that the synergistic effect of sunlight irradiation and TiO 2 was more efficient on pyrene degradation in quartz sand and red and alluvial soils than the corresponding reaction system without sunlight irradiation. In the presence of sunlight irradiation, the photooxidation (without TiO 2 ) of pyrene was very pronounced in alluvial and red soils and especially in quartz sand. However, in the absence of sunlight irradiation, the catalytic pyrene degradation by TiO 2 and the photooxidation (without TiO 2 ) of pyrene were almost nil. This implicates that ultra-violet (UV) wavelength range of sunlight plays an important role in TiO 2 -enhanced photocatalytic pyrene degradation and in photooxidation (without TiO 2 ) of pyrene. The percentages of photocatalytic pyrene degradation by TiO 2 in quartz sand, alluvial and red soils under sunlight irradiation were 78.3, 23.4, and 31.8%, respectively, at 5 h reaction period with a 5% (w/w) dose of the amended catalyst. The sequence of TiO 2 -enhanced catalytic pyrene degradation in quartz sand and alluvial and red soils was quartz sand > red soil > alluvial soil, due to different texture and total organic carbon (TOC) contents of the quartz sand and other two soils. The differential Fourier transform infrared (FT-IR) spectra of degraded pyrene in alluvial soil corroborate that TiO 2 -enhanced photocatalytic degradation rate of degraded pyrene was much greater than photooxidation (without TiO 2 ) rate of degraded pyrene. Based on the data obtained, the importance for the application of TiO 2 -enhanced photocatalytic pyrene degradation and associated organic contaminants in contaminated soils was elucidated. - Highlights: → Synergistic effect of sunlight irradiation and TiO 2 promoted degradation of pyrene. → Micro-nano size TiO 2 enhanced

  14. Exploration of Hydrocarbon Degrading Bacteria on Soils Contaminated by Crude Oil From South Sumatera

    OpenAIRE

    Napoleon, A; Probowati, D S

    2014-01-01

    The goal of this research was to explore hydrocarbon degrading bacteria on crude oil contaminated soil with potential to degrade hydrocarbon in oil pollutant. The research started by early August 2013 till January 2014. Soil sampling for this research was taken on several places with contaminated soil location such as Benakat, Rimau, and Pengabuan all of it located in South Sumatera. Conclusion from this research Isolates obtained from three (3) sites of contaminated soil and treated using SB...

  15. Role of litter turnover in soil quality in tropical degraded lands of Colombia.

    Science.gov (United States)

    León, Juan D; Osorio, Nelson W

    2014-01-01

    Land degradation is the result of soil mismanagement that reduces soil productivity and environmental services. An alternative to improve degraded soils through reactivation of biogeochemical nutrient cycles (via litter production and decomposition) is the establishment of active restoration models using new forestry plantations, agroforestry, and silvopastoral systems. On the other hand, passive models of restoration consist of promoting natural successional processes with native plants. The objective in this review is to discuss the role of litter production and decomposition as a key strategy to reactivate biogeochemical nutrient cycles and thus improve soil quality in degraded land of the tropics. For this purpose the results of different projects of land restoration in Colombia are presented based on the dynamics of litter production, nutrient content, and decomposition. The results indicate that in only 6-13 years it is possible to detect soil properties improvements due to litter fall and decomposition. Despite that, low soil nutrient availability, particularly of N and P, seems to be major constraint to reclamation of these fragile ecosystems.

  16. Soil erosion and degradation in Mediterranean Type Ecosystems. The Soil Erosion and Degradation Research Group (SEDER) approach and findings

    Science.gov (United States)

    Cerdà, Artemi; Keesstra, Saskia; Pulido, Manuel; Jordán, Antonio; Novara, Agata; Giménez-Morera, Antonio; Borja, Manuel Esteban Lucas; Francisco Martínez-Murillo, Juan; Rodrigo-Comino, Jesús; Pereira, Paulo; Nadal-Romero, Estela; Taguas, Tani; Úbeda, Xavier; Brevik, Eric C.; Tarolli, Paolo; Bagarello, Vicenzo; Parras Alcantara, Luis; Muñoz-Rojas, Miriam; Oliva, Marc; di Prima, Simone

    2017-04-01

    The Soil Erosion and Degradation Reseach Group (SEDER) is developing a research program since 2002 to assess the soil erosion and degradation processes at the Canyoles River watershed in Eastern Spain. The research study site was selected as representative of the environmental changes that take place in the Mediterranean: abandonment of the agriculture land in the mountains, forest fire expansion, intensification of the agriculture, impact of the infraesturctures such as rail and road embankments, and soil sealing due to the urban expansion. The research is based on the continuous measurements in the Montesa and El Teularet research stations and the sampling of the soils, topographical measurements and the use of rainfall simulators, minidisk infiltrometers, ring infiltrometers and Water Drop Penetration Time tests. The research is moving from a pure scientific approach to a more socio-economic view, and the stakeholders are being researched from a perception point of view. SEDER is also moving from pure to applied science, with the objective to design new managements that will satisfy the stakeholders and will achieve the sustainability. The research is being carried out in vineyards and orchards as they show extremely high erosion rates. But also we are interested in the impact of forest fires and the road embankments. In all three research topics, SEDER wish to find the sustainable managements. Acknowledgements The research leading to these results has received funding from the European Union Seventh Framework Programme (FP7/2007-2013) under grant agreement n° 603498 (RECARE project) and the CGL2013- 47862-C2-1-R and CGL2016-75178-C2-2-R national research projects. References Bodí, M. B., Martin, D. A., Balfour, V. N., Santín, C., Doerr, S. H., Pereira, P., . . . Mataix-Solera, J. (2014). Corrigendum to "wildland fire ash: Production, composition and eco-hydro-geomorphic effects", earth sci. rev. 130 (2014) [103-127]. Earth-Science Reviews, 138, 503. doi:10

  17. Effect of biochar or activated carbon amendment on the volatilisation and biodegradation of organic soil pollutants

    Science.gov (United States)

    Werner, David; Meynet, Paola; Bushnaf, Khaled

    2013-04-01

    Biochar or activated carbon added to contaminated soil may temporarily reduce the volatilisation of organic pollutants by enhanced sorption. The long-term effect of sorbent amendments on the fate of volatile petroleum hydrocarbon mixtures (VPHs) will depend on the responses of the soil bacterial community members, especially those which may utilize VPHs as carbon substrates. We investigated the volatilisation and biodegradation of VPHs emanating from NAPL sources and migrating through one meter long columns containing unsaturated sandy soil with and without 2% biochar or activated carbon amendment. After 420 days, VPH volatilisation from AC amended soil was less than 10 percent of the cumulative VPH volatilisation flux from unamended soil. The cumulative CO2 volatilisation flux increased more slowly in AC amended soil, but was comparable to the untreated soil after 420 days. This indicated that the pollution attenuation over a 1 meter distance was improved by the AC amendment. Biochar was a weaker VPH sorbent than AC and had a lesser effect on the cumulative VPH and CO2 fluxes. We also investgated the predominant bacterial community responses in sandy soil to biochar and/or VPH addition with a factorially designed batch study, and by analyzing preserved soil samples. Biochar addition alone had only weak effects on soil bacterial communities, while VPH addition was a strong community structure shaping factor. The bacterial community effects of biochar-enhanced VPH sorption were moderated by the limited biomass carrying capacity of the sandy soil investigated which contained only low amounts of inorganic nitrogen. Several Pseudomonas spp., including Pseudomonas putida strains, became dominant in VPH polluted soil with and without biochar. The ability of these versatile VPH degraders to effectively regulate their metabolic pathways according to substrate availabilities may additionally have moderated bacterial community structure responses to the presence of biochar

  18. Pasture degradation modifies soil organic matter properties and biochemical functioning in Tibetan grasslands

    Science.gov (United States)

    Spielvogel, Sandra; Steingräber, Laura; Schleuß, Per; Kuzyakov, Yakov; Guggenberger, Georg

    2015-04-01

    Kobresia pastures of the Tibetan Plateau represent the world's largest alpine ecosystem. Moderate husbandry on Kobresia pastures is beneficial for the storage of soil organic carbon (OC), nitrogen (N) and other nutrients and prevents erosion by establishment of sedge-turf root mats with high OC allocation rates below ground. However, undisturbed root mats are affected by freezing and thawing processes, which cause initial ice cracks. As a consequence decomposition of root mat layers will be accelerated and current sedentarization programs with concomitant increased grazing intensity may additionally enhance root mat degradation. Finally, cracks are enlarged by water and wind erosion as well as pika activities until bare soil surface areas without root mat horizons occur. The aim of this study was to understand the impact of the root mat layer on soil organic carbon stabilization and microbial functioning depending on soil depths and to predict future changes (OC, N and nutrient losses, soil microbial functioning in SOM transformation) by overgrazing and climate change. We investigated the mineral soil below Kobresia root mats along a false time degradation sequence ranging from stage 1 (intact root mat) to stage 4 (mats with large cracks and bare soil patches). Vertical gradients of δ13C values, neutral sugar, cutin and suberin contents as well as microbial biomass estimated by total phospholipid fatty acid (PLFA), microbial community composition (PLFA profiles) and activities of six extracellular enzymes involved in the C, N, and P cycle were assessed. Soil OC and N contents as well as C/N ratios indicate an increasing illuviation of topsoil material into the subsoil with advancing root mat degradation. This was confirmed by more negative δ13C values as well as significantly (p ≤ 0.05) increasing contributions of cutin derived hydroxy fatty acids to OC in the subsoils from degradation stages 1 to 4. PLFA profiles were surprisingly similar in the subsoils of

  19. Effect of soil compaction on the degradation and ecotoxicological impact of isoproturon

    Science.gov (United States)

    Mamy, L.; Vrignaud, P.; Cheviron, N.; Perreau, F.; Belkacem, M.; Brault, A.; Breuil, S.; Delarue, G.; Touton, I.; Chaplain, V.

    2009-04-01

    Soil is essentially a non-renewable resource which performs many functions and delivers services vital to human activities and ecosystems survival. However the capacity of soil to keep on fully performing its broad variety of crucial functions is damaged by several threats and, among them, chemical contamination by pesticides and compaction due to intensive agriculture practices. How these two threats could interact is largely unknown: compaction may modify the fate of pesticides in soil therefore their effects on the biological functioning of soil. The aim of this work was to study the effect of soil compaction on (1) the degradation of one herbicide, isoproturon (2) the ecotoxicological impact of this herbicide measured through two enzyme activities involved in C (beta-glucosidase) and N (urease) cycles in soil. Undisturbed soil cylinders were sampled in the 2-4 cm layer of La Cage experimental site (INRA, Versailles, France), under intensive agriculture practices. Several soil samples were prepared with different bulk density then treated with isoproturon (IPU). The samples were incubated at 18 ± 1°C in darkness for 63 days. At 0, 2, 7, 14, 28 and 63 days, the concentrations of isoproturon and of two of its main metabolites in soil (monodesmethyl-isoproturon, IPPMU; didesmethyl-isoproturon, IPPU), and the enzyme activities were measured. The results showed that there was no significant difference in IPU degradation under no and moderate soil compaction. IPU was less persistent in the highly compacted soil, but this soil had also higher humidity which is known to increase the degradation. Only one metabolite, IPPMU, was detected independently of the conditions of compaction. The compaction did not modify the effect of IPU on beta-glucosidase and urease activities in the long term, but microbial communities were probably the same in all the soil samples that were initially not compacted. The communities developed in durably compacted zones in the field are

  20. [Assessment of soil degradation in regions of nuclear power explosions at Semipalatinsk Nuclear Test Site].

    Science.gov (United States)

    Evseeva, T I; Geras'kin, S A; Maĭstrenko, T A; Belykh, E S

    2011-01-01

    Degree of the soil cover degradation at the "Balapan" and "Experimental field" test sites was assessed based on Allium-test of soil toxicity results and international guidelines on radioactive restriction of solid materials (IAEA, 2004) and environment (Smith, 2005). Soil cover degradation maps of large-scale (1 : 25000) were made. The main part of the area mapped belongs to high-contaminated toxic degraded soil. A relationship between the soil toxicity and the total radionuclide activity concentrations was found to be described by power functions. When the calculated value (equal to 413-415 Bq/kg of air dry soil) increases, the soil becomes toxic for plants. This value is 7.8 times higher than the maximal value for background territories (53 Bq/kg) surrounding SNTS. Russian sanitary and hygienic guidelines (Radiation safety norms, 2009; Sanitary regulations of radioactive waste management, 2003) underestimate the degree of soil radioactive contamination for plants.

  1. Microbial degradation of alpha-cypermethrin in soil by compound-specific stable isotope analysis

    Energy Technology Data Exchange (ETDEWEB)

    Xu, Zemin [MOE Key Laboratory of Environmental Remediation and Ecosystem Health, College of Environmental and Resource Sciences, Zhejiang University, Hangzhou 310058 (China); Shen, Xiaoli [MOE Key Laboratory of Environmental Remediation and Ecosystem Health, College of Environmental and Resource Sciences, Zhejiang University, Hangzhou 310058 (China); Department of Environmental Engineering, Quzhou University, Quzhou 324000 (China); Zhang, Xi-Chang [Laboratory for Teaching in Environmental and Resource Sciences, Zhejiang University, Hangzhou 310058 (China); Liu, Weiping [MOE Key Laboratory of Environmental Remediation and Ecosystem Health, College of Environmental and Resource Sciences, Zhejiang University, Hangzhou 310058 (China); Yang, Fangxing, E-mail: fxyang@zju.edu.cn [MOE Key Laboratory of Environmental Remediation and Ecosystem Health, College of Environmental and Resource Sciences, Zhejiang University, Hangzhou 310058 (China); Department of Effect-Directed Analysis, Helmholtz Center for Environmental Research – UFZ, Leipzig 04318 (Germany)

    2015-09-15

    Highlights: • Alpha-cypermethrin (α-CP) can be degraded by microorganisms in soil. • Biodegradation of α-CP resulted in carbon isotope fractionation. • A relationship was found between carbon isotope ratios and concentrations of α-CP. • An enrichment factor ϵ of α-CP was determined as −1.87‰. • CSIA is applicable to assess biodegradation of α-CP. - Abstract: To assess microbial degradation of alpha-cypermethrin in soil, attenuation of alpha-cypermethrin was investigated by compound-specific stable isotope analysis. The variations of the residual concentrations and stable carbon isotope ratios of alpha-cypermethrin were detected in unsterilized and sterilized soils spiked with alpha-cypermethrin. After an 80 days’ incubation, the concentrations of alpha-cypermethrin decreased to 0.47 and 3.41 mg/kg in the unsterilized soils spiked with 2 and 10 mg/kg, while those decreased to 1.43 and 6.61 mg/kg in the sterilized soils. Meanwhile, the carbon isotope ratios shifted to −29.14 ± 0.22‰ and −29.86 ± 0.33‰ in the unsterilized soils spiked with 2 and 10 mg/kg, respectively. The results revealed that microbial degradation contributed to the attenuation of alpha-cypermethrin and induced the carbon isotope fractionation. In order to quantitatively assess microbial degradation, a relationship between carbon isotope ratios and residual concentrations of alpha-cypermethrin was established according to Rayleigh equation. An enrichment factor, ϵ = −1.87‰ was obtained, which can be employed to assess microbial degradation of alpha-cypermethrin. The significant carbon isotope fractionation during microbial degradation suggests that CSIA is a proper approach to qualitatively detect and quantitatively assess the biodegradation during attenuation process of alpha-cypermethrin in the field.

  2. Soil Degradation, Policy Intervention and Sustainable Agricultural Growth

    NARCIS (Netherlands)

    Sasmal, J.; Weikard, H.P.

    2013-01-01

    Sustainable agricultural growth in developing countries is jeopardized by soil degradation consequent upon intensive cultivation and use of increasing doses of chemical inputs. To pave the way to sustainable agricultural growth we develop a model that incorporates organic fertilizer into the

  3. Impact of electrochemical treatment of soil washing solution on PAH degradation efficiency and soil respirometry

    International Nuclear Information System (INIS)

    Mousset, Emmanuel; Huguenot, David; Hullebusch, Eric D. van; Oturan, Nihal; Guibaud, Gilles; Esposito, Giovanni; Oturan, Mehmet A.

    2016-01-01

    The remediation of a genuinely PAH-contaminated soil was performed, for the first time, through a new and complete investigation, including PAH extraction followed by advanced oxidation treatment of the washing solution and its recirculation, and an analysis of the impact of the PAH extraction on soil respirometry. The study has been performed on the remediation of genuine PAH-contaminated soil, in the following three steps: (i) PAH extraction with soil washing (SW) techniques, (ii) PAH degradation with an electro-Fenton (EF) process, and (iii) recirculation of the partially oxidized effluent for another SW cycle. The following criteria were monitored during the successive washing cycles: PAH extraction efficiency, PAH oxidation rates and yields, extracting agent recovery, soil microbial activity, and pH of soil. Two representative extracting agents were compared: hydroxypropyl-beta-cyclodextrin (HPCD) and a non-ionic surfactant, Tween"® 80. Six PAH with different numbers of rings were monitored: acenaphthene (ACE), phenanthrene (PHE), fluoranthene (FLA), pyrene (PYR), benzo(a)pyrene (BaP), and benzo(g,h,i)perylene (BghiP). Tween"® 80 showed much better PAH extraction efficiency (after several SW cycles) than HPCD, regardless of the number of washing cycles. Based on successive SW experiments, a new mathematical relation taking into account the soil/water partition coefficient (Kd*) was established, and could predict the amount of each PAH extracted by the surfactant with a good correlation with experimental results (R"2 > 0.975). More HPCD was recovered (89%) than Tween"® 80 (79%), while the monitored pollutants were completely degraded (>99%) after 4 h and 8 h, respectively. Even after being washed with partially oxidized solutions, the Tween"® 80 solutions extracted significantly more PAH than HPCD and promoted better soil microbial activity, with higher oxygen consumption rates. Moreover, neither the oxidation by-products nor the acidic media (p

  4. Subsidence estimation of breakwater built on loosely deposited sandy seabed foundation: Elastic model or elasto-plastic model

    Directory of Open Access Journals (Sweden)

    Jianhua Shen

    2017-07-01

    Full Text Available In offshore area, newly deposited Quaternary loose seabed soils are widely distributed. There are a great number of offshore structures has been built on them in the past, or will be built on them in the future due to the fact that there would be no very dense seabed soil foundation could be chosen at planed sites sometimes. However, loosely deposited seabed foundation would bring great risk to the service ability of offshore structures after construction. Currently, the understanding on wave-induced liquefaction mechanism in loose seabed foundation has been greatly improved; however, the recognition on the consolidation characteristics and settlement estimation of loose seabed foundation under offshore structures is still limited. In this study, taking a semi-coupled numerical model FSSI-CAS 2D as the tool, the consolidation and settlement of loosely deposited sandy seabed foundation under an offshore breakwater is investigated. The advanced soil constitutive model Pastor-Zienkiewics Mark III (PZIII is used to describe the quasi-static behavior of loose sandy seabed soil. The computational results show that PZIII model is capable of being used for settlement estimation problem of loosely deposited sandy seabed foundation. For loose sandy seabed foundation, elastic deformation is the dominant component in consolidation process. It is suggested that general elastic model is acceptable for subsidence estimation of offshore structures on loose seabed foundation; however, Young's modulus E must be dependent on the confining effective stress, rather than a constant in computation.

  5. Liming effect in the degradation of 14C-glyphosate in soils

    International Nuclear Information System (INIS)

    Arantes, Sayonara A.C.M.; Lavorenti, Arquimedes

    2007-01-01

    Liming is soil fertility management practice essential in tropical soils, in general extremely acidic. This practice, by influencing physical, chemical and biological features of soils may influence the behavior of organic molecules in soils. The glyphosate is one the most widely used pesticides in Brazil in several cultures to pest management control. Studies on its fate in soil are still incipient, mainly under the effect of liming practice The objective of the present study was to verify the effect of liming practice in the degradation of glyphosate in Red Latosol (LE) and Quartzarenic Neosol (RQ) soils and also in the microbial activity of the same soils. The experiment was conducted in a completely randomized design in a 2 x 2 factorial scheme, corresponding to two soils and two management conditions (with liming and without liming), with four replicates. The Radiometric technique was utilized to evaluate the evolution the 14 CO 2 at intervals of 7 days, during 70 days. The study of microbial activity was conducted parallel to the degradation experiment, using the methodology of radiolabelled glucose ( 14 C-glucose), which was measured at intervals of fourteen days, during 70 days. The results showed that in the studied soils, the liming increased the 14 C-glyphosate mineralization and the microbial activity. (author)

  6. Soil bacteria showing a potential of chlorpyrifos degradation and plant growth enhancement

    Directory of Open Access Journals (Sweden)

    Shamsa Akbar

    Full Text Available ABSTRACT Background: Since 1960s, the organophosphate pesticide chlorpyrifos has been widely used for the purpose of pest control. However, given its persistence and toxicity towards life forms, the elimination of chlorpyrifos from contaminated sites has become an urgent issue. For this process bioremediation is the method of choice. Results: Two bacterial strains, JCp4 and FCp1, exhibiting chlorpyrifos-degradation potential were isolated from pesticide contaminated agricultural fields. These isolates were able to degrade 84.4% and 78.6% of the initial concentration of chlorpyrifos (100 mg L-1 within a period of only 10 days. Based on 16S rRNA sequence analysis, these strains were identified as Achromobacter xylosoxidans (JCp4 and Ochrobactrum sp. (FCp1. These strains exhibited the ability to degrade chlorpyrifos in sterilized as well as non-sterilized soils, and were able to degrade 93-100% of the input concentration (200 mg kg-1 within 42 days. The rate of degradation in inoculated soils ranged from 4.40 to 4.76 mg-1 kg-1 d-1 with rate constants varying between 0.047 and 0.069 d-1. These strains also displayed substantial plant growth promoting traits such as phosphate solubilization, indole acetic acid production and ammonia production both in absence as well as in the presence of chlorpyrifos. However, presence of chlorpyrifos (100 and 200 mg L-1 was found to have a negative effect on indole acetic acid production and phosphate solubilization with percentage reduction values ranging between 2.65-10.6% and 4.5-17.6%, respectively. Plant growth experiment demonstrated that chlorpyrifos has a negative effect on plant growth and causes a decrease in parameters such as percentage germination, plant height and biomass. Inoculation of soil with chlorpyrifos-degrading strains was found to enhance plant growth significantly in terms of plant length and weight. Moreover, it was noted that these strains degraded chlorpyrifos at an increased rate (5

  7. Soil bacteria showing a potential of chlorpyrifos degradation and plant growth enhancement.

    Science.gov (United States)

    Akbar, Shamsa; Sultan, Sikander

    2016-01-01

    Since 1960s, the organophosphate pesticide chlorpyrifos has been widely used for the purpose of pest control. However, given its persistence and toxicity towards life forms, the elimination of chlorpyrifos from contaminated sites has become an urgent issue. For this process bioremediation is the method of choice. Two bacterial strains, JCp4 and FCp1, exhibiting chlorpyrifos-degradation potential were isolated from pesticide contaminated agricultural fields. These isolates were able to degrade 84.4% and 78.6% of the initial concentration of chlorpyrifos (100mgL(-1)) within a period of only 10 days. Based on 16S rRNA sequence analysis, these strains were identified as Achromobacter xylosoxidans (JCp4) and Ochrobactrum sp. (FCp1). These strains exhibited the ability to degrade chlorpyrifos in sterilized as well as non-sterilized soils, and were able to degrade 93-100% of the input concentration (200mgkg(-1)) within 42 days. The rate of degradation in inoculated soils ranged from 4.40 to 4.76mg(-1)kg(-1)d(-1) with rate constants varying between 0.047 and 0.069d(-1). These strains also displayed substantial plant growth promoting traits such as phosphate solubilization, indole acetic acid production and ammonia production both in absence as well as in the presence of chlorpyrifos. However, presence of chlorpyrifos (100 and 200mgL(-1)) was found to have a negative effect on indole acetic acid production and phosphate solubilization with percentage reduction values ranging between 2.65-10.6% and 4.5-17.6%, respectively. Plant growth experiment demonstrated that chlorpyrifos has a negative effect on plant growth and causes a decrease in parameters such as percentage germination, plant height and biomass. Inoculation of soil with chlorpyrifos-degrading strains was found to enhance plant growth significantly in terms of plant length and weight. Moreover, it was noted that these strains degraded chlorpyrifos at an increased rate (5.69mg(-1)kg(-1)d(-1)) in planted soil. The

  8. Effects of traditional land transactions on soil erosion and land degradation

    OpenAIRE

    Leduka, R.C.

    1998-01-01

    A research report on the effects of traditional land transactions on soil erosion and land degradation in Lesotho. This report focuses on the land transactions in Lesotho and how these transaction affect the growing erosion rates of the soil.

  9. Degradation of polycyclic aromatic hydrocarbons by microbial consortia enriched from three soils using two different culture media.

    Science.gov (United States)

    Wu, Manli; Chen, Liming; Tian, Yongqiang; Ding, Yi; Dick, Warren A

    2013-07-01

    A consortium composed of many different bacterial species is required to efficiently degrade polycyclic aromatic hydrocarbons (PAH) in oil-contaminated soil. We obtained six PAH-degrading microbial consortia from three oil-contaminated soils using two different isolation culture media. Denaturing gradient gel electrophoresis (DGGE) and sequence analyses of amplified 16s rRNA genes confirmed the bacterial community was greatly affected by both the culture medium and the soil from which the consortia were enriched. Three bacterial consortia enriched using malt yeast extract (MYE) medium showed higher degradation rates of PAHs than consortia enriched using Luria broth (LB) medium. Consortia obtained from a soil and then added back to that same soil was more effective in degrading PAHs than adding, to the same soil, consortia isolated from other, unrelated soils. This suggests that inoculum used for bioremediation should be from the same, or very similar nearby soils, as the soil that is actually being bioremediated. Copyright © 2013 Elsevier Ltd. All rights reserved.

  10. Jatropha curcas L. Root Structure and Growth in Diverse Soils

    Science.gov (United States)

    Valdés-Rodríguez, Ofelia Andrea; Sánchez-Sánchez, Odilón; Pérez-Vázquez, Arturo; Caplan, Joshua S.; Danjon, Frédéric

    2013-01-01

    Unlike most biofuel species, Jatropha curcas has promise for use in marginal lands, but it may serve an additional role by stabilizing soils. We evaluated the growth and structural responsiveness of young J. curcas plants to diverse soil conditions. Soils included a sand, a sandy-loam, and a clay-loam from eastern Mexico. Growth and structural parameters were analyzed for shoots and roots, although the focus was the plasticity of the primary root system architecture (the taproot and four lateral roots). The sandy soil reduced the growth of both shoot and root systems significantly more than sandy-loam or clay-loam soils; there was particularly high plasticity in root and shoot thickness, as well as shoot length. However, the architecture of the primary root system did not vary with soil type; the departure of the primary root system from an index of perfect symmetry was 14 ± 5% (mean ± standard deviation). Although J. curcas developed more extensively in the sandy-loam and clay-loam soils than in sandy soil, it maintained a consistent root to shoot ratio and root system architecture across all types of soil. This strong genetic determination would make the species useful for soil stabilization purposes, even while being cultivated primarily for seed oil. PMID:23844412

  11. Jatropha curcas L. root structure and growth in diverse soils.

    Science.gov (United States)

    Valdés-Rodríguez, Ofelia Andrea; Sánchez-Sánchez, Odilón; Pérez-Vázquez, Arturo; Caplan, Joshua S; Danjon, Frédéric

    2013-01-01

    Unlike most biofuel species, Jatropha curcas has promise for use in marginal lands, but it may serve an additional role by stabilizing soils. We evaluated the growth and structural responsiveness of young J. curcas plants to diverse soil conditions. Soils included a sand, a sandy-loam, and a clay-loam from eastern Mexico. Growth and structural parameters were analyzed for shoots and roots, although the focus was the plasticity of the primary root system architecture (the taproot and four lateral roots). The sandy soil reduced the growth of both shoot and root systems significantly more than sandy-loam or clay-loam soils; there was particularly high plasticity in root and shoot thickness, as well as shoot length. However, the architecture of the primary root system did not vary with soil type; the departure of the primary root system from an index of perfect symmetry was 14 ± 5% (mean ± standard deviation). Although J. curcas developed more extensively in the sandy-loam and clay-loam soils than in sandy soil, it maintained a consistent root to shoot ratio and root system architecture across all types of soil. This strong genetic determination would make the species useful for soil stabilization purposes, even while being cultivated primarily for seed oil.

  12. Jatropha curcas L. Root Structure and Growth in Diverse Soils

    Directory of Open Access Journals (Sweden)

    Ofelia Andrea Valdés-Rodríguez

    2013-01-01

    Full Text Available Unlike most biofuel species, Jatropha curcas has promise for use in marginal lands, but it may serve an additional role by stabilizing soils. We evaluated the growth and structural responsiveness of young J. curcas plants to diverse soil conditions. Soils included a sand, a sandy-loam, and a clay-loam from eastern Mexico. Growth and structural parameters were analyzed for shoots and roots, although the focus was the plasticity of the primary root system architecture (the taproot and four lateral roots. The sandy soil reduced the growth of both shoot and root systems significantly more than sandy-loam or clay-loam soils; there was particularly high plasticity in root and shoot thickness, as well as shoot length. However, the architecture of the primary root system did not vary with soil type; the departure of the primary root system from an index of perfect symmetry was 14±5% (mean ± standard deviation. Although J. curcas developed more extensively in the sandy-loam and clay-loam soils than in sandy soil, it maintained a consistent root to shoot ratio and root system architecture across all types of soil. This strong genetic determination would make the species useful for soil stabilization purposes, even while being cultivated primarily for seed oil.

  13. Sandy soil plantation in semi-arid zones by polyacrylamide gel conditioner prepared by ionizing radiation. Part of a coordinated programme on radiation modified polymers for biomedical and biochemical applications

    International Nuclear Information System (INIS)

    Azzam, R.A.I.

    1983-07-01

    Polyacrylamide gel prepared by ionizing radiation was found to be capable of furnishing adequate conditions for sandy-soil plantation in semi-arid zones. The gel can be tailored for any soil texture under various climatic conditions. The sand-gel combination maintains three cycles of complete destruction and reformation without significant changes in erosion index. Water holding capacity and retention at different suctions in treated sand are increased. This increases water use efficiency. Fertilizers use efficiency is also increased to almost three times that of fertile clayey soil

  14. Degradation of soil-sorbed trichloroethylene by stabilized zero valent iron nanoparticles: Effects of sorption, surfactants, and natural organic matter

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Man [Auburn University, Auburn, Alabama; He, Feng [ORNL; Zhao, Dongye [Auburn University, Auburn, Alabama; Hao, Xiaodi [Beijing University of Civil Engineering and Architecture

    2011-01-01

    Zero valent iron (ZVI) nanoparticles have been studied extensively for degradation of chlorinated solvents in the aqueous phase, and have been tested for in-situ remediation of contaminated soil and groundwater. However, little is known about its effectiveness for degrading soil-sorbed contaminants. This work studied reductive dechlorination of trichloroethylene (TCE) sorbed in two model soils (a potting soil and Smith Farm soil) using carboxymethyl cellulose (CMC) stabilized Fe-Pd bimetallic nanoparticles. Effects of sorption, surfactants and dissolved organic matter (DOC) were determined through batch kinetic experiments. While the nanoparticles can effectively degrade soil-sorbed TCE, the TCE degradation rate was strongly limited by desorption kinetics, especially for the potting soil which has a higher organic matter content of 8.2%. Under otherwise identical conditions, {approx}44% of TCE sorbed in the potting soil was degraded in 30 h, compared to {approx}82% for Smith Farm soil (organic matter content = 0.7%). DOC from the potting soil was found to inhibit TCE degradation. The presence of the extracted SOM at 40 ppm and 350 ppm as TOC reduced the degradation rate by 34% and 67%, respectively. Four prototype surfactants were tested for their effects on TCE desorption and degradation rates, including two anionic surfactants known as SDS (sodium dodecyl sulfate) and SDBS (sodium dodecyl benzene sulfonate), a cationic surfactant hexadecyltrimethylammonium (HDTMA) bromide, and a non-ionic surfactant Tween 80. All four surfactants were observed to enhance TCE desorption at concentrations below or above the critical micelle concentration (cmc), with the anionic surfactant SDS being most effective. Based on the pseudo-first-order reaction rate law, the presence of 1 x cmc SDS increased the reaction rate by a factor of 2.5 when the nanoparticles were used for degrading TCE in a water solution. SDS was effective for enhancing degradation of TCE sorbed in Smith Farm

  15. Pore structure characteristics after two years biochar application to a sandy loam field

    DEFF Research Database (Denmark)

    Sun, Zhencai; Arthur, Emmanuel; de Jonge, Lis Wollesen

    2015-01-01

    the effects of birch wood biochar (20, 40, and 100 Mg ha−1) applied to a sandy loam on soil total porosity and pore structure indices. Bulk and intact soil samples were collected for physicochemical analyses and water retention and gas diffusivity measurements between pF 1.0 and pF 3.0. Biochar application...

  16. The importance of Soil Science to understand and remediate Land Degradation and Desertification processes

    Science.gov (United States)

    Bouma, Johan; Keesstra, Saskia; Cerdà, Artemi

    2017-04-01

    Documentation is abundantly available to demonstrate the devastating effect of Land degradation and desertification on sustainable development in many countries. This present a major barrier to achieving the UN Sustainable Development Goals by 2030, as agreed upon at the General Assembly of the UN in September 2015. Research has certainly been successful in reversing these two processes in many case studies but persistant problems remain not only in developing countries but also in developed countries where, for example, soil compaction and loss of soil organic matter due to the industrialization of agriculture, result in a structural decline of agricultural productivity and environmental quality. The problems are quite complex because not only technical matters play a role but also, and often quite prominantly, socio-economic factors. What turn out to be successful remediation procedures at a given location or region, based on the characterization of underlying soil processes, will most likely not work in other regions inhibiting the extrapolation of local research results to areas elsewhere. One important reason for location specificity of research is the variation of soil properties in combination with the location of soils in a given landscape which governs its water, energy and nutrient dynamics, also considering the climate. Different soils are characterized by different natural riks for degradation and , in arid regions, deserticification and their particular remediation potential differs widely as well. Such risks can sometimes be overcome by innovative soil management and knowing the soil type, the climate and landscape processes, extrapolation of such types of innovative management to comparable soils and landscapes elsewhere may be feasible and effective , provided that socio-economic conditions allow the required risk-reducing measures to be realized in practice. More cooperation between soil scientists and physical geographers, familiar with landscape

  17. Irradiated Sewage Sludge for Production of Fennel (Foeniculum vulgare L.) Plants in Sandy Soil 2- Seed production, oil content, oil constituents and heavy metals in seeds

    International Nuclear Information System (INIS)

    El-Motaium, R. A.; Abo-El-Seoud, M. A.

    2007-01-01

    Field experiment was conducted to study the impact of irradiated and non-irradiated sewage sludge applied to sandy soil on fennel plants (Foeniculum vulgare L.) productivity. In this regards, four rates of sewage sludge application were used (20, 40, 60 and 80 ton/ha) in addition to the mineral fertilizer treatment (control). Sandy soil amended with sewage sludge showed a promising effect on fennel seed yield. A linear gradual increase in seeds yield was observed as the sludge application rate increases. Seeds production increased by 41% to 308% over the control at 80 t /ha application rate, for non-irradiated and irradiated sewage sludge treatments, respectively. Irradiated sewage sludge treatments showed higher fennel seed yield than non-irradiated sewage sludge treatments.Volatile oil percent exhibited no observable variation due to the use of sewage sludge. A few and limited fluctuations could be observed. However, total oil content (cc/plot) increased due to the increase in seeds yield. The magnitude of increase in volatile oil production in response to the sewage sludge application was parallel to the increase in seeds yield. The GLC measurements of the fennel volatile oil reveal that, the t-anethole is the predominant fraction. However, fenchone was detected in relatively moderate concentration. The applied sewage sludge treatment induced some variations in fennel volatile oil constituents. The t.anethole is relatively higher in volatile oil obtained from plants grown on sandy soil fertilized with non-irradiated sewage sludge than the one fertilized with irradiated sewage sludge or chemical fertilizer. In the meantime, the obtained increase in t.anethole was accompanied by a decline in fenchone content. Seeds heavy metals (Zn, Fe, Pb, Cd) were determined. Under all sludge application rates iron and zinc concentrations were in the normal plant concentration range whereas, Cd concentrations were traces.

  18. A discrete element model for soil-sweep interaction in three different soils

    DEFF Research Database (Denmark)

    Chen, Y; Munkholm, Lars Juhl; Nyord, Tavs

    2013-01-01

    . To serve the model development, the sweep was tested in three different soils (coarse sand, loamy sand, and sandy loam). In the tests, soil cutting forces (draught and vertical forces) and soil disturbance characteristics (soil cross-section disturbance and surface deformation) resulting from the sweep...... were measured. The measured draught and vertical forces were used in calibrations of the most sensitive model parameter, particle stiffness. The calibrated particle stiffness was 0.75 × 103 N m−1 for the coarse sand, 2.75 × 103 N m−1 for the loamy sand, and 6 × 103 N m−1 for the sandy loam...

  19. Soil quality changes in land degradation as indicated by soil chemical, biochemical and microbiological properties in a karst area of southwest Guizhou, China

    Science.gov (United States)

    Zhang, Pingjiu; Li, Lianqing; Pan, Genxing; Ren, Jingchen

    2006-12-01

    Not only the nutritional status and biological activity but also the soil ecological functioning or soil health has been impacted profoundly by land degradation in the karst area of southwest China where the karst ecosystems are generally considered as extremely vulnerable to land degradation under intensified land-use changes. The objectives of this study are to elucidate the changes in overall soil quality by a holistic approach of soil nutritional, biological activity, and soil health indicators in the karst area as impacted by intense cultivation and vegetation degradation. Topsoil samples were collected on selected eco-tesserae in a sequence of land degradation in a karst area of southwest Guizhou in 2004. The soil nutrient pools of organic carbon (Corg), extractable extracellular carbon (Cext), total soil nitrogen (Nt), alkali-hydrolyzable nitrogen (Nah), total phosphorus (Pt), available phosphorus (Pa) were analyzed by wet soil chemistry. The soil biological properties were studied by means of measurements of microbial biomass carbon (both by fumigation-extraction, FE-Cmic, and by calculation from substrate-incubation respiration, SIR-Cmic) of respiration [respiration without addition of substrates, basal respiration (BR), and potential respiration (PR) with substrate-incubation] and of soil enzyme activities (invertase, urease, and alkaline phosphatase). Soil health status was assessed by simple indices of Cmic/Corg and BR/Cmic in conjunction with bacterial community structures determined by polymerase chain reaction and denaturing gradient gel electrophoresis. While the nutritional pool parameters, such as Corg and Cext, described basically the changes in soil life-supporting capacity with cultivation interference and vegetation declined, those parameters of biological activity such as FE-Cmic, SIR, and SIR-Cmic as well as bacterial community structures measured by molecular method evidenced well the changes in soil functioning for ecosystem health with

  20. Organochlorine Pesticides and Degradation Products in Soil around ...

    African Journals Online (AJOL)

    The levels and compositions of organochlorine pesticides and degradation products in soil samples collected from a former formulation plant in Morogoro municipality, Tanzania, were determined. Extraction was performed by pressurized fluid extraction using n-hexane:acetone (75:25) mixture. Clean-up of extracts was ...

  1. SYSTEMIC APPROACH AND ROUGHNESS APPLICATION TO CAUSE EMERGING PROPERTIES IN THE RESTORATION OF DEGRADED SOILS

    Directory of Open Access Journals (Sweden)

    Juarês José Aumond

    2014-09-01

    Full Text Available http://dx.doi.org/10.5902/1980509815737Based on the general systems theory, an ecological model for the restoration of ecosystems has been developed, which soils are highly degraded, and treating the ecosystem as a complex dynamic system, hyper-sensitive to initial conditions of soil preparation. Assuming that degraded ecosystems are sensitive to initial conditions of soil preparation, the technique of roughness was evaluated (relief variations alternating between concave and convex surfaces to trigger over time emergent properties that accelerate the process of ecological restoration. The degraded ecosystems can be understood as organizationally open systems, as a dissipative structure, in which irreversibly matter and energy flow. The main task in ecological restoration in areas that had the soil degraded is to achieve the internalization of matter and energy to induce the system to organizational closure. The roughness, represented by soil micro-topography is an effective technique in the internalization of matter, retaining water, sediment, organic matter, nutrients and seeds. Variations of relief trigger environmental changes over time in a dynamic and heterogeneous way, which influence the interactions between solar radiation, moisture and nutrients, creating different opportunities for plants and animal species. There must be an oriented concentration to flow structures and processes between the degraded ecosystem (system and the environment (neighborhood. In this approach, a particular concentration on the interrelationships between the system and the environment is dedicated. For ecological restoration, whose area is with degraded soil, such as mining and ranching, a new integrative degraded systemic approach is proposed, in which the roughness of the soil might trigger spatial and temporal patterns and emergent environmental properties due to the hyper-sensitivity to initial conditions of the land preparation.

  2. Degradation of roxarsone in a silt loam soil and its toxicity assessment.

    Science.gov (United States)

    Liang, Tengfang; Ke, Zhengchen; Chen, Qing; Liu, Li; Chen, Guowei

    2014-10-01

    The land application of poultry or swine litter, containing large amounts of roxarsone, causes serious arsenic pollution in soil. Understanding biotransformation process of roxarsone and its potential risks favors proper disposal of roxarsone-contaminated animal litter, yet remains not achieved. We report an experimental study of biotransformation process of roxarsone in a silt loam soil under various soil moisture and temperature conditions, and the toxicity of roxarsone and its products from degradation. Results showed that soil moisture and higher temperature promoted roxarsone degradation, associating with emergent pentavalent arsenic. Analysis of fluorescein diacetate (FDA) hydrolysis activity revealed that roxarsone does not exert acute toxic on soil microbes. With the release of inorganic arsenic, FDA hydrolysis activity was inhibited gradually, as evidenced by ecotoxicological assessment using Photobacterium leiognathi. The results shade new lights on the dynamic roxarsone biotransformation processes in soil, which is important for guiding appropriate disposal of poultry or swine litter in the environment. Copyright © 2014 Elsevier Ltd. All rights reserved.

  3. Isolation and characterization of mesotrione-degrading Bacillus sp. from soil

    International Nuclear Information System (INIS)

    Batisson, Isabelle; Crouzet, Olivier; Besse-Hoggan, Pascale; Sancelme, Martine; Mangot, Jean-Francois; Mallet, Clarisse; Bohatier, Jacques

    2009-01-01

    Dissipation kinetics of mesotrione, a new triketone herbicide, sprayed on soil from Limagne (Puy-de-Dome, France) showed that the soil microflora were able to biotransform it. Bacteria from this soil were cultured in mineral salt solution supplemented with mesotrione as sole source of carbon for the isolation of mesotrione-degrading bacteria. The bacterial community structure of the enrichment cultures was analyzed by temporal temperature gradient gel electrophoresis (TTGE). The TTGE fingerprints revealed that mesotrione had an impact on bacterial community structure only at its highest concentrations and showed mesotrione-sensitive and mesotrione-adapted strains. Two adapted strains, identified as Bacillus sp. and Arthrobacter sp., were isolated by colony hybridization methods. Biodegradation assays showed that only the Bacillus sp. strain was able to completely and rapidly biotransform mesotrione. Among several metabolites formed, 2-amino-4-methylsulfonylbenzoic acid (AMBA) accumulated in the medium. Although sulcotrione has a chemical structure closely resembling that of mesotrione, the isolates were unable to degrade it. - A Bacillus sp. strain isolated from soil was able to completely and rapidly biotransform the triketone herbicide mesotrione

  4. Liming effect in the degradation of 14C-glyphosate in soils

    Energy Technology Data Exchange (ETDEWEB)

    Arantes, Sayonara A.C.M.; Lavorenti, Arquimedes [Universidade de Sao Paulo (USP), Piracicaba, SP (Brazil). Escola Superior de Agricultura Luiz de Queiroz]. E-mails: samoreno@esalq.usp.br; alavoren@esalq.usp.br; Tornisielo, Valdemar L. [Centro de Energia Nuclear na Agricultura (CENA), Piracicaba, SP (Brazil)]. E-mail: vltornis@cena.usp.br

    2007-07-01

    Liming is soil fertility management practice essential in tropical soils, in general extremely acidic. This practice, by influencing physical, chemical and biological features of soils may influence the behavior of organic molecules in soils. The glyphosate is one the most widely used pesticides in Brazil in several cultures to pest management control. Studies on its fate in soil are still incipient, mainly under the effect of liming practice The objective of the present study was to verify the effect of liming practice in the degradation of glyphosate in Red Latosol (LE) and Quartzarenic Neosol (RQ) soils and also in the microbial activity of the same soils. The experiment was conducted in a completely randomized design in a 2 x 2 factorial scheme, corresponding to two soils and two management conditions (with liming and without liming), with four replicates. The Radiometric technique was utilized to evaluate the evolution the {sup 14}CO{sub 2} at intervals of 7 days, during 70 days. The study of microbial activity was conducted parallel to the degradation experiment, using the methodology of radiolabelled glucose ({sup 14}C-glucose), which was measured at intervals of fourteen days, during 70 days. The results showed that in the studied soils, the liming increased the {sup 14}C-glyphosate mineralization and the microbial activity. (author)

  5. Land degradation and adoption of soil conservation technologies ...

    African Journals Online (AJOL)

    The study investigates the causes of land degradation, and adoption of soil conservation practices using a two-stage decision making process. The data for the study were collected with the aid of structured questionnaire and analyzed with descriptive analysis, difference regression equation and simultaneous probit model.

  6. Parâmetros nutricionais da pastagem natural em diferentes tipos de solos na APA do Ibirapuitã, Rio Grande do Sul - Brasil Nutritional parameters of natural pasture in different soils at APA of Ibirapuitã, Rio Grande do Sul - Brazil

    Directory of Open Access Journals (Sweden)

    Vicente Celestino Pires Silveira

    2006-12-01

    Full Text Available O desempenho de ruminantes domésticos é influenciado por fatores intrínsecos ao animal, ao alimento e pela interação entre animal e alimento. O trabalho foi realizado na Estância do 28, pertencente à Fundação Maronna, Alegrete - RS, dentro da APA do Ibirapuitã. Para representar o fator solo, foram escolhidos os três tipos predominantes da APA do Ibirapuitã: Basalto Superficial, Basalto Profundo e Arenito. As amostras da pastagem natural foram retiradas por simulação de pastejo, através de coleta manual. Os parâmetros nutricionais avaliados foram: proteína bruta, fibra em detergente neutro e taxa de degradação da matéria seca. A forragem da pastagem natural oriunda do solo Basalto Superficial apresentou diferença significativa (PIntrinsic animal and food factors and the interaction between them influence the performance of domestic ruminants. This study was done at Estância do 28, property of the Maronna Foundation, Alegrete - RS, inside the Ibirapuitã Area of Environmental Protection. In order to represent soil as a factor, the three main soil types were chosen: Superficial Basalt, Deep Basalt and Sandy. Hand plucking methods were used to obtain samples of natural pasture. Nutritional parameters considered were crude protein, neutral detergent fiber and dry matter degradation rate. The forage from natural pasture of the Superficial Basalt presented significant difference (P<0.05 in crude protein rates over the other two types of soil, which did not differ amongst themselves. The highest rate of neutral detergent fibre (84.54% was obtained in pasture originated from Sandy soil, in relation to Superficial and Deep Basalt, with values of 74.53% and 77.98%, respectively. There was also a significant difference in the degradation rate of dry matter (P<0.05. Sandy soil pasture presented an intermediate degradation value (3.61% h-1, not differing from other soils. The forage from natural pastures present similar degradation rates

  7. Effects of interactions between Collembola and soil microbial community on the degradation of glyphosate-based herbicide

    Science.gov (United States)

    Wee, J.; Lee, Y. S.; Son, J.; Kim, Y.; Nam, T. H.; Cho, K.

    2017-12-01

    Glyphosate is the most widely used herbicide because of its broad spectrum activity and effectiveness, however, little is known about adverse effects on non-target species and their interactions. Therefore, in this study, we investigated the effects of glyphosate on interactions between Collembola and soil microbial community and the effect of Collembola on degradation of glyphosate. The experiment carried out in PS container filled with 30g of soil according to OECD 232 guidelines. Investigating the effects of soil microbial community and Collembola on degradation of glyphosate, we prepared defaunated field soil (only maintaining soil microbial community, sampling in May and September, 2016.) and autoclaved soil with 0, 10, 30 adults of Paronychiurus kimi (Collembola) respectively. Survived adults and hatched juveniles of P. kimi were counted after 28-day exposures in both soils spiked with 100 mg/kg of glyphosate. Glyphosate in soil of 7, 14, 21, 28 days after spiking of glyphosate based herbicide was analyzed by spectrophotometer (Jan et al., 2009). Also soil microbial community structure was investigated using phospholipid fatty acids (PLFAs) composition analysis of soils following the procedures given by the Sherlock Microbial Identification System (MIDI Inc., Newark, DE). Glyphosate (100mg/kg soil) has no effects on reproduction and survival of P. kimi in any soils. Also, glyphosate in soils with Collembola was more rapidly degraded. Rapid increase of soil microbial biomass(PLFAs) was shown in soil with Collembola addition. This result showed that glyphosate affected interactions between Collembola and soil microorganisms, and also soil microbial community affected by Collembola changed degradation of glyphosate.

  8. Diuron degradation by bacteria from soil of sugarcane crops

    Directory of Open Access Journals (Sweden)

    Tassia C. Egea

    2017-12-01

    Full Text Available The isolation of microorganisms from soil impacted by xenobiotic chemicals and exposing them in the laboratory to the contaminant can provide important information about their response to the contaminants. The purpose of this study was to isolate bacteria from soil with historical application of herbicides and to evaluate their potential to degrade diuron. The isolation media contained either glucose or diuron as carbon source. A total of 400 bacteria were isolated, with 68% being Gram-positive and 32% Gram-negative. Most isolates showed potential to degrade between 10 and 30% diuron after five days of cultivation; however Stenotrophomonas acidophila TD4.7 and Bacillus cereus TD4.31 were able to degrade 87% and 68%, respectively. The degradation of diuron resulted in the formation of the metabolites DCPMU, DCPU, DCA, 3,4-CAC, 4-CA, 4-CAC and aniline. Based on these results it was proposed that Pseudomonas aeruginosa TD2.3, Stenotrophomonas acidaminiphila TD4.7, B. cereus TD4.31 and Alcaligenes faecalis TG 4.48, act on 3,4-DCA and 4-CA by alkylation and dealkylation while Micrococcus luteus and Achromobacter sp follow dehalogenation directly to aniline. Growth on aniline as sole carbon source demonstrates the capacity of strains to open the aromatic ring. In conclusion, the results show that the role of microorganisms in the degradation of xenobiotics in the environment depends on their own metabolism and also on their synergistic interactions.

  9. 14C tebuconazole degradation in Colombian soils.

    Science.gov (United States)

    Mosquera, C S; Martínez, M J; Guerrero, J A

    2010-01-01

    Tebuconazole is a fungicide used on onion crops (Allium Fistulosum L) in Colombia. Persistence of pesticides in soils is characterized by the half-life (DT50), which is influenced by their chemical structure, the physical and chemical properties of the soil and the previous soil history. Based on its structural and chemical properties, tebuconazole should be expected to be relatively persistent in soils. Laboratory incubation studies were conducted to evaluate persistence and bond residues of 14C tebuconazole in three soils, two inceptisol (I) and one histosol (H). Textural classifications were: loam (101), loamy sand (102) and loam (H03), respectively. Data obtained followed a first-order degradation kinetics (R2 > or = 0.899) with DT50 values between 158 and 198 days. The production of 14CO2 from the 14C-ring-labelled test chemicals was very low and increased slightly during 63 days in all cases. The methanol extractable 14C-residues were higher than aqueous ones and both decreased over incubation time for the three soils. The formation of bound 14C-residues increased with time and final values were 11.3; 5.55 and 7.87% for 101, 102 and H03 respectively. Soil 101 showed the lowest mineralization rate and the highest bound residues formation, which might be explained by the clay fraction content. In contrast, an inverse behavior was found for soils 102 and H03, these results might be explained by the higher soil organic carbon content.

  10. Sorption, degradation and leaching of pesticides in soils amended with organic matter: A review

    Directory of Open Access Journals (Sweden)

    Fardin Sadegh-Zadeh

    2017-04-01

    Full Text Available The use of pesticides in modern agriculture is unavoidable because they are required to control weeds. Pesticides are poisonous; hence, they are dangerous if misused. Understanding the fate of pesticides will be useful to use them safely. Therefore, contaminations of water and soil resources could be avoided. The fates of pesticides in soils are influenced by their sorption, decomposition and movement. Degradation and leaching of pesticides are control by sorption. Soil organic matter and clay content are main soil constituents that have a high capacity for sorption of pesticides. Addition of organic maters to amend the soils is a usual practice that every year has been done in a huge area of worldwide.  The added organic amendments to the soils affect the fate of pesticides in soils as well. Pesticides fates in different soils are different. The addition of organic matter to soils causes different fates for pesticides as well. It is known from the studies that sorption of non-ionic pesticides by soil in aqueous system is controlled mainly by the organic matter content of the soils. Sorption of pesticides has been reported to increase by amending soils with organic matter. In general, conditions that promote microbial activity enhance the rate of pesticides degradation, and those that inhibit the growth of microorganisms reduce the rate of degradation. Amendment of soils with organic matter may modify leaching of pesticides in soil. Some studies showed that organic matter added to soils reduced pesticides in ground water. Generally, organic amendments induces the restriction of pesticides leaching in soils.

  11. Degradation of Triazine-2-(14C Metsulfuron-Methyl in Soil from an Oil Palm Plantation.

    Directory of Open Access Journals (Sweden)

    B S Ismail

    Full Text Available Triazine-2-(14C metsulfuron-methyl is a selective, systemic sulfonylurea herbicide. Degradation studies in soils are essential for the evaluation of the persistence of pesticides and their breakdown products. The purpose of the present study was to investigate the degradation of triazine-2-(14C metsulfuron-methyl in soil under laboratory conditions. A High Performance Liquid Chromatograph (HPLC equipped with an UV detector and an on-line radio-chemical detector, plus a Supelco Discovery column (250 x 4.6 mm, 5 μm, and PRP-1 column (305 x 7.0 mm, 10 μm was used for the HPLC analysis. The radioactivity was determined by a Liquid Scintillation Counter (LSC in scintillation fluid. The soil used was both sterilized and non-sterilized in order to observe the involvement of soil microbes. The estimated DT50 and DT90 values of metsulfuron-methyl in a non-sterile system were observed to be 13 and 44 days, whereas in sterilized soil, the DT50 and DT90 were 31 and 70 days, respectively. The principal degradation product after 60 days was CO2. The higher cumulative amount of (14CO2 in (14C-triazine in the non-sterilized soil compared to that in the sterile system suggests that biological degradation by soil micro-organisms significantly contributes to the dissipation of the compound. The major routes of degradation were O-demethylation, sulfonylurea bridge cleavage and the triazine "ring-opened."

  12. Degradation of Biofumigant Isothiocyanates and Allyl Glucosinolate in Soil and Their Effects on the Microbial Community Composition.

    Directory of Open Access Journals (Sweden)

    Franziska S Hanschen

    Full Text Available Brassicales species rich in glucosinolates are used for biofumigation, a process based on releasing enzymatically toxic isothiocyanates into the soil. These hydrolysis products are volatile and often reactive compounds. Moreover, glucosinolates can be degraded also without the presence of the hydrolytic enzyme myrosinase which might contribute to bioactive effects. Thus, in the present study the stability of Brassicaceae plant-derived and pure glucosinolates hydrolysis products was studied using three different soils (model biofumigation. In addition, the degradation of pure 2-propenyl glucosinolate was investigated with special regard to the formation of volatile breakdown products. Finally, the influence of pure glucosinolate degradation on the bacterial community composition was evaluated using denaturing gradient gel electrophoresis of 16S rRNA gene amplified from total community DNA. The model biofumigation study revealed that the structure of the hydrolysis products had a significant impact on their stability in the soil but not the soil type. Following the degradation of pure 2-propenyl glucosinolate in the soils, the nitrile as well as the isothiocyanate can be the main degradation products, depending on the soil type. Furthermore, the degradation was shown to be both chemically as well as biologically mediated as autoclaving reduced degradation. The nitrile was the major product of the chemical degradation and its formation increased with iron content of the soil. Additionally, the bacterial community composition was significantly affected by adding pure 2-propenyl glucosinolate, the effect being more pronounced than in treatments with myrosinase added to the glucosinolate. Therefore, glucosinolates can have a greater effect on soil bacterial community composition than their hydrolysis products.

  13. Bioaccessible Porosity in Soil Aggregates and Implications for Biodegradation of High Molecular Weight Petroleum Compounds.

    Science.gov (United States)

    Akbari, Ali; Ghoshal, Subhasis

    2015-12-15

    We evaluated the role of soil aggregate pore size on biodegradation of essentially insoluble petroleum hydrocarbons that are biodegraded primarily at the oil-water interface. The size and spatial distribution of pores in aggregates sampled from biodegradation experiments of a clayey, aggregated, hydrocarbon-contaminated soil with relatively high bioremediation end point were characterized by image analyses of X-ray micro-CT scans and N2 adsorption. To determine the bioaccessible pore sizes, we performed separate experiments to assess the ability of hydrocarbon degrading bacteria isolated from the soil to pass through membranes with specific sized pores and to access hexadecane (model insoluble hydrocarbon). Hexadecane biodegradation occurred only when pores were 5 μm or larger, and did not occur when pores were 3 μm and smaller. In clayey aggregates, ∼ 25% of the aggregate volume was attributed to pores larger than 4 μm, which was comparable to that in aggregates from a sandy, hydrocarbon-contaminated soil (~23%) scanned for comparison. The ratio of volumes of inaccessible pores (4 μm) in the clayey aggregates was 0.32, whereas in the sandy aggregates it was approximately 10 times lower. The role of soil microstructure on attainable bioremediation end points could be qualitatively assessed in various soils by the aggregate characterization approach outlined herein.

  14. Soil Fertility Gradient in the Restinga Ecosystem

    Science.gov (United States)

    América Castelar da Cunha, Joana; Casagrande, José Carlos; Soares, Marcio Roberto; Martins Bonilha, Rodolfo

    2013-04-01

    The restinga ecosystem (coastal plain vegetation) can be termed as a set of plant communities that suffer strong influenced by fluvial and marine factors and is characterized as an ecosystem of great biological diversity, therefore, represents areas of great importance in the context of ecological preservation. The degradation processes from many forms of anthropogenic disturbances that has taken place since the colonization of the country, made studies on the characterization and dynamics of soil fertility of these areas even more important in relation to the maintenance of its biodiversity and conservation. The sites studied were the Cardoso Island and Comprida Island, and in these, we analyzed four physiognomies, restinga, low restinga, dune and antedune (from continent to ocean). Chemical analyses were performed and soil salinity in these areas in depths 0-5; 0-10; 0-20; 20-40; 40-60 cm. In all soils the cationic exchange capacity was intimately associated with the concentration of soil organic matter, which makes this parameter essential to the maintenance of soil fertility of these areas; in more superficial layers (0-20 cm) there was an increase of pH and base saturation and decline of organic matter, aluminum saturation and cationic exchange capacity in the nearby sea, physiognomies what determines the existence of fertility gradient towards the continent-coast; restinga forests showed a chemical standard that is heavily marked by sandy texture, high degree of leaching, nutrient poverty, low base saturation, high saturation by aluminum and acidity, opposite conditions to soils of the dunes and antedunes, with the exception of sandy texture; despite the existence of a chemical gradient of fertility among the physiognomies studied it is possible to determine the soil acts more strongly as a physical support than as provider of fertility; as for salinity, soil collected in Cardoso Island did not present salinity in any depth, a fact which can be explained due

  15. Microbial degradation pathways of the herbicide dichlobenil in soils with different history of dichlobenil-exposure

    International Nuclear Information System (INIS)

    Holtze, Maria S.; Hansen, Hans Christian B.; Juhler, Rene K.; Sorensen, Jan; Aamand, Jens

    2007-01-01

    This is the first detailed study of metabolite production during degradation of the herbicide 2,6-dichlorobenzonitrile (dichlobenil). Degradation of dichlobenil and three potential metabolites: 2,6-dichlorobenzamide (BAM), 2,6-dichlorobenzoic acid (2,6-DCBA) and ortho-chlorobenzamide (OBAM) was studied in soils either previously exposed or not exposed to dichlobenil using a newly developed HPLC method. Dichlobenil was degraded in all four soils; BAM and 2,6-DCBA were only degraded in soils previously exposed to dichlobenil (100% within 35-56 days and 85-100% in 56 days, respectively), and OBAM in all four soils (25-33% removal in 48 days). BAM produced from dichlobenil was either hydrolyzed to 2,6-DCBA or dechlorinated to OBAM, which was further hydrolyzed to ortho-chlorobenzoic acid. BAM was rapidly mineralized in previously exposed soils only. All potential metabolites and the finding that BAM was a dead-end metabolite of dichlobenil in soils not previously exposed to dichlobenil needs to be included in risk assessments of the use of dichlobenil. - BAM produced from dichlobenil was either hydrolyzed to 2,6-DCBA or dechlorinated to OBAM, which was further hydrolyzed to ortho-chlorobenzoic acid

  16. Microbial degradation pathways of the herbicide dichlobenil in soils with different history of dichlobenil-exposure

    Energy Technology Data Exchange (ETDEWEB)

    Holtze, Maria S. [Department of Natural Sciences, Soil and Environmental Chemistry, Royal Veterinary and Agricultural University, Thorvaldsensvej 40, DK-1871 Frederiksberg C (Denmark) and Department of Geochemistry, Geological Survey of Denmark and Greenland, Oster Voldgade 10, DK-1350 Copenhagen K (Denmark) and Section of Genetics and Microbiology, Department of Ecology, Royal Veterinary and Agricultural University, Thorvaldsensvej 40, DK-1871 Frederiksberg C (Denmark)]. E-mail: msh@geus.dk; Hansen, Hans Christian B. [Department of Natural Sciences, Soil and Environmental Chemistry, Royal Veterinary and Agricultural University, Thorvaldsensvej 40, DK-1871 Frederiksberg C (Denmark); Juhler, Rene K. [Department of Geochemistry, Geological Survey of Denmark and Greenland, Oster Voldgade 10, DK-1350 Copenhagen K (Denmark); Sorensen, Jan [Section of Genetics and Microbiology, Department of Ecology, Royal Veterinary and Agricultural University, Thorvaldsensvej 40, DK-1871 Frederiksberg C (Denmark); Aamand, Jens [Department of Geochemistry, Geological Survey of Denmark and Greenland, Oster Voldgade 10, DK-1350 Copenhagen K (Denmark)

    2007-07-15

    This is the first detailed study of metabolite production during degradation of the herbicide 2,6-dichlorobenzonitrile (dichlobenil). Degradation of dichlobenil and three potential metabolites: 2,6-dichlorobenzamide (BAM), 2,6-dichlorobenzoic acid (2,6-DCBA) and ortho-chlorobenzamide (OBAM) was studied in soils either previously exposed or not exposed to dichlobenil using a newly developed HPLC method. Dichlobenil was degraded in all four soils; BAM and 2,6-DCBA were only degraded in soils previously exposed to dichlobenil (100% within 35-56 days and 85-100% in 56 days, respectively), and OBAM in all four soils (25-33% removal in 48 days). BAM produced from dichlobenil was either hydrolyzed to 2,6-DCBA or dechlorinated to OBAM, which was further hydrolyzed to ortho-chlorobenzoic acid. BAM was rapidly mineralized in previously exposed soils only. All potential metabolites and the finding that BAM was a dead-end metabolite of dichlobenil in soils not previously exposed to dichlobenil needs to be included in risk assessments of the use of dichlobenil. - BAM produced from dichlobenil was either hydrolyzed to 2,6-DCBA or dechlorinated to OBAM, which was further hydrolyzed to ortho-chlorobenzoic acid.

  17. How far can we prevent further physical soil degradation in the future?

    Science.gov (United States)

    Horn, Rainer

    2017-04-01

    Arable as well as forest soils are exposed to increasing external stresses, which coincide with a further and deeper reaching soil degradation, which may result in an aggravation of hydraulic, gaseous, thermal but also physicochemical and chemical soil functions. The decline coincides with a simultaneous reduction in useable land areas and worsens food production amongst others. Therefore, it is mandatory, that stable soil structure from the surface down to depth prevents soil compaction, sustains water infiltration, reduces rates of soil erosion by water and wind in each case to the minimum possible under the soil, terrain, land use, and climatic conditions in which the soils occur. It improves organic carbon storage in soils and optimizes microbial activity and functions. These benefits coincide with sustainable soil properties and soil management systems, which prevent - deep mechanical stress propagation which can cause irreversible soil deformation, - loss of surface soil layers with coinciding organic and mineral nutrient pool available for microbial processing and plant uptake, - Truncation of soil horizons, or damage on private and public infrastructures (roads, houses) and downstream fields. In order to prevent negative impacts on soils, it is recommended, that A) concerning prevention of soil compaction - stresses applied to soils shall not exceed the mechanical soil stability to maintain the actual functioning of chemical, physical and biological processes and to utilize their resilience (i.e. the elasticity), - land use management strategies have to be related to the actual soil properties in order to optimize plant growth, yield, filtering and buffering of infiltrating water, and carbon sequestration. B) soil erosion by - water, wind, and tillage is counteracted by an adequate surface soil stability including a site specific residue management (e.g. conservation tillage), controlled traffic and harvesting, ecological grassland use strategies (e

  18. An integrated (nano-bio) technique for degradation of γ-HCH contaminated soil

    Energy Technology Data Exchange (ETDEWEB)

    Singh, Ritu [Ecotoxicology Division, CSIR-Indian Institute of Toxicology Research, Post Box 80, Mahatma Gandhi Marg, Lucknow 226 001, UP (India); Analytical Chemistry Division, CSIR-Indian Institute of Toxicology Research, Post Box 80, Mahatma Gandhi Marg, Lucknow 226 001, UP (India); Manickam, Natesan [Environmental Biotechnology Division, CSIR-Indian Institute of Toxicology Research, Post Box 80, Mahatma Gandhi Marg, Lucknow 226 001, UP (India); Mudiam, Mohana Krishna Reddy [Analytical Chemistry Division, CSIR-Indian Institute of Toxicology Research, Post Box 80, Mahatma Gandhi Marg, Lucknow 226 001, UP (India); Murthy, Ramesh Chandra, E-mail: murthyrc729@gmail.com [Analytical Chemistry Division, CSIR-Indian Institute of Toxicology Research, Post Box 80, Mahatma Gandhi Marg, Lucknow 226 001, UP (India); Misra, Virendra, E-mail: virendra_misra2001@yahoo.co.in [Ecotoxicology Division, CSIR-Indian Institute of Toxicology Research, Post Box 80, Mahatma Gandhi Marg, Lucknow 226 001, UP (India)

    2013-08-15

    Highlights: • An integrated (nano-bio) technique is employed to degrade γ-HCH in soil. • Degradation efficiency of γ-HCH in integrated and individual systems is compared. • Synergistic effect was noticed on γ-HCH degradation in integrated system. • Integrated system was found 1.7–2.1 times more efficient than individual methods. • This technique could be exploited for other chlorinated pesticides as well. -- Abstract: We have evaluated the effect of an integrated (nano-bio) technique involving the use of stabilized Pd/Fe{sup 0} bimetallic nanoparticles (CMC-Pd/nFe{sup 0}) and a Sphingomonas sp. strain NM05, on the degradation of γ-HCH in soil. Factors affecting degradation such as pH, incubation temperature and γ-HCH initial concentration were also studied. The results revealed that γ-HCH degradation efficiency is ∼ 1.7–2.1 times greater in integrated system as compared to system containing either NM05 or CMC-Pd/nFe{sup 0} alone. The integration showed synergistic effect on γ-HCH degradation. Further, cell growth studies indicated that NM05 gets well acclimatized to nanoparticles, showing potential growth in the presence of CMC-Pd/nFe{sup 0} with respect to control system. This study signifies the potential efficacy of integrated technique to become an effective alternative remedial tool for γ-HCH contaminated soil. Further research in this direction could lead to the development of effective remediation strategies for other isomers of HCH and other chlorinated pesticides as well.

  19. Bioremediation Potential of Native Hydrocarbons Degrading Bacteria in Crude Oil Polluted Soil

    Directory of Open Access Journals (Sweden)

    Mariana MARINESCU

    2017-05-01

    Full Text Available Bioremediation of crude oil contaminated soil is an effective process to clean petroleum pollutants from the environment. Crude oil bioremediation of soils is limited by the bacteria activity in degrading the spills hydrocarbons. Native crude oil degrading bacteria were isolated from different crude oil polluted soils. The isolated bacteria belong to the genera Pseudomonas, Mycobacterium, Arthrobacter and Bacillus. A natural biodegradable product and bacterial inoculum were used for total petroleum hydrocarbon (TPH removal from an artificial polluted soil. For soil polluted with 5% crude oil, the bacterial top, including those placed in the soil by inoculation was 30 days after impact, respectively 7 days after inoculum application, while in soil polluted with 10% crude oil,  multiplication top of bacteria was observed in the determination made at 45 days after impact and 21 days after inoculum application, showing once again how necessary is for microorganisms habituation and adaptation to environment being a function of pollutant concentration. The microorganisms inoculated showed a slight adaptability in soil polluted with 5% crude oil, but complete inhibition in the first 30 days of experiment at 10% crude oil.

  20. Exploration of hydrocarbon degrading bacteria on soils contaminated by crude oil from South Sumatera

    Directory of Open Access Journals (Sweden)

    A. Napoleon

    2014-07-01

    Full Text Available The goal of this research was to explore hydrocarbon degrading bacteria on crude oil contaminated soil with potential to degrade hydrocarbon in oil pollutant. The research started by early August 2013 till January 2014. Soil sampling for this research was taken on several places with contaminated soil location such as Benakat, Rimau, and Pengabuan all of it located in South Sumatera. Conclusion from this research Isolates obtained from three (3 sites of contaminated soil and treated using SBS medium were Bacillus cereus, Pseudomonas aeruginosa, Klebsiella pnumoniae, Streptococcus beta hemolisa, Proteus mirabilis, Staphylococcus epidermis and Acinotobacter calcoaceticus. Isolates that survived on 300 ppm of hydrocarbon concentration were Bacillus cereus, Pseudomonas aeruginosa and Acinetobacter cakciaceticus Selected isolates posses the ability to degrade hydrocarbon by breaking hydrocarbon substance as the energy source to support isolates existence up to 1,67 TPH level. Based on results accomplish by this research, we urge for further research involving the capacity of isolates to degrade wide variety of hydrocarbon substance and more to develop the potential of these bacteria for bioremediation.

  1. Apparent Contradiction: Psychrotolerant Bacteria from Hydrocarbon-Contaminated Arctic Tundra Soils That Degrade Diterpenoids Synthesized by Trees

    Science.gov (United States)

    Yu, Zhongtang; Stewart, Gordon R.; Mohn, William W.

    2000-01-01

    Resin acids are tricyclic terpenoids occurring naturally in trees. We investigated the occurrence of resin acid-degrading bacteria on the Arctic tundra near the northern coast of Ellesmere Island (82°N, 62°W). According to most-probable-number assays, resin acid degraders were abundant (103 to 104 propagules/g of soil) in hydrocarbon-contaminated soils, but they were undetectable (soil) in pristine soils from the nearby tundra. Plate counts indicated that the contaminated and the pristine soils had similar populations of heterotrophs (106 to 107 propagules/g of soil). Eleven resin acid-degrading bacteria belonging to four phylogenetically distinct groups were enriched and isolated from the contaminated soils, and representative isolates of each group were further characterized. Strains DhA-91, IpA-92, and IpA-93 are members of the genus Pseudomonas. Strain DhA-95 is a member of the genus Sphingomonas. All four strains are psychrotolerant, with growth temperature ranges of 4°C to 30°C (DhA-91 and DhA-95) or 4°C to 22°C (IpA-92 and IpA-93) and with optimum temperatures of 15 to 22°C. Strains DhA-91 and DhA-95 grew on the abietanes, dehydroabietic and abietic acids, but not on the pimaranes, isopimaric and pimaric acids. Strains IpA-92 and IpA-93 grew on the pimaranes but not the abietanes. All four strains grew on either aliphatic or aromatic hydrocarbons, which is unusual for described resin acid degraders. Eleven mesophilic resin acid degraders did not use hydrocarbons, with the exception of two Mycobacterium sp. strains that used aliphatic hydrocarbons. We conclude that hydrocarbon contamination in Arctic tundra soil indirectly selected for resin acid degraders, selecting for hydrocarbon degraders that coincidentally use resin acids. Psychrotolerant resin acid degraders are likely important in the global carbon cycle and may have applications in biotreatment of pulp and paper mill effluents. PMID:11097882

  2. Study on Soil Mobility of Two Neonicotinoid Insecticides

    Directory of Open Access Journals (Sweden)

    Mária Mörtl

    2016-01-01

    Full Text Available Movement of two neonicotinoid insecticide active ingredients, clothianidin (CLO and thiamethoxam (TMX, was investigated in different soil types (sand, clay, or loam and in pumice. Elution profiles were determined to explore differences in binding capacity. Soil characterized by high organic matter content retained the ingredients, whereas high clay content resulted in long release of compounds. Decrease in concentration was strongly influenced by soil types: both CLO and TMX were retained in loam and clay soils and showed ready elution through sandy soil and pumice. Elution capability of the active ingredients in sandy soil correlated with their water solubility, indicating approximately 30% higher rapidity for TMX than for CLO. Soil organic carbon-water partitioning coefficients (Koc determined were in good agreement with literature values with somewhat lower value for CLO in sandy soil and substantially higher values for TMX in clay soil. High mobility of these neonicotinoid active ingredients in given soil types urges stronger precautionary approach taken during their application.

  3. The influence of reduced tillage on water regime and nutrient leaching in a loamy soil

    OpenAIRE

    Baigys, Giedrius; Gaigalis, Kazimieras; Kutra, Ginutis

    2006-01-01

    The effect of tillage technologies and terms on soil moisture regime and nitrate leaching was studied in field trials carried out on 0.76-1.36-ha fields. The study site was arranged in Pikeliai village (Kėdainiai district). The soil prevailing in the study site is Endocalcari - Endohypogleic Cambisol, sandy light loam and sandy loam on deeper layers of sandy loam and sandy light loam. The arable horizon contains sandy light loam, which is characteristic of the soils prevailing in the Middle L...

  4. Pedotransfer functions estimating soil hydraulic properties using different soil parameters

    DEFF Research Database (Denmark)

    Børgesen, Christen Duus; Iversen, Bo Vangsø; Jacobsen, Ole Hørbye

    2008-01-01

    Estimates of soil hydraulic properties using pedotransfer functions (PTF) are useful in many studies such as hydrochemical modelling and soil mapping. The objective of this study was to calibrate and test parametric PTFs that predict soil water retention and unsaturated hydraulic conductivity...... parameters. The PTFs are based on neural networks and the Bootstrap method using different sets of predictors and predict the van Genuchten/Mualem parameters. A Danish soil data set (152 horizons) dominated by sandy and sandy loamy soils was used in the development of PTFs to predict the Mualem hydraulic...... conductivity parameters. A larger data set (1618 horizons) with a broader textural range was used in the development of PTFs to predict the van Genuchten parameters. The PTFs using either three or seven textural classes combined with soil organic mater and bulk density gave the most reliable predictions...

  5. Deep Soil Recharge in Arid and Semi-Arid Regions: New Evidences in MU-US Sandy Land of China

    Science.gov (United States)

    Cheng, Y.; Yang, W.; Zhan, H.

    2017-12-01

    Precipitation induced recharge is an important source of groundwater budget but it is very difficult to quantify in arid and semiarid regions. In this study, a newly invented lysimeter was used to monitor deep soil recharge (DSR) under 200 cm depth in MU-US sandy land in western China under three kinds of landforms (mobile dune, semi-fixed dune, and fixed dune). We found that the annual DSRs in such three different kinds of landforms varied significantly. Specifically, the annual DSRs were 224.1 mm (50.5% of the annual precipitation), 71.1 mm (50.5% of the annual precipitation), and 1.3 mm (0.3% of the annual precipitation) in mobile dune, semi-fixed dune, and fixed dune, respectively. We also found that vegetation coverage and precipitation pattern significantly affected DSR. A 24-hr precipitation event with the precipitation amount greater than 8 mm was able to infiltrate soil deeper than 200 cm and contributed to ground water recharge directly. Vegetation was a dominant factor influencing infiltration in the fixed sand dune. Our research revealed that precipitation induced DSR in arid and semi-arid regions was a complex process that required long-term monitoring and innovative system analysis of interrelated factors such as precipitation strength and pattern, meteorological parameters, and dynamic soil moisture. Key words: Precipitation pattern, sand dune groundwater, deep soil recharge, infiltration.

  6. Associations of Pseudomonas species and forage grasses enhance degradation of chlorinated benzoic acids in soil

    Energy Technology Data Exchange (ETDEWEB)

    Siciliano, S. D.

    1998-12-01

    Using chlorinated benzoic acid (CBA) as a model compound, this study attempted to show that microorganisms and plants can be used as bioremediation agents to clean up contaminated soil sites in a cost effective and environmentally friendly manner. CBA was used because it is present in soils contaminated with polychlorinated biphenyls (PCBs), or chlorinated pesticides. Sixteen forage grasses were screened in combination with 12 bacterial inoculants for their ability to promote the degradation of CBA in soil. Five associations of plants and bacteria were found to degrade CBA to a greater extent than plants without bacterial inoculants. Bacterial inoculants were shown to stimulate CBA degradation by altering the microbial community present on the root surface and thereby increasing the ability of this community to degrade CBA.

  7. [Degradation characteristics of naphthalene with a Pseudomonas aeruginosa strain isolated from soil contaminated by diesel].

    Science.gov (United States)

    Liu, Wen-Chao; Wu, Bin-Bin; Li, Xiao-Sen; Lu, Dian-Nan; Liu, Yong-Min

    2015-02-01

    Abstract: A naphthalene-degrading bacterium (referred as HD-5) was isolated from the diesel-contaminated soil and was assigned to Pseudomonas aeruginosa according to 16S rDNA sequences analysis. Gene nah, which encodes naphthalene dioxygenase, was identified from strain HD-5 by PCR amplification. Different bioremediation approaches, including nature attenuation, bioaugmentation with strain Pseudomonas aeruginosa, biostimulation, and an integrated degradation by bioaugmentation and biostimulation, were evaluated for their effectiveness in the remediating soil containing 5% naphthalene. The degradation rates of naphthalene in the soil were compared among the different bioremediation approaches, the FDA and dehydrogenase activity in bioremediation process were measured, and the gene copy number of 16S rRNA and nah in soil were dynamically monitored using real-time PCR. It was shown that the naphthalene removal rate reached 71.94%, 62.22% and 83.14% in approaches of bioaugmentation (B), biostimulation(S) and integrated degradation composed of bioaugmentation and biostimulation (BS), respectively. The highest removal rate of naphthalene was achieved by using BS protocol, which also gives the highest FDA and dehydrogenase activity. The gene copy number of 16S rRNA and nah in soil increased by about 2.67 x 10(11) g(-1) and 8.67 x 10(8) g(-1) after 31 days treatment using BS protocol. Above-mentioned results also demonstrated that the screened bacterium, Pseudomonas aeruginosa, could grow well in naphthalene-contaminated soil and effectively degrade naphthalene, which is of fundamental importance for bioremediation of naphthalene-contaminated soil.

  8. DEGRADATION AND MIGRATION OF VINCLOZOLIN IN SAND AND SOIL

    Science.gov (United States)

    The migration of the dicarboximide fungicide vinclozolin and its principal degradation products through porous media was experimentally determined by simulating pesticide applications to a 23-30 mesh Ottawa sand and a North Carolina Piedmont, aquic hapludult soil in laboratory ...

  9. Assessment of soil ecosystem in degraded areas of vineyards after organic treatments

    Science.gov (United States)

    Landi, Silvia; D'Errico, Giada; Gagnarli, Elena; Simoni, Sauro; Goggioli, Donatella; Guidi, Silvia; D'Avino, Lorenzo; Lagomarsino, Alessandra; Valboa, Giuseppe; Castaldini, Maurizio; Elio Agnelli, Alessandro; Fantappiè, Maria; Lorenzetti, Romina; Priori, Simone; Costantini, Edoardo A. C.

    2017-04-01

    In Italian vineyards, it is quite common to have areas characterized by problems in vine health, grape production and quality, often caused by improper land preparation before vine plantation and/or management. Causes for soil malfunctioning can include reduced contribution of the soil fauna to the ecosystem services such as nutrient cycles and organic matter turnover. ReSolVe is a transnational and interdisciplinary project, supported by Core-Organic+ program, aimed at testing the effects of selective agronomic strategies for restoring optimal soil functionality in degraded areas within organic vineyard. For this purpose, the evaluation and biomonitoring of the abundance of soil mesofauna, nematodes and microarthropods, represents an efficient tool to characterize the effects of crop management on soil quality. Assessing enzyme activities involved in the main biogeochemical cycling of C, N, P and S can also provide indication of soil functions and health status. Italian experimental plots are situated in two commercial farms in Tuscany: i) Fontodi, Panzano in Chianti (FI), which has been managed organically for more than 20 years and ii) San Disdagio, Roccastrada (GR), under organic farming since 2014. In each farm, three plots (250 m2 each) in the degraded areas and three relative control plots in the non-degraded areas were selected. The different restoring strategies implemented in each area were: i) compost, produced on farm by manure + pruning residue + grass, ii) faba bean and winter barley green manure, iii) dry mulching after sowing with Trifolium squarrosum L. Each treated and control plot has been studied for soil nematodes, microarthropods, enzymatic activity, and organic matter turnover using tea-bag index, as well as total organic carbon (TOC) and total nitrogen (TN). Soil sampling was carried out to 0-30 cm depth for TOC, TN, enzymes and nematodes and to 10 cm for microarthropods. Tea-bag index was determined following the Keuskamp et al. method

  10. Vertical small scale variations of sorption and mineralization of three herbicides in subsurface limestone and sandy aquifer

    Science.gov (United States)

    Janniche, G. S.; Mouvet, C.; Albrechtsen, H.-J.

    2011-04-01

    Vertical variation in sorption and mineralization potential of mecoprop (MCPP), isoproturon and acetochlor were investigated at low concentrations (μg-range) at the cm-scale in unsaturated sub-surface limestone samples and saturated sandy aquifer samples from an agricultural catchment in Brévilles, France. From two intact core drills, four heterogenic limestone sections were collected from 4.50 to 26.40 m below surface (mbs) and divided into 12 sub-samples of 8-25 cm length, and one sandy aquifer section from 19.20 to 19.53 m depth divided into 7 sub-samples of 4-5 cm length. In the sandy aquifer section acetochlor and isoproturon sorption increased substantially with depth; in average 78% (acetochlor) and 61% (isoproturon) per 5 cm. Also the number of acetochlor and isoproturon degraders (most-probable-number) was higher in the bottom half of the aquifer section (93-> 16 000/g) than in the upper half (4-71/g). One 50 cm long limestone section with a distinct shift in color showed a clear shift in mineralization, number of degraders and sorption: In the two brown, uppermost samples, up to 31% mecoprop and up to 9% isoproturon was mineralized during 231 days, the numbers of mecoprop and isoproturon degraders were 1300 to > 16 000/g, and the sorption of both isoproturon and acetochlor was more than three times higher, compared to the two deeper, grayish samples just below where mineralization (≤ 4%) and numbers of degraders (1-520/g) were low for all three herbicides. In both unsaturated limestone and sandy aquifer, variations and even distinct shifts in both mineralization, number of specific degraders and sorption were seen within just 4-15 cm of vertical distance. A simple conceptual model of herbicides leaching to groundwater through a 10 m unsaturated limestone was established, and calculations showed that a 30 cm active layer with the measured sorption and mineralization values hardly impacted the fate of the investigated herbicides, whereas a total

  11. Determination of soil degradation in argentine semi-arid environments from remote sensors: case department of patagones, province of buenos aires

    Science.gov (United States)

    Pezzola, Alejandro; Cacella, Alejandra; Enrique, Mario; Winschel, Cristina

    2017-04-01

    The continental territory of the Argentine Republic owns 75% of its surface under arid and semiarid conditions to the west of the meridian of 64°. Wind erosion is the main physical cause of desertification. In the Pampena area, studies showed that the sandy loam soils were more pronounced than the sandy loam with significant losses of organic matter, decreases in the cation exchange capacity and modification of the mineral composition of the very fine sand fraction (From 73 to 100 μm), with increases in the proportion of heavy minerals (magnetite) relative to light (quartz). In the Patagones department, Buenos Aires province, the soils with a sandy-loamy texture, which are transported by wind and deposited on calcium carbonate (tosca), with little moisture retention and susceptible to wind erosion. In the 1980s and 1990s, increases in rainfall above the historical average led to a shift of the isohytes towards the southwest, leading to agricultural intensification that caused greater pressure on the soil and native vegetation. This advance on the native vegetation within the Patagones produced a reduction between 1975 and 2009 of 432,280 ha, leaving only 31% of the area covered by native forest - shrub xerophyte today. Between 2005-2009, the call "agricultural drought" caused losses in crops, wheat - oats and natural pastures associated with the native forest, causing a significant deterioration of the soil, exposing them to wind erosion. Remote sensors represent a very valuable technology for the mapping and evaluation of soil erosion. The availability of multispectral images allows the mapping and monitoring of changes in the dynamics of the erosion process. The objective of this work was to make an expeditious diagnosis of the surface affected by wind erosion and to evaluate the degree to which the soils destined for agriculture and livestock were affected. For this purpose, Terra's MODIS (Moderate-Resolution Imaging Spectroradiometer) sensor information was

  12. Passive Microwave Observation of Soil Water Infiltration

    Science.gov (United States)

    Jackson, Thomas J.; Schmugge, Thomas J.; Rawls, Walter J.; ONeill, Peggy E.; Parlange, Marc B.

    1997-01-01

    Infiltration is a time varying process of water entry into soil. Experiments were conducted here using truck based microwave radiometers to observe small plots during and following sprinkler irrigation. Experiments were conducted on a sandy loam soil in 1994 and a silt loam in 1995. Sandy loam soils typically have higher infiltration capabilities than clays. For the sandy loam the observed brightness temperature (TB) quickly reached a nominally constant value during irrigation. When the irrigation was stopped the TB began to increase as drainage took place. The irrigation rates in 1995 with the silt loam soil exceeded the saturated conductivity of the soil. During irrigation the TB values exhibited a pattern that suggests the occurrence of coherent reflection, a rarely observed phenomena under natural conditions. These results suggested the existence of a sharp dielectric boundary (wet over dry soil) that was increasing in depth with time.

  13. Effect of dairy manure rate and the stabilization time of amended soils on atrazine degradation.

    Science.gov (United States)

    Aguilera, Paula; Briceño, Gabriela; Candia, Maribel; Mora, Maria de la Luz; Demanet, Rolando; Palma, Graciela

    2009-10-01

    The application rate of liquid cow manure (LCM) in the field and the stabilization time of amended soils before application of pre-plant herbicides are factors that determine their efficiency. This study includes evaluation of residual atrazine (2-chloro-4-ethylamino-6-isopropylamino-1,3,5-triazine) in soil and amended soils with equivalent rate of 100,000; 200,000; and 300,000 L ha(-1) of LCM and the effect of pre-incubation time of amended soils on atrazine degradation. The study was carried out under controlled conditions using an Andisol with previous historical application of atrazine. The respiratory activity and fluorescein diacetate (FDA) studies indicated that the time necessary for stabilization of amended soils is over 20-30 d. During the measurement of respiratory and FDA activity, no significant differences were observed when atrazine was applied. The half-life of atrazine ranged from 5 to 8d and the relative distribution of degradation products seem to be affected by the application of LCM. The pre-incubation time of amended soil and LCM dose would not affect atrazine degradation rate, when the soil has a history of herbicide application. However, repeated applications of LCM in a long period of time could change the soil pH and increase the content of dissolved organic carbon (DOC) which could further contribute to a faster degradation of atrazine. Both effects would reduce the effectiveness of atrazine in weed control.

  14. Effect of elevated CO2 on chlorpyriphos degradation and soil microbial activities in tropical rice soil.

    Science.gov (United States)

    Adak, Totan; Munda, Sushmita; Kumar, Upendra; Berliner, J; Pokhare, Somnath S; Jambhulkar, N N; Jena, M

    2016-02-01

    Impact of elevated CO2 on chlorpyriphos degradation, microbial biomass carbon, and enzymatic activities in rice soil was investigated. Rice (variety Naveen, Indica type) was grown under four conditions, namely, chambered control, elevated CO2 (550 ppm), elevated CO2 (700 ppm) in open-top chambers and open field. Chlorpyriphos was sprayed at 500 g a.i. ha(-1) at maximum tillering stage. Chlorpyriphos degraded rapidly from rice soils, and 88.4% of initially applied chlorpyriphos was lost from the rice soil maintained under elevated CO2 (700 ppm) by day 5 of spray, whereas the loss was 80.7% from open field rice soil. Half-life values of chlorpyriphos under different conditions ranged from 2.4 to 1.7 days with minimum half-life recorded with two elevated CO2 treatments. Increased CO2 concentration led to increase in temperature (1.2 to 1.8 °C) that played a critical role in chlorpyriphos persistence. Microbial biomass carbon and soil enzymatic activities specifically, dehydrogenase, fluorescien diacetate hydrolase, urease, acid phosphatase, and alkaline phosphatase responded positively to elevated CO2 concentrations. Generally, the enzyme activities were highly correlated with each other. Irrespective of the level of CO2, short-term negative influence of chlorpyriphos was observed on soil enzymes till day 7 of spray. Knowledge obtained from this study highlights that the elevated CO2 may negatively influence persistence of pesticide but will have positive effects on soil enzyme activities.

  15. Predictable bacterial composition and hydrocarbon degradation in Arctic soils following diesel and nutrient disturbance

    Science.gov (United States)

    Bell, Terrence H; Yergeau, Etienne; Maynard, Christine; Juck, David; Whyte, Lyle G; Greer, Charles W

    2013-01-01

    Increased exploration and exploitation of resources in the Arctic is leading to a higher risk of petroleum contamination. A number of Arctic microorganisms can use petroleum for growth-supporting carbon and energy, but traditional approaches for stimulating these microorganisms (for example, nutrient addition) have varied in effectiveness between sites. Consistent environmental controls on microbial community response to disturbance from petroleum contaminants and nutrient amendments across Arctic soils have not been identified, nor is it known whether specific taxa are universally associated with efficient bioremediation. In this study, we contaminated 18 Arctic soils with diesel and treated subsamples of each with monoammonium phosphate (MAP), which has successfully stimulated degradation in some contaminated Arctic soils. Bacterial community composition of uncontaminated, diesel-contaminated and diesel+MAP soils was assessed through multiplexed 16S (ribosomal RNA) rRNA gene sequencing on an Ion Torrent Personal Genome Machine, while hydrocarbon degradation was measured by gas chromatography analysis. Diversity of 16S rRNA gene sequences was reduced by diesel, and more so by the combination of diesel and MAP. Actinobacteria dominated uncontaminated soils with soils, and this pattern was exaggerated following disturbance. Degradation with and without MAP was predictable by initial bacterial diversity and the abundance of specific assemblages of Betaproteobacteria, respectively. High Betaproteobacteria abundance was positively correlated with high diesel degradation in MAP-treated soils, suggesting this may be an important group to stimulate. The predictability with which bacterial communities respond to these disturbances suggests that costly and time-consuming contaminated site assessments may not be necessary in the future. PMID:23389106

  16. Nitrous oxide emission from soils amended with crop residues

    NARCIS (Netherlands)

    Velthof, G.L.; Kuikman, P.J.; Oenema, O.

    2002-01-01

    Crop residues incorporated in soil are a potentially important source of nitrous oxide (N2O), though poorly quantified. Here, we report on the N2O emission from 10 crop residues added to a sandy and a clay soil, both with and without additional nitrate (NO3-). In the sandy soil, total nitrous oxide

  17. Fate of glyphosate and degradates in cover crop residues and underlying soil: A laboratory study

    Energy Technology Data Exchange (ETDEWEB)

    Cassigneul, A. [Université de Toulouse — École d' ingénieurs de Purpan, UMR 1248 AGIR — 75, Voie du TOEC BP 57 611, 31 076, Toulouse cedex 3 (France); INRA, UMR 1402 ECOSYS, 78850 Thiverval-Grignon (France); Benoit, P.; Bergheaud, V.; Dumeny, V.; Etiévant, V. [INRA, UMR 1402 ECOSYS, 78850 Thiverval-Grignon (France); Goubard, Y. [AgroParisTech, UMR 1402 ECOSYS, 78850 Thiverval-Grignon (France); Maylin, A. [Université de Toulouse — École d' ingénieurs de Purpan, UMR 1248 AGIR — 75, Voie du TOEC BP 57 611, 31 076, Toulouse cedex 3 (France); Justes, E. [INRA, UMR 1248 AGIR Auzeville — BP 52 627, 31 326, Castanet-Tolosan cedex (France); Alletto, L. [Université de Toulouse — École d' ingénieurs de Purpan, UMR 1248 AGIR — 75, Voie du TOEC BP 57 611, 31 076, Toulouse cedex 3 (France)

    2016-03-01

    The increasing use of cover crops (CC) may lead to an increase in glyphosate application for their destruction. Sorption and degradation of {sup 14}C-glyphosate on and within 4 decaying CC-amended soils were compared to its fate in a bare soil. {sup 14}C-Glyphosate and its metabolites distribution between mineralized, water-soluble, NH{sub 4}OH-soluble and non-extractable fractions was determined at 5 dates during a 20 °C/84-d period. The presence of CC extends {sup 14}C-glyphosate degradation half-life from 7 to 28 days depending on the CC. {sup 14}C-Glyphosate dissipation occurred mainly through mineralization in soils and through mineralization and bound residue formation in decaying CC. Differences in sorption and degradation levels were attributed to differences in composition and availability to microorganisms. CC- and soil-specific dissipation patterns were established with the help of explicit relationships between extractability and microbial activity. - Highlights: • Glyphosate sorption on cover crop residues increases with their decomposition degree. • Glyphosate degradation and mineralization are lower in mulch than in soil. • Nonextractable residue formation is one of the main dissipation pathways of glyphosate in cover crop mulch.

  18. Fate of glyphosate and degradates in cover crop residues and underlying soil: A laboratory study

    International Nuclear Information System (INIS)

    Cassigneul, A.; Benoit, P.; Bergheaud, V.; Dumeny, V.; Etiévant, V.; Goubard, Y.; Maylin, A.; Justes, E.; Alletto, L.

    2016-01-01

    The increasing use of cover crops (CC) may lead to an increase in glyphosate application for their destruction. Sorption and degradation of "1"4C-glyphosate on and within 4 decaying CC-amended soils were compared to its fate in a bare soil. "1"4C-Glyphosate and its metabolites distribution between mineralized, water-soluble, NH_4OH-soluble and non-extractable fractions was determined at 5 dates during a 20 °C/84-d period. The presence of CC extends "1"4C-glyphosate degradation half-life from 7 to 28 days depending on the CC. "1"4C-Glyphosate dissipation occurred mainly through mineralization in soils and through mineralization and bound residue formation in decaying CC. Differences in sorption and degradation levels were attributed to differences in composition and availability to microorganisms. CC- and soil-specific dissipation patterns were established with the help of explicit relationships between extractability and microbial activity. - Highlights: • Glyphosate sorption on cover crop residues increases with their decomposition degree. • Glyphosate degradation and mineralization are lower in mulch than in soil. • Nonextractable residue formation is one of the main dissipation pathways of glyphosate in cover crop mulch.

  19. Biophysical-and socioeconomic aspects of land degradation in the Guadalentin (SE-Spain): towards understanding and effective soil conservation

    International Nuclear Information System (INIS)

    Vente, J. de; Sole-Benet, A.; Boix-Fayos, C.; Nainggolan, D.; Romero-Diaz, A.

    2009-01-01

    Desertification and land degradation have been widely studied in the Guadalentin basin (SE Spain) through various national and international research projects. Most important identified degradation types are due to soil erosion, soil surface crusting, aridity, soil organic matter decline and salinisation. On the one hand, political and socioeconomic drivers have caused important land use and management changes, which have formed an important driver for further land degradation. On the other hand, soil conservation practice were initiated by the government and by individual land users, although there is very limited knowledge on their effectiveness. the objective of this work is to provide and overview of previous studies that addressed land degradation in the Guadalentin and to present an integrated synthesis of the main biophysical and socioeconomic factors identifies in these studies as being responsible for land degradation, with a focus on feasible soil conservation strategies. (Author) 18 refs.

  20. Biophysical-and socioeconomic aspects of land degradation in the Guadalentin (SE-Spain): towards understanding and effective soil conservation

    Energy Technology Data Exchange (ETDEWEB)

    Vente, J. de; Sole-Benet, A.; Boix-Fayos, C.; Nainggolan, D.; Romero-Diaz, A.

    2009-07-01

    Desertification and land degradation have been widely studied in the Guadalentin basin (SE Spain) through various national and international research projects. Most important identified degradation types are due to soil erosion, soil surface crusting, aridity, soil organic matter decline and salinisation. On the one hand, political and socioeconomic drivers have caused important land use and management changes, which have formed an important driver for further land degradation. On the other hand, soil conservation practice were initiated by the government and by individual land users, although there is very limited knowledge on their effectiveness. the objective of this work is to provide and overview of previous studies that addressed land degradation in the Guadalentin and to present an integrated synthesis of the main biophysical and socioeconomic factors identifies in these studies as being responsible for land degradation, with a focus on feasible soil conservation strategies. (Author) 18 refs.

  1. Longevity of terrestrial Carbon sinks: effects of soil degradation on greenhouse gas emissions

    Science.gov (United States)

    Kuhn, Nikolaus J.; Berger, Samuel; Kuonen, Samuel

    2013-04-01

    Soil erosion by water is a key process of soil and land degradation. In addition, significant amounts of nutrients and organic Carbon are moved from eroding source areas to landscape sinks. As a consequence, areas affected by erosion suffer a loss of fertility, while sinks experience the development of a stockpile of the deposited sediment, including soil organic matter and nutrients. The deposited nutrients are largely unavailable for the plants growing in these landscape sediment sinks once the thickness of the deposited layer is greater than the rooting depth of the plants. In addition, the deposited organic matter is decomposed slowly through the pack of sediment. At sites of erosion, nutrients have to be replaced and organic matter content of the soil declines due to a destruction of the A horizon. Over time, the risk of a significant reduction in productivity, for example caused by a loss of top soil with a sufficient water storage capacity for maximum plant growth, leads to a decline in CO2 uptake by photosynthesis. Soil organic matter at eroding sites therefore declines and consequently the sediment that is moved to landscape sinks also has a smaller organic matter content than sediment generated from the non-degraded soil. The sediment sinks, on the other hand, emit an increasing amount of greenhouse gases as a consequence of the increasing amount of organic matter deposited while the upslope area is eroded. Over time, the perceived sink effect of soil erosion for greenhouse gases is therefore replaced with a neutral or positive emission balance of erosion in agricultural landscapes. Such a switch from none or a negative emission balance of agricultural landscapes to a positive balance carries the risk of accelerating climate change. In this study, we tried to estimate the risk associated with ongoing soil degradation and closing landscape soil organic matter sinks. Currently observed global erosion rates were linked to known limitations of soil

  2. Suitability of soils of the university of Nigeria, Nsukka for the ...

    African Journals Online (AJOL)

    The Nkpologu series of valley bottom, plain and gentle slopes (0-6%) are suitable due to favorable topography, moderately heavy soil textures (sandy clay loam to sandy loam at the topsoil, and sandy clay at the subsoil), and relative soil fertility (with average topsoil % base sat. on the basis of ECEC of 45.08% and O.M. ...

  3. Degradation of biodegradable plastic mulch films in soil environment by phylloplane fungi isolated from gramineous plants.

    Science.gov (United States)

    Koitabashi, Motoo; Noguchi, Masako T; Sameshima-Yamashita, Yuka; Hiradate, Syuntaro; Suzuki, Ken; Yoshida, Shigenobu; Watanabe, Takashi; Shinozaki, Yukiko; Tsushima, Seiya; Kitamoto, Hiroko K

    2012-08-02

    To improve the biodegradation of biodegradable plastic (BP) mulch films, 1227 fungal strains were isolated from plant surface (phylloplane) and evaluated for BP-degrading ability. Among them, B47-9 a strain isolated from the leaf surface of barley showed the strongest ability to degrade poly-(butylene succinate-co-butylene adipate) (PBSA) and poly-(butylene succinate) (PBS) films. The strain grew on the surface of soil-mounted BP films, produced breaks along the direction of hyphal growth indicated that it secreted a BP-degrading enzyme, and has directly contributing to accelerating the degradation of film. Treatment with the culture filtrate decomposed 91.2 wt%, 23.7 wt%, and 14.6 wt% of PBSA, PBS, and commercially available BP polymer blended mulch film, respectively, on unsterlized soil within 6 days. The PCR-DGGE analysis of the transition of soil microbial community during film degradation revealed that the process was accompanied with drastic changes in the population of soil fungi and Acantamoeba spp., as well as the growth of inoculated strain B47-9. It has a potential for application in the development of an effective method for accelerating degradation of used plastics under actual field conditions.

  4. Spatial pattern of soil organic carbon and total nitrogen, and analysis of related factors in an agro-pastoral zone in Northern China

    Science.gov (United States)

    Wang, Xuyang; Chen, Yinping; Lian, Jie; Luo, Yongqing; Niu, Yayi; Gong, Xiangwen

    2018-01-01

    The spatial pattern of soil organic carbon (SOC) and total nitrogen (TN) densities plays a profound important role in estimating carbon and nitrogen budgets. Naiman Banner located in northern China was chosen as research site, a total of 332 soil samples were taken in a depth of 100 cm from the low hilly land in the southern part, sandy land in the middle part and an alluvial plain in the northern part of the county. The results showed that SOC and TN density initially decreased and then increased from the north to the south, The highest densities, were generally in the south, with the lowest generally in the middle part. The SOC and TN densities in cropland were significantly greater than those in woodland and grassland in the alluvial plains and for Naiman as a whole. The woodland SOC and TN density were higher than those of grassland in the low hilly land, and higher densities of SOC and TN in grassland than woodland in the sandy land and low hilly land. There were significant differences in SOC and TN densities among the five soil types of Cambisols, Arenosols, Gleysols, Argosols, and Kastanozems. In addition, SOC and TN contents generally decreased with increasing soil depth, but increased below a depth of 40 cm in the Cambisols and became roughly constant at this depth in the Kastanozems. There is considerable potential to sequester carbon and nitrogen in the soil via the conversion of degraded sandy land into woodland and grassland in alluvial plain, and more grassland should be established in sandy land and low hilly land. PMID:29771979

  5. Land Sensitivity Analysis of Degradation using MEDALUS model: Case Study of Deliblato Sands, Serbia

    Directory of Open Access Journals (Sweden)

    Kadović Ratko

    2016-12-01

    Full Text Available This paper studies the assessment of sensitivity to land degradation of Deliblato sands (the northern part of Serbia, as a special nature reserve. Sandy soils of Deliblato sands are highly sensitive to degradation (given their fragility, while the system of land use is regulated according to the law, consisting of three zones under protection. Based on the MEDALUS approach and the characteristics of the study area, four main factors were considered for evaluation: soil, climate, vegetation and management. Several indicators affecting the quality of each factor were identified. Each indicator was quantified according to its quality and given a weighting of between 1.0 and 2.0. ArcGIS 9 was utilized to analyze and prepare the layers of quality maps, using the geometric mean to integrate the individual indicator map. In turn, the geometric mean of all four quality indices was used to generate sensitivity of land degradation status map. Results showed that 56.26% of the area is classified as critical; 43.18% as fragile; 0.55% as potentially affected and 0.01% as not affected by degradation. The values of vegetation quality index, expressed as coverage, diversity of vegetation functions and management policy during the protection regime are clearly represented through correlation coefficient (0.87 and 0.47.

  6. Simulation of herbicide degradation in different soils by use of Pedo-transfer functions (PTF) and non-linear kinetics.

    Science.gov (United States)

    von Götz, N; Richter, O

    1999-03-01

    The degradation behaviour of bentazone in 14 different soils was examined at constant temperature and moisture conditions. Two soils were examined at different temperatures. On the basis of these data the influence of soil properties and temperature on degradation was assessed and modelled. Pedo-transfer functions (PTF) in combination with a linear and a non-linear model were found suitable to describe the bentazone degradation in the laboratory as related to soil properties. The linear PTF can be combined with a rate related to the temperature to account for both soil property and temperature influence at the same time.

  7. The Soil Program of the Restoration Seedbank Initiative: addressing knowledge gaps in degraded soils for use in dryland restoration

    Science.gov (United States)

    Muñoz-Rojas, Miriam; Bateman, Amber; Erickson, Todd E.; Turner, Shane; Merritt, David J.

    2017-04-01

    Global environmental changes and other anthropogenic impacts are rapidly transforming the structure and functioning of ecosystems worldwide. These changes are leading to land degradation with an estimated 25 % of the global land surface being affected. Landscape-scale restoration of these degraded ecosystems has therefore been recognised globally as an international priority. In the resource-rich biodiverse semi-arid Pilbara region of north-west Western Australia hundreds of thousands of hectares are disturbed due to established and emerging iron-ore mine operations. At this scale, the need to develop cost-effective large-scale solutions to restore these landscapes becomes imperative to preserve biodiversity and achieve functionality and sustainability of these ecosystems. The Restoration Seedbank Initiative (RSB) (http://www.plants.uwa.edu.au/ research/restoration-seedbank-initiative) is a five-year multidisciplinary research project that aims to build knowledge and design strategies to restore mine-impacted landscapes in the Pilbara and other arid and semi-arid landscapes worldwide (Kildiseheva et al., 2016). The RSB comprises four research programs that focus on seedbank management and curation, seed storage, seed enhancement, and the use of alternative soil substrates (soil or growing medium program) respectively. These multi-disciplinary programs address the significant challenges of landscape scale restoration in arid systems. In the soil program we follow an integrated approach that includes the characterization of undisturbed ecosystems, assessment of restored soils with the use of soil quality indicators, and design of alternative soil substrates to support the establishment of native plant communities. A series of glasshouse studies and field trials have been conducted in the last three years to advance our knowledge on soil limitations and to provide solutions to effectively overcome these challenges in arid ecosystem restoration. These studies include

  8. Bioremediation of diuron contaminated soils by a novel degrading microbial consortium.

    Science.gov (United States)

    Villaverde, J; Rubio-Bellido, M; Merchán, F; Morillo, E

    2017-03-01

    Diuron is a biologically active pollutant present in soil, water and sediments. It is persistent in soil, water and groundwater and slightly toxic to mammals and birds as well as moderately toxic to aquatic invertebrates. Its principal product of biodegradation, 3,4-dichloroaniline, exhibits a higher toxicity than diuron and is also persistent in the environment. On this basis, the objective of the study was to determine the potential capacity of a proposed novel diuron-degrading microbial consortium (DMC) for achieving not only diuron degradation, but its mineralisation both in solution as well as in soils with different properties. The consortium was tested in a soil solution where diuron was the only carbon source, and more than 98.8% of the diuron initially added was mineralised after only a few days. The consortium was composed of three diuron-degrading strains, Arthrobacter sulfonivorans, Variovorax soli and Advenella sp. JRO, the latter had been isolated in our laboratory from a highly contaminated industrial site. This work shows for the first time the potential capacity of a member of the genus Advenella to remediate pesticide-contaminated soils. However, neither of the three strains separately achieved mineralisation (ring- 14 C) of diuron in a mineral medium (MSM) with a trace nutrient solution (NS); combined in pairs, they mineralised 40% of diuron in solution, but the most relevant result was obtained in the presence of the three-member consortium, where complete diuron mineralisation was achieved after only a few days. In the presence of the investigated soils in suspension, the capacity of the consortium to mineralise diuron was evaluated, achieving mineralisation of a wide range of herbicides from 22.9 to 69.0%. Copyright © 2016 Elsevier Ltd. All rights reserved.

  9. Nitrogen Amendment Stimulated Decomposition of Maize Straw-Derived Biochar in a Sandy Loam Soil: A Short-Term Study.

    Directory of Open Access Journals (Sweden)

    Weiwei Lu

    Full Text Available This study examined the effect of nitrogen (N on biochar stability in relation to soil microbial community as well as biochar labile components using δ13C stable isotope technology. A sandy loam soil under a long-term rotation of C3 crops was amended with biochar produced from maize (a C4 plant straw in absence (BC0 and presence (BCN of N and monitored for dynamics of carbon dioxide (CO2 flux, phospholipid fatty acids (PLFAs profile and dissolved organic carbon (DOC content. N amendment significantly increased the decomposition of biochar during the first 5 days of incubation (P < 0.05, and the proportions of decomposed biochar carbon (C were 2.30% and 3.28% in BC0 and BCN treatments, respectively, during 30 days of incubation. The magnitude of decomposed biochar C was significantly (P < 0.05 higher than DOC in biochar (1.75% and part of relatively recalcitrant biochar C was mineralized in both treatments. N amendment increased soil PLFAs concentration at the beginning of incubation, indicating that microorganisms were N-limited in test soil. Furthermore, N amendment significantly (P < 0.05 increased the proportion of gram-positive (G+ bacteria and decreased that of fungi, while no noticeable changes were observed for gram-negative (G- bacteria and actinobacteria at the early stage of incubation. Our results indicated that N amendment promoted more efficiently the proliferation of G+ bacteria and accelerated the decomposition of relatively recalcitrant biochar C, which in turn reduced the stability of maize straw-derived biochar in test soil.

  10. New strains of oil-degrading microorganisms for treating contaminated soils and wastes

    Science.gov (United States)

    Muratova, A. Yu; Panchenko, L. V.; Semina, D. V.; Golubev, S. N.; Turkovskaya, O. V.

    2018-01-01

    Two new strains Achromobacter marplatensis101n and Acinetobacter sp. S-33, capable of degrading 49 and 46% of oil within 7 days were isolated, identified, and characterized. The application of A. marplatensis 101n in combination with ammonium nitrate (100 mg·kg-1) for 30 days of cultivation resulted in the degradation of 49% of the initial total petroleum hydrocarbon content (274 g·kg-1) in the original highly acid (pH 4.9) oil-contaminated waste. Up to 30% of oil sludge added to a liquid mineral medium at a concentration of 15% was degraded after 10 days of cultivation of A. marplatensis 101n. Application of yellow alfalfa (Medicago falcata L.) plants with Acinetobacter sp. S-33 for bioremediation of oil-sludge-contaminated soil improved the quality of cleanup in comparison with the bacterium- or plant-only treatment. Inoculation of Acinetobacter sp. S-33 increased the growth of both roots and shoots by more than 40%, and positively influenced the soil microflora. We conclude that the new oil-degrading strains, Acinetobacter sp. S-33 and A. marplatensis 101n, can serve as the basis for new bioremediation agents for the treatment of oil contaminated soils and waste.

  11. Comparative study of the selective degradations of two enantiomers in the racemate and an enriched concentration of indoxacarb in soils.

    Science.gov (United States)

    Zhang, Yu-Ping; Hu, De-Yu; Ling, Hu-Rong; Zhong, Lei; Huang, An-Xiang; Zhang, Kan-Kan; Song, Bao-An

    2014-09-17

    In this study, selective degradations of the two enantiomers of indoxacarb in the concentrate (2.33S/1R) and racemate (1S/1R) are examined. The absolute configurations of indoxacarb enantiomers were determined using X-ray diffraction. The results showed that in two alkaline soils, the S-(+)-indoxacarb was preferentially degraded in both the concentrate and racemate. In one acid soil, the two enantiomers degraded no-selectivity. In another acid soil and one neutral soil, the R-(-)-indoxacarb was preferentially degraded in both the concentrate and racemate. Indoxacarb enantiomers were configurationally stable in the five soils, and no interconversion was observed during the incubation. Because no significant difference in degradation was observed after samples were sterilized, the observed enantioselectivity may be attributed primarily to microbial activity in soils. The results indicate that the selective degradation behavior was the same for both formulations that were tested.

  12. Indexing Permafrost Soil Organic Matter Degradation Using High-Resolution Mass Spectrometry.

    Science.gov (United States)

    Mann, Benjamin F; Chen, Hongmei; Herndon, Elizabeth M; Chu, Rosalie K; Tolic, Nikola; Portier, Evan F; Roy Chowdhury, Taniya; Robinson, Errol W; Callister, Stephen J; Wullschleger, Stan D; Graham, David E; Liang, Liyuan; Gu, Baohua

    2015-01-01

    Microbial degradation of soil organic matter (SOM) is a key process for terrestrial carbon cycling, although the molecular details of these transformations remain unclear. This study reports the application of ultrahigh resolution mass spectrometry to profile the molecular composition of SOM and its degradation during a simulated warming experiment. A soil sample, collected near Barrow, Alaska, USA, was subjected to a 40-day incubation under anoxic conditions and analyzed before and after the incubation to determine changes of SOM composition. A CHO index based on molecular C, H, and O data was utilized to codify SOM components according to their observed degradation potentials. Compounds with a CHO index score between -1 and 0 in a water-soluble fraction (WSF) demonstrated high degradation potential, with a highest shift of CHO index occurred in the N-containing group of compounds, while similar stoichiometries in a base-soluble fraction (BSF) did not. Additionally, compared with the classical H:C vs O:C van Krevelen diagram, CHO index allowed for direct visualization of the distribution of heteroatoms such as N in the identified SOM compounds. We demonstrate that CHO index is useful not only in characterizing arctic SOM at the molecular level but also enabling quantitative description of SOM degradation, thereby facilitating incorporation of the high resolution MS datasets to future mechanistic models of SOM degradation and prediction of greenhouse gas emissions.

  13. Novel Chryseobacterium sp. PYR2 degrades various organochlorine pesticides (OCPs) and achieves enhancing removal and complete degradation of DDT in highly contaminated soil.

    Science.gov (United States)

    Qu, Jie; Xu, Yang; Ai, Guo-Min; Liu, Ying; Liu, Zhi-Pei

    2015-09-15

    Long term residues of organochlorine pesticides (OCPs) in soils are of great concerning because they seriously threaten food security and human health. This article focuses on isolation of OCP-degrading strains and their performance in bioremediation of contaminated soil under ex situ conditions. A bacterium, Chryseobacterium sp. PYR2, capable of degrading various OCPs and utilizing them as a sole carbon and energy source for growth, was isolated from OCP-contaminated soil. In culture experiments, PYR2 degraded 80-98% of hexachlorocyclohexane (HCH) or 1,1,1-trichloro-2,2-bis (4-chlorophenyl) ethane (DDT) isomers (50 mg L(-1)) in 30 days. A pilot-scale ex situ bioremediation study of highly OCP-contaminated soil augmented with PYR2 was performed. During the 45-day experimental period, DDT concentration was reduced by 80.3% in PYR2-augmented soils (35.37 mg kg(-1) to 6.97 mg kg(-1)) but by only 57.6% in control soils. Seven DDT degradation intermediates (metabolites) were detected and identified in PYR2-augmented soils: five by GC/MS: 1,1-dichloro-2,2-bis (4-chlorophenyl) ethane (DDD), 1,1-dichloro-2,2-bis (4-chlorophenyl) ethylene (DDE), 1-chloro-2,2-bis (4-chlorophenyl) ethylene (DDMU), 1-chloro-2,2-bis (4-chlorophenyl) ethane (DDMS), and dichlorobenzophenone (DBP); and two by LC/MS: 4-chlorobenzoic acid (PCBA) and 4-chlorophenylacetic acid (PCPA). Levels of metabolites were fairly stable in control soils but varied greatly with time in PYR2-augmented soils. Levels of DDD, DDMU, and DDE in PYR2-augmented soils increased from day 0 to day 30 and then decreased by day 45. A DDT biodegradation pathway is proposed based on our identification of DDT metabolites in PYR2-augmented systems. PYR2 will be useful in future studies of OCP biodegradation and in bioremediation of OCP-contaminated soils. Copyright © 2015 Elsevier Ltd. All rights reserved.

  14. Using the VS-Fast methodology for soil degradation assessment: a case study from Senegal

    NARCIS (Netherlands)

    Sonneveld, B.G.J.S.; McGarry, D.; Ndiaye, D.

    2012-01-01

    Soil degradation threatens sustainable food production and accelerates global warming. Poorer countries, whose agricultural sectors are highly dependent on their natural resource bases, are hit particularly hard by declining soil productivity. Calls for soil-quality monitoring are therefore,

  15. PHYSICAL AND CHEMICAL DEGRADATION OF AGRICULTURAL SOILS AT SAN PEDRO LAGUNILLAS, NAYARIT

    Directory of Open Access Journals (Sweden)

    Gelacio Alejo Santiago

    2012-08-01

    Full Text Available The objective of this study was to evaluate the degradation to propose strategies for remediation and recovery of agricultural soils of San Pedro Lagunillas, Nayarit, Mexico; considering physical and chemical properties. Soils maintained with natural vegetation but slightly grazed and agricultural soils used for more than 20 years for the production of several crops, were compared. Eight sites were studied (four cultivated and four uncultivated, each agricultural lands (cultivated was located at a distance of 30 to 80 m from its counterpart or soil with natural vegetation (uncultivated. Samples were obtained from the following layers: 0 to 10, 10 to 20 and 20 to 30 cm. The variables evaluated were: particles smaller than 2 mm, pH, organic matter, extractable phosphorus, exchangeable potassium, calcium and magnesium; soil texture and water infiltration rate. An analysis of variance and Tukey means test (α = 0.05 was applied. It was concluded that traditional farming practices led to adverse changes in soil chemical properties, in the upper 20 cm soil layer. Physical properties were also affected because infiltration film and water infiltration rate decreased about 50% in cultivated soils. The overall results in this work evident the need to take appropriate measures to prevent the physical and chemical degradation of cultivated soils in order to preserve this resource and maintain their productivity.

  16. Combined use of GIS and environmental indicators for assessment of chemical, physical and biological soil degradation in a Spanish Mediterranean region.

    Science.gov (United States)

    de Paz, José-Miguel; Sánchez, Juan; Visconti, Fernando

    2006-04-01

    Soil is one of the main non-renewable natural resources in the world. In the Valencian Community (Mediterranean coast of Spain), it is especially important because agriculture and forest biomass exploitation are two of the main economic activities in the region. More than 44% of the total area is under agriculture and 52% is forested. The frequently arid or semi-arid climate with rainfall concentrated in few events, usually in the autumn and spring, scarcity of vegetation cover, and eroded and shallow soils in several areas lead to soil degradation processes. These processes, mainly water erosion and salinization, can be intense in many locations within the Valencian Community. Evaluation of soil degradation on a regional scale is important because degradation is incompatible with sustainable development. Policy makers involved in land use planning require tools to evaluate soil degradation so they can go on to develop measures aimed at protecting and conserving soils. In this study, a methodology to evaluate physical, chemical and biological soil degradation in a GIS-based approach was developed for the Valencian Community on a 1/200,000 scale. The information used in this study was obtained from two different sources: (i) a soil survey with more than 850 soil profiles sampled within the Valencian Community, and (ii) the environmental information implemented in the Geo-scientific map of the Valencian Community digitised on an Arc/Info GIS. Maps of physical, chemical and biological soil degradation in the Valencian Community on a 1/200,000 scale were obtained using the methodology devised. These maps can be used to make a cost-effective evaluation of soil degradation on a regional scale. Around 29% of the area corresponding to the Valencian Community is affected by high to very high physical soil degradation, 36% by high to very high biological degradation, and 6% by high to very high chemical degradation. It is, therefore, necessary to draw up legislation and to

  17. Degradation of phenanthrene and pyrene using genetically engineered dioxygenase producing Pseudomonas putida in soil

    Directory of Open Access Journals (Sweden)

    Mardani Gashtasb

    2016-01-01

    Full Text Available Bioremediation use to promote degradation and/or removal of contaminants into nonhazardous or less-hazardous substances from the environment using microbial metabolic ability. Pseudomonas spp. is one of saprotrophic soil bacterium and can be used for biodegradation of polycyclic aromatic hydrocarbons (PAHs but this activity in most species is weak. Phenanthrene and pyrene could associate with a risk of human cancer development in exposed individuals. The aim of the present study was application of genetically engineered P. putida that produce dioxygenase for degradation of phenanthrene and pyrene in spiked soil using high-performance liquid chromatography (HPLC method. The nahH gene that encoded catechol 2,3-dioxygenase (C23O was cloned into pUC18 and pUC18-nahH recombinant vector was generated and transformed into wild P. putida, successfully. The genetically modified and wild types of P. putida were inoculated in soil and pilot plan was prepared. Finally, degradation of phenanthrene and pyrene by this bacterium in spiked soil were evaluated using HPLC measurement technique. The results were showed elimination of these PAH compounds in spiked soil by engineered P. putida comparing to dishes containing natural soil with normal microbial flora and inoculated autoclaved soil by wild type of P. putida were statistically significant (p0.05 but it was few impact on this process (more than 2%. Additional and verification tests including catalase, oxidase and PCR on isolated bacteria from spiked soil were indicated that engineered P. putida was alive and functional as well as it can affect on phenanthrene and pyrene degradation via nahH gene producing. These findings indicated that genetically engineered P. putida generated in this work via producing C23O enzyme can useful and practical for biodegradation of phenanthrene and pyrene as well as petroleum compounds in polluted environments.

  18. Complex Adaptive Systems, soil degradation and land sensitivity to desertification: A multivariate assessment of Italian agro-forest landscape.

    Science.gov (United States)

    Salvati, Luca; Mavrakis, Anastasios; Colantoni, Andrea; Mancino, Giuseppe; Ferrara, Agostino

    2015-07-15

    Degradation of soils and sensitivity of land to desertification are intensified in last decades in the Mediterranean region producing heterogeneous spatial patterns determined by the interplay of factors such as climate, land-use changes, and human pressure. The present study hypothesizes that rising levels of soil degradation and land sensitivity to desertification are reflected into increasingly complex (and non-linear) relationships between environmental and socioeconomic variables. To verify this hypothesis, the Complex Adaptive Systems (CAS) framework was used to explore the spatiotemporal dynamics of eleven indicators derived from a standard assessment of soil degradation and land sensitivity to desertification in Italy. Indicators were made available on a detailed spatial scale (773 agricultural districts) for various years (1960, 1990, 2000 and 2010) and analyzed through a multi-dimensional exploratory data analysis. Our results indicate that the number of significant pair-wise correlations observed between indicators increased with the level of soil and land degradation, although with marked differences between northern and southern Italy. 'Fast' and 'slow' factors underlying soil and land degradation, and 'rapidly-evolving' or 'locked' agricultural districts were identified according to the rapidity of change estimated for each of the indicators studied. In southern Italy, 'rapidly-evolving' districts show a high level of soil degradation and land sensitivity to desertification during the whole period of investigation. On the contrary, those districts in northern Italy are those experiencing a moderate soil degradation and land sensitivity to desertification with the highest increase in the level of sensitivity over time. The study framework contributes to the assessment of complex local systems' dynamics in affluent but divided countries. Results may inform thematic strategies for the mitigation of land and soil degradation in the framework of action

  19. Nano chitosan-NPK fertilizer enhances the growth and productivity of wheat plants grown in sandy soil

    Energy Technology Data Exchange (ETDEWEB)

    Abdel-Aziz, H.M.M.; Hasaneen, M.N.A.; Ome, A.M.

    2016-11-01

    Nanofertilizers have become a pioneer approach in agriculture research nowadays. In this paper we investigate the delivery of chitosan nanoparticles loaded with nitrogen, phosphorus and potassium (NPK) for wheat plants by foliar uptake. Chiotsan-NPK nanoparticles were easily applied to leaf surfaces and entered the stomata via gas uptake, avoiding direct interaction with soil systems. The uptake and translocation of nanoparticles inside wheat plants was investigated by transmission electron microscopy. The results revealed that nano particles were taken up and transported through phloem tissues. Treatment of wheat plants grown on sandy soil with nano chitosan-NPK fertilizer induced significant increases in harvest index, crop index and mobilization index of the determined wheat yield variables, as compared with control yield variables of wheat plants treated with normal non-fertilized and normal fertilized NPK. The life cycle of the nano-fertilized wheat plants was shorter than normal-fertilized wheat plants with the ratio of 23.5% (130 days compared with 170 days for yield production from date of sowing). Thus, accelerating plant growth and productivity by application of nanofertilizers can open new perspectives in agricultural practice. However, the response of plants to nanofertilizers varies with the type of plant species, their growth stages and nature of nanomaterials. (Author)

  20. Delignification and Enhanced Gas Release from Soil Containing Lignocellulose by Treatment with Bacterial Lignin Degraders.

    Science.gov (United States)

    Rashid, Goran M M; Duran-Pena, Maria Jesus; Rahmanpour, Rahman; Sapsford, Devin; Bugg, Timothy D H

    2017-04-10

    The aim of the study was to isolate bacterial lignin-degrading bacteria from municipal solid waste soil, and to investigate whether they could be used to delignify lignocellulose-containing soil, and enhance methane release. A set of 20 bacterial lignin degraders, including 11 new isolates from municipal solid waste soil, were tested for delignification and phenol release in soil containing 1% pine lignocellulose. A group of 7 strains were then tested for enhancement of gas release from soil containing 1% lignocellulose in small-scale column tests. Using an aerobic pre-treatment, aerobic strains such as Pseudomonas putida showed enhanced gas release from the treated sample, but four bacterial isolates showed 5-10 fold enhancement in gas release in an in situ experiment under microanaerobic conditions: Agrobacterium sp., Lysinibacillus sphaericus, Comamonas testosteroni, and Enterobacter sp.. The results show that facultative anaerobic bacterial lignin degraders found in landfill soil can be used for in situ delignification and enhanced gas release in soil containing lignocellulose. The study demonstrates the feasibility of using an in situ bacterial treatment to enhance gas release and resource recovery from landfill soil containing lignocellulosic waste. This article is protected by copyright. All rights reserved. This article is protected by copyright. All rights reserved.

  1. Degradation of soil fertility can cancel pollination benefits in sunflower.

    Science.gov (United States)

    Tamburini, Giovanni; Berti, Antonio; Morari, Francesco; Marini, Lorenzo

    2016-02-01

    Pollination and soil fertility are important ecosystem services to agriculture but their relative roles and potential interactions are poorly understood. We explored the combined effects of pollination and soil fertility in sunflower using soils from a trial characterized by different long-term input management in order to recreate plausible levels of soil fertility. Pollinator exclusion was used as a proxy for a highly eroded pollination service. Pollination benefits to yield depended on soil fertility, i.e., insect pollination enhanced seed set and yield only under higher soil fertility indicating that limited nutrient availability may constrain pollination benefits. Our study provides evidence for interactions between above- and belowground ecosystem services, highlighting the crucial role of soil fertility in supporting agricultural production not only directly, but also indirectly through pollination. Management strategies aimed at enhancing pollination services might fail in increasing yield in landscapes characterized by high soil service degradation. Comprehensive knowledge about service interactions is therefore essential for the correct management of ecosystem services in agricultural landscapes.

  2. Effects of spent mushroom compost application on the physicochemical properties of a degraded soil

    Directory of Open Access Journals (Sweden)

    İ. Gümüş

    2017-11-01

    Full Text Available Under field and laboratory conditions, the application of organic amendments has generally shown an improvement in soil physicochemical properties. Here, spent mushroom compost (SMC is proposed as a suitable organic amendment for soil structure restoration. Our study assessed the impact of SMC on the physicochemical properties of a weak-structured and physically degraded soil. The approach involved the establishment of a pot experiment with SMC applications into soil (control, 0.5, 1, 2, 4 and 8 %. Soils were incubated at field capacity (−33 kPa for 21, 42, and 62 days under laboratory conditions. SMC applications into the soil significantly increased the aggregate stability (AS and decreased the modulus of rupture. The application of SMC at rates of 1, 2, 4, and 8 % significantly increased the total nitrogen and soil organic carbon contents of the degraded soil at all incubation periods (p < 0.05. The results obtained in this study indicate that the application of SMC can improve soil physicochemical properties, which may benefit farmers, land managers, and mushroom growers.

  3. Effects of spent mushroom compost application on the physicochemical properties of a degraded soil

    Science.gov (United States)

    Gümüş, İlknur; Şeker, Cevdet

    2017-11-01

    Under field and laboratory conditions, the application of organic amendments has generally shown an improvement in soil physicochemical properties. Here, spent mushroom compost (SMC) is proposed as a suitable organic amendment for soil structure restoration. Our study assessed the impact of SMC on the physicochemical properties of a weak-structured and physically degraded soil. The approach involved the establishment of a pot experiment with SMC applications into soil (control, 0.5, 1, 2, 4 and 8 %). Soils were incubated at field capacity (-33 kPa) for 21, 42, and 62 days under laboratory conditions. SMC applications into the soil significantly increased the aggregate stability (AS) and decreased the modulus of rupture. The application of SMC at rates of 1, 2, 4, and 8 % significantly increased the total nitrogen and soil organic carbon contents of the degraded soil at all incubation periods (p < 0.05). The results obtained in this study indicate that the application of SMC can improve soil physicochemical properties, which may benefit farmers, land managers, and mushroom growers.

  4. Long-term influence of tillage and fertilization on net carbon dioxide exchange rate on two soils with different textures.

    Science.gov (United States)

    Feiziene, Dalia; Feiza, Virginijus; Slepetiene, Alvyra; Liaudanskiene, Inga; Kadziene, Grazina; Deveikyte, Irena; Vaideliene, Asta

    2011-01-01

    The importance of agricultural practices to greenhouse gas mitigation is examined worldwide. However, there is no consensus on soil organic carbon (SOC) content and CO emissions as affected by soil management practices and their relationships with soil texture. No-till (NT) agriculture often results in soil C gain, though, not always. Soil net CO exchange rate (NCER) and environmental factors (SOC, soil temperature [T], and water content [W]), as affected by soil type (loam and sandy loam), tillage (conventional, reduced, and NT), and fertilization, were quantified in long-term field experiments in Lithuania. Soil tillage and fertilization affected total CO flux (heterotrophic and autotrophic) through effect on soil SOC sequestration, water, and temperature regime. After 11 yr of different tillage and fertilization management, SOC content was 23% more in loam than in sandy loam. Long-term NT contributed to 7 to 27% more SOC sequestration on loam and to 29 to 33% more on sandy loam compared with reduced tillage (RT) or conventional tillage (CT). Soil water content in loam was 7% more than in sandy loam. Soil gravimetric water content, averaged across measurement dates and fertilization treatments, was significantly less in NT than CT and RT in both soils. Soil organic carbon content and water storage capacity of the loam and sandy loam soils exerted different influences on NCER. The NCER from the sandy loam soil was 13% greater than that from the loam. In addition, NCER was 4 to 9% less with NT than with CT and RT systems on both loam and sandy loam soils. Application of mineral NPK fertilizers promoted significantly greater NCER from loam but suppressed NCER by 15% from sandy loam. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

  5. From oil spills to barley growth - oil-degrading soil bacteria and their promoting effects.

    Science.gov (United States)

    Mikolasch, Annett; Reinhard, Anne; Alimbetova, Anna; Omirbekova, Anel; Pasler, Lisa; Schumann, Peter; Kabisch, Johannes; Mukasheva, Togzhan; Schauer, Frieder

    2016-11-01

    Heavy contamination of soils by crude oil is omnipresent in areas of oil recovery and exploitation. Bioremediation by indigenous plants in cooperation with hydrocarbon degrading microorganisms is an economically and ecologically feasible means to reclaim contaminated soils. To study the effects of indigenous soil bacteria capable of utilizing oil hydrocarbons on biomass production of plants growing in oil-contaminated soils eight bacterial strains were isolated from contaminated soils in Kazakhstan and characterized for their abilities to degrade oil components. Four of them, identified as species of Gordonia and Rhodococcus turned out to be effective degraders. They produced a variety of organic acids from oil components, of which 59 were identified and 7 of them are hitherto unknown acidic oil metabolites. One of them, Rhodococcus erythropolis SBUG 2054, utilized more than 140 oil components. Inoculating barley seeds together with different combinations of these bacterial strains restored normal growth of the plants on contaminated soils, demonstrating the power of this approach for bioremediation. Furthermore, we suggest that the plant promoting effect of these bacteria is not only due to the elimination of toxic oil hydrocarbons but possibly also to the accumulation of a variety of organic acids which modulate the barley's rhizosphere environment. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  6. Effect of cement injection on sandy soil slope stability, case study: slope in Petang district, Badung regency

    Science.gov (United States)

    Arya, I. W.; Wiraga, I. W.; GAG Suryanegara, I.

    2018-01-01

    with cement injection interval 5 cm and third model is soil with cement injection interval 10 cm. The result is the shear strength (ϕ value) the soil is increase from 32.02° to 47.57°. The increase value of internal friction angle (ϕ) shows that an increase in shear strength of the cement improved soil. While, the value of cohesion (c) is zero indicating there is no cohesion in the soil. This is common for sand soil or sandy soil. The calculation of safety factor with GeoStructural Analysis obtained an increase of safety factor from 0.78 if the soil without cement injection to 1.07 and 1.17 if the soil is injected with cement at a distance of 10 cm and 5 cm.

  7. Restoration of Soil Physical and Chemical Properties of Abandoned Tin- Mining in Bangka Belitung Islands

    Directory of Open Access Journals (Sweden)

    Ishak Yuarsah

    2017-01-01

    Full Text Available The practices of tin mining that remove all soil layers on top of the mineral deposit layers have caused serious environmental problems, i.e. degradation of soil physical and chemical properties and disappearance of vegetation, flora and fauna in ecosystems, which further can change the local microclimate. The tailing area of tin mining have unstable soil structure and low organic matter content, so it is vulnerable to land slides and erosion. The characteristics of the soils in the tailing area that are very acidic, low nutrient availability, low water holding capacity and high soil temperature challange the restoration and improvement processes of this area. The aim of the research was to develop appropriate restoration techniques to improve the soil properties of post tin mining land that have been degraded due to mining activities. Appropriate plant species and specific location technology were determined based on the characterization and evaluation of potential land resources. Annual crop cultivation, cultivation of legume cover crops (Mucuna sp., Calopogonium sp., Pueraria javanica and management of top soil and organic matter should be applied in order to improve soil structure, maintain soil moisture, as well as to reduce nutrient loss in coarse sandy soils.

  8. Degradation of 14C-lindane in soils of planting ginseng

    International Nuclear Information System (INIS)

    Wang Zhengguo; Zhao Jing; Yao Jianren

    1992-01-01

    14 C-Lindane was used to study degradation of Lindane (γ-BHC) in different types of soil of planting ginseng. Results indicated that Lindane was very slowly mineralized after a 228 day's incubation period in closed system. It took about 9 years to completely mineralize Lindane in the chernozem, and 11 years in the brown calcareous at 20 ppm in the soils. In addition, the rate of Lindane mineralized depended on population and number of microorganism. In this test the fungi played more important role than the bacteria in the Lindane mineralization. 14 C-Lindane residues extracted from the soils were 77.43%-80.54%, and Lindane residues associated with the soils were 13.11%-20.77%

  9. In-Field Spatial Variability in the Degradation of the Phenyl-Urea Herbicide Isoproturon Is the Result of Interactions between Degradative Sphingomonas spp. and Soil pH

    Science.gov (United States)

    Bending, Gary D.; Lincoln, Suzanne D.; Sørensen, Sebastian R.; Morgan, J. Alun W.; Aamand, Jens; Walker, Allan

    2003-01-01

    Substantial spatial variability in the degradation rate of the phenyl-urea herbicide isoproturon (IPU) [3-(4-isopropylphenyl)-1,1-dimethylurea] has been shown to occur within agricultural fields, with implications for the longevity of the compound in the soil, and its movement to ground- and surface water. The microbial mechanisms underlying such spatial variability in degradation rate were investigated at Deep Slade field in Warwickshire, United Kingdom. Most-probable-number analysis showed that rapid degradation of IPU was associated with proliferation of IPU-degrading organisms. Slow degradation of IPU was linked to either a delay in the proliferation of IPU-degrading organisms or apparent cometabolic degradation. Using enrichment techniques, an IPU-degrading bacterial culture (designated strain F35) was isolated from fast-degrading soil, and partial 16S rRNA sequencing placed it within the Sphingomonas group. Denaturing gradient gel electrophoresis (DGGE) of PCR-amplified bacterial community 16S rRNA revealed two bands that increased in intensity in soil during growth-linked metabolism of IPU, and sequencing of the excised bands showed high sequence homology to the Sphingomonas group. However, while F35 was not closely related to either DGGE band, one of the DGGE bands showed 100% partial 16S rRNA sequence homology to an IPU-degrading Sphingomonas sp. (strain SRS2) isolated from Deep Slade field in an earlier study. Experiments with strains SRS2 and F35 in soil and liquid culture showed that the isolates had a narrow pH optimum (7 to 7.5) for metabolism of IPU. The pH requirements of IPU-degrading strains of Sphingomonas spp. could largely account for the spatial variation of IPU degradation rates across the field. PMID:12571001

  10. Construction and applications of DNA probes for detection of polychlorinated biphenyl-degrading genotypes in toxic organic-contaminated soil environments

    International Nuclear Information System (INIS)

    Walia, S.; Khan, A.; Rosenthal, N.

    1990-01-01

    Several DNA probes for polychlorinated biphenyl (PCB)-degrading genotypes were constructed from PCB-degrading bacteria. These laboratory-engineered DNA probes were used for the detection, enumeration, and isolation of specific bacteria degrading PCBs. Dot blot analysis of purified DNA from toxic organic chemical-contaminated soil bacterial communities showed positive DNA-DNA hybridization with a 32P-labeled DNA probe (pAW6194, cbpABCD). Less than 1% of bacterial colonies isolated from garden topsoil and greater than 80% of bacteria isolated from PCB-contaminated soils showed DNA homologies with 32P-labeled DNA probes. Some of the PCB-degrading bacterial isolates detected by the DNA probe method did not show biphenyl clearance. The DNA probe method was found to detect additional organisms with greater genetic potential to degrade PCBs than the biphenyl clearance method did. Results from this study demonstrate the usefulness of DNA probes in detecting specific PCB-degrading bacteria, abundance of PCB-degrading genotypes, and genotypic diversity among PCB-degrading bacteria in toxic chemical-polluted soil environments. We suggest that the DNA probe should be used with caution for accurate assessment of PCB-degradative capacity within soils and further recommend that a combination of DNA probe and biodegradation assay be used to determine the abundance of PCB-degrading bacteria in the soil bacterial community

  11. Adsorption-desorption, mobility and degradation of 14C-Glyphosate in two soil series

    International Nuclear Information System (INIS)

    Ismail, B. S.; Zaifah Abdul Kadir; Khairiah Jusoh; Nashriyah Mat

    2002-01-01

    The adsorption desorption and degradation of glyphosate (Roundup) have been studied using 14 C glyphosate in two soils, namely Serdang Series and Sungai Buloh Series. The percentage of adsorption was not significantly different (p 14 C- glyphosate was detected in 0-10 cm zone of the two soils studied. However, in Sungai Buloh Series, a significant amount of 14 C-glyphosate was detected in the 10-20 cm zone. A small amount of 14 C radioactivity was also detected in the leachate of the two soils. The percentage of degradation in the Sungai Buloh and Serdang Series soils was higher at 10 μg/ml and 50 μg/ml, concentration, respectively. At 50 μg/ml concentration the Sungai Buloh Series soil showed higher glyphosate residue (83%) as compared to Serdang Series (48%). In contrast, the glyphosate residue was found to be higher in the Serdang Series (73916) as compared to the Sungai Buloh Series (30%) at 10 μg/ml concentration. (Author)

  12. Impact of electrochemical treatment of soil washing solution on PAH degradation efficiency and soil respirometry.

    Science.gov (United States)

    Mousset, Emmanuel; Huguenot, David; van Hullebusch, Eric D; Oturan, Nihal; Guibaud, Gilles; Esposito, Giovanni; Oturan, Mehmet A

    2016-04-01

    The remediation of a genuinely PAH-contaminated soil was performed, for the first time, through a new and complete investigation, including PAH extraction followed by advanced oxidation treatment of the washing solution and its recirculation, and an analysis of the impact of the PAH extraction on soil respirometry. The study has been performed on the remediation of genuine PAH-contaminated soil, in the following three steps: (i) PAH extraction with soil washing (SW) techniques, (ii) PAH degradation with an electro-Fenton (EF) process, and (iii) recirculation of the partially oxidized effluent for another SW cycle. The following criteria were monitored during the successive washing cycles: PAH extraction efficiency, PAH oxidation rates and yields, extracting agent recovery, soil microbial activity, and pH of soil. Two representative extracting agents were compared: hydroxypropyl-beta-cyclodextrin (HPCD) and a non-ionic surfactant, Tween(®) 80. Six PAH with different numbers of rings were monitored: acenaphthene (ACE), phenanthrene (PHE), fluoranthene (FLA), pyrene (PYR), benzo(a)pyrene (BaP), and benzo(g,h,i)perylene (BghiP). Tween(®) 80 showed much better PAH extraction efficiency (after several SW cycles) than HPCD, regardless of the number of washing cycles. Based on successive SW experiments, a new mathematical relation taking into account the soil/water partition coefficient (Kd*) was established, and could predict the amount of each PAH extracted by the surfactant with a good correlation with experimental results (R(2) > 0.975). More HPCD was recovered (89%) than Tween(®) 80 (79%), while the monitored pollutants were completely degraded (>99%) after 4 h and 8 h, respectively. Even after being washed with partially oxidized solutions, the Tween(®) 80 solutions extracted significantly more PAH than HPCD and promoted better soil microbial activity, with higher oxygen consumption rates. Moreover, neither the oxidation by-products nor the acidic media (p

  13. Impact of repeated two-phase olive mill waste application on phosphorus fractionation in a degraded olive grove soil

    International Nuclear Information System (INIS)

    Lopez-Pineiro, A.; Albarran, A.; Flores, S.; Rato, J. M.; Munoz, A.; Cabrera, D.; Pena, D.; Fernandez, S.

    2009-01-01

    Loss of organic matter is one of the main forms of soil degradation in Mediterranean agricultural soils, and external sources of organic matter are required to improve soil properties. the two-phase centrifugation system in the olive-oil extraction industry produces a large amount of olive mill waste sludge (TPOMW) which can be used to add organic C to degraded soils. (Author)

  14. Metagenomic Functional Potential Predicts Degradation Rates of a Model Organophosphorus Xenobiotic in Pesticide Contaminated Soils

    Directory of Open Access Journals (Sweden)

    Thomas C. Jeffries

    2018-02-01

    Full Text Available Chemical contamination of natural and agricultural habitats is an increasing global problem and a major threat to sustainability and human health. Organophosphorus (OP compounds are one major class of contaminant and can undergo microbial degradation, however, no studies have applied system-wide ecogenomic tools to investigate OP degradation or use metagenomics to understand the underlying mechanisms of biodegradation in situ and predict degradation potential. Thus, there is a lack of knowledge regarding the functional genes and genomic potential underpinning degradation and community responses to contamination. Here we address this knowledge gap by performing shotgun sequencing of community DNA from agricultural soils with a history of pesticide usage and profiling shifts in functional genes and microbial taxa abundance. Our results showed two distinct groups of soils defined by differing functional and taxonomic profiles. Degradation assays suggested that these groups corresponded to the organophosphorus degradation potential of soils, with the fastest degrading community being defined by increases in transport and nutrient cycling pathways and enzymes potentially involved in phosphorus metabolism. This was against a backdrop of taxonomic community shifts potentially related to contamination adaptation and reflecting the legacy of exposure. Overall our results highlight the value of using holistic system-wide metagenomic approaches as a tool to predict microbial degradation in the context of the ecology of contaminated habitats.

  15. Three-year study of fast-growing trees in degraded soils amended with composts: Effects on soil fertility and productivity.

    Science.gov (United States)

    Madejón, Paula; Alaejos, Joaquin; García-Álbala, José; Fernández, Manuel; Madejón, Engracia

    2016-03-15

    Currently, worries about the effects of intensive plantations on long-term nutrient supply and a loss of productivity have risen. In this study two composts were added to degraded soils where this type of intensive crops were growing, to avoid the soil fertility decrease and try to increase biomass production. For the experiment, two degraded soils in terms of low organic carbon content and low pH were selected in South-West Spain: La Rábida (RA) and Villablanca (VI) sites. Both study sites were divided into 24 plots. In RA, half of the plots were planted with Populus x canadensis "I-214"; the other half was planted with Eucalyptus globulus. At the VI site, half of the plots were planted with Paulownia fortunei, and the other plots were planted with Eucalyptus globulus. For each tree and site, three treatments were established (two organic composts and a control without compost), with four replications per treatment. The organic amendments were "alperujo" compost, AC, a solid by-product from the extraction of olive oil, and BC, biosolid compost. During the three years of experimentation, samples of soils and plants were analyzed for studying chemical and biochemical properties of soil, plant growth and plant nutritional status and biomass production. The composts increased total organic carbon, water-soluble carbon, nutrients and pH of soil only in the most acidic soil. Soil biochemical quality was calculated with the geometric mean of the enzymatic activities (Dehydrogenase, β-glucosidase, Phosphatase and Urease activities) determined in soils. The results showed a beneficial improvement in comparison with soils without compost. However, the best results were found in the growth and biomass production of the studied trees, especially in Eucalyptus. Nutritional levels of leaves of the trees were, in general, in the normal established range for each species, although no clear effect of the composts was observed. The results of this study justify the addition of

  16. Plasticity and density-moisture-resistance relations of soils amended with fly ash

    Energy Technology Data Exchange (ETDEWEB)

    Mapfuno, E.; Chanasyk, D.S. [University of Alberta, Edmonton, AB (Canada). Dept. of Renewable Resources

    1998-06-01

    The objective of this study was to investigate the impact of fly ash amendments on the plasticity, water retention and penetration resistance-density-moisture relationships of three soils of sandy loam, loam and clay loam textures in order to determine the potential compaction of these soil/fly ash mixtures if they were worked at different moisture ranges. For all three soils the addition of fly ash decreased the plasticity index, but slightly increased the Proctor maximum density. This implies that fly ash amendments reduce the range of moisture within which soils are most susceptible to compaction. However, for the sandy loam and loam textured soils amended with fly ash, cultivation must be avoided at moisture contents close to field capacity since maximum densification occurs at these moisture contents. In all three soils the addition of fly ash increased water retention, especially in the sandy loam. Fly ash amendments increased penetration resistance of the clay loam, but increased penetration resistance of the sandy loam.

  17. Sediment Chemistry and Toxicity in Barnegat Bay, New Jersey: Pre- and Post- Hurricane Sandy, 2012-2013.

    Science.gov (United States)

    Romanok, Kristin M.; Szabo, Zoltan; Reilly, Timothy J.; Defne, Zafer; Ganju, Neil K.

    2016-01-01

    Hurricane Sandy made landfall in Barnegat Bay, October, 29, 2012, damaging shorelines and infrastructure. Estuarine sediment chemistry and toxicity were investigated before and after to evaluate potential environmental health impacts and to establish post-event baseline sediment-quality conditions. Trace element concentrations increased throughout Barnegat Bay up to two orders of magnitude, especially north of Barnegat Inlet, consistent with northward redistribution of silt. Loss of organic compounds, clay, and organic carbon is consistent with sediment winnowing and transport through the inlets and sediment transport modeling results. The number of sites exceeding sediment quality guidance levels for trace elements tripled post-Sandy. Sediment toxicity post-Sandy was mostly unaffected relative to pre-Sandy conditions, but at the site with the greatest relative increase for trace elements, survival rate of the test amphipod decreased (indicating degradation). This study would not have been possible without comprehensive baseline data enabling the evaluation of storm-derived changes in sediment quality.

  18. Bioremediation of PAH-contamined soils: Consequences on formation and degradation of polar-polycyclic aromatic compounds and microbial community abundance.

    Science.gov (United States)

    Biache, Coralie; Ouali, Salma; Cébron, Aurélie; Lorgeoux, Catherine; Colombano, Stéfan; Faure, Pierre

    2017-05-05

    A bioslurry batch experiment was carried out over five months on three polycyclic aromatic compound (PAC) contaminated soils to study the PAC (PAH and polar-PAC) behavior during soil incubation and to evaluate the impact of PAC contamination on the abundance of microbial communities and functional PAH-degrading populations. Organic matter characteristics and reactivity, assessed through solvent extractable organic matter and PAC contents, and soil organic matter mineralization were monitored during 5 months. Total bacteria and fungi, and PAH-ring hydroxylating dioxygenase genes were quantified. Results showed that PAHs and polar-PACs were degraded with different degradation dynamics. Differences in degradation rates were observed among the three soils depending on PAH distribution and availability. Overall, low molecular weight compounds were preferentially degraded. Degradation selectivity between isomers and structurally similar compounds was observed which could be used to check the efficiency of bioremediation processes. Bacterial communities were dominant over fungi and were most likely responsible for PAC degradation. Abundance of PAH-degrading bacteria increased during incubations, but their proportion in the bacterial communities tended to decrease. The accumulation of some oxygenated-PACs during the bioslurry experiment underlines the necessity to monitor these compounds during application of remediation treatment on PAH contaminated soils. Copyright © 2017 Elsevier B.V. All rights reserved.

  19. The impact of biosolids application on organic carbon and carbon dioxide fluxes in soil.

    Science.gov (United States)

    Wijesekara, Hasintha; Bolan, Nanthi S; Thangavel, Ramesh; Seshadri, Balaji; Surapaneni, Aravind; Saint, Christopher; Hetherington, Chris; Matthews, Peter; Vithanage, Meththika

    2017-12-01

    A field study was conducted on two texturally different soils to determine the influences of biosolids application on selected soil chemical properties and carbon dioxide fluxes. Two sites, located in Manildra (clay loam) and Grenfell (sandy loam), in Australia, were treated at a single level of 70 Mg ha -1 biosolids. Soil samples were analyzed for SOC fractions, including total organic carbon (TOC), labile, and non-labile carbon contents. The natural abundances of soil δ 13 C and δ 15 N were measured as isotopic tracers to fingerprint carbon derived from biosolids. An automated soil respirometer was used to measure in-situ diurnal CO 2 fluxes, soil moisture, and temperature. Application of biosolids increased the surface (0-15 cm) soil TOC by > 45% at both sites, which was attributed to the direct contribution from residual carbon in the biosolids and also from the increased biomass production. At both sites application of biosolids increased the non-labile carbon fraction that is stable against microbial decomposition, which indicated the soil carbon sequestration potential of biosolids. Soils amended with biosolids showed depleted δ 13 C, and enriched δ 15 N indicating the accumulation of biosolids residual carbon in soils. The in-situ respirometer data demonstrated enhanced CO 2 fluxes at the sites treated with biosolids, indicating limited carbon sequestration potential. However, addition of biosolids on both the clay loam and sandy loam soils found to be effective in building SOC than reducing it. Soil temperature and CO 2 fluxes, indicating that temperature was more important for microbial degradation of carbon in biosolids than soil moisture. Copyright © 2017 Elsevier Ltd. All rights reserved.

  20. Fate of sulfur mustard on soil: Evaporation, degradation, and vapor emission.

    Science.gov (United States)

    Jung, Hyunsook; Kah, Dongha; Chan Lim, Kyoung; Lee, Jin Young

    2017-01-01

    After application of sulfur mustard to the soil surface, its possible fate via evaporation, degradation following absorption, and vapor emission after decontamination was studied. We used a laboratory-sized wind tunnel, thermal desorber, gas chromatograph-mass spectrometry (GC-MS), and 13 C nuclear magnetic resonance ( 13 C NMR) for systematic analysis. When a drop of neat HD was deposited on the soil surface, it evaporated slowly while being absorbed immediately into the matrix. The initial evaporation or drying rates of the HD drop were found to be power-dependent on temperature and initial drop volume. Moreover, drops of neat HD, ranging in size from 1 to 6 μL, applied to soil, evaporated at different rates, with the smaller drops evaporating relatively quicker. HD absorbed into soil remained for a month, degrading eventually to nontoxic thiodiglycol via hydrolysis through the formation of sulfonium ions. Finally, a vapor emission test was performed for HD contaminant after a decontamination process, the results of which suggest potential risk from the release of trace chemical quantities of HD into the environment. Copyright © 2016 Elsevier Ltd. All rights reserved.

  1. Study on kinetic degradation in soil and horizontal transfer of bt gene by 35S isotopic tracing method

    International Nuclear Information System (INIS)

    Wang Haiyan; Zhang Yanfei; Ye Qingfu

    2012-01-01

    In this study, 35 S isotopic tracing method was applied to investigate kinetic degradation of bt gene from Bt transgenic rice TT51 in two different soil and possibility of its horizontal transfer into soil bacteria as well. Results showed that, during 30 d of aerobic incubation, it was indicated that 35 S-Bt gene was not horizontally transferred into soil microorganisms. The aerobic soil degradation dynamics significantly followed a first-order dissipation pattern for bt gene. After 30 d of incubation, the amount of bt gene reached 9.32% of applied radioactivity for the fluvio-marine yellow loamy soil and 9.92% for the fluvio-aquatic soil, respectively. The half-lives in two soils were 3.53 d for the former soil and 5. 77 d for the latter soil, which means that bt gene was more easily degradable in the weak acidic soil. The use of 35 S labeling proved to be valuable; it served the purpose of validating the rigorousness of experimental protocols, and provided insights into the soil environmental safety assessment for Bt transgenic rice. (authors)

  2. Clay minerals and metal oxides strongly influence the structure of alkane-degrading microbial communities during soil maturation.

    Science.gov (United States)

    Steinbach, Annelie; Schulz, Stefanie; Giebler, Julia; Schulz, Stephan; Pronk, Geertje J; Kögel-Knabner, Ingrid; Harms, Hauke; Wick, Lukas Y; Schloter, Michael

    2015-07-01

    Clay minerals, charcoal and metal oxides are essential parts of the soil matrix and strongly influence the formation of biogeochemical interfaces in soil. We investigated the role of these parental materials for the development of functional microbial guilds using the example of alkane-degrading bacteria harbouring the alkane monooxygenase gene (alkB) in artificial mixtures composed of different minerals and charcoal, sterile manure and a microbial inoculum extracted from an agricultural soil. We followed changes in abundance and community structure of alkane-degrading microbial communities after 3 and 12 months of soil maturation and in response to a subsequent 2-week plant litter addition. During maturation we observed an overall increasing divergence in community composition. The impact of metal oxides on alkane-degrading community structure increased during soil maturation, whereas the charcoal impact decreased from 3 to 12 months. Among the clay minerals illite influenced the community structure of alkB-harbouring bacteria significantly, but not montmorillonite. The litter application induced strong community shifts in soils, maturated for 12 months, towards functional guilds typical for younger maturation stages pointing to a resilience of the alkane-degradation function potentially fostered by an extant 'seed bank'.

  3. Stability Behavior and Thermodynamic States of Iron and Manganese in Sandy Soil Aquifer, Manukan Island, Malaysia

    International Nuclear Information System (INIS)

    Lin, Chin Yik; Abdullah, Mohd. Harun; Musta, Baba; Praveena, Sarva Mangala; Aris, Ahmad Zaharin

    2011-01-01

    A total of 20 soil samples were collected from 10 boreholes constructed in the low lying area, which included ancillary samples taken from the high elevation area. Redox processes were investigated in the soil as well as groundwater in the shallow groundwater aquifer of Manukan Island, Sabah, Malaysia. Groundwater samples (n = 10) from each boreholes were also collected in the low lying area to understand the concentrations and behaviors of Fe and Mn in the dissolved state. This study strives to obtain a general understanding of the stability behaviors on Fe and Mn at the upper unsaturated and the lower-saturated soil horizons in the low lying area of Manukan Island as these elements usually play a major role in the redox chemistry of the shallow groundwater. Thermodynamic calculations using PHREEQC showed that the groundwater samples in the study area are oversaturated with respect to goethite, hematite, Fe(OH) 3 and undersaturated with respect to manganite and pyrochroite. Low concentrations of Fe and Mn in the groundwater might be probably due to the lack of minerals of iron and manganese oxides, which exist in the sandy aquifer. In fact, high organic matters that present in the unsaturated horizon are believed to be responsible for the high Mn content in the soil. It was observed that the soil samples collected from high elevation area (BK) comprises considerable amount of Fe in both unsaturated (6675.87 mg/kg) and saturated horizons (31440.49 mg/kg) compared to the low Fe content in the low lying area. Based on the stability diagram, the groundwater composition lies within the stability field for Mn 2+ and Fe 2+ under suboxic condition and very close to the FeS/Fe 2+ stability boundary. This study also shows that both pH and Eh values comprise a strong negative value thus suggesting that the redox potential is inversely dependent on the changes of pH.

  4. Patterns of Arbuscular Mycorrhizal Fungal Distribution on Mainland and Island Sandy Coastal Plain Ecosystems in Brazil.

    Science.gov (United States)

    da Silva, Iolanda Ramalho; de Souza, Francisco Adriano; da Silva, Danielle Karla Alves; Oehl, Fritz; Maia, Leonor Costa

    2017-10-01

    Although sandy coastal plains are important buffer zones to protect the coast line and maintain biological diversity and ecosystem services, these ecosystems have been endangered by anthropogenic activities. Thus, information on coastal biodiversity and forces shaping coastal biological diversity are extremely important for effective conservation strategies. In this study, we aimed to compare arbuscular mycorrhizal (AM) fungal communities from soil samples collected on the mainland and nearby islands located in Brazilian sandy coastal plain ecosystems (Restingas) to get information about AM fungal biogeography and identify factors shaping these communities. Soil samples were collected in 2013 and 2014 on the beachfront of the tropical sandy coastal plain at six sites (three island and three mainland locations) across the northeast, southeast, and south regions of Brazil. Overall, we recorded 53 AM fungal species from field and trap culture samples. The richness and diversity of AM fungal species did not differ between mainland and island locations, but AM fungal community assemblages were different between mainland and island environments and among most sites sampled. Glomeromycota communities registered from island samples showed higher heterogeneity than communities from mainland samples. Sandy coastal plains harbor diverse AM fungal communities structured by climatic, edaphic, and spatial factors, while the distance from the colonizing source (mainland environments) does not strongly affect the AM fungal communities in Brazilian coastal environments.

  5. Predictable bacterial composition and hydrocarbon degradation in Arctic soils following diesel and nutrient disturbance.

    Science.gov (United States)

    Bell, Terrence H; Yergeau, Etienne; Maynard, Christine; Juck, David; Whyte, Lyle G; Greer, Charles W

    2013-06-01

    Increased exploration and exploitation of resources in the Arctic is leading to a higher risk of petroleum contamination. A number of Arctic microorganisms can use petroleum for growth-supporting carbon and energy, but traditional approaches for stimulating these microorganisms (for example, nutrient addition) have varied in effectiveness between sites. Consistent environmental controls on microbial community response to disturbance from petroleum contaminants and nutrient amendments across Arctic soils have not been identified, nor is it known whether specific taxa are universally associated with efficient bioremediation. In this study, we contaminated 18 Arctic soils with diesel and treated subsamples of each with monoammonium phosphate (MAP), which has successfully stimulated degradation in some contaminated Arctic soils. Bacterial community composition of uncontaminated, diesel-contaminated and diesel+MAP soils was assessed through multiplexed 16S (ribosomal RNA) rRNA gene sequencing on an Ion Torrent Personal Genome Machine, while hydrocarbon degradation was measured by gas chromatography analysis. Diversity of 16S rRNA gene sequences was reduced by diesel, and more so by the combination of diesel and MAP. Actinobacteria dominated uncontaminated soils with diesel degradation in MAP-treated soils, suggesting this may be an important group to stimulate. The predictability with which bacterial communities respond to these disturbances suggests that costly and time-consuming contaminated site assessments may not be necessary in the future.

  6. Addition of residues and reintroduction of microorganisms in Jatropha curcas cultivated in degraded soil

    Directory of Open Access Journals (Sweden)

    Adriana A. Santos

    2016-04-01

    Full Text Available ABSTRACT The aim of this study was to evaluate, through mycorrhization (root colonization and number of spores of arbuscular mycorrhizal fungi - AMF, leaf acid phosphatase and soil chemical characteristics, the effects of the addition of residues (macrophytes and ash, hydrogel and the reintroduction of microorganisms in a degraded area cultivated with jatropha. Degradation occurred when the surface soil was removed during the construction of a hydroelectric power plant. The experiment was set in a randomized block design, using a 2 x 2 x 4 factorial scheme, i.e., two inoculation treatments (with and without soil-inoculum, two hydrogel treatments (with and without and four with the addition of residues (macrophytes - MAC, ash, MAC + ash and control, without residues applied in the planting hole, with 4 replicates and 5 plants in each replicate. Soil from preserved Cerrado area was used as a source of microorganisms, including AMF. The conclusion is that, after 12 months of planting, the hydrogel increased root colonization, while the chemical characteristics of the degraded soil responded positively to the addition of MAC and MAC + ash, with increase in pH and SB and reduction of Al and H + Al. The addition of the soil-inoculum, along with MAC and MAC + ash, promoted higher mycorrhizal colonization and number of spores and reduced amounts of leaf acid phosphatase, indicating increased absorption of P by the host.

  7. Comparison of an ability to degrade MTBE between mixed culture and monoculture isolated from gasoline contaminated soil

    Directory of Open Access Journals (Sweden)

    Wanpen Virojanakud

    2004-02-01

    Full Text Available Methyl tertiary butyl ether (MTBE is an oxygenated compound used to enhance the octane index of gasoline and replace lead in gasoline. MTBE can reduce air pollution but causes water pollution due to its high water solubility and low sorption to soil and thus can easily contaminate the environment. Biodegradation is one of the promising techniques to reduce MTBE contaminated in the environment and MTBE degrader was proposed as an efficient method used to degrade MTBE. In this study, MTBE degraders were isolated from gasoline contaminated soil and then were evaluated with the hypothesis that MTBE degraders could improve biodegradation of MTBE in soil and mixed culture could degrade MTBE more rapidly than monoculture. Gasoline contaminated soil samples were taken from retail gas stations and a motorcycle repair shop in Khon Kaen University. Isolation of MTBE degrader was conducted by using Basal Salt Medium (BSM containing 200 mg/L of MTBE as a carbon source. Mixed culture of MTBE degrader was successfully isolated under aerobic condition. Morphology study was conducted by streaking isolated mixed culture in solid medium, agar slant and identifying the cells shape under a microscope. It was found that this mixed culture was a gram negative bacteria with 7 different isolates. A comparison of the ability to degrade MTBE between mixed culture and monoculture was investigated in BSM containing 100 mg/L of MTBE. The results indicated that a mixed culture degraded MTBE more rapidly than monoculture i.e. 20% within 14 days. Monoculture, J4 and J7, were the most rapid MTBE degraders among the other monocultures in which they degraded 14% of MTBE in 14 days while monoculture J15 could degrade only 1% of MTBE.This preliminary result suggests that mixed cultures degrade MTBE more efficiently than monoculture.

  8. Microbial degradation and impact of Bracken toxin ptaquiloside on microbial communities in soil

    DEFF Research Database (Denmark)

    Engel, Pernille; Brandt, Kristian Koefoed; Rasmussen, Lars Holm

    2007-01-01

    ), but not in the NZ soil (weak acid loamy Entisol). In the DK soil PTA turnover was predominantly due to microbial degradation (biodegradation); chemical hydrolysis was occurring mainly in the uppermost A horizon where pH was very low (3.4). Microbial activity (basal respiration) and growth ([3H]leucine incorporation...... assay) increased after PTA exposure, indicating that the Bracken toxin served as a C substrate for the organotrophic microorganisms. On the other hand, there was no apparent impact of PTA on community size as measured by substrate-induced respiration or composition as indicated by community......-level physiological profiles. Our results demonstrate that PTA stimulates microbial activity and that microorganisms play a predominant role for rapid PTA degradation in Bracken-impacted soils....

  9. The impact of ancestral heath management on soils and landscapes. A reconstruction based on paleoecological analyses of soil records in the middle and southeast Netherlands.

    Science.gov (United States)

    van Mourik, Jan; Doorenbosch, Marieke

    2016-04-01

    The evolution of heath lands during the Holocene has been registered in various soil records . Paleoecological analyses of these records enable to reconstruct the changing economic and cultural management of heaths and the consequences for landscape and soils. Heaths are characteristic components of cultural landscape mosaics on sandy soils in the Netherlands. The natural habitat of heather species was moorland. At first, natural events like forest fires and storms caused small-scale forest degradation, in addition on the forest degradation accelerated due to cultural activities like forest grazing, wood cutting and shifting cultivation. Heather plants invaded on degraded forest soils and heaths developed. People learned to use the heaths for economic and cultural purposes. The impact of the heath management on landscape and soils was registered in soil records of barrows, drift sand sequences and plaggic Anthrosols. Based on pollen diagrams of such records we could reconstruct that heaths were developed and used for cattle grazing before the Bronze Age. During the Late Neolithic, the Bronze Age and Iron Age, people created the barrow landscape on the ancestral heaths. After the Iron Age people probably continued with cattle grazing on the heaths and plaggic agriculture until the Early Middle Ages. After 1000 AD two events affected the heaths. At first deforestation for the sale of wood resulted in the first regional extension of sand drifting and heath degradation. After that the introduction of the deep stable economy and heath sods digging resulted in acceleration of the rise of plaggic horizons, severe heath degradation and the second extension of sand drifting. At the end of the 19th century the heath lost its economic value due to the introduction of chemical fertilizers. The heaths were transformed into 'new' arable fields and forests and due to deep ploughing most soil archives were destroyed. Since 1980 AD, the remaining relicts of the ancestral heaths are

  10. Effect of cropping cycles and repeated herbicide applications on the degradation of diclofop-methyl, bentazone, diuron, isoproturon and pendimethalin in soil.

    Science.gov (United States)

    Piutti, Séverine; Marchand, Anne-Laure; Lagacherie, Bernard; Martin-Laurent, Fabrice; Soulas, Guy

    2002-03-01

    A greenhouse study was conducted to investigate the ability of four crops (wheat, corn, oilseed rape and soybean) to influence the degradation of bentazone, diclofop-methyl, diuron, isoproturon and pendimethalin in soil. The present study showed that microbial biomass-carbon was significantly higher in planted soils than in bulk soil, especially with wheat and corn, after several cropping cycles. The biomass in corn and soybean planted soils was adversely affected by bentazone but recovered after three cropping cycles. In wheat-planted soils, diclofop-methyl application resulted in persistent increase of the amount of microbial biomass. Bentazone did not show accelerated degradation even after five successive treatments, differing from diclofop-methyl, for which two applications were sufficient to enhance significantly its rate of degradation. Enhanced degradation of diclofop-methyl was even more pronounced in wheat-planted soil. The rates of mineralisation of diuron, isoproturon and pendimethalin were not affected after the first cropping cycle, but were significantly increased in planted soils after five cropping cycles. The results confirm that plants may promote pesticide degradation in soil by stimulating biodegradation processes. In the case of diclofop-methyl, stimulation of accelerated degradation was observed.

  11. Biological degradation of triclocarban and triclosan in a soil under aerobic and anaerobic conditions and comparison with environmental fate modelling

    International Nuclear Information System (INIS)

    Ying Guangguo; Yu Xiangyang; Kookana, Rai S.

    2007-01-01

    Triclocarban and triclosan are two antimicrobial agents widely used in many personal care products. Their biodegradation behaviour in soil was investigated by laboratory degradation experiments and environmental fate modelling. Quantitative structure-activity relationship (QSAR) analyses showed that triclocarban and triclosan had a tendency to partition into soil or sediment in the environment. Fate modelling suggests that either triclocarban or triclosan 'does not degrade fast' with its primary biodegradation half-life of 'weeks' and ultimate biodegradation half-life of 'months'. Laboratory experiments showed that triclocarban and triclosan were degraded in the aerobic soil with half-life of 108 days and 18 days, respectively. No negative effect of these two antimicrobial agents on soil microbial activity was observed in the aerobic soil samples during the experiments. But these two compounds persisted in the anaerobic soil within 70 days of the experimental period. - Triclocarban and triclosan can be degraded by microbial processes in aerobic soil, but will persist in anaerobic soil

  12. Biological degradation of triclocarban and triclosan in a soil under aerobic and anaerobic conditions and comparison with environmental fate modelling

    Energy Technology Data Exchange (ETDEWEB)

    Guangguo, Ying [State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640 (China); CSIRO Land and Water, Adelaide Laboratory, PMB2, Glen Osmond SA 5064 (Australia)], E-mail: guang-guo.ying@gig.ac.cn; Xiangyang, Yu [CSIRO Land and Water, Adelaide Laboratory, PMB2, Glen Osmond SA 5064 (Australia); Food Safety Research Institute, Jiangsu Academy of Agricultural Sciences, Nanjing 210014 (China); Kookana, Rai S [CSIRO Land and Water, Adelaide Laboratory, PMB2, Glen Osmond SA 5064 (Australia)

    2007-12-15

    Triclocarban and triclosan are two antimicrobial agents widely used in many personal care products. Their biodegradation behaviour in soil was investigated by laboratory degradation experiments and environmental fate modelling. Quantitative structure-activity relationship (QSAR) analyses showed that triclocarban and triclosan had a tendency to partition into soil or sediment in the environment. Fate modelling suggests that either triclocarban or triclosan 'does not degrade fast' with its primary biodegradation half-life of 'weeks' and ultimate biodegradation half-life of 'months'. Laboratory experiments showed that triclocarban and triclosan were degraded in the aerobic soil with half-life of 108 days and 18 days, respectively. No negative effect of these two antimicrobial agents on soil microbial activity was observed in the aerobic soil samples during the experiments. But these two compounds persisted in the anaerobic soil within 70 days of the experimental period. - Triclocarban and triclosan can be degraded by microbial processes in aerobic soil, but will persist in anaerobic soil.

  13. Performance of Low-Volume Roads with Wearing Course Layer of Silty Sandy Soil Modified with Rice Husk Ash and Lime

    Energy Technology Data Exchange (ETDEWEB)

    Behak Katz, L.; Musso Laespiga, M.

    2016-07-01

    Rice husk ash (RHA) is a by-product of rice milling. Its use as soil stabilizer is a way to replace the final disposal with environmental benefit. However, RHA is not cementitious itself but when mixed with lime forms cements which improve the soil properties. A research of performance of a silty sandy soil modified with RHA and lime as wearing course layer of low-volume roads was conducted through two full-scale test sections with different pavements built in Artigas, northern Uruguay. The alkaline reactivity of RHA is low because the husk burning is not controlled. The soil-RHA-lime mix design was conducted according to the Thompson’s Method. The pavement test sections were monitored through deflection measures by Benkelman beam and observations of surface condition. The deflections decreased over time in both test sections due to the development of cementation of the study materials. After one year, the dust emission was reduced, the wet skid resistance of pavement surfaces improved and there was not rutting. The researched pavements have had a good performance under the existing traffic and environmental conditions, demonstrating that wearing course layer of silty sand modified with RHA and lime is an alternative to improve the condition of low-volume roads and to replace the final disposal of RHA, with environmental, social and economic benefits. (Author)

  14. Degradation of sustainable mulch materials in two types of soil under laboratory conditions

    Science.gov (United States)

    Villena, Jaime; González, Sara; Moreno, Carmen; Aceituno, Patricia; Campos, Juan; Meco, Ramón; María Moreno, Marta

    2017-04-01

    Mulching is a technique used in cultivation worldwide, especially for vegetable crops, for reducing weed growth, minimising or eliminating soil erosion, and often for enhancing total yields. Manufactured plastic films, mainly polyethylene (PE), have been widely used for this purpose due to their excellent mechanical properties, light weight and relatively low prices in recent years. However, the use of PE is associated with serious environmental problems related to its petrochemical origin and its long shelf-life, which causes a waste problem in our crop fields. For this reason, the use of biodegradable mulch materials (biopolymers and papers) as alternative to PE is increasing nowadays, especially in organic farming. However, these materials can suffer an undesirable early degradation (and therefore not fulfilling their function successfully), greatly resulting from the type of soil. For this reason, this study aimed to analyse the degradation pattern of different mulch materials buried in two types of soils, clay and sand, under laboratory conditions (25°C, dark surroundings, constant humidity). The mulch materials used were: 1) black polyethylene (15 µm); black biopolymers (15 µm): 2) maize starch-based, 3) potato starch-based, 4) polylactic acid-based, 5) black paper, 85 g/m2. Periodically (every 15-20 days), the weight and surface loss of the different materials were recorded. The results indicate that mulch degradation was earlier and higher in the clay soil, especially in the paper and in the potato starch-based materials, followed by the maize starch-based mulch, while polylactic acid-based suffered the least and the latest degradation. Keywords: mulch, biodegradable, biopolymer, paper, degradation. Acknowledgements: the research was funded by Project RTA2011-00104-C04-03 from the INIA (Spanish Ministry of Economy and Competitiveness).

  15. Catalytic degradation of the soil fumigant 1,3-dichloropropene in aqueous biochar slurry

    Energy Technology Data Exchange (ETDEWEB)

    Qin, Jiaolong [School of Agriculture and Biology, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240 (China); Cheng, Yuxiao; Sun, Mingxing [Shanghai Entry–Exit Inspection and Quarantine Bureau, Shanghai 200135 (China); Yan, Lili [School of Agriculture and Biology, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240 (China); Shen, Guoqing, E-mail: gqsh@sjtu.edu.cn [School of Agriculture and Biology, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240 (China)

    2016-11-01

    Biochar has been explored as a cost-effective sorbent of contaminants, such as soil fumigant. However, contaminant-loaded biochar probably becomes a source of secondary air pollution. In this study, biochars developed from cow manure and rice husk at 300 °C or 700 °C were used to investigate the catalytic degradation of the soil fumigant 1,3-dichloropropene (1,3-D) in aqueous biochar slurry. Results showed that the adsorption of 1,3-D on the biochars was influenced by Langmuir surface monolayer adsorption. The maximum adsorption capacity of cow manure was greater than that of rice husk at the same pyrolysis temperature. Batch experiments revealed that 1,3-D degradation was improved in aqueous biochar slurry. The most rapid 1,3-D degradation occurred on cow manure-derived biochar produced at 300 °C (C-300), with t{sub 1/2} = 3.47 days. The degradation efficiency of 1,3-D on C-300 was 95.52%. Environmentally persistent free radicals (EPFRs) in biochars were detected via electron paramagnetic resonance (EPR) techniques. Dissolved organic matter (DOM) and hydroxyl radical (·OH) in biochars were detected by using a fluorescence spectrophotometer coupled with a terephthalic acid trapping method. The improvement of 1,3-D degradation efficiency may be attributed to EPFRs and DOM in aqueous biochar slurry. Our results may pose implications in the development of effective reduction strategies for soil fumigant emission with biochar. - Highlights: • Hydrolysis of 1,3-D was accelerated in aqueous biochar slurry. • 1,3-D adsorption kinetics on biochars fitted well with Langmuir model. • Cow manure biochar showed higher catalytic degradation activity for 1,3-D than rice husk biochar did. • EPFRs and DOM have potential roles in 1,3-D degradation on biochar.

  16. Catalytic degradation of the soil fumigant 1,3-dichloropropene in aqueous biochar slurry

    International Nuclear Information System (INIS)

    Qin, Jiaolong; Cheng, Yuxiao; Sun, Mingxing; Yan, Lili; Shen, Guoqing

    2016-01-01

    Biochar has been explored as a cost-effective sorbent of contaminants, such as soil fumigant. However, contaminant-loaded biochar probably becomes a source of secondary air pollution. In this study, biochars developed from cow manure and rice husk at 300 °C or 700 °C were used to investigate the catalytic degradation of the soil fumigant 1,3-dichloropropene (1,3-D) in aqueous biochar slurry. Results showed that the adsorption of 1,3-D on the biochars was influenced by Langmuir surface monolayer adsorption. The maximum adsorption capacity of cow manure was greater than that of rice husk at the same pyrolysis temperature. Batch experiments revealed that 1,3-D degradation was improved in aqueous biochar slurry. The most rapid 1,3-D degradation occurred on cow manure-derived biochar produced at 300 °C (C-300), with t 1/2 = 3.47 days. The degradation efficiency of 1,3-D on C-300 was 95.52%. Environmentally persistent free radicals (EPFRs) in biochars were detected via electron paramagnetic resonance (EPR) techniques. Dissolved organic matter (DOM) and hydroxyl radical (·OH) in biochars were detected by using a fluorescence spectrophotometer coupled with a terephthalic acid trapping method. The improvement of 1,3-D degradation efficiency may be attributed to EPFRs and DOM in aqueous biochar slurry. Our results may pose implications in the development of effective reduction strategies for soil fumigant emission with biochar. - Highlights: • Hydrolysis of 1,3-D was accelerated in aqueous biochar slurry. • 1,3-D adsorption kinetics on biochars fitted well with Langmuir model. • Cow manure biochar showed higher catalytic degradation activity for 1,3-D than rice husk biochar did. • EPFRs and DOM have potential roles in 1,3-D degradation on biochar.

  17. Correlations of soil-gas and indoor radon with geology in glacially derived soils of the northern Great Plains

    International Nuclear Information System (INIS)

    Schumann, R.R.; Owen, D.E.; Peake, R.T.; Schmidt, K.M.

    1990-01-01

    This paper reports that a higher percentage of homes in parts of the northern Great Plains underlain by soils derived from continental glacial deposits have elevated indoor radon levels (greater than 4 pCi/L) than any other area in the country. Soil-gas radon concentrations, surface radioactivity, indoor radon levels, and soil characteristics were studied in areas underlain by glacially-derived soils in North Dakota and Minnesota to examine the factors responsible for these elevated levels. Clay-rich till soils in North Dakota have generally higher soil-gas radon levels, and correspondingly higher indoor radon levels, than the sandy till soils common to west-central Minnesota. Although the proportions of homes with indoor radon levels greater than 4 pCi/L are similar in both areas, relatively few homes underlain by sandy tills have screening indoor radon levels greater than 20 pCi/L, whereas a relatively large proportion of homes underlain by clayey tills have screening indoor radon levels exceeding 20 pCi/L. The higher radon levels in North Dakota are likely due to enhanced emanation from the smaller grains and to relatively higher soil radium concentrations in the clay-rich soils, whereas the generally higher permeability of the sandy till soils in Minnesota allows soil gas to be drawn into structures from a larger source volume, increasing indoor radon levels in these areas

  18. Radiological aspects of choice of a system of cultivation of sod-podzolic sandy loam soils with different degree of humidity on lands of Mogilev region contaminated with 137Cs

    International Nuclear Information System (INIS)

    Lazarevich, S.S.; Ermolenko, A.V.; Shapsheeva, T.P.

    2010-01-01

    In the conditions of the Republic of Belarus there were presented data about the influence of technological factors on entry of 137Cs into plant products (grain and green mass). In course of the study there were analyzed the following variants of soil cultivation: moldboard plowing; subsurface chisel soil tillage; subsurface surface soil tillage; minimal tillage. There were presented data on specific activity of 137Cs in plant product samples of oat (Avena sativa) grain; field pea (Pisum arvense L.) and oat mixture grain and green mass; wheat (Triticum aestivum) grain. There were determined the main principles of influence of cultivation systems of sod-podzolic sandy loam soil with different degree of humidity on transition of 137Cs into plants depending on the degree of soil and crop humidity. On the automorphic soil there was revealed a tendency of increased transition of 137Cs into grain and green mass after application of subsurface surface soil tillage system

  19. Soil bacterial consortia and previous exposure enhance the biodegradation of sulfonamides from pig manure.

    Science.gov (United States)

    Islas-Espinoza, Marina; Reid, Brian J; Wexler, Margaret; Bond, Philip L

    2012-07-01

    Persistence or degradation of synthetic antibiotics in soil is crucial in assessing their environmental risks. Microbial catabolic activity in a sandy loamy soil with pig manure using 12C- and 14C-labelled sulfamethazine (SMZ) respirometry showed that SMZ was not readily degradable. But after 100 days, degradation in sulfadiazine-exposed manure was 9.2%, far greater than soil and organic manure (0.5% and 0.11%, respectively, p library from the treatment with highest degradation showed that most bacteria belonged to α, β and γ classes of Proteobacteria, Firmicutes, Bacteroidetes and Acidobacteria. Proteobacteria (α, β and γ), Firmicutes and Bacteroidetes which were the most abundant classes on day 1 also decreased most following prolonged exposure. From the matrix showing the highest degradation rate, 17 SMZ-resistant isolates biodegraded low levels of 14C-labelled SMZ when each species was incubated separately (0.2-1.5%) but biodegradation was enhanced when the four isolates with the highest biodegradation were incubated in a consortium (Bacillus licheniformis, Pseudomonas putida, Alcaligenes sp. and Aquamicrobium defluvium as per 16S rRNA gene sequencing), removing up to 7.8% of SMZ after 20 days. One of these species (B. licheniformis) was a known livestock and occasional human pathogen. Despite an environmental role of these species in sulfonamide bioremediation, the possibility of horizontal transfer of pathogenicity and resistance genes should caution against an indiscriminate use of these species as sulfonamide degraders.

  20. Soil degradation of parthenin-does it contradict the role of allelopathy in the invasive weed Parthenium hysterophorus L.?

    Science.gov (United States)

    Belz, Regina G; van der Laan, Michael; Reinhardt, Carl F; Hurle, Karl

    2009-09-01

    The invasive success of Parthenium hysterophorus L. is thought to be partially attributable to allelopathy mediated by the plant metabolite parthenin. To assess the ecological significance of parthenin release from plant material, its persistence and phytotoxicity in soil was studied. Results show parthenin is rapidly degraded with an average DT (50) of 59 h under standard experimental conditions. Degradation was delayed in sterilized soils, at lower soil moisture, and higher parthenin concentrations. Higher temperatures, higher CEC(pot)/clay content of soils, soil preconditioning with parthenin, and P. hysterophorus infestation accelerated degradation. Physico-chemical and biological processes are, therefore, expected to govern the fate of parthenin in soil. Parthenin exhibited low soil phytotoxicity and did not accumulate over time. Along with the indicated reduction in bioavailability and development of hormetic effects, results suggest that for parthenin to have detrimental allelopathic effects, it requires high P. hysterophorus densities that result in high soil levels of parthenin and soil conditions that favor the persistence of parthenin. In light of this, the ecological significance of parthenin is discussed.

  1. Use of olive oil for soil extraction and ultraviolet degradation of polychlorinated dibenzo-p-dioxins and dibenzofurans.

    Science.gov (United States)

    Isosaari, P; Tuhkanen, T; Vartiainen, T

    2001-03-15

    This paper represents a successful laboratory-scale photolysis of soil-bound tetra- to octachlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) in olive oil. The irradiation source consisted of two blacklight lamps emitting light at a near-ultraviolet range. Samples used in the experiments included pure 1,2,3,4,6,7,8-heptachlorodibenzofuran, PCDD/F extract made of a wood preservative (chlorophenol product Ky 5), and soil that was highly contaminated with PCDD/Fs. Degradation of 1,2,3,4,6,7,8-heptachlorodibenzofuran dissolved in olive oil proceeded rapidlywith a first-order reaction half-life of 13 min. Irradiation of a soil sample resulted in an 84% reduction in PCDD/F toxicity equivalent (I-TEQ) in 17.5 h. A more complete degradation of soil-bound PCDD/Fs was achieved after extraction of the soil with olive oil. The oil was effective in solubilizing PCDD/Fs. After one extraction at room temperature, only 9% of I-TEQ remained in soil. Irradiation of the resulting extract reduced toxicity of the extract by 99%, and even the highly chlorinated congeners octachlorodibenzo-p-dioxin and octachlorodibenzofuran degraded easily (97 and 99% degradation, respectively). Photodegradation byproducts found included diphenyl ether and small amounts of dechlorination products, which were mainly nontoxic PCDD/Fs. Degradation was probably mediated by light absorption of unsaturated fatty acids and phenolic compounds in olive oil, leading to sensitized photolysis of PCDD/Fs.

  2. Amylase activity of a starch degrading bacteria isolated from soil ...

    African Journals Online (AJOL)

    Starch degrading bacteria are most important for industries such as food, fermentation, textile and paper. Thus isolating and manipulating pure culture from various waste materials has manifold importance for various biotechnology industries. In the present investigation a bacterial strain was isolated from soil sample ...

  3. Composting Technology and the Impact of Compost on Soil Biochemical Properties

    International Nuclear Information System (INIS)

    Abdel-aziz, Reda Abdel Thaher; Al-Barakh, Fahad bin Nasser

    2005-01-01

    Organic farming is one of several approaches to sustainable agriculture. Properly managed, organic farming reduces or eliminates environmental pollution and helps conserve water and soil on the farm. Organic farming systems require significantly greater amounts of organic fertilizers input than conventional systems. Because of the shortage of organic fertilizers in arid areas, composting is a way to transform waste materials left over from agricultural production and processing into a useful resource. Mature compost is an excellent organic fertilizer and soil amendment. The potential of composting to turn on-farm waste material into farm resources makes it an attractive proposition. Composting offers several benefits such as to enhance soil fertility and soil health, thereby increasing agricultural productivity, improving soil biodiversity, reducing ecological risks and improving the environment. Aerobic composting of some agricultural wastes (peanut, wheat straw and palm tree wastes) was carried out to raise its fertilizing value compared with widely used organic fertilizer, farmyard manure. The influence of composted and non-composted agricultural wastes on the availability of nitrogen, phosphorus and potassium (NPK) in sandy soil, as well as the uptake of these elements by corn plants, was also studied. Results indicated a rapid degradation of palm tree and wheat straw wastes as compared with peanut wastes. The composting process raised the fertilizing value of agricultural wastes as indicated by increase in nutritional availability. The application of the composted wastes as organic fertilizers to sandy soil increased the content of available N, P and K. Results showed that the application of different composted organic materials increased the dry weight and NPK uptake by corn plants. (author)

  4. IMPACT OF A USED STABILISER ON THE CALIFORNIA BEARING RATIO OF THE CLAYEY-SANDY SILT

    Directory of Open Access Journals (Sweden)

    Katarzyna Kamińska

    2017-01-01

    Full Text Available The paper aimed at the determination of the California Bearing Ratio of a stabilised and unstabilised fine-grained mineral soil. A clayey-sandy silt with the addition of 3, 6 and 10% of road stabilisers Solidex and Solidex A was used for the tests. The tests were carried out in the press Tritech 50 at the loading of 22 and 44 N. The stabilised samples were subjected to 7-days treatment, whereas unstabilised 4-days treatment. Stabilization with the applied road binders brought positive effects, there occurred a significant improvement in the mechanical properties of the clayey-sandy silt. The better binder, which significantly increased the value of the CBR ratio, was Solidex A. The use of hydraulic binders is of a great importance in road building, because their addition improves the mechanical properties of weaker mineral soils.

  5. Analysis of volatile organic compound from Elaeis guineensis inflorescences planted on different soil types in Malaysia

    Science.gov (United States)

    Muhamad Fahmi, M. H.; Ahmad Bukhary, A. K.; Norma, H.; Idris, A. B.

    2016-11-01

    The main attractant compound for Eleidobius kamerunicus to male spikelet Elaeis guineensis (oil palm) were determined by analyzing volatile organic compound extracted from E. guineenses inflorescences planted on different soil types namely peat soil, clay soil and sandy soil. Anthesizing male oil palm inflorescences were randomly choosen from palm aged between 4-5 years old age. Extraction of the volatiles from the oil palm inflorescences were performed by Accelerated Solvent Extraction method (ASE). The extracted volatile compound were determined by using gas chromatography-mass spectrometry. Out of ten identified compound, estragole was found to be a major compound in sandy soil (37.49%), clay soil (30.71%) and peat soil (27.79%). Other compound such as 9,12-octadecadieonic acid and n-hexadecanoic acid were found as major compound in peat soil (27.18%) and (7.45%); sandy soil (14.15 %) and (9.31%); and clay soil (30.23%) and (4.99%). This study shows that estragole was the predominant volatile compound detected in oil palm inflorescences with highly concentrated in palm planted in sandy soil type.

  6. Effects of grazing strategy on limiting nitrate leaching in grazed grass-clover pastures on coarse sandy soil

    DEFF Research Database (Denmark)

    Hansen, Elly Møller; Eriksen, Jørgen; Søegaard, Karen

    2012-01-01

    -term mean. The experiment was initiated in a 4-yr-old grass-clover sward in south Denmark. Three treatments were as follows grazing only (G), spring cut followed by grazing (CG) and both spring and autumn cuts with summer grazing (CGC). Nitrate leaching was calculated by extracting water isolates from 80 cm......Urinations of ruminants on grazed pastures increase the risk of nitrate leaching. The study investigated the effect of reducing the length of the grazing season on nitrate leaching from a coarse sandy, irrigated soil during 2006–2007 and 2007–2008. In both years, precipitation was above the long...... depth using ceramic suction cups. Because of considerable variation in measured nitrate concentrations, the 32 installed suction cups per treatment were insufficient to reveal differences between treatments. However, weighted nitrate leaching estimations for G, CG and CGC showed estimated mean nitrate N...

  7. Diphenylarsinic acid contaminated soil remediation by titanium dioxide (P25) photocatalysis: Degradation pathway, optimization of operating parameters and effects of soil properties

    International Nuclear Information System (INIS)

    Wang, A-nan; Teng, Ying; Hu, Xue-feng; Wu, Long-hua; Huang, Yu-juan; Luo, Yong-ming; Christie, Peter

    2016-01-01

    Diphenylarsinic acid (DPAA) is formed during the leakage of arsenic chemical weapons in sites and poses a high risk to biota. However, remediation methods for DPAA contaminated soils are rare. Here, the photocatalytic oxidation (PCO) process by nano-sized titanium dioxide (TiO_2) was applied to degrade DPAA in soil. The degradation pathway was firstly studied, and arsenate was identified as the final product. Then, an orthogonal array experimental design of L_9(3)"4, only 9 experiments were needed, instead of 81 experiments in a conventional one-factor-at-a-time, was used to optimize the operational parameters soil:water ratio, TiO_2 dosage, irradiation time and light intensity to increase DPAA removal efficiency. Soil:water ratio was found to have a more significant effect on DPAA removal efficiency than other properties. The optimum conditions to treat 4 g soil with a DPAA concentration of 20 mg kg"−"1 were found to be a 1:10 soil: water ratio, 40 mW cm"−"2 light intensity, 5% TiO_2 in soil, and a 3-hour irradiation time, with a removal efficiency of up to 82.7%. Furthermore, this method (except for a change in irradiation time from 3 to 1.5 h) was validated in nine different soils and the removal efficiencies ranged from 57.0 to 78.6%. Removal efficiencies were found to be negatively correlated with soil electrical conductivity, organic matter content, pH and total phosphorus content. Finally, coupled with electron spin resonance (ESR) measurement, these soil properties affected the generation of OH• by TiO_2 in soil slurry. This study suggests that TiO_2 photocatalytic oxidation is a promising treatment for removing DPAA from soil. - Highlights: • DPAA was degraded into arsenate through TiO_2 (P25) photocatalytic oxidation. • Soil/water ratio was more influential on the removal of DPAA in soil by TiO_2 (P25). • Soil properties affected the adsorption of DPAA and the generation of OH• by TiO_2.

  8. Soil physical degradation by human activities in the zone II of the basin of Burgos, Tamaulipas, Mexico

    International Nuclear Information System (INIS)

    Arias Mino, F.; Espinosa Rmirez, M.; Andrade Limas, E.; Castro Meza, B.; Romero Diaz, A.

    2009-01-01

    The objective of this work was to characterize the physical degradation of the soil for antropic activities during the years 2007 and 2008 in the II zone of the Burgos Basin in Tamaulipas, Mexico. In this region, human action manifests itself due to activities such as agriculture, livestock and industry. The conventional farming, based mainly on the cultivation of sorghum, is characterized by great mechanization and tilling the soil which has contributed in large measure to aggravate erosion processes. There is also some logging, mainly for charcoal production and, recently, has joined the exploration and exploitation of natural gas. We used the methodology for Assessment of Soil Degradation (ASSOD) to identify, located and define the types of soil degradation within physiographic units. Results showed that nearly 74% of the study area presents some kind of degradation. The main process was water erosion, followed, by compaction and wind erosion. The main factors are essentially overgrazing and inadequate farming practices. Approximately 60% of the units evaluated presented a moderate level of degradation, but the speed of this process indicates that maintenance works are needed to reverse. (Author) 7 refs.

  9. Plant-uptake of uranium: Hydroponic and soil system studies

    Science.gov (United States)

    Ramaswami, A.; Carr, P.; Burkhardt, M.

    2001-01-01

    Limited information is available on screening and selection of terrestrial plants for uptake and translocation of uranium from soil. This article evaluates the removal of uranium from water and soil by selected plants, comparing plant performance in hydroponic systems with that in two soil systems (a sandy-loam soil and an organic-rich soil). Plants selected for this study were Sunflower (Helianthus giganteus), Spring Vetch (Vicia sativa), Hairy Vetch (Vicia villosa), Juniper (Juniperus monosperma), Indian Mustard (Brassica juncea), and Bush Bean (Phaseolus nanus). Plant performance was evaluated both in terms of the percent uranium extracted from the three systems, as well as the biological absorption coefficient (BAC) that normalized uranium uptake to plant biomass. Study results indicate that uranium extraction efficiency decreased sharply across hydroponic, sandy and organic soil systems, indicating that soil organic matter sequestered uranium, rendering it largely unavailable for plant uptake. These results indicate that site-specific soils must be used to screen plants for uranium extraction capability; plant behavior in hydroponic systems does not correlate well with that in soil systems. One plant species, Juniper, exhibited consistent uranium extraction efficiencies and BACs in both sandy and organic soils, suggesting unique uranium extraction capabilities.

  10. Engineering Pseudomonas putida KT2440 for simultaneous degradation of organophosphates and pyrethroids and its application in bioremediation of soil.

    Science.gov (United States)

    Zuo, Zhenqiang; Gong, Ting; Che, You; Liu, Ruihua; Xu, Ping; Jiang, Hong; Qiao, Chuanling; Song, Cunjiang; Yang, Chao

    2015-06-01

    Agricultural soils are usually co-contaminated with organophosphate (OP) and pyrethroid pesticides. To develop a stable and marker-free Pseudomonas putida for co-expression of two pesticide-degrading enzymes, we constructed a suicide plasmid with expression cassettes containing a constitutive promoter J23119, an OP-degrading gene (mpd), a pyrethroid-hydrolyzing carboxylesterase gene (pytH) that utilizes the upp gene as a counter-selectable marker for upp-deficient P. putida. By introduction of suicide plasmid and two-step homologous recombination, both mpd and pytH genes were integrated into the chromosome of a robust soil bacterium P. putida KT2440 and no selection marker was left on chromosome. Functional expression of mpd and pytH in P. putida KT2440 was demonstrated by Western blot analysis and enzyme activity assays. Degradation experiments with liquid cultures showed that the mixed pesticides including methyl parathion, fenitrothion, chlorpyrifos, permethrin, fenpropathrin, and cypermethrin (0.2 mM each) were degraded completely within 48 h. The inoculation of engineered strain (10(6) cells/g) to soils treated with the above mixed pesticides resulted in a higher degradation rate than in noninoculated soils. All six pesticides could be degraded completely within 15 days in fumigated and nonfumigated soils with inoculation. Theses results highlight the potential of the engineered strain to be used for in situ bioremediation of soils co-contaminated with OP and pyrethroid pesticides.

  11. Patterns and possible mechanisms of soil CO2 uptake in sandy soil.

    Science.gov (United States)

    Fa, Ke-Yu; Zhang, Yu-Qing; Wu, Bin; Qin, Shu-Gao; Liu, Zhen; She, Wei-Wei

    2016-02-15

    It has been reported that soils in drylands can absorb CO2, although the patterns and mechanisms of such a process remain under debate. To address this, we investigated the relationships between soil CO2 flux and meteorological factors and soil properties in Northwest China to reveal the reasons for "anomalous" soil CO2 flux in a desert ecosystem. Soil CO2 flux increased significantly and exponentially with surficial turbulence at the diel scale under dry conditions (Psoil CO2 flux demonstrated remarkable negative correlation with soil air pressure (Psoil water content was insufficient to dissolve the absorbed CO2 in dry conditions, but was sufficient in wet conditions. The concentration of soil HCO3(-) in the morning was higher than in the evening in dry conditions, but this pattern was reversed in wet conditions. These results imply that CO2 outgassing induced by turbulence, expansion of soil air, CO2 effusion from soil water, and carbonate precipitation during daytime can explain the abiotic diurnal CO2 release. Moreover, CO2 pumping from the atmosphere into the soil, caused mainly by carbonate dissolution, can account for nocturnal CO2 absorption in dry conditions. The abiotic soil CO2 flux pattern (CO2 absorption throughout the diel cycle) in wet conditions can be attributed to downward mass flow of soil CO2 and intensified soil air shrinkage, CO2 dissolving in soil water, and carbonate dissolution. These results provide a basis for determining the location of abiotic fixed carbon within soils in desert ecosystems. Copyright © 2015 Elsevier B.V. All rights reserved.

  12. Bacteria capable of degrading anthracene, phenanthrene, and fluoranthene as revealed by DNA based stable-isotope probing in a forest soil

    Energy Technology Data Exchange (ETDEWEB)

    Song, Mengke [Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640 (China); Jiang, Longfei [College of Life Sciences, Nanjing Agricultural University, Nanjing 210095 (China); Zhang, Dayi [Lancaster Environment Centre, Lancaster University, Lancaster LA1 4YQ (United Kingdom); Luo, Chunling, E-mail: clluo@gig.ac.cn [Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640 (China); Wang, Yan [Key Laboratory of Industrial Ecology and Environmental Engineering (MOE), School of Environmental Science and Technology, Dalian University of Technology, Dalian 116024 (China); Yu, Zhiqiang [Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640 (China); Yin, Hua [College of Environment and Energy, South China University of Technology, Guangzhou 510006 (China); Zhang, Gan [Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640 (China)

    2016-05-05

    Highlights: • Investigate PAHs degraders in forest carbon-rich soils via DNA-SIP. • Rhodanobacter is identified to metabolite anthracene for the first time. • The first fluoranthene degrader belongs to Acidobacteria. • Different functions of PAHs degraders in forest soils from contaminated soils. - Abstract: Information on microorganisms possessing the ability to metabolize different polycyclic aromatic hydrocarbons (PAHs) in complex environments helps in understanding PAHs behavior in natural environment and developing bioremediation strategies. In the present study, stable-isotope probing (SIP) was applied to investigate degraders of PAHs in a forest soil with the addition of individually {sup 13}C-labeled phenanthrene, anthracene, and fluoranthene. Three distinct phylotypes were identified as the active phenanthrene-, anthracene- and fluoranthene-degrading bacteria. The putative phenanthrene degraders were classified as belonging to the genus Sphingomona. For anthracene, bacteria of the genus Rhodanobacter were the putative degraders, and in the microcosm amended with fluoranthene, the putative degraders were identified as belonging to the phylum Acidobacteria. Our results from DNA-SIP are the first to directly link Rhodanobacter- and Acidobacteria-related bacteria with anthracene and fluoranthene degradation, respectively. The results also illustrate the specificity and diversity of three- and four-ring PAHs degraders in forest soil, contributes to our understanding on natural PAHs biodegradation processes, and also proves the feasibility and practicality of DNA-based SIP for linking functions with identity especially uncultured microorganisms in complex microbial biota.

  13. Investigation of the variation of the specific heat capacity of local soil samples from the Niger delta, Nigeria with moisture content

    International Nuclear Information System (INIS)

    Ofoegbu, C.O.; Adjepong, S.K.

    1987-11-01

    Results of an investigation of the variation, with moisture content, of the specific heat capacity of samples of three texturally different types of soil (clayey, sandy and sandy loam) obtained from the Niger delta area of Nigeria, are presented. The results show that the specific heat capacities of the soils studied, increase with moisture content. This increase is found to be linear for the entire range of moisture contents considered (0-25%), in the case of the sandy loam soil while for the clayey and sandy soils the specific heat capacity is found to increase linearly with moisture content up to about 15% after which the increase becomes parabolic. The rate of increase of specific heat capacity with moisture content appears to be highest in the clayey soil and lowest in the sandy soil. It is thought that the differences in the rates of increase of specific heat capacity with moisture content, observed for the soils, reflect the soils' water-retention capacities. (author) 3 refs, 5 figs

  14. Characterization of dioxygenases and biosurfactants produced by crude oil degrading soil bacteria

    Directory of Open Access Journals (Sweden)

    Santhakumar Muthukamalam

    Full Text Available ABSTRACT Role of microbes in bioremediation of oil spills has become inevitable owing to their eco friendly nature. This study focused on the isolation and characterization of bacterial strains with superior oil degrading potential from crude-oil contaminated soil. Three such bacterial strains were selected and subsequently identified by 16S rRNA gene sequence analysis as Corynebacterium aurimucosum, Acinetobacter baumannii and Microbacterium hydrocarbonoxydans respectively. The specific activity of catechol 1,2 dioxygenase (C12O and catechol 2,3 dioxygenase (C23O was determined in these three strains wherein the activity of C12O was more than that of C23O. Among the three strains, Microbacterium hydrocarbonoxydans exhibited superior crude oil degrading ability as evidenced by its superior growth rate in crude oil enriched medium and enhanced activity of dioxygenases. Also degradation of total petroleum hydrocarbon (TPH in crude oil was higher with Microbacterium hydrocarbonoxydans. The three strains also produced biosurfactants of glycolipid nature as indicated d by biochemical, FTIR and GCMS analysis. These findings emphasize that such bacterial strains with superior oil degrading capacity may find their potential application in bioremediation of oil spills and conservation of marine and soil ecosystem.

  15. Least limiting water range of Udox soil under degraded pastures on different sun-exposed faces

    Science.gov (United States)

    Passos, Renato Ribeiro; Marciano da Costa, Liovando; Rodrigues de Assis, Igor; Santos, Danilo Andrade; Ruiz, Hugo Alberto; Guimarães, Lorena Abdalla de Oliveira Prata; Andrade, Felipe Vaz

    2017-07-01

    The efficient use of water is increasingly important and proper soil management, within the specificities of each region of the country, allows achieving greater efficiency. The South and Caparaó regions of Espírito Santo, Brazil are characterized by relief of `hill seas' with differences in the degree of pasture degradation due to sun exposure. The objective of this study was to evaluate the least limiting water range in Udox soil under degraded pastures with two faces of exposure to the sun and three pedoenvironments. In each pedoenvironment, namely Alegre, Celina, and Café, two areas were selected, one with exposure on the North/West face and the other on the South/East face. In each of these areas, undisturbed soil samples were collected at 0-10 cm depth to determine the least limiting water range. The exposed face of the pasture that received the highest solar incidence (North/West) presented the lowest values in least limiting water range. The least limiting water range proved to be a physical quality indicator for Udox soil under degraded pastures.

  16. Coastal Plain Soil Fertility Degradation And Natural Forest Ecosystem Regeneration

    Science.gov (United States)

    Casagrande, J. C.; Sato, C. A.; Reis-Duarte, R. M.; Soares, M. R.; Galvão Bueno, M. S.

    2009-04-01

    The sand coastal plain vegetation (Restinga Forest) has been described as an ecosystem associated with the Atlantic Forest, constituted of mosaics, which occur in areas of great ecological diversity, particularly the features of the soil which mostly influence the forest, therefore assigned as edaphic community. The Restinga forest is one of the most fragile, showing low resilience to human damage This work was carried out in several points (14) of Restinga Forest (six low - trees from 3 to 10 m high - and eight high forest - trees from 10 to 15 m high) in the litoral coast of the state of São Paulo. Each sample was made of 15 subsamples of each area collected in each depth (one in 0 - 5, 5 - 10, 10 - 15, 15 - 20, and another in 0 - 20, 20 - 40, 40 and 60 cm). Soil characteristics analyzed were pH, P, Na, K, Ca, Mg, S, H + Al, Al, B, Cu, Fe, Mn, Zn contents and base saturation, cation exchange capacity and aluminum saturation. The vegetation physiognomies of Restinga forest (low and high) were associated with soil results and with the history of human occupation. The soils are sandy (2 to 4% of clay), resulting in a low capacity of nutrient retention. Soil fertility analysis to low and high Restinga forest were similar and showed very low contents of phosphorous, calcium and magnesium in all areas investigated. The base saturation was low due to low amounts of Na, K, Ca and Mg. Base saturation presents low level in all cases, less than 10, indicating low nutritional reserve in the soil. The aluminum saturation values varied from 58 to 69%. The level of calcium and magnesium were low in the subsurface soil layer mainly, associate with high aluminum saturation, representing an limiting factor for the root system development in depth. If soil fertility parameters do not show any significant difference between low and high Restinga physiognomy, what make distinction is the recuperation time. In the areas of high Forest can be note a too long time of recuperation

  17. Influence of soil texture on hydraulic properties and water relations of a dominant warm-desert phreatophyte.

    Science.gov (United States)

    Hultine, K R; Koepke, D F; Pockman, W T; Fravolini, A; Sperry, J S; Williams, D G

    2006-03-01

    We investigated hydraulic constraints on water uptake by velvet mesquite (Prosopis velutina Woot.) at a site with sandy-loam soil and at a site with loamy-clay soil in southeastern Arizona, USA. We predicted that trees on sandy-loam soil have less negative xylem and soil water potentials during drought and a lower resistance to xylem cavitation, and reach E(crit) (the maximum steady-state transpiration rate without hydraulic failure) at higher soil water potentials than trees on loamy-clay soil. However, minimum predawn leaf xylem water potentials measured during the height of summer drought were significantly lower at the sandy-loam site (-3.5 +/- 0.1 MPa; all errors are 95% confidence limits) than at the loamy-clay site (-2.9 +/- 0.1 MPa). Minimum midday xylem water potentials also were lower at the sandy-loam site (-4.5 +/- 0.1 MPa) than at the loamy-clay site (-4.0 +/- 0.1 MPa). Despite the differences in leaf water potentials, there were no significant differences in either root or stem xylem embolism, mean cavitation pressure or Psi(95) (xylem water potential causing 95% cavitation) between trees at the two sites. A soil-plant hydraulic model parameterized with the field data predicted that E(crit) approaches zero at a substantially higher bulk soil water potential (Psi(s)) on sandy-loam soil than on loamy-clay soil, because of limiting rhizosphere conductance. The model predicted that transpiration at the sandy-loam site is limited by E(crit) and is tightly coupled to Psi(s) over much of the growing season, suggesting that seasonal transpiration fluxes at the sandy-loam site are strongly linked to intra-annual precipitation pulses. Conversely, the model predicted that trees on loamy-clay soil operate below E(crit) throughout the growing season, suggesting that fluxes on fine-textured soils are closely coupled to inter-annual changes in precipitation. Information on the combined importance of xylem and rhizosphere constraints to leaf water supply across soil

  18. Determination of degradation rates of organic substances in the unsaturated soil zone depending on the grain size fractions of various soil types

    Science.gov (United States)

    Fichtner, Thomas; Stefan, Catalin; Goersmeyer, Nora

    2015-04-01

    Rate and extent of the biological degradation of organic substances during transport through the unsaturated soil zone is decisively influenced by the chemical and physical properties of the pollutants such as water solubility, toxicity and molecular structure. Furthermore microbial degradation processes are also influenced by soil-specific properties. An important parameter is the soil grain size distribution on which the pore volume and the pore size depends. Changes lead to changes in air and water circulation as well as preferred flow paths. Transport capacity of water inclusive nutrients is lower in existing bad-drainable fine pores in soils with small grain size fractions than in well-drainable coarse pores in a soil with bigger grain size fractions. Because fine pores are saturated with water for a longer time than the coarse pores and oxygen diffusion in water is ten thousand times slower than in air, oxygen is replenished much slower in soils with small grain size fractions. As a result life and growth conditions of the microorganisms are negatively affected. This leads to less biological activity, restricted degradation/mineralization of pollutants or altered microbial processes. The aim of conducted laboratory column experiments was to study the correlation between the grain size fractions respectively pore sizes, the oxygen content and the biodegradation rate of infiltrated organic substances. Therefore two columns (active + sterile control) were filled with different grain size fractions (0,063-0,125 mm, 0,2-0,63 mm and 1-2 mm) of soils. The sterile soil was inoculated with a defined amount of a special bacteria culture (sphingobium yanoikuae). A solution with organic substances glucose, oxalic acid, sinaphylic alcohol and nutrients was infiltrated from the top in intervals. The degradation of organic substances was controlled by the measurement of dissolved organic carbon in the in- and outflow of the column. The control of different pore volumes

  19. Soil Degradation Evaluated by a 27 years Landsat image (Vis-Nir-Swir-Tir), climate and digital elevation derivatives

    Science.gov (United States)

    Dematte, J. A., Sr.; Santos, N. V.; de Almeida Malzoni, M. M.; Poppiel, R. R.; Fongaro, C. T.; Rizzo, R.; Safanelli, J. L.; Sayão, V. M.; Mendes, W. S.

    2017-12-01

    According to Food and Agriculture Organization of the United Nations, 30% of the global soils are degraded. Therefore, novel researches on soil degradation process are imperative to prevent damages on social and environmental dynamics. Since we have a wide world dimension, and few manpower, we have to focus on high dimensional evaluation techniques such as remote sensing. The main goal of this work was to develop a method, based on a 27 years time-series of satellite images (Landsat), from which determine the most important factors on soil degradation. The area is located in south Brazil with a 1400 km2 area. The steps of the method are as follows: a) we collected images from the area and based on a novel technique determined the areas with exposed soils; b) we quantified soil properties such as clay and capacity of ionic exchange based on pixel spectra signature; c) the technique also indicated how many times a single pixel was with bare soil during the period; d) we also determined the surface temperature based on band 6; e) using elevation model we created the layers LS factor, drainage density, topographic wetness index, solar radiation; f) we also determined climate information (water balance); g) organic matter (OM) was also estimated. All factors from item a to f were balanced and overlapped (GIS) to generate an index of soil degradation, SD (fig 1a) - values from 1 (low risk) to 5 (high risk). We concluded that 30% of the area is degraded. SD presented coherent values with OM and validate the method. We observed that areas with higher SD (5) contain 43.6% less OM than the ones with low risk (1). In addition, the soil spectral reflectance curve was analyzed concluding that degraded soils shows higher intensity. The current land use (fig 1b) was correlated demonstrating that a higher risk of SD happens mainly in sugar cane (41.6%) in contrast to pasture (16.9%) and forestry (11.7%). Therefore, this approach allows land uses decision-making and public policies.

  20. Peculiarities of pulse crops mineral feeding on sod-podzolic sandy soils contaminated with radionuclides

    International Nuclear Information System (INIS)

    Timofeev, S.F.; Sedukova, G.V.; Demidovich, S.A.

    2010-01-01

    In the conditions of the Republic of Belarus there was analyzed the influence of mineral fertilizers of leguminius crops (blue lupine (Lupinus angustifolius) of Gelena variety and field pea (Pisum arvense) of Alex variety) on yielding capacity, grain and green mass quality, and parameters transit of 137Cs and 90Sr radionuclides into leguminous products. In course of the experiment there were analyzed six variants of mineral fertilizer application P30K30; P30K90; P30K120; P60K60; P60K90; and P60K120. Variant without any fertilizers was as control. Double superphosphate (46% of P2O5) and potash chloride (60% of K2O) were applied as mineral fertilizers. Research results showed that application of phosphate-potassium fertilizers on sod-podzolic sandy soils moderately supplied with phosphate and potassium made it possible to increase pea and lupine yield. The highest efficiency of application of phosphate-potassium fertilizers was in the ratio of 1 (ðá2ð×5) : 2 (ðÜ2ð×) provided. Fertilizer system did not render substantial influence on indexes of nutritive value of green mass of pea and lupine. There was marked a tendency of increasing of phosphorous in lupine grain after its application in dose of P60. Mineral fertilizer application made it possible to lower 137Cs transit from soil into lupine green mass in 2 times and seeds ÔÇô in 1,5 times. Application of potassium fertilizer in dose of 120 kg/ha proved to be the most efficient for the lowering of 137Cs accumulation in products of the analyzed crops

  1. Degradation and plant uptake of nonylphenol (NP) and nonylphenol-12-ethoxylate (NP12EO) in four contrasting agricultural soils

    International Nuclear Information System (INIS)

    Sjoestroem, A.E.; Collins, C.D.; Smith, S.R.; Shaw, G.

    2008-01-01

    Nonylphenol polyethoxylates (NPEOs) are surfactants found ubiquitously in the environment due to widespread industrial and domestic use. Biodegradation of NPEOs produces nonylphenol (NP), an endocrine disruptor. Sewage sludge application introduces NPEOs and NP into soils, potentially leading to accumulation in soils and crops. We examined degradation of NP and nonylphenol-12-ethoxylate (NP12EO) in four soils. NP12EO degraded rapidly (initial half time 0.3-5 days). Concentrations became undetectable within 70-90 days, with a small increase in NP concentrations after 30 days. NP initially degraded quickly (mean half time 11.5 days), but in three soils a recalcitrant fraction of 26-35% remained: the non-degrading fraction may consist of branched isomers, resistant to biodegradation. Uptake of NP by bean plants was also examined. Mean bioconcentration factors for shoots and seeds were 0.71 and 0.58, respectively. Removal of NP from the soil by plant uptake was negligible (0.01-0.02% of initial NP). Root concentrations were substantially higher than shoot and seed concentrations. - Degradation curves of nonylphenol (NP) and nonylphenol-12-ethoxylate (NP12EO) in four soils indicate that 26-35% of NP is recalcitrant, with minor NP ingrowth from NP12EO breakdown

  2. Characterization of Trapped Lignin-Degrading Microbes in Tropical Forest Soil

    Energy Technology Data Exchange (ETDEWEB)

    DeAngelis, Kristen; Allgaier, Martin; Chavarria, Yaucin; Fortney, Julian; Hugenholtz, Phillip; Simmons, Blake; Sublette, Kerry; Silver, Whendee; Hazen, Terry

    2011-07-14

    Lignin is often the most difficult portion of plant biomass to degrade, with fungi generally thought to dominate during late stage decomposition. Lignin in feedstock plant material represents a barrier to more efficient plant biomass conversion and can also hinder enzymatic access to cellulose, which is critical for biofuels production. Tropical rain forest soils in Puerto Rico are characterized by frequent anoxic conditions and fluctuating redox, suggesting the presence of lignin-degrading organisms and mechanisms that are different from known fungal decomposers and oxygen-dependent enzyme activities. We explored microbial lignin-degraders by burying bio-traps containing lignin-amended and unamended biosep beads in the soil for 1, 4, 13 and 30 weeks. At each time point, phenol oxidase and peroxidase enzyme activity was found to be elevated in the lignin-amended versus the unamended beads, while cellulolytic enzyme activities were significantly depressed in lignin-amended beads. Quantitative PCR of bacterial communities showed more bacterial colonization in the lignin-amended compared to the unamended beads after one and four weeks, suggesting that the lignin supported increased bacterial abundance. The microbial community was analyzed by small subunit 16S ribosomal RNA genes using microarray (PhyloChip) and by high-throughput amplicon pyrosequencing based on universal primers targeting bacterial, archaeal, and eukaryotic communities. Community trends were significantly affected by time and the presence of lignin on the beads. Lignin-amended beads have higher relative abundances of representatives from the phyla Actinobacteria, Firmicutes, Acidobacteria and Proteobacteria compared to unamended beads. This study suggests that in low and fluctuating redox soils, bacteria could play a role in anaerobic lignin decomposition.

  3. Characterization of trapped lignin-degrading microbes in tropical forest soil

    Energy Technology Data Exchange (ETDEWEB)

    DeAngelis, K.M.; Allgaier, M.; Chavarria, Y.; Fortney, J.L.; Hugenholz, P.; Simmons, B.; Sublette, K.; Silver, W.L.; Hazen, T.C.

    2011-03-01

    Lignin is often the most difficult portion of plant biomass to degrade, with fungi generally thought to dominate during late stage decomposition. Lignin in feedstock plant material represents a barrier to more efficient plant biomass conversion and can also hinder enzymatic access to cellulose, which is critical for biofuels production. Tropical rain forest soils in Puerto Rico are characterized by frequent anoxic conditions and fluctuating redox, suggesting the presence of lignin-degrading organisms and mechanisms that are different from known fungal decomposers and oxygen-dependent enzyme activities. We explored microbial lignin-degraders by burying bio-traps containing lignin-amended and unamended biosep beads in the soil for 1, 4, 13 and 30 weeks. At each time point, phenol oxidase and peroxidase enzyme activity was found to be elevated in the lignin-amended versus the unamended beads, while cellulolytic enzyme activities were significantly depressed in lignin-amended beads. Quantitative PCR of bacterial communities showed more bacterial colonization in the lignin-amended compared to the unamended beads after one and four weeks, suggesting that the lignin supported increased bacterial abundance. The microbial community was analyzed by small subunit 16S ribosomal RNA genes using microarray (PhyloChip) and by high-throughput amplicon pyrosequencing based on universal primers targeting bacterial, archaeal, and eukaryotic communities. Community trends were significantly affected by time and the presence of lignin on the beads. Lignin-amended beads have higher relative abundances of representatives from the phyla Actinobacteria, Firmicutes, Acidobacteria and Proteobacteria compared to unamended beads. This study suggests that in low and fluctuating redox soils, bacteria could play a role in anaerobic lignin decomposition.

  4. Sphingomonas from petroleum-contaminated soils in Shenfu, China and their PAHs degradation abilities

    Directory of Open Access Journals (Sweden)

    Lisha Zhou

    2016-06-01

    Full Text Available Abstract Members of the Sphingomonas genus are often isolated from petroleum-contaminated soils due to their unique abilities to degrade polycyclic aromatic hydrocarbons (PAHs, which are important for in situ bioremediation. In this study, a combined phenotypic and genotypic approach using streptomycin-containing medium and Sphingomonas -specific PCR was developed to isolate and identify culturable Sphingomonas strains present in petroleum-contaminated soils in the Shenfu wastewater irrigation zone. Of the 15 soil samples examined, 12 soils yielded yellow streptomycin-resistant colonies. The largest number of yellow colony-forming units (CFUs could reach 105 CFUs g-1 soil. The number of yellow CFUs had a significant positive correlation (p < 0.05 with the ratio of PAHs to total petroleum hydrocarbons (TPH, indicating that Sphingomonas may play a key role in degrading the PAH fraction of the petroleum contaminants at this site. Sixty yellow colonies were selected randomly and analyzed by colony PCR using Sphingomonas -specific primers, out of which 48 isolates had PCR-positive signals. The 48 positive amplicons generated 8 distinct restriction fragment length polymorphism (RFLP patterns, and 7 out of 8 phylotypes were identified as Sphingomonas by 16S rRNA gene sequencing of the representative strains. Within these 7 Sphingomonas strains, 6 strains were capable of using fluorene as the sole carbon source, while 2 strains were phenanthrene-degrading Sphingomonas. To the best of our knowledge, this is the first report to evaluate the relationship between PAHs contamination levels and culturable Sphingomonas in environmental samples.

  5. Predicting where enhanced atrazine degradation will occur based on soil pH and herbicide use history

    Science.gov (United States)

    Soil bacteria on all continents except Antartica have developed the ability to rapidly degrade the herbicide atrazine, a phenomenon referred to as enhanced degradation. The agronomic significance of enhanced degradation is the potential for reduced residual weed control with atrazine in Corn, Sorgh...

  6. Sustainable agriculture and soil conservation

    DEFF Research Database (Denmark)

    Olsen, Preben; Dubgaard, Alex

    , sandy soils in the West, (that had not been covered by ice) from more fertile soils being mostly sandy loams and finer textured soils covering the Eastern part of the study area. Several geological features such as pitting due to dead ice formation, smaller, terminal moraines in association with melt......, separate the moraine plateau. From the plateau several, minor erosion valleys, formed at the end of the glaciation some 10,000 years ago, feed into the two valleys. Very accurate soil type information is available for the area as intensive measurements within the area has formed the basis for a new...... methodology for soil classification in Denmark. The soil survey included a detailed mapping at field level, using the electromagnetic sensor, EM38. A high-resolution digital elevation model, obtained by use of laser scanning, is available for the study area. The original scanning has a horizontal resolution...

  7. Pyrethroid-Degrading Microorganisms and Their Potential for the Bioremediation of Contaminated Soils: A Review

    Science.gov (United States)

    Cycoń, Mariusz; Piotrowska-Seget, Zofia

    2016-01-01

    Pyrethroid insecticides have been used to control pests in agriculture, forestry, horticulture, public health and for indoor home use for more than 20 years. Because pyrethroids were considered to be a safer alternative to organophosphate pesticides (OPs), their applications significantly increased when the use of OPs was banned or limited. Although, pyrethroids have agricultural benefits, their widespread and continuous use is a major problem as they pollute the terrestrial and aquatic environments and affect non-target organisms. Since pyrethroids are not degraded immediately after application and because their residues are detected in soils, there is an urgent need to remediate pyrethroid-polluted environments. Various remediation technologies have been developed for this purpose; however, bioremediation, which involves bioaugmentation and/or biostimulation and is a cost-effective and eco-friendly approach, has emerged as the most advantageous method for cleaning-up pesticide-contaminated soils. This review presents an overview of the microorganisms that have been isolated from pyrethroid-polluted sites, characterized and applied for the degradation of pyrethroids in liquid and soil media. The paper is focused on the microbial degradation of the pyrethroids that have been most commonly used for many years such as allethrin, bifenthrin, cyfluthrin, cyhalothrin, cypermethrin, deltamethrin, fenpropathrin, fenvalerate, and permethrin. Special attention is given to the bacterial strains from the genera Achromobacter, Acidomonas, Bacillus, Brevibacterium, Catellibacterium, Clostridium, Lysinibacillus, Micrococcus, Ochrobactrum, Pseudomonas, Serratia, Sphingobium, Streptomyces, and the fungal strains from the genera Aspergillus, Candida, Cladosporium, and Trichoderma, which are characterized by their ability to degrade various pyrethroids. Moreover, the current knowledge on the degradation pathways of pyrethroids, the enzymes that are involved in the cleavage of

  8. Pyrethroid-Degrading Microorganisms and Their Potential for the Bioremediation of Contaminated Soils: A Review

    Directory of Open Access Journals (Sweden)

    Mariusz Sebastian Cycoń

    2016-09-01

    Full Text Available Pyrethroid insecticides have been used to control pests in agriculture, forestry, horticulture, public health and for indoor home use for more than 20 years. Because pyrethroids were considered to be a safer alternative to organophosphate pesticides (OPs, their applications significantly increased when the use of OPs was banned or limited. Although pyrethroids have agricultural benefits, their widespread and continuous use is a major problem as they pollute the terrestrial and aquatic environments and affect non-target organisms. Since pyrethroids are not degraded immediately after application and because their residues are detected in soils, there is an urgent need to remediate pyrethroid-polluted environments. Various remediation technologies have been developed for this purpose; however, bioremediation, which involves bioaugmentation and/or biostimulation and is a cost-effective and eco-friendly approach, has emerged as the most advantageous method for cleaning-up pesticide-contaminated soils. This review presents an overview of the microorganisms that have been isolated from pyrethroid-polluted sites, characterized and applied for the degradation of pyrethroids in liquid and soil media. The paper is focused on the microbial degradation of the pyrethroids that have been most commonly used for many years such as allethrin, bifenthrin, cyfluthrin, cyhalothrin, cypermethrin, deltamethrin, fenpropathrin, fenvalerate and permethrin. Special attention is given to the bacterial strains from the genera Achromobacter, Acidomonas, Bacillus, Brevibacterium, Catellibacterium, Clostridium, Lysinibacillus, Micrococcus, Ochrobactrum, Pseudomonas, Serratia, Sphingobium, Streptomyces and the fungal strains from the genera Aspergillus, Candida, Cladosporium and Trichoderma, which are characterized by their ability to degrade various pyrethroids. Moreover, the current knowledge on the degradation pathways of pyrethroids, the enzymes that are involved in the

  9. Critical Analysis of Forest Degradation in the Southern Eastern Ghats of India: Comparison of Satellite Imagery and Soil Quality Index

    Science.gov (United States)

    Ramachandran, Andimuthu; Radhapriya, Parthasarathy; Jayakumar, Shanmuganathan; Dhanya, Praveen; Geetha, Rajadurai

    2016-01-01

    India has one of the largest assemblages of tropical biodiversity, with its unique floristic composition of endemic species. However, current forest cover assessment is performed via satellite-based forest surveys, which have many limitations. The present study, which was performed in the Eastern Ghats, analysed the satellite-based inventory provided by forest surveys and inferred from the results that this process no longer provides adequate information for quantifying forest degradation in an empirical manner. The study analysed 21 soil properties and generated a forest soil quality index of the Eastern Ghats, using principal component analysis. Using matrix modules and geospatial technology, we compared the forest degradation status calculated from satellite-based forest surveys with the degradation status calculated from the forest soil quality index. The Forest Survey of India classified about 1.8% of the Eastern Ghats’ total area as degraded forests and the remainder (98.2%) as open, dense, and very dense forests, whereas the soil quality index results found that about 42.4% of the total area is degraded, with the remainder (57.6%) being non-degraded. Our ground truth verification analyses indicate that the forest soil quality index along with the forest cover density data from the Forest Survey of India are ideal tools for evaluating forest degradation. PMID:26812397

  10. Critical Analysis of Forest Degradation in the Southern Eastern Ghats of India: Comparison of Satellite Imagery and Soil Quality Index.

    Science.gov (United States)

    Ramachandran, Andimuthu; Radhapriya, Parthasarathy; Jayakumar, Shanmuganathan; Dhanya, Praveen; Geetha, Rajadurai

    2016-01-01

    India has one of the largest assemblages of tropical biodiversity, with its unique floristic composition of endemic species. However, current forest cover assessment is performed via satellite-based forest surveys, which have many limitations. The present study, which was performed in the Eastern Ghats, analysed the satellite-based inventory provided by forest surveys and inferred from the results that this process no longer provides adequate information for quantifying forest degradation in an empirical manner. The study analysed 21 soil properties and generated a forest soil quality index of the Eastern Ghats, using principal component analysis. Using matrix modules and geospatial technology, we compared the forest degradation status calculated from satellite-based forest surveys with the degradation status calculated from the forest soil quality index. The Forest Survey of India classified about 1.8% of the Eastern Ghats' total area as degraded forests and the remainder (98.2%) as open, dense, and very dense forests, whereas the soil quality index results found that about 42.4% of the total area is degraded, with the remainder (57.6%) being non-degraded. Our ground truth verification analyses indicate that the forest soil quality index along with the forest cover density data from the Forest Survey of India are ideal tools for evaluating forest degradation.

  11. Soil Organic Carbon Fractions and Stocks Respond to Restoration Measures in Degraded Lands by Water Erosion

    Science.gov (United States)

    Nie, Xiaodong; Li, Zhongwu; Huang, Jinquan; Huang, Bin; Xiao, Haibing; Zeng, Guangming

    2017-05-01

    Assessing the degree to which degraded soils can be recovered is essential for evaluating the effects of adopted restoration measures. The objective of this study was to determine the restoration of soil organic carbon under the impact of terracing and reforestation. A small watershed with four typical restored plots (terracing and reforestation (four different local plants)) and two reference plots (slope land with natural forest (carbon-depleted) and abandoned depositional land (carbon-enriched)) in subtropical China was studied. The results showed that soil organic carbon, dissolved organic carbon and microbial biomass carbon concentrations in the surface soil (10 cm) of restored lands were close to that in abandoned depositional land and higher than that in natural forest land. There was no significant difference in soil organic carbon content among different topographic positions of the restored lands. Furthermore, the soil organic carbon stocks in the upper 60 cm soils of restored lands, which were varied between 50.08 and 62.21 Mg C ha-1, were higher than 45.90 Mg C ha-1 in natural forest land. Our results indicated that the terracing and reforestation could greatly increase carbon sequestration and accumulation and decrease carbon loss induced by water erosion. And the combination measures can accelerate the restoration of degraded soils when compared to natural forest only. Forest species almost have no impact on the total amount of soil organic carbon during restoration processes, but can significantly influence the activity and stability of soil organic carbon. Combination measures which can provide suitable topography and continuous soil organic carbon supply could be considered in treating degraded soils caused by water erosion.

  12. Soil Organic Carbon Fractions and Stocks Respond to Restoration Measures in Degraded Lands by Water Erosion.

    Science.gov (United States)

    Nie, Xiaodong; Li, Zhongwu; Huang, Jinquan; Huang, Bin; Xiao, Haibing; Zeng, Guangming

    2017-05-01

    Assessing the degree to which degraded soils can be recovered is essential for evaluating the effects of adopted restoration measures. The objective of this study was to determine the restoration of soil organic carbon under the impact of terracing and reforestation. A small watershed with four typical restored plots (terracing and reforestation (four different local plants)) and two reference plots (slope land with natural forest (carbon-depleted) and abandoned depositional land (carbon-enriched)) in subtropical China was studied. The results showed that soil organic carbon, dissolved organic carbon and microbial biomass carbon concentrations in the surface soil (10 cm) of restored lands were close to that in abandoned depositional land and higher than that in natural forest land. There was no significant difference in soil organic carbon content among different topographic positions of the restored lands. Furthermore, the soil organic carbon stocks in the upper 60 cm soils of restored lands, which were varied between 50.08 and 62.21 Mg C ha -1 , were higher than 45.90 Mg C ha -1 in natural forest land. Our results indicated that the terracing and reforestation could greatly increase carbon sequestration and accumulation and decrease carbon loss induced by water erosion. And the combination measures can accelerate the restoration of degraded soils when compared to natural forest only. Forest species almost have no impact on the total amount of soil organic carbon during restoration processes, but can significantly influence the activity and stability of soil organic carbon. Combination measures which can provide suitable topography and continuous soil organic carbon supply could be considered in treating degraded soils caused by water erosion.

  13. Microseisms from Superstorm Sandy

    Science.gov (United States)

    Sufri, Oner; Koper, Keith D.; Burlacu, Relu; de Foy, Benjamin

    2014-09-01

    We analyzed and visualized the microseisms generated by Superstorm Sandy as recorded by the Earthscope Transportable Array (TA) during late October through early November of 2012. We applied continuous, frequency-dependent polarization analysis to the data and were able to track the course of Sandy as it approached the Florida coastline and, later, the northeastern coast of the U.S. The energy level of Sandy was roughly comparable to the background microseism level generated by wave-wave interactions in the North Atlantic and North Pacific oceans. The maximum microseismic power and degree of polarization were observed across the TA when Sandy sharply changed its direction to the west-northwest (specifically, towards Long Island, New York) on October 29. The westward turn also briefly changed the dominant microseism period from 5 s to 8 s. We identified three other microseismic source regions during the 18 day observation period. In particular, peak-splitting in the double frequency band and the orientation of the 5 s and 8 s polarization vectors revealed two contemporaneous microseism sources, one in the North Atlantic and one in the Northeast Pacific, for the dates of November 3-4. Predictions of microseismic excitation based on ocean wave models showed consistency with the observed microseismic energy generated by Sandy and other storms.

  14. Effect of nitrogen and water availability of three soil types on yield, radiation use efficiency and evapotranspiration in field-grown quinoa

    DEFF Research Database (Denmark)

    Razzaghi, Fatemeh; Plauborg, Finn; Jacobsen, Sven-Erik

    2012-01-01

    Quinoa (Chenopodium quinoa Willd.) is believed to be tolerant to abiotic stress including salinity, drought and poor soil quality. To investigate the effect of soil type and soil-drying during the seed-filling phase on N-uptake, yield and water use, a Danish-bred cultivar (cv. Titicaca) was grown...... in field lysimeters with sand, sandy loam and sandy clay loam soil. Despite application of the same amount of nitrogen (120 kg N ha−1) to all plots, there were large differences in crop nitrogen-uptake for sandy clay loam (134 kg ha−1), sandy loam (102 kg ha−1) and sand (77 kg ha−1) under full irrigation....... This lead to higher interception of photosynthetic active radiation and higher seed yield on sandy clay loam (3.3 Mg ha−1) and sandy loam (3.0 Mg ha−1) than on sand (2.3 Mg ha−1). The soil with higher clay content had also the highest transpiration, crop evapotranspiration and yield due to the higher uptake...

  15. A Slurry Biocascade for the Enhanced Degradation of Fuels in Soils

    National Research Council Canada - National Science Library

    Apitz, Sabine

    1994-01-01

    .... In the first step of the cascade, the simplest fuel components (e.g., n-alkanes) are biodegraded. Then, the soil is transferred to the next steps in the cascade, in which different "microbial soups" degrade the next groups of hydrocarbons...

  16. Development and duration of accelerated degradation of nematicides in different soils

    NARCIS (Netherlands)

    Smelt, J.H.; Peppel-Groen, van de A.E.; Pas, van der L.J.T.; Dijksterhuis, A.

    1996-01-01

    The development and duration of accelerated degradation of nematicides were studied in incubation experiments with soils from three experimental fields that had been treated annually for three to ten years with aldicarb, oxamyl, ethoprophos, fenamiphos or 1,3-dichloropropene. Highly accelerated

  17. Soil compaction during harvest operations in five tropical soils with different textures under eucalyptus forests

    Directory of Open Access Journals (Sweden)

    Paula Cristina Caruana Martins

    Full Text Available ABSTRACT Traffic of farm machinery during harvest and logging operations has been identified as the main source of soil structure degradation in forestry activity. Soil susceptibility to compaction and the amount of compaction caused by each forest harvest operation differs according to a number of factors (such as soil strength, soil texture, kind of equipment, traffic intensity, among many others, what requires the adequate assessment of soil compaction under different traffic conditions. The objectives of this study were to determine the susceptibility to compaction of five soil classes with different textures under eucalyptus forests based on their load bearing capacity models; and to determine, from these models and the precompression stresses obtained after harvest operations, the effect of traffic intensity with different equipment in the occurrence of soil compaction. Undisturbed soil samples were collected before and after harvest operations, being then subjected to uniaxial compression tests to determine their precompression stress. The coarse-textured soils were less resistant and endured greater soil compaction. In the clayey LVd2, traffic intensity below four Forwarder passes limited compaction to a third of the samples, whereas in the sandy loam PVd all samples from the 0-3 cm layer were compacted regardless of traffic intensity. The Feller Buncher and the Clambunk presented a high potential to cause soil compaction even with only one or two passes. The use of soil load bearing capacity models and precompression stress determined after harvest and logging operations allowed insight into the soil compaction process in forestry soils.

  18. Detection of Toluene Degradation in Bacteria Isolated from Oil Contaminated Soils

    International Nuclear Information System (INIS)

    Ainon Hamzah; Tavakoli, A.; Amir Rabu

    2011-01-01

    Toluene (C 7 H 8 ) a hydrocarbon in crude oil, is a common contaminant in soil and groundwater. In this study, the ability to degrade toluene was investigated from twelve bacteria isolates which were isolated from soil contaminated with oil. Out of 12 bacterial isolates tested, most of Pseudomonas sp. showed the capability to grow in 1 mM of toluene compared with other isolates on the third day of incubation. Based on enzyme assays towards toluene monooxygenase, Pseudomonas aeruginosa UKMP-14T and Bacillus cereus UKMP-6G were shown to have the highest ability to degrade toluene. The toluene monooxygenase activity was analysed by using two calorimetric methods, Horseradish peroxidase (HRP) and indole-indigo. Both of the methods measured the production of catechol by the enzymatic reaction of toluene monooxygenase. In the HRP assay, the highest enzyme activity was 0.274 U/ mL, exhibited by Pseudomonas aeruginosa UKMP-14T. However, for indole-indigo assay, Bacillus cereus UKMP-6G produced the highest enzyme activity of 0.291 U/ ml. Results from both experiments showed that Pseudomonas aeruginosa UKMP-14T and Bacillus cereus UKMP-6G were able to degrade toluene. (author)

  19. Physical-hydraulic properties of a sandy loam typic paleudalf soil under organic cultivation of 'montenegrina' mandarin (Citrus deliciosa Tenore¹

    Directory of Open Access Journals (Sweden)

    Caroline Valverde dos Santos

    2014-12-01

    Full Text Available Citrus plants are the most important fruit species in the world, with emphasis to oranges, mandarins and lemons. In Rio Grande do Sul, Brazil, most fruit production is found on small properties under organic cultivation. Soil compaction is one of the factors limiting production and due to the fixed row placement of this crop, compaction can arise in various manners in the interrows of the orchard. The aim of this study was to evaluate soil physical properties and water infiltration capacity in response to interrow management in an orchard of mandarin (Citrus deliciosa Tenore 'Montenegrina' under organic cultivation. Interrow management was performed through harrowing, logs in em "V", mowing, and cutting/knocking down plants with a knife roller. Soil physical properties were evaluated in the wheel tracks of the tractor (WT, between the wheel tracks (BWT, and in the area under the line projection of the canopy (CLP, with undisturbed soil samples collected in the 0.00-0.15, 0.15-0.30, 0.30-0.45, and 0.45-0.60 m layers, with four replicates. The soil water infiltration test was performed using the concentric cylinder method, with a maximum time of 90 min for each test. In general, soil analysis showed a variation in the physical-hydraulic properties of the Argissolo Vermelho-Amarelo distrófico arênico (sandy loam Typic Paleudalf in the three sampling sites in all layers, regardless of the management procedure in the interrows. Machinery traffic leads to heterogeneity in the soil physical-hydraulic properties in the interrows of the orchard. Soil porosity and bulk density are affected especially in the wheel tracks of the tractor (WT, which causes a reduction in the constant rate of infiltration and in the accumulated infiltration of water in this sampling site. The use of the disk harrow and mower leads to greater harmful effects on the soil, which can interfere with mandarin production.

  20. Phosphorus application to cotton enhances growth, yield, and quality characteristics on a sandy loam soil

    International Nuclear Information System (INIS)

    Ahmad, M.; Ranjha, A.M.

    2009-01-01

    Phosphorus (P) is the second most limiting nutrient in cotton (Gossypium hirsutum L.) production after nitrogen. Under wheat-cotton cropping system of Pakistan most of the farmers apply P fertilizer only to wheat crop. A field experiment was conducted to evaluate the effect of fertilizer P on the growth, yield and fibre quality of cotton on a sandy loam calcareous soil at farmer's field in cotton growing area of district Khanewal, Punjab. Five levels of P (0, 17, 26, 34 and 43 kg P ha /sup -1/) along with 120 kg N and 53 kg K ha/sup -1/ were applied. The response of cotton growth parameters was greater than quality components to P addition in calcareous soil. There was significant increase in the growth and yield parameters with each additional rate of P. The response of number of bolls per plant, boll weight and seed cotton yield was to the tune of 88.23, 16.82 and 42%, respectively at P application rate of 34 kg ha/sup -1/. Cotton quality components (lint %age, fiber length and fiber strength) improved from 2 to 5% where 43 kg P ha/sup -1/ was added. The lint and seed P concentration was little affected by P application as compared to stem and leaves showing its essentiality for cell division and development of meristematic tissue. Phosphorus use, thus not only valuable for wheat crop but also its application to cotton crop is of vital importance in improving both lint yield and quality. (author)